Chemical Loading Chemical Loading PPMDoc owner: JLuman

Doc author: JLuman Version: 0.01 Effective: 2009-07-15

Review by: yyyy-mm-dd

Approvals: DRAFT

Safety Manager: _______________________

District Manager:_______________________

Talsico® Process Picture MapsTM & all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, & subject to licensing Agreement Page 1 of 3 

Sub-Process Bar 1 2 3 4 5 6 7 

Reminders Overview Instructions & Explanations 

Std Site Clothing 

and PPE Required

 Warning 

1 



Special note 

1 Picture in 

following tables 

 Additional 

person(s) required

 See tools & 

materials list

 Related COGs, 

documents, etc. 

 Paperwork 

(Permits, JSA)

 Lock, Tag, 

and Try

 Breathing 

Apparatus

 Dust Mask

 Face Shield

 Safety 

Harness

1 Prepare

2 Loading 

1.1 Engineer provides a job procedure with the 

required chemicals. 1

1.2 This information is reviewed by the facility 

manager to fill out the load sheet2

1.3 Facility manager informs loaders of job 

responsibilities with a J.S.A 4

1.4 Loaders prepare a load sheet.13 2 

2.1 Daily inspection performed on the forklift

2.2 Chemicals are loaded on to the truck.2

2.3 Fluid tech verifies chemicals and quantities

recorded are correct in the load sheet before 

leaving the yard. 1 

2.4 Fluid tech will fill out chemical inventory report 

and turn in the yellow copy to dispatch before 

leaving the yard.3 5

2.5 

 

2.6 Driver secures the chemicals with straps and 

transports them to the location with the 

appropriate DOT shipping papers and MSDS 

sheets. 6

Dispatcher will complete shipping papers for 

driver

2.7 Chem add operator is responsible for the safe 

transportation of the chemicals. 7

2.8 Fluid tech will drive behind the Chemadd.4 3 

4 

5 

1 Prepare a load sheet

2 Load the truck

3 Prepare chemical inventory 

report
Chemical Loading Chemical Loading PPMTalsico® Process Picture MapsTM & all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, & subject to licensing Agreement Page 2 of 3 

 Hazards (JSA)

The hazards are any exposure to hazardous chemicals based 

upon absorption, Ingestion or Inhalation.

We have the responsibility of preventing environmental 

contamination.

 Pre-Checks (before starting this procedure)

 The appropriate P.P.E (determined by MSDS) are available

 Forklift Inspected and approved for service

 Visual Inspection of all chemical containers for damage and use of 

caps and lids on all containers

 Hazard labels on all hazardous materials in good and readable 

condition and current

 Employee must inspect all tools and equipment used in the process.

 Tools & Materials

Quantity & Description Step

 Forklift & Pallets, 3 inch Straps, Poly and Steel Totes 2.3

 Non sparking rubber Pails, Hoses, Adaptor and 

Valves to transfer chemicals

 Gauge Sticks, Tape Measures, Small Hammers (non 

sparking rubber mallets or brass hammers)

 Drum and Totes, Wrenches for the caps and Lips.

 Chemical Totes.

<Step#> 

People (Who is required or needs to be notified)

 Engineer to write the procedure.

 Facility Manager to review the chemicals and designate the loading 

responsibilities.

 Chemical Loading loads the chemicals on the trucks

 Dispatcher to complete shipping papers

 Driver transports the chemicals to the work site. 

 Fluid tech verifies all information and dispenses the chemicals.

 Quality Checks

 The employees are educated on the chemicals and their particular 

hazards.

 A MSDS notebook readily available

 All personnel involved in this procedure must have completed 

training by a competent person prior to performing task

 Information Details Step

1 The actual procedure list with all chemicals and amounts

. 1.1

2 Chemical order form that compares the required quantity of 

each chemical to the current inventory. 1.2

3 Load sheet that determine the chemicals and their 

quantities for each Job 2.1

4 • MSDS 

• Proper PPE 

• Forklift safety 

• Emergency procedures 

5 Chemical Inventory Report is used to describe what 

chemicals and chemical levels leave the yard and come 

back to the yard 2.6

6

Shipping Paper for the transportation obtained from 

dispatcher 3.1

7

MSDS for each chemical 3.2

1 Check and verify all chemical levels

2 Measure chemical levels
Chemical Loading Chemical Loading PPMTalsico® Process Picture MapsTM & all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, & subject to licensing Agreement Page 3 of 3 

Talsico® Process Picture MapsTM and all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, and subject to licensing 

agreement. Duplication or use of this methodology or format is prohibited without the written permission of Talsico. www.talsico.com
Safety Data Sheet

LPA Pmteethe lathing DOT

Section Product Identification and Uses

Corn mouflrade name ProSURF cut Not applicable

Synonyms Not available rsct TS 8b vi vent ry Al

components are listed

Chemkid name Not applicable

Chemical formula Not applicable

CAS Mixture

4a.UN ian PGH

Chemical farntly Allpttatlc alcohol Solvent

Supplier

.1oIccular weight Not applicable

nan Manufacturer Chemplex L.C

rnnalS7aes P.O Box 1071

Material uses Not available 506 CR 137

Snyder Tx 79550

915 573-7298

Section IA FirstAid Measures

Eye contact Check for and remove any contact lenses Immediately flush eyes with running water for at least 15

mInutes keeping eyelids open Cold water may be used Do not use an eye ointment Seek medical

attention

Skin contact After contact with skin wash immediately with plenty of water Gently and thoroughly wash the

contaminated skin with running water and non-abrasive soap Be particularly careful to clean folds

crevices creases and groin Cold water may be used Cover the irritated skin with an emollient If

irntatlon persists seek medical attention Wash contaminated clothing before reusing

Hazardous skin Wash with disinfectant soap and cover the contaminated skin with an anti-bacterial cream Seek

contact medical attention

Slight inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention

hazardous Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie belt or

Inhalation waistband It breathing is difficult administer oxygen If the victim is not breathing perform

mouth-to-mouth resuscitation Seek medical attention

Slight ingestion Do not induce vomiting Loosen tight dothing such as collar tie belt or waistband If the victim is not

breathing perform mouth-to-mouth resuscitation Seek immediate medical attention

Ila.ardous ingestion Not available

KEY-HEC-1-000976 KEY-EPA-000968

KEY-H EC-1 -001300
ane Veigbt TLV/PEL LCM/LDo

Isopropyl alcohol 67-630 85-95 Not available ORAL LD5O Acute

3600 mg/kg

VAPOR LC5O Acute

16970 ppm hours Rat.J

Section III Physical Data

Phydcal state and Liquid Odor Rubbing alcohol

appearance

II 1% olnIwater Near Neutral Taste Not available

Odor threshold Not avaUable Color Pale yellow

VoIatilit% Not available

Melting point May start to solidify at -89.5C -129.1F based on data for Isopropyl alcohol

Roiling jnint 84C 184F

Specific gravity 0.80 VVater

Vapor density The highest known value is 2.08 Air Isopropyl alcohol

Vapor pressure The highest known value is 33 mm of Hg 20C Isopropyl alcohol

Evaporation rate Not available

Viscosity Not available

LugK. The product is more soluble in water

onicjl% jurracc acIi%I Nonionic

Critical ternperIture Not available

Instability temperature Not available

onditious of instability Not available

lispersion properties See solubility in water methanol diethyl ether n-octanol

Soluhility Easily soluble in cold water hot water methanol diethyl ether

Partially soluble in n-octanol

KEY-HEC-1-000977 KEY-EPA-000969

KEY-H EC-1 -001301
ge 3/5

The product is Flammable

Aisto-iinition cniperattire The lowest known value is 398.89CC 750F Isopropyl alcohol

Fire degradation These products are carbon oxides CO C02

products

Flash points CLOSED CUP 12.C 54F

Flammable limits The greatest known ratge is LOWER 2% UPPER 12% Isopropyl alcohol

Fire elinguishing Flammable liquid soluble or dispersed in water

procedures SMALL FIRE Use DRY chemical powder

LARGE FIRE Use alcohol foam water spray or fog

Flaznntatiiiilv Highly flammable in presence of open flames and sparks of heat of oxidizing materials

Flammable in presence of combustible materials

Remark

Vapor may travel considerable distance to source of ignition and flash back When heated to

decomposition it emits acrid smoke and fumes lscpropyl alcohol

Risks of explosion Risks of explosion of the product in presence of mechanical impact Not available

Risks of explosion of the product in presence of static discharge Not available

Remark

Not available

Section Reactivity Data

Stability The product is stable

Iiirdnm kornp Not available

prmidurt

legratlahility Not available

lrodmicts Possibly hazardous short term degradation products are not lely However long term degradation products may arise

degradation The product itself and its products of degradation are not toxic

Remark

Not available

orrosiYity Non-corrosive in presence of glass

Reniaik

Not available

liil Reactive with oxidizing agents acids

Slightly reactive to reactive with moisture

Remark

Incompatible with halogens and aluminium lsopropyl alcohol

KEY-HEC-1-000978 KEY-EPA-000970

KEY-H EC-1 -001302
Section VI Toxicological Properties -II page9

Routes of entry Dermal contact Eye contact Inhalation Ingestion

uN Not available

iokity for atiunab WARNING THE LC5O VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF 4-HOUR

EXPOSURE

Acute oral toxicity 1D50 3600 mg/kg Isopropyl alcohol

Acute toxicity of the vapor LC5O 16970 ppm hours Isopropyl alcohol

Remark

Not available

Clirtnic efltcts on DEVELOPMENTAL TOXICITY PROVEN alcohol

humans The substance is toxic to the reproductive system

Remark

0900 Detected in maternal milk in humain

lsopropyl alcohol

Mute effcct on Very hazardous in case of ingestion

humans Hazardous in case of skin contact irritant sensitizer permeator of inhalation

Remark

Exposure can cause nausea headache and vomiting Isopropyl alcohol

Section Vii Preventive Measures

Waste disposal Whatever cannot be saved for recovery or recycling should be managed in an approriate and approved

waste disposal facility Processing use or contamination of this product may change the waste

management options State and local disposal regulations may differ from federal disposal regulations

Dispose of container and unused contents in accordance with federal state and local requirements

Not available

Storage Flammable materials should be stored in separate safety storage cabinet or room Keep away from

heat Keep away from sources of ignition Keep container tightly closed Keep in cool well-ventilated

place Ground all equipment containing material refrigerated room would be preferable for materials

with flash point lower than 37.8C 100F

Piccatitions Keep away from heat Keep away from sources of ignition Ground all equipment containing material

Do not ingest Do riot breathe gas/fumes vapour/spray Wear suitable protective clothing In case of

insufficient ventilation wear suitable respiratory equipment If ingested seek medical advice immediately

and show the container or the label Avoid contact with skin and eyes Keep away from incompatibles

such as oxidizing agents acids

Small spill and leak Dilute with water and mop up or absorb with an inert dry material and place in an appropriate waste

disposal container

Large spill and leak Flammable liquid

Keep away from heat Keep away from sources of ignition Stop leak if without risk Absorb with DRY

earth sand or other non-combustible material Do not touch spilled material Prevent entry into sewers

basements or confined areas dike if needed Eliminate all ignition sources

Itoltclit Clothing Splash goggles Full suit Vapor respirator Boots Gloves self contained breathmg apparatus should be usedt

avoid inhalation of the product Suggested protective clothing might not be sufficient Consult specialist BEFORE

handling this product

KEY-HEC-1-000979 KEY-EPA-000971

KEY-H EC-1 -001303
Section IX Protective Clothing

Splash goggles Lab coat Vapor respirator Be sure to use an approved/certified respiratoror equivalent

Gloves

Section Other In formation

Reterences Not available

Validated by ChempleN on 10/3112001 Verifled by Cheinpiex

Printed l/2/20tb0

Emergency Response 800 633-8253

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IProSURF-Il page5/

Section_VIII._Classification

DOT Class Flammable liquid

Shipping name Flammable liquids n.c.s Isopropyl alcohol UNNA UN1993 PG II

ReiuaI1

Not available

Maritime Not available

transportation

Remark

Not available

IICS Class Flammable liquid having flash point lower than 37.8C 100F Class Sensitizing substance

Class Target organ effects

Remark

Not available

FPA F1.AIdIMABILflV

HEALTH

_SPCFIC HAZARD

Federal and

State

Regulations

KEY-HEC-1-000980 KEY-EPA-000972

KEY-H EC-1 -001304
J5uF_Safety Data Sheet

NPA

DOT

Section Product Identification and Uses Common/Trnijc annie PrOSURF-I

apiicale

Sauonvrns Notavailable iSCA T$CA 8b inventoryAU

.heinu.a1 name Not components are listed

applicable

Cbemwat furniula Not applicable cs Mixture

s3 PG hemical fnni.Jv Aromatic hydrocarbon Solvent Dl

Supplier loIecular weight Not applicable

7DlO 4MaflUr3Ctuier Chemplex LC

P0 Box 1071 IatnJ Oil-Soluble Surfactarit

506 CR 137

Snyder Tx 79550

915 573-7298

Section IA FirstAid Measures

Eye contact Check for and remove any contact lenses Immediately flush eyes with running water for at least 15 minutes keeping eyelids open Cold water may be used Do not use an eye ointment Seek medical attention

Skin contact After contact with skin wash immediately with plenty of water Gently and thoroughly wash the

contaminated skin with running water and non-abrasive soap Be panicularly careful to clean folds crevices creases and groin Cover the irritated skin with an emollient It irritation persists seek medical

attention Wash contaminated clothing before reusing

Hazardous skin Wash with disinfectant soap and cover the contaminated skin with an anti-bacterial cream Seek contact medical attention

Slight inhalation Allow the victim to rest in well ventilated area Seek Immediate medical attention

hazardous Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie bolt or inhalation waistband If breathing is difficult administer oxygen If the victim is not breathing perform mouth-to-mouth resuscitation Seek medical attention

Slight Ingestion Do not induce vomiting Loosen tight clothing such as collar tie belt or waistband If the victim is not

breathing perform mouth-to-mouth resuscitation Seek immediate medical attention

hazardous ingestion Not available

KEY-HEC-1-000981 KEY-EPA-000973

KEY-H EC-1 -001295
Section II Hazardous Ingredients JPrOSLIRFI page 2/5

same s.j Whi TIN/PEL LCFJLD

Petroleum distdate 6742975 5-15 TWA CElL mg/rn3 ORAL LD5O Acute

1530 mg/kg Rae

DERMAL 1050 Acute

2740 mg/kg tRabbit

Toluerie 108-88-3 70-90% TWA 100 ppm ORAL 1050 Acute

2600 mg/kg

DERMAL 1D50 Acute

12210 mg/kg

VAPOR LCSO Acute

8000 ppm hours

Amidoamine mixture 5-15% Not Available Not available

Section liiPhysical Data

Physical state and Liquid

appearance

p11 1%sot n/water 57 Taste Not available

Odor threshold The highest known value is 0.6 ppm Trimeffiylbenzene COlor Clear Brown

Volatility Not ava1abIe

Melting point -20F

Boiling point The lowest known value is 110.6C 231.1 Toluerie

Speciticgrtwity 88 Water

Vapor density The highest known value is 4.14 Air Trimethylbenzene Weighted average 3.34 LAir

Vapor pressure The highest known value is 21.9mm of Hg 20C Toluene

Evaporation rate Not available

Viscosity Not available

IdogK. The product is more soluble in oil

loicitv urracc aeth agent Not available

Critical temperature Not available

Instability temperature Not available

nntIitions of iIIstalilits Not available

lispcrsiun ProPerties See solubdity in water methanol diethyl ether n-oclanol

Soluliitity Easily soluble in methanol diethyl ether

Soluble in n-octanol

Very slightly soluble in cold water hot water

KEY-HEC-1-000982 KEY-EPA-000974

KEY-H EC-1 -001296
Section IV Fire and Explosion Data 1PrOURI.I Pae3I9

The poduct Is Flammable

nIo-ignition mpcrature The lowest known value is 480C 896F Toluene

Fire degradation These products are carbon oxides CO C02 products

Flash points Closed cup 43SF

Flammable limits The greatest known range is LOWER 1.2% UPPER 7.1% Toluene

Fire ethnguistiing Flammable liquid soluble or dispersed in water

procedures SMALL FIRE Use DRY chemical powder

LARGE FIRE Use alcohol foam water spray or fog

FtainmaliIit Flammable in presence of open flames and sparks

Slightly flammable to flammable in presence of heat of oxidizing materials of combustible materials

Non-flammable in presence of moisture

Remark

Vapor may travel considerable distance to source of ignition and flash back Toluene

Risks of esJIos ion Risks of explosion of the product in presence of mechanical impact Not available

Risks of explosion of the product in presence of static discharge Not available

Remark

Not available

Section Reactivity Data

Stability The product is stable

JIazr4uus deromp NOt available

products

Hegradability Not available

Prmlucts POssd3ly hazardous short term degradation products are not hkely However tong temi degradation products may arise

degradation The product itself and its products of degradation are not toxic

Remark

Not available

orrosivity Non-corrosive in presence of glass

Remark

Not available

Reactivity Reactive with oxidizing agents

Slightly reactive to reactive with reducing agents acids alkalis

Non-reactive with moisture

Remark

Not available

KEY-HEC-1-000983 KEY-EPA-000975

KEY-H EC-1 -001297
Routes of eniry Dermal contact Eye contact Inhalation Ingestion

ILV

iicity for anirnjls WARNING THE LCSO VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF 4HOUR EXPOSURE

Acute oral toxicity LD5O 2600 mg/kg Rat. Toluene

Acute demiat toxicity LD5O 12210 mg/kg IRabbit. Toluene

Acute toxicity of the vapor LC5O 8000 ppm4 hours Toluene

Iteniark

lJot available

lironic effects on The substance is toxic to blood kidneys the nervous system liver

hunuuis

Remark

Inhalation of vapors may cause dizziness an irregular heartbeat narcosis nausea or asphyxiation Toluene

Acute effects on Hazardous in case of skin contact irritant permeator of ingestion of inhalation

itunians

Reris rk

Exposure can cause lung irritation chest pain and oedema which may be fatal Toluene

Section VII Preventive Measures

Waste disposal Whatever cannot be saved for recovery or recycling should be managed in an approriate and approved

waste disposal facility Processing use or contamination of this product may change the waste

management options State and local disposal regulations may differ from federal disposal regulations

Dispose of container and unused contents in accordance with federal state and local requirements

Not available

Storage Flammable materials should be stored in separate safety storage cabinet or room Keep away from

heat Keep away from sources of ignition Keep container tightly closed Keep in cool well-ventilated

place Ground alt equipment containing material refrigerated room would be preferable for materials

with flash point lower than 37.8C 100F

Precautions Keep away from heat Keep away from sources of ignition Ground all equipment containing material

Do not ingest Do not breathe gas/fumes vapour/spray Wear suitable protective clothing In case of

insufficient ventilation wear suitable respiratory equipment If ingested seek medical advice immediately

and show the container or the label Avoid contact with skin and eyes Keep away from incompatibles

such as oxidizing agents organic materials

Siiall spill and leak Absorb with an inert material and put the spilled material in an appropriate waste disposal

1.arge spill and leak Flammable liquid

Keep away from heat Keep away from sources of ignition Stop leak if without risk Absorb with DRY

earth sand or other non-combustible material Do not touch spilled material Prevent entry into sewers

basements or confined areas dike if needed Eliminate all ignition sources Be careful that the product

is not present at concentration level above TLV Check TLV on the MSDS and with local authorities

Protect ie lathing Splash goggles Full suit Vapor respirator Boots Gloves self contained breathing apparatus should be used tc

avoid inhalation of the product Suggested protective clothing might not be sufficient consult specialist BEFORE

handing this product

KEY-HEC-1-000984 KEY-EPA-000976

KEY-H EC-1 -001298
Section Viii Classification ProSLJ lW-I

page_5/9

DOT

Maritime

ra.isportntion

Class Flammable liquid

Shipping name Flammable liquids n.o.s contains Toluene UNHA UN1993 PG II

Remark

Not available

Not available

Remark

Not available

HCS Class Flammable liquid having flash point lower than 37.8C 100F Class Target organ effects

Remark

Not available

\fp FLAMMABILITY

HEALTH ACTIVELY

SPECIFIC HAZARD

Federal .Ifll RQ 14lgallons toluene State

Regulations

Section IX Protective Clothing

Splash goggles Lab coat Vapor respirator Be sure to use an approved/certified respirator or equivalent

Section

GlovesM_

Other Information

Relerenees Not available

Emergency Response 915 570-4899

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Validated by Chemple on 11/6/2000 Verified by Chemples

Printed 11/6/2000

KEY-HEC-1-000985 KEY-EPA-000977

KEY-H EC-1 -001299
MATERIALSAFETYDATA SHEET

SECTION 1- PRODUCT mENTIUER

Product S-4 NFPA Raiir

Energy Cbemicals II Ltd Health

2709 Industrial Ave Fire

Midland Texas 79701 React

915 686-7847 Special

0Leasc to Extreme

HMIS PERSONAL PROT

SECTION -JLAZ.4RDOUS INGREDIENTS

Hazardous Components-CAS Number Exposure Limits

Not hazardous as defined in 29CFR1910.1200

SECTION 3- PJJYSICALCHEMICAL CHARACTERISTICS

Boiling Point Approx 215 Melting Point NA

Specific Gravity H201 1.005- 1.0 10 Vapor Pressure NA

Vapor Density Airl NA Evaporation Rate BuAccl NA

Density 1gal NA pH 6.5 8.0

Solubility in Water Soluble

Appearance and Odor Tan/brown sobition bland odor

Freeze Point NA Dry Point NA

Danger

Physical Hazards NA

Generic Name NA

UNINA Number NA

North American Emergency Response Guide Number NA

DOT Proper Shipping Name NA

DOT Hazard Class NA

DOT Packing Group NA

DOT/CERCLA RQ NA

SECTION 4- FIRE AND EXPLOSION HAZARD DATA

Flash Point method None

Flammable Limits Lower Upper

Extinguishing Media Dry powder carbon dioxide co2 water fog or spray alcohol foam

SPECIAL FIRE FIGHTiNG PROCEDURES Approach fire from upwind side Avoid breathing

smoke fumes mist vapors on tho downside wind Firefighters wear protective clothing and self

contained breathing apparatus

UNUSUAL FIRE AND EXPLOSION HAZARDS

KEY-HEC-1-000986 KEY-EPA-000978

KEY-H EC-1 -001331
Firefighters protective clothing and self contained breathing apparatus

T1ON -REACTIViTY INFORMATION

Product is stable

hompaty

None

Materials to avoid

Oxidizers

Hazardous Deconçosition or By-products

From combustion smoke carbon monoxide carbon dioxide

Hazardous Polymerization

Not expected to occur

SECHON HEALTH HAZARD DATA

ROUTES OF ENTRY

Inhalation

Possible-irritant

Eye Contact Priury Route

Eye irritation

Skin absorption

No data

Skin Irritation Primary Route

May cause irritation

Ingestion

Possible-irritant

HEALTH HAZARDS Acute and chronic

Acute Health Effects Short Term

Mild eye irritant at point of contact

Mild skin irritant at point of contact

Chronic Health Eflbcts None Established

CARCINOGENICITY LISTED IN NTP NO IARX MONOGRAPHS NO

OSHA REGULATED NO

SIGNS AND SYMPTOMS OF EXPOSURE Skin irritation develops slowly after contact Eye irritation

Develops immediate

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

Pre-existing skin disorders

KEY-HEC-1-000987 KEY-EPA-000979

KEY-H EC-1 -001332
S-4

EMERGENCY AND FIRST AID PROCEDURES

1nh.Ltn

Renve victim to fresh air and If needed immediately begin artificial respiration Give oxygen if

breathing Is labored Get emergency medical help Contact physician inanediately

Eye Contact

Flush eyes with water 15 minutes Jet medical attention if symptoms develop and persist

Skin Contact

Immediately remove contamhted clothing Wash skin thoroughly with mild soap and water

Flush with hike warm water for 15 minutes or until all traces are have been removed Seek medical

attention ifsymptoms develop and persist

Ingestion

Include vomiting if victim is conscious by giving water then stick fingers down throat Never give

unconscious person anything by mouth

OTHER HEALTH WARNINGS NA

SECTION 7- PRECAUTIONS FOR SAFE HANDLING AND USE

SPILL OR LEAK PROCEDURES

Emergency response coordinator must have nntlated training Elimintiig an ignition sources

SMALL SPILLS Pick up with absorbent materials and place in non-leaking containers seal tightly

for proper disposal or reuse LARGE SPILLS Evacuate the hazard area of unprotected personnel

Wear appropriate respirator and protective clothing Shut off source of leak if sale to do so Dike and

contain Remove with vacuum trucks or pump storage/salvage vessels

WASTE DISPOSAL METHOD NA

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE No Special

OTHER PRECAUTIONS

Clean up leaks/spills immediately to prevent soil or water contamination

SECTION 8- CONTROL MEASURES

Ventilation Local Exhaust Recommended Special Not necessary

Mechanical Reconineixied Other Not necessary

Respiratory Protection

Not Normally needed

Protective Gloves Chemical Type

Eye Protection

Eye protection including both chemical splash goggles and face shield

Skin Protection

Boots apron drench shower eye wash as needed for protection against spills and/or splashes

Other Hygienic Practices

Avoid contact with skin eyes and clothing After handling this product wash bands before

KEY-HEC-1-000988 KEY-EPA-000980

KEY-H EC-1 -001333
S-4

eafin driniig or smoking if contact occurs remove contsinihted clothing eded take frst aid

action shown in section Launder contanirted clothing before reuse

Other Work Practices

Emergency eye wash fbuntn and safety showers should be available in the immediate vicinity of

any potential expoane Promptly remove soiled clothing and wash thoroughly before reuse

SECTION 9- ThANSPRTA11ON INFORMATiON

NOT REGULATED

SECTION ie- REGULATORYENVIRONMENTAL

EPA HAZARDS ACUTE- Yes CHRONIC-NO FLAMMABILITY-NO

SUDDEN RELEASE OF PRESSURE-No REACTIVE-No

SARA Title

Section 313 Toxic Materials

Chemical Name CAS Percentage

CLEAN AIR ACT No CLEAN WATER ACT No

STATES LISTS None

TOXIC SUBSTANCES CONTROL ACT FSCA 40 CFR 710 Sources ofthe raw materials used in

this mixture assure that all chemical ingredients present are in compliance with Sect 8b Chemical

Substance Inventory or are otherwise in compliance with TSCA

FOOTNOTES

NA-Not applicable ND-Data not available

CS- Cancer Suspect Agent OX-Oxidizer

Cor-Corrosive CALC-Calculated

EST-Estimated STEL-Short Time Exposure Limit

TLV-Threshold Limit Value PEL-Permissible Exposure Limit

TWA-Tune Weighted Average hours HNMIS PPI-Hazardous Material identification System

Personal Protection Index

The data presented is true and correct to the best of our knowledge and belicf however neither seller nor

prepare makes any warranties express or implied concerning the inlbnnation presented The user is

cautioned to perform his own hazard evaluation and to rely upon his own determinations

SCIENI1FIC INFORMATION SERVICES

Telephone 817 560-4613

Form essentially the same as OSHA

Form 174 data September 1985

Preparation date July 1991

KEY-HEC-1-000989 KEY-EPA-000981

KEY-H EC-1 -001334
eCUfl Cluthiug

7TU

Ml 5- Material Safety_Data

Sheet

DOT

Section Product identification and Uses

Coinmonfrade S-5 AES cl Not apphcIe

Synonyms Not avathla

TSCA products listed

Chemical name Not pliceble

.-.. .-

iicmical formula Not plmcable

Code ooI_

Chesmcal family Aliphetic ether Solvent

Supplier CtemPIeX

Molecular wet Not appOcable

P.O 8c4c 1071

sr Tx 79550 Manufacturer Chençlex LC

P.O BoxlO7l

Material uses

Not available Snyder TX 79550

915 573-1296

Section L4 FirstAid Measures

Eye contact Check for and remove any cormbct lenses IMMEDIATELY flush eyes with running water for at least 15 minutes keeping

eyelids open COW water may be used DO NOT use an eye o.rdment Seek medical attention

Side contact If the chemical got onto the clothed portion of the body remove the contaminated clothes as quicldy as possible

protecting your own hands and body Place the victim under deluge shower If the chemical touches the vicbms

exposed skin such as the hancte Gently and thoroughly wash the contaminated skin wilti rwmrmg water and non-abrasive

soap Be purticulmly cul to clean folds crevices creases and groin COW water may be used Cover the iiitated

skin with an emollient If irritonpersists seek medical attention Wash contaminated clothing before reusing

Hazardous skin contact Wash with disinfectant soap and cover the contaminated skin with an anti-bactmial cream Seek irrwnecliate medical

attention

Sliplt inhalation Allow the victim to rest in wall ventilated area Seek immediate medical attenitort

Hazardous imhalabon No additional information

Slimtiniteslion DO NOT induce vomiting Have conscious person drink several gasses of water or milk Seek immediate medical

attention

Hazardous ingestion DO NOT induce vomiting Exarmne the lips and mouth to ascertain whether the tissues are damaged possible

indication that the todc material was ingested the absence of such signs however is not cnckmive Loosen tight

clothing such as collar tie belt or waistand If the victim is not breathumg perform mouth-b-mouth resuscitation

Seek immediate medical attention

KEY-HEC-1-000990 KEY-EPA-000982

KEY-H EC-1 -001335
14amc CAS byWciit TLWPEL C5J11n

Ethyler glycol monobutyl ether 111-76-2 Wade secret Plot available ORAL 1050 mglkg Acute

470 Ret DERMALLD5O

mglkg Acute Rabbit

Section III Physical Data

Physical state Odor Sweet

appealmiCt

pH 1% solo/waler Neutal l5k Notavailable

Odor threshold Not available

C01W Colotless

Volatility

Not available

Melting point

liloling paint 220F

Spccific gravIty 1.03 Water

Vapor density The highest knn yalta is 4.1 Ar Ethylene glycol inonobutyl ether

Vapor pressiwe Not available

Evaporation late Not available

Vucosiy Not available

logIL The product is much more sok4ble water

lonicity snrlace ucttve agent Anionic

Critical temperature Plot available

Instability temperature Not available

Conditions of Instability No additional remark

Dispersion properties See sdubikty in water methanol dieth1 ether

Solubility Easily soluble in cold water hot water methanol

Partially soluble in cliethyl ether

Very slightly soluble in n-octenol

KEY-HEC-1-000991 KEY-EPA-000983

KEY-H EC-1 -001336
Section Fire and Expi ion Data page 3/5k

The product is Combustible

Auto-ignition temperature The lowest known value is 24445C 47F Ethylene glycci rnonobutyl ether

Fire dcgradatini products These products are carbon oxides CO C02

lilusis polilts 200F

Flammable links Th puatost known range is LOWER 1.1% UPPER 10.6% Ethylene glycol monobutl ether

Fire eEingnisbisg SMALL FIRE Use DRY chemicals C02 waler spray or foam

procedures LARGE FIRE Use water sqxsy fog or foam DO NOT use water jet

Fianunubfflty Slightiy flammable to flammable in presence of open flames and sparks of heat

Remark

When heated to decomposibon it emits acnd smoke and inite fijoas Ethylene glycol monobutyl ether

Riska otexpkjsion Risks of explosion of the product in presence of mechanical knpact Not available

Risks of explosion of th product in presence of static discharge Not available

No specific information is available in our database regarding the produces risks of explosion in the presence of various

materials

Remark

No additional remark

Section Reactivity Data

Stability The product is stable

Hazardous decooip products Not available

Degradabllity Not available

Products of dcgrada 1km Possibly hazardous short term dogradabon products are not hkely However long term degradation products may aria.

The products of degradation are less toxic than the product itself

Remark

No additional remark

Corrosivity Non-corrosive in presence of glass

Remark

No adddonal remark

Reacthity Slitiy reactive to reactive with oxidizing ogents

Remark

No adddonal remark

KEY-HEC-1-000992 KEY-EPA-000984

KEY-H EC-1 -001337
___________________ page 4/S

Section Vi Toxkglogical Properties

Routes of entry Eye contact Ingestion Skin contact Inhalation

LV Not available

Toxicity for au1sal Acute oral toxicity 1050 4700 mglkg Rat CaIcud value for the mixture

Acute dermat toxicity LD5O 2200 mglkg Ralft Calculated value for the mixture

Remark

No additiorul remark

iroic elTccts on Toxicity of the product to the reproductive system Not available

humans

Remark

No additional remark

Acute effects on humans Very daigercus in case of ingestion

Shghtty dangerous to dangerous in case of skin contact irritant peimeator of eye contact irritant of inhalation

Remark

Exposure can cause nausea headache and vomiting Ethylene glycol monobutyl ether

Section VII Preventive Measures

Waste disposal Whatever cannot be saved for recovery or recycling should be managed man approriats and approved waste disposal

facility Processing use or contamination of this product may change the waste management cions Stat aid local

disposal regulations may differ from federal disposal regulations Dispose of container and .mused contents in

accordance with federal state and local recpirernerds

Storage Keep container cky Keep in cool place Ground aN equçment containing material Keep container lightly dosed Keep

in cool wall-ventilated place Highly toxic or infectious materials stould be stored in separate lucked safety storage

cabinetor room

Precautions Keep locked up Keep away from heat Keep away from sources of ignition Empty containers pose fire nsk

evaporate the residue under fume hood Ground all equjiment containing material DO NOT ingest Do not breathe

gas fumes vapor or spray In case of insufficient ventilation weer suitable respiratory equjimant If ingested seek

medical advice immediately aid show the container or the label Avoid contact with sldn and eyes Keep away from

incompattles such as oxidizing agents

Small spill and leak Dilute with water and mop up or absorb with an lied DRY material end place in an appropriate waste disposal container

Finish cleaning by spreadeng water on the contaminated surface and dispose of according to local aid regional mihority

requrements

Large api11 and leak Combustible material Poisonous liquid

Keep away from heat Keep away from souitesof ignition Stop leak without risk DO NOT get water inside container

DO NOT touch spilled material Use water spray to reduce vapors Prevent entry into sewev hasements or confined

areas dike If need.d Elininate eli sources of ignition Call for assistance on disposal Fish cleaning by spreading

water on the contaminated surface and allow to evacuate through the sanitary system

Protective jotting Splash goggles Fuli sat Vapor respirator Bouts GirNeS self contained breathing apparatus should be used to avoid

inhalation of the product Suggested protective clothing migt not be sufliclent consult speciol BEFORE handling this

KEY-HEC-1-000993 KEY-EPA-000985

KEY-H EC-1 -001338
SOctlon WI Classification

DOT Not DOT Controlled material Lkiited States

Not applicable PIN and PG

Reaark

Not availalle

Mari$iinv

transportation

Remark

Not appcable

tICS HCS CLASS lnitabng sstace

HCS CLASS Contuslible Iiqtid havTng flash point between 378C 100F and 93.3C 200F

Reusark

No adcbtional renark

NFIA R.MMAaII.rry

01 CTMTY

ECARD

Federal and

State

ReguIatium

Section IX Protective Clothing

Splash goggles Lab coat Vapor respirator Be sure to use MSHAJNIOSH approved respirator or equivalent Gloves

impervious Wear approprIate reapa-ator when ventilation is inadequate

Section X. Other InfoAnatioæ

References Not avaiIle

Vabdated by Oieuspkx LC on 3/5/99 Verted esiplri LC

Printed 315/99

Emergency Response 915 570-4899

JL_L ffi. JJ..L .n..ftr dJJ__L .u itwon

KEY-HEC-1-000994 KEY-EPA-000986

KEY-H EC-1 -001339
Versaprop®

1. Chemical Name & Company Identification

PRODUCT NAME: Versaprop® (all mesh sizes)

SYNONYM(S): Ceramic Proppant

CHEMICAL FAMILY: Aluminosilicate

MANUFACTURER: Saint-Gobain Proppants

5300 Gerber Road

Fort Smith, Arkansas 72904

24-Hour Emergency (479) 782-2001

2. Component Information

CHEMICAL NAME COMMON NAME % BY WEIGHT (TYPICAL)

Aluminum Silicate Mullite 35-65

Aluminum Oxide Corundum 35-65 

3. Hazards Identification

3.1 Emergency Overview 

HMIS RATING

Health: 1. (Slight)

Flammability: 0. (Minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

INHALATION: Prolonged exposure to dusts may cause respiratory 

tract irritation.

INGESTION: No known adverse effects.

EYE CONTACT: May cause irritation on prolonged or repeated contact.

SKIN CONTACT: May cause irritation on prolonged or repeated contact.

4.0 First Aid Measures

INGESTION: Seek medical attention if large quantities are ingested.

INHALATION: Remove to fresh air.

EYE CONTACT: Immediately flush eyes with large quantities of

water. Call a physician if irritation persists.

5.0 Fire Fighting Measures

FLASH POINT: Nonflammable

LOWER EXPLOSION LIMIT: Not applicable

UPPER EXPLOSION LIMIT: Not applicable

AUTOIGNITION TEMPERATURE: Not applicable

Use extinguishing agent suitable 

for type of surrounding fire.

6.0 Accidental Release Measures

SPILLS: No special procedures are required for cleanup of spills or 

leaks. Spherical shape of spilled pellets can create a slip hazard.

7.0 Handling and Storage

Store under dry conditions. Handle with adequate ventilation.

Use a NIOSH/MSHA approved respirator if dust is present.

Material Safety Data Sheet

FOR INDUSTRIAL USE ONLY

KEY-HEC-1-000995 KEY-EPA-000987
8.0 Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creation of dust.

8.2 Personal Protection

Use NIOSH/MSHA approved respiratory protective

equipment when airborne concentrations exceed

acceptable criteria. Wear safety glasses at all times 

to prevent eye irritation.

8.3 Exposure Guidelines

INGREDIENT CAS# %/ OSHA ACGIH-TWA TLV

WT PEL/TWA

Corundum 1302-44-56 35-65 15mg/m3 (Total) 10mg/m3 (Total) 

5mg/m3 (Resp) 3mg/m3 (Resp)

Aluminum 

Silicate 1302-76-7 35-65 15mg/m3 (Total) 10mg/m3 (Total) 

5mg/m3 (Resp) 3mg/m3 (Resp)

9.0 Physical and Chemical Properties

APPEARANCE: Grayish brown to black

free-flowing granules

ODOR: None

FLASH POINT: N/A This material does

not give a flash point by 

conventional methods.

STABILITY: Stable

SPECIFIC GRAVITY: 3.05-3.20

PH: Not applicable

VAPOR PRESSURE @ 25 ̊C: Not applicable

VISCOSITY: Not applicable

SOLUBILITY IN WATER: Nonsoluble

BOILING POINT: Not applicable

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1)

11. Toxicological Information

SEE SECTION 3

LC50 Not available

LD50 Not available

12. Ecological Information

Not determined

13. Disposal Conditions

Dispose of according to local, state/provincial,

and federal requirements.

14. Transportation Information

14.1 U.S. Department of Transportation

Non-regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated

15. U.S Regulatory Information (Selected Regulations)

SARA TITLE III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA): N/A

CERCLA Reportable Quantity: None

Clean Air AmendmentsHazardous Air Pollutants: None

California State Proposition 65: N/A

16. Other Information

The OSHA Hazard Communication Standard 29CFR 1910.1200

requires that the information contained on these sheets be

made available to your workers. Instruct your workers to 

handle this product properly. Consult with appropriate

experts to guard against hazards associated with use of this

product and its ingredients.

Disclaimer

Seller makes no warranty, expressed or implied, concerning 

the product or the merchantability or fitness thereof for any

purpose, except that the product conforms to contracted 

specifications, and that the product does not infringe any

valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the

quantity of product in respect of which damages are claimed.

In no event shall seller be liable for incidental or consequential damages, whether buyer’s claim is based on contract,

breach of warranty, negligence or otherwise.

ISSUE DATE: 1-SEPTEMBER-06

Tel: 479.782.2001

Toll Free: 800.643.2149

Fax: 479.782.9984

www.proppants.saint-gobain.com

5300 Gerber Road

Fort Smith, AR 72904

KEY-HEC-1-000996 KEY-EPA-000988
Sand 100 mesh MSDS

Page of4

SHBENCHMARK3M

MATERIAL SAFETY DATA SHEET

Insignificant Slight Moderate High Extrame

Section General Information

Sand 100 mesh

NA

Benchmark Energy Products L.P

4113 West Industrial

Midland Texas 79703

432 697-8171

432 697-8171

800 349-8171

800 4249300

September 2004

November 1994

Benchmark Energy Products L.P

Section II Composition Information on Ingredients

Principle Hazardous Components CAS By Weight%

This product is non-hazardous in accordance with OSHAs Hazard Communication Statement

Section III Physical and Chemical Properties

Freezing Point NA

Boiling Point NA

Vapor Pressure NA

Solubility in Water Insoluble

Specific Gravity 11201 2.65

pH NA

Appearance and Odor Light brown granules odorless

HMIS Hazard Rating Health Fire Reactivity

Product Name

Product Description

Manufacturer

Address

For information on health hazards call

For product sales information call

24 Hour Emergency Information call

Chemtrec Emergency Number

Information effective date

Replaces

Preparer

KEY-HEC-1-000997 KEY-EPA-000989

KEY-H EC-1 -001371
Sand 100 mesh MSDS

Page of

Section IV Fire and Explosion Information

Flash Point and Method of

Determination NA

Upper Explosion Limit by Vol NA

Lower Explosion Limit by Vol NA

Auto-Ignition Temperature

Extinguishing Media This chemical is not combustible Use media suitable for the surrounding fires Dry

chemical C02 foam or water spray

Special Fire Fighting Procedures None known

Unusual Fire/Explosion Hazards None known

Section Health Effects Information

Primary Routes of Entry Inhalation

Effects of Overexposure Acute

EYE/SKIN CONTACT

SKn ABSORPTION

INHALATION Inhaling respirable silica may aggravate existing respiratory system diseases and/or dysfunctions

Exposure to dust may aggravate existing skin and/or eye condition

INGESTION

Chronic Chronic overexposure to respirable crystalline silica has caused silicosis progressive

pneumoconiosis Chronic tobacco smoking may further increase the risk of developing chronic lung problems

EMERGENCY AND FIRST AID PROCEDURES

EYES In case of contact immediately flush eyes with plenty of water for at least 15 minutes using an eyewash

fountain if available Lift upper and lower lids and rinse well under them Get medical attention preferably an

ophthalmologist if irritation occurs

SKIN Flush all affected areas with plenty of water for several minutes Remove and wash any contaminated

clothing and shoes Get medical attention if skin irritation occurs

INGEsTIoN If victim is conscious and alert give two or more glasses or milk or water to drink If available give

one tablespoon of Syrup of Ipecac to induce vomiting If vomiting has not occurred in 10 minutes the same

amount of Syrup of Ipecac may be repeated one additional time Alternatively induce vomiting by touching the

back of the throat with finger Do not induce vomiting on unconscious or convulsing person Contact

physician or call the Poison Control Center 800 441-0040

INHALATION Remove to fresh air If breathing has stopped administer artificial respiration oxygen or CPR if

needed Consult physician

Carcinogenicity IARC Monographs No NIP No OSHA No

EMERGENCY AND FIRST AID PROCEDURES

Crystalline silica the major component of this product is on the NTP and IARC carcinogen lists but not on the

OSHA carcinogen list IARC and NIP have determined that there is sufficient evidence for carcinogenicity to

experimental animals exposed to crystalline silica and limited evidence for carcinogenicity to humans Limited

evidence means that causal relationship is possible however other explanations such as chance bias or

confounding factors cannot be adequately excluded

KEY-HEC-1-000998 KEY-EPA-000990

KEY-H EC-1 -001372
Sand 100 mesh MSDS

Page of4

Section VI Reactivity Information

Stability Stable

Conditions to Avoid Do not use for abrasive blasting Avoid contact with strong oxidizing agents and

hydrofluoric acid

Hazardous Decomposition Products When heated above 1580 deg is transformed into tridymite and when

heated above 2678 deg it is transformed into cristobalite which are both fibrogenic to the lungs

Hazardous PolymerizationWill not occur

Section VII Spill and Leak Procedures

Leak and Spill Procedures Dike or contain spill to prevent material from entering waterways Pump large

spills into salvage containers Soak up residue or small spills with absorbent pads clay or dirt and place in

salvage containers

Waste Disposal Dispose of according to all local/state and federal regulations

Handling Procedures and Special Equipment Do not get in eyes on skin or on clothing Do not take

internally Do not breathe vapors or dust Wash thoroughly after handling product

Storage Requirements Keep container closed Store in cool dry place Store in well-ventilated area

Section VIII Personal Protection

Respiratory Protection Not generally required unless needed to prevent respiratory irritation If concentration

exist at levels greater than an hour TWA of 0.1 mg/m3 an approved dust respiratory must be worn For

respirable levels that exceed an hour TWA of 0.5 mg/m3 an approved HEPA filter respirator must be worn If

respirable levels exceed an hour TWA of mg/rn3 positive pressure full face respiratory or equivalent is

required Follow guidelines contained in 29 CFR 1910.134 OSHAs respiratory protection standard

Ventilation Provided adequate ventilation Use local exhaust as needed to maintain airborne exposure below

control limits

Personal Protective Equipment Use safety glasses or goggles PVC or nitrile gloves and chemical apron

Section IX Transportation Information

OSHA Label Sand 100 Mesh

Avoid contact with skin eyes and clothing

Wear protective goggles rubber or PVC gloves and aprons

Benchmark Energy Products L.P

4113 Industrial Midland TX 79703

24 hour Chemical Emergency Number 800 424-9300

Product label may contain additional non-OSHA related information

DOT Proper Shipping Name Hazard Class UN/NA Number Packing Group RQ If needed

Not regulated

Label Required None

KEY-HEC-1-000999 KEY-EPA-000991

KEY-H EC-1 -001373
Sand 100 mesh MSDS

Page of

Section Regulatory Information

Environmental Sara Title III

Section 302/304 This product does not contain ingredients listed as an Extremely

Hazardous Substance

Section 311/312 Delayed

Section 313 This product contains the following ingredients at level of 1% or

greater which appear

on the list of Toxic Chemicals None

Other Regulatory Information

TSCA Inventory All of the components in this product appear on the TSCA inventory

Domestic Substances List All of the components in this product appear on the Domestic

Substances List

Section XI DISCLAIMER

This Material Safety Data Sheet MSDS was prepared in accordance with the provisions and requirements of 29

CFR 1910.1200 and discloses the physical and health hazards of all hazardous chemicals contained in the

Product described in this MSDS but unless otherwise noted does NOT describe or disclose ALL of the

chemicals/components in the Product some of which may be Trade Secrets The information included in this

MSDS is based on data developed or compiled by Benchmark Energy Products L.P Benchmark from open

literature independent laboratory studies and other available scientific evidence and is believed to be accurate

and complete but Benchmark makes no warranty with respect thereto Neither does Benchmark make any

representation or warranty express or implied with respect to the Product or its suitability for any

purpose or use hereby disclaiming all such warranties including the implied warranties of merchantability

and fitness for particular purpose and the implied warranty that the Product is free of claims of third

persons by way of infringement or the like Anyone intending to use the Product described in this MSDS

should satisfy himself that the Product is suitable for their particular purposes and intended uses It is the

obligation of each user of the Product described in this MSDS to determine and comply with the requirements of

all statutes local state and federal applicable to its use storage and disposal

Footnote

ACGIIII American Conference of Governmental Industrial Hygienists

NIOSH National Institute for Occupational Safety and Health Hygienists

CAS Chemical Abstracts Service Register number

NIP National Toxicology Program

CL Ceiling Limit

OSHA TWA Occupational Safety and Health Administration Time Weighted Average

IARC International Agency for Research on Cancer

PMCC Pensky Martens Closed Cup Flash Point Determination

ASTM D93-19 34

NA Not Applicable

STEL Short Term Exposure Limit

ICC Tagliabue Closed Cup flash point determination

ND Not Determined

TLV Threshold Limit Value

NFPA National Fire Protection Association

TWA Time Weighted Average hours

KEY-HEC-1-001000 KEY-EPA-000992

KEY-H EC-1 -001374
DATE PREPARED JANUARY 1996

DATE REVISED OCTOBER 111999

T- PAK WARM/OTHER WARM PRODUCTS

MATERIAL SAFETY DATA SHEET

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME PRODUCT CODES

T-PAK WARM/104 CATALOG 11465-010

PORTA WARM DISPOSABLE MATTRESS CATALOG 114 75-010

VHA PORTA WARM DISPOSABLE MATTRESS CATALOG V11475-O1I

INFANT HEEL WARMER CATALOG 11460-010

VHA INFANT HEEL WAEMER CATALOG V1146I-I10

INFANT HEEL WARMER W/TAPE CATALOG 11460-ClOT

NOVA INFANT HEEL WARMER W/TAPE CATALOG V1146I-O1T

DESCRIPTION CHEMICAL MIXTURE

PRODUCT USE PACK USED FOR TEMPORARY TEMPERATURE MAINTENANCE

USER CODE/ IDENTIFICATION

MANUFACTURER

ALLEGIANCE HEALTHCARE

1500 WAUKEGAN ROAD

MCGAW PARK IL 60085 USA

TELEPHONE 1-800-964-5227 CUSTOMER SERVICE AM-430 PM CST M-F

FOR EMERGENCY INFORMATION CONTACT

3E COMPANY 1-800-451-8346

COMPOSITION/INFORMATION ON INGREDIENTS

ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 THIS

PRODUCT CONTAINS NO HAZARDOUS INGREDIENTS

COMPONENT SYNONYM GAS NO PERCENTAGE EXPOSURE LIMITt

W/V

SOOIUM THIOSULFATE

PENTAHYDRATE 10102-17-7 80 NONE

DEXTROSE MONOHYDRATE 50-99-7 15 NONE

WATER 7732-18-5 NONE

LIMIT ESTABLISHED BY ACGIR AND NIOSH

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

NONVOLATILE NONFLAMMABLE MIXTURE IN WATER PACKAGED IN SMALL QUANTITIES

POTENTIAL HEALTH EFFECTS

EYE CONTACT

MAY RE SLIGHT IRRITANT

INGESTION

NOT HAZARDOUS BY INGESTION IN SMALL QUANTITIES

INHALATION

INHALATION NOT LIKELY UNDER NORMAL USE CONDITIONS ASPIRATION HAZARD LIRE THAT

OF WATER

SKIN ABSORPTION

KEY-HEC-1-001001 KEY-EPA-000993

KEY-H EC-1 -001375
PRESENTS NO HAZARD ABSORBED

SKIN CONTACT

SLIGHT IRRITANT TO NONIRRITANT

CARCINOGEN STATUS

OSHA NOT LISTED

NTP NOT LISTED

IARC NOT LISTED

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

NOT APPLICABLE FROM ACCIDENTAL EXPOAURE

FIRST AID MEASURES

EYE CONTACT

RINSE WITH WATER OR NORMAL SALINE

INGESTION

NOT HARMFUL IF ACCIDENTALLY INGESTED IN OMALL QUANTITIES

INHALATION

NONVOLATILE LIQUID TREAT FOR ASPIRATION OF WATER

SKIN CONTACT

NONHAZARDOUS WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND WATER REMOVE

AND LAUNDER OR CLEAN CONTAMINATED CLOTHING AND SHOES

FIRE FIGHTING MEASURES

NONFLAMMABLE SOLUT EON

ACCIDENTAL RELEASE MEASURES

SMALl SPILLS CAN BE TAKEN UP WITH AN ADSORBANT AND PLACED IN CLEAN DRY

CONTAINERS FOR LATER DISPOSAL

THIS PRODUCT IS NONHAZARDOUS WASTE WHEN SPILLED OR DISPOSED OF AS DEFINED IN

RESOURCE CONSERVATION RECOVERY ACT RCBA REGULATIONS 40 CFR 261

HANDLING AND STORAGE

STORE UNDER THE FOLLOWING CONDITIONS

STORE AT ROOM TEMPERATURE NOT TO EXCEED 104 DEC F/40 DEG PROTECT FROM

FREEZING

EXPOSURE CONTROLS/PERSONAL PROTECTION

CLOTHING N/A

EYE PROTECTION N/A

GLOVES N/A

RESPIRATORY PROTECTION

NO RESPIRATORY PROTECTION NEEDED UNDER NORMAL USE CONDITIONS

SKIN PROTECTION

NO SKIN PROTECTION NEEDED UNDER NORMAL USE CONDITIONS

VENTILATION

NO VENTILATION SHOULD BE REQUIRED UNDER NORMAL CONDITIONS OF USE

EXPOSURE GUIDELINES OR LIMITS

NO OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY ACGIH OR NIOSH

KEY-HEC-1-001002 KEY-EPA-000994

KEY-H EC-1 -001376
PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE CLEAR TO OFF WHITE LIQUID

BOILING POINT NOT ESTABLISHED

FREEZING POINT NOT ESTABLISHED

VAPOR PRESSURE NOT ESTABLISHED

SPECIFIC GRAVITY NOT ESTABLISHED

SOLUBILITY IN WATER SOLUBLE

PH NOT ESTABLISHED

10 STABILITY AND REACTIVITY

HAZARDOUS POLYMERIZATION

NOT REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES

INCOMPATIBILITIES SPECIFIC MATEEIALS TO AVOID

ACIDS NITRATE SALTS OXIDIZING ADENTS CHLORINE

DECOMPOSITION PRODUCTS

THERMAL DECOMPOSITION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES

11 TOXICOLOGICAL INFORMATION

SEE WARNING STATEMENTS ON PACKADE LABEL

ADVERSE AND OVERDOSE EFFECTS IN HUMANS

THE FOLLOWING SIDE/ADVERSE EFFECTS HAVE BEEN SELECTED ON THE BASIS OF THEIR

POTENTIAL CLINICAL SIGNIFICANCE AND ARE NOT NECESSARILY INCLUSIVE

GET MEDICAL ATTENTION

FlAY REQUIRE MEDICAL ATTENTION IF HOTHERSOME

MULTIPLE UNITS INGESTED

EXTENSIVE AND PROLONGED EYE OR SEIN CONTACT LEADS TO PERSISTENT IRRITATION

INGESTION OF LARGE QUANTITIES LEADS TO PROLONGED DIARRHEA

12 ECOLOGICAL INFORMATION

ENVIRONMENTAL IMPACT RATING 0-4

NO DATA

ACUTE AQUATIC TOXICITY

NO DATA

DEGRADABILITY

YES

LOG BIOCONCENTRATIONS FACTOR

DATA NOT AVAILABLE

LOG OCTANOL/ WATER PARTITION COEFFICIENT

NO DATA

13 DISPOSAL CONSIDERATIONS

REPROCESS OR BURN IN AN APPROVED INCINERATOR

WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL STATE AND LOCAL

ENVIRONMENTAL CONTROL REGULATIONS PLEASE BE ADVISED HOWEVER THAT STATE AND

LOCAL REQUIREMENTS FOR WASTE DISPOSAL MAY BE MORE RESTRICTIVE OR OTHERWISE

DIFFERENT FROM FEDERAL REGULATIONS

KEY-HEC-1-001003 KEY-EPA-000995

KEY-H EC-1 -001377
14 TRANSPORT INFORMATION

DOT HAZARDOUS MATERIAL REOULAT IONS DO NOT APPLY TO THIS PRODUCT

TRANSPORTATION AND HAZARDOUS MATERIALS DESCRIPTION

DOT SHIPPING NAME NOT APPLICABLE

DOT HAZARD CLASS NOT APPLICABLE

UN/NA NDr4BEE NOT APPLICABLE

PRODUCT RQ LBS NOT APPLICABLE

DOT LABEL NOT APPLICABLE

DOT PLACARD NOT APPLICABLE

FREIGHT CLASS BULR NOT APPLICABLE

FREIGHT CLASS PACKAGE NOT APPLICABLE

PRODUCT LABEL NOT APPLICABLE

15 REGULATORY INFORMATION

FEDERAL REOULATORY INFORMATION

CERCLA SECTION 103 41 CFR 302.4 REPORTABLE QUANTITY

NON-APPLICABLE

CERCLA/SUPERFUND 40 CFR 117.302

NON- APPLICABLE

OSHA PROCESS SAFETY 29 CFR 1910.119

NON-APPLICABLE

RCRA STATUS

IF DISCARDED IN ITS PURCHASED FORM THIS PRODUCT WOULD NOT BE HAZARDOUS WASTE

EITHER BY LISTING OR BY CHARACTERISTIC HOWEVER UNDER RCRA IT IS THE

RESPONSIBILITY OF THE PRODUCT USER TO DETERMINE AT THE TIME OF DISPOSAL WHETHER

MATERIAL CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT SHOULD BE

CLASSIFIED AS HAZARDOUS WASTE 40 CFR 261.20-24

SARA SECTION 302 40 CFR 355.30 EXTREMELY HAZARDOUS SUBSTANCES

NON-APPLICABLE

SARA SECTION 304 40 CFR 355.40

NON-APPLICABLE

SARA HAZARD CATEOORIES TITLE III SECTIONS 311 AND 312 40 CFR 370.21

ACUTE HAZARD NO

CHRONIC HAZARD NO

FIRE HAZABD NO

REACTIVITY HAZARD NO

BUDDER RELEASE HAZARD NO

SARA SECTION 313 40 CFR 372.65 TOXIC CHEMICALS

NON-APPLICABLE

TSCA STATUS

FDA EXEMPT

STATE REGULATORY INFORMATION

CALIFORNIA PROPOSITION 65

NOT ON LIST

OTHER STATES MAY BE MORE RESTRICTIVE OR OTHERWISE DIFFERENT

16 OTHER IN FORMATION

ABBREVIATIONS

CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT

ADMINISTERED BY EPA

IARC INTERNATIONAL AGENCY FOR RESEARCH ON CANCER

NTP NATIONAL TOXICOLOGY PROGRAM

KEY-HEC-1-001004 KEY-EPA-000996

KEY-H EC-1 -001378
OSHA OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION US DEPARTMENT OF LABOR

WHICH REGULATES WORKPLACE CONDITiONS

RCRA RESOURCE CONSERVATION AND RECOVERY ACT ADMINI STERED BY EPA

SARA SUPERFUND ANENDMENTS AND REAUTHORIZATION ACT OF 190 TITLE III IS ALSO

KNOWN AS THE EMEROENCY PLANNING AND COMMUNITY RIGHT-TO-RROW ACT

ADMINISTEEED BY EPA

TSCA TOXIC SUBSTANCES CONTROL ACT

ALLEGIANCE HEALTHCARE CORPORATION DISCLAIMER

NEITHER ALLEGIANCE HEALTHCARE CORPORATION NOR ANY OF ITS AFFILIATES OR

SUBSIDIARIES ASSUMES ANY LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS

INFORMATION FINAL DETERMINATION OF SUITAHILITY OF ANY MATERIAL FOR PARTICULAR

USE IS THE SOLE RESPONSIBILITY OF THE USER ALL MATERIALS MAY PRESENT UNKNOWN

HAZARDS AND SHOULD BE USED WITH CAUTION ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED

HEREIN WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS WHICH EXIST IT IS

THE USERS RESPONSIBILITY TO DETERMINE THE APPROPRIATE HANDLING DISPOSAL OR

OPEN DISPOSITION FOR THE MATERIAL OR EMERGENCY RESPONSE ACTIONS IN LIGHT OF THE

CONDITION OF THE MATERIAL APPLICABLE REGULATIONS AND OTHER CIRCUMSTANCES

ALLEGIANCE HEALTHCARE

MCGAW PARK IL 6008

KEY-HEC-1-001005 KEY-EPA-000997

KEY-H EC-1 -001379
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

KEY-HEC-1-000481 KEY-EPA-000481
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

KEY-HEC-1-000482 KEY-EPA-000482
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

KEY-HEC-1-000483 KEY-EPA-000483
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

KEY-HEC-1-000484 KEY-EPA-000484
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

KEY-HEC-1-001006 KEY-EPA-000998
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

KEY-HEC-1-001007 KEY-EPA-000999
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

KEY-HEC-1-001008 KEY-EPA-001000
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

KEY-HEC-1-001009 KEY-EPA-001001
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

KEY-HEC-1-001010 KEY-EPA-001002
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

KEY-HEC-1-001011 KEY-EPA-001003
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

KEY-HEC-1-001012 KEY-EPA-001004
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

KEY-HEC-1-001013 KEY-EPA-001005
Receive 7/10/98 1040 19155733340 AMERICAN ENERGY Page 16

@7/10/1998 1113 19155733348 CHEMPLE BEARD PAGE 15

Material Safety Data Sheet

NYPA DOT

Co.flrsde $14 American Energy Service ci Not available

Syio.y Not available

TSCA

Cbees1 .g Not applicable

Cbe.kal forela Not applicable

CAS Not appllCSble

CbeW.I ieiIy Phoephonete

COdS

Sip.i Ch.mprnx LC Moleikr wele Not applicable

P.O Box 1011

Snydir Msaueturer Chemplex LC 51d673-72S P.O Box 1071

Matertel Phoephonate scale inhoc Snyder TX 79550

915 573-7298

ecOn IA Flrzt Aid $9.asws

Eye coitact Check for and remove any contact lenses IMMEDLATELY flush eyes with running water for at least 15 mInutes keectng

eyelids open COLD watei may be used DO NOT use an eye ointment Seek medical attention

Skis contect If the chemical got onto the clothed portion of the body remove the contaminated clothes as quickly as possible

protecting your awn hands and body Place the victim under deluge shawer If the chemical touches the victrna

exposed skin such as the hands Gently and thoroughly wash the contaminated skin with running water and non-abrasrie

soap Be particularty careful to clean folds crevices creases and groln COLD water may be used If irritation persints

seek medical attention Wash contaminated clothIng before reusing

Hsasrdou skis contact Wash with disinfectant soap end cover the contaminated skin with an anti-bacterial cream Seek medical attention

S1tht lahalatlo PJIow the victim to rest in welt ventilated area Seek immediate medical attention

Uaardoas IehIatIon Evacuate the vict to safe area as soon as possible Loosen tht clothing such as collar tie belt or waistband If

breathing is difficult administer oxygen If the victim is not breathing perform mouth-to-mouth resuscitation WARNING

It may be dangerous to the person providing aid to grve mouth-to-mouth resusotation when the Inhaled material is tc infectious or corrosr Seek immediate medical attention

3II IeSIiOn LJ ru. IIP.JU VL$IflUIS IiY %MIJUG ...

8ttGntiÆi

Hazardous lacstlo DO NOT induce vomiting Examine the lips and mouth to ascertain whether the tissues are damaged pos3e

indication that the toxic material was Ingested the absence of such ans hawever is not Conclusive Loosen tI clothing such as collar tin belt or waistband If the victim is not breathing perform mouth-to-mouth eeuecatc

Seek medical attention

KEY-HEC-1-001014 KEY-EPA-001006

KEY-H EC-1 -001402
ReceIved 7/10/98 1041 19155733340 AMERICAN ENERGY Page 17

07/10/1998 1113 19155733340 CHEMPLEX BEARD PAGE 17

II HJZEdOUS 1n

CAS %by We%bt TLV/PEL _______________________

pho.phcA.cid

trade secret

KEY-HEC-1-001015 KEY-EPA-001007

KEY-H EC-1 -001403
Received 7/10/96 1041 19155733340 AMERICAN ENERGY Page 18

Ffredc$rtdstlOD products Not plicthle

Flosh ts Not applicable

Not applicable

CHEMPLEX BEARD

Fir ezIkbl.g Not applicable

procedures

Th.$bUftY Not apcable

Reark

No additional remark

Risks of explosion Risks of eelofl of the product presence of mechanical mipect P4ot available

Risks ofelon of the product in presence of static dmcherge Not avthle

No specific information available in our databeee regarding the producta risks of pIoaiOfl the presence of vaictiS

matenats

Re.ark

No additional remark

S.ctlon jvftv Da.a

StebWcy The product stable

RiaMous O.r cts Not avadable

Products ç1dcrsdattoQ Possibly hazardous short term degradation products ama nlikely Hwsver long term degradation products may re

The products of degradation are lees toxic than the product itself

Reusark

No addltnal remark

CorrosMly No specific information is available in our database rgarthng the corrosri4y of th product fri presence of varotis

materiats

R.cusark

No additional remark

urfrst available our database reaardinQ the reactwy of this matenal at presence of vaflCJ3 cthV

No additional remark

07/10/1998 1113 19155733340

The product

Auto-Iguidon te.per.ture Not apcable

Non-f1Tlmnable

PAGE 18

KEY-HEC-1-001016 KEY-EPA-001008

KEY-H EC-1 -001404
Received 7/10/98 1041 19155733340 AMERICAN ENERGY Page 19

87/10/1998 1113 19155733340 CHEMPLEX BEARD

Sedkfl Th nMdCaI fI .. .JiiiAwkak E.ergy Ssrvke

PAGE 19

ig4/5

s.fefl7 Ingestion

TLV TfIa iic.t

1WA CEL mhi

COdIUl lOCal AOfllMl or oug IlmilO

Tozicity for aulls Acute oral tdcity 1150 3060 mg/kg Rat Calculated value for the mbdure

Acute dermal todcity LD5O 5000 mg/kg Rthbit Calculated value for the mbdure

Rawk

No eddionel remark

Cbreak eets as TOOCkY of the product to the reproductive system Not available

ku.s

Rerk

No addlonal renieric

Acute effects as ssa No specific iiformetion is available in our database regarding the otner tedc effects of th material for humans

No additional remark

W.t disposal

Storage Corrosive matetM houI be stored In separate safety etorege cabinet or room

Precastlois Keep container dry Do not breathe gas fumes vapor or spray Never add water to this productS Wear euttstis

protacthle clothig if you feel unwell seek medical attentIon and show the label when possible

S.satt aud leak DIute with water and mop up or absoib with an inert DRY material and place in en appropriate waste disposal C0ntEer

If necessary Neutrelir the residue with duI solution of sodium carbonate

Large sp sad lack Corrosrvs lud

Stop leak if wifhotst risk Abaot with DRY earth sand or otlw non-combustible material DO NOT get water inz

container DO NOT touch spilled material Lisa water spray curtain to divert vapor drift Prevent entry Into aewr

basements or confined areas dike if needed Call for assistance on disposal Neutralize th residue with dI

solution of sodium c.rbonte

Protective Clotkmg Splash Q9les Full gut Vor respirator Boots Gl.es self contained breilng epperattm should be used to

inhalation of the product Sugges protective clothing might not be sufflcient rsult specialist BEFORE handling tH3

-.

KEY-HEC-1-001017 KEY-EPA-001009

KEY-H EC-1 -001405
Reeived 7/10/98 1042 19155733340 AMERICAN ENERGY Page 20

MArklt

ts..p.rtadon

Rtmark

No eddttlonsi remark

tICS CLASS Corrosre uid

Re.srk

No additional remark

NA A8lLJTY

HEALTH RETIVTTV

iPCiPIC KA2A

ederI s.d

Stats

Reg.kdoes

S.ctlon Clothing

Facs eh4d Full sud Vapor resptrator Be sure to use MSI-IA/NIOSH approved respirator or aquivalent Gloves peros

Boots Wear appropriate respirator when ventilatiOn Is kiudequete

Sec fIn Oihr lr4brmaiion

Rdere.ce Not avaIlle

Ptad 7110/98

EMERGENCY RESPONSE 800 633-8253

Ud 1f 4lJS LLIL

Ib.IS u.Œq..y Ii Al 4M14

aaa aiam

@7/10/1998 1113 19155733340

cfl WIi Classlrfcson

DOT DOT CLASS Corrosive quid

CHEMPLEX BEARD

Servke

PAGE 20

page 55

ào corrosive liqu n.o.s Phop4ontC Acid Ill

Re.ark

Not available

Vahdated by Cbep4ei L.C 059/9/94 Verl6sd by Che.pkx L.C

KEY-HEC-1-001018 KEY-EPA-001010

KEY-H EC-1 -001406
MATERIAL SAFETY DATA SHEET

Plexaid 667

NFPA 5r Product And Company Identification

Su%ter tMnufattufel

Chemplex LC Chemplex LC

P.O Box 1071 P.O Box 1071

506CR 137 506 CR 137

Snyder TX 79550 United States Snyder TX 79550 United States

Telephone Number 325 573-7298 Telephone Number 325 573-7298

FAX Number 325 573-3340 FAX Number 325 573-3340

SuDolier Emeroencv Contacts Phone Number Manufacturer Emeraencv Contacts Phone Number

800 6334253 800 6334253

Issue Date 03/04/2003

Product Name Plexakl 667

CAS Number Not Estabtied

Chemical Family Not Available

MSDS Number 101

Synonyms

Not Available

Product/Materiat Uses

Oilfield Scale Inhibitor

Compositionfnfomaton On ngrethents

Uecknt CAS Percent Of

tne Nuaer Tcdal Weht

NO HAZARDOUS INGREDIENT Not EstIish

Hazards Identification

Primaiy Routess Of Entry

Not available

Eve Hazards

Not Available

Skn Hazards

Not Available

Inaestion Hazards

Not Available

Inhalation Hazards

Pao tof

Iot Poaiabe

KEY-HEC-1-001019 KEY-EPA-001011

KEY-H EC-1 -001407
MATERiAL SAFETY DATA SHEET

Plexaid 667

FIrSt Aid Measures

No known EFFECT on eye contact rinse with water for few minutes

Skin

No known EFFECT on skin contact rinse with water for few minutes

lnaestion

Do not induce vomiting Loosen tight clothing such as collar tie belt or waist band If the victim is not

breathing perform mouth-to-mouth resuscitation Seek immediate medical attention

Inhalation

Allow the victim to rest in well ventilated area Seek immediate medical attention

Note To Physician

None

Fire Fighting Measures

Fire And Exolosion Hazards

May be combustible at high temperature

Fire Finhtina Instructions

SMALL FIRE Use DRY chemical powder

%JaiRGE FIRE tise water spTay fog or loam Do not use water iet

Accidental Release Measures

Small Spilt and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal

Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal

Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system

HandlIng And Storage

Handling And Storage Precautions

Keep away from heat Keep away from sources of ignition Empty containers pose fire risk evaporate the

residue under fume hood Ground all equipment containing material Do not breathe gas/fumes/vapor/spray

Keep container dry Deep in cool place Ground all equipment containing material Keep container tightly

closed Keep in cool well-ventilated place Combustible materials should be stored away from extreme heat

and away from strong oxidizing agents

Protective Clothina Pictoaramsi

Exposure Controls/Personal Protection

EvelFace Protection

Safety glasses

Skin Protection

Apron/Lab coat

Pane nf

KEY-HEC-1-001020 KEY-EPA-001012

KEY-H EC-1 -001408
MATERIAL SAFETY DATA SHEET

Plexaid 667

Physical And Chemical Properties

Appearance

Colorless liquid

Odor

Sweelish

Chemical Type Pure

Physical State Liquid

Boiling Point 212

Specific Gravity 1.09 Water1

pH Factor 4-5 At Concentration Of 1% solniWater

Solubility Soluble in water

10 Stability And Reactivity Lt This product is stable

11 Toxicological Information

Acute Studies

No specilic information is avaliable in our database regarding the toxic effects of this material for humans

12 Ecological Information

Data Available..

13 Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropnate and approved waste disposal

facility Processing use or contamination of this product may change the waste management options State and local

disposa% regulaYions may dWIer 1mm fedeia dispos regutsYions ispose of conlaineT and unused contents in

accordance with federal state and local requirements

14 Transport Information

Proper Shipping Name

Not DOT Regulated

15 Regulatory Information

U.S R.aulatorv Infomratkn

Not DOT Regulated

16 Other information

NFPA Ratina

Health

Fire

Reactivity

Revisionipreparer information

MSDS Preparer Edward Vinson

MSDS Preparer Phone Number 915-573-7298

This MSDS Supercedes Previous MSOS Dated 071192002

Pane of

KEY-HEC-1-001021 KEY-EPA-001013

KEY-H EC-1 -001409
MATERIAL SAFETY DATA SHEET

Plexaid 667

Disclaimer

Although reasonable care has been taken in the preparation of th document we extend no warranties and make

no representations as to the accuracy or completeness of the information contained therein and assume no

responsibility regarding the suitablility of this information for the useis intended purposes or for the

consequences of its use Each Edividual should make determination as to the suitability of the information for

their particular purposess

Chemplex LC

PWd UIM PmD5

Pane of

KEY-HEC-1-001022 KEY-EPA-001014

KEY-H EC-1 -001410
KEY-HEC-1-000498 KEY-EPA-000498
KEY-HEC-1-000499 KEY-EPA-000499
KEY-HEC-1-000500 KEY-EPA-000500
KEY-HEC-1-000501 KEY-EPA-000501
KEY-HEC-1-000502 KEY-EPA-000502
KEY-HEC-1-000503 KEY-EPA-000503
Material Safety Data Sheet 

Plexaid 673

Page 1 of 4 

SECTION I – IDENTIFICATION 

PRODUCT NAME: ........................... Plexaid 673 

CHEMICAL FAMILY: . ...................... Phosphonates 

CAS NUMBER: ............................... Mixture

PRODUCT USE: .............................. Oilfield Scale Inhibitor. 

SECTION II – HAZARDOUS INGREDIENTS 

HAZ INGREDIENT PERCENT CAS NUMBER PEL 

ORGANIC 

PHOSPHONIC ACID

SALTS

Proprietary Mixture Not Available

METHYL ALOCHOL 15-25% 67-56-1 Not Available

SECTION III – PHYSICAL DATA 

APPEARANCE: ...............................Yellowish Liquid 

ODOR: ........................................... Fruity 

BOILING POINT: ............................. <100°C

FLASHPOINT: .................................68°F

VAPOR DENSITY (AIR=1): .................1.02 

SPECIFIC GRAVITY (WATER=1): ........0.99 

pH (1% SOLN/WATER):.......................4-6 

SOLUBILITY....................................Easily soluble in cold water, hot water, methanol. 

Soluble in diethyl ether. 

Insoluble in n-octanol. 

WT: ................................................8.3 # per gallon 

SECTION IV – FIRE AND EXPLOSION DATA 

FLASHPOINT: .................................68°F

FLAMMABLE LIMITS:.......................LOWER: 6 % 

UPPER: 36.5 % (Methyl Alcohol) 

Chem

Plex

 

 

DATE PREPARED:...........11/18/2008

REVISION DATE:.............08/25/2009

EMERGENCY NUMBER:...800-633-8253

PRODUCT NUMBER:........01119

Chemplex, Ltd.

506 CR 137

Snyder, TX 79549

(325) 573-7298

CHEMPLEX

KEY-HEC-1-000504 KEY-EPA-000504
Material Safety Data Sheet 

Plexaid 673

Page 2 of 4 

FLAMMABLE HAZARDS: ..................Flammable in presence of open flames and sparks of 

heat, of combustible materials. 

Non-flammable in presence of oxidizing materials, of 

reducing materials. 

EXTINGUISHING MEDIA: ..................Flammable liquid, soluble or dispersed in water. 

FIRE FIGHTING PROCEDURES: .......SMALL: Use dry chemical powder. 

LARGE: Use alcohol foam, water spray or fog. 

EXPLOSION HAZARDS:...................Explosive in form of vapor when exposed to heat or 

flames. Vapor may travel considerable distance to 

source of ignition and flash back. When heated to 

decomposition, it emits acrid smoke and irritating fumes. 

SECTION V – REACTIVITY DATA 

STABILITY: .................................... This product is stable. 

CORROSIVITY: ............................... Not considered to be corrosive for metals and glass. 

REACTIVITY: .................................. Reactive with oxidizing agents. 

Non-reactive with organic materials, metals. 

SECTION VI A - HEALTH HAZARD DATA 

ROUTE OF ENTRY: ......................... Not available. 

ACUTE EFFECT ON HUMANS: ......... Slightly hazardous in case of skin contact (irritant, 

permeator), of ingestion, of inhalation. Non-sensitizer 

for skin. Narcotic. (Methyl Alcohol) 

CHRONIC EFFECTS ON HUMANS: ... This substance is toxic to the nervous system, the 

reproductive system. 

Passes through the placental barrier. 

May be fatal or cause blindness if swallowed. (Methyl 

Alcohol) 

SECTION VI B - FIRST AID 

INHALATION: .................................SLIGHT INHALATION: Allow the victim to rest in a well 

ventilated area. Seek immediate medical attention. 

HAZARD INHALATION: Evacuate the victim to a safe 

area as soon as possible. Loosen tight clothing such as 

a collar, tie, belt or waist band. If breathing is difficult, 

administer oxygen. If the victim is not breathing, perform 

mouth-to-mouth resuscitation. Seek medical attention. 

INGESTION: ................................... Do NOT induce vomiting. Loosen tight clothing such as 

a collar, tie, belt or waist band. If the victim is not 

breathing, perform mouth-to-mouth resuscitation. Seek 

immediate medical attention. 

EYE CONTACT: .............................. Immediately flush eyes with running water for at least 15 

minutes, keeping eyelids open. Cold water may be 

used. 

KEY-HEC-1-000505 KEY-EPA-000505
Material Safety Data Sheet 

Plexaid 673

Page 3 of 4 

SKIN CONTACT: ............................. After contact with skin, wash immediately with plenty of 

water. Gently and thoroughly wash the contaminated 

skin with running water and non-abrasive soap. Be 

particularly careful to clean folds, crevices and groin. 

Cold water may be used. Cover the irritated skin with an 

emollient. If irritation persists, seek medical attention. 

Wash contaminated clothing before reusing. 

SECTION VII – SPILL, STORAGE AND DISPOSAL DATA 

SPILL: ........................................... SMALL SPILL: Dilute with water and mop up, or absorb 

with an inert DRY material and place in an appropriate 

waste disposal container. 

LARGE SPILL: Stop leak if without risk. Absorb with 

DRY earth, sand or other non-combustible material. Do 

not touch spilled material. Prevent entry into sewers, 

basements or confined areas; dike if needed. Eliminate 

all ignition sources. 

WASTE DISPOSAL: ......................... Whatever cannot be saved for recovery or recycling 

should be managed in an appropriate and approved 

waste disposal facility. Processing, use or 

contamination of this product may change the waste 

management options. State and local disposal 

regulations may differ from federal disposal regulations. 

Dispose of container and unused contents in accordance 

with federal, state and local requirements. 

HANDLING: .................................... Keep away from heat. Keep away from sources of 

ignition. Ground all equipment containing material. Do 

not ingest. Do not breathe gas/ fumes/ vapor/ spray. If 

ingested, seek medical advice immediately and show the 

container or the label. Keep away from incompatibles 

such as oxidizing agents. 

STORAGE: ..................................... Flammable materials should be stored in a separate 

safety storage cabinet or room. Keep away from heat. 

Keep away from sources of ignition. Keep container 

tightly closed. Keep in a cool, well-ventilated place. 

Ground all equipment containing material. A refrigerated 

room would be preferable for materials with a flash point 

lower than 37.8°C (100°F). 

SECTION VIII – PROTECTIVE CLOTHING 

RESPIRATORY PROTECTION: ......... Wear appropriate respirator when ventilation is 

inadequate 

PROTECTIVE CLOTHING/EQUIPMENT: .....Safety glasses, lab coat, gloves. 

KEY-HEC-1-000506 KEY-EPA-000506
Material Safety Data Sheet 

Plexaid 673

Page 4 of 4 

SECTION IX – TRANSPORTATION DATA 

PROPER SHIPPING NAME: .............. Flammable liquid, n.o.s., (Contains Methyl Alcohol) 

HAZARD CLASS: ............................ 3 

UN NUMBER: ................................. UN 1993 

PACKAGING GROUP: ..................... II

RQ: ............................................... N/A 

DOT SHIPPING: .............................. Flammable liquid, n.o.s., (Contains Methyl Alcohol), 3, 

UN 1993, PG II

SECTION X – OTHER REGULATORY INFORMATION 

TSCA STATUS: .............................. All components of this product are listed on the TSCA 

inventory. 

NFPA HEALTH: .............................. 1 

NFPA FLAMMABILITY: .................... 3 

NFPA REACTIVITY: ......................... 0 

SECTION XI - ADDITIONAL INFORMATION 

PREPARED BY: .............................. Edward F. Vinson 

EMERGENCY RESPONSE NUMBER: .......... 800-633-8253

KEY-HEC-1-000507 KEY-EPA-000507
KEY-HEC-1-000508 KEY-EPA-000508
KEY-HEC-1-000509 KEY-EPA-000509
KEY-HEC-1-000510 KEY-EPA-000510
KEY-HEC-1-000511 KEY-EPA-000511
MATERIAL SAFETY DATA SHEET

SinterBall Bauxite

SECTION I - SUPPLIER INFORMATION

Common Name: Sinter Blast

Chemical Name: BAUXITE

Formula: CHEMICAL COMPONENTS MIXTURE

Application: ABRASIVE - Service Used: BLASTING

Product CAS#: 1318-16-7

SECTION II-A – COMPONENT INFORMATION

COMPONENT PERCENT (%) TLV mg/m3 PEL mg/m3

Alfa-Alumina >70 10 10

Hematite 1 to 15 N/A 15

Maghemite <2 N/A 15 

SECTION II-B - HAZARDOUS INGREDIENT INFORMATION

INGREDIENT: BAUXITE CAS# 1318-16-7

% WEIGHT 100

PEL-OSHA: 10 mg/m3 Total dust - 5 mg/m3 Respirable as Alumina

TLV-ACGIH: 10 mg/m3 as Al 

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS

Boiling Point: Not applicable

Melting Point: Not applicable

Vapor density (Air=1): Not applicable

% Solubility/Water: Insoluble at 20oC

% Solubility/Sea Water: Insoluble at 20oC

Specific Gravity (H2O=1): 3.58 to 3.68

Biodegradability: Not applicable

Volatiles Percent: Not applicable

Vapor Density: Not applicable

Vapor Pressure (mm Hg): Not applicable

Boiling Point (760mm Hg): Not applicable

Pour Point: Not applicable 

Freeze Point: Not applicable

Evaporation rate (Butyl Acetate=1): Not applicable

Partition Coef (Octanol in Water): Not applicable

Appearance: Black Grains

Odor: Odorless

pH: Neutral

VOC: None

Mineração Curimbaba Ltda

Avenida João Pinheiro, 3665

37704-392 - Poços de Caldas –

Minas Gerais

Brazil

Emergency Telephone:

At any time, in Portuguese language:

+55-35.3729.7600

From 7:30 A.M. to 5:00 P.M.,in

English language:+55-35.3729.7676

KEY-HEC-1-000512 KEY-EPA-000512
SECTION IV - FIRE AND EXPLOSION HAZARD DATA

Flash Point: Not applicable

Auto-Ignition: Not applicable

Extinguishing media: Use water spray, dry chemical, alcohol foam, or carbon dioxide.

Use water to keep fire-exposed containers cool.

Special Fire Fighting Procedures: None needed

Unusual Fire and Explosion Hazards: Not a fire or explosion hazard

NFPA HAZARD CLASSIFICATION

Health: 1 Flammable: 0 Reactivity: 0

HMIS HAZARD CLASSIFICATION

Health: 1 Flammable: 0 Reactivity: 0

SECTION V - REACTIVITY DATA

Stability: Generally considered stable

Incompatibility (Materials to avoid): None expected

Hazardous Decomposition or By-Product: None expected

Polymerization: Polymerization is not expected to occur

SECTION VI - HEALTH HAZARD DATA

ROUTES OF ENTRY

Eyes? YES Skin? YES Inhalation? YES Ingestion? NO

EFFECTS OF OVEREXPOSURE

EYE CONTACT may cause irritation

SKIN CONTACT may cause irritation

INHALATION may cause drying of mucous membranes and respiratory tract irritation

INGESTION may cause gastrointestinal disturbances

CARCINOGENICITY

NTP? NO IARC? NO OSHA? NO

CHRONIC HEALTH HAZARDS

None known

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

May aggravate existing respiratory and/or skin ailments

EMERGENCY AND FIRST AID PROCEDURES

EYE CONTACT: Flush eyes with plenty of water. If irritation develops, call a physician.

SKIN CONTACT: Flush with plenty of water. If irritation persists, call a physician.

INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth.

If breathing is difficult, give oxygen. Call a physician.

INGESTION: Procedures normally not needed. If large quantities are ingested, seek medical advice.

KEY-HEC-1-000513 KEY-EPA-000513
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE

EPA Waste #: Not applicable

UN #: Not applicable

DOT Classification: Not classified

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Contain spillage and scoop up or vacuum. Do not use a cleaning method that will generate dust. Product

can cause slippery floor.

WASTE DISPOSAL METHOD

Federal, state and local disposal laws and regulations will determine the proper waste disposal

procedure. All waste materials should be reviewed to determine the applicable hazards (testing may be

necessary). Disposal requirements are dependent on the hazard classification and will vary by location

and the type of disposal selected. Some waste materials are amenable to recycle/reuse.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

Keep bag closed. Avoid creating or inhaling dust. Wash thoroughly after handling. Store in a cool, dry

location to protect product quality.

PERSONNEL SAMPLING PROCEDURE

For NUISANCE DUST: Refer to NIOSH Manual of Analytical Methods, 3rd Edition Volume 2, Method

0500.

For METALLIC COMPONENTS: Refer to NIOSH Manual of Analytical Methods, 3rd Edition Volume 1,

Method 7300.

SECTION VIII - CONTROL MEASURES

RESPIRATORY PROTECTION

Use NIOSH-approved dust mask if exposure exceeds TLV.

VENTILATION

General; local exhaust ventilation as necessary to control dust.

PROTECTIVE EQUIPMENT

Chemical goggles as needed to prevent irritation.

WORK/HYGIENE PRACTICES

Avoid generating or breathing dust. Use with adequate ventilation. Do not eat, drink, or smoke in work

area.

SECTION IX - FEDERAL AND STATE REGULATIONS 

SARA HAZARD CATEGORIES

IMMEDIATE (Acute) Health Hazard: YES

DELAYED (Chronic) Health Hazard: NO

FIRE Hazard: NO

REACTIVITY Hazard: NO

Sudden Release of PRESSURE: NO

KEY-HEC-1-000514 KEY-EPA-000514
SARA SECTION 313 NOTIFICATION

This product does not contain toxic chemicals subject to the reporting requirements of Section 313 of

Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

The information which is contained in this document is based upon available data and is believed to be correct. However, as such

as it has been obtained from various sources, including the manufacturer and independent laboratories, it is given without warranty

or representation that is complete, accurate and that it can be relied on. Mineração Curimbaba Ltda., has not attempted to conceal

in any way the deleterious aspects of the product listed herein, but makes no warranty as to such. Further, as Mineração

Curimbaba Ltda. cannot anticipate nor control the many situations in which the listed product or this information may be used by

our customer, there is no guarantee that the health and safety precautions suggested will be proper under all conditions. It is sole

responsibility of each user of the listed product to determine and comply with the requirements of all applicable laws and

regulations regarding its use or disposal. This information is given solely for the purposes of heath and safety to persons and

property. Any other use of this information is expressly prohibited. Health, safety, and environment department, Mineração

Curimbaba Ltda.

DATE: 10/10/2005

KEY-HEC-1-000515 KEY-EPA-000515
Sintered Bauxite 

1. Chemical Name & Company Identification

PRODUCT NAME: Sintered Bauxite (all mesh sizes)

SYNONYM(S): Ceramic Proppant

CHEMICAL FAMILY: Aluminosilicate

MANUFACTURER: Saint-Gobain Proppants

5300 Gerber Road

Fort Smith, Arkansas 72904

24-Hour Emergency (479) 782-2001

2. Component Information

CHEMICAL NAME COMMON NAME % BY WEIGHT (TYPICAL)

Aluminum Silicate Mullite 15-35

Aluminum Oxide Corundum 65-85 

3. Hazards Identification

3.1 Emergency Overview 

HMIS RATING

Health: 1. (Slight)

Flammability: 0. (Minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

INHALATION: Prolonged exposure to dusts may cause respiratory 

tract irritation.

INGESTION: No known adverse effects.

EYE CONTACT: May cause irritation on prolonged or repeated contact.

SKIN CONTACT: May cause irritation on prolonged or repeated contact.

4.0 First Aid Measures

INGESTION: Seek medical attention if large quantities are ingested.

INHALATION: Remove to fresh air.

EYE CONTACT: Immediately flush eyes with large quantities of

water. Call a physician if irritation persists.

5.0 Fire Fighting Measures

FLASH POINT: Nonflammable

LOWER EXPLOSION LIMIT: Not applicable

UPPER EXPLOSION LIMIT: Not applicable

AUTOIGNITION TEMPERATURE: Not applicable

Use extinguishing agent suitable 

for type of surrounding fire.

6.0 Accidental Release Measures

SPILLS: No special procedures are required for cleanup of spills or 

leaks. Spherical shape of spilled pellets can create a slip hazard.

7.0 Handling and Storage

Store under dry conditions. Handle with adequate ventilation.

Use a NIOSH/MSHA approved respirator if dust is present.

Material Safety Data Sheet

FOR INDUSTRIAL USE ONLY

KEY-HEC-1-000516 KEY-EPA-000516
8.0 Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creation of dust.

8.2 Personal Protection

Use NIOSH/MSHA approved respiratory protective

equipment when airborne concentrations exceed

acceptable criteria. Wear safety glasses at all times 

to prevent eye irritation.

8.3 Exposure Guidelines

INGREDIENT CAS# %/ OSHA ACGIH-TWA TLV

WT PEL/TWA

Corundum 1302-44-56 65-85 15mg/m3 (Total) 10mg/m3 (Total) 

5mg/m3 (Resp) 3mg/m3 (Resp)

Aluminum 

Silicate 1302-76-7 15-35 15mg/m3 (Total) 10mg/m3 (Total) 

5mg/m3 (Resp) 3mg/m3 (Resp)

9.0 Physical and Chemical Properties

APPEARANCE: Grayish brown to black

free-flowing granules

ODOR: None

FLASH POINT: N/A This material does

not give a flash point by 

conventional methods.

STABILITY: Stable

SPECIFIC GRAVITY: 3.45–3.55

PH: Not applicable

VAPOR PRESSURE @ 25 ̊C: Not applicable

VISCOSITY: Not applicable

SOLUBILITY IN WATER: Nonsoluble

BOILING POINT: Not applicable

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1)

11. Toxicological Information

SEE SECTION 3

LC50 Not available

LD50 Not available

12. Ecological Information

Not determined

13. Disposal Conditions

Dispose of according to local, state/provincial,

and federal requirements.

14. Transportation Information

14.1 U.S. Department of Transportation

Non-regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated

15. U.S. Regulatory Information (Selected Regulations)

SARA TITLE III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA): N/A

CERCLA Reportable Quantity: None

Clean Air AmendmentsHazardous Air Pollutants: None

California State Proposition 65: N/A

16. Other Information

The OSHA Hazard Communication Standard 29CFR 1910.1200

requires that the information contained on these sheets be

made available to your workers. Instruct your workers to 

handle this product properly. Consult with appropriate

experts to guard against hazards associated with use of this

product and its ingredients.

Disclaimer

Seller makes no warranty, expressed or implied, concerning 

the product or the merchantability or fitness thereof for any

purpose, except that the product conforms to contracted 

specifications, and that the product does not infringe any

valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the

quantity of product in respect of which damages are claimed.

In no event shall seller be liable for incidental or consequential damages, whether buyer’s claim is based on contract,

breach of warranty, negligence or otherwise.

ISSUE DATE: 1-SEPTEMBER-06

Tel: 479.782.2001

Toll Free: 800.643.2149

Fax: 479.782.9984

www.proppants.saint-gobain.com

5300 Gerber Road

Fort Smith, AR 72904

KEY-HEC-1-000517 KEY-EPA-000517
KEY-HEC-1-001023 KEY-EPA-001015
KEY-HEC-1-001024 KEY-EPA-001016
KEY-HEC-1-001025 KEY-EPA-001017
KEY-HEC-1-001026 KEY-EPA-001018
Received 7/17/98 909 580 658 3223 AMERICAN ENERGY Page 11

JUL11 45AM F-RUM LRINM-N IbLH INC IU 1l5bb4 Ij.11

125

NFPAkEALTH

NFPA FLAMMABILITY

NFPA REAtTIVITY

...PCIF.IC HAZARD

SECTION IDENTIFICATION

COMPANY NAME ........... PLAINSMAN TECHNOLOGY INC

P.O BOX 57

MARLOW OK 755

4O658-6O

EMEP.SENCY PHONE NUMBER DOMESTIC/INTERNATIONAL 4Q5282-5iO

EFFECTIVE DATE........ Dc.mber 29 1993

REVISED DATE ......... N/A

CHEMICAL NAME Amir

TRADE NAME SSA125

CHEMICAL FA1ILY .... N/A

SECTION II COMPONENTS

HAZARDOUS COMPONENTS HAZAFDOUS PEL/TLV

Mthano1 TWA 200 STEL 676i

2O ACGIH

TWA 200 StEL

2O OSHA

SECTION III PHYSICAL DATA

BOILING PointF

.FREEZIN..PJINT F..--12F

VOLATILITY/VOL% 708O

MELTING POINT NA

VAPOR PRESSURE mm Hop N/A

VAPOR DENSITY Aj.l N/A

S0LUILITY IN H20 CocnpItejy so1ubI

APPEARANCE/ODOR Co1or1e viCCus lould mId odor

SPFflIFIC GRAViTy H2C1 0.9

EVAPORATION RATE N/A

PH

DENSITY S.OStb/1

SECTION IV FIRE AND EXPLOSION HAZARD DATA

FLASH POINT II9CJF TCC

LOWER FLAME LIMIT based on nitharioi

HIHER FLAME LIMIT on mthôj

EXTINGUISH MEDIA Us foc dry chnic1 CD2 wterfo or FOR FIRE Do not enter fire area aithout.DrDQr rotcve

equofm2nt ineludi NIOSH/MSHA aporovd ifcontind brthinQ Dratu Cool xood

cortirrs with water Drav.Avojd.vDor

2/1ô/1997 1--

KEY-HEC-1-001027 KEY-EPA-001019

KEY-H EC-1 -001501
Received 7/17/98 910 580 658 3223 AMERICAN ENERGY Page 12

JUL171998 094EAM FROM PLAINSMPN TECH INC TO 19156872542 P.12

SSA-125

UNUSUAL FIR.E HAZARD..... Material is Combustible Vapors are heavier thar

and may travel .lor orourd to ignition source arid

flash back Never use ae1cino orcu torch on or near drums even when empty Explosin may result

SECTION HEALTH HAZARD DATA

ROUTES OF ENTRY INHALATION EYES SKIN INGESTION

Yes

HEALTH HAZARDS ... .... N/A

NTP IARC MONOGRAPHS OSHA REGULATED

No

Not established

N/sZ

INHALATION Inhalation of hiQh levels of vaoors or mists may cause liohtheadedness dizzinss headaches or urtconscaousress

EYES Eye contact may cus9 irritation redr.e SKIN Prolonoed or repeated contact with skin may Ca irritation or

tN3ETIJN May be harmful if rrge5ted EYES Flush eyes immediately with laroe amours

water for at least 15 minutes Call phvjcian

irritation persists

INHALATION Remove to fresh air If labored breathjn continues contact physician SKIN Remove contaminated clothes .Wah skin

thorouthly with mild soao.and waters Launoer clotho

before reuse

INGESTION DO NOT induce .vomitjno If conscious

drink are amounts of catr and contact

physician

SECTION VI REACTIVITY flATA

CHEMICAL STAILIYY......

CONDITIONS TO AVOID

INCOMPATIBLE MATERIALS..

DECOMPOSrr ION PRODUCTS..

HAZARDOUS POLYMERIZATION

POLYMERIZATION AVOID....

SECTION VII SPILL OR LEAK PROCEDURE

CARCINOGENICITY

THRESHOLD LIMIT VALUE...

SYMPTOMS

OVER EXPOSURE EFFECTS

FIRST AID RQCEDjRE5

Stable

Oidjzrg heat sparks or ooeri .f1am

Oxidzers heat sparks or bpeh..flame

Carbon monoxide oides of niitrcôen

hJill OCCUI

None

12/1 1997

KEY-HEC-1-001028 KEY-EPA-001020

KEY-H EC-1 -001502
Received 7/17/98 910 580 658 3223 AMERICAN ENERGY Page 13

JUL171998 0946AM FROM PL1INSMAN TECH INC TO 19156872542-- P.13

12/16/1997

Don aoproDrite brotctioe clothincj nd resoirtory

orotetion orior to entei-incj Sp.jl1fiEk

1iirte ioritior soureg rth area uüwind -f

rJossible Shut off leak if it caribe done safeiv

Di .e ard oumo large siils into salvaoe Containers

Soak residue and sma11oiuis.tii.th absorbent clay sand or dirt and riace sg.iye containers RC

portable cuantity is ceded rØort to NationaL

spil Resporse Office 18004249802 Also in

.iurisdictions spills or leaks of any hazardous

materialE are reportableçrs1t local lead arcies

for further formation Cantilnue tO observe

orecauton

Reevaluation of the oroduct maybe reauired by the

user the time of disDosal sincthe oroduct uses

trnformations mixtures arid prO.csses may chanos

the clasifjcatjop to norhaardthis or hazardQLs or reasons other than or in ddition to DtOdJ.t

characterjstj DisDoe ofail waste and/or

containers ir accordance ith federal stete anc

local reciultions

Avoid jntialatjori o1 vapors or mists Do no oct jr

eyes on skin or on clothing Keep.ccntairer closed

when reot in use Wear suitablep.rotction fo eyes aflC skin when hardlinô. Use wih adouate

ventilat0n Avoid contact with ojdjcrs 9tore jr

area Storei ol dry area

Control jonition ourc keep way from heat soark

and ooen flame -1

FOR SPILL

WASTE DISPOSAL METHOD

HANDLING AND STORAGE

PRECAUTIONARY MEASURES None

SECTION VIII SPECIAL PROTECTION

RESPIRATORY PROTECTION.. Use resiratory devica arid other ersonai orotectve

eauiomert reouircci by OSHA29CFR110

VENTILATION Th use of mechanical ventilation is ro-rimeded

whenever this oroduct in confined soace is

heated above ambient tecnberatLI.res or is aoi tated

tJhere erqineerirtci controls are not feasible assure use is in an area where there is.rtural air

movement

PROTECTIVE GLOVES Neorrenc or rubber ciloves

EYE PROTECTiON

OTHER PROTECTIVE

EQUIPIIENT

SECTION IX SPECIAL PRECAUTIONS

HAZARD CLASS Flammable Liujd

DOT SHIPPING NAME Flammable lioulds n.o.s.

Contains Methanol

UN1993 3III

REPORTABLE QUANTITY RQ N/A

UN NUMBER 1953

NA

KEY-HEC-1-001029 KEY-EPA-001021

KEY-H EC-1 -001503
Received 7/17/98 911 580 658 3223 -AMERICAN ENERGY Page 14

SSA125

P4CKAeIN SIZE oallor drums

Sara Tit1 III uorfund Amerdrnents ReauthorizatjflAct5cf..1986 Stior

302 311k 312

Sctiori 302 Etrecne1v Haardo Substances 40CFR355 Th.s orouct does

not cortain irredi.ents listed in ADQertdi and as.nxtreme1y Hazardous

Subs tarse

St.ons 311 312 Material Safety Data Sheet Rquirernert 40CFR370 JL1P

hazard evaluation has ound this orodLLct to be hazardous. ..Th roouct shuid

be reoorted under the foil minio EPA hazard cateoories

Immediate acute health hazard

Deiave croriic health h-9zard

Fire hazar

_n/a_ Suddert relea o-f oressure hazard

_r/a_ Reactive haard

Jrder Section 311 submittal of NSDSs or iisto duct.names to local emerecy piannirci mmission state emerQency subnse commnisin lccai tire deoartment is rajred aftei- October 17 .1989 for all hazardous substances

Section 13 Lit of Tcxi Cemjcals 40CFR372 Th.js.oroduct contains the liowino incredients ith CAS and rarae which .oear on the List o-f Toxic Chemicals Methanol

DISCLAIMER OF LIAEILlTv

Plainsmar Techr.olooy Lnc tarrants only title to the odid rHis WARRANTY IS IN LIEU OF ALL JTHER WARRANTIES EXPRESS OR ItPLIE WITH RESPECT TO THE GOODS SOLD 1NCLUDINs UT NOT LIMITED TO THE IMPLIED THE IMPLIED WARRANTIES OF UTILITY MERCHANTABILITY OR FITNESS FOR PARTICULAR USE Plainsman Thriolocy Inc not warrart that the Oodd or he made threo-f by th buyer ui11 not infrinQe any i.flteilectLm oropercv rihts iricludinci but not limited to oatents ny third Party and that use of rnoods sold ii1 riot aamace ary subterranean formation tzjhich oms -rto contt with oods

12/16/19c7 4--

TDTflL P.14

KEY-HEC-1-001030 KEY-EPA-001022

KEY-H EC-1 -001504
SAPJTROL Material Safety Data Sheet

Product Superset

Section

Manufacturers Name Telephone Number

Santrol 281 431-0670

2727 FM 521

Fresno TX 77545 Date 06/02/97

Section II Emergency Assistance

For emergency Assistance involving chemicals call CHEMTREEC 800 424-9300

Section III Hazardous Ingredients

Hazardous components CAS OSHA PEL ACGIH TLV OTHER

Methanol 67-56-1 200 PPM 200 PPM

Poiyoxyethylenenonylphenol ether 9016-45-9 none none

mmHg Temp Weight

Vaper Pressure 100.0 70F 43

0.0 68F 55

DOT Proper Name Methyl Alcohol Solution

DOT Hazard Class

Dot Id No UN1230 PGII Guide 28

Hazard Rating Scale Product

0-Minimal 3-Serious Health

1-Slight 4-Severe Fire

2-Moderate Reactivity

Special NONE

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency

Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372

CAS Chemical Name by Weight

67-56-1 Methanol 60

California Safe Drinking Water and Toxic Enforcement Act of 1986

This product may contain trace amounts less than loppm of Ethylene Oxide CAS 75-21-8 and trace amounts up to

125 ppm of 14-Dioxane CAS 123-91-1

Page

KEY-HEC-1-001031 KEY-EPA-001023

KEY-H EC-1 -001505
SANTROL Material Safety Data Sheet

Product Superset

Section IV Physical/Chemical Characteristics

Boiling Point 148F Specific Gravity H201 0.910

Vapor Pressure mmHg 97 at 20C Melting Point N/A

Vapor Density Air1 1.1 Evaporation Rate Butyl Acetate1

Solubility in Water Complete Appearance and Odor Colorless liquid alcohol odor

Section Fire and Explosion Hazard Data

Flash Point 58F TCC Flammable Limits in air Lower Upper 36.5

Extinguishing Media Use water spray alcohol foam CO2 or Dry Chemical Do not use direct water stream

Special Fire Fighting Procedures

Fire Fighters should wear self contained breathing apparatus Use water spray to cool nearby containers

and structures exposed to fire

Unusual Fire and Explosion Hazards

Extinguish all nearby sources of ignition This product may burn with flame which is invisible in daylight

Section VI Reactivity Data

Stability Stable Polymerization Will not occur

Conditions to avoid Heat sparks and open flames

Materials to avoid Strong Oxidizers aluminum zinc Any metal that displaces hydrogen certain plastics and rubber

Hazardous decomposition products May liberate carbon monoxide carbon dioxide formaldehyde and unidentified

compounds in black smoke

Section VII Health Hazard Data

Primary Routes of exposure Swallowing skin or eye contact inhalation

Signs and symptoms of exposure

Inhalation Prolonged or repeated exposure or breathing very high concentrations may cause headaches

nausea vomiting dizziness and visual disturbances

Eye contact Vapors may irritate the eyes Liquid and mists may severely irritate or damage the eyes

Skin contact Contact with skin may cause severe irritation Prolonged contact may cause dermatitis

Swallowed Swallowing large quantities causes headaches nausea vomiting blindness damage to pancreas

and perhaps death

Chronic effects of exposure Prolonged or repeated exposure may result in CNS damage blindness damage

to pancreas and perhaps death

Medical conditions generally aggravated by exposure None known

Emergency and First Aid Procedures

Inhalation Remove to fresh air Give artificial respiration if not breathing Get immediate medical attention

Eye contact Immediately flush eyes with running water for at least 15 minutes Get immediate medical

attention

Skin contact Immediately was skin with lots of soap and water Remove contaminated clothing and shoes and

wash before reuse Get medical attention if irritation persists after washing

Swallowed If conscious immediately induce vomiting by giving glasses of warm water and sticking finger

down the throat Get immediate medical attention After patient has vomited give milk water or

solution of sodium bicarbonate ltsp/qt Do not give anything to an unconscious or convulsing

person

Page

KEY-HEC-1-001032 KEY-EPA-001024

KEY-H EC-1 -001506
SANTROL Material Safety Data Sheet

Product Superset

Section VIII Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released

Wear protective equipment including rubber boots rubber gloves rubber apron chemical goggles and respiratory

protection Extinguish all ignition sources and ensure that all handling equipment is electrically grounded For

small spills or drips mop or wipe up and dispose of in DOT approved waste containers For large spills contain

by diking with soil or other absorbent material and then pump into DOT approved waste containers or absorb with

absorbent material and place in DOT approved waste containers Keep out of sewers storm drains surface

waters and soil Comply with all applicable Governmental regulations on spill reporting and handling and disposal

of waste

Precautions to Be Taken in Handling and Storing

Keep away from heat sparks and flames Store in cool dry place Vent container frequently and more often in

warm weather to release pressure Electrically ground all equipment when handling this product and use only

non-sparking tools Keep container tightly closed when not in use Do not get in eyes on skin or on clothing

Repair and Maintenance Precautions

Do not cut grind weld or near this container

Other Precautions

Containers even those that have been emptied will retain product residue and vapors Always obey hazard

warnings and handle empty containers as if they were full

Section IX Control Measures

Respiratory Protection NIOSH-Approved canister respirator in the absence of adequate environmental contros at the

point of use

Ventilation Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL

Eye Protection Chemical Goggles

Protective Clothing Long-sleeved shirt full length trousers safety shoes rubber gloves and rubber apron

Other Precautions An eyewash and safety shower should be nearby and ready for use

Section Toxicity Data

Methanol

Oral Rat LD50 5.628 g/kg

Dermal Rabbit LD50 20 g/kg

Inhalation Rat LC50 64000 ppm/4h

Polyoxyethylenenonlyphenol ether

Oral Rat LD50 g/kg

Dermal Rabbit LD50 g/kg

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for particular purpose with respect tot he product or information provided herein

All information appearing herein is based upon data obtained from recognized technical sources While the information is believed to be accurate Santrol makes no

representations as to its accuracy or sufficiency Conditions of use are beyond Santrols control and therefore users are responsible to verify this data under their own operating

conditions to determine whether the product is suitable for their particular purposes arid they assume all risks of their use of or reliance upon information contained herein

This information relates only to the product designated herein and does not relate to its use in combination with any other matenal or in any other process

Page

KEY-HEC-1-001033 KEY-EPA-001025

KEY-H EC-1 -001507
SANTROL Material Safety Data Sheet

Product: Superset W

Page 1

Section I

Manufacturer's Name Telephone Number

Santrol (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/10/02

Section II - Emergency Assistance

For emergency Assistance involving chemicals call - CHEMTREC (800) 424-9300

Section III - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV OTHER

50 % Methanol 67-56-1 200 PPM 200 PPM

50 % Poly(oxyethylene)nonylphenol ether 9016-45-9 none none

Vapor Pressure: Methanol –100mm Hg @ 70°F

 Poly(oxyethylene)nonyphenol ether – 0 mm Hg @ 68°F

DOT Proper Name: Methyl Alcohol Solution

DOT Hazard Class: 3 Flammable Liquid

Dot Id No: UN1230, PGII, (BP>95°F,FP,73°F) Guide 131 (2000 Emergency Response Guidebook)

Hazard Rating Scale: 2 Product:

0-Minimal 3-Serious Health: 2

1-Slight 4-Severe Fire: 3

2-Moderate Reactivity: 0

Special: NONE

Canada Hazardous Products Act

 Ingredients Disclosure List

Chemical Name: % Item Number French Version Cas#

Methyl Alcohol 50% 1012 183 67-56-11

Class B- Flammable liquid having a flash point between 0° and 100°F

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:

CAS# Chemical Name % by Weight

67-56-1 Methanol <60

KEY-HEC-1-001034 KEY-EPA-001026
SANTROL Material Safety Data Sheet

Product: Superset W

Page 2

California "Safe Drinking Water and Toxic Enforcement Act of 1986"

This product may contain trace amounts (less than 10ppm) of Ethylene Oxide (CAS # 75-21-8), and trace amounts

(up to 125 ppm) of 1,4-Dioxane (CAS # 123-91-1).

Section IV - Physical/Chemical Characteristics

Boiling Point: 148oF Specific Gravity (H2O=1): 0.910

Vapor Pressure (mmHg): 97 at 20oC Melting Point: N/A

Vapor Density (Air=1): 1.1 Evaporation Rate (Butyl Acetate=1): >1

Solubility in Water: Complete Appearance and Odor: Colorless liquid, alcohol odor

Section V - Fire and Explosion Hazard Data

Flash Point: 58oF (TCC) Flammable Limits in air, % : Lower: 6 Upper: 36.5

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. Do not use direct water stream

Special Fire Fighting Procedures:

Fire Fighters should wear self contained breathing apparatus. Use water spray to cool nearby

containers and structures exposed to fire.

Unusual Fire and Explosion Hazards:

Extinguish all nearby sources of ignition. This product may burn with a flame which is invisible in

daylight.

Section VI - Reactivity Data

Stability: Stable Polymerization:Will not occur.

Conditions to avoid: Heat, sparks and open flames.

Materials to avoid: Strong Oxidizers, aluminum, zinc. Any metal that displaces hydrogen; certain plastics and

rubber.

Hazardous decomposition products: May liberate carbon monoxide, carbon dioxide, formaldehyde, and

unidentified compounds in black smoke.

Section VII - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Signs and symptoms of exposure:

Inhalation: Prolonged or repeated exposure or breathing very high concentrations may cause

headaches, nausea, vomiting, dizziness and visual disturbances.

Eye contact: Vapors may irritate the eyes. Liquid and mists may severely irritate or damage the eyes.

Skin contact: Contact with skin may cause severe irritation. Prolonged contact may cause dermatitis

Swallowed: Swallowing large quantities causes headaches, nausea, vomiting, blindness, damage to

pancreas and perhaps death.

Chronic effects of exposure: Prolonged or repeated exposure may result in CNS damage, blindness,

damage to pancreas and perhaps death.

Medical conditions generally aggravated by exposure: None known.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical

attention.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

KEY-HEC-1-001035 KEY-EPA-001027
SANTROL Material Safety Data Sheet

Product: Superset W

Page 3

Skin contact: Immediately was skin with lots of soap and water. Remove contaminated clothing and shoes

and wash before reuse. Get medical attention if irritation persists after washing.

Swallowed: If conscious, immediately induce vomiting by giving 2 glasses of warm water and sticking

finger down the throat. Get immediate medical attention. After patient has vomited, give

milk, water or solution of sodium bicarbonate (1tsp/qt). Do not give anything to an

unconscious or convulsing person.

Section VIII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, chemical goggles, and

respiratory protection. Extinguish all ignition sources and ensure that all handling equipment is electrically

grounded. For small spills or drips, mop or wipe up and dispose of in DOT approved waste containers. For

large spills, contain by diking with soil or other absorbent material and then pump into DOT approved waste

containers or absorb with absorbent material and place in DOT approved waste containers. Keep out of

sewers, storm drains, surface waters, and soil. Comply with all applicable Governmental regulations on spill

reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat, sparks, and flames. Store in a cool, dry place. Vent container frequently, and more

often in warm weather, to release pressure. Electrically ground all equipment when handling this product and

use only non-sparking tools. Keep container tightly closed when not in use. Do not get in eyes, on skin, or

on clothing.

Repair and Maintenance Precautions:

Do not cut, grind, weld, or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section IX - Control Measures

Respiratory Protection: NIOSH-Approved canister respirator in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the

PEL.

Eye Protection: Chemical Goggles

Protective Clothing: Long-sleeved shirt, full length trousers, safety shoes, rubber gloves, and rubber apron.

Other Precautions: An eyewash and a safety shower should be nearby and ready for use.

Section X - Toxicity Data

Methanol

Oral: Rat LD50 - 5.628 g/kg

Dermal: Rabbit LD50 - 20 g/kg

Inhalation: Rat LC50 - 64,000 ppm/4h

Poly(oxyethylene)nonlyphenol ether

Oral: Rat LD50 - < 5 g/kg

Dermal: Rabbit LD50 - > 3 g/kg

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

KEY-HEC-1-001036 KEY-EPA-001028
SANTROL Material Safety Data Sheet

Product: Superset W

Page 4

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol makes no

representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their own

operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon, information

contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other

process.

KEY-HEC-1-001037 KEY-EPA-001029
Material Safet Dale icct

ThLwie

DATE PPED.71153

REVISION DATE 04/19/04

Chcmplcx L.C EMERGENCY NUUBER...800-633-8253

Snyder TX 79549

PRODUCT NUMBER 00904

325 573-7298

SECTION IDENTIFICATION

PRODUCT NAME Toluene

SYNONYMS- Methytbenzene

CHEMICAL FAMILY- Aromatic Hydrocarbons

CAS NUMBER- 108-88-3

PRODUCT USE- Coatings Solvent for resins

industrial applications

Intermediate Manufacture of

ofganic products Textile

industry Manufacture of soaps

and detergents

SECTION II HAZARDOUS INGREDIENTS

HAZ INGREDIENT PERCENT CASMIMBER PEL

TOLUENE 95 100 108-88-3 TWA 100pprn

SECTION III PHYSICAL DATA

ApPEARANCE- Coloiless liquid

ODOR Benzene-Iike Strong

BOILING POINT 110.6C 231.1F

FLASHPOINT CLOSED CUP 4.4C 39.9F OPEN CUP 12.78C

55F Cleveland

VAPOR DENSITY AIR1 3.14

VAPOR PRESSURE 2t9 mm of Hg @20C

EVAPORATIVE RATE Not Available

SPECIFIC GRAVITY WATER1- 0.87

pH 1% SOLNIWATER Not available

SOLUBILITY Easy soluble in methanol diethyl ether

Soluble in n-octanol

Very slightly soluble in cold water hot water

WI 7.26 per gallon

Page of5

KEY-HEC-1-001038 KEY-EPA-001030

KEY-H EC-1 -001509
Mateiial Safety Data Sheet

Toluene

SECTION IV FIRE AND EXPLOSION DATA

FLASHPOINT CLOSED CUP 4.4C 39.9SF OPEN CUP 12.78C

55F Cleveland

FLAMMABLE LIMITS LOWER 1.2%

UPPER 7.1%

FLAMMABLE HAZARDS Highly flammable in presence of open flames and sparks

Slightly flammable to flammable in presence of heat of

oddizing matenals of combustible mateæa$s

Very slightly to slightly flammable in presence of

reducing materials

EXTINGUISHING MEDIA Flammable liquid soluble or dispersed in water

FIRE FIGHTING PROCEDURES SMALL FiRE Use DRY chemicals C02 water spray or

alcohol foam

LARGE RRE Use alcohol foam water spray or fog

Cool containing vessels with waler jet in order to prevent

pressure build-up autoignition or explosion

EXPLOSION HAZARDS Vapor may travel considerable distance to source of

ignition and flash back

SECTION REACTWITY DATA

STABILiTY This product is stable

CORROSIVflY Non-corrosive in presence of glass

REACTIVITY Highly reactive with oxidizing agents organic materials

SECTION VI HEALTH HAZARD DATA

ROUTE OF ENTRY ingestion skin contact inhalation

ACUTE EFFECT ON HUMANS Very dangerous in case of skin contact Irritant

perrneator of eye contact Irritant of ingestion of

Inhalation Very slightly to slightly dangerous in case of

skin contact sensitizer

CHRONIC EFFECTS ON HUMANS .. The substance is toxic to blood kidneys the nervous

system liver Inhalation of vapors may cause dizziness

an irregular heartbeat narcosis nausea or asphyxiation

SECTiON VI FIRST AID

INHALATION SLIGHT INHAL.4 T1ON Allow the victim to rest in well

ventilated area Seek immediate medical attention

HAZARD INHALATION Evacuate the victim to safe

area as soon as possible Loosen tight clothing such as

collar tie bell or waist band If breathing is difficult

administer oxygen If the victim is not breathing perform

mouth-to-mouth resuscitation Seek medical attention

Page of

KEY-HEC-1-001039 KEY-EPA-001031

KEY-H EC-1 -001510
Material Safcty Data Sheif

Toluene

WARNING It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation when

the inhaled material is toxic infectious or corrosive

INGESTION SUGHT INGESTiON Mow the victim to rest in well

ventilated area Seek immediate medical attention

HAZARDOUS INGESTiON Do NOT induce vomiting

Examine the lips and mouth to ascertain whether the

tissues are damaged possible indication that the toxic

material was ingested the absence of such signs

however is not conclusive Loosen tight clothing such

as collar tie belt or waist band If the victim is not

breathing perform mouth-to-mouth resuscitation Seek

medical attention

EYE CONTACT- Check for and remove any contact lenses Immediately

flush eyes with running water for at least 15 minutes

keeping eyelids open Cold water may be used Do

NOT use an eye ointment Seek medical attention

SKIN CONTACT If the chemical got onto the dothed portion of the body

remove the contaminated clothes as quickly as possible

protecting your own hands and body Place the victim

under deluge shower If the chemical touches the

victims exposed skin such as the hands Gently and

thoroughly wash the contaminated skin with running

water and non-abrasive soap Be careful to clean folds

crevices creases and groin Cover the irritated skin with

an emollient If imtation persists seek medical attention

Wash contaminated clothing before reusing If the

chemical got onto the clothed portion of the body

remove the contaminated clothes as quickly as possible

protecting your own hands and body Place the victim

under deluge shower If the chemical touches the

victims exposed skin such as the hands Gently and

thoroughly wash the contaminated skin with running

water and non-abrasive soap Be careful to dean folds

crevices creases and groin Cover the imtated skin with

an emollient If irritation persists seek medical attention

Wash contaminated clothing before reusing

SECTION VII SPILL STORAGE AND DISPOSAL DATA

SPILL SMALL SPILL Absorb with an inert material and put

the spilled material in an appropriate waste disposal

LARGE SPILL Keep away from heat Keep away from

sources of ignition Stop leak if without risk Absorb with

DRY earth sand or other non-combustible material DO

NOT touch spilled material Prevent entry into sewers

basements or confined areas dike if needed Eliminate

all sources of ignition

WASTE DISPOSAL- Whatever cannot be saved for recovery or recyding

should be managed in an appropriate and approved

waste disposal facility Processing use or

Page of5

KEY-HEC-1-001040 KEY-EPA-001032

KEY-HEC-1 -001511
Material Safety Data Shea

Toluene

contamination of this product may change the waste

management options State and local disposal

regulations may differ from federal disposal regulations

Dispose of container and unused contents in accordance with federal state and local HANDLING requirements

Keep locked up Keep container thy Keep away from heat Keep away from sources of ignition Ground all

equipment containing material Do not ingest Do not

breathe gaslfumes/ vapor/spray Never add water to this

product In case of insufficient ventilation wear suitable

respiratojy equipment If ingested seek medical advice

immediately and show the container or the label Avoid contact with skin and eyes Keep away from

iflcOmpatibjes such as oxidizing agents reducing

agents organic materials acids alkalis STORAGE Flammable materials should be stored in separate

safety storage cabinet or room Keep away from heat

Keep away from sources of ignition Keep container

tightly closed Keep in cool well-ventilated place

Ground all equipment containing material refrigerated

room would be preferable for materials with flash point lower than 37.8C 100F

SECTION VIII PROTECTIVE CLOTHiNG

RESPIRATORY PROTECTION Use MSHA/NlOSI.f approved resp1rator- or equivalent PROTECTIVE CLOTH INGIEQUIPMENT Goggles lab coat apron gloves

SECTION IX TRANSPORTATION DATA

PROPER SHIPPING NAME- Toluene

HAZARD CLASSUN NUMBER UN 1294

PACKAGING GROUP

DOT SHIPPING Toluene UN 1294 PG II

SECTiON OTHER REGULATORy INFORMATION

TSCA STATUS- MI components of this product are hsted on the TSCA

inventory NFPA HEALTH

NFPA FLAMMABILITY

NFPA REAc-rIviry

Page of

KEY-HEC-1-001041 KEY-EPA-001033

KEY-H EC-1 -001512
MdeiiaI Safety Data Sheet

Touene

SECTION XI ADDITIONAL INFORMATION

PREPARED BY Edward \Tinson

EMERGENCY RESPONSE NUMBER 800-633-8253

PageS of

KEY-HEC-1-001042 KEY-EPA-001034

KEY-H EC-1 -001513
International Chemical Safety Cards WHO/IPCS/ILO Page of

International Chemical Safety Cards

TOLUENE ICSC 0078

TOUJ1NE

Methylbe rizene

Toluol

C6H5CITI3/C7H8

Molecular mass 92.1

CAS 108-88-3

RTECS XS5250000

ICSC 0078

UN 1294

EC 601-021-00-3

ACUTE HAZARDS

PIREVENTION FIRE FIGHTING

FIRE Highly flammable NO open flames NO sparks and Powder AFFF foam carbon

NO smoking dioxide

Vapour/air mixtures are Closed system ventilation In case of fire keep drums etc

explosive explosion-proof electrical cool by spraying with water

equipment and lighting Prevent

EXPLOSiON build-up of electrostatic charges

e.g by grounding Do NOT

use compressed air for filling

discharging or handling

STRICT HYGIENE AVOLI

EXPOSURE EXPOSURE OF PREGNANT

WOMEN

Dizziness Drowsiness Ventilation local exhaust or Fresh air rest Artificial

INHALATION Headache Nausea breathing protection respiration if indicated Refer for

Unconsciousness medical attention

Dry skin Redness Protective gloves Remove contaminated clothes

SKIN Rinse and then wash skin with

water and soap Refer for

medical attention

Redness Pain Safety goggles or face shield First rinse with plenty of water

EYES for several minutes remove

contact lenses if easily possible

then take to doctor

Abdominal pain Burning Do not eat drink or smoke Rinse mouth Give slurry of

INGESTION sensation further see during work activated charcoal in water to

Inhalation drink Do NOT induce vomiting

Refer for medical attention

SPILLAGE DISPOSAL STORAGE PACKAGING

Collect leaking liquid in sealable Fireproof Separated from strong

containers Absorb remaining liquid in oxidants symbol

sand or inert absorbent and remove to Xn symbol

http//www2.hazard.com/msds/mf/cards/fi1e/0078.htmIl 9/27/2007

KEY-HEC-1-001043 KEY-EPA-001035

KEY-H EC-1 -001514
International Chemical Safety Cards WHO/IPCS/ILO Page of

safe place Do NOT wash away into 11-20

sewer extra personal protection self- 2- 16-25-29-33

contained breathing apparatus UN Hazard Class

UN Packing Group II

SEE IMPORTANT INFORMATION ON BACK

CC p078 Prepared in the context of cooperation between the International Programme on Chemical Safety the

Commission of the European Communities IPCS CEC 1993

International Chemical Safety Cards

TOLUENE ICSC 0078

PHYSICAL STATE APPEARANCE ROUTES OF EXPOSURE

COLOURLESS LIQUID WITh The substance can be absorbed into the body by

CHARACTERISTIC ODOUR inhalation through the skin and by ingestion

PHYSICAL DANGERS INHALATION RISK

The vapour is heavier than air and may travel harmful contamination of the air can be

along the ground distant ignition possible As reached rather quickly on evaporation of this

result of flow agitation etc electrostatic substance at 20C

charges can be generated

EFFECTS OF SHORT-TERM EXPOSURE

CHEMICAL DANGERS The substance irritates the eyes and the

Reacts violently with strong oxidants causing respiratory tract Exposure could cause central

fire and explosion hazard nervous system depression Exposure at high

levels may result in cardiac dysrhythmia

OCCUPATIONAL EXPOSURE LIMITS unconsciousness and death

OELs

TLV 50 ppm 188 mg/rn3 as TWA skin EFFECTS OF LONG-TERM OR

ACGIH 1993-1994 REPEATED EXPOSURE

Repeated or prolonged contact with skin may

cause dermatitis The substance may have

effects on the central nervous system resulting

in decreased learning ability and psychological

disorders Animal tests show that this substance

possibly causes toxic effects upon human

reproduction

Boiling point 11 1C Relative density of the vapour/air-mixture at

Melting point -95C 20C air 1.06

PHYSICAL Relative density water 0.87 Flash point 4C c.c.C

PROPERTIES Solubility in water none Auto-ignition temperature 480C

Vapour pressure kPa at 20C 2.9 Explosive limits vol% in air 1.1-7.1

Relative vapour density air 3.2 Octanollwater partition coefficient as log Pow

2.69

ENVIRONMENTAL

DATA

NOTES

Depending on the degree of exposure periodic medical examination is indicated

Transport Emergency Card TEC R-3

NFPACodeH2

http//www2 .hazard.com/msds/mf/cards/file/0078.htrril 9/27/2007

KEY-HEC-1-001044 KEY-EPA-001036

KEY-H EC-1 -001515
International Chemical Safety Cards WHO/IPCS/ILO Page of

ADDITIONAL INFORMATION

II

ICSC 0078 TOLUENi

IPCS.CEC 1993

Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible

IMPORTANT for the use which might be made of this information This card contains the collective views of the

LEGAL IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included

NOTICE in national legislation on the subject The user should verily compliance of the cards with the

relevant legislation in the country of use

http//www2.hazard.comjmsds/mf/cards/file/0078ht1111 9/27/2007

KEY-HEC-1-001045 KEY-EPA-001037

KEY-H EC-1 -001516
2/

-27OO 357PM

Material Safety Data Sheet

NVPA Pr.tectvrCIotbIn DOT

coeunonrrrade RJAS cr Not applicable

Syeony.is Not available

ISCA TSCA 8b Nventory All products listed

Clienilcal name Cationic Potyacrylamide emulsion

Chemical formula Not appicable

CAS Moct3.iVe

UDO1Pd

Chemical family Aliphatic amide Alhatic

Supplier

Molecular weight Not applicable

5T7IO Manufacturer Cheniplex L.C

P.O Box 1071

Material uses Not available 509 CR 137

Snyder Tx 79550

915 573-7298

stionmrpiist4jdMesw1el

Eye contact Check for and remove any contact lenses Do not use an eye ointment Seek medical attention Flush with plenty of

water for at least 15 minutes occasionally lifting the upper and lower eyelds

Side contact After contact with skin wash rnmedately with plenty of water Gently and thoroufly wash the contiinated skin with

runrng waterand non-abrasive Be particularly careful to clean folds crevices creases and groin Cover The

initated skin with an emoflient If irritation persists seek medcal attention Wash contaminated clothing before reusing

Hazardous skin contact Wash with disinfectant soap and cover the contaminated skin with an anti-bacterial cream Seek mwnedlate medical

attention

Slight inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention

Hazardous inhalation Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar lie bell or waistband If

breathing is cfrfticuit administer oxygen If the victim is not breathing perform mouth-to-mouth resuscitation Seek

medical attention

Slight ingestion Do not induce vomiting Examine the lips and mouth to ascertain whether the tissues are damaged possible indication

that the toxic material was ingested the absence of such signs however is not conclusive Loosen tight clothing such as

coar tie belt or waistband If the victim is not breathing perform mouth-to-mouth resuscitation Seek immediate

medical attention

Hazardous Ingestion Not available

KEY-HEC-1-001046 KEY-EPA-001038

KEY-H EC-1 -001565
357PM 3/

ithUtthM

Narie CAS by Weight TLV/PEL LC5ILDs

Acrylamide 79-06-1 Trade secret liNk 0.01 ppm ORAL LD5O Ac4e 124

mglkg Rat DERMAL

LDSO Acute 400 mg/kg

Physical state OJId UC4UId Oior Slit

appearance

pH 1% sohi/ssatcr Basis TaSte NOt 2oiabis

Odor threshold Not avalabte Color Whits Off-wtite

Volatility Not avalabie

Melting poin Not avathe

Boiling point The lowest known value is 360C 680F MiieraI oil

Specific gravity Water

Vapor density Not available

Vapor pressure Not available

Evaporation rate Not available

Viscosity Not available

LogiL The product is much more soluble in oiL

loiddly surface active ant Not available

Critical temperature Not available

Instability temperature Not available

Conditions of instability Not available

Dispersion properties Is not dispersed in cold water hot water

See sokibirity in methanol diethyl ether n-octanol

SoubilJty Easily soluble ii n-octanol

Soluble in methanol diethyl ether

InsoWe in cold water hot water

KEY-HEC-1-001047 KEY-EPA-001039

KEY-H EC-1 -001566
4/ 27oo 357PM

Tfe peodut Ii May be combustible at high temperature

AitO4gfl1thfl tetzre Not adable

Flre egrsdadoe products These products are carbon oxides CO C02 nthogen oxides NO N02...

Flash points The lowest known value is CLOSED CUP 2.29C 444.2F OPEN CUP 193C 379.4F Cleveland Mineral

Flajisnable limits Not avadable

Fire extinguishing SMALL FIRE Use DRY themical powder

procedures LARGE FIRE Use water spray fog or foam Do not use water jet

1.nbWty Highly flaniiithle in presence of oxizing materials

Remark

Not available

Risks of explosion Risks of explosion of the product in presence of mechanical impact Not available

Risks of explosion of the product wi presence of static chcharge Not avadable

Remark

Not available

.1

Stability The product is stable

Bawdous decomp products Not available

Degradabllity Not avaiable

Products of degradation Possy hazardous short term degradation products are not likely However long term degradation products may arise

The products of degradation are less toxic than the product itself

Remark

Not avaiable

Corrosivity Non-corrosive in presence of glass

Remark

Not avatable

Reactivity Reactive with oxidizing agents acids alkalis moisture

Remark

May poiTienze on exposure to light The solid is stable at room temperature but may polymerize violently on rnefting

Acrylatvide

KEY-HEC-1-001048 KEY-EPA-001040

KEY-H EC-1 -001567
-VJi-27OO 357PM 5/

Routes eentry Dermal contact Eye contact Inhalation Ingestion

vs IWb OJI pp

Toxicity for anmials Acute oral toxicity LD5O 124 mglkg Acrylanide

Acute dermal toxicity LD5O 400 mglkg Rat Acrylamide

Remark

Not available

Chronic elTecta on CARCINOGENIC EFFECTS Classified A2 Suspected for human by ACGIH Acrylamide

hiasans

Remark

Not available

Acute effects on hmnans Very hazardous ui case of ingestion

Hazardous in case of skin contact irritant permeator of inhalation

Remark

Material is corrosive to the mucous membranes Acrylanide

Waite disposal Whatever cannot be saved for recovery or recycling shoald be managed in an approriate and approved waste disposal

acWty Processing use or contamination of this product may change the waste management options State and local

disposal regulations may differ from federal disposal regi4ations Dispose of container and unused contents

accordance with federal state and local requiements

Not avaable

Storage Keep container dry Keep in cool place Ground all equçment containing material Keep container tightly closed Keep

in cool well-ventilated place Highly toxic or infectious materials should be stored in separate locked safety storage

cabinet or room

Precautions Keep locked up Keep away from heat Keep away from sources of ignition Empty contariers pose fire risk evaporate

the residue under fume hood Ground all equipment containing material Do not ingest Do not breathe gas/fumes/

vapourspray Wear suitable protective clothing In case of insufficient ventllation wear suile respiratory equipment if

Egested seek medical advice mmediately and show the container or the label Avoid contact with skii and eyes Keep

away from incompalibies such as oxidizing agents acids alkalis moisture

Small spin and leak Absorb with an inert material and put the spilled material in an appropriate waste disposal If necessary Neutralize the

residue with dIlute solution of acetic acid

Large sp1 aiui leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Neutralize the residue with

dilute solution of acetic acid Be careful that the product is not present at concentration level above TL.V Check TLV

on the MSDS and with local authorities

Protective Clothing Splash goges Fill suit Vapor respirator Boots Gloves self contained breathing apparatus should be used to avoid

inhalation of the product Suggested protective clothing might not be sufficient consuL specialist BEFORE handling thts

producl

KEY-HEC-1-001049 KEY-EPA-001041

KEY-H EC-1 -001568
00 000P LI 1.12700 357PM page

DOT Not DOT contrclled material United States

Not DOT regulated

Rniark

Not avaable

Mai4tiee Not available

transportedon

Remark

Not avaable

RCS No an HCSconfroled material USA

Remark

Not available

NFPA wlAJy

SPECIFiC HAZARD

Federal and No products were found

State

Regulations

-.

References Not available

Validated by Chemplex on 6130/99 Verified by ChempleL

PrInted 6130/99

Emergency Response 800 633-8253

HEALTH L_ REACTMTY

Splash goggles Lati coat Vapor respirater Be sure to use an pcoved/cectifled respirator or equivalent Gloves

4-

msbq wI fr H.s as iqm _d 5Id as Ailt kÆ..i4s ..d av daha Wi

amvv as esSa

KEY-HEC-1-001050 KEY-EPA-001042

KEY-H EC-1 -001569
MATERIAL SAFETY DATA SHEET

Plexslick 961

NFPA WF1

Product And Company Identification

SuDDher Manufacturer

Chemplex LC Chemplax IC

P.O Box 1071 P.O Box 1071

506 CR 137 506 CR 137

Snyder TX 79550 UnIted States Snyder TX 79550 United States

Telephone Number 325 573-7298 Telephone Number 325 573-7298

FAX Number 325 573-3340 FAX Number 325 573-3340

SuDolier Emeroencv Contacts Phone Number Manufacturer Emeroencv Contacts Phone Number

800 633-8253 800 633-8253

Issue Date 01130/2003

Product Name Plexslick 961

Chemical Name Anionic Potyacrytarnide emulsion

CAS N.snber Not Established

Chemical Family Aliphatic anide

MSDS Number 211

Product/Material Uses

Friction reducer for water

Composition/lnformnation On Ingredients

Ingrecknt CAS Percent Of

Name Nwnber Total Weight

PETROLEUM DISTILLATE 64742-47-8 20-30

Hazards Identification

Primary Routess Of Entry

Dermal contact Eye contact Ingestion Inhalation

Ingestion Hazards

Hazardous in case at ingesbon

Inhalation Hazards

Hazardous ii case of skin contact irritant

First Aid Measures

Check for and remove any contact lenses Do not use an eye ointment Seek medical attention Flush with

plenty of water for at least 15 minutes occasionally lifting the upper lower eyelids

Paoe f4

KEY-HEC-1-001051 KEY-EPA-001043

KEY-H EC-1 -001570
MATERIAL SAFETY DATA SHEET

Plexslick 961

First Aid Measures Continued

After contact with skin wash immediately with plenty of water Gently and thoroughly wash the contaminated

skin with running water and non-abrasive soap Be particularly careful to clean folds crevices creases and

groin Cold water may be used Cover the irritated skin with an emollient If irritation persists seek medical

attention Wash contaminated clothing before reusing

HAZARD SKIN CONTACT Wash with disinfectant soap and cover the contaminated sldn with an

anti-bacterial cream Seek immediate medical attention

Inciestion

DO NOT induce vomiting Examine the 1ips and mouth to ascertain whether the tissues are damaged possible

indication that the toxic matenal was ingested the absence of such signs however is not conclusive Loosen

light clothing such as coflar tie belt or waistband It the vichm is not breathing perform mouth-to-moult

resusictahon Seek immediate medical attention

Inhalation

Slight Inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention

Hazardous Inhalation Evacuate the victim to safe area as soon as possible Loosen tight clothing such as

collar tie belt or waist band If breathing is diflicult administer oxen If the victim is not breathing perform

mouth-to-mouth resuscitation Seek medical attention

Fire Fighting Measures

Flash Point 200

Fire And Explosion Hazards

Flammable in presence of oxidizing materials

Fire Fighting Instructions

SMALL FIRE Use DRY chemicals powder

LARGE FIRE Use water spray foam or tog Do not use water jet Product will become very slippery when

contacted with water

Accidental Release Measures

Small Spill and Leak Absorb with an inert DRY material and place in an appropriate waste disposal container Water

will cause residue to become etremey slippery

Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Be

careful that the product is not present at concentration level above TLV Check TLV on the MSDS and with local

authorities

Handling And Storage

Handii Md Stoisqe Pietautions

Keep container dry keep in cool place Ground all equipment containing material Keep container tightly

closed Keep at above 35F

Keep locked up Keep away from heat Keep away from sources of rgnion Enipy containers pose fire risk

evaporate the residue under fume hood Ground all equipment containing material Do not ingest Do not

breathe gas/fumes/vapor/spray Wear suitable protective clothing in case of insufficient ventilation wear

sutabie iespaoiy eqthpment fl vgested seec medical advice immec.ately and shriw the container OT the

label Avoid contact with skin and eyes Keep away from incompathles such as oxidizing agents and moisture

Pane nf

KEY-HEC-1-001052 KEY-EPA-001044

KEY-H EC-1 -001571
MATERIAL SAFETY DATA

Plexslick 961

SHEET

Protective Ciothino lPictoorams na

Exposure Controls/Personal Protection

Eye/Face Protection

Spash gogges

Skin Protection

Apron/Lab coat gloves

Respiratory Protection

Vapor respirator

Be sure to use an approvedicered respirator or eqwvaent

Ingredients Exposure Limits

PETROLEUM DISTILLATE

ACGIH TLV-STEL 500 ppm Notice of Intended Change

ACGIH TLV-STEL 400 ppm Proposed

ACGU-I TLV-TWA 400 ppm Notice of Intended Changel

ACGIH TLV-TWA 200 ppm Proposed

OSHA PEL-TWA 400 ppm

Physical And Chemical Properties

Appearance

Tcavect vthit

Odor

Hydrocarbon oil

Chemical Type Mixture

Boiling Point 105

Specific Grant .04 tec

pH Factor Neutral

10 Stability And Reactivity

Stability This product is stable

Conditions To Avoid Stability

Reactive with oxidizing agents moisture

11 Toxicological Information

Skin Effects

Hazardous in case of skin contact irritant

Acute Oral Effects

Hazardous in case of ingestion

Jnaredientls Careinoaenicity

PETROLEUM DISTILLATE

Listed In The LRC Monographs

Paae3nfd

KEY-HEC-1-001053 KEY-EPA-001045

KEY-H EC-1 -001572
MATERIAL SAFETY DATA SHEET

Plexslick 961

12 Ecological Information

No Data Available..

13 Dbsposa% Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal

facility Processing use or contamination of this product may change the waste management options State and local

disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in

accordance with federal state and local requirements

14 Transport Information

Prooer ShiDnina Name

Not DOT Regulated

15 Regulatory Information

U.S Reaulatorv Information

Not DOT Regulated

Inaredientls State Reaulaf ions

PETROLEUM DISTILLATE

New Jersey Workplace Hazard

New Jersey Specia Hazard

Pennsylvania Workplace Hazard

Massachusetts Hazardous Substance

New York City I-lazardos Substance

16 Other Information

NFPA Rating

Health

Fire

Reactivtty

Revision/Preiarer Information

MSDS Preparer Dr Edward Vinson

MSDS Preparer Phone Number 915-573-7298

This MSDS Supercedes Previous MSDS Dated 07/15/2002

Disclaimer

Although reasonable care has been taken in the preparation of this document we extend no warranties and make

no rep esentati as to the accuracy or corncdeteness of the IntQftnaOn cootas1 thereu aM assuno

responsibility regarding the suitablility of this information for the users intended purposes or for the

consequences of its use Each individual should make determination as to the suitability of the information for

their pallcular purposess

Chemplex L.C

Paoa nf

KEY-HEC-1-001054 KEY-EPA-001046

KEY-H EC-1 -001573
PAGE of

MATERIAL SAFETY DATA SHEET 06/02I20q PRINT DATE 06/14/2005

IDENTIFICATION OF THE PRODUCT AND THE COMPANY

WFR-6

Supplier PEACH CREEK

Box 30341

Edmond Oklahoma 73003

INFORMATION PHONE 405-850-2520 EMERGENCY PHONE 800-535-5053

_2 COMPOSITION/INFORMATION ON INGREDIENTS

Identification of the preparation Cationic water-soluble polymer in emulsion

HAZARDS IDENTIFICATION

Aqueous solutions or powders that become wet render surfaces extremely slippery

FIRST AID MEASURES

Inhalation Move to fresh air

Skin contact Wash off immediately with soap and plenty of water In case of persistent skin imtation consult

physician

Eye contact Rinse thoroughly with plenty of water also under the eyelids In case of persistent eye irritation

consult physician

Ingestion The product is not considered toxic based on studies on laboratory animals

MEASURES

Suitable extinguishing media Water water spray foam carbon dioxide C02 dry powder

Special fire-fighting precautions Spills produce extremely slippery surfaces

Protective equipment for firefighters No special protective equipment required

ACCIDENTAL RELEASE MEASURES

Personal precautions

Environmental precautions

No special precautions required

Do not contaminate water

KEY-HEC-1-001055 KEY-EPA-001047

KEY-H EC-1 -001584
viscous liquid

millcy

aliphatic

g/1 for product series See Technical Bulletin for specific value

Does not flash

Does not ignite

0.13 20C

See Technical Bulletin

See Technical Bulletin

WFR-6 PAGE of

REVISION DATE 06/02/2005

PRINT DATE 06114/2005

Methods for cleaning up Do not flush with water Dam up Soak up with inert absorbent material If liquid

has been spilled in large quantities clean up promptly by scoop or vacuum Keep in

suitable and closed containers for disposal After cleaning flush away traces with

water

HANDLING AND STORAGE

Handling Avoid contact with skin and eyes When preparing the working solution ensure there is adequate

ventilation When using do not smoke

Storage Keep in dry cool place 30C Keep away from heat and sources of ignition Freezing will

affect the physical condition and may damage the material

_8 EXPOSURE CONTROLS PERSONAL PROTECTION

Engineering controls Use local exhaust if misting occurs Natural ventilation is adequate in absence of mists

Personal protection equipment

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment

Hand protection Rubber gloves

Eye protection Safety glasses with side-shields Do not wear contact lenses

Skin protection Chemical resistant apron or protective suit if splashing or contact with solution is likely

Hygiene measures Wash hands before breaks and at the end of workday Handle in accordance with

good industrial hygiene and safety practice

PHYSICAL AND CHEMICAL PROPERTIES

Form

Color

Odor

pH

Flash point

Autoignition temperature

Vapour pressure mm Hg

Bulk density

Water solubility

KEY-HEC-1-001056 KEY-EPA-001048

KEY-H EC-1 -001585
PAGE 3of5 WFR6 REVISION DATE 06/02/2005

PRINT DATE 06/14/2005

Viscosity mPa See Technical Bulletin

10 STABILITY AND REACTIVITY

Stability Product is stable No hazardous polymerization will occur.

Oxidizing agents may cause exothermic reactions

Hazardous decomposition Thermal decomposition may produce hydrogen chloride gas nitrogen oxides NOx

products carbon oxides

11 TOXICOLOGICAL INFORMATION

cute toxicity

Oral LD5OIoral/rat 5000 mg/kg

Dermal The results of testing on rabbits showed this material to be non-toxic even at high dose levels

Inhalation The product is not expected to be toxic by inhalation

Irritation

Skin May cause skin irritation with suseptible persons

Eyes May cause eye irritation with susceptible persons

Sensitization The results of testing on guinea pigs showed this material to he non-sensitizing

Chronic toxicity two-year feeding study on rats did not reveal adverse health effects one-year feeding

study on dogs did not reveal adverse health effects Prolonged skin contact may defat the skin

and produce dermatitis

ECOLOGICAL INFORMATION

Eco toxicity

The effects of this product on aquatic organisms are rapidly and significantly mitigated by the presence of dissolved

organic carbon in the aquatic environment

Fish LC5O/Danio rerio/96 hr 10 100 mg/L OECD 203Based on the toxicity of the

components using the Conventional Method

Algae Algal inhibition tests are not appropriate The flocculating characteristics of the product

interfere directly in the test medium preventing homogenous distribution which invalidates the

test

KEY-HEC-1-001057 KEY-EPA-001049

KEY-H EC-1 -001586
PAGE 4of5

WFR-6 REVISION DATE 06/0212005

PRINT DATE 06/i 4I299J

Daphnia EC5O/Daplmia magna/48 hi 50 mg/L OECD 202Based on the toxicity of the components

using the Conventional Method

Environmental fate

The product is rapidly eliminated from the aquatic medium through irreversible adsorption onto suspended matter and

dissolved organics

Bioaccumulation loes not bioaccurnulate

Persistence degradability Not readily biodegradable

13 DISPOSAL CONSIDERATIONS

Waste from residues unused In accordance with federal state and local regulations

products

Contaminated packaging Rinse empty containers with water and use the rinse water to prepare the

working solution Can be laridfihled or incinerated when in compliance with local

regulations

L14 TRANSPORT IN FORMATION I_____________________________

Not regulated by DOT

15 REGULATORY INFORMATION

All components of this product are on the TSCA and DSL inventories

RCRA status Not hazardous waste

Hazardous waste number Not applicable

Reportable quantity 40 CFR 302 Not applicable

Threshold planning quantity 40 CFR 355 Not applicable

California Proposition 65 information The following statement is made in order to comply with the

California Safe Drinking Water and Toxic Enforcement Act of

1986 Thi product contains chemicals known to the State of

California to cause cancer residual Acrylamide

KEY-HEC-1-001058 KEY-EPA-001050

KEY-H EC-1 -001587
WFR-6 IPAGE 5of5J

REVISION DATE 06102120051

PRINT DATE 06/1412005

HMIS NFPA Ratings HMIS NFPA

LHealth LIP

Flammability jj

Reactivity

16 OTHER INFORMATION

Person to contact Regulatory Affairs Manager

The information provided in this Safety Data Sheet is correct to the best of our knowledge information and belief at the date of its publication

The information given is designed only as guidance for safe handling use processing storage transportation disposal and release and is not to

he considered warranty or quality specification The information relates only to the specific material designated and may not he valid for such

niateriiI used iiicombination with any other materials or in any process unless specified in the text

KEY-HEC-1-001059 KEY-EPA-001051

KEY-H EC-1 -001588
MATERIAL SAFETY DATA SHEET

FR

9ATE PREEDO9.02-0S

MSDS No WFR-7

WFR-7

I.PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME WFR-7

CHEMICAL FAMILY Anionic Polyacrylamide Copolymer in Water-in-Oil Emulsion

MOLECULAR FORMULA Mixture

MANUFACTURER Information

Key Energy Pressure Pumping Services

303W Wall Suite 1200

Midland TX 79701

24 HR EMERGENCY TELEPHONE NUMBERS

PERS US Transportation 800 633-8253

Emergency Phone 432-570-4899

Emergency Phone 432 570-4899

COMPOSITION INFORMATION ON INGREDIENTS

Chemical Name Wt.% CAS

Petroleum Distillate 64742-47-8

Anionic Polyacrylamide Copolymer

OSHA HAZARDOUS COMPONENTS 29 CFR 1910.1200

EXPOSURE LIMITS

Chemical Name OSHA PEL ACCIH TLV Supplier

Petroleum Distillate 165 ppm

HAZARDS IDENTIFICATION

EMERGENCY OVERVtEW

PHYSICAL APPEARANCE Opaque off-white emulsion

IMMEDIATE CONCERNS WARNING Causes eye irritation Mist may be harmthl if inhaled

POTENTIAL HEALTH EFFECTS

EYES Irritating and may iniure eye tissue if not removed promptly

SKIN Low order of toxicity Prolonged or repeated contact may irritate and cause dermatitis

INGESTION Low order of toxicity May result in gastrointestinal irritation nausea and diarrhea Small amounts of

the liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchiopneumonm or

pulmonary edema

INHALATiON Irritating to eyes and respiratory tract in high concentrations Repeated and prolonged overexposure

to oil mists may result in droplet deposition oil granuloma formation inflammation and increased incidence of

infection

CANCER STATEMENT This product or any componeni at concentration of 0.1% or greater is not listed by the

NTP IARC OSHA or EPA as carcinogen

FIRST AU MEASURES

EYES Immediately flush eyes with large amounts of water for at least 15 minutes Get immediate medical attention

SKIN Wash with large amounts of water use soap if available Remove grossly contaminated clothing including

shoes and launder before reuse If irritation persists seek medical attention

INGESTION ifswallowed DO NOT induce vomiting Keep at rest Get prompt medical attention If spontaneous

vomiting occurs keep head below hips to prevent aspiration and monitor for breathing difficulty

INHALATION In ease of adverse exposure to vapors and/or aerosols immediately remove the affected victim from

exposure and get immediate medical attention If breathing is difficult give oxygen If breathing stops give artificial

respiration

FHE FIGHTIN MFASURES

KEY-HEC-1-001060 KEY-EPA-001052

KEY-H EC-1 -001589
FLASHIPOINT AND METHOD 200FPensky-Maitens CC

FLAMMABLE LIMITS 13 to 8.1% Petroleum Distillate

AUTOIGNITION TEMPERATURE Not Available

hAZARDOUS COMBUSTION PRODUCTS No unusual

FIRE FIGHTING PROCEDURES Use water to cool fire-exposed surfaces and to protect personnel Isolate fuel

supply from fire Use foam dry chemical or water spray to extinguish fire

FIRE FIGHTING EQUiPMENT As in any fire wear self-contained breathing apparatus pressure-demand

MS1-IA/NIOSFT approved or equivalent and full protective gear

ACCIDENTAL RELEASE MEASURES

ENVIRONMENTAL PRECAUTIONS

WA1ER SPILL Prevent additional discharge of material if possible to do so without hazard Remove from surface

by skimming or with suitable adsorbents Consult an expert on disposal of recovered material and ensure conformity to

all federal state and local disposal regulations see Section 1.5 Clean Water Act

LAND SPILL Prevent additional discharge of material if possible to do so without hazard For small spills

implement cleanup procedures for large spills implement cleanup procedures and if in public area advise authorities

GENERAL PROCEDURES Spilled product should be scooped up as much as possible and the remaining thin layer

absorbed with solid material such as sweeping compound Washing the area with atcr should only be attempted

after most of the polymer has been removed

RELEASE NOTES Recycle or dispose of recovered material in accordance with all federal state and local

regulations

COMMENTS Spilled material is slippery Contact with water may form highly viscous and stringy material which

is extremely slippery difficult to clean up and can clog small drains

HANDLING AND STORAGE

GENERAL PROCEDURES Keep container closed Both open and handle containers with care Store in cool vell

ventilated place away from incompatible materials 1o NOT pressurize cut heat or weld containers Empty product

containers may contain product residue Do NOT reuse empty containers without commercial cleaning or

reconditioning

HANDLING Mix will before using Upon standing product may stratifr as noted by clear upper layer of oil Mild

agitation will restore uniformity

STORAGE Do not usc aluminum copper or mild steel tank pumps or piping with this product Store in glass

stainless steel plastic or epoxy lined containers

STORAGE TEMPERATURE Keep from freezing

STORAGE PRESSURE Atmospheric

EXPOSURE CONTROLS PERSONAL PROTECTION

ENGINEERING CONTROLS Ventilation should be provided to control worker exposures and prevent health risk

and as necessary to reduce prevent and control aerosol gener.stion

PERSONAL PROTECTION

EYES AND FACE Safety glasses with side shields

SKIN Where contact may occur wear chemical resistant gloves and long sleeves

RESPIRATORY Where concentrations in air may exceed the limits given in this section or Section and

engineering work practice or other means of exposure reduction are not adequate NIOSFI/MSUA approved respirators

may be necessary to prevent overexposure by inhalation

OTHER USE PRECAUTIONS In Ihe area where this product is used an eyewash station is necessary and safety

shower is recommended

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid

ODOR Slight hydrocarbon odor

VAPOR PRESSURE mm Hg at 100F

VAPOR DENSiTY Air

BOILING POINT 212F to 415F

KEY-HEC-1-001061 KEY-EPA-001053

KEY-H EC-1 -001590
FREEZING POINT 10F to 32F

EVAPORATION RATE n-Butyl Acetate1

SPECIFIC GRAVITY 1.04 to 1.07 at 77F

VISCOSITY 400 to l200cP at 80F Brookfield RVT 3/50

COMMENTS

WATER SOLUBILITY Soluble with vigorous agitation Contact with water at product content greater then

approximately 2% without vigorous agitation results in highly viscous and stringy material which is cxtrcmcly

slippery difficult to clean up and can clog small drains

10 STABILITY AND REACTWITY

STABLE YES

HAZARDOUS POLYMERIZATION NO

CONDITIONS TO AVOID Heat over 50 degrees 122 and moisture/water

HAZARDOUS DECOMPOSITION None

INCOMPATIBLE MATERIALS Strong oxidizing agents

11 TOXICOLOCICAL D4FORMATION

TARGET ORGANS At high oral doses the petroleum distillate used in this product caused reversible damage to the

user and kidney male only of rats These effects are not relevant to humans at occupational levels of exposure

12 ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION No information available

13 DISPOSAL CONSIDERATIONS

EMPTY CONTAINER Empty containers retain product residue liquid and/or vapor Although the residue is

low fire hazard flash point 200 it can burn upon heating to temperatures at or above the flashpoint and can be

dangerous Therefore 10 NOT PRESSURIZE CUT WELD BRAZE SOLIER DRILL GRIN OR EXPOSE

SUCH CONTAINERS TO HEAT FLAME SPARKS STATIC ELECTRICITY OR OTHER SOURCES OF

IGNITION THEY MAY EXPLODF AND CAUSE INJURY OR lEATH Empty drums should be completely

drained properly bunged and promptly returned to drum reconditioner or properly disposed of

GENERAL COMMENTS Ensure compliance with local slate and Federal regulations in disposing of this container

residual contents or rinsing

14 TRANSPORT INFORMATION

DOT DEPARTMENT OF TRANSPORTATION

PROPER SHIPPING NAME Not Regulated

15 REGULATORY INFORMATION

UNITED STATES

SARA TITLE III SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT

FIRE NO PRESSURE GENERATING NO REACTIVI1Y NO ACUTE YES CHRONIC NO

311/312 1-LZARD CATEGORIES Acute l-Iealth

313 REPORTABLE INGREDIENTS This product does not contain Section 313 Reportable Ingredients

CERCLA COMPREHENSWE RESPONSE COMPENSATION AND LIABILITY ACT

CERCLA REGULATORY If this product is accidentally spilled it is not subject to any special reporting under the

requirements of the Comprehensive Environmental Response Compensation and Liability Act CERCLA We

recommend you contact local authorities to determine if there may be other local reporting requirements

TSCA TOXIC SUBSTANCE CONTROL ACT

TSCA STATUS All components of this product are listed on the TSCA Inventory or are exempt from TSCA

Inventory requirements

RCRA STATUS Discarded product as sold would not be considered RCRA Hazardous Waste

KEY-HEC-1-001062 KEY-EPA-001054

KEY-H EC-1 -001591
CLEAN WATER ACT This product is classified as an oil under Section 311 of the Clean Water Act 40 CFR 110

and the Oil Pollution Act of 1990 Discharge or spills which produce visible sheen on either surface water or in

waterways/sewers which lead to surface water must be reported to the National Response Center at 800-424-8802

16 OTHER INFORMATION

APPROVAL DATE 04-13-05

PREPARED BY Ed Vinson

IIMIS CODES

FLAMMABILITY HEALTH PHYSiCAL HAZARD

LMIS RATINGS NOTES This information is for people trained in Key the National Paint Coatings Associations

Severe NPCM Hazardous Materials Identification Serious System IIMIS Moderate Slight

Minimal

MANUFACTURER DISCLAIMER NOTICE We believe that the information contained on this Material Safety

Data Sheet is accurate The suggested procedures are based on experience as of the date of publication They are not

necessarily either all-inclusive or fully adequate in every circumstance Also these suggestions should not be confused

with or followed in violation ol applicable laws regulation rules or insurance requirements NO WARRANTY IS

MAIE EXPRESSED OR IMPLIED OF MERCHANTABILITY FITNESS FOR PARTICULAR PURPOSE OR

OTHERWISE

KEY-HEC-1-001063 KEY-EPA-001055

KEY-H EC-1 -001592
Material Safety Data Sheet

WFR-9

Chemplex Ltd DATE PREPARED 02/04/2009

Box 1071 REVISION DATE 02/04/2009

/C Snyder TX 79550 EMERGENCY NUMBER.. 800-633-8253

325 573-7298

SECTION IDENTIFICATION

PRODUCT NAME WFR -9

CHEMICAL FAMILY Polyacrylamides

CAS NUMBER Mixture

PRODUCT USE Friction reducer for water

SECTION II- HAZARDOUS INGREDIENTS

HAZ INGREDIENT PERCENT CAS NUMBER PEL

Petroleum Distillate 20-30% 64742-47-8 N/A

SECTION III PHYSICAL DATA

APPEARANCE Opaque off-white emulsion

ODOR Slight hydrocarbon odor

BOIUNG POINTS 212F

FLASHPOINT 200F

VAPOR DENSITY AIR1 Air

VAPOR PRESSURE mm Hg at 100F

SPECIFIC GRAViTY wATER1 0.99

pH 1% SOLN/WATER Near neutral

SOLUBILITY Complete limited by viscosity

DENSITY 8.67 lb/gal

SECTION IV FIRE AND EXPLOSION DATA

FLASH POINT 200F

FLAMMABLE HAZARDS Will burn in surrounding fire

FIRE FIGHTING PROCEDURES SMALL Use dry chemical powder

LARGE FIRE Use water spray fog or foam DO NOT

use water jet Product will become very slippery when

contacted with water

Page of4

KEY-HEC-1-000543

KEY-H EC-1 -001597 KEY-EPA-000543
Material Safety Data Sheet

WFR-9

SECTION REACTIVITY DATA

STABILITY This product is stable

REAC11VITY Reacts with strong oxidizing agents

SECTION VI HEALTH HAZARD DATA

ROUTE OF ENTRY Skin contact eye contact

CHRONIC EFFECTS ON HUMANS .. None known

SECTION VI FIRST AID

INHALATION

EYE CONTACT

SKIN CONTACT

SECTION VII SPILL STORAGE AND DISPOSAL DATA

SPILL SMALL SPILL Absorb with an inert material and put

the spilled material in an appropriate waste disposal

Spills of this product are very slippery particularly if

Page of

SLIGHT INHALATION Allow the victim to rest in well

ventilated area Seek immediate medical attention

HAZARD INHALATION Evacuate the victim to safe

area as soon as possible Loosen tight clothing such as

collar tie belt or waist band If breathing is difficult

administer oxygen If the victim is not breathing perform

mouth-to-mouth resuscitation Seek medical attention

INGESTION Only induce vomiting at the instruction of physician

Never give anything by mouth to an unconscious

person Examine the lips and mouth to ascertain

whether the tissues are damaged possible indication

that the toxic material was ingested the absence of such

signs however is not conclusive Loosen tight clothing

such as collar tie belt or waistband If the victim is

not breathing perform mouth-to-mouth resuscitation

Seek immediate medical attention

Check for and remove any contact lenses Do not use

an eye ointment Seek medical attention Flush with

plenty of water for at least 15 minutes occasionally

lifting the upper and lower eyelids

After contact with skin wash immediately with plenty of

water Gently and thoroughly wash the contaminated

skin with running water and non-abrasive soap Be

particularly careful to clean folds crevices and groin

Cold water may be used Cover the irritated skin with an

emollient If irritation persists seek medical attention

Wash contaminated clothing before reusing

KEY-HEC-1-000544

KEY-H EC-1 -001598 KEY-EPA-000544
Material Safety Data Sheet

WFR-9

contacted with water

LARGE SPILL Absorb with an inert material and put

the spilled material in an appropriate waste disposal

WASTE DISPOSAL Whatever cannot be saved for recovery or recycling

should be managed in an appropriate and approved

waste disposal facility Processing use or

contamination of this product may change the waste

management options State and local disposal

regulations may differ from federal disposal regulations

Dispose of container and unused contents in accordance

with federal state and local requirements

HANDLING Keep away from heat Keep away from sources of

ignition Empty containers pose fire risk evaporate the

residue under fume hood Ground all equipment

containing material Do not breathe gas fumes vapor

or spray If you feel unwell seek medical attention and

show the label when possible Avoid contact with skin

and eyes Keep away from incompatibles such as

oxidizing agents and moisture

STORAGE Keep container dry Keep in cool place Ground all

equipment containing material Keep container tightly

closed Keep above 35F

SECTION VIII PROTECTIVE CLOTHING

RESPIRATORY PROTECTION Use MSHA/NIOSH approved respirator or equivalent

PROTECTIVE CLOTHING/EQUIP Apron/lab coat safety glasses gloves

SECTION IX TRANSPORTATION DATA

PROPER SHIPPING NAME Not DOT Regulated

HAZARD CLASS N/A

UN NUMBER N/A

PACKAGING GROUP N/A

RQ N/A

DOT SHIPPING Not DOT Regulated

SECTION OTHER REGULATORY INFORMATION

TSCA STATUS All components of this product are listed on the TSCA

inventory

NFPA HEALTH

NFPA FLAMMABILiTY

NFPA REACTIVflY

Page of4

KEY-HEC-1-000545

KEY-H EC-1 -001599 KEY-EPA-000545
Material Safety Data Sheet

WFR-9

SECTION XI ADDITIONAL INFORMATION

PREPARED BY Edward Vinson

EMERGENCY RESPONSE NUMBER 800-633-8253

Page of

KEY-HEC-1-000546

KEY-H EC-1 -001600 KEY-EPA-000546
Economy 

Polymers & Chemicals

P.O. Box 450246

Houston, TX 77245-0246

USA Toll free: (800) 231-2066

Phone: (713) 723-8416

Fax: (713) 723-1845 

URL: www.EconomyPolymers.com 

E-mail: economy@economypolymers.com

M A T E R I A L S A F E T Y D A T A S H E E T 

PRODUCT NAME: WGA-1 

REVISION DATE: May 21, 2007 

For Chemical Emergency (Spill, Leak, Fire, Exposure or Accident) 

CALL CHEMTREC Day or Night 800-424-9300 

For International, Call 703-527-3887 (Collect Calls Accepted) 

** FOR INDUSTRIAL USE ONLY **

Section I - Product Information

Chemical Name: GUAR GUM 

Formula: NA CAS Number: 9000-30-0 

DOT Hazard Class: Not Regulated 

Reportable Quantity: None 

Section II – Composition, Information on Ingredients

 Material CAS #: Percent 

Guar Gum 9000-30-0 >90 

 

Section III - Health Hazard Data

Signs & Systems of Overexposure in the Workplace 

Eyes: May cause irritation.Skin: May cause mild irritation. 

Inhalation: Inhaling dust may cause respiratory irritation. Ingestion: None Known. 

MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE: 

None Known 

PRIMARY ROUTE OF ENTRY: Following standard industrial hygiene and recommended procedures, 

entry of the compound into the body is not expected. 

CANCER INFORMATION: Not listed as a carcinogen by NTP (National Toxicology Program); not 

regulated as a carcinogen by OSHA (Occupational Safety & Health Administration); not evaluated by 

IARC (International Agency for Research on Cancer). 

Toxic Data 

Eye contact: A PRIMARY ROUTE OF ENTRY, no data is available 

Skin Contact: A PRIMARY ROUTE OF ENTRY, no data available 

Inhalation: No data is available 

Ingestion: No data is available 

Special Precautions: Individuals with skin or respiratory diseases should not be exposed to this product 

unless properly protected. 

Section IV- First Aid Measures

Threshold Limit Value (TLV) for Product: None Established. 

Does product contain any OSHA, NTP or IARC Carcinogens? No 

First Aid 

KEY-HEC-1-001064 KEY-EPA-001056
Economy 

Polymers & Chemicals

P.O. Box 450246

Houston, TX 77245-0246

USA Toll free: (800) 231-2066

Phone: (713) 723-8416

Fax: (713) 723-1845 

URL: www.EconomyPolymers.com 

E-mail: economy@economypolymers.com

Eyes: Flush thoroughly with running water at least 15 minutes. Get medical attention if irritation persists. 

Skin: Remove contaminated clothing and wash contact area with soap and water for 15 minutes. 

Inhalation: In case of exposure to a high concentration of dust, remove person to fresh air. If breathing has 

stopped, administer artificial respiration and seek medical attention. Ingestion: If appreciable quantities are 

swallowed, seek medical attention. 

Nature of Hazard (Physiological Effects) 

WARNING: MAY CAUSE EYE IRRITATION. BREATHING DUST MAY CAUSE 

RESPIRATORY IRRITATION 

Section V - Fire & Explosion Hazard Data

Flash Point (Closed Cup): >300 Degrees F 

Flammable Limits: No data is available 

Extinguishing Media: Water spray, Foam, CO2, Dry Chemical 

Special Fire Fighting Procedures: Wear a self contained breathing apparatus to avoid toxic fumes. 

Slippery when wet. 

Fire & Explosion Hazards: Closed containers may rupture (due to buildup of pressure) when exposed to 

extreme heat. Cool drums exposed to flames with a water spray. 

*Additional information will be provided in a medical emergency to qualified medical personnel. 

Section VI – Accidental Release Measures

Evacuation Procedures and Safety: CAUTION: Spilled material may become slippery when 

wet. Do not leave traces of product on floors, ladders, etc., as this may present a slipping 

hazard. Wear appropriate protective gear for the situation. See Personal Protection 

information in Section 8. 

Containment of Spill: Follow procedure described below under Cleanup and Disposal of 

Spill 

Cleanup and Disposal of Spill: Dry Material: Sweep up and place in an appropriate closed 

container (see Section 7: Handling and Storage). Wet Material: Absorb with an inert 

absorbent. Shovel up into an appropriate closed container (see Section7: Handling and 

Storage). 

Environmental and Regulatory Reporting: Spills may be reportable to the National Response 

Center (800-424-8802) and to state and/or local agencies. 

Section VII – Handling & Storage

Handling: Avoid breathing dusts 

Storage: Store in closed containers. Store in an area that is dry. 

Section VIII - Special Protection Information

Air Exposure Recommendations 

Gas, Fumes, Mists Special Thermal 

Normal Use Exceeds TLV Spray Application 

General Ventilation General Ventilation General Ventilation 

2 * 2* 2 * 

*Respiratory protection codes: 

1. None Needed 

KEY-HEC-1-001065 KEY-EPA-001057
Economy 

Polymers & Chemicals

P.O. Box 450246

Houston, TX 77245-0246

USA Toll free: (800) 231-2066

Phone: (713) 723-8416

Fax: (713) 723-1845 

URL: www.EconomyPolymers.com 

E-mail: economy@economypolymers.com

2. Particle-removing, air purifier. Store in dry place. Keep container closed to avoid moisture 

pickup. Material slippery when wet. 

Section IX - Physical Data

Boiling Point: >6000F pH (1% Solution): 6.0-8.0 

Vapor Pressure (mmHg): NA Vapor Density (air = 1): >10 

Water Solubility: Forms gel Specific gravity: 1.30 

Evaporation Rate (ether = 1): >1 Vapor Pressure: <0.1 

Section X - Reactivity Data

Stability: Stable Hazardous Polymerization: Will not occur 

Conditions to avoid: Fire, excessive heat 

Incompatibility (Materials to Avoid): Strong oxidizers, Liquid Acids 

Hazardous Decomposition Products: Fumes produced when heated to decomposition may include: oxides 

of carbon. 

Section XI – Toxicological Data

Acute Eye Irritation: No test data found for product 

Acute Skin Irritation: No test data found for product 

Acute Dermal Toxicity: No test data found for product 

Acute Respiratory Irritation: No test data found for product. 

Acute Inhalation Toxicity: No test data found for product 

Acute Oral Toxicity: No test data found for product. 

Chronic Toxicity: This product does not contain any substnces that are considered by 

OSHA, NTP, IARC or ACGIH to be "probable" human carcinogens. No additional test data 

found for product 

Section XII – Ecological Data

Ecotoxicological Information: No data found for product 

Chemical rate information: No data found for product 

Section XIII – Disposal Considerations

Waste Disposal Method: Chemical additions, processing or otherwise altering this material 

may make the waste management information presented in this MSDS incomplete, 

inaccurate or otherwise inappropriate. Please be advised that state and local requirements for 

waste disposal may be more restrictive or otherwise different from federal laws and 

regulations. Consult state and local regulations regarding the proper disposal of this material. 

Container Handling and Disposal: Any containers or equipment used should be 

decontaminated immediately after use. 

EPA Hazardous Waste - NO 

Section XIV – Transport Information

This product is not regulated for transport 

KEY-HEC-1-001066 KEY-EPA-001058
Economy 

Polymers & Chemicals

P.O. Box 450246

Houston, TX 77245-0246

USA Toll free: (800) 231-2066

Phone: (713) 723-8416

Fax: (713) 723-1845 

URL: www.EconomyPolymers.com 

E-mail: economy@economypolymers.com

Section XV – Regulatory Information

Inventory status Inventory status 

UNITED STATES (TSCA) Y CANADA (DSL) Y 

EUROPE (EINECS/ELINCS) N AUSTRALIA (AICS) Y 

JAPAN (MITI) N SOUTH KOREA (KECL) Y 

Y = All ingredients are on the inventory. E = All ingredients are on the inventory or 

exempt from listing. 

P = One or more ingredients fall under the polymer exemption or are on the no longer 

polymer list. All other ingredients are on the inventory or exempt from listing. 

N = Not determined or one or more ingredients are not on the inventory and are not exempt 

from listing. 

FEDERAL REGULATIONS 

Inventory Issues: All functional components of this product are listed on the TSCA 

Inventory. 

SARA Title III Hazard Classes: 

Fire Hazard NO 

Reactive Hazard NO 

Release of Pressure NO 

Acute Health Hazard NO 

Chronic Health Hazard NO 

 

SARA Extremely Hazardous Substances (EHS)/CERCLA Hazardous Substances: This 

product does not contain any hazardous substances as considered by SARA or CERCLA. 

State Regulations: This product does not contain any components that are regulated under 

California Proposition 65.

Section XVI - Miscellaneous

Comments: Use good housekeeping procedures to minimize dust build-up

Disclaimer: THE INFORMATION WHICH IS IN THIS DOCUMENT IS BASED UPON AVAILABLE 

DATA AND BELIEVED TO BE CORRECT; HOWEVER, THE PRODUCT DISCUSSED HEREIN IS 

SOLD WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED, AS TO MERCHANTIBILITY OR 

FITNESS FOR A PARTICULAR PURPOSE. 

KEY-HEC-1-001067 KEY-EPA-001059
lar 15 01 0921a ECONOMY 7134338382 p.1

MATERIAL SAFETY DATA SHEET 03-08-2000

COMPANY

ECONOMY POLYMERS AND ChEMICALS

P.O BOX 450246

HOUSTON TEXAS 77245-0246

Emergency phone number in USA 0O-23 1-2066

For product informatiOn 713-723-8416

CAS 9000-30-0

Product Name WGAI-ASLR

CHEMICAL NAME GALACTOMANNAN MIXTURE

INGREDIENTS

Percent TLV PEL

Guar Gum 80 lOmg/m3 lSmg/m3

Silica amorphous 0.1-5.0 lOmg/m3 6mg/m3

Organophilic clay 0.1-5.0

PROPERTIES

Appearance Off-white solid powder Solubility in water at 20 complete

Odor Odorless gms/l OOmi water

Specific gravity 0.900 BiodegradabilitY

slow

Bulk density 29.07 lb/cu.ft Volatiles ND

pH not determined ND Solubility in sea water ND

Flash point 200

TOXICITY HAZARD RATING Nontoxic

OSHA Hazardous F1JNn Hazardous NH NH

NFPA Hazard Code 1-lealth Flammability Reactivity 010

4ExtremelSevere 2Moderate

HMIS Labeling Health Flammability Reactivity 100

SARA Title ifi Classification Exempt Not listed as toxic chemical under 40 CFR section 372.65

Regulatory Information This product is listed on the TSCA Inventory

FIRE AND EXPLOSION HAZARD DATA

Flash Point Ignition Temp 200

Extinguishing Media- Water foam C02

Special Fire Fighting Procedures Good Housekeeping is best preventative

Unusual Fire and Explosion Hazards- Excessive dusts from powder products are potentially hazardous Avoid

excessive dusting open flames open lights or welding in area of dry product if bag dumping Incomplete thermal

decomposition may produce carbon dioxide and carbon monoxide

REACTWITY DATA

Stability Stable

Conditions to Avoid Excessive dusting

Hazardous Polymerization- Will not occur

HEALTH HAZARD DATA/FIRST AllPROCEDURES

Routes of Entry Inhalation May cause allergic respiratory reaction in susceptible individuals

ingestion ND Eye May cause irritation Skin non irritating

Carcinogenicity None

KEY-HEC-1-001068 KEY-EPA-001060

KEY-H EC-1 -001601
Mar 15 01 0921a ECOMOMY 7134338382 P.2

Signs and Symptoms of Exposure No harm under most conditions

Medical Conditions Aggravated by Exposure Inhalation of nuisance dusts have long history of little adverse

effect an lungs May iffitate mucous membranes

Emergency and First Aid Procedures

EYE immediately flush eyes with plenty of water for at least 15 minutes If irritation persists seek prompt medical

attention

SKIN PROMPTLY WASH SKThI WITH SOAP AND WATER WASH CLOTHING BEFORE REUSE

INhALATION Remove to fresh air if irritation persist seek medical attention

INGESTION do not induce vomiting in general no treatment is necessary unless large quantities are ingested

However medical advice should be obtained

PRECAUTIONS FOR SAFE HANDLING AND USE

Steps to Be Taken if Material is Rekased or Spilled Sweep up or shovel into DOT approved containers

Waste Disposal Method Comply with all applicable local state and federal regulations for waste disposal

Department of Transportation DOT Classification.- N/A non-hazardous

Precautions to Be Taken in Handling and Storing Avoid dust accumulations Best storage is realized at dry

coal conditions Store in an odor-free area Store away from heat source Do not expose to open flame or sparks

Other Precautions Enforce No Smoking Rules Excessive concentrations ofnuisance dusts in workroom air

may seriously reduce visibility

CONTROL MEASURES

Respiratory Protection Use NIOSHJOSHA approved mask when bag dumping Eye Protection Recommended

Ventilation- Use local exhaust as needed to maintain airborne exposure

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPiLLED

Use protective equipment sweep up and remove avoid creating or inhaling dust

Product is very slippery when wet

Waste disposal method If not contaminated reuse product get approval from landfill operator and transport to

sanitary landfill

ENVIRONMENTAL EVALUATION

EPA SUPERFUND SARA TITLE ifi- HAZARD CLASSIFICATiON AND ASSOCIATED INFORMATION

FIRE PRESSURE REACTIVE ACUTE IMMEDiATE

CHRONIC DELAYED MiXTURE OR PURE MATERIAL MiX

EPA CERCLA/SUPERFUND 40 CFR 302 REPORTABLE SPILL QUANTITY NA

EPA SARA TiTLE III CFR 355 EXTREMELY HAZARDOUS SUBSTANCES

PRODUCT CONTAINS NO EXTREMELY HAZARDOUS COMPONENTS

EPA SARA TITLE 11140 CFR 372 LIST OF TOXIC CHEMICALS

PRODUCT CONTAINS NO TOXIC INGREDIENTS

COMPONENTS LiSTED ON FOLLOWING CHEMICAL INVENTORIES

TSCA YES CEPA NE EEC ND ACOIN ND NPR ND DRSM NE

EPA RCRA HAZARDOUS WASTE 40 CFR 261

IF PRODUCT BECOMES WASTE IT DOES NOT MEET THE CRITERIA OF HAZARDOUS WASTE

THE INFORMATION WHICH IS IN THIS DOCUMENT IS BASED UPON AVAILABLE DATA AND

BELIEVED TO BE CORRECT HOWEVER THE PRODUCT DISCUSSED HEREIN IS SOLD WITHOUT

ANY WARRANTY EXPRESSED OR IMPLIED AS TO MERCHANTIBILITY OR FITNESS FOR

PARTICULAR PURPOSE

KEY-HEC-1-001069 KEY-EPA-001061

KEY-H EC-1 -001602
MATERIAL SAFETY DATA SHEET

PR0DUCr NAME 711 t5

REVISION DATE APR11 32003

ThIZPHONENU%m13R 713-723-8416

IN CHEMICAL EMERGENCY CALL ECONOMY 100-231-2066

Maaic BoomyPolymers

Mdre.a 43511 Anderson Rd

Houitcn Tema 77047

FOR INDUSThML USE ONLY

Section 1-Product Information

Chemical Nanw BLEND

Formula NA

DOT Hazard ama Not Pogulted

DOT B1Th.X Petroleum diatillstca N.O.S Costhustible liquid UN 1268 ifi

CANADIAN ADR ICAO/IATA SM TRANSPORTA11C IMDG ALL NOT RESTRICIED

Section II Physical Data

Flash Point 176F Aiitoignition Ten 437F or 225C

Boiling Point 400-700F pHraie 6.5-7.5

Color BEI Odor Hydrocarbon

Physical state liquid Specific Gravity 1.03

Vo1tiks 12.5 Vapor Demity 4.5

Density lbs/gil 8.6

Section 111- Hazardous I.gredlents

Matatlal Cu Perecot ILVunits Had

1PcomdjstjlIitebl NA 30-60 NA combustible

Polysaccbaridc blend NA 30-60 NA

Section IV Fire Explodoir Hazaid Data

Th1ingiahiiig Media Water Foam CO2 Dry Chemical

Special Fira F%iiig Procedmza Wear self contained bm.bing apparatus to avoid toxic flunes

Slippery when wat

Fire Explosion Haranis aoaerl containers may niptum due to buildup pressure when

erposed to treme heat Cool kums ecposed to flames with water apray

Addifioeal information will be provided in medical amàgoncy to qualified medical personnel

KEY-HEC-1-001070 KEY-EPA-001062

KEY-H EC-1 -001603
Section Health flmrd Dat

lirealiold Unijt Value TLV fbr Product None Established

Does product contain any OSHA NIP or IARC Carcinogens No

Fist Aid

Eyes Flush thoroughly with turning water at least 15 minutes Get medical atteslion if irritation

Skis Remove cocimiiiated clothing sari wash contact area with soap and water lbr 15 minutes

bJiation In of exposure to high concentration remove person to fresh air If breathing

has stopped ahniner artificial respiration and scak medical ilidioa

Ingestion If appreciable iaitiea are swallowed seek medical atton

Nature of Hazard Physiological Effects

Signs Systems ofOveroxposore in the Woàplace

Eyes May canse irritation

Skis May onise mild irritation

btios Inlmiuiig dust maycmise respiratuiy iiitation

Nature ofHazard Physiological Effects

MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGORAVA1 BY OSURE kne Known

PRIMARY ROIYrB OP FRmY

Following .Indiud industrial hygiene a.d reconunerKled procedures thy of the cempound into

thebodyisnctexpected CAINFORMATION

Contains petrobema ailate wiuich have been shown to cmise akin cancer in isboratosy Irninal$

Special Precautions Individuals with akin or icapiatoiy diacucs should not be esposed to this

urdeas predy prctccte

Section VI Resetivity Data

Stability Stable Hazardous Polymerization Will not ocour

Conditloen to avoid Fire erceonve best

Inconipatibilky Materials to Avoid Strong oxidizers1 Uquid Acids

HazardonDeconipositlon Products Fumes produced when bested to

deconiposition may dIe oxides of aiboui

NFPA RATINGS HEALTh FLAMMABILITY REACIIVTY

HIMS RATINGS FLAMMABILITY REACflV1TY IJEAL1B

Sediwi VU Spli Leak Prced.res

Stopflowaod containspifi ydfr eandbegs etc

Ellmjnate all ignition loumes

InCiflerate unng aftcer and scrubber

Uso skin protection as per section VIII

4Absoib on itmaterial and .cra up or shovel into thums

Observo federal spill and water quality regulations

KEY-HEC-1-001071 KEY-EPA-001063

KEY-H EC-1 -001604
Product Name HPG

Revision Date December 2005

Manufacturer Economy Polymers Chemicals

IN CHEMICAL EMERGENCY CALL 800-231-2066

FOR INDUSTRIAL USE ONLY

Section Product Information

Chemical Name Hydroxypropyl Guar Gum

Chemical FamilyGalactomannafl Thickner

Formula C6H1205.0.42 POE CAS Number 39421-75-5

DOT Hazard Class Not Regulated

Reportable Quantity None

DOT Proper Shipping Name Bean Meal NOl Dried

Section II Physical Data

Boiling Point N/A Density .38-I .4OgIcm3

Water Solubility Forms Gel pH 9.0 10.5 1- 0.5 1% Solution

Moisture 6.0 10

Appearance and Odor Cream Color Solid Powder with Bean like Odor

Section DI Hazardous ingredients

Material Percent liv lunits Hazard

Hydroxypropyl Guar Gum 50-90% 10 mgfm3 Nuisance Dust

CAS 39421-75-5

Silica amorphous 0.1-5.0 lOmgfm3

Organophilic clay 0.1-10.0

Dicarboxylic acid 0.1-10.0

Section 1V Fire Explosion Hazard Data

No data is available Flash point close cup 200uF PMCC Flammable Limits

Extinguishing Media Water spray Foam C02 Dry Chemical

Special Fire Fighting Procedures Wear self-containing breathing apparatus to avoid toxics Slippery

when wet

Fire Explosion Hazards Closed containers may rupture due to buildup of pressure when exposed to

extreme heat Cool drums exposed to flames with water spray

Additional information will he provided in medical emergency to qualified medical personnel

Polymers Chemicals

P.O Box 450246

Houston TX 77245-0246

USA Toll free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconornyPolymers.com

E-mail economyeconomypolymers.Com

irt my /4- POLYMES CHEMICALS

MATERIAL SAFETY DATA SHEET

Complies with OSHA 29 CFR 1910.1200

KEY-HEC-1-001072 KEY-EPA-001064

KEY-H EC-1 -001605
Eaa

POLYMERS 4EALS

Section Health Hazard Data

Threshold Limit Value TLV for Product None Established

Does Product contain any OSHA NTP or IARC Carcinogen No

FIRST All

Eyes Flush thoroughly with running water for at leasl 15 minutes Get medical attention if irritation

persists

Skin Remove contaminated clothing and wash contact area with soap and water for 15 minutes

Inhalation In case of exposure to high concentration of dust remove person to fresh air If breathing has

stopped administer artificial respiration and seek medical attention

Ingestion If appreciable quantities are swallowed seek medical attention

NATURE OF HAZARD Physiological Effects

Eyes No specific information available Contains materials that may cause severe injurydamage

reversible

Skin Contains materials that may cause moderate skin injury reddening swelling

Inhalation No specific information available Dust may produce respiratory allergenic response andi or

irritation in some individuals

Ingestion No specific information available Contains materials that may be slightly toxic

Acute Overexposure Based on medical study of exposed workers some individuals may develop

respiratory allergenic response to guar dust

TOXICITY DATA

Eye Contact PRIMARY ROUTE OF ENTRY no data is available

Skin Contact PRIMARY ROUTE OF ENTRY no data is available

Inhalation No date is available Ingestion No date is available

Special Precaution Individuals with skin or respiratory disease should not be exposed tois product unless

properly protected

Section Vi Reactivity Dta

Stability Stable Hazardous Polymerization Will not occur

Conditions to avoid Fire excessive heat

Incompatibility Materials to Avoid Strong oxidizers

Hazardous Decomposition Products Fumes produced when heated to decomposition may include oxides

of carbon

Section VII Siiill or Leak Procedures

Stop flow and contain spill by diking sandbags etc

Eliminates all ignition sources Incinerate using afterburner and scrubber

Use skin protection as per section VIII Absorb on inert material and scrape up or shovel into drums

Observe federal spill and water quality regulations

Section VIII Special Protection Information

Air ojçecommendation las Fumes and M.ists

Normal Use General Ventilation Exceed TLV General Ventilation

Special Thermal Spray Applications -- General Ventilation

Respiratory protection codes

P.O Box 450246

fly Houston TX 77245-0246

Polymers ChemIcals USA Toll free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconomyPolymers.com

E-mail economyeconomypolymerS.cOm

KEY-HEC-1-001073 KEY-EPA-001065

KEY-H EC-1 -001606
POLYMERS CHEMICALS

Particle-removing air purifying respirator Dusk Mask

Gas and vapor-removing air purifying respirator Canister

Full thee mask positive pressure-demand type air supplied

Eye Protection Goggles and Face Shield in_Protectjon Neoprene Gloves and Nitrile Gloves

Other Protective Equipment Chemical Resistant Apron and Shoes

Section IX Special Precautions

Wear eye and skin protection Store in dry place Keep container closed to avoid moisture pickup Avoid

creating dust clouds and breathing dust when handling

Material slippery when wet

Section Miscellaneous

Is product RCRA regulated No

Are all ingredients listed in the TSCA Inventory Yes

Ingredients regulated by the Clean Air Act or the Clean Water Act Nine

Environmental Effects No data is available but the aquatic toxicity is probably in the moderate range

SARA Classification None

EPA Hazard Category Non

Comments Use good housekeeping procedures to minimize dust build-up

Polymers Chemicals

P.O Box 450246

Houston TX 77245-0246

USA Toil free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconomyPotymerz.com

E-mail economyeconomypoiyn1ers.com

None needed

KEY-HEC-1-001074 KEY-EPA-001066

KEY-H EC-1 -001607
.4

PRODUCT NAME

REVISION DATE

Section Product Information and Company Identification

Chemical Name BLEND Formula NA

DOT Hazard Class Not Regulated

CANADIAN ADR ICAOIIATA SEA TRANSPORTATION IMDG ALL NOT

RESTRICTED

Material

Iso-Alkanes/n-Alkanes

Polysaccharide blend

Section III Hazards Identification

Hazard Overview May cause eye skin and respiratory irritation May cause headache

dizziness and other central nervous system effects May cause allergic respiratory

reaction May be harmful if swallowed

Section IV First Aid Measures

Eyes Flush thoroughly with running water at least 15 minutes Remove contact lenses if

worn Get medical attention if irritations persist

Skin Remove contaminated clothing and wash contact area with soap and water for 15

minutes Do not reuse clothing until thoroughly cleaned Get medical attention if

irritations persist

Inhalation In case of exposure to high concentration remove person to fresh air If

breathing has stopped administer artificial respiration and seek medical attention

Ingestion Do not induce vomiting Seek medical attention

Economy

Polymers Chemicals

IEcoriorriy WGP rId

POLYMERS CHEMICALS

MATERIAL SAFETY DATA SHEE

ECOPOL-18Y2LMS

MARCH 11 2008

For Chemical Emergency SpifiLeak Fire Exposure or Accident

CALL CHEMTREC Day or Night 800-424-9300

For International Call 703-527-3887 Collect Calls Accepted

FOR INDUSTRIAL USE ONLY

Section II Composition Information on Ingredients

Cas Percent TLVunits

NA 30-60 NA

NA 0-60 NA

Section Fire Explosion Hazard Data

P.O Box 450246

Houston TX 77245-0246

USA Toll free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconomyPolymers.com

E-mail economyeconomypolymers.cOm

KEY-HEC-1-001075 KEY-EPA-001067

KEY-H EC-1 -001608
E.coriamy

POLYMERS CHEMICALS

Extinguishing Media Water spray Foam C02 Dry Chemical

Special Fire Fighting Procedures Wear selfcontained breathing apparatus to avoid

toxic fumes Slippery when wet Do not use direct stream of water as material can float

and reignite on surface

Fire Explosion Hazards Closed containers may rupture due to buildup of pressure

when exposed to extreme heat Cool drums exposed to flames with water spray

Additional information will be provided in medical emergency to qualified medical

personnel

Section VI Accidental Release Measures

Stop flow and contain spill by diking sandbags etc

Eljminate all ignition sources

Incirierate using afterburner and scrubber

Use skin protection as per section VIII

Absorb on inert material and scraps up or shovel into drums

Obsei.ve federal spill and water quality regulations

Section VII Handling and Storage

Handling Precautions Avoid contact with eyes skin or clothing Avoid breathing

vapors Wash hands after use Launder contaminated clothing before reuse

Storage Information Store away from oxidizers Store in cool well ventilated area

Keep from heat sparks and open flames Keep container closed when not in use

Section VIII Personal Protection Information

AirExposure Recommendations

Normal Use

General Ventilation

Respiratol.y protection codes

None Needed

Particle-removing air purifying respirator Dusk Mask

Gas and vapor-removing air purifying respirator Canister

Full face mask positive pressure-demand type Air Supplied

Eye Protection Goggles Face Shield

Skin Protection Neoprene Gloves Nitrile Gloves

Other Protective Equipment Chemical Resistant Apron Shoes

Economy

Polymers Chemicals

Gas Fumes Mists

Exceeds TLV

General Ventilation

Special Thermal

Spray Application

General Ventilation

P.O Box 450246

Houston TX 77245-0246

USA Toll free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconomyPolymers.com

E-mail economyeconomypolymers.com

KEY-HEC-1-001076 KEY-EPA-001068

KEY-H EC-1 -001609
E.canamy

POLYMERS CHEMICALS

215F

475-560F

Section IX Physical Data

Autoignition Temp

pH range

Flash Point

Boiling Point

Color

Physical state

Volatiles

Density lbs/gal

Section Reactivity Data

Stability Stable Hazardous Polymerization Will not occur

Conditions to avoid Keep away from heat sparks and flame

Incompatibility Materials to Avoid Strong oxidizers

Hazardous Decomposition Products Fumes produced when heated to

decomposition may include oxides of carbon

NFPA RATiNGS HEALTH FLAMMABILITY REACTIVITY

HIMS RATINGS FLAMMABILITY REACTIVITY HEALTH

Section XI Toxicological Information

Threshold Limit Value TLV for Product 5mg/m3

Does product contain any OSHA NTP or IARC Carcinogens No

Nature of Hazard Physiological Effects

Signs Systems of Overexposure in the Workplace

Principle Route of Exposure Eye or skin contact inhalation

Eyes May cause irritation

Skin Causes drying of the skin May cause mild irritation

Inhalation May cause respiratory irritation May cause allergic reaction May cause

chemical pneumonia May cause nervous system depression including headache

dizziness drowsiness incoordination slowed reaction time slurred speech giddiness

and unconsciousness

Ingestion Irritation of the mouth throat and stomach Aspiration into the lungs may

cause chemical pneumonitis including coughing difficulty breathing wheezing

coughing up blood and pneumonia which can be fatal May cause central nervous

system depression including headache dizziness drowsiness muscular weakness

incoordination slowed reaction time fatigue blurred vision slurred speech giddiness

tremors and convulsions

MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED

BY EXPOSURE Skin disorders

Economy

Polymers Chemicals

P.O Box 450246

Houston TX 77245-0246

USA Toll free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconomyPolymers.com

E-mail economyeconomypolymers.com

Beige

liquid

ND

8.51

Odor

Specific Gravity

Vapor Density

ND

6.5-8.0

Hydrocarbon

1.02

ND

KEY-HEC-1-001077 KEY-EPA-001069

KEY-H EC-1 -001610
_p Ecar.amy

POLYMERS CHEMICALS

Section XII Ecological Information

No data available

Section XIII Disposal Considerations

Disposal Method Disposal should be made in accordance with federal state and local

regulations

Contaminated Packaging Follow all applicable national or local regulations

DOT Not Regulated

Canadian TDG Not restricted

ADR Not Restricted

ICAO/IATA Not Restricted

IMDG Not Restricted

Harmonized Tariff Code 2901.10.50

Section XV Regulatory Information

Is product RCRA regulated No

Are all ingredients listed in the TSCA Inventory Yes

Ingredients regulated by the Clean AirAct or the Clean Water Act None

EPA SARA 311312 Hazard Class Acute Health Hazard

Section XVI Miscellaneous

Disclaimer This information is furnished without warranty expressed or implied as to accuracy for

completeness This information is obtained from various sources including the manufacturer and other

third party sources The information may not be valid under all conditions nor if this material is used in

combination with other materials or in any process Final determination of suitability of any material is the

sole responsibility of the user

Economy

Polymers Chemicals

P.O Box 450246

Houston TX 77245-0246

USA Toll free 800 231-2066

Phone 713 723-8416

Fax 713 723-1845

URL www.EconomyPolymers.com

E-mail economyeconomypolymers.com

Section XIV Transport Information

KEY-HEC-1-001078 KEY-EPA-001070

KEY-HEC-1 -001611
Material Safety Data Sheet

1A

PlexsurfWftS

STORAGE Flammable materials should be stored in separate

safety storage cabinet or room Keep away from heat

Keep away from sources of ignition Keep container

tightly closed Keep in cool welt-ventilated place

Ground all equtpment containing material refrigerated

room would be preferable for materials with flash point

lower than 37.8C 100F L_ SECTION \IIl PRO1 LCTIVF CLOT IING

RESPIRATORY PROTECTION Wear appropriate respirator when ventilation is

inadequate

PROTECTIVE CLOTHING/EQUIPMENT Splash goggles lab cotIapron gloves

SECTIONI TRANSPORTATION DATA

PROPER SHIPPING NAME Flammable liquid n.o.s

HAZARD CLSS

UN NUMBER UN 1993

PACKAGING GROUP II

RQ N/A

DOT SHIPPING Flammable liquid n.o.s Contains Methyl Alcohol

UN 1993 PG

This material is classified as marine pollutant due to its

content ol dodecylbenzene sulfonic acid salts

SECTION OTHER REGULATORY INFORMATION

TSCA sTATUS Al components of this product are listed on the TSCA

inventory

NFPAHEALTH

NFPA FLAMMABILiTY

NFPA REACTIvrrY

SECTION XI ADDITIONAL INFORMATION

PREPARED BY Edward Vinson

EMERGENCY RESPONSE NUMBER 800

Page of4

KEY-HEC-1-001079 KEY-EPA-001071

KEY-H EC-1 -001630
Material Safety ftita Sheet

Plexsurf WRS

tissues are damaged possible indication that the toxic

material was ingested the absence of such signs

however is not conclusive Loosen tight clothing such

as collar tie belt or waist hand If the victim is not

breathing perform mouth-to-mouth resuscitation Seek

medical attention

EYE CONTACT Check for and remove any contact lenses Immediately

flush eyes with running water for at least 15 minutes

keeping Eyelids open Cold water may be used Do

NOT use an eye ointment Seek medical attention

SKIN CONTACT If the chemical got onto the clothed portion of the body

remove the contaminated clothes as quickly as possible

protecting your own hands and body Place the victim

under deluge shower If the chemical touches the

victims exposed skin such as the hands Gently and

thoroughly wash the contaminated skin with running

water and non-abrasive soap Be particularly careful to

clean folds crevices creases and groin COLD water

may be used Cover the irritated skin with an emollient

If irritation persists seek medical attention Wash

contaminated clothing before reusing

FCTION Vii SPILL SIORAG AND DiSPOSAL DA 1A

SPILL SMALL Dilute with water and mop up or absorb

with an inert DRY material and place in an appropriate

waste disposal container

LARGE SPILL Keep away from heat Keep away from

sources of ignition Stop leak if without risk Absorb with

DRY earth sand or other non-combustible material DO

NOT touch spilled material Prevent entry into sewers

basements or confined areas dike if needed Eliminate

all sources of ignition

WASTE DISPoSAL Whatever cannot be saved for recovery or recycling

should be managed in an appropriate and approved

waste disposal facility Processing use or

contamination of this product may change the waste

management options State and local disposal

regulations may differ from federal disposal regulatrons

Dispose of container and unused contents in accordance

with federal state and local requirements

HANDLING Keep locked up Keep away from heat Keep away

from sources of ignition Ground all equipment

containing material DO NOT ingest Do not breathe

gas fumes vapor or spray In case of insufficient

ventilation wear suitable respiratory equipment If

ingested seek medical advice immediately and show the

container or the label Avoid contact with skin and eyes

Keep away from incompatibles as oxidizing agents

Page ol4

KEY-HEC-1-001080 KEY-EPA-001072

KEY-H EC-1 -001631
Material Safety ata Sheet

PlexsurfWRS

EXTINGUISHING MEDIA Flammable liquid soluble or dispersed in water

FIRE FIGHTING PROCEDURES SMALL FIRE Use DRY chemicals C02 water spray or

alcohol foam

kARGE_F Use alcohol foam water spray or fog

Cool containing vessels with water jet in order to prevent

pressure build-up autoignition or explosion

EXPLOSION HAZARDS Explosive in the form of vapor when exposed to heat or

flames Vapor may travel considerable distance to

source of ignition and flash back When heated to

decomposition it emits acrid smoke and irritating fumes

Methyl alcohol

SECTION REACTIVITY DATA

STABILFfl This product is stable

CORROSIVrIY Non-corrosive in presence of glass

REACflV11Y Highly reactive with oxidizing agents

LSEcTTON VT HEALTH HAZARD IATA

ROUTE OF ENTRY Ingestion Inhalation

ACUTE EFFECT ON HUMANS Slightly dangerous to dangerous in case of skin contact

irritant of eye contact irritant of ingestion of

inhalation Very slightly to slightly dangerous in case of

skin contact permeator

CHRONIC EFFECTS ON HUMANS .. The substance is toxic to the nervous system the

reproductive system

Passes through the placental barrier

SECTION VIB-FIRST AID

INHALATION SLIGHT INHALATION Allow the victim to rest in well

ventilated area Seek immediate medical attention

HAZARL.QS INHALATION Evacuate the victim to

safe area as soon as possible Loosen tight clothing

such as collar tie belt or waistband If breathing is

difficult administer oxygen If the victim is not breathing

perform mouth-to-mouth resuscitation WARNING It

may be dangerous to the person providing aid to give

mouth-to-mouth resuscitation when the inhaled material

is toxic infectious or corrosive Seek medical attention

INGESTION SLJGHTjjESTION Do not induce vomiting Have

conscious person drink several glasses of water or milk

Seek immediate medical attention

HAZARPQQS INGESTION Do NOT induce vomiting

Examine the lips and mouth to ascertain whether the

Page of

KEY-HEC-1-001081 KEY-EPA-001073

KEY-H EC-1 -001632
MJ$afCtY Data Sheet

PlexsurfWRS

DATh PREPARED 05/19/04

them le REVISION DATE 10/08/04

_____ 506 CR 1071 EMERGENCY NUMBER...800-633-8253

Ll Snyder 79549 PRODUCT NuMBER 00826

325 573-7298

SECTION IDENTIFICATION

PRODUCT NAME PlexsurfWRS

SYNONYMS N/A

CHEMICAL FAMILY Surfuctants

CAS NUMBER N/A

PRODUCT USE Petrochemical industry

SECTION II- HAZARDOUS INGREDIENTS

HAZINGREDIENT PERCENT CAS NUMBER PEL

METHYL ALCOHOL 60% 67-56-1 Not Available

Dodecylbenzene 15-20% 6864.8-81-7 Not Available

Sulfonic 4id Salts

SECTION III PHYSICAL DATA

APPEARANCE Pale Yellow liquid

ODOR Alcohol like slight

BOIUNG POINT 1700

FLASHPOINT 56F Open Cup

VAPOR DENSITY AIR1 1.11

SPECIFIC GRAViTY WATER1 0.95

pH 1% SOIN/WATER Neutral

SOLUBILY Easily soluble in cold water hot water methanol diethyl ether

WI 7.93 per gallon

SECTION IV FIRE AND EXPLOSION DATA

FLASHPOINT 56F Open Cup

FLAMMABII UM1TS LOWER 6% Methyl Alcohol

UPPER 36.5 Methyl Alcohol

FLAMMABLE HAZARDs Highly flammable in presence of open flames and sparks of

heaL of combustible materials

Page of

KEY-HEC-1-000562

KEY-H EC-1 -001633 KEY-EPA-000562
Material Safety Data Sbeet

PlexsurfWRS

EXTINGUISHING MEDIA Flammable liquid soluble or dispersed in water

FIRE FIGI-ITING PROCEDURES SMALL FIRE Use DRY chemicals C02 water spray or

alcohol foam

LARGE FIRE Use alcohol foam water spray or fog

Cool containing vessels with water jet in order to prevent

pressure build-up autoignition or explosion

EXPLOSION HAZARDS Explosive in the form of vapor when exposed to heat or

flames Vapor may travel considerable distance to

source of ignition and flash back When heated to

decomposition it emits acrid smoke and irritating fumes

Methyl alcohol

SECTION REACTIVITY DATA

STABILITY This product is stable

CORROSIVITi Non-corrosive in presence of glass

PEACrIvflY Highly reactive with oxidizing agents

SECTION VI HEALTH HAZARD DATA

ROUTE OF ENTRY Ingestion Inhalation

ACUTE EFFECT ON HUMANS Slightly dangerous to dangerous in case of skin contact

irritant of eye contact irritant of ingestion

inhalation Very slightly to slightly dangerous in case of

skin contact permeator

CHRONIC EFFECTS ON HUMANS .. The substance is toxic to the nervous system the

reproductive system

Passes through the placental barrier

SECTION VI FIRST All

INHALA11ON SUGHTINHAL4TION Allow the victim to rest in well

ventilated area Seek immediate medical attention

HAZARDOUS INHALATION Evacuate the victim to

safe area as soon as possible Loosen tight clothing

such as collar tie belt or waisthand If breathing is

difficult administer oxygen If the victim is not breathing

peform mouth-to-mouth resuscitation WARNING It

may be dangerous to the person providing aid to give

mouth-to-mouth resuscitation when the inhaled material

is toxic infectious or corrosive Seek medical attention

iNGESTiON SLiGHT INGES71ON Do not induce vomiting Have

conscious person drink several glasses of water or milk

Seek immediate medical attention

HAZARDOUS INGESTiON Do NOT induce vomiting

Examine the lips and mouth to ascertain whether the

Page of

KEY-HEC-1-000563

KEY-H EC-1 -001634 KEY-EPA-000563
Material Safety Data Sheet

PlexsurfWRS

tissues are damaged possible indication that the toxic

material was ingested the absence of such signs

however is not conclusive Loosen tight clothing such

as collar tie belt or waist band If the victim is not

breathing perform mouth-to-mouth resuscitation Seek

medical attention

EYE CONTACF Check for and remove any contact lenses Immediately

flush eyes with running water for at least 15 minutes

keeping eyelids open Cold water may be used Do

NOT use an eye ointment Seek medical attention

SKIN CONTACP If the chemical got onto the clothed portion of the body

remove the contaminated clothes as quickly as possible

protecting your own hands and body Place the victim

under deluge shower If the chemical touches the

victims exposed skin such as the hands Gently and

thoroughly wash the contaminated skin with running

water and non-abrasive soap Be particulaily careful to

clean folds crevices creases and groin COLD water

may be used Cover the imtated skin with an emollient

If irritation persists seek medical attention Wash

contaminated clothing before reusing

SECTION VII SPILL STORAGE AND DISPOSAL DATA

SPILL SMALL SPILL Dilute with water and mop up or absorb

with an Inert DRY material and place in an appropriate

waste disposal container

LARGE SPILL Keep away from heat Keep away from

sources of ignition Stop leak if without risk Absorb with

DRY earth sand or other non-combustible material DO

NOT touch spilled material Prevent entry into sewers

basements or confined areas dike if needed Eliminate

all sources of ignition

WASTE DISPOSALS Whatever cannot be saved for recovery or recycling

should be managed in an appropriate and approved

waste disposal facility Processing use or

contamination of this product may change the waste

management options State and local disposal

regulations may differ from federal disposal regulations

Dispose of container and unused contents in accordance

with federal state and local requirements

HANDLING Keep locked up Keep away from heat Keep away

from sources of ignition Ground all equipment

containing material DO NOT ingest Do not breathe

gas fumes vapor or spray In case of insufficient

ventilation wear suitable respiratory equipment If

ingested seek medical advice immediately and show the

container or the label Avoid contact with skin and eyes

Keep away from incompatibles as oxidizing agents

Page of4

KEY-HEC-1-000564

KEY-H EC-1 -001635 KEY-EPA-000564
Material Safety Data Sheet

PlexsurfWRS

Flammable matenals should be stored in separate

safety storage cabinet or room Keep away from heat

Keep away from sources of ignition Keep container

tightly closed Keep In cool well-ventilated place

Ground all equipment containing material refrigerated

room would be preferable for materials with flash point

lower than 37.8C 100F

SECTION VIII PROTECTIVE CLOTHING

RESPIRATORY PROTECTIONS Wear appropriate respirator when ventilation is

inadequate

PROTECTIVE CLOTHING/EQUIPMENT Splash goggles lab coat/apron gloves

SECTION IX TRANSPORTATION DATA

PROPER SHIPPING NAME Flammable liquid n.o.s

HAZARD aASS

UN NUMBER UN 1993

PACKAGING GROUP II

RQ N/A

DOT SKIPPING Flammable liquid n.o.s Contains Methyl Alcohol

UN 1993 PG II

This material is classified as marine pollutant due to its

content of dodecylbenzene sulfonic acid salts

SECTION OTHER REGULATORY INFORMATION

TSCA STATUS All components of this product are listed on the TSCA

inventory

NFPA HEALTH

NFPA FLAMMABILI1Y

NFPA REACTIVITY

SECTION ADDITIONAL INFORMATION

PREPARED BY Edward Vinson

EMERGENCY RESPONSE NUMBER 800-633-8253

Page of

KEY-HEC-1-000565

KEY-H EC-1 -001636 KEY-EPA-000565
MATERIAL SAFETY DATA

Xylene

SHEET

NFPA

Product And Company ldentficatiOn

Suopher Manufacturer

Chemplex LC C1empeX b.c

P.O Box 1071 P.O Box 1071

506CR137 506CR137

Snyder1 TX T9560 UntIed States Snyder TX T9550 United Slates

Telephone Number 325 573-7298 Telephone Number 325 573-7298

FAX Number 325 573-3340 FAX Number 325 573-3340

SuDoher Emeraencv Contacts Phone Number Manufacturer EmeroeflCV Contacts Phone Number

800 633-8253 800 633-8253

Issue Date- 08121/2002

Product Name Xylene

Chemical Name Dimethylbenzefle

CAS Number 1330-20-7

Chemical Family Aromatic hydrocarbon Solvent

Chemical Formula C6H4CH32

MSDS Number 109

Synonyms

XyloJ

ProductlMaterial Uses

Industrial Applicatins Solvent for organic products paraffin

Composition/InformatiOn On Ingredients

frnt CAS PenitOf

Name Iktnber Total Weight

XYLENE 1330-20-7 95-100

Hazards Identification

Primary Routess Of Entry

contact Ingestion Skin contact inhalation

Eve Hazards

Extremely dangerous in case of eye contact

Skin Hazards

Extremely dangerous in case of skin contact irritant permeator

Innestion Hazards

Very dangerous in case of ingestion

ptIor4

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KEY-H EC-1 -001646
MATERIAL SAFETY DATA SHEET

Xylene

Hazards Identification Continued

Inhalation Hazards

Very dangerous in case of Inhalation

ChroniclCarcinooenicitv Effects

The substance is toxic to blood kidneys liver

Reoroductive Effects

Not available

NeuotoxAiti

Narcotic effect may cause nervous system disturbances

Conditions Apriravated By Exposure

Material is irritating to mucous membranes and upper espratoiy tract

First Aid Measures

Check for and remove any contact lenses Do not use an eye ointment Seek medical attention

Skin

If the chemical got onto the clothed portion of the body remove the contaminated clothes as quickly as possible

protecting your own hands and body Place the victim under deluge shower It the chemical touches the

ctrns posed shin suth as The ands Oen1y and Thorougy wasn The cmltaTnWiated Ænâth nmmng water

and non-abrasive soap Be particularly careful to clean folds crevices creases and groin COLD water may be

used Cover the irritated skin with an emollient II iritaiion persists seek medical attention Wash contaminated

cfoltung beibre reusing

HAZARD SKIN CONTACT Wash with disinfectant soap and cover the contaminated skin with an

anti-bacterial cream The product is solvent irfltaling for the skin Xylene is insoluble in water It the victim

sti suffers after iong term ænsung wtih water we suggest to ænse the contaminated area SK%N OR EYES with

lukewarm pasteurized milk After the pain has stopped rinse thoroughly with wnnrig water to avoid possible

infection Milk is very good emulsifier and it is also very mild for skin and eyes Seek medical attention

lnaestion

DO NOT INDUCE VOMmNG Have conscious person drink several glasses of water or milk Seek immediate

medical attention

Inhalation

Allow the victim to rest in well ventilated area Seek immediate medical attention

Fire Fighting Measures

Flash Point 100

Flash Point Method Open cup

Autoignition Point 567.2

Lower Explosive Limit 1.1%

Upper Explosive Limit 7%

Fire And Explosion Hazards

rigtwmab scesevce olt opec flames avd spcs oc %eat of co Slightly flammable to flammable in presence of oxidizing materials of reducing materials

Vapors may travel considerable distance to source of ignftion and flash back

Extinciulehing Media

Flammable liquid insoluble in water

Pane of

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MATERIAL SAFETY DATA SHEET

Xylene

Fire Fighting Measures Continued

Fire Fiphtin InStructions

SMALL ARE Use DRY chemicals C02 alcohol foam or water spray LARGE FIRE Use water spray fog or foam Cool containing vessels with water jet in order to prevent pressure build-up autoiginition or explosion

Accidental Release Measwes

Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal

Large Spill and Leak Flammable hquid Insoluable in water Keep away from heat Keep away from sources of

Ignition Stop leak if without risk Absorb with dry earth sand or other non-combustible material DO NOT touch

spilled material Prevent entry into sewers basemenis or confined areas dike if needed Eliminate aft sources of

ignition Call for assistance on disposal

Handling And Storage

Handling And Storaoe Precautions

Keep away from heat Keep away from sources of ignition Ground all equipment containing matenal DO NOT ingest Do not breathe gas fumes vapor or spray In case of insuffident ventilation wear suitable respiratory

eqllpnierit If ingested seek medical advice immediately and show the container or the label Avoid contact

with skin and eyes Keep away from licompatibles as oxidizing agents reducing agents organic materials

metals alkalis

Flammable materials should be stored Vi separate satety storage cabinet or room Keep away from heat

Keep away from sources of Ignition Keep container tightly closed Keep in cool well-ventilated place Ground all equipment containing material refrigerated room would be preferable for materials with flash

point lower than 378 100

Protective Clothina Pictoorws

nan

Exposure ControlslPersonal Protection

Eve/Face Protection

Splash goggies

Skin Protection

Apron/Lab coat Gloves

Resoiratory Protection

Be sure to use an approveWcettiflecl respirator or equivalent

Physical And Chemical Properties

Anoearance

Colotless to pale amber bquid

Aromatic stror

Chemical Type Pure

Physical State Uquki

Boiling Point 251.3

PaDP 015

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MATERIAL SAFETY DATA SHEET

Xylene

Physical And Chemical Properties Continued

Odor Continued

Specdlc Gravity 0.86 waterl

Vapor Density 37 air1

Solubility methanol diethyl etther

10 Stabfffty And Reactivity

Stability This product is stable

nconiatibe tl.aterta%s

Highly reactive with oxidizing agents

Slightly reactive to reactive wh reducing agents metals organic materials alkalis

11 Toxicological Information

Eve Effects

reme%y dangerous in case ot eye contact irrar

Skin Effects

Exfremely dangerous in case of skin contact

Acute Oral Effects

Very dangerous in case of ingestion

Acute Inhalation Effects

Very dangerous in case of inhalation

ClironiclcarcinOoeflicftV

The substance is toxic to the blood kidneys liver

Reoroductive Effects

Not Available

Neurotoxlcitv

Narcotic eflbct may cause neivous system disturbances

Conditions Awuavated By EXDOSUre

Material is irritating to mucous membranes and upper resçatnty tract

12 Ecological Information

No Data AvaHabe..

13 Disposal Considerations

Wtiatever cannot be saved br recovery or recyding ioud be managed in an approfMiate and approved waste disposal

facildy Processing use or contamination of this product may change the waste management options State and local

disposal regulations may differ from federal disposal regulations Dispose of contamer and unused contents in

accordance th federal slate and local requirements ______________________________________________

14 Transport Information

Prooer Shipping Name

Xylenes UN 1307 PG II

RQ13 gailons xyet

Paoe of

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MATERIAL SAFETY DATA SHEET

Xylene

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

lrpduct Identification

Product Name Xvlcne

Synonyms Z-l0

CAS Number Blend

Company Identification

MidndIX79706 USA

FIJEIEF 1432-560-5601 For product in formation

1-800-535-5053 For emergencies

COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENT LISTiNG

XYLENE Condentia1 133I-20-7

ETHYLBENZENE Confidential 100-41-4

TO UUN ConIiiential

See Se.tiou 1o exptuute guidelines

See Section IS for repulatorv information

HA1.ARS IHSCIOS1 RI

flii prudit Loitaius hazardous oatciials defiied the CJSfl Haiazd Cu iuaieutioii Smdard CUR ft 20ft

deined under Sdra 311 and 312 this product oataii1s materials tiiàt are acute chiouic tire hazards

FIAZARDS IDENTIFiCATION

E1ERFNCY OVFRVIFV

lmtating to the eyes and skin lhis prodoct conlains ethyiheozene The TARC has caluted and classified it as possible human

carcinogen grotto 2Ri hascd ciii airial ej\inicIit liHntIctc 1uid

HMIS Ratiug

I111h

Hanintahilu

Rezsctiity

Pc ro al Po it tct In dy

POlEYFIAL IIEALTII EFFETS

EYE

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KEY-H EC-1 -001650
Xylne 3uge of

RTLt Nurnbe 00000473 April 2007

irritating but does not injure eye tisSue

SKINt

Frequent or prolonged contact may irritate Low order o1toxiitv Occasional brief contact with the liquid will not result in

significant initation unless evaporation is impeded Skin contact may aggravate an existing dermatitis condition

INHALATION

High vapor/aerosol concentrations greater than approximately XX ppm are irritating to the eyes and the respiratory tract may

cause headaches dizziness anesthesia drowsiness unconsciouoess and other central nervous system effects including death

Negligible hazard at ambient temperature -1 to 38 Deg to 1X dee

iNGESTION

Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe

pulmonary injury possibly progressing to death Low order ottoxicity

CHRONIC EFFECTS

This product contains ethvlbenzene The international agency tir research on cancer ARC has evaluated ethylbenzene and

classified it as possible human carcinogen group 23 Based on sufficient evidence for carcinogenicity in experimental animals

but inadequate evidence kit cancer in exposed humans

REPRODUCTIVE HAZARDS

Nune Known

CARCINOGENICITY INFORMATION

Possible cancer hazad based on tC5t with Iahoratorr- animol

TARGET ORGAN

Eyes Skin Respiratory Tract

FIRST AID MEASURES

EYE CONTACT FIRST AID

After initial flushing remove any contact lenses and cOntinue flushing for at least IS ntinulC5 let medical attention if irritation

develops or persists

SKIN CONTACT FIRST AID

Immediately 1ush skin with plenty of water for at least 15 minutes Get medical attention if irritation develops or persists

INHALATION FIRSt All

Using proper respiratory protection immediately remove the attected victim from exposure Administer artificial respiration ii

breathing is stopped Keep at rest Call fur proilipt medical attention

INGESTION FIRST AID

If swallowcd do not induce vomiting Keep at rest jet prompt medical attention

FIRE FIGHTING MEASURES

FLAMM ABLE PROP ERTIFS

1CC Flash Point 26.1 79.0

Autoignition Temperature N/A

FLAMMABLE LIMITS AIR

1FF N/A

tjFL NA

FLAMMABLE PROPERTiES

liihIv Flainmahle

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Flamniable liquiI can release .apors that krm flammable niixtures at teniperatuies at orabo the flashponi

FIRE FEGHTING iNSTRUCTIONS

Avoid spraying water directly into storage cootaincrs due to darigcr ofboilovcr

COMBUSTION PRODUCTS

Smoke Carbon lioxide Carbon Monoxide Oxides of Nitrogen

ACCIDENTAL RELEASE MEASURES

SAFEGUARDS PERSONNEL Avoid breathing vapor Eliminate all sources of initiou heaL sparks ilauc electricity impact and friction Wear appropriate

personal protective equipment

INITIAL CON FAIN MENT

Contain spilled material Eliminate all sources of ignition heat sparks flame electricity and impact Absorb spills with inert

material Treat or dispose olwask material in aeordance with all local state/provincial and national requirements

LARGE SPILLS PROCEDURE

Contain spilled material Eliminate all ignition surccs Absorb spill with inert material dry sand or earth then place in

chemical waste container Treat or dispose of waste material in accordance with all local stntcprovincial and national

requirements

SMALL SPILLS PROCEDURE

Secure the spill area Absorb spills with inert material Treat or dispose uf waste material in accordance with all local

state/provincial and national requirements

HANDLING AND STORAGE

HANDLING PERSONNEL Avoid breathing vapors Do not get iii eves on skin or clothing Ground and bond containers when transferring material

UA\DLI PIIVSICU ASPEC IS Eliminate all sources of ignition heat sparks flame electricity impact and friction

STORAGE PRECAUTIONS

Avoid extreme temperatures

SPFTCJ4L SFNSIflVliY

Material will accumulate static charges wInch may cause an electrical spark Ignition source Use proper hondtng and/or grounding

procedures Containers may contain product residue lo not reu.e empty coniainer without commercial cleaning or

reconditionint

EXPOSURE CONTROLS PERSONAL PROTECTION

ENGINEERiNG CONTROLS

he use of local exhaust ventilation is recommended to control process emissions near the sostrcc laboratory atnplcs should be

handled in lab hood Provide mechanical ventilation of confined spaces

FACE PROTFCIION REQUIREMENTS

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KEY-H EC-1 -001652
When splashing of the material may occur chemical goggles and face shield are recommended

SKIN IROIEC HON REQUIRLMENTh

Wear protective gloves to minimize skin contamination

RESPIRATORY PROTECTION REQUIREMENTS

Use NIOSH approved organic vapor respirator when exposed to vapor from heated material

EXPOSURE CUIDELINES

XYLENE

OSHA PEL 100 ppm 435 mm3

OSHA TWA 100 ppm 435 mgmt3

ACGIH TWA 100 ppm 434 rng/m3

OSHA STEL 150 ppm

1OLUENE

081-IA TWA 100 ppm 375 mg/m3

ACGIH TWA 101 ppm

OSI-IA STEL 150 ppm 560 mgimA3

ACGIH STEL 150 ppm

PHYSICAL AND CHEMICAL PROPERTIES

FORM Liquid

COLOR Clear

ODOR Sols cut

BOILING POINT 252 286

VAPOR PRESSURE 14.2 mm Hg 100

VAPOR DENSITY 3.7 Air

SOLUB1LITY IN WATER 0.02 at 77

SPECIFIC GRAViTY 087 Water

BULK DENSiTY 7.256 pounds per gallon

MELTiNG/FREEZING POINT -48

Pit NT

VOLATILES ND

VISCOS1IY 0.7 77

EVAPORATION RATE 0.8 approx

10 STABILiTY AND REACTIVITY

STABILITY

Stable

POIY \IERIZAlION

Hazardous polymerization will not occur

INCOMPATIBiLITY VITII OTHER MAERIAIS

Strong acids alkalies and oxidizers such as liquid chlorine hydrogen peroxide and oxygen

DECOMPOSITION

Decomposition may produce fumes smoke oxides of carbon and hydrocarbons

ii TOXICOLOGICAL INFORMATION

XYLENE

lest Code Oral

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Species Rat

Results 3.523 mg/kg NIP TR 327

Test Code Inhalation LC5O

Species Rat

Results 5000 pprni4 Hr RTECS

Test Code Demial LULo

Species Rabbit

Results mLkg

Test Code Inhalation LCLo

Species Human

Results 10000 ppm/6 Ut

12 ECOLOGICAL INFORMATION

No information available

13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL

Treat or dispose of waste material in accordance with all local state/provincial and national requirements

14 TRANSPORTATION INFORMATKN

PRODUCT LABEL Xylene

DOT SI1IPPIN NAM Xyleoes3tT4l 307PGlil

D.O.T HAZARI CLASS Flammable Liquid

UN NUMBER 1307

PTODUCT RQLBS 111 pounds based on xyicnc

DOT LABEL Flammable -3

D.OT PLACARD UN 1307

PACKAGE CLASS PG III

15 REGULATORY INFORMATION

Canadian Disclosure tJst

ETHYLBENZENE l00-41-4i

SARA Title 111 Section 313

XYLENF 330-207

FTHYLBENZENE 10041-4

CERCLA Hazardous Substances

XYLENE 1330-20-7 RQ 100 lb

ETHYLBENZENE l00-41-4iRQ 1000 lb

TOLLJENF l0-8S-3 -- RQ 1000 lb

RCRA Hazardous Substances

XY1.ENE 330-20-7 -- RCRA Code U239

lOLL I.NE lO--3 RCRA Code L220

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Xylene Page of

.TN Eutnbei OLC-73 jrii 11 2C07

Title

XYLENE 1330-20-7

ETHYLBENZENE 100-41-4

TOUTFNE OS-8-3

CA ProposItion

TOLUENE l08-S8-3

SC toxic Air hfllutains List

XYLENE 1330-20-7

LTHYLBENZENE 100-41-4

TOLIJFNE3 lOS-8S-3

MISCELLANEOUS NFORMAT1ON

1hi.s material or all of its components are listed on the Inventory of ExisLing Chemical Substances under the Toxic Substance

Control Act TSCA

16 OTHER INFORMATION

REASON FOR ISSUE Revision

PREPARED BY Tom Roland

APPROVED BY Tom Roland

TITLE Director of Safety Envronrnental

APPROVAL DATE April 11 2007

SUPERCEDES DA IL January 27 2007

RTN NUMBER 00000473 OfficIal Cups

REVISION STATEMENT

Section information has been updated Ingredients added Section information has been updated Physical properties updated

Section 10 information has been updated Incompatibility inkrInation updated Section 14 information has been updated

Reportable quantity updated DOT description UN number updated

ADDiTiONAL INFORMATION

The data in this Material Safety Data Sheet relates only to the specific material designated herein It does not relate to use in

combinaLion with any other material or in any process

This iitcwmation is furnished without warriniy expressed or implied except that it is accurate to the best knowledge of Reef

Services LLC The data on this sheet arc related only to the specific material designated herein Reef Services LLC assumes no

iegul responsibility for use or reliance upon these data

ENI OF MSDS

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