# Acop y o f

th eChai no f Custody canb efoun din LABWARELIM S

Acop y o f th eGP O and/o r Protoco lcanb efoun dinth e Lotu s Note s GP O Databas e

Communication s Misc

.

## Westo nSolutions , Inc

. 140 0 Westo n Wa y P.O

. Bo x265 3 Westchester , Pennsylvani a 1938 0 610-701-300 0 •Fa

x610-701-318 6 ® www.westonsolutlons.co m 

# Th e Truste d Integrato rfo rSustainabl e Solution s



# Augus t 31,201 1

Dr

. Clesto nLang e 3 M EnvironmentalLaboratory 3 M Center Buildin g 260-5N-1 7 St

. Paul , M N55144-100 0

Dea r Dr

. Lange :

Per your request , 1 amreturnin g herewithGL P10-01-0 1 Interi mReport 18

. Th e appropriatepage s hav ebee nsigne dan dareinclude dwiththi s transmittal

. Shoul dyouhav ean y questions , pleas ed o no t hesitatet o contac t

m eat 610-701-3761

. Very trul y yours , WEST/2( NSOLUTIONS , INC

.

Jaisimh aKesari , P.E. , DE E PrincipalProjec t

Manage r

Enclosure

a n employee-owne d compan yS S

M:\FOLDERS.0-9\3M-DECAT\Lange-6 3 (Interi mRp t 1 8 Audit).doc x

# Pag e1 of4

RE : FW : Quarterl y G

Wsamplin g - Decatur

Former Sludg eIncorporatio nAre aWell s Frinak , Timothy R

. to : 

# Young , Charle s T. , stwolf@mmm.co m 07/14/201 1 07:4 6 P M Hid eDetail s From : "Frinak , Timoth y R. " <T.Frinak(^WestonSolutions.com >

To : "Young , Charle s T. " <Charles.Young@WestonSolutions.com> , "stwolf@mmm.com " <stwolf@mmm

. com >

5 Attachment s



# m

\ imageOOLjp

g image002.gi

f image003.gi

f image004.pn

g imageOOS.pn

g

Sue , I tshoul d b e reference d a s 144S

. I n th e origina l wor k plan , i twa s propose d a s a n R well , meaning i twoul d b e complete d withi n th e soi l horizon

. However , upo n drillin g th e locatio n i twa s determine d tha tther e wa s n o wate ri n thi s zone , s o i twa s extende d int o th e epikars tzon e a s a n S well

.

Pleas e le tm e kno wi fyo u have an yothe rquestions

.

Ti m

Timoth y R

. Frinak , P

. G

. WestonSolutions , Inc

. 162 5 Piimphrey Avenu

e Auburn , A L3683 2 Ph : 334-466-565 3 Fx : 334-466-566 0 CI: 334-332-912 3



# From : Young , Charle s T

. Sent : Thursday , Jul y14 , 2011 12:1 7 PM



# file://C:\Users\US263070\Ar)DData\Local\TemD\notes256C 9 A\~web6824.htm7/15/201 1

# Pag e2 of4

To : Frinak , Timoth yR

. Subject : RE : FW : Quarterl yGWsamplin g - Decatu rForme rSludg e Incorporatio n Are a Well s

Tim : Ca n yo u respon d t o thi s an d cc : me ?

The yar e probabl yalread ylogge d int o thei rLIM S a s 144 8 i ftha ti s wha tth e Co C an d label s had

. Thanks , Charli e 

# Charle s T

. Youn g Technica lDirecto r

Westo nSolutions , Inc

. 140 0 Westo nWay (5-2 ) Wes t Chester , P

A1938 0 (610)701-378 7 P'§?J61.0)J701^-340 1

_ _^ , . _. . From : stwolf@mmm.co m rmailto:stwolf(ia)mmm.com 1 Sent : Thursday , Jul y14 , 201 1 12:5 3 PM To : Young , Charle s T

. Cc : Frinak , Timoth yR

. Subject : Re : FW : Quarterl yGWsamplin g - Decatu rForme rSludg e Incorporatio n Are a Well s

Hi , Whil e labelin g th e sample s receive d las tweek , w e notice d tha tsamplin g locatio n 14 4 wa s identifie d a s 144 S o n th e Co C form , bu twa s liste d a s 144 R i n th e attache d tabl e provide d wit h i n th e origina l bottl e orde rrequest

. Pleas e confir m i fi tshoul d b e identifie d a s 144 S o r144R

.

O n ^ ^Stm^ ^ ktmx i fivt%:« * 

# m u6 ^ m ^ m.....um ^

£>M

. MI S i K

lia/j ^ ITT *



# IM±.

.

(Seeattache dfile: Quarterl y GWMonito r ing

. doc )

Thanks , Su e



# 3 M

Susa n T

. Wol f| Environmenta l La b 3 M EH S Operation s 3 M Center , 260-5N-1 7 | St

. Paul , M N 55144-100 0 Office : 65 1 73 3 985 1 | Triminet : 73 3 985 1 stwolf@nnmm.co m | www.3M.co m (3 M Interna l We b site ) www.3M.com/sustainabilit v



# file://C:\Users\US263070\AppData\Local\Temp\notes256C9A\~web6824.htm 7/15/201 1

# Pag e3 of4

Thi s communicatio n i s intende d onl yfo rth e addressee(s ) name d above

. I tcontain s confidentia l information

. Unauthorize d use , disclosure , disseminatio n o rcopyin g o fthi s communication , o ran y par tthereof , i s strictl yprohibited

. I fth e reade ro fthi s messag e i s no tth e intende d recipien tpleas e notif yu s immediatel yb ytelephon e o relectroni cmai l an d delet e o rdestro ythi s messag e an d al l copie s thereof , includin g attachments

. "Young , Charle s T. " —07/08/201 1 08:15:5 1 AM—Sue : Yo u shoul d se e th e FSI AG Wsample s today

. Tw o well s wer e dr ya s describe d i n Martin' s emai l be l

From : "Young , Charle s T. " <Charles.Young@WestonSolutions.com > To : "stwolf@mmm.com " <stwolf@mmm.com > Cc : "Frinak , Timoth yR. " <T.Frinak@WestonSolutions.com > Date : 07/08/201 1 08:1 5 A M SLibJect : FW : Quarterl yG Wsamplin g - Decatu rFomne rSludg e Incorporatio n Are a Well s



# Sue :

Yo u shoul d se e th e FSI AG Wsample s today

. Tw o wells wer e dr ya s describe d i n Martin' s emai l below

. Charli e



# Charle s T

. Youn g Technica lDirecto r

Westo nSolutions , Inc

. 140 0 Westo nWa y (5-2 ) Wes t Chester , P

A1938 0 (610 ) 701-378 7 Fa x(610 ) 701-340 1 From : Smith , Marti n Sent : Thursday , Jul y07 , 201 1 4:3 6 PM To : Young , Charle s T

. Cc : Frinak , Timoth yR

. Subject : RE : Quarterl yGWsamplin g - Decatu rForme rSludg e Incorporatio n Are a Well s

Th e la b shoul d receiv e th e sample s tomorro wvi a FedEx

. I twil l b e thre e coolers , tw o wit h sample s an d on e wit h empt ybottles

. Well s 136 R an d 137 R wer e dr yan d wer e no tsampled , thes e ar e th e empt ybottle s i n th e thir d cooler

. Not e tha t4 tri p blan k

set s wer e requeste d bu tonl ytw o wer e sent

. W e ha d t o bu ya bigge rcoole ri n orde rt o shi p i n onl ytw o coolers

. Marti n

From : Young , Charle s T

. Sent : Monday , Jun e 13 , 201 1 2:1 4 PM To : stwolf@mmm.co m Cc : Frinak , Timoth yR. ; Smith , Marti n Subject : Quarterl yGWsamplin g - Decatu rForme rSludg e Incorporatio n Are a Well s Sue :

WESTO N wil l b e performin g quarterl ygroundwate rsamplin g o fth e forme rsludg e incorporatio n are a (FSIA ) well s beginnin g o n Jun e 20 , 2011

. Th e attache d wor d documen tshow s th e FSI Awell s (highlighte d i n yellow ) tha twil l



# file://C:\Users\US263070\AppData\Local\Temp\notes256C9A\~web6824.htm7/15/201 1

# Pag e4 of4

b e sample d fo rfluorochemlca l analyses.unde rGL P 10-01-0 1 an d GL P 10-01-02

. I tals o show s samplin g schedul e fo rothe rquarterl ysamplin g (an d conventional parameters )

Als o attache d i s a spreadshee tsummar ytabl e fro m th e mos trecen t(Nov-2010 ) roun d a tth e FSI Awells

. I n additio n t o th e primary/duplicate/spik e bottles , w e wil l nee d bottle s an d Milli- Q wate rfo rth e tw o equipmen t rinseat e blank s tha twil l b e collected

. Thanks , Charli e



# Charle s T

. Youn g Technica lDirecto r

Westo nSolutions , Inc

. 140 0 Westo nWa y (5-2 ) Wes t Chester , P

A1938 0 (610 ) 701-378 7 Fa x(610 ) 701-340 1



# CONFIDENTIALITY : Thi s emai lan dattachment s may contai ninformatio nwhic hi s confidentialan d proprietary

. Disclosur eo r us eo f any suc hconfidentialo r

proprietary informatio nwithou t th ewritte n permissio no f

Westo nSolutions , Inc

. i s strictl y prohibited

. I f yo ureceive dthi s emai linerror , pleas e notif y th esender

b y returne-mai lan ddelet ethi s emai lfromyou r system

. Thank

you

.

CONFIDENTIALITY: Thi s emai lan dattachment s may contai ninformatio nwhic hi s confidentialan d proprietary

. Disclosur eo r us eo f any suc hconfidentialo r

proprietary informatio nwithou t th ewritte n permissio no f

Westo nSolutions , Inc

. i s strictl y prohibited

. I f yo ureceive dthi s emai linerror , pleas e notif y th esende r

b y returne-mai lan ddelet ethi s emai lfromyou r system

. Than k

you

.

file://C:\Users\US263070\AppData\Local\Temp\notes256C 9 A\~web6824.htm7/15/201 1

# 3 M ENVIRONMENTA LLABORATOR Y



# Not et o Fil e
Projec t o r Stud y Number : LIM S Number : Affecte dData : GLPlO-01-01-1 8

GLPlO-01-01-1 8

Non e

Al l logboo k

page s fo rth e individua l stoc k standard s an d mixe s use d fo rth e calibratio n curve s an d LC S use d fo rth e analysi s o fGLP10-01-01-1 8 wer e printe d t o pd f(exactcopie s o foriginals ) an d include d i n a folde rlabele d 'Logboo k page s use d fo rGLPlO-01-01-18 ' locate d i n th e project folde rlocate d at : \\Winsnas01a\b2\Projects\Lab_ES AAnalytical\La b Request s 2011 -stw\GLP10-0 1 Decatu r Phas e 3\GLP10-01-0 1 PF0A\GLP10-01-01-1 8 FSI AGW-Jun e 2011

Th e chromatogram s fo rresult s fil e k l 10715 a an d k l 10728 a wer e printe d t o pd fan d save d i n th e projectfolde rlocate d at : \\Winsnas01a\b2\Projects\Lab_ES AAnalytical\La b Request s 2011 -stw\GLP10-0 1 Decatu r Phas e 3\GLP10-01-0 1 PF0A\GLP10-01-01-1 8 FSI AGW-Jun e 2011

Apd fcop yo fth e signe d protoco l amendmen tGLPIO-OI-O I Amendmen t1 8 i s locate d i n th e projectfolde rlocate d at : \\Winsnas01a\b2\Projects\Lab_ES AAnalytical\La b Request s 2011 -stw\GLP10-0 1 Decatu r Phas e 3\GLP10-01-0 1 PF0A\GLP10-01-01-1 8 FSI AGW-Jun e 2011

Onc e th e dat a packag e ha s bee n reviewe d byQ Aan d th e reportsigned , th e pd fwil l b e move d t o th e share d driv e (\\Winsnas01a\b2\Projects\Lab_Shared\Archiv e Requests\Electroni cReports ) an d a referenc e t o th e locatio n o fth e pd fwil l b e adde d t o th e archive d reques tfor m unde rEle c Medi a Path

.



# Recorde dBy : Date :

Pag e1 o f 1

# Standar dPre p

Sampl ePre p Collectio nBottl ePre p

# Not eT o Fil e

Projec t o r Stud y Description : LIM S Number : Affecte dData : Decatu r Phas e3 - FSI Agroundwate r

GLPlO-01-01-1 8 Non e

On e hundre d sixty-fou r25 0 m LNalgen e bottle s were marke d wit h a 20 0 m Lleve l lin e an d labeled

. Th e followin g tri p blanks/spike s wer e fille d wit h Mill i Q wate r(TN11-0208 ) an d seale d afte rtheywer e spiked

. Tw o bottle s wil l b e provide d t o b e use d a s equipmen trinseat e blanks , alon g wit h 1- Lo fMill i Q Wate r(TN11

- 0208)

. O n 6/15/11 , th e fiel d matri xspike bottle s were spike d wit h th e following :

Interna l Standard wil l b e adde d t o th e followin g sampl e sets : 134S , 135S , 136R , 137R , 137S , 137L , 138L , Tri p Blan k sampl e 1 an d 2 , Tri p Blanks LS 1 an d 2 , an d equipmen trinseat e blanks

. Intema l Standards : Sampl e bottle s (250-mL ) wil l b e spike d wit h th e following :

Bottl e descriptio n Spik e Descriptio n Spik e Leve l Spikin g Solutio n I D Gone , o f

Spikin g solutio n Volum e o f

spikin g solutio n (ML ) Se e abov e I S - Acids , Sulfonates , PFOS A 1. 0 ng/m L 1 0 006-12 9 2. 0 MQ/m l 10 0



# Fiel d Matri xSpike s

Wel l No

.

134S,135S , 136R , 137R,137S , 137Land138 L

130L , 131S , 131L , 133R , 135L , 136S , 136L , 141R , 142R , 143 R an d 144 R

130R , 130S , 133S , 133L , 134L , 138R , 138S , CW26C , CW26 Lan d 140 R

131R , 134Rand135 R

Tri p Blan k

Set s 1 an d 2 Sampl e Leve l

Lo w Mi d Hig h Lo w Mi d Hig h Lo w Mi d Hig h Lo w Hig h Lo w Mi d Mid-Hig h Hig h Spikin g

Solutio n

1 0 006-14 1 1 0 006-14 1 1 0 006-14 1 1 0 006-14 1 1 0 006-14 1 1 0 006-14 0 1 0 006-14 1 1 0 006-14 0 1 0 006-14 0 1 0 006-14 0 1 0 006-13 9 1 0 006-14 1 1 0 006-14 1 1 0 006-14 0 1 0 006-14 0 Approx

.

Valu e (jjg/mL )



## 2. 0 2. 0 2. 0 2. 0 2. 0 10 0 2. 0 10 0 10 0 10 0 50 0 2. 0 2. 0 10 0 10 0 Spik e

Amoun t (ML )

1 0 10 0 100 0 10 0 100 0 20 0 100 0 20 0 100 0 20 0 80 0 10 0 100 0 20 0 100 0 Spik e

Cone

. (ng/mL )

0. 1 1. 0 1 0 1 1 0 10 0 1 0 10 0 50 0 10 0 200 0 1 1 0 10 0 50 0



# UsedEppendor

f Researchpipette s 340227 7 and207712 7 to addspiking solutionto samples

.



# Recorde dBy : Date :

### Printin g 7/14/2011 ; 3:5 6 P M

6LP10-01-01-1 8 Sampl e Pre p Wor k Sheet ; ETS-8-04 4 datej7/14/1/ 1 

# rv<^(^ns^/ ^ i t ^ - ^ Sampl e I D ' LCS-110714- 1 LCS-110714- 2 LCS-110714- 3 LCS-110714- 4 LCS-110714- 5 LCS-110714- 6 LCS-110714- 7 LCS-110714- 8 LCS-110714- 9 LCS-110714-1 0 LCS-110714-1 1 LCS-110714-1 2 LCS-110714-1 3 LCS-110714-1 4 LCS-110714-1 5 LCS-110714-1 6 LCS-110714-1 7 LCS-110714-1 8 Analyst : CJ G Sampl e Descriptio n O.Sppb LC S O.Sppb LC S O.Spp b LC S 5pp b LC S 5pp b LC S 5pp b LC S 30pp b LC S 30pp b LC S 30pp b LC S 0.5pp b LC S EC F 0.5pp b LC S EC F 0.5pp b LC S EC F 5pp b LC S EC F 5pp b LC S EC F 5pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F Spii(in g st d I D 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 6 1 0 006-14 6 1 0 006-14 6 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 1 005-4 7 1 1 005-4 7 1 1 005-4 7 1 1 005-4 6 1 1 005-4 6 1 1 005-4 6 1 0 006-15 2 1 0 006-15 2 1 0 006-15 2 Spik e Am t(pL ) 5 0 5 0 5 0 5 0 5 0 5 0 3 0 3 0 3 0 5 0 5 0 5 0 2 5 2 5 2 5 3 0 3 0 3 0 La b wate r(mL )

1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0

7/14/1 1 CJG ; LC S an d Solven tBlanks prepare d wit h Mill i Q Wate r(TN11-0234) , vorte xmixed , an d aliquote d int o 2-m Lglas s autovials

.



# 1 1 7/14/1 1 CJG ; 1 seto faliquot s o f11003-2 6 curv e w^a s transten'e d int o 2-m Lglas s autovial s 

# 1 1 Tota l Volum e (mL ) 10.0 5 10.0 5 10.0 5 10.0 5 10.0 5 10.0 5 10.0 3 10.0 3 10.0 3 10.0 5 10.0 5 10.0 5 10.02 5 10.02 5 10.02 5 10.0 3 10.0 3 10.0 3

7/14/1 1 CJG ; Sample s GLPlO-01-01-1 8 requirin g 1:1 0 dilutio n wer e prepare d bytakin g 1 m Lo fsampl e an d addin g 9 m Lo fMill i Q Elemen tWate r(TN11-0234) , mixe d , an d the n aliquote d int o 2-m Lglas s autovials

. 7/14/1 1 CJG ; Sample s GLPlO-01-01-1 8 requirin g 1:10 0 dilutio n wer e prepare d bytakin g 0. 1 m Lo fsampl e an d addin g 9. 9 m Lo fMill i Q Elemen tWate r(TN11-0234) , mixe d , an d the n aliquote d int o 2-m Lglas s autovials

. 7/14/1 1 CJG ; Sample s GLPlO-01-01-1 8 no trequirin g dilutio n wer e aliquote d int o a 2-m Lglas s autovia l



# 1 7/14/1 1 CJG ; Pipette s used : 3402277 , 207712 7

/'"^'" ^ r ^ 

# CL^?{e. e \ ^ 

# "T V

1 1 

# -r\-H-AcVie d Mafe>e\'

\ ^ 1 J-

- ^

f^ ' 

# I P r\i\uric> n \~nrfi\

^ 9^e: tO^

r-f h 1 ^ 1 J 

# ' i ^ \\^ M \r

y •, r v 

# ^ St'^ f
^ y+ -r? ) t ^ ,, 

# ^vDpie..^ ; rao^Lur i OP s<^rn'i" ' , .



# n a cm\\ j M

. A fOr^rXW T

' 

# o n tlori



# hrt ^ •n- « 1 

# KFJil l

ETS-8-04 4 sampl e pre p 110714.xl s 

# C3'6~7jlM/ l Pag e 1 o f1

### Cun/e Point s an d LCS ; Metho d ETS-8-04 4

Concentratio n - ug/m L Stoc k I D 1 0 006-14 7

1 0 006-14 6 1 0 006-14 5 1 0 006-13 0 1 0 006-13 1 1 1 005-4 6 1 1 005-4 7 1 0 006-15 2 PFO A 0.100 0 1.00 0 10.0 0 10 0

2.0 0 0.10 0 10. 0 PFB S

0.100 0 1.00 0 10.0 0

10 0



# - PFH S

0.10 0 1.0 0 10. 0

10 0



# - PFO S

0.100 0 1.00 0 10.0 0

10 0 1.9 9 0.099 5 9.9 5

11003-26- 1 0.02 5 ng/m LF C st d i n Mill i Q Wate r 11003-26- 2 0.0 3 ng/m LF C st d i n Mill i Q Wate r 11003-26- 3 0.0 4 ng/m LF C st d i n Mill i Q Wate r 11003-26- 4 0.0 5 ng/m LF C st d i n Mill i Q Wate r 11003-26- 5 0. 1 ng/m LF C st d i n Mill i Q Wate r 11003-26- 6 0.2 5 ng/m LF C st d i n Mill i Q Wate r 11003-26- 7 0. 5 ng/m LF C st d i n Mill i Q Wate r 11003-26- 8 1. 0 ng/m LF C st d i n Mill i Q Wate r 11003-26- 9 2. 5 ng/m LF C st d i n Mill i Q Wate r 11003-26-1 0 5. 0 ng/m LF C st d i n Mill i Q Wate r 11003-26-1 1 1 0 ng/m LF C st d i n Mill i Q Wate r 11003-26-1 2 2 5 ng/m LF C st d i n Mill i Q Wate r 11003-26-1 3 5 0 ng/m LF C st d i n Mill i Q Wate r 11003-26-1 4 7 5 ng/m LF C st d i n Mill i Q Wate r 11003-26-1 5 10 0 ng/m LF C st d i n Mill i Q Wate r

LCS-110714- 1 O.Spp b LC S LCS-110714- 2 O.Spp b LC S LCS-110714- 3 O.Spp b LC S LCS-110714- 4 SppbLC S LCS-110714- 5 SppbLC S LCS-110714- 6 SppbLC S LCS-110714- 7 30ppbLC S LCS-110714- 8 30ppbLC S LCS-110714- 9 30ppbLC S LCS-110714-1 0 O.Spp b LC S EC F LCS-110714-1 1 O.Spp b LC S EC F LCS-110714-1 2 O.Spp b LC S EC F LCS-110714-1 3 SppbLCSEC F LCS-110714-1 4 SppbLCSEC F LCS-110714-1 S SppbLCSEC F LCS-110714-1 6 30pp b LC S EC F LCS-110714-1 7 aOpp b LC S EC F LCS-110714-1 8 30pp b LC S EC F 

### PFO A 0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 25. 0 50. 0 75. 0 10 0
0.49 8 0.49 8 0.49 8 4.9 8 4.9 8 4.9 8 29. 9 29. 9 29. 9 0.49 8 0.49 8 0.49 8 4.9 9 4.9 9 4.9 9 29. 9 29. 9 29. 9 PFB S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 25. 0 50. 0 75. 0 10 0 PFH S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 25. 0 50. 0 75. 0 10 0

0.49 8 0.49 8 0.49 8 4.9 8 4.9 8 4.9 8 29. 9 29. 9 29. 9



# - 0.49 8

0.49 8 0.49 8 4.9 8 4.9 8 4.9 8 29. 9 29. 9 29. 9



# - PFO S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 25. 0 50. 0 75. 0 10 0
0.49 8 0.49 8 0.49 8 4.9 8 4.9 8 4.9 8 29. 9 29. 9 29. 9 0.49 5 0.49 5 0.49 5 4.9 6 4.9 6 4.9 6 29. 8 29. 8 29. 8 Stoc k

I D 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 6 1 0 006-14 6 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5

1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 6 1 0 006-14 6 1 0 006-14 6 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 11005-4 7 11005-4 7 1 1 005-4 7 1 1 005-4 6 1 1 005-4 6 1 1 005-4 6 1 0 006-15 2 1 0 006-15 2 1 0 006-15 2 Spik e

Volum e (uL ) 2 5 3 0 4 0 5 0 10 0 25 0 5 0 10 0 2 5 5 0 10 0 25 0 50 0 75 0 100 0

5 0 5 0 5 0 5 0 5 0 5 0 3 0 3 0 3 0 5 0 5 0 5 0 2 5 2 5 2 5 3 0 3 0 3 0 Fina l

Volum e (mL ) 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0

10.0 5 10.0 5 10.0 5 10.0 5 10.0 5 10.0 5 10.0 3 10.0 3 10.0 3 10.0 5 10.0 5 10.0 5 10.02 5 10.02 5 10.02 5 10.0 3 10.0 3 10.0 3

ETS-8-04 4 sampl e pre p 110714.xl s Calibratio n Curv e Pag e 1 o f1

### Sampl e I d Descriptio n Pre p Dat e

LCS-110714- 1 O.Spp b LC S Prepared : 7 LCS-110714- 2 O.Spp b LC S Prepared : 7 / LCS-110714- 3 O.Spp b LC S Prepared : 7J LCS-110714- 4 SppbLC S Prepared : 7 i LCS-110714- 5 SppbLC S Prepared : 7 ; LCS-110714- 6 SppbLC S Prepared : 7 ; LCS-110714- 7 SOppbLC S Prepared : 7 ; LCS-110714- 8 SOppbLC S Prepared : 7 / LCS-110714- 9 30ppbLC S Prepared : 7 / LCS-110714-1 0 O.Spp b LC S EC F Prepared : 7J LCS-110714-1 1 O.Spp b LC S EC F Prepared : 7 i LCS-110714-1 2 O.Spp b LC S EC F Prepared : 7 i LCS-110714-1 3 SppbLCSEC F Prepared : 7 ; LCS-110714-1 4 SppbLCSEC F Prepared : 7 i LCS-110714-1 5 SppbLCSEC F Prepared : 7 i LCS-110714-1 6 30ppbLCSEC F Prepared : 7 i LCS-110714-1 7 30ppbLCSEC F Prepared : 7 i LCS-110714-1 8 30ppbLCSEC F Prepared : 7 /

GLP10-01-01-18-00 5 Tri p BlankSet2HS(di l 1:100 ) Prepared : 7 ; GLP10-01-01-18-00 6 DA LGW130 R 0 11063 0 (dil l :100 ) Prepared : 7 , GLP10-01-01-18-00 7 DA LGW130RD B 11063 0 (di l 1:100 ) Prepared : 7 ; GLP10-0 1 -0 1 -18-00 8 DA LG W130 R L S 11063 0 (di l 1:100 ) Prepared : 7 ; GLP10-01-01-18-00 9 DA LGW130 R M S 11063 0 (di l 1:100 ) Prepared : 7 ; GLP10-01-01-18-01 0 DA LGW130RH S 11063 0 (dill : 100 ) Prepared : 7 , GLP10-01-01-18-01 1 DA LGW130 S 0 11063 0 (dil l :10 ) Prepared : 7 , GLP10-01-01-18-01 2 DA LGW130 S 0 11063 0 (di l 1:10 ) Prepared : 7 ; GLP10-01-01-18-01 3 DA LGW130SL S 11063 0 (di l 1:100 ) Prepared : 7 , GLP10-01-01-18-01 4 DA LGW130 S M S 11063 0 (di l 1:100 ) Prepared : 7 , GLP10-01-01-18-01 5 DA LGW130SH S 11063 0 (dill : 100 ) Prepared : 7 i GLP10-01-01-18-01 6 DA LGW130 L0 11063 0 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-01 7 DA LGW130LD B 11063 0 (di l 1:10 ) Prepared : 7 i GLP10-01-01-18-01 8 DA LGW130LL S 11063 0 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-01 9 DA LGW130 LM S 11063 0 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-02 0 DA LGW130LH S 11063 0 (di l 1:10 ) Prepared : 7 i GLP10-01-01-18-02 1 DA LGW131 R 0 11062 2 (di l 1:100 ) Prepared : 7 , GLP10-01-01-18-02 2 DA LG W131 R D B 11062 2 (di l 1:100 ) Prepared : 7 , GLP10-01-01-18-02 3 DA LG W131 R L S 11062 2 (di l 1:100 ) Prepared : 7 , GLP10-01-01-18-02 4 DA LG W131 R H S 11062 2 (di l 1:100 ) Prepared : 7 , GLP10-01-01-18-02 5 DA LG W131 S 0 11062 2 (diM:10 ) Prepared : 7 , GLP10-01-01-18-02 6 DA LG W131 S D B 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-02 7 DA LG W131 S L S 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-02 8 DALG W131 S M S 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-02 9 DA LG W131 S H S 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 0 DA LGW131 L0 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 1 DALG W131LD B 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 2 DA LG W131 LL S 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 3 DA LG W131 LM S 11062 2 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 4 DA LG W131 LH S 11062 2 (di l 1:10 ) Prepared : 7 ; GLP10-01-01-18-03 S DA LGW133 L0 11063 0 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 6 DA LG W133 LD B 11063 0 (dill : 10 ) Prepared : 7 , GLP10-01-01-18-03 7 DA LG W133 LL S 11063 0 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-03 8 DA LG W133 LM S 11063 0 (di l 1:10 ) Prepared : 7J GLP10-01-01-18-03 9 DA LG W133 LH S 11063 0 (di l 1:10 ) Prepared : 7J GLP10-01-01-18-04 0 DALG W133 8 0 11063 0 (di l 1:10 ) Prepared : 7J GLP10-01-01-18-04 1 DA LGW133SD B 11063 0 (di l 1:10 ) Prepared : 7 , GLP10-01-01-18-04 2 DA LG W133 S L S 11063 0 (di l 1:10 ) Prepared : 7j GLP10-01-01-18-04 3 DA LG W133 8 M S 11063 0 (di l 1:10 ) Prepared : 7 i GLP10-01-01-18-04 4 DA LG W133 8 H S 11063 0 (di l 1:10 ) Prepared : 7 ; GLP10-01-01-18-04 S DA LGW133 R 0 11063 0 (di l 1:10 ) Prepared : 7 ; GLP10-01-01-18-04 6 DA LG W133 R D B 11063 0 (dill : 10 ) Prepared : 7 i GLP10-0 1 -0 1 -18-04 7 DA LG W133 R L S 11063 0 (dill : 10 ) Prepared : 7j GLP10-01-01-18-04 8 DA LG W133 R M S 11063 0 (di l 1:10 ) Prepared : 7 ; GLP10-01-01-18-04 9 DA LG W133 R H S 11063 0 (di l 1:10 ) Prepared : 7J GLP10-0 1 -0 1 -18-OS O DA LG W134 R 0 11062 8 (dill : 100 ) Prepared : 7 i GLP10-01-01-18-05 1 DA LGW134RD B 11062 8 (di l 1:100 ) Prepared : 7J GLP10-01-01-18-05 2 DA LG W134 R L S 11062 8 (di l 1:100 ) Prepared : 7 / GLP10-0 1 -0 1 -18-05 3 DA LG W134 R H S 11062 8 (di l 1:100 ) Prepared : 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G

14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G 14/1 1 CJ G toxic ,

toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic ,
toxi c toxic , toxic , toxi c toxic , toxi c toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxi c toxic , toxic , toxi c toxic , toxic , toxic , toxi c toxic , toxic , toxi c toxic , toxi c toxi c toxi c toxi c toxi c toxi c toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic

. Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e

ETS-8-04 4 sampl e pre p 110714.xl s labe l Pag e 1 o f2

### Sampl e I d Descriptio n Pre p Dat e

GLP10-01-01-18-0S 4 DA LGW134 L0 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-0S 5 DA LGW134LD B 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-05 6 DA LG W134 LL S 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-0S 7 DA LGW134 LM S 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-05 8 DA LG W134 LH S 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-06 8 Tri p Blan k Se t1 H S (di l 1:100 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-07 4 DA LG W135 L0 11062 8 (di l 1 ; 10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-07 S DA LGW135LD B 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-07 6 DA LG W135 LL S 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-07 7 DA LG W135 LM S 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-07 8 DA LG W135 LH S 11062 8 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-07 9 DA LG W13SR 0 11062 8 (di l 1:100 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 0 DA LGW135RD B 11062 8 (di l 1:100 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 1 DA LGW135RL S 11062 8 (di l 1:100 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 3 DA LG W13S R H 8 11062 8 (di l 1:100 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 4 DA LG W136 L0 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 S DA LGW136LD B 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 6 DA LG W136 LL S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-1S S DA LGW136 LM S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 7 DA LG W136 LH S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 8 DA LG W136 8 0 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-08 9 DA LG W136 8 D B 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-09 0 DALG W136 8 L 8 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-09 1 DALG W136 8 M S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-09 2 DA LG W136 8 H 8 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-10 3 DA LGW138 R 0 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-10 4 DA LGW138RD B 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18- 1 O

S DA LGW138RL S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-10 6 DA LGW138 R M S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-10 7 DALG W138RH S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 3 DA LGW138 S 0 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 4 DA LGW138SD B 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 5 DA LG W138 8 L S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 6 DA LGW138 S M S 11063 0 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 7 DA LG W138 8 H S 11063 0 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 8 DA LGWCW26 C 0 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-11 9 DA LGWCW26CD B 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 0 DA LGWCW26CL S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 1 DA LGWCW26 C M S 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 2 DA LGWCW26CH S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 3 DA LGWCW26 L0 11062 2 (dill : 10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 4 DA LGWCW26LD B 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 5 DA LGWCW26LL 8 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 6 DALGWCW26LM S 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 7 DA LGWCW26LH S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-12 8 DALGW140R0110622(dil1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-12 9 DALG W140RD B 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-13 0 DALG W140RL S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-13 1 DALG W140RM 8 11062 2 (di l 1;10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-13 2 DALG W140RH S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-13 9 DALGW141RHS110630(di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 0 DA LGW142 R 0 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 1 DALG W142RD B 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxi c GLP10-01-01-18-14 2 DALG W142RL S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 3 DA LGW142 R M S 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 4 DA LGW142RH 8 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 S DA LGW143 R 0 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 6 DA LGW143RD B 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 7 DA LGW143RL 8 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 8 DALG W143 R M S 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-14 9 DALG W143RH S 11062 2 (di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxic , GLP10-01-01-18-15 0 DALGW14480110628(di l 1:10 ) Prepared ; 7/14/1 1 CJ G toxi c GLP10-01-01-18- 1 S I DALG W144SD B 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-1S 2 DALG W144 8 L 8 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18- 1 S 3 DALG W144 8 M S 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , GLP10-01-01-18-15 4 DALG W144 8 H 8 11062 2 (di l 1:10 ) Prepared : 7/14/1 1 CJ G toxic , Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e

ETS-8-04 4 sampl e pre p 110714.xl s labe l Pag e 2 o f2

## Sampl e I d

Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k 11003-26- 1 11003-26- 2 11003-26- 3 11003-26 ^ 11003-26- 5 11003-26- 6 11003-26- 7 11003-26- 8 11003-26- 9 11003-26-1 0 11003-26-1 1 11003-26-1 2 11003-26-1 3 11003-26-1 4 11003-26-1 5

LC8-110714- 1 LC8-110714- 2 LCS-110714- 3 LC8-110714- 4 LC8-110714- 5 LCS-110714- 6 LCS-110714- 7 LCS-110714- 8 LC8-110714- 9 LCS-110714-1 0 LC8-110714-1 1 LCS-110714-1 2 LC8-110714-1 3 LCS-110714-1 4 LCS-110714-1 5 LCS-110714-1 6 LCS-110714-1 7 LC8-110714-1 8

GLP10-01-01-18-00 1 GLP10-01-01-18-00 2 GLP10-01-01-18-00 3 GLP10-01-01-18-00 4 GLP10-01-01-18-00 5 GLP10-01-01-18-00 6 GLP10-01-01-18-00 7 GLP10-01-01-18-00 8 GLP10-01-01-18-00 9 GLP10-01-01-18-01 0 GLP10-01-01-18-01 1 GLP10-01-01-18-01 2 GLP10-01-01-18-01 3 GLP10-01-01-18-01 4 GLP10-01-01-18-01 5 GLP10-01-01-18-01 6 GLP10-01-01-18-01 7 GLP10-01-01-18-01 8 GLP10-01-01-18-01 9 GLP10-01-01-18-02 0 GLP10-01-01-18-02 1 GLP10-01-01-18-02 2 Descriptio n Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 0.02 5 ng/m LFC st d i n Mill i Q Wate r 0.0 3 ng/m LFC st d i n Mill i Q Wate r 0.04 ng/m LFC st d i n Mill i Q Wate r 0.0 5 ng/m LFC st d i n Mill i Q Wate r 0. 1 ng/m LFC st d i n Mill i Q Wate r 0.2 5 ng/m LFC st d i n Mill i Q Wate r 0. 5 ng/m LFC st d i n Mill i Q Wate r 1. 0 ng/m LF C st d i n Mill i Q Wate r 2. 5 ng/m LFC st d i n Mill i Q Wate r 5. 0 ng/m LFC st d i n Mill i Q Wate r 1 0 ng/m LFC st d i n Mill i Q Wate r 2 5 ng/m LFC st d i n Mill i Q Wate r 5 0 ng/m LFC st d i n Mill i Q Wate r 7 5 ng/m LFC st d i n Mill i Q Wate r 10 0 ng/m LFC st d i n Mill i Q Wate r O.Sppb LC S O.Sppb LC S O.Sppb LC S Spp b LC S Spp b LC S Spp b LC S 30pp b LC S 30pp b LC S 30pp b LC S O.Sppb LC S EC F O.Sppb LC S EC F O.Sppb LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F

Tri p Blan k

Se t2 Sampl e Tri p Blan k

Se t2 L 8 Tri p Blan k

Se t2 M S Tri p Blan k

Se t2 MH S Tri p Blan k

Set2 H S (di l 1:100) DA LG W130 R 0 11063 0 (di l 1:100) DA LG W130 R D B 11063 0 (di l 1 ; 100 ) DA LG W130 R L 8 11063 0 (di l 1:100) DA LG W130 R M S 11063 0 (di l 1:100) DA LG W130 R H S 11063 0 (di l 1:100) DA LG W130 S 0 11063 0 (di l 1:10) DA LG W130 8 0 11063 0 (di l 1:10) DA LG W130 8 L 8 11063 0 (diM : 100 ) DA LG W130 8 M S 11063 0 (di l 1:100) DA LG W130 8 H S 11063 0 (di l 1:100) DA LG W130 L0 11063 0 (di l 1:10) DA LG W130 LD B 11063 0 (di l 1:10) DA LG W130 LLS 11063 0 (di l 1:10) DA LG W1 SO

LM S 11063 0 (di l 1:10) DA LG W130 LH S 11063 0 (di l 1:10) DA LG W131 R 0 11062 2 (di l 1:100) DALG W131 R D B 11062 2 (di l 1:100) Pre p Dat e iquoted : ' i iquoted : ^

i iquoted ; ' i Aliquoted ; 1 iquoted ; 7 , iquoted ; 7 iquoted : 7 iquoted : 7 i iquoted ; 7 , iquoted ; 7 , iquote d iquote d iquoted : 7 , iquoted ; 7 , iquote d iquoted : 7 i iquoted : 7 iquoted : 7 iquoted : 7 iquoted : 7 iquoted : 7 iquoted : 7 iquoted : 7 iquoted : 7 iquoted : 7

iquoted : iquoted : iquoted : iquoted : iquoted : iquoted ; iquoted ; iquoted ; iquoted : iquoted : iquoted ; iquoted ; iquoted : iquoted ; iquoted ; iquoted ; iquoted ; iquoted :

iquoted : iquoted ; iquoted ; iquoted ; iquoted : iquoted : iquoted : iquoted ; iquoted ; iquoted : iquoted ; iquoted ; iquoted : iquoted : iquoted ; iquoted ; iquoted ; iquoted ; iquoted : iquoted : iquoted : iquoted : 15/1 1

15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 15/1 1 

## CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G CJ G

15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G

15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G 15/1 1 CJ G oxrc ,

oxi c oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic ,

:oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic , :oxic , oxic , oxic , oxic , :oxic , :oxic , :oxic , :oxic , :oxic ,

oxic , :oxic , :oxic , :oxic , :oxic , :oxic , loxic , oxic , oxic , oxic , oxic , oxic , oxic , oxi c oxic , oxi c oxi c oxic , oxic , oxi c oxi c oxi c Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e

Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e

Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e

ETS-8-04 4 sampl e pre p 110714.xl s labe l (2 ) Pag e 1 o f3

## Sampl e I d Descriptio n Pre p Dat e

GLP10-01-01-18-02 3 DALG W131 R LS 11062 2 (di l 1:100) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-02 4 DA LG W131 R H S 11062 2 (di l 1:100) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-02 5 DA LG W131 8 0 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-02 6 DA LG W131 S D B 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-02 7 DA LG W131 8 L 8 11062 2 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-02 8 DA LG W131 S M S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-02 9 DA LG W131 8 H S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-03 0 DA LG W131 L0 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-03 1 DALGW131LDB110622(dil1;10 ) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-03 2 DALG W131LL S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-03 3 DALG W131 LM S 11062 2 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-03 4 DA LG W131 LH S 11062 2 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-03 S DA LGW133 L0 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-03 6 DA LG W133 LD B 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-03 7 DALG W133 LL 8 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-03 8 DA LG W133 LM S 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-03 9 DALG W133 LH S 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-04 0 DA LGW133 S 0 11063 0 (diM : 10 ) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-04 1 DALG W133 8 D B 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-04 2 DALGW133SL S 110630(di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-04 3 DALG W133 S M S 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-04 4 DA LG W133 S H S 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-04 5 DA LG W133 R 0 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-04 6 DA LG W133 R D B 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-04 7 DA LG W133 R LS 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-04 8 DA LG W133 R M S 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-04 9 DA LG W133 R H 8 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-05 0 DA LG W134 R 0 11062 8 (di l 1:100 ) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 1 DA LG W134 R D B 11062 8 (di l 1:100) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 2 DA LG W134 R LS 11062 8 (di l 1:100) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 3 DA LG W134 R H S 11062 8 (di l 1;100) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-05 4 DA LG W134 L0 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 5 DA LG W134 LD B 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-0S 6 DA LG W134 LLS 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 7 DA LG W134 LM S 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 8 DA LG W134 LH 8 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-05 9 DA LG W134 S 0 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-06 0 DALG W134 8 D B 11062 8 Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-06 1 DA LG W134 8 L S 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-06 2 DA LG W134 8 M S 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-06 3 DA LG W134 8 H S 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-06 4 Tri p Blan k Se t1 Sampl e Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-06 S Tri p Blan k Se t1 LS Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-06 6 Tri p Blan k Set1 M S Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-06 7 Tri p Blan k Se t1 MH S Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-06 8 Tri p Blan k Se t1 H S (di l 1:100) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-06 9 DA LG W135 8 0 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-07 0 DA LG W135 8 D B 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-07 1 DA LG W135 8 L 8 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-0 1 -0 1 -18-07 2 DA LG W135 8 M S 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-07 3 DA LG W135 S H S 11062 8 Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-07 4 DALG W13SL 0 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-07 5 DA LG W135 LD B 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-07 6 DA LG W13S LL 8 11062 8 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-07 7 DA LG W135 LM S 11062 8 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-07 8 DA LG W135 LH S 11062 8 (di l 1 ; 10 ) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-07 9 DA LG W135 R 0 11062 8 (di l 1:100) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 0 DA LGW13SRD B 11062 8 (di l 1:100 ) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-08 1 DA LGW135 R LS11062 8 (di l 1:100 ) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 3 DA LG W135 R H S 11062 8 (diM : 100 ) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 4 DALG W136L 0 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 5 DA LG W136 LD B 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 6 DALGW136LL 8 110630(di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-15 S DA LGW136 LM S 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 7 DA LG W136 LH S 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G GLP10-01-01-18-08 8 DA LG W136 S 0 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G GLP10-01-01-18-08 9 DA LG W136 8 D B 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxi c toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic

. , Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e : , Refrigerat e

, Refrigerat e ; , Refrigerat e : , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e ; , Refrigerat e ; , Refrigerat e ; , Refrigerat e : , Refrigerat e ; , Refrigerat e ; , Refrigerat e

, Refrigerat e ; , Refrigerat e : , Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e ; , Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

, Refrigerat e

ETS-8-04 4 sampl e pre p 110714.xl s labe l (2 ) Pag e 2 o f3

## Sampl e I d Descriptio n Pre p Dat e

GLP10-01-01-18-09 0 DALG W136 8 LS 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 1 DALG W136 8 M S 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 2 DA LG W136 8 H S 11063 0 (diM : 10 ) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 3 DA LG W137 S 0 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 4 DA LG W137 S D B 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 5 DA LG W137 8 LS 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 6 DALG W137 8 M S 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 7 DA LG W137 8 H S 11062 4 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 8 DA LG W137 L0 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-09 9 DA LG W137 LD B 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 0 DA LGW137 LLS11062 4 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 1 DA LGW137 LM S 11062 4 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 2 DA LGW137LH S 11062 4 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-0 1 -0 1 -18-10 3 DA LG W138 R 0 11063 0 (di l 1 ; 10 ) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 4 DA LGW138RD B 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 5 DA LGW138 R LS11063 0 (dill : 10 ) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 6 DALGW138RMS110630(dil1:10 ) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 7 DA LGW138RH S 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 8 DALG W138L 0 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-10 9 DA LGW138LD B 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 0 DA LGW138LL 8 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 1 DA LGW138 LM S 11063 0 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 2 DA LGW138LH 8 11063 0 Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 3 DALG W138 8 0 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 4 DA LG W138 8 D B 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 5 DA LG W138 S LS 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 6 DALGW1388M8110630(dil1:10 ) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 7 DA LG W138 8 H S 11063 0 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 8 DA LGWCW26 C 0 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-11 9 DALGWCW26CDB110622(dil1;10 ) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-12 0 DA LGWCW26CL 8 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-12 1 DALGWCW26CM S 11062 2 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-12 2 DA LG WCW26 C H S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-12 3 DA LGWCW26 L0 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-12 4 DALGWCW26LDB110622(diM;10 ) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-12 5 DA LGWCW26 LLS11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-12 6 DA LGWCW26 LM S 11062 2 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-12 7 DALGWCW26LHS110622(diM;10 ) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-12 8 DA LGW140 R 0 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-12 9 DA LGW140RD B 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-13 0 DA LGW140RL S 11062 2 (diM;10 ) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-13 1 DA LGW140 R M S 11062 2 (dil l ;10 ) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-13 2 DA LGW140RH 8 11062 2 (di M :10 ) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-13 3 DA LGW130LR B 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-13 4 DALG W133 8 R B 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-13 5 DA LGW141 R 0 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-13 6 DALG W141RD B 11063 0 Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-13 7 DA LG W141RL 8 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-13 8 DA LG W141 R M S 11063 0 Aliquoted ; 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-13 9 DA LGW141RH S 11063 0 (di l 1:10) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-14 0 DA LGW142R 0 11062 2 (diM;10 ) Aliquoted ; 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-14 1 DA LGW142RD B 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-14 2 DA LGW142RL 8 11062 2 (dil1:10 ) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-14 3 DA LGW142 R M S 11062 2 (dil1;10 ) Aliquoted ; 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-14 4 DA LGW142RH S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-14 5 DA LGW143R 0 11062 2 (dil1:10 ) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-14 6 DA LGW143RD B 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-14 7 DA LGW143RL S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-14 8 DA LGW143 R M S 11062 2 (dil1:10 ) Aliquoted : 7/1S/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-14 9 DALGW143RHS110622(dil1:10 ) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18- 1 S

O DA LG W144 S 0 11062 8 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-15 1 DALG W144SD B 11062 2 (dil1:10 ) Aliquoted : 7/15/1 1 CJ G toxic

. Refrigerat e GLP10-01-01-18-15 2 DA LGW144 S LS11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18- 1 S

3 DALG W144 8 M S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e GLP10-01-01-18-15 4 DA LG W144 8 H S 11062 2 (di l 1:10) Aliquoted : 7/15/1 1 CJ G toxic , Refrigerat e

ETS-8-04 4 sampl e pre p 110714.xl s labe l (2 ) Pag e 3 of3

# Printin g 7/26/2011 ; 3:3 9 P M

GLP10-01-01-18 , GLP10-01-01-1 9 Sampl e Pre p Wor k Sheet ; ETS-8-04 4 date : 7/26/1 1

Sampl e I D LCS-110726- 1 LCS-110726- 2 LCS-110726- 3 LCS-110726- 4 LCS-110726- 5 LCS-110726- 6 LCS-110726- 7 LCS-110726- 8 LCS-110726- 9 LCS-110726-1 0 LCS-110726-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 5 LCS-110726-1 6 LCS-110726-1 7 LCS-110726-1 8 Analyst : CJ G

Sampl e Descriptio n 0.2pp b LC S 0.2pp b LC S 0.2pp b LC S 2pp b LC S 2pp b LC S 2pp b LC S 20pp b LC S 20pp b LC S 20pp b LC S 0.2pp b LC S EC F 0.2pp b LC S EC F 0.2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F Spikin g st d I D 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 6 1 0 006-14 6 1 0 006-14 6 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 1 005-4 7 1 1 005-4 7 1 1 005-4 7 1 1 005-4 6 1 1 005-4 6 1 1 005-4 6 1 0 006-15 2 1 0 006-15 2 1 0 006-15 2 Spik e Am t

(ML ) 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 1 0 1 0 1 0 2 0 2 0 2 0 La b wate r

(mL ) 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 10. 0 Interna l

Standar d I D 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 11005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 Spik e Am t(pL )

5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 Fina l Volum e

(mL ) 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 6 10.0 6 10.0 6 10.0 7 10.0 7 10.0 7

7/26/1 1 CJG ; LC S prepare d wit h Syntiieti cgroundwate r1 0 006-171 , vorte xmixed , an d 1 se twer e transferre d int o 2-m Lautovials

. 7/26/1 1 CJG ; 1 se to faliquot s o f1 1 003-25- 1 throug h 1 6 wer e transferre d int o 2-m Lautovials

. 7/26/1 1 CJG ; 1 0 replicate s o f1 1 005-5 9 wer e aliquote d fo rmetho d blanks

. 7/26/1 1 CJG ; LC S spike d usin g EppendorfResearc h pipett e 4215537

. 7/26/1 1 CJG ; GLP10-01-01-18 , GLP10-01-01-1 9 sample s wer e aliquote d int o 2 m Lautovi a S

.



# The-fbllDVMinaGLPIO'Ol'Ol'lSSdmple S wer e a\i^uotfed S G>LPlO0l-0i-i^-0(f?S , -010 , a.nd-013 ^ CT G Slsl ) I

ETS-8-04 4 sampl e pre p 110726.xl s , Pag e 1 o f1Curv e Point s an d LCS ; Metho d ETS-8-04 4 ETS-8-04 4 sampl e pre p 110726.xl s

Stoc k I D 1 0 006-14 7

1 0 006-14 6 1 0 006-14 5 1 0 006-13 0 1 0 006-13 1 11002-21 4 1 1 002-2 8 1 0 006-8 8 1 1 005-4 7 1 1 005-4 6 1 0 006-15 2 Targe tAnalyt e Concentratio n (ug/mL ) 

### PFdA 0.10 0 1.0 0 10. 0 10 0



# -

0.10 0 2.0 0 10. 0 PFB S

0.10 0 1.0 0 10. 0

10 0



# - PFH S

0.10 0 1.0 0 10. 0

10 0



# - PFO S

0.10 0 1.0 0 10. 0

10 0



# -

0.099 5 1.9 9 9.9 5

Stoc k I D 11005-3 0

1 0 006-14 9 1 1 002-24 0 11005-29,11005-2 8 1 1 002-23 8 1 1 002-23 9 Interna l Standar d Concentratio n (ug/mL ) M8-PFO A 0.20 0 2.0 0



# -

4.9 9 4.9 9 1802PFB S

0.19 5 1.9 5 81. 2



# . M3PFH S

0.18 9 1.8 9

4.7 3 4.7 3 M8-PF0 S

0.19 2 1.9 2

4.7 9 4.7 9

1 1 003-25- 1 0.02 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 2 0.0 3 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 3 0.0 4 ng/m LF C st d i n Synth

. Wate r 1 1 003-25 ^

0.0 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 5 0. 1 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 6 0.2 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 7 0. 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 8 1. 0 ng/m LF C st d i n Synth

. Wate r 1 1 003-25- 9 2. 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 0 5. 0 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 1 1 0 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 2 1 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 3 2 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 4 5 0 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 5 7 5 ng/m LF C st d i n Synth

. Wate r 1 1 003-25-1 6 10 0 ng/m LF C st d i n Synth

. Wate r Interna l Standar d 1 ng/m LI S mi x Fina l Spik e Concentratio n (ng/mL ) |

PFO A 0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 15. 0 25. 0 SO. O 75. 0 10 0 1.0 0 PFB S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 S.O O 10. 0 IS. O 25. 0 50. 0 75. 0 10 0 0.97 5 PFH S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 15. 0 25. 0 50. 0 7S. 0 10 0 0.94 5 PFO S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 15. 0 25. 0 50. 0 75. 0 10 0 0.96 0 Stoc * I D

1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 7 1 0 006-14 6 1 0 006-14 6 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5
1 0 006-14 9 Spik e

Volum e (uL ) 2 5 3 0 4 0 5 0 10 0 25 0 5 0 10 0 2 5 5 0 10 0 15 0 25 0 50 0 7S 0 100 0 5 0 Fina l Volum e (mL ) 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 

### to o 10 0

LCS-110726- 1 LCS-110726- 2 LCS-110726- 3 LCS-110726- 4 LCS-110726- 5 LCS-110726- 6 LCS-110726- 7 LCS-110726- 8 LCS-110726- 9 LCS-110726-1 0 LCS-110726-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 5 LCS-110726-1 6 LCS-110726-1 7 LCS-110726-1 8 0.2pp b LC S 0.2pp b LC S 0.2pp b LC S 2pp b LC S 2pp b LC S 2pp b LC S 20pp b LC S 20pp b LC S 20pp b LC S 0.2pp b LC S EC F 0.2pp b LC S EC F 0.2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F

Interna l standar d LCS-110726- 1 LCS-110726- 2 LCS-110726- 3 LCS-110726- 4 LCS-110726- 5 LCS-110726- 6 LCS-110726- 7 LCS-110726- 8 LCS-110726- 9 LCS-110726-1 0 LCS-110726-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 5 LCS-110726-1 6 LCS-110726-1 7 LCS-110726-1 8 0.2pp b LC S 0.2pp b LC S 0.2pp b LC S 2pp b LC S 2pp b LC S 2pp b LC S 20pp b LC S 20pp b LC S 20pp b LC S 0.2pp b LC S EC F 0.2pp b LC S EC F 0.2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 0.19 9 0.19 9 0.19 9 1.9 9 1.9 9 1.9 9 19. 9 19. 9 19. 9 0.19 9 0.19 9 0.19 9 1.9 9 1.9 9 1.9 9 19. 9 19. 9 19. 9



### Mi-PFO A 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 3 0.99 4 0.99 4 0.99 4 0.99 3 0.99 3 0.99 3 0.19 9

0.19 9 0.19 9 1.9 9 1.9 9 1.9 9 19. 9 19. 9 19. 9



### UdiPPb S 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 8 0.96 9 0.96 9 0.96 9 0.96 8 0.96 8 0.96 8 0.19 9

0.19 9 0.19 9 1.9 9 1.9 9 1.9 9 19. 9 19. 9 19. 9



### MaPFH S 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 8 0.93 9 0.93 9 0.93 9 0.93 8 0.93 8 0.93 8 0.19 9

0.19 9 0.19 9 1.9 9 1.9 9 1.9 9 19. 9 19. 9 19. 9 0.19 8 0.19 8 0.19 8 1.9 8 1.9 8 1.9 8 19. 8 19. 8 19. 8

MS-PFO S 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 3 0.95 4 0.95 4 0.95 4 0.95 3 0.95 3 0.95 3 1 0 006-14 7

1 0 006-14 7 1 0 006-14 7 1 0 006-14 6 1 0 006-14 6 1 0 006-14 6 1 0 006-14 5 1 0 006-14 5 1 0 006-14 5 1 1 005-4 7 1 1 005-4 7 11005-4 7 11005-4 6 11005-4 6 1 1 005-4 6 1 0 006-15 2 1 0 006-15 2 1 0 006-15 2

11005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 11005-3 0 11005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 1 1 005-3 0 2 0

2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 1 0 1 0 1 0 2 0 2 0 2 0

5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 S O 5 0 5 0 5 0 5 0 10.0 7

10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 6 10.0 6 10.0 6 10.0 7 10.0 7 10.0 7

10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 7 10.0 6 10.0 6 10.0 6 10.0 7 10.0 7 10.0 7

Pag e 1 o f1 

# cs esiiM iETS-8-04 4 sampl e pre p 110726.xl s

Sampl e I d LCS-110726- 1 LCS-110726- 2 LCS-110726- 3 LCS-110726- 4 LCS-110726- 5 LCS-110726- 6 LCS-110726- 7 LCS-110726- 8 LCS-110726- 9 LCS-110726-1 0 LCS-110726-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 S LCS-110726-1 6 LCS-110726-1 7 LCS-110726-1 8 LCS-110726- 1 LCS-110726- 2 LCS-110726- 3 LCS-110726- 4 LCS-110726- 5 LCS-110726- 6 LCS-110726- 7 LCS-110726- 8 LCS-110726- 9 LCS-110726-1 0 LCS-110726-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 5 LCS-110726-1 6 LCS-110726-1 7 LCS-110726-1 8 1 1 003-25- 1 1 1 003-25- 2 1 1 003-25- 3 1 1 003-25- 4 11003-25- 5 1 1 003-25- 6 11003-25- 7 11003-25- 8 11003-25- 9 1 1 003-25-1 0 1 1 003-25-1 1 11003-25-1 2 1 1 003-25-1 3 1 1 003-25-1 4 11003-25-1 5 11003-25-1 6 11005-5 9 1 1 005-5 9 11005-5 9 11005-5 9 1 1 005-5 9 1 1 005-5 9 1 1 005-5 9 1 1 005-5 9 1 1 005-5 9 1 1 005-5 9 GLP10-01-01-18-06 9 GLP10-01-01-18-07 0 GLP10-01-01-18-07 3 GLP10-01-01-19-00 1 GLP10-01-01-19-00 2 GLP10-01-01-19-00 3 GLP10-01-01-19-00 4 GLP10-01-01-19-00 5 GLP10-01-01-19-00 6 GLP10-01-01-19-00 7 GLP10-01-01-19-00 8 GLP10-01-01-19-00 9 GLP10-01-01-19-01 0 GLP10-01-01-19-01 1 GLP10-01-01-19-01 2 GLP10-01-01-19-01 3 Descriptio n 0.2pp b LC S 0.2pp b LC S 0.2pp b LC S 2pp b LC S 2pp b LC S 2pp b LC S 20pp b LC S 20pp b LC S 20ppbLC S 0.2pp b LC S EC F 0.2pp b LC S EC F 0.2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 0.2pp b LC S 0.2pp b LC S 0.2pp b LC S 2pp b LC S 2pp b LC S 2pp b LC S 20pp b LC S 20pp b LC S 20pp b LC S 0.2pp b LC S EC F 0.2pp b LC S EC F 0.2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 2pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 20pp b LC S EC F 0.02 5 ng/m LF C st d i n Synth

. Wate r 0.0 3 ng/m LF C st d i n Synth

. Wate r 0.0 4 ng/m LF C st d i n Synth

. Wate r 0.0 5 ng/m LF C st d i n Synth

. Wate r 0. 1 ng/m LF C st d i n Synth

. Wate r 0.2 5 ng/m LF C st d i n Synth

. Wate r 0. 5 ng/m LF C st d i n Synth

. Wate r 1. 0 ng/m LF C st d i n Synth

. Wate r 2. 5 ng/m LF C st d i n Synth

. Wate r 5. 0 ng/m LF C st d i n Synth

. Wate r 1 0 ng/m LF C st d i n Synth

. Wate r 1 5 ng/m LF C st d i n Synth

. Wate r 2 5 ng/m LF C st d i n Synth

. Wate r 5 0 ng/m LF C st d i n Synth

. Wate r 7 5 ng/m LF C st d i n Synth

. Wate r 10 0 ng/m LF C st d i n Synth

. Wate r Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k Metho d Blan k DALG W135 S 0 11062 8 DA LGW135SD B 11062 8 DA LGW135SH S 11062 8 DALGWTRIP 1 0 11071 3 DALGWTRIP 1 L S 11071 3 DALGWTRIP 1 M S 11071 3 DALGWTRIP 1 H S 11071 3 DA LG WBPMW4 7 0 11071 3 DA LG WBPMW4 7 D B 11071 3 DA LG WBPMW4 7 L S 11071 3 DA LG WBPMW4 7 H S 11071 3 DALGWBPMW12 1 R S 11071 3 DALGWBPMW12 1 0 11071 3 DALGWBPMW12 1 D B 11071 3 DALGWBPMW12 1 L S 11071 3 DALGWBPMW12 1 H S 11071 3 Pre p Dat e Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : iquoted : 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G 7/26/1 1 CJ G hazar d

toxic , Re f toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxi c toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f Re f

labe l Pag e 1 o f1 

# ar6^|i/i N

# Analytica lCas eNarrativ e Dat aReductio nCalculation s Contro lChar t

- Analytica l Uncertainty

# 3 M Confidentia l 3 M Environmenta l Laborator y Project : GLPlO-01-01-1 8 Sequenc e k l 10715 a 3 M Environmenta l Laborator y 3 M Technica l Lead : Susa n Wol f Buildin g 260-5N-1 7 651-733-985 1 Repor tAutho rChelsi e Grocho w Analytica l Team : Kell yUke s



# Analytica l Cas e Narrativ e fo rMetho d ETS-8-44. 0

Projec tGLPlO-01-01-1 8 Decatu rPhas e 3 FSI AGroundwater

- Jun e 201 1 Direc tinjectio n analysi s o

fdilute d an d undilute d samples Sequenc e k110715a ReportDate : Jul y20 , 2011

Instrumen tsummar

yan d calibratio n curves wil l be printe d an d include d i n th e ra wdata package

.
Chromatogram s wil l be printe d to pdf

.

ET S 8-04 4 Analytica l SummaryChecklis tPag e 1 o f3

## 3 M Confidentia l



# 1 Projec tScop e an d Dat a Qualit yObjectiv e SIV I Environmenta l Laboratory Project : GLPlO-01-01-1 8 Sequenc e k l 10715 a

Genera l ProjectOutlin e available

.

GL P 1 3 Ye s

1 3 Ye s D N o

n N o I fNo , Pleas e briefl ydescrib e

projec tscop e an d DQ O



# 2 Sampl e Containe rPreparatio n

Sampl e containe rpreparatio n documente d i n a Not e to Fil e an d include d i n th e ra wdata package

. 

# 3 Sampl e Analysi s

3. 1 Syste m Suitabilit y

Initia l Syste m Suitabilit yare a count s wit h RS D <5 % (ETS-8-15 4 sectio n 10.5 ) an d retentio n tim e wit h RS D 52 % JElYe s D N o



# 3.1. 1 Syste m Suitabilit yDeviation s

N A 

# 3. 2 Instrumen tCalibratio n Cun/e typ e r^>0.99 0 Linearit ycriteri a me t(ETS-8-4 4 sectio n 12.2 )

< ±25 % residuals , excep tLO Q o f±30 % (ETS-8-4 4 sectio n 12.2 ) Mid-leve l calibratio n point s disable d Quadratic , 1/ x 1 3 Ye s 1 3 Ye s DYe s D N o

D N o 1 3 N o



# 3. 3 Continuin g Calibratio n Verificatio n

±25 % Differenc e criteri a me tfo rperiodi cCCV s (ETS-8-4 4 sectio n 12.2 ) 1 3 Ye s n N o 

# 3.3. 1 Continuin g Calibratio n Verificatio n Deviation s

N A 

# 3. 4 Metho d Blank s

Metho d blank s uniquel yidentifie d i n th e ru n sequence

. Averag e are a count s o ftarge tanalyte s i n th e metho d blan k presen ta t s V

^ x th e are a count s o fth e LO Q standar d (ETS-8-4 4 Sectio n 10.2 ) ^Ye s

1 3 Ye s D N o

D N o



# 3.4. 1 Metho d Blan k

Deviation s N A

ET S 8-04 4 Analytica l SummaryChecklis t Pag e 2 o f3

## 3I\/ I Confidentia l



# 3. 5 La b Contro l Spike s 3I\/ I Environmenta l Laborator y Project : GLPlO-01-01-1 8 Sequenc e k l 10715 a

±20 % recoverycriteri a me t(ET S 8-4 4 Sectio n 10.5 ) <20 % RS D precisio n (ET S 8-4 4 Sectio n 10.5 ) 1 3 Ye s 1 3 Ye s D N o

D N o 

# 3.5. 1 La b Contro l Spik e Deviation s N A 

# 3. 6 Sampl e Replicate s

RP D fo rfiel d duplicate s <20 % (ETS-8-4 4 Sectio n 10.5 ) 1 3 Ye s D N o 

# 3.6. 1 Sampl e Replicate s Deviation s N A 

# 3. 7 Fiel d Matri xSpike s

±30 % recoverycriteri a met

. (ET S 8-4 4 Sectio n 10.5 ) DYe s 1 3 N o 

# 3.7. 1 Fiel d Matri xSpik e Deviation s DA LG W135S : H S recovery206%

. DA LG W135L : N o appropriat e FM S leve l t o determin e recovery

. 

# 3. 8 Limi to fQuantitatio n (LOQ )

Al l LOQ s equa l th e low-leve l calibratio n standar d concentratio n wit h are a count s a tleas ttwic e tha to fth e metho d blank(s ) (ET S 8

- 4 4 Sectio n 10.2 ) 1 3 Ye s D N o



# 3. 9 Manua l Integration s

Manua l integratio n reviewe d byanothe ranalyst/tea m lead : Reviewe d bv : i^'T KDate : -^jzaj-Z e n 

# 1 3 Ye s DN o

4 Additiona l analytica l note s

Al l dat a wil l b e reporte d excep tfo rDA LG W135 S du e t o unacceptabl e FM S recovery

. 

# 5 Signature s 

# ^i}m.^yi&4i m

Li i -7/10/1 1 Analys t Dat e

ET S 8-04 4 Analytica l Summar yChecklis t Pag e 3 o f3

# Kir k AP I5500 , BB2150101 0 pag e1/ 1

DATE : 7/15/201 1

ANALYST : CJ G

STUD YNUMBER : GLPlO-01-01-1 8 Sampl ePre p Date : 7/14/1 1 Sampl eAliquo t

Date : 7/15/1 1

LC/MS/M S Method : PFOAonly

Mobil ePhase : (A ) 2m M ammoniumacetate(aq) (B ) Methano l

TN-A-o r standardnumber

(A ) 11005-9 1 (B ) TN I1-0209 7/8

Guar dcolumn : Pris mR PColum n2.1x50m

m Size : 5uLot

number : 996 0 Seria lnumber 0711213T4 starte d7/13/1 1 Par t number : 32105-05213 0

Analyticalcolumn : Betasi lCI 8 Colum n2.1x100m

m Size : 5uLo t

number : 10920 Seria lnumber 0516989T4 Started7/13/1 1 Par t number : 70105-10213 0

DATAFILE : k l10715 a

Seemetho dfo

r LC/MS/M S parameter s

Printed : Friday , July 15 , 201 1 3:4 2 P M

### *Kir k BB2150101 0

Project : P:\Projects\LabJnslrumon l Data\Kir»kirkdata\ProioctafIuoroctiemtcals_walBrBalch;k110715 a TabiSampl a Set:SET 1 AcqMelhod:PFOA Sampl e

1 2 3 4 5 6 7 8 ~ 9 1 0 1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 • 2 5 " 2 6 2 7 2 8 2 9 30 3 1 32 3 3 3 4 35 36 3 7 38 3 9 4 0 4 1 '" ^ 42 43 44 45 46 47 48 4 9 5 0 5 1 52 5 3 54 5 5 5 6 5 7 5 8 5 9 "' ~ 6 0 

### 6 i 62 6 3 64 6 5 6 6 6 7 6 8 6 9 7 0 7 1 Sampl e Nam e k110715a00 1 k110715a002 k110715a00 3 k110715a00 4 k110715a00 5 k110715a00 6 k110715a00 7 k110715a00 8 k110715a00 9 k110715a01 0 k110715a01 1 k110715a01 2 k110715a01 3 k110715a01 4 k110715a01 5 k110715a01 6 k110716a01 7 k1ia715a01 8 k110715a01 9 k110715a02 0 k110715a02 1 k110715a02 2 k110715a02 3 k110715a02 4 k110715a02 5 k110715302 6 kl10715302 7 k l 10715302 8 k110715302 9 k110715303 0 k110715a03 1 k1107i5a03 2 k l 107153033 k l 107153034 k l 107153035 k l 10715303 6 k l 10715303 7 k l 10715303 8 k110715a03 9 k110715a04 0 k110715a04 1 k1107153042 k110715304 3 k110715a044 k110715304 5 k110715a04 6 kl10715304 7 k110715a04 8 kl10715304 9 k110715305 0 k110715a05 1 k110715a05 2 kl10715305 3 kl10715305 4 k110715305 5 k110715a05 6 k110715a05 7 kl10715305 8 k l 10715305 9 k l 10715306 0 kl10715306 1 k l 107153062 kl10715306 3 kl10715306 4 k110715a06 5 k110715a06 6 k110715a06 7 kl10715306 8 kl10715306 9 k l 10715307 0 k110715307 1 Sampl e I D

Solven t6l3n k Solven tBl3n k 11003-26- 8 Solven tBlen k 11003-26- 9 11003-26- 9 11003-26- 9 11003-26- 9 Solven tBlan k Solven tBlen k 11003-26- 1 11003-26- 2 11003-26- 3 11003-26- 4 11003-26- 5 11003-26- 6 11003-26- 7 11003-26- 8 11003-26- 9 11003-26-1 0 11003-26-1 1 11003-26-1 2 11003-26-1 3 11003-26-1 4 11003-26-1 5 Solven tBlan k Solven tBlan k Solven tBlan k Solven tBlan k LCS-110714- 1 LCS-110714- 2 LCS-110714- 3 LCS-110714- 4 LCS-110714- 5 LCS-110714- 6 LCS-110714- 7 LCS-110714- 8 LCS-110714- 9 Solven tBlan k Solven tBlan k 11003-26-1 0 Solven tBlan k LCS-110714-1 0 LCS-110714-1 1 LCS-110714-1 2 LCS-110714-1 3 LCS-110714-1 4 LCS-110714-1 5 LCS-110714-1 6 LCS-110714-1 7 LCS-110714-1 8 Solven tBlan k Solven tBlan k 11003-26- 9 Solven tBlan k Solven tBlan k GLP10-01-01-18-00 1 GLP10-01-01-18-00 2 GLP10-01-01-18-00 3 GLP10-01-01-18-56 4 GLP10-01-01-18-00 5 GLP10-01-01-18-00 6 GLP10-01-01-18-00 7 GLP10-01-01-18-00 8 GLP10-01-01-18-00 9 GLP10-01-01-18-01 0 Solven tBlan k Solven tBlan k 11003-26-1 0 Solven tBl3n k GLP10-01-01-18-01 1 Via l Positio n 9 1 9 1 

### [ 8 9 1 9 9 9 9 9 1 9 2 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 9 2 9 2 9 3 9 3 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 9 3 9 4 1 0 9 4 2 5 ^ 2 6 2 7 2 8 2 9 3 0 3 1 32 3 3 9 4 9 4 9 9 5 9 5 34 

# fe 3 6 3 7 3 8 3 9 4 0 4 1 42 4 3 9 5 9 6 1 0 9 6 4 4 Data ni e

k110715 a kl10715 3 kl10716 a kl10715 a kl10715 a k110715 3 kl10715 a k l 10715 a k110715 3 k110715 3 k l 10715 3 k l 10715 a • k l 10715 a k110715 a kl10715 3 kl10715 3 kl10715 3 kl10715 3 jk110715 3 ikTToTBs kl10715 3 kl10716 3 k l 10715 a K l 10715 a k110715 a k110715 3 k110715 3 k110715 3 k110715 3 k110715 8 k110715 a k110715 a k110715 3 k110715 3 k110715 3 k110715 a k110715 3 k110715 3 kl10715 3 k110715 3 kl10715 3 k110715 3 k110715 a k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k110715 a k110715 3 k110715 a k110715 a k110715 3 kl10715 3 kl10715 3 k110715 a kl10715 a ki10715 a kl10715 a rw10715 a kl10715 a k110715 3 kl10715 a k l 10715 a kl10715 a kl10715 a k110715 3 k110715 3 k110715 a k110715 a k110715 3 InJ.Volum s (Ml )

25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 2500 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 2500 0 25.00 0 25.00 0 25.00 0 25,00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 2500 0 25.00 0 25.00 0 25.00 0 25,00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25,00 0 25,00 0 26,00 0 25,00 0 26,00 0 2500 0 25,00 0 25,00 0 2500 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25.00 0 2500 0 5.00 0 25.00 0 25.00 0 25,00 0 25,00 0 25.00 0 25.00 0 25.00 0 25.00 0 2500 0 26,00 0 25.00 0 Comment s

Milli Q Wate rTO11-0234 Milli Q Wate rTO11-0234 1, 6 ng/m LF

C st d i n Mil l Q Wate r Milli Q Wate rTN11-0234 2, 5 ng/m LF

C st d i n Mill i Q Wate r 2, 5 ng/trl LF

C st d i n Miii i Q Wate r 2, 5 ng/m LF

C st d i n Mil l Q Wate r 2. 5 ng/rt tF

C sT d i n Mi l Q Wete r Milli Q Wate rTN11-0234 Mini Q Wate rTN11-0234 0,02 5 ng/m LF

C st d i n Mil l Q Wate r 0.0 3 ng/m LF

C st d i n Mil l Q Wate r 0.04 ng/m LF

C st d i n Mil l Q Wate r 0.0 5 ng/m LF

C st d i n Mil l Q Wate r 0. 1 ng/m LF

C st d i n Mill i Q Wate r 0.2 5 ng/m LF

C st d i n Mil l Q Wste r 0. 5 ng/m LF

C st d i n Mill i Q Wste r 1. 0 ng/m LF

C st d i n Mill i Q Wate r 2. 5 ng/m LF

C st d i n Mill i Q Wate r 5, 0 ng/m LF

C st d i n Mill i Q Wate r 1 0 ng/rtl

. F

C st d i n Mill i Q Wate r 2 5 ng/m LF

C st d i n Mill i Q Wate r 5 0 nglni

. F

C st d i n Mill i Q Wate r 7 5 ng/m LF

C st d i n Milli Q Wate r 100 ngln LF

C st d i n Mill i Q Wate r Mlli Q Wate rTN11-0234 Milli Q Wate rTN11-0234 Mil l Q Wate rTM11-023

4 Mil l Q Wate rTN11-0234 0,5pp b LCS 0,5pp b LCS O.Spp b LCS Spp b LCS Spp b LCS Sppb LCS 30pp b LCS 30pp b LCS 30pp b LCS Milli Q Wate rTN11-0234 Milli Q Wate rTN11-0234 5. 0 ng/m LF

C st d i n Mini Q Wate r Milli Q Wate rTN11-0234 O.Spp b LCS BCF O.Spp b LCS BCF O.Spp b LCS K F • Sppb LCS EC F Sppb LCS EC F Spp b LCS EC F 30pp b LCS EC F 30pp b LCS EC F 30pp b LCS EC F Milli Q Wate rTN11-0234 Milli Q Wate rTN11-0234 2, 5 ng/m LF

C st d i n Mill i Q Wate r Milli Q Wate rTN11-0234 Milli Q Wate rTN11-0234 Tri p Blan k

Se t2 Sampl e Tri p Blan k

Se t2 L S Tri p Bten k

Se t2 M S Tri p Blan k

Set2 MHS Tri p Blan k

Se t2 H S (di l 1:100) DfV LG W130 R 0 11063 0 (d

H 1:100) DA LGW130RD B 11063 0 (di l 1:100) DALG W130 R L

S 11063 0 (di l 1:100) DA LG W130 R M

S 11063 0 (di l 1:100) DALG W130 R H

S 110630 (di l 1:100) Milli Q Wate rTN11-0234 Milli Q Wate rTN11-0234 5 0 ng/m LF

C st d i n MrD

i Q Wate r Milli Q Wate rTN11-0234 DA LG W130 S 0 11063 0 (di l 1:10 ) only.da m



### Printin g Time : Printin g Date : 10:15:0 1 A M

Monday , Jul y1 8 Pag e 1 o f 4 

# C^GllC^h ^

### *Kirl < BB2150101 0

Project : P:\ProiectaLabJnslnimen l Data\Kirtokirkdata\Pro]ectafIuorocliemlcals_waterBatcti:k110715 a Tab:Sampl e Sot:SET 1 AcqMettiod:PFO A Sampl e

,72 73 17 4

'"7 5 "• • |7 6 177 ;7 8 

## J7 9 |8 0 'e i 82 18 3 84 8 5 8 6 8 7 8 8 8 9 9 0 9 1 92 9 3 94 9 5 9 6 9 7 9 8 9 9 100 10 1 102 103 104 105 106 107 108 109 11 0 11 1 11 2 11 3 11 4 11 5 11 6 11 7 11 8 11 9 12 0 12 1 122 123 124 12 5 ' 12 6 12 7 ' 12 8 "l2 9 " 130 13 1 132 133 13 4 135 13 6 13 7 138 139 |l4 0 114 1 jl4 2 Sampl e Nam e k l 107153072 kl10715307 3 M l 67153074 k110715a07 5 k110715307 6 k110715307 7 k110715307 8 kTT6715307 9 kl10715308 0 k110715308 1 k110715a08 2 k l 10715308 3 k110715a08 4 kl10715308 5 k11071S308 6 k110715308 7 k110715308 8 k l 10715308 9 k110715309 0 kl10715309 1 k l 107153092 kl10715309 3 k l 167153094 kl16715309 5 k110715309 6 k11071Sa09 7 k l 10715309 8 kl10715309 9 kl107 1 Sa l 0 0 k11071S3l0 1 k110715a102 k110715a10 3 k11071S3l0 4 k1107153l0 5 k11071S3l0 6 k1107153l0 7 k1107153l0 8 kl10715310 9 k1107153l1 0 k1107153l1 1 kli67i53l1 2 k1107153l1 3 kl10715311 4 k11071Sa11 5 k11071Sa11 6 k11071S3l1 7 k1107153l1 8 k1l671Sa11 9 k110715a12 0 k110715a12 1 k11071Sa122 k11071Sa12 3 k110715a12 4 k11071S3l2 S k11071Sa12 6 k110715a12 7 k1107153l2 8 k1107153l2 9 k1107153l3 0 kl10715313 1 k1107153l3 2 k1107153l3 3 k1l67153l3 4 k11071S3l3 S k11071Sa13 6 k1107153l3 7 k11071S3l3 8 k110715a13 9 k110715a14 0 k110715a14 1 k11071Sa142 Sampl e I D

GLP10-01-01-18-01 2 GLP10-01-01-18-01 3 GLPi6-6l-6i-i8::6l 4 GLP10-01-01-18-01 5 GLP10-01-01-18-01 6 GLP10-01-01-18-01 7 GLP10-01-01-18-01 8 GLP10-01-01-18-01 9 GLP10-01-01-18-02 0 Solven tBlan k Solven tBIsn k 11003-26-1 1 Solven tBl3n k GLP10-01-01-18-02 1 GLP10-01-01-18-02 2 GLP10-01-01-18-02 3 GLP10-01-01-18-02 4 GLP10-01-01-18-02 5 GLP10-01-01-18-02 6 GLP10-01-01-18-02 7 GLP10-01-01-18-02 8 GLP10-01-01-18-02 9 Solven tBlan k Solven tBlan k 11003-26- 9 Solven tBlan k GLP10-01-01-18-03 0 GLP10-01-01-18-03 1 GLP10-01-01-18-03 2 GLP10-01-01-18-03 3 GLP10-01-01-18-03 4 GLP10-01-01-18-03 5 GLPI0-01-01-18-03 6 GLP10-01-01-18-03 7 GLP I 0-01-01-18-03 8 GLP I 0-01-01-18-03 9 Solven tBlan k Solven tBlan k 11003-26-1 0 Solven tBlan k GLP I 0-01-01-18-04 0 GLP I 0-01-01-18-04 1 GLP I 0-01-01-18-04 2 GLP I 0-01-01-18-04 3 GLP I 0-01-01-18-04 4 GLP I 0-01-01-18-04 5 GLP I 0-01-01-18-04 6 GLP I 0-01-01-18-04 7 GLP I 0-01-01-18-04 8 GLP I 0-01-01-18-04 9 Solven tBlen k Solven tBlen k 11003-26- 8 Solven tBlen k GLP I 0-01-01-18-05 0 GLP I 0-01-01-18-05 1 GLP I 0-01-01-18-05 2 GLP I 0-01-01-18-05 3 GLP I 0-01-01-18-05 4 GLP I 0-01-01-18-05 5 SC n 6-013T-18-05 6 GLP I 0-01-01-18-05 7 GLP I 0-01-01-18-05 8 Solven tBl3n k Solven tBIsn k 11003-26- 9 Solven tBl3n k GLP I 0-01-01-18-05 9 GLP I 0-01-01-18-06 0 GLP I 0-01-01-18-06 1 GLP I 0-01-01-18-06 2 Vis I Positio n 4 5 4 6 4 7 4 6 4 9 5 0 5 1 52 5 3 9 6 9 7 1 1 9 7 5 4 5 5 5 6 5 7 5 8 5 9 6 0 6 1 6 2 9 7 9 8 9 9 8 6 3 6 4 6 5 6 6 6 7 6 8 6 9 7 0 7 1 7 2 9 8 9 9 1 0



# ,

__| 7 3 7 4 7 5 76 77 78 7 9 8 0 8 1 82 9 9 10 0 8 100 8 3 84 85 8 6 8 7 8 8 8 9 9 0 1 6 100 9 1 9 9 1 1 7 1 8 1 9 2 0 Dat a RI e

k110715 a k11071S a k1ld715 a k110715 a k11071S 3 k110715 a k110715 a k11071S a k1107 1 S 3 k110715 3 k110715 3 kl10715 3 k110715 3 k110715 3 kl10715 3 kl10715 a kl10715 3 kl10715 3 kl10715 3 kl10715 3 kl107 1 S 3 kl107 1 S 3 ki10715 3 ki10715 3 ki10715 3 k i 10715 3 k11071S 3 k11071S 3 k11071S a k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k11071S 3 k110715 a k11071S a k110715 a k110715 3 k110715 a k110715 a k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k110715 a k11071S 3 k11071S a k110715 3 k11071S a k11071S a k110715 a k110715 3 k110715 3 k110715 a iiiiofis' a kl10715 a k110715 3 k l 10715 3 kl10715 3 kl10715 3 kl107 1 S 3 kl10715 3 k110715 3 kl10715 3 kl10715 3 k110715 3 Inj.Volum e (|il )

25.00 0 25.00 0 25.00 0 25.00 0 25.66 0 2500 0 25.00 0 25,00 0 25.00 0 25.00 0 25.00 0 25.00 0 2500 0 2500 0 2500 0 25.00 0 25,00 0 5.00 0 5.00 0 5.00 0 5.00 0 5.00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 5,00 0 5,00 0 5.00 0 5.00 0 5.00 0 25.00 0 25.00 0 25.00 0 25.00 0 5,00 0 5,00 0 5,00 0 5,00 0 5.00 0 25.00 0 25.00 0 25,00 0 25,00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 2566 6 5:60 b " 

### 5,66 6 5,00 0 5,00 0 5,00 0 25,00 0 25,00 0 25.00 0 25.00 0 5.00 0 5.00 0 5,00 0 5.00 0 Comment s

DA LGW130S 0 11063 0 (di l 1:10 ) D^ LG W130 S L S 11063 0 (di l 1:100 ) CV\LGW130 S M S 11063 0 (di l 1:100 ) DA LG W130 S H S 11063 0 (d j 1:100 ) DA LGW130 L0 11063 0 (di l 1:10 ) DI\ LG W130 LD B 11063 0 (d y1:10 ) O\LGW130 LLS11063 0 (di l 1:10 ) DA LGW130 LM S 11063 0 (di l 1:10 ) DA LGW130LH S 11063 0 (di l 1:10 ) Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 1 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTN11-023 4 DALGW131R 0 11062 2 (d J 1:100 ) D^ LGW131RD B 11062 2 (di l 1:100 ) D^LGW131RL S 11062 2 (di l 1:100 ) DALGW131RH S 11062 2 (di l 1:100 ) D^LGW131 S 0 11062 2 (di l 1:10 ) D^ LG W131 S D B 11062 2 (di l 1:10 ) DA LGW131 S L S 11062 2 (di l 1:10 ) DALGW131 S M S 11062 2 (di l 1:10 ) DA LG W131 S H S 11062 2 (di l 1:10 ) Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 2. 5 ng/m LF C st d i n Mill i Q Wate r Mil l Q W3te rTN11-023 4 Dl\LGW131L0110622(dil1:10 ) D^LGW131 LOB 11062 2 (di l 1:10 ) DA LGW131LL S 11062 2 (di l 1:10 ) D^LGW131 LM S 11062 2 (di l 1:10 ) Dl\LGW131LH S 11062 2 (di l 1:10 ) DA LGW133 L0 11063 0 (di l 1:10 ) DA LGW133LD B 11063 0 (di l 1:10 ) DA LG W133 LL S 11063 0 (di l 1:10 ) (3A LG W133 LM S 11063 0 (di l 1:10 ) DA LG W133 LH S 11083 0 (di l 1:10 ) Mill i QWete rTN11-023 4 Milli Q Wate rTN11-023 4 5. 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTN11-023 4 DALGW133S0110630(dil1:10 ) CWLGW133 S D B 11063 0 (di l 1:10 ) DA LG W133 S L S 11063 0 (di l 1:10 ) DA LG W133 S M S 11063 0 (di l 1:10 ) DA LG W133 S H S 11063 0 (di l 1 ; 10 ) DA LGW133R 0 11063 0 (di l 1:10 ) D»,LGW133RD B 11063 0 (di l 1:10 ) [3A LG W133 R L S 11063 0 (di l 1:10 ) DA LG W133 R M S 11063 0 (di l 1:10 ) DA LG W133 R H S 11063 0 (di l 1:10 ) Mlli Q Wate rTN11-023 4 Mil l QWete rTN11-023 4 1. 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTN11-023 4 QALGW134R 0 11062 8 (di l 1:100 ) DA LG W134 R D B 11062 8 (di l 1:100 ) DA LG W134 R L S 11062 8 (di l 1:100 ) QA LG W134 R H S 11062 8 (d J 1:100 ) DA LGW134 L0 11062 8 (di l 1:10 ) DA LGW134LD e 11062 8 (di l 1:10 ) DA LGW134LL S 11062 8 (di l 1:10 ) DA LG W134 LM S 11062 8 (di l 1:10 ) DA LG W134 LH S 11062 8 (di l 1:10 ) Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 2. 5 ng/m LF C st d i n Mill i Q Wate r Mill i QWste rTN11-023 4 DA LGW134 S 0 11062 8 DALGW134SD B 11062 8 DALGW134SL S 11062 8 DALGW134 S M S 11062 8 only.da m



### Printin g Time : 10:15:0 1 A M Printin g Date : Monday , Jul y18 , Pag e 2 o f 4

### *Kir) t BB2150101 0

Project : P:\PrDjectSLabJnarumen t Data\Kir1«Mikdata\Praiect!*fluorochemicals_waterBatcti:k110716 a Tab:Sampl e Set:SET 1 AcqMethod:PFOA Sampl e

143 14 4 i4 5 " ^ i4 6 f4 7 148 " 149 150 15 1 152 153 154 155 156 157 158 

# i!?Z I 160 16 1 162 163 " 16 4 165 " 166 T6 7 168 " " " 169 170 17 1 172 173 17 4 175 176 177 178 179 180 18 1 18 2 183

_„.... . T85 "" • 186 187 188 189 190 19 1 192 193 

# Ll^Z I 195 196 197 198 19 9 20 0 M l 202" " 20 3 20 4 |205^

_ 20 6 20 7 20 8 20 9 [21 0 21 1 21 2 21 3 Sampl e Nam e k l 107153143 k l 107153144 k l 107163145 kl10715314 6 kl10715314 7 k110715314 8 kl10715314 9 kl10715316 0 k110715a15 1 k110715a15 2 k110715a16 3 k110715a15 4 rkTl0715ai65 ~ k1107153l5 6 k1107153l5 7 k110715a15 8 k110715a15 9 k110715a16 0 

### ToioTTsaieT " k110715a16 2 k1107153l6 3 k110715a164 k110715a16 5 k110715a16 6 k1107153l6 7 k1107153l6 B k110715a16 9 k1107153l7 0 k110715a17 1 k110715a172 M<Tl67i53i73 ~ k110715a174 k110715a17 5 k110715a17 6 k1107153l7 7 k110716317 8 k110715317 9 k l 10715318 0 kl10715318 1 k l 107153182 kl10715318 3 k i 107153184 k l 10715318 5 k1107163l8 6 k110715318 7 kl10715318 8 kl10715318 9 k110715a19 0 k110715319 1 k110715319 2 li(iT07T53i93 ~ kl10715319 4 

### liciToTissisT

s k l 10715319 6 kl10715319 7 kl10715319 8 liciToTTSiigg " kii67i5a26 6 kl10716320 1 k l 107163202 Iiii67i5326 3 kl10715320 4 MclJOTIS^O S k110715320 6 ^k110715320 7 kl10715320 8 T<iT67i5320 9 k110715a21 0 k l 10715321 1 k110715321 2 

### ^j^___

_ Ssmpl e I D

GLP I 0-01-01-18-06 3 GLPlO-01-01-1 8 664" " GLP I 0-01-01-18-06 5 GLP I 0-01-01-18-06 6 GLP I 0-01-01-18-06 7 GLP10-01-01-18-06 8 Solven tBlsn k So^/en tBlsn k 11003-26-1 1 Solven tBlan k GLP I 0-01-01-18-06 9 GLP I 0-01-01-18-07 0 GLP I 0-01-01-18-07 1 GLP I 0-01-01-18-07 2 GLP I 0-01-01-18-07 3 GLP I 0-01-01-18-07 4 GLP I 0-01-01-18-07 5 GLP I 0-01-01-18-07 6 GLP I 0-01-01-18-07 7 GLP I 0-01-01-18-07 8 Solven tBlan k Solven tBlan k 11003-26-1 0 Solven tBlan k GLP I 0-01-01-18-07 9 [GI£10-01l-01-18-08 0 GLP I 0-01-01-18-08 1 GLP I 0-01-01-18-08 3 GLP I 0-01-01-18-08 4 GLP I 0-01-01-18-08 6 GLP I 0-01-01-18-08 6 GLP I 0-01-01-18-15 5 GLP I 0-01-01-18-08 7 Solven tBlan k Solven tBlsn k 11003-26- 8 Solven tBlan k GLP I 0-01-01-18-08 8 GLP I 0-01-01-18-08 9 GLP I 0-01-01-18-09 0 GLP I 0-01-01-18-09 1 GLP I 0-01-01-18-09 2 GLP I 0-01-01-18-09 3 GLP I 0-01-01-18-09 4 GLP I 0-01-01-18-09 5 GLP I 0-01-01-18-09 6 GLP I 0-01-01-18-09 7 Solven tBlan k Soh/en tBlsn k 11003-26- 9 Solven tBlan k GLP I 0-01-01-18-09 8 GLP I 0-01-01-18-09 9 GLP I 0-01-01-18-10 0 

### lGiJio;6T:6w8;To i GLP I 0-01-01-18-10 2 GLP I 0-01-01-18-10 3 GLP I 0-01-01-18-10 4 GLP I 0-01-01-18-10 6 GLPi6-6l-01-ie-i6 6 GLP I 0-01-01-18-10 7 Solven tBlan k Solven tBlan k 11003-26-1 1 Solven tBlan k GLP I 0-01-01-18-10 8 GLRO-01-01-18-10 9 GLP I 0-01-01-18-11 0 GLP I 0-01-01-18-11 1 GLP I 0-01-01-18-11 2 GLP I 0-01-01-18-11 3 Via l Positio n 2 1 Data Fil e

'k l 167153 ' 2 2 kl10715 a 2 3 kl10715 3 2 4 kl10715 3 2 5 kl10715 a 2 6 kl10715 a 9 1 !k110716 a 9 3 ikli6715 3 f l l

' M 2 7 2 8 2 9 30 

### t3 i 32 33 34 35 36 9 3 9 4 1 0 94 37 38 kl10715 a

kl10715 a kl10716 a k110716 s kl10715 a k110715 s k110715 a k110715 3 

### triOTil a k110715 a k110715 a k110716 s k110715 3 k110715 s k110715 a k110715 a kl10715 s k110715 3 3 9 k110715 3 4 0 ^4 1 4 2 4 3 4 4 k110715 3

k110715 3 k110715 3 k110715 3 k110715 3 4 5 ik110715 a 9 4 |k110715 a 9 5 |k110715 a 8 |k110715 a 9 5 ;k110715 a 4 6 Ik110715 a 4 7 kl10715 3 4 8 kl10715 3 4 9 kl10715 3 5 0 kl10715 3 5 1 k110715 3 ^•5 2 ' " "k l 10715a ' 5 3 54 55 9 5 9 6 9 9 6 5 6 5 7 6 8 5 9 6 0 6 1 6 2 6 3 6 4 

### kli67i5 s

k110715 a k110715 a kl10716 a k110715 a k110715 3 k110715 a kl10715 3 kl10715 s k110716 3 kl10715 3 k110715 s kl10715 3 kl10715 3 k1107i5 3 k110716 3 6 5 i|<il07i5 a 9 6 9 7 1 1 9 7 6 6 6 7 6 8 6 9 7 0 k110715 a

k1107i5 s k110716 3 k110715 a k110715 s kl10715 a k110715 s k110715 a k110715 a 7 1 ;k110715 3 Inj.Volum e ||il ) 5 00 0 2 5 00 6 2 5 00 0 2 5 00 0 5 00 0 2 5 00 0 "26.00 0 26.00 0 25.00 0 25.00 0 5.00 0 5.00 0 6.00 0 5.00 0 6 m i 

# l _

_ 

# , 25,00 0 25.00 0 25.00 0 2 5 00 0 2 5 00 0 2 5 00 0 2 5 00 0 2 5 00 0 2 5 00 0 25,00 0 25,00 0 25.00 0 5,00 0 5.00 0 5.00 0 5.00 0 5.00 0 25.00 0 25.00 0 25.00 0 '2500 0 ' f^g

_ 25.00 0 26.00 0 2 6 00 0 2 5 00 0 2 5 00 0 2 5 00 6 25.00 0 25.00 0 26,00 0 "26,00 0 25.00 0 25.00 0 25.00 0 25.00 0 26.00 0 26,00 0 '2566 6 25.00 0 26,00 0 25,00 0 25,00 0 26,00 0 125,66 6 25.00 0 25.66 6 25.00 0 25.00 0 

## £??5

_ teioo" 25.00 0 26.00 0 25.00 0 5.00 0 Comment s

DALGW134SH S 11062 8 Tri p Blsn k

Set1 Ssmpl e Tri p Blan k

Set1 LS Tri p Blan k

Set1 M S Tn p Blan k

Set1 MHS Tri p Blan k

Set1 HS (di l 1 100) Milli Q Wate rTN11-0234 Mill i Q Wate rTN1 1 -023 4 _]] j 1 0 ng/m LF

C st d i n Mill i Q Wate r Milli Q Wate rTN11-0234 DA LGW135S 0 11062 8 DALGW135SD B 11062 8 DA LGW135 S LS11062 8 (aALGW135 S M

S 11062 8 DALGW135SH S 11062 8 DA LG W135 L0 11062 8 (di l 1:10) DA LG W135 L1 » 11062 8 (di l 1:10) QALG W136 LLS 11062 8 (di l 1:10) DA LG W135 LM

S 11062 8 (di l 1:10) (3ALG W136 LHS 11062 8 (di l 1 10) Mil l Q Wate rTN11-0234 Mil l Q Wafe rTN11-0234 5 0 ng/m LF

C st d i n Mill i Q Wate r Milli Q Wate rTN11-0234 DALGW135R0110628(dll 1 100) DA LG W135 R DB 11062 8 (di l 1:100) DA LG W135 R LS 11062 8 (di l 1:100) DA LG W135 R HS 11062 8 (di l 1:100) DA LG W136 L0 110630 (di l 1:10) DA LG W136 LDB 11063 0 (di l 1:10) DA LGW136LL S 11063 0 (di l 1:10) DA LG W136 LM

S 11063 0 (di l 1:10

) DA LG W136 LHS 110630 (di l 1:10) Mill i QWste rTN11-0234 Mill i QWsterTN l 1-023

4 1. 0 ng/m LF

C st d i n Mini Q Wste r Mill i QWste rTN11-0234 DA LGW136 S 011063 0 (di l 1:10) DA LG W136S DB 11063 0 (di l 1:10) DALGW136 S LS 11063 0 (di l 1:10) DA LGW136 S M

S 110630 (di l 1 10) DA LG W136S HS 11063 0 (di l 1 10) DA LGW137S 0 110624 DALGW137SDB11062 4 DALG'wi"37SL S 11062 4 DALGW137SMS11062 4 DA LGW137SH S 110624 Mill i QWste rTN11-0234 MQ"VtoterTNT^023 4 1 2. 5 ng/m LF

C st d i n Mill i Q Wste r Mill i QWste rTN11-0234 DA LGW137 L011062 4 DA LGW137L(3 B 110624 pAiGv\M3na£i ^ j DALrGW137LWTi062 4 | DALGW137LHS11062 4 DA LGW138R0.11063 0 (di l 1:10) DA LG W138 R DB 110630 (di l 1:10) (3ALGW138RL S 11663 6 (di l 1:10) DA LGW138 R M

S 110630 (di l 1:10

) DA LG Wi38 R i«li663 6 ((1iii:l6 j Mill i QWste rTN11-0234 Mlli Q Wate rfNii-623 4 1 0 ng/m LFCst d i n Mlli Q Wate r IM^Vteltel^NI^^O^ ^ DSTGWISSTOTTOS O j DALGW138LD611063 0 DA LGW138 LLS11063 0 1 DALGW138LMS11063 0 DA LGW138LH S 110630 OM

- G W138S 0 11063 0 (di l 1:10) only.da m



### Printin g Time : 10:15:0 1 A M Printin g Date : Monday , Jul y1 8 Pag e 3 o f 4

### »Kir) t BB2150101 0

Project : P:\Project^ab_lnstmmentData\Kir1(\Mrkdata\ProjectSVfluorochemlcals_waterBatcti:k110715 a Tab:Sampl e Set:SET 1 AcqMettiod:PFOA Sampl e

21 4 21 5 "21 6 " ^ 21 7 2i 8 "21 9 22 0 "22"i ' " " 22 2 22 3 22 4 22 5 22 6 22 7 22 8 22 9 23 0 23 1 23 2 23 3 23 4 23 5 23 6 " " 23 7 238" " "239 " • 24 0 24 1 24 2 24 3 24 4 24 5 24 6 24 7 24 8 , 24 9 26 0 25 1 252' ! 25 3 i254"" ' • 25 5 256^ 25 7 25 8 25 9 26 0 26 1 26 2 26 3 26 4 26 5 26 6 26 7 26 8 26 9 27 0 2'7 1 " " [272 27 3 27 4 Sampl e Nam e kl10715321 4 kl10715321 5 k110715321 6 kl10715321 7 kl10715321 8 kl10716321 9 kl10715322 0 "kli07i632"2 1 k110715322 2 k110716322 3 k110715322 4 kl10715322 5 kl10715322 6 k110715s22 7 k110715322 8 k110715a22 9 k110716323 0 kl10715323 1 k1107153232 k110715a23 3 k110715a234 k110715a23 5 k110715s23 6 k110fl5""s23 7 k110715a23 8 kl10715323 9 kl10715324 0 k110715324 1 kl10715324 2 kl10716324 3 kl10715324 4 k110715s24 5 kl10715324 6 kl10715324 7 kl10715324 8 kl10715324 9 kl10715325 0 kl10715325 1 kl10715325 2 kl10715325 3 k i 167163254 kl10715325 5 kl10715325 6 kl10716325 7 k110715325 8 k110715s25 9 k110716326 0 1(110716326 1 kl10715326 2 k110715s26 3 k110715326 4 kl10715326 5 kl10715326 6 k110715326 7 k110715326 8 kl10715326 9 k110715327 0 k110715s27 1 k110715s2"7

2 kl10716327 3 kl10715327 4 Sampl e I D | Via l Positio n

GLP I 0-01-01-16-11 4 GLP I 0-01-01-18-11 5 GLP I 0-01-01-18-11 6 GLP I 0-01-01-18-11 7 Solven tBlsn k Solven tBlsn k 11003-26-1 0 Solven tBlsn k GLP I 0-01-01-18-11 8 GLP I 0-01-01-18-11 9 GLP I 0-01-01-18-12 0 GL H 0-01-01-18-12 1 GLP I 0-01-01-18-12 2 GLP I 0-01-01-18-12 3 GLP I 0-01-01-18-12 4 GLP I 0-01-01-18-12 5 GLP I 0-01-01-18-12 6 GLP1 0 0 1 0 1 1 8 12 7 Solven tBlsn k Solven tBlsn k 11003 2 6 8 Solven tBlsn k GLP1 0 0 1 o i 1 8 133 GLF10-01-01-18-13 4 GLP10-01-01-18-12 8 GLP I 0-01-01-18-12 9 GLP I 0-01-01-18-13 0 GLP I 0-01-01-18-13 1 GLP I 0-01-01-18-13 2 Solven tBlsn k Solven tBlsn k 11003-26- 9 Solven tBlsn k GLP I 0-01-01-18-13 5 GLP I 0-01-01-18-13 6 GLP I 0-01-01-18-13 7 GLP I 0-01-01-18-13 8 GLP I 0-01-01-18-13 9 GLP I 0-01-01-18-14 0 GL H 0-01-01-18-14 1 GLP I 0-01-01-18-14 2 GLP I 0-01-01-18-14 3 GL H 0-01-01-18-14 4 Solven tBlsn k Solven tBlan k 11003-26-1 1 Solven tBlan k GLP I 0-01-01-18-14 5 GLP I 0-01-01-18-14 6 GLP I 0-01-01-18-14 7 GLP I 0-01-01-18-14 8 GLP I 0-01-01-18-14 9 GLP I 0-01-01-18-15 0 GLP I 0-01-01-18-15 1 GLP I 0-01-01-18-16 2 GLP I 0-01-01-18-15 3 GLP I 0-01-01-18-15 4 Solven tBlan k Solven tBlsn k 11003-26-1 0 Solven tBlan k 72 7 3 7 4 7 5 9 7 9 8 1 0 9 8 7 6 7 7 7 8 7 9 8 0 8 1 82 8 3 8 4 OstsHl e i Inj.Volum e (|il ) Comment s

k l 10715 a k l 10716 3 "kli07r5 3 k l 10716 3 Ik l 167153 k110716 3 kl10715 3 kiiotis s k l 10715 a kl10715 3 kl10715 a kl10715 a k l 10715 3 £n0i715s_

_ 

## £1!?Z1£!L_

_ kl10716 3 k110716 3 85 kl10715 a 9 8 [k110715 3 9 9 8 9 9 8 6 6 7 8 8 8 9 9 0 1 6 1 7 9 9 100 9 100 1 8 1 9 2 0 2 1 2 2 2 3 2 4 2 5 2 6 2 7 100 9 1 1 1 9 1 2 8 2 9 30 3 1 32 33 3 4 35 3 6 37 9 i 9 1 

## i o 9 3 5,00 0 5.00 0 6.00 0 1 6.00 0 26,00 0 2500 0 25,00 0 26,00 0 5,00 0 5;o5 6 ' 5.00 0 5.00 0 5.00 0 5.00 0 5.00 0 6.00 0 5.00 0 5 00 0 2 6 66 5 k110715 a 2500 0 k l 10715 a j 2 6 00 0 k110715 a k110715 s k110715 s kli67i5 3 fei67i"53 kl10715 3 k110715 s k110715 s k110716 3 kl10715 3 k110715 s k110715 s kl10715 s k110715 s kl10715 s k110715 3 kl10715 3 k110715 3 k110715 s k110715 3 kiioHs s icii67i5 s k110715 3 kl10715 s kl10716 3 k110715 s k110715 s k110716 3 k110715 3 k110715 s k110715 3 kl10715 s kl10715 3 kl10715 3 k110715 s k110715 s IciiO^iS a kil0715 s "k1l67i5 3 J k110715 a 2 5 00 0

2 5 00 0 25.00 0 6.00 0 5.66 6 5.00 0 5.00 0 5.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 5.00 0 5.00 0 5.00 0 5.00 0 5.00 0 5.6oo"" " " 5.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 26,00 0 25.00 0 25.00 0 5.00 0 5.00 0 5.00 0 5.00 0 5.00 0 25.00 0 25.00 0 25.60 0 25.00 0 DA LGW138SD B 11063 0 (di l 1:10)

DA LG W138S LS 11063 0 (dJ 1:10) DALGW138 S M

S 11063 0 (di l 1:10) DALGW138 S HS 11063 0 (di l 1:10) Mi l Q Wate rTN11-0234 Mlli Q Wate rTN11-0234 5. 0 ng/m LF

C st d i n Mil l Q Wate r Mlli Q Wate rTN11-0234 DA LGWCW26 C 0 110622 (di l 1:10) DA LGWCW26CD B 110622 (di l 1:10) DALGWCW26CL S 110622 (di l 1:10) DA LGWCW26 C M

S 110622 (di l 1:10) DA LGWCW26CH S 110622 (di l 1:10) DA LGWCW26L 0 110622 (di l 1:10 ) DA LGWCW26 LD B 110622 (di l 1:10 ) DA LGWCW26 LLS 110622 (di l 1:10 ) DA LGWCW26 LM

S 110622 (di l 1:10) DA LGWCW26LH S 110622 (dil l 10) Mil l Q Wate rTN1 1 023 4 Mil l Q Wate rTN1 1 023 4 1 0 ng/m LF

C st d i n Mil l Q Wate r MDl Q Wate rTN1 1 023 4 (iALGW130LRBTT063 0 DALGW133SRB11063 0 DA LGW140R 0 110622 (di l 1:10) "DA LG Wi46R"D B ii662 2 (di l i:l6 ) DA LGW140RL S 110622 (di l 1:10) DA LGW140 R M

S 11062 2 (di l 1:10

) DA LGW140RH S 11062 2 (di l 1:10 ) Mi l Q Wate rTN11-0234 MHi Q Wate rTN11-0234 2. 5 ng/nl

. F

C st d i n Mll i Q Wste r Mil l QWste rTN11-0234 DA LGW141R 0 11063 0 DALGW141RDB11063 0 DA LGW141RL S 110630 DA LGW141RM S 11063 0 QALGW141RH S 11063 0 (di l 1:10 ) DA LGW142R 0 110622 (di l 1:10) DA LGW142RD B 11062 2 (di l 1:10 ) DALGW142RL S 110622 (di l 1:10) DA LG W142 R M

S 11062 2 (di l 1:10

) DALGW142RH S 11062 2 (di l 1:10 ) Mll i QWste rTN11-0234 Mll i QWste rTN11-0234 1 0 ng/m LF

C st d i n Mll i Q Wste r Mll i QWste rTN11-0234 DALGW143R 0 110622 (di l 1:10) DA LGW143RD B 110622 (di l 1:10) DALGW143RL S 110622 (di l 1:10) DA LG W143 R M

S 110622 (di l 1:10

) DA LGW143RH S 110622 (di l 1:10) DA LG W144S 0 11062 8 (di l 1:10) DA LG W144S D B 11062 2 (di l 1:10 ) DA LG W144S LS 11062 2 (di l 1:10) DA LGW144 S M

S 110622 (di l 1:10

) DALGW144 S HS 110622 (di l 1:10) Mll i Q Wste rTOI i-0"234 Mll i QWste rTN11-0234 5. 0 ng/m LFC st d i n Mil l Q Wste r Mll i QWste rTN11-0234 

# Ru n sVDpp^c i oASavnpl c\<.i\oil6a241

. - 5 K\\oni5o{2MM , tV^6-sampl e HAm e ^M0. ^ chc^ng ^ only.da m



# >i-arfin Q a tsajmple

. 

# d an d fh tru o 

# l^a s

Printin g Tiine : 10:15:0 1 A M Printin g Date : Monday , Jul y18 , 201 1 Pag e 4 o f 4

### *Kirl c BB21S0101 0

Prajed : P:\Proiects\LabJnslrumen tData\Klrt4Mri<data\Projectafluorachemicals_waterBalch:k110715 a Tab:Sampl e Set:SET 1 AcqMethod:PF C Sampl e

1 2 3 4 5 " " " " 6 7 "8 " 9 1 0 1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 " i2 5 2 6 2 7 

# b e 2 9 3 0 3 1 3 2 3 3 34 35 3 6 3 7 3 8 3 9 4 0 4 1 4 2 43 " 44 4 5 46 4 7 4 8 4 9 5 0 5 1 5 2 5 3 54 1 55 5 6 5 7 5 8 " " " ' 5 9 6 0 6 1 6 2 "63 " 6 4 65 6 6 6 7 6 8 6 9 7 0 7 1 Sampl e Nam e

k110715a00 1 k110715a00 2 k110715s00 3 k110715s00 4 k110715a00 5 kii67i5a66" 6 k110715a00 7 kil67i5a66 8 k110715a00 9 k110715301 0 k110715301 1 k110715s01 2 k110715301 3 k110715301 4 k110715s01 5 k110715s01 6 kl10715301 7 k110715301 8 kl10715301 9 k110715302 0 k110715302 1 k110716302 2 k l 10715302 3 k110715302 4 ki10715302 5 k110715s02 6 kl10716302 7 kl10715302 8 k l 10715302 9 k l 10715303 0 k l 10715303 1 k l 10715303 2 k110715s03 3 kl10715303 4 k110715a03 5 k110715a03 6 k110715303 7 k110715303 8 k110715s03 9 kl10715304 0 

### kii67i5s64 i k110715a04 2 k110715a04 3 k110715s04 4 k110715a04 5 k110715a04 6 k110715304 7 k110715a04 8 k110715304 9 k110715a05 0 k110715a06 1 k110715s05 2 k110715s05 3 k110715a05 4 k110715s05 5 k110715305 6 k110715a06 7 k110715a05 8 kl10715305 9 k110715306 0 k110715306 1 k110715a06 2 )c110715a66 3 k110715B06 4 k110715s06 5 k110715a06 6 kl10715306 7 kl10715306 8 kl10715306 9 k110715a07 0 kl10716307 1 Ssmpl e I D

Solven tBlan k Solven tBlan k 11003-26- 8 Solven tBlsn k 11003-26- 9 11003-26- 9 11003-26- 9 11003-26- 9 Solven tBlsn k Solven tBlsn k 11003-26- 1 11003-26- 2 11003-26- 3 11003-26- 4 11003-26- 5 11003-26- 6 11003-26- 7 11003-26- 8 11003-26- 9 11003-26-1 0 11003-26-1 1 11003-26-1 2 11003-26-1 3 11003-26-1 4 11003-26-1 5 Solven tBlan k Soh/en tBlsn k Solven tBlsn k Solven tBlsn k LCS-110714- 1 LCS-110714- 2 LCS-110714- 3 LCS-110714- 4 LCS-110714- 5 LCS-110714- 6 LCS-110714- 7 LCS-110714- 8 LCS-110714- 9 Solven tBlsn k Solven tBlsn k 11003-26-1 0 Solven tBlsn k LCS-110714-1 0 LCS-110714-1 1 LCS-110714-1 2 LCS-110714-1 3 LCS-110714-1 4 LCS-110714-1 5 LCS-110714-1 6 LCS-110714-1 7 LCS-110714-1 8 Solven tBlan k Solven tBlsn k 11003-26- 9 Solven tBlsn k Solven tBlsn k GLP I 0-01-01-18-00 1 GLP I 0-01-01-18-00 2 GL"P10-"0l"-6i-i8-"66 3 GLPi6-6i-6i-i8-66 4 GLP I 0-01-01-18-00 5 GLP I 0-01-01-18-00 6 GLP I 0-01-01-18-00 7 GLP1O-01-01-18-00 8 GLP I 0-01-01-18-00 9 GLP I 0-01-01-16-01 0 Solven tBlsn k Solven tBlsn k 11003-26-1 0 Solven tBlsn k GLP10-01-01-18-01 1 Via l Positio n 9 1 9 1 8 9 1 9 " 9 9 9 9 1 9 2 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 

### i 3 1 4 '1 5 9 2 9 2 9 3 9 3 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 9 3 94 

## i 6 94 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 33 9 4 94 9 9 5 9 5 34 35 3 6 3 7 3 8 3 9 4 0 4 1 42 4 3 9 5 9 6 1 0 9 6 4 4 Dat a Fil e

kl10715 3 kl10715 3 k110715 3 kl10715 s kl10715 s kl10715 3 k110716 3 kl10715 a kl10715 a kl10715 3 kl10715 3 kl10715 s kl10715 3 kl10715 3 kl10715 3 kl10715 s kl10715 3 kl10715 3 kl10715 s kl10715 s kii67i5 3 kl10715 3 kl10715 s kl10715 s k110715 3 k110715 3 k110715 3 k110715 s k110715 3 k110715 3 k110715 s k110715 s kl10715 3 kl10715 3 kl10715 3 kl10715 3 kl10715 3 k110715 a kl10715 3 kl10715 a kl10715 3 k110715 3 kl10715 3 k110715 3 k110715 s kl10715 3 kl10715 s kl10715 s kl10715 s k110715 3 kl10715 3 kl10715 s kl10715 s k l 10715 3 kl10715 a kl10715 3 k110715 3 k110715 s k110715 3 kl10715 s kl10715 s kl10715 3 kl10715 s kl10715 s k110715 s kl10715 3 

# ^___

_ kl10715 a k110715 a kl10715 a kl10715 a Inj.Volum e (|jl )

25.00 0 26.00 0 i25.606 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25,00 0 25,00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.6o 6 26.00 0 5.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 Comment s

Mlli Q Wate rTN11-023 4 Mlli Q Wate rTN11-023 4 1. 0 ng/m LF C st d i n Mll i Q Wate r Mli Q Wate rTN11-023 4 2. 5 ng/m LF C st d i n Mll i Q Wste r 2. 5 ng/m LF C st d i n Mil l Q Wste r 2. 5 ng/m LF C st d i n Mll i Q Wste r 2. 5 ng/mi l F C st d I n Mil l Q Wste r Mli Q Wste rTN11-023 4 Mll i QWste rTN11-023 4 0.02 5 ng/m LF C st d i n Mill i Q Wste r 0.0 3 ng/m LF C st d i n Mill i Q Wste r 0,0 4 ng/m LF C st d i n Mll i Q Wate r 0,0 5 ng/m LF C st d i n Mll i Q Wate r 0, 1 ng/m LF C st d i n Mll i Q Wate r 0,2 6 ng/m LF C st d i n Mil l Q Wate r 0 6 ng/m LF C st d i n Mll i Q Wate r 1, 0 ng/m LF C st d i n Mll i Q Wate r 2, 5 ng/m LF C st d i n Mll i Q Wate r 5, 0 ng/m LF C st d i n Mill i Q Wste r i o ng/m LF C st d i n Mli i Q Wate r 2 5 ng/m LF C st d i n Mi l Q Wste r 5 0 ng/m LF C st d i n Mff l Q Wste r 7 5 ng/n tF C st d i n MH i Q Wste r 10 0 ng/m LFCst d i n M B Q Wste r M l QWste rTN I i-0234 " Mll i QWste rTN11-023 4 Mll i QWste rTN11-023 4 Mli Q Wste rTN11-023 4 0,6pp b LC S 0.5pp b LC S 0.5pp b LC S Spp b LC S Spp b LC S Spp b LC S 30pp b LC S 30pp b LC S 30pp b LC S Mil l QWste rTN11-023 4 Mll i QWste rTN11-023 4 5. 6 ng/r« LFCstc i i n Mli i Q Wste r Mi l QWsterTN l 1-023 4 O.Spp b LC S EC F O.Spp b LC S EC F 0.5pp b LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F Mll i QWste rTN11-023 4 Mll i QWste rTN11-023 4 2. 5 ng/m LF C st d i n Mll i Q Wste r Mi l QWste rTN11-023 4 Mli Q Wate rTN11-023 4 Tri p Blan k

Se t2 Ssmpl e Tri p Blsn k

Se t2 L S Tri p Blan k

Se t2 M S Tri p Blsn k

Se t2 MH S Tri p Blsn k

Se t2 H S (di l 1:100 ) DA LG W130 R 0 11063 0 (di l 1:100 ) DA LG W130 R D B 11063 0 (di l 1:100 ) t:iALGW130RL S 11063 0 (di l 1:100 ) DALGW130RM S 110630(di l 1:100 ) DA LG W130 R H S 11063 0 (di l 1:100 ) Mlli Q Wate rTN11-023 4 Mi l QWste rTN11-023 4 5. 0 ng/m LF C st d i n Mll i Q Wste r Mi l QWste rTN11-023 4 DA LG W130 S 0 11063 0 (di l 1:10 )



# , ) Aonly.da m



### Printin g Time : 9:30:4 2 A M Printin g Date : Tuesday , Jul y19 , 201 1 Pag e1 o f 4 

# c^ e lll^/l l

### •Kiri c BB2150101 0

Projed : P:\ProjectilLabJnslmmen t Data\Kir14Wrtidata\Projectafluorocliemlcals_walerBatch:k110715 a Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m Sampl e

72 73
7 4 "75 7 6 7 7 7 8 7 9 8 0 8 1 82 83 84 8 5 8 6 8 7 8 8 8 9 9 0

9 1 9 2 ~ 9 3 9 4 9 5 9 6 9 7 9 8 9 9 100 10 1 102 103 10 4 105 106 107 108 109 110 ^ 11 1 11 2 11 3 11 4 11 5 11 6 11 7 11 8 11 9 12 0 12 1
12 2 12 3 1 124 125 12 6 

## Tjr ^ 128" 12 9 " 130 13 1 '13 2 ' " 13 3 134 " 135 136 137 138 139 140 14 1 142 Sampl e Nam e k l 107153072 k11071Sa073 kl10715307 4 k11071Sa075 k110715307 6 k110715307 7 kl10715307 8 Ikil67i5s67 9 k l 10716308 0 k110716308 1 k l 107153082 k110715308 3 k l 107153084 k110715308 5 k l 10715308 6 k l 10715308 7 kl10715308 8 kl10715308 9 k110715s09 0 kl10715309 1 k110715309 2 kl10716309 3 k110715309 4 i(ii67 i 5309 5 k110715309 6 k11071Ss09 7 k11071Sa09 8 k11071Sa09 9 k11071S3l0 0 k11071Ss10 1 k1107163l0 2 k1107163l0 3 k l 107153104 k l 107153105 kl10715310 6 kl10715310 7 kl10715310 8 kl10715310 9 k1107153l1 0 k110715s11 1 k110715s11 2 k110715s11 3 k110715s11 4 k110715s11 S k110715s11 6 k110715s11 7 k1107153l1 8 k110715s11 9 k110715s12 0 k11071Ss12 1 k11071Ss12 2 k11071Ss12 3 k11071Ss12 4 k1107153l2 5 k1107153l2 6 k110715s12 7 k110715s12 8 k l 10715312 9 k110715s13 0 k l 10716313 1 kli67i53i3 2 k1107153l3 3 k1107153l3 4 k11071Ss13 S k110715s13 6 k11071Sa13 7 k11071Ss13 8 k11071Ss13 9 kl10715314 0 k1107163l4 1 kl10716314 2 Ssmpl e I D

GLP I 0-01-01-18-01 2 GLP I 0-01-01-18-01 3 GLP I 0-01-01-18-01 4 GLP I 0-01-01-18-01 5 GLP I 0-01-01-18-01 6 GLP I 0-01-01-16-01 7 GLP I 0-01-01-18-01 8 GLP I 0-01-01-18-01 9 GLP I 0-01-01-18-02 0 Solven tBlsn k Solven tBlsn k 11003-26-1 1 Solven tBlsn k GLP I 0-01-01-18-02 1 GLP I 0-01-01-18-02 2 GLP I 0-01-01-18-02 3 GLP I 0-01-01-18-02 4 GLP I 0-01-01-18-02 5 GLP I 0-01-01-18-02 6 GLP I 0-01-01-18-02 7 GLP I 0-01-01-18-02 8 GLP I 0-01-01-18-02 9 Solven tBlsn k Solven tBlsn k 11003-26- 9 Solven tBlsn k GLP I 0-01-01-18-03 0 GLP I 0-01-01-18-03 1 GLP I 0-01-01-18-03 2 GLP I 0-01-01-18-03 3 GLP I 0-01-01-18-03 4 GLP I 0-01-01-18-03 5 GLP I 0-01-01-18-03 6 GLP I 0-01-01-18-03 7 GLP I 0-01-01-18-03 8 GLP I 0-01-01-18-03 9 Solven tBlsn k Solven tBlsn k 11003-26-1 0 Solven tBlsn k GLP I 0-01-01-18-04 0 GLP I 0-01-01-18-04 1 GLP I 0-01-01-18-04 2 GLP I 0-01-01-18-04 3 GLP I 0-01-01-18-04 4 GLP I 0-01-01-18-04 5 GLP I 0-01-01-18-04 6 GLP I 0-01-01-18-04 7 GLP I 0-01-01-18-04 8 GLP I 0-01-01-18-04 9 Solven tBlsn k Solven tBlsn k 11003-26- 8 Solven tBlsn k GLP I 0-01-01-18-05 0 GLP I 0-01-01-18-05 1 GLP I 0-01-01-18-05 2 GLP I 0-01-01-18-05 3 GLP I 0-01-01-18-05 4 GLP I 0-01-01-18-05 6 GLPi"6-6i-61-18-65 6 GL H 0-01-01-18-05 7 GLP I 0-01-01-18-05 8 Solven tBlsn k Solven tBlsn k 11003-26- 9 Solven tBlsn k GLP I 0-01-01-18-05 9 GLP I 0-01-01-18-06 0 GLP I 0-01-01-18-06 1 GLP I 0-01-01-18-06 2 VIs I Positio n 4 5 4 6 4 7 4 8 4 9 S O 5 1 62 5 3 9 6 9 7 1 1 9 7 54 55 5 6 5 7 5 8 5 9 6 0 6 1 62 9 7 9 8 9 9 8 6 3 6 4 6 6 6 6 6 7 6 8 6 9 7 0 7 1 72 9 8 9 9 1 0 9 9 1 7 3 7 4 7 5 7 6 7 7 78 79 8 0 8 1 82 9 9 100 8 100 83 84 85 8 6 8 7 8 8 8 9 9 0 

### i 6 100 9 1 9 9 1 1 7 1 8 1 9 2 0 Dat a Fil e

k l 10715 a kl10715 3 kl10715 3 kl10715 3 k l 10715 3 kl10715 3 kl10715 3 kl10715 s kl10715 3 kl10715 3 kl10715 3 k l 10715 s kl107 1 S 3 k110715 s kl10715 3 kl10715 3 kl10715 3 k110715 s k110715 a k110715 3 k11071S a k11071S a kl107 1 S 3 kl10715 8 k11071S a kl10715 s kl10716 3 kl10715 3 k l 10715 s k l 10715 3 k11071S s k11071S s k l 10716 3 kl10715 3 M10716 3 kl10715 3 kl10715 3 k110715 s k l 10715 3 k110715 3 

### iciiofis s k l 10715 s k l 10715 3 k l 10716 3 kl10715 3 k110715 s k110715 3 k110715 s k110715 3 k110715 s k110716 3 k110715 3 kl10715 s kl10715 s kl10715 3 k110715 3 k110715 s kil0"7"i"5"3 " k110716 3 kllOtiS s k"ii67i5 3 k l 10715 s i<i i 6715 3 k110715 3 kl10715 3 k110715 s kl10715 3 k110715 3 k110715 a k11071S a k11071S a lnj.Volum e (|il )

25,00 0 25.00 0 26.00 0 25.66 6 25.00 0 25.60" 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 5.00 0 6.00 0 5.00 0 5.00 0 5.00 0 25.00 0 25.00 0 25.66 6 26.66 6 26.00 0 25.00 0 25.00 0 26,00 0 25,00 0 5,00 0 5,00 0 5,00 0 5.00 0 5.00 0 25,00 0 25,00 0 25,00 0 25,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 25,00 0 25,00 0 25,00 0 25.00 0 25.00 0 25.00 0 25,00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 6.00 0 5.00 0 5.00 0 5.00 0 5.00 0 26.00 0 26.00 0 26.00 0 25.00 0 6.00 0 6.00 0 5.00 0 5.00 0 Comment s

DA LG W130 S 0 11063 0 (di l 1:10 ) DA LG W130 S L S 11063 0 (di l 1:100 ) DALGW136 S M S 110636(cii l i:i66 j DALGW130SH S 11063 0 (di l 1:100 ) DALGW130L0110630(dil1:10 ) DA LG W130 LD B 11063 0 (di l 1:10 ) DA LG W130 LL S 11063 0 (di l 1:10 ) DA LG Wi36 LiVI S i 1063 6 (cii i i: i 6 ) DA LG W1 SO LH S 11063 0 (di l 1:10 ) Mlli Q Wate rTN11-023 4 Mlli Q Wate rTN11-023 4 1 0 ng/m LF C st d i n Mi l Q Wate r Mli Q Wate rTN11-023 4 DA LGW131R 0 11062 2 (di l 1:100 ) DALGW131RD B 11062 2 (di l 1:100 ) DA LG W131 R L S 11062 2 (di l 1:100 ) DALGW131RHS110622(di l 1:100 ) DA LGW131 S 0 11062 2 (di l 1:10 ) DA LG W131 S D B 11062 2 (di l 1:10 ) DALGW131 S L S 11062 2 (di l 1:10 ) DA LG W131 S M S 11062 2 (di l 1:10 ) DA LGW131 S H S 11062 2 (di l 1:10 ) Mli Q Wate rTN11-023 4 Mlli Q Wate rTN11-023 4 2. 5 ng/m LF C st d i n Mll i Q Wste r Mi l QWste rTN11-023 4 [3ALG W131L 0 11062 2 (di l 1:10 ) DA LGW131LD B 11062 2 (di l 1:10 ) DALGW131 LL S 11062 2 (di l 1:10 ) DA LGW131 LM S 11062 2 (di l 1:10 ) DALG W131 LH S 11062 2 (di l 1:10 ) DA LG W133 L0 11063 0 (di l 1:10 ) DA LG W133 LD B 11063 0 (d l 1:10 ) DALG W133 LL S 11063 0 (d l 1:10 ) DA LG W133 LM S 11063 0 (di l 1:10 ) DA LG W133LH S 11063 0 (d l 1:10 ) Mll i QWste rTN11-023 4 Mll i QWste rTN11-023 4 5, 0 ng/m LF C st d i n Mill i Q Wste r Mll i QWste rTN11-023 4 DA LG W133 S 0 11063 0 (di l 1:10 ) DA LG W133 S D B 11063 0 (d l 1:10 ) DA LGW133 S LS11063 0 (d l 1:10 ) DALGW133 S M S 11063 0 (d l 1:10 ) DA LG W133 S H S 11063 0 (d l 1:10 ) DA LG W133 R 0 11063 0 (di l 1:10 ) DA LGW133RD B 11063 0 (d l 1:10 ) DA LG W133 R L S 11063 0 (d l 1:10 ) DA LGW133 R M S 11063 0 (di l 1:10 ) DA LG W133 R H S 11063 0 (di l 1:10 ) Mil l QWste rTN11-023 4 Mll i QWste rTN11-023 4 1, 0 ng/m LF C st d i n Mll i Q Wate r Mll i QWste rTN11-023 4 DA LG W134 R 0 11062 8 (d l 1:100 ) DALGW134RD B 11062 8 (d l 1:100 ) DA LG W134 R L S 11062 8 (di l 1:100 ) DA LGW134RH S 11062 8 (d l 1:100 ) DA LG W134 L0 11062 8 (d l 1:10 ) DA LG W134 LD B 11062 8 (d l 1:10 ) DA LG W134 LL S 11062 8 (di l 1:10 ) DA LGW134 LM S 11062 8 (d l 1:10 ) DA LG W134 LH S 11062 8 (d l 1:10 ) Mli Q Wste rTN11-023 4 Mi l QWste rTN11-023 4 2. 5 ng/m LF C st d i n M« i Q Wste r Mli Q Wste rTN11-023 4 DALGW134S011062 8 DALGW134SDB11062 8 DALGW134SL S 11062 8 DALGW134 S M S 11062 8



### Printin g Time : 9:30:4 2 A M Printin g Date ; Tuesday , Jul y19 , Pag e 2 o f 4

### *Kirl < BB2150101 0

Project : P:\ProjectsM-abJnammen t Data\KirWl5i1cdat3\Pro|ectafluorochemicals_waterBatcti:k110715 a Tab:Sampl e Set:SET 1 AcqMethod:PFOAonly.da m Sampl e

143 14 4 145 14 6 14 7 148" " 14 9 15 0 15 1 152 153 15 4 15 5 156 157 158 15 9 160 16 1 16 2 16 3 "" " 16 4 16 5 166 " " 167 " 168" " 169 170 17 1 172 173 17 4 175 176 177 178 179 180 18 1 18" 2 183 18 4 185 ~ 186'" ' 187 188 189 19 0 19 1 19 2 193 19 4 195 196 197 198 19 9 20 6 20 i 202 " " 20 3 204 205 " 20 6 20 7 20 8 20 9 21 0 21 1 21 2 21 3 Ssmpl e Nsm e k110715314 3 k1107153l4 4 kii67i53i4 6 kl10715314 6 k110715314 7 i<li6"7i"5si4 8 k11071S3l4 9 k11071Ss15 0 k1107153l5 1 k110715s1S 2 k1107153l5 3 J<11CI7153l54 k110715s1S S k1107153l6 6 k11071S3lS 7 k1107153l6 8 k1107153l6 9 k1107153l6 0 kl10715316 1 kl10715316 2 i(ii67i53i6 3 k1107153l6 4 k110715s16 S k110715s16 6 k110715s16 7 k1107153l6 8 k1107153l6 9 k11071S3l7 0 kl10715317 1 k11071Ss172 k11071Ss173 k1107163l7 4 kl10715317 5 k l 10716317 6 k l 107153177 k1107153l7 8 kl10715317 9 k1107153l8 0 k1107153l8 1 k1107153l8 2 k1107153l8 3 kl10715318 4 kl10715318 5 k110715s18 6 kl10715318 7 kl10716318 8 k1107163l8 9 k110715s19 0 k1107153l9 1 k110715a19 2 k11071S3l9 3 kl10715319 4 k l 10715319 5 kl10715319 6 k11071Ss19 7 kl10715319 8 k110715s19 9 k110715320 0 k11071Ss20 1 k110715320 2 k110715s20 3 k110715s20 4 fei67i53265 k110715320 6 k11071Sa20 7 kl10715320 8 kl10715320 9 k11071Sa21 0 k110715a21 1 k11071Sa21 2 k110715a21 3 Ssmpl e I D

GLP I 0-01-01-18-06 3 GLP I 0-01-01-18-06 4 GL R 0-01-01-18-06 5 GLP I 0-01-01-18-06 6 GLP I 0-01-01-18-06 7 GLPi6-6i-6i-ie-66 8 Solven tBlsn k Solven tBlsn k 11003-26-1 1 Solven tBlsn k GLP I 0-01-01-18-06 9 GLP I 0-01-01-18-07 0 GLP I 0-01-01-18-07 1 GLP I 0-01-01-18-07 2 GLP I 0-01-01-18-07 3 GLP I 0-01-01-18-07 4 GLP I 0-01-01-18-07 5 GLP I 0-01-01-18-07 6 GLP I 0-01-01-18-07 7 GLP I 0-01-01-18-07 8 Solven tBlsn k Solven tBlsn k 11003-26-1 0 Solven tBlsn k GLP I 0-01-01-18-07 9 GLP I 0-01-01-18-08 0 GLP I 0-01-01-18-08 1 GLP I 0-01-01-18-08 3 GLP I 0-01-01-18-08 4 GL R 0-01-01-18-08 5 GLP I 0-01-01-18-08 6 GLP I 0-01-01-18-15 5 GLP I 0-01-01-18-08 7 Solven tBlsn k Solven tBlsn k 11003-26- 8 Solven tBlsn k GLP I 0-01-01-18-08 8 GLP I 0-01-01-18-08 9 GLP I 0-01-01-18-09 0 GLP I 0-01-01-18-09 1 GLP I 0-01-01-18-09 2 GLP I 0-01-01-18-09 3 GLP I 0-01-01-18-09 4 GLP I 0-01-01-18-09 5 GLP I 0-01-01-18-09 6 GL H 0-01-01-18-09 7 Solven tBlsn k Solven tBlsn k 11003-26- 9 Solven tBlsn k GLP I 0-01-01-18-09 8 GLP I 0-01-01-18-09 9 GLP I 0-01-01-18-10 0 GLP I 0-01-01-18-10 1 GLP I 0-01-01-18-10 2 GLP I 0-01-01-18-10 3 GLP I 0-01-01-18-10 4 GLP I 0-01-01-18-10 5 GLP I 0-01-01-18-10 6 GLP I 0-01-01-18-10 7 Solven tBlsn k So"h/on tBlsni i 11003-26-1 1 Solven tBlsn k GLP I 0-01-01-18-10 8 GLP I 0-01-01-18-10 9 GLP I 0-01-01-18-11 0 GLP I 0-01-01-18-11 1 GLP I 0-01-01-18-11 2 GLP I 0-01-01-18-11 3 Via l Positio n 2 1 2 2 2 3 2 4 2 5 2 6 9 1 9 3 1 1 9 3 2 7 2 8 2 9 30 3 1 32 33 34 35 36 9 3 9 4 

## 'i o " 94 37 38 3 9 4 0 4 1 42 4 3 4 4 4 5 94 95 8 95 4 6 47 48 49 5 0 5 1 52 63 64 65 95 9 6 9 9 6 5 6 5 7 6 8 5 9 6 0 6 1 6 2 6 3 6 4 6 5 9 6 9 7 1 1 9 7 6 6 6 7 6 8 6 9 70 7 1 Dat a RI e

kl10715 3 kl10715 a kl10715 a kl10716 a 

### kiiotis a k l 10715 3 k l 10715 a k l 10715 s k110715 3 kl10715 s k110715 s k110715 3 k110715 3 k l 10715 a k110715 a k110715 a k110715 a k110715 a kl10716 a kl10716 a kl10715 a k110715 a k110715 3 k110715 3 kl10715 s kl10715 3 k l 10716 3 kl10716 a k110716 a k110716 3 kl10716 3 kl10715 a k l 10716 3 kl10715 3 k110715 3 kl10715 3 k110715 3 k110715 3 k110715 s k110715 s k110716 3 kl10715 s k110715 s kl10715 s k110715 s k110716 3 k110716 3 k110715 3 k110716 3 kl10715 3 k110716 3 k110715 a k110715 a k110716 3 

## licTWiS i kl10715 a k110715 3 k110715 3 k110715 3 k110715 3 k110715 3 k110716 3 k110715 s k l 10715 3 kl10715 3 kl10715 3 kl10715 3 k110715 3 k110716 3 kl10715 3 kl10715 s Inj.Volum e (|il )

5.00 0 25.00 0 i25.o6 6 26.66 6 5.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 5.00 0 6.00 0 6.00 0 5.00 0 5.00 0 25.00 0 25.00 0 25.00 0 26.00 0 25,00 0 25,00 0 25,00 0 25.00 0 25.66 6 25.00 0 26.00 0 26.00 0 26.00 0 6.00 0 5,00 0 5,00 0 5,00 0 5,00 0 25,00 0 25,00 0 25,00 0 26,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25","66 o 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,66 0 25.66 6 2""5T00 0 25.06 6 25.00 0 2566 6 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 6.00 0 Comment s

DALGW134SH S 11062 8 Tri p Bl3n k

Se t1 Ssmpl e Tri p Blsn k

Set1 LS tri p iisni cSeti M"

S Tri p Blsn k

Se t1 MHS Tri p Blan k

Se t1 HS(d l 1:100) Mi l QWsterTN l 1-023

4 Mi l QWsterTN l 1-023

4 1 0 ng/m LF

C st d i n Mi l Q Wste r Mi l QWste rTN11-0234 DA LGW136 S 0 11062 8 DALGW135SDB11062 8 DALGW135SL S 11062 8 DA LGW135 S M

S 11062 8 DALGW135SH S 11062 8 DA LG W136 L0 11062 8 (d l 1:10) DA LG W136 LD B 11062 8 (di l 1 ; 10) DA LG W136 LLS 11062 8 (di l 1:10) DA LGW135 LM

S 11062 8 (d l 1:10) DA LGW135LH S 11062 8 (d l 1:10) Miii i Q Wste riwii-623 4 Mill i QWsterTN l 1-023

4 5. 0 ng/m LF

C st d i n Mi l Q Wate r Milli Q Wate rTN11-0234 DA LGW135R 0 11062 8 (di l 1:100) DA LG W135 R D B 11062 8 (di l 1:100) DA LG W135 R LS 11062 8 (d l 1:100) DA LGW135RH S 11062 8 (d l 1:100) DALGW136L0110630(dl1:10 ) DALG W136 LDB 110630 (d l 1:10) DALG W136 LL

S 110630 (d l 1:10) DA LGW136 LM

S 11063 0 (d l 1:10) DA LGW136LH S 110630 (d l 1:10) Mlli Q Wate rTN11-0234 Mlli Q Wate rTN11-0234 1. 0 ng/m LF

C st d i n Ml i Q Wate r Mll i QWste rTN11-0234 DALGW136S 0 11063 0 (d l 1:10) DA LGW136S DB 11063 0 (d l 1:10) DA LGW136 S LS 110630 (d l 1:10) DA LG W136 S MS 11063 0 (d l 1:10) DA LGW136S H S 11063 0 (d l 1:10) DA LGW137 S 0 110624 DALGW137SDB11062 4 DA LGW137SL S 110624 DA LGW137 S M

S 110624 DA LGW137SH S 11062 4 Mil l QWste rTN11-0234 Mll i QWste rTN11-0234 2. 5 ng/m LF

C st d i n Mill i Q Wste r Mll i QWste rTN11-0234 aALGW137 L0 110624 DA LGW137LD B 110624 DA LGW137 LLS11062 4 DA LGW137 LM

S 110624 DA LGW137LH S 11062 4 DA LGW138R0110630(d l 1:10 ) DA LGW138RD 8 11063 0 (d l 1:10 ) IDA L"<3 W1 38' R L

S 11063 0 (d l "i: i 6) " DA LGW138 R MS 11063 0 (di l 1:10 ) DA LGW138RH S 11063 0 (d l 1:10 ) Mll i QWste rTN11-0234 Mli i Q Wste rfN"ii-6i2"3" 4 1 0 ng/m LF

C st d i n Ml i Q Wste r Ml i QWste rTN11-0234 DA LGW138 L011063 0 DA LGW138LD B 11063 0 DA LGW138 LLS11063 0 DALGW138LMS11063 0 DA LGW138LH S 11063 0 DALGW138S 0 110630(dl1:10 )



# ,

Printin g Time : 9:30:4 2 A M Printin g Date : Tuesday , Jul y19 , Pag e 3 o f 4

### •Kirl c BB2150101 0

Project : P:\ProjectSU.ab_lndmmen tData\KiriAWri(data\ProjectsMluorochemicsls_waterBatcti:k110715 E Sampl e i Ssmpl e Nsm e 21 4 21 5 216"" ^ 21 7 218 " 21 9 22 0 '22 1 22 2 22 3 22 4 22 5 22 6 22 7 22 8 22 9 23 0 23 1 23 2 23 3 "234"" " 23 5 236""" " 23 7 " 23 8 239 " " 24 0 24 1 24 2 24 3 24 4 24 5 24 6 24 7 24 8 24 9 25 0 25 1 25 2 25 3 26 4 25 6 "256 " 25 7 26 8 26 9 26 0 26 1 26 2 26 3 26 4 126 6 26 6 76" 7 26 8 26 9 :27 0 

### izf i " 27 2 27 3 " "27 4 k110715321 4 k110715321 5 k110715s21 6 k110715321 7 kl10715321 8 kl10715321 9 kl10715322 0 kl10715322 1 kl10716322 2 kl10715322 3 kl10715322 4 k110715322 5 k110715322 6 k110715322 7 k110715322 8 k110715s22 9 kl10715323 0 k110715s23 1 k110715s232 k110715323 3 k110715a234 k110715a23 5 kl10715323 6 kl10715323 7 k110715a23 8 k110715a23 9 k110715a24 0 kl10715324 1 kl10715324 2 k110716324 3 k110715b244 k110715b24 5 k110716b24 6 k110715b24 7 k110716b24 8 k110715b24 9 k110716b26 0 k110716b25 1 k110715b25 2 k110716b25 3 klio"716"b25 4 k110716b25 5 k110715b25 6 k110715b25 7 k110715b25 8 k110715b25 9 k110715b26 0 k110715b26 1 k110715b26 2 k110716b26 3 k110715b26 4 k110715b26 5 k110715b26 6 k110715b26 7 k110715b26 8 k110715b26 9 k110716b27 0 i(ii67i5b27 i k110715b272 k110715b27 3 k110715b274 Ssmpl e I D

GLP I 0-01-01-18-11 4 GLP I 0-01-01-18-11 5 GLP I 0-01-01-18-11 6 GLP I 0-01-01-18-11 7 Solven tBlsn k Solven tBlsn k 11003-26-1 0 Solven tBlsn k GLP I 0-01-01-18-11 8 GLP I 0-01-01-18-11 9 GL R 0-01-01-18-12 0 GL R 0-01-01-18-12 1 GL R 0-01-01-18-12 2 GLRO-01-01-18-12 3 GLRO-01-01-18-12 4 GL R 0-01-01-18-12 5 GL R 0-01-01-18-12 6 GL R 0-01-01-18-12 7 Solven tBlsn k Solven tBlsn k 11003-26- 8 Solven tBlsn k GL R 0-01-01-18-13 3 GL R 0-01-01-18-13 4 GL R 0-01-01-18-12 8 GL R 0-01-01-18-12 9 GL R 0-01-01-18-13 0 GL R 0-01-01-18-13 1 GL R 0-01-01-18-13 2 Solven tBlsn k Solven tBlsn k 11003-26- 9 Solven tBIsnic GL R 0-01-01-18-13 5 GL R 0-01-01-18-13 6 GL R 0-01-01-18-13 7 GL R 0-01-01-18-13 8 GL R 0-01-01-18-13 9 GL R 0-01-01-18-14 0 GL R 0-01-01-18-14 1 G"L"Pi6-6l-0i"-ie"-i4 2 GL R 0-01-01-18-14 3 GL R 0-01-01-18-14 4 Solven tBlsn k Solven tBlsn k 11003-26-1 1 Solven tBlsn k GL R 0-01-01-18-14 5 GL R 0-01-01-18-14 6 GL R 0-01-01-18-14 7 GL R 0-01-01-18-14 8 GL R 0-01-01-18-14 9 GL R 0-01-01-18-15 0 GLRO-01-01-18-15 1 GL R 0-01-01-18-15 2 GL R 0-01-01-18-16 3 GL R 0-01-01-18-16 4 Solven tBlsn k Soiven tisnl c 11003-26-1 0 Solven tBlsn k VIs I Positio n 72 7 3 7 4 "7 5 9 7 9 8 1 0 9 8 7 6 7 7 7 8 ,7 9 ^8 0 ' 8 1 8 2 8 3 8 4 8 6 9 8 9 9 8 9 9 8 6 8 7 las 8 9 9 0 1 6 1 7 9 9 100 9 100 1 8 1 9 2 0 2 1 2 2 2 3 2 4 i2" 5 2 6 2 7 100 9 1 1 1 9 1 2 8 2 9 3 0 3 1 32 3 3 3 4 3 5 3 6 37 9 1 9 1 1 0 9i 3 Dat a Fil e

k110715 3 kl10715 s k110715 s kli67i"5 s k110715 s j(ii07i5 s kl10715 3 ki16715 3 M l 0715 3 M l 0715 s M10716 3 iciTOTIS i ' M10715 3 M l 0716 3 M10715 3 M10715 3 M10715 3 M10715 3 kl10715 3 k110716 3 i(1l6715 s k110715 s k110715 3 "Mi"6"715 3 "kii"0716 3 "

^ M l 0715 s M10715 3 M10715 s kl10716 3 kl10716 3 M l 0715 3 M10715 3 M l 0715 3 k110715 3 kl10715 3 k110715 3 M10715 3 M10715 3 M10715 3 M10715 a M10715 3 kl10715 a kli67"l5 a k110715 s M l 0715 a k110715 a M l 0716 3 M l 0716 3 M l 0715 3 k110715 s k110716 3 M10716 3 M10715 3 M10715 3 M10715 3 M10715 3 M10715 3 kl10715 a M l 0715 a M10715 a kl10715 a Inj.Volum e (id )

5.00 0 5.00 0 5.00 0 5.66 6 25.66 6 25.00 0 25.06 0 25,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5.00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 5.00 0 5.00 0 5.00 0 5.00 0 5,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 5,00 0 5,00 0 5.00 0 5,00 0 5,00 0 5,00 0 "5,0"6~ 6 25.00 0 25.00 0 25.00 0 25,00 0 25,00 0 25,00 0 25,00 0 25,00 0 26,00 0 5,00 0 5,00 0 5,00 0 5,00 0 5,00 0 25.66 6 25.66 6 25.66 6 26.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFOA

Comment s DALGW138 S D B 11063 0 (d l 1:10 ) DA LGW138 S LS11063 0 (di l 1:10) DALGW138 S M

S 11063 0 (d l 1:10) DA LG W138S HS 11063 0 (d l 1:10 ) Ml i QWste rTN11-0234 Ml i QWste rTN11-0234 5, 0 ng/m LF

C st d i n Mill i Q Wste r Mil l QWste rTN11-0234 DA LGWCW26C 0 11062 2 (d l 1:10 ) DA LGWCW26CD B 110622 (d l 1:10) DA LGWCW26CL S 110622 (d l 1:10) DALGWCW26CM S 110622 (d l 1:10) DA LGWCW26CH S 110622 (d l 1:10) DA LGWCW26 L0 110622 (d l 1:10) DA LGWCW26 LD B 110622 (d l 1:10 ) DA LGWCW26 LLS 11062 2 (d l 1:10 ) DA LGWCW26 LM

S 110622 (d l 1:10

) DA LGWCW26 LHS 110622 (d l 1:10 ) Mll i QWste rTN11-0234 Mll i QWste rTN11-0234 1. 0 ng/m LF

C st d i n Mi l Q Wste r Mll i QWste rTN11-0234 DA LGW130 LRB11063 0 DALGW133SR B 110630 DA LGW140R 0 110622 (d l 1:10) DA LGW140 R D B 110622 (d l 1:10) DA LGW140RL S 110622 (d l 1:10) DA LGW140 R M

S 110622 (d l 1:10) DA LGW140 R HS 110622 (d l 1:10) Mll i QWste rTN11-0234 Mll i QWste rTN11-0234 2, 5 ng/m LF

C st d i n Ml i Q Wste r Mll i QWste rTN11-0234 DA LGW141R 0 110630 DA LGW141RD B 110630 DA LGW141RL S 110630 DALGW141RMS11063 0 DA LGW141RH S 110630 (d l 1:10) DA LGW142 R 0 110622 (d l 1:10) DA LGW142RD B 11062 2 (d l 1:10) DALG W142 R L

S 110622 (d l 1:10) DA LGW142 R M

S 110622 (d l 1:10) DA LGW142 R HS 11062 2 (d l 1:10) Mli Q Wate rTN11-0234 Mlli Q Wate rTN11-0234 1 0 ng/m LF

C st d i n Ml i Q Wate r Mll i QWste rTN11-0234 DA LGW143R 0 110622 (d l 1:10) DA LGW143 R DB 110622 (d l 1:10) DA LGW143 R LS 110622 (d l 1:10) DA LG W143 R MS 110622 (d l 1:10) DA LGW143 R HS 110622 (d l 1:10) DA LGW144S 0 11062 8 (d l 1:10) DA LGW144S DB 110622 (d l 1:10) DA LGW144 S LS 110622 (d l 1:10) DA LGW144S M

S 110622 (d l 1:10) DALG W144S HS 110622 (d l 1:10) Mi l QWste rTN11-0234 Ml i QWste rTN11-0234 5, 0 ng/m LF

C st d i n Mi l Q Wste r Mi l QWste rTN11-0234 only.da m



### Printin g Time : Printin g Date : 9:30:4 2 A M

Tuesday , Jul y19 , 201 1 Pag e 4 o f 4

### *Kir) c BB2150101 0

AcciuisitionInfomiation :

0:eal:ed : las t Maiified : ttitment; Synchrenlzatic nM^de : Aito-EljiilihratJjCii : fiojiisitiimDuration : Njifce r O f Scans : Bariod s E i Pile : Pa^iisitia i M^ile : SoftMaz evecBicz :

Beticdl :

Scan s i nBerlcd : Relativ eStar t

TijTe : Experinait s i nIteciod :

Beric d1 Experiiiei t 1 :

Sca nlipe ; S<±priii1e dHM : Rjlarity : ScanKxfc : T mSource : Reaolutio i Ql : HesolutionQ3 : mteisit y Thres. : Settlin g Tme : mreuse: tCR : St^Sije :

0 1 ^BS 3 (CB ) 0 3 Kis s (la ) Duell(TlBSC ) 413.00 0 369.00 0 20.0 0

Q lms a(EB ) 0 3 NBB S la ) DuelKmgec ) 413.00 0 219.00 0 20.0 0

(S

. NBs s (m ) 0 3 NBB s (la ) DuellCtBec: ) 413.00 0 169.00 0 20.0 0

ESrantter " Tabl e(Perio d1 Enperincn t 1 ) OJR

a c •U M OS l GE 2 35.0 0

6.0 0 450.0 0 55.0 0 50.0 0 I S ; -4500.0 0
/gilai t L C Pixi p Mst±o i Prcpertie s Pui p rtdel ; Agilen t 120 0 Binar y Pui p Mininu nPressur e(pei) : 0. 0 ^6xiJnl nPressur e(psi) ; 5801. 0 npw l\bLut e(pi) : 40. 0 texiininFlo w i&n p (mL/min') : 100. 0 ttodnuf lPressur eRan p (pei/sec) : ^to c FOc w Ran p H ) (ml/min') : 100. 0 ^fa xFle w fenp li i (ml/min') : 100. 0

Ste p TbCa lTiitB(min ) Flo w tete(pl/min) C 0.0 0 30 0 1 2.0 0 30 0 2 14.5 0 30 0 3 15.5 0 30 0 4 15.6 0 30 0 E20.0 0 30 0

Righ t Oirpnessibility : 115. 0 l£f t Dea d\toluT e(pi) : 40. 0 Rigii t Dea dVblui E(pi) : 40. 0 l£f C Strck eVUXJX(pi ) : Rigl t SCrck eWli m(pi) : lif t SDlvent : A l Righ t Sjlvcnt : B l

/gilai t Att-npanple r

Prt?«rt:ie s ara n E X 

### s C E 

### act

Rirai r 0 9 E £ C E OT

Kia n I P E £ 

### a OC E

290. 0

A( % 97. 0 97. 0 5. 0 5. 0 97. 0 97. 0

-1. 0 -1. 0 E¥CRcnly.da m •Diirsda y Februar y n201 1 12 ; 53 ; 0 4 t M Frida y Jul y I E20 U15 : 26 : 1 3 E H EK A ICSyn c Of f 20minOse c 1S99 2 1 jcquisitirx i Metiio d ftialysc 1.5. 2

1599 2 0.0 0 HBO

C 1

M: M(WW

) N 3 ^egativ e N/A "Rjiij o ^xs y tUL t Uli t 0.0 0 cp s 0.000 0 mse c 5.007 0 mse c K > 0.0 0 E B

Star t Stq f K -41.0 0 -41.0 0 PFCft- 1 -8.5 0 -8.5 0 -IS.O O -15.0 0 -6.0 0 -6.0 0

Star t Stq c I T -41.0 0 -41.0 0 PEm- 2 -8.5 0 -8.5 0 -22.0 0 -22.0 0 -9.0 0 -9.0 0

Star t Ste p K -100.00-100.0 0 PKft- 3 -10.0 0 -10.0 0 -37.0 0 -37.0 0 -9.0 0 -9.0 0

B (% ) 3. 0 3. 0 95. 0 95. 0 3. 0 3. 0

Aitoeanple r

rtdel : Agilai t 120 0 Standar dAitosanple r Syring eSiz e(pi) : 10 0 mjocti m\«)lur e(pi) : 25.0 0 Ecaw Etiee d(pl/min) : 200. 0 Ejec t %jee d(pl/min) : 200. 0



### Print;ing Time : 10:16:0 3 A M Printin g Date : Monday , Jul y18 , 201 1 Pag e1 o f 2 

# cshnh^l w*Kir k

BB2150101 0

N-edl eLevel(imi) : 0.0 0 Haiperatur eCtntca lEirBble d Setpoinb (

4 - 40 O : I S v&s hI B ne t use d

IteeOjstcmDijecto r

Progra nIt ) Agilen t Cblu mOve

nPrcpertie s E£f t T&rperatirre(" O : 30.0 0 KLc^'teipecatiir e(» 0 : 20.0 0 •ftnperatureTdLexarv

x+/

- {<» 0 : 1.00 Star t fiequigitieniblecanc e-f/

- C O : 0.5 0 Tin elabl eKJsed

) Cblu mSwitchin g \&1V

EInstalle dCS

V ECeitic nfo r

firs t sanpl ei nth ebatch ; Left Usesan epcGitic nfa r

al lsatrple s i nth ebatd : Tbta lTiiTe{inln

) \&lv eEtjsitic n 0.0 0 Left 5.00 Ri ^



### Printin g Time : 10:16:0 3 A MPag e 2 o f 2 Printin g Date : Monday , Jul y18 , 201 1

### Worlcstation : ETSKIR K Result s Name : )cll0715a.rd b



## •k l 10715a.rd b (PFOA) : "Quadratic " Regressio n (" 1 / x " weighting) : y= -6.93e+00 3 x'^ 2 + 1.82e+00 6 x+ 3.65e+00 4 ( r= 0.9998 )

1.15e8

- I.IOeS

1.05e8 :

1.00e8

- 9.50e7

-
9.00e7 t

8.50e7 ^

8.00e7 ^

7.50e7

- 7.00e7

- 6.50e7

- g 6.00e7

- o ra 5.50e7

-

** •5.00e7

- 4.50e7 :

4.00e7

- 3.50e7

- 3.00e7

- 2.50e7

- 2.00e7

- 1.50e7

- 1.00e7 ^

5.00e6 :

0.00

- 

# ^^' '

. ^

y ' 

# /"" •

y '

y '



# y

y y 

# / y

y 

# / y 

# y 7 *

/

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 5 5 6 0 6 5 Conc»ntration , ng/m L „.-•' •

1 1 1

. 

## 7 0 ,.-•''•• '



## 7 5 

## ^---" ^

8 0 

## ^-- ^

8 5 9 0 

## ,-^ ^

9 5 

## •

100

Dat a worke d up b

yKJ U

Printin g Time : 12:12:2 2 PM Printin g Date : Wednesday , Jul y20 , 201 1 Pag e 1 o f 1Workstation : ETSKIR K Result s Name : kll0715a.rd b

1 2 3 4 5 6 7 8 9 " 1 0 T i " 1 2 J 1 3 ' 1 4 1 1 5 To " J 1 7 ' 1 8

2 0 2 1 2 2 2 3 2 4 2 5 2 6 2 7 2 8 2 9 ' 3 0 3 1 3 2 i 33 3 4 3 5 

## U e 3 7 3 8 3 9 4 0 4 1 4 2 4 3 4 4 14 5 4 8 4 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 5 5 5 6 5 7 15 8 5 9 6 0 6 1 6 2 Sampl e Nam e

k110715a00 1 k110715a00 2 k110715a00 3 k110715a00 4 k110715a00 5 k110715a00 6 k110715a00 7 k110715a00 8 k110715a00 9 k110715a01 0 k110715a01 1 k110715a01 2 k110715a01 3 k110715a01 4 k110715a01 5 k110715a01 6 k110715a01 7 k110715a01 8 k110715a01 9 k110715a02 0 k110715a02 1 k110715a02 2 kl10715a02 3 Ml6715a02 4 k110715a02 5 k11071Sa02 6 k1107l5a02 7 k110715a02 8 k110715a02 9 k110715a03 0

. k110715a03 1 k110715a03 2 kli0715a03 3 k110715a03 4 k110715a03 5 k110715a03 6 ^kli0715a03 7 k110715a03 8 k110715a03 9 k110715a04 0 k1l0715a04 1 k110715a04 2 k11071Sa04 3 ^110715a04 4 k110715a04 S k110715a04 6 k110715a04 7 k110715a04 8 k110715a04 9 k110715a05 0 k110715a05 1 k110715a05 2 k110715a05 3 k110715a05 4 k110715a05 5 k110715a05 6 k110715a0S 7 k110715a05 8 k110715a05 9 k110715a06 0 k110715a06 1 k110715a06 2 Sampl e I D

SoNen tBlan k SoNen tBlan k 11003-26 * SoKen tBlan k 11003-26- 9 11003-26- 9 11003-26- 9 110OM6- 9 Solven tBlan k Solven tBlan k 11003-26- 1 11003-26- 2 11003-26- 3 11003-26- 1 11003-26- 5 11003-26- 6 11003-26- 7 11003-26. 8 11003-26- 9 11003-26-1 0 11003-26-1 1 11003-26-1 2 1100J.26-1 3 11003-26-1 4 1100J.26-1 5 Solven tBlan k Solven tBlan k Solven tBlan k Solven l Blan k

~ ^ LCS-110714- 1 LCS-110714- 2 LCS-110714- 3 LCS-110714- 4 LCS-110714- S LCS-llb714- 6 LCS-110714- 7 LCS-110714- 8 LCS-110714- 9 Solven tBlan k Solven tBlan k 1100J.26-1 0 Solven tBlan k LCS-110714-1 0 LCS-110714-1 1 LCS-110714-1 2 LCS-110714-1 3 LCS-110714-1 4 LCS-110714-1 5 LCS-110714-1 6 LCS-110714-1 7 LCS-110714-1 8 Solven tBlan k Solven tBlan k 11003-26- 9 Solven tBlan k Solven tBlan k GLP10-01-01-ie-00 1 GLP1IM)1-01-18-00 2 GLP1CM)1-01-1e-00 3 GLP10-01-01-1M0 4 GLPllW)1-01-18-00 5 GLPlO-01-01-18-00 6 Sampl e Commen t

Milli Q Wate rTM i 1-0234 Milli Q Wate rTN11-023 4 1. 0 ng/m LF C st d i n Min i Q Wate r Milli Q Wate rTN11-023 4 2. 5 ng/m LF C st d i n Mill i Q Wate r 2. 5 ng/m LF C st d i n Mill i Q Wate r 2. 5 ng/m LF C st d i n MiD i Q Wate r 2. 5 ng/m LF C st d i n MiD i Q Wate r Milli Q Wate rTN11-023 4 Milli Q Wate rTN11-023 4 0.02 5 ng/m LF C st d i n MiD i Q Wate r 0.0 3 ng/m LF C st d i n Mill i Q Wate r 0.0 4 ng/m LF C st d i n Mill i Q Wate r 0.0 5 ng/m LF C st d i n Mill i Q Wate r 0. 1 ng/m LF C st d i n MiD i Q Wate r 0.2 5 ng/m LF C st d i n Mill i Q Wate r 0. 5 ng/m LF C st d i n MiD i Q Wate r 1. 0 ng/m LF C st d i n MiD i Q Wate r 2. 5 ng/m LF C st d i n Min i Q Wate r 5. 0 ng/m LF C st d i n MiD i Q Wate r 1 0 ng/m LF C st d i n Min i Q Wate r 2 5 ng/m LF C st d i n MiD i Q Wate r S O ng/m LF C st d i n MiD i Q Wate r 7 5 ng/m LF C st d i n MiD i Q Wate r to o ng/m LF C st d i n Mill i Q Wate r MiD i Q Wate rTN11-023 4 MiD i Q Wate rTN11-023 4 MiD i Q Wate rTN11-023 4 MiD i Q Wate rTN11-023 4 O.Sppb LC S O.Sppb LC S O.Spp b LC S Spp b LC S Spp b LC S Spp b LC S 30pp b LC S 30pp b LC S 30pp b LC S MID I Q Wate rTN11-023 4 MiD i Q Wate rTN11-023 4 S.O ng/m LF C st d i n MiD i Q Wate r MiD i Q Wate rTN11-023 4 O.Sppb LC S EC F |0.5pp b LC S EC F O.Sppb LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F MiD i Q Wate rTN I 1-0234 MiD i Q Wate rTN11-023 4 2. 5 ng/m LF C st d i n MiD i Q Wate r MiD i Q Wate rTN I 1-0234 MiOi Q Wate rTN11-023 4 Tri p Blan k

Se t2 Sampl e Tri p Blan k

Se t2 L S Tri p Blan k

Se t2 M S Tri p Blan k

Se t2 MH S Tri p Blan k

Se t2 H S (di l 1:100 ) DA LG W130 R 0 11063 0 (d D 1:100 ) Sampl e Typ e

Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Standar d Standar d Standan l standan l Standar d Standan i Standar d Standar d Standait l Standan j Standar d Standan S Standar d Standar d Standan d Unknow n Unknow n Unknow n Unknow n Qualit yContro l Qualit yOintro l Qualit yContro l QualrtyContro l Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Unknow n Unknow n Qualit yContro l Unknow n Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Qualit yc^ontro l Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n /Xnalyt e Pea k Nam e PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A "PFOA PFO A PFb/ \ PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A /Analyt e Pea k Are a (counts ) 428SS 2 6101 6 227525 4 1807 3 524138 1 51B1S9 9 509288 7 494318 1 665 6 533 0 7968 4 8491 4 10779 5 11890 6 22210 9 51629 2 98186 3 202671 1 477730 5 921715 1 177S763 2 4177950 1 7208417 1 9639463 6 11470388 8 3004 8 845 S 752 6 541 6 96387 9 9S619 9 103195 0 925207 7 943970 9 944029 9 4605392 7 4493992 1 4618642 S 677 9 341 6 893278 6 590 0 98697 5 89232 3 92892 3 889804 7 895671 6 929110 4 5028700 5 4891430 4 4915085 5 529 4 558 8 451S00 7 373 3 615 4 280 1 176998 8 1636427 7 30S1306 S 798210 2 1480299 0 >\nalyt e Retentio n Tim e (min ) 15. 4 1S. 4 15. 4 15. 4 15. 4 1S. 4 15. 4 1S. 4 1S. 7 1S. 7 15. S 1S. S 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15. 4 15. 4 15. 5 15. 4 15. 4 15. 5 15. 5 15. 5 15. 5 15. 5 1S. 5 15. 4 15. 4 15. 4 1S. S 15. 4 15. 5 15. 4 1S. 5 1S. S 1S. 9 15. S 1S. S 15. 5 15. 4 15. 4 15. 5 15. 4 15. 4 15. 5 15. 4 15. 4 15. 8 15. 8 15. 4 15. 5 15. 8 15. 9 15. 4 15. 4 1S. 4 15. 4 15. 5 Analyt e concentratio n (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.0 0 2.5 0 5.0 0 10. 0 25. 0 SO. O 75. 0 100

. N/ A N/ A N/ A N/ A 0.49 8 0.49 8 0.49 8 4.9 8 4.9 8 4.9 8 29. 9 "29. 9 29. 9 N/ A N/ A 5.0 0 Us e Recor d



# ^ ^ ^ ^ ^ E l 

# ^ R l 

# ^ R l 

# ^ R l B IS I 

### B



### R l E l S 

### E l E l E l S 

### E l E l

E l N/ A 0.49 8 0.49 8 0.49 8 4.9 9 4.9 9 4.9 9 29. 9 29. 9 29. 9 W A N/ A 2.5 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 

### E l

E l R l E l E l E l E l E l E l

E l Calculate d Concentratio n (ng/mL ) 0.21 5 0.013 4 1.2 3

< 0 2.8 9 2.8 5 2.8 0 2.7 2

< 0

< 0 0.023 7 0.026 6 0.039 1 0.045 2 0.10 2 0.26 3 0.52 0 1.1 0 2.6 3 5.1 4 10. 1 25. 3 48. 5 73. 3 104

. < 0

< 0

< 0

< 0 0.51 0 0.50 6 0.54 7 5.1 6 5.2 6 5.2 6 28. 3 27. 5 28. 4

< 0

< 0 4.9 7

< 0 0.52 2 0.47 0 0.49 1 4.9 6 4.9 9 5.1 8 31. 3 30. 3 30. 5

< 0

< 0 2.4 8

< 0

< 0

< 0 0.95 4 9.2 9 89. 7 443

. 837

. Accurac y



## (%) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 94. 7 88. S 97. 8 90. 4 102

. 105

. 104

. 110

. 105

. 103

. 101

. 101

. 96. 9 97. 7 104

. N/ A N/ A N/ A N/ A 102

. 102

. 110

. 104

. 106

. 106

. 94. 6 92. 0 94. 9 N/ A N/ A 99. 5 N/ A 105

. 94. 4 98. 5 99. 3 100

. 104

. 105

. 101

. 102

. Nf A N/ A 99. 2 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A Recor d

Modifie d 

## _-.El_

. E l E l E l D 

## g l E l E l D 

# n D 

### E l E l D D 

### E l E l E l E l E l 

## E l , E l E l E l 

## ^_EL.

. D



## _D D 

### E l D D 

# • D 

### E l 

## H.

. E l E l D D D D 

### E l 

# r ^ E l E l E l E l E ! E l E l D D 

## r~ H 

# n D D 

### E l E l E l E l E l Dilutio n Facto r

5 10 0 10 0 Acquisitio n Dat e

7/15/201 1 3:46:3 8 P M 7/15/201 1 4:08:3 1 P M 7/15/201 1 4:29:3SP M 7/15/201 1 4:50:4 3 P M 7/15/201 1 5:11:4 9 P M 7/15/201 1 5:32:5 9 P M 7/15/201 1 5:54:0 5 P M 7/15/201 1 6:15:1 2 P M 7/15/201 1 6:36:1 7 P M 7/15/201 1 6:57:2 3 P M 7/1S/201 1 7:18:2 7 P M 7/15/201 1 7:39:3 4 P M 7/1S/201 1 8:00:4 3 P M 7/15/201 1 8:21:5 0 P M 7/15/201 1 8:42:5 6 P M 7/15/201 1 9:04:0 0 P M 7/15/201 1 9:25:0 4 P M 7/15/201 1 9:46:1 1 P M 7/15/201 1 10:07:1 7 P M 7/15/201 1 10:28:2 2 P H 7/15/201 1 10:49:2 9 P M 7/15/201 1 11:10:3 6 P M 7/15/201 1 11:31:4 0 P M 7/15/261 1 11:52:4 6 P M 7/16/201 1 12:13:5 4 A M 7/16/201 1 12:34:5 9 A M 7/16/201 1 12:56:0 4 A M 7/16/201 1 1:17:0 8 A M 7/16/201 1 1:38:13A M 7/16/201 1 1:59:1 8 A M 7/16/201 1 2:20:2 6 A M 7/16/201 1 2:41:3 2 A M 7/16/201 1 3:02:3 8 A M 7/16/201 1 3:23:4 5 A M 7/16/201 1 3:44:5 4 A M 7/16/201 1 4:06:0 3 A M 7/16/201 1 4:27:1 3 A M 7/I6/2OI I 4:48:19A M 7/16/201 1 5:09:2 6 A M 7/16/201 1 5:30:3 2 A M 7/16/201 1 5:51:4 0 A M 7/16/201 1 6:12:5 2 A M 7/16/201 1 6:34:0 1 A M 7/16/201 1 6:55:1 1 A M 7/16/201 1 7:16:1 7 A M 7/16/201 1 7:37:2 6 A M 7/16/201 1 7:S8:32A M 7/16/201 1 8:19:3 8 A M 7/16/201 1 8:40:4 6 A M 7/16/201 1 9:01:5 4 A M 7/16/201 1 9:22:5 9 A M 7/16/201 1 9:44:0 6 A M 7/16/201 1 10:05:1 6 A M 7/16/201 1 10:26:2 5 A M 7/16«01 1 10:47:3 5 A M 7/16/201 1 11:08:4 5 A M 7/16/201 1 11:29:5 0 A M 7/16/201 1 11:51:0 3 A M 7/16/201 1 12:12:1 0 P M 7/16/201 1 12:33:1 8 P M 7/16/201 1 12:54:1 7 P M 7/16/201 1 1:15:1 8 P M

rke d u p b yKJ U

Printin g Time : 12:10:4 9 P H Printin g Date : Wednesday , Jul y20 , 201 1 

# i^V ^ 1']^\^^ \Workstation : ETSKIR K Result s Name : kll0715a.rd b

6 3 54 " " 65" " • 6 6 "67" " 6 8 6 9 7 0 7 1 7 2 7 3 "7 4 " 7 5 7 6 [77 |7 8 7 9 |8 0 18 1 8 2 [8 3 8 4 8 5 8 6 |8 7 8 8 8 9 9 0 9 1 [9 2 9 3 9 4 9 5 9 6 9 7 9 8 9 9 10 0 • 10 1 10 2 10 3 104 10 5 106 ' " Td 7 " 10 8 10 9 11 0 11 1 11 2 11 3 11 4 Tis " 11 6 11 7 11 8 11 9 12 0 12 1 12 2 12 3 12 4 Sampl e Nam e

k11071Sa06 3 k11071Sa06 4 k110715a06 5 k110715a06 6 k11071Sa06 7 k11071Sa06 8 k11071Sa06 9 k11071Sa07 0 k11071Sa07 1 k11071Sa07 2 k11071Sa07 3 k11071Sa07 4 k11071Sa07 5 k1t071Sa07 6 k110715a07 7 k1107t5a07 8 k110715a07 9 k11071Sa08 0 k11071Sa08 1 k110715a08 2 k11071Sa08 3 k11071Sa08 4 k11071Sa08 5 k1107lSa08 6 k110715a08 7 k11071Sa08 8 k1107lSa08 9 k110715a09 0 k110715a09 1 k11071Sa09 2 k11071SaO9 3 k110715a09 4 k11071Sa09 5 k110715a09 6 k11071Sa09 7 ^0715a09 8 TrTTb71Sa09 9 k1107lSa10 0 k110715a10 1 k110715a10 2 k110715a10 3 k110715a10 4 k110715a10 5 k110715a10 6 k110715a10 7 k11O71Sa10 8 k11071Sa10 9 k11071Sa11 0 k11071Sa1l 1 k11071Sa11 2 k110715a1l 3 k11071Sa11 4 k110715a11 5 k11071Sa11 6 kl10715a11 7 k110715a11 8 k110715a11 9 k1107lSa12 0 k1l0715a12 1 k110715a12 2 k11071Sa12 3 k11071Sa12 4 Sampl e I D

GLP10-01-01-18-00 7 GLP I 0-01-01-18-00 8 GLP10-01-01-18-00 9 GLP I 0-01-01-18-01 0 Solven tBlan k Solven tBlan k 11003-26-1 0 Solven tBlan k GLP10-01-01-18-01 1 GLP10-01-01-18-01 2 GLP10mi-01-18-01 3 GLP I 04)1-01-18-01 4 GLPIO.01-01-1^01 5 GLP10-01-01-18-01 6 GLP10-01-01-18-01 7 GLP I 0-01-01-18-01 8 GLP10-01-01-18-01 9 GLP10-01-01-164)2 0 Solven tBlan k Solven tBlan k 11003-26-1 1 Solven tBlan k GLP10-01-01-18-02 1 GLP10-01-01-18-02 2 GLP10-01-01-18-02 3 GLPlO-01-01-18-02 4 GLPlO-01-01-18-02 5 GLP10-01-01-18-02 6 GLP10-01-01-18-02 7 GLPlO-01-01-18-02 8 GLPlO-01-01-18-02 9 Solven tBlan k Solven tBlan k 11003-26- 9 Solven tBlan k GLP10-01-01-18-03 0 GLP10-01-01-18-03 1 GLP10-01-01-18-03 2 GLPlO-01-01-18-03 3 GLP10-01-01-18-03 4 GLP10-01-01-18-03 5 GLP I 0-01-01-184)3 6 GLP10-01-01-18-03 7 GLP10-01-01-18-03 8 GLP10-01-01-18-03 9 Solven tBlan k Solven tBlan k 11003.26-1 0 Solven tBlan k GLP10-01-01-18-04 0 GLP10-01-01-18-04 1 GLP10-01-01-184)4 2 GLP10-01-01-184)4 3 GLP10-01-01-18-04 4 GLP10-01-01-18-04 5 GLP10-01-O1-18-O4 6 GLP10-01-01-18-04 7 GLP10-01-01-18-04 8 GLP1IM)1-01-18-04 9 Solven tBlan k Solven tBlan k 11003-26- 8 Sampl e Commen t

DA LG W130 R D B 11063 0 (di l 1:100 ) DA LG W130 R L S 11063 0 (di l 1:100 ) DA LG W130 R M S 11063 0 (d N 1:100 ) DA LG W130 R H S 11063 0 (di l 1:100 ) Min i Q Wate rTN I 1-0234 Min i Q Wate rTN11-023 4 S.O ngfm LF C st d i n MID I Q Wate r Min i Q Wate rTN11-023 4 DA LG W130 S 0 11063 0 (d D 1:10 ) DA LG W130 S 0 11063 0 (d D 1:10 ) DA LG W130 S L S 11063 0 (di l 1:100 ) DA LG W130 S M S 11063 0 (d D 1:100 ) DA LG W130 S H S 11063 0 (di l 1:100 ) DA LG W130 L0 11063 0 (di l 1:10 ) DA LG W130 LD B 11063 0 (di l 1:10 ) DA LG W130 LL S 11063 0 (di l 1:10 ) DA LG W130 LM S 11063 0 (di l 1:10 ) DA LG W130 LH S 11063 0 (di l 1:10 ) Min i Q Wate rTN11-023 4 Min i Q Wate rTN I 1-0234 1 0 ng/m LFCst d i n Min i Q Wate r Min i Q Wate rTN11-023 4 DA LG W131 R 0 11062 2 (di l 1:100 ) DA LG W131 R D B 11062 2 (di l 1:100 ) DA LG W131 R L S 11062 2 (di l 1:100 ) DA LG W131 R H S 11062 2 (di l 1:100 ) DA LG W131 S 0 11062 2 (d D 1:10 ) DA LG W131 S D B 11062 2 (di l 1:10 ) DA LG W131 S L S 11062 2 (di l 1:10 ) DALGW131 S M S 11062 2 (d N 1:10 ) DA LG W131 S H S 11062 2 (di l 1:10 ) Min i Q Wate rTN I 1-0234 MilH Q Wate rTN11-023 4 2. 5 ng/m LF C st d I n Mill i Q Wate r Milli Q Wate rTN11-023 4 DA LG W131 L0 11062 2 (di l 1:10 ) DA LG W131 LD B 11062 2 (di l 1:10 ) DA LG W131 LL S 11062 2 (di l 1:10 ) DALGW131LM S 11062 2 (di l 1:10 ) DA LG W131 LH S 11062 2 (di l 1:10 ) DA LG W133 L0 11063 0 (di l 1:10 ) DA LG W133 LD B 11063 0 (di l 1:10 ) DA LG W133 LL S 11063 0 (di l 1:10 ) DA LG W133 LM S 11063 0 (di l 1:10 ) DA LG W133 LH S 11063 0 (d » 1:10 ) Min i Q Wate rTN11-023 4 Min i Q Wate rTN11-023 4 5. 0 ng/m LF C st d i n Min i Q Wate r Min i Q Wate rTN11-023 4 DA LG W133 S 0 11063 0 (di l 1:10 ) DA LG W133 S D B 11063 0 (di l 1:10 ) DA LG W133 S LS 11063 0 (d D 1:10 ) DA LG W133 S M S 11063 0 (di l 1:10 ) DA LG W133 S H S 11063 0 (di l 1:10 ) DA LG W133 R 0 11063 0 (di l 1:10 ) DA LG W133 R D B 11063 0 (di l 1:10 ) DA LG W133 R LS 11063 0 (d D 1:10 ) DA LG W133 R M S 11063 0 (di l 1:10 ) DA LG W133 R H S 11063 0 (di l 1:10 ) MiD i Q Wate rTN11-023 4 MiD i Q Wate rTN11-023 4 1. 0 ng/m LF C st d i n MiD i Q Wate r Sampl e Typ e

Unknov m Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknovw i Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknov m Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Analyt e Pea k Nam e PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A

. PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A P"FO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A Analyt e Pea k Are a (counts ) 1456529 4 1474665 6 1624321 9 2230377 7 996 4 852 6 883942 0 360 8 3052407 3 3034949 7 331685 5 481996 6 1259633 4 1189888 0 1130215 4 1223S96 2 1328395 9 2704634 0 354 7 429 6 1698917 1 781 6 3839077 5 4204696 2 4116457 0 6257499 9 100642 9 97238 5 100310 0 134398 6 420598 3 303 3 644 4 455999 6 284 7 1654864 3 1692432 4 1712339 2 1882861 0 3141892 6 826047 3 81314S 3 950871 1 1476783 8 2446504 7 690 8 783 0 894659 6 739 6 1110411 2 1121788 5 1128917 5 1406312 9 2638454 4 1889092 5 1890901 6 1700257 7 1956377 8 3214606 0 450 9 324 7 195069 0 Analyt e Retentio n Tim e (mtn ) 15: 4 15. 5 15. 4 15. 4 15. 9 15. 5 15. 4 15. 9 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 1S. 4 15. 4 15. 4 15. 5 1S. S 15. 4 15. 5 15. 4 15. 4 1S. 5 15. 4 15. 4 1S. 4 1S. 4 15. 4 15. 4 15. 8 15. 5 15. 4 15. S 15. 4 15. 4 15. 4 15. 5 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15. 9 15. 5 15. 9 15. 4 15. 4 15. 4 1S. 4 15. 4 1S. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15. 9 15. 4 Analyt e Concentratio n (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A 5.0 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A Us e Recor d



### E l

N/ A N/ A N/ A N/ A N/ A N/ A 10. 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 2.5 0 N/ A N/ A N/ A 

### E l

E l

N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 5.0 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 1.0 0 

### E l

E l Calculate d

823

. 833

. 921

. 1280

. < 0

< 0 4.9 2

< 0 180

. 178

. 181

. 265

. 708

. 66. 8 63. 3 68. 7 74. 8 158

. < 0

< 0 9.6 6

< 0 2310

. 2550

. 2490

. 4060

. 26. 7 25. 7 26. 6 36. 0 115

. < 0 

### < 6 2.5 1 "< o • " 93. 9 96. 2 97. 3 107

. 185

. 230

. 226

. 265

. 417

. 708

. < 0

< 0 4.9 8

< 0 311

. 314

. 316

. 397

. 768

. 108

. 108

. 96. 6 112

. 190

. < 0

< 0 1.0 5 /^curac y



## (%) N/ A SS A N/ A N/ A N/ A N/ A 98. 4 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 96. 6 N/ A N/ A N/ A N/ A N W N/ A N/ A N/ A N/ A N/ A N/ A N/ A 100

. N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 99. 7 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 105

. Recor d

Modifie d 

### E l E l E l E l D D 

### E l D 

### E l E l E l E l E l E l E l E l E l E l 

# • D 

### E l D 

### E ! E l ^ 

### E l 'E l 

### E l E l E l E l E l 

# n

r— O 

### E l D 

### E l E l E l 

# g E l E l E l E l 

## ^ S E l D D 

### E l 

# n E l E l E l E l 

## l_E I r-^ i E l E l E l E l D D 

### E l Dilutio n Facto r 10 0 10 0 10 0 10 0 1 1 1 1 1 0 1 0 10 0 10 0 10 0 1 0 1 0 1 0 1 0 1 0 1 1 1 1 10 0 

### io d 10 0 10 0 

### s o s o 5 0 

### s o s o 1 1 1 1 1 0 1 0 1 0 1 0 1 0 

### s o s o s o 5 0 

### s o 1 1 1 1 5 0 5 0 

### s o 5 0 5 0 1 0 1 0 1 0 1 0 1 0 1 1 1 Acquisitio n Dat e

7/16/201 1 1:36:2 7 P M 7/16/201 1 1:57:3 6 P M 7/16/201 1 2:18:4 6 P M 7/16/201 1 2:39:5 7 P M 7/16/201 1 3:01:0 6 P M 7/16/201 1 3:22:1 8 P M 7/16/201 1 3:43:2 4 P M 7/16/201 1 4:04:3 4 P M 7/16/201 1 4:25:4 3 P M 7/16/201 1 4:46:5 4 P M 7/16/201 1 5:08:0 1 P M 7/16/201 1 5:29:0 7 P M 7/16/201 1 5:50:1 8 P M 7/16/201 1 6:11:2 6 P M 7/16/201 1 6:32:1 4 P M 7/16/201 1 6:53:4 2 P M 7/16/201 1 7:14:5 1 P M 7/16/201 1 7:35:5 9 P M 7/16/201 1 7:57:0 7 P M 7/16/201 1 8:18:1 7 P M 7/16/201 1 8:39:2 6 P M 7/16/201 1 9:00:3 5 P M 7/16/201 1 9:21:4 4 P M 7/16/201 1 9:43:0 0 P M 7/16/201 1 10:04:0 9 P M 7/16/201 1 10:25:1 8 P M 7/16/201 1 10:46:2 7 P M 7/16/201 1 11:07:2 9 P M 7/16/201 1 11:28:2 9 P M 7/16/201 1 11:49:2 6 P M 7/17/201 1 12:10:2 5 A M 7/17/201 1 12:31:2 5 A M 7/17/201 1 12:52:3 1 A M 7/17/201 1 1:13:3 9 A M 7/17/201 1 1:34:4 8 A M 7/17/201 1 1:55:5 6 A M 7/17/201 1 2:17:1 4 A M 7/17/201 1 2:38:2 6 A M 7/17/201 1 2:59:3 6 A M 7/17/201 1 3:20:4 6 A M 7/17/201 1 3:42:0 1 A M 7/17/201 1 4:03:0 7 A M 7/17/201 1 4:24:0 4 A M 7/17/201 1 4:45:0 3 A M 7/17/201 1 5:06:0 2 A M 7/17/201 1 5:26:5 7 A M 7/17/201 1 5:48:0 2 A M 7/17/201 1 6:09:1 9 A M 7/17/201 1 6:30:3 3 A M 7/17/201 1 6:51:4 9 A M 7/17/201 1 7:12:5 3 A M 7/17/201 1 7:33:5 9 A M 7/17/201 1 7:54:5 8 A M 7/17/201 1 8:15:5 7 A M 7/17/201 1 6:36:5 5 A M 7/17/201 1 8:58:0 0 A M 7/17/201 1 9:19:1 4 A M 7/17/201 1 9:40:2 6 A M 7/17/201 1 10:01:4 3 A M 7/17/201 1 10:22:5 2 A M 7/17/201 1 10:44:1 0 A M 7/17/201 1 11:05:2 0 A M

ocke d u p byKJ U Pag e 2 o f 5

Printin g Time : 12:10:4 9 P M Printin g Date : Wednesday , Jul y20 , 201 1Workstation : ETSKIR K Result s Name : kll0715a.rd b

12 5 12 6 12 7 12 8 12 9 13 0 13 1 13 2 13 3 13 4 T35 ~ 13 6 13 7 [13 8 13 9 14 0 14 1 142 14 3 14 4 " 14 5 14 6 14 7 l14 8 14 9 15 0 

### isT " 15 2 15 3 " 15 4 15 5 15 6 15 7 15 8 1S9 16 0 16 1 K 2 16 3 16 4 16 5 166~" ' 16 7 16 8 l"6 9 " 17 0 17 1 17 2 17 3 17 4 17 5 17 6 177 " 17 8 17 9 18 0 13 1 18 2 18 3 184 18 5 18 6 Sampl e Nam e

k110715a12 5 k110715a12 8 k110715a12 7 k110715a12 8 k11071Sa12 9 k110715a13 0 k110715a13 1 k11071Sa13 2 k110715al3 3 k110715al3 4 k11071Sa13 S k110715al3 6 k11071Sa13 7 k110715a13 8 k110715a13 9 k110715a14 0 k110715a14 1 k110715a14 2 k110715a14 3 k110715a14 4 k110715a14 5 k110715a14 8 k110715a14 7 k110715a14 8 k11071Sa14 9 k110715a1S 0 k110715a15 1 k110715a15 2 k11071Sa1S 3 k110715a15 4 kl10715a15 5 k11071Sa1S 6 k11071Sa15 7 k110715a15 8 k11071Sa15 9 k110715a16 0 k110715a16 1 k110715a16 2 k110715a16 3 kl10715a16 4 k110715a16 5 k110715a16 6 k110715a16 7 k11071Sa16 8 k11071Sa16 9 k110715a17 0 k110715a17 1 k110715a17 2 kl1071Sa17 3 k110715a17 4 k11071Sa17 S k11071Sa17 6 k1l071Sal7 7 k110715al7 8 k11071Sal7 9 k11071Sal8 0 k110715aie i kll0715a18 2 k1l0715a18 3 k110715a18 4 kl10715a18 5 k110715a18 e Sampl e I D

Solven tBlan k GLP10-01-01-18-05 0 GLP10-01-01-18-05 1 GLP104)1-01-18-05 2 GLP10-01-01-18-05 3 GLP10-01-01-18-05 4 GLP10-01-01.18-05 S GLP1M1-01-16O5 6 'GLPIO-01-01-18-05 7 GLP10-01-01-18-05 8 SoNen tBlan k Solven tBlan k 11003-26- 9 Solven l Blan k GLP10-01-O1-18-05 9 GLP10-01-01-16O6 0 GLP10-01-01-184)6 1 GLP10-01-01-1»4)6 2 GLP10-01J)1-184)6 3 GLP1fr<ll-01-1»4l6 4 GLP10-01-01-18-06 5 GLP10-01-01-1W)6 6 GLP10-01-01-18-06 7 GLP10-01-01-1S4)6 8 Solven tBlan k Solvent'Blan k 11003-26-1 1 Solven tBlan k GLP10-01-01-18-06 9 GLP10-01-01-18-07 0 GLP104)1-01-1B4)7 1 GLP104)1-01-18-07 2 GLP1W)1-01-18O7 3 GLP10-01-01-18-07 4 GLP104)1-01-184)7 5 GLP104)1-01-164)7 6 GLP10-01-01-18-07 7 GLP10-01-01-18-07 8 SoNen tBlan k Solven tBlan k 11003-26-1 0 Solven tBlan k GLP104)1-01-1»O7 9 GLP10-01-01-1M8 0 GLP1D-01-01-184)8 1 GLP10-01-01-18-08 3 GLP I 04)1-01-1608 4 GLP10-01-01-1B4)8 5 GLPlSoi-01-184)8 6 GLP104)14)1-18-15 5 GLP104)14)1-184)8 7 Solven l Blan k Solven tBlanl l 11003-26 ^ Solven tBlan k GLP104)14)1-184)8 8 GLP104)14)1-18-08 9 GLP104)14)1-184)9 0 GLP104)1-01-18-09 1 GLP104)14)1-184)9 2 GLP104)14)1-184)9 3 GLP104)14)1-184)9 4 Sampl e Commen t

Milli Q Wate rTN I 14)23 4 DA LG W134 R 0 11062 8 (di l 1:100 ) DA LG W134 R D B 11062 8 (di l 1:100 ) DA LG W134 R L S 11062 8 (d D 1:100 ) DA LG W134 R H S 11062 8 (di l 1:100 ) DA LGW134L 0 11062 8 (dD 1:10 ) DA LG W134 LD B 11062 8 (d D 1:10 ) DA LG W134 LL S 11062 8 (di l 1:10 ) DA LG W114 LM S 11062 8 (di l 1:10 ) DA LG W134 LH S 11062 8 (di l 1:10 ) MiD i Q Wate rTN1141234 MiD i Q Wate rTN114)23 4 2. 5 ng/m LF C st d i n MiD i Q Wate r MiD i Q Wate rTN114)23 4 DA LGW134 S 011062 8 DA LGW134SD B 11062 8 DALGW134SL S 11062 8 DALGW134SMS11062 8 DA LGW134SH S 11062 8 Tri p Blan k

Se t1 Sampl e Tri p Blan k

Se t1 L S Tri p Blan k

Se t1 M S Tri p Blan k

Se t1 MH S Tri p Blan k

Se t1 H S (di l 1:100 ) MiD i Q Wate rTN114)23 4 Min i Q Wate rTN114)23 4 1 0 ng/m LF C st d i n MiD i Q Wate r Min i Q Wate rTN I 14)23 4 DA LGW135 S 011062 8 DALGW135SD B 11062 8 DA LGW135SL S 11062 8 DALGW135 S M S 11062 8 DA LGW135SH S 11062 8 DA LG W135 L0 11062 8 (di l 1:10 ) DA LG W135 LD B 11062 8 (d D 1:10 ) DA LG W13S LL S 11062 8 (di l 1:10 ) DA LG W135 LM S 11062 8 (di l 1:10 ) DA LG W13S LH S 11062 8 (d D 1:10 ) MID I Q Wate rTN114)23 4 MiD i Q Wate rTN114)23 4 S. O ng/m LF C st d i n MiD i Q Wate r MiD i Q Wate rTN114)23 4 DA LG W135 R 0 11062 8 (di l 1:100 ) DA LG W135 R D B 11062 8 (di l 1:100 ) DA LG W135 R L S 11062 8 (di l 1:100 ) DA LG W135 R H S 11062 8 (di l 1:100 ) DA LG W136 L0 11063 0 (di l 1:10 ) DA LG W136 LD B 11063 0 (di l 1:10 ) DA LG W136 LL S 11063 0 (di l 1:10 ) DALGW136LM S 11063 0 (di l 1:10 ) DA LG W136 LH S 11063 0 (di l 1:10 ) Min i Q Wate rTN I 14)23 4 Milli Q Wate rTN I 14)21 4 1. 0 ng/m LF C st d I n Mii n Q Wate r MiD i Q Wate rTN1141234 DA LG W136 S 0 11063 0 (di l 1:10 ) DA LG W136 S D B 11063 0 (di l 1:10 ) DA LG W136 S L S 11063 0 (d D 1:10 ) DA LG W136 S M S 11063 0 (di l 1:10 ) DA LG W136 S H S 11063 0 (di l 1:10 ) DA LGW137 S 0 11062 4 DA LGW137SD B 11062 4 Sampl e Typ e

Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknov m Unknov m Unknov m Unknow n Unknov m Unknov m Unknov m Unknov m Unknov m Unknov m u"nknow n Qualit ycontro l Unknov m Unknow n Unknov m Unknow n Unknow n Unknov m Unknow n Unknow n Unknov m Unknow n Unknow n Unknov m Unknov m Qualit yContro l Unknov m Unknov m Unknov m Unknov m Unknow n Unknow n Unknov m Unknov m Unknow n Unknov m Unknov m Unknov m Qualit ycontro l Unknow n Unknow n Unknov m Unknow n Unknov m Unknov m Unknow n Unknov m Analyt e Pea k Nam e PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A I^FOA PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A Analyt e Pea k Are a (counts ) 389 6 3042043 0 3055230 2 3172213 9 5676481 1 1847142 2 2062965 0 2096815 5 2343148 3 3416937 1 1109 0 2517 7 461830 1 1422 0 353519 3 362422 0 351055 7 390463 5 707708 7 956 2 181804 6 1762051 2 3233222 9 884961 8 424 3 456 7 1754S96 3 647 3 683015 7 732271 5 8709S3 S 742725 4 1413547 8 4612215 6 4451956 2 4530792 2 4693986 2 5727908 8 833 7 263 7 898678 6 1262 8 5622297 4 5480493 4 5670071 3 7664466 3 292501 9 287490 5 292133 6 326381 1 614378 2 1030 3 294 3 194525 2 603 3 2265384 7 2266898 1 2281794 4 2347530 9

. 3633781 0 55387 6 52586 4 Analyt e Retentio n Tim e (min ) 15. 7 1S. 5 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15. 5 15. 4 15. 5 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15: 5 15. 5 15. 6 15. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15. 5 15. 5 15. 5 15. 5 15. 5 15. 6 15. 5 15. 6 15. 5 15. 4 15. 4 15. 4 l"5. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 5 15. 4 15. 5 15. 4 15. 4 15. 4 15. 5 15. 4 15. 5 15. 5 /Xnalyt e concentratio n (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 2.5 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A" 10. 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A f^ A N/ A 5.0 0 

## 1:* * N/ A N/ A N/ A
tl" ^ .,., ^ N/ A N/ A N/ A N/ A N/ A Kl/ A N/ A 1.0 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A Us e Recor d



## E l

E l

E l

E l Calculate d concentratio n (ng/mL )

< 0 1790

. 1800

. 1870

. 3610

. 527

. 592

. 602

. 677

. 1010

. < 0

< 0 2.5 4

< 0 9.6 7 9.9 2 9.6 0 10. 7 19. 6

< 0 0.98 1 10. 0 95. 5 493

. < 0 

### <o " 9.9 9

< 0 18. 9 20. 3 24. 2 20. 6 39. 9 283

. 272

. 278

. 289

. 365

. < 0

< 0 5.0 1

< 0 3570

. 3460

. 3600

. 5250

. 79. 7 78. 3 79. 6 89. 1 170

. < 0

< 0 1.05

< 0 131

. 131

. 132

. 136

. 217

. 0.28 4 0.26 9 Accurac y



## (%)

N/ A N/ A "N// k N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 102

. N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N// V 99. 9 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 100

. N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 105

. N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A Recort j

Modifie d 

# n M , E l E l E l E l E l E l E l E l 

# • D E l 

# n E l E l E l E l E l E l E l E l E l E l ^ 

## 1 m E l E l E l ^ 

## E l E l E l E l E l E l E l . E l ' ^ H 

## D 

# n E l 

## D E l E l E l E l E l E l E l E l E l 

## D D E l 

# n E l E l E l E l E l E l E l Dilutio n Facto r 1 10 0 10 0 10 0 10 0 5 0 5 0 5 0 5 0 5 0

10 0

1 0 1 0 1 0 1 0 1 0

10 0 10 0 10 0 10 0 5 0 5 0 5 0 5 0 S O

1 0 1 0 1 0 1 0 1 0 Acquisitio n Oat e

7/17/201 1 11:26:3 1 A M 7/17/201 1 11:47:4 3 A M 7/17/201 1 12:08:5 5 P M 7/17/201 1 12:30:0 8 P M 7/17/201 1 12:51:1 8 P M 7/17/201 1 1:12:2 7 P M 7/17/201 1 1:33:3 1 P M 7/17/201 1 1:54:2 8 P M 7/17/201 1 2:15:3 1 P M 7/17/201 1 2:36:3 2 P M 7/17/201 1 2:57:3 1 P M 7/17/201 1 3:18:3 7 P M 7/17/201 1 3:39:5 0 P M 7/17/201 1 4:01:0 4 P M 7/17/201 1 4:22:1 6 P M 7/17/201 1 4:43:2 4 P M 7/17/201 1 5:04:2 2 P M 7/17/201 1 5:25:2 3 P M 7/17/201 1 5:46:2 3 P M 7/17/201 1 6:07:2 2 P M 7/17/201 1 6:28:2 8 P M 7/17/201 1 6:49:4 0 P M 7/17/201 1 7:10:5 0 P M 7/17/201 1 7:31:5 3 P M 7/17/201 1 7:53:0 0 P M 7/17/201 1 8:14:1 4 P M 7/17/201 1 8:35:2 6 P M 7/17/201 1 8:56:3 9 P M 7/17/201 1 9:17:5 1 P M 7/17/201 1 9:39:0 2 P M 7/17/201 1 10:00:0 2 P M 7/17/201 1 10:21:0 1 P M 7/17/201 1 10:42:0 3 P M 7/17/201 1 11:03:0 3 P M 7/17/201 1 11:24:0 8 P M 7/17/201 1 11:45:1 7 P M 7/18/201 1 12:06:3 0 A M 7/18/201 1 12:27:4 2 A M 7/18/201 1 12:48:5 3 A M 7/18/201 1 1:10:0 5 A M 7/18/201 1 1:31:1 8 A M 7/18/201 1 1:52:3 5 A M 7/18/201 1 2:13:5 0 A M 7/18/201 1 2:35:0 4 A M 7/18/201 1 2:56:1 9 A M 7/18/201 1 3:17:3 4 A M 7/18/201 1 3:38:4 7 A M 7/18/201 1 3:59:5 8 A M 7/18/201 1 4:21:0 1 A M 7/18/201 1 4:42:0 4 A M 7/16/201 1 5:03:0 4 A M 7/18/201 1 5:24:0 3 A M 7/18/201 1 5:45:1 3 A M 7/18/201 1 6:06:2 6 A M 7/18/201 1 6:27:4 0 A M 7/18/201 1 6:48:5 8 A M 7/18/201 1 7:10:1 2 A M 7/18/201 1 7:31:2 7 A M 7/18/201 1 7:52:3 9 A M 7/18/201 1 8:13:5 1 A M 7/18/201 1 8:35:0 5 A M 7/18/201 1 8:56:1 9 A M

Dat a worke d u p byKJ U

Printin g Time : 12:10:'1 9 P M Printin g Date : Wednesday , Jul y20 , 201 1Workstation : Result s Name : kll0715 a

i s f 18 8 18 9 19 0 191" " 19 2 19 3 19 4 19 5 i19 6 19 7 19 8 {19 9 200 ^ 20 1 20 2 20 3 20 4 m s " & 6 20 7 20 8 20 9 210 " 21 1 21 2 21 3 21 4 fel5 21 6 21 7 21 8 [219_

_ 22 0 122 1 22 2 22 3 22 4 22 5 22 6 22 7 22 8 22 9 23 0 23 1 23 2 23 3 23 4 23 5 23 6 23 7 23 8 23 9 24 0 24 1 24 2 24 3 24 4 24 5 24 6 24 7 24 8 Sampl e Nam e

k110715a18 7 k110715a18 8 k110715a18 9 k110715a19 0 k110715a19 1 k110715a19 2 klTb715a19 3 k1l0715a19 4 k110715a19 5 k110715a19 6 k110715a19 7 kil07i5a19 8 k110715a19 9 kl10715a20 0 kl10715a20 1 kl10715a20 2 kl10715a20 3 kl10715a20 4 kl10715a20 5 ' kl10715a20 6 kl107l5a20 7 kl10715a20 8 kll0715a20 9 k1107l5a21 0 k110715a21 1 k110715a21 2 k110715a21 3 k110715a21 4 k110715a21 5 k110715a21 6 k110715a21 7 k110715a21 8 k110715a21 9 kll0715a22 O k110715a22 1 k110715a22 2 k110715a22 3 k110715a22 4 k110715a22 S k110715a22 6 k110715a22 7 kl10715a22 8 kl10715a22 9 k110715a23 0 kl10715a23 1 kl107l5a23 2 k110715a23 3 k110715a23 4 k110715a23 5 k110715a23 6 k110715a23 7 k110715a23 8 k110715a23 9 k110715a24 0 k110715a24 1 k110715a24 2 k110715a24 3 k1l0715a24 4 k1l0715a24 5 k110715a24 6 k110715b24 4 kl10715b24 5 Sampl e I D

GLP104)1411-184)9 5 GLP104)14)1-1»4)9 6 GLP104)14)1-18419 7 Solven tBlan k Solven tBlan k "ll00i.26: 9 Solven tBlan k GLP10-0H)1-18-O9 8 GLP104)14)1-18439 9 GLPTl>-0T4)1-18-T6 b GLP104)14)1-18-10 1 GLP104)14)1-18-10 2 GLP104)14)1-18-10 3 GLP1O-OlJ0i-iB-ld 4 "GLPTSovSviSior" ' GLP10-014)1-18-10 6 GLP104)14)1-18-10 7 Solven l Blan k Solven tBlan k 11003-26-1 1 Solven tBlan k GLPl64)1-dl-1w6 8 GLP104)14)1-18-10 9 GLP104)14)1-18-11 0 GLP104)14)1-18-11 1 GLP104)14)1-18-11 2 GLP104)1-01-18-11 3 GLP104)14)1-18-11 4 

## i5?If52*tl!il!L

GLP104)14)1-18-11 6 GLP104)14)1-18-11 7 Solven tBlan k |Soli«niiBtenk

_ 11003-26-1 0 Solven tBlan k GLP I 0-014)1-18-11 8 GLP104)14)1-1S-11 9 GLP104)14)1-18-12 0 GLP104)14)1-18-12 1 GLP104)14)1-18-12 2 GLP104)14)1-18-12 3 GLP104)14)1-18-12 4 GLP I 04)1-01-18-12 5 GLP10-014)1-18-12 6 GLP10-01-01-18-12 7 Solven tBlan k Sohen tBlan k 11003-26- 8 Solven tBlan k GLP104)14)1-18-13 3 GLPTb4)14)1-Ts;i3 4 GLPlO-014)1-18-12 8 GLP104)14)1-18-12 9 GLP104)14)1-18-13 0 GLP104)1411-18-13 1 GLP104)1-01-18-13 2 Solven tBlan k Solven tBlan k 11003-26- 9 Soiven tBlan k Solven tBlan k 11003-26- 9 Sampl e Commen t

DA LGW137SL S 11062 4 DA LG W137 S M S 11062 4 DA LG W137 S H S 11062 4 MiD i Q Wate rTN I 14)23 4 MID I Q Wate rTN114)23 4 2. 5 ng/m LF C st d i n Mil U Q Wate r MiD i Q Wate rTN I 14)23 4 DA LGW137 L0 11062 4 DA LGW137LD B 11062 4 DA LGW137LL S 11062 4 DALGW137LM S 11062 4 DA LGW137LI4 S 111)624 DA LG W138 R 0 11063 0 (di l 1:10 ) DA LG W138 R D B 11063 0 (di l 1:10 ) DA LG W138 R L S 11063 0 (d D 1:10 ) DA LG W138 R M S 11063 0 (di l 1:10 ) DA LG W138 R H S 11063 0 (di l 1:10 ) Milli Q Wate rTN114)23 4 Min i 0 Wate rTN114)23 4 1 0 ng/m LF C st d i n Mil D Q Wate r Min i Q Wate rTN1141234 DA LGW138 L011063 0 DA LGW138LD B 11063 0 DA LGW138LL S 11063 0 DA LGW138 LM S 11063 0 DALGW138LH S 11063 0 DA LG W138 S 0 11063 0 (di l 1:10 ) DA LG W138 S D B 11063 0 (di l 1:10 ) DALG W138 S L S 11063 0 (d D 1:10 ) DA LG W13S S M S 11063 0 (d D 1:10 ) DA LG W138 S H S 11063 0 (di l 1:10 ) MiD i Q Wate rTN114)23 4 Milli Q Wate rTN I 14123 4 5. 0 ng/m LF C st d i n Min i Q Wate r MID I Q Wate rTN I 14)23 4 DA LG WCW26 C 0 11062 2 (di l 1:10 ) DA LG WCW26 C D B 11062 2 (di l 1:10 ) DA LGWCW26 C L S 11062 2 (di l 1:10 ) DA LG WCW26 C M S 11062 2 (di l 1:10 ) DA LG WCW26 C H S 11062 2 (di l 1:10 ) DA LGWCW26 L0 11062 2 (di l 1:10 ) DA LG WCW26 LD B 11062 2 (di l 1:10 ) DA LG WCW26 LL S 11062 2 (d D 1:10 ) DA LG WCW26 LM S 11062 2 (d U 1:10 ) IJArG WCW26riHSTlb62 2 W^^^^ ^ Milli Q Wate rTN114)23 4 Milli Q Wate rTN114)23 4 1. 0 ng/m LF C st d i n MiD i Q Wate r Milli Q Wate rTN114)23 4 DALGW130LR B 11063 0 DA LGW133SR B 11063 0 DA LG W140 R 0 11062 2 (di l 1:10 ) DA LG W140 R D B 11062 2 (di l 1:10 ) DA LG W140 R L S 11062 2 (d D 1:10 ) DA LG W140 R M S 11062 2 (d D 1:10 ) DA LG W140 R H S 11062 2 (di l 1:10 ) MID I Q Wate rTN114)23 4 MID I Q Wate rTN I 14)21 4 2. 5 ng/m LF C st d i n Min i Q Wate r MiD i Q Wate rTN I 14)23 4 Milli Q Wate rTN I 14)23 4 2. 5 ng/m LF C st d i n Mill i Q Wate r Sampl e Typ e

Unknov m Unicnow n Unknov m Unknow n Unknow n Qualit yContro l Unknow n "ijnknov m Unknow n IJnknov m Unknov m Unknov m Unknov m Unknov m " " Unknov m Unknov m Unknov m Unknov m Unknov m Quality " Contro l Unknow n Unkncivm " Unknow n Unknov m Unknov m Unknov m Unknov m Unknov m Unknov m Unknov m Unknow n Unknov m Unknov m Qualit yContro l Unknov m Unknov m Unknow n Unknov m Unknow n Unknov m Unknow n Unknov m Unknovm" " Unknov m Unknov m Unknow n Unknow n QualD yContro l Unknow n Unknow n Unknov m Unknov m Unknow n Unknow n Unknov m Unknov m Unknov m Unknov m QualK yContro l Unknow n Unknow n Qualit ycontro l Analyt e Pea k Nam e PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO AJ PFO A^ PFOA " PFOA " PFO A PFO A PFO A PFO A PFO A PFO A' PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFCJ A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFOA " PFO A PFO A PFO A PFOA " PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A /Uialyt e PeakAre a (counts ) 73350 8 218067 2 1643019 6 2424 7 1138 1 473894 9 687 5 71396 8 72939 6 965110 " 247917 6 175M35 7 4758369 2 4672684 5 4738328 2 5802185 7 9441552 1 5109 8 1426 5 ^7469490 " 3484 9 1655909 " " " 166058 9 180597 6 309223 3 1611972 5 560433 7 1555701 6 583636 6 830139 0 2124568 5 Igj^ g '"6440 863913 8 960 8 1508764 1 1^029361" " 1542051 4 1763811 1 2873142 2 2239230 8 2237152 2 2313183 7 2493286 7 3569119 7 1091 4 849 3 183237 2 1478 6 1941 8 M87 8 460448 7 472"647 2 513599 5 804124 7 1982838 7 2156 2 657 8 439705 3 1330 7 4884 3 455666 6 lAnalyt e Retentio n {Analyt e concentratio n Tim e (mm ) (ng/mL ) 1 5 4 15 4 "15 4

" 1 5 5" " 1 5 4 "1 5 4 "15 5 "1 5 4 1 5 4 "l" 5 4 " " 15 4 1 5 4 " " 15 4 115. 4 115. 4 15. 4 15. 4 15. 5 15. 4 15. 4 15. 5 15. 4 15. 4 15. 4 1 5 4 1 5 4 15 4 1 5 4 1 5 4 1 5 4 1 5 4 1 5 6 1 5 5 1 5 4 1 5 5 15 4 15 4 15 4 15 4 15 4 15 4 15 4 15 4 15 4 1 5 4 1 5 5 1 5 5 1 5 4 1 5 5 1 5 5 15 4 1 5 4 15 4 1 5 4 15 4 15 4 15 4 1 5 5 1 5 4 1 5 4 1 5 5 1 5 4 N/ A N/ A N/ A N/ A Us e Recor d Calculate d

Concentratio n (ng/mL ) 0.38 3 1 1 8 9 3 2

K O N/ A 25 0 0 < 0 2"6 1 N/ A|< 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 10. 0 N/ A N/ A N/ A N/ A ~ S 0 37 2 0 38 1 —~ ~ 0 47 7 1.35 9.¥s" ' 294

. 288

. 292

. 370

. 709

. 0 0080 0

< 0 99 4 ~ ~ —

< 0 '0S9 1

N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 5.0 0 E N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 1.0 0 E l N/ A N/ A N/ A N/ A N/A " N/A " N/ A N/ A N/ A N/ A 2.5 0 : E l N/ A N/ A 2.5 0 E l 0.89 4 0.97 4 1.6 9 9.1 4 155

. 153

. 161

. 231

. 610

. < 0

< 0 4.81

< 0 427

. 425

. 436

. 502

. 841

. 645

. 644

. 667

. 723

. 1060

. < 0

< 0 0.98 9

< 0

< 0

< 0 127

. 130

. 141

. 223

. |567 ^

< 0 <6" 2.4 1

< 0 0.0067 6 2.5 0 Accurac y



## (%) N/ A N/ A N/A" " N/ A N/ A 104 ! W A N/ A" N/A" N/A " N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 99 4 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 96. 1 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 98. 9 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 96. 6 N/ A N/ A 100

. Recor d

Modifie d E l 

# a " a D 1

E I 1 " D "

"'E l E l E l D E l E l " E l "El " 

## m a E l D

E l E I E l _„.E1„ ^ E l E l E l E l E l E l 

## n D E l D E l E l E l E l E l E l E l E l E l E l D D E l 

# n E l E l E l E l E l E l E l E l D D E l E l E l Dilutio n

Facto r



## ;:::. :

1

1 0 1 0 1 0 1 0 1 0 Acquisitio n Dat e

7/18/201 1 9:17:3 2 A M 7/18/201 1 9:38:4 5 A M 7/18/201 1 10:00:01A M 7/18/201 1 10:21:1 4 A M 7/18/201 1 10:42:3 2 A M 7/18/201 1 11:03:4 5 A M 7/18/201 1 11:25:0 0 A M 7/18/201 1 11:46:1 4 A M 7/18/20T f12:07:3 0 P M 7/18/201 1 12:28:4 2 P M 7/18/201 1 12:49:5 8 P M 7/18/201 1 1:11:1 5 P M 7/18/201 1 1:32:3 0 P M 7/18/201 1 1:53:4 4 P M 7/18/201 1 2:14:5 7 P M 7/18/201 1 2:36:1 7 P M 7/18/201 1 2:57:3 2 P M 7/18/201 1 3-18-44P M 1 7/18/201 1 3 4 0 0 0 P M 1 |7/18/201 1 4 0 1 1 3 P M

5 0 5 0 5 0 5 0 5 0 1 1 1 1 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 1 1 1

1 " • 1 1 5 0 

# =°

. 

# _^. 

# ^ 5 0 5 0 |5 0 

# J - 7/18/201 1 4 2 2 2 9 P M

7/18/201 1 4 4 3 4 4 P M 7/18/201 1 5:05:0 0 P M "7/18/201 1 5:26:1 7 P M 7/18/201 1 5:47:3 2 P M 7718/201 1 6:08:4 7 P M 7/18/201 1 6:30:0 4 P M " * 7/18/201 1 6:51:1 4 P M 17/18/201 1 7:12:1 3 P M 7/18/201 1 7:33:1 3 P M 7/18/201 1 7:54:2 2 P M 7/18/201 1 8:15:2 6 P M 7/18/201 1 8:36:3 5 P M 7/18/201 1 8:57:4 8 P M 7/18/201 1 9:19:0 3 P M 7/18/201 1 9:40:1 9 P M 7/18/201 1 10:01:3 1 P M 7/18/201 1 10:22:3 5 P M 7/18/201 1 10:43:4 3 P M 7/18/201 1 11:04:5 0 P M 7/18/201 1 11:25:5 2 P M 7/18/201 1 11:47:0 1 P M 7/19/201 1 12:08:0 3 A M 7/19/201 1 12:29:0 4 A M 7/19/201 1 12:50:1 0 A M 7/19/201 1 1:11:1 3 A M 7/19/201 1 1:32:2 1 A M 7/19/201 1 1:53:4 2 A M 7/19/201 1 2:14:5 8 A M 7/19/201 1 2:36:2 0 A M 7/19/201 1 2:57:3 6 A M 7/19/201 1 3:18:5 1 A M 7/19/201 1 3:39:5 9 A M 7/19/201 1 4:01:0 7 A M 7/19/201 1 4:22:1 2 A M 7/19/201 1 4:43:1 6 A M 7/19/201 1 5:04:1 7 A M 7/19/201 1 5:25:3 1 A M 7/19/201 1 5:46:4 8 A M 7/19/201 1 6:08:0 4 A M 7/19/201 1 9:03:4 3 A M 7/19/201 1 9:24:5 9 A M

Dat a worke d u p b yKJ U

Printin g Time : 12:10:4 9 P H Printin g Date : Wednesday , Jul y20 , 201 1Workstation : Result s N a kll0715a.rd b

24 9 25 0 25 1 25 2 25 3 25 4 25 5 25 6 25 7 25 8 I2M~ ' 26 0 26 1 26 2 26 3 26 4 26 5 26 6 26 7 26 8 26 9 27 0 27 1 27 2 27 3 ^7 4 27 5 27 6 27 7 Sampl e Nam e

k110715b24 6 k110715b24 7 k1l0715b24 8 k110715b24 9 k110715b25 0 k110715b25 1 k110715b25 2 k110715b25 3 k110715b25 4 k110715b25 5 k1107l5b25 6 k110715b25 7 k1107l5b25 8 k110715b25 9 k110715b26 0 k110715b26 1 k110715b26 2 k110715b26 3 k110715b26 4 k110715b26 5 kl10715b26 6 k110715b26 7 kl10715b26 8 k1107151)26 9 kl10715b27 0 kl10715b27 i k110715b27 2 kl10715b27 3 kl10715b27 4 Sampl e I D

Sohen tBlan k GLP104)14)1-18-13 5 GLP1(M)14)1-18-13 6 GLP104)14)1-18-13 7 GLP104)14)1-18-13 S GLP104)14)1-18-13 9 GLP104)1-01-18-14 0 GLP10-014)1-18-14 1 GLP1(M)14)1-18-14 2 GLP104114)1-18-14 3 GLP104)14)1-18-14 4 Solven tBlan k Solven tBlan k 11003-26-1 1 Solven tBlan k GLP104)14)1-18-14 5 GLP104)14)1-18-14 6 GLP104)14)1-1B-14 7 GLP104114)1-18-14 8 GLP104)14)1-18-14 9 GLP10-014)1-18-15 0 GLP104114)1-18-15 1 GLP104)14)1.18-15 2 GLP104)14)1-18-15 3 GLP104)14)1-18-15 4 Solven tBlan k Solven tBlan k 11003-26-1 0 Solven tBlan k Sampl e Commen t

Min i 0 Wate rTN114)23 4 DA LGW141 R 0 11063 0 DA LGW141RD B 11063 0 DA LGW141RL S 11063 0 DA LGW141 R M S 11063 0 DA LG W141 R H S 11063 0 (di l 1:10 ) DA LG W142 R 0 11062 2 (di l 1:10 ) DA LG W142 R D B 11062 2 (di l 1:10 ) DA LG W142 R L S 11062 2 (d D 1:10 ) DA LG W142 R M S 11062 2 (di l 1:10 ) DA LG W142 R H S 11062 2 (di l 1:10 ) MiD i Q Wate rTN I 14)234 MiD i Q Wate rTN114)23 4 1 0 ng/m LF C st d i n Min i Q Wate r Milli Q Wate rTN114)23 4 DA LG W143 R 0 11062 2 (d D 1:10 ) DA LG W143 R D B 11062 2 (di l 1:10 ) DA LG W143 R L S 11062 2 (d D 1:10 ) DA LG W143 R M S 11062 2 (di l 1:10 ) DA LG W143 R H S 11062 2 (di l 1:10 ) DA LG W144 S 0 11062 8 (d D 1:10 ) DA LG W144 S D B 11062 2 (di l 1:10 ) DA U G W144 S L S 11062 2 (d D 1:10 ) DA LG W144 S M S 11062 2 (di l 1:10 ) DA LG W144 S H S 11062 2 (di l 1:10 ) MiD i Q Wate rTN I 14)23 4 Sampl e Typ e

Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknov m Unknow n Unknow n Unknov m Unknov m Unknov m Unknov m Qualit ycontro l Unknov m Unknov m Unknov m Unknow n Unknov m Unknov m /Vnalyt e Pea k Nam e PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A Unknow n PFO A Unknow n PFO A Unknow n PFO A Unknov m Unknov m Unknov m MID I Q Wate rTN I 14)23 4 iUnknow n 5. 0 ng/m LF C st d i n Min i Q Wate r MiD i Q Wate rTN114)23 4 Qualit yContro l PFO A PFO A PFO A PFO A PFO A Unknow n :PFO A Analyt e PeakAre a Analyt e Retention'Analyt e concentratio n (counts ) Tim e (min ) (ng/mL ) 2131 1 i15. 4 291899 7 |15. 4 287604 0 :i5. 4 454606 5 15. 4 385496 3 15. 4 335422 9 185717 8 190354 0 188328 6 212304 3 524568 6 453 2 781 7 1734530 5 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 6 15. 9 15. 4 1473 0 i15. 7 425276 5 115. 4 451670 1 464086 9 599438 0 2038220 1 192731 8 181669 8 189599 3 222480 1 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 15. 4 501517 6 il5. 4 677 4 J1S. 5 257 2 ;iS. 5 904116 6 '15. 4 1472 6 ;15. 5 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 10. 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A



# , _ N/ A N/ A N/ A N/ A N/ A 5.0 0 N/ A Us e Recor d



### E l

E l Calculate d Concentratio n (ng/mL )

< 0 1.5 9 1.5 7 2.5 0 10. 6 91. 6 50. 1 51. 4 50. 9 57. 5 144

. < 0

< 0 9.8 7

< 0 23. 3 24. 8 25. 5 33. 1 117

. 52. 1 49. 0 51. 2 60. 3

< 0

< 0 5.0 4

< 0 /Accurac y



## (%) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 98. 7 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 101

. N/ A Recor d

Modifie d 

### E l E l E l E l E l E l E l E l E l E l E l D D 

### E l D 

### E l E l E l E l E l E l E l E l El " 

### E l D 

### E l E l E l Dilutio n

Facto r

5 0 5 0 5 0 5 0 5 0 5 0 1 1 1 1 1 0 1 0 1 0 1 0 1 0 5 0 5 0 5 0 5 0 5 0 1 1 1 1 Acquisitio n Dat e

7/19/201 1 9:46:1 4 A M 7/19/201 1 10:07:2 7 A M 7/19/201 1 10:28:3 9 A M 7/19/201 1 10:49:5 4 A M 7/19/201 1 11:11:0 6 A M 7/19/201 1 11:32:1 5 A M 7/19/201 1 11:53:1 7 A M 7/19/201 1 12:14:2 1 P M 7/19/201 1 12:35:2 2 P M 7/19/201 1 12:56:2 0 P M 7/19/201 1 1:17:1 8 P M 7/19/201 1 1:38:1 8 P M 7/19/201 1 1:59:2 4 P M 7/19/201 1 2:20:3 8 P M 7/19/201 1 2:41:5 1 P M 7/19/201 1 3:03:0 2 P M 7/19/201 1 3:24:2 1 P M 7/19/201 1 3:45:3 2 P M 7/19/201 1 4:06:4 7 P M 7/19/201 1 4:28:0 1 P M " 1 7/19/201 1 4:49:1 2 P M 7/19/201 1 5:10:1 8 P M 7/19/201 1 5:31:2 0 P M "7/19/2011 " "5:52:2 0 P M 7/19/201 1 6:13:2 0 P M 7/19/201 1 6:14:1 9 P M 7/19/201 1 6:55:2 6 P M 7/19/201 1 7:16:3 6 P M 7/19/201 1 7:37:5 4 P M

rke d u p b yKJ U Pag e 5 o f 5

Printin g Time : 12:10:4 9 P M Printin g Date : Wednesday , Jul y20 , 201 1

# 3 M Confidentia l 3 M Environmenta l Laboratory Project : GLP10-01-01-1 8 Sequenc e k110728 a 3 M Environmenta l Laborator y 3 M Technica l Lead : Susa n Wol f Buildin g 260-5N-1 7 651-733-985 1 Repor tAuthor : Chelsi e Grocho w Analytica l Team : Kell yUke s



# Analytica l Cas e Narrativ e fo rMetho d ETS-8-44. 0

Projec tGLP10-01-01-1 8 Decatu rPhas e 3 FSI AGroundwater

- Jun e 201 1

Direc tinjectio n analysi s o

fsamples Sequenc e kl10728 a ReportDate : Jul y29 , 2011

Instrumen tsummar

yan d calibratio n curve s wil l be printe d an d include d i n th e ra wdata package

.
Chromatogram s wil l b e printe d to pdf

.

ET S 8-04 4 Analytica l SummaryChecklis tPag e 1 o f3

## 3I\/I Confidentia l



# 1 Projec tScop e an d Dat a Qualit yObjectiv e 3 M Environmenta l Laboratory Project : GLPlO-01-01-1 8 Sequencekl10728 a

Genera l ProjectOutlin e available

.

GL P E I Ye s

1 3 Ye s n N o

n N o I fNo , Pleas e briefl ydescrib e

projec tscop e an d DQ O



# 2 Sampl e Containe rPreparatio n

Sampl e containe rpreparatio n documente d i n a Not e to Fil e an d Include d i n th e ra wdata package

. 

# 3 Sampl e Analysi s

3. 1 Syste m Suitabilit y

Initia l Syste m Suitabilit yare a count s wit h RS D S5 % (ETS-8-15 4 sectio n 10.5 ) an d retentio n tim e wit h RS D s2 % 

# 1 3 Ye s DN o



# 3.1. 1 Syste m Suitabilit yDeviation s
N A 

# 3. 2 Instrumen tCalibratio n Curv e typ e r'>0.99 0 Linearit ycriteri a me t (ETS-8-4 4 sectio n 12.2 )

< ±25 % residuals , excep tLO Q o f±30 % (ETS-8-4 4 sectio n 12.2 ) Mid-leve l calibratio n point s disable d Quadratic , 1/ x 1 3 Ye s 1 3 Ye s DYe s D N o

D N o 1 3 N o



# 3. 3 Continuin g Calibratio n Verificatio n

±25 % Difference criteri a me t fo rperiodi cCCV

s (ETS-8-44 sectio n 12.2 ) 

# 1 3 Ye s DN o

3.3. 1 Continuin g Calibratio n Verificatio n Deviation s
N A



# 3. 4 Metho d Blank s

Metho d blank s uniquel yidentifie d i n th e ru n sequence

. Averag e are a count s o ftarge tanalyte s i n th e metho d blan k presen ta t 2 V

4 x th e are a count s o fth e LO Q standar d (ETS-8-4 4 Sectio n 10.2 ) 1 3 Ye s

1 3 Ye s D N o

D N o



# 3.4. 1 Metho d Blan k

Deviation s N A

ET S 8-04 4 Analytica l SummaryChecklis t Pag e 2 o f3

# 3 M Confidentia l



# 3. 5 La b Contro l Spike s 3 M Environmenta l Laboratory Project : GLPlO-01-01-1 8 Sequenc e k l 10728 a

±20 % recoverycriteri a me t(ET S 8-4 4 Sectio n 10.5 ) <20 % RS D precisio n (ET S 8-4 4 Sectio n 10.5 ) 1 3 Ye s 1 3 Ye s D N o

D N o 

# 3.5. 1 La b Contro l Spik e Deviation s N A 

# 3. 6 Sampl e Replicate s

RP D fo rfiel d duplicate s <20 % (ETS-8-4 4 Sectio n 10.5 ) 1 3 Ye s D N o 

# 3.6. 1 Sampl e Replicate s Deviation s N A 

# 3. 7 Fiel d Matri xSpike s

±30 % recoverycriteri a met

. (ET S 8-4 4 Sectio n 10.5 ) 1 3 Ye s D N o 

# 3.7. 1 Fiel d Matri xSpik e Deviation s N o appropriate spik

e leve l to assess sampl e recover yfo r135S

. 

# 3. 8 Limi to fQuantitatio n (LOQ )

Al l LOQ s equa l th e low-leve l calibratio n standar d concentratio n wit h are a count s a tleas ttwic e tha to fth e metho d blank(s ) (ET S 8

- 4 4 Sectio n 10.2 ) 1 3 Ye s D N o



# 3. 9 Manua l Integration s Manua l integratio n reviewe d b yanothe ranalyst/tea m lead : Date : *&|>|i l Reviewed bv : tcf ^ 1 3 Ye s DN o



# 4 Additiona l analytica l note s

Al l data wil l be reported

. 

# 5 Signature s



# ^VihiiL'^/iArrhM^ ) •^-2^- 1 \ Analys t Dat e

ET S 8-04 4 Analytica l SummaryChecklis t Pag e 3 o f3

# Kir k AP I5500 , BB2150101 0 pag e1/ 1

DATE : 7/28/201 1

ANALYST : CJG

STUD YNUMBER : GLPlO-01-01-18

. GLPlO-01-01-1 9 Sampl ePre p Date : 7/26/1 1 Sampl eAliquo t

Date : 7/26/1 1

LC/MS/M S Method : PFOAwit hI S

Mobil ePhase : (A ) 2m M ammoniumacetate(aq) (B ) Methano l

TN-A

- o r standardnumber

(A ) 11005-120 (B ) TN I1-024 0 8/ 8

Guar dcolumn : Betasi l€1 8 Colum n4.6xl00mm Size : 5 uLot

number : 10827 Seria lnumber 0213785K 3 started6/27/1 1 Par t number : 70105-10463 0

Analytica lcolumn : Betasi lC1 8 Colum n4.6xl00mm Size : 5uLot

number : 10827 Seria lnumber 0213786K

4 started : 6/27/1 1 Par t number : 70105-10463 0

DATAFILE : k l10728 a

Seemetho dfo

r LC/MS/M S parameter s 

# c^cbimiw

Printed : Thursday , July 28 , 201 1 9:47 A M

### •Kir k BB2150101 0

Prajed ; P:\Pro]ect*LabJnstnjmenlData\KirMkrkdala\Pro|ectSfluorocliemlcals_walerBatch:k110728 a TabiSampl e Sel:SET 1 AcqMothod:PFOAwit h IS.da m Sampl e

1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0

2 2 2 3 2 4 2 5 2 6 2 7 2 8 2 9 30 3 1 32 33 34 35 36 3 7 38 3 9 4 0 4 1 42 4 3 4 4 4 5 4 6 4 7 4 8 4 9 6 0 5 1 52 5 3 54 55 5 6 5 7 5 8 5 9 6 0 6 1 6 2 63' ^ ' 6 4 6 5 6 6 6 7 6 8 6 9 70 7 1 Sampl e Nam e I<110728a00 1 k110728a002 k110728a00 3 k110728a00 4 k110728a00 5 k110728a00 6 kl10728300 7 k110728a00 8 k110728a00 9 k110728a01 0 k110728a01 1 k110728a01 2 kl10728801 3 k110728a01 4 k110728a01 5 k110728a01 6 k110728a01 7 k110728a01 8 k110728a01 9 k110728a02 0 kl10728302 1 k110728a02 2 kl16723302 3 k110728a02 4 kri0728a02 5 k110728a02 6 kl10728302 7 kl10728302 8 kl10728302 9 k110728303 0 kl10728303 1 kl10728303 2 kl10728303 3 kl10728303 4 kl10728303 5 kl10728303 6 kl10728303 7 kl10728303 8 k110728a03 9 k110728304 0 kl10723304 1 kl10728304 2 kl10728304 3 kl10728304 4 kl10728304 5 kl10728304 6 kl10726304 7 kl10728304 8 kl10728304 9 kl10728305 0 kl10728305 1 kl10728305 2 kl10728305 3 kl10728305 4 k110728a05 5 kl10728305 6 k110728a05 7 kl10728305 8 k110728a05 9 k110726306 0 kl10728306 1 kl10728306 2 k110728306 3 k110728306 4 k110728306 5 k110728a06 6 kl10728306 7 k110728a06 8 k110728a06 9 k110728307 0 k110728307 1 Sampl e I D

11005-5 9 11005-5 9 11003-25- 8 11003-25- 8 1 1 003-25- 8 1 1 003-25- 8 11005-5 9 11005-5 9 1 1 003-25- 1 1 1 003-25- 2 11003-25- 3 11003-25- 4 11003-25- 5 11003-25- 6 11003-25- 7 1 1 003-25- 8 11003-25- 9 1 1 003-25-1 0 1 1 003-25-1 1 11003-25-1 2 1 1 003-25-1 3 11003-25-1 4 11003-25-1 5 11003-25-1 6 1 1 005-5 9 11005-5 9 1 1 005-5 9 LCS-110726- 1 LCS-110726- 2 LCS-110726- 3 LCS-110726- 4 LCS-110726- 5 LCS-110726- 6 LCS-110726- 7 LCS-110726- 8 LCS-110726- 9 11005-5 9 11005-5 9 11003-25-1 0 1 1 005-5 9 LCS-110726-1 0 LCS-110726-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 5 LCS-110726-1 6 LCS-110726-1 7 LCS-110726-1 8 1 1 005-5 9 11005-5 9 11003-25- 9 1 1 005-5 9 1 1 005-5 9 GLP I 0-01-01-19-00 9 GLP I 0-01-01-19-00 1 GLP I 0-01-01-19-00 2 GLP I 0-01-01-19-00 3 GLP I 0-01-01-19-00 4 11005-5 9 GLP I 0-01-01-19-00 5 GL H 0-01-01-19-00 6 GLP I 0-01-01-19-00 7 GLP I 0-01-01-19-00 8 1 1 005-5 9 1 1 005-5 9 1 1 003-25- 8 1 1 005-5 9 GLP I 0-01-01-19-01 0 GLP I 0-01-01-19-01 1 GLP I 0-01-01-19-01 2 Via l Positio n 9 1 9 1 8 8 8 8 92 9 2 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 1 6 92 9 3 9 3 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 2 5 9 4 94 1 0 95 2 6 2 ^ 2 8 2 9 30 3 1 32 33 34 95 9 6 9 9 6 9 7 3 5 3 6 37 38 3 9 9 7 4 0 4 1 42 4 3 9 7 9 8 8 9 8 4 4 4 5 4 6 Data Fil e | Inj.Volum e (|il )

kl10728 a kl10728 3 k l 10728 3 kl10728 3 k l 10728 a kl10728 3 k l 10728 a kl10728 3 kl10728 3 kl10728 3 kl10728 3 kl10728 3 kl10728 3 kl10728 a kl10728 3 kl10728 3 kl10728 3 k l 10728 a kl10728 a kl10728 3 kl10728 a kl10728 3 kl10728 3 kl10728 3 kl10728 a kl10728 a kl10728 a kl10728 3 kl10728 3 kl10728 3 k l 10728 3 kl10728 a k l 10728 3 k l 10728 a kl10728 a kl10728 a kl10728 a kl10728 a kl10728 3 k l 10728 a kl10728 a kli0728 a kl10728 a k l 10728 a k l 10728 3 k l 10728 3 k l 10728 a k110728 3 k l 10728 a k l 10728 a k l 10728 a k l 10728 3 k110728 3 k110728 3 k110728 a kl10728 a k110728 3 k110728 3 kl10728 a kl10728 3 kl10728 3 k l 10728 3 k110728 a k110728 a k110728 3 k l 107283 k l 10728 3 kl10728 a k l 10728 a k l 10728 3 k l 10728 3 25.00 0

25.00 0 25.6d 0 25.00 0 25.6b d 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.d6 b 25.00 0 25.00 0 26.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 26.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 Comment s

Method Blen k Method Blan k 1. 0 ng/m LF

C st d i n Synth

. Wate r 1. 6 ng M F

C st d i n Synth

. W3te r 1. 0 ng/m LF

C st d i n Synth

. Wete r 1. 0 ng/m LF

C st d i n Synth

. Wete r Method Blen k Method Blan k 0.02 5 ng/m LF

C st d i n Synth

. Wate r 0.0 3 ng/m LF

C st d i n Synth

. Wete r 0.04 ng/m LF

C st d i n Synth

. Wate r 0.0 5 ng/m LF

C st d i n Synth

. Wate r 0. 1 ng/m LF

C st d i n Synth

. Wate r 0.2 5 ng/m LF

C st d i n Synth

. Wete r 0. 5 ng/m LF

C st d i n Synth

. Wete r 1. 0 ng/m LF

C st d i n Synth

. Wete r 2. 5 ng/m LF

C st d i n Synth

. Wate r 5. 0 ng/m LF

C st d i n Synth

. Wete r 1 0 ng/m LF

C st d i n Synth

. Wate r 1 5 ng/m LF

C st d i n Synth

. Wate r 2 5 ng/m LF

C st d i n Synth

. Wate r 5 0 ng/m LF

C st d i n Synth

. Wate r 75 ng/m LF

C st d i n Synth

. Wete r 10 0 ng/lT l F

C st d I n Synth

. Wate r Method Blan k Method Bl3n k Method Blen k 0.2pp b LCS 0.2pp b LCS 0.2pp b LCS 2pp b LCS 2pp b LCS 2pp b LCS 20pp b LCS 20pp b LCS 20pp b LCS Method Blen k Method Blsn k 5. 0 ng/m LF

C st d i n Synth

. Wate r Method Ben k 0.2pp b LCS ECF 0.2pp b LCS EC F 0.2ppbLCSEC F 2pp b LCS ECF 2pp b LCS ECF 2pp b LCS ECF 20pp b LCS ECF 20pp b LCS ECF 20pp b LCS ECF Method Blen k Method Blan k 2. 5 ng/m LF

C st d i n Synth

. Wate r Method Han k Method Bl3n k DALGWBPMW12 1 R

S 11071 3 CWLGWTRiP I 011071 3 DALGWTRIP 1 LS 11071 3 DALGWTRIP 1 M

S 11071 3 DALGWTRIP1H S 11071 3 Method Blan k DA LGWBPMW47 0 11071 3 DA LG WBPMW4

7 D B 11071 3 DALGWBPMW47LS11071 3 DA LGWBPMW47H S 11071 3 Method Blen k lUethod Blen k 1. 0 ng/m LF

C st d i n Synth

. Wate r Method Blan k D^LGWBF=MW12 1 0 11071 3 DALGWBPMW12 1 D B 11071 3 DALGWBPMW12 1 LS 11071 3



### Print;ing Time : 9:44:1 2 A M Printin g Date : Thursday , Jul y28 , 201 1 Pag e 1 o f 2 

# CJ<S7/2'S/) I

### *Kir k BB2150101 0

Project : P:\Project^ab_lnstnjmen tData\KJrMMrfcdata\Project£\f1uoroche[nicaIs_waterBatch:k110728 a TabiSampl e Set:SET 1 AcqMethod:PFO Awit h IS.da m Sampl e (Sampl e Nam e 72 73 74 75 76 "7 7 "" • 78 79 ' 8 0 8 1 kl10728307 2 kl10728307 3 kl10728307 4 kl10728307 5 ki16728367 6 kl10728307 7 kl10728307 8 k110728a07 9 k110728308 0 k110728a08 1 Sampl e I D

GLP I 0-01-01-19-01 3 11005-5 9 11005-5 9 GLP I 0-01-01-18-06 9 GLP I 0-01-01-18-07 0 GLP I 0-01-01-18-07 3 11005-5 9 11005-5 9 11003-25-1 1 11005-5 9 Via l Positio n 47 9 9 9 9 4 8 4 9 6 0 9 9 100 1 1 100 Data Fil e

kl10728 a kl10728 a kl10728 a kl10728 a kl10728 3 kl10728 3 kl10728 a k l 10728 3 kl10728 3 k110728 3 Inj.Volum e (pi )

25.00 0 25.00 0 25.66 6 J 25.00 0 25.00 0 25.66 6 25.00 0 25.00 0 25.00 0 25.00 0 Comment s

DALGWBPMW12 1 HS 11071 3 Method Blan k Method Blen k DA LGW135 S 011062 8 CALGW135SDB11062 8 mLGW135SH S 11062 8 Method Blen k Method Blan k 1 0 ng/m LF

C st d i n Synth

. Wate r Method Blan k



### Printin g Time : Printin g Date : 9:44:1 2 A M

Thursday , Jul y28 , 201 1 Pag e 2 o f 2

### •Kir k BB2150101 0

Acquisitio nInformation :

Aoqji^itio i Method : CEcated : las t MTriiflM ; OcriTHit : q^ff ^ 111

. .ii7at-i mMSJC : Aitu-Bjjilibiatiicn : itojjisitiici i cucarim : Hjiiae r o f scans : Eedaf eI nPile : itojiisitJ mttDdLOe : SoftMai eversi m

S-rirr l 1 :

Scan s i nPeriod : Relat^lv estar t

TiiiE : Ei^erinEnt s i nPerixxi :

Perio d1 B^^rinen t 1 :

Sca nT^pe : SdeJule dMM ; Balarity : Sca nM33e : li2 i Source : nesolutdxz i Ql : Besolutim03 : intensit y Three. : Settlin g Tims : M lreuse: hCR : s t ^ Size :

0 1 v& m(CB) 0 3 t^is s (ca ) I>,:ell{iiGec ) 413.00 0 369.00 0 30.0 0

CO

. ^BS S (TB ) 0 3 N6S S (IB ) DueUtriBCC ) 413.00 0 219.00 0 30.0 0

QlffisstDa ) 0 3 res s (ra ) D»ell(iraec ) 413.00 0 169.00 0 30.0 0

Q l^es B (CB ) 0 3 hBs s (EB ) Du=U(nBCC ) 421.00 0 376.00 0 30.0 0

EBianete r

l^l e(Perio d1 E5?)erijT»tf : 1 ) CU R CU D TI M OS l G5 2 35.0 0

6.0 0 450.0 0 55.0 0 50.0 0 IS : -4500.0 0

PLiip «riel : J^ilsi t 120 0 Binar y Eui p Miniitu nPressur e(psi) : 0. 0 texinunPressur e(pei) : 5801. 0 Dea dVblui edil ) : 40. 0 NbxijTunFle w I^n p (nil/niin>) ; 100. 0 Kodiiu nPressur eI^n p (pei/sec) : ^e xFlDURan p t * (ni/min' ) : 100. 0 texFlo w Ran p II I(ml/tnin O : 100. 0

Stq j Table : Ste p Tbta lTlnednin ) Flo w Rate(iiL/min ) C 0.0 0 75 0 1 2.0 0 75 0 2 14.5 0 75 0 3 15.5 0 75 0 4 16.5 0 75 0 £20.0 0 75 0

l£f t Onpressiljility : 50. 0

Lef t Dea d\t3lllI E(111 ) : 40. 0 Righ t Dea d\blij m(iH) : 40. 0 lef t Strct e«3lui e(liL) : Righ t Strrt e*lut Edil ) : Lef t Sdvm; : A l Righ t Solvmt : B l Bara n 

### a E £ 

### a CX E

EBran C E K C E C H

I^ua n C E E I 

### a CO T

EBran 

### a S C E CO T

290. 0

A( * 97. 0 97. 0 S. O S. O 97. 0 97. 0

-1. 0 -1. 0 [¥C1Awit hIS.da m WetiXBday Jul y 2 7 201 1 U : 44 : 1 3 i* I Itetiesda y Jul y 2 7 201 1 U : 44 : 1 3 » 1 ETOAwit hI S L C Syn c Cff 20min0se c 856 8 1 to(jisitiai Metha i toalyst

856 8 1.5. 2

0.0 0 nse c 1

n m(WW

) N 3 tfcgati^r e tV A •nnt o Stira y Uli t Uli t 0.0 0 cp e 0.000 0 nse c 5.007 0 nBe c K > 0.0 0 n a

star t -41.0 0 -8.5 0 -15.0 0 -6.0 0

Star t -41.0 0 -8.5 0 -22.0 0 -9.0 0

Star t -100.0 0 -10.0 0 -37.0 0 -9.0 0

Star t -41.0 0 - 8

. S O -15.0 0 -6.0 0

B (% ) 3. 0 3. 0 9S. 0 95. 0 3. 0 3. 0 Sto p IC -41.0 0 PFOA- 1 -8.5 0 -15.0 0 -6.0 0

Ste p I E -41.0 0 PEDA- 2 -8.5 0 -22.0 0 -9.0 0

Sto p I T -100.0 0 PFaA- 3 -10.0 0 -37.0 0 -9.0 0

Ste p I E -41.0 0 13C8PECIA-IS -8.5 0 -15.0 0 -6.0 0



### Printin g Time : 9:44:3 6 A M Printin g Date : Thursday , Jul y28 , Pag e 1 o f 2 

# C j 6 7/Z^/( (

### *Kir k BB2150101 0

;>gilen t Aitceaiple r

Pccpertle s Aitosanple r

Mxlel : .^^ilen t

120 0 StandardAitoGanpIer Syring eSla e(^a

) : 10

0 Uijectio n\tilui e(pi) : 2S.0 0 Dca w £(»e d(pl/min) : 200. 0 Ejec t £t«a i (pl/min) : 200. 0 Needl eleve l(mr

O : 0.0 0 ItoperaCur eQntro lEiiable d Setpoin t ( 4 - 40 O : 1 5 Vfeis hi s no t use d

tfeeQjstx mInjecto r

Ptrgrantto i^gilen t CbluT nCXfle nPrcpertie s Left T&ipeiatureC O : 30.0 0 Ric ^ Tfenperatur

e(" O : 20.0 0 T&rperadjr

eTbleranc e+/

- C O : 1.00 Star t flcqulsitionTblec3ix: e+/

- C O : 0.5 0 TiiT eTable(Used

) Oalxi mSwitdiin g ^alv eDistalle dCS V Ksitio nfo r

firs t sanpl ei nth etattii : Left Usesam epceitic nfo r

al lsanple s i nth ebat( ± Tbta lTme{miii) Mdlv

eEtisitio n 0.0 0 Lef

t S.O O Righ t



### Printin g Time : 9:44:3 6 A MPag e 2 o f 2 Printin g Date : Thursday , Jul y28 , 201 1

### Worlcstation : ETSKIR K Result s Name : kll0728a.rd b



## k110728a.rd b (PFOA) : "Quadratic " Regressio n (" 1 / x " weighting) : y= -0.0030 7 x'^ 2 + 1.0 9 x+ 0.016 6 ( r= 0.9998 )

80

-

75

-

70

-

65

-

60

-

55

-

50

-

45

-

40

-

35

-

30- ;

25

-

20

-

15 ^

10 ^



## 5

-

0

- 

# • r

^ y 

# • y 

# /

. • y 

# A y y y y y 

# •/ ^ y ' 

# X X

y ' 

## y y '



# ,' ' y ' 

# y'' "

, y ' 

## y ' ,•••-•• " ,y' ' , y ' 

# ,--''

,^' ' ,^''' ' ,,•••" '

,.,••• ' 

# y ^.^"

^ ,..^" " ^..'-" ' _.-

- ^..-'-^ ' .,•' •

^^' ' "-"" "

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 5 5 6 0 Analyt e Cone

. / IS Cone

. 6 5 7 0 

# 7 5 8 0 8 5 9 0 9 5 10 0

Dat a worke d up b

yKJ U

Printin g Time : 2:35:4 6 PM Printin g Date : Monday , Augus t 01 , 201 1 Pag e 1 o f 11 Sampl e Nant e

1 2 " 3 4 5 6 7 ' 

# «

• 9 N o

12 ~ 1 3 1 4 1 5 1 6 1 7 1 8 1 9 *2 D ' 21 " 2 2 k110728a00 1 ^ikTlO72aaO0 G k110728a00 3 k110728aOD 4 k11072Sa00 5 k11072aa00 6 k11O72aaO0 7 k110728a00 6 k11072SaOG S k110728aO1 D k'll672!abl 1 k110728aO1 2 k110728aO1 3 k11072Sa01 4 k110728aO1 5 k110728aO1 6 k11072aa01 7 klib728a6i a k110728aO1 9 kTib72aio2 0 k1lb72&b2 1 k110728a02 2 2 3 ;k110728aO2 3 2 4 k110728aO2 4 2 5 ^kllOTTflanTf i

' Xik l 10728302 6 2 7 ^k110728a02 7 2 S k110728aO2 8 2 9 iT l 1072^02 9 2 0 k110728a03 0 ^3 1 k110728aO3 1 13 2 3 3 3 4 36 ' 3 6 3 7 3 8 3 9 

# «

4 1 ~ 4 2 4 3 |4 4 4 5 4 6 4 7 4 8 4 9 5 0 5 1 5 2 b 3 5 4 "

5 6 5 7 58" "

6 1 6 2 6 3 6 4 6 5 

# * 6 7 6 8 6 9 k11072a303 2 kli0728a03 3 k110728a03 4 k11-6raWE 6 k110728a03 6 k11072BaO3 7 k110728aO3 8 k110728aO3 9 k11072SaO4 0 kl10728304 1 k1107MaO4 2 k110728a04 3 k110728aO4 4 kTl072tob4 5 kll0728a04 6 kl1072BaO4 7 k1107aaD4 a kl1072aa04 9 k i 107^305 0 k1107:fflaO5 1 k110728aO5 2 k110728aO5 3 k110728aO5 4 k110728aOS 5 k110728aCB 6 k l 107^305 7 kl10728aOS 8 k110728aO5 9 k110728a06 0 k110728a06 1 kl10728a06 2 k110728a06 3 k110728a06 4 k1107^a06 5 k110728a06 6 kl107^a06 7 k11072aai368 " •

• k110728a06 9 7 0 ik11072aa07 0 f fiklT072te67i"'~ " 7 2 k1l072BaO n 7 3 ;k1l072BaO7 3 7 4 'k110728a07 4 |7 S n<11072aa07 S " 7 6 kll072Sa07 6 7 7 ''k11072Ba07 7 7 8 kl10728aO7 8 SampkI D

1100&S 9 1100&6 9 iiooi5s e iio(»-2S a 11003.2 M 11003-25 ^ 1100&5 9 1100&5 9 11003-25- 1 11003-2S- 2 iiai3-2 M 11003-25- 4 11003-2& 5 11003-25- 6 11003-25- 7 i i 003-25 ^ 11003.2S a liaB-25-i b 11003-2S-1 1 iidb3-25-i2 " "" • 11003-25-1 3 11003-25-1 4 Sampl e Coramen t

Metho d Blan k Metho d Blar « 1. 0 r^m LF C Bt d i n Syrfh

. Wate r 1. 0 ng/m LF C M i n Synl KWate r 1. 0 nfl/m LF C U d i n Syrlh

. Wate r 1. 0 r^m LF C tt d i n Syrlh

. Wate r Metho d Blar * Metho d Blan k 0.02 5 r^lm l F C kt d ' m Syr«h

. Wate r 0.0 3 r^m LF C st d i n Synth

. Wate r 0.0 4 rg/m LF C st d i n Syrth

. Wate r 0.0 5 ng/m LF C st d i n Syrt KWate r 0. 1 nglm l F C st d i n Synth

. Wate r 0.2 5 i^m LF C st d i n Synth

. Wate r 0. 5 r^m LF C st d i n Synth

. Wate r i. O nftfm LF C st d i n Syrih

. Wate r Z 5 ng/m LF C st d i n Syrth

. Wate r 5. 0 r^m LF C st d i n Synth

. Wate r I D ngfrn LF C st d i n Synt h Wate r 1 5 r^m LF C stdln'Synth

. Wate T 2 5 ngfrn LF C st d i n Synth

. Wate r 5 0 nglm l F C st d i n Synth

. Wate r 1 1 003-25-1 5 ^75 ng/m LF C st d i n Synl KWate r 11003-25-1 6 11005-5 9 110055 9 11005-S 9 LCS-11D726- 1 LCS-11072&. 2 LCS-110726 O LCS-110726 ^ LCS-11072& 6 LCS-11072& e LCS-110726^7 ' •LCS^ii072M l LCS-iiD72& a 1100&6 9 1100&5 9 1 1 oro-s-1 0 11005 ^ LCS-11D72&-i 0 LCS-11D72S-1 1 LCS-110726-1 2 LCS-110726-1 3 LCS-110726-1 4 LCS-110726-1 5 LCS-110726-1 6 I Xrxf/m LF C st d i n Synt h Wate r Metho d Blan k Metho d Blan k Metho d Blan k 0 2pp b LC S 0 2pp b LC S 0 2ppbLC S 2ppbLC S 2ppbLC S 2ppbLC S 20ppbLC S 20ppbLCS " 2b^S>"LC S Metho d Blar * Metho d Blan k 5. 0 ng/m LF C st d i n SyrU vWate r Metho d Blar * 0.*p b LC S EC F 0.*p b LC S EC F 0.^p b LC S EC F 2pp b LC S EC F ilppbLCStCF ' 2pp b LC S EC F 2Cpp b LC S EC F LCS-110726-1 7 ;20pp b LC S EC F LCS-110726-1 8 irdbss g 20ppbLCSEC F Metho d Biar k IIOOS ^

IMethodBlar k 11003-2 M 11005-5 9 1100S5 9 GLP I 001-01- 1 »0 0 GLPltWI-OI-IM O GL P 1001-01-190 0 GLP I 001-01-190 0 GLP I 001-01-190 0 Tili05:s9 " ~ ' " GLP I 001-01-190 0 GLP I 001-01-190 0 GLP I 001-01-190 0 GLP1&01-01-190 0 iioc&5 9 11Q0&5 9 11003-25 * iioce^ ' GLP I 001-01- 1 M l GLP I 001-01-1^0 1 GLP I 001-01-190 1 GLP10Ol^)i-i9O 1 " 11005 ^

GLP10O1-01-1&0 6 GLP I 001-01-lft0 7 GLP I 001-01-IftO T 1100& ^ 2. 5 ng/m LF C st d i n Synth

. Wate r Metho d Blan k Metho d Blan k DA LG WBPMW12 1 R S 11071 3 DA LGWTRIP 1 011071 3 DALGWTRP1LS11071 3 DALGWmP I M S 11071 3 DALGWTRIP1H S 11071 3 Metho d Blan k CW.GWBPMW4 7 011071 3 DA LG WBPMW4 7 D B 11071 3 DA LG WBPMW4 7 LIS 11071 3 DA LG WB'PMW4 7 H S 11071 3 MdhSd'BUi * " " " Metho d Blan k 1. 0 ng/m LF C ct d i n Synth

. Wate r Metho d Blank" ' DA LG WBPMW12 1 0 11071 3 DA LG WBPMWii i D B 11071 3 DALGWBPMW12 1 L S 11071 3 DA LGW"BPMW12i"'His"' i 1071 3 "* Mtri'ho d Btiin k Metho d Blar * DA LGWiiSS'oi l 062 8 DA LGW135SD B 11062 8 DA LGW135SH S 11062 8 Metho d Blar * Sampl e Typ e | ^ ^

Unknow n USfSwn " " Ur*novii n Unknow n Unknow n Ur*now n Unknow n Unknow n Standar d Standar d PFO A

PFO A" " PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A Standar d jPFO A Standar d :PFO A Standar d iPFO A Standar d jPFG A Standar d iPFO A Standar d iPFO A Standar d 'standar d PFO A

PFO A Standar d iPFO A Sti^idiid" " "IPFtDA " ~""" ' " Siaritai d jPFO A Standar d Standar d Standar d LMcnow n PFO A

PFO A PFO A PFO A Lirfinow n ;PF6 A Unknow n Qualit yContro l Qualit yCarlitA ' Qlalily'C^ ^ Qualit yContro l Quality'Contro l PFO A

PFO A PFO A PFO A

PFO A Qualit yContit) ! IPFO A Qualit yCortro l 'PFO A Qualit yContro l Qualit yCortro l Ur*now n lA*now n Qualit yCortro l Unknow n Qualit yCortro l QuahtyCofir d Qualit yContm l Qualit yCortro l QinHTCwTrro t QuaGt yCortin l Qualit yCortro l QuaBtyCortra l Qualit yCartn: ^ LfcSrwvin' ^

" Unknow n Qualit yCortro l Urktm m Unknow n Unknow n tA*now n Unknow n Ur*now n Unknow n Ur*now n L**now n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yCortro l Unknow n Unknow n Unknow n Unknow n Unk'nowr i Unknow n Ur*nosv n Unknow n Unknow n Unkriow n Ur*now n PFO A

PFO A PFO A PFO A PFO A PFO A PFO A~ PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFOA " ~ " PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFOA * PFO A PFO A PFO A PFO A PFO A PFO A P'FO A PFO A PFO A PFO A PFO A PFO A •PFOA ^ •" " " PFO A PFO A PFO A PFO A PFO A PFO A Analyt e PeakAre a (count 4 4S31 0 1S46 4 163737 6 162605 2 162013 3 163839 1 3136 6

7490 6 8062 4 8897 1 11263 1 16969 0 43601 0 73700 0 166171 4 434146 9 764331 3 1545822 1 2532948 0 3914997 6 6709470 4 8678067 0 10109400 7 3170 4 3364 6 3678 9 41243 0 41479 5 42359 5 "• " "•" " ' 3727598 " " " 360635 0 36r756S4 3170723 5 J 319450^ " 3199604 6 2688 9 2595 5 770448 1 2485 2 40871 5 40881 3 41078 9 355880 3 3S4446 3 384062 5 3348741 1 3543237 0 3660856 7 :M56 7 3897 4 434997 6 2790 7 2460 7 2522 0 2507 4 52850 2 193628 9 3536242 7 3154 5 61116 0 62611 7 109943 4 244046 0 2649 2 " " 2741 0 169645 2 25386 ' 14226 4 14549 6 392302 2 3046^66""" " " ~ 2703 2 2991 1 3596857 8 3855179 1 713527 ^ 3243 5 Tim e (min ) 15. 7 1& 8 15. 7 15. 8 15. 7 15. 7 15. 8 15. 8 15. 8 15. 7 115. 8 "" ' " " 15. 8 15. 8 " 15. 8 15. 8 is:" ? 15. 8 15. 8 15. 7 15. 8 i & a 15. 8 15. 8 15. 8 15.7 " " • 15. 8 15. 8 15. 8 15. 8 15. 8 15: 8 " 15. 8 15: 8 "" " 15. 8 15. 8 15. 7 15. 7 15. 7 15. 7 15. 8 15. 8 15. 8 15. 8 15. 7 15. 7 15L 7 15. 8 15. 7 15. 7 15. 8 15. 7 15. 7 15. 8 15. 8 15. 8 i a 8 15. 8 15. 8 15. 8 ISTB " ~~ " " 15 8 15 8 15 8 1 5 8 1 5 8 15 8 15 8 15 8 1 5 8 1 5 8 1 5 8 1 5 7 " " is: 8 " 15. 7 15. 8 15. 7 15. 8 15. 8 Analyt e ConccRtratlo n (ngftn y N/ A 

## m N/ A N/ A N/ A N/ A N/ A

0.025 0 6.030 0 0.040 0 0.050 0 0.10 0 025 0 0.50 0 1. M 2.5 0 5.0 0 10. 0 15. 0 25. 0 50. 0 75. 0 1W

. N/ A N/ A N/ A 0.19 9 0.19 9 b:i9 9 1.9 9 1.9 9 i'.' ^ •"~ i 19. 9 19. 9 19. 9 N/ A N/ A 5.0 0 N/ A 0.19 9 0.19 9 0.19 9 1.9 9 T99 " " 1.9 9 19. 9 19. 9 19. 9 N/ A N/ A Z5 0 N/ A N/ A* " N/ A N/ A N/ A N/ A N/ A" • " ' N/ A N/ A N/ A W A N/ A "N/ A"" " N/ A i.r o W A W A W A W A W A'" ~ W A W A W A W A W A W A I S Pea k Nam e

13C8PFOA-I S 13C8PFOA4 S " 13C8PFOA^ S 13C8PFOArl S 13C8PF0A-< S 13C8PF0/W S 13C8PFbA4 S 13C8PF0Arl S 13CaPF0A-I S 13C8PF0A4 S 13C8PF0A-1 S i3C8PF0/W S 13C8PFbA4 S 13CaPF0A-I S 13C8PF0A-I S 13CePF0A-I S 13C8PF0A-I S 13C8PFOArl S 13C8PF0A-I S i"3C8PFOA4S' ~ iSCSPFOM S 13C8PFOA-I S i3CBPF0A4 S 13CBPFO/V4 S 13C8PFaVIS~ " iSCSPFOAj' S T3C8PFOA-I S i3C6PFOW S 13CePFbA-I S iSCSPFOWS "
13C8P'F6A4 S 13C8PFOA-I S i3C8PFOiM S 13C8PFOA-I S ^3C8PF6/^ & 1KMPFbA4 S 13C8PFOA4 S 13C8PFOA- K 13C8PFOA4 S I S PeakAre a (counts } 169935 6 169901 0 147499 8 145528 1 147525 6 146477 4 •i77T05 7 178615 6 163915 0 161985 1 141939 6 150810 1 138961 6 149652 7 147227 6 150581 7 158887 0 151936 0 150276 4 158060 9 154741 8 14ia» 0 134156 4 129109 7 176484 7 179121 3 178988 2 166627 7 167195 8 163484 7 166509 8 166485 1 i647% 2 159390 4 159094 0 159584 9 182062 2 181 ^ 157301 1 13C8PFOA4 S ; 182594 2 T3C8PF"bArt S 13C8PFOA4 S 13C8PFOA4 S 13C8PFOA4 S 13C8PFbA4 S 13C8PFOA4 S ^3C8PF0A4 S T3C8P"F0A4 S 13C8PFOA4 S 13C8PFOA4 S 13C8PFOAr4 S 13CSPF0/W S 13C8PFOA4 S 'i3C8PFOA-I S 13C8PFOW S 13C8PFOA4 S 13C8PFOA-I S 13CaPF0A-I S i3CBPF0A-I S 13C8PF0A-I S 13C8PFOAJ S 13C8PFOA-I S 13C8PF6W S 13C8PFOA-I S i^SPFOAJ S 13C8PFOA-I S 13C8PFOA-I S i3C6PF'OA4 S 13CSPF0A-I S 13C8PFOA-1 S 13C8PFOA-1 S 13C8PFOA-t S 13C8PFOA4 S 13C8PFOA-t S 13C8PFOA-t S 13C8PFOA-4 S i3C8PFbA4 S 13C8PFOA-I S 167905 2

161507 8 161157 5 162702 5 164527 8 1S3401 4 159720 2 157823 1 156849 5 i'84560 2 187693 3 160150 2 191073 9 133727 9 166242 0 184537 9 183414 7 182024 7 165305 5 1 193528 4 168317 5 118879 6 170070 3 161382 8 194943 0 205498 6 152076 7 201519 5 j j 56084 5 173962 2 171154 3 143341 3 234985 0 j234185 6 172593 7 172757 6 168524 0 238438 6 I S Retentio n Tim e (min )

15. 8 15. 7 15. 7 15. 8 15. 7 "l5. 7 15. 8 15. 8 15. 8 15. 8 15. 8 15. 8 15. 8 15. 8 is; ? 15. 8 i s ? 15. 7 15. 8 15. 8 1S 7 15. 8 15. 7 i5. 7 15. 8 15. 7 15. 8

i5. 8 15. 8 15. 8 i"5:' 7 15. 8 i5. 7 i'i s 15. 7 15: 7 15. 7 15. 7 15. 7 15. 8 15. 7 15. 7 15. 7 15. 7 15L 7 15. 8 15. 7 15. B 15. 8 15. 7 15. 8 15. 8 15, 8 15. 6 15. 8 15. 7 15. 8 15. 8 15. 8 1S. 8 15. 8 15. 8 i"5: 8 " " • 15. 8 15. 8 i'sa 15. 8 15. 8 15. 8 15: 7 15: 7 15. 7 15. 8 15. 7 15. 8 15. 8 (ng/m g

1.0 0

1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 ^:6 o i.bb ' i.0 6 i.d o 1.0 0 6.9S 3 a9S 3 0.99 3 6.9s a 0 ^ 0.99 3 0.99 3 0.99 3 asali"^..

. ..- . - - 1.0 0 1.0 0 1.0 0 1.0 0 0.99 3 0.99 3 0.99 3 0.99 4 0.99 4 0.99 4 0.99 3 0.99 3 0.99 3 Too ' 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 0 1.0 6 1.0 0 "i.o o 1.0 0 1.0 0 1.0 0 1.0 0 i.D O 1.0 0 1.0 0 i.d o 1.0 0 i.o o r:66"~'" ' ' • 1.0 0 1.0 0 1.0 0 i.b o 1.00' " 1.0 0 1.0 0 Us e Recon I



# , CaicuUte d

Concentrallo n (ng/mL ) 0.0091 9

< 0 il.O O 11.0 1 iO.99 3 1.0 1 0.00096 9 ~'~< o " R 

# » R l 

## m 

# ^ ^ ^ ^ ^ ^ iXI 

# ^ m R i 

# ^ ^ ^

M R i K l R l R l R l R l

H R l R t 1 ^ R J R l R R I 

# ^ __ia_

.

P 3



## a , 0.0266 0.030 5 0.042 2 0.053 2 0.0966 0.25 1 0.44 4 0.99 8 Z5 0 A.6 5 9.6 6 1S. 7 24. 9 50. 5 75. 0 99. 5 00012 2 0.0019 7 00035 9 0.21 0 0.21 1 0.22 1 Z0 3 1.9 7 Z0 2 19. 1 19. 3 19. 3

< 0

< 0 4.5 3

< 0 0.20 6 0.21 5 0.21 7 1.9 9 Z0 1 Z1 4 20. 2 21. 7 22. 7 "•< b 0.0037 9 Z4 9

< 0

< 0

< 0

< 0 0.24 9 0.96 1 20. 3

< o - 1 0.31 7 " ^ 0.46 8

asr a 1.3 7

< 0

< 0 1.0 1 <' o 0,068 2 0.061 4 Z1 0 20. 6

< 0

< 0 20. 2 21: 7 "• " ' ~ - 44. 3

< 0 

### *—-N^roTn' ^

W A0 WA ' TB N/ A1 • W Ai 0 N/ A; 0 N/ A1 • N/ At E ' ^ N/ A• 106

. 1 • 1Q Z < 0 1t»

. E 106

- I E 96. 6 E 101

. 8a 7 99. 8 100

. 93. 0 96 6 i"o5 : 99. 6 101

. 100

. 99: 5 W A W A W An i'oe ; 106. " 111

. lO Z 98. 7 102. 96 0

96. 8 N/ A N/ A 90. 5 N/ A 104

. 108

. D



## m Q D 

## i^



# .. . 

# ^

_ _ n m E l 

### ^ S

M E l



## n D

. E l

, E l D 

## m m D S lE J 109

. H

107

. 1 0 10 Z 109

. 114

. W A W A 99. 6 W A W A W A W A W A W A" W A" W A W A W A W A N/A " N/ A N/ A 101

. W A W A W A W A W A W A W A W A W A W A W A B

IS ] ^ ^

Acquldtlo n Dat e

0.026 7 17/28/201 1 1000:0 5 A M 0.010 9 !7/2a«01110;21:10A M 1.1 1 j7/28ra)11ia4Z14A M 1.1 2 |7/28/201 1 ll:03:24/V M 1.1 0 j7/28raM l 11:24:29A M 1.1 2 :7/28«01 1 11:45:32A M "0.017 7 b:6i43 ~ 0045 7 7/280D 1 H Z 06:3 6 P M

7/2SO0111227:4 3 P M 7/28001 1 1248:4 8 P M 0.049 9 17/28/201 1 1:09:59P M b:b627";7fi!8i20lTi:3f:06>M " 0074 7 7/2800 1 l"l:5 Z 1 1 P M 012 2 j7/2ara011213:1 5 P M 0.29 1 ;7/2ara011234:1 9 P M O50 1 i7/28OT1 1 255:2 4 P M 1.1 0 [7/2an0113;16:32P M Z7 3 :7/28«01 1 3:37:3 7 P M 5.0 3 i7/2a«01 1 3:58:4 2 P M 10 3 T6:4~~ ' 7/28O0114 ; 19:4 8 P M

7/28O0fl"4^:5 5 PM ~ iiS.' 3 7/28Q0li5:bi:59P M 47. 4 64. 7 78. 3 OTbiBO" " acii'BB" ' '0.0206 " "O-iMi B 0.24 8 6:259~ ~ Z24 ' Z17 " f z a 7/28001 1 5:23:0 3 P M

7/28O011 5:44:1 0 P M 7/28001 1 605:1 5 P M 7/2BO0lT6:26"i"9Pfc ^ 7/28O0116:47:2 4 P M 70800 1 l'7:0e:28"'P M 7OBO01 1 7:29:3 2 P M 7/28Obl"f7:SO.40P"M " 7wnsnV& : 1 i:4 7 P M " 7/28001 1 8:325 4 P M 7I2B^20^

^ 8:54*0 0 PM " 7/2BO01 1 9:15:0 7 P M 19. 9 i7/28raH 1 9:36:1 4 P M 20. 1 • '2b. i •• " 7/28001 1 9:57:2 3 P M 7/280D1 1 10.18:2 8 P M 0.014 8 ;7/28ra)1 1 1039:3 2 P M 0.01 « !7/28rabl 1 11:00:4 0 PM " 4.9 0 |7/28raM l 11:21:4 7 P M 0.0136 i7/2ara01 1 11:425 6 P M 0.24 3 ;7/2fi!01 1 1204:0 8 A M 0.25 3 7/29/201 1 1225:16A M a 2 K|7/29ra01 1 1246:2 6 A M Z1 9 t7/29ra01 1 1:07:32A M Z22 " 7/29«bi l 1:28:37/W ' Z3 5 i7/29«)1 1 1:49:4 3 A M 21. 0 |7/29Q011210:50A M 2Z 5 ,7/29001 1 Z31:5SA M

^ E ^23. 3 i7/29OT11Z53;01A M

•;b.bi6 6 ,7/2900113:14:lbA M 

# ^ Q 

## m a ^ H H 

## n D B l 1 

# ^ m e ^ E l i^E I E l E l 

### i^i a E l 

### 1 ^ rH D L - H E l E l 

# ^ fa E l 0.020 8 17/29O0113:35:2 3 A M Z7 2 7/29001 1 3:56:2 7 A M 0.014 6 "0.0127" ' 7/29O011 4:17:3 6 A M

7/29O0114:38:4 4 A M 0.015 2 j7/29i20114:59:4 9 A M 0.013 6 17/29001 1 5:20:5 8 A M 0.28 8 j7/29O0115:4Z04A M 

# ^

- 7/29^)1 1 6:03:11A M

7/29/201 1 624:2 1 A M 0.016 3 ;7/2af2bl i 6:45:29A M 0.36 3 0.52 7 '064 6 1.5 1 0013 6 0.013 3 1.1 2 0012 6 0091 1 0.08 ^ Z2 9 7/29O0117:06:35/k M

7/2af20117:27:43/k M 7/SObl'i7:48:55'A M 7/29001 1 8:10762/yi- i 7/290bli8:3i:i2'A M 7/29O01 1 8:522 3 A M 7/29/201 1 9:13:2 9 A M 7/290bii"9:'34':38'A"M" " 7/2900119:55:4 5 A M 7/29O01 1 1tt16:5SA M 7/29/201 1 1038:XA M 21. 3 1709001 1 1tt5906A M b.b i i s 'jtTarx n i i i :'2o : i e A M 0.012 8 "20. 8 2Z 3 42. 3 0.013 6 7/29O011 11:41:2 7 A M

7/29O01 1 12023 6 P M 7/29/201 1 1223:4 4 P M 7/SObii'1244:5 0 P M 709001 1 1:05:5 7 P Mo n : ETSKIR K

; Sampt e Nan M i Sampl e I D Sampl e Commen t

Metho d Blart c 1 0 r^m LF C st d i n Syrlh

. V Analyt e Pea k Analyt e PeakAre a J^nalyt e Retentio n

Unknow n bi^ yCortro l PFO A

PFbA " Analyt e Concentratio n I S Retentio n Tim e|mln ) I S Concentratio n

(ng/mL ) Us e Calculate d

Recor d | Concentratio n (ng/ml 4 ' AcquidUo n Dat e

13CePF0A-t S i:^8PFbA4S " T3C8PFbA4S

~ S60416 " 0.0136 1709001 1 1:27:0 6 P M "ToTe " l7raooiTiy48ii6yM " '0.009«l7O9O01 1 209:2 6 PM" "