# Technical Memorandum

TO:Brenda Shine, Environmental Engineer Refining and Chemicals Group, SPPD (E143-01)

FROM:Eric Goehl, Environmental Protection Specialist Refining and Chemicals Group,SPPD (E143-01)

DATE:October 16, 2012

SUBJECT:Summary of Fluid Catalytic Cracking Unit Emission Source Test Reports

I. Purpose The objective of this document is to provide a summary of the Fluid Catalytic Cracking Unit (FCCU) emission source test reports received by the EPA from the 2011 Information Collection Request (ICR) of the Petroleum Refinery industry.

II. Background On April 1, 2011, the EPA sent an ICR to facilities in the U.S. petroleum refining industry. The ICR was comprehensive and designed to collect information on processing characteristics, crude slate characteristics, emissions inventories and sourcetesting to bolster our current data and fill known data gaps. The ICR had four components:(1) a questionnaire on processes and controls to becompleted by all petroleum refineries (Component 1); (2) an emissions inventory to be developed by all petroleum refineries using the emissions estimation protocol developed for this effort (Component 2); (3) distillation feed sampling and analysis to be conducted by all petroleum refineries (Component 3); and (4) emissions source testing to be completed in accordance with an EPA-approved protocol for specific sources at specific petroleum refineries(Component 4). Component 4 of the ICR required source testing for twelve different types of emission sources or units: fluid catalytic cracking units (FCCU), thermal catalytic cracking units, catalytic reforming units, sulfur recoveryunits, delayed coking units,fluid coking units, hydrocracking units, hydrogen plants, asphalt blowing units, fuelgas systems, cooling water systems, and wastewater treatment systems. This memorandum summarizes the results of the FCCU sources
tests. A similar memorandum is available for the other sources required to be tested as a result of

# this ICR. Facilities often claimed specificprocess information as CBI, and included that
information in the CBI version of the emission source test report stored in the EPA’s CBI office in Research Triangle Park, NC. However, emissions data cannot be claimed as CBI. This memorandum summarizes and presents only non-CBI data.

III. Source-specific Testing Program Below is a list of the ten facilities requiredto perform an emission source test on
their FCCU.

• Marathon Oil – Robinson, IL (IL2A0420)

• Flint Hills – Rosemount, MN (MN2B0720)

• Motiva – Norco, LA (LA3C0630)

• Citgo – Lake Charles, LA (LA3C0560)

• Hovensa – St. Croix, USVI (VI6A1530)

• Valero – Port Arthur, TX (TX3B1250)

• Chevron – Barbers Point, HI (HI5A0380)

• BP – Whiting, IN (IN2A0440)

• ExxonMobil – Torrance, CA (CA5A0190)

• Sunoco – Philadelphia, PA (PA1A1030) Owners or operators of the FCCU at these facilities were required to test for:

• Speciated volatile organic hazardous air pollutants (HAP)

• Speciated semi-volatile organic HAP

• Total hydrocarbons, methane, and ethane

• Aldehydes

• Carbon monoxide

• Dioxins, furans, and polychlorinated biphenyls

• Hydrogen chloride, chlorine, hydrogen fluoride, and hydrogen cyanide

• Mercury (speciated)

• Hexavalent chromium and multiple metals

• Particulate matter (PM, PM2.5

# filterable, and PM condensable) and ammonia

• NOX

# , SO2

# , O2

# , CO2

# , moisture, and gas flow rate.

2

# 3 The EPA required that the data collected from the emission source testing to be reported using the EPA Electronic Reporting Tool (ERT).The ERT is a Microsoft® Access database application. If the facility conducted testing using a method not currently supported by the ERT, the facility was required to report the results in the Refinery Testing Supplement, a Microsoft® Excel spreadsheet. After completing the Refinery Testing Supplement, the refineries were also to submit an electronic copy of the emission test report, preferably in PDF format.

IV. Results A summary of the emission results for the FCCUare provided in attached spreadsheet. In order to better characterize the reported data from the emission test reports, detection level information was provided in the attached summary spreadsheet. The following designations were
used to describe the detection levelsof the reported emissions data.

• DLL = Detection Level Limited = 1or 2 runs below detection limit

• BDL = Below Detection Limit = All three runs are below detection limit

• No designation = All three r uns are above detection limit While reviewing the reported FCCU test data for Motiva in Norco, LA, we found conflicting data between the Refinery Testing Supplement and the PDF emission test report. A phone call to the facilityclarified that the information contained in the PDF emission test report
reflected the correct data.Summary of FCCU Test Report Data

75-07-0 Acetaldehyde 8.00E-02 8.40E-01 BDL1.90E-01 3.62E-03 2.52E-02 4.04E-01 3.31E-03 DLL 6.27E-04 BDL 6.80E-04 BDL 1.70E-01 50-00-0 Formaldehyde 1.34E+00 2.10E-01 DLL 4.70E-02 2.05E-03 DLL 1.55E-01 BDL 5.99E-02 1.08E-02 5.91E-03 BDL 2.00E-02 74-90-8 Hydrogen cyanide 1.20E+01 4.60E-01 BDL7.00E-01 2.07E+00 1.05E+02 4.20E+01 BDL0.00E+00 3.22E+01 3.33E+00 5.36E+00 Propanal 3.70E-01 BDL2.50E-01 2.83E-03 1.10E-03 DLL 4.39E-02 0.00E+00 6.73E-04 BDL 1.80E-01 7647-01-0 Hydrogen Chloride 1.01E+00 3.55E-01 2.36E-01 3.12E-02 9.90E-01 BDL 7.20E-02 DLL 7.78E-01 1.96E-01 5.75E-02 7782-50-5 Chlorine BDL 2.00E-02 5.20E-02 BDL 1.70E-03 BDL 1.00E-02 BDL 3.57E-02 BDL0.00E+00 1.30E+00 BDL 2.90E-03 7782-41-4 Hydrogen Fluoride BDL 2.00E-02 1.40E-02 3.63E-02 BDL 2.02E-03 BDL 3.00E-02 BDL 9.85E-03 BDL0.00E+00 BDL 2.60E-02 1.49E-02

67-64-1 Acetone 1.68E+00 3.79E+00 BDL8.20E-04 2.86E+00 BDL 1.57E+00 8.85E+01 DLL 4.89E-01 7.00E-01 BDL 4.10E-01 750-05-8 Acetonitrile 3.70E-01 BDL 1.20E-01 BDL1.88E-03 BDL 2.85E-01 BDL 1.93E+00 DLL 3.62E-01 BDL 6.06E-01 BDL 2.80E-01 data rejected 107-02-8 Acrolein BDL 2.30E-01 BDL 1.20E-01 BDL6.77E-04 BDL 2.85E-01 DLL 1.60E-01 BDL0.00E+00 BDL 2.59E-01 BDL 4.13E-01 BDL 5.40E-01 107-13-1 Acrylonitrile BDL 2.30E-01 BDL 1.19E-01 BDL7.34E-04 BDL 2.85E-01 BDL 1.38E+00 DLL 1.92E-01 BDL 2.55E-01 BDL 2.30E-01 BDL 1.10E-02 71-43-2 Benzene BDL 2.30E-01 BDL 1.22E-01 BDL6.60E-04 BDL 2.85E-01 BDL 4.39E-01 BDL 1.49E-01 2.40E-01 BDL 2.32E-01 BDL 4.93E-01 BDL 5.10E-01 106-99-0 1,3-Butadiene BDL 2.40E-01 BDL 1.22E-01 BDL5.79E-04 BDL 2.85E-01 BDL 8.57E-01 BDL 7.50E-01 BDL0.00E+00 BDL 2.66E-01 BDL 4.00E-01 BDL 6.20E-01 75-15-0 Carbon Disulfide BDL 2.30E-01 BDL 1.19E-01 BDL4.60E-04 BDL 2.85E-01 BDL 1.49E-01 DDL1.29E+00 DLL 1.28E-01 BDL 1.73E-01 BDL 1.40E-01 108-90-7 Chlorobenzene BDL 2.30E-01 BDL 1.22E-01 BDL5.80E-03 BDL 2.85E-01 BDL 8.63E-01 BDL 1.49E-01 BDL0.00E+00 BDL 7.00E-03 BDL 6.53E-02 BDL 1.10E-02 98-82-8 Cumene (Isopropylbenzene) BDL 2.30E-01 BDL 1.22E-01 BDL4.36E-03 BDL 2.85E-01 BDL 1.84E+00 BDL 1.49E-01 BDL0.00E+00 BDL 5.00E-03 BDL 4.73E-02 BDL 1.10E-02 106-93-4 1,2-Dibromoethane BDL 2.30E-01 DLL 1.42E-01 BDL1.41E-03 BDL 2.85E-01 BDL 4.00E+00 BDL 1.49E-01 BDL 3.17E-01 BDL 1.27E+00 BDL 1.30E+00 100-41-4 Ethylbenzene BDL 2.30E-01 BDL 1.22E-01 BDL4.45E-03 BDL 2.85E-01 BDL 5.43E-01 BDL 1.49E-01 BDL0.00E+00 BDL 6.00E-03 BDL 4.83E-02 BDL 1.10E-02 110-54-3 Hexane BDL 2.30E-01 BDL 1.19E-01 BDL6.60E-04 BDL 2.85E-01 BDL 2.20E+00 BDL 1.49E-01 BDL0.00E+00 BDL 2.15E-01 DLL 5.80E-01 BDL 4.40E-01 108-10-1 Methyl iso-Butyl Ketone BDL 2.30E-01 BDL 1.23E-01 BDL 2.85E-01 BDL 1.43E+00 BDL 1.44E-01 BDL0.00E+00 BDL 5.00E-03 BDL 5.00E-02 BDL 8.90E-03 1634-04-4 Methyl t-Butyl Ether (MTBE) BDL 2.30E-01 BDL 1.19E-01 BDL 2.85E-01 BDL 1.36E+00 BDL 1.49E-01 BDL 5.00E-03 BDL 4.73E-02 BDL 7.80E-03 75-09-2 Methylene Chloride BDL 2.30E-01 BDL 1.20E-01 BDL2.68E-03 3.64E-01 BDL 2.61E+00 1.43E+00 BDL0.00E+00 DLL 8.97E-01 DLL 2.51E+00 BDL 1.30E+00 98-95-3 Nitrobenzene BDL 1.17E+00 BDL 6.30E-01 BDL6.96E-03 BDL 1.42E+00 BDL 7.46E-01 7.00E-03 BDL 7.20E-02 BDL 1.30E-02 79-46-9 2-Nitropropane BDL 2.30E-01 BDL 1.22E-01 BDL6.05E-02 BDL 2.85E-01 BDL 3.19E+00 BDL 1.49E-01 DLL 8.00E-03 BDL 4.40E-01 BDL 1.10E-02 109-66-0 Pentane BDL 2.30E-01 BDL 1.22E-01 BDL6.63E-04 BDL 2.85E-01 BDL 1.84E+00 BDL 7.76E-01 BDL 2.14E-01 BDL 4.90E-01 BDL 7.90E-01 100-42-5 Styrene BDL 2.30E-01 BDL 1.22E-01 BDL4.83E-03 BDL 2.85E-01 BDL 1.81E+00 BDL 1.49E-01 BDL 6.00E-03 BDL 5.23E-02 BDL 8.60E-02 127-18-4 Tetrachloroethene BDL 2.30E-01 BDL 1.22E-01 BDL1.42E-03 BDL 2.85E-01 BDL 2.37E+00 BDL 1.49E-01 BDL0.00E+00 BDL 2.81E-01 BDL 1.28E+00 BDL 2.30E+00 108-88-3 Toluene BDL 2.30E-01 BDL 1.23E-01 BDL7.37E-04 BDL 2.85E-01 BDL 2.40E+00 BDL 1.50E-01 6.13E+00 DLL 2.26E-01 BDL 5.63E-01 BDL 8.60E-01 79-01-6 Trichloroethene BDL 2.30E-01 BDL 1.23E-01 BDL1.34E-03 BDL 2.85E-01 BDL 6.71E-01 BDL 1.50E-01 BDL 3.48E-01 BDL 1.21E+00 BDL 7.60E-01 540-84-1 2,2,4-Trimethylpentane BDL 2.30E-01 BDL 1.22E-01 BDL 2.85E-01 BDL 2.04E+00 BDL 1.49E-01 BDL 4.00E-03 BDL 4.10E-02 BDL 7.00E-03 1330-20-7 Xylene BDL 1.22E-01 BDL 5.43E-01 BDL 1.49E-01 BDL0.00E+00 BDL 1.10E-02 BDL 9.60E-02 o-Xylene BDL 2.30E-01 BDL4.52E-03 BDL 2.85E-01 BDL0.00E+00 BDL 1.00E-02 m&p-Xylenes BDL 2.30E-01 BDL4.40E-03 BDL 2.85E-01 BDL0.00E+00 BDL 1.00E-02 Total VOC as propane BDL 5.24E+01

1.93E-08 83-32-9 Acenaphthene BDL 1.92E-06 1.35E-05 BDL1.48E-05 BDL 7.48E-06 BDL 1.18E-04 DLL 1.11E-04 BDL 1.06E-04 BDL 1.60E-05 BDL 2.10E-06 209-96-8 Acenaphthylene DLL 8.95E-06 8.03E-06 BDL1.49E-05 9.31E-06 BDL 1.12E-04 BDL 1.42E-04 BDL 3.37E-05 BDL 1.60E-05 BDL 2.10E-06 62-53-3 Aniline BDL 3.60E-04 BDL 3.07E-04 BDL1.03E-03 BDL 2.13E-04 4.78E-01 BDL 2.89E-07 BDL 5.09E-04 BDL 5.70E-03 BDL 5.20E-04 120-12-7 Anthracene 1.72E-06 1.67E-06 BDL1.49E-05 3.73E-06 7.57E-04 DLL 2.28E-05 BDL 3.37E-05 DLL 1.60E-05 BDL 2.10E-06 92-87-5 Benzidine BDL 7.40E-03 BDL 6.31E-03 BDL3.39E-02 BDL 4.49E-03 BDL 1.28E+00 BDL 5.94E-06 BDL 5.21E-05 BDL 1.90E-01 data rejected 56-55-3 Benzo(a)Anthracene BDL 7.79E-07 BDL 9.60E-07 BDL 6.82E-07 9.40E-04 BDL 8.78E-07 BDL 1.51E-04 DLL 1.60E-05 BDL 2.10E-06 205-99-2 Benzo(b)Fluoranthene BDL 7.79E-07 BDL 1.38E-06 BDL1.48E-05 BDL 4.26E-06 BDL 1.12E-04 BDL 6.75E-07 BDL 2.76E-05 DLL 1.60E-05 BDL 2.10E-06 207-08-9 Benzo(k)Fluoranthene BDL 7.79E-07 BDL 1.00E-06 BDL1.48E-05 DLL 6.98E-07 BDL 1.12E-04 BDL 6.26E-07 BDL 4.14E-05 DLL 1.60E-05 BDL 2.10E-06 191-24-2 Benzo(ghi)Perylene 1.52E-06 BDL 6.60E-07 BDL1.48E-05 BDL 4.73E-07 BDL 1.12E-04 DLL 3.04E-06 BDL 1.00E-04 BDL 1.60E-05 BDL 2.10E-06 50-32-8 Benzo(a)Pyrene BDL 7.79E-07 BDL 6.60E-07 BDL1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 8.05E-06 BDL 9.35E-05 DLL 1.60E-05 BDL 2.10E-06 192-97-2 Benzo(e)Pyrene BDL 7.79E-07 BDL 2.16E-06 BDL1.48E-05 BDL 1.62E-06 BDL 1.12E-04 DLL 1.31E-05 BDL 3.07E-05 DLL 1.60E-05 BDL 2.10E-06 92-52-4 Biphenyl 2.18E-04 1.16E-03 BDL1.48E-05 3.00E-04 BDL 5.62E-02 BDL 9.08E-05 BDL 3.07E-05 BDL 8.20E-03 BDL 2.10E-04 1319-77-3 Cresols BDL 1.29E-03 6.49E+00 1.80E-02 DLL 1.00E-02 218-01-9 Chrysene* 1.70E-06 2.93E-06 BDL1.48E-05 1.21E-05 8.80E-04 BDL 1.31E-06 BDL 1.07E-04 DLL 1.60E-05 BDL 2.10E-06 53-70-3 Dibenzo(a,h)Anthracene* BDL 7.79E-07 BDL 7.70E-07 BDL1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 7.29E-07 BDL 9.12E-05 BDL 1.60E-05 BDL 2.10E-06 132-64-9 Dibenzofuran BDL 4.48E-04 BDL 3.82E-04 BDL1.02E-03 3.69E-04 BDL 3.87E-02 BDL 3.60E-07 BDL 7.74E-05 BDL 5.60E-03 BDL 1.40E-04 192-65-4 Dibenzo(a,e)pyrene BDL 6.60E-07 BDL1.48E-05 BDL 4.73E-07 BDL 2.25E-04 BDL 6.26E-07 BDL 8.20E-05 BDL 2.10E-06 119-90-4 3,3'-Dimethoxybenzidine BDL 5.65E-03 BDL 4.82E-03 BDL1.48E-03 BDL 3.43E-03 BDL 1.12E+00 BDL 4.54E-06 BDL 3.07E-05 BDL 8.20E-03 data rejected 60-11-7 Dimethylaminobenzene BDL 3.90E-04 BDL 3.32E-05 BDL1.48E-03 BDL 2.37E-04 BDL 3.55E-02 BDL 3.13E-07 BDL 3.07E-05 BDL 8.20E-03 BDL 2.10E-04 57-97-6 7,12-Dimethybenz(a)anthracene BDL 6.60E-07 BDL5.09E-03 BDL 4.73E-07 BDL 2.25E-04 BDL 6.26E-07 BDL 3.07E-05 BDL 3.30E-05 BDL 2.10E-06 119-93-7 3,3'-Dimethylbenzidine BDL 5.65E-03 BDL 4.82E-03 BDL1.60E-02 BDL 3.43E-03 BDL 6.06E-01 BDL 4.54E-06 BDL 3.07E-05 BDL 8.80E-02 data rejected 122-09-8 a,a-Dimethylphenethylamine BDL 2.34E-03 BDL 1.99E-03 BDL1.48E-03 BDL 1.42E-03 BDL 2.81E-01 BDL 1.88E-06 BDL 3.07E-05 BDL 8.20E-03 data rejected 105-67-9 2,4-Dimethylphenol BDL 5.07E-04 BDL 4.32E-04 BDL1.08E-03 BDL 3.08E-04 4.29E-01 BDL 4.07E-07 DLL 8.45E-04 BDL 5.90E-03 BDL 1.50E-04 206-44-0 Fluoranthene 6.72E-06 1.00E-05 3.82E-05 4.89E-05 1.58E-03 9.79E-06 BDL 3.07E-05 3.60E-05 BDL 2.10E-06 86-73-7 Fluorene DLL 4.87E-06 1.75E-05 DLL 1.78E-05 BDL 3.51E-05 BDL 1.12E-04 DLL 4.98E-05 BDL 3.99E-05 DLL 1.60E-05 3.41E-06 193-39-5 Indeno(1,2,3-cd)Pyrene BDL 7.79E-07 BDL 9.40E-07 BDL1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 5.58E-06 BDL 9.66E-05 DLL 1.60E-05 BDL 2.10E-06 78-59-1 Isophorone BDL 4.38E-04 BDL 3.74E-04 BDL1.11E-03 BDL 2.60E-04 BDL 4.20E-02 BDL 3.52E-07 BDL 2.22E-05 BDL 6.10E-03 BDL 1.60E-04 56-49-5 3-Methylcholanthrene BDL 6.64E-07 BDL1.48E-05 BDL 4.73E-07 BDL 2.25E-04 BDL 6.26E-07 BDL 3.07E-05 BDL 8.20E-05 BDL 2.10E-06 91-57-6 2-Methylnaphthalene 6.16E-05 5.89E-04 3.23E-05 2.44E-05 BDL 1.20E-04 7.41E-05 BDL 5.06E-05 3.40E-05 6.98E-06 95-48-7 2-Methylphenol BDL 4.09E-04 BDL 2.48E-04 DLL 4.26E-06 BDL 1.40E-04 106-44-5/1084-Methylphenol & 3-Methylphenol BDL 1.10E-03 BDL 6.62E-04 BDL 1.27E-06 BDL 1.20E-04 91-20-3 Naphthalene 1.62E-04 3.22E-04 3.24E-04 7.93E-03 2.52E-04 2.80E-04 BDL 1.33E-04 5.90E-04 9.98E-05 198-55-0 Perylene BDL 7.79E-07 BDL 6.64E-07 BDL1.48E-05 BDL 4.73E-07 BDL 1.12E-04 BDL 6.21E-07 BDL 3.07E-05 DLL 1.60E-05 BDL 2.10E-06 85-01-8 Phenanthrene 4.23E-05 5.11E-05 BDL3.62E-05 3.05E-04 2.33E-03 6.31E-05 BDL 1.21E-04 2.70E-05 2.53E-06 108-95-2 Phenol BDL 1.26E-03 1.46E-03 BDL5.79E-03 BDL 2.04E-03 6.07E+00 1.21E-06 DLL 1.31E-02 DLL 5.30E-03 1.12E-03 106-50-3 1,4-Phenylenediamine BDL 3.51E-03 BDL 2.99E-03 BDL1.48E-03 BDL 2.13E-03 BDL 2.81E-01 BDL 2.82E-06 BDL 2.98E-05 BDL 8.20E-03 data rejected SVOC lb/hr DL DL lb/hr DL lb/hr DL lb/hr

VOLATILE ORGANIC HAP DL lb/hr DL lb/hr CAS # Compound IL2A0420 - Marathon Robinson, IL VI6A1530 - Hovensa Christiansted, USVI MN2B0720 - Flint Hills Rosemount, MN HI5A0380 - Chevron Kapolei, HI

DL lb/hr Detection Level (DL) lb/hr DL DL lb/hr lb/hr TX3B1250 - Valero

Port Arthur, TX PA1A1030 - Sunoco Philadelphia, PA LA3C0560 - Citgo Lake Charles, LA CA5A0190 - ExxonMobil Torrance CA IN2A0440 - BP Whiting, IN LA3C0630 - Motiva Norco LASummary of FCCU Test Report Data

lb/hr DL DL lb/hr DL lb/hr DL lb/hr DL lb/hr DL lb/hr CAS # Compound IL2A0420 - Marathon Robinson, IL VI6A1530 - Hovensa Christiansted, USVI MN2B0720 - Flint Hills Rosemount, MN HI5A0380 - Chevron Kapolei, HI

DL lb/hr Detection Level (DL) lb/hr DL DL lb/hr lb/hr TX3B1250 - Valero

Port Arthur, TX PA1A1030 - Sunoco Philadelphia, PA LA3C0560 - Citgo Lake Charles, LA CA5A0190 - ExxonMobil Torrance CA IN2A0440 - BP Whiting, IN LA3C0630 - Motiva Norco LA

129-00-0 Pyrene 6.83E-06 1.06E-05 8.65E-05 BDL 2.49E-05 4.87E-03 DLL 2.26E-06 BDL 3.68E-05 7.30E-05 BDL 2.10E-06 95-53-4 o-Toluidine BDL 9.74E-04 BDL 8.31E-04 BDL1.48E-03 BDL 5.91E-04 BDL 1.10E-01 BDL 7.82E-07 BDL 3.07E-05 BDL 8.20E-03 BDL 2.10E-04 Total PAHs BDL 8.72E-03

7400-36-0 Antimony BDL 2.86E-04 3.12E-04 DLL 3.47E-03 BDL 2.21E-03 2.00E-03 BDL 3.59E-05 BDL 3.43E-04 8.44E-05 7440-38-2 Arsenic BDL 2.45E-04 BDL 2.10E-04 BDL3.31E-04 BDL 1.94E-04 2.00E-04 BDL 1.44E-04 BDL 5.44E-04 DLL 6.80E-04 7440-41-7 Beryllium BDL 2.45E-04 BDL 5.26E-05 BDL8.28E-05 BDL 4.46E-05 BDL 1.00E-05 BDL 3.59E-05 DLL 3.91E-06 DLL 5.00E-06 7440-43-9 Cadmium BDL 2.45E-04 1.19E-03 BDL8.30E-05 BDL 2.68E-05 2.00E-04 8.35E-04 DLL 5.37E-05 DLL 4.40E-06 7440-47-3 Chromium 1.09E-03 2.44E-03 7.30E-04 BDL 1.29E-03 1.40E-03 4.21E-04 DLL 1.11E-03 4.07E-04 7439-92-1 Lead DLL 4.64E-04 3.11E-03 BDL1.66E-04 1.15E-03 1.90E-03 2.16E-04 DLL 6.27E-04 1.50E-04 7439-96-5 Manganese 7.54E-04 9.46E-04 3.84E-03 2.40E-03 6.30E-03 6.71E-04 7.70E-04 9.88E-04 7440-02-0 Nickel DLL 6.08E-04 3.33E-03 1.14E-02 4.61E-03 5.30E-03 1.11E-03 2.18E-03 1.63E-02 7782-22-4 Selenium DLL 9.66E-04 BDL 5.26E-04 DLL 1.02E-03 BDL 7.29E-04 1.40E-03 BDL 3.59E-04 DLL 9.53E-04 DLL 3.80E-04 7440-48-4 Cobalt 3.39E-04 8.11E-04 BDL 2.06E-04 1.00E-03 5.82E-05 BDL 1.69E-04 1.08E-03 18540-29-9 Hexavalent Chromium BDL 1.13E-04 BDL 8.00E-03 1.64E-03 BDL 8.14E-05 DLL 9.00E-04 BDL 3.24E-04 1.74E-04 BDL 2.04E-04 DLL 4.03E-05

- Oxidized/organic Mercury BDL 2.72E-04 6.78E-05 BDL1.20E-05 DLL 7.24E-05 2.92E-05 1.90E-05 DLL 1.54E-06 DLL 1.50E-05 Total Mercury BDL 8.51E-04 BDL 1.98E-04 DLL 3.87E-05 BDL 1.91E-04 BDL 1.81E-04 7439-97-6 Elemental Mercury BDL 5.71E-04 BDL 1.19E-04 2.42E-05 1.04E-04 2.55E-04 BDL 1.52E-04 7.09E-04 DLL 3.86E-05 DLL 2.73E-05 DLL 3.00E-05

7664-41-7 Ammonia 5.49E+00 4.50E-01 DLL 2.70E-01 7.23E-01 9.85E+00 5.22E-01 BDL0.00E+00 6.39E-01 5.50E+00 1.20E-01 630-08-0 Carbon Monoxide 7.86E+01 3.23E+00 3.73E+01 3.22E+00 2.36E+01 2.11E+01 1.26E+01 7782-50-5 Chlorine 5.20E-02 BDL 1.73E-03 67-56-1 Methanol BDL 5.87E-01 4.86E+01 7.67E+00 1.80E-01 5.49E-01 DLL 5.86E-01 DLL 1.33E+00 BDL 2.80E-02 74-82-8 Methane 3.45E+01 BDL 7.00E-02 BDL1.10E-01 8.00E-01 4.10E-01 4.73E-01 2.49E+00 7.77E-01 3.50E-01 BDL 8.15E-02 74-84-0 Ethane 1.21E+01 BDL 8.00E-02 BDL2.60E-01 BDL 1.00E-01 7.68E-01 BDL 8.05E-01 1.26E+01 1.25E+00 BDL 3.40E-01 BDL 4.70E-01 75-69-4 Trichlorofluoromethane 74-83-9 Bromomethane 10102-43-9 Nitrogen Oxides 2.52E+01 1.59E+02 2.16E+01 9.53E+00 1.26E+01 1.01E+01 1.67E+01 Sulfur Dioxide 2.84E+01 4.15E+01 2.84E+00 DLL 9.38E-01 2.70E+01 Reported a negative 0.01 6.80E+00

Condensible Inorganic (aqueous) PM 1.99E+01 2.05E+01 3.29E+01 1.59E+00 Condensible Organic Particulate Matter 9.10E-01 1.26E+00 1.32E+00 9.16E-02 Condensible Particulate Matter 9.49E+00 8.53E+00 2.28E+01 2.29E+00 2.61E+00 Filterable Particulate 1.26E+00 2.17E+01 2.27E+01 1.54E+01 6.22E+00 8.20E+01 4.45E+00 Filterable PM2.5 1.32E+01 2.42E+00 Total PM2.5 2.10E+01 2.27E+01 4.10E+00 Total PM 4.35E+01 3.12E+01 3.82E+01 8.51E+00 1.16E+02 4.23E+00

Total PCBs 3.10E-07 BDL 2.17E-08 BDL 6.51E-09 PCB TEQs 1.65E-10

2,3,3',4,4',5,5'-HpCB (PCB189) BDL 1.01E-09 2.73E-09 BDL 3.92E-10 BDL 6.92E-11 BDL 3.38E-10 BDL 3.00E-10 2,3,3',4,4',5'-HxCB (PCB157) DLL 5.42E-10 2.09E-09 DLL 2.37E-10 BDL 1.42E-10 BDL 3.54E-10 DLL 5.70E-10 2,3,3,4,4,5-HxCB (PCB156) 1.82E-09 7.50E-09 6.27E-10 BDL 1.48E-10 1.08E-08 DLL 5.70E-10 2,3,3',4,4'-PeCB (PCB105) 1.25E-08 6.14E-08 DLL 5.14E-09 DLL 6.77E-10 8.98E-08 BDL 3.57E-09 2,3',4,4',5,5'-HxCB (PCB167) DLL 8.42E-10 5.88E-09 DLL 3.26E-10 BDL 1.67E-10 2.69E-08 BDL 3.30E-10 2,3,4,4',5-PeCB (PCB114) BDL 8.62E-10 5.40E-09 BDL 4.42E-10 BDL 9.44E-11 DLL 8.30E-09 BDL 2.80E-10 2,3',4,4',5-PeCB (PCB118) 3.22E-08 1.71E-07 1.19E-08 DLL 1.78E-09 3.01E-07 1.02E-08 2',3,4,4',5-PeCB (PCB123) DLL 1.40E-09 1.68E-08 DLL 6.17E-10 BDL 1.51E-10 2.85E-07 BDL 4.70E-10 2,3,4,6,7,8-HxCDF DLL 2.19E-09 DLL 1.74E-10 BDL 6.97E-10 BDL 1.80E-10 2,3,7,8-TCDD BDL 6.79E-10 DLL 6.30E-10 BDL3.19E-10 BDL 1.83E-10 BDL 3.82E-10 BDL 6.80E-10 2,3,7,8-TCDF 3.42E-09 BDL4.77E-10 BDL 2.19E-10 DLL 5.44E-10 BDL 4.30E-10 3,3',4,4',5,5'-HxCB (PCB169) BDL 1.14E-09 9.42E-10 BDL 3.19E-10 BDL 2.80E-09 BDL 3.91E-10 BDL 3.40E-10 3,3',4,4',5-PeCB (PCB126) BDL 6.00E-10 3.39E-09 BDL 4.30E-10 BDL 1.67E-10 BDL 3.43E-10 BDL 3.00E-10 3,3',4,4'-TCB (PCB77) 6.71E-09 2.90E-08 DLL 5.90E-09 DLL 2.60E-10 DLL 7.39E-09 9.10E-10 3,4,4',5-TCB (PCB81) DLL 4.28E-10 3.69E-09 DLL 5.88E-10 BDL 1.06E-10 DLL 5.75E-09 BDL 3.10E-10 OCDD 4.96E-09 BDL1.16E-09 1.45E-08 DLL 1.88E-09 OCDF BDL 1.77E-09 DLL 7.00E-09 BDL5.58E-10 BDL 2.66E-10 DLL 2.22E-09 DLL 4.06E-09 1,2,3,6,7,8-HxCDF BDL 3.45E-10 BDL 1.44E-10 BDL 6.42E-10 DLL 2.00E-10 1,2,3,4,6,7,8-HpCDD BDL 8.65E-10 2.77E-09 BDL3.96E-10 BDL 4.33E-10 BDL 7.12E-10 DLL 4.30E-10 2,3,4,7,8-PeCDF BDL 5.09E-10 DLL 3.39E-09 BDL4.77E-10 DLL 3.76E-10 BDL 5.93E-10 DLL 2.20E-10 1,2,3,4,6,7,8-HpCDF DLL 5.59E-10 DLL 3.49E-09 BDL3.24E-10 DLL 2.64E-10 1.39E-09 1,2,3,4,7,8,9-HpCDF BDL 8.58E-10 DLL 7.57E-09 BDL3.33E-10 DLL 1.45E-10 DLL 1.14E-09 DLL 4.50E-10 1,2,3,4,7,8-HxCDD BDL 6.11E-10 DLL 4.75E-10 BDL3.15E-10 BDL 1.71E-10 BDL 9.40E-10 BDL 3.30E-10 1,2,3,4,7,8-HxCDF 3.32E-09 BDL2.88E-10 BDL 1.32E-10 BDL 6.93E-10 DLL 2.80E-10 1,2,3,6,7,8-HxCDD BDL 6.21E-10 DLL 8.15E-10 BDL3.15E-10 BDL 1.69E-10 BDL 8.88E-10 DLL 4.00E-10 1,2,3,7,8,9-HxCDD BDL 6.72E-10 DLL 1.09E-09 BDL2.88E-10 BDL 1.67E-10 BDL 9.16E-10 BDL 3.30E-10 1,2,3,7,8,9-HxCDF BDL 4.50E-10 DLL 5.37E-09 BDL3.60E-10 BDL 1.26E-10 BDL 8.26E-10 BDL 2.10E-10 1,2,3,7,8-PeCDD BDL 7.53E-10 DLL 9.59E-10 BDL2.88E-10 BDL 3.49E-10 BDL 6.27E-10 BDL 3.10E-10 1,2,3,7,8-PeCDF DLL 6.28E-09 BDL2.97E-10 BDL 3.01E-10 BDL 5.80E-10 BDL 2.80E-10 Total HpCDD 4.62E-09 BDL3.96E-10 5.17E-10 DLL 4.30E-10 METALS

PARTICULATE MATTER

TOTAL PCBs

DIOXIN AND FURANSSummary of FCCU Test Report Data

lb/hr DL DL lb/hr DL lb/hr DL lb/hr DL lb/hr DL lb/hr CAS # Compound IL2A0420 - Marathon Robinson, IL VI6A1530 - Hovensa Christiansted, USVI MN2B0720 - Flint Hills Rosemount, MN HI5A0380 - Chevron Kapolei, HI

DL lb/hr Detection Level (DL) lb/hr DL DL lb/hr lb/hr TX3B1250 - Valero

Port Arthur, TX PA1A1030 - Sunoco Philadelphia, PA LA3C0560 - Citgo Lake Charles, LA CA5A0190 - ExxonMobil Torrance CA IN2A0440 - BP Whiting, IN LA3C0630 - Motiva Norco LA

Other HpCDF DLL 4.44E-10 Total HpCDF DLL 1.41E-08 BDL3.51E-10 DLL 3.31E-10 DLL 2.23E-09 Other HxCDD DLL 1.77E-09 Total HxCDD 5.68E-09 BDL3.15E-10 BDL 1.71E-10 DLL 2.84E-09 Other HxCDF DLL 3.15E-10 Total HxCDF 2.50E-08 BDL3.06E-10 DLL 3.65E-10 DLL 7.90E-10 Other PeCDD DLL 1.45E-10 Total PeCDD 7.05E-09 BDL5.67E-10 BDL 3.49E-10 DLL 4.41E-10 Other PeCDF DLL 3.38E-10 Total PeCDF DLL 3.69E-08 BDL5.76E-10 DLL 4.95E-10 DLL 7.90E-10 Other TCDD DLL 8.90E-12 Total TCDD 8.89E-09 BDL2.97E-10 DLL 4.50E-10 DLL 6.90E-10 Other TCDF DLL 0.00E+00 Total TCDF 9.19E-08 BDL8.46E-10 BDL 2.19E-10 BDL 4.30E-10 Total Dioxins and Furans DLL 2.52E-07 1.41E-08 5.80E-09 Total PCDD/F BDL5.77E-09 2.18E-08 Total PCDD/F TEQ 3.69E-09 Total Dioxins 7.20E-09 DLL 6.29E-09 Total Furans 6.89E-09 DLL 8.29E-09 Total Hydrocarbon 1.01E+02 7.61E-01 3.19E+00