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# OAR Box 1413 Prepped by Ollie Stewart



## Document

Number: 

# 9 ) 11-1- 9

Docket Number: 

# A-94-5 2

Printed 7/9/2008 3:11:20 PM

Sheet 9 of 114

# r M-rf- W

oz^y\~ty Rul e 74.1 4 Polyeste r Resi nMateria l Operation s

(Adopte d 11/24/87 , revise d 5/26/92 )
A . Applicabilit y 1 . Thi s mil e i s applicabl e to th e manufacturehofjr .protiucta»if')3o m p r th e us e o f polyeste r resi nmaterial . **""" * "~~~~ "*
2 . An

y mantifactrurln

g proces s using polyeste r resi nmaterial s vhic hi s exemp t fro

m thi s rul e pursuan t t o SectionC.2 , shal l compl y vit h th e provision s o f Rul e 66 . B . Requirement s
1 . Al l polyeste r resi nmateria l shal l compl y vit hone o r mor e o f th e followin

g requirements :

a . Fo r al l formulations , th e reactiv

e organi c compoun

d (ROC ) los s rat e shal l be les s tha no r equa l t o 6 0 gram s pe r squar e mete r o f expose d surfac e are a durin g resi npolymerization ; o r b . Fo r al l formulation s excep t specialty resin s an

d ge l coats , th e monome r conten t o f th e materia l shal l b e n o mor e tha

n3 5 percen t b

y weigh t a s applied an d a s determined b

y manufacturer s specifications . Fo r al l specialt y

resins , th

e monome r conten t o f th e materia l shal l be no mor e tha n5 0 percen t b

y weigh t a s applied an

d a s determined b

y manufacturer s specifications . Fo r al l ge l coats , th e monome r conten t o f th e materia l shal l be n o mor e than4 5 percen t b y weigh t a s applied for pigmented ge l coat s an d 5 0 percen t b

y weigh t a s applied fo r clea r ge l coats , a s determined b y manufacturer s specifications ; or

c . Applicationo f th e materia l shal l occur usin g a closed-mol d system . Complyin

g formulation s shal l no t be thinned o r diluted vit han y RO C o r changed i nan y manne r tha t may

increas e ROC emission s afte r testing , bu t prio r t o or durin g application . 2 . Airless , air-assiste d airless , electrostatic , o r hig hvolume-lo

w pressur e spra

y equipmen t shal l b e use d i nan y spra y application , excep t for touch-u p o r repai r usin

g a hand-held , air-atomized spra y gu nutilizing anattached resi ncontaine r o f no mor e tha n on e quar t capacity . 3 . Cleaning materia l use d onlines , rollers , brushes , spra y equipmen t an d personnel , an

d containin

g mor e than1. 7 pound s o f ROC pe r gallono f materia l a s applied , or wher e th e initia l boilin

g point i s les s tha

n19 0 degree s Celsius , shal l be limited in us e t o les s 7/9 2 Rul e 74.14 : 1 

# Attachmen t3 BP. 3

¥•

• t

A\
thanfifteen(15 ) gallon s pe r calenda r wee k -unles s a reclamation syste m i s used . Residue s fro m on-sit e reclamationsystem s shal l / " contai n no mor e tha n2 0 percent ROC b

y veigh t an

d shal l b e V dispose d o f i na manne r consisten t vit hfederal , stat e an d loca l hazardou s vast e regulations . 4 . I nlieu o f complianc e wit hth e provision s o f Subsectio nB. l an

d B.2 , a personma

y elec t t

o reduc e reactiv

e organi c compoun

d emission s fro

m the applicatio

nproces s b

y a tota l captur e an d contro l efficiency o f a t leas t 8 5 percen t b y weight , bu t n o les s than th e percen t reductio

nachievabl e throug hth e application o f Subsection s B. l an d B.2 . Contro l efficiency shal l b

e continuousl y monitore d acros s anemissio ncontro l device , th e result s o f whic h shal l b e averaged ove r a rollin g 2 4 hou r period . Touch-u p o r repai r wor k shal l no t b e exclude

d fro m thi s subsection . 5 . Al l material s containin g reactiv

e organi c compounds , used o r unused , includin

g bu t no t limite

d t o semi-soli d or liqui d polyeste r resi nmaterial s an d soli d o r liqui d cleanin g materials , shal l b e store

d i nclose

d containers . C . Exemption s 1 . An

y polyeste r resi nmateria l operationsubjec t t o th e requirement s o f thi s Rul e shal l be exemp t fro m the requirement s o f Rul e 66 , wit hthe exceptiono f Rul e 66.A.7 . 2 . Th e provision s o f Sectio nB o f thi s rul e shal l no t appl y t o stationar

y source s usin

g no t mor e than2 0 gallon s pe r mont ho f polyeste r resi nmaterial . D . Recordkeeping
A perso nsubjec t t o th e provision s o f thi s Rul e shal l maintai nth e followin

g records . Suc hrecord s shal l b e mad e availabl e t o th e AFC O uponreques t an

d shal l be maintained for no t les s thantv o year s fro

m th e dat e o f eachentry . Th e record s shal l contain : 1 . Weekl y

report s (Initiale d b y operator ) o f th

e followin

g information :

a . The manufacture r an d produc t numbe r o f eachpolyeste r resi n materia l an

d cleanin

g materia l used , an d amoun t o f cleaning materia l bot hused an d reclaime d o r recycled . b . The applicationmetho d fo r eac hpolyeste r resi nan d cleaning materia l used . 2 . Th e emissionrat e o f eac hpolyeste r resi nmateria l used , a s eithe r th

e ROC los s rat e in grams pe r squar e mete r (gm/ m ) o r a s monome r conten t inpercen t b y weight , an

d th e ge l time . Fo r cleaning material , th e RO C conten t i npound s o f ROC pe r gallo no f materia l a s applied . Documentatio nshal l b e availabl e t o suppor t thes e records . 7/9 2 Rul e 74.14 : 2P. 4

3 . Dail y

report s o f th

e continuou s contro l efficienc y monitoring informationrequire d inSubsectio nB.4 , i f applicable . Dail y report s shal l includ e th e quantit y

an d typ e o f polyeste r resi n materia l used . A perso noperatin

g unde r th

e provision s o f Subsectio nC. 2 o f thi s rul e shall , i n lie u o f Subsection s 1 , 2 , an d 3 above , maintai nmonthl y record s o f th

e amoun t o f polyeste r resi nmateria l used . Tes t Method s
1 . Complianc e wit hSubsectio nB.l. a shal l b e determined b

y laborator

y stati c test , a s describe d i nAttachmen t A . Tes t result s shal l b e submitte d t o the APC O fo r approva l inwritin g an d a cop y o f th e tes t result s shal l b e retaine d at th e worksite . 2 . Complianc e wit hthe requirement s o f Subsection s B.l. bshal l be determine d using AST M method D2369-81 . Materia l tested shal l be non-catalyzed . 3 . Captur e efficiency determination s require d i nSubsectionB. 4 shal l be base d o

ncriteri a se t fort hb y EP A in5 5 Federa l Registe r (FR ) 26865 , June 29 , 1990 . 4 . Contro l efficiency determination s require d inSubsectionB. 4 shal l b e mad e usin

g EPA Metho d 25A . Ga s flo w rat e measurement s lnpipe s o r smal l duct s shal l be mad e usin g EP A Metho d 2A . 5 . Complianc e wit hth e requirement s o f Subsectio nB. 3 o f thi s rul e shal l b e determine d a s follows :

a . Fo r pound s o f RO C pe r gallono f material , EP A Metho d 24 . b . Fo r initia l boiling point , AST M metho d D1078-86 .

c . Fo r RO C conten t i nresidue , ARB Metho d 401 . 6 . Exemp t organi c compound s shal l be determine d b y using AST M

metho d D4457-85 . Violation s Failur e t o compl y

wit hany

provisiono f thi s rul e shal l constitut e a violation o f thi s rule . Definition s
1 . "Closed-mol d System" : A method o f formin

g object s fro

m polyeste r resin s tha t involve s placing th e polyeste r resi nmateria l ina confining mol d cavit y an d applyin

g pressure and/o r heat .

7/9 2 Rul e 74.14 : 3P. 5 

# r

" \
2 . "Cure" : T o transfor m or polymeriz e materia l fro m a liqui d stat e t

o a soli d or semi-soli d stat e i nvhic hth

e desire d physica l properties , includin g hardness , are achieved . 3 . "Electrostatic" : A sufficient chargin g o f atomized droplet s to caus e depositio nprincipall y b y electrostati c attraction . Thi s application metho d shal l operat e at a minimu m o f 6 0 kilovolts . 4 . "Exempt Organi c Compounds" : As defined i nRul e 2 . 5 . "Ge l Coat" : A polyeste r resi nmaterial , eithe r pigmente d or clear , used t o provid e laminate d surface s vit hexterio r cosmeti c enhancemen t an

d improve

d resistanc e t o degradationfro m exposur e t o th e elements . 6 . "Pound s o f RO C pe r Gallo no f Material" : Th e weigh t o f RO C pe r volum e o f material , a s calculate d b y th e equation , Pound s o f RO C pe r Gallono f Materia l - (Ws-Ww-Wes)/V m Wher e
W s - weigh t o f volatil e compound s i npound s W w - weigh t o f wate r inpound s We s - weigh t o f exemp t organi c compound s i npound s V m - volum

e o f tota l materia l i ngallon s 7 . "Hig

hVolume-Lo

w Pressur e (HVLP)" : Spra y equipmen t whic huse s a hig hvolum e o f ai r delivere

d a t pressure s betwee n0. 1 an d 1 0 psi g an d whic hoperate s a t a maximu m flui d delivery

pressur e o f 10 0 psig . 8 . "Monomer" : A norgani c compoun d tha t combine s wit hitsel f o r othe r simila r compound s t o becam e a cured thermose t resin . 9 . "Polyeste r Resi nMaterial" : Unsaturated polyeste r resins , suc ha s isophthalic , orthophthalic , halogenated , bispheno l A , viny l ester , or furanresins ; cross-linkin g agents , catalysts , ge l coats , inhibitors , accelerators , promoters , an d an y othe r materia l containin

g RO C an

d used i

n a polyeste r resi nmanufacturin g process . Iner t fille r an d cleanin

g materia l i s specificall y excluded fro

m thi s definition . 10 . "ReclamationSystem" : Equipment capabl e o f reclaimin g spen t solven t fo r re-use . Reclamatio nsystem

s ma y be operate

d on-sit e or b y an off-sit e commercia l reclamatio nfacility . 11 . "Repair" : Tha t portiono f th e fabricationproces s tha t require s th e additiono f polyeste r resi nmaterial s t o portion s o f a previousl y

fabricate d produc t inorde r t o mend damag e Immediatel y followin

g norma l fabricatio n operations . 12 . "ROC" : Reactive Organi c Compound , a s define d inRul e 2 .

7/9 2 Rul e 74.14 : 4 (P. 6

1 3 "Specialt y

Polyeste r Resi nMaterial" : Halogenated , furan , bispheno l A , viny l ester , o r isophthali c resin s used t o mak e product s for corrosive , fir e retardant , hig hstrength , or mol d makin g services . 14 . "Touch-up" : Tha t portiono f th e fabricatio

nproces s tha t i s necessary

t o cove r mino r imperfections .

7/9 2 RuI e 74.14 : 5P. 7



# r r

ATTACHMEN

T A
LABORATOR

YSTATI C TES T FO

RPOLYESTERRESI N

MATERIA

L
1 . PRINCIPL E

A weighe d amoun t o f polyeste r resi nmateria l i s reacted wit hmethy l ethy l keton e peroxide (MEKP ) catalys t to for m a 14. 5 c

m diamete r casting . The ROC los s rat e i s determined a t roo m temperatur e (7 7 ±3°F ) an d 50 Xroo

m humidit y

ove r a specifie

d tim e period . Thi s method i s applicabl e onl y t o polyeste r resi nmaterial s an d doe s no t simulat e spra

y boot hoperations . 2 . APPARATU S

a . Analytica l balance , to p loading , capabl e o f measurin g withi n0.0 1 gram . b . Gallo nca

nli d o r equivalent . Th e li d shoul d be 14. 5 c m inside diamete r (165.1 3 s q cm) . Differen t siz e lid s shoul d be measure d prio r t o testing .

c . Pape r clip , ben t 9 0 degrees . d . Cloc k or time r capabl e o f reportin g tim e t o a precisiono f 0.0 1 minute .

e . Constan t temperatur e an d humidit y

room , a s described above . Roo m mus t als o b e fre e o f drafts . I f a constan t temperatur e roo m i s no t available , measur e temperatur e an d humidit y

prio r t o eac h weigh t measuremen t or tes t procedure . 3 . DETERMINATIO

N O F RO C LOS S
NOTE : The mixin

g shoul d b

e don e ina hoo

d o r i na vei l ventilate d area .

a . Plac e th

e ben t pape r cli p o na galloncanlid , o r equivalent . b . Tar e weig

ht o ±0.0 1 gram

s (g ) th

e galloncanli d an d clip . Record th e weigh t a s ?*[ .

c . Catalyz e 20 0 gram s o f polyeste r resi nmateria l wit hth e recommended typ

e an d amount o f catalys t an d promoter . Ensur e tha t th e resi ntemperatur e i s 7 7 degree s a t catalyzation . d . Ad

d 10 0 g (±0.0 5 g ) o f catalyze d polyeste r resi nmateria l t o th e gallonca

n lid . Recor

d th e weigh t o f th

e li d plu s th

e polyeste r resi nmateria l t o ±0.0 1 g a s W 2 . Star t timer .

e . At fiv

e (5 ) minut e intervals , recor d th e gros s weigh t los s t o ±0.0 1 g a s W t an

d chec k th

e catalyzed resi nfo r ge l point . Gellin g ha s occurred whenth e resi ntear s o r th e ca nli d raise s

7/9 2 Rul e 74.14 : 6 (