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# ATTACHMENT C: FLASHING EMISSIONS CALCULATIONS

• E&P Tanks Emission Summary

• E&P Tanks Linear Relationship (Emission Factor)Van Hook Field 1000 BOPD wt%

****************************************************************************************** * Project Setup Information *
****************************************************************************************** Project File : Y:\Projects\Williams Exploration & Production WEP\WEP211324 Ft. Berthold IR Well Work\E&P Tanks\Van Hook Field 1000 BOPD.ept Flowsheet Selection : Oil Tank with Separator Calculation Method : RVP Distillation Control Efficiency : 100.0% Known Separator Stream : Low Pressure Oil Entering Air Composition : No
Filed Name : Van Hook Well Name : Pennington 16-15H and Van Hook 16-14H Averages Permit Number : Dakota-3 E&P Company, LLC Date : 2010.09.24

****************************************************************************************** * Data Input *
****************************************************************************************** Separator Pressure : 52.00[psig] Separator Temperature : 90.00[F] Ambient Pressure : 13.70[psia] Ambient Temperature : 50.00[F] C10+ SG : 0.7970 C10+ MW : 233.494
-- Low Pressure Oil ---------------------------------------------------------------------- No. Component wt % 1 H2S 0.0027 2 O2 0.0000 3 CO2 0.0038 4 N2 0.0008 5 C1 0.0261 6 C2 0.3417 7 C3 1.3723 8 i-C4 0.3662 9 n-C4 1.6928 10 i-C5 0.6858 11 n-C5 1.2496 12 C6 1.4712 13 C7 7.9550 14 C8 19.2940 15 C9 13.4810 16 C10+ 49.4241 17 Benzene 0.0470 18 Toluene 0.1281 19 E-Benzene 0.0586 20 Xylenes 0.3912 21 n-C6 1.5420 22 224Trimethylp 0.4660
-- Sales Oil ----------------------------------------------------------------------------- Production Rate : 1000[bbl/day] Days of Annual Operation : 365 [days/year] API Gravity : 41.5 Reid Vapor Pressure : 6.20[psia]

****************************************************************************************** * Calculation Results *
****************************************************************************************** -- Emission Summary ---------------------------------------------------------------------- Item Uncontrolled Uncontrolled [ton/yr] [lb/hr] Page 1---------------------------------------------------------------- E&P TANK
Total HAPs 6.040 1.379 Total HC 836.657 191.018 VOCs, C2+ 823.270 187.961 VOCs, C3+ 649.305 148.243 Page 1Van Hook Field 1000 BOPD wt% Uncontrolled Recovery Info. Vapor 41.5700 [MSCFD] HC Vapor 41.3600 [MSCFD] GOR 41.57 [SCF/bbl] -- Emission Composition ------------------------------------------------------------------ No Component Uncontrolled Uncontrolled [ton/yr] [lb/hr] 1 H2S 1.343 0.307 2 O2 0.000 0.000 3 CO2 1.941 0.443 4 N2 0.412 0.094 5 C1 13.387 3.056 6 C2 173.965 39.718 7 C3 448.169 102.322 8 i-C4 34.294 7.830 9 n-C4 102.418 23.383 10 i-C5 13.956 3.186 11 n-C5 18.394 4.200 12 C6 6.270 1.432 13 C7 10.476 2.392 14 C8 7.517 1.716 15 C9 1.774 0.405 16 C10+ 0.002 0.000 17 Benzene 0.156 0.036 18 Toluene 0.111 0.025 19 E-Benzene 0.016 0.004 20 Xylenes 0.090 0.021 21 n-C6 5.168 1.180 22 224Trimethylp 0.493 0.113 Total 840.352 191.861

-- Stream Data --------------------------------------------------------------------------- No. Component MW LP Oil Flash Oil Sale Oil Flash Gas W&S Gas Total Emissions wt % wt % wt % wt % wt % wt % 1 H2S 34.80 0.0027 0.0024 0.0001 0.1791 0.1609 0.1631 2 O2 32.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 3 CO2 44.01 0.0038 0.0026 0.0000 0.5796 0.1818 0.2307 4 N2 28.01 0.0008 0.0001 0.0000 0.3282 0.0099 0.0490 5 C1 16.04 0.0261 0.0112 0.0000 7.4009 0.7777 1.5911 6 C2 30.07 0.3417 0.2811 0.0024 30.3262 19.3302 20.6806 7 C3 44.10 1.3723 1.3000 0.5065 37.1767 55.5360 53.2811 8 i-C4 58.12 0.3662 0.3594 0.3044 3.7640 4.1203 4.0766 9 n-C4 58.12 1.6928 1.6719 1.5180 12.0581 12.1907 12.1744 10 i-C5 72.15 0.6858 0.6836 0.6696 1.7610 1.6447 1.6590 11 n-C5 72.15 1.2496 1.2474 1.2340 2.3296 2.1666 2.1866 12 C6 86.16 1.4712 1.4725 1.4830 0.8134 0.7577 0.7645 13 C7 100.20 7.9550 7.9683 8.0662 1.3546 1.2768 1.2865 14 C8 114.23 19.2940 19.3310 19.6004 0.9553 0.9145 0.9195 15 C9 128.28 13.4810 13.5078 13.7022 0.2134 0.2208 0.2201 16 C10+ 233.49 49.4241 49.5238 50.2483 0.0000 0.0000 0.0000 17 Benzene 78.11 0.0470 0.0471 0.0475 0.0197 0.0184 0.0186 18 Toluene 92.13 0.1281 0.1283 0.1300 0.0137 0.0131 0.0132 19 E-Benzene 106.17 0.0586 0.0587 0.0596 0.0020 0.0020 0.0018 20 Xylenes 106.17 0.3912 0.3920 0.3976 0.0109 0.0106 0.0109 21 n-C6 86.18 1.5420 1.5438 1.5575 0.6517 0.6091 0.6143 22 224Trimethylp 114.24 0.4660 0.4668 0.4728 0.0617 0.0581 0.0587

MW 137.41 138.18 142.90 36.81 42.83 41.99 Stream Mole Ratio 1.0000 0.9924 0.9456 0.0076 0.0468 0.0544 Heating Value [BTU/SCF] 2105.43 2442.60 2395.38 Gas Gravity [Gas/Air] 1.27 1.48 1.45 Bubble Pt. @ 100F [psia] 29.55 23.39 7.57 Page 2---------------------------------------------------------------- E&P TANK RVP @ 100F [psia] 15.49 13.82 6.27 Spec. Gravity @ 100F 0.673 0.674 0.677

Page 2Emission estimates are based on using the E&P TANK V2.0 Model, RVP Distillation Column As shown below, the E&P Tanks summary output has a linear relationship with the production rate of the oil with the given inputs listed below.


### Inputs: Low pressure oil from average of 2 representative Van Hook Field Dakota-3 Wells Separator: 52 psig, 90 degF Flash Valve: 13.7 psia, 50 degF Sales Oil: API Gravity 41.5, Reid Vapor Pressure 6.2 psia, 365 days/year
Outputs: Oil Production Rates (bbl/day) (P) 0 50 100 300 1000 Emission (tons/yr) Total HC 0 41.83255 83.6651 250.9953 836.651 VOCs, C3+ 0 32.46485 64.9297 194.7891 649.297 Total HAPs 0 0.302 0.604 1.812 6.04
VOC (C3+) Emission Factor: 0.6493 tpy/BOPD HAP Emission Factor: 0.00604 tpy/BOPD Oil Storage Tank Flashing Emissions Calculation Methodology E&P Tanks Linear Relation between Production (bbls/day) and Emissions (tons/yr)

y = 0.00604x R 2 = 1.00000 y = 0.6493x R 2 = 1

-100 0 100 200 300 400 500 600 700

0 500 1000 1500tons/year



### bbl/day 

### Tank Emissions by Production Rate

Total HAPs VOCs, C3+ Linear (Total HAPs) Linear (VOCs, C3+)Dakota-3 E&P Company, LLC. NSR Synthetic Minor Application WEP211324 

# ATTACHMENT D: REPRESENTATIVE LOW PRESSURE OIL ANALYTICAL DATA

### Company

.................... ZENERGY 

### Lab Number

................ CR

Ͳ 10330 Study Number.......... CR

Ͳ 5 Date Sampled

.............. 7

Ͳ 15

Ͳ 2010 Date Tested............. 7

Ͳ 23

Ͳ 2010

S l Id tifi ti VAN HOOK 16 14 H CRUDE OIL 

### EXTENDED HYDROCARBON (GLYCALC) LIQUID STUDY

Samp l e I d enti f ication

.................... V AN H OO K 16-14 H C RUDE O IL



### Sample Location .......... MONTANA. Sample Pressure ......... 28 PSIG Sample Temperature.... 80 F Type Sample ............... SPOT County...................... MONTRAIL Test method ................ 

### GPA

Ͳ 2286 Sampling Method........ YZ PISTON

Components Mole % Weight % Liq. Vol. % Hydrogen Sulfide

.......... 0.009 0.002 0.002 

### Oxygen

...................... 0.000 0.000 0.000 

### Carbon Dioxide

............ 0.010 0.003 0.003 

### Nitrogen

..................... 0.003 0.001 0.001 

### Methane 0 184 0 021 0 051



### ..................... . . . 

### Ethane

....................... 1.152 0.241 0.501 

### Propane

..................... 3.568 1.096 1.600 

### iso

Ͳ Butane

.................. 0.778 0.315 0.414



### n

Ͳ Butane

.................... 3.694 1.496 1.896 

### iso

Ͳ Pentane

................ 1.242 0.624 0.739



### n

Ͳ Pentane

................... 2.270 1.141 1.339 

### H 2 276 1 367 1 523 

### exanes

..................... . . . 

### Heptanes

.................... 10.418 7.274 7.823 

### Octanes

..................... 24.125 19.203 20.117 

### Nonanes

..................... 16.003 14.302 14.658 

### Decanes+

................... 30.668 50.576 46.892 

### Benzene...................... 0.090 0.049 0.041 

### Toluene....................... 0.183 0.117 0.100 

### Ethylbenzene............... 0.047 0.035 0.030 

### Xylenes....................... 0.455 0.337 0.288



### n

Ͳ Hexane

.................... 2.304 1.384 1.542 

### 2,2,4

Ͳ Trimethylpentane... 0.521 0.415 0.441 

### TOTALS

..................... 100.000 100.000 100.000ADDITIONAL BETX DATA



### Components Mole % Weight % Liq. Vol. % 2-Methylpentane 1.293 0.777 0.866 3-Methylpentane 0 983 0 590 0 658 3

- Methylpentane

. . . n-Hexane 2.304 1.384 1.542 2,2,4-Trimethylpentane 0.521 0.415 0.441
Benzene 0.090 0.049 0.041
Toluene 0.183 0.117 0.100 Ethylbenzene 0.047 0.035 0.030 m-Xylene 0.056 0.041 0.035 p-Xylene 0.291 0.216 0.184 o-Xylene 0.108 0.080 0.068

API GRAVITY AT 60/60 F, calculated........................................................................ 59.7 SPECIFIC GRAVITY AT 60/60 F, calculated.............................................................. 0.7402 RELATIVE SPECIFIC GRAVITY OF DECANES+ (C10+) FRACTION ............................... 0.7983 AVERAGE MOLECULAR WEIGHT .......................................................................... 143.505 AVERAGE MOLECULAR WEIGHT OF DECANES+ (C10+) FRACTION .......................... 236.660 TRUE VAPOR PRESSURE AT 100 F PSIA calculated 28 847 TRUE VAPOR PRESSURE AT 100 F
, PSIA

, calculated

................................................ . AVERAGE BOILING POINT, F, ................................................................................ 308.034 CUBIC FEET OF GAS / GALLON OF LIQUID, as Ideal Gas .......................................... 18.973 BTU / GALLON OF LIQUID AT 14.73 PSIA, calculated ................................................. 122702.719 LBS / GALLON OF LIQUID, calculated ...................................................................... 6.171

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

TO THE NATURAL GAS INDUSTRY.

### EXTENDED HYDROCARBON LIQUID STUDIES



## CERTIFICATE OF ANALYSIS

Company................ ZENERGY

L bN b CR 10330 St d N b a umer............. CR-10330 Study Number............ CR-5B Date Sampled............. 7-15-2010 Date Tested.............. 7-22-2010

Sample Identification................ VAN HOOK 16-14 H CRUDE OIL

Sample Location......... MONTANA. Sample Pressure.......... N/A Sample Temperature.... N/A
Flowrate................... N/A County..................... MONTRAIL

Test Method.............. VARIOUS Sample Container........ 1-QUART BOTTLE

TEST PERFORMED RESULTS

A PI GRAVITY AT 60/60 F (ASTM D-287), observed...................... 41.2 / ( ),

SPECIFIC GRAVITY AT 60/60 F (ASTM D-1657), calculated.......... 0.8193

REID VAPOR PRESSURE (ASTM D-323), PSIG AT 100 F.............. 4.6 PSIG

TOTAL SULFUR CONTENT (ASTM D-5453), PPMW.................. 1,562.18 PPMW

TRUE VAPOR PRESSURE (ASTM D-2889), PSIA AT 100 F ........... N/A

BASIC SEDIMENT AND WATER CONTENT, % BY VOLUME.... N/A

COPPER STRIP CORROSION (ASTM D-130), 1 HOUR AT 100 F........... N/A

FREE WATER, observed......................................................... N/A

NOTATION : ALL TESTING PROVIDED ABOVE WAS PERFORMED IN ACCORDANCE TO METHODOLOGY OUTLINED BY THE AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM).

### 5HSRUW5HSRUW(GLWRU

Chromatogram VanHook 16-14 C:\GCsolution\DRO\DRO Data\08-2010\08-01-2010\VanHook 16-14.gcd - Channel 1min Intensity 0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0 0 50000 100000 150000 200000 250000

1.055 / 1.137 / 1.307 / 1.405 / 1.552 / 1.669 / 1.729 / 1.901 / 2.038 / 2.108 / 2.280 / 2.361 / 2.417 / 2.564 / 2.666 / 2.854 / 2.948 / 3.034 / 3.135 /

3.210 / 3.301 / 3.420 / 3.538 / 3.638 / 3.772 / 3.857 / 3.966 / 4.069 / 4.147 / 4.333 / 4.508 / 4.582 / 4.693 / 4.899 / 5.021 /

5.165 / 5.364 / 5.509 / 5.608 / Decane (C10) 5.816 / 5.947 / 6.069 / 6.190 / 6.289 / 6.392 / 6.510 /

6.562 / 6.657 / 6.713 / 6.778 / 6.903 / 7.082 / 7.220 / 7.323 / 7.381 / 7.455 / 7.559 / 7.632 / 7.745 / 7.831 / 7.906 /

7.967 / 8.056 / 8.184 / 8.269 / 8.326 / 8.451 / 8.540 / 8.632 / 8.744 / 8.807 / 8.998 / 9.127 /

9.270 / 9.380 / 9.467 / 9.526 /

9.595 / 9.724 / 9.861 / 9.939 / 10.055 / 10.125 / 10.256 / 10.332 / 10.425 /

10.487 / 10.569 / 10.639 / 10.828 / 10.912 /

11.054 / 11.219 /

11.470 / 11.614 / 11.785 / 12.031 / 12.130 / 12.183 / 12.301 / 12.412 / 12.607 / 12.705 / 12.822 / 13.004 / 13.087 / 13.300 / 13.367 / 13.454 / 13.582 / 13.672 / 13.726 / 13.925 / 14.089 / 14.146 / 14.315 / 14.446 /

14.518 / 14.594 / 14.691 / 14.776 / 14.896 / 15.041 / 15.130 / 15.242 / 15.297 /

15.369 / 15.430 / 15.565 / 15.626 / 15.792 /

15.884 / 15.948 / o-terphenyl 16.062 / 16.183 / 16.346 / 16.458 / 16.570 / 16.667 / 16.813 / 16.896 / 16.987 / 17.134 / 17.231 / 17.310 /

17.450 / 17.528 / 17.642 / 17.765 / 17.957 / 18.048 / 18.140 / 18.222 / 18.289 / 18.436 / 18.589 /

18.722 / 18.914 / 18.981 / 19.082 / 19.197 / 19.332 / 19.465 / 19.623 / 19.673 / 19.783 / 19.850 / 19.928 / 19.997 / 20.067 / 20.181 / 20.252 / 20.368 / 20.446 / 20.500 / 20.633 / 20.762 / 20.792 / 20.873 / 21.032 / 21.137 / 21.213 / 21.310 / 21.411 / 21.473 / 21.528 / 21.626 / 21.725 / 21.801 / 21.880 / 21.970 / 22.051 / 22.098 / 22.215 / 22.368 / 22.429 / 22.605 / Octacosane (C28) 22.722 / 22.823 / 22.885 / 22.945 / 22.995 / 23.073 /

23.221 / 23.292 / 23.353 / 23.417 / 23.532 / 23.600 / 23.660 /

23.821 / 23.896 / 23.952 / 24.047 / 24.180 / 24.301 /

24.406 / 24.591 / 24.643 / 24.750 / 24.810 / 24.881 / 24.977 / 25.158 / 25.337 / 25.421 / 25.573 / 25.745 / 25.809 / 25.959 / 26.054 / 26.221 / 26.392 / 26.509 / 26.605 / 26.710 / 26.802 / 26.946 / 27.105 / 27.178 / 27.281 / 27.449 / 27.533 / 27.670 / 27.787 / 28.002 / 28.136 / 28.277 / 28.724 / 29.009 / 29.145 / 29.457 / 29.673 / 29.860 /

### Company

.................... ZENERGY 

### Lab Number

................ CR

Ͳ 10330 Study Number.............. CR

Ͳ 4 Date Sampled

.............. 7

Ͳ 15

Ͳ 2010 Date Tested................. 7

Ͳ 23

Ͳ 2010

S l Id tifi ti PENNINGTON 16 15 H CRUDE OIL 

### EXTENDED HYDROCARBON (GLYCALC) LIQUID STUDY

Samp l e I d enti f ication

.................... PENNIN G T O N 16-15 H C RUDE O IL



### Sample Location .......... MONTANA. Sample Pressure ......... 75 PSIG Sample Temperature...... 100 F Type Sample ............... SPOT County........................ MONTRAIL Test method ................ 

### GPA

Ͳ 2286 Sampling Method........ YZ PISTON

Components Mole % Weight % Liq. Vol. % Hydrogen Sulfide

.......... 0.012 0.003 0.003 

### Oxygen

...................... 0.000 0.000 0.000 

### Carbon Dioxide

............ 0.013 0.004 0.004 

### Nitrogen

..................... 0.004 0.001 0.001 

### Methane 0 270 0 032 0 078



### ..................... . . . 

### Ethane

....................... 2.018 0.448 0.920 

### Propane

..................... 5.113 1.663 2.400 

### iso

Ͳ Butane

.................. 0.980 0.420 0.546



### n

Ͳ Butane

.................... 4.432 1.900 2.381 

### iso

Ͳ Pentane

................ 1.409 0.750 0.878



### n

Ͳ Pentane

................... 2.562 1.364 1.582 

### H 2 488 1 582 1 743 

### exanes

..................... . . . 

### Heptanes

.................... 11.732 8.673 9.222 

### Octanes

..................... 22.998 19.381 20.074 

### Nonanes

..................... 13.316 12.600 12.767 

### Decanes+

................... 28.387 48.236 44.369 

### Benzene...................... 0.078 0.045 0.037 

### Toluene....................... 0.204 0.139 0.116 

### Ethylbenzene............... 0.107 0.084 0.070 

### Xylenes....................... 0.573 0.449 0.379



### n

Ͳ Hexane

.................... 2.688 1.709 1.883 

### 2,2,4

Ͳ Trimethylpentane... 0.616 0.519 0.545 

### TOTALS

..................... 100.000 100.000 100.000ADDITIONAL BETX DATA



### Components Mole % Weight % Liq. Vol. % 2-Methylpentane 1.398 0.889 0.979 3-Methylpentane 1 090 0 693 0 764 3

- Methylpentane

. . . n-Hexane 2.688 1.709 1.883 2,2,4-Trimethylpentane 0.616 0.519 0.545
Benzene 0.078 0.045 0.037
Toluene 0.204 0.139 0.116 Ethylbenzene 0.107 0.084 0.070 m-Xylene 0.067 0.053 0.045 p-Xylene 0.386 0.302 0.255 o-Xylene 0.120 0.094 0.079

API GRAVITY AT 60/60 F, calculated........................................................................ 61.9 SPECIFIC GRAVITY AT 60/60 F, calculated.............................................................. 0.7318 RELATIVE SPECIFIC GRAVITY OF DECANES+ (C10+) FRACTION ............................... 0.7956 AVERAGE MOLECULAR WEIGHT .......................................................................... 135.548 AVERAGE MOLECULAR WEIGHT OF DECANES+ (C10+) FRACTION .......................... 230.327 TRUE VAPOR PRESSURE AT 100 F PSIA calculated 43 649 TRUE VAPOR PRESSURE AT 100 F
, PSIA

, calculated

................................................ . AVERAGE BOILING POINT, F, ................................................................................ 283.928 CUBIC FEET OF GAS / GALLON OF LIQUID, as Ideal Gas .......................................... 19.480 BTU / GALLON OF LIQUID AT 14.73 PSIA, calculated ................................................. 121815.044 LBS / GALLON OF LIQUID, calculated ...................................................................... 6.102

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

TO THE NATURAL GAS INDUSTRY.

### EXTENDED HYDROCARBON LIQUID STUDIES



## CERTIFICATE OF ANALYSIS

Company................ ZENERGY

L bN b CR 10330 St d N b a umer............. CR-10330 Study Number............ CR-4B Date Sampled............. 7-15-2010 Date Tested.............. 7-22-2010

Sample Identification................ PENNINGTON 16-15 H CRUDE OIL

Sample Location......... MONTANA. Sample Pressure.......... N/A Sample Temperature.... N/A
Flowrate................... N/A County..................... MONTRAIL

Test Method.............. VARIOUS Sample Container........ 1-QUART BOTTLE

TEST PERFORMED RESULTS

A PI GRAVITY AT 60/60 F (ASTM D-287), observed...................... 41.8 / ( ),

SPECIFIC GRAVITY AT 60/60 F (ASTM D-1657), calculated.......... 0.8165

REID VAPOR PRESSURE (ASTM D-323), PSIG AT 100 F.............. 7.8 PSIG

TOTAL SULFUR CONTENT (ASTM D-5453), PPMW.................. 1,435.60 PPMW

TRUE VAPOR PRESSURE (ASTM D-2889), PSIA AT 100 F ........... N/A

BASIC SEDIMENT AND WATER CONTENT, % BY VOLUME.... N/A

COPPER STRIP CORROSION (ASTM D-130), 1 HOUR AT 100 F........... N/A

FREE WATER, observed......................................................... N/A

NOTATION : ALL TESTING PROVIDED ABOVE WAS PERFORMED IN ACCORDANCE TO METHODOLOGY OUTLINED BY THE AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM).

### Report(Report Editor)

Chromatogram Pennington 16-15H C:\GCsolution\DRO\DRO Data\08-2010\08-01-2010\Pennington 16-15H.gcd - Channel 1min Intensity

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0 0 50000 100000 150000 200000

1.054 / 1.137 / 1.405 /

1.552 / 1.669 / 1.730 / 1.901 / 2.039 / 2.109 / 2.281 / 2.362 / 2.418 / 2.564 / 2.667 / 2.854 / 2.949 / 3.035 / 3.135 /

3.210 / 3.301 / 3.421 / 3.539 / 3.637 / 3.740 / 3.857 / 3.967 / 4.069 / 4.148 / 4.334 / 4.509 / 4.583 / 4.693 / 4.901 / 5.022 / 5.166 / 5.365 / 5.512 / 5.609 / Decane (C10) 5.819 / 5.949 / 6.070 / 6.136 / 6.191 / 6.292 / 6.395 / 6.466 / 6.659 / 6.714 / 6.779 / 6.905 / 7.083 / 7.154 /

7.221 /

7.325 / 7.457 / 7.560 / 7.634 / 7.745 / 7.833 / 7.907 /

7.967 / 8.057 / 8.184 / 8.270 / 8.327 / 8.452 / 8.541 / 8.633 / 8.743 / 8.809 / 8.999 / 9.128 /

9.270 / 9.380 / 9.467 / 9.529 /

9.595 / 9.724 / 9.863 / 9.941 / 10.053 / 10.147 / 10.259 / 10.331 / 10.427 /

10.487 / 10.570 / 10.638 / 10.768 /

10.828 / 10.912 / 11.059 / 11.222 / 11.265 / 11.470 / 11.614 / 11.786 / 12.030 / 12.130 / 12.186 / 12.300 / 12.416 / 12.469 / 12.604 / 12.703 / 12.823 / 13.006 / 13.087 / 13.304 / 13.372 / 13.447 / 13.583 / 13.673 / 13.730 / 13.932 / 14.090 / 14.147 / 14.322 / 14.440 /

14.518 / 14.594 / 14.692 / 14.776 / 14.903 / 15.041 / 15.131 / 15.243 / 15.302 /

15.370 / 15.432 / 15.570 / 15.626 / 15.788 /

15.885 / 15.948 / o-terphenyl 16.044 / 16.183 / 16.344 / 16.460 / 16.573 / 16.674 / 16.814 / 16.895 / 16.970 / 17.137 / 17.329 /

17.446 / 17.535 / 17.643 / 17.802 / 17.961 / 18.057 / 18.128 / 18.224 / 18.286 / 18.435 / 18.595 / 18.722 / 18.918 / 18.983 / 19.078 / 19.197 / 19.331 / 19.480 / 19.598 / 19.651 / 19.702 / 19.783 / 19.851 / 19.927 / 20.074 / 20.181 / 20.361 / 20.440 / 20.517 / 20.634 / 20.795 / 20.874 / 21.027 / 21.136 / 21.309 / 21.400 / 21.541 / 21.724 / 21.789 / 21.888 / 21.969 / 22.076 / 22.183 / 22.375 / 22.436 /

22.605 / Octacosane (C28) 22.719 / 22.799 / 22.998 / 23.056 / 23.106 /

23.220 / 23.422 / 23.502 / 23.624 / 23.677 /

23.815 / 23.917 / 23.968 / 24.038 / 24.175 / 24.300 /

24.404 / 24.615 / 24.704 / 24.762 / 24.824 / 24.896 / 24.973 / 25.070 / 25.139 / 25.197 / 25.259 / 25.329 / 25.454 / 25.573 / 25.720 / 25.795 / 25.869 / 25.956 / 26.069 / 26.222 / 26.421 / 26.547 / 26.638 / 26.744 / 26.842 / 26.947 / 27.166 / 27.295 / 27.437 / 27.581 / 27.764 / 27.902 / 28.049 / 28.197 / 28.360 / 28.528 /Dakota-3 E&P Company, LLC. NSR Synthetic Minor Application WEP211324 

# ATTACHMENT E: REPRESENTATIVE GAS ANALYSIS

## 	

	

 	
  
      
    
   
    
   
 
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  47
 
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!# ##"#%#! !##&)
	### Client: BISON ENGINEERING 

### Analysis Date: 10/11/2011
WILLIAMS 

### Sample ID: MARY R SMITH 

### Date Sampled: 10/11/2011



### Unique #: Purpose:

Sample Temperature: 72 DEG F 

### Sample Pressure: 20 PSI



### Sampled By: TC 

### Type Sample: ONLINE



### County: DUNN

Components Mole % Weight % Liq. Vol. % Carbon Dioxide............. 0.445 0.536 0.296 

### Hydrogen Sulfide........... 0.000 0.000 0.000 

### Nitrogen...................... 0.535 0.410 

### 0.230 Methane...................... 24.513 10.763 

### 16.208 Ethane........................ 28.935 23.813 

### 30.180 Propane....................... 27.572 33.276 

### 29.626 iso

Ͳ Butane................... 3.024 4.811 

### 3.860

n

Ͳ Butane...................... 9.829 15.636 

### 12.086 iso

Ͳ Pentane.................. 1.564 3.089 

### 2.231

n

Ͳ Pentane.................... 2.184 4.313 

### 3.088 Cyclopentane............... 0.102 0.195 

### 0.118

n

Ͳ Hexane..................... 0.411 0.970 

### 0.660 Cyclohexane................ 0.075 0.172 

### 0.099 Other Hexanes ............. 0.545 1.287 0.875 

### Heptanes..................... 0.099 0.271 0.178 

### Methylcyclohexane........ 0.028 0.074 0.043 

### 2,2,4

Ͳ Trimethylpentane... 0.000 0.000 0.000 

### Benzene...................... 0.030 0.063 0.032 

### Toluene....................... 0.023 0.058 0.030 

### Ethylbenzene............... 0.003 0.008 0.004 

### Xylenes....................... 0.017 0.050 0.026 

### C8+ Heavies................ 0.066 0.205 

### 0.131 Totals

........................ 100.000 100.000 

### 100.000ADDITIONAL BETX DATA



### Components Mole % Weight % Liq. Vol. % Cyclopentane 0.102 0.195 0.118 Cyclohexane 0.075 0.172 0.099 2-Methylpentane 0.343 0.810 0.551 3-Methylpentane 0.202 0.477 0.324
n-Hexane 0.411 0.970 0.660 Methylcyclohexane 0.028 0.074 0.043 2,2,4-Trimethylpentane 0.000 0.000 0.000
Benzene 0.030 0.063 0.032
Toluene 0.023 0.058 0.030 Ethylbenzene 0.003 0.008 0.004 0 003 0 008 0 004 m-Xylene . . . p-Xylene 0.012 0.034 0.018 o-Xylene 0.003 0.008 0.004

SPECIFIC GRAVITY @ 60/60 F l l t d 1 2615 SPECIFIC GRAVITY @ 60 / 60 F, calculated................................................... . TOTAL GPM (Ethane Inclusive)................................................................. 21.293 CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 2117.258 CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 2081.086 AVERAGE MOLECULAR WEIGHT............................................................ 36.537 MOLAR MASS RATIO.............................................................................. 1.2615 RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 1.2771 IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA 2086 694 IDEAL GROSS HEATING VALUE , BTU / IDEAL CF @ 14

. 696 PSIA

.................. 2086

. 694 COMPRESSIBILITY FACTOR (Z).............................................................. 0.98783

PROPANE GPM ..................................................................................... 7.5766 BUTANE GPM ....................................................................................... 4.0779 GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.9202

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

TO THE NATURAL GAS INDUSTRY.

### Client: BISON ENGINEERING 

### Analysis Date: 10/11/2011
WILLIAMS 

### Sample ID: PENNINGTON 16

Ͳ 15 

### Date Sampled: 10/11/2011



### Unique #: Purpose:

Sample Temperature: 57 DEG F 

### Sample Pressure: 40 PSI



### Sampled By: TC 

### Type Sample: ONLINE



### County: DUNN

Components Mole % Weight % Liq. Vol. % Carbon Dioxide............. 0.612 1.003 0.490 

### Hydrogen Sulfide........... 0.000 0.000 0.000 

### Nitrogen...................... 4.459 4.652 

### 2.300 Methane...................... 53.689 32.081 

### 42.686 Ethane........................ 20.555 23.021 

### 25.781 Propane....................... 13.906 22.839 

### 17.967 iso

Ͳ Butane................... 1.188 2.571 

### 1.823

n

Ͳ Butane...................... 3.555 7.695 

### 5.256 iso

Ͳ Pentane.................. 0.461 1.238 

### 0.790

n

Ͳ Pentane.................... 0.611 1.641 

### 1.038 Cyclopentane............... 0.031 0.081 

### 0.043

n

Ͳ Hexane..................... 0.121 0.389 

### 0.234 Cyclohexane................ 0.058 0.181 

### 0.092 Other Hexanes ............. 0.443 1.423 0.855 

### Heptanes..................... 0.134 0.500 0.290 

### Methylcyclohexane........ 0.045 0.166 0.086 

### 2,2,4

Ͳ Trimethylpentane... 0.000 0.000 0.000 

### Benzene...................... 0.019 0.056 0.025 

### Toluene....................... 0.026 0.089 0.041 

### Ethylbenzene............... 0.003 0.012 0.005 

### Xylenes....................... 0.014 0.055 0.025 

### C8+ Heavies................ 0.072 0.306 

### 0.173 Totals

........................ 100.000 100.000 

### 100.000ADDITIONAL BETX DATA



### Components Mole % Weight % Liq. Vol. % Cyclopentane 0.031 0.081 0.043 Cyclohexane 0.058 0.181 0.092 2-Methylpentane 0.279 0.895 0.538 3-Methylpentane 0.164 0.527 0.317
n-Hexane 0.121 0.389 0.234 Methylcyclohexane 0.045 0.166 0.086 2,2,4-Trimethylpentane 0.000 0.000 0.000
Benzene 0.019 0.056 0.025
Toluene 0.026 0.089 0.041 Ethylbenzene 0.003 0.012 0.005 0 002 0 009 0 004 m-Xylene . . . p-Xylene 0.009 0.037 0.017 o-Xylene 0.002 0.009 0.004

SPECIFIC GRAVITY @ 60/60 F l l t d 0 9270 SPECIFIC GRAVITY @ 60 / 60 F, calculated................................................... . TOTAL GPM (Ethane Inclusive)................................................................. 11.595 CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1511.141 CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1485.576 AVERAGE MOLECULAR WEIGHT............................................................ 26.848 MOLAR MASS RATIO.............................................................................. 0.9270 RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 0.9324 IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA 1498 858 IDEAL GROSS HEATING VALUE , BTU / IDEAL CF @ 14

. 696 PSIA

.................. 1498

. 858 COMPRESSIBILITY FACTOR (Z).............................................................. 0.99415

PROPANE GPM ..................................................................................... 3.8212 BUTANE GPM ....................................................................................... 1.5054 GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 0.7848

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

TO THE NATURAL GAS INDUSTRY.Dakota-3 E&P Company, LLC. NSR Synthetic Minor Application WEP211324 

# ATTACHMENT F: ENGINE MANUFACTURER’S SPECS

# This section of the document has been redacted because it contains copyrighted information. The redacted information

can be viewed from the hard copy of the docket, which is available at the EPA Region 8 Office upon request.Dakota-3 E&P Company, LLC. NSR Synthetic Minor Application WEP211324 

# ATTACHMENT G: EMISSION CONTROL DEVICE MANUFACTURER’S SPECS	

 	





  

# 		 	
  	

### TYPICAL VAN HOOK AREA **THREE WELL PAD FACILITY PLOT PLAN Dakota-3 E&P Company, LLC**  **FBIR, North Dakota**

**NOT TO SCALE Chemicals** 

**(3)Wellheads**

**Tank Vent line**

Utility Flare **Gas to sales Gas Meter** 

12’d x 20’h

12’d x 20’h

12’d x 20’h 400 bbl oik Enclosed Combustor

**Recycle Pump**  **Recycle Pump**  12’d x 20’h

12’d x 20’h

12’d x 20’h 400 bbl oil **Valve Valve** 

**Valve**

**Recycle Line** 6’d x 20’h vertical treater Separator 30” d by 10’ h

6’d x 20’h vertical treater Separator 30” d by 10’ h

6’d x 20’h vertical treater Separator 30” d by 10’ h Gas Meter **(3) Gensets Genset** 

12’d x 20’h

12’d x 20’h

12’d x 20’h 400 bbl oil 12’d x 20’h

12’d x 20’h

12’d x 20’h 400 bbl oil 12’d x 20’h

12’d x 20’h

12’d x 20’h 400 bbl oil 12’d x 20’h 400 bbl

12’d x 20’h

12’d x 20’h 400 bbl oil 12’d x 20’h 400 bbl

12’d x 20’h

12’d x 20’h 400 bbl oil 24 bbl Diesel

**Oil Getty Box**

**Water Getty Box Recycle**  **Pump** Gas Meter

Legend

Berms Water Line Crude Line Flowline Buried Recycle Lines Gas Sales Line Tank Vapor Line Flared Gas Line	

 	





  

# 		 	 		Dakota-3 E&P Company, LLC. NSR Synthetic Minor Application WEP211324 

# ATTACHMENT J: DIESEL TANK EPA TANKS 4.09D **E MISSIONS SUMMARY** 

### TANKS 4.0.9d Emissions Report - Detail Format Tank Indentification and Physical Characteristics

Identification User Identification: 1000 gallon diesel tank City: Williston State: North Dakota Company: Williams E&P, LLC Type of Tank: Horizontal Tank Description: 1,000 gallon diesel tank to fuel onsite diesel generators. Tank throughput is based on engine fuel consumption.

Tank Dimensions Shell Length (ft): 10.00 Diameter (ft): 4.16 Volume (gallons): 1,000.00 Turnovers: 2,244.31 Net Throughput(gal/yr): 2,244,312.00 Is Tank Heated (y/n): N Is Tank Underground (y/n): N

Paint Characteristics Shell Color/Shade: Gray/Medium Shell Condition Good

Breather Vent Settings Vacuum Settings (psig): -0.03 Pressure Settings (psig) 0.03

Meterological Data used in Emissions Calculations: Bismarck, North Dakota (Avg Atmospheric Pressure = 13.86 psia) 

### Page 1 of 6 TANKS 4.0 Report

9/29/2011 file://C:\Program Files\Tanks409d\summarydisplay.htm

### 1000 gallon diesel tank - Horizontal Tank Williston, North Dakota 

### T ANKS 4.0.9d Emissions Report - Detail Format Liquid Contents of Storage Tank

Daily Liquid Surf. Temperature (deg F) Liquid Bulk Temp Vapor Pressure (psia) Vapor Mol. Liquid Mass Vapor Mass Mol. Basis for Vapor Pressure Mixture/Component Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract. Fract. Weight Calculations

Distillate fuel oil no. 2 All 50.18 39.72 60.64 44.68 0.0045 0.0031 0.0067 130.0000 188.00 Option 1: VP50 = .0045 VP60 = .0065 

### Page 2 of 6 TANKS 4.0 Report

9/29/2011 file://C:\Program Files\Tanks409d\summarydisplay.htm

### 1000 gallon diesel tank - Horizontal Tank Williston, North Dakota 

### T ANKS 4.0.9d Emissions Report - Detail Format Detail Calculations (AP-42)

Annual Emission Calcaulations

Standing Losses (lb): 0.2654 Vapor Space Volume (cu ft): 86.5719 Vapor Density (lb/cu ft): 0.0001 Vapor Space Expansion Factor: 0.0780 Vented Vapor Saturation Factor: 0.9995
Tank Vapor Space Volume: Vapor Space Volume (cu ft): 86.5719 Tank Diameter (ft): 4.1600 Effective Diameter (ft): 7.2797 Vapor Space Outage (ft): 2.0800 Tank Shell Length (ft): 10.0000
Vapor Density Vapor Density (lb/cu ft): 0.0001 Vapor Molecular Weight (lb/lb-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature (psia): 0.0045 Daily Avg. Liquid Surface Temp. (deg. R): 509.8466 Daily Average Ambient Temp. (deg. F): 41.5958 Ideal Gas Constant R (psia cuft / (lb-mol-deg R)): 10.731 Liquid Bulk Temperature (deg. R): 504.3458 Tank Paint Solar Absorptance (Shell): 0.6800 Daily Total Solar Insulation Factor (Btu/sqft day): 1,276.2450
Vapor Space Expansion Factor Vapor Space Expansion Factor: 0.0780 Daily Vapor Temperature Range (deg. R): 41.8377 Daily Vapor Pressure Range (psia): 0.0036 Breather Vent Press. Setting Range(psia): 0.0600 Vapor Pressure at Daily Average Liquid Surface Temperature (psia): 0.0045 Vapor Pressure at Daily Minimum Liquid Surface Temperature (psia): 0.0031 Vapor Pressure at Daily Maximum Liquid Surface Temperature (psia): 0.0067 Daily Avg. Liquid Surface Temp. (deg R): 509.8466 Daily Min. Liquid Surface Temp. (deg R): 499.3872 Daily Max. Liquid Surface Temp. (deg R): 520.3060 Daily Ambient Temp. Range (deg. R): 24.3583
Vented Vapor Saturation Factor Vented Vapor Saturation Factor: 0.9995 Vapor Pressure at Daily Average Liquid: Surface Temperature (psia): 0.0045 Vapor Space Outage (ft): 2.0800

Working Losses (lb): 5.6720 Vapor Molecular Weight (lb/lb-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature (psia): 0.0045 Annual Net Throughput (gal/yr.): 2,244,312.0000 

### Page 3 of 6 TANKS 4.0 Report

9/29/2011 file://C:\Program Files\Tanks409d\summarydisplay.htmAnnual Turnovers: 2,244.3120 Turnover Factor: 0.1800 Tank Diameter (ft): 4.1600 Working Loss Product Factor: 1.0000

Total Losses (lb): 5.9375 

### Page 4 of 6 TANKS 4.0 Report

9/29/2011 file://C:\Program Files\Tanks409d\summarydisplay.htm

### Emissions Report for: Annual

1000 gallon diesel tank - Horizontal Tank Williston, North Dakota 

### T ANKS 4.0.9d Emissions Report - Detail Format Individual Tank Emission Totals

Losses(lbs) Components Working Loss Breathing Loss Total Emissions
Distillate fuel oil no. 2 5.67 0.27 5.94 

### Page 5 of 6 TANKS 4.0 Report

9/29/2011 file://C:\Program Files\Tanks409d\summarydisplay.htm

### Page 6 of 6 TANKS 4.0 Report

9/29/2011 file://C:\Program Files\Tanks409d\summarydisplay.htm