TS-E077KJ For R&D use only ISSUED:2013/May/13

Page 1 of 4 

### CBI



# MATERIAL SAFETY DATA SHEET 

# CBI

SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION (CBI) TRADE NAME: (CBI) CHEMICAL FAMILY: Fluoroalkylacrylate co polymer (solution) – For R&D use only (CBI) INDUSTREIES, LTD: (CBI) PHONE: (CBI) FAX: (CBI) 

### SECTION 2: HAZARDS IDENTIFICATION PHYSICAL DESCRIPTION: (CBI) POTENTIAL HEALTH EFFECTS: May cause eye, skin and respira tory irritation. May be harmful if ingested. Above 200°C, hydrogen fluoride and other t oxic fluorinated compounds may be produced; inhalation of these compounds under these conditions m ay result in serious lung irritation. HMIS RATINGS: Health : 1 Flammability : 1 Reactivity : 0 

### SECTION 3: INFORMATION ON INGREDIENTS
COMPONENT CAS. NO. Wt% OSHA (PEL) ACGIH (TLV) NON-HAZARDOUS INGREDIENTS CBI CBI CBI None None CBI CBI CBI None None



### SECTION 4. FIRST AID PROCEDURES INGESTION: Consult a physician immediately. EYE CONTACT: Flush with large amounts of water fo r 10-15 minutes. Consult a physician if needed. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing and shoes. INHALATION: Leave the contaminated area and seek fresh air. If breathing is difficult, contact a physician. NOTE TO PHYSICIANS: In the event of inhalation of gas es generated by high temperature decomposition of the product, treat for hydrogen fluoride inhalati on. Excessive exposure to thermal degradation products could result in delayed pulmonary edema in some cases, and on very high exposure, damage to the liver and kidneys.



# R&D Use Onl y Attachment 5 Pa g e 1/4TS-E077KJ For R&D use only ISSUED:2013/May/13

Page 2 of 4 

### SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT (METHOD USED): Not tested FLAMMABLE LIMITS: LEL: Not tested UEL: Not tested HAZARDOUS COMBUSTION PRODUCTS: Toxic by-products incl uding hydrofluoric acid, perfluoroisobutylene, and carbonyl fluoride may be formed at very high temperatures. EXTINGUISHING MEDIA: Alcohol foam, CO 2 , dry chemical or water spray PROTECTIVE EQUIPMENT: Use NIOSH/MSHA approve d SCBA and bunker gear. Evolution of acidic gases may require complete wash down of protective clothing prior to removal. 

### SECTION 6. ACCIDENTAL RELEASE MEASURES Ensure cleanup is done only by trained personnel wearing approp riate personal protective equip ment. Ventilate area and cover with absorbent material. Collect the spilled material in a container and seal. Spilled material is a slipping hazard. 

### SECTION 7. HANDLING & STORAGE

HANDLING: Follow safe industrial hygiene practices and wear proper protective equipment. Use only in well ventilated areas. Safety showers & eyewashes should be available in the work area. Wash hands thoroughly after hand ling. Wash clothing after use. Avoid contact with the skin or eyes. Do not breathe vapor or spray. Do not store or consume food, drink or tobacco in area s where they may become contaminated with this material.
STORAGE: Store material at –5 ° C (23 ° F) to 40 ° C (104 ° F). Keep away from heat, sparks and open flame. Keep containers tightly closed when not in use. 

### SECTION 8. EXPOSURE CONTROLS & PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: Use respirator suitable for protect ion when spraying this material. If material is heated above 200 ° C, use a positive pressure air supplied respirator or SCBA. EYE PROTECTION: Safety glasses with sideshields or goggles PROTECTIVE CLOTHING: Chemical resistant gloves VENTILATION: If material is heated above 200 ° C, use local exhaust ventilation. OTHER PROTECTIVE EQUIPMENT: Eyewash station and safety shower. Attachment 5 Pa g e 2/4TS-E077KJ For R&D use only ISSUED:2013/May/13

Page 3 of 4 

### SECTION 9. PHYSICAL & CHEMICAL PROPERTIES

PHYSICAL STATE: CBI
VAPOR PRESSURE: CBI DENSITY: CBI SOLUBILITY IN SOLVENT: CBI SOLUBILITY IN WATER: CBI MELTING POINT ( ° C): CBI BOILING POINT ( ° C): CBI SPECTRA: CBI DISSOCIATION CONSTANT: CBI PARTICLE SIZE: CBI OCTANOL/WATER PARTITION COEFFICIENT: CBI HENRY’S LAW CONSTANT: CBI VOLITALIZATION FROM WATER: CBI VOLITALIZATION FROM SOIL: CBI pH: CBI FLAMMABILITY: CBI EXPLODABILITY: CBI ADSORPTION/COEFFICIENT: CBI 

### SECTION 10. STABILITY & REACTIVITY

STABILITY: Stable CONDITIONS TO AVOID: Excessive heat, sparks, open flame HAZARDOUS POLYMERIZATION: Should not occur INCOMPATIBILITIES: May react with metals, such as sodium, magn esium, aluminum at elevated temperatures (above 425 ° C); may react upon prolonged exposure to fluorine or in oxygen-fluorine mixtures at high temperatures and pressures. Contact with incompatible materials may result in fire or explosion. Hazardous decomposition or by-produc ts and toxic by-products including hydrofluoric acid, perfluoroisobutylene, and carbonyl fluoride may be formed at very high temperatures. 

### SECTION 11. TOXICOLOGICAL INFORMATION

ACUTE EFFECTS OF EXPOSURE Ingestion: May be harmful if swallowed Eye Contact: May cause mild irritation Skin Contact: May cause skin irritation and sensitization Inhalation: May cause respiratory irritation CHRONIC EFFECTS OF EXPOSURE: No data available CARCINOGENICITY: None of the components in this material is listed by NTP, OSHA or IARC. TOXICOLOGICAL TEST: No data available OTHER POTENTIAL HAZARDS (OF THE PURE MATERIALS): No data available

Excessive exposure to thermal degradation products could result in delayed pulmona ry edema in some cases, and on very high exposure, damage to the liver and kidneys. These s ubstances may include: perfluoroisobutylene (TLV = 10 ppb), carbonyl fluoride (TLV = 2 ppm TWA, 5 ppm STEL), hydrogen fluoride (TLV = 2 ppm Ceiling, 0.5 ppm TWA). Attachment 5 Pa g e 3/4TS-E077KJ For R&D use only ISSUED:2013/May/13

Page 4 of 4 

### SECTION 12. ECOLOGICAL INFORMATION

ECOTOXICITY: CBI BIODEGRADABILITY: CBI 

### SECTION 13. DISPOSAL CONSIDERATIONS Comply with Federal, State, a nd Local regulations concerning health and environ ment when disposing of materials. Regulations may also apply to empty containers, liners, or rinsate. DO NOT INCINERATE unless incinerator is capable of scrubbing hydrogen fluoride and other ac idic combustion products. 

### SECTION 14. TRANSPORT INFORMATION

UN CLASSIFICATION: CBI DOT HAZARD DESCRIPTION: CBI CANADIAN TRANSPORTATION OF DANGEROUS GOODS (TDG): CBI 

### SECTION 15. REGULATORY INFORMATION TSCA: The TSCA status of this product has not yet been determined; as such, use of this product should be restricted to research and development work only. 

### SECTION 16. OTHER INFORMATION For additional information, refer to the American Conference of Governmental Industr ial Hygienists (ACGIH) documentation of TLV’s (Threshold Limit Values) for individual components , Fluoropolymers Safe Handling Guide published by The Society of the Plastics Industry, and the DOT Emergency Response Guidebook.

CBI believes the information in this MSDS to be correct as of the date issued, but CBI assu mes no liability for the accuracy or completeness of the data relied on in preparing this MSDS. CB I makes no warranties in this MSDS, either express or implied, and excludes all warranties, in cluding without limitation any implied warranty of merchantability, fitness for a particular purpose or course of performance, or usage of trade.

CBI may provide MSDS information in elect ronic form as a customer service. Due to the remote possibility that electronic transfer may result in errors, omissions or al terations in this information, CBI makes no representation or warranty as to its completeness or accuracy when so transferred. Attachment 5 Pa g e 4/4