D SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 1 o f 7 Mate r ial Safety D ata Sh e et Ve rs ion: 4.0

D SPA ‘F ixed I n s tall a tion’ G ene r ator R evisi o n da t e 2 7 /0 3 / 2 0 1 2

1. I de n t i f i c a t i o n o f t h e s u b s t a nce / p re p a r a t i on a n d th e com p a n y

P r oduct na m e and c ode: D SPA ‘F ixed I n s tall a t ion’ G ene r ator

S y nonym: DSPA 0.3 ; DSPA

- 2 / 4 ; D SPA

- 6 ; DSPA 7/1,

- 7/2;

D SP A

- 8 / 1,

- 8 / 2 ; DSPA

- 11 / 1

, - 11 / 2

, - 11 / 3

, - 11 / 4,

- 11 / 5

, - 1 1 /6

Mate r ial uses: C an b e u s ed for ope r a ti onal a p pl i c a t ion d u r ing lo c al i z ation

and e x ti n guish i ng fi r e of c lass A, B and C , loc a l i z ation

of fi r e of c lass A in c l o s ed s paces up, a nd e l e c t r ical

fi r es( v oltage < 40 k V) a

. o. indust r ial bu i ld i ngs, r ai l r oad,

and v ehic l e t r an s po r t.

Identif i c ation c omp a ny : D SP A. nl B

. V.

H ulzen s e w eg 1 0 2 0

6 5 34 AN N i j m ege n

- NL

P .O . Box 6 5 72

6 5 03 G B N i j meg e n

- NL

T he N et h e r lands

T el: + 3 1 ( 0 ) 24 35 22 5 7 3

F ax: +3 1 ( 0 ) 2 4 3 7 8 7 5 8 3

Mai l : i n fo @ d s pa

. nl

Website : w ww

. d s pa

. nl

Eme r gency te l epho n e no. T el: + 3 1 ( 0 ) 3 0

– 2748888 , o n l y f o r t h e d o ct o r.

N ati o nal Poi s ons Info r ma t ion C e nt r e U t r echt, T he N eth e r

lands

2. H a z a r d s i d e n t i f i c a t i o n

T he p r epa r ation is not c las s if i ed ac c o r ding to D i r ective 1 9 9 9 / 4 5 / EC or D i r ective

6 7 / 5 4 8 /E E C a n d its a mend m ents.

R ema r k: C ont e nt of t h e D SPA G ene r ator c onsist of s o l id bloc k s

that a r e not f r iab l e a n d a r e c ontained in a r i gid s teel

c asing. D u r ing no r m al t r anspo r t, s to r age and handl i ng,

the c ontents c an n ot c o m e into c ontact w ith a c o mbustib l e

mate r ial

If D SPA G ene r ator is activated exposu r e to ae r o s ol s u p

p r e ss ion agent m ay c ause tempo r a ry , mi l d i rr i tation o f

mucous m emb r ane if i n h aled.

When usi n g and ha n dl i n g in ac c o r dance w ith t h e r egu l a

tions the un d ama g ed fi r e extingu i s h er does not p r esent

any heal t h d a nge rs

.D SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 2 o f 7 3. C ompo s i t i on / Info r m a t i on on i n g re d i en t s

H aza r dous i ng r edi e nts

Ing r edient % w eight C AS# E G # C las s if i c a tion

Pota ss ium nit r ate >50 775 7

- 7 9

- 1 231

- 818

- 8 O ; R 8

Phenol f o r mal d ehyde,

N ovolac r es i n 5

- 15 N /A N /A Xi; R 3 6, R 37

4. Fir s t ai d m e as u r e s

G ene r al: Seek medic a l advice in c ase of sy mptoms w hich a r e

obviously d ue to inh a lat i o n of c o m bustion ga ss es.

Inhala t ion: R emove to f r esh ai r

. I f not b r eat h ing, if b r e athing is

i rr egular or if r espi r ato r y a rr est oc c u r s p r ovide a r tif i c i a l

r espi r ation or ox y g en by t r ained pe rs onnel. G ive noth i ng

by mouth. If u n c ons c i ou s , place in r ecove r y posit i on and

s eek medic a l ad v i c e

Ingestion: If s w al l o w ed, w a s h out mouth w i t h plenty of w ate r

. D o

not induce v omi t ing. Ke e p at r est and s eek medical a d

v ice.

E y e c ontact: R emove po ss i b le con t act lense s

. C o nta m inat i on o f the

eyes must b e t r eated by tho r ough i rr igat i on w i t h w ater

for 1 5 minu t es, w i t h the e y el i ds h eld open. D o not r ub

or scr atch e y es. A do c t o r (or e y e s pecia l ist) s h ould be

c onsulted im m edia t ely.

S k in conta c t: R inse w i t h pl e nty of w a t er for at least 15 m i nu t es. R e

move any c o nta m inat e d c loth i ng or c ontact lens e s

.

5. Fire f i g ht i n g m e a s ur e s

E x tingu i s h i ng m edia N O N E

– T H IS IS AN E X T I N G U I S H I N G A G ENT

T he D SPA

- 5 G ene r a t or c an be used by fi r e d e pa r tments

as fi rs t r esponder to s upp r ess fi r es, w ater must be used

as an a d dit i o nal s u pp r e ss ion ag e nt.

Spe c ial h aza r ds a cc o r di n g s ubstance or p r epa r at i on itself, c o mb u s t i on p r o d ucts or r e

s ulting gases: C om b ustion p r oducts m ay include: c a r b o n m o noxi d e,

c arbon dioxi d e, ae r osol and s moke.

P r otection of fi r e

- f i ghte r s: F i r emen have to w ear s el f

- c on t ained b r eath i ng a ppa r atus

and c om p lete p r otective c loth i ng when en tering burning

structure

.D SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 3 o f 7 6. Acci d e n t a l re l e a s e me a s u res

Pe rs onal p r ecau t ions: Elim i n ate all s ou rc es of heat a nd i gnit i on. Pe o p l e dea l i n g

w ith major s p i l l ages s h ould w ear pe rs on a l p r otective

c lo t hing ( s uita b le g l oves and f i lter mask FF P

- 2 if dust

is fo r med).

En v i r onmen t al p r ecau t ion s : D o not dis c ha r ge i nto d r ains or s e w e rs

. If s ign i fica n t

quanti t ies a r e bei n g r el e ased in the envi r o n men t

, info r m

the au t ho r it i es ac c o r d i ng to the local r u l es.

C lean

- up meth o ds: Imp r oper dis c ha r ge c ould r esult in the deposit of s mal l

,

localized a r eas o f hig h ly c oncent r ated ag g lo m e r ated p a r

ticulate on t hat s u r

face. If left unt e nded, a n a g g l ome r at e d

mass may t ake on moistu r e a n d may c au s e non

p r og r es s ive s u r

face dis c o l o r ation of unp r otec t ed m etal s u r

faces. Any agglomerated pa r ticulate must be c l e aned up

w ith a w ate r /alc o hol s o l ution no l a ter than 24 h ou r s f o l

lo w i ng a dis c ha r g e

. C o ll ect s pi l led m a te r ial by h and, e

. g.

w ith a d ustpan a n d d u s t er or a v acuum c leane r

. C ol l ect

the w aste p r oduct i n s uitab l e d r ums for dis p osal. Wa s h

the s pi l lage a r ea c le a n w ith plenty of w ate r

.

7. H a n d l i ng a n d s to r a g e

H and l ing: When h andl i ng ob s e rv e the usual p r ecaut i ona r y measu r es

for c hemicals. A v oid c ontact w ith heat, s pa rks

, flames

and other ig n it i on s o u rc es. D o not use e q ui pm ent p r o

du c ing an o pen f lame o r electri c al e qui p ment w hich m a y

c ause s pa rks . P r event dust fo r mation a n d inh a lat i on o f

dust. If i ntense ae r osol is r eleas e d f r om a d r y s p r inkler

po w der sys t e m, r espi r ato r y p r ot e c tion is r equired.

Sto r age Sto r e in ac c o r dance w ith local r egula t ions. Sto r e in o r i g i

nal D SPA pac k agi n g at r oom t empe r a t u r e. P r event p r o d

uct tem p e r atu r es above 7 5 °C a nd b e l o w

- 50 ° C

. K e e p

a w ay f r om heat s ou rc es. P r oduct is hyd r os c op i c ; p r event

c ontact w ith o ther l i q uid s

.

Spe c if i c u s e( s ): E x tingu i s h i ng ma t e r ial in c ase of a fi r e. O nly use in

c ombi n a t ion w ith the ign i t ion device of D SP A

.D SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 4 o f 7 8. Ex p o s u r e c o nt r o l s

– P e r s o n a l p r otec t io n

Lim i ts o f e x posu r e: N o oc c upa t ion a l exposu r e l i mits a r e d e te r min e d for the

p r epa r ation an d /or for the c ompo n ents. After activati n g

the D S PA, as dense ae r osol or du s t is fo r med.

G ene r al p r otective and

Hygienic measu r es: T he u s ual p r ecautio n a r y measu r es a r e to be a d h e r ed to

w hen han d l i ng c h emic a ls.

R espi r ato r y p r otec t ion: R equired a t inad e quat e ly v enti l ated w o rk place s

. As r esp i r

able d ust i n c ase of ap pl i c ati o n of the ma t e r ial as ext i n

guishing m ate r ia l

, use r espi r ato r y p r otection ( FF P

- 2

mask EN14 9 : 2 0 0 1 ).

Sk i n a n d b o d y : W ear s uitab l e p r otective c loth i ng (p r e f e r able h e avy c otton

or di s po s a b l e c o v e r a l l ) a n d e y e / f a c e p r o te c t i on

.

H ands: Wash hands befo r e b r e a k s and at the end of w o rk

.

P r o te c tive g l ove s o f neop r en e o r buty l r ubbe r sho u l d b e w o r n w h e n

ha n d l i n g wi t h th e p r oduct

. U s e hea t

- r es i st a n t g l ove s f o r h a n dl i n g a s

e x t in g u i s h in g ma te r i al i n c a s e of a f i r e.

E y es: U s e s afety ey e w ear (ti g ht fitt i ng g o ggles) or a ful l

- fa c e

s hie l d. E y e – w ash.

9. P h y s i c a l a n d ch e mi c a l p r op e r t i e s

G ene r al in f o r mati o n:

Appea r ance: Solid, p r es s ed c o mpo u nd in rig i d s teel c a s in g

.

O dou r : N one

Impo r tant heal t h, s afety and en v i r o n men t al i n fo r m ation.

p H : N /A

Boil i ng po i nt: N /A

F lash point: N /A

E x plosive p r ope r t i es: N /A

Vapour p r es s u r e: N ot a v a i l a b le. R ela t ive

d e nsity: 1

, 9 ( w ater = 1 ).

Solubi l ity in w a t e r : N ot v e r y s ol u ble(< 1 % )

Auto a c tiva t ion t empe r a tu r e: > 2 70°C

10. St a b i l i ty a nd r e a ct i v i t y

Stabil i ty N ot s el f

- r eactive s ubst a nce. Stable u n der r ecommen d e d

s to r age and han d l i ng c on dit i ons.

C ond i tions t o a v o i d A v oid high t e m pe r atu r es, heating, open fi r e a n d ig n ition

s ou rc es, and p r event the effects of a g r ind i n g motion

and i m pact fo rc es t h at may r esult i n ig n ition.

Mate r ia l s t o a v o i d: U pon dism a ntl i n g an int a c t gene r ato r , the c onten t s s hall

be t r eated as an oxid i z in g mate r i a l.D SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 5 o f 7 11. T o xi c o l o g i c a l i nf o rm a t i o n

A c ute to x icity f r om t h e c ompon e nts:

P r oduct inform a tion: Pota ss ium nit r ate, C AS# 7 7 57

- 7 9

- 1.

L D 50 (o r al, r at): 3

. 0 1 5 mg/ k g.

P r oduct inform a tion: Phenol f o r mal d ehyde, N o v olac r esin C AS# N /A.

L D 50 (o r al, r at): > 2. 0 0 0 mg/ k g.

L D 50 ( d e r mal, r abb i t): > 2. 0 0 0 mg/ k g.

F u r ther informati o n: When usi n g and ha n dl i n g in ac c o r dance w ith t h e r egu l a

tions the und a maged g ene r ator does n ot p r e s ent any

health da n ge rs . After a c tivating the gene r ato r

, s l i g htly i r r i

tations to sk in due to inc r ease of the pH v alue and

s l i ghtly i rr itat i on of r e s pi r a t o r y due to an i nc r ease of

s moke(ae r osol).

12. Eco l o g i c a l i nf o r m a t i o n

E c olog i c al ha z a r ds a r e n ot p r esent a t un d ama g ed gene r ato r

.

E c otoxicity f r om the c om ponents.

P r oduct inform a tion: Pota ss ium nit r ate, C AS# 7 7 57

- 7 9

- 1.

L C 5 0 : 2 2, 5 mg/l ( 9 6 h r s , g a mbusia affin i s

EC5 0 : 2 2 6 mg/l ( 7 2 h rs , da p hnia m agna, cr ustacea

P r oduct inform a tion: Phenol f o r mal d ehyde, N o v olac r esin C AS# N /A.

N o e c o log i c a l data on th is c ompo n ents a r e k n o w n.

Pe rs isten c e / d e g r adab i l i t y : Fr om the co m pone n ts p o or biolo g ically d eg r ada b l e

.

WG K : 1 (Wa ss e r gefäh r du n gs k las s e or w ater p o l l ut io n c las s

,

G e r man Wa t er R es o u rc es A c t

. , li m it e d w ater po l l u tant).

O ther informa t ion

Oz one D e plet i on P o tent i a l ( O D P) = 0

G lobal Wa r ming Pote n tia l ( G WP) = 0

13. D i s p o s a l c on d i t i ons

With i n the p r es e nt k n o w l edge of the s u p pl i e r

, th i s p r oduct is not r ega r d e d as haza r d

ous w aste, as def i ned by D i r ective 9 1 / 6 8 9 / EC. C o m ply w i th all l o c al, s tate and

fede r al/in t e r nati o nal r eg ul ations.D SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 6 o f 7 14. T r a n s p o rt in fo r m a t i on

C las s if i c a tion as A D R / R I D m a te r ial f or r oad t r an s po r t.

U N num b e r : 3178

P r oper s hipp i n g n a me: F lam m a b le S o l i d, Ino r g an ic, n

. o

. s

AD R / R I D c las s : 4.1

ADR Lab e l:

Pa ck aging g r oup: II

H aza r d I D : 40

R ema rk : Method of p ac k aging P 0 02

C las s if i c a tion as I M D G m ate r ial for s ea t r anspo r t.

U N num b e r : 3178

P r oper s hipp i n g n a me: F lam m a b le S o l i d, Ino r g an ic, n

. o .s

.

IM D G C las s : 4

. 1

Ma r ine P o l l ut a nt: No

EmS: F

- A

, S

- G

C las s if i c a tion as I C A O /I A T A m ate r ial for air t r an s po r t.

U N num b e r : 3178

P r oper s hipp i n g n a me: F lam m a b le S o l i d, Ino r g an ic, n

. o .s

.

I C A O /IA T A C las s : 4

. 1

Pa ss enger

Pa ck ing inst r uct i on: 415

Maxim u m qu a ntity: 15 k g

C a r go

Pa ck ing inst r uct i on: 417

Maxim u m qu a ntity: 50 k g

F u r ther informati o n: D ivi s ion 4

. 1 a r ticles p r e s ent no s i gni f icant h aza r d as

p r ope r ly pa ck aged for t r a nspo r t.

15. R egu l a t o ry i n f or m a t i on

EU D i r ective: T his p r epa r ation is not c las s if i ed as d a nge r ous ac c o r ding

D i r e c tive 1 9 9 9 / 4 5 / EC o r D i r ective 6 7 / 5 4 8 /EC and its

amen d ments.

H aza r dous sy m b ol: N one

EU l a bel l i ng c las s i ficati on : N one

R

– ( r is k ) ph r ase s : N one

Safety ph r ases S 1 5: Keep a w ay f r om h eat

S 3 5: T his mate r ial and i ts c ontainer must be di s posed of

in a safe w ayD SPA. n l BV, T h e N e t h erla n d s

D SPA ‘F i x e d I n stall a ti o n ’ G e n erat o r C o n f o r m EC 1 9 0 7 / 2 0 0 6 P a g e 7 o f 7 16. Other i n f or m a t i on

List of r ele v ant R

- a nd S

- ph r ases r efe rr ed to u n der head i ngs 2 a n d 3:

R 8

- C on t act w ith c o m b ustib l e mate r i a l m ay c au s e fi r e.

R 3 6 : I rr itat i ng to e y es

R 3 7 : I rr itat i ng to r espi r a t o r y sys tem

H isto ry : D ate of p r evious is s ue 1 2 Oc tober 2 0 10

Ve rs ion 3.0

T he data giv e n h e r e is based o n c u rr ent k n o w l e dge a nd e x pe r ience. T h e pu r pose o f

this Sa f ety D ata She e t is to des c r ibe the p r oducts i n te r ms o f their s afe t y

r equirements. T he d a ta does not s i gnify any w a rr anty w i t h r ega r d to the p r oduct ' s

p r ope r ties. In all c ases, it is the r esponsib i l i ty of the user to dete r mine th e

appl i c a b i l ity o f s uch in f o r mation a nd r eco m me n datio n s a nd the s uita b i l i ty of a n y

p r oducts for its o w n pa r ticular pu r pose.