Final 

First Quarter 2013 - Quarterly 

Groundwater Monitoring Report 

Outside Tunnel Wells 

Red Hill Bulk Fuel Storage Facility 

Joint Base Pearl Harbor-Hickam, Oahu, Hawaii 

DOH Facility ID: 9-102271 

DOH Release ID: 990051, 010011, and 020028 

April 2013 

Department of the Navy 

Naval Facilities Engineering Command, Hawaii 

400 Marshall Road 

JBPHH, HI 96860-3139 

Contract Number N62742-12-D-1853, CTO 0002 
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Final 

First Quarter 2013 - Quarterly 

Groundwater Monitoring Report 

Outside Tunnel Wells 

Red Hill Bulk Fuel Storage Facility 

Joint Base Pearl Harbor-Hickam, Oahu, Hawaii 

DOH Facility ID: 9-102271 

DOH Release ID: 990051, 010011, and 020028 

April 2013

Prepared for: 

Department of the Navy 

Naval Facilities Engineering Command, Hawaii 

400 Marshall Road 

JBPHH, HI 96860-3139 

Prepared by: 

Environmental Science International, Inc. 

354 Uluniu Street, Suite 304 

Kailua, HI 96734 

Prepared under: 

Contract Number N62742-12-D-1853, CTO 0002
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FINAL 

FIRST QUARTER 2013 - QUARTERLY GROUNDWATER MONITORING REPORT 

OUTSIDE TUNNEL WELLS 

RED HILL BULK FUEL STORAGE FACILITY

Long-Term Groundwater and Soil Vapor Monitoring 

Red Hill Bulk Fuel Storage Facility 

Joint-Base Pearl Harbor-Hickam, Oahu, Hawaii 

Prepared for: 

Department of the Navy 

Commanding Officer, Naval Facilities Engineering Command, Hawaii 

400 Marshall Road 

JBPHH, HI 96860-3139 

Prepared by: 

Environmental Science International, Inc. 

354 Uluniu Street, Suite 304 

Kailua, HI 96734 

(808) 261-0740 

Prepared under: 

Contract Number: N62742-12-D-1853 

Contract Task Order: 0002 

Approval Signature: 

 Darren Uchima, Navy Technical Representative Date 

Approval Signature: 4/19/2013 

 Robert Chong, ESI Project Manager Date 

Approval Signature: 4/19/2013 

 Traci Sylva, ESI QA Manager Date 
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TABLE OF CONTENTS 

Section Title Page

ES EXECUTIVE SUMMARY ES-1

 

1.0 INTRODUCTION 1-1

1.1 Site Description 1-1

1.2 Physical Settings 1-2

1.3 Background 1-3

 

2.0 GROUNDWATER SAMPLING 2-1

2.1 Groundwater Sampling 2-1

2.2 Analytical Results 2-1

2.3 Waste Disposal 2-2

3.0 DATA QUALITY ASSESSMENT 3-1

3.1 Data Validation and Assessment 3-1

3.2 Data Assessment and Usability Conclusions 3-3

 

4.0 SUMMARY, CONCLUSIONS, AND RECOMMENDATIONS 4-1

5.0 FUTURE WORK 5-1

 

6.0 REFERENCES 6-1
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LIST OF TABLES 

Number Title Page

1.1 Current Status of USTs 1-2

2.1 Analytical Results for Groundwater Sampling (January 30, 2013) 2-3

3.1 Quality Control Results for Groundwater Sampling (January 30, 2013) 3-5

 

 

LIST OF FIGURES 

Number Title 

1 Site Location 

2 Site Layout 

 

 

APPENDICES 

Appendix Title 

A Groundwater Sampling Logs 

B Field Notes 

C 

D 

Laboratory Reports 

Historical Groundwater Exceedance Trends 

E Waste Disposal Manifest 
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ACRONYMS AND ABBREVIATIONS 

ACRONYMS/ 

ABBREVIATIONS DEFINITION/MEANING 

% percent 

COPC Contaminant of Potential Concern 

DLNR State of Hawaii Department of Land and Natural Resources 

DOH State of Hawaii Department of Health 

DON Department of the Navy 

EAL Environmental Action Level 

EPA Environmental Protection Agency 

ESI Environmental Science International 

F-76 Marine Diesel Fuel 

ID Identification 

JBPHH Joint Base Pearl Harbor-Hickam 

JP-5 Jet Fuel Propellant-5 

JP-8 Jet Fuel Propellant-8 

LCS Laboratory Control Sample 

LCSD Laboratory Control Sample Duplicate 

LOD Limit of Detection 

LOQ Limit of Quantitation 

μg/L micrograms per Liter 

MS Matrix Spike 

MSD Matrix Spike Duplicate 

NAVFAC Naval Facilities Engineering Command 

NAVSUP FLC Naval Supply Systems Command Fleet Logistics Center 

N.D. Not Detected 

PAH Polycyclic Aromatic Hydrocarbons 

PARCCS Precision, Accuracy, Representativeness, Completeness, Comparability, 

and Sensitivity 

pH hydrogen activity 

QC Quality Control 

RHSF Red Hill Bulk Fuel Storage Facility 

RPD Relative Percent Difference 

SAP Sampling and Analysis Plan 

TEC The Environmental Company, Inc. 

TPH-d Total Petroleum Hydrocarbons as diesel 

TPH-g Total Petroleum Hydrocarbons as gasoline 

U.S. United States of America 

UST Underground Storage Tank 

VOC Volatile Organic Compounds 

WP Work Plan 
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EXECUTIVE SUMMARY 

This quarterly monitoring report presents the results of the first quarter 2013 groundwater 

sampling event conducted on January 30, 2013, at the outside tunnel wells of the Red Hill Bulk 

Fuel Storage Facility [RHSF], Joint Base Pearl Harbor-Hickam [JBPHH], Hawaii. The RHSF is 

located in Halawa Heights on the Island of Oahu. There are 18 active and 2 inactive 

underground storage tanks [USTs] located at the RHSF. The State of Hawaii Department of 

Health [DOH] Facility Identification [ID] number is 9-102271. The DOH Release ID numbers are 

990051, 010011, and 020028. 

The groundwater sampling was conducted as part of the long-term groundwater and soil vapor 

monitoring at the RHSF, under Naval Facilities Engineering Command [NAVFAC] Contract 

Number N62742-12-D-1853. The sampling was conducted in accordance with the approved 

Work Plan [WP]/Sampling and Analysis Plan [SAP] prepared by Environmental Science 

International [ESI]. 

On January 30, 2013, ESI personnel collected groundwater samples from two outside tunnel 

monitoring wells (wells HDMW2253-03 and OWDFMW01). A summary of the analytical results 

is provided below. 

 HDMW2253-03 – Total Petroleum Hydrocarbons as diesel [TPH-d] (600 micrograms per 

Liter [μg/L]) and naphthalene (0.37 μg/L) were detected. TPH-d was detected at a 

concentration above the DOH Environmental Action Levels [EALs] for both drinking water 

toxicity and gross contamination. 

 OWDFMW01 – TPH-d (1,000 μg/L), acetone (17 μg/L), naphthalene (0.032-0.039 μg/L), and 

benzene (0.39 μg/L) were detected. TPH-d was detected at a concentration above the DOH 

EALs for both drinking water toxicity and gross contamination. 

Since the wells were last sampled (November 2012), with the exception of TPH-d, groundwater 

contaminant concentrations remained at low concentrations and did not change significantly, or 

were not detected. TPH-d concentrations increased in well HDMW2253-03 and decreased in 

well OWDFMW01. The TPH-d concentration detected in HDMW2253-03 was the highest 

concentration detected since quarterly groundwater monitoring was initiated in 2009. TPH-d 

concentrations increased from 25 μg/L during the last round of sampling to 600 μg/L during this 

round of sampling. TPH-d concentrations in well OWDFMW01 decreased from 2,500 μg/L 

during the last round of sampling to 1,000 μg/L during this round of sampling. 

Based on the results of the assessment, we recommend continuing the groundwater monitoring 

program at the RHSF. If the TPH-d concentrations continue to systemically increase, we 

recommend increasing monitoring frequency to monthly even though the two outside wells are 

not included in the RHSF Groundwater Protection Plan. 
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SECTION 1 – INTRODUCTION 

This quarterly monitoring report presents the results of the first quarter 2013 groundwater 

sampling event conducted on January 30, 2013, at the outside tunnel wells of the RHSF, 

JBPHH, Hawaii. The RHSF is located in Halawa Heights on the Island of Oahu. The purpose of 

the sampling is to (1) assess the condition of groundwater beneath and in the vicinity of the 

RHSF with respect to chemical constituents associated with jet fuel propellant and marine diesel 

fuel, and (2) to ensure the Navy remains in compliance with DOH UST release response 

requirements as described in Hawaii Administrative Rules 11-281 Subchapter 7, Release 

Response Action (DOH, 2000). The DOH Facility ID number for the RHSF is 9-102271. The 

DOH Release ID numbers are 990051, 010011, and 020028. 

The groundwater sampling was conducted as part of the long-term groundwater and soil vapor 

monitoring at the RHSF, under NAVFAC Contract Number N62742-12-D-1853. The sampling 

was conducted in accordance with the approved WP/SAP prepared by ESI (ESI, 2012a). 

1.1 SITE DESCRIPTION

The RHSF is located on federal government land (zoned F1- Military and Federal), located in 

Halawa Heights, approximately 2.5 miles northeast of Pearl Harbor (Figure 1). It is located on a 

low ridge on the western edge of the Koolau Mountain Range that divides Halawa Valley from 

Moanalua Valley. The RHSF is bordered on the north by Halawa Correctional Facility and 

private businesses, on the west by the United States of America [U.S.] Coast Guard reservation, 

on the south by residential neighborhoods, and on the east by Moanalua Valley. A quarry is 

located less than a quarter mile away to the northwest. The RHSF occupies 144 acres of land 

and the majority of the site is at an elevation of approximately 200 to 500 feet above mean sea 

level. 

The RHSF contains 18 active and 2 inactive USTs, which are operated by Naval Supply 

Systems Command Fleet Logistics Center [NAVSUP FLC] Pearl Harbor (formerly Fleet and 

Industrial Supply Center). Each UST has a capacity of approximately 12.5 million gallons. The 

RHSF is located approximately 100 feet above the basal aquifer. The USTs contain Jet Fuel 

Propellant-5 [JP-5], Jet Fuel Propellant-8 [JP-8], and Marine Diesel Fuel [F-76]. The current 

status of each of the USTs is summarized in Table 1.1. 

Two groundwater monitoring wells (well HDMW2253-03 and OWDFMW01) are located outside 

of the RHSF tunnel system (Figure 2). Well HDMW2253-03 is located at the Halawa 

Correctional Facility (outside the RHSF) and well OWDFMW01 is located at the Oily Waste 

Disposal Facility near Adit 3. Five groundwater monitoring wells (wells RHMW01, RHMW02, 

RHMW03, RHMW05, and RHMW2254-01) are located within the RHSF lower access tunnel. 

(Monitoring data for the five wells located inside the tunnel are included in a separate report.) 
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Monitoring wells RHMW01, RHMW02, RHMW03, and RHMW05 are located inside the 

underground tunnels. Monitoring well RHMW2254-01 is located inside the infiltration gallery of 

the Department of the Navy [DON] Well 2254-01. DON Well 2254-01 is located approximately 

2,400 feet downgradient of the USTs and provides approximately 24 percent [%] of the potable 

water to the Pearl Harbor System, which serves approximately 52,200 military customers. 

NAVFAC Public Works Department operates the infiltration gallery and DON Well 2254-01. 

TABLE 1.1 

Current Status of the USTs 

Red Hill Bulk Fuel Storage Facility 

January 2013 Quarterly Monitoring Report 

Tank Identification Fuel Type Status Capacity 

F-1 None Inactive 12.5 million gallons 

F-2 JP-8 Active 12.5 million gallons 

F-3 JP-8 Active 12.5 million gallons 

F-4 JP-8 Active 12.5 million gallons 

F-5 JP-8 Active 12.5 million gallons 

F-6 JP-8 Active 12.5 million gallons 

F-7 JP-5 Active 12.5 million gallons 

F-8 JP-5 Active 12.5 million gallons 

F-9 JP-5 Active 12.5 million gallons 

F-10 JP-5 Active 12.5 million gallons 

F-11 JP-5 Active 12.5 million gallons 

F-12 JP-5 Active 12.5 million gallons 

F-13 F-76 Active 12.5 million gallons 

F-14 F-76 Active 12.5 million gallons 

F-15 F-76 Active 12.5 million gallons 

F-16 F-76 Active 12.5 million gallons 

F-17 JP-5 Active 12.5 million gallons 

F-18 JP-5 Active 12.5 million gallons 

F-19 None Inactive 12.5 million gallons 

F-20 JP-5 Active 12.5 million gallons 

F-76 Marine Diesel Fuel 

JP-5 Jet Fuel Propellant-5 

JP-8 Jet Fuel Propellant-8

1.2 PHYSICAL SETTINGS

Climatological conditions in the area of the RHSF consist of warm to moderate temperatures 

and low to moderate rainfall. The RHSF is leeward of the prevailing northeasterly trade winds. 

The average annual precipitation is approximately 40 inches, which occurs mainly between 

November and April (State of Hawaii Department of Land and Natural Resources [DLNR], 

1986). Annual pan evaporation is approximately 75 inches (DLNR, 1985). Average 

temperatures range from the low 60’s to high 80’s (degrees Fahrenheit) (Atlas of Hawaii, 1983). 

Oahu consists of the eroded remnants of two shield volcanoes, Waianae and Koolau. The 

RHSF is located on the southwest flank of the Koolau volcanic shield. Lavas erupted during the 

shield-building phase of the volcano belong to the Koolau Volcanic Series (Stearns and Vaksvik, 

1935). Following formation of the Koolau shield, a long period of volcanic quiescence occurred, 
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during which the shield was deeply eroded. Following this erosional period, eruptive activity 

resumed. Lavas and pyroclastic material erupted during this period belong to the Honolulu 

Volcanic Series (Stearns and Vaksvik, 1935). 

In the immediate area of the RHSF, Koolau Volcanic Series lavas dominate, although there are 

consolidated and unconsolidated non-calcareous deposits in the vicinity that consist of alluvium 

generated during erosion of the Koolau volcanic shield. South-southwest of the Site, and in 

isolated exposures to the west, are pyroclastic deposits formed during eruptions from three 

Honolulu Volcanic Series vents, Salt Lake, Aliamanu, and Makalapa (Stearns and Vaksvik, 

1935). Based on established geology and records of the drilled wells (Stearns and Vaksvik, 

1938), the RHSF is underlain by Koolau Volcanic Series basalts. The area of the RHSF is 

classified as Rock Land, where 25 to 90% of the land surface is covered by exposed rock and 

there are only shallow soils (Foote, et al., 1972). 

Groundwater in Hawaii exists in two principal types of aquifers. The first and most important 

type, in terms of drinking water resources, is the basal aquifer. The basal aquifer exists as a 

lens of fresh water floating on and displacing seawater within the pore spaces, fractures, and 

voids of the basalt that forms the underlying mass of each Hawaiian island. In parts of Oahu, 

groundwater in the basal aquifer is confined by the overlying caprock and is under pressure. 

Waters that flow freely to the surface from wells that tap the basal aquifer are referred to as 

artesian. 

The second type of aquifer is the caprock aquifer, which consists of various kinds of unconfined 

and semi-confined groundwater. Commonly, the caprock consists of a thick sequence of nearly 

impermeable clays, coral, and basalt, which separates the caprock aquifer from the basal 

aquifer. The impermeable nature of these materials and the artesian nature of the basal aquifer 

severely restrict the downward migration of groundwater from the upper caprock aquifer. In the 

area of the RHSF, there is no discernible caprock. 

Groundwater in the area of the RHSF is part of the Waimalu Aquifer System of the Pearl Harbor 

Aquifer Sector. The aquifer is classified as a basal, unconfined, flank-type; and is currently used 

as a drinking water source. The aquifer is considered fresh with less than 250 milligrams per 

liter of chloride and is considered an irreplaceable resource with a high vulnerability to 

contamination (Mink and Lau, 1990). 

The nearest drinking water supply well is the DON Well 2254-01, located in the infiltration 

gallery within the RHSF. DON Well 2254-01 is located approximately 2,400 feet downgradient of 

the USTs (Figure 2). 
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1.3 BACKGROUND

The RHSF was constructed by the U.S. Government in the early 1940s. Twenty USTs and a 

series of tunnels were constructed to supply fuel to the Navy. The USTs were constructed of 

steel and they currently contain JP-5, JP-8, and F-76. Several tanks in the past have stored 

DON special fuel oil, DON distillate, aviation gasoline, and motor gasoline (Environet, 2010). 

The fueling system is a self-contained underground unit that was installed into native rock 

comprised primarily of basalt with some interbedded tuffs and breccias (Environet, 2010). Each 

UST measures approximately 245 feet in height and 100 feet in diameter. The upper domes of 

the tanks lie at depths varying between 100 feet and 200 feet below ground surface. 

In response to increasing concentrations of Contaminants of Potential Concern [COPCs] in the 

groundwater monitoring wells within the facility (specifically RHMW02) during the 2008 sampling 

events, quarterly groundwater monitoring was initiated in 2009 at the outside tunnel wells. 

In 2009, groundwater samples were collected from wells RHMW04, OWDFMW01, and 

HDMW2253-03. Samples were collected in August and October 2009. None of the COPCs 

were detected at concentrations exceeding the gross contamination or drinking water toxicity 

DOH EALs. 

In 2010, groundwater samples were collected from wells RHMW04, OWDFMW01, and 

HDMW2253-03. Samples were collected from well RHMW04 in January and April 2010. 

Samples were collected from well OWDFMW01 in January, April, and October 2010. Samples 

were collected from well HDMW2253-03 in January, April, July and October 2010. The COPCs 

concentrations exceeding DOH EALs are summarized below. 

 HDMW2253-03 – TPH-d was detected at a concentration above the gross contamination 

and drinking water toxicity DOH EAL in January 2010 (The Environmental Company, Inc. 

[TEC], 2010a). 

 OWDFMW01 – TPH-d was detected at a concentration above the gross contamination and 

drinking water toxicity DOH EALs in January and April 2010 (TEC, 2010a; TEC, 2010b). 

In 2011, groundwater samples were collected from wells OWDFMW01 and HDMW2253-03. 

Samples were collected in January, April, July, and October 2011. None of the COPCs were 

detected at concentrations exceeding the gross contamination or drinking water toxicity DOH 

EALs. 

In 2012, groundwater samples were collected from wells OWDFMW01 and HDMW2253-03. 

Samples were collected in January, April, July, and November 2012. TPH-d was detected at a 

concentration above the DOH EALs in samples collected from wells HDMW2253-03 and 

OWDFMW01 (Environet, 2012; ESI, 2012b). The COPCs concentrations exceeding DOH EALs 

are summarized below. 
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 HDMW2253-03 – TPH-d was detected at a concentration above the DOH EALs for gross 

contamination and drinking water toxicity in April and November 2012. 

 OWDFMW01 – TPH-d was detected at a concentration above the DOH EALs for gross 

contamination and drinking water toxicity in April 2012. 

1.3.1 Previous Reports 

The following groundwater monitoring reports were previously submitted to the DOH: 

1. Groundwater Monitoring Report, August 2009 (submitted September 2009). 

2. Groundwater Monitoring Report, October 2009 (submitted December 2009). 

3. Groundwater Monitoring Report, January, 2010 (submitted April 2010). 

4. Groundwater Monitoring Report, April 2010 (submitted May 2010). 

5. Groundwater Monitoring Report, July 2010 (submitted August 2010). 

6. Groundwater Monitoring Report, October 2010 (submitted December 2010). 

7. Groundwater Monitoring Report, January 2011 (submitted March 2011). 

8. Groundwater Monitoring Report, April 2011 (submitted June 2011). 

9. Groundwater Monitoring Report, July 2011 (submitted September 2011). 

10. Groundwater Monitoring Report, October 2011 (submitted December 2011). 

11. Groundwater Monitoring Report, January 2012 (submitted March 2012). 

12. Groundwater Monitoring Report, April 2012 (submitted July 2012). 

13. Groundwater Monitoring Report, July 2012 (submitted August 2012). 

14. Groundwater Monitoring Report, November 2012 (submitted January 2013) 
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SECTION 2 – GROUNDWATER SAMPLING 

On January 30, 2013, ESI personnel collected groundwater samples from two monitoring wells 

(wells OWDFMW01 and HDMW2253-03). The samples were collected in accordance with DOH 

UST release response requirements and the RHSF Groundwater Protection Plan (TEC, 2008). 

Prior to purging and sampling, the depth to groundwater and the depth to the bottom of the wells 

were measured. Well OWDFMW01 was measured using a Geotech oil/water interface probe. 

Well HDMW2253-03 was measured by the DLNR using their Geotech oil/water interface probe. 

The measurements are included in the groundwater sampling logs. No measurable product, 

sheen, or petroleum hydrocarbon odor was observed in either well. 

2.1 GROUNDWATER SAMPLING

Prior to collecting groundwater samples, disposable bailers were used to purge groundwater 

from the monitoring wells. The wells were purged at a rate of 0.21 and 0.42 liters per minute. 

Water quality parameters were monitored on a periodic basis during well purging. The water 

quality parameters that were measured included hydrogen activity [pH], temperature, 

conductivity, dissolved oxygen, and oxidation reduction potential. The water quality parameters 

were evaluated to demonstrate that the natural characteristics of the aquifer formation water 

were present within the monitoring well before collecting the sample. At least four readings were 

collected during the purging process. Purging was considered complete when at least three 

consecutive water quality measurements stabilized within approximately 10%. The readings 

were recorded on groundwater monitoring logs which are included in Appendix A. The field 

notes are included in Appendix B. 

When the water quality parameters stabilized, groundwater samples were collected from the 

wells. The disposable bailers were used to collect the groundwater samples from the monitoring 

wells. For each monitoring well, the groundwater samples were collected no more than two 

hours after purging was completed to prevent groundwater interaction with the monitoring well 

casing and atmosphere. Samples collected for dissolved lead were filtered in the field using a 

peristaltic pump and a 0.45 micron filter. 

2.2 ANALYTICAL RESULTS

The samples were analyzed for TPH-d using U.S. Environmental Protection Agency [EPA] 

Method 8015M, total petroleum hydrocarbons as gasoline [TPH-g] and Volatile Organic 

Compounds [VOCs] using EPA Method 8260B, Polycyclic Aromatic Hydrocarbons [PAHs] using 

EPA Method 8270C SIM, and dissolved lead using EPA Method 6020. The analytical results are 

summarized below and in Table 2.1. A copy of the laboratory report is included in Appendix C. 
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 HDMW2253-03 – TPH-d (600 μg/L) and naphthalene (0.037 μg/L) were detected. TPH-d 

was detected at a concentration above the DOH EALs for both drinking water toxicity and 

gross contamination. 

 OWDFMW01 – TPH-d (1,000 μg/L), acetone (17 μg/L), naphthalene (0.032-0.039 μg/L), 

and benzene (0.39 μg/L) were detected. TPH-d was detected at a concentration above the 

DOH EALs for both drinking water toxicity and gross contamination. 

2.2.1 Groundwater Contaminant Trends 

Historical groundwater contaminant concentration trends of COPCs that exceed the DOH EALs 

are presented in Appendix D. A summary of groundwater contaminant trends are provided 

below. 

 HDMW2253-03 – Both TPH-d and naphthalene were detected; however, TPH-g which was 

detected during the previous sampling event in November 2012 (15 μg/L) was not detected 

this round of quarterly sampling. Naphthalene was last detected in July 2010. TPH-d 

concentrations detected during this round of quarterly sampling increased to concentrations 

above the DOH EALs for both drinking water toxicity and gross contamination. TPH-d 

concentrations last exceeded the DOH EALs for both drinking water toxicity and gross 

contamination in April 2012 (160 μg/L). 

 OWDFMW01 – With the exception of TPH-d, groundwater contaminant concentrations 

remained at low concentrations and did not change significantly, or were not detected. TPH-d 

concentrations detected during this round of sampling remained above the DOH EALs for 

both drinking water toxicity and gross contamination, but decreased from the previous 

sampling event in November 2012 (2,500 μg/L). 

Historical groundwater contaminants concentrations above the DOH EALs for both drinking 

water toxicity and gross contamination are presented in Appendix D. 

2.3 WASTE DISPOSAL

The purged groundwater and decontamination water generated during sampling of the wells 

was stored in a 55-gallon drum along with the purged water and decontamination water from the 

inside tunnel wells. The drum was stored onsite at Adit 3. On February 26, 2013, the drum of 

water was picked up by Pacific Commercial Services, LLC and disposed at Unitek Solvent 

Services, Inc. The waste disposal manifest is included in Appendix E. 
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TABLE 2.1 

Analytical Results for Groundwater Sampling (January 30, 2013) 

Red Hill Bulk Fuel Storage Facility 

January 2013 Quarterly Monitoring Report 

Method Chemical 

DOH EALs OWDFMW01 (ES016) OWDFMW01 (E

Drinking Water 

Toxicity

Gross 

Contamination Results Q LOQ LOD DL Results Q LO

EPA 8015B TPH-d 190 100 1,000 50 20 15 1,000 50 EPA 8260B TPH-g 100 100 N.D. U 50 30 13 N.D. U 50 EPA 8270C SIM 

Acenaphthene 370 20 N.D. U 0.2 0.05 0.018 N.D. U 0.2 Acenaphthylene 240 2,000 N.D. U 0.2 0.05 0.021 N.D. U 0.2 Anthracene 1,800 22 N.D. U 0.2 0.05 0.034 N.D. U 0.2 Benzo[a]anthracene 0.092 4.7 N.D. U 0.2 0.05 0.024 N.D. U 0.2 Benzo[g,h,i]perylene 1,500 0.13 N.D. U 0.2 0.05 0.022 N.D. U 0.2 Benzo[a]pyrene 0.2 0.81 N.D. U 0.2 0.05 0.036 N.D. U 0.2 Benzo[b]fluoranthene 0.092 0.75 N.D. U 0.2 0.05 0.025 N.D. U 0.2 Benzo[k]fluoranthene 0.92 0.4 N.D. U 0.2 0.05 0.023 N.D. U 0.2 Chrysene 9.2 1 N.D. U 0.2 0.05 0.019 N.D. U 0.2 Dibenzo[a,h]anthracene 0.0092 0.52 N.D. U 0.2 0.05 0.027 N.D. U 0.2 Fluoranthene 1,500 130 N.D. U 0.2 0.05 0.027 N.D. U 0.2 Fluorene 240 950 N.D. U 0.2 0.05 0.024 N.D. U 0.2 Indeno[1,2,3-cd]pyrene 0.092 0.095 N.D. U 0.2 0.05 0.022 N.D. U 0.2 1,-Methylnaphthalene 4.7 10 N.D. U 0.2 0.05 0.028 N.D. U 0.2 2,-Methylnaphthalene 24 10 N.D. U 0.2 0.05 0.026 N.D. U 0.2 Naphthalene 17 21 0.032 J 0.2 0.05 0.023 0.039 J 0.2 Phenanthrene 240 410 N.D. U 0.2 0.05 0.031 N.D. U 0.2 Pyrene 180 68 N.D. U 0.2 0.05 0.025 N.D. U 0.2 

EPA 8260B 

1,1,1-Trichloroethane 200 970 N.D. U 5 0.5 0.3 N.D. U 5 1,1,2-Trichloroethane 5 50,000 N.D. U 1 0.5 0.38 N.D. U 1 1,1-Dichloroethane 2.4 50,000 N.D. U 5 0.5 0.28 N.D. U 5 1,1-Dichloroethylene 7 1,500 N.D. U 1 0.5 0.43 N.D. U 1 1,2,3-Trichloropropane 0.6 50,000 N.D. U 5 2 0.64 N.D. U 5 1,2,4-Trichlorobenzene 70 3,000 N.D. U 5 1 0.5 N.D. U 5 1,2-Dibromo-3- chloropropane 0.04 10 N.D. U 10 2 1.2 N.D. U 10 1,2-Dibromoethane 0.04 50,000 N.D. U 1 0.5 0.36 N.D. U 1 1,2-Dichlorobenzene 600 10 N.D. U 1 0.5 0.46 N.D. U 1 1,2-Dichloroethane 0.15 7,000 N.D. U 1 0.5 0.24 N.D. U 1 1,2-Dichloropropane 5 10 N.D. U 5 0.5 0.42 N.D. U 5 1,3-Dichlorobenzene 180 5 N.D. U 1 0.5 0.4 N.D. U 1 1,3-Dichloropropene (total of cis/trans) 0.43 50,000 N.D. U 1 0.5 0.25 N.D. U 1 1,4-Dichlorobenzene 75 5 N.D. U 1 0.5 0.43 N.D. U 1 Acetone 22,000 20,000 17 ICH, J 20 10 10 N.D. ICH, U 20 Benzene 5 170 0.39 J 1 0.5 0.14 0.17 J 1 Bromodichloromethane 0.12 50,000 N.D. U 5 0.5 0.21 N.D. U 5 Bromoform 80 510 N.D. IJ, U 10 2 0.5 N.D. IJ, U 10 Bromomethane 8.7 50,000 N.D. U 20 5 3.9 N.D. U 20 Carbon Tetrachloride 5 520 N.D. U 1 0.5 0.23 N.D. U 1 Chlorobenzene 100 50 N.D. U 5 0.5 0.17 N.D. U 5 Chloroethane 21,000 16 N.D. U 10 5 2.3 N.D. U 10 Chloroform 70 2,400 N.D. U 5 0.5 0.46 N.D. U 5 Chloromethane 1.8 50,000 N.D. U 10 2 1.8 N.D. U 10 cis-1,2-Dichloroethylene 70 50,000 N.D. U 1 0.5 0.48 N.D. U 1 Dibromochloromethane 0.16 50,000 N.D. U 1 0.5 0.25 N.D. U 1 Ethylbenzene 700 30 N.D. U 1 0.5 0.14 N.D. U 1 Hexachlorobutadiene 0.86 6 N.D. U 1 0.5 0.32 N.D. U 1 Methyl ethyl ketone (2-Butanone) 7,100 8,400 N.D. U 10 5.0 2.21 N.D. U 10 Methyl isobutyl ketone (4-Methyl-2-Pentanone) 2,000 1300 N.D. U 10 5.0 4.4 N.D. U 10 Methyl tert-butyl Ether 12 5 N.D. U 1 0.5 0.31 N.D. U 1 Methylene chloride 4.8 9,100 N.D. U 5 2.0 0.64 N.D. U 5 Styrene 100 10 N.D. U 1 0.5 0.17 N.D. U 1 Tetrachloroethane, 1,1,1,2- 0.52 50,000 N.D. U 1 0.5 0.4 N.D. U 1 Tetrachloroethane, 1,1,2,2- 0.067 500 N.D. U 1 0.5 0.41 N.D. U 1 Tetrachloroethylene 5 170 N.D. U 5 0.5 0.39 N.D. U 5 Toluene 1,000 40 N.D. U 1 0.5 0.24 N.D. U 1 trans-1,2- Dichloroethylene 100 260 N.D. U 1 0.5 0.37 N.D. U 1 Trichloroethylene 5 310 N.D. U 1 0.5 0.37 N.D. U 1 Vinyl chloride 2 3,400 N.D. U 1 0.5 0.3 N.D. U 1 Xylenes 10,000 20 N.D. U 10 1 0.23 N.D. U 10 

EPA 6020 Dissolved Lead 15 50,000 N.D. U 1 0.2 0.0898 N.D. U 1 

The data are in micrograms per liter (μg/L). Shaded values exceeded the DOH EALs. DOH EALs DOH Tier 1 Environmental Action Levels for groundwater where groundwater is a current drinking water source and surface water is greater than 150 meters from the site (DOH, Fall 2011). LOQ Limit of Quantitation 

DL Detection Limit or Method Detection Limit (MDL) N.D. Not Detected EPA Environmental Protection Agency Q Qualifiers ICH Initial calibration verification recovery above method control limit for this analyte. TPH-g Total Petroleum Hydrocarbons as gasoline IJ Calibration verification recovery above method control limit for this analyte. TPH-d Total Petroleum Hydrocarbons as diesel 

J Analyte was detected at a concentration below the LOQ and above the DL. Reported value is estimated. U Undetected at DL and is reported as less than thLOD Limit of Detection 
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SECTION 3 – DATA QUALITY ASSESSMENT 

A data quality assessment, which consists of a review of the overall groundwater sample 

collection and analysis process, was performed in order to determine whether the analytical 

data generated meet the quality objectives for the project. The field Quality Control [QC] 

program consisted of standardized sample collection and management procedures, and the 

collection of field duplicate samples, matrix spike samples, and trip blank samples. The 

laboratory quality assurance program consisted of the use of standard analytical methods and 

the preparation and analyses of Matrix Spike [MS]/Matrix Spike Duplicate [MSD] samples, 

surrogate spikes, method blanks, Laboratory Control Samples [LCS] and Laboratory Control 

Sample Duplicate [LCSD]. 

3.1 Data Validation and Assessment 

The objective of data validation is to provide data of known quality for project decisions. Data 

quality is judged in terms of its Precision, Accuracy, Representativeness, Completeness, 

Comparability, and Sensitivity [PARCCS]. A number of factors may affect the quality of data, 

including: sample collection methods, sample analysis methods, and adherence to established 

procedures for sample collection, preservation, management, shipment, and analysis. 

Precision 

Precision is defined as the reproducibility of replicate measurements. Precision is evaluated by 

Relative Percentage Difference [RPD] of field duplicates and laboratory LCS/LCSD or MS/MSD 

results. Field duplicate and MS/MSD samples were collected at a rate of approximately 10% of 

project samples. Field duplicates were sent to the laboratory along with the primary samples. 

For this monitoring event, the RPDs for MS/MSD and LCS/LCSD pairs were all within the 

acceptable range except for 1,1,2,2-tetrachloroethane (40%), which is discussed in the next 

section. The RPDs of detected analytes for the primary and field duplicate samples (ES016 and 

ES017) are provided in Table 3.1. The benzene and naphthalene concentrations detected in the 

samples were below the respective limits of quantitation [LOQs] implying a higher uncertainty 

for these results than for values detected above the LOQs (i.e. estimated, J-flagged). 

Consequently, the assigned RPDs signified the anticipated decrease in precision below the 

LOQs but were not indicative of a QC issue. TPH-d was detected above the DOH EAL, and with 

excellent precision (RPD = 0%). Therefore the data precision is considered acceptable. 

Accuracy 

Accuracy is defined as the degree of conformity of a measurement to a standard or true value. 

Accuracy is evaluated through measurement of the percent recovery of an analyte in a 

reference standard or spiked sample. Accuracy limits for surrogates, laboratory control spike, 

MS, and MSD samples are established by the individual laboratory. The acceptance criteria for 

accuracy are dependent on the analytical method and are based on historical laboratory data. 
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All of the LCS and surrogate spike recoveries for analyzed constituents were within acceptable 

percent recovery limits. The MS/MSD recoveries for tetrachloroethylene and trichloroethylene 

were high, and the MS/MSD recovery for 1,1,2,2-tetrachloroethane was low. The MS/MSD 

recoveries for the three analytes were outside of the control limits. However, the analyte 

concentrations detected in the samples were below the respective LOQs, implying a higher 

uncertainty for these results than for values detected above the LOQs. Consequently, the 

assigned RPDs signified the anticipated decrease in precision below the LOQs but were not 

indicative of a QC issue. All other MS/MSD recoveries were within acceptable recovery limits; 

therefore, the data accuracy for this monitoring event is considered acceptable. 

 

Representativeness 

Representativeness is the degree that data accurately and precisely represents a characteristic 

of a population, parameter variations at a sampling point, or an environmental condition. 

Representativeness was achieved by conducting sampling in compliance with the sample 

collection procedures described in the WP/SAP specifically written for this project (ESI, 2012a). 

Representativeness is also evaluated through the compliance with the sample holding time, 

sample preservation, and the analysis of blank samples, including method blank and trip blank 

samples. The sample holding time and sample preservation complied with the EPA criteria. For 

this sampling event, one trip blank was included in the cooler to assess cross contamination 

during sample transport for TPH-g and VOCs. There was no detection of VOCs in the method 

blank. TPH-g was detected in the trip blank below the LOD, and was qualified (J), and implied a 

high uncertainty for the result and was not indicative of a QC issue. Therefore, the groundwater 

sample data are considered representative of the groundwater quality on site. 

Completeness 

Completeness is defined as the overall percentage of valid analytical results (including 

estimated results) compared to the total number of analytical results reported by the laboratory. 

No data were rejected for this project, and therefore the completeness goal for this project 

(90%) was successfully met. Successful completion of data acquisition can only be 

accomplished if both the field and laboratory portions of the project are performed according to 

the procedures described in the WP/SAP (ESI, 2012a). 

Comparability 

Comparability expresses the confidence with which one data set can be compared to another 

data set. Comparability can be related to accuracy and precision because these quantities are 

measures of data reliability. Data, with acceptable precision and accuracy, are considered 

comparable if collection techniques, analytical procedures, methods and reporting are 

equivalent. For this monitoring event, the samples were collected using approaches consistent 

with those in the previous events, and the same analytical methods/procedures were used to 

measure the concentration of COPCs. Therefore, the results are considered comparable within 

this data set and with the data collected from previous sampling events. 
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Sensitivity 

The LOQs are established by the laboratory based on the LODs or instrument detection limits, 

historical data, and EPA limits established for the methods. The LOQs for samples may require 

adjustment due to matrix interference or if high levels of target analytes necessitate dilution 

before analysis. Matrix interference and sample dilutions have the effect of increasing the 

LOQs. Laboratory LODs and LOQs for several analytes differed from the LODs and LOQs in the 

WP/SAP because the laboratory updates them quarterly. LODs and LOQs for several analytes 

were greater than the DOH EALs (as stated in the WP/SAP) and therefore it is not possible to 

determine whether the analytes are present at concentrations greater than or equal to the DOH 

EALs. As suggested by the DOH Technical Guidance Manual, the project action level will be the 

LOD for these analytes. 

3.2 Data Assessment and Usability Conclusions 

The PARCCS criteria were evaluated, and with a few exceptions, all criteria were met. These 

exceptions include the exceedances of recovery criteria for MS/MSDs for several VOCs. Since 

the surrogate recoveries and the recoveries of the VOCs in the LCS/LCSD are all within 

recovery criteria, the MS/MSD exceendaces are not considered to affect the usability of the 

data, but may indicate some matrix heterogeneity. Since the data are consistent with data from 

previous events, it appears that the effect of this QC exceedance is not substantial, and the data 

is usable. The data assessment concludes that all data generated during this event are usable 

for their intended use. 
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TABLE 3.1 

Quality Control Results for Groundwater Sampling (January 30, 2013) 

Red Hill Bulk Fuel Storage Facility 

January 2013 Quarterly Monitoring Report

Method Chemical Constituent 

DOH EALs OWDFMW01 (ES016) OWDFMW01 (ES0

Drinking Water 

Toxicity

Gross 

Contamination Results Q LOQ LOD DL Results Q LOQ 

EPA 8015B TPH-d 190 100 1,000 50 20 15 1,000 50 EPA 8260B TPH-g 100 100 N.D. U 50 30 13 N.D. U 50 EPA 8270C SIM 

Acenaphthene 370 20 N.D. U 0.2 0.05 0.018 N.D. U 0.2 Acenaphthylene 240 2,000 N.D. U 0.2 0.05 0.021 N.D. U 0.2 Anthracene 1,800 22 N.D. U 0.2 0.05 0.034 N.D. U 0.2 Benzo[a]anthracene 0.092 4.7 N.D. U 0.2 0.05 0.024 N.D. U 0.2 Benzo[g,h,i]perylene 1,500 0.13 N.D. U 0.2 0.05 0.022 N.D. U 0.2 Benzo[a]pyrene 0.2 0.81 N.D. U 0.2 0.05 0.036 N.D. U 0.2 Benzo[b]fluoranthene 0.092 0.75 N.D. U 0.2 0.05 0.025 N.D. U 0.2 Benzo[k]fluoranthene 0.92 0.4 N.D. U 0.2 0.05 0.023 N.D. U 0.2 Chrysene 9.2 1 N.D. U 0.2 0.05 0.019 N.D. U 0.2 Dibenzo[a,h]anthracene 0.0092 0.52 N.D. U 0.2 0.05 0.027 N.D. U 0.2 Fluoranthene 1,500 130 N.D. U 0.2 0.05 0.027 N.D. U 0.2 Fluorene 240 950 N.D. U 0.2 0.05 0.024 N.D. U 0.2 Indeno[1,2,3-cd]pyrene 0.092 0.095 N.D. U 0.2 0.05 0.022 N.D. U 0.2 1,-Methylnaphthalene 4.7 10 N.D. U 0.2 0.05 0.028 N.D. U 0.2 2,-Methylnaphthalene 24 10 N.D. U 0.2 0.05 0.026 N.D. U 0.2 Naphthalene 17 21 0.032 J 0.2 0.05 0.023 0.039 J 0.2 Phenanthrene 240 410 N.D. U 0.2 0.05 0.031 N.D. U 0.2 Pyrene 180 68 N.D. U 0.2 0.05 0.025 N.D. U 0.2 

EPA 8260B 

1,1,1-Trichloroethane 200 970 N.D. U 5 0.5 0.3 N.D. U 5 1,1,2-Trichloroethane 5 50,000 N.D. U 1 0.5 0.38 N.D. U 1 1,1-Dichloroethane 2.4 50,000 N.D. U 5 0.5 0.28 N.D. U 5 1,1-Dichloroethylene 7 1,500 N.D. U 1 0.5 0.43 N.D. U 1 1,2,3-Trichloropropane 0.6 50,000 N.D. U 5 2 0.64 N.D. U 5 1,2,4-Trichlorobenzene 70 3,000 N.D. U 5 1 0.5 N.D. U 5 1,2-Dibromo-3- chloropropane 0.04 10 N.D. U 10 2 1.2 N.D. U 10 1,2-Dibromoethane 0.04 50,000 N.D. U 1 0.5 0.36 N.D. U 1 1,2-Dichlorobenzene 600 10 N.D. U 1 0.5 0.46 N.D. U 1 1,2-Dichloroethane 0.15 7,000 N.D. U 1 0.5 0.24 N.D. U 1 1,2-Dichloropropane 5 10 N.D. U 5 0.5 0.42 N.D. U 5 1,3-Dichlorobenzene 180 5 N.D. U 1 0.5 0.4 N.D. U 1 1,3-Dichloropropene (total of cis/trans) 0.43 50,000 N.D. U 1 0.5 0.25 N.D. U 1 1,4-Dichlorobenzene 75 5 N.D. U 1 0.5 0.43 N.D. U 1 Acetone 22,000 20,000 17 ICH, J 20 10 10 N.D. ICH, U 20 Benzene 5 170 0.39 J 1 0.5 0.14 0.17 J 1 Bromodichloromethane 0.12 50,000 N.D. U 5 0.5 0.21 N.D. U 5 Bromoform 80 510 N.D. IJ, U 10 2 0.5 N.D. IJ, U 10 Bromomethane 8.7 50,000 N.D. U 20 5 3.9 N.D. U 20 Carbon Tetrachloride 5 520 N.D. U 1 0.5 0.23 N.D. U 1 Chlorobenzene 100 50 N.D. U 5 0.5 0.17 N.D. U 5 Chloroethane 21,000 16 N.D. U 10 5 2.3 N.D. U 10 Chloroform 70 2,400 N.D. U 5 0.5 0.46 N.D. U 5 Chloromethane 1.8 50,000 N.D. U 10 2 1.8 N.D. U 10 cis-1,2-Dichloroethylene 70 50,000 N.D. U 1 0.5 0.48 N.D. U 1 Dibromochloromethane 0.16 50,000 N.D. U 1 0.5 0.25 N.D. U 1 Ethylbenzene 700 30 N.D. U 1 0.5 0.14 N.D. U 1 Hexachlorobutadiene 0.86 6 N.D. U 1 0.5 0.32 N.D. U 1 Methyl ethyl ketone (2-Butanone) 7,100 8,400 N.D. U 10 5.0 2.21 N.D. U 10 Methyl isobutyl ketone (4-Methyl-2-Pentanone) 2,000 1300 N.D. U 10 5.0 4.4 N.D. U 10 Methyl tert-butyl Ether 12 5 N.D. U 1 0.5 0.31 N.D. U 1 Methylene chloride 4.8 9,100 N.D. U 5 2.0 0.64 N.D. U 5 Styrene 100 10 N.D. U 1 0.5 0.17 N.D. U 1 Tetrachloroethane, 1,1,1,2- 0.52 50,000 N.D. U 1 0.5 0.4 N.D. U 1 Tetrachloroethane, 1,1,2,2- 0.067 500 N.D. U 1 0.5 0.41 N.D. U 1 Tetrachloroethylene 5 170 N.D. U 5 0.5 0.39 N.D. U 5 Toluene 1,000 40 N.D. U 1 0.5 0.24 N.D. U 1 trans-1,2- Dichloroethylene 100 260 N.D. U 1 0.5 0.37 N.D. U 1 Trichloroethylene 5 310 N.D. U 1 0.5 0.37 N.D. U 1 Vinyl chloride 2 3,400 N.D. U 1 0.5 0.3 N.D. U 1 Xylenes 10,000 20 N.D. U 10 1 0.23 N.D. U 10 

EPA 6020 Dissolved Lead 15 50,000 N.D. U 1 0.2 0.0898 N.D. U 1 

The data are in micrograms per liter (μg/L). Shaded values exceeded the DOH EALs. DOH EALs DOH Tier 1 Environmental Action Levels for groundwater where groundwater is a current drinking water source and surface water is greater than 150 meters from the site (DOH, Fall 2011). LOQ Limit of Quantitation 

DL Detection Limit or Method Detection Limit (MDL) NA Both results for duplicate pair were non-detect, no REPA Environmental Protection Agency N.D. Not Detected ICH Initial calibration verification recovery above method control limit for this analyte. Q Qualifiers IJ Calibration verification recovery above method control limit for this analyte. TPH-g Total Petroleum Hydrocarbons as gasoline J Analyte was detected at a concentration below the LOQ and above the DL. Reported value is estimated. TPH-d Total Petroleum Hydrocarbons as diesel LOD Limit of Detection U Undetected at DL and is reported as less than the L
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SECTION 4 – SUMMARY, CONCLUSIONS, AND RECOMMENDATIONS 

This quarterly monitoring report presents the results of groundwater sampling conducted on 

January 30, 2013, at the RHSF, JBPHH, Hawaii. The RHSF is located in Halawa Heights on 

the Island of Oahu. The DOH Facility ID number for the RHSF is 9-102271. The DOH Release 

ID numbers are 990051, 010011, and 020028. 

The groundwater sampling was conducted as part of the long-term groundwater and soil 

vapor monitoring at the RHSF, under NAVFAC Contract Number N62742-12-D-1853. The 

sampling was conducted in accordance with the approved WP/SAP prepared by ESI. 

On January 30, 2013, ESI personnel collected groundwater samples from two monitoring 

wells (wells HDMW2253-03 and OWDFMW01). A summary of the analytical results is 

provided below. 

 HDMW2253-03 – TPH-d (600 μg/L) and naphthalene (0.037 μg/L) were detected. TPH-d 

was detected at a concentration above the DOH EALs for both drinking water toxicity and 

gross contamination.

 OWDFMW01 – TPH-d (1,000 μg/L), acetone (17 μg/L), benzene (0.39 μg/L), and 

naphthalene (0.032 μg/L) were detected. TPH-d was detected at a concentration above 

the DOH EALs for both drinking water toxicity and gross contamination. 

Groundwater Contaminant Trends 

Historical groundwater contaminant concentration trends of COPCs that exceed the DOH 

EALs are presented in Appendix D. A summary of groundwater contaminant trends are 

provided below. 

 HDMW2253-03 – Both TPH-d and naphthalene were detected; however, TPH-g which 

was detected during the previous sampling event in November 2012 (15 μg/L) was not 

detected this round of quarterly sampling. Naphthalene was last detected in July 2010. 

TPH-d concentrations detected during this round of quarterly sampling increased to 

concentrations above the DOH EALs for both drinking water toxicity and gross 

contamination. TPH-d concentrations last exceeded the DOH EALs for both drinking water 

toxicity and gross contamination in April 2012 (160 μg/L). 

 OWDFMW01 – With the exception of TPH-d, groundwater contaminant concentrations 

remained at low concentrations and did not change significantly, or were not detected. 

TPH-d concentrations detected during this round of sampling remained above the DOH 

EALs for both drinking water toxicity and gross contamination, but decreased from the 

previous sampling event in November 2012 (2,500 μg/L). 
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Conclusions and Recommendations 

Since the wells were last sampled (November 2012), with the exception of TPH-d, 

groundwater contaminant concentrations remained at low concentrations and did not change 

significantly, or were not detected. TPH-d concentrations increased in well HDMW2253-03 

and decreased in well OWDFMW01. The TPH-d concentration detected in HDMW2253-03 

was the highest concentration detected since quarterly groundwater monitoring was initiated 

in 2009. TPH-d concentrations increased from 25 μg/L during the last round of sampling to 

600 μg/L during this round of sampling. TPH-d concentrations in well OWDFMW01 decreased 

from 2,500 μg/L during the last round of sampling to 1,000 μg/L. 

Based on the results of the assessment, we recommend continuing the groundwater 

monitoring program at the RHSF. If the TPH-d concentrations continue to systemically 

increase, we recommend increasing monitoring frequency to monthly even though the two 

outside wells are not included in the RHSF Groundwater Protection Plan. 
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SECTION 5 – FUTURE WORK 

GROUNDWATER SAMPLING

Future work includes the second quarter 2013 groundwater monitoring which is scheduled for 

April 2013. It is anticipated that the quarterly groundwater monitoring status report will be 

submitted in May 2013. 
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SECTION 6 – REFERENCES 

Atlas of Hawaii, 1983, Department of Geography, University of Hawaii Press. 

DLNR, 1985, Pan Evaporation: State of Hawai’i 1894-1983: Report R74, Division of Water and 

Land Development, August 1995. 

DLNR, 1986, Rainfall Atlas of Hawaii: Report R76, Division of Water and Land Development, 

June 1986. 

DOH, 2000, Hawaii Department of Health, Technical Guidance Manual for Underground 

Storage Tank Closure and Release Response, March 2000. 

DOH, 2011, Screening for Environmental Hazards at Sites with Contaminated Soil and 

Groundwater, Hawai'i Department of Health, Hazard Evaluation and Emergency Response, 

December 2011. 

DON, 2007, Project Procedures Manual, U.S. Navy Installation Restoration Program, NAVFAC 

Pacific, Prepared for Pacific Division, Naval Facilities Engineering Command (NAVFAC Pacific), 

February 2007. 

Environet, 2010, Work Plan, Long-Term Monitoring, Red Hill Bulk Fuel Storage Facility, Pearl 

Harbor, Oahu, Hawaii, September 2010. 

Environet, 2012, Quarterly Groundwater Monitoring Report-Outside (Non-Tunnel Wells), Red 

Hill Bulk Fuel Storage Facility, Pearl Harbor, Oahu, Hawaii, July 2012. 

ESI, 2012a, Work Plan/Sampling and Analysis Plan, Red Hill Bulk Fuel Storage Facility, Pearl 

Harbor, Oahu, Hawaii, October 2012. 

ESI, 2012b, Fourth Quarter 2012- Quarterly Groundwater Monitoring Report Outside Tunnel 

Wells, Red Hill Bulk Fuel Storage Facility, Pearl Harbor, Oahu, Hawaii, January 2013. 

Foote et al., 1972, Soil Survey of the Islands of Kauai, Oahu, Maui, Molokai, and Lanai, State of 

Hawaii. 

Mink, J. F. and Lau, L. S., 1990, Aquifer Identification and Classification for Oahu: Groundwater 

Protection Strategy for Hawaii: Water Resources Research Center Technical Report No. 179, 

February 1990. 

Stearns, H. T. and Vaksvik, K. N., 1935, Geology and Groundwater Resources of the Island of 

Oahu, Hawaii: Hawaii Div. Hydrogr. Bull. 
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Stearns, H. T. and Vaksvik, K. N., 1938, Records of the Drilled Wells on the Island of Oahu, 

Hawaii: Hawaii Div. Hydrogr. Bull. 4, 213 p. 

TEC, 2008, Final Groundwater Protection Plan, Red Hill Fuel Storage Facility, Prepared for 

Navy Region Hawaii, Pearl Harbor, Hawaii, January 2008. 

TEC, 2010a, Quarterly Groundwater Monitoring Report – Outside (Non-Tunnel) Wells, Prepared 

for Navy Region Hawaii, Pearl Harbor, Hawaii, April 2010. 

TEC, 2010b, Quarterly Groundwater Monitoring Report – Outside (Non-Tunnel) Wells, Prepared 

for Navy Region Hawaii, Pearl Harbor, Hawaii, May 2010. 
FIGURES 
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KAENA POINT KAHUKU MAKAHA MAILI NANAKULI WAIANAE BARBERS POINT EWA BEACH HONOLULU INTERNATIONAL AIRPORT WAIKIKI DIAMOND HICKAM AFB KAPOLEI EWA MOKULEIA HALEIWA WAIMEA POINT LAIE PUNALUU KAAAWA WAIAHOLE KANEOHE BAY KANEOHE MOKAPU KAILUA WAIMANALO MAKAPUU POINT HAWAII KAHALA KAI HONOLULU WAHIAWA SCHOFIELD BARRACKS PEARL CITY 83 930 803 99 80 780 83 61 63 78 72 61 83 836 76 63 780 93 930 750 99 H3 H1 H1 H1 H2 (RESIDENTIAL HOUSING) 

LAWA 

ONAL 

ILITY NAVY FIRING RANGE RED HILL BULK FUEL STORAGE FACILITY 

GRAPHIC SCALE 900 0 900 Scale in Feet The accuracy of this document is limited to the quality and scale of the source information. This document is not a legal representation of an engineered survey. NOTES SOURCES Pearl Harbor Base Map Navy GIS files PROJECT LOCATION FIGURE 1 SITE LOCATION GROUNDWATER MONITORING RED HILL BULK FUEL STORAGE FACILITY NAVAL SUPPLY SYSTEM COMMAND (NAVSUP) FLEET LOGISTICS CENTER JBPHH, OAHU, HAWAII
This Page Intentionally Left Blank.
RHMW05 RHMW04 HDMW2253-03 SVMP04 SVMP06 SVMP12 SVMP14 SVMP16 SVMP18 SVMP20 SVMP17 SVMP15 SVMP11 SVMP09 SVMP07 SVMP05 SVMP03 RHMW03 (RESIDENTIAL HOUSING) RED HILL BULK FUEL STORAGE FACILITY SVMP13 SVMP08 HALAWA 

CTIONAL 

ACILITY NAVY FIRING RANGE 

RHMW01 SVMP02 RHMW02 SVMP10 

GRAPHIC SCALE 1,200 0 1,200 Scale in Feet The accuracy of this document is limited to the quality and scale of the source information. This document is not a legal representation of an engineered survey. NOTES RED HILL BULK FUEL STORAGE FACILITY HALAWA CORRECTIONAL FACILITY HALAWA STREAM BUILDING ROAD ABOVEGROUND STORAGE TANK WATER TANK SOIL VAPOR MONITORING POINT GROUNDWATER MONITORING WELL LOCATED INSIDE TUNNEL GROUNDWATER MONITORING WELL LOCATED OUTSIDE TUNNEL BOARD OF WATER SUPPLY PUMP STATION LEGEND SOURCES Pearl Harbor Base Map Navy GIS files FIGURE 2 SITE LAYOUT GROUNDWATER MONITORING RED HILL BULK FUEL STORAGE FACILITY NAVAL SUPPLY SYSTEM COMMAND (NAVSUP) FLEET LOGISTICS CENTER JBPHH, OAHU, HAWAII
This Page Intentionally Left Blank.
APPENDIX A 

Groundwater Sampling Logs 
This Page Intentionally Left Blank.
Groundwater Sampling Log

Well ID: Location: Project No.:

Initial Water Level: Time:

Total Depth of Well: Personnel Involved:

Length of Saturated Zone: Weather Conditions:

Volume of Water to be Removed: Method of Removal:

Water Level After Purging: Pumping Rate:

Well Purge Data:

Red Hill Bulk Fuel Storage Facility 112066

120.55 ft Date: 1/30/2013 730

OWDFMW01

145.10 ft

Time

Volume 

Removed pH

Conductivity 

(mS/cm) DO (mg/l)

Justin Lam, Branden Ibara

Clear

Disposable Bailer

Temperature Salinity

Redox (ORP) 

(mV)

8.80

8.84

8.87

8.85

120.55 ft 0.42 L/min

5.0 L

-

738

740

7.61

8.85

4.089

3.473

742

744

746

750

0.0 L

1.0 L

2.0 L

3.0 L

4.0 L

5.0 L

3.556

3.558

3.555

6.40

5.45

5.03

4.89

4.86

3.534

4.87

23.35

23.37

23.32

23.19

22.74 2.28

1.89

1.92

1.93

1.93

23.33 1.92

20.8

-5.1

-7.7

-7.7

-7.7

-7.7

Sample Withdrawal Method:

Appearance of Sample:

Color:

Turbidity:

Sediment:

Other:

Laboratory Analysis Parameters and Preservatives:

Number and Types of Sample Containers:

Sample Identification Numbers:

Decontamination Procedures:

Notes:

Sampled by:

Sampled Delivered to: Transporters:

Date: Time:

Capacity of Casing (Gallons/Linear Feet)

2"-0.16• 4"-0.65 • 8"-2.61 • 10"-4.08 • 12"-5.87

 TPH-d - 8015; TPH-g, VOCs - 8260; PAHs - 8270C sim;

lead - 6020

ES016 [0800], ES017 (Dup) [0930], ES016 MS/MSD [0800]

Clear

Low

Slight

22 - VOAs, 8 - 1L amber jar, 5 - 500ml HDPE bottle

2/1/2013 1045

Disposable Bailer

Triple Rinsed

Justin Lam, Branden Ibara

Calscience Environmental Lab FedEx

GW Monitoring Log Outside Jan
Groundwater Sampling Log

Well ID: Location: Project No.:

Initial Water Level: Time:

Total Depth of Well: Personnel Involved:

Length of Saturated Zone: Weather Conditions:

Volume of Water to be Removed: Method of Removal:

Water Level After Purging: Pumping Rate:

Well Purge Data:

Red Hill Bulk Fuel Storage Facility 112066

208.15 ft Date: 1/30/2013 955

HDMW2253-03

1575 ft Justin Lam, Branden Ibara

- Clear, Sunny

- Disposable Bailer

- 0.21 L/min

Time

Volume 

Removed pH

Conductivity 

(mS/cm) DO (mg/l) Temperature Salinity

Redox (ORP) 

(mV)

1111 0.0 L 7.64 0.692 2.80 22.70 0.35 -50.4

1114 1.0 L 7.19 0.513 1.56 22.54 0.26 -101.3

1117 2.0 L 7.08 0.511 1.41 22.36 0.26 -52.1

1121 3.0 L 7.07 0.499 1.38 22.46 0.25 -84.9

1127 4.0 L 7.07 0.497 1.37 22.32 0.25 -85.6

1134 5.0 L 7.07 0.501 1.35 22.40 0.25 -89.1

Sample Withdrawal Method:

Appearance of Sample:

Color:

Turbidity:

Sediment:

Other:

Laboratory Analysis Parameters and Preservatives:

Number and Types of Sample Containers:

Sample Identification Numbers:

Decontamination Procedures:

Notes:

Sampled by:

Sampled Delivered to: Transporters:

Date: Time:

Clear

Low

Slight

 TPH-d - 8015; TPH-g, VOCs - 8260; PAHs - 8270C sim;

Disposable Bailer

lead - 6020

ES018 [1100]

Triple Rinsed

Justin Lam, Branden Ibara

6 - VOAs, 3 - 1L amber jar, 1 - 500ml HDPE bottle

Calscience Environmental Lab FedEx

2/1/2013 1045

Capacity of Casing (Gallons/Linear Feet)

2"-0.16• 4"-0.65 • 8"-2.61 • 10"-4.08 • 12"-5.87

GW Monitoring Log Outside Jan
APPENDIX B 

Field Notes 
This Page Intentionally Left Blank.





This Page Intentionally Left Blank.
APPENDIX C 

Laboratory Reports 
This Page Intentionally Left Blank.
Analytical Report For

Client: Environmental Science International, Inc.

Client Project Name: Red Hill LTM 112066

Attention: Robert Chong

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

WORK ORDER NUMBER: 13-02-0014

Richard Villafania

Project Manager

02/7/2013

Page 1 of 41
Contents

Client Project Name: Red Hill LTM 112066

Work Order Number: 13-02-0014

1 Client Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

1.1 EPA 6020 ICP/MS Metals (Aqueous) . . . . . . . . . . . . . . . . . . . . . . . . 3

1.2 EPA 8015B (M) TPH Diesel (Aqueous) . . . . . . . . . . . . . . . . . . . . . . . 4

1.3 EPA 8270C SIM PAHs (Aqueous) . . . . . . . . . . . . . . . . . . . . . . . . . . 5

1.4 GC/MS GRO/EPA 8260B Volatile Organics (Aqueous) . . . . . . . . . . . . 9

2 Quality Control Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

2.1 MS/MSD and/or Duplicate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

2.2 LCS/LCSD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29

3 Sample Analysis Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36

4 Glossary of Terms and Qualifiers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

5 Chain of Custody/Sample Receipt Form . . . . . . . . . . . . . . . . . . . . . . . . . 38

Page 2 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: 13-02-0014 Client: Environmental Science International, Inc.

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

EPA 6020 ICP/MS Metals Extraction: EPA 3020A Total

Client ID: ES016 Matrix: Aqueous Units: ug/L Sampled: 01/30/13 08:00

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-1

Lead <0.200 U 0.0898 0.200 1.00 1 02/01/13 00:00 02/04/13 16:55 130201L02D

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

EPA 6020 ICP/MS Metals Extraction: EPA 3020A Total

Client ID: ES017 Matrix: Aqueous Units: ug/L Sampled: 01/30/13 09:30

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-2

Lead <0.200 U 0.0898 0.200 1.00 1 02/01/13 00:00 02/04/13 16:58 130201L02D

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

EPA 6020 ICP/MS Metals Extraction: EPA 3020A Total

Client ID: ES018 Matrix: Aqueous Units: ug/L Sampled: 01/30/13 11:00

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-3

Lead <0.200 U 0.0898 0.200 1.00 1 02/01/13 00:00 02/04/13 17:01 130201L02D

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

EPA 6020 ICP/MS Metals Extraction: EPA 3020A Total

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled: 02/05/13 15:30

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-14-497-15

Lead <0.200 U 0.0898 0.200 1.00 1 02/01/13 00:00 02/04/13 16:20 130201L02D

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 3 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: 13-02-0014 Client: Environmental Science International, Inc.

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

EPA 8015B (M) TPH Diesel Extraction: EPA 3510C

Client ID: ES016 Matrix: Aqueous Units: ug/L Sampled: 01/30/13 08:00

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-1

TPH as Diesel 1000 15 20 50 1 02/04/13 00:00 02/05/13 02:45 130204B14

Surr: n-Octacosane (51-141%) 99% 02/04/13 00:00 02/05/13 02:45 130204B14

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

EPA 8015B (M) TPH Diesel Extraction: EPA 3510C

Client ID: ES017 Matrix: Aqueous Units: ug/L Sampled: 01/30/13 09:30

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-2

TPH as Diesel 1000 15 20 50 1 02/04/13 00:00 02/05/13 03:02 130204B14

Surr: n-Octacosane (51-141%) 92% 02/04/13 00:00 02/05/13 03:02 130204B14

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

EPA 8015B (M) TPH Diesel Extraction: EPA 3510C

Client ID: ES018 Matrix: Aqueous Units: ug/L Sampled: 01/30/13 11:00

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-3

TPH as Diesel 600 15 20 50 1 02/04/13 00:00 02/05/13 03:20 130204B14

Surr: n-Octacosane (51-141%) 107% 02/04/13 00:00 02/05/13 03:20 130204B14

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

EPA 8015B (M) TPH Diesel Extraction: EPA 3510C

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled: 02/05/13 16:44

Analyte

Dilution

Factor Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-15-516-26

TPH as Diesel <20 U 15 20 50 1 02/04/13 00:00 02/05/13 01:17 130204B14

Surr: n-Octacosane (51-141%) 115% 02/04/13 00:00 02/05/13 01:17 130204B14

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 4 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

EPA 8270C SIM PAHs Extraction: EPA 3510C

Client ID: ES016 Matrix: Aqueous Units: ug/L Sampled:01/30/13 08:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-1

Naphthalene 0.032 J 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

2-Methylnaphthalene <0.050 U 0.026 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

1-Methylnaphthalene <0.050 U 0.028 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Acenaphthylene <0.050 U 0.018 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Acenaphthene <0.050 U 0.021 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Fluorene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Phenanthrene <0.050 U 0.031 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Anthracene <0.050 U 0.034 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Fluoranthene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Pyrene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Benzo (a) Anthracene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Chrysene <0.050 U 0.019 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Benzo (k) Fluoranthene <0.050 U 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Benzo (b) Fluoranthene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Benzo (a) Pyrene <0.050 U 0.036 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Indeno (1,2,3-c,d) Pyrene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Dibenz (a,h) Anthracene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Benzo (g,h,i) Perylene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 17:34 130204L11

Surr: Nitrobenzene-d5 (28-139%) 108% 02/04/13 00:00 02/05/13 17:34 130204L11

Surr: 2-Fluorobiphenyl (33-144%) 96% 02/04/13 00:00 02/05/13 17:34 130204L11

Surr: p-Terphenyl-d14 (23-160%) 110% 02/04/13 00:00 02/05/13 17:34 130204L11

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 5 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

EPA 8270C SIM PAHs Extraction: EPA 3510C

Client ID: ES017 Matrix: Aqueous Units: ug/L Sampled:01/30/13 09:30

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-2

Naphthalene 0.039 J 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

2-Methylnaphthalene <0.050 U 0.026 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

1-Methylnaphthalene <0.050 U 0.028 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Acenaphthylene <0.050 U 0.018 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Acenaphthene <0.050 U 0.021 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Fluorene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Phenanthrene <0.050 U 0.031 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Anthracene <0.050 U 0.034 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Fluoranthene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Pyrene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Benzo (a) Anthracene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Chrysene <0.050 U 0.019 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Benzo (k) Fluoranthene <0.050 U 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Benzo (b) Fluoranthene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Benzo (a) Pyrene <0.050 U 0.036 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Indeno (1,2,3-c,d) Pyrene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Dibenz (a,h) Anthracene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Benzo (g,h,i) Perylene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 18:00 130204L11

Surr: Nitrobenzene-d5 (28-139%) 105% 02/04/13 00:00 02/05/13 18:00 130204L11

Surr: 2-Fluorobiphenyl (33-144%) 96% 02/04/13 00:00 02/05/13 18:00 130204L11

Surr: p-Terphenyl-d14 (23-160%) 107% 02/04/13 00:00 02/05/13 18:00 130204L11

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 6 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

EPA 8270C SIM PAHs Extraction: EPA 3510C

Client ID: ES018 Matrix: Aqueous Units: ug/L Sampled:01/30/13 11:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-3

Naphthalene 0.037 J 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

2-Methylnaphthalene <0.050 U 0.026 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

1-Methylnaphthalene <0.050 U 0.028 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Acenaphthylene <0.050 U 0.018 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Acenaphthene <0.050 U 0.021 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Fluorene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Phenanthrene <0.050 U 0.031 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Anthracene <0.050 U 0.034 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Fluoranthene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Pyrene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Benzo (a) Anthracene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Chrysene <0.050 U 0.019 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Benzo (k) Fluoranthene <0.050 U 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Benzo (b) Fluoranthene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Benzo (a) Pyrene <0.050 U 0.036 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Indeno (1,2,3-c,d) Pyrene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Dibenz (a,h) Anthracene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Benzo (g,h,i) Perylene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 18:26 130204L11

Surr: Nitrobenzene-d5 (28-139%) 108% 02/04/13 00:00 02/05/13 18:26 130204L11

Surr: 2-Fluorobiphenyl (33-144%) 97% 02/04/13 00:00 02/05/13 18:26 130204L11

Surr: p-Terphenyl-d14 (23-160%) 110% 02/04/13 00:00 02/05/13 18:26 130204L11

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 7 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 099-15-148

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

EPA 8270C SIM PAHs Extraction: EPA 3510C

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled:02/05/13 15:30

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-15-148-8

Naphthalene <0.050 U 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

2-Methylnaphthalene <0.050 U 0.026 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

1-Methylnaphthalene <0.050 U 0.028 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Acenaphthylene <0.050 U 0.018 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Acenaphthene <0.050 U 0.021 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Fluorene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Phenanthrene <0.050 U 0.031 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Anthracene <0.050 U 0.034 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Fluoranthene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Pyrene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Benzo (a) Anthracene <0.050 U 0.024 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Chrysene <0.050 U 0.019 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Benzo (k) Fluoranthene <0.050 U 0.023 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Benzo (b) Fluoranthene <0.050 U 0.025 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Benzo (a) Pyrene <0.050 U 0.036 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Indeno (1,2,3-c,d) Pyrene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Dibenz (a,h) Anthracene <0.050 U 0.027 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Benzo (g,h,i) Perylene <0.050 U 0.022 0.050 0.20 1 02/04/13 00:00 02/05/13 15:22 130204L11

Surr: Nitrobenzene-d5 (28-139%) 107% 02/04/13 00:00 02/05/13 15:22 130204L11

Surr: 2-Fluorobiphenyl (33-144%) 102% 02/04/13 00:00 02/05/13 15:22 130204L11

Surr: p-Terphenyl-d14 (23-160%) 116% 02/04/13 00:00 02/05/13 15:22 130204L11

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 8 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ES016 Matrix: Aqueous Units: ug/L Sampled:01/30/13 08:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-1

Acetone 17 ICH,J 10 10 20 1 02/04/13 00:00 02/04/13 14:10 130204L01

Benzene 0.39 J 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Bromodichloromethane <0.50 U 0.21 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Bromoform <2.0 IJ,U 0.50 2.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

Bromomethane <5.0 U 3.9 5.0 20 1 02/04/13 00:00 02/04/13 14:10 130204L01

2-Butanone <5.0 U 2.2 5.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

Carbon Tetrachloride <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Chlorobenzene <0.50 U 0.17 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Chloroethane <5.0 U 2.3 5.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

Chloroform <0.50 U 0.46 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Chloromethane <2.0 U 1.8 2.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

Dibromochloromethane <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,2-Dibromo-3-Chloropropane <2.0 U 1.2 2.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,2-Dibromoethane <0.50 U 0.36 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,2-Dichlorobenzene <0.50 U 0.46 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,3-Dichlorobenzene <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,4-Dichlorobenzene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,1-Dichloroethane <0.50 U 0.28 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,2-Dichloroethane <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,1-Dichloroethene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

c-1,2-Dichloroethene <0.50 U 0.48 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

t-1,2-Dichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,2-Dichloropropane <0.50 U 0.42 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

c-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

t-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Ethylbenzene <0.50 U 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Methylene Chloride <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

4-Methyl-2-Pentanone <5.0 U 4.4 5.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

Styrene <0.50 U 0.17 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,1,1,2-Tetrachloroethane <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,1,2,2-Tetrachloroethane <0.50 U 0.41 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Tetrachloroethene <0.50 U 0.39 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Toluene <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,2,4-Trichlorobenzene <0.50 U 0.50 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,1,1-Trichloroethane <0.50 U 0.30 0.50 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Hexachloro-1,3-Butadiene <0.50 U 0.32 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

1,1,2-Trichloroethane <0.50 U 0.38 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Trichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 9 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ES016 Matrix: Aqueous Units: ug/L Sampled:01/30/13 08:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-1

1,2,3-Trichloropropane <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Vinyl Chloride <0.50 U 0.30 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

p/m-Xylene <1.0 U 0.30 1.0 10 1 02/04/13 00:00 02/04/13 14:10 130204L01

o-Xylene <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Methyl-t-Butyl Ether (MTBE) <0.50 U 0.31 0.50 1.0 1 02/04/13 00:00 02/04/13 14:10 130204L01

Gasoline Range Organics <30 U 13 30 50 1 02/04/13 00:00 02/04/13 14:10 130204L01

Surr: Dibromofluoromethane (80-126%) 88% 02/04/13 00:00 02/04/13 14:10 130204L01

Surr: 1,2-Dichloroethane-d4 (80-134%) 94% 02/04/13 00:00 02/04/13 14:10 130204L01

Surr: Toluene-d8 (80-120%) 98% 02/04/13 00:00 02/04/13 14:10 130204L01

Surr: Toluene-d8-TPPH (88-112%) 99% 02/04/13 00:00 02/04/13 14:10 130204L01

Surr: 1,4-Bromofluorobenzene (80-120%) 96% 02/04/13 00:00 02/04/13 14:10 130204L01

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 10 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ES017 Matrix: Aqueous Units: ug/L Sampled:01/30/13 09:30

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-2

Acetone <10 ICH,U 10 10 20 1 02/04/13 00:00 02/04/13 17:15 130204L01

Benzene 0.17 J 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Bromodichloromethane <0.50 U 0.21 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Bromoform <2.0 IJ,U 0.50 2.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

Bromomethane <5.0 U 3.9 5.0 20 1 02/04/13 00:00 02/04/13 17:15 130204L01

2-Butanone <5.0 U 2.2 5.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

Carbon Tetrachloride <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Chlorobenzene <0.50 U 0.17 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Chloroethane <5.0 U 2.3 5.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

Chloroform <0.50 U 0.46 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Chloromethane <2.0 U 1.8 2.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

Dibromochloromethane <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,2-Dibromo-3-Chloropropane <2.0 U 1.2 2.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,2-Dibromoethane <0.50 U 0.36 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,2-Dichlorobenzene <0.50 U 0.46 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,3-Dichlorobenzene <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,4-Dichlorobenzene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,1-Dichloroethane <0.50 U 0.28 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,2-Dichloroethane <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,1-Dichloroethene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

c-1,2-Dichloroethene <0.50 U 0.48 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

t-1,2-Dichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,2-Dichloropropane <0.50 U 0.42 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

c-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

t-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Ethylbenzene <0.50 U 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Methylene Chloride <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

4-Methyl-2-Pentanone <5.0 U 4.4 5.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

Styrene <0.50 U 0.17 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,1,1,2-Tetrachloroethane <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,1,2,2-Tetrachloroethane <0.50 U 0.41 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Tetrachloroethene <0.50 U 0.39 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Toluene <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,2,4-Trichlorobenzene <0.50 U 0.50 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,1,1-Trichloroethane <0.50 U 0.30 0.50 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Hexachloro-1,3-Butadiene <0.50 U 0.32 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

1,1,2-Trichloroethane <0.50 U 0.38 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Trichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 11 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ES017 Matrix: Aqueous Units: ug/L Sampled:01/30/13 09:30

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-2

1,2,3-Trichloropropane <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Vinyl Chloride <0.50 U 0.30 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

p/m-Xylene <1.0 U 0.30 1.0 10 1 02/04/13 00:00 02/04/13 17:15 130204L01

o-Xylene <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Methyl-t-Butyl Ether (MTBE) <0.50 U 0.31 0.50 1.0 1 02/04/13 00:00 02/04/13 17:15 130204L01

Gasoline Range Organics <30 U 13 30 50 1 02/04/13 00:00 02/04/13 17:15 130204L01

Surr: Dibromofluoromethane (80-126%) 95% 02/04/13 00:00 02/04/13 17:15 130204L01

Surr: 1,2-Dichloroethane-d4 (80-134%) 96% 02/04/13 00:00 02/04/13 17:15 130204L01

Surr: Toluene-d8 (80-120%) 98% 02/04/13 00:00 02/04/13 17:15 130204L01

Surr: Toluene-d8-TPPH (88-112%) 100% 02/04/13 00:00 02/04/13 17:15 130204L01

Surr: 1,4-Bromofluorobenzene (80-120%) 93% 02/04/13 00:00 02/04/13 17:15 130204L01

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 12 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ES018 Matrix: Aqueous Units: ug/L Sampled:01/30/13 11:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-3

Acetone <10 ICH,U 10 10 20 1 02/04/13 00:00 02/04/13 17:42 130204L01

Benzene <0.50 U 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Bromodichloromethane <0.50 U 0.21 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Bromoform <2.0 IJ,U 0.50 2.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

Bromomethane <5.0 U 3.9 5.0 20 1 02/04/13 00:00 02/04/13 17:42 130204L01

2-Butanone <5.0 U 2.2 5.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

Carbon Tetrachloride <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Chlorobenzene <0.50 U 0.17 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Chloroethane <5.0 U 2.3 5.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

Chloroform <0.50 U 0.46 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Chloromethane <2.0 U 1.8 2.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

Dibromochloromethane <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,2-Dibromo-3-Chloropropane <2.0 U 1.2 2.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,2-Dibromoethane <0.50 U 0.36 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,2-Dichlorobenzene <0.50 U 0.46 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,3-Dichlorobenzene <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,4-Dichlorobenzene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,1-Dichloroethane <0.50 U 0.28 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,2-Dichloroethane <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,1-Dichloroethene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

c-1,2-Dichloroethene <0.50 U 0.48 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

t-1,2-Dichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,2-Dichloropropane <0.50 U 0.42 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

c-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

t-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Ethylbenzene <0.50 U 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Methylene Chloride <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

4-Methyl-2-Pentanone <5.0 U 4.4 5.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

Styrene <0.50 U 0.17 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,1,1,2-Tetrachloroethane <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,1,2,2-Tetrachloroethane <0.50 U 0.41 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Tetrachloroethene <0.50 U 0.39 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Toluene <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,2,4-Trichlorobenzene <0.50 U 0.50 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,1,1-Trichloroethane <0.50 U 0.30 0.50 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Hexachloro-1,3-Butadiene <0.50 U 0.32 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

1,1,2-Trichloroethane <0.50 U 0.38 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Trichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 13 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ES018 Matrix: Aqueous Units: ug/L Sampled:01/30/13 11:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-3

1,2,3-Trichloropropane <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Vinyl Chloride <0.50 U 0.30 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

p/m-Xylene <1.0 U 0.30 1.0 10 1 02/04/13 00:00 02/04/13 17:42 130204L01

o-Xylene <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Methyl-t-Butyl Ether (MTBE) <0.50 U 0.31 0.50 1.0 1 02/04/13 00:00 02/04/13 17:42 130204L01

Gasoline Range Organics <30 U 13 30 50 1 02/04/13 00:00 02/04/13 17:42 130204L01

Surr: Dibromofluoromethane (80-126%) 99% 02/04/13 00:00 02/04/13 17:42 130204L01

Surr: 1,2-Dichloroethane-d4 (80-134%) 100% 02/04/13 00:00 02/04/13 17:42 130204L01

Surr: Toluene-d8 (80-120%) 101% 02/04/13 00:00 02/04/13 17:42 130204L01

Surr: Toluene-d8-TPPH (88-112%) 102% 02/04/13 00:00 02/04/13 17:42 130204L01

Surr: 1,4-Bromofluorobenzene (80-120%) 92% 02/04/13 00:00 02/04/13 17:42 130204L01

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 14 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ESTrip Matrix: Aqueous Units: ug/L Sampled:01/30/13 07:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-4

Acetone <10 IJ,ICH,U 10 10 20 1 02/01/13 00:00 02/01/13 20:00 130201L01

Benzene <0.50 U 0.14 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Bromodichloromethane <0.50 U 0.21 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Bromoform <2.0 U 0.50 2.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

Bromomethane <5.0 U 3.9 5.0 20 1 02/01/13 00:00 02/01/13 20:00 130201L01

2-Butanone <5.0 U 2.2 5.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

Carbon Tetrachloride <0.50 U 0.23 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Chlorobenzene <0.50 U 0.17 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Chloroethane <5.0 U 2.3 5.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

Chloroform <0.50 U 0.46 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Chloromethane <2.0 U 1.8 2.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

Dibromochloromethane <0.50 U 0.25 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,2-Dibromo-3-Chloropropane <2.0 U 1.2 2.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,2-Dibromoethane <0.50 U 0.36 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,2-Dichlorobenzene <0.50 U 0.46 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,3-Dichlorobenzene <0.50 U 0.40 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,4-Dichlorobenzene <0.50 U 0.43 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,1-Dichloroethane <0.50 U 0.28 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,2-Dichloroethane <0.50 U 0.24 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,1-Dichloroethene <0.50 U 0.43 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

c-1,2-Dichloroethene <0.50 U 0.48 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

t-1,2-Dichloroethene <0.50 U 0.37 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,2-Dichloropropane <0.50 U 0.42 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

c-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

t-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Ethylbenzene <0.50 U 0.14 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Methylene Chloride <2.0 U 0.64 2.0 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

4-Methyl-2-Pentanone <5.0 U 4.4 5.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

Styrene <0.50 U 0.17 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,1,1,2-Tetrachloroethane <0.50 U 0.40 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,1,2,2-Tetrachloroethane <0.50 U 0.41 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Tetrachloroethene <0.50 U 0.39 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Toluene <0.50 U 0.24 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,2,4-Trichlorobenzene <0.50 U 0.50 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,1,1-Trichloroethane <0.50 U 0.30 0.50 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Hexachloro-1,3-Butadiene <0.50 U 0.32 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

1,1,2-Trichloroethane <0.50 U 0.38 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Trichloroethene <0.50 U 0.37 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 15 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 13-02-0014

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: ESTrip Matrix: Aqueous Units: ug/L Sampled:01/30/13 07:00

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

13-02-0014-4

1,2,3-Trichloropropane <2.0 U 0.64 2.0 5.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Vinyl Chloride <0.50 U 0.30 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

p/m-Xylene <1.0 U 0.30 1.0 10 1 02/01/13 00:00 02/01/13 20:00 130201L01

o-Xylene <0.50 U 0.23 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Methyl-t-Butyl Ether (MTBE) <0.50 U 0.31 0.50 1.0 1 02/01/13 00:00 02/01/13 20:00 130201L01

Gasoline Range Organics 14 J 13 30 50 1 02/01/13 00:00 02/01/13 20:00 130201L01

Surr: Dibromofluoromethane (80-126%) 104% 02/01/13 00:00 02/01/13 20:00 130201L01

Surr: 1,2-Dichloroethane-d4 (80-134%) 104% 02/01/13 00:00 02/01/13 20:00 130201L01

Surr: Toluene-d8 (80-120%) 100% 02/01/13 00:00 02/01/13 20:00 130201L01

Surr: Toluene-d8-TPPH (88-112%) 101% 02/01/13 00:00 02/01/13 20:00 130201L01

Surr: 1,4-Bromofluorobenzene (80-120%) 94% 02/01/13 00:00 02/01/13 20:00 130201L01

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 16 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 099-13-057

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled:02/04/13 11:36

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-13-057-5

Acetone <10 U 10 10 20 1 02/04/13 00:00 02/04/13 13:42 130204L01

Benzene <0.50 U 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Bromodichloromethane <0.50 U 0.21 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Bromoform <2.0 U 0.50 2.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

Bromomethane <5.0 U 3.9 5.0 20 1 02/04/13 00:00 02/04/13 13:42 130204L01

2-Butanone <5.0 U 2.2 5.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

Carbon Tetrachloride <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Chlorobenzene <0.50 U 0.17 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Chloroethane <5.0 U 2.3 5.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

Chloroform <0.50 U 0.46 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Chloromethane <2.0 U 1.8 2.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

Dibromochloromethane <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,2-Dibromo-3-Chloropropane <2.0 U 1.2 2.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,2-Dibromoethane <0.50 U 0.36 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,2-Dichlorobenzene <0.50 U 0.46 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,3-Dichlorobenzene <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,4-Dichlorobenzene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,1-Dichloroethane <0.50 U 0.28 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,2-Dichloroethane <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,1-Dichloroethene <0.50 U 0.43 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

c-1,2-Dichloroethene <0.50 U 0.48 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

t-1,2-Dichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,2-Dichloropropane <0.50 U 0.42 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

c-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

t-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Ethylbenzene <0.50 U 0.14 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Methylene Chloride <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

4-Methyl-2-Pentanone <5.0 U 4.4 5.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

Styrene <0.50 U 0.17 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,1,1,2-Tetrachloroethane <0.50 U 0.40 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,1,2,2-Tetrachloroethane <0.50 U 0.41 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Tetrachloroethene <0.50 U 0.39 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Toluene <0.50 U 0.24 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,2,4-Trichlorobenzene <0.50 U 0.50 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,1,1-Trichloroethane <0.50 U 0.30 0.50 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Hexachloro-1,3-Butadiene <0.50 U 0.32 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

1,1,2-Trichloroethane <0.50 U 0.38 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Trichloroethene <0.50 U 0.37 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 17 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 099-13-057

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled:02/04/13 11:36

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-13-057-5

1,2,3-Trichloropropane <2.0 U 0.64 2.0 5.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Vinyl Chloride <0.50 U 0.30 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

p/m-Xylene <1.0 U 0.30 1.0 10 1 02/04/13 00:00 02/04/13 13:42 130204L01

o-Xylene <0.50 U 0.23 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Methyl-t-Butyl Ether (MTBE) <0.50 U 0.31 0.50 1.0 1 02/04/13 00:00 02/04/13 13:42 130204L01

Gasoline Range Organics <30 U 13 30 50 1 02/04/13 00:00 02/04/13 13:42 130204L01

Surr: Dibromofluoromethane (80-126%) 93% 02/04/13 00:00 02/04/13 13:42 130204L01

Surr: 1,2-Dichloroethane-d4 (80-134%) 92% 02/04/13 00:00 02/04/13 13:42 130204L01

Surr: Toluene-d8 (80-120%) 99% 02/04/13 00:00 02/04/13 13:42 130204L01

Surr: Toluene-d8-TPPH (88-112%) 100% 02/04/13 00:00 02/04/13 13:42 130204L01

Surr: 1,4-Bromofluorobenzene (80-120%) 97% 02/04/13 00:00 02/04/13 13:42 130204L01

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 18 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 099-13-057

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled:02/04/13 17:49

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-13-057-6

Acetone <10 U 10 10 20 1 02/01/13 00:00 02/01/13 13:49 130201L01

Benzene <0.50 U 0.14 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Bromodichloromethane <0.50 U 0.21 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Bromoform <2.0 U 0.50 2.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

Bromomethane <5.0 U 3.9 5.0 20 1 02/01/13 00:00 02/01/13 13:49 130201L01

2-Butanone <5.0 U 2.2 5.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

Carbon Tetrachloride <0.50 U 0.23 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Chlorobenzene <0.50 U 0.17 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Chloroethane <5.0 U 2.3 5.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

Chloroform <0.50 U 0.46 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Chloromethane <2.0 U 1.8 2.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

Dibromochloromethane <0.50 U 0.25 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,2-Dibromo-3-Chloropropane <2.0 U 1.2 2.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,2-Dibromoethane <0.50 U 0.36 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,2-Dichlorobenzene <0.50 U 0.46 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,3-Dichlorobenzene <0.50 U 0.40 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,4-Dichlorobenzene <0.50 U 0.43 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,1-Dichloroethane <0.50 U 0.28 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,2-Dichloroethane <0.50 U 0.24 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,1-Dichloroethene <0.50 U 0.43 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

c-1,2-Dichloroethene <0.50 U 0.48 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

t-1,2-Dichloroethene <0.50 U 0.37 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,2-Dichloropropane <0.50 U 0.42 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

c-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

t-1,3-Dichloropropene <0.50 U 0.25 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Ethylbenzene <0.50 U 0.14 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Methylene Chloride <2.0 U 0.64 2.0 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

4-Methyl-2-Pentanone <5.0 U 4.4 5.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

Styrene <0.50 U 0.17 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,1,1,2-Tetrachloroethane <0.50 U 0.40 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,1,2,2-Tetrachloroethane <0.50 U 0.41 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Tetrachloroethene <0.50 U 0.39 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Toluene <0.50 U 0.24 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,2,4-Trichlorobenzene <0.50 U 0.50 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,1,1-Trichloroethane <0.50 U 0.30 0.50 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Hexachloro-1,3-Butadiene <0.50 U 0.32 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

1,1,2-Trichloroethane <0.50 U 0.38 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Trichloroethene <0.50 U 0.37 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 19 of 41
Project Name: Red Hill LTM 112066 354 Uluniu Street, Suite 304

Work Order: Client: Environmental Science International, Inc. 099-13-057

ANALYTICAL REPORT

Attn: Robert Chong Received: 02/01/13 10:45

Kailua, HI 96734-2500

GC/MS GRO/EPA 8260B Volatile Organics Extraction: EPA 5030C

Client ID: Method Blank Matrix: Aqueous Units: ug/L Sampled:02/04/13 17:49

Dilution

Factor Analyte Result Qual. DL LOD LOQ

Preparation

Date/Time

Analysis

Date/Time Batch

099-13-057-6

1,2,3-Trichloropropane <2.0 U 0.64 2.0 5.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Vinyl Chloride <0.50 U 0.30 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

p/m-Xylene <1.0 U 0.30 1.0 10 1 02/01/13 00:00 02/01/13 13:49 130201L01

o-Xylene <0.50 U 0.23 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Methyl-t-Butyl Ether (MTBE) <0.50 U 0.31 0.50 1.0 1 02/01/13 00:00 02/01/13 13:49 130201L01

Gasoline Range Organics <30 U 13 30 50 1 02/01/13 00:00 02/01/13 13:49 130201L01

Surr: Dibromofluoromethane (80-126%) 94% 02/01/13 00:00 02/01/13 13:49 130201L01

Surr: 1,2-Dichloroethane-d4 (80-134%) 94% 02/01/13 00:00 02/01/13 13:49 130201L01

Surr: Toluene-d8 (80-120%) 98% 02/01/13 00:00 02/01/13 13:49 130201L01

Surr: Toluene-d8-TPPH (88-112%) 100% 02/01/13 00:00 02/01/13 13:49 130201L01

Surr: 1,4-Bromofluorobenzene (80-120%) 94% 02/01/13 00:00 02/01/13 13:49 130201L01

-Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 20 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: EPA 6020

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 3020A Total

Date Received: 02/01/13

Quality Control Sample ID

ES016

MS/MSD Batch

Number

130201S02D

Matrix

Aqueous

Date

Analyzed

02/04/13

Date

Prepared

02/01/13

Instrument

ICP/MS 03

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

Lead ND 100.0 107.8 108 106.5 106 80-120 1 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 21 of 41
Quality Control - PDS / PDSD

Work Order No: 13-02-0014

Method: EPA 6020

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project: Red Hill LTM 112066

Preparation: EPA 3020A Total

Date Received 02/01/13

Quality Control Sample ID

ES016

PDS / PDSD Batch

Number

130201S02D

Matrix

Aqueous

Date Analyzed

02/04/13

Date

Prepared

02/01/13

Instrument

ICP/MS 03

%REC

CL

Parameter PDS RPD RPD CL Qualifiers

%REC

PDSD

%REC

SPIKE

ADDED

SAMPLE

CONC

PDSD

CONC

PDS CONC

Lead ND 100.0 107.9 108 109.5 109 75-125 1 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 22 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: EPA 8015B (M)

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 3510C

Date Received: 02/01/13

Quality Control Sample ID

ES016

MS/MSD Batch

Number

130204S14

Matrix

Aqueous

Date

Analyzed

02/05/13

Date

Prepared

02/04/13

Instrument

GC 45

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

TPH as Diesel 1036 4000 4602 89 4715 92 55-133 2 0-30

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 23 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: EPA 8270C SIM PAHs

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 3510C

Date Received: 02/01/13

Quality Control Sample ID

ES016

MS/MSD Batch

Number

130204S11

Matrix

Aqueous

Date

Analyzed

02/05/13

Date

Prepared

01/01/95

Instrument

GC/MS AAA

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

Naphthalene ND 2.000 1.958 98 2.014 101 21-133 3 0-25

2-Methylnaphthalene ND 2.000 2.172 109 2.240 112 21-140 3 0-25

1-Methylnaphthalene ND 2.000 2.139 107 2.199 110 20-140 3 0-25

Acenaphthylene ND 2.000 1.987 99 2.020 101 33-145 2 0-25

Acenaphthene ND 2.000 1.936 97 2.026 101 49-121 5 0-25

Fluorene ND 2.000 2.121 106 2.159 108 59-121 2 0-25

Phenanthrene ND 2.000 2.090 104 2.134 107 54-120 2 0-25

Anthracene ND 2.000 1.925 96 1.975 99 27-133 3 0-25

Fluoranthene ND 2.000 2.088 104 2.133 107 26-137 2 0-25

Pyrene ND 2.000 2.398 120 2.419 121 18-168 1 0-25

Benzo (a) Anthracene ND 2.000 2.603 130 2.639 132 33-143 1 0-25

Chrysene ND 2.000 2.243 112 2.312 116 17-168 3 0-25

Benzo (k) Fluoranthene ND 2.000 2.537 127 2.577 129 24-159 2 0-25

Benzo (b) Fluoranthene ND 2.000 2.539 127 2.594 130 24-159 2 0-25

Benzo (a) Pyrene ND 2.000 2.372 119 2.413 121 17-163 2 0-25

Indeno (1,2,3-c,d) Pyrene ND 2.000 2.289 114 2.344 117 10-171 2 0-25

Dibenz (a,h) Anthracene ND 2.000 2.284 114 2.297 115 10-219 1 0-25

Benzo (g,h,i) Perylene ND 2.000 2.230 111 2.255 113 10-227 1 0-25

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 24 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: EPA 8260B

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 5030C

Date Received: 02/01/13

Quality Control Sample ID

13-01-1812-1

MS/MSD Batch

Number

130201S01

Matrix

Aqueous

Date

Analyzed

02/01/13

Date

Prepared

02/01/13

Instrument

GC/MS OO

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

Acetone ND 50.00 37.82 76 49.25 98 40-140 26 0-20 4

Benzene ND 50.00 44.02 88 49.35 99 80-120 11 0-20

Bromodichloromethane ND 50.00 45.98 92 52.26 105 75-120 13 0-20

Bromoform ND 50.00 47.63 95 56.04 112 70-130 16 0-20

Bromomethane ND 50.00 43.28 87 43.96 88 30-145 2 0-20

2-Butanone ND 50.00 43.99 88 49.70 99 30-150 12 0-20

Carbon Tetrachloride ND 50.00 43.17 86 47.14 94 65-140 9 0-20

Chlorobenzene ND 50.00 44.98 90 51.01 102 80-120 13 0-20

Chloroethane ND 50.00 46.57 93 49.31 99 60-135 6 0-20

Chloroform ND 50.00 44.94 90 49.80 100 65-135 10 0-20

Chloromethane ND 50.00 33.74 67 39.58 79 40-125 16 0-20

Dibromochloromethane ND 50.00 45.43 91 52.51 105 60-135 14 0-20

1,2-Dibromo-3-Chloropropane ND 50.00 39.96 80 51.15 102 50-130 25 0-20 4

1,2-Dibromoethane ND 50.00 47.17 94 54.84 110 80-120 15 0-20

1,2-Dichlorobenzene ND 50.00 46.43 93 53.65 107 70-120 14 0-20

1,3-Dichlorobenzene ND 50.00 46.25 93 52.55 105 75-125 13 0-20

1,4-Dichlorobenzene ND 50.00 45.66 91 52.28 105 75-125 14 0-20

1,1-Dichloroethane ND 50.00 43.08 86 47.35 95 70-135 9 0-20

1,2-Dichloroethane ND 50.00 43.58 87 49.85 100 70-130 13 0-20

1,1-Dichloroethene ND 50.00 37.37 75 40.41 81 70-130 8 0-20

c-1,2-Dichloroethene ND 50.00 46.73 93 51.33 103 70-125 9 0-20

t-1,2-Dichloroethene ND 50.00 45.05 90 50.02 100 60-140 10 0-20

1,2-Dichloropropane ND 50.00 45.58 91 52.86 106 75-125 15 0-20

c-1,3-Dichloropropene ND 50.00 47.71 95 54.81 110 70-130 14 0-20

t-1,3-Dichloropropene ND 50.00 42.27 85 49.27 99 55-140 15 0-20

Ethylbenzene ND 50.00 47.32 95 53.19 106 75-125 12 0-20

Methylene Chloride ND 50.00 43.63 87 49.00 98 55-140 12 0-20

4-Methyl-2-Pentanone ND 50.00 45.41 91 55.10 110 60-135 19 0-20

Styrene ND 50.00 47.47 95 55.44 111 65-135 15 0-20

1,1,1,2-Tetrachloroethane ND 50.00 46.26 93 52.75 106 80-130 13 0-20

1,1,2,2-Tetrachloroethane ND 50.00 44.83 90 53.54 107 65-130 18 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 25 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: EPA 8260B

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 5030C

Date Received: 02/01/13

Quality Control Sample ID

13-01-1812-1

MS/MSD Batch

Number

130201S01

Matrix

Aqueous

Date

Analyzed

02/01/13

Date

Prepared

02/01/13

Instrument

GC/MS OO

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

Tetrachloroethene ND 50.00 39.09 78 43.09 86 45-150 10 0-20

Toluene ND 50.00 46.42 93 51.87 104 75-120 11 0-20

1,2,4-Trichlorobenzene ND 50.00 46.61 93 54.94 110 65-135 16 0-20

1,1,1-Trichloroethane ND 50.00 44.80 90 49.56 99 65-130 10 0-20

Hexachloro-1,3-Butadiene ND 50.00 43.76 88 49.93 100 50-140 13 0-20

1,1,2-Trichloroethane ND 50.00 45.13 90 52.35 105 75-125 15 0-20

Trichloroethene ND 50.00 43.81 88 49.50 99 70-125 12 0-20

1,2,3-Trichloropropane ND 50.00 44.28 89 52.27 105 75-125 17 0-20

Vinyl Chloride ND 50.00 38.90 78 43.51 87 50-145 11 0-20

p/m-Xylene ND 100.0 94.57 95 107.4 107 75-130 13 0-20

o-Xylene ND 50.00 49.90 100 56.10 112 80-120 12 0-20

Methyl-t-Butyl Ether (MTBE) ND 50.00 46.93 94 54.53 109 65-125 15 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 26 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: GC/MS / EPA 8260B

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 5030C

Date Received: 02/01/13

Quality Control Sample ID

ES016

MS/MSD Batch

Number

130204S01

Matrix

Aqueous

Date

Analyzed

02/04/13

Date

Prepared

02/04/13

Instrument

GC/MS OO

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

Acetone ND 50.00 95.75 192 98.45 197 40-140 3 0-20 3

Benzene ND 50.00 51.57 103 47.73 95 80-120 8 0-20

Bromodichloromethane ND 50.00 52.75 106 49.20 98 75-120 7 0-20

Bromoform ND 50.00 56.99 114 53.76 108 70-130 6 0-20

Bromomethane ND 50.00 56.01 112 46.32 93 30-145 19 0-20

2-Butanone ND 50.00 60.34 121 54.65 109 30-150 10 0-20

Carbon Tetrachloride ND 50.00 52.07 104 48.02 96 65-140 8 0-20

Chlorobenzene ND 50.00 53.31 107 48.79 98 80-120 9 0-20

Chloroethane ND 50.00 54.22 108 49.81 100 60-135 8 0-20

Chloroform ND 50.00 51.47 103 47.54 95 65-135 8 0-20

Chloromethane ND 50.00 43.76 88 41.36 83 40-125 6 0-20

Dibromochloromethane ND 50.00 53.64 107 49.14 98 60-135 9 0-20

1,2-Dibromo-3-Chloropropane ND 50.00 51.73 103 45.08 90 50-130 14 0-20

1,2-Dibromoethane ND 50.00 55.57 111 50.49 101 80-120 10 0-20

1,2-Dichlorobenzene ND 50.00 55.01 110 50.41 101 70-120 9 0-20

1,3-Dichlorobenzene ND 50.00 54.25 108 50.21 100 75-125 8 0-20

1,4-Dichlorobenzene ND 50.00 53.73 107 49.39 99 75-125 8 0-20

1,1-Dichloroethane ND 50.00 48.94 98 45.78 92 70-135 7 0-20

1,2-Dichloroethane ND 50.00 50.20 100 46.95 94 70-130 7 0-20

1,1-Dichloroethene ND 50.00 43.82 88 41.04 82 70-130 7 0-20

c-1,2-Dichloroethene ND 50.00 52.24 104 49.27 99 70-125 6 0-20

t-1,2-Dichloroethene ND 50.00 52.27 105 48.70 97 60-140 7 0-20

1,2-Dichloropropane ND 50.00 53.02 106 48.59 97 75-125 9 0-20

c-1,3-Dichloropropene ND 50.00 55.94 112 51.60 103 70-130 8 0-20

t-1,3-Dichloropropene ND 50.00 49.89 100 45.96 92 55-140 8 0-20

Ethylbenzene ND 50.00 56.70 113 52.02 104 75-125 9 0-20

Methylene Chloride ND 50.00 49.24 98 45.39 91 55-140 8 0-20

4-Methyl-2-Pentanone ND 50.00 53.53 107 52.09 104 60-135 3 0-20

Styrene ND 50.00 58.53 117 52.87 106 65-135 10 0-20

1,1,1,2-Tetrachloroethane ND 50.00 55.57 111 50.01 100 80-130 11 0-20

1,1,2,2-Tetrachloroethane ND 50.00 6.699 13 4.454 9 65-130 40 0-20 3,4

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 27 of 41
Quality Control - Spike/Spike Duplicate

Work Order No: 13-02-0014

Method: GC/MS / EPA 8260B

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

Environmental Science International, Inc.

Project Red Hill LTM 112066

Preparation: EPA 5030C

Date Received: 02/01/13

Quality Control Sample ID

ES016

MS/MSD Batch

Number

130204S01

Matrix

Aqueous

Date

Analyzed

02/04/13

Date

Prepared

02/04/13

Instrument

GC/MS OO

MS

%REC

MSD

%REC

SPIKE %REC CL RPD RPD CL Qualifiers

ADDED

Parameter SAMPLE

CONC

MS

CONC

MSD

CONC

Tetrachloroethene ND 50.00 81.63 163 75.10 150 45-150 8 0-20 3

Toluene ND 50.00 53.83 108 49.91 100 75-120 8 0-20

1,2,4-Trichlorobenzene ND 50.00 57.83 116 50.54 101 65-135 13 0-20

1,1,1-Trichloroethane ND 50.00 52.92 106 49.36 99 65-130 7 0-20

Hexachloro-1,3-Butadiene ND 50.00 55.51 111 49.05 98 50-140 12 0-20

1,1,2-Trichloroethane ND 50.00 52.58 105 47.85 96 75-125 9 0-20

Trichloroethene ND 50.00 89.55 179 84.22 168 70-125 6 0-20 3

1,2,3-Trichloropropane ND 50.00 53.47 107 47.43 95 75-125 12 0-20

Vinyl Chloride ND 50.00 48.47 97 44.64 89 50-145 8 0-20

p/m-Xylene ND 100.0 113.5 113 104.1 104 75-130 9 0-20

o-Xylene ND 50.00 58.92 118 53.54 107 80-120 10 0-20

Methyl-t-Butyl Ether (MTBE) ND 50.00 53.56 107 49.79 100 65-125 7 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 28 of 41
Quality Control - LCS/LCS Duplicate

Method: EPA 6020

13-02-0014

Red Hill LTM 112066

Preparation: EPA 3020A Total

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/01/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

ICP/MS 03 130201L02D

Date

Prepared

Date

Analyzed

02/04/13

Quality Control Sample ID

099-14-497-15

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

Lead 100.0 98.36 98 99.38 99 80-120 1 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 29 of 41
Quality Control - LCS/LCS Duplicate

Method: EPA 8015B (M)

13-02-0014

Red Hill LTM 112066

Preparation: EPA 3510C

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/04/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

GC 45 130204B14

Date

Prepared

Date

Analyzed

02/05/13

Quality Control Sample ID

099-15-516-26

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

TPH as Diesel 4000 4209 105 4206 105 60-132 0 0-11

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 30 of 41
Quality Control - LCS/LCS Duplicate

Method: EPA 8270C SIM PAHs

13-02-0014

Red Hill LTM 112066

Preparation: EPA 3510C

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/04/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

GC/MS AAA 130204L11

Date

Prepared

Date

Analyzed

02/05/13

Quality Control Sample ID

099-15-148-8

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

Naphthalene 2.000 1.964 98 1.974 99 21-133 1 0-25

2-Methylnaphthalene 2.000 2.176 109 2.150 107 21-140 1 0-25

1-Methylnaphthalene 2.000 2.150 108 2.142 107 20-140 0 0-25

Acenaphthylene 2.000 2.001 100 2.025 101 33-145 1 0-25

Acenaphthene 2.000 1.940 97 1.975 99 55-121 2 0-25

Fluorene 2.000 2.128 106 2.147 107 59-121 1 0-25

Phenanthrene 2.000 2.162 108 2.175 109 54-120 1 0-25

Anthracene 2.000 1.930 97 1.935 97 27-133 0 0-25

Fluoranthene 2.000 2.169 108 2.159 108 26-137 0 0-25

Pyrene 2.000 2.486 124 2.453 123 45-129 1 0-25

Benzo (a) Anthracene 2.000 2.639 132 2.625 131 33-143 1 0-25

Chrysene 2.000 2.337 117 2.329 116 17-168 0 0-25

Benzo (k) Fluoranthene 2.000 2.627 131 2.647 132 24-159 1 0-25

Benzo (b) Fluoranthene 2.000 2.670 133 2.597 130 24-159 3 0-25

Benzo (a) Pyrene 2.000 2.435 122 2.415 121 17-163 1 0-25

Indeno (1,2,3-c,d) Pyrene 2.000 2.330 116 2.338 117 25-175 0 0-25

Dibenz (a,h) Anthracene 2.000 2.243 112 2.289 114 25-175 2 0-25

Benzo (g,h,i) Perylene 2.000 2.267 113 2.266 113 25-157 0 0-25

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 31 of 41
Quality Control - LCS/LCS Duplicate

Method: GC/MS / EPA 8260B

13-02-0014

Red Hill LTM 112066

Preparation: EPA 5030C

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/01/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

GC/MS OO 130201L01

Date

Prepared

Date

Analyzed

02/01/13

Quality Control Sample ID

099-13-057-6

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

Acetone 50.00 63.88 128 57.49 115 40-140 11 0-20

Benzene 50.00 50.29 101 44.85 90 80-120 11 0-20

Bromodichloromethane 50.00 54.16 108 47.74 95 75-120 13 0-20

Bromoform 50.00 59.12 118 52.80 106 70-130 11 0-20

Bromomethane 50.00 46.92 94 41.36 83 30-145 13 0-20

2-Butanone 50.00 58.36 117 50.94 102 30-150 14 0-20

Carbon Tetrachloride 50.00 51.26 103 46.17 92 65-140 10 0-20

Chlorobenzene 50.00 52.42 105 47.01 94 80-120 11 0-20

Chloroethane 50.00 52.91 106 47.84 96 60-135 10 0-20

Chloroform 50.00 51.26 103 46.53 93 65-135 10 0-20

Chloromethane 50.00 43.72 87 39.59 79 40-125 10 0-20

Dibromochloromethane 50.00 54.85 110 49.59 99 60-135 10 0-20

1,2-Dibromo-3-Chloropropane 50.00 52.98 106 50.46 101 50-130 5 0-20

1,2-Dibromoethane 50.00 55.29 111 51.42 103 80-120 7 0-20

1,2-Dichlorobenzene 50.00 55.07 110 48.78 98 70-120 12 0-20

1,3-Dichlorobenzene 50.00 55.22 110 48.14 96 75-125 14 0-20

1,4-Dichlorobenzene 50.00 53.38 107 47.98 96 75-125 11 0-20

1,1-Dichloroethane 50.00 49.91 100 45.37 91 70-135 10 0-20

1,2-Dichloroethane 50.00 50.66 101 45.12 90 70-130 12 0-20

1,1-Dichloroethene 50.00 44.22 88 39.05 78 70-130 12 0-20

c-1,2-Dichloroethene 50.00 53.00 106 48.01 96 70-125 10 0-20

t-1,2-Dichloroethene 50.00 52.01 104 47.33 95 60-140 9 0-20

1,2-Dichloropropane 50.00 52.76 106 47.46 95 75-125 11 0-20

c-1,3-Dichloropropene 50.00 56.26 113 50.92 102 70-130 10 0-20

t-1,3-Dichloropropene 50.00 51.40 103 46.56 93 55-140 10 0-20

Ethylbenzene 50.00 55.68 111 49.97 100 75-125 11 0-20

Methylene Chloride 50.00 50.22 100 45.73 91 55-140 9 0-20

4-Methyl-2-Pentanone 50.00 54.02 108 53.18 106 60-135 2 0-20

Styrene 50.00 57.70 115 51.37 103 65-135 12 0-20

1,1,1,2-Tetrachloroethane 50.00 54.96 110 48.81 98 80-130 12 0-20

1,1,2,2-Tetrachloroethane 50.00 53.84 108 48.76 98 65-130 10 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

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Page 32 of 41
Quality Control - LCS/LCS Duplicate

Method: GC/MS / EPA 8260B

13-02-0014

Red Hill LTM 112066

Preparation: EPA 5030C

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/01/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

GC/MS OO 130201L01

Date

Prepared

Date

Analyzed

02/01/13

Quality Control Sample ID

099-13-057-6

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

Tetrachloroethene 50.00 49.02 98 42.19 84 45-150 15 0-20

Toluene 50.00 53.16 106 47.42 95 75-120 11 0-20

1,2,4-Trichlorobenzene 50.00 57.56 115 52.08 104 65-135 10 0-20

1,1,1-Trichloroethane 50.00 52.63 105 46.97 94 65-130 11 0-20

Hexachloro-1,3-Butadiene 50.00 54.99 110 48.08 96 50-140 13 0-20

1,1,2-Trichloroethane 50.00 53.21 106 48.60 97 75-125 9 0-20

Trichloroethene 50.00 51.83 104 45.11 90 70-125 14 0-20

1,2,3-Trichloropropane 50.00 52.77 106 49.16 98 75-125 7 0-20

Vinyl Chloride 50.00 46.51 93 42.00 84 50-145 10 0-20

p/m-Xylene 100.0 112.3 112 100.4 100 75-130 11 0-20

o-Xylene 50.00 57.68 115 52.20 104 80-120 10 0-20

Methyl-t-Butyl Ether (MTBE) 50.00 54.47 109 50.84 102 65-125 7 0-20

Gasoline Range Organics 1000 1007 101 1062 106 80-120 5 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 33 of 41
Quality Control - LCS/LCS Duplicate

Method: GC/MS / EPA 8260B

13-02-0014

Red Hill LTM 112066

Preparation: EPA 5030C

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/04/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

GC/MS OO 130204L01

Date

Prepared

Date

Analyzed

02/04/13

Quality Control Sample ID

099-13-057-5

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

Acetone 50.00 67.27 135 57.57 115 40-140 16 0-20

Benzene 50.00 45.55 91 46.28 93 80-120 2 0-20

Bromodichloromethane 50.00 49.55 99 49.67 99 75-120 0 0-20

Bromoform 50.00 55.22 110 55.34 111 70-130 0 0-20

Bromomethane 50.00 43.27 87 43.20 86 30-145 0 0-20

2-Butanone 50.00 49.03 98 50.67 101 30-150 3 0-20

Carbon Tetrachloride 50.00 47.77 96 48.10 96 65-140 1 0-20

Chlorobenzene 50.00 47.25 94 48.15 96 80-120 2 0-20

Chloroethane 50.00 48.74 97 49.19 98 60-135 1 0-20

Chloroform 50.00 46.70 93 47.15 94 65-135 1 0-20

Chloromethane 50.00 41.43 83 41.22 82 40-125 1 0-20

Dibromochloromethane 50.00 49.80 100 51.14 102 60-135 3 0-20

1,2-Dibromo-3-Chloropropane 50.00 49.18 98 52.32 105 50-130 6 0-20

1,2-Dibromoethane 50.00 49.44 99 50.84 102 80-120 3 0-20

1,2-Dichlorobenzene 50.00 48.69 97 49.77 100 70-120 2 0-20

1,3-Dichlorobenzene 50.00 48.80 98 49.96 100 75-125 2 0-20

1,4-Dichlorobenzene 50.00 48.34 97 49.24 98 75-125 2 0-20

1,1-Dichloroethane 50.00 45.23 90 45.92 92 70-135 2 0-20

1,2-Dichloroethane 50.00 45.76 92 46.13 92 70-130 1 0-20

1,1-Dichloroethene 50.00 39.52 79 40.08 80 70-130 1 0-20

c-1,2-Dichloroethene 50.00 47.45 95 48.42 97 70-125 2 0-20

t-1,2-Dichloroethene 50.00 47.22 94 47.53 95 60-140 1 0-20

1,2-Dichloropropane 50.00 48.31 97 49.14 98 75-125 2 0-20

c-1,3-Dichloropropene 50.00 52.65 105 53.06 106 70-130 1 0-20

t-1,3-Dichloropropene 50.00 45.61 91 46.99 94 55-140 3 0-20

Ethylbenzene 50.00 49.76 100 50.64 101 75-125 2 0-20

Methylene Chloride 50.00 44.15 88 45.23 90 55-140 2 0-20

4-Methyl-2-Pentanone 50.00 48.24 96 49.97 100 60-135 4 0-20

Styrene 50.00 51.11 102 52.37 105 65-135 2 0-20

1,1,1,2-Tetrachloroethane 50.00 49.85 100 51.42 103 80-130 3 0-20

1,1,2,2-Tetrachloroethane 50.00 46.24 92 48.68 97 65-130 5 0-20

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

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Page 34 of 41
Quality Control - LCS/LCS Duplicate

Method: GC/MS / EPA 8260B

13-02-0014

Red Hill LTM 112066

Preparation: EPA 5030C

Work Order No:

Date Received:

Project:

Environmental Science International, Inc.

354 Uluniu Street, Suite 304

Kailua, HI 96734-2500

N/A

02/04/13

Matrix

Aqueous

Instrument

LCS/LCSD Batch

Number

GC/MS OO 130204L01

Date

Prepared

Date

Analyzed

02/04/13

Quality Control Sample ID

099-13-057-5

Parameter %REC CL RPD RPD CL Qualifiers LCS

%REC

LCSD

%REC

SPIKE

ADDED

LCS

CONC

LCSD

CONC

Tetrachloroethene 50.00 42.79 86 43.81 88 45-150 2 0-20

Toluene 50.00 47.97 96 48.54 97 75-120 1 0-20

1,2,4-Trichlorobenzene 50.00 51.98 104 52.13 104 65-135 0 0-20

1,1,1-Trichloroethane 50.00 48.14 96 48.97 98 65-130 2 0-20

Hexachloro-1,3-Butadiene 50.00 49.87 100 49.23 98 50-140 1 0-20

1,1,2-Trichloroethane 50.00 47.04 94 47.86 96 75-125 2 0-20

Trichloroethene 50.00 46.90 94 46.87 94 70-125 0 0-20

1,2,3-Trichloropropane 50.00 45.90 92 47.96 96 75-125 4 0-20

Vinyl Chloride 50.00 44.01 88 44.08 88 50-145 0 0-20

p/m-Xylene 100.0 100.4 100 102.5 102 75-130 2 0-20

o-Xylene 50.00 51.59 103 52.73 105 80-120 2 0-20

Methyl-t-Butyl Ether (MTBE) 50.00 49.62 99 51.22 102 65-125 3 0-20

Gasoline Range Organics 1000 1245 125 1226 123 80-120 2 0-20 X

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . .

RPD - Relative Percent Difference , CL - Control Limit

Return to Contents

Page 35 of 41
Sample Analysis Summary Report

 WORK ORDER #: 13-02-0014

Instrument

Client Sample

 ID

Date/Time

Method Extraction Analyzed

Chemist

ID

Lab Sample

 Number

 Analytical

Location

1-K ES016 EPA 6020 EPA 3020A T 02/4/2013 16:55 598 ICP/MS 03 1

1-O ES016 EPA 8270C SIM PA EPA 3510C 02/5/2013 17:34 449 GC/MS AA 1

1-L ES016 EPA 8015B (M) EPA 3510C 02/5/2013 2:45 682 GC 45 1

1-B ES016 GC/MS / EPA 8260 EPA 5030C 02/4/2013 14:10 486 GC/MS OO 2

2-G ES017 EPA 6020 EPA 3020A T 02/4/2013 16:58 598 ICP/MS 03 1

2-I ES017 EPA 8270C SIM PA EPA 3510C 02/5/2013 18:00 449 GC/MS AA 1

2-L ES017 EPA 8015B (M) EPA 3510C 02/5/2013 3:02 682 GC 45 1

2-B ES017 GC/MS / EPA 8260 EPA 5030C 02/4/2013 17:15 486 GC/MS OO 2

3-G ES018 EPA 6020 EPA 3020A T 02/4/2013 17:01 598 ICP/MS 03 1

3-I ES018 EPA 8270C SIM PA EPA 3510C 02/5/2013 18:26 449 GC/MS AA 1

3-L ES018 EPA 8015B (M) EPA 3510C 02/5/2013 3:20 682 GC 45 1

3-B ES018 GC/MS / EPA 8260 EPA 5030C 02/4/2013 17:42 486 GC/MS OO 2

4-A ESTrip GC/MS / EPA 8260 EPA 5030C 02/1/2013 20:00 486 GC/MS OO 2

Location Description

1 7440 Lincoln Way, Garden Grove, CA 92841

2 7445 Lampson Avenue, Garden Grove, CA 92841

02/07/13 1

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Page 36 of 41
Glossary of Terms and Qualifiers

Work Order Number:

Qualifier Definition

13-02-0014

* See applicable analysis comment.

< Less than the indicated value.

> Greater than the indicated value.

Surrogate compound recovery was out of control due to a required sample dilution. Therefore, the sample

data was reported without further clarification.

1

Surrogate compound recovery was out of control due to matrix interference. The associated method blank

surrogate spike compound was in control and, therefore, the sample data was reported without further

clarification.

2

Recovery of the Matrix Spike (MS) or Matrix Spike Duplicate (MSD) compound was out of control due to

matrix interference. The associated LCS and/or LCSD was in control and, therefore, the sample data was

reported without further clarification.

3

The MS/MSD RPD was out of control due to matrix interference. The LCS/LCSD RPD was in control and,

therefore, the sample data was reported without further clarification.

4

The PDS/PDSD or PES/PESD associated with this batch of samples was out of control due to a matrix

interference effect. The associated batch LCS/LCSD was in control and, hence, the associated sample

data was reported without further clarification.

5

6 Surrogate recovery below the acceptance limit.

7 Surrogate recovery above the acceptance limit.

B Analyte was present in the associated method blank.

BU Sample analyzed after holding time expired.

The Detection Limit (DL) is the smallest analyte concentration that can be demonstrated to be different

from zero or a blank concentration at the 99% level of confidence.

DL

E Concentration exceeds the calibration range.

ET Sample was extracted past end of recommended max. holding time.

HD The chromatographic pattern was inconsistent with the profile of the reference fuel standard.

ICH Initial calibrtn. verif. recov. above method CL for this analyte.

ICJ Initial calibrtn. verif. recov. below method CL for this analyte.

IH Calibrtn. verif. recov. below method CL for this analyte.

IJ Calibrtn. verif. recov. above method CL for this analyte.

J Analyte was detected at a concentration below the LOQ and above the DL. Reported value is estimated.

The Limit of Detection (LOD) is the smallest amount or concentration of a substance that must be present

in a sample in order to be detected at 99% confidence level.

LOD

The Limit of Quantitation (LOQ) is the lowest concentration of a substance that produces a quantitative

result within specified limits of precision and bias.

LOQ

Spike recovery and RPD control limits do not apply resulting from the parameter concentration in the

sample exceeding the spike concentration by a factor of four or greater.

Q

SG The sample extract was subjected to Silica Gel treatment prior to analysis.

U Undetected at Detection Limit (DL) and is reported as less than the Limit of Detection (LOD).

X % Recovery and/or RPD out-of-range.

Z Analyte presence was not confirmed by second column or GC/MS analysis.

Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for

% moisture. All QC results are reported on a wet weight basis.

MPN - Most Probable Number

 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501 . . Return to Contents

Page 37 of 41
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APPENDIX D 

Historical Groundwater Exceedance Trends 
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0

200400600800

100012001400160018002000220024002600

8/4/2009

10/13/2009

1/26/2010

4/26/2010

10/21/2010

10/21/2010

1/21/2011

1/21/2011

4/21/2011

4/21/2011

7/21/2011

7/21/2011

10/26/2011

10/26/2011

1/24/2012

1/24/2012

4/26/2012

7/19/2012

11/7/2012

11/7/2012

1/30/2013

1/30/2013

Concentration (μg/L)

Date

TPH‐d Concentrations for OWDFMW01

DOH EAL Gross C

Drinking Water T

TPH‐d (μg/L)
600

650

TPH‐d Concentrations for HDMW2253‐03

500550600350400450

(μg/L)

250300350

Concentration DOH EAL Gross C

Drinking Water TTPH‐d (μg/L)

100150200

0

50

9000011112222310/13/200

1/26/201

4/26/201

7/8/201

10/21/201

1/21/201

4/21/201

7/21/201

10/26/201

1/24/201

4/26/201

7/19/201

11/7/201

1/30/201

Date
APPENDIX E 

Waste Disposal Manifest 
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