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Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT C: FLASHING EMISSIONS CALCULATIONS 

• E&P Tanks Emission Summary

• E&P Tanks Linear Relationship (Emission Factor)
Van Hook Field 1000 BOPD wt%

******************************************************************************************

* Project Setup Information *

******************************************************************************************

Project File : Y:\Projects\Williams Exploration & Production WEP\WEP211324 Ft. Berthold

IR Well Work\E&P Tanks\Van Hook Field 1000 BOPD.ept

Flowsheet Selection : Oil Tank with Separator

Calculation Method : RVP Distillation

Control Efficiency : 100.0%

Known Separator Stream : Low Pressure Oil

Entering Air Composition : No

Filed Name : Van Hook

Well Name : Pennington 16-15H and Van Hook 16-14H Averages

Permit Number : Dakota-3 E&P Company, LLC

Date : 2010.09.24

******************************************************************************************

* Data Input *

******************************************************************************************

Separator Pressure : 52.00[psig]

Separator Temperature : 90.00[F]

Ambient Pressure : 13.70[psia]

Ambient Temperature : 50.00[F]

C10+ SG : 0.7970

C10+ MW : 233.494

-- Low Pressure Oil ----------------------------------------------------------------------

 No. Component wt %

 1 H2S 0.0027

 2 O2 0.0000

 3 CO2 0.0038

 4 N2 0.0008

 5 C1 0.0261

 6 C2 0.3417

 7 C3 1.3723

 8 i-C4 0.3662

 9 n-C4 1.6928

 10 i-C5 0.6858

 11 n-C5 1.2496

 12 C6 1.4712

 13 C7 7.9550

 14 C8 19.2940

 15 C9 13.4810

 16 C10+ 49.4241

 17 Benzene 0.0470

 18 Toluene 0.1281

 19 E-Benzene 0.0586

 20 Xylenes 0.3912

 21 n-C6 1.5420

 22 224Trimethylp 0.4660

-- Sales Oil -----------------------------------------------------------------------------

Production Rate : 1000[bbl/day]

Days of Annual Operation : 365 [days/year]

API Gravity : 41.5

Reid Vapor Pressure : 6.20[psia]

******************************************************************************************

* Calculation Results *

******************************************************************************************

-- Emission Summary ----------------------------------------------------------------------

Item Uncontrolled Uncontrolled 

 [ton/yr] [lb/hr] 

Page 1---------------------------------------------------------------- E&P TANK 

Total HAPs 6.040 1.379 

Total HC 836.657 191.018 

VOCs, C2+ 823.270 187.961 

VOCs, C3+ 649.305 148.243 

Page 1
Van Hook Field 1000 BOPD wt%

 

Uncontrolled Recovery Info. 

 Vapor 41.5700 [MSCFD] 

 HC Vapor 41.3600 [MSCFD] 

 GOR 41.57 [SCF/bbl] 

-- Emission Composition ------------------------------------------------------------------

No Component Uncontrolled Uncontrolled 

 [ton/yr] [lb/hr] 

1 H2S 1.343 0.307 

2 O2 0.000 0.000 

3 CO2 1.941 0.443 

4 N2 0.412 0.094 

5 C1 13.387 3.056 

6 C2 173.965 39.718 

7 C3 448.169 102.322 

8 i-C4 34.294 7.830 

9 n-C4 102.418 23.383 

10 i-C5 13.956 3.186 

11 n-C5 18.394 4.200 

12 C6 6.270 1.432 

13 C7 10.476 2.392 

14 C8 7.517 1.716 

15 C9 1.774 0.405 

16 C10+ 0.002 0.000 

17 Benzene 0.156 0.036 

18 Toluene 0.111 0.025 

19 E-Benzene 0.016 0.004 

20 Xylenes 0.090 0.021 

21 n-C6 5.168 1.180 

22 224Trimethylp 0.493 0.113 

 Total 840.352 191.861 

-- Stream Data ---------------------------------------------------------------------------

No. Component MW LP Oil Flash Oil Sale Oil Flash Gas W&S Gas Total Emissions

 wt % wt % wt % wt % wt % wt % 

1 H2S 34.80 0.0027 0.0024 0.0001 0.1791 0.1609 0.1631 

2 O2 32.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

3 CO2 44.01 0.0038 0.0026 0.0000 0.5796 0.1818 0.2307 

4 N2 28.01 0.0008 0.0001 0.0000 0.3282 0.0099 0.0490 

5 C1 16.04 0.0261 0.0112 0.0000 7.4009 0.7777 1.5911 

6 C2 30.07 0.3417 0.2811 0.0024 30.3262 19.3302 20.6806 

7 C3 44.10 1.3723 1.3000 0.5065 37.1767 55.5360 53.2811 

8 i-C4 58.12 0.3662 0.3594 0.3044 3.7640 4.1203 4.0766 

9 n-C4 58.12 1.6928 1.6719 1.5180 12.0581 12.1907 12.1744 

10 i-C5 72.15 0.6858 0.6836 0.6696 1.7610 1.6447 1.6590 

11 n-C5 72.15 1.2496 1.2474 1.2340 2.3296 2.1666 2.1866 

12 C6 86.16 1.4712 1.4725 1.4830 0.8134 0.7577 0.7645 

13 C7 100.20 7.9550 7.9683 8.0662 1.3546 1.2768 1.2865 

14 C8 114.23 19.2940 19.3310 19.6004 0.9553 0.9145 0.9195 

15 C9 128.28 13.4810 13.5078 13.7022 0.2134 0.2208 0.2201 

16 C10+ 233.49 49.4241 49.5238 50.2483 0.0000 0.0000 0.0000 

17 Benzene 78.11 0.0470 0.0471 0.0475 0.0197 0.0184 0.0186 

18 Toluene 92.13 0.1281 0.1283 0.1300 0.0137 0.0131 0.0132 

19 E-Benzene 106.17 0.0586 0.0587 0.0596 0.0020 0.0020 0.0018 

20 Xylenes 106.17 0.3912 0.3920 0.3976 0.0109 0.0106 0.0109 

21 n-C6 86.18 1.5420 1.5438 1.5575 0.6517 0.6091 0.6143 

22 224Trimethylp 114.24 0.4660 0.4668 0.4728 0.0617 0.0581 0.0587 

 

 MW 137.41 138.18 142.90 36.81 42.83 41.99 

 Stream Mole Ratio 1.0000 0.9924 0.9456 0.0076 0.0468 0.0544 

 Heating Value [BTU/SCF] 2105.43 2442.60 2395.38 

 Gas Gravity [Gas/Air] 1.27 1.48 1.45 

 Bubble Pt. @ 100F [psia] 29.55 23.39 7.57 

Page 2---------------------------------------------------------------- E&P TANK 

 RVP @ 100F [psia] 15.49 13.82 6.27 

 Spec. Gravity @ 100F 0.673 0.674 0.677 

Page 2
Emission estimates are based on using the E&P TANK V2.0 Model, RVP Distillation Column

As shown below, the E&P Tanks summary output has a linear relationship with the production rate

of the oil with the given inputs listed below.

Inputs:

Low pressure oil from average of 2 representative Van Hook Field Dakota-3 Wells

Separator: 52 psig, 90 degF

Flash Valve: 13.7 psia, 50 degF

Sales Oil: API Gravity 41.5, Reid Vapor Pressure 6.2 psia, 365 days/year

Outputs:

Oil Production Rates (bbl/day) (P) 0 50 100 300 1000

Emission (tons/yr)

Total HC 0 41.83255 83.6651 250.9953 836.651

VOCs, C3+ 0 32.46485 64.9297 194.7891 649.297

Total HAPs 0 0.302 0.604 1.812 6.04

VOC (C3+) Emission Factor: 0.6493 tpy/BOPD

HAP Emission Factor: 0.00604 tpy/BOPD

Oil Storage Tank Flashing Emissions Calculation Methodology

E&P Tanks Linear Relation between Production (bbls/day) and Emissions (tons/yr)

y = 0.00604x

R2 = 1.00000

y = 0.6493x

R2 = 1

-100

0

100

200

300

400

500

600

700

0 500 1000 1500

tons/year

bbl/day

Tank Emissions by Production Rate

Total HAPs

VOCs, C3+

Linear (Total HAPs)

Linear (VOCs, C3+)
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT D: REPRESENTATIVE LOW PRESSURE OIL 

ANALYTICAL DATA 
Company .................... ZENERGY 

Lab Number ................ CRͲ10330 Study Number.......... CRͲ5

Date Sampled .............. 7Ͳ15Ͳ2010 Date Tested............. 7Ͳ23Ͳ2010

S l Id tifi ti VAN HOOK 16 14 H CRUDE OIL

 EXTENDED HYDROCARBON (GLYCALC) LIQUID STUDY

Sample Identification .................... VAN HOOK 16-14 H CRUDE OIL

Sample Location .......... MONTANA.

Sample Pressure ......... 28 PSIG Sample Temperature.... 80 F

Type Sample ............... SPOT County...................... MONTRAIL

Test method ................ GPAͲ2286 Sampling Method........ YZ PISTON

 Components Mole % Weight % Liq. Vol. %

Hydrogen Sulfide .......... 0.009 0.002 0.002

Oxygen ...................... 0.000 0.000 0.000

Carbon Dioxide ............ 0.010 0.003 0.003

Nitrogen ..................... 0.003 0.001 0.001

Methane ..................... 0 184 . 0 021 . 0 051 .

Ethane ....................... 1.152 0.241 0.501

Propane ..................... 3.568 1.096 1.600

isoͲButane .................. 0.778 0.315 0.414

nͲButane .................... 3.694 1.496 1.896

isoͲPentane ................ 1.242 0.624 0.739

nͲPentane ................... 2.270 1.141 1.339

Hexanes ..................... 2 276. 1 367. 1 523.

Heptanes .................... 10.418 7.274 7.823

Octanes ..................... 24.125 19.203 20.117

Nonanes ..................... 16.003 14.302 14.658

Decanes+ ................... 30.668 50.576 46.892

Benzene...................... 0.090 0.049 0.041

Toluene....................... 0.183 0.117 0.100

Ethylbenzene............... 0.047 0.035 0.030

Xylenes....................... 0.455 0.337 0.288

nͲHexane .................... 2.304 1.384 1.542

2,2,4ͲTrimethylpentane... 0.521 0.415 0.441

TOTALS ..................... 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

2-Methylpentane 1.293 0.777 0.866

3-Methylpentane 3-Methylpentane 0 983 . 0 590 . 0 658 .

n-Hexane 2.304 1.384 1.542

2,2,4-Trimethylpentane 0.521 0.415 0.441

Benzene 0.090 0.049 0.041

Toluene 0.183 0.117 0.100

Ethylbenzene 0.047 0.035 0.030

m-Xylene 0.056 0.041 0.035

p-Xylene 0.291 0.216 0.184

o-Xylene 0.108 0.080 0.068

API GRAVITY AT 60/60 F, calculated........................................................................ 59.7

SPECIFIC GRAVITY AT 60/60 F, calculated.............................................................. 0.7402

RELATIVE SPECIFIC GRAVITY OF DECANES+ (C10+) FRACTION ............................... 0.7983

AVERAGE MOLECULAR WEIGHT .......................................................................... 143.505

AVERAGE MOLECULAR WEIGHT OF DECANES+ (C10+) FRACTION .......................... 236.660

TRUE VAPOR PRESSURE AT 100 F PSIA calculated TRUE VAPOR PRESSURE AT 100 F, PSIA, calculated................................................ 28 847 .

AVERAGE BOILING POINT, F, ................................................................................ 308.034

CUBIC FEET OF GAS / GALLON OF LIQUID, as Ideal Gas .......................................... 18.973

BTU / GALLON OF LIQUID AT 14.73 PSIA, calculated ................................................. 122702.719

LBS / GALLON OF LIQUID, calculated ...................................................................... 6.171

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
 EXTENDED HYDROCARBON LIQUID STUDIES

 CERTIFICATE OF ANALYSIS

Company................ ZENERGY

L bN ba umer............. CR-10330 CR 10330 Study Number............ St d N b CR-5B 

Date Sampled............. 7-15-2010 Date Tested.............. 7-22-2010

Sample Identification................ VAN HOOK 16-14 H CRUDE OIL

Sample Location......... MONTANA.

Sample Pressure.......... N/A Sample Temperature.... N/A

Flowrate................... N/A County..................... MONTRAIL

Test Method.............. VARIOUS Sample Container........

1-QUART

 BOTTLE

TEST PERFORMED RESULTS

API GRAVITY AT 60/60 F (ASTM D-287), observed...................... / ( ), 41.2

SPECIFIC GRAVITY AT 60/60 F (ASTM D-1657), calculated.......... 0.8193

REID VAPOR PRESSURE (ASTM D-323), PSIG AT 100 F.............. 4.6 PSIG

TOTAL SULFUR CONTENT (ASTM D-5453), PPMW.................. PPMW 1,562.18

TRUE VAPOR PRESSURE (ASTM D-2889), PSIA AT 100 F ........... N/A

BASIC SEDIMENT AND WATER CONTENT, % BY VOLUME.... N/A

COPPER STRIP CORROSION (ASTM D-130), 1 HOUR AT 100 F........... N/A

FREE WATER, observed......................................................... N/A

NOTATION : ALL TESTING PROVIDED ABOVE WAS PERFORMED IN ACCORDANCE TO METHODOLOGY

 OUTLINED BY THE AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM).
5HSRUW5HSRUW(GLWRU

Chromatogram VanHook 16-14 C:\GCsolution\DRO\DRO Data\08-2010\08-01-2010\VanHook 16-14.gcd - Channel 1

min

Intensity 0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0

0 50000 100000 150000 200000 250000

 1.055 / 1.137 / 1.307 / 1.405 / 1.552 / 1.669 / 

 1.729 / 1.901 / 2.038 / 2.108 / 2.280 / 2.361 / 2.417 / 2.564 / 

 2.666 / 2.854 / 2.948 / 3.034 / 3.135 / 3.210 / 3.301 / 3.420 / 3.538 / 3.638 / 3.772 / 3.857 / 3.966 / 4.069 / 4.147 / 4.333 / 4.508 / 4.582 / 4.693 / 4.899 / 5.021 / 5.165 / 5.364 / 5.509 / 5.608 / Decane (C10) 5.816 / 5.947 / 6.069 / 6.190 / 6.289 / 6.392 / 6.510 / 6.562 / 6.657 / 6.713 / 6.778 / 6.903 / 7.082 / 7.220 / 7.323 / 7.381 / 7.455 / 7.559 / 7.632 / 7.745 / 7.831 / 7.906 / 7.967 / 8.056 / 8.184 / 8.269 / 8.326 / 8.451 / 8.540 / 8.632 / 8.744 / 8.807 / 8.998 / 9.127 / 9.270 / 9.380 / 9.467 / 9.526 / 9.595 / 9.724 / 9.861 / 9.939 / 10.055 / 10.125 / 10.256 / 10.332 / 10.425 / 10.487 / 10.569 / 10.639 / 10.828 / 10.912 / 11.054 / 11.219 / 11.470 / 11.614 / 11.785 / 12.031 / 12.130 / 12.183 / 12.301 / 12.412 / 12.607 / 12.705 / 12.822 / 13.004 / 13.087 / 13.300 / 13.367 / 13.454 / 13.582 / 13.672 / 13.726 / 13.925 / 14.089 / 14.146 / 14.315 / 14.446 / 14.518 / 14.594 / 14.691 / 14.776 / 14.896 / 15.041 / 15.130 / 15.242 / 15.297 / 15.369 / 15.430 / 15.565 / 15.626 / 15.792 / 15.884 / 15.948 / o-terphenyl 16.062 / 16.183 / 16.346 / 16.458 / 16.570 / 16.667 / 16.813 / 16.896 / 16.987 / 17.134 / 17.231 / 17.310 / 17.450 / 17.528 / 17.642 / 17.765 / 17.957 / 18.048 / 18.140 / 18.222 / 18.289 / 18.436 / 18.589 / 18.722 / 18.914 / 18.981 / 19.082 / 19.197 / 19.332 / 19.465 / 19.623 / 19.673 / 19.783 / 19.850 / 19.928 / 19.997 / 20.067 / 20.181 / 20.252 / 20.368 / 20.446 / 20.500 / 20.633 / 20.762 / 20.792 / 20.873 / 21.032 / 21.137 / 21.213 / 21.310 / 21.411 / 21.473 / 21.528 / 21.626 / 21.725 / 21.801 / 21.880 / 21.970 / 22.051 / 22.098 / 22.215 / 22.368 / 22.429 / 22.605 / Octacosane (C28) 22.722 / 22.823 / 22.885 / 22.945 / 22.995 / 23.073 / 23.221 / 23.292 / 23.353 / 23.417 / 23.532 / 23.600 / 23.660 / 23.821 / 23.896 / 23.952 / 24.047 / 24.180 / 24.301 / 24.406 / 24.591 / 24.643 / 24.750 / 24.810 / 24.881 / 24.977 / 25.158 / 25.337 / 25.421 / 25.573 / 25.745 / 25.809 / 25.959 / 26.054 / 26.221 / 26.392 / 26.509 / 26.605 / 26.710 / 26.802 / 26.946 / 27.105 / 27.178 / 27.281 / 27.449 / 27.533 / 27.670 / 27.787 / 28.002 / 28.136 / 28.277 / 

 28.724 / 

 29.009 / 29.145 / 

 29.457 / 29.673 / 29.860 / 
Company .................... ZENERGY

Lab Number ................ CRͲ10330 Study Number.............. CRͲ4

Date Sampled .............. 7Ͳ15Ͳ2010 Date Tested................. 7Ͳ23Ͳ2010

S l Id tifi ti PENNINGTON 16 15 H CRUDE OIL

 EXTENDED HYDROCARBON (GLYCALC) LIQUID STUDY

Sample Identification .................... PENNINGTON 16-15 H CRUDE OIL

Sample Location .......... MONTANA.

Sample Pressure ......... 75 PSIG Sample Temperature...... 100 F

Type Sample ............... SPOT County........................ MONTRAIL

Test method ................ GPAͲ2286 Sampling Method........ YZ PISTON

 Components Mole % Weight % Liq. Vol. %

Hydrogen Sulfide .......... 0.012 0.003 0.003

Oxygen ...................... 0.000 0.000 0.000

Carbon Dioxide ............ 0.013 0.004 0.004

Nitrogen ..................... 0.004 0.001 0.001

Methane ..................... 0 270 . 0 032 . 0 078 .

Ethane ....................... 2.018 0.448 0.920

Propane ..................... 5.113 1.663 2.400

isoͲButane .................. 0.980 0.420 0.546

nͲButane .................... 4.432 1.900 2.381

isoͲPentane ................ 1.409 0.750 0.878

nͲPentane ................... 2.562 1.364 1.582

Hexanes ..................... 2 488. 1 582. 1 743.

Heptanes .................... 11.732 8.673 9.222

Octanes ..................... 22.998 19.381 20.074

Nonanes ..................... 13.316 12.600 12.767

Decanes+ ................... 28.387 48.236 44.369

Benzene...................... 0.078 0.045 0.037

Toluene....................... 0.204 0.139 0.116

Ethylbenzene............... 0.107 0.084 0.070

Xylenes....................... 0.573 0.449 0.379

nͲHexane .................... 2.688 1.709 1.883

2,2,4ͲTrimethylpentane... 0.616 0.519 0.545

TOTALS ..................... 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

2-Methylpentane 1.398 0.889 0.979

3-Methylpentane 3-Methylpentane 1 090 . 0 693 . 0 764 .

n-Hexane 2.688 1.709 1.883

2,2,4-Trimethylpentane 0.616 0.519 0.545

Benzene 0.078 0.045 0.037

Toluene 0.204 0.139 0.116

Ethylbenzene 0.107 0.084 0.070

m-Xylene 0.067 0.053 0.045

p-Xylene 0.386 0.302 0.255

o-Xylene 0.120 0.094 0.079

API GRAVITY AT 60/60 F, calculated........................................................................ 61.9

SPECIFIC GRAVITY AT 60/60 F, calculated.............................................................. 0.7318

RELATIVE SPECIFIC GRAVITY OF DECANES+ (C10+) FRACTION ............................... 0.7956

AVERAGE MOLECULAR WEIGHT .......................................................................... 135.548

AVERAGE MOLECULAR WEIGHT OF DECANES+ (C10+) FRACTION .......................... 230.327

TRUE VAPOR PRESSURE AT 100 F PSIA calculated TRUE VAPOR PRESSURE AT 100 F, PSIA, calculated................................................ 43 649 .

AVERAGE BOILING POINT, F, ................................................................................ 283.928

CUBIC FEET OF GAS / GALLON OF LIQUID, as Ideal Gas .......................................... 19.480

BTU / GALLON OF LIQUID AT 14.73 PSIA, calculated ................................................. 121815.044

LBS / GALLON OF LIQUID, calculated ...................................................................... 6.102

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
 EXTENDED HYDROCARBON LIQUID STUDIES

 CERTIFICATE OF ANALYSIS

Company................ ZENERGY

L bN ba umer............. CR-10330 CR 10330 Study Number............ St d N b CR-4B 

Date Sampled............. 7-15-2010 Date Tested.............. 7-22-2010

Sample Identification................ PENNINGTON 16-15 H CRUDE OIL

Sample Location......... MONTANA.

Sample Pressure.......... N/A Sample Temperature.... N/A

Flowrate................... N/A County..................... MONTRAIL

Test Method.............. VARIOUS Sample Container........

1-QUART 

BOTTLE

TEST PERFORMED RESULTS

API GRAVITY AT 60/60 F (ASTM D-287), observed...................... / ( ), 41.8

SPECIFIC GRAVITY AT 60/60 F (ASTM D-1657), calculated.......... 0.8165

REID VAPOR PRESSURE (ASTM D-323), PSIG AT 100 F.............. 7.8 PSIG

TOTAL SULFUR CONTENT (ASTM D-5453), PPMW.................. PPMW 1,435.60

TRUE VAPOR PRESSURE (ASTM D-2889), PSIA AT 100 F ........... N/A

BASIC SEDIMENT AND WATER CONTENT, % BY VOLUME.... N/A

COPPER STRIP CORROSION (ASTM D-130), 1 HOUR AT 100 F........... N/A

FREE WATER, observed......................................................... N/A

NOTATION : ALL TESTING PROVIDED ABOVE WAS PERFORMED IN ACCORDANCE TO METHODOLOGY

 OUTLINED BY THE AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM).
Report(Report Editor)

Chromatogram Pennington 16-15H C:\GCsolution\DRO\DRO Data\08-2010\08-01-2010\Pennington 16-15H.gcd - Channel 1

min

Intensity 0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0

0 50000 100000 150000 200000

 1.054 / 1.137 / 1.405 / 1.552 / 

 1.669 / 1.730 / 1.901 / 2.039 / 2.109 / 2.281 / 2.362 / 2.418 / 2.564 / 

 2.667 / 2.854 / 2.949 / 3.035 / 3.135 / 3.210 / 3.301 / 3.421 / 3.539 / 3.637 / 3.740 / 3.857 / 3.967 / 4.069 / 4.148 / 4.334 / 4.509 / 4.583 / 4.693 / 4.901 / 5.022 / 5.166 / 5.365 / 5.512 / 5.609 / Decane (C10) 5.819 / 5.949 / 6.070 / 6.136 / 6.191 / 6.292 / 6.395 / 6.466 / 6.659 / 6.714 / 6.779 / 6.905 / 7.083 / 7.154 / 7.221 / 7.325 / 7.457 / 7.560 / 7.634 / 7.745 / 7.833 / 7.907 / 7.967 / 8.057 / 8.184 / 8.270 / 8.327 / 8.452 / 8.541 / 8.633 / 8.743 / 8.809 / 8.999 / 9.128 / 9.270 / 9.380 / 9.467 / 9.529 / 9.595 / 9.724 / 9.863 / 9.941 / 10.053 / 10.147 / 10.259 / 10.331 / 10.427 / 10.487 / 10.570 / 10.638 / 10.768 / 10.828 / 10.912 / 11.059 / 11.265 / 11.222 / 11.470 / 11.614 / 11.786 / 12.030 / 12.130 / 12.186 / 12.300 / 12.416 / 12.469 / 12.604 / 12.703 / 12.823 / 13.006 / 13.087 / 13.304 / 13.372 / 13.447 / 13.583 / 13.673 / 13.730 / 13.932 / 14.090 / 14.147 / 14.322 / 14.440 / 14.518 / 14.594 / 14.692 / 14.776 / 14.903 / 15.041 / 15.131 / 15.243 / 15.302 / 15.370 / 15.432 / 15.570 / 15.626 / 15.788 / 15.885 / 15.948 / o-terphenyl 16.044 / 16.183 / 16.344 / 16.460 / 16.573 / 16.674 / 16.814 / 16.895 / 16.970 / 17.137 / 17.329 / 17.446 / 17.535 / 17.643 / 17.802 / 17.961 / 18.057 / 18.128 / 18.224 / 18.286 / 18.435 / 18.595 / 18.722 / 18.918 / 18.983 / 19.078 / 19.197 / 19.331 / 19.480 / 19.598 / 19.651 / 19.702 / 19.783 / 19.851 / 19.927 / 20.074 / 20.181 / 20.361 / 20.440 / 20.517 / 20.634 / 20.795 / 20.874 / 21.027 / 21.136 / 21.309 / 21.400 / 21.541 / 21.724 / 21.789 / 21.888 / 21.969 / 22.076 / 22.183 / 22.375 / 22.436 / 22.605 / Octacosane (C28) 22.719 / 22.799 / 22.998 / 23.056 / 23.106 / 23.220 / 23.422 / 23.502 / 23.624 / 23.677 / 23.815 / 23.917 / 23.968 / 24.038 / 24.175 / 24.300 / 24.404 / 24.615 / 24.704 / 24.762 / 24.824 / 24.896 / 24.973 / 25.070 / 25.139 / 25.197 / 25.259 / 25.329 / 25.454 / 25.573 / 25.720 / 25.795 / 25.869 / 25.956 / 26.069 / 26.222 / 26.421 / 26.547 / 26.638 / 26.744 / 26.842 / 26.947 / 27.166 / 27.295 / 27.437 / 27.581 / 27.764 / 27.902 / 28.049 / 28.197 / 28.360 / 28.528 / 
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT E: REPRESENTATIVE GAS ANALYSIS 
	

	



	


















































 
 


 




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	Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: MARY R SMITH Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 72 DEG F Sample Pressure: 20 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.445 0.536 0.296

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 0.535 0.410 0.230

Methane...................... 24.513 10.763 16.208

Ethane........................ 28.935 23.813 30.180

Propane....................... 27.572 33.276 29.626

isoͲButane................... 3.024 4.811 3.860

nͲButane...................... 9.829 15.636 12.086

isoͲPentane.................. 1.564 3.089 2.231

nͲPentane.................... 2.184 4.313 3.088

Cyclopentane............... 0.102 0.195 0.118

nͲHexane..................... 0.411 0.970 0.660

Cyclohexane................ 0.075 0.172 0.099

Other Hexanes ............. 0.545 1.287 0.875

Heptanes..................... 0.099 0.271 0.178

Methylcyclohexane........ 0.028 0.074 0.043

2,2,4ͲTrimethylpentane... 0.000 0.000 0.000

Benzene...................... 0.030 0.063 0.032

Toluene....................... 0.023 0.058 0.030

Ethylbenzene............... 0.003 0.008 0.004

Xylenes....................... 0.017 0.050 0.026

C8+ Heavies................ 0.066 0.205 0.131

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.102 0.195 0.118

Cyclohexane 0.075 0.172 0.099

2-Methylpentane 0.343 0.810 0.551

3-Methylpentane 0.202 0.477 0.324

n-Hexane 0.411 0.970 0.660

Methylcyclohexane 0.028 0.074 0.043

2,2,4-Trimethylpentane 0.000 0.000 0.000

Benzene 0.030 0.063 0.032

Toluene 0.023 0.058 0.030

Ethylbenzene 0.003 0.008 0.004

m-Xylene 0 003. 0 008. 0 004.

p-Xylene 0.012 0.034 0.018

o-Xylene 0.003 0.008 0.004

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 1 2615.

TOTAL GPM (Ethane Inclusive)................................................................. 21.293

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 2117.258

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 2081.086

AVERAGE MOLECULAR WEIGHT............................................................ 36.537

MOLAR MASS RATIO.............................................................................. 1.2615

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 1.2771

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 2086 694 2086.694

COMPRESSIBILITY FACTOR (Z).............................................................. 0.98783

PROPANE GPM ..................................................................................... 7.5766

BUTANE GPM ....................................................................................... 4.0779

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.9202

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: PENNINGTON 16Ͳ15 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 57 DEG F Sample Pressure: 40 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.612 1.003 0.490

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 4.459 4.652 2.300

Methane...................... 53.689 32.081 42.686

Ethane........................ 20.555 23.021 25.781

Propane....................... 13.906 22.839 17.967

isoͲButane................... 1.188 2.571 1.823

nͲButane...................... 3.555 7.695 5.256

isoͲPentane.................. 0.461 1.238 0.790

nͲPentane.................... 0.611 1.641 1.038

Cyclopentane............... 0.031 0.081 0.043

nͲHexane..................... 0.121 0.389 0.234

Cyclohexane................ 0.058 0.181 0.092

Other Hexanes ............. 0.443 1.423 0.855

Heptanes..................... 0.134 0.500 0.290

Methylcyclohexane........ 0.045 0.166 0.086

2,2,4ͲTrimethylpentane... 0.000 0.000 0.000

Benzene...................... 0.019 0.056 0.025

Toluene....................... 0.026 0.089 0.041

Ethylbenzene............... 0.003 0.012 0.005

Xylenes....................... 0.014 0.055 0.025

C8+ Heavies................ 0.072 0.306 0.173

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.031 0.081 0.043

Cyclohexane 0.058 0.181 0.092

2-Methylpentane 0.279 0.895 0.538

3-Methylpentane 0.164 0.527 0.317

n-Hexane 0.121 0.389 0.234

Methylcyclohexane 0.045 0.166 0.086

2,2,4-Trimethylpentane 0.000 0.000 0.000

Benzene 0.019 0.056 0.025

Toluene 0.026 0.089 0.041

Ethylbenzene 0.003 0.012 0.005

m-Xylene 0 002. 0 009. 0 004.

p-Xylene 0.009 0.037 0.017

o-Xylene 0.002 0.009 0.004

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 0 9270.

TOTAL GPM (Ethane Inclusive)................................................................. 11.595

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1511.141

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1485.576

AVERAGE MOLECULAR WEIGHT............................................................ 26.848

MOLAR MASS RATIO.............................................................................. 0.9270

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 0.9324

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1498 858 1498.858

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99415

PROPANE GPM ..................................................................................... 3.8212

BUTANE GPM ....................................................................................... 1.5054

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 0.7848

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT F: ENGINE MANUFACTURER’S SPECS 
This section of the document has been redacted because it 

contains copyrighted information. The redacted information 

can be viewed from the hard copy of the docket, which is 

available at the EPA Region 8 Office upon request. 






Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT G: EMISSION CONTROL DEVICE 

MANUFACTURER’S SPECS 


	



	









		
	
 

	
TYPICAL VAN HOOK AREA 

THREE WELL PAD FACILITY PLOT PLAN 

Dakota-3 E&P Company, LLC 

FBIR, North Dakota 

NOT TO SCALE 

Chemicals 

(3)Wellheads 

Tank Vent line 

Utility Flare

Gas to sales

Gas Meter

12’d x 20’h 

12’d x 20’h 

12’d x 20’h 

400 bbl oik 

Enclosed 

Combustor

Recycle 

Pump 

Recycle 

Pump 

12’d x 20’h 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

Valve

Valve

Valve

Recycle Line 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 

Gas Meter 

(3) Gensets 

Genset

12’d x 20’h 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

24 bbl 

Diesel 

Oil Getty Box 

Water Getty Box Recycle 

Pump 

Gas Meter 

Legend 

Berms 

Water Line 

Crude Line 

Flowline 

Buried Recycle Lines 

Gas Sales Line 

Tank Vapor Line 

Flared Gas Line 
	



	









		
	 	

	
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT J: DIESEL TANK EPA TANKS 4.09D 

EMISSIONS SUMMARY 
TANKS 4.0.9d

Emissions Report - Detail Format 

Tank Indentification and Physical Characteristics

Identification

 User Identification: 1000 gallon diesel tank

 City: Williston

 State: North Dakota

 Company: Williams E&P, LLC

 Type of Tank: Horizontal Tank

 Description: 1,000 gallon diesel tank to fuel onsite diesel generators. Tank throughput is based on engine fuel consumption.

Tank Dimensions

 Shell Length (ft): 10.00

 Diameter (ft): 4.16

 Volume (gallons): 1,000.00

 Turnovers: 2,244.31

 Net Throughput(gal/yr): 2,244,312.00

 Is Tank Heated (y/n): N

 Is Tank Underground (y/n): N

Paint Characteristics

 Shell Color/Shade: Gray/Medium

 Shell Condition Good

Breather Vent Settings

 Vacuum Settings (psig): -0.03

 Pressure Settings (psig) 0.03

Meterological Data used in Emissions Calculations: Bismarck, North Dakota (Avg Atmospheric Pressure = 13.86 psia)

TANKS 4.0 Report Page 1 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
1000 gallon diesel tank - Horizontal Tank

Williston, North Dakota 

TANKS 4.0.9d

Emissions Report - Detail Format 

Liquid Contents of Storage Tank

Daily Liquid Surf. 

Temperature (deg F)

Liquid

Bulk

Temp Vapor Pressure (psia)

Vapor

Mol. 

Liquid

Mass 

Vapor

Mass Mol. Basis for Vapor Pressure

Mixture/Component Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract. Fract. Weight Calculations

Distillate fuel oil no. 2 All 50.18 39.72 60.64 44.68 0.0045 0.0031 0.0067 130.0000 188.00 Option 1: VP50 = .0045 VP60 = .0065

TANKS 4.0 Report Page 2 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
1000 gallon diesel tank - Horizontal Tank

Williston, North Dakota 

TANKS 4.0.9d

Emissions Report - Detail Format 

Detail Calculations (AP-42)

Annual Emission Calcaulations

Standing Losses (lb): 0.2654

 Vapor Space Volume (cu ft): 86.5719

 Vapor Density (lb/cu ft): 0.0001

 Vapor Space Expansion Factor: 0.0780

 Vented Vapor Saturation Factor: 0.9995

Tank Vapor Space Volume:

 Vapor Space Volume (cu ft): 86.5719

 Tank Diameter (ft): 4.1600

 Effective Diameter (ft): 7.2797

 Vapor Space Outage (ft): 2.0800

 Tank Shell Length (ft): 10.0000

Vapor Density

 Vapor Density (lb/cu ft): 0.0001

 Vapor Molecular Weight (lb/lb-mole): 130.0000

 Vapor Pressure at Daily Average Liquid

 Surface Temperature (psia): 0.0045

 Daily Avg. Liquid Surface Temp. (deg. R): 509.8466

 Daily Average Ambient Temp. (deg. F): 41.5958

 Ideal Gas Constant R

 (psia cuft / (lb-mol-deg R)): 10.731

 Liquid Bulk Temperature (deg. R): 504.3458

 Tank Paint Solar Absorptance (Shell): 0.6800

 Daily Total Solar Insulation

 Factor (Btu/sqft day): 1,276.2450

Vapor Space Expansion Factor

 Vapor Space Expansion Factor: 0.0780

 Daily Vapor Temperature Range (deg. R): 41.8377

 Daily Vapor Pressure Range (psia): 0.0036

 Breather Vent Press. Setting Range(psia): 0.0600

 Vapor Pressure at Daily Average Liquid

 Surface Temperature (psia): 0.0045

 Vapor Pressure at Daily Minimum Liquid

 Surface Temperature (psia): 0.0031

 Vapor Pressure at Daily Maximum Liquid

 Surface Temperature (psia): 0.0067

 Daily Avg. Liquid Surface Temp. (deg R): 509.8466

 Daily Min. Liquid Surface Temp. (deg R): 499.3872

 Daily Max. Liquid Surface Temp. (deg R): 520.3060

 Daily Ambient Temp. Range (deg. R): 24.3583

Vented Vapor Saturation Factor

 Vented Vapor Saturation Factor: 0.9995

 Vapor Pressure at Daily Average Liquid:

 Surface Temperature (psia): 0.0045

 Vapor Space Outage (ft): 2.0800

Working Losses (lb): 5.6720

 Vapor Molecular Weight (lb/lb-mole): 130.0000

 Vapor Pressure at Daily Average Liquid

 Surface Temperature (psia): 0.0045

 Annual Net Throughput (gal/yr.): 2,244,312.0000

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 Annual Turnovers: 2,244.3120

 Turnover Factor: 0.1800

 Tank Diameter (ft): 4.1600

 Working Loss Product Factor: 1.0000

Total Losses (lb): 5.9375

TANKS 4.0 Report Page 4 of 6

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Emissions Report for: Annual 

1000 gallon diesel tank - Horizontal Tank

Williston, North Dakota 

TANKS 4.0.9d

Emissions Report - Detail Format 

Individual Tank Emission Totals

Losses(lbs)

Components Working Loss Breathing Loss Total Emissions

Distillate fuel oil no. 2 5.67 0.27 5.94

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