## EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -002 UNIT 2

PARTICULATE MATTER, SULFUR DIOXIDE, and VISIBLE EMISSIONS October 26, 2006

Prepared For: Tampa Electric Company Big Bend Station

P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Environmental Services Air Services Group

Environmental Services Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Jorge A. Varino Environmental Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE NO.
1.0 SUMMARY OF RESULTS 1
2.0 DISCUSSION OF RESULTS 2
3.0 SOURCE DESCRIPTION / TEST PROCEDURES 3
4.0 TABULATED RESULTS
SOOT BLOWING PARTICULATE TEST SUMMARY 6
NON SOOT BLOWING PARTICULATE TEST SUMMARY 7
SULFUR DIOXIDE INFORMATION SUMMARY 8
SOOT BLOWING OPACITY DATA SUMMARY 9
NON SOOT BLOWING OPACITY DATA SUMMARY 10
HEAT INPUT CALCULATIONS 11
4.0 FIGURES
FIGURE 1 SAMPLING LOCATION DIAGRAM 13
APPENDICES
A. PARTICULATE MATTER CALCULATIONS
B. PARTICULATE MATTER LABORATORY ANALYTICAL DATA
C. BOILER/PRECIPITATOR OPERATIONAL DATA
D. PLANT CEMS DAHS PRINTOUTS
E. FUEL ANALYSIS
F. FIELD DATA SHEETS
G. SAMPLING EQUIPMENT CALIBRATIONS
H. CHAIN OF CUSTODY
I. TEST PARTICIPANTS

## 1.0 INTRODUCTION

On October 26, 2006, Tampa Electric Co mpany’s, Environmental Services, Air Services Group, performed source emission tests at the Big B end Station, Boiler No. 2, emissions unit I.D.# 0570039-002. Testing was conducted according to procedures stipulated by t he Florida Department of Environmental Protection (FDEP) for fossil fuel steam generators. Testing wa s conducted in accordance
with the Title V Permit #05700 39-021-AV, Conditions A.12.

1

## 2.0 DISCUSSION OF RESULTS

The particulate matter emission rate under both soot blowing, and non-soot blowing conditions were derived from three United States Environmental Protection Agency (USEPA) Re ference Method 5B test runs. Under soot blowing conditions the average of the three test runs was 0.03 lb/mmBtu. Under nonsoot blowing conditions t he average of the three test runs was 0.02 lb/mmBtu.
The USEPA Consent Decree allowable emi ssion rate under either condition is
0.03 lb/mmBtu.

The Sulfur Dioxide (SO 2 

### ) emission rate was determined using data provided by the Continuous Emissions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was determined to be 0.2 lb/mmBtu, and 657 lb s/hr. The FDEP a llowable emission
rate is 6.5 lbs/mmBtu based on a two hour average, and 3277 lbs/hr based on scenario 3 as listed in condition A.9 of the permit.

Visible emissions were evaluated using a United Sciences, Incorporated, Model 500C transmissometer (S/N 5001689), duri ng both soot blowing and non-soot blowing testing. The 1-hour average opac ity under soot blowin g conditions was 7%. The 1-hour average opacity under non- soot blowing conditions was 9%. The FDEP allowable emission rate is 20 percent opacity.

During the test performed on October 26, 2006, Boiler No. 2 was operated at an average heat input rate of 3584 mmBtu/hr. The average quant ity of fuel burned was 152.0 tons per hour. Based on the pe rmitted maximum heat input rate of 3996 mmBtu/hr, the capacity factor for this test was determined to be 90%.

2

## 3.0 SOURCE DESCRIPT ION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The Boiler No. 2 particulate matter sampling location consists of a shared circ ular stack 29.83 feet in diameter with four sample ports located 90 degrees apart on the stack circumference. These ports are located downstr eam of the electrostatic precipitator and the FGD scrubber. The sampling ports were determined to be 8.74 diameters
downstream of the transition ductwork and 2.42 diameters upstream of the stack exit. Using these criteria, a total of 12 sampling points were chosen for particulate sampling as stipulated in t he USEPA Method 1 test procedure. During this test, Boiler No. 1 was not operating, and was isolated from the FGD module. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site.

Boiler No. 2 is serviced by an electrostati c precipitator for the control of flyash emissions, and a flue gas desulfurization (FGD) system for control of sulfur
dioxide emissions. Generat or and precipitator operations data is included in Appendix C of this report.

Particulate sampling was perform ed according to USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources".
Individual test run calcul ations are included as A ppendix A of this report. Particulate matter laboratory analysis may be found in Appendix B of this report.

Diluent gas sampling and analysis was performed according to USEPA Method 3B "Gas Analysis for Determination of Emission Rate Correction Factor, or Excess Air”. Gas analysis was perform ed on-site using an Orsat analyzer.

Sulfur Dioxide (SO 2 

### ) and Carbon Dioxide (CO 2 

### ) data were provided by the Continuous Emissions Monitoring System (CEMS) , Data Acquisition and

3

### Handling System (DAHS). Averages were derived from the time frame of 8:15 through 17:15 on October 26, 2006. This dat a is included as Appendix D of this report.

Visible emissions were a ssessed using the installed Continuous Opacity Monitor (COM), and the CEMS DAHS.

4

## 4.0 TABULATED RESULTS

5

## BIG BEND STATION PARTICULATE MATTER DATA SUMMARY

Run 2s Run 3s Run 4s V m(std) 

### , scf 36.982 36.312 36.167

B ws 

### , ratio 0.12101 0.15952 0.16125

O 2 

### , % volume 9 11 10.5

M

d 

### , lb/lb - mole 29.96 29.96 30.02

M

s 

### , lb/lb - mole 28.51 28.05 28.08

Q s 

### , acf/min 1259894.6 1241871.7 1237879.0

Q s(std) 

### , dscf/min 997948.2 939910.9 936644.1

I, % 100.1 104.3 104.3

C, lbs/dscf 1.01E-06 1.86E-06 1.44E-06

E r 

### , lb/mmBtu 0.017 0.038 0.028

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) 

### 102.90

1.4386E-06

0.0281 29.980

28.216

1246548.42

958167.74 

### Test Summary 36.487

0.147259

10.17 

### Boiler #2 WET-BOTTOM UTILITY BOILE R October 26, 2006 SOOT BLOWING



### 6

## BIG BEND STATION PARTICULATE MATTER DATA SUMMARY

Run 1 Run 2 Run 3 V m(std) 

### , scf 38.094 36.586 36.747

B ws 

### , ratio 0.10618 0.15558 0.15501

O 2 

### , % volume 9 10.5 10.5

M

d 

### , lb/lb - mole 29.96 29.94 29.94

M

s 

### , lb/lb - mole 28.69 28.08 28.09

Q s 

### , acf/min 1298171.6 1255417.7 1253792.6

Q s(std) 

### , dscf/min 1046781.9 955294.1 956950.7

I, % 98.3 103.4 103.7

C, lbs/dscf 1.05E-06 8.53E-07 9.09E-07

E r 

### , lb/mmBtu 0.018 0.017 0.018

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) 

### 9.3730E-07

0.0176 

### NON - SOOT BLOWING

28.287

1269127.30

986342.25

101.80 37.143

0.138925

10.00

29.947 

### Boiler #2 WET-BOTTOM UTILITY BOILE R October 26, 2006

Test Summary



### 7

## BIG BEND STATION SULFUR DIOXIDE DATA FROM CEMs

Test Period Information Start Time 8:15:00 Eastern Standard Time (EST) Stop Time 17:15:00 Eastern Standard Time (EST) Total Time 9:00:00 Correspondin g to the time frame for the PM test.

Sulfur Dioxide Data:

SO 2 

### CO 2 

### SO 2 

### SO 2 

### ppmvw %, wet lb/mmBtu lbs/hr

55.87 10.02 0.2 657

Calculation Details SO 2 

### , lb/mmBtu = SO 2 

### , ppmvw x C f 

### x F c 

### x (100 / CO2 %, wet)

where: C f



### = 1.6635E-07 (lb/scf)/ppm SO 2 

### F c



### = 1800 scf/mmBtu
SO 2 

### , lbs/hr = SO 2 

### , lb/mmBtu x Heat Input, mmBtu/hr
where: Heat Input = 3936 mmBtu/hr, fr om Heat Input Calculation 

### Unit #2 WET-BOTTOM UTILITY BOILER October 26, 2006

CEM DATA RM - 19



### 8Facility: Bi g Bend Station Unit: Unit 2 Operatin g Conditions: Sootblowin g

Record# DATE TIME OPACITY2 Record# DATE TIME OPACITY2 1 10/26/06 9:44 7.9 31 10/26/06 10:14 6.8 2 10/26/06 9:45 7.5 32 10/26/06 10:15 6.8 3 10/26/06 9:46 7.3 33 10/26/06 10:16 7.4 4 10/26/06 9:47 7.4 34 10/26/06 10:17 6.9 5 10/26/06 9:48 7.3 35 10/26/06 10:18 6.5 6 10/26/06 9:49 7.5 36 10/26/06 10:19 6.6 7 10/26/06 9:50 7.0 37 10/26/06 10:20 6.7 8 10/26/06 9:51 6.9 38 10/26/06 10:21 6.8 9 10/26/06 9:52 6.9 39 10/26/06 10:22 6.8 10 10/26/06 9:53 6.6 40 10/26/06 10:23 7.3 11 10/26/06 9:54 6.8 41 10/26/06 10:24 7.5 12 10/26/06 9:55 7.7 42 10/26/06 10:25 7.0 13 10/26/06 9:56 7.6 43 10/26/06 10:26 6.8 14 10/26/06 9:57 7.1 44 10/26/06 10:27 6.8 15 10/26/06 9:58 7.2 45 10/26/06 10:28 6.9 16 10/26/06 9:59 7.1 46 10/26/06 10:29 7.0 17 10/26/06 10:00 6.6 47 10/26/06 10:30 7.1 18 10/26/06 10:01 7.2 48 10/26/06 10:31 7.5 19 10/26/06 10:02 7.5 49 10/26/06 10:32 7.2 20 10/26/06 10:03 7.1 50 10/26/06 10:33 7.2 21 10/26/06 10:04 6.9 51 10/26/06 10:34 7.1 22 10/26/06 10:05 6.7 52 10/26/06 10:35 7.1 23 10/26/06 10:06 6.6 53 10/26/06 10:36 7.2 24 10/26/06 10:07 7.2 54 10/26/06 10:37 7.3 25 10/26/06 10:08 7.3 55 10/26/06 10:38 7.1 26 10/26/06 10:09 7.3 56 10/26/06 10:39 7.1 27 10/26/06 10:10 7.1 57 10/26/06 10:40 7.8 28 10/26/06 10:11 7.1 58 10/26/06 10:41 7.4 29 10/26/06 10:12 6.5 59 10/26/06 10:42 8.1 30 10/26/06 10:13 6.7 60 10/26/06 10:43 8.5

Test Avera g e: 7.14 % Minimum One Minute Avera g e: 6.50 % Maximum One Minute Avera g e: 8.50 %

Maximum Six Minute Avera g e: 7.78 % V isible Emissions Determinat ion from Opacity Monitor



### 9Facility: Bi g Bend Station Unit: Unit 2 Operatin g Conditions: Non-sootblowin g

Record# DATE TIME OPACITY2 Record# DATE TIME OPACITY2 1 10/26/06 8:15 8.5 31 10/26/06 8:45 8.9 2 10/26/06 8:16 8.3 32 10/26/06 8:46 8.8 3 10/26/06 8:17 8.4 33 10/26/06 8:47 8.5 4 10/26/06 8:18 8.4 34 10/26/06 8:48 8.8 5 10/26/06 8:19 8.7 35 10/26/06 8:49 8.7 6 10/26/06 8:20 8.9 36 10/26/06 8:50 8.6 7 10/26/06 8:21 8.8 37 10/26/06 8:51 8.3 8 10/26/06 8:22 9.0 38 10/26/06 8:52 8.2 9 10/26/06 8:23 8.3 39 10/26/06 8:53 8.3 10 10/26/06 8:24 8.3 40 10/26/06 8:54 8.4 11 10/26/06 8:25 8.4 41 10/26/06 8:55 8.2 12 10/26/06 8:26 8.6 42 10/26/06 8:56 8.3 13 10/26/06 8:27 8.6 43 10/26/06 8:57 8.4 14 10/26/06 8:28 8.5 44 10/26/06 8:58 9.1 15 10/26/06 8:29 8.4 45 10/26/06 8:59 9.0 16 10/26/06 8:30 8.5 46 10/26/06 9:00 8.9 17 10/26/06 8:31 8.6 47 10/26/06 9:01 9.2 18 10/26/06 8:32 8.6 48 10/26/06 9:02 9.0 19 10/26/06 8:33 8.9 49 10/26/06 9:03 8.9 20 10/26/06 8:34 9.1 50 10/26/06 9:04 8.6 21 10/26/06 8:35 8.9 51 10/26/06 9:05 8.7 22 10/26/06 8:36 9.0 52 10/26/06 9:06 9.2 23 10/26/06 8:37 9.4 53 10/26/06 9:07 9.3 24 10/26/06 8:38 8.9 54 10/26/06 9:08 8.9 25 10/26/06 8:39 9.0 55 10/26/06 9:09 8.8 26 10/26/06 8:40 8.8 56 10/26/06 9:10 8.7 27 10/26/06 8:41 8.5 57 10/26/06 9:11 9.0 28 10/26/06 8:42 8.5 58 10/26/06 9:12 9.0 29 10/26/06 8:43 8.6 59 10/26/06 9:13 9.2 30 10/26/06 8:44 8.6 60 10/26/06 9:14 8.9

Test Avera g e: 8.71 % Minimum One Minute Avera g e: 8.20 % Maximum One Minute Avera g e: 9.40 %

Maximum Six Minute Avera g e: 9.05 % V isible Emissions Determinat ion from Opacity Monitor



### 10

## BIG BEND GENERATING STATION HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (September): 9920 KMBtu/MWh 9.9200E+06 MMBtu/MWh

Me g aWatt Hour Inte g rator Information Initial Inte g rator Readin g : 937409 MWh

Final Inte g rator Readin g : 940661 MWh Total: 3252 MWh

T est Time Information Testin g Start Time: 8:15

Testin g End Time: 17:15

Total Test Time: 9.00 hours

Calculated Heat Input Avera g e Unit Load, MW = MWh / hours: 361.3 MW Heat Input, MMBtu/h = MMBtu/MWh x MW: 3584 mmBtu/hr

Fuel Consumptio n Calculation

Laboratory Sample ID: AA85469 Btu as received: 11788 Btu/lb Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 152.0 Tons/hour Unit #2

October 26, 2006 WET-BOTTOM UTILTIY BOILE R



### 11

## 5.0 FIGURES

12FIGURE 1 EXHAUST STACK 426.5 ’ EL. BIG BEND GENERATING STATION

PARTICULATE TRAVERSE POINTS

OUTLET 

# N

PORT LOCATION PLAN

REVISED: 10-Jan-06 CS0W1 (BOILERS 1 & 2) TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 8.74

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 2.42

STACK DIAMETER = 29.917 FT. ID. STACK AREA = 702.952 SQ. FT.

PORT LENGTH = 62 IN. TRAVERSE

POINT

1

2

3 % OF STACK DIAMETER IN. FROM STACK WALL

4.4%

14.6%

29.6% 15.80 IN.

52.41 IN.

106.27 IN.

. 499 ’ EL.

165 ’ EL. 261.5 ’

FGD

PRESSURIZED

ANNULUS 72.5 ’



## A

B C D

9 ’ EL.



### 13

## APPENDIX A

PARTICULATE MATTER CALCULATIONS

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 1s Date: October 26, 2006

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.282 inches Barometric Pressure, P b : 29.84 "Hg Nozzle Area, A n : 0.000434 ft 2 Stack Pressure, P s : 29.83 "Hg Average Orifice Meter, Δ H: 1.197 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 37.809 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 79.4 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 124.2 o F
9.0 % O 2 Average √ Δ p: 0.502 "H 2 O 0.0 % CO Condensate Volume, V lc : 108.0 ml 81.0 % N 2 Meter Box Y: 0.999 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V lc 5.091 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.982 dscf
B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.121 % FDA = 1.0 - B w s 0.879 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole
M s = (M d x FDA) + (18.0 x B w s ) 28.51 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.87 ft/second Q s = v s x A s x 60 1259894.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 997948.2 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.1 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01700 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.007 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.013E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.017 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 2s Date: October 26, 2006

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.282 inches Barometric Pressure, P b : 29.81 "Hg Nozzle Area, A n : 0.000434 ft 2 Stack Pressure, P s : 29.80 "Hg Average Orifice Meter, Δ H: 1.148 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 37.373 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 82.4 o F Gas Analysis: 9.5 % CO 2 Average Stack Temp., T s : 124.0 o F
11.0 % O 2 Average √ Δ p: 0.491 "H 2 O

0.0 % CO Condensate Volume, V lc : 146.2 ml 79.5 % N 2 Meter Box Y: 0.999 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V lc 6.892 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.312 dscf
B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.160 % FDA = 1.0 - B w s 0.840 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole
M s = (M d x FDA) + (18.0 x B w s ) 28.05 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.44 ft/second Q s = v s x A s x 60 1241871.7 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 939910.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 104.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.03065 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.013 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.010 grains/acf C = c s / 7000 1.861E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.038 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 3s Date: October 26, 2006

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.282 inches Barometric Pressure, P b : 29.89 "Hg Nozzle Area, A n : 0.000434 ft 2 Stack Pressure, P s : 29.88 "Hg Average Orifice Meter, Δ H: 1.176 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 38.190 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 97.8 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 124.5 o F
10.5 % O 2 Average √ Δ p: 0.490 "H 2 O

0.0 % CO Condensate Volume, V l c : 147.5 ml 79.5 % N 2 Meter Box Y: 0.999 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 6.953 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.167 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.161 % FDA = 1.0 - B ws 0.839 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.02 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.08 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.35 ft/second Q s = v s x A s x 60 1237879.0 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 936644.1 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 104.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02365 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.010 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.008 grains/acf C = c s / 7000 1.442E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.028 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 1 Date: October 26, 2006

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.282 inches Barometric Pressure, P b : 29.76 "Hg Nozzle Area, A n : 0.000434 ft 2 Stack Pressure, P s : 29.75 "Hg Average Orifice Meter, Δ H: 1.275 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 38.760 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 75.5 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 122.0 o F
9.0 % O 2 Average √ Δ p: 0.519 "H 2 O 0.0 % CO Condensate Volume, V l c : 96.0 ml 81.0 % N 2 Meter Box Y: 0.999 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 4.525 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 38.094 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.106 % FDA = 1.0 - B ws 0.894 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.96 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.69 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 30.78 ft/second Q s = v s x A s x 60 1298171.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1046781.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 98.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01815 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.007 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.050E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.018 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 2 Date: October 26, 2006

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.282 inches Barometric Pressure, P b : 29.82 "Hg Nozzle Area, A n : 0.000434 ft 2 Stack Pressure, P s : 29.81 "Hg Average Orifice Meter, Δ H: 1.169 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 37.415 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 79.2 o F Gas Analysis: 9.5 % CO 2 Average Stack Temp., T s : 123.8 o F
10.5 % O 2 Average √ Δ p: 0.496 "H 2 O

0.0 % CO Condensate Volume, V l c : 143.0 ml 80.0 % N 2 Meter Box Y: 0.999 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 6.741 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.586 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.156 % FDA = 1.0 - B ws 0.844 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.94 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.08 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.77 ft/second Q s = v s x A s x 60 1255417.7 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 955294.1 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 103.4 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01415 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.006 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.005 grains/acf C = c s / 7000 8.526E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.017 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 3 Date: October 26, 2006

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.282 inches Barometric Pressure, P b : 29.89 "Hg Nozzle Area, A n : 0.000434 ft 2 Stack Pressure, P s : 29.88 "Hg Average Orifice Meter, Δ H: 1.169 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 37.492 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 79.2 o F Gas Analysis: 9.5 % CO 2 Average Stack Temp., T s : 123.8 o F
10.5 % O 2 Average √ Δ p: 0.496 "H 2 O

0.0 % CO Condensate Volume, V l c : 143.0 ml 80.0 % N 2 Meter Box Y: 0.999 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 6.741 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.747 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.155 % FDA = 1.0 - B ws 0.845 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.94 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.09 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.73 ft/second Q s = v s x A s x 60 1253792.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 956950.7 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 103.7 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01515 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0064 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0049 grains/acf C = c s / 7000 9.089E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.018 lbs/MMBtu

## APPENDIX B

PARTICULATE MATTER LABORATORY ANALYTICAL DATACustomerAIR SERVICESPlantBIG BENDUnitBOILER 2Method5-BStack Test Completion Date10/26/2006AnalystSSSample NumberAA85469ACETONE BEAKER1st weighingDate11/1/2006Time17:35% RH41.5%2nd weighingDate11/2/2006Time17:15% RH41.5%3rd weighingDate11/3/2006Time18:40% RH43.0%4th weighingDateTime% RH***Blank***Run 1Run 2Run 3Run 1SRun 2SRun 3SAcetone Container IDAIR 55AIR 51AIR 59AIR 77AIR 108AIR 17AIR 05Acetone Rinse Vol.(Va), mls200.00002002002002002002001st Gross Wt., grams107.4850107.4772107.9577107.5096107.3071105.1141106.83092nd Gross Wt., grams107.4846107.4761107.9566107.5093104.3066105.1129106.83003rd Gross Wt., grams107.4844107.4759107.9562107.5094104.3062105.1129106.82984th Gross Wt., gramsAvg. Gross Wt., grams107.48480107.47600107.95640107.50945104.30640105.11290106.82990Tare Wt., grams107.48385107.47040107.94685107.50420104.30310105.09725106.81985Acetone Blank Wt.,mg0.950.950.950.950.950.950.95Acetone Particulate Wt.,mg4.658.604.302.3514.709.10Acetone Residue, mg/g0.0060Acetone Blank CriteriaOK to subtract acetone blankFILTER1st weighingDate11/1/2006Time17:10% RH41.5%2nd weighingDate11/2/2006Time17:30% RH41.5%3rd weighingDateTime% RH4th weighingDateTime% RHFilter/Thimble ID2030432030412030302030372030382030332030391st Gross Wt., grams0.26490.28240.28400.28590.28390.28420.28312nd Gross Wt., grams0.26500.28220.28410.28560.28380.28410.28283rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams0.264950.282300.284050.285750.283850.284150.28295Tare Wt., grams0.265050.268800.267650.270450.269200.268200.26840Filter Particulate Wt.,mg13.5016.4015.3014.6515.9514.55Difference, milligrams-0.1Total Sample Particulate Wt.,mg18.1525.0019.6017.0030.6523.650.018150.025000.019600.017000.030650.02365Start Here

## APPENDIX C

BOILER/PRECIPITATOR OPERATIONAL DATA

## APPENDIX D

PLANT CEMS DAHS PRINTOUTS

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

10/26/2006 8:15 50.3 9.5 10/26/2006 8:16 50.3 9.5 10/26/2006 8:17 50.4 9.6 10/26/2006 8:18 50.3 9.5 10/26/2006 8:19 50.2 9.5 10/26/2006 8:20 49.5 9.5 10/26/2006 8:21 49.8 9.6 10/26/2006 8:22 51.1 9.6 10/26/2006 8:23 51.4 9.6 10/26/2006 8:24 50.8 9.6 10/26/2006 8:25 50.8 9.6 10/26/2006 8:26 50.3 9.4 10/26/2006 8:27 50.4 9.5 10/26/2006 8:28 51.6 9.6 10/26/2006 8:29 52.2 9.7 10/26/2006 8:30 50.5 9.6 10/26/2006 8:31 51.1 9.6 10/26/2006 8:32 49.2 9.6 10/26/2006 8:33 50 9.7 10/26/2006 8:34 48.3 9.5 10/26/2006 8:35 48.1 9.6 10/26/2006 8:36 49.3 9.7 10/26/2006 8:37 48.5 9.6 10/26/2006 8:38 49.2 9.6 10/26/2006 8:39 49.2 9.5 10/26/2006 8:40 49.1 9.6 10/26/2006 8:41 50 9.6 10/26/2006 8:42 49 9.6 10/26/2006 8:43 49.5 9.5 10/26/2006 8:44 48.6 9.5 10/26/2006 8:45 48.3 9.6 10/26/2006 8:46 48.3 9.6 10/26/2006 8:47 50.1 9.6 10/26/2006 8:48 49.8 9.6 10/26/2006 8:49 49.2 9.6

Page 1 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

10/26/2006 8:50 49.7 9.6 10/26/2006 8:51 48.2 9.6 10/26/2006 8:52 48.2 9.6 10/26/2006 8:53 49.6 9.6 10/26/2006 8:54 49.4 9.5 10/26/2006 8:55 49.8 9.5 10/26/2006 8:56 49.9 9.6 10/26/2006 8:57 50.1 9.6 10/26/2006 8:58 50 9.6 10/26/2006 8:59 49.6 9.6 10/26/2006 9:00 47.9 9.7 10/26/2006 9:01 48.2 9.7 10/26/2006 9:02 48.1 9.7 10/26/2006 9:03 46.9 9.6 10/26/2006 9:04 47.5 9.6 10/26/2006 9:05 47.5 9.6 10/26/2006 9:06 46.9 9.5 10/26/2006 9:07 46.5 9.4 10/26/2006 9:08 47.4 9.5 10/26/2006 9:09 48.3 9.6 10/26/2006 9:10 48.6 9.6 10/26/2006 9:11 49.4 9.6 10/26/2006 9:12 49.6 9.5 10/26/2006 9:13 49.9 9.5 10/26/2006 9:14 51.3 9.6 10/26/2006 9:15 52.5 9.8 10/26/2006 9:16 50.1 9.6 10/26/2006 9:17 49.6 9.5 10/26/2006 9:18 49.6 9.5 10/26/2006 9:19 50.9 9.7 10/26/2006 9:20 51.8 9.7 10/26/2006 9:21 50.8 9.6 10/26/2006 9:22 51.7 9.7 10/26/2006 9:23 51 9.7 10/26/2006 9:24 50.9 9.6 10/26/2006 9:25 50 9.5 10/26/2006 9:26 50.6 9.7

Page 2 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21

10/26/2006 9:27 50.6 9.7 10/26/2006 9:28 50.1 9.7 10/26/2006 9:29 49.8 9.6 10/26/2006 9:30 48.3 9.6 10/26/2006 9:31 48.2 9.6 10/26/2006 9:32 49.8 9.6 10/26/2006 9:33 51.2 9.8 10/26/2006 9:34 54.2 9.9 10/26/2006 9:35 53.9 9.9 10/26/2006 9:36 53.7 9.8 10/26/2006 9:37 53 9.8 10/26/2006 9:38 52.6 9.7 10/26/2006 9:39 53.5 9.7 10/26/2006 9:40 52.5 9.7 10/26/2006 9:41 53.6 9.7 10/26/2006 9:42 53.4 9.7 10/26/2006 9:43 53.2 9.8 10/26/2006 9:44 55.8 9.9 10/26/2006 9:45 55 9.9 10/26/2006 9:46 53.1 9.8 10/26/2006 9:47 53.4 9.8 10/26/2006 9:48 53.5 9.8 10/26/2006 9:49 52.1 9.9 10/26/2006 9:50 53.4 9.8 10/26/2006 9:51 53.2 9.8 10/26/2006 9:52 51.4 9.8 10/26/2006 9:53 50.1 9.8 10/26/2006 9:54 49.4 9.8 10/26/2006 9:55 50.5 9.9 10/26/2006 9:56 53.3 10 10/26/2006 9:57 53.2 10 10/26/2006 9:58 51.8 9.9 10/26/2006 9:59 52.1 9.8 10/26/2006 10:00 51.3 9.8 10/26/2006 10:01 51.5 9.8 10/26/2006 10:02 52.8 9.9 10/26/2006 10:03 53.8 9.9

Page 3 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 10:04 56.6 9.9 10/26/2006 10:05 54.6 9.8 10/26/2006 10:06 53.8 9.7 10/26/2006 10:07 53.1 9.8 10/26/2006 10:08 56.3 9.9 10/26/2006 10:09 56.4 10 10/26/2006 10:10 56.1 10 10/26/2006 10:11 55.6 9.9 10/26/2006 10:12 57.4 10 10/26/2006 10:13 56.4 10 10/26/2006 10:14 56.3 9.9 10/26/2006 10:15 54.5 9.8 10/26/2006 10:16 55 10 10/26/2006 10:17 54.1 10 10/26/2006 10:18 53.9 9.9 10/26/2006 10:19 53.6 9.9 10/26/2006 10:20 54.8 10 10/26/2006 10:21 54.3 10 10/26/2006 10:22 55.7 10 10/26/2006 10:23 57.1 10 10/26/2006 10:24 56.8 10 10/26/2006 10:25 55.7 9.9 10/26/2006 10:26 56.5 9.8 10/26/2006 10:27 55.6 9.9 10/26/2006 10:28 54.6 9.8 10/26/2006 10:29 55.6 9.7 10/26/2006 10:30 55.8 9.8 10/26/2006 10:31 57.3 10 10/26/2006 10:32 59.2 10 10/26/2006 10:33 59 10 10/26/2006 10:34 60.3 9.9 10/26/2006 10:35 59.7 9.9 10/26/2006 10:36 58.6 9.8 10/26/2006 10:37 59.1 9.9 10/26/2006 10:38 59.6 10 10/26/2006 10:39 57.5 9.9 10/26/2006 10:40 55.2 9.9

Page 4 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 10:41 54.4 9.9 10/26/2006 10:42 54.2 9.9 10/26/2006 10:43 56.8 10 10/26/2006 10:44 56.5 9.9 10/26/2006 10:45 54.9 9.9 10/26/2006 10:46 55 9.8 10/26/2006 10:47 55 9.8 10/26/2006 10:48 56 9.8 10/26/2006 10:49 55.8 9.8 10/26/2006 10:50 55.9 9.8 10/26/2006 10:51 56.4 9.9 10/26/2006 10:52 56.6 9.9 10/26/2006 10:53 58.3 9.9 10/26/2006 10:54 57.7 9.9 10/26/2006 10:55 57 9.8 10/26/2006 10:56 58.1 9.9 10/26/2006 10:57 56.8 9.9 10/26/2006 10:58 58.8 10.1 10/26/2006 10:59 59.4 10 10/26/2006 11:00 56.9 9.8 10/26/2006 11:01 57.4 9.8 10/26/2006 11:02 56.8 9.9 10/26/2006 11:03 55.5 9.8 10/26/2006 11:04 54.1 9.9 10/26/2006 11:05 57.5 10 10/26/2006 11:06 54.9 9.9 10/26/2006 11:07 53.9 9.8 10/26/2006 11:08 55 9.7 10/26/2006 11:09 55.1 9.9 10/26/2006 11:10 56.7 10 10/26/2006 11:11 56.9 10.1 10/26/2006 11:12 57.8 9.9 10/26/2006 11:13 57.8 9.8 10/26/2006 11:14 57.5 9.9 10/26/2006 11:15 57.9 9.9 10/26/2006 11:16 57.3 9.9 10/26/2006 11:17 58.3 10

Page 5 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 11:18 57.8 10 10/26/2006 11:19 57.8 9.9 10/26/2006 11:20 58.2 9.9 10/26/2006 11:21 56.5 9.9 10/26/2006 11:22 56.4 9.9 10/26/2006 11:23 57.1 9.9 10/26/2006 11:24 57.4 9.8 10/26/2006 11:25 57.3 9.8 10/26/2006 11:26 56.3 9.7 10/26/2006 11:27 55.6 9.8 10/26/2006 11:28 56.2 9.9 10/26/2006 11:29 55.6 10 10/26/2006 11:30 55.1 10 10/26/2006 11:31 55 10 10/26/2006 11:32 56.4 9.9 10/26/2006 11:33 55 9.9 10/26/2006 11:34 55.8 10 10/26/2006 11:35 55.9 9.9 10/26/2006 11:36 56.1 9.9 10/26/2006 11:37 56.8 9.8 10/26/2006 11:38 56.4 9.8 10/26/2006 11:39 58 9.9 10/26/2006 11:40 59 10 10/26/2006 11:41 58.8 10 10/26/2006 11:42 59.4 10.1 10/26/2006 11:43 60.2 10 10/26/2006 11:44 57.9 9.9 10/26/2006 11:45 58.3 10 10/26/2006 11:46 58.1 10 10/26/2006 11:47 58.5 10 10/26/2006 11:48 59 10 10/26/2006 11:49 58.1 10.1 10/26/2006 11:50 57 10 10/26/2006 11:51 55.6 10 10/26/2006 11:52 56.6 10.1 10/26/2006 11:53 58.3 10.1 10/26/2006 11:54 56.9 10

Page 6 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 11:55 56.8 10 10/26/2006 11:56 57.4 10.1 10/26/2006 11:57 58.6 10.1 10/26/2006 11:58 58.7 10.1 10/26/2006 11:59 57.4 10 10/26/2006 12:00 57.3 10 10/26/2006 12:01 59 10.1 10/26/2006 12:02 58.4 10 10/26/2006 12:03 57.2 10 10/26/2006 12:04 59.1 10.1 10/26/2006 12:05 60 10 10/26/2006 12:06 57.4 10 10/26/2006 12:07 58.6 10.1 10/26/2006 12:08 59.8 10.1 10/26/2006 12:09 59.6 10.1 10/26/2006 12:10 59.6 10.2 10/26/2006 12:11 60.6 10.1 10/26/2006 12:12 58.4 10.1 10/26/2006 12:13 56.8 10.1 10/26/2006 12:14 56.7 10.1 10/26/2006 12:15 56.1 10.1 10/26/2006 12:16 55.1 10 10/26/2006 12:17 55.3 10.1 10/26/2006 12:18 55.1 10.1 10/26/2006 12:19 54.2 10.1 10/26/2006 12:20 55.6 9.9 10/26/2006 12:21 56.6 10.1 10/26/2006 12:22 57.6 10.2 10/26/2006 12:23 58.2 10.1 10/26/2006 12:24 56.9 10 10/26/2006 12:25 58.6 10.1 10/26/2006 12:26 60.5 10.2 10/26/2006 12:27 59 10.1 10/26/2006 12:28 58.7 10.1 10/26/2006 12:29 59.3 10.1 10/26/2006 12:30 59.9 10.1 10/26/2006 12:31 60.1 10.1

Page 7 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 12:32 59.2 10.1 10/26/2006 12:33 60.2 10.1 10/26/2006 12:34 60.8 10.2 10/26/2006 12:35 62.5 10.2 10/26/2006 12:36 61.5 10.1 10/26/2006 12:37 61.1 10.1 10/26/2006 12:38 61.3 10.2 10/26/2006 12:39 60.2 10.2 10/26/2006 12:40 59.8 10.2 10/26/2006 12:41 58 10.1 10/26/2006 12:42 57.6 10.1 10/26/2006 12:43 57.8 10.1 10/26/2006 12:44 57.7 10 10/26/2006 12:45 59.5 10.1 10/26/2006 12:46 59.6 10.2 10/26/2006 12:47 61 10.3 10/26/2006 12:48 61.7 10.3 10/26/2006 12:49 61.6 10.3 10/26/2006 12:50 62.4 10.2 10/26/2006 12:51 62 10.2 10/26/2006 12:52 61.5 10.3 10/26/2006 12:53 62.8 10.2 10/26/2006 12:54 63 10.2 10/26/2006 12:55 61.5 10.1 10/26/2006 12:56 62.7 10.1 10/26/2006 12:57 63.9 10.2 10/26/2006 12:58 64.1 10.2 10/26/2006 12:59 63.8 10.2 10/26/2006 13:00 64.3 10.3 10/26/2006 13:01 65.7 10.3 10/26/2006 13:02 63.8 10.3 10/26/2006 13:03 60.8 10.3 10/26/2006 13:04 58.9 10.3 10/26/2006 13:05 58.2 10.2 10/26/2006 13:06 60.4 10.3 10/26/2006 13:07 60.3 10.4 10/26/2006 13:08 59.2 10.2

Page 8 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 13:09 60 10.3 10/26/2006 13:10 60.4 10.3 10/26/2006 13:11 61.8 10.2 10/26/2006 13:12 60.1 10.1 10/26/2006 13:13 60.2 10.2 10/26/2006 13:14 61.5 10.3 10/26/2006 13:15 62.1 10.4 10/26/2006 13:16 62.2 10.4 10/26/2006 13:17 60.5 10.3 10/26/2006 13:18 60.4 10.2 10/26/2006 13:19 61.4 10.3 10/26/2006 13:20 60.1 10.2 10/26/2006 13:21 60 10.2 10/26/2006 13:22 60.2 10.2 10/26/2006 13:23 59.4 10.2 10/26/2006 13:24 60.2 10.3 10/26/2006 13:25 60.3 10.3 10/26/2006 13:26 59 10.2 10/26/2006 13:27 59.6 10.2 10/26/2006 13:28 59.4 10.3 10/26/2006 13:29 59.7 10.3 10/26/2006 13:30 58.4 10.2 10/26/2006 13:31 58.1 10.2 10/26/2006 13:32 58.1 10.1 10/26/2006 13:33 59.6 10.2 10/26/2006 13:34 58.3 10.2 10/26/2006 13:35 58.6 10.1 10/26/2006 13:36 59.2 10.2 10/26/2006 13:37 59.7 10.1 10/26/2006 13:38 59.4 10 10/26/2006 13:39 61.5 10.2 10/26/2006 13:40 62.8 10.3 10/26/2006 13:41 61.7 10.2 10/26/2006 13:42 62.1 10.2 10/26/2006 13:43 61.7 10.2 10/26/2006 13:44 63.1 10.2 10/26/2006 13:45 61.3 10.2

Page 9 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 13:46 60.7 10.2 10/26/2006 13:47 61.1 10.1 10/26/2006 13:48 58.7 10.1 10/26/2006 13:49 58.6 10.2 10/26/2006 13:50 58.1 10.2 10/26/2006 13:51 55.3 10.1 10/26/2006 13:52 54.7 9.9 10/26/2006 13:53 54.2 10 10/26/2006 13:54 55.4 10.2 10/26/2006 13:55 57.8 10.2 10/26/2006 13:56 56.6 10.2 10/26/2006 13:57 56.5 10.2 10/26/2006 13:58 55.9 10.2 10/26/2006 13:59 56.8 10.3 10/26/2006 14:00 57.5 10.3 10/26/2006 14:01 58.6 10.2 10/26/2006 14:02 57.4 10.1 10/26/2006 14:03 57.4 10.2 10/26/2006 14:04 56.9 10.1 10/26/2006 14:05 58.8 10.2 10/26/2006 14:06 57.5 10.1 10/26/2006 14:07 58.3 10.2 10/26/2006 14:08 60.2 10.2 10/26/2006 14:09 59.8 10.2 10/26/2006 14:10 58.5 10.1 10/26/2006 14:11 57.8 10.1 10/26/2006 14:12 56.1 10.1 10/26/2006 14:13 57.2 10.3 10/26/2006 14:14 58.3 10.4 10/26/2006 14:15 55 10.2 10/26/2006 14:16 55.4 10.2 10/26/2006 14:17 56.3 10.2 10/26/2006 14:18 58.4 10.3 10/26/2006 14:19 58.7 10.2 10/26/2006 14:20 58.6 10.2 10/26/2006 14:21 59.9 10.3 10/26/2006 14:22 58.8 10.2

Page 10 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 14:23 59.7 10.1 10/26/2006 14:24 60.8 10.3 10/26/2006 14:25 59.8 10.2 10/26/2006 14:26 58.6 10.2 10/26/2006 14:27 57.7 10.2 10/26/2006 14:28 58.9 10.2 10/26/2006 14:29 59.1 10.2 10/26/2006 14:30 59 10.1 10/26/2006 14:31 60 10.2 10/26/2006 14:32 62.1 10.3 10/26/2006 14:33 59.1 10.2 10/26/2006 14:34 57.1 10.1 10/26/2006 14:35 57 10.2 10/26/2006 14:36 56.8 10.2 10/26/2006 14:37 56.2 10.2 10/26/2006 14:38 54.9 10.2 10/26/2006 14:39 56.7 10.3 10/26/2006 14:40 57.9 10.3 10/26/2006 14:41 58.1 10.2 10/26/2006 14:42 56.3 10.2 10/26/2006 14:43 55.8 10.1 10/26/2006 14:44 56.8 10.2 10/26/2006 14:45 55.9 10.1 10/26/2006 14:46 56.2 10 10/26/2006 14:47 57.4 10 10/26/2006 14:48 57.6 10.2 10/26/2006 14:49 57.1 10.2 10/26/2006 14:50 55.4 10.1 10/26/2006 14:51 56.4 10.1 10/26/2006 14:52 56.2 10.1 10/26/2006 14:53 57.1 10.1 10/26/2006 14:54 56 10.2 10/26/2006 14:55 55.1 10.2 10/26/2006 14:56 53.4 10.1 10/26/2006 14:57 52.5 10 10/26/2006 14:58 52.8 10 10/26/2006 14:59 54.4 10.1

Page 11 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 15:00 53.6 10.1 10/26/2006 15:01 53.9 10 10/26/2006 15:02 55.3 10.1 10/26/2006 15:03 56 10.1 10/26/2006 15:04 55.4 10.1 10/26/2006 15:05 54 10.1 10/26/2006 15:06 54.4 10.1 10/26/2006 15:07 54.7 10.1 10/26/2006 15:08 56.5 10.2 10/26/2006 15:09 55.2 10.2 10/26/2006 15:10 54.7 10 10/26/2006 15:11 55.5 10 10/26/2006 15:12 55.2 10.1 10/26/2006 15:13 56.9 10.1 10/26/2006 15:14 56.6 10.2 10/26/2006 15:15 55.8 10.2 10/26/2006 15:16 56 10.1 10/26/2006 15:17 54.3 10 10/26/2006 15:18 52.2 10 10/26/2006 15:19 52.7 10.1 10/26/2006 15:20 53.2 10.3 10/26/2006 15:26 54.9 9.8 10/26/2006 15:27 54.9 9.8 10/26/2006 15:28 55.8 9.9 10/26/2006 15:29 56.5 9.9 10/26/2006 15:30 52.9 9.8 10/26/2006 15:31 54.5 9.9 10/26/2006 15:32 57.1 10 10/26/2006 15:33 55.4 10.1 10/26/2006 15:34 56.7 10.1 10/26/2006 15:35 56.5 10.1 10/26/2006 15:36 55.2 10.1 10/26/2006 15:37 55.2 10.1 10/26/2006 15:38 54.7 10.1 10/26/2006 15:39 56.4 10.2 10/26/2006 15:40 56.7 10.2 10/26/2006 15:41 55.1 10.1

Page 12 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 15:42 52 10.1 10/26/2006 15:43 52.2 10.1 10/26/2006 15:44 52.2 10.1 10/26/2006 15:45 52 10.2 10/26/2006 15:46 52.2 10.1 10/26/2006 15:47 51.3 10.2 10/26/2006 15:48 52.8 10.3 10/26/2006 15:49 54.5 10.2 10/26/2006 15:50 54 10.2 10/26/2006 15:51 54.5 10.2 10/26/2006 15:52 54.4 10.2 10/26/2006 15:53 55.1 10.1 10/26/2006 15:54 56.8 10.2 10/26/2006 15:55 57.1 10.3 10/26/2006 15:56 56.7 10.2 10/26/2006 15:57 56.2 10.2 10/26/2006 15:58 55.4 10.1 10/26/2006 15:59 56.3 10.3 10/26/2006 16:00 59.3 10.5 10/26/2006 16:01 59.7 10.5 10/26/2006 16:02 59.2 10.5 10/26/2006 16:03 59.6 10.4 10/26/2006 16:04 58.8 10.4 10/26/2006 16:05 58.4 10.5 10/26/2006 16:06 57.6 10.5 10/26/2006 16:07 55.2 10.4 10/26/2006 16:08 54.9 10.2 10/26/2006 16:09 54 10.3 10/26/2006 16:10 54.7 10.4 10/26/2006 16:11 56.3 10.4 10/26/2006 16:12 55.8 10.4 10/26/2006 16:13 54.8 10.3 10/26/2006 16:14 57 10.2 10/26/2006 16:15 55 10.3 10/26/2006 16:16 55.3 10.3 10/26/2006 16:17 56.6 10.4 10/26/2006 16:18 56.5 10.4

Page 13 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 16:19 55 10.3 10/26/2006 16:20 56.2 10.3 10/26/2006 16:21 57.4 10.2 10/26/2006 16:22 58.2 10.2 10/26/2006 16:23 57.1 10.2 10/26/2006 16:24 56.1 10.2 10/26/2006 16:25 57.8 10.3 10/26/2006 16:26 57.8 10.3 10/26/2006 16:27 55.8 10.3 10/26/2006 16:28 55.4 10.2 10/26/2006 16:29 55.7 10.4 10/26/2006 16:30 54.6 10.4 10/26/2006 16:31 54.8 10.4 10/26/2006 16:32 53.6 10.3 10/26/2006 16:33 51.7 10.1 10/26/2006 16:34 52.3 10.2 10/26/2006 16:35 53.7 10.3 10/26/2006 16:36 55.1 10.3 10/26/2006 16:37 56.2 10.4 10/26/2006 16:38 55.4 10.3 10/26/2006 16:39 55.3 10.2 10/26/2006 16:40 54.9 10.1 10/26/2006 16:41 54.7 10 10/26/2006 16:42 55.3 10.1 10/26/2006 16:43 56.9 10.2 10/26/2006 16:44 58.1 10.3 10/26/2006 16:45 56.6 10.2 10/26/2006 16:46 55.5 10.1 10/26/2006 16:47 56.2 10.1 10/26/2006 16:48 58.4 10.2 10/26/2006 16:49 57 10.3 10/26/2006 16:50 55.7 10.1 10/26/2006 16:51 54.7 10.2 10/26/2006 16:52 55.9 10.3 10/26/2006 16:53 54.2 10.3 10/26/2006 16:54 54.2 10.2 10/26/2006 16:55 54.4 10.3

Page 14 of 15

### Big Bend Unit 2 Compliance SO2 Data

Date Time SO21 CO21 10/26/2006 16:56 55.9 10.4 10/26/2006 16:57 56.4 10.4 10/26/2006 16:58 56 10.2 10/26/2006 16:59 54.9 10.2 10/26/2006 17:00 56.1 10.2 10/26/2006 17:01 57.1 10.3 10/26/2006 17:02 57.5 10.3 10/26/2006 17:03 54.6 10.2 10/26/2006 17:04 54.6 10.1 10/26/2006 17:05 54.9 10.1 10/26/2006 17:06 57.3 10.3 10/26/2006 17:07 56.6 10.2 10/26/2006 17:08 56.2 10.2 10/26/2006 17:09 55.2 10.1 10/26/2006 17:10 58 10.2 10/26/2006 17:11 58.1 10.4 10/26/2006 17:12 57.5 10.3 10/26/2006 17:13 56.6 10.3 10/26/2006 17:14 54.6 10.2 10/26/2006 17:15 53.2 10.1 A verages: 55.87 10.02

Note : Data from 15:21 through 15:25 removed from averaqe due to prob e blowback.

Page 15 of 15

### Date Time OPACITY2 10/26/2006 9:44 7.9 10/26/2006 9:45 7.5 10/26/2006 9:46 7.3 10/26/2006 9:47 7.4 10/26/2006 9:48 7.3 10/26/2006 9:49 7.5 10/26/2006 9:50 7 10/26/2006 9:51 6.9 10/26/2006 9:52 6.9 10/26/2006 9:53 6.6 10/26/2006 9:54 6.8 10/26/2006 9:55 7.7 10/26/2006 9:56 7.6 10/26/2006 9:57 7.1 10/26/2006 9:58 7.2 10/26/2006 9:59 7.1 10/26/2006 10:00 6.6 10/26/2006 10:01 7.2 10/26/2006 10:02 7.5 10/26/2006 10:03 7.1 10/26/2006 10:04 6.9 10/26/2006 10:05 6.7 10/26/2006 10:06 6.6 10/26/2006 10:07 7.2 10/26/2006 10:08 7.3 10/26/2006 10:09 7.3 10/26/2006 10:10 7.1 10/26/2006 10:11 7.1 10/26/2006 10:12 6.5 10/26/2006 10:13 6.7 10/26/2006 10:14 6.8 10/26/2006 10:15 6.8 10/26/2006 10:16 7.4 10/26/2006 10:17 6.9 10/26/2006 10:18 6.5 10/26/2006 10:19 6.6 10/26/2006 10:20 6.7 10/26/2006 10:21 6.8 10/26/2006 10:22 6.8 10/26/2006 10:23 7.3 10/26/2006 10:24 7.5 10/26/2006 10:25 7

Page 1 of 2

### Date Time OPACITY2 10/26/2006 10:26 6.8 10/26/2006 10:27 6.8 10/26/2006 10:28 6.9 10/26/2006 10:29 7 10/26/2006 10:30 7.1 10/26/2006 10:31 7.5 10/26/2006 10:32 7.2 10/26/2006 10:33 7.2 10/26/2006 10:34 7.1 10/26/2006 10:35 7.1 10/26/2006 10:36 7.2 10/26/2006 10:37 7.3 10/26/2006 10:38 7.1 10/26/2006 10:39 7.1 10/26/2006 10:40 7.8 10/26/2006 10:41 7.4 10/26/2006 10:42 8.1 10/26/2006 10:43 8.5 10/26/2006 10:44 7.8

Page 2 of 2

### Date Time OPACITY2 10/26/2006 8:15 8.5 10/26/2006 8:16 8.3 10/26/2006 8:17 8.4 10/26/2006 8:18 8.4 10/26/2006 8:19 8.7 10/26/2006 8:20 8.9 10/26/2006 8:21 8.8 10/26/2006 8:22 9 10/26/2006 8:23 8.3 10/26/2006 8:24 8.3 10/26/2006 8:25 8.4 10/26/2006 8:26 8.6 10/26/2006 8:27 8.6 10/26/2006 8:28 8.5 10/26/2006 8:29 8.4 10/26/2006 8:30 8.5 10/26/2006 8:31 8.6 10/26/2006 8:32 8.6 10/26/2006 8:33 8.9 10/26/2006 8:34 9.1 10/26/2006 8:35 8.9 10/26/2006 8:36 9 10/26/2006 8:37 9.4 10/26/2006 8:38 8.9 10/26/2006 8:39 9 10/26/2006 8:40 8.8 10/26/2006 8:41 8.5 10/26/2006 8:42 8.5 10/26/2006 8:43 8.6 10/26/2006 8:44 8.6 10/26/2006 8:45 8.9 10/26/2006 8:46 8.8 10/26/2006 8:47 8.5 10/26/2006 8:48 8.8 10/26/2006 8:49 8.7 10/26/2006 8:50 8.6 10/26/2006 8:51 8.3 10/26/2006 8:52 8.2 10/26/2006 8:53 8.3 10/26/2006 8:54 8.4 10/26/2006 8:55 8.2 10/26/2006 8:56 8.3

Page 1 of 2

### Date Time OPACITY2 10/26/2006 8:57 8.4 10/26/2006 8:58 9.1 10/26/2006 8:59 9 10/26/2006 9:00 8.9 10/26/2006 9:01 9.2 10/26/2006 9:02 9 10/26/2006 9:03 8.9 10/26/2006 9:04 8.6 10/26/2006 9:05 8.7 10/26/2006 9:06 9.2 10/26/2006 9:07 9.3 10/26/2006 9:08 8.9 10/26/2006 9:09 8.8 10/26/2006 9:10 8.7 10/26/2006 9:11 9 10/26/2006 9:12 9 10/26/2006 9:13 9.2 10/26/2006 9:14 8.9 10/26/2006 9:15 8.7

Page 2 of 2

## APPENDIX E

FUEL ANALYSIS

## Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 Ph (813) 630-7378 * Fax (813) 630-7360 * DOH #E54272

11/14/2006 Report For:

TE_BB_2_COMP_CO Location Code: Location Description: Sample Collector: Sample Collection Date Lab Submittal Date: 

### Sample Information

Big Bend 2 Compliance 10/26/2006 10/30/2006

ASG Report Date: 

## Laboratory ID: AA85469

Laboratory Results

Coal Analysis - As Received Result Units Lower Limit Upper Limit Violation

% Ash, as Received 8.59
BTU/Lb BTU, as Received 11788
% Sulfur, as Received 2.85



### Coal Analysis - Dry Basis Result Units Lower Limit Upper Limit Violation

% Ash, Dry Basis 9.60
BTU/Lb. BTU, Dry Basis 13172
% Sulfur, Dry Basis 3.18



### Coal Analysis - Mi scellaneous Result Units Lower Limit Upper Limit Violation

BTU/Lb. BTU, Moisture-Ash Free 14571
Lbs. SO2/MMBTU Pounds SO2 / Million BTU 4.59
% Total Moisture 10.51


### Comments

Robert Dorey, Manager, Laboratory Services

Report Number: -111406- 09 AA85469 Page 1 of 1 "Coal Report"

## APPENDIX F

FIELD DATA SHEETS

## APPENDIX G

SAMPLING EQUIPMENT CALIBRATIONS

## SUMMARY OF E Q UIPMENT CALIBRATION S Bi g Bend Unit #2

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 07) USEPA RM 5 INITIA L 10/03/06 (ORIFICE) 0.999 POST TEST 10/09/06 0.982

NOZZLE SN19 INITIA L 10/02/06 CALIPER 0.282 POST TEST 11/01/06 MEASUREMENTS 0.283

PYROMETER (PY 09) 10/03/06 ASTM THERMOMETER + 2 o 

### F

PITOT TUBE (PT 05) 10/03/06 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 07) 10/02/06 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Blue Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30.15 "Hg Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.22 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.60 15 356.984 363.887 6.903 79 77 79 77 1.10 15 347.782 356.984 9.202 81 78 80 78 1.90 15 335.841 347.782 11.941 81 78 83 78 3.50 15 319.720 335.841 16.121 80 75 88 78

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3483 22.0 72 72 72.0 55 0.4660 21.0 72 72 72.0 63 0.5971 19.0 72 72 72.0 73 0.8177 16.5 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC
Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.834 6.829 6.831 0.999 0.000 1.610 -0.060 9.100 9.137 9.140 1.004 0.005 1.645 -0.025 11.815 11.708 11.711 0.991 -0.008 1.729 0.058 16.006 16.033 16.038 1.002 0.003 1.697 0.027 Averages: 0.999 1.670

Review/Approval: 5-Oct-06 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

10/3/2006

JAV

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice

### Environmental Services Air Services Group

Manufacturer: Thermo Calibration Date: Model Number:MST Barometric Pressure: 30.15 "Hg Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.22 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: BLUE

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF

1.1 10 640.400 646.530 6.130 72 72 74 72 1.1 10 646.530 652.600 6.070 74 72 75 73 1.1 10 652.600 658.750 6.150 74 73 77 74

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4592 20.5 72 72 72.0 55 0.4592 20.5 72 72 72.0 55 0.4592 20.5 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC
Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.139 6.003 6.004 0.978 -0.004 1.716 0.003 6.067 6.003 6.004 0.989 0.008 1.713 0.000 6.136 6.003 6.004 0.978 -0.004 1.709 -0.003 Averages: 0.982 1.713 Prior Y: 0.999 % Difference: 1.72%

Review/Approval: Date: Big Bend CS001W IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

GDB 11/9/2006 

### POST - TEST CALIBRATION CHECK

10-Nov-06 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Service s A ir Services Grou p

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET

Calibration Date: 10/2/2006 Responsible Party: SEG

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average
I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.296 0.294 0.290 0.002 0.115 ^SN04 0.320 0.320 0.320 0.000 0.126 ^SN05 0.380 0.380 0.378 0.001 0.149 ^SN06 0.500 0.496 0.500 0.002 0.196 ^SN09 0.695 0.689 0.690 0.002 0.272 ^SN10 0.755 0.750 0.755 0.002 0.297 ^SN12 0.985 0.985 0.983 0.001 0.388 ^SN15 0.420 0.420 0.420 0.000 0.165 ^SN16 0.504 0.505 0.505 0.000 0.199 ^SN19 0.717 0.714 0.715 0.001 0.282 ^SN22 0.932 0.930 0.934 0.002 0.367 ^SN30 0.795 0.792 0.795 0.001 0.313 ^SN36 0.480 0.477 0.477 0.001 0.188 ^SN37 0.535 0.534 0.532 0.001 0.210 ^SN38 0.635 0.640 0.640 0.002 0.251 ^SN46 0.482 0.485 0.483 0.001 0.190 ^SN47 0.515 0.516 0.516 0.000 0.203 ^SN48 0.645 0.640 0.640 0.002 0.253 ^SN50 0.788 0.790 0.791 0.001 0.311 ^SN58 0.619 0.611 0.615 0.003 0.242 ^SN68 0.630 0.625 0.632 0.003 0.248 ^SN69 0.950 0.950 0.950 0.000 0.374 ^SN70 1.565 1.565 1.565 0.000 0.616 ^SN71 1.558 1.560 1.560 0.001 0.614 ^SN72 0.955 0.953 0.950 0.002 0.375 ^SN73 1.277 1.280 1.280 0.001 0.504 ^SN74 1.245 1.240 1.245 0.002 0.490 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by: 5-Oct-06

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 11/1/2006 

### Calibration Personnel: Jorge A. Varino 

### Test Designation:

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN19 0.720 0.720 0.717 0.001 0.283

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN19 was 0.282

Difference (Pre-test/Post-test) is: -0.001

QA/QC Review by: 1-Nov-06

### Environmental Services A ir Services Group Pyrometer Calibration Blue Team Pyrometer Under Tes t Pyrometer Number: ^PY09 Labworks Sample # 0 Calibration Date: 10/2/2006

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 7/11/2006 Calibration Personnel (Typed and Signature): JAV

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 399 1 2 

### 212 213 -1 3 

### 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: 

### 5-Oct-06Environmental Services Air Services Group

_ _

s PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT05 Calibration Dat e 10/3/2006 Operating Quarter/Year: Red Team Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 2 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 0.8 degrees Pass α < 10 degrees β 1 2.1 degrees Pass ( α 1 measured across top impact openings) β 2 3.1 degrees Pass ( α 2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α

, Ζ

, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.3 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.31 cm W < 0.08 cm (Asin ο )
Ζ 0.012 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.1 degrees ψ angle between tips W 0.004 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by:

Quality Assurance Review / Approval: 16-Oct-06

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR04 Calibration Date: 10/2/2006 Calibration Personnel: JA V Labworks #: Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 11:00 30.25 30.18 0.07 13:00 30.2 30.15 0.05 14:50 30.2 30.12 0.08

Avera g e Difference: 0.07

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: Date: 5-Oct-06

## APPENDIX H

CHAIN OF CUSTODY

## APPENDIX I

TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL SERVICES AIR SERVICES GROUP Test Team Scott Given Associate Technician Charles Dufeny Environmental Technician Jorge Varino Environmental Technician, Test Team Lead

Process Data Curtis Seebaran Engineer, Big Bend Station Raymond A. McDarby Senior Environmental Technician Fuel Analysis
Patrece Jackson Environmental Technician Sample Analysis
Sam Soth Environmental Technician Report Preparation Raymond A. McDarby Senior Environmental Technician
Test Coordination Curtis Seebaran Engineer, Big Bend Station