p. 1


# OAR Box 1706 Prepped by Ollie Stewart



### Document

Number: 

# 48 ) IV-E- 8 Docket Number: 

# A-98-1 3

Printed 10/8/2008 10:25:09 AM Sheet 48 of 142P. 2 

# \\j-e-ot

AU G - , ( pn n 

### 3

MEMORANDU M Subject : Meetin g Minute s for th e May 22,2003 , Meetin g EP A an dth e America n Chemistr y Counci l (ACC ) - OLD MAC T Rule , 10:00-11:3 0 am From : K.C . Hustved t

U.S . EPA/OAQPS/ES D To : Ai r

an dRadiatio n Docke t Docke t No . A-98-1 3 Purpos e o f

Meetin g T o presen t

th e OLD Technica l Team' s lates t thinkin g o n th e directio n ofth e final rul e o n th e basi s ofth e comment s receive do n th e propose drule . Attendee s Mr . K . C . Hustvedt , U S EPA/OAQP S Ms . Marth aSmith , U S EPA/OAQP S Mr . Ke n Meardon , MACTE C Mr . Robert

Morehouse , Exxon/Mobi l Mr . Te dCromwell , AC C Ms . Tar aLanier , Ashland/Maratho n Summarv o f

Discussio n W e first summarize dth e majo r

item s ofth e propose drul e an dth e directio n that th e EP A Staf

f was considerin g for

th e final rul e base do n th e comment s receive dan dth e re-analysi s o f th e dat abas e (se e Attachmen t

1) . Item s covere dincluded :

• Wastes . AC C was concerne dthat w e intende dt o includ e waste s a s organi c liquids . AC C note dtha t at large r facilitie s wast e tank s ar e likel y t o b e emptie dint o tan k truck s throug h aloadin g rack , wherea s at smalle r facilitie s wast e tank s ar e likel y t o b e emptie dint o tan k truck s usin g apum p hook-u p directl y betwee n th e wast e tan k an dth e tan k

truck . EP A indicate dtha t

th e coverag e o f

waste s stil l need s t o b e clarified . 

# IP. 3

• Lis t

o f HAP . EP A indicate dtha t th e Tabl e 1 HA P i n th e propose drul e no w include dal l 9 8 HA P (includin g th e si x glyco l ethers ) identifie di n th e Technica l Support Documen t

(TSD ) a s bein g i n OL D liquid s (se e Attachmen t 2) . AC C expresse dconcer n abou t ho w th e vapo r pressure s wer e calculated , especiall y that th e vapo r pressur e for

styren e appeare dt o b e to o high .

• Equipmen t

leak component s associate dwith pipelines . AC C was concerne dtha t thes e component s woul db e picke du p b y th e rul e eve n whe n th e pipelin e wen t directl y t o anon OL D storag e tank . EP A indicate dthat th e intentio n i n th e final rul e was not t o cove r suc h component s unles s th e pipelin e wa s associate dwith a n OLD storag e tank . EP A indicate d tha t th e inten t

ofth e rul e i s t o "catch " tank s an drack s an dassociate dequipmen t no t covere d b y othe r 4 0 CF Rpart

6 3 rules .

• Storag e tank s (Attachmen t 3) . Curren t

staf f recommendatio n ar e control s for tank s greate r tha n 40,00 0 gallo n capacity at an y partia l HA P vapo r

pressur e an dcontro l for

tank s with capacitie s betwee n 20,00 0 gallon s an d40,00 0 gallon s storin g liquid s with at leas t 1. 9 psi a partia l HA P vapo r

pressure . Curren t

staf f recommendation s als o includ e an o emissio n reductio n floo r

for tank s with capacitie s les s tha n 20,00 0 gallons . AC C was concerne dtha t singl e tank s wer e apparentl y settin g ne w sourc e floor s for anumbe r

o f tan k capacity an d vapo r pressur e range s an dsuggeste dthat EP A re-examin e thes e tank s (e.g. , t o ensur e that non e o f the mwer e operatin g o n atemporary basi s a s migh t occu r i n an "overflow " situation) . W e agree dt o sen dAC C th e databas e an dput i t int o th e record .

• Transfe r

Rack s (Attachmen t

4) . Curren t

staf f recommendation s i s contro l for existin g rack s a

t facilitie s with outgoin g OLD liqui dtransfe r betwee n 800,00 0 an d7 millio n gallon s i f th e liqui d i s at leas t 98 % HA P an dfo

r existin g rack s a

t facilitie s with outgoin g OL D liqui dtransfe r o f 7 millio n gallon s o r

mor e a t any HA P concentratio n (greate r tha n 0. 1 weigh t

percent) . Ne w sourc e MAC T woul drequir e control s a t al l siz e facilitie s bu t

with differen t

minimu mHA P percentage s (les s tha n 800,00 0 gallon s an d5 % HA P o r greater ; 800,00 0 t o 7 millio n gallon s an d1 % HA P o r

greater ; 7 millio n gallon s o r greate r an d0.1 % HA P o r

greater) . I t

wa s note d tha t onl y rack s transferrin g OLD liquid s woul db e require dt o b e controlle dunde r th e rul e an d tha t onl y th e amoun t

o f outgoin g OLD liqui dwoul db e use dt o determin e th e facility throughpu t

amount .

• Storag e o f

oi l a t oi l an dga s sites . AC C aske di f tank s storin g crud e oi l at oi l an dga s site s wer e covere db y th e OLD rule . EP A indicate dtha t i f th e storag e tank s wer e after transfe r custody , the y woul db e covered . It was noted , however , that ther e can b e

• severa l point s o f

transfe r custod y an dthat

th e final rul e woul dhav e t o clarif y whic h poin t

o f 

# 2 .P. 4



### 3 transfe r custod y i s the relevan

t one . EP A didnot e tha t crud e oi l pipelin e station s ar

e covered by th e OL D rul e an dtha t crud e oi l tank s a

t suc h site s wouldtherefor

e als o b e subject

t o th e OL D rule . EP

A als o notedtha

t it i s not the inten t ofth e OL D rul e to cove

r oil an dga s exploratio n facilities . Q Containers . EP

A indicatedtha

t the final rul e migh

t have arequiremen

t fo r the loading o

f larg e container s (5 5 gallon s o

r larger ) fo r ne w sources . ACC expressedconcer n abou t the potentia l impact on the pain

t an dcoating industry . EP

A indicate dtha

t thos e facilitie s should b e subject t o the MON' s pain

t an dcoating regulation .

• Equipmen

t to b e includedi

n the affecte

dsource . EP

A indicatedtha

t i n orde r to b e includedi

n the affecte dsource , the equipmen

t (tanks , racks , an

dequipmen

t lea k components ) ha

dt o handl e a n organi c liquid , which i s currentl y being considereda s aliqui dcontainin g a t leas t 0. 1 weigh t percen t HA P an dwit h atota l vapo r pressur e ofa t leas t 0. 1 psia . Equipmen

t subject to the MO N i s not par t ofth e OL D affecte dsource . ACC askedif

i t wa s stil l th e inten

t ofth e OL D rul e t o onl y requir e contro l o f loading (outgoing ) rack s an dnot unloadin g (incoming racks) , bu t tha t bot h outgoing an

dincoming rack s wouldstill b e par t ofth e affecte

dsource . EP A indicate dtha

t thi s wa s still the intention .



# JP. 5



### ATTACHMEN

T 1 OL D MAC T STAF FRECOMMENDATIONS Ma y 21 , 200 3



# f

### OL D MAC T Staf f Recommendation s Ma y 21 , 200 3 TOPI C PROPOSA L DRAF T FINA L RUL E Facilit y applicabilit y Organi c liqui d throughpu t

cutof f Facilitie s with les s tha n 7.2 9 millio n gallon s o f Organi c Liquid s exemp t N o facility-wid e throughpu t cutof f Definitio n o f

Organi c Liqui d Lis t o f organi c HA P i n Tabl e 1 o f

rul e Liste d6 9 HA P Lis t al l 9 8 HA P identifie di n th e OL D surve y (wit h individua l glyco l ether s identified )

V \ Organi c Liqui d definitio n Liquid s containin g 5 o r mor e weigh t

percen t ofth e Tabl e 1 HA P Liquid s containin g 0. 1 o r mor e weigh t

percen t ofth e Tabl e 1 HA P an dwith tota l organi c vapo r pressure s greate r

tha n 0. 1 psi . Considerin g approache s t o justif y raisin g th e weigh t

percen t HA P cutof

f t o 1 t o 5 percen t "Blac k Oil " Exemptio n fo r Crud e Oi l Exempte dBlac k Oil , whic h i s crud e oi l les s tha n a n AP I gravity (40° ) an dga s t o oi l ratio (3 1 fVVgal ) cutoff s a s define di n th e Oi l an dGa s MAC T Blac k Oi l definitio n i s deleted . Crud e oi l i s subjec t t o th e sam e requirement s a s othe r

organi c liquid s Emissio n Poin tStandard s Emissio n point s subjec t t o othe r MAC T standard s No t clear . Exclude deithe r

emissio n point s subject

to o r controlled

by anothe r

MAC T Emissio n point s subjec t t o anothe r

MAC T standar dwoul db e exclude d Storag e tank s Tank s subjec t t o contro l base do n th e HO N vapo r pressur e an dsiz e cutoff

s an do n tota l vapo r

pressur e o f store dliqui d Tank s subjec t t o contro l base do n siz e an dpartia l pressur e o f th e HAP . Value s determine db y OL D databas e an dbeyon d floo r consideration s Transfe r Rack s Loadin g position s wit h annua l organi c liqui dtransfer s

o f 3.1 2 millio n gallon s o r

mor e subjec t

t o 9 5 percen t contro l requiremen t Loadin g rack s subjec t t o contro l base do n facilit y rac k throughpu t

an dHA P content . Value s determine db y th e OL D databas e an dbeyon dfloo r considerations . Affecte drack s subjec t t o 9 8 percen t

emissio n reductio n requirement .
T JTOPI C

Equipmen t

Leak s Container s Wastewate r PROPOSA L

Referenc e existin g MAC T standard s t o appl y t o equipmen t

with 5 percen t

o r greate r Tabl e 1 HA P N o additiona l requirement s N o additiona l requirement s DRAF T FINA L RUL E N o chang e Existin g - n o chang e Ne w - contro l larg e container s N o chang e



### <r »

" 0P. 8



### ATTACHMEN

T 2 OL D HA P b y VAPO RPRESSUR

E



# 1P. 9



### ATTACHMEN

T 2 OL D HA P b y VAPO RPRESSUR

E

«P.1 0



### OL D HA P b y Vapo r Pressur e HA P Compoun d Methy l chlorid e (Chloromethane ) Fonnaldehyd e Viny l chlorid e 1,3-Butadien e Ethylen e oxid e Ethy l chlorid e (Chloroethane ) Hydroge n fluorid e (Hydrofluori c acid ) Acetaldehyd e Vinyliden e chlorid e Ethyliden e dichlorid e Propylen e oxid e Methylen e chlorid e Ally l chlorid e Propionaldehyd e Chloropren e Acrolei n Chloroform Hydrochlori c aci d Methy l tert

buty l ethe r 1,2-Epoxybutan e 1,1-Dimethy l hydrazin e Hexan e Metiiy l chloroform Viny l acetat e Acrylonitril e Methano l Carbo n tetrachlorid e Methy l ethy l keton e Benzen e Acetonitril e Ethylen e dichlorid e Chlorin e Glyco l ether s Trichloroethylen e Triethylamin e Methy l hydrazin e 1,3-Dichloropropen e 2,2,4-Trimethylpentan e Ethy l acrylat e Propylen e dichlorid e ambe r 7487 3 5000 0 7501 4 10699 0 7521 8 7500 3 766439 3 7507 0 7535 4 7534 3 7556 9 7509 2 10705 1 12338 6 12699 8 10702 8 6766 3 764701 0 163404 4 10688 7 5714 7 11054 3 7155 6 10805 4 10713 1 6756 1 5623 5 7893 3 7143 2 7505 8 10706 2 778250 5 Glyco l 7901 6 12144 8 6034 4 54275 6 54084 1 14088 5 7887 5 Vapo r Pressur e (psi ) 74.06 0 67.67 9 51.43 6 40.60 7 24.17 1 23.20 4 17.40 3 16.82 3 12.18 2 11.42 8 10.15 2 8.47 0 7.11 6 5.80 1 5.27 9 4.71 8 4.02 2 3.67 4 3.59 6 3.48 1 3.03 6 2.90 1 2.37 8 2.22 4 2.20 4 2.20 4 2.18 5 1.93 4 1.842 1.740 1.54 7 1.49 6 1.47 0 1.45 0 1.10 4 0.95 9 0.83 1 0.78 5 0.77 3 0.77 3p.1 1

Methy l methacrylat e 1,4-Dioxan e (1,4-Diethhyleneoxide ) Toluen e 1,1,2-Trichloroethan e Tetrachloroethylen e Epichlorohydri n Methy l isobuty l keton e Hydrazin e Chlorobenzen e Ethylen e dibromid e Ethy l benzen e Titaniu mtetrachlorid e p-Xylene s Xylene s (isomer s an dmixture ) m-Xylene s Styren e o-Xylene s 1,1,2,2-Tetrachloroethan e Acryli c aci d Cumen e Dimethy l fprmamid e Hexachloroethan e Diethanolamin e N,N-Diethy l anilin e Anilin e Isophoron e Acetophenon e Pheno l Cresols/Cresyli c aci d Nitrobenzen e Styren e oxid e o-Creso l Malei c anhydrid e o-Toluidin e Naphthalen e 1,2,4-Trichlorobenzen e Chloroaeeti c aci d m-Creso l p-Creso l Quinolin e Ethylen e glyco l 2,4-Toluen e diisocyanat e umbe r 8062 6 12391 1 10888 3 7900 5 12718 4 10689 8 10810 1 30201 2 10890 7 10693 4 10041 4 755045 0 10642 3 133020 7 10838 3 10042 5 9547 6 7934 5 7910 7 9882 8 6812 2 6772 1 11142 2 12169 7 6253 3 7859 1 9886 2 10895 2 131977 3 9895 3 9609 3 9548 7 10831 6 9553 4 9120 3 12082 1 7911 8 10839 4 10644 5 9122 5 10721 1 58484 9 \apo r Pi i (psi ) 0.75 4 0.71 5 0.58 0 0.48 3 0.36 7 0.32 9 0.30 4 0.27 8 0.22 8 0.22 8 0.19 3 0.19 3 0.18 4 0.16 4 0.15 5 0.14 1 0.13 5 0.12 6 0.10 1 0.08 9 0.07 7 0.01 3 0.01 1 0.01 0 0,0 1 0.00 8 0.00 8 0.00 7 0.00 6 0.00 6 0.00 6 0.0 ' 0.00 5 0.00 5 0.00 4 0.00 3 0.00 3 0.00 2 0.00 2 0.00 2 0.00 2 0.00 2


# toP.1 2

IIA P Compoun dVapo r Pressur e Diethy l sulfat e Bipheny l Acrylamid e 2,4-D , salt s an dester s Dibenzofuran s Phthali c anhydrid e Iroquinon e Dibutylphthalat e Methylen e diphenyl diisocyanat e 4,4'-Methylenedianilin e 6467 5 9252 4 7906 1 9475 7 13264 9 8544 9 12331 9 8474 2 10168 8 10177 9 0.0 i 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0 0.00 0 0.0 1 0.00 0 0.00 0



# llP.1 3



### ATTACHMEN

T 3 STORAG E TANK S PROMULGATIO

N FLOO RANALYSIS Ma y 21 , 200 3



# I *P.1 4 

### STORAG E TANK S PROMULGATIO

N FLOO RANALYSI S Ma y 21 , 200 3 Capacity (gallons ) <5,00 0 5,00 0 t o <10,00 0
10,00 0 t o <20,00 0
20,00 0 t o <40,00 0

>40,00 0 Vapo r Pressur e Rang e (partia l pressur e o f

HAP ) al l <0. 1 0. 1 to<4. 0 >4. 0 <0. 1 0. 1 to<4. 0 >4. 0 O. I 0. 1 t o <1. 9 1.9to<4. 0 >4. 0 <0. 1 0.1to<0.7 5 0.7 5 t o <1. 9 1.9to<4. 0 >4. 0 Count s Controlle d 0 0 2 1 0 2 1 1 1 0 2 9 3 15 8 4 6 11 2 1 5 Tota l 3 1 1 8 1 9 2 1 0 2 6 2 1 3 1 6 7 2 18 8 19 9 7 6 11 6 1 9



# t lP.1 5



### ATTACHMEN

T 4 TABL E 1 . THROUGHPU

T AN D HA P CONTEN

T RANGES - TRANSFE

RRACK S (Ma y 21 , 2003 )



# / tTabl e 1 . Throughpu t an dHA P Conten t

Range s - Transfe r

Rack s (May 21 , 2003 ) Transfer Operatio n Annual Throughpu t (gallons ) <800,00 0 800,00 0 t o 7millio n

> 7 millio n <1%HA P

Con
trolle d 0
0
3 Total

0
2
6 1 t o <5 % HAP Con
trolle d 0
1
4 Total

2
4
5 5 t o <25 % HA P Con
trolle d 2
2
6 Total

5
8
1 3 2 5 t o <50 % HAP Con
trolle d 1
0
2 Total

1
3
4 5 0 t o <75 % HA P Con
trolle d 0
1
4 Tota l

0
1
4 7 5 t o <98 % HA P Con
trolle d 0
0
5 Tota l

3
5
7 >98 % Con
trolle d 1
8
2 9 Tota l

4
2 8
3 9 Thi s analysi s exclude s liquid s wit h tota l vapo r pressure s les s tha n 0. 1 psi aan dwith HA P content s les s tha n 0. 1 w t % . Som e liquid s ar e exclude dbase d o n th e tota l vapo r

pressur e exclusion , but

non e o n th e HA P conten t exclusio n (i.e. , al l ar e abov e 0. 1 w t %) .
V N