Material Safety Data Sheet

1. Chemical product and company identification

Product name CALCINED COKE

MSDS # APPC168

Historic MSDS #: None.

Product use Fuel.

Code APPC168

Supplier BP Products North America Inc.

150 West Warrenville Road

Naperville, Illinois 60563-8460

USA

EMERGENCY HEALTH

INFORMATION:

1 (800) 447-8735

Outside the US: +1 703-527-3887 (CHEMTREC)

EMERGENCY SPILL

INFORMATION:

1 (800) 424-9300 CHEMTREC (USA)

OTHER PRODUCT

INFORMATION

1 (866) 4 BP - MSDS

(866-427-6737 Toll Free - North America)

email: bpcares@bp.com

2. Composition/information on ingredients

Ingredient name CAS # %

Coke, petroleum, calcined 64743-05-1 100

3. Hazards identification

Physical state Solid.

Color Black. Amorphous solid powder or lumps.

Emergency overview

Handling and/or processing of this material may generate a dust which can cause mechanical

irritation of the eyes, skin, nose and throat.

Avoid contact with eyes. Avoid breathing dust. Keep container closed. Use with adequate

ventilation. Wash thoroughly after handling. Heated material can cause thermal burns.

CAUTION!

Routes of entry Dermal contact. Eye contact. Inhalation. Ingestion.

Potential health effects

Eyes Dust may cause mechanical irritation to eye. Particles or fibers may cause slight discomfort similar

to getting dust in the eye.

Skin Dust may cause mechanical irritation. Particles or fibers may cause slight discomfort similar to

rubbing sand against the skin.

Inhalation Dust may cause mechanical irritation. Inhalation: May cause respiratory tract irritation.

Ingestion No significant health hazards identified.

Medical conditions

aggravated by overexposure

None identified.

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See toxicological Information (section 11).

4. First aid measures

Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical

attention if irritation occurs.

Skin contact In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing

and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical

attention if irritation develops.

Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms appear.

Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by

mouth to an unconscious person. If large quantities of this material are swallowed, call a physician

immediately.

5. Fire-fighting measures

Auto-ignition temperature 850 °C

Flash point >93 °C (Open cup)

Explosion limits 125 g/m3

Flammability of the

product

Products of combustion carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide), sulfur oxides (SO2, SO3 etc.)

Unusual fire/explosion

hazards

This material is not explosive as defined by established regulatory criteria. High dust

concentrations have a potential for combustion or explosion. Fine dust clouds may form explosive

mixtures with air.

Fire-fighting media and

instructions

In case of fire, use water fog, foam, dry chemicals, or carbon dioxide.

Protective clothing (fire) Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full

turnout gear.

May be combustible at high temperature.

Personal precautions

Personal protection in

case of a large spill

Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable

protective equipment (See Section: "Exposure controls/personal protection"). Follow all fire

fighting procedures (See Section: "Fire-fighting measures").

Goggles, face shield, or other full-face protection potential exists for direct exposure to dust. Full

suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist

BEFORE handling this product.

6. Accidental release measures

If emergency personnel are unavailable, contain spilled material. For small spills add absorbent

(soil may be used in the absence of other suitable materials) scoop up material and place in a

sealed, liquid-proof container for disposal. For large spills dike spilled material or otherwise

contain material to ensure runoff does not reach a waterway. Place spilled material in an

appropriate container for disposal. Avoid contact of spilled material with soil and prevent runoff

entering surface waterways. See Section 13 for Waste Disposal Information.

Environmental

precautions and clean-up

methods

7. Handling and storage

Handling Contact with hot product may cause burns. Avoid contact with eyes. Avoid breathing dust. Use

only with adequate ventilation Avoid the creation of dust when handling and avoid all possible

sources of ignition (spark or flame). To avoid fire or explosion, dissipate static electricity during

transfer by grounding and bonding containers and equipment before transferring material. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment. Wash thoroughly

after handling. When using do not eat, drink or smoke.

Regular periodic self inspection of the skin is recommended, especially those areas subject to

contamination. In the event of any localized changes in appearance or texture of the skin being

noticed, medical advice should be sought without delay.

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Storage Keep container tightly closed. Keep container in a cool, well-ventilated area. Empty containers

may contain harmful, flammable/combustible or explosive residue or vapors. Do not cut, grind, drill,

weld, reuse or dispose of containers unless adequate precautions are taken against these

hazards.

Not suitable Prolonged exposure to elevated temperature.

8. Exposure controls/personal protection

Occupational exposure

limits

Control Measures Provide exhaust ventilation or other engineering controls to keep the relevant airborne

concentrations below their respective occupational exposure limits.

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating,

smoking and using the lavatory and at the end of the working period.

Personal protection

Eyes Goggles, face shield, or other full-face protection if potential exists for direct exposure to dust. Use

dust goggles if high dust concentration is generated.

Skin and body Use of protective clothing is good industrial practice.

Respiratory Use only with adequate ventilation Avoid breathing dust. If ventilation is inadequate, use certified

respirator that will protect against dust/mist. If operating conditions cause high vapor, mist, or dust

concentrations, or the TLV is exceeded, use supplied-air respirator.

CAUTION: The protection provided by air-purifying respirators is limited. Use a positive pressure

air-supplied respirator if there is any potential for an uncontrolled release, if exposure levels are

not known, or if concentrations exceed the protection limits of air-purifying respirator.

Hands Wear gloves that cannot be penetrated by chemicals or oil.

The correct choice of protective gloves depends upon the chemicals being handled, the conditions

of work and use, and the condition of the gloves (even the best chemically resistant glove will

break down after repeated chemical exposures). Most gloves provide only a short time of

protection before they must be discarded and replaced. Because specific work environments and

material handling practices vary, safety procedures should be developed for each intended

application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and

with a full assessment of the working conditions.

Consult your supervisor or S.O.P. for special handling directions

Consult local authorities for acceptable exposure limits.

Coke, petroleum, calcined ACGIH TLV (United States).

TWA: 3 mg/m3, (Respirable.) 8 hour(s). Form: Recommended

TWA: 10 mg/m3, (Inhalable) 8 hour(s). Form: Recommended

OSHA PEL (United States).

TWA: 5 mg/m3, (Respirable.) 8 hour(s). Form: Recommended

TWA: 15 mg/m3, (Inhalable) 8 hour(s). Form: Recommended

Ingredient name Occupational exposure limits

Some states may enforce more stringent exposure limits.

9. Physical and chemical properties

Color Black. Amorphous solid powder or lumps.

Physical state Solid.

Odor Hydrocarbon.

Solubility Insoluble in cold water.

Specific gravity 1.5

Heat of combustion Not available.

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10. Stability and reactivity

The product is stable.

Reactive or incompatible with the following materials: oxidizing materials.

Chlorine

Will not occur.

carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide), sulfur oxides (SO2, SO3 etc.)

Keep away from heat, sparks and flame. Keep away from sources of ignition.

Stability and reactivity

Conditions to avoid

Incompatibility with

various substances

Hazardous decomposition

products

Hazardous polymerization

11. Toxicological information

Chronic toxicity

No component of this product at levels greater than 0.1% is identified as a carcinogen by ACGIH

or the International Agency for Research on Cancer (IARC). No component of this product present

at levels greater than 0.1% is identified as a carcinogen by the U.S. National Toxicology Program

(NTP) or the U.S. Occupational Safety and Health Act (OSHA).

Carcinogenic

effects

Overexposure to dust may cause mechanical irritation. Repeated or prolonged inhalation of dust

may lead to chronic respiratory irritation. Repeated and prolonged inhalation of any respirable dust

may result in changes in lung function.

Other chronic toxicity

data

Acute toxicity Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated

exposure may lead to dermatitis. Dust may cause mechanical irritation.

12. Ecological information

Ecotoxicity

No testing has been performed by the manufacturer.

Mobility Spillages are unlikely to penetrate the soil.

Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment.

Other ecological

information

Unlikely to be harmful to aquatic organisms.

Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer

could also be impaired. This product is lighter than water and will float on the surface.

Persistence/degradability Not readily biodegradable.

13. Disposal considerations

Waste information Avoid contact of spilled material and runoff with soil and surface waterways. Consult an

environmental professional to determine if local, regional or national regulations would classify

spilled or contaminated materials as hazardous waste. Use only approved transporters, recyclers,

treatment, storage or disposal facilities. Dispose of in accordance with all applicable local and

national regulations.

Consult your local or regional authorities.

14. Transport information

Not classified as hazardous for transport (DOT, TDG, IMO/IMDG, IATA/ICAO)

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15. Regulatory information

U.S. Federal regulations US INVENTORY (TSCA): Listed on inventory.

This product is not regulated under Section 302 of SARA and 40 CFR Part 355.

CERCLA Sections 102a/103 Hazardous Substances (40 CFR Part 302.4):: This material is not

regulated under CERCLA Sections 103 and 107.

State regulations

California Prop 65: No products were found

This product does not contain any hazardous ingredients at or above regulated thresholds.

This product does not contain any hazardous ingredients at or above regulated thresholds.

SARA 313

Form R - Reporting

requirements

Supplier notification

SARA 311/312 MSDS distribution - chemical inventory - hazard identification: PETROLEUM

COKE (ARCO): Delayed (Chronic) Health Hazard

Massachusetts

Substances

Massachusetts RTK: None of the components are listed.

New Jersey

Hazardous

Substances

New Jersey Hazardous Substances: None of the components are listed.

Pennsylvania RTK

Hazardous

Substances

Pennsylvania RTK: None of the components are listed.

Inventories AUSTRALIAN INVENTORY (AICS): Listed on inventory.

CANADA INVENTORY (DSL): Listed on inventory.

CHINA INVENTORY (IECS): Not determined.

EC INVENTORY (EINECS/ELINCS): Listed on inventory.

JAPAN INVENTORY (ENCS): Not determined.

KOREA INVENTORY (ECL): Listed on inventory.

PHILIPPINE INVENTORY (PICCS): Not determined.

16. Other information

Label requirements CAUTION!

Handling and/or processing of this material may generate a dust which can cause mechanical

irritation of the eyes, skin, nose and throat.

National Fire

Protection

Association

(U.S.A.)

Health 0

1

1

Fire hazard

Instability

Specific hazard

History

Date of issue 02/22/2007.

Date of previous issue No Previous Validation.

Prepared by Product Stewardship

Notice to reader

HMIS® Rating :

Physical

Hazard

Flammability

Health * 1

1

0

Personal X

protection

Date of issue 02/22/2007.

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NOTICE : This Material Safety Data Sheet is based upon data considered to be accurate at the time of its preparation. Despite our

efforts, it may not be up to date or applicable to the circumstances of any particular case. We are not responsible for any damage or

injury resulting from abnormal use, from any failure to follow appropriate practices or from hazards inherent in the nature of the

product.

Date of issue 02/22/2007.

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Product

name

Product code

Version 1 Format US-COMP Language

APPC168

Build 5.3.1