# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data** Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL Test date: 5/4/10-5/5/10 Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 16.0 148.5 5,222 640.84 6.66E-08 152.393 432.30 1.35E-03 #REF! #REF!

2 16.3 140.7 5,335 531.37 5.83E-08 133.339 402.92 1.21E-03 #REF! #REF! 3 16.1 143.7 5,465 555.14 5.96E-08 136.369 394.90 1.27E-03 #REF! #REF! Average 16.1 5,341 6.15E-08 140.700 410.04 1.28E-03 #REF! #REF! TEQ 1 16.0 148.5 5,22210.4592 1.09E-09 2.487 7.0562.21E-05 #REF! #REF!

2 16.3 140.7 5,335 7.5150 8.24E-10 1.886 5.698 1.71E-05 #REF! #REF! 3 16.1 143.7 5,465 7.1406 7.67E-10 1.754 5.080 1.63E-05 #REF! #REF! Average 16.1 5,341 8.93E-10 2.042 5.944 1.85E-05 #REF! #REF! Notes:

Kiln 2-Emission Calcs 1 of 1 12/1/2014

### DIOXIN-FURAN PARTICLE CATCH **Kiln 2** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 58.8 42.6 42.5 Total TCDD 58800 42600 42500 Total TCDD 58800 42600 42500 Total PeCDD 73.4 50.5 51.6 Total PeCDD 73400 50500 51600 Total PeCDD 73400 50500 51600 Total Hx CDD 59.4 55.8 57.2 Total Hx CDD 59400 55800 57200 Total Hx CDD 59400 55800 57200 Total HpCDD 88.7 59 62.5 Total HpCDD 88700 59000 62500 Total HpCDD 88700 59000 62500 Total OCDD 359 322 340 Total OCDD 359000 322000 340000 Total OCDD 359000 322000 340000

Total dioxins 639.3 529.9 553.8 Total TCDF 0.626 0.761 0.709 Total TCDF 626 761 709 Total TCDF 626 761 709 Total PeCDF 0.517 0.426 0.366 Total PeCDF 517 426 366 Total PeCDF 517 426 366 Total Hx CDF 0.151 0.189 0.156 Total Hx CDF 151 189 156 Total Hx CDF 151 189 156 Total HpCDF 0.156 0.0939 0.106 Total HpCDF 156 93.9 106 Total HpCDF 156 93.9 106 Total OCDF 0.0862 0 0 Total OCDF 86.2 69.0 69.0 Total OCDF 86.2< R 69.0< M, R 69.0

Total furans 1.5362 1.4699 1.337 TOTAL CDD/CDF640.836 531.37 555.137

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 2.32 1.63 1.76 2.32 1.63 1.76 1 2,3,7,8 TCDD 2320 1630 1760 2,3,7,8 TCDD 2320 1630 1760 1,2,3,7,8 PeCDD 5.78 4.18 4.04 5.78 4.18 4.04 1 1,2,3,7,8 PeCDD 5780 4180 4040 1,2,3,7,8 PeCDD 5780 M 4180 M 4040 1,2,3,4,7,8 Hx

CDD 2.5 1.81 1.62 0.25 0.181 0.162 0.1 1,2,3,4,7,8 Hx CDD 2500 1810 1620 1,2,3,4,7,8 Hx CDD 2500 1810 1620 1,2,3,6,7,8 Hx

CDD 3.7 2.66 2.71 0.37 0.266 0.271 0.1 1,2,3,6,7,8 Hx CDD 3700 2660 2710 1,2,3,6,7,8 Hx CDD 3700 2660 2710 1,2,3,7,8,9 Hx

CDD 12.3 8.79 5.11 1.23 0.879 0.511 0.1 1,2,3,7,8,9 Hx CDD 12300 8790 5110 1,2,3,7,8,9 Hx CDD 12300 8790 M 5110 1,2,3,4,6,7,8 HpCDD 36 24.9 26.4 0.36 0.249 0.264 0.01 1,2,3,4,6,7,8 HpCDD 36000 24900 26400 1,2,3,4,6,7,8 HpCDD 36000 24900 26400 Total OCDD 359 322 340 0.1077 0.0966 0.102 0.0003 Total OCDD 359000 322000 340000 OCDD 359000 322000 340000 Total 10.4177 7.4816 7.11 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0523 0.0649 0.0550.005230.00649 0.0055 0.1 2,3,7,8 TCDF 52.3 64.9 55.0 2,3,7,8 TCDF M 52.3 M 64.9 55.0 1,2,3,7,8 PeCDF 0.0461 0.0327 0.03290.001380.000980.00099 0.03 1,2,3,7,8 PeCDF 46.1 32.7 32.9 1,2,3,7,8 PeCDF 46.1 32.7 32.9 2,3,4,7,8 PeCDF 0.0637 0.0506 0.0464 0.01911 0.015180.01392 0.3 2,3,4,7,8 PeCDF 63.7 50.6 46.4 2,3,4,7,8 PeCDF 63.7 50.6 46.4 1,2,3,4,7,8 Hx

CDF 0.0407 0.0219 0.0180.004070.00219 0.0018 0.1 1,2,3,4,7,8 Hx CDF 40.7 21.9 18.0 1,2,3,4,7,8 Hx CDF M 40.7 M 21.9< M, J, R 18.0 1,2,3,6,7,8 Hx

CDF 0.0522 0.0331 0.03590.00522 0.00331 0.00359 0.1 1,2,3,6,7,8 Hx CDF 52.2 33.1 35.9 1,2,3,6,7,8 Hx CDF M 52.2 M 33.1 M 35.9 2,3,4,6,7,8 Hx

CDF 0.0334 0.026 0.0231 0.00334 0.0026 0.00231 0.1 2,3,4,6,7,8 Hx CDF 33.4 26.0 23.1 2,3,4,6,7,8 Hx CDF M 33.4 26.0 M 23.1 1,2,3,7,8,9 Hx

CDF 0.0203 0.0186 0.01780.002030.00186 0.00178 0.1 1,2,3,7,8,9 Hx CDF 20.3 18.6 17.8 1,2,3,7,8,9 Hx CDF M 20.3 M, J 18.6 M, J 17.8 1,2,3,4,6,7,8 HpCDF 0.0539 0.029 0.0302 0.00054 0.00029 0.0003 0.01 1,2,3,4,6,7,8 HpCDF 53.9 29.0 30.2 1,2,3,4,6,7,8 HpCDF M 53.9 29.0 30.2 1,2,3,4,7,8,9 HpCDF 0.0512 0.0436 0.0402 0.00051 0.00044 0.0004 0.01 1,2,3,4,7,8,9 HpCDF 51.2 43.6 40.2 1,2,3,4,7,8,9 HpCDF M 51.2 M 43.6 40.2 Total OCDF 0.0862 0.069 0.069 2.6E-05 2.1E-05 2.1E-05 0.0003 Total OCDF 86.2 69.0 69.0 OCDF 86.2< R 69.0< M, R 69.0 Total 0.04146 0.03336 0.03061 **TOTA L CDD/CDF (TEQ)**  10.4592 7.51496 7.14061 √7/17/12 

### √7/17/12 

### √7/17/12



### M Indicates that a peak has been manually integrated J Indicates that a target analyte was detected below the LQL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Kiln 2-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data** Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL Test date: 5/6/10-5/7/10 Control device: Wet scrubber Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 19.1 130.4 20,184 123.47 1.46E-08 33.422 258.09 1.15E-03 #REF! #REF!

2 19.1 133.3 20,278 122.42 1.42E-08 32.421 250.36 1.12E-03 #REF! #REF! 3 19.1 134.4 20,127 98.83 1.13E-08 25.967 200.528.88E-04 #REF! #REF! Average 19.1 20,196 1.34E-08 30.603 236.32 1.05E-03 #REF! #REF! TEQ 1 19.1 130.4 20,184 0.4413 5.22E-11 0.119 0.9224.10E-06 #REF! #REF!

2 19.1 133.3 20,278 0.4653 5.39E-11 0.123 0.9524.25E-06 #REF! #REF! 3 19.1 134.4 20,127 0.3785 4.35E-11 0.099 0.7683.40E-06 #REF! #REF! Average 19.1 20,196 4.98E-11 0.114 0.881 3.91E-06 #REF! #REF! Notes:

Spray Dryer 1-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Spray Dryer 1** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 1.97 2.3 2.16 Total TCDD 1970 2300 2160 Total TCDD 1970 2300 2160 Total PeCDD 3.15 3.53 3.2 Total PeCDD 3150 3530 3200 Total PeCDD 3150 3530 3200 Total HxCDD 4.87 4.95 3.78 Total HxCDD 4870 4950 3780 Total HxCDD 4870 4950 3780 Total HpCDD 8.45 7.62 5.67 Total HpCDD 8450 7620 5670 Total HpCDD 8450 7620 5670 Total OCDD 105 104 84 Total OCDD 105000 104000 84000 Total OCDD 105000 104000 84000

Total dioxins 123.44 122.4 98.81 Total TCDF 0.0014 0.0018 0.0013 Total TCDF 1.4 1.8 1.3 Total TCDF < 1.4< 1.8< 1.3 Total PeCDF 0.0016 0.002 0.0016 Total PeCDF 1.6 2.0 1.6 Total PeCDF < 1.6< 2.0< 1.6 Total HxCDF 0.0017 0.0016 0.00091 Total HxCDF 1.7 1.6 0.91 Total HxCDF < 1.7< 1.6< 0.91 Total HpCDF 0.0023 0.0019 0.0015 Total HpCDF 2.3 1.9 1.5 Total HpCDF < 2.3< 1.9< 1.5 Total OCDF 0.0203 0.012 0.014 Total OCDF 20.3 12 14 Total OCDF J 20.3< M, J, R 12< J, R 14

Total furans 0.0273 0.0193 0.01931 TOTAL CDD/CDF 123.467 122.419 98.8293

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.0824 0.082 0.0734 0.0824 0.082 0.0734 1 2,3,7,8 TCDD 82.4 82 73.4 2,3,7,8 TCDD 82.4 M 82 M 73.4 1,2,3,7,8 PeCDD 0.212 0.236 0.198 0.212 0.236 0.198 1 1,2,3,7,8 PeCDD 212 236 198 1,2,3,7,8 PeCDD M 212 M 236 M 198 1,2,3,4,7,8 HxCDD 0.107 0.136 0.0956 0.0107 0.0136 0.00956 0.1 1,2,3,4,7,8 HxCDD 107 136 95.6 1,2,3,4,7,8 HxCDD M 107 M 136 95.6 1,2,3,6,7,8 HxCDD 0.205 0.183 0.127 0.0205 0.0183 0.0127 0.1 1,2,3,6,7,8 HxCDD 205 183 127 1,2,3,6,7,8 HxCDD M 205 M 183 127 1,2,3,7,8,9 HxCDD 0.48 0.515 0.351 0.048 0.0515 0.0351 0.1 1,2,3,7,8,9 HxCDD 480 515 351 1,2,3,7,8,9 HxCDD M 480 M 515 M 351 1,2,3,4,6,7,8 HpCDD 3.49 3.09 2.35 0.0349 0.0309 0.0235 0.01 1,2,3,4,6,7,8 HpCDD 3490 3090 2350 1,2,3,4,6,7,8 HpCDD 3490 3090 2350 OCDD 105 104 84 0.0315 0.0312 0.0252 0.0003 OCDD 105000 104000 84000 OCDD 105000 104000 84000 Total 0.44 0.4635 0.37746 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0014 0.0018 0.0013 0.00014 0.00018 0.00013 0.1 2,3,7,8 TCDF 1.4 1.8 1.3 2,3,7,8 TCDF < U 1.4< U 1.8< U 1.3 1,2,3,7,8 PeCDF 0.0016 0.002 0.0016 4.8E-05 0.00006 4.8E-05 0.03 1,2,3,7,8 PeCDF 1.6 2.0 1.6 1,2,3,7,8 PeCDF < U 1.6< U 2.0< U 1.6 2,3,4,7,8 PeCDF 0.0015 0.0032 0.0016 0.00045 0.00096 0.00048 0.3 2,3,4,7,8 PeCDF 1.5 3.2 1.6 2,3,4,7,8 PeCDF < U 1.5< M, J, R 3.2< U 1.6 1,2,3,4,7,8 HxCDF 0.0015 0.0014 0.0008 0.00015 0.00014 0.00008 0.1 1,2,3,4,7,8 HxCDF 1.5 1.4 0.80 1,2,3,4,7,8 HxCDF < U 1.5< U 1.4< U 0.80 1,2,3,6,7,8 HxCDF 0.0013 0.0013 0.00072 0.00013 0.00013 7.2E-05 0.1 1,2,3,6,7,8 HxCDF 1.3 1.3 0.72 1,2,3,6,7,8 HxCDF < U 1.3< U 1.3< U 0.72 2,3,4,6,7,8 HxCDF 0.0014 0.0014 0.00077 0.00014 0.00014 7.7E-05 0.1 2,3,4,6,7,8 HxCDF 1.4 1.4 0.77 2,3,4,6,7,8 HxCDF < U 1.4< U 1.4< U 0.77 1,2,3,7,8,9 HxCDF 0.0017 0.0016 0.00091 0.00017 0.00016 9.1E-05 0.1 1,2,3,7,8,9 HxCDF 1.7 1.6 0.91 1,2,3,7,8,9 HxCDF < U 1.7< U 1.6< U 0.91 1,2,3,4,6,7,8 HpCDF 0.0017 0.0014 0.0011 1.7E-05 1.4E-05 1.1E-05 0.01 1,2,3,4,6,7,8 HpCDF 1.7 1.4 1.1 1,2,3,4,6,7,8 HpCDF < U 1.7< U 1.4< U 1.1 1,2,3,4,7,8,9 HpCDF 0.0023 0.0019 0.0015 2.3E-05 1.9E-05 1.5E-05 0.01 1,2,3,4,7,8,9 HpCDF 2.3 1.9 1.5 1,2,3,4,7,8,9 HpCDF < U 2.3< U 1.9< U 1.5 OCDF 0.0203 0.012 0.014 6.1E-06 3.6E-06 4.2E-06 0.0003 OCDF 20.3 12 14 OCDF J 20.3< M, J, R 12< J, R 14 Total 0.00127 0.00181 0.00101 **TOTAL CDD/CDF (TEQ)** 0.44127 0.46531 0.37847 √7/17/12 √7/17/12 √7/17/12

M Indicates that a peak has been manually integrated J Indicates that a target analyte was detected below the LQL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. U Indicates that this compound was not detected above the MDL B Indicates that this target was detected in the blank at greater than 10% of the sample concentration Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Spray Dryer 1-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data** Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL Test date: 5/6/10-5/7/10 Control device: Fabric filter Gas Volum. Emission Process

Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 18.0 178.1 20,490 5.53 4.79E-10 1.096 5.253.82E-05 #REF! #REF!

2 18.0 173.4 19,452 5.59 4.97E-10 1.137 5.453.76E-05 #REF! #REF! 3 18.0 167.7 19,649 6.03 5.54E-10 1.269 6.084.24E-05 #REF! #REF! Average 18.0 19,864 5.10E-10 1.167 5.603.94E-05 #REF! #REF! TEQ 1 18.0 178.1 20,490 0.0315 2.73E-12 0.006 0.0302.18E-07 #REF! #REF!

2 18.0 173.4 19,452 0.0596 5.30E-12 0.012 0.0584.01E-07 #REF! #REF! 3 18.0 167.7 19,649 0.0571 5.25E-12 0.012 0.0584.01E-07 #REF! #REF! Average 18.0 19,864 4.43E-12 0.010 0.0493.40E-07 #REF! #REF! Notes:

Spray Dryer 2-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Spray Dryer 2** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.299 0.274 0.111 Total TCDD 299 274 111 Total TCDD 299 274 111 Total PeCDD 0.16 0.225 0.21 Total PeCDD 160 225 210 Total PeCDD 160 225 210 Total HxCDD 0.263 0.198 0.268 Total HxCDD 263 198 268 Total HxCDD 263 198 268 Total HpCDD 0.548 0.541 0.515 Total HpCDD 548 541 515 Total HpCDD 548 541 515 Total OCDD 4.25 4.32 4.91 Total OCDD 4250 4320 4910 Total OCDD 4250 4320 4910

Total dioxins 5.52 5.558 6.014 Total TCDF 0.0013 0.0016 0.0017 Total TCDF 1.3 1.6 1.7 Total TCDF < 1.3< 1.6< 1.7 Total PeCDF 0.0013 0.0015 0.0014 Total PeCDF 1.3 1.5 1.4 Total PeCDF < 1.3< 1.5< 1.4 Total HxCDF 0.00091 0.0013 0.0014 Total HxCDF 0.91 1.3 1.4 Total HxCDF < 0.91< 1.3< 1.4 Total HpCDF 0.0013 0.0023 0.0017 Total HpCDF 1.3 2.3 1.7 Total HpCDF < 1.3< 2.3< 1.7 Total OCDF 0.00273 0.022 0.0056 Total OCDF 2.73 22 5.6 Total OCDF J, B 2.73<M, J, R 22<J, R 5.6

Total furans0.00754 0.0287 0.0118 TOTAL CDD/CDF5.52754 5.5867 6.0258

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.013 0.014 0.02 0.013 0.014 0.02 1 2,3,7,8 TCDD 13 14 20 2,3,7,8 TCDD < R 13<R 14 M 20 1,2,3,7,8 PeCDD 0.0085 0.0371 0.0268 0.0085 0.0371 0.0268 1 1,2,3,7,8 PeCDD 8.5 37.1 26.8 1,2,3,7,8 PeCDD < M, J, R 8.5 37.1 M 26.8 1,2,3,4,7,8 HxCDD 0.015 0.0051 0.016 0.00150.00051 0.0016 0.1 1,2,3,4,7,8 HxCDD 15.0 5.1 16 1,2,3,4,7,8 HxCDD M, J 15.0<M, J, R 5.1<J, R 16 1,2,3,6,7,8 HxCDD 0.0086 0.012 0.00850.00086 0.0012 0.00085 0.1 1,2,3,6,7,8 HxCDD 8.6 12 8.5 1,2,3,6,7,8 HxCDD < M, J, R 8.6<M, J, R 12<J, R 8.5 1,2,3,7,8,9 HxCDD 0.0322 0.019 0.02980.00322 0.00190.00298 0.1 1,2,3,7,8,9 HxCDD 32.2 19 29.8 1,2,3,7,8,9 HxCDD 32.2<M, J, R 19 M 29.8 1,2,3,4,6,7,8 HpCDD 0.231 0.228 0.2250.00231 0.002280.00225 0.01 1,2,3,4,6,7,8 HpCDD 231 228 225 1,2,3,4,6,7,8 HpCDD 231 228 225 OCDD 4.25 4.32 4.91 0.00128 0.0013 0.00147 0.0003 OCDD 4250 4320 4910 OCDD 4250 4320 4910 Total 0.030670.058290.05595 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0013 0.0016 0.00170.000130.00016 0.00017 0.1 2,3,7,8 TCDF 1.3 1.6 1.7 2,3,7,8 TCDF < U 1.3<U 1.6<U 1.7 1,2,3,7,8 PeCDF 0.0013 0.0015 0.0014 3.9E-05 4.5E-05 4.2E-05 0.03 1,2,3,7,8 PeCDF 1.3 1.5 1.4 1,2,3,7,8 PeCDF < U 1.3<U 1.5<U 1.4 2,3,4,7,8 PeCDF 0.0012 0.0015 0.00130.00036 0.000450.00039 0.3 2,3,4,7,8 PeCDF 1.2 1.5 1.3 2,3,4,7,8 PeCDF < U 1.2<U 1.5<U 1.3 1,2,3,4,7,8 HxCDF 0.00081 0.0011 0.0012 8.1E-050.00011 0.00012 0.1 1,2,3,4,7,8 HxCDF 0.81 1.1 1.2 1,2,3,4,7,8 HxCDF < U 0.81<U 1.1<U 1.2 1,2,3,6,7,8 HxCDF 0.00073 0.001 0.0011 7.3E-05 0.0001 0.00011 0.1 1,2,3,6,7,8 HxCDF 0.73 1.0 1.1 1,2,3,6,7,8 HxCDF < U 0.73<U 1.0<U 1.1 2,3,4,6,7,8 HxCDF 0.00077 0.0011 0.0012 7.7E-050.00011 0.00012 0.1 2,3,4,6,7,8 HxCDF 0.77 1.1 1.2 2,3,4,6,7,8 HxCDF < U 0.77<U 1.1<U 1.2 1,2,3,7,8,9 HxCDF 0.00091 0.0013 0.0014 9.1E-050.000130.00014 0.1 1,2,3,7,8,9 HxCDF 0.91 1.3 1.4 1,2,3,7,8,9 HxCDF < U 0.91<U 1.3<U 1.4 1,2,3,4,6,7,8 HpCDF 0.001 0.02 0.0016 0.00001 0.0002 1.6E-05 0.01 1,2,3,4,6,7,8 HpCDF 1.0 20 1.6 1,2,3,4,6,7,8 HpCDF<J, R 1.0<J, R 20<J, R 1.6 1,2,3,4,7,8,9 HpCDF 0.0013 0.0023 0.0017 1.3E-05 2.3E-05 1.7E-05 0.01 1,2,3,4,7,8,9 HpCDF 1.3 2.3 1.7 1,2,3,4,7,8,9 HpCDF< U 1.3<U 2.3<U 1.7 OCDF 0.00273 0.022 0.0056 8.2E-07 6.6E-06 1.7E-06 0.0003 OCDF 2.73 22 5.6 OCDF J, B 2.73<M, J, R 22<J, R 5.6 Total 0.000870.001330.00113 **TOTAL CDD/CDF (TEQ)** 0.03154 0.05962 0.05708 √7/17/12 √7/17/12 √7/17/12

M Indicates that a peak has been manually integrated J Indicates that a target analyte was detected below the LQL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. U Indicates that this compound was not detected above the MDL B Indicates that this target was detected in the blank at greater than 10% of the sample concentration Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Spray Dryer 2-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\881040653379956960\[EPA-HQ-OAR-2013-0290-DRAFT-0092.xls]Kiln 2-D-F Data** Date: 12/1/14

Plant name: Monarch Ceramic Tile Location: Florence, AL Test date: 5/4/10-5/5/10 Control device: None Gas Volum. Emission Process

Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 18.6 172.3 3,543 35.89 3.21E-09 7.356 44.454.43E-05 #REF! #REF!

2 18.8 173.2 3,563 33.48 2.98E-09 6.827 45.194.13E-05 #REF! #REF! 3 19.0 166.8 3,558 28.36 2.62E-09 6.005 43.93 3.63E-05 #REF! #REF! Average 18.8 3,555 2.94E-09 6.729 44.524.06E-05 #REF! #REF! TEQ 1 18.6 172.3 3,543 0.0926 8.29E-12 0.019 0.115 1.14E-07 #REF! #REF!

2 18.8 173.2 3,563 0.1055 9.40E-12 0.022 0.142 1.30E-07 #REF! #REF! 3 19.0 166.8 3,558 0.0888 8.22E-12 0.019 0.138 1.14E-07 #REF! #REF! Average 18.8 3,555 8.64E-12 0.020 0.132 1.19E-07 #REF! #REF! Notes:

Press Dryer 1-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Press Dryer 1** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.0651 0.102 0.0778 Total TCDD 65.1 102 77.8 Total TCDD 65.1 102 77.8 Total PeCDD 0.267 0.386 0.314 Total PeCDD 267 386 314 Total PeCDD 267 386 314 Total HxCDD 1.07 1.22 0.951 Total HxCDD 1070 1220 951 Total HxCDD 1070 1220 951 Total HpCDD 2.57 2.47 2.11 Total HpCDD 2570 2470 2110 Total HpCDD 2570 2470 2110 Total OCDD 31.9 29.3 24.9 Total OCDD 31900 29300 24900 Total OCDD 31900 29300 24900

Total dioxins 35.8721 33.478 28.3528 Total TCDF 0.0013 0.001 0.0012 Total TCDF 1.3 1.0 1.2 Total TCDF < 1.3< 1.0< 1.2 Total PeCDF 0.0014 0.00097 0.0011 Total PeCDF 1.4 0.97 1.1 Total PeCDF < 1.4< 0.97< 1.1 Total HxCDF 0.0013 0.001 0.0012 Total HxCDF 1.3 1.0 1.2 Total HxCDF < 1.3< 1.0< 1.2 Total HpCDF 0.0019 0.0017 0.0014 Total HpCDF 1.9 1.7 1.4 Total HpCDF < 1.9< 1.7< 1.4 Total OCDF 0.00753 0.0018 0.0061 Total OCDF 7.53 1.8 6.1 Total OCDF J, B 7.53<U 1.8<J, R 6.1

Total furans 0.01343 0.00647 0.011 TOTAL CDD/CDF 35.8855 33.4845 28.3638

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEF Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.01 0.001 0.0021 0.01 0.001 0.0021 1 2,3,7,8 TCDD 10 1.0 2.1 2,3,7,8 TCDD <M, R 10<U 1.0<U 2.1 1,2,3,7,8 PeCDD 0.0401 0.061 0.0513 0.0401 0.061 0.0513 1 1,2,3,7,8 PeCDD 40.1 61 51.3 1,2,3,7,8 PeCDD M 40.1 61 51.3 1,2,3,4,7,8 HxCDD 0.0406 0.0451 0.0245 0.00406 0.00451 0.00245 0.1 1,2,3,4,7,8 HxCDD 40.6 45.1 24.5 1,2,3,4,7,8 HxCDD M 40.6 M 45.1 M 24.5 1,2,3,6,7,8 HxCDD 0.0506 0.036 0.0525 0.00506 0.0036 0.00525 0.1 1,2,3,6,7,8 HxCDD 50.6 36 52.5 1,2,3,6,7,8 HxCDD M 50.6<M, R 36 M 52.5 1,2,3,7,8,9 HxCDD 0.126 0.158 0.107 0.0126 0.0158 0.0107 0.1 1,2,3,7,8,9 HxCDD 126 158 107 1,2,3,7,8,9 HxCDD M 126 M 158 M 107 1,2,3,4,6,7,8 HpCDD 1.01 1 0.858 0.0101 0.01 0.00858 0.01 1,2,3,4,6,7,8 HpCDD 1010 1000 858 1,2,3,4,6,7,8 HpCDD 1010 1000 858 OCDD 31.9 29.3 24.9 0.00957 0.00879 0.00747 0.0003 OCDD 31900 29300 24900 OCDD 31900 29300 24900 Total 0.09149 0.1047 0.08785 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0013 0.001 0.0012 0.00013 0.0001 0.00012 0.1 2,3,7,8 TCDF 1.3 1.0 1.2 2,3,7,8 TCDF <U 1.3<U 1.0<U 1.2 1,2,3,7,8 PeCDF 0.0014 0.00097 0.0011 4.2E-05 2.9E-05 3.3E-05 0.03 1,2,3,7,8 PeCDF 1.4 0.97 1.1 1,2,3,7,8 PeCDF <U 1.4<U 0.97<U 1.1 2,3,4,7,8 PeCDF 0.0014 0.00092 0.0011 0.00042 0.00028 0.00033 0.3 2,3,4,7,8 PeCDF 1.4 0.92 1.1 2,3,4,7,8 PeCDF <U 1.4<U 0.92<U 1.1 1,2,3,4,7,8 HxCDF 0.0012 0.0009 0.0011 0.00012 0.00009 0.00011 0.1 1,2,3,4,7,8 HxCDF 1.2 0.90 1.1 1,2,3,4,7,8 HxCDF <U 1.2<U 0.90<U 1.1 1,2,3,6,7,8 HxCDF 0.0011 0.00081 0.00098 0.00011 8.1E-05 9.8E-05 0.1 1,2,3,6,7,8 HxCDF 1.1 0.81 0.98 1,2,3,6,7,8 HxCDF <U 1.1<U 0.81<U 0.98 2,3,4,6,7,8 HxCDF 0.0011 0.00087 0.001 0.00011 8.7E-05 0.0001 0.1 2,3,4,6,7,8 HxCDF 1.1 0.87 1.0 2,3,4,6,7,8 HxCDF <U 1.1<U 0.87<U 1.0 1,2,3,7,8,9 HxCDF 0.0013 0.001 0.0012 0.00013 0.0001 0.00012 0.1 1,2,3,7,8,9 HxCDF 1.3 1.0 1.2 1,2,3,7,8,9 HxCDF <U 1.3<U 1.0<U 1.2 1,2,3,4,6,7,8 HpCDF 0.0014 0.0013 0.001 1.4E-05 1.3E-05 0.00001 0.01 1,2,3,4,6,7,8 HpCDF 1.4 1.3 1.0 1,2,3,4,6,7,8 HpCDF <U 1.4<U 1.3<U 1.0 1,2,3,4,7,8,9 HpCDF 0.0019 0.0017 0.0014 1.9E-05 1.7E-05 1.4E-05 0.01 1,2,3,4,7,8,9 HpCDF 1.9 1.7 1.4 1,2,3,4,7,8,9 HpCDF <U 1.9<U 1.7<U 1.4 OCDF 0.00753 0.0018 0.0061 2.3E-06 5.4E-07 1.8E-06 0.0003 OCDF 7.53 1.8 6.1 OCDF J, B 7.53<U 1.8<J, R 6.1 Total 0.0011 0.00079 0.00094 **TOTAL CDD/CDF (TEQ)** 0.09259 0.10549 0.08879 √7/17/12 √7/17/12 √7/17/12

M Indicates that a peak has been manually integrated J Indicates that a target analyte was detected below the LQL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. U Indicates that this compound was not detected above the MDL B Indicates that this target was detected in the blank at greater than 10% of the sample concentration Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0092 Press Dryer 1-D-F Data 12/1/2014