## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

1 / 9 This SDS adheres to the standards and regulatory re quirements of the United States and may not meet th e regulatory

requirements in other countries.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name :

MSDS Number : 13 0 0 00 1 1 58 30

Manufacturer : DuPont

10 0 7 Market Street

Wilmington, DE 19898

Product Information : 1- 8 00

- 4 4 1- 7 5 15 (outside the U.S. 1-302-774-1000)

Medical Emergency : 1- 8 00

- 4 4 1- 3 6 37 (outside the U.S. 1-302-774-1139)

Transport Emergency :

Other information : For Research and Development purposes only. Must be handled only under

the direct supervision of a technically qualified i ndividual.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

THE TOXICOLOGICAL PROPERTIES OF THIS CHEMICAL HAVE NOT BEEN FULLY CHARACTERIZED IN

HUMANS. LABORATORY CONTROL SYSTEMS AND WORK PRACTI CES SHOULD BE IN PLACE TO

MINIMIZE THE POTENTIAL FOR INHALATION EXPOSURE, SKI N CONTACT, EYE CONTACT, OR

INGESTION.

Potential Health Effects

Skin

Propan-2-ol : Prolonged or repeated contact may dry skin and caus e irritation.

Eyes

Propan-2-ol : May cause: Eye irritation, Discomfort, tearing, Blu rred vision.

Inhalation

Propan-2-ol : May cause respiratory tract irritation. Inhalation of high vapour

concentrations can cause CNS-depression and narcosi s.

Ingestion



### Print date: 5 - 29 - 2012 *Will update MSDS after all toxicity reports issue.

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

2 / 9 Propan-2-ol : Effects due to ingestion may include: Gastrointesti nal disturbance,

Incoordination, Lethargy, Aspiration hazard if swal lowed - can enter lungs

and cause damage..

Repeated exposure

Propan-2-ol : Adverse effects from repeated inhalation may includ e: Central nervous

system depression lung effects Liver effects Kidne y effects Spleen

effects

Target Organs

Propan-2-ol : Respiratory Tract Central nervous system

Carcinogenicity

None of the components present in this material at concentrations equal to or greater than 0.1% are li sted by

IARC, NTP, or OSHA, as a carcinogen.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Concentration

Water 7 73 2

- 1 8- 5 4 1 - 56 %

Propan-2-ol 6 7- 6 3- 0 1 8 - 23 %

Fluorinated alkyl phosphate salt 3 2 - 36 %

SECTION 4. FIRST AID MEASURES

Skin contact : Wash off immediately with soap and plenty of water. Wash contaminated

clothing before re-use.

Eye contact : Rinse immediately with plenty of water for at least 15 minutes. Seek medical

advice.



### Print date: 5 - 29 - 2012

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

3 / 9 Inhalation : Move to fresh air. Oxygen or artificial respiration if needed. Symptoms may be

delayed. Call a physician immediately.

Ingestion : Call a physician or poison control centre immediate ly. If swallowed, DO NOT

induce vomiting unless directed to do so by medical personnel. Never give

anything by mouth to an unconscious person.

General advice : When symptoms persist or in all cases of doubt seek med ical advice.

SECTION 5. FIREFIGHTING MEASURES

Flammable Properties

Flash point : 26 °C (79 °F)

Thermal decomposition : > 200 °C (> 392 °F)

To avoid thermal decomposition, do not overheat.

Thermal decomposition can lead to release of irrita ting gases and vapours.

Fire and Explosion Hazard : The product itself does not burn. Hazardous decompo sition products formed

under fire conditions. Hazardous combustion product s: Hydrogen fluoride

Carbon dioxide (CO2) Carbon monoxide Other hazardou s decomposition

products may be formed.

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and

the surrounding environment.

Firefighting Instructions : Wear self contained breathing apparatus for fire fi ghting if necessary.

Evacuate personnel to safe areas. Do not allow run -off from fire fighting to

enter drains or water courses.

SECTION 6. ACCIDENTAL RELEASE MEASURES

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (P ERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT d uring clean-up.

Safeguards (Personnel) : Evacuate personnel to safe areas. Use personal prot ective equipment.

Ventilate the area.

Spill Cleanup : Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid

binder, universal binder, sawdust). Pick up and tra nsfer to properly labelled



### Print date: 5 - 29 - 2012 **MSDS is being updated with correct

flash point of 40 °C (105 °F)

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

4 / 9 containers.

Accidental Release Measures : Do not discharge to streams, ponds, lakes or sewers . Avoid subsoil

penetration.

SECTION 7. HANDLING AND STORAGE

Handling (Personnel) : Avoid formation of respirable particles. Do not bre athe vapor or mist. Avoid

contact with skin, eyes and clothing.

Wash hands before breaks and immediately after hand ling the product. Wash

contaminated clothing before re-use.

Handling (Physical Aspects) : To avoid thermal decomposition, do not overheat. Th ermal decomposition

can lead to release of irritating gases and vapours

. Do not spray near open flame or heated surface.

Storage : Keep tightly closed in a dry, cool and well- ventilated place.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls : Use only in area provided with appropriate exhaust ventilation. Use an airless

flow type of spray applicator. Keep spraying pressu re below 60 psi.

Personal protective equipment

Respiratory protection : In case of mist, spray or aerosol exposure wear sui table personal respiratory

protection and protective suit.

Hand protection : Additional protection: Impervious gloves

Eye protection : Wear safety glasses or coverall chemical splash gog gles.

Skin and body protection : Lightweight protective clothing

Exposure Guidelines

Exposure Limit Values

Propan-2-ol

PEL: (OSHA) 4 00 ppm 9 8 0 mg/m3 8 hr. TWA



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## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

5 / 9 TLV (ACGIH) 2 00 ppm TWA

TLV (ACGIH) 4 00 ppm STEL

AEL * (DUPONT) 2 00 ppm 8 & 12 hr. TWA

Biological Exposure Indices

Propan-2-ol

BEI ( ACGIH ) 4 0 mg/l Acetone/Urine

Sampling time: End of shift at end of work week.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form :

Color :

Odor :

pH : Melting point :

Boiling point :

% Volatile : Density :

SECTION 10. STABILITY AND REACTIVITY

Stability : Stable under normal conditions.

Conditions to avoid : To avoid thermal decomposition, do not overheat.

Hazardous decomposition

products : Carbon dioxide

, Carbon monoxide

, Hydrofluoric acid...%

Incompletely burned carbon products



### Print date: 5 - 29 - 2012

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

6 / 9 Other hazardous decomposition products may be forme d.

SECTION 11. TOXICOLOGICAL INFORMATION

Propan-2-ol

Dermal LD50 : 12 ,900 mg/kg , rabbit

Oral LD50 : 4,700 mg/kg , rat

Gastrointestinal effects

Kidney effects

Inhalation 4 h LC50 : 39 .3 mg/l , rat

Target Organs: Respiratory Tract, Central nervous s ystem

Respiratory tract damage

Central nervous system depression

Skin irritation : Mild skin irritation, rabbit

Eye irritation : Eye irritation, rabbit

Skin sensitization : There are no reports of human skin sensitization.

Repeated dose toxicity : Inhalation

Target Organs: Central nervous system, Respiratory Tract

Central nervous system effects, Liver effects, Kidn ey effects, lung

effects, Spleen effects, Testes

Oral

Liver enlargement, Kidney enlargement, Adrenal effe cts

Dermal

Drying of skin, Weight loss, Organ weight changes

Carcinogenicity : Animal testing did not show any carcinogenic effect s.

Mutagenicity : Did not show mutagenic effects in animal experiment s.

Tests on bacterial or mammalian cell cultures did n ot show mutagenic

effects.

Reproductive toxicity : Evidence suggests the substance is not a reproducti ve toxin in

animals.



### Print date: 5 - 29 - 2012

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

7 / 9 Teratogenicity : Animal testing showed effects on embryo-fetal devel opment at levels

equal to or above those causing maternal toxicity.

SECTION 12. ECOLOGICAL INFORMATION

Aquatic Toxicity

Propan-2-ol

9 6 h LC50 : Pimephales promelas (fathead minnow) 3,200 mg/l

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal : In accordance with local and national regulations.

SECTION 14. TRANSPORT INFORMATION

DOT UN number : 1 99 3

Proper shipping name : Flammable liquids, n.o.s. (Isopropanol)

Class : 3

Packing group : III

Labelling No. : 3

Reportable Quantity : 1 00 lbs Propan-2-ol

IATA_C UN number : 1 99 3

Proper shipping name : Flammable liquid, n.o.s. (Isopropanol)

Class : 3

Packing group : III

Labelling No. : 3

Consult applicable regulation handbook for addition al requirements.

IMDG UN number : 1 99 3



### Print date: 5 - 29 - 2012

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

8 / 9 Proper shipping name : FLAMMABLE LIQUID, N.O.S. (Isopropanol)

Class : 3

Packing group : III

Labelling No. : 3

SECTION 15. REGULATORY INFORMATION

TSCA : FOR LABORATORY R&D SAMPLES ONLY:

One or more components of this product is not liste d on EPA's Toxic

Substances Control Act (TSCA) Chemical Inventory. T herefore, until

this/these components get listed through PreManufac ture Notification, this

product should only be used for TSCA-excluded appli cations or under the

requirements of the TSCA R&D Exemption (40CFR 720.3 6)

SARA 313 Regulated

Chemical(s) : Propan-2-ol

CERCLA Reportable

Quantity : 435 lbs

Based on the percentage composition of this chemica l in the product.:

Propan-2-ol

California Prop. 65 : Chemicals known to the State of California to cause cancer, birth defects or

any other harm: none known

PA Right to Know

Regulated Chemical(s) : Substances on the Pennsylvania Hazardous Substances List present at

a concentration of 1% or more (0.01% for Special Ha zardous

Substances): Propan-2-ol

NJ Right to Know

Regulated Chemical(s) : Substances on the New Jersey Workplace Hazardous Su bstance List

present at a concentration of 1% or more (0.1% for substances

identified as carcinogens, mutagens or teratogens): Propan-2-ol

SECTION 16. OTHER INFORMATION



### Print date: 5 - 29 - 2012

## Material Safety Data Sheet

Version 2

. 0

Revision Date 03/02/2012 Ref. 130000115830

9 / 9 The DuPont Oval Logo is a registered trademark of E .I. du Pont de Nemours and Company.

Contact person : MSDS Coordinator, DuPont Chemicals and Fluoroproduc ts, Wilmington, DE

19 89 8, (800) 441-7515

The information provided in this Safety Data Sheet is correct to the best of our knowledge, informatio n and belief at

the date of its publication. The information given is designed only as a guidance for safe handling, u se, processing,

storage, transportation, disposal and release and i s not to be considered a warranty or quality specif ication. The

information relates only to the specific material d esignated and may not be valid for such material us ed in combination

with any other materials or in any process, unless specified in the text.

Significant change from previous version is denoted with a dou ble bar.



### Print date: 5 - 29 - 2012