Name:

Title:

Company:

Sign Date:

Name:

Title:

Company:

Sign Date:

Permitted Facility Representative / Date Testing Company Representative / Date

Dunkirk 4

Final Test Report 

for

/ /

Based on information and belief formed 

after reasonable inquiry, I certify that the 

statements and information in this test 

report are true, accurate, and complete.

I have reviewed all testing details and 

results in this test report and hereby 

certify that the test report is authentic 

and accurate.

Wednesday, February 09, 2011 Page 1 of 20
Dunkirk 4

Facility Information:

Dunkirk Steam Generating Station

106 Point Drive North

Dunkirk NY 14048

Contact: Bob Brombos

Phone: 716-673-6343

Fax:

Email: bob.brombos@nrgenergy.com

Testing Company:

Eagle Mountain Scientific, Inc.

8905 Autumn Oaks Drive

Suite 2

Rockford MN 55373

Contact:Brian Durkop

Phone: 763-477-4462

Fax: 763-477-5991

Email: bdurkop@eagle-msi.com

Air Permit Number:

2554

Permitted Source ID/Name:

CS003 Unit 4

Permitted Maximum Process Rate:

192 MW

Max. Normal Operation Process Rate:

192 MW

Target Process Test Rate

184 MW

Description of the source (including control equipment). Please see the attachments for source or

 process flow diagram:

Dunkirk Power Station is located in the city of Dunkirk, New York on the east shore of Lake Erie. The power plant 

has a total of four pulverized bituminous coal-fired steam generators. Unit 4 is rated at 192 MW.

Generating Units 4 is a coal-fired CE Balanced Draft Furnace. The unit is designed to produce 1,470,000 #/hr of 

steam at 2,400 psig with cross compound turbines. The unit is base loaded and shares a common stack. The unit is 

comprised of two furnaces; a superheat furnace and a reheat furnace. The furnaces share a common drum and are 

coupled with two-forced draft and two induced draft fans each. Each forced draft (FD) fan discharges to a 

regenerative air heater that exhausts to the secondary air ducts. The FD fan discharges, for each unit, are cross-tied. 

The flue gas from unit 4 enters breaching that leads to the newly installed baghouse (99% removal efficiency). Stack 

3 is 310 feet high and is constructed of reinforced concrete with an acid resistant brick liner.

The unit is equipped with a fabric filter baghouse combined with Trona injection and Activated Carbon Injection.

Industry/SCC/NAIS: 221112

Sampling Location Information:

Test Parameter Information:

AFS #: 3601300006 FRS #: 110000326460

SCC / Description:10100221 External Combustion Boilers - Electric Generation - Bituminous/Subbituminous 

Coal - Pulverized Coal: Wet Bottom (Subbituminous Coal) 

The following state and federal regulations that apply to the proposed testing:

Location

Round

Duct

Diam.

Distance from 

upstream dist.

Distance from

downstream dist.

Number of

Traverse Ports

Equiv. 

Diam

Min.Travers 

Points

Rect. Duct 

Length /Width

Stack Exit 220 612 1565 4 0 0 0 12

Target

Parameter 

Test

Method

Number of

Test Runs

Test Run

Duration

Sample 

Location Points Comments

Wednesday, February 09, 2011 Page 2 of 20
Dunkirk 4

Stack Exit Naphthalene** SW0010 3 120 0

2-

Methylnaphthalene

Stack Exit SW0010 3 120 0

Stack Exit Acenaphthylene** SW0010 3 120 0

Stack Exit Acenaphthene** SW0010 3 120 0

Stack Exit Fluorene** SW0010 3 120 0

Stack Exit Phenanthrene** SW0010 3 120 0

Stack Exit Anthracene** SW0010 3 120 0

Stack Exit Fluoranthene** SW0010 3 120 0

Stack Exit Pyrene** SW0010 3 120 0

Benzo(a)Anthracen

e*

Stack Exit SW0010 3 120 0

Stack Exit Chrysene* SW0010 3 120 0

Benzo(b)Fluoranth

ene*

Stack Exit SW0010 3 120 0

Benzo(k)Fluoranth

ene*

Stack Exit SW0010 3 120 0

Stack Exit Benzo(e)Pyrene SW0010 3 120 0

Stack Exit Benzo(a)Pyrene* SW0010 3 120 0

Stack Exit Perylene SW0010 3 120 0

Indeno(1,2,3-

cd)Pyrene*

Stack Exit SW0010 3 120 0

Dibenzo(a,h)Anthr

acene*

Stack Exit SW0010 3 120 0

Benzo(ghi)Perylen

e**

Stack Exit SW0010 3 120 0

Stack Exit Carbon Monoxide Method 10 3 180 0

Stack Exit Formaldehyde Method 0011 3 120 0

Total organic 

compounds (TOC) 

as Propane

Stack Exit Method 25A 3 120 0

Stack Exit Hydrogen Chloride Method 26 3 180 0

Stack Exit Hydrogen Fluoride Method 26 3 180 0

Organic 

Condensible 

Particulate

Stack Exit OTM - 27/28 3 240 0

Inorganic 

(Aqueous) 

Condensible Part.

Stack Exit OTM - 27/28 3 240 0

Filterable 

Particulate

Stack Exit OTM - 27/28 3 240 0

Stack Exit Total PM2.5 OTM - 27/28 3 240 0

Stack Exit Total Particulate OTM - 27/28 3 240 0

Stack Exit Filterable PM2.5 OTM - 27/28 3 240 0

Stack Exit Arsenic Method 29 3 240 0

Stack Exit Magnesium Method 29 3 240 0

Stack Exit Manganese Method 29 3 240 0

Stack Exit Nickel Method 29 3 240 0

Stack Exit Selenium Method 29 3 240 0

Filterable 

Particulate

Stack Exit Method 29 3 240 0

Stack Exit Chromium Method 29 3 240 0

Stack Exit Beryllium Method 29 3 240 0

Stack Exit Lead Method 29 3 240 0

Wednesday, February 09, 2011 Page 3 of 20
Dunkirk 4

The following describes any modifications and/or deviations to the applicable test 

methods. If alternative methods were requested, see the attachments for documentation 

of request AND approval, including dates.

None

Stack Exit Antimony Method 29 3 240 0

Stack Exit Cadmium Method 29 3 240 0

Stack Exit Co2 Method 3A CO2 3 480 0

Stack Exit Co2 Method 3A CO2 3 240 0

Stack Exit Co2 Method 3A CO2 3 120 0

Stack Exit O2 Method 3A O2 3 120 0

Stack Exit O2 Method 3A O2 3 240 0

Stack Exit O2 Method 3A O2 3 480 0

Filterable 

Particulate

Stack Exit Method 5/OTM-28 3 240 0

Inorganic 

(Aqueous) 

Condensible Part.

Stack Exit Method 5/OTM-28 3 240 0

Stack Exit Total Particulate Method 5/OTM-28 3 240 0

Organic 

Condensible 

Particulate

Stack Exit Method 5/OTM-28 3 240 0

Stack Exit Sulfur Dioxide Method 6C 3 180 0

Nitrogen oxides 

(NOx)

Stack Exit Method 7E 3 180 0

Wednesday, February 09, 2011 Page 4 of 20
Dunkirk 4

Sampling / Stack Data Results Summary

Location Stack Exit - Method 0011

Average

Run Number 1 2 3 

Test Date 4/22/10 4/22/10 4/22/10 

Run Start Time 9:07:00 AM 2:33:00 PM 5:28:00 PM 

Run Finish Time 1:22:00 PM 4:40:00 PM 7:36:00 PM 

Net Run Time, minutes 120 120 120 

Dry Gas Meter Volume Sampled, dscf 105.455 87.498 87.796 93.583

Moisture Content of Stack Gas, % 9.54 9.33 9.33 9.400

Carbon Dioxide, % 12.2 12.4 12.4 12.333

Oxygen, % 7.7 7.4 7.4 7.500

Average Stack Gas Temperature, °F 277.26 276.93 278.61 277.600

Dry Volumetric Flow Rate, dry scfm 433,419.6 433,814.6 432,827.9 433,354.033

Actual Wet Volumetric Flue Gas Flow Rate, acfm 686,456.2 684,713.9 684,713.9 685,294.667

Percent Isokinetic of Sampling Rate, % 101.5 101.6 102.2 101.767

F-Factor, dscfm/MMBtu @ %O2 9424 9546 9546 9,505.333

Fw 0 0 0 0.000

Fc 0 0 0 0.000

Location Stack Exit - Method 26

Average

Run Number

Test Date

Run Start Time

Run Finish Time

Net Run Time, minutes

Dry Gas Meter Volume Sampled, dscf #Num!

Moisture Content of Stack Gas, % #Num!

Carbon Dioxide, % #Num!

Oxygen, % #Num!

Average Stack Gas Temperature, °F #Num!

Dry Volumetric Flow Rate, dry scfm #Num!

Actual Wet Volumetric Flue Gas Flow Rate, acfm #Num!

Percent Isokinetic of Sampling Rate, % #Num!

F-Factor, dscfm/MMBtu @ %O2 #Num!

Fw #Num!

Fc #Num!

Wednesday, February 09, 2011 Page 5 of 20
Dunkirk 4

Emissions Summary

Location: Stack Exit - Method 10

Compound: Carbon Monoxide

Average

Run 1 2 3 

Elb/hr 1.58E+01 1.53E+01 1.56E+01 15.567

lb/mmBtuO2 8.85E-03 8.29E-03 8.64E-03 0.009

ppm 9.13E+00 8.75E+00 8.93E+00 8.937

ppm@7%O2 8.21E+00 7.69E+00 8.02E+00 7.973

Location: Stack Exit - Method 25A

Compound: Total organic compounds (TOC) as 

Average

Run 1 2 3 

Elb/hr 2.51E-01 9.55E-02 4.12E-01 0.253

lb/mmBtuO2 1.41E-04 5.16E-05 2.28E-04 0.000

ppm 9.24E-02 3.46E-02 1.50E-01 0.092

ppm@7%O2 8.31E-02 3.04E-02 1.35E-01 0.083

Wednesday, February 09, 2011 Page 6 of 20
Dunkirk 4

Process Run Data

Run Name Value UOM Comments

Target

Value

1 Opacity 2.6 % 0

1 Flue Gas Temp 251.3 °F

1 sulfur Dioxide 157 ppm 0

1 Nitrogen oxides 0.1508 lb/mmBtu 0

1 Co2 11.6 % 0

1 Stack Flow 3E+07 wscfh 0

1 Heat Input 1752.7 mmBtu/hr 0

1 Load 178 MW 0

2 Opacity 2.5 % 0

2 Flue Gas Temp 256.1 °F

2 sulfur Dioxide 159.3 ppm 0

2 Nitrogen oxides 0.1535 lb/mmBtu 0

2 Co2 11.6 % 0

2 Stack Flow 3E+07 wscfh 0

2 Heat Input 1749.7 mmBtu/hr 0

2 Load 178.3 MW 0

3 Opacity 2.4 % 0

3 Flue Gas Temp 257.1 °F

3 sulfur Dioxide 161.4 ppm 0

3 Nitrogen oxides 0.1454 lb/mmBtu 0

3 Co2 11.6 % 0

3 Stack Flow 2E+07 wscfh 0

3 Heat Input 1500 mmBtu/hr 0

3 Load 152.6 MW 0

4 Opacity 2.8 % 0

4 Flue Gas Temp 266.5 °F

4 sulfur Dioxide 163.9 ppm 0

4 Nitrogen oxides 0.1576 lb/mmBtu 0

4 Co2 11.4 % 0

4 Stack Flow 3E+07 wscfh 0

4 Heat Input 1720.1 mmBtu/hr 0

4 Load 178.5 MW 0

5 Opacity 2.5 % 0

Wednesday, February 09, 2011 Page 7 of 20
Dunkirk 4

5 Flue Gas Temp 269.3 °F

5 sulfur Dioxide 167.8 ppm 0

5 Nitrogen oxides 0.1579 lb/mmBtu 0

5 Co2 11.5 % 0

5 Stack Flow 3E+07 wscfh 0

5 Heat Input 1722.4 mmBtu/hr 0

5 Load 178.1 MW 0

6 Opacity 2.6 % 0

6 Flue Gas Temp 272.6 °F

6 sulfur Dioxide 166.8 ppm 0

6 Nitrogen oxides 0.1547 lb/mmBtu 0

6 Co2 11.6 % 0

6 Stack Flow 3E+07 wscfh 0

6 Heat Input 1718 mmBtu/hr 0

6 Load 177.7 MW 0

7 Opacity 2.8 % 0

7 Flue Gas Temp 269.3 °F

7 sulfur Dioxide 164.7 ppm 0

7 Nitrogen oxides 0.1564 lb/mmBtu 0

7 Co2 11.5 % 0

7 Stack Flow 3E+07 wscfh 0

7 Heat Input 1729.8 mmBtu/hr 0

7 Load 178.1 MW 0

8 Opacity 2.4 % 0

8 Flue Gas Temp 270 °F

8 sulfur Dioxide 167.9 ppm 0

8 Nitrogen oxides 0.1543 lb/mmBtu 0

8 Co2 11.6 % 0

8 Stack Flow 3E+07 wscfh 0

8 Heat Input 1727.8 mmBtu/hr 0

8 Load 178.6 MW 0

9 Opacity 2.6 % 0

9 Flue Gas Temp 272.4 °F

9 sulfur Dioxide 166.5 ppm 0

9 Nitrogen oxides 0.1545 lb/mmBtu 0

9 Co2 11.6 % 0

Wednesday, February 09, 2011 Page 8 of 20
Dunkirk 4

APCD Run Data

9 Stack Flow 3E+07 wscfh 0

9 Heat Input 1717 mmBtu/hr 0

9 Load 177.5 MW 0

Run Name Value UOM Comments

Target

Value

1 FABRIC FILTER 1 3.96 Delta P 5

2 FABRIC FILTER 1 4.34 Delta P 5

3 FABRIC FILTER 1 4.12 Delta P 5

4 FABRIC FILTER 1 4.11 Delta P 5

5 FABRIC FILTER 1 3.75 Delta P 5

6 FABRIC FILTER 1 4.53 Delta P 5

7 FABRIC FILTER 1 3.68 Delta P 5

8 FABRIC FILTER 1 2.91 Delta P 5

9 FABRIC FILTER 1 4.64 Delta P 5

1 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

2 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

3 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

4 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

5 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

6 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

7 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

8 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

9 ACTIVATED CARBON ADSORPTION 0 lbs/hr 0

1 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

2 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

3 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

4 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

5 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

6 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

7 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

8 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

9 ALKALINE FLY ASH SCRUBBING 0 lbs/hr 0

1 FABRIC FILTER 2 3.88 Delta P 0

2 FABRIC FILTER 2 4.76 Delta P 0

3 FABRIC FILTER 2 4.04 Delta P 0

Wednesday, February 09, 2011 Page 9 of 20
Dunkirk 4

Process Lab Run Data

4 FABRIC FILTER 2 4.07 Delta P 0

5 FABRIC FILTER 2 3.64 Delta P 0

6 FABRIC FILTER 2 4.33 Delta P 0

7 FABRIC FILTER 2 3.49 Delta P 0

8 FABRIC FILTER 2 2.83 Delta P 0

9 FABRIC FILTER 2 4.44 Delta P 0

Run Name Value UOM Comments

1 Moister As Received 27.8 %

2 Moister As Received 27.9 %

3 Moister As Received 27.4 %

1 Ash As Received 4.75 %

2 Ash As Received 4.62 %

3 Ash As Received 4.88 %

1 Carbon As Received 48.8 %

2 Carbon As Received 49.5 %

3 Carbon As Received 49.5 %

1 Hydrogen (Excl. H in Moister) As Received 3.21 %

2 Hydrogen (Excl. H in Moister) As Received 2.96 %

3 Hydrogen (Excl. H in Moister) As Received 3.33 %

1 Hydrogen (Incl. H in Moister) As Received 6.32 %

2 Hydrogen (Incl. H in Moister) As Received 6.08 %

3 Hydrogen (Incl. H in Moister) As Received 6.4 %

1 Nitrogen As Received 0.84 %

2 Nitrogen As Received 0.89 %

3 Nitrogen As Received 0.83 %

1 Oxygen (Excl. O in Moister) As Received 14.4 %

2 Oxygen (Excl. O in Moister) As Received 14 %

3 Oxygen (Excl. O in Moister) As Received 13.8 %

1 Oxygen (Incl. O in Moister) As Received 39 %

2 Oxygen (Incl. O in Moister) As Received 38.7 %

3 Oxygen (Incl. O in Moister) As Received 38.2 %

1 Fixed Carbon As Received 34.1 %

2 Fixed Carbon As Received 35.3 %

3 Fixed Carbon As Received 33.1 %

1 Heating Value As Received 8500 Btu/lb

2 Heating Value As Received 8530 Btu/lb

3 Heating Value As Received 8570 Btu/lb

1 Sulfur As Received 0.21 %

2 Sulfur As Received 0.21 %

Wednesday, February 09, 2011 Page 10 of 20
Dunkirk 4

3 Sulfur As Received 0.22 %

1 Volatile Matter As Received 33.4 %

2 Volatile Matter As Received 32.2 %

3 Volatile Matter As Received 34.6 %

1 Ash Dry Basis 6.58 %

2 Ash Dry Basis 6.41 %

3 Ash Dry Basis 6.72 %

1 Carbo Dry Basis 67.6 %

2 Carbo Dry Basis 68.7 %

3 Carbo Dry Basis 68.2 %

1 Hydrogen (Excl. H in Moister) Dry Basis 4.45 %

2 Hydrogen (Excl. H in Moister) Dry Basis 4.11 %

3 Hydrogen (Excl. H in Moister) Dry Basis 4.59 %

1 Nitrogen Dry Basis 1.16 %

2 Nitrogen Dry Basis 1.23 %

3 Nitrogen Dry Basis 1.14 %

1 Oxygen (Excl. O in Moister) Dry Basis 19.9 %

2 Oxygen (Excl. O in Moister) Dry Basis 19.4 %

3 Oxygen (Excl. O in Moister) Dry Basis 19 %

1 Fixed Carbon Dry Basis 47.2 %

2 Fixed Carbon Dry Basis 49 %

3 Fixed Carbon Dry Basis 45.6 %

1 Heating Value Dry Basis 11770 Btu/lb

2 Heating Value Dry Basis 11830 Btu/lb

3 Heating Value Dry Basis 11800 Btu/lb

1 Sulfur Dry Basis 0.29 %

2 Sulfur Dry Basis 0.29 %

3 Sulfur Dry Basis 0.3 %

1 Volatile Matter Dry Basis 46.3 %

2 Volatile Matter Dry Basis 44.7 %

3 Volatile Matter Dry Basis 47.7 %

4 Moister As Received 28.3 %

4 Ash As Received 4.73 %

4 Carbon As Received 49 %

4 Hydrogen (Excl. H in Moister) As Received 3.39 %

4 Hydrogen (Incl. H in Moister) As Received 6.56 %

4 Nitrogen As Received 0.83 %

4 Oxygen (Excl. O in Moister) As Received 13.5 %

4 Oxygen (Incl. O in Moister) As Received 38.6 %

4 Fixed Carbon As Received 34.1 %

4 Heating Value As Received 8520 Btu/lb

4 Sulfur As Received 0.22 %

4 Volatile Matter As Received 32.8 %

Wednesday, February 09, 2011 Page 11 of 20
Dunkirk 4

4 Ash Dry Basis 6.6 %

4 Carbo Dry Basis 68.3 %

4 Hydrogen (Excl. H in Moister) Dry Basis 4.73 %

4 Nitrogen Dry Basis 1.16 %

4 Oxygen (Excl. O in Moister) Dry Basis 18.8 %

4 Fixed Carbon Dry Basis 47.6 %

4 Heating Value Dry Basis 11880 Btu/lb

4 Sulfur Dry Basis 0.31 %

4 Volatile Matter Dry Basis 45.7 %

5 Moister As Received 27.9 %

5 Ash As Received 4.62 %

5 Carbon As Received 49.5 %

5 Hydrogen (Excl. H in Moister) As Received 2.96 %

5 Hydrogen (Incl. H in Moister) As Received 6.08 %

5 Nitrogen As Received 0.89 %

5 Oxygen (Excl. O in Moister) As Received 14 %

5 Oxygen (Incl. O in Moister) As Received 38.7 %

5 Fixed Carbon As Received 35.3 %

5 Heating Value As Received 8530 Btu/lb

5 Sulfur As Received 0.21 %

5 Volatile Matter As Received 32.2 %

5 Ash Dry Basis 6.41 %

5 Carbo Dry Basis 68.7 %

5 Hydrogen (Excl. H in Moister) Dry Basis 4.11 %

5 Nitrogen Dry Basis 1.23 %

5 Oxygen (Excl. O in Moister) Dry Basis 19.4 %

5 Fixed Carbon Dry Basis 49 %

5 Heating Value Dry Basis 11830 Btu/lb

5 Sulfur Dry Basis 0.29 %

5 Volatile Matter Dry Basis 44.7 %

6 Moister As Received 27.4 %

6 Ash As Received 4.88 %

6 Carbon As Received 49.5 %

6 Hydrogen (Excl. H in Moister) As Received 3.33 %

6 Hydrogen (Incl. H in Moister) As Received 6.4 %

6 Nitrogen As Received 0.83 %

6 Oxygen (Excl. O in Moister) As Received 13.8 %

6 Oxygen (Incl. O in Moister) As Received 38.2 %

6 Fixed Carbon As Received 33.1 %

6 Heating Value As Received 8570 Btu/lb

6 Sulfur As Received 0.22 %

6 Volatile Matter As Received 34.6 %

6 Ash Dry Basis 6.72 %

Wednesday, February 09, 2011 Page 12 of 20
Dunkirk 4

6 Carbo Dry Basis 68.2 %

6 Hydrogen (Excl. H in Moister) Dry Basis 4.59 %

6 Nitrogen Dry Basis 1.14 %

6 Oxygen (Excl. O in Moister) Dry Basis 19 %

6 Fixed Carbon Dry Basis 45.6 %

6 Heating Value Dry Basis 11800 Btu/lb

6 Sulfur Dry Basis 0.3 %

6 Volatile Matter Dry Basis 47.7 %

7 Moister As Received 28.3 %

7 Ash As Received 4.73 %

7 Carbon As Received 49 %

7 Hydrogen (Excl. H in Moister) As Received 3.39 %

7 Hydrogen (Incl. H in Moister) As Received 6.56 %

7 Nitrogen As Received 0.83 %

7 Oxygen (Excl. O in Moister) As Received 13.5 %

7 Oxygen (Incl. O in Moister) As Received 38.6 %

7 Fixed Carbon As Received 34.1 %

7 Heating Value As Received 8520 Btu/lb

7 Sulfur As Received 0.22 %

7 Volatile Matter As Received 32.8 %

7 Ash Dry Basis 6.6 %

7 Carbo Dry Basis 68.3 %

7 Hydrogen (Excl. H in Moister) Dry Basis 4.73 %

7 Nitrogen Dry Basis 1.16 %

7 Oxygen (Excl. O in Moister) Dry Basis 18.8 %

7 Fixed Carbon Dry Basis 47.6 %

7 Heating Value Dry Basis 11880 Btu/lb

7 Sulfur Dry Basis 0.31 %

7 Volatile Matter Dry Basis 45.7 %

8 Moister As Received 0 %

8 Ash As Received 0 %

8 Carbon As Received 0 %

8 Hydrogen (Excl. H in Moister) As Received 0 %

8 Hydrogen (Incl. H in Moister) As Received 0 %

8 Nitrogen As Received 0 %

8 Oxygen (Excl. O in Moister) As Received 0 %

8 Oxygen (Incl. O in Moister) As Received 0 %

8 Fixed Carbon As Received 0 %

8 Heating Value As Received 0 Btu/lb

8 Sulfur As Received 0 %

8 Volatile Matter As Received 0 %

8 Ash Dry Basis 0 %

8 Carbo Dry Basis 0 %

Wednesday, February 09, 2011 Page 13 of 20
Dunkirk 4

8 Hydrogen (Excl. H in Moister) Dry Basis 0 %

8 Nitrogen Dry Basis 0 %

8 Oxygen (Excl. O in Moister) Dry Basis 0 %

8 Fixed Carbon Dry Basis 0 %

8 Heating Value Dry Basis 0 Btu/lb

8 Sulfur Dry Basis 0 %

8 Volatile Matter Dry Basis 0 %

9 Moister As Received 0 %

9 Ash As Received 0 %

9 Carbon As Received 0 %

9 Hydrogen (Excl. H in Moister) As Received 0 %

9 Hydrogen (Incl. H in Moister) As Received 0 %

9 Nitrogen As Received 0 %

9 Oxygen (Excl. O in Moister) As Received 0 %

9 Oxygen (Incl. O in Moister) As Received 0 %

9 Fixed Carbon As Received 0 %

9 Heating Value As Received 0 Btu/lb

9 Sulfur As Received 0 %

9 Volatile Matter As Received 0 %

9 Ash Dry Basis 0 %

9 Carbo Dry Basis 0 %

9 Hydrogen (Excl. H in Moister) Dry Basis 0 %

9 Nitrogen Dry Basis 0 %

9 Oxygen (Excl. O in Moister) Dry Basis 0 %

9 Fixed Carbon Dry Basis 0 %

9 Heating Value Dry Basis 0 Btu/lb

9 Sulfur Dry Basis 0 %

9 Volatile Matter Dry Basis 0 %

1 Phosphorus 10 mg/Kg

1 Antimony 3 mg/Kg

1 Arsenic 2 mg/Kg

1 Beryllium 1 mg/Kg

1 Cadmium 1 mg/Kg

1 Chromium 4.82 mg/Kg

1 Cobalt 1.57 mg/Kg

1 Lead 2.77 mg/Kg

1 Manganese 9.29 mg/Kg

1 Nickel 2.59 mg/Kg

1 Selenium 2 mg/Kg

10 Moister As Received 28.1 %

10 Ash As Received 4.75 %

10 Carbon As Received 49.4 %

10 Hydrogen (Excl. H in Moister) As Received 3.32 %

Wednesday, February 09, 2011 Page 14 of 20
Dunkirk 4

10 Hydrogen (Incl. H in Moister) As Received 6.47 %

10 Nitrogen As Received 0.83 %

10 Oxygen (Excl. O in Moister) As Received 13.5 %

10 Oxygen (Incl. O in Moister) As Received 38.4 %

10 Fixed Carbon As Received 35 %

10 Heating Value As Received 8470 Btu/lb

10 Sulfur As Received 0.21 %

10 Volatile Matter As Received 32.2 %

10 Ash Dry Basis 6.61 %

10 Carbo Dry Basis 68.7 %

10 Hydrogen (Excl. H in Moister) Dry Basis 4.62 %

10 Nitrogen Dry Basis 1.15 %

10 Oxygen (Excl. O in Moister) Dry Basis 18.8 %

10 Fixed Carbon Dry Basis 48.7 %

10 Heating Value Dry Basis 11780 Btu/lb

10 Sulfur Dry Basis 0.29 %

10 Volatile Matter Dry Basis 44.8 %

10 Phosphorus 10 mg/Kg

10 Antimony 3 mg/Kg

10 Arsenic 2 mg/Kg

10 Beryllium 1 mg/Kg

10 Cadmium 1 mg/Kg

10 Chromium 5.34 mg/Kg

10 Cobalt 1.46 mg/Kg

10 Lead 2.72 mg/Kg

10 Manganese 9.8 mg/Kg

10 Nickel 2.53 mg/Kg

10 Selenium 2 mg/Kg

11 Moister As Received 27.7 %

11 Ash As Received 4.96 %

11 Carbon As Received 49.2 %

11 Hydrogen (Excl. H in Moister) As Received 2.93 %

11 Hydrogen (Incl. H in Moister) As Received 6.03 %

11 Nitrogen As Received 0.86 %

11 Oxygen (Excl. O in Moister) As Received 14.2 %

11 Oxygen (Incl. O in Moister) As Received 38.8 %

11 Fixed Carbon As Received 33.2 %

11 Heating Value As Received 8520 Btu/lb

11 Sulfur As Received 0.2 %

11 Volatile Matter As Received 34.2 %

11 Ash Dry Basis 6.86 %

11 Carbo Dry Basis 68 %

11 Hydrogen (Excl. H in Moister) Dry Basis 4.05 %

Wednesday, February 09, 2011 Page 15 of 20
Dunkirk 4

11 Nitrogen Dry Basis 1.19 %

11 Oxygen (Excl. O in Moister) Dry Basis 19.6 %

11 Fixed Carbon Dry Basis 45.9 %

11 Heating Value Dry Basis 11780 Btu/lb

11 Sulfur Dry Basis 0.28 %

11 Volatile Matter Dry Basis 47.3 %

11 Phosphorus 10 mg/Kg

11 Antimony 3 mg/Kg

11 Arsenic 2 mg/Kg

11 Beryllium 1 mg/Kg

11 Cadmium 1 mg/Kg

11 Chromium 3.99 mg/Kg

11 Cobalt 1.22 mg/Kg

11 Lead 3.88 mg/Kg

11 Manganese 9.04 mg/Kg

11 Nickel 2.34 mg/Kg

11 Selenium 2 mg/Kg

12 Moister As Received 28.1 %

12 Ash As Received 4.75 %

12 Carbon As Received 49.4 %

12 Hydrogen (Excl. H in Moister) As Received 3.32 %

12 Hydrogen (Incl. H in Moister) As Received 6.47 %

12 Nitrogen As Received 0.83 %

12 Oxygen (Excl. O in Moister) As Received 13.5 %

12 Oxygen (Incl. O in Moister) As Received 38.4 %

12 Fixed Carbon As Received 35 %

12 Heating Value As Received 8470 Btu/lb

12 Sulfur As Received 0.21 %

12 Volatile Matter As Received 32.2 %

12 Ash Dry Basis 6.61 %

12 Carbo Dry Basis 68.7 %

12 Hydrogen (Excl. H in Moister) Dry Basis 4.62 %

12 Nitrogen Dry Basis 1.15 %

12 Oxygen (Excl. O in Moister) Dry Basis 18.8 %

12 Fixed Carbon Dry Basis 48.7 %

12 Heating Value Dry Basis 11780 Btu/lb

12 Sulfur Dry Basis 0.29 %

12 Volatile Matter Dry Basis 44.8 %

12 Phosphorus 10 mg/Kg

12 Antimony 3 mg/Kg

12 Arsenic 2 mg/Kg

12 Beryllium 1 mg/Kg

12 Cadmium 1 mg/Kg

Wednesday, February 09, 2011 Page 16 of 20
Dunkirk 4

12 Chromium 5.34 mg/Kg

12 Cobalt 1.46 mg/Kg

12 Lead 2.72 mg/Kg

12 Manganese 9.8 mg/Kg

12 Nickel 2.53 mg/Kg

12 Selenium 2 mg/Kg

1 Mercury 0.185 mg/Kg

13 Moister As Received 28.1 %

13 Ash As Received 4.75 %

13 Carbon As Received 49.4 %

13 Hydrogen (Excl. H in Moister) As Received 3.32 %

13 Hydrogen (Incl. H in Moister) As Received 6.47 %

13 Nitrogen As Received 0.83 %

13 Oxygen (Excl. O in Moister) As Received 13.5 %

13 Oxygen (Incl. O in Moister) As Received 38.4 %

13 Fixed Carbon As Received 35 %

13 Heating Value As Received 8470 Btu/lb

13 Sulfur As Received 0.21 %

13 Volatile Matter As Received 32.2 %

13 Ash Dry Basis 6.61 %

13 Carbo Dry Basis 68.7 %

13 Hydrogen (Excl. H in Moister) Dry Basis 4.62 %

13 Nitrogen Dry Basis 1.15 %

13 Oxygen (Excl. O in Moister) Dry Basis 18.8 %

13 Fixed Carbon Dry Basis 48.7 %

13 Heating Value Dry Basis 11780 Btu/lb

13 Sulfur Dry Basis 0.29 %

13 Volatile Matter Dry Basis 44.8 %

13 Phosphorus 10 mg/Kg

13 Antimony 3 mg/Kg

13 Arsenic 2 mg/Kg

13 Beryllium 1 mg/Kg

13 Cadmium 1 mg/Kg

13 Chromium 5.34 mg/Kg

13 Cobalt 1.46 mg/Kg

13 Lead 2.72 mg/Kg

13 Manganese 9.8 mg/Kg

13 Nickel 2.53 mg/Kg

13 Selenium 2 mg/Kg

13 Mercury 0.056 mg/Kg

14 Moister As Received 27.7 %

14 Ash As Received 4.96 %

14 Carbon As Received 49.2 %

Wednesday, February 09, 2011 Page 17 of 20
Dunkirk 4

14 Hydrogen (Excl. H in Moister) As Received 2.93 %

14 Hydrogen (Incl. H in Moister) As Received 6.03 %

14 Nitrogen As Received 0.86 %

14 Oxygen (Excl. O in Moister) As Received 14.2 %

14 Oxygen (Incl. O in Moister) As Received 38.8 %

14 Fixed Carbon As Received 33.2 %

14 Heating Value As Received 8520 Btu/lb

14 Sulfur As Received 0.2 %

14 Volatile Matter As Received 34.2 %

14 Ash Dry Basis 6.86 %

14 Carbo Dry Basis 68 %

14 Hydrogen (Excl. H in Moister) Dry Basis 4.05 %

14 Nitrogen Dry Basis 1.19 %

14 Oxygen (Excl. O in Moister) Dry Basis 19.6 %

14 Fixed Carbon Dry Basis 45.9 %

14 Heating Value Dry Basis 11780 Btu/lb

14 Sulfur Dry Basis 0.28 %

14 Volatile Matter Dry Basis 47.3 %

14 Phosphorus 10 mg/Kg

14 Antimony 3 mg/Kg

14 Arsenic 2 mg/Kg

14 Beryllium 1 mg/Kg

14 Cadmium 1 mg/Kg

14 Chromium 3.99 mg/Kg

14 Cobalt 1.22 mg/Kg

14 Lead 3.88 mg/Kg

14 Manganese 9.04 mg/Kg

14 Nickel 2.34 mg/Kg

14 Selenium 2 mg/Kg

14 Mercury 0.073 mg/Kg

Wednesday, February 09, 2011 Page 18 of 20
Dunkirk 4

Sampling / Stack Data Results Detail

Location Stack Exit - Method 0011

Average

Run Number 1 2 3 

Test Date 4/22/10 4/22/10 4/22/10 

Run Start Time 9:07:00 AM 2:33:00 PM 5:28:00 PM 

Run Finish Time 1:22:00 PM 4:40:00 PM 7:36:00 PM 

Net Traversing Points 120 120 120 

Net Run Time, minutes 120 120 120 

Nozzle Diameter, inches 0.311 0.283 0.283 0.292

Pitot Tube Coefficient 0.84 0.84 0.84 0.840

Dry Gas Meter Calibration Factor 0.98 0.98 0.98 0.980

Barometric Pressure, inches of Mercury 29.2 29.22 29.22 29.213

Average Orifice Meter Differential, inches H2O 2.77 1.94 1.94 2.217

Dry Gas Meter Volume Sampled, cubic feet 110.347 91.239 91.176 97.587

Average Dry Gas Meter Temperature, °F 72.10 69.51 67.35 69.653

Dry Gas Meter Volume Sampled, dscf 105.455 87.498 87.796 93.583

Total Moisture Liquid collected, g 236.2 191.2 191.9 206.433

Volume of Water Vapor, standard cubic feet 11.12 9.00 9.03 9.717

Moisture Content of Stack Gas, % 9.54 9.33 9.33 9.400

Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000

Dry Mole Fraction 0.9046 0.9067 0.9067 0.906

Carbon Dioxide, % 12.2 12.4 12.4 12.333

Oxygen, % 7.7 7.4 7.4 7.500

Carbon Monoxide & Nitrogen, % 80.1 80.2 80.2 80.167

Fuel Factor 1.08 1.09 1.09 

Dry Molecular Weight, lb/lb-Mole 30.26 30.28 30.28 30.273

Wet Molecular weight, lb/lb-Mole 29.09 29.13 29.13 29.117

Flue Gas Static Pressure, inches of H2O -0.53 -0.53 -0.53 -0.530

Absolute Flue Gas Pressure, inches of Mercury 29.16 29.18 29.18 29.173

Average Stack Gas Temperature, °F 277.26 276.93 278.61 277.600

Average Velocity Head, inches of H2O 0.419 0.418 0.417 0.418

Average Stack Gas Velocity, feet/second 43.34 43.23 43.23 43.267

Stack Cross-Sectional Area, square feet 263.981 263.981 263.981 263.981

Dry Volumetric Flow Rate, dry scfm 433,419.6 433,814.6 432,827.9 433,354.033

Actual Wet Volumetric Flue Gas Flow Rate, acfm 686,456.2 684,713.9 684,713.9 685,294.667

Percent Isokinetic of Sampling Rate, % 101.5 101.6 102.2 101.767

Percent Excess Air, % 57.3 53.7 53.7 54.900

F-Factor, dscfm/MMBtu @ %O2 9424 9546 9546 9,505.333

Round Duct Diameter, inches 220 220 220 

Rectangular Duct Width, inches 0 0 0 

Rectangular Duct Length, inches 0 0 0 

Fw 0 0 0 0.000

Fc 0 0 0 0.000

Wednesday, February 09, 2011 Page 19 of 20
Dunkirk 4

Location Stack Exit - Method 26

Average

Run Number

Test Date

Run Start Time

Run Finish Time

Net Traversing Points

Net Run Time, minutes

Nozzle Diameter, inches #Num!

Pitot Tube Coefficient #Num!

Dry Gas Meter Calibration Factor #Num!

Barometric Pressure, inches of Mercury #Num!

Average Orifice Meter Differential, inches H2O #Num!

Dry Gas Meter Volume Sampled, cubic feet #Num!

Average Dry Gas Meter Temperature, °F #Num!

Dry Gas Meter Volume Sampled, dscf #Num!

Total Moisture Liquid collected, g #Num!

Volume of Water Vapor, standard cubic feet #Num!

Moisture Content of Stack Gas, % #Num!

Moisture Saturation at Stack Gas Temperature, % #Num!

Dry Mole Fraction #Num!

Carbon Dioxide, % #Num!

Oxygen, % #Num!

Carbon Monoxide & Nitrogen, % #Num!

Fuel Factor

Dry Molecular Weight, lb/lb-Mole #Num!

Wet Molecular weight, lb/lb-Mole #Num!

Flue Gas Static Pressure, inches of H2O #Num!

Absolute Flue Gas Pressure, inches of Mercury #Num!

Average Stack Gas Temperature, °F #Num!

Average Velocity Head, inches of H2O #Num!

Average Stack Gas Velocity, feet/second #Num!

Stack Cross-Sectional Area, square feet #Num!

Dry Volumetric Flow Rate, dry scfm #Num!

Actual Wet Volumetric Flue Gas Flow Rate, acfm #Num!

Percent Isokinetic of Sampling Rate, % #Num!

Percent Excess Air, % #Num!

F-Factor, dscfm/MMBtu @ %O2 #Num!

Round Duct Diameter, inches

Rectangular Duct Width, inches

Rectangular Duct Length, inches

Fw #Num!

Fc #Num!

Wednesday, February 09, 2011 Page 20 of 20