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# OAR Box 1851 Prepped by Keeia Richards



# Document

Number: 

# 34) ll-A-8 Docket Number: 

# A-90-1 9

Printed 11/19/200811:19:51 AM Sheet 34 of 41

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# J * A-90-1 9 ll-A- 8 

# W

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# tPA-450/3-73-006- e 

# I T
r 

# : T
' T 

# i r 

# j rami [ l ENGINEERING

AN D COST STUD

Y j E^RJX>CKE; 

# O F AI RPOLLUTION CONTRO L FO RTH E PETROCHEMICA

L INDUSTR

Y VOLUM E 5 : FORMALDEHYDE MANUFACTUR

E WIT H TH E MIXE D OXIDE CATALYS T PROCES S b y '
. , R
. B
. Morris , F
. B
. Hoggins , Jr. , , ,- . " ; J
. A
. Lee , R
. Newirth , an dJ
. W
. Pervie r . ' 0

# a Houdr y Divisio n Ai r Product s an dChemicals , Inc
. P
. O
. Bo x 42 7

_„ Marcu s Hook , Pennsylvani a1906 1 J i Contrac t No
. 68-02-025 5 EP AProjec t

Officer : Lesli e B
. Evan s 

# I j 

# I ~ >



# ENVIRONMENTA L PROTECTIONAGENC Y Offic e o f

Ai r an dWast e Managemen t Offic e o f

Ai r Qualit y Plannin g an dStandard s Researc hTriangl e Park , N
. C
. 2771 1

Marc h197 5

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# Thi s repor t

i s issue db y th e Environmenta l Protectio nAgenc y to repor t technica l dat ao

f interes t t o alimite dnumbe r

o f readers
. Copie s ar e availabl e fre e o

f charg e to Federa l employees , curren t contractor s an d grantees , an dnonprofi t organization s - a s supplie s permi t - fro mth e Ai r Pollutio nTechnica l Informatio nCenter , Environmenta l Protectio nAgency , Researc hTriangl e Park , Nort hCarolin a27711 ; or , fo r afee , fro mth e Nationa l Technica l Informatio nService , 528 5 Por t Roya l Road , Springfield , Virgini a22161
.

Thi s repor t

wa s furnishe dt o th e Environmenta l Protectio nAgenc y b y th e Houdr y Divisio no

f Ai r Product s an dChemicals , Inc
. , i nfulfillmen t of Contrac t

No
. 68-02-0255
. Th e content s o f thi s repor t

ar e reproduce d herei na s receive dfro mth e Houdr y Divisio nof Ai r Product s an dChemicals , Inc
. Th e opinions , findings , an dconclusion s expresse dar e thos e o f th e autho r

an dno t necessaril y thos e o

f th e Environmenta l Protectio n Agency
. Mentio no

f compan y o r

produc t name s i s no t

t o b e considere d a s a nendorsemen t

b y th e Environmenta l Protectio nAgency
.

Publicatio nNo
. EPA-450/3-73-006- e

nit ~ _ k -
••I 

## J L 

# - - - - * - H -h-« 4

Plan tEP

A Cod e No . Capacit y - Ton s o f 37 % Formaldehyde/Yr . Rang e i n Productio n - 7. o f Max . Emlaalon at o Atmospher e Strea m
Flo v- Lbs./Hr . Flo vCharacteristic , Continuou s o rIntermitten t i f Intermitten t- Hrs . /Yr . Flo - Composition , Tons/To n o f 377 . Formaldehyd e Methano l o Formaldehyd e Dimcthylethe r Nitroge n= t Oxyge n Carbo nDioxid e Carbo nMonoxid e Wate r Dovther

m Catalys t Dus t Ven t Stack s Numbe r Heigh t - Fee t Diamete r - Inche s Exi t Ca s Temp . - F ° . SCFM/Stac k Emissio nContro l Device s ' Incinerato r Scrubbe r Othe r Analysi s Dat ao rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f Analysi s ° Odo rProble m Suamer y o f

Ai rPollutant s (T/ T o f 37 2 HCHO

) Hydrocarbon s Aerosol s & Particulate s NO , 

## so , C O Typ e o f Operatio n - Recycl e iR ) o rNon-Recycl e (N.R. ) TABL E FM- 5 ;.:-.';; . NATIONA

L EMISSION S INVENTOR Y FO R FORMALDEHYD

E PRODUCTIO

N ".' VIA " ^ . - M

e Absorbe rVen t

5 > No tSpecifie d Continuou s



## ' + + + LXt U

14 - OXI D

• 2 30,00 0 0 t

-CA I

Dovther m
No t Spe c ALY5 T

Ven t
lfle d

< ? PROCESS . . - p« g „

• • -. . 14-1 6 ' „ 20,00 0 ' • " • 18. 5

. . ^ Absorbe rVen tTan kVen t

} 027,61 9 "Ver y Smell " Continuou s

|.0163 0 + o f 2 1 4 50 .



## . " Compresso rExhaus t
No tSpecifie d Intermittent ? -1 7 90 0

. 3 Absorbe rVen t
No tSpecifie d Continuou s

Y-e a 

## 1 4 9 U l
Non e

Neve r Non e

Desig n Value s N o Canno tb e determine d 4.2918 0 1.0772 0 

## ) .0182 0 .1203 0
Ye s 1 6 0 2 4 70-9 5 6000-800 0 Ye s d 49. 5 6 <.15 0 Unknow n

Infrequen t A tStac k CL C an d Desig n Ye s Neve r

N.R . > .0163 0 

## +

+ N.R . 

## + +

Ye s 1 2 0 8 21 0 Non e

Neve r
N o Ye s 1 7 3 3 0 50-5 5 Ye s (FM-l )
W a tElim . Neve r

Canno tb e determine dPlan tEP

A Cod e No . Capacit y - Ton s o f iTX Formaldehyde/Yr . Rang e I n Productio n - I o f Max . Emission s t o Atmospher e Strea m • a TABL E FM- 5 NATIuWC . EMISSIQN S INVENTOR Y FO R FORMALDEHYD E PRODUCTIO N

VI A MIXE D OXID E CATALYS

T PROCESS Pag e 2 o f 2 14-1 9 49,50 0 0 Absorbe rVen t Tan kVen t 14-2 1 and/o r14-2 3 50,00 0 @ 0 

## ( D

Absorbe rVen t Dovther m Ven t Converte r Cat . Actlv . Ven t 14-2 2 50.00 0 0 Absorbe rVen t
Flo v - Lbs./Hr . Flov Characteristic , Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr . Flo v Composition , Tons/To no f 37 % Formaldehyd e Methano l Formaldehyd e Dlmethylethe r Nitroge n Oxyge n

. Carbo n Dioxid e Carbo n Monoxid e Wate r Dovther m Catalys tDus t Ven tStack s Nu_be r Heigh t• Fee t Diamete r- Inche s Exi tGa s Temp . - F ° SCFM/Stac k Emissio n Contro l Device s Incinerato r Scrubbe r Othe r Analysi s Dat e o r Frequenc y o f Samplin g Sampl e Ta pLocatio n Typ e o f Analysi s Odo r Problem Summar y

o f Ai r Pollutant s (T/ T o f iJX HCHO ) Hydrocarbon s Aerosol s & Particulate s NO , SO , C O Typ e o f Operatio n- Recycl e (R ) or Non-Recycl e (N.R. ) 73,07 8 Contlnuou s
.0005 5 .0002 6 .0069 2 ) 6.2141 3 

## > 0.0 7 Continuou s

K. 0000 1

1 0 time s (1969 ) A t Stac k 

### GL C N o Neve r Calc' d 

### N o .0077 3

l.R . 17.58 3 Continuou s
.0016 7 .0004 7 .0008 4 1.3508 1 .10*1 2 .0017 7 .0122 8 Continuou s



### Ye s 

### 1 8 5 2 4 8 0 16,00 0 Ye s (FM-2 ) 

### Ye s 

### 1 8 4 10 0 1. 7 Ye s (FM-3 ) 

### Ye s 

### 1 7 4 3 0 8 0 393 2 Non e

Neve r Calc'd . N o .0029 8



## +
.0122 8 R Ye a

1 4 0 1 8 0 "Nil " Non e

Neve r


### N o Intermitten t

+ + + T R

+ Ye s 1 4 2 1 4 100-70 0 800 0 Non e

Neve r N o 14,00 0 Continuou s
.0022 4 .0011 2 .9962 4 .0772 8 .0216 0 .0375 2
Ye s 1 1 0 1 4 9 ? 319 9 Ye s (FM-4 )
Demlste r Twic e Dat e e xdesig n N o .0033 6

.0216 0
( 1 ) Questionnair e rasponsa s fro m plant s 14-2 1 an d 14-2 3 ver e Identical .



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