SANITIZED 

1111111111111111111111111111111111111111111111111111111 IY}R3~~;tfofuBMISSION 

PMN2010P1 PMN Page 1 

U.S. ENVIRONMENTAL PROTECTION AGENCY AGENCY USE ONLY 

PREMANUFACTURE 

NOTICE 

FOR NEW CHEMICAL SUBSTANCES 

74126417045 

OffIce of Pollution and Toxlcs 

Document Control OffIce 17407MI 

US EPA, 1200 Pennsylvania Ave NW 

WASHINGTON, D.C, 204eO 

Number 

X78T84 

i you do not have 

• Before you complete this form. you should read the "Instructions Manual for Premanutacture Notification" (the Instructions Manual is available from the Toxic Substances Control Act 

(TSCA) Information Service by calling 202-554-1404, or faxing 202-554-5603). 

• If a user fee has been remitted for this notice (40 CFR 700.45), indicate in the boxes above the TS-user fee identification number you have generated. Remember. your user fee ID number 

must also appear on your corresponding fee remittance For mailing address information see the Help instructions in the e"PMN tool. 

• You must provide all information requested in this form to the extent that it is known to or reasonably ascertainable by you. Make 

Part 1- GENERAL INFORMATION 

You must provide the curren~y correct Chemical Abstracts (CA) 

Name of the new chemical substance, even if you claim the 

identity as confidential. You may authorize another person to 

submit chemical identity information for you, but your submission 

will not be complete and the review will not begin until EPA 

receives this information. A letter in support of your submission 

should reference your TS user fee identification number. For all 

Section 5 Notice submissions (paper or electronic) you must 

submit an original notice including all test data; if you claimed any 

information as confidential, an original sanitized copy must also be 

submitted. 

Part 11- HUMAN EXPOSURE AND ENVIRONMENTAL 

RELEASE 

If there are several manufacture, processing, or use operations to 

be described in Part II, sections A and B of this notice, reproduce 

the sections as needed. 

Part 111- LIST OF ATTACHMENTS 

For paper submissions, attach additional sheets if there is not 

enough space to answer a question fully. Label each continuation 

sheet with the corresponding section heading. I n Part III, list these 

attachments, any test data or other data and any optional 

information included in the notice. 

OPTIONAL INFORMATION 

You may include any information that you want EPA to consider in 

evaluating the new substance. On page 11 of this form, space has 

been provided for you to describe pollution prevention and 

recycling information you may have regarding the new substance. 

"Binding" boxes are included throughout this form for you to 

indicate your willingness to be bound to certain statements you 

make in this section, such as use, production volume, protective 

equipment ... The intention is to reduce delays that routinely 

accompany the development of consent orders or Significant New 

Use Rules. Checking a "bind ing" box in a P MN does not by itself 

prohibit the submitter from later deviating from the information 

(except chemical identity) reported in the form; however, in the 

case of exemption applications (such as TMEA, LVE, LOREX) 

certain information provided in such notifications is binding on the 

submitter when the Agency approves the exemption application, 

especially if the production volume "binding" box is chosen in a 

LVE. 

CONFIDENTIALITY CLAIMS 

You may claim any information in this notice as confidential. To 

assert a claim on the form, marK (X) the confidential box next to 

the information that you claim as confidential. To assert a claim in 

an attachment, circle or bracket the information you claim as 

confidential. If you claim information in the notices as confidential 

you must also provide a sanitized version of the notice !including 

attachments). For additional instructions on claiming information 

as confidential, read the Instructions Manual. 

TEST DATA AND OTHER DATA P-10·4521

·453 

You are required to submit all test data in your possession or control and to provide a 

description of all other data known to or reasonably ascertainable by you, if these data are 

related to the health and environmental effects on the manufacture, processing, distribution in 

commerce, use, or disposal of the new chemical substance. Standard literabure citations may 

be submitted for data in the open SCientific literature. Complete test data (written in English), 

not summaries of data must be submitted if they do not appear in the open literature. You 

should clearly identify whether test data is on the substance or on an analog. Also. the 

chemical composition of the tested material should be characterized. Following are examples 

of test data and other data. Data should be submitted according to the requirements of 

§720.50 of the Premanufacture Notification Rule (40 CFR Part 720). 

Test Data (Check Below any included in this notice) 

D Environmental fate data D Other Data 

D Health effects data D Risk Assessments 

D Environmental effects data D Structure/activity relationships 

o Physical/Chemical Properties (A physical and chemical properties worKsheet is 

located on the last page of this form.) 

D Test data not in the possession or control of the submitter 

TYPE OF NOTICE (Check Only One) 

o PMN (Premanufacture Notice) 

D SNUN (Significant New Use Notice) 

D TMEA (Test MarKeting Exemption Application) 

D LVE (Low Volume Exemption) @ 40 CFR 723.50(c)(1) 

D LOREX (Low Release/Low Exposure Exemption) @ 40 CFR 723.50(c)(2) 

LVE Modification 

LOREX Modification 

Mock Submission 

D Mark (X) if pending Letter of Support 

X IS THIS A CONSOLIDATED PMN (Y/N)? 

# of chemicals or polymers (Prenotice Communication # required, enter # on 

2 p.3). 

Mark (X) if any information in this notice is claimed as confidential. 

EPA FORM 7710"25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 1 P10-45 2 -453 
11I111I11I1I11 111111111111111111 SANITIZED SUBMISSION 

PMN2010P2 PMN Page 2 

The public reporting and record keeping burden for this collection of information is estimated to average 93 hours per response. Send 

comments on the Agency's need for this information, the accuracy of the provided burden estimates, and any suggested methods for 

minimizing respondent burden, including through the use of automated collection techniques to the Director, Collection Strategies 

Division, U.S. Environmental Protection Agency (2822T). 1200 Pennsylvania Ave.• NW, Washington, D.C. 20460. Include the OMB 

control number in any correspondence. Do not send the completed EPA Form 7710-25 to this address. . 

CERTIFICATION -- A printed copy of this signature page, with original signature, must be submitteCl 

with CD or paper submission. 

I certify that to the best of my knowledge and belief: 

1. The company named in Part I, section A, subsection 1 a of this notice form intends to 

manufacture, import or process for a commercial purpose, other than in small quantities solely for 

research and development, the SUbstance identified in Part I, Section B. 

2. All information provided in this notice is complete and truthful as of the date of submission. 

3. 	I am submitting with this notice all test data in my possession or control and a description of all 


other data known to or reasonably ascertainable by me as required by §720.50 of the 


Premanufacture Notification Rule. 


Additional Certification Statements: 

If you are submitting a PMN, Intermediate PMN, Consolidated PMN, or SNUN, check the following user fee 

certification statement that applies: 

The Company named in Part I, Section A has remitted the fee of $2500 specified in 40 CFR 700.45(b), or 

The Company named in Part I, Section A has remitted the fee of $1000 for an Intermediate PMN (defined @ 40 CFR 700.43) in D accordance with 40 CFR 700.45(b). or 

The Company named in Part I Section A is a small business concem under 40 CFR 700.43 and has remitted a fee of $1 00 in D accordance with 40 CFR 700.45(b). 

If you are submitting a Low Volume Exemption (LVE) application in accordance with 40 CFR 723.50{c)(1) or a 

Low Release and Low Exposure Exemption (LoRex) application in accordance with 40 CFR 723.50{c){2), check 

the following certification statements: 

The manufacturer submitting this notice intends to manufacture or import the new chemical substance for commercial purposes. D other than in small quantities solely for research and development, under the terms of 40 CFR 723.50. 

D 
 The manufacturer is familiar with the terms of this section and will comply with those terms; and 

D The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

D If this application is for an LVE in accordance with 40 CFR 723.50(c)(1), the manufacturer intends to commence manufacture of 

the exempted substance for commercial purposes within 1 year of the date of the expiration of the 30 day review period. 

The accuracy of the statements you make in this notice should reflect your best prediction of the 

anticipated facts regarding the chemical substance described herein. Any knowing and willful 

misrepresentation is subject to criminal penalty pursuant to 18 USC 1001. 

Signature and title of 

Authorized Official (Original 

Signature Required) 

Date 15 "]v\ 2010 

Confidential 

D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 2 

11111111111111111111111111111111 11111111111 
 SANITIZED SUBMISSION 

PMN2010P3 PMN Page 3 m::l:~.!.'.I~I;:(.]:~, 

SeCtiorA ~IFICATION Mark (X) theL I' box nextto any ~"h~o...I;')n you claim as "VllIlVCIIlIa, 

1a. Person Submittin'~ Notice (in J.S.l Cv, 'VC, '''''' 

Name of Authorized Official (first) David (last) Hay 

Position Ronlll:>tory Compliance Director 

Company Huntsman CorporClllur 

Mailing Address (number & street) 8600 Gosling Road 

D

City The Woodlands I State TX I Postal Code 77381 

email david hay@huntsman.com 

b Agent (if Applicable) Gv,",vc,"ia, 

Name of Authorized Official (first) (last) 

Position 

Company 

Mailing Address (number & street) D

City I State I Postal Code 

e-mail ~~~I~d'~'~~ea code) 

C, Joint Submmer (if ann1il'"!lIhle: CU"IIU""lI'" 

If you are submitting this notice as part of a joint submission, mark (X) I [ ] 

Name of Authorized Official (first) (last) 

Position 

Company D 

Mailing Address (number & street) 

City I State I Postal Code 

e-mail Telephone 

(include area code) 

2 Technical Contact (in U.S.) L;orlllu"ntiai 

Name of Authorized Official (first) David (last) Hay 

Position Regulatory Compliance Director 

Company Huntsman Corporation 

Mailing Address (number & street) 8600 Gosling Road D

City The Woodlands I State TX I Postal Code 77381 

e-mail david hay@huntsman.com ~~~~~~~~~ea code) 281-719-3026 

If you have had a prenotice communication (PC) concerning 5608C Mark (X) if none GU,",uc,"ial 

3. this notice and EPA assigned a PC Number to the notice, 

enter the number. D D

If you previously submitted an exemption application for the Mark (X) if none Confiu"llua, chemical substance covered by this notice, enter the 

4. exemption number assigned by EPA. If you previously 

submitted 

~~~;nnorl by 

a PMN 

EPA (Le. 

for this substance 

lor i 

enter the PMN number [Xl D

If you have submitted a notice of Bona fide intent to Mark (X) if none ConfiU""lI'" 

5. manufacture or import for the chemical substance covered 

by this notice, enter the notice number assigned by EPA. [Xl D

6. Type of Notice . Mark (X) 

Manufacture Only [X] Import Only D 1. D D 2. D 3. Both 

Binding Option Binding Option 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 3 

SANITIZED SUBMISSION 

(for either Item 1 or 2), mark (X) the box at the right. Identify 

sheet. 

1. Class 1 or 2 chemical substances (for definitions of class 1 and class 

2 substances, see the Instructions Manual) 

a. Class of substance - Mark 

Class 1 

o 

Class 2 

o 

o 

CBI 

o 

b. 	 Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar 

substances. 

Preferred Name 

For Class 

must be 

1 substances 

which 

a CA 

ever 

Index 

is 

Name 

a . 

must be 

based 

provided. 

on current 

For Class 

CA index 

2 substances 

nomenclature 

either 

rules 

a CA 

and 

Index 

N''''''''·nlir,n,,\ 

Name or CA o

Method 1 (CAS Inventory Expert Service - a copy of the 

Identification report obtained from the CAS Inventory Expert 

Enter Attachment filename for Part I, Section B, 1. c. 

d. 

e. 

Enter Attachment filename for Part I, Section B, 1. e. 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 4 

11111111111111111 SANITIZED SUBMISSION 

PMN2010P4A PMN Page 4a 

For a class 2 substance - (1) List the immediate precursor substances with their respective CAS Registry Numbers. (2) Describe 

the nature of the reaction or process. (3) Indicate the range of composition and the typical composition (where appropriate). Confidential 

e. (1) List the immediate precursor substance names with their respective CAS Registry Numbers. D 

Enter Attachment filename for Part I. Section B. 1. e. (1) I [ ] e. (2) Describe the nature of the reaction or process. D 

Enter Attachment filename for Part I. Section 8. 1. e. (2) I [ ] e. (3) Indicate the range of composition and the typical composition (where appropriate). D 

Enter Attachment filename for Part I. Section B. 1. e. (3) I [ ] 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 5 
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PMN2010P5 PMN P age 5 

Part I -- GENERAL INFORMATION - Continued 

Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 

2. Polymers (For a definition of polymer, see the Instructions Manual.) 

a. Indicate the number-average weight of the lowest molecular weight composition of the polymer you intend to manufacture. 

Indicate maximum weight percent of low molecular weight species (not including residual monomers, reactants, or solvents) 

below 500 and below 1,000 absolute molecular weight of that composition. 

Confidential 

IX] 

Describe the methods of measurement or the basis for your estimates: 

GPC D I Other (Specify Below) D I 

Specify Other: 

(i) lowest number average molecular 

weight: 

(ii) maximum weight % below 500 molecular 

weight: 

(iii) maximum weight % below 1000 molecular 

weight: 

XXX XXX XXX 

Enter Attachment filename for Part I, Section B, 2. a. I D 

b. You must make separate confidentiality claims for monomer or other reactant identity, composition information, and residual information. Mark 

(X) the "Confidential" box next to any item you claim as confidential 

(1 ) - Provide the specific chemical name and CAS Registry Number (if a number exists) of each monomer or other reactant used in the 

manufacture of the polymer. 

(2) - Mark (X) this column if entry in column (1) is confidential. 

(3) - Indicate the typical weight percent of each monomer or other reactant in the polymer. 

(4) - Choose "yes" from drop down menu if you want a monomer or other reactant used at two weight percent or less to be listed as part of 

the polymer description on the TSCA Chemical Substance Inventory. 

(5) - Mark (X) this column if entries in columns (3) and (4) are confidential. 

(6) - Indicate the maximum weight percent of each monomer or other reactant that may be present as a residual in the polymer as 

manufactured for commercial purposes. 

(7) - Mark (X) this column if entry in column (6) is confidential. 

Monomer or other reactant specific chemical name 

(1) CBI 

(2) 

Typical 

composition 

(3) 

Include in 

identity 

(4) 

CBI 

(5) 

Max 

residual 

(6) 

CBI 

(7) 

Poly[oxy(methyl-1,2-ethanediyl)], .alpha. ,.alpha. '_[1 ,4-cyclohexanediylbis(methylene)] 

bis[.omega.-hydroxyXXX X XXX X 

CAS Registry Number (1) 1214710-36-8 

Ammonia XXX X XXX X 

CAS Registry Number (1) 17664-41-7 

Raney Nickel (Catalyst) XXX X XXX X 

CAS Registry Number (1) 17440-02-0 

CAS Registry Number (1) 1 

CAS Registry Number (1) 1 

Mark (X) this box if the data continues on the next page. D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 6 
111I1111 

PMN2010P5A 

I11I111I11111 	 SANITIZED SUBMISSION 

PMN Page 5a c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this notice eBI (check one). 

Method 1 (CAS Inventory Expert Service 150681-1 a copy of the identification report obtained IES Order Method 2 

from CAS Inventory Expert Service must be Number (other source) o

submitted as an attachment to this notice) 

Enter Attachment filename for Part I, Section B, 2. c. 1220986-58-2.pdf 	 [ ] 

d. The currently correct Chemical Abstracts (CA) name for the polymer that is consistent with TSCA Inventory listings for similar 

polymers. o 

Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha. '-[1 ,4-cyclohexanediylbis(methylene )]bis[ .omega .-(2-aminomethylethoxy)­

CAS Registry Number (if a number already exists for the substance) 1220986-58-2 

e. 	 Provide a correct representative or partial chemical structure diagram, as complete as can be known, if one can be reasonably 

ascertained. o 

See Attachment 003 (Subst 1 Structure. pdf) 

111111111111111111111111111111111111111111111111111111111111111111111111II1 

5 1 100 0 0 0 4 52! S 

Enter Attachment filename for Part I, Section B, 2. e. I Subst 1 Structure.pdf o 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 7 
SANITIZED SUBMISSION 1111111111111111111111111111111111111 11111111 


PMN2010P6 PMN P age 6 

Part I -- GENERAL INFORMATION -- Continued 

Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 

3. Impurities 

(a) - Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial 

purpose. Provide the CAS Registry Number if available. If there are unidentified impurities, enter "unidentified." 

(b) - Estimate the maximum weight % of each impurity. If there are unidentified impurities, estimate Iheir total weight %. 

CAS Registry Maximum Confi- Impurity (a) Number Percent % dential (a) (b) 

Mark (X) this box if the data continues on the next page. D 

Enter Attachment filename for Part I, Section B, 3. I D 

4. Synonyms - Enter any chemical synonyms for the new chemical identified in subsection 1 or 2. 

D 

Enter Attachment filename for Part I, Section B, 4. I D 

5. Trade identification - List trade names for the new chemical substance identified in subsection 1 or 2. 

XTJ-684 

Jeffamine RFD-270 D 

Enter Attachment filename for Part I, Section B, 5. I D 

6. Generic chemical name - If you claim chemical identify as confidential, you must provide a generic name for your substance that reveals the 

specific chemical identity of the new chemical substance to the maximum extent possible. Refer to the TSCA Chemical 

Substance Inventory, 1985 Edition, Appendix B for guidance on developing generic names. 

Enter Attachment filename for Part I, Section B, 6. I 

7. Byproducts - Describe any byproducts resulting from the manufacture, processing, use, or disposal of the new chemical substance. Provide the 

CAS Registry Number if available. 

Byproduct (1) CAS Registry Number Confi­

(2)' dential 

1,4-Cyclohexanedimethanamine 2549-93-1 

3-Azabicyclo[3.2.2]nonane 283-24-9 

Water 7732-18-5 

Mark (X) this box if the data continues on the next page. D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 8 

111111111111I11111111111111~11111111111~111111111 SANITIZED SUBMISSION 

Identify D 

Class 1 or 2 chemical substances (for definitions of class 1 and class Class 1 	 Class 2 CBI 2 substances, see the Instructions Manual) 

a. 	 Class of substance - Mark D 	 D D

b. 	 Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar 

substances. 

Preferred Name 

For Class 1 substances 

which 

a CA 

ever 

Index 

is 

Name must be 

based 

provided. 

on current 

For Class 

CA index 

2 substances 

nomenclature 

either 

rules 

a CA 

and 

Index Name or CA D

d. 

e. 

Enter Attachment filename for Part I, Section B, 1. e. 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 9 

1111111111111111111111111111111111111111111111111111111 SANITIZED SUBMISSION 

PMN2010P4AX1 PMN Page4a 

For a class 2 substance (1) List the immediate precursor substances with their respective CAS Registry Numbers. (2) Describe 

the nature of the reaction or process. (3) Indicate the range of composition and the typical composition (where appropriate). Confidential 

e. (1) List the immediate precursor substance names with their respective CAS Registry Numbers. D 

Enter Attachment filename for Part I, Section B. 1. e. (1) I [ ] e. (2) Describe the nature of the reaction or process. D 

Enter Attachment filename for Part I, Section B, 1. e. (2) I D e. (3) Indicate the range of composition and the typical composition (where appropriate). D 

Enter Attachment filename for Part I, Section B, 1. e. (3) D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 10 
~11~11111111111111111111~ SANITIZED SUBMISSION 

PMN2010P5Xl PMN Page 5 

Replaces previous editions of EPA Form 7710-25 


I Part I -- GENERAL INFORMATION - Continued 

Section B .- CHEMICAL IDENTITY INFORMATION .- Continued 

: 2. Polymers {For a definition of polymer, see the Instructions Manual.} 

a:-Tridicate the number-average weight of the lowest molecular weight composition of the polymer you intend to manufacture. 

I 

Indicate maximum weight percent of low molecular weight species (not including residual monomers, reactants, or solvents) 

below 500 and below 1,000 absolute molecular weight of that composition. 

Describe the methods of measurement or the basis for your estimates: 

GPC D I Other (Specify Below) D I 

: Specify Other: 

I 

Confidential 

I 

(i) lowest number average molecular 

weight: 

(ii) maximum weight % below 500 molecular 

weight: 

(iii) maximum weight % below 1000 molecular 

weight: 

: XXX XXX xxx 

Enter Attachment filename for Part I, Section B. 2, a, I [ ] 

b. You must make separate confidentiality claims for monomer or other reactant identity, composition information, and residual information. Mark 

(X) the "Confidential" box next to any item you claim as confidential 

(1) - Provide the specific chemical name and CAS Registry Number (if a number exists) of each monomer or other reactant used in the 

manufacture of the polymer. 

(2) Mark (X) this column if entry in column (1) is confidential. 

(3) Indicate the typical weight percent of each monomer or other reactant in the polymer. 

(4) - Choose "yes" from drop down menu if you want a monomer or other reactant used at two weight percent or less to be listed as part of 

the polymer description on the TSCA Chemical Substance Inventory. 

(5) - Mark (X) this column if entries in columns (3) and (4) are confidential. 

(6) - Indicate the maximum weight percent of each monomer or other reactant that may be present as a residual in the polymer as 

manufactured for commercial purposes. 

(7) - Mark (X) this column if entry in column (6) is confidential. 

Monomer or other reactant specific chemical name 

(1) 

Poly[oxy(methyl-l ,2-ethanediyl)], ,alpha.,.alpha.'-(2,2-dimethyl-l ,3-propanediyl) 

bis[.omega.-hydroxyCAS Registry Number (1) 152479-58-0 

i Ammonia 

CAS Registry Number (1) 17664-41-7 

Raney Nickel (Catalyst) 

CAS Registry Number (1) 17440-02-0 

CAS Registry Number (1) I 

CAS Registry Number (1) I 

Mark (X) this box if the data continues on the next page. 

EPA FORM 7710-25 (Rev. 6-09) 

Typical Include in 

CBI composition identity CBI 

(2) (3) (4) (5) 

XXX X 

I 

! XXX X 

XXX I X 

I 

I 

I 

Max 

residual CBI 

(6) (7) 

XXX X 

xxx X 

XXX X 

I 

L J 

Page 11 

111I1111111111 

PMN201 OP5AX1 

11111111111111 SANITIZED SUBMISSION 

PMNPage 5a 

I c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this notice 

: (check one). eBI 

Method 1 (CAS Inventory Expert Service 

- a copy of the identification report obtained [X] from CAS Inventory Expert Service must be 

submitted as an attachment to this notice) 

IES Order 

Number 

150681-2 I Method 2 D I 

(other source) 

Enter Attachment filename for Part I, Section B, 2. c. 1220986-59-3.pdf [ ] 

d. The currenUy correct Chemical Abstracts (CA) name for the polymer that is consistent with TSCA Inventory listings for similar 

polvmers. D 

Poly[oxy(methyl-1,2-ethanediyl)J. 

.alpha., .alpha.' -(2,2-dimethyl-1 ,3-propanediyl)bis[.omega. -(2-aminomethylethoxy)­

CAS Registry Number (if a number already exists for the substance) 11220986-59-3 1 

e. Provide a correct representative or partial chemical structure diagram, as complete as can be known, if one can be reasonably 

ascertained. 

D 

See Attachment 004 (Subs! 2 Structure. pdf) 

Enter Attachment filename for Part I, Section B, 2. e. I Subst 2 Structure.pdf D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 12 P10 453 
SANITIZED SUBMISSION 111111111111111111111111111111 

PMN2010P6X1 PMN P age 6 

Part I -- GENERAL INFORMATION -- Continued 

Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 

3. Impurities 

(a) - Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial 

purpose. Provide the CAS Registry Number if available. If there are unidentified impurities, enter "unidentified." 

(b) - Estimate the maximum weight % of each impurity. If there are unidentified impurities, estimate their total weiQht %. 

Impurity (a) 

CAS Registry 

Number 

(a) 

Maximum 

Percent % 

(b) 

Confidential 

Mark (X) this box if the data continues on the next page. D 

Enter Attachment filename for Part I, Section B, 3. I D 

4. Synonyms - Enter any chemical synonyms for the new chemical identified in subsection 1 or 2. 

D 

Enter Attachment filename for Part I, Section B, 4. I D 

5. Trade identification - List trade names for the new chemical substance identified in subsection 1 or 2. 

XTJ-678 

Jeffamine 0-198 D 

Enter Attachment filename for Part I, Section B, 5. I D 

6. Generic chemical name - If you claim chemical identify as confidential, you must provide a generic name for your substance that reveals the 

specific chemical identity of the new chemical substance to the maximum extent possible. Refer to the TSCA Chemical 

Substance Inventory, 1985 Edition, Appendix B for guidance on developing generic names. 

Enter Attachment filename for Part I, Section B, 6. I 

7. Byproducts - Describe any byproducts resulting from the manufacture, processing, use, or disposal of the new chemical substance. Provide the 

CAS Registry Number if available. 

Byproduct (1) CAS Registry Number 

(2) 

Confidential 

2-Propanamine 75-31-0 

3,6,6-trimethyl homomorpholine 

1 ,3-Propanediamine, 2,2-dimethyl­ 7328-91-8 

Water 7732-18-5 

Mark (X) this box if the data continues on the next page. D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 13 
XXX 

II~II~IIIIIIIIIIIIIIIIII ~III III1 SANITIZED SUBMISSION 

PMN2010P7 	 PMNPage 7 

Part I -- GENERAL INFORMATION -- Continued 


Section C -- PRODUCTION, IMPORT, AND USE INFORMATION: 


The information on this page refers to consolidated chemical number(s): X] 2 0 3 5 06 


Mark (X) the ·Confidential" box next to any item you claim as confidential. 


1. 	 Production volume - Estimate the maximum production volume during the first 12 months of production. Also estimate the maximum production 

volume for any consecutive 12-month period during the first three years of production. Estimates should be on 100% new chemical substance basis. 

For a Low Volume Exemption application. if you choose to have your notice reviewed at a lower production volume than 10,000 kg/yr, specify the 

volume and mark (x) in the binding box. If granted, you are bound to this volume. 

imum first 12-month production (kg/yr) Maximum 12-month production (kg/yr) Binding Option Confidential (100% new chemical substance basis) (100% new chemical substance basis) Mark (X) 

XXX [XJ 0 

Enter Attachment filename for Part I, Section C, 1. I CBI 0

2. 	 Use Information - You must make separate confidentiality claims for the description of the category of use, the percent of production volume devoted 

to each category, the formulation of the new substance, and other use information. Mark (X) the "Confidential" Box next to any item you claim as 

confidential. 

a. 	 (1) --Describe each intended category of use of the new chemical substance by function and application. 

(2) --Mark (X) this column if entry column (1) is confidential business information (CBI). 

(3) --Indicate your willingness to have the information provided in column (1) binding. 


(4 ) --Estimate the percent of total production for the first three Years devoted to each cate g0 ry of use. 


(5) --Mark (X) this column if entry In co umn (4) is can fid I entia . I b . f uSlness In ormation (CBI) 

(6) --Estimate the percent of the new substance as formulated in mixtures, suspensions, emulsions, solutions, or gels as manufactured for 

commercial purposes at sites under your control associated with each category of use. 

(7) --Mark (X) this column if entry in column (6) is confidential business information (CBI). 

(8) --Indicate % of product volume expected for the listed "use" sectors. Mark more than one box if appropriate. Mark (X) to indicate your 

willingness to have the use type provided in (8) binding. 

(9) -Mark (X) this column if entry(ies)in column (8) is (are)confidential business information (CBI). 

Category of use (1) Binding Prod %in % of substance expected per use 

CBI Option uction Form- CBI (8) CBI (by function and application i.e. a dispersive dye for 

finishing polyester fibers) Mark (X) % ulation Site-­ Con· Com- Binding 

(2) {3} (4) (6) (7) limIted sume mercial Option (9) 

Epoxy Curing Agent 100 95 0 0 100 0 

• If you have identified a "consumer" use, please provide on a continuation sheet a detailed description of the use(s) of this chemical substance in 

consumer products. In addition include estimates of the concentration of the new chemical substance as expected in consumer products and describe 

the chemical reactions by which this substance loses its identity in the consumer product. 

Mark (X) this box if the data continues on the next page. [ ] 

b. Generic use If you claim any category of use description in subsection 2a as confidential, enter a generic description of that category. 

deSCription Read the Instruction Manual for examples of generic use descriptions. 

Enter Attachment filename for Part I, Section C, 2. b. I CBI 0 

3. Hazard Information •• Include in the notice a copy of reasonable facsimile of any hazard warning statement, label. material safety 

data sheet. or other information which will be provided to any person who is reasonably likely to be exposed to this substance Binding Option 

regarding protective equipment or practices for the safe handing. transport. use. or disposal of the new substance. List in part III Mark (X) 

hazard information you include. 

Mark (X) this box if you attach hazard information. [R] 0 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 14 
11111111 SANITIZED SUBMISSION 

PMN2010P8 PMNPage 8 IIIIIIIIIII~IIIIIIIII Part 11-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE 

I Mark (X) the "Confidential" box next to i Section A - INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER any item you claim as confidential 


The information on pages 8 and 8a refer to consolidated chemical number(s): [XJ 1 [XJ2 
 J3 l J4 05 06 

Complete section A for each type of manufacture, processing, or use operation involving the new chemical substance at industrial sites 

you control. Importers do not have to complete this section for operations outside the U.S.; however, you may still have reporting

requirements . If there are further Industrial ...... processing or use operations after Import. You must describe these operations. See 

instructions manual 

I 

1. Operation description 

a. Identity -­ Enter the identity of the site at which the operation will occur. 

Name Huntsman Corporation Conroe Site 

Site address (number and 

street) 5451 Jefferson Chemical Road 

City Conroe County Montgomery 

State TX ZIP code 77306 

If the same operation will occur at more than one site, enter the number of sites. Identify the additional 

sites on a continuation sheet, and if any of the sites have significantly different production rates or 1 

operations, include all the information requested in this section for those sites as attachments. ~ 

Mark (X) this box if the data continues on the next page. 0 

b. Type-­

Mark (X) Manufacturing [&] Processing 0 Use 0 c. Amount and Duration Complete 1 or 2 as appropriate 

Maximum kg/batch 

I (100% new chemical Hours/batch Batches/year 

1. Batch substance) 

Maximum kg/day Hours/day Days/year 

2. Continuous (100% new chemical substance) 

XXX XXX XXX 

Mark (X) to indicate your willingness to 

d. Process description have your process description binding. 0 ~ 

Confidential 

0 

0 

0 

Confidential 

0 

[&] 

(1) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specify- e.g. 5 gallon 

pails, 55 gallon drum, rail car, tank trUCk, etc.). 

(2) Provide the identity, the approximate weight (by kg/day or kglbatch on a 100% new chemical substance basis), and entry point of all starting 

materials and feedstocks (inCluding reactants, solvents, catalysts, etc.), and of all products, recycle streams, and wastes. Include cleaning 

chemicals (note frequency if not used daily or per batch.). 

(3) Identify by number the pOints of release, including small or intermittent releases, to the environment of the new chemical substance. If 

releasing to two media at the same step, assign a second release number for the second medium. 

[&] 

XXX 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 15 
11111111111111111111111111111111111111111111111111111111111 SANITIZED SUBMISSION 

PMN2010P8A PMNPage 8 a 

Confidential 

Diagram of the major unit operation steps. 0 

See Attachment 007 (SANITIZED PMN BLOCK FLOW DIAGRAM ,doc) 

Enter Attachment filename for Part II, Section A. 1. d, I SANITIZED PMN BLOCK FLOW DIAGRAM.doc [ J 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Fonn 7710-25 


Page 16 

11111 11111111111111111111111 	 SANITIZED SUBMISSION 

PMN2010P9 	 PMN Page 9 

Part II·· HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE .. Continued 

Section A .. INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER .• Continued 

The information on pages 9 and 9a refer to consolidated chemical number(s): [XJ 1 [X 2 [ J3 [ J4 [ 5 [ J6 

2. Occupational Exposure -- You must make separate confidentiality claims for the description of worker activity, physical form of the new chemical 

substance, number of workers exposed, and duration of activity. Mark (X) the ·Confidential" box next to any item you claim as confidential. 

(1) -­ Describe the activities (Le. bag dumping, tote filling, unloading drums, sampling, cleaning, etc.) in which workers may be exposed to the 

substance. 

(2) --	 Mark (X) this column if entry in column (1) is confidential business information (CSI). 

(3) --	 Describe any protective equipment and engineering controls used to protect workers. 

(4) and (6) Indicate your willingness to have the information provided in column (3) or (5) binding. 

(5) 	-- Indicate the physical formes) of the new chemical substance (e.g., solid: crystal, granule, powder, or dust) and % new chemical substance (if 

part of a mixture) at the time of exposure. 

(7) Mark (X) this column if entries in columns (3) and (5) are confidential business information (CSI). 

(8) 	 Estimate the maximum number of workers involved in each activity for all sites combined. 

(9) --	 Mark (X) this column if entry in column (8) is confidential business information (CSI). 

(10) and (11) -- Estimate the maximum duration of the activity for any worker in hours per day and days per year. 

(12) -- Mark (X) this column if entries in columns (10) and (11) are confidential business information (CSI). 	 I 

Worker activity Protective Equipment! Binding Physical 

form(s) (i.e., bag dumping, filling CBI Option &%new drums) Engineering Controls Mark (X) substance (1) (2) (3) (4) (S) 

Binding #of 

Option CBI Workers CBI 

Mark (X) Exposed 

(6) (7) (8) (9) 

Maximum Duration 

HrslDay Days/Yr 

(10) (11) 

I 

CBI 

i 

(12) 

QC Sampling XXX XXX X XXX X XXX XXX X 

Shipping QC Sampling XXX XXX X XXX X XXX XXX X 

Loading tank wagons XXX XXX X XXX X XXX XXX X 

Water waste periodically XXX XXX 

sent to the on-site 

treatment ponds 

X XXX X XXX XXX X 

I 

, 

I 

Mark (X) this box if the data continues on the next page. 

Enter Attachment filename for Part II, Section A on the bottom of page 9a. 

I I 

D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 17 
1111111111111111111111 111I SANITIZED SUBMISSION 

PMN2010P9A PMNPage 9a 

3. Environmental Release and Disposal-- You must make separate confidentiality claims for the release number and the amount of the new chemical 

substance released and other release and disposal information, Mark (X) the "Confidential" box next to each item you claim as confidential. 

(1) -­ Enter the number of each release point identified in the process description, part II, section A, subsection 1d(3). 

(2) -­ Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch), 

(3) -­ Mark (X) this column if entries in columns (1) and (2) are confidential business information (CSI), 

(4) -­ Identify the media (stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration, POTW, or 

other (specify» to which the new substance will be released from that release point. 

(5) a, Describe control technology, if any, and control efficiency that will be used to limit the release of the new substance to the environment. 

For releases disposed of on land, characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste. 

On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to 

secondary or tertiary on-site treatment. b, Estimate the amount released to the environment after control technology (in kg/day). 

(6) •• Mark (X) this column if entries in columns (4) and (5) are confidential business information (CSI). 

(7) -­ Identify the destinalion(s) of releases to water, Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct 

discharges or NPDES numbers of the POTW (Publicly Owned Treatment Works). Mark (X) if the POTW name or NPDES # is confidential 

business information (CSI), 

Release Amount of New Medium of release Control technology and efficiency (you may wish to 

Number Substance Released CBI e.g. Stack air optionally attach efficiency data) CBI i 

Binding 

I i 

(1) (2a) (2b) (3) (4) (58) Mark (5b) (6) 

(X) 

1 0 0.1 kg / Other: On-site waste water tank Waste water tank 0.01 g / 

campaign campaign 

2 0 0.1 kg / Other: On-site waste water tank waste water tank 0.01 g / 

campaign campaign 

I 

3 0 Hg/ Other: On-site waste water tank Waste water tank 0.1 g / 

campaign campaign 

4 0 4500 kg / Other: On-site waste water tank Waste water tank, then on-site 0.1 kg / 

campaign treatment ponds for microbial day 

digestion 

I 

I 

Mark (X) this box if the data continues on the next page. D 

(7) Mark (X) the destination(s' of releases to water. NPDES# CBI 

D POTW--provide D I i name(s) I 

D Navigable waterway- i 

- provide name(s) D i 

D Other-Specify D 

Enter Attachment filename for Part II, Section A. I D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 18 

PMN2010P10 

11111111111111111111111111111111 SANITIZED SUBMISSION 

PMN Page 10 

Part 11-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued 

Section B -- INDUSTRIAL SITES CONTROLLED BY OTHERS 

The information on pages 10 and 10a refer to consolidated chemical number(s): [X] 1 [X] 2 D 3 [J 4 [J 5 D 6 

Complete section B for typical processing or use operations involving the new chemical substance at sites you do not control. Importers do not have to 

complete this section for operations outside the U.S.; however, you must report any processing or use activities after import. See the Instructions Manual. 

Complete a separate section B for each type ofprocessing, or use operation involving the new chemical substance. If the same operation is performed at 

more than one site describe the typical operation common to Ihese sites. Identify additional sites on a continuation sheet. 

1(a). Operation Description -- To claim infonnalion in this section as confidential, bracket (e.g. {)) the specific information that you claim as 

confidential. 

(1) -­ Diagram the major unit operation steps and chemical conversions, including interim storage and transport containers (specify - e.g. 5 gallon 

pailS, 55 gallon drums, rail cars, tank trucks, etc). On the diagram, identify by letter and briefly describe each worker activity. 

(2) -­ Either in the diagram or in the text field 1(b) below, provide the identity, the approximate weight (by kglday or kglbatch, on an 100% new 

chemical substance basis), and entry point of all feedstocks (including reactants, solvents and catalysts, etc) and all products, recycle 

streams, and wastes. Include cleaning chemicals (note frequency if not used daily or per batch). 

(3) -­ Either in the diagram or in the text field 1(b) below, identify by number the pOints of release, including small or intermittent releases, to the 

environment of the new chemical substance. 

(4) -­ Please enter the # of sites (remember to identify the locations of these sites on a continuation sheet): 

I 

• 

! 

. 

I Number of Sites I IConfidential [Z] 

See Attachment 008 (PMN BLOCK FLOW DIAGRAM 2.doc) 

1(b). (Optional) This space is for a text description to clarify the diagram above. Confidential u 

The PMN substance is a curing agent which will be blended with an epoxy resin system and injected into a mold containing fiberglass. Heat is applied 

to complete the curing. The finished article will be a wind turbine blade for use in wind fanns that generate electricity. 

The PMN substance will be supplied to the customer and unloaded from 4000-gal. tank wagons (Activity A, Release 1) into a blending vessel where 

other components are added under agitation. The material containing the PMN substance is then pumped (Activity B) into the closed mold along with 

the epoxy resin using a "vacuum bagging" process. The PMN substance is consumed in this process by reacting with the epoxy resin. The mold is 

opened and the finished wind blade is removed (Activity C). The fiberglass provides a substrate for the cured epoxy to adhere to thus giving the 

finished wind blade extra strength. 

The empty tank wagons of the PMN substance are rinsed with water (Activity D, Release 2) which is collected in a waste water tank and periodically 

sent to treatment ponds where it is decomposed by microbes. 

Enter Attachment filename for Part II, Section B on the bottom of page 10a. I PMN BLOCK FLOW DIAGRAM 2.doc D 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 19 
xxx 

1111111111111111111111 11111111111111 SANITIZED SUBMISSION 

PMN2010P10-1 

Continuation Sheet 

ID IP10SB1(a)(4)1 I Field I Part II, Section B, 1 (a)(4). Operation Site Locations 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 20 

IIIII~IIIIIIIIIIIIIIIIIIIIIIIII SANITIZED SUBMISSION 

PMN2010P10A PMN P age 10a 

2. Worker ExposurelEnvironmental Release 

(1) -­ From the diagram above. provide the letter for each worker activity. Complete 2-8 for each worker activity described. 

(2) -­ Estimate the number of workers exposed for all sites combined. 

(4) -­ Estimate the typical duration of exposure per worker in (a) hours per day and (b) days per year. 

(6) Describe physical form of exposure and % new chemical substance (if in mixture). and any protective equipment and engineering controls. if 

any, used to protect workers. 

(7) -­ Estimate the percent of the new substance as formulated when packaged or used as a final product. 

(9) -­ From the process diagram above. enter the number of each release point. Complete 9-13 for each release point identified. 

(10) -­ Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology to the environment (in 

kg/day or kglbatch). 

(12) -­ Describe media of release i.e. stack air. fugitive air (optional-see Instructions Manual). sur1ace water, on-site or off-site land or incineration. I POTW. or other (specify) and control technology. if any. that will be used to limit the release of the new substance to the environment. 

(14) Identify byproducts which may result from the operation. 

(3), (5), (8). (11), (13) and (15) -- Mark (X) this column if any of the proceeding entries are confidential business information (CBI). 

Letter #of Duration of Protective EquipJEngineering ControlslPhysical "10 new "loin of Workers CBI CBI CBI 

Activity Exposed Exposure Form substance Formulation 

(1) (2) (3) (4a) (4b) (5) (6) (6) (7) (8) 

A 1 0.5 20 Hard hat. face shield, safety glasses, rubber gloves. 95 95 

Nomex overalls I 

D 1 .5 20 Hard hat, face shield. safety glasses, rubber gloves. 1 1 

I Nomex overalls 

[ 

I 

i 

I 

Release Amount of New Substance Released CBI Media of Release & Control Technology CBI I Number 

(9) (10a) I (10b) (11) (12) (13) 

1 0 I 0.01 kg / day Waste Water Tank 

2 0 1 kg I day Waste water tank 

i 

i I 

I 

I 

I 

I I 

Mark (X) this box if the data continues on the next page. [ ] 

(14) Byproducts: I (15) CBI 0 

Enter Attachment filename for Part II, Section B. [ ] 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 


Page 21 

1111111111111111111111111111111111111111111111111111111111II SANITIZED SUBMISSION 

PMN2010P11 PMN Page 11 

OPTIONAL POLLUTION PREVENTION INFORMATION 

To claim information in the following section as confidential, bracket (e.g. 0> the specific information that you claim as confidential. 

In this section you may provide information not reported elsewhere in this form regarding your efforts to reduce or minimize potential risks 

associated with activities surrounding manufacturing, processing, use and disposal of the PMN substance. Please include new information 

pertinent to pollution prevention, including source reduction, recycling activities and safer processes or products available due to the new chemical 

substance. Source reduction includes the reduction in the amount or toxicity of chemical wastes by technological modification, process and 

procedure modification, product reformulation, and/or raw materials substitution. Recycling refers to the reclamation of useful chemical components 

from wastes that would otherwise be treated or released as air emiSSions or water discharges, or land disposal. Quantitative or qualitative 

descriptions of pollution prevention, source reduction and recycling should emphasize potential risk reduction in addition to compliance with existing 

regulatory requirements. The EPA is interested in the information to assess overall net reductions in toxicity or environmental releases and 

exposures, not the shifting of risks to other media (e.g., air to water) or nonenvironmental areas (e.g., occupational or consumer exposure). To the 

extent known, information about the technology being replaced will assist EPA in its relative risk determination. In addition, information on the 

relative cost or performance characteristics of the PMN substance to potential alternatives may be provided. 

Describe the expected net benefits, such as 

(1) an overall reduction in risk to human health or the environment; 

(2) a reduction in the generation of waste materials through recycling, source reduction or other means; 

(3) a reduction in the use of hazardous starting materials, reagents, or feedstocks; 

(4) a reduction in potential toxicity. human exposure and/or environmental release; or 

(5) the extent to which the new chemical substance may be a substitute for an existing substance that poses a greater overall risk to human 

health or the environment. 

Information provided in this section will be taken into consideration during the review of this substance. See PMN Instructions Manual 

and Pollution Prevention Guidance manual for guidance and examples. 

The PMN substance will be used to make wind blades for electricity generation. This will offset the need for electricity generated from the buming 

of fossil fuels thereby aVOiding all of the environmental problems associated with this method. This will reduce potential toxicity to human health 

and the environment. 

Enter Attachment filename for Pollution Prevention Page 11. I [ ] 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 22 
111111111111111111111111111111 SANITIZED SUBMISSION

PMN2010P12 PMNPage 12 

Part III -- UST OF ATTACHMENTS 

Attach continuation sheets for sections of the form, test data and other data (including physical/chemical properties and 

structure/activity information), and optional information after this page. Clearly identify the attachment and the section of the form 

to which it relates, if appropriate. Number consecutively the pages of any paper attachments. In the Number of Pages column 

below, enter the inclusive page numbers of each attachment for paper submissions or enter the total number of pages for each 

attachment for electronic submissions. Electronic attachments can be identified by filename. 

Mark (X) the "Confidential" box next to any attachment name or filename you claim as confidential. Read the Instructions Manual 

for guidance on how to claim any information in an attachment as confidential. You must include with the sanitized copy of the 

notice form a sanitized version of any attachment in which you claim information as confidential. 

# Attachment Name Attachment Filename Number 

of Pages 

Associated 

PMN Section 

Number 

CBI 

001 CAS IES Report 1220986-58-2 1220986-58-2.pdf 1 PU, Sec.B, 2c. 

002 CAS IES Report 1220986-59-3 1220986-59-3.pdf 1 PLI, Sec.B, 2c. (Chem 2) 

003 Substance 1 Structure Subst 1 Structure.pdf 1 Pt.I, Sec.B, 2e. 

004 Substance 2 Structure Subst 2 Structure.pdf 1 Pt.!, Sec.B, 2e. (Chem 2) 

005 MSDS for Subs!. 1 Jeffamine RFD 270 Subst 1 MSDS.pdf 7 

006 MSDS for Subs!. 2 XTJ-678 Subst 2 MSDS.pdf 7 

007 Sanitized Block Flow Diagram for PMN 

Synthesis 

SANITIZED PMN BLOCK FLOW 

DIAGRAM.doc 

1 Pt.2, Sec.A, 1d. 

008 Flow Diagram of Wind Blade Formation PMN BLOCK FLOW DIAGRAM 

2.doc 

1 Pt.2, Sec.B, 1a. 

009 Surrogate Toxicity Data Reference Surrogate Toxicity Data for 

PMN.doc 

1 

Mark (X) this box if the data continues on the next page. [ ] 

EPA FORM 7710-25 (Rev. 6-09) Replaces previous editions of EPA Form 7710-25 

Page 23 
111111111111111111111111111 1111111111111 SANITIZED SUBMISSION 

PMN2010P13 PMNPage 13 

PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET 

The Information on this page refers to chemical number(s): rAJ 1 [AJ2 [h [ ] 4 [ ]5 [ ] 6 

To assist EPA's review of physical and chemical properties data, please complete the following worksheet for data you provide and include it in the 

notice. Identify the property measured, the value of the property, the units in which the property is measured (as necessary). and whether or not the 

property is claimed as confidential. Give the attachment number (found on page 12) in column (b). The physical state of the neat substance should be 

provided. These measured properties should be for the neat (100% pure) chemical substance. Properties that are measured for mixtures or 

formulations should be so noted (% PMN substance in ->. You are not required to submit this worksheet; however, EPA strongly recommends that 

you do so, as it will simplify the review and ensure that confidential information is proper1y protected. You should submit this worksheet as a 

supplement to your submission of test data. This worksheet is not a substitute for submission of test data. 

Property 

(a) Unit I Mark X if 

Provided 

Attachment 

Number 

(b) 

Value 

(e) 

Measured 

or Estimate 

(M orE) 

CBI 

Mark (X) 

(d) 

Physical state of neat substance D (solid) I (liquid) (gas) 

X D D D 

Vapor Pressure @ 

Temperature 

xxx ·C D xxx Torr X 

Density/relative denSity D XXX g/em3 X 

Solubility 

@ Temperature 

Solvent 

·c D gil 

Solubility in Water @ 

Temperature 

XXX ·c D XXX giL X 

Melting Temperature D ·c 

Boiling / Sublimation 

temperature @ 

XXX Torr D XXX ·C X I 

Spectra D 

Dissociation constant D 

Octanol/ water partition coefficient D 

Henry's Law constant D 

Volatilization from water D 

Volatilization from soil D 

pH@ concentration xxx D xxx X 

Flammability D 

Explodability D 

Adsorption / Coefficient D 

Particle Size Distribution D 

Other - Specify D 

Page 24 
ATTACHMENT HEADER SHEET 


Attachment Number 001 

Attachment Name 


CAS IES Report 1220986-58-2 


Associated PMN Section Number 


Pt.l, Sec.B, 2c. 


Does not contain CBI 

Report Number 


X78T100714067813343 

Inventory Expert Service 


A division of the American Chemical Society Phone: 800-631-1884, 614-447-3870 

Fax: 614-447-3747 

E-mail: answers@cas.org 

Web: www.cas.orglproducts/clientl 

Substance 1 

INVENTORY EXPERT SERVICE REPORT 

rES-ORDER NUMBER: 150681-1 

REGISTRY NUMBER: 1220986-58-2 

CA INDEX NAME 

Poly[oxy(methyl-1,2-ethanediyl)l, a,a'-[l,4-cyclohexanediylbis 

(methylene)]bis[w-(2-aminornethylethoxy) 

Please print the above CA Index Name on the appropriate page of your PMN. 

o If this box is checked, CAS has made correction(s) marked in red to 

your rES order. Please make the same correction(s) to your PMN before 

submitting it to the EPA. 

CAS 2540 Olefltangy River Road P.O. Box 3343 Columbus. Ohio 43210-0334 USA 
ATIACHMENT HEADER SHEET 


Attachment Number 002 

Attachment Name 


CAS IES Report 1220986-59-3 


Associated PMN Section Number 


Pt.l, Sec.B. 2c. (Chem 2) 


Does not contain CBI 

Report Number 


X78T100714067813343 

Inventory Expert Service 


A division of the American Chemical Society Phone: 800-631-1884.614-447-3870 

Fax: 614-447-3747 

E-mail: answers@cas.org 

Web: www.cas.orglproducts/clientf 

Substance 2 

IN'JENTORY EXPERT SERVICE REPOR'1' 

IES-ORDER NUMBER: 150681-2 

REGISTRY NUMBER: 1220986-59-3 

CA INDEX NA!1E 

[oxy(rnethyl-1,2-ethanediyl)J, ula' (2,2-dirnethyl-1,3­

propanediyl)bis[ro-(2-arninomethylethoxy)­

Please print the above CA Index Name on the appropriate page of your PMN. 

If this box is checked, CAS has made correction(s) marked in red to 

your IES order. Please make the same correction(s) to your PMN before 

submitting it to the EPA. 

CAS 2540 Olentangy River Ro~d P.O. Box 3343 Columbus. Ohio 43210-0334 USA 
ATTACHMENT HEADER SHEET 


Attachment Number 003 

Attachment Name 


Substance 1 Structure 


Associated PMN Section Number 

pt.l, Sec.B, 2e. 

Does not contain CBI 

Report Number 


X78T100714067813343 

tk 4866 p, 4
 ,~pr, 29, 20 10 3:04PM 


Substance /S7)b'Jl 1 


XTJ-684 


nAJ"lQ/0il1A TUII 10-11 r T v j 0 v un;.:. '1 ("'<I') 1 r::h A n A 
ATTACHMENT HEADER SHEET 


Attachment Number 004 

Attachment Name 


Substance 2 Structure 


Associated PMN Section Number 

pt.l, Sec.B, 2e. (Chern 2) 

Does not contain CBI 

Report Number 

X78T100714067813343 
No.4866 P. 7 

Substance 2 


~NH2 

o ,'Y 

XTJ"()78 


04128/2010 HU 16:11 [TX/RX tlO 52631 tal007 
ATTACHMENT HEADER SHEET 


Attachment Number 005 

Attachment Name 


MSDS for Subst. 1 - Jeffamine RFD 270 


Associated PMN Section Number 

N/A 

Does not contain CBI 

Report Number 


X78T100714067813343 

HUNTSMAN Material Safety Data Sheet Enriching lives through innovation

11. Product and company identification 


Product name ~EFFAMINE® RFD 270 MSDS # Km061681 

,,* For Research and Development or Export Only *** 

Product use ~uring agents. 

,.,. Huntsman International LLC 

P.O. Box 4980 

The Woodlands, TX 77387 

TELEPHONE NUMBERS 

Transportation/Emergency 

CHEMTREC: (800) 424·9300 

Technical Information: (281) 719-7780 

E-MAIL: MSDS@huntsman.com 

Validation date : 512812010. 

In case of emergency 

" Spills Leaks Fire or Exposure Call Chemtrec: (800) 424-9300 

In Mexico: 01 8000021400 

In Columbia: 01 80091 6012 

12. Hazards identification 


Physical state 

Odor 

OSHAlHCS status 

GENERAL INFORMATION 

I!f'quid. 


!A"mmoniacal. 


rMiis material is considered hazardous by the OSHA Hazard Communication Standard 


(29 CFR 1910.1200). 


!'!fANGER! 


FFOR RESEARCH AND DEVELOPMENT OR EXPORT ONL Y*** 


CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF ABSORBED THROUGH SKIN 


OR IF SWALLOWED. 


r"orrosive to eyes and skin. Causes burns. May be harmful if absorbed through skin or if 


swallowed. Do not breathe vapor or mist. Do not ingest. Do not get in eyes or on skin or 


clothing. Use only with adequate ventilation. Keep container tightly closed and sealed 


until ready for use. Wash thoroughly after handling. 


!Read the entire MSDS for a more thorough evaluation of the hazards. 


3. Composition/information on ingredients 


Name CAS number % 

"'mine-terminated cycloaliphatic propoxylate 1220986-58-2 90 - 95 

512812010. Page: 1fl 
IfEFFAMINE® RFD 270 m 

/4. First aid measures 


Eye contact 

Skin contact 

Inhalation 

Ingestion 

Notes to physician 

lIJ'et medical attention immediately, Immediately flush eyes with plenty of water, 


occasionally lifting the upper and lower eyelids. Check for and remove any contact 


lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated 


promptly by a physician. 


Iret medical attention immediately. Flush contaminated skin with plenty of water. 


Remove contaminated clothing and shoes, Wash contaminated clothing thoroughly with 


water before removing it, or wear gloves, Continue to rinse for at least 10 minutes. 


Chemical burns must be treated promptly by a physician. Wash clothing before reuse. 


Clean shoes thoroughly before reuse. 


Iret medical attention immediately. Move exposed person to fresh air. If it is suspected 


that fumes are still present, the rescuer should wear an appropriate mask or self­


contained breathing apparatus. Keep person warm and at rest. If not breathing, if 


breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen 


by trained personnel. It may be dangerous to the person providing aid to give mouth-to­


mouth resuscitation. If unconscious, place in recovery position and get medical attention 


immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or 


waistband, In case of inhalation of decomposition products in a fire, symptoms may be 


delayed. The exposed person may need to be kept under medical surveillance for 48 


hours. 


rfet medical attention immediately. Wash out mouth with water, Move exposed person to 


fresh air. 00 not induce vomiting unless directed to do so by medical personnel. 


Chemical burns must be treated promptly by a physician. Never give anything by mouth 


to an unconscious person. 


Ifymptomatic and supportive therapy as needed. Following severe exposure medical 


follow-up should be monitored for at least 48 hours, 


15. Fire-fighting measures 


Flash point 

Products of combustion 

Extinguishing media 

Suitable 

Not suitable 

Special exposure hazards 

Special protective 

equipment for fire-fighters 

~osed cup: >149°C (>300,2°F) 


Ilfecomposition products may include the following materials: 


carbon dioxide 


carbon monoxide 


nitrogen oxides 


IT'se an extinguishing agent suitable for the surrounding fire. 


IifOne known. 


Iffa fire or if heated, a pressure increase will occur and the container may burst. 


promptly isolate the scene by removing all persons from the vicinity of the incident if there 


is a fire. No action shall be taken involving any personal risk or without suitable training. 


Pfre-fighters should wear appropriate protective equipment and self-contained breathing 


apparatus (SCBA) with a full face-piece operated in positive pressure mode, 


/s. Accidental release measures 

Personal precautions 

Environmental precautions 

R"o action shall be taken involving any personal risk or without suitable training. Evacuate 

surrounding areas. Keep unnecessary and unprotected personnel from entering. 00 not 

touch or walk through spilled material. 00 not breathe vapor or mist. Provide adequate 

ventilation, Wear appropriate respirator when ventilation is inadequate. Put on 

appropriate personal protective equipment (see section 8). 

lftVoid dispersal of spilled material and runoff and contact with soil, waterways, drains and 

sewers. Inform the relevant authorities if the product has caused environmental pollution 

(sewers, waterways, soil or air). 

5128/2010. Page: 211 
F1E.FFAMINE® RFD 270 

6. Accidental release measures 

Methods for cleaning up : 	imop leak if without risk. Move containers from spill area. Approach release from upwind. 

Prevent entry into sewers, water courses, basements or confined areas. Wash spillages 

into an effluent treatment plant or proceed as follows, Contain and collect spillage with 

non-combustible, absorbent material e,g. sand, earth, vermiculite or diatomaceous earth 

and place in container for disposal according to local regulations (see section 13), 

Dispose of via a licensed waste disposal contractor. Contaminated absorbent material 

may pose the same hazard as the spilled product. Note: see section 1 for emergency 

contact information and section 13 for waste disposal. 

17. Handling and storage 

Handling 

Storage 

PUt on appropriate personal protective equipment (see section 8). Eating, drinking and 

smoking should be prohibited in areas where this material is handled, stored and 

processed, Workers should wash hands and face before eating, drinking and smoking. 

Do not get in eyes or on skin or clothing, Do not breathe vapor or mist. Do not ingest. If 

during normal use the material presents a respiratory hazard, use only with adequate 

ventilation or wear appropriate respirator. Keep in the original container or an approved 

alternative made from a compatible material, kept tightly closed when not in use, Empty 

containers retain product residue and can be hazardous. Do not reuse container. 

Ifore in accordance with local regulations, Store in original container protected from 

direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials 

(see section 10) and food and drink. Keep container tightly closed and sealed until ready 

for use, Containers that have been opened must be carefully resealed and kept upright 

to prevent leakage, Do notstore in unlabeled containers. Use appropriate containment 

to avoid environmental contamination, 

~m Exposure controls/personal protection 


Consult local authorities for acceptable exposure limits. 

Preventive Measures 

Engineering controls 

Personal protection 

Eyes 

Skin 

Respiratory 

Hands 

~nditions of use, adequacy of engineering or other control measures, and actual 

exposures will dictate the need for specific protective devices at your workplace. 

Ifse local exhaust ventilation to maintain airborne concentrations below the TLV. Suitable 

respiratory equipment should be used in cases of insufficient ventilation or where 

operational procedures demand tt. For guidance on engineering control measures refer 

to publications such as the ACGIH current edition of 'Industrial Ventilation, a manual of 

Recommended Practice,' 

~fety eyewear complying with an approved standard should be used when a risk 

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or 

dusts, 

PYersonal protective equipment for the body should be selected based on the task being 

performed and the risks involved and should be approved by a specialist before handling 

this product. 

Ilfse a properly fitted, air-purifying or air-fed respirator complying with an approved 

standard if a risk assessment indicates this is necessary. Respirator selection must be 

based on known or anticipated exposure levels, the hazards of the product and the safe 

working limits of the selected respirator. 

rf,emical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary, 

5/28/2010. 	 Page: 3n 
I1EFFAMINE® RFD 270 

19. Physical and chemical properties_____________-----' 


General information 

Appearance 

Physical state ~quid. 

Color ~ear Colorless to light yellow 

Odor Jfmmoniacal. 

Odor threshold frot available. 

Important health, safety and environmental information 

pH iilfj.5 

Boiling point ~3°C (541.4°F) 

Melting point I'fot available. 


Flash point ffosed cup: >149°C (>300.2°F) 


Oxidizing properties R'ot available. 


Vapor pressure Jlf'ot available. 


Relative density "'96 


Octanollwater partition Ilf'ot available. 


coefficient 


Viscosity Mnematic (40°C (104°F)): 0.301 cm 2

/s (30.1 cSt) 


Vapor density Frot available. 


VOC content 1I'f'0t available. 

110. Stability and re_a_c_ti_v_H_y________________~ Stability and reactivity lPhe product is stable. 


Incompatibility with various lfeactive or incompatible with the following materials: oxidizing materials, metals and 


SUbstances acids. 


Hazardous polymerization IFnder normal conditions of storage and use, hazardous polymerization will not occur. 


Hazardous decomposition lJ"ecomposition products may include the following materials: 


products carbon dioxide 


carbon monoxide 


nitrogen oxides 


111 . Toxicological information 

Toxicity data 

Acute toxicity 

Product/ingredient name 

fS!milar material) 

Test 

LD50 Dermal 

LD50 Oral 

Species 

Rabbit 

Rat 

Result 

1700 mglkg 

500 to 1000 

mglkg 

Exposure 

Potential acute health effects 

Ingestion prarmful if swallowed. May cause burns to mouth, throat and stomach. 


Inhalation M'ay give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. 


Eyes !"orrosive to eyes. Causes burns. 


Skin !"orrosive to the skin. Causes burns. Harmful in contact with skin. 


Potential chronic health effects 


5/28/2010. Page:4fl 
ffEFFAMINE® RFD 270 

11 . Toxicological information 


Target organs None known. 

Carcinogenicity Fro known significant effects or critical hazards. 

Mutagenicity Ilfo known significant effects or critical hazards. 

Teratogenicity pro known significant effects or critical hazards. 

Fertility effects R'o known significant effects or critical hazards. 

Developmental effects Jfo known significant effects or critical hazards. 

12. Ecological information 


Environmental effects : 	RO known signifICant effects or critical hazards. 113. Disposal considerations --------~---------, 

Waste disposal 	 P'he generation of waste should be avoided or minimized wherever possible. Empty 


containers or liners may retain some product residues. This material and its container 


must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a 


licensed waste disposal contractor. Disposal of this product, solutions and any by­


products should at all times comply with the requirements of environmental protection 


and waste disposal legislation and any regional local authority requirements. Avoid 


dispersal of spilled material and runoff and contact with soil, waterways, drains and 


sewers. 


114 . Transport information 

Transportation Emergency Number 1-800-424-9300 (CHEMTREC). 

Regulatory UN number Proper shipping Class PG* Label Additional information 

information name 

DOT Classification 1JN2922 Ibrrosive liquid, toxic, r(6.1) Jr ". 

n.o.s. (Amineterminated 

propoxylate) 

cycloaliphatic ~ 

~ TOG Classification fBN2922 "-orrosive liquid, toxic, r(6.1) If ~ 

n.o.s. (Aminepropoxylate) 

~ycloal

erminated 

iphatic ~ 

¢ 

IMDG Class SN2922 Jirorrosive liquid, toxic, W(6.1) rr IF!mergenc~ schedules

n.o.s. (Amine­ (EmS) 

terminated F-A, SoB 

cycloaliphatic 

propoxytate) ¢

•• 

5/28/2010. 	 Page: 5fl 
i 

IrJEFFAMINE® RFD 270 

14. Transport information 

\ IATA-DGR Class IJBN2922 ~orrosive liquid, toxic, 1"(6.1) !IV' 

~ l'assenaer and Carao 

n.o.s. (Amine- AircraftQuantity 

terminated limitation: 1 L 

cycloaliphatic Packaging instructions: 

propoxylate) ¢ 808 

Cargo Aircraft Only: 

Quantity limitation: 30 L 

Packaging instructions: 

812 

I 

i 

• 

PG* : Packing group 

115. Regulatory information 


United States 

HCS Classification : ~rrosive material 

U.S. Federal regulations : S"nited States inventory (TSCA 8b): At least one component is not listed. 

CERCLA: Hazardous substances.: No ingredients listed. 

SARA 313 No ingredients listed. 

l'Jiis product does not contain nor is it manufactured with ozone depleting substances. 

California Prop 65 mis product contains no listed substances known to the State of California to cause 

cancer, birth defects or other reproductive harm, at levels which would require a warning 

under the statute. 

Canada 

WHMIS (Canada) li!Jass 0-1 B: Material causing immediate and serious toxic effects (Toxic). 

Class E: Corrosive material 

CEPA (OSL) p:r least one component is not listed. 

This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products 

Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR. 

116 . Other information 

F*FOR RESEARCH AND DEVELOPMENT OR EXPORT ONL y*** 

CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF ABSORBED THROUGH SKIN 

OR IF SWALLOWED. 

Hazardous Material 

Information System (U.S.A.) 

National Fire Protection 

Association (U.S.A.) ~Iammability 

Health Instability 

Date of printing 5/28/2010. 

5/28/2010. Page: 6fl 
Ift;FFAMINE® RFD 270 

116 . Other informati~n Date of issue 28 May 2010 

Date of previous issue : 9/1712009. 

Notice to reader 

While the information and recommendations in this publication are to the best of our knowledge, information and 

beliefaccurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR 

OTHERWISE. 

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH 

INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR 

PURPOSE. 

THE PRODUCT MA Y PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE 

DESCRIBED IN THIS PUBLICA TION, NO GUARANTEE IS MADE THAT THESE ARE THE ONL Y HAZARDS THA T EXIST. 

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon 

the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined 

by the user and made known to handlers, processors and end users. 

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO 

PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM 

UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO 

PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, 

WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE 

MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT 

THE ABOVEADDRESS. 

Trademarks: ". 

JEFFAMINE® is a registered trademark of Huntsman Petrochemical Corporation in one or more 

countries. but not all countries. 

"Indicates information that has changed from previously issued version. 

5/28/2010. Page: 7n 
ATTACHMENT HEADER SHEET 


Attachment Number 006 

Attachment Name 


MSDS for Subst. 2 - XlJ-678 


Associated PMN Section Number 


N/A 


Does not contain CBI 

Report Number 


X78l100714067813343 

HUNTSMAN Material Safety Data Sheet Enriching iives through innovation 

Product and cornpany identification 


Product name XTJ 678, EXPERIMENTAL MSDS # 00060811 

*** For Research and Development or Export Only *** 

Product use Epoxy curing 

Huntsman Petrochemical Corporation 

P.O. Box 4980 

The Woodlands, TX 77387-4980 

TELEPHONE NUMBERS 

Transportation Emergency 

Company: (800) 328·8501 

CHEMTREC: (800) 424·9300 

Medical Emergency: (409) 722·9673 (24 Hour) 

General MSDS Assistance: (281) 719·6000 

Technicallnformalion: (281) 719·7780 

E·MAlL: MSDS@huntsman.com 

Validation dale : 6/24/2009. 

In case of emergency 

Spills Leaks Fire or Exposure Call Chemtrec: (800) 424-9300 


Medical Emergency Information: (800) 328-8501 


In Mexico: 01 800 00 214 00 


In Columbia: 01 800 91 6012 


12. Hazards identification 


Physical state Liquid. 

Odor Amine-like. 

OSHAlHCS status This material is considered hazardous by the OSHA Hazard Communication Standard 

(29 CFR 1910.1200). 

DANGER! 

CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. 

Corrosive to eyes and skin. Causes burns. May be harmful if swallowed. Do not breathe 

vapor or mist. Do not ingest. Do not get in eyes or on skin or clothing. Use only with 

adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash 

thoroughly after handling. 

GENERAL INFORMATION : Read the entire MSDS for a more thorough evaluation of the hazards. 

3. Compositionlinforrriation on ingredients 


Name CAS number 


Neopentyl glycol, propoxylated, aminated TSCAR&D 


6/24/2009. Page: 1/6 
IXTJ 678, EXPERIMENTAL 

14. First aid measures 


Eye contact 	 Immediately flush eyes with plenty of water, occasionally lifting the upper and lower 


eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 


minutes. Get medical attention if irritation occurs. 


Skin contact 	 Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. 

Get medical attention if symptoms occur. 

Inhalation 	 Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if 

breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen 

by trained personnel. Get medical attention if symptoms occur. 

Ingestion 	 Get medical attention immediately. Wash out mouth with water. Move exposed person to 

fresh air. Do not induce vomiting unless directed to do so by medical personnel. 

Chemical burns must be treated promptly by a physician. Never give anything by mouth 

to an unconscious person. 

Notes to physician 	 SymptomatiC and supportive therapy as needed. Following severe exposure medical 

follow-up should be monitored for at least 48 hours. 

IS. Fire-fighting measures 

Flash point 

Products of combustion 

Extinguishing media 

Suitable 

Not suitable 

Special exposure hazards 

Special protective 

equipment for fire-fighters 

Closed cup: 95.28°C (203SF) 


No specific data. 


Use an extinguishing agent suitable for the surrounding fire. 


None known. 


In a fire or if heated, a pressure increase will occur and the container may burst. 


Promptly isolate the scene by removing all persons from the vicinity of the incident if there 


is a fire. No action shall be taken involving any personal risk or without suitable training. 


Fire-fighters should wear appropriate protective equipment and self-contained breathing 


apparatus (SCBA) with a full face-piece operated in positive pressure mode. 


6. Accidental release measures 


Personal precautions 

Environmental precautions 

Methods for cleaning up 

No action shall be taken involving any personal risk or without suitable training. Evacuate 

surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not 

touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate 

ventilation. Wear appropriate respirator when ventilation is inadequate. Put on 

appropriate personal protective equipment (see section 8). 

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and 

sewers. Inform the relevant authorities if the product has caused environmental pollution 

(sewers, waterways, soil or air). 

Stop leak if without risk. Move containers from spill area. Approach release from upwind. 

Prevent entry into sewers, water courses, basements or confined areas. Wash spillages 

into an effluent treatment plant or proceed as follows. Contain and collect spillage with 

non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth 

and place in container for disposal according to local regulations (see section 13). 

Dispose of via a licensed waste disposal contractor. Contaminated absorbent material 

may pose the same hazard as the spilled product. Note: see section 1 for emergency 

contact information and section 13 for waste disposal. 

6124120()'9. 	 Page: 216 
[XTJ 678, EXPERIMENTAL 

\1. Handling and storage 

Handling 

Storage 

Put on appropriate personal protective equipment (see section 8). Eating, drinking and 

smoking should be prohibited in areas where this material is handled, stored and 

processed. Workers should wash hands and face before eating, drinking and smoking. 

Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If 

during normal use the material presents a respiratory hazard, use only with adequate 

ventilation or wear appropriate respirator. Keep in the original container or an approved 

alternative made from a compatible material, kept tightly closed when not in use. Empty 

containers retain product residue and can be hazardous. Do not reuse container. 

Store in accordance with local regulations. Store in original container protected from 

direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials 

(see section 10) and food and drink. Keep container tightly closed and sealed until ready 

for use. Containers that have been opened must be carefully resealed and kept upright 

to prevent leakage. Do not store in unlabeled containers. Use appropriate containment 

to avoid environmental contamination. 

!8. Exposure controls/personal protection 


Consult local authorities for acceptable exposure limits. 

Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual 

exposures will dictate the need for specific protective devices at your workplace. 

Engineering controls Use local exhaust ventilation to maintain airborne concentrations below the TLV. Suitable 

respiratory equipment should be used in cases of insufficient ventilation or where 

operational procedures demand it. For guidance on engineering control measures refer 

to publications such as the ACGIH current edition of 'Industrial Ventilation, a manual of 

Recommended Practice.' 

Personal protection 

Eyes Safety eyewear complying with an approved standard should be used when a risk 

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or 

dusts. 

Skin Personal protective equipment for the body should be selected based on the task being 

performed and the risks involved and should be approved by a specialist before handling 

this product. 

Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved 

standard if a risk assessment indicates this is necessary. Respirator selection must be 

based on known or anticipated exposure levels, the hazards of the product and the safe 

working limits of the selected respirator. 

Hands Chemical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary. 

19. Physical and chemical properties 


General information 

Appearance 

Physical state Liquid. 

Color Off-white. 

Odor Amine-like. 

Odor threshold Not available. 

Important health. safety and environmental information 

pH 10.5 

BOiling point 120 to 20QoC (248 to 392°F) 

Melting pOint Not available. 

6/24/2009. Page: 316 
rXTJ 678, EXPERIMENTAL 

.9. Physical and chemical properties 


Flash point 

Oxidizing properties 

Vapor pressure 

Relative density 

Octanollwater partition 

coefficient 

Vapor density 

VOC content 

Closed cup: 9S.28°C (203.S0F) 

Not available. 

Not available. 

0.91 

Not available. 

Not available. 

Not available. 

,10. Stability and reactivity 


Stability and reactivity The product is stable. 

Incompatibility with various 

substances 

Reactive or incompatible with the follOwing materials: acids. 

Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. 

Hazardous decomposition 

products 

No specific data. 

111 . Toxicological information 


Toxicity data 

Potential acute health effects 

Ingestion Harmful if swallowed. May cause burns to mouth, throat and stomach. 


Inhalation May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. 


Eyes Corrosive to eyes. Causes burns. 


Skin Corrosive to the skin. Causes burns. 


Potential chronic health effects 

Target organs None known. 

Carcinogenicity No known significant effects or critical hazards. 

Mutagenicity No known significant effects or critical hazards. 


Teratogenicity No known significant effects or critical hazards. 


Fertility effects No known significant effects or critical hazards. 


Developmental effects No known significant effects or critical hazards. 


!12. Ecological information 


Environmental effects : No known significant effects or critical hazards. 

\13 . Disposal considerations 

Waste disposal 

6/24/2009. 

The generation of waste should be avoided or minimized wherever possible. Empty 

containers or liners may retain some product residues. This material and its container 

must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a 

licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection 

and waste disposal legislation and any regional local authority requirements. Avoid 

dispersal of spilled material and runoff and contact with soil, waterways, drains and 

sewers. 

Page: 416 
IXTJ 678, EXPERIMENTAL 

114 . Transport information 


Transportation Emergency Number 1-800-424-9300 (CHEIVITREC). 

Additional information 

information 

!Regulatory UN number Proper shipping Class PG* ILabel 

name 

DOT Classification UN2735 Amines, liquid, 8 III - corrosive, n.o.s. 

aminated) 

propoxylated, 

(Neopentyl glycol, ,+

TDG Classification UN2735 ~mines,liquid, 8 III - \Corrosive, n.o.s. 

Neopentyl glycol, 

I laminated)

propoxyl ated, +

IMDG Class UN2735 Amines, liquid, 8 III - corrosive, n.o.s. 

(Neopentyl glycol, 

propoxylated, + 

aminated) i 

IATA-DGR Class UN2735 Amines, liquid, 8 III - corrosive, n.o.s. 

tNeOpenryl glyCOl, 

..s ~~.. ~ 

propoxylated, 

aminated) 

• 

PG* : Packing group 

\15. Regulatory information 


United States 

HCS Classification Corrosive material 

U.S. Federal regulations United States inventory (TSCA 8b): At least one component is not fisted. 

***For Research and Development or Export Only"* 

CERCLA: Hazardous sUbstances.: No ingredients listed. 

SARA 313 	 No ingredients listed. 

This product does not contain nor is it manufactured with ozone depleting substances. 

California Prop 65 	 This product contains no listed substances known to the State of California to cause 

cancer, birth defects or other reproductive harm, at levels which would require a warning 

under the statute. 

Canada 

WHMIS (Canada) Class E: Corrosive material 

CEPA(DSL) At least one component is not listed. 

This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products 

Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR. 

6f24f2009. 	 Page: 516 
[XTJ678, EXPERIMENTAL 

\16 . Other information 

CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. 

Hazardous Material 

Information System (U.S.A.) 

3 

1 

o 

National Fire Protection ~Iammability Association (U.S.A.) 

Health V Instability 

Date of printing 6/24/2009. 

Date of issue 24 June 2009 

Date of previous issue No previous validation. 

Notice to reader 

While the information and recommendations in this publication are to the best of our knowledge, information and 

belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR 

OTHERWISE. 

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH 

INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR 

PURPOSE. 

THE PRODUCT MA YPRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE 

DESCRIBED IN THIS PUBLICA TlON, NO GUARANTEE IS MADE THAT THESE ARE THE ONL YHAZARDS THA TEXIST. 

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon 

the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined 

by the user and made known to handlers, processors and end users. 

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO 

PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM 

UNAUTHORIZED SOURCES MAY CONTAIN INFORMA TION THA T IS NO LONGER CURRENT OR ACCURATE. NO 

PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, 

WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE 

MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT 

THE ABOVE ADDRESS. 

,. Indicates information that has changed from previously issued version. 

6/Z4/2009. Page: 6/6 
ATTACHMENT HEADER SHEET 


Attachment Number 007 

Attachment Name 


Sanitized Siock Flow Diagram for PMN Synthesis 


Associated PMN Section Number 


Pt.2, Sec.A, 1 d. 


Does not contain CSI 

Report Number 


X78T100714067813343 

STORAGE TANK A STORAGE TANK B 

******** kg of pol yo I NH3 CAS # 7664-41-7 

CAS # 214710-36-8 or ****** kg for Subst.l 

******** kg of pol yo I or 

***** kg for Subst. 2 

H2 Carrier Gas 

CAS # 52479-58-0 

H2 Carrier Gas 

REACTOR 

Continuous Bed Type 

with Fixed Catalyst of 

Raney Nickel 

********* 

HYDROGEN STRIPPER 

H2 Recycled to Reactor 

WATER STRIPPER I+-­ AMMONIA STRIPPER r-­ H20 and light amines sent 

NH3 Recycled to Reactor to Water Waste 

FINISHING TOWER SAMPLING & QC 

r-­ Remove any remaining ---+ (Activity A, Release #1) 

lights to Water Waste 

1 

STORAGE TANK PACKAGING 

****** kg ofXTJ-684 or 1-----11>1 (Activity B, Release #2) for 

****** kg ofXTJ-678 pre-packaging QC 


(PMN Substance) 
 (Activity C, Release #3) for 

loading into tank wagons. 

WATER WASTE TANK 

Water waste including ca. 

**** kg ofthe PMN 

ON-SITE TREATMENT PONDS 

Water Waste decomposed by 

microbes. 

Substance from equipment (Activity D, Release #4) 

stripping and flushes. 
ATTACHMENT HEADER SHEET 


Attachment Number 008 

Attachment Name 


Flow Diagram of Wind Blade Formation 


Associated PMN Section Number 


Pt.2, Sec.B, 1a. 


Does not contain CBI 

Report Number 


X78T100714067813343 

EPOXY RESIN TANK 

UNLOADING 

TANK WAGON 

• Epoxy Resin 

of PMN Substance • Catalyst 

(Activity A, Release #1) 

BLEND TANK 

PMN Substance is 

blended with other 

unknown components 

MOLD 

Resins injected into 

fiberglass-filled closed mold 

and heated in "Vacuum 

Bagging" process 

(Activity B, Release #2) 

FINISHED WIND 

BLADE 

Article removed from mold 

(Activity C) 

EQUIPMENT CLEANING 

Water washing of the tanks and 

other equipment containing the 

PMN Substance 

(Activity E, Release #4) 

TANK WAGON 

CLEANING 

~ 

DISPOSAL 

Water washing of the tank Water waste containing PMN 

wagons containing the PIVIN --'" Substance is sent to treatment 

Substance ponds for microbial digestion. (Activity D, Release #3) 
ATTACHMENT HEADER SHEET 


Attachment Number 009 

Attachment Name 


Surrogate Toxicity Data Reference 


Associated PMN Section Number 


N/A 


Does not contain CBI 

Report Number 

X78T100714067813343 
Surrogate Toxicity Data for PMN TSX78T84 

Huntsman Corporation suggests that the Agency use P06-0748 as a surrogate for the PMN 

substance. P06-0748 contains a significant amount of data, is used for the same commercial 

purpose as the PMN substance and is of similar molecular weight.