TS-E077KJ For R&D use only ISSUED:2013/May/13 

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CBI 

MATERIAL SAFETY DATA SHEET 

CBI

SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION 

(CBI) TRADE NAME: (CBI) 

CHEMICAL FAMILY: Fluoroalkylacrylate copolymer (solution) – For R&D use only 

(CBI) INDUSTREIES, LTD: (CBI) 

PHONE: (CBI) 

FAX: (CBI) 

SECTION 2: HAZARDS IDENTIFICATION 

PHYSICAL DESCRIPTION: (CBI) 

POTENTIAL HEALTH EFFECTS: May cause eye, skin and respiratory irritation. May be harmful if ingested. Above 200°C, 

hydrogen fluoride and other toxic fluorinated compounds may be produced; inhalation of 

these compounds under these conditions may result in serious lung irritation. 

HMIS RATINGS: Health : 1 

 Flammability : 1 

 Reactivity : 0 

SECTION 3: INFORMATION ON INGREDIENTS 

COMPONENT CAS. NO. Wt% OSHA (PEL) ACGIH (TLV) 

NON-HAZARDOUS INGREDIENTS 

CBI CBI CBI None None 

CBI CBI CBI None None 

SECTION 4. FIRST AID PROCEDURES 

INGESTION: Consult a physician immediately. 

EYE CONTACT: Flush with large amounts of water for 10-15 minutes. Consult a physician if needed. 

SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing and shoes. 

INHALATION: Leave the contaminated area and seek fresh air. If breathing is difficult, contact a physician. 

NOTE TO PHYSICIANS: In the event of inhalation of gases generated by high temperature decomposition of the 

product, treat for hydrogen fluoride inhalation. Excessive exposure to thermal degradation 

products could result in delayed pulmonary edema in some cases, and on very high exposure, 

damage to the liver and kidneys. 

R&D Use Only

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SECTION 5. FIRE FIGHTING MEASURES 

FLASH POINT (METHOD USED): Not tested 

FLAMMABLE LIMITS: LEL: Not tested UEL: Not tested 

HAZARDOUS COMBUSTION PRODUCTS: Toxic by-products including hydrofluoric acid, perfluoroisobutylene, and 

carbonyl fluoride may be formed at very high temperatures. 

EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical or water spray 

PROTECTIVE EQUIPMENT: Use NIOSH/MSHA approved SCBA and bunker gear. Evolution of acidic 

gases may require complete wash down of protective clothing prior to removal. 

SECTION 6. ACCIDENTAL RELEASE MEASURES 

Ensure cleanup is done only by trained personnel wearing appropriate personal protective equipment. Ventilate area and cover 

with absorbent material. 

Collect the spilled material in a container and seal. 

Spilled material is a slipping hazard. 

SECTION 7. HANDLING & STORAGE 

HANDLING: 

Follow safe industrial hygiene practices and wear proper protective equipment. 

Use only in well ventilated areas. 

Safety showers & eyewashes should be available in the work area. 

Wash hands thoroughly after handling. Wash clothing after use. 

Avoid contact with the skin or eyes. 

Do not breathe vapor or spray. 

Do not store or consume food, drink or tobacco in areas where they may become contaminated with this material. 

STORAGE: 

Store material at –5 °C (23 °F) to 40 °C (104 °F). 

Keep away from heat, sparks and open flame. 

Keep containers tightly closed when not in use. 

SECTION 8. EXPOSURE CONTROLS & PERSONAL PROTECTIVE EQUIPMENT 

RESPIRATORY PROTECTION: Use respirator suitable for protection when spraying this material. If material is 

heated above 200 °C, use a positive pressure air supplied respirator or SCBA. 

EYE PROTECTION: Safety glasses with sideshields or goggles 

PROTECTIVE CLOTHING: Chemical resistant gloves 

VENTILATION: If material is heated above 200 °C, use local exhaust ventilation. 

OTHER PROTECTIVE EQUIPMENT: Eyewash station and safety shower. 

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SECTION 9. PHYSICAL & CHEMICAL PROPERTIES 

PHYSICAL STATE: CBI 

VAPOR PRESSURE: CBI 

DENSITY: CBI 

SOLUBILITY IN SOLVENT: CBI 

SOLUBILITY IN WATER: CBI 

MELTING POINT (°C): CBI 

BOILING POINT (°C): CBI 

SPECTRA: CBI 

DISSOCIATION CONSTANT: CBI 

PARTICLE SIZE: CBI 

OCTANOL/WATER PARTITION COEFFICIENT: CBI 

HENRY’S LAW CONSTANT: CBI 

VOLITALIZATION FROM WATER: CBI 

VOLITALIZATION FROM SOIL: CBI 

pH: CBI 

FLAMMABILITY: CBI 

EXPLODABILITY: CBI 

ADSORPTION/COEFFICIENT: CBI 

SECTION 10. STABILITY & REACTIVITY 

STABILITY: Stable 

CONDITIONS TO AVOID: Excessive heat, sparks, open flame 

HAZARDOUS POLYMERIZATION: Should not occur 

INCOMPATIBILITIES: May react with metals, such as sodium, magnesium, aluminum at elevated 

temperatures (above 425 °C); may react upon prolonged exposure to fluorine or in 

oxygen-fluorine mixtures at high temperatures and pressures. Contact with 

incompatible materials may result in fire or explosion. 

 Hazardous decomposition or by-products and toxic by-products including 

hydrofluoric acid, perfluoroisobutylene, and carbonyl fluoride may be formed at very 

high temperatures. 

SECTION 11. TOXICOLOGICAL INFORMATION 

ACUTE EFFECTS OF EXPOSURE 

Ingestion: May be harmful if swallowed 

Eye Contact: May cause mild irritation 

Skin Contact: May cause skin irritation and sensitization 

Inhalation: May cause respiratory irritation 

CHRONIC EFFECTS OF EXPOSURE: No data available 

CARCINOGENICITY: None of the components in this material is listed by NTP, OSHA or IARC. 

TOXICOLOGICAL TEST: No data available 

OTHER POTENTIAL HAZARDS (OF THE PURE MATERIALS): No data 

available 

 

Excessive exposure to thermal degradation products could result in delayed pulmonary edema in some cases, and on very 

high exposure, damage to the liver and kidneys. These substances may include: perfluoroisobutylene (TLV = 10 ppb), 

carbonyl fluoride (TLV = 2 ppm TWA, 5 ppm STEL), hydrogen fluoride (TLV = 2 ppm Ceiling, 0.5 ppm TWA). 

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SECTION 12. ECOLOGICAL INFORMATION 

ECOTOXICITY: CBI 

BIODEGRADABILITY: CBI 

SECTION 13. DISPOSAL CONSIDERATIONS 

Comply with Federal, State, and Local regulations concerning health and environment when disposing of materials. Regulations 

may also apply to empty containers, liners, or rinsate. DO NOT INCINERATE unless incinerator is capable of scrubbing 

hydrogen fluoride and other acidic combustion products. 

SECTION 14. TRANSPORT INFORMATION 

UN CLASSIFICATION: CBI 

DOT HAZARD DESCRIPTION: CBI 

CANADIAN TRANSPORTATION 

OF DANGEROUS GOODS (TDG): CBI 

SECTION 15. REGULATORY INFORMATION 

TSCA: The TSCA status of this product has not yet been determined; as such, use of this product should be 

restricted to research and development work only. 

SECTION 16. OTHER INFORMATION 

For additional information, refer to the American Conference of Governmental Industrial Hygienists (ACGIH) documentation 

of TLV’s (Threshold Limit Values) for individual components, Fluoropolymers Safe Handling Guide published by The Society 

of the Plastics Industry, and the DOT Emergency Response Guidebook. 

CBI believes the information in this MSDS to be correct as of the date issued, but CBI assumes no liability for the accuracy or 

completeness of the data relied on in preparing this MSDS. CBI makes no warranties in this MSDS, either express or implied, 

and excludes all warranties, including without limitation any implied warranty of merchantability, fitness for a particular 

purpose or course of performance, or usage of trade. 

CBI may provide MSDS information in electronic form as a customer service. Due to the remote possibility that electronic 

transfer may result in errors, omissions or alterations in this information, CBI makes no representation or warranty as to its 

completeness or accuracy when so transferred. 

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