UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

CERTIFICATION EVALUATION AND CONCURRENCE

Report Request ID: 1218192 Report Code: AMP600 May. 29, 2014

Selection Criteria Page 1

User ID: HSL

State County City Site Parameter POC AQCR UAR CBSA CSA

EPA

Region

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

CRITERIA

AGENCY SELECTIONS

Arizona Department Of Environmental 

Quality

Freeport McMoRan Miami, Inc.

SELECTED OPTIONS

MERGE PDF FILES

AGENCY ROLE

Option Type Option Value

YES

CERTIFYING

DATE CRITERIA

2013

Start Date End Date

2013

Tribal

Code
May. 29, 2014 Data Evaluation and Concurrence Report Summary

Page 1 of 2

Certification Year: 2013

Certifying Agency (CA): Arizona Department Of Environmental Quality (0053)

Pollutants in Report:

PQAO

Parameter

Code

Carbon monoxide

Lead (TSP) LC

Lead PM10 LC FRM/FEM

Nitrogen dioxide (NO2)

Ozone

PM10 Total 0-10um STP

PM2.5 - Local Conditions

Sulfur dioxide

42101

14129

85129

42602

44201

81102

88101

42401

Parameter Name Code

1

3

1

1

7

15

11

5

Arizona Department Of Environmental Quality 0053

PQAO Code

AQS Site-ID POC

AQS

Recommended

Flag

Cert. Agency

Recommended

Flag Reason for AQS Recommendation

0053

0053

0053

42101

88101

42602

1

3

1

04-013-9997

04-023-0004

04-013-9997

N

N

N

Y

Y

Y

Quality Assurance Project Plan not approved in 10 

years.

Flow Rate Audit completeness < 65%.

Quality Assurance Project Plan not approved in 10 

years.

Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name

Summary of 'N' flags for all pollutants:

0

3

1

0

7

15

10

5

1

0

0

1

0

0

1

0

PQAOs in Report:

04/09/12

TSA Date

Monitors 

Evaluated

Monitors Recommended for

Concurrence by AQS

Monitors NOT Recommended 

for Concurrence by AQS
May. 29, 2014 Data Evaluation and Concurrence Report Summary

Page 2 of 2

Certification Year: 2013

Certifying Agency (CA): Freeport McMoRan Miami, Inc. (1357)

Pollutants in Report:

PQAO

Parameter

Code

PM10 Total 0-10um STP 81102

Parameter Name Code

3

Freeport McMoRan Miami, Inc. 1357

PQAO Code

AQS Site-ID POC

AQS

Recommended

Flag

Cert. Agency

Recommended

Flag Reason for AQS Recommendation

Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name

Summary of 'N' flags for all pollutants:

3 0

PQAOs in Report:

TSA Date

Monitors 

Evaluated

Monitors Recommended for

Concurrence by AQS

Monitors NOT Recommended 

for Concurrence by AQS
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2013

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Carbon monoxide (42101) (ppm)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 08/06/1994

04-013-9997 SLAMS 0.416 1

Mean

 0.010

Min

 3.239

Max

0

Exceed.

Count

0

Outlier

Count

87

Perc.

Comp.

 9.48

Precision

+/-7.38

Bias

 100

Complete

100

Complete Bias

Y

PQAO Level

Criteria

N

Aqs Rec 

Flag

Y

CA Rec

Flag

S

Epa 

Eval.

Submitter Comment The AQS recommended flag is the result of not having

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

 15.90

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2013

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Nitrogen dioxide (NO2) (42602) (ppb)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date

04-013-9997 SLAMS 17.0 1

Mean

 1.0

Min

 72.0

Max Exceed.

Count

0

Outlier

Count

87

Perc.

Comp.

 6.89

Precision

+7.41

Bias

 88

Complete

100

Complete Bias

Y

PQAO Level

Criteria

N

Aqs Rec 

Flag

Y

CA Rec

Flag

S

Epa 

Eval.

Submitter Comment The AQS recommended flag is the result of not having

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

 2.16

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2013

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Ozone (44201) (ppm)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 12/31/2013

1

1

1

1

1

1

1

04-005-1008

04-007-0010

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

 0.056

 0.061

 0.057

 0.055

 0.062

 0.053

 0.056

Mean

 0.035

 0.037

 0.035

 0.021

 0.037

 0.025

 0.029

Min

 0.078

 0.096

 0.076

 0.095

 0.094

 0.077

 0.087

Max

0

0

0

0

0

0

0

Exceed.

Count

0

0

0

0

0

0

0

Outlier

Count

97

99

99

95

99

100

98

Perc.

Comp.

 1.92

 1.10

 1.18

 3.86

 2.35

 0.66

 1.14

Precision

+3.50

+1.88

+/-1.07

+/-3.25

+/-1.95

+1.16

+1.32

Bias

 100

 100

 100

 100

 100

 100

 100

Complete

100

100

100

100

100

100

100

Complete

 1.41

 1.41

Bias

Y

Y

Y

Y

Y

Y

Y

PQAO Level

Criteria

Y

Y

Y

Y

Y

Y

Y

Aqs Rec 

Flag

Y

Y

Y

Y

Y

Y

Y

CA Rec

Flag

S

S

S

S

S

S

S

Epa 

Eval.

Parameter

2 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

1.40845

- 0.21

- 1.35

- 1.29

 8.55

- 3.52

 1.17

- 0.54

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

Y

Y

Y

Y

Y

Y

Y
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2013

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Sulfur dioxide (42401) (ppb)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 12/31/2013

1

1

1

3

1

04-007-0009

04-007-0011

04-007-0012

04-007-1001

04-013-9997

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

 5.4

 3.3

 1.9

 6.9

 0.8

Mean

 2.0

 0.0

 0.0

 0.0

 0.0

Min

 193.0

 205.0

 171.0

 310.0

 7.8

Max Exceed.

Count

0

0

0

0

0

Outlier

Count

100

92

92

97

88

Perc.

Comp.

 3.20

 5.57

 14.67

 5.26

 16.53

Precision

+5.67

+/-4.50

+9.33

+/-4.19

+11.71

Bias

 100

 100

 100

 96

 100

Complete

100

100

100

100

100

Complete Bias

Y

Y

Y

Y

Y

PQAO Level

Criteria

Y

Y

Y

Y

Y

Aqs Rec 

Flag

Y

Y

Y

Y

Y

CA Rec

Flag

S

S

S

S

S

Epa 

Eval.

Submitter Comment An audit performed on 11/21/13 failed. A previous aud

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

 7.53

 10.33

 5.90

 1.88

 3.11

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

Y

Y

Y

Y

Y
Data Evaluation and Concurrence Report for Particulate Matter

2013

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) CONTINUOUS

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/08/2013

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete Bias

%

Complete

Routine Data (ug/m3) Flow Rate Verification Flow Rate Audit Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Eval.

04-003-0011

04-003-1005

04-007-1001

04-007-8000

04-013-9997

04-015-1003

04-019-0001

04-019-0020

04-023-0004

04-027-8011

3

3

3

3

3

3

3

3

3

3

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SPECIAL 

PURPOSE

SLAMS

 21.21

 37.72

 43.37

 22.90

 30.68

 21.20

 29.02

 40.84

 46.47

 41.50

-21.0

-22.0

-30.0

-34.0

 2.0

-26.0

-16.0

-18.0

 2.0

-43.0

********

 924.0

********

 405.0

********

 568.0

********

********

 985.0

********

0

0

0

0

0

0

0

0

0

0

91

99

97

97

99

97

99

99

75

97

AQS Site ID POC

+/-1.50

+/-0.97

+/-2.49

+/-1.17

+/-0.85

+/-0.99

+/-1.73

+/-0.81

+/-5.27

+/-1.30

100

100

100

100

100

100

100

100

100

100

-3.15

-1.18

-2.79

-1.41

+1.08

+0.19

-2.87

-0.05

-1.04

-0.18

100

100

100

70

100

100

100

100

100

100

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Submitter Comment: Two flow rate audits were peformed on this monitor during 

2013. One was performed in 1st quarter on March 6, 2013 

and one was performed in 3rd quarter on July 25, 2013. 

These two audits were less than five months apart, which 

is the reason why the AMP 60

EPA Comment:

QAPP

Appr.

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

S

S

S

S

S

S

S

S

S

S
Data Evaluation and Concurrence Report for Particulate Matter

2013

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) INTERMITTENT

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/08/2013

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Met?

4 1 1 100 7.31 8.39 Y

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Eval.

04-005-1008

04-007-0008

04-007-0008

04-023-0004

04-025-2002

1

1

2

1

1

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

 15.90

 19.15

 18.49

 35.66

 11.91

 2.0

 2.0

 2.0

 5.0

 2.0

 30.0

 58.0

 54.0

 89.0

 51.0

0

0

0

0

0

0

0

0

0

0

100

98

95

96

91

AQS Site ID POC

-0.68

-0.36

-0.13

-1.51

-1.39

100

100

100

100

100

 8.39 100

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

QAPP

Appr.

Y

Y

Y

Y

Y

S

S

S

S

S
Data Evaluation and Concurrence Report for Particulate Matter

2013

2013

Arizona Department Of Environmental Quality (0053)

Freeport McMoRan Miami, Inc. (1357)

Certifying Year:

Certifying Year:

Certifying Agency:

Certifying Agency:

PM2.5 - Local Conditions (88101) 

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/08/2013

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Method Met?

143

170

6

3

1

1

1

1

100

100

 2.74

 13.93

 3.68

 16.50

Y

Y

PEP Summary

#

Methods

# Audited

Methods

# PEP

Required

# PEP

Submitted

%

Complete Bias

Criteria

Met?

2 0 8 6 75 +4.62 Y

Monitors Summaries

Method

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

PEP

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Eval.

04-003-1005

04-003-1005

04-005-1008

04-013-9997

04-013-9997

04-023-0004

04-023-0004

04-025-2002

04-027-8011

04-027-8011

04-023-0004

1

3

1

1

3

1

2

1

1

3

3

143

170

143

143

170

143

143

143

143

170

170

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SPECIAL 

PURPOSE

 7.25

 6.75

 5.43

 8.41

 7.18

 9.91

 9.63

 4.14

 8.84

 6.10

 8.76

 2.4

-8.0

 1.0

 1.9

-8.0

 3.5

 2.5

 1.1

 1.1

-8.0

-6.0

 17.5

 65.0

 11.1

 40.5

 454.0

 35.0

 34.2

 9.7

 26.7

 213.0

 337.0

0

0

0

0

0

0

0

0

0

0

0

96

91

100

100

91

96

93

96

100

89

85

AQS Site ID POC

-0.83

-2.22

-0.65

-1.36

-1.44

-1.27

-1.94

-0.48

-0.75

-0.78

-1.07

100

100

100

100

100

100

100

100

100

100

50

50

100

 3.68

 16.50

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

N

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Submitter Comment: At Nogales Post Office during the 1st quarter of 2013, the 

PM2.5 data were collected under non-FEM method with 

parameter code 88501; and during the rest of 2013 the 

PM2.5 data were collected under FEM method with 

parameter code 88101. The flow rate audit

EPA Comment:

QAPP

Appr.

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

S

S

S

S

S

S

S

S

S

S

S
Data Evaluation and Concurrence Report for Particulate Matter

2013

Freeport McMoRan Miami, Inc. (1357)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) INTERMITTENT

Freeport McMoRan Miami, Inc. (1357)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date:

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Met?

2 1 1 100 8.76 10.02 Y

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Eval.

04-007-0009

04-007-8000

04-007-8000

1

1

2

INDUSTRI

AL

INDUSTRI

AL

INDUSTRI

AL

 12.76

 16.70

 17.35

 2.0

 2.0

 2.0

 51.0

 55.0

 54.0

0

0

0

0

0

0

96

100

95

AQS Site ID POC

+0.31

-0.31

-0.15

100

100

100

 10.02 100

Y

Y

Y

Y

Y

Y

QAPP

Appr.

Y

Y

Y
Data Concurrence and Evaluation Report for Lead

Certification Year 2013

Certifying Agency Name: Arizona Department Of Environmental Quality (0053)

Lead (TSP) LC (14129)

Lead PM10 LC FRM/FEM (85129)

Arizona Department Of Environmental Quality (0053)

Arizona Department Of Environmental Quality (0053)

PQAO Name:

PQAO Name:

Y

Y

Criteria

Met

Criteria

Met

+/-8.82

-6.68

Bias

Bias

 100

 100

Percent

Complete

Percent

Complete

24

24

Number

Submitted

Number

Submitted

24

24

Number

Required

Number

Required

Y

Criteria

Met

Criteria

Met

Bias

Bias

 0

 0

Percent

Complete

Percent

Complete

0

0

Number of 

Audits

Submitted

Number of 

Audits

Submitted

1

1

Number of 

PEP Audits 

Required

Number of 

PEP Audits 

Required

0

0

Number of 

Methods 

Audited

Number of 

Methods 

Audited

1

1

Number of

Methods

Number of

Methods

Y

Criteria

Met

Criteria

Met

 6.37

 1.54

CV UB

CV UB

 5.40

 0.68

CV

Est

CV

Est

 100

 100

Percent

Collocated

Percent

Collocated

1

1

Number of 

Actual

Colloc Sites

Number of 

Actual

Colloc Sites

1

1

Number of 

Colloc Sites 

Required

Number of 

Colloc Sites 

Required

2

1

Number 

of Sites

Number 

of Sites

Collocation Summary:

Collocation Summary:

01/22/2013

01/22/2013

Quality Assurance Project Plan Approval Date:

Quality Assurance Project Plan Approval Date:

Analysis Audit Summary:

Analysis Audit Summary:

PEP Summary

PEP Summary

AQS Site-ID

AQS Site-ID

POC

POC

Monitor

Type

Monitor

Type

Mean

Mean

Min

Min

Max

Max

Exceed.

Count

Exceed.

Count

Outlier

Count

Outlier

Count

Percent

Comp.

Percent

Comp.

Bias

Bias

Percent

Comp.

Percent

Comp.

CV UB

CV UB

Percent

Comp.

Percent

Comp.

PQAO

Crit. Met

PQAO

Crit. Met

PQAO

Crit. Met

PQAO

Crit. Met

Analysis

Crit. Met

Analysis

Crit. Met

AQS 

Rec. V

AQS 

Rec. V

CA Rec

Value

CA Rec

Value

EPA

Eval.

EPA

Eval.

Monitors Recommended for Certification

Monitors Recommended for Certification

Routine Data (ug/m^3)

Routine Data (ug/m^3)

Flow Rate Audit

Flow Rate Audit

Collocation

Collocation

PEP

PEP

Lead

Lead

Certification

Certification

04-007-1002

04-007-1002

04-007-8000

04-013-9997

1

2

1

1

SLAMS

SLAMS

SLAMS

SLAMS

 0.077

 0.077

 0.019

 0.0033

 0.001

 0.001

 0.001

 0.0006

 0.501

 0.502

 0.091

 0.0109

0

0

0

0

0

0

0

0

 100

 96

 100

 100

+1.64

-0.29

-3.05

-2.12

 100

 100

 100

 100

 6.37

 1.54

 100

 13

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

S

S

S

S

QAPP

Appr.

QAPP

Appr.

Y

Y

Y

Y