# OAR Box 1878

Prepped by Charmelle Mathews



# Document

Number: 

# 86)11-1-1 6

Docket Number: 

# A-90-1 9

Printed 11/28/20081:21:24

PM Sheet 86 of 145$60,60 4 precipitatio n bath . Thi s valu e shal l b e use d i n al l case s unles s a n owne r o rop erato r demonstrate s t o th e satisfactio n o f th e Administrato rtha tgreate rnon gaseou s losse s occu ra tth e affecte d fa cility . I n thi s case , th e greate rvalu e ma y b e substitute d i n th e equation . (Approve d by th e Offic e o f Managemen t an d Budge tunde r contro l numbe r2060 - 0069 ) (4 9 P R13661 . Apr . 6 . 1884 ; 4 8 F R16096 . Apr . 27 . 1984 1 160.60 4 Reportin g requirement* . (a ) Th e owne ro roperato ro f a n affecte d facilit y shal l submi ta writte n repor tt o th e Administrato rof th e fol lowing : (1 ) Th e result s o f

th e initia l per formanc e teet ; an d (2 ) Th e result s of

subsequen tper formanc e test s tha tindicat e tha tVO C emission s excee d th e standard s I n | 60.602 . Thes e report s shal l b e sub mitte d quarterl y a t3-mont h interval s afte r th e initia l performanc e test . I f n o exceedance s occu rdurin g a particu la r quarter , a repor tstatin g thi s shal l b e submitte d t o th e Administrato r semiannually . (b ) Solvent-spu n syntheti c fibe rpro ducin g facilitie s exempte d fro m thes e standard s ln I 60.600(a ) (thos e produc in g lea s tha n 50 0 megagram a annually ) shal l repor tt o th e Administrato r withi n 3 0 day s wheneve rextrude d fibe r fo r th e precedin g 1 2 calenda r month s exceed s 60 0 megagrams . (c ) Th e requirement s o f thi s sectio n remai n i n forc e unti l an d unles s EPA , i n delegatin g enforcemen tauthorit y t o a Stat e unde rsectio n 111(c ) of th e Act , approve s reportin g requirement s o r a n alternat e mean s o f complianc e surveillanc e adopte d b y suc h State . I n tha tevent , affecte d source s withi n th e Stat e wil l b e relieve d of th e obligatio n t o compl y wit h thi s section , provide d tha tthe y compl y wit h th e requlre ment s establishe d b y th e State . Non e Thi s regulatio n doe s no tInvolv e a "collectio n o f

Information " a s define d unde r th e Paperwor k Reductio n Ac to f I96 0 (Pub . L . 66-811) . Therefore , th e provision s o f th e Paperwork . Reductio n Ac tappUcabl e t o col lection s o f

Informatio n d o no tappl y t o thi s regulation . 4 0 C KCh

. I (7-1-9 1 Edition ) (Approve d by th e Offic e o f Managemen t an d Budge tunde rcontro l numbe r2060 - 0050 ) (4 9 F R13651 . Apr . 6 . 1984 . a s amende d a t5 5 F R51384 . Dec . 13 . 1990 ] Subpar t III—Standard s o f Perform

anc e fo rVolatil e Organi c Com

. poun d (VOC ) Emission s Fro m th e Syntheti c Organi c Chemica l Man

ufacturin g Industr y (SOCMI ) Ai r Oxidatio n Uni t Processe s Souses : 6 6 F R36922 . Jun e 29 . 1990 . unles s otherwis e noted . 160.61 0 Applicabilit

y an d designatio n o

f affected facility . (a ) Th e provision s o f thi s subpar t appl y t o eac h affecte d facilit y desig nate d i n paragrap h (b ) o f thi s sectio n tha tproduce s an y of th e chemical s liste d i n f

60.61 7 a s a product , co-prod uct , by-product , or intermediate , excep ta s provide d i n paragrap h (c ) o f thi s section . (b ) Th e affecte d facilit y i s an y o f th e followin g fo r whic h construction , modification , o rreconstructio n com mence d afte rOctobe r21 , 1983 : (1 ) Eac h ai r 'oxidatio n reacto r no t dischargin g It s ven tstrea m int o a re cover y system . (2 ) Eac h combinatio n o f a n ai r oxi datio n reacto ran d th e recover y syste m int o whic h Its ven tstrea m i s discharged . (3 ) Eac h combinatio n of tw o o rmor e ai r oxidatio n reactor s an d th e commo n recover y syste m int o whic h thei r ven t stream s ar e discharged . (c ) Eac h affecte d facilit y tha tha s a tota l resourc e effectivenes s (TRE ) inde x valu e greate rtha n 4. 0 I s exemp t fro m al l provision s o f thi s subpar t excep tfo rI S 60.612 . 60.614(f) . 60.615(h) . an d 60.615(1) . [NOTE : Th e Inten to f

thes e standard s I s t o minimiz e th e emission s o f VO C throug h th e applicatio n o f

BDT . Th e numerica l emissio n limit s I n thes e standard * ar e expresse d I n term s o f tota l organi c compound s (TOO . measure d a s TO C minu s methan e an d ethane . Thi s emissio n limi treflect s th e p« r forraanc e o f

BDT. l 

# T

58 6 environmenta l Protectio n Agenc y 160.61 1 Definitions . A s use d i n thi s subpart , al l term s no t define d her e shal l hav e th e meanin g give n the m l n th e Ac tan d i n subpar t A of par t60 . an d th e followin g term s shal l hav e th e specifi c meaning s give n them . AirOxidation Reactormean s an y devic e o r proces s vesse l i n whic h on e o rmor e organi c reactant s ar e com bine d wit h air , o ra combinatio n o f ai r an d oxygen , t o produc e on e o r mor e organi c compounds . Ammoxidatlo n an d oxychlorinatio n reaction s ar e in clude d l n thi s definition . AirOxidation ReactorRecovery Train mean s a n individua l recover y syste m receivin g th e ven tstrea m fro m a tleas ton e ai roxidatio n reactor , alon g wit h al l ai r oxidatio n reactor s feedin g ven tstream s int o thi s system . AirOxidation Unit

Process mesn e a uni tprocess , includin g ammoxidatlo n an d oxychlorinatio n uni tprocess , tha t use s air , o r a combinatio n o f ai r an d oxygen , a s a n oxyge n sourc e i n combi natio n wit h on e o r mor e organi c reac tant s t o produc e on e o r mor e organi c compounds . Boilers mean s an y enclose d combus tio n devic e tha textract s usefu l energ y ln th e for m of

steam . By Compound

mean s b y individua l stream components , no tcarbo n equivalents . Continuous recordermean s a dat a recordin g devic e recordin g a n instanta neou s dat a valu e a tleas tonc e ever y 1 5 minutes . Flame zone mean s th e portio n o f th e combustio n chambe ri n a boile roccu pie d b y th e flam e envelope . Flow indicatormean s a devic e whic h Indicate s whethe rga s flo w i s presen t I n a ven tstream . Halogenated

Vent Stream mean s an y ventstrea m determine d t o hav e a tota l concentratio n (b y volume ) o f com pound s containin g halogen s o f 2 0 PPm v (b y compound ) o rgreater . Incineratormean s an y enclose d combustio n devic e tha tI s use d fo r de stroyin g organi c compound s an d doe s °o textrac tenerg y i n th e for m o f •tes m o r proces s heat . Process Heater

mean s a devic e tha t transfer s hea tliberate d b y burnin g fu « l t o fluid s containe d I n tubes , in - § 60.61 1

eludin g al l fluid s excep twate r tha tI s heate d t o produc e steam . Proces s Unit

mean s equipmen tas semble d an d connecte d b y pipe s o r duct s t o produce , a s intermediate s o r fina l products , on e o r mor e o f th e chemical s I

n | 60.617 . A proces s uni t ca n operat e independentl y I f supplie d wit h sufficien tfue l o r raw material s an d sufficien tproduc tstorag e facul ties . Product mean s an y compoun d o r chemica l liste d i n | 60.61 7 tha tI s pro duce d fo rsal e a s a fina l produc ta s tha tchemica l o r i s produce d fo rus e l n a proces s tha tneed s tha tchemica l fo r th e productio n o f

othe r chemical s i n anothe r facility . By-products , co-prod ucts , an d Intermediate s ar e considere d t o b e products . Recovery Device mean s a n Individua l uni to f equipment , suc h a s a n absorb er , condenser , an d carbo n adsorber , ca pabl e o f an d use d t o recove rchemical s fo r use , reus e o r sale . Recoverv System mean s a n Individ ua l recover y devic e o rserie s o f suc h device s applie d t o th e sam e proces s stream . Total organic compounds (TO O mean s thos e compound s measure d ac cordin g t o th e procedure s i n 160.614(b)(4) . Fo r th e purpose s o f measurin g mola r compositio n a s re quire d l n | 60.614(dX2Xl) , hourl y emis sion s rat e a s require d i n | 60.614(d)(5 ) an d | 60.614(e ) an d TO C concentratio n a s require d i n 160.615(b)(4 ) an d I 60.615(g)(4) . thos e compound s whic h th e Administrato r ha s determine d d o no tcontribut e appreciabl y t o th e for matio n o f

ozon e ar e t o b e excluded . Th e compound s t o b e exclude d ar e identifie d i n Environmenta l Protec tio n Agency' s statement s o n ozon e abatemen tpolic y fo r SI P revision s (4 2 F R35314 ; 4 4 F R32042 ; 4 5 F R32424 ; 45 F R48042) . Total resource effectiveness CTRE) Index Value mean s a measur e o f th e supplementa l tota l resourc e require men tpe r uni treductio n of TO C asso ciate d wit h a n Individua l ai r oxidatio n ven tstream , base d o n ven tstrea m flo w rate , emissio n rat e of TOC . ne t heatin g value , an d corrosio n proper tie s (whethe r o r no tth e ven tstrea m I s halogenated) . a s quantifie d b j equatio n give n unde r I 60.614(e). : 

### 58 7 ' • fc

- • » 

# 8 i



# z > - C D 

# c n o C O

T J 

### h o§60.61 2 

### Vent Stream mean s an

y gas stream , containin g nitroge n which wa s Intro duced as air t o th e ai r oxidatio n reactor , release d t o th e atmosphere directly from an

y ai r oxidatio n reacto rre cover y trai n orIndirectly , afte rdiversio n throug h othe rproces s equipment. Th e ven tstrea

m exclude s equipment leak s and relief

valve discharge s In

cluding , bu tno tlimite d to , pumps , compressors , and valves . [6 5 F R26922 , Jun e 29 . 1990 ; 5 5 F R36932

. Sept . 7.1990 1 860.61 2 Standard* . 

### Eac h owne roroperato ro tan

y affected facult

y shal l compl

y with paragrap h (a) , (b) , o

r (c ) o f thi s sectio n for each ven tstrea

m o n and afte r th e dat

e o n whic h th e Initia

l performance tes t require d b y g 60. 8 and i 60.61 4 I

s completed , butno tlate rtha n 6 0 day s afte r achievin g th e maximu

m production rat e a twhich th e affecte d facilit y will b e operated , o r18

0 day s afte rth e Ini

tia l start-up , whicheve rdat e come s first. Eac h ownero

roperato r shal l either : (a) Reduc e emission s o

f TO C (minu s methan e an

d ethane ) b

y 98 weight percent, o rt o a TO C (minu s methan e an d ethane ) concentratio n o f 2 0 ppm v o n a dr y basi s correcte d t o 3 percen t oxygen , whicheve ri s les s stringent . I f a boile rorproces s heate rI s used t o compl y with thi s paragraph , the n th e ventstrea

m shal l b e Introduce

d into th e flam e zon e of

th e boile ro rproces s heater ; o r (b ) Combustth e emission s i n a flar e tha tmeets th e requirement s o f 160.18 . or (c ) Maintai n a TRE index valu e greater tha n 1.

0 withou tus e o

f VOC emissio n control devices . I SS.C1 3 Monitorin

g o f cmlsalon a an d operation* . (a ) Th e owne

ro roperato ro

f a n affecte d facilit

y tha tuse s a n incinerato r t o see k t o comply wit

h th e TO C emis sio n limi tspecifie d unde rI 60.612(a) shal l install , calibrate , maintain , an d operat e according t o manufacturer' s spedftcaUon s th e followin g equip ment : (D A temperature monitorin g device equipped wit

h a continuou s recorder and havin g a n accurac

y of ± 1 percent 4 0 CF R Ch . I (7-1-9 1 Edition ) 

### o f th e temperatur e bein g monitore d expresse d l n degree s Celsiu s or ±0. 5 *C . whicheve r i s greater . (1 ) Wher e a n Incinerato r othe rtha n a catalyti c Incinerato r i s used , a tem peratur e monitorin g devic e shal l b e Installe d I n th e firebox . (ii ) Wher e a catalyti c Incinerato r i s used , temperature monitorin g device s shal l b e Installe d i n th e gas stream immediately befor e and afte rth e cata lys tbed . (2 ) A flo w Indicato r tha tprovide s a recor d o f ven tstream flow t o th e in cinerato ra tleas tonc e ever y hou rfo r each affecte d facility . Th e flow Indicato rshal l b e installe d l n th e ven t strea m fro m eac h affecte d faculty a ta poin tcloses tt o th e inle tof eac h incin erato rand before bein g joine d with an y othe rven tstream . (b ) Th e owne roroperato ro f a n affecte d facility tha tuse s a flar e t o see k t o compl y with 160.612(b ) shal l in stall , calibrate , maintain , and operate according t o manufacturer' s specifica tion s th e followin g equipment : (D A hea tsensin g device , suc h a s a n ultra-viole tsenso r o rthermocouple , a t th e pilo tligh tt o indicate th e continu ou s presenc e o

f a flame . (2 ) A flow indicato rtha tprovide s a recor d o f ven tstream flo w t o th e flar e atleas tonc e ever

y hou rfo reac h af

fecte d facility . Th e flow indicato r shal l b e installe d i n th e ven tstream fro m eac h affecte d facility a ta poin t closes tt o th e flare an d befor e bein g joine d with any othe rven tstream . (c ) Th e owne roroperato rof a n affecte d facility tha tuse s a boile ror proces s heate rt o see k t o compl y with {60.612(a ) shal l install , calibrate , maintai n and operate according t o th e manufacturer' s specification s l n th e followin g equipment : (D A flo w Indicato r tha tprovide s a recor d o f ven tstream flo w t o th e boile rorproces s heate r a tleas tonce ever y hou rfo reac h affecte d facility . Th e flow indicato rshal l b e installe d l n th e ven tstream from eac h ai r oxida tio n reacto rwithi n a n affecte d facult y a ta poin tcloses tt o th e inle tof each boile ro rproces s heate ran d befor e bein g joine d with an y othe rven t stream . (2 ) A temperatur e monitorin g device l n th e firebox equippe d with a contin 

### 56 8 Environmenta l Protection Agonc y uous recorde rand havin g a n accurac y o f ± 1 percen to

f th e temperature being measure d expresse d i n degrees Celsiu s or±0. 5 *C

, whicheve ri s greater, fo r boiler s orproces s heater s of les s tha n 44 M

W (15 0 trillio n Btu/hr ) hea t inpu tdesig n capacity . (3 ) Monito rand recor

d th e periods o f operatio n o

f th e boile ro

rproces s heate ri f th e desig n inpu tcapacit y o f th e boile rI

s 44 M W (15 0 millio n Btu / hr ) o rgreater . Th e record s mus tb e readily availabl e fo r inspection . (d ) Th e owne ro roperato rof a n affecte d facility tha tseek s t o demon strat e complianc e wit h th e TRE index valu e limi tspecifie d unde r{ 60.612(c) shal l install , calibrate , maintain , an d operate accordin g t o manufacturer' s specification s th e followin g equip ment , unles s alternativ e monitorin g procedure s o rrequirements ar e ap proved fo r tha tfacility b y th e Administrato r (1 ) Where a n absorberi s th e fina l re cover y devic e i n a recover

y system : (i ) A scrubbin g liqui d temperature monitorin g devic e havin g a n accurac y o f ± 1 percen to

f th e temperature bein g monitore d expresse d i n degree s Celsiu s o r 0. 6 *C

, whicheve ri s greater , an d a specifi c gravit

y monitorin g device havin g a n accurac y of 0.0 2 spe cifi c gravit

y units , eac h equipped with a continuou s recorder ; (il ) A n organi c monitorin g device use d t o Indicat

e th e concentratio n leve l of organi c compound s exitin g th e recover y devic e base d o n a detectio n principl e suc h a s infra-red . photolonl satton , o rtherma l conductivity , each equippe d wit h a continuou s recorder. (2 ) Wher e a condense ri s th e fina l recover y devic e i n a recover

y system : (i ) A condense rexi t(produc tside ) temperatur e monitorin g devic e equippe d wit h a continuou s recorde r and havin g a n acurac

y o f ± 1 percent o f th e temperatur e bein g monitore d expresse d I

n degree s Celsiu s or0. 5 'C , whicheve ri s greater , (U ) A n organi c monitorin g device use d t o Indicat

e th e concentratio n leve l of organi c compound s exitin g th e recover y devic e baae

d o n a detectio n principl e suc h a s infra-red . photolonl zatlon , o rtherma l conductivity , each equippe d wit h a continuou s recorder . S 60.61 4 

### (3 ) Where a carbon adsorberi s th e fina l recover y devic e i n a recover

y system : (I ) A n integratin g stea m flow moni toring devic e havin g a

n accurac y o f 10 percent, an d a carb o i ' « d temperature monitorin g device havin g a n accurac y o f ± 1 percen to

f th e temperature bein g monitore d expresse d I n degree s Celsius o r±0. 5 *C

. whicheve rI

s greater , both equippe d with a continuou s recorder ; (II ) A n organi c monitorin g device used t o Indicat

e th e concentratio n leve l o f organi c compound s exitin g th e recover y devic e base d o n a detectio n principl e suc h as infra-red , phototonl zation , o rthermal conductivity , eac h equipped with a continuou s recorder . (e ) A n owne ro roperato rof a n affecte d facility seekin g t o demonstrate compliance with th e standard s sped ; fled unde r 160.61 2 wit h contro l de* vice s othe rtha n a n Incinerator , boiler , proces s heater , o rflare ; o rrecover y devices othe rtha n a n absorber, con denser , o rcarbon adsorbershal l pro vide t o th e Administrato rInformation describin g th e operatio n o f th e contro l devic e o rrecover

y devic e and th e proc es s parameteris ) whic h woul d indicate prope roperatio n an d maintenanc e o f th e device . Th e Administrato r ma y re ques tfurthe rinformatio n and will specif y appropriat

e monitorin g proce dures o rrequirements . S 60.61 4 Tea tmethod s an d procedures

. (a ) Fo rth e purpos e of

demonstrat in g complianc e wit h 160.612 . al l affecte d facultie s shal l b e ru n a tful l op eratin g condition s an d flow rate s durin g an y performance test . (b ) Th e followin g method s I n appen di x A t o thi s part , excep ta s provide d unde r 160.8(b ) shal l b e use d a s refer enc e method s t o determin e compliance wit h th e emissio n limi to r percentreductio n efficiency specifie d under 160.612(a) . ( D Metho d 1 o r IA . a s appropriate , for selectio n o

f th e samplin g Bites . Th e contro l devic e Inletsamplin g sit e fo r determinatio n o f

ven tstream molar compositio n o r TO C (les s methan e an d ethane ) reductio n efficiency shall b e prio rt o th e inle to f th e contro l device an d afte r th e recover y system . 

# • * i

58 9860.61 4 (2 ) Metho d 2 . 2A . 2C . o r2D . a s ap propriate , fo rdeterminatio n o f th e volumetri c flo w rates . (3 ) Th e emissio n rat e correctio n factor , integrate d samplin g an d analy si s procedur e o f

Metho d 3 shal l b e use d t o determin e th e oxyge n concen tratio n (%OM > fo rth e purpose s o f de terminin g complianc e ~ wit h th e 2 0 ppm v limit . Th e samplin g sit e shal l b e t h e sam e a s tha to f

th e TO C sample s an d th e sample s shal l b e take n durin g th e sam e tim e tha tth e TO C sample s ar e taken . Th e TO C .concentratio n correcte d t o 3 percen tO i (C c ) shal l b e compute d usin g th e followin g equation : 4 0 CF R Ch . I (7-1-9 1 Edition ) (Hi ) Th e mas s rate s o f TO C (E, , £«, ) shal l b e compute d usin g th e followin g equations :

C.-C„c 17. 9

20.9-%O u where : Ct-Concentratio n o f

TO C correcte d t o 3 percen t0, . dry basis , pp m b y volume . Ctoc-Concentratio n o f

TO C (minu s meth an e an d ethane) , dr y basis , pp m b y volume . %On-Concentratio n o f O, , dr y basis , per cen tb y volume . (4 ) Metho d 1 8 t o determin e concen tratio n o f

TO C l n th e contro l devic e outle tan d th e concentratio n o f TO C I n th e Inle twhe n th e reductio n effi cienc y o f

th e contro l devic e i s t o b e de termined . (i ) Th e samplin g tim e fo reac h ru n shal l b e 1 hou ri n whic h eithe ra n in tegrate d sampl e o rfou rgra b sample s shal l b e taken . I f

gra b samplin g I s use d the n th e sample s shal l b e take n a t15-mlnut e intervals . (il ) Th e emissio n reductio n (R ) o f TO C (minu s methan e an d ethane ) shal l b e determine d usin g th e follow in g equation :

R - E.-E .

- X 10 0

where : R-Cmlaslo n reduction , precen tb y weight . Kj-IIaa s rat e o f

TO C enterin g th e contro l device , k g TOC/hr . B.-Maa a rat e of

TO C discharge d t o th e at mosphere , k g TOC/hr . E.-K , n I I C u M J Q ,

B.-K . n | x CMJQ .

Where : Co . C-Concentratlo n o f sampl e componen t "J " o f th e ga s strea m a tth e inle tan d outle to f th e contro l device , respectively , dr y basi s pp m b y volume . M„ . UU-Molecula rweigh to f sampl e compo nen t"1 " o f

th e ga s strea m a tth e inle t an d ouUe to f

th e contro l device , respec tively , g/g-mol e <lb/lb-mole) . Q b Q.-Flo w rat e o f

ga s strea m a tth e inle t an d ouUe to f

th e contro l device , respec tively , dscm/ml n (dsef/hr) . Ki-Constant . 2.49 4 x lO'd/ppm ) (g-mole / scm ) (kg/g ) (min/hr) , wher e standar d temperatur e fo r(g-mole/acm ) i s 20*C . (iv ) Th e TO C concentratio n (Croc ) i a t h e su m o f

th e individua l component s an d shal l b e compute d fo reac h ru n usin g th e followin g equation :

Cro c n

I C , 1- 1 where : Croc-Concentratio n o f

TO C (minu s meth an e an d ethane) , dr y basis , pp m b y volume . C,—Concentratio n o f

sampl e component s In th e sample . n-Numbe ro f

component s In th e sample . (5 ) Whe n a boile ro rproces s heate r wit h a desig n hea tinpu tcapacit y o f 4 4 M W (15 0 millio n Btu/hour ) o rgreate r I s use d t o see k t o compl y wit h 160.612(a) , th e requiremen tfo ra n Ini tia l performanc e tes ti s waived , i n ac cordanc e wit h 8 60.8(b) . However , th e Administrato rreserve s th e optio n t o requir e testin g a tsuc h othe rtime s a s 

### 59 0 Environmenta l Protectio n Agonc y

ma y b e required , a s provide d fo ri n sectio n 11 4 o f

th e Act . (c ) Whe n a flar e i s use d t o see k t o compl y wit h S 60.612(b) , th e flar e shal l compl y wit h th e requirement s o f { 60.18 . (d ) Th e followin g tes tmethod s l n appendi x A t o thi s part , excep ta s pro vide d unde r{ 60.8(b) . shal l b e use d fo r determinin g th e ne theatin g valu e o f th e ga s combuste d t o determin e com plianc e unde r{60.612(b ) an d fo rde terminin g th e proces s ven tstrea m TR E Inde x valu e t o determin e compli anc e unde ri 60.612(c) . (1X1 ) Metho d 1 o r1 A , a s appropri ate , fo rselectio n o f

th e samplin g site . Th e samplin g sit e fo rth e ven tstrea m flow rat e an d mola rcompositio n deter minatio n prescribe d l n i 60.614(d ) (2 ) an d (3 ) shal l be , excep tfo rth e situa tion s outline d i n paragrap h (dxixti ) o f thi s section , prio rt o th e inle to f an y contro l device , prio rt o an y post reacto rdilutio n o f

th e strea m wit h air , an d prio rt o an y post-reacto rintroduc tio n o f halogenate d compound s Int o th e ven tstream . N o transvers e sit e se lectio n metho d I s neede d fo rvent s smalle rtha n 4 Inche s l n diameter . (11 ) I f an y ga s strea m othe rtha n th e ai roxidatio n ven tstrea m fro m th e affecte d facilit y i s normall y conducte d throug h th e fina l recover y device . (A ) Th e samplin g sit e fo rven t strea m flo w rat e an d mola rcomposi tio n shal l b e prio rt o th e fina l recov er y devic e an d prio rt o th e poin ta t whic h th e nonal roxidatio n strea m i s introduced . (B ) Th e efficienc y o f

th e fina l recov er y devic e I s determine d b y measurin g th e TO C concentratio n usin g Metho d 1 8 a tth e Inle tt o th e fina l recover y devic e afte rth e introductio n o f an y nonal roxidatio n ven tstrea m an d a t th e outle to f

th e fina l recover y device . (C ) Thi s efficienc y i s applie d t o th e TO C concentratio n measure d prio rt o th e fina l recover y devic e an d prio rt o th e Introductio n o f

th e nonal roxida tio n strea m t o determin e th e concen tratio n o f

TO C l n th e ai roxidatio n strea m fro m th e fina l recover y device . Thi s concentratio n o f TO C i s the n use d t o perfor m th e calculation s out line d I n ( 60.614(d ) (4 ) an d (5) . 

### 59 1 § 60.61 4 (2 ) Th e mola rcompositio n o f th e proces s ven tstrea m shal l b e deter mine d a s follows : (1 ) Metho d 1 8 t o measur e th e con centratio n o f

TO C Includin g thos e containin g halogens . (U ) AST M D1946-7 7 (Incorporatio n b y referenc e a s specifie d l n i 60.1 7 o f thi s part ) t o measur e tri e concentra tio n o f carbo n monoxid e an d hydro gen . (ill ) Metho d 4 t o measur e th e con ten to f wate rvapor . (3 ) Th e volumetri c flo w rat e shal l b e determine d usin g Metho d 2 . 2A , 2C . o r 2D . a s appropriate . (4 ) Th e ne theatin g valu e o f th e ven t strea m shal l b e calculate d usin g th e followin g equation :

HT=K J n 

### J I 

### CH, ]

where : H T =Ne theatin g valu e o f th e sample . MJ / scm , wher e th e ne tenthalp y pe rmol e o f offga s U base d o n combustio n a t2 5 * C an d 76 0 m m Hg . bu tth e standar d tem peratur e fo rdeterminin g th e volum e correspondin g to on e mol e i s 2 0 *C . a s t n th e definitio n o f

Q , (offga s flow rate) . K,=Constant . 1.74 0 x 10- '

(1 ) (gmole ) (MJ) . pp m kca l

wher e standar d temperatur e fo r

(g-mole ) sc m I s 2 0 *C. C,=Concentratio n o f

compoun d J i n ppm , a s measure d fo rorganic s b y Metho d 1 8 an d measure d fo rhydroge n an d carbo n mon oxid e b y AST M D1946-7 7 (Incorporate d b y referenc e a s specifie d l n 160.1 7 o f thi s part ) a s indicate d i n i 60.614(dX2) . - J j 

### 7 * •

_ 

# I

« <§ 60.61 4 H,-Ne thea to f

combustio n J

. kcal/g-molc . base d o n combustio n a t2 5 ' C an d 76 0 m m Hg . Th e heat s o f combustio n of ven tstrea m component s woul d b e re quire d t o b e determine d usin g AST M D2382-7 6 (Incorporatio n b y referenc e a s specifie d i n 160.1 7 o f

thi s part ) I

f pub lishe d value s ar e no tavailabl e o rcanno t b e calculated . (5 ) Th e emissio n rat e o f TO C l n th e proces s ven tstrea m shal l b e calculate d usin g th e followin g equation :

Eroc=K , n

z J = l C,M ,

where : Ero c - Emissio n rat e o f

TO C l n th e sample , kg/h r K,=Constant . 2.49 4 X 1 0 * (1/ppm ) (g mole/scm ) (kg/g > (mln/hr) . wher e standar d temperatur e fo r(g-mole/scm ) ls20' C Cj-Concentratio n o n a basi s o f compoun d J I n pp m a s measure d b y Metho d 1 8 a s in dicate d l n 100.614(dX2 ) M|-Molecula r weigh to f sampl e J

, g/g-mol e 4 0 CF R Ch . I (7-1-9 1 Edition ) Q,iVen tstrea m flow rat e (scm/mln ) a ta standar d temperatur e o f 2 0 " C (6 ) Th e tota l proces s ven tstrea m concentratio n (b y volume ) o f com pound s containin g halogen s (ppmv , b y compound ) shal l b e summe d fro m th e Individua l concentration s o f com pound s containin g halogen s whic h wer e measure d b y Metho d 18 . (e ) Fo rpurpose s o f

complyin g wit h i 60.612(c) , th e owne r o roperato r o f a facilit y affecte d b y thi s subpar tshal l calculat e th e TR E Inde x valu e o f th e ven tstrea m usin g th e equatio n fo rin cineratio n i n paragrap h (e)(1 ) o f thi s sectio n fo rhalogenate d ven tstreams . Th e owne r o roperato ro f a n affecte d facilit y wit h a nonhalogenate d ven t strea m shal l determin e th e TR E inde x valu e b y calculatin g value s usin g bot h th e incinerato requatio n i n paragrap h (e)(1 ) o f thi s sectio n an d th e flar e equatio n i n paragrap h (e)(2 ) o f thi s sectio n an d selectin g th e lowe ro f th e tw o values . (1 ) Th e TR E Inde x valu e o f th e ven t strea m controlle d b y a n incinerato r shal l b e calculate d usin g th e followin g equation :



### 59 2 Environmenta l Protectio n Aponcy §60.61 4

+ t 

# X I

tt

« + V + 

### d + 

### d 

# -J l > i 

# 1

*<A



### 59 3S 60.61 4

(1 ) wher e fo r a ven tstrea m flo w rat e (scm/mln ) a ta standar d temperatur e o f 2 0 * C tha tI s greate r tha n o r equa l t o 14. 2 scm/mln : TRE-TR E Index value . Q.=Ven tstrea m flow rat e (scm/mln) . a ta standar d temperatur e o f 2 0 *C . H T -Ven tstrea m ne theatin g valu e (MJ / scm) , wher e th e ne tenthalp y o f combus tio n pe r mol e of

ven tstrea m I

s base d o n combustio n a t2 5 " C an d 76 0 m m Hg , bu t th e standar d temperatur e fo r determin in g th e volum e correspondin g t o on e mol e I s 2 0 'C , a s I

n th e definitio n o f

Q. . 4 0 CF

R Ch . I (7-1-9 1 Edition ) 

# T gpvironmonto l Protectio n Agoncy § 60.61 4 Y . Q , fo r al l ven tstrea m categorie s list*, . l n Tabl e 1 excep tfo r Categor y E V»£ . stream s wher e Y.=(Q.MH T )/3.6 . m E,ic=Hourl y emission s o f TO C reporte d i kg/hr . ° m a , b , c , d , e , an d f

ar e coefficients . Th e se to f

coefficient s whic h appl y t o a ven tstrea m shal l b e obtaine d fro m Tabl e 1 .



### 59 4 1ABI E 1

. AI R OXIDATIO N USPS IR E COEFFICIENT S FO R VEN T STREAM S CONTROLLE D B T A H INCINERATO R

OCSIG " CATEGOR

T Al

. FO

R HALOGENATE D PROCES S VEN T STREAKS

. I F 0 « NE T HEATIN G VALU E (HJ/jcm ) < 3.5 : 

### o, . Ven

tStrea m Do w rat e (sen/m l n l 14. 2 i 0 , i 16. 8 18. 8 < 0 * 1 69 9 69 9 « 0 , I

140 0 140 0 < 0 , « 210 0 210 0 < 0 , 1 280 0 280 0 < 0 , I 350 0 a

19.1837 0 20.0056 3 39.6702 2 59.7348 1 79.5994 1 99.4640 0 b

0.2758 0 0.2758 0 0.2997 3 0.3146 7 0.32572 0.3345 6 c

0.7576 2 0.303S 7 0.3038 7 0 3018 ; 0.3038 7 0.3038 7 d

-0.1306 4 -0.1306 4 -0.1306 4 -0.1306 4 -0.1306 4 -0.1306 4 eOOOOOO f

0.0102 5 0.0102 5 0.0144 9 0.0177 5 0.0204 9 0.0229 1

0CSI6 N CATEGOR

Y A? . FO

R HALOGENATE D PROCES S VEN T STREAMS , 0 • Ven t Street * Flo wrat e " * (|C«/>in ) 14. 2 • Q , ; 18. 6 18. 8 < O i 1 69 9 69 9 < 0 , < 140 0 140 0 < Q * < 210 0 280 0 < Q j • 350 0 a 18.8446 6 19.6665 8 39.1921 3 58.7176 8 78.2432 3 97.7687 9 b

0.2674 2 0.2674 2 0.2906 2 0.3051 1 0.3158 2 0.3243 9 I F NE

T HEATIN 6 VALU E >

c -0.2004 4 -0.2533 2 -0.2533 2 -0.2533 2 -0.2533 2 -0.2533 2 d

0 0 0 0 0 0 3. 5 MJ/sca :

e 0 0 0 0 0 0 f

0.0102 5 0.0102 5 0.0144 9 0.0177 5 0.0204 9 0.0229 1

OESIG N CATEGOR

T 8

. FO R NONHALOGENATE O PROCES S VEN T STREAKS

. I F 0 i NE T KEATIN 6 VALU E (HJ/soa ) < 0.48 :

0 , * Ven

tStrea m Flo w rat e (san/mln l 14. 2 < Q i < 134 0 134 0 « Q , < 269 0 269 0 < 0 , < 404 0 8.5424 5 16.9438 6 25.3452 8 O.I05S 5

0.1147 0 0.1204 2 0.0903 0

0.0903 0 0 0903 0 -0.1710 9

-0.1710 9 -0.1710 9 0.0102 5 0.0144 9 0.0177 5

DESIG N CATEGOR

T C

. FOR NONHALOGENATE O PROCES S VEN T STREAKS

. I F 0.4 8 < NE T HEATIN G VALU E (NJ/sca l < 1.9 : 0 . • Ven t Strea m Flo wrat e

(scm/min ) 14. 2 < 0 , < 134 0 134 0 < 6 : < 269 0 269 0 < 0 * < 404 0 a 9.2523 3 18.3636 3 27.4749 2 b

0.0610 5 0.0663 5 0.0696 5 c

0.3193 7 0.3193 7 0.3193 7 d

-0.1618 1 -0.1618 1 -0.1618 1 e

0 0 0 f

0.0102 5 0.0144 9 0.0177 5

OESIG N CATEGOR

T 0

. FOR NONHALOGENATE O PROCES S VEN T STREAKS

. I F 1. 9 < NE T HEATIN G VALU E (MJ/sca ) < 3.6 : Q , • Ven t Strea m Flo wrat e

(scei/aln ) 14. 2 « 0 , < 118 0 118 0 < 6 : < 237 0 237 0 < 0 , < 355 0 a 6.6786 8 13.2163 3 19.7539 8 t

0.0694 3 0.0754 6 0.0792 2 c

0.0258 2 0.0258 2 0.0258 2 dooo 

### •ooo1 f

0.0102 5 0.0144 9 0 0177 5

KSI6 N CATEGOR

T E . FO

R NONHALOGENATE

O PROCES

S VEN T STREAK

S

T , > Dilutio n Flo wrat e flcValn ) - (0, | (H,)/3. 6 14. 2 < T , < 118 0 118 0 < T ! <

237 0 237 0 « T J <

355 0 a 6.6786 8 13.2163 3 19.7539 8 b

0 0 0 I F NE

T HEATIN G VALU E

c 0 0 0 d

-0.0070 7

- 0 0070 7 -0.0070 7 > 3. 6 MJ/scm :

e 0.0222 0 0.0241 2 0.0253 3 f

0.0102 5 0.0144 9 0.0177 5



### 59 5 "i i a - t 

# 1 1S 60.61 4

(11 ) Wher e fo r a ven tstrea m flow rat e (scm/mln ) a ta standar d tempera tur e o f 2 0 ' C tha ti s les s tha n 14. 2 scm/mln : THEATR

E Inde x value . Q.-14. 2 scm/mln . B,-(FIiOWXHVAI,)/14.2 . Wher e th e followin g Input s ar e used : PLOW-Ven tstrea

m flo w rat e (scm/mln) . a ta standar

d temperatur

e o f 2 0 "C . HVAL--Ven

tstrea m ne theatin g value (MJ / scm) . wher

e th e ne tenthalp y per mol e o f ven tstrea

m I s base d o n combustion at 2 5 ' C an d 76 0 m m Hg . bu tth e standar

d temperatur

e for determinin

g th e volum

e correspondin

g t o 1 mol

e i s 2 0 * C a s I n th e definitio n o

f Q.. 4 0 CFR Ch . I (7-1-9 1 Edition ) Y. = 14.2 scm/ml n for al l ventstrea m catego rie s liste d ln Table 1 excep tfo r Categor y , E ven tstreams , wher

e Y,=(14.2XHt) / 3.6 . ETOC=Hourl

y emission s o

f TO C reporte d i n kg/hr . a , b , c , d , e . and f

ar e coefficients . Th e se to f

coefficient s tha tappl y t o a ven tstrea m ca n b e obtaine d fro m Tabl e 1 . (2 ) Th e equatio n fo r calculatin g th e TR E inde x valu e o f

a ven tstrea m con trolle d b y a flare i s a s follows : Environmenta l Protectio n Agonc y §6061 4

•a + 

# I T X +

tt + 

# r

59 6 59 74 0 CF R Ch . I (7-1-9 1 Edition ) a . b . c . d . an d e ar e coefficients . Th e se to f

coefficient s tha tappl y t o a ven tstrea m shal l b e obtaine d fro m Tabl e 2 . $6041 5 where : TRE-TR E inde

x value . Enc- * Hourl

y emissio n rat

e o f TO C reporte

d l n kg/hr . Q.-Ven tstrea

m flo w rat e (scm/mln ) ata standar d temperatur

e o f 2 0 *C . H T -Ven tstrea

m ne theatin g valu

e (MJ / scm) wher e th e ne tenthalp y pe

rmol e o f offgas i s base

d o n combustion at2

5 * C an d 16 0 m m Hg . bu tth e standar

d tem peratur e fo rdeterminin g th e volum e correspondin

g t o 1 mol e I

s 2 0 * C a s ln th e definition o

f Q ^

TABL E 2—AI R OXIDATIO N PROCESSE S NSP S TR E COEFFICIENT S FO R VEN T STREAM S CONTROU-E D B Y A FLAR E 

### • 22 5 0.30 9 b

0.28 8 0.081 9 c

-0.19 3 -0.004 3 4

-0.005 1 -0.003 4 

### • 2.0 8

2.0 8 (f ) Eac h owne ro roperato ro f a n affecte d facilit y seekin g t o compl y wit h I 00.610(c ) o r| 80.612(c ) shal l recalcu lat e th e TR E Inde x valu e fo rtha taffecte d facilit y wheneve rproces s change s ar e made . Som e example s o f proces s change s ar e change s i n pro ductio n capacity , feedstoc k type , o r catalys ttype , o r wheneve rther e i s re placement , removal , o radditio n o f re cover y equipment . Th e TR E inde x valu e shal l b e recalculate d base d o n tes tdata , o ro n bes tengineerin g esti mate s o f th e effect s o f

th e chang e t o th e recover y system . (1 ) Wher e th e recalculate d TR E inde x valu e Is les s tha n o requa l t o 1.0 , th e owne ro roperato rshal l notif y th e Administrato rwithi n 1 wee k o f th e re calculatio n an d shal l conduc ta per formanc e tes taccordin g t o th e meth od s an d procedure s require d b y 160.61 4 t o determin e complianc e wit h 160.612(a) . Performanc e test s mus tb e conducte d a s soo n a s possibl e afte r th e proces s chang e bu tn o late rtha n 18 0 day s fro m th e tim e o f th e proces s change . (2 ) Wher e th e Initia l TR E inde x valu e i s greate rtha n 4. 0 an d th e recal culate d TR E inde x valu e Is les s tha n o r equa l t o 4.0 , bu tgreate rtha n 1.0 . th e owne ro roperato rshal l conduc ta performanc e tes tIn accordanc e wit h 160. 8 an d 160.61 4 an d shal l compl y wit h I I 60.813 . 60.614 . an d 60.615 . Per formanc e test s mus tb e conducte d a s soo n a s possibl e afte rth e proces s chang e bu tn o late r tha n 18 0 day s fro m th e tim e o f

th e proces s change . [55 F R26022 . Jun e 29 , 1090 : 6 5 FR36932. Sept . 7.1990 ] 9 60.61 5 Reporting and recordkeeping requirements . (a ) Eac h owne ro r operato rsubjec t t o 160.61 2 shal l notif

y th e Administra to r o f th e specifi c provision s o f { 60.61 2 ( | 60.61 2 (a ) (b) , o r(O ) wit h whic h th e owne r o roperato r ha s elect e d t o comply . Notificatio n shal l b e submitte d wit h th e notificatio n o f ini tia l start-u p require d b y 160.7(a)(3) . If a n owne ro roperato relect s a ta late r dat e t o us e a n alternativ e provisio n o f 160.61 2 wit h whic h h e o rsh e wil l comply , the n th e Administrato rshal l b e notifie d b y th e owne r o r operato r 0 0 day s befor e implementin g a chang e and , upo n Implementin g th e change , a performanc e tes tshal l b e performe d a s specifie d b y 160.61 4 withi n 18 0 days . (b ) Eac h owne ro roperato rsubjec t t o th e provision s o f

thi s subpar tshal l kee p up-to-date , readil y accessibl e record s o f

th e followin g dat a meas ure d durin g eac h performanc e test , an d als o Includ e th e followin g dat a i n th e repor to f

th e initia l performanc e tes trequire d unde r|60.8 . Wher e a boile r o rproces s heate r wit h a desig n hea tinpu tcapacit y o f 4 4 M W (15 0 5 9 8 Environmenta l Protectio n Agenc y millio n Btu/hour ) o rgreate r Is use d t o compl y wit h 160.612(a) . a repor tcon tainin g performanc e tes tdat a nee d no tb e submitted , bu ta repor tcontain in g th e informatio n o f

| 60.616(b)(2)(l ) I s required . Th e sam e dat a specifie d i n thi s sectio n shal l b e submitte d i n th e report s o f

al l subsequentl y require d performanc e test s wher e eithe r th e emissio n contro l efficienc y o f a contro l device , outle tconcentratio n o f TOC . o r th e TR E inde x valu e o f a ven t strea m fro m a recover y syste m i s de termined . (1).Wher e a n owne ro r operato r sub jec tt o thi s subpar tseek s t o demon strat e complianc e wit h {60.612(a ) throug h us e o f

eithe r a therma l o r catalyti c incinerato r (1 ) Th e averag e firebo x temperatur e o f th e Incinerato r (o rth e averag e tem peratur e upstrea m an d downstrea m o f th e catalys tbe d fo r a catalyti c inciner ator) , measure d a tleas tever y 1 5 min ute s an d average d ove r th e sam e tim e perio d o f th e performanc e testing , an d (11 ) Th e percen treductio n o f TO C determine d a s specifie d l n 160.614(b ) achieve d b y th e Incinerator , o r th e concentratio n o f

TO C (ppmv , b y com pound ) determine d a s specifie d i n 160.614(b ) a tth e outle to f th e contro l devic e o n a dr y basi s correcte d t o 3 percen toxygen . (2 ) Wher e a n owne r o r operato rsub jec tt o th e provision s o f thi s subpar t seek s t o demonstrat e complianc e wit h 160.612(a ) throug h us e o f a boile r o r proces s heate r (I ) A descriptio n o f

th e locatio n a t whic h th e ven tstrea m i s introduce d int o th e boile r o rproces s heater , an d (II ) Th e averag e combustio n temper atur e o f th e boile ro rproces s heate r wit h a desig n hea tinpu tcapacit y o f les s tha n 4 4 M W (15 0 millio n Btu/hr ) measure d a tleas tever y 1 5 minute s an d average d ove r th e sam e tim e perio d o f th e performanc e testing . (3 ) Wher e a n owne r o r operato r sub jec tt o th e provision s o f thi s subpar t seek s t o compl y wit h 160.612(b ) throug h th e us e o f

a smokeles s flare , flar e desig n (I.e. , steam-assisted , air-as sisted , o r nonasslsted) , al l visibl e emis sio n readings , hea tconten tdetermina tions , flow rat e measurements , an d exi tvelocit y determination s mad e durin g th e performanc e test , contlnu - § 60.61 5 ou s record s o f

th e flar e pilo tflame monitoring , an d record s o f al l period s o f operation s durin g whic h th e pilo t flam e i s absent . (4 ) Wher e a n owne r o r operato r seek s t o demonstrat e complianc e wit h 160.612(c) : (i ) Wher e a n absorbe r I s th e fina l re cover y devic e l n a recover y system , th e exi tspecifi c gravit y (o ralternativ e pa ramete r whic h 1 | a measur e o f th e degre e o f

absorbin g liqui d saturation , i f approve d b y th e Administrator) , an d averag e exi ttemperatur e o f th e ab sorbin g liquid , measure d a tleas tever y 1 5 minute s an d average d ove r th e sam e tim e perio d o f

th e performanc e testin g (bot h measure d whil e th e ven t strea m I s normall y route d an d consti tuted) , o r (il ) Wher e a condense r i s th e fina l recover y devic e l n a recover y system , th e averag e exi t(produc tside ) tem perature , measure d a tleas tever y 1 6 minute s an d averag e ove rth e sam e tim e perio d o f

th e performanc e testin g whil e th e ven tstrea m i s normall y route d an d constituted . (ill ) Wher e a carbo n adsorbe r i s th e fina l recover y devic e l n a recover y system , th e tota l stea m mas s flo w measure d a tleas tever y 1 6 minute s an d average d ove rth e sam e tim e perio d o f

th e performanc e tes t(ful l carbo n be d cycle) , temperatur e o f th e carbo n be d afte r regeneratio n (an d withi n 1 5 minute s o f completio n o f an y coolin g cycle(s) , an d duratio n o f th e carbo n be d steamin g cycl e (al l measure d whil e th e ven tstrea m i s nor mall y route d an d constituted) , o r (iv ) A s a n alternativ e t o 160.615(bX4Ki) . (U ) o r (Ui) . th e con centratio n leve l o r readin g indicate d b y th e organi c monitorin g devic e a t th e outle to f

th e absorber , condenser , o r carbo n adsorbe r measure d a tleas t ever y 1 5 minute s an d average d ove r th e sam e tim e perio d o f th e perform anc e testin g whil e th e ven tstrea m Is normall y route d an d constituted . (v ) Al l measurement s an d calcula tion s performe d t o determin e th e TR E Inde x valu e o f

th e ven tstream . (c ) Eac h owne r o roperato r subjec t t o th e provision s o f

thi s subpar tshal l kee p up-to-date , readil y accessibl e con tinuou s record s o f

th e equipmen top eratin g parameter s specifie d t o b e 

### 59 9 60-14 0 O—91 - - »5 60.61 5 

### monitored unde

r{ 60.613(a) and (c ) a s wel l a s up-to-date , readily accessibl e records o f periods o f operatio n durin g which th e parameterboundarie s es tablishe d durin

g th e mos trecen tper formanc e tes tar e exceeded . Th e Administrato rma

y a tan y tim e require a repor to f thes e data . Wher

e a combus tio n devic e i s use d by a n ownero rop erato rseeking t o demonstrate compli ance wit h | 60.612(a

) or(c) , period s o

f operatio n durin

g which th e paramete r boundarie s establishe d during th e mos trecen

tperformanc

e test s ar e ex ceeded ar e defined a s follows : (1 ) Fo rtherma l incinerators , al l 3 - hourperiod

s o f operatio n durin g whic h th e averag

e combustio n temper ature wa s mor e tha n 28* C (50*F) belo w th e averag

e combustio n temperatur e during th e mos trecen tperformance tes ta twhich complianc e wit h 160.612(a) wa

s determined . (2 ) Forcatalyti c incinerators , al l 3 - hou r periods of

operatio n durin g which th e averag

e temperature of

th e ven tstrea

m Immediatel

y befor e th e catalys tbe

d I s mor e tha n 2 8 * C (5 0 'F ) below th e averag

e temperature o f

th e ven tstrea

m durin g th e mos trecen t performanc

e tes ta twhich complianc e with 160.612(a) was determined . Th e ownero r operato rals o shal l recor d al l 3-hour periods o

f operatio n durin g which th e average temperatur e differ enc e across th e catalys tbe d I s less tha n 8 0 percento

f th e averag e tem perature difference o

f th e devic e during th e mostrecen tperformance tes tatwhic

h complianc e wit h 160.612(a) wa

s determined . (3 ) Al l 3-hou rperiod s o

f operatio n durin g whic h th e average combustio n temperatur

e wa s mor e tha n 2 8 * C (5 0 *F ) belo w th e average combustio n tem peratur e durin g th e mos trecen tper formanc e tes ta twhich complianc e with 160.612(a) was determine d fo r boilers orproces s heater s with a design heatinpu

tcapacit y o f less tha n 4 4 M W (160 millio n Btu/hr) . (4 ) Fo rboilers orproces s heaters , wheneverther e I

s a chang e i n th e lo catio n atwhic

h th e ven tstream i s In

troduced int o th e flam e zon e a s re quire d unde rI 60.612(a) . (d ) Eac h owne roroperato rsubjec t t o th e provisions of

thi s subpartshal l keep up-to-date , readily accessibl e con 4 0 CF R Ch . I (7-1-9 1 Edition ) 

### tlnuou s records o

f th e flow indicatio n specifie d under160.613(a)(2 ) 160.613(b)(2) . an

d {60.613(c)(1) . a s wel l a s up-to-date , readily accessibl e record s o f all periods whe n th e ven t stream I s diverted fro

m th e contro l devic e orha s n o flow rate . (e ) Eac h owne roroperato rsubjec t t o th e provisions of

thi s subpartwh o use s a boile rorproces s heate rwit h a desig n hea tInpu

tcapacit y o f 4 4 M W o rgreate rt o comply wit h { 60.812(a ) shall keep a

n up-to-date , readil y acces sibl e recor

d o f all period s of

operatio n o f th e boile rorproces s heater . (Exam ple s o f such records coul d Includ e record s o f stea m use , fue l use , ormoni torin g dat

a collecte d pursuan tt o othe r 8tat e orFedera

l regulatory require ments) . (f ) Eac h owne roroperato rsubjec t t o th e provisions o

f thi s subpartshal l kee p up-to-date , readily accessibl e con tinuou s records o

f th e flare pilo tflam e monitorin g specifie d i n { 60.613(b) . a s wel l a s up-to-date , readily accessibl e record s o f all period s o

f operation s i n whic h th e pilo tflame I

s absent . (g ) Each owne

r o roperato rsubjec t t o th e provisions of

thi s subpartshal l kee p up-to-date , readily accessibl e con tinuou s records of

th e equipmen top eratin g parameter

s specifie d t o b e monitore d under160.613(c ) a s wel l a s up-to-date , readily accessibl e record s o f period s o

f operatio n durin g whic h th e parameter boundarie s establishe d durin g th e mos trecen tperformanc e tes tare exceeded . Th e Administrato r ma y a tan y tim e require a reporto f thes e data . Wher

e th e owne r o ropera to rseek s t o demonstrate complianc e with (60.612(c) . period s of operatio n durin g whic

h th e paramete rbound arie s establishe d durin g th e mos t recen tperformanc

e test s are exceede d are define d as follows : (1 ) Wher e a n absorber I

s th e final re cover y devic e i n a recover

y system , and wher

e a n organi c monitorin g devic e I s no tused : (i ) All 3-hou

rperiod s of

operatio n durin g whic

h th e average absorbin g liqui d temperature was more tha n 1 1 ' C (2 0 *F ) above th e averag e absorbin g liqui d temperatur

e durin g th e mos t recen tperformanc

e test , o r (ii ) All 3-hourperiod s of operatio n durin g whic

h th e average absorbin g 60 0 Environmenta l Protectio n Agenc y 

### liquid specifi c gravit

y was more tha n 0. 1 uni tabove , ormor

e tha n 0. 1 uni t below, th e average absorbing liqui d specifi c gravit

y during th e mos trecen t performanc

e tes t(unles s monitorin g of a n alternativ e parameter , whic h i s a measur e o f th e degre e o

f absorbing liquid saturation , i s approved b y th e Administrator, i n whic h cas e h e o rsh e wil l define appropriat

e paramete r boundarie s an d period s o

f operatio n durin g whic h the y are exceeded) . (2 ) Whe n a condense rIs th e fina

l re cover y device l n a recover

y system , an d wher e a n organi c monitorin g devic e i s no tused , al l 3-hou rperiod s of operatio n during whic h th e average exi t(produc

tside ) condense roperat in g temperature wa s more tha n 6 * C (1 1 *F ) abov e th e average exi t(product side ) operatin g temperatur e durin g th e mos trecen tperformance test . (3 ) Wher e a carbon adsorbe ri s th e fina l recover y device i n a recover

y system and where a n organi c monitor in g devic e i s no tused : (i ) Al l carbon be d regeneratio n cycle s during which th e tota l mas s steam flow was more tha n 1 0 percen t belo w th e tota l mas s stea m flo w durin g th e mos trecen tperformance test , o r (11 ) All carbon bed regeneratio n cycle s durin

g whic h th e temperatur e o f th e carbon be d afte rregeneratio n (an d afte rcompletio n of

any coolin g cycle(s) ) wa

s more tha n 10 percen t greatertha n th e carbo n be d tempera ture (i n degree s Celsius ) durin g th e mos trecentperformance test . (4 ) Wher e a n absorber , condenser , o r carbo n adsorberi s th e final recover y devic e i n th e recover

y syste m and a n organic monitorin g devic e approved b y th e Administrato ri s used , al l 3-hou r periods o f operatio n durin g which th e averag e concentratio n leve l o rreadin g o f organic compound s l n th e exhaus t gases i s mor

e tha n 2 0 percen tgreate r tha n th e exhaus tga s organi c com poun d concentratio n leve l o rreadin g measure d b y th e monitorin g devic e durin g th e mos trecen tperformance test . (h ) Eac h ownero roperato rsubjec t t o th e provisions of

thi s subpar

tan d seeking t o demonstrate complianc e wit h 160.612(c) shal l kee p up-to-date , readil y accessibl e record s of

: § 60.61 5



### (1 ) An y change s i n productio n capac ity , feedstock type , o rcatalys ttype , o r o f an y replacement , remova

l o raddi tio n o f recover y equipmen to rairoxi datio n reactors ; (2 ) An y recalculatio n o

f th e TRE Inde x valu e performed pursuantt o I 60.614(f) ; (3 ) Th e results o f

an y performance tes tperforme

d pursuan tt o th e meth od s and procedures required b y { 60.614(d) . (i ) Eac h owneran d operato rsubjec t t o th e provisions o

f thi s subparti s exemp tfro

m th e quarterl y reportin g requirement

s containe d l n 160.7(c ) o f th e Genera

l Provisions . (j ) Eac h owneror operato rtha t seek s t o compl y wit h th e requirements of thi s subpar

tb y complyin g wit h th e requirement

s o f 160.61 2 shall submi t t o th e Administrato r semiannua l re ports o f th e following ; information . Th e initial repor

tshall b e submitte d withi n 6 month s afte rth e initia l start up-date . (1 ) Exceedance s o

f monitore d pa rameters recorde

d unde r160.615(c ) and (g) . (2 ) A U period s recorde d unde r { 60.616(d) whe n th e ven tstream i s di verte d fro

m th e contro l devic e o rha s n o flow rate . (3 ) All period s recorde d unde r 160.615(e ) whe n th e boile ro rproces s heate r was no toperating . (4 ) All period s recorde d unde r 160.615(f ) I n which th e pilo tflam e o f th e flar e wa s absent . (5 ) An y recalculatio n of

th e TRE Inde x value , a s recorde d unde r 160.615(h) . (k ) Th e requirements o

f |60.616(J ) remain i n force unti l an d unles s EPA . i n delegatin g enforcemen tauthorit y t o a Stat e undersectio n 111(c) of th e Act, approves reportin g requirements o ra n alternativ e mean s of

compliance surveillance adopte d b y suc h State . I n tha tevent , affecte d source s withi n th e Stat e will be relieve d o f

th e obligatio n t o comply with |60.815(J) , provided tha tthe y comply wit h th e require ments establishe d b y th e 8tate . (1 ) Th e Administrato rwil l specif y appropriat

e reportin g an d recordkeep in g requirement

s wher e th e owne r o r operato r o

f a n affecte d facility seek s t o demonstrat

e complianc e with th e * 'A, \



# 4 A K1

60 1§ 60.61 6 standard s specifie d unde r{60.61 2 othe r tha n a s provide d unde r { 80.613(a) . (b) , (c) . an d (d) . [5 5 F R26922. Jun e 29 . 1990 ; 5 5 F R36932. Sept . 7 . 1990 ] 8 60.61 6 Reconstruction . Fo r purpose s o f

thi s subpar t"fixe d capita l cos to f

th e ne w components. " a s use d In (60.15 . Include s th e fixe d capita l cos to f

al l depreciabl e compo nent s whic h ar e o rwil l b e replace d pursuan tt o al l continuou s program s o f componen treplacemen twhic h ar e commence d withi n an y 2-yea rperio d followin g Octobe r21 , 1983 . Fo rpur pose s o f thi s paragraph , "commenced " mean s tha ta n owne ro roperato rha s undertake n a continuou s progra m o f componen treplacemen to rtha ta n owne r o r operato rha s entere d int o a contractua l obligatio n t o undertak e an d complete , withi n a reasonabl e time , a continuou s progra m o f compo nen treplacement . (Approve d b y th e Offic

e o f Managemen

t an d Budge tunde rcontrol numbe

r2060 - 0053) 0 60.617 Chemicals affected b y subpar tIII . CtwifiiCafj l rtfjma

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PNM c «rti»*ld » CA S No. * 75-07- 0 84-19- 7 S7-S4- 1 75-05- 8 9S-SS- 2 107-02- 8 79-10- 7 107-13- 1 84-85- 1 100-42- 7 66-65- 0 106-99- 0 9S-73- 7 107-92- 6 3724-66- 0 60-18- 9 106-93- O 106-94- 1 120-61- 6 107-06- 2 76-21- 6 50-00- 0 64-16- 6 107-22- 2 74-90- 6 79-31- 2 121-61- 6 106-31- 6 76-63- 3 96-83- 9 106-96- 2 65-44- 6 40CFRCh . Chemica l nam e

Tarephthali c ad d 1 (7-1-9 1 Edition ) CA S No. "

"CA S »un*« » <•*» • t o th a Chamica J Abatract

a RgMi y nufflbar a uskjno d t o apacift . i

' liainh'ala , itotnafi , o r mhTiaa a o l chanUcstt . Som a laomar a o r mMura a tha

t ar a conra d b

y U M atandard a d o no

t hava CA S numbar

a aaatana

d to tham . Th a atandard a appl y t o a « o t th e chamtcal a fetad. whatha r havabaan i CA S numbar

a hava t o r no t S 60.61 8 Delegatio n o f

authority . (a ) I n delegatin g implementatio n an d enforcemen tauthorit y t o a Stat e unde rsectio n 111(c ) o f th e Act , th e authoritie s containe d i n paragrap h (b ) o f thi s sectio n shal l b e retaine d b y th e Administrato ran d no ttransferre d t o a State . (b ) Authoritie s whic h wil l no tb e del egate d t o States : ( 60.613(e) . Subpar t JJJ—Standard s o f Perform anc e fo r Petrolew m Dry Cleaner s Bounce : 49 F R37331 . Sept . 21 . unles s otherwis e noted . 1964. 860.62 0 Applicabilit

y and designatio n o f affected facility . (a ) Th e provision s o f thi s subpar t ar e applicabl e t o th e followin g affect e d facilitie s locate d a ta petroleu m dr y cleanin g plan twit h a tota l manufac turers ' rate d drye rcapacit y equa l t o o r greate rtha n 3 8 kilogram s (8 4 pounds) : Petroleu m solven tdr y cleanin g dryers , washers , filters , stills , an d settlin g tanks . (1 ) Whe n th e affecte d facult y i s in stalle d l n a n existin g plan ttha ti s no t expandin g th e manufacturers ' rate d capacit y o f

It s petroleu m solven t dryerts) , th e tota l manufacturers ' rate d drye rcapacit y i s th e summatio n o f th e manufacturers ' rate d capacit y fo reac h existin g petroleu m solven t dryer . (2 ) Whe n th e affecte d facult y Is in stalle d l n a plan ttha ti s expandin g th e manufacturers ' rate d capacit y o f It s petroleu m solven tdryers , th e tota l manufacturers ' rate d drye r capacit y i s th e summatio n o f

th e manufacturers ' rate d drye r capacit y fo r eac h existin g an d propose d ne w petroleu m solven t dryer . 

### 60 2 Environmenta l Protectio n Agenc y (3 ) Whe n th e affecte d facllt y i s in Maile d i n a ne w plant , th e tota l manu facturers ' rate d drye rcapacit y i s th e summatio n o f

th e manufacturers ' rate d drye rcapacit y fo reac h propose d ne w petroleu m solven tdryer . (4 ) Th e petroleu m solven tdryer s considere d i n th e determinatio n o f th e tota l manufacturers ' rate d drye rca pacit y ar e thos e ne w an d existin g dryer s i n th e plan ttha twil l b e l n serv ic e a tan y tim e afte r th e propose d ne w sourc e o r modificatio n commence s op eration . (b ) An y facilit y unde rparagrap h (a ) o f thi s sectio n tha tcommence s con structio n o r modificatio n afte r Decem be r14 , 1982 , i s subjec tt o th e require ment s o f thi s subpar twit h th e follow in g exception . A drye rInstalle d be twee n Decembe r14,1982 . an d Septem be r 21 , 1984 . l n a plan twit h a n annua l solven tconsumptio n leve l o f les s tha n 4,70 0 gallons , i s exemp tfro m th e re quirement s o f

thi s subpart . [4 9 F R37331 . 8ept . 21 . 1984. a s amende d at 5 0 F R49026 . Nov. 27.1985 ] 660.62 1 Definitions . A s use d l n thi s subpart , al l term s no t define d herei n shal l hav e th e sam e meanin g give n the m i n th e Ac tan d l n subpar tA o f

thi s part . Cartridge filtermean s a discret e filte runi tcontainin g bot h filte r pape r an d activate d carbo n tha ttrap s an d remove s contaminant s fro m petroleu m solvent , togethe rwit h th e pipin g an d ductwor k use d l n th e installatio n o f thi s device . Dryermean s a machin e use d t o remov e petroleu m solven tfro m arti cle s o f clothin g o r othe rtextil e o r leathe r goods , afte r washin g an d re movin g o f

exces s petroleu m solvent , togethe rwit h th e pipin g an d ductwor k use d l n th e installatio n o f thi s device . Manufacturers'rated

dryercapacity mean s th e dryer' s rate d capacit y o f ar ticles , i n pound s o rkilogram s o f cloth in g article s pe rload , dr y basis , tha tI s typicall y foun d o n eac h drye r o n th e manufacturer' s name-plat e o r l n th e manufacturer' s equipmen tspecifica tions . Perceptible leaks mean s an y petrole u m solven tvapo ro rliqui d leak s tha t ar e conspicuou s fro m visua l observa tio n o rtha tbubbl e afte r applicatio n o f §60.62 2 a soa p solution , suc h a s pool s o r drop let s o f liquid , ope n container s o rsol vent , o r solven tlade n wast e standin g ope n t o th e atmosphere . Petroleum dry cleanermean s a dr y cleanin g facilit y tha tuse s petroleu m solven ti n a combinatio n o f washers , dryers , filters , stills , an d settlin g tanks . Settling tank mean s a containe r tha t gravimetricall y separate s oils , grease , an d dir tfro m petroleu m solvent , to gethe r wit h th e pipin g an d ductwor k use d i n th e Installatio n o f thi s device . Solven tfiltermean s a discret e sol ven tfilte r uni tcontainin g a porou s mediu m tha ttrap s an d remove s con taminant s fro m petroleu m solvent , to gethe r wit h th e pipin g an d ductwor k use d i n th e installatio n o f thi s device . Solvent recovery dryer

mean s a clas s o f dr y cleanin g dryer s tha temploy s a condense r t o condens e an d recove r sol ven tvapor s evaporate d l n a closed loo p strea m o f

heate d air , togethe r wit h th e pipin g an d ductwor k use d l n th e installatio n o f

thi s device . Still mean s a devic e use d t o volatil ize , separate , an d recove r petroleu m solven tfro m contaminate d solvent , to gethe r wit h th e pipin g an d ductwor k use d l n th e Installatio n o f thi s device . Washermean s a machin e whic h agi tate s fabri c article s i n a petroleu m sol ven tbat h an d spin s th e article s t o remov e th e solvent , togethe r wit h th e pipin g an d ductwor k use d l n th e in stallatio n o f

thi s device . S 60.62 2 Standards fo r volatil e organi c compounds . (a ) Eac h affecte d petroleu m solven t dr y cleanin g drye r tha ti s Installe d a t a petroleu m dr y cleanin g plan tafte r Decembe r14 , 1982 . shal l b e a solven t recover y dryer . Th e solven trecover y dryerts ) shal l b e properl y Installed , op erated , an d maintained . (b ) Eac h affecte d petroleu m solven t filte r tha ti s installe d a ta petroleu m dr y cleanin g plan tafte r Decembe r 14 . 1982 , sha U b e a cartridg e filter . Car tridg e filter s sha U b e draine d l n thel r seale d housing s fo r a tleas t8 hour s prio r t o thei r remova l (c ) Eac h manufacture ro f a n affect e d petroleu m solven tdrye r sha U in clud e lea k inspectio n an d lea k repai r 60 3 

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