Filename: C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL

Test date: 5/4/10-5/5/10

Control device: None

Gas Volum. Emission Process

Run Test O2

 conc., volume, flow rate, Mass, Concentration, rate, rate, Emission factor,

Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 g/hr ton/hr g/ton g/lb

CDD/CDF 1 M23 16.0 148.5 5,222 640.84 6.66E-08 152.393 432.30 1.35E-03 #REF! #REF!

2 16.3 140.7 5,335 531.37 5.83E-08 133.339 402.92 1.21E-03 #REF! #REF!

3 16.1 143.7 5,465 555.14 5.96E-08 136.369 394.90 1.27E-03 #REF! #REF!

Average 16.1 5,341 6.15E-08 140.700 410.04 1.28E-03 #REF! #REF!

TEQ 1 16.0 148.5 5,222 10.4592 1.09E-09 2.487 7.056 2.21E-05 #REF! #REF!

2 16.3 140.7 5,335 7.5150 8.24E-10 1.886 5.698 1.71E-05 #REF! #REF!

3 16.1 143.7 5,465 7.1406 7.67E-10 1.754 5.080 1.63E-05 #REF! #REF!

Average 16.1 5,341 8.93E-10 2.042 5.944 1.85E-05 #REF! #REF!

Notes: 

Kiln 2-Emission Calcs 1 of 1 12/1/2014
DIOXIN-FURAN PARTICLE CATCH

Kiln 2

Measured wt, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

Total TCDD 58.8 42.6 42.5 Total TCDD 58800 42600 42500 Total TCDD 58800 42600 42500

Total PeCDD 73.4 50.5 51.6 Total PeCDD 73400 50500 51600 Total PeCDD 73400 50500 51600

Total HxCDD 59.4 55.8 57.2 Total HxCDD 59400 55800 57200 Total HxCDD 59400 55800 57200

Total HpCDD 88.7 59 62.5 Total HpCDD 88700 59000 62500 Total HpCDD 88700 59000 62500

Total OCDD 359 322 340 Total OCDD 359000 322000 340000 Total OCDD 359000 322000 340000

Total dioxins 639.3 529.9 553.8

Total TCDF 0.626 0.761 0.709 Total TCDF 626 761 709 Total TCDF 626 761 709

Total PeCDF 0.517 0.426 0.366 Total PeCDF 517 426 366 Total PeCDF 517 426 366

Total HxCDF 0.151 0.189 0.156 Total HxCDF 151 189 156 Total HxCDF 151 189 156

Total HpCDF 0.156 0.0939 0.106 Total HpCDF 156 93.9 106 Total HpCDF 156 93.9 106

Total OCDF 0.0862 0 0 Total OCDF 86.2 69.0 69.0 Total OCDF 86.2 < R 69.0 < M, R 69.0

Total furans 1.5362 1.4699 1.337

TOTAL CDD/CDF 640.836 531.37 555.137

Measured wt, ng TEQ, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

2,3,7,8 TCDD 2.32 1.63 1.76 2.32 1.63 1.76 1 2,3,7,8 TCDD 2320 1630 1760 2,3,7,8 TCDD 2320 1630 1760

1,2,3,7,8 PeCDD 5.78 4.18 4.04 5.78 4.18 4.04 1 1,2,3,7,8 PeCDD 5780 4180 4040 1,2,3,7,8 PeCDD 5780 M 4180 M 4040

1,2,3,4,7,8 HxCDD 2.5 1.81 1.62 0.25 0.181 0.162 0.1 1,2,3,4,7,8 HxCDD 2500 1810 1620 1,2,3,4,7,8 HxCDD 2500 1810 1620

1,2,3,6,7,8 HxCDD 3.7 2.66 2.71 0.37 0.266 0.271 0.1 1,2,3,6,7,8 HxCDD 3700 2660 2710 1,2,3,6,7,8 HxCDD 3700 2660 2710

1,2,3,7,8,9 HxCDD 12.3 8.79 5.11 1.23 0.879 0.511 0.1 1,2,3,7,8,9 HxCDD 12300 8790 5110 1,2,3,7,8,9 HxCDD 12300 8790 M 5110

1,2,3,4,6,7,8 HpCDD 36 24.9 26.4 0.36 0.249 0.264 0.01 1,2,3,4,6,7,8 HpCDD 36000 24900 26400 1,2,3,4,6,7,8 HpCDD 36000 24900 26400

Total OCDD 359 322 340 0.1077 0.0966 0.102 0.0003 Total OCDD 359000 322000 340000 OCDD 359000 322000 340000

Total 10.4177 7.4816 7.11

Measured wt, ng TEQ, ng

2,3,7,8 TCDF 0.0523 0.0649 0.055 0.00523 0.00649 0.0055 0.1 2,3,7,8 TCDF 52.3 64.9 55.0 2,3,7,8 TCDF M 52.3 M 64.9 55.0

1,2,3,7,8 PeCDF 0.0461 0.0327 0.0329 0.00138 0.00098 0.00099 0.03 1,2,3,7,8 PeCDF 46.1 32.7 32.9 1,2,3,7,8 PeCDF 46.1 32.7 32.9

2,3,4,7,8 PeCDF 0.0637 0.0506 0.0464 0.01911 0.01518 0.01392 0.3 2,3,4,7,8 PeCDF 63.7 50.6 46.4 2,3,4,7,8 PeCDF 63.7 50.6 46.4

1,2,3,4,7,8 HxCDF 0.0407 0.0219 0.018 0.00407 0.00219 0.0018 0.1 1,2,3,4,7,8 HxCDF 40.7 21.9 18.0 1,2,3,4,7,8 HxCDF M 40.7 M 21.9 < M, J, R 18.0

1,2,3,6,7,8 HxCDF 0.0522 0.0331 0.0359 0.00522 0.00331 0.00359 0.1 1,2,3,6,7,8 HxCDF 52.2 33.1 35.9 1,2,3,6,7,8 HxCDF M 52.2 M 33.1 M 35.9

2,3,4,6,7,8 HxCDF 0.0334 0.026 0.0231 0.00334 0.0026 0.00231 0.1 2,3,4,6,7,8 HxCDF 33.4 26.0 23.1 2,3,4,6,7,8 HxCDF M 33.4 26.0 M 23.1

1,2,3,7,8,9 HxCDF 0.0203 0.0186 0.0178 0.00203 0.00186 0.00178 0.1 1,2,3,7,8,9 HxCDF 20.3 18.6 17.8 1,2,3,7,8,9 HxCDF M 20.3 M, J 18.6 M, J 17.8

1,2,3,4,6,7,8 HpCDF 0.0539 0.029 0.0302 0.00054 0.00029 0.0003 0.01 1,2,3,4,6,7,8 HpCDF 53.9 29.0 30.2 1,2,3,4,6,7,8 HpCDF M 53.9 29.0 30.2

1,2,3,4,7,8,9 HpCDF 0.0512 0.0436 0.0402 0.00051 0.00044 0.0004 0.01 1,2,3,4,7,8,9 HpCDF 51.2 43.6 40.2 1,2,3,4,7,8,9 HpCDF M 51.2 M 43.6 40.2

Total OCDF 0.0862 0.069 0.069 2.6E-05 2.1E-05 2.1E-05 0.0003 Total OCDF 86.2 69.0 69.0 OCDF 86.2 < R 69.0 < M, R 69.0

Total 0.04146 0.03336 0.03061

TOTAL CDD/CDF (TEQ) 10.4592 7.51496 7.14061

√ 7/17/12 √ 7/17/12 √ 7/17/12

M Indicates that a peak has been manually integrated

J Indicates that a target analyte was detected below the LQL

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion.

Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Kiln 2-D-F Data 12/1/2014
Filename: C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL

Test date: 5/6/10-5/7/10

Control device: Wet scrubber

Gas Volum. Emission Process

Run Test O2

 conc., volume, flow rate, Mass, Concentration, rate, rate, Emission factor,

Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 g/hr ton/hr g/ton g/lb

CDD/CDF 1 M23 19.1 130.4 20,184 123.47 1.46E-08 33.422 258.09 1.15E-03 #REF! #REF!

2 19.1 133.3 20,278 122.42 1.42E-08 32.421 250.36 1.12E-03 #REF! #REF!

3 19.1 134.4 20,127 98.83 1.13E-08 25.967 200.52 8.88E-04 #REF! #REF!

Average 19.1 20,196 1.34E-08 30.603 236.32 1.05E-03 #REF! #REF!

TEQ 1 19.1 130.4 20,184 0.4413 5.22E-11 0.119 0.922 4.10E-06 #REF! #REF!

2 19.1 133.3 20,278 0.4653 5.39E-11 0.123 0.952 4.25E-06 #REF! #REF!

3 19.1 134.4 20,127 0.3785 4.35E-11 0.099 0.768 3.40E-06 #REF! #REF!

Average 19.1 20,196 4.98E-11 0.114 0.881 3.91E-06 #REF! #REF!

Notes: 

Spray Dryer 1-Emission Calcs 1 of 1 12/1/2014
DIOXIN-FURAN PARTICLE CATCH

Spray Dryer 1

Measured wt, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

Total TCDD 1.97 2.3 2.16 Total TCDD 1970 2300 2160 Total TCDD 1970 2300 2160

Total PeCDD 3.15 3.53 3.2 Total PeCDD 3150 3530 3200 Total PeCDD 3150 3530 3200

Total HxCDD 4.87 4.95 3.78 Total HxCDD 4870 4950 3780 Total HxCDD 4870 4950 3780

Total HpCDD 8.45 7.62 5.67 Total HpCDD 8450 7620 5670 Total HpCDD 8450 7620 5670

Total OCDD 105 104 84 Total OCDD 105000 104000 84000 Total OCDD 105000 104000 84000

Total dioxins 123.44 122.4 98.81

Total TCDF 0.0014 0.0018 0.0013 Total TCDF 1.4 1.8 1.3 Total TCDF < 1.4 < 1.8 < 1.3

Total PeCDF 0.0016 0.002 0.0016 Total PeCDF 1.6 2.0 1.6 Total PeCDF < 1.6 < 2.0 < 1.6

Total HxCDF 0.0017 0.0016 0.00091 Total HxCDF 1.7 1.6 0.91 Total HxCDF < 1.7 < 1.6 < 0.91

Total HpCDF 0.0023 0.0019 0.0015 Total HpCDF 2.3 1.9 1.5 Total HpCDF < 2.3 < 1.9 < 1.5

Total OCDF 0.0203 0.012 0.014 Total OCDF 20.3 12 14 Total OCDF J 20.3 < M, J, R 12 < J, R 14

Total furans 0.0273 0.0193 0.01931

TOTAL CDD/CDF 123.467 122.419 98.8293

Measured wt, ng TEQ, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

2,3,7,8 TCDD 0.0824 0.082 0.0734 0.0824 0.082 0.0734 1 2,3,7,8 TCDD 82.4 82 73.4 2,3,7,8 TCDD 82.4 M 82 M 73.4

1,2,3,7,8 PeCDD 0.212 0.236 0.198 0.212 0.236 0.198 1 1,2,3,7,8 PeCDD 212 236 198 1,2,3,7,8 PeCDD M 212 M 236 M 198

1,2,3,4,7,8 HxCDD 0.107 0.136 0.0956 0.0107 0.0136 0.00956 0.1 1,2,3,4,7,8 HxCDD 107 136 95.6 1,2,3,4,7,8 HxCDD M 107 M 136 95.6

1,2,3,6,7,8 HxCDD 0.205 0.183 0.127 0.0205 0.0183 0.0127 0.1 1,2,3,6,7,8 HxCDD 205 183 127 1,2,3,6,7,8 HxCDD M 205 M 183 127

1,2,3,7,8,9 HxCDD 0.48 0.515 0.351 0.048 0.0515 0.0351 0.1 1,2,3,7,8,9 HxCDD 480 515 351 1,2,3,7,8,9 HxCDD M 480 M 515 M 351

1,2,3,4,6,7,8 HpCDD 3.49 3.09 2.35 0.0349 0.0309 0.0235 0.01 1,2,3,4,6,7,8 HpCDD 3490 3090 2350 1,2,3,4,6,7,8 HpCDD 3490 3090 2350

OCDD 105 104 84 0.0315 0.0312 0.0252 0.0003 OCDD 105000 104000 84000 OCDD 105000 104000 84000

Total 0.44 0.4635 0.37746

Measured wt, ng TEQ, ng

2,3,7,8 TCDF 0.0014 0.0018 0.0013 0.00014 0.00018 0.00013 0.1 2,3,7,8 TCDF 1.4 1.8 1.3 2,3,7,8 TCDF < U 1.4 < U 1.8 < U 1.3

1,2,3,7,8 PeCDF 0.0016 0.002 0.0016 4.8E-05 0.00006 4.8E-05 0.03 1,2,3,7,8 PeCDF 1.6 2.0 1.6 1,2,3,7,8 PeCDF < U 1.6 < U 2.0 < U 1.6

2,3,4,7,8 PeCDF 0.0015 0.0032 0.0016 0.00045 0.00096 0.00048 0.3 2,3,4,7,8 PeCDF 1.5 3.2 1.6 2,3,4,7,8 PeCDF < U 1.5 < M, J, R 3.2 < U 1.6

1,2,3,4,7,8 HxCDF 0.0015 0.0014 0.0008 0.00015 0.00014 0.00008 0.1 1,2,3,4,7,8 HxCDF 1.5 1.4 0.80 1,2,3,4,7,8 HxCDF < U 1.5 < U 1.4 < U 0.80

1,2,3,6,7,8 HxCDF 0.0013 0.0013 0.00072 0.00013 0.00013 7.2E-05 0.1 1,2,3,6,7,8 HxCDF 1.3 1.3 0.72 1,2,3,6,7,8 HxCDF < U 1.3 < U 1.3 < U 0.72

2,3,4,6,7,8 HxCDF 0.0014 0.0014 0.00077 0.00014 0.00014 7.7E-05 0.1 2,3,4,6,7,8 HxCDF 1.4 1.4 0.77 2,3,4,6,7,8 HxCDF < U 1.4 < U 1.4 < U 0.77

1,2,3,7,8,9 HxCDF 0.0017 0.0016 0.00091 0.00017 0.00016 9.1E-05 0.1 1,2,3,7,8,9 HxCDF 1.7 1.6 0.91 1,2,3,7,8,9 HxCDF < U 1.7 < U 1.6 < U 0.91

1,2,3,4,6,7,8 HpCDF 0.0017 0.0014 0.0011 1.7E-05 1.4E-05 1.1E-05 0.01 1,2,3,4,6,7,8 HpCDF 1.7 1.4 1.1 1,2,3,4,6,7,8 HpCDF < U 1.7 < U 1.4 < U 1.1

1,2,3,4,7,8,9 HpCDF 0.0023 0.0019 0.0015 2.3E-05 1.9E-05 1.5E-05 0.01 1,2,3,4,7,8,9 HpCDF 2.3 1.9 1.5 1,2,3,4,7,8,9 HpCDF < U 2.3 < U 1.9 < U 1.5

OCDF 0.0203 0.012 0.014 6.1E-06 3.6E-06 4.2E-06 0.0003 OCDF 20.3 12 14 OCDF J 20.3 < M, J, R 12 < J, R 14

Total 0.00127 0.00181 0.00101

TOTAL CDD/CDF (TEQ) 0.44127 0.46531 0.37847

√ 7/17/12 √ 7/17/12 √ 7/17/12

M Indicates that a peak has been manually integrated

J Indicates that a target analyte was detected below the LQL

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion.

U Indicates that this compound was not detected above the MDL

B Indicates that this target was detected in the blank at greater than 10% of the sample concentration

Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Spray Dryer 1-D-F Data 12/1/2014
Filename: C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL

Test date: 5/6/10-5/7/10

Control device: Fabric filter

Gas Volum. Emission Process

Run Test O2

 conc., volume, flow rate, Mass, Concentration, rate, rate, Emission factor,

Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 g/hr ton/hr g/ton g/lb

CDD/CDF 1 M23 18.0 178.1 20,490 5.53 4.79E-10 1.096 5.25 3.82E-05 #REF! #REF!

2 18.0 173.4 19,452 5.59 4.97E-10 1.137 5.45 3.76E-05 #REF! #REF!

3 18.0 167.7 19,649 6.03 5.54E-10 1.269 6.08 4.24E-05 #REF! #REF!

Average 18.0 19,864 5.10E-10 1.167 5.60 3.94E-05 #REF! #REF!

TEQ 1 18.0 178.1 20,490 0.0315 2.73E-12 0.006 0.030 2.18E-07 #REF! #REF!

2 18.0 173.4 19,452 0.0596 5.30E-12 0.012 0.058 4.01E-07 #REF! #REF!

3 18.0 167.7 19,649 0.0571 5.25E-12 0.012 0.058 4.01E-07 #REF! #REF!

Average 18.0 19,864 4.43E-12 0.010 0.049 3.40E-07 #REF! #REF!

Notes: 

Spray Dryer 2-Emission Calcs 1 of 1 12/1/2014
DIOXIN-FURAN PARTICLE CATCH

Spray Dryer 2

Measured wt, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

Total TCDD 0.299 0.274 0.111 Total TCDD 299 274 111 Total TCDD 299 274 111

Total PeCDD 0.16 0.225 0.21 Total PeCDD 160 225 210 Total PeCDD 160 225 210

Total HxCDD 0.263 0.198 0.268 Total HxCDD 263 198 268 Total HxCDD 263 198 268

Total HpCDD 0.548 0.541 0.515 Total HpCDD 548 541 515 Total HpCDD 548 541 515

Total OCDD 4.25 4.32 4.91 Total OCDD 4250 4320 4910 Total OCDD 4250 4320 4910

Total dioxins 5.52 5.558 6.014

Total TCDF 0.0013 0.0016 0.0017 Total TCDF 1.3 1.6 1.7 Total TCDF < 1.3 < 1.6 < 1.7

Total PeCDF 0.0013 0.0015 0.0014 Total PeCDF 1.3 1.5 1.4 Total PeCDF < 1.3 < 1.5 < 1.4

Total HxCDF 0.00091 0.0013 0.0014 Total HxCDF 0.91 1.3 1.4 Total HxCDF < 0.91 < 1.3 < 1.4

Total HpCDF 0.0013 0.0023 0.0017 Total HpCDF 1.3 2.3 1.7 Total HpCDF < 1.3 < 2.3 < 1.7

Total OCDF 0.00273 0.022 0.0056 Total OCDF 2.73 22 5.6 Total OCDF J, B 2.73 < M, J, R 22 < J, R 5.6

Total furans 0.00754 0.0287 0.0118

TOTAL CDD/CDF 5.52754 5.5867 6.0258

Measured wt, ng TEQ, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

2,3,7,8 TCDD 0.013 0.014 0.02 0.013 0.014 0.02 1 2,3,7,8 TCDD 13 14 20 2,3,7,8 TCDD < R 13 < R 14 M 20

1,2,3,7,8 PeCDD 0.0085 0.0371 0.0268 0.0085 0.0371 0.0268 1 1,2,3,7,8 PeCDD 8.5 37.1 26.8 1,2,3,7,8 PeCDD < M, J, R 8.5 37.1 M 26.8

1,2,3,4,7,8 HxCDD 0.015 0.0051 0.016 0.0015 0.00051 0.0016 0.1 1,2,3,4,7,8 HxCDD 15.0 5.1 16 1,2,3,4,7,8 HxCDD M, J 15.0 < M, J, R 5.1 < J, R 16

1,2,3,6,7,8 HxCDD 0.0086 0.012 0.0085 0.00086 0.0012 0.00085 0.1 1,2,3,6,7,8 HxCDD 8.6 12 8.5 1,2,3,6,7,8 HxCDD < M, J, R 8.6 < M, J, R 12 < J, R 8.5

1,2,3,7,8,9 HxCDD 0.0322 0.019 0.0298 0.00322 0.0019 0.00298 0.1 1,2,3,7,8,9 HxCDD 32.2 19 29.8 1,2,3,7,8,9 HxCDD 32.2 < M, J, R 19 M 29.8

1,2,3,4,6,7,8 HpCDD 0.231 0.228 0.225 0.00231 0.00228 0.00225 0.01 1,2,3,4,6,7,8 HpCDD 231 228 225 1,2,3,4,6,7,8 HpCDD 231 228 225

OCDD 4.25 4.32 4.91 0.00128 0.0013 0.00147 0.0003 OCDD 4250 4320 4910 OCDD 4250 4320 4910

Total 0.03067 0.05829 0.05595

Measured wt, ng TEQ, ng

2,3,7,8 TCDF 0.0013 0.0016 0.0017 0.00013 0.00016 0.00017 0.1 2,3,7,8 TCDF 1.3 1.6 1.7 2,3,7,8 TCDF < U 1.3 < U 1.6 < U 1.7

1,2,3,7,8 PeCDF 0.0013 0.0015 0.0014 3.9E-05 4.5E-05 4.2E-05 0.03 1,2,3,7,8 PeCDF 1.3 1.5 1.4 1,2,3,7,8 PeCDF < U 1.3 < U 1.5 < U 1.4

2,3,4,7,8 PeCDF 0.0012 0.0015 0.0013 0.00036 0.00045 0.00039 0.3 2,3,4,7,8 PeCDF 1.2 1.5 1.3 2,3,4,7,8 PeCDF < U 1.2 < U 1.5 < U 1.3

1,2,3,4,7,8 HxCDF 0.00081 0.0011 0.0012 8.1E-05 0.00011 0.00012 0.1 1,2,3,4,7,8 HxCDF 0.81 1.1 1.2 1,2,3,4,7,8 HxCDF < U 0.81 < U 1.1 < U 1.2

1,2,3,6,7,8 HxCDF 0.00073 0.001 0.0011 7.3E-05 0.0001 0.00011 0.1 1,2,3,6,7,8 HxCDF 0.73 1.0 1.1 1,2,3,6,7,8 HxCDF < U 0.73 < U 1.0 < U 1.1

2,3,4,6,7,8 HxCDF 0.00077 0.0011 0.0012 7.7E-05 0.00011 0.00012 0.1 2,3,4,6,7,8 HxCDF 0.77 1.1 1.2 2,3,4,6,7,8 HxCDF < U 0.77 < U 1.1 < U 1.2

1,2,3,7,8,9 HxCDF 0.00091 0.0013 0.0014 9.1E-05 0.00013 0.00014 0.1 1,2,3,7,8,9 HxCDF 0.91 1.3 1.4 1,2,3,7,8,9 HxCDF < U 0.91 < U 1.3 < U 1.4

1,2,3,4,6,7,8 HpCDF 0.001 0.02 0.0016 0.00001 0.0002 1.6E-05 0.01 1,2,3,4,6,7,8 HpCDF 1.0 20 1.6 1,2,3,4,6,7,8 HpCDF < J, R 1.0 < J, R 20 < J, R 1.6

1,2,3,4,7,8,9 HpCDF 0.0013 0.0023 0.0017 1.3E-05 2.3E-05 1.7E-05 0.01 1,2,3,4,7,8,9 HpCDF 1.3 2.3 1.7 1,2,3,4,7,8,9 HpCDF < U 1.3 < U 2.3 < U 1.7

OCDF 0.00273 0.022 0.0056 8.2E-07 6.6E-06 1.7E-06 0.0003 OCDF 2.73 22 5.6 OCDF J, B 2.73 < M, J, R 22 < J, R 5.6

Total 0.00087 0.00133 0.00113

TOTAL CDD/CDF (TEQ) 0.03154 0.05962 0.05708

√ 7/17/12 √ 7/17/12 √ 7/17/12

M Indicates that a peak has been manually integrated

J Indicates that a target analyte was detected below the LQL

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion.

U Indicates that this compound was not detected above the MDL

B Indicates that this target was detected in the blank at greater than 10% of the sample concentration

Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Spray Dryer 2-D-F Data 12/1/2014
Filename: C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL

Test date: 5/4/10-5/5/10

Control device: None

Gas Volum. Emission Process

Run Test O2

 conc., volume, flow rate, Mass, Concentration, rate, rate, Emission factor,

Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 g/hr ton/hr g/ton g/lb

CDD/CDF 1 M23 18.6 172.3 3,543 35.89 3.21E-09 7.356 44.45 4.43E-05 #REF! #REF!

2 18.8 173.2 3,563 33.48 2.98E-09 6.827 45.19 4.13E-05 #REF! #REF!

3 19.0 166.8 3,558 28.36 2.62E-09 6.005 43.93 3.63E-05 #REF! #REF!

Average 18.8 3,555 2.94E-09 6.729 44.52 4.06E-05 #REF! #REF!

TEQ 1 18.6 172.3 3,543 0.0926 8.29E-12 0.019 0.115 1.14E-07 #REF! #REF!

2 18.8 173.2 3,563 0.1055 9.40E-12 0.022 0.142 1.30E-07 #REF! #REF!

3 19.0 166.8 3,558 0.0888 8.22E-12 0.019 0.138 1.14E-07 #REF! #REF!

Average 18.8 3,555 8.64E-12 0.020 0.132 1.19E-07 #REF! #REF!

Notes: 

Press Dryer 1-Emission Calcs 1 of 1 12/1/2014
DIOXIN-FURAN PARTICLE CATCH

Press Dryer 1

Measured wt, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

Total TCDD 0.0651 0.102 0.0778 Total TCDD 65.1 102 77.8 Total TCDD 65.1 102 77.8

Total PeCDD 0.267 0.386 0.314 Total PeCDD 267 386 314 Total PeCDD 267 386 314

Total HxCDD 1.07 1.22 0.951 Total HxCDD 1070 1220 951 Total HxCDD 1070 1220 951

Total HpCDD 2.57 2.47 2.11 Total HpCDD 2570 2470 2110 Total HpCDD 2570 2470 2110

Total OCDD 31.9 29.3 24.9 Total OCDD 31900 29300 24900 Total OCDD 31900 29300 24900

Total dioxins 35.8721 33.478 28.3528

Total TCDF 0.0013 0.001 0.0012 Total TCDF 1.3 1.0 1.2 Total TCDF < 1.3 < 1.0 < 1.2

Total PeCDF 0.0014 0.00097 0.0011 Total PeCDF 1.4 0.97 1.1 Total PeCDF < 1.4 < 0.97 < 1.1

Total HxCDF 0.0013 0.001 0.0012 Total HxCDF 1.3 1.0 1.2 Total HxCDF < 1.3 < 1.0 < 1.2

Total HpCDF 0.0019 0.0017 0.0014 Total HpCDF 1.9 1.7 1.4 Total HpCDF < 1.9 < 1.7 < 1.4

Total OCDF 0.00753 0.0018 0.0061 Total OCDF 7.53 1.8 6.1 Total OCDF J, B 7.53 < U 1.8 < J, R 6.1

Total furans 0.01343 0.00647 0.011

TOTAL CDD/CDF 35.8855 33.4845 28.3638

Measured wt, ng TEQ, ng Measured wt, pg

Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3

2,3,7,8 TCDD 0.01 0.001 0.0021 0.01 0.001 0.0021 1 2,3,7,8 TCDD 10 1.0 2.1 2,3,7,8 TCDD < M, R 10 < U 1.0 < U 2.1

1,2,3,7,8 PeCDD 0.0401 0.061 0.0513 0.0401 0.061 0.0513 1 1,2,3,7,8 PeCDD 40.1 61 51.3 1,2,3,7,8 PeCDD M 40.1 61 51.3

1,2,3,4,7,8 HxCDD 0.0406 0.0451 0.0245 0.00406 0.00451 0.00245 0.1 1,2,3,4,7,8 HxCDD 40.6 45.1 24.5 1,2,3,4,7,8 HxCDD M 40.6 M 45.1 M 24.5

1,2,3,6,7,8 HxCDD 0.0506 0.036 0.0525 0.00506 0.0036 0.00525 0.1 1,2,3,6,7,8 HxCDD 50.6 36 52.5 1,2,3,6,7,8 HxCDD M 50.6 < M, R 36 M 52.5

1,2,3,7,8,9 HxCDD 0.126 0.158 0.107 0.0126 0.0158 0.0107 0.1 1,2,3,7,8,9 HxCDD 126 158 107 1,2,3,7,8,9 HxCDD M 126 M 158 M 107

1,2,3,4,6,7,8 HpCDD 1.01 1 0.858 0.0101 0.01 0.00858 0.01 1,2,3,4,6,7,8 HpCDD 1010 1000 858 1,2,3,4,6,7,8 HpCDD 1010 1000 858

OCDD 31.9 29.3 24.9 0.00957 0.00879 0.00747 0.0003 OCDD 31900 29300 24900 OCDD 31900 29300 24900

Total 0.09149 0.1047 0.08785

Measured wt, ng TEQ, ng

2,3,7,8 TCDF 0.0013 0.001 0.0012 0.00013 0.0001 0.00012 0.1 2,3,7,8 TCDF 1.3 1.0 1.2 2,3,7,8 TCDF < U 1.3 < U 1.0 < U 1.2

1,2,3,7,8 PeCDF 0.0014 0.00097 0.0011 4.2E-05 2.9E-05 3.3E-05 0.03 1,2,3,7,8 PeCDF 1.4 0.97 1.1 1,2,3,7,8 PeCDF < U 1.4 < U 0.97 < U 1.1

2,3,4,7,8 PeCDF 0.0014 0.00092 0.0011 0.00042 0.00028 0.00033 0.3 2,3,4,7,8 PeCDF 1.4 0.92 1.1 2,3,4,7,8 PeCDF < U 1.4 < U 0.92 < U 1.1

1,2,3,4,7,8 HxCDF 0.0012 0.0009 0.0011 0.00012 0.00009 0.00011 0.1 1,2,3,4,7,8 HxCDF 1.2 0.90 1.1 1,2,3,4,7,8 HxCDF < U 1.2 < U 0.90 < U 1.1

1,2,3,6,7,8 HxCDF 0.0011 0.00081 0.00098 0.00011 8.1E-05 9.8E-05 0.1 1,2,3,6,7,8 HxCDF 1.1 0.81 0.98 1,2,3,6,7,8 HxCDF < U 1.1 < U 0.81 < U 0.98

2,3,4,6,7,8 HxCDF 0.0011 0.00087 0.001 0.00011 8.7E-05 0.0001 0.1 2,3,4,6,7,8 HxCDF 1.1 0.87 1.0 2,3,4,6,7,8 HxCDF < U 1.1 < U 0.87 < U 1.0

1,2,3,7,8,9 HxCDF 0.0013 0.001 0.0012 0.00013 0.0001 0.00012 0.1 1,2,3,7,8,9 HxCDF 1.3 1.0 1.2 1,2,3,7,8,9 HxCDF < U 1.3 < U 1.0 < U 1.2

1,2,3,4,6,7,8 HpCDF 0.0014 0.0013 0.001 1.4E-05 1.3E-05 0.00001 0.01 1,2,3,4,6,7,8 HpCDF 1.4 1.3 1.0 1,2,3,4,6,7,8 HpCDF < U 1.4 < U 1.3 < U 1.0

1,2,3,4,7,8,9 HpCDF 0.0019 0.0017 0.0014 1.9E-05 1.7E-05 1.4E-05 0.01 1,2,3,4,7,8,9 HpCDF 1.9 1.7 1.4 1,2,3,4,7,8,9 HpCDF < U 1.9 < U 1.7 < U 1.4

OCDF 0.00753 0.0018 0.0061 2.3E-06 5.4E-07 1.8E-06 0.0003 OCDF 7.53 1.8 6.1 OCDF J, B 7.53 < U 1.8 < J, R 6.1

Total 0.0011 0.00079 0.00094

TOTAL CDD/CDF (TEQ) 0.09259 0.10549 0.08879

√ 7/17/12 √ 7/17/12 √ 7/17/12

M Indicates that a peak has been manually integrated

J Indicates that a target analyte was detected below the LQL

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion.

U Indicates that this compound was not detected above the MDL

B Indicates that this target was detected in the blank at greater than 10% of the sample concentration

Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Press Dryer 1-D-F Data 12/1/2014