## Polyvinyl Chloride and Copolymers (PVC) Production

**MACT Floor, Baseline Emissions, and Emission Reductions Analyses**

**Heat Exchange Systems**

**February 7, 2012**

**Worksheet Name Description**  Survey Data (Form D) Section 114 Survey Data for Heat Exchange Systems Monitoring Programs - Pivot Monitoring Programs Data Extraction Monitoring Programs - Summary Summary of Monitoring Programs Flow Rates - Pivot Flow Rate Data Extraction Reported Emissions from CTs Reported Emisisons from Cooling Towers - Survey Data Responses

Form C-1-A Data Section 114 Survey Form C-1-A Data Summary Survey Data Summary Heat Exchange Systems - Survey Data Analysis and Summary Clarification Data Heat Exchange Systems - Summary of Clarification Data Submitted to EPA FLOOR Calculation MACT Floor Analysis - Heat Exchange Systems Baseline, Reductions, Costs COOLING TOWERS - BASELINE EMISSIONS ANALYSIS Count for PVC HeatExch COOLING TOWERS - Count for PVC HeatExch**CompanyName**

Georgia Gulf Corporation Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Georgia Gulf Corporation Georgia Gulf Corporation Georgia Gulf Corporation Georgia Gulf Corporation Georgia Gulf Corporation Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office CertainTeed CorporationCertainTeed Corporation

CertainTeed Corporation CertainTeed Corporation The Dow Chemical Company The Dow Chemical Company Union Carbide Corporation Union Carbide Corporation Union Carbide Corporation Union Carbide Corporation Union Carbide Corporation Union Carbide Corporation Union Carbide Corporation Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LPOxy

Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation We stlake Chemical Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation PolyOne Corporation We stlake Chemical Corporation We stlake Chemical Corporation We stlake Chemical CorporationWe stlake Chemical Corporation

We stlake Chemical Corporation We stlake Chemical Corporation We stlake Chemical Corporation**FacilityName ProcessUnitID** 

Georgia Gulf Chemicals Plaquemine Facility P-1 Oxy Vinyls Pedricktown P-1 Oxy Vinyls Pedricktown P-1 Oxy Vinyls Pedricktown P-1 Oxy Vinyls Pedricktown P-2 Oxy Vinyls Pedricktown P-2 Oxy Vinyls Pedricktown P-2 Oxy Vinyls Pedricktown P-3 Oxy Vinyls Pedricktown P-3 Oxy Vinyls Pedricktown P-3 Oxy Vinyls Pedricktown P-3 Oxy Vinyls Pedricktown P-4 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation Deleware City P1 Formosa Plastics Corporation Deleware City P-2 Formosa Plastics Corporation Point Comfort - PVC Unit P-1 Formosa Plastics Corporation Point Comfort - PVC Unit P-1 Formosa Plastics Corporation Point Comfort - PVC Unit P-1 Formosa Plastics Corporation, Point Comfort - Specialty Poly viny l Chloride (SPVC) Unit

P-2 Georgia Gulf Chemicals Aberdeen Facility 1 Georgia Gulf Chemicals Aberdeen Facility 1 Georgia Gulf Chemicals Plaquemine Facility P-1 Georgia Gulf Chemicals Plaquemine Facility P-1 Georgia Gulf Chemicals Plaquemine Facility P-1 Oxy Vinyls Pedricktown P-5 Oxy Vinyls Pedricktown P-6 Oxy Vinyls Pedricktown P-6 Oxy Vinyls Pedricktown P-6 Oxy Vinyls Pedricktown P-6 Oxy Vinyls Pedricktown P-6 Oxy Vinyls Pedricktown P-6 Oxy Vinyls Pedricktown P-7 Shintech Addis P-1 Shintech Addis P-1 Shintech Addis P-1 Shintech Addis P-1 Shintech Freeport P-1 Shintech Freeport P-1 Shintech Freeport P-1 Shintech Freeport P-1 Shintech Plaquem ine P-1 Shintech Plaquem ine P-1 Shintech Plaquem ine P-1 Shintech Plaquem ine P-1 Lake Charles Poly me r Plant P-1Lake Charles Poly me r Plant P-1

Lake Charles Poly me r Plant P-1 Lake Charles Poly me r Plant P-2 Dow Midland - SARAN Resins Viny l Train Dow Midland - SARAN Resins Viny l Train Union Carbide Texas City P-1, P-2 Union Carbide Texas City P-1, P-3 Union Carbide Texas City P-1, P-2, P-3 Union Carbide Texas City P-2, P-3 Union Carbide Texas City P-2, P-3 Union Carbide Texas City P-2 Union Carbide Texas City P-1 Oxy Vinyls Deer Park P-1 Oxy Vinyls Deer Park P-1 Oxy Vinyls Deer Park P-1 Oxy Vinyls Deer Park P-1 Oxy Vinyls Deer Park P-1 Oxy Vinyls Deer Park P-1 Oxy Vinyls Deer Park P-2 Oxy Vinyls Deer Park P-2 Oxy Vinyls Deer Park P-2 Oxy Vinyls Deer Park P-2 Oxy Vinyls Deer Park P-2 Oxy Vinyls Deer Park P-3 Oxy Vinyls Deer Park P-4 Oxy Vinyls Deer Park P-4 Oxy Vinyls Deer Park P-4 Oxy Vinyls Deer Park P-4 Oxy Vinyls Deer Park P-4 Oxy Vinyls Deer Park P-4 Oxy Vinyls Deer Park P-4 Oxy Vinyls Pasadena P1 Oxy Vinyls Pasadena P1 Oxy Vinyls Pasadena P1 Oxy Vinyls Pasadena P1 Oxy Vinyls Pasadena P3 Oxy Vinyls Pasadena P4 Oxy Vinyls Pasadena P5 Oxy Vinyls Pasadena P6 Oxy Vinyls Pasadena P7 Oxy Vinyls Pasadena P8 Oxy Vinyls Pasadena P9 Oxy Vinyls Pasadena P3 Oxy Vinyls Pasadena P4 Oxy Vinyls Pasadena P5 Oxy Vinyls Pasadena P6 Oxy Vinyls Pasadena P7 Oxy Vinyls Pasadena P8 Oxy Vinyls Pasadena P9 Oxy Vinyls Pasadena P3 Oxy Vinyls Pasadena P4 Oxy Vinyls Pasadena P5Oxy

Vinyls Pasadena P6 Oxy Vinyls Pasadena P7 Oxy Vinyls Pasadena P8 Oxy Vinyls Pasadena P9 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P10 Oxy Vinyls Pasadena P11 Oxy Vinyls Pasadena P11 Oxy Vinyls Pasadena P12 Oxy Vinyls Pasadena P12 PolyOne Henry P-13 Cooling Twr for P-4 PolyOne Henry P-13 Cooling Twr for P-4 PolyOne Henry P-13 Cooling Twr for P-4 PolyOne Henry P-13 Cooling Twr for P-5 PolyOne Henry P-13 Cooling Twr for P-5 PolyOne Henry P-13 Cooling Twr for P-5 PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Henry Chilled H2O - L4 PolyOne Henry P-14 Chilled H2O for P-5 PolyOne Henry P-14 Chilled H2O for P-5 PolyOne Henry P-14 Chilled H2O for P-5 PolyOne Henry P-14 Chillers PolyOne Pedricktown P-1 We stlake Calvert City P-1 PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Henry P-13 Cooling Twr for P-2 PolyOne Henry P-13 Cooling Twr for P-2 We stlake Calvert City P-1 We stlake Calvert City P-1 We stlake Calvert City P-1We stlake Calvert City P-1

We stlake Geismar P-1 We stlake Geismar P-1 We stlake Geismar P-1**ProcessEquipID1 ProcessEquipID2**  **ProcessEquipID3 ProcessEquipID4**  **ProcessEquipID5**

U-166 thru U-173 U-1 thru U-18 U-142 thru U-149 U-100 U-115 U-107 U-200 U-207 U-218 U-309 U-311 U-310 U-303 N/A PE205A PE206A PE206C PE206B PE301 PE302 PE310 PE303A/B PE304A/B PE-305A/B PE309 U-14 U-27 U-28 U-29 U-30 U-60 U-75 U-76 U-77 U-78 U-7 U-24 U-19 U-24 U-3 U-25 U-17 U-43 / U-44 U-45 / U-46 U-47 U-57 U-34 thru 45 U-46 thru 53 U-175 U-176 U-19 + U-20 U-63 + U-64 U-182 U-508 U-600 U-611 U-616 U-610 U-613 U-615 N/A U-28 U-34A U-34B U-50A U-50B U-2 U-27A-D U-38A U-38B U-49 U-35A U-35B U-36A U-36B U-60 U-43 U-39 U-48 U-49 U-21A thru D U-23A thru D U-14A thru F U-16 U-20A thru D U-24A thru D U-25 U-30 U-46A thru B U-51 U-54 U-24A thru B U-34 U-45 U-47 U-53 U-31 U-32 U-56 U-5a U-5b U-5c U-5d U-5eU-10a U-10b U-10c

U-10d U-16a U-16b U-16c U-16d CTW -1 R-302 Jacket R-303 Jacket R-304 Jacket R-305 Jacket CTW -1 E-511 E-512 E-521 E-522 U-1 U-5 U-12 U-16 U-20 U-3 U-7 U-9 U-10 U-11 U-14 U-24 U-44 U-57 U-58 U-20 U-24 U-57 U-58 U-60 U-28 U-47 U-34 C-3 U-34 U-14 U-102 U-135 U-110 U-111 U-118 U-131 U-202 U-231 U-210 U-214 U-131 U-315 U-419 U-403 U-404 U-410 U-411 U-414 U-413 U119 U120 U121 U122 U300 U400 U500 U600 U700 U800 U900 U304 U404 504 U604 U704 U804 U904 U308 U408 U508U608

U708 U808 U908 U1006 U1041 U1046 U1051 U1027 U1030 U1028 U1031 U1035 U1034 U1033 U1037 U1103 U1104 U1203 U1219 Poly 1 Jacket Poly 2 Jacket Poly

3 Jacket Poly

4 Jacket Poly

1 Baffle Poly 4 Baffle Upper Recovery Lower Recovery Colum n 3 Cond Lean Oil Cooler Seal H2O Heat Xch Poly 5 Jacket Poly 6 Jacket Poly

7 Jacket Poly

8 Jacket Poly

9 Jacket Poly 12 Jacket Poly 5 Baffle Poly

6 Baffle Poly

7 Baffle Poly

8 Baffle Poly 11 Baffle Poly 12 Baffle Colum n 2 Poly 21 Jacket Poly 22 Jacket Poly

23 Jacket Poly

24 Jacket Poly

25 Jacket Poly 28 Jacket Poly 29 Jacket Poly

30 Jacket Poly

31 Jacket Poly

32 Jacket Poly 35 Jacket Poly 36 Jacket Poly

21 Condenser Poly

22 Condenser Poly

23 Condenser Poly 26 Condenser Poly 27 Condenser Poly

28 Condenser Poly

29 Condenser Poly

30 Condenser Poly 33 Condenser Poly 34 Condenser Poly

35 Condenser Poly

36 Condenser L1 Slurry Cooler Poly 37 Jacket Poly 38 Jacket Poly

39 Jacket Poly

40 Jacket Poly

37 Condenser Poly 40 Condenser Premix Jacket L2 Slurry Cooler Poly 1 Jacket Poly 2 Jacket Poly

3 Jacket Poly

4 Jacket Poly

1 Baffle Poly 4 Baffle Upper Recovery Lower Recovery Colum n 3 Cond Lean Oil Cooler P-14 Chilled H2O for P-4 Poly 5 Jacket Poly 6 Jacket Poly

7 Jacket Poly

8 Jacket Poly

9 Jacket Poly 12 Jacket Poly 5 Baffle Poly

6 Baffle Poly

7 Baffle Poly

8 Baffle Poly 11 Baffle Poly 12 Baffle Colum n 2 Chiller Unit 1 Chiller Unit 2 U-18 U-8 U-9 U-11 U-12 U-14 Poly 21 Jacket Poly 22 Jacket Poly

23 Jacket Poly

24 Jacket Poly

25 Jacket Poly 28 Jacket Poly 29 Jacket Poly

30 Jacket Poly

31 Jacket Poly

32 Jacket Poly 35 Jacket Poly 36 Jacket Poly

21 Condenser Poly

22 Condenser Poly

23 Condenser Poly 26 Condenser Poly 27 Condenser Poly

28 Condenser Poly

29 Condenser Poly

30 Condenser Poly 33 Condenser Poly 34 Condenser Poly

35 Condenser Poly

36 Condenser L1 Slurry Cooler Poly 37 Jacket Poly 38 Jacket Poly

39 Jacket Poly

40 Jacket Poly

37 Condenser Poly 40 Condenser Premix Jacket L2 Slurry Cooler U-17 U-16 U-89 U-22 U-26 U-89 U-34 U-30 U-89U-40 U-42 U-45 U-89

U-3 U-20 U-23 U-24 U-26 U-31 U-13**ProcessEquipID6 ProcessEquipID7**  **CoolingWaterSidePressure_Kpa** 690 370 275 275 370 0 275 415 415 415 415

480 480 480 480 653 480 515 U-15 U-11 60 U-79 60 345 345 620 U-58 584 790 790 345 414 620 400 0 410 410 200 1400 210

U-55 U-58 430 U-51 U-57 400 305 240 240 450 380 330 423 424 353 267 U-5f U-5g 551.58056551.58056 551.58056 551.58056 E-501 E-502 450 to 500 E-112 E-702 450 to 500 U-17 241 U-13 U-59 240 240 U-44 U47 240 240 240 240 310 310 350 350 365 Unknown 310 310 350 365 Unknown 430 101.4 690 310 atmospheric atmospheric 310 310 420 340 340 340 180 180 180 330 330 330 565 550 550 480 480 480 825 825 620 450 450620 900 620 760 340 480 480 480 520 520 450 7 480 1480 1330 7 0 0 385 650 Poly 2 Baffle Poly

3 Baffle 618 VGA Reflux WWS Condenser 618 618 Poly 10 Jacket Poly

11 Jacket 618 Poly 9 Baffle Poly

10 Baffle 618 618 Poly 26 Jacket Poly

27 Jacket 412 Poly 33 Jacket Poly

34 Jacket 412 Poly 24 Condenser Poly

25 Condenser 412 Poly 31 Condenser Poly

32 Condenser 412 412 Poly 38 Condenser Poly

39 Condenser 412 412 Poly 2 Baffle Poly

3 Baffle 412 VGA Reflux WWS Condenser 412 412 Poly 10 Jacket Poly

11 Jacket 412 Poly 9 Baffle Poly

10 Baffle 412 412 412 700 U-15 U-89 586 Poly 26 Jacket Poly

27 Jacket 618 Poly 33 Jacket Poly

34 Jacket 618 Poly 24 Condenser Poly

25 Condenser 618 Poly 31 Condenser Poly

32 Condenser 618 618 Poly 38 Condenser Poly

39 Condenser 618 618 586 586 586586

U-30 35 200 330**ProcessSidePressure_Kpa HeatExchangersCnt**  **CoolingWaterFlowRateA vg_Gpm**  930 26 17000 840 3 1200 275 2 220 0 1 106 840 3 1200 275 1 26000 275 2 220 0 1 30 0 3 15 0 3 20 0 4 5

116 12 125 122 12 250 127 12 250 580 12 446 12 411 12 1500 585 12 50 21 4000 15 0 7 46200 345 4 46200 1034 10 66300 630 7 100 930 12 1000 450 9 1000 414 47 40000 827 10 22300 0 1181 80 5 50 0 4 13333 140 1 70 35 1 150 140 1 100 100 1 15 200 1 100

260 7 449 630 10 348 380 4 208 205 1 45 240 1 60 400 3 340 380 8 200 340 20 360 292 6 433 543 6 162 222 2 280 212 1 33 806.686569 7 10000379.211635 3 100 468.843476 1 100 806.686569 4 5000 0 to 690 6 2400 0 to 690 6 2400 117 29 500 2 15 300 344 45 900 34 2800 200 2 3 25 34 2 50 344.5 15 300 415 1 Unknown 827 1 2200 350 1 140 350 1 130 350 1 Unknown Unknown 1 Unknown 415 1 Unknown 827 1 2200 350 1 140 350 1 Unknown Unknown 1 Unknown 360 1 75 1241 4 Unknown 100 1 Unknown Unknown 2 Unknown atmospheric 1 8400 atmospheric 1 1200 380 1 1600 Unknown 4 8400 0 1 44 0 1 4 0 1 4 0 1 4 860 2 1265 860 2 1265 860 2 1265 860 2 655 860 2 655 860 2 655 860 2 910 860 1 240 860 1 240 860 1 175 1100 1 215 1100 1 215 Process side pressure (kPa) 1 260 Process side pressure (kPa) 1 260 0 1 2100 0 1 1350 0 1 13500 1 2100 0 1 1500 0 1 2100 0 1 2600 575 2 200 0 1 125 0 1 125 173 1 125 570 1 1625 570 1 1625 570 1 1870 520 2 1870 1480 1 250 2585 1 1870 7 1 1870 1330 1 1870 0 3 9000 0 2 11600 380 1 240 520 3 750 1101 15 3000 1101 15 3000 1101 15 3000 1273 17 3000 1273 17 3000 1273 17 3000 722 33 2500 722 33 2500 722 33 2500 722 33 2500 722 33 2500 928 10 2500 928 10 2500 1101 15 2500 1101 15 2500 1101 15 2500 1273 17 2500 1273 17 2500 1273 17 2500 377 2 2500 1225 1 100 0 8 100 722 33 3000 722 33 3000 722 33 3000 722 33 3000 722 33 3000 928 10 3000 928 10 3000 896 16 20000 0 3 500 863 4 200689 10 2000 480 15 12500 130 3 1500 0 2 650**IsHeatExchangeSystemRegulated HeatExchangeSystemRegulations** 

No No No No No No No No No No No

Yes LAC 33:III.1311.C Yes LAC 33:III.1311.C Yes LAC 33:III.1311.C Yes LAC 33:III.1311.C Yes LAC 33:III.1311.C Yes LAC 33:III.1311.C Yes LAC 33:III.1311.C No No Yes State Permit Yes State Permit No Yes State Permit No No Yes 40CFR61+63 Yes 40CFR61+63 No No No No No No No No

Yes 40 CFR 63.104 No Yes 40 CFR 61 Yes 40 CFR 61 No No No No Yes No No Yes NoNo

No No Yes Subpart FFFF Yes Subpart FFFF No No No No No No No No No Yes 30 TAC 115 Sub. D Yes 30 TAC 115 Sub. D Yes 30 TAC 115 Sub. D No No No Yes 30 TAC 115 Sub. D Yes 30 TAC 115 Sub. D No Yes 30 TAC 115 Sub. D No No No No No No No Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116Yes 40 CFR 61, Subpart V; 30 TAC 116

Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Yes 40 CFR 61, Subpart V; 30 TAC 116 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No NoNo

Yes LAC 13; LAC 51 No No**HeatExchangeSystemType DoesSystemProcessFluidsContainingHA** **POrVOC HasInterveningFluid** 

Recirculating Yes No recirulating Yes No once-through Yes No once-through Yes No recirulating Yes No Once-Through No No once-through Yes No recirculating Yes No recirculating Yes No recirculating Yes No recirculating Yes No

Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes Yes Recirculating Yes Yes Recirculating Yes No Recirculating Yes No Recirculating Yes No Both Yes No Recirculating Yes No recirculating Yes No Recirculating CT Yes No Recirculating CT Yes No Recirculating recirculation Yes No recirculating Yes No recirculating Yes No recirculation Yes No once through Yes No once through No No once through No No

Recirculating Yes No N/A Yes No N/A Yes No N/A Yes No N/A No No N/A No No N/A No No RECIRCULATING No No Recirculating Yes No N/A Yes No N/A Yes No N/A Yes No Recirculating Yes NoRecirculating Yes Yes

Recirculating Yes Yes Recirculating Yes No R Yes No R Yes No Recirculating brine Yes No Recirculating brine No No Cooling Tower Yes No Cooling Tower Yes No Recirculating brine No No Cooling Tower Yes No Recirc brine Yes No Recirculating Yes No recirculating Yes No once-through Yes No once-through Yes No recirculating Yes No once-through Yes No Recirculating Yes No recirculating Yes No once-through Yes No recirculating Yes No once-through Yes No once-through Yes No Recirculating No No once-through Yes No recirculating Yes No Recirculating Yes No recirculating Yes No Recirculating No No Recirculating No No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No Recirc Yes No once through Yes No once through Yes No once through Yes No once through Yes No once through Yes No once through Yes No once through Yes No Recirc No Yes Recirc No Yes Recirc No YesRecirc No Yes

Recirc No Yes Recirc No Yes Recirc No Yes Recirc Yes No recirc Yes No recirc Yes No recirc Yes No recirc Yes No recirc Yes No recirc Yes No recirc Yes No once through Yes No recirc Yes No recirc Yes No recirc Yes No recirc Yes No recirc Yes No once through Yes No once through No No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculation Yes No RECIRCULATING Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No Recirculating Yes No RECIRCULATING Yes No RECIRCULATING Yes No RECIRCULATING Yes NoRECIRCULATING Yes No

Recirculating Yes No Recirculating Yes Yes Recirculating Yes Yes**DoesInterveningFluidContainHA POrVOC**  **TotalVOC_PctByWeight TotalVOCNote**  **HA P1** 

No NoNo

No

No No

Unknown Cumene Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride Unknown Methanol Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride

Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride Unknown Viny l chloride

N/A Unknown Cumene N/A Unknown Cumene N/A Unknown Cumene N/A Unknown Cumene N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown AcetaldehydeNo Unknown Acetaldehyde

No Unknown Acetaldehyde No Unknown Acetaldehyde No Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde N/A N/A Unknown Acetaldehyde N/A N/A N/A Unknown Acetaldehyde N/A Unknown Acetaldehyde No Unknown Acetaldehyde N/A Unknown AcetaldehydeNo

Yes 25 Ethylene glycol No**HA P1_PctByWeight**  **HA P1Note**  **HA P2**  **HA P2_PctByWeight**  **HA P2Note**  **HA P3** Unknown Methanol Unknown

Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde

Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde Unknown Methanol Unknown Acetaldehyde

Unknown Unknown Unknown Unknown Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown CumeneUnknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene

Unknown Acetophenone Unknown Cumene

Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene25**HA P3_PctByWeight**  **HA P3Note**  **HA P4**  **HA P4_PctByWeight**  **HA P4Note**  **HA P5** Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene

Unknown Unknown Unknown Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene

Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene Unknown Acetophenone Unknown Cumene

Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chlorideUnknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride

Unknown Formaldehyde Unknown Viny l chloride

Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride Unknown Formaldehyde Unknown Viny l chloride**HA P5_PctByWeight**  **HA P5Note**  **IsMonitoredForHA POrVOCInCoolingWater**  No Yes Yes

Yes No Yes No No No

Yes Yes Yes Yes Yes Yes Yes Yes

Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes

Yes

Yes No No No

Yes Yes Yes No NoNo No No Yes Yes No No No No No No No No Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown No No Yes

Unknown No Unknown No

Unknown No Unknown Yes Unknown Yes Unknown Yes No No Yes Yes Yes Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown YesUnknown Yes

Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Yes Unknown Yes Yes Yes Unknown Yes Unknown Yes Unknown Yes Unknown Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No Yes Yes Yes Yes Yes Yes Yes No No NoNo

No No**ProceduresToIdentifyLeaks MonitoringSamplingFreq** 

High readings identified by the VCM Area Monitoring System requires follow up investigation by Operator with hand held meter. Wa ter is not sampled / VCM Area Monitoring System GC monitoring of cooling tower airspace every 15 minutes Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours GC monitoring of cooling tower airspace every 15 minutes Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours HE's are monitored only when unusual conditions are noted. N/A

The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water.

Quarterly Wa ter is sampled weekly . If VOC detected than individual equipment is sampled. We ekly

Sam pling of the cooling tower for VCM/EDC/NMHC Tw ice per day Sam pling of the cooling tower for VCM/EDC/NMHC Tw ice per day Sam pling of the chill water tanks for VCM Tw ice per week Sam pling of cooling tower for VCM and NMHC We ekly Cooling water is obtained from the exhanger outlets and anayly zed for VCM concentration.

Quarterly Cooling water is obtained from the exhanger outlets and anayly zed for VCM concentration.

Quarterly Sam ples caught and analy zed We ekly Sam ples caught and analy zed We ekly Sam ples caught and analy zed 4 tim es daily Gas Chromatograph sample point every 15 minutes Gas Chromatograph sample point every 15 minutes Gas Chromatograph sample point every 15 minutes Gas Chromatograph sample point every 15 minutes None

LDAR and NESHAP Quarterly Monitoring Quarterly LDAR & NESHAP Quarterly Monitoring Quarterly LDAR Quarterly

Monitoring Quarterly LDAR Quarterly

Monitoring Quarterly LDAR and NESHAP Quarterly Monitoring daily leak patrol LDAR and NESHAP Quarterly Monitoring daily leak patrol LDAR and NESHAP Quarterly Monitoring daily leak patrol LDAR and NESHAP Quarterly Monitoring daily leak patrol LDAR and NESHAP Quarterly Monitoring Quarterly LDAR and NESHAP Quarterly Monitoring Quarterly LDAR and NESHAP Quarterly Monitoring Quarterly LDAR and NESHAP Quarterly Monitoring Quarterly Not required - not a major source of HAP emissions N/ANot required - not a major source of HAP emissions N/A

Not required - not a major source of HAP emissions N/A Not required - not a major source of HAP emissions N/A Quarterly Quarterly Brine would leak into the process and be picked up by process monitors Continuous analyzers and level m onitoring detect brine leaking into the process Brine leaks detected by process analy

zers, process levels and brine levels Continuous analyzers and level m onitoring detect brine leaking into the process Vessel testing and leakage into the process when depressurized 5 year pressure test and inspection. Vessel testing and Cycle W ater leakage into process 5 year pressure test and inspection. Brine leaks detected by process analy

zers, process levels and brine levels Continuous analyzers and level m onitoring detect brine leaking into the process Vessel testing and Cycle W ater leakage into process 5 year pressure test and inspection. Vessel testing and Brine leakage into process, when vessel depressurized 5 year pressure test/inspection and level during wash cycle. Process Side flow is not continuous If there were a failure of the exchanger, cooling water would back intothe process side and would be detectedi n the process. N/A We ekly testing of the chilled water to detect the presence of VCM. In addition, a GC/MS anlay zer is positioned at the vent of the chill water storage tank and would detect fugitive VCM. We ekly / Continuously Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly Periodic maintenance inspection. Although the centrate water may contain levels of HAPS, this system does not contain VCM and is not monitored.

None Process Side flow is not conintuous. If there were a failure of the exchanger, cooling water would back intothe process side and would be detectedi n the process. N/A We ekly testing of the chilled water to detect the presence of VCM. In addition, a GC/MS anlay zer is positioned at the vent of the chill water storage tank and would detect fugitive VCM. We ekly / Continuously Residual VCM is monitored in the outlet stream of the stripped slurry (hot side) every 8 hours Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly Periodic maintenance inspection. Although the centrate water may contain levels of HAPS, this system does not contain VCM and is not monitored.

None We ekly Sam ple of W W Stripper discharge. In addition, area GC monitors would detect fugitive VCM if present. We ekly

Although the centrate water may contain levels of HAPS, this system does not contain VCM and is not monitored. The chilled water is sampled and tested for VCM; Chill W ater storage tank has a GC/MS sample point running continuously which would detect VCM in the tank vapor space. We ekly Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly None N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day The stripped slurry

is sampled. The sample is analyzed for residual VCM Three times per day N/A N/A N/A N/A N/A N/AN/A N/A

N/A N/A N/A N/A N/A N/A sample only when needed The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly DCS Continuous DCS Continuous DCS Continuous DCS Continuous Sam ple We ekly Refrigeration machine shutdown N/A Refrigeration machine shutdown N/A Refrigeration machine shutdown N/A The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly The stripped waste water sampled. The sample is analyzed for residual VCM We ekly N/A N/A Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Pm 's by contractor. Check for leaks and amount of Freon 134a lost. Refill and record amount Quarterly Routine sampling of System Once per week None Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day None None NoneNone

None None None**TestMethod1 TestMethod2**  **TestMethod3 TestMethod4**  Wa ter is not sampled / VCM Area Monitoring System

Real-time Gas Chromotography EPA-107 EPA-107 Real-time Gas Chromotography EPA-107 EPA-107

Method 624 Method 624 Method 624 Method 624 Method 624 Method 624 Method 624 106

EPA Method 601 EPA Method 601 EPA Method 601 EPA Method 601 EPA Method 107 EPA Method 107 Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" Real Time Gas Chromatography Real Time Gas Chromatography Real Time Gas Chromatography Real Time Gas Chromatography

Method 107 Method 107 Method 107 Method 107

Method 107 Method 107 Method 107 Method 107 N/AN/A

N/A N/A 415.1

415.1 Near Infrared level m easurement Near Infrared Level m easurement N/A N/A Near Infrared Level m easurement N/A N/A N/A EPA-107 EPA-107 EPA-107 EPA-107 None N/A EPA-107 EPA-107 EPA-107 None EPA-107

Although the centrate water may contain levels of HAPS, this system does not contain VCM and is not monitored. EPA-107 EPA-107 EPA-107

N/A N/A N/A N/A N/A EPA107 (W eekly) Method 624 (Monthly) EPA107 (W eekly) Method 624 (Monthly) EPA107 (W eekly) Method 624 (Monthly) EPA107 (W eekly) Method 624 (Monthly) EPA107 (W eekly) Method 624 (Monthly) EPA107 (W eekly) Method 624 (Monthly) EPA107 (W eekly) Method 624 (Monthly) EPA107 EPA107 EPA107 EPA107 EPA107 EPA107 EPA107 N/A N/A N/AN/A

N/A N/A N/A titration EPA107 Method 624 EPA107 Method 624 EPA107 Method 624 N/A N/A N/A N/A EPA107 N/A N/A N/A EPA107 Method 624 EPA107 Method 624 EPA107 N/A Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107

Gas Chromotograph

Method 107 Method 107 Method 107 Method 107 Method 107 Method 107 Method 107**LocationOfCollectedSamples Ar** **eSurrogateIndicatorsUsedToDetectLeaks** Yes Stationary

sampling point above hot water basin No discharge of stripped slurry exchanger No discharge of stripped slurry exchanger No Stationary

sampling point above hot water basin No discharge of stripped slurry exchanger No discharge of stripped slurry exchanger No Chilled water storage tank owned and operated by PolyOne. No No No No

Inlet and outlet of cooling tower No Inlet and outlet of cooling tower No Inlet and outlet of cooling tower No Inlet and outlet of cooling tower No Inlet and outlet of cooling tower No Inlet and outlet of cooling tower No Inlet and outlet of cooling tower No Wa ter utility

station

Cooling Tower No Cooling Tower No Chill water tanks No Cooling Tower No Exchanger outlet No Exchanger outlet No Cooling Tower Outlet No Cooling Tower Outlet No Cooling Tower Outlet No air space above hot water basin No air space above hot water basin No air space above hot water basin No air space above hot water basin No No No No

Cooling Tower entrance and exit No Connectors No Connectors No Connectors No

Connectors No Connectors No Connectors No Connectors No N/A NoN/A No

N/A No N/A No CTW inlet and outlet No CTW inlet and outlet No Inline optic monitor, no external samples No No, Inprocess anayzers and level m easurements No N/A No N/A No No, Inprocess anayzers and level m easurements No N/A No N/A No No No Chill water pum p discharge No discharge of stripper economizer No discharge of stripper economizer No Cooling Tower Basin No N/A No N/A No Chill water pum p discharge No discharge of stripper economizer No Cooling Tower Basin No N/A No Discharge of Stripper to process sewer No

Chill water pum p discharge No Cooling Tower Basin No Cooling Tower pump discharge No N/A No N/A No N/A No N/A No N/A No N/A No Pum p discharge. No Pum p discharge. No Pum p discharge. No Pum p discharge. No Pum p discharge. No Pum p discharge. No Pum p discharge. No U308 & U408 outlet No U308 & U408 outlet No U508 outlet No U608 & U708 outlet No U608 & U708 outlet No U908 & U908 outlet No U908 & U908 outlet No N/A No N/A No N/A NoN/A No

N/A No N/A No N/A No

pum p discharge No Pum p discharge. No Pum p discharge. No Pum p discharge. No N/A Yes N/A Yes N/A Yes N/A Yes Pum p discharge. No N/A Yes N/A Yes N/A Yes Pum p discharge No Pum p discharge No Pum p discharge No N/A No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No From sample bleed on outlet of chilled water pumps No No Refrigeration W ater Collection Tank No

From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No From Cooling tower as water falls into basin. No**SurrogateIndicatorsUsed ValueToIndicateA**  **Leak**

VCM Area Monitoring Follow Up Investigation by Operator with Hand Held Meter

N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A

>5 ppb/>5 ppb/>30 ppb >5 ppb/>5 ppb/>30 ppb >5 ppb < 50 ppb

N/AN/A N/A N/A N/A N/A N/A N/A

N/A N/A N/A N/A N/A N/A N/A N/AFeed Rate Being reduced by controller Feed Rate Being reduced by controller FeedRate Being reduced by controller FeedRate Being reduced by controller

Shutdown Down Shutdown Down Shutdown Down**Monitoring Programs**

Count of ValueToIndicateALeak CompanyName FacilityName IsHeatExchangeSystemRegulated HeatExchangeSystemRegulations HeatExchangeSystemType IsMonitoredForHAPOrVOCInCoolingWater ProceduresToIdentifyLeaks MonitoringSamplingFreq TestMethod1 TestMethod2 TestMethod3 TestMethod4 LocationOfCollectedSamples AreSurrogateIndicatorsUsedToDetectLeaks SurrogateIndicatorsUsed ValueToIndicateALeak Total Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge Yes LAC 33:III.1311.C Recirculating Yes The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 (blank) (blank) (blank) Inlet and outlet of cooling tower No N/A N/A 7 Formosa Plastics Corporation Point Comfort - PVC Unit Yes State Permit Recirculating Yes Sampling of the cooling tower for VCM/EDC/NMHC Twice per day EPA Method 601 (blank) (blank) (blank) Cooling Tower No (blank) >5 ppb/>5 ppb/>30 ppb 2 Formosa Plastics Corporation, Point Comfort - Specialty Polyvinyl Chloride (SPVC) Unit Yes State Permit Both Yes Sampling of cooling tower for VCM and NMHC Weekly EPA Method 601 (blank) (blank) (blank) Cooling Tower No (blank) < 50 ppb 1 Georgia Gulf Corporation Georgia Gulf Chemicals Plaquemine Facility Yes 40CFR61+63 Recirculating CT Yes Samples caught and analyzed Weekly Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" (blank) (blank) (blank) Cooling Tower Outlet No (blank) (blank) OxyVinyls, LP OxyVinyls Deer Park Yes 30 TAC 115 Sub. D Recirculating Yes Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. Monthly EPA-107 (blank) (blank) (blank) Cooling Tower Basin No (blank) (blank) (blank) Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. Monthly EPA-107 (blank) (blank) (blank) Cooling Tower Basin No (blank) (blank) OxyVinyls Pasadena Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes The chilled water is sampled. The sample is analyzed for VCM. Weekly & Monthly EPA107 (Weekly) Method 624 (Monthly) (blank) (blank) Pump discharge. No (blank) (blank) The cooling water is sampled. The sample is analyzed for VCM. Weekly & Monthly EPA107 Method 624 (blank) (blank) Pump discharge. No (blank) (blank) EPA107 (Weekly) Method 624 (Monthly) (blank) (blank) Pump discharge. No (blank) (blank) 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes DCS Continuous N/A (blank) (blank) (blank) N/A Yes Feed Rate Being reduced by controller 2 FeedRate Being reduced by controller 2 N/A N/A N/A (blank) (blank) (blank) N/A No N/A N/A 4 (blank) (blank) Refrigeration machine shutdown N/A N/A (blank) (blank) (blank) N/A Yes Shutdown Down 3 sample only when needed titration (blank) (blank) (blank) pump discharge No (blank) (blank) The cooling water is sampled. The sample is analyzed for VCM. Weekly & Monthly EPA107 Method 624 (blank) (blank) pump discharge No (blank) (blank) Shintech, Inc. Corporate Office Shintech Addis Yes 40 CFR 63.104 Recirculating Yes LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 (blank) (blank) (blank) Cooling Tower entrance and exit No (blank) (blank) Shintech Plaquemine Yes (blank) Recirculating Yes LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 (blank) (blank) (blank) Connectors No (blank) (blank) The Dow Chemical Company Dow Midland - SARAN Resins Yes Subpart FFFF R Yes (blank) Quarterly 415.1 (blank) (blank) (blank) CTW inlet and outlet No N/A N/A 2 Westlake Chemical Corporation Westlake Geismar Yes LAC 13; LAC 51 Recirculating (blank) None (blank) (blank) (blank) (blank) (blank) (blank) (blank) (blank) (blank) Grand Total 23**Summary of Monitoring Programs**

**CompanyName FacilityName**  **IsHeatExchangeSystem Regulated**  **HeatExchangeSystemRe gulations**  **HeatExchangeSystemTy**

**pe IsMonitoredForHAPOrV** 

**OCInCoolingWater ProceduresToIdentifyLe**  **aks MonitoringSamplingFreq**  **TestMethod1 TestMethod2**  **TestMethod3 TestMethod4**  **LocationOfCollectedSa mples**  **AreSurrogateIndicatorsU**

**sedToDetectLeaks SurrogateIndicatorsUse**  **d ValueToIndicateALeak** 

Formosa Baton Rouge Yes LAC 33:III.1311.C Recirculating Yes The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 Inlet and outlet of cooling tower No N/A N/A

Formosa Point Comfort - PVC Unit Yes State Permit Recirculating Yes Sampling of the cooling tower for Twice per day EPA Method 601 Cooling Tower No >5 ppb/>5 ppb/>30 ppb

Formosa Point Comfort - Specialty Polyvinyl Chloride (SPVC) Unit Yes State Permit Both Yes Sampling of cooling tower for VCM and NMHC We ekly EPA Method 601 Cooling Tower No < 50 ppb

Georgia Gulf Plaquemine Yes 40CFR61+63 Recirculating CT Yes Samples caught and analyzed We ekly Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Cooling Tower Outlet No

OxyVinyls Deer Park Yes 30 TAC 115 Sub. D Recirculating Yes Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. Monthly EPA-107 Cooling Tower Basin No

OxyVinyls Deer Park Yes 31 TAC 115 Sub. D Recirculating Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. Monthly EPA-107 Cooling Tower Basin No

OxyVinyls Pasadena Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) Method 624 (Monthly) Pump discharge. No

OxyVinyls Pasadena Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 Method 624 Pump discharge. No

OxyVinyls Pasadena Yes 40 CFR 61, Subpart F; 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) Method 624 (Monthly) Pump discharge. No

OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes DCS Continuous N/A N/A Yes Feed Rate Being reduced by controller TAC 116 OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes DCS Continuous N/A N/A Yes FeedRate Being reduced by controller OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes N/A N/A N/A N/A No N/A N/A

OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes N/A N/A N/A N/A No

OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes Refrigeration machine shutdown N/A N/A N/A Yes Shutdown Down

OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes sample only when needed titration pump discharge No

OxyVinyls Pasadena Yes 40 CFR 61, Subpart V; 30 TAC 116 Recirc Yes The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 Method 624 pump discharge No

Shintech Addis Yes 40 CFR 63.104 Recirculating Yes LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 Cooling Tower entrance and exit No

Shintech Plaquemine Yes Recirculating Yes LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 Connectors No

Dow Midland Yes Subpart FFFF R Yes Quarterly 415.1 CTW inlet and outlet No N/A N/A We stlake Geismar Yes LAC 13; LAC 51 Recirculating None**Cooling Water Flow Rates**

Sum of CoolingW aterFlowRateAvg_Gpm CompanyName FacilityName ProcessUnitID HeatExchangeSystemType ProcessEquipID1 Total CertainTeed Corporation Lake Charles Polymer Plant P-1 Recirculating U-10a 100 U-10d 100 U-5a #### P-2 Recirculating U-16a 5000 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Recirculating PE205A 125 PE206A 250 PE206B 250 PE301 PE303A/B PE304A/B 1500 PE309 50 Formosa Plastics Corporation Deleware City P1 Recirculating U-14 4000 P-2 Recirculating U-60 Formosa Plastics Corporation Point Comfort - PVC Unit P-1 Recirculating U-19 #### U-3 #### U-7 #### Georgia Gulf Corporation Georgia Gulf Chemicals Aberdeen Facility 1 Recirculating U-34 thru 45 1000 U-46 thru 53 1000 Georgia Gulf Chemicals Plaquemine Facility P-1 Recirculating U-166 thru U-173 #### U-182 1181 Recirculating CT U-175 #### U-176 #### OxyVinyls, LP OxyVinyls Deer Park P-1 Recirculating U-102 0 U-118 0 U-135 2200 P-2 Recirculating U-202 0 U-214 0 U-231 2200 P-4 Recirculating U-404 0 U-410 8400 U-411 1200 U-413 8400 U-414 1600 U-419 0 OxyVinyls Pasadena P1 Recirc U119 44 U120 4 U121 4 U122 4 P10 Recirc U1006 200 U1027 1625 U1028 1870 U1030 1625 U1031 1870 U1033 1870 U1034 1870 U1037 1870 U1041 125 U1046 125 U1051 125 P11 Recirc U1103 9000 U1104 #### P3 Recirc U300 1265 U308 2100 P4 Recirc U400 1265 U408 1350 P5 Recirc U500 1265 U508 1350 P5 Recirc U500 1265 U508 1350 P6 Recirc U600 655 U608 2100 P7 Recirc U700 655 U708 1500 P8 Recirc U800 655 U808 2100 P9 Recirc U900 910 U908 2600 OxyVinyls Pedricktown P-1 recirulating U-100 1200 P-2 recirulating U-200 1200 P-3 Recirculating U-303 5 U-309 30 U-310 20 U-311 15 P-5 recirculation U-508 50 P-6 Recirculating U-600 #### U-611 70 recirculation U-616 150 PolyOne Corporation PolyOne Henry Chilled H2O - L4 Recirculating P-14 Chilled H2O for P-4 2500 P-13 Cooling Twr for P-1 Recirculating Poly 21 Jacket 3000 Poly 26 Condenser 3000 Poly 28 Jacket 3000 Poly 33 Condenser 3000 Poly 35 Jacket 3000 P-13 Cooling Twr for P-2 Recirculating Poly 37 Jacket 3000 Poly 40 Condenser 3000 P-13 Cooling Twr for P-4 Recirculating Poly 1 Jacket 3000 Poly 4 Baffle 3000 Seal H2O Heat Xch 3000 P-13 Cooling Twr for P-5 Recirculating Poly 11 Baffle 3000 Poly 12 Jacket 3000 Poly 5 Jacket 3000 P-14 Chilled H2O for P-1 Recirculating Poly 21 Jacket 2500 Poly 26 Condenser 2500 Poly 28 Jacket 2500 Poly 33 Condenser 2500 Poly 35 Jacket 2500 P-14 Chilled H2O for P-2 Recirculating Poly 1 Jacket 2500 Poly 37 Jacket 2500 Poly 4 Baffle 2500 Poly 40 Condenser 2500 P-14 Chilled H2O for P-5 Recirculating Poly 11 Baffle 2500 Poly 12 Jacket 2500 Poly 5 Jacket 2500 P-14 Chillers Recirculating Chiller Unit 1 2500 PolyOne Pedricktown P-1 recirculation U-18 100 Shintech, Inc. Corporate Office Shintech Addis P-1 Recirculating U-28 449 Shintech Freeport P-1 Recirculating U-14A thru F 360 Shintech Plaquemine P-1 Recirculating U-25 433 The Dow Chemical Company Dow Midland - SARAN Resins Vinyl Train R CTW -1 4800 Union Carbide Corporation Union Carbide Texas City P-1, P-2, P-3 Cooling Tower U-14 900 P-2 Cooling Tower U-34 50 P-2, P-3 Cooling Tower U-20 200 We stlake Chemical Corporation We stlake Calvert City P-1 Recirculating U-17 #### U-22 500 U-30 200 U-40 2000 U-8 100 We stlake Geismar P-1 Recirculating U-13 650 U-3 #### U-31 1500 Grand Total ####**Reported Emisisons from Cooling Towers - Survey Data Responses**

**CompanyName FacilityName**  **ProcessUnitID ProcessEquipID**  **ProcessEquipType ExitingProcessEquip**  **TotalVOCOrHAPDesc Pounds**  **BasisForEmissions** CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 1,3-Butadiene CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Chlorine CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Ethyl chloride (Chloroethane) CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Ethylene dichloride (1,2-Dichloroethane) CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Ethylene glycol CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Hydrochloric acid CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Methyl chloride (Chloromethane) CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Total VOC CertainTeed Corporation Lake Charles Polymer Plant P-1 U-13 Cooling Tower EP-4 Vinyl chloride CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 1,3-Butadiene CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 Ethyl chloride (Chloroethane) CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 Ethylene dichloride (1,2-Dichloroethane) CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 Ethylene glycol CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 Methyl chloride (Chloromethane) CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 Total VOC CertainTeed Corporation Lake Charles Polymer Plant P-2 U-19 Cooling Tower EP-8 Vinyl chloride OxyVinyls, LP OxyVinyls Pasadena P-11 U-1103 Cooling Tower E-310/E-311/318 EP-1117 Other VOC 1410 U-1103 / EP-1117 OxyVinyls, LP OxyVinyls Pasadena P-11 U-1103 Cooling Tower E-310/E-311/318 EP-1117 Other VOC 1655 U-1104 / EP-1130 OxyVinyls, LP OxyVinyls Pasadena P-11 U-1103 Cooling Tower E-310/E-311/318 EP-1117 Total VOC OxyVinyls, LP OxyVinyls Pasadena P-11 U-1103 Cooling Tower E-310/E-311/318 EP-1117 Vinyl chloride 188 U-1103 / EP-1117 OxyVinyls, LP OxyVinyls Pasadena P-11 U-1103 Cooling Tower E-310/E-311/318 EP-1117 Vinyl chloride 361 U-1104 / EP-1130 OxyVinyls, LP OxyVinyls Pedricktown P-6 U-600 Cooling Tower EP-600 Acetaldehyde OxyVinyls, LP OxyVinyls Pedricktown P-6 U-600 Cooling Tower EP-600 Total VOC OxyVinyls, LP OxyVinyls Pedricktown P-6 U-600 Cooling Tower EP-600 Vinyl chloride Shintech, Inc. Corporate Office Shintech Addis P-1 U-62 COOLING TOWER EP-22 Chlorine 200 Engineering Estimate Shintech, Inc. Corporate Office Shintech Addis P-1 U-62 COOLING TOWER EP-22 Ethyl chloride (Chloroethane) Shintech, Inc. Corporate Office Shintech Addis P-1 U-62 COOLING TOWER EP-22 Hydrochloric acid Shintech, Inc. Corporate Office Shintech Addis P-1 U-62 COOLING TOWER EP-22 Methanol Shintech, Inc. Corporate Office Shintech Addis P-1 U-62 COOLING TOWER EP-22 Total VOC 0 Engineering Estimate Shintech, Inc. Corporate Office Shintech Addis P-1 U-62 COOLING TOWER EP-22 Vinyl chloride Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Acetaldehyde Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Benzene (including benzene from gasoline) Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Carbon tetrachloride Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Chlorine Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Chloroform Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Ethyl chloride (Chloroethane) Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Ethylene dichloride (1,2-Dichloroethane) Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Ethylidene dichloride (1,1-Dichloroethane) Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Hydrochloric acid Shintech, Inc. Corporate Office Shintech Plaquemine COOLING TOWER Hydrochloric acid Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Methanol Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Methyl chloride (Chloromethane) Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Total VOC 0 Material Balance Shintech, Inc. Corporate Office Shintech Plaquemine P-1 U-58 COOLING TOWER EP-19 Vinyl chloride The Dow Chemical Company Dow Midland - SARAN Resins Vinyl Train CTW-1 Cooling Tower EP-5 Total VOC 0 Engineering Estimate The Dow Chemical Company Dow Midland - SARAN Resins Vinyl Train CTW-1 Cooling Tower EP-5 Vinyl chloride 0 Engineering Estimate The Dow Chemical Company Dow Midland - SARAN Resins Vinyl Train CTW-1 Cooling Tower EP-5 Vinylidene chloride (1,1-Dichloroethylene) 0 Engineering Estimate Westlake Chemical Corporation Westlake Calvert City P-1 U-89 Cooling Tower EP-26 Hydrochloric acid Westlake Chemical Corporation Westlake Calvert City P-1 U-89 Cooling Tower EP-26 Methanol Westlake Chemical Corporation Westlake Calvert City P-1 U-89 Cooling Tower EP-26 Methyl chloride (Chloromethane) Westlake Chemical Corporation Westlake Calvert City P-1 U-89 Cooling Tower EP-26 Total VOC Material Balance Westlake Chemical Corporation Westlake Calvert City P-1 U-89 Cooling Tower EP-26 Vinyl chloride Material Balance Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Benzene (including benzene from gasoline) Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Carbon tetrachloride Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Chlorine Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Chlorobenzene Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Chloroform Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Ethyl chloride (Chloroethane) Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Ethylene dichloride (1,2-Dichloroethane) Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Hydrochloric acid Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Tetrachloroethylene (Perchloroethylene) Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Toluene Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Total VOC 0 Engineering Estimate Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Trichloroethylene Westlake Chemical Corporation Westlake Geismar P-1 U-40 Cooling Water Tower EP-10 Vinyl chloride 0 Engineering Estimate

### Section 114 Survey **Form C-1-A**

**Data Summary**

**CompanyName** CertainTeed Corporation

CertainTeed Corporation Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA

Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA

Formosa Plastics Corporation USA Georgia Gulf Corporation

Georgia Gulf

Oxy viny ls

Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LPOxy

Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP

Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP PolyOne Corporation PolyOne CorporationShintech, Inc. Corporate Office

Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office The Dow Chemical Company The Dow Chemical Company

We stlake Chemical Corporation We stlake Chemical Corporation

We stlake Chemical Corporation

### Section 114 Survey **Form C-1-A**

**Data Summary**

**FacilityName ProcessUnitID**  **ProcessEquipID** Lake Charles Poly me r Plant P-1 U-13

Lake Charles Poly me r Plant P-2 U-19 Formosa Plastics Corporation Baton Rouge P-1 U-10 Formosa Plastics Corporation Baton Rouge P-1 U-10 Formosa Plastics Corporation Baton Rouge P-1 U-10

Formosa Plastics Corporation Deleware City P-1 U-14 Formosa Plastics Corporation Deleware City P-1 U-14 Formosa Plastics Corporation Deleware City P-1 U-14 Formosa Plastics Corporation Deleware City P-2 U-73 Formosa Plastics Corporation Deleware City P-2 U-73 Formosa Plastics Corporation Deleware City P-2 U-73 Formosa Plastics Corporation Point Comfort - PVC Unit P-1 U-24

Formosa Plastics Corporation, Point Comfort - Specialty Poly viny l Chloride (SPVC) Unit

P-2 U-17 Georgia Gulf Chemicals Aberdeen Facility 1 U-66, 67, 68, 69

Plaquem ine

Deer Park

Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1103 Oxy Vinyls Pasadena P-11 U-1104 Oxy Vinyls Pasadena P-11 U-1104Oxy

Vinyls Pasadena P-11 U-1104 Oxy Vinyls Pasadena P-11 U-1104 Oxy Vinyls Pasadena P-11 U-1104 Oxy Vinyls Pasadena P-11 U-1104

Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 Oxy Vinyls Pedricktown P-6 U-600 PolyOne Henry P-13 U-1 PolyOne Henry P-13 U-1Shintech Addis P-1 U-62

Shintech Freeport P-1 U-45 Shintech Plaquem ine P-1 U-58 Dow Midland - SARAN Resins Viny l Train CTW -1 Dow Midland - SARAN Resins Viny l Train CTW -1

We stlake Calvert City P-1 U-89 We stlake Calvert City P-1 U-89

We stlake Geismar P-1 U-40**ProcessEquipType ExitingProcessEquip**  **IsShared**

**SharedProcessUnitID** Cooling Tower EP-4

Cooling Tower EP-8 Cooling Tower No N/A Cooling Tower No N/A Cooling Tower EP-16 No N/A

Cooling tower S-2 No Cooling tower S-3 No Cooling tower W- 8 No Cooling tower S-2 No Cooling tower S-3 No Cooling tower W- 8 No Cooling Tower EP Yes VCM Unit

COOLING TOW ER EP-9 No Cooling Towers EP-12 No

Cooling Tower E-310/E-311/318 EP-1117 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1118 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1119 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1120 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1121 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1122 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1123 Yes P10,P12 Cooling Tower E-310/E-311/318 S-1124 Yes P10,P12 Cooling Tower E-618/956 EP-1130 Yes P*, P10 Cooling Tower E-618/956 S-1131 Yes P*, P10Cooling Tower E-618/956 S-1132 Yes P*, P10

Cooling Tower E-618/956 S-1133 Yes P*, P10 Cooling Tower E-618/956 S-1134 Yes P*, P10 Cooling Tower E-618/956 S-1135 Yes P*, P10

Cooling Tower EP-600 Yes P-1 Cooling Tower S-610 Yes P-1 Cooling Tower S-611 Yes P-1 Cooling Tower S-612 Yes P-1 Cooling Tower S-613 Yes P-2 Cooling Tower S-614 Yes P-2 Cooling Tower S-615 Yes P-2 Cooling Tower S-616 Yes P-5 Cooling Tower S-617 Yes P-5 Cooling Tower S-618 Yes P-2 Cooling Tower S-636 No Cooling Tower S-639 No Cooling Tower EP-1 No Cooling Tower S-1 NoCOOLING TOW ER EP-22 No

COOLING TOW ERS EP-13 No COOLING TOW ER EP-19 No Cooling Tower EP-5 Yes MA Train Cooling Tower W- 9 Yes MA Train

Cooling Tower EP-26 No Cooling Tower W- 8 No

Cooling W ater Tower EP-10 NoCertainTeed Corporation Lake Charles Poly me r Plant P-1

CertainTeed Corporation Lake Charles Poly me r Plant P-1 CertainTeed Corporation Lake Charles Poly me r Plant P-1 CertainTeed Corporation Lake Charles Poly me r Plant P-2 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Deleware City P1 Formosa Plastics Corporation USA Formosa Plastics Corporation Deleware City P-2

Formosa Plastics Corporation USA Formosa Plastics Corporation Point Comfort - PVC Unit P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Point Comfort - PVC Unit P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Point Comfort - PVC Unit P-1

Georgia Gulf Corporation Georgia Gulf Chemicals Aberdeen Facility 1 Georgia Gulf Corporation Georgia Gulf Chemicals Aberdeen Facility 1 Georgia Gulf Corporation Georgia Gulf Chemicals Plaquemine Facility P-1 Georgia Gulf Corporation Georgia Gulf Chemicals Plaquemine Facility P-1 Georgia Gulf Corporation Georgia Gulf Chemicals Plaquemine Facility P-1 Georgia Gulf Corporation Georgia Gulf Chemicals Plaquemine Facility P-1 Oxy Vinyls, LP Oxy Vinyls Deer Park P-1 Oxy Vinyls, LP Oxy Vinyls Deer Park P-1 Oxy Vinyls, LP Oxy Vinyls Deer Park P-1 Oxy Vinyls, LP Oxy Vinyls Deer Park P-2 Oxy Vinyls, LP Oxy Vinyls Deer Park P-2 Oxy Vinyls, LP Oxy Vinyls Deer Park P-2 Oxy Vinyls, LP Oxy Vinyls Deer Park P-4 Oxy Vinyls, LP Oxy Vinyls Deer Park P-4 Oxy Vinyls, LP Oxy Vinyls Deer Park P-4 Oxy Vinyls, LP Oxy Vinyls Deer Park P-4 Oxy Vinyls, LP Oxy Vinyls Deer Park P-4 Oxy Vinyls, LP Oxy Vinyls Deer Park P-4 Oxy Vinyls, LP Oxy Vinyls Pasadena P1 Oxy Vinyls, LP Oxy Vinyls Pasadena P1 Oxy Vinyls, LP Oxy Vinyls Pasadena P1 Oxy Vinyls, LP Oxy Vinyls Pasadena P1 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10Oxy

Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P10 Oxy Vinyls, LP Oxy Vinyls Pasadena P11 Oxy Vinyls, LP Oxy Vinyls Pasadena P11 Oxy Vinyls, LP Oxy Vinyls Pasadena P3 Oxy Vinyls, LP Oxy Vinyls Pasadena P3 Oxy Vinyls, LP Oxy Vinyls Pasadena P4 Oxy Vinyls, LP Oxy Vinyls Pasadena P4 Oxy Vinyls, LP Oxy Vinyls Pasadena P5 Oxy Vinyls, LP Oxy Vinyls Pasadena P5 Oxy Vinyls, LP Oxy Vinyls Pasadena P6 Oxy Vinyls, LP Oxy Vinyls Pasadena P6 Oxy Vinyls, LP Oxy Vinyls Pasadena P7 Oxy Vinyls, LP Oxy Vinyls Pasadena P7 Oxy Vinyls, LP Oxy Vinyls Pasadena P8 Oxy Vinyls, LP Oxy Vinyls Pasadena P8 Oxy Vinyls, LP Oxy Vinyls Pasadena P9 Oxy Vinyls, LP Oxy Vinyls Pasadena P9 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-1 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-2 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-3 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-3 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-3 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-3 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-5 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-6 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-6 Oxy Vinyls, LP Oxy Vinyls Pedricktown P-6

PolyOne Corporation PolyOne Henry Chilled H2O - L4 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-1 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-2 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-2 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-4 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-4 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-4 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-5 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-5 PolyOne Corporation PolyOne Henry P-13 Cooling Twr for P-5 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-1 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-1PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-2

PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-2 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-5 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-5 PolyOne Corporation PolyOne Henry P-14 Chilled H2O for P-5 PolyOne Corporation PolyOne Henry P-14 Chillers PolyOne Corporation PolyOne Pedricktown P-1 Shintech, Inc. Corporate Office Shintech Addis P-1 Shintech, Inc. Corporate Office Shintech Freeport P-1 Shintech, Inc. Corporate Office Shintech Plaquem ine P-1 The Dow Chemical Company Dow Midland - SARAN Resins Viny l Train

Union Carbide Corporation Union Carbide Texas City P-1, P-2, P-3 Union Carbide Corporation Union Carbide Texas City P-2 Union Carbide Corporation Union Carbide Texas City P-2, P-3 We stlake Chemical Corporation We stlake Calvert City P-1 We stlake Chemical Corporation We stlake Calvert City P-1 We stlake Chemical Corporation We stlake Calvert City P-1 We stlake Chemical Corporation We stlake Calvert City P-1 We stlake Chemical Corporation We stlake Calvert City P-1 We stlake Chemical Corporation We stlake Geismar P-1 We stlake Chemical Corporation We stlake Geismar P-1 We stlake Chemical Corporation We stlake Geismar P-1**Ty pe**  **Unit ID(s) Rate (gpm)**  **Number of HTEX** Recirculating U-10a 100 3 Recirculating U-10d 100 1 Recirculating U-5a 10000 7 Recirculating U-16a 5000 4 Recirculating PE205A 125 12 Recirculating PE206A 250 12 Recirculating PE206B 250 12 Recirculating PE301 12 Recirculating PE303A/B 12 Recirculating PE304A/B 1500 12 Recirculating PE309 50 12 Recirculating U-14 4000 21 Recirculating U-60 15

Recirculating U-19 46200 4 Recirculating U-3 66300 10 Recirculating U-7 46200 7

Recirculating U-34 thru 45 1000 12 Recirculating U-46 thru 53 1000 9 Recirculating U-166 thru U-173 17000 26 Recirculating U-182 1181 0 Recirculating CT

U-175 40000 47 Recirculating CT

U-176 22300 10 Recirculating U-102 0 1 Recirculating U-118 0 1 Recirculating U-135 2200 1 Recirculating U-202 0 1 Recirculating U-214 0 1 Recirculating U-231 2200 1 Recirculating U-404 0 2 Recirculating U-410 8400 1 Recirculating U-411 1200 1 Recirculating U-413 8400 1 Recirculating U-414 1600 4 Recirculating U-419 0 4 Recirc U119 44 1 Recirc U120 4 1 Recirc U121 4 1 Recirc U122 4 1 Recirc U1006 200 2 Recirc U1027 1625 1 Recirc U1028 1870 1 Recirc U1030 1625 1 Recirc U1031 1870 2 Recirc U1033 1870 1Recirc U1034 1870 1

Recirc U1037 1870 1 Recirc U1041 125 1 Recirc U1046 125 1 Recirc U1051 125 1 Recirc U1103 9000 3 Recirc U1104 11600 2 Recirc U300 1265 2 Recirc U308 2100 1 Recirc U400 1265 2 Recirc U408 1350 1 Recirc U500 1265 2 Recirc U508 1350 1 Recirc U600 655 2 Recirc U608 2100 1 Recirc U700 655 2 Recirc U708 1500 1 Recirc U800 655 2 Recirc U808 2100 1 Recirc U900 910 2 Recirc U908 2600 1 recirulating U-100 1200 3 recirulating U-200 1200 3 Recirculating U-303 5 4 Recirculating U-309 30 1 Recirculating U-310 20 3 Recirculating U-311 15 3 recirculation U-508 50 5 Recirculating U-600 13333 4 Recirculating U-611 70 1 recirculation U-616 150 1

Recirculating P-14 Chilled H2O for P-4 2500 15 Recirculating Poly

21 Jacket 3000 33 Recirculating Poly

26 Condenser 3000 33 Recirculating Poly

28 Jacket 3000 33 Recirculating Poly

33 Condenser 3000 33 Recirculating Poly

35 Jacket 3000 33 Recirculating Poly

37 Jacket 3000 10 Recirculating Poly

40 Condenser 3000 10 Recirculating Poly

1 Jacket 3000 15 Recirculating Poly

4 Baffle 3000 15 Recirculating Seal H2O Heat Xch 3000 15 Recirculating Poly

11 Baffle 3000 17 Recirculating Poly

12 Jacket 3000 17 Recirculating Poly

5 Jacket 3000 17 Recirculating Poly

21 Jacket 2500 33 Recirculating Poly

26 Condenser 2500 33 Recirculating Poly

28 Jacket 2500 33 Recirculating Poly

33 Condenser 2500 33 Recirculating Poly

35 Jacket 2500 33Recirculating Poly 1 Jacket 2500 15 Recirculating Poly

37 Jacket 2500 10 Recirculating Poly

4 Baffle 2500 15 Recirculating Poly

40 Condenser 2500 10 Recirculating Poly

11 Baffle 2500 17 Recirculating Poly

12 Jacket 2500 17 Recirculating Poly

5 Jacket 2500 17 Recirculating Chiller Unit 1 2500 2 recirculation U-18 100 1 Recirculating U-28 449 7 Recirculating U-14A thru F 360 20 Recirculating U-25 433 6 R CTW -1 4800 6

Cooling Tower U-14 900 45 Cooling Tower U-34 50 2 Cooling Tower U-20 200 2800 Recirculating U-17 20000 16 Recirculating U-22 500 3 Recirculating U-30 200 4 Recirculating U-40 2000 10 Recirculating U-8 100 8 Recirculating U-13 650 2 Recirculating U-3 12500 15 Recirculating U-31 1500 3**How Leaks Id'd Freq**  **Me thod** 

Not required - not a major source of HAP emissions N/A N/A Not required - not a major source of HAP emissions N/A N/A Not required - not a major source of HAP emissions N/A N/A Not required - not a major source of HAP emissions N/A N/A The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 Wa ter is sampled weekly . If VOC detected than individual equipment is sampled. We ekly 106 0 0 0 #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A Sam pling of the cooling tower for VCM/EDC/NMHC Tw ice per day EPA Method 601 Sam pling of the chill water tanks for VCM Tw ice per week EPA Method 601 Sam pling of the cooling tower for VCM/EDC/NMHC Tw ice per day EPA Method 601 #N/A #N/A #N/A Cooling water is obtained from the exhanger outlets and anayly zed for VCM concentration. Quarterly EPA Method 107 Cooling water is obtained from the exhanger outlets and anayly zed for VCM concentration. Quarterly EPA Method 107 High readings identified by the VCM Area Monitoring System requires follow up investigation by Operator with hand held meter. Wa ter is not sampled / VCM Area Monitoring System 0 Sam ples caught and analy zed 4 tim es daily Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" Sam ples caught and analy zed We ekly Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" Sam ples caught and analy zed We ekly Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B" Process Side flow is not continuous If there were a failure of the exchanger, cooling water would back intothe process side and would be detectedi n the process. N/A N/A Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly EPA-107 We ekly testing of the chilled water to detect the presence of VCM. In addition, a GC/MS anlay zer is positioned at the vent of the chill water storage tank and would detect fugitive VCM. We ekly / Continuously EPA-107 Process Side flow is not conintuous. If there were a failure of the exchanger, cooling water would back intothe process side and would be detectedi n the process. N/A N/A Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly EPA-107 We ekly testing of the chilled water to detect the presence of VCM. In addition, a GC/MS anlay zer is positioned at the vent of the chill water storage tank and would detect fugitive VCM. We ekly / Continuously EPA-107 The chilled water is sampled and tested for VCM; Chill W ater storage tank has a GC/MS sample point running continuously which would detect VCM in the tank vapor space. We ekly EPA-107 Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly EPA-107 Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlay zers in the area would detect fugitive VCM. Monthly EPA-107 N/A N/A N/A None N/A 0 0 0 0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A sample only when needed titration DCS Continuous N/A DCS Continuous N/A DCS Continuous N/A DCS Continuous N/A Refrigeration machine shutdown N/A N/ARefrigeration machine shutdown N/A N/A

Refrigeration machine shutdown N/A N/A The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A The chilled water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 (W eekly) N/A N/A N/A GC monitoring of cooling tower airspace every 15 minutes Real-time Gas Chromotography GC monitoring of cooling tower airspace every 15 minutes Real-time Gas Chromotography 0 0 0 HE's are monitored only when unusual conditions are noted. N/A 0 0 0 0 0 0 0 Gas Chromatograph sample point every 15 minutes Real Time Gas Chromatography Gas Chromatograph sample point every 15 minutes Real Time Gas Chromatography Gas Chromatograph sample point every 15 minutes Real Time Gas Chromatography Gas Chromatograph sample point every 15 minutes Real Time Gas Chromatography #N/A #N/A #N/A #N/A #N/A #N/A Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sy tematically

pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 Pm 's by contractor. Check for leaks and amount of Freon 134a lost. Refill and record amount Quarterly 0 Routine sampling of System Once per week Gas Chromotograph LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 LDAR and NESHAP Quarterly Monitoring daily leak patrol 0 LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 0 Quarterly 415.1 #N/A #N/A #N/A Vessel testing and leakage into the process when depressurized 5 year pressure test and inspection. N/A Vessel testing and Cycle W ater leakage into process 5 year pressure test and inspection. N/A Vessel testing and Cycle W ater leakage into process 5 year pressure test and inspection. N/A None 0 0 None 0 0 None 0 0 None 0 0 None 0 0 None 0 0 None 0 0 None 0 0**Location**

N/A N/A N/A N/A Inlet and outlet of cooling tower Inlet and outlet of cooling tower Inlet and outlet of cooling tower Inlet and outlet of cooling tower Inlet and outlet of cooling tower Inlet and outlet of cooling tower Inlet and outlet of cooling tower Wa ter utility

station 0 #N/A #N/A #N/A #N/A Cooling Tower Chill water tanks Cooling Tower #N/A Exchanger outlet Exchanger outlet

0 Cooling Tower Outlet Cooling Tower Outlet Cooling Tower Outlet No Cooling Tower Basin Chill water pum p discharge N/A Cooling Tower Basin Chill water pum p discharge Chill water pum p discharge Cooling Tower Basin Cooling Tower pump discharge N/A N/A 0 N/A N/A N/A N/A

pum p discharge N/A N/A N/A N/A N/AN/A

N/A Pum p discharge. Pum p discharge. Pum p discharge. Pum p discharge Pum p discharge Pum p discharge. N/A Pum p discharge. N/A Pum p discharge. N/A Pum p discharge. N/A Pum p discharge. N/A Pum p discharge. N/A Pum p discharge. N/A Stationary

sampling point above hot water basin Stationary

sampling point above hot water basin 0 Chilled water storage tank owned and operated by PolyOne. 0 0 air space above hot water basin air space above hot water basin air space above hot water basin air space above hot water basin #N/A #N/A From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From Cooling tower as water falls into basin. From Cooling tower as water falls into basin. From Cooling tower as water falls into basin. From Cooling tower as water falls into basin. From Cooling tower as water falls into basin. From Cooling tower as water falls into basin. From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumps From sample bleed on outlet of chilled water pumpsFrom Cooling tower as water falls into basin.

From sample bleed on outlet of chilled water pumps From Cooling tower as water falls into basin. From sample bleed on outlet of chilled water pumps From Cooling tower as water falls into basin. From Cooling tower as water falls into basin. From Cooling tower as water falls into basin.

0 Refrigeration W ater Collection Tank Cooling Tower entrance and exit

0 Connectors CTW inlet and outlet #N/A N/A N/A N/A 0

0 0 0 0 0 0 0**Heat Exchange Sy stems - Surv** **ey Data A** **naly sis and Summary** 

**OxyVinyls - Pasadena** For El Paso Method... **F Vinyl Chloride**  **Other VOC**

**Total VOC Total VOC**  **C C**  **C in air, ppmv as methane (gal/min)**  **(lb/y r)**  **(lb/y r)**  **(lb/y r)**  **(lb/hr) (ppmw)**  **(ppbw)** OxyVinyls Pasadena U-1103 9,000 188 1410 1600 0.190 0.042 42.2 **3.16** OxyVinyls Pasadena U-1104 11,600 361 1660 2020 0.240 0.041 41.3 **3.10** 20,600 549 3070 3620 0.430 0.042 41.7 **3.13**

**Formosa - Point Comfort (PVC)** For El Paso Method...

**F (gal/min) NMHC, C (ppb)**  **E (lb/hr) C in air, ppmv as methane** 

46,200 30 0.694 2.25 66,300 30 0.995 2.25 46,200 30 0.694 2.25 **158,700 30**  **2.382 2.25** 

**Formosa - Point Comfort (Specialty PVC)** For El Paso Method...

**F (gal/min) NMHC, C (ppb)**  **E (lb/hr) C in air, ppmv as methane** 

52,900 **50** 1.32 **3.75 Company**  **Facility Unit ID** **Heat Exchange Systems - Summary of Clarification Data Submitted to EPA**

**Company Facility**  **CT # Flow Rate (gpm)**  **Pollutant Measured Leak A**  **ction Level Units**  **Monitoring Frequency Monitoring Method**  **Note(s)**

1 10,000 Vinyl chloride N/A N/A We ekly Wa ter sampling - GC headspace

2 5,000 Vinyl chloride N/A N/A We ekly Wa ter sampling - GC headspace

Vinyl chloride 10000 ppbw Quarterly Method 415.1

Vinylidene chloride 10000 ppbw Quarterly Method 415.1

Formosa Baton Rouge 1 48,000 Vinyl chloride 10 ppbw Daily Method 601

1 6,000 [no data]

2 3,000 [no data]

Formosa Point Comfort

1 13,500 Vinyl chloride 250 ppbw Quarterly Method 107

2 18,000 Vinyl chloride 250 ppbw Quarterly Method 107

3 18,000 Vinyl chloride 250 ppbw Quarterly Method 107

1 40,000 [cw pressure > process pressure]

2 22,300 [cw pressure > process pressure]

3 1,181 [no heat exchangers]

4 11,000 [utility system]

Vinyl chloride 5000 ppbw Monthly Method 107

Vinyl chloride 1000 ppbw Continuous GC/MS [continuous monitoring of air above cooling tower]

Speciated VOC 5000 ppbw Monthly Method 624

Vinyl chloride 5000 ppbw Monthly Method 107

Vinyl chloride 1000 ppbw Continuous GC/MS [air stripping]

Speciated VOC 5000 ppbw Monthly Method 624

Vinyl chloride 50 ppbw Monthly Method 107

Vinyl chloride 1000 ppbw Continuous GC [continuous monitoring of air above cooling tower]

Speciated VOC 50 ppbw Monthly Method 624

Vinyl chloride 50 ppbw Monthly Method 107

Vinyl chloride 1000 ppbw Continuous GC [continuous monitoring of air above cooling tower]

Speciated VOC 50 ppbw Monthly Method 624

VOC 50 ppbw Monthly El Paso OxyVinyls Pedricktown 1 13,333 Vinyl chloride 1000 ppbv Continuous Similar to M106 and M21 [continuous monitoring of air above cooling tower]

PolyOne Henry

1 1,900 ammonia and iron N/A N/A Daily N/A

2 1,850 ammonia and iron N/A N/A Daily N/A

Shintech Addis

Shintech Freeport

Shintech Plaquemine

We stlake Calvert City 1 23,000 [no data]

We stlake Geismar 1 10,653 Vinyl chloride 50 ppbw Yearly Method 107 PolyOne Pedricktown OxyVinyls Pasadena 1 9,000

2 11,600 OxyVinyls Deer Park 1 8,400

2 1,200 Formosa Delaware City

Georgia Gulf Aberdeen

Georgia Gulf Plaquemine 16,500 CertainTeed Lake Charles

Dow Midland 1

### ATTACHMENT H: HEAT EXCHANGE SYSTEM MACT FLOOR ANALYSIS

02/08/2012

**MAC T Floor A** **nalysis - Heat Exchange Systems**

**Including Formosa - Point Comfort Survey Data Systems That Monitor for VOC Using Modified El Paso or Water Sampling Method** 

**Company Facility**  **CT # Flow Rate (gpm)**  **Pollutant Measured Leak A**  **ction Level Units** 

**Monitoring Frequency Monitoring Method** **Note(s)**

Formosa Point Comfort 1 46,200 NMHC 30 ppbw We ekly Method 601

Formosa Point Comfort 2 66,300 NMHC 30 ppbw We ekly Method 601

Formosa Point Comfort 3 46,200 NMHC 30 ppbw We ekly Method 601 OxyVinyls Pasadena 1 9,000 Speciated VOC 50 ppbw Monthly Method 624 1 OxyVinyls Pasadena 2 11,600 Speciated VOC 50 ppbw Monthly Method 624 2 OxyVinyls Pasadena 2 11,600 VOC 50 ppbw Monthly El Paso 3

Formosa Point Comfort (SPVC) 1 52900 NMHC 50 ppbw Twice-Daily Method 601 OxyVinyls Deer Park 1 8,400 Speciated VOC 5000 ppbw Monthly Method 624 4 OxyVinyls Deer Park 2 1,200 Speciated VOC 5000 ppbw Monthly Method 624 5 Cooling W ater Conc. Existing 50 ppbw [LAL floor determined from median LAL of top 5 systems that monitor for VOC using El Paso or water sampling method]

New 50 ppbw Stripping Gas Conc. Existing 3.9 ppmv New 3.9 ppmv

Delay of Repair Cooling W ater Conc. 500 ppbw

Stripping Gas Conc. 39 ppmw

**Systems That Monitor for Vinyl Chloride Using Method 107**

**Company Facility**  **CT # Flow Rate (gpm)**  **Pollutant Measured Leak A**  **ction Level Units** 

**Monitoring Frequency Monitoring Method** **Note(s)** OxyVinyls Pasadena 1 9,000 Vinyl chloride 50 ppbw Monthly Method 107 1 OxyVinyls Pasadena 2 11,600 Vinyl chloride 50 ppbw Monthly Method 107 2 We stlake Geismar 1 10,653 Vinyl chloride 50 ppbw Yearly Method 107 3 Georgia Gulf Aberdeen 1 13,500 Vinyl chloride 250 ppbw Quarterly Method 107 4 Georgia Gulf Aberdeen 2 18,000 Vinyl chloride 250 ppbw Quarterly Method 107 5 Georgia Gulf Aberdeen 3 18,000 Vinyl chloride 250 ppbw Quarterly Method 107 OxyVinyls Deer Park 1 8,400 Vinyl chloride 5000 ppbw Monthly Method 107 OxyVinyls Deer Park 2 1,200 Vinyl chloride 5000 ppbw Monthly Method 107 Cooling W ater Conc. Existing 50 ppbw [LAL floor determined from median LAL of top 5 systems that monitor for vinyl chloride using Method 107] New 50 ppbw

Delay of Repair Cooling W ater Conc. 500 ppbw

### ATTACHMENT D/H: HEAT EXCHANGE SYSTEM COST ANALYSIS

02/08/2012

**Heat Exchange Systems - Summary of Clarification Data Submitted to EPA Calculated Emissions, Reductions, and Costs** 

OVP Conc (ppbw) 5.93

% of LAL 12%

Avg LAL (ppbw) 1363 Based on M107 only

Avg Conc (ppbw) 162

LAL (ppbw) 50 Cost per Repair ($/tower/yr) 4300

DOR LAL (ppbw) 800

DOR Period (days) 120

Repairs per yr 1

**REPORTED EMISSIONS**  **FROM VC Conc**  **LAL BASELINE**  **EMISSIONS EMISSION** 

**REDUCTIONS REPAIR COSTS** 

**Company Facility**  **CT # Flow Rate (gpm)**  **Pollutant Measured Leak Action Level**  **Units Monitoring Frequency**  **Monitoring Method Note(s)**  **VC (tpy) (ppbw)**  **(ppbw) VC (tpy)**  **VC (tpy) ($/yr)** 

1 10,000 Vinyl chloride Weekly Water sampling - GC headspace 162 1363 3.54E+00 2.45E+00 4,300

2 5,000 Vinyl chloride Weekly Water sampling - GC headspace 162 1363 1.77E+00 1.22E+00 4,300

Vinyl chloride 10000 ppbw Quarterly Method 415.1 1186 10000 4.29E+01 4.11E+01 4,300

Formosa Baton Rouge 1 48,000 Vinyl chloride 10 ppbw Daily Method 601 1 10 1.25E-01 0.00E+00 4,300

1 6,000 [no data] 162 1363 2.13E+00 1.47E+00 4,300

2 3,000 [no data] 162 1363 1.06E+00 7.34E-01 4,300

Formosa Point Comfort 158700 162 1363 5.62E+01 3.88E+01 4,300

1 13,500 Vinyl chloride 250 ppbw Quarterly Method 107 30 250 8.78E-01 0.00E+00 4,300

2 18,000 Vinyl chloride 250 ppbw Quarterly Method 107 30 250 1.17E+00 0.00E+00 4,300

3 18,000 Vinyl chloride 250 ppbw Quarterly Method 107 30 250 1.17E+00 0.00E+00 4,300

1 40,000 [cw pressure > process pressure] 4,300

2 22,300 [cw pressure > process pressure] 4,300

3 1,181 [no heat exchangers] 4,300

4 11,000 [utility system] 4,300

Vinyl chloride 5000 ppbw Monthly Method 107 593 5000 1.09E+01 1.00E+01 4,300

Vinyl chloride 5000 ppbw Monthly Method 107 593 5000 1.56E+00 1.43E+00 4,300

Vinyl chloride 50 ppbw Monthly Method 107 9.40E-02 6 50 9.40E-02 0.00E+00 4,300

Vinyl chloride 50 ppbw Monthly Method 107 1.81E-01 6 50 1.81E-01 0.00E+00 4,300

OxyVinyls Pedricktown 1 13,333 Vinyl chloride 1000 ppbv Continuous Similar to M106 and M21 [continuous monitoring of air above cooling tower] 119 1000 3.47E+00 2.01E+00 4,300

PolyOne Henry 39000 162 1363 1.38E+01 9.54E+00 4,300

1 1,900 162 1363 6.73E-01 4.65E-01 4,300

2 1,850 162 1363 6.55E-01 4.53E-01 4,300

Shintech Addis 449 162 1363 1.59E-01 1.10E-01 4,300

Shintech Freeport 360 162 1363 1.28E-01 8.81E-02 4,300

Shintech Plaquemine 433 162 1363 1.53E-01 1.06E-01 4,300

Westlake Calvert City 1 23,000 [no data] 162 1363 8.15E+00 5.63E+00 4,300

Westlake Geismar 1 10,653 Vinyl chloride 50 ppbw Yearly Method 107 6 50 1.39E-01 0.00E+00 4,300

**151.1 115.6**  **116,100** CertainTeed Lake Charles

Dow Midland 1 16,500

Formosa Delaware City

Georgia Gulf Aberdeen

Georgia Gulf Plaquemine

OxyVinyls Deer Park 1 8,400

2 1,200

9,000

2 11,600

PolyOne Pedricktown OxyVinyls Pasadena 1

### ATTACHMENT D/H: HEAT EXCHANGE SYSTEM COST ANALYSIS

02/08/2012

**Calculated Emissions, Reductions, and Costs**

**Total Capital Cost Ttal Annual Cost** 

**Control Equip**

**T&M $**  **$/yr VCM**  **HCl D/F**  **TOH VCM**  **HCl D/F**  **TOH Control**  **Testing and Control**  **Control Testing and**  **Testing and Total**  **Total Baseline -**  **Baseline - Baseline -**  **Baseline - Reduction -**  **Reduction - Reduction -**  **Reduction -**

Certain Teed - Lake Charles Area Source Bulk 8,600 5.31E+00 5.31E+00 3.67E+00 3.67E+00

PolyOne - Henry PVC - Only Suspension, Dispersion, Suspension Blending 4,300 1.38E+01 1.38E+01 9.54E+00 9.54E+00

PolyOne - Pedricktown PVC - Only Dispersion 8,600 1.33E+00 1.33E+00 9.18E-01 9.18E-01

Formosa - Delaware City PVC - Only Dispersion, Copolymer (VACO-D) 8,600 3.19E+00 3.19E+00 2.20E+00 2.20E+00

Dow - Midland PVC - Combined Copolymer (VDCO-S) 4,300 4.29E+01 4.29E+01 4.11E+01 4.11E+01

Formosa - Baton Rouge PVC - Combined Suspension 4,300 1.25E-01 1.25E-01 0.00E+00 0.00E+00

Formosa - Point Comfort PVC - Combined Suspension 4,300 5.62E+01 5.62E+01 3.88E+01 3.88E+01

Georgia Gulf - Aberdeen PVC - Only Suspension 12,900 3.22E+00 3.22E+00 0.00E+00 0.00E+00

Georgia Gulf - Plaquemine PVC - Combined Suspension 17,200 0.00E+00 0.00E+00 0.00E+00 0.00E+00

OxyVinyls - Deer Park PVC - Combined Suspension 8,600 1.25E+01 1.25E+01 1.14E+01 1.14E+01

OxyVinyls - Pasadena PVC - Only Suspension 8,600 2.75E-01 2.75E-01 0.00E+00 0.00E+00

OxyVinyls - Pedricktown PVC - Only Suspension 4,300 3.47E+00 3.47E+00 2.01E+00 2.01E+00

Shintech - Addis PVC - Only Suspension 4,300 1.59E-01 1.59E-01 1.10E-01 1.10E-01

Shintech - Freeport PVC - Only Suspension 4,300 1.28E-01 1.28E-01 8.81E-02 8.81E-02

Shintech - Plaquemine PVC - Combined Suspension 4,300 1.53E-01 1.53E-01 1.06E-01 1.06E-01

Westlake - Calvert City PVC - Combined Suspension 4,300 8.15E+00 8.15E+00 5.63E+00 5.63E+00

Westlake - Geismar PVC - Combined Suspension 4,300 1.39E-01 1.39E-01 0.00E+00 0.00E+00 **MACT Floor Costs Baseline Emissions and MACT Floor Emissions Reductions**  **MACT Floor Capital Cost ($) MACT Floor - Annual Costs ($/yr)**  **Baseline Emissions (TPY) MACT Floor Emissions Reductions (TPY)** 

**Control Equip T&M** **COOLING TOWERS - Count for PVC HeatExch**

**Company Nam** 

**e Facility**  **Name Proces** 

**s Num of** 

**CTs CT ID**  **Total Flow,**

**gpm # of HeatEx** 

**In Sy stem**  **lb water/y r**  **How Leaks Id'd Freq**  **Metho d**  **Location How Leaks**  **Id'd Freq**  **Metho**

**d Location** 

CertainTeed Lake Charles B 1 U-13 10200 11 4.29E+10 Not required - not a major source of HAP emissions N/A N/A N/A CertainTeed Lake Charles B 1 U-19 5000 4 2.10E+10 Not required - not a major source of HAP emissions N/A N/A N/A Formosa Baton Rouge S 1 U-10 2175 84 9.14E+09 The cooling tower water inlet and outlet was sampled quarterly in 2008 and tested using Method 624 to determine concentration of specific HAPs in the cooling water. Quarterly Method 624 Inlet and outlet of cooling tower Formosa Delaware City D 1 U-14 4000 21 1.68E+10 Wa ter is sampled weekly. If VOC detected than individual equipment is sampled. We ekly 106 Wa ter utility station Formosa Delaware City D 1 U-73 4000 21 1.68E+10 Formosa Point Comfort - PVC S 1 U-24 158700 21 6.67E+11 Sampling of the cooling tower for VCM/EDC/NMHC Twice per day EPA Method 601 Cooling Tower Sampling of the chill water tanks for VCM Twice per week EPA Method 601 Chill water tanks Formosa Point Comfort - Specialty Polyvinyl Chloride (SPVC) Unit S, O 1 U-17 Georgia Gulf Aberdeen S 1 U-66 2000 21 8.41E+09 Cooling water is obtained from the exhanger outlets and anaylyzed for VCM concentration. Quarterly EPA Method 107 Exchanger outlet Georgia Gulf Aberdeen S 1 U-67 2000 21 8.41E+09 Cooling water is obtained from the exhanger outlets and anaylyzed for VCM concentration. Quarterly EPA Method 107 Exchanger outlet Georgia Gulf Aberdeen S 1 U-68 2000 21 8.41E+09 Cooling water is obtained from the exhanger outlets and anaylyzed for VCM concentration. Quarterly EPA Method 107 Exchanger outlet Georgia Gulf Aberdeen S 1 U-69 2000 21 8.41E+09 Cooling water is obtained from the exhanger outlets and anaylyzed for VCM concentration. Quarterly EPA Method 107 Exchanger outlet Georgia Gulf Plaquemine S 1 unknown - assume 2 CTs 40000 47 1.68E+11 Samples caught and analyzed We ekly Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B"

Cooling Tower Outlet Georgia Gulf Plaquemine S 1 unknown - assume 2 CTs 22300 10 9.37E+10 Samples caught and analyzed We ekly Lab Procedure # PPVC 27, "Residual Vinyl Chloride using Perkin Elmer HS40B"

Cooling Tower Outlet OxyVinyls Deer Park S 1 unknown - assume 3 CTs 2200 3 9.25E+09 Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. OxyVinyls Deer Park S 1 unknown - assume 3 CTs 2200 3 9.25E+09 Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. OxyVinyls Deer Park S 1 unknown - assume 3 CTs 19600 13 8.24E+10 Monthly testing of the cooling tower water to detect the presence of VCM. In addition, GC/MS anlayzers in the area would detect fugitive VCM. OxyVinyls Pasadena S 1 U-1103 9000 3 3.78E+10 The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 Pump discharge OxyVinyls Pasadena S 1 U-1104 11600 2 4.88E+10 The cooling water is sampled. The sample is analyzed for VCM. We ekly & Monthly EPA107 Pump discharge OxyVinyls Pedricktown S 1 U-600 13333 4 5.60E+10 Gas Chromatograph sample point every 15 minutes Real Time Gas Chromatography air space above hot water basin PolyOne Henry S, D 1 U-1 39000 281 1.64E+11 Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sytematically pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks 1/ shift or 2 /day Method 107 From sample bleed on outlet of chilled water pumps Wa ter is sampled for residual VCM per Method 107. If VCM is detected we sytematically pressure check and sample around each process unti for RVCM. W e systematically stagger equipment use to look for VCM peaks to find equipment with leaks

1/ shift or 2 /day Method 107 From Cooling tower as water falls into basin. PolyOne Pedricktwon D 1 U-18 100 1 4.20E+08 Routine sampling of System Once per week Gas Chromotograph Refrigeration W ater Collection Tank Shintech Addis S 1 U-62 449 7 1.89E+09 LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 Cooling Tower entrance and exit Shintech Freeport S 1 U-45 360 20 1.51E+09 LDAR and NESHAP Quarterly Monitoring daily leak patrol

0 0 Shintech Freeport 1.51E+09 LDAR and NESHAP Quarterly Monitoring daily leak patrol Shintech Plaquemine S 1 U-58 433 6 1.82E+09 LDAR and NESHAP Quarterly Monitoring Quarterly Method 107 Connectors Dow Midland S 1 CTW -1 4800 6 2.02E+10 Quarterly 415.1 CTW inlet and outlet We stlake Calvert City S 1 U-89 22800 41 9.58E+10 None We stlake Geismar S 1 U-40 14650 20 6.16E+10 None