# Chemical Loading Chemical Loading PPM Doc owner: JLuman Doc author: JLuman Version: 0.01 Effective: 2009 - 07 - 15 Review by: yyyy - mm - dd Approvals: 

# DRAFT Safety Manager: _______________________ District Manager:_______________________ Talsico ® 

## Process Picture MapsTM & all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, & subjec t to licensing Agreement 

## Page 1 of 3



# Sub

- Process Bar 1 2 3 4 5 6 7 

# Reminders Overview Instructions & Explanations  Std Site Clothing and PPE Required Warning 

#  1 

#  Special note 1 Picture in following tables Additional person(s) required 

#  See tools & materials list 

#  Related COG s, documents, etc. 

#  Paperwork (Permits, JSA) 

#   Lock, Tag, and Try Breathing Apparatus
Dust Mask
Face Shield Safety Harness 

# 1 Prepare

2 Loading 

#  1.1 Engineer provides a job procedure with the required c hemicals. 

#  1 1.2 This information is reviewed by the facility manager to fill out the load sheet 

#  2 1.3 Facility manager informs loaders of job responsibilities with a J.S.A 

#  4 1.4 Loaders prepare a load sheet.  1 

#  3

2 

# 2.1 Daily inspection performed on the forklift 2.2 Chemicals are loaded on to the truck.  2 

#  2.3 F luid tech verifies chemicals and quantities recorded are correct in the load sheet before leaving the yard.  1 

# 2.4 Fluid tech will fill out chemical inventory report and turn in the yellow copy to dispatch before leaving the yard.  3 

#  5 2.5 2.6 Driver secures the chemicals with straps and transports them to th e location with the approp riate DOT shipping papers and MSDS sheets. 

#  6 Dispatch er will complete shipping papers for driver



# 2.7 Chem add operator is responsible for the safe transpo rtation of the chemicals. 

#  7 2.8 Fluid tech will drive behind the Chemadd.  4

3

4

5 

#  1 Prepare a load sheet

 2 Load the truck

 3 Prepare chemical inventory report

# Chemical Loading Chemical Loading PPM Talsico ® 

## Process Picture MapsTM & all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, & subjec t to licensing Agreement 

## Page 2 of 3 

# Hazards (JSA)

The hazards are any exposure to hazardous chemicals base d upon absorption, Ingestion or Inhalation. 

# We have the responsibility of preventing environmental contamination. 

#  Pre - Checks (before starting this procedure) 

#  The appropriate P.P.E (determined by MSDS) are available 

#  Forklift Inspected and approved for service 

#  Visual Inspection of all chemical containers for damage and use of caps and lid s on all containers 

#  Hazard labels on all hazardous materials in good and readable condition and current 

#  Employee must inspect all tools and equipment used in the p rocess. 

#  Tools & Materials Quantity & Description Step  Forklift & Pallets, 3 inch Straps, Poly and Steel Totes 

# 2.3  Non sparking rubber Pails, Hoses, Adaptor and Valves to transfer chemicals 

#  Gauge Sticks, Tape Measures, Small Hammers (non sparking rubber mallets or brass hammers) 

#  Drum and Totes, Wrenches for the caps and Lips. 

#  Chemical Totes. 

# <Step#>



# People (Who is required or needs to be notified) 

#  Engineer to write the procedure. 

#  Facility Manager to review the chemicals and designate the loading responsibilities. 

#  Chemical Loading loads the chemicals on the trucks 

#  Dispatcher to complete shipping papers 

#  Driver transports the chemicals to the work site. 

#  Fluid tech verifies all information and dispenses the chemicals. 

#  Quality Checks  The employees are educated on the chemicals and their particular hazards. 

#  A MSDS notebook readily available 

#  All personnel involved in this procedure must have completed training by a competent person prior to performing task 

#  Information Details Step 

#  1 The actual procedure list with all chemicals and amounts

. 1.1  2 Chemical order form that compares the required quantity of each chemic al to the current inventory. 1.2 

#  3 Load sheet that determine the chemicals and their quantities for each Job 2. 1  4 **•** MSDS **•** Proper PPE **•** 

# Forklift safety **•** 

# Emergency procedures  5 Chemical Inventory Report is used to describe what chemicals and chemical levels leave the yard and come back to the yard 2.6  6 Shipping Paper for the transportation obtained from dispatcher 3.1  7 MSDS for each chemical 3.2 

#  1 Check and verify all chemical levels



#  2 Measure chemical levels

# Chemical Loading Chemical Loading PPM Talsico ® 

## Process Picture MapsTM & all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, & subjec t to licensing Agreement 

## Page 3 of 3 Talsico® 

## Proc ess Picture MapsTM and all associated intellectual property are owned by Talsico International, ABN 20 419 167 619, and subjec t to licensing agreement. Duplication or use of this methodology or format is prohibited without the written permission of Talsico. www.talsico.com

# Safety 

# Data Sheet
LPA Pmteethe lathing 

## DOT



## Section 

# Product Identification 

# and Uses
Corn mouflrade name 

# ProSURF cut Not applicable Synonyms Not available 

### rsct 

## TS 

# 8b vi 

### vent 

## ry Al components are listed Chemkid name Not applicable Chemical formula Not applicable 

# CAS Mixture 4a.UN ian PGH Chemical farntly Allpttatlc alcohol 

### Solvent Supplier .1oIccular weight Not applicable 

# nan Manufacturer Chemplex L.C rnnalS7aes 

### P.O Box 1071 Material uses Not available 506 

## CR 137 Snyder Tx 79550 

## 915 573-7298


## Section 

# IA First 

# Aid 

# Measures Eye contact 

### Check for and remove any contact lenses Immediately flush eyes with running water for at least 15 mInutes keeping eyelids 

### open Cold water 

### may be 

### used Do not use an eye ointment Seek medical attention

Skin contact After contact with skin 

### wash immediately with plenty of 

### water Gently 

### and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be particularly careful to clean folds crevices creases and groin Cold water 

### may be 

### used Cover the irritated skin with an emollient If irntatlon persists seek medical attention 

### Wash contaminated clothing before reusing Hazardous skin 

## Wash with disinfectant soap and cover the contaminated skin with an anti-bacterial 

### cream Seek contact medical attention
Slight inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention

hazardous Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie belt or Inhalation waistband It breathing is difficult administer 

### oxygen If the victim is not breathing perform mouth-to-mouth resuscitation Seek medical attention

Slight ingestion 

### Do not induce vomiting Loosen tight dothing such as collar tie belt or waistband If the victim is not breathing perform mouth-to-mouth resuscitation Seek immediate medical attention

Ila.ardous ingestion Not available



## KEY-H EC-1 -001300

# ane Veigbt 

### TLV/PEL LCM/LDo Isopropyl alcohol 67-630 85-95 Not available 

## ORAL 

# LD5O Acute 3600 mg/kg 

## VAPOR 

# LC5O Acute 16970 

### ppm hours Rat.J



## Section III 

# Physical Data Phydcal state and Liquid Odor Rubbing alcohol appearance 

### II 

# 1% olnIwater Near Neutral Taste Not available Odor threshold Not avaUable Color Pale yellow
VoIatilit% Not available Melting point 

### May start to solidify at -89.5C 

### -129.1F based on data for Isopropyl alcohol Roiling jnint 

## 84C 

# 184F
Specific gravity 0.80 VVater Vapor density 

### The highest known value is 2.08 Air Isopropyl alcohol Vapor pressure The highest known value is 33 

# mm of 

### Hg 

# 20C Isopropyl alcohol Evaporation rate Not available Viscosity Not available LugK. The product is more soluble in water onicjl% jurracc acIi%I Nonionic
Critical ternperIture Not available Instability temperature Not available onditious of instability Not available

lispersion properties See solubility in water methanol diethyl ether n-octanol

Soluhility Easily soluble in cold water hot water methanol diethyl ether Partially soluble in n-octanol



## KEY-H EC-1 -001301ge 3/5 The product is Flammable
Aisto-iinition cniperattire The lowest known value is 398.89CC 

# 750F Isopropyl alcohol
Fire degradation These products are carbon oxides 

# CO C02 products Flash points 

## CLOSED 

# CUP 12.C 

# 54F
Flammable limits The greatest known ratge is 

# LOWER 2% UPPER 12% Isopropyl alcohol

Fire elinguishing Flammable liquid soluble or dispersed in water procedures 

### SMALL FIRE Use 

## DRY chemical powder 

## LARGE FIRE Use alcohol 

### foam water spray or fog

Flaznntatiiiilv Highly flammable in presence of open flames and sparks of heat of oxidizing materials Flammable in presence of combustible materials

Remark Vapor 

### may travel considerable distance to source of ignition and flash 

### back 

## When heated to decomposition it emits acrid 

### smoke and 

### fumes lscpropyl alcohol Risks of explosion Risks of explosion of the product in presence of mechanical impact Not available Risks of explosion of the product in presence of static discharge Not available

Remark Not available


# Section Reactivity 

# Data Stability The product is stable Iiirdnm kornp Not available prmidurt legratlahility Not available

lrodmicts Possibly hazardous short term degradation products are not lely However long term degradation products may arise degradation The product itself and its products of degradation are not toxic Remark Not available
orrosiYity Non-corrosive in presence of glass

Reniaik Not available 

# liil Reactive with oxidizing agents acids Slightly reactive to reactive with moisture

Remark Incompatible with halogens and aluminium lsopropyl alcohol



## KEY-H EC-1 -001302

# Section 

# VI Toxicological Properties -II 

# page9 Routes of entry Dermal contact Eye contact Inhalation Ingestion 

# uN Not available
iokity for atiunab 

# WARNING THE LC5O 

## VALUES HEREUNDER ARE ESTIMATED ON THE BASIS 

## OF 4-HOUR 

## EXPOSURE Acute oral toxicity 

# 1D50 3600 mg/kg Isopropyl alcohol Acute toxicity of the vapor 

# LC5O 16970 

### ppm hours Isopropyl alcohol Remark Not available

Clirtnic efltcts on 

## DEVELOPMENTAL TOXICITY 

## PROVEN alcohol humans The substance is toxic to the reproductive system
Remark 0900 Detected in maternal milk in humain

lsopropyl alcohol 

### Mute effcct on Very hazardous in case of ingestion humans Hazardous in case of skin contact irritant sensitizer permeator of inhalation

Remark Exposure can cause 

### nausea headache and vomiting Isopropyl alcohol 

# Section Vii Preventive 

# Measures Waste disposal Whatever cannot be saved for recovery or recycling should be 

### managed in an approriate and approved waste disposal facility Processing use or contamination of this product 

### may change the waste management options State and local disposal regulations 

### may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements

Not available

Storage Flammable materials should be stored in separate safety storage cabinet or 

### room Keep away from heat Keep away from sources of ignition Keep container tightly closed Keep in cool well-ventilated place Ground all equipment containing material refrigerated room would be preferable for materials with flash point lower than 

### 37.8C 

# 100F
Piccatitions Keep away from heat Keep away from sources of ignition Ground all equipment containing material 

### Do not ingest 

### Do riot breathe gas/fumes vapour/spray 

### Wear suitable protective clothing In case of insufficient ventilation wear suitable respiratory equipment If ingested seek medical advice immediately and show the container or the label Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents acids Small spill and leak Dilute with water and 

### mop up or absorb with an inert dry material and place in an appropriate waste disposal container Large spill and leak Flammable liquid Keep away from heat Keep away from sources of ignition Stop leak if without risk Absorb with 

## DRY earth sand or other non-combustible material Do not touch spilled material Prevent entry into sewers basements or confined areas dike if needed Eliminate all ignition sources

Itoltclit Clothing Splash goggles Full suit Vapor respirator Boots Gloves self contained breathmg apparatus should be usedt avoid inhalation of the product Suggested protective clothing might not be sufficient Consult specialist 

### BEFORE handling this product



## KEY-H EC-1 -001303

## Section 

# IX Protective Clothing Splash goggles Lab coat Vapor respirator Be sure to use an approved/certified respiratoror equivalent Gloves



# Section 

# Other In 

# formation Reterences Not available

Validated by ChempleN on 10/3112001 

### Verifled by Cheinpiex Printed l/2/20tb0 

# Emergency Response 

# 800 633-8253

he

.. ia 

# kJ .h. isiruii iM.sI 

# kq js 1l...s. 

## hrpb ....d it s.bMiks ii.h1Ir ..A...r j.r 1S.r .rnr OH.P4.f tl 

## dii kr.ü 

## tt frs iIii- ..i .usr is qk ..4 ny....siiO 4i1. ss lit i.ls sr Io rsis F..IJi u..I ...t ..MsSIsU ISssUsk res1m .n 4sssJh.. tss 11 th.s...n Dl.. ...Ir ..nts th..g .ii IProSURF-Il page5/ 

## Section_VIII._Classification DOT Class Flammable liquid

Shipping name Flammable liquids n.c.s Isopropyl alcohol 

### UNNA UN1993 

## PG II
ReiuaI1 Not available Maritime Not available transportation
Remark Not available

IICS Class Flammable liquid having flash point lower than 

### 37.8C 

# 100F Class Sensitizing substance Class Target organ effects Remark Not available
FPA F1.AIdIMABILflV


### HEALTH 

## _SPCFIC HAZARD
Federal and State Regulations



## KEY-H EC-1 -001304

# J5uF_ Safety 

# Data Sheet NPA DOT



## Section 

# Product Identification 

# and Uses Common/Trnijc annie 

# PrOSURF-I apiicale Sauonvrns Notavailable 

### iSCA 

# T$CA 

# 8b inventoryAU components are listed .heinu.a1 name Not applicable Cbemwat furniula Not applicable 

# cs Mixture 

## s3 PG

hemical fnni.Jv Aromatic hydrocarbon 

### Solvent Dl Supplier loIecular weight Not applicable 7DlO 4MaflUr3Ctuier Chemplex 

## LC 

# P0 Box 1071 

## IatnJ Oil-Soluble Surfactarit 506 

### CR 137 Snyder Tx 79550 

## 915 573-7298 

## Section 

# IA First 

# Aid Measures Eye contact Check for and remove any contact lenses Immediately flush eyes with running water for at least 15 minutes keeping eyelids 

### open Cold water 

### may be 

### used Do not use an eye ointment Seek medical attention
Skin contact After contact with skin 

### wash immediately with plenty of water Gently and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be panicularly careful to clean folds crevices creases and groin Cover the irritated skin with an emollient It irritation persists seek medical attention 

### Wash contaminated clothing before reusing Hazardous skin 

### Wash with disinfectant soap and cover the contaminated skin with an anti-bacterial 

### cream Seek contact medical attention
Slight inhalation Allow the victim to rest in well ventilated area Seek Immediate medical attention hazardous Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie bolt or inhalation waistband If breathing is difficult administer 

### oxygen If the victim is not breathing perform mouth-to-mouth resuscitation Seek medical attention

Slight Ingestion 

### Do not induce vomiting Loosen tight clothing such as collar tie belt or waistband If the victim is not breathing perform mouth-to-mouth resuscitation Seek immediate medical attention

hazardous ingestion Not available



## KEY-H EC-1 -001295

# Section II 

# Hazardous Ingredients JPrOSLIRFI page 2/5


### same 

## s.j 

# Whi TIN/PEL 

## LCFJLD

Petroleum distdate 

### 6742975 5-15 

# TWA CElL mg/rn3 

## ORAL 

# LD5O Acute 1530 mg/kg 

## Rae DERMAL 

# 1050 Acute 2740 mg/kg tRabbit Toluerie 108-88-3 70-90% 

# TWA 100 

# ppm ORAL 

# 1050 Acute 2600 mg/kg 

## DERMAL 

# 1D50 Acute 12210 mg/kg 

## VAPOR 

# LCSO Acute 8000 

### ppm hours Amidoamine mixture 5-15% Not Available Not available



# Section lii 

# Physical Data Physical state and Liquid appearance p11 

# 1% sot n/water 

## 57 Taste Not available Odor threshold The highest known value is 0.6 ppm Trimeffiylbenzene COlor Clear 

### Brown
Volatility Not ava1abIe Melting point 

## -20F Boiling point The lowest known value is 110.6C 231.1 Toluerie Speciticgrtwity 88 

# Water Vapor density The highest known value is 4.14 Air Trimethylbenzene Weighted average 3.34 LAir Vapor pressure The highest known value is 

### 21.9mm of 

### Hg 

# 20C Toluene Evaporation rate Not available Viscosity Not available IdogK. The product is more soluble in oil loicitv urracc aeth agent Not available
Critical temperature Not available Instability temperature Not available nntIitions of iIIstalilits Not available

lispcrsiun ProPerties See solubdity in water methanol diethyl ether n-oclanol

Soluliitity Easily soluble in methanol diethyl ether Soluble in n-octanol Very slightly soluble in cold water hot water



## KEY-H EC-1 -001296

# Section 

# IV Fire 

# and Explosion 

# Data 1PrOURI.I Pae3I9 The poduct Is Flammable nIo-ignition mpcrature The lowest known value is 

## 480C 

# 896F Toluene
Fire degradation These products are carbon oxides 

# CO C02 products Flash points Closed 

### cup 43SF
Flammable limits The greatest known range is 

# LOWER 1.2% 

## UPPER 7.1% 

### Toluene

Fire ethnguistiing Flammable liquid soluble or dispersed in water procedures 

### SMALL FIRE Use 

## DRY chemical powder 

### LARGE FIRE Use alcohol 

### foam water spray or fog

FtainmaliIit Flammable in presence of open flames and sparks Slightly flammable to flammable in presence of heat of oxidizing materials of combustible materials Non-flammable in presence of moisture

Remark Vapor 

### may travel considerable distance to source of ignition and flash 

### back Toluene

Risks of esJIos ion Risks of explosion of the product in presence of mechanical impact Not available Risks of explosion of the product in presence of static discharge Not available

Remark Not available


# Section Reactivity 

# Data Stability The product is stable
JIazr4uus deromp NOt available products Hegradability Not available
Prmlucts POssd3ly hazardous short term degradation products are not hkely However tong temi degradation products may arise degradation The product itself and its products of degradation are not toxic Remark Not available
orrosivity Non-corrosive in presence of glass

Remark Not available

Reactivity Reactive with oxidizing agents Slightly reactive to reactive with reducing agents acids alkalis Non-reactive with moisture Remark Not available



## KEY-H EC-1 -001297Routes of eniry Dermal contact Eye contact Inhalation Ingestion 

### ILV
iicity for anirnjls 

## WARNING THE LCSO 

### VALUES HEREUNDER ARE ESTIMATED 

## ON THE BASIS 

### OF 

## 4HOUR EXPOSURE Acute oral toxicity 

## LD5O 2600 mg/kg Rat. Toluene Acute demiat toxicity 

## LD5O 12210 mg/kg IRabbit. Toluene Acute toxicity of the vapor 

## LC5O 8000 

### ppm4 hours 

### Toluene
Iteniark lJot available

lironic effects on The substance is toxic to blood kidneys the nervous system liver hunuuis
Remark Inhalation of vapors may cause dizziness an irregular heartbeat narcosis nausea or asphyxiation Toluene
Acute effects on Hazardous in case of skin contact irritant permeator of ingestion of inhalation itunians

Reris rk Exposure can cause lung irritation chest pain and 

### oedema which 

### may be fatal 

### Toluene


## Section VII 

# Preventive 

# Measures Waste disposal Whatever cannot be saved for recovery or recycling should be 

### managed in an approriate and approved waste disposal facility Processing use or contamination of this product 

### may change the waste management options State and local disposal regulations 

### may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements

Not available

Storage Flammable materials should be stored in separate safety storage cabinet or 

### room Keep away from heat Keep away from sources of ignition Keep container tightly closed Keep in cool well-ventilated place Ground alt equipment containing material refrigerated room would be preferable for materials with flash point lower than 

### 37.8C 

# 100F Precautions Keep away from heat Keep away from sources of ignition Ground all equipment containing material 

### Do not ingest 

### Do not breathe gas/fumes vapour/spray 

### Wear suitable protective clothing In case of insufficient ventilation wear suitable respiratory equipment If ingested seek medical advice immediately and show the container or the label Avoid contact with skin and eyes 

### Keep away from incompatibles such as oxidizing agents organic materials Siiall spill and leak Absorb with an inert material and put the spilled material in an appropriate waste disposal

1.arge spill and leak Flammable liquid Keep away from heat Keep away from sources of ignition Stop leak if without risk Absorb with 

## DRY earth sand or other non-combustible material 

### Do not touch spilled material Prevent entry into sewers basements or confined areas dike if needed Eliminate all ignition sources Be careful that the product
is not present at concentration level above 

### TLV Check 

### TLV on the 

## MSDS and with local authorities

Protect ie lathing Splash goggles Full suit Vapor respirator Boots Gloves self contained breathing apparatus should be used tc avoid inhalation of the product Suggested protective clothing might not be sufficient consult specialist 

### BEFORE handing this product



## KEY-H EC-1 -001298

# Section Viii 

## Classification ProSLJ lW-I page_5/9 

## DOT

Maritime ra.isportntion Class Flammable liquid

Shipping name Flammable liquids n.o.s contains Toluene 

### UNHA UN1993 

## PG II Remark Not available Not available

Remark Not available


### HCS Class Flammable liquid having flash point lower than 

### 37.8C 

# 100F Class Target organ effects

Remark Not available 

# \fp FLAMMABILITY
HEALTH ACTIVELY
SPECIFIC 

### HAZARD Federal .Ifll 

# RQ 14lgallons toluene State Regulations



# Section 

# IX Protective Clothing Splash goggles Lab coat Vapor respirator 

### Be sure to use an approved/certified respirator or equivalent Gloves



# M_

Section 

# Other Information Relerenees Not available



# Emergency Response 

# 915 570-4899
il osr Asws.1. th h.r.siwn th..4 knit 1j.n..nn .N.sk .Is 5.t.9 iifl.lJ..r Jj www.wi.fr thi wiwnrr ii 1k il.rsshw ii .in4i-o FjwI frtmJdntn ..f siiE$siik .q its .ugsiM is 1k swfr nwssikilft Ike inn ii musvw.is nsuj Iw.Aw.. kesnis .srni wtIJ s.M IfrmwssI rew .n .iM4MACtiiff ii 

### 4wn tlfNrHffethtfkni wa thg our lwc.rf IbM rust Validated by 

### Chemple on 11/6/2000 Verified by Chemples Printed 11/6/2000



## KEY-H EC-1 -001299

# MATERIALSAFETYDATA SHEET

SECTION 1- 

# PRODUCT mENTIUER

Product S-4 

## NFPA Raiir Energy Cbemicals II 

### Ltd Health 

### 2709 Industrial 

## Ave Fire 

### Midland Texas 79701 

### React 

# 915 686-7847 Special 

## 0Leasc to Extreme 

## HMIS 

## PERSONAL PROT SECTION -JLAZ.4RDOUS 

## INGREDIENTS Hazardous 

### Components-CAS 

## Number Exposure Limits


### Not hazardous as defined in 

### 29CFR1910.1200 

## SECTION 3- 

## PJJYSICALCHEMICAL CHARACTERISTICS Boiling Point 

### Approx 

## 215 Melting Point 

# NA
Specific Gravity 

# H201 1.005- 1.0 10 

### Vapor Pressure 

# NA Vapor Density 

# Airl NA Evaporation Rate 

# BuAccl 

# NA Density 

# 1gal NA pH 6.5 8.0 Solubility in 

### Water Soluble Appearance and 

## Odor Tan/brown sobition bland 

### odor Freeze Point 

# NA Dry Point 

# NA Danger Physical 

### Hazards 

# NA

Generic 

## Name 

# NA UNINA Number 

# NA

North American Emergency Response Guide 

## Number 

# NA DOT Proper Shipping 

## Name 

# NA DOT Hazard Class 

# NA DOT Packing 

### Group 

# NA DOT/CERCLA 

# RQ NA SECTION 4- 

## FIRE 

## AND EXPLOSION 

# HAZARD DATA Flash Point 

## method None Flammable Limits 

### Lower Upper Extinguishing 

### Media Dry powder carbon dioxide 

# co2 water fog or spray alcohol 

### foam 

## SPECIAL FIRE 

## FIGHTiNG 

## PROCEDURES Approach fire 

### from upwind side Avoid breathing 

## smoke fumes mist vapors 

### on tho downside 

## wind Firefighters 

### wear protective clothing and self contained breathing apparatus 

## UNUSUAL FIRE 

# AND EXPLOSION 

# HAZARDS

KEY-H EC-1 -001331Firefighters protective clothing and self contained breathing apparatus 

# T1ON -REACTIViTY 

## INFORMATION

Product is stable 

# hompaty None

Materials to avoid Oxidizers
Hazardous Deconçosition or By-products 

### From combustion 

## smoke carbon 

### monoxide carbon dioxide

Hazardous Polymerization 

### Not expected to occur 

# SECHON HEALTH HAZARD DATA ROUTES OF 

# ENTRY Inhalation Possible-irritant 

### Eye Contact 

### Priury Route 

### Eye irritation
Skin absorption 

## No data
Skin Irritation Primary Route 

## May cause irritation Ingestion Possible-irritant 

## HEALTH HAZARDS Acute and 

### chronic Acute Health Effects 

### Short 

## Term Mild eye irritant at point of contact Mild skin irritant at point of contact Chronic Health Eflbcts 

### None Established 

## CARCINOGENICITY LISTED IN 

# NTP NO IARX 

# MONOGRAPHS NO OSHA 

# REGULATED NO SIGNS 

# AND SYMPTOMS OF EXPOSURE Skin irritation develops slowly after contact 

### Eye irritation Develops immediate 

## MEDICAL CONDITIONS 

## GENERALLY AGGRAVATED 

# BY EXPOSURE Pre-existing skin disorders



## KEY-H EC-1 -001332

## S-4 

# EMERGENCY AND FIRST 

## AID 

## PROCEDURES 1nh.Ltn 

## Renve victim to fresh air 

### and If 

### needed immediately begin artificial respiration Give oxygen if breathing Is labored Get emergency medical help Contact physician inanediately 

### Eye Contact Flush eyes with water 15 minutes 

### Jet medical attention if 

### symptoms develop and persist
Skin Contact Immediately remove 

### contamhted clothing 

### Wash skin thoroughly with mild soap and 

### water Flush with hike 

## warm water for 15 minutes or until all traces are have been 

### removed Seek medical attention if 

### symptoms develop and persist
Ingestion Include vomiting if victim is conscious by giving water then stick fingers 

### down throat 

### Never give unconscious person anything by 

### mouth 

## OTHER HEALTH WARNINGS 

# NA SECTION 7- 

## PRECAUTIONS FOR SAFE HANDLING 

# AND USE SPILL 

# OR LEAK PROCEDURES Emergency response coordinator 

### must have nntlated training Elimintiig an ignition sources 

# SMALL SPILLS Pick 

### up with absorbent materials and place in non-leaking containers seal tightly for proper disposal or reuse 

# LARGE SPILLS Evacuate the hazard area 

### of unprotected personnel 

### Wear appropriate respirator and protective clothing Shut off source of leak if sale to 

### do so Dike and contain 

### Remove with 

### vacuum trucks or 

## pump storage/salvage vessels 

## WASTE DISPOSAL 

# METHOD NA PRECAUTIONS 

## TO BE 

## TAKEN IN 

## HANDLING 

# AND STORAGE No Special 

## OTHER PRECAUTIONS Clean 

### up leaks/spills immediately to prevent soil or water contamination 

## SECTION 8- 

# CONTROL MEASURES Ventilation Local Exhaust 

### Recommended Special 

### Not necessary Mechanical Reconineixied Other 

### Not necessary Respiratory Protection 

### Not Normally needed

Protective 

### Gloves Chemical 

### Type Eye Protection 

### Eye protection including both chemical splash goggles and face shield Skin Protection 

### Boots apron drench 

### shower eye 

### wash as needed for protection against spills and/or splashes
Other Hygienic Practices Avoid contact with skin eyes and clothing After handling this product 

### wash bands before



## KEY-H EC-1 -001333

## S-4 eafin driniig or 

### smoking if contact occurs 

### remove contsinihted clothing 

### eded take frst aid action 

### shown in section Launder contanirted clothing before reuse
Other 

## Work Practices 

### Emergency eye 

### wash 

## fbuntn and safety showers should be available in the immediate vicinity 

### of any potential 

### expoane Promptly 

### remove soiled clothing and 

### wash thoroughly before reuse


## SECTION 9- 

# ThANSPRTA11ON INFORMATiON 

# NOT REGULATED SECTION ie- 

# REGULATORYENVIRONMENTAL EPA 

# HAZARDS ACUTE- Yes 

## CHRONIC-NO FLAMMABILITY-NO 

## SUDDEN RELEASE OF PRESSURE-No REACTIVE-No 

## SARA Title Section 

## 313 Toxic Materials Chemical 

## Name CAS Percentage


## CLEAN AIR 

# ACT No CLEAN 

# WATER 

# ACT No STATES LISTS None 

## TOXIC 

## SUBSTANCES CONTROL ACT 

# FSCA 40 

## CFR 710 Sources 

### of the 

### raw materials used in
this mixture assure that all chemical ingredients present are in compliance with Sect 

# 8b Chemical Substance Inventory or are otherwise in compliance with 

## TSCA FOOTNOTES NA-Not applicable 

### ND-Data not available 

### CS- Cancer Suspect Agent OX-Oxidizer Cor-Corrosive CALC-Calculated EST-Estimated 

### STEL-Short Time Exposure Limit TLV-Threshold Limit Value PEL-Permissible Exposure Limit 

## TWA-Tune Weighted 

### Average hours 

# HNMIS PPI-Hazardous Material identification 

### System Personal Protection Index 

### The data presented is true and correct to the best of our knowledge and belicf 

### however neither seller nor
prepare 

### makes any warranties express or implied concerning the inlbnnation presented 

### The user is cautioned to perform his 

## own hazard evaluation and to rely 

### upon his 

## own determinations



### SCIENI1FIC 

## INFORMATION SERVICES Telephone 

# 817 560-4613 

### Form essentially the 

### same as 

## OSHA

Form 174 data September 1985

Preparation date July 1991



## KEY-H EC-1 -001334

### eCUfl Cluthiug 

# 7TU Ml 

# 5- Material Safety_Data Sheet
DOT



## Section 

## Product identification 

# and Uses
Coinmonfrade 

## S-5 

# AES cl Not apphcIe
Synonyms Not avathla TSCA products listed

Chemical name Not pliceble

.-.. .- iicmical formula Not plmcable Code 

# ooI_ Chesmcal family Aliphetic ether Solvent
Supplier CtemPIeX Molecular 

# wet Not appOcable P.O 8c4c 1071 

# sr Tx 79550 Manufacturer Chençlex 

## LC P.O BoxlO7l
Material uses Not available Snyder TX 79550 

## 915 573-1296



## Section L4 First 

## Aid Measures Eye contact Check for and remove any cormbct lenses IMMEDIATELY flush eyes with running water for at least 15 minutes keeping eyelids open 

## COW water may be used 

### DO NOT use an eye o.rdment Seek medical attention

Side contact If the chemical got onto the clothed portion of the body remove the contaminated clothes as quicldy as possible protecting your own hands and body Place the victim under deluge shower If the chemical touches the vicbms exposed skin such as the hancte Gently and thoroughly wash the contaminated skin wilti rwmrmg water and non-abrasive
soap Be purticulmly 

# cul to clean folds crevices creases and groin 

## COW water may be used Cover the iiitated
skin with an emollient If irriton persists seek medical attention Wash contaminated clothing before reusing
Hazardous skin contact Wash with disinfectant soap and cover the contaminated skin with an anti-bactmial cream Seek irrwnecliate medical
attention

Sliplt inhalation Allow the victim to rest in wall ventilated area Seek immediate medical attenitort

Hazardous imhalabon No additional information

Slimt initeslion 

### DO NOT induce vomiting Have conscious person drink several gasses of water or milk Seek immediate medical
attention

Hazardous ingestion 

### DO NOT induce vomiting Exarmne the lips and mouth to ascertain whether the tissues are damaged possible
indication that the todc material was ingested the absence of such signs however is not cnckmive Loosen tight clothing such as collar tie belt or waistand If the victim is not breathumg perform mouth-b-mouth resuscitation Seek immediate medical attention



## KEY-H EC-1 -00133514amc 

## CAS byWciit 

### TLWPEL C5J11n
Ethyler glycol monobutyl ether 111-76-2 Wade secret Plot available 

### ORAL 1050 mglkg Acute 470 

## Ret DERMALLD5O mglkg Acute Rabbit



### Section III 

### Physical 

## Data Physical state Odor Sweet appealmiCt pH 

## 1% solo/waler Neutal 

# l5k Notavailable
Odor threshold Not available C01W Colotless

Volatility Not available Melting point
liloling paint 

## 220F
Spccific gravIty 1.03 Water Vapor density The highest 

# knn yalta is 4.1 

## Ar Ethylene glycol inonobutyl ether Vapor pressiwe Not available
Evaporation late Not available Vucosiy Not available logIL The product is much more sok4ble water

lonicity snrlace ucttve agent Anionic
Critical temperature Plot available

Instability temperature Not available
Conditions of Instability No additional remark

Dispersion properties See sdubikty in water methanol dieth1 ether

Solubility Easily soluble in cold water hot water methanol Partially soluble in cliethyl ether Very slightly soluble in n-octenol



## KEY-H EC-1 -001336

## Section Fire 

# and Expi ion Data page 3/5k The product is Combustible
Auto-ignition temperature The lowest known value is 

### 24445C 

# 47F Ethylene glycci rnonobutyl ether
Fire dcgradatini products These products are carbon oxides 

# CO C02

lilusis polilts 

## 200F

Flammable links 

## Th puatost known range is 

## LOWER 1.1% 

### UPPER 10.6% Ethylene glycol monobutl ether

Fire eEingnisbisg SMALL FIRE Use 

### DRY chemicals 

### C02 waler spray or foam procedures LARGE FIRE Use water sqxsy fog or foam 

### DO NOT use water jet

Fianunubfflty Slightiy flammable to flammable in presence of open flames and sparks of heat

Remark 

### When heated to decomposibon it emits acnd smoke and inite fijoas Ethylene glycol monobutyl ether

Riska otexpkjsion Risks of explosion of the product in presence of mechanical knpact Not available Risks of explosion of 

### th product in presence of static discharge Not available No specific information is available in our database regarding the produces risks of explosion in the presence of various materials Remark No additional remark



## Section Reactivity 

## Data

Stability The product is stable
Hazardous decooip products Not available
Degradabllity Not available

Products of dcgrada 1km Possibly hazardous short term dogradabon products are not hkely However long term degradation products may aria. The products of degradation are less toxic than the product itself Remark No additional remark

Corrosivity Non-corrosive in presence of glass

Remark No adddonal remark

Reacthity Slitiy reactive to reactive with oxidizing ogents

Remark No adddonal remark



## KEY-H EC-1 -001337

# ___________________ page 4/S 

## Section Vi Toxkglogical Properties
Routes of entry Eye contact Ingestion Skin contact Inhalation LV Not available

Toxicity for au1sal Acute oral toxicity 

## 1050 4700 mglkg 

## Rat CaIcud value for the mixture Acute dermat toxicity 

## LD5O 2200 mglkg 

### Ralft Calculated value for the mixture

Remark No additiorul remark


### iroic elTccts on Toxicity of the product to the reproductive system Not available humans

Remark No additional remark

Acute effects on humans Very daigercus in case of ingestion Shghtty dangerous to dangerous in case of skin contact irritant peimeator of eye contact irritant of inhalation

Remark Exposure can cause nausea headache and vomiting Ethylene glycol monobutyl ether



### Section VII 

### Preventive 

## Measures
Waste disposal Whatever cannot be saved for recovery or recycling should be managed 

### man approriats and approved waste disposal
facility Processing use or contamination of this product may change the waste management 

### cions Stat aid local disposal regulations may differ from federal disposal regulations Dispose of container and .mused contents in accordance with federal state and local recpirernerds

Storage Keep container cky Keep in cool place Ground aN equçment containing material Keep container lightly dosed Keep

in cool wall-ventilated place Highly toxic or infectious materials stould be stored in separate lucked safety storage cabinetor room

Precautions Keep locked 

### up Keep away from heat Keep away from sources of ignition Empty containers pose fire nsk
evaporate the residue under fume hood Ground all equjiment containing material 

### DO NOT ingest Do not breathe gas fumes vapor or spray In case of insufficient ventilation weer suitable respiratory equjimant If ingested seek medical advice immediately aid show the container or the label Avoid contact with sldn and eyes Keep away from incompattles such as oxidizing agents

Small spill and leak Dilute with water and mop up or absorb with an lied 

### DRY material end place in an appropriate waste disposal container Finish cleaning by spreadeng water on the contaminated surface and dispose of according to local aid regional mihority requrements Large api11 and leak Combustible material Poisonous liquid Keep away from heat Keep away from souitesof ignition Stop leak without risk 

### DO NOT get water inside container 

### DO NOT touch spilled material Use water spray to reduce vapors Prevent entry into 

### sewev hasements or confined
areas dike If need.d Elininate eli sources of ignition Call for assistance on disposal Fish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system

Protective jotting Splash goggles Fuli sat Vapor respirator Bouts GirNeS self contained breathing apparatus should be used to avoid

inhalation of the product Suggested protective clothing migt not be sufliclent consult speciol BEFORE handling this



## KEY-H EC-1 -001338

## SOctlon 

# WI Classification DOT Not 

### DOT Controlled material Lkiited States

Not applicable PIN and 

# PG Reaark Not availalle Mari$iinv transportation
Remark Not appcable

tICS 

### HCS CLASS lnitabng 

## sstace HCS CLASS Contuslible Iiqtid havTng flash point between 

## 378C 100F and 93.3C 

## 200F

Reusark No adcbtional renark
NFIA R.MMAaII.rry 

# 01 CTMTY 

# ECARD

Federal and State ReguIatium



### Section 

## IX Protective Clothing Splash goggles Lab coat Vapor respirator Be sure to use MSHAJNIOSH approved respirator or equivalent Gloves impervious Wear approprIate reapa-ator when ventilation is inadequate



## Section X. 

## Other InfoAnatioæ
References Not avaiIle

Vabdated by Oieuspkx 

## LC on 3/5/99 Verted esiplri 

# LC

Printed 315/99 

# Emergency Response 

# 915 570-4899 

# JL_L ffi. JJ..L .n..ftr 

## dJJ__L .u itwon

KEY-H EC-1 -001339

# Versa prop ® 1. Chemical Name & Company Identification PRODUCT NAME: Versaprop® (all mesh sizes) SYNONYM(S): Ceramic Proppant CHEMICAL FAMILY: Aluminosilicate MANUFACTURER: Saint-Gobain Proppants 5300 Gerber Road Fort Smith, Arkansas 72904 24-Hour Emergency (479) 782-2001 

# 2. Component Information CHEMICAL NAME COMMON NAME % BY WEIGHT (TYPICAL) Aluminum Silicate Mullite 35-65 Aluminum Oxide Corundum 35-65 

# 3. Hazards Identification 3.1 Emergency Overview HMIS RATING Health: 1. (Slight) Flammability: 0. (Minimal) Reactivity: 0. (Minimal) Chronic: 1. (Slight) 3.2 Potential Health Effects INHALATION: Prolonged exposure to dusts may cause respiratory tract irritation. INGESTION: No known adverse effects. EYE CONTACT: May cause irritation on prolonged or repeated contact. SKIN CONTACT: May cause irritation on prolonged or repeated contact. 

# 4.0 First Aid Measures INGESTION: Seek medical attention if large quantities are ingested. INHALATION: Remove to fresh air. EYE CONTACT: Immediately flush eyes with large quantities of water. Call a physician if irritation persists. 

# 5.0 Fire Fighting Measures FLASH POINT: Nonflammable LOWER EXPLOSION LIMIT: Not applicable UPPER EXPLOSION LIMIT: Not applicable AUTOIGNITION TEMPERATURE: Not applicable Use extinguishing agent suitable for type of surrounding fire. 

# 6.0 Accidental Release Measures SPILLS: No special procedures are required for cleanup of spills or leaks. Spherical shape of spilled pellets can create a slip hazard. 

# 7.0 Handling and Storage Store under dry conditions. Handle with adequate ventilation. Use a NIOSH/MSHA approved respirator if dust is present. 

# Material Safety Data Sheet FOR INDUSTRIAL USE ONLY

# 8.0 Exposure Control/Personal Protection 8.1 Exposure Control Minimize creation of dust. 8.2 Personal Protection Use NIOSH/MSHA approved respiratory protective equipment when airborne concentrations exceed acceptable criteria. Wear safety glasses at all times to prevent eye irritation. 8.3 Exposure Guidelines INGREDIENT CAS# %/ OSHA ACGIH-TWA TLV WT PEL/TWA Corundum 1302-44-56 35-65 15mg/m 3 

## (Total) 10mg/m 3 

## (Total) 5mg/m 3 

## (Resp) 3mg/m 3 

## (Resp) Aluminum Silicate 1302-76-7 35-65 15mg/m 3 

## (Total) 10mg/m 3 

## (Total) 5mg/m 3 

## (Resp) 3mg/m 3 

## (Resp) 

# 9.0 Physical and Chemical Properties APPEARANCE: Grayish brown to black free-flowing granules ODOR: None FLASH POINT: N/A This material does not give a flash point by conventional methods. STABILITY: Stable SPECIFIC GRAVITY: 3.05-3.20 PH: Not applicable VAPOR PRESSURE @ 25 ̊C: Not applicable VISCOSITY: Not applicable SOLUBILITY IN WATER: Nonsoluble BOILING POINT: Not applicable 

# 10. Stability and Reliability Normally stable as defined in NFPA 704-12 (4-3.1) 

# 11. Toxicological Information SEE SECTION 3 LC50 Not available LD50 Not available 

# 12. Ecological Information Not determined 

# 13. Disposal Conditions Dispose of according to local, state/provincial, and federal requirements. 

# 14. Transportation Information 14.1 U.S. Department of Transportation Non-regulated 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-regulated 

# 15. U.S Regulatory Information (Selected Regulations) SARA TITLE III Section 302: None Section 312: None Section 313: None Toxic Substance Control Act (TSCA): N/A CERCLA Reportable Quantity: NoneClean Air AmendmentsHazardous Air Pollutants: None California State Proposition 65: N/A 

# 16. Other Information The OSHA Hazard Communication Standard 29CFR 1910.1200 requires that the information contained on these sheets be made available to your workers. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. 

# Disclaimer Seller makes no warranty, expressed or implied, concerning the product or the merchantability or fitness thereof for any purpose, except that the product conforms to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed.In no event shall seller be liable for incidental or consequential damages, whether buyer’s claim is based on contract, breach of warranty, negligence or otherwise. ISSUE DATE: 1-SEPTEMBER-06



# Tel: 479.782.2001 Toll Free: 800.643.2149 Fax: 479.782.9984 www.proppants.saint-gobain.com 5300 Gerber Road Fort Smith, AR 72904Sand 100 mesh 

## MSDS Page of4 

# SHBENCHMARK3M
MATERIAL SAFETY 

# DATA SHEET

Insignificant Slight Moderate High Extrame



### Section 

## General Information

Sand 100 mesh 

## NA Benchmark Energy Products L.P 4113 West Industrial Midland Texas 79703 

## 432 697-8171 

## 432 697-8171 

### 800 349-8171 

### 800 4249300 September 2004 November 1994 Benchmark Energy Products L.P 

### Section II 

## Composition Information 

## on Ingredients Principle Hazardous 

### Components 

# CAS By 

### Weight%
This product is non-hazardous in accordance with 

## OSHAs Hazard Communication Statement


### Section III 

### Physical 

## and Chemical Properties
Freezing Point 

## NA Boiling Point 

## NA Vapor Pressure 

## NA Solubility in 

### Water Insoluble Specific Gravity 

# 11201 2.65 

## pH NA Appearance and 

### Odor Light brown granules odorless 

### HMIS Hazard Rating Health Fire Reactivity

Product 

### Name Product Description Manufacturer Address

For information on health hazards call For product sales information call 24 Hour Emergency Information call Chemtrec Emergency 

### Number Information effective date Replaces Preparer



## KEY-H EC-1 -001371Sand 100 mesh 

## MSDS Page of 

### Section 

## IV Fire 

## and Explosion Information Flash Point and Method of Determination 

## NA Upper Explosion Limit by 

## Vol NA Lower Explosion Limit by 

## Vol NA Auto-Ignition Temperature Extinguishing 

### Media This chemical is not combustible Use media suitable for the surrounding fires Dry chemical 

## C02 foam or water spray Special Fire Fighting Procedures None 

### known Unusual Fire/Explosion Hazards None 

### known

Section 

## Health Effects 

## Information Primary Routes of Entry Inhalation
Effects of Overexposure Acute EYE/SKIN 

### CONTACT SKn ABSORPTION INHALATION Inhaling respirable silica may aggravate existing respiratory system diseases and/or dysfunctions Exposure to dust 

### may aggravate existing skin and/or eye condition INGESTION Chronic Chronic overexposure to respirable crystalline silica has caused silicosis progressive pneumoconiosis Chronic tobacco smoking may further increase the risk of developing chronic lung problems 

## EMERGENCY AND FIRST AID 

## PROCEDURES EYES In case of contact immediately flush eyes with plenty of water for at least 15 minutes using an eyewash fountain if available Lift upper and lower lids and rinse well under them Get medical attention preferably an ophthalmologist if irritation occurs SKIN Flush all affected areas with plenty of water for several minutes Remove and wash any contaminated clothing and shoes Get medical attention if skin irritation occurs INGEsTIoN If victim is conscious and alert give two or more glasses or milk or water to drink If available give one tablespoon of Syrup of Ipecac to induce vomiting If vomiting has not occurred in 10 minutes the same amount of Syrup of Ipecac 

### may be repeated one additional time Alternatively induce vomiting by touching the back of the throat with finger 

### Do not induce vomiting on unconscious or convulsing person Contact physician or call the Poison Control Center 

## 800 441-0040
INHALATION Remove to fresh air If breathing has stopped administer artificial respiration oxygen or 

### CPR if needed Consult physician Carcinogenicity 

### IARC Monographs 

### No 

## NIP No 

## OSHA No EMERGENCY AND FIRST AID 

### PROCEDURES Crystalline silica the major component of this product is on the 

### NTP and 

### IARC carcinogen lists but not on the 

## OSHA carcinogen list 

### IARC and 

### NIP have determined that there is sufficient evidence for carcinogenicity to experimental animals exposed to crystalline silica and limited evidence for carcinogenicity to humans Limited evidence means that causal relationship is possible however other explanations such as chance bias or confounding factors cannot be adequately excluded



## KEY-H EC-1 -001372Sand 100 mesh 

## MSDS Page of4


### Section 

## VI Reactivity 

## Information Stability Stable Conditions to 

### Avoid Do not use for abrasive blasting Avoid contact with strong oxidizing agents and hydrofluoric acid Hazardous Decomposition Products 

### When heated above 1580 deg is transformed into tridymite and when heated above 2678 deg it is transformed into cristobalite which are both fibrogenic to the lungs Hazardous Polymerization Will not occur



### Section 

## VII Spill 

## and Leak Procedures Leak and Spill Procedures Dike or contain spill to prevent material from entering waterways 

### Pump large spills into salvage containers Soak up residue or small spills with absorbent pads clay or dirt and place in salvage containers
Waste Disposal Dispose of according to all local/state and federal regulations Handling Procedures and Special 

### Equipment Do not get in eyes on skin or on clothing 

### Do not take internally 

### Do not breathe vapors or dust 

### Wash thoroughly after handling product Storage Requirements Keep container closed Store in cool dry place Store in well-ventilated area


### Section 

## VIII Personal Protection Respiratory Protection Not generally required unless needed to prevent respiratory irritation If concentration exist at levels greater than an hour 

## TWA of 0.1 mg/m3 an approved dust respiratory must be worn For respirable levels that exceed an hour 

## TWA of 0.5 

### mg/m3 an approved 

## HEPA filter respirator must be 

### worn If respirable levels exceed an hour 

## TWA of mg/rn3 positive pressure full face respiratory or equivalent is required Follow guidelines contained in 29 

### CFR 1910.134 

## OSHAs respiratory protection standard
Ventilation Provided adequate ventilation Use local exhaust as needed to maintain airborne exposure below control limits Personal Protective 

### Equipment Use safety glasses or goggles 

### PVC or nitrile gloves and chemical apron


### Section 

## IX Transportation Information OSHA Label Sand 100 

### Mesh Avoid contact with skin eyes and clothing Wear protective goggles rubber or 

### PVC gloves and aprons Benchmark Energy Products 

### L.P 4113 Industrial Midland 

## TX 79703 24 hour Chemical Emergency 

### Number 

## 800 424-9300 Product label 

### may contain additional 

### non-OSHA related information 

## DOT Proper Shipping 

## Name Hazard Class 

### UN/NA 

## Number Packing 

### Group 

## RQ If needed
Not regulated
Label Required None



## KEY-H EC-1 -001373Sand 100 mesh 

## MSDS Page of 

### Section 

## Regulatory Information

Environmental Sara Title III Section 302/304 This product does not contain ingredients listed as an Extremely Hazardous Substance
Section 311/312 Delayed
Section 

### 313 This product contains the following ingredients at level of 

### 1% or greater which appear on the list of Toxic Chemicals None
Other Regulatory Information 

### TSCA Inventory All of the components in this product appear on the 

### TSCA inventory Domestic Substances List All of the components in this product appear on the Domestic Substances List 

### Section 

## XI 

# DISCLAIMER

This Material Safety Data Sheet 

# MSDS was prepared in accordance with the provisions and requirements of 29 

### CFR 1910.1200 and discloses the physical and health hazards of all hazardous chemicals contained in the Product described in this 

## MSDS but unless otherwise noted does 

## NOT describe or disclose 

### ALL of the chemicals/components in the Product some of which 

### may be Trade Secrets The information included in this 

## MSDS is based on data developed or compiled by Benchmark Energy Products L.P 

## Benchmark from open literature independent laboratory studies and other available scientific evidence and is believed to be accurate and complete but Benchmark makes no warranty with respect thereto Neither does Benchmark 

### make any

representation or warranty express or implied with respect to the Product or its suitability for any purpose or use hereby disclaiming all such warranties including the implied warranties of merchantability

and fitness for particular purpose and the implied warranty that the Product is free of claims of third persons by way of infringement or the like Anyone intending to use the Product described in this 

## MSDS

should satisfy himself that the Product is suitable for their particular purposes and intended uses It is the obligation of each user of the Product described in this 

## MSDS to determine and comply with the requirements of
all statutes local state and federal applicable to its use storage and disposal
Footnote ACGIIII American Conference of Governmental Industrial Hygienists NIOSH National Institute for Occupational Safety and Health Hygienists CAS Chemical Abstracts Service Register number NIP National Toxicology Program CL Ceiling Limit 

### OSHA TWA Occupational Safety and Health Administration Time Weighted Average IARC International Agency for Research on Cancer PMCC Pensky Martens Closed Cup Flash Point Determination ASTM D93-19 34 

### NA Not Applicable STEL Short Term Exposure Limit ICC Tagliabue Closed Cup flash point determination ND Not Determined TLV Threshold Limit Value NFPA National Fire Protection Association 

### TWA Time Weighted Average hours



## KEY-H EC-1 -001374DATE PREPARED JANUARY 1996 DATE REVISED OCTOBER 111999
T- PAK WARM/OTHER WARM PRODUCTS MATERIAL SAFETY DATA SHEET

CHEMICAL PRODUCT AND 

### COMPANY IDENTIFICATION

PRODUCT NAME PRODUCT CODES T-PAK WARM/104 CATALOG 11465-010
PORTA WARM DISPOSABLE MATTRESS CATALOG 114 75-010 VHA PORTA WARM DISPOSABLE MATTRESS CATALOG V11475-O1I
INFANT HEEL WARMER CATALOG 11460-010 VHA INFANT HEEL WAEMER CATALOG V1146I-I10
INFANT HEEL WARMER W/TAPE CATALOG 11460-ClOT NOVA INFANT HEEL WARMER W/TAPE CATALOG V1146I-O1T
DESCRIPTION CHEMICAL MIXTURE
PRODUCT USE PACK USED FOR TEMPORARY TEMPERATURE MAINTENANCE USER CODE/ IDENTIFICATION MANUFACTURER ALLEGIANCE HEALTHCARE 1500 WAUKEGAN ROAD MCGAW PARK IL 60085 USA TELEPHONE 1-800-964-5227 CUSTOMER SERVICE AM-430 PM CST M-F
FOR EMERGENCY INFORMATION CONTACT 3E COMPANY 1-800-451-8346

COMPOSITION/INFORMATION 

### ON INGREDIENTS

ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 THIS PRODUCT CONTAINS NO HAZARDOUS INGREDIENTS COMPONENT SYNONYM GAS NO PERCENTAGE EXPOSURE LIMITt W/V SOOIUM THIOSULFATE PENTAHYDRATE 10102-17-7 80 NONE DEXTROSE MONOHYDRATE 50-99-7 15 NONE WATER 7732-18-5 NONE

LIMIT ESTABLISHED BY ACGIR AND NIOSH

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW NONVOLATILE NONFLAMMABLE MIXTURE IN WATER PACKAGED IN SMALL QUANTITIES
POTENTIAL HEALTH EFFECTS
EYE CONTACT MAY RE SLIGHT IRRITANT INGESTION NOT HAZARDOUS BY INGESTION IN SMALL QUANTITIES INHALATION INHALATION NOT LIKELY UNDER NORMAL USE CONDITIONS ASPIRATION HAZARD LIRE THAT OF WATER
SKIN ABSORPTION



## KEY-H EC-1 -001375PRESENTS NO HAZARD ABSORBED
SKIN CONTACT SLIGHT IRRITANT TO NONIRRITANT CARCINOGEN STATUS OSHA NOT LISTED NTP NOT LISTED IARC NOT LISTED MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE NOT APPLICABLE FROM ACCIDENTAL EXPOAURE

FIRST AID MEASURES

EYE CONTACT RINSE WITH WATER OR NORMAL SALINE INGESTION NOT HARMFUL IF ACCIDENTALLY INGESTED IN OMALL QUANTITIES INHALATION NONVOLATILE LIQUID TREAT FOR ASPIRATION OF WATER
SKIN CONTACT NONHAZARDOUS WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND WATER REMOVE AND LAUNDER OR CLEAN CONTAMINATED CLOTHING AND SHOES

FIRE FIGHTING MEASURES

NONFLAMMABLE SOLUT EON

ACCIDENTAL RELEASE MEASURES

SMALl SPILLS CAN BE TAKEN UP WITH AN ADSORBANT AND PLACED IN CLEAN DRY CONTAINERS FOR LATER DISPOSAL
THIS PRODUCT IS NONHAZARDOUS WASTE WHEN SPILLED OR DISPOSED OF AS DEFINED IN RESOURCE CONSERVATION RECOVERY ACT RCBA REGULATIONS 40 CFR 261

HANDLING AND STORAGE

STORE UNDER THE FOLLOWING CONDITIONS STORE AT ROOM TEMPERATURE NOT TO EXCEED 104 DEC F/40 DEG PROTECT FROM FREEZING

EXPOSURE CONTROLS/PERSONAL PROTECTION

CLOTHING N/A
EYE PROTECTION N/A GLOVES N/A RESPIRATORY PROTECTION NO RESPIRATORY PROTECTION NEEDED UNDER NORMAL USE CONDITIONS
SKIN PROTECTION NO SKIN PROTECTION NEEDED UNDER NORMAL USE CONDITIONS VENTILATION NO VENTILATION SHOULD BE REQUIRED UNDER NORMAL CONDITIONS OF USE EXPOSURE GUIDELINES OR LIMITS NO OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY ACGIH OR NIOSH



## KEY-H EC-1 -001376PHYSICAL 

### AND CHEMICAL PROPERTIES

APPEARANCE CLEAR TO OFF WHITE LIQUID BOILING POINT NOT ESTABLISHED FREEZING POINT NOT ESTABLISHED VAPOR PRESSURE NOT ESTABLISHED SPECIFIC GRAVITY NOT ESTABLISHED SOLUBILITY IN WATER SOLUBLE PH NOT ESTABLISHED

10 STABILITY 

### AND REACTIVITY

HAZARDOUS POLYMERIZATION NOT REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES INCOMPATIBILITIES SPECIFIC MATEEIALS TO AVOID ACIDS NITRATE SALTS OXIDIZING ADENTS CHLORINE DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES

11 TOXICOLOGICAL INFORMATION

SEE WARNING STATEMENTS ON PACKADE LABEL ADVERSE AND OVERDOSE EFFECTS IN HUMANS THE FOLLOWING SIDE/ADVERSE EFFECTS HAVE BEEN SELECTED ON THE BASIS OF THEIR POTENTIAL CLINICAL SIGNIFICANCE AND ARE NOT NECESSARILY INCLUSIVE GET MEDICAL ATTENTION FlAY REQUIRE MEDICAL ATTENTION IF HOTHERSOME MULTIPLE UNITS INGESTED EXTENSIVE AND PROLONGED EYE OR SEIN CONTACT LEADS TO PERSISTENT IRRITATION INGESTION OF LARGE QUANTITIES LEADS TO PROLONGED DIARRHEA

12 ECOLOGICAL INFORMATION

ENVIRONMENTAL IMPACT RATING 

### 0-4 NO DATA ACUTE AQUATIC TOXICITY NO DATA DEGRADABILITY YES
LOG BIOCONCENTRATIONS FACTOR DATA NOT AVAILABLE LOG OCTANOL/ WATER PARTITION COEFFICIENT NO DATA

13 DISPOSAL CONSIDERATIONS

REPROCESS OR BURN IN AN APPROVED INCINERATOR WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS PLEASE BE ADVISED HOWEVER THAT STATE AND LOCAL REQUIREMENTS FOR WASTE DISPOSAL MAY BE MORE RESTRICTIVE OR OTHERWISE DIFFERENT FROM FEDERAL REGULATIONS



## KEY-H EC-1 -00137714 TRANSPORT INFORMATION

DOT HAZARDOUS MATERIAL REOULAT IONS DO NOT APPLY TO THIS PRODUCT TRANSPORTATION AND HAZARDOUS MATERIALS DESCRIPTION
DOT SHIPPING NAME NOT APPLICABLE
DOT HAZARD CLASS NOT APPLICABLE UN/NA NDr4BEE NOT APPLICABLE PRODUCT RQ 

### LBS NOT APPLICABLE
DOT LABEL NOT APPLICABLE
DOT PLACARD NOT APPLICABLE
FREIGHT CLASS BULR NOT APPLICABLE FREIGHT CLASS PACKAGE NOT APPLICABLE PRODUCT LABEL NOT APPLICABLE

15 REGULATORY INFORMATION

FEDERAL REOULATORY INFORMATION CERCLA SECTION 103 41 CFR 302.4 REPORTABLE QUANTITY NON-APPLICABLE CERCLA/SUPERFUND 40 CFR 117.302 NON- APPLICABLE OSHA PROCESS SAFETY 29 CFR 1910.119 NON-APPLICABLE
RCRA STATUS IF DISCARDED IN ITS PURCHASED FORM THIS PRODUCT WOULD NOT BE HAZARDOUS WASTE EITHER BY LISTING OR BY CHARACTERISTIC HOWEVER UNDER RCRA IT IS THE RESPONSIBILITY OF THE PRODUCT USER TO DETERMINE AT THE TIME OF DISPOSAL WHETHER

MATERIAL CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT SHOULD BE CLASSIFIED AS HAZARDOUS WASTE 40 CFR 261.20-24
SARA SECTION 302 40 CFR 355.30 EXTREMELY HAZARDOUS SUBSTANCES NON-APPLICABLE
SARA SECTION 304 40 CFR 355.40 NON-APPLICABLE SARA HAZARD CATEOORIES TITLE III SECTIONS 311 AND 312 40 CFR 370.21 ACUTE HAZARD NO CHRONIC HAZARD NO FIRE HAZABD NO REACTIVITY HAZARD NO BUDDER RELEASE HAZARD NO SARA SECTION 313 40 CFR 372.65 TOXIC CHEMICALS NON-APPLICABLE TSCA STATUS FDA EXEMPT
STATE REGULATORY INFORMATION CALIFORNIA PROPOSITION 65 NOT ON LIST OTHER STATES MAY BE MORE RESTRICTIVE OR OTHERWISE DIFFERENT

16 OTHER IN FORMATION

ABBREVIATIONS CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT ADMINISTERED BY EPA IARC INTERNATIONAL AGENCY FOR RESEARCH ON CANCER NTP NATIONAL TOXICOLOGY PROGRAM



## KEY-H EC-1 -001378OSHA OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION US DEPARTMENT OF LABOR WHICH REGULATES WORKPLACE CONDITiONS RCRA RESOURCE CONSERVATION AND RECOVERY ACT ADMINI STERED BY EPA SARA SUPERFUND ANENDMENTS AND REAUTHORIZATION ACT OF 

### 190 TITLE III IS ALSO KNOWN AS THE EMEROENCY PLANNING AND COMMUNITY RIGHT-TO-RROW ACT ADMINISTEEED BY EPA TSCA TOXIC SUBSTANCES CONTROL ACT
ALLEGIANCE HEALTHCARE CORPORATION DISCLAIMER NEITHER ALLEGIANCE HEALTHCARE CORPORATION NOR ANY OF ITS AFFILIATES OR SUBSIDIARIES ASSUMES ANY LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS INFORMATION FINAL DETERMINATION OF SUITAHILITY OF ANY MATERIAL FOR PARTICULAR USE IS THE SOLE RESPONSIBILITY OF THE USER ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS WHICH EXIST IT IS THE USERS RESPONSIBILITY TO DETERMINE THE APPROPRIATE HANDLING DISPOSAL OR OPEN DISPOSITION FOR THE MATERIAL OR EMERGENCY RESPONSE ACTIONS IN LIGHT OF THE CONDITION OF THE MATERIAL APPLICABLE REGULATIONS AND OTHER CIRCUMSTANCES ALLEGIANCE HEALTHCARE MCGAW PARK IL 6008



## KEY-H EC-1 -001379

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 1 

# Section I Product Type : Oil/gas well proppant Application: Hydraulic Fracturing Manufacturer's Name Telephone Number Santrol, Inc. (281) 431-0670 2727 FM 521 Fresno, TX 77545 

# Date 10/02/02 

# Section II - Hazardous Ingredients Hazardous components CAS # OSHA PEL ACGIH TLV Percent Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M 3 

# 0.10 mg/M 3 

# Balance Respirable Respirable 

# P/F Resin 900303504 N/K N/K 1-5 Hexamethylenetetramine 1009-7-0 N/K N/K <2 

# Hazard Rating Scale:1 Product: 0-Minimal 3-Serious Health: 1 1-Slight 4-Severe Fire: 0 2-Moderate Reactivity: 0 Special: None Canada Hazardous Products Act Ingredients Disclosure List Chemical Name % Item No French Version Cas# None N/A N/A N/A N/A WHIMIS CLASS D, DIV 2A, 2B CEPA Listed on DSL or otherwise in compliance with CEPA NPRI CEPA subsection 16 (1) None required U.S DOT Not Regulated 

# Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight None None

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 2 

# Section III - Physical/Chemical Characteristics Boiling Point: N/A o 

# F Specific Gravity (H 2 

# O=1): 2.53 - 2.60 Vapor Pressure (mmHg):N/A at 20 o 

# C Melting Point: N/A Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A Solubility in Water: Insoluble Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.



# Section IV - Fire and Explosion Hazard Data Flash Point: o 

# F (TCC) Not Known Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K Extinguishing Media: Use water spray, alcohol foam, CO 2 

# or Dry Chemical. Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in the presence of an ignition source. See Hazardous decomposition products, Sec. V and Toxicity, Sec. IX. 

# Section V - Reactivity Data Stability: Stable Polymerization will not occur. Conditions to avoid: Materials to avoid: Oxidizers Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and unidentified compounds in smoke. 

# Section VI - Health Hazard Data Primary Routes of exposure: Swallowing, skin or eye contact, inhalation. Emergency and First Aid Procedures: Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary. Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention. Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 3 Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention. OSHA Hazard Communication Standard 29 CFR1910.1200 See above standard. This material presents possible health hazards SARA Title III Delayed Health Hazard TSCA Section 8(b) All reportable chemical substances are listed on the TSCA inventory. 

# Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Spilled or Released: Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste. Precautions to Be Taken in Handling and Storing: Keep away from heat and flames. Store in a cool, dry place. Repair and Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container. Other Precautions: Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. 

# Section VIII - Control Measures Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at the point of use. Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL. Eye Protection: Eye Goggles Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes. Other Precautions: None 

# Section IX - Toxicity Data Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria. Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria. Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease, including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant characteristics of the crystalline silica or on external factors affecting its biological activity or

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 4 distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997). NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen. Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided herein. All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 1 

# Section I Product Type : Oil/gas well proppant Application: Hydraulic Fracturing Manufacturer's Name Telephone Number Santrol, Inc. (281) 431-0670 2727 FM 521 Fresno, TX 77545 

# Date 10/02/02 

# Section II - Hazardous Ingredients Hazardous components CAS # OSHA PEL ACGIH TLV Percent Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M 3 

# 0.10 mg/M 3 

# Balance Respirable Respirable 

# P/F Resin 900303504 N/K N/K 1-5 Hexamethylenetetramine 1009-7-0 N/K N/K <2 

# Hazard Rating Scale:1 Product: 0-Minimal 3-Serious Health: 1 1-Slight 4-Severe Fire: 0 2-Moderate Reactivity: 0 Special: None Canada Hazardous Products Act Ingredients Disclosure List Chemical Name % Item No French Version Cas# None N/A N/A N/A N/A WHIMIS CLASS D, DIV 2A, 2B CEPA Listed on DSL or otherwise in compliance with CEPA NPRI CEPA subsection 16 (1) None required U.S DOT Not Regulated 

# Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight None None

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 2 

# Section III - Physical/Chemical Characteristics Boiling Point: N/A o 

# F Specific Gravity (H 2 

# O=1): 2.53 - 2.60 Vapor Pressure (mmHg):N/A at 20 o 

# C Melting Point: N/A Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A Solubility in Water: Insoluble Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.



# Section IV - Fire and Explosion Hazard Data Flash Point: o 

# F (TCC) Not Known Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K Extinguishing Media: Use water spray, alcohol foam, CO 2 

# or Dry Chemical. Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in the presence of an ignition source. See Hazardous decomposition products, Sec. V and Toxicity, Sec. IX. 

# Section V - Reactivity Data Stability: Stable Polymerization will not occur. Conditions to avoid: Materials to avoid: Oxidizers Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and unidentified compounds in smoke. 

# Section VI - Health Hazard Data Primary Routes of exposure: Swallowing, skin or eye contact, inhalation. Emergency and First Aid Procedures: Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary. Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention. Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 3 Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention. OSHA Hazard Communication Standard 29 CFR1910.1200 See above standard. This material presents possible health hazards SARA Title III Delayed Health Hazard TSCA Section 8(b) All reportable chemical substances are listed on the TSCA inventory. 

# Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Spilled or Released: Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste. Precautions to Be Taken in Handling and Storing: Keep away from heat and flames. Store in a cool, dry place. Repair and Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container. Other Precautions: Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. 

# Section VIII - Control Measures Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at the point of use. Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL. Eye Protection: Eye Goggles Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes. Other Precautions: None 

# Section IX - Toxicity Data Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria. Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria. Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease, including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant characteristics of the crystalline silica or on external factors affecting its biological activity or

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 4 distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997). NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen. Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided herein. All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 1 

# Section I Product Type : Oil/gas well proppant Application: Hydraulic Fracturing Manufacturer's Name Telephone Number Santrol, Inc. (281) 431-0670 2727 FM 521 Fresno, TX 77545 

# Date 10/02/02 

# Section II - Hazardous Ingredients Hazardous components CAS # OSHA PEL ACGIH TLV Percent Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M 3 

# 0.10 mg/M 3 

# Balance Respirable Respirable 

# P/F Resin 900303504 N/K N/K 1-5 Hexamethylenetetramine 1009-7-0 N/K N/K <2 

# Hazard Rating Scale:1 Product: 0-Minimal 3-Serious Health: 1 1-Slight 4-Severe Fire: 0 2-Moderate Reactivity: 0 Special: None Canada Hazardous Products Act Ingredients Disclosure List Chemical Name % Item No French Version Cas# None N/A N/A N/A N/A WHIMIS CLASS D, DIV 2A, 2B CEPA Listed on DSL or otherwise in compliance with CEPA NPRI CEPA subsection 16 (1) None required U.S DOT Not Regulated 

# Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight None None

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 2 

# Section III - Physical/Chemical Characteristics Boiling Point: N/A o 

# F Specific Gravity (H 2 

# O=1): 2.53 - 2.60 Vapor Pressure (mmHg):N/A at 20 o 

# C Melting Point: N/A Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A Solubility in Water: Insoluble Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.



# Section IV - Fire and Explosion Hazard Data Flash Point: o 

# F (TCC) Not Known Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K Extinguishing Media: Use water spray, alcohol foam, CO 2 

# or Dry Chemical. Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in the presence of an ignition source. See Hazardous decomposition products, Sec. V and Toxicity, Sec. IX. 

# Section V - Reactivity Data Stability: Stable Polymerization will not occur. Conditions to avoid: Materials to avoid: Oxidizers Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and unidentified compounds in smoke. 

# Section VI - Health Hazard Data Primary Routes of exposure: Swallowing, skin or eye contact, inhalation. Emergency and First Aid Procedures: Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary. Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention. Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 3 Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention. OSHA Hazard Communication Standard 29 CFR1910.1200 See above standard. This material presents possible health hazards SARA Title III Delayed Health Hazard TSCA Section 8(b) All reportable chemical substances are listed on the TSCA inventory. 

# Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Spilled or Released: Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste. Precautions to Be Taken in Handling and Storing: Keep away from heat and flames. Store in a cool, dry place. Repair and Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container. Other Precautions: Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. 

# Section VIII - Control Measures Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at the point of use. Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL. Eye Protection: Eye Goggles Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes. Other Precautions: None 

# Section IX - Toxicity Data Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria. Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria. Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease, including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant characteristics of the crystalline silica or on external factors affecting its biological activity or

# SANTROL Material Safety Data Sheet

Super HS TM



# , Super LC TM



# , Super TF

TM 

# , Super DCTM



# , PolarProp Tempered HS TM



# , Tempered LC TM



# , Tempered TF TM 

# , Tempered DC TM 

# Super Pac TM



# , Super HT

TM

# , OptiProp TM



# Page 4 distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997). NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen. Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided herein. All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.

# Receive 7/10/98 

# 1040 19155733340 AMERICAN 

## ENERGY Page 16 @7/10/1998 

## 1113 19155733348 

## CHEMPLE BEARD PAGE 15 

# Material Safety 

# Data Sheet

NYPA 

### DOT



## Co.flrsde 

# $14 American Energy Service ci Not available Syio.y Not available 

### TSCA Cbees1 

# .g Not applicable Cbe.kal forela Not applicable 

## CAS Not appllCSble 

### CbeW.I ieiIy Phoephonete COdS 

### Sip.i Ch.mprnx LC Moleikr 

### wele Not applicable P.O Box 1011 Snydir Msaueturer Chemplex 

## LC 51d673-72S P.O Box 1071 Matertel Phoephonate scale 

### inhoc Snyder 

### TX 79550 

## 915 573-7298 

# ecOn IA Flrzt 

## Aid 

# $9.asws Eye coitact Check for and remove any contact lenses IMMEDLATELY flush eyes with running water for at least 15 mInutes keectng eyelids open 

### COLD watei may be used 

### DO NOT use an eye ointment Seek medical attention

Skis contect If the chemical got onto the clothed portion of the body remove the contaminated clothes as quickly as possible protecting your awn hands and body Place the victim under deluge shawer If the chemical touches the victrna exposed skin such as the hands Gently and thoroughly wash the contaminated skin with running water and non-abrasrie soap Be particularty careful to clean folds crevices creases and groln 

### COLD water may be used If irritation persints seek medical attention 

### Wash contaminated clothIng before reusing Hsasrdou skis contact 

### Wash with disinfectant soap end cover the contaminated skin with an anti-bacterial cream Seek medical attention

S1tht lahalatlo PJIow the victim to rest in welt ventilated area Seek immediate medical attention
Uaardoas IehIatIon Evacuate the vict to safe area as soon as possible Loosen tht clothing such as collar tie belt or waistband If breathing is difficult administer oxygen If the victim is not breathing perform mouth-to-mouth resuscitation 

## WARNING

It may be dangerous to the person providing aid to grve mouth-to-mouth resusotation when the Inhaled material is 

# tc
infectious or corrosr Seek immediate medical attention


## 3II IeSIiOn 

## LJ ru. IIP.JU VL$IflUIS 

## IiY %MIJUG

... 8ttGntiÆi

Hazardous lacstlo 

## DO NOT induce vomiting Examine the lips and mouth to ascertain whether the tissues are 

### damaged 

## pos3e indication that the toxic material was Ingested the absence of such 

## ans hawever is not Conclusive Loosen 

# tI clothing such as collar tin belt or waistband If the victim is not breathing perform mouth-to-mouth 

### eeuecatc Seek medical attention



## KEY-H EC-1 -001402

## ReceIved 7/10/98 

# 1041 19155733340 AMERICAN 

## ENERGY Page 17 07/10/1998 

## 1113 19155733340 CHEMPLEX BEARD PAGE 17


### II 

# HJZEdOUS 

# 1n
CAS 

## %by 

## We%bt TLV/PEL



## _______________________ pho.phcA.cid trade secret



## KEY-H EC-1 -001403

## Received 7/10/96 

# 1041 19155733340 AMERICAN 

## ENERGY Page 18

Ffredc$rtdstlOD products Not plicthle

Flosh 

# ts Not applicable

Not applicable 

### CHEMPLEX BEARD

Fir 

## ezIkbl.g Not applicable procedures



### Th.$bUftY Not 

### apcable

Reark No additional remark

Risks of explosion Risks of 

### eelofl of the product presence of mechanical mipect P4ot available Risks of 

# elon of the product in presence of static dmcherge Not avthle No specific information available in our databeee regarding the producta risks of pIoaiOfl the presence of vaictiS
matenats Re.ark No additional remark



## S.ctlon 

# jvftv Da.a StebWcy The product stable RiaMous 

# O.r 

# cts Not avadable

Products ç1dcrsdattoQ Possibly hazardous short term degradation products ama nlikely 

### Hwsver long term degradation products may 

# re
The products of degradation are lees toxic than the product itself
Reusark No addltnal remark
CorrosMly No specific information is available in our database rgarthng the corrosri4y of 

## th product fri presence of varotis
materiats

R.cusark No additional remark 

## urfrst available our database reaardinQ the reactwy of this matenal at presence of vaflCJ3 cthV

No additional remark 

### 07/10/1998 

## 1113 19155733340

The product Auto-Iguidon te.per.ture Not 

### apcable Non-f1Tlmnable 

### PAGE 18



## KEY-H EC-1 -001404

## Received 7/10/98 

# 1041 19155733340 AMERICAN 

## ENERGY Page 19 87/10/1998 

## 1113 19155733340 CHEMPLEX BEARD 

# Sedkfl Th nMdCaI 

# fI

.. .Jiii 

# Awkak E.ergy Ssrvke 

### PAGE 19 

# ig 4/5

s.fefl7 Ingestion 

### TLV TfIa iic.t 1WA CEL 

## mhi
COdIUl lOCal AOfllMl or 

# oug IlmilO Tozicity for 

### aulls Acute oral tdcity 

## 1150 3060 mg/kg 

## Rat Calculated value for the mbdure Acute dermal todcity 

## LD5O 5000 mg/kg Rthbit Calculated value for the mbdure



## Rawk No eddionel remark

Cbreak 

### eets as TOOCkY of the product to the reproductive system Not available 

## ku.s Rerk No addlonal renieric
Acute effects as 

# ssa No specific iiformetion is available in our database regarding the otner tedc effects of 

## th material for humans

No additional remark



# W.t disposal

Storage Corrosive matetM 

### houI be stored In separate safety etorege cabinet or room

Precastlois Keep container dry Do not breathe 

### gas fumes vapor or spray Never add water to this productS 

### Wear euttstis protacthle clothig if you feel unwell seek medical attentIon and show the label when possible

S.satt aud leak DIute with water and mop up or absoib with an inert 

### DRY material and place in en appropriate waste disposal C0ntEer

If necessary Neutrelir the residue with 

## duI solution of sodium carbonate

Large 

## sp sad lack Corrosrvs 

## lud Stop leak if wifhotst risk Abaot with 

### DRY earth sand or otlw non-combustible material 

### DO NOT get water 

## inz
container 

### DO NOT touch spilled material Lisa water spray curtain to divert vapor drift Prevent entry Into 

## aewr basements or confined areas dike if needed Call for assistance on disposal Neutralize 

## th residue with 

# dI

solution of sodium c.rbonte

Protective Clotkmg Splash 

### Q9les Full gut 

## Vor respirator Boots Gl.es self contained breilng epperattm should be used to inhalation of the product 

## Sugges protective clothing might not be sufflcient rsult specialist 

### BEFORE handling tH3

-.



## KEY-H EC-1 -001405

# Reeived 7/10/98 

# 1042 19155733340 AMERICAN 

## ENERGY Page 20

MArklt ts..p.rtadon
Rtmark No eddttlonsi remark

tICS 

### CLASS Corrosre 

## uid

Re.srk No additional remark 

# NA A8lLJTY

HEALTH RETIVTTV

iPCiPIC 

## KA2A ederI s.d Stats Reg.kdoes



## S.ctlon Clothing Facs 

### eh4d Full sud Vapor resptrator Be sure to use MSI-IA/NIOSH approved respirator or aquivalent Gloves 

# peros Boots Wear appropriate respirator when ventilatiOn Is kiudequete



# Sec 

# fIn Oihr lr4brmaiion Rdere.ce Not avaIlle



## Ptad 7110/98 

# EMERGENCY RESPONSE 

# 800 633-8253 

# Ud 1f 

# 4l 

# JS LLIL 

# Ib.IS u.Œ q..y Ii Al 4M14 

## aaa 

# ai am 

### @7/10/1998 

## 1113 19155733340 

# cfl WIi Classlrfcson DOT DOT CLASS Corrosive quid 

### CHEMPLEX BEARD Servke 

### PAGE 20 page 

### 55



# ào corrosive liqu n.o.s Phop4ontC Acid Ill Re.ark Not available

Vahdated by Cbep4ei L.C 059/9/94 Verl6sd by 

### Che.pkx L.C



## KEY-H EC-1 -001406

# MATERIAL SAFETY DATA SHEET
Plexaid 

## 667 NFPA 

# 5r

Product 

## And Company Identification 

## Su%ter tMnufattufel 

### Chemplex 

# LC Chemplex 

# LC P.O Box 1071 

## P.O Box 1071 

## 506CR 137 

### 506 

## CR 137 

### Snyder TX 79550 United States 

### Snyder 

## TX 79550 United States Telephone 

## Number 

## 325 573-7298 

### Telephone 

## Number 

## 325 573-7298 

## FAX Number 

## 325 573-3340 

## FAX Number 

## 325 573-3340
SuDolier 

### Emeroencv Contacts 

### Phone Number Manufacturer 

### Emeraencv Contacts 

### Phone Number 

## 800 6334253 

## 800 6334253

Issue 

### Date 03/04/2003 Product 

## Name Plexakl 667 

## CAS Number Not 

### Estabtied Chemical 

### Family Not Available 

## MSDS Number 101 

### Synonyms Not Available Product/Materiat 

### Uses Oilfield Scale Inhibitor 

### Compositionfnfomaton 

## On ngrethents 

### Uecknt CAS Percent Of



## tne Nuaer Tcdal 

### Weht NO HAZARDOUS INGREDIENT Not EstIish

Hazards Identification Primaiy 

## Routess Of Entry Not available 

### Eve Hazards Not Available 

## Skn Hazards Not Available Inaestion Hazards Not Available Inhalation Hazards


# Pao tof Iot 

### Poaiabe



## KEY-H EC-1 -001407

# MATERiAL SAFETY DATA SHEET
Plexaid 

## 667

FIrSt Aid 

### Measures
No known 

### EFFECT on eye contact rinse with water for few minutes Skin 

### No known 

## EFFECT on skin contact rinse with water for few minutes lnaestion 

### Do not induce vomiting Loosen tight clothing such as collar tie belt or waist 

### band If the victim is not breathing perform mouth-to-mouth resuscitation 

### Seek immediate medical attention
Inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention Note 

### To Physician 

### None
Fire Fighting 

### Measures Fire 

## And Exolosion Hazards 

### May be combustible at high temperature Fire Finhtina Instructions 

### SMALL FIRE Use 

## DRY chemical 

### powder %JaiRGE 

### FIRE tise water spTay fog or 

### loam 

## Do not use water iet Accidental Release 

### Measures Small Spilt and 

### Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Large Spill and 

### Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system HandlIng 

## And Storage Handling 

## And Storage Precautions 

### Keep away from heat 

### Keep away from sources of ignition Empty containers pose fire risk evaporate the residue under fume 

### hood Ground all equipment containing material 

### Do not breathe gas/fumes/vapor/spray 

### Keep container dry 

### Deep in cool place Ground all equipment containing material 

### Keep container tightly closed 

### Keep in cool well-ventilated place Combustible materials should be stored 

### away from extreme heat and 

### away from strong oxidizing agents
Protective Clothina 

### Pictoaramsi

Exposure Controls/Personal Protection EvelFace Protection Safety glasses Skin Protection Apron/Lab coat



### Pane nf



## KEY-H EC-1 -001408

# MATERIAL SAFETY DATA SHEET
Plexaid 

## 667

Physical 

### And Chemical Properties 

### Appearance Colorless liquid 

### Odor Sweelish Chemical 

## Type Pure Physical State Liquid Boiling Point 

## 212 Specific Gravity 1.09 

## Water1 pH Factor 4-5 At Concentration Of 

# 1% solniWater Solubility Soluble in water 

## 10 Stability 

### And Reactivity 

# Lt This product is stable 

## 11 Toxicological Information Acute Studies 

### No specilic information is avaliable in our database regarding the toxic effects of this material for 

### humans 12 Ecological Information Data Available.. 

## 13 Disposal Considerations Whatever cannot be saved for recovery or recycling should be 

### managed in an appropnate and approved waste disposal facility Processing use or contamination of this product 

### may change the waste 

### management options State and local disposa% regulaYions 

## may dWIer 

## 1mm fedeia 

### dispos regutsYions 

### ispose of conlaineT and unused contents in accordance with federal state and local requirements 

### 14 Transport Information Proper Shipping 

## Name Not 

## DOT Regulated 

### 15 Regulatory Information 

### U.S R.aulatorv Infomratkn Not 

## DOT Regulated 

## 16 Other information 

## NFPA Ratina Health Fire Reactivity Revisionipreparer information 

## MSDS Preparer Edward Vinson 

## MSDS Preparer 

### Phone 

## Number 915-573-7298 This 

## MSDS Supercedes Previous 

## MSOS Dated 071192002



### Pane of



## KEY-H EC-1 -001409

# MATERIAL SAFETY DATA SHEET
Plexaid 

## 667

Disclaimer Although reasonable care has been taken in the preparation of 

## th document we extend no warranties and 

### make
no representations as to the accuracy or completeness of the information contained therein and 

### assume no responsibility regarding the suitablility of this information for the useis intended purposes or for the consequences of its 

### use Each Edividual should 

### make determination as to the suitability of the information for
their particular 

### purposess Chemplex 

# LC PWd UIM PmD5



### Pane of



## KEY-H EC-1 -001410

# Material Safety Data Sheet 

# Plexaid 6 73

Page 1 of 4 SECTION I

– IDENTIFICATION PRODUCT NAME: ........................... Plexaid 6 73 CHEMICAL FAMILY: . ...................... Phosphonates CAS NUMBER: ............................... Mixture PRODUCT USE: .............................. Oilfield Scale Inhibitor.



# SECTION II

–

HAZARDOUS INGREDIENTS HAZ INGREDIENT PERCENT CAS NUMBER PEL ORGANIC P HOSPHONIC ACID SALTS Proprietary Mixture Not Available METHYL ALOCHOL 15 - 25% 67 - 56 - 1 Not Available 

# SECTION III

–

PHYSICAL DATA APPEARANCE: .. ............................. Yellowish Liquid ODOR: . ............... . .......................... Fruity BOILING POINT: .. ........................... <100 °C FLASHPOINT: ... ..................... ... ...... 68 °F VAPOR DENSITY ( AIR =1 

# ): ............ . .... 1.02 SPECIFIC GRAVITY ( WATER =1 

# ): ... .. ... 0.99 pH (1% SOLN/WATER) 

# : ....................... 4-6 SOLUBILITY .................................... Easily soluble in cold water, hot water, methanol. Soluble in diethyl ether. Insoluble in n-octanol. WT : .......................................... .. .... 8.3 # per gallon



# SECTION IV

–

FIRE AND EXPLOSION DATA FLASHPOINT: ........................ . ... ..... 68 °F FLAMMABLE LIMITS: ... . ................... LOWER: 6 % UPPER: 36.5 % (Methyl Alcohol)

DATE PREPARED: ........... 11 / 18 /20 0 8 REVISION DATE: ............. 0 8 /25 /2 0 0 9 EMERGENCY NUMB ER: ... 800 - 633 - 8253 PRODUCT NUMBER: ....... .011 19 Chemplex, Ltd
. 506 CR 1 3 7 Snyder, TX 79549 ( 325 ) 573

- 7298 

# CHEMPLEX

# Material Safety Data Sheet 

# Plexaid 6 73

Page 2 of 4 FLAMMABLE HAZARDS: ......... . .... .... Flammable in presence of open flames and sparks of heat, of combustible materials. Non-flammable in presence of oxidizing materials, of reducing materials. EXTINGUISHING MEDIA: ......... . ....... . Flammable liquid, soluble or dispersed in water. FIRE FIGHTING PROCEDURES: ....... SMALL: Use dry chemical powder. LARGE: Use alcohol foam, water spray or fog. EXPLOSION HAZARDS: .................. . Explosive in form of vapor when exposed to heat or flames. Vapor may travel considerable distance to source of ignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes. 

# SECTION V

–

REACTIVITY DATA STABILITY: .................................... This product is stable. CORROSIVITY: ............................... Not considered to be corrosive for metals and glass. REACTIVITY: .................................. Reactive with oxidizing agents. Non-reactive with organic materials, metals. 

# SECTION VI A - HEALTH HAZARD DATA ROUTE OF ENTRY: ......................... Not available. AC UTE EFFECT ON HUMANS: ......... Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. Non-sensitizer for skin. Narcotic. (Methyl Alcohol) CHRONIC EFFECTS ON HUMANS: ... This substance is toxic to the nervous system, th e reproductive system. Passes through the placental barrier. May be fatal or cause blindness if swallowed. (Methyl Alcohol) 

# SECTION VI B - FIRST AID INHALATION: ................................. SLIGHT INHALATION: Allow the victim to rest in a well ventilated area. Seek immediate medical attention. HAZARD INHALATION: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waist band. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth- to -mouth resuscitation. Seek medical attention. INGESTION: ................................... Do NOT induce vomiting. Loosen tight clothing such as a collar, tie, belt or waist band. If the victim is not breathing, perform mouth- to -mouth resuscitation. Seek immediate medical attention. EYE CONTACT: .............................. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used.

# Material Safety Data Sheet 

# Plexaid 6 73

Page 3 of 4 SKIN CONTACT: ............................ . After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices and groin. Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. 

# SECTION VII

–

SPILL, STORAGE AND DISPOSAL DATA SPILL: ........................................... SMALL SPILL: Dilute with water and mop up, or absorb with an inert DRY material and place in an appropriate waste disposal container. LARGE SPILL: Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers , basements or confined areas; dike if needed. Eliminate all ignition sources. WASTE DISPOSAL: ......................... Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. HANDLING: ................................. ... Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/ fumes/ vapor/ spray. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents. STORAGE: ..................................... Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material. A refrigerated room would be preferable for materials with a flash point lower than 37.8°C (100°F). 

# SECTION VIII

–

PROTECTIVE CLOTHING RESPIRATORY PROTECTION: ......... Wear appropriate respirator when ventilation is inadequate PROTECTIVE CLOTHING/EQUIPMENT: ..... Safety glasses, lab coat, gloves.

# Material Safety Data Sheet 

# Plexaid 6 73

Page 4 of 4 SECTION IX

–

TRANSPORTATION DATA PROPER SHIPPING NAME: .............. Flammable liquid, n.o.s., (Contains Methyl Alcohol) HAZARD CLASS: ............................ 3 UN NUMBER: ................................. UN 1993 PACKAGING GROUP: ..................... II RQ: ............................................... N/A DOT SHIPPING : .............................. Flammable liquid, n.o.s., (Contains Methyl Alcohol), 3 , UN 1993, PG II 

# SECTION X

–

OTHER REGULATORY INFORMATION TSCA STATUS: .............................. All components of this product are listed on the TSCA inventory. NFPA HEALTH: .............................. 1 NFPA FLAMMABILITY: .................... 3 NFPA REACTIVITY: ......................... 0



# SECTION XI - ADDITION ALINFORMATION PREPARED BY: .............................. Edward F. Vinson 

# EMERGENCY RESPONSE NUMBER : ... ....... 800 -633-8253

# MATERIAL SAFETY DATA SHEET SinterBall Bauxite SECTION I - SUPPLIER INFORMATION Common Name: Sinter Blast Chemical Name: BAUXITE Formula: CHEMICAL COMPONENTS MIXTURE Application: ABRASIVE - Service Used: BLASTING Product CAS#: 1318-16-7 

# SECTION II-A – COMPONENT INFORMATION COMPONENT PERCENT (%) TLV mg/m3 PEL mg/m3 Alfa-Alumina >70 10 10 Hematite 1 to 15 N/A 15 Maghemite <2 N/A 15 

# SECTION II-B - HAZARDOUS INGREDIENT INFORMATION INGREDIENT: BAUXITE CAS# 1318-16-7 % WEIGHT 100 PEL-OSHA: 10 mg/m3 Total dust - 5 mg/m3 Respirable as Alumina TLV-ACGIH: 10 mg/m3 as Al 

# SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Not applicable Melting Point: Not applicable Vapor density (Air=1): Not applicable % Solubility/Water: Insolub le a t 20oC % Solubility/Sea Water: Insoluble at 20oC Specific Gravity (H2O=1): 3.58 to 3.68 Biodegradability: Not a pplicab le Volatiles Percent: Not applicable Vapor Density: Not applicable Vapor Pressure (mm Hg): Not applicable Boiling Point (760mm Hg): Not applicable Pour Point: Not applicable Freeze Point: Not applicable Evaporation rate (Butyl Acetate=1): Not applicable Partition Coef (Octanol in Water): Not applicable Appearance: Black Grains Odor: Odorless pH: Neutral VOC: None Mineração Curimbaba Ltda Avenida João Pinheiro, 3665 37704-392 - Poços de Caldas – Minas Gerais Brazil Emergency Telephone: At any time, in Portuguese language: +55-35.3729.7600 From 7:30 A.M. to 5:00 P.M.,in English language:+55-35.3729.7676

# SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: Not applicable Auto-Ignition: Not applicable Extinguishing media: Use water spray, dry chemical, alcohol foam, or carbon dioxide. Use water to keep fire-exposed containers cool. Special Fire Fighting Procedures: None needed Unusual Fire and Explosion Hazards: Not a fire or explosion hazard NFP A HAZARD CLASSIFICATION Health: 1 Flammable: 0 Reactivity: 0 HMIS HAZARD CLASSIFICA TION Health: 1 Flammable: 0 Reactivity: 0 

# SECTION V - REACTIVITY DATA Stability: Generally considered stable Incompatibility (Materials to avoid): None expected Hazardous Decomposition or By-Product: None expected Polymerization: Polymerization is not expected to occur 

# SECTION VI - HEALTH HAZARD DATA ROUTES OF ENTRY Eyes? YES Skin? YES Inhalation? YES Ingestion? NO EFFECTS OF OVEREXPOSURE EYE CONTACT may cause irritation SKIN CONT ACT may cause irritation INHALA TION may cause drying of mucous membranes and respiratory tract irritation INGESTION may cause gastrointestinal disturbances CARCINOGENICITY NTP? NO IARC? NO OSHA? NO CHRONIC HEALTH HAZARDS None known MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE May aggravate existing respiratory and/or skin ailments EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT: Flush eyes with plenty of water. If irritation develops, call a physician. SKIN CONT ACT: Flush with plenty of water. If irritation persists, call a physician. INHALA TION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. INGESTION: Procedures normally not needed. If large quantities are ingested, seek medical advice.

# SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE EPA Waste #: Not applicable UN #: Not applicable DOT Classification: Not classified STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Contain spillage and scoop up or vacuum. Do not use a cleaning method that will generate dust. Product can cause slippery floor

. WASTE DISPOSAL METHOD Federal, state and local disposal laws and regulations will determine the proper waste disposal procedure. All waste materials should be reviewed to determine the applicable hazards (testing may be necessary). Disposal requirements are dependent on the hazard classification and will vary by location and the type of disposal selected. Some waste materials are amenable to recycle/reuse. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep bag closed. Avoid creating or inhaling dust. Wash thoroughly after handling. Store in a cool, dry location to protect product quality. PERSONNEL SAMPLING PROCEDURE For NUISANCE DUST: Refer to NIOSH Manual of Analytical Methods, 3rd Edition V olume 2, Method 0500. For METALLIC COMPONENTS: Refer to NIOSH Manual of Analytical Methods, 3rd Edition Volume 1, Method 7300. 

# SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION Use NIOSH-approved dust mask if exposure exceeds TL V. VENTILATION General; local exhaust ventilation as necessary to control dust. PROTECTIVE EQUIPMENT Chemical goggles as needed to prevent irritation. WORK/HY GIENE PRACTICES Avoid generating or breathing dust. Use with adequate ventilation. Do not eat, drink, or smoke in work area. 

# SECTION IX - FEDERAL AND STATE REGULATIONS SARA HAZARD CA TEGORIES IMMEDIATE (Acute) Health Hazard: YES DELAYED (Chronic) Health Hazard: NO FIRE Hazard: NO REACTIVITY Hazard: NO Sudden Release of PRESSURE: NO

# SARA SECTION 313 NOTIFICATION This product does not contain toxic chemicals subject to the reporting requirements of Section 313 of T itle III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

The information which is contained in this document is based upon available data and is believed to be correct. However, as such as it has been obtained from various sources, including the manufacturer and independent laboratories, it is given without warranty or representation that is complete, accurate and that it can be relied on. Mineração Curimbaba Ltda., has not attempted to conceal in any way the deleterious aspects of the product listed herein, but makes no warranty as to such. Further, as Mineração Curimbaba Ltda. cannot anticipate nor control the many situations in which the listed product or this information may be used by our customer, there is no guarantee that the health and safety precautions suggested will be proper under all conditions. It is sole responsibility of each user of the listed product to determine and comply with the requirements of all applicable laws and regulations regarding its use or disposal. This information is given solely for the purposes of heath and safety to persons and property. Any other use of this information is expressly prohibited. Health, safety, and environment department, Mineração Curimbaba Ltda. DA TE: 10/10/2005

# Sintered Bauxite 1. Chemical Name & Company Identification PRODUCT NAME: Sintered Bauxite (all mesh sizes) SYNONYM(S): Ceramic Proppant CHEMICAL FAMILY: Aluminosilicate MANUFACTURER: Saint-Gobain Proppants 5300 Gerber Road Fort Smith, Arkansas 72904 24-Hour Emergency (479) 782-2001 

# 2. Component Information CHEMICAL NAME COMMON NAME % BY WEIGHT (TYPICAL) Aluminum Silicate Mullite 15-35 Aluminum Oxide Corundum 65-85 

# 3. Hazards Identification 3.1 Emergency Overview HMIS RATING Health: 1. (Slight) Flammability: 0. (Minimal) Reactivity: 0. (Minimal) Chronic: 1. (Slight) 3.2 Potential Health Effects INHALATION: Prolonged exposure to dusts may cause respiratory tract irritation. INGESTION: No known adverse effects. EYE CONTACT: May cause irritation on prolonged or repeated contact. SKIN CONTACT: May cause irritation on prolonged or repeated contact. 

# 4.0 First Aid Measures INGESTION: Seek medical attention if large quantities are ingested. INHALATION: Remove to fresh air. EYE CONTACT: Immediately flush eyes with large quantities of water. Call a physician if irritation persists. 

# 5.0 Fire Fighting Measures FLASH POINT: Nonflammable LOWER EXPLOSION LIMIT: Not applicable UPPER EXPLOSION LIMIT: Not applicable AUTOIGNITION TEMPERATURE: Not applicable Use extinguishing agent suitable for type of surrounding fire. 

# 6.0 Accidental Release Measures SPILLS: No special procedures are required for cleanup of spills or leaks. Spherical shape of spilled pellets can create a slip hazard. 

# 7.0 Handling and Storage Store under dry conditions. Handle with adequate ventilation. Use a NIOSH/MSHA approved respirator if dust is present. 

# Material Safety Data Sheet FOR INDUSTRIAL USE ONLY

# 8.0 Exposure Control/Personal Protection 8.1 Exposure Control Minimize creation of dust. 8.2 Personal Protection Use NIOSH/MSHA approved respiratory protective equipment when airborne concentrations exceed acceptable criteria. Wear safety glasses at all times to prevent eye irritation. 8.3 Exposure Guidelines INGREDIENT CAS# %/ OSHA ACGIH-TWA TLV WT PEL/TWA Corundum 1302-44-56 65-85 15mg/m 3 

## (Total) 10mg/m 3 

## (Total) 5mg/m 3 

## (Resp) 3mg/m 3 

## (Resp) Aluminum Silicate 1302-76-7 15-35 15mg/m 3 

## (Total) 10mg/m 3 

## (Total) 5mg/m 3 

## (Resp) 3mg/m 3 

## (Resp) 

# 9.0 Physical and Chemical Properties APPEARANCE: Grayish brown to black free-flowing granules ODOR: None FLASH POINT: N/A This material does not give a flash point by conventional methods. STABILITY: Stable SPECIFIC GRAVITY: 3.45–3.55 PH: Not applicable VAPOR PRESSURE @ 25 ̊C: Not applicable VISCOSITY: Not applicable SOLUBILITY IN WATER: Nonsoluble BOILING POINT: Not applicable 

# 10. Stability and Reliability Normally stable as defined in NFPA 704-12 (4-3.1) 

# 11. Toxicological Information SEE SECTION 3 LC50 Not available LD50 Not available 

# 12. Ecological Information Not determined 

# 13. Disposal Conditions Dispose of according to local, state/provincial, and federal requirements. 

# 14. Transportation Information 14.1 U.S. Department of Transportation Non-regulated 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-regulated 

# 15. U.S. Regulatory Information (Selected Regulations) SARA TITLE III Section 302: None Section 312: None Section 313: None Toxic Substance Control Act (TSCA): N/A CERCLA Reportable Quantity: NoneClean Air AmendmentsHazardous Air Pollutants: None California State Proposition 65: N/A 

# 16. Other Information The OSHA Hazard Communication Standard 29CFR 1910.1200 requires that the information contained on these sheets be made available to your workers. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. 

# Disclaimer Seller makes no warranty, expressed or implied, concerning the product or the merchantability or fitness thereof for any purpose, except that the product conforms to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed.In no event shall seller be liable for incidental or consequential damages, whether buyer’s claim is based on contract, breach of warranty, negligence or otherwise. ISSUE DATE: 1-SEPTEMBER-06



# Tel: 479.782.2001 Toll Free: 800.643.2149 Fax: 479.782.9984 www.proppants.saint-gobain.com 5300 Gerber Road Fort Smith, AR 72904

## Received 7/17/98 

# 909 580 658 3223 AMERICAN 

## ENERGY Page 11 

# JUL11 45AM F-RUM 

## LRINM-N IbLH INC IU 

# 1l5bb4 Ij.11 

## 125 

# NFPAkEALTH NFPA 

## FLAMMABILITY NFPA 

## REAtTIVITY ...PCIF.IC HAZARD SECTION IDENTIFICATION COMPANY NAME


# ........... PLAINSMAN 

# TECHNOLOGY 

# INC P.O BOX 

# 57 MARLOW OK 

# 755 4O658-6O EMEP.SENCY 

## PHONE 

# NUMBER DOMESTIC/INTERNATIONAL 

# 4Q5282-5iO EFFECTIVE 

# DATE........ Dc.mber 

# 29 1993 

## REVISED DATE


# ......... N/A 

## CHEMICAL NAME 

# Amir TRADE NAME 

# SSA125 CHEMICAL FA1ILY 

# .... N/A


## SECTION II 

## COMPONENTS HAZARDOUS COMPONENTS HAZAFDOUS PEL/TLV 

# Mthano1 TWA 200 STEL 

# 676i 2O ACGIH TWA 200 StEL 

# 2O OSHA
SECTION III 

## PHYSICAL DATA BOILING 

# PointF .FREEZIN..PJINT 

# F..--12F

VOLATILITY/VOL% 

# 708O MELTING POINT NA 

## VAPOR PRESSURE 

# mm 

# Hop N/A 

## VAPOR DENSITY 

# Aj.l N/A 

# S0LUILITY IN 

## H20 CocnpItejy 

# so1ubI APPEARANCE/ODOR 

# Co1or1e viCCus lould 

# mId odor SPFflIFIC 

## GRAViTy 

# H2C1 

# 0.9 EVAPORATION RATE N/A PH 

# DENSITY 

# S.OStb/1
SECTION IV 

## FIRE AND EXPLOSION HAZARD DATA FLASH POINT II9CJF 

# TCC LOWER FLAME LIMIT based on nitharioi 

# HIHER FLAME LIMIT on 

# mthôj EXTINGUISH MEDIA 

# Us 

# foc dry 

# chnic1 CD2 

# wterfo or FOR 

## FIRE Do not 

## enter fire 

## area 

# aithout.DrDQr 

# rotcve equofm2nt ineludi 

## NIOSH/MSHA 

# aporovd 

# ifcontind brthinQ 

# Dratu Cool 

# xood cortirrs with water 

# Drav.Avojd.vDor

2/1ô/1997 1--
KEY-H EC-1 -001501

## Received 7/17/98 

# 910 580 658 3223 AMERICAN 

## ENERGY Page 12 

## JUL171998 094EAM FROM PLAINSMPN 

# TECH INC TO 

# 19156872542 P.12 

## SSA-125 UNUSUAL FIR.E 

## HAZARD..... Material is 

## Combustible Vapors are heavier thar and may travel 

# .lor orourd 

# to ignition 

## source arid 

## flash 

# back Never use ae1cino 

# or 

# cu torch on 

## or near 

# drums even 

## when 

# empty Explosin may 

# result SECTION HEALTH HAZARD DATA ROUTES OF 

## ENTRY INHALATION 

# EYES 

# SKIN INGESTION Yes 

## HEALTH HAZARDS



# ... 

# .... N/A 

# NTP IARC 

# MONOGRAPHS OSHA REGULATED No Not 

## established N/sZ 

## INHALATION Inhalation of hiQh levels of 

## vaoors or 

## mists may cause 

## liohtheadedness 

# dizzinss headaches or 

## urtconscaousress 

# EYES Eye contact 

## may 

# cus9 irritation 

# redr.e SKIN Prolonoed or 

## repeated contact 

## with skin may Ca irritation or 

# tN3ETIJN May be harmful if 

## rrge5ted 

# EYES Flush eyes 

## immediately with 

## laroe 

# amours water for at least 15 

# minutes Call 

# phvjcian irritation 

# persists INHALATION Remove to fresh 

# air If 

## labored 

# breathjn continues contact 

## physician 

# SKIN Remove contaminated clothes 

# .Wah skin thorouthly with mild soao.and waters 

## Launoer 

# clotho before 

# reuse INGESTION DO NOT induce .vomitjno If 

# conscious drink 

# are amounts of 

# catr and 

## contact physician
SECTION VI 

## REACTIVITY flATA 

## CHEMICAL 

# STAILIYY...... CONDITIONS TO 

## AVOID INCOMPATIBLE MATERIALS.. DECOMPOSrr ION 

## PRODUCTS.. HAZARDOUS POLYMERIZATION POLYMERIZATION 

# AVOID....
SECTION VII 

## SPILL OR 

## LEAK PROCEDURE CARCINOGENICITY
THRESHOLD LIMIT 

# VALUE... SYMPTOMS OVER EXPOSURE 

# EFFECTS

FIRST AID 

# RQCEDjRE5

Stable 

# Oidjzrg heat sparks or ooeri 

# .f1am Oxidzers heat sparks or 

## bpeh..flame Carbon 

# monoxide 

# oides of niitrcôen hJill 

# OCCUI None

12/1 1997

KEY-H EC-1 -001502

## Received 7/17/98 

# 910 580 658 3223 AMERICAN 

## ENERGY Page 13 

## JUL171998 0946AM FROM PL1INSMAN 

# TECH INC TO 

## 19156872542-- P.13



## 12/16/1997 Don 

# aoproDrite brotctioe clothincj 

# nd resoirtory orotetion orior to entei-incj 

## Sp.jl1fiEk 

# 1iirte ioritior 

# soureg 

# rth area uüwind -f 

## rJossible 

## Shut off leak if it 

## caribe done 

# safeiv Di .e 

## ard 

## oumo large 

# siils into 

## salvaoe 

# Containers Soak 

## residue and 

## sma11oiuis.tii.th absorbent 

# clay sand or dirt and 

## riace 

# sg.iye containers RC 

# portable cuantity is 

# ceded rØort to 

## NationaL 

# spil Resporse Office 

# 18004249802 Also in 

## .iurisdictions spills or leaks of any 

## hazardous materialE are 

# reportableçrs1t local lead 

# arcies for 

## further 

# formation Cantilnue tO 

## observe orecaut 

# on Reevaluation of the 

## oroduct 

# maybe reauired by the 

## user the time of 

# disDosal 

# sincthe oroduct 

# uses trnformations mixtures arid 

## prO.csses may 

## chanos the 

# clasifjcatjop to 

# norhaardthis or 

## hazardQLs 

# or reasons 

## other 

# than or in 

# ddition to 

## DtOdJ.t 

# characterjstj DisDoe ofail waste and/or containers ir 

## accordance 

# ith federal stete anc local 

# reciultions Avoid jntialatjori 

## o1 

## vapors or 

# mists Do 

# no oct jr 

# eyes on skin or on 

# clothing Keep.ccntairer closed when reot 

### in 

# use Wear suitablep.rotction 

# fo eyes aflC 

## skin when 

## hardlinô. Use 

# wih adouate ventilat0n Avoid contact with 

# ojdjcrs 9tore jr 

# area 

# Storei 

# ol dry 

# area Control jonition 

# ourc keep 

# way from 

# heat soark and ooen 

# flame -1 FOR 

## SPILL

WASTE DISPOSAL 

# METHOD

HANDLING AND 

## STORAGE

PRECAUTIONARY 

# MEASURES None


## SECTION VIII 

## SPECIAL PROTECTION RESPIRATORY PROTECTION.. Use 

# resiratory 

# devica arid 

## other ersonai 

# orotectve eauiomert reouircci by 

# OSHA29CFR110 VENTILATION 

# Th use of 

## mechanical ventilation is 

# ro-rimeded whenever this 

## oroduct in 

## confined 

# soace is 

## heated above ambient tecnberatLI.res 

## or is 

## aoi 

# tated tJhere erqineerirtci 

## controls are not 

# feasible assure use is in 

## an 

## area where there 

# is.rtural air 

# movement PROTECTIVE GLOVES Neorrenc or 

## rubber ciloves EYE 

## PROTECTiON OTHER PROTECTIVE EQUIPIIENT


## SECTION IX 

## SPECIAL PRECAUTIONS HAZARD CLASS 

## Flammable 

# Liujd DOT 

## SHIPPING NAME 

## Flammable 

# lioulds n.o.s. Contains Methanol UN1993 

# 3III REPORTABLE QUANTITY 

# RQ N/A UN 

## NUMBER 1953 NA

KEY-H EC-1 -001503

## Received 7/17/98 

# 911 580 658 3223 

## -AMERICAN ENERGY Page 14 

# SSA125 P4CKAeIN SIZE oallor 

## drums
Sara 

# Tit1 III 

# uorfund Amerdrnents 

## ReauthorizatjflAct5cf..1986 

# Stior 302 311k 312



## Sctiori 302 

## Etrecne1v 

# Haardo Substances 

# 40CFR355 Th.s 

# orouct does not 

## cortain irredi.ents listed in 

## ADQertdi and 

# as.nxtreme1y Hazardous Subs 

# tarse



# St.ons 311 

# 312 Material 

## Safety Data Sheet 

# Rquirernert 

# 40CFR370 JL1P 

## hazard evaluation has ound this orodLLct 

## to be 

## hazardous. 

# ..Th roouct shuid be 

## reoorted under the foil minio 

## EPA 

## hazard 

# cateoories Immediate 

# acute health hazard 

# Deiave croriic health h-9zard 

## Fire 

# hazar _n/a_ Suddert 

# relea o-f 

## oressure hazard _r/a_ Reactive 

# haard Jrder Section 

# 311 submittal of 

# NSDSs or 

# iisto duct.names to local 

# emerecy piannirci 

# mmission state emerQency subnse 

# commnisin lccai tire 

## deoartment is 

# rajred aftei- 

## October 

# 17 .1989 

## for all 

## hazardous 

# substances

Section 

# 13 Lit of 

# Tcxi Cemjcals 

# 40CFR372 Th.js.oroduct 

## contains the



## liowino incredients 

# ith CAS and 

# rarae which 

# .oear on the List o-f 

## Toxic 

# Chemicals Methanol

DISCLAIMER OF 

## LIAEILlTv Plainsmar Techr.olooy 

# Lnc tarrants only title to the 

# odid rHis 

## WARRANTY IS IN 

## LIEU OF ALL 

## JTHER 

# WARRANTIES EXPRESS OR 

# ItPLIE WITH RESPECT TO 

## THE GOODS 

# SOLD 1NCLUDINs 

# UT NOT 

## LIMITED 

# TO THE IMPLIED THE 

## IMPLIED WARRANTIES OF 

# UTILITY MERCHANTABILITY OR 

## FITNESS FOR PARTICULAR 

# USE Plainsman 

# Thriolocy Inc not 

# warrart that the 

# Oodd or 

# he made threo-f by 

# th buyer ui11 not 

## infrinQe any i.flteilectLm 

## oropercv 

# rihts iricludinci 

## but not limited 

# to oatents 

# ny third 

# Party and that use of rnoods 

## sold 

# ii1 riot 

## aamace ary 

## subterranean formation tzjhich 

# oms -rto 

# contt with 

# oods

12/16/19c7 4--

TDTflL 

### P.14 

## KEY-H EC-1 -001504

# SAPJTROL Material Safety 

# Data Sheet 

# Product Superset
Section
Manufacturers 

# Name Telephone 

## Number Santrol 

# 281 431-0670 

### 2727 

## FM 521 

### Fresno 

## TX 77545 

## Date 06/02/97


## Section II 

# Emergency Assistance

For 

### emergency Assistance involving chemicals call 

## CHEMTREEC 

# 800 424-9300


## Section III 

# Hazardous Ingredients

Hazardous 

### components 

## CAS 

## OSHA PEL 

## ACGIH TLV 

## OTHER Methanol 67-56-1 

### 200 

## PPM 200 

## PPM Poiyoxyethylenenonylphenol ether 9016-45-9 

### none none 

## mmHg Temp Weight 

### Vaper Pressure 100.0 

## 70F 43 0.0 

## 68F 55 

## DOT Proper 

## Name Methyl Alcohol Solution 

## DOT Hazard 

### Class Dot Id 

## No UN1230 PGII Guide 

### 28



## Hazard Rating Scale Product 0-Minimal 3-Serious Health 1-Slight 4-Severe Fire 2-Moderate Reactivity Special 

## NONE

Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the 

### Emergency Planning and 

### Community Right-To-Know Act of 1986 and of 

### 40 

## CFR 372 

# CAS Chemical 

## Name by Weight 67-56-1 Methanol 

# 60

California 

# Safe Drinking Water 

## and Toxic Enforcement Act of 

# 1986 This product 

## may contain trace 

### amounts less than 

## loppm of Ethylene Oxide 

## CAS 75-21-8 and trace 

### amounts 

## up to 125 

## ppm of 

### 14-Dioxane 

# CAS 123-91-1

Page



## KEY-H EC-1 -001505

# SANTROL Material 

# Safety Data Sheet 

# Product Superset Section IV 

## Physical/Chemical Characteristics

Boiling Point 

## 148F Specific Gravity 

# H201 0.910 

### Vapor Pressure 

# mmHg 97 at 

## 20C Melting Point 

### N/A Vapor Density 

# Air1 1.1 Evaporation Rate Butyl 

## Acetate1 Solubility in 

### Water Complete 

### Appearance and 

### Odor Colorless liquid alcohol odor 

## Section Fire 

# and Explosion 

# Hazard Data

Flash Point 

## 58F 

# TCC Flammable Limits in air 

### Lower Upper 36.5 Extinguishing 

### Media Use water spray alcohol 

## foam CO2 or Dry 

### Chemical Do not use direct water stream Special Fire Fighting Procedures Fire Fighters should 

### wear self contained breathing apparatus 

### Use water spray to cool nearby containers 

### and structures exposed to fire Unusual Fire and Explosion 

### Hazards Extinguish all nearby sources of ignition This product 

### may burn with flame which is invisible in daylight 

## Section VI Reactivity 

## Data

Stability Stable Polymerization Will not occur Conditions to avoid 

### Heat sparks and open flames Materials to avoid Strong Oxidizers 

### aluminum zinc 

### Any metal that displaces 

### hydrogen certain plastics 

### and rubber 

### Hazardous decomposition products 

### May liberate carbon 

### monoxide carbon dioxide formaldehyde and unidentified 

### compounds in black 

## smoke 

## Section VII 

## Health 

# Hazard Data
Primary Routes of 

### exposure Swallowing skin or eye contact inhalation Signs 

### and symptoms of 

### exposure Inhalation Prolonged or repeated exposure or breathing very high concentrations 

## may cause headaches nausea vomiting dizziness and visual disturbances 

### Eye contact Vapors 

### may irritate the 

### eyes Liquid 

### and mists 

### may severely irritate or 

### damage the 

### eyes Skin contact Contact with skin 

### may cause severe irritation Prolonged contact 

### may cause dermatitis 

### Swallowed Swallowing large quantities causes 

### headaches nausea vomiting blindness 

### damage to pancreas and perhaps death Chronic effects of 

### exposure Prolonged or repeated exposure 

### may result in 

## CNS damage blindness 

### damage
to pancreas and perhaps death Medical conditions generally aggravated by 

### exposure None known Emergency and First Aid Procedures Inhalation 

## Remove to fresh air Give artificial respiration if not breathing Get immediate medical attention 

### Eye contact Immediately flush eyes with running water for at least 15 minutes Get immediate medical attention Skin contact Immediately 

### was skin with lots of soap and water 

## Remove contaminated clothing and 

### shoes and 

### wash before reuse Get medical attention if irritation persists after 

### washing Swallowed If conscious immediately induce vomiting by giving glasses of 

### warm water and sticking finger 

### down the throat Get immediate medical attention After patient has 

### vomited give milk water or solution of sodium bicarbonate 

### ltsp/qt Do not give anything to an unconscious or convulsing 

### person Page



## KEY-H EC-1 -001506

# SANTROL Material Safety 

# Data Sheet 

# Product Superset
Section VIII 

## Precautions for 

## Safe Handling 

# and 

# Use
Steps to 

### Be Taken in 

### Case Material is Spilled or 

### Released Wear protective equipment including rubber boots rubber gloves rubber 

### apron chemical 

### goggles and respiratory protection Extinguish all ignition sources and ensure that all handling equipment is electrically 

### grounded For small spills or drips 

## mop or wipe up and dispose of in 

## DOT approved waste containers For large spills contain by diking with soil or other absorbent material and then 

### pump into 

## DOT approved waste containers or absorb with absorbent material and place in 

## DOT approved waste containers 

### Keep out of 

### sewers storm drains surface 

### waters and soil 

### Comply with all applicable Governmental regulations on spill reporting and handling and disposal of 

### waste
Precautions to 

### Be Taken in Handling and Storing 

### Keep away from heat sparks and flames Store in cool dry place Vent container frequently and 

### more often in 

## warm weather to release pressure Electrically ground all equipment 

### when handling this product and use only non-sparking tools 

### Keep container tightly closed 

### when not in 

### use Do not get in 

### eyes on skin or on clothing Repair 

### and Maintenance Precautions 

### Do not cut grind 

### weld or near this container
Other Precautions Containers even those that have 

### been emptied will retain product residue and 

### vapors Always 

### obey hazard warnings 

### and handle empty containers as if they 

### were full 

## Section IX 

## Control 

# Measures
Respiratory Protection 

### NIOSH-Approved canister respirator in the absence of adequate environmental contros at the point of 

### use Ventilation Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the 

## PEL Eye Protection Chemical Goggles Protective Clothing Long-sleeved shirt full length trousers safety 

### shoes rubber gloves and rubber 

### apron Other Precautions 

### An eyewash and safety 

### shower should be nearby and ready for 

### use 

## Section Toxicity 

## Data

Methanol Oral Rat LD50 5.628 g/kg 

### Dermal Rabbit LD50 20 g/kg Inhalation Rat LC50 

### 64000 ppm/4h Polyoxyethylenenonlyphenol ether Oral Rat LD50 g/kg 

### Dermal Rabbit LD50 g/kg

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for particular purpose with respect tot he product or information provided herein

All information appearing herein is based upon data obtained from recognized technical sources While the information is believed to be accurate Santrol makes no representations as to its accuracy or sufficiency Conditions of use are beyond Santrols control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes arid they assume all risks of their use of or reliance upon information contained herein This information relates only to the product designated herein and does not relate to its use in combination with any other matenal or in any other process Page



## KEY-H EC-1 -001507

# SANTROL Material Safety Data Sheet Product: Superset W

Page 1 

# Section I Manufacturer's Name Telephone Number Santrol (281) 431-0670 2727 FM 521 Fresno, TX 77545 

# Date 10/10/02 

# Section II - Emergency Assistance For emergency Assistance involving chemicals call - CHEMTREC (800) 424-9300 

# Section III - Hazardous Ingredients Hazardous components CAS # OSHA PEL ACGIH TLV OTHER 50 % Methanol 67-56-1 200 PPM 200 PPM 50 % Poly(oxyethylene)nonylphenol ether 9016-45-9 none none Vapor Pressure: Methanol –100mm Hg @ 70 ° F

Poly(oxyethylene)nonyphenol ether – 0 mm Hg @ 68 ° F DOT Proper Name: Methyl Alcohol Solution DOT Hazard Class: 3 Flammable Liquid Dot Id No: UN1230, PGII, (BP>95 ° F,FP,73 ° F) Guide 131 (2000 Emergency Response Guidebook) 

# Hazard Rating Scale: 2 Product: 0-Minimal 3-Serious Health: 2 1-Slight 4-Severe Fire: 3 2-Moderate Reactivity: 0 Special: NONE 

# Canada Hazardous Products Act Ingredients Disclosure List C hemical Name: % Item Number French Version Cas# Methyl Alcohol 50% 1012 183 67-56-11 Class B- Flammable liquid having a flash point between 0 ° and 100 ° F 

# Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: CAS# Chemical Name % by Weight 67-56-1 Methanol <60

# SANTROL Material Safety Data Sheet Product: Superset W

Page 2 

# California "Safe Drinking Water and Toxic Enforcement Act of 1986" This product may contain trace amounts (less than 10ppm) of Ethylene Oxide (CAS # 75-21-8), and trace amounts (up to 125 ppm) of 1,4-Dioxane (CAS # 123-91-1). 

# Section IV - Physical/Chemical Characteristics Boiling Point: 148 o 

# F Specific Gravity (H 2 

# O=1): 0.910 Vapor Pressure (mmHg): 97 at 20 o 

# C Melting Point: N/A Vapor Density (Air=1): 1.1 Evaporation Rate (Butyl Acetate=1): >1 Solubility in Water: Complete Appearance and Odor: Colorless liquid, alcohol odor 

# Section V - Fire and Explosion Hazard Data Flash Point: 58 o 

# F (TCC) Flammable Limits in air, % : Lower: 6 Upper: 36.5 Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. Do not use direct water stream Special Fire Fighting Procedures:

Fire Fighters should wear self contained breathing apparatus. Use water spray to cool nearby containers and structures exposed to fire. Unusual Fire and Explosion Hazards:

Extinguish all nearby sources of ignition. This product may burn with a flame which is invisible in daylight. 

# Section VI - Reactivity Data Stability: Stable Polymerization:Will not occur. Conditions to avoid: Heat, sparks and open flames. Materials to avoid: Strong Oxidizers, aluminum, zinc. Any metal that displaces hydrogen; certain plastics and rubber. Hazardous decomposition products: May liberate carbon monoxide, carbon dioxide, formaldehyde, and unidentified compounds in black smoke. 

# Section VII - Health Hazard Data Primary Routes of exposure: Swallowing, skin or eye contact, inhalation. Signs and symptoms of exposure: Inhalation: Prolonged or repeated exposure or breathing very high concentrations may cause

headaches, nausea, vomiting, dizziness and visual disturbances. Eye contact: Vapors may irritate the eyes. Liquid and mists may severely irritate or damage the eyes. Skin contact: Contact with skin may cause severe irritation. Prolonged contact may cause dermatitis Swallowed: Swallowing large quantities causes headaches, nausea, vomiting, blindness, damage to

pancreas and perhaps death. Chronic effects of exposure: Prolonged or repeated exposure may result in CNS damage, blindness, damage to pancreas and perhaps death. Medical conditions generally aggravated by exposure: None known. Emergency and First Aid Procedures: Inhalation: Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical

attention. Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

# SANTROL Material Safety Data Sheet Product: Superset W

Page 3 Skin contact: Immediately was skin with lots of soap and water. Remove contaminated clothing and shoes

and wash before reuse. Get medical attention if irritation persists after washing. Swallowed: If conscious, immediately induce vomiting by giving 2 glasses of warm water and sticking

finger down the throat. Get immediate medical attention. After patient has vomited, give milk, water or solution of sodium bicarbonate (1tsp/qt). Do not give anything to an unconscious or convulsing person. 

# Section VIII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Spilled or Released: Wear protective equipment including rubber boots, rubber gloves, rubber apron, chemical goggles, and respiratory protection. Extinguish all ignition sources and ensure that all handling equipment is electrically grounded. For small spills or drips, mop or wipe up and dispose of in DOT approved waste containers. For large spills, contain by diking with soil or other absorbent material and then pump into DOT approved waste containers or absorb with absorbent material and place in DOT approved waste containers. Keep out of sewers, storm drains, surface waters, and soil. Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste. Precautions to Be Taken in Handling and Storing: Keep away from heat, sparks, and flames. Store in a cool, dry place. Vent container frequently, and more often in warm weather, to release pressure. Electrically ground all equipment when handling this product and use only non-sparking tools. Keep container tightly closed when not in use. Do not get in eyes, on skin, or on clothing. Repair and Maintenance Precautions: Do not cut, grind, weld, or near this container. Other Precautions: Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. 

# Section IX - Control Measures Respiratory Protection: NIOSH-Approved canister respirator in the absence of adequate environmental controls at the point of use. Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the

PEL. Eye Protection: Chemical Goggles Protective Clothing: Long-sleeved shirt, full length trousers, safety shoes, rubber gloves, and rubber apron. Other Precautions: An eyewash and a safety shower should be nearby and ready for use. 

# Section X - Toxicity Data Methanol Oral: Rat LD 50



# - 5.628 g/kg Dermal: Rabbit LD 50



# - 20 g/kg Inhalation: Rat LC 50



# - 64,000 ppm/4h Poly(oxyethylene)nonlyphenol ether Oral: Rat LD 50



# - < 5 g/kg Dermal: Rabbit LD 50



# - > 3 g/kg Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided herein.

# SANTROL Material Safety Data Sheet Product: Superset W

Page 4 All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.Material Safet Dale icct 

# ThLwie

DATE 

# PPED.71153 REVISION 

## DATE 04/19/04 Chcmplcx L.C 

## EMERGENCY NUUBER...800-633-8253 Snyder 

## TX 79549 

## PRODUCT NUMBER 00904 

## 325 573-7298



## SECTION IDENTIFICATION 

## PRODUCT 

# NAME Toluene 

## SYNONYMS- Methytbenzene 

## CHEMICAL FAMILY- Aromatic Hydrocarbons 

## CAS NUMBER- 108-88-3 

## PRODUCT USE- Coatings Solvent for resins industrial applications Intermediate Manufacture of ofganic products Textile industry Manufacture of soaps and detergents 

## SECTION II 

# HAZARDOUS INGREDIENTS HAZ INGREDIENT 

## PERCENT CASMIMBER PEL TOLUENE 95 100 108-88-3 

## TWA 100pprn


## SECTION III 

## PHYSICAL 

# DATA ApPEARANCE- Coloiless liquid 

# ODOR Benzene-Iike 

## Strong BOILING 

## POINT 110.6C 

## 231.1F FLASHPOINT CLOSED 

## CUP 4.4C 

## 39.9F OPEN 

## CUP 12.78C 

# 55F Cleveland 

## VAPOR DENSITY 

# AIR1 3.14 

## VAPOR PRESSURE 2t9 

# mm of 

### Hg 

# @20C EVAPORATIVE 

## RATE Not Available 

### SPECIFIC 

## GRAVITY 

## WATER1- 0.87 

## pH 

# 1% SOLNIWATER Not available 

### SOLUBILITY Easy soluble in methanol diethyl ether Soluble in n-octanol Very slightly soluble in cold water hot water 

# WI 7.26 per gallon



### Page of5



## KEY-H EC-1 -001509Mateiial Safety Data Sheet 

# Toluene

SECTION IV 

## FIRE 

# AND EXPLOSION 

# DATA FLASHPOINT CLOSED 

## CUP 4.4C 39.9SF 

## OPEN 

## CUP 12.78C 

# 55F Cleveland 

## FLAMMABLE LIMITS 

## LOWER 1.2% 

## UPPER 7.1% 

## FLAMMABLE 

## HAZARDS Highly flammable in presence of open flames and sparks Slightly flammable to flammable in presence of heat of oddizing matenals of combustible mateæa$s Very slightly to slightly flammable in presence of reducing materials 

### EXTINGUISHING 

## MEDIA Flammable liquid soluble or dispersed in water 

### FIRE FIGHTING 

## PROCEDURES SMALL FiRE Use 

## DRY chemicals 

## C02 water spray or alcohol 

### foam 

## LARGE 

# RRE Use alcohol 

### foam water spray or fog Cool containing vessels with waler jet in order to prevent pressure build-up autoignition or explosion 

## EXPLOSION 

## HAZARDS Vapor 

### may travel considerable distance to source of ignition and flash 

### back


## SECTION 

# REACTWITY DATA
STABILiTY This product is stable 

## CORROSIVflY Non-corrosive in presence of glass 

### REACTIVITY Highly reactive with oxidizing agents organic materials 

## SECTION VI 

# HEALTH HAZARD 

# DATA ROUTE OF 

## ENTRY ingestion skin contact inhalation 

## ACUTE EFFECT 

## ON 

# HUMANS Very dangerous in case of skin contact Irritant perrneator of eye contact Irritant of ingestion of Inhalation Very slightly to slightly dangerous in case of skin contact sensitizer 

## CHRONIC EFFECTS 

## ON 

# HUMANS

.. 

### The substance is toxic to blood kidneys the nervous 

### system liver Inhalation of vapors 

### may cause dizziness an irregular heartbeat narcosis nausea or asphyxiation 

## SECTiON VI 

## FIRST AID INHALATION SLIGHT INHAL.4 

## T1ON Allow the victim to rest in well ventilated area 

### Seek immediate medical attention 

## HAZARD INHALATION Evacuate the victim to safe area as soon as possible Loosen tight clothing such as

collar tie bell or waist 

### band If breathing is difficult administer 

### oxygen If the victim is not breathing perform mouth-to-mouth resuscitation 

### Seek medical attention



### Page of



## KEY-H EC-1 -001510Material Safcty Data Sheif 

# Toluene
WARNING It 

### may be dangerous to the person providing aid to give mouth-to-mouth resuscitation 

### when the inhaled material is toxic infectious or corrosive 

## INGESTION 

## SUGHT INGESTiON 

# Mow the victim to rest in well ventilated area 

### Seek immediate medical attention 

## HAZARDOUS INGESTiON Do 

## NOT induce vomiting 

### Examine the lips and mouth to ascertain whether the tissues are 

### damaged possible indication that the toxic material 

### was ingested the absence of such signs 

### however is not conclusive Loosen tight clothing such as collar tie belt or waist 

### band If the victim is not breathing perform mouth-to-mouth resuscitation 

### Seek medical attention 

### EYE 

## CONTACT- Check for and remove any contact lenses Immediately flush eyes with running water for at least 15 minutes keeping eyelids 

### open Cold water 

## may be 

### used Do 

## NOT use an eye ointment 

### Seek medical attention 

### SKIN 

## CONTACT If the chemical got onto the dothed portion of the 

### body remove the contaminated clothes as quickly as possible protecting your 

### own hands and 

### body Place the victim under deluge 

### shower If the chemical touches the victims exposed skin such as the 

### hands Gently and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be careful to clean folds crevices creases and groin Cover the irritated skin with an emollient If imtation persists seek medical attention 

## Wash contaminated clothing before reusing If the chemical got onto the clothed portion of the 

### body remove the contaminated clothes as quickly as possible protecting your 

### own hands and 

### body Place the victim under deluge 

### shower If the chemical touches the victims exposed skin such as the 

### hands Gently and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be careful to 

### dean folds crevices creases and groin Cover the imtated skin with an emollient If irritation persists seek medical attention 

## Wash contaminated clothing before reusing


## SECTION VII 

## SPILL 

## STORAGE 

# AND DISPOSAL 

# DATA
SPILL 

## SMALL SPILL Absorb with an inert material and put the spilled material in an appropriate waste disposal 

## LARGE SPILL Keep away from heat 

### Keep away from sources of ignition Stop leak if without risk Absorb with 

## DRY earth sand or other non-combustible material 

## DO 

## NOT touch spilled material Prevent entry into sewers basements or confined areas dike if 

### needed Eliminate
all sources of ignition 

## WASTE DISPOSAL- Whatever cannot be saved for recovery or recyding should be 

### managed in an appropriate and approved waste disposal facility Processing use or



### Page of5



## KEY-HEC-1 -001511Material Safety Data Shea 

# Toluene

contamination of this product 

### may change the waste 

### management options State and local disposal regulations 

### may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements 

## HANDLING Keep locked 

## up Keep container thy 

### Keep away from heat 

### Keep away from sources of ignition Ground all equipment containing material 

### Do not ingest 

### Do not breathe gaslfumes/ vapor/spray Never add water to this product In case of insufficient ventilation 

### wear suitable respiratojy equipment If ingested seek medical advice immediately and 

### show the container or the label Avoid contact with skin and 

### eyes Keep away from iflcOmpatibjes such as oxidizing agents reducing agents organic materials acids alkalis 

## STORAGE Flammable materials should be stored in separate safety storage cabinet or 

### room Keep away from heat 

### Keep away from sources of ignition 

### Keep container tightly closed 

### Keep in cool well-ventilated place Ground all equipment containing material refrigerated 

### room would be preferable for materials with flash point lower than 

### 37.8C 

# 100F
SECTION VIII 

## PROTECTIVE CLOTHiNG RESPIRATORY PROTECTION Use MSHA/NlOSI.f approved resp1rator- or equivalent 

## PROTECTIVE CLOTH INGIEQUIPMENT Goggles lab coat apron gloves 

## SECTION IX 

## TRANSPORTATION 

# DATA PROPER SHIPPING 

## NAME- Toluene 

## HAZARD CLASS

## UN 

# NUMBER UN 1294 

## PACKAGING 

# GROUP DOT SHIPPING Toluene 

## UN 1294 

## PG II 

## SECTiON 

# OTHER REGULATORy INFORMATION TSCA STATUS- MI components of this product are hsted on the 

## TSCA inventory 

## NFPA 

## HEALTH NFPA FLAMMABILITY NFPA REAc-rIviry



### Page of



## KEY-H EC-1 -001512MdeiiaI Safety Data Sheet 

# To uene
SECTION XI 

## ADDITIONAL INFORMATION PREPARED BY Edward \Tinson 

# EMERGENCY RESPONSE 

# NUMBER 800-633-8253

PageS of



## KEY-H EC-1 -001513International 

### Chemical Safety 

### Cards 

## WHO/IPCS/ILO Page of


# International 

# Chemical Safety 

# Cards 

# TOLUENE ICSC 0078 

# TOUJ1NE Methylbe rizene Toluol 

### C6H5CITI3/C7H8 Molecular 

## mass 92.1 

## CAS 108-88-3 

## RTECS XS5250000 ICSC 0078 

# UN 1294 

## EC 601-021-00-3 

# ACUTE 

# HAZARDS PIREVENTION FIRE 

# FIGHTING FIRE Highly flammable 

## NO open flames 

## NO sparks and 

### Powder 

## AFFF foam carbon 

## NO smoking dioxide Vapour/air mixtures are Closed system ventilation In case of fire keep 

### drums etc explosive explosion-proof electrical cool by spraying with water equipment and lighting Prevent 

# EXPLOSiON build-up of electrostatic charges 

## e.g by grounding 

### Do 

## NOT
use compressed air for filling discharging or handling 

### STRICT 

## HYGIENE AVOLI 

# EXPOSURE EXPOSURE OF 

# PREGNANT 

# WOMEN
Dizziness Drowsiness Ventilation local exhaust or Fresh air rest Artificial 

## INHALATION Headache Nausea breathing protection respiration if indicated Refer for Unconsciousness medical attention Dry skin Redness Protective gloves 

### Remove contaminated clothes 

### SKIN Rinse and then wash skin with water and soap Refer for medical attention Redness Pain Safety goggles or face shield First rinse with plenty of water 

## EYES for several minutes 

### remove contact lenses if easily possible then take to doctor Abdominal pain Burning 

### Do not eat drink or smoke Rinse 

### mouth Give slurry of 

## INGESTION sensation further see during 

### work activated charcoal in water to Inhalation drink 

### Do 

## NOT induce vomiting Refer for medical attention 

# SPILLAGE DISPOSAL 

# STORAGE PACKAGING

Collect leaking liquid in sealable Fireproof Separated from strong containers Absorb remaining liquid in oxidants symbol sand or inert absorbent and remove to 

### Xn symbol

http//www2.hazard.com/msds/mf/cards/fi1e/0078.htmIl 

### 9/27/2007



## KEY-H EC-1 -001514International 

### Chemical Safety 

### Cards 

## WHO/IPCS/ILO Page of

safe place 

### Do 

## NOT wash away into 11-20 sewer extra personal protection self- 

## 2- 16-25-29-33 contained breathing apparatus 

## UN Hazard Class 

## UN Packing 

### Group II 

### SEE 

## IMPORTANT INFORMATION ON BACK 

# CC p078 Prepared in the context of cooperation between the International Programme on Chemical Safety the Commission of the European Communities IPCS CEC 1993 

# International 

# Chemical Safety 

# Cards TOLUENE ICSC 0078 

## PHYSICAL 

## STATE APPEARANCE ROUTES OF EXPOSURE COLOURLESS LIQUID WITh The substance can be absorbed into the body by 

## CHARACTERISTIC 

# ODOUR inhalation through the skin and by ingestion 

## PHYSICAL 

## DANGERS INHALATION RISK The vapour is heavier than air and 

### may travel harmful contamination of the air can be along the ground distant ignition possible 

### As reached rather quickly on evaporation of this result of flow agitation 

### etc electrostatic substance at 

# 20C charges can be generated 

## EFFECTS 

## OF SHORT-TERM EXPOSURE CHEMICAL DANGERS The substance irritates the eyes and the Reacts violently with strong oxidants causing respiratory tract Exposure could cause central fire and explosion hazard nervous system depression Exposure at high levels 

### may result in cardiac dysrhythmia 

## OCCUPATIONAL EXPOSURE LIMITS unconsciousness and death 

# OELs TLV 50 

## ppm 188 mg/rn3 

### as 

# TWA skin 

## EFFECTS 

## OF LONG-TERM 

# OR ACGIH 1993-1994 

## REPEATED EXPOSURE Repeated or prolonged contact with skin 

### may cause dermatitis The substance 

### may have effects on the central nervous system resulting in decreased learning ability and psychological disorders Animal tests show that this substance possibly causes toxic effects upon 

### human reproduction

Boiling point 11 

## 1C Relative density of the vapour/air-mixture at Melting point 

### -95C 

## 20C air 1.06 

## PHYSICAL Relative density water 0.87 Flash point 

# 4C c.c.C 

## PROPERTIES Solubility in water none Auto-ignition temperature 

## 480C Vapour pressure kPa at 

# 20C 2.9 Explosive limits vol% in air 1.1-7.1 Relative vapour density air 3.2 Octanollwater partition coefficient as log 

## Pow 2.69 

## ENVIRONMENTAL DATA 

# NOTES Depending on the degree of exposure periodic medical examination is indicated Transport Emergency 

### Card TEC 

## R-3 

# NFPACodeH2 http//www2 .hazard.com/msds/mf/cards/file/0078.htrril 

### 9/27/2007



## KEY-H EC-1 -001515International 

### Chemical Safety 

### Cards 

## WHO/IPCS/ILO Page of



## ADDITIONAL 

## INFORMATION

II 

# ICSC 0078 

# TOLUENi IPCS.CEC 1993

Neither the 

## CEC or the IPCS nor any person acting on behalf of the 

## CEC or the IPCS is responsible 

## IMPORTANT for the use which might be 

### made of this information This card contains the collective views of the 

## LEGAL IPCS Peer Review Committee and 

### may not reflect in all cases all the detailed requirements included 

## NOTICE in national legislation on the subject The user should verily compliance of the cards with the relevant legislation in the country of use

http//www2.hazard.comjmsds/mf/cards/file/0078ht1111 

### 9/27/2007



## KEY-H EC-1 -0015162/ 

# -27OO 

# 357PM Material Safety 

# Data Sheet

NVPA Pr.tectvrCIotbIn 

### DOT

coeunonrrrade 

# RJAS cr Not applicable Syeony.is Not available ISCA TSCA 

## 8b Nventory All products listed

Clienilcal name Cationic Potyacrylamide emulsion Chemical formula Not appicable 

## CAS Moct3.iVe UDO1Pd Chemical family Aliphatic amide 

### Alhatic Supplier Molecular weight Not applicable 

## 5T7IO Manufacturer Cheniplex L.C P.O Box 1071 Material uses Not available 509 CR 137 Snyder Tx 79550 

### 915 573-7298 

# stionmrpiist4jdMesw1el Eye contact Check for and remove any contact lenses Do not use an eye ointment Seek medical attention Flush with plenty of water for at least 15 minutes occasionally lifting the upper and lower eyelds

Side contact After contact with skin wash rnmedately with plenty of water Gently and thoroufly wash the contiinated skin with runrng waterand non-abrasive Be particularly careful to clean folds crevices creases and groin Cover The initated skin with an emoflient If irritation persists seek medcal attention Wash contaminated clothing before reusing

Hazardous skin contact Wash with disinfectant soap and cover the contaminated skin with an anti-bacterial cream Seek mwnedlate medical attention

Slight inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention

Hazardous inhalation Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar lie bell or waistband If breathing is cfrfticuit administer oxygen If the victim is not breathing perform mouth-to-mouth resuscitation Seek medical attention

Slight ingestion Do not induce vomiting Examine the lips and mouth to ascertain whether the tissues are damaged possible indication that the toxic material was ingested the absence of such signs however is not conclusive Loosen tight clothing such as

coar tie belt or waistband If the victim is not breathing perform mouth-to-mouth resuscitation Seek immediate medical attention

Hazardous Ingestion Not available



## KEY-H EC-1 -0015653/ 

# 357PM 

# ithUtthM

Narie 

### CAS by Weight TLV/PEL LC5ILDs

Acrylamide 79-06-1 Trade secret liNk 0.01 

## ppm ORAL 

## LD5O Ac4e 124 mglkg 

## Rat DERMAL 

## LDSO Acute 400 mg/kg

Physical state OJId UC4UId Oior Slit appearance 

### pH 

# 1% sohi/ssatcr Basis TaSte NOt 2oiabis Odor threshold Not avalabte Color Whits Off-wtite
Volatility Not avalabie Melting poin Not avathe
Boiling point The lowest known value is 

### 360C 

## 680F MiieraI oil
Specific gravity Water Vapor density Not available Vapor pressure Not available Evaporation rate Not available Viscosity Not available 

### LogiL The product is much more soluble in oiL loiddly surface active 

## ant Not available
Critical temperature Not available Instability temperature Not available Conditions of instability Not available

Dispersion properties Is not dispersed in cold water hot water See sokibirity in methanol diethyl ether n-octanol

SoubilJty Easily soluble ii n-octanol Soluble in methanol diethyl ether InsoWe in cold water hot water



## KEY-H EC-1 -0015664/ 

# 27oo 

# 357PM

Tfe peodut Ii May be combustible at high temperature
AitO4gfl1thfl 

## tetzre Not adable
Flre egrsdadoe products These products are carbon oxides 

# CO C02 nthogen oxides 

# NO N02...

Flash points The lowest known value is 

### CLOSED 

## CUP 2.29C 

### 444.2F OPEN 

## CUP 193C 379.4F Cleveland Mineral

Flajisnable limits Not avadable

Fire extinguishing SMALL FIRE Use 

### DRY themical powder procedures 

### LARGE FIRE Use water spray fog or foam Do not use water jet



## 1.nbWty Highly flaniiithle in presence of oxizing materials

Remark Not available

Risks of explosion Risks of explosion of the product in presence of mechanical impact Not available Risks of explosion of the product wi presence of static chcharge Not avadable

Remark Not available

.1
Stability The product is stable Bawdous decomp products Not available
Degradabllity Not avaiable

Products of degradation 

### Possy hazardous short term degradation products are not likely However long term degradation products may arise
The products of degradation are less toxic than the product itself Remark Not avaiable

Corrosivity Non-corrosive in presence of glass

Remark Not avatable

Reactivity Reactive with oxidizing agents acids alkalis moisture

Remark May poiTienze on exposure to light The solid is stable at room temperature but may polymerize violently on rnefting Acrylatvide



## KEY-H EC-1 -001567

## -VJi-27OO 

# 357PM 5/

Routes eentry Dermal contact Eye contact Inhalation Ingestion vs IWb OJI 

### pp

Toxicity for anmials Acute oral toxicity 

## LD5O 124 mglkg Acrylanide Acute dermal toxicity 

## LD5O 400 mglkg 

## Rat Acrylamide

Remark Not available

Chronic elTecta on CARCINOGENIC 

### EFFECTS Classified A2 Suspected for 

### human by ACGIH Acrylamide hiasans

Remark Not available
Acute effects on hmnans Very hazardous ui case of ingestion Hazardous in case of skin contact irritant permeator of inhalation

Remark Material is corrosive to the mucous membranes Acrylanide

Waite disposal Whatever cannot be saved for recovery or recycling shoald be managed in an approriate and approved waste disposal acWty Processing use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regi4ations Dispose of container and unused contents accordance with federal state and local requiements

Not avaable

Storage Keep container dry Keep in cool place Ground all equçment containing material Keep container tightly closed Keep in cool well-ventilated place Highly toxic or infectious materials should be stored in separate locked safety storage cabinet or room

Precautions Keep locked up Keep away from heat Keep away from sources of ignition Empty contariers pose fire risk evaporate the residue under fume hood Ground all equipment containing material Do not ingest Do not breathe gas/fumes/ vapourspray Wear suitable protective clothing In case of insufficient ventllation wear 

### suile respiratory equipment if Egested seek medical advice mmediately and show the container or the label Avoid contact with skii and eyes Keep away from incompalibies such as oxidizing agents acids alkalis moisture
Small spin and leak Absorb with an inert material and put the spilled material in an appropriate waste disposal If necessary Neutralize the residue with dIlute solution of acetic acid
Large sp1 aiui leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Neutralize the residue with dilute solution of acetic acid Be careful that the product is not present at concentration level above TL.V Check TLV on the 

### MSDS and with local authorities

Protective Clothing Splash 

### goges Fill suit Vapor respirator Boots Gloves self contained breathing apparatus should be used to avoid
inhalation of the product Suggested protective clothing might not be sufficient consuL specialist 

### BEFORE handling thts producl



## KEY-H EC-1 -00156800 000P LI 

## 1.12700 

# 357PM

page 

## DOT Not 

### DOT contrclled material United States

Not 

### DOT regulated Rniark Not avaable Mai4tiee Not available transportedon
Remark Not avaable



### RCS No an HCSconfroled material 

### USA

Remark Not available 

### NFPA 

# wlAJy

SPECIFiC HAZARD
Federal and No products were found State Regulations



# -. References Not available

Validated by Chemplex on 6130/99 Verified by ChempleL
PrInted 6130/99 

# Emergency Response 

# 800 633-8253 HEALTH 

# L_ REACTMTY

Splash goggles Lati coat Vapor respirater Be sure to use an pcoved/cectifled respirator or equivalent Gloves 

# 4-

msbq 

# wI
fr 

## H.s as 

# iqm _d 

# 5Id as 

## Ailt 

# kÆ ..i4s ..d 

# av daha Wi 

# amvv as 

# esSa

KEY-H EC-1 -001569

# MATERIAL SAFETY DATA SHEET
Plexslick 961 NFPA 

# WF1

Product 

### And 

## Company Identification 

### SuDDher Manufacturer 

### Chemplex 

# LC Chemplax 

# IC P.O Box 1071 

## P.O Box 1071 506 

## CR 137 506 

## CR 137 

### Snyder TX 79550 UnIted States 

### Snyder 

## TX 79550 United States Telephone 

## Number 

## 325 573-7298 

### Telephone 

## Number 

## 325 573-7298 

## FAX Number 

## 325 573-3340 

## FAX Number 

## 325 573-3340
SuDolier 

### Emeroencv Contacts 

### Phone Number Manufacturer 

### Emeroencv Contacts 

### Phone Number 

## 800 633-8253 

## 800 633-8253

Issue 

### Date 01130/2003 Product 

## Name Plexslick 961 Chemical 

## Name Anionic Potyacrytarnide emulsion 

## CAS N.snber Not Established Chemical 

### Family Aliphatic anide 

## MSDS Number 211 Product/Material 

### Uses Friction reducer for water Composition/lnformnation 

## On Ingredients
Ingrecknt CAS Percent Of

Name Nwnber Total Weight PETROLEUM DISTILLATE 64742-47-8 20-30

Hazards Identification Primary 

## Routess Of Entry Dermal contact Eye contact Ingestion Inhalation Ingestion Hazards Hazardous in case at ingesbon Inhalation Hazards Hazardous ii case of skin contact irritant
First Aid 

### Measures
Check for and remove any contact lenses 

### Do not use an eye ointment Seek medical attention Flush with plenty of water for at least 15 minutes occasionally lifting the upper lower eyelids



### Paoe 

# f4

KEY-H EC-1 -001570

# MATERIAL SAFETY DATA SHEET
Plexslick 961

First Aid 

### Measures Continued

After contact with skin 

### wash immediately with plenty of water Gently and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be particularly careful to clean folds crevices creases and groin Cold water 

### may be 

### used Cover the irritated skin with an emollient If irritation persists seek medical attention 

### Wash contaminated clothing before reusing 

## HAZARD SKIN 

## CONTACT Wash with disinfectant soap and cover the contaminated sldn with an anti-bacterial 

### cream Seek immediate medical attention Inciestion 

## DO NOT induce vomiting Examine the 1ips and mouth to ascertain whether the tissues are 

### damaged possible indication that the toxic matenal 

### was ingested the absence of such signs however is not conclusive Loosen light clothing such as coflar tie belt or waistband It the vichm is not breathing perform mouth-to-moult resusictahon Seek immediate medical attention Inhalation Slight Inhalation Allow the victim to rest in well ventilated area Seek immediate medical attention Hazardous Inhalation Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie belt or waist 

### band If breathing is diflicult administer 

# oxen If the victim is not breathing perform mouth-to-mouth resuscitation Seek medical attention
Fire Fighting 

### Measures Flash Point 

## 200
Fire 

### And Explosion Hazards Flammable in presence of oxidizing materials Fire Fighting Instructions 

### SMALL FIRE Use 

## DRY chemicals 

### powder 

## LARGE FIRE Use water spray 

### foam or tog 

### Do not use water jet Product will 

### become very slippery 

### when contacted with water Accidental Release 

### Measures Small Spill and 

### Leak Absorb with an inert 

## DRY material and place in an appropriate waste disposal container Water will cause residue to 

### become etremey slippery Large Spill and 

### Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Be careful that the product is not present at concentration level above 

## TLV Check TLV on the 

## MSDS and with local authorities Handling 

## And Storage 

## Handii 

# Md Stoisqe Pietautions 

### Keep container dry keep in cool place Ground all equipment containing material 

### Keep container tightly closed 

### Keep at above 

## 35F Keep locked 

### up Keep away from heat 

### Keep away from sources of rgnion 

### Enipy containers pose fire risk evaporate the residue under fume 

### hood Ground all equipment containing material 

### Do not ingest 

### Do not breathe gas/fumes/vapor/spray 

### Wear suitable protective clothing in case of insufficient ventilation wear sutabie 

### iespaoiy eqthpment fl 

### vgested seec medical advice immec.ately and shriw the container OT the label Avoid contact with skin and eyes 

### Keep away from incompathles such as oxidizing agents and moisture



### Pane nf



## KEY-H EC-1 -001571

# MATERIAL SAFETY DATA
Plexslick 

## 961 

# SHEET

Protective Ciothino lPictoorams



# na

Exposure Controls/Personal Protection Eye/Face Protection 

### Spash gogges Skin Protection Apron/Lab coat gloves Respiratory Protection Vapor respirator 

### Be sure to use an approvedicered respirator or 

### eqwvaent Ingredients 

### Exposure Limits 

## PETROLEUM DISTILLATE



### ACGIH TLV-STEL 500 

### ppm Notice of Intended 

### Change ACGIH TLV-STEL 400 

## ppm Proposed ACGU-I 

## TLV-TWA 400 

## ppm Notice of Intended Changel 

### ACGIH TLV-TWA 200 

### ppm Proposed 

## OSHA PEL-TWA 400 ppm Physical 

### And Chemical Properties 

### Appearance 

## Tcavect vthit 

### Odor Hydrocarbon oil Chemical 

## Type Mixture Boiling Point 105 Specific 

## Grant .04 

# tec pH Factor Neutral 

### 10 Stability 

## And Reactivity Stability This product is stable Conditions 

### To Avoid Stability Reactive with oxidizing agents moisture 

## 11 Toxicological Information Skin Effects Hazardous in case of skin contact irritant Acute Oral Effects Hazardous in case of ingestion Jnaredientls Careinoaenicity 

## PETROLEUM DISTILLATE

Listed In 

### The 

## LRC Monographs


## Paae3nfd

KEY-H EC-1 -001572

# MATERIAL SAFETY DATA SHEET
Plexslick 961

12 Ecological Information 

### No Data Available.. 

## 13 Dbsposa% Considerations Whatever cannot be saved for recovery or recycling should be 

### managed in an appropriate and approved waste disposal facility Processing use or contamination of this product 

## may change the waste 

### management options State and local disposal regulations 

### may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements 

### 14 Transport Information Prooer ShiDnina 

## Name Not 

## DOT Regulated 

### 15 Regulatory Information 

### U.S Reaulatorv Information Not 

## DOT Regulated Inaredientls State Reaulaf ions 

## PETROLEUM DISTILLATE



## New Jersey Workplace Hazard 

## New Jersey Specia Hazard Pennsylvania Workplace Hazard Massachusetts Hazardous Substance 

## New York City I-lazardos Substance 

### 16 Other Information 

## NFPA Rating Health Fire Reactivtty Revision/Preiarer Information 

## MSDS Preparer 

### Dr Edward Vinson 

## MSDS Preparer 

### Phone 

## Number 915-573-7298 This 

## MSDS Supercedes Previous 

## MSDS Dated 07/15/2002 Disclaimer Although reasonable care has been taken in the preparation of this 

### document we extend no warranties and 

### make no rep esentati as to the accuracy or corncdeteness of the IntQftnaOn 

### cootas1 thereu 

# aM assu no responsibility regarding the suitablility of this information for the users intended purposes or for the consequences of its 

### use Each individual should 

### make determination as to the suitability of the information for their pallcular 

### purposess Chemplex L.C



### Paoa nf



## KEY-H EC-1 -001573

### PAGE of 

# MATERIAL SAFETY 

# DATA SHEET 06/02I20q PRINT 

### DATE 06/14/2005


## IDENTIFICATION 

## OF THE 

# PRODUCT AND THE 

# COMPANY 

# WFR-6 Supplier 

# PEACH 

# CREEK Box 30341 

# Edmond Oklahoma 73003 

# INFORMATION 

# PHONE 405-850-2520 

# EMERGENCY 

# PHONE 800-535-5053 

## _2 COMPOSITION/INFORMATION 

# ON INGREDIENTS

Identification of the preparation Cationic water-soluble polymer in emulsion



# HAZARDS IDENTIFICATION
Aqueous solutions or 

### powders that 

### become wet render surfaces extremely slippery



## FIRST AID 

# MEASURES

Inhalation 

### Move to fresh air
Skin 

### contact Wash off immediately with soap and plenty of water In case of persistent skin imtation consult physician Eye 

### contact Rinse thoroughly with plenty of water also under the eyelids In case of persistent eye irritation consult physician Ingestion The product is not considered toxic based on studies on laboratory animals 

# MEASURES

Suitable extinguishing 

## media Water water spray 

### foam carbon dioxide 

# C02 dry powder Special fire-fighting precautions Spills produce extremely slippery surfaces
Protective equipment for firefighters 

## No special protective equipment required



## ACCIDENTAL 

# RELEASE MEASURES

Personal precautions Environmental precautions 

## No special precautions required 

## Do not contaminate water



## KEY-H EC-1 -001584viscous liquid
millcy
aliphatic
g/1 for product series See Technical Bulletin for specific value
Does not flash Does not ignite
0.13 

## 20C

See Technical Bulletin
See Technical Bulletin 

# WFR-6 PAGE of REVISION 

### DATE 06/02/2005 PRINT 

### DATE 06114/2005

Methods for cleaning up 

### Do not flush with water 

## Dam up Soak up with inert absorbent material If liquid has been spilled in large quantities clean up promptly by scoop or 

### vacuum Keep in suitable and closed containers for disposal After cleaning flush 

### away traces with water 

## HANDLING 

# AND STORAGE
Handling Avoid contact with skin and eyes 

### When preparing the working solution ensure there is adequate ventilation 

## When using do not 

### smoke Storage Keep in dry cool place 

# 30C Keep away from heat and sources of ignition Freezing will affect the physical condition and 

### may damage the material 

## _8 

# EXPOSURE CONTROLS PERSONAL PROTECTION
Engineering controls Use local exhaust if misting occurs Natural ventilation is adequate in absence of mists Personal protection equipment

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment 

### Hand protection Rubber gloves Eye protection Safety glasses with side-shields 

## Do not wear contact lenses
Skin protection Chemical resistant apron or protective suit if splashing or contact with solution is likely Hygiene measures 

### Wash hands before breaks and at the end of 

### workday Handle in accordance with good industrial hygiene and safety practice 

## PHYSICAL 

# AND CHEMICAL PROPERTIES Form Color 

## Odor 

# pH

Flash point Autoignition temperature Vapour pressure 

# mm Hg
Bulk density
Water solubility



## KEY-H EC-1 -001585

## PAGE 3of5 

# WFR6 REVISION 

### DATE 06/02/2005 PRINT 

### DATE 06/14/2005

Viscosity 

## mPa See Technical Bulletin


## 10 STABILITY 

# AND REACTIVITY

Stability Product is stable 

### No hazardous polymerization will occur. Oxidizing agents 

### may cause exothermic reactions Hazardous decomposition Thermal decomposition 

### may produce hydrogen chloride gas nitrogen oxides 

# NOx products carbon oxides


## 11 

## TOXICOLOGICAL INFORMATION

cute toxicity 

### Oral LD5OIoral/rat 5000 mg/kg 

### Dermal The results of testing on rabbits showed this material to be non-toxic even at high dose levels Inhalation The product is not expected to be toxic by inhalation

Irritation

Skin 

## May cause skin irritation with suseptible persons 

## Eyes May cause eye irritation with susceptible persons
Sensitization The results of testing on guinea pigs showed this material to he non-sensitizing Chronic toxicity two-year feeding study on rats did not reveal adverse health effects one-year feeding study on dogs did not reveal adverse health effects Prolonged skin contact 

### may defat the skin and produce dermatitis


## ECOLOGICAL INFORMATION

Eco toxicity The effects of this product on aquatic organisms are rapidly and significantly mitigated by the presence of dissolved organic carbon in the aquatic environment

Fish LC5O/Danio rerio/96 

# hr 10 100 

### mg/L 

# OECD 203Based on the toxicity of the components using the Conventional 

## Method Algae Algal inhibition tests are not appropriate The flocculating characteristics of the product interfere directly in the test 

### medium preventing homogenous distribution which invalidates the test



## KEY-H EC-1 -001586

### PAGE 4of5 

# WFR-6 REVISION 

### DATE 06/0212005 PRINT 

### DATE 06/i 4I299J 

### Daphnia EC5O/Daplmia magna/48 

# hi 50 

### mg/L 

# OECD 202Based on the toxicity of the components using the Conventional 

## Method Environmental fate The product is rapidly eliminated from the aquatic 

### medium through irreversible adsorption onto suspended matter and dissolved organics Bioaccumulation loes not bioaccurnulate
Persistence degradability Not readily biodegradable 

## 13 DISPOSAL CONSIDERATIONS

Waste from residues 

### unused In accordance with federal state and local regulations 

### products Contaminated 

### packaging Rinse empty containers with water and use the rinse water to prepare the working solution Can be laridfihled or incinerated 

### when in compliance with local regulations


## L14 

# TRANSPORT IN 

# FORMATION 

# I_____________________________

Not regulated by 

# DOT
15 

# REGULATORY INFORMATION

All components of this product are on the 

### TSCA and 

### DSL inventories 

## RCRA status Not hazardous waste Hazardous waste 

## number Not applicable Reportable quantity 

## 40 CFR 

# 302 Not applicable Threshold planning quantity 

## 40 CFR 355 Not applicable
California Proposition 65 information The following statement is 

### made in order to comply with the California Safe Drinking Water 

### and Toxic Enforcement Act of 

## 1986 Thi product contains chemicals 

### known to the State of California to cause cancer residual Acrylamide



## KEY-H EC-1 -001587IPAGE 

## 5of5J 

# WFR-6 REVISION 

### DATE 06102120051 PRINT 

### DATE 06/1412005



### HMIS NFPA Ratings 

### HMIS NFPA

LHealth 

# LIP Flammability 

# jj Reactivity 

## 16 

# OTHER INFORMATION

Person to contact Regulatory Affairs Manager

The information provided in this Safety Data Sheet is correct to the best of our knowledge information and belief at the date of its publication The information given is designed only as guidance for safe handling use processing storage transportation disposal and release and is not to he considered warranty or quality specification The information relates only to the specific material designated and may not he valid for such niateriiI used iii combination with any other materials or in any process unless specified in the text



## KEY-H EC-1 -001588

# MATERIAL SAFETY 

# DATA SHEET 

# FR

9ATE 

### PREEDO9.02-0S MSDS No WFR-7 

## WFR-7 I.PRODUCT 

## AND COMPANY IDENTIFICATION

PRODUCT 

## NAME WFR-7 

### CHEMICAL 

## FAMILY Anionic Polyacrylamide Copolymer in Water-in-Oil Emulsion 

## MOLECULAR FORMULA Mixture 

## MANUFACTURER Information Key Energy Pressure Pumping Services 

### 303W Wall Suite 1200 Midland 

### TX 79701
24 

# HR EMERGENCY TELEPHONE 

# NUMBERS PERS 

## US Transportation 

## 800 633-8253 Emergency 

### Phone 432-570-4899 Emergency Phone 

## 432 570-4899



## COMPOSITION INFORMATION 

## ON INGREDIENTS

Chemical 

### Name Wt.% 

## CAS
Petroleum Distillate 64742-47-8 Anionic Polyacrylamide Copolymer 

### OSHA 

## HAZARDOUS COMPONENTS 29 CFR 1910.1200 

### EXPOSURE LIMITS Chemical 

### Name OSHA PEL ACCIH TLV Supplier Petroleum Distillate 165 ppm



## HAZARDS IDENTIFICATION EMERGENCY OVERVtEW PHYSICAL 

## APPEARANCE Opaque off-white emulsion 

### IMMEDIATE 

## CONCERNS WARNING Causes eye irritation Mist may be harmthl if inhaled 

### POTENTIAL 

## HEALTH EFFECTS EYES Irritating and may iniure eye tissue if not removed promptly 

### SKIN Low order of toxicity Prolonged or repeated contact may irritate and cause dermatitis 

### INGESTION Low order of toxicity May result in gastrointestinal irritation nausea and diarrhea Small amounts of
the liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchiopneumonm or pulmonary edema 

### INHALATiON Irritating to eyes and respiratory tract in high concentrations Repeated and prolonged overexposure

to oil mists may result in droplet deposition oil granuloma formation inflammation and increased incidence of
infection 

### CANCER 

## STATEMENT This product or any componeni at concentration of 0.1% or greater is not listed by the 

### NTP IARC OSHA or EPA as carcinogen



### FIRST 

# AU MEASURES EYES Immediately flush eyes with large amounts of water for at least 15 minutes Get immediate medical attention 

### SKIN Wash with large amounts of water use soap if available Remove grossly contaminated clothing including shoes and launder before reuse If irritation persists seek medical attention 

### INGESTION if swallowed 

## DO NOT induce vomiting Keep at rest Get prompt medical attention If spontaneous vomiting occurs keep head below hips to prevent aspiration and monitor for breathing difficulty 

### INHALATION In ease of adverse exposure to vapors and/or aerosols immediately remove the affected victim from
exposure and get immediate medical attention If breathing is difficult give oxygen If breathing stops give artificial respiration 

## FHE FIGHTIN MFASURES

KEY-H EC-1 -001589FLASHIPOINT 

## AND 

## METHOD 200FPensky-Maitens 

### CC 

## FLAMMABLE LIMITS 13 to 8.1% Petroleum Distillate 

### AUTOIGNITION 

## TEMPERATURE Not Available 

## hAZARDOUS COMBUSTION 

## PRODUCTS No unusual FIRE 

### FIGHTING 

## PROCEDURES Use water to cool fire-exposed surfaces and to protect personnel Isolate fuel supply from fire Use foam dry chemical or water spray to extinguish fire FIRE FIGHTING 

## EQUiPMENT As in any fire wear self-contained breathing apparatus pressure-demand MS1-IA/NIOSFT approved or equivalent and full protective gear



## ACCIDENTAL RELEASE 

## MEASURES ENVIRONMENTAL PRECAUTIONS 

## WA1ER SPILL Prevent additional discharge of material if possible to do so without hazard Remove from surface by skimming or with suitable adsorbents Consult an expert on disposal of recovered material and ensure conformity to
all federal state and local disposal regulations see Section 1.5 Clean Water 

### Act LAND SPILL Prevent additional discharge of material if possible to do so without hazard For small spills implement cleanup procedures for large spills implement cleanup procedures and if in public area advise authorities 

### GENERAL 

## PROCEDURES Spilled product should be scooped up as much as possible and the remaining thin layer absorbed with solid material such as sweeping compound Washing the area with atcr should only be attempted after most of the polymer has been removed 

### RELEASE 

## NOTES Recycle or dispose of recovered material in accordance with all federal state and local regulations 

## COMMENTS Spilled material is slippery Contact with water may form highly viscous and stringy material which
is extremely slippery difficult to clean up and can clog small drains



## HANDLING AND STORAGE GENERAL 

## PROCEDURES Keep container closed Both open and handle containers with care Store in cool vell ventilated place away from incompatible materials 1o 

### NOT pressurize cut heat or weld containers Empty product containers may contain product residue Do 

### NOT reuse empty containers without commercial cleaning or reconditioning 

## HANDLING Mix will before using Upon standing product may stratifr as noted by clear upper layer of oil Mild agitation will restore uniformity 

## STORAGE Do not usc aluminum copper or mild steel tank pumps or piping with this product Store in glass stainless steel plastic or epoxy lined containers 

### STORAGE 

## TEMPERATURE Keep from freezing 

### STORAGE PRESSURE Atmospheric 

## EXPOSURE 

## CONTROLS PERSONAL PROTECTION ENGINEERING 

## CONTROLS Ventilation should be provided to control worker exposures and prevent health risk and as necessary to reduce prevent and control aerosol gener.stion 

### PERSONAL PROTECTION EYES AND 

## FACE Safety glasses with side shields 

### SKIN Where contact may occur wear chemical resistant gloves and long sleeves 

### RESPIRATORY Where concentrations in air may exceed the limits given in this section or Section and engineering work practice or other means of exposure reduction are not adequate NIOSFI/MSUA approved respirators may be necessary to prevent overexposure by inhalation 

### OTHER USE PRECAUTIONS In Ihe area where this product is used an eyewash station is necessary and safety shower is recommended



## PHYSICAL 

## AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid 

## ODOR Slight hydrocarbon odor 

### VAPOR PRESSURE 

## mm Hg at 

## 100F VAPOR DENSiTY Air BOILING 

### POINT 

## 212F to 

## 415F

KEY-H EC-1 -001590

### FREEZING POINT 

## 10F to 

## 32F EVAPORATION 

## RATE n-Butyl Acetate1 SPECIFIC 

## GRAVITY 1.04 to 1.07 at 

## 77F VISCOSITY 400 to l200cP at 

## 80F Brookfield 

### RVT 3/50 

## COMMENTS WATER SOLUBILITY Soluble with vigorous agitation Contact with water at product content greater then approximately 

### 2% without vigorous agitation results in highly viscous and stringy material which is cxtrcmcly slippery difficult to clean up and can clog small drains 

### 10 STABILITY 

## AND REACTWITY STABLE YES 

### HAZARDOUS POLYMERIZATION NO CONDITIONS TO 

## AVOID Heat over 50 degrees 122 and moisture/water 

## HAZARDOUS DECOMPOSITION None 

### INCOMPATIBLE MATERIALS Strong oxidizing agents 

### 11 

## TOXICOLOCICAL D4FORMATION TARGET 

## ORGANS At high oral doses the petroleum distillate used in this product caused reversible damage to the user and kidney male only of rats These effects are not relevant to humans at occupational levels of exposure 

### 12 

## ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No information available 

### 13 

## DISPOSAL CONSIDERATIONS EMPTY 

## CONTAINER Empty containers retain product residue liquid and/or vapor Although the residue is low fire hazard flash point 200 it can burn upon heating to temperatures at or above the flashpoint and can be dangerous Therefore 

# 10 NOT PRESSURIZE 

## CUT WELD BRAZE SOLIER DRILL 

## GRIN OR EXPOSE 

### SUCH CONTAINERS TO 

## HEAT FLAME SPARKS STATIC ELECTRICITY 

### OR OTHER SOURCES OF IGNITION 

### THEY 

## MAY EXPLODF AND CAUSE INJURY 

### OR 

## lEATH Empty drums should be completely drained properly bunged and promptly returned to drum reconditioner or properly disposed of 

### GENERAL 

## COMMENTS Ensure compliance with local slate and Federal regulations in disposing of this container residual contents or rinsing 

### 14 

## TRANSPORT INFORMATION DOT 

## DEPARTMENT OF TRANSPORTATION PROPER SHIPPING 

## NAME Not Regulated 

### 15 

## REGULATORY INFORMATION UNITED STATES SARA TITLE III 

## SUPERFUND AMENDMENTS AND REAUTHORIZATION 

## ACT FIRE NO PRESSURE 

## GENERATING NO REACTIVI1Y 

## NO ACUTE YES 

## CHRONIC NO 311/312 1-LZARD 

### CATEGORIES Acute l-Iealth 313 

### REPORTABLE INGREDIENTS This product does not contain Section 313 Reportable Ingredients 

### CERCLA 

## COMPREHENSWE RESPONSE 

## COMPENSATION AND LIABILITY 

## ACT CERCLA 

## REGULATORY If this product is accidentally spilled it is not subject to any special reporting under the requirements of the Comprehensive Environmental Response Compensation and Liability Act 

## CERCLA We recommend you contact local authorities to determine if there may be other local reporting requirements 

### TSCA 

## TOXIC SUBSTANCE 

## CONTROL ACT TSCA STATUS All components of this product are listed on the 

### TSCA Inventory or are exempt from TSCA Inventory requirements 

## RCRA STATUS Discarded product as sold would not be considered 

### RCRA Hazardous Waste



## KEY-H EC-1 -001591

### CLEAN 

## WATER ACT This product is classified as an oil under Section 311 of the Clean Water Act 

### 40 CFR 110 and the Oil Pollution Act of 1990 Discharge or spills which produce visible sheen on either surface water or in waterways/sewers which lead to surface water must be reported to the National Response Center at 800-424-8802 

### 16 

## OTHER INFORMATION APPROVAL 

## DATE 04-13-05 

### PREPARED 

## BY Ed Vinson
IIMIS 

### CODES FLAMMABILITY 

## HEALTH PHYSiCAL 

## HAZARD LMIS RATINGS 

## NOTES This information is for people trained in Key the National Paint Coatings Associations Severe 

## NPCM Hazardous Materials Identification Serious System 

### IIMIS Moderate Slight Minimal 

## MANUFACTURER DISCLAIMER NOTICE We believe that the information contained on this Material Safety Data Sheet is accurate The suggested procedures are based on experience as of the date of publication They are not necessarily either all-inclusive or fully adequate in every circumstance Also these suggestions should not be confused with or followed in violation ol applicable laws regulation rules or insurance requirements 

## NO WARRANTY IS 

## MAIE EXPRESSED OR IMPLIED OF 

### MERCHANTABILITY FITNESS 

### FOR PARTICULAR PURPOSE 

### OR OTHERWISE



## KEY-H EC-1 -001592Material Safety Data Sheet 

# WFR-9

Chemplex Ltd 

### DATE PREPARED 02/04/2009 

### Box 1071 

### REVISION 

## DATE 02/04/2009 /C Snyder 

## TX 79550 

## EMERGENCY NUMBER.. 800-633-8253 

## 325 573-7298



## SECTION IDENTIFICATION
PRODUCT NAME 

# WFR -9 CHEMICAL FAMILY Polyacrylamides 

### CAS 

## NUMBER Mixture 

## PRODUCT USE Friction reducer for water


## SECTION II- 

# HAZARDOUS INGREDIENTS HAZ INGREDIENT PERCENT CAS 

# NUMBER PEL Petroleum Distillate 20-30% 64742-47-8 N/A


## SECTION III 

## PHYSICAL 

# DATA
APPEARANCE 

## Opaque off-white emulsion 

## ODOR Slight hydrocarbon odor 

## BOIUNG POINTS 

## 212F FLASHPOINT 

## 200F VAPOR DENSITY 

# AIR1 Air 

## VAPOR PRESSURE 

# mm Hg at 

## 100F SPECIFIC 

### GRAViTY 

# wATER1 0.99 

### pH 

# 1% SOLN/WATER Near neutral 

### SOLUBILITY Complete limited by viscosity 

### DENSITY 8.67 lb/gal


## SECTION IV FIRE 

# AND EXPLOSION 

# DATA
FLASH POINT 

## 200F FLAMMABLE 

## HAZARDS Will burn in surrounding fire FIRE 

### FIGHTING 

## PROCEDURES 

# SMALL Use dry chemical 

### powder 

## LARGE FIRE Use water spray fog or 

### foam 

## DO NOT use water jet Product will 

### become very slippery 

### when contacted with water



### Page 

## of4

KEY-H EC-1 -001597Material Safety Data Sheet 

# WFR-9

SECTION REACTIVITY 

# DATA
STABILITY This product is stable 

### REAC11VITY Reacts with strong oxidizing 

### agents


## SECTION VI 

# HEALTH HAZARD DATA
ROUTE OF ENTRY Skin contact eye contact 

## CHRONIC EFFECTS 

## ON 

## HUMANS

.. 

### None 

## known


## SECTION VI FIRST 

## AID
INHALATION

EYE 

## CONTACT

SKIN 

## CONTACT



## SECTION VII 

## SPILL 

# STORAGE 

# AND DISPOSAL 

# DATA

SPILL 

## SMALL SPILL Absorb with an inert material 

### and put the spilled material in an appropriate waste disposal Spills of this product are very slippery particularly if



### Page of 

## SLIGHT INHALATION Allow the victim to rest in well ventilated 

### area Seek immediate medical attention 

## HAZARD INHALATION Evacuate the victim to safe area as soon as possible 

### Loosen tight clothing such as

collar tie belt or waist 

### band If breathing is difficult administer 

### oxygen If the victim is not breathing perform mouth-to-mouth resuscitation 

### Seek medical attention 

### INGESTION Only induce vomiting at the instruction of 

### physician Never give anything 

### by mouth to 

### an unconscious person Examine the lips 

### and mouth to ascertain whether the tissues are 

## damaged possible indication that the toxic material 

### was ingested the 

### absence of such signs 

### however is not conclusive 

### Loosen tight clothing such as collar tie belt or waistband If the victim is not breathing perform mouth-to-mouth resuscitation 

### Seek immediate medical attention 

### Check for 

### and remove any contact lenses 

### Do not use an eye ointment 

### Seek medical attention Flush with plenty of water for at least 15 minutes occasionally lifting the upper 

### and lower eyelids After contact with skin 

### wash immediately with plenty of water Gently 

### and thoroughly 

### wash the contaminated skin with running water 

### and non-abrasive 

### soap Be particularly careful to clean folds crevices 

### and groin Cold water 

## may be 

### used Cover the irritated skin with an emollient If irritation persists seek medical attention 

## Wash contaminated clothing before reusing



## KEY-H EC-1 -001598Material Safety Data Sheet 

# WFR-9

contacted with water 

## LARGE SPILL Absorb with an inert material 

### and put the spilled material in an appropriate waste disposal 

## WASTE DISPOSAL Whatever cannot be saved for recovery or recycling should 

### be managed in 

### an appropriate 

### and approved waste disposal facility Processing use or contamination of this product 

## may change the waste 

### management options State 

### and local disposal regulations 

## may differ from federal disposal regulations Dispose of container 

### and unused contents in accordance with federal state 

### and local requirements 

## HANDLING Keep away from heat 

### Keep away from sources of ignition 

### Empty containers 

### pose fire risk evaporate the residue under 

### fume hood Ground all equipment containing material 

### Do not breathe 

### gas fumes vapor or spray If you feel unwell seek medical attention 

### and show the label 

### when possible Avoid contact with skin 

### and eyes Keep away from incompatibles such as oxidizing agents 

### and moisture 

## STORAGE Keep container dry 

### Keep in cool place 

### Ground all equipment containing material 

### Keep container tightly closed 

### Keep above 

# 35F
SECTION VIII 

## PROTECTIVE 

# CLOTHING
RESPIRATORY 

## PROTECTION Use 

## MSHA/NIOSH approved respirator or equivalent 

### PROTECTIVE 

## CLOTHING/EQUIP Apron/lab coat safety glasses gloves


## SECTION IX 

# TRANSPORTATION 

# DATA
PROPER SHIPPING 

## NAME Not 

## DOT Regulated 

## HAZARD CLASS N/A 

## UN NUMBER N/A PACKAGING 

## GROUP N/A 

# RQ N/A 

## DOT SHIPPING Not 

## DOT Regulated


## SECTION 

# OTHER REGULATORY INFORMATION
TSCA 

## STATUS All 

### components of this product are listed on the 

## TSCA inventory 

### NFPA 

## HEALTH NFPA FLAMMABILiTY NFPA REACTIVflY

Page 

## of4

KEY-H EC-1 -001599Material Safety Data Sheet 

# WFR-9

SECTION XI 

# ADDITIONAL INFORMATION
PREPARED BY Edward Vinson 

# EMERGENCY RESPONSE NUMBER 800-633-8253



### Page of



## KEY-H EC-1 -001600

# E c ono my P o l y m e r s & C h e m i ca ls P. O . B o x 450246 H ou s t o n , TX 77245 - 0 2 46 USA T oll free : ( 800 ) 231 - 2066 P hone : ( 713 ) 723 - 84 16 Fa x : ( 713 ) 723 - 184 5 UR L : www .E c ono m y P ol y m e rs . c om E- m ai l : e c on o m y @ e c o no m y po l y m e rs . c om 

# M A T E R I A L S A F E T Y D A T A S H E E T PR O D UC T NA M E : W GA- 1 RE V I S I O N DA TE : M ay 21, 2007 F o r C h e mi c al E me r g e n cy ( Sp ill , L e a k , F i re , E x p os u reo r A cci d e n t) CA LL C HE M T RE C D ay o r N i g h t 800 - 424 - 9 3 00 F o rI n tern ati o n al , C all703 - 527 - 3887 (C o ll e ct C all s A cce p te d ) ** F O RI N D U ST RIA L U SE O N L Y** Sec ti o n I- P r o duc t I nfo r ma t i on Ch e mical N ame: GU AR GUM F o rm u l a : N A C A S N u m b er : 9000

- 30

- 0 DO T Hazard C la ss : N o t Re g u l ate d Reportab le Qu antity : N o n e Sec ti o n II

– C o mp o s i ti o n , I n fo r mati o n o n I n g redien ts M aterial C A S # : P erce nt Gu ar Gum 9000

- 30 -0 > 90 Sec ti o n III- H e a l th Ha z a rd D ata Si g n s & S y s te m s o f O v ere xpo s ure i n the Wo rk p lace E ye s : M ay cau s e irritati o n . S ki n : M ay c au s e mi l d irritati o n . I nh alati o n : I nh al i ng d u s t m ay cau s ere s p ir atory irritati o n . I ng e s ti o n : N o n e Kn o w n . MED I C AL C O N D I T I ONS GENE RALLY RE C OGN I ZE D AS B EI NG A G G RAV AT E D B YEX P OSU RE : N o n e Kn o w n P RIM A RY R OU T E OFENT RY: F o ll o w i ng s t an d ard i n du s trial h yg i e n e an drec o mme n d e d pro c e dure s , e ntry o f the c o m

p o un d i nto th e body i s n o t e xp ecte d
. C AN C E RI NF O RM AT I ON: N o t li s te d a s a carci n o g e n b y NT P( Nati o n alT o xic o l og y Pro gr am) ; n o t re gu late d a s a carc i n o g e n b y OS H A( Occ up ati o n al S a f e ty & Heal th Ad mi ni s tr ati o n ) ; n o t e v alu ate d b y I A RC(I ntern ati o n a l A g e n c y for Re s earc h o n C an cer). T o xic Data E ye c o ntact: A P RI M AR Y R OU T E OFENT RY , n o d ata i s av ailab le S ki n C o ntact: A P RI M AR Y R OU T E OFENT RY , n o d ata av ailab le I nh alati o n : N o d ata i s av ailab l e I ng e s ti o n : N o d ata i s av ailab l e S p ecial Precauti o n s : I n di v i du a l s w i th s ki n orre s p ir atory di s e a s e s s h o u l d n o t b e e xpo s e d to thi s produ ct un le ss prop erl y pro tecte d
. Sec ti o n IV - F ir s t Aid M e a s ures T hre s h o l d Li mit Val u e( T LV ) f or Pro du ct: N o n eE s tab l i s he d
. D o e s produ ct c o ntai n an y O S H A , NT P or I AR C C arc i n o g e n s ? N o Fir s t Ai d

# E c ono my P o l y m e r s & C h e m i ca ls P. O . B o x 450246 H ou s t o n , TX 77245 - 0 2 46 USA T oll free : ( 800 ) 231 - 2066 P hone : ( 713 ) 723 - 84 16 Fa x : ( 713 ) 723 - 184 5 UR L : www .E c ono m y P ol y m e rs . c om E- m ai l : e c on o m y @ e c o no m y po l y m e rs . c om 

# E ye s : Fl u s h th oro u g hl y w i thrun ni n g w ater at lea s t 15 mi nu t e s . Get me dical atte nti o n i f irritati o n p er s i s t s . S ki n : Re mo v e c o nt ami n ate d cl o thi ng an d w a s h c o ntact area w i th s o ap an d w ater f or 15 mi nu te s . I nh alati o n : I n ca s e o f e xpo s ure to a hi g h c o n ce n tr ati o n o f du s t , re mo v e p er s o n to f re s h air. I f breathi n g h a s s topp e d , admi ni s ter arti f

icial r e s p ir ati o n an d s e e k me dical atte nti o n . I ng e s ti on : I f appreciab le qu antiti e s are s w all o w e d , s eek me dical atte n ti o n . Nature o f Hazard ( P h y s i o l og i c alE ff e c t s ) WARN IN G : M AY CAUS E E Y E I RRI T A TI O N . B REA T H IN G DU S T M AY CAUS E RE S P I RA T O R Y I R R IT A T I O N Sec ti o n V- F ire & Exp l o s i o n Ha z a rd D a ta Fla s h P o i nt

( C l o s e d Cup) : > 3 00 De gree s F Fl amm ab le Li mi t s : N o d ata i s av ailab le E xti n g ui s hi n gM e dia: W ater s pr ay , F o am , CO 2 

# , D ry Ch e mi c al S p ecial Fire Fi g hti n g Pro ce dure s : W ear a s el f c o ntai n e d breathi ng app ar atu s to av o i d to xi c f u me s . Slipp ery wh e n w et . Fire &E xp l o s i o n Hazard s : C l o s e d c o ntai n er s m ay rup ture ( du e to b uil dup o f pre s s ure ) wh e n e xpo s e d to e xtre me heat . C oo l dru m s e xp o s e d to f l ame s w i th a w ater s p r ay . * A dditi o n al i n f

o rmati o n w ill b e pro v i d e d i n a me dical e merg e n c y to qu al i f ie d me dical p er s o nn e l
. Sec ti o n V I

– Acciden tal Rel e a s e M e a s ures E v ac u ati o n Pro ce dure s an d Saf e ty : C AU T I ON: S p ille d mate rial may b ec o me s lipp ery whe n w et . D o n o t le a v e tr ace s o f p r odu ct o n f l oor s , ladd er s , etc ., a s thi s may pre s e n t a s lipp i n g h azard. W ear appr opriate p ro tecti v e g ear f or the s i tu ati o n . S ee P er s o n al Pro tecti o n i n f o rmati o n i n Se c ti o n 8
. C o ntai n me n t o f S p ill: F o ll o w pro ce dure d e s c rib e d b el o w und er C leanup an d Di s po s al o f S p ill C leanup an d D i s po s al o f S p ill : D ryM aterial: S w eep up an d p lace i n an appropriate cl o s e d c o ntai n er ( s ee Sec ti o n 7 : Han d li n g an d Stor ag e ). W et M ateri al: Ab s orb w i th an i n ert ab s orb e nt . S h o v el up i nto an appr opriate cl o s e d c o ntai n er ( s ee Secti o n7 : Han d l i n g an d Stor ag e ). E nv iro n me ntal an d Re gu l atory Reporti n g : S p il l s may b ereportab le to the Nati o n al Re s pon s e C e nter (800

- 424

- 8802) an d to s tate an d/or l o cal ag e n cie s . Sec ti o n V II

– Ha ndlin g & S t o r age Han d l i ng : A v o i d breathi n g du s t s Stor ag e: Store i n cl o s e d c o ntai n er s . Store i n an area th at i s dry . Sec ti o n V I I I- Speci a lP r otec ti o n I nfo r mati on Air E xpo s ure Rec o mme n d ati o n s Ga s , Fu me s , M i s t s S p ecial T herma l N orma l U s e E x cee d s T LV S pr ay App licati o n Ge n er al Ve n tilati o n Ge n er al Ve n tilati o n Ge n er al Ve n tilati o n 2 * 2 * 2 * *Re s p ir ato ry pro tecti o n c od e s : 1
. N o n e Nee d e d

# E c ono my P o l y m e r s & C h e m i ca ls P. O . B o x 450246 H ou s t o n , TX 77245 - 0 2 46 USA T oll free : ( 800 ) 231 - 2066 P hone : ( 713 ) 723 - 84 16 Fa x : ( 713 ) 723 - 184 5 UR L : www .E c ono m y P ol y m e rs . c om E- m ai l : e c on o m y @ e c o no m y po l y m e rs . c om 

# 2. P article

- re mo v i n g , air p uri f ier . Store i n dry p lace
. Keep c o nt ai n er cl o s e d to av o i d mo i s ture p ic kup . M aterial s lipp ery wh e n w et . Sec ti o n IX- Ph y s ic a l D ata Bo ili ng P o i nt: > 6000 F p H( 1 % S o luti o n ) : 6
. 0

- 8
. 0 Vapor Pre ss ure ( mmH g ) : NA Vapor De n s i ty( air = 1) : > 10 W ater S o lub ili ty : F o rm s g e l S p eci f ic gr av i ty : 1
. 3 0 E v apor ati o n R ate( ether = 1) : > 1 Vapor Pre ss ure: < 0
. 1 Sec ti o n X- Re a c ti v i ty D ata Stab ili ty : Stab le Hazardo u s P o l ymerizati o n : W ill n o t o cc ur C o n diti on s to av o i d : Fire , e x c e ss i v e heat I n c o m p atib ili ty(M aterial s to A v o i d) : Stro ng o xi dizer s , Li q ui d Aci d s Hazardo u s Dec o m

po s iti o n Produ ct s : Fu me s produ ce d whe n heate d to d ec o m po s iti o n may i n c l u d e: o xi d e s o f carbo n . Sec ti o n X I

– T o xic o l og ic a l D ata Ac ute E yeIrritati o n : N o te s t d ata f ou n d f or produ ct Ac ute S ki nIrritati o n : N o te s t d ata f o un d f or produ ct Ac ute Derm al T o xici ty : N o te s t d ata f ou n d f or produ ct Ac ute Re s p ir ato ryIrritati o n : N o te s t d ata f ou n d f or produ ct . Ac uteI nh alati o n T o xici ty : N o te s t d ata f ou n d f or produ ct Ac ute O r al T o xici ty : N o te s t d ata f ou n d f or produ ct . Chr o nic T ox ici ty: T hi s product do e s n o t c o ntai n an y s ub s tn ce s th at are c o n s i d ere d b y OS H A , NT P , I AR C or A C GI H to b e " p rob ab l e " hu man car ci n o g e n s . N o additi o n al te s t d ata f ou n d f or produ ct Sec ti o n X II

– E c o l og ic a l D ata E c o to xic o l o g icalI n f

o rmati o n : N o d ata f

o un d f or produ ct Ch e micalr ate i n f

o rmati o n : N o d ata f

o un d f or produ ct Sec ti o n X I I I

– Di s p o s a l C o n s ider ati o ns W a s te Di s po s alM e th od : Ch e mical additi on s , pro ce ss i n g or o ther w i s e alteri ng thi s material m ay m ake the w a s te m an a g e m e nt i nf o rm ati o n pre s e nte d i n thi s M SDS i n c o m p lete , i n ac c ur ate or o ther wi s e i n appropriate
. P lea s e b e ad v i s e d th at s tate an d l o calre quire me nt s f or w a s te di s po s al may b e morere s tricti v e or o ther wi s e di f f ere nt f ro m f e d er al l a w s an d re gu lati o n s . C o n s u lt s tate an d l o calre gu lati o n s re g ardi ng the prop er di s po s al o f thi s m ateri al
. C o ntai n er Han d l i n g an d Di s p o s al: An y c o nt ai n er s or e quip m e nt u s e d s h o u l d b e d ec o nt ami n ate d i mme diate l y a f ter u s e . E P A Hazardo u s W a s te - N O Sec ti o n X IV

– T r a n s p o rt I nfo r mati on T hi s produ ct i s n o t

re gu l ate df

or tr an s port

# E c ono my P o l y m e r s & C h e m i ca ls P. O . B o x 450246 H ou s t o n , TX 77245 - 0 2 46 USA T oll free : ( 800 ) 231 - 2066 P hone : ( 713 ) 723 - 84 16 Fa x : ( 713 ) 723 - 184 5 UR L : www .E c ono m y P ol y m e rs . c om E- m ai l : e c on o m y @ e c o no m y po l y m e rs . c om 

# Sec ti o n XV

– Re g ul ato ry I nf o r mati on I nv e nto ry s tatu s I nv e nto ry s tatu s UN I T E D S T AT E S ( T S C A ) Y C AN AD A( D S L ) Y EU R O P E (EI NE C S/ELI N C S ) N AU S T RALI A ( AI C S ) Y J AP AN(MI T I ) N SOU T H KO RE A( KE C L ) Y Y= All i n gre die nt s are o n the i n v e nto ry . E = All i ngre di e nt s are o n the i n v e nto ry or e x e m p t f ro m l i s ti ng . P= O n e or more i n gre die nt s f all u n d er the po l y mer e x e m p ti o n or are o n the n o l o ng er po l ymer li s t . All o ther i n gre di e nt s are o n the i n v e nto ry or e x e m p t f ro m li s ti n g . N = N o t d etermi n e d or o n e or more i n gre die nt s are n o t o n th e i nv e nto ry an d are n o t e x e m p t f ro m l i s ti ng . FE D E RAL RE GU LAT I ONS I nv e nto ryI s s u e s : All f

u n cti o n al c o m

po n e nt s o f thi s produ ct are li s te d o n the T S C A I nv e nto ry . S ARA T itleIII Hazard C la ss e s : Fire Hazard NO Reacti v e Hazard NO Relea s e o f Pre s s ure NO Ac ute Heal th Hazard NO Chron ic Heal th Hazard NO S ARA E xtre me l y Hazardo u s S ub s t an ce s (E HS ) /C E RC LA Hazardo u s S ub s t an c e s : T hi s produ ct do e s n o t c o ntai n an y h azardo u s s ub s t an ce s a s c o n s i d ere d b y S ARA or C E RC LA
. State Re g u lati on s : T hi s produ ct do e s n o t c o ntai n an y c o m p o n e n t s th at arere gu l ate d un d er C al i f ornia Propo s iti o n 65. Sec ti o n XV I- M i s cell a ne o us C o mme nt s : U s e g ood h ou s eke ep i ng pro ce dure s to mi ni mize du s t b uil d

- up Di s clai mer : T HE I NFO RM A T I ON W HI C HI S I N T H I S D O C UMENT I S B A S E D U P O N AV AI LAB LE D AT A AND B ELIE V E D T O B E C O RRE C T ; HO WE V E R , T HE P R ODU C T D I S C USS E D HE REI NI S SO LD W I T HO UT ANY W A RRANT Y , EX P RE SS E D O RIM P LIE D , A S T O ME RC H ANT IB I LI T Y O R FI T NE SS FO R A P A RT I C ULA R P U RP OS E.

## lar 15 01 

# 0921a ECONOMY 7134338382 p.1


# MATERIAL SAFETY 

# DATA SHEET 03-08-2000 

# COMPANY ECONOMY POLYMERS AND ChEMICALS P.O 

## BOX 450246 

# HOUSTON TEXAS 77245-0246 

### Emergency phone number in 

# USA 0O-23 1-2066 

### For product informatiOn 713-723-8416 

## CAS 9000-30-0 

### Product 

## Name WGAI-ASLR 

# CHEMICAL 

# NAME GALACTOMANNAN MIXTURE INGREDIENTS Percent 

## TLV PEL Guar 

## Gum 

# 80 lOmg/m3 lSmg/m3
Silica amorphous 0.1-5.0 

### lOmg/m3 6mg/m3 Organophilic clay 0.1-5.0 

## PROPERTIES Appearance Off-white solid 

### powder Solubility in water at 20 complete 

### Odor Odorless gms/l 

### OOmi water
Specific gravity 0.900 BiodegradabilitY slow
Bulk density 29.07 lb/cu.ft Volatiles 

# ND pH not determined 

# ND Solubility in sea water 

# ND

Flash point 

## 200 TOXICITY 

# HAZARD RATING Nontoxic 

## OSHA Hazardous 

# F1JNn Hazardous 

# NH NH NFPA Hazard 

## Code 1-lealth Flammability Reactivity 

## 010 4ExtremelSevere 2Moderate 

## HMIS Labeling Health Flammability Reactivity 

## 100 SARA Title ifi Classification 

### Exempt Not listed as toxic chemical under 40 

## CFR section 372.65 Regulatory 

### Information This product is listed on the 

## TSCA Inventory


## FIRE 

# AND EXPLOSION 

# HAZARD DATA
Flash 

### Point Ignition 

## Temp 

## 200 Extinguishing 

### Media- Water foam 

## C02 Special Fire Fighting 

### Procedures Good Housekeeping is best preventative 

### Unusual Fire 

### and Explosion 

### Hazards- Excessive dusts from powder products are potentially hazardous Avoid

excessive dusting open flames open lights or welding in area of dry product if bag 

### dumping Incomplete thermal decomposition 

### may produce carbon dioxide and carbon 

### monoxide 

# REACTWITY DATA Stability Stable Conditions to 

### Avoid Excessive dusting 

### Hazardous Polymerization- Will not occur 

# HEALTH HAZARD DATA/FIRST All 

## PROCEDURES Routes of 

## Entry Inhalation 

## May cause allergic respiratory reaction in susceptible individuals ingestion 

# ND Eye May cause irritation Skin non irritating Carcinogenicity 

### None


## KEY-H EC-1 -001601

## Mar 15 01 

# 0921a ECOMOMY 7134338382 P.2

Signs 

### and 

## Symptoms of 

### Exposure 

## No harm under most conditions 

### Medical Conditions 

### Aggravated by 

### Exposure Inhalation of 

### nuisance dusts have long history of little adverse
effect an lungs 

## May iffitate 

### mucous membranes Emergency and First 

### Aid Procedures 

# EYE immediately flush eyes with plenty of water for at least 15 minutes If irritation persists seek prompt medical attention 

## SKIN PROMPTLY 

# WASH SKThI 

## WITH SOAP 

## AND 

# WATER WASH CLOTHING BEFORE 

## REUSE INhALATION Remove to fresh air if irritation persist seek medical attention 

## INGESTION do not induce vomiting in general no treatment is necessary unless large quantities are ingested 

### However medical advice should be obtained 

## PRECAUTIONS FOR SAFE 

## HANDLING AND USE Steps to 

### Be Taken if Material is 

### Rekased or Spilled 

### Sweep up or shovel into 

## DOT approved containers 

### Waste Disposal 

## Method Comply with all applicable local state and federal regulations for waste disposal 

### Department of Transportation 

# DOT Classification.- 

## N/A non-hazardous Precautions to 

### Be Taken in Handling 

### and Storing Avoid dust accumulations Best storage is realized at 

### dry coal conditions Store in an odor-free 

### area Store 

### away from heat source 

## Do not expose to open flame or sparks 

### Other Precautions Enforce 

# No Smoking Rules Excessive concentrations ofnuisance dusts in 

### workroom air 

### may seriously reduce visibility 

# CONTROL MEASURES Respiratory Protection 

### Use 

## NIOSHJOSHA approved 

### mask when bag 

### dumping Eye Protection 

### Recommended Ventilation- 

### Use local exhaust as needed to maintain airborne exposure 

## STEPS 

# TO BE 

# TAKEN IF 

## MATERIAL IS 

## RELEASED 

# OR SPiLLED Use protective equipment sweep up and 

### remove avoid creating or inhaling dust Product is very slippery 

### when wet Waste disposal 

### method If not contaminated reuse product get approval from landfill operator and transport to sanitary landfill 

# ENVIRONMENTAL EVALUATION EPA 

## SUPERFUND 

# SARA TITLE ifi- 

## HAZARD CLASSIFICATiON 

## AND ASSOCIATED 

## INFORMATION FIRE 

## PRESSURE REACTIVE ACUTE 

# IMMEDiATE CHRONIC 

# DELAYED MiXTURE OR PURE 

## MATERIAL MiX EPA 

## CERCLA/SUPERFUND 40 

## CFR 302 

## REPORTABLE SPILL 

## QUANTITY 

# NA
EPA 

## SARA TiTLE III 

## CFR 355 

## EXTREMELY HAZARDOUS SUBSTANCES PRODUCT CONTAINS 

# NO EXTREMELY HAZARDOUS COMPONENTS EPA 

## SARA TITLE 11140 

## CFR 372 

## LIST OF TOXIC 

## CHEMICALS PRODUCT CONTAINS 

# NO TOXIC INGREDIENTS 

## COMPONENTS LiSTED 

## ON FOLLOWING CHEMICAL INVENTORIES 

## TSCA YES 

## CEPA NE EEC ND ACOIN 

# ND NPR ND 

# DRSM NE EPA 

## RCRA 

# HAZARDOUS 

# WASTE 40 

## CFR 261
IF 

## PRODUCT BECOMES 

# WASTE IT 

## DOES 

## NOT MEET THE CRITERIA 

## OF 

## HAZARDOUS WASTE THE INFORMATION WHICH IS IN 

### THIS 

## DOCUMENT IS 

## BASED UPON AVAILABLE 

## DATA AND BELIEVED 

## TO BE 

## CORRECT 

# HOWEVER THE PRODUCT DISCUSSED HEREIN IS 

## SOLD 

## WITHOUT ANY 

# WARRANTY EXPRESSED 

## OR IMPLIED AS 

## TO MERCHANTIBILITY 

## OR FITNESS 

## FOR PARTICULAR PURPOSE

KEY-H EC-1 -001602

# MATERIAL SAFETY DATA SHEET PR0DUCr 

# NAME 711 

# t5 REVISION 

# DATE APR11 32003 ThIZPHONENU%m13R 713-723-8416 

### IN 

## CHEMICAL 

# EMERGENCY CALL 

# ECONOMY 100-231-2066 

# Maaic BoomyPolymers Mdre.a 43511 Anderson 

## Rd Houitcn 

## Tema 77047 

## FOR INDUSThML USE 

# ONLY

Section 

### 1-Product Information Chemical 

## Nanw 

## BLEND Formula 

# NA DOT Hazard 

# ama Not 

### Pogulted 

## DOT B1Th.X Petroleum diatillstca 

### N.O.S Costhustible liquid 

# UN 1268 ifi 

## CANADIAN 

# ADR ICAO/IATA 

# SM TRANSPORTA11C IMDG ALL NOT RESTRICIED
Section II Physical Data Flash Point 

### 176F Aiitoignition 

# Ten 437F or 

## 225C Boiling Point 

### 400-700F 

## pHraie 6.5-7.5 Color 

# BEI Odor Hydrocarbon Physical state liquid Specific Gravity 1.03

Vo1tiks 12.5 Vapor 

### Demity 4.5 Density 

### lbs/gil 8.6
Section 111- 

### Hazardous I.gredlents Matatlal 

# Cu Perecot 

### ILVunits 

# Had 1PcomdjstjlIitebl 

# NA 30-60 

# NA combustible

Polysaccbaridc blend 

# NA 30-60 

# NA
Section 

### IV Fire Explodoir 

### Hazaid Data Th1ingiahiiig 

### Media Water 

## Foam 

## CO2 Dry Chemical Special Fira 

### F%iiig Procedmza Wear self contained 

### bm.bing apparatus to avoid toxic flunes Slippery 

### when wat Fire Explosion Haranis aoaerl containers 

## may niptum 

## due to buildup pressure 

### when erposed to 

## treme heat Cool 

## kums ecposed to flames with water apray Addifioeal information will be provided in medical 

### amàgoncy to qualified medical personnel



## KEY-H EC-1 -001603Section Health 

## flmrd 

## Dat lirealiold Unijt Value 

# TLV fbr Product 

### None Established 

### Does product contain any 

# OSHA NIP or 

## IARC Carcinogens 

## No Fist Aid 

### Eyes Flush thoroughly with turning water at least 15 minutes Get medical atteslion if irritation Skis 

### Remove cocimiiiated clothing sari 

### wash contact area with soap and water lbr 15 minutes bJiation In of exposure to high concentration remove person to fresh air If breathing has stopped 

## ahniner artificial respiration and scak medical 

### ilidioa Ingestion If appreciable 

### iaitiea are swallowed seek medical 

## atton Nature of Hazard Physiological Effects Signs Systems 

### of Overoxposore in the 

### Woàplace Eyes 

## May canse irritation Skis 

## May onise mild irritation 

# btios Inlmiuiig dust 

## may cmise respiratuiy iiitation
Nature 

### of Hazard Physiological Effects 

## MEDICAL CONDITIONS 

## GENERALLY RECOGNIZED AS BEING 

# AGORAVA1 BY 

# OSURE kne Known 

## PRIMARY ROIYrB 

## OP 

# FRmY Following .Indiud industrial hygiene a.d reconunerKled procedures 

## thy of the 

### cempound into thebodyisnctexpected 

# CA INFORMATION Contains petrobema 

### ailate wiuich have been 

### shown to cmise akin cancer in isboratosy Irninal$ Special Precautions Individuals with akin or icapiatoiy diacucs should not be esposed to this urdeas 

## predy prctccte
Section 

### VI Resetivity 

### Data Stability Stable Hazardous Polymerization Will not ocour Conditloen to avoid Fire erceonve best Inconipatibilky Materials to 

## Avoid Strong oxidizers1 

### Uquid Acids HazardonDeconipositlon Products 

### Fumes produced 

### when bested to deconiposition 

## may 

# dIe oxides 

### of aiboui 

## NFPA RATINGS 

## HEALTh FLAMMABILITY 

## REACIIVTY HIMS RATINGS FLAMMABILITY REACflV1TY IJEAL1B Sediwi 

# VU Spli 

### Leak Prced.res Stopflowaod containspifi 

# ydfr eandbegs etc Ellmjnate all ignition 

### loumes InCiflerate 

### unng 

# aftcer and scrubber



### Uso skin protection 

## as per section 

### VIII 4Absoib on 

# it material and 

## .cra up or shovel into thums 

### Observo federal spill and water quality regulations



## KEY-H EC-1 -001604

### Product 

# Name HPG Revision 

## Date December 2005 Manufacturer 

## Economy Polymers Chemicals
IN 

# CHEMICAL 

# EMERGENCY CALL 800-231-2066 

# FOR INDUSTRIAL USE 

# ONLY

Section Product Information Chemical 

## Name Hydroxypropyl Guar 

## Gum Chemical FamilyGalactomannafl Thickner Formula C6H1205.0.42 

### POE CAS Number 39421-75-5 

## DOT Hazard Class Not Regulated Reportable Quantity None 

## DOT Proper Shipping 

## Name Bean Meal 

## NOl Dried
Section II Physical Data Boiling Point 

### N/A Density .38-I .4OgIcm3 Water Solubility Forms Gel 

## pH 9.0 10.5 1- 0.5 

# 1% Solution

Moisture 6.0 10 Appearance and 

### Odor Cream Color Solid Powder with Bean like Odor

Section DI Hazardous ingredients Material Percent 

## liv lunits Hazard

Hydroxypropyl Guar 

## Gum 50-90% 10 mgfm3 Nuisance Dust 

### CAS 39421-75-5 Silica amorphous 0.1-5.0 lOmgfm3 Organophilic clay 0.1-10.0 Dicarboxylic acid 0.1-10.0
Section 1V Fire Explosion Hazard Data 

### No data is available Flash point close 

### cup 200uF 

## PMCC Flammable Limits Extinguishing 

### Media Water spray 

## Foam 

## C02 Dry Chemical Special Fire Fighting Procedures Wear self-containing breathing apparatus to avoid toxics Slippery when wet

Fire Explosion Hazards Closed containers 

### may rupture 

### due to buildup of pressure when exposed to extreme heat Cool drums exposed to flames with water spray

Additional information will he provided in medical emergency to qualified medical personnel

Polymers Chemicals 

### P.O Box 450246 Houston 

### TX 77245-0246 

### USA Toll free 

## 800 231-2066 Phone 

## 713 723-8416 Fax 

## 713 723-1845 

## URL www.EconornyPolymers.com E-mail economyeconomypolymers.Com 

# irt 

# my /4- 

# POLYMES CHEMICALS 

# MATERIAL SAFETY 

# DATA SHEET Complies with 

# OSHA 29 

## CFR 1910.1200



## KEY-H EC-1 -001605

# Eaa POLYMERS 

# 4EALS

Section Health Hazard Data Threshold Limit Value 

# TLV for Product None Established Does Product contain any 

## OSHA NTP or 

### IARC Carcinogen 

### No FIRST All Eyes Flush thoroughly with running water for at leasl 15 minutes Get medical attention if irritation persists Skin Remove contaminated clothing and wash contact area with soap and water for 15 minutes
Inhalation In case of exposure to high concentration of dust remove person to fresh air If breathing has stopped administer artificial respiration and seek medical attention Ingestion If appreciable quantities are swallowed seek medical attention 

## NATURE OF 

## HAZARD Physiological Effects Eyes 

### No specific information available Contains materials that 

### may cause severe injurydamage reversible Skin Contains materials that 

### may cause moderate skin injury reddening swelling Inhalation 

### No specific information available Dust may produce respiratory allergenic response andi or irritation in some individuals Ingestion 

### No specific information available Contains materials that 

### may be slightly toxic Acute Overexposure Based on medical study of exposed workers some individuals may develop respiratory allergenic response to guar dust 

### TOXICITY 

## DATA Eye Contact 

### PRIMARY 

## ROUTE OF 

## ENTRY no data is available Skin Contact 

## PRIMARY ROUTE OF 

## ENTRY no data is available Inhalation 

### No date is available Ingestion 

### No date is available Special Precaution Individuals with skin or respiratory disease should not be exposed 

### tois product unless properly protected Section 

# Vi Reactivity 

## Dta Stability Stable Hazardous Polymerization Will not occur Conditions to avoid Fire excessive heat Incompatibility Materials to 

### Avoid Strong oxidizers Hazardous Decomposition Products Fumes produced when heated to decomposition may include oxides of carbon Section 

## VII Siiill or Leak Procedures

Stop flow and contain spill by diking sandbags etc Eliminates all ignition sources Incinerate using afterburner and scrubber Use skin protection 

## as per section VIII Absorb on inert material and scrape up or shovel into drums Observe federal spill and water quality regulations
Section VIII Special Protection Information Air 

### ojçecommendation las Fumes and M.ists Normal Use General Ventilation Exceed 

### TLV General Ventilation Special Thermal Spray Applications -- General Ventilation
Respiratory protection codes P.O Box 450246 

### fly Houston TX 77245-0246 Polymers ChemIcals 

### USA Toll free 

## 800 231-2066 Phone 

## 713 723-8416 Fax 

## 713 723-1845 

## URL www.EconomyPolymers.com E-mail economyeconomypolymerS.cOm



## KEY-H EC-1 -001606

# POLYMERS CHEMICALS

Particle-removing air purifying respirator 

### Dusk Mask Gas and vapor-removing air purifying respirator Canister Full thee 

### mask positive pressure-demand type air supplied Eye Protection Goggles and Face Shield in_Protectjon Neoprene Gloves and Nitrile Gloves Other Protective Equipment Chemical Resistant Apron and Shoes
Section IX Special Precautions Wear eye and skin protection Store in dry place Keep container closed to avoid moisture pickup Avoid creating dust clouds and breathing dust when handling Material slippery when wet Section Miscellaneous
Is product 

## RCRA regulated 

### No Are all ingredients listed in the 

### TSCA Inventory Yes Ingredients regulated by the Clean Air Act or the Clean Water Act Nine Environmental Effects 

### No data is available but the aquatic toxicity is probably in the moderate range 

## SARA Classification None 

### EPA Hazard Category 

### Non Comments Use good housekeeping procedures to minimize dust build-up

Polymers Chemicals P.O Box 450246 Houston 

### TX 77245-0246 

### USA Toil free 

## 800 231-2066 Phone 

## 713 723-8416 Fax 

## 713 723-1845 

## URL www.EconomyPotymerz.com E-mail economyeconomypoiyn1ers.com None needed



## KEY-H EC-1 -001607

# .4

PRODUCT 

# NAME REVISION 

# DATE

Section Product Information 

## and 

## Company Identification 

### Chemical 

# Name 

# BLEND Formula 

# NA DOT Hazard Class 

## Not Regulated 

# CANADIAN 

# ADR ICAOIIATA SEA 

# TRANSPORTATION 

# IMDG ALL 

# NOT RESTRICTED

Material 

### Iso-Alkanes/n-Alkanes Polysaccharide 

### blend
Section III 

## Hazards Identification 

### Hazard 

## Overview 

## May cause 

## eye skin and respiratory irritation 

## May cause headache dizziness 

### and other central 

### nervous system effects 

## May cause allergic respiratory reaction 

## May be harmful if 

### swallowed

Section 

## IV First 

## Aid Measures Eyes Flush thoroughly with running water at least 15 

### minutes 

## Remove contact lenses if 

## worn Get medical attention if irritations persist 

## Skin Remove contaminated clothing 

### and 

## wash contact area 

### with soap and water for 15 

### minutes 

## Do not reuse clothing until 

### thoroughly cleaned Get medical attention if irritations persist Inhalation In case 

### of exposure to 

### high concentration 

## remove person to fresh air If breathing has 

### stopped administer artificial respiration 

### and seek 

### medical attention Ingestion 

## Do not induce 

### vomiting Seek medical attention 

# Economy Polymers Chemicals 

# IEcoriorriy 

# WGP rId POLYMERS CHEMICALS 

# MATERIAL SAFETY 

# DATA SHEE ECOPOL-18Y2LMS 

# MARCH 11 2008 

## For Chemical Emergency Spifi 

## Leak Fire 

## Exposure or 

## Accident 

# CALL CHEMTREC Day or Night 800-424-9300 

## For International Call 703-527-3887 Collect Calls 

## Accepted 

# FOR INDUSTRIAL USE 

# ONLY

Section 

# II Composition Information 

## on Ingredients Cas Percent 

## TLVunits 

# NA 30-60 

# NA NA 0-60 

# NA

Section 

### Fire Explosion 

## Hazard Data
P.O Box 450246 Houston 

### TX 77245-0246 

## USA Toll free 

## 800 231-2066 

### Phone 

## 713 723-8416 

### Fax 

## 713 723-1845 

## URL www.EconomyPolymers.com E-mail 

### economyeconomypolymers.cOm



## KEY-H EC-1 -001608

# E.coriamy POLYMERS CHEMICALS

Extinguishing 

## Media Water spray 

# Foam C02 Dry Chemical Special Fire Fighting 

### Procedures 

## Wear self contained breathing apparatus to 

### avoid toxic 

## fumes Slippery 

## when wet 

## Do not 

### use direct stream 

### of water as material 

### can float 

### and reignite 

### on surface Fire 

### Explosion 

## Hazards Closed containers 

## may rupture 

## due to buildup 

### of pressure 

## when exposed to 

### extreme heat Cool drums exposed to 

### flames with water spray

Additional information will 

### be provided in 

### medical emergency to qualified 

### medical personnel Section 

# VI Accidental Release 

## Measures

Stop flow and contain spill 

### by diking sandbags etc Eljminate all ignition 

### sources Incirierate using afterburner 

### and scrubber 

# Use skin protection 

## as per section 

## VIII Absorb 

## on inert material 

### and scraps 

### up or shovel into 

### drums Obsei.ve federal spill 

### and water quality regulations 

### Section 

# VII Handling and Storage Handling Precautions 

## Avoid contact 

### with 

## eyes skin or clothing 

### Avoid breathing 

### vapors 

## Wash hands after 

## use Launder contaminated clothing before 

### reuse Storage 

### Information Store 

## away from oxidizers Store in cool well ventilated 

### area 

## Keep from heat sparks and open flames 

## Keep container closed 

## when not in 

## use
Section 

### VIII Personal Protection Information Air Exposure Recommendations 

## Normal Use General Ventilation
Respiratol.y protection 

### codes 

## None Needed Particle-removing air purifying respirator 

## Dusk 

# Mask Gas and vapor-removing air purifying respirator 

### Canister Full face 

## mask positive 

### pressure-demand type 

## Air Supplied 

## Eye Protection 

## Goggles Face Shield 

### Skin Protection 

### Neoprene 

## Gloves Nitrile 

### Gloves Other Protective 

## Equipment Chemical Resistant 

## Apron Shoes


# Economy Polymers Chemicals 

## Gas Fumes Mists Exceeds 

# TLV General Ventilation Special 

### Thermal Spray Application 

### General Ventilation



### P.O Box 450246 Houston 

### TX 77245-0246 

## USA Toll free 

## 800 231-2066 

### Phone 

## 713 723-8416 

### Fax 

## 713 723-1845 

## URL www.EconomyPolymers.com E-mail 

### economyeconomypolymers.com



## KEY-H EC-1 -001609

# E.canamy POLYMERS CHEMICALS

215F 475-560F Section 

## IX Physical 

## Data Autoignition 

# Temp pH range Flash 

### Point Boiling 

### Point Color Physical state Volatiles 

### Density 

## lbs/gal

Section Reactivity 

## Data Stability Stable 

### Hazardous Polymerization Will not occur Conditions to 

### avoid 

## Keep away from heat sparks and flame Incompatibility 

### Materials to 

## Avoid Strong oxidizers 

### Hazardous Decomposition Products 

## Fumes produced 

## when heated to 

### decomposition 

## may include oxides 

### of carbon 

# NFPA RATiNGS 

# HEALTH FLAMMABILITY REACTIVITY HIMS 

# RATINGS FLAMMABILITY REACTIVITY 

# HEALTH

Section 

# XI Toxicological 

### Information Threshold Limit Value 

# TLV for 

### Product 

## 5mg/m3 Does product contain 

### any 

# OSHA NTP or 

## IARC Carcinogens 

## No Nature of Hazard Physiological Effects Signs 

### Systems of Overexposure in the 

## Workplace Principle 

### Route of 

## Exposure Eye or skin 

### contact inhalation 

## Eyes 

## May cause irritation 

## Skin Causes drying 

### of the 

### skin 

## May cause mild irritation Inhalation 

## May cause respiratory irritation 

## May cause allergic reaction 

## May cause 

### chemical 

## pneumonia 

## May cause nervous system depression including 

### headache dizziness 

### drowsiness incoordination 

### slowed reaction 

## time slurred 

### speech giddiness and unconsciousness Ingestion Irritation 

### of the 

## mouth throat 

### and 

## stomach Aspiration into the lungs 

## may cause chemical pneumonitis including 

### coughing difficulty 

### breathing 

## wheezing coughing up blood and 

## pneumonia which can be fatal 

## May cause central 

### nervous system depression including 

### headache dizziness 

### drowsiness muscular 

## weakness incoordination 

### slowed reaction 

## time fatigue blurred 

### vision slurred 

### speech giddiness tremors and convulsions 

# MEDICAL CONDITIONS 

# GENERALLY RECOGNIZED AS BEING 

# AGGRAVATED BY EXPOSURE Skin disorders 

# Economy Polymers Chemicals P.O Box 450246 Houston 

### TX 77245-0246 

### USA Toll free 

## 800 231-2066 

### Phone 

## 713 723-8416 

### Fax 

## 713 723-1845 

## URL www.EconomyPolymers.com E-mail 

### economyeconomypolymers.com Beige liquid 

# ND 8.51 

## Odor Specific Gravity 

## Vapor Density 

# ND 6.5-8.0 

### Hydrocarbon 1.02 

# ND

KEY-H EC-1 -001610

# _p 

# Ecar.amy POLYMERS CHEMICALS
Section XII Ecological Information 

## No data available
Section 

### XIII Disposal Considerations Disposal 

## Method Disposal 

### should be 

## made in 

### accordance with federal state 

### and local regulations 

### Contaminated Packaging Follow all applicable national or local regulations 

# DOT Not Regulated Canadian 

# TDG Not restricted 

# ADR Not Restricted 

## ICAO/IATA Not Restricted 

# IMDG Not Restricted 

### Harmonized Tariff 

## Code 2901.10.50

Section 

# XV Regulatory Information Is 

### product 

# RCRA regulated 

## No Are all ingredients listed in the 

# TSCA Inventory Yes Ingredients regulated 

### by the 

### Clean Air Act or the 

### Clean Water 

## Act None 

# EPA SARA 

# 311312 Hazard Class Acute Health Hazard
Section 

# XVI Miscellaneous Disclaimer 

### This information is furnished without warranty expressed or implied as to accuracy for completeness This information is obtained from various sources including the manufacturer and other third party sources The information 

### may not be valid under all conditions nor if this material is used in combination with other materials or in any process Final determination of suitability of any material is the sole responsibility of the user



# Economy Polymers Chemicals P.O Box 450246 Houston 

### TX 77245-0246 

## USA Toll free 

## 800 231-2066 

### Phone 

## 713 723-8416 

### Fax 

## 713 723-1845 

## URL www.EconomyPolymers.com E-mail 

### economyeconomypolymers.com Section 

## XIV Transport Information



## KEY-HEC-1 -001611Material Safety Data Sheet 

# 1A PlexsurfWftS

STORAGE Flammable materials should be stored in separate safety storage cabinet or 

### room Keep 

### away from heat 

### Keep away from sources of ignition 

### Keep container tightly closed 

### Keep in cool welt-ventilated place Ground all equtpment containing material refrigerated room would be preferable for materials with flash point lower than 

### 37.8C 

# 100F 

# L_
SECTION \IIl 

## PRO1 LCTIVF 

# CLOT IING
RESPIRATORY PROTECTION Wear appropriate respirator 

### when ventilation is inadequate 

### PROTECTIVE CLOTHING/EQUIPMENT Splash goggles lab cotIapron gloves 

# SECTIONI TRANSPORTATION 

# DATA
PROPER SHIPPING 

## NAME Flammable liquid n.o.s 

### HAZARD 

## CLSS UN 

## NUMBER UN 1993 

### PACKAGING 

## GROUP II 

## RQ N/A 

## DOT SHIPPING Flammable liquid n.o.s Contains Methyl Alcohol 

## UN 1993 

## PG This material is classified as marine pollutant due to its content ol dodecylbenzene sulfonic acid salts 

## SECTION 

## OTHER 

# REGULATORY INFORMATION
TSCA sTATUS Al components of this product are listed on the 

## TSCA inventory 

## NFPAHEALTH NFPA 

### FLAMMABILiTY NFPA REACTIvrrY


## SECTION XI 

## ADDITIONAL INFORMATION
PREPARED 

## BY Edward Vinson 

# EMERGENCY RESPONSE 

# NUMBER 800

Page of4



## KEY-H EC-1 -001630Material Safety ftita Sheet 

# Plexsurf 

# WRS

tissues are 

### damaged possible indication that the toxic material 

### was ingested the absence of such signs 

### however is not conclusive Loosen tight clothing such
as collar tie belt or waist 

### hand If the victim is not breathing perform mouth-to-mouth resuscitation Seek medical attention EYE 

## CONTACT Check for and remove any contact lenses Immediately flush eyes with running water for at least 15 minutes keeping Eyelids 

### open Cold water 

### may be 

### used Do 

## NOT use an eye ointment Seek medical attention SKIN 

## CONTACT If the chemical got onto the clothed portion of the 

### body remove the contaminated clothes as quickly as possible protecting your 

### own hands and 

### body Place the victim under deluge 

### shower If the chemical touches the victims exposed skin such as the 

### hands Gently and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be particularly careful to clean folds crevices creases and groin 

## COLD water 

### may be 

### used Cover the irritated skin with an emollient
If irritation persists seek medical attention 

### Wash contaminated clothing before reusing 

# FCTION Vii 

## SPILL 

# SIORAG AND DiSPOSAL 

# DA 1A

SPILL 

## SMALL Dilute with water and 

### mop up or absorb with an inert 

## DRY material and place in an appropriate waste disposal container 

## LARGE SPILL Keep away from heat 

### Keep away from sources of ignition Stop leak if without risk Absorb with 

## DRY earth sand or other non-combustible material 

## DO NOT touch spilled material Prevent entry into sewers basements or confined areas dike if 

### needed Eliminate

all sources of ignition 

### WASTE DISPoSAL Whatever cannot be saved for recovery or recycling should be 

### managed in an appropriate and approved waste disposal facility Processing use or contamination of this product 

### may change the waste 

### management options State and local disposal regulations 

### may differ from federal disposal regulatrons Dispose of container and unused contents in accordance with federal state and local requirements 

### HANDLING Keep locked 

### up Keep 

### away from heat Keep 

### away from sources of ignition Ground all equipment containing material 

## DO NOT ingest 

### Do not breathe 

### gas fumes vapor or spray In case of insufficient ventilation wear suitable respiratory equipment If ingested seek medical advice immediately and 

### show the container or the label Avoid contact with skin and eyes 

### Keep away from incompatibles as oxidizing agents



### Page ol4



## KEY-H EC-1 -001631Material Safety ata Sheet 

# Plexsurf 

# WRS

EXTINGUISHING MEDIA Flammable liquid soluble or dispersed in water FIRE 

### FIGHTING PROCEDURES 

## SMALL FIRE Use 

## DRY chemicals 

## C02 water spray or alcohol 

### foam 

# kARGE_F Use alcohol 

### foam water spray or fog Cool containing vessels with water jet in order to prevent pressure build-up autoignition or explosion 

### EXPLOSION 

## HAZARDS Explosive in the form of vapor 

### when exposed to heat or flames Vapor 

### may travel considerable distance to source of ignition and flash back 

## When heated to decomposition it emits acrid 

### smoke and irritating 

### fumes Methyl alcohol


## SECTION 

## REACTIVITY 

# DATA

STABILFfl This product is stable 

### CORROSIVrIY Non-corrosive in presence of glass 

### REACflV11Y Highly reactive with oxidizing agents 

# LSEcTTON VT 

# HEALTH HAZARD IATA

ROUTE OF ENTRY Ingestion Inhalation 

### ACUTE EFFECT 

## ON HUMANS Slightly dangerous to dangerous in case of skin contact irritant of eye contact irritant of ingestion of inhalation Very slightly to slightly dangerous in case of skin contact 

### permeator CHRONIC EFFECTS 

## ON HUMANS

.. 

### The substance is toxic to the nervous system the reproductive system Passes through the placental barrier


## SECTION 

# VIB-FIRST AID
INHALATION SLIGHT 

## INHALATION Allow the victim to rest in well ventilated area Seek immediate medical attention 

## HAZARL.QS INHALATION Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie belt or waistband If breathing is difficult administer oxygen If the victim is not breathing perform mouth-to-mouth resuscitation 

## WARNING It 

### may be dangerous to the person providing aid to give mouth-to-mouth resuscitation 

### when the inhaled material
is toxic infectious or corrosive Seek medical attention 

### INGESTION 

## SLJGHTjjESTION Do not induce vomiting Have conscious person drink several glasses of water or milk 

### Seek immediate medical attention 

## HAZARPQQS INGESTION Do 

## NOT induce vomiting Examine the lips and mouth to ascertain whether the



### Page of



## KEY-H EC-1 -001632

## MJ$afCtY Data Sheet 

# PlexsurfWRS

DATh PREPARED 05/19/04 

### them le REVISION 

### DATE 10/08/04



### _____ 506 

## CR 1071 

### EMERGENCY NUMBER...800-633-8253 

# Ll Snyder 79549 

### PRODUCT 

## NuMBER 00826 

## 325 573-7298



## SECTION IDENTIFICATION
PRODUCT 

## NAME PlexsurfWRS 

## SYNONYMS N/A 

### CHEMICAL FAMILY Surfuctants 

### CAS 

## NUMBER N/A 

### PRODUCT 

## USE Petrochemical industry 

## SECTION II- 

# HAZARDOUS INGREDIENTS HAZINGREDIENT PERCENT CAS 

## NUMBER PEL METHYL ALCOHOL 60% 67-56-1 Not Available Dodecylbenzene 15-20% 6864.8-81-7 Not Available Sulfonic 

### 4id Salts


## SECTION III 

## PHYSICAL 

# DATA
APPEARANCE Pale Yellow liquid 

## ODOR Alcohol like slight 

### BOIUNG POINT 

## 1700 FLASHPOINT 

# 56F Open Cup VAPOR DENSITY 

# AIR1 1.11 SPECIFIC 

### GRAViTY 

# WATER1 0.95 

### pH 

# 1% SOIN/WATER Neutral 

## SOLUBILY Easily soluble in cold water hot water methanol diethyl ether 

# WI 7.93 per gallon 

## SECTION IV 

## FIRE 

# AND EXPLOSION 

# DATA
FLASHPOINT 

# 56F Open Cup FLAMMABII 

## UM1TS 

## LOWER 6% Methyl Alcohol 

## UPPER 36.5 Methyl Alcohol 

### FLAMMABLE 

## HAZARDs Highly flammable in presence of open flames and sparks of heaL of combustible materials



### Page of



## KEY-H EC-1 -001633Material Safety Data Sbeet 

# Plexsurf 

# WRS

EXTINGUISHING MEDIA Flammable liquid soluble or dispersed in water FIRE FIGI-ITING 

### PROCEDURES 

## SMALL FIRE Use 

## DRY chemicals 

## C02 water spray or alcohol 

### foam 

## LARGE FIRE Use alcohol 

### foam water spray or fog Cool containing vessels with water jet in order to prevent pressure build-up autoignition or explosion 

### EXPLOSION HAZARDS Explosive in the form of vapor 

### when exposed to heat or flames Vapor 

### may travel considerable distance to source of ignition and flash 

### back 

## When heated to decomposition it emits acrid 

### smoke and irritating 

### fumes Methyl alcohol


## SECTION 

## REACTIVITY 

# DATA

STABILITY This product is stable 

### CORROSIVITi Non-corrosive in presence of glass 

### PEACrIvflY Highly reactive with oxidizing agents 

## SECTION VI 

# HEALTH HAZARD DATA
ROUTE OF ENTRY Ingestion Inhalation 

### ACUTE EFFECT 

## ON HUMANS Slightly dangerous to dangerous in case of skin contact irritant of eye contact irritant of ingestion inhalation Very slightly to slightly dangerous in case of skin contact 

### permeator CHRONIC EFFECTS 

## ON HUMANS

.. 

### The substance is toxic to the nervous 

### system the reproductive 

### system Passes through the placental barrier 

## SECTION VI 

## FIRST 

## All INHALA11ON 

## SUGHTINHAL4TION Allow the victim to rest in well ventilated 

### area Seek immediate medical attention 

## HAZARDOUS INHALATION Evacuate the victim to safe area as soon as possible Loosen tight clothing such as collar tie belt or waisthand If breathing is difficult administer 

### oxygen If the victim is not breathing 

### peform mouth-to-mouth resuscitation 

## WARNING It 

### may be dangerous to the person providing aid to give mouth-to-mouth resuscitation 

### when the inhaled material is toxic infectious or corrosive 

### Seek medical attention 

### iNGESTiON SLiGHT 

## INGES71ON Do not induce vomiting 

### Have conscious person drink several glasses of water or milk Seek immediate medical attention 

## HAZARDOUS INGESTiON Do 

## NOT induce vomiting Examine the lips and mouth to ascertain whether the



### Page of



## KEY-H EC-1 -001634Material Safety Data Sheet 

# Plexsurf 

# WRS

tissues are 

## damaged possible indication that the toxic material 

### was ingested the absence of such signs however is not conclusive Loosen tight clothing such as collar tie belt or waist 

### band If the victim is not breathing perform mouth-to-mouth resuscitation 

### Seek medical attention EYE 

## CONTACF Check for and remove any contact lenses Immediately flush eyes with running water for at least 15 minutes keeping eyelids 

### open Cold water 

### may be 

### used Do 

## NOT use an eye ointment 

### Seek medical attention SKIN 

## CONTACP If the chemical got onto the clothed portion of the 

### body remove the contaminated clothes as quickly as possible protecting your 

### own hands and 

### body Place the victim under deluge 

### shower If the chemical touches the victims exposed skin such as the 

### hands Gently and thoroughly 

### wash the contaminated skin with running water and non-abrasive 

### soap Be particulaily careful to clean folds crevices creases and groin 

## COLD water 

### may be 

### used Cover the imtated skin with an emollient If irritation persists seek medical attention 

## Wash contaminated clothing before reusing 

## SECTION VII 

## SPILL 

## STORAGE 

# AND DISPOSAL 

# DATA

SPILL 

## SMALL SPILL Dilute with water and 

### mop up or absorb with an Inert 

## DRY material and place in an appropriate waste disposal container 

## LARGE SPILL Keep away from heat 

### Keep away from sources of ignition Stop leak if without risk Absorb with 

## DRY earth sand or other non-combustible material 

## DO NOT touch spilled material Prevent entry into sewers basements or confined areas dike if 

### needed Eliminate all sources of ignition 

## WASTE DISPOSALS Whatever cannot be saved for recovery or recycling should be 

### managed in an appropriate and approved waste disposal facility Processing use or contamination of this product 

### may change the waste 

### management options State and local disposal regulations 

## may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state 

### and local requirements 

### HANDLING Keep locked 

## up Keep away from heat 

### Keep away from sources of ignition Ground all equipment containing material 

## DO NOT ingest 

### Do not breathe 

### gas fumes vapor or spray In case of insufficient ventilation 

### wear suitable respiratory equipment If ingested seek medical advice immediately and 

### show the container or the label Avoid contact with skin and 

### eyes Keep away from incompatibles as oxidizing agents



### Page of4



## KEY-H EC-1 -001635Material Safety Data Sheet 

# PlexsurfWRS

Flammable matenals should be stored in separate safety storage cabinet or 

### room Keep away from heat 

### Keep away from sources of ignition 

### Keep container tightly closed 

### Keep In cool well-ventilated place Ground all equipment containing material refrigerated room would be preferable for materials with flash point lower than 

### 37.8C 

# 100F
SECTION VIII 

## PROTECTIVE CLOTHING RESPIRATORY PROTECTIONS Wear appropriate respirator 

### when ventilation is inadequate 

### PROTECTIVE CLOTHING/EQUIPMENT Splash goggles lab coat/apron gloves 

## SECTION IX 

## TRANSPORTATION 

# DATA
PROPER SHIPPING 

## NAME Flammable liquid n.o.s 

### HAZARD 

## aASS UN 

## NUMBER UN 1993 

### PACKAGING 

## GROUP II 

## RQ N/A 

## DOT SKIPPING Flammable liquid n.o.s Contains Methyl Alcohol 

## UN 1993 

## PG II This material is classified as marine pollutant due to its content of dodecylbenzene sulfonic acid salts 

## SECTION 

# OTHER REGULATORY INFORMATION TSCA STATUS All components of this product are listed on the 

## TSCA inventory 

### NFPA 

## HEALTH NFPA FLAMMABILI1Y NFPA REACTIVITY


## SECTION ADDITIONAL INFORMATION
PREPARED 

## BY Edward Vinson 

# EMERGENCY RESPONSE 

# NUMBER 800-633-8253

Page of



## KEY-H EC-1 -001636

# MATERIAL SAFETY DATA Xylene 

# SHEET

NFPA

Product 

## And Company ldentficatiOn 

### Suopher Manufacturer 

### Chemplex 

# LC C1empeX b.c P.O Box 1071 

## P.O Box 1071 

## 506CR137 506CR137 Snyder1 

### TX T9560 UntIed States 

### Snyder TX T9550 United Slates Telephone 

## Number 

## 325 573-7298 

### Telephone 

## Number 

## 325 573-7298 

## FAX Number 

## 325 573-3340 

## FAX Number 

## 325 573-3340


### SuDoher Emeraencv Contacts 

### Phone 

## Number Manufacturer EmeroeflCV Contacts 

### Phone Number 

## 800 633-8253 

## 800 633-8253

Issue Date- 08121/2002 Product 

## Name Xylene Chemical 

## Name Dimethylbenzefle 

## CAS Number 1330-20-7 Chemical 

### Family Aromatic hydrocarbon Solvent Chemical 

### Formula 

## C6H4CH32 MSDS Number 109 

### Synonyms XyloJ ProductlMaterial 

### Uses
Industrial Applicatins Solvent for organic products paraffin Composition/InformatiOn 

## On Ingredients 

# frnt CAS PenitOf

Name Iktnber Total Weight XYLENE 1330-20-7 95-100
Hazards Identification Primary 

## Routess Of Entry contact Ingestion Skin contact inhalation 

### Eve Hazards Extremely dangerous in case of eye contact Skin Hazards Extremely dangerous in case of skin contact irritant 

### permeator Innestion Hazards Very dangerous in case of ingestion

ptIor4



## KEY-H EC-1 -001646

# MATERIAL SAFETY DATA SHEET Xylene

Hazards Identification Continued
Inhalation Hazards Very dangerous in case of Inhalation ChroniclCarcinooenicitv Effects 

### The substance is toxic to blood kidneys liver Reoroductive Effects Not available 

### NeuotoxAiti Narcotic effect 

### may cause nervous system disturbances Conditions Apriravated 

### By Exposure Material is irritating to 

### mucous membranes and upper espratoiy tract

First Aid 

### Measures
Check for and remove any contact lenses 

### Do not use an eye ointment 

### Seek medical attention Skin

If the chemical got onto the clothed portion of the 

### body remove the contaminated clothes as quickly as possible protecting your 

### own hands and 

### body Place the victim under deluge 

### shower It the chemical touches the 

## ctrns 

## posed shin suth as The 

## ands Oen1y and 

### Thorougy wasn The cmltaTnWiated 

# Æn âth 

## nmmng water and non-abrasive 

### soap Be particularly careful to clean folds crevices creases and groin 

## COLD water 

### may be 

### used Cover the irritated skin with an emollient II iritaiion persists seek medical attention 

### Wash contaminated cfoltung beibre reusing 

## HAZARD SKIN 

## CONTACT Wash with disinfectant soap and cover the contaminated skin with an
anti-bacterial 

### cream The product is solvent irfltaling for the skin Xylene is insoluble in water It the victim sti suffers after iong term ænsung wtih water 

## we suggest to ænse the contaminated area 

### SK%N 

## OR EYES with lukewarm pasteurized milk After the pain has stopped rinse thoroughly with wnnrig water to avoid possible infection Milk is very good emulsifier and it is also very mild for skin and 

### eyes Seek medical attention lnaestion 

## DO NOT INDUCE 

# VOMmNG Have conscious person drink several glasses of water or milk Seek immediate medical attention Inhalation Allow the victim to rest in well ventilated area 

### Seek immediate medical attention
Fire Fighting 

### Measures Flash Point 100 Flash Point 

## Method Open cup Autoignition 

### Point 567.2 

### Lower Explosive Limit 1.1% 

### Upper Explosive Limit 

## 7%
Fire 

### And Explosion Hazards 

## rigt 

# wmab scesevce olt 

### opec flames 

### avd 

# spcs oc %eat of 

# co
Slightly flammable to flammable in presence of oxidizing materials of reducing materials Vapors 

### may travel considerable distance to source of ignftion and flash 

### back Extinciulehing 

### Media Flammable liquid insoluble in water



### Pane of



## KEY-H EC-1 -001647

# MATERIAL SAFETY DATA SHEET Xylene

Fire Fighting 

### Measures Continued Fire 

### Fiphtin InStructions 

### SMALL 

## ARE Use 

## DRY chemicals 

## C02 alcohol foam or water spray 

## LARGE FIRE Use water spray fog or 

### foam Cool containing vessels with water jet in order to prevent pressure build-up autoiginition or explosion Accidental Release 

## Measwes Small Spill and 

### Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal Large Spill and 

### Leak Flammable hquid Insoluable in water 

### Keep away from heat 

### Keep away from sources of Ignition Stop leak if without risk Absorb with dry earth sand or other non-combustible material 

## DO NOT touch spilled material Prevent entry into sewers basemenis or confined areas dike if 

### needed Eliminate aft sources of ignition Call for assistance on disposal

Handling 

## And Storage Handling 

## And Storaoe Precautions 

### Keep away from heat 

### Keep away from sources of ignition Ground all equipment containing matenal 

## DO NOT ingest 

### Do not breathe 

### gas fumes vapor or spray In case of insuffident ventilation wear suitable respiratory eqllpnierit If ingested seek medical advice immediately and 

### show the container or the label Avoid contact with skin and eyes 

### Keep away from licompatibles as oxidizing agents reducing agents organic materials metals alkalis Flammable materials should be stored Vi separate satety storage cabinet or 

### room Keep away from heat 

### Keep away from sources of Ignition 

### Keep container tightly closed 

### Keep in cool well-ventilated place Ground all equipment containing material refrigerated 

### room would be preferable for materials with flash point lower than 

### 378 

## 100
Protective Clothina 

## Pictoorws



# nan

Exposure ControlslPersonal Protection Eve/Face Protection Splash goggies Skin Protection Apron/Lab coat Gloves Resoiratory Protection 

### Be sure to use an approveWcettiflecl respirator or equivalent Physical 

## And Chemical Properties 

### Anoearance Colotless to pale 

### amber bquid
Aromatic 

## stror Chemical 

## Type Pure Physical State Uquki Boiling 

### Point 251.3


### PaDP 015



## KEY-H EC-1 -001648

# SHEET MATERIAL SAFETY DATA Xylene

Physical 

### And Chemical Properties Continued 

### Odor Continued Specdlc Gravity 0.86 

## waterl Vapor Density 

## 37 air1 Solubility methanol diethyl etther 

## 10 Stabfffty 

## And Reactivity Stability This product is stable 

### nconiatibe tl.aterta%s Highly reactive with oxidizing agents Slightly reactive to reactive 

# wh reducing agents metals organic materials alkalis


### 11 Toxicological Information Eve Effects 

## reme%y dangerous in case ot eye contact 

## irrar Skin Effects Exfremely dangerous in case of skin contact Acute Oral Effects Very dangerous in case of ingestion Acute Inhalation Effects Very dangerous in case of inhalation
ClironiclcarcinOoeflicftV 

### The substance is toxic to the blood kidneys liver Reoroductive Effects Not Available Neurotoxlcitv Narcotic eflbct 

### may cause neivous system disturbances Conditions 

### Awuavated By EXDOSUre Material is irritating to 

### mucous membranes and upper resçatnty tract 

### 12 Ecological Information 

### No Data AvaHabe.. 

### 13 Disposal Considerations Wtiatever cannot 

### be saved 

### br recovery or recyding 

## ioud be managed in an approfMiate and approved waste disposal facildy Processing use or contamination of this product 

### may change the waste 

### management options State and local disposal regulations 

### may differ from federal disposal regulations Dispose of contamer and unused contents in accordance 

# th federal slate 

### and local requirements



### ______________________________________________ 

## 14 Transport Information Prooer Shipping 

## Name Xylenes 

## UN 1307 

## PG II 

## RQ13 gailons 

# xyet

Paoe of



## KEY-H EC-1 -001649

# MATERIAL SAFETY 

# DATA SHEET Xylene CHEMICAL 

# PRODUCT AND COMPANY IDENTIFICATION

lrpduct Identification Product 

### Name Xvlcne Synonyms Z-l0 

### CAS Number Blend Company Identification


### MidndIX79706 USA 

# FIJEIEF

1432-560-5601 For product in formation 1-800-535-5053 For emergencies 

# COMPOSITION/INFORMATION 

# ON INGREDIENTS

COMPONENT LISTiNG

XYLENE Condentia1 133I-20-7 

### ETHYLBENZENE Confidential 100-41-4 

## TO 

## UUN ConIiiential See Se.tiou 1o exptuute guidelines See Section IS for repulatorv information 

### HA1.ARS IHSCIOS1 RI

flii prudit Loitaius hazardous oatciials defiied the CJSfl Haiazd Cu iuaieutioii Smdard CUR ft 20ft

deined under Sdra 311 and 312 this product oataii1s materials tiiàt are acute chiouic tire hazards 

# FIAZARDS 

# IDENTIFiCATION E1ERFNCY OVFRVIFV lmtating to the eyes and skin lhis prodoct conlains ethyiheozene The TARC has caluted and classified it as possible human carcinogen grotto 2Ri hascd ciii airial ej\inicIit liHntIctc 1uid 

### HMIS Ratiug I111h Hanintahilu

Rezsctiity Pc 

### ro al Po it tct In 

### dy POlEYFIAL IIEALTII 

## EFFE TS 

## EYE

KEY-H EC-1 -001650Xylne 3uge of RTLt Nurnbe 00000473 April 2007
irritating but does not injure eye tisSue SKINt Frequent or prolonged contact may irritate Low order o1toxiitv Occasional brief contact with the liquid will not result in significant initation unless evaporation is impeded Skin contact may aggravate an existing dermatitis condition 

### INHALATION High vapor/aerosol concentrations greater than approximately 

## XX ppm are irritating to the eyes and the respiratory tract may
cause headaches dizziness anesthesia drowsiness unconsciouoess and other central nervous system effects including death Negligible hazard at ambient temperature -1 to 38 Deg to 

### 1X dee 

### iNGESTION Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury possibly progressing to death Low order ottoxicity 

### CHRONIC EFFECTS This product contains ethvlbenzene The international agency tir research on cancer 

## ARC has evaluated ethylbenzene and classified it as possible human carcinogen group 

## 23 Based on sufficient evidence for carcinogenicity in experimental animals but inadequate evidence kit cancer in exposed humans 

### REPRODUCTIVE 

## HAZARDS Nune 

### Known CARCINOGENICITY 

## INFORMATION Possible cancer hazad based on tC5t with Iahoratorr- animol 

## TARGET 

## ORGAN Eyes Skin Respiratory Tract 

## FIRST 

# AID 

# MEASURES
EYE 

## CONTACT FIRST 

### AID After initial flushing remove any contact lenses and cOntinue flushing for at least IS ntinulC5 let medical attention if irritation develops or persists SKIN 

## CONTACT FIRST 

### AID Immediately 1ush skin with plenty of water for at least 15 minutes Get medical attention if irritation develops or persists 

### INHALATION FIRSt 

### All Using proper respiratory protection immediately remove the attected victim from exposure Administer artificial respiration ii breathing is stopped Keep at rest Call fur proilipt medical attention 

### INGESTION FIRST 

## AID

If swallowcd do not induce vomiting Keep at rest jet prompt medical attention 

# FIRE 

# FIGHTING MEASURES
FLAMM ABLE PROP ERTIFS 1CC Flash Point 26.1 79.0 Autoignition Temperature N/A 

## FLAMMABLE LIMITS 

### AIR 1FF N/A tjFL 

## NA FLAMMABLE PROPERTiES liihIv Flainmahle



## KEY-H EC-1 -001651Flamniable liquiI can release .apors that krm flammable niixtures at teniperatuies at 

### orabo the flashponi FIRE 

### FEGHTING iNSTRUCTIONS Avoid spraying water directly into storage cootaincrs due to darigcr ofboilovcr 

## COMBUSTION PRODUCTS Smoke Carbon lioxide Carbon Monoxide Oxides of Nitrogen 

# ACCIDENTAL RELEASE MEASURES
SAFEGUARDS 

## PERSONNEL Avoid breathing vapor Eliminate all sources of initiou heaL sparks ilauc electricity impact and friction Wear appropriate personal protective equipment INITIAL 

## CON FAIN 

## MENT Contain spilled material Eliminate all sources of ignition heat sparks flame electricity and impact Absorb spills with inert material Treat or dispose olwask material in aeordance with all local state/provincial and national requirements 

## LARGE SPILLS 

## PROCEDURE Contain spilled material Eliminate all ignition surccs Absorb spill with inert material dry sand or earth then place in chemical waste container Treat or dispose of waste material in accordance with all local stntcprovincial and national requirements 

## SMALL SPILLS 

## PROCEDURE Secure the spill area Absorb spills with inert material Treat or dispose uf waste material in accordance with all local state/provincial and national requirements 

# HANDLING AND STORAGE
HANDLING 

## PERSONNEL Avoid breathing vapors Do not get iii eves on skin or clothing Ground and bond containers when transferring material 

### UA\DLI PIIVSICU ASPEC 

## IS Eliminate all sources of ignition heat sparks flame electricity impact and friction 

## STORAGE PRECAUTIONS Avoid extreme temperatures SPFTCJ4L SFNSIflVliY Material will accumulate static charges wInch may cause an electrical spark Ignition source Use proper hondtng and/or grounding procedures Containers may contain product residue lo not reu.e empty coniainer without commercial cleaning or reconditionint 

# EXPOSURE CONTROLS PERSONAL PROTECTION
ENGINEERiNG 

## CONTROLS

he use of local exhaust ventilation is recommended to control process emissions near the sostrcc laboratory atnplcs should be handled in lab hood Provide mechanical ventilation of confined spaces 

### FACE PROTFCIION 

## REQUIREMENTS

KEY-H EC-1 -001652When splashing of the material may occur chemical goggles and face shield are recommended SKIN 

### IROIEC 

## HON REQUIRLMENTh Wear protective gloves to minimize skin contamination 

### RESPIRATORY PROTECTION 

## REQUIREMENTS Use NIOSH approved organic vapor respirator when exposed to vapor from heated material 

### EXPOSURE CUIDELINES XYLENE OSHA PEL 100 

### ppm 435 

# mm3 OSHA 

## TWA 100 

### ppm 435 

### mgmt3 ACGIH 

## TWA 100 

### ppm 434 rng/m3 

### OSHA STEL 150 ppm 

### 1OLUENE 081-IA 

## TWA 100 

### ppm 375 

### mg/m3 ACGIH 

## TWA 101 ppm OSI-IA 

### STEL 150 

### ppm 560 mgimA3 ACGIH 

### STEL 150 ppm 

# PHYSICAL 

# AND CHEMICAL PROPERTIES FORM Liquid 

## COLOR Clear 

## ODOR Sols cut BOILING 

### POINT 252 286 

### VAPOR PRESSURE 14.2 

## mm Hg 100 

### VAPOR DENSITY 3.7 Air SOLUB1LITY IN 

## WATER 0.02 at 77 SPECIFIC 

### GRAViTY 087 Water 

### BULK DENSiTY 7.256 pounds per gallon MELTiNG/FREEZING 

### POINT -48 Pit 

## NT

VOLATILES 

## ND VISCOS1IY 0.7 77 

### EVAPORATION RATE 0.8 approx


## 10 

# STABILiTY 

# AND REACTIVITY
STABILITY Stable 

### POIY \IERIZAlION Hazardous polymerization will not occur 

### INCOMPATIBiLITY VITII 

## OTHER 

## MAERIAIS Strong acids alkalies and oxidizers such as liquid chlorine hydrogen peroxide and oxygen 

## DECOMPOSITION Decomposition may produce fumes smoke oxides of carbon and hydrocarbons


## ii 

# TOXICOLOGICAL INFORMATION
XYLENE lest Code Oral



## KEY-H EC-1 -001653Species Rat Results 3.523 mg/kg 

## NIP TR 327

Test Code Inhalation LC5O Species Rat Results 5000 pprni4 Hr 

## RTECS

Test Code Demial LULo Species Rabbit Results 

### mLkg

Test Code Inhalation LCLo Species Human Results 10000 ppm/6 Ut


## 12 

# ECOLOGICAL INFORMATION

No information available


## 13 

# DISPOSAL 

# CONSIDERATIONS
WASTE DISPOSAL Treat or dispose of waste material in accordance with all local state/provincial and national requirements


## 14 

# TRANSPORTATION 

# INFORMATKN
PRODUCT 

## LABEL Xylene 

# DOT SI1IPPIN 

# NAM Xyleoes3tT4l 307PGlil D.O.T 

## HAZARI CLASS Flammable Liquid 

### UN 

## NUMBER 1307 

### PTODUCT 

# RQLBS 111 pounds based on xyicnc 

# DOT LABEL Flammable -3 

### D.OT 

## PLACARD UN 1307 

### PACKAGE CLASS PG III


## 15 

# REGULATORY INFORMATION

Canadian Disclosure tJst 

### ETHYLBENZENE l00-41-4i 

### SARA Title 111 Section 313 

### XYLENF 330-207 

### FTHYLBENZENE 10041-4 CERCLA Hazardous Substances 

### XYLENE 1330-20-7 

### RQ 100 lb 

### ETHYLBENZENE l00-41-4iRQ 1000 lb TOLLJENF 

### l0-8S-3

-- 

### RQ 1000 lb 

## RCRA Hazardous Substances XY1.ENE 330-20-7
-- 

### RCRA Code U239 lOLL I.NE 

# lO--3 RCRA Code L220



## KEY-H EC-1 -001654Xylene Page of .TN Eutnbei 

### OLC-73 jrii 11 2C07

Title 

### XYLENE 1330-20-7 

### ETHYLBENZENE 100-41-4 

### TOUTFNE OS-8-3 

### CA ProposItion 

### TOLUENE l08-S8-3 SC toxic Air hfllutains List 

### XYLENE 1330-20-7 

### LTHYLBENZENE 100-41-4 TOLIJFNE3 lOS-8S-3 

### MISCELLANEOUS 

## NFORMAT1ON

1hi.s material or all of its components are listed on the Inventory of ExisLing Chemical Substances under the Toxic Substance Control Act 

# TSCA
16 

# OTHER INFORMATION
REASON FOR ISSUE Revision 

### PREPARED 

## BY Tom Roland 

### APPROVED 

## BY Tom Roland TITLE Director of Safety Envronrnental 

### APPROVAL 

## DATE April 11 2007 

### SUPERCEDES DA IL January 27 2007 RTN 

## NUMBER 00000473 OfficIal 

### Cups REVISION 

## STATEMENT Section information has been updated Ingredients added Section information has been updated Physical properties updated Section 10 information has been updated Incompatibility inkrInation updated Section 14 information has been updated Reportable quantity updated 

### DOT description 

### UN number updated 

### ADDiTiONAL 

## INFORMATION The data in this Material Safety Data Sheet relates only to the specific material designated herein It does not relate to use in combinaLion with any other material or in any process

This iitcwmation is furnished without warriniy expressed or implied except that it is accurate to the best knowledge of Reef Services 

### LLC The data on this sheet arc related only to the specific material designated herein Reef Services LLC assumes no iegul responsibility for use or reliance upon these data


### ENI OF MSDS



## KEY-H EC-1 -001655