# II

II 

# TEST REPORT
for 

# Hanson Brick Monroe, NC

Prepared for:

Hanson Brick East, LLC dba Hanson Brick

2304 Brickyard Road & US Highway 7 4 Monroe, NC 2811



## Prepared by:

Air- Tech Environmental, LLC P. 

## 0. Box 12353 Research Triangle Park, NC 27709-2353 (919) 544-6338



## Test Date: November 30, 2006 

# II

II

### Air- Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (AT06-{)396-HBCJ Test Date: 11/30/2006- Page ii 

### Air- Tech Environmental, LLC 

### Report Certification

This report has been reviewed by the following Air- Tech Environmental, LLC 

### personnel and is a true representation of the results obtained from the sampling program for Brick Kiln 3LK at the Monroe, NC facility. The sampling and analytical methods were performed in accordance with procedures approved by the State of North Carolina.

A Qualified Source Test Individual (QSTI) from Air- Tech Environmental, LLC 

### was present during the test.

Team Leader: Michael W. Hartman, Principal Scientist Date Qualified Source

Reviewer: Date Qualified Source Test IndividualsOURCE EVALUATION SOCIETy

**~** Qualified Source Test Individual

LET IT BE KNOWN THAT MICHAEL W. HARTMAN

HAS SUCCESSFULLY PASSED A COMPREHENSNE EXAMINATION AND SATISFIED

EXPERIENCE

REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES

ISSUED

BY THESES QUALIFIED SOURCE TEST INDMDUAL REVIEW BOARD FOR INSTRUMENTAL METHODS soURCE EVALUATION

**SOCIET~**
• Qualified Source Test Individual

LET IT BE KNOWN THAT MICHAEL W. HARTMAN

HAS SUCCESSFULLY PASSED A COMPREHENSIVE EXAMINATION AND SATISFIED

EXPERIENCE

REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES

ISSUED

BY THE SES QUALIFIED SOURCE TEST INDMDUAL REVIEW BOARD FOR

BABIC KNOWI.BDOB AND MANUAL PARTICUUTB SAMPUNG METHODS

ISSUED

THIS 12"' DAY OF JULY, 2004 AND EFFECTNE UNTIL JULY II"', 2009 A""",J'&d

h;:: **o~**

-·

- - ·- ' LeRoy F. 01wta1 SES

VIA PrNidetlf•rrdOST1R.vlew8oanl APPLICATION NO. 2004·005 soURCE EVALUATION

**SOCIET~**
• Qualified Source Test Individual

LET IT BE KNOWN THAT MICHAEL W. HARTMAN

HAS SUCCESSFULLY PASSED A COMPREHENSNE EXAMINATION AND SATISFIED

EXPERIENCE

REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES

ISSUED

BY THE SES QUALIFIED SOURCE TEST INDMDUAL REVIEW BOARD FOR

M&NUAL GAS SOI7.RCE SAMPUNG METHODS

ISSUED THIS 12"' DAY OF JULY, 2004 AND EFFECTNE UNTIL JULY 11"', 2009 **h;::O~** L;-Ro; F. OwwJ• SES

W.:. PruldMf •nd QSn Rnlew BOMI APPLICATION NO. 2004-005 :c Dl :I 00 0 :I OJ :I. (") **~** s: 0 :I **~):,.**
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LET IT BE KNOWN THAT DARRELL H. DOERLE

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EXPERIENCE

REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES

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BY THE SES QUALIFIED SOURCE TEST INDMDUAL REVIEW BOARD FOR

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HAS SUCCESSFULLY PASSED A COMPREHENSIVE EXAMINATION AND SATISFIED

EXPERIENCE

REQUIREMENTS IN ACCORDANCE WITH THE GUIDELINES

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### Air- Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (ATOG-0396-HBC) Test Date: 11/30/2006- Page v 

# TABLE OF CONTENTS
Page



## 1.0 INTRODUCTION
...................................................... 1
2.0 RESULTS SUMMARY
.................................................. 2 2.1 HF and HCI Sampling Results
...................................... 2 2.2 Particulate Matter Sampling Results
................................. 3
3.0 SAMPLING AND ANALYTICAL METHODS

................................. 4
4.0 QUALITY ASSURANCE/ QUALITY CONTROL

.............................. 8

Table 1. Table 2. Table 3.

Figure 1 Figure 2
Appendices Appendix A
Appendix B Appendix C Appendix D Appendix E Tables
HF and HCI Results Summary
...................................... 2 Method 5 Results Summary

- Outlet
................................. 3 QA Summary
................................................... 9 Figures

Process Schematic, Hanson Brick (Columbia, SC)

...................... 6 Method 26A Sampling Train
........................................ 7

Field Data Sheets and Run Summaries Appendix A.1 Inlet Appendix A.2 Outlet Analytical Report Meter Calibrations Process Documentation Example Calculations

# 1.0 INTRODUCTION Air-Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (ATOS-{)396-HBC) Test Date: 11/30/2006- Page 1



## On November 30, 2006, Air- Tech Environmental 

## performed sampling at the Hanson Brick Monroe, NC facility per Air Permit No. 03752T27. Emissions testing was conducted to demonstrate compliance with the emission limits and to develop operational limits for an existing affected source as defined in Subpart 

## JJJJJ of Part 63 NESHAP. The testing was conducted at brick kiln no. 3LK.
The kiln exhaust is d ucted to a common scrubber (a dry lime absorber or DLA, ID 

## # CD-8), to remove hydrogen fluoride (HF) emissions from the exhaust stream. Sampling was conducted at the exhaust stack of the DLA to characterize emissions of HF and hydrogen chloride (HCI) using the sampling procedures of Method 26A. Filterable particulate matter (PM) was measured at the outlet of the exhaust stack using the sampling procedures of Method 5. Additionally, Method 26 samples were collected at the inlet to the DLA in order to determine the DLA removal efficiency for HF and HCI. A summary of the results is presented in the table below. These results indicate Hanson Brick is operating in compliance with the MACT requirements.
This report presents the results of the sampling in Section 2. A description of the sampling locations and the methodologies employed in emissions characterizations are contained in Section 3. Section 4 presents an assessment of the quality control measures taken during the performance of this test program.

Mass Rate lblhr lblton Inlet Outlet Inlet Outlet DRE 

# PM NM 0.56 

# NM 0.038 

# N/A HF 

## 5.71 0.032 0.385 0.0021 99.44 HCI 

# N/A 0.52 

# N/A 0.035 

# N/A

a 

### NM =not measured b 

### N/A =not applicable to compliance assessment

# 2.0 RESULTS SUMMARY Air- Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (AT06-0396-HBC) Test Date: 11/30/2006- Page 2



## Three test runs were conducted for the determination of emission rates for each of the compounds of interest. Test summaries grouped by compounds of interest are presented below. Efforts were made, successfully, to collect all samples during steady production rates of a single type of product. The brick production rate during the testing averaged 14.8 tons per hour. Pressure drop across the DLA averaged 0.16"H 2 

## 0 for the test periods. The limestone feed rate during the compliance test was maintained at 154 pounds per hour.


## 2.1 HF and HCI Sampling Results Samples were collected simultaneously at the DLA inlet and exhaust for all three test runs. A summary of the results of the HF and HCI flue gas concentrations and emission rates is presented in Table 1. All tests did comply with field sampling procedures pertaining to sample train operating temperatures and leak checks.
Flue gas concentrations of HF were found to average 213 ppm at the DLA inlet and 0.84 ppm at the outlet. These concentrations yield mass rates of HF that average 5. 71 lb/hr into the DLA and 0.032 lb/hr out. These measurements show a removal efficiency exceeding 99.44% for HF.
Flue gas concentrations of HCI averaged 10.8 and 7.52 ppm at the DLA inlet and outlet gas streams, respectively. These concentrations yield mass emission rates of 0.53 and 0.52 lb/hr. 

## Table 1. HF and HCI Results Summary

Flue Gas Concentration Mass Rate
Run#/ Flow {dscfm) HF(ppm) HCI{ppm) HF{Iblhr) HCI(Ib/hr) DRE(%) Inlet Run

Times lb/ton lblton Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet brick Inlet Outlet brick HF HCI 1 8098 11528 210 0.77 10.6 6.78 5.28 0.028 0.0018 0.49 0.44 0.030 99.47 N/A 1040-1140 2 8948 12279 215 1.08 10.8 7.85 5.99 0.041 0.0028 0.55 0.55 0.037 99.32 N/A 1153-1253 3 8757 12531 214 0.68 11.0 7.94 5.87 0.027 0.0018 0.55 0.56 0.038 99.54 N/A 1300-1400 Average 8601 12113 213 0.84 10.8 7.52 5.71 0.032 0.0021 0.53 0.52 0.035 99.44 N/A

## 2.2 Particulate Sampling Results Air-Tech Environmental, LLC Hanson Brick!/Monroe, NC Test Report (AT06-0396-HBC) Test Date: 11/30/2006- Page 3



## Particulate sampling was performed at the outlet only for the determination of filterable PM using procedures of Method 5. These results are presented in Table 2. The average concentration of PM was found to be 0.0055 grains per dry standard cubic foot (gr/dscf), ranging from 0.0025 to 0.0100 gr/dscf. These concentrations yield emission rates that range from 0.26 to 0.99 lb/hr, and average 0.56 lb/hr.



## Table 2. Method 5 Results Summary

- Outlet

Emission Outlet Run Concentration Flow Rate Emission Rate Run# Times (gr/dscf) (dscfm) (#lhr) (lblton brick) 

### 1 1027-1133 0.0100 11528 0.99 0.066 2 1200-1303 0.0025 12279 0.26 0.018 3 1328-1432 0.0040 12531 0.43 0.029 Average 

### 0.0055 12113 0.56 0.038

### Air-Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (AT06-0396-HBC) Test Date: 11/30/2006- Page 4 

# 3.0 SAMPLING AND ANALYTICAL METHODS
The samples were collected from the exhaust of the brick kilns, a natural gas-fired process operating continuously 24 hours per day, seven days per week. There were no PM control of emissions from these sources; acid gases were scrubbed in a dry lime absorber prior to exhaust. A schematic of the process exhaust is contained in Figure 1.
Inlet samples were collected from a circular duct 55 inches in diameter. Two sampling ports, placed at right angles, provided for access for velocity traverses. A total of 12 points were sampled for velocity measurements. A schematic of this test location showing sample point location on the "Traverse Point Location Form" has been appended with the test data.
DLA outlet sampling was conducted at the exhaust stack from a duct 57 inches in diameter. This sampling location met the requirements of Method 1 allowing a 12-point particulate matter test to be conducted. A schematic of this location on the "Traverse Point Location Form" showing point placement has been appended as well.
Three one-hour samples simultaneously were collected from each sampling location. Concurrent with the testing readings of DLA pressure drop were made at the facility monitor, a photohelic differential pressure gauge. These readings were logged instrumentally at approximately 5 minute intervals by facility monitors. Sampling was performed according to the procedures of Method 26A at the outlet test location. These procedures entail isokinetic collection of a particulate sample followed by collection of acid gases in dilute solutions of sulfuric acid. A schematic of this sampling train is contained in Figure 2. Note that the caustic impingers used for the collection of diatomic halogens was not used.
The flue gas sample was withdrawn through a glass nozzle into a glass probe. Particulate matter was filtered through a heated Teflon filter and then entered the impinger portion of the sampling train. This impinger portion consisted of two impingers containing 100 ml of 0.1 N sulfuric acid each followed by an empty impinger, then a silica gel containing impinger used for final moisture collection. A type S pitot tube and type K thermocouple were used to measure velocity pressures and temperatures at each sampling point. A calibrated dry gas meter was used to measure sample volume. A calibrated orifice placed on the meter outlet was used to set sample rate.

### Air-Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (AT06-0396-HBC) Test Date: 11/30/2006- Page 5 

## Inlet sampling was conducted according to the procedures of Method 26. The nonisokinetic Method 26 sample was collected from three points at the inlet location. With the exception of not collecting a particulate fraction at the DLA inlet, sample recovery resulted in the collection of the following sample fractions.

• Acetone washes, with brushing, of those portions of the sample train upstream of the filter. • The filter. • The sulfuric acid impinger solutions and water rinses of all exposed glass surfaces downstream from the filter to the inlet to the silica gel impinger. • The silica gel.
Acetone washes were dried down in tared beakers for the gravimetric determination of weight gain. This gain, added to that determined for the tared filters, made up the particulate total of the sample. The total mass of PM collected was divided by the sample volume to determine particulate concentration (gr/dscf). This value was multiplied by flue gas flow rate to determine mass emission rate (lb/hr). Mass emissions were divided by production rates to determine emissions in terms of brick production rates (lb/ton). Complete example calculations as well as the analytical and run data have been appended.
The acid matrix samples were analyzed for fluoride and chloride ions following the ion chromatography analytical procedures of Method 26A. These analyses yielded liquid concentrations for the ions of interest (ug/ml). Conversions of ion concentration to acid concentration were made on a one to one basis. These acid concentrations were then converted to total mass of the compound of interest collected using the liquid sample volume. This total mass was then converted to mass rates for each sampling location in fashion similar to the particulate matter calculations. DLA removal efficiencies were calculated based on the calculated mass rates of the compounds of interest at the inlet and outlet. Complete analytical summaries and example calculations have been appended.
After noting the post test weight gain, the silica gel was discarded. This weight gain was added to that determined for the rest of the impinger train prior to sample recovery. The total weight gain of the impinger train was attributed to flue gas water vapor and used for flue gas moisture fraction calculations (Method 4 ). Flue gas fixed gas analysis was performed on bags collected during each test using the grab procedures of Method 3 using an Orsat combustion analyzer. These data, along with the velocity pressure and temperature (Method 2) determined each sample point (Method 1) during the performance of the isokinetic sampling were used to calculate flue gas volumetric flow rates used in mass rate calculations.KILN 3LK

Kiln Exhaust Fan Inlet Duct

Inlet Sampling Location 

# f

Ul 

### Air-Tech Environmental, LLC Hanson Brickl/Monroe, NC Test Report (AT06-0396-HBC) Test Date: 11/30/2006- Page 6



# ,--- 141.8"

DLA 

### 0 

# i (11.8') 

# l

DLA STACK 890.2" 

# [ t DLA Fan



### Figure 1. Process Schematic, Hanson BrickAirFlow

TypeS Pilot Tube Filter

Oven


# .. .. .. I •• lceBathl" 

# "I "I 

# .. 

# .. .. .. 

# .. .. .. 

# .. IH1 lii1



# .. .. 

# .. 

# .. .:: .::

Temperature Sensors • 0.1N H2S04 

### Air-Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (ATOG-0396-HBC)



# -

Empty Silica Gel (300 grams) Test Date: 11/30/2006- Page 7

Temperature Sensor

Vacuum Line



## Figure 2. Method 26A Sampling Train

### Air-Tech Environmental, LLC Hanson Brick//Monroe, NC Test Report (AT06-0396-HBCJ Test Date: 11/30/2006- Page 8 

# 4.0 QUALITY ASSURANCE 

# I QUALITY CONTROL
The Quality Assurance (QA) procedures required by the reference methodologies employed during the testing were strictly adhered to during the performance of this test program. Such adherence ensures production of useful and valid data throughout the course of the project. An analytical audit sample was not provided to 

## Air- Tech for analysis, therefore the measures made as described below comprise the analytical QA. Control criteria for these measures are not specified in the method. The QA procedures described in this section represent an integral part of the overall sampling and analytical scheme. The acceptance criteria, control limits, and the results of these measures obtained during this testing and analysis are summarized in Table 4. A brief discussion of the QA measures is presented below. QA measures taken to provide some assessment of the quality of sample collection included measures of sampling rate, and the assessment of the accuracy of metered gas volumes and the integrity of sampling train. Outlet sampling rates, assessed as % isokinetics, met method criteria for all test runs. Therefore, any sample bias caused by non representative collection of differing particle sizes (either particulate matter or water droplets) was within acceptable limits. The dry gas meters used for sample volume determination meet method criteria for accuracy. Post-test sample train leak checks meet the method criteria for all test runs. The analytical measures of QA meet the method criteria for acetone purity, an assessment of the Method 5 analysis. The Method 26A analytical QC relies on performance of an audit to be provided at the discretion of the SCDHEC. In absence of such a sample the analytical QA assessment was made based on the measurements tabulated in Table 4. These data show that the analysis suffered no significant bias due to the reagents or the sample matrix. All duplicate analysis show a precision of measurement of exceeding 2% of the reported value for all measurements. The calibration linearity indicates the results will be accurate regardless of where they fall on the calibration curve.

# I

a 

### Criteria

Sampling % lsokinetics
Dry Gas Meter Calibration (M26)

Post Test Calibration Check (M26A)
Sample Train Leak Rate (M26A)
Analytical Acetone Blank (M5) H2S04 Blank (M26A) Water Blank (M26A)

Matrix Spike Recovery
Duplicate Analysis, Inlet
Duplicate Analysis, Outlet

Calibration Linearity Air-Tech Environmental, LLC Hanson Bricki/Monroe, NC Test Report (AT06-0396-HBC) Test Date: 11/30/2006- Page 9 

## Table 3. QA 

## Summary, 

# I Control Limit 

# I Result 

# I

100 

## ± 10% Inlet NA Outlet 101.6- 102.7% 1.00 

## ± 2% Inlet 1.0052 Outlet 0.9961 

### yd 

## ± 5% Inlet 0.96 Outlet 1.03 <0.02 cfm Inlet 0.00-0.00 Outlet 0.00-0.00

:s; 

### 0.001 wt% O.OOOOg/1 00 results HF ND HCI 0.041Jg/ml a 

### HF ND HCI ND
Not specified HF 104% Not specified HCI 105% 

## ± 5% mean HF 0.0-0.6% 

## ± 5% mean HCI 0.0-0.2% 

## ± 5% mean HF 0.1 -1.5% 

## ± 5% mean HCI 0.0-2.1% Not specified HF R 2 

# = 0.9997 Not specified HCI R 2 

# = 0.9994 Value falls between the method detection limit and limit of quantization.

# I

a 

### Criteria

Sampling % lsokinetics
Dry Gas Meter Calibration {M26)

Post Test Calibration Check {M26A)
Sample Train Leak Rate (M26A)
Analytical Acetone Blank (M5) H2S04 Blank (M26A)

Water Blank (M26A)

Matrix Spike Recovery
Duplicate Analysis, Inlet
Duplicate Analysis, Outlet

Calibration Linearity 

### Air- Tech 

### Environmenta-t;t:t:cHanson Bricki/Monroe, NC Test Report (AT06-D396-HBC) Test Date: 11/30/2006- Page 9 

## Table 3. QA Summary 

# I Control Limit 

# I Result 

# I

100 ± 10% Inlet NA Outlet 101.6-102.7% 1.00 ± 2% Inlet 1.0052 Outlet 0.9961 Yct ± 5% Inlet 0.96 Outlet 1.03 <0.02 cfm Inlet 0.00-0.00 Outlet 0.00-0.00

:s; 

### 0.001 wt% O.OOOOg/1 00 HF ND HCI 0.09 tJg/ml a


### HF ND HCI ND
Not specified HF 104% Not specified HCI 105%
± 5% mean HF 0.0-0.6%
± 5% mean HCI 0.0-0.2%
± 5% mean HF 0.1 -1.5%
± 5% mean HCI 0.0-2.1% Not specified HF R 2 

# = 0.9997 Not specified HCI R 2 

# = 0.9994 Value falls between the method detection limit and limit of quantization.

# Appendix A Field Data Sheets and Run Summaries
Appendix A.1 Inlet Appendix A.2 Outlet

# Appendix A.1 Inlet

## Facility; 

## Date: Location: 

## Run Number: sample Type: Hanson/Monroe 

## 11i30i2006 Inlet Plant 3 

## R1 • Inlet HF/HCI



## Average Stack 

## Temperature 

## C'!=}**_§l1~~k_A~a** 

## _**_(~g** 

## lr1L

_____ ..... ___ _ Actual Meter Volume (cu ft) 

## Average Meter Pressure (in H20) Moisture Collected (g)

__ 

## Carbon Dioxide Concentration (% V) 

## Oxygen Concentration (%V) Dry Gas Meter Factor 

## Nozzle Diameter (in) Pitot**c~:mstant** 

## Standard 

## Metered Volume (dscf) Start**Time~** 

## End Time: Initial Leak Check: 

## Final Leak Check: 

## 0.000@5" 0.000@6" 1040 

## 1140

60.0 

## 29.55 -0.50

. ··-··**~-** ·-·



## 370.13. 

## 2375.83

---- -----·--····· 

## 34.44S 1.10 

## 92.75 134.10 

## 8.0 

## 13.0 79.0

. ----- ------·--·---------- ---- ... -. ..**·~--** 

### ------·· 

## 1.0052 

## NA 0.84 0.547 32.827 

## Standard Metered Volume (dsc@

__ _ __________ _ 

## 0.930 Staek Moisture 

# t% 'i)_

_ 

## 16,12 Mole Fraction 

## Ory Stack Gas 0.639 

## Qry Molecul!!r Weight 29.80 Wet MoJecular 

## We_ight__

___ _ 

## 27.90 931.65

--- ------- ----------------- - ----· ------------·········--·------------ --------------------- ---- --------- -----·--- 

## stack 

## Gas Velocity (mpm) Volumetric Flow Rate (acfm) 

## 15371.04 

## 435.31 Volumetric Flow Rate (dscfm) 

## 8097.97**VoJu.ITl_~tric_** 

## f"lo'J\f**R~t~_(d~cmrn)** 

## __________ ... 229.33 

## Percent lsokine-tic 

# ERR Percent Excess Air 165.15

-······---···---··---·····-- ··-··-·· --······--- ---·· ... -- ·--····---·· ··-- ···---··· -- 

## Concentration (g/dscm) 

## Concentration 

## (kg/hr) 0.00 

## Concentration (ppmv) 0.00 Emissions (lb/hr) 0.00

# Volumetric Flow Spreadsheet

Plant Hanson/Monroe Date Sampling Location Run Number Ambient Temperature (°F) Barometric Pressure (in Hg) Static Pressure (in H20) Operator Time

Traverse Point Number

A-1 A-2 A-3 A-4 A-5 A-6 A-7 A-8 B-1 B-2 B-3 B-4 B-5 B-6 B-7 B-8 Averages 11/30/2006 Plant 3 Inlet Run 1 86 29.6 -0.5 CFD IV 1040-1140
Velocity Stack Square HeaddP Ts Root of (in H20) (OF) dP

0.05 370 0.22 0.06 373 0.24 0.06 370 0.24 0.05 372 0.22 0.04 374 0.20 0.04 370 0.20 0.04 372 0.20 0.04 360 0.19 0.05 370 0.22 0.06 370 0.24 0.06 370 0.24 0.07 370 0.27 0.07 371 0.26 0.07 371 0.25 0.06 371 0.25 0.04 371 0.21 370.31 0.23

Actual Volumetric Flow Rate (acfm) Standard Volumetric Flow Rate (scfm) Dry Standard Volumetric Flow Rate (dscfm) 02 Percent C02 Percent N2 Percent Stack Moisture(%) Mole Fraction (dry) Molecular Weight (dry) Molecular Weight (wet) Stack ID (in) Stack Area (sq 

### ft)

Stack Gas

Velocity

(fps) 16.10558 17.67465 17.64278 16.12498 14.43995 14.40527 14.42262 13.39345 15.61494 17.19606 17.34624 19.59329 18.79349 18.37425 17.94522 15.11748

16.51

16345.60 10270.30

8614.73 Stack Gas Velocity

(fpm) 966.33501 1060.47902 1058.56696 967.49900 866.39727 864.31631 865.35741 803.60684 936.89655 1031.76345 1040.77465 1175.59727 1127.60951 1102.45520 1076.71340 907.04871

990.71 13 8 79 16.12 0.8388 29.8 27.89784 55 16.49881559**Ar~** FIELD OAT A SHEET

Run-1-

**,~----** .. **-~---** --- --------- -·---------- ---·· l@···---

-----------

Plant :JJAAJ

S' Dll"' g,i .._j, Probe Length & Type /b I **(;1114-~'!1** Filter Number **l'l~Lo t~o~** 

A?.- 2 **~**

Date· It /io

**lt.u<~** Nozzle ID (in.) AJ 114

Height of Location (ft) ""' '2,....,, b

sad.i)lrng.Location, **1.:~-'- ~-\-?..**  Pilot Constant .84 Duct Dimensions (in.) **~**

...... 7-5"'M, $'TTl

**~**

Sample Type ·"· **~** '· Meter Box Number A"r D Stack Geometry (R or C) c ..._

.. :......•

Run Number **~I**

- **~f'l** MeterAH@ {.

**7~3_** Assume Moisture (%) II __::;> **~ ~** 
:.......

Operator **C..\'::0~**

j.

**oos~** 02 (%) 13 lr@)

-

Yd **~**

Ambient Temperature 9!tJ)o,;. K Factor "'/Jf C0 2 (%) **~ ~~,---_j** 

Barometric Pressure (ln.) ;;.q. t. 0 Probe Heater Setting (°F) :;.so Nitrogen (%) .. 79

Static Pressure (ln. H 2 0)

' I S'O Heater Box Setting (°F) **~so** Moisture Collected (g)

Initial

Leak Check **lo.oool?_~** Final Leak Check **~~/)047** e r, ·'b.. ---------- --- ---------

, ·-

· ram of uctl

·-----

- vel]

---------- .---------

·---------·--· ·-- ·-· ---· --- -- ---- . - ··-·

ReadandR· ·dAI/Data E g (Diag

Mt

Sampling Gas Meter Dry Gas Meter

Velocity

Orifice Temperature

Traverse Time Clock Time Reading

Head Pressure Flue Gas Probe Filter lmpinger Pump

Point (min) (24-hr) vm (ftl)

AP Differential Temperature Temperature Temperature Inlet Outlet Exit Vacuum

Number (in. H

2 0) AH (in. H

2 0) c·F> c·F> c·F> c·F> c·F> ("F) (in. Hg)

A I 0 1oUn I

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7 o. oc-:z. '3'77

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In Dift./

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-- ------ -----------·- ------ . ---- ---- ---· . ----- ---- **----~** ···-. ·- ·-· ----------------- ----------- -. - .. , - . -- . - - ·- -- .... -

# MOISTURE RECOVERY FORM FOR METHOD 4

Plant 

# J111JII I 

## tJ rt 

## Date 

# !I- 3() -ofa Samollna Location 

# --tAll{_,+ Run Number 

# I

.. 

## lmolnaer Box Number Recoverv Person Recoverv Rinses Samolina Identification Filter Number 

## D 

# It,

**j.(~** 

### D 

## :A _.

**,2~** 

## _XAO Number

Amount of lmpinger Weight lmpinger lmpinger Solution lmplnger Tip Final Initial Weight Gain Number Solution (g) Configuration (g) (g) (g)


### 1 t 

# /;U

**~ ~()y**  I ()0 rttL 

# Af]G-) i-& 

# t.

**~** 

# &11- 5

2 

# , lrJ 

# liz

**~** 

# Y

**o~** 

# 111L 

# &:; +Yt-+ 7();!' 

# 8

3 

# bu-1.;1 f) 

# fV1 

# C-5 (,31_ 

# I" £-;3, <f

4



# ~t:-1 **,~I** ?



# ~W\ L-. 

# ;/)

**(_,~** 

# '1t<\.q

**1~9,** 

# _]

5

6

7



### 8

9



### 10
Total Weight Gain (g) 

# \

**?7~** I 

# I

### Facility: Hanson/Monroe Start Time: , 153 

### Date: 11/30/2006 Erid Time: 1253 Location: h11et Plant 

## 3- Initial Leak Check: 0.000@5" Run Number: R2- lrHef Final Leak Check: 0.000@5" 

## sample Type: HF/HCI
Total Sampling Time (min) 60.0 Corrected Barometric Pressure (in Hg) 29.59 Absolute Stack Pressure (in Hg) 29.55 Stack Static Pressure (in H20) -0.50 Average Stack Temperature COF) 369.38 Stack Area (sq in) 2375.83 Actual Meter Volume (cu ft) 34.789 Average Meter Pressure (in H20) 1.10 Average Meter Temperature COF) 99.63 Moisture Collected (g) 134.40 Carbon Dioxide Concentration (% 

### V) 6.5 Oxygen Concentration (% 

### V) 12.0 Nitrogen Concentration 

### (o/oV) 81.5 Dry Gas Meter Factor 1.0052 Nozzle Diameter (in) NA Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.545 Standard Metered Volume (dscf) 32.725 Standard Metered Volume (dscm) 0.927 Stack Moisture 

### (% V) 16.20 Mole Fraction Dry Stack Gas 0.838 Dry Molecular Weight 29.52 Wet Molecular Weight 27.65 Stack Gas Velocity (fpm) 1029.38 Stack Gas Velocity (mpm) 313.75 Volumetric Flow Rate (acfm) 16983.53 Volumetric Flow Rate (acmm) 480.97 Volumetric Flow Rate (dscfm) 8947.86 Volumetric Flow Rate (dscmm) 253.40 Percent lsokinetic ERR Percent Excess Air 125.89 Concentration (g/dscm) 0.00 Concentration (kg/hr) 0.00 Concentration (ppmv) 0.00 Emissions (lb/hr) 0.00

# Volumetric Flow Spreadsheet

Plant Date Sampling Location Run Number Ambient Temperature CF) Barometric Pressure (in Hg) Static Pressure (in H20) Operator Time

Traverse Point Number

A-1 A-2 A-3 A-4 A-5 A-6 A-7 A-8 B-1 B-2 B-3 B-4 B-5 B-6 8-7 8-8 Averages Hanson/Monroe 11/30/2006 Plant3 Inlet Run 2 85 29.6 -0.5 CFDIV 1153-1253
Velocity Stack Head dP Ts (in H20) 

### r•FJ

0.07 367 0.07 371 0.07 370 0.06 371 0.06 373 0.05 369 0.04 367 0.04 367 0.05 370 0.06 370 0.06 370 0.06 369 0.06 370 0.05 370 0.05 369 0.04 368 369.44

Actual Volumetric Flow Rate (acfm) Standard Volumetric Flow Rate (scfm) Square Root of

dP 0.25 0.26 0.26 0.24 0.24 0.22 0.20 0.20 0.22 0.24 0.24 0.23 0.24 0.22 0.22 0.20 0.23

Dry Standard Volumetric Flow Rate (dscfm) 02 Percent C02 Percent N2 Percent Stack Moisture(%) Mole Fraction (dry) Molecular Weight (dry) Molecular Weight (wet) Stack ID (in) Stack Area (sq ft)

Stack Gas

Velocity

(fps) 18.41068 19.15183 19.14030 17.73115 17.75248 16.16675 14.44252 14.44252 16.17650 17.72047 17.72047 16.95583 17.72047 16.17650 16.16675 14.45126

16.90

16725.25 10519.93 8815.70 Stack Gas Velocity

(fpm) 1104.64059 1149.10969 1148.41783 1063.86885 1065.14879 970.00512 866.55137 866.55137 970.59021 1063.22831 1063.22831 1017.34996 1063.22831 970.59021 970.00512 867.07532

1013.72 12 6.5 81.5 16.2 0.838 29.52 27.65376 55 16.49881558526**At~** Plant Date ·"t·' SartiJ)IIhg .Location. Sample Type !• .•' ..
Run Number Operator Ambient Temperature Barometric Pressure (ln.) Static Pressure (ln. H 2 0)
Initial Leak Check Sampling Traverse Time Point

(min) Number

Jl I {')

z_

s

3 **I~**

" ZJ.I

'5 32..

c... C/o

'7 **f(~**

f> **s~** ltlo

il I l. J lf s **~** 2 6 -------- L- -- **---~-** --- FIELD DATA SHEET **Jrt~~-~** l. 'C. --- -----·- - --·-------

I-f

**lf-rJ~o~** Br; ,\L Probe Length & Type **~I** L!h.s. **~** Filter Number **O<.(r,O~-** Z.$"

It

J?.o/-z.oo'-" Nozzle ID (in.) N }I+

Height of Location (ft) '-" 2-{) I

r .... **t~!** P"'-* 3 Pilot Constant .84 Duct Dimensions (in.) SS'' 7. s';\,.;

**~ ~c..r.....** 

Meter Box Number A 11::> Stack Geometry (R or C) (!_,

f!..'--ItJ Meter 6H@ **/.?S~** Assume Moisture (%) II

C.r-'t:> **~** Yd I ·OOS2- 02 (%) /2- **5~~**

as·F- K Factor N/Jif C0 2 (%) **~-!>**

;J-9·/f'.)D Probe Heater Setting ("F) :2S'o Nitrogen(%)

- o ·s-o Heater Box Setting ("F) **~s-o** Moisture Collected (g)

**~** . /J?"}D

**tO~~** Final Leak Check **ltJ,OD~ ~$''/A**  ' '"

Read and Record All Data E B

Mt :vef]

-------·-
--------- ,-----

... ------- --· -- ..

Gas

Meter Dry Gas Meter

Velocity

Orifice Temperature

Clock Time Reading

Head Pressure Flue Gas Probe Filter

(24-hr) vm (ft 3 ) 6P Differential Temperature Temperature Temperature Inlet Outlet

(in. H 2 0) 6H (in. H 2 0) c·F> c·FJ c·F> c·F> c·FJ

IIS'3 '111. J.-2'Z., CJ

**·OU.~** 1 j

**3~7** _<.so :J.SD 9s- 9r

I9A/. 9o

,..., 0'7 37__/ 2.5.;--

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9_'1__/, 3o Q_. !2{t:L

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Cfl:j..>., 2.. a.of.l

373 G.s-o 2..<(9 tOt/ 97

**/a~YJ. q~** 

CJ ·.OS' **~~9** Zl/<1 2-t/611 **/L).~** q/

**lloo~** . **o~** n.nt/ **~ltl7** ,2,t:;(J -:::J.tc;"/ lbS" 9'7

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.. -···- -- ---------- -- -·- lmpinger Pump

Exit

Vacuum

c•FJ

(in. Hg) &t, } **~2.** / SB I ss / 59 I **s~** 1 **5"~** I **~c,.** I '

# MOISTURE RECOVERY FORM FOR METHOD 4

Plant 

## AIJ/Jr!}t Date 

# II- 5!J -Of, Samolina Location 

# :[;zjblRun Number

.. 

# r2 lmolnaer Box.Number Recovery Person Recovery Rinses Samp_lina Identification Filter Number

**()0l~{).2-** r;). 

# '-1 XAD Number

Amount of lmpinger Weight lmpinger lmpinger Solution /mplnger Tip Final Initial Weight Gain Number Solution (g) Configuration (g) (g) (g)
1 

# ,f N 

# {5oy ;ofJ 

# t11L ;Vl 

# G- 

# s 82 '( 

# _q 1J.V. 

# i

2 

# ./tJ ;/z)otf 

# !PO 

# m( 

# &-S ¥3

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# /32-1

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# {Wl(Jfj 

# 0 

# ;#1 &5 Co2 J 

# .s 619.0

4 

# )



# ~ 1 Jtf

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# ;vl&S '132.8 

# 91 '/.?

5



### 6

7

8

9



### 10
Total Weight Gain (g) 

# \)

**~** 

# ·i

### Facility: Hanson/Monroe Start Time: 1300 Date: 11/30/2006 End Time: 1400 Location: Inlet Plant 3 Initial Leak Check: 0.000@5" Run Number: R3- Inlet Final Leak Check: 0.000@5" Sample Type: HF/HCI
Total Sampling Time (min) 60.0 Corrected Barometric Pressure (in Hg) 29.59 Absolute Stack Pressure (in Hg) 29.55 Stack Static Pressure (in H20) -0.50 Average Stack Temperature (°F) 368.63 Stack Area (sq in) 2375.83 Actual Meter Volume (cu ft) 34.708 Average Meter Pressure (in H20) 1.10 Average Meter Temperature (°F) 101.81 Moisture Collected (g) 133.80 Carbon Dioxide Concentration 

### (% V) 5.0 Oxygen Concentration 

### (% V) 13.0 Nitrogen Concentration 

### (% V) 82.0 Dry Gas Meter Factor 1.0052 Nozzle Diameter (in) NA Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.542 Standard Metered Volume (dscf) 32.518 Standard Metered Volume (dscm) 0.921 Stack Moisture 

### (% V) 16.22 Mole Fraction Dry Stack Gas 0.838 Dry Molecular Weight 29.32 Wet Molecular Weight 27.48 Stack Gas Velocity (fpm) 1006.85 Stack Gas Velocity (mpm) 306.89 Volumetric Flow Rate (acfm) 16611.84 Volumetric Flow Rate (acmm) 470.45 Volumetric Flow Rate (dscfm) 8757.32 Volumetric Flow Rate (dscmm) 248.01 Percent lsokinetic ERR Percent Excess Air 150.04 Concentration (g/dscm) 0.00 Concentration (kg/hr) 0.00 Concentration (ppmv) 0.00 Emissions (lb/hr) 0.00

# Volumetric Flow Spreadsheet

Plant Date Sampling Location Run Number Ambient Temperature (°F) Barometric Pressure (in Hg) Static Pressure (in H20) Operator Time

Traverse Point Number

A-1 A-2 A-3 A-4 A-5 A-6 A-7 A-8 B-1 B-2 B-3 B-4 B-5 B-6 B-7 B-8 Averages Hanson/Monroe 11/30/2006 Plant 3 Inlet Run 3 86 29.6 -0.5 CFDIV 1300-1400
Velocity Stack HeaddP Ts (in H20) (oF)

0.06 366 0.06 367 0.07 371 0.07 369 0.06 370 0.05 367 0.04 368 0.03 371 0.05 365 0.06 366 0.07 366 0.06 367 0.06 368 0.06 367 0.04 366 0.04 366 367.50

Actual Volumetric Flow Rate (acfm) Standard Volumetric Flow Rate (scfm) Square Root of

dP 0.24 0.24 0.25 0.26 0.24 0.22 0.20 0.17 0.23 0.24 0.26 0.25 0.25 0.24 0.20 0.20 0.23

Dry Standard Volumetric Flow Rate (dscfm) 02 Percent C02 Percent N2 Percent Stack Moisture (%) Mole Fraction (dry) Molecular Weight (dry) Molecular Weight (wet) Stack ID (in) Stack Area (sq ft)

Stack Gas

Velocity

(fps) 17.73225 17.74298 18.51211 19.18778 17.77515 16.19705 14.49584 12.57650 16.49783 17.73225 18.59774 17.89023 18.19214 17.74298 14.47832 14.47832

16.86

16694.50 10525.17 8817.99 Stack Gas Velocity

(fpm) 1063.93492 1064.57899 1110.72640 1151.26683 1066.50888 971.82321 869.75067 754.58999 989.86954 1063.93492 1115.86435 1073.41382 1091.52843 1064.57899 868.69922 868.69922

1011.86 13 5 82 16.22 0.8378

29.32 27.483896 55 16.49881558526**An~. tY/M~Or£**  MC Run_l_ Page _f_ of _f_

FIELD DATA SHEET

t/.,.IA,.,_,g Ar.-tJir... ----

Plant Probe Length & Type <4'

**~/~s** Filter Number tJ(,ffiO't

**-~'5** ---·- ------·--]

Date tl/311/% •• **~** Nozzle ID (in.) "";,.

Height of Location (fl)

- Zo'

·-i·

. San'lpllng .Location_. **~!o. P/,...~3**  Pilot Constant .84 Duct Dimensions (in.) **.~S'' 7..5'~.1!?** 

Sample Type .'• r., HF HCL. Meter Box Number 4-TD Stack Geometry (R or C) c.

..
Run

Number IJ..) -.&-A) Meter aH@ /. ? t!fi' ') Assume Moisture(%) (/

Operator C.r-o '1Z. Yd I. oo-s-z... 02(%) I 3 **tr~** t}.

Ambient Ternperature gc.··£ K Factor pL,_

C0 2 (%) 5"'

Barometric Pressure (in.) ;::z. 9.

**~** t:) Probe Heater Setting ("F) 2r-n Nitrogen(%)

Static

Pressure (ln. H

2 0)

- I!J. s-o Heater Box Setting ("F) 2)1> Moisture Collected (g)

Initial

Leak Check **~~-(X)(;)** ,?c;-•c k, Final Leak Check i?--oe- e s;

**'1;~,** . ____ .• j (Diagram

of Duct)

Read and Record All Data E B

M,· .----.-------.-------

:ven __

,______ ,------···· ·--------·--··· -·· _ ___ _ ___ . _ .. ____ _

Dry Gas Meter

Sampling Gas Meter V 1 't

0 'fi

Temperature

Time Clock Time Reading e OCI Y n Ice . .

Traverse ( . ) (

24 _h ) V (fl 3 ) Head Pressure Flue Gas Probe F11ter lmpmger Pump

Point mm r m 4P Differential Temperature Temperature Temperature Inlet Outlet Exit Vacuum

Number (in. Hp) "H (in. H 2 0) ("F) ("F) ("F) ("F) ("F) ("F) (in. Hg)

A f a 1'3 o o I 1.. • I **~** I D.

**o~** I

. I '3

**~** II "Z. **~** .o **z...~** 1:1 q q 9 g t'., 7 1

t Jt

ll._ ._"ls-

'1'1. o c...._ **3.~.,** Z.S'C'J **:2.~13** /01::;' 99 **~liP** I

J **/~** '2 /. 3 '7 n.

**tJI~f(** '9"7 I 2/of;

**2-w~** /1-1 '" 9 9 c.. e:;- I

_t_ Z.o.f **-~**

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**Z..t.j__~ /nt..~_**  q 9 SL. /

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\. --·-·--------- --------- ---- ... ---- -··· ------------------------· ------------------------------------------ -- ..... ------

# MOISTURE RECOVERY FORM FOR METHOD 4

Plant 

# Jl/1 tlrlm fJ Date 

# ;/- "J()

**~o** 

# k SamDIIna Location



# ~ltdRun Number 

# t1 lmDinaer Box ·Number Recovery 

# Person Recovery Rinses Sampling Identification Filter Number 

# Dfo 

# /h tJd.
-

**~0** _XA[) tdll

...



### Amount of lmpinger Weight lmpinger lmpinger Solution lmplnger Tip Final Initial Weight Gain Number Solution (g) Configuration (g) (g) (g) 

### 1 I



# ;;v4f~ f(}tJ 

# 41-1_

**)/1_~** 

# €17-.i /3/. 

# I

2 

# ,I 

# ,.u 

# l-Iz {or 

# I tJ!J



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# [r!J

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# 7Y:Z, 

# 7

3 

# £f'Vll+) {j



# M&~



# ~r9.G 

# &17- 

# 3

4 

# 5e);e / ;7o

**/It~** 

# !L1 &-:S 

# b9&'.

**~** 

# fJfO. 

# g

5



### 6

7



### 8

9



### 10
Total Weight Gain (g) 

# \)



# )~~

# Appendix A.2 Outlet

### Facility: Hanson/Monroe Start Time: 1027 Date: 11/30/2006 End Time: 1133 Location: Outlet Initial Leak Check: 0.002@15" Run Number: R1 Final Leak Check: .000@8" Sample Type: M5/HF/HCI Total Sampling Time (min) 60.0 Corrected Barometric Pressure (in Hg) 29.70 Absolute Stack Pressure (in Hg) 29.69 Stack Static Pressure (in H20) -0.08 Average Stack Temperature CF) 338.67 Stack Area (sq in) 2551.76 Actual Meter Volume ( cu ft) 37.060 Average Meter Pressure (in H20) 1.27 Average Meter Temperature CF) 76.63 Moisture Collected (g) 130.20 Carbon Dioxide Concentration 

### (% V) 8.0 Oxygen Concentration 

### (% V) 13.0 Nitrogen Concentration 

### (% V) 79.0 Dry Gas Meter Factor 0.9961 Nozzle Diameter (in) 0.409 Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.603 Standard Metered Volume (dscf) 36.167 Standard Metered Volume (dscm) 1.024 Stack Moisture 

### (%V) 14.49 Mole Fraction Dry Stack Gas 0.855 Dry Molecular Weight 29.80 Wet Molecular Weight 28.09 Stack Gas Velocity (fpm) 1159.83 Stack Gas Velocity (mpm) 353.52 Volumetric Flow Rate (acfm) 20552.78 Volumetric Flow Rate (acmm) 582.05 Volumetric Flow Rate (dscfm) 11528.35 Volumetric Flow Rate (dscmm) 326.48 Percent lsokinetic 101.55 Percent Excess Air 165.15 Concentration (g/dscm) 0.00 Concentration (kg/hr) 0.00 Concentration (ppmv) 0.00 Emissions (lb/hr) 0.00

# Volumetric Flow Spreadsheet

Plant Hanson/Monroe Date Sampling Location Run Number Ambient Temperature (°F) Barometric Pressure (in Hg) Static Pressure (in H20) Operator Time

Traverse Point Number

A-1 A-2 A-3 A-4 A-5 A-6 B-1 B-2 B-3 B-4 B-5 B-6 Averages 11/30/2006 Plant 3 Outlet Run 1 68 29.74 -0.08 GJ 1Q27-11JJ
Velocity Stack Square HeaddP Ts Root ol (in H20) (OF) dP

0.08 340 0.28 0.07 339 0.26 0.07 339 0.26 0.07 340 0.26 0.08 338 0.28 0.07 338 0.26 0.07 340 0.28 0.08 338 0.28 0.08 339 0.30 0.09 339 0.28 0.08 337 0.26 0.07 337 0.25 0.07 338.67 0.27

Actual Volumetric Flow Rate (acfm) Standard Volumetric Flow Rate (scfm) Dry Standard Volumetric Flow Rate (dscfm) 02 Percent C02 Percent N2 Percent Stack Moisture(%) Mole Fraction (dry) Molecular Weight (dry) Molecular Weight (wet) Stack ID (in) Stack Area (sq ft)

Stack Gas

Velocity

(fps) 19.87448 18.57924 18.57924 18.59087 19.84961 18.56761 19.87448 19.84961 21.06688 19.86205 18.55597 17.88098

19.26

20478.84 13454.48 11504.93 Stack Gas Velocity

(fpm) 1192.46852 1114.75451 1114.75451 1115.45216 1190.97642 1114.05643 1192.46852 1190.97642 1264.01281 1191.72270 1113.35791 1072.85853

1155.65 13 8 79 14.49 0.8551

29.8 28.09018 57 17.72054606**Ar~ ~-**  FIELD OA l A. SHEET

**;~** ·-· ·-. ··--··· ------------- -- ___ , 6Ji:---,---------··---··-------- _______ .. __ ..... _____

Plant

Probe Length &Type lb **~5**

·Filter Number **07~'1·** d'I,O

Date **tl-30~011** Nozzle ID (in.) .L/01 Height of Location (fl) fiD '

sail,prtng -Location. At.

**~...J..I~** J.

Pi tot. Constant .84 Duct Dimensions (in.)

**<57~**

Sample Type .... .M5: flcJ.. lfP Meter Box Number A-Tf>

Stack Geometry (R or C) C_

.. . - . I •. /. 8DV.

· . tl

Run Number ., Meter t.H@ Assume Moisture (%)

Operator t'__;]

Yd ,

**qq~** I

·' 02 (%) /:::,

Ambient Temperature **~8** K Factor

**,~.,.c,** . C0 2 ('Yo) **~**

..21.:7¥ ..

Barometric Pressure (in.) Probe Heater Setting COF) + 24fZJ Nitrogen(%)

Static

Pressure (ln. H

2 0) -.05

Heater Box Setting (°F) '!.. **z~o··**

Moisture Collected (g) i

Initial

leak Check J2 .pO

**~A)j** ') **-~f** ___ Final Leak Check L>t>o [;) _8!-'------·

_·

___ ... __ ,
.-----.------··· __________ **-~---·** ·- __ .. ____ --,---- **_fJ~d** and Record

**~IJ** Dat<!__qf!!Y.. J **Mif!~S------.---·--** __ _

Traverse Point Number A.-' < Ll :1 2 rA- Ia < '1 .::; 2 I Sampling Time (min) () c; tt> !5 Z/) 2t:; :70 .7S "Lib C/5 SD 55 (;l5 Clock Time (24-hr) 110'-t **A~'1 ....,-v~**  ll"" v iJ33 Gas Meter Reading v .. (ft 3 ) IRlfl. 7D **r-g-,~·.oo '~,tfi_qo**  **~iB.** 55 21. Btl **~~v: <~**  CJ 111' '1 </ **~~-8,** '3'1. 0.3 **~1n 'r1vo~**  **~a ~'l:f.7S**  ettt,.760 Velocity Head t.P (in. HPJ (Jfl ,{:Jr; ,{1 '1 **0~** tJR

• tJ I **_~_a-z..** .6 -Ol

a<. z,c **.6~ ~.a**  1 Orifice Pressure Differential **t.H~(in.** H 2 0) **I~** 3

**~** -r:•" i. I j l. I R

La· ,_-, fJ.. **1-1~** .35 ,(35 .-5i. **~** t. t **~** Flue Gas Probe Temperature I Temperature

(of) (of) 31./0 **2~0** 33G **,;t~j** 3'39

.2..'5)

3_ 1.[0

**26~** t33fi

.:J.i{)

J3S **2.~** I **~CfD**

_2_d_j **3~1f** .:J,

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..il 5 ()

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L of _j__

., --------1 I I

6

. __ ·________

_ ___ **[_tlJ~** (Diagram of Duct) ·-··- . ") I I lmpinger Pump

Exit

Vacuum

("F)

(in. Hg)

# MOISTURE RECOVERY FORM FOR METHOD 4

Plant 

# J1.t? lr.f() 

# e Date

**!!.~** )tJ -0 

# f, Samllllna • 

# .. n

**tJJ/~_)** Run Number ·. ,.

**~** 

# I lmDinaer 

# Box Number

--· .·· 

## Recoverv Per8on Recoverv Rinses Samglina Identification Filter Number 

# D 7.26o 

# '-1 

# -ovo XADNlJ .L



### Amount of lmpinger Weight lmpinger lmpinger Solution lmplnger Tip Final Initial Weight Gain Number Solution (g) Configuration (g) (g) (g)


### 1 

# ./N

**YL~"i** /DO 

# NtL f{L- 

# s 4

**~0(,** 

# 7 2 

# 5

. .2.__

2 

# .ftv

**tJl~f)y** 

# roD J1!VL 

# [,--)

**~6.fr** 

# 712-1

3 

# fYVtfj 

# 0 

# ;Vl&S b { 

# LJ

**-~** 

# frJCJ2. 

# '7

4



# ~~('?~' l) K t'V\ 

# l-- 

# /lu.S

**&~~.** 

# q

**g~:,8.** 

# 8

5

6

7



### 8

9



### 10
Total Weight Gain (g) 

## I (;O

. 

### :b-

### Facility: Hanson/Monroe Start Time: 1200 Date: 11/30/2006 End Time: 1303 Location: Outlet Initial Leak Check: 0.003@15" Run Number: R2 Final Leak Check: .000@5" Sample Type: M5/HF/HCI Total Sampling Time (min) 60.0 Corrected Barometric Pressure (in Hg) 29.70 Absolute Stack Pressure {in Hg) 29.69 Stack Static Pressure (in H20) -0.08 Average Stack Temperature CF) 335.75 Stack Area (sq in) 2551.76 Actual Meter Volume (cu ft) 39.777 Average Meter Pressure (in t-120) 1.44 Average Meter Temperature CF) 75.00 rv'Joisture_ Collected (g} _. 140.80

- ---- ·-- ·--- ... - ·--- 

### Carbon Dioxide Concentration 

### (% V) 6.5 Oxygen Concentration 

### (% V) 12.0 Nitrogen Concentration 

### (% V) 81.5 Dry Gas Meter Factor 0.9961 Nozzle Diameter (in) 0.409 Pitot Constant 0.84 Aver?_ge Sampling Rate**(d~cfm)** 

### 0.649

. ------ ------ --- ·- -·-- 

### Standard Metered Volume (dscf) 38.952 Standard Metered Volume (dscm) 1.103 Stack Moisture 

## (%\i) 14.54 Mole Fraction Dry Stack Gas 0.855 Dry Molecular Weight 29.52 Wet Molecular Weight 27.85 Stack Gas Velocity (fpm) 1231.61 Stack Gas Velocity 

## (mpm) 375.39 Volumetric Flow Rate (acfm) 21824.77 Volumetric Flow Rate (acmm) 618.08 Volumetric Flow Rate (dscfm) 12279.47 Volumetric Flow Rate (dscmm) 347.75 Percent lsokinetic 102.68 Percent Excess Air 125.89 Concentration (g/dscm) 0.00 Concentration (kg/hr) 0.00 Concentration (ppmv) 0.00 Emissions (lb/hr) 0.00

# Volumetric Flow Spreadsheet

Plant Date Sampling Location Run Number Ambient Temperature (°F) Barometric Pressure (in Hg) Static Pressure (in H20) Operator Time

Traverse Point Number

A-1 A-2 A-3 A-4 A-5 A-6 B-1 B-2 B-3 B-4 B-5 B-6 Averages Hanson/Monroe 11/30/2006 Plant3 Outlet Run 2 68 29.74 -0.08

CJ 1200-1303
Velocity HeaddP (in H20}

0.08 0.09 0.09 0.09 0.08 0.08 0.08 0.09 0.09 0.09 0.08 0.08 Stack Ts (oF} 339 336 336 336 335 335 338 335 335 336 334 334 33§,7§

Actual Volumetric Flow Rate (acfm) Standard Volumetric Flow Rate (scfm) Square Root of

dP 0.28 0.30 0.30 0.30 0.28 0.28 0.28 0.30 0.30 0.30 0.28 0.28 Q,29

Dry Standard Volumetric Flow Rate (dscfm) 02 Percent C02 Percent N2 Percent Stack Moisture(%) Mole Fraction (dry) Molecular Weight (dry) Molecular Weight (wet) Stack ID (in) Stack Area (sq ft)

Stack Gas

Velocity

(fps} 19.94930 21.11965 21.11965 21.11965 19.89928 19.89928 19.93681 21.10638 21.10638 21.11965 19.88676 19.88676

2Q,§1

21809.52 14381.26 12290.22 Stack Gas Velocity

(fpm} 1196.95804 1267.17914 1267.17914 1267.17914 1193.95697 1193.95697 1196.20848 1266.38261 1266.38261 1267.17914 1193.20553 1193.20553

12JQ,7a 12 6.5 81.5 14.54 0.8546

29.52 27.844992 57 17.72054606165. ArR/_ **-~**

I Plant !U:77d

JVL.l

Probe Length

**~~~~~------r6 7**  **/~;;--l-Filter~~mber** FIELD OAT A. SHEET -·----,------- 0 7 J_cc V -tJ<t_j_

Date **I~~** ..-C6 **j_t>l<:>;zz~** l()_(in.} I . '/09 I Height of Location (ft) BDJ

sa'ri;pllng.Location.

I t>c..Jit.-.J- I Pilot Constant I

.84 I Duct Dimensions (in.)

**~·7** II

Sample

Type I **M~** J.l..t/.... .t-1-fr I

Meter Box Number I _f±Tfb I Stack Geometry (R or C) c..

Run Number I 4.,. ' I

Meter <1H@ I 1: B 0 '/ Assume Moisture (%) I {

Operator I G ;5' I

Yd I·· ,_9i_'-_l 02 (%} J;;L

AmblentTemperature I **~.B._~** _____

**jK_F=a~or_** _ I f,,q

C02(%) & '<;

Barometric Pressure (in.) I ..1 e;

. 1 'f I

Probe Heater Setting ("F) I t .2--..in Nitrogen(%}

Static

Pressure (ln. Hp) I

-. 0 f3 I

Heater Box Setting ("F) I -!.. ..2 '$ 0 Moisture Collected (g)

Initial

Leak Check **-'"·t!)Q_3_£).-112~J.Final** Leak Che;k

**p~~$;}~** ____ -··- ________

_

Traverse Point Number **~-ec,** 5 **~** _2 ' **A~t,** r--·

L

oC q 3 2.

[ ___ ---- Sampling Time (min) f> 5 _LC> t.S _2A 2> JO _a5 **~.tO _L/~**  ;SO 62 b() ...., __ ---.--- ____ --,------- _ **----.----f!~nd** Record All Data

**Eve~** $ Minutes_

- -,--- .. - -D-;}.-Gas Meter Temperature

Clock Time (24-hr) __Ll,/JO ... n **II~** tOO **I~A3** Gas Meter Reading vm (ft 3 ) 1(_,:'}l_lJ l!fJ() .. 2.0 **~3.-G,O e~r98**  **~UJ.</5 "-3~8_**  fl,iJ.BI '71J.oo 'Jl3. "'" )7,-_ **g~ ~B(J.30**  **~83.S2..** fJB6. 737 Velocity Head <1P (in.HzO) **3~**

. IJ '1 "' **__.._0~** D3 _,_()_ **~** 08

.. Oq **~ ~«1**  **~** .,02:) ,l) f\ Orifice Pressure Differential <1H (in. HzO) f.as /.6<.. **/.~2** :L-.5"2.. I·'?.C: .... **,.,.~** J.J_.S /. **3~** I. 1>'< ti.-5.l. (). 5 l.. **~** fJS i3$ Flue Gas Temperature ("F) 33q J3(, 33G, **-~** sc:r< **.~-as (~a~**  **33~.··** ..J.a5_ 3'3Ct, 3Blf 3tJ If Probe Temperature ("F) d--YS: **~!:LB.** 2¥-. 2-ell .!:l 't'G **~tjd_** .z_yq 256 -2-- 't Cj **d'l~** .:1'19 **,;2.~-** Filter Temperature ("F) 2'5 { **_..2.~() .2~{)**  2S_l 2111 _..2'5'2. .#'5 I 2<£s:t **.:2-~~** .:1 **"'~ ~-6().**  **.2~"0** Inlet (oF) -7'1 7_S_ 7'5 15_ 7ft, 77 **~** '7/ ..:lfi '1t:t ,q 7!7- Outlet ("F) 7<- 7..3 7t3 _7_3 73 7<.3_ _'2_3_ 7,1 ?C/ 7_V_ 7S /_"(_ Run£ Page

_j_ of L

,, --· - ---- .. ----1 **~** A-- I

lb

0 :J (Diagram of Duct) lmpinger Exit ("F) **---;~ZJ** _S__Z_ **s-~** _6.3 **~,1** 6Y _;5_({ **~-c;,-** -sz:. **_6_~** 67 S7 Pump Vacuum (in. Hg} s **~** S' S_ 3- _5 s s c:-· g_ :-so ,5_ I I

# MOISTURE RECOVERY FORM FOR METHOD 4

Plant 

# 41 tJI1. ( () 

# f Date 

## (1- 

# JtJ

**-tf~** SamDIIna Location 

# ()u/(of.fRun Number 

# 2 lmDin_aer Box Number Recovtuv Person Recove_ry Rinses SamDIIna Identification Filter Number 

# [) 7J-OO 

# </ -1./ 

# I XAD N11nirt111n

Amount of lmpinger Weight lmpinger lmpinger Solution lmpinger Tip Final Initial Weight Gain Number Solution (g) Configuration (g) (g) (g) 

## 1 

# .( vJ



# {/t~D'/ 1 /)o 

# t-t1L )A 6::) 

# r2 '-/.

**~ 7)&.~**  2 

# t fl) 

# t1z

**~tJ** Y

**;OtJ~t~tL-** 

# t-5 :tl.f9 

# .1- 7 

# J. /. 

# 'I

3



# ftvtf~J {) 

# ;/1 t-5 C,'LI.c_ 

# t1!0 ' t(

4



# ~~ **~** e_ 

# I J 

# 50 .1/l /., 

# /l&-_5 

# 'oS.(, 

# &9f. 2
5



### 6

7



### 8



### 9


## 10
Total Weight Gain (g) 

## l t{V I 

# 8

### Facility: Hanson/Monroe Start Time: 1328 Date: 11/30/2006 End Time: 1432 Location: Outlet Initial Leak Check: 0.000@10" Run Number: R3 Final Leak Check: .000@5" Sample Type: M5/HF/HCI Total Sampling Time (min) 60.0 Corrected Barometric Pressure (in Hg) 29.70 Absolute Stack Pressure (in Hg) 29.69 Stack Static Pressure (in H20) -0.08 Average Stack Temperature (°F) 332.58 Stack Area (sq in) 2551.76 Actual Meter Volume (cu ft) 

### 40.542 Average Meter Pressure (in H20) 1.49 Average Meter Temperature CF) 75.38 Moisture Collected (g) 148.50 Carbon Dioxide Concentration 

### (% V) 

### 5.0 Oxygen Concentration 

### (% V) 

### 13.0 Nitrogen Concentration 

### (% V) 82.0 Dry Gas Meter Factor 0.9961 Nozzle Diameter (in) 0.409 Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.661 Standard Metered Volume (dscf) 39.679 Standard Metered Volume (dscm) 1.124 Stack Moisture 

### (% V) 

### 14.98 Mole Fraction Dry Stack Gas 0.850 Dry Molecular Weight 29.32 Wet Molecular Weight 27.62 Stack Gas Velocity (fpm) 1258.27 Stack Gas Velocity (mpm) 383.52 Volumetric Flow Rate (acfm) 22297.16 Volumetric Flow Rate (acmm) 631.46 Volumetric Flow Rate (dscfm) 12530.95 Volumetric Flow Rate (dscmm) 354.88 Percent lsokinetic 102.50 Percent Excess Air 150.04 Concentration (g/dscm) 0.00 Concentration (kg/hr) 0.00 Concentration (ppmv) 0.00 Emissions (lb/hr) 0.00

# Volumetric Flow Spreadsheet

Plant Date Sampling Location Run Number Ambient Temperature (°F) Barometric Pressure (in Hg) Static Pressure (in H20) Operator Time

Traverse Point Number

A-1 A-2 A-3 A-4 A-5 A-6 B-1 B-2 B-3 B-4 B-5 B-6 Averages Hanson/Monroe 11/30/2006 Plant 3 Outlet Run 3 68 29.74 -0.08

CJ 1328-1432
Velocity HeaddP (in H20)

0.09 0.09 0.09 0.09 0.09 0.09 0.08 0.09 0.09 0.09 0.09 0.08 Stack Ts (oF) 333 333 333 334 333 330 330 333 333 333 333 333 332.58

Actual Volumetric Flow Rate (acfm) Standard Volumetric Flow Rate (scfm) Square Root of

dP 0.30 0.30 0.30 0.30 0.30 0.30 0.28 0.30 0.30 0.30 0.30 0.28 0.30

Dry Standard Volumetric Flow Rate (dscfm) 02 Percent C02 Percent N2 Percent Stack Moisture (%) Mole Fraction (dry) Molecular Weight (dry) Molecular Weight (wet) Stack ID (in) Stack Area ( sq ft)

Stack Gas

Velocity

(fps) 21.16385 21.16385 21.16385 21.17720 21.16385 21.12376 19.91568 21.16385 21.16385 21.16385 21.16385 19.95347

20.96

22281.90 14751.44 12541.68 Stack Gas Velocity

(fpm) 1269.83105 1269.83105 1269.83105 1270.63177 1269.83105 1267.42589 1194.94059 1269.83105 1269.83105 1269.83105 1269.83105 1197.20820

1257.40 13 5 82 14.98 0.8502

29.32 27.624264 57 17.72054606165**Ar~** Plant Date Safll'pllhg -Location, Sample Type ..... ' ..
Run Number Operator Ambient Temperature Barometric Pressure (in.) Static Pressure (in. H 2 0)
Initial Leak Check · · - , Sampling Time (min) '· I FIELD OAT A SHEET

f/\01'1 **ro~-** 1.-)_(

-· -·-- ------- -----·------- ----;--r------,--------------- ·--- -·---·-----.---·----------- ·----

L

--- .- Probe Length & Type {9

**,;~Ia_~** "l Filter Number ICi1d..flJ.J **~** D t/4

rl-u-o to Nozzle ID (in.) . '/oct Height of Location (ft) fj{)'

0 t,;v\--1

**~-+·** Pilot Constant .84 Duct Dimensions (in.) _1{7

,,

**M~**

.lk.l I.J.-1= Meter Box Number A-m

Stack Geometry (R or C) ('_

**~'** Meter 6H@ f, Bt>t./ Assume Moisture(%) I I

c..-:s Yd **,qq~/** 02(%) 1'3

_fiB_

K Factor /(,., 9 C0

2 (%) .s

**~'i-1'1** 'Probe Heater Setting (°F) t .251) Nitrogen(%) I

-.DB_ Heater Box Setting (°F) + **.L~b** Moisture Collected (g)

tf)

1/

,f)Cfj- ;:J -;,)

I(

tJ.IJIJtJ ;tJ Final Leak Check

---- ·--·-

Read and Record All Data EvetY_ 6

Minutes r------

-----------· Dry

Gas Meter Temperature Run 3.._ Page_of_

-- --- ----------1 -# (Diagram of Duct)

**~--··** - **--~** ·-- ··-- -· --

Clock Time (24-hr) Gas Meter Reading VmW)

Velocity Head 6P (in.Hp) Orifice Pressure Differential 6H (in. H

2 0) --------'

tb:kR ll;IS/.£10 aq /.6?.... **1e~-'l~ ~dq**  1- $"2.

rm__a ._CflJ !IJ tt

,_ 5'"2. 1Bfi.21-. .. tJCf **~2.** qOO,lt_'-/ " lJ elf **,~-6'2.::**
**I~O<I~**

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**tM~~** I9D"l.6_'- il(f8 /._33

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l'fli.60 .tl'Q I· 52.

iq.1tJ,

**~1** _L £)<; 1-12 **rq.zq.z~** 'll fl f. o5

**_1~**

rq.v __ **~tt<** Flue Gas Temperature (oF) **~3J il3~**  33..3 _a_rl_'/_ **B3~** 3_3__l) **(~** ,'7,0 '333 213,-:a 333 **~~** 333 -- Probe Temperature (oF) .241£ ·2V3 .:J 1/S L'f1.t,_ **-J'I~** _2__'£']_ **~--:-ce-s**

' 2 "''et **2.,~'(';) :z.,:S~**  **.2~** .2..SI Filter Temperature (oF) OL'Sl_ **~~-(J** .2 f7 _2__'/j ;J. <tCJ **~** .. '51 **;2..5~** .:2:-;;

,--_ -:L$7 **2_$~ .2~<.**  **2-$~** lmpinger Pump

Exit

Vacuum

(oF)

(in. Hg)

# MOISTURE RECOVERY FORM FOR METHOD 4

Plant )//()i!l(tlf 

## Date 

# ;(- ?o -{),b SamDIIna Location 

# ;) vel-! .e / Run Number
' .·

**'~** 

# :J

- lmDinaer Bo.X,Number

.. --· ., 

## Recovery Pef80n Recovery Rinses SamDJing Identification Filter Number 

# () 7 J}O(J 

# Lj



# - CJf/f/ XAD NurnhA•



### Amount of lmpinger Weight lmpinger lmpinger Solution lmplnger Tip Final Initial Weight Gain Number Solution (g) Configuration (g) (g) (g) 

### 1 

# -/(JU t-/-7._ )()o/ 

# ;IJ7J t411[ ;1;1 

# t-5 8''Lt.L_ 

# "11/ 

# :2
2 

# 'I tAJ 

# tlz 

# 5oy 1/){)t«l 

# &-5

**~42_.)-** 

# 719_{)

3 

# £vttl; () ,Miff 

# b (<;; 

# ''f 0/l.t/

4



# ?~(.::,e_( z£;J 

# ·« 

# L- J1 &- 

# t:

**qD1.-~** 

# 89/0

5



### 6

7



### 8

9



### 10
Total Weight Gain (g) 

## ['f-t ,(

# Appendix B Analytical Report

# Air- Tech Environmental, LLC 3216 S. Alston Ave Durham, NC 27713



# Hanson Brick- Monroe #3

Analytical Report (1206-11)



# EPA Method 26A Hydrogen chloride Hydrogen fluoride



# Enthalpy Analytical, Inc. Phone: (919) 850-4392 

### I Fax: (919) 850-9012 

### I www.enthalpy.com 2202 Ellis Road Durham, NC 27703-5518

### I certify that to the best of my knowledge all 

### analytical data 

### presented in 

### this report: • Have been checked for completeness • Aie accurate, error-free, and legible • Have been conducted in 

### accordance with approved protocol, and that all 

### deviations and analytical problems are summarized in 

### the appropriate narrative(s) • This analytical report was prepared in 

### Portable Document Format (.PDF) and contains 84 pages.



## QA Review Performed by: 

## Ann L. H. Morris

Page 2 of84

# Summary of Results

### Company Air-Tech Environmental Analyst KEH Parameters EPA Method 26A # Samples 6 runs Client # Hanson Brick Job# 1206-11 PO# Verbal Report Date 12/11/2006


## Compound Sample ID 

## I Catch Weight (ug)

Hydrogen Fluoride Hydrogen Chloride

Hydrogen Fluoride Hydrogen Chloride 

## Inlet Run 1 161,967

14,969



## Outlet Run 1 653 10,530 

## Inlet Run 

## 2 165,838

15,190



## Outlet Run 

# 2 986 13,132

Page 4 of 84 1206-11 Results 

## Inlet Run 3 165,027

15,373



## Outlet Run 3 639 13,535

12/12/2006

# Results

Page 5 of84Company Air-Tech Environmental Analyst KEH Parameters EPA Method 26A

# Samples 6 runs Client # Hanson Brick Job# 1206-11 PO# Verbal Report Date 12/11/2006

MDL 0.0313 (ug/mL)

LOQ 0.197 (ug/mL) Lower Curve Limit 0.197 (ug/mL)

Upper Curve Limit 6.87 (ug/mL)

Compound Hydrogen Fluoride Sample LabiD Lab ID Analysis Ret Ret

% Diff Cone Cone

% Diff

ID #1 #2 Method Time Time

Ret #1 #2

Cone

(min) (min) (ug/mL) (ug/mL) Avg Cone (ug/mL)

Inlet Run 1 022-2801.D 022-2802.D 1206-16S. 2.83 2.81 0.5 3.86 3.86 0.0 _3.86 Vol Catch

DF (mL) Weight Qual (ug)

100 420 161,967

I Inlet Run 2 I 023-2901.0 lb23-2902.D I 1206-16S. I 2.83 I 2.81 I 0.7 I 3.61 I 3.60 I 0.0 I 3.61 -1 100 I 460 I 165,838 I I

I Inlet Run 3 I 024-3001.D I 024-3002.D I 1206-16S. I 2.83 I 2.81 I 0.7 I 3.46 I 3.42 I 0.6 I 3.44 I 100 I 480 I 165,027 I I

I Outlet Run 1 I 025-3101.D I 025-3102.D I 1206-16S. I 2.85 I 2.84 I 0.6 I 1.54 I 1.50 I 1.5 I 1.52 I 1 I 430 I 653 I I

I Outlet Run 2 I 026-3401.0 I 026-3402.D I 1206-16S. I 2.96 I 2.98 I 0. 7 I 2.35 I 2.34 I 0.1 I 2.35 I 1 I 420 I 986 I I

I Outlet Run 3 I 027-3501.D I 027-3502.D I 1206-16S. I 2.95 I 2.97 I 0.5 I 1.29 I 1.31 I 0.8 I 1.30 I 1 I 490 I 639 I I

I H2S04LabBiank I 008-0801.D I 008-0802.D I1206-16S.I NA I NA I NA I 0.0313 I 0.0313 I 0.0 I 0.0313 I 1 T1.00 I 0.0313 I ND I

I DIUF H20 Lab Blank I 009-0901.D I 009-0902.D I 1206-16S. I NA I NA I NA I 0.0313 I 0.0313 I 0.0 I 0.0313 I 1 I 1.00 I 0.0313 I ND I

I MS /Inlet Run 1 I 029-3701.D I 029-3702.D I 1206-16S. I 2.83 I 2.81 I 0.6 I Page 6 of 84 1206-11 Results 4.99 I 4.99 I o.o I 4.99 I 1 I o.525 2.62 I

Spike Amount (ug) 0.663 Native Amount (ug) 1.93 Spike Recovery 104% 12/12/2006CompanyAir-TechEnvironmentalAnalystKEHParametersEPAMethod26A#Samples6runsClient#HansonBrickJob#1206-11PO#VerbalReportDate12/11/2006MDL0.0421(ug/mL)LOQ0.383(ug/mL)LowerCurveLimit0.383(ug/mL)UpperCurveLimit13.3(ug/mL)CompoundHydrogenChlorideSample.LabIDLabIDAnalysisRetRet%DiffCone Cone%DiffTime Time#1#2ID#1#2Method(min) (min)Ret(ug/mL)(ug/mL)ConeInletRun1016-2201.D016-2202.D1206-16S.3.953.881-8_'---3.563.570.2AvgVolCatchConeDFWeightQual(ug/mL)(mL)(ug)3.561042014,969IInletRun2I017-2301.DI017-2302.DI1206-16S.I3.95I3.88I1.9I3.30T3.30I0.0I3.30I10I460I15,190IIIInletRun3I018-2401.DI018-2402.DI1206-16S.I3.95I3.88I1.9I3.20I3.21I0.2I3.20I10I480I15,373IIr---olltletRun11o19-25o1.D1o19-25o2.D112o6-16s.13.9513.8712.112.4512.45r-o.o12.4511 o143o11o,53o11IOutletRun2I020-2601.DI020-2602.DI1206-16S.I3.98I3.93I1.2I3.19I3.06I2.1I3.13I10I420I13,132IIIOutletRun3I021-2701.DI021-2702.DI1206-16S.I3.97I3.92I1.4I2.81I2.71I1.8I2.76I10I490I13,535IIIH2S04LabBlankI008-0B61.bI008-0802.DI1206-16S.I3.89I3.80I2.4I0.0884I0.0853I1.8I0.0868I1I1.00IIJIIDIUFH20LabBlankI009-0901.0I009-0902.DI1206-16S.INAINAINAI0.0421I0.0421I0.0I0.0421I1I1.00I0.0421INDIIMSIOutletRun1I028-3601.DI028-3602.DI1206-16S.I3.93I3.86I1.8IPage7of841206-11Results4.89I4.92I0.3I4.90I1I0.5252.57ISpikeAmount(ug)1.29NativeAmount(ug)1.22SpikeRecovery105%12/12/2006

# Narrative Summary

Page 8 of84

# Enthalpy Analytical Narrative Summary
Company Air- 

## Tech Environmental Client# Hanson Brick- Monroe #3

Analyst KEH Job# 1206-11 Parameters EPA Method 26A PO# Verbal

#Samples 6nms Custody

Analysis

Calibration

Chromatographic Conditions Report Date December 12,2006 Bryan Tyler received the samples on 12/1106 after being relinquished by Air- 

## Tech Environmental, LLC. The samples were received at ambient temperature in good condition. Prior to and during analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. The samples were analyzed for Hydrogen chloride and Hydrogen fluoride using the analytical procedures in 

## EPA Method 26A, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Method ( 40 CFR Part 60, Appendix A). The samples were analyzed following the procedures in 

## Section 11.0, Analytical Procedures. All samples and standards are prepared, stored, and analyzed using 

## high-density polyethylene**containers~** 

## The Agilent Model 1100, High Performance Liquid Chromatograph ("Gonzo") was equipped as follows: Front: DIONEX ED40 Electrochemical Detector Front: Dionex Ion Pac AS14A, 4 x 250 mm (SIN 2243) Rear: DIONEX ED40 Electrochemical Detector Rear: Dionex Ion Pac AS14A, 4 x 250 mm (SIN 004604) The calibration curves are located in the back of this 

## report and referenced in the Analysis Method column on the Detailed Results page. For each calibration curve used, the first page of the curve contains all 

## method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. The acquisition method COLSWTCHM is 

## included in the Curve/QA Chromatograms section of this report.

Page 9 of 84

## QCNotes Enthalpy Analytical Narrative Summary (continued)
Although Section 7.2.2, Absorbing Solution Blanks, requires client-provided reagent blanks to be analyzed, none were provided by the client. A quality control check sample was analyzed at the same time as the laboratory blanks and samples. Unless otherwise specified, 

## all method required acceptance criteria were met. All sample preparation and analytical holding times specified in the method were met unless otherwise indicated. Section 13.2, Sample Stability, specifies an analytical holding time of four weeks. Reporting Notes The instrument was set up using two columns of the same type to reduce the total time needed to run 

## all the samples. Each sample was analyzed with two injections, one injection on each of the columns. The H2S04 matrix samples were analyzed for Cl- and F- but are reported as HCl and HF. The peaks listed 

## in the "Sample Chromatograms" section are labeled hydrogen chloride and hydrogen fluoride. The additional molecular weight contribution from the H+ is 

## included in the 

## results listed on each chromatogram and throughout the report. Enthalpy Analytical, Inc. is 

## accredited to perform this 

## method for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

Page 10 of 84

# General Reporting Notes
The following are general reporting notes that are applicable to all 

## Enthalpy Analytical, me. reports, unless specifically noted otherwise.

• The symbol MDL 

### represents the Minimum Detection Limit. Below this value the laboratory cannot confnn the presence of the analyte of interest reliably.
• The symbol 

### LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within 

### the criteria of the method
• The symbol ND 

### following a value indicates a non-detect or analytical result below the MDL.
• The symbol J 

### following a value indicates an analytical result between the MDL and the LOQ. A 

### J flag indicates that the laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate.
• The symbol 

### E following a value indicates an analytical result exceeding 100% of the highest calibration point.
• The symbol DF 

### represents a Dilution Factor. This number represents dilutions during the extraction and/or laboratory stages of sample treatment. The analytical result taken from a laboratory instrument is multiplied by the DF to get final 

### results.
• The Sample ID 

### MS represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whe1her or not anything in the sample matrix prohibits analysis for the analyte(s).
• The Sample ID 

### MSD represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. Most methods performed by Enthalpy do not require analysis of an MSD.
• The Sample ID 

### BS represents a Blind Spike. A member of the Quality Assurance department has created BS samples for many of the analytes Enthalpy tests for, and only QA and the Enthalpy Analytical ownership have access to the actual values of these samples. The laboratory analyzes them without knowledge of the actual value, and the spreadsheets get completed for these samples solely by the QA group. • The Sample ID 

### LCS represents a Laboratory Control Sample. Whenever spikes are prepared for our clients more spikes are prepared 

### than needed. The extras (randomly chosen) are kept in-house at the appropriate temperature conditions. When the spike samples come back from the client for analysis, the LCSs (usually two are saved) are analyzed to confirm that the analyte could be recovered from the media, separate from the spike samples which were used on the project and which may have had issues caused during collection and/or transport.
• Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed (specifically values of 1,000 or greater), the number is rounded to a whole number of units, rather 

### than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits reported, but no confidence should be placed on more 

### than three significant digits.



## Page 11 of 84

# Sample Custody

Page 12 of 841-i.ll-1 **~II** EnvlroniTHH1t.l,

LLC AIIYTICB P. 0. Box 12353 R.-rdl

Trt.ngle PW'k, NC 77708-2353 PROJECT A 1 e..._ re_c+r

SITE Chain of Custody Record

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(2.vrJ , l.aJ_QJ- **-~A)** 1- **ld~±M-** _e.u_,v_3 REMARKS -c SAMPLE MATRIX **Q.t~ Ht.~O**  **~** w
RECEIVED BY: I DATE I TIME I nELJNOUISHEo BY: DATErrtME

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# Appendix C Meter CalibrationsMethod 5 Dry Gas Meter Calibrations For:   FULL CALl BRA TION ** **

1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range. &Duo U®©Gu

2) Record barometric pressure before and after calibration procedure.

3) Run at tested vacuum (from Orifice Calibration Report), for a period of time

necessary to achieve a minimum total volume of 5 cubic feet.

4) Record readings in outlined boxes below, other columns are automatically calculated.

DATE: I 1 0/26/06 I
METER PART#: ATB RUN# rn 2 3 []] 1 2 3 **.nfl;~** L.;iJ 3 []] 1 1 DO 8 8 1 2 3 1 2 3 K' FACTOR (AVG) 0.2951 0.2951 0.2951 0.426. 0.426 0.426 0.5876.

·' 0;5876 .·

0.5876" 0.6647 0.6647 0.6647 0.8252 0.8252 0.8252 METER SERIAL #:c==]
CRITICAL ORIFICE SET **SERIAL#:~**

TESTED VACUUM (in Hg) 23 23 23 21 21 21 19 19 19 18 18 18 36.100 41.210 41.330 47.300 47.450 52.700 59.400 68.200 68.410 76.400 76.600 82.900 2.700 12.350 12.600 22.800 **2~.100** 35.600 83.500 92.400 92.900 99.900 0.100 9.000 EE 5.110 5.970 5.250 8.800 7.990 6.300 9.650 10.200 12.500 8.900 7.000 8.900 INITIAL FINAL 29.98 AVG (Pbarl 129.981 1 r- ---- **-~**

BAROMETRIC PRESSURE (in Hg): 29.98

Pressure on 10/27/2006 (in Hg) 29.91

66.5 73 72 69 70

66.5 72 72 70 70

66.5 72 72 70 70

61.5 61 63 60 61

62.5 63 65 61 62

63 65 66 62 63

65 .. •. 66 69. 65 66

. 65 j, -69 71 .66 68

65.5' _;>71 73 68 69

"• 64. 67 70 63 64

64 70 72 64 66

64.5 72 74 66 67

I I I I I I DGM AVG 71 71 71 61.25 62.75 64 66.5 68.5 70.25 66 68 69.75 29.91 ELAPSED TIME(MIN) a 12.99 15.13 13.33 15.95 14.45 11.32 12.75 13.42 16.45 10.37 8.15 10.32 29.91 §!j 5 5 **~** 9 . **~** 4 4 §§ 5.0985 5.9566 5.2382 8.9353 8.0895 6.3633 5.010 5.8354 5.1411 AVG= 0.9826 0.9797 0.9815 0.9813 8.9020 0.9963 8.0571 0.9960 6.3089 0.9914 AVG = 0.9946 9.7439 9.8056 1.0063 10.2603 10.3208 1.0059 12.5324 12.6451 1.0090 8.9852 7.0403 8.9216 AVG = 1.0071 9.0091 7.0805 8.9614 1.0027 1.0057 1.0045 AVG = 1.0043 **~**

AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =I 0.9961 I AVERAGE t.H@ =I 1.8039 I 1.855 1.855 1.855 1.828 1.834 1.835 1.778 1.771 1.771 1.759 1.753 1.752Method5DryGasMeterCalibrationsFor:HansonBrick1)Selectthreecriticalorificestocalibratethedrygasmeterwhichbrackettheexpectedoperatingrange.2)Recordbarometricpressurebeforeandaftercalibrationprocedure.3)Runattestedvacuum(fromOrificeCalibrationReport),foraperiodoftimenecessarytoachieveaminimumtotalvolumeof5cubicfeet.4)Recordreadingsinoutlinedboxesbelow,othercolumnsareautomaticallycalculated.INITIALDATE:I1215/06METERSERIAL#:c=JCRITICALORIFICESETBAROMETRICPRESSURE(inHg):30.14METERPART#:ATBrn12K'FACTOR(AVG)0.58760.58760.5876TESTEDVACUUM(inHg)1932.401942.001952.30USINGTHECRITICALORIFICESASCALIBRATIONSTANDARDS:41.8052.1060.609.4010.108.30575757.55958.5635659635764:58575860DGMAVG57.2559.2561.25FINAL30.14ELAPSEDTIME(MIN)0/12.5813.4211.01 POSTCALIBRATION** **&O[JolJ@©GlJAVG(Pba,)130.1411.851.851.85PreTest"YD"=Io.99si]DH=I1.8312IIFYVARIATIONEXCEEDS5.00%,ORIFICESHOULDBERECALIBRATED9.71159.801510.394510.45098.50928.56581.00931.00541.0067AVG=1.00711.031.77111.76591.7626ThefollowingequationsareusedtocalculatethestandardvolumesofairpassedthroughtheDGM,Vm{std),andthecriticalorifice,V"{std),andtheDGMcalibrationfactor,Y:Theseequationsareautoinatlcallycalculatedinthespreadsheet·above.".AVERAGEDRYGASMETERCALIBRATIONY=I1.Cloi1--J(1)Vm(std)=(2)Vcr(std)=(3)Y=K,VmPba,+(t,H/13.6)=NetvolumeofgassamplepassedthroughDGM,correctedtostandardconditionsK1=17.64'Riin.Hg(English),0.3858'KimmHg(Metric)TmPbar9K'--vr:::::Tm=AbsoluteDGMavg.temperature('R-English,'K-Metric)=Volumeofgassamplepassedthroughthecriticalorifice,correctedtostandardconditionsT,mb=Absoluteambienttemperature('R-English,'K-Metric)K'=AverageK'factorfromCriticalOrificeCalibrationVcr(std)=DGMcalibrationfactorv.;.(std)AVERAGE8H@=j1.7665It,H@=2..Zlit,HVm(std)V0,(Std)Vm12-05-06Hansonbrick..··Method5DryGasMeterCalibrationsFor:ATD11-16-06 FULLCALIBRATION** **1)Selectthreeorificestocalibratethedrygasmeterwhichbrackettheexpectedoperatingrange.&Duolf®©lliJ2)Recordbarometricpressurebeforeandaftercalibrationprocedure.3)Runattestedvacuum(fromOrificeCalibrationReport),foraperiodoftimenecessarytoachieveaminimumtotalvolumeof5cubicfeet.4)Recordreadingsinoutlinedboxesbelow,othercolumnsareautomaticallycalculated.METERSERIAL#:c=!CRITICALORIFICESETDATE:I•"--•nIMETERPART#:1--·-1[[]66rn2323rn123rn11D23K'TESTEDFACTOR'VACUUM(AVG)(inHg)0.2951190.29511910.295119I0.426180.426180.426180;5876160.587616.0;5876·160.6647150.6647150.664715III74.05083.25083.35086.75086.85092.25092.50098.60098.700106.2006.40013;40046.700.52.300,·52.50"0'62.55062.750••73.850.13.80025.75026.10034.55034.80041.800§9.2003.4005.4006.1007.5007.000#5.6QO10.050#11.10011.9508.4507.000INITIALBAROMETRICPRESSURE(inHg):29.9260636261 616062626162606263616260.56363 62 6261636462 6361.564 646363616259 58 58596263.606160.6364.6161.61.56466 63 6361.5636466 6761.567 6764 64FTrlllDGMAVG61.7561.756262.56363.559.2561.562.25646565.5FINAL29.92ELAPSEDTIME(MIN)e23.678.7313.8911.0313.5312.637.5713.5514.9314.1310.008.28AVG(Pbarl129.9210.490.490.490.980.980.989944§§9.32323.44555.46976.18037.59147.07859.16763.38125.3797I0.98330.98130.98361.79361.79361.7927AVG=0.98271.79336.16400.99741.72387.55750.99551.72727.05140.99621.7305AVG=0.99641.72725.72215.83241.01931.77271.74481.752410.224810.45991.023011.276811.51411.0210AVG=1.02111.756712.11468.5507.076112.30928.71147.2131AVG=1.01611.01891.01941.01811.73901.73571.73411.7363AVERAGEDRYGASMETERCALIBRATIONFACTOR,Y=I1.0052IAVERAGE=11.7533IMethod5DryGasMeterCalibrationsFor:HansonBrick1)Selectthreecriticalorificestocalibratethedrygasmeterwhichbrackettheexpectedoperatingrange.2)Recordbarometricpressurebeforeandaftercalibrationprocedure.3)Runattestedvacuum(fromOrificeCalibrationReport),foraperiodoftimenecessarytoachieveaminimumtotalvolumeof5cubicfeet.4)Recordreadingsinoutlinedboxesbelow,othercolumnsareautomaticallycalculated.INITIALDATE:I·-·-·--IMETERSERIAL#:c=JCRITICALORIFICESETBAROMETRICPRESSURE(inHg):29.98METERPART#:[]123._____......K"FACTOR(AVG)0.58760.58760.5876TESTEDVACUUM(inHg)1759.901767.1501774.70USINGTHECRITICALORIFICESASCALIBRATIONSTANDARDS:66.9074.51082.107.07.3607.406262.·62.564-62.5666460666167'62616264DGMAVG61.7563.2564.75FINAL29.98ELAPSEDTIME(MIN)e9.379.859.88 POSTCALIBRATION** **&D[jolJ@@lhJAVG(Pbarl129.98199PreTest"YD"=I1.0052IDH=I1.753I7.13257.47787.4970IFYVARIATIONEXCEEDS5.00%,ORIFICESHOULDBERECALIBRATED7.22687.59347.61651.01321.01551.0159AVG=1.01490.961.83071.82721.8219ThefollowingequationsareusedtocalculatethestandardvolumesofairpassedthroughtheDGM,Vm(std),andthecriticalorifice,Va(std),andtheDGMcalibrationfactor,Y.TheseequationsareautomaticallycalculatedinthespreadsheetabOve.·AVERAGEDRYGASMETERCALIBRATIONFACTOR,y=I1.0149I(1)Vmistd)=(2)Vcr(std)=(3)Y=K,VmPba,+{Ll.H/13.6)=NetvolumeofgassamplepassedthroughDGM,correctedtostandardconditionsK1=17.64"Riin.Hg(English),0.3858"KimmHg(Metric)TmPba,eTm=AbsoluteDGMavg.temperature("R-English,"K-Metric)=Volumeofgassamplepassedthroughthecriticalorifice,correctedtostandardconditionsT,mb=Absoluteambienttemperature("R-English,"K-Metric)K'=AverageK'factorfromCriticalOrificeCalibrationVcr(std)=DGMcalibrationfactorVm(std)AVERAGE=I1.8266ILl.H@=l!..Z5...ftLl.HVm(std)V0,{Std)Vm12-06-06Hansonbrick

# Appendix D Process Documentation

## 'bATE t \ \ - 

# 30-D(Q



# Ho.r.so~r~ Be; 

# ck- 

# fVl onf'<De.. 

# Y la_f"l 

# t flctnt.tJ. 

## "3. 

# ES 3Lk



# L~~·\31 

# k;\n

**Th<::~'J ~-?v·\-'iZ..J-e..**  \-<; \"' C..a.r

**Vu~hRa.i-~** =: 

## I 

## Ci •. 

## 5

**Q.~D** / 

## do-.'1 

## 51



## ~e
**~ tv\5~"<e·e.-r;** 
**Cf~** 

## D'b

**f'~l"'eeo** 

## /c.a..r 

# F;

**re~ WQ_\~ht**  := 

## 3o '6

**~** 

# Lbs.

# Monroe Plant 3 Stack Test: 11/30/06 Time: each Inches H20 feet/sec 15 minutes Pressure Flow Test Run #lt1 Inlet Testing 10:47 0.183 Start 

# I Finish 11:02 0.248

10:401 11:40 11:17 0.187 Outlet Testing 11:32 0.102 Start 

# I Finish

10:271 11:33 Run 1 Average 0.170 W'LJIVIUI 

## Test Run 

## #lt2 Inlet Testing 12:02 0.178 Start I Finish 12:17 0.180

11:531 12:53 12:32 0.088 Outlet Testing 12:47 0.148 Start 

# I Finish 13:02 0.138

12:001 13:03 Run 2 Average D.1415 fFOIV/DI 

## Test Run #lt3 

## Inlet Testing 13:02 0.138 Start I Finish 13:17 0.175

13:001 14:00 13:32 0.141 Outlet Testing 13:47 0.180 Start 

## I Finish 14:02 0.201

13:281 14:32 14:17 0.137

# Appendix E Example Calculations

# SAMPLE CALCULATIONS

• Volume of dry gas sampled at standard conditions (68°F, 29.92 "Hg):


## Y X 

## Vm X 

## 528 X [Pbar 

## + (flH /13.6] 29.92 X 

## (T m 

## + 460}

• Volume of water vapor at standard conditions:



# = 0.04715 cf/gm X 

## Mw

• Fractional moisture content in stack gas:

V m(std} 

## + V w(STD)

• Mole fraction of dry stack gas:

• Absolute stack gas pressure:



## p 

# =

s 

### pbar 

## + Static 13.6

## • Average molecular weight of stack gas (lb/lb.mole): Dry: 

## MWd 

## = (.32 x %0 2 ) 

## + (.44 x %C0 2 ) 

## + [.28 x {100- (%0 2 

## + %C0 2 )}] 

## Wet: 

## MW 5 

## = [MWd X 

## {1
- 

## Bws)] + {18 X 

## Bws)

• Stack gas velocity at stack conditions (fUsee):



## = 85.49 X 

## .84 X 

# '\ft:P X 

# Ts + 

# 460 P 5 

### X 

## MW 5



## • Average stack gas volumetric flow at dry, standard conditions (DSCFM):

528 x P s 

## x 60 sec {T 5 

## + 460)x 29.92 min

• lsokinetic sampling rate(%):



# c = .0945 for English Units



## 1% 

# = 

# c X vm(std) X ( Ts 

## + 460)

• Particulate concentration (gr/dscf):

15.43 grains

vm(std)

## • Particulate emission rate (lb/hr):



## E = 7000 grains/lb 60 min X 

## Qsd X 

## hr



## • Flue gas concentration of compound of interest (J.Jg/dscf):
Liquid Samples

vmstd



## Filter Samples

vmstd



## • Flue gas mass rate (lb/hr) 1.32 X 

## 10" 7 

### X Qsd 

### X 

## Ccoi

### Definitions**~H** 

## = average meter orifice pressure (in. H 2 

### 0)**~p** 

## = velocity pressure (in. H 2 

### 0)**~** 

## = area of nozzle (ft2) 

# As = cross sectional area of duct (ft 2 ) 

### Bws 

## = mole fraction of wet gas (unitless)
cs 

## = particulate concentration (gr/dscf) 

# on = diameter of nozzle (in) E 

## = emission rate (lb/hr) EEOI 

## = mass rate, compound of interest (lb/hr) Md 

## = mole fraction of dry gas (unitless) MF 

## = mass of filter, post test (g) MP 

## = mass of particulate (g) Mw 

## = mass of water collected (g) MWd 

## = flue gas molecular weight, dry basis (lb/lb-mole) MWS 

## = flue gas molecular weight, wet basis (lb/lb-mole) Pbar 

## = barometric pressure (in. Hg) ps 

## = absolute stack pressure (in. Hg) Qsd 

## = flue gas dry volumetric flow @ 

### STP (fe/min) Static 

## = stack static pressure (in. H 2 

### 0) t 

## = test time (min) Tm 

## = average meter temperature (°F) Ts 

## = average flue gas temperature (°F) IJg/g 

## = laboratory result, analytical concentration of sample IJg/ml 

## = laboratory result, analytical concentration of sample 

## VA = volume of liquid aliquot analyzed (ml) 

## VL = volume of liquid recovery fraction (ml)
vm 

## = actual meter volume (fe) vm(std) 

## = meter volume @ 

### STP (fe)
vs 

## = flue gas velocity (ft/sec)

vw 

## = volume of water vapor condensed (ftl) y 

## = dry gas meter correction factor (unitless)