A copy of the Chain of 

Custody can be found in 

LABWARELIMS 

A copy of the GPO and/or 

Protocol can be found in the 

Lotus Notes GPO Database 

Communications 

Misc. 
Weston Solutions, Inc. 

1400 Weston Way 

P.O. Box 2653 

Westchester, Pennsylvania 19380 

610-701-3000 • Fax 610-701-3186 

® www.westonsolutlons.com 

The Trusted Integrator for Sustainable Solutions 

August 31,2011 

Dr. Cleston Lange 

3M Environmental Laboratory 

3M Center 

Building 260-5N-17 

St. Paul, MN 55144-1000 

Dear Dr. Lange: 

Per your request, 1 am returning herewith GLP 10-01-01 Interim Report 18. The 

appropriate pages have been signed and are included with this transmittal. 

Should you have any questions, please do not hesitate to contact me at 610-701-3761. 

Very truly yours, 

WEST/2(N SOLUTIONS, INC. 

Jaisimha Kesari, P.E., DEE 

Principal Project Manager 

Enclosure 

an employee-owned company S S 

M:\FOLDERS.0-9\3M-DECAT\Lange-63 (Interim Rpt 18 Audit).docx 
Page 1 of4 

RE: FW: Quarterly GW sampling - Decatur Former Sludge Incorporation Area Wells 

Frinak, Timothy R. 

to: 

Young, Charles T., stwolf@mmm.com 

07/14/2011 07:46 PM 

Hide Details 

From: "Frinak, Timothy R." <T.Frinak(^WestonSolutions.com> 

To: "Young, Charles T." <Charles.Young@WestonSolutions.com>, "stwolf@mmm.com" 

<stwolf@mmm. com> 

5 Attachments 

m\ 

imageOOLjpg image002.gif image003.gif image004.png imageOOS.png 

Sue, 

It should be referenced as 144S. In the original work plan, it was proposed as an R well, meaning it would be 

completed within the soil horizon. However, upon drilling the location it was determined that there was no 

water in this zone, so it was extended into the epikarst zone as an S well. 

Please let me know if you have any other questions. 

Tim 

Timothy R. Frinak, P. G. 

Weston Solutions, Inc. 

1625 Piimphrey Avenue 

Auburn, AL 36832 

Ph: 334-466-5653 

Fx: 334-466-5660 

CI: 334-332-9123 

From: Young, Charles T. 

Sent: Thursday, July 14, 2011 12:17 PM 

file://C:\Users\US263070\Ar)DData\Local\TemD\notes256C9 A\~web6824.htm 7/15/2011 
Page 2 of4 

To: Frinak, Timothy R. 

Subject: RE: FW: Quarterly GW sampling - Decatur Former Sludge Incorporation Area Wells 

Tim: 

Can you respond to this and cc: me? 

They are probably already logged into their LIMS as 1448 if that is what the CoC and labels had. 

Thanks, 

Charlie 

Charles T. Young 

Technical Director 

Weston Solutions, Inc. 

1400 Weston Way (5-2) 

West Chester, PA 19380 

(610)701-3787 

P'§?J61.0)J701^-3401 _ _ ^ ,. _ .. 

From: stwolf@mmm.com rmailto:stwolf(ia)mmm.com1 

Sent: Thursday, July 14, 2011 12:53 PM 

To: Young, Charles T. 

Cc: Frinak, Timothy R. 

Subject: Re: FW: Quarterly GW sampling - Decatur Former Sludge Incorporation Area Wells 

Hi, 

While labeling the samples received last week, we noticed that sampling location 144 was identified as 144S on 

the CoC form, but was listed as 144R in the attached table provided with in the original bottle order request. 

Please confirm if it should be identified as 144S or 144R. 

O n ^ ^Stm^^ ktmxi fivt%:«* 

mu 6^ m^ m.....um^ 

£>M. MIS iK lia/j^ 

ITT* 

IM±.. 

(See attached file: Quarterly GW Monitor ing. doc) 

Thanks, 

Sue 

3M 

Susan T. Wolf | Environmental Lab 

3M EHS Operations 

3M Center, 260-5N-17 | St. Paul, MN 55144-1000 

Office: 651 733 9851 | Triminet: 733 9851 

stwolf@nnmm.com | www.3M.com 

(3M Internal Web site) www.3M.com/sustainabilitv 

file://C:\Users\US263070\AppData\Local\Temp\notes256C9A\~web6824.htm 7/15/2011 
Page 3 of4 

This communication is intended only for the addressee(s) named above. It contains confidential 

information. Unauthorized use, disclosure, dissemination or copying of this communication, or any 

part thereof, is strictly prohibited. If the reader of this message is not the intended recipient please 

notify us immediately by telephone or electronic mail and delete or destroy this message and all 

copies thereof, including attachments. 

"Young, Charles T." —07/08/2011 08:15:51 AM—Sue: You should see the FSIA GW samples today. Two wells 

were dry as described in Martin's email bel 

From: "Young, Charles T." <Charles.Young@WestonSolutions.com> 

To: "stwolf@mmm.com" <stwolf@mmm.com> 

Cc: "Frinak, Timothy R." <T.Frinak@WestonSolutions.com> 

Date: 07/08/2011 08:15 AM 

SLibJect: FW: Quarterly GW sampling - Decatur Fomner Sludge Incorporation Area Wells 

Sue: 

You should see the FSIA GW samples today. Two wells were dry as described in Martin's email below. 

Charlie 

Charles T. Young 

Technical Director 

Weston Solutions, Inc. 

1400 Weston Way (5-2) 

West Chester, PA 19380 

(610) 701-3787 

Fax (610) 701-3401 

From: Smith, Martin 

Sent: Thursday, July 07, 2011 4:36 PM 

To: Young, Charles T. 

Cc: Frinak, Timothy R. 

Subject: RE: Quarterly GW sampling - Decatur Former Sludge Incorporation Area Wells 

The lab should receive the samples tomorrow via FedEx. It will be three coolers, two with samples and one with 

empty bottles. 

Wells 136R and 137R were dry and were not sampled, these are the empty bottles in the third cooler. 

Note that 4 trip blank sets were requested but only two were sent. We had to buy a bigger cooler in order to ship 

in only two coolers. 

Martin 

From: Young, Charles T. 

Sent: Monday, June 13, 2011 2:14 PM 

To: stwolf@mmm.com 

Cc: Frinak, Timothy R.; Smith, Martin 

Subject: Quarterly GW sampling - Decatur Former Sludge Incorporation Area Wells 

Sue: 

WESTON will be performing quarterly groundwater sampling of the former sludge incorporation area (FSIA) wells 

beginning on June 20, 2011. The attached word document shows the FSIA wells (highlighted in yellow) that will 

file://C:\Users\US263070\AppData\Local\Temp\notes256C9A\~web6824.htm 7/15/2011 
Page 4 of4 

be sampled for fluorochemlcal analyses.under GLP 10-01-01 and GLP 10-01-02. It also shows sampling schedule 

for other quarterly sampling (and conventional parameters) 

Also attached is a spreadsheet summary table from the most recent (Nov-2010) round at the FSIA wells. 

In addition to the primary/duplicate/spike bottles, we will need bottles and Milli-Q water for the two equipment 

rinseate blanks that will be collected. 

Thanks, 

Charlie 

Charles T. Young 

Technical Director 

Weston Solutions, Inc. 

1400 Weston Way (5-2) 

West Chester, PA 19380 

(610) 701-3787 

Fax (610) 701-3401 

CONFIDENTIALITY: This email and attachments may contain information which is confidential and 

proprietary. Disclosure or use of any such confidential or proprietary information without the written 

permission of Weston Solutions, Inc. is strictly prohibited. If you received this email in error, please 

notify the sender by return e-mail and delete this email from your system. Thank you. 

CONFIDENTIALITY: This email and attachments may contain information which is confidential and 

proprietary. Disclosure or use of any such confidential or proprietary information without the written 

permission of Weston Solutions, Inc. is strictly prohibited. If you received this email in error, please 

notify the sender by return e-mail and delete this email from your system. Thank you. 

file://C:\Users\US263070\AppData\Local\Temp\notes256C9 A\~web6824.htm 7/15/2011 
3M ENVIRONMENTAL LABORATORY 

Note to File 

Project or Study Number: 

LIMS Number: 

Affected Data: 

GLPlO-01-01-18 

GLPlO-01-01-18 

None 

All logbook pages for the individual stock standards and mixes used for the calibration curves 

and LCS used for the analysis of GLP10-01-01-18 were printed to pdf (exact copies of originals) 

and included in a folder labeled 'Logbook pages used for GLPlO-01-01-18' located in the project 

folder located at: 

\\Winsnas01a\b2\Projects\Lab_ESA Analytical\Lab Requests 2011 -stw\GLP10-01 Decatur 

Phase 3\GLP10-01-01 PF0A\GLP10-01-01-18 FSIA GW-June 2011 

The chromatograms for results file kl 10715a and kl 10728a were printed to pdf and saved in the 

project folder located at: 

\\Winsnas01a\b2\Projects\Lab_ESA Analytical\Lab Requests 2011 -stw\GLP10-01 Decatur 

Phase 3\GLP10-01-01 PF0A\GLP10-01-01-18 FSIA GW-June 2011 

A pdf copy of the signed protocol amendment GLPIO-OI-OI Amendment 18 is located in the 

project folder located at: 

\\Winsnas01a\b2\Projects\Lab_ESA Analytical\Lab Requests 2011 -stw\GLP10-01 Decatur 

Phase 3\GLP10-01-01 PF0A\GLP10-01-01-18 FSIA GW-June 2011 

Once the data package has been reviewed by QA and the report signed, the pdf will be moved to 

the shared drive (\\Winsnas01a\b2\Projects\Lab_Shared\Archive Requests\Electronic Reports) 

and a reference to the location of the pdf will be added to the archived request form under Elec 

Media Path. 

Recorded By: Date: 

Page 1 of 1 
Standard Prep 

Sample Prep 

Collection Bottle Prep 
Note To File 

Project or Study 

Description: 

LIMS Number: 

Affected Data: 

Decatur Phase 3 - FSIA groundwater 

GLPlO-01-01-18 

None 

One hundred sixty-four 250 mL Nalgene bottles were marked with a 200 mL level line and labeled. 

The following trip blanks/spikes were filled with Milli Q water (TN11-0208) and sealed after they were spiked. 

Two bottles will be provided to be used as equipment rinseate blanks, along with 1-L of Milli Q Water (TN11-

0208). 

On 6/15/11, the field matrix spike bottles were spiked with the following: 

Internal Standard will be added to the following sample sets: 134S, 135S, 136R, 137R, 137S, 137L, 138L, Trip 

Blank sample 1 and 2, Trip Blanks LS 1 and 2, and equipment rinseate blanks. 

Intemal Standards: Sample bottles (250-mL) will be spiked with the following: 

Bottle description Spike Description 

Spike Level Spiking 

Solution ID 

Gone, of 

Spiking 

solution 

Volume of 

spiking 

solution (ML) 

See above IS - Acids, Sulfonates, PFOSA 1.0 ng/mL 10 006-129 2.0 MQ/ml 100 

Field Matrix Spikes 

Well No. 

134S,135S, 136R, 137R,137S, 

137Land138L 

130L, 131S, 131L, 133R, 135L, 

136S, 136L, 141R, 142R, 143R and 

144R 

130R, 130S, 133S, 133L, 134L, 

138R, 138S, CW26C, CW26L and 

140R 

131R, 134Rand135R 

Trip Blank Sets 1 and 2 

Sample 

Level 

Low 

Mid 

High 

Low 

Mid 

High 

Low 

Mid 

High 

Low 

High 

Low 

Mid 

Mid-High 

High 

Spiking 

Solution 

10 006-141 

10 006-141 

10 006-141 

10 006-141 

10 006-141 

10 006-140 

10 006-141 

10 006-140 

10 006-140 

10 006-140 

10 006-139 

10 006-141 

10 006-141 

10 006-140 

10 006-140 

Approx. 

Value 

(jjg/mL) 

2.0 

2.0 

2.0 

2.0 

2.0 

100 

2.0 

100 

100 

100 

500 

2.0 

2.0 

100 

100 

Spike 

Amount 

(ML) 

10 

100 

1000 

100 

1000 

200 

1000 

200 

1000 

200 

800 

100 

1000 

200 

1000 

Spike 

Cone. 

(ng/mL) 

0.1 

1.0 

10 

1 

10 

100 

10 

100 

500 

100 

2000 

1 

10 

100 

500 

Used Eppendorf Research pipettes 3402277 and 2077127 to add spiking solution to samples. 

Recorded By: Date: 
Printing 7/14/2011; 3:56 PM 

6LP10-01-01-18 Sample Prep Work Sheet; ETS-8-044 

datej7/14/1/1 

rv<^(^ns^/^ it ^ - ^ Sample ID ' 

LCS-110714-1 

LCS-110714-2 

LCS-110714-3 

LCS-110714-4 

LCS-110714-5 

LCS-110714-6 

LCS-110714-7 

LCS-110714-8 

LCS-110714-9 

LCS-110714-10 

LCS-110714-11 

LCS-110714-12 

LCS-110714-13 

LCS-110714-14 

LCS-110714-15 

LCS-110714-16 

LCS-110714-17 

LCS-110714-18 

Analyst: CJG 

Sample Description 

O.Sppb LCS 

O.Sppb LCS 

O.Sppb LCS 

5ppb LCS 

5ppb LCS 

5ppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

0.5ppb LCS ECF 

0.5ppb LCS ECF 

0.5ppb LCS ECF 

5ppb LCS ECF 

5ppb LCS ECF 

5ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

Spii(ing std ID 

10 006-147 

10 006-147 

10 006-147 

10 006-146 

10 006-146 

10 006-146 

10 006-145 

10 006-145 

10 006-145 

11 005-47 

11 005-47 

11 005-47 

11 005-46 

11 005-46 

11 005-46 

10 006-152 

10 006-152 

10 006-152 

Spike Amt (pL) 

50 

50 

50 

50 

50 

50 

30 

30 

30 

50 

50 

50 

25 

25 

25 

30 

30 

30 

Lab water (mL) 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

7/14/11 CJG; LCS and Solvent Blanks prepared with Milli Q Water (TN11-0234), vortex mixed, and aliquoted into 2-mL glass autovials. 

1 1 7/14/11 CJG; 1 setof aliquots of 11003-26 curve w^as transten'ed into 2-mL glass autovials 

1 1 

Total Volume (mL) 

10.05 

10.05 

10.05 

10.05 

10.05 

10.05 

10.03 

10.03 

10.03 

10.05 

10.05 

10.05 

10.025 

10.025 

10.025 

10.03 

10.03 

10.03 

7/14/11 CJG; Samples GLPlO-01-01-18 requiring 1:10 dilution were prepared by taking 1 mL of sample and adding 9 mL of Milli Q Element Water (TN11-0234), mixed , and then aliquoted into 2-mL glass autovials. 

7/14/11 CJG; Samples GLPlO-01-01-18 requiring 1:100 dilution were prepared by taking 0.1 mL of sample and adding 9.9 mL of Milli Q Element Water (TN11-0234), mixed , and then aliquoted into 2-mL glass autovials. 

7/14/11 CJG; Samples GLPlO-01-01-18 not requiring dilution were aliquoted into a 2-mL glass autovial 

1 

7/14/11 CJG; Pipettes used: 3402277, 2077127 

/'"^'" ^ r^ 

CL^?{e.e \ ^ 

"TV 11 

-r\-H-AcVied Mafe>e\' 

\^ 1 J-- ^ f^' 

IP r\i\uric>n \~nrfi\^ 

9^e:t O^r -fh 1 ^ 1 J 

' i ^ \\^ M \ry 

• , r v 

^ St'^f 

^y + -r?) t 

^ ,, 

^vDpie..^; rao^Luri 

OP s<^rn'i"' 

,. 

na cm\\j M . A f Or^rXW T ' on 

tlorihrt^ 

•n-« 1 

K FJil l 

ETS-8-044 sample prep 110714.xls C3'6~7jlM/l Page 1 of 1 
Cun/e Points and LCS; Method ETS-8-044 

Concentration - ug/mL 

Stock ID 

10 006-147 

10 006-146 

10 006-145 

10 006-130 

10 006-131 

11 005-46 

11 005-47 

10 006-152 

PFOA 

0.1000 

1.000 

10.00 

100 

2.00 

0.100 

10.0 

PFBS 

0.1000 

1.000 

10.00 

100 

-

PFHS 

0.100 

1.00 

10.0 

100 

-

PFOS 

0.1000 

1.000 

10.00 

100 

1.99 

0.0995 

9.95 

11003-26-1 0.025 ng/mL FC std in Milli Q Water 

11003-26-2 0.03 ng/mL FC std in Milli Q Water 

11003-26-3 0.04 ng/mL FC std in Milli Q Water 

11003-26-4 0.05 ng/mL FC std in Milli Q Water 

11003-26-5 0.1 ng/mL FC std in Milli Q Water 

11003-26-6 0.25 ng/mL FC std in Milli Q Water 

11003-26-7 0.5 ng/mL FC std in Milli Q Water 

11003-26-8 1.0 ng/mL FC std in Milli Q Water 

11003-26-9 2.5 ng/mL FC std in Milli Q Water 

11003-26-10 5.0 ng/mL FC std in Milli Q Water 

11003-26-11 10 ng/mL FC std in Milli Q Water 

11003-26-12 25 ng/mL FC std in Milli Q Water 

11003-26-13 50 ng/mL FC std in Milli Q Water 

11003-26-14 75 ng/mL FC std in Milli Q Water 

11003-26-15 100 ng/mL FC std in Milli Q Water 

LCS-110714-1 O.Sppb LCS 

LCS-110714-2 O.Sppb LCS 

LCS-110714-3 O.Sppb LCS 

LCS-110714-4 SppbLCS 

LCS-110714-5 SppbLCS 

LCS-110714-6 SppbLCS 

LCS-110714-7 30ppbLCS 

LCS-110714-8 30ppbLCS 

LCS-110714-9 30ppbLCS 

LCS-110714-10 O.Sppb LCS ECF 

LCS-110714-11 O.Sppb LCS ECF 

LCS-110714-12 O.Sppb LCS ECF 

LCS-110714-13 SppbLCSECF 

LCS-110714-14 SppbLCSECF 

LCS-110714-1S SppbLCSECF 

LCS-110714-16 30ppb LCS ECF 

LCS-110714-17 aOppb LCS ECF 

LCS-110714-18 30ppb LCS ECF 

PFOA 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

25.0 

50.0 

75.0 

100 

0.498 

0.498 

0.498 

4.98 

4.98 

4.98 

29.9 

29.9 

29.9 

0.498 

0.498 

0.498 

4.99 

4.99 

4.99 

29.9 

29.9 

29.9 

PFBS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

25.0 

50.0 

75.0 

100 

PFHS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

25.0 

50.0 

75.0 

100 

0.498 

0.498 

0.498 

4.98 

4.98 

4.98 

29.9 

29.9 

29.9 

-

0.498 

0.498 

0.498 

4.98 

4.98 

4.98 

29.9 

29.9 

29.9 

-

PFOS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

25.0 

50.0 

75.0 

100 

0.498 

0.498 

0.498 

4.98 

4.98 

4.98 

29.9 

29.9 

29.9 

0.495 

0.495 

0.495 

4.96 

4.96 

4.96 

29.8 

29.8 

29.8 

Stock ID 

10 006-147 

10 006-147 

10 006-147 

10 006-147 

10 006-147 

10 006-147 

10 006-146 

10 006-146 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-147 

10 006-147 

10 006-147 

10 006-146 

10 006-146 

10 006-146 

10 006-145 

10 006-145 

10 006-145 

11005-47 

11005-47 

11 005-47 

11 005-46 

11 005-46 

11 005-46 

10 006-152 

10 006-152 

10 006-152 

Spike 

Volume 

(uL) 

25 

30 

40 

50 

100 

250 

50 

100 

25 

50 

100 

250 

500 

750 

1000 

50 

50 

50 

50 

50 

50 

30 

30 

30 

50 

50 

50 

25 

25 

25 

30 

30 

30 

Final 

Volume 

(mL) 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

10.05 

10.05 

10.05 

10.05 

10.05 

10.05 

10.03 

10.03 

10.03 

10.05 

10.05 

10.05 

10.025 

10.025 

10.025 

10.03 

10.03 

10.03 

ETS-8-044 sample prep 110714.xls Calibration Curve Page 1 of 1 
Sampl

e Id Description Prep Date 

LCS-110714-1 O.Sppb LCS Prepared: 7 

LCS-110714-2 O.Sppb LCS Prepared: 7/ 

LCS-110714-3 O.Sppb LCS Prepared: 7J 

LCS-110714-4 SppbLCS Prepared: 7i 

LCS-110714-5 SppbLCS Prepared: 7; 

LCS-110714-6 SppbLCS Prepared: 7; 

LCS-110714-7 SOppbLCS Prepared: 7; 

LCS-110714-8 SOppbLCS Prepared: 7/ 

LCS-110714-9 30ppbLCS Prepared: 7/ 

LCS-110714-10 O.Sppb LCS ECF Prepared: 7J 

LCS-110714-11 O.Sppb LCS ECF Prepared: 7i 

LCS-110714-12 O.Sppb LCS ECF Prepared: 7i 

LCS-110714-13 SppbLCSECF Prepared: 7; 

LCS-110714-14 SppbLCSECF Prepared: 7i 

LCS-110714-15 SppbLCSECF Prepared: 7i 

LCS-110714-16 30ppbLCSECF Prepared: 7i 

LCS-110714-17 30ppbLCSECF Prepared: 7i 

LCS-110714-18 30ppbLCSECF Prepared: 7/ 

GLP10-01-01-18-005 Trip BlankSet2HS(di l 1:100) Prepared: 7; 

GLP10-01-01-18-006 DAL GW130R 0 110630 (dil l :100) Prepared: 7, 

GLP10-01-01-18-007 DAL GW130RDB 110630 (dil 1:100) Prepared: 7; 

GLP10-01 -01 -18-008 DAL GW 130R LS 110630 (dil 1:100) Prepared: 7; 

GLP10-01-01-18-009 DAL GW130R MS 110630 (dil 1:100) Prepared: 7; 

GLP10-01-01-18-010 DAL GW130RHS 110630 (dill : 100) Prepared: 7, 

GLP10-01-01-18-011 DAL GW130S 0 110630 (dil l :10) Prepared: 7, 

GLP10-01-01-18-012 DAL GW130S 0 110630 (dil 1:10) Prepared: 7; 

GLP10-01-01-18-013 DAL GW130SLS 110630 (dil 1:100) Prepared: 7, 

GLP10-01-01-18-014 DAL GW130S MS 110630 (dil 1:100) Prepared: 7, 

GLP10-01-01-18-015 DAL GW130SHS 110630 (dill : 100) Prepared: 7i 

GLP10-01-01-18-016 DAL GW130L 0 110630 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-017 DAL GW130LDB 110630 (dil 1:10) Prepared: 7i 

GLP10-01-01-18-018 DAL GW130LLS 110630 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-019 DAL GW130L MS 110630 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-020 DAL GW130LHS 110630 (dil 1:10) Prepared: 7i 

GLP10-01-01-18-021 DAL GW131R 0 110622 (dil 1:100) Prepared: 7, 

GLP10-01-01-18-022 DAL GW 131R DB 110622 (dil 1:100) Prepared: 7, 

GLP10-01-01-18-023 DAL GW 131R LS 110622 (dil 1:100) Prepared: 7, 

GLP10-01-01-18-024 DAL GW 131R HS 110622 (dil 1:100) Prepared: 7, 

GLP10-01-01-18-025 DAL GW 131S 0 110622 (diM:10) Prepared: 7, 

GLP10-01-01-18-026 DAL GW 131S DB 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-027 DAL GW 131S LS 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-028 DALGW 131S MS 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-029 DAL GW 131S HS 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-030 DAL GW131L 0 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-031 DALGW 131LDB 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-032 DAL GW 131L LS 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-033 DAL GW 131L MS 110622 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-034 DAL GW 131L HS 110622 (dil 1:10) Prepared: 7; 

GLP10-01-01-18-03S DAL GW133L 0 110630 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-036 DAL GW 133L DB 110630 (dill : 10) Prepared: 7, 

GLP10-01-01-18-037 DAL GW 133L LS 110630 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-038 DAL GW 133L MS 110630 (dil 1:10) Prepared: 7J 

GLP10-01-01-18-039 DAL GW 133L HS 110630 (dil 1:10) Prepared: 7J 

GLP10-01-01-18-040 DALGW 1338 0 110630 (dil 1:10) Prepared: 7J 

GLP10-01-01-18-041 DAL GW133SDB 110630 (dil 1:10) Prepared: 7, 

GLP10-01-01-18-042 DAL GW 133S LS 110630 (dil 1:10) Prepared: 7j 

GLP10-01-01-18-043 DAL GW 1338 MS 110630 (dil 1:10) Prepared: 7i 

GLP10-01-01-18-044 DAL GW 1338 HS 110630 (dil 1:10) Prepared: 7; 

GLP10-01-01-18-04S DAL GW133R 0 110630 (dil 1:10) Prepared: 7; 

GLP10-01-01-18-046 DAL GW 133R DB 110630 (dill : 10) Prepared: 7i 

GLP10-01 -01 -18-047 DAL GW 133R LS 110630 (dill : 10) Prepared: 7j 

GLP10-01-01-18-048 DAL GW 133R MS 110630 (dil 1:10) Prepared: 7; 

GLP10-01-01-18-049 DAL GW 133R HS 110630 (dil 1:10) Prepared: 7J 

GLP10-01 -01 -18-OSO DAL GW 134R 0 110628 (dill : 100) Prepared: 7i 

GLP10-01-01-18-051 DAL GW134RDB 110628 (dil 1:100) Prepared: 7J 

GLP10-01-01-18-052 DAL GW 134R LS 110628 (dil 1:100) Prepared: 7/ 

GLP10-01 -01 -18-053 DAL GW 134R HS 110628 (dil 1:100) Prepared: 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

14/11 CJG 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic 

toxic, 

toxic, 

toxic 

toxic, 

toxic 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic 

toxic, 

toxic, 

toxic 

toxic, 

toxic, 

toxic, 

toxic 

toxic, 

toxic, 

toxic 

toxic, 

toxic 

toxic 

toxic 

toxic 

toxic 

toxic 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic. 

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ETS-8-044 sample prep 110714.xls label Pag

e 1 of 2 
Sample Id Description Prep Date 

GLP10-01-01-18-0S4 DAL GW134L 0 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-0S5 DAL GW134LDB 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-056 DAL GW 134L LS 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-0S7 DAL GW134L MS 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-058 DAL GW 134L HS 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-068 Trip Blank Set 1 HS (dil 1:100) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-074 DAL GW 135L 0 110628 (dil 1; 10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-07S DAL GW135LDB 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-076 DAL GW 135L LS 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-077 DAL GW 135L MS 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-078 DAL GW 135L HS 110628 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-079 DAL GW 13SR0 110628 (dil 1:100) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-080 DAL GW135RDB 110628 (dil 1:100) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-081 DAL GW135RLS 110628 (dil 1:100) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-083 DAL GW 13SR H8 110628 (dil 1:100) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-084 DAL GW 136L 0 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-08S DAL GW136LDB 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-086 DAL GW 136L LS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-1SS DAL GW136L MS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-087 DAL GW 136L HS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-088 DAL GW 1368 0 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-089 DAL GW 1368 DB 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-090 DALGW 1368 L8 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-091 DALGW 1368 MS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-092 DAL GW 1368 H8 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-103 DAL GW138R 0 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-104 DAL GW138RDB 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-1 OS DAL GW138RLS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-106 DAL GW138R MS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-107 DALGW 138RHS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-113 DAL GW138S 0 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-114 DAL GW138SDB 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-115 DAL GW 1388 LS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-116 DAL GW138S MS 110630 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-117 DAL GW 1388 HS 110630 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-118 DAL GWCW26C 0 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-119 DAL GWCW26CDB 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-120 DAL GWCW26CLS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-121 DAL GWCW26C MS 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-122 DAL GWCW26CHS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-123 DAL GWCW26L 0 110622 (dill : 10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-124 DAL GWCW26LDB 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-125 DAL GWCW26LL8 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-126 DALGWCW26LMS 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-127 DAL GWCW26LHS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-128 DALGW140R0110622(dil1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-129 DALGW 140RDB 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-130 DALGW 140RLS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-131 DALGW 140RM8 110622 (dil 1;10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-132 DALGW 140RHS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-139 DALGW141RHS110630(di l 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-140 DAL GW142R 0 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-141 DALGW 142RDB 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic 

GLP10-01-01-18-142 DALGW 142RLS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-143 DAL GW142R MS 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-144 DAL GW142RH8 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-14S DAL GW143R 0 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-146 DAL GW143RDB 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-147 DAL GW143RL8 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-148 DALGW 143R MS 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-149 DALGW 143RHS 110622 (dil 1:10) Prepared; 7/14/11 CJG toxic, 

GLP10-01-01-18-150 DALGW14480110628(di l 1:10) Prepared; 7/14/11 CJG toxic 

GLP10-01-01-18-1 SI DALGW 144SDB 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-1S2 DALGW 1448 L8 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-1 S3 DALGW 1448 MS 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

GLP10-01-01-18-154 DALGW 1448 H8 110622 (dil 1:10) Prepared: 7/14/11 CJG toxic, 

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ETS-8-044 sample prep 110714.xls label Page 2 of 2 
Sampl

e Id 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

11003-26-1 

11003-26-2 

11003-26-3 

11003-26^ 

11003-26-5 

11003-26-6 

11003-26-7 

11003-26-8 

11003-26-9 

11003-26-10 

11003-26-11 

11003-26-12 

11003-26-13 

11003-26-14 

11003-26-15 

LC8-110714-1 

LC8-110714-2 

LCS-110714-3 

LC8-110714-4 

LC8-110714-5 

LCS-110714-6 

LCS-110714-7 

LCS-110714-8 

LC8-110714-9 

LCS-110714-10 

LC8-110714-11 

LCS-110714-12 

LC8-110714-13 

LCS-110714-14 

LCS-110714-15 

LCS-110714-16 

LCS-110714-17 

LC8-110714-18 

GLP10-01-01-18-001 

GLP10-01-01-18-002 

GLP10-01-01-18-003 

GLP10-01-01-18-004 

GLP10-01-01-18-005 

GLP10-01-01-18-006 

GLP10-01-01-18-007 

GLP10-01-01-18-008 

GLP10-01-01-18-009 

GLP10-01-01-18-010 

GLP10-01-01-18-011 

GLP10-01-01-18-012 

GLP10-01-01-18-013 

GLP10-01-01-18-014 

GLP10-01-01-18-015 

GLP10-01-01-18-016 

GLP10-01-01-18-017 

GLP10-01-01-18-018 

GLP10-01-01-18-019 

GLP10-01-01-18-020 

GLP10-01-01-18-021 

GLP10-01-01-18-022 

Description 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

0.025 ng/mL FC std in Milli Q Water 

0.03 ng/mL FC std in Milli Q Water 

0.04 ng/mL FC std in Milli Q Water 

0.05 ng/mL FC std in Milli Q Water 

0.1 ng/mL FC std in Milli Q Water 

0.25 ng/mL FC std in Milli Q Water 

0.5 ng/mL FC std in Milli Q Water 

1.0 ng/mL FC std in Milli Q Water 

2.5 ng/mL FC std in Milli Q Water 

5.0 ng/mL FC std in Milli Q Water 

10 ng/mL FC std in Milli Q Water 

25 ng/mL FC std in Milli Q Water 

50 ng/mL FC std in Milli Q Water 

75 ng/mL FC std in Milli Q Water 

100 ng/mL FC std in Milli Q Water 

O.Sppb LCS 

O.Sppb LCS 

O.Sppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

Trip Blank Set 2 Sample 

Trip Blank Set 2 L8 

Trip Blank Set 2 MS 

Trip Blank Set 2 MHS 

Trip Blank Set 2 HS (dil 1:100) 

DAL GW 130R 0 110630 (dil 1:100) 

DAL GW 130R DB 110630 (dil 1; 100) 

DAL GW 130R L8 110630 (dil 1:100) 

DAL GW 130R MS 110630 (dil 1:100) 

DAL GW 130R HS 110630 (dil 1:100) 

DAL GW 130S 0 110630 (dil 1:10) 

DAL GW 1308 0 110630 (dil 1:10) 

DAL GW 1308 L8 110630 (diM: 100) 

DAL GW 1308 MS 110630 (dil 1:100) 

DAL GW 1308 HS 110630 (dil 1:100) 

DAL GW 130L 0 110630 (dil 1:10) 

DAL GW 130L DB 110630 (dil 1:10) 

DAL GW 130L LS 110630 (dil 1:10) 

DAL GW 1 SOL MS 110630 (dil 1:10) 

DAL GW 130L HS 110630 (dil 1:10) 

DAL GW 131R 0 110622 (dil 1:100) 

DALGW 131R DB 110622 (dil 1:100) 

Prep Date 

iquoted: 'i 

iquoted: ^i 

iquoted; 'i 

Aliquoted; 1 

iquoted; 7, 

iquoted; 7 

iquoted: 7 

iquoted: 7i 

iquoted; 7, 

iquoted; 7, 

iquoted 

iquoted 

iquoted: 7, 

iquoted; 7, 

iquoted 

iquoted: 7i 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 7 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted; 

iquoted; 

iquoted; 

iquoted: 

iquoted: 

iquoted; 

iquoted; 

iquoted: 

iquoted; 

iquoted; 

iquoted; 

iquoted; 

iquoted: 

iquoted: 

iquoted; 

iquoted; 

iquoted; 

iquoted: 

iquoted: 

iquoted: 

iquoted; 

iquoted; 

iquoted: 

iquoted; 

iquoted; 

iquoted: 

iquoted: 

iquoted; 

iquoted; 

iquoted; 

iquoted; 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

15/11 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

15/11 CJG 

oxrc, 

oxic 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

oxic, 

oxic, 

oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

:oxic, 

loxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic, 

oxic 

oxic, 

oxic 

oxic 

oxic, 

oxic, 

oxic 

oxic 

oxic 

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ETS-8-044 sample prep 110714.xls label (2) Page 1 of 3 
Sample Id Description Prep Date 

GLP10-01-01-18-023 DALGW 131R LS 110622 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-024 DAL GW 131R HS 110622 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-025 DAL GW 1318 0 110622 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-026 DAL GW 131S DB 110622 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-027 DAL GW 1318 L8 110622 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-028 DAL GW 131S MS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-029 DAL GW 1318 HS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-030 DAL GW 131L 0 110622 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-031 DALGW131LDB110622(dil1;10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-032 DALGW 131LLS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-033 DALGW 131L MS 110622 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-034 DAL GW 131L HS 110622 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-03S DAL GW133L 0 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-036 DAL GW 133L DB 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-037 DALGW 133L L8 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-038 DAL GW 133L MS 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-039 DALGW 133L HS 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-040 DAL GW133S 0 110630 (diM: 10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-041 DALGW 1338 DB 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-042 DALGW133SLS 110630(dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-043 DALGW 133S MS 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-044 DAL GW 133S HS 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-045 DAL GW 133R 0 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-046 DAL GW 133R DB 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-047 DAL GW 133R LS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-048 DAL GW 133R MS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-049 DAL GW 133R H8 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-050 DAL GW 134R 0 110628 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-051 DAL GW 134R DB 110628 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-052 DAL GW 134R LS 110628 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-053 DAL GW 134R HS 110628 (dil 1;100) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-054 DAL GW 134L 0 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-055 DAL GW 134L DB 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-0S6 DAL GW 134L LS 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-057 DAL GW 134L MS 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-058 DAL GW 134L H8 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-059 DAL GW 134S 0 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-060 DALGW 1348 DB 110628 Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-061 DAL GW 1348 LS 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-062 DAL GW 1348 MS 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-063 DAL GW 1348 HS 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-064 Trip Blank Set 1 Sample Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-06S Trip Blank Set 1 LS Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-066 Trip Blank Set 1 MS Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-067 Trip Blank Set 1 MHS Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-068 Trip Blank Set 1 HS (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-069 DAL GW 1358 0 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-070 DAL GW 1358 DB 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-071 DAL GW 1358 L8 110628 Aliquoted: 7/15/11 CJG 

GLP10-01 -01 -18-072 DAL GW 1358 MS 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-073 DAL GW 135S HS 110628 Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-074 DALGW 13SL0 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-075 DAL GW 135L DB 110628 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-076 DAL GW 13SL L8 110628 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-077 DAL GW 135L MS 110628 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-078 DAL GW 135L HS 110628 (dil 1; 10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-079 DAL GW 135R 0 110628 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-080 DAL GW13SRDB 110628 (dil 1:100) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-081 DAL GW135R LS110628 (dil 1:100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-083 DAL GW 135R HS 110628 (diM: 100) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-084 DALGW 136L0 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-085 DAL GW 136L DB 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-086 DALGW136LL8 110630(dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-15S DAL GW136L MS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-087 DAL GW 136L HS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

GLP10-01-01-18-088 DAL GW 136S 0 110630 (dil 1:10) Aliquoted; 7/15/11 CJG 

GLP10-01-01-18-089 DAL GW 1368 DB 110630 (dil 1:10) Aliquoted: 7/15/11 CJG 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic. 

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ETS-8-044 sample prep 110714.xls label (2) Page 2 of 3 
Sample Id Description Prep Date 

GLP10-01-01-18-090 DALGW 1368 LS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-091 DALGW 1368 MS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-092 DAL GW 1368 HS 110630 (diM: 10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-093 DAL GW 137S 0 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-094 DAL GW 137S DB 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-095 DAL GW 1378 LS 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-096 DALGW 1378 MS 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-097 DAL GW 1378 HS 110624 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-098 DAL GW 137L 0 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-099 DAL GW 137L DB 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-100 DAL GW137L LS110624 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-101 DAL GW137L MS 110624 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-102 DAL GW137LHS 110624 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01 -01 -18-103 DAL GW 138R 0 110630 (dil 1; 10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-104 DAL GW138RDB 110630 (dil 1:10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-105 DAL GW138R LS110630 (dill: 10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-106 DALGW138RMS110630(dil1:10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-107 DAL GW138RHS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-108 DALGW 138L0 110630 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-109 DAL GW138LDB 110630 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-110 DAL GW138LL8 110630 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-111 DAL GW138L MS 110630 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-112 DAL GW138LH8 110630 Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-113 DALGW 1388 0 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-114 DAL GW 1388 DB 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-115 DAL GW 138S LS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-116 DALGW1388M8110630(dil1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-117 DAL GW 1388 HS 110630 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-118 DAL GWCW26C 0 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-119 DALGWCW26CDB110622(dil1;10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-120 DAL GWCW26CL8 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-121 DALGWCW26CMS 110622 (dil 1:10) Aliquoted; 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-122 DAL GW CW26C HS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-123 DAL GWCW26L 0 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-124 DALGWCW26LDB110622(diM;10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-125 DAL GWCW26L LS110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-126 DAL GWCW26L MS 110622 (dil 1:10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-127 DALGWCW26LHS110622(diM;10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-128 DAL GW140R 0 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-129 DAL GW140RDB 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-130 DAL GW140RLS 110622 (diM;10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-131 DAL GW140R MS 110622 (dill ;10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-132 DAL GW140RH8 110622 (diM :10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-133 DAL GW130LRB 110630 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-134 DALGW 1338 RB 110630 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-135 DAL GW141R 0 110630 Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-136 DALGW 141RDB 110630 Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-137 DAL GW 141RL8 110630 Aliquoted; 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-138 DAL GW 141R MS 110630 Aliquoted; 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-139 DAL GW141RHS 110630 (dil 1:10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-140 DAL GW142R0 110622 (diM;10) Aliquoted; 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-141 DAL GW142RDB 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-142 DAL GW142RL8 110622 (dil1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-143 DAL GW142R MS 110622 (dil1;10) Aliquoted; 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-144 DAL GW142RHS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-145 DAL GW143R0 110622 (dil1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-146 DAL GW143RDB 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-147 DAL GW143RLS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-148 DAL GW143R MS 110622 (dil1:10) Aliquoted: 7/1S/11 CJG toxic. Refrigerate 

GLP10-01-01-18-149 DALGW143RHS110622(dil1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-1 SO DAL GW 144S 0 110628 (dil 1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-151 DALGW 144SDB 110622 (dil1:10) Aliquoted: 7/15/11 CJG toxic. Refrigerate 

GLP10-01-01-18-152 DAL GW144S LS110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-1 S3 DALGW 1448 MS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

GLP10-01-01-18-154 DAL GW 1448 HS 110622 (dil 1:10) Aliquoted: 7/15/11 CJG toxic, Refrigerate 

ETS-8-044 sample prep 110714.xls label (2) Page 3 of 3 
Printing 7/26/2011; 3:39 PM 

GLP10-01-01-18, GLP10-01-01-19 Sample Prep Work Sheet; ETS-8-044 

date: 7/26/11 

Sample ID 

LCS-110726-1 

LCS-110726-2 

LCS-110726-3 

LCS-110726-4 

LCS-110726-5 

LCS-110726-6 

LCS-110726-7 

LCS-110726-8 

LCS-110726-9 

LCS-110726-10 

LCS-110726-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-15 

LCS-110726-16 

LCS-110726-17 

LCS-110726-18 

Analyst: CJG 

Sample Description 

0.2ppb LCS 

0.2ppb LCS 

0.2ppb LCS 

2ppb LCS 

2ppb LCS 

2ppb LCS 

20ppb LCS 

20ppb LCS 

20ppb LCS 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

Spiking std ID 

10 006-147 

10 006-147 

10 006-147 

10 006-146 

10 006-146 

10 006-146 

10 006-145 

10 006-145 

10 006-145 

11 005-47 

11 005-47 

11 005-47 

11 005-46 

11 005-46 

11 005-46 

10 006-152 

10 006-152 

10 006-152 

Spike Amt 

(ML) 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

10 

10 

10 

20 

20 

20 

Lab water 

(mL) 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

10.0 

Internal 

Standard ID 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

11005-30 

11 005-30 

11 005-30 

11 005-30 

11 005-30 

Spike Amt (pL) 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

Final Volume 

(mL) 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.06 

10.06 

10.06 

10.07 

10.07 

10.07 

7/26/11 CJG; LCS prepared with Syntiietic groundwater 10 006-171, vortex mixed, and 1 set were transferred into 2-mL autovials. 

7/26/11 CJG; 1 set of aliquots of 11 003-25-1 through 16 were transferred into 2-mL autovials. 

7/26/11 CJG; 10 replicates of 11 005-59 were aliquoted for method blanks. 

7/26/11 CJG; LCS spiked using Eppendorf Research pipette 4215537. 

7/26/11 CJG; GLP10-01-01-18, GLP10-01-01-19 samples were aliquoted into 2 mL autovia S. 

The-fbllDVMinaGLPIO'Ol'Ol'lSSdmpleS were a\i^uotfedS G>LPlO0l-0i-i^-0(f?S, -010 , a.nd-013^ 

CTG Slsl) I 

ETS-8-044 sample prep 110726.xls , Page 1 of 1 
Curve Points and LCS; Method ETS-8-044 ETS-8-044 sample prep 110726.xls 

Stock ID 

10 006-147 

10 006-146 

10 006-145 

10 006-130 

10 006-131 

11002-214 

11 002-28 

10 006-88 

11 005-47 

11 005-46 

10 006-152 

Target Analyte Concentration (ug/mL) 

PFdA 

0.100 

1.00 

10.0 

100 

-

0.100 

2.00 

10.0 

PFBS 

0.100 

1.00 

10.0 

100 

-

PFHS 

0.100 

1.00 

10.0 

100 

-

PFOS 

0.100 

1.00 

10.0 

100 

-

0.0995 

1.99 

9.95 

Stock ID 

11005-30 

10 006-149 

11 002-240 

11005-29,11005-28 

11 002-238 

11 002-239 

Internal Standard Concentration (ug/mL) 

M8-PFOA 

0.200 

2.00 

-

4.99 

4.99 

1802PFBS 

0.195 

1.95 

81.2 

. 

M3PFHS 

0.189 

1.89 

4.73 

4.73 

M8-PF0S 

0.192 

1.92 

4.79 

4.79 

11 003-25-1 0.025 ng/mL FC std in Synth. Water 

11 003-25-2 0.03 ng/mL FC std in Synth. Water 

11 003-25-3 0.04 ng/mL FC std in Synth. Water 

11 003-25^ 0.05 ng/mL FC std in Synth. Water 

11 003-25-5 0.1 ng/mL FC std in Synth. Water 

11 003-25-6 0.25 ng/mL FC std in Synth. Water 

11 003-25-7 0.5 ng/mL FC std in Synth. Water 

11 003-25-8 1.0 ng/mL FC std in Synth. Water 

11 003-25-9 2.5 ng/mL FC std in Synth. Water 

11 003-25-10 5.0 ng/mL FC std in Synth. Water 

11 003-25-11 10 ng/mL FC std in Synth. Water 

11 003-25-12 15 ng/mL FC std in Synth. Water 

11 003-25-13 25 ng/mL FC std in Synth. Water 

11 003-25-14 50 ng/mL FC std in Synth. Water 

11 003-25-15 75 ng/mL FC std in Synth. Water 

11 003-25-16 100 ng/mL FC std in Synth. Water 

Internal Standard 1 ng/mL IS mix 

Final Spike Concentration (ng/mL) | 

PFOA 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

15.0 

25.0 

SO.O 

75.0 

100 

1.00 

PFBS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

S.OO 

10.0 

IS.O 

25.0 

50.0 

75.0 

100 

0.975 

PFHS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

15.0 

25.0 

50.0 

7S.0 

100 

0.945 

PFOS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

15.0 

25.0 

50.0 

75.0 

100 

0.960 

Stoc* ID 

10 006-147 

10 006-147 

10 006-147 

10 006-147 

10 006-147 

10 006-147 

10 006-146 

10 006-146 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-145 

10 006-149 

Spike 

Volume 

(uL) 

25 

30 

40 

50 

100 

250 

50 

100 

25 

50 

100 

150 

250 

500 

7S0 

1000 

50 

Final 

Volume 

(mL) 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

too 

100 

LCS-110726-1 

LCS-110726-2 

LCS-110726-3 

LCS-110726-4 

LCS-110726-5 

LCS-110726-6 

LCS-110726-7 

LCS-110726-8 

LCS-110726-9 

LCS-110726-10 

LCS-110726-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-15 

LCS-110726-16 

LCS-110726-17 

LCS-110726-18 

0.2ppb LCS 

0.2ppb LCS 

0.2ppb LCS 

2ppb LCS 

2ppb LCS 

2ppb LCS 

20ppb LCS 

20ppb LCS 

20ppb LCS 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

Internal standard 

LCS-110726-1 

LCS-110726-2 

LCS-110726-3 

LCS-110726-4 

LCS-110726-5 

LCS-110726-6 

LCS-110726-7 

LCS-110726-8 

LCS-110726-9 

LCS-110726-10 

LCS-110726-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-15 

LCS-110726-16 

LCS-110726-17 

LCS-110726-18 

0.2ppb LCS 

0.2ppb LCS 

0.2ppb LCS 

2ppb LCS 

2ppb LCS 

2ppb LCS 

20ppb LCS 

20ppb LCS 

20ppb LCS 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

0.199 

0.199 

0.199 

1.99 

1.99 

1.99 

19.9 

19.9 

19.9 

0.199 

0.199 

0.199 

1.99 

1.99 

1.99 

19.9 

19.9 

19.9 

Mi-PFOA 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.993 

0.994 

0.994 

0.994 

0.993 

0.993 

0.993 

0.199 

0.199 

0.199 

1.99 

1.99 

1.99 

19.9 

19.9 

19.9 

UdiPPbS 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.968 

0.969 

0.969 

0.969 

0.968 

0.968 

0.968 

0.199 

0.199 

0.199 

1.99 

1.99 

1.99 

19.9 

19.9 

19.9 

MaPFHS 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.938 

0.939 

0.939 

0.939 

0.938 

0.938 

0.938 

0.199 

0.199 

0.199 

1.99 

1.99 

1.99 

19.9 

19.9 

19.9 

0.198 

0.198 

0.198 

1.98 

1.98 

1.98 

19.8 

19.8 

19.8 

MS-PFOS 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.953 

0.954 

0.954 

0.954 

0.953 

0.953 

0.953 

10 006-147 

10 006-147 

10 006-147 

10 006-146 

10 006-146 

10 006-146 

10 006-145 

10 006-145 

10 006-145 

11 005-4 7 

11 005-4 7 

11005-4 7 

11005-4 6 

11005-4 6 

11 005-4 6 

10 006-15 2 

10 006-15 2 

10 006-15 2 

11005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11005-3 0 

11005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

11 005-3 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

2 0 

10 

10 

10 

2 0 

2 0 

2 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

5 0 

SO 

5 0 

5 0 

5 0 

5 0 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.06 

10.06 

10.06 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.07 

10.06 

10.06 

10.06 

10.07 

10.07 

10.07 

Pag e 1 of 1 

cse siiMi 
ETS-8-044 sample prep 110726.xls 

Sample Id 

LCS-110726-1 

LCS-110726-2 

LCS-110726-3 

LCS-110726-4 

LCS-110726-5 

LCS-110726-6 

LCS-110726-7 

LCS-110726-8 

LCS-110726-9 

LCS-110726-10 

LCS-110726-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-1S 

LCS-110726-16 

LCS-110726-17 

LCS-110726-18 

LCS-110726-1 

LCS-110726-2 

LCS-110726-3 

LCS-110726-4 

LCS-110726-5 

LCS-110726-6 

LCS-110726-7 

LCS-110726-8 

LCS-110726-9 

LCS-110726-10 

LCS-110726-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-15 

LCS-110726-16 

LCS-110726-17 

LCS-110726-18 

11 003-25-1 

11 003-25-2 

11 003-25-3 

11 003-25-4 

11003-25-5 

11 003-25-6 

11003-25-7 

11003-25-8 

11003-25-9 

11 003-25-10 

11 003-25-11 

11003-25-12 

11 003-25-13 

11 003-25-14 

11003-25-15 

11003-25-16 

11005-59 

11 005-59 

11005-59 

11005-59 

11 005-59 

11 005-59 

11 005-59 

11 005-59 

11 005-59 

11 005-59 

GLP10-01-01-18-069 

GLP10-01-01-18-070 

GLP10-01-01-18-073 

GLP10-01-01-19-001 

GLP10-01-01-19-002 

GLP10-01-01-19-003 

GLP10-01-01-19-004 

GLP10-01-01-19-005 

GLP10-01-01-19-006 

GLP10-01-01-19-007 

GLP10-01-01-19-008 

GLP10-01-01-19-009 

GLP10-01-01-19-010 

GLP10-01-01-19-011 

GLP10-01-01-19-012 

GLP10-01-01-19-013 

Description 

0.2ppb LCS 

0.2ppb LCS 

0.2ppb LCS 

2ppb LCS 

2ppb LCS 

2ppb LCS 

20ppb LCS 

20ppb LCS 

20ppbLCS 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

0.2ppb LCS 

0.2ppb LCS 

0.2ppb LCS 

2ppb LCS 

2ppb LCS 

2ppb LCS 

20ppb LCS 

20ppb LCS 

20ppb LCS 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

0.025 ng/mL FC std in Synth. Water 

0.03 ng/mL FC std in Synth. Water 

0.04 ng/mL FC std in Synth. Water 

0.05 ng/mL FC std in Synth. Water 

0.1 ng/mL FC std in Synth. Water 

0.25 ng/mL FC std in Synth. Water 

0.5 ng/mL FC std in Synth. Water 

1.0 ng/mL FC std in Synth. Water 

2.5 ng/mL FC std in Synth. Water 

5.0 ng/mL FC std in Synth. Water 

10 ng/mL FC std in Synth. Water 

15 ng/mL FC std in Synth. Water 

25 ng/mL FC std in Synth. Water 

50 ng/mL FC std in Synth. Water 

75 ng/mL FC std in Synth. Water 

100 ng/mL FC std in Synth. Water 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

Method Blank 

DALGW 135S 0 110628 

DAL GW135SDB 110628 

DAL GW135SHS 110628 

DALGWTRIP1 0 110713 

DALGWTRIP1 LS 110713 

DALGWTRIP1 MS 110713 

DALGWTRIP1 HS 110713 

DAL GW BPMW47 0 110713 

DAL GW BPMW47 DB 110713 

DAL GW BPMW47 LS 110713 

DAL GW BPMW47 HS 110713 

DALGWBPMW121 RS 110713 

DALGWBPMW121 0 110713 

DALGWBPMW121 DB 110713 

DALGWBPMW121 LS 110713 

DALGWBPMW121 HS 110713 

Prep Date 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

iquoted: 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

7/26/11 CJG 

hazard 

toxic, Ref 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

Ref 

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label Page 1 of 1 ar6^|i/iN 
Analytical Case Narrative 

Data Reduction Calculations 

Control Chart - Analytical 

Uncertainty 
3M Confidential 3M Environmental Laboratory 

Project: GLPlO-01-01-18 

Sequence kl 10715a 

3M Environmental Laboratory 

3M Technical Lead: Susan Wolf 

Building 260-5N-17 

651-733-9851 

Report Author Chelsie Grochow 

Analytical Team: Kelly Ukes 

Analytical Case Narrative for Method ETS-8-44.0 

Project GLPlO-01-01-18 

Decatur Phase 3 FSIA Groundwater- June 2011 

Direct injection analysis of diluted and undiluted samples 

Sequence k110715a 

Report Date: July 20, 2011 

Instrument summary and calibration curves will be printed and included in the raw data package. 

Chromatograms will be printed to pdf. 

ETS 8-044 Analytical Summary Checklist Page 1 of 3 
3M Confidential 

1 Project Scope and Data Quality Objective 

SIVI Environmental Laboratory 

Project: GLPlO-01-01-18 

Sequence kl 10715a 

General Project Outline available. 

GLP 

13 Yes 

13 Yes 

D No 

n No 

If No, Please briefly describe 

project scope and DQO 

2 Sample Container Preparation 

Sample container preparation documented in a Note to File and included in the raw data package. 

3 Sample Analysis 

3.1 System Suitability 

Initial System Suitability area counts with RSD <5% (ETS-8-154 section 

10.5) and retention time with RSD 52% JElYes D N o 

3.1.1 System Suitability Deviations 

NA 

3.2 Instrument Calibration 

Cun/e type 

r^>0.990 Linearity criteria met (ETS-8-44 section 12.2) 

< ± 25% residuals, except LOQ of ±30% (ETS-8-44 section 12.2) 

Mid-level calibration points disabled 

Quadratic, 1/x 

13 Yes 

13 Yes 

DYe s 

D N o 

D N o 

13 No 

3.3 Continuing Calibration Verification 

±25% Difference criteria met for periodic CCVs (ETS-8-44 section 12.2) 13 Yes n No 

3.3.1 Continuing Calibration Verification Deviations 

NA 

3.4 Method Blanks 

Method blanks uniquely identified in the run sequence. 

Average area counts of target analytes in the method blank present at s V^ x 

the area counts of the LOQ standard (ETS-8-44 Section 10.2) 

^Ye s 

13 Yes 

D N o 

D N o 

3.4.1 Method Blank Deviations 

NA 

ETS 8-044 Analytical Summary Checklist Page 2 of 3 
3I\/I Confidential 

3.5 Lab Control Spikes 

3I\/I Environmental Laboratory 

Project: GLPlO-01-01-18 

Sequence k l 10715a 

±20% recovery criteria met (ETS 8-44 Section 10.5) 

<20% RSD precision (ETS 8-44 Section 10.5) 

13 Yes 

13 Yes 

D N o 

D N o 

3.5.1 Lab Control Spike Deviations 

NA 

3.6 Sample Replicates 

RPD for field duplicates <20% (ETS-8-44 Section 10.5) 13 Yes D N o 

3.6.1 Sample Replicates Deviations 

NA 

3.7 Field Matrix Spikes 

±30% recovery criteria met. (ETS 8-44 Section 10.5) DYe s 13 No 

3.7.1 Field Matrix Spike Deviations 

DAL GW 135S: HS recovery 206%. 

DAL GW 135L: No appropriate FMS level to determine recovery. 

3.8 Limit of Quantitation (LOQ) 

All LOQs equal the low-level calibration standard concentration 

with area counts at least twice that of the method blank(s) (ETS 8-

44 Section 10.2) 

13 Yes D N o 

3.9 Manual Integrations 

Manual integration reviewed by another analyst/team lead: 

Reviewed bv: i^'TK Date: -^jzaj-Ze n 

13 Yes DNo 

4 Additional analytical notes 

All data will be reported except for DAL GW 135S due to unacceptable FMS recovery. 

5 Signatures 

^i}m.^yi&4im Lii -7/10/11 

Analyst Date 

ETS 8-044 Analytical Summary Checklist Page 3 of 3 
Kirk API 5500, BB21501010 page 1/1 

DATE: 7/15/2011 

ANALYST: CJG 

STUDY NUMBER: GLPlO-01-01-18 

Sample Prep Date: 7/14/11 

Sample Aliquot Date: 7/15/11 

LC/MS/MS Method: PFOA only 

Mobile Phase: (A) 2mM ammonium acetate (aq) (B) Methanol 

TN-A-or standard number (A) 11005-91 (B) TNI 1-0209 7/8 

Guard column: Prism RP Column 2.1x50mm 

Size: 5u Lot number: 9960 

Serial number 0711213T4 started 7/13/11 

Part number: 32105-052130 

Analytical column: Betasil CI8 Column 2.1x100mm 

Size: 5u Lot number: 10920 

Serial number 0516989T4 Started 7/13/11 

Part number: 70105-102130 

DATA FILE: kl 10715a 

See method for LC/MS/MS parameters 

Printed: Friday, July 15, 2011 3:42 PM 
*Kirk BB21501010 

Project: P:\Projects\LabJnslrumonl Data\Kir»kirkdata\ProioctafIuoroctiemtcals_walBrBalch;k110715a TabiSampla Set:SET1 AcqMelhod:PFOA 

Sample 

1 

2 

3 

4 

5 

6 

7 

8~ 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 • 

2 5 " 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 '" ^ 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

55 

56 

57 

58 

59 "' ~ 

60 

6i 

62 

63 

64 

65 

66 

67 

68 

69 

70 

71 

Sample Name 

k110715a001 

k110715a002 

k110715a003 

k110715a004 

k110715a005 

k110715a006 

k110715a007 

k110715a008 

k110715a009 

k110715a010 

k110715a011 

k110715a012 

k110715a013 

k110715a014 

k110715a015 

k110715a016 

k110716a017 

k1ia715a018 

k110715a019 

k110715a020 

k110715a021 

k110715a022 

k110715a023 

k110715a024 

k110715a025 

k1107153026 

kl107153027 

kl 107153028 

k1107153029 

k1107153030 

k110715a031 

k1107i5a032 

kl 107153033 

kl 107153034 

kl 107153035 

kl 107153036 

kl 107153037 

kl 107153038 

k110715a039 

k110715a040 

k110715a041 

k1107153042 

k1107153043 

k110715a044 

k1107153045 

k110715a046 

kl107153047 

k110715a048 

kl107153049 

k1107153050 

k110715a051 

k110715a052 

kl107153053 

kl107153054 

k1107153055 

k110715a056 

k110715a057 

kl107153058 

kl 107153059 

kl 107153060 

kl107153061 

kl 107153062 

kl107153063 

kl107153064 

k110715a065 

k110715a066 

k110715a067 

kl107153068 

kl107153069 

kl 107153070 

k1107153071 

Sample ID 

Solvent 6l3nk 

Solvent Bl3nk 

11003-26-8 

Solvent Blenk 

11003-26-9 

11003-26-9 

11003-26-9 

11003-26-9 

Solvent Blank 

Solvent Blenk 

11003-26-1 

11003-26-2 

11003-26-3 

11003-26-4 

11003-26-5 

11003-26-6 

11003-26-7 

11003-26-8 

11003-26-9 

11003-26-10 

11003-26-11 

11003-26-12 

11003-26-13 

11003-26-14 

11003-26-15 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvent Blank 

LCS-110714-1 

LCS-110714-2 

LCS-110714-3 

LCS-110714-4 

LCS-110714-5 

LCS-110714-6 

LCS-110714-7 

LCS-110714-8 

LCS-110714-9 

Solvent Blank 

Solvent Blank 

11003-26-10 

Solvent Blank 

LCS-110714-10 

LCS-110714-11 

LCS-110714-12 

LCS-110714-13 

LCS-110714-14 

LCS-110714-15 

LCS-110714-16 

LCS-110714-17 

LCS-110714-18 

Solvent Blank 

Solvent Blank 

11003-26-9 

Solvent Blank 

Solvent Blank 

GLP10-01-01-18-001 

GLP10-01-01-18-002 

GLP10-01-01-18-003 

GLP10-01-01-18-564 

GLP10-01-01-18-005 

GLP10-01-01-18-006 

GLP10-01-01-18-007 

GLP10-01-01-18-008 

GLP10-01-01-18-009 

GLP10-01-01-18-010 

Solvent Blank 

Solvent Blank 

11003-26-10 

Solvent Bl3nk 

GLP10-01-01-18-011 

Vial Position 

91 

91 

[8 

91 

9 

9 

9 

9 

91 

92 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

92 

92 

93 

93 

16 

17 

18 

19 

20 

21 

22 

23 

24 

93 

94 

10 

94 

25 ^ 

26 

27 

28 

29 

30 

31 

32 

33 

94 

94 

9 

95 

95 

34 

fe 36 

37 

38 

39 

40 

41 

42 

43 

95 

96 

10 

96 

44 

Data nie 

k110715a 

kl107153 

kl10716a 

kl10715a 

kl10715a 

k1107153 

kl10715a 

kl 10715a 

k1107153 

k1107153 

kl 107153 

kl 10715a • 

kl 10715a 

k110715a 

kl107153 

kl107153 

kl107153 

kl107153 

jk1107153 

ikTToTBs 

kl107153 

kl107163 

kl 10715a 

Kl 10715a 

k110715a 

k1107153 

k1107153 

k1107153 

k1107153 

k1107158 

k110715a 

k110715a 

k1107153 

k1107153 

k1107153 

k110715a 

k1107153 

k1107153 

kl107153 

k1107153 

kl107153 

k1107153 

k110715a 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k110715a 

k1107153 

k110715a 

k110715a 

k1107153 

kl107153 

kl107153 

k110715a 

kl10715a 

ki10715a 

kl10715a 

rw 10715a 

kl10715a 

k1107153 

kl10715a 

kl 10715a 

kl10715a 

kl10715a 

k1107153 

k1107153 

k110715a 

k110715a 

k1107153 

InJ.Volums (Ml) 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25000 

25.000 

25.000 

25.000 

25.000 

25.000 

25000 

25.000 

25.000 

25.000 

25,000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25000 

25.000 

25.000 

25.000 

25,000 

25.000 

25.000 

25.000 

25.000 

25.000 

25,000 

25,000 

26,000 

25,000 

26,000 

25000 

25,000 

25,000 

25000 

25,000 

25,000 

25,000 

25,000 

25,000 

25.000 

25000 

5.000 

25.000 

25.000 

25,000 

25,000 

25.000 

25.000 

25.000 

25.000 

25000 

26,000 

25.000 

Comments 

MilliQ Water TO11-0234 

MilliQ Water TO11-0234 

1,6 ng/mL FC std in Mill Q Water 

MilliQ Water TN11-0234 

2,5 ng/mL FC std in Milli Q Water 

2,5 ng/trlL FC std in Miiii Q Water 

2,5 ng/mL FC std in Mill Q Water 

2.5 ng/rtt FC sTd in Mil Q Weter 

MilliQ Water TN11-0234 

Mini Q Water TN11-0234 

0,025 ng/mL FC std in Mill Q Water 

0.03 ng/mL FC std in Mill Q Water 

0.04 ng/mL FC std in Mill Q Water 

0.05 ng/mL FC std in Mill Q Water 

0.1 ng/mL FC std in Milli Q Water 

0.25 ng/mL FC std in Mill Q Wster 

0.5 ng/mL FC std in Milli Q Wster 

1.0 ng/mL FC std in Milli Q Water 

2.5 ng/mL FC std in Milli Q Water 

5,0 ng/mL FC std in Milli Q Water 

10 ng/rtl. FC std in Milli Q Water 

25 ng/mL FC std in Milli Q Water 

50 nglni. FC std in Milli Q Water 

75 ng/mL FC std in MilliQ Water 

100 nglnL FC std in Milli Q Water 

MlliQ Water TN11-0234 

MilliQ Water TN11-0234 

Mill Q Water TM11-0234 

Mill Q Water TN11-0234 

0,5ppb LCS 

0,5ppb LCS 

O.Sppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

5.0 ng/mL FC std in Mini Q Water 

MilliQ Water TN11-0234 

O.Sppb LCS BCF 

O.Sppb LCS BCF 

O.Sppb LCS K F • 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

2,5 ng/mL FC std in Milli Q Water 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

Trip Blank Set 2 Sample 

Trip Blank Set 2 LS 

Trip Btenk Set 2 MS 

Trip Blank Set 2 MHS 

Trip Blank Set 2 HS (dil 1:100) 

DfVL GW 130R 0 110630 (dH 1:100) 

DAL GW130RDB 110630 (dil 1:100) 

DALGW 130R LS 110630 (dil 1:100) 

DAL GW 130R MS 110630 (dil 1:100) 

DALGW 130R HS 110630 (dil 1:100) 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

50 ng/mL FC std in MrDi Q Water 

MilliQ Water TN11-0234 

DAL GW 130S 0 110630 (dil 1:10) 

only.dam 

Printing Time: 

Printing Date: 

10:15:01 AM 

Monday, July 18 

Page 1 of 4 C^GllC^h^ 
*Kirl< BB21501010 

Project: P:\ProiectaLabJnslnimenl Data\Kirtokirkdata\Pro]ectafIuorocliemlcals_waterBatcti:k110715a Tab:Sample Sot:SET1 AcqMettiod:PFOA 

Sample 

,72 

73 

174 

'"75 "• • 

|76 

177 

;78 

J79 

|80 

'ei 

82 

183 

84 

85 

86 

87 

88 

89 

90 

91 

92 

93 

94 

95 

96 

97 

98 

99 

100 

101 

102 

103 

104 

105 

106 

107 

108 

109 

110 

111 

112 

113 

114 

115 

116 

117 

118 

119 

120 

121 

122 

123 

124 

125 ' 

126 

127 ' 

128 

"l29 " 

130 

131 

132 

133 

134 

135 

136 

137 

138 

139 

|l4 0 

1141 

jl42 

Sample Name 

kl 107153072 

kl107153073 

M l 67153074 

k110715a075 

k1107153076 

k1107153077 

k1107153078 

kTT67153079 

kl107153080 

k1107153081 

k110715a082 

kl 107153083 

k110715a084 

kl107153085 

k11071S3086 

k1107153087 

k1107153088 

kl 107153089 

k1107153090 

kl107153091 

kl 107153092 

kl107153093 

kl 167153094 

kl167153095 

k1107153096 

k11071Sa097 

kl 107153098 

kl107153099 

kl1071 Sal 00 

k11071S3l01 

k110715a102 

k110715a103 

k11071S3l04 

k1107153l05 

k11071S3l06 

k1107153l07 

k1107153l08 

kl107153109 

k1107153l10 

k1107153l11 

kli67i53l12 

k1107153l13 

kl107153114 

k11071Sa115 

k11071Sa116 

k11071S3l17 

k1107153l18 

k1l671Sa119 

k110715a120 

k110715a121 

k11071Sa122 

k11071Sa123 

k110715a124 

k11071S3l2S 

k11071Sa126 

k110715a127 

k1107153l28 

k1107153l29 

k1107153l30 

kl107153131 

k1107153l32 

k1107153l33 

k1l67153l34 

k11071S3l3S 

k11071Sa136 

k1107153l37 

k11071S3l38 

k110715a139 

k110715a140 

k110715a141 

k11071Sa142 

Sample ID 

GLP10-01-01-18-012 

GLP10-01-01-18-013 

GLPi6-6l-6i-i8::6l4 

GLP10-01-01-18-015 

GLP10-01-01-18-016 

GLP10-01-01-18-017 

GLP10-01-01-18-018 

GLP10-01-01-18-019 

GLP10-01-01-18-020 

Solvent Blank 

Solvent BIsnk 

11003-26-11 

Solvent Bl3nk 

GLP10-01-01-18-021 

GLP10-01-01-18-022 

GLP10-01-01-18-023 

GLP10-01-01-18-024 

GLP10-01-01-18-025 

GLP10-01-01-18-026 

GLP10-01-01-18-027 

GLP10-01-01-18-028 

GLP10-01-01-18-029 

Solvent Blank 

Solvent Blank 

11003-26-9 

Solvent Blank 

GLP10-01-01-18-030 

GLP10-01-01-18-031 

GLP10-01-01-18-032 

GLP10-01-01-18-033 

GLP10-01-01-18-034 

GLP10-01-01-18-035 

GLPI0-01-01-18-036 

GLP10-01-01-18-037 

GLPI 0-01-01-18-038 

GLPI 0-01-01-18-039 

Solvent Blank 

Solvent Blank 

11003-26-10 

Solvent Blank 

GLPI 0-01-01-18-040 

GLPI 0-01-01-18-041 

GLPI 0-01-01-18-042 

GLPI 0-01-01-18-043 

GLPI 0-01-01-18-044 

GLPI 0-01-01-18-045 

GLPI 0-01-01-18-046 

GLPI 0-01-01-18-047 

GLPI 0-01-01-18-048 

GLPI 0-01-01-18-049 

Solvent Blenk 

Solvent Blenk 

11003-26-8 

Solvent Blenk 

GLPI 0-01-01-18-050 

GLPI 0-01-01-18-051 

GLPI 0-01-01-18-052 

GLPI 0-01-01-18-053 

GLPI 0-01-01-18-054 

GLPI 0-01-01-18-055 

SCn 6-013T-18-056 

GLPI 0-01-01-18-057 

GLPI 0-01-01-18-058 

Solvent Bl3nk 

Solvent BIsnk 

11003-26-9 

Solvent Bl3nk 

GLPI 0-01-01-18-059 

GLPI 0-01-01-18-060 

GLPI 0-01-01-18-061 

GLPI 0-01-01-18-062 

VisI Position 

45 

46 

47 

46 

49 

50 

51 

52 

53 

96 

97 

11 

97 

54 

55 

56 

57 

58 

59 

60 

61 

62 

97 

98 

9 

98 

63 

64 

65 

66 

67 

68 

69 

70 

71 

72 

98 

99 

10 

,_ _| 

73 

74 

75 

76 

77 

78 

79 

80 

81 

82 

99 

100 

8 

100 

83 

84 

85 

86 

87 

88 

89 

90 

16 

100 

91 

9 

91 

17 

18 

19 

20 

Data RIe 

k110715a 

k11071Sa 

k1ld715a 

k110715a 

k11071S3 

k110715a 

k110715a 

k11071Sa 

k11071 S3 

k1107153 

k1107153 

kl107153 

k1107153 

k1107153 

kl107153 

kl10715a 

kl107153 

kl107153 

kl107153 

kl107153 

kl1071 S3 

kl1071 S3 

ki107153 

ki107153 

ki107153 

ki 107153 

k11071S3 

k11071S3 

k11071Sa 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k11071S3 

k110715a 

k11071Sa 

k110715a 

k1107153 

k110715a 

k110715a 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k110715a 

k11071S3 

k11071Sa 

k1107153 

k11071Sa 

k11071Sa 

k110715a 

k1107153 

k1107153 

k110715a 

iiiiofis'a 

kl10715a 

k1107153 

kl 107153 

kl107153 

kl107153 

kl1071 S3 

kl107153 

k1107153 

kl107153 

kl107153 

k1107153 

Inj.Volume (|il) 

25.000 

25.000 

25.000 

25.000 

25.660 

25000 

25.000 

25,000 

25.000 

25.000 

25.000 

25.000 

25000 

25000 

25000 

25.000 

25,000 

5.000 

5.000 

5.000 

5.000 

5.000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

5,000 

5,000 

5.000 

5.000 

5.000 

25.000 

25.000 

25.000 

25.000 

5,000 

5,000 

5,000 

5,000 

5.000 

25.000 

25.000 

25,000 

25,000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25666 

5:60b " 

5,666 

5,000 

5,000 

5,000 

25,000 

25,000 

25.000 

25.000 

5.000 

5.000 

5,000 

5.000 

Comment s 

DAL GW130S0 110630 (dil 1:10) 

D^L GW 130S LS 110630 (dil 1:100) 

CV\LGW130S MS 110630 (dil 1:100) 

DAL GW 130S HS 110630 (dj 1:100) 

DAL GW130L 0 110630 (dil 1:10) 

DI\L GW 130L DB 110630 (dy 1:10) 

O\LGW130 L LS110630 (dil 1:10) 

DAL GW130L MS 110630 (dil 1:10) 

DAL GW130LHS 110630 (dil 1:10) 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

10 ng/mL FC std in Milli Q Water 

MilliQ Water TN11-0234 

DALGW131R 0 110622 (dJ 1:100) 

D^L GW131RDB 110622 (dil 1:100) 

D^LGW131RLS 110622 (dil 1:100) 

DALGW131RHS 110622 (dil 1:100) 

D^LGW131S 0 110622 (dil 1:10) 

D^L GW 131S DB 110622 (dil 1:10) 

DAL GW131S LS 110622 (dil 1:10) 

DALGW131S MS 110622 (dil 1:10) 

DAL GW 131S HS 110622 (dil 1:10) 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

2.5 ng/mL FC std in Milli Q Water 

Mill Q W3ter TN11-0234 

Dl\LGW131L0110622(dil1:10) 

D^LGW131 L OB 110622 (dil 1:10) 

DAL GW131LLS 110622 (dil 1:10) 

D^LGW131 L MS 110622 (dil 1:10) 

Dl\LGW131LHS 110622 (dil 1:10) 

DAL GW133L 0 110630 (dil 1:10) 

DAL GW133LDB 110630 (dil 1:10) 

DAL GW 133L LS 110630 (dil 1:10) 

(3AL GW 133L MS 110630 (dil 1:10) 

DAL GW 133L HS 110830 (dil 1:10) 

Milli QWeter TN11-0234 

MilliQ Water TN11-0234 

5.0 ng/mL FC std in Milli Q Water 

MilliQ Water TN11-0234 

DALGW133S0110630(dil1:10) 

CWLGW133S DB 110630 (dil 1:10) 

DAL GW 133S LS 110630 (dil 1:10) 

DAL GW 133S MS 110630 (dil 1:10) 

DAL GW 133S HS 110630 (dil 1; 10) 

DAL GW133R0 110630 (dil 1:10) 

D»,LGW133RDB 110630 (dil 1:10) 

[3AL GW 133R LS 110630 (dil 1:10) 

DAL GW 133R MS 110630 (dil 1:10) 

DAL GW 133R HS 110630 (dil 1:10) 

MlliQ Water TN11-0234 

Mill QWeter TN11-0234 

1.0 ng/mL FC std in Milli Q Water 

MilliQ Water TN11-0234 

QALGW134R 0 110628 (dil 1:100) 

DAL GW 134R DB 110628 (dil 1:100) 

DAL GW 134R LS 110628 (dil 1:100) 

QAL GW 134R HS 110628 (dJ 1:100) 

DAL GW134L 0 110628 (dil 1:10) 

DAL GW134LD e 110628 (dil 1:10) 

DAL GW134LLS 110628 (dil 1:10) 

DAL GW 134L MS 110628 (dil 1:10) 

DAL GW 134L HS 110628 (dil 1:10) 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

2.5 ng/mL FC std in Milli Q Water 

Milli QWster TN11-0234 

DAL GW134S 0 110628 

DALGW134SDB 110628 

DALGW134SLS 110628 

DALGW134S MS 110628 

only.dam 

Printing Time: 10:15:01 AM 

Printing Date: Monday, July 18, 

Page 2 of 4 
*Kir)t BB21501010 

Project: P:\PrDjectSLabJnarument Data\Kir1«Mikdata\Praiect!*fluorochemicals_waterBatcti:k110716a Tab:Sample Set:SET1 AcqMethod:PFOA 

Sample 

143 

144 

i45 "^ 

i46 

f47 

148 " 

149 

150 

151 

152 

153 

154 

155 

156 

157 

158 

i!?ZI 

160 

161 

162 

163" 

164 

165" 

166 

T67 

168" "" 

169 

170 

171 

172 

173 

174 

175 

176 

177 

178 

179 

180 

181 

182 

183 

_„.... . 

T85 ""• 

186 

187 

188 

189 

190 

191 

192 

193 

Ll^ZI 195 

196 

197 

198 

199 

200 

M l 

202"" 

203 

204 

|205^_ 

206 

207 

208 

209 

[210 

211 

212 

213 

Sample Name 

kl 107153143 

kl 107153144 

kl 107163145 

kl107153146 

kl107153147 

k1107153148 

kl107153149 

kl107153160 

k110715a151 

k110715a152 

k110715a163 

k110715a154 

rkTl0715ai65~ 

k1107153l56 

k1107153l57 

k110715a158 

k110715a159 

k110715a160 

ToioTTsaieT" 

k110715a162 

k1107153l63 

k110715a164 

k110715a165 

k110715a166 

k1107153l67 

k1107153l6B 

k110715a169 

k1107153l70 

k110715a171 

k110715a172 

M<Tl67i53i73~ 

k110715a174 

k110715a175 

k110715a176 

k1107153l77 

k1107163178 

k1107153179 

kl 107153180 

kl107153181 

kl 107153182 

kl107153183 

ki 107153184 

kl 107153185 

k1107163l86 

k1107153187 

kl107153188 

kl107153189 

k110715a190 

k1107153191 

k1107153192 

li(iT07T53i93~ 

kl107153194 

liciToTissisTs 

kl 107153196 

kl107153197 

kl107153198 

liciToTTSiigg" 

kii67i5a266 

kl107163201 

kl 107163202 

Iiii67i53263 

kl107153204 

MclJOTIS^OS 

k1107153206 

^k1107153207 

kl107153208 

T<iT67i53209 

k110715a210 

kl 107153211 

k1107153212 

^j^___ _ 

Ssmple ID 

GLPI 0-01-01-18-063 

GLPlO-01-01-18 664"" 

GLPI 0-01-01-18-065 

GLPI 0-01-01-18-066 

GLPI 0-01-01-18-067 

GLP10-01-01-18-068 

Solvent Blsnk 

So^/ent Blsnk 

11003-26-11 

Solvent Blank 

GLPI 0-01-01-18-069 

GLPI 0-01-01-18-070 

GLPI 0-01-01-18-071 

GLPI 0-01-01-18-072 

GLPI 0-01-01-18-073 

GLPI 0-01-01-18-074 

GLPI 0-01-01-18-075 

GLPI 0-01-01-18-076 

GLPI 0-01-01-18-077 

GLPI 0-01-01-18-078 

Solvent Blank 

Solvent Blank 

11003-26-10 

Solvent Blank 

GLPI 0-01-01-18-079 

[GI£10-01l-01-18-080 

GLPI 0-01-01-18-081 

GLPI 0-01-01-18-083 

GLPI 0-01-01-18-084 

GLPI 0-01-01-18-086 

GLPI 0-01-01-18-086 

GLPI 0-01-01-18-155 

GLPI 0-01-01-18-087 

Solvent Blank 

Solvent Blsnk 

11003-26-8 

Solvent Blank 

GLPI 0-01-01-18-088 

GLPI 0-01-01-18-089 

GLPI 0-01-01-18-090 

GLPI 0-01-01-18-091 

GLPI 0-01-01-18-092 

GLPI 0-01-01-18-093 

GLPI 0-01-01-18-094 

GLPI 0-01-01-18-095 

GLPI 0-01-01-18-096 

GLPI 0-01-01-18-097 

Solvent Blank 

Soh/ent Blsnk 

11003-26-9 

Solvent Blank 

GLPI 0-01-01-18-098 

GLPI 0-01-01-18-099 

GLPI 0-01-01-18-100 

lGiJio;6T:6w8;Toi 

GLPI 0-01-01-18-102 

GLPI 0-01-01-18-103 

GLPI 0-01-01-18-104 

GLPI 0-01-01-18-106 

GLPi6-6l-01-ie-i66 

GLPI 0-01-01-18-107 

Solvent Blank 

Solvent Blank 

11003-26-11 

Solvent Blank 

GLPI 0-01-01-18-108 

GLRO-01-01-18-109 

GLPI 0-01-01-18-110 

GLPI 0-01-01-18-111 

GLPI 0-01-01-18-112 

GLPI 0-01-01-18-113 

Vial Position 

21 

Data File 

'kl 167153' 

22 kl10715a 

23 kl107153 

24 kl107153 

25 kl10715a 

26 kl10715a 

91 !k110716a 

93 ikli67153 

f l l 

' M 

27 

28 

29 

30 

t3i 

32 

33 

34 

35 

36 

93 

94 

10 

94 

37 

38 

kl10715a 

kl10715a 

kl10716a 

k110716s 

kl10715a 

k110715s 

k110715a 

k1107153 

triOTila 

k110715a 

k110715a 

k110716s 

k1107153 

k110715s 

k110715a 

k110715a 

kl10715s 

k1107153 

39 k1107153 

40 

^41 

42 

43 

44 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

45 ik110715a 

94 |k110715a 

95 |k110715a 

8 |k110715a 

95 ;k110715a 

46 Ik110715a 

47 kl107153 

48 kl107153 

49 kl107153 

50 kl107153 

51 k1107153 

^•52 ' " "kl 10715a' 

53 

54 

55 

95 

96 

9 

96 

56 

57 

68 

59 

60 

61 

62 

63 

64 

kli67i5s 

k110715a 

k110715a 

kl10716a 

k110715a 

k1107153 

k110715a 

kl107153 

kl10715s 

k1107163 

kl107153 

k110715s 

kl107153 

kl107153 

k1107i53 

k1107163 

65 i|<il07i5a 

96 

97 

11 

97 

66 

67 

68 

69 

70 

k110715a 

k1107i5s 

k1107163 

k110715a 

k110715s 

kl10715a 

k110715s 

k110715a 

k110715a 

71 ;k1107153 

Inj.Volume ||il) 

5 000 

25 006 

25 000 

25 000 

5 000 

25 000 

"26.000 

26.000 

25.000 

25.000 

5.000 

5.000 

6.000 

5.000 

6 m i 

l _ _ , 

25,000 

25.000 

25.000 

25 000 

25 000 

25 000 

25 000 

25 000 

25 000 

25,000 

25,000 

25.000 

5,000 

5.000 

5.000 

5.000 

5.000 

25.000 

25.000 

25.000 

'25000 ' 

f^g _ 

25.000 

26.000 

26 000 

25 000 

25 000 

25 006 

25.000 

25.000 

26,000 

"26,000 

25.000 

25.000 

25.000 

25.000 

26.000 

26,000 

'25666 

25.000 

26,000 

25,000 

25,000 

26,000 

125,666 

25.000 

25.666 

25.000 

25.000 

£??5_ 

teioo" 

25.000 

26.000 

25.000 

5.000 

Comments 

DALGW134SHS 110628 

Trip Blsnk Set 1 Ssmple 

Trip Blank Set 1 LS 

Trip Blank Set 1 MS 

Tnp Blank Set 1 MHS 

Trip Blank Set 1 HS (dil 1 100) 

MilliQ Water TN11-0234 

Milli Q Water TN11 -0234 _]] j 

10 ng/mL FC std in Milli Q Water 

MilliQ Water TN11-0234 

DAL GW135S0 110628 

DALGW135SDB 110628 

DAL GW135S LS110628 

(aALGW135S MS 110628 

DALGW135SHS 110628 

DAL GW 135L 0 110628 (dil 1:10) 

DAL GW 135L 1» 110628 (dil 1:10) 

QAL GW 136L LS 110628 (dil 1:10) 

DAL GW 135L MS 110628 (dil 1:10) 

(3AL GW 136L HS 110628 (dil 1 10) 

Mill Q Water TN11-0234 

Mill Q Wafer TN11-0234 

5 0 ng/mL FC std in Milli Q Water 

MilliQ Water TN11-0234 

DALGW135R0110628(dll1 100) 

DAL GW 135R DB 110628 (dil 1:100) 

DAL GW 135R LS 110628 (dil 1:100) 

DAL GW 135R HS 110628 (dil 1:100) 

DAL GW 136L 0 110630 (dil 1:10) 

DAL GW 136L DB 110630 (dil 1:10) 

DAL GW136LLS 110630 (dil 1:10) 

DAL GW 136L MS 110630 (dil 1:10) 

DAL GW 136L HS 110630 (dil 1:10) 

Milli QWster TN11-0234 

Milli QWsterTNl 1-0234 

1.0 ng/mL FC std in Mini Q Wster 

Milli QWster TN11-0234 

DAL GW136S 0110630 (dil 1:10) 

DAL GW 136S DB 110630 (dil 1:10) 

DALGW136S LS 110630 (dil 1:10) 

DAL GW136S MS 110630 (dil 1 10) 

DAL GW 136S HS 110630 (dil 1 10) 

DAL GW137S0 110624 

DALGW137SDB110624 

DALG'wi"37SLS 110624 

DALGW137SMS110624 

DAL GW137SHS 110624 

Milli QWster TN11-0234 

MQ"VtoterTNT^0234 1 

2.5 ng/mL FC std in Milli Q Wster 

Milli QWster TN11-0234 

DAL GW137L 0110624 

DAL GW137L(3B 110624 

pAiGv\M3na£i ^ j 

DALrGW137LWTi0624 | 

DALGW137LHS110624 

DAL GW138R0.110630 (dil 1:10) 

DAL GW 138R DB 110630 (dil 1:10) 

(3ALGW138RLS 116636 (dil 1:10) 

DAL GW138R MS 110630 (dil 1:10) 

DAL GW i38R i«li6636 ((1iii:l6j 

Milli QWster TN11-0234 

MlliQ Water fNii-6234 

10 ng/mL FCstd in MlliQ Water 

IM^Vteltel^NI^^O^^ 

DSTGWISSTOTTOSO j 

DALGW138LD6110630 

DAL GW138L LS110630 1 

DALGW138LMS110630 

DAL GW138LHS 110630 

OM- GW 138S 0 110630 (dil 1:10) 

only.dam 

Printing Time: 10:15:01 AM 

Printing Date: Monday, July 18 

Page 3 of 4 
»Kir)t BB21501010 

Project: P:\Project^ab_lnstmmentData\Kir1(\Mrkdata\ProjectSVfluorochemlcals_waterBatcti:k110715a Tab:Sample Set:SET1 AcqMettiod:PFOA 

Sample 

214 

215 

"216 "^ 

217 

2i8 

"219 

220 

"22"i' "" 

222 

223 

224 

225 

226 

227 

228 

229 

230 

231 

232 

233 

234 

235 

236 "" 

237 

238"" 

"239" • 

240 

241 

242 

243 

244 

245 

246 

247 

248 , 

249 

260 

251 

252' ! 

253 

i254""' • 

255 

256^ 

257 

258 

259 

260 

261 

262 

263 

264 

265 

266 

267 

268 

269 

270 

2'71 " " 

[272 

273 

274 

Sample Name 

kl107153214 

kl107153215 

k1107153216 

kl107153217 

kl107153218 

kl107163219 

kl107153220 

"kli07i632"21 

k1107153222 

k1107163223 

k1107153224 

kl107153225 

kl107153226 

k110715s227 

k1107153228 

k110715a229 

k1107163230 

kl107153231 

k1107153232 

k110715a233 

k110715a234 

k110715a235 

k110715s236 

k110fl5""s237 

k110715a238 

kl107153239 

kl107153240 

k1107153241 

kl107153242 

kl107163243 

kl107153244 

k110715s245 

kl107153246 

kl107153247 

kl107153248 

kl107153249 

kl107153250 

kl107153251 

kl107153252 

kl107153253 

ki 167163254 

kl107153255 

kl107153256 

kl107163257 

k1107153258 

k110715s259 

k1107163260 

1(1107163261 

kl107153262 

k110715s263 

k1107153264 

kl107153265 

kl107153266 

k1107153267 

k1107153268 

kl107153269 

k1107153270 

k110715s271 

k110715s2"72 

kl107163273 

kl107153274 

Sample ID | Vial Position 

GLPI 0-01-01-16-114 

GLPI 0-01-01-18-115 

GLPI 0-01-01-18-116 

GLPI 0-01-01-18-117 

Solvent Blsnk 

Solvent Blsnk 

11003-26-10 

Solvent Blsnk 

GLPI 0-01-01-18-118 

GLPI 0-01-01-18-119 

GLPI 0-01-01-18-120 

GLH 0-01-01-18-121 

GLPI 0-01-01-18-122 

GLPI 0-01-01-18-123 

GLPI 0-01-01-18-124 

GLPI 0-01-01-18-125 

GLPI 0-01-01-18-126 

GLP10 01 01 18 127 

Solvent Blsnk 

Solvent Blsnk 

11003 26 8 

Solvent Blsnk 

GLP10 01 oi 18 133 

GLF10-01-01-18-134 

GLP10-01-01-18-128 

GLPI 0-01-01-18-129 

GLPI 0-01-01-18-130 

GLPI 0-01-01-18-131 

GLPI 0-01-01-18-132 

Solvent Blsnk 

Solvent Blsnk 

11003-26-9 

Solvent Blsnk 

GLPI 0-01-01-18-135 

GLPI 0-01-01-18-136 

GLPI 0-01-01-18-137 

GLPI 0-01-01-18-138 

GLPI 0-01-01-18-139 

GLPI 0-01-01-18-140 

GLH 0-01-01-18-141 

GLPI 0-01-01-18-142 

GLPI 0-01-01-18-143 

GLH 0-01-01-18-144 

Solvent Blsnk 

Solvent Blank 

11003-26-11 

Solvent Blank 

GLPI 0-01-01-18-145 

GLPI 0-01-01-18-146 

GLPI 0-01-01-18-147 

GLPI 0-01-01-18-148 

GLPI 0-01-01-18-149 

GLPI 0-01-01-18-150 

GLPI 0-01-01-18-151 

GLPI 0-01-01-18-162 

GLPI 0-01-01-18-153 

GLPI 0-01-01-18-154 

Solvent Blank 

Solvent Blsnk 

11003-26-10 

Solvent Blank 

72 

73 

74 

75 

97 

98 

10 

98 

76 

77 

78 

79 

80 

81 

82 

83 

84 

OstsHle i Inj.Volume (|il) Comments 

kl 10715a 

kl 107163 

"kli07r53 

kl 107163 

Ikl 167153 

k1107163 

kl107153 

kiiotis s 

kl 10715a 

kl107153 

kl10715a 

kl10715a 

kl 107153 

£n0i715s__ 

£1!?Z1£!L__ 

kl107163 

k1107163 

85 kl10715a 

98 [k1107153 

99 

8 

99 

86 

67 

88 

89 

90 

16 

17 

99 

100 

9 

100 

18 

19 

20 

21 

22 

23 

24 

25 

26 

27 

100 

91 

11 

91 

28 

29 

30 

31 

32 

33 

34 

35 

36 

37 

9i 

91 

io 

93 

5,000 

5.000 

6.000 1 

6.000 

26,000 

25000 

25,000 

26,000 

5,000 

5;o56 ' 

5.000 

5.000 

5.000 

5.000 

5.000 

6.000 

5.000 

5 000 

26 665 

k110715a 25000 

kl 10715a j 26 000 

k110715a 

k110715s 

k110715s 

kli67i53 

fei67i"53 

kl107153 

k110715s 

k110715s 

k1107163 

kl107153 

k110715s 

k110715s 

kl10715s 

k110715s 

kl10715s 

k1107153 

kl107153 

k1107153 

k110715s 

k1107153 

kiioHss 

icii67i5s 

k1107153 

kl10715s 

kl107163 

k110715s 

k110715s 

k1107163 

k1107153 

k110715s 

k1107153 

kl10715s 

kl107153 

kl107153 

k110715s 

k110715s 

IciiO^iSa 

kil0715s 

"k1l67i53 J 

k110715a 

25 000 

25 000 

25.000 

6.000 

5.666 

5.000 

5.000 

5.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

5.000 

5.000 

5.000 

5.000 

5.000 

5.6oo""" " 

5.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

26,000 

25.000 

25.000 

5.000 

5.000 

5.000 

5.000 

5.000 

25.000 

25.000 

25.600 

25.000 

DAL GW138SDB 110630 (dil 1:10) 

DAL GW 138S LS 110630 (dJ 1:10) 

DALGW138S MS 110630 (dil 1:10) 

DALGW138S HS 110630 (dil 1:10) 

Mil Q Water TN11-0234 

MlliQ Water TN11-0234 

5.0 ng/mL FC std in Mill Q Water 

MlliQ Water TN11-0234 

DAL GWCW26C 0 110622 (dil 1:10) 

DAL GWCW26CDB 110622 (dil 1:10) 

DALGWCW26CLS 110622 (dil 1:10) 

DAL GWCW26C MS 110622 (dil 1:10) 

DAL GWCW26CHS 110622 (dil 1:10) 

DAL GWCW26L0 110622 (dil 1:10) 

DAL GWCW26L DB 110622 (dil 1:10) 

DAL GWCW26L LS 110622 (dil 1:10) 

DAL GWCW26L MS 110622 (dil 1:10) 

DAL GWCW26LHS 110622 (dill 10) 

Mill Q Water TN11 0234 

Mill Q Water TN11 0234 

1 0 ng/mL FC std in Mill Q Water 

MDlQ Water TN11 0234 

(iALGW130LRBTT0630 

DALGW133SRB110630 

DAL GW140R0 110622 (dil 1:10) 

"DAL GW i46R"DB ii6622 (dil i:l6) 

DAL GW140RLS 110622 (dil 1:10) 

DAL GW140R MS 110622 (dil 1:10) 

DAL GW140RHS 110622 (dil 1:10) 

Mil Q Water TN11-0234 

MHiQ Water TN11-0234 

2.5 ng/nl. FC std in Mlli Q Wster 

Mill QWster TN11-0234 

DAL GW141R0 110630 

DALGW141RDB110630 

DAL GW141RLS 110630 

DAL GW141RMS 110630 

QALGW141RHS 110630 (dil 1:10) 

DAL GW142R0 110622 (dil 1:10) 

DAL GW142RDB 110622 (dil 1:10) 

DALGW142RLS 110622 (dil 1:10) 

DAL GW 142R MS 110622 (dil 1:10) 

DALGW142RHS 110622 (dil 1:10) 

Mlli QWster TN11-0234 

Mlli QWster TN11-0234 

10 ng/mL FC std in Mlli Q Wster 

Mlli QWster TN11-0234 

DALGW143R0 110622 (dil 1:10) 

DAL GW143RDB 110622 (dil 1:10) 

DALGW143RLS 110622 (dil 1:10) 

DAL GW 143R MS 110622 (dil 1:10) 

DAL GW143RHS 110622 (dil 1:10) 

DAL GW 144S 0 110628 (dil 1:10) 

DAL GW 144S DB 110622 (dil 1:10) 

DAL GW 144S LS 110622 (dil 1:10) 

DAL GW144S MS 110622 (dil 1:10) 

DALGW144S HS 110622 (dil 1:10) 

Mlli Q Wster TOI i-0"234 

Mlli QWster TN11-0234 

5.0 ng/mL FC std in Mill Q Wster 

Mlli QWster TN11-0234 

Run sVDpp^ci oA Savnplc \<.i\oil6a241. -5 

K\\oni5o{2MM, tV^6-sample HAme ^M0.^ chc^ng^ 

only.dam 

>i-arfinQ at sajmple. 

d and fh t ruo l^as 

Printing Tiine: 10:15:01 AM 

Printing Date: Monday, July 18, 2011 

Page 4 of 4 
*Kirlc BB21S01010 

Prajed: P:\Proiects\LabJnslrument Data\Klrt4Mri<data\Projectafluorachemicals_waterBalch:k110715a Tab:Sample Set:SET1 AcqMethod:PFC 

Sample 

1 

2 

3 

4 

5" " "" 

6 

7 

"8" 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 " 

i25 

26 

27 

be 

29 

30 

31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43" 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 1 

55 

56 

57 

58 "" "' 

59 

60 

61 

62 

"63" 

64 

65 

66 

67 

68 

69 

70 

71 

Sample Name 

k110715a001 

k110715a002 

k110715s003 

k110715s004 

k110715a005 

kii67i5a66"6 

k110715a007 

kil67i5a668 

k110715a009 

k1107153010 

k1107153011 

k110715s012 

k1107153013 

k1107153014 

k110715s015 

k110715s016 

kl107153017 

k1107153018 

kl107153019 

k1107153020 

k1107153021 

k1107163022 

k l 107153023 

k1107153024 

ki107153025 

k110715s026 

kl107163027 

kl107153028 

k l 107153029 

k l 107153030 

k l 107153031 

k l 107153032 

k110715s033 

kl107153034 

k110715a035 

k110715a036 

k1107153037 

k1107153038 

k110715s039 

kl107153040 

kii67i5s64i 

k110715a042 

k110715a043 

k110715s044 

k110715a045 

k110715a046 

k1107153047 

k110715a048 

k1107153049 

k110715a050 

k110715a061 

k110715s052 

k110715s053 

k110715a054 

k110715s055 

k1107153056 

k110715a067 

k110715a058 

kl107153059 

k1107153060 

k1107153061 

k110715a062 

)c110715a663 

k110715B064 

k110715s065 

k110715a066 

kl107153067 

kl107153068 

kl107153069 

k110715a070 

kl107163071 

Ssmple ID 

Solvent Blank 

Solvent Blank 

11003-26-8 

Solvent Blsnk 

11003-26-9 

11003-26-9 

11003-26-9 

11003-26-9 

Solvent Blsnk 

Solvent Blsnk 

11003-26-1 

11003-26-2 

11003-26-3 

11003-26-4 

11003-26-5 

11003-26-6 

11003-26-7 

11003-26-8 

11003-26-9 

11003-26-10 

11003-26-11 

11003-26-12 

11003-26-13 

11003-26-14 

11003-26-15 

Solvent Blank 

Soh/ent Blsnk 

Solvent Blsnk 

Solvent Blsnk 

LCS-110714-1 

LCS-110714-2 

LCS-110714-3 

LCS-110714-4 

LCS-110714-5 

LCS-110714-6 

LCS-110714-7 

LCS-110714-8 

LCS-110714-9 

Solvent Blsnk 

Solvent Blsnk 

11003-26-10 

Solvent Blsnk 

LCS-110714-10 

LCS-110714-11 

LCS-110714-12 

LCS-110714-13 

LCS-110714-14 

LCS-110714-15 

LCS-110714-16 

LCS-110714-17 

LCS-110714-18 

Solvent Blank 

Solvent Blsnk 

11003-26-9 

Solvent Blsnk 

Solvent Blsnk 

GLPI 0-01-01-18-001 

GLPI 0-01-01-18-002 

GL"P10-"0l"-6i-i8-"663 

GLPi6-6i-6i-i8-664 

GLPI 0-01-01-18-005 

GLPI 0-01-01-18-006 

GLPI 0-01-01-18-007 

GLP1O-01-01-18-008 

GLPI 0-01-01-18-009 

GLPI 0-01-01-16-010 

Solvent Blsnk 

Solvent Blsnk 

11003-26-10 

Solvent Blsnk 

GLP10-01-01-18-011 

Vial Position 

91 

91 

8 

91 

9" 

9 

9 

9 

91 

92 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

i3 

14 

'15 

92 

92 

93 

93 

16 

17 

18 

19 

20 

21 

22 

23 

24 

93 

94 

i6 

94 

25 

26 

27 

28 

29 

30 

31 

32 

33 

94 

94 

9 

95 

95 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

95 

96 

10 

96 

44 

Data File 

kl107153 

kl107153 

k1107153 

kl10715s 

kl10715s 

kl107153 

k1107163 

kl10715a 

kl10715a 

kl107153 

kl107153 

kl10715s 

kl107153 

kl107153 

kl107153 

kl10715s 

kl107153 

kl107153 

kl10715s 

kl10715s 

kii67i53 

kl107153 

kl10715s 

kl10715s 

k1107153 

k1107153 

k1107153 

k110715s 

k1107153 

k1107153 

k110715s 

k110715s 

kl107153 

kl107153 

kl107153 

kl107153 

kl107153 

k110715a 

kl107153 

kl10715a 

kl107153 

k1107153 

kl107153 

k1107153 

k110715s 

kl107153 

kl10715s 

kl10715s 

kl10715s 

k1107153 

kl107153 

kl10715s 

kl10715s 

kl 107153 

kl10715a 

kl107153 

k1107153 

k110715s 

k1107153 

kl10715s 

kl10715s 

kl107153 

kl10715s 

kl10715s 

k110715s 

kl107153 

^____ 

kl10715a 

k110715a 

kl10715a 

kl10715a 

Inj.Volume (|jl) 

25.000 

26.000 

i25.606 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25,000 

25,000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.6o6 

26.000 

5.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

Comments 

MlliQ Water TN11-0234 

MlliQ Water TN11-0234 

1.0 ng/mL FC std in Mlli Q Water 

Mli Q Water TN11-0234 

2.5 ng/mL FC std in Mlli Q Wster 

2.5 ng/mL FC std in Mill Q Wster 

2.5 ng/mL FC std in Mlli Q Wster 

2.5 ng/mil FC std In Mill Q Wster 

Mli Q Wster TN11-0234 

Mlli QWster TN11-0234 

0.025 ng/mL FC std in Milli Q Wster 

0.03 ng/mL FC std in Milli Q Wster 

0,04 ng/mL FC std in Mlli Q Water 

0,05 ng/mL FC std in Mlli Q Water 

0,1 ng/mL FC std in Mlli Q Water 

0,26 ng/mL FC std in Mill Q Water 

0 6 ng/mL FC std in Mlli Q Water 

1,0 ng/mL FC std in Mlli Q Water 

2,5 ng/mL FC std in Mlli Q Water 

5,0 ng/mL FC std in Milli Q Wster 

i o ng/mL FC std in Mlii Q Water 

25 ng/mL FC std in Mi l Q Wster 

50 ng/mL FC std in Mffl Q Wster 

75 ng/n t FC std in MHi Q Wster 

100 ng/mL FCstd in MB Q Wster 

M l QWster TNI i-0234" 

Mlli QWster TN11-0234 

Mlli QWster TN11-0234 

Mli Q Wster TN11-0234 

0,6ppb LCS 

0.5ppb LCS 

0.5ppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

Mill QWster TN11-0234 

Mlli QWster TN11-0234 

5.6 ng/r«L FCstci in Mlii Q Wster 

Mi l QWsterTNl 1-0234 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

0.5ppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

Mlli QWster TN11-0234 

Mlli QWster TN11-0234 

2.5 ng/mL FC std in Mlli Q Wster 

Mi l QWster TN11-0234 

Mli Q Water TN11-0234 

Trip Blank Set 2 Ssmple 

Trip Blsnk Set 2 LS 

Trip Blank Set 2 MS 

Trip Blsnk Set 2 MHS 

Trip Blsnk Set 2 HS (dil 1:100) 

DAL GW 130R 0 110630 (dil 1:100) 

DAL GW 130R DB 110630 (dil 1:100) 

t:iALGW130RLS 110630 (dil 1:100) 

DALGW130RMS 110630(dil 1:100) 

DAL GW 130R HS 110630 (dil 1:100) 

MlliQ Water TN11-0234 

Mi l QWster TN11-0234 

5.0 ng/mL FC std in Mlli Q Wster 

Mi l QWster TN11-0234 

DAL GW 130S 0 110630 (dil 1:10) 

, 

)A only.dam 

Printing Time: 9:30:42 AM 

Printing Date: Tuesday, July 19, 2011 

Page 1 of 4 

c^e lll^/l l 
•Kiric BB21501010 

Projed: P:\ProjectilLabJnslmment Data\Kir14Wrtidata\Projectafluorocliemlcals_walerBatch:k110715a Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Sample 

72 

73 

74 

"75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

85 

86 

87 

88 

89 

90 

91 

92 ~ 

93 

94 

95 

96 

97 

98 

99 

100 

101 

102 

103 

104 

105 

106 

107 

108 

109 

110 ^ 

111 

112 

113 

114 

115 

116 

117 

118 

119 

120 

121 

122 

123 1 

124 

125 

126 

Tjr ^ 

128" 

129 " 

130 

131 

'132 '" 

133 

134" 

135 

136 

137 

138 

139 

140 

141 

142 

Sample Name 

kl 107153072 

k11071Sa073 

kl107153074 

k11071Sa075 

k1107153076 

k1107153077 

kl107153078 

Ikil67i5s679 

kl 107163080 

k1107163081 

kl 107153082 

k1107153083 

kl 107153084 

k1107153085 

kl 107153086 

kl 107153087 

kl107153088 

kl107153089 

k110715s090 

kl107153091 

k1107153092 

kl107163093 

k1107153094 

i(ii67i 53095 

k1107153096 

k11071Ss097 

k11071Sa098 

k11071Sa099 

k11071S3l00 

k11071Ss101 

k1107163l02 

k1107163l03 

kl 107153104 

kl 107153105 

kl107153106 

kl107153107 

kl107153108 

kl107153109 

k1107153l10 

k110715s111 

k110715s112 

k110715s113 

k110715s114 

k110715s11S 

k110715s116 

k110715s117 

k1107153l18 

k110715s119 

k110715s120 

k11071Ss121 

k11071Ss122 

k11071Ss123 

k11071Ss124 

k1107153l25 

k1107153l26 

k110715s127 

k110715s128 

kl 107153129 

k110715s130 

kl 107163131 

kli67i53i32 

k1107153l33 

k1107153l34 

k11071Ss13S 

k110715s136 

k11071Sa137 

k11071Ss138 

k11071Ss139 

kl107153140 

k1107163l41 

kl107163142 

Ssmple ID 

GLPI 0-01-01-18-012 

GLPI 0-01-01-18-013 

GLPI 0-01-01-18-014 

GLPI 0-01-01-18-015 

GLPI 0-01-01-18-016 

GLPI 0-01-01-16-017 

GLPI 0-01-01-18-018 

GLPI 0-01-01-18-019 

GLPI 0-01-01-18-020 

Solvent Blsnk 

Solvent Blsnk 

11003-26-11 

Solvent Blsnk 

GLPI 0-01-01-18-021 

GLPI 0-01-01-18-022 

GLPI 0-01-01-18-023 

GLPI 0-01-01-18-024 

GLPI 0-01-01-18-025 

GLPI 0-01-01-18-026 

GLPI 0-01-01-18-027 

GLPI 0-01-01-18-028 

GLPI 0-01-01-18-029 

Solvent Blsnk 

Solvent Blsnk 

11003-26-9 

Solvent Blsnk 

GLPI 0-01-01-18-030 

GLPI 0-01-01-18-031 

GLPI 0-01-01-18-032 

GLPI 0-01-01-18-033 

GLPI 0-01-01-18-034 

GLPI 0-01-01-18-035 

GLPI 0-01-01-18-036 

GLPI 0-01-01-18-037 

GLPI 0-01-01-18-038 

GLPI 0-01-01-18-039 

Solvent Blsnk 

Solvent Blsnk 

11003-26-10 

Solvent Blsnk 

GLPI 0-01-01-18-040 

GLPI 0-01-01-18-041 

GLPI 0-01-01-18-042 

GLPI 0-01-01-18-043 

GLPI 0-01-01-18-044 

GLPI 0-01-01-18-045 

GLPI 0-01-01-18-046 

GLPI 0-01-01-18-047 

GLPI 0-01-01-18-048 

GLPI 0-01-01-18-049 

Solvent Blsnk 

Solvent Blsnk 

11003-26-8 

Solvent Blsnk 

GLPI 0-01-01-18-050 

GLPI 0-01-01-18-051 

GLPI 0-01-01-18-052 

GLPI 0-01-01-18-053 

GLPI 0-01-01-18-054 

GLPI 0-01-01-18-056 

GLPi"6-6i-61-18-656 

GLH 0-01-01-18-057 

GLPI 0-01-01-18-058 

Solvent Blsnk 

Solvent Blsnk 

11003-26-9 

Solvent Blsnk 

GLPI 0-01-01-18-059 

GLPI 0-01-01-18-060 

GLPI 0-01-01-18-061 

GLPI 0-01-01-18-062 

VIsI Position 

45 

46 

47 

48 

49 

SO 

51 

62 

53 

96 

97 

11 

97 

54 

55 

56 

57 

58 

59 

60 

61 

62 

97 

98 

9 

98 

63 

64 

66 

66 

67 

68 

69 

70 

71 

72 

98 

99 

10 

99 1 

73 

74 

75 

76 

77 

78 

79 

80 

81 

82 

99 

100 

8 

100 

83 

84 

85 

86 

87 

88 

89 

90 

i6 

100 

91 

9 

91 

17 

18 

19 

20 

Data File 

k l 10715a 

kl107153 

kl107153 

kl107153 

k l 107153 

kl107153 

kl107153 

kl10715s 

kl107153 

kl107153 

kl107153 

k l 10715s 

kl1071 S3 

k110715s 

kl107153 

kl107153 

kl107153 

k110715s 

k110715a 

k1107153 

k11071Sa 

k11071Sa 

kl1071 S3 

kl107158 

k11071Sa 

kl10715s 

kl107163 

kl107153 

k l 10715s 

k l 107153 

k11071Ss 

k11071Ss 

kl 107163 

kl107153 

M107163 

kl107153 

kl107153 

k110715s 

kl 107153 

k1107153 

iciiofiss 

kl 10715s 

kl 107153 

kl 107163 

kl107153 

k110715s 

k1107153 

k110715s 

k1107153 

k110715s 

k1107163 

k1107153 

kl10715s 

kl10715s 

kl107153 

k1107153 

k110715s 

kil0"7"i"5"3" 

k1107163 

kllOtiSs 

k"ii67i53 

kl 10715s 

i<ii 67153 

k1107153 

kl107153 

k110715s 

kl107153 

k1107153 

k110715a 

k11071Sa 

k11071Sa 

lnj.Volume (|il) 

25,000 

25.000 

26.000 

25.666 

25.000 

25.60"0 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

5.000 

6.000 

5.000 

5.000 

5.000 

25.000 

25.000 

25.666 

26.666 

26.000 

25.000 

25.000 

26,000 

25,000 

5,000 

5,000 

5,000 

5.000 

5.000 

25,000 

25,000 

25,000 

25,000 

5,000 

5,000 

5,000 

5,000 

5,000 

25,000 

25,000 

25,000 

25.000 

25.000 

25.000 

25,000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

6.000 

5.000 

5.000 

5.000 

5.000 

26.000 

26.000 

26.000 

25.000 

6.000 

6.000 

5.000 

5.000 

Comment s 

DAL GW 130S 0 110630 (dil 1:10) 

DAL GW 130S LS 110630 (dil 1:100) 

DALGW136S MS 110636(ciil i:i66 j 

DALGW130SHS 110630 (dil 1:100) 

DALGW130L0110630(dil1:10) 

DAL GW 130L DB 110630 (dil 1:10) 

DAL GW 130L LS 110630 (dil 1:10) 

DAL GW i36 L iVIS i 10636 (ciii i:i 6) 

DAL GW 1 SOL HS 110630 (dil 1:10) 

MlliQ Water TN11-0234 

MlliQ Water TN11-0234 

10 ng/mL FC std in Mi l Q Water 

Mli Q Water TN11-0234 

DAL GW131R0 110622 (dil 1:100) 

DALGW131RDB 110622 (dil 1:100) 

DAL GW 131R LS 110622 (dil 1:100) 

DALGW131RHS110622(di l 1:100) 

DAL GW131S 0 110622 (dil 1:10) 

DAL GW 131S DB 110622 (dil 1:10) 

DALGW131S LS 110622 (dil 1:10) 

DAL GW 131S MS 110622 (dil 1:10) 

DAL GW131S HS 110622 (dil 1:10) 

Mli Q Water TN11-0234 

MlliQ Water TN11-0234 

2.5 ng/mL FC std in Mlli Q Wster 

Mi l QWster TN11-0234 

[3ALGW 131L0 110622 (dil 1:10) 

DAL GW131LDB 110622 (dil 1:10) 

DALGW131L LS 110622 (dil 1:10) 

DAL GW131L MS 110622 (dil 1:10) 

DALGW 131L HS 110622 (dil 1:10) 

DAL GW 133L 0 110630 (dil 1:10) 

DAL GW 133L DB 110630 (dl 1:10) 

DALGW 133L LS 110630 (dl 1:10) 

DAL GW 133L MS 110630 (dil 1:10) 

DAL GW 133LHS 110630 (dl 1:10) 

Mlli QWster TN11-0234 

Mlli QWster TN11-0234 

5,0 ng/mL FC std in Milli Q Wster 

Mlli QWster TN11-0234 

DAL GW 133S 0 110630 (dil 1:10) 

DAL GW 133S DB 110630 (dl 1:10) 

DAL GW133S LS110630 (dl 1:10) 

DALGW133S MS 110630 (dl 1:10) 

DAL GW 133S HS 110630 (dl 1:10) 

DAL GW 133R 0 110630 (dil 1:10) 

DAL GW133RDB 110630 (dl 1:10) 

DAL GW 133R LS 110630 (dl 1:10) 

DAL GW133R MS 110630 (dil 1:10) 

DAL GW 133R HS 110630 (dil 1:10) 

Mill QWster TN11-0234 

Mlli QWster TN11-0234 

1,0 ng/mL FC std in Mlli Q Water 

Mlli QWster TN11-0234 

DAL GW 134R 0 110628 (dl 1:100) 

DALGW134RDB 110628 (dl 1:100) 

DAL GW 134R LS 110628 (dil 1:100) 

DAL GW134RHS 110628 (dl 1:100) 

DAL GW 134L 0 110628 (dl 1:10) 

DAL GW 134L DB 110628 (dl 1:10) 

DAL GW 134L LS 110628 (dil 1:10) 

DAL GW134L MS 110628 (dl 1:10) 

DAL GW 134L HS 110628 (dl 1:10) 

Mli Q Wster TN11-0234 

Mi l QWster TN11-0234 

2.5 ng/mL FC std in M«i Q Wster 

Mli Q Wster TN11-0234 

DALGW134S011062 8 

DALGW134SDB110628 

DALGW134SLS 110628 

DALGW134S MS 110628 

Printing Time: 9:30:42 AM 

Printing Date; Tuesday, July 19, 

Page 2 of 4 
*Kirl< BB21501010 

Project: P:\ProjectsM-abJnamment Data\KirWl5i1cdat3\Pro|ectafluorochemicals_waterBatcti:k110715a Tab:Sample Set:SET1 AcqMethod:PFOAonly.dam 

Sample 

143 

144 

145 

146 

147 

148"" 

149 

150 

151 

152 

153 

154 

155 

156 

157 

158 

159 

160 

161 

162 

163 """ 

164 

165 

166" " 

167" 

168"" 

169 

170 

171 

172 

173 

174 

175 

176 

177 

178 

179 

180 

181 

18"2 

183 

184 

185 ~ 

186'"' 

187 

188 

189 

190 

191 

192 

193 

194 

195 

196 

197 

198 

199 

206 

20i 

202 "" 

203 

204 

205 " 

206 

207 

208 

209 

210 

211 

212 

213 

Ssmple Nsme 

k1107153143 

k1107153l44 

kii67i53i46 

kl107153146 

k1107153147 

i<li6"7i"5si48 

k11071S3l49 

k11071Ss150 

k1107153l51 

k110715s1S2 

k1107153l53 

J<11CI7153l54 

k110715s1SS 

k1107153l66 

k11071S3lS7 

k1107153l68 

k1107153l69 

k1107153l60 

kl107153161 

kl107153162 

i(ii67i53i63 

k1107153l64 

k110715s16S 

k110715s166 

k110715s167 

k1107153l68 

k1107153l69 

k11071S3l70 

kl107153171 

k11071Ss172 

k11071Ss173 

k1107163l74 

kl107153175 

kl 107163176 

kl 107153177 

k1107153l78 

kl107153179 

k1107153l80 

k1107153l81 

k1107153l82 

k1107153l83 

kl107153184 

kl107153185 

k110715s186 

kl107153187 

kl107163188 

k1107163l89 

k110715s190 

k1107153l91 

k110715a192 

k11071S3l93 

kl107153194 

kl 107153195 

kl107153196 

k11071Ss197 

kl107153198 

k110715s199 

k1107153200 

k11071Ss201 

k1107153202 

k110715s203 

k110715s204 

fei67i53265 

k1107153206 

k11071Sa207 

kl107153208 

kl107153209 

k11071Sa210 

k110715a211 

k11071Sa212 

k110715a213 

Ssmple ID 

GLPI 0-01-01-18-063 

GLPI 0-01-01-18-064 

GLR 0-01-01-18-065 

GLPI 0-01-01-18-066 

GLPI 0-01-01-18-067 

GLPi6-6i-6i-ie-668 

Solvent Blsnk 

Solvent Blsnk 

11003-26-11 

Solvent Blsnk 

GLPI 0-01-01-18-069 

GLPI 0-01-01-18-070 

GLPI 0-01-01-18-071 

GLPI 0-01-01-18-072 

GLPI 0-01-01-18-073 

GLPI 0-01-01-18-074 

GLPI 0-01-01-18-075 

GLPI 0-01-01-18-076 

GLPI 0-01-01-18-077 

GLPI 0-01-01-18-078 

Solvent Blsnk 

Solvent Blsnk 

11003-26-10 

Solvent Blsnk 

GLPI 0-01-01-18-079 

GLPI 0-01-01-18-080 

GLPI 0-01-01-18-081 

GLPI 0-01-01-18-083 

GLPI 0-01-01-18-084 

GLR 0-01-01-18-085 

GLPI 0-01-01-18-086 

GLPI 0-01-01-18-155 

GLPI 0-01-01-18-087 

Solvent Blsnk 

Solvent Blsnk 

11003-26-8 

Solvent Blsnk 

GLPI 0-01-01-18-088 

GLPI 0-01-01-18-089 

GLPI 0-01-01-18-090 

GLPI 0-01-01-18-091 

GLPI 0-01-01-18-092 

GLPI 0-01-01-18-093 

GLPI 0-01-01-18-094 

GLPI 0-01-01-18-095 

GLPI 0-01-01-18-096 

GLH 0-01-01-18-097 

Solvent Blsnk 

Solvent Blsnk 

11003-26-9 

Solvent Blsnk 

GLPI 0-01-01-18-098 

GLPI 0-01-01-18-099 

GLPI 0-01-01-18-100 

GLPI 0-01-01-18-101 

GLPI 0-01-01-18-102 

GLPI 0-01-01-18-103 

GLPI 0-01-01-18-104 

GLPI 0-01-01-18-105 

GLPI 0-01-01-18-106 

GLPI 0-01-01-18-107 

Solvent Blsnk 

So"h/ont Blsnii 

11003-26-11 

Solvent Blsnk 

GLPI 0-01-01-18-108 

GLPI 0-01-01-18-109 

GLPI 0-01-01-18-110 

GLPI 0-01-01-18-111 

GLPI 0-01-01-18-112 

GLPI 0-01-01-18-113 

Vial Position 

21 

22 

23 

24 

25 

26 

91 

93 

11 

93 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

93 

94 

'io " 

94 

37 

38 

39 

40 

41 

42 

43 

44 

45 

94 

95 

8 

95 

46 

47 

48 

49 

50 

51 

52 

63 

64 

65 

95 

96 

9 

96 

56 

57 

68 

59 

60 

61 

62 

63 

64 

65 

96 

97 

11 

97 

66 

67 

68 

69 

70 

71 

Data RIe 

kl107153 

kl10715a 

kl10715a 

kl10716a 

kiiotisa 

k l 107153 

k l 10715a 

k l 10715s 

k1107153 

kl10715s 

k110715s 

k1107153 

k1107153 

k l 10715a 

k110715a 

k110715a 

k110715a 

k110715a 

kl10716a 

kl10716a 

kl10715a 

k110715a 

k1107153 

k1107153 

kl10715s 

kl107153 

k l 107163 

kl10716a 

k110716a 

k1107163 

kl107163 

kl10715a 

kl 107163 

kl107153 

k1107153 

kl107153 

k1107153 

k1107153 

k110715s 

k110715s 

k1107163 

kl10715s 

k110715s 

kl10715s 

k110715s 

k1107163 

k1107163 

k1107153 

k1107163 

kl107153 

k1107163 

k110715a 

k110715a 

k1107163 

licTWiSi 

kl10715a 

k1107153 

k1107153 

k1107153 

k1107153 

k1107153 

k1107163 

k110715s 

k l 107153 

kl107153 

kl107153 

kl107153 

k1107153 

k1107163 

kl107153 

kl10715s 

Inj.Volume (|il) 

5.000 

25.000 

i25.o66 

26.666 

5.000 

25.000 

25.000 

25.000 

25.000 

25.000 

5.000 

6.000 

6.000 

5.000 

5.000 

25.000 

25.000 

25.000 

26.000 

25,000 

25,000 

25,000 

25.000 

25.666 

25.000 

26.000 

26.000 

26.000 

6.000 

5,000 

5,000 

5,000 

5,000 

25,000 

25,000 

25,000 

26,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25","66o 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,660 

25.666 

2""5T000 

25.066 

25.000 

25666 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

6.000 

Comments 

DALGW134SHS 110628 

Trip Bl3nk Set 1 Ssmple 

Trip Blsnk Set 1 LS 

trip iisnic Set i M"S 

Trip Blsnk Set 1 MHS 

Trip Blank Set 1 HS(dl 1:100) 

Mil QWsterTNl 1-0234 

Mil QWsterTNl 1-0234 

10 ng/mL FC std in Mil Q Wster 

Mil QWster TN11-0234 

DAL GW136S 0 110628 

DALGW135SDB110628 

DALGW135SLS 110628 

DAL GW135S MS 110628 

DALGW135SHS 110628 

DAL GW 136L 0 110628 (dl 1:10) 

DAL GW 136L DB 110628 (dil 1; 10) 

DAL GW 136L LS 110628 (dil 1:10) 

DAL GW135L MS 110628 (dl 1:10) 

DAL GW135LHS 110628 (dl 1:10) 

Miiii Q Wster iwii-6234 

Milli QWsterTNl 1-0234 

5.0 ng/mL FC std in Mil Q Water 

MilliQ Water TN11-0234 

DAL GW135R0 110628 (dil 1:100) 

DAL GW 135R DB 110628 (dil 1:100) 

DAL GW 135R LS 110628 (dl 1:100) 

DAL GW135RHS 110628 (dl 1:100) 

DALGW136L0110630(dl1:10) 

DALGW 136L DB 110630 (dl 1:10) 

DALGW 136L LS 110630 (dl 1:10) 

DAL GW136L MS 110630 (dl 1:10) 

DAL GW136LHS 110630 (dl 1:10) 

MlliQ Water TN11-0234 

MlliQ Water TN11-0234 

1.0 ng/mL FC std in Mli Q Water 

Mlli QWster TN11-0234 

DALGW136S0 110630 (dl 1:10) 

DAL GW 136S DB 110630 (dl 1:10) 

DAL GW 136S LS 110630 (dl 1:10) 

DAL GW 136S MS 110630 (dl 1:10) 

DAL GW 136S HS 110630 (dl 1:10) 

DAL GW137S 0 110624 

DALGW137SDB110624 

DAL GW137SLS 110624 

DAL GW137S MS 110624 

DAL GW137SHS 110624 

Mill QWster TN11-0234 

Mlli QWster TN11-0234 

2.5 ng/mL FC std in Milli Q Wster 

Mlli QWster TN11-0234 

aALGW137L 0 110624 

DAL GW137LDB 110624 

DAL GW137L LS110624 

DAL GW137L MS 110624 

DAL GW137LHS 110624 

DAL GW138R0110630(dl 1:10) 

DAL GW138RD8 110630 (dl 1:10) 

IDAL "<3W 1 38'R LS 110630 (dl "i:i 6)" 

DAL GW138R MS 110630 (dil 1:10) 

DAL GW138RHS 110630 (dl 1:10) 

Mlli QWster TN11-0234 

Mlii Q Wster fN"ii-6i2"3"4 

10 ng/mL FC std in Mli Q Wster 

Mli QWster TN11-0234 

DAL GW138L 0110630 

DAL GW138LDB 110630 

DAL GW138L LS110630 

DALGW138LMS110630 

DAL GW138LHS 110630 

DALGW138S0 110630(dl1:10) 

, 

Printing Time: 9:30:42 AM 

Printing Date: Tuesday, July 19, 

Page 3 of 4 
•Kirlc BB21501010 

Project: P:\ProjectSU.ab_lndmment Data\KiriAWri(data\ProjectsMluorochemicsls_waterBatcti:k110715E 

Sample 

i Ssmple Nsme 

214 

215 

216""^ 

217 

218 " 

219 

220 

'221 

222 

223 

224 

225 

226 

227 

228 

229 

230 

231 

232 

233 

"234""" 

235 

236"""" 

237 " 

238 

239" " 

240 

241 

242 

243 

244 

245 

246 

247 

248 

249 

250 

251 

252 

253 

264 

256 

"256" 

257 

268 

269 

260 

261 

262 

263 

264 

1266 

266 

76"7 

268 

269 

:270 

izfi " 

272 

273 " 

"274 

k1107153214 

k1107153215 

k110715s216 

k1107153217 

kl107153218 

kl107153219 

kl107153220 

kl107153221 

kl107163222 

kl107153223 

kl107153224 

k1107153225 

k1107153226 

k1107153227 

k1107153228 

k110715s229 

kl107153230 

k110715s231 

k110715s232 

k1107153233 

k110715a234 

k110715a235 

kl107153236 

kl107153237 

k110715a238 

k110715a239 

k110715a240 

kl107153241 

kl107153242 

k1107163243 

k110715b244 

k110715b245 

k110716b246 

k110715b247 

k110716b248 

k110715b249 

k110716b260 

k110716b251 

k110715b252 

k110716b253 

klio"716"b254 

k110716b255 

k110715b256 

k110715b257 

k110715b258 

k110715b259 

k110715b260 

k110715b261 

k110715b262 

k110716b263 

k110715b264 

k110715b265 

k110715b266 

k110715b267 

k110715b268 

k110715b269 

k110716b270 

i(ii67i5b27i 

k110715b272 

k110715b273 

k110715b274 

Ssmple ID 

GLPI 0-01-01-18-114 

GLPI 0-01-01-18-115 

GLPI 0-01-01-18-116 

GLPI 0-01-01-18-117 

Solvent Blsnk 

Solvent Blsnk 

11003-26-10 

Solvent Blsnk 

GLPI 0-01-01-18-118 

GLPI 0-01-01-18-119 

GLR 0-01-01-18-120 

GLR 0-01-01-18-121 

GLR 0-01-01-18-122 

GLRO-01-01-18-123 

GLRO-01-01-18-124 

GLR 0-01-01-18-125 

GLR 0-01-01-18-126 

GLR 0-01-01-18-127 

Solvent Blsnk 

Solvent Blsnk 

11003-26-8 

Solvent Blsnk 

GLR 0-01-01-18-133 

GLR 0-01-01-18-134 

GLR 0-01-01-18-128 

GLR 0-01-01-18-129 

GLR 0-01-01-18-130 

GLR 0-01-01-18-131 

GLR 0-01-01-18-132 

Solvent Blsnk 

Solvent Blsnk 

11003-26-9 

Solvent BIsnic 

GLR 0-01-01-18-135 

GLR 0-01-01-18-136 

GLR 0-01-01-18-137 

GLR 0-01-01-18-138 

GLR 0-01-01-18-139 

GLR 0-01-01-18-140 

GLR 0-01-01-18-141 

G"L"Pi6-6l-0i"-ie"-i42 

GLR 0-01-01-18-143 

GLR 0-01-01-18-144 

Solvent Blsnk 

Solvent Blsnk 

11003-26-11 

Solvent Blsnk 

GLR 0-01-01-18-145 

GLR 0-01-01-18-146 

GLR 0-01-01-18-147 

GLR 0-01-01-18-148 

GLR 0-01-01-18-149 

GLR 0-01-01-18-150 

GLRO-01-01-18-151 

GLR 0-01-01-18-152 

GLR 0-01-01-18-163 

GLR 0-01-01-18-164 

Solvent Blsnk 

Soivent isnlc 

11003-26-10 

Solvent Blsnk 

VIsI Position 

72 

73 

74 

"75 

97 

98 

10 

98 

76 

77 

78 

,79 

^80 ' 

81 

82 

83 

84 

86 

98 

99 

8 

99 

86 

87 

las 

89 

90 

16 

17 

99 

100 

9 

100 

18 

19 

20 

21 

22 

23 

24 

i2"5 

26 

27 

100 

91 

11 

91 

28 

29 

30 

31 

32 

33 

34 

35 

36 

37 

91 

91 

10 

9i3 

Data File 

k1107153 

kl10715s 

k110715s 

kli67i"5s 

k110715s 

j(ii07i5s 

kl107153 

ki167153 

M l 07153 

M l 0715s 

M107163 

iciTOTISi ' 

M107153 

Ml 07163 

M107153 

M107153 

M107153 

M107153 

kl107153 

k1107163 

i(1l6715s 

k110715s 

k1107153 

"Mi"6"7153 

"kii"07163 "^ 

Ml 0715s 

M107153 

M10715s 

kl107163 

kl107163 

M l 07153 

M107153 

M l 07153 

k1107153 

kl107153 

k1107153 

M107153 

M107153 

M107153 

M10715a 

M107153 

kl10715a 

kli67"l5a 

k110715s 

M l 0715a 

k110715a 

M l 07163 

M l 07163 

M l 07153 

k110715s 

k1107163 

M107163 

M107153 

M107153 

M107153 

M107153 

M107153 

kl10715a 

M l 0715a 

M10715a 

kl10715a 

Inj.Volume (id) 

5.000 

5.000 

5.000 

5.666 

25.666 

25.000 

25.060 

25,000 

5,000 

5,000 

5,000 

5,000 

5,000 

5,000 

5,000 

5,000 

5,000 

5.000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

5.000 

5.000 

5.000 

5.000 

5,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

25,000 

5,000 

5,000 

5.000 

5,000 

5,000 

5,000 

"5,0"6~6 

25.000 

25.000 

25.000 

25,000 

25,000 

25,000 

25,000 

25,000 

26,000 

5,000 

5,000 

5,000 

5,000 

5,000 

25.666 

25.666 

25.666 

26.000 

Tab:Sample Set:SET1 AcqMethod:PFOA 

Comments 

DALGW138S DB 110630 (dl 1:10) 

DAL GW138S LS110630 (dil 1:10) 

DALGW138S MS 110630 (dl 1:10) 

DAL GW 138S HS 110630 (dl 1:10) 

Mli QWster TN11-0234 

Mli QWster TN11-0234 

5,0 ng/mL FC std in Milli Q Wster 

Mill QWster TN11-0234 

DAL GWCW26C0 110622 (dl 1:10) 

DAL GWCW26CDB 110622 (dl 1:10) 

DAL GWCW26CLS 110622 (dl 1:10) 

DALGWCW26CMS 110622 (dl 1:10) 

DAL GWCW26CHS 110622 (dl 1:10) 

DAL GW CW26L 0 110622 (dl 1:10) 

DAL GWCW26L DB 110622 (dl 1:10) 

DAL GWCW26L LS 110622 (dl 1:10) 

DAL GWCW26L MS 110622 (dl 1:10) 

DAL GWCW26L HS 110622 (dl 1:10) 

Mlli QWster TN11-0234 

Mlli QWster TN11-0234 

1.0 ng/mL FC std in Mil Q Wster 

Mlli QWster TN11-0234 

DAL GW130L RB110630 

DALGW133SRB 110630 

DAL GW140R0 110622 (dl 1:10) 

DAL GW 140R DB 110622 (dl 1:10) 

DAL GW140RLS 110622 (dl 1:10) 

DAL GW 140R MS 110622 (dl 1:10) 

DAL GW 140R HS 110622 (dl 1:10) 

Mlli QWster TN11-0234 

Mlli QWster TN11-0234 

2,5 ng/mL FC std in Mli Q Wster 

Mlli QWster TN11-0234 

DAL GW141R0 110630 

DAL GW141RDB 110630 

DAL GW141RLS 110630 

DALGW141RMS110630 

DAL GW141RHS 110630 (dl 1:10) 

DAL GW 142R 0 110622 (dl 1:10) 

DAL GW142RDB 110622 (dl 1:10) 

DALGW 142R LS 110622 (dl 1:10) 

DAL GW142R MS 110622 (dl 1:10) 

DAL GW 142R HS 110622 (dl 1:10) 

MliQ Water TN11-0234 

MlliQ Water TN11-0234 

10 ng/mL FC std in Mli Q Water 

Mlli QWster TN11-0234 

DAL GW143R0 110622 (dl 1:10) 

DAL GW 143R DB 110622 (dl 1:10) 

DAL GW 143R LS 110622 (dl 1:10) 

DAL GW 143R MS 110622 (dl 1:10) 

DAL GW143R HS 110622 (dl 1:10) 

DAL GW 144S 0 110628 (dl 1:10) 

DAL GW 144S DB 110622 (dl 1:10) 

DAL GW144S LS 110622 (dl 1:10) 

DAL GW 144S MS 110622 (dl 1:10) 

DALGW 144S HS 110622 (dl 1:10) 

Mil QWster TN11-0234 

Mli QWster TN11-0234 

5,0 ng/mL FC std in Mil Q Wster 

Mil QWster TN11-0234 

only.dam 

Printing Time: 

Printing Date: 

9:30:42 AM 

Tuesday, July 19, 2011 

Page 4 of 4 
*Kir)c BB21501010 

Acciuisition Infomiation: 

0:eal:ed: 

last Maiified: 

ttitment; 

Synchrenlzaticn M^de: 

Aito-EljiilihratJjCii: 

fiojiisitiim Duration: 

Njifcer Of Scans: 

Bariods Ei Pile : 

Pa^iisitiai M^ile: 

SoftMaze vecBicz: 

Beticdl : 

Scans i n Berlcd: 

Relative Start TijTe: 

Experinaits i n Iteciod: 

Bericd 1 Experiiieit 1: 

Scan lipe ; 

S<±priii1ed HM: 

Rjlarity : 

ScanKxfc: 

Tm Source: 

Reaolutioi Ql: 

HesolutionQ3: 

mteisit y Thres.: 

Settlin g Tme : 

m reuse: 

tCR: 

St^Sije : 

01 ^BS3 (CB) 03 Kiss (la) Duell(TlBSC) 

413.000 369.000 20.00 

Ql ms a (EB) 03 NBBS la ) DuelKmgec) 

413.000 219.000 20.00 

(S. NBss (m) 03 NBBs (la) DuellCtBec:) 

413.000 169.000 20.00 

ESrantter" Table (Period 1 Enperincnt 1) 

OJR 

a c 

•UM 

OSl 

GE2 

35.00 

6.00 

450.00 

55.00 

50.00 

I S; -4500.00 

/gilai t LC Pixip Mst±oi Prcpertie s 

Puip rtdel ; Agilent 1200 Binary Puip 

Mininun Pressure (pei): 0.0 

^6xiJnln Pressure (psi); 5801.0 

npwl \bLute (pi): 40.0 

texiinin Flow i&np (mL/min'): 100.0 

ttodnufl Pressure Ranp (pei/sec): 

^toc FOcw Ranp H) (ml/min'): 100.0 

^fax Flew fenp lii (ml/min'): 100.0 

Step TbCal TiitB(min) Flow tete(pl/min) 

C 0.00 300 

1 2.00 300 

2 14.50 300 

3 15.50 300 

4 15.60 300 

E 20.00 300 

Right Oirpnessibility : 115.0 

l£f t Dead \toluTe (pi): 40.0 

Rigiit Dead VbluiE (pi): 40.0 

l£fC Strcke VUXJX (pi) : 

Riglt SCrcke Wli m (pi): 

lif t SDlvent: Al 

Right Sjlvcnt: Bl 

/gilai t Att-npanpler Prt?«rt:ies 

ara n 

EX 

s 

CE 

act 

Rirair 

09 

E£ 

CE 

OT 

Kia n 

IP 

E£ 

a 

OCE 

290.0 

A (% 

97.0 

97.0 

5.0 

5.0 

97.0 

97.0 

-1.0 

-1.0 

E¥CR cnly.dam 

•Diirsday February n 2011 12; 53; 04 tM 

Friday Jul y IE 20U 15: 26: 13 EH 

EKA 

ICSync 

Off 

20minOsec 

1S992 

1 

jcquisitirx i Metiiod 

ftialysc 1.5.2 

15992 

0.00 HBOC 

1 

M:M (WW) 

N3 

^egative 

N/A 

"Rjiijo ^xs y 

tULt 

Uli t 

0.00 cps 

0.0000 msec 

5.0070 msec 

K> 

0.00 EB 

Start Stqf K 

-41.00 -41.00 PFCft-1 

-8.50 -8.50 

-IS.OO -15.00 

-6.00 -6.00 

Start Stqc IT 

-41.00 -41.00 PEm-2 

-8.50 -8.50 

-22.00 -22.00 

-9.00 -9.00 

Start Step K 

-100.00-100.00 PKft-3 

-10.00 -10.00 

-37.00 -37.00 

-9.00 -9.00 

B (%) 

3.0 

3.0 

95.0 

95.0 

3.0 

3.0 

Aitoeanpler rtdel : Agilait 1200 Standard Aitosanpler 

Syringe Size (pi): 100 

mjocti m \«)lure (pi): 25.00 

Ecaw Etieed (pl/min): 200.0 

Eject %jeed (pl/min): 200.0 

Print;ing Time: 10:16:03 AM 

Printing Date: Monday, July 18, 2011 

Page 1 of 2 cshnh^lw 
*Kir k BB2150101 0 

N-edle Level (imi): 0.00 

Haiperature Ctntcal EirBbled 

Setpoinb (4 - 40 O : IS 

v&sh IB net used 

Itee Ojstcm Dijector Progran It) 

Agilent Cblum Oven Prcperties 

E£ft T&rperatirre ("O : 30.00 

KLc^'teipecatiire (»0 : 20.00 

•ftnperature TdLexarvx +/- {<»0 : 1.00 

Start fiequigitien iblecance -f/- CO : 0.50 

Tine lable KJsed) 

Cblum Switching \&1VE Installed CSV 

ECeiticn for first sanple in the batch; Left 

Use sane pcGiticn far all satrples in the batd: 

Tbtal TiiTe{inln) \&lve Etjsiticn 

0.00 Left 

5.00 Ri ^ 

Printing Time: 10:16:03 AM Page 2 of 2 

Printing Date: Monday, July 18, 2011 
Worlcstation: ETSKIRK Results Name: )cll0715a.rdb 

• kl 10715a.rdb (PFOA): "Quadratic" Regression ("1 / x" weighting): y = -6.93e+003 x'^2 + 1.82e+006 x + 3.65e+004 (r = 0.9998) 

1.15e8-

I.IOeS1.05e8: 

1.00e8-

9.50e7-

9.00e7t 

8.50e7^ 

8.00e7^ 

7.50e7-

7.00e7-

6.50e7-

g 6.00e7-

o 

ra 5.50e7-

**• 5.00e7-

4.50e7: 

4.00e7-

3.50e7-

3.00e7-

2.50e7-

2.00e7-

1.50e7-

1.00e7^ 

5.00e6: 

0.00-

^^'' 

. ^ 

y ' 

/"" • 

y ' 

y ' 

y 

y 

y / 

y 

y 

/ 

y 

y 7* 

/ 

0 5 10 15 20 25 30 35 40 45 50 55 60 65 

Conc»ntration, ng/mL 

„.-•' • 

1 1 1 . 

70 

,.-•''•• ' 

75 

^---" ^ 

80 

^-- ^ 

85 90 

,-^ ^ 

95 

• 

100 

Data worked up by KJU 

Printing Time: 12:12:22 PM 

Printing Date: Wednesday, July 20, 2011 

Page 1 of 1 
Workstation: ETSKIRK Results Name: kll0715a.rdb 

1 

2 

3 

4 

5 

6 

7 

8 

9 " 

10 

Ti " 

12 J 

13 ' 

14 1 

15 

To" J 

17 ' 

18 

20 

21 

22 

23 

24 

25 

26 

27 

28 

2 9 ' 

30 

31 

32 i 

33 

34 

35 

Ue 

37 

38 

39 

40 

41 

42 

43 

44 

145 

48 

47 

48 

49 

50 

51 

52 

53 

54 

55 

56 

57 

158 

59 

60 

61 

62 

Sample Name 

k110715a001 

k110715a002 

k110715a003 

k110715a004 

k110715a005 

k110715a006 

k110715a007 

k110715a008 

k110715a009 

k110715a010 

k110715a011 

k110715a012 

k110715a013 

k110715a014 

k110715a015 

k110715a016 

k110715a017 

k110715a018 

k110715a019 

k110715a020 

k110715a021 

k110715a022 

kl10715a023 

Ml6715a024 

k110715a025 

k11071Sa026 

k1107l5a027 

k110715a028 

k110715a029 

k110715a030 . 

k110715a031 

k110715a032 

kli0715a033 

k110715a034 

k110715a035 

k110715a036 

^kli0715a037 

k110715a038 

k110715a039 

k110715a040 

k1l0715a041 

k110715a042 

k11071Sa043 

^110715a044 

k110715a04S 

k110715a046 

k110715a047 

k110715a048 

k110715a049 

k110715a050 

k110715a051 

k110715a052 

k110715a053 

k110715a054 

k110715a055 

k110715a056 

k110715a0S7 

k110715a058 

k110715a059 

k110715a060 

k110715a061 

k110715a062 

Sample ID 

SoNent Blank 

SoNent Blank 

11003-26* 

SoKent Blank 

11003-26-9 

11003-26-9 

11003-26-9 

110OM6-9 

Solvent Blank 

Solvent Blank 

11003-26-1 

11003-26-2 

11003-26-3 

11003-26-1 

11003-26-5 

11003-26-6 

11003-26-7 

11003-26.8 

11003-26-9 

11003-26-10 

11003-26-11 

11003-26-12 

1100J.26-13 

11003-26-14 

1100J.26-15 

Solvent Blank 

Solvent Blank 

Solvent Blank 

Solvenl Blank ~^ 

LCS-110714-1 

LCS-110714-2 

LCS-110714-3 

LCS-110714-4 

LCS-110714-S 

LCS-llb714-6 

LCS-110714-7 

LCS-110714-8 

LCS-110714-9 

Solvent Blank 

Solvent Blank 

1100J.26-10 

Solvent Blank 

LCS-110714-10 

LCS-110714-11 

LCS-110714-12 

LCS-110714-13 

LCS-110714-14 

LCS-110714-15 

LCS-110714-16 

LCS-110714-17 

LCS-110714-18 

Solvent Blank 

Solvent Blank 

11003-26-9 

Solvent Blank 

Solvent Blank 

GLP10-01-01-ie-001 

GLP1IM)1-01-18-002 

GLP1CM)1-01-1e-003 

GLP10-01-01-1M04 

GLPllW)1-01-18-005 

GLPlO-01-01-18-006 

Sample Comment 

MilliQ Water TM i 1-0234 

MilliQ Water TN11-0234 

1.0 ng/mL FC std in Mini Q Water 

MilliQ Water TN11-0234 

2.5 ng/mL FC std in Milli Q Water 

2.5 ng/mL FC std in Milli Q Water 

2.5 ng/mL FC std in MiDi Q Water 

2.5 ng/mL FC std in MiDi Q Water 

MilliQ Water TN11-0234 

MilliQ Water TN11-0234 

0.025 ng/mL FC std in MiDi Q Water 

0.03 ng/mL FC std in Milli Q Water 

0.04 ng/mL FC std in Milli Q Water 

0.05 ng/mL FC std in Milli Q Water 

0.1 ng/mL FC std in MiDi Q Water 

0.25 ng/mL FC std in Milli Q Water 

0.5 ng/mL FC std in MiDi Q Water 

1.0 ng/mL FC std in MiDi Q Water 

2.5 ng/mL FC std in Mini Q Water 

5.0 ng/mL FC std in MiDi Q Water 

10 ng/mL FC std in Mini Q Water 

25 ng/mL FC std in MiDi Q Water 

SO ng/mL FC std in MiDi Q Water 

75 ng/mL FC std in MiDi Q Water 

too ng/mL FC std in Milli Q Water 

MiDi Q Water TN11-0234 

MiDi Q Water TN11-0234 

MiDi Q Water TN11-0234 

MiDi Q Water TN11-0234 

O.Sppb LCS 

O.Sppb LCS 

O.Sppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

MIDI Q Water TN11-0234 

MiDi Q Water TN11-0234 

S.O ng/mL FC std in MiDi Q Water 

MiDi Q Water TN11-0234 

O.Sppb LCS ECF 

|0.5ppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

MiDi Q Water TNI 1-0234 

MiDi Q Water TN11-0234 

2.5 ng/mL FC std in MiDi Q Water 

MiDi Q Water TNI 1-0234 

MiOiQ Water TN11-0234 

Trip Blank Set 2 Sample 

Trip Blank Set 2 LS 

Trip Blank Set 2 MS 

Trip Blank Set 2 MHS 

Trip Blank Set 2 HS (dil 1:100) 

DAL GW 130R 0 110630 (dD 1:100) 

Sample Type 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Standard 

Standard 

Standanl 

standanl 

Standard 

Standani 

Standard 

Standard 

Standaitl 

Standanj 

Standard 

StandanS 

Standard 

Standard 

Standand 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Quality Ointrol 

Quality Control 

Qualrty Control 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Unknown 

Unknown 

Quality Control 

Unknown 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Quality c^ontrol 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

/Xnalyte Peak 

Name 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

"PFOA 

PFOA 

PFb/\ 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

/Analyte Peak Area 

(counts) 

428SS2 

61016 

2275254 

18073 

5241381 

51B1S99 

5092887 

4943181 

6656 

5330 

79684 

84914 

107795 

118906 

222109 

516292 

981863 

2026711 

4777305 

9217151 

177S7632 

41779501 

72084171 

96394636 

114703888 

30048 

845S 

7526 

5416 

963879 

9S6199 

1031950 

9252077 

9439709 

9440299 

46053927 

44939921 

4618642S 

6779 

3416 

8932786 

5900 

986975 

892323 

928923 

8898047 

8956716 

9291104 

50287005 

48914304 

49150855 

5294 

5588 

451S007 

3733 

6154 

2801 

1769988 

16364277 

30S1306S 

7982102 

14802990 

>\nalyte Retention 

Time (min) 

15.4 

1S.4 

15.4 

15.4 

15.4 

1S.4 

15.4 

1S.4 

1S.7 

1S.7 

15.S 

1S.S 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15.4 

15.4 

15.5 

15.4 

15.4 

15.5 

15.5 

15.5 

15.5 

15.5 

1S.5 

15.4 

15.4 

15.4 

1S.S 

15.4 

15.5 

15.4 

1S.5 

1S.S 

1S.9 

15.S 

1S.S 

15.5 

15.4 

15.4 

15.5 

15.4 

15.4 

15.5 

15.4 

15.4 

15.8 

15.8 

15.4 

15.5 

15.8 

15.9 

15.4 

15.4 

1S.4 

15.4 

15.5 

Analyte concentration 

(ng/mL) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

25.0 

SO.O 

75.0 

100. 

N/A 

N/A 

N/A 

N/A 

0.498 

0.498 

0.498 

4.98 

4.98 

4.98 

29.9 

"29.9 

29.9 

N/A 

N/A 

5.00 

Use 

Record 

^ 

^ 

^ 

^ 

^ 

El 

^ 

Rl 

^ 

Rl 

^ 

Rl 

B 

ISI 

B 

Rl 

El 

S 

El 

El 

El 

S 

El 

El 

El 

N/A 

0.498 

0.498 

0.498 

4.99 

4.99 

4.99 

29.9 

29.9 

29.9 

WA 

N/A 

2.50 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

El 

El 

Rl 

El 

El 

El 

El 

El 

El 

El 

Calculated 

Concentration (ng/mL) 

0.215 

0.0134 

1.23 

< 0 

2.89 

2.85 

2.80 

2.72 

< 0 

< 0 

0.0237 

0.0266 

0.0391 

0.0452 

0.102 

0.263 

0.520 

1.10 

2.63 

5.14 

10.1 

25.3 

48.5 

73.3 

104. 

< 0 

< 0 

< 0 

< 0 

0.510 

0.506 

0.547 

5.16 

5.26 

5.26 

28.3 

27.5 

28.4 

< 0 

< 0 

4.97 

< 0 

0.522 

0.470 

0.491 

4.96 

4.99 

5.18 

31.3 

30.3 

30.5 

< 0 

< 0 

2.48 

< 0 

< 0 

< 0 

0.954 

9.29 

89.7 

443. 

837. 

Accuracy 

(%) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

94.7 

88.S 

97.8 

90.4 

102. 

105. 

104. 

110. 

105. 

103. 

101. 

101. 

96.9 

97.7 

104. 

N/A 

N/A 

N/A 

N/A 

102. 

102. 

110. 

104. 

106. 

106. 

94.6 

92.0 

94.9 

N/A 

N/A 

99.5 

N/A 

105. 

94.4 

98.5 

99.3 

100. 

104. 

105. 

101. 

102. 

NfA 

N/A 

99.2 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

Record 

Modified 

_-.El_. 

El 

El 

El 

D 

gl 

El 

El 

D 

n 

D 

El 

El 

D 

D 

El 

El 

El 

El 

El 

El , 

El 

El 

El 

^_EL.. 

D 

_ D 

D 

El 

D 

D 

• D 

El 

H.. 

El 

El 

D 

D 

D 

D 

El 

r ^ 

El 

El 

El 

El 

E! 

El 

El 

D 

D 

r~H 

n D 

D 

El 

El 

El 

El 

El 

Dilution 

Factor 

5 

100 

100 

Acquisition Date 

7/15/2011 3:46:38 PM 

7/15/2011 4:08:31 PM 

7/15/2011 4:29:3SPM 

7/15/2011 4:50:43 PM 

7/15/2011 5:11:49 PM 

7/15/2011 5:32:59 PM 

7/15/2011 5:54:05 PM 

7/15/2011 6:15:12 PM 

7/15/2011 6:36:17 PM 

7/15/2011 6:57:23 PM 

7/1S/2011 7:18:27 PM 

7/15/2011 7:39:34 PM 

7/1S/2011 8:00:43 PM 

7/15/2011 8:21:50 PM 

7/15/2011 8:42:56 PM 

7/15/2011 9:04:00 PM 

7/15/2011 9:25:04 PM 

7/15/2011 9:46:11 PM 

7/15/2011 10:07:17 PM 

7/15/2011 10:28:22 PH 

7/15/2011 10:49:29 PM 

7/15/2011 11:10:36 PM 

7/15/2011 11:31:40 PM 

7/15/2611 11:52:46 PM 

7/16/2011 12:13:54 AM 

7/16/2011 12:34:59 AM 

7/16/2011 12:56:04 AM 

7/16/2011 1:17:08 AM 

7/16/2011 1:38:13AM 

7/16/2011 1:59:18 AM 

7/16/2011 2:20:26 AM 

7/16/2011 2:41:32 AM 

7/16/2011 3:02:38 AM 

7/16/2011 3:23:45 AM 

7/16/2011 3:44:54 AM 

7/16/2011 4:06:03 AM 

7/16/2011 4:27:13 AM 

7/I6/2OII 4:48:19AM 

7/16/2011 5:09:26 AM 

7/16/2011 5:30:32 AM 

7/16/2011 5:51:40 AM 

7/16/2011 6:12:52 AM 

7/16/2011 6:34:01 AM 

7/16/2011 6:55:11 AM 

7/16/2011 7:16:17 AM 

7/16/2011 7:37:26 AM 

7/16/2011 7:S8:32AM 

7/16/2011 8:19:38 AM 

7/16/2011 8:40:46 AM 

7/16/2011 9:01:54 AM 

7/16/2011 9:22:59 AM 

7/16/2011 9:44:06 AM 

7/16/2011 10:05:16 AM 

7/16/2011 10:26:25 AM 

7/16«011 10:47:35 AM 

7/16/2011 11:08:45 AM 

7/16/2011 11:29:50 AM 

7/16/2011 11:51:03 AM 

7/16/2011 12:12:10 PM 

7/16/2011 12:33:18 PM 

7/16/2011 12:54:17 PM 

7/16/2011 1:15:18 PM 

rked up by KJU 

Printing Time: 12:10:49 PH 

Printing Date: Wednesday, July 20, 2011 

i^V^ 1']^\^^\ 
Workstation: ETSKIRK Results Name: kll0715a.rdb 

63 

54" " 

65"" • 

66 

"67"" 

68 

69 

70 

71 

72 

73 

"74 " 

75 

76 

[77 

|78 

79 

|80 

181 

82 

[83 

84 

85 

86 

|87 

88 

89 

90 

91 

[92 

93 

94 

95 

96 

97 

98 

99 

100 • 

101 

102 

103 

104 

105 

106' " 

Td7 " 

108 

109 

110 

111 

112 

113 

114 

Tis " 

116 

117 

118 

119 

120 

121 

122 

123 

124 

Sample Name 

k11071Sa063 

k11071Sa064 

k110715a065 

k110715a066 

k11071Sa067 

k11071Sa068 

k11071Sa069 

k11071Sa070 

k11071Sa071 

k11071Sa072 

k11071Sa073 

k11071Sa074 

k11071Sa075 

k1t071Sa076 

k110715a077 

k1107t5a078 

k110715a079 

k11071Sa080 

k11071Sa081 

k110715a082 

k11071Sa083 

k11071Sa084 

k11071Sa085 

k1107lSa086 

k110715a087 

k11071Sa088 

k1107lSa089 

k110715a090 

k110715a091 

k11071Sa092 

k11071SaO93 

k110715a094 

k11071Sa095 

k110715a096 

k11071Sa097 

^0715a09 8 

TrTTb71Sa099 

k1107lSa100 

k110715a101 

k110715a102 

k110715a103 

k110715a104 

k110715a105 

k110715a106 

k110715a107 

k11O71Sa108 

k11071Sa109 

k11071Sa110 

k11071Sa1l1 

k11071Sa112 

k110715a1l3 

k11071Sa114 

k110715a115 

k11071Sa116 

kl10715a117 

k110715a118 

k110715a119 

k1107lSa120 

k1l0715a121 

k110715a122 

k11071Sa123 

k11071Sa124 

Sample ID 

GLP10-01-01-18-007 

GLPI 0-01-01-18-008 

GLP10-01-01-18-009 

GLPI 0-01-01-18-010 

Solvent Blank 

Solvent Blank 

11003-26-10 

Solvent Blank 

GLP10-01-01-18-011 

GLP10-01-01-18-012 

GLP10mi-01-18-013 

GLPI 04)1-01-18-014 

GLPIO.01-01-1^015 

GLP10-01-01-18-016 

GLP10-01-01-18-017 

GLPI 0-01-01-18-018 

GLP10-01-01-18-019 

GLP10-01-01-164)20 

Solvent Blank 

Solvent Blank 

11003-26-11 

Solvent Blank 

GLP10-01-01-18-021 

GLP10-01-01-18-022 

GLP10-01-01-18-023 

GLPlO-01-01-18-024 

GLPlO-01-01-18-025 

GLP10-01-01-18-026 

GLP10-01-01-18-027 

GLPlO-01-01-18-028 

GLPlO-01-01-18-029 

Solvent Blank 

Solvent Blank 

11003-26-9 

Solvent Blank 

GLP10-01-01-18-030 

GLP10-01-01-18-031 

GLP10-01-01-18-032 

GLPlO-01-01-18-033 

GLP10-01-01-18-034 

GLP10-01-01-18-035 

GLPI 0-01-01-184)36 

GLP10-01-01-18-037 

GLP10-01-01-18-038 

GLP10-01-01-18-039 

Solvent Blank 

Solvent Blank 

11003.26-10 

Solvent Blank 

GLP10-01-01-18-040 

GLP10-01-01-18-041 

GLP10-01-01-184)42 

GLP10-01-01-184)43 

GLP10-01-01-18-044 

GLP10-01-01-18-045 

GLP10-01-O1-18-O46 

GLP10-01-01-18-047 

GLP10-01-01-18-048 

GLP1IM)1-01-18-049 

Solvent Blank 

Solvent Blank 

11003-26-8 

Sample Comment 

DAL GW 130R DB 110630 (dil 1:100) 

DAL GW 130R LS 110630 (dil 1:100) 

DAL GW 130R MS 110630 (dN 1:100) 

DAL GW 130R HS 110630 (dil 1:100) 

Mini Q Water TNI 1-0234 

Mini Q Water TN11-0234 

S.O ngfmL FC std in MIDI Q Water 

Mini Q Water TN11-0234 

DAL GW 130S 0 110630 (dD 1:10) 

DAL GW 130S 0 110630 (dD 1:10) 

DAL GW 130S LS 110630 (dil 1:100) 

DAL GW 130S MS 110630 (dD 1:100) 

DAL GW 130S HS 110630 (dil 1:100) 

DAL GW 130L 0 110630 (dil 1:10) 

DAL GW 130L DB 110630 (dil 1:10) 

DAL GW 130L LS 110630 (dil 1:10) 

DAL GW 130L MS 110630 (dil 1:10) 

DAL GW 130L HS 110630 (dil 1:10) 

Mini Q Water TN11-0234 

Mini Q Water TNI 1-0234 

10 ng/mL FCstd in Mini Q Water 

Mini Q Water TN11-0234 

DAL GW 131R 0 110622 (dil 1:100) 

DAL GW 131R DB 110622 (dil 1:100) 

DAL GW 131R LS 110622 (dil 1:100) 

DAL GW 131R HS 110622 (dil 1:100) 

DAL GW 131S 0 110622 (dD 1:10) 

DAL GW 131S DB 110622 (dil 1:10) 

DAL GW 131S LS 110622 (dil 1:10) 

DALGW131S MS 110622 (dN 1:10) 

DAL GW 131S HS 110622 (dil 1:10) 

Mini Q Water TNI 1-0234 

MilHQ Water TN11-0234 

2.5 ng/mL FC std In Milli Q Water 

MilliQ Water TN11-0234 

DAL GW 131L 0 110622 (dil 1:10) 

DAL GW 131L DB 110622 (dil 1:10) 

DAL GW 131L LS 110622 (dil 1:10) 

DALGW131LMS 110622 (dil 1:10) 

DAL GW 131L HS 110622 (dil 1:10) 

DAL GW 133L 0 110630 (dil 1:10) 

DAL GW 133L DB 110630 (dil 1:10) 

DAL GW 133L LS 110630 (dil 1:10) 

DAL GW 133L MS 110630 (dil 1:10) 

DAL GW 133L HS 110630 (d» 1:10) 

Mini Q Water TN11-0234 

Mini Q Water TN11-0234 

5.0 ng/mL FC std in Mini Q Water 

Mini Q Water TN11-0234 

DAL GW 133S 0 110630 (dil 1:10) 

DAL GW 133S DB 110630 (dil 1:10) 

DAL GW 133S LS 110630 (dD 1:10) 

DAL GW 133S MS 110630 (dil 1:10) 

DAL GW 133S HS 110630 (dil 1:10) 

DAL GW 133R 0 110630 (dil 1:10) 

DAL GW 133R DB 110630 (dil 1:10) 

DAL GW 133R LS 110630 (dD 1:10) 

DAL GW 133R MS 110630 (dil 1:10) 

DAL GW 133R HS 110630 (dil 1:10) 

MiDi Q Water TN11-0234 

MiDi Q Water TN11-0234 

1.0 ng/mL FC std in MiDi Q Water 

Sample Type 

Unknovm 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknovwi 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknovm 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Analyte Peak 

Name 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA . 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

P"FOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Analyte Peak Area 

(counts) 

14565294 

14746656 

16243219 

22303777 

9964 

8526 

8839420 

3608 

30524073 

30349497 

3316855 

4819966 

12596334 

11898880 

11302154 

1223S962 

13283959 

27046340 

3547 

4296 

16989171 

7816 

38390775 

42046962 

41164570 

62574999 

1006429 

972385 

1003100 

1343986 

4205983 

3033 

6444 

4559996 

2847 

16548643 

16924324 

17123392 

18828610 

31418926 

8260473 

81314S3 

9508711 

14767838 

24465047 

6908 

7830 

8946596 

7396 

11104112 

11217885 

11289175 

14063129 

26384544 

18890925 

18909016 

17002577 

19563778 

32146060 

4509 

3247 

1950690 

Analyte Retention 

Time (mtn) 

15:4 

15.5 

15.4 

15.4 

15.9 

15.5 

15.4 

15.9 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

1S.4 

15.4 

15.4 

15.5 

1S.S 

15.4 

15.5 

15.4 

15.4 

1S.5 

15.4 

15.4 

1S.4 

1S.4 

15.4 

15.4 

15.8 

15.5 

15.4 

15.S 

15.4 

15.4 

15.4 

15.5 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15.9 

15.5 

15.9 

15.4 

15.4 

15.4 

1S.4 

15.4 

1S.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15.9 

15.4 

Analyte Concentration 

(ng/mL) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

Use 

Record 

El 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

10.0 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

2.50 

N/A 

N/A 

N/A 

El 

El 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

1.00 

El 

El 

Calculated 

823. 

833. 

921. 

1280. 

< 0 

< 0 

4.92 

< 0 

180. 

178. 

181. 

265. 

708. 

66.8 

63.3 

68.7 

74.8 

158. 

< 0 

< 0 

9.66 

< 0 

2310. 

2550. 

2490. 

4060. 

26.7 

25.7 

26.6 

36.0 

115. 

< 0 

<6 

2.51 

"<o •" 

93.9 

96.2 

97.3 

107. 

185. 

230. 

226. 

265. 

417. 

708. 

< 0 

< 0 

4.98 

< 0 

311. 

314. 

316. 

397. 

768. 

108. 

108. 

96.6 

112. 

190. 

< 0 

< 0 

1.05 

/^curacy 

(%) 

N/A 

SSA 

N/A 

N/A 

N/A 

N/A 

98.4 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

96.6 

N/A 

N/A 

N/A 

N/A 

NW 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

100. 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

99.7 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

105. 

Record 

Modified 

El 

El 

El 

El 

D 

D 

El 

D 

El 

El 

El 

El 

El 

El 

El 

El 

El 

El 

• D 

El 

D 

E! 

El 

^ El 

'El 

El 

El 

El 

El 

El 

n 

r—O 

El 

D 

El 

El 

El 

g 

El 

El 

El 

El 

^ S 

El 

D 

D 

El 

n 

El 

El 

El 

El 

l_EI 

r-^i 

El 

El 

El 

El 

D 

D 

El 

Dilution 

Factor 

100 

100 

100 

100 

1 

1 

1 

1 

10 

10 

100 

100 

100 

10 

10 

10 

10 

10 

1 

1 

1 

1 

100 

iod 

100 

100 

so 

so 

50 

so 

so 

1 

1 

1 

1 

10 

10 

10 

10 

10 

so 

so 

so 

50 

so 

1 

1 

1 

1 

50 

50 

so 

50 

50 

10 

10 

10 

10 

10 

1 

1 

1 

Acquisition Date 

7/16/2011 1:36:27 PM 

7/16/2011 1:57:36 PM 

7/16/2011 2:18:46 PM 

7/16/2011 2:39:57 PM 

7/16/2011 3:01:06 PM 

7/16/2011 3:22:18 PM 

7/16/2011 3:43:24 PM 

7/16/2011 4:04:34 PM 

7/16/2011 4:25:43 PM 

7/16/2011 4:46:54 PM 

7/16/2011 5:08:01 PM 

7/16/2011 5:29:07 PM 

7/16/2011 5:50:18 PM 

7/16/2011 6:11:26 PM 

7/16/2011 6:32:14 PM 

7/16/2011 6:53:42 PM 

7/16/2011 7:14:51 PM 

7/16/2011 7:35:59 PM 

7/16/2011 7:57:07 PM 

7/16/2011 8:18:17 PM 

7/16/2011 8:39:26 PM 

7/16/2011 9:00:35 PM 

7/16/2011 9:21:44 PM 

7/16/2011 9:43:00 PM 

7/16/2011 10:04:09 PM 

7/16/2011 10:25:18 PM 

7/16/2011 10:46:27 PM 

7/16/2011 11:07:29 PM 

7/16/2011 11:28:29 PM 

7/16/2011 11:49:26 PM 

7/17/2011 12:10:25 AM 

7/17/2011 12:31:25 AM 

7/17/2011 12:52:31 AM 

7/17/2011 1:13:39 AM 

7/17/2011 1:34:48 AM 

7/17/2011 1:55:56 AM 

7/17/2011 2:17:14 AM 

7/17/2011 2:38:26 AM 

7/17/2011 2:59:36 AM 

7/17/2011 3:20:46 AM 

7/17/2011 3:42:01 AM 

7/17/2011 4:03:07 AM 

7/17/2011 4:24:04 AM 

7/17/2011 4:45:03 AM 

7/17/2011 5:06:02 AM 

7/17/2011 5:26:57 AM 

7/17/2011 5:48:02 AM 

7/17/2011 6:09:19 AM 

7/17/2011 6:30:33 AM 

7/17/2011 6:51:49 AM 

7/17/2011 7:12:53 AM 

7/17/2011 7:33:59 AM 

7/17/2011 7:54:58 AM 

7/17/2011 8:15:57 AM 

7/17/2011 6:36:55 AM 

7/17/2011 8:58:00 AM 

7/17/2011 9:19:14 AM 

7/17/2011 9:40:26 AM 

7/17/2011 10:01:43 AM 

7/17/2011 10:22:52 AM 

7/17/2011 10:44:10 AM 

7/17/2011 11:05:20 AM 

ocked up by KJU Page 2 of 5 

Printing Time: 12:10:49 PM 

Printing Date: Wednesday, July 20, 2011 
Workstation: ETSKIRK Results Name: kll0715a.rdb 

125 

126 

127 

128 

129 

130 

131 

132 

133 

134 

T35~ 

136 

137 

[138 

139 

140 

141 

142 

143 

144 " 

145 

146 

147 

l148 

149 

150 

isT" 

152 

153 " 

154 

155 

156 

157 

158 

1S9 

160 

161 

K2 

163 

164 

165 

166~"' 

167 

168 

l"69 " 

170 

171 

172 

173 

174 

175 

176 

177 " 

178 

179 

180 

131 

182 

183 

184 

185 

186 

Sample Name 

k110715a125 

k110715a128 

k110715a127 

k110715a128 

k11071Sa129 

k110715a130 

k110715a131 

k11071Sa132 

k110715al33 

k110715al34 

k11071Sa13S 

k110715al36 

k11071Sa137 

k110715a138 

k110715a139 

k110715a140 

k110715a141 

k110715a142 

k110715a143 

k110715a144 

k110715a145 

k110715a148 

k110715a147 

k110715a148 

k11071Sa149 

k110715a1S0 

k110715a151 

k110715a152 

k11071Sa1S3 

k110715a154 

kl10715a155 

k11071Sa1S6 

k11071Sa157 

k110715a158 

k11071Sa159 

k110715a160 

k110715a161 

k110715a162 

k110715a163 

kl10715a164 

k110715a165 

k110715a166 

k110715a167 

k11071Sa168 

k11071Sa169 

k110715a170 

k110715a171 

k110715a172 

kl1071Sa173 

k110715a174 

k11071Sa17S 

k11071Sa176 

k1l071Sal77 

k110715al78 

k11071Sal79 

k11071Sal80 

k110715aiei 

kll0715a182 

k1l0715a183 

k110715a184 

kl10715a185 

k110715a18e 

Sample ID 

Solvent Blank 

GLP10-01-01-18-050 

GLP10-01-01-18-051 

GLP104)1-01-18-052 

GLP10-01-01-18-053 

GLP10-01-01-18-054 

GLP10-01-01.18-05S 

GLP1M1-01-16O56 

'GLPIO-01-01-18-057 

GLP10-01-01-18-058 

SoNent Blank 

Solvent Blank 

11003-26-9 

Solvenl Blank 

GLP10-01-O1-18-059 

GLP10-01-01-16O60 

GLP10-01-01-184)61 

GLP10-01-01-1»4)62 

GLP10-01J)1-184)63 

GLP1fr<ll-01-1»4l64 

GLP10-01-01-18-065 

GLP10-01-01-1W)66 

GLP10-01-01-18-067 

GLP10-01-01-1S4)68 

Solvent Blank 

Solvent'Blank 

11003-26-11 

Solvent Blank 

GLP10-01-01-18-069 

GLP10-01-01-18-070 

GLP104)1-01-1B4)71 

GLP104)1-01-18-072 

GLP1W)1-01-18O73 

GLP10-01-01-18-074 

GLP104)1-01-184)75 

GLP104)1-01-164)76 

GLP10-01-01-18-077 

GLP10-01-01-18-078 

SoNent Blank 

Solvent Blank 

11003-26-10 

Solvent Blank 

GLP104)1-01-1»O79 

GLP10-01-01-1M80 

GLP1D-01-01-184)81 

GLP10-01-01-18-083 

GLPI 04)1-01-16084 

GLP10-01-01-1B4)85 

GLPlSoi-01-184)86 

GLP104)14)1-18-155 

GLP104)14)1-184)87 

Solvenl Blank 

Solvent Blanll 

11003-26^ 

Solvent Blank 

GLP104)14)1-184)88 

GLP104)14)1-18-089 

GLP104)14)1-184)90 

GLP104)1-01-18-091 

GLP104)14)1-184)92 

GLP104)14)1-184)93 

GLP104)14)1-184)94 

Sample Comment 

MilliQ Water TNI 14)234 

DAL GW 134R 0 110628 (dil 1:100) 

DAL GW 134R DB 110628 (dil 1:100) 

DAL GW 134R LS 110628 (dD 1:100) 

DAL GW 134R HS 110628 (dil 1:100) 

DAL GW134L0 110628 (dD 1:10) 

DAL GW 134L DB 110628 (dD 1:10) 

DAL GW 134L LS 110628 (dil 1:10) 

DAL GW 114L MS 110628 (dil 1:10) 

DAL GW 134L HS 110628 (dil 1:10) 

MiDi Q Water TN1141234 

MiDi Q Water TN114)234 

2.5 ng/mL FC std in MiDi Q Water 

MiDi Q Water TN114)234 

DAL GW134S 0110628 

DAL GW134SDB 110628 

DALGW134SLS 110628 

DALGW134SMS110628 

DAL GW134SHS 110628 

Trip Blank Set 1 Sample 

Trip Blank Set 1 LS 

Trip Blank Set 1 MS 

Trip Blank Set 1 MHS 

Trip Blank Set 1 HS (dil 1:100) 

MiDi Q Water TN114)234 

Mini Q Water TN114)234 

10 ng/mL FC std in MiDi Q Water 

Mini Q Water TNI 14)234 

DAL GW135S 0110628 

DALGW135SDB 110628 

DAL GW135SLS 110628 

DALGW135S MS 110628 

DAL GW135SHS 110628 

DAL GW 135L 0 110628 (dil 1:10) 

DAL GW 135L DB 110628 (dD 1:10) 

DAL GW 13SL LS 110628 (dil 1:10) 

DAL GW 135L MS 110628 (dil 1:10) 

DAL GW 13SL HS 110628 (dD 1:10) 

MIDI Q Water TN114)234 

MiDi Q Water TN114)234 

S.O ng/mL FC std in MiDi Q Water 

MiDi Q Water TN114)234 

DAL GW 135R 0 110628 (dil 1:100) 

DAL GW 135R DB 110628 (dil 1:100) 

DAL GW 135R LS 110628 (dil 1:100) 

DAL GW 135R HS 110628 (dil 1:100) 

DAL GW 136L 0 110630 (dil 1:10) 

DAL GW 136L DB 110630 (dil 1:10) 

DAL GW 136L LS 110630 (dil 1:10) 

DALGW136LMS 110630 (dil 1:10) 

DAL GW 136L HS 110630 (dil 1:10) 

Mini Q Water TNI 14)234 

MilliQ Water TNI 14)214 

1.0 ng/mL FC std In Miin Q Water 

MiDi Q Water TN1141234 

DAL GW 136S 0 110630 (dil 1:10) 

DAL GW 136S DB 110630 (dil 1:10) 

DAL GW 136S LS 110630 (dD 1:10) 

DAL GW 136S MS 110630 (dil 1:10) 

DAL GW 136S HS 110630 (dil 1:10) 

DAL GW137S 0 110624 

DAL GW137SDB 110624 

Sample Type 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknovm 

Unknovm 

Unknovm 

Unknown 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

u"nknown 

Quality control 

Unknovm 

Unknown 

Unknovm 

Unknown 

Unknown 

Unknovm 

Unknown 

Unknown 

Unknovm 

Unknown 

Unknown 

Unknovm 

Unknovm 

Quality Control 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknown 

Unknown 

Unknovm 

Unknovm 

Unknown 

Unknovm 

Unknovm 

Unknovm 

Quality control 

Unknown 

Unknown 

Unknovm 

Unknown 

Unknovm 

Unknovm 

Unknown 

Unknovm 

Analyte Peak 

Name 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

I^FOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Analyte Peak Area 

(counts) 

3896 

30420430 

30552302 

31722139 

56764811 

18471422 

20629650 

20968155 

23431483 

34169371 

11090 

25177 

4618301 

14220 

3535193 

3624220 

3510557 

3904635 

7077087 

9562 

1818046 

17620512 

32332229 

8849618 

4243 

4567 

1754S963 

6473 

6830157 

7322715 

8709S3S 

7427254 

14135478 

46122156 

44519562 

45307922 

46939862 

57279088 

8337 

2637 

8986786 

12628 

56222974 

54804934 

56700713 

76644663 

2925019 

2874905 

2921336 

3263811 

6143782 

10303 

2943 

1945252 

6033 

22653847 

22668981 

22817944 

23475309 . 

36337810 

553876 

525864 

Analyte Retention 

Time (min) 

15.7 

1S.5 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15.5 

15.4 

15.5 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15:5 

15.5 

15.6 

15.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15.5 

15.5 

15.5 

15.5 

15.5 

15.6 

15.5 

15.6 

15.5 

15.4 

15.4 

15.4 

l"5.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.5 

15.4 

15.5 

15.4 

15.4 

15.4 

15.5 

15.4 

15.5 

15.5 

/Xnalyte concentration 

(ng/mL) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

2.50 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A " 

10.0 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

f^A 

N/A 

5.00 

1:** 

N/A 

N/A 

N/A 

tl" ^ .,.,^ 

N/A 

N/A 

N/A 

N/A 

N/A 

Kl/A 

N/A 

1.00 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

Use 

Record 

El 

El 

El 

El 

Calculated 

concentration (ng/mL) 

< 0 

1790. 

1800. 

1870. 

3610. 

527. 

592. 

602. 

677. 

1010. 

< 0 

< 0 

2.54 

< 0 

9.67 

9.92 

9.60 

10.7 

19.6 

< 0 

0.981 

10.0 

95.5 

493. 

<0 

<o" 

9.99 

< 0 

18.9 

20.3 

24.2 

20.6 

39.9 

283. 

272. 

278. 

289. 

365. 

< 0 

< 0 

5.01 

< 0 

3570. 

3460. 

3600. 

5250. 

79.7 

78.3 

79.6 

89.1 

170. 

< 0 

< 0 

1.05 

< 0 

131. 

131. 

132. 

136. 

217. 

0.284 

0.269 

Accuracy 

(%) 

N/A 

N/A 

"N//k 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

102. 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N//V 

99.9 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

100. 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

105. 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

Recortj 

Modified 

n 

M , El 

El 

El 

El 

El 

El 

El 

El 

• D 

El 

n El 

El 

El 

El 

El 

El 

El 

El 

El 

E l ^ 

1 m 

El 

El 

E l ^ 

El 

El 

El 

El 

El 

El 

El 

. E l 

' ^ H 

D 

n El 

D 

El 

El 

El 

El 

El 

El 

El 

El 

El 

D 

D 

El 

n El 

El 

El 

El 

El 

El 

El 

Dilution 

Factor 

1 

100 

100 

100 

100 

50 

50 

50 

50 

50 

100 

10 

10 

10 

10 

10 

100 

100 

100 

100 

50 

50 

50 

50 

SO 

10 

10 

10 

10 

10 

Acquisition Oate 

7/17/2011 11:26:31 AM 

7/17/2011 11:47:43 AM 

7/17/2011 12:08:55 PM 

7/17/2011 12:30:08 PM 

7/17/2011 12:51:18 PM 

7/17/2011 1:12:27 PM 

7/17/2011 1:33:31 PM 

7/17/2011 1:54:28 PM 

7/17/2011 2:15:31 PM 

7/17/2011 2:36:32 PM 

7/17/2011 2:57:31 PM 

7/17/2011 3:18:37 PM 

7/17/2011 3:39:50 PM 

7/17/2011 4:01:04 PM 

7/17/2011 4:22:16 PM 

7/17/2011 4:43:24 PM 

7/17/2011 5:04:22 PM 

7/17/2011 5:25:23 PM 

7/17/2011 5:46:23 PM 

7/17/2011 6:07:22 PM 

7/17/2011 6:28:28 PM 

7/17/2011 6:49:40 PM 

7/17/2011 7:10:50 PM 

7/17/2011 7:31:53 PM 

7/17/2011 7:53:00 PM 

7/17/2011 8:14:14 PM 

7/17/2011 8:35:26 PM 

7/17/2011 8:56:39 PM 

7/17/2011 9:17:51 PM 

7/17/2011 9:39:02 PM 

7/17/2011 10:00:02 PM 

7/17/2011 10:21:01 PM 

7/17/2011 10:42:03 PM 

7/17/2011 11:03:03 PM 

7/17/2011 11:24:08 PM 

7/17/2011 11:45:17 PM 

7/18/2011 12:06:30 AM 

7/18/2011 12:27:42 AM 

7/18/2011 12:48:53 AM 

7/18/2011 1:10:05 AM 

7/18/2011 1:31:18 AM 

7/18/2011 1:52:35 AM 

7/18/2011 2:13:50 AM 

7/18/2011 2:35:04 AM 

7/18/2011 2:56:19 AM 

7/18/2011 3:17:34 AM 

7/18/2011 3:38:47 AM 

7/18/2011 3:59:58 AM 

7/18/2011 4:21:01 AM 

7/18/2011 4:42:04 AM 

7/16/2011 5:03:04 AM 

7/18/2011 5:24:03 AM 

7/18/2011 5:45:13 AM 

7/18/2011 6:06:26 AM 

7/18/2011 6:27:40 AM 

7/18/2011 6:48:58 AM 

7/18/2011 7:10:12 AM 

7/18/2011 7:31:27 AM 

7/18/2011 7:52:39 AM 

7/18/2011 8:13:51 AM 

7/18/2011 8:35:05 AM 

7/18/2011 8:56:19 AM 

Data worked up by KJU 

Printing Time: 12:10:'19 PM 

Printing Date: Wednesday, July 20, 2011 
Workstation: Results Name: kll0715a 

i s f 

188 

189 

190 

191"" 

192 

193 

194 

195 

i196 

197 

198 

{199 

200 ^ 

201 

202 

203 

204 

m s " 

& 6 

207 

208 

209 

210" 

211 

212 

213 

214 

fel5 

216 

217 

218 

[219__ 

220 

1221 

222 

223 

224 

225 

226 

227 

228 

229 

230 

231 

232 

233 

234 

235 

236 

237 

238 

239 

240 

241 

242 

243 

244 

245 

246 

247 

248 

Sample Name 

k110715a187 

k110715a188 

k110715a189 

k110715a190 

k110715a191 

k110715a192 

klTb715a193 

k1l0715a194 

k110715a195 

k110715a196 

k110715a197 

kil07i5a198 

k110715a199 

kl10715a200 

kl10715a201 

kl10715a202 

kl10715a203 

kl10715a204 

kl10715a205 ' 

kl10715a206 

kl107l5a207 

kl10715a208 

kll0715a209 

k1107l5a210 

k110715a211 

k110715a212 

k110715a213 

k110715a214 

k110715a215 

k110715a216 

k110715a217 

k110715a218 

k110715a219 

kll0715a22O 

k110715a221 

k110715a222 

k110715a223 

k110715a224 

k110715a22S 

k110715a226 

k110715a227 

kl10715a228 

kl10715a229 

k110715a230 

kl10715a231 

kl107l5a232 

k110715a233 

k110715a234 

k110715a235 

k110715a236 

k110715a237 

k110715a238 

k110715a239 

k110715a240 

k110715a241 

k110715a242 

k110715a243 

k1l0715a244 

k1l0715a245 

k110715a246 

k110715b244 

kl10715b245 

Sample ID 

GLP104)1411-184)95 

GLP104)14)1-1»4)96 

GLP104)14)1-184197 

Solvent Blank 

Solvent Blank 

"ll00i.26:9 

Solvent Blank 

GLP10-0H)1-18-O98 

GLP104)14)1-184399 

GLPTl>-0T4)1-18-T6b 

GLP104)14)1-18-101 

GLP104)14)1-18-102 

GLP104)14)1-18-103 

GLP1O-OlJ0i-iB-ld4 

"GLPTSovSviSior"' 

GLP10-014)1-18-106 

GLP104)14)1-18-107 

Solvenl Blank 

Solvent Blank 

11003-26-11 

Solvent Blank 

GLPl64)1-dl-1w68 

GLP104)14)1-18-109 

GLP104)14)1-18-110 

GLP104)14)1-18-111 

GLP104)14)1-18-112 

GLP104)1-01-18-113 

GLP104)14)1-18-114 

i5?If52*tl!il!LGLP104)14)1-18-116 

GLP104)14)1-18-117 

Solvent Blank 

|Soli«niiBtenk_ 

11003-26-10 

Solvent Blank 

GLPI 0-014)1-18-118 

GLP104)14)1-1S-119 

GLP104)14)1-18-120 

GLP104)14)1-18-121 

GLP104)14)1-18-122 

GLP104)14)1-18-123 

GLP104)14)1-18-124 

GLPI 04)1-01-18-125 

GLP10-014)1-18-126 

GLP10-01-01-18-127 

Solvent Blank 

Sohent Blank 

11003-26-8 

Solvent Blank 

GLP104)14)1-18-133 

GLPTb4)14)1-Ts;i34 

GLPlO-014)1-18-128 

GLP104)14)1-18-129 

GLP104)14)1-18-130 

GLP104)1411-18-131 

GLP104)1-01-18-132 

Solvent Blank 

Solvent Blank 

11003-26-9 

Soivent Blank 

Solvent Blank 

11003-26-9 

Sample Comment 

DAL GW137SLS 110624 

DAL GW 137S MS 110624 

DAL GW 137S HS 110624 

MiDi Q Water TNI 14)234 

MIDI Q Water TN114)234 

2.5 ng/mL FC std in MilU Q Water 

MiDi Q Water TNI 14)234 

DAL GW137L 0 110624 

DAL GW137LDB 110624 

DAL GW137LLS 110624 

DALGW137LMS 110624 

DAL GW137LI4S 111)624 

DAL GW 138R 0 110630 (dil 1:10) 

DAL GW 138R DB 110630 (dil 1:10) 

DAL GW 138R LS 110630 (dD 1:10) 

DAL GW 138R MS 110630 (dil 1:10) 

DAL GW 138R HS 110630 (dil 1:10) 

MilliQ Water TN114)234 

Mini 0 Water TN114)234 

10 ng/mL FC std in MilD Q Water 

Mini Q Water TN1141234 

DAL GW138L 0110630 

DAL GW138LDB 110630 

DAL GW138LLS 110630 

DAL GW138L MS 110630 

DALGW138LHS 110630 

DAL GW 138S 0 110630 (dil 1:10) 

DAL GW 138S DB 110630 (dil 1:10) 

DALGW 138S LS 110630 (dD 1:10) 

DAL GW 13SS MS 110630 (dD 1:10) 

DAL GW 138S HS 110630 (dil 1:10) 

MiDi Q Water TN114)234 

MilliQ Water TNI 141234 

5.0 ng/mL FC std in Mini Q Water 

MIDI Q Water TNI 14)234 

DAL GW CW26C 0 110622 (dil 1:10) 

DAL GW CW26C DB 110622 (dil 1:10) 

DAL GWCW26C LS 110622 (dil 1:10) 

DAL GW CW26C MS 110622 (dil 1:10) 

DAL GW CW26C HS 110622 (dil 1:10) 

DAL GWCW26L 0 110622 (dil 1:10) 

DAL GW CW26L DB 110622 (dil 1:10) 

DAL GW CW26L LS 110622 (dD 1:10) 

DAL GW CW26L MS 110622 (dU 1:10) 

IJArGW CW26riHSTlb622 W^^^^^ 

MilliQ Water TN114)234 

MilliQ Water TN114)234 

1.0 ng/mL FC std in MiDi Q Water 

MilliQ Water TN114)234 

DALGW130LRB 110630 

DAL GW133SRB 110630 

DAL GW 140R 0 110622 (dil 1:10) 

DAL GW 140R DB 110622 (dil 1:10) 

DAL GW 140R LS 110622 (dD 1:10) 

DAL GW 140R MS 110622 (dD 1:10) 

DAL GW 140R HS 110622 (dil 1:10) 

MIDI Q Water TN114)234 

MIDI Q Water TNI 14)214 

2.5 ng/mL FC std in Mini Q Water 

MiDi Q Water TNI 14)234 

MilliQ Water TNI 14)234 

2.5 ng/mL FC std in Milli Q Water 

Sample Type 

Unknovm 

Unicnown 

Unknovm 

Unknown 

Unknown 

Quality Control 

Unknown 

"ijnknovm 

Unknown 

IJnknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm "" 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Quality" Control 

Unknown 

Unkncivm" 

Unknown 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Unknown 

Unknovm 

Unknovm 

Quality Control 

Unknovm 

Unknovm 

Unknown 

Unknovm 

Unknown 

Unknovm 

Unknown 

Unknovm 

Unknovm"" 

Unknovm 

Unknovm 

Unknown 

Unknown 

QualDy Control 

Unknown 

Unknown 

Unknovm 

Unknovm 

Unknown 

Unknown 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

QualKy Control 

Unknown 

Unknown 

Quality control 

Analyte Peak 

Name 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA J 

PFOA ^ 

PFOA" 

PFOA" 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA ' 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFCJA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA" 

PFOA 

PFOA 

PFOA 

PFOA" 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

/Uialyte PeakArea 

(counts) 

733508 

2180672 

16430196 

24247 

11381 

4738949 

6875 

713968 

729396 

965110" 

2479176 

175M357 

47583692 

46726845 

47383282 

58021857 

94415521 

51098 

14265 

^7469490" 

34849 

1655909" "" 

1660589 

1805976 

3092233 

16119725 

5604337 

15557016 

5836366 

8301390 

21245685 

Igj^g 

'"6440 

8639138 

9608 

15087641 

1^029361"" 

15420514 

17638111 

28731422 

22392308 

22371522 

23131837 

24932867 

35691197 

10914 

8493 

1832372 

14786 

19418 

M878 

4604487 

472"6472 

5135995 

8041247 

19828387 

21562 

6578 

4397053 

13307 

48843 

4556666 

lAnalyte Retention {Analyte concentration 

Time (mm) (ng/mL) 

15 4 

154 

"154 

" 15 5"" 

15 4 

"15 4 

"155 

"15 4 

15 4 

"l"5 4 "" 

154 

15 4 " " 

154 

115.4 

115.4 

15.4 

15.4 

15.5 

15.4 

15.4 

15.5 

15.4 

15.4 

15.4 

15 4 

15 4 

154 

15 4 

15 4 

15 4 

15 4 

15 6 

15 5 

15 4 

15 5 

154 

154 

154 

154 

154 

154 

154 

154 

154 

15 4 

15 5 

15 5 

15 4 

15 5 

15 5 

154 

15 4 

154 

15 4 

154 

154 

154 

15 5 

15 4 

15 4 

15 5 

15 4 

N/A 

N/A 

N/A 

N/A 

Use 

Record 

Calculated 

Concentration (ng/mL) 

0.383 

1 18 

9 32 

K O 

N/A 

250 0 

< 0 

2"61 

N/A |<0 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

10.0 

N/A 

N/A 

N/A 

N/A 

~ S 

0 372 

0 381 — ~ ~ 

0 477 

1.35 

9.¥s"' 

294. 

288. 

292. 

370. 

709. 

0 00800 

< 0 

994 ~ ~ — 

< 0 

'0S91 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 E 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

1.00 El 

N/A 

N/A 

N/A 

N/A 

N/A" 

N/A" 

N/A 

N/A 

N/A 

N/A 

2.50 : El 

N/A 

N/A 

2.50 El 

0.894 

0.974 

1.69 

9.14 

155. 

153. 

161. 

231. 

610. 

< 0 

< 0 

4.81 

< 0 

427. 

425. 

436. 

502. 

841. 

645. 

644. 

667. 

723. 

1060. 

< 0 

< 0 

0.989 

< 0 

< 0 

< 0 

127. 

130. 

141. 

223. 

|567^ 

< 0 

<6" 

2.41 

< 0 

0.00676 

2.50 

Accuracy 

(%) 

N/A 

N/A 

N/A"" 

N/A 

N/A 

104! 

WA 

N/A " 

N/A" 

N/A" 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

994 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

96.1 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

98.9 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

96.6 

N/A 

N/A 

100. 

Record 

Modified 

El 

a " 

a 

D 1 

EI 1 

" D " 

"'E l 

El 

El 

D 

El 

El " 

El 

"El" 

m 

a 

El 

D 

El 

EI 

El 

_„.E1„^ 

El 

El 

El 

El 

El 

El 

n 

D 

El 

D 

El 

El 

El 

El 

El 

El 

El 

El 

El 

El 

D 

D 

El 

n El 

El 

El 

El 

El 

El 

El 

El 

D 

D 

El 

El 

El 

Dilution 

Factor 

;:::. : 

1 

10 

10 

10 

10 

10 

Acquisition Date 

7/18/2011 9:17:32 AM 

7/18/2011 9:38:45 AM 

7/18/2011 10:00:01AM 

7/18/2011 10:21:14 AM 

7/18/2011 10:42:32 AM 

7/18/2011 11:03:45 AM 

7/18/2011 11:25:00 AM 

7/18/2011 11:46:14 AM 

7/18/20Tf 12:07:30 PM 

7/18/2011 12:28:42 PM 

7/18/2011 12:49:58 PM 

7/18/2011 1:11:15 PM 

7/18/2011 1:32:30 PM 

7/18/2011 1:53:44 PM 

7/18/2011 2:14:57 PM 

7/18/2011 2:36:17 PM 

7/18/2011 2:57:32 PM 

7/18/2011 3-18-44PM 

1 7/18/2011 3 40 00 PM 

1 |7/18/2011 4 01 13 PM 

50 

50 

50 

50 

50 

1 

1 

1 

1 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

1 

1 

1 

1 " • 

1 

1 

50 

=° 50 . _^. ^ 

50 

|50 

J -

7/18/2011 4 22 29 PM 

7/18/2011 4 43 44 PM 

7/18/2011 5:05:00 PM 

"7/18/2011 5:26:17 PM 

7/18/2011 5:47:32 PM 

7718/2011 6:08:47 PM 

7/18/2011 6:30:04 PM "* 

7/18/2011 6:51:14 PM 

17/18/2011 7:12:13 PM 

7/18/2011 7:33:13 PM 

7/18/2011 7:54:22 PM 

7/18/2011 8:15:26 PM 

7/18/2011 8:36:35 PM 

7/18/2011 8:57:48 PM 

7/18/2011 9:19:03 PM 

7/18/2011 9:40:19 PM 

7/18/2011 10:01:31 PM 

7/18/2011 10:22:35 PM 

7/18/2011 10:43:43 PM 

7/18/2011 11:04:50 PM 

7/18/2011 11:25:52 PM 

7/18/2011 11:47:01 PM 

7/19/2011 12:08:03 AM 

7/19/2011 12:29:04 AM 

7/19/2011 12:50:10 AM 

7/19/2011 1:11:13 AM 

7/19/2011 1:32:21 AM 

7/19/2011 1:53:42 AM 

7/19/2011 2:14:58 AM 

7/19/2011 2:36:20 AM 

7/19/2011 2:57:36 AM 

7/19/2011 3:18:51 AM 

7/19/2011 3:39:59 AM 

7/19/2011 4:01:07 AM 

7/19/2011 4:22:12 AM 

7/19/2011 4:43:16 AM 

7/19/2011 5:04:17 AM 

7/19/2011 5:25:31 AM 

7/19/2011 5:46:48 AM 

7/19/2011 6:08:04 AM 

7/19/2011 9:03:43 AM 

7/19/2011 9:24:59 AM 

Data worked up by KJU 

Printing Time: 12:10:49 PH 

Printing Date: Wednesday, July 20, 2011 
Workstation: Results Na kll0715a.rdb 

249 

250 

251 

252 

253 

254 

255 

256 

257 

258 

I2M~ ' 

260 

261 

262 

263 

264 

265 

266 

267 

268 

269 

270 

271 

272 

273 

^74 

275 

276 

277 

Sample Name 

k110715b246 

k110715b247 

k1l0715b248 

k110715b249 

k110715b250 

k110715b251 

k110715b252 

k110715b253 

k110715b254 

k110715b255 

k1107l5b256 

k110715b257 

k1107l5b258 

k110715b259 

k110715b260 

k110715b261 

k110715b262 

k110715b263 

k110715b264 

k110715b265 

kl10715b266 

k110715b267 

kl10715b268 

k1107151)269 

kl10715b270 

kl10715b27i 

k110715b272 

kl10715b273 

kl10715b274 

Sample ID 

Sohent Blank 

GLP104)14)1-18-135 

GLP1(M)14)1-18-136 

GLP104)14)1-18-137 

GLP104)14)1-18-13S 

GLP104)14)1-18-139 

GLP104)1-01-18-140 

GLP10-014)1-18-141 

GLP1(M)14)1-18-142 

GLP104114)1-18-143 

GLP104)14)1-18-144 

Solvent Blank 

Solvent Blank 

11003-26-11 

Solvent Blank 

GLP104)14)1-18-145 

GLP104)14)1-18-146 

GLP104)14)1-1B-147 

GLP104114)1-18-148 

GLP104)14)1-18-149 

GLP10-014)1-18-150 

GLP104114)1-18-151 

GLP104)14)1.18-152 

GLP104)14)1-18-153 

GLP104)14)1-18-154 

Solvent Blank 

Solvent Blank 

11003-26-10 

Solvent Blank 

Sample Comment 

Mini 0 Water TN114)234 

DAL GW141R 0 110630 

DAL GW141RDB 110630 

DAL GW141RLS 110630 

DAL GW141R MS 110630 

DAL GW 141R HS 110630 (dil 1:10) 

DAL GW 142R 0 110622 (dil 1:10) 

DAL GW 142R DB 110622 (dil 1:10) 

DAL GW 142R LS 110622 (dD 1:10) 

DAL GW 142R MS 110622 (dil 1:10) 

DAL GW 142R HS 110622 (dil 1:10) 

MiDi Q Water TNI 14)234 

MiDi Q Water TN114)234 

10 ng/mL FC std in Mini Q Water 

MilliQ Water TN114)234 

DAL GW 143R 0 110622 (dD 1:10) 

DAL GW 143R DB 110622 (dil 1:10) 

DAL GW 143R LS 110622 (dD 1:10) 

DAL GW 143R MS 110622 (dil 1:10) 

DAL GW 143R HS 110622 (dil 1:10) 

DAL GW 144S 0 110628 (dD 1:10) 

DAL GW 144S DB 110622 (dil 1:10) 

DAU GW 144S LS 110622 (dD 1:10) 

DAL GW 144S MS 110622 (dil 1:10) 

DAL GW 144S HS 110622 (dil 1:10) 

MiDi Q Water TNI 14)234 

Sample Type 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknovm 

Unknown 

Unknown 

Unknovm 

Unknovm 

Unknovm 

Unknovm 

Quality control 

Unknovm 

Unknovm 

Unknovm 

Unknown 

Unknovm 

Unknovm 

/Vnalyte Peak 

Name 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Unknown PFOA 

Unknown PFOA 

Unknown PFOA 

Unknovm 

Unknovm 

Unknovm 

MIDI Q Water TNI 14)234 iUnknown 

5.0 ng/mL FC std in Mini Q Water 

MiDi Q Water TN114)234 

Quality Control 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Unknown :PFOA 

Analyte PeakArea Analyte Retention'Analyte concentration 

(counts) Time (min) (ng/mL) 

21311 i15.4 

2918997 |15.4 

2876040 :i5.4 

4546065 15.4 

3854963 15.4 

3354229 

1857178 

1903540 

1883286 

2123043 

5245686 

4532 

7817 

17345305 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.6 

15.9 

15.4 

14730 i15.7 

4252765 115.4 

4516701 

4640869 

5994380 

20382201 

1927318 

1816698 

1895993 

2224801 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

15.4 

5015176 il5.4 

6774 J1S.5 

2572 ;iS.5 

9041166 '15.4 

14726 ;15.5 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

10.0 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

,_ N/A 

N/A 

N/A 

N/A 

N/A 

5.00 

N/A 

Use 

Record 

El 

El 

Calculated 

Concentration (ng/mL) 

< 0 

1.59 

1.57 

2.50 

10.6 

91.6 

50.1 

51.4 

50.9 

57.5 

144. 

< 0 

< 0 

9.87 

< 0 

23.3 

24.8 

25.5 

33.1 

117. 

52.1 

49.0 

51.2 

60.3 

< 0 

< 0 

5.04 

< 0 

/Accuracy 

(%) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

98.7 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

101. 

N/A 

Record 

Modified 

El 

El 

El 

El 

El 

El 

El 

El 

El 

El 

El 

D 

D 

El 

D 

El 

El 

El 

El 

El 

El 

El 

El 

El" 

El 

D 

El 

El 

El 

Dilution 

Factor 

50 

50 

50 

50 

50 

50 

1 

1 

1 

1 

10 

10 

10 

10 

10 

50 

50 

50 

50 

50 

1 

1 

1 

1 

Acquisition Date 

7/19/2011 9:46:14 AM 

7/19/2011 10:07:27 AM 

7/19/2011 10:28:39 AM 

7/19/2011 10:49:54 AM 

7/19/2011 11:11:06 AM 

7/19/2011 11:32:15 AM 

7/19/2011 11:53:17 AM 

7/19/2011 12:14:21 PM 

7/19/2011 12:35:22 PM 

7/19/2011 12:56:20 PM 

7/19/2011 1:17:18 PM 

7/19/2011 1:38:18 PM 

7/19/2011 1:59:24 PM 

7/19/2011 2:20:38 PM 

7/19/2011 2:41:51 PM 

7/19/2011 3:03:02 PM 

7/19/2011 3:24:21 PM 

7/19/2011 3:45:32 PM 

7/19/2011 4:06:47 PM 

7/19/2011 4:28:01 PM "1 

7/19/2011 4:49:12 PM 

7/19/2011 5:10:18 PM 

7/19/2011 5:31:20 PM 

"7/19/2011" "5:52:20 PM 

7/19/2011 6:13:20 PM 

7/19/2011 6:14:19 PM 

7/19/2011 6:55:26 PM 

7/19/2011 7:16:36 PM 

7/19/2011 7:37:54 PM 

rked up by KJU Page 5 of 5 

Printing Time: 12:10:49 PM 

Printing Date: Wednesday, July 20, 2011 
3M Confidential 3M Environmental Laboratory 

Project: GLP10-01-01-18 

Sequence k110728a 

3M Environmental Laboratory 

3M Technical Lead: Susan Wolf 

Building 260-5N-17 

651-733-9851 

Report Author: Chelsie Grochow 

Analytical Team: Kelly Ukes 

Analytical Case Narrative for Method ETS-8-44.0 

Project GLP10-01-01-18 

Decatur Phase 3 FSIA Groundwater- June 2011 

Direct injection analysis of samples 

Sequence kl10728a 

Report Date: July 29, 2011 

Instrument summary and calibration curves will be printed and included in the raw data package. 

Chromatograms will be printed to pdf. 

ETS 8-044 Analytical Summary Checklist Page 1 of 3 
3I\/I Confidential 

1 Project Scope and Data Quality Objective 

3M Environmental Laboratory 

Project: GLPlO-01-01-18 

Sequencekl10728a 

General Project Outline available. 

GLP 

EI Yes 

13 Yes 

n No 

n No 

If No, Please briefly describe 

project scope and DQO 

2 Sample Container Preparation 

Sample container preparation documented in a Note to File and Included in the raw data package. 

3 Sample Analysis 

3.1 System Suitability 

Initial System Suitability area counts with RSD S5% (ETS-8-154 section 

10.5) and retention time with RSD s2% 13 Yes DNo 

3.1.1 System Suitability Deviations 

NA 

3.2 Instrument Calibration 

Curve type 

r'>0.990 Linearity criteria met (ETS-8-44 section 12.2) 

< ± 25% residuals, except LOQ of ±30% (ETS-8-44 section 12.2) 

Mid-level calibration points disabled 

Quadratic, 1/x 

13 Yes 

13 Yes 

DYe s 

D N o 

D N o 

13 No 

3.3 Continuing Calibration Verification 

±25% Difference criteria met for periodic CCVs (ETS-8-44 section 12.2) 13 Yes DNo 

3.3.1 Continuing Calibration Verification Deviations 

NA 

3.4 Method Blanks 

Method blanks uniquely identified in the run sequence. 

Average area counts of target analytes in the method blank present at 2 V4 x 

the area counts of the LOQ standard (ETS-8-44 Section 10.2) 

13 Yes 

13 Yes 

D N o 

D N o 

3.4.1 Method Blank Deviations 

NA 

ETS 8-044 Analytical Summary Checklist Page 2 of 3 
3M Confidential 

3.5 Lab Control Spikes 

3M Environmental Laboratory 

Project: GLPlO-01-01-18 

Sequence kl 10728a 

±20% recovery criteria met (ETS 8-44 Section 10.5) 

<20% RSD precision (ETS 8-44 Section 10.5) 

13 Yes 

13 Yes 

D N o 

D N o 

3.5.1 Lab Control Spike Deviations 

NA 

3.6 Sample Replicates 

RPD for field duplicates <20% (ETS-8-44 Section 10.5) 13 Yes D N o 

3.6.1 Sample Replicates Deviations 

NA 

3.7 Field Matrix Spikes 

±30% recovery criteria met. (ETS 8-44 Section 10.5) 13 Yes D N o 

3.7.1 Field Matrix Spike Deviations 

No appropriate spike level to assess sample recovery for 135S. 

3.8 Limit of Quantitation (LOQ) 

All LOQs equal the low-level calibration standard concentration 

with area counts at least twice that of the method blank(s) (ETS 8-

44 Section 10.2) 

13 Yes D N o 

3.9 Manual Integrations 

Manual integration reviewed by another analyst/team lead: 

Reviewed Date: *&|>|il bv: tcf ^ 13 Yes DNo 

4 Additional analytical notes 

All data will be reported. 

5 Signatures 

^VihiiL'^/iArrhM^) •^-2^-1 \ 

Analyst Date 

ETS 8-044 Analytical Summary Checklist Page 3 of 3 
Kirk API 5500, BB21501010 page 1/1 

DATE: 7/28/2011 

ANALYST: CJG 

STUDY NUMBER: GLPlO-01-01-18. GLPlO-01-01-19 

Sample Prep Date: 7/26/11 

Sample Aliquot Date: 7/26/11 

LC/MS/MS Method: PFOA with IS 

Mobile Phase: (A) 2mM ammonium acetate (aq) (B) Methanol 

TN-A- or standard number (A) 11005-120 (B) TNI 1-0240 8/8 

Guard column: Betasil €18 Column 4.6xl00mm 

Size: 5u Lot number: 10827 

Serial number 0213785K3 started 6/27/11 

Part number: 70105-104630 

Analytical column: Betasil C18 Column 4.6xl00mm 

Size: 5u Lot number: 10827 

Serial number 0213786K4 started: 6/27/11 

Part number: 70105-104630 

DATA FILE: kl 10728a 

See method for LC/MS/MS parameters 

c^cbimiw 

Printed: Thursday, July 28, 2011 9:47 AM 
•Kirk BB21501010 

Prajed; P:\Pro]ect*LabJnstnjmenlData\KirMkrkdala\Pro|ectSfluorocliemlcals_walerBatch:k110728a TabiSample Sel:SET1 AcqMothod:PFOA with IS.dam 

Sample 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

22 

23 

24 

25 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

60 

51 

52 

53 

54 

55 

56 

57 

58 

59 

60 

61 

62 

63' ^ ' 

64 

65 

66 

67 

68 

69 

70 

71 

Sample Name 

I<110728a001 

k110728a002 

k110728a003 

k110728a004 

k110728a005 

k110728a006 

kl107283007 

k110728a008 

k110728a009 

k110728a010 

k110728a011 

k110728a012 

kl107288013 

k110728a014 

k110728a015 

k110728a016 

k110728a017 

k110728a018 

k110728a019 

k110728a020 

kl107283021 

k110728a022 

kl167233023 

k110728a024 

kri0728a025 

k110728a026 

kl107283027 

kl107283028 

kl107283029 

k1107283030 

kl107283031 

kl107283032 

kl107283033 

kl107283034 

kl107283035 

kl107283036 

kl107283037 

kl107283038 

k110728a039 

k1107283040 

kl107233041 

kl107283042 

kl107283043 

kl107283044 

kl107283045 

kl107283046 

kl107263047 

kl107283048 

kl107283049 

kl107283050 

kl107283051 

kl107283052 

kl107283053 

kl107283054 

k110728a055 

kl107283056 

k110728a057 

kl107283058 

k110728a059 

k1107263060 

kl107283061 

kl107283062 

k1107283063 

k1107283064 

k1107283065 

k110728a066 

kl107283067 

k110728a068 

k110728a069 

k1107283070 

k1107283071 

Sample ID 

11005-59 

11005-59 

11003-25-8 

11003-25-8 

11 003-25-8 

11 003-25-8 

11005-59 

11005-59 

11 003-25-1 

11 003-25-2 

11003-25-3 

11003-25-4 

11003-25-5 

11003-25-6 

11003-25-7 

11 003-25-8 

11003-25-9 

11 003-25-10 

11 003-25-11 

11003-25-12 

11 003-25-13 

11003-25-14 

11003-25-15 

11003-25-16 

11 005-59 

11005-59 

11 005-59 

LCS-110726-1 

LCS-110726-2 

LCS-110726-3 

LCS-110726-4 

LCS-110726-5 

LCS-110726-6 

LCS-110726-7 

LCS-110726-8 

LCS-110726-9 

11005-59 

11005-59 

11003-25-10 

11 005-59 

LCS-110726-10 

LCS-110726-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-15 

LCS-110726-16 

LCS-110726-17 

LCS-110726-18 

11 005-59 

11005-59 

11003-25-9 

11 005-59 

11 005-59 

GLPI 0-01-01-19-009 

GLPI 0-01-01-19-001 

GLPI 0-01-01-19-002 

GLPI 0-01-01-19-003 

GLPI 0-01-01-19-004 

11005-59 

GLPI 0-01-01-19-005 

GLH 0-01-01-19-006 

GLPI 0-01-01-19-007 

GLPI 0-01-01-19-008 

11 005-59 

11 005-59 

11 003-25-8 

11 005-59 

GLPI 0-01-01-19-010 

GLPI 0-01-01-19-011 

GLPI 0-01-01-19-012 

Vial Position 

91 

91 

8 

8 

8 

8 

92 

92 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

16 

92 

93 

93 

17 

18 

19 

20 

21 

22 

23 

24 

25 

94 

94 

10 

95 

26 

2^ 

28 

29 

30 

31 

32 

33 

34 

95 

96 

9 

96 

97 

35 

36 

37 

38 

39 

97 

40 

41 

42 

43 

97 

98 

8 

98 

44 

45 

46 

Data File | Inj.Volume (|il) 

kl10728a 

kl107283 

kl 107283 

kl107283 

kl 10728a 

kl107283 

kl 10728a 

kl107283 

kl107283 

kl107283 

kl107283 

kl107283 

kl107283 

kl10728a 

kl107283 

kl107283 

kl107283 

kl 10728a 

kl10728a 

kl107283 

kl10728a 

kl107283 

kl107283 

kl107283 

kl10728a 

kl10728a 

kl10728a 

kl107283 

kl107283 

kl107283 

kl 107283 

kl10728a 

kl 107283 

kl 10728a 

kl10728a 

kl10728a 

kl10728a 

kl10728a 

kl107283 

kl 10728a 

kl10728a 

kli0728a 

kl10728a 

kl 10728a 

kl 107283 

kl 107283 

kl 10728a 

k1107283 

kl 10728a 

kl 10728a 

kl 10728a 

kl 107283 

k1107283 

k1107283 

k110728a 

kl10728a 

k1107283 

k1107283 

kl10728a 

kl107283 

kl107283 

kl 107283 

k110728a 

k110728a 

k1107283 

kl 107283 

kl 107283 

kl10728a 

kl 10728a 

kl 107283 

kl 107283 

25.000 

25.000 

25.6d0 

25.000 

25.6bd 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.d6b 

25.000 

25.000 

26.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

26.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

25.000 

Comments 

Method Blenk 

Method Blank 

1.0 ng/mL FC std in Synth. Water 

1.6 ng M FC std in Synth. W3ter 

1.0 ng/mL FC std in Synth. Weter 

1.0 ng/mL FC std in Synth. Weter 

Method Blenk 

Method Blank 

0.025 ng/mL FC std in Synth. Water 

0.03 ng/mL FC std in Synth. Weter 

0.04 ng/mL FC std in Synth. Water 

0.05 ng/mL FC std in Synth. Water 

0.1 ng/mL FC std in Synth. Water 

0.25 ng/mL FC std in Synth. Weter 

0.5 ng/mL FC std in Synth. Weter 

1.0 ng/mL FC std in Synth. Weter 

2.5 ng/mL FC std in Synth. Water 

5.0 ng/mL FC std in Synth. Weter 

10 ng/mL FC std in Synth. Water 

15 ng/mL FC std in Synth. Water 

25 ng/mL FC std in Synth. Water 

50 ng/mL FC std in Synth. Water 

75 ng/mL FC std in Synth. Weter 

100 ng/lTl FC std In Synth. Water 

Method Blank 

Method Bl3nk 

Method Blenk 

0.2ppb LCS 

0.2ppb LCS 

0.2ppb LCS 

2ppb LCS 

2ppb LCS 

2ppb LCS 

20ppb LCS 

20ppb LCS 

20ppb LCS 

Method Blenk 

Method Blsnk 

5.0 ng/mL FC std in Synth. Water 

Method Benk 

0.2ppb LCS ECF 

0.2ppb LCS ECF 

0.2ppbLCSECF 

2ppb LCS ECF 

2ppb LCS ECF 

2ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

20ppb LCS ECF 

Method Blenk 

Method Blank 

2.5 ng/mL FC std in Synth. Water 

Method Hank 

Method Bl3nk 

DALGWBPMW121 RS 110713 

CWLGWTRiPI 0110713 

DALGWTRIP1 LS 110713 

DALGWTRIP1 MS 110713 

DALGWTRIP1HS 110713 

Method Blank 

DAL GWBPMW470 110713 

DAL GW BPMW47 DB 110713 

DALGWBPMW47LS110713 

DAL GWBPMW47HS 110713 

Method Blenk 

lUethod Blenk 

1.0 ng/mL FC std in Synth. Water 

Method Blank 

D^LGWBF=MW121 0 110713 

DALGWBPMW121 DB 110713 

DALGWBPMW121 LS 110713 

Print;ing Time: 9:44:12 AM 

Printing Date: Thursday, July 28, 2011 

Page 1 of 2 CJ<S7/2'S/)I 
*Kirk BB21501010 

Project: P:\Project^ab_lnstnjment Data\KJrMMrfcdata\Project£\f1uoroche[nicaIs_waterBatch:k110728a TabiSample Set:SET1 AcqMethod:PFOA with IS.dam 

Sample 

(Sample Name 

72 

73 

74 

75 

76 

"77 ""• 

78 

79' 

80 

81 

kl107283072 

kl107283073 

kl107283074 

kl107283075 

ki167283676 

kl107283077 

kl107283078 

k110728a079 

k1107283080 

k110728a081 

Sample ID 

GLPI 0-01-01-19-013 

11005-59 

11005-59 

GLPI 0-01-01-18-069 

GLPI 0-01-01-18-070 

GLPI 0-01-01-18-073 

11005-59 

11005-59 

11003-25-11 

11005-59 

Vial Position 

47 

99 

99 

48 

49 

60 

99 

100 

11 

100 

Data File 

kl10728a 

kl10728a 

kl10728a 

kl10728a 

kl107283 

kl107283 

kl10728a 

kl 107283 

kl107283 

k1107283 

Inj.Volume (pi) 

25.000 

25.000 

25.666 J 

25.000 

25.000 

25.666 

25.000 

25.000 

25.000 

25.000 

Comments 

DALGWBPMW121 HS 110713 

Method Blank 

Method Blenk 

DAL GW135S 0110628 

CALGW135SDB110628 

mLGW135SHS 110628 

Method Blenk 

Method Blank 

10 ng/mL FC std in Synth. Water 

Method Blank 

Printing Time: 

Printing Date: 

9:44:12 AM 

Thursday, July 28, 2011 

Page 2 of 2 
•Kirk BB21501010 

Acquisition Information: 

Aoqji^itio i Method: 

CEcated: 

last MTriiflM; 

OcriTHit: 

q^ff^ 111. .ii7at-i m MSJC : 

Aitu-Bjjilibiatiicn: 

itojjisitiicii cucarim: 

Hjiiaer of scans: 

Eedaf e In Pile : 

itojiisitJ m ttDdLOe: 

SoftMaie versim 

S-rirrl 1: 

Scans i n Period: 

Relat^lve star t TiiiE: 

Ei^erinEnts i n Perixxi: 

Period 1 B^^rinen t 1: 

Scan T^pe: 

SdeJule d MM; 

Balarity: 

Scan M33e: 

li2i Source: 

nesolutdxzi Ql: 

Besolutim03 : 

intensit y Three.: 

Settlin g Tims: 

Ml reuse: 

hCR: 

s t ^ Size : 

01 v&m (CB) 03 t^iss (ca) I>,:ell{iiGec) 

413.000 369.000 30.00 

CO. ^BSS (TB) 03 N6SS (IB) DueUtriBCC) 

413.000 219.000 30.00 

QlffisstDa ) 03 ress (ra) D»ell(iraec) 

413.000 169.000 30.00 

Ql ^esB (CB) 03 hBss (EB) Du=U(nBCC) 

421.000 376.000 30.00 

EBianeter l^l e (Period 1 E5?)erijT»tf: 1) 

CUR 

CUD 

TIM 

OSl 

G52 

35.00 

6.00 

450.00 

55.00 

50.00 

IS: -4500.00 

PLiip «riel : J^ilsi t 1200 Binary Euip 

Miniitun Pressure (psi): 0.0 

texinun Pressure (pei): 5801.0 

Dead Vbluie dil) : 40.0 

NbxijTun Flew I^np (nil/niin>); 100.0 

Kodiiun Pressure I^np (pei/sec): 

^ex FlDU Ranp t * (ni/min') : 100.0 

tex Flow Ranp III (ml/tninO : 100.0 

Stq j Table: 

Step Tbta l Tlnednin) Flow Rate(iiL/min) 

C 0.00 750 

1 2.00 750 

2 14.50 750 

3 15.50 750 

4 16.50 750 

£ 20.00 750 

l£ft Onpressiljility : 50.0 

Left Dead \t3lllIE (111) : 40.0 

Right Dead \blijm (iH): 40.0 

lef t Strct e «3lui e (liL): 

Right Strrt e *lut E dil) : 

Left Sdvm; : Al 

Right Solvmt: Bl 

Baran 

a 

E£ 

a 

CXE 

EBran 

CE 

K 

CE 

CH 

I^uan 

CE 

EI 

a 

COT 

EBran 

a 

S 

CE 

COT 

290.0 

A (* 

97.0 

97.0 

S.O 

S.O 

97.0 

97.0 

-1.0 

-1.0 

[¥C1A with IS.dam 

WetiXBday Jul y 27 2011 U : 44: 13 i*I 

Itetiesday Jul y 27 2011 U : 44: 13 » 1 

ETOAwith IS 

LC Sync 

Cff 

20min0sec 

8568 

1 

to(jisitiai Methai 

toalyst 

8568 

1.5.2 

0.00 nsec 

1 

n m (WW) 

N3 

tfcgati^re 

tVA 

•nnt o Stiray 

Ulit 

Uli t 

0.00 cpe 

0.0000 nsec 

5.0070 nBec 

K> 

0.00 na 

star t 

-41.00 

-8.50 

-15.00 

-6.00 

Start 

-41.00 

-8.50 

-22.00 

-9.00 

Start 

-100.00 

-10.00 

-37.00 

-9.00 

Start 

-41.00 

- 8 . SO 

-15.00 

-6.00 

B (%) 

3.0 

3.0 

9S.0 

95.0 

3.0 

3.0 

Stop IC 

-41.00 PFOA-1 

-8.50 

-15.00 

-6.00 

Step IE 

-41.00 PEDA-2 

-8.50 

-22.00 

-9.00 

Stop IT 

-100.00 PFaA-3 

-10.00 

-37.00 

-9.00 

Step IE 

-41.00 13C8PECIA-IS 

-8.50 

-15.00 

-6.00 

Printing Time: 9:44:36 AM 

Printing Date: Thursday, July 28, 

Page 1 of 2 C j 6 7/Z^/(( 
*Kirk BB21501010 

;>gilent Aitceaipler Pccpertles 

Aitosanpler Mxlel: .^^ilent 1200 Standard AitoGanpIer 

Syringe Slae (^a) : 100 

Uijection \tiluie (pi): 2S.00 

Dcaw £(»ed (pl/min): 200.0 

Eject £t«ai (pl/min): 200.0 

Needle level (mrO : 0.00 

ItoperaCure Qntrol Eiiabled 

Setpoint (4 - 40 O : 15 

Vfeish is not used 

tfee Qjstxm Injector Ptrgran tto 

i^gilent CbluTn CXflen Prcperties 

Left T&ipeiature CO : 30.00 

Ric^ Tfenperature ("O : 20.00 

T&rperadjre Tblerance +/- CO : 1.00 

Start flcqulsition Tblec3ix:e +/- CO : 0.50 

TiiTe Table (Used) 

Oalxim Switdiing ^alve Distalled CSV 

Ksition for first sanple in the tattii: Left 

Use same pceiticn for all sanples in the bat(± 

Tbtal Tme{miii) Mdlve Etisition 

0.00 Left 

S.OO Right 

Printing Time: 9:44:36 AM Page 2 of 2 

Printing Date: Thursday, July 28, 2011 
Worlcstation : ETSKIRK Results Name: kll0728a.rd b 

k110728a.rdb (PFOA): "Quadratic" Regression ("1 / x" weighting): y = -0.00307 x'^2 + 1.09 x + 0.0166 (r = 0.9998) 

80-

75-

70-

65-

60-

55-

50-

45-

40-

35-

30-; 

25-

20-

15^ 

10^ 

5-

0-

•r 

^ y 

• 

y 

/ 

.• 

y 

A 

y 

y 

y 

y 

y 

•/^ 

y ' X 

X y ' 

y 

y ' 

,'' y ' 

y''" 

, y ' 

y ' 

,•••-•• " 

,y' ' 

, y ' 

,--'' 

,^'' 

,^'''' 

,,•••"' 

,.,•••' 

y 

^.^"^ 

,..^"" ^..'-"' 

_.--

^..-'-^' 

.,•'• 

^^'' 

"-""" 

0 5 10 15 20 25 30 35 40 45 50 55 60 

Analyte Cone. / IS Cone. 

65 70 75 80 85 90 95 100 

Data worked up by KJU 

Printing Time: 2:35:46 PM 

Printing Date: Monday, August 01, 2011 

Page 1 of 1 
1 Sample Nante 

1 

2" 

3 

4 

5 

6 

7 ' 

•« 9 

No 

12~ 

13 

14 

15 

16 

17 

18 

19 

*2D ' 

21" 

22 

k110728a001 

^ikTlO72aaO0G 

k110728a003 

k110728aOD4 

k11072Sa005 

k11072aa006 

k11O72aaO07 

k110728a006 

k11072SaOGS 

k110728aO1D 

k'll672!abl1 

k110728aO12 

k110728aO13 

k11072Sa014 

k110728aO15 

k110728aO16 

k11072aa017 

klib728a6ia 

k110728aO19 

kTib72aio20 

k1lb72&b21 

k110728a022 

23 ;k110728aO23 

24 k110728aO24 

25 ^kllOTTflanTfi 

' X ikl 107283026 

27 ^k110728a027 

2S k110728aO28 

29 iTl 1072^029 

20 k110728a030 

^31 k110728aO31 

132 

33 

34 

36' 

36 

37 

38 

39 

« 

4 1 42 ~ 

43 

|44 

45 

46 

47 

48 

49 

50 

51 

52 

b3 

5 4 " 

56 

57 

58" " 

61 

62 

63 

64 

65 

* 67 

68 

69 

k11072a3032 

kli0728a033 

k110728a034 

k11-6raWE6 

k110728a036 

k11072BaO37 

k110728aO38 

k110728aO39 

k11072SaO40 

kl107283041 

k1107MaO42 

k110728a043 

k110728aO44 

kTl072tob45 

kll0728a046 

kl1072BaO47 

k1107aaD4a 

kl1072aa049 

k i 107^3050 

k1107:fflaO51 

k110728aO52 

k110728aO53 

k110728aO54 

k110728aOS5 

k110728aCB6 

kl 107^3057 

kl10728aOS8 

k110728aO59 

k110728a060 

k110728a061 

kl10728a062 

k110728a063 

k110728a064 

k1107^a065 

k110728a066 

kl107^a067 

k11072aai368" •• 

k110728a069 

70 ik11072aa070 

f f iklT072te67i"'~" 

72 k1l072BaOn 

73 ;k1l072BaO73 

74 'k110728a074 

|7S n<11072aa07S " 

76 kll072Sa076 

77 ''k11072Ba077 

78 kl10728aO78 

SampkI D 

1100&S9 

1100&69 

iiooi5s e 

iio(»-2Sa 

11003.2M 

11003-25^ 

1100&59 

1100&59 

11003-25-1 

11003-2S-2 

iiai3-2 M 

11003-25-4 

11003-2&5 

11003-25-6 

11003-25-7 

i i 003-25^ 

11003.2Sa 

liaB-25-i b 

11003-2S-11 

iidb3-25-i2" ""• 

11003-25-13 

11003-25-14 

Sample Corament 

Method Blank 

Method Blar« 

1.0 r^mL FC Btd in Syrfh. Water 

1.0 ng/mL FC M in SynlK Water 

1.0 nfl/mL FC Ud in Syrlh. Water 

1.0 r^mL FC ttd in Syrlh. Water 

Method Blar* 

Method Blank 

0.025 r^lml FC ktd 'm Syr«h. Water 

0.03 r^mL FC std in Synth. Water 

0.04 rg/mL FC std in Syrth. Water 

0.05 ng/mL FC std in SyrtK Water 

0.1 nglml FC std in Synth. Water 

0.25 i^m L FC std in Synth. Water 

0.5 r^mL FC std in Synth. Water 

i.O nftfmL FC std in Syrih. Water 

Z5 ng/mL FC std in Syrth. Water 

5.0 r^mL FC std in Synth. Water 

ID ngfrnL FC std in Synth Water 

15 r^mL FC stdln'Synth. WateT 

25 ngfrnL FC std in Synth. Water 

50 nglml FC std in Synth. Water 

11 003-25-15 ^75 ng/mL FC std in SynlK Water 

11003-25-16 

11005-59 

1100559 

11005-S9 

LCS-11D726-1 

LCS-11072&.2 

LCS-110726O 

LCS-110726^ 

LCS-11072&6 

LCS-11072&e 

LCS-110726^7' 

•LCS^ii072Ml 

LCS-iiD72&a 

1100&69 

1100&59 

11 oro-s-10 

11005 ^ 

LCS-11D72&-i0 

LCS-11D72S-11 

LCS-110726-12 

LCS-110726-13 

LCS-110726-14 

LCS-110726-15 

LCS-110726-16 

I X rxf/mL FC std in Synth Water 

Method Blank 

Method Blank 

Method Blank 

0 2ppb LCS 

0 2ppb LCS 

0 2ppbLCS 

2ppbLCS 

2ppbLCS 

2ppbLCS 

20ppbLCS 

20ppbLCS" 

2b^S>"LCS 

Method Blar* 

Method Blank 

5.0 ng/mL FC std in SyrUv Water 

Method Blar* 

0.*pb LCS ECF 

0.*pb LCS ECF 

0.^pb LCS ECF 

2ppb LCS ECF 

ilppbLCStCF' 

2ppb LCS ECF 

2Cppb LCS ECF 

LCS-110726-17 ;20ppb LCS ECF 

LCS-110726-18 

irdbss g 

20ppbLCSECF 

Method Biark 

IIOOS ^ IMethodBlark 

11003-2M 

11005-59 

1100S59 

GLPI 001-01-1 »00 

GLPltWI-OI-IMO 

GLP 1001-01-1900 

GLPI 001-01-1900 

GLPI 001-01-1900 

Tili05:s9" ~' " 

GLPI 001-01-1900 

GLPI 001-01-1900 

GLPI 001-01-1900 

GLP1&01-01-1900 

iioc&5 9 

11Q0&59 

11003-25* 

iioce^ ' 

GLPI 001-01-1 M l 

GLPI 001-01-1^01 

GLPI 001-01-1901 

GLP10Ol^)i-i9O1 " 

11005 ^ 

GLP10O1-01-1&06 

GLPI 001-01-lft07 

GLPI 001-01-IftOT 

1100& ^ 

2.5 ng/mL FC std in Synth. Water 

Method Blank 

Method Blank 

DAL GW BPMW121 RS 110713 

DAL GWTRIP1 0110713 

DALGWTRP1LS110713 

DALGWmP I MS 110713 

DALGWTRIP1HS 110713 

Method Blank 

CW.GWBPMW47 0110713 

DAL GW BPMW47 DB 110713 

DAL GW BPMW47 LIS 110713 

DAL GW B'PMW47 HS 110713 

MdhSd'BUi* " " " 

Method Blank 

1.0 ng/mL FC ctd in Synth. Water 

Method Blank"' 

DAL GW BPMW121 0 110713 

DAL GW BPMWii i DB 110713 

DALGWBPMW121 LS 110713 

DAL GW"BPMW12i"'His"'i 10713 "* 

Mtri'hod Btiink 

Method Blar* 

DAL GWiiSS'oi l 0628 

DAL GW135SDB 110628 

DAL GW135SHS 110628 

Method Blar* 

Sample Type | ^ ^ 

Unknown 

USfSwn" " 

Ur*noviin 

Unknown 

Unknown 

Ur*nown 

Unknown 

Unknown 

Standard 

Standard 

PFOA 

PFOA " " 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Standard jPFOA 

Standard :PFOA 

Standard iPFOA 

Standard jPFGA 

Standard iPFOA 

Standard iPFOA 

Standard 

'standard 

PFOA 

PFOA 

Standard iPFOA 

Sti^idiid"" "IPFtDA" ~""" ' " 

Siaritaid jPFOA 

Standard 

Standard 

Standard 

LMcnown 

PFOA 

PFOA 

PFOA 

PFOA 

Lirfinown ;PF6 A 

Unknown 

Quality Control 

Quality CarlitA' 

Qlalily'C^ ^ 

Quality Control 

Quality'Control 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Quality Contit)! IPFOA 

Quality Cortrol 'PFOA 

Quality Control 

Quality Cortrol 

Ur*nown 

lA*nown 

Quality Cortrol 

Unknown 

Quality Cortrol 

Quahty Cofird 

Quality Contml 

Quality Cortrol 

QinHTCwTrrot 

QuaGty Cortinl 

Quality Cortrol 

QuaBtyCortral 

Quality Cartn:^ 

LfcSrwvin'^ " 

Unknown 

Quality Cortrol 

Urktmm 

Unknown 

Unknown 

tA*nown 

Unknown 

Ur*nown 

Unknown 

Ur*nown 

L**nown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Cortrol 

Unknown 

Unknown 

Unknown 

Unknown 

Unk'nowri 

Unknown 

Ur*nosvn 

Unknown 

Unknown 

Unkriown 

Ur*nown 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA ~ 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA" ~ " 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA* 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

P'FOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

•PFOA^ •"" " 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Analyte PeakArea 

(count4 

4S310 

1S464 

1637376 

1626052 

1620133 

1638391 

31366 

74906 

80624 

88971 

112631 

169690 

436010 

737000 

1661714 

4341469 

7643313 

15458221 

25329480 

39149976 

67094704 

86780670 

101094007 

31704 

33646 

36789 

412430 

414795 

423595 "•" "• " "' 

3727598" " " 

3606350 

36r756S4 

31707235 J 

319450^" 

31996046 

26889 

25955 

7704481 

24852 

408715 

408813 

410789 

3558803 

3S44463 

3840625 

33487411 

35432370 

36608567 

:M56 7 

38974 

4349976 

27907 

24607 

25220 

25074 

528502 

1936289 

35362427 

31545 

611160 

626117 

1099434 

2440460 

26492 "" 

27410 

1696452 

25386' 

142264 

145496 

3923022 

3046^66"""" " ~ 

27032 

29911 

35968578 

38551791 

713527^ 

32435 

Time (min) 

15.7 

1&8 

15.7 

15.8 

15.7 

15.7 

15.8 

15.8 

15.8 

15.7 

115.8 ""' "" 

15.8 

15.8 " 

15.8 

15.8 

is:"? 

15.8 

15.8 

15.7 

15.8 

i & a 

15.8 

15.8 

15.8 

15.7" " • 

15.8 

15.8 

15.8 

15.8 

15.8 

15:8 " 

15.8 

15:8 """ 

15.8 

15.8 

15.7 

15.7 

15.7 

15.7 

15.8 

15.8 

15.8 

15.8 

15.7 

15.7 

15L7 

15.8 

15.7 

15.7 

15.8 

15.7 

15.7 

15.8 

15.8 

15.8 

i a 8 

15.8 

15.8 

15.8 

ISTB" ~~ " " 

158 

158 

158 

15 8 

15 8 

158 

158 

158 

15 8 

15 8 

15 8 

15 7 " " 

is:8 " 

15.7 

15.8 

15.7 

15.8 

15.8 

Analyte ConccRtratlon 

(ngftny 

N/A 

m 

N/A 

N/A 

N/A 

N/A 

N/A 

0.0250 

6.0300 

0.0400 

0.0500 

0.100 

0250 

0.500 

1.M 

2.50 

5.00 

10.0 

15.0 

25.0 

50.0 

75.0 

1W. 

N/A 

N/A 

N/A 

0.199 

0.199 

b:i99 

1.99 

1.99 

i'.'^ • "~i 

19.9 

19.9 

19.9 

N/A 

N/A 

5.00 

N/A 

0.199 

0.199 

0.199 

1.99 

T99 " " 

1.99 

19.9 

19.9 

19.9 

N/A 

N/A 

Z50 

N/A 

N/A * " 

N/A 

N/A 

N/A 

N/A 

N/A " • " ' 

N/A 

N/A 

N/A 

WA 

N/A 

"N/A """ 

N/A 

i.ro 

WA 

WA 

WA 

WA 

WA '"~ 

WA 

WA 

WA 

WA 

WA 

WA 

IS Peak Name 

13C8PFOA-IS 

13C8PFOA4S " 

13C8PFOA^S 

13C8PFOArlS 

13C8PF0A-<S 

13C8PF0/WS 

13C8PFbA4S 

13C8PF0ArlS 

13CaPF0A-IS 

13C8PF0A4S 

13C8PF0A-1S 

i3C8PF0/WS 

13C8PFbA4S 

13CaPF0A-IS 

13C8PF0A-IS 

13CePF0A-IS 

13C8PF0A-IS 

13C8PFOArlS 

13C8PF0A-IS 

i"3C8PFOA4S'~ 

iSCSPFOMS 

13C8PFOA-IS 

i3CBPF0A4S 

13CBPFO/V4S 

13C8PFaVIS~" 

iSCSPFOAj'S 

T3C8PFOA-IS 

i3C6PFOWS 

13CePFbA-IS 

iSCSPFOWS" 

13C8P'F6A4S 

13C8PFOA-IS 

i3C8PFOiMS 

13C8PFOA-IS 

^3C8PF6/^& 

1KMPFbA4S 

13C8PFOA4S 

13C8PFOA-K 

13C8PFOA4S 

IS PeakArea 

(counts} 

1699356 

1699010 

1474998 

1455281 

1475256 

1464774 

•i77T057 

1786156 

1639150 

1619851 

1419396 

1508101 

1389616 

1496527 

1472276 

1505817 

1588870 

1519360 

1502764 

1580609 

1547418 

14ia»0 

1341564 

1291097 

1764847 

1791213 

1789882 

1666277 

1671958 

1634847 

1665098 

1664851 

i647%2 

1593904 

1590940 

1595849 

1820622 

181 ^ 

1573011 

13C8PFOA4S ; 1825942 

T3C8PF"bArtS 

13C8PFOA4S 

13C8PFOA4S 

13C8PFOA4S 

13C8PFbA4S 

13C8PFOA4S 

^3C8PF0A4S 

T3C8P"F0A4S 

13C8PFOA4S 

13C8PFOA4S 

13C8PFOAr4S 

13CSPF0/WS 

13C8PFOA4S 

'i3C8PFOA-IS 

13C8PFOWS 

13C8PFOA4S 

13C8PFOA-IS 

13CaPF0A-IS 

i3CBPF0A-IS 

13C8PF0A-IS 

13C8PFOAJS 

13C8PFOA-IS 

13C8PF6W S 

13C8PFOA-IS 

i^SPFOAJS 

13C8PFOA-IS 

13C8PFOA-IS 

i3C6PF'OA4S 

13CSPF0A-IS 

13C8PFOA-1S 

13C8PFOA-1S 

13C8PFOA-tS 

13C8PFOA4S 

13C8PFOA-tS 

13C8PFOA-tS 

13C8PFOA-4S 

i3C8PFbA4S 

13C8PFOA-IS 

1679052 

1615078 

1611575 

1627025 

1645278 

1S34014 

1597202 

1578231 

1568495 

i'845602 

1876933 

1601502 

1910739 

1337279 

1662420 

1845379 

1834147 

1820247 

1653055 1 

1935284 

1683175 

1188796 

1700703 

1613828 

1949430 

2054986 

1520767 

2015195 

j j 560845 

1739622 

1711543 

1433413 

2349850 

j2341856 

1725937 

1727576 

1685240 

2384386 

IS Retention 

Time (min) 

15.8 

15.7 

15.7 

15.8 

15.7 

"l5.7 

15.8 

15.8 

15.8 

15.8 

15.8 

15.8 

15.8 

15.8 

is;? 

15.8 

i s ? 

15.7 

15.8 

15.8 

1S7 

15.8 

15.7 

i5.7 

15.8 

15.7 

15.8 

i5.8 

15.8 

15.8 

i"5:'7 

15.8 

i5.7 

i'i s 

15.7 

15:7 

15.7 

15.7 

15.7 

15.8 

15.7 

15.7 

15.7 

15.7 

15L7 

15.8 

15.7 

15.B 

15.8 

15.7 

15.8 

15.8 

15,8 

15.6 

15.8 

15.7 

15.8 

15.8 

15.8 

1S.8 

15.8 

15.8 

i"5:8 " " • 

15.8 

15.8 

i'sa 

15.8 

15.8 

15.8 

15:7 

15:7 

15.7 

15.8 

15.7 

15.8 

15.8 

(ng/mg 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

^:6o 

i.bb' 

i.06 

i.do 

1.00 

6.9S3 

a9S3 

0.993 

6.9sa 

0 ^ 

0.993 

0.993 

0.993 

asali"^... ..-. - -

1.00 

1.00 

1.00 

1.00 

0.993 

0.993 

0.993 

0.994 

0.994 

0.994 

0.993 

0.993 

0.993 

Too' 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.00 

1.06 

1.00 

"i.oo 

1.00 

1.00 

1.00 

1.00 

i.DO 

1.00 

1.00 

i.do 

1.00 

i.oo 

r:66"~'"' '• 

1.00 

1.00 

1.00 

i.bo 

1.00'" 

1.00 

1.00 

Use 

ReconI 

, 

CaicuUted 

Concentrallon (ng/mL) 

0.00919 

< 0 

il.OO 

11.01 

iO.993 

1.01 

0.000969 

~'~< o " 

R 

» Rl 

m 

^ ^ ^ ^ ^^ iXI 

^ m 

Ri 

^ ^ ^ 

M 

Ri 

Kl 

Rl 

Rl 

Rl 

Rl 

H 

Rl 

Rt 

1^ 

RJ 

Rl 

R 

RI 

^ __ia_. 

P3 

a, 

0.0266 

0.0305 

0.0422 

0.0532 

0.0966 

0.251 

0.444 

0.998 

Z50 

A.65 

9.66 

1S.7 

24.9 

50.5 

75.0 

99.5 

000122 

0.00197 

000359 

0.210 

0.211 

0.221 

Z03 

1.97 

Z02 

19.1 

19.3 

19.3 

< 0 

< 0 

4.53 

< 0 

0.206 

0.215 

0.217 

1.99 

Z01 

Z14 

20.2 

21.7 

22.7 

"•<b 

0.00379 

Z49 

< 0 

< 0 

< 0 

< 0 

0.249 

0.961 

20.3 

< o -1 

0.317 "^ 

0.468 

asr a 

1.37 

< 0 

< 0 

1.01 

<'o 

0,0682 

0.0614 

Z10 

20.6 

< 0 

< 0 

20.2 

21:7 "• " ' ~ -

44.3 

< 0 

*—-N^roTn' ^ 

WA 0 

WA' T B 

N/A 1 • 

WA i 0 

N/A ; 0 

N/A 1 • 

N/A t E ' ^ 

N/A • 

106. 1 • 

1QZ < 0 

1t». E 

106- I E 

96.6 E 

101. 

8a7 

99.8 

100. 

93.0 

966 

i"o5: 

99.6 

101. 

100. 

99:5 

WA 

WA 

WA n 

i'oe; 

106." 

111. 

lOZ 

98.7 

102. 

960 

96.8 

N/A 

N/A 

90.5 

N/A 

104. 

108. 

D 

m 

Q 

D 

i^ 

... ^_ _ 

n 

m 

El 

^ S 

M 

El 

n 

D 

. El 

, El 

D 

m 

m 

D 

S 

lEJ 

109. H 

107. 1 0 

10Z 

109. 

114. 

WA 

WA 

99.6 

WA 

WA 

WA 

WA 

WA 

WA " 

WA " 

WA 

WA 

WA 

WA 

N/A" 

N/A 

N/A 

101. 

WA 

WA 

WA 

WA 

WA 

WA 

WA 

WA 

WA 

WA 

WA 

B 

IS] 

^ ^ Acquldtlon Date 

0.0267 17/28/2011 1000:05 AM 

0.0109 !7/2a«01110;21:10AM 

1.11 j7/28ra)11ia4Z14AM 

1.12 |7/28/2011 ll:03:24/VM 

1.10 j7/28raMl 11:24:29AM 

1.12 :7/28«011 11:45:32AM 

"0.0177 

b:6i43~ 

00457 

7/280D1 H Z 06:36 PM 

7/2SO0111227:43 PM 

7/280011 1248:48 PM 

0.0499 17/28/2011 1:09:59PM 

b:b627";7fi!8i20lTi:3f:06>M" 

00747 7/28001 l"l:5Z 11 PM 

0122 j7/2ara011213:15 PM 

0.291 ;7/2ara011234:19 PM 

O501 i7/28OT11 255:24 PM 

1.10 [7/2an0113;16:32PM 

Z73 :7/28«011 3:37:37 PM 

5.03 i7/2a«011 3:58:42 PM 

103 

T6:4~~' 

7/28O0114; 19:48 PM 

7/28O0fl"4^:55 PM~ 

iiS.'3 7/28Q0li5:bi:59PM 

47.4 

64.7 

78.3 

OTbiBO"" 

acii'BB"' 

'0.0206" 

"O-iMiB 

0.248 

6:259~~ 

Z24' 

Z17" 

f z a 

7/280011 5:23:03 PM 

7/28O011 5:44:10 PM 

7/280011 605:15 PM 

7/2BO0lT6:26"i"9Pfc^ 

7/28O0116:47:24 PM 

708001 l'7:0e:28"'PM 

7OBO011 7:29:32 PM 

7/28Obl"f7:SO.40P"M" 

7wnsnV&: 1 i:47 P M " 

7/280011 8:3254 PM 

7I2B^20^^ 8:54*00 PM " 

7/2BO011 9:15:07 PM 

19.9 i7/28raH1 9:36:14 PM 

20.1 • 

'2b.i ••" 

7/280011 9:57:23 PM 

7/280D11 10.18:28 PM 

0.0148 ;7/28ra)11 1039:32 PM 

0.01« !7/28rabl1 11:00:40 PM" 

4.90 |7/28raMl 11:21:47 PM 

0.0136 i7/2ara011 11:4256 PM 

0.243 ;7/2fi!011 1204:08 AM 

0.253 7/29/2011 1225:16AM 

a 2 K |7/29ra011 1246:26 AM 

Z19 t7/29ra011 1:07:32AM 

Z22" 7/29«bil 1:28:37/W' 

Z35 i7/29«)11 1:49:43 AM 

21.0 |7/29Q011210:50AM 

2Z5 ,7/290011 Z31:5SAM 

^ E ^23.3 i7/29OT11Z53;01AM 

• ;b.bi66 ,7/2900113:14:lbAM 

^ Q 

m 

a 

^ H 

H 

n D 

Bl 

1 

^ m 

e 

^ El 

i^EI 

El 

El 

i^ia 

El 

1^ 

r H 

D 

L - H 

El 

El 

^ f a 

El 

0.0208 17/29O0113:35:23 AM 

Z72 7/290011 3:56:27 AM 

0.0146 

"0.0127"' 

7/29O011 4:17:36 AM 

7/29O0114:38:44 AM 

0.0152 j7/29i20114:59:49 AM 

0.0136 17/290011 5:20:58 AM 

0.288 j7/29O0115:4Z04AM 

^ -

7/29^)11 6:03:11AM 

7/29/2011 624:21 AM 

0.0163 ;7/2af2bli 6:45:29AM 

0.363 

0.527 

'0646 

1.51 

00136 

0.0133 

1.12 

00126 

00911 

0.08^ 

Z29 

7/29O0117:06:35/kM 

7/2af20117:27:43/kM 

7/SObl'i7:48:55'AM 

7/290011 8:10762/yi-i 

7/290bli8:3i:i2'AM 

7/29O011 8:5223 AM 

7/29/2011 9:13:29 AM 

7/290bii"9:'34':38'A"M"" 

7/2900119:55:45 AM 

7/29O011 1tt16:5SAM 

7/29/2011 1038:XAM 

21.3 17090011 1tt5906AM 

b.bi i s 'jtTarxn i i i :'2o: ie A M 

0.0128 

"20.8 

2Z3 

42.3 

0.0136 

7/29O011 11:41:27 AM 

7/29O011 120236 PM 

7/29/2011 1223:44 PM 

7/SObii'1244:50 PM 

7090011 1:05:57 PM 
o n : ETSKIRK 

; Sampte NanM i Sample ID Sample Comment 

Method Blartc 

10 r^mL FC std in Syrlh. V 

Analyte Peak Analyte PeakArea J^nalyte Retention 

Unknown 

bi^ y Cortrol 

PFOA 

PFbA" 

Analyte Concentration IS Retention 

Time |mln) 

IS Concentration 

(ng/mL) 

Use Calculated 

Record | Concentration (ng/ml4 ' AcquidUon Date 

13CePF0A-tS 

i:^8PFbA4S" 

T3C8PFbA4S~ S60416" 

0.0136 17090011 1:27:06 PM 

"ToTe" l7raooiTiy48ii6yM" 

'0.009«l7O9O011 209:26 PM""