UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

CERTIFICATION EVALUATION AND CONCURRENCE
May. 29, 2014 Report Request ID: 1218192 Report Code: AMP600

Selection Criteria Page 1 User ID:HSL

State County City Site Parameter POC AQCR UAR CBSA CSA EPA Region 04 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration
CRITERIA AGENCY SELECTIONS Arizona Department Of Environmental Quality Freeport McMoRan Miami, Inc.
SELECTED OPTIONS

MERGE PDF FILES AGENCY ROLE Option Type Option Value YES CERTIFYING
DATE CRITERIA

2013 Start Date End Date 2013 Tribal CodeMay. 29, 2014 

## Data Evaluation and Concurrence Report Summary

Page 1 of 2 2013 

### Certification Year: Certifying Agency (CA):Arizona Department Of Environmental Quality (0053) 

### Pollutants in Report:

PQAO Parameter Code Carbon monoxide Lead (TSP) LC Lead PM10 LC FRM/FEM Nitrogen dioxide (NO2) Ozone PM10 Total 0-10um STP PM2.5 - Local Conditions Sulfur dioxide 42101 14129 85129 42602 44201 81102 88101 42401 

### Parameter Name Code 1 3 1 1 7 15 11 5

0053 Arizona Department Of Environmental Quality 

### PQAO Code

AQS Site-ID POC AQS Recommended Flag Cert. Agency

Recommended Flag Reason for AQS Recommendation 0053
0053 0053 42101

88101 42602 1
3 1 04-013-9997
04-023-0004 04-013-9997 N
N N Y

Y Y Quality Assurance Project Plan not approved in 10

years. Flow Rate Audit completeness < 65%. Quality Assurance Project Plan not approved in 10 years. 

### Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name Summary of 'N' flags for all pollutants: 0 3 1 0 7 15 10 5 1 0 0 1 0 0 1 0 

### PQAOs in Report:

04/09/12 

### TSA Date Monitors Evaluated Monitors Recommended for

Concurrence by AQS Monitors NOT Recommended for Concurrence by AQSMay. 29, 2014 

## Data Evaluation and Concurrence Report Summary

Page 2 of 2 2013 

### Certification Year: Certifying Agency (CA):Freeport McMoRan Miami, Inc. (1357) 

### Pollutants in Report:

PQAO Parameter Code PM10 Total 0-10um STP 81102 

### Parameter Name Code 3

1357 Freeport McMoRan Miami, Inc. 

### PQAO Code

AQS Site-ID POC AQS Recommended Flag Cert. Agency

Recommended Flag Reason for AQS Recommendation Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name Summary of 'N' flags for all pollutants: 3 0 

### PQAOs in Report: TSA Date Monitors Evaluated Monitors Recommended for

Concurrence by AQS Monitors NOT Recommended for Concurrence by AQS

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2013 Certifying Year Certifying Agency CodeArizona Department Of Environmental Quality (0053) Carbon monoxide (42101) (ppm) Arizona Department Of Environmental Quality (0053) PQAO Name 08/06/1994 QAPP Approval Date

1 04-013-9997 SLAMS 0.416 Mean
0.010

Min
3.239 Max
0 Exceed. Count 0

Outlier Count 87 Perc. Comp. 9.48

Precision
+/-7.38

Bias
100 Complete
100 Complete Bias
Y

PQAO Level Criteria N Aqs Rec Flag Y

CA Rec Flag S Epa Eval.
The AQS recommended flag is the result of not having Submitter Comment 

### Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met NPAP Audit Summary:

15.90 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2013 Certifying Year Certifying Agency CodeArizona Department Of Environmental Quality (0053) Nitrogen dioxide (NO2) (42602) (ppb) Arizona Department Of Environmental Quality (0053) PQAO Name QAPP Approval Date

1 04-013-9997 SLAMS 17.0 Mean
1.0

Min
72.0 Max Exceed. Count 0

Outlier Count 87 Perc. Comp. 6.89

Precision

+7.41

Bias
88 Complete
100 Complete Bias
Y

PQAO Level Criteria N Aqs Rec Flag Y

CA Rec Flag S Epa Eval.
The AQS recommended flag is the result of not having Submitter Comment 

### Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met NPAP Audit Summary:

2.16 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2013 Certifying Year Certifying Agency CodeArizona Department Of Environmental Quality (0053) Ozone (44201) (ppm) Arizona Department Of Environmental Quality (0053) PQAO Name 12/31/2013 QAPP Approval Date

1 1 1 1 1 1 1 04-005-1008 04-007-0010 04-012-8000 04-013-9997 04-021-8001 04-025-8033 04-027-8011 SLAMS

SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS 0.056

0.061 0.057 0.055 0.062 0.053 0.056 Mean
0.035 0.037 0.035 0.021 0.037 0.025 0.029 Min
0.078 0.096 0.076 0.095 0.094 0.077 0.087 Max
0

0 0 0 0 0 0 Exceed. Count 0

0 0 0 0 0 0 Outlier Count 97

99 99 95 99 100 98 Perc. Comp. 1.92

1.10 1.18 3.86 2.35 0.66 1.14 Precision
+3.50

+1.88 +/-1.07 +/-3.25 +/-1.95 +1.16 +1.32 Bias
100

100 100 100 100 100 100 Complete
100 100 100 100 100 100 100 Complete

1.41

1.41 Bias
Y

Y Y Y Y Y Y PQAO Level Criteria Y Y Y Y Y Y Y Aqs Rec Flag Y

Y Y Y Y Y Y CA Rec Flag S

S S S S S S Epa Eval. 

### Parameter

2 Y Number of Valid Audits NPAP Bias Criteria Met NPAP Audit Summary: 1.40845

- 0.21 - 1.35 - 1.29 8.55 - 3.52 1.17 - 0.54 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. Y Y Y Y Y Y Y

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2013 Certifying Year Certifying Agency CodeArizona Department Of Environmental Quality (0053) Sulfur dioxide (42401) (ppb) Arizona Department Of Environmental Quality (0053) PQAO Name 12/31/2013 QAPP Approval Date

1 1 1 3 1 04-007-0009 04-007-0011 04-007-0012 04-007-1001 04-013-9997 SLAMS

SLAMS SLAMS SLAMS SLAMS 5.4

3.3 1.9 6.9 0.8 Mean
2.0

0.0 0.0 0.0 0.0 Min
193.0 205.0 171.0 310.0 7.8 Max Exceed. Count 0

0 0 0 0 Outlier Count 100

92 92 97 88 Perc. Comp. 3.20

5.57 14.67 5.26 16.53 Precision
+5.67

+/-4.50 +9.33 +/-4.19 +11.71 Bias
100

100 100 96 100 Complete
100 100 100 100 100 Complete Bias
Y Y Y Y Y PQAO Level Criteria Y Y Y Y Y Aqs Rec Flag Y

Y Y Y Y CA Rec Flag S

S S S S Epa Eval.

An audit performed on 11/21/13 failed. A previous aud Submitter Comment 

### Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met NPAP Audit Summary:

7.53 10.33 5.90 1.88 3.11 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. Y Y Y Y Y

# Data Evaluation and Concurrence Report for Particulate Matter

2013 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency:PM10 Total 0-10um STP (81102) CONTINUOUS

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/08/2013 Quality Assurance Project Plan Approval Date: Monitors Summaries

Monitor Type Mean Min MaxExceed. CountOutlier Count % Complete Bias %

Complete Bias %

Complete Flow Rate Verification Flow Rate Audit Routine Data (ug/m3) Concurrence Flag AQS Rec Flag CA Rec

Flag EPA Eval. 04-003-0011 04-003-1005 04-007-1001 04-007-8000

04-013-9997 04-015-1003 04-019-0001 04-019-0020 04-023-0004
04-027-8011 3

3 3 3

3 3 3 3 3
3 SLAMS

SLAMS SLAMS SLAMS

SLAMS SLAMS SLAMS SLAMS SPECIAL PURPOSE SLAMS 21.21

37.72 43.37 22.90

30.68 21.20 29.02 40.84 46.47
41.50-21.0 -22.0 -30.0 -34.0

2.0 -26.0 -16.0 -18.0 2.0
-43.0******** 924.0

******** 405.0

******** 568.0

********

******** 985.0

******** 0

0 0 0

0 0 0 0 0
0 91 99 97 97

99 97 99 99 75
97 AQS Site IDPOC +/-1.50 +/-0.97 +/-2.49 +/-1.17

+/-0.85 +/-0.99 +/-1.73 +/-0.81 +/-5.27
+/-1.30 100

100 100 100

100 100 100 100 100
100 -3.15

-1.18 -2.79 -1.41

+1.08 +0.19 -2.87 -0.05 -1.04
-0.18 100

100 100 70

100 100 100 100 100
100 Y

Y Y Y

Y Y Y Y Y
Y Y

Y Y Y

Y Y Y Y Y
Y Submitter Comment: Two flow rate audits were peformed on this monitor during

2013. One was performed in 1st quarter on March 6, 2013 and one was performed in 3rd quarter on July 25, 2013. These two audits were less than five months apart, which is the reason why the AMP 60 EPA Comment: QAPP Appr. Y Y Y Y

Y Y Y Y Y
Y S S S S

S S S S S
S

# Data Evaluation and Concurrence Report for Particulate Matter

2013 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency:PM10 Total 0-10um STP (81102) INTERMITTENT

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/08/2013 Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites# Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? 4 1 1 100 7.31 8.39 Y 

### Monitors Summaries

Monitor Type Mean Min MaxExceed. CountOutlier Count % Complete Bias %

Complete Flow Rate Audit Collocation % Complete CV PQAO

Crit. Met Routine Data (ug/m3) Concurrence Flag AQS Rec Flag CA Rec

Flag EPA Eval. 04-005-1008 04-007-0008 04-007-0008 04-023-0004 04-025-2002 1

1 2 1 1 SLAMS

SLAMS SLAMS SLAMS SLAMS 15.90

19.15 18.49 35.66 11.91 2.0 2.0 2.0 5.0 2.0 30.0 58.0 54.0 89.0 51.0 0

0 0 0 0 0 0 0 0 0 100 98 95 96 91 AQS Site IDPOC -0.68 -0.36 -0.13 -1.51 -1.39 100

100 100 100 100 100 8.39 Y

Y Y Y Y Y

Y Y Y Y Y

Y Y Y Y QAPP Appr. Y Y Y Y Y S S S S S

# Data Evaluation and Concurrence Report for Particulate Matter

2013

2013 Arizona Department Of Environmental Quality (0053)

Freeport McMoRan Miami, Inc. (1357) Certifying Year:

Certifying Year: Certifying Agency:

Certifying Agency:PM2.5 - Local Conditions (88101)

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/08/2013 Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites# Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? Method 143 170 6

3 1 1 1

1 100

100 2.74 13.933.68 16.50 Y

Y 

### PEP Summary

# Methods# Audited

Methods # PEP

Required # PEP

Submitted %

Complete Bias Criteria Met? 2 0 8 6 75 +4.62 Y


### Monitors Summaries

MethodMonitor

Type Mean Min MaxExceed. CountOutlier Count % Complete Bias %

Complete Flow Rate Audit Collocation % Complete CV PQAO

Crit. Met PEP

PQAO Crit. Met Routine Data (ug/m3) Concurrence Flag AQS Rec Flag CA Rec

Flag EPA Eval. 04-003-1005 04-003-1005 04-005-1008 04-013-9997 04-013-9997 04-023-0004 04-023-0004 04-025-2002 04-027-8011 04-027-8011 04-023-0004 1

3 1 1 3 1 2 1 1 3 3 143 170 143 143 170 143 143 143 143 170 170 SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SPECIAL PURPOSE 7.25

6.75 5.43 8.41 7.18 9.91 9.63 4.14 8.84 6.10 8.76 2.4 -8.0 1.0 1.9 -8.0 3.5 2.5 1.1 1.1 -8.0 -6.0 17.5 65.0 11.1 40.5 454.0 35.0 34.2 9.7 26.7 213.0 337.0 0

0 0 0 0 0 0 0 0 0 0 96 91 100 100 91 96 93 96 100 89 85 AQS Site IDPOC -0.83 -2.22 -0.65 -1.36 -1.44 -1.27 -1.94 -0.48 -0.75 -0.78 -1.07 100

100 100 100 100 100 100 100 100 100 50 50

100 3.68

16.50 Y

Y Y Y Y Y Y Y Y Y Y Y

Y Y Y Y Y Y Y Y Y Y Y

Y Y Y Y Y Y Y Y Y N Y

Y Y Y Y Y Y Y Y Y Y Submitter Comment: At Nogales Post Office during the 1st quarter of 2013, the

PM2.5 data were collected under non-FEM method with parameter code 88501; and during the rest of 2013 the PM2.5 data were collected under FEM method with parameter code 88101. The flow rate audit EPA Comment: QAPP Appr. Y Y Y Y Y Y Y Y Y Y Y S S S S S S S S S S S

# Data Evaluation and Concurrence Report for Particulate Matter

2013 Freeport McMoRan Miami, Inc. (1357) Certifying Year: Certifying Agency:PM10 Total 0-10um STP (81102) INTERMITTENT

Freeport McMoRan Miami, Inc. (1357) Parameter: PQAO Name: Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites# Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? 2 1 1 100 8.7610.02 Y 

### Monitors Summaries

Monitor Type Mean Min MaxExceed. CountOutlier Count % Complete Bias %

Complete Flow Rate Audit Collocation % Complete CV PQAO

Crit. Met Routine Data (ug/m3) Concurrence Flag AQS Rec Flag CA Rec

Flag EPA Eval. 04-007-0009
04-007-8000
04-007-8000 1

1

2 INDUSTRI

AL INDUSTRI AL INDUSTRI AL 12.76
16.70
17.35 2.0
2.0
2.0 51.0
55.0
54.0 0

0
0 0
0
0 96
100
95 AQS Site IDPOC +0.31
-0.31
-0.15 100

100
100 100 10.02 Y

Y
Y Y

Y
Y QAPP Appr. Y
Y
Y

## Data Concurrence and Evaluation Report for Lead 2013 Certification Year Arizona Department Of Environmental Quality (0053) Certifying Agency Name: Lead (TSP) LC (14129)

Lead PM10 LC FRM/FEM (85129)

Arizona Department Of Environmental Quality (0053)

Arizona Department Of Environmental Quality (0053) PQAO Name:

PQAO Name: Y

Y Criteria Met

Criteria Met +/-8.82

-6.68 Bias

Bias 100

100 Percent Complete

Percent Complete 24

24 Number Submitted

Number Submitted 24

24 Number Required

Number Required Y Criteria Met

Criteria Met Bias

Bias 0

0 Percent Complete

Percent Complete 0

0 Number of Audits Submitted

Number of Audits Submitted 1

1 Number of PEP Audits Required

Number of PEP Audits Required 0

0 Number of Methods Audited

Number of Methods Audited 1

1 Number of Methods

Number of Methods Y Criteria Met

Criteria Met 6.37

1.54 CV UB

CV UB 5.40

0.68 CV Est

CV Est 100

100 Percent Collocated

Percent Collocated 1

1 Number of Actual Colloc Sites

Number of Actual Colloc Sites 1

1 Number of Colloc Sites Required

Number of Colloc Sites Required 2

1 Number of Sites

Number of Sites Collocation Summary:

Collocation Summary: 01/22/2013

01/22/2013 Quality Assurance Project Plan Approval Date:

Quality Assurance Project Plan Approval Date: Analysis Audit Summary:

Analysis Audit Summary: PEP Summary

PEP Summary AQS Site-ID

AQS Site-ID POC

POC Monitor Type

Monitor Type Mean

Mean Min

Min Max

Max Exceed. Count

Exceed. Count Outlier

Count

Outlier Count Percent

Comp.

Percent Comp. Bias

Bias Percent

Comp.

Percent Comp. CV UB

CV UB Percent

Comp.

Percent Comp. PQAO

Crit. Met

PQAO Crit. Met PQAO

Crit. Met

PQAO Crit. Met Analysis

Crit. Met

Analysis Crit. Met AQS Rec. V

AQS Rec. VCA Rec Value

CA Rec Value EPA Eval.

EPA Eval. Monitors Recommended for Certification

Monitors Recommended for Certification Routine Data (ug/m^3)

Routine Data (ug/m^3) Flow Rate Audit

Flow Rate Audit Collocation

Collocation PEP

PEP Lead

Lead Certification

Certification 04-007-1002 04-007-1002 04-007-8000

04-013-9997 1

2 1

1 SLAMS SLAMS SLAMS

SLAMS 0.077

0.077 0.019

0.0033 0.001

0.001 0.001

0.0006 0.501

0.502 0.091

0.0109 0

0 0

0 0

0 0

0 100

96 100

100 +1.64

-0.29 -3.05

-2.12 100

100 100

100 6.37

1.54 100

13 Y Y Y Y

Y Y Y

Y Y

Y Y

Y Y

Y Y Y Y

Y S

S S

S QAPP Appr.

QAPP Appr. Y Y Y

Y