## COMPREHENSIVE REPORT Report Date:08/16/2012 

## Facility Information

RBLC ID: 

## CA-1187 (draft) Date Determination Last Updated: 06/26/2012 Corporate/Company Name: PETROROCK- TUNNELL LEASE Permit Number: ATC- 12949-01 Facility Name: PETROROCK- TUNNELL LEASE Permit Date: 01/24/2012 (actual) Facility Contact: FRS Number: Facility Description: SIC Code: 1311 Permit Type: B: Add new process to existing facility NAICS Code: 211111 Permit URL: EPA Region: 9 COUNTRY: USA Facility County: SANTA BARBARA Facility State: CA Facility ZIP Code: 93454 Permit Issued By: SANTA BARBARA COUNTY APCD, CA (Agency Name) MR. BEN ELLENBERGER(Agency Contact) (805) 961-8879 EllenbergerC@SBCAPCD.ORG Other Agency Contact Info: 805-961-8800

cbe@sbcapcd.org Permit Notes:



## Process/Pollutant Information

PROCESS NAME: Enclosed Ground Flare Process Type: 19.390 (Other Flares) Primary Fuel: Field Gas Throughput: 17.00 MMBTU/H

Process Notes: Combust produced gas from an oilfield vapor recovery system

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 15.0000 PPMVD@3% O2 40 MINUTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/A Control Method: (P) Burner design, premix, and combustion temperature control Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.0000 PPMVD@3% O2 40 MINUTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/A Control Method: (P) Burner design, premix, and combustion temperature control Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0605 (draft) Date Determination Last Updated: 05/11/2012 Corporate/Company Name: WTG BENEDUM JOINT VENTURE Permit Number: 8941/PSDTX487M1 Facility Name: ACID GAS FLARE Permit Date: 12/21/2011 (estimated)Facility Contact: BOB STEWART 432-682-6311 FRS Number: 110015744480

Facility Description: Acid Gas Flare SIC Code: 1311 Permit Type: C: Modify process at existing facility NAICS Code: 211112 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: UPTON Facility State: TX Facility ZIP Code: 79778 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: Ozden Tamer, Ph; 512-239-4577 ozden.tamer@tceq.texas.gov Permit Notes: Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 TX Guadalupe Mountain NP > 250 km



## Process/Pollutant Information

PROCESS NAME: Acid Gas flare Process Type: 19.390 (Other Flares) Primary Fuel: Natural gas Throughput: 0

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 12.7600 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , SIPControl Method: (B)

Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0257 (final) Date Determination Last Updated: 05/11/2012 Corporate/Company Name: SABINE PASS LNG, LP & SABINE PASS LIQUEFACTION, LL Permit Number: PSD-LA-703(M3)

Facility Name: SABINE PASS LNG TERMINAL Permit Date: 12/06/2011 (actual) Facility Contact: PATRICIA OUTTRIM 713-375-5212 PAT.OUTTRIM@CHENIERE.COM FRS Number: 110030770351 Facility Description: A liquefaction section of the terminal which will include 24 compressor turbines, two generator turbines, two generator engines, flares, acid gas vents, and fugitives SIC Code: 4925

Permit Type: B: Add new process to existing facility NAICS Code: 221210 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: CAMERON Facility State: LA Facility ZIP Code: 70631 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: Permit writer: Dan Nguyen

Permit Notes:



## Process/Pollutant Information

PROCESS NAME: Generator Engines (2) Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: Natural Gas Throughput: 2012.00 hpProcess Notes:

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: EPA/OAR Mthd 5 and 202 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7500 LB/H HOURLY MAXIMUM Emission Limit 2: 0.1700 TONS/YEAR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: also for PM10 and PM2.5

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 9.7600 LB/H HOURLY MAXIMUM Emission Limit 2: 2.2200 TONS/YR ANNUAL MAXIMUM Standard Emission: 2.0000 GRAM/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Comply with 40 CFR 60 Subpart JJJJ Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0Test Method: EPA/OAR Mthd 10

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 19.5100 LB/H HOURLY MAXIMUM Emission Limit 2: 4.4300 TONS/YR ANNUAL MAXIMUM Standard Emission: 4.0000 LB/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Comply with 40 CFR 60 Subpart JJJJ Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4.4300 LB/H HOURLY MAXIMUM Emission Limit 2: 1.1100 TONS/YEAR ANNUAL MAXIMUM Standard Emission: 1.0000 GRAM/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Comply with 40 CFR 60 Subpart JJJJ Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 412.0000 TONS/YR ANNUAL MAXIMUM Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Fueled by natural gas, good combustion/operating practices Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: Simple Cycle Refrigeration Compressor Turbines (16) Process Type: 15.110 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: Natural Gas Throughput: 286.00 MMBTU/H

Process Notes: GE LM2500+G4

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: EPA/OAR Mthd 5 and 202 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0800 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: also for PM10 and PM2.5

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: EPA/OAR Mthd 25A

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6600 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 20 Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 22.9400 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 20.0000 PPMV AT 15% O2 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) water injection Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 43.6000 LB/H HOURLY MAXIMUM Emission Limit 2:Standard Emission: 58.4000 PPMV AT 15% OXYGEN

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 4872107.0000 TONS/YR ANNUAL MAXIMUM FROM THE FACILITYWIDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion/operating practices and fueled by natural gas - use GE LM2500+G4 turbines Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO2(e)



## Process/Pollutant Information

PROCESS NAME: Combined Cycle Refrigeration Compressor Turbines (8) Process Type: 15.210 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: natural gas Throughput: 286.00 MMBTU/H

Process Notes: GE LM2500+G4

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PMTest Method: EPA/OAR Mthd 5 and 202

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0800 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: also for PM10 and PM2.5

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6600 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 20 Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 22.9400 LB/H HOURLY MAXIMUM Emission Limit 2:Standard Emission: 20.0000 PPMV AT 15% O2

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) water injection Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 43.6000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 58.4000 PPMV AT 15% O2 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 4872107.0000 TONS/YEAR ANNUAL MAXIMUM FROM THE FACILITYWIDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (P) Good combustion/operating practices and fueled by natural gas - use GE LM2500+G4 turbines

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: co2(e)



## Process/Pollutant Information

PROCESS NAME: Simple Cycle Generation Turbines (2) Process Type: 15.110 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: Natural Gas Throughput: 286.00 MMBTU/H

Process Notes: GE LM2500+G4

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: EPA/OAR Mthd 5 and 202 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0800 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: also for PM10 and PM2.5

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6600 LB/H HOURLY MAXIMUM Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices and fueled by natural gas Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 20 Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 28.6800 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 25.0000 PPMV AT 15% O2 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) water injection Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 17.4600 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 25.0000 PPMV AT 15% O2 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (P) Good combustion practices and fueled by natural gas

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 4872107.0000 TONS/YR ANNUAL MAXIMUM FROM THE FACILITYWIDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion/operating practices and fueled by natural gas - use GE LM2500+G4 turbines Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO2(e)



## Process/Pollutant Information

PROCESS NAME: Acid Gas Vents (4) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 0

Process Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 39.2900 LB/H HOURLY MAXIMUM Emission Limit 2: 172.0900 TONS/YR ANNUAL MAXIMUMStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO2(e)

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.0300 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) No additional control Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: Marine Flare Process Type: 19.390 (Other Flares) Primary Fuel: natural gas Throughput: 1590.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 14.9700 LB/H HOURLY MAXIMUM Emission Limit 2: 0.1700 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Also for PM10 and PM2.5

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 185.1600 LB/H HOURLY MAXIMUM Emission Limit 2: 2.1300 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 705.4900 LB/H HOURLY MAXIMUM Emission Limit 2: 8.1200 TONS/YR ANNUAL MAXIMUMStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.8300 LB/H HOURLY MAXIMUM Emission Limit 2: 0.1200 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 2909.0000 TONS/YR ANNUAL MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO2(e)



## Process/Pollutant Information

PROCESS NAME: Wet/Dry Gas Flares (4) Process Type: 19.390 (Other Flares) Primary Fuel: natural gas Throughput: 0.26 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.0100 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: also for PM10 and PM2.5

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/H HOURLY MAXIMUM Emission Limit 2: 0.1100 TONS/YR ANNUAL MAXIMUMStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.4200 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.0100 TONS/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 133.0000 TONS/YR ANNUAL MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) proper plant operations and maintain the presence of the flame when the gas is routed to the flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO2(e)



## Process/Pollutant Information

PROCESS NAME: Fugitive Emissions Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 0

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.0300 LB/H HOURLY MAXIMUM Emission Limit 2: 17.2100 TONS/YEAR ANNUAL MAXIMUMStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Mechanical seals or equivalent for pumps and compressors that serve VOC with vapor pressure of 1.5 psia and above Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Dioxide Equivalent (CO2e)

CAS Number: CO2e Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) ) Emission Limit 1: 89629.0000 TONS/YR ANNUAL MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) conduct a leak detection and repair (LDAR) program Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO2(e)



## Facility Information

RBLC ID: 

## IN-0135 (draft) Date Determination Last Updated: 08/07/2012 Corporate/Company Name: HOOSIER ENERGY REC INC. - MEROM GENERATING STATION Permit Number: 153-29394-00005 Facility Name: HOOSIER ENERGY REC INC. - MEROM GENERATING STATION Permit Date: 11/10/2011 (actual) Facility Contact: ANGIE LEE 8129354715 FRS Number: Facility Description: STATIONARY ELECTRIC POWER GENERATING PLANT SIC Code: 4911 Permit Type: A: New/Greenfield Facility NAICS Code: 221112Permit URL: HTTP://PERMITS.AIR.IDEM.IN.GOV/29394F.PDF

EPA Region: 5 COUNTRY: USA Facility County: SULLIVAN Facility State: IN Facility ZIP Code: 47882 Permit Issued By: INDIANA DEPT OF ENV MGMT, OFC OF AIR (Agency Name) MR. MATT STUCKEY(Agency Contact) (317) 233-0203 mstuckey@idem.in.gov Other Agency Contact Info: PERMIT REVIEWER: DAVID J. MATOUSEK DMATOUSEK@IDEM.IN.GOV (317)232-8253

BRANCH CHIEF: MATT STUCKEY MSTUCKEY@IDEM.IN.GOV (317)233-0203 Permit Notes:



## Process/Pollutant Information

PROCESS NAME: 4-STROKE LEAN BURN COAL BED METHANE (CBM)-FIRED RECIPROCATING INTERNAL COMUBSTION ENGINES (RICE) Process Type: 17.150 (Other Gaseous) Primary Fuel: COAL BED METHANE Throughput: 4601.00 BRAKE HORSEPOWER

Process Notes: THERE ARE 8 OF THESES PROCESSES

POLLUTANT NAME: Carbon Dioxide

CAS Number: 124-38-9 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Greenhouse Gasses (GHG) , InOrganic Compounds ) Emission Limit 1: 1100.0000 LB/MW-H 3 HOURS Emission Limit 2: 16030.0000 TONS 12 CONSECUTIVE MONTH PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/AControl Method: (P) GOOD COMBUSTION PRACTICES AND PROPER MAINTENANCE

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PERFORM REGULAR MAINTENANCE USING THE MANUFACTURER'S OR OPERATOR'S MAINTENANCE PROCEDURES; KEEP RECORDS OF ANY MAINTENANCE THAT WOULD HAVE A SIGNIFICANT EFFECT ON EMISSIONS; THE RECORDS MAY BE KEPT IN ELECTRONIC FORMAT; AND KEEP A COPY OF EITHER THE MANUFACTURER'S OR THE OPERATOR'S MAINTENANCE PROCEDURES. PSD BACT

POLLUTANT NAME: Methane

CAS Number: 74-82-8 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 9.5700 LB/MW-H 3 HOURS Emission Limit 2: 139.4000 TONS 12 CONSECUTIVE MONTH PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/A Control Method: (P) GOOD COMBUSTION PRACTICES AND PROPER MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PERFORM REGULAR MAINTENANCE USING THE MANUFACTURER'S OR OPERATOR'S MAINTENANCE PROCEDURES; KEEP RECORDS OF ANY MAINTENANCE THAT WOULD HAVE A SIGNIFICANT EFFECT ON EMISSIONS; THE RECORDS MAY BE KEPT IN ELECTRONIC FORMAT; AND KEEP A COPY OF EITHER THE MANUFACTURER'S OR THE OPERATOR'S MAINTENANCE PROCEDURES. PSD BACT

POLLUTANT NAME: Nitrous Oxide (N2O)

CAS Number: 10024-97-2 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2300 LB MW-HR Emission Limit 2: 3.3500 TONS 12 CONSECUTIVE MONTH PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: OTHER CASE-BY-CASE

Other Applicable Requirements: N/A Control Method: (P) GOOD COMBUSTION PRACTICES AND PROPER MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PERFORM REGULAR MAINTENANCE USING THE MANUFACTURER'S OR OPERATOR'S MAINTENANCE PROCEDURES; KEEP RECORDS OF ANY MAINTENANCE THAT WOULD HAVE A SIGNIFICANT EFFECT ON EMISSIONS; THE RECORDS MAY BE KEPT IN ELECTRONIC FORMAT; AND KEEP A COPY OF EITHER THE MANUFACTURER'S OR THE OPERATOR'S MAINTENANCE PROCEDURES. PSD BACT



## Process/Pollutant Information

PROCESS NAME: COAL BED METHANE CBM DEHYDRATOR UNITS (CBM-FIRED REBOILER AND FLASH TANK) Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: COAL BED METHANE Throughput: 0.50 MMBTU/HR

Process Notes: THERE ARE TWO OF THESE PROCESSES

POLLUTANT NAME: Carbon Dioxide

CAS Number: 124-38-9 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Greenhouse Gasses (GHG) , InOrganic Compounds ) Emission Limit 1: 59.3600 LB HOURLY Emission Limit 2: 260.0000 TONS 12 CONSECUTIVE MONTH PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/A Control Method: (P) PROPER MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PSD BACT

## Process/Pollutant Information

PROCESS NAME: COAL BED METHANE-FIRED STANDBY FLARE W/PROPANE-FIRED PILOT Process Type: 19.390 (Other Flares) Primary Fuel: COAL BED METHANE Throughput: 25.00 MMBTU/HR

Process Notes: WITH 0.8 MMBTU/HR FOR THE PILOT WITH PROPANE AS THE PILOT'S PRIMARY FUEL

POLLUTANT NAME: Carbon Dioxide

CAS Number: 124-38-9 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Greenhouse Gasses (GHG) , InOrganic Compounds ) Emission Limit 1: 3235.0000 LB MW-HR Emission Limit 2: 4852.0000 TONS 12 MONTH CONSECUTIVE PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/A Control Method: (P) GOOD COMBUSTION PRACTICES AND PROPER MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PERFORM REGULAR MAINTENANCE USING THE MANUFACTURER'S OR OPERATOR'S MAINTENANCE PROCEDURES; KEEP RECORDS OF ANY MAINTENANCE THAT WOULD HAVE A SIGNIFICANT EFFECT ON EMISSIONS; THE RECORDS MAY BE KEPT IN ELECTRONIC FORMAT; AND KEEP A COPY OF EITHER THE MANUFACTURER'S OR THE OPERATOR'S MAINTENANCE PROCEDURES PSD BACT

POLLUTANT NAME: Methane

CAS Number: 74-82-8 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0600 LB MW-HR Emission Limit 2: 0.0800 TONS 12 MONTH CONSECUTIVE PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: OTHER CASE-BY-CASE

Other Applicable Requirements: N/A Control Method: (P) GOOD COMBUSTION PRACTICES AND PROPER MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PERFORM REGULAR MAINTENANCE USING THE MANUFACTURER'S OR OPERATOR'S MAINTENANCE PROCEDURES; KEEP RECORDS OF ANY MAINTENANCE THAT WOULD HAVE A SIGNIFICANT EFFECT ON EMISSIONS; THE RECORDS MAY BE KEPT IN ELECTRONIC FORMAT; AND KEEP A COPY OF EITHER THE MANUFACTURER'S OR THE OPERATOR'S MAINTENANCE PROCEDURES PSD BACT

POLLUTANT NAME: Nitrous Oxide (N2O)

CAS Number: 10024-97-2 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB MW-HR Emission Limit 2: 0.0800 T/YR 12 CONSECUTIVE MONTH PERIOD Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: N/A Control Method: (P) GOOD COMBUSTION PRACTICES AND PROPER MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PERFORM REGULAR MAINTENANCE USING THE MANUFACTURER'S OR OPERATOR'S MAINTENANCE PROCEDURES; KEEP RECORDS OF ANY MAINTENANCE THAT WOULD HAVE A SIGNIFICANT EFFECT ON EMISSIONS; THE RECORDS MAY BE KEPT IN ELECTRONIC FORMAT; AND KEEP A COPY OF EITHER THE MANUFACTURER'S OR THE OPERATOR'S MAINTENANCE PROCEDURES PSD BACT



## Facility Information

RBLC ID: 

## TX-0603 (draft) Date Determination Last Updated: 05/11/2012 Corporate/Company Name: CHEVRON PHILLIPS CHEMICAL COMPANY LP Permit Number: 21101/PSDTX1248 Facility Name: ETHYLENE PROCESS FLARE Permit Date: 10/27/2011 (actual)Facility Contact: RAZA AMJAD 4099850785 FRS Number: 110020148008

Facility Description: Ethylene Process Flare SIC Code: 2869 Permit Type: C: Modify process at existing facility NAICS Code: 325199 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: JEFFERSON Facility State: TX Facility ZIP Code: 77640 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: Ozden Tamer, Phone: 512-239-4577 email: ozden.tamer@tceq.texas.gov Permit Notes: Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 LA Breton > 250 km



## Process/Pollutant Information

PROCESS NAME: Ethylene Process Flare Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Natural Gas Throughput: 0

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 136.3700 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: Other Applicable Requirements: NSPS , NESHAP , MACT , SIPControl Method: (B) Process Flare

Est. % Efficiency: 98.000 Compliance Verified: No Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0248 (final) Date Determination Last Updated: 12/08/2011 Corporate/Company Name: CONSOLIDATED ENVIRONMENTAL MANAGEMENT INC - NUCOR Permit Number: PSD-LA-751

Facility Name: DIRECT REDUCTION IRON PLANT Permit Date: 01/27/2011 (actual) Facility Contact: STEVE ROWLAN (704) 366-7000 FRS Number: 110037583442 Facility Description: The DRI process reduces the iron oxide content of iron ore pellets into iron metal through direct contact with a

reducing gas. The effectiveness of this reduction process is called metallization, and the process equipment will be designed to achieve a metallization rate of at least 92% of the oxides within the ore. The reduction will take place in a countercurrent vertical shaft furnace, where reducing gas passes up through iron oxide pellets, which feed through the furnace by gravity. The major elements of the DRI process include the following: (1) iron oxide preparation; (2) reducing gas preparation; (3) DRI reactor shaft furnace; (4) spent reducing gas preparation for reuse, (5) DRI product handling; and (6) ancillary operations, including a package boiler, two cooling towers, and a flare for emergency situations. SIC Code: 3312

Permit Type: B: Add new process to existing facility NAICS Code: 331111 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: ST JAMES PARISH Facility State: LA Facility ZIP Code: 70723 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name)

MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: Kermit Wittenburg kermit.wittenburg@la.gov Permit Notes: This PSD permit also evaluated BACT for Green House Gases Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 581.8400 (Tons/Year) Nitrogen Oxides (NOx) 117.6200 (Tons/Year)Particulate Matter (PM) 135.5600 (Tons/Year) Sulfur Oxides (SOx) 28.3400 (Tons/Year) Volatile Organic Compounds (VOC) 33.9400 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: DRI-101 DRI Unit #1 Iron Oxide Day Bins Dust Collection

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 3858090.00 Tons/yr

Process Notes: The DRI process is fed iron oxide in pellet form to provide a consistent size of material in the shaft furnace to reduce the likelihood of fused product.

Batches of pellets directed to the DRI facility will be screened prior to storage in the Iron Oxide Day Bins. The Iron Oxide Day Bins provide a continuous feed of pellets to the shaft furnace. The continuous feed is again screened before being transferred by the furnace feed conveyor to the charge hopper at the top of the furnace.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1900 LB/H Emission Limit 2: 4.3200 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter baghouse achieving at least 99.5% control of PM10/PM2.5. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-201 DRI Unit #2 Iron Oxide Day Bins Dust CollectionProcess Type: 81.900 (Other Ferrous Metal Industry Processes)

Primary Fuel: Throughput: 3858090.00 tons/yr

Process Notes: The DRI process is fed iron oxide in pellet form to provide a consistent size of material in the shaft furnace to reduce the likelihood of fused product.

Batches of pellets directed to the DRI facility will be screened prior to storage in the Iron Oxide Day Bins. The Iron Oxide Day Bins provide a continuous feed of pellets to the shaft furnace. The continuous feed is again screened before being transferred by the furnace feed conveyor to the charge hopper at the top of the furnace.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1900 LB/H Emission Limit 2: 4.3200 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter baghouse achieving at least 99.5% control of PM10/PM2.5. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-102 DRI Unit #1 Iron Oxide Screen Dust Collection

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 3858090.00 Tons/yr

Process Notes: The DRI process is fed iron oxide in pellet form to provide a consistent size of material in the shaft furnace to reduce the likelihood of fused product.

Batches of pellets directed to the DRI facility will be screened prior to storage in the Iron Oxide Day Bins. The Iron Oxide Day Bins provide a continuous feed of pellets to the shaft furnace. The continuous feed is again screened before being transferred by the furnace feed conveyor to the charge hopper at the top of the furnace.POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0900 LB/H Emission Limit 2: 1.7300 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter baghouse achieving at least 99.5% control of PM10/PM2.5. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-202 DRI Unit #2 Iron Oxide Screen Dust Collection

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 3858090.00 Tons/yr

Process Notes: The DRI process is fed iron oxide in pellet form to provide a consistent size of material in the shaft furnace to reduce the likelihood of fused product.

Batches of pellets directed to the DRI facility will be screened prior to storage in the Iron Oxide Day Bins. The Iron Oxide Day Bins provide a continuous feed of pellets to the shaft furnace. The continuous feed is again screened before being transferred by the furnace feed conveyor to the charge hopper at the top of the furnace.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0900 LB/H Emission Limit 2: 1.7300 T/YR Standard Emission: 0.0020 GRAINS/DSCFDid factors, other then air pollution technology considerations influence the BACT decisions: N

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter baghouse achieving at least 99.5% control of PM10/PM2.5. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-105 DRI Unit #1 Furnace Feed Conveyor Baghouse

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 3858090.00 Tons/yr

Process Notes: The DRI process is fed iron oxide in pellet form to provide a consistent size of material in the shaft furnace to reduce the likelihood of fused product.

Batches of pellets directed to the DRI facility will be screened prior to storage in the Iron Oxide Day Bins. The Iron Oxide Day Bins provide a continuous feed of pellets to the shaft furnace. The continuous feed is again screened before being transferred by the furnace feed conveyor to the charge hopper at the top of the furnace.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.3800 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter baghouse achieving at least 99.5% control of PM10/PM2.5. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling Est. % Efficiency: 99.500 Compliance Verified: YesPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-205 DRI Unit #2 Furnace Feed Conveyor Baghouse

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 3858090.00

Process Notes: The DRI process is fed iron oxide in pellet form to provide a consistent size of material in the shaft furnace to reduce the likelihood of fused product.

Batches of pellets directed to the DRI facility will be screened prior to storage in the Iron Oxide Day Bins. The Iron Oxide Day Bins provide a continuous feed of pellets to the shaft furnace. The continuous feed is again screened before being transferred by the furnace feed conveyor to the charge hopper at the top of the furnace.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.3800 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter baghouse achieving at least 99.5% control of PM10/PM2.5. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-103 DRI Unit #1 Coating Bin Filter

Process Type: 81.900 (Other Ferrous Metal Industry Processes)Primary Fuel:

Throughput: 3858090.00 tons/yr

Process Notes: Iron oxide pellets are given a light coating of pulverized limestone prior to being transferred to the furnace. The limestone coating helps to reduce the

tendency of the pellets to fuse together during the reduction process. Water is added to the limestone to make a water-based slurry, which is then applied to the pellets. The pulverized limestone is periodically received by truck and pneumatically conveyed into a storage bin. The act of filling the Iron Oxide Coating Bin may generate dust emissions

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: 0.0200 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BACT for emissions of PM10 and PM2.5 from Iron Oxide Coating Bin is selected to be local collection and control through a fabric filter employing enhanced filter media Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-203 DRI Unit #2 Coating Bin Filter

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 3858090.00 tons/yr

Process Notes: Iron oxide pellets are given a light coating of pulverized limestone prior to being transferred to the furnace. The limestone coating helps to reduce the

tendency of the pellets to fuse together during the reduction process. Water is added to the limestone to make a water-based slurry, which is then applied to the pellets. The pulverized limestone is periodically received by truck and pneumatically conveyed into a storage bin. The act of filling the Iron Oxide Coating Bin may generate dust emissions

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: 0.0200 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BACT for emissions of PM10 and PM2.5 from Iron Oxide Coating Bin is selected to be local collection and control through a fabric filter employing enhanced filter media Est. % Efficiency: 99.500 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-104 DRI Unit #1 Iron Oxide Fines Handling

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 385039.00 tons/yr

Process Notes: The screening and handling of iron oxide pellets generates a quantity of undersized material referred to as fines. This material is too small to charge to

the shaft furnace, where it would clog the flow of reducing gas, and contribute to the problem of pellets fusing together during the reduction reaction, and impeding the flow of pellets out of the furnace. Iron oxide fines are stored at the DRI units temporarily. The fines will be stored in an outdoor pile. Fines will typically be transferred by truck and front end loader.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: NCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (B) Nucor will control dust emissions through the application of a chemical surface stabilizer on the iron oxide storage pile. Water sprays will be used locally to control dust generation from activities such as stacking/reclaiming and pile maintenance activity. These activities will be minimized as much as practicable in order to prevent unnecessary dust emissions. Est. % Efficiency: 95.000 Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-204 DRI Unit #1 Iron Oxide Fines Handling

Process Type: 81.900 (Other Ferrous Metal Industry Processes) Primary Fuel: Throughput: 385039.00 tons/yr

Process Notes: The screening and handling of iron oxide pellets generates a quantity of undersized material referred to as fines. This material is too small to charge to

the shaft furnace, where it would clog the flow of reducing gas, and contribute to the problem of pellets fusing together during the reduction reaction, and impeding the flow of pellets out of the furnace. Iron oxide fines are stored at the DRI units temporarily. The fines will be stored in an outdoor pile. Fines will typically be transferred by truck and front end loader.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Nucor will control dust emissions through the application of a chemical surface stabilizer on the iron oxide storage pile. Water sprays will be used locally to control dust generation from activities such as stacking/reclaiming and pile maintenance activity. These activities will be minimized as much as practicable in order to prevent unnecessary dust emissions. Est. % Efficiency: 95.000Est. % Efficiency: 95.000

Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-113 - DRI Unit #1 Process Water Cooling Tower

Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 26857.00 gpm

Process Notes: The cross-flow cooling towers continuously circulate cooling water through heat exchangers and other equipment where the water absorbs heat. That

heat is then rejected to the atmosphere by the partial evaporation of the water in cooling towers where up-flowing air is contacted with the circulating down-flow of water. The loss of evaporated water into the air exhausted to the atmosphere is replaced by "make-up" water.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4000 T/YR Standard Emission: 1000.0000 MG/L TDS Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BACT is a combination of less than or equal to 1,000 milligrams per liter TDS concentration in the cooling water and drift eliminators employing a drift maximum of 0.0005%. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The design drift efficiency of 0.0005% and cooling tower circulating water rate shall be verified by vendor certification. Collect a grab sample of the cooling water at least once per day for seven consecutive operating days, analyze each sample in accordance with Standard Method 2540 C or EPA Method 160.1, and record the results. Subsequently, collect a grab sample of the cooling water at least once per week, analyze each sample using one of the aforementioned methods, and record the results. Maintain the assembled cooling tower drift eliminators consistent with the manufacturer's recommendation as described in the operating manual for the cooling tower. Compliance shall be documented by maintaining a log of maintenance activity performed on the cooling tower drift eliminators.

## Process/Pollutant Information

PROCESS NAME: DRI-213 - DRI Unit #2 Process Water Cooling Tower

Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 26857.00 gpm

Process Notes: The cross-flow cooling towers continuously circulate cooling water through heat exchangers and other equipment where the water absorbs heat. That

heat is then rejected to the atmosphere by the partial evaporation of the water in cooling towers where up-flowing air is contacted with the circulating down-flow of water. The loss of evaporated water into the air exhausted to the atmosphere is replaced by "make-up" water.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4000 T/YR Standard Emission: 1000.0000 MG/L TDS Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BACT is a combination of less than or equal to 1,000 milligrams per liter TDS concentration in the cooling water and drift eliminators employing a drift maximum of 0.0005%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The design drift efficiency of 0.0005% and cooling tower circulating water rate shall be verified by vendor certification. Collect a grab sample of the cooling water at least once per day for seven consecutive operating days, analyze each sample in accordance with Standard Method 2540 C or EPA Method 160.1, and record the results. Subsequently, collect a grab sample of the cooling water at least once per week, analyze each sample using one of the aforementioned methods, and record the results. Maintain the assembled cooling tower drift eliminators consistent with the manufacturer's recommendation as described in the operating manual for the cooling tower. Compliance shall be documented by maintaining a log of maintenance activity performed on the cooling tower drift eliminators.

## Process/Pollutant Information

PROCESS NAME: DRI-114 - DRI Unit #1 Clean Water Cooling Tower

Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 17611.00 gpm

Process Notes: The cross-flow cooling towers continuously circulate cooling water through heat exchangers and other equipment where the water absorbs heat. That

heat is then rejected to the atmosphere by the partial evaporation of the water in cooling towers where up-flowing air is contacted with the circulating down-flow of water. The loss of evaporated water into the air exhausted to the atmosphere is replaced by "make-up" water.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.2900 T/YR Standard Emission: 1000.0000 MG/L TDS Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BACT is a combination of less than or equal to 1,000 milligrams per liter TDS concentration in the cooling water and drift eliminators employing a drift maximum of 0.0005%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The design drift efficiency of 0.0005% and cooling tower circulating water rate shall be verified by vendor certification. Collect a grab sample of the cooling water at least once per day for seven consecutive operating days, analyze each sample in accordance with Standard Method 2540 C or EPA Method 160.1, and record the results. Subsequently, collect a grab sample of the cooling water at least once per week, analyze each sample using one of the aforementioned methods, and record the results. Maintain the assembled cooling tower drift eliminators consistent with the manufacturer's recommendation as described in the operating manual for the cooling tower. Compliance shall be documented by maintaining a log of maintenance activity performed on the cooling tower drift eliminators.



## Process/Pollutant Information

PROCESS DRI-214 - DRI Unit #1 Clean Water Cooling TowerPROCESS

NAME: DRI-214 - DRI Unit #1 Clean Water Cooling Tower

Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 17611.00 gpm

Process Notes: The cross-flow cooling towers continuously circulate cooling water through heat exchangers and other equipment where the water absorbs heat. That

heat is then rejected to the atmosphere by the partial evaporation of the water in cooling towers where up-flowing air is contacted with the circulating down-flow of water. The loss of evaporated water into the air exhausted to the atmosphere is replaced by "make-up" water.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.2900 T/YR Standard Emission: 1000.0000 MG/L TDS Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BACT is a combination of less than or equal to 1,000 milligrams per liter TDS concentration in the cooling water and drift eliminators employing a drift maximum of 0.0005%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The design drift efficiency of 0.0005% and cooling tower circulating water rate shall be verified by vendor certification. Collect a grab sample of the cooling water at least once per day for seven consecutive operating days, analyze each sample in accordance with Standard Method 2540 C or EPA Method 160.1, and record the results. Subsequently, collect a grab sample of the cooling water at least once per week, analyze each sample using one of the aforementioned methods, and record the results. Maintain the assembled cooling tower drift eliminators consistent with the manufacturer's recommendation as described in the operating manual for the cooling tower. Compliance shall be documented by maintaining a log of maintenance activity performed on the cooling tower drift eliminators.



## Process/Pollutant Information

PROCESS NAME: DRI-117 - Briquetting Mill

Process Type: 81.290 (Other Steel Manufacturing Processes)Process Type: 81.290 (Other Steel Manufacturing Processes)

Primary Fuel: Throughput: 551155.70 tons/yr

Process Notes: The screening and handling of DRI pellets results in undersize material, or fines. DRI fines will be recycled and formed into bricks for use in the blast

furnace or off-site EAF furnaces. Fines will be mixed with a cement binder, and then pressed in molds to form bricks of uniform size and shape. After curing on racks, the bricks are transported for shipment off-site.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 0.2600 T/YR Standard Emission: 0.0022 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) High-energy wet scrubber. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling. Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively level across the particle size range. However, DRI particles are known to react with oxygen in the atmosphere, reoxidizing in an exothermic reaction. This reoxidation process frequently causes fires when the DRI material is improperly handled, particularly when freshly discharged from the furnace before being passivated. The nature of the DRI particulate being captured makes the application of a fabric filter to this source a significant safety hazard, and thus a baghouse is technically infeasible.



## Process/Pollutant Information

PROCESS NAME: DRI-118 - DRI Barge Loading Dock

Process Type: 99.190 (Other Fugitive Dust Sources) Primary Fuel: Throughput: 5511557.00 tons/yr

Process Notes: DRI pellets will be loaded for shipment to other Nucor facilities by barge. Due to the special handling requirement of the DRI product, the loadingProcess Notes: DRI pellets will be loaded for shipment to other Nucor facilities by barge. Due to the special handling requirement of the DRI product, the loading dock will be specialized for the loading of DRI product.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7800 LB/H Emission Limit 2: 0.6500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) High-energy wet scrubber. Additionally, hooded conveyors and enclosed transfer stations will be installed to limit emissions from material handling. Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: A scrubber will be installed on the product storage silos for DRI dust control. Wet suppression of dust generating sources by water sprays will be utilized at each storage pile site. Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively level across the particle size range. However, DRI particles are known to react with oxygen in the atmosphere, reoxidizing in an exothermic reaction. This reoxidation process frequently causes fires when the DRI material is improperly handled, particularly when freshly discharged from the furnace before being passivated. The nature of the DRI particulate being captured makes the application of a fabric filter to this source a significant safety hazard, and thus a baghouse is technically infeasible.



## Process/Pollutant Information

PROCESS NAME: DRI-115 - Product Screen Dust Collection

Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 5511557.00 tons/yr

Process Notes: The DRI fines collected from the screening operation are transported to the Briquetting Mill. This transportation operation generates particulate

matter emissions.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4000 LB/H Emission Limit 2: 0.9600 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) High-energy wet scrubber Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively level across the particle size range. However, DRI particles are known to react with oxygen in the atmosphere, reoxidizing in an exothermic reaction. This reoxidation process frequently causes fires when the DRI material is improperly handled, particularly when freshly discharged from the furnace before being passivated. The nature of the DRI particulate being captured makes the application of a fabric filter to this source a significant safety hazard, and thus a baghouse is technically infeasible.



## Process/Pollutant Information

PROCESS NAME: DRI-116 - Screened Product Transfer Dust Collection Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 5511557.00 tons/yr

Process Notes: Prior to final shipment, the DRI pellets are screened to remove fines. This screening process generates particulate matter emissions.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7100 LB/H Emission Limit 2: 0.4900 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: YCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (A) high-energy wet scrubber Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively level across the particle size range. However, DRI particles are known to react with oxygen in the atmosphere, reoxidizing in an exothermic reaction. This reoxidation process frequently causes fires when the DRI material is improperly handled, particularly when freshly discharged from the furnace before being passivated. The nature of the DRI particulate being captured makes the application of a fabric filter to this source a significant safety hazard, and thus a baghouse is technically infeasible.



## Process/Pollutant Information

PROCESS NAME: DRI-107 - DRI Unit No. 1 Furnace Dust Collection

Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 2755778.00 tons/yr

Process Notes: The DRI Product exits the cooling zone of the shaft furnace and falls onto a waiting conveyor for transport to the product silos. This discharge point has

a high potential for dust generation, since any fines generated during the action of the pellets passing through the reactor are also discharged.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9300 LB/H Emission Limit 2: 2.9200 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) high-energy wet scrubber Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively levelPollutant/Compliance Notes: Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively level across the particle size range. However, DRI particles are known to react with oxygen in the atmosphere, reoxidizing in an exothermic reaction. This reoxidation process frequently causes fires when the DRI material is improperly handled, particularly when freshly discharged from the furnace before being passivated. The nature of the DRI particulate being captured makes the application of a fabric filter to this source a significant safety hazard, and thus a baghouse is technically infeasible.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.2400 LB/H Emission Limit 2: 4.7400 T/YR Standard Emission: 0.0700 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) The seal gas is removed before the flue gas is treated for NOX control. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The SCR controlling NOX from the reformer contributes ammonia to the reformer flue gas. Ammonia would react with the lime coating on the iron oxide pellets to form ammonium bicarbonate and ammonium carbamate, which are a sticky white salt. These compounds would tend to promote fusion of the iron ore pellets, which can cause a significant process upset as the clumped product cannot be removed from the shaft furnace. Nitrogen oxides (NOx)

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.7100 LB/H Emission Limit 2: 2.7100 T/YR Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N) BACT for CO is determined as good combustion practices for the Reformer Flue gas and so no additional control is feasible for the use of a small portion of this flue gas as seal gas. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Carbon monoxide (CO)



## Process/Pollutant Information

PROCESS NAME: DRI-207 - DRI Unit No. 2 Furnace Dust Collection Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 2755778.00 tons/yr

Process Notes: Prior to final shipment, the DRI pellets are screened to remove fines. This screening process generates particulate matter emissions.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9300 LB/H Emission Limit 2: 2.9200 T/YR Standard Emission: 0.0020 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) High-energy wet scrubber Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: Baghouses often are capable of 99.5% removal efficiencies, and baghouse removal efficiency is relatively level across the particle size range. However, DRI particles are known to react with oxygen in the atmosphere, reoxidizing in an exothermic reaction. This reoxidation process frequently causes fires when the DRI material is improperly handled, particularly when freshly discharged from the furnace before being passivated. The nature of the DRI particulate being captured makes the application of a fabric filter to this source a significant safety hazard, and thus a baghouse is technically infeasible.

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.2400 LB/H Emission Limit 2: 4.7400 T/YR Standard Emission: 0.0700 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) The seal gas is removed before the flue gas is treated for NOX control. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The SCR controlling NOX from the reformer contributes ammonia to the reformer flue gas. Ammonia would react with the lime coating on the iron oxide pellets to form ammonium bicarbonate and ammonium carbamate, which are a sticky white salt. These compounds would tend to promote fusion of the iron ore pellets, which can cause a significant process upset as the clumped product cannot be removed from the shaft furnace. Nitrogen oxides (NOx)

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.7100 LB/H Emission Limit 2: 2.7100 T/YR Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) BACT for CO isdetermined as good combustion practices for the Reformer Flue gas and so no additional control is feasible for the use of a small portion of this flue gas as seal gas. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: Carbon monoxide (CO)



## Process/Pollutant InformationPROCESS

NAME: DRI-109 - DRI Unit #1 Package Boiler Flue Stack

Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Natural Gas Throughput: 1760.00 Billion Btu/yr

Process Notes: The package boilers provide steam to each DRI unit. The steam is primarily used to heat the reboiler in the acid gas absorption system, as well as for

utility purposes.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Mthd 201A Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.3800 LB/H Emission Limit 2: 8.6400 T/YR Standard Emission: 0.0046 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 11.4200 LB/H Emission Limit 2: 41.5400 T/YR Standard Emission: 0.0390 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good Combustion PracticesEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Emissions of SO2 are usually attributable to the sulfur contained within the fuel being combusted. Therefore the use of a low sulfur fuel can drastically reduce emissions of SO2 when compared to other potential fuels. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sulfur dioxide: Purchase natural gas with a sulfur content less than 2000 grains per million standard cubic feet of gas. Sulfur content shall be monitored and recorded monthly and shall be based on either the natural gas analysis provided by the supplier or direct sampling by the facility

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.9400 LB/H Emission Limit 2: 3.4100 T/YR Standard Emission: 0.0032 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) BACT for the package boiler is selected to be low NOX burners, combined with selective catalytic reduction. Est. % Efficiency: 90.000 Compliance Verified: NoPollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.5600 LB/H Emission Limit 2: 4.7500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-209 - DRI Unit #2 Package Boiler Flue Stack

Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Natural Gas Throughput: 1760.00 Billion Btu/yr

Process Notes: The package boilers provide steam to each DRI unit. The steam is primarily used to heat the reboiler in the acid gas absorption system, as well as for

utility purposes.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Mthd 201A Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.3800 LB/H Emission Limit 2: 8.6400 T/YR Standard Emission: 0.0046 GRAINS/DSCFDid factors, other then air pollution technology considerations influence the BACT decisions: N

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 11.4200 LB/H Emission Limit 2: 41.5400 T/YR Standard Emission: 0.0390 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good Combustion Practices Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Emissions of SO2 are usually attributable to the sulfur contained within the fuel being combusted. ThereforeControl Method: (P) Emissions of SO2 are usually attributable to the sulfur contained within the fuel being combusted. Therefore the use of a low sulfur fuel can drastically reduce emissions of SO2 when compared to other potential fuels. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sulfur dioxide: Purchase natural gas with a sulfur content less than 2000 grains per million standard cubic feet of gas. Sulfur content shall be monitored and recorded monthly and shall be based on either the natural gas analysis provided by the supplier or direct sampling by the facility

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.9400 LB/H Emission Limit 2: 3.4100 T/YR Standard Emission: 0.0032 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) BACT for the package boiler is selected to be low NOX burners, combined with selective catalytic reduction. Est. % Efficiency: 90.000 Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.1900 LB/H Emission Limit 2: 4.7500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRI-112 - DRI Unit No. 1 Product storage silo Dust Collection

Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 2755778.00 tons/yr

Process Notes: the DRI Product exits the cooling zone of the shaft furnace and falls onto a waiting conveyor for transport to the product silos. Transfer into and out of

the Silo has a high potential for dust generation, since any fines generated during the action of the pellets passing through the reactor are also discharged.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Other Test Mthd 27 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9900 LB/H Emission Limit 2: 3.3700 T/YR Standard Emission: 0.0100 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) In order to prevent the reducing gas from escaping the furnace, a higher pressure gas called seal gas is applied at both the charging and discharging opening. The seal gas is allowed to escape the furnace while the reducing gas is retained. This seal gas is merely a small amount of cooled flue gas from the reformer combustion side, and primarily consists of atmospheric nitrogen, carbon dioxide and water vapor. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sulfur dioxide and particulate matter BACT was determined to treat the spent reducing gas being sent to the Reformer as combustion fuel and so no additional control is feasible for the seal gas. Emissions of these two pollutants are expected to be less than five tons per year combined. It should be noted that all of the spent reducing gas has particulate matter emission controlled. Particulate matter (10 microns or less) (PM10)

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0CAS Number: 630-08-0

Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5700 LB/H Emission Limit 2: 2.1700 T/YR Standard Emission: 0.0040 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) In order to prevent the reducing gas from escaping the furnace, a higher pressure gas called seal gas is applied at both the charging and discharging opening. The seal gas is allowed to escape the furnace while the reducing gas is retained. This seal gas is merely a small amount of cooled flue gas from the reformer combustion side, and primarily consists of atmospheric nitrogen, carbon dioxide and water vapor. BACT was good combustion practices in the reformer. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.9900 LB/H Emission Limit 2: 3.7900 T/YR Standard Emission: 0.0700 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The seal gas is removed before the flue gas is treated for NOX control. The SCR controlling NOX from the reformer contributes ammonia to the reformer flue gas. Ammonia would react with the lime coating on the iron oxide pellets to form ammonium bicarbonate and ammonium carbamate, which are a sticky white salt. These compounds would tend to promote fusion of the iron ore pellets, which can cause a significant process upset as the clumped product cannot be removed from the shaft furnace Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Nitrogen oxides (NOx)

## Process/Pollutant Information

PROCESS NAME: DRI-212 - DRI Unit No. 2 Product storage silo Dust Collection

Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 2755778.00 tons/yr

Process Notes: the DRI Product exits the cooling zone of the shaft furnace and falls onto a waiting conveyor for transport to the product silos. Transfer into and out of

the Silo has a high potential for dust generation, since any fines generated during the action of the pellets passing through the reactor are also discharged.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Other Test Mthd 27 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9900 LB/H Emission Limit 2: 3.3700 T/YR Standard Emission: 0.0100 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) In order to prevent the reducing gas from escaping the furnace, a higher pressure gas called seal gas is applied at both the charging and discharging opening. The seal gas is allowed to escape the furnace while the reducing gas is retained. This seal gas is merely a small amount of cooled flue gas from the reformer combustion side, and primarily consists of atmospheric nitrogen, carbon dioxide and water vapor. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sulfur dioxide and particulate matter BACT was determined to treat the spent reducing gas being sent to the Reformer as combustion fuel and so no additional control is feasible for the seal gas. Emissions of these two pollutants are expected to be less than five tons per year combined. It should be noted that all of the spent reducing gas has particulate matter emission controlled. Particulate matter (10 microns or less) (PM10)

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds )Pollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.5700 LB/H Emission Limit 2: 2.1700 T/YR Standard Emission: 0.0040 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) In order to prevent the reducing gas from escaping the furnace, a higher pressure gas called seal gas is applied at both the charging and discharging opening. The seal gas is allowed to escape the furnace while the reducing gas is retained. This seal gas is merely a small amount of cooled flue gas from the reformer combustion side, and primarily consists of atmospheric nitrogen, carbon dioxide and water vapor. BACT was good combustion practices in the reformer. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.9900 LB/H Emission Limit 2: 3.7900 T/YR Standard Emission: 0.0700 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The seal gas is removed before the flue gas is treated for NOX control. The SCR controlling NOX from the reformer contributes ammonia to the reformer flue gas. Ammonia would react with the lime coating on the iron oxide pellets to form ammonium bicarbonate and ammonium carbamate, which are a sticky white salt. These compounds would tend to promote fusion of the iron ore pellets, which can cause a significant process upset as the clumped product cannot be removed from the shaft furnace Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Nitrogen oxides (NOx)

## Process/Pollutant Information

PROCESS NAME: DRI-110 - DRI Unit No. 1 Hot Flare

Process Type: 19.390 (Other Flares) Primary Fuel: DRI Reducing Gas Throughput: 1180.00 acfm

Process Notes: The reducing furnace must run as close to steady state operation as possible in order to produce product of acceptable quality. Due to the nature of the

reducing gas recycle system periodic shifts in pressure may occur. The pressure of the reducing gas must be maintained below that of the seal gas system or an uncontrolled release of reducing gas will result from the top seal and the bottom seal. To maintain this condition, the reducing gas is occasionally flared to prevent a rise in pressure. The Hot Flare prevents an uncontrolled release of carbon monoxide from the system by combusting the reducing gas.

POLLUTANT NAME: Particulate matter, filterable (FPM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.2700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) the best available technology for controlling PM10/PM2.5 from the natural gas pilot is good combustion practice Est. % Efficiency: 50.000 Compliance Verified: No Pollutant/Compliance Notes: The reducing gas contains incombustible particulate matter in the gas stream as gas is recycled from the shaft furnace. Therefore, the control of particulate from the hot flare is best addressed by cleaning of the reducing gas prior to its combustion. Particulate matter cleaning of the spent reducing gas has already been addressed, so BACT for PM is venting to the Hot Flare after the spent reducing gas has been cleaned by the wet scrubbers described as BACT for the Reformer Flue Gas. The flare shall be of the continuous pilot variety, fueled by natural gas.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 1.2700 LB/H Emission Limit 2: 2.5800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) A low-NOX fuel is one which results in a lower generation rate of NOX over traditional fossil fuels, on an equal energy basis. DRI reducing gas is a low-NOX fuel, generating less NOX per unit of energy as natural gas. This property is due to the low-BTU value of reducing gas, which burns at a cooler temperature, preventing the formation of much of the NOX seen with hotter natural gas combustion. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.4700 LB/H Emission Limit 2: 2.5800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The reducing gas is rich in carbon monoxide and hydrogen. The pilot for the flare is natural gas. Good combustion practices are used to reduce emissions of CO, as well as other pollutants, by optimizing conditions in the combustion zone of a fuel burning source. Good combustion practices typically entail introducing the proper ratio of combustion air to the fuel, maintaining a minimum temperature in the firebox of the combustor, or a minimum residence time of fuel and air in the combustion zone. By employing good combustion practices CO emissions may be greatly reduced. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The hot flare will combust reducing gas, which contains a significant portion of carbon monoxide. Nucor will install a flare tip employing good combustion practices to control the generation of CO emissions due to incomplete combustion of reducing gas.

## Process/Pollutant Information

PROCESS NAME: DRI-210 - DRI Unit No. 1 Hot Flare

Process Type: 19.390 (Other Flares) Primary Fuel: DRI Reducing Gas Throughput: 1180.00 acfm

Process Notes: The reducing furnace must run as close to steady state operation as possible in order to produce product of acceptable quality. Due to the nature of the

reducing gas recycle system periodic shifts in pressure may occur. The pressure of the reducing gas must be maintained below that of the seal gas system or an uncontrolled release of reducing gas will result from the top seal and the bottom seal. To maintain this condition, the reducing gas is occasionally flared to prevent a rise in pressure. The Hot Flare prevents an uncontrolled release of carbon monoxide from the system by combusting the reducing gas.

POLLUTANT NAME: Particulate matter, filterable (FPM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.2700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) the best available technology for controlling PM10/PM2.5 from the natural gas pilot is good combustion practices. Est. % Efficiency: 50.000 Compliance Verified: No Pollutant/Compliance Notes: The reducing gas contains incombustible particulate matter in the gas stream as gas is recycled from the shaft furnace. Therefore, the control of particulate from the hot flare is best addressed by cleaning of the reducing gas prior to its combustion. Particulate matter cleaning of the spent reducing gas has already been addressed, so BACT for PM is venting to the Hot Flare after the spent reducing gas has been cleaned by the wet scrubbers described as BACT for the Reformer Flue Gas. The flare shall be of the continuous pilot variety, fueled by natural gas.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 1.2700 LB/H Emission Limit 2: 2.5800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) A low-NOX fuel is one which results in a lower generation rate of NOX over traditional fossil fuels, on an equal energy basis. DRI reducing gas is a low-NOX fuel, generating less NOX per unit of energy as natural gas. This property is due to the low-BTU value of reducing gas, which burns at a cooler temperature, preventing the formation of much of the NOX seen with hotter natural gas combustion. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.2700 LB/H Emission Limit 2: 2.5800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The reducing gas is rich in carbon monoxide and hydrogen. The pilot for the flare is natural gas. Good combustion practices are used to reduce emissions of CO, as well as other pollutants, by optimizing conditions in the combustion zone of a fuel burning source. Good combustion practices typically entail introducing the proper ratio of combustion air to the fuel, maintaining a minimum temperature in the firebox of the combustor, or a minimum residence time of fuel and air in the combustion zone. By employing good combustion practices CO emissions may be greatly reduced. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The hot flare will combust reducing gas, which contains a significant portion of carbon monoxide. Nucor will install a flare tip employing good combustion practices to control the generation of CO emissions due to incomplete combustion of reducing gas.

## Process/Pollutant Information

PROCESS NAME: DRI-111 - DRI Unit #1 Acid Gas Absorption Vent

Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 30624.00 scfm

Process Notes: Acid gases, primarily hydrogen sulfide and carbon dioxide, are removed from the DRI top gas prior to its use as a fuel in the acid gas absorption unit.

This unit is an amine-based absorption scrubber, which selectively dissolves acid gases from the top gas fuel. The amine solution is then regenerated by applying heat in a steam reboiler, which liberates the acid gases from solution. The resulting gas stream is treated for the removal of sulfur compounds prior to being vented.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Emissions of PM10 from the acid gas absorption vent are due to the absorption of PM10/PM2.5 in the amine unit treating the top gas fuel, which is partially released during the amine regeneration step. Due to the low quantity of emissions from the acid gas absorption vent, less than one ton per year from both DRI units combined, No technologies exist which meet the environmental, energy and economic considerations inherent in a BACT review. BACT for emissions of PM10/PM2.5 from the acid gas absorption vent is determined to be no control. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 0.5800 LB/H

Emission Limit 2: 2.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BACT is selected to be treatment of the acid gas stream through the use of a sulfur redox catalyst, such as the SulfaTreat catalyst bed or LO-CAT Redox process, for the removal of H2S. Nucor will install a redox catalyst on each of the acid gas absorption vents at the DRI facility for the control of sulfur compound emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The acid gas absorber selectively removes acid gases such as hydrogen sulfide and carbon dioxide from the top gas fuel, prior to combustion at the reformer. The amine-based absorption medium is then regenerated by the application of heat, releasing the absorbed acid gases as a separate gas stream. The efficiency of the DRI process benefits from the removal of these gases, which are no longer heated during combustion. The energy saved from no longer heating inert gases in the top gas fuel is then available for the reforming reaction. An added benefit is the isolation of hydrogen sulfide, which can then be treated more effectively.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.7300 LB/H Emission Limit 2: 2.6500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Emissions of carbon monoxide from the acid gas absorption vent are due to the slight absorption of CO in the amine unit treating the top gas fuel. Due to the low quantity of emissions from the acid gas absorption vent, no technologies exist which meet the environmental, energy and economic considerations inherent in a BACT review. BACT for emissions of carbon monoxide from the acid gas absorption vent is determined to be no control Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: DRI-211 - DRI Unit #1 Acid Gas Absorption Vent

Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput: 30624.00 scfm

Process Notes: Acid gases, primarily hydrogen sulfide and carbon dioxide, are removed from the DRI top gas prior to its use as a fuel in the acid gas absorption unit.

This unit is an amine-based absorption scrubber, which selectively dissolves acid gases from the top gas fuel. The amine solution is then regenerated by applying heat in a steam reboiler, which liberates the acid gases from solution. The resulting gas stream is treated for the removal of sulfur compounds prior to being vented.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Emissions of PM10 from the acid gas absorption vent are due to the absorption of PM10/PM2.5 in the amine unit treating the top gas fuel, which is partially released during the amine regeneration step. Due to the low quantity of emissions from the acid gas absorption vent, less than one ton per year from both DRI units combined, No technologies exist which meet the environmental, energy and economic considerations inherent in a BACT review. BACT for emissions of PM10/PM2.5 from the acid gas absorption vent is determined to be no control.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 0.5800 LB/H

Emission Limit 2: 2.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The acid gas absorber selectively removes acid gases such as hydrogen sulfide and carbon dioxide from the top gas fuel, prior to combustion at the reformer. The amine-based absorption medium is then regenerated by the application of heat, releasing the absorbed acid gases as a separate gas stream. The efficiency of the DRI process benefits from the removal of these gases, which are no longer heated during combustion. The energy saved from no longer heating inert gases in the top gas fuel is then available for the reforming reaction. An added benefit is the isolation of hydrogen sulfide, which can then be treated more effectively. BACT is selected to be treatment of the acid gas stream through the use of a sulfur redox catalyst, such as the SulfaTreat catalyst bed or LO-CAT Redox process, for the removal of H2S. Nucor will install a redox catalyst on each of the acid gas absorption vents at the DRI facility for the control of sulfur compound emissions.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.7300 LB/H Emission Limit 2: 2.6500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Emissions of carbon monoxide from the acid gas absorption vent are due to the slight absorption of CO in the amine unit treating the top gas fuel. Due to the low quantity of emissions from the acid gas absorption vent, no technologies exist which meet the environmental, energy and economic considerations inherent in a BACT review. BACT for emissions of carbon monoxide from the acid gas absorption vent is determined to be no control

## Process/Pollutant Information

PROCESS NAME: DRI-106 - DRI Unit No. 1 Upper Seal Gas Vent

Process Type: 81.290 (Other Steel Manufacturing Processes)

Primary Fuel: Throughput: 1765.00 acfm

Process Notes: Iron oxide pellets are fed continuously into the shaft furnace from the top, and pass down through the reaction area by gravity. Reducing gas from the

Reformer is passed through the iron oxide as it progresses through the furnace, in a countercurrent fashion. The DRI product then continuously exits the bottom of the furnace onto a waiting conveyor. In order to prevent the reducing gas from escaping the furnace, a higher pressure gas called seal gas is applied at both the charging and discharging opening. The seal gas is allowed to escape the furnace while the reducing gas is retained. Due to the higher seal gas pressure, a portion is also entrained into the reactor and combined with the spent reducing gas travels back to the Reformer. This seal gas is merely a small amount of cooled flue gas from the reformer combustion side, and primarily consists of atmospheric nitrogen, carbon dioxide and water vapor.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.2600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: particulate matter BACT was determined to treat the spent reducing gas being sent to the Reformer as combustion fuel and so no additional control is feasible for the seal gas. It is already treated before the seal gas is split off.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sulfur dioxide BACT was determined to treat the spent reducing gas being sent to the Reformer as combustion fuel. The seal gas is removed before the spent reducing gas is treated for SO2 control, and so no additional control is feasible for the seal gas.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5300 LB/H Emission Limit 2: 2.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT for CO was already determined as good combustion practices for the Reformer Flue gas and so no additional control is feasible for the use of a small portion of this flue gas as seal gas.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 0.7500 LB/H

Emission Limit 2: 2.8400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The seal gas is removed before the flue gas is treated for NOX control. The SCR controlling NOX from the reformer contributes ammonia to the reformer flue gas. Ammonia would react with the lime coating on the iron oxide pellets to form ammonium bicarbonate and ammonium carbamate, which are a sticky white salt. These compounds would tend to promote fusion of the iron ore pellets, which can cause a significant process upset as the clumped product cannot be removed from the shaft furnace.



## Process/Pollutant Information

PROCESS NAME: DRI-206 - DRI Unit No. 2 Upper Seal Gas Vent

Process Type: 81.290 (Other Steel Manufacturing Processes)

Primary Fuel: Throughput: 1765.00 acfm

Process Notes: Iron oxide pellets are fed continuously into the shaft furnace from the top, and pass down through the reaction area by gravity. Reducing gas from the

Reformer is passed through the iron oxide as it progresses through the furnace, in a countercurrent fashion. The DRI product then continuously exits the bottom of the furnace onto a waiting conveyor. In order to prevent the reducing gas from escaping the furnace, a higher pressure gas called seal gas is applied at both the charging and discharging opening. The seal gas is allowed to escape the furnace while the reducing gas is retained. Due to the higher seal gas pressure, a portion is also entrained into the reactor and combined with the spent reducing gas travels back to the Reformer. This seal gas is merely a small amount of cooled flue gas from the reformer combustion side, and primarily consists of atmospheric nitrogen, carbon dioxide and water vapor.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/HEmission Limit 2: 0.2600 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: particulate matter BACT was determined to treat the spent reducing gas being sent to the Reformer as combustion fuel and so no additional control is feasible for the seal gas. It is already treated before the seal gas is split off.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sulfur dioxide BACT was determined to treat the spent reducing gas being sent to the Reformer as combustion fuel. The seal gas is removed before the spent reducing gas is treated for SO2 control, and so no additional control is feasible for the seal gas.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.7500 LB/H Emission Limit 2: 2.8400 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The seal gas is removed before the flue gas is treated for NOX control. The SCR controlling NOX from the reformer contributes ammonia to the reformer flue gas. Ammonia would react with the lime coating on the iron oxide pellets to form ammonium bicarbonate and ammonium carbamate, which are a sticky white salt. These compounds would tend to promote fusion of the iron ore pellets, which can cause a significant process upset as the clumped product cannot be removed from the shaft furnace.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5300 LB/H Emission Limit 2: 2.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT for CO was already determined as good combustion practices for the Reformer Flue gas and so no additional control is feasible for the use of a small portion of this flue gas as seal gas.



## Process/Pollutant Information

PROCESS NAME: DRI-108 - DRI Unit #1 Reformer Main Flue Stack

Process Type: 81.200 (Steel Production (excludes Steel & Iron Foundry Processes))Primary

Fuel: Iron Ore and Natural Gas

Throughput: 12168.00 Billion Btu/yr

Process Notes: The Direct Reduction Iron process consists of two main components, a Reformer and the DRI reactor. Natural gas passes through special catalyst tubes

where the natural gas dissociates into a reducing gas rich in carbon monoxide and hydrogen, which are the primary chemicals used to remove the oxygen from the iron ore. The reducing gas is fed in from the bottom of the DRI Reactor. The gas flows countercurrent to the descending iron ore pellets. At the top of the reactor, the partially spent reducing gas exits and is recompressed, enriched with natural gas, preheated, and transported back to the gas reformer. The reformer reforms the mixture back to 95% hydrogen plus carbon monoxide, which is then ready for re-use by the direct reduction furnace. Some of the reducing gas that has already passed over the iron ore in the DRI reactor (the spent reducing gas is also known as top gas) is mixed with the natural gas that is being combusted in the reformer and is also therefore combusted.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Other Test Mthd 27 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 9.9500 LB/H Emission Limit 2: 37.9000 T/YR Standard Emission: 0.0027 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) a high-energy wet scrubber can accommodate the large volume of gas that is generated by the DRI process, and is insensitive to variations in dust loading. Additionally, the safety aspects of using a wet system provide the most viable scenario for PM10/PM2.5 emissions control from the DRI process, by cleaning the top gas fuel stream prior to combustion. Nucor will also maintain good combustion practices at the reformer for particulate control of the natural gas combustion, but these actions are not likely to significantly contribute to the control of PM10 emissions due to the inorganic nature of topgas. Est. % Efficiency: 99.000 Compliance Verified: Yes Pollutant/Compliance Notes: The top gas contains incombustible particulate matter in the stream as it leaves the shaft furnace. This particulate would pass through the combustion zone and be emitted in the reformer flue gas if left untreated.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 10.8800 LB/HEmission Limit 2: 41.4500 T/YR

Standard Emission: 0.0070 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) The low NOX combustion qualities of top gas fuel are inherent in the DRI reforming process. Additionally, low-NOX burners may be used with the boosted heating value of top gas mixed with natural gas, without unduly penalizing combustion efficiency. Finally, SCR may be applied to the resulting flue gas stream from combustion in the reformer. Therefore, BACT is selected to be low NOX fuel combustion, combined with low NOX burners and selective catalytic reduction. Est. % Efficiency: 90.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 8.3800 LB/H Emission Limit 2: 12.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency: 98.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 62.1800 LB/H Emission Limit 2: 236.8600 T/YRStandard Emission: 0.0400 LB/MMBTU

Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency: 98.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: Method 8 Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 3.1600 LB/H Emission Limit 2: 11.5000 T/YR Standard Emission: 0.0020 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BACT is selected to be the removal of hydrogen sulfide from the top gas fuel through acid gas scrubbing. This technology was identified as the most stringent control method of the available technologies, and has the added benefit of slightly reducing energy demand at the reformer. Nucor will install and acid gas scrubbing system for top gas prior to its use as fuel in the reformer. BACT for natural gas is to purchase natural gas containing no more than 2000 grains of Sulfur per MM scf. Est. % Efficiency: 95.000 Compliance Verified: Yes Pollutant/Compliance Notes: Method 8 - Determination of Sulfuric Acid Mist and Sulfur Dioxide Emissions from Stationary Sources. Emissions of SO2 are usually attributable to the sulfur contained within the fuel being combusted. Therefore the use of a low sulfur fuel can drastically reduce emissions of SO2 when compared to other potential fuels. Sweet natural gas is often cited as an alternative to other fuels due to the very low sulfur content of this fuel The reformer also burns top gas from the shaft furnace, which contains a small portion of hydrogen sulfide originating from sulfur compounds in the iron ore, as well as any sulfur that was in the natural gas converted into reformer gas. Once combusted, this hydrogen sulfide converts directly to SO2. Because sulfur is rarely introduced into a combustion reaction other than as a component of the fuel, Nucor evaluated both fuel treatment for the removal of hydrogen sulfide and other sulfur compounds, as well as flue gas desulfurization (FGD) for the removal of SO2 from the products of combustion in the flue gas.POLLUTANT NAME: Carbon Dioxide

CAS Number: 124-38-9 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Greenhouse Gasses (GHG) , InOrganic Compounds ) Emission Limit 1: 11.7900 MMBTU/TON OF DRI Emission Limit 2: Standard Emission: 11.7900 MMBTU/TON OF DRI Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) the best available technology for controlling CO2e emissions from the DRI Reformer is good combustion practices, the Acid gas separation system, and Energy integration. BACT shall be good combustion practices, which will be adhered to maintain low levels of fuel consumption by the LNB burners. Est. % Efficiency: Compliance Verified: Yes Pollutant/Compliance Notes: Due to production rate and product quality variability in any production process, production rates should be inclusive of all production at the facility, both of regular and off-spec materials. Additionally, natural gas is consumed in the DRI process as both a raw material (for the formation of reducing gas) and as a fuel (for heating to reaction temperatures). All sources of natural gas consumption at the Reformer should be included in the analysis. BACT is no more than 13 decatherms of natural gas per tonne of DRI (11.79 MM Btu/ton of DRI). Compliance with the BACT limit shall be determined on the basis of total natural gas consumption, divided by total production (including regular and off-spec DRI product) of the facility on a 12-month rolling average.



## Process/Pollutant Information

PROCESS NAME: DRI-208 - DRI Unit #2 Reformer Main Flue Stack

Process Type: 81.200 (Steel Production (excludes Steel & Iron Foundry Processes))

Primary Fuel: Iron ore and Natural Gas

Throughput: 12168.00 Billion Btu/yr

Process The Direct Reduction Iron process consists of two main components, a Reformer and the DRI reactor. Natural gas passes through special catalyst tubesProcess

Notes: The Direct Reduction Iron process consists of two main components, a Reformer and the DRI reactor. Natural gas passes through special catalyst tubes

where the natural gas dissociates into a reducing gas rich in carbon monoxide and hydrogen, which are the primary chemicals used to remove the oxygen from the iron ore. The reducing gas is fed in from the bottom of the DRI Reactor. The gas flows countercurrent to the descending iron ore pellets. At the top of the reactor, the partially spent reducing gas exits and is recompressed, enriched with natural gas, preheated, and transported back to the gas reformer. The reformer reforms the mixture back to 95% hydrogen plus carbon monoxide, which is then ready for re-use by the direct reduction furnace. Some of the reducing gas that has already passed over the iron ore in the DRI reactor (the spent reducing gas is also known as top gas) is mixed with the natural gas that is being combusted in the reformer and is also therefore combusted.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Other Test Mthd 27 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 9.9500 LB/H Emission Limit 2: 37.9000 T/YR Standard Emission: 0.0027 GRAINS/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) a high-energy wet scrubber can accommodate the large volume of gas that is generated by the DRI process, and is insensitive to variations in dust loading. Additionally, the safety aspects of using a wet system provide the most viable scenario for PM10/PM2.5 emissions control from the DRI process, by cleaning the top gas fuel stream prior to combustion. Nucor will also maintain good combustion practices at the reformer for particulate control of the natural gas combustion, but these actions are not likely to significantly contribute to the control of PM10 emissions due to the inorganic nature of topgas. Est. % Efficiency: 99.000 Compliance Verified: Yes Pollutant/Compliance Notes: The top gas contains incombustible particulate matter in the stream as it leaves the shaft furnace. This particulate would pass through the combustion zone and be emitted in the reformer flue gas if left untreated.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 10.8800 LB/H Emission Limit 2: 41.4500 T/YR Standard Emission: 0.0070 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: YCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (B) The low NOX combustion qualities of top gas fuel are inherent in the DRI reforming process. Additionally, low-NOX burners may be used with the boosted heating value of top gas mixed with natural gas, without unduly penalizing combustion efficiency. Finally, SCR may be applied to the resulting flue gas stream from combustion in the reformer. Therefore, BACT is selected to be low NOX fuel combustion, combined with low NOX burners and selective catalytic reduction. Est. % Efficiency: 90.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 8.3800 LB/H Emission Limit 2: 12.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) good combustion practices Est. % Efficiency: 98.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 62.1800 LB/H Emission Limit 2: 236.8600 T/YR Standard Emission: 0.0040 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) good combustion practices Est. % Efficiency: 98.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: Method 8 Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 3.1600 LB/H Emission Limit 2: 11.5000 T/YR Standard Emission: 0.0020 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BACT is selected to be the removal of hydrogen sulfide from the top gas fuel through acid gas scrubbing. This technology was identified as the most stringent control method of the available technologies, and has the added benefit of slightly reducing energy demand at the reformer. Nucor will install and acid gas scrubbing system for top gas prior to its use as fuel in the reformer. BACT for natural gas is to purchase natural gas containing no more than 2000 grains of Sulfur per MM scf. Est. % Efficiency: 95.000 Compliance Verified: Yes Pollutant/Compliance Notes: Method 8 - Determination of Sulfuric Acid Mist and Sulfur Dioxide Emissions from Stationary Sources. Emissions of SO2 are usually attributable to the sulfur contained within the fuel being combusted. Therefore the use of a low sulfur fuel can drastically reduce emissions of SO2 when compared to other potential fuels. Sweet natural gas is often cited as an alternative to other fuels due to the very low sulfur content of this fuel The reformer also burns top gas from the shaft furnace, which contains a small portion of hydrogen sulfide originating from sulfur compounds in the iron ore, as well as any sulfur that was in the natural gas converted into reformer gas. Once combusted, this hydrogen sulfide converts directly to SO2. Because sulfur is rarely introduced into a combustion reaction other than as a component of the fuel, Nucor evaluated both fuel treatment for the removal of hydrogen sulfide and other sulfur compounds, as well as flue gas desulfurization (FGD) for the removal of SO2 from the products of combustion in the flue gas.

POLLUTANT NAME: Carbon Dioxide

CAS Number: 124-38-9Test Method: Unspecified

Pollutant Group(s): ( Acid Gasses/Mist , Greenhouse Gasses (GHG) , InOrganic Compounds ) Emission Limit 1: 11.7900 MMBTU/TON OF DRI Emission Limit 2: Standard Emission: 11.7900 MMBTU/TON OF DRI Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) the best available technology for controlling CO2e emissions from the DRI Reformer is good combustion practices, the Acid gas separation system, and Energy integration. BACT shall be good combustion practices, which will be adhered to maintain low levels of fuel consumption by the LNB burners. Est. % Efficiency: Compliance Verified: Yes Pollutant/Compliance Notes: Due to production rate and product quality variability in any production process, production rates should be inclusive of all production at the facility, both of regular and off-spec materials. Additionally, natural gas is consumed in the DRI process as both a raw material (for the formation of reducing gas) and as a fuel (for heating to reaction temperatures). All sources of natural gas consumption at the Reformer should be included in the analysis. BACT is no more than 13 decatherms of natural gas per tonne of DRI (11.79 MM Btu/ton of DRI). Compliance with the BACT limit shall be determined on the basis of total natural gas consumption, divided by total production (including regular and off-spec DRI product) of the facility on a 12-month rolling average.



## Facility Information

RBLC ID: 

## FL-0322 (final) Date Determination Last Updated: 07/06/2011 Corporate/Company Name: SOUTHEAST RENEWABLE FUELS (SRF), LLC Permit Number: PSD-FL-412

(0510032-001-AC) Facility Name: SWEET SORGHUM-TO-ETHANOL ADVANCED BIOREFINERY Permit Date: 12/23/2010 (actual) Facility Contact: DON MARKLEY 954-492-1588 DMARKLEY@SERENEWABLE.COM FRS Number: Not Applicable Facility Description: The SRF facility will be located just East of County Road (CR) 835 at the intersection with Hill Grade Road

and approximately 13 miles south southwest of Clewiston/Lake Okeechobee in Hendry County. Hendry County is bounded by Lee County to the west, Glades County to the north, Collier County to the south, Palm Beach County to the east and Broward County to the southeast. Lake Okeechobee is located immediately northeast of Hendry County. The Big Cypress Seminole Indian Reservation is located approximately 18 miles south southeast of the site entrance. Most of Hendry County is agricultural. SIC Code: 2869

Permit Type: A: New/Greenfield Facility NAICS Code: 325193Permit URL: http://www.dep.state.fl.us/Air/emission/bioenergy/southern_renewables.htm

EPA Region: 4 COUNTRY: USA Facility County: HENDRY COUNTY Facility State: FL Facility ZIP Code: 33440 Permit Issued By: FLORIDA DEPT. OF ENVIRONMENTAL PROTECTION (Agency Name)

MR. JEFF KOERNER(Agency Contact) (850)921-9000 Jeff.Koerner@dep.state.fl.us Other Agency Contact Info: Alvaro Linero, P.E. Administrator

alvaro.linero@dep.state.fl.us Phone: 850-717-9076

David Read, Engineer david.read@dep.state.fl.us Phone: 850-717-9075

Teresa Heron, Engineer teresa.heron@dep.state.fl.us phone: 850-717-9082

Permit Notes: The applicant proposes to construct a sweet sorghum-to-ethanol advanced biorefinery with a capacity of 22.11 million gallons per year (MGPY).

The sweet sorghum will be grown on adjacent farmland. The sweet sorghum juice will be squeezed from the sorghum stalks, fermented, distilled and blended to make a range of ethanol/gasoline products. The leftover stalk fiber (bagasse) and other parts of the plant (harvest field residue) will be combusted in a cogeneration biomass boiler to make process steam and up to 30 megawatts (MW, gross) of electricity. The applicant also plans to use sweet sorghum molasses in the ethanol process when sweet sorghum is not available. Wood and yard waste will be used as a backup and supplemental fuel for the biomass boiler. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 FL Everglades NP < 100 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase:

Carbon Monoxide 212.6000 (Tons/Year) Nitrogen Oxides (NOx) 223.2000 (Tons/Year) Particulate Matter (PM) 53.1000 (Tons/Year) Sulfur Oxides (SOx) 181.3000 (Tons/Year) Volatile Organic Compounds (VOC) 87.4000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: Biomass Material Handling and Preparation

Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel:Primary Fuel:

Throughput: 522149.00 tons per year

Process Notes: The maximum amount of biomass burned in the boiler is estimated at 382,080 tons per year (TPY) of sorghum bagasse and 140,069 TPY of wood/yard

waste, for a total of 522,149 TPY. For the biomass handling system, an additional 10 percent (%) overhead is assumed for year-to-year variability in biomass fuel handled, resulting in 420,288 TPY of sorghum bagasse and 154,076 TPY of wood throughput.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) SRF shall utilize reasonable precautions for controlling fugitive PM emissions from this emission unit. These include but are not limited to: •Enclosing material drop points, transfer points, shredders and screens wherever practical; •Contouring storage piles to minimize wind erosion; •Utilizing water sprays on storage piles as needed; •Paving all main plant roads; •Watering of gravel surfaces as needed to control dust; and •Weekly sweeping and watering of paved surfaces as needed to remove dust. The permittee shall also comply with additional precautions listed in Appendix BMP- Best Management Practices of permit PSD-FL-412. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: To minimize fugitive particulate matter (PM), PM with a mean diameter of 10 micrometers (μm) or less (PM10) and PM with a mean diameter of 2.5 μm or less (PM2.5); henceforth called PM, biomass conveyors shall be enclosed. Where required to meet the 5 % opacity requirement, the permittee shall install dust collectors on the conveyor transfer and drop points. The dust collectors shall be designed to obtain an outlet PM loading of 0.005 grains per dry standard cubic foot (gr/dscf). {Permitting Note: Enclosed conveyors means that the conveyance belt for the biomass is totally enclosed from above thus preventing wind from causing fugitive dust emissions. However, the bottom of the conveyance belt shall be accessible for maintenance and repairs.}



## Process/Pollutant Information

PROCESS NAME: Cogeneration Biomass Boiler

Process Type: 12.120 (Biomass (includes wood, wood waste, bagasse, and other biomass))Primary Fuel: biomass

Throughput: 536.00 MMBTU/H

Process Notes: Capacity: The maximum heat input capacity to the boiler is 536 mmBtu/hr on a 4 hour basis and 488 mmBtu/hr on a 24-hour basis. Steam production

capability will be approximately 283,800 pounds per hour (lb/hr). The maximum heat input capacity using fossil fuels in the biomass boiler shall be physically constrained by burner design to be less than 250 mmBtu/hr so the boiler is not subject to 40 CFR 60 NSPS, Subpart Da.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/MMBTU 30-DAY ROLLING BY CEMS Emission Limit 2: 0.0800 LB/MMBTU 30-DAY ROLLING BY CEMS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) Controls: Good combustion practices (GCP) leading to the efficient combustion of biomass in the boiler, including an over-fired air (OFA) system, to minimize formation of PM, nitrogen oxides (NOX), Selective Non-Catalytic Reduction (SNCR), Selective Catalytic Reduction (SCR) or a combination of the two with urea or anhydrous ammonia (NH3) injection to destroy NOX. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: CEMS based NOX limit in pounds per million Btu heat input (lb/mmBtu) will ensure compliance with NSPS Subpart Db NOX limit of 0.20 lb NOX/mmBtu. Limit of 0.10 lb/mmBtu is for the stoker boiler option while the 0.08 lb/mmBtu limit is for the BFB boiler option. SNCR, SCR or a Combined SNCR/SCR System: The permittee shall design, install, operate, and maintain a urea or anhydrous ammonia (NH3) based SNCR, SCR or a combined SNCR/SCR system to reduce NOX emissions in the flue gas exhaust and achieve the NOX emissions standards specified in this subsection. The SNCR, SCR or a combined SNCR/SCR system shall be on line and functioning properly whenever the boiler is in operation, other than during startup conditions. During startup conditions, the SNCR, SCR or combined SNCR/SCR manufacturer’s instructions shall be followed regarding operation of the systems.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: EPA/OAR Mthd 6C Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0600 LB/MMBTU 30-DAY ROLLING BY CEMSEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Dry sorbent injection system. A wet scrubber to remove hydrogen sulfide from the biogas prior to combustion in the boiler to minimize SO2 emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The permittee shall design, install, operate, and maintain a DSIS to inject lime, trona, or sodium bicarbonate into the flue gas to control SO2 and SAM emissions. The DSIS will also help control acid gas HAP emissions. The HCl and SO2 CEMS output data expressed in lbs/hr averaged over a 24 hour period shall be reviewed by trained plant personnel on a daily and monthly basis to determine required operation of, or adjustment to the sorbent injection augmentation to ensure the HCl, HF, SAM and SO2 emission standards will be maintained. CEMS based HCl and SO2 emissions data shall be reported to the Department on a quarterly basis. The permittee shall design, install, operate and maintain a wet scrubber to remove H2S from the biogas from the bioreactors prior to combustion in the biomass boiler. The scrubber shall have a design control efficiency of at least 98% and shall be on line and operating as necessary to meet the SO2 emissions limits.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10B Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1000 LB/MMBTU 30-DAY ROLLING BY CEMS Emission Limit 2: 240.0000 T/YR 12-MONTH ROLLING BY CEMS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Good combustion practices, including an over-fired air system. If necessary, the permittee shall design and build the project to facilitate future installation of an ox-cat system to control in conjunction with good combustion practices (GCP), emissions of NOX, CO, VOC and organic HAP emissions to the permitted standards. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The 30-day limit is subject to CEMS data exclusion. The 12-month limit is not subject to CEMS data exclusion.Pollutant/Compliance Notes: The 30-day limit is subject to CEMS data exclusion. The 12-month limit is not subject to CEMS data exclusion. Ox-Cat or SCR System: If necessary, the permittee shall design and build the project to facilitate future installation of a SCR or an ox-cat system to control in conjunction with GCP emissions of NOX, CO, VOC and organic HAP emissions to the standards specified in this subsection. The permittee may install an SCR or an Ox-Cat system during project construction or after notifying the department at a future data. After notification, the permittee shall have twelve consecutive months to complete the SCR or Ox-Cat system installation.

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: EPA/OAR Mthd 8 Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0030 LB/MMBTU INITIAL AND ANNUAL STACK TEST Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: Control Method: (B) A dry sorbent injection system (DSIS) utilizing lime, trona, or sodium bicarbonate to control SO2, sulfuric acid mist (SAM) and acid gas HAP; a wet scrubber to remove hydrogen sulfide (H2S) from the biogas prior to combustion in the boiler to minimize SO2 emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The permittee shall design, install, operate, and maintain a DSIS to inject lime, trona, or sodium bicarbonate into the flue gas to control SO2 and SAM emissions. The DSIS will also help control acid gas HAP emissions. The HCl and SO2 CEMS output data expressed in lbs/hr averaged over a 24 hour period shall be reviewed by trained plant personnel on a daily and monthly basis to determine required operation of, or adjustment to the sorbent injection augmentation to ensure the HCl, HF, SAM and SO2 emission standards will be maintained. CEMS based HCl and SO2 emissions data shall be reported to the Department on a quarterly basis. The permittee shall design, install, operate and maintain a wet scrubber to remove H2S from the biogas from the bioreactors prior to combustion in the biomass boiler. The scrubber shall have a design control efficiency of at least 98% and shall be on line and operating as necessary to meet the SO2 emissions limits.

POLLUTANT NAME: Hydrochloric Acid

CAS Number: 7647-01-0 Test Method: EPA/OAR Mthd 26 Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 2.0000 T/YR 12-MONTH ROLLING MONTHLY BY CEMS Emission Limit 2:Emission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: OTHER Control Method: (B) A dry sorbent injection system (DSIS) utilizing lime, trona, or sodium bicarbonate to control SO2, sulfuric acid mist (SAM) and acid gas HAP. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Emission cap. The permittee shall design, install, operate, and maintain a DSIS to inject lime, trona, or sodium bicarbonate into the flue gas to control SO2 emissions to the limits specified in this subsection. The DSIS will also help control acid gas HAP emissions. The HCl and SO2 CEMS output data expressed in lbs/hr averaged over a 24 hour period shall be reviewed by trained plant personnel on a daily and monthly basis to determine required operation of, or adjustment to the sorbent injection augmentation to ensure the HCl, HF and SO2 emission standards will be maintained. CEMS based HCl and SO2 emissions data shall be reported to the Department on a quarterly basis.

POLLUTANT NAME: Hazardous Air Pollutants (HAP)

CAS Number: HAP Test Method: Other Other Test Method: EPA Method 29 Pollutant Group(s): ( Hazardous Air Pollutants (HAP) ) Emission Limit 1: 20.0000 T/YR 12-MONTH BLOCKS; CEMS + STACK TEST Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: OTHER Control Method: (B) Use of inherently clean fossil fuels fired in low-NOX burners (LNB) for boiler startup, shutdown and flame (bed) stabilization to minimize formation of PM, NOX, sulfur dioxide (SO2) and HAP; a dry sorbent injection system (DSIS) utilizing lime, trona, or sodium bicarbonate to control SO2, sulfuric acid mist (SAM) and acid gas HAP; a wet scrubber to remove hydrogen sulfide (H2S) from the biogas prior to combustion in the boiler to minimize SO2 emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Sum (Σ) of the following hazardous air pollutants (HAP): HCl, HF, organic HAP [C2H4O (acetaldenhyde),Pollutant/Compliance Notes: Sum (Σ) of the following hazardous air pollutants (HAP): HCl, HF, organic HAP [C2H4O (acetaldenhyde), C3H4O (acrolein), C6H6 (benzene), C24H38O4 ( Bis(2-ethylhexyl)phthalate), Cl 2 (chlorine), C6H4Cl2 (1,4-Dichlorobenzene), CH2O (formaldehyde), C6H14 (Hexane), C8H8 (styrene), C7H8 (toluene), PAH/POM (polycyclic aromatic hydrocarbon/polycyclic organic matter)] and metal HAP [Cr (chromium), Pb (lead), Mn (manganese), Ni (nickel)]. The permittee shall design, install, operate, and maintain a dry sorbent injection system (DSIS) to inject lime, trona, or sodium bicarbonate into the flue gas to control SO2 and SAM emissions. The DSIS will also help control acid gas HAP emissions. The HCl and SO2 CEMS output data expressed in lbs/hr averaged over a 24 hour period shall be reviewed by trained plant personnel on a daily and monthly basis to determine required operation of, or adjustment to the sorbent injection augmentation to ensure the HCl, HF, SAM and SO2 emission standards will be maintained. CEMS based HCl and SO2 emissions data shall be reported to the Department on a quarterly basis.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Other Other Test Method: Method 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0150 LB/MMBTU INITIAL AND ANNUAL STACK TEST Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) A wet sand separator (cyclone) and a electrostatic precipitator (ESP) or fabric filter baghouse to further control PM and VE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Filterable fraction as measured by EPA Method 5. The permittee shall install, calibrate, maintain and operate CEMS, a COMS and a diluent monitor to measure and record the emissions of SO2, NOX, CO and HCl, and opacity from the biomass boiler stack in a manner sufficient to demonstrate continuous compliance with the CEMS-based and COMS-based emission standard. Each CEMS and COMS shall be installed, calibrated and properly functioning within 60 calendar days of achieving permitted capacity as defined in Rule 62-297.310(2), F.A.C., but no later than 180 calendar days after initial startup and prior to the initial performance tests.

POLLUTANT NAME: Hydrogen Fluoride

CAS Number: 7664-39-3 Test Method: EPA/OAR Mthd 26 Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 0.4750 LB/H INITIAL AND ANNUAL TEST

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: OTHER Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Individual HCl and HF mass emission limits to provide reasonable assurance that annual emissions of all HAP from the SRF facility will be less than 25. FROM THE TECHNICAL EVALUATION HF Emissions Although the applicant estimated 0.03 TPY, the Department will set a limit of 4.0 TPY of HF on a 12-month rolling average, rolled monthly. The control method will be the same as previously discussed for SO2 (i.e. removal by fly ash, the DSIS and the ESP or a fabric filter baghouse). Compliance shall be demonstrated by a HF-CEMS. The 12-month limit equates to approximately 0.95 lb HF. The limit, the DSIS, the ESP and the HF-CEMS requirement will provide reasonable assurance that HF emissions will be less than 10 TPY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25 Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/MMBTU INITIAL AND ANNUAL TESTS Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices (GCP) leading to the efficient combustion of biomass in the boiler, including an over-fired air (OFA) system, to minimize formation of PM, nitrogen oxides (NOX), carbon monoxide (CO), volatile organic compounds (VOC) and HAP. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VETest Method: EPA/OAR Mthd 9

Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) ESP OR BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: During startups, shutdowns and malfunction the following limits apply: 20% opacity (6-minute blocks) except for one 6-minute block per hour of 27%. By meeting the VE standard the 30% opacity except that 40% opacity for no more than 2 minutes in any hour of Rule 62-296.410, F.A.C., Carbonaceous Fuel Burning Equipment will also be met.



## Process/Pollutant Information

PROCESS NAME: Cooling Water Tower

Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 0

Process Notes: The SRF facility will have three mechanical draft cooling towers. One cooling tower, the machine cooling tower, will consist of a single cell used to cool

miscellaneous machinery. A condensing set cooling tower, containing three cells, will be used to cool water coming from the power house condensing set. A third cooling tower also consisting of three cells will be used for cooling of process equipment used in ethanol production.

POLLUTANT NAME: Total Suspended Particulates

CAS Number: PM Test Method: Other Other Test Method: Records & monitoring Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Weekly Testing and Recording Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The makeup water used in the cooling towers may contain no more than 1,000 parts per million by weight (ppmw) of TDS. The makeup water in each cooling tower must be tested weekly for TDS. Records of each test must be kept on site and made available to the Compliance Authority upon request. Within 60 days of commencing operation, the permittee shall certify that the cooling towers were constructed to achieve the specified drift rate of no more than 0.001% of the circulating water flow rate. These work practice standards is established as BACT for PM10/PM2.5 emissions from the cooling towers.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Other Other Test Method: Records & monitoring Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The permittee shall control VOC emissions by promptly repairing any leaking components in accordance with the approved LDAR plan. The permittee shall collect a sample of cooling water on a weekly basis from cooling towers No. 1 and No. 3 and analyze it for VOCs to enable the early detection of leaking heat exchangers and thereby minimizing VOC emissions from the cooling towers. These work practice standards are established as BACT for VOC emissions from the cooling towers.



## Process/Pollutant Information

PROCESS Ethanol Production ProcessPROCESS

NAME: Ethanol Production Process

Process Type: 70.120 (Alcohol Fuel Production)

Primary Fuel: Throughput: 22.11 MMGAL/YR

Process Notes: The ethanol will be made from the sorghum juice and not the cellulosic fractions. The product is nevertheless considered by some to be cellulosic

ethanol. The reason is that the cellulosic/lignin fractions (bagasse and field residue) will be used in the steam and power production that support the ethanol production. The SRF process is akin to conventional sugar production practiced in the area, except that the juice is fermented and distilled to produce ethanol rather than evaporated and refined to produce sugar. It is also similar (differing only in the crop) to the production of ethanol from sugarcane, which is widely practiced in Brazil. The main process steps are: •Sorghum and other biomass receiving, handling and feeding; •Juice extraction and evaporation; •Ethanol production (including fermentation, distillation and dehydration); •Product storage, blending and loadout; •Steam and electrical production; and •Wastewater treatment.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.2000 LB/H Emission Limit 2: 42.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Wet scrubbers Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The permittee shall install three wet scrubbers to control VOC emissions from the fermentation, distillation and dehydration systems. The wet scrubbers shall have a design control efficiency of 98%. Emissions from the wet scrubbers shall discharge through a wet scrubber stack with a design height of 25 ft (minimum), a design diameter of 4.9 ft (maximum) at a design exit temperature of 70 °F and flow rate of 4,223 acfm.



## Process/Pollutant Information

PROCESS NAME: Bioreactors and Biogas FlareProcess Type: 19.390 (Other Flares)

Primary Fuel: biogas

Throughput: 27.55 MMBTU/H

Process Notes: The SRF facility will include bioreactors to treat process wastewaters and to condition the resulting biogas for use as fuel in the biomass boiler or to flare

it when it cannot be used in the boiler. During ethanol production, wastewaters from production are collected and treated in the bioreactors to reduce the chemical and biological oxygen demand prior to discharging the waters. The permittee shall construct one flare system with a continuous pilot and combustion chambers to combust the biogas from the bioreactors when the biomass boiler is not available. The flare shall be operated with a flame present at all times. The presence of a flare pilot flame shall be monitored using a thermocouple or any other equivalent device to detect the presence of a flame.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: EPA/OAR Mthd 15 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: Control Method: (B) Wet scrubber Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: Scrubber efficiency- H2S Biogas Standard and Testing: Three samples of biogas entering (inlet) and exiting (outlet) the scrubber shall be taken every calendar quarter and tested for H2S concentration in ppm. The control efficiency of the scrubber shall be determined as indicated below and must be 98% or greater based on the arithmetic average of the 3 samples from each calendar quarter. Efficiency (%)= (H2S Inlet-H2S Outlet)/(H2SInlet ))×100 Where: H2S Inlet = H2S inlet concentration in ppm H2S Outlet = H2S outlet concentration in ppm

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 22 Pollutant Group(s): Emission Limit 1: % OPACITY Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: OTHER CASE-BY-CASE Other Applicable Requirements: OTHER Control Method: (B) Flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Good combustion practices will be utilized at all times to ensure emissions from the flare system are minimized. Therefore, all operators and supervisors shall be properly trained to operate and ensure maintenance of this system in accordance with the guidelines and procedures established by the manufacturer. The training shall include good operating practices as well as methods for minimizing excess emissions. The flare pilot shall be operated with a flame present at all times. The flare shall be designed for and operated with no visible emissions (VE) except for periods not to exceed a total of 5 minutes during any 2 consecutive hours.



## Process/Pollutant Information

PROCESS NAME: Storage Tanks

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020))

Primary Fuel: ethanol

Throughput: 23.01 MMGAL/12-MO

Process Notes: The maximum throughput (process) rate in gallons per year for all the tanks is 23.01 million gallons of denatured ethanol product in any consecutive

twelve month period. Several tanks will be used during the ethanol production process to store ethanol, byproducts and intermediate products. In addition, the purified ethanol and gasoline (denaturant) will be stored in tanks and then blended, resulting in a product that contains approximately 10% or 85% ethanol and 90% or 15% gasoline by volume with the resulting blended product commonly called E10 or E85. The denatured ethanol product will have dedicated storage tanks. Anhydrous ammonia or urea will be stored in a tank for use in the SCR/SNCR system(s) for the boiler NOX control. ULSD fuel oil will be stored in a tank for use in the boiler as a startup, shutdown and bed stabilization fuel.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Other Other Test Method: Reports & Recordkeeping Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Emissions of VOC from the Blending and Storage tanks will be controlled by the proper construction of the tanks per 40 CFR 60.110b(a)(2) which requires internal floating roofs in the tanks or the equivalent. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: Pressure Relief Valves: In lieu of internal floating roofs in the Blending and Storage tanks, SRF may use pressure relief valves provided that these meet the equivalency requirements of NSPS, Subpart Kb. If SRF decides to use pressure relief valves in lieu of internal floating roofs, it must provide to the Compliance Authority 90 days before construction of the Blending and Storage VOL tanks commences, proof of the valves equivalency as defined in the NSPS.



## Process/Pollutant Information

PROCESS NAME: Truck Rack Product and Flare

Process Type: 19.390 (Other Flares) Primary Fuel: Throughput: 600.00 GAL/MIN

Process Notes: The denatured ethanol product will be loaded onto tank trucks at a maximum rate of 600 gpm. Vapors displaced from the trucks will be combusted by a

product loadout flare. The product loadout flare will have a nominal rated heat input capacity of 9.8 mmBtu/hr to control vapors displaced from the tanker trucks during the loading of the denatured ethanol product. The flare will have a design control efficiency of 99%.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 22 Pollutant Group(s): Emission Limit 1: % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Flare. One flare system with a continuous pilot and combustion chambers to destroy displaced vapors duringControl Method: (B) Flare. One flare system with a continuous pilot and combustion chambers to destroy displaced vapors during truck loadout. The flare shall be operated with a flame present at all times. The presence of a flare pilot flame shall be monitored using a thermocouple or any other equivalent device to detect the presence of a flame. Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: VE Standard: The flare shall be designed for and operated with no visible emissions (VE) except for periods not to exceed a total of 5 minutes during any 2 consecutive hours. The permittee is required to construct one flare system with a continuous pilot and combustion chambers to destroy displaced vapors during truck loadout. The flare shall be operated with a flame present at all times. The presence of a flare pilot flame shall be monitored using a thermocouple or any other equivalent device to detect the presence of a flame.



## Process/Pollutant Information

PROCESS NAME: Miscellaneous Storage Silos

Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput: 0

Process Notes: Miscellaneous Storage Silos: Silos at SRF to store lime for the wastewater treatment and DSIS systems; limestone and sand for the BFB boiler (if

used); urea (if used); and fly ash from the boiler.

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Other Other Test Method: Method 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Baghouse. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: PM emissions from each baghouse of the silos shall not exceed 0.01 gr/dscf.POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Baghouse Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VE from the silo baghouses shall not exceed 5% opacity as demonstrated by initial and annual compliance tests. A visible emission reading of 5% opacity or less may be used to establish compliance with the PM emission standard of 0.01 gr/dscf. A visible emission reading greater than 5% opacity will require the permittee to perform a PM emissions stack test within 60 days to show compliance.



## Process/Pollutant Information

PROCESS NAME: Emergency Generators, Two 2682 HP EA

Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: ULSD Throughput: 0

Process Notes: Two emergency generators, each rated at 2,000 kW, will be installed to provide backup electrical power in the event of a power outage at the SRF

facility. The engines will fire ULSD fuel oil or propane and each will be limited to 500 hours per year of operation during emergencies. Each unit will be operated no more than 100 hours per year for testing and maintenance purposes per 40 CFR 60, Subpart IIII. Each engine will be designed to meet USEPA’s emission standards listed in 40 CFR Part 60 Subpart IIII for model year 2006 or later.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Other Other Test Method: Manufacturer CertificationPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 3.5000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: Each emergency generator shall comply with the emission limit and demonstrate compliance in accordance with the procedures given in NSPS 40 CFR 60, Subpart IIII the language of which is given in Appendix IIII. Manufacturer certification can be provided to the Department in lieu of actual stack testing.

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The emergency generators shall comply with the emission limit and demonstrate compliance in accordance with the procedures given in NSPS 40 CFR 60, Subpart IIII. Manufacturer certification may be provided to the Department in lieu of actual testing. These emergency generators are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102CAS Number: 10102

Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.4000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT: 6.4 (NMHC+NOX) g/KW-hr The emergency generators shall comply with the emission limit and demonstrate compliance in accordance with the procedures given in NSPS 40 CFR 60, Subpart IIII. Manufacturer certification may be provided to the Department in lieu of actual testing. These emergency generators are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.



## Process/Pollutant Information

PROCESS NAME: Emergency Diesel Fire Pump, One 600 HP Process Type: 17.210 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: ULSD Throughput: 0

Process Notes:

POLLUTANT NAME: Nitrogen Dioxide (NO2)

CAS Number: 10102-44-0 Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) ) Emission Limit 1: 3.0000 G/HP-H Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT: 3.0 (NMHC+NOX) g/KW-hr The fire pumps shall comply with the emission limit and demonstrate compliance in accordance with the procedures given in NSPS 40 CFR 60, Subpart IIII. Manufacturer certification may be provided to the Department in lieu of actual testing. The fire pumps are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.6000 G/HP-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The fire pumps shall comply with the emission limit and demonstrate compliance in accordance with the procedures given in NSPS 40 CFR 60, Subpart IIII. Manufacturer certification may be provided to the Department in lieu of actual testing. The fire pumps are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.1500 G/HP-H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The fire pumps shall comply with the emission limit and demonstrate compliance in accordance with the procedures given in NSPS 40 CFR 60, Subpart IIII. Manufacturer certification may be provided to the Department in lieu of actual testing. The fire pumps are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.



## Process/Pollutant Information

PROCESS NAME: Fugitive VOC Emission Leaks (facility-wide)

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput: 0

Process Notes: The fugitive VOC emissions from equipment leaks involved in the ethanol production process and associated processes at the SRF facility. Total

fugitive VOC emissions from equipment leaks at the SRF facility were estimated to be 6.52 TPY. To minimize VOC fugitive emissions, SRF shall implement a monthly leak detection and repair (LDAR) program. The plan to implement the LDAR program shall be approved by the Compliance Authority in accordance with New Source Performance Standard (NSPS) 40 CFR Part 60, Subpart VVa.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Other Other Test Method: 40 CFR Subpart VVa requirements Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.5200 TON/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) The permittee shall demonstrate compliance with the requirements of §§60.482–1a through 60.482–10a or §60.480a(e) for all equipment subject to NSPS Subpart VVa within 180 days of initial startup of the SRF. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: The permittee shall follow the recordkeeping requirements specified in §§60.486a to show compliance with NSPS Subpart VVa and submit the records to the Compliance Authority 180 days after the initial startup of the SRF and annually thereafter. Leak Detection and Repair (LDAR) Program: SRF is subject to NSPS 40 CFR 60, Subpart VVa - VOC Equipment Leaks in the Synthetic Chemical Manufacturing Industry (SOCMI), for projects that commence construction or modifications after November 7, 2006. NSPS Subpart VVa requires a LDAR program. SRF must demonstrate compliance with Subpart VVa, including the LDAR program, no later than 180 days after SRF becomes operational.



## Facility Information

RBLC ID: 

## LA-0244 (final) Date Determination Last Updated: 07/06/2011 Corporate/Company Name: SASOL NORTH AMERICA, INC. Permit Number: PSD-LA-291(M3) Facility Name: LAKE CHARLES CHEMICAL COMPLEX - LAB UNIT Permit Date: 11/29/2010 (actual) Facility Contact: MAGGIE PAGELS 337-494-5769 MARGARET.PAGELS@US.SASOL.COM FRS Number: 110017418061 Facility Description: Chemical Production Unit for Linear Alkyl Benzene (LAB)production. SIC Code: 2869 Permit Type: C: Modify process at existing facility NAICS Code: 325110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: CALCASIEU Facility State: LA Facility ZIP Code: 70669 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: Permit Writer: Dan Nguyen (225) 219-3395 Permit Notes: Modification to an existing PSD Permit (PSD-LA-291(M2), dated October 18, 1988) to increase operating time of the heater. Emissions will not be increased above the permitted limits. Existing BACT will not be revised.



## Process/Pollutant InformationPROCESS NAME: EQT0026 - LAB Unit Flare LF-1

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Natural Gas Throughput: 0

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 10.2300 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Steam Assisted Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H HOURLY MAXIMUM Emission Limit 2: % OPACITY Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Steam assisted Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: BACT was determined in 1983



## Process/Pollutant Information

PROCESS NAME: EQT0027 - PACOL CHARGE HEATER H-201 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Natural Gas Throughput: 87.30 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 7.1500 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Low NOX Burners Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8600 LB/H HOURLY MAXIMUM Emission Limit 2: % OPACITY Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983



## Process/Pollutant Information

PROCESS NAME: EQT0028 - PACOL STARTUP HEATER H-202 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: natural gas Throughput: 21.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2100 LB/H HOURLY MAXIMUM Emission Limit 2: % OPACITY Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) No additional Control Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.7100 LB/H HOURLY MAXIMUMEmission Limit 2: % OPACITY

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) low nox burners Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983



## Process/Pollutant Information

PROCESS NAME: EQT0029 - Hot Oil Heater H-601 Process Type: 12.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: natural gas Throughput: 170.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.7100 LB/H HOURLY MAXIMUM Emission Limit 2: % OPACITY Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) No additional control Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 19.6900 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) low nox burners Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT was determined in 1983



## Facility Information

RBLC ID: 

## TX-0575 (final) Date Determination Last Updated: 08/03/2011 Corporate/Company Name: SABINA PETROCHEMICALS LLC Permit Number: 41945

Facility Name: SABINA PETROCHEMICALS LLC Permit Date: 08/20/2010 (actual) Facility Contact: 4099605000 CHRISTOPHER.WITTE@BASF.COM FRS Number: 110006134691 Facility Description: C4 OLEFINS COMPLEX BRIEF PLANT DESCRIPTION/NARRATIVE (FOR EXAMPLE - CHEMICAL

PLANT, STEEL MILL, PAINT MANUFACTURING, ETC.): C4 OLEFINS COMPLEX BRIEF EMISSION SOURCE(S) DESCRIPTION (FOR EXAMPLE - BOILER, PAINT SPRAY BOOTH, FURNACE, ETC.): STORM WATER TANK, COOLING TOWER, FUGITIVES, TANK TRUCK LOADING , AND ABOILER, TYPE(S) OF FUEL USED AT THIS FACILITY: DESCRIPTION OF THE POLLUTION ABATEMENT STRATEGY (FOR EXAMPLE - FABRIC FILTER, ESP, CARBON ADSORBERS, POWDER COATINGS, ETC.): HIGH AND LOW-PRESSURE FLARES, AND AN AMMONIA SCRUBBER FACILITY NOTES: THE FACILITY INCLUDES A BUTADIENE UNIT WITH A MAXIMUM CAPACITY OF 1 BILLION POUNDS PER YEAR OF BUTADIENE, AN ALKYLATE (MIXTURE OF OCTANES) UNIT (REFERRED TO AS INALK UNIT) WITH A MAXIMUM CAPACITY OF 1 BILLION POUNDS PER YEAR OF ALKYLATE, AND ANCILLARY SUPPORT EQUIPMENT. SIC Code: 2869

Permit Type: A: New/Greenfield Facility NAICS Code: 325199 Permit URL:EPA Region: 6 COUNTRY: USA

Facility County: JEFFERSON Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: AGENCY CONTACT: DANIEL A. SMOTHERS

TELEPHONE NUMBER: (512) 239-1664 FAX: E-MAIL ADDRESS:DSMOTHER@TCEQ.STATE.TX.US ADDRESS: OFFICE OF PERMITTING AND REGISTRATION AIR PERMITS DIVISION, MC-163, P.O. BOX 13087 CITY: AUSTIN STATE: TEXAS ZIP CODE: 78711-3087 Permit Notes: BRIEF PLANT DESCRIPTION/NARRATIVE (FOR EXAMPLE - CHEMICAL PLANT, STEEL MILL, PAINT MANUFACTURING, ETC.): C4

OLEFINS COMPLEX BRIEF EMISSION SOURCE(S) DESCRIPTION (FOR EXAMPLE - BOILER, PAINT SPRAY BOOTH, FURNACE, ETC.): STORM WATER TANK, COOLING TOWER, FUGITIVES, TANK TRUCK LOADING , AND ABOILER, TYPE(S) OF FUEL USED AT THIS FACILITY: DESCRIPTION OF THE POLLUTION ABATEMENT STRATEGY (FOR EXAMPLE - FABRIC FILTER, ESP, CARBON ADSORBERS, POWDER COATINGS, ETC.): HIGH AND LOW-PRESSURE FLARES, AND AN AMMONIA SCRUBBER FACILITY NOTES: THE FACILITY INCLUDES A BUTADIENE UNIT WITH A MAXIMUM CAPACITY OF 1 BILLION POUNDS PER YEAR OF BUTADIENE, AN ALKYLATE (MIXTURE OF OCTANES) UNIT (REFERRED TO AS INALK UNIT) WITH A MAXIMUM CAPACITY OF 1 BILLION POUNDS PER YEAR OF ALKYLATE, AND ANCILLARY SUPPORT EQUIPMENT. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 AL Sipsey > 250 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase:

Nitrogen Oxides (NOx) 9.0700 (Tons/Year) Volatile Organic Compounds (VOC) 10.3300 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: HIGH AND LOW PRESSURE FLARES

Process Type: 19.310 (Chemical Plant Flares)

Primary Fuel: NATURAL GAS

Throughput: 1600.00 T/YR

Process THE NOX EMISSIONS INCREASES FROM THE FLARES ARE DUE TO THE COMBUSTION OF NATURAL GAS USED AS SWEEP GAS INProcess

Notes: THE NOX EMISSIONS INCREASES FROM THE FLARES ARE DUE TO THE COMBUSTION OF NATURAL GAS USED AS SWEEP GAS IN

THE FLARE HEADER SYSTEM. THE NATURAL GAS ALSO HELPS TO MAINTAIN THE MINIMUM HEATING VALUE NECESSARY TO ENSURE DESTRUCTION OF THE VOCS IN THE VENT STREAMS. THE NATURAL GAS FLOW WAS NOT COMPLETELY ACCOUNTED FOR IN THE ORIGINAL PERMIT REPRESENTATIONS AND IS BEING ADDED TO THE PERMIT AT THIS TIME. THERE IS NO APPLICABLE POST-COMBUSTION TECHNOLOGY TO REDUCE NOX EMISSIONS FROM FLARES. EMISSIONS ARE MINIMIZED BY PROPER OPERATION OF THE FLARES, INCLUDING COMPLIANCE WITH THE APPLICABLE PROVISIONS IN SECTION 60.18 OF SUBPART A OF THE FEDERAL NEW SOURCE PERFORMANCE STANDARDS (NSPS) IN 40 CFR PART 60 AND THE PROVISIONS OF SPECIAL CONDITION 13 OF PERMIT 41945. SPECIAL CONDITION 13 REQUIRES THE FLARES TO BE OPERATED WITH A FLAME PRESENT AT ALL TIMES, MONITORING TO ENSURE THE PRESENCE OF A CONSTANT PILOT FLAME, NO VISIBLE EMISSIONS, AND CONTINUOUS FLOW RATE AND BTU CONTENT MONITORING OF THE FLARED STREAMS. THESE OPERATING REQUIREMENTS WERE DETERMINED TO SATISFY LAER IN THE ORIGINAL PERMITTING OF THE FLARES, AND THERE HAVE BEEN NO CHANGES IN FLARE TECHNOLOGY SINCE THAT TIME THAT WOULD FURTHER IMPROVE FLARE OPERATION. THE FLARES WILL CONTINUE TO OPERATE IN COMPLIANCE WITH THESE CONDITIONS; THEREFORE, THE LAER REQUIREMENT WILL BE MET.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 9.0700 T/YR ANNUAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3200 T/YR ANNUAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: NCase-by-Case Basis: LAER

Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: 98.000 Compliance Verified: Yes Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ALKFUG, BDEFUG, AND UTILFUG

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.))

Primary Fuel: Throughput: 0

Process Notes: THE INCREASE IN VOC EMISSIONS FROM THE PROCESS FUGITIVE EPNS (ALKFUG, BDEFUG, AND UTILFUG) ARE THE RESULT OF A

CORRECTION TO THE UNDERESTIMATED COMPONENT COUNTS. THE COMPONENTS ARE CURRENTLY INCLUDED IN SABINA'S LEAK DETECTION AND REPAIR (LDAR) DATABASE AND ARE MONITORED IN ACCORDANCE WITH THE SAME 28LAER LDAR PROGRAM REQUIRED FOR THE COMPONENTS THAT ARE CURRENTLY AUTHORIZED BY THE PERMIT. AS THE NAME IMPLIES, 28LAER WAS SPECIFICALLY DEVELOPED BY TCEQ TO SATISFY THE LAER REQUIREMENT FOR FUGITIVE EMISSIONS THAT ARE SUBJECT TO NNSR. SPECIAL CONDITION 9 OF THE DRAFT CONDITIONS FOR THIS PERMIT AMENDMENT CONTAINS TCEQ'S MOST CURRENT 28LAER LDAR LANGUAGE; THEREFORE, IT REPRESENTS CURRENT LAER REQUIREMENTS. IN ADDITION TO THE STANDARD 28LAER REQUIREMENT, SPECIAL CONDITION 10 OF THE PERMIT REQUIRES FLANGES AND CONNECTORS IN GAS/VAPOR AND LIGHT LIQUID SERVICE TO BE MONITORED QUARTERLY IN ACCORDANCE WITH THE SAME REQUIREMENTS SPECIFIED IN SPECIAL CONDITION 9 FOR VALVES. BECAUSE THE ADDITIONAL COMPONENTS ARE ALSO MONITORED IN ACCORDANCE WITH THESE SAME REQUIREMENTS AND WILL CONTINUE TO BE AS SPECIFIED IN THE PERMIT, THE LAER REQUIREMENT IS MET.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.0100 T/YR ANNUAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: LAER

Other Applicable Requirements: Control Method: (P) THE FACILITY UTILIZES THE LOWEST ACHEIVABLE EMISSION RATE (LAER) LDAR (LEAK DETECTION AND REPAIR) PROGRAM. Est. % Efficiency: 98.000 Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STORMWATER TANK

Process Type: 64.006 (Wastewater Collection & Treatment)

Primary Fuel: N/A

Throughput: 15.00 MGAL/YR

Process Notes: THERE IS A SMALL INCREASE, 0.31 TPY, IN THE ALLOWABLE VOC EMISSIONS FROM THE STORMWATER TANK (TK-9804) DUE TO

A CHANGE IN THE EMISSION CALCULATION METHOD THAT IS MORE APPLICABLE TO THE TANK AND ITS CONTENTS THAN THE CALCULATION ORIGINALLY USED FOR THE TANK. THE TANK IS EQUIPPED WITH AN EXTERNAL FLOATING ROOF WITH A MECHANICAL PRIMARY SEAL AND A RIM-MOUNTED SECONDARY SEAL TO CONTROL VOC EMISSIONS. THIS LEVEL OF EMISSIONS CONTROL IS THE MOST STRINGENT CONTROL KNOWN TO BE USED FOR STORAGE OF STORMWATER CONTAINING TRACE AMOUNTS OF VOC AND IS THEREFORE CONSIDERED TO BE LAER

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3100 T/YR ANNUAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (A) EXTERNAL FLOATING ROOF Est. % Efficiency: 88.000Compliance Verified: No

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER

Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 228.00 SCF/H

Process Notes: THE BOILER, EPN BLR, HAS SCR WITH LOW NOX BURNERS, A NOX LONG-TERM EMISSION FACTOR OF 0.007 LB NOX /MMBTU

AND A SHORT-TERM EMISSION FACTOR OF 0.020 LB NOX /MMBTU TO ACCOMMODATE FOR HOT STANDBY. BECAUSE OF THE LOW ANNUAL EMISSION FACTOR, THIS WAS ACCEPTED AS LAER.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/MMBTU HOURLY Emission Limit 2: 0.0070 LB/MMBTU ANNUAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS AND SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions)Primary Fuel: N/A

Throughput: 73000.00 GPM

Process Notes: THE COOLING TOWER, EPN CT, HAS A NON-CONTACT DESIGN, UTILIZES MONTHLY MONITORING OF VOC IN WATER PER

APPENDIX P OR APPROVED EQUIVALENT AND IDENTIFIED LEAKS ARE REPAIRED AS SOON AS POSSIBLE, BUT BEFORE NEXT SCHEDULED SHUTDOWN.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 13.4300 T/YR ANNUAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE COOLING TOWER, EPN CT, HAS A NON-CONTACT DESIGN, UTILIZES MONTHLY MONITORING OF VOC IN WATER PER APPENDIX P OR APPROVED EQUIVALENT AND IDENTIFIED LEAKS ARE REPAIRED AS SOON AS POSSIBLE, BUT BEFORE NEXT SCHEDULED SHUTDOWN. Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0574 (final) Date Determination Last Updated: 09/14/2010 Corporate/Company Name: DIAMOND SHAMROCK REFINING COMPANY L.P. Permit Number: PSDTX1017M1

Facility Name: VALERO THREE RIVERS REFINERY Permit Date: 08/19/2010 (actual) Facility Contact: 3617868286 JON.KIGGANS@VALERO.COM FRS Number: UNKNOWN Facility Description: PETROLEUM REFINERY THIS PERMIT AMENDMENT AUTHORIZES EMISSIONS FROM MAINTENANCE, STARTUP, AND SHUTDOWN (MSS) ACTIVITIES AT THE VALERO THREE RIVERS REFINERY. SIC Code: 2911

Permit Type: A: New/Greenfield Facility NAICS Code: 324110Permit URL:

EPA Region: 6 COUNTRY: USA Facility County: LIVE OAK Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: THIS PERMIT AMENDMENT AUTHORIZES EMISSIONS FROM MAINTENANCE, STARTUP, AND SHUTDOWN (MSS) ACTIVITIES AT THE VALERO THREE RIVERS REFINERY. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 168.5000 (Tons/Year) Sulfur Oxides (SOx) 237.2400 (Tons/Year) Volatile Organic Compounds (VOC) 260.8000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: FLARE MSS Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: Throughput: 0

Process Notes: EMISSIONS FROM MSS ACTIVITIES THAT ARE CONTROLLED BY THE PLANT FLARES.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) BEST PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: USE BEST PRACTICES TO RECOVER FLUIDS TO PROCESS AS MUCH AS POSSIBLE BEFORE VENTING RESIDUALS TO FLARE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) BEST PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: USE BEST PRACTICES TO RECOVER FLUIDS TO PROCESS AS MUCH AS POSSIBLE BEFORE VENTING RESIDUALS TO FLARE.

POLLUTANT NAME: Sulfur Oxides (SOx)

CAS Number: 7446 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) BEST PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: USE BEST PRACTICES TO RECOVER FLUIDS TO PROCESS AS MUCH AS POSSIBLE BEFORE VENTING RESIDUALS TO FLARE. MINIMIZE AMOUNT OF SULFUR COMPOUNDS VENTED TO FLARE.

## Process/Pollutant Information

PROCESS NAME: MSS FOR PROCESS EQUIPMENT AND STORAGE TANKS

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 0

Process Notes: CLEARING PROCESS EQUIPMENT AND STORAGE TANKS IN PREPARATION FOR MAINTENANCE, STARTUP, AND SHUTDOWN

ACTIVITIES.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) VENT TO CONTROL UNTIL VOC CONCENTRATION < 10,000 PPMV Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: IF VOC VAPOR PRESSURE OF MATERIAL CONTAINED IN VESSEL OR STORAGE TANK IS 0.5 PSIA OR GREATER, ROUTE TO CONTROL SUCH AS FLARE, THERMAL OXIDIZER, INTERNAL COMBUSTION ENGINE, CARBON ADSORBER. VENT TO ATMOSPHERE AFTER VOC CONVENTRATION IS MEASURED TO BE < 10,000 PPMV OR < 10% OF LOWER EXPLOSIVE LIMIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) BEST PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARISE FROM CONTROL OF VOC BY COMBUSTION PROCESSES SUCH AS THERMAL OXIDIZERS OR INTERNAL COMBUSTION ENGINES. EMISSIONS FROM CONTROL BY FLARES ARE INCLUDED UNDER FLARE PROCESS. EMISSIONS ARE MINIMIZED BY USING BEST PRACTICES TO MINIMIZE AMOUNT OF VOC VENTED TO CONTROLS IN PREPARATION FOR MSS ACTIVITIES.

POLLUTANT NAME: Sulfur Oxides (SOx)

CAS Number: 7446 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) BEST PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARISE FROM CONTROL OF VOC BY COMBUSTION PROCESSES SUCH AS THERMAL OXIDIZERS OR INTERNAL COMBUSTION ENGINES. EMISSIONS FROM CONTROL BY FLARES ARE INCLUDED UNDER FLARE PROCESS. EMISSIONS ARE MINIMIZED BY USING BEST PRACTICES TO MINIMIZE AMOUNT OF VOC AND SULFUR COMPOUNDS VENTED TO CONTROLS IN PREPARATION FOR MSS ACTIVITIES.



## Facility Information

RBLC ID: 

## FL-0321 (final) Date Determination Last Updated: 12/03/2010Corporate/Company

Name: WASTE MANAGEMENT Permit Number: PPSD-FL-382

(0930104-014-AC) Facility Name: OKEECHOBEE LANDFILL Permit Date: 04/19/2010 (actual) Facility Contact: TIM HAWKINS 954-984-2000 THAWKINS@WM.COM FRS Number: 1209300104 Facility Description: The landfill is operated by Okeechobee Landfill, Inc. (OLI), a Waste Management Company. The OL

comprises the Berman Road Landfill and the authorized development known as the Clay Farms Landfill. The total OL comprises 847 acres within 4150 acres owned by the applicant. The property boundary actually extends south to SR 70 and east into neighboring St. Lucie County. The nearest Class I area is the large Everglades National Park (ENP) that straddles Monroe, Collier and Miami-Dade Counties. The nearest boundary point in the ENP is located approximately 169 km south of the southernmost property boundary of the facility. Biscayne Bay National Park, a Class II National Park, is located approximately 193 km from the facility towards the southwest. Big Cypress National Preserve is located approximately 121 km from the facility. SIC Code: 4953

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 221119 Permit URL: EPA Region: 4 COUNTRY: USA Facility County: OKEECHOBEE COUNTY Facility State: FL Facility ZIP Code: 34972 Permit Issued By: FLORIDA DEPT. OF ENVIRONMENTAL PROTECTION (Agency Name)

MR. JEFF KOERNER(Agency Contact) (850)921-9000 Jeff.Koerner@dep.state.fl.us Other Agency Contact Info: Alvaro Linero

alvaro.linero@dep.state.fl.us Phone 850-921-9523

Teresa Heron teresa.heron@dep.state.fl.us Phone 850-921-9529 Permit Notes: Permit to construct a LFG to energy (LFGTE) plant at the existing site with an ultimate capacity of 67.5 megawatts (MW). Process: The OL receives

waste from central and southern Florida. Wastes including municipal solid waste (MSW), construction and demolition (C&D) material and special wastes are received over scales at the entrance to the landfill. Trucks are directed to the operating face of the above-grade landfill for the actual disposal. Waste is spread in layers, compacted and covered with soil. The compacted layers compose the landfill building blocks called cells. A cell is a constructed lined area where waste is placed. Synthetic liners of high density polyethylene contain liquid (leachate) produced from waste decomposition. Waste is covered at the end of each day with soil or an approved alternative daily cover such as temporary plastic sheets. When the final permitted elevations and grades of the waste are reached, the landfill is capped. The cap systems, similar to the cell liners, are constructed of a low-permeable soil or a synthetic liner. The waste flow is variable depending on contracts, general economic activity, hurricane debris generation, etc. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 FL Everglades NP 100km - 50km Facility-wide Pollutant Name: Facility-wide Emissions Increase:Emissions: Carbon Monoxide 913.0000 (Tons/Year) Nitrogen Oxides (NOx) 343.0000 (Tons/Year) Particulate Matter (PM) 40.0000 (Tons/Year) Sulfur Oxides (SOx) 239.0000 (Tons/Year) Volatile Organic Compounds (VOC) 4.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: Okeechobee landfill

Process Type: 21.400 (Municipal Waste Combustion) Primary Fuel: landfill gas Throughput: 13500.00 SCFM

Process Notes: The permitted capacity of the landfill gas collection system (LFGCS) is 13,500 scfm on a 30 day rolling average basis. The maximum permitted

capacity of the gas desulfurizacion plant (GDP) is 32,500 scfm of LFG on a 30 day rolling average basis.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Other Other Test Method: CMS Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 200.0000 PPM Emission Limit 2: 12.0000 GR S/100 SCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP Control Method: (A) A gas desulfurization plant (GDP) to control all collected LFG to a concentration less than or equal to 200 ppmv H2S (12 gr S/100 SCF) prior to combustion whether or not the permittee builds a LFGTE plant. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The permittee shall install a H2S CEMS to continuously monitor and record the concentration of H2S in the LFG after it is processed by the GDP and before it is combusted in the CTG or the backup flares. The CEMS shall be calibrated, maintained, and operated according to the manufacturer specifications. The LFG may be monitored at only one location if monitoring at this location accurately represents the concentration of H2S in the LFG being combusted. The applicant shall notify the Compliance Authority of the CEMS location(s) 90 days before installation of the CEMS. Within 30 days of initial startup of H2S CEMS (or startup of any new or replacementH2S CEMS), the performance evaluations for this H2S CEMS shall be done using Performance Specification 7. EPA Methods 11, 15, 15A, or 16 shall be used for conducting the relative accuracy evaluations.



## Process/Pollutant Information

PROCESS NAME: Flares

Process Type: 19.300 (Flares) Primary Fuel: landfill gas Throughput: 0

Process Notes: One 1,500 scfm open flare and four 3,000 scfm open flares with a continuous pilots and combustion chambers to combust LFG as necessary to backup

the CTG that will combust the LFG to generate electrical power. The presence of flare pilot flames shall be monitored using thermocouples or any other equivalent device to detect the presence of a flame.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 22 Pollutant Group(s): Emission Limit 1: SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The flares shall be designed for and operated with no visible emissions (VE) as determined by the methods specified in paragraph 40 CFR 60.18 (f), except for period not to exceed a total of 5 minutes during any 2 consecutive hours.



## Process/Pollutant Information

PROCESS NAME: 15 MW Solar Titan 130Process Type: 16.120 (Landfill/Digester/Bio-Gas)

Primary Fuel: landfill gas Throughput: 150.00 MMBTU/H

Process Notes: The maximum heat input rate of the CTG is 150 million British thermal units per hour (mmBtu/hr) on a 4 hour averaging time basis and based on the

lower heating value (LHV) of the LFG. This rate is based on a compressor inlet temperature of 59 °F, International Organization for Standardization (ISO) conditions of the LFG. The heat input rate will vary depending upon CTG characteristics, ambient conditions, alternate methods of operation and evaporative cooling (if installed).

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 100.0000 PPMVD @ 15% O2 Emission Limit 2: 78.4000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 72.0000 PPMVD @ 15% O2 4-HR BLOCK AVERAGE Emission Limit 2: 46.8400 LB/H 4-HR BLOCK AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: The initial and annual EPA Method 7E or Method 20 tests associated with demonstration of compliance with 40 CFR 60, Subpart KKKK or certification of the CEMS instruments shall also be used to demonstrate compliance with the individual standards during the time of those tests. NOX mass emission rates are defined as oxides of nitrogen expressed as nitrogen dioxide (NO2). Continuous compliance with the 4-hour rolling average NOX standards shall be demonstrated based on data collected by the required CEMS. CEMS monitoring compliance shall in accordance with the 40 CFR 60, NSPS, Subpart KKKK for NOX.

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Other Other Test Method: Fuel Specification Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.8000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Efficient combustion will minimize PM/PM10 emissions, while SO2 and NOx control will minimize PM2.5 emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: After the initial compliance test the sulfur fuel specification combined with the efficient combustion design and operation of the CTG shall indicate compliance. Compliance with the fuel specifications and visible emissions standards shall serve as indicators of good combustion. Compliance with the fuel specifications (200 ppmv H2S) shall be demonstrated by keeping records of the fuel sulfur content. Compliance with the visible emissions standard shall be demonstrated by conducting tests in accordance with EPA Method 9.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: Fuel Specifications Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTES Emission Limit 2: Standard Emission:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) To install and operate a gas desulfurization plant (GDP) such that all collected LFG shall be treated to a concentration less than or equal to 200 ppmv H2S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The LFG H2S specification effectively limits the potential emissions of SAM and SO2 from the CTG. Compliance with the LFG H2S specification of 200 ppmv shall be determined by H2S CEMS. Such representative LFG CEMS data will insure that the sulfur content of the LFG (a type of biogas) does not exceed (0.15 lb SO2/mmBtu) heat input limitation of 40 CFR 60, Subpart KKKK.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 3.5 MW Solar Centaur

Process Type: 16.120 (Landfill/Digester/Bio-Gas) Primary Fuel: landfill gas Throughput: 45.00 MMBTU/HThroughput: 45.00 MMBTU/H

Process Notes: The design heat input rate of each CTG is 45 mmBtu/hr (4 hour averaging time basis) based on lower heating value (LHV) of the LFG. This rate is

based on a compressor inlet temperature of 59 °F, International Organization for Standardization (ISO) conditions. The heat input rate will vary depending upon combustion turbine characteristics, ambient conditions, alternate methods of operation and evaporative cooling.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 250.0000 PPMVD Emission Limit 2: 28.6000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 42.0000 PPMVD 4-HR BLOCK AVERAGE Emission Limit 2: 7.9000 LB/H 4-HR BLOCK AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The initial and annual EPA Method 7E or Method 20 tests associated with demonstration of compliance with 40Pollutant/Compliance Notes: The initial and annual EPA Method 7E or Method 20 tests associated with demonstration of compliance with 40 CFR 60, Subpart KKKK or certification of the CEMS instruments shall also be used to demonstrate compliance with the individual standards during the time of those tests. NOX mass emission rates are defined as oxides of nitrogen expressed as nitrogen dioxide (NO2). Continuous compliance with the 4 hour average NOX standards shall be demonstrated based on data collected by the required CEMS.

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Other Other Test Method: Fuel Specification Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.8000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Efficient combustion will minimize PM/PM10 emissions, while SO2 and NOx control will minimize PM2.5 emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: After the initial compliance test the sulfur fuel specification combined with the efficient combustion design and operation of each CTG shall indicate compliance. Compliance with the fuel specifications and visible emissions standards shall serve as indicators of good combustion. Compliance with the fuel specifications shall be demonstrated by keeping records of the fuel sulfur content. Compliance with the visible emissions standard shall be demonstrated by conducting tests in accordance with EPA Method 9.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: Fuel Specifications Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (A) To install and operate a gas desulfurizationplant (GDP) such that all collected landfill gas (LFG) shall be treated to a concentration less than or equal to 200 ppmv H2S . Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Landfill gas (LFG) H2S specification effectively limits the potential emissions of SAM and SO2 from each CTG. Compliance with the LFG H2S specification of 200 ppmv shall be determined by H2S CEMS. Such representative LFG CEMS data will insure that the sulfur content of the LFG (a type of biogas) does not exceed (0.15 lb SO2/mmBtu) heat input limitation of 40 CFR 60, Subpart KKKK.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 10.0000 PPMVD Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: After the initial compliance test the sulfur fuel specification combined with the efficient combustion design and operation of each CTG shall indicate compliance. Compliance with the fuel specifications and visible emissions standards shall serve as indicators of good combustion. Compliance with the fuel specifications shall be demonstrated by keeping records of the fuel sulfur content. Compliance with the visible emissions standard shall be demonstrated by conducting tests in accordance with EPA Method 9.



## Facility Information

RBLC ID: 

## AL-0249 (final) Date Determination Last Updated: 08/17/2010 Corporate/Company Name: EVONIK DEGUSSA CORPORATION Permit Number: X001, X008, X043, X125 Facility Name: EVONIK DEGUSSA CORPORATION Permit Date: 01/07/2010 (actual)Facility Contact: 2514434763 BILL.KLUTZ@EVONIK.COM FRS Number: 110017408296

Facility Description: CHEMICAL MANUFACTURING FACILITY SIC Code: 2869 Permit Type: A: New/Greenfield Facility NAICS Code: 11 Permit URL: EPA Region: 4 COUNTRY: USA Facility County: MOBILE Facility State: AL Facility ZIP Code: Permit Issued By: ALABAMA DEPT OF ENVIRONMENTAL MGMT (Agency Name) MR. ANTHONY SMILEY(Agency Contact) (334) 271-7714 ASMILEYSR@ADEM.STATE.AL.US Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Nitrogen Oxides (NOx) 463.1000 (Tons/Year) Particulate Matter (PM) 21.9000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: METHIONINE PRODUCTION UNIT - THERMAL OXIDIZER Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: NATURAL GAS Throughput: 62.40 MMBTU/H

Process Notes: EXPANDING METHIONINE PRODUCTION

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICESEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4900 LB/H Emission Limit 2: 0.0260 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4900 LB/H Emission Limit 2: 0.0260 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 16.0700 LB/H Emission Limit 2: 360.0000 PPM @ 3% O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER - SNCR Est. % Efficiency: 64.800 Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4900 LB/H Emission Limit 2: 0.0260 G/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHIONINE PRODUCTION UNIT - CEILCOTE SCRUBBER A Process Type: 64.999 (Other SOCMI Processes)Primary Fuel:

Throughput: 0

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHIONINE PRODUCTION UNIT - CEILCOTE SCRUBBER B Process Type: 64.999 (Other SOCMI Processes)Primary Fuel:

Throughput: 0

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHIONINE PRODUCTION UNIT - CEILCOTE SCRUBBER C Process Type: 64.999 (Other SOCMI Processes)Primary Fuel:

Throughput: 0

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHIONINE PRODUCTION UNIT - CEILCOTE SCRUBBER D Process Type: 64.999 (Other SOCMI Processes)Primary Fuel:

Throughput: 0

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHIONINE PRODUCTION UNIT - CEILCOTE SCRUBBER E Process Type: 64.999 (Other SOCMI Processes)Primary Fuel:

Throughput: 0

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 0.0023 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PACKED BED SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: EXISTING HCN PRODUCTION UNIT - WASTE HEAT BOILER Process Type: 12.300 (Gaseous Fuel & Gaseous Fuel Mixtures (>100 million BTU/H & ¿250 million Btu/H))Primary Fuel: NATURAL GAS

Throughput: 212.60 MMBTU/H

Process Notes: HCN PRODUCTION UNIT WASTE HEAT BOILER

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 59.1000 LB/H Emission Limit 2: 243.0000 PPM @ 3% 02 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SNCR Est. % Efficiency: 60.000 Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5800 LB/H Emission Limit 2: 0.0050 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5800 LB/H Emission Limit 2: 0.0050 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5800 LB/H Emission Limit 2: 0.0050 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s):Emission Limit 1: 10.0000 % OPACITY

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HCN PRODUCTION UNIT - FLARE A1 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput: 0

Process Notes: HCN PRODUCTION UNIT EMERGENCY FLARE - A1

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 14.2900 LB/H ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.0700 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 63.11(B) SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: HCN PRODUCTION UNIT - FLARE A2 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput: 0

Process Notes: HCN PRODUCTION UNIT EMERGENCY FLARE A2POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 14.2900 LB/H ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.0700 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 63.11(B) SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: MACT Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: HCN PRODUCTION UNIT - TANK FARM FLARE - A5 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput: 0

Process Notes: HCN PRODUCTION UNIT TANK FARM FLARE A5

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.7900 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.0160 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0160 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0160 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 63.11(B) SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: AMSUL PRODUCTION UNIT - DUST SCRUBBER - A10 Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput: 0

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.2400 LB/H

Emission Limit 2: 0.0145 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: 85.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2400 LB/H Emission Limit 2: 0.0145 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: 85.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2400 LB/H Emission Limit 2: 0.0145 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: 85.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACROLEIN PRODUCTION UNIT - THERMAL OXIDIZER Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: NATURAL GAS Throughput: 77.44 MMBTU/H

Process Notes: ACROLEIN PRODUCTION UNIT THERMAL OXIDIZER

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 15.4900 LB/H

Emission Limit 2: 61.0000 PPM @ 3% O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: 45.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8330 LB/H Emission Limit 2: 0.0030 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8330 LB/H Emission Limit 2: 0.0030 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8330 LB/H Emission Limit 2: 0.0030 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ANDRUSSOW HCN PRODUCTION UNIT - THERMAL OXIDIZER / WASTE HEAT BOILER Process Type: 12.300 (Gaseous Fuel & Gaseous Fuel Mixtures (>100 million BTU/H & ¿250 million Btu/H)) Primary Fuel: NATURAL GAS Throughput: 48.30 MMBTU/H

Process Notes: ANDRUSSOW WASTE HEAT BOILER/ THERMAL OXIDIZER

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 0.0544 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 0.0544 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 18.3100 LB/H Emission Limit 2: 150.0000 PPM @ 3% O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SNCR Est. % Efficiency: 60.000Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 0.0544 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ANDRUSSOW HCN PRODUCTION UNIT - FLARE HCNA - 2 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput: 0

Process Notes: ANDRUSSOW FLARE HCNA - 2

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 20.0100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 63.11(B) SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

## Process/Pollutant Information

PROCESS NAME: ANDRUSSOW AMSUL PRODUCTION UNIT DUST SCRUBBER Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput: 0

Process Notes: ANDRUSSOW DUST SCRUBBER HCNA - 3

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 0.0544 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: 85.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 0.0544 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBEREst. % Efficiency: 85.000

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 0.0544 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: 85.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) WET SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Facility Information

RBLC ID: 

## FL-0318 (final) Date Determination Last Updated: 11/02/2010 Corporate/Company Name: VERENIUM Permit Number: PSD-FL- 406 (0550061-001-AC) Facility Name: HIGHLANDS ETHANOL FACILITY Permit Date: 12/10/2009 (estimated) Facility Contact: FRS Number: UNKNOWN Facility Description: The Highlands Ethanol Facility (HEF) will be a cellulosic ethanol production facility. The HEF will have a permitted annual capacity 39.4 MGPY of ethanol that will be blended and denatured with gasoline to produce up to 41.5 MGPY of denatured product. SIC Code: 2869

Permit Type: A: New/Greenfield Facility NAICS Code: 325193 Permit URL: EPA Region: 4 COUNTRY: USA Facility County: HIGHLAND Facility State: FL Facility ZIP Code: Permit Issued By: FLORIDA DEPT. OF ENVIRONMENTAL PROTECTION (Agency Name) MR. JEFF KOERNER(Agency Contact) (850)921-9000 Jeff.Koerner@dep.state.fl.us Other Agency Contact Info: Alvaro Linero, P.E. Administrator Phone 850-921-9523 alvaro.linero@dep.state.fl.us David Read david.read@dep.state.fl.us Permit Notes: The average daily ethanol production capacity is 108,000 gallons per day (gpd) and 118,800 gpd as peak daily capacity. The HEF will generate its own process steam fuel consisting of biomass (stillage cake) from the fermentation and distillation steps and biogas from the on-site wastewater treatment plant. Natural gas (NG-depending on local availability) and ultralow sulfur diesel (ULSD) fuel oil (FO) with a maximum sulfur (S) concentration of 0.0015% or propane will be used as backup fuels. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 FL Everglades NP 100km - 50km



## Process/Pollutant Information

PROCESS NAME: Roadway Emissions and Biomass Handling

Process Type: 99.120 (Ash Storage, Handling, Disposal)Primary Fuel:

Throughput: 0

Process Notes: Material transfer points will be enclosed to the extent practical. Conveyer belts will be covered to keep wind and rain away from the material. All

conveying will be by mechanical means and no air (such as pneumatic systems) will be used in conveying, thereby reducing potential emission points.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 5.0000 OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Visible Emission (VE) Standard: As determined by EPA Method 9, there shall be no VE greater than 5% opacity at drop points, transfer points and dust collector outlets. PM Standard: PM emissions from dust collectors shall not exceed 0.005 grains per dry standard cubic foot (gr/dscf). A control plan to control PM emissions from biomass delivery, handling and preparation is given in Appendix BMP and shall be followed at all times by the permittee. This plan also addresses measures to minimize the chance of the spontaneous combustion of supplemental biomass storage piles and quality assurance measures for biomass delivered from vendors to the HEF. An example of the procedures to control fugitive PM emission is the wetting of roads and gravel areas during dry periods. PM emissions from dust collectors shall not exceed 0.005 grains per dry standard cubic foot (gr/dscf).

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Other Other Test Method: Method 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PM Standard: PM emissions from dust collectors shall not exceed 0.005 grains per dry standard cubic foot (gr/dscf). A control plan to control PM emissions from biomass delivery, handling and preparation, given in Appendix BMP of the permit, shall be followed at all times by the permittee. This plan also addresses measures to minimize the chance of the spontaneous combustion of supplemental biomass storage piles and quality assurance measures for biomass delivered from vendors to the HEF. An example of the procedures to control fugitive PM emission is the wetting of roads and gravel areas during dry periods. PM emissions from dust collectors shall not exceed 0.005 grains per dry standard cubic foot (gr/dscf). The initial and annual VE tests with regard to the dust collectors shall serve as a surrogate for the PM emissions tests. If the VE emissions standard is not met for the dust collectors, a PM test utilizing EPA Method 5 must be conducted on dust collector stack to show compliance with the PM emissions standard within 60 days.



## Process/Pollutant Information

PROCESS NAME: Hydrolysis, Liquid/Solid Separation and Neutralization

Process Type: 70.190 (Other Alcohol Production)

Primary Fuel: Throughput: 14.80 T/H

Process Notes: The maximum ethanol production rate is 14.8 tons per hour (TPH) and in any consecutive twelve month period 129,298 tons which is the equivalent to an

ethanol production rate 39.4 MGPY which when blended with gas will equal up to 41.5 MGPY of denatured ethanol product. The feedstocks for the facility will be dedicated energy crops, such as energy cane and forage sorghum, grown on adjacent farmland. Steam and a dilute acid solution hydrolyze the hemicellulose fraction of the biomass feedstock to produce slurry containing cellulose/lignin solids mixed with a liquid fraction containing a variety of pentose (5-carbon) sugars. The liquid pentose sugars are separated from the fiber solids through mechanical de-watering in a series of screw presses and sent to filtrate tanks to separate liquids and solids. The liquid pentose sugars will be neutralized with lime in a neutralization tank. The cellulose/lignin solids stream will be neutralized with lime in a mixer. A vapor capture system will be used to collect the evaporative emissions from each of the enclosed feed tanks and filtrate tanks. The captured emissions will be exhausted to a wet scrubber dedicated to this step. Scrubbing water will be returned to the neutralization tank as make-up water. Each stream is then stored in a tank until a fermentation vessel becomes available.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6000 LB/H Emission Limit 2: 0.1060 LB/1000 GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Wet scrubbing Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Limit: 0.106 pounds per 1000 gallons of ethanol produced

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6000 LB/H Emission Limit 2: 0.1060 LB/100 GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) The permittee shall install a wet scrubber to control VOC emissions from the liquid/solid separation system. The wet scrubber shall have a design control efficiency of 98 percent. Emissions from the wet scrubber shall discharge through a stack approximately 20 feet high at a design exit temperature of 77 degrees Fahrenheit (°F). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The maximum permitted capacity of the hydrolyzer and liquid/solid separation systems is 3,247 gallons per minute (GPM) of hydrolyzed biomass. The liquid/solid separation system shall not discharge VOC through the wet scrubber stack in excess of 0.6 pounds per hour (lbs/hr) and 0.106 pounds per 1000 gallons of ethanol produced.



## Process/Pollutant InformationPROCESS

NAME: Enzymatic Conversion, Fermentation, Distillation and Enzyme Propagation

Process Type: 70.190 (Other Alcohol Production)

Primary Fuel: Throughput: 14.80 T/H

Process Notes: The maximum ethanol production rate is 14.8 TPH and in any consecutive twelve month period 129,298 tons which is the equivalent to an ethanol

production rate 39.4 MGPY which when blended with gas will equal up to 41.5 MGPY of denatured ethanol product. This process: •The cellulose in the solids’ stream will be converted to liquid glucose (six-carbon) sugars using a proprietary enzyme. These sugars will be fermented with an enzyme to produce a dilute ethanol beer. The beer will then be transferred to a stripper that initiates the distillation process. •The hemicellulosic sugars will be separately fermented in batch mode with an enzyme to produce dilute ethanol beer. The fermented mash will be passed to a beerwell upon completion of each fermentation batch. The beer will then be transferred to a beer stripper that initiates the distillation process. •The heads (vapors) from the two beer strippers will be passed to a stripper/rectifier for further distillation and then a molecular sieve system to remove remaining water (dehydration) from the product. •Proprietary bacteria and enzymes will be produced on-site. These will be cultured, nourished and propagated under sanitary conditions using a clean-in-place (CIP) system. Nutrients required to produce the enzyme and bacteria will be stored adjacent to the propagation system. •The vents associated with this equipment will be connected to a wet scrubber to control volatile organic compounds (VOC). Scrubbing water will be returned to the cellulosic beerwell as make-up water.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.1000 LB/H Emission Limit 2: 0.9540 LB/1000 GAL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) A wet scrubber to control VOC emissions from the fermentation and propagation and distillation systems. The wet scrubber shall have a design control efficiency of 98 percent. Emissions from the wet scrubber shall discharge through a stack approximately 24.5 feet high at a design exit temperature of 77 °F. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The maximum permitted feed rate into the fermentation, propagation and distillation systems is 14.8 TPH and 129,298 tons in any consecutive twelve month period which is the equivalent to an ethanol production rate 39.42 million gallons. The fermentation, propagation and distillation systems shall not discharge VOC through the wet scrubber stack in excess of 5.1 lbs/hr and 0.954 pounds per 1000 gallons of ethanol produced.

## Process/Pollutant Information

PROCESS NAME: Solids (stillage and gypsum) separation, dewatering and loadout

Process Type: 70.190 (Other Alcohol Production)

Primary Fuel: Throughput: 14.80 T/H

Process Notes: The maximum ethanol production rate is 14.8 tons per hour (TPH) and in any consecutive twelve month period 129,298 tons which is the equivalent to an

ethanol production rate of 39.4 MGPY which when blended with gas will equal up to 41.5 MGPY of denatured ethanol product. This process: •The lignin-rich biomass residue (stillage cake) will be removed from the bottom of the cellulosic beer stripper, partially dewatered, and conveyed to the biomass boilers. Stillage will be generated at a rate of 25 dry tons per hour with moisture content between 35 and 60%. Handling will be performed entirely within a closed system except for the conveyor. •Gypsum (CaSO4) residue will be removed from the hemicellulosic beer stripper, dewatered, and conveyed to farms. •The water fraction from the stillage and gypsum dewatering steps will be conveyed to the wastewater treatment plant (WWTP).

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) To minimize VOC emissions the stillage shall be kept at ambient temperature. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The maximum permitted capacity of the stillage loadout systems is 25 TPH of stillage with a maximum of 219,000 tons in any consecutive twelve month period. Emissions from the stillage loadout system will consist of fugitive VOC. These emissions are not controlled. To minimize VOC emissions the stillage shall be kept at ambient temperature. According to the permittee, due to the high moisture content of the stillage (35 to 60 percent) fugitive PM emissions should be minimal.

## Process/Pollutant Information

PROCESS NAME: Ethanol, Gasoline Storage and Blending

Process Type: 70.190 (Other Alcohol Production) Primary Fuel: Throughput: 14.80 T/H

Process Notes: The maximum ethanol production rate is 14.8 tons per hour (TPH) and in any consecutive twelve month period 129,298 tons which is the equivalent to

an ethanol production rate of 39.4 MGPY which when blended with gas will equal up to 41.5 MGPY of denatured ethanol product. This process: The purified ethanol and gasoline (denaturant) will be stored in tanks and then blended, resulting in the denatured ethanol product, which will have dedicated storage tanks.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Other Other Test Method: Tanks design Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Emissions of VOC from the product storage tanks will be controlled by the proper construction of the tanks per 40 CFR 60.110b(a)(2). These tanks will be designed with internal floating roofs to minimize VOC emissions. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The permitted estimated VOC emissions from the product storage tanks to be 0.5 lb/hr and 1.7 TPY. BACT for these tanks is the selection of floating roof. The maximum throughput (process) rate of the product storage emissions unit is 39,420,000 gallons of ethanol. For the E95 blended final product, the throughput of gasoline shall be no more than 2,074,737 gallons with a final product production rate of no more than 41,494,737 gallons of E95 in any consecutive twelve month period. For the E98 blended final product, the throughput of gasoline shall be mo more than 804,490 gallons with a final product production rate of no more than 40,224,420 gallons of E98 in any consecutive twelve month period. Ethanol denatured within the E95 to E98 range shall have the allowable amount of gasoline and final denatured product production rate prorated to the appropriate amount in any consecutive twelve month period.

## Process/Pollutant Information

PROCESS NAME: Product Loadout and Flare

Process Type: 70.190 (Other Alcohol Production) Primary Fuel: Throughput: 14.80 T/H

Process Notes: The maximum ethanol production rate is 14.8 tons per hour (TPH) and in any consecutive twelve month period 129,298 tons which is the equivalent to

an ethanol production rate of 39.4 million gallons per year (MGPY) which when blended with gasoline will equal up to 41.5 MGPY of denatured ethanol product. This process: The denatured ethanol product will be loaded onto tank trucks at a rate of 600 gallons per minute. Vapors displaced from the trucks will be exhausted to a flare (006). The product loadout flare will have a rated capacity of 9.42 million Btu per hour (mmBtu/hr) to control vapors displaced from the trucks during the loading of denatured ethanol. The trucks are assumed as not in dedicated ethanol service (i.e., some trucks will have returned from delivering gasoline and gasoline vapors will be displaced).

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Other Other Test Method: Flare Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The flare shall be operated at all times when truck loading operations are taking place. Only E95 to E98 shall only be loaded into the trucks. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The flare shall be designed for and operated with no visible emissions (VE) except for periods not to exceed a total of 5 minutes during any 2 consecutive hours The flare system is designed to combust vapors displaced from the trucks during the loading of the denatured ethanol product. The trucks are assumed to not to be in dedicated denatured ethanol product service (i.e., some trucks will have returned from delivering gasoline and gasoline vapors will be displaced). The product loadout flare will have a rated capacity of 9.42 mmBtu/hr. NG will be used as the fuel for the pilot which has a rated capacity of 0.18 mmBtu/hr. If NG is not available, propane will be used for the pilot until NG becomes available.

## Process/Pollutant Information

PROCESS NAME: Wastewater Treatment Plant, Biogas Conditioning and Flare

Process Type: 22.900 (Other Wastewater Treatment Processes) Primary Fuel: Throughput: 1640.00 G/M

Process Notes: The facility will include a WWTP to treat process wastewaters and to condition the resulting biogas for use as fuel in the boilers or to flare it when it

cannot be used in the boilers. The effluent from the WWTP will be recycled to the plant or reused for irrigation. The flow through the WWTP will be approximately 1,640 gallons per minute (gpm). The WWTP and associated systems will consist of an equalization basin, clarifiers, anaerobic reactors, aeration basin and sand filters.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.4000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) The flare shall be operated with a flame present at all times. The presence of a flare pilot flame shall be monitored using a thermocouple or any other equivalent device to detect the presence of a flame. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The flare shall be designed for and operated with no visible emissions (VE) except for periods not to exceed a total of 5 minutes during any 2 consecutive hours. The flare system is designed to combust biogas when the biomass and backup boilers are not operating. The WWTP flare will have a rated capacity of 44.03 mmBtu/hr. Natural gas will be used as fuel for the pilot which has a rated capacity of 0.18 mmBtu/hr. If NG is not available, propane will be used for the pilot until NG becomes available.



## Process/Pollutant Information

PROCESS 198 mmBtu/hr Biomass Fueled BoilerPROCESS

NAME: 198 mmBtu/hr Biomass Fueled Boiler

Process Type: 12.120 (Biomass (includes wood, wood waste, bagasse, and other biomass)) Primary Fuel: Stillage & biomass Throughput: 198.00 MMBTU

Process Notes: Two BFB combustion boilers, each with a design heat input capacity of 198 mmBtu/hr, will be used to combust the stillage cake augmented by

supplementary biomass, NG and the biogas produced by the anaerobic reactors of the WWTP. ULSD FO or propane will be used at least until NG is locally available. The maximum heat input is 218 mmBtu/hr (4-hr average). The facility will include a backup boiler with a design heat input rate of 198 mmBtu/hr and the ability to burn biogas, NG, ULSD FO or propane. The ULSD FO storage tank will have a capacity of 110,000 gallons and will be contained in a concrete dike for spill containment.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0750 LB/MMBTU 30-DAY ROLLING AVERAGE Emission Limit 2: 14.9000 LB/H 30-DAY ROLLING AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) SNCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: EPA/OAR Mthd 6C Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0600 LB/MMBTU 30 DAY ROLLING AVERAGE Emission Limit 2: 11.9000 LB/H 30 DAY ROLLING AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (B) Limestone injection in the BFB boilers to control SO2 and HCl Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: A

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1000 LB/MMBTU 30 DAY ROLLING AVERAGE Emission Limit 2: 19.8000 LB/H 30 DAY ROLLING AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Good combustion practices Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Other Other Test Method: Method 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/MMBTU Emission Limit 2: 2.0000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Baghouse Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrochloric Acid

CAS Number: 7647-01-0 Test Method: Other Other Test Method: Method 26 Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0054 LB/MMBTU 30 DAY ROLLING AVERAGE Emission Limit 2: 1.0500 LB/H 30 DAY ROLLING AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Limestone injection into the BFB boilers to control SO2 and HCl Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU Emission Limit 2: 1.0000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Good combustion controls Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: EPA/OAR Mthd 320 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 10.0000 PPMVD Emission Limit 2: 1.4500 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 10.0000 % Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Baghouse Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: 10 percent (%) opacity (6-minute blocks) 20% opacity (one 6-minutes block per hour)



## Process/Pollutant Information

PROCESS NAME: Cooling TowerProcess Type: 99.009 (Industrial Process Cooling Towers)

Primary Fuel: Throughput: 22500.00 GAL/M

Process Notes: An induced draft evaporative cooling tower will provide cooling of process water for the project. The tower will be of rectangular mechanical-draft

design with six cells. Each cell will be equipped with its own fan and a high efficiency drift eliminator to minimize water drift losses. The recirculating flow rate will be approximately 22,500 gpm. Total dissolved solids in the cooling water are expected to be approximately 2,750 milligrams per liter (mg/l).

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Other Other Test Method: Sampling of water Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4.1000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The cooling tower shall be constructed to achieve the specified drift rate of no more than 0.0005 percent of the circulating water flow rate. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC emissions can occur from cooling towers used in chemical plants, where the circulating water is used to cool down hydrocarbon process streams. While the process heat exchangers will be designed to prevent contact of the cooling water with the process streams, leaks in the process heat exchangers can occur. The VOCs that would consequently enter the cooling water would ultimately be stripped out by the cooling tower’s air flow. Therefore, the permittee shall control VOC emissions by promptly repairing any leaking components in accordance with the approved LDAR plan. The permittee shall collect a sample of cooling water on a weekly basis and analyze it for VOCs to enable the early detection of leaking heat exchangers and thereby minimizing VOC emissions from the cooling tower.



## Process/Pollutant Information

PROCESS NAME: Miscellaneous Storage Silos

Process Type: 99.999 (Other Miscellaneous Sources)Primary Fuel:

Throughput: 0

Process Notes: The facility will include equipment and silos for the handling and storage of dry materials. The materials stored in these silos include enzyme

propagation nutrients and pebbled lime for the ethanol process and limestone, sand, urea and ash related to the biomass boilers. These materials will be stored in silos, each of which will be equipped with fabric filters to control emissions during material handling.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 5.0000 OPACITY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Fabric filters baghouses (bin vent filters) will be used to control PM emissions from all the silos. All silos will have stacks with design diameters of 1.5 feet with design flow rates of 2,500 ACFM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VE from the silo baghouses shall not exceed 5% opacity as demonstrated by initial and annual compliance tests. A visible emission reading of 5% opacity or less may be used to establish compliance with the PM emission standard. A visible emission reading greater than 5% opacity will require the permittee to perform a PM emissions stack test within 60 days to show compliance. The HEF will include equipment and silos for the handling and storage of dry materials. These materials include nutrients for the propagation of the proprietary enzyme and bacteria, lime for the neutralization of hydrolyzate and cake prior to fermentation, and materials associated with the biomass boilers.

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Other Other Test Method: Method 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Fabric filters baghouses (bin vent filters) will be used to control PM emissions from all the silos. All silos will have stacks with design diameters of 1.5 feet with design flow rates of 2,500 ACFM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PM emissions from each baghouse of the silos shall not exceed 0.005 gr/dscf. VE Standard: VE from the silo baghouses shall not exceed 5% opacity as demonstrated by initial and annual compliance tests. A visible emission reading of 5% opacity or less may be used to establish compliance with the PM emission standard. A visible emission reading greater than 5% opacity will require the permittee to perform a PM emissions stack test within 60 days to show compliance



## Process/Pollutant Information

PROCESS NAME: Emergency Generators

Process Type: 17.220 (Other Liquid Fuel & Liquid Fuel Mixtures) Primary Fuel: Throughput: 0

Process Notes: Four emergency generators, each rated at 2,000 kilowatts (kW), will be installed to provide backup electrical power in the event of a power outage at

the facility.

POLLUTANT NAME: Hydrocarbons, Total

CAS Number: VOC Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 6.4000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: These emergency generators are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification. Standard : 6.4 (NMHC+NOX) g/kWH non-methane hydrocarbons

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Other Other Test Method: Manufacturer Description Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.5000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: These emergency generators are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Other Other Test Method: Manufacturer Specifications Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: These emergency generators are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0015 % S Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: These emergency generators are Stationary Compression Ignition Internal Combustion Engines (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII, including emission testing or certification.



## Process/Pollutant Information

PROCESS NAME: Facility-wide Fugitive VOC Equipment Leaks

Process Type: 49.999 (Other Organic Evaporative Loss Sources) Primary Fuel: Throughput: 0

Process Notes: Fugitive VOC emissions are grouped for the entire process and will be minimized by implementation of a monthly leak detection and repair (LDAR)

monitoring program.

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Other Other Test Method: Leak Detection and Repair (LDR) program Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 19.6000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) The most practical method of controlling fugitive VOC emissions from HEF is to promptly repair any leaking components. HEF is subject to NSPS 40 CFR 60, Subpart VVa - VOC Equipment Leaks in the Synthetic Chemical Manufacturing Industry (SOCMI). NSPS Subpart VVa requires a LDAR program. HEF must come in to compliance with Subpart VVA, including the LDAR program, no later than 180 days after HEF becomes operational. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The permittee must submit for approval a Leak Detention Plan (LDAR) no later than June 30, 2010. Once the program plan is approved by the Compliance Authority, the permitted shall implement the program within 180 days of initial startup of the HEF.



## Process/Pollutant Information

PROCESS NAME: Emergency Fired Pump

Process Type: 17.220 (Other Liquid Fuel & Liquid Fuel Mixtures) Primary Fuel: ULSD fuel oil Throughput: 0

Process Notes: A backup 360 hp diesel fire pump will also be installed to provide firewater during power outages. This unit will fire ULSD FO or propane and will be

limited to 500 hours per year of operation. This unit will be operated no more than 100 hours per year for testing and maintenance purposes per 40 CFR 60, Subpart IIII. The engine will be designed to meet USEPA’s emission standards listed in 40 CFR Part 60 Subpart IIII for model year 2009 or later. Potential to emit (PTE) emissions are based on an assumed maximum operating time of 500 hr/yr.

POLLUTANT NAME: Hydrocarbons, Total

CAS Number: VOC Test Method: Other Other Test Method: Manufacturer CertificationOther Test Method: Manufacturer Certification

Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 3.0000 G/HP-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The fire pump engine is an Emergency Stationary Compression Ignition Internal Combustion Engine (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII. Standard: 3.0 NMHC + NOX (g/hp-hr)

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The fire pump engine is an Emergency Stationary Compression Ignition Internal Combustion Engine (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII.

POLLUTANT NAME: Particulate matter, total (TPM)

CAS Number: PM Test Method: Other Other Test Method: Manufacturer CertificationPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.1500 G/HP-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The fire pump engine is an Emergency Stationary Compression Ignition Internal Combustion Engine (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: Manufacturer Certification Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0015 % S Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Ultra low sulfur fuel oil (ULSFO) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: The fire pump engine is an Emergency Stationary Compression Ignition Internal Combustion Engine (Stationary ICE) and shall comply with applicable provisions of 40 CFR 60, Subpart IIII.



## Process/Pollutant Information

PROCESS NAME: Backup 198 mmBtu/hr boiler

Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary Fuel: Natural gas Throughput: 0

Process Notes: If NG is not available, propane or ULSD FO may be used as a primary fuel. Biogas produced in the anaerobic reactors of the facility's WWTP may

be used to supplement the fossil fuels.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7E Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0720 LB/MMBTU 30-DAYS ROLLING AVERAGE Emission Limit 2: 14.3000 LB/H 30-DAYS ROLLING AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: NSPS Control Method: (P) Low NOx burners and Flue Gas Recirculation Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CEMS based NOx limit in lb/mmBtu will ensure compliance with 40 CFR 60, NSPS Subpart Db NOx limit of 0.30 lbNOx/mmBtu

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: EPA/OAR Mthd 6C Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0056 LB/MMBTU Emission Limit 2: 1.1000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: Use of low sulfur fossil fuels such as ULSD FO, natural gas or propane in the backup boiler insures that uncontrolled SO2 emissions are less than 0.32 lb SO2/mmBtu. Therefore, no specific limit from 40 CFR 60, NSPS Subpart Db applies to the backup boiler.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0370 LB/MMBTU Emission Limit 2: 7.3000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Other Other Test Method: Method 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0071 LB/MMBTU Emission Limit 2: 1.4000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Fabric filter Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Compliance with the PM/PM10 mass emission limit insures compliance with the 40 CFR60, Subpart Db limit of 0.030 lb/PM/mmBtu (filterable PM)POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25A Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU Emission Limit 2: 0.3000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 10.0000 PERCENT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: During startups, shutdowns and malfunction the following limits apply: 20% opacity (6-min block) except for one 6-minute block per hour 27%.



## Facility InformationRBLC ID: 

## LA-0213 (final) Date Determination Last Updated: 03/05/2010 Corporate/Company Name: VALERO REFINING - NEW ORLEANS, LLC Permit Number: PSD-LA-619(M5)

Facility Name: ST. CHARLES REFINERY Permit Date: 11/17/2009 (actual) Facility Contact: ROB MARTIN 9857645605 FRS Number: 110002046189 Facility Description: PETROLEUM REFINERY. PROJECT INVOLVES INCREASE IN CAPACITY FROM 220,000 TO 380,000 BARRELS PER DAY. SIC Code: 2911

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: ST. CHARLES Facility State: LA Facility ZIP Code: 70079 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: PERMIT WRITER: MR. DAN NGUYEN, 225-219-3180

Permit Notes: APPLICATION ACCEPTED DATE REFLECTS DATE OF ADMINISTRATIVE COMPLETENESS. PSD-LA-619(M3), ISSUED JUNE 28, 2007, SPECIFIED THAT THE AVERAGING PERIOD FOR FUEL GAS H2S CONCENTRATION IS AN ANNUAL AVERGE; REMOVED MAXIMUM LB/HR LIMITS FOR FUGITIVE AND AREA SOURCES AND SULFURIC ACID TANKS; AND INCREASED THE CIRCULATION RATE OF COOLING TOWER 2004-6 (EQT035) FROM 36,000 TO 43,200 GPM. PERMITTED PM10 EMISSIONS INCREASED BY 0.01 TPY; PERMITTED VOC EMISSIONS INCREASED BY 0.18 TPY. BACT WAS NOT REEVALUATED. PSD-LA-619(M4), ISSUED DECEMBER 5, 2008 TO REVISE THE SCOPE OF THE REFINERY EXPANSION PROJECT. PSD-LA-619(M5), ISSUED NOVEMBER 17, 2009 TO IMPLEMENT THE MSATII COMPLIANCE PROJECT AND SCALE DOWN THE ORIGINAL REFINERY EXPANSION PROJECT. BACT WAS NOT REEVALUATED. FCCU NO. 3 AND GDU NO. 2 HEATER WERE REMOVED. THE REVISION DROPPED H2SO4 OUT OF THE PSD REVIEW.



## Process/Pollutant Information

PROCESS NAME: BOILER 401-E (2004-10) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 525.00 MMBTU/H

Process Notes: BOILER ALSO FIRES NATURAL GAS.POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 34.5900 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0800 LB/MMBTU HOURLY AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEATERS/REBOILERS

Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes: 6-81: 135 MM BTU/HR 2004-1: 86 MM BTU/HR 2004-2: 24 MM BTU/HR 2004-3: 52 MM BTU/HR 2004-4: 86 MM BTU/HR 2004-7: 885 MM

BTU/HR 2004-8: 885 MM BTU/HR 2005-1: 1274 MM BTU/HR 2005-2: 744 MM BTU/HR 2005-3: 555 MM BTU/HR 2005-8: 100 MM BTU/HR 2005-9: 83 MM BTU/HR 2005-10: 336 MM BTU/HR 2005-22: 261 MM BTU/HR 2005-23: 100 MM BTU/HR 2005-24: 83 MM BTU/HR 2005-25: 336 MM BTU/HR SOURCES ALSO FIRE NATURAL GAS.

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR REFINERY FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 100 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/MMBTU THREE 1-HOUR TEST AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/MMBTU THREE 1-HOUR TEST AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: HEATERS (2008-1 - 2008-9)

Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: PROCESS FUEL GAS Throughput:

Process Notes: 2008-1: 36 MM BTU/HR 2008-2: 880 MM BTU/HR 2008-3: 641 MM BTU/HR 2008-4: 108 MM BTU/HR 2008-5: 123 MM BTU/HR 2008-6: 803

MM BTU/HR 2008-7: 122 MM BTU/HR 2008-8: 803 MM BTU/HR 2008-9: 122 MM BTU/HR SOURCES ALSO FIRE NATURAL GAS.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR PROCESS FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 10 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/MMBTU THREE 1-HOUR TEST AVERAGE AIR PREHEATEDEmission Limit 2: 0.0300 LB/MMBTU THREE 1-HOUR TEST AVERAGE

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/MMBTU HOURLY AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPARTS NNN AND RRR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) COMPLY WITH 40 CFR 60 SUBPARTS NNN AND RRR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , SIP Control Method: (P) COMPLY WITH 40 CFR 60 SUBPARTS NNN AND RRR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: MVR THERMAL OXIDIZER NO. 2 (2008-38) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: REFINERY FUEL GAS Throughput: 200.00 MMBTU/H

Process Notes: SOURCES ALSO FIRE NATURAL GAS.

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.2300 LB/H HOURLY MAXIMUMEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.4500 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR PROCESS FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 10 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 29.4100 LB/H HOURLY MAX Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 24.7100 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.4000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMITOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) COMPLY WITH 40 CFR 61 SUBPART BB Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEATERS (94-21 & 94-29) Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes: SOURCE ALSO FIRES NATURAL GAS. 94-21: 48 MM BTU/HR 94-29: 75 MM BTU/HR

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR REFINERY FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 100 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: SEE NOTE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: CPF HEATER H-39-03 & H-39-02 (94-28 & 94-30) Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes: H-30-03: 68 MM BTU/HR H-39-02: 90 MM BTU/HR SOURCES ALSO FIRE NATURAL GAS.

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0074 LB/MMBTU ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/MMBTU THREE ONE HOUR TEST AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR TEST AVERAGEEmission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR TEST AVERAGE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0054 LB/MMBTU ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR REFINERY FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 100 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: BOILERS (94-43 & 94-45) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 354.00 MMBTU/H EA

Process Notes: SOURCES ALSO BURN NATURAL GAS.

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.6400 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) CLEAN FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 9.4300 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR REFINERY FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 100 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 46.3700 LB/H HOURLY MAXIMUM FOR BOILER 94-43 Emission Limit 2: 36.8200 LB/H HOURLY MAXIMUM FOR BOILER 94-45 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) FUEL CHOICE, OPERATING TECHNIQUES, AND LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 29.1500 LB/H HOURLY MAXIMUMEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD OPERATING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.9100 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE 1-5 (15-77, 12-81, 2004-5A, 2004-5B & 2005-38) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR REFINERY FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 100 PPMV (ANNUAL AVERAGE) AS FUELS AT FLARE TIP. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: SEEE NOTE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: COOLING TOWERS (13-81, 2004-6, 2005-42, 2005-43, 2008-35)

Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput:

Process Notes: 13-81: 61,000 GPM 2004-6: 42,000 GPM 2005-42: 32,000 GPM 2005-43: 32,000 GPM 2008-35: 50,000 GPM (AROMATIC RECOVERY UNIT)

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) MONITORING PROCESS SIDE OF THE HEAT EXCHANGERS FOR LEAKS 2008-35: VOC MONITORING PROGRAM MEETS 40 CFR 63 SUBPART F Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.0100 T/YR ANNUAL MAXIMUM Standard Emission:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS IN PERMIT READ



## Process/Pollutant Information

PROCESS NAME: SRU THERMAL OXIDIZERS (99-3, 99-4, 2005-39, 2007-4) Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput: 50.00 MMBTU/H

Process Notes: 99-3: 60 MM BTU/HR 99-4: 60 MM BTU/HR 2005-39: 50 MM BTU/HR 2007-4: 50 MM BTU/HR

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)CAS Number: 7446-09-5

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 250.0000 PPMVD 12 HOUR ROLLING AVERAGE Emission Limit 2: 115.3100 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) CONTROL DEVICE - COMPLY WITH 40 CFR 60 SUBPART J Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 9.4000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.1100 LB/H HOURLY MAXIMUMEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3400 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.7300 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FCCU REGENERATOR (16-77) Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes: 130,000 BBLS/DAY

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 74.6000 LB/H Emission Limit 2: 240.8600 T/YR Standard Emission: 2.0000 LB/T OF COKE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) WET SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Oxides (SOx)

CAS Number: 7446 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 176.1200 LB/HEmission Limit 2: 326.3500 T/YR

Standard Emission: 50.0000 PPMV 7 DAY ROLLING AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (A) WET SCRUBBER Est. % Efficiency: 90.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 145.3200 LB/H Emission Limit 2: 182.7300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 696.8000 LB/H Emission Limit 2: 95.0000 T/YR Standard Emission: 250.0000 MG/NM3 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) FULL BURN DESIGN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 15.5000 LB/H Emission Limit 2: 13.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FULL BURN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.9000 LB/H Emission Limit 2: 1.6800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PETROLEUM PRODUCT LOADING DOCKS (94-9) Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 687.0000 LB/H HOURLY MAXIMUM Emission Limit 2: 160.2500 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) COMPLY WITH LAC 33:III.2108 FOR LOADING MATERIALS WITH VAPOR PRESSURE > 1.5 PSIA Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKER NOS. 1 & 2 STEAM VENT (2005-58 & 2005-59) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 77.50 MMSCF/YR

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 14.2100 LB/H HOURLY MAXIMUM Emission Limit 2: 5.1900 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKE HANDLING (5-83) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.4700 T/YR ANNUAL MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) KEEP COKE WET WHILE STORING AND TRANSPORTINGEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVE EMISSIONS

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: INCLUDING: ROAD DUST 90-0: REFINERY FUGITIVES 2008-39: ARU FUGITIVES 2008-37: ARU MARINE LOADING DOCK

FUGITIVES

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) REFINERY (90-0): LA REFINERY MACT LDAR PROGRAM; ARU (2008-39): MONITORING ACCORDING TO 40 CFR 63 SUBPART H; ARU LOADING (2008-37): MONITORING ACCORDING TO 40 CFR 61 SUBPART V Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: SEE NOTE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: FROM REFINERY FUGITIVES. NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) PAVING ROADS OR WETTING UNPAVED ROADS AS NECESSARY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ROAD DUST. NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: MVR THERMAL OXIDIZER NO. 1 (94-8) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: Throughput: 240.00 MMBTU/H

Process Notes:POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.8000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 3.3000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF PIPELINE QUALITY NATURAL GAS OR REFINERY FUEL GASES WITH AN H2S CONCENTRATION LESS THAN 100 PPMV (ANNUAL AVERAGE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 23.5000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 19.8000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER EQUIPMENT DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 442.0000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (N) COMPLY WITH LAC 33:III.2108 AND 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.9500 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: WASTEWATER COLLECTION & TREATMENT: ARU Process Type: 64.006 (Wastewater Collection & Treatment) Primary Fuel: Throughput:

Process Notes: WW (EQT0255) - AROMATIC RECOVERY UNIT

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPARTS F & G Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: TANKS - FOR BENZENE, XYLENE, SULFOLANE, PAREX, INTERMEDIATE Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes: 16 IFR TANKS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) EQUIPPED WITH INTERNAL FLOATING ROOFS FOLLOWED BY THERMAL OXIDIZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

## Process/Pollutant Information

PROCESS NAME: TANKS - FOR LIGHT MATERIALS, SOUR WATER, NAPHTHA, RAFFINATE Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput:

Process Notes: 38 TANKS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) EQUIP WITH FLOATING ROOFS (IFR OR EFR) & COMPLY WITH 40 CFR 60 SUBPART KB OR 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: ARU FLARE (2008-36) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: PROCESS FUEL GAS Throughput:

Process Notes: ALSO FUELED BY NATURAL GAS

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTEEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) FUELED BY NATURAL GAS OR PROCESS FUEL GAS WITH H2S Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: BOILERS (2008-10, 2008-11, 2008-40) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 715.00 MMBTU/H EA

Process Notes: ALSO FUELED BY NATURAL GAS AND PROCESS FUEL GAS

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPARTS NNN AND RRR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTEEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FUELED BY NATURAL GAS AND/OR REFINERY FUEL GAS WITH H2S Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/MMBTU WITH COMBUSTION AIR PREHEAT Emission Limit 2: 0.0300 LB/MMBTU WITHOUT COMBUSTION AIR PREHEAT Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: 79.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR TEST AVE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) COMPLY WITH 40 CFR 60 SUBPARTS NNN AND RRR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPARTS NNN AND RRR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: DHT HEATERS (4-81, 5-81) Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 70.00 MMBTU/H EA

Process Notes: ALSO FUELED BY NATURAL GAS

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTEEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FUELED BY NATURAL GAS OR REFINERY FUEL GAS WITH H2S Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR TEST AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR TEST AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: HEATER F-72-703 (7-81) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 633.00 MMBTU/H

Process Notes: ALSO FUELED BY NATURAL GAS

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) FUELED BY NATURAL GAS OR REFINERY FUEL GAS WITH H2S Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/MMBTU THREE ONE HOUR TEST AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: THERMAL OXIDIZERS (2008-32, 2008-33, 2008-34) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: PROCESS FUEL GAS Throughput: 15.00 MMBTU/H EA

Process Notes: ALSO FUELED BY NATURAL GAS

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES, AND GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FUELED BY NATURAL GAS AND PROCESS FUEL GAS WITH H2S Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND OPERATION, GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant InformationPROCESS NAME: TANKS - FOR HEAVY MATERIALS

Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes: 39 FIXED ROOF TANKS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) EQUIPPED WITH FIXED ROOF AND COMPLY WITH 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: TANKS - FOR SPENT CAUSTIC Process Type: 62.020 (Inorganic Liquid/Gas Storage & Handling) Primary Fuel: Throughput:

Process Notes: 2 FIXED ROOF TANKS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTEEmission Limit 1: SEE NOTE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FIXED ROOF AND SUBMERGED FILL LINES (LAC 33:III.2103) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: LOADINGS - REFINERY Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes: SULFURIC ACID LOADING TRUCK/RAILCAR LOADING SULFUR LOADING

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) TRUCK/RAILCAR LOADING: COMPLY WITH 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLEPOLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) PROPER DESIGN AND OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: LOADINGS - AROMATIC RECOVERY UNIT Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) RAILCAR LOADING: COMPLY WITH 40 CFR 63 SUBPART G MARINE LOADING: COMPLY WITHControl Method: (P) RAILCAR LOADING: COMPLY WITH 40 CFR 63 SUBPART G MARINE LOADING: COMPLY WITH 40 CFR 61 SUBPART BB Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: PROCESS VENTS - REFINERY (CCEX) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) ROUTE TO THE FUEL GAS SYSTEMS OR FLARES OR COMPLY WITH 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTEEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) ROUTE TO FUEL GAS SYSTEMS OR FLARES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: VENT GAS WASH TOWER (99-8) Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

## Process/Pollutant Information

PROCESS NAME: WASTEWATER COLLECTION & TREATMENT: REFINERY Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes: WW (EQT0255) WWTU (EQT0359) CRUIDS (EQT0369)

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , NESHAP Control Method: (P) WW (EQT0255): COMPLY WITH LA REFINERY MACT WWTU (EQT0359): COMPLY WITH 40 CFR 61 SUBPART FF CRUIDS (EQT369): COMPLY WITH 40 CFR 63 SUBPARTS F & G Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: CRU: CHLOROSORB VENT AND DUST COLLECTOR Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 63 SUBPART UUU Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: STARTUPS/SHUTDOWNS - SRU Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: EQT0358 - OF THE SRU (SULFUR RECOVERY UNITS)

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FOLLOW WRITTEN SOP, MINIMIZE DURATION AND FREQUENCY, PROPERLY DOCUMENT ALL SU/SD Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Facility Information

RBLC ID: 

## CA-1171 (final) Date Determination Last Updated: 04/14/2011 Corporate/Company Name: BREITBURN ENERGY COMPANY LP Permit Number: ATC13000 Facility Name: BREITBURN ENERGY- NEWLOVE LEASE Permit Date: 07/17/2009 (actual) Facility Contact: FRS Number: UNKNOWN Facility Description: SIC Code: 1311 Permit Type: A: New/Greenfield Facility NAICS Code: 211111 Permit URL: EPA Region: 9 COUNTRY: USA Facility County: SANTA BARBARA Facility State: CA Facility ZIP Code: 93455 Permit Issued By: SANTA BARBARA COUNTY APCD, CA (Agency Name) MR. BEN ELLENBERGER(Agency Contact) (805) 961-8879 EllenbergerC@SBCAPCD.ORG Other Agency Contact Info: Ben Ellenberger 805-961-8800 cbe@sbcapcd.org Permit Notes:



## Process/Pollutant Information

PROCESS NAME: Horizontal Enclosed Flare Process Type: 19.390 (Other Flares) Primary Fuel: Field gas Throughput: 50.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0146 LB/MMBTU 40 MINUTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OTHER Control Method: (P) Forced draft enclosed flare. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0371 LB/MMBTU 40 MINUTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OTHER Control Method: (P) Forced draft enclosed flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0013 LB/MMBTU 40 MINUTES Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OTHER Control Method: (P) Forced draft enclosed flare Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0231 (final) Date Determination Last Updated: 05/17/2010 Corporate/Company Name: LAKE CHARLES COGENERATION, LLC Permit Number: PSD-LA-742

Facility Name: LAKE CHARLES GASIFICATION FACILITY Permit Date: 06/22/2009 (actual) Facility Contact: DOUG BARBA 7139634635 INTERPOWERLLC@AOL.COM FRS Number: UNKNOWN Facility Description: A FACILITY TO CONVERT APPROXIMATELY 7400 TONS/DAY OF PETROLEUM COKE TO NATURAL GAS AND SULFURIC ACID. PERMIT PSD-LA-742(M1), DECEMBER 30, 2010, ALLOWS THE FACILITY TO PRODUCE 2.3 MILLION TONS OF METHANOL, INSTEAD OF NATURAL GAS. SIC Code: 2869

Permit Type: A: New/Greenfield Facility NAICS Code: 325110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: CALCASIEU Facility State: LA Facility ZIP Code: 70665 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: PERMIT WRITER: MR. DAN NGUYEN - 225-219-3180Permit Notes: APPLICATION ACCEPTED DATE REFLECTS DATE OF ADMINISTRATIVE COMPLETENESS. PERMIT PSD-LA-742(M1) WAS ISSUED DECEMBER 30, 2010 TO REVISE THE PROCESS DESIGN. THE FACILITY WILL PRODUCE H2SO4 AND METHANOL, INSTEAD OF NATURAL GAS. EXISTING BACT WILL NOT BE CHANGED. NO NEW BACT WILL BE ADDED. PERMIT PSD-LA-742(M2) DATED JUNE 29, 2012 1) REVISES THE PROCESS DESIGN TO PRODUCE HYDROGEN, 2) INCORPORATE PM 2.5 AND CO2E, AND 3)CHANGE NAME TO LAKE CHARLES CLEAN ENERGY. NO NEW BACT WILL BE ADDED. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 701.0000 (Tons/Year) Nitrogen Oxides (NOx) 218.7600 (Tons/Year) Particulate Matter (PM) 33.3800 (Tons/Year) Sulfur Oxides (SOx) 262.2700 (Tons/Year) Volatile Organic Compounds (VOC) 24.6900 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: HYDROCARBON/GASIFIERS STARTUP FLARE Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: NATURAL GAS Throughput: 487.55 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 3.6300 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND MONITORING TO ENSURE THE PRESENCE OF A FLAME AT THE FLARE TIP AT ALL THE TIME Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 333.7000 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND MONITORING TO ENSURE THE PRESENCE OF A FLAME AT THE FLARE TIP AT ALL THE TIME Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1303.9900 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 48.8100 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHANATION STARTUP HEATERS Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 56.90 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4200 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0300 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FUELED BY NATURAL GAS OR SUBSTITUTE NATURAL GAS (SNG) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 5.5800 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 4.6900 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: AUXILIARY BOILER Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 938.30 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 6.9900 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 33.7800 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 32.8400 MMBTU/H MAXIMUM Emission Limit 2: 0.0350 LB/MMBTU Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 0.2800 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FUELED BY NATURAL GAS OR SUBSTITUTE NATURAL GAS (SNG) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: THERMAL OXIDIZERS (2) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: NATURAL GAS Throughput: 40.90 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3000 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 22.9200 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.4500 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 91.8500 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) CO2 VENTS ARE ROUTED TO THE THERMAL OXIDIZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: EMERGENCY DIESEL POWER GENERATOR ENGINES (2) Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: DIESEL Throughput: 1341.00 HP EACH

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 17.0900 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.6200 LB/H MAXIMUN (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: WET SULFURIC ACID PLANTS (2) Process Type: 62.015 (Sulfuric Acid Plants) Primary Fuel: Throughput: 2000.00 T/D

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 24.8500 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 13.5000 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) SELECTIVE CATALYTIC REDUCTION SYSTEMS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , OPERATING PERMIT Control Method: (A) WET ELECTROSTATIC PRECIPITATORS AND HYDROGEN PEROXIDE SCRUBBERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 13.8000 LB/H MAXIMUM (EACH) Emission Limit 2: 0.5000 LB/T H2SO4 PROD. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) HYDROGEN PEROXIDE SCRUBBERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 6.5500 LB/H MAXIMUM (EACH) Emission Limit 2: 0.1500 LB/T H2SO4 PROD. Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) CONDENSERS, WET ELECTROSTATIC PRECIPITATORS, AND HYDROGEN PEROXIDE SCRUBBERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWERS Process Type: 62.999 (Other Inorganic Chemical Manufacturing Sources) Primary Fuel: Throughput: 436000.00 GAL/MINThroughput: 436000.00 GAL/MIN

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.6400 LB/H MAXIMUM Emission Limit 2: 0.0005 % DRIFT RATE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFURIC ACID STORAGE TANKS (6) Process Type: 62.015 (Sulfuric Acid Plants) Primary Fuel: Throughput:

Process Notes: 6 TANKS, VOLUME = 564,016 GALLONS EACH

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H MAXIMUM (EACH TANK) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FIXED ROOFS, SUBMERGED FILL PIPES, AND NITROGEN BLANKET Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKE HANDLING SYSTEMS (2) Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput: 33737.00 SCFM

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4500 LB/H MAXIMUM (EACH) Emission Limit 2: 0.0050 G/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) FABRIC FILTERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ROD MILL AIR EDUCTORS (4) Process Type: 62.015 (Sulfuric Acid Plants)Process Type: 62.015 (Sulfuric Acid Plants)

Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H MAXIMUM (EACH EDUCTOR) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ASU MOLECULAR SIEVE REGENERATION Process Type: 62.015 (Sulfuric Acid Plants) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: FUGITIVES Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: FILTER VACUUM PUMP DISCHARGES (2)

Process Type: 62.015 (Sulfuric Acid Plants) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ASU MOLECULAR SIEVE REGENERATION (2) Process Type: 62.015 (Sulfuric Acid Plants) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/H MAXIMUM (EACH)Emission Limit 1: 0.1000 LB/H MAXIMUM (EACH)

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SAND/BOTTOM ASH SILOS AND DAY BINS Process Type: 99.120 (Ash Storage, Handling, Disposal) Primary Fuel: Throughput: 2699.00 SCFM

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H MAXIMUM (EACH) Emission Limit 2: 0.0050 G/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) FABRIC FILTERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: ACID GAS FLARE Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: NATURAL GAS Throughput: 0.27 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , OPERATING PERMIT Control Method: (P) GOOD DESIGN AND MONITORING TO ENSURE THE PRESENCE OF A FLAME AT THE FLARE TIP AT ALL THE TIME Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMITControl Method: (N) NO ADDITIONAL CONTROL

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO ADDITIONAL CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND MONITORING TO ENSURE THE PRESENCE OF A FLAME AT THE FLARE TIP AT ALL THE TIME Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FIRE WATER DIESEL PUMPS (3) Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: DIESEL Throughput: 575.00 HP EACH

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: NSPS , OPERATING PERMIT

Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.0200 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) COMPLY WITH 40 CFR 60 SUBPART IIII Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SHIFT REACTOR STARTUP HEATER Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 34.20 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2500 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) FUELED BY NATURAL GAS OR SUBSTITUTE NATURAL GAS (SNG) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.3500 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.8200 LB/H MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GASIFIER STARTUP PREHEATER BURNERS (5) Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 35.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) FUELED BY NATURAL GAS OR SUBSTITUTE NATURAL GAS (SNG) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.8500 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.9600 LB/H MAXIMUM (EACH) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STEAM SUPERHEATERS (A & B) Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: SUBSTITUTE NATURAL GAS Throughput: 415.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 3.0900 LB/H TOTAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 14.5300 LB/H TOTAL Emission Limit 2: 0.0350 LB/MMBTU Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (P) ULTRA LOW NOX BURNERS (ULNB) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 14.9400 LB/H TOTAL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD DESIGN AND PROPER OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## RI-0023 (final) Date Determination Last Updated: 03/05/2010 Corporate/Company Name: RIDGEWOOD POWER MANAGEMENT Permit Number: RI-PSD-8 Facility Name: RHODE ISLAND CENTRAL GENCO, LLC Permit Date: 05/12/2009 (actual) Facility Contact: FRS Number: UNKNOWN Facility Description: LANDFILL GAS-FIRED POWER PLANT SIC Code: 173 Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 221122

Permit URL: EPA Region: 1 COUNTRY: USA Facility County: PROVIDENCEFacility State: RI

Facility ZIP Code: Permit Issued By: Rhode Island Department of Environmental Management; Air Resources (Agency Name) MS. RUTH GOLD(Agency Contact) (401)222-2808X7110 ruth.gold@dem.ri.gov Permit Notes:



## Process/Pollutant Information

PROCESS NAME: LANDFILL GAS-FIRED COMBUSTION TURBINE Process Type: 16.220 (Landfill/Digester/Bio-Gas) Primary Fuel: LANDFILL GAS Throughput: 6.00 MW

Process Notes: 5 SOLAR TAURUS 60 COMBUSTION TURBINES

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 25.0000 PPMV 1-HOUR AVERAGE Emission Limit 2: 7.9500 LB/H 1-HOUR AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (A) SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 100.0000 PPMV 1-HOUR AVERAGEEmission Limit 2: 34.8600 LB/H 1-HOUR AVERAGE

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: 100 PPMV LIMIT IS AT FULL LOAD CONDITIONS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.0000 PPMV 1-HOUR AVERAGE Emission Limit 2: 1.9900 LB/H 1-HOUR AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: 10 PPMV LIMIT IS AT FULL LOAD CONDITIONS

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0240 LB/MMBTU Emission Limit 2: 1.9000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0340 LB/MMBTU Emission Limit 2: 2.7000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 20.0000 PPMV 1-HOUR AVERAGE Emission Limit 2: 2.3500 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ULE FLARE (REGEN) Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: LANDFILL GAS Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0250 LB/MMBTU Emission Limit 2: 0.5200 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAEROther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0600 LB/MMBTU Emission Limit 2: 1.2500 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: EMISSION LIMIT: 99% REDUCTION UNLESS OUTLET NMOC HAS BEEN REDUCED TO 5PPMVD OR LESS AS HEXANE AT 3% OXYGEN. NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: ENCLOSED FLARES Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: LANDFILL GAS Throughput: 3000.00 CFM

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/MMBTU Emission Limit 2: 5.9400 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2000 LB/MMBTU Emission Limit 2: 19.8000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMIT: 98% REDUCTION UNLESS OUTLET NMOC HAS BEEN REDUCED TO 5PPMVD OR LESS AS HEXANE AT 3% OXYGEN. NO EMISSION LIMITS AVAILABLE



## Facility Information

RBLC ID: 

## OH-0308 (final) Date Determination Last Updated: 03/31/2011 Corporate/Company Name: SUNOCO, INC. Permit Number: 04-01447

Facility Name: SUN COMPANY, INC., TOLEDO REFINERY Permit Date: 02/23/2009 (actual) Facility Contact: ELAINE MOORE 4106986847 FRS Number: 110004583512Facility Description: PETROLEUM REFINERY, INCREASE IN PRODUCTION FOR TWO FLUID CATALYTIC CRACKING UNITS (FCCU) AND TO MEET COMPLIANCE WITH A CONSENT DECREE FOR THE INSTALLATION OF AIR POLLUTION CONTROL EQUIPMENT. THIS PERMIT IS PSD FOR PM10 AND CO. THE FACILITY HAS NETTED-OUT OF NONATTAINMENT NEW SOURCE REVIEW FOR VOC EMISSIONS. SIC Code: 2911

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110 Permit URL: EPA Region: 5 COUNTRY: USA Facility County: LUCAS Facility State: OH Facility ZIP Code: 43616 Permit Issued By: OHIO ENVIRONMENTAL PROTECTION AGENCY (Agency Name) MS. CHERYL SUTTMAN(Agency Contact) (614)644-3617 mailto:cheryl.suttman@epa.ohio.gov Permit Notes: MODIFICATION TO PERMIT TO INCREASE LIMIT FOR H2SO4; STACK TEST EXCEEDED MFG.'S RECOMMENDED LIMIT, THIS PERMIT #P0106143 ISSUED 5/28/10. ON 1/14/10 A MODIFICATION WAS ISSUED TO ESTABLISH COMPLIANCE W/ THE CONTROL EFFICIENCY (99%) FOR CO AND 95% FOR PM10 FROM THE CRACKING UNIT: FOR CO THRU STACK DATA ANALYZERS FOR %O2, %CO2, %CO, AND FLOW RATE; FOR PM10 METHODS 201 AND 202 WHEN REQUIRED, IN PTI # P0105652. THE PERMIT DATED 2/23/09 WAS ISSUED TO MODIFY THE ORIGINAL PERMIT, #04-01447 ISSUED FINAL ON 9/29/06, TO REFLECT THE REVISED ESTIMATED EMISSIONS AND MODIFICATIONS TO MATCH THE ACTUAL SIZE OF THE EQUIPMENT INSTALLED, TO DATE. CONTINUOUS ON-SITE CONSTRUCTION TO PROCESS UNITS IS ANTICIPATED THROUGH APRIL OF 2013. THE NETTING BELOW HAS ALSO BEEN ADJUSTED. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 360.1000 (Tons/Year) Nitrogen Oxides (NOx) -426.6700 (Tons/Year) Particulate Matter (PM) 82.8000 (Tons/Year) Sulfur Oxides (SOx) -8350.0500 (Tons/Year) Volatile Organic Compounds (VOC) 30.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: BOILER (2)

Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS + Throughput: 374.00 MMBTU/H

Process Notes: TWO BOILERS FIRED WITH REFINERY PROCESS GAS, NATURAL GAS, RESIDUAL #6 OIL, AND CO FROM FLUIDIZED CATALYTIC

CRACKING UNIT; NEW LOW NOX BURNERS TO BE INSTALLEDPOLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Other Other Test Method: METHOD 5 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.5300 LB/H Emission Limit 2: 11.1000 T/YR PER ROLLING 12 MONTHS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) BOILERS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ABOVE EMISSIONS FOR EACH INDIVIDUAL BOILER (2). THESE BOILERS ARE OPERATED AS CONTROL FOR CO WHEN THE FLUID CATALYTIC CRACKING UNIT (FCCU) IS IN OPERATION. THE LIMITS ABOVE REPRESENT THE EMISSIONS FROM THESE BOILERS WHEN THE FCCU HAS A MALFUNCTION OR IS IN STARTUP/SHUTDOWN AND VENTED TO THE 2 BOILERS. THE BOILERS ALSO HAVE COMBINED EMISSION LIMITS SHARED WITH THE FCCU DURING NORMAL FCCU OPERATIONS, SEE THE FCCU PROCESS EMISSIONS. METHOD 5, IF REQUIRED.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 9.1500 LB/H FROM EACH OF 2 BOILERS Emission Limit 2: 40.0600 T/YR PER ROLLING 12-MO.FROM EACH OF 2 BOILERS Standard Emission: 0.0270 LB/MMBTU FROM BOILERS OPERATING WITHOUT FCCU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) BOILERS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ABOVE EMISSIONS FOR EACH INDIVIDUAL BOILER (2). THESE BOILERS ARE OPERATED ASPollutant/Compliance Notes: ABOVE EMISSIONS FOR EACH INDIVIDUAL BOILER (2). THESE BOILERS ARE OPERATED AS CONTROL FOR CO WHEN THE FLUID CATALYTIC CRACKING UNIT (FCCU) IS IN OPERATION. THE LIMITS ABOVE REPRESENT THE EMISSIONS FROM THESE BOILERS WHEN THE FCCU HAS A MALFUNCTION OR IS IN STARTUP/SHUTDOWN AND VENTED TO THE 2 BOILERS. THE BOILERS ALSO HAVE COMBINED EMISSION LIMITS SHARED WITH THE FCCU DURING NORMAL FCCU OPERATIONS, SEE THE FCCU PROCESS EMISSIONS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 28.0000 LB/H Emission Limit 2: 122.6400 T/YR PER ROLLING 12 MONTHS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) THE BOILERS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ABOVE EMISSIONS FOR EACH INDIVIDUAL BOILER (2). THESE BOILERS ARE OPERATED AS CONTROL FOR CO WHEN THE FLUID CATALYTIC CRACKING UNIT (FCCU) IS IN OPERATION. THE LIMITS ABOVE REPRESENT THE EMISSIONS FROM THESE BOILERS WHEN THE FCCU HAS A MALFUNCTION OR IS IN STARTUP/SHUTDOWN AND VENTED TO THE 2 BOILERS. THE BOILERS ALSO HAVE COMBINED EMISSION LIMITS SHARED WITH THE FCCU DURING NORMAL FCCU OPERATIONS, SEE THE FCCU PROCESS EMISSIONS. METHOD 10, IF REQUIRED.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 13.6000 LB/H Emission Limit 2: 59.5700 T/YR PER ROLLING 12 MONTHS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/AOther Applicable Requirements: SIP

Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ABOVE EMISSIONS FOR EACH INDIVIDUAL BOILER (2). THESE BOILERS ARE OPERATED AS CONTROL FOR CO WHEN THE FLUID CATALYTIC CRACKING UNIT (FCCU) IS IN OPERATION. THE LIMITS ABOVE REPRESENT THE EMISSIONS FROM THESE BOILERS WHEN THE FCCU HAS A MALFUNCTION OR IS IN STARTUP/SHUTDOWN AND VENTED TO THE 2 BOILERS. THE BOILERS ALSO HAVE COMBINED EMISSION LIMITS SHARED WITH THE FCCU DURING NORMAL FCCU OPERATIONS, SEE THE FCCU PROCESS EMISSIONS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.8300 LB/H Emission Limit 2: 8.0300 T/YR PER ROLLING 12 MONTHS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) THE BOILERS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ABOVE EMISSIONS FOR EACH INDIVIDUAL BOILER (2). THESE BOILERS ARE OPERATED AS CONTROL FOR CO WHEN THE FLUID CATALYTIC CRACKING UNIT (FCCU) IS IN OPERATION. THE LIMITS ABOVE REPRESENT THE EMISSIONS FROM THESE BOILERS WHEN THE FCCU HAS A MALFUNCTION OR IS IN STARTUP/SHUTDOWN AND VENTED TO THE 2 BOILERS. THE BOILERS ALSO HAVE COMBINED EMISSION LIMITS SHARED WITH THE FCCU DURING NORMAL FCCU OPERATIONS, SEE THE FCCU PROCESS EMISSIONS.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 20.0000 % OPACITY AS A 6-MINUTE AVERAGE, EXCEPT PER RULE Emission Limit 2:Emission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) THE BOILERS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THESE BOILERS ARE OPERATED AS CONTROL FOR CO WHEN THE FLUID CATALYTIC CRACKING UNIT (FCCU) IS IN OPERATION. THE OPACITY LIMIT FOR THE STACK OR ANY EMISSIONS POINT FROM THESE BOILERS DOES NOT CHANGE REGARDLESS OF THE FCCU OPERATIONS. EXCEPT AS PROVIDED BY OHIO RULE: MAY EXCEED 20% OPACITY, AS A 6-MINUTE AVERAGE, FOR NOT MORE THAN 6 CONSECUTIVE MINUTES IN ANY 60 MINUTES, BUT SHALL NOT EXCEED 60% OPACITY AS A 6-MINUTE AVERAGE AT ANY TIME.



## Process/Pollutant Information

PROCESS NAME: FLUIDIZED CATALYTIC CRACKING UNIT

Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: PETROLEUM Throughput: 84200.00 LB/H COKE BURN-OFF

Process Notes: FLUIDIZED CATALYTIC CRACKING UNIT (FCCU) WITH CAPACITY OF 100,000 BARRELS/DAY; W/ CO CONTROLLED BY TWO

BOILERS (WHICH SHARE EMISSIONS LIMITS WITH THE FCCU); AN SCR SYSTEM FOR NOX, AND A WET GAS SCRUBBER FOR SO2 AND PM CONTROL.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Mthd 201 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 331.9200 T/YR ROLLING 365-DAY SUM OF DAILY EMISSIONS Emission Limit 2: 0.9000 LB/1000 LB COKE POUND PER 1000 LB OF COKE BURNOFF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , SIPControl Method: (A) WET GAS SCRUBBER

Est. % Efficiency: 95.000 Compliance Verified: Unknown Pollutant/Compliance Notes: THESE LIMITS ARE SHARED WITH THE TWO BOILERS, I.E., THE T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. IF REQUIRED TESTING SHALL BE PERFORMED IN ACCORDANCE WITH METHODS 201 AND 202, PART 51.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: EPA/OAR Mthd 6 Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 316.0000 LB/H FROM FCCU AND 2 BOILERS TOGETHER Emission Limit 2: 345.7100 T/YR AS A ROLLING 365-DAY SUMMATION Standard Emission: 25.0000 PPMVD AT 0% O2, AS A ROLLING 365-DAY AVG.CONC. Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (A) WET GAS SCRUBBER Est. % Efficiency: 95.500 Compliance Verified: Yes Pollutant/Compliance Notes: THESE LIMITS ARE SHARED WITH THE TWO BOILERS CONTROLLING CO, I.E., THE LB/H AND T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. ADDITIONAL LIMIT FOR BOILERS AND FCCU: 50 PPMVD AT 0% O2 AS A 7-DAY ROLLING AVERAGE 100 PPMVD AT 0% O2 AS THE MAXIMUM SO2 CONCENTRATION 3 LB SO2/1000 LBS OF FRESH FEED, PER OAC RULE 3745-18-54(O)(3). CEM FOR SO2 AND COMPLIANCE SHALL BE DEMONSTRATED USING METHODS AND PROCEDURES IN 40 CFR 60.106(H) -SMALL H INITIAL COMPLIANCE TEST USING METHOD 6 OR 6C. MAXIMUM OF 100 PPMVD ON A DRY BASIS AT 7% O2 ANNUAL AVERAGE OF 25 PPMVD ON A DRY BASIS AT 7% O2

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Other Other Test Method: CEM FOR NOx Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 40.0000 PPMVD @ 0% O2 AS A 7-DAY ROLLING AVERAGE, AT 0%O2 Emission Limit 2: 198.5100 T/YR AS 365-DAY SUMMATION OF DAILY EMISSIONSStandard Emission: 20.0000 PPMVD @ 0% O2 AS A 365-DAY ROLLING AVERAGE AT 0% O2

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (A) SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: 80.000 Compliance Verified: Yes Pollutant/Compliance Notes: THESE LIMITS ARE SHARED WITH THE TWO BOILERS CONTROLLING CO, I.E., THE LB/H AND T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. THE PERMITTEE MAY MEET EITHER THE 7-DAY ROLLING AVERAGE OR THE 365-DAY ROLLING AVERAGE LIMIT ABOVE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25 Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.6700 LB/H Emission Limit 2: 16.0700 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THESE LIMITS ARE SHARED WITH THE TWO BOILERS CONTROLLING CO, I.E., THE LB/H AND T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. THE PERMITTEE HAS NETTED-OUT OF NONATTAINMENT NEW SOURCE REVIEW FOR VOC EMISSIONS. CAN USE METHOD 25 OR 25A.

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: EPA/OAR Mthd 8 Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 263.1100 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Emission Limit 2: 60.0700 LB/HStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Yes Pollutant/Compliance Notes: THESE LIMITS ARE SHARED WITH THE TWO BOILERS CONTROLLING CO, I.E., THE LB/H AND T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. This limit was originally set too low based on the manufacturer's recommendation. The limit was exceeded in a stack test and this limit has been adjusted to show compliance with the stack test.

POLLUTANT NAME: Particulate matter, filterable (FPM)

CAS Number: PM Test Method: Other Other Test Method: 40 CFR 60.106 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4500 LB/1000 LB PER 1000 POUNDS OF COKE BURNOFF Emission Limit 2: 165.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (A) WET GAS SCRUBBER Est. % Efficiency: 95.000 Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS SHARED WITH THE TWO BOILERS CONTROLLING CO, I.E., THE LB/H AND T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. IF REQUIRED, COMPLIANCE SHALL BE DEMONSTRATED USING METHODS AND PROCEDURES IN 40 CFR 60.106(A) AND (B) -SMALL A AND B

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Other Other Test Method: CEM FOR CO Pollutant Group(s): ( InOrganic Compounds )Pollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 180.0000 PPMVD@ 0% O2 AS ROLLING 365-DAY AVERAGE AT 0% O2 Emission Limit 2: 1087.2800 T/YR ROLLING 365-DAY SUM OF CO EMISSIONS Standard Emission: 500.0000 PPMVD@0% O2 AS A 1-HOUR AVERAGE, AT 0% O2 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , SIP Control Method: (A) TWO BOILERS BURNING, IN PART, THE FCCU WASTE GASES Est. % Efficiency: 99.000 Compliance Verified: Yes Pollutant/Compliance Notes: THESE LIMITS ARE SHARED WITH THE TWO BOILERS CONTROLLING CO, I.E., THE LB/H AND T/YR LIMITS ARE FOR THE FCCU AND TWO BOILERS TOGETHER. THE PERMITTEE MUST MEET ONE OF THE LIMITS ABOVE, I.E, AS A 1-HOUR AVERAGE, AS A ROLLING 365-DAY AVERAGE, OR AS ROLLING 365-DAY SUMMATION OF THE DAILY CO EMISSIONS. DEMONSTRATE INITIAL COMPLIANCE USING METHODS 1 THROUGH 4 AND 40 CFR 60.106(D) -LITTLE D.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 20.0000 % OPACITY AS A 6-MINUTE AVERAGE, EXCEPT PER RULE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (A) TWO BOILERS COMBUST FCCU GAS Est. % Efficiency: 95.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EXCEPT AS PROVIDED BY OHIO RULE: MAY EXCEED 20% OPACITY, AS A 6-MINUTE AVERAGE, FOR NOT MORE THAN 6 CONSECUTIVE MINUTES IN ANY 60 MINUTES, BUT SHALL NOT EXCEED 60% OPACITY AS A 6-MINUTE AVERAGE AT ANY TIME. VENTED TO THE BOILER CONTROLS.

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: EPA/OAR Cond. Test Mthd 027Test Method: EPA/OAR Cond. Test Mthd 027

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMV AMMONIA SLIP EMISSIONS Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: FROM SELECTIVE CATALYTIC REDUCTION CONTROL. IF REQUIRED SHALL DEMONSTRATE COMPLIANCE WITH CTM 027.



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNIT

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: CLAUS SULFUR RECOVERY UNIT AND SULFUR PIT WITH TAIL GAS UNIT AND INCINERATOR CONTROL. CONTINUOUS

MONITORING SYSTEM FOR SO2 THIS IS AN OLDER SRU AND IT HAS FEWER BAT LIMITS THAN DOES THE NEW SRU ALSO INCLUDED IN THE PERMIT. EACH SRU IS SUBJECT TO THE REQUIREMENTS OF PART 60 SUBPARTS A AND J, AND PART 63 SUBPARTS A AND UUU

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Other Other Test Method: METHOD IN 40 CFR 60.106 Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0700 LB/LB S LB SO2/LB OF SULFUR PROCESSED Emission Limit 2: 250.0000 PPMVD @ 0% AIR AS ROLLING 12-HR AVERAGE, 0% EXCESS AIR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: N/A

Other Applicable Requirements: NSPS , SIP Control Method: (A) TAIL GAS TREATMENT UNITS AND SRU INCINERATOR FOR H2S Est. % Efficiency: 97.000 Compliance Verified: Unknown Pollutant/Compliance Notes: CONTINUOUS EMISSION MONITOR FOR SO2. PPMVD LIMIT IS FROM PART 60, SUBPART J. MUST MAINTAIN PREVENTIVE MAINTENANCE AND MALFUNCTION PLAN.



## Process/Pollutant Information

PROCESS NAME: FLARE, STEAM ASSISTED

Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: PROCESS GASES Throughput: 155.44 MMBTU/H

Process Notes: FLARE, STEAM ASSISTED, TO CONTROL HYDROCARBON EMISSIONS FROM PROCESS VENTS. SUBJECT TO PART 63, SUBPART

CC AND PART 60, SUBPARTS A, J, AND GGG.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1600 LB/H Emission Limit 2: 5.0800 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 0.0074 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , NSPS , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5CAS Number: 7446-09-5

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 4.2000 LB/H Emission Limit 2: 18.4000 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 0.0100 GR/DSCF H2SO4 LIMIT FROM PART 60 SUBPART J Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE H2SO4 LIMIT FROM PART 60 SUBPART J WAS USED TO ESTABLISH AN SO2 EMISSION FACTOR OF 0.027 LB/MMBTU.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 12.8000 LB/H Emission Limit 2: 56.0700 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 0.0820 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 15.2300 LB/HEmission Limit 1: 15.2300 LB/H

Emission Limit 2: 66.7100 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8400 LB/H Emission Limit 2: 3.6800 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 5.5000 LB/MMSCF AP-42 FACTOR Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: MACT Other Applicable Requirements: NSPS , MACT , SIP Control Method: (A) FLARE IS CONTROL FOR HYDROCARBONS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITY NO VE EXCEPT FOR 5 MIN DURING ANY 2 HRS Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: MACT

Other Applicable Requirements: MACT , SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO VISIBLE EMISSIONS EXCEPT FOR PERIODS NOT TO EXCEED A TOTAL OF 5 MINUTES DURING ANY 2 CONSECUTIVE HOURS OF OPERATION, FROM PART 63, SUBPART A.



## Process/Pollutant Information

PROCESS NAME: WASTEWATER STREAMS

Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes: ALL WASTEWATER STREAMS, COOLING TOWERS, WASTEWATER TANKS, AND STORM WATER SYSTEMS IN THE REFINERY

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 91.1900 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: MACT Other Applicable Requirements: MACT , NSPS , SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: APPLICABLE REQUIREMENTS FROM: PART 60, SUBPART QQQ; PART 61, SUBPART FF; PART 63, SUBPART CC



## Process/Pollutant InformationPROCESS NAME: COOLING TOWER

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 2000.00 GAL/MIN

Process Notes: NON-CONTACT, INDUCED DRAFT, WITH DRIFT ELIMINATION

POLLUTANT NAME: Particulate matter, filterable (FPM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H Emission Limit 2: 0.5200 T/YR AS A ROLLING 12-MONTH SUMMATION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (A) DRIFT ELIMINATOR Est. % Efficiency: 75.000 Compliance Verified: Unknown Pollutant/Compliance Notes: REQUIREMENT TO TEST AND RECORD TDS CONTENT, IN PPM, OF THE COOLING WATER ONCE PER WEEK. TDS VALUE OF 2500 PPM, ASSUMING A DRIFT LOSS OF 0.005%, WAS USED TO CALCULATE THE PM 10 LIMIT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0840 LB/H Emission Limit 2: 0.3700 T/YR Standard Emission: 0.7000 LB/MM LBS PER MILLION GALLONS OF FLOW Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION FACTOR FROM AP-42, TABLE 5.1-2

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY AS A 6-MINUTE AVERAGE, EXCEPT PER RULE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNIT

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: REFINERY FUEL GAS Throughput: 17.00 MMBTU/H

Process Notes: CLAUS SULFUR RECOVERY UNIT AND SULFUR PIT WITH TAIL GAS UNIT AND INCINERATOR CONTROL. STACK GAS FLOW RATE

OF 4020 DSCFM OR 3899 DSCFM AT 0% O2. BURN NATURAL GAS OR REFINERY FUEL GAS ONLY CONTINUOUS MONITORING SYSTEM FOR SO2 EACH SRU IS SUBJECT TO THE REQUIREMENTS OF PART 60 SUBPARTS A AND J, AND PART 63 SUBPARTS A AND UUU

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: EPA/OAR Mthd 6 Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 9.8800 LB/H

Emission Limit 2: 43.2800 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 250.0000 PPMVD @ 0% AIR AS ROLLING 12-HR AVERAGE, 0% EXCESS AIR Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (A) TAIL GAS TREATMENT UNITS AND SRU INCINERATOR FOR H2S Est. % Efficiency: 97.000 Compliance Verified: Unknown Pollutant/Compliance Notes: CONTINUOUS EMISSION MONITOR FOR SO2 WITH WRITEN QUALITY ASSURANCE AND CONTROL PLAN FOR THE SO2 MONITORING SYSTEM. IF REQUIRED METHOD 6.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: EPA/OAR Mthd 201 Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.3600 LB/H Emission Limit 2: 5.9600 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 0.0800 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , NSPS , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: IF REQUIRED METHODS 5 FOR PM AND METHOD 201/202 FOR CONDENSABLE PM.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: EPA/OAR Mthd 7 Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.5500 LB/H Emission Limit 2: 11.1700 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 0.1500 LB/MMBTU MANUFACTURER'S RATINGDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: IF REQUIRED METHOD 7.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: EPA/OAR Mthd 25 Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8900 LB/H Emission Limit 2: 3.8900 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 60.0000 PPMVD AT 0% O2 Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , MACT , SIP Control Method: (A) TAIL GAS TREATER WITH 7 MMBTU/HR INCINERATOR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: IF REQUIRED METHOD 25.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: EPA/OAR Mthd 10 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.5900 LB/H Emission Limit 2: 11.3400 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: 0.1500 LB/MMBTU HEAT INPUT OF 7 MMBTU/HR INCINERATOR Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , SIP Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: IF REQUIRED METHOD 10.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY AS A 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Other Other Test Method: 40 CFR 60.106 Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 10.0000 PPMVD Emission Limit 2: 0.9500 T/YR BASED ON 365-DAY SUM OF DAILY EMISSIONS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (A) THERMAL OXIDIZER, 7 MMBTU/HR Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: IF REQUIRED COMPLIANCE SHALL BE DEMONSTRATED ACCORDING TO 40 CFR 60.106(F)(2) -Pollutant/Compliance Notes: IF REQUIRED COMPLIANCE SHALL BE DEMONSTRATED ACCORDING TO 40 CFR 60.106(F)(2) - LITTLE F.



## Process/Pollutant Information

PROCESS NAME: LEAK DETECTION AND REPAIR (LDAR) PROGRAM

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: FACILITY WIDE LEAK DETECTION AND REPAIR PROGRAM SUBJECT TO PART 63 SUBPART CC, PART 60 SUBPARTS VV AND

GGG.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 385.4300 T/YR PER ROLLING 12 MONTHS Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: MACT Other Applicable Requirements: NSPS , MACT , SIP Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SUBJECT TO PART 63, SUBPART CC AND PART 60 SUBPARTS VV AND GGG. IN ACCORDANCE WITH 63.648 THE UNIT IS INCLUDED IN A FACILITY-WIDE LEAK DETECTION AND REPAIR PROGRAM.



## Process/Pollutant Information

PROCESS NAME: PROPYLENE-PROPANE LOADING RACK Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: PROPANE/PROPYLENEPrimary Fuel: PROPANE/PROPYLENE

Throughput: 34224600.00 GAL/YR

Process Notes: RAILCAR LOADING, WITH 6 LOADING ARMS USING PRESSURIZED LOADING.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6000 T/YR PER ROLLING 12-MONTH PERIOD Emission Limit 2: 0.0935 LB/1000 GAL SUBMITTED EMISSION FACTOR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: MACT , SIP Control Method: (P) PRESSURIZED LOADING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SUBJECT TO PART 63 SUBPARTS A AND CC. BACK CALCULATED TO 34,224,599 GALLONS/YEAR (NOT PROVIDED)



## Facility Information

RBLC ID: 

## ID-0017 (final) Date Determination Last Updated: 02/05/2010 Corporate/Company Name: SOUTHEAST IDAHO ENERGY, LLC Permit Number: P-2008.0066

Facility Name: POWER COUNTY ADVANCED ENERGY CENTER Permit Date: 02/10/2009 (actual) Facility Contact: TOM HORNYAK 3039534297 T.HORNYAK@REHINC.COM FRS Number: UNKNOWN Facility Description: COAL/PETCOKE GASIFICATION PLANT PRODUCING AMMONIA, UREA, UAN, AND ELEMENTAL SULFUR. SIC Code: 2873

Permit Type: A: New/Greenfield Facility NAICS Code: 113210 Permit URL: EPA Region: 10 COUNTRY: USA Facility County: POWERFacility State: ID

Facility ZIP Code: 83211 Permit Issued By: IDAHO DEPT OF ENVIRONMENTAL QUALITY (Agency Name) MR. BILL ROGERS(Agency Contact) (208)373-0437 WILLIAM.ROGERS@DEQ.IDAHO.GOV Permit Notes: FACILITY LOCATION: LAMB WESTON ROAD, AMERICAN FALLS, IDAHO. DESIGNATED FACILITY (FUEL CONVERSION PLANT AND CHEMICAL PLANT). PSD THRESHOLD IS 100 T/YR. BACT REQ'D FOR PM, PM10, CO, AND NOX. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 WY Bridger 100km - 50km CLASS1 ID Craters of the Moon < 100 km CLASS1 WY Fitzpatrick 100km - 50km CLASS1 NV Jarbridge 100km - 50km CLASS1 MT Red Rock Lakes 100km - 50km CLASS1 ID Sawtooth 100km - 50km CLASS1 WY Teton 100km - 50km CLASS1 WY Washakie 100km - 50km CLASS1 WY Yellowstone NP 100km - 50km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 166.0000 (Tons/Year) Nitrogen Oxides (NOx) 109.0000 (Tons/Year) Particulate Matter (PM) 60.2000 (Tons/Year) Sulfur Oxides (SOx) 23.4000 (Tons/Year) Volatile Organic Compounds (VOC) 5.1000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: ZLDS COOLING TOWER, SRC30 Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 985.00 GAL/MIN

Process Notes: ZERO LIQUID DISCHARGE SYSTEM - COOLING WATER FLOW RATE 985 GPM. TDS MAX 50,000 MG/L.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0010 % OF TOTAL CIRC FLOW Emission Limit 2: 0.3000 LB/H Standard Emission: 20.0000 %Did factors, other then air pollution technology considerations influence the BACT decisions: Y

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT/MIST ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0010 % OF TOTAL CIRC FLOW Emission Limit 2: 0.3000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT/MIST ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COAL/PETCOKE RAILCAR UNLOADING & STORAGE, SRC01-SRC07

Process Type: 90.011 (Coal Handling/Processing/Preparation/Cleaning) Primary Fuel: Throughput: 5000.00 T/H

Process Notes: ENCLOSED RAILCAR UNLOADING AT NEGATIVE PRESSURE. COVERED CONVEYORS AND ENCLOSED TRANSFER POINTS.

STORAGE IN EUROSILO OR EQUIVALENT. HIGH EFFICIENCY BAGHOUSES (RAILCAR UNLOADING, CONVEYORS, STORAGE SILO VENTS).

POLLUTANT NAME: Particulate Matter (PM)POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.0009 GR/DSCF Standard Emission: 5.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) ENCLOSED RAILCAR UNLOADING AT NEGATIVE PRESSURE. COVERED CONVEYORS AND ENCLOSED TRANSFER POINTS. STORAGE IN EUROSILO OR EQUIVALENT. HIGH EFFICIENCY BAGHOUSES (RAILCAR UNLOADING, CONVEYORS, STORAGE SILO VENTS). Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: PMT LIMIT IS IN LB/H (APPROX. EQUIV TO GRAIN LOADING SHOWN AS EMISSION LIMIT 2). NSPS SUBPART Y: CURRENT OPACITY=20%, 2008 PROPOSED= 5%.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.0004 GR/DSCF Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) ENCLOSED RAILCAR UNLOADING AT NEGATIVE PRESSURE. COVERED CONVEYORS AND ENCLOSED TRANSFER POINTS. STORAGE IN EUROSILO OR EQUIVALENT. HIGH EFFICIENCY BAGHOUSES (RAILCAR UNLOADING, CONVEYORS, STORAGE SILO VENTS). Est. % Efficiency: 99.000 Compliance Verified: No Pollutant/Compliance Notes: PMT LIMIT IS IN LB/H (APPROX. EQUIV TO GRAIN LOADING SHOWN AS EMISSION LIMIT 2).

## Process/Pollutant Information

PROCESS NAME: COAL/PETCOKE RECLAIM TO ROD MILL, SRC08-SRC12 Process Type: 90.011 (Coal Handling/Processing/Preparation/Cleaning) Primary Fuel: Throughput: 105.00 T/H

Process Notes: COVERED CONVEYORS WITH ENCLOSED TRANSFER POINTS. CAPACITY IS 105 T/H FOR EACH CONVEYOR.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0020 LB/H Emission Limit 2: GR/DSCF SEE NOTE Standard Emission: 5.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) COVERED CONVEYORS WITH ENCLOSED TRANSFER POINTS. HIGH EFFICIENCY BAGHOUSES. Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: PMT LIMIT IS IN LB/H (APPROX EQUIV TO GRAIN LOADING SHOWN AS EMISSION LIMIT 2). NSPS SUBPART Y: CURRENT OPACITY=20%, 2008 PROPOSED= 5%.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0010 LB/H Emission Limit 2: GR/DSCF SEE NOTE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (B) COVERED CONVEYORS WITH ENCLOSED TRANSFER POINTS. HIGH EFFICIENCY BAGHOUSES.

Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: PMT LIMIT IS IN LB/H (APPROX EQUIV TO GRAIN LOADING SHOWN AS EMISSION LIMIT 2).



## Process/Pollutant Information

PROCESS NAME: FLUXANT TRUCK LDOUT & CONVEYING, FUG Process Type: 90.019 (Lime/Limestone Handling/Kilns/Storage/Manufacturing) Primary Fuel: Throughput: 250.00 T/H

Process Notes: GASIFIER FLUXANT VARIES, BUT MAY INCLUDE LIMESTONE, IRON ORE OR SAND.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 20.0000 % Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) COVERED CONVEYORS AND ENCLOSED TRANSFER POINTS. FUGITIVE DUST BMPS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) COVERED CONVEYORS AND ENCLOSED TRANSFER POINTS. FUGITIVE DUST BMPS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: FLUXANT STORAGE, SRCXX

Process Type: 90.019 (Lime/Limestone Handling/Kilns/Storage/Manufacturing) Primary Fuel: Throughput: 250.00 T/H

Process Notes: GASIFIER FLUXANT VARIES, BUT MAY INCLUDE LIMESTONE, IRON ORE, OR SAND. MAX FILL RATE PRESUMED TO BE 250 T/H.

MAX USE RATE IN GASIFIER IS 250 T/D.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0020 LB/H Emission Limit 2: LB/T SEE NOTE Standard Emission: 20.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) HIGH EFFICIENCY BAGHOUSE(S) ON STORAGE SILO VENT(S) Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: PMT LIMIT IS LB/H (EQUIVALENT LB/T LIMIT IS SHOWN AS EMISSION LIMIT 2), BASED ON 250 T/H FILL RATE.POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0020 LB/H Emission Limit 2: LB/T SEE NOTE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) HIGH EFFICIENCY BAGHOUSE(S) ON STORAGE SILO VENT(S) Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: PMT LIMIT IS LB/H (EQUIVALENT LB/T LIMIT IS SHOWN AS EMISSION LIMIT 2), BASED ON 250 T/H FILL RATE.



## Process/Pollutant Information

PROCESS NAME: SLAG HAND, FUG Process Type: 99.190 (Other Fugitive Dust Sources) Primary Fuel: Throughput: 580.00 T/D

Process Notes: GASIFIER SLAG IS WET WHEN CONVEYED TO STORAGE.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 20.0000 % Emission Limit 2: Standard Emission: % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N) STORAGE IN 3-SIDED BUNKER. FUGITIVE DUST BMPS.

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) STORAGE IN 3-SIDED BUNKER. FUGITIVE DUST BMPS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: LEAKS - SYNGAS PIPING OR VALVES, CO FUG Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: HIGH CO CONCENTRATION IN SYNGAS FROM GASIFIER TO FINAL CO-SHIFT REACTOR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) FUGITIVE CO BMPS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: ASU REGEN HEATER, 0.1 MMBTU/H, SRC13 Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NAT GAS Throughput: 0.10 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 20.0000 % Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: GASIFIER HEATERS (2), 25 MMBTU/H, SRC14 & SRC15

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NAT GAS Throughput: 25.00 MMBTU/H

Process Notes: BOTH HEATERS AT APPROX 25 MMBTU/H FOR STARTUP. NORMAL OPS ONE HEATER OFF, ONE ON STANDBY AT 9 MMBTU/H.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 20.0000 % Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTEEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAIILABLE



## Process/Pollutant Information

PROCESS NAME: GASIFIER FLARE, SRC16

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: SWEET SYNGAS Throughput: 900000.00 LB/H

Process Notes: FLARING DURING STARUP AND UPSETS. SYNGAS CLEANUP PRIOR TO FLARING - GASIFIER QUENCH, SOUR WATER SCRUB,

ACTIVATED CARBON BEDS (MIN 95% HG REMOVAL), AMINE SCRUB (MIN 95% S REMOVAL AS SO2). 1.5 MMBTU/HR NAT GAS PILOT.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLEPOLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCES SMOKE. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE. VE PER 40 CFR 60.18: NO VE AS DETERMINED BY METHOD 22, EXCEPT FOR TOTAL OF 5 MINS IN ANY 2-HR PERIOD. NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCES SMOKE. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon MonoxidePOLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FLARE DESIGNED TO MINIMIZE CO EMISSIONS. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: SELEXOL AGR CO2 VENT, SRC17 Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes: CO2-RICH STREAM FROM ACID GAS REMOVAL (AGR) UNIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.7000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) THERMAL OXIDIZER (CAT-OX)

Est. % Efficiency: 95.000 Compliance Verified: Yes Pollutant/Compliance Notes: TOTAL FLOW 299,585 LB/HR AT 28 F AND 44 PSIG. FLOW IS 98.89% CO2, 0.09% CO.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.9000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES FOR THERMAL OXIDIZER (CAT-OX) USED TO CONTROL CO EMISSIONS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS BASED ON 9 MMBTU/H NAT GAS BURNER ASSOCIATED WITH THE T.O/CAT-OX



## Process/Pollutant Information

PROCESS NAME: UREA GRANULATION VENT, SRC19 Process Type: 61.012 (Fertilizer Production (except 61.009)) Primary Fuel: Throughput: 1800.00 T/D

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0110 LB/TEmission Limit 2: 20.5000 LB/H

Standard Emission: 20.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) WET SCRUBBER IS INTEGRAL PART OF GRANULATION PROCESS, IS PROCESS EQUIPMENT. DESIGNED FOR MIN 98% CAPTURE AND RECYCLING OF PM/PM10. Est. % Efficiency: 98.000 Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 LB/T Emission Limit 2: 9.0000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) WET SCRUBBER IS INTEGRAL PART OF GRANULATION PROCESS, IS PROCESS EQUIPMENT. DESIGNED FOR MIN 98% CAPTURE AND RECYCLING OF PM/PM10. Est. % Efficiency: 98.000 Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NITRIC ACID PLANT TAILGAS, SRC20 Process Type: 62.014 (Nitric Acid Plants) Primary Fuel: Throughput: 575.00 T/D

Process Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 50.0000 PPMV Emission Limit 2: 1.1200 LB/T Standard Emission: 10.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) SCR, AMMONIA SLIP MAX 10 PPMV (DRY) CONVERTED TO 15% O2. Est. % Efficiency: 98.000 Compliance Verified: Yes Pollutant/Compliance Notes: AT 575 T/D OF 57% ACID, PMT LIMIT IS 15.3 LB/H - (100% ACID/57% ACID) X 15.3 X 24 LB/DAY/ 575 TPD = 1.12 LB/TON OF 100% ACID.



## Process/Pollutant Information

PROCESS NAME: PROCESS FLARE, SRC21

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: PROCESS & PURGE GASES Throughput:

Process Notes: PROCESS & PURGE GASES FROM 2000 T/D AMMONIA PLANT AND 2400 T/D UREA PLANT (LIQUID SOLUTION). 1.5 MMBTU/HR

NAT GAS PILOT.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: YCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCES SMOKE. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE. VE PER 40 CFR 60.18: NO VE AS DETERMINED BY METHOD 22, EXCEPT FOR TOTAL OF 5 MINS IN ANY 2-HR PERIOD. NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCESControl Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCES SMOKE. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER, SRC22 Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 121000.00 GAL/MIN

Process Notes: COOLING WATER FLOW RATE 121,000 GPM. TDS MAX 5000 MG/L.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0005 % OF TOTAL CIRC FLOWEmission Limit 2: 1.5000 LB/H

Standard Emission: 20.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT/MIST ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0005 % OF TOTAL CIRC FLOW Emission Limit 2: 1.5000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT/MIST ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 250 MMBTU/H PACKAGE BOILER, SRC24

Process Type: 12.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NAT GAS Throughput: 250.00 MMBTU/H

Process Notes: OPERATED ONLY DURING STARTUP AND SHUTDOWN, RAMPS DOWN/UP AS STEAM SUPERHEATER BOILER RAMPS UP/DOWN.

COMBINED HEAT INPUT BALANCEDPOLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0052 LB/MMBTU Emission Limit 2: 1.3000 LB/H Standard Emission: 20.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LB/MMBTU AND LB/H LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0052 LB/MMBTU Emission Limit 2: 1.3000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0740 LB/MMBTU Emission Limit 2: 18.5000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/MMBTU Emission Limit 2: 5.0000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) LOW-NOX BURNER AND FGR Est. % Efficiency: 95.000 Compliance Verified: No Pollutant/Compliance Notes: LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.



## Process/Pollutant Information

PROCESS NAME: 250 MMBTU/H STEAM SUPERHEATER BOILER, SRC31

Process Type: 12.300 (Gaseous Fuel & Gaseous Fuel Mixtures (>100 million BTU/H & ¿250 million Btu/H)) Primary Fuel: NAT GAS & PSA TAILGASThroughput: 250.00 MMBTU/H

Process Notes: OPERATED DURING STEADY-STATE PRODUCTION ON NATURAL GAS AND (HYDROGEN-RICH) PRESSURE SWING ADSORBER

(PSA) TAILGAS. BALANCED WITH PACKAGE BOILER AT STARTUP/SHUTDOWN SO COMBINED HEAT INPUT

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0052 LB/MMBTU Emission Limit 2: 1.3000 LB/H Standard Emission: 20.0000 % Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LB/MMBTU AND LB/H LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0052 LB/MMBTU Emission Limit 2: 1.3000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LB/MMBTU AND LB/H LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0740 LB/MMBTU Emission Limit 2: 18.5000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/MMBTU Emission Limit 2: 5.0000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) LOW-NOX BURNER & SCR, AMMONIA SLIP LIMITED TO 10 PPM (DRY) CORRECTED TO 15% O2. Est. % Efficiency: 97.000 Compliance Verified: No Pollutant/Compliance Notes: LIMITS APPLY TO PACKAGE BOILER AND STEAM SUPERHEATER COMBINED EMISSIONS.



## Process/Pollutant Information

PROCESS NAME: 2 MW EMERGENCY GENERATOR, SRC25PROCESS NAME: 2 MW EMERGENCY GENERATOR, SRC25

Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: ASTM #1, 2, DIESEL Throughput: 2000.00 KW

Process Notes: LIMITED TO 100 H/YR FOR ROUTINE TESTING AND MAINTENANCE

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NSPS Control Method: (P) ULSD FUEL, GOOD COMBUSTION PRACTICES, EPA CERTIFIED PER NSPS IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VE PER NSPS SUBPART IIII. NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULSD FUEL, GOOD COMBUSTION PRACTICES, EPA CERTIFIED PER NSPS IIII Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES. EPA CERTIFIED PER NSPS IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES. EPA CERTIFIED PER NSPS IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: 500 KW EMERGENCY GENERATOR, FIRE PUMP, SRC26

Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: ASTM #1, 2, DIESEL Throughput: 500.00 KW

Process Notes: LIMITED TO 100 H/YR FOR ROUTINE TESTING AND MAINTENANCE

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) ULSD FUEL, EPA CERTIFICATION PER NSPS IIII Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VE PER NSPS SUBPART IIII. NO EMISSION LIMITS AVAILABLE.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULSD FUEL, EPA CERTIFICATION PER NSPS IIII Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: NO EMISSION LIMITSAVAILABLE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES. EPA CERTIFICATION PER NSPS IIII. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION KLIMITS AVAILABLE.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES. EPA CERTIFICATION PER NSPS IIII. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant InformationPROCESS NAME: AMMONIA STORAGE FLARE, SRC27

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: AMMONIA Throughput:

Process Notes: 0.75 MMBTU/H NAT GAS PILOT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCES SMOKE. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SMOKELESS FLARE. AIR OR STEAM-ASSIST ONLY IF UNASSISTED FLARE PRODUCES SMOKE. GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18.Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: VE PER 40 CFR 60.18: NO VE AS DETERMINED BY METHOD 22, EXCEPT FOR TOTAL OF 5 MINS IN ANY 2-HR PERIOD. NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES. MEET 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

## Process/Pollutant Information

PROCESS NAME: AMMONIUM NITRATE NEUTRALIZER VENT, SRC29 Process Type: 61.012 (Fertilizer Production (except 61.009)) Primary Fuel: Throughput: 715.00 T/D

Process Notes: AMMONIUM NITRATE/UAN PLANT PRODUCTION ~715 TPD AMMONIUM NITRATE AND ~1600 TPD UAN

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5000 LB/H Emission Limit 2: 20.0000 % Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) WET SCRUBBER IS INTEGRAL TO PROCESS. MUST BE DESIGNED TO CAPTURE AND RECYCLE 90% OF PM/PM10. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) WET SCRUBBER IS INTEGRAL TO PROCESS. MUST BE DESIGNED TO CAPTURE AND RECYCLE 90% OF PM/PM10. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## OH-0330 (final) Date Determination Last Updated: 05/18/2010 Corporate/Company Name: RUMPKE SANITARY LANDFILL Permit Number: 07-00574

Facility Name: RUMPKE SANITARY LANDFILL Permit Date: 12/23/2008 (actual) Facility Contact: LEO SHANAYDA 5138510122 FRS Number: 110009610215 Facility Description: MUNICIPAL SOLID WASTE LANDFILL, MODIFICATION TO INCREASE THE CAPACITY AND TO ALLOW FOR THE DISPOSAL OF ASBESTOS CONTAINING WASTES. SIC Code: 4953

Permit Type: C: Modify process at existing facility NAICS Code: 562212 Permit URL: EPA Region: 5 COUNTRY: USA Facility County: BROWN Facility State: OH Facility ZIP Code: 45121 Permit Issued By: OHIO ENVIRONMENTAL PROTECTION AGENCY (Agency Name) MS. CHERYL SUTTMAN(Agency Contact) (614)644-3617 mailto:cheryl.suttman@epa.ohio.gov Permit Notes: Expansion of RUMPKE landfill and added requirement to implement an asbestos spill contingency plan. This existing landfill not previously entered into RBLC. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 361.0000 (Tons/Year) Nitrogen Oxides (NOx) 143.0000 (Tons/Year) Particulate Matter (PM) 29.0000 (Tons/Year) Sulfur Oxides (SOx) 29.0000 (Tons/Year) Volatile Organic Compounds (VOC) 15.0000 (Tons/Year)



## Process/Pollutant InformationPROCESS

NAME: MUNICIPAL WASTE LANDFILL

Process Type: 29.900 (Other Waste Processing & Disposal Processes) Primary Fuel: Throughput:

Process Notes: THE EXISTING LANDFILL IS NOT SUBJECT TO THE REQUIREMENTS OF NSPS SUBPART WWW BECAUSE THE 5-YEAR NMOC

EMISSION REPORT SUBMITTED ON 6/12/03 SHOWED NMOC EMISSIONS WELL BELOW 50 MG/YR. WHEN NMOC EMISSIONS ARE CALCULATED TO EQUAL OR EXCEED THE 50 MG LIMIT THE FACILITY WILL INSTALL LANDFILL WELLS THAT MEET THE REQUIREMENTS OF THE SUBPART.

POLLUTANT NAME: Methane

CAS Number: 74-82-8 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 75712.0000 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: 500.0000 PPM QUARTERLY SURFACE MONITORING Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (A) 4 ENCLOSED COMBUSTORS AND 5 CANDLESTICK FLARES; AND MAIN OPEN FLARE FOR EXISTING LANDFILL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS IS THE PERMITTED LIMIT THAT INCLUDES THE FUTURE EXPANSION.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 488.1400 T/YR NON-METHANE ORGANICS Emission Limit 2: 20.0000 PPMV DRY BASIS AS HEXANE, CORRECT TO 3% O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/ACase-by-Case Basis: N/A

Other Applicable Requirements: NSPS , SIP Control Method: (A) 4 ENCLOSED COMBUSTORS AND 5 CANDLESTICK FLARES; AND MAIN OPEN FLARE FOR EXISTING LANDFILL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS IS THE PERMITTED LIMIT THAT INCLUDES THE FUTURE EXPANSION, AND COMPLIANCE WITH THE REQUIREMENTS OF NSPS SUBPART WWW WHEN THE CALCULATED NMOC EMISSIONS EXCEEDES 50 MEGAGRAMS. THE NSPS WILL REQUIRE A CONTROL SYSTEM: EITHER AN OPEN FLARE; OR AN ENCLOSED COMBUSTOR THAT WILL REDUCE NMOC BY 98 WEIGHT PERCENT OR REDUCE THE OUTLET NMOC TO LESS THAN 20 PPMV ON A DRY BASIS AS HEXANE, CORRECT TO 3% O2.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 37.0200 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) 4 ENCLOSED COMBUSTORS AND 5 CANDLESTICK FLARES; AND MAIN OPEN FLARE FOR EXISTING LANDFILL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS IS THE PERMITTED LIMIT THAT INCLUDES THE FUTURE EXPANSION.

POLLUTANT NAME: Particulate matter, filterable (FPM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1700 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, total < 10 μ (TPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0800 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Fluorides, Total

CAS Number: 16984-48-8 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 22.8400 T/YR EXCLUDING HYDROGEN FLORIDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: THIS IS THE PERMITTED LIMIT THAT INCLUDES THE FUTURE EXPANSION

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 11.5800 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: OHIO REQUIRES ANY LANDFILL THAT ACCEPTS CONSTRUCTION AND DEMOLITION DEBRIS TO DEVELOP AND IMPLEMENT A CONTIGENCY PLAN FOR EFFECTIVE ACTION IN RESPONSE TO HYDROGEN SULFIDE. IF REQUESTED BY THE OHIO EPA, RUMPKE WILL DEVELOP SUCH A PLAN AS A CONDITION OF THIS PERMIT.

POLLUTANT NAME: Dichlorodifluoromethane

CAS Number: 75-71-8 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 18.2600 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: CFC-12 ADDITIONAL LIMIT: FLUOROTRICHLOROMETHANE (CFC-11) 0.99 T/YR

POLLUTANT NAME: Hazardous Air Pollutants (HAP)

CAS Number: HAP Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) ) Emission Limit 1: 95.0800 T/YR FROM EXISTING LF AND FUTURE EXPANSION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: MACT , SIP Control Method: (A) 4 ENCLOSED COMBUSTORS AND 5 CANDLESTICK FLARES; AND MAIN OPEN FLARE FOR EXISTING LANDFILL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SUBJECT TO PART 63, SUBPART AAAA.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: EPA/OAR Mthd 9 Pollutant Group(s): Emission Limit 1: 20.0000 % OPACITY AS A 3-MINUTE AVERAGE Emission Limit 2: % OPACITY NO VE FROM ASBESTOS-CONTAINING MATERIALS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP , SIP Control Method: (P) WATERING OR OTHER APPROPRIATE CONTROL WHEN VISIBLE EMISSIONS EXCEED LIMIT. COMPLIANCE WITH NESHAP AND SIP FOR HANDLING OF ASBESTOS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: WILL USE BEST AVAILABLE CONTROL MEASURES TO MINIMIZE OR ELIMINATE FUGITIVE DUST EMISSIONS. IF REQUIRED METHOD 9.POLLUTANT NAME: Asbestos

CAS Number: 1332-21-4 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: NESHAP , SIP Control Method: (P) WORK PRACTICES PER RULE AND ASBESTOD DISPOSAL OPERATING PROCEDURE AND SPILL CONTIGENCY PLAN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO VISIBLE EMISSIONS OF ASBESTOS-CONTAINING WASTE MATERIALS AND PROPER HANDLING PER RULES.



## Process/Pollutant Information

PROCESS NAME: ENCLOSED COMBUSTORS (4) Process Type: 29.900 (Other Waste Processing & Disposal Processes) Primary Fuel: LANDFILL GAS Throughput:

Process Notes:

POLLUTANT NAME: Methane

CAS Number: 74-82-8 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 299.0100 LB/H Emission Limit 2: 1309.6600 T/YR FROM EXISTING LF AND FUTURE EXPANSION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/AOther Applicable Requirements: NSPS

Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CALCULATED FROM EMISSION FACTORS FROM USEPA'S LANDFILL GAS EMISSIONS MODEL AND AP-42 SECTION 2.4

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.9300 LB/H NON-METHANE ORGANICS Emission Limit 2: 8.4400 T/YR NON-METHANE ORGANICS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP , NSPS Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS INCLUDES THE FUTURE EXPANSION

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 5.5000 LB/H Emission Limit 2: 24.0900 T/YR FROM EXISTING LF AND FUTURE EXPANSION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes: H2S EMISSIONS ARE ASSUMED TO BE COMPLETELY CONVERTED TO SO2 DURING COMBUSTION OF LANDFILL GAS

POLLUTANT NAME: Hydrochloric Acid

CAS Number: 7647-01-0 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 8.6000 LB/H Emission Limit 2: 37.6800 T/YR FROM EXISTING LF AND FUTURE EXPANSION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) COMBUTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Fluoride

CAS Number: 7664-39-3 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.4200 LB/H Emission Limit 2: 6.2000 T/YR FROM EXISTING LF AND FUTURE EXPANSION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Dichlorodifluoromethane

CAS Number: 75-71-8 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0720 LB/H CFC-12 Emission Limit 2: 0.3200 T/YR FROM EXISTING LF AND FUTURE EXPANSION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT: FLUOROTRICHLOROMETHANE (CFC-11) SHALL NOT EXCEED 0.0039 LB/H AND 0.017 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 79.9000 LB/H Emission Limit 2: 350.0000 T/YR FROM EXISTING LF AND FUTURE EXPANSION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 6.1000 LB/H Emission Limit 2: 26.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 21.7800 LB/H Emission Limit 2: 95.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) COMBUSTORS ARE THE CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CANDLESTICK FLARE (5) Process Type: 29.900 (Other Waste Processing & Disposal Processes) Primary Fuel: LANDFILL GAS Throughput:

Process Notes:Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5100 LB/H Emission Limit 2: 2.2300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.2000 LB/H Emission Limit 2: 5.2600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.4700 LB/H Emission Limit 2: 2.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 22.5000 LB/H Emission Limit 2: 98.5500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Methane

CAS Number: 74-82-8 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 25.0000 LB/H Emission Limit 2: 109.4500 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1600 LB/H NON-METHANE ORGANICS Emission Limit 2: 0.7100 T/YR NON-METHANE ORGANICS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: OPEN FLARE

Process Type: 29.900 (Other Waste Processing & Disposal Processes) Primary Fuel: LANDFILL GAS Throughput:

Process Notes: MAIN FLARE FOR CONTROL OF LANDFILL GAS AND ODORS FROM EXISTING LANDFILL, NOT SUBJECT TO THE CONTROL

REQUIREMENTS OF THE NSPS, SUBPART WWW, BECAUSE NON-METHANE ORANIC COMPOUND EMISSIONS ARE CALCULATED TO BE LESS THAN 50 MEGAGRAMS/YR.POLLUTANT NAME: Methane

CAS Number: 74-82-8 Test Method: Unspecified Pollutant Group(s): ( Greenhouse Gasses (GHG) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 25.0000 LB/H Emission Limit 2: 109.4500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1600 LB/H NON-METHANE ORGANICS Emission Limit 2: 0.7100 T/YR NON-METHANE ORGANICS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 0.4700 LB/H Emission Limit 2: 2.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 22.5000 LB/H Emission Limit 2: 98.5500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5100 LB/H Emission Limit 2: 2.2300 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.2000 LB/H Emission Limit 2: 5.2600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FLARE IS CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PAVED ROADWAYS AND PARKING AREAS

Process Type: 99.150 (Unpaved Roads) Primary Fuel: Throughput:

Process Notes: INCLUDES BOTH PAVED AND UNPAVED ROADS AND PARKING AREAS, TON PER YEAR EMISSION ESTIMATES/LIMITS ARE

PERMITTED TOGETHER.

POLLUTANT NAME: Particulate matter, filterable (FPM)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 58.0000 T/YR PAVED AND UNPAVED ROADS/PARKING Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (P) BEST AVAILABLE CONTROL MEASURES TO MINIMIZE OR PREVENT EMISSIONS, INCLUDING WATER FLUSHING AND SWEEPING OF PAVED ROADS/PARKING AREAS; AND APPLYING WATER OR OTHER DUST SUPPRESSANT TO UNPAVED ROADS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 15.1000 T/YR PAVED AND UNPAVED ROADS/PARKING Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (P) BEST AVAILABLE CONTROL MEASURES TO MINIMIZE OR PREVENT EMISSIONS, INCLUDING WATER FLUSHING AND SWEEPING OF PAVED ROADS/PARKING AREAS; AND APPLYING WATER OR OTHER DUST SUPPRESSANT TO UNPAVED ROADS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VETest Method: EPA/OAR Mthd 9

Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY AS A 3 MINUTE AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (P) BEST AVAILABLE CONTROL MEASURES TO MINIMIZE OR PREVENT VISIBLE EMISSIONS, INCLUDING WATER FLUSHING AND SWEEPING OF PAVED ROADS/PARKING AREAS; AND APPLYING WATER OR OTHER DUST SUPPRESSANT TO UNPAVED ROADS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: IF REQUIRED METHOD 9.



## Facility Information

RBLC ID: 

## NM-0050 (final) Date Determination Last Updated: 08/01/2008 Corporate/Company Name: NAVAJO REFINING COMPANY LLC Permit Number: PSD-NM-195-M25 Facility Name: ARTESIA REFINERY Permit Date: 12/14/2007 (actual) Facility Contact: DOUG PRICE 5057465294 DOUG.PRICE@HOLLYCORP.COM FRS Number: 110012882586 Facility Description: 115,000 - 125,000 BBL/DAY NOMINALLY RATED PETROLEUM REFINERY. SIC Code: 2911 Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110

Permit URL: EPA Region: 6 COUNTRY: USA Facility County: EDDY Facility State: NM Facility ZIP Code: 882110159 Permit Issued By: NEW MEXICO ENVIRONMENT DEPT/APC BUREAU (Agency Name) MR. TED SCHOOLEY(Agency Contact) (505) 476-4300 Other Agency Contact Info: MICHAEL SCHNEIDER AIR PERMITTING SPECIALIST (505) 476-4323 Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase:Carbon Monoxide 1136.1400 (Tons/Year) Nitrogen Oxides (NOx) 673.1400 (Tons/Year) Particulate Matter (PM) 198.9700 (Tons/Year) Sulfur Oxides (SOx) 342.1000 (Tons/Year) Volatile Organic Compounds (VOC) 1491.8900 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: STEAM METHANE REFORMER HEATER Process Type: 11.300 (Gaseous Fuel & Gaseous Fuel Mixtures (>250 million BTU/H)) Primary Fuel: NATURAL GAS AND REFORMER OFF-GAS Throughput: 337.00 MMBTU/H

Process Notes: ALSO CAPABLE OF BURNING REFORMER OFF-GAS

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.0000 PPMV (WET) 3-HOUR ROLLING AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: AMMONIA SLIP EMISSIONS ARE EXPECTED OVER TIME FROM THE SCR SYSTEM USED TO CONTROL NOX.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0600 LB/MMBTU 3-HOUR ROLLING AVERAGEEmission Limit 2: 20.2200 LB/H 3-HOUR ROLLING AVERAGE

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU HOURLY Emission Limit 2: 1.6900 LB/H HOURLY Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HOUR ROLLING AVERAGE @3% O2 Emission Limit 2: 4.2100 LB/H 3-HOUR ROLLING AVERAGE @ 3% O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) SELECTIVE CATALYTIC REDUCTION ("SCR") Est. % Efficiency: 70.000 Compliance Verified: Unknown Pollutant/Compliance Notes: COST EFFECTIVENESS USES AN UNCONTROLLED BASE CASE OF 0.14 LB/MMBTU NOX INCREMENTAL COST EFFECTIVENESS USES A BASELINE EMISSION RATE OF 0.04 LB/MMBTU NOX AS THIS VALUE REFLECTED A REALISTIC UPPER BOUNDARY OF ULNB NOX EMISSIONS AT THE TIME OF REVIEW.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.4940 LB/H Emission Limit 2: 2.1600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) PIPELINE QUALITY NATURAL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE SULFUR LEVEL IN THE NATURAL GAS IS NOT EXPECTED TO EXCEED 0.05 (5) GRAINS OF SULFUR PER 100 DRY STANDARD CUBIC FEET OF GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU HOURLY Emission Limit 2: 2.5200 LB/H HOURLY Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (P) GASEOUS FUEL COMBUSTION ONLY

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ROSE 2 HOT OIL HEATER Process Type: 12.300 (Gaseous Fuel & Gaseous Fuel Mixtures (>100 million BTU/H & ¿250 million Btu/H)) Primary Fuel: REFINERY FUEL GAS Throughput: 120.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 60.0000 PPMV 365-DAY ROLLING AVERAGE Emission Limit 2: 160.0000 PPMV HOURLY MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) REFINERY FUEL GAS SULFUR REMOVAL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3-HOUR ROLLING AVERAGE @ 3% O2Emission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0600 LB/MMBTU 3-HOUR ROLLING AVERAGE @ 3% O2 Emission Limit 2: 7.2000 LB/H 3-HOUR ROLLING AVERAGE @ 3%O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU HOURLY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) GASEOUS FUEL COMBUSTION ONLY. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU HOURLY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROCRACKER FRACTIONATOR FURNACE Process Type: 13.300 (Gaseous Fuel & Gaseous Fuel Mixtures (¿100 million BTU/H)) Primary Fuel: REFINERY FUEL GAS Throughput: 9.60 MMBTU/H

Process Notes: THERE ARE TWO IDENTICAL UNITS

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 60.0000 PPMV 365-DAY ROLLING AVERAGEEmission Limit 2: 160.0000 PPMV HOURLY MAXIMUM

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) REFINERY FUEL GAS SULFUR CLEANING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU HOURLY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3-HOUR ROLLING AVERAGE @ 3% O2 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0900 LB/MMBTU 3-HOUR ROLLING AVERAGE @ 3% O2 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU HOURLY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROCRACKER REBOILER Process Type: 13.300 (Gaseous Fuel & Gaseous Fuel Mixtures (¿100 million BTU/H)) Primary Fuel: REFINERY FUEL GAS Throughput: 35.00 MMBTU/H

Process Notes: THERE ARE TWO IDENTICAL UNITS REPRESENTED BY THIS ENTRY

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 60.0000 PPMV 365-DAY ROLLING AVERAGE Emission Limit 2: 160.0000 PPMV HOURLY MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) REFINERY FUEL GAS SULFUR REMOVAL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3-HOUR ROLLING AVERAGE @ 3% O2 Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0900 LB/MMBTU 3 HOUR ROLLING AVERAGE @ 3% O2 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU HOURLY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLYEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU HOURLY Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY HOT OIL HEATER Process Type: 13.300 (Gaseous Fuel & Gaseous Fuel Mixtures (¿100 million BTU/H)) Primary Fuel: REFINERY FUEL GAS Throughput: 9.60 MMBTU

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 60.0000 PPMV 365-DAY ROLLING AVERAGE Emission Limit 2: 160.0000 PPMV HOURLY MAXIMUM Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) REFINERY FUEL GAS SULFUR REMOVAL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3 HOUR AVERAGE @ 3% O2 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (P) GOOD COMBUSTION PRACTICES

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNIT NO. 3 (SRU-3) Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput: 100.00 LTPD

Process Notes: THIS SULFUR RECOVERY UNIT IS EQUIPPED WITH ITS OWN TAIL GAS INCINERATOR.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 192.0000 PPMVD 12 HOUR ROLLING AVERAGE @ 0% O2 Emission Limit 2: 192.0000 PPMVD 365 DAY ROLLING AVERAGE @ 0% O2 Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) TAIL GAS INCINERATOR Est. % Efficiency: 99.800 Compliance Verified: Unknown Pollutant/Compliance Notes: APPLICABLE BACT WORK PRACTICES AND EQUIPMENT (SRU3/TGTU3/TGI3): ¿ MAINTAIN AT LEAST 98% SRP ON-STREAM OPERATIONS. THIS INCLUDES CURTAILING REFINERY OPERATIONS AS NECESSARY WHEN SRU CAPACITY IS LIMITED DURING PLANNED STARTUP, SHUTDOWN, AND MAINTENANCE EVENTS. ¿ CONSTRUCT A 20,000 BARREL SOUR WATER STORAGE TANK IN ADDITION TO THE EXISTING 10,000 BARREL TANK. ¿ MAINTAIN ADEQUATE SRP EXCESS CAPACITY TO REDUCE THE FREQUENCY AND QUANTITY OF REFINERY EXCESS SO2 EMISSIONS. AFTER THE REFINERY EXPANSION PROJECT PROPOSED UNITS ARE CONSTRUCTED, THE PROPOSED SRU3 WILL PROVIDE AT LEAST 25% EXCESS CAPACITY. ¿ MAINTAIN AND USE A SULFUR SHEDDING PLAN TO PREVENT OR REDUCE ACID GAS FLARING EVENTS FROM REFINERY UPSETS. AN ACID GAS FLARING EVENT IS DEFINED AS EXCESS SO2 EMISSIONS GREATER THAN 500 POUNDS IN A 24-HOUR PERIOD. THE PLAN SHALL STATEEMISSIONS GREATER THAN 500 POUNDS IN A 24-HOUR PERIOD. THE PLAN SHALL STATE SPECIFIC ACTIONS THAT MAY BE TAKEN TO REDUCE OR PREVENT ACID GAS FLARING. THE ACTIONS TAKEN DURING ANY EVENT WILL BE BASED ON THE REFINERY OPERATORS¿ DISCRETION, CONSIDERING SAFETY AND OTHER FACTORS RELATED TO PRUDENT OPERATION. THIS PLAN IS SUBJECT TO REVIEW BY NMED OR EPA, AND SHALL BE AMENDED UPON WRITTEN REQUEST BY NMED OR EPA. THE SULFUR SHEDDING PLAN MAY INCLUDED, BUT IS NOT LIMITED TO THE FOLLOWING OPTIONS: A. STORE SOUR WATER TO REDUCE ACID GAS GENERATION FROM THE SOUR WATER STRIPPERS B. REDUCE THE OPERATING RATE OF ONE OR MORE AMINE STRIPPERS TO LOWER THE ACID GAS GENERATION RATE C. REDUCE ONE OR MORE HYDROTREATING UNIT THROUGHPUT RATES TO LOWER ACID GAS GENERATION RATE. ¿ USE HYDROGEN, WHEN AVAILABLE, AS SRU FUEL DURING STARTUP AND HOT STANDBY TO MINIMIZE CARBON DEPOSITS ON THE SRU CATALYSTS. ¿ DURING STARTUP AND SHUTDOWN PROCESS VESSELS SHALL BE DEPRESSURIZED INTO OTHER PROCESS EQUIPMENT RATHER THAN VENTING TO A FLARE. THE PERMITTEE SHALL DOCUMENT INSTANCES WHEN THIS IS NOT PRACTICABLE.



## Process/Pollutant Information

PROCESS NAME: FUGITIVE EQUIPMENT COMPONENTS Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: NOT APPLICABLE Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: 95.000 Compliance Verified: UnknownPollutant/Compliance Notes: ALL FUGITIVE PIPING COMPONENTS IN VOC SERVICE ASSOCIATED WITH THE PROPOSED PROCESS UNITS SHALL BE MONITORED UNDER THE MACT SUBPART CC LEAK DETECTION AND REPAIR PROGRAM, OR AN APPROVED EQUIVALENT PROGRAM, TO REDUCE VOC EMISSIO



## Process/Pollutant Information

PROCESS NAME: TRUCK LOADING RACK Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.0000 MG/L Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (A) CARBON ADSORPTION SYSTEM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: COMPLIANT WITH MACT SUBPART(S) R AND CC



## Process/Pollutant Information

PROCESS NAME: STORAGE TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: NAPTHA Throughput: 100000.00 BBL

Process Notes: NAPTHA STORAGE TANKProcess Notes: NAPTHA STORAGE TANK

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) EXTERNAL FLOATING ROOF TANK EQUIPPED WITH DOUBLE SEALS . Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOT AUTHORIZED TO STORE HYDROCARBON LIQUID HAVING A VAPOR PRESSURE GREATER THAN 11.0 PSI. NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: SOUR WATER TANK Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput: 20000.00 BBL

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: NSPS Control Method: (A) EXTERNAL FLOATING ROOF EQUIPPED WITH DOUBLE SEALS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: OIL WATER SEPARATOR Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) CARBON CANISTER Est. % Efficiency: 90.000 Compliance Verified: Unknown Pollutant/Compliance Notes: NO SEMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: EAST CRUDE EXPANSION FLAREProcess Type: 19.330 (Refinery Flares)

Primary Fuel: HYDROGEN AND NATURAL GAS Throughput: 7.50 MMBTU/H

Process Notes: ¿THE FLARE SHALL BE USED ONLY FOR CONTROLLING STARTUP, SHUTDOWN, MAINTENANCE, OR MALFUNCTION EMISSIONS

AND IS NOT AUTHORIZED FOR CONTROLLING ROUTINE PROCESS VENTS. EMISSIONS FROM THE FLARE WILL OCCUR DURING HYDROGEN, PILOT AND PURGE GAS FLARING.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.5400 LB/H Emission Limit 2: 2.3800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: FLARE WILL COMPLY WITH 40 CFR 60.18 CONTROL DEVICE REQUIREMENTS. EMISSION RATES ARE AS FOLLOWS:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2000 LB/H Emission Limit 2: 0.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Facility Information

RBLC ID: 

## IA-0089 (final) Date Determination Last Updated: 07/21/2008 Corporate/Company Name: HOMELAND ENERGY SOLUTIONS, LLC, PN 06-672 Permit Number: 07-A-955P TO

07-A-982P Facility Name: HOMELAND ENERGY SOLUTIONS, LLC, PN 06-672 Permit Date: 08/08/2007 (actual) Facility Contact: KEVIN HOWES 563-238-5555 KHOWES@ETOH.US FRS Number: 110031117716 Facility Description: 170 MILLION GALLON PER ROLLING 12-MONTH PERIOD DRY MILL ETHANOL PLANT. THE

PROCESS WILL USE GASIFICATION TECHNOLOGY TO PRODUCE SYNGAS AS THE SOURCE FOR ENERGY. WILL USE 60,714,286 BUSHELS OF CORN PER ROLLING 12-MONTH PERIOD PRODUCING EITHER 1.411 MILLION TONS OF WDGS OR 552,500 TONS OF DDGS PER ROLLING 12-MONTH PERIOD. THE GASIFICATION PROCESS COULD USE UP TO 298, 213 TONS OF COAL PER ROLLING 12-MONTH PERIOD. PROJECT NUMBER (PN) 06-672, 28 PERMITS ISSUED SIC Code: 2869

Permit Type: A: New/Greenfield Facility NAICS Code: 325193 Permit URL: EPA Region: 7 COUNTRY: USA Facility County: CHICKASAW Facility State: IA Facility ZIP Code: 50659 Permit Issued By: IOWA DEPARTMENT OF NATURAL RESOURCES AIR QUALITY (Agency Name)

MR. GARY SMITH(Agency Contact) (515) 281-4635 GARY.SMITH@DNR.IOWA.GOV Other Agency Contact Info: AARON SCHMIDT, ENVIRONMENTAL ENGINEER (REVIEW ENGINEER) (515) 281-4897 OR AARON.SCHMIDT@DNR.STATE.IA.US PROJECT NUMBER 06-672 FOR 28 ISSUED PERMITS Permit Notes: THIS PERMIT IF FOR THE GASIFICATION SYSTEM AND THE PRE-TREATMENT CONTROL ITEMS (ACTIVATED CARBON BED

FOR MERCURY REMOVAL AND H2S REMOVAL SYSTEM) AND THE TREATMENT OF EXHAUST GASES USING RECUPERATIVE THERMAL OXIDIZERS OF 150 MM BTU / HR WITH LOW NOX BURNERS. THE SYSTEM CONTROLS EMISSIONS FROM THE DRYERS AND COOLING SYSTEMF FOR THE DDGS. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 221.0800 (Tons/Year) Nitrogen Oxides (NOx) 96.2500 (Tons/Year) Particulate Matter (PM) 151.0400 (Tons/Year) Sulfur Oxides (SOx) 75.2300 (Tons/Year) Volatile Organic Compounds (VOC) 74.4900 (Tons/Year)

## Process/Pollutant Information

PROCESS NAME: THERMAL OXIDIZER FOR HRSG FROM DRYERS AND GASIFICATION - TWO SYSTEMS, S10 AND S11 (07-A-955P AND 07-A-956P)

Process Type: 12.300 (Gaseous Fuel & Gaseous Fuel Mixtures (>100 million BTU/H & ¿250 million Btu/H)) Primary Fuel: SYNGAS Throughput: 250.00 MMBTU/H

Process Notes: THE THERMAL OXIDIZER IS 150 MM BTU / HR AND EACH DRYER (TWO TOTAL FOR THIS EMISSION POINT) IS 50 MM BTU / HR.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/MMBTU BACT Emission Limit 2: 0.0300 LB/MMBTU SUBPART DB Standard Emission: 0.1000 GR/DSCF 23.3(2) Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OTHER Control Method: (N) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/MMBTU BACT Emission Limit 2: 0.0300 LB/MMBTU NSPS Standard Emission: 0.1000 GR/DSCF 23.3(2) Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OTHER , NSPSControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0340 LB/MMBTU 30-DAY ROLLING, BACT OVERALL SO2 Emission Limit 2: 0.0140 LB/MMBTU 30-DAY ROLLING AVERAGE, BACT FOR SYN GAS Standard Emission: 0.2000 LB/MMBTU 30-DAY ROLLING, NSPS Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OTHER Control Method: (P) H2S REMOVAL SYSTEM AFTER THE GASIFICATION PROCESS AND PRIOR TO THE USE IN THE DRYERS OR THERMAL OXIDIZERS Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: FOR THE SYN-GAS MADE FROM COAL, THE SO2 IS LIMITED TO 0.014 LB / MM BTU AND THE SO2 FROM THE PROCESS IS LIMITED TO 0.02 LB / MM BTU EACH BASED ON 250 MM BTU / HR HEAT INPUT.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/MMBTU 30 DAY ROLLING AVERAGE, BACT Emission Limit 2: 0.2000 LB/MMBTU 30-DAY ROLLING AVERAGE, NSPS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) LOW NOX BURNERS Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0060 LB/MMBTU Emission Limit 2: 98.0000 % REDUCTION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: THE FACILITY SHALL MEET EITHER THE 0.006 LB / MM BTU HEAT INPUT OR 98% REDUCTION.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0860 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)CAS Number: VE

Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % SIX MINUTE AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Formaldehyde

CAS Number: 50-00-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0740 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITING THE POTENTIAL TO EMIT OF THE POLLUTANT SO THE FACILTIY CAN REMAIN A SYNTHETIC MINOR FOR NESHAP / MACT CATEGORY.

POLLUTANT NAME: Methanol

CAS Number: 67-56-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) )Emission Limit 1: 0.2480 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT ESTABLISHED FOR FACILITY TO STAY SYNTHETIC MINOR FOR NESHAP / MACT APPLICABLILITY

POLLUTANT NAME: Mercury

CAS Number: 7439-97-6 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Heavy Metals , InOrganic Compounds ) Emission Limit 1: 0.0094 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT ESTABLISHED FOR FACILITY TO STAY SYNTHETIC MINOR FOR NESHAP / MACT APPLICABLILITY

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 1.6000 LB/H Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT ESTABLISHED FOR FACILITY TO STAY SYNTHETIC MINOR FOR NESHAP / MACT APPLICABLILITY

POLLUTANT NAME: Acetaldehyde

CAS Number: 75-07-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1850 LB/H ACETALDEHYDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT ESTABLISHED FOR FACILITY TO STAY SYNTHETIC MINOR FOR NESHAP / MACT APPLICABLILITY

POLLUTANT NAME: Acrolein

CAS Number: 107-02-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2500 LB/H ACROLEIN Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-CaseOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT ESTABLISHED FOR FACILITY TO STAY SYNTHETIC MINOR FOR NESHAP / MACT APPLICABLILITY

POLLUTANT NAME: Hazardous Air Pollutants (HAP)

CAS Number: HAP Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) ) Emission Limit 1: 1.6600 LB/H TOTAL HAP Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT ESTABLISHED FOR FACILITY TO STAY SYNTHETIC MINOR FOR NESHAP / MACT APPLICABLILITY



## Process/Pollutant Information

PROCESS NAME: BIOMETHANATOR FLARE, EP11 (07-A-957P)

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: METHANE / SYNGAS / NATURAL GAS Throughput: 6.40 MM BTU / H

Process Notes: USED TO CONTORL METHANATOR ODORS AND ONLY USED WHEN DRYERS AND THERMAL OXIDIZERS ARE NOT OPERATING.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0019 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0019 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % SIX-MINUTE AVERAGE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0007 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 98.0000 % Emission Limit 2: 0.0520 LB/MMBTU Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: COAL RECEIVING AND HANDLING, S12 (07-A-958P) Process Type: 90.011 (Coal Handling/Processing/Preparation/Cleaning) Primary Fuel: Throughput: 200.00 T/H

Process Notes: THIS IS THE UNLOADING AND STORAGE OF COAL AT THE FACILITY.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE AND WATER FOGGING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE BAGHOUSE IS USED TO CONTROL THE STORAGE BINS AND THE WATER FOGGING IS USED TO ELIMINATE THE PARTICULATE AT THE UNLOADING AREA.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) BAGHOUSE WATER FOGGING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE BAGHOUSE IS USED TO CONTROL THE STORAGE BINS AND THE WATER FOGGING IS USED TO ELIMINATE THE PARTICULATE AT THE UNLOADING AREA.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE AND WATER FOGGING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE BAGHOUSE IS USED TO CONTROL THE STORAGE BINS AND THE WATER FOGGING IS USED TO ELIMINATE THE PARTICULATE AT THE UNLOADING AREA.



## Process/Pollutant Information

PROCESS NAME: GASIFIER COAL FEED BINS, S14 (07-A-959P) Process Type: 90.011 (Coal Handling/Processing/Preparation/Cleaning) Primary Fuel: Throughput: 15.00 TONS

Process Notes: THE GASIFIER COAL FEED BINS ARE USED AS STORAGE FOR FEEDING THE GASIFICATION PROCESS

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOSUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COAL STORAGE SILOS, S15 (07-A-960P) Process Type: 90.011 (Coal Handling/Processing/Preparation/Cleaning) Primary Fuel: Throughput: 5000.00 TONS

Process Notes: THROUGHPUT IS ALSO 200 TONS PER HOUR

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.0050 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COAL STORAGE RECLAIM SILO, S16 (07-A-961P) Process Type: 90.011 (Coal Handling/Processing/Preparation/Cleaning) Primary Fuel: Throughput: 5000.00 TONSProcess Notes: THIS IS USED TO STORE COAL

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ASH STORAGE AND HANDLING, S17 (07-A-962P) Process Type: 99.120 (Ash Storage, Handling, Disposal) Primary Fuel: Throughput: 250.00 TONS

Process Notes: THE MAXIMUM STORAGE CAPACITY IS 250 TONS, THE MAXIMUM LOADOUT RATE IS 20 TONS PER HOUR

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: SULFUR STORAGE AND HANDLING, S18 (07-A-963P)

Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput: 500.00 LB/H

Process Notes: THIS UNIT STORES AND HANDLES THE SULFUR THAT IS OBTAINED FROM THE CONVERSION OF COAL INTO SYNGAS.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GRAIN RECEIVING, STORAGE, AND HANDLING, S20 (07-A-964P)

Process Type: 70.200 (Grain Handling and Drying) Primary Fuel: Throughput: 60714288.00 BU/YR

Process Notes: THE FACILTIY WILL STORE UP TO 60,714,286 BUSHELS PER ROLLING 12-MONTH PERIOD. THERE ARE TWO PRIMARY BINS THAT

CAN STORE A MAXIMUM OF 500,000 BUSHELS EACH AT ANYONE TIME.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOSUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSEEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PRODUCT LOADOUT FOR TRUCKS AND RAIL CARS, EP22 AND F50 (07-A-965P)

Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 1500.00 GAL/MIN

Process Notes: THIS IS THE LOADOUT OF TRUCKS AND RAILCARS. THE TRUCKS LOADOUT AT A RATE OF 750 GALLONS PER MINUTE AND

RAILCARS AT A RATE OF 1500 GALLONS PER MINUTE.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MM BTU BACTEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % SIX-MINUTE AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MM BTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/MM BTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 98.0000 % BACT FOR REDUCTION EFFICIENCY Emission Limit 2: 0.2100 LB/MMBTU BACT Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HAMMERMILL, S30 (07-A-966P) Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 2100.00 BU/H

Process Notes: THIS UNIT IS THE START OF THE ETHANOL PROCESS TO BREAK THE FEED INGREDIENT DOWN (IN THIS CASE CORN).

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) BAGHOSUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STARTUP AND SHUTDOWN FLARES 1, 2, AND 3, EP33A, EP33B, AND EP33C (07-A-967P, 07-A-968P, AND 07-A-969P)

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: NATURAL GAS OR SYNGAS Throughput: 25.00 MMBTU

Process Notes: PERMIT NUMBERS OF 07-A-967P, 07-A-968P, AND 07-A-969P. THE MAXIMUM CAPACITY IS 166.67 MM BTU / HR. THE UNIT CAN

ONLY OPERATE AT 25 MM BTU / HR DUE TO THE INHERENT PROCESS. ALL THREE UNITS ARE THE SAME AND ALL THREE UNITS COMBINED CAN ONLY OPERATE FOR 146 TOTAL HOURS PER ROLLING 12-MONTH PERIOD.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTU BACT Emission Limit 2: Standard Emission:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % SIX-MINUTE AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3950 LB/MM BTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) FLARE

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2000 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0060 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.1000 LB/MMBTU BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FERMENTERS AND BEERWELL, S40 (07-A-970P) Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 170.00 MM GAL/ 12-month rol

Process Notes: 170 MILLION GALLONS PER ROLLING 12-MONTH PERIOD

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0030 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) SCRUBBER

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0030 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 97.0000 % BACT Emission Limit 2: 100.0000 PPMV BACT Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS UNIT SHALL ACHIEVE EITHER 97% REDUCTION OR 100 PPMV FOR EMISSION RATES.

POLLUTANT NAME: Formaldehyde

CAS Number: 50-00-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Methanol

CAS Number: 67-56-1 Test Method: UnspecifiedPollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) )

Emission Limit 1: 0.0600 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Acetaldehyde

CAS Number: 75-07-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.8700 LB/H ACETALDEHYDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Acrolein

CAS Number: 107-02-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0600 LB/H ACROLEIN Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Hazardous Air Pollutants (HAP)

CAS Number: HAP Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) ) Emission Limit 1: 2.0800 LB/H TOTAL HAP Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.



## Process/Pollutant Information

PROCESS NAME: VOC EMISSIONS FROM EQUIPMENT LEAKS, F60 (07-A-971P) Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput:

Process Notes: THIS IS THE PERMIT WRITTEN FOR THE EMISSION LEAKS AT THE FACILITY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 13.6800 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BEST PRACTICES TO REDUCE EMISSIONS FROM LEAKING EQUIPMENT SUCH AS PUMPS, CONNECTIONS, AND VALVES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DENATURED ETHANOL STORAGE TANK, T61 AND T62 (07-A-972P AND 07-A-973P) Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput: 1500000.00 GAL

Process Notes: THERE ARE TWO TANKS FOR THE DENATURED ETHANOL STORAGE TANK. THE PERMITS ARE 07-A-972P AND 07-A-973P.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3600 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) INTERNAL FLOATING ROOF Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 200 PROOF ANYHDROUS ETHANOL STORAGE TANK, T63 (07-A-974P) Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput: 200000.00 GAL

Process Notes: STORES ANHYDROUS ETHANOL.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6100 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) INTERNAL FLOATING ROOF Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DENATURANT STORAGE TANK, T64 (07-A-975P) Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput: 200000.00 GAL

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.4900 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) INTERNAL FLOATING ROOF Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 190-PROOF ETHANOL STORAGE TANK, T65 (07-A-976P) Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput: 200000.00 GAL

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6100 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) INTERNAL FLOATING ROOFEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ADDITIVE (CORROSION INHIBITOR) TANK, T66 (07-A-977P) Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput: 2300.00 GAL

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DDGS COOLER, S70 (07-A-978P)

Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 80.00 T/HThroughput: 80.00 T/H

Process Notes: THIS UNIT IS USED TO COOL THE DDGS BEING PRODUCED AT THE FACILITY. A PORTION OF THE AIR BEING VENTED IS

VENTED BACK TO THE DRYERS FOR USE AS HEAT INPUT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Formaldehyde

CAS Number: 50-00-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0270 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Methanol

CAS Number: 67-56-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) )Emission Limit 1: 0.0781 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Acetaldehyde

CAS Number: 75-07-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0570 LB/H ACETALDEHYDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Acrolein

CAS Number: 107-02-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0610 LB/H ACROLEIN Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Hazardous Air Pollutants (HAP)

CAS Number: HAP Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) ) Emission Limit 1: 0.1600 LB/H TOTAL HAP Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.3500 LB/H BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER, F80 (07-A-979P) Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 50000.00 GAL/MIN

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0005 % DRIFT LOSS BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATOR / DEMISTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 0.0005% IS BASED ON THE DRIFT PER GALLON OF COOLING WATER FLOW WITH A MAXIMUM OF 2,000 MG / L FOR TDS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0005 % DRIFT LOSS BACT Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATOR / DEMISTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 0.0005% IS BASED ON THE DRIFT PER GALLON OF COOLING WATER FLOW WITH A MAXIMUM OF 2,000 MG / L FOR TDS.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % D/GAL BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELEIMIANTOR / DEMISTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 0.0005% IS BASED ON THE DRIFT PER GALLON OF COOLING WATER FLOW WITH A MAXIMUM OF 2,000 MG / L FOR TDS.



## Process/Pollutant Information

PROCESS NAME: DDGS LOADOUT, S90 (07-A-980P) Process Type: 70.900 (Other Food & Agricultural Products & Processes) Primary Fuel: Throughput: 150.00 tons per hour

Process Notes: THIS IS THE LOADOUT OF THE PRODUCED DDGS.

POLLUTANT NAME: Particulate Matter (PM)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 GR/DSCF BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACTEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Formaldehyde

CAS Number: 50-00-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0030 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Methanol

CAS Number: 67-56-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0090 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-CaseOther Applicable Requirements:

Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Acetaldehyde

CAS Number: 75-07-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H ACETALDEHYDE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Acrolein

CAS Number: 107-02-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0070 LB/H ACROLEIN Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Hazardous Air Pollutants (HAP)

CAS Number: HAP Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) ) Emission Limit 1: 0.0500 LB/H TOTAL HAP Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS USED TO MAKE SURE THE FACILITY IS A SYNTHETIC MINOR FOR NESHAP.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1400 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: DUST EMISSIONS FROM INTERNAL PLANT ROADS, F100 (07-A-981P)

Process Type: 99.140 (Paved Roads) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 96.4800 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BEST MANAGEMENT PRACTICES WITH SWEEPERS AND DUST SUPPRESSIONS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 18.7800 T/YR BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BEST MANAGEMENT PRACTICES WITH SWEEPERS AND DUST SUPPRESSIONS Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT - SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) BEST MANAGEMENT PRACTICES WITH SWEEPERS AND DUST SUPPRESSIONS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO VISIBLE EMISSIONS AT THE LOT LINE OF THE PROPERTY



## Process/Pollutant Information

PROCESS NAME: EMERGENCY DIESEL FIRE WATER PUMP, S110, (07-A-982P) Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput: 300.00 BHP

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2000 G/KW-H Emission Limit 2: 0.0990 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) NONE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT EQUIVALENT TO 0.20 G / KWH

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2000 G/KW-H BACT Emission Limit 2: 0.0990 LB/H BACT Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % BACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2030 G/KW-H Emission Limit 2: 0.1000 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT EQUIVALENT TO 0.203 G/KWH

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.2000 G/KW-H Emission Limit 2: 1.5800 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT EQUIVALENT TO 3.2 G / KWH

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8000 G/KW-H Emission Limit 2: 0.3950 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT EQUIVALENT TO 0.8 G/KWH

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.2600 G/KW-H Emission Limit 2: 1.6100 LB/H Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT EQUIVALENT TO 3.26 G/KWH



## Facility Information

RBLC ID: 

## NH-0014 (final) Date Determination Last Updated: 01/18/2012 Corporate/Company Name: UNIVERSITY OF NEW HAMSHIRE Permit Number: TP-B-0531 Facility Name: UNIVERSITY OF NEW HAMPSHIRE Permit Date: 07/25/2007 (actual)Facility Contact: JIM DOMBROSK 6038622345 JIM.DOMBROSK@UNH.EDU FRS Number: 065187122

Facility Description: CAMPUS COGENERATION (STEAM/ELECTRICITY) PLANT SIC Code: 4911 Permit Type: B: Add new process to existing facility NAICS Code: 611310 Permit URL: HTTP://WWW2.DES.STATE.NH.US/ONESTOPPUB/AIR/330170000909-0236TYPEPERMIT.PDF EPA Region: 1 COUNTRY: USA Facility County: STRAFFORD Facility State: NH Facility ZIP Code: 03824 Permit Issued By: NEW HAMPSHIRE DEPT OF ENV SERV, AIR RES (Agency Name) MR. TODD MOORE(Agency Contact) (603)271-6798 Todd.Moore@des.nh.gov Other Agency Contact Info: GARY.MILBURY@DES.NH.GOV Permit Notes: FACILITY WENT ONLINE IN MID 2009. COMPLIANCE STACK TESTING WAS COMPLETED DURING MID TO LATE 2009. PSD/NSR PERMIT MAY BE DOWNLOADED AT: HTTP://WWW2.DES.STATE.NH.US/ONESTOPPUB/AIR/330170000909-0236TYPEPERMIT.PDF Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 NH Presidential Range-Dry River < 100 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 176.2300 (Tons/Year) Nitrogen Oxides (NOx) 42.6100 (Tons/Year) Particulate Matter (PM) 23.1400 (Tons/Year) Sulfur Oxides (SOx) 24.5200 (Tons/Year) Volatile Organic Compounds (VOC) 48.2400 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: LANDFILL GAS ENGINES

Process Type: 17.140 (Landfill/Digester/Bio-Gas) Primary Fuel: LANDFILL GAS Throughput: 14.30 MMBTU/H

Process Notes: TWO 1,600 KW INTERAL COMBUSTION ENGINES FIRING ON LANDFILL GAS (LFG). THE LFG WILL BE SENT THROUGH A MOISTURE

SEPARATOR, WHICH WILL HAVE AN INTERNAL MESH PAD FILTER TO COLLECT WATER DROPLETS AND SOME PARTICULATE. THE ENGINES WILL BE EQUIPPED WITH COALESCING FILTERS THAT CALL FOR 99% REMOVAL OF ALL WATER DROPLETS AND PARTICULATES OVER 1 MICRON.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.5000 G/B-HP-H 1-HOUR AVG. PERIOD (STACK TEST) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) COMBUSTION CONTROLS (LEAN BURN DESIGN, AIR/FUEL RATIO CONTROLLER, INTERCOOLER, GOOD COMBUSTION PRACTICES) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: DUE TO CONTAMINANTS PRESENT IN LANDFILL GAS, CATALYST BASED CONTROLS SUCH AS SCR WERE DISMISSED AS POTENTIALLY APPLICABLE CONTROL TECHNOLOGIES.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.7500 G/B-HP-H 3-HOUR AVERAGE (STACK TEST) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: DUE TO CONTAMINANTS PRESENT IN THE LANDFILL GAS, CATALYST BASED CO CONTROLS WERE DISMISSED AS POTENTIALLY APPLICABLE CONTROL TECHNOLOGIES.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.1000 G/B-HP-H 3-HOUR AVG (STACK TEST) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) FILTERING OF INLET AIR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LANDFILL GAS/ NAT GAS COMBUSTION TURBINE Process Type: 16.120 (Landfill/Digester/Bio-Gas) Primary Fuel: LANDFILL GAS Throughput: 43.60 MMBTU/H

Process Notes: SOLAR TURBINES - MODEL: MERCURY 50

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 10.0000 PPM @ 15% O2 3 HOUR AVG (STACK TEST) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0420 G/B-HP-H 3-HOUR AVG (STACK TEST) Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) GOOD COMBUSTION PRACTICES AND FILTERING OF LFG THROUGH CARBON FILTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 5.0000 PPM @ 15% O2 3 HOUR AVG Emission Limit 2: 25.0000 PPM @ 15% O2 HOURLY (NOX RACT LIMIT - STACK TEST) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: LAER Other Applicable Requirements: SIP Control Method: (N) DRY LOW NOX (ULTRA LEAN PREMIX) COMBUSTION TECHNOLOGY GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS

NAME: UTILITY FLARE

Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: LANDFILL GAS Throughput: 125.40 MMBTU/H

Process Notes: A SECOND LFG FLARE RATED AT 105.06 MMBTU/HR IS ALSO PERMITTED. BACT/LAER LIMITS ARE THE SAME FOR BOTH

FLARES.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0680 LB/MMBTU 3-HOUR AVG Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: NSPS Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: FLARES WILL BE USED AT GREATLY VARYING PERCENTAGES OF DESIGN CAPACITY (BACKUP AND SUPPLEMENTAL OPERATING MODES). BASED ON THIS, APPLICANT PROPOSED THAT OPEN FLARES WOULD HAVE GREATEST FLEXIBILITY IN OPERATING EFFICENTLY AT VARIOUS LOADS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/MMBTU 3-HOUR AVG Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: FLARES WILL BE USED AT GREATLY VARYING PERCENTAGES OF DESIGN CAPACITY (BACKUP AND SUPPLEMENTAL OPERATING MODES). BASED ON THIS, APPLICANT PROPOSED THAT OPEN FLARES WOULD HAVE GREATEST FLEXIBILITY IN OPERATING EFFICENTLY AT VARIOUS LOADS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0420 LB/MMBTU 3-HOUR AVG Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0211 (final) Date Determination Last Updated: 07/16/2008 Corporate/Company Name: MARATHON PETROLEUM CO LLC Permit Number: PSD-LA-719

Facility Name: GARYVILLE REFINERY Permit Date: 12/27/2006 (actual) Facility Contact: DAVE ELDER 9855357881 DDELDER@MARATHONPETROLEUM.COM FRS Number: 110008374311Facility Description: PETROLEUM REFINERY. PROJECT INVOLVES ADDITION OF 8 NEW PROCESS UNITS, INCLUDING A 180,000 BBL/DAY CRUDE UNIT, TO INCREASE TOTAL REFINERY CAPACITY TO 425,000 BBL/DAY. PERMIT PSD-LA-719(M-2) ALLOWED MARATHON TO INCREASE THE REFINERY CAPACITY FROM 425,000 BBL/DAY TO 545,000 BBL/DAY. APPLICATION ACCEPTED DATE REFLECTS ADMINISTRATIVE COMPLETENESS DETERMINATION. SIC Code: 2911

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: ST. JOHN THE BAPTIST Facility State: LA Facility ZIP Code: 70051 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name)

MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: PERMIT WRITER: SYED QUADRI, 225-219-3181

Permit Notes: PSD-LA-719 HAS BEEN MODIFIED SEVERAL TIMES. NONE OF THE PROJECTS ADDRESSED IN SUBSEQUENT REVISIONS HAVE

RESULTED IN A SIGNIFICANT NET EMISSIONS INCREASE; HOWEVER, THERE HAVE BEEN A NUMBER OF REVISIONS TO HOURLY AND ANNUAL EMISSION LIMITATIONS, AVERAGING PERIODS, CONTROL EFFICIENCIES, AND OTHER PARAMETERS. THESE PERMITS CAN BE ACCESSED ON LDEQ’S ELECTRONIC DOCUMENT MANAGEMENT SYSTEM (EDMS) (HTTP://EDMS.DEQ.LOUISIANA.GOV) UNDER THE FOLLOWING “DOCUMENT ID” NOS.: PSD-LA-719(M-1): 3496708 PSD-LA-719(M-2): 6603214 PSD-LA-719(M-3): 7741813 PSD-LA-719(M-4): 7982866 PSD-LA-719(M-5): 8241202 PSD-LA-719(M-6): 8426666 PSD-LA-719(M-3), ISSUED 11/29/10, REVISED CALCULATIONS FOR THE HEATERS AND BOILER BASED ON THE OBSERVED HHV OF THE REFINERY FUEL GAS AND REDUCED THE EFFICIENCY OF THE NORTH AND SOUTH GROUND FLARES FROM 99.5 TO 98%. PSD-LA-719(M-4), ISSUED 6/8/11, ADDRESSED THE DIESEL OPTIMIZATION PROJECT (DOP). THE DOP WILL INCREASE PRODUCTION OF ULTRA-LOW SULFUR DIESEL, KEROSENE, SULFUR, AND WASTEWATER. WITH PSD-LA-719(M-5), ISSUED 12/21/11, LIMITS FOR THE DELAYED COKER UNIT 205 DRUM VENTS AND UNIT 205 QUENCH WATER WERE REVISED BASED ON TEST RESULTS. M-5 REVISED THE NOX BACT AVERAGING PERIOD FOR CERTAIN HEATERS AND A BOILER FROM A 3-HOUR AVERAGE TO AN ANNUAL AVERAGE AND ESTABLISHED ALTERNATE BACT LIMITS FOR 4 HEATERS WHEN THEY ARE OPERATING AT REDUCED CAPACITY. PSD-LA-719(M-6), ISSUED JUNE 13, 2012, ADDRESSED THE HYDROCRACKER OPTIMIZATION PROJECT (HOP), WHICH WILL INCREASE THE DESIGN CAPACITY OF THE HYDROCRACKER UNIT FROM 90,000 TO 110,000 BPD AND THE DOP. IN ADDITION, M-6 REVISED LIMITATIONS FOR THE COKER CHARGE HEATER BASED ON STACK TEST DATA AND SU/SD EMISSIONS FROM THE NORTH AND SOUTH GROUND FLARES. M-6 ALSO REFLECTS AN INCREASE IN THE CRUDE CAPACITY OF THE GARYVILLE MAJOR EXPANSION PROJECT FROM 270,000 TO 290,000 BPD AND THE RESULTANT INCREASE IN GASOLINE, ULTRA LOW SULFUR DIESEL, AND ASPHALT PRODUCTION. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 668.7200 (Tons/Year) Nitrogen Oxides (NOx) 682.5900 (Tons/Year) Particulate Matter (PM) 198.4700 (Tons/Year) Sulfur Oxides (SOx) 432.0700 (Tons/Year) Volatile Organic Compounds (VOC) 424.6300 (Tons/Year)

## Process/Pollutant Information

PROCESS NAME: A & B CRUDE HEATERS (1-08 & 2-08) & COKER CHARGE HEATER (15-08) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes: 1-08: 368.40 MM BTU/H 2-08: 368.40 MM BTU/H 15-08: 480.1 MM BTU/H

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 30 DAY ROLLING AV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU 3 HR AV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICESEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3 HR. AVE. Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H2S ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU ANNUAL AV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) ULTRA LOW NOX BURNERS (ULNB) AND SELECTIVE CATALYTIC REDUCTION (SCR VOLUNTARY) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROGEN REFORMER FURNACE FLUE GAS VENT (48-08) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: PURGE GAS Throughput: 1412.50 MMBTU/H

Process Notes: AVG. HEAT INPUT: 1130.0 MM BTU/H PURGE GAS: 813.6 MMBTU/H TRIM GAS: 316.4 MMBTU/H

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 30-DAY ROLLING AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMITControl Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU 3 HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , SIP Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H2S ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) ULTRA LOW NOX BURNERS (ULNB) AND SELECTIVE CATALYTIC REDUCTION (SCR VOLUNTARY) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: PLATFORMER HEATER CELLS NO. 1-3 (7A-08, 7B-08, & 7C-08) & HCU FRACTIONATOR HEATER (13-08)

Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes: 7A-08: 474 MM BTU/H 7B-08: 542.4 MM BTU/H 7C-08: 333.8 MM BTU/H 13-08: 361.26 MM BTU/H

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H2S ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS (ULNB) WITHOUT AIR PREHEAT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 30-DAY ROLLING AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU 3-HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: A & B VACUUM TOWER HEATERS (3-08 & 4-08) Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 155.20 MMBTU/H EA.

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3 HR AV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H2S ANNUAL AV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU ANNUAL AV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (B) ULTRA LOW NOX BURNERS (ULNB) AND SELECTIVE CATALYTIC REDUCTION (SCR VOLUNTARY) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 30 DAY ROLLING AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU 2 HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NAPHTHA HYDROTREATER REACTOR CHARGE HEATER (5-08), KHT REACTOR CHARGE HEATER (9-08), & HCU TRAIN 1&2

REACTOR CHARGE HEATERS (11-08 & 12-08) Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)Primary Fuel: REFINERY FUEL GAS

Throughput:

Process Notes: 5-08: 75.7 MMBTU/H 9-08: 73.8 MMBTU/H 11-08: 85.05 MMBTU/H 12-08: 85.05 MMBTU/H

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H2S ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS (ULNB) WITHOUT AIR PREHEAT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-RUN AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: 0.0015 LB/MMBTU 3-HOUR AVERAGE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NAPHTHA HYDROTREATER STRIPPER REBOILER HEATER (6-08) & KHT STRIPPER REBOILER HEATER (10-08) Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes: 6-08: 138.4 MMBTU/H 10-08: 121.8 MMBTU/H

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H2S ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS (ULNB) WITHOUT AIR PREHEAT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 0.0400 LB/MMBTU 30-DAY ROLLING AVERAGE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU 3-HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER NO. 1 (16-08) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 525.70 MMBTU/H

Process Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3 HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV AS H3S ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) USE OF LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 0.4000 LB/MMBTU ANNUAL AV

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) ULTRA LOW NOX BURNERS (ULNB) & FLUE GAS RECIRCULATION (FGR) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 30 DAY ROLLING AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0015 LB/MMBTU 3 HOUR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN, OPERATION, AND GOOD ENGINEERING PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SRU THERMAL OXIDIZER NOS. 1 & 2 (18-08 & 19-08) Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: NATURAL GAS Throughput: 63.70 MM BTU/H EA.

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) OPTIMIZED AIR-FUEL RATIO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 93.4100 PPMVD @ 0% EXCESS AIR

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , NSPS Control Method: (B) SEE NOTES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: OXYGEN ENRICHMENT AND SULFUR SHEDDING PROCEDURES WITH AUTOMATED CONTROLS WITHIN THE SRU; EXCESS SRU CAPACITY; DEGASSING THE LIQUID SULFUR PRODUCT UPSTREAM OF THE SULFUR PIT TO

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2000 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) OPTIMIZED AIR-FUEL RATIO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) OPTIMIZED AIR-FUEL RATIO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0004 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) OPTIMIZED AIR-FUEL RATIO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: EMERGENCY GENERATORS (DOCK & TANK FARM) (21-08 & 22-08) Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: DIESEL Throughput:

Process Notes: 21-08: 1341 HP 22-08: 671 HP GENERATORS PERMITTED FOR 182 H/YR EA.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0022 LB/HP-H ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF DIESEL WITH A SULFUR CONTENT OF 15 PPMV OR LESS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: USE OF DIESEL WITH A SULFUR CONTENT OF 15 PPMV OR LESS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0310 LB/HP-H ANNUAL AVERAGE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF DIESEL WITH A SULFUR CONTENT OF 15 PPMV OR LESS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0067 LB/HP-H ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) USE OF DIESEL WITH A SULFUR CONTENT OF 15 PPMV OR LESS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0025 LB/HP-H ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMITControl Method: (N) USE OF DIESEL WITH A SULFUR CONTENT OF 15 PPMV OR LESS

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER NOS. 1 & 2 (24-08 & 32-08) & HYDROGEN PLANT COOLING TOWER (53-08) Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput:

Process Notes: 24-08: 30,000 GAL/M 32-08: 96,250 GAL/M 53-08: 2500 GAL/M

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 PERCENT DRIFT RATE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) HIGH EFFICIENCY DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4.1400 MAX LB/H Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) MONTHLY MONITORING OF THE HEAT EXCHANGER/COOLING TOWER UNDER LDAR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THERE ARE NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: FIXED ROOF STORAGE TANKS Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes: INCLUDES EPNS 27-74, 28-74, 36-74 - 45-74, 66-74, 67-74, 73-74 - 76-74, 97-80 - 99-80, 120-91, 34-08, & 35-08.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

## Process/Pollutant Information

PROCESS NAME: INTERNAL FLOATING ROOF STORAGE TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput:

Process Notes: INCLUDES EPNS 16-74, 17-74, & 47-08.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOFS; COMPLY WITH 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: EXTERNAL FLOATING ROOF STORAGE TANKS

Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput:

Process Notes: INCLUDES EPNS 15-74, 18-74 - 25-74, 29-74 - 35-74, 63-74 - 65-74, 68-74, 71-74, 77-74 - 80-74, 90-74, 93-80 - 96-80, 3-05, 36-08 - 44-08, &

57-08.

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , SIP , OPERATING PERMIT Control Method: (P) EXTERNAL FLOATING ROOFS; COMPLY WITH 40 CFR 63 SUBPART CC Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THERE ARE NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: A & B COKER DRUM VENTS (33-08A & B) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 4500.00 LB/DAY

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 45.0000 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROGEN PLANT FLARE (52-08) Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: H2 PLANT FEED GAS Throughput: 2472.00 MMBTU/H

Process Notes: H2 PLANT FEED GAS: 2472 MMBTU/H PURGE GAS: 204.45 MMBTU/H PROCESS VENT GAS: 61.2 MMBTU/H

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.8000 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 20.2200 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18 Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: PERCENT SEE NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EXCEPT FOR A TOTAL OF 5 MINUTES DURING ANY 2 CONSECUTIVE HOURS



## Process/Pollutant Information

PROCESS NAME: HYDROGEN PLANT FUGITIVES (51-08) Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LDAR PROGRAM: LAC 33:III.2121 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: FUGITIVE EMISSIONS

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: UNITS 9, 19, 20, 21, 25, 26, 32, 33, 34, 60, 205, 205A, 210, 211, 212, 212A, 214, 215, 220, 221, 222, 222A, 222B, 232, 233, 234, 241, 243, 247, 250,

250A, 259, 260, 263, 265, 267, & 271 INCLUDES EPN 10-00 & 16-00, AS WELL AS OTHERS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LDAR PROGRAM: COMPLY WITH OVERALL MOST STRINGENT PROGRAM APPLICABLE TO UNIT. APPLICABLE PROGRAMS INCLUDE 40 CFR 63 SUBPART CC, 40 CFR 60 SUBPART GGG, LAC 33:III.2121, & LAC 33:III.CHAPTER 51 (LA REFINERY MACT). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

## Process/Pollutant Information

PROCESS NAME: FCCU REGENERATOR VENT (86-74) Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3000 LB/1000 LB COKE BURN ANNUAL AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (A) VENTURI WET GAS SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 25.0000 PPMV@0%02 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (A) VENTURI WET GAS SCRUBBER W/ ADDITION OF CAUSTIC SOLUTIONEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 40.0000 PPMV@0%02 Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) CATALYST ADDITIVES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 481.7600 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) FULL BURN OPERATION; MONITOR DAILY COKE BURN-OFF RATE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0700 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) FULL BURN OPERATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 10.4100 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) VENTURI WET GAS SCRUBBER W/ ADDITION OF CAUSTIC SOLUTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MARINE VAPOR COMBUSTOR (55-08) & MARINE LOADING VAPOR COMBUSTOR (107-90) Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading))Primary Fuel:

Throughput: 50000.00 BBL/H EA.

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLEPOLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: SEE NOTE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) SOURCE IS CONTROL DEVICE FOR VOC. COMPLY WITH 40 CFR 60.18. CONTROL PRODUCTS HAVING A TRUE VAPOR PRESSURE GREATER THAN 0.5 PSIA. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: MARINE/BARGE LOADING OPERATIONS (134-96) Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput: 65081.00 BBL/H

Process Notes: UNCONTROLLED

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

## Process/Pollutant Information

PROCESS NAME: WASTEWATER COLLECTION/TREATMENT (TRAINS 1-5) (30-08) Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput: 7125.00 GAL/MIN

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT , OPERATING PERMIT Control Method: (N) COMPLY WITH 40 CFR 63 SUBPART CC, 40 CFR 61 SUBPART FF, & 40 CFR 60 SUBPART QQQ Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: THERMAL DRYING UNIT HEATEC HEATER (124-1-91)

Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 9.60 MM BTU/H

Process Notes: UNIT DESTROYS VAPORS CREATED BY THE THERMAL DRYING UNT, WHICH HEATS SOLIDS SEGREGATED FROM

WASTEWATER BY THE API SEPARATORS.POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0500 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2000 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 0.4300 MAX LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5600 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1500 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: THERMAL DRYING UNIT-WASTEWATER SUMP & FEED TANKS (124-9-91, 124-10-91, 124-11-91, & 124-12-91) Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes: 124-9-91: 94 GALS/MIN 124-10-91: 21,000 GALS 124-11-91: 3780 GALS 124-12-91: 3780 GALS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) 124-10-91: SUBMERGED FILL PIPE 124-11-91: SUBMERGED FILL PIPE 124-12-91: SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Process/Pollutant Information

PROCESS NAME: HYDROGEN PLANT STEAM VENT (49-08)Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))

Primary Fuel: Throughput: 254500.00 LB/H

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: HYDROGEN PLANT DEAERATOR VENT (50-08) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 3125.00 LB/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: HYDROGEN PLANT HYDROGEN VENT (54-08) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 5.00 SCF/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: COKER UNIT STOCKPILE, CRUSHING, LOADING, & CONVEYING (2-00 - 8-00) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput: 1000.00 TONS/H

Process Notes: 5700 TONS/DAY (30-DAY ROLLING AVERAGE)

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF WATER SPRAYS & ENCLOSURES. MAINTAIN MOISTURE CONTENT AT 8% OR ABOVE. Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: THERE ARE NO EMISSION LIMITS



## Process/Pollutant Information

PROCESS NAME: COKE STOCKPILE (31-08) Process Type: 99.130 (Construction Activities) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0400 MAX LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF WATER SPRAYS, ENCLOSURE AND MOISTURE CONTENT OF 8-12%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKER HAUL ROAD (9-00) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: NONE Throughput: 1000.00 T/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF WATER SPRAYS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE



## Facility Information

RBLC ID: 

## TX-0526 (final) Date Determination Last Updated: 04/08/2008 Corporate/Company Name: AIR PRODUCTS Permit Number: NA 63 AND

39693 Facility Name: AIR PRODUCTS HYDROGEN, STEAM, AND ELECTRICITY PRODUCTION Permit Date: 08/18/2006 (estimated) Facility Contact: WILLIAM CALDWELL 713 920-7326 FRS Number: 110013817209 Facility Description: THE PORT ARTHUR HYDROGEN PRODUCTION FACILITY IS AN INTEGRATED OPERATION

CONSISTING OF A GAS TURBINE (GT) THAT PRODUCES ELECTRICAL POWER, A STEAM METHANE REFORMER (SMR) FURNACE THAT PRODUCES HYDROGEN, AND A HEAT RECOVERY STEAM GENERATOR (HRSG) THAT PRODUCES PROCESS STEAM. AIR PRODUCTS HAS PROPOSED SEVERAL DIFFERENT OPERATING SCENARIOS DEPENDING UPON THE NEEDS OF REFINERY AND EXTERNAL CUSTOMERS AS WELL AS ALLOWING FOR PERIODIC MAINTENANCE OF EACH OF THE THREE MAIN UNITS. THE PRIMARY MODE OF OPERATION IS INTEGRATED MODE WHERE THE GT FIRES (NATURAL GAS ONLY) AT MAXIMUM LOAD (950 MMBTU/HR) AND 60% OF THE GT EXHAUST IS ROUTED TO THE SMR UNIT AND REMAINING 40% OF THE GT EXHAUST IS ROUTED TO THE HRSG. THE SMR HAS ADDITIONAL BURNERS THAT FIRE (NATURAL GAS, REFINERY FUEL GAS, OR PSA PURGE GAS) AT RATE OF 1200 MMBTU/HR. THE HRSG HAS ADDITIONAL BURNERS THAT FIRE (NATURAL GAS OR REFINERY FUEL GAS) AT A RATE OF 550 MMBTU/HR DURING MAXIMUM STEAM PRODUCTION, 299 MMBTU/HR DURING AVERAGE STEAM PRODUCTION, AND SIC Code: 4931100 MMBTU/HR DURING MINIMUM STEAM PRODUCTION. WHILE INTEGRATED MODE IS THE PRIMARY MODE OF OPERATION (AN ESTIMATED 7,752 HR/YR) AND IS THE MOST EFFICIENT MODE OF OPERATION, IT IS NECESSARY AT TIMES TO OPERATE ONLY 2 OF THE UNITS IN INTEGRATED MODE OR TO OPERATE ALL 3 INDEPENDENTLY. DURING PARTIAL INTEGRATION MODE, THE GT WILL VENT EITHER 40% OR 60% OF ITS EXHAUST THROUGH A BYPASS STACK DEPENDING ON WHETHER IT IS INTEGRATED WITH THE SMR UNIT OR THE HRSG. THE GT, SMR, AND HRSG, ARE EACH EXPECTED TO BE TAKEN OFF LINE FOR 3 WEEKS A YEAR FOR MAINTENANCE (NOT SIMULTANEOUSLY). WHEN THE SMR UNIT OR THE HRSG OPERATE INDEPENDENTLY OF THE GT, THEY ARE FRESH AIR FIRED AND FIRE AT A MAXIMUM RATE OF 1,364 MMBTU/HR AND 765 MMBTU/HR, RESPECTIVELY. THE HIGHER HEAT RATES ARE REQUIRED BECAUSE THE COMBUSTION AIR IS NOT PREHEATED. IT IS ALSO NECESSARY TO USE THE GT BYPASS STACK WHEN IN TRANSITION BETWEEN NON INTEGRATED MODES AND INTEGRATED MODES. IN THE STEAM METHANE REFORMER PROCESS, H2 Permit Type: C: Modify process at existing facility NAICS Code: 221122 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: JEFFERSON Facility State: TX Facility ZIP Code: 77641 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes:



## Process/Pollutant Information

PROCESS NAME: REFORMER FURNACE STACK

Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary Fuel: STEAM

Throughput: 1373.00 MMBTU/H

Process Notes: STEAM METHANE REFORMER - PRIOR TO TREATMENT BY THE SCR, THE SMR ACHIEVES 0.024 LB/MMBTU NOX IN INTEGRATED

OPERATION AND 0.067 LB/ MMBTU NOX IN FRESH AIR FIRED MODE. THE SCR UNIT WILL REDUCE EMISSIONS OF NOX FROM THE SMR AS WELL AS THE GT BY 90% WHICH REPRESENTS LAER. THE PERMIT LIMITS THE SMR TO 9 PPM NOX AT 3% O2. STARTUP, SHUTDOWN, AND MAINTENANCE EMISSIONS ARE INCLUDED ON THE MAERT AND ARE BASED ON 0.067 LB/MMBTU NOX (92 LB/HR) IN FRESH AIR FIRING MODE WITHOUT SCR. BACT FOR THE OTHER CRITERIA POLLUTANTS ARE AS FOLLOWS: OPERATIONAL DATA FROM A SIMILARLY SIZED UNIT SHOWS EXTREMELY LOW CO (3.5 TPY) AND VOC EMISSIONS (4.7 TPY). PM10EMISSIONS ARE 0.0075 LB/MMBTU BASED ON AP-42 FACTORS AND SO2 EMISSIONS ARE BASED ON 45 PPM OF TOTAL SULFUR ANNUAL AVERAGE CONCENTRATION IN THE REFINERY FUEL GAS. NH3 SLIP WILL BE LIMITED TO 10 PPM AT 3% O2.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 21.6000 LB/H Emission Limit 2: 59.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 81.0000 LB/H Emission Limit 2: 87.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 16.7000 LB/H Emission Limit 2: 63.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 7.3000 LB/H Emission Limit 2: 28.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.6000 LB/H Emission Limit 2: 14.0000 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 24.9000 LB/H Emission Limit 2: 110.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GAS TURBINE STACK

Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas))

Primary Fuel: NATURAL GAS

Throughput: 700.00 MMBTU/H

Process DRY LOW-NOX COMBUSTION TECHNOLOGY WILL BE USED PRODUCING AN EXHAUST STREAM WITH A NOX CONCENTRATIONProcess

Notes: DRY LOW-NOX COMBUSTION TECHNOLOGY WILL BE USED PRODUCING AN EXHAUST STREAM WITH A NOX CONCENTRATION

OF 9 PPM WHEN VENTING DIRECTLY TO THE ATMOSPHERE. THE EXHAUST TEMPERATURE FROM THE BYPASS STACK WILL BE OVER 1,000 F AND IS TOO HOT TO BE CONTROLLED BY SCR, MAKING 9 PPM AND THE MINIMIZATION OF THE USE OF THE BYPASS STACK LAER. NORMAL INTEGRATED OPERATION WILL HAVE THE EXHAUST STREAM ROUTED DIRECTLY TO THE SMR FURNACE AND HRSG, WHICH WILL BE EQUIPPED WITH A SELECTIVE CATALYTIC REDUCTION (SCR) UNIT TO CONTROL THE NOX EMISSIONS AND REPRESENTS LAER. BACT FOR THE OTHER CRITERIA POLLUTANTS ARE AS FOLLOWS: CO, VOC, AND PM10 EMISSIONS ARE BASED ON VENDOR GUARANTEES OF 0.0068 LB/MMBTU, 0.0019 LB/MMBTU AND 5 LB/HR, RESPECTIVELY, AND ARE MINIMIZED BY GOOD COMBUSTION PRACTICES. SO2 EMISSIONS ARE BASED ON 4.5 PPM OF TOTAL SULFUR ANNUAL AVERAGE CONCENTRATION IN THE NATURAL GAS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 33.3000 LB/H Emission Limit 2: 13.0000 T/YR Standard Emission: 166.5000 LB/H MSS Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 19.6000 LB/H Emission Limit 2: 7.4000 T/YR Standard Emission: 166.5000 LB/H MSS Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 7.0000 LB/H Emission Limit 2: 0.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.9200 LB/H Emission Limit 2: 0.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.3300 LB/H Emission Limit 2: 0.4000 T/YR Standard Emission: 27.0000 LB/H MSS Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE PILOTS ONLY

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: PLANT FLARE - THE FLARE CONSISTS OF A STAND-ALONE ELEVATED, SMOKELESS FLARE AND A NETWORK OF PIPING AND

ANCILLARY EQUIPMENT CONNECTING ALL RELIEF DEVICES AND PROCESS VENTS IN COMBUSTIBLE GAS (VOC) SERVICE. THE FLARE WILL ACHIEVE A MINIMUM OF 98% DESTRUCTION AND REMOVAL OF VOCS. THE FLARE WILL PRIMARILY BE USED UNDER SARTUP/SHUTDOWN CONDITIONS OR DURING MAINTENANCE ACTIVITIES OR UPSETS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0430 LB/H Emission Limit 2: 0.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0220 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0020 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0310 LB/H Emission Limit 2: 0.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE-MSS

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: PLANT FLARE - THE FLARE CONSISTS OF A STAND-ALONE ELEVATED, SMOKELESS FLARE AND A NETWORK OF PIPING AND

ANCILLARY EQUIPMENT CONNECTING ALL RELIEF DEVICES AND PROCESS VENTS IN COMBUSTIBLE GAS (VOC) SERVICE. THE FLARE WILL ACHIEVE A MINIMUM OF 98% DESTRUCTION AND REMOVAL OF VOCS. THE FLARE WILL PRIMARILY BE USED UNDER SARTUP/SHUTDOWN CONDITIONS OR DURING MAINTENANCE ACTIVITIES OR UPSETS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1654.0000 LB/HEmission Limit 2: 28.8000 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 160.0000 LB/H Emission Limit 2: 2.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2000 LB/H Emission Limit 2: 0.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## VA-0301 (final) Date Determination Last Updated: 05/03/2007 Corporate/Company Name: USA WASTE OF VIRGINIA LANDFILLS Permit Number: 61291

Facility Name: BETHEL LANDFILL Permit Date: 07/25/2006 (actual) Facility Contact: RICHARD GUIDRY 8047212136 FRS Number: 110001908589 Facility Description: A MUNICIPAL SOLID WASTE LANDFILL WITH GAS COLLECTION SYSTEM AND SIX ENERGY RECOVERY ENGINE/GENERATORS SIC Code: 4953

Permit Type: A: New/Greenfield Facility NAICS Code: 562212 Permit URL:EPA Region: 3 COUNTRY: USA

Facility County: HAMPTON Facility State: VA Facility ZIP Code: 23666 Permit Issued By: VIRGINIA DEPT. OF ENVIRONMENTAL QUALITY; DIVISION OF AIR QUALITY (Agency Name) MR. YOGESH DOSHI(Agency Contact) (804)698-4017 Yogesh.doshi@deq.virginia.gov Other Agency Contact Info: FOR TECHNICAL INFORMATION ON THIS FACILITY PLEASE CONTACT THE PERMIT WRITTER, STEPHEN HACKNEY AT (757)518-2124 OR BY E-MAIL AT SAHACKNEY@DEQ.VIRGINIA.GOV Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 279.8000 (Tons/Year) Nitrogen Oxides (NOx) 127.5000 (Tons/Year) Particulate Matter (PM) 12.6000 (Tons/Year) Sulfur Oxides (SOx) 17.7000 (Tons/Year) Volatile Organic Compounds (VOC) 26.2000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: ENGINE/GENERATORS RECOVERY SYSTEM Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: TREATED LANDFILL GAS Throughput: 10.10 MMBTU/H

Process Notes: EMISSIONS ARE FOR EACH UNIT

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.8000 LB/H EACH ENGINE Emission Limit 2: 179.7000 T/YR COMBINED ENGINES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.8000 LB/H EACH ENGINE Emission Limit 2: 99.8000 T/YR COMBINED ENGINES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW EMISSION ENGINES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CONTROL SYSTEM FLARES Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: UNTREATED LANDFILL GAS Throughput: 4300.00 CFM

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 13.4000 LB/H Emission Limit 2: 58.6000 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (P) LOW EMISSION ENGINES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 19.9000 LB/H Emission Limit 2: 87.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## NY-0096 (final) Date Determination Last Updated: 08/18/2008 Corporate/Company Name: NYC DEPARTMENT OF ENVIRONMENTAL PROTECTION Permit Number: 2610500687

Facility Name: FOUNTAIN AVENUE LANDFILL Permit Date: 06/29/2006 (actual) Facility Contact: PATRICK O'CONNOR 7185956043 FRS Number: 110019246822Facility Description: THE FOUNTAIN AVENUE LANDFILL (FAL) WAS A FORMER SOLID WASTE MANAGEMENT FACILITY, LOCATED AT THE FOOT OF FOUNTAIN AVENUE, IN BROOKLYN, NEW YORK. THE LANDFILL MEASURES 297 ACRES AND EXTENDS INTO JAMAICA BAY. THE LANDFILL RECEIVED MUNICIPAL AND INDUSTRIAL WASTE FROM FEBRUARY 1961 TO DECEMBER 1985. SOLID WASTE DISPOSED AT THE FACILITY INCLUDED GARBAGE, RUBBISH, STREET DIRT, COMMERCIAL WASTE, CONSTRUCTION AND DEMOLITION DEBRIS, INCINERATOR ASH AND RESIDUE. APPROXIMATELY 31.2 MILLION CUBIC YARDS OF WASTE HAVE BEEN DISPOSED AT THE LANDFILL. IN ADDITION, WASTE OIL CONTAINING HAZARDOUS SUBSTANCES HAD BEEN USED FOR CONTROL OF ROADWAY DUST. ASBESTOS CONTAINING WASTE WAS ALSO DISPOSED AT THE FACILITY. REMEDIAL ACTIVITIES CONDUCTED AT THE LANDFILL ARE DONE UNDER THE SUPPORT OF THE NEW YORK CITY DEPARTMENT OF ENVIRONMENTAL PROTECTION (DEP); HOWEVER, THE LANDFILL IS ACTUALLY OWNED BY THE NATIONAL PARK SERVICE (NPS). THE DEP IS ACTING AS THE CLOSURE AGENCY FOR THE FAL. ACTIVITIES AT THE LANDFILL CURRENTLY CONSIST OF CONSTRUCTING THE FINAL CLOSURE SYSTEM OF A NYSDEC PART 360 CAP AND ACTIVE LANDFILL GAS COLLECTION AND FLARING. SIC Code: 4953

Permit Type: A: New/Greenfield Facility NAICS Code: 562212 Permit URL: EPA Region: 2 COUNTRY: USA Facility County: KINGS Facility State: NY Facility ZIP Code: 11208 Permit Issued By: NEW YORK DEPT. OF ENVIRONMENTAL CONSERVATION (Agency Name)

MR. NICK ONDERDONK-MILN(Agency Contact) (518)402-8403 nlonderd@gw.dec.state.ny.us Other Agency Contact Info: 625 BROADWAY

ALBANY NY 12233-3254 (518)402-8403 JLHENKES@GW.DEC.STATE.NY.US Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase:

Carbon Monoxide 30.0000 (Tons/Year) Nitrogen Oxides (NOx) 1.5000 (Tons/Year) Particulate Matter (PM) 0.7500 (Tons/Year) Sulfur Oxides (SOx) 0.0300 (Tons/Year) Volatile Organic Compounds (VOC) 0.0100 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: LANDFILL FLARE

Process Type: 12.320 (Landfill/Digester/Bio-Gas)Process Type: 12.320 (Landfill/Digester/Bio-Gas)

Primary Fuel: Throughput:

Process Notes: A "JOHN ZINK" ENCLOSED GROUND FLARE AND LFG SPECIALITIES BLOWER AND INSTRUMENTATION SYSTEM IS USED FOR

CONTROL OF LANDFILL GAS EMISSIONS. AT AN EXPECTED TEMPERATURE OF 1600 DEGREES FAHRENHEIT, THE DETENTION TIME WILL BE 1.13 SECONDS. THE GAS COLLECTION AND FLARING SYSTEM TO BE INSTALLED AT THE LANDFILL IS EXPECTED TO HAVE A 98% DESTRUCTION RATE OF NMOCS AND 99% DESTRUCTION RATE OF VOCS. THE FLARE HAS DIMENSIONS OF 12 FEET DIAMETER AND AN OVERALL HEIGHT OF 50 FEET.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSION LIMITS AVAILABLE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 39.0000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT , OPERATING PERMITControl Method: (N) THE FACILITY OBTAINED 50.7 TONS OF NOX ERCS FOR THIS FACILITY TO OPERATE THE FLARE. THE EMISSIONS LIMITS FOR THIS FACILITY ARE AS FOLLOWS: NOX - 39 TONS PER YEAR NMOC - 98% REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE FACILITY OBTAINED 50.7 TONS OF NOX ERCS FOR THIS FACILITY TO OPERATE THE FLARE. THE EMISSIONS LIMITS FOR THIS FACILITY ARE AS FOLLOWS: NOX - 39 TONS PER YEAR NMOC - 98% REDUCTION

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: SIP , OPERATING PERMIT Control Method: (A) A JOHN ZINK ENCLOSED GROUND FLARE AND LFG SPECIALITIES BLOWER AND INSTRUMENTATION SYSTEM IS CONTROL OF LANDFILL GAS EMISSIONS. AT AN EXPECTED TEMPERATURE OF 1600 DEGREES FAHRENHEIT, THE DETENTION TIME WILL BE 1.13 SECONDS. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: A JOHN ZINK ENCLOSED GROUND FLARE AND LFG SPECIALITIES BLOWER AND INSTRUMENTATION SYSTEM IS USED TO CONTROL OF LANDFILL GAS EMISSIONS. AT AN EXPECTED TEMPERATURE OF 1600 DEGREES FAHRENHEIT, THE DETENTION TIME WILL BE 1.13 SECONDS. THE GAS COLLECTION AND FLARING SYSTEM TO BE INSTALLED AT THE LANDFILL IS EXPECTED TO HAVE A 98% DESTRUCTION RATE OF NMOCS AND 99% DESTRUCTION RATE OF VOCS. THE FLARE HAS DIMENSIONS OF 12 FEET DIAMETER AND AN OVERALL HEIGHT OF 50 FEET.



## Facility Information

RBLC ID: 

## TX-0511 (final) Date Determination Last Updated: 05/01/2008Corporate/Company

Name: BASF FINA PETROCHEMICALS Permit Number: PSD-TX

903M1,N-007M1 AND 36644 Facility Name: BASF ETHYLENE/PROPYLENE CRACKER Permit Date: 02/03/2006 (actual) Facility Contact: FRS Number: 110006134691 Facility Description: BASF FINA PETROCHEMICALS LP (BFLP) OPERATES AN ETHYLENE CRACKER AND

ASSOCIATED SUPPORT FACILITIES AT ITS PORT ARTHUR PLANT SITE. THE ETHYLENE CRACKER HAS A NOMINAL CAPACITY OF 2.45 BILLION POUNDS OF ETHYLENE PER YEAR AND IS CURRENTLY THE LARGEST SINGLE TRAIN NAPHTHA CRACKER IN THE WORLD. IT WAS BUILT AT A GRASSROOTS LOCATION WITH LIMITED INTEGRATION WITH OTHER PETROCHEMICAL PROCESS UNITS AND ASSOCIATED UTILITIES, MAKING IT DIFFERENT THAN MOST OTHER ETHYLENE CRACKERS IN THE WORLD. PERMIT NUMBERS 36644, PSD-TX-903, AND N-007 WERE ISSUED 9/98, AND THE PLANT BEGAN OPERATIONS 12/2001. SIC Code: 4932

Permit Type: C: Modify process at existing facility NAICS Code: 325110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: JEFFERSON Facility State: TX Facility ZIP Code: 77643 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes:



## Process/Pollutant Information

PROCESS NAME: RECYCLE ETHANE CRACKING FURNACE Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.1200 LB/HEmission Limit 2: 4.8900 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 23.2500 LB/H Emission Limit 2: 101.8500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5100 LB/H Emission Limit 2: 6.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5700 LB/H Emission Limit 2: 2.5100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 24.1600 LB/H Emission Limit 2: 79.3700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FRESH FEED CRACKING HEATER

Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.))

Primary Fuel: Throughput:

Process Notes: BFLP'S PORT ARTHUR ETHYLENE CRACKER CONSISTS OF A SINGLE TRAIN UNIT DIVIDED MAINLY INTO TWO SECTIONS, THE

PYROLYSIS SECTION AND THE SEPARATION SECTION. IN THE PYROLYSIS SECTION, THE FEEDSTOCK IS THERMALLY CRACKED, FOLLOWED BY THE SEPARATION SECTION. THE GROUND FLARE CONSISTS OF A MULTIPOINT BURNER, STAGED PERFORMANCE HIGH PRESSURE FLARE SYSTEM. THIS FLARE WAS DESIGNED TO EFFICIENTLY CONTROL A VARIETY OF VENTING SCENARIOS FROM THIS PROCESS. THE HEATING VALUE OF STREAMS ROUTED TO THE FLARE CAN VARY FROM 10 TO OVER 38,000 MMBTU/HR. THE STREAMS ROUTED TO THE FLARE CAN INCREASE FROM A MINIMUM FLOW TO MAXIMUM FLOW IN ONLY A FEW SECONDS. RELATIVELY HIGH FLOW RATES TO THE FLARE CAN CONTINUE FOR MINUTES, HOURS, OR DAYS. PERIODS OF VERY LOW FLOW MAY CONTINUE FOR WEEKS AT A TIME. SINCE LARGE PORTIONS OF THE ETHYLENE CRACKER PROCESS ARE CHARACTERIZED BY ¿INTERMEDIATE¿ STREAMS IN THE GAS PHASE, A PARTICULARLY LARGE AMOUNT OF OPERATING EQUIPMENT AND ASSOCIATED PROCESS CONTROL SYSTEMS MUST WORK CONTINUOUSLY AND CLOSELY TOGETHER TO AVOID OPERATING SCENARIOS REQUIRING VENTING TO THE FLARE. A CERTAIN AMOUNT OF THIS TYPE OF FLARING IS INHERENT IN A WELL-RUN FACILITY OF THE SIZE, TYPE AND COMPLEXITY OF THE BFLP CRACKER.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 35.3500 LB/H Emission Limit 2: 116.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.6100 LB/H Emission Limit 2: 7.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 34.0100 LB/H Emission Limit 2: 148.9700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.2100 LB/H Emission Limit 2: 9.6700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8400 LB/H Emission Limit 2: 3.6800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: REACTOR REGENERATION EFFLUENT Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 63.5500 LB/H Emission Limit 2: 53.3700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: DP FEED HEATER Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 5.0100 LB/H Emission Limit 2: 13.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2200 LB/H Emission Limit 2: 0.9500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.6900 LB/H Emission Limit 2: 3.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 1.6400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1700 LB/H Emission Limit 2: 0.7400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DP REACTOR REGENERATION HEATER Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.7300 LB/H Emission Limit 2: 1.4200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2400 LB/H Emission Limit 2: 0.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: AUXILARY BOILER Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.))Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 13.6000 LB/H Emission Limit 2: 20.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.2400 LB/H Emission Limit 2: 0.9200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 15.6000 LB/H Emission Limit 2: 23.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.5800 LB/H Emission Limit 2: 2.3500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 1.5800 LB/H

Emission Limit 2: 2.3500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GTG HRSG UNIT 1 GE FRAME 6B 310.4 MMBTU/H DUCT BURNER (WITH SCR) Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput: 310.40 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 15.3000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 4.4600 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 53.9000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 5.4800 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.8500 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.6100 LB/H Emission Limit 2: 30.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GTG HRSG UNIT 2 GE FRAME 6B 310.4 MMBTU/HR DUCT BURNER (WITH SCR) Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput: 310.40 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 24.1000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 4.4600 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 53.9000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 5.4800 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.8500 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.6100 LB/H Emission Limit 2: 30.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GROUND FLARE

Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006))

Primary Fuel: Throughput:

Process Notes: THE GROUND FLARE CONSISTS OF A MULTIPOINT BURNER, STAGED PERFORMANCE HIGH PRESSURE FLARE SYSTEM. THIS

FLARE WAS DESIGNED TO EFFICIENTLY CONTROL A VARIETY OF VENTING SCENARIOS FROM THIS PROCESS. THE HEATING VALUE OF STREAMS ROUTED TO THE FLARE CAN VARY FROM 10 TO OVER 38,000 MMBTU/HR. THE STREAMS ROUTED TO THE FLARE CAN INCREASE FROM A MINIMUM FLOW TO MAXIMUM FLOW IN ONLY A FEW SECONDS. RELATIVELY HIGH FLOW RATES TO THE FLARE CAN CONTINUE FOR MINUTES, HOURS, OR DAYS. PERIODS OF VERY LOW FLOW MAY CONTINUE FOR WEEKS AT A TIME. SINCE LARGE PORTIONS OF THE ETHYLENE CRACKER PROCESS ARE CHARACTERIZED BY ¿INTERMEDIATE¿ STREAMS IN THE GAS PHASE, A PARTICULARLY LARGE AMOUNT OF OPERATING EQUIPMENT AND ASSOCIATED PROCESS CONTROL SYSTEMS MUST WORK CONTINUOUSLY AND CLOSELY TOGETHER TO AVOID OPERATING SCENARIOS REQUIRING VENTING TO THE FLARE. A CERTAIN AMOUNT OF THIS TYPE OF FLARING IS INHERENT IN A WELL-RUN FACILITY OF THE SIZE, TYPE AND COMPLEXITY OF THE BFLP CRACKER.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2219.7000 LB/H Emission Limit 2: 452.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 165.8000 LB/H Emission Limit 2: 7.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 15794.4004 LB/H Emission Limit 2: 1040.3001 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 24418.0996 LB/H Emission Limit 2: 905.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.8000 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FIRE WATER PUMP ENGINE (2) Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:Process Notes: EMISSIONS ARE PER ENGINE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 15.8100 LB/H Emission Limit 2: 1.2300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.0500 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.4100 LB/H Emission Limit 2: 0.2700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.2600 LB/H Emission Limit 2: 0.1000 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER (2) Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Throughput: 425.40 MMBTU/H

Process Notes: EMISSIONS ARE THE TOTAL OF BOTH BOILERS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 12.0000 LB/H Emission Limit 2: 39.3400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 8.5000 LB/H ROUTINE Emission Limit 2: 34.0400 LB/H START UP Standard Emission: 37.2600 T/YR Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 29.8800 LB/H Emission Limit 2: 130.4200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 12.1000 LB/H Emission Limit 2: 38.6800 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.7600 LB/H Emission Limit 2: 16.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 6.3400 LB/H Emission Limit 2: 27.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0514 (final) Date Determination Last Updated: 11/20/2007 Corporate/Company Name: ENTERPRISE PRODUCTS OPEATING LP Permit Number: PSD-TX 1057

AND 76070 Facility Name: ENTERPRISE MONT BELVIEU COMPLEX Permit Date: 01/24/2006 (actual) Facility Contact: FRS Number: 110000463711 Facility Description: THE MONT BELVIEU COMPLEX OPERATES SEVERAL UNITS WHICH PROCESS LIQUID PETROLEUM

GASES TO PRODUCE HIGH-GRADE PRODUCTS AND CERTAIN SYNTHETIC ORGANIC CHEMICALS. THE PROCESSES INCLUDE FRACTIONIZATION, REACTION, SEPARATION, AND DISTILLATION. THE FOUR FLARES IN THIS PERMIT ARE USED TO CONTROL PROCESS, MAINTENANCE, START-UP, AND SHUTDOWN EMISSIONS. NORTH PLANT FLARE (EPN 45) USED TO CONTROL ROUTINE EMISSIONS FROM THE PRODUCTION OF METHYL-TERT-BUTYL ETHER (MTBE) AND RELATED GASOLINE ADDITIVE PRODUCTS FROM THE BEF UNIT, AND ROUTINE EMISSIONS FROM THE PROPANE/PROPYLENE (P/P) SPLITTER II UNIT. VENT GASES INCLUDE C3-, BUTANES, BUTENES, AND SOME NITROGEN AND CO2. SOUTH PLANT (MAIN) FLARE ( FL-1) USED AS A CONTROL DEVICE FOR A NUMBER OF UNITS INCLUDING: DEISOBUTANIZER UNITS 300, 400, 900, AND 1300; BUTAMER UNITS I AND II, THE WEST TEXAS AND SEMINOLE FRACTIONATOR UNITS; AND THE P/P SPLITTER I UNIT. VENT GASES INCLUDE C3-, BUTANES, BUTENES, AND SOME NITROGEN AND CO2. THE NORTH AND SOUTH PLANT FLARES ARE CONNECTED SO THAT THEY MAY SERVE AS BACKUPS TO EACH OTHER. NORTH STORAGE FLARE (FL-2) USED TO CONTROL PERIODIC EMISSIONS FROM THE BRINE DEGASSING OPERATIONS ASSOCIATED WITH THE OPERATION OF UNDERGROUND STORAGE FACILITIES. IT IS ALSO USED TO CONTROL ROUTINE MAINTENANCE EMISSIONS FROM METERING STATIONS AND FACILITY PIPELINES. VENT GASES INCLUDE C3-, BUTANE, AND ISOBUTANE. THE LRGO FLARE (FL-3) USED TO CONTROL EMISSIONS ASSOCIATED WITH THE WEST TERMINAL AREA OPERATIONS. THE TERMINAL IS USED TO LOAD AND UNLOAD LIQUID PETROLEUM GAS (LPG) FROM TRUCKS AND RAIL CARS. IT IS ALSO USED AS AN OVER PRESSURE RELIEF FLARE FOR THE SOUTH PLANT FLARE. WHEN THE FLOW TO THE SOUTH PLANT FLARE EXCEEDS A CERTAIN PRESSURE POINT, THE EXCESS FLOW IS DIVERTED TO THE LRGO FLARE. THE FLARE CONSISTS OF A RING OF 24 STAGED BURNERS ATTACHED TO THE RISER STACK OF THE SOUTH PLANT FLARE. IT MEETS THE VELOCITY REQUIREMENTS OF 40CFR 60.18. SIC Code: 291Permit Type: C: Modify process at existing facility NAICS Code: 324110

Permit URL: EPA Region: 6 COUNTRY: USA Facility County: CHAMBERS Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase:

Carbon Monoxide 166.2000 (Tons/Year) Nitrogen Oxides (NOx) 124.7000 (Tons/Year) Volatile Organic Compounds (VOC) 0.2000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: FLARE-NORMAL OPERATION Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 468.1000 LB/H Emission Limit 2: 93.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 376.6000 LB/H Emission Limit 2: 153.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 372.7000 LB/H Emission Limit 2: 233.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)CAS Number: 7446-09-5

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.1000 LB/H Emission Limit 2: 0.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE-START-UP, MAINTENANCE, AND SHUTDOWN Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 63.7000 LB/H Emission Limit 2: 23.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 154.1000 LB/H Emission Limit 2: 1.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 354.3000 LB/H Emission Limit 2: 4.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Facility Information

RBLC ID: 

## TX-0475 (final) Date Determination Last Updated: 04/19/2007 Corporate/Company Name: FORMOSA PLASTICS CORPORATION TEXAS Permit Number: 19168 / PSD-TX-760M6 Facility Name: FORMOSA POINT COMFORT PLANT Permit Date: 05/09/2005 (actual) Facility Contact: RANDY SMITH 3619877000 FRS Number: 110018925957 Facility Description: SIC Code: 2821 Permit Type: U: Unspecified NAICS Code: 325211 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: CALHOUN Facility State: TX Facility ZIP Code: 779870700 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 95.9100 (Tons/Year) Nitrogen Oxides (NOx) 197.1000 (Tons/Year) Particulate Matter (PM) 14.2500 (Tons/Year) Sulfur Oxides (SOx) 5.3400 (Tons/Year) Volatile Organic Compounds (VOC) 33.3800 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: PYROLYSIS FURNACES (1001-1008, 1009 B) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: FUEL GAS Throughput: 250.00 MMBtu/h

Process Notes: EMISSIONS ARE BASED ON EACH FURNANCE

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 0.7000 LB/H Emission Limit 2: 3.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 30.3000 LB/H Emission Limit 2: 132.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) THE PYROLYSIS FURNACES WILL USE INTERNAL FLUE GAS RECIRCULATION (IFGR) AND STAGED FUEL GAS ULTRA LOW-NOX BURNERS TO CONTROL NOX EMISSIONS. THE BURNER TECHNOLOGY INSTALLED WILL USE THE FUEL GAS MOMENTUM TO INSPIRATE HOT FLUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.2000 LB/H Emission Limit 2: 35.9200 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5000 LB/H Emission Limit 2: 2.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 1.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/AControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DECOKE DRUM (5) Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes: EMISSIONS ARE THE TOTAL OF THE FIVE DRUMS

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 7.0500 LB/H Emission Limit 2: 1.6200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 76.6000 LB/H Emission Limit 2: 17.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PYROLYSIS FURNACE (1010B) Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: FUEL GAS Throughput: 250.00 MMBtu/H

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.3100 LB/H Emission Limit 2: 10.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 18.7500 LB/H Emission Limit 2: 65.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) THE PYROLYSIS FURNACES WILL USE INTERNAL FLUE GAS RECIRCULATION (IFGR) AND STAGED FUEL GAS ULTRA LOW-NOX BURNERS TO CONTROL NOX EMISSIONS. THE BURNER TECHNOLOGY INSTALLED WILL USE THE FUEL GAS MOMENTUM TO INSPIRATE HOT FLUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.7500 LB/HEmission Limit 1: 8.7500 LB/H

Emission Limit 2: 28.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5000 LB/H Emission Limit 2: 2.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.4100 LB/H Emission Limit 2: 1.7800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis:

Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: REBOILER (1 AND 2) Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: FUEL GAS Throughput: 250.00 MMBtu

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.3600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 1.8200 LB/H

Emission Limit 2: 7.9700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) THE PYROLYSIS FURNACES WILL USE INTERNAL FLUE GAS RECIRCULATION (IFGR) AND STAGED FUEL GAS ULTRA LOW-NOX BURNERS TO CONTROL NOX EMISSIONS. THE BURNER TECHNOLOGY INSTALLED WILL USE THE FUEL GAS MOMENTUM TO INSPIRATE HOT FLUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.0200 LB/H Emission Limit 2: 4.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2200 LB/H Emission Limit 2: 0.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.1400 LB/H Emission Limit 2: 2.3800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 9.7700 LB/H Emission Limit 2: 20.4100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:Other Applicable Requirements: N/A

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIESEL EMERGENCY GENERATOR Process Type: 16.290 (Liquid Fuel & Liquid fuel Mixtures) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 13.4000 LB/H Emission Limit 2: 0.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0800 LB/HEmission Limit 2: 0.0100 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.4400 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.0600 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis:Other Applicable Requirements: N/A

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5000 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PYROLYSIS FURNACE (1054-1056) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: FUEL GAS Throughput: 250.00 mmbtu/h

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.7300 LB/HEmission Limit 2: 27.3300 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 20.0200 LB/H Emission Limit 2: 720.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) THE PYROLYSIS FURNACES WILL USE INTERNAL FLUE GAS RECIRCULATION (IFGR) AND STAGED FUEL GAS ULTRA LOW-NOX BURNERS TO CONTROL NOX EMISSIONS. THE BURNER TECHNOLOGY INSTALLED WILL USE THE FUEL GAS MOMENTUM TO INSPIRATE HOT FLUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 12.5700 LB/H Emission Limit 2: 319.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5100 LB/H Emission Limit 2: 18.9900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 14.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PYROLYSIS FURNACE (1057-1062, 1091) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: FUEL GAS Throughput: 250.00 MMBTU/h

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.5400 LB/H Emission Limit 2: 319.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5100 LB/H Emission Limit 2: 18.9900 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 14.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.7100 LB/H Emission Limit 2: 27.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 19.2900 LB/H Emission Limit 2: 720.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (B) THE PYROLYSIS FURNACES WILL USE INTERNAL FLUE GAS RECIRCULATION (IFGR) AND STAGED FUEL GAS ULTRA LOW-NOX BURNERS TO CONTROL NOX EMISSIONS. THE BURNER TECHNOLOGY INSTALLED WILL USE THE FUEL GAS MOMENTUM TO INSPIRATE HOT FLUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PYROLYSIS FURNACE (N1011-1012) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 250.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.3100 LB/HEmission Limit 2: 10.1300 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 18.7500 LB/H Emission Limit 2: 65.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) THE PYROLYSIS FURNACES WILL USE INTERNAL FLUE GAS RECIRCULATION (IFGR) AND STAGED FUEL GAS ULTRA LOW-NOX BURNERS TO CONTROL NOX EMISSIONS. THE BURNER TECHNOLOGY INSTALLED WILL USE THE FUEL GAS MOMENTUM TO INSPIRATE HOT FLUE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.7500 LB/H Emission Limit 2: 28.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9900 LB/H Emission Limit 2: 4.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.4100 LB/H Emission Limit 2: 1.7800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE (1067) Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 7.5500 LB/H Emission Limit 2: 33.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.9200 LB/H Emission Limit 2: 8.3900 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 13.8400 LB/H Emission Limit 2: 60.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE (1087) Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1400 LB/H Emission Limit 2: 0.5100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.4500 LB/H Emission Limit 2: 6.3400 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 12.4200 LB/H Emission Limit 2: 54.3800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.4300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIESEL EMERGENCY GENERATOR (N7900LJD) Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: DIESEL Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 9.1300 LB/H Emission Limit 2: 0.1200 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.5200 LB/H Emission Limit 2: 0.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/AControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4900 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.8500 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: REGENERATION HEATER Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.6600 LB/H Emission Limit 2: 0.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/AControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.6700 LB/H Emission Limit 2: 0.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SECOND STAGE FEED HEATER Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/AControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2400 LB/H Emission Limit 2: 1.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0110 LB/H Emission Limit 2: 0.4800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE (8003B)PROCESS NAME: FLARE (8003B)

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.2100 LB/H Emission Limit 2: 4.2400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.8000 LB/H Emission Limit 2: 4.9300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.6000 LB/H Emission Limit 2: 9.8300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility InformationRBLC ID: 

## TX-0492 (final) Date Determination Last Updated: 08/17/2007 Corporate/Company Name: VIRTEX PETROLEUM INC. Permit Number: P1041

Facility Name: VIRTEX PETROLEUM COMPANY DOERING RANCH GAS PLANT Permit Date: 05/05/2005 (actual) Facility Contact: MR. DALE PHIPPS FRS Number: UNKNOWN Facility Description: VIRTEX CURRENTLY OPERATES A GAS PLANT WHICH IS AUTHORIZED UNDER AN OIL AND GAS

STANDARD PERMIT. THE MAXIMUM PRODUCTION IS CURRENTLY AUTHORIZED AT 0.3 LONG TONS PER DAY OF SULFUR. THEY ARE REQUESTING AUTHORIZATION TO MODIFY THE EXISTING FACILITY TO PROCESS SOUR GAS FROM NEW FIELD WELLS AND INCREASE MAXIMUM PRODUCTION TO 0.75 LONG TONS PER DAY OF SULFUR (4.0 MMSDFD OF GAS WITH AN H2S CONTENT OF 8.000 PPM). MODIFICATIONS INCLUDE THE INSTALLATION OF NEW COMPRESSORS, AUTHORIZING AN AMINE SWEETENING UNIT, A LARGER CAPACITY GLYCOL DEHYDRATOR, AND ALL ASSOCIATED PIPING. THE INCREASE IN SO2 REQUIRES PSD ANALYSIS. SIC Code: 2911

Permit Type: C: Modify process at existing facility NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: FRIO Facility State: TX Facility ZIP Code: 780170230 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: PERMIT ENGINEER: ANNA DE LA GARZA

Permit Notes: Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide -4.7400 (Tons/Year) Nitrogen Oxides (NOx) -34.3000 (Tons/Year) Particulate Matter (PM) 0.3000 (Tons/Year) Sulfur Oxides (SOx) 370.2000 (Tons/Year) Volatile Organic Compounds (VOC) -3.8700 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: AJAX DPC-115 COMPRESSOR ENGINE Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary Fuel: GAS Throughput: 0.75 LTPD

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.7300 LB/H Emission Limit 2: 3.1900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5300 LB/H Emission Limit 2: 2.3400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3400 LB/H Emission Limit 2: 1.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOWERED THROUGHPUT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 3 AJAX DPC-360LE COMPRESSOR ENGINES Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 0.75 LTPD

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.5300 LB/H Emission Limit 2: 6.6800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.7600 LB/H Emission Limit 2: 3.3400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.7600 LB/H Emission Limit 2: 3.3400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.6400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOWER THROUGHPUT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 1.8 MMBTU AMINE REBOILER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: SWEET NATURAL GAS Throughput: 1.80 MMBTUProcess Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1700 LB/H Emission Limit 2: 0.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.6400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 1.0 MMBTU DEHY REBOILER Process Type: 12.290 (Other Liquid Fuel & Liquid Fuel Mixtures) Primary Fuel: SWEET NATURAL GAS Throughput: 1.00 MMBtu

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.4200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.3600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0300 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FACILITY FLARE-AMINE UNIT STILL VENT Process Type: 19.330 (Refinery Flares) Primary Fuel: SWEET NATURAL GAS Throughput: 0.75 LTPD

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1900 LB/H Emission Limit 2: 0.8500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.6600 LB/H Emission Limit 2: 7.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.7200 LB/H Emission Limit 2: 3.1600 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 140.5000 LB/H Emission Limit 2: 615.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.4900 LB/H Emission Limit 2: 6.5500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LOADING LOSSES Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: SWEET NATURAL GAS Throughput: 0.75 LTPD

Process Notes: LOADING EMISSIONS ARE .58 TPY DUE TO VAPOR PRESSURE OF .5 PSIA

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.1600 LB/H Emission Limit 2: 0.2900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.0100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES (4)

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: SWEET NATURAL GAS Throughput:

Process Notes: TOTAL UNCONTROLLED FUGITIVE EMISSIONS ARE LESS THAN 10 TPY, SO NO MONITORING IS REQUIRED. THE COMPANY WILL

IMPLEMENT DAILY WALKTHROUGHS TO INSPECT THE PIPING. THERE ARE ALSO H2S MONITORS ON SITE TO CAPTURE ANY H2S LEAKS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8800 LB/H Emission Limit 2: 3.8500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0478 (final) Date Determination Last Updated: 10/01/2007 Corporate/Company Name: CITGO REFINING AND CHEMICALS COMAPNY LP Permit Number: PSD-TX-408M3 Facility Name: CITGO CORPUS CHRISTI REFINERY - WEST PLANT Permit Date: 04/20/2005 (actual) Facility Contact: MIKE SIDES 3618445325 FRS Number: 110000505640 Facility Description: SIC Code: 2869 Permit Type: U: Unspecified NAICS Code: 325110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: NUECES Facility State: TX Facility ZIP Code: 78409 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: VOLATILE ORGANIC COMPOUND LIQ. - 2 TANKS AMINE AREA - METHYL DIETHYL AMINE: .O2 LB/H AND Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 180.5100 (Tons/Year)Nitrogen Oxides (NOx) -33.9100 (Tons/Year) Particulate Matter (PM) 4.0300 (Tons/Year) Sulfur Oxides (SOx) -22.7500 (Tons/Year) Volatile Organic Compounds (VOC) 250.0700 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: DHT CHARGER HEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters)

Primary Fuel: Throughput:

Process Notes: THE MDH UNIT REMOVES ORGANIC NITROGEN AND SULFUR FROM THE FEED STREAMS. FEEDSTOCK IS MIXED WITH HYDROGEN

, HEATED, AND FED TO A REACTOR. A CATALYTIC REACTION CONVERTS THE ORGANIC SULFUR TO HYDROGEN SULFIDE AND THE NITROGEN COMPOUNDS TO AMMONIA. THE EFFLUENT STREAM IS COOLED AND EXCESS HYDROGEN REMOVED FOR RECYCLE. HYDROGEN SULFIDE IS REMOVED FROM THE HYDROGEN STREAM BY AN AMINE ABSORBER AND ROUTED TO THE SRU. NEW EQUIPMENT UNDER THE AMENDMENT INCLUDES A SECOND REACTOR, ADDITIONAL PREHEAT TRAIN, AN ADDITIONAL REACTOR PRODUCT FLASH DRUM, A HYDROGEN PURIFICATION MEMBRANE AND AN ADDITIONAL HYDROGEN MAKEUP COMPRESSOR. AS PART OF THE AMENDMENT, THE FRACTIONATOR REBOILER WILL BE RETROFIT WITH LOW NOX BURNERS.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.1000 LB/H Emission Limit 2: 8.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5100 LB/H Emission Limit 2: 2.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.8000 LB/H Emission Limit 2: 31.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 3.3000 LB/H Emission Limit 2: 13.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS TO REACH .035 LBNOX/MMBTU Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7100 LB/H Emission Limit 2: 2.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DHT STRIPPER REBOILER

Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary REFINERY FUEL GASPrimary

Fuel: REFINERY FUEL GAS

Throughput:

Process Notes: THE MDH UNIT REMOVES ORGANIC NITROGEN AND SULFUR FROM THE FEED STREAMS. FEEDSTOCK IS MIXED WITH HYDROGEN

, HEATED, AND FED TO A REACTOR. A CATALYTIC REACTION CONVERTS THE ORGANIC SULFUR TO HYDROGEN SULFIDE AND THE NITROGEN COMPOUNDS TO AMMONIA. THE EFFLUENT STREAM IS COOLED AND EXCESS HYDROGEN REMOVED FOR RECYCLE. HYDROGEN SULFIDE IS REMOVED FROM THE HYDROGEN STREAM BY AN AMINE ABSORBER AND ROUTED TO THE SRU. NEW EQUIPMENT UNDER THE AMENDMENT INCLUDES A SECOND REACTOR, ADDITIONAL PREHEAT TRAIN, AN ADDITIONAL REACTOR PRODUCT FLASH DRUM, A HYDROGEN PURIFICATION MEMBRANE AND AN ADDITIONAL HYDROGEN MAKEUP COMPRESSOR. AS PART OF THE AMENDMENT, THE FRACTIONATOR REBOILER WILL BE RETROFIT WITH LOW NOX BURNERS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.0000 LB/H Emission Limit 2: 28.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.0000 LB/H Emission Limit 2: 12.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6400 LB/H Emission Limit 2: 2.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.9000 LB/H Emission Limit 2: 7.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4700 LB/H Emission Limit 2: 1.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKER HEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput: 291.00 MMBUT/H

Process Notes: THE COKER UNIT USES THERMAL CRACKING TO UPGRADE HEAVY BOTTOM STREAMS TO DISTILLATES. THE OVERHEAD

PRODUCTS ARE SENT TO A FRACTIONATOR FOR ADDITIONAL SEPARATION. A COMBINATION OF COMPRESSION, ADSORPTION, STRIPPING AND DISTILLATION PRODUCES THE FOLLOWING PRODUCT STREAMS: LPG/ALKY FEED, GASOLINE, NAPHATHA, KEROSENE, LIGHT COKER GAS OIL, HEAVY COKER GAS OIL AND FUEL GAS. THE COKER UNIT ALSO PRODUCES A SOLID PETROLEUM COKE PRODUCT WHICH IS STEAM CUT FROM THE COKE DRUMS ONTO A COKE PAD. THIS UNIT IS UNAFFECTED BY THE AMENDMENT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 23.9000 LB/H Emission Limit 2: 104.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 52.3100 LB/H Emission Limit 2: 229.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.2000 LB/H Emission Limit 2: 9.5000 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 6.6000 LB/H Emission Limit 2: 28.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6000 LB/H Emission Limit 2: 6.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MIXED DISTILLATE HYDROHEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters)

Primary Fuel: Throughput: 62.00 MMBTU/H

Process Notes: THE MDH UNIT REMOVES ORGANIC NITROGEN AND SULFUR FROM THE FEED STREAMS. FEEDSTOCK IS MIXED WITH HYDROGEN

, HEATED, AND FED TO A REACTOR. A CATALYTIC REACTION CONVERTS THE ORGANIC SULFUR TO HYDROGEN SULFIDE AND THE NITROGEN COMPOUNDS TO AMMONIA. THE EFFLUENT STREAM IS COOLED AND EXCESS HYDROGEN REMOVED FOR RECYCLE. HYDROGEN SULFIDE IS REMOVED FROM THE HYDROGEN STREAM BY AN AMINE ABSORBER AND ROUTED TO THE SRU. NEW EQUIPMENT UNDER THE AMENDMENT INCLUDES A SECOND REACTOR, ADDITIONAL PREHEAT TRAIN, AN ADDITIONAL REACTOR PRODUCT FLASH DRUM, A HYDROGEN PURIFICATION MEMBRANE AND AN ADDITIONAL HYDROGEN MAKEUP COMPRESSOR. AS PART OF THE AMENDMENT, THE FRACTIONATOR REBOILER WILL BE RETROFIT WITH LOW NOX BURNERS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.1000 LB/H Emission Limit 2: 22.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 7.4000 LB/H Emission Limit 2: 32.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4600 LB/H Emission Limit 2: 2.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 1.4000 LB/H Emission Limit 2: 6.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 99.800 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3300 LB/H Emission Limit 2: 1.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MIXED DISTILLATE HYDROHEATER REBOILER HEATER

Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary REFINERY FUEL GASPrimary

Fuel: REFINERY FUEL GAS

Throughput: 82.00 MMBTU/H

Process Notes: THE MDH UNIT REMOVES ORGANIC NITROGEN AND SULFUR FROM THE FEED STREAMS. FEEDSTOCK IS MIXED WITH HYDROGEN

, HEATED, AND FED TO A REACTOR. A CATALYTIC REACTION CONVERTS THE ORGANIC SULFUR TO HYDROGEN SULFIDE AND THE NITROGEN COMPOUNDS TO AMMONIA. THE EFFLUENT STREAM IS COOLED AND EXCESS HYDROGEN REMOVED FOR RECYCLE. HYDROGEN SULFIDE IS REMOVED FROM THE HYDROGEN STREAM BY AN AMINE ABSORBER AND ROUTED TO THE SRU. NEW EQUIPMENT UNDER THE AMENDMENT INCLUDES A SECOND REACTOR, ADDITIONAL PREHEAT TRAIN, AN ADDITIONAL REACTOR PRODUCT FLASH DRUM, A HYDROGEN PURIFICATION MEMBRANE AND AN ADDITIONAL HYDROGEN MAKEUP COMPRESSOR. AS PART OF THE AMENDMENT, THE FRACTIONATOR REBOILER WILL BE RETROFIT WITH LOW NOX BURNERS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4400 LB/H Emission Limit 2: 1.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.8000 LB/H Emission Limit 2: 29.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 9.9000 LB/H Emission Limit 2: 43.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6100 LB/H Emission Limit 2: 2.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 5.7000 LB/H Emission Limit 2: 25.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 99.800 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SOUR WATER STRIPPER FLARE

Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: THE SOUR WATER STRIPPER FLARE AND AMINE FLARE WERE PREVIOUSLY LISTED AS FOR EMERGENCY USE ONLY. THE

EMISSIONS FROM THESE FLARES WILL NOW REFLECT EMISSIONS FROM THE PILOTS. THE COKER BLOWDOWN FLARE HANDLES A PROCESS STREAM FROM THE COKER UNIT AND NON-ROUTINE EMISSIONS. THE CHANGES TO THESE FLARES ARE PART OF THE PERMIT AMENDMENT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.1000 LB/H Emission Limit 2: 5.0000 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.1900 LB/H Emission Limit 2: 0.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: 99.800 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.9000 LB/H Emission Limit 2: 8.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 1.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: SOUR WATER TANK Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2000 LB/H Emission Limit 2: 0.8800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 17.9000 LB/H Emission Limit 2: 2.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE-COKE DRUM BLOWDOWN Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: THE COKER BLOWDOWN FLARE HANDLES A PROCESS STREAM FROM THE COKER UNIT AND NON-ROUTINE EMISSIONS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 43.2000 LB/H Emission Limit 2: 12.1000 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 11.5000 LB/H Emission Limit 2: 1.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 8.5000 LB/H Emission Limit 2: 2.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1056.0000 LB/H Emission Limit 2: 116.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 27.9000 LB/H Emission Limit 2: 8.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: TAIL GAS INCINERATOR

Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput: 100.00 MMBTU/H

Process Notes: THE OVERALL SULFUR RECOVERY EFFICIENCY FOR THE SULFUR COMPLEX IS 99.8% AND THE TAIL GAS INCINERATOR WILL

NOT EXCEED AN SO2 CONCENTRATION OF 250 PPMV. EMISSIONS FROM THE SULFUR PIT ARE ROUTED TO THE TAIL GAS INCINERATOR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.9000 LB/H Emission Limit 2: 14.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbonyl Sulfide

CAS Number: 463-58-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 1.8000 LB/H Emission Limit 2: 4.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Disulfide

CAS Number: 75-15-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.3200 LB/H Emission Limit 2: 0.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5000 LB/H Emission Limit 2: 1.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.5000 LB/H Emission Limit 2: 9.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1900 LB/H Emission Limit 2: 0.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 22.4000 LB/H Emission Limit 2: 53.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.3000 LB/H Emission Limit 2: 5.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACID GAS FLARE Process Type: 19.310 (Chemical Plant Flares)Primary Fuel:

Throughput:

Process Notes: THE FLARES HAVE A MINIMUM DRE OF 98% AND ARE EQUIPPED WITH CONTINUOUS PILOTS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.6000 LB/H Emission Limit 2: 15.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2000 LB/H Emission Limit 2: 0.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.6000 LB/H Emission Limit 2: 2.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NO.3 BOILERProcess Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary Fuel: REFINERY FUEL GAS Throughput: 99.00 MMBTU/H

Process Notes: UTILITY BOILER 3 PRODUCES IS A 99 MMBTU/H HEAT INPUT BOILER FIRING REFINERY FUEL GAS WHICH IS USED TO

PRODUCE STEAM FOR USE IN A NUMBER OF REFINERY PROCESSES.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.1000 LB/H Emission Limit 2: 35.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 11.9000 LB/H Emission Limit 2: 52.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7400 LB/H Emission Limit 2: 3.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.2000 LB/H Emission Limit 2: 9.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5000 LB/H Emission Limit 2: 2.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STORAGE TANK 13A&B Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6000 LB/H Emission Limit 2: 3.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STORAGE TANKS 6020-6023 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4.4000 LB/H Emission Limit 2: 3.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STORAGE TANKS 6011-6012 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8000 LB/H Emission Limit 2: 1.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STORAGE TANK 6017-6019 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sodium Hydroxide

CAS Number: 1310-73-2 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MDHU FUGITIVES 2 Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 25.5000 LB/H Emission Limit 2: 111.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKE STORAGE AND HANDLING FACILITIES Process Type: 42.999 (Other Liquid Marketing Sources) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 3.3000 LB/H Emission Limit 2: 14.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SRU PROCESS FUGITIVES (4) Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.2000 LB/H Emission Limit 2: 5.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2600 LB/H Emission Limit 2: 1.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKER UNIT FUGITIVES (4)PROCESS NAME: COKER UNIT FUGITIVES (4)

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 35.8000 LB/H Emission Limit 2: 157.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8000 LB/H Emission Limit 2: 3.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: WP MEROX FUGITIVES Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 8.5000 LB/H Emission Limit 2: 37.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/AOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DHT FUGITIVES Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.7000 LB/H Emission Limit 2: 24.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/HEmission Limit 2: 0.0200 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## AZ-0046 (final) Date Determination Last Updated: 08/25/2006 Corporate/Company Name: ARIZONA CLEAN FUELS YUMA LLC Permit Number: 1001205 Facility Name: ARIZONA CLEAN FUELS YUMA Permit Date: 04/14/2005 (actual) Facility Contact: GLENN MCGINNIS GLENN@REFINERY.ORG FRS Number: 1100200580460 Facility Description: OIL REFINERY SIC Code: 2911Permit Type: A: New/Greenfield Facility NAICS Code: 320000

Permit URL: EPA Region: 9 COUNTRY: USA Facility County: YUMA Facility State: AZ Facility ZIP Code: 85352 Permit Issued By: ARIZONA DEPT OF ENV QUAL, OFC OF AIR QUA (Agency Name) BALAJI VAIDYANATHAN(Agency Contact) (602) 771-4527 TB4@AZDEQ.GOV Permit Notes: Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: INTL BORDER US/Mexico Border < 100 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 816.9600 (Tons/Year) Nitrogen Oxides (NOx) 395.5400 (Tons/Year) Particulate Matter (PM) 181.9200 (Tons/Year) Sulfur Oxides (SOx) 250.6600 (Tons/Year) Volatile Organic Compounds (VOC) 250.9700 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: ATMOSPHERIC CRUDE CHARGE HEATER Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: NATURAL GAS OR REFINERY FUEL GAS Throughput: 346.00 MMBTU/H

Process Notes: THIS UNIT IS IDENTIFIED AS EQUIPMENT # B-01300

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU THREE-HOUR ROLLING AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU THREE-HOUR ROLLING AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU THREE HOUR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU THREE HOUR AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD @ 0% OXYGEN THREE-HOUR ROLLING AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) 35 PPM SULFUR LIMIT IN FUEL. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 35 PPMV SULFUR LIMIT, AS H2S, IS A RESTRICTION ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS BEING FIRED IN THE UNIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU THREE HOUR ROLLING AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU THREE HOUR ROLLING AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: VACUUM CRUDE CHARGE HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NG Throughput: 101.00 MMBTU/H

Process Notes: THIS UNIT IS IDENTIFIED BY EQUIPMENT ID # B-02100

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD THREE-HOUR ROLLING AVG Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS 5.0 PPMVD BASED ON 0% OXYGEN

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU THREE-HOUR ROLLING AVG Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU THREE-HOUR ROLLING AVG Emission Limit 2: Standard Emission: 0.1250 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: THIS LIMIT IS FOR SULFUR, AS H2S, AND IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU THREE-HOUR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROCRACKER UNIT CHARGE HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NG Throughput: 70.00 MMBTU/H

Process Notes: THIS UNIT IS IDENTIFIED BY EQUIPMENT ID # B-10200

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY Emission Limit 2: Standard Emission: NOT AVAILABLEDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT FOR SULFUR, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0340 LB/MMBTU THREE-HOUR ROLLING AVG Emission Limit 2: Standard Emission: 0.0340 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU THREE-HOUR ROLLING AVG Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU THREE-HOUR AVG Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROCRACKER UNIT MAIN FRACTIONATOR HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NG Throughput: 211.00 MMBTU/H

Process Notes: THIS UNIT IS IDENTIFIED BY EQUIPMENT ID # B-10500

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2:Standard Emission: NOT AVAILABLE

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT ON SULFUR, AS H2S, IS A RESTRICTION ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU THREE-HOUR AVG Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0250 LB/MMBTU THREE HOUR ROLLING AVG Emission Limit 2: Standard Emission: 0.0250 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) LOW-NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU THREE-HOUR ROLLING AVG Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NAPHTHA HYDROTREATER CHARGE HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NG Throughput: 21.40 MMBTU/H

Process Notes: THIS UNIT IS IDENTIFIED BY EQUIPMENT ID # B-04200

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU THREE-HOUR ROLLING AVGEmission Limit 2:

Standard Emission: 0.0300 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW-NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: NSPS

Control Method: (P) S LIMITED TO 35 PPM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT ON SULFUR, AS H2S, IS A RESTRICTION ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU THREE-HOUR AVG Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CATALYTIC REFORMING UNIT CHARGE HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS AND NATURAL GAS Throughput: 122.00 MMBTU/H

Process Notes: THIS UNIT IS IDENTIFIED BY EQUIPMENT ID # B-05110

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVG.

Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN ON A 3-HR AVG. Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: NSPSControl Method: (P) SULFUR LIMITED TO 35 PPM IN FUEL.

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 35 PPMV SULFUR LIMIT, AS H2S, IS A RESTRICTION ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS BEING FIRED IN THE UNIT.



## Process/Pollutant Information

PROCESS NAME: CATALYTIC REFORMING UNIT INTERHEATER NO. 1 Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS AND NATURAL GAS Throughput: 192.00 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY EQUIPMENT ID # B-05120

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 35 PPMV SULFUR LIMIT, AS H2S, IS A RESTRICTION ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS BEING FIRED IN THE UNIT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE

Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HOUR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2:Standard Emission: 0.0400 LB/MMBTU

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN - 3-HR AVG. Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CATALYTIC REFORMING UNIT INTERHEATER NO. 2 Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 129.00 MMBTU/H

Process Notes: THIS EQUIPMENT IS IDENTIFIED BY ID # B-05130

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGEEmission Limit 2:

Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN - 3-HR AVERAGE Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CATALYTIC REFORMING UNIT DEBUTANIZER REBOILER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 23.20 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY ID # B-05609

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMIT OF 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0300 LB/MMBTU NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2:Standard Emission: 0.0400 LB/MMBTU

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CATALYST REGENERATOR V-05800 Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput:

Process Notes: REGENERATION OF CATALYST USING PERCHLOROETHYLENE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5000 LB/H 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VETest Method: Unspecified

Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Tetrachloroethylene

CAS Number: 127-18-4 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: DAILY AVERAGE RATIO OF PERCHLOROETHYLENE FEED RATE TO CATALYST CIRCULATION RATE (MAXIMUM) TO BE ESTABLISHED DURING THE PERFORMANCE TEST. THIS LIMIT DOES NOT APPLY DURING DEPRESSURING AND PURGING OPERATIONS WHEN THE REACTOR VENT PRESSURE IS 5 POUNDS PER SQUARE INCH OR LESS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 0.8200 LB/H 3-HR AVERAGE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DISTILLATE HYDROTREATER CHARGE HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 25.00 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY ID # B-08200

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0330 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0330 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DISTILLATE HYDROTREATER SPLITTER REBOILER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 117.00 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY ID # B-08509

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0320 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0320 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BUTANE CONVERSION UNIT DEHYDROGENATION REACTOR CHARGE HEATER Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 311.00 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY ID # B-15310

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) 35 PPM SULFUR LIMIT ON FUEL BURNED. Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN, 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BUTANE CONVERSION UNIT DEHYDROGENATION REACTOR INTERHEATERPROCESS NAME: BUTANE CONVERSION UNIT DEHYDROGENATION REACTOR INTERHEATER

Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FULE GAS OR NATURAL GAS Throughput: 328.00 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY ID # B-15320

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) SULFUR LIMIT OF 35 PPM IN FUEL BURNED. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN - 3 HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BUTANE CONVERSION UNIT ISOSTRIPPER REBOILER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS AND NATURAL GAS Throughput: 222.00 MMBTU/H

Process Notes: THIS EQUIPMENT IDENTIFIED BY ID # B-15110

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPSControl Method: (P) SULFUR LIMITED TO 35 PPM IN FUEL BURNED.

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN - 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: CATALYST REGENERATOR V-15340 Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput:

Process Notes: REGENERATION OF CATALYST USING PERCHLOROETHYLENE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.8200 LB/H 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0500 LB/H 3-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DELAYED COKING UNIT CHARGE HEATER NOS. 1 AND 2 Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 99.50 MMBTU/H

Process Notes: THESE TWO PEICES OF EQUIPMENT ARE IDENTIFIED BY ID #S B-14110A AND B-14110B

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0300 LB/MMBTUDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) FUEL LIMITED TO 35 PPM S.Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKE PAD AND COKE PIT Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITY ACROSS THE REFINERY'S PROPERTY BOUNDARY Emission Limit 2:Standard Emission: % OPACITY ACROSS THE REFINERY'S PROPERTY BOUNDARY

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) WATER SPRAY SYSTEMS, COMPLETELY WALLED ENCLOSURE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKE CRUSHER Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # H-14604

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITY Emission Limit 2: Standard Emission: % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) PARTIAL ENCLOSURE, WATER SPRAY SYSTEMS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: COKE CONVEYOR

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # H-14121

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITY Emission Limit 2: Standard Emission: % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) WATER SPRAY SYSTEM, FULL ENCLOSURE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE CONVEYOR SYSTEM IS ONLY PERMITTED TO HAVE 2 TRANSFER POINTS (FROM THE CRUSHER TO THE CONVEYOR AND FROM THE CONVEYOR TO THE SILO).



## Process/Pollutant Information

PROCESS NAME: COKE SILO Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # H-14607

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s):Emission Limit 1: % OPACITY NO VISIBLE EMISSIONS

Emission Limit 2: Standard Emission: % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) FABRIC FILTER, FULL ENCLOSURE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # S-28100

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.6000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) HIGH EFFICIENCY DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: STEAM BOILERS NOS. 1 AND 2 Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 419.00 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID #S S-20110 AND S-20120

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) LOW NOX BURNERS AND FLUE GAS RECIRCULATION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0160 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0160 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GROUP B STORAGE TANKS

Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput:

Process Notes: THIS GROUP OF TANKS INCLUDES 47 DIFFERENT TANKS RANGING IN SIZE FROM 378,000 GALLONS CAPACITY TO 7,560,000

GALLONS CAPACITY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Applicable Requirements: Control Method: (B) INTERNAL FLOATING ROOFS WITH HEADSPACE ROUTED TO THE TANK FARM THERMAL OXIDIZER. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THERE IS NO NUMERICAL EMISSIONS LIMIT FOR GROUP A TANKS SINCE THE EMISSIONS MUST BE COLLECTED AND NOT EMITTED INTO THE ATMOSPHERE.



## Process/Pollutant Information

PROCESS NAME: HYDROGEN REFORMER HEATERProcess Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 1435.00 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID # B-07200

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.0000 PPMVD CORRECTED TO 0.0% OXYGEN - 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) S LIMITED TO 35 PPM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0125 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0125 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE INITIAL LIMIT FOR NOX IS 0.0125 LB PER MMBTU HEAT INPUT (HHV). AFTER THE FIRST 24 MONTHS, A NEW LIMIT IS TO BE ESTABLISHED BASED ON THE PERFORMANCE OF THE UNIT. A LIMIT OF 0.006 LB PER MMBTU MAY BE TAKEN WITHOUT REGARD TO THE UNIT PERFORMANCE.



## Process/Pollutant Information

PROCESS NAME: FIRE WATER PUMPS NOS 1 AND 2 Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: NO. 2 DIESEL FUEL Throughput: 5.46 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID #S S-29200A AND S29200B

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 4.0000 G/KW-H Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS FOR NOX PLUS NONMETHANE HYDROCARBONS. THE ENGINES MUST BE CERTIFIED BY THE MANUFACTURER TO MEET THIS LIMIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.5000 G/KW-H Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE ENGINES MUST BE CERTIFIED BY THE MANUFACTURER TO MEET THIS LIMIT.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2000 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE ENGINES MUST BE CERTIFIED BY THE MANUFACTURER TO MEET THIS LIMIT.

## Process/Pollutant Information

PROCESS NAME: EMERGENCY GENERATOR Process Type: 17.110 (Fuel Oil (ASTM # 1,2, includes kerosene, aviation, diesel fuel)) Primary Fuel: NO. 2 DIESEL FUEL Throughput: 10.90 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID # S-29100

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.5000 G/KW-H Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE ENGINE MUST BE CERTIFIED BY THE MANUFACTURER TO MEET THIS LIMIT.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 G/KW-H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE ENGINE MUST BE CERTIFIED BY THE MANUFACTURER TO MEET THIS LIMIT.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.4000 G/KW-H Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS LIMIT IS FOR NOX PLUS NONMETHANE HYDROCARBONS. THE ENGINE MUST BE CERTIFIED BY THE MANUFACTURER TO MEET THIS LIMIT.



## Process/Pollutant Information

PROCESS NAME: EMERGENCY FLARES Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: NATURAL GAS Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID #S S-27100 AND S-27200. THE FLARES WILL HAVE A NATURAL GAS PILOT.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITYEmission Limit 2:

Standard Emission: % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE FLARES MUST BE DESIGNED AND OPERATED WITH NO VISIBLE EMISSIONS.



## Process/Pollutant Information

PROCESS NAME: SPRAY DRYER HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 44.00 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID # E-26502

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: 0.0300 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE

Emission Limit 2: Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SPRAY DRYER Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0050 GR/DSCF 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GROUP E STORAGE TANKS Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # 42801 3.15 MILLION GALLONS STORAGE CAPACITY, STORING ASPHALT

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THE EXHAUST GASES FROM THIS STORAGE TANK MUST BE COOLED TO 120 DEGREES FControl Method: (A) THE EXHAUST GASES FROM THIS STORAGE TANK MUST BE COOLED TO 120 DEGREES F AND THEN VENTED TO A FIBERGLASS OR STEEL WOOL FILTER SYSTEM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THERE IS NO NUMERICAL EMISSIONS LIMIT FOR GROUP A TANKS SINCE THE EMISSIONS MUST BE COLLECTED AND NOT EMITTED INTO THE ATMOSPHERE.



## Process/Pollutant Information

PROCESS NAME: TANK FARM THERMAL OXIDIZER

Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: REFINERY FUEL GAS AND GASES FROM TANKS Throughput:

Process Notes: THE THERMAL OXIDIZER IS ONLY PERMITTED TO FIRE NATURAL GAS, REFINERY FUEL GAS, AND THE GASES VENTED FROM

THE STORAGE TANKS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 99.9000 % DESTRUCTION THIS IS A DESIGN STANDARD Emission Limit 2: 20.0000 PPMV MAX OUTLET CONC. WHEN INLET Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE 20 PPMV LIMITS APPLIES WHEN THE INLET CONCENTRATION OF THE THERMAL OXIDIZER IS LESS THAN 20,000 PPMV. THE OXIDIZER MUST BE DESIGNED AT OPERATED SUCH THAT THE COMBUSTION CHAMBER IS AT LEAST 1600 DEGREES F (OR HIGHER DEPENDING BASED ON A PERFORMANCE TEST) ON A 5-MINUTE AVERAGE. A MAXIMUM FLOW RATE WILL ALSO BE ESTABLISHED DURING PERFORMANCE TESTING.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.0075 LB/MMBTU 3-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GROUP A STORAGE TANKS

Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes: THE GROUP A TANKS CONSIST OF SEVERAL TANKS (3.78 MILLION GALLONS TO 1.51 MILLION GALLONS) CONTAINING

PETROLEUM LIQUIDS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE THE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THE EMISSIONS FROM GROUP A STORAGE TANKS MUST BE COLLECTED BY A VAPOR COMPRESSION SYSTEM AND ROUTED TO THE REFINERY FUEL GAS SYSTEM. NO EMISSIONS ARE PERMITTED TO BE RELEASED INTO THE AIR EXCEPT FOR EQUIPMENT LEAKS.Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: THERE IS NO NUMERICAL EMISSIONS LIMIT FOR GROUP A TANKS SINCE THE EMISSIONS MUST BE COLLECTED AND NOT EMITTED INTO THE ATMOSPHERE.



## Process/Pollutant Information

PROCESS NAME: GROUP D STORAGE TANKS

Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes: GROUP D STORAGE TANKS ARE SIX 850,000 GALLON TANKS STORING LIQUIFIED PETROLEUM GAS, BUTANE/BUTYLENE, OR

OTHER PETROLEUM LIQUIDS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE TANKS ARE REQUIRED TO BE UNDER PRESSURE SO THAT NO EMISSIONS ARE EMITTED TO THE ATMOSPHERE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE TANKS ARE REQUIRED TO BE UNDER PRESSURE SO THAT NO EMISSIONS ARE EMITTED TO THE ATMOSPHERE.



## Process/Pollutant Information

PROCESS NAME: WASTEWATER TREATMENT PLANT THERMAL OXIDIZERProcess Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006))

Primary Fuel: NATURAL GAS OR REFINERY FUEL GAS Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 99.9000 % DESTRUCTION DESIGN STANDARD Emission Limit 2: 20.0000 PPMV WHEN INLET IS LESS THAN 20,000 PPMV Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE THERMAL OXIDIZER IS REQUIRED TO MAINTAIN A 1600 DEGREE F TEMPERATURE OR HIGHER AS DETERMINED BY A PERFORMANCE TEST. THE PERFORMANCE TEST WILL ALSO ESTABLISH A MAXIMUM FLOW RATE THROUGH THE OXIDIZER.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 35.0000 PPMV DAILY AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (P) 35 PPM SULFUR LIMIT IN FUEL. Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTRATION OF THE REFINERY FUEL GAS.



## Process/Pollutant Information

PROCESS NAME: EQUIPMENT LEAKS

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: REQUIERMENTS FOR EQUIPMENT LEAKS ARE APPLICABLE TO PIPING AND COMPONENTS IN VOC, ORGANIC HAP, AND H2S

SERVICE THROUGHOUT THE REFINERY. GENERAL BACT REQUIREMENTS INCLUDE: ALL PIPING, VALVES, PUMP SYSTEMS, AND COMPRESSOR SYSTEMS SHALL CONFORM TO APPLICABLE ANSI, API, ASME OR EQUIVALENT CODES. UNDER GROUND PROCESS PIPELINES SHALL CONTAIN NO BURIED VALVES SUCH THAT FUGITIVE EMISSINO MONITORING IS RENDERED IMPRACTICAL. AND ALL VALVES AND PIPING CONNECTIONS MUST BE LOCATED TO BE REASONABLY ACCESSIBLE FOR LEAK-CHECKING DURING PLANT OPERATION (AS POSSIBLE).

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE REQUIREMENTS OF THE HON SUBPART H LDAR PROGRAM HAVE BEEN DEEMED TO BE BACT. IN ADDITION, THE FOLLOWING LEAK DEFINITIONS HAVE BEEN INCLUDED: 100 PPMV FOR VALVES AND CONNECTORS IN GAS/VAPOR AND LIGHT LIQUID SERVICE AND 500 PPMV FOR ALL OTHER COMPONENTS. ALL PUMPS MUST BE EQUIPPED WITH A SHAFT SEALING SYSTEM THAT PREVENTS OR DETECTS EMISSIONS OF VOC FROM THE SEAL. ALLCOMPRESSORS MUST BE EQUIPPED WITH A SEAL SYSTEM THAT INCLUDES A BARRIER FLUID SYSTEM THAT PREVENTS LEACKAGE OF PROCESS FLUID TO THE ATMOSPHERE. OTHER REQUIREMENTS EXIST FOR OTHER CONNECTOR TYPES AND VALVES. THE PERCENT OF LEAKING COMPONENTS CANNOT EXCEED THE FOLLOWING: 1.0% FOR PUMPS IN LIGHT LIQUID SERVICE AND COMPRESSORS ON A SOURCE-WIDE BASIS, 1.0% FOR THE TOTAL NUMBER OF PRESSURE RELIEF DEVICES ON A SOURCE-WIDE BASIS, 0.3% FOR TOTAL NUMBER OF CONNECTORS IN GAS/VAPOR SERVICE AND CONNECTORS IN LIGHT LIQUID SERVICE ON A SOURCE-WIDE BASIS, 0.3% OF THE TOTAL NUMBER OF VALVES IN GAS/VAPOR SERVICE AND VALVES IN LIGHT LIQUID SERVICE ON A SOURCE-WIDE BASIS, AND NOT MORE THAN 0.025% OF VALVES IN GAS/VAPOR SERVICE AND VALVES IN LIGHT LIQUID SERVICE SHALL BE LEAKING WITH A CONCENTRATION IN EXCESS OF 10,000 PPMV.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE SOURCE IS REQUIRED TO INSTALL, CERTIFY, OPERATE, AND MAINTAIN A NETWORK OF H2S CONCENTRATION MONITORS AT THE FACILITY BOUNDARY. THE SOURCE MUST ALSO SUMIT AN H2S MONTORING PLAN. IN ADDITION, AUDIO, OLFACTORY, AND VISUAL CHECKS FOR H2S LEAKS WITHIN EACH OPERATING AREA CONTAINING EQUIPMENT IN H2S SERVICE ONCE PER SHIFT. CORRECTIVE ACTION MUST BE TAKEN IMMEDIATELY, AND NO LATER THAN ONE HOUR UPON DETECTION OF A LEAK.



## Process/Pollutant Information

PROCESS NAME: AMINE REGENERATOR Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel:Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # V-12110

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT REQUIRES ALL GASES DISCHARGED FROM THE AMINE REGENERATOR CONTAINING VOC MUST BE ROUTED TO THE SULFUR RECOVERY PLANT FOR DESTRUCTION. NO EMISSION LIMITS GIVEN.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT REQUIRESALL GASES DISCHARGED FROM THE AMINE REGENERATOR CONTAINING H2S MUST BE ROUTED TO THE SULFUR RECOVERY PLANT.

## Process/Pollutant Information

PROCESS NAME: SOUR WATER STRIPPER Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # V-11120

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL GASES DISCHARGED FROM THE SOUR WATER STIPPER CONTAINING VOC MUST BE ROUTED TO THE SULFUR RECOVERY PLANT.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL GASES DISCHARGED FROM THE SOUR WATER STIPPER CONTAINING H2S MUST BE ROUTED TO THE SULFUR RECOVERY PLANT.



## Process/Pollutant Information

PROCESS NAME: SOUR WATER FLASH DRUM Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # V-11100

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL GASES DISCHARGED FROM THE SOUR WATER FLASH DRUM CONTAINING VOC MUST BE ROUTED TO THE SULFUR RECOVERY PLANT THERMAL OXIDIZER.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL GASES DISCHARGED FROM THE SOUR WATER FLASH DRUM CONTAINING H2S MUST BE ROUTED TO THE SULFUR RECOVERY PLANT THERMAL OXIDIZER.



## Process/Pollutant Information

PROCESS NAME: SOUR WATER TANK Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID # T-11100

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (B) FIXED ROOF TANK WITH INTERNAL FLOATING ROOF. HEAD SPACE ROUTED TO A CARBON ADSORPTION SYSTEM. Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: RACT IS FIXED ROOF TANK WITH INTERNAL FLOATING ROOF. HEAD SPACE ROUTED TO A CARBON ADSORPTION SYSTEM.



## Process/Pollutant Information

PROCESS NAME: SULFER PIT NOS. 1 AND 2 Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID #S T-13150 AND T13250

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 33.5000 LB/H 1-HR ROLLING AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT Control Method: (A) ALL GASES DISCHARGED FROM THE SULFUR PITS MUST BE COLLECTED AND ROUTED TO THE FRONT OF EITHER SULFER RECOVERY UNIT 1 OR UNIT 2. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE SULFUR LIMIT IS FOR ANY GASES FROM THE SULFUR RECOVERY PLANT.



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNITS 1 AND 2

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:Throughput:

Process Notes: THESE UNITS ARE THREE-STAGE CLAUSE SULFUR RECOVERY UNITS. EQUIPMENT IDENTIFIED BY ID #S B-13120, V-13130,

V-13140 AND B-13220, V-13230, V-13240

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 33.5000 LB/H 1-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT Control Method: (A) ALL GASES DISCHARGED FROM THE SULFUR RECOVERY UNITS MUST BE COLLECTED AND ROUTED TO THE FRONT OF EITHER SULFER RECOVERY UNIT 1 OR UNIT 2. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE SULFUR LIMIT IS FOR ANY GASES FROM THE SULFUR RECOVERY PLANT.



## Process/Pollutant Information

PROCESS NAME: TAIL GAS TREATMENT UNIT Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 33.5000 LB/H 1-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLEDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT Control Method: (A) ALL GASES DISCHARGED FROM THE TAIL GAS TREATMENT UNIT MUST BE ROUTED TO THE SULFUR RECOVERY PLANT THERMAL OXIDIZER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE SULFUR LIMIT IS FOR ANY GASES FROM THE SULFUR RECOVERY PLANT.



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY PLANT THERMAL OXIDIZER Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 100.00 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID # B-13500

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0890 LB/H 3-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/MMBTU 1-HR AVERAGE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 33.5000 LB/H 1-HR AVERAGE Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE SULFUR LIMIT IS FOR ANY GASES FROM THE SULFUR RECOVERY PLANT.



## Process/Pollutant Information

PROCESS NAME: SULFUR PRODUCT TRUCK AND RAIL CAR LOADING RACKS Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID #S Y-45401 AND Y-47801

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 15.0000 PPMW SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NOT PERMITTED TO LOAD ANY PRODUCT CONTAINING 15 PPM SULFUR OR MORE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE FACILITY IS NOT ALLOWED TO LOAD ANY SULFUR INTO ANY RAIL CAR OR TRUCK WHICH CONTAINS H2S IN EXCESS OF 15 PPWM.



## Process/Pollutant Information

PROCESS NAME: GASOLINE PRODUCT TRUCK LOADING RACKS Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: 45 LOADING RACKS, 600 GALLONS PER MINUTE PUMPING CAPACITY EACH.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) VAPOR COLLECTION SYSTEM, REGENERATIVE ADSORPTION SYSTEM AND TRUCK LOADING RACK THERMAL OXIDIZER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VAPORS DISPLACED FROM GASOLINE CARGO TANKS DURING GASOLINE PRODUCT LOADING MUST BE COLLECED BY A VAPOR COLLECTION SYSTEM AND ROUTED TO THE TRUCK LOADING RACK REGENERATIVE ADSORPTION SYSTEM.



## Process/Pollutant Information

PROCESS NAME: GASOLINE PRODUCT RAIL CAR LOADING RACKS Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: 45 LOADING RAGKS, PUMPLING CAPACITY OF 600 GPM EACH.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT Control Method: (N) VAPOR COLLECTION SYSTEM, REGENERATIVE ADSORPTION SYSTEM AND THERMAL OXIDIZER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VAPORS DISPLACED FROM GASOLINE CARGO TANKS DURING GASOLINE PRODUCT LOADINGPollutant/Compliance Notes: VAPORS DISPLACED FROM GASOLINE CARGO TANKS DURING GASOLINE PRODUCT LOADING MUST BE COLLECED BY A VAPOR COLLECTION SYSTEM AND ROUTED TO THE TRUCK LOADING RACK REGENERATIVE ADSORPTION SYSTEM.



## Process/Pollutant Information

PROCESS NAME: TRUCK AND RAIL CAR LOADING RACK REGENERATIVE ADSORPTION SYSTEMS Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EQUIPMENT IDENTIFIED BY ID #S S-47300 AND S-46300

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANTS NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: RACT REQUIRES EXHAUST FROM THE REGENERATIVE ADSORPTION SYSTEMS MUST BE ROUTED TO A THERMAL OXIDIZER (THE TRUCK LOADING RACK ADSORPTION SYSTEM TO THE TRUCK LOADING RACK THERMAL OXIDIZER AND THE RAIL CAR ADSORPTION SYSTEM TO THE RAIL CAL THERMAL OXIDIZER).



## Process/Pollutant Information

PROCESS NAME: DISTILLATE PRODUCT LOADING RACKS

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))Primary Fuel:

Throughput:

Process Notes: DISTILLATE PRODUCT TRUCK AND RAIL CAR LOADING RACKS. 15 LOADING RACKS FOR EACH (TRUCK AND RAIL CAR) EACH

WITH A CAPACITY OF 600 GALLONS PER MINITE. PRODUCTS TO BE LOADED INCLUDE JET AND DIESEL FUEL.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) VAPOR COLLECTION SYSTEM AND THERMAL OXIDIZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT REQUIRES THAT VAPORS DISPLACED FROM DISTILLATE PRODUCT LOADING MUST BE ROUTED TO A THERMAL OXIDIZER (TRUCK DISTILLATE LOADING GASES TO THE TRUCK LOADING RACK THERMAL OXIDIZER AND RAIL CAR DISTILLATE LOADING GASES TO THE RAIL CAL LOADING RACK THERMAL OXIDIZER).



## Process/Pollutant Information

PROCESS NAME: TRUCK AND RAIL CAR LOADING RACK THERMAL OXIDIZERS Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: REFINERY FUEL GAS OR NATURAL GAS Throughput: 12.30 MMBTU/H

Process Notes: EQUIPMENT IDENTIFIED BY ID #S S-47200 AND S-46200

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 35.0000 PPMV DAILY AVERAGE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS SULFUR LIMIT, AS H2S, IS A LIMIT ON THE INLET CONCENTATION OF THE REFINERY FUEL GAS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.2500 LB/MM GAL FOR GASOLINE RACKS-SEE POLLUTANT NOTES Emission Limit 2: 22.0000 LB/MM GAL FOR DISTILLATE RACKS-SEE POLLUTANT NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: FOR PERIODS WHEN A THERMAL OXIDIZER IS RECEIVING VAPORS FROM BOTH GASOLINE AND DISTILLATE LOADING RACKS, THE VOC EMISSIONS ARE LIMITED BASED UPON THE FOLLOWING EQUATION: ETOTAL = ELG*VG+ELD*VD. WHERE ETOTAL IS THE EMISSIONS LIMIT, ELG IS 1.25 POUNDS PER MMGAL, VG IS VOLUME OF PRODUCT LOADED AT THE GASOLINE RACKS (IN MMGAL), ELD IS 22.0 POUNDS PER MMGAS, AND VD IS VOLUME OF PRODUCT LOADED AT THE DISTILLATE RACKS (IN MMGAL). ALL LIMITS ARE ON A 3-HR AVERAGE.



## Process/Pollutant Information

PROCESS BENZENE WASTE OPERATIONSPROCESS

NAME: BENZENE WASTE OPERATIONS

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: THE PERMIT PRESENTS REQUIREMENTS THAT ARE APPLICABLE TO BENZENE-CONTAINING WASTE STREAMS THROUGHOUT

THE REFINERY.

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE POLLUTANT NOTES Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP Control Method: (N) SEE POLLUTANT NOTES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PERMIT CONTAINS VARIOUS BACT REQUIREMENTS FOR SEVERAL DIFFERENT TYPES OF EQUIPMENT INCLUDING TANKS, CONTAINERS, DRAIN SYSTEMS AND OTHERS. THEY ARE TOO NUMEROUS TO SPECIFY AND THE PERMIT SHOULD BE REVIEW TO SEE THE SPECIFIC CONDITIONS. MEETING THESE REQUIREMENTS IS BACT.



## Facility Information

RBLC ID: 

## TX-0487 (final) Date Determination Last Updated: 10/15/2007 Corporate/Company Name: ROHM AND HAAS TEXAS INCORPORATION Permit Number: PSD-TX-828M1

Facility Name: ROHM AND HAAS CHEMICALS LLC LONE STAR PLANT Permit Date: 03/24/2005 (actual)Facility Contact: ROBERT BRINLY 2812288100 FRS Number: 110000755193

Facility Description: THE N AREA PRODUCES ACETONE CYANOHYDRIN (ACH) AND HYDROGEN CYANIDE AND

PROVIDES INSTRUMENT AIR, NITROGEN, AMMONIA AND REFRIGERATED WATER TO OTHER OPERATING UNITS IN THE PLANT. THE N AREA HAS THREE PROCESS UNITS: THE HCN PROCESS, THE AMMONIA RECOVERY PROCESS, AND THE ACH PROCESS. IN THE HCN PROCESS, AMMONIA, NATURAL GAS AND AIR ARE REACTED TO FORM DILUTE HCN GAS. THE GAS IS PURIFIED AND THEN ABSORBED INTO ACIDIFIED WATER AND DISTILLED YIELDING A FINAL LIQUID HCN STREAM THAT IS 99% PURE. THE AMMONIA RECOVERY PROCESS RECOVERS AND PURIFIES UNREACTED AMMONIA FROM THE HCN REACTION. IN THE ACH PROCESS AREA, HCN IS REACTED WITH ACETONE TO FORM CRUDE ACH WHICH IS THEN PURIFIED. SIC Code: 2821

Permit Type: U: Unspecified NAICS Code: 325211 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: HARRIS Facility State: TX Facility ZIP Code: 775362416 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes:



## Process/Pollutant Information

PROCESS NAME: L-AREA GAS TURBINE

Process Type: 15.110 (Natural Gas (includes propane & liquified petroleum gas))

Primary Fuel: NATURAL GAS

Throughput:

Process Notes: THE PROPOSED N-AREA PRODUCTION INCREASE WILL INCREASE THE ANNUAL HEAT INPUT TO THE TURBINE IN ORDER TO MEET

THE HIGHER DEMAND FOR COMPRESSED AIR. HOURLY HEAT INPUT RATE WILL REMAIN THE SAME. THIS TURBINE IS CURRENTLY OPERATING UNDER PERMIT NO. 2165. WITH THIS AMENDMENT ACTION, IT IS BEING MOVED TO PERMIT NO. 723/P828M1. IT IS CURRENTLY OPERATING WITH STEAM INJECTION TO MEET THE RACT REQUIREMENT OF 42 PPMVD (CORRECTED TO 15% OXYGEN) NOX. TURBINE=S 1997 STACK TEST DATA SHOWS THAT THE MEASURED CONCENTRATION OF NOX IN THE TURBINE EXHAUST IS LOWER THAN 42 PPMVD . ROHM AND HAAS USED THE LOWER MEASURED NOX CONCENTRATION IN THE STACK (CONFIDENTIAL) TO CALCULATE THE HOURLY NOX EMISSION RATE OF 27.46 LB/HR MAERT LIMIT. THIS HOURLY RATE IS SLIGHTLY LOWER THAN THE CURRENT PERMIT NO. 2165 NOX LEVEL OF 29.8 LB/HR. THE CURRENT PERMIT=S ANNUAL NOX LIMIT IS 102.3 TPY. THIS LIMIT WAS BASED ON REDUCED THEORETICAL HOURS OF OPERATION (CONFIDENTIAL) IN THE ORIGINALIS 102.3 TPY. THIS LIMIT WAS BASED ON REDUCED THEORETICAL HOURS OF OPERATION (CONFIDENTIAL) IN THE ORIGINAL PERMIT, IT WAS NOT BASED ON THE MAXIMUM HOURS OF OPERATION OF 8760 HOURS/YEAR. IN THIS AMENDMENT, THEY CALCULATED THE ANNUAL NOX LIMIT OF 120.29 TPY BASED ON THE HOURLY LIMIT OF 27.46 LB/HR AND 8760 HOURS/YR. THE INCREASED HOURS OF OPERATION IS THE REASON FOR THE 17.99 TPY ANNUAL NOX INCREASES. NO PHYSICAL MODIFICATIONS TO THE TURBINE IS NEEDED AS PART OF THIS

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 27.4600 LB/H Emission Limit 2: 120.2900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 38.5300 LB/H Emission Limit 2: 168.7400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5900 LB/H Emission Limit 2: 2.5600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0900 LB/H Emission Limit 2: 9.1600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 0.0300 LB/H

Emission Limit 2: 0.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N-3 BACKUP INSTRUMENT AIR COMPRESSOR Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes: NO EMISSION LIMITATIONS PER COMPRESSOR RATED 440 HP '106.512 FOR ENGINES RATED LESS THAN 500 HP

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.2100 LB/H Emission Limit 2: 2.2300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.2600 LB/H Emission Limit 2: 0.4500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) )Emission Limit 1: 0.0800 LB/H

Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N-5 COOLING TOWER NORTH

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: THESE COOLING TOWERS ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED INTO PERMIT NO.Process Notes: THESE COOLING TOWERS ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED INTO PERMIT NO. 723/P828M1 WITHOUT ANY EMISSION CHANGES. THEY WILL CONTINUE UNDERGOING MONTHLY MONITORING FOR VOC IN THE COOLING WATER. THEY ARE EQUIPPED WITH DRIFT ELIMINATORS TO MINIMIZE PM EMISSIONS. THIS MEETS THE BACT FOR THESE SMALL COOLING TOWERS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4500 LB/H Emission Limit 2: 1.9500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0400 LB/H Emission Limit 2: 8.9200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: N-5 COOLING TOWER SOUTH

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: THESE COOLING TOWERS ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED INTO PERMIT NO.

723/P828M1 WITHOUT ANY EMISSION CHANGES. THEY WILL CONTINUE UNDERGOING MONTHLY MONITORING FOR VOC IN THE COOLING WATER. THEY ARE EQUIPPED WITH DRIFT ELIMINATORS TO MINIMIZE PM EMISSIONS. THIS MEETS THE BACT FOR THESE SMALL COOLING TOWERS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6200 LB/H Emission Limit 2: 2.7200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.8400 LB/H Emission Limit 2: 12.4400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N-7 COOLING TOWER

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: THESE COOLING TOWERS ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED INTO PERMIT NO.

723/P828M1 WITHOUT ANY EMISSION CHANGES. THEY WILL CONTINUE UNDERGOING MONTHLY MONITORING FOR VOC IN THE COOLING WATER. THEY ARE EQUIPPED WITH DRIFT ELIMINATORS TO MINIMIZE PM EMISSIONS. THIS MEETS THE BACT FOR THESE SMALL COOLING TOWERS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6700 LB/H Emission Limit 2: 7.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 7.6500 LB/H Emission Limit 2: 33.5100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N7/8 PREHEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes: THE PREHEATERS; EPNS N-12, N-13 AND N-14, ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED

INTO PERMIT NO. 723/P828M1. THE PREHEATER; EPN N-3, IS OPERATING UNDER PERMIT NO. 723/P828M1. THESE PREHEATERS ARE SMALL SOURCES WITH A HEAT INPUT CAPACITY OF MUCH LESS THAN 40MMBTU/HR. THEY WILL CONTINUE TO ACHIEVE 0.1 LB NOX/MMBTU. ROHM AND HAAS DID NOT PROPOSE ADDITIONAL CONTROL FOR THESE PROCESS HEATERS. MOST RECENT AP-42 FACTORS ARE USED TO CALCULATE THE REST OF THE EMISSION RATES FROM THESE HEATERS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.4700 LB/H Emission Limit 2: 2.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.4500 LB/H Emission Limit 2: 1.9700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: N7/8 ABSORBER FEED WATER TANK

Process Type: 42.010 (Volatile Organic Liquid Marketing (except 42.009)) Primary Fuel: Throughput:

Process Notes: THESE STORAGE TANKS ARE CURRENTLY OPERATING UNDER VERP PERMIT NO. 48922 WHICH IS BEING ROLLED INTO PERMIT

NO. 723/P828M1. THEY ALL ARE FIXED ROOF TANKS LESS THAN 25,000 GALLON CAPACITY EXCEPT N-19. ACETONE TANK, N-19 IS AN INTERNAL FLOATING ROOF TANK. ALL TANKS ARE FILLED VIA SUBMERGED FILL PIPES. THESE TANKS MEET THE CURRENT BACT.

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.5400 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N3/7 FEED AND EXIT GAS FLARE

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: THE PROPOSED N-AREA PRODUCTION INCREASE WILL INCREASE THE FLOW INTO THESE EXISTING FLARES. THEREFORE, THE

EMISSIONS FROM THESE FLARES ARE INCREASED DURING THIS AMENDMENT. THE FLARES WILL CONTINUE TO ACHIEVE 98% DESTRUCTION REMOVAL EFFICIENCY (DRE) FOR VOC. THE EMISSION FACTORS FOR LOW BTU STREAMS OF 0.0641 LB NOX/MMBTU AND 0.5496 LB CO/MMBTU ARE USED IN THE EMISSION CALCULATIONS FOR THE FLARES. THE FLARES WILL CONTINUE TO MEET THE BACT.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 130.6500 LB/H Emission Limit 2: 7.7800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 699.0900 LB/H Emission Limit 2: 136.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 0.1100 LB/H

Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 28.3600 LB/H Emission Limit 2: 1.7700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 31.8800 LB/H Emission Limit 2: 0.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Acetone

CAS Number: 67-64-1 Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 0.1600 LB/H Emission Limit 2: 0.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SAFETY VENT STACK (2)

Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes: THESE PROCESS VENTS ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED INTO PERMIT NO.

723/P828M1 WITHOUT ANY EMISSION CHANGES. THE EMISSION RATES OF VOC AND AMMONIA FROM THESE VENTS ARE CALCULATED USING FLOW RATES FROM THE VENTS AND SAMPLED CONCENTRATIONS OF POLLUTANTS COLLECTED AT EACH VENT. THE EMISSION RATES ARE SMALL. NO CONTROL IS ACCEPTED AS BACT FOR THESE VENTS. EMISSIONS ARE PER STACK.

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5800 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.4600 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SVG FAN Process Type: 19.900 (Other Misc. Combustion) Primary Fuel:Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.2400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: ALCOHOL TANK (3)

Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes: THESE STORAGE TANKS ARE CURRENTLY OPERATING UNDER VERP PERMIT NO. 48922 WHICH IS BEING ROLLED INTO PERMIT

NO. 723/P828M1. THEY ALL ARE FIXED ROOF TANKS LESS THAN 25,000 GALLON CAPACITY EXCEPT N-19. ACETONE TANK, N-19 IS AN INTERNAL FLOATING ROOF TANK. ALL TANKS ARE FILLED VIA SUBMERGED FILL PIPES. THESE TANKS MEET THE CURRENT BACT. EMISSIONS ARE PER TANK.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N-3,4 PREHEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:Process

Notes: THE PREHEATERS; EPNS N-12, N-13 AND N-14, ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED

INTO PERMIT NO. 723/P828M1. THE PREHEATER; EPN N-3, IS OPERATING UNDER PERMIT NO. 723/P828M1. THESE PREHEATERS ARE SMALL SOURCES WITH A HEAT INPUT CAPACITY OF MUCH LESS THAN 40MMBTU/HR. THEY WILL CONTINUE TO ACHIEVE 0.1 LB NOX/MMBTU. ROHM AND HAAS DID NOT PROPOSE ADDITIONAL CONTROL FOR THESE PROCESS HEATERS. MOST RECENT AP-42 FACTORS ARE USED TO CALCULATE THE REST OF THE EMISSION RATES FROM THESE HEATERS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2700 LB/H Emission Limit 2: 1.1800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2300 LB/H Emission Limit 2: 0.9900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 2.5 μ (FPM2.5)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: N-5/6 PREHEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes: THE PREHEATERS; EPNS N-12, N-13 AND N-14, ARE CURRENTLY OPERATING UNDER VERP PERMIT 48922 WHICH IS BEING ROLLED

INTO PERMIT NO. 723/P828M1. THE PREHEATER; EPN N-3, IS OPERATING UNDER PERMIT NO. 723/P828M1. THESE PREHEATERS ARE SMALL SOURCES WITH A HEAT INPUT CAPACITY OF MUCH LESS THAN 40MMBTU/HR. THEY WILL CONTINUE TO ACHIEVE 0.1 LB NOX/MMBTU. ROHM AND HAAS DID NOT PROPOSE ADDITIONAL CONTROL FOR THESE PROCESS HEATERS. MOST RECENT AP-42 FACTORS ARE USED TO CALCULATE THE REST OF THE EMISSION RATES FROM THESE HEATERS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.1900 LB/H Emission Limit 2: 5.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.0000 LB/H Emission Limit 2: 4.3800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS

NAME: N5/6 FLARE

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: THE PROPOSED N-AREA PRODUCTION INCREASE WILL INCREASE THE FLOW INTO THESE EXISTING FLARES. THEREFORE, THE

EMISSIONS FROM THESE FLARES ARE INCREASED DURING THIS AMENDMENT. THE FLARES WILL CONTINUE TO ACHIEVE 98% DESTRUCTION REMOVAL EFFICIENCY (DRE) FOR VOC. THE EMISSION FACTORS FOR LOW BTU STREAMS OF 0.0641 LB NOX/MMBTU AND 0.5496 LB CO/MMBTU ARE USED IN THE EMISSION CALCULATIONS FOR THE FLARES. THE FLARES WILL CONTINUE TO MEET THE BACT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.1300 LB/H Emission Limit 2: 3.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 152.1300 LB/H Emission Limit 2: 48.4100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 450.5200 LB/H Emission Limit 2: 235.3400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 23.9800 LB/H Emission Limit 2: 16.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 171.7200 LB/H Emission Limit 2: 49.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Acetone

CAS Number: 67-64-1Test Method: Unspecified

Pollutant Group(s): Emission Limit 1: 4.1200 LB/H Emission Limit 2: 7.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: WASTEWATER COLLECTION TANK

Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes: THIS TANK IS CURRENTLY AUTHORIZED BY STANDARD PERMIT NO. 43803 WHICH IS BEING ROLLED INTO PERMIT NO.

723/P828M1. IT HAS A HORIZONTAL WATER SCRUBBER WITH 90% REMOVAL EFFICIENCY FOR HCN. THE PROPOSED PRODUCTION INCREASE AT N AREA WILL INCREASE THE WASTEWATER FLOW INTO THIS TANK. THEREFORE, EMISSIONS WILL INCREASE SLIGHTLY FROM THIS TANK. SCRUBBER CONTROL EXCEEDS THE BACT FOR THIS SMALL FIXED ROOF TANK.

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) HORIZONTAL SCRUBBER

Est. % Efficiency: 90.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACETONE DAY TANK

Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput:

Process Notes: ACETONE TANK, N-19 IS AN INTERNAL FLOATING ROOF TANK. ALL TANKS ARE FILLED VIA SUBMERGED FILL PIPES. THESE

TANKS MEET THE CURRENT BACT.

POLLUTANT NAME: Acetone

CAS Number: 67-64-1 Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 0.5600 LB/H Emission Limit 2: 0.9500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACETONE DOCK TANK Process Type: 42.999 (Other Liquid Marketing Sources)Primary Fuel: ACETONE

Throughput:

Process Notes:

POLLUTANT NAME: Acetone

CAS Number: 67-64-1 Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 1.3600 LB/H Emission Limit 2: 2.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACETONE DOCK TANK FUGITIVE Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Acetone

CAS Number: 67-64-1 Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1800 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVE (4) Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: ACH: 1.68 LB/H 7.37 T/YR

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 2.4400 LB/H Emission Limit 2: 10.6800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.5200 LB/H Emission Limit 2: 2.2600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Acetone

CAS Number: 67-64-1 Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 1.3500 LB/H Emission Limit 2: 5.9200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES (4) Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:Process Notes: ACH: .22 LB/H .98 T/YR

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.1900 LB/H Emission Limit 2: 0.8200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.4900 LB/H Emission Limit 2: 2.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Acetone

CAS Number: 67-64-1 Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 0.4500 LB/H Emission Limit 2: 1.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0464 (final) Date Determination Last Updated: 10/01/2007Corporate/Company

Name: CONTINENTAL CARBON COMPANY Permit Number: P1014

Facility Name: CONTINENTAL CARBON SUNRAY PLANT Permit Date: 03/18/2005 (actual) Facility Contact: MR. TODD N MILLER 2816473858 FRS Number: 110000465728 Facility Description: FEEDSTOCK OIL, SULFUR CONTENT OF 4.5 WEIGHT PERCENT (WT%) MAXIMUM AND 3.5 WT%

ANNUAL AVERAGE, FROM CRUDE OIL REFINERIES IS RECEIVED AT THE PILOT PLANT BY TANK TRUCK, TANK CARS, AND PIPELINE INTO ONE OF THE TWO HEATED AND INSULATED STORAGE TANKS: THE 10,000 GALLON TANK (EPN 29) AND THE NEW 20,000 GALLON TANK (EPN 30). WHILE UNLOADING, FRESH FEEDSTOCK OIL IS BLENDED WITH OIL IN INVENTORY FOR UNIFORM FEEDING. THE OIL FROM THE FEEDSTOCK TANK IS TRANSFERRED TO THE CHARGE TANK TO FEED THE REACTORS. BY WAY OF A NATURAL GAS FIRED OIL PREHEATER (EPN 19), THE OIL IS ROUTED TO THE REACTOR BURNERS WHERE IT IS PARTIALLY COMBUSTED AT 2,800°F-3,800°F. ELECTRIC MOTOR DRIVEN FORCED DRAFT BLOWERS PROVIDE COMBUSTION AIR. THE COMBUSTION AIR IS PASSED THROUGH AN AIR PREHEATER EXCHANGER. NATURAL GAS, FUEL OIL, OR FLUE GAS FROM THE MAIN BAG FILTER (MBF) WILL MAINTAIN THE REACTOR TEMPERATURE. DURING THE PARTIAL COMBUSTION, POTASSIUM CARBONATE (K2CO3) IS INJECTED AT THE REACTOR FACEPLATE FOR PRODUCT STRUCTURE CONTROL. OXYGEN, ROUTED THROUGH A NATURAL GAS FIRED PREHEATER (EPN 28), MAY ALSO BE INTRODUCED TO THE REACTOR TO ENHANCE THE OXYGEN CONTENT. LIQUID OXYGEN IS BROUGHT ONSITE AND STORED IN LIQUID OXYGEN STORAGE TANKS. SIC Code: 2895

Permit Type: U: Unspecified NAICS Code: 335991 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: MOORE Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: THE CONTINENTAL CARBON COMPANY (CCC) SUBMITTED AN AIR PERMIT APPLICATION FOR THEIR CARBON BLACK PILOT

PLANT AT THEIR SUNRAY, TEXAS SITE FOR PLANT MODIFICATIONS AND A PRODUCTION CAPACITY INCREASE. THE PILOT PLANT IS LOCATED AT THE SAME SITE AS CCC¿S MAIN PLANT, BUT CURRENTLY OPERATES AS A GRANDFATHERED FACILITY AS IT WAS BUILT PRIOR TO 1970. THE PILOT PLANT PRIMARILY PRODUCED ¿TREAD¿ BLACK, BUT IS ALSO CAPABLE OF PRODUCING CARCASS BLACK AND OTHER TYPES OF SPECIAL BLACKS. SINCE 1995, THE PILOT PLANT HAS PRODUCED NO MORE THAN 1.5 MILLION POUNDS PER YEAR (MMLB/YR) OF CARBON BLACK AND WISHES TO INCREASE PRODUCTION UP TO 40 MMLB/YR. THIS INCREASE IN PRODUCTION WILL BE ACCOMPLISHED WITH AN INCREASE IN HOURS OF OPERATION AND THE ADDITION OF NEW EQUIPMENT TO THE PRODUCT RECOVERY PORTION OF THE PROCESS. IN CONJUNCTION WITH THE PRODUCTION INCREASE, A FLARE WILL BE ADDED TO REDUCE EMISSIONS OF H2S, CS2, COS, CO, HCN, AND VOC. THE PILOT PLANT IS LOCATED NEAR SUNRAY, TEXAS IN MOORE COUNTY, AN AREA IN ATTAINMENT FOR ALL CRITERIA POLLUTANTS. THE CONTINENTAL CARBON SUNRAY, TEXAS FACILITY IS A MAJOR SOURCE; THEREFORE, PSD REVIEW IS REQUIRED FOR EMISSION INCREASES OF SO2, NOX, AND PM10. VOC AND CO WILL DECREASE AS A RESULT OFTHESE MODIFICATIONS.

Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase:

Carbon Monoxide -161.9800 (Tons/Year) Nitrogen Oxides (NOx) 108.3800 (Tons/Year) Particulate Matter (PM) 61.1300 (Tons/Year) Sulfur Oxides (SOx) 1481.9200 (Tons/Year) Volatile Organic Compounds (VOC) -39.4900 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: PILOT PLANT FLARE

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: THE NEW FLARE IS THE PROPOSED CONTROL TECHNOLOGY WITH A 98% DESTRUCTION EFFICIENCY OF ALL VOCS. THE FLARE

WILL ALSO REDUCE EMISSIONS OF H2S, CO, HCN, CS2, COS, AND PM10 EMITTED BY THE MBF. VOC CAN ALSO BE EMITTED FROM THE FEEDSTOCK OIL STORAGE TANKS. THE FIXED ROOF TANKS ARE CONSIDERED BACT DUE TO THE LOW VAPOR PRESSURE OF THE FEEDSTOCK OIL.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 435.2700 LB/H Emission Limit 2: 1487.0501 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen SulfideCAS Number: 7783-06-4

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.0300 LB/H Emission Limit 2: 10.3600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Disulfide

CAS Number: 75-15-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 2.1500 LB/H Emission Limit 2: 7.3400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbonyl Sulfide

CAS Number: 463-58-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.3400 LB/HEmission Limit 2: 1.1500

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 159.6300 LB/H Emission Limit 2: 699.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.2800 LB/H Emission Limit 2: 1.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Acetylene

CAS Number: 74-86-2 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 5.4400 LB/H Emission Limit 2: 23.8100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 25.9600 LB/H Emission Limit 2: 113.7200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4200 LB/H Emission Limit 2: 1.8300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PROCESS BAG FILTER

Process Type: 69.015 (Carbon Black Manufacturing)

Primary Fuel: Throughput:

Process Notes: FABRIC FILTERS WITH 99.9 PERCENT REMOVAL EFFICIENCY ON ALL THE EMISSION SOURCES THAT CONTAIN CARBON BLACK

WILL CONTROL EMISSIONS OF PM10 FROM THE PLANT AS BACT. THE MBF RECEIVES THE PROCESS STREAM FROM THE REACTORS CONTAINING CARBON BLACK AND THE EFFLUENT GASES. THE PBF RECEIVES THE CARBON BLACK COLLECTED IN THE MBF PNEUMATICALLY CONVEYED FROM THE AIR PURGE CLASSIFYING MILL (VIA AIR BLOWER). A SMALL AMOUNT OF CARBON BLACK NOT TRAPPED IN THE PBF EXITS THE OUTLET HEADER WITH THE CONVEYING AIR TO THE ATMOSPHERE. AIRBORNE CARBON PARTICULATE GENERATED BY THE HANDLING SYSTEM ARE COLLECTED IN THE CLEAN-UP BAG FILTER (CUBF). THE FILTERED AIR IS THEN EMITTED TO THE ATMOSPHERE. THE PACKAGING AND CONVEYANCE SYSTEM ARE ENCLOSED AND CONNECTED TO A VACUUM CLEAN-UP SYSTEM AND PRODUCT LOADING SYSTEMS ARE ESSENTIALLY CLOSED. THERE IS A MOTORIZED VACCUUM SWEEP OF THE PLANT SEVERAL TIMES DAILY TO CONTROL FUGITIVE PARTICULATE EMISSIONS AND A PORTABLE VACCUUM UNIT FOR CONTROL OF CARBON BLACK SPILLS.POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.5100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2300 LB/H Emission Limit 2: 0.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Disulfide

CAS Number: 75-15-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds )Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds )

Emission Limit 1: 0.2900 LB/H Emission Limit 2: 0.9800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbonyl Sulfide

CAS Number: 463-58-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 9.4000 LB/H Emission Limit 2: 41.1800 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Acetylene

CAS Number: 74-86-2 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4200 LB/H Emission Limit 2: 1.8300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 8.3300 LB/H Emission Limit 2: 40.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: CLEAN UP BAG FILTER Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 4.1700 LB/H Emission Limit 2: 20.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FEED STOCK OIL PRE HEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NATURAL GAS, FUEL OIL, OR FLUE GAS

Throughput: 0.90 MMBTU/H

Process BY WAY OF A NATURAL GAS FIRED OIL PREHEATER (EPN 19), THE OIL IS ROUTED TO THE REACTOR BURNERS WHERE IT ISProcess

Notes: BY WAY OF A NATURAL GAS FIRED OIL PREHEATER (EPN 19), THE OIL IS ROUTED TO THE REACTOR BURNERS WHERE IT IS

PARTIALLY COMBUSTED AT 2,800°F-3,800°F. ELECTRIC MOTOR DRIVEN FORCED DRAFT BLOWERS PROVIDE COMBUSTION AIR. THE COMBUSTION AIR IS PASSED THROUGH AN AIR PREHEATER EXCHANGER. NATURAL GAS, FUEL OIL, OR FLUE GAS FROM THE MAIN BAG FILTER (MBF) WILL MAINTAIN THE REACTOR TEMPERATURE. DURING THE PARTIAL COMBUSTION, POTASSIUM CARBONATE (K2CO3) IS INJECTED AT THE REACTOR FACEPLATE FOR PRODUCT STRUCTURE CONTROL.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: LAER Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.3200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0010 LB/H Emission Limit 2: 0.0020 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.0060 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: OXYGEN PRE HEATER

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NATURAL GAS Throughput:

Process Notes: OXYGEN, ROUTED THROUGH A NATURAL GAS FIRED PREHEATER (EPN 28), MAY ALSO BE INTRODUCED TO THE REACTOR TO

ENHANCE THE OXYGEN CONTENT. LIQUID OXYGEN IS BROUGHT ONSITE AND STORED IN LIQUID OXYGEN STORAGE TANKS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0030 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)CAS Number: 7446-09-5

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0010 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0040 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SMALL STORAGE TANK Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel:Primary Fuel:

Throughput:

Process Notes: THE FIXED ROOF TANKS ARE CONSIDERED BACT DUE TO THE LOW VAPOR PRESSURE OF THE FEEDSTOCK OIL.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE FIXED ROOF TANKS ARE CONSIDERED BACT DUE TO THE LOW VAPOR PRESSURE OF THE FEEDSTOCK OIL. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LARGE STORAGE TANK Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes: THE FIXED ROOF TANKS ARE CONSIDERED BACT DUE TO THE LOW VAPOR PRESSURE OF THE FEEDSTOCK OIL.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE FIXED ROOF TANKS ARE CONSIDERED BACT DUE TO THE LOW VAPOR PRESSURE OF THE FEEDSTOCK OIL. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0494 (final) Date Determination Last Updated: 05/21/2007 Corporate/Company Name: FLINT HILLS RESOURCES Permit Number: 8803A PSD-TX-413M7 Facility Name: FLINT HILLS RESOURCES INSTALLATION OF BOILERS Permit Date: 01/24/2005 (actual) Facility Contact: ERIC KAYSEN FRS Number: 1100109923723 Facility Description: SIC Code: 2911 Permit Type: B: Add new process to existing facility NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: NUECES Facility State: TX Facility ZIP Code: 784032608 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: PERMIT ENGINEER: KATE HAUER Permit Notes:



## Process/Pollutant Information

PROCESS NAME: FLARES 5,6 Process Type: 19.330 (Refinery Flares) Primary Fuel:Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1150.9301 LB/H Emission Limit 2: 3123.6599 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 884.5700 LB/H Emission Limit 2: 2624.9099 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 942.5100 LB/H Emission Limit 2: 965.7900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 130.2800 LB/H Emission Limit 2: 546.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 0.1700 LB/H

Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MISC. COMBUSTION SOURCES

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes: SOURCES ARE EXEMPTED ANALYZER VENTS (7), SEDIMENTATION CHAMBE, WASTEWATER TREATMENT, AERATION BASINS,

API OWS CONTROL SYSTEM, TANK 08FB9

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3564.1499 LB/H Emission Limit 2: 2236.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: 16 BENZENE TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: BENZENE Throughput:

Process Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 8.2900 LB/H Emission Limit 2: 12.7500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 43 ETHYLBENZENE TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: ETHYLBENZENE Throughput:

Process Notes:

POLLUTANT NAME: Ethyl BenzenePOLLUTANT NAME: Ethyl Benzene

CAS Number: 100-41-4 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 255.8000 LB/H Emission Limit 2: 14.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 17 TOLUENE TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: TOLUENE Throughput:

Process Notes:

POLLUTANT NAME: Toluene

CAS Number: 108-88-3 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 61.4400 LB/H Emission Limit 2: 13.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 74 XYLENE TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: XYLENE Throughput:

Process Notes:

POLLUTANT NAME: o-Xylene

CAS Number: 1330-20-7 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 1184.6400 LB/H Emission Limit 2: 1686.4301 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ULTRAFORMER FLARE, CCR REGENERATION VENT Process Type: 19.330 (Refinery Flares) Primary Fuel:Throughput:

Process Notes:

POLLUTANT NAME: Chlorine / Chlorine Compounds

CAS Number: 7782-50-5 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) ) Emission Limit 1: 0.6500 LB/H Emission Limit 2: 2.8900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrochloric Acid

CAS Number: 7647-01-0 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.9600 LB/H Emission Limit 2: 1.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: EAST PLANT TRUCK RACK Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 31.5900 LB/H Emission Limit 2: 5.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MARINE VAPOR COMBUSTOR Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 76.9200 LB/H Emission Limit 2: 18.4400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 19.3200 LB/H Emission Limit 2: 4.6200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 125.0700 LB/H Emission Limit 2: 30.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: UNCONTROLLED MARINE LOADING Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 277.8000 LB/H Emission Limit 2: 13.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## VT-0019 (final) Date Determination Last Updated: 12/21/2005 Corporate/Company Name: NEW ENGLAND WASTE SERVICES, INC. Permit Number: AOP-03-044

Facility Name: NEW ENGLAND WASTE SERVICES OF VERMONT, INC. Permit Date: 12/16/2004 (actual) Facility Contact: JOHN GAY 8022237221 FRS Number: 110021144279 Facility Description: THE FACILITY IS A MUNICIPAL SOLID WASTE LANDFILL THAT OPERATES A LANDFILL GAS TO ENERGY (LFGTE) SYSTEM. THE LFGTE SYSTEM WILL CONSIST OF UP TO 4 INTERNAL COMBUSTION ENGINES: CATERPILLAR G3520C LE, EACH RATED TO BURN 507 SCFM OF GAS AND PRODUCE 1600KW. EXCESS GAS IS BURNED TWO BACKUP FLARES: JOHN ZINK MODEL ZEF1235 EACH RATED AT 2500 SCFM. SIC Code: 4953

Permit Type: A: New/Greenfield Facility NAICS Code: 562212 Permit URL: EPA Region: 1 COUNTRY: USA Facility County: ORLEANS Facility State: VT Facility ZIP Code: 05825 Permit Issued By: VERMONT AIR POLLUTION CONTROL DIVISION (Agency Name) MR. DOUG ELLIOTT(Agency Contact) (802) 241-3845 doug.elliott@state.vt.usPermit Notes:

Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 NH Great Gulf < 100 km CLASS1 VT Lye Brook 100km - 50km CLASS1 NH Presidential Range-Dry River 100km - 50km INTL BORDER US/Canada Border < 100 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 325.0000 (Tons/Year) Nitrogen Oxides (NOx) 59.0000 (Tons/Year) Particulate Matter (PM) 8.6000 (Tons/Year) Sulfur Oxides (SOx) 7.8000 (Tons/Year) Volatile Organic Compounds (VOC) 17.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: LANDFILL GAS FLARE

Process Type: 11.320 (Landfill/Digester/Bio-Gas) Primary Fuel: LANDFILL GAS Throughput: 5000.00 SCFM

Process Notes: THERE ARE TWO JOHN ZINK FLARES: MODEL ZEF1235. THEY ARE USED AS A BACKUP COMBUSTION DEVICE IF THE ENGINES

ARE NOT AVAILABLE OR WHEN THERE IS EXCESS LANDFILL GAS UNUSED BY THE ENGINEES.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/MMBTU 1 HOUR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LOW EMISSION DESIGN Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Dioxide (NO2)

CAS Number: 10102-44-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) ) Emission Limit 1: 0.0680 LB/MMBTU 1 HOUR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LOW EMISSION DESIGN Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STATIONARY INTERNAL COMBUSTION ENGINE

Process Type: 17.140 (Landfill/Digester/Bio-Gas) Primary Fuel: LANDFILL GAS Throughput: 2028.00 SCFM

Process Notes: THE PROCESS IS PERMITTED FOR FOUR INTERNAL COMBUSTION ENGINES EACH DRIVING AN ELECTRICAL GENERATOR. EACH

SET IS THE SAME: CATERPILLAR G3520C LE RATED AT 2,221 HP / 1600 KW, BURNING 507 SCFM OF LANDFILL GAS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.7500 G/B-HP-H 1 HOUR Emission Limit 2: 13.5000 LB/H 1 HOUR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: OTHER Control Method: (P) LOW EMISSION ENGINE DESIGN Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Dioxide (NO2)

CAS Number: 10102-44-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) ) Emission Limit 1: 0.5000 G/B-HP-H 1 HOUR Emission Limit 2: 2.4500 LB/H 1 HOUR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: OTHER Control Method: (P) LOW EMISSION ENGINE DESIGN Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0208 (final) Date Determination Last Updated: 09/14/2007 Corporate/Company Name: DEGUSSA ENGINEERED CARBONS, LP Permit Number: PSD-LA-585(M-1) Facility Name: IVANHOE CARBON BLACK PLANT Permit Date: 12/09/2004 (actual) Facility Contact: JOSEPH S. LEBLANC III 3379237531 FRS Number: 110012617677 Facility Description: PSD ALLOWS FOR AN INCREASE IN CARBON BLACK PRODUCTION FROM 260 MM LB/YR TO 350 MM LB/YR. SIC Code: 2895

Permit Type: C: Modify process at existing facility NAICS Code: 325182 Permit URL: EPA Region: 6 COUNTRY: USAFacility County: ST. MARY

Facility State: LA Facility ZIP Code: 70538 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Permit Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT 2 Process Type: 19.390 (Other Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 8.3100 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 8.7900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY, EXCEPT TANKS AND FUGITIVES, ARE CAPPED AT 26.61 LB/HR (ANNUAL AVERAGE) & 116.57 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 27.80 LB/HR (ANNUAL AVERAGE) & 121.76 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 46.4100 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 49.0900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 79.0300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 83.5900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUALPollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUAL AVERAGE) & 1108.26 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 264.29 LB/HR (ANNUAL AVERAGE) & 1157.59 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PSD PERMIT DOES NOT ESTABLISH MASS LIMITS FOR TRS. INSTEAD, SEPARATE LIMITS HAVE BEEN ESTABLISHED FOR CARBON DISULFIDE, CARBONYL SULFIDE, AND HYDROGEN SULFIDE.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 383.8600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 405.9900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.1600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 2.2900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: H2S EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 6.93 LB/HR (ANNUAL AVERAGE) & 30.35 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 7.24 LB/HR (ANNUAL AVERAGE) & 31.70 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 1.6500 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT 3 Process Type: 19.390 (Other Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PSD PERMIT DOES NOT ESTABLISH MASS LIMITS FOR TRS. INSTEAD, SEPARATE LIMITS HAVE BEEN ESTABLISHED FOR CARBON DISULFIDE, CARBONYL SULFIDE, AND HYDROGEN SULFIDE.POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 522.6600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 535.3200 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 11.3500 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 11.6300 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY, EXCEPT TANKS AND FUGITIVES, AREPollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY, EXCEPT TANKS AND FUGITIVES, ARE CAPPED AT 26.61 LB/HR (ANNUAL AVERAGE) & 116.57 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 27.80 LB/HR (ANNUAL AVERAGE) & 121.76 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.9600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 3.0300 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: H2S EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 6.93 LB/HR (ANNUAL AVERAGE) & 30.35 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 7.24 LB/HR (ANNUAL AVERAGE) & 31.70 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 107.9100 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 110.5300 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUAL AVERAGE) & 1108.26 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 264.29 LB/HR (ANNUAL AVERAGE) & 1157.59 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.1300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 2.1800 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 63.3700 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 64.9100 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED)Emission Limit 2: 64.9100 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED)

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT 4 Process Type: 19.390 (Other Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 64.6000 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 69.5400 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUAL AVERAGE) & 1108.26 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 264.29 LB/HR (ANNUAL AVERAGE) & 1157.59 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.2800 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 1.3700 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 37.9300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 40.8400 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.7900 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 7.3100 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 26.61 LB/HR (ANNUAL AVERAGE) & 116.57 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 27.80 LB/HR (ANNUAL AVERAGE) & 121.76 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTEEmission Limit 1: SEE NOTE

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PSD PERMIT DOES NOT ESTABLISH MASS LIMITS FOR TRS. INSTEAD, SEPARATE LIMITS HAVE BEEN ESTABLISHED FOR CARBON DISULFIDE, CARBONYL SULFIDE, AND HYDROGEN SULFIDE.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 37.9300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 40.8400 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 1.7700 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 1.9000 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: H2S EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 6.93 LB/HR (ANNUAL AVERAGE) & 30.35 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 7.24 LB/HR (ANNUAL AVERAGE) & 31.70 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: DRYER, UNIT 4/5 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 50.5800 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 54.7000 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMITControl Method: (P) GOOD COMBUSTION PRACTICES

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 50.5800 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 54.7000 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.0600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 9.8000 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY, EXCEPT TANKS AND FUGITIVES, ARE CAPPED AT 26.61 LB/HR (ANNUAL AVERAGE) & 116.57 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 27.80 LB/HR (ANNUAL AVERAGE) & 121.76 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PSD PERMIT DOES NOT ESTABLISH MASS LIMITS FOR TRS. INSTEAD, SEPARATE LIMITS HAVE BEEN ESTABLISHED FOR CARBON DISULFIDE, CARBONYL SULFIDE, AND HYDROGEN SULFIDE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.3600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED)Emission Limit 2: 2.5500 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED)

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: H2S EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 6.93 LB/HR (ANNUAL AVERAGE) & 30.35 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 7.24 LB/HR (ANNUAL AVERAGE) & 31.70 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.7000 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 1.8400 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 86.1300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 93.1400 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUAL AVERAGE) & 1108.26 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 264.29 LB/HR (ANNUAL AVERAGE) & 1157.59 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: DRYER, UNIT 2/3 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PSD PERMIT DOES NOT ESTABLISH MASS LIMITS FOR TRS. INSTEAD, SEPARATE LIMITS HAVE BEEN ESTABLISHED FOR CARBON DISULFIDE, CARBONYL SULFIDE, AND HYDROGEN SULFIDE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 13.1100 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 13.6100 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY, EXCEPT TANKS AND FUGITIVES, ARE CAPPED AT 26.61 LB/HR (ANNUAL AVERAGE) & 116.57 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 27.80 LB/HR (ANNUAL AVERAGE) & 121.76 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 603.6400 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 626.7900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 73.1900 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 76.0000 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 3.4100 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 3.5400 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: H2S EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 6.93 LB/HR (ANNUAL AVERAGE) & 30.35 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 7.24 LB/HR (ANNUAL AVERAGE) & 31.70 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 124.6300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 129.4100 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUAL AVERAGE) & 1108.26 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 264.29 LB/HR (ANNUAL AVERAGE) & 1157.59 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.4600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 2.5600 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT 5 Process Type: 19.390 (Other Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.2800 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 1.3900 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 64.6000 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 70.1700 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 253.03 LB/HR (ANNUAL AVERAGE) & 1108.26 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 264.29 LB/HR (ANNUAL AVERAGE) & 1157.59 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 312.8600 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 339.8700 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.7900 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 7.3800 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSIONS FROM ALL SOURCES AT THE FACILITY, EXCEPT TANKS AND FUGITIVES, ARE CAPPED AT 26.61 LB/HR (ANNUAL AVERAGE) & 116.57 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 27.80 LB/HR (ANNUAL AVERAGE) & 121.76 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE PSD PERMIT DOES NOT ESTABLISH MASS LIMITS FOR TRS. INSTEAD, SEPARATE LIMITS HAVE BEEN ESTABLISHED FOR CARBON DISULFIDE, CARBONYL SULFIDE, AND HYDROGEN SULFIDE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.7700 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 1.9200 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: H2S EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 6.93 LB/HR (ANNUAL AVERAGE) & 30.35 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 7.24 LB/HR (ANNUAL AVERAGE) & 31.70 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 37.9300 LB/H HOURLY MAXIMUM (NATURAL GAS-FIRED) Emission Limit 2: 41.2100 LB/H HOURLY MAXIMUM (FEEDSTOCK OIL-FIRED) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: DRYER EXHAUST BAG FILTER, UNIT 2 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 8.0100 LB/H HOURLY MAXIMUM Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PMTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8900 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: UTILITY VACUUM SYSTEM, UNIT 4/5 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: DRYER EXHAUST BAG FILTERS, UNITS 4 & 5 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7400 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HRPollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 6.5500 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: OPERATING PERMIT

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: CAMBELT ULTILITY VACCUM SYSTEM Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HRPollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: DRYER EXHAUST BAG FILTER, UNIT 3 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1900 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Sulfur Dioxide (SO2)CAS Number: 7446-09-5

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 10.9300 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) LIMIT SULFUR CONTENT IN FEEDSTOCK TO Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SO2 EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 2501.45 LB/HR (ANNUAL AVERAGE) & 10,956.33 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 2611.66 LB/HR (ANNUAL AVERAGE) & 11,439.07 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0900 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 297.38 LB/HR (ANNUAL AVERAGE) & 1302.54 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 316.61 LB/HR (ANNUAL AVERAGE) & 1360.47 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFURLOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: NORTH UTILITY VACUUM SYSTEM, NO. 1 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: LOOP FILTER VENT, UNIT 2 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel:Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1300 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: LOOP FILTER VENT, UNIT 3 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.1700 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: LOOP FILTER VENTS, UNITS 4 & 5 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMITControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: HOPPER TRUCK LOADING VACUUM, UNIT 2/3 & UNIT 4/5 (2) Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PARTICULATE EMISSIONS FROM ALL SOURCES AT THE FACILITY ARE CAPPED AT 11.57 LB/HR (ANNUAL AVERAGE) & 50.66 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH NATURAL GAS AND 11.92 LB/HR (ANNUAL AVERAGE) & 52.22 TPY (ANNUAL MAXIMUM) WHEN FUELING REACTORS WITH FEEDSTOCK OIL. IN THE NATURAL GAS SCENARIO, SULFUR LOADING IS LIMITED TO 295 LB/HR AND 1239 TPY. IN THE FEEDSTOCK OIL SCENARIO, SULFUR LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.LOADING IS LIMITED TO 311 LB/HR AND 1294 TPY.



## Process/Pollutant Information

PROCESS NAME: TANK #3 (2.31 MM GALS) Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes: TANK STORES CARBON BLACK OIL

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1400 LB/H HOURLY MAXIMUM Emission Limit 2: 0.6300 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HOT FEEDSTOCK OIL FUGITIVES Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes: VALVES, FLANGES, PUMPS, & AGITATORS

POLLUTANT NAME: Volatile Organic Compounds (VOC)POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4100 LB/H HOURLY MAXIMUM Emission Limit 2: 1.7900 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0481 (final) Date Determination Last Updated: 10/01/2007 Corporate/Company Name: AIR PRODUCTS LP Permit Number: PSD-TX-1044 /

35873 Facility Name: AIR PRODUCTS BAYTOWN I I Permit Date: 11/02/2004 (actual) Facility Contact: KATHLEEN BRANDT 2818380202 FRS Number: 110012710423 Facility Description: THIS FACILITY GETS RAW SYNTHESIS GAS FROM EXXON¿S SYNTHESIS GAS MANUFACTURING

UNIT. THE RAW SYNGAS STREAM FROM THE EXXON PLANT, CONSISTING OF CO2, CO, H2, H2S, COS, HCN, NH3 AND METHANE, IS PIPED TO THE AIR PRODUCTS PLANT WHERE THE ACID GASES AND AMMONIA WILL BE REMOVED BY AIR PRODUCTS¿ RECTISOL UNIT. THE PRODUCTS PRODUCED INCLUDE CO, AND TWO PURE SYNTHESES GAS PRODUCTS. THESE PRODUCTS ARE DISTRIBUTED TO CUSTOMERS VIA PIPELINES. AN IMPURE SYNGAS IS ALSO PRODUCED AND USED OFFSITE AS FUEL. THE NEW PROCESS WILL CONVERT A PORTION OF THE SYNGAS TO HYDROGEN. THE HYDROGEN WILL BE PURIFIED AND DISTRIBUTED TO CUSTOMERS. SIC Code: 492

Permit Type: U: Unspecified NAICS Code: 486210 Permit URL: EPA Region: 6 COUNTRY: USAFacility County: HARRIS

Facility State: TX Facility ZIP Code: 77520 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: AIR PRODUCTS REQUESTED AN AMENDMENT TO AUTHORIZE THE ADDITION OF A HYDROGEN PURIFICATION SYSTEM TO

THEIR SYN GAS PRODUCTION FACILITY. THE REQUESTED ADDITIONS INCLUDED: 1) A SHIFT REACTOR TO PRODUCE ADDITIONAL HYDROGEN 2) 2 PRESSURE SWING ADSORBERS (PSA¿S) TO PURIFY HYDROGEN 3) A 350 MMBTU/HR BOILER (EPN 7) TO GENERATE STEAM FIRING PSA TAIL GAS . THE BOILER EMITS MORE THAN 100 TPY CO, MAKING THIS PERMIT A PSD PROJECT FOR CO, PSD PERMIT NO. P1044. THE COMPANY ALSO INCLUDED THE FOLLOWING PERMIT BY RULES: AUTHORIZATION TYPE NUMBER DESCRIPTION PBR 43611 A DIESEL FUEL TANK (EPN 8), MEETS BACT, SEE SOURCES AND CONTROLS PBR 43611 A PROCESS STEAM VENT (EPN SVENT1), MEETS BACT, SEE SOURCES AND CONTROLS 106.511 NONE AN EMERGENCY GENERATOR (EPN 9), MEETS BACT, SEE SOURCES AND CONTROLS FINALLY, THE COMPANY AUTHORIZED A START UP PROCESS VENT FOR THE SHIFT REACTOR STEAM DRUM. THERE ARE VIRTUALLY NO VOC EMISSIONS FROM THE VENT. THERE WAS A SMALL INCREASE IN FUGITIVE EMISSIONS DUE TO NEW PIPING FOR THE SHIFT REACTOR SYSTEM.



## Process/Pollutant Information

PROCESS NAME: RECTISOL VENT Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Methanol

CAS Number: 67-56-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.3000 LB/H Emission Limit 2: 5.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 11.4000 LB/H Emission Limit 2: 0.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.6500 LB/H Emission Limit 2: 7.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: N/A Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbonyl SulfideCAS Number: 463-58-1

Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 2.9200 LB/H Emission Limit 2: 12.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE (NORMAL OPERATION) Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: NATURAL GAS Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 11.4000 LB/H Emission Limit 2: 0.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 797.7000 LB/H Emission Limit 2: 11.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MSS-NONCONDENSIBLES (PROPYLENE VENTING) Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.5200 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 21.6400 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Propylene

CAS Number: 115-07-1 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 20.0000 LB/H Emission Limit 2: 0.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: PARTS WASHER Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES (4) Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: THE CO EMISSIONS ARE ELIGIBLE FOR PSD

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 0.2300 LB/H Emission Limit 2: 1.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.8500 LB/H Emission Limit 2: 34.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 1.6400 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbonyl Sulfide

CAS Number: 463-58-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Cyanide

CAS Number: 74-90-8 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Propylene

CAS Number: 115-07-1 Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.3900 LB/H Emission Limit 2: 1.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Methanol

CAS Number: 67-56-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.8100 LB/H Emission Limit 2: 3.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: COOLING TOWER Process Type: 50.005 (Petroleum Refining Separation Processes (distillation and light ends recovery)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.3600 LB/H Emission Limit 2: 5.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SUPPLEMENTARY COOLING TOWER Process Type: 50.005 (Petroleum Refining Separation Processes (distillation and light ends recovery)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3400 LB/H Emission Limit 2: 1.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER STACK Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: NATURAL GAS Throughput:

Process Notes: CO EMISSIONS ARE ELIGIBLE FOR PSD

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 28.3000 LB/H Emission Limit 2: 123.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.0000 LB/H Emission Limit 2: 9.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 24.2000 LB/H Emission Limit 2: 9.9400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.4500 LB/H Emission Limit 2: 10.7400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 33.1800 LB/H Emission Limit 2: 9.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.6100 LB/H Emission Limit 2: 11.4300 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER STACK (HIGH BTU FUEL) Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 21.0000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: BOILER STACK (START UP)

Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 176.7800 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIESEL FUEL TANK Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/HEmission Limit 1: 0.0100 LB/H

Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: EMERGENCY GENERATOR Process Type: 19.800 (Misc. Internal Combustion Engines) Primary Fuel: Throughput:

Process Notes: CO EMISSIONS ARE ELIGIBLE FOR PSDPOLLUTANT NAME: Carbon Dioxide

CAS Number: 124-38-9 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Greenhouse Gasses (GHG) , InOrganic Compounds ) Emission Limit 1: 2.2400 LB/H Emission Limit 2: 0.9900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 10.4000 LB/H Emission Limit 2: 4.5600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: 1.0100 LB/H

Emission Limit 2: 0.4600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 4.8000 LB/H Emission Limit 2: 2.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7400 LB/H Emission Limit 2: 0.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: EMERGENCY GENERATOR TANK Process Type: 19.800 (Misc. Internal Combustion Engines) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PROCESS STEAM VENT Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels))Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels))

Primary Fuel: Throughput:

Process Notes: DS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MSS PROCESS STEAM VENT Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## IA-0074 (final) Date Determination Last Updated: 11/03/2008 Corporate/Company Name: ARCHER DANIELS MIDLAND CORN PROCESSING Permit Number: 04-A-308P

Facility Name: ARCHER DANIELS MIDLAND CORN PROCESSING Permit Date: 08/16/2004 (actual) Facility Contact: RICH STEPHENS 3193980735 R_STEPHENS@ADMWORLD.COM FRS Number: 110010507503 Facility Description: WET CORN MILL PRODUCING CORN SYRUP, STARCH AND ETHANOL. THIS PROJECT IS FOR INCREASED ETHANOL PRODUCTION. SIC Code: 2869

Permit Type: C: Modify process at existing facility NAICS Code: 325193 Permit URL: EPA Region: 7 COUNTRY: USA Facility County: LINN Facility State: IA Facility ZIP Code: 52406 Permit Issued By: IOWA DEPARTMENT OF NATURAL RESOURCES AIR QUALITY (Agency Name) MR. GARY SMITH(Agency Contact) (515) 281-4635 GARY.SMITH@DNR.IOWA.GOV Other Agency Contact Info: GARY.SMITH@DNR.STATE.IA.US 515-281-4635 Permit Notes: MAJOR FOR NOX AND SO2 DUE TO DEBOTTLENECKED BOILER. LOCAL PROGRAM (LINN COUNTY) ISSUED PERMITS FOR NON-PSD UNITS. ETHANOL PRODUCTION INCREASED BY 51.5 MILLION GALLONS PER YEAR.



## Process/Pollutant InformationPROCESS NAME: ETHANOL PRODUCTION,190 PROOF ALCOHOL SCRUBBER VENT

Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 316.50 MMGAL/YR

Process Notes: SCRUBBER ON NON-CONDENSIBLE GAS VENT ON ETHANOL PRODUCTION USED TO RECOVER ETHANOL.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3000 LB/H Emission Limit 2: 1.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: NO ADDITIONAL CONTROL REQUIRED DUE TO LOW EMISSION RATE. SCRUBBER WATER IS NOT PH ADJUSTED SO NO SO2 CONTROL IS EXPECTED.



## Process/Pollutant Information

PROCESS NAME: MR EVAPORATOR VENT #2 Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 316.50 MMGAL/YR

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 1.0000 LB/H

Emission Limit 2: 4.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (A) SCRUBBER WITH PH ADJUSTED SCRUBBER LIQUOR Est. % Efficiency: 97.000 Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE, ETHANOL LOADOUT Process Type: 19.390 (Other Flares) Primary Fuel: NATURAL GAS Throughput: 27.00 MMBTU/H

Process Notes: TRUCK AND RAIL LOADOUT OF DENATURED ALCOHOL, 316.5 MMGAL/YR

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 4.0500 LB/H Emission Limit 2: 0.1500 LB/MMBTU 3 HOUR AVG Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Y Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , OTHER Control Method: (P) LOW NOX BURNER ON FLARE Est. % Efficiency: 50.000 Compliance Verified: No Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: 7.4000 LB/MMBTU E-4 CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT , OTHER Control Method: (P) NATURAL GAS ONLY Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes: EMISSIONS FROM FLARE, SO2 EMISSIONS BASED ON MASS BALANCE



## Facility Information

RBLC ID: 

## TX-0442 (final) Date Determination Last Updated: 03/20/2007 Corporate/Company Name: SHELL OIL COMPANY Permit Number: P928M1 Facility Name: SHELL OIL DEER PARK Permit Date: 07/30/2004 (actual) Facility Contact: MR. TIM HAKE 713 246-6887 FRS Number: 110000599424 Facility Description: ULTRA-LOW SULFUR DIESEL PROJECT SIC Code: 2911 Permit Type: U: Unspecified NAICS Code: Permit URL: EPA Region: 6 COUNTRY: USA Facility County: HARRIS Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes:

## Process/Pollutant Information

PROCESS NAME: SR- 3/4 INCINERATOR Process Type: 19.200 (Emission Control Afterburners & Incinerators (combustion gasses only)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , NSPS , NESHAP Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NINE ENGINES Process Type: 17.200 (Small Internal Combustion Engines (¿500 HP)) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , NSPS , NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FOUR ENGINES Process Type: 17.200 (Small Internal Combustion Engines (¿500 HP)) Primary Fuel: REFINERY FUEL GAS Throughput:Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: MACT Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COKER FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements: NSPS , NESHAP , MACT

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: MACT Other Applicable Requirements: NSPS , NESHAP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: EAST PROPERTY FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPMEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TWO FLARES Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NORTH PROPERTY FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TWENTY ONE FURNACES Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FOURTEEN HEATERS Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 500.0000 PPMV

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DHT H2 HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: HYDROGEN Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CO BOILER Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: CARBON MONOXIDE Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CCU FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FOUR TAIL GAS INCINERATORS Process Type: 19.200 (Emission Control Afterburners & Incinerators (combustion gasses only)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: WEST PROPERTY FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: MACT Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 500.0000 PPMV Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: THREE FLARESPROCESS NAME: THREE FLARES

Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPM Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ANALYZER Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 300.0000 PPMEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## AR-0077 (final) Date Determination Last Updated: 10/25/2004 Corporate/Company Name: STEELCORR, INC. Permit Number: 2062-AOP-R0

Facility Name: BLUEWATER PROJECT Permit Date: 07/22/2004 (actual) Facility Contact: WYNN CALLAND 2059685152 FRS Number: Facility Description: THE FACILITY IS A NEW SPECIALTY STEEL MILL PRODUCING VARIOUS HOT ROLLED, COLD ROLLED AND GALVANIZED PRODUCTS FOR VARIOUS END USE MARKETS. AFIN: 47-00541 SIC Code: 3312

Permit Type: A: New/Greenfield Facility NAICS Code: 331110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: MISSISSIPPI Facility State: AR Facility ZIP Code: 72370 Permit Issued By: ARKANSAS DEPT OF ENVIRONMENTAL QUALITY (Agency Name) MR. TOM RHEAUME(Agency Contact) (501) 682-0762 rheaume@adeq.state.ar.us Other Agency Contact Info: SHAWN HUTCHINGS 8001 NATIONAL DRIVE LITTLE ROCK, AR 72209 (501) 682-0761 Permit Notes: FUEL: NATURAL GAS

## Process/Pollutant Information

PROCESS NAME: ELECTRIC ARC FURNACE (EAF) Process Type: 81.510 (Electric Arc Furnaces) Primary Fuel: NATURAL GAS Throughput: 350.00 t/h

Process Notes: THROUGHPUT IS T/H OF STEEL

POLLUTANT NAME: Lead (Pb) / Lead Compounds

CAS Number: 7439-92-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Heavy Metals , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0009 LB/T STEEL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FABRIC FILTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0018 GR/DSCF Emission Limit 2: Standard Emission: 0.0018 GR/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) FABRIC FILTER

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2000 LB/T Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR COKE AND SCRAP MANAGEMENT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1300 LB/T Emission Limit 2: Standard Emission: STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SCRAP MANAGEMENT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.0000 LB/T Emission Limit 2: Standard Emission: STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) AIR GAP Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.3500 LB/T Emission Limit 2: Standard Emission: STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LADLE METALLURGY FURNACEPROCESS NAME: LADLE METALLURGY FURNACE

Process Type: 81.340 (Ladle Mettallurgy Processes) Primary Fuel: Throughput: 350.00 T/H

Process Notes: THROUGHPUT IS T/H OF STEEL

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/T STEEL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0500 LB/T STEEL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SIDE DRAFT AIR GAP Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0800 LB/T STEEL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0018 GR/DSCF Emission Limit 2: Standard Emission: 0.0018 GR/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FABRIC FILTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/T STEEL Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CASTER Process Type: 81.350 (Casting & Pouring Processes) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0018 GR/DSCF Emission Limit 2: Standard Emission: 0.0018 GR/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FABRIC FILTER Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: EMISSIONS ROUTED TO EAF BAGHOUSE.



## Process/Pollutant Information

PROCESS NAME: FURNACES, HEATERS, & DRYERS

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NATURAL GAS Throughput: 11.00 MMBTU/H

Process Notes: PROCESS COVERS ANNEALING FURNACES, TUNDISH PREHEATERS AND DRYERS, LADLE PREHEATERS AND DRYERS, VERTICAL

HOLDING STATIONS, CHROMATE DRYERS, AND GALVANIZING LINE AND DRYERS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/MMBTU Emission Limit 2: Standard Emission: 0.1000 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8400 LB/MMBTU Emission Limit 2: Standard Emission: 0.8400 LB/MMBTUDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MMBTU Emission Limit 2: Standard Emission: 0.0006 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0055 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLYEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTU Emission Limit 2: Standard Emission: 0.0076 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COLD MILL, 5 STAND Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 18.9000 LB/H Emission Limit 2: 82.6000 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT/MIST ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWERS Process Type: 99.003 (Comfort Cooling Towers) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 6.0000 LB/H COMBINED FOR ALL COOLING TOWERS Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT/MIST ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MATERIAL HANDLING SILOSPROCESS NAME: MATERIAL HANDLING SILOS

Process Type: 81.380 (Scrap Handling & Preparation Processes) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FABRIC FILTERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GALVANIZING LINE Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: NATURAL GAS Throughput: 9.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTUEmission Limit 2: 0.3000 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MMBTU Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU Emission Limit 2: 0.3000 T/YR Standard Emission: 0.0055 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8400 LB/MMBTU Emission Limit 2: 3.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1500 LB/MMBTU Emission Limit 2: 4.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILERS Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 22.00 MMBTU/H

Process Notes: ENTRY INCLUDES TWO BOILERS. THE 22 MMBTU/H PICKLE LINE BOILER, 51 MMBTU/H VACUUM DEGASSER BOILERS.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MMBTU Emission Limit 2: Standard Emission: 0.0006 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0055 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/MMBTU Emission Limit 2: Standard Emission: 0.0800 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8400 LB/MMBTU Emission Limit 2: Standard Emission: 0.8400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTU Emission Limit 2: Standard Emission: 0.0076 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SLAG/MILL SCALE PROCESSING Process Type: 81.290 (Other Steel Manufacturing Processes) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 3.5000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) WATER APPLICATION AND LIMITED DROP HEIGHTS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PICKLE LINE SCRUBBER Process Type: 81.600 (Pickling Processes) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) WET SCRUBBER AND MIST ELIMINATOR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ROADWAY EMISSIONS Process Type: 99.140 (Paved Roads)Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 26.9000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) APPLICATION OF WETTING AGENT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DEGASSER HOTWELL FLARE

Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: NATURAL GAS Throughput:

Process Notes: THE DEGASSER WILL USE A FLARE TO CONTROL CO EMISSIONS. PARTICULATE EMISSIONS WILL BE CONTROLLED BY THE

HOTWELL.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 7.3200 LB/H Emission Limit 2:Emission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) HOTWELL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY IN FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.0600 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) NATURAL GAS COMBUSTION ONLY IN FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.0600 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TUNNEL FURNACE Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NATURAL GAS Throughput: 160.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0370 LB/MMBTU Emission Limit 2: 26.0000 T/YR Standard Emission: 0.0370 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT 6.0 LB/H

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/MMBTU Emission Limit 2: 70.0000 T/YR Standard Emission: 0.1000 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT: 16 LB/H.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MMBTU Emission Limit 2: 0.5000 T/YR Standard Emission: 0.0006 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT: .1 LB/H

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0050 LB/MMBTU Emission Limit 2: 3.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: ADDITIONAL LIMIT: .9 LB/H

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0076 LB/MMBTU Emission Limit 2: 5.4000 T/YR Standard Emission: 0.0076 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) NATURAL GAS COMBUSTION ONLY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT: 1.3 LB/H



## Facility Information

RBLC ID: 

## AR-0086 (final) Date Determination Last Updated: 02/13/2006 Corporate/Company Name: NUCOR-YAMATO STEEL COMPANY Permit Number: 883-AOP-R4 Facility Name: NUCOR-YAMATO STEEL COMPANY, BLYTHEVILLE MILL Permit Date: 06/11/2004 (actual) Facility Contact: BOB HICE 8707627198 FRS Number: NEW, NOT FOUND Facility Description: SIC Code: 3312 Permit Type: A: New/Greenfield Facility NAICS Code: 331111 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: MISSISSIPPI Facility State: AR Facility ZIP Code: 72316 Permit Issued By: ARKANSAS DEPT OF ENVIRONMENTAL QUALITY (Agency Name) MR. TOM RHEAUME(Agency Contact) (501) 682-0762 rheaume@adeq.state.ar.usPermit Notes:

Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide -2065.0000 (Tons/Year) Nitrogen Oxides (NOx) -457.7000 (Tons/Year) Particulate Matter (PM) -45.2000 (Tons/Year) Sulfur Oxides (SOx) 291.0000 (Tons/Year) Volatile Organic Compounds (VOC) -135.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: EAF #1 BAGHOUSE, SN-01 Process Type: 81.210 (Electric Arc Furnaces) Primary Fuel: NATURAL GAS Throughput: 450.00 T/H STEEL

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 90.0000 LB/H Emission Limit 2: 394.2000 T/YR Standard Emission: 0.2000 LB/T STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR COKE USAGE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LMF #1 BAGHOUSE, SN-35 Process Type: 81.340 (Ladle Mettallurgy Processes)Primary Fuel:

Throughput: 250.00 T/YR STEEL

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 7.0000 LB/H Emission Limit 2: 29.3000 T/YR Standard Emission: 0.0052 GR/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FABRIC FILTER Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 70.0000 LB/H Emission Limit 2: 306.6000 T/YR Standard Emission: 0.0050 LB/T STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) OXIDATION WITH SIDE DRAFT AIR GAPS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 90.0000 LB/H Emission Limit 2: 394.2000 T/YR Standard Emission: 0.3600 LB/T STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR COKE USAGE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: VACUUM TANK DEGASSER HOTWELL FLARE, SN-36 Process Type: 81.370 (Miscellaneous Melt Shop Operations) Primary Fuel: NATURAL GAS Throughput: 250.00 T/YR STEEL

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.4000 LB/H Emission Limit 2: 5.9000 T/YR Standard Emission: 0.0050 LB/T STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLAREEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6000 LB/H Emission Limit 2: 2.3000 T/YR Standard Emission: 0.0020 LB/T STEEL Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) STEAM INJECTION HOTWELL SCRUBBING Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: VTD BOILER Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 50.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.2000 T/YR Standard Emission: 0.0006 LB/MMBTUDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE, NATURAL GAS COMBUSTION Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4000 LB/H Emission Limit 2: 1.7000 T/YR Standard Emission: 0.0075 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 4.2000 LB/H Emission Limit 2: 18.1000 T/YR Standard Emission: 0.0824 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICEEst. % Efficiency:

Compliance Verified: No Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## OH-0276 (final) Date Determination Last Updated: 08/04/2008 Corporate/Company Name: CHARTER MANUFACTURING CO., INC. Permit Number: 13-04176

Facility Name: CHARTER STEEL Permit Date: 06/10/2004 (actual) Facility Contact: TED ROGERS 2167028781 FRS Number: 110000387402 Facility Description: NEW MELT SHOP AT EXISTING FACILITY, INCLUDES NEW: ELECTRIC ARC FURNACE; LADLE METALLURGY FURNACE; VACUUM OXYGEN DEGASSER (VOD); VOC BOILER; CONTINUOUS CASTING MACHINES; 3 SILOS; 4 LADLE PREHEATERS; 4 CUT-OFF-TORCHS; 3 TUNDISH PREHEATERS; PROCESS SPACE HEATER; COOLING TOWER; SLAG PROCESSING; ROADWAYS/PARKING AREAS SIC Code: 3312

Permit Type: A: New/Greenfield Facility NAICS Code: 33 Permit URL: EPA Region: 5 COUNTRY: USA Facility County: CUYAHOGA Facility State: OH Facility ZIP Code: 44125 Permit Issued By: OHIO ENVIRONMENTAL PROTECTION AGENCY (Agency Name) MS. CHERYL SUTTMAN(Agency Contact) (614)644-3617 mailto:cheryl.suttman@epa.ohio.gov Permit Notes: NEW MELT SHOP AT EXISTING FACILITY. ADMISTRATIVE MODIFICATION TO PERMIT 2/12/08 150 TPH CAPACITY, OPERATING AT 100 TPH 710,600 TONS OF LOW CARBON AND STAINLESS STEEL PER ROLLING 12-MONTHS Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 1385.5600 (Tons/Year) Nitrogen Oxides (NOx) 182.6500 (Tons/Year) Particulate Matter (PM) 112.7900 (Tons/Year) Sulfur Oxides (SOx) 99.4200 (Tons/Year) Volatile Organic Compounds (VOC) 75.0200 (Tons/Year)

## Process/Pollutant Information

PROCESS NAME: ELECTRIC ARC FURNACE Process Type: 81.310 (Electric Arc Furnaces) Primary Fuel: ELECTRIC Throughput: 110.00 T/H MELT

Process Notes: SCRAP METAL, COKE, AND PEBBLE LIME IS CHANGED TO THE ELECTRIC ARC FURNACE

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 22.0000 LB/H Emission Limit 2: 71.0600 T/YR PER ROLLING 12-MONTHS FOR EAF AND LMF Standard Emission: 0.2000 LB/T Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) PRODUCTION LIMITS. SEE NOTE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CUYAHOGA COUNTY WAS NON-ATTAINMENT FOR SO2 AT THE TIME THE PERMIT WAS ISSUED; THIS PERMIT WAS A SYNTHETIC MINOR FOR SO2 AT 99.53 TONS; WITH RESTRICTIONS ON PRODUCTION: 710,600 TONS OF STEEL AND 28,000 TONS OF RESULFURIZATION GRADE STEEL. ADDITIONAL LIMITS: FROM ELECTRIC ARC FURNACE AND LADLE METALLURGY FURNACE TOGETHER: 71.06 T/ROLLING 12-MO FROM ALL GRADES OF STEEL EXCEPT RESULFURIZED GRADES. 0.2 LB SO2 EMISSION FACTOR PER TON OF STEEL

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 36.2900 LB/H Emission Limit 2: 117.2500 T/YR Standard Emission: 0.3300 LB/TDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) DIRECT EVACUATION CONTROL AND LOW NOX OXY-FUEL BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: COST ANALYSIS NOT DONE FOR DIRECT EVACUATION CONTROL. 0.33 LB NOX / PER TON OF STEEL, EMISSION FACTOR

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 356.4000 LB/H Emission Limit 2: 1151.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) DIRECT EVACUATION CONTROL Est. % Efficiency: 80.000 Compliance Verified: Unknown Pollutant/Compliance Notes: COST ANALYSIS NOT DONE FOR DIRECT EVACUATION CONTROL. 18 LB CO / PER TON OF STEEL EMISSION FACTOR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 22.0000 LB/H Emission Limit 2: 71.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIPOther Applicable Requirements: SIP

Control Method: (B) DIRECT EVACUATION CONTROL AND OPERATIONAL PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: COST ANALYSIS NOT DONE FOR DIRECT EVACUATION CONTROL. 0.2 LB VOC / T OF STEEL, EMISSION FACTOR

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 12.4300 LB/H Emission Limit 2: 40.1500 T/YR Standard Emission: 0.0024 GR/DSCF FROM MELTSHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Yes Pollutant/Compliance Notes:

POLLUTANT NAME: Lead (Pb) / Lead Compounds

CAS Number: 7439-92-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Heavy Metals , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.5500 LB/H Emission Limit 2: 1.7800 T/YR Standard Emission: 0.0001 GR/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes: LIMIT IS 0.000065 GR/DSCF; RBLC ROUNDS DOWN TO 0.0001

POLLUTANT NAME: Mercury

CAS Number: 7439-97-6 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Heavy Metals , InOrganic Compounds ) Emission Limit 1: 0.0520 LB/H Emission Limit 2: 0.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) LIMITATION ON MERCURY CONTAINING SCRAP Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THESE LIMITS REPRESENT THE MAXIMUM FOR THE ENTIRE MELT SHOP, BUT ALSO LIMIT FOR EAF ALONE.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 6.0000 % OPACITY OPACITY FROM EAF Emission Limit 2: Standard Emission: 3.0000 % OPACITY OPACITY FROM MELTSHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: BOTH OPACITY LIMITS FROM 60.272A(A)

## Process/Pollutant Information

PROCESS NAME: LADLE METALLURGY FURNACE Process Type: 81.340 (Ladle Mettallurgy Processes) Primary Fuel: ELECTRIC Throughput: 110.00 T/H

Process Notes: ALLOY MIXING AND RE-SULFURIZATION OF MOLTEN STEEL IN LADLE METALLURGY FURNACE

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 33.0000 LB/H Emission Limit 2: 107.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2200 LB/H Emission Limit 2: 0.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Lead (Pb) / Lead Compounds

CAS Number: 7439-92-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Heavy Metals , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: 0.0001 GR/DSCF Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS 0.000065 GR/DSCF; RBLC ROUNDS OFF TO 0.0001

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 3.0000 % OPACITY OPACITY FROM MELTSHOP BAGHOUSE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: NSPS , SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 220.0000 LB/H RESULFURIZED GRADE STEEL Emission Limit 2: 22.0000 LB/H ALL OTHER GRADES OF STEEL Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CUYAHOGA COUNTY WAS NON-ATTAINMENT FOR SO2 AT THE TIME THE PERMIT WAS ISSUED; THIS PERMIT WAS A SYNTHETIC MINOR FOR SO2 AT 99.53 TONS; WITH RESTRICTIONS ON PRODUCTION: 710,600 TONS OF STEEL AND 28,000 TONS OF RESULFURIZATION GRADE STEEL. ADDITIONAL LIMITS: 28.0 T/ROLLING 12-MO FROM RESULFURIZED GRADE STEEL; AND FROM ELECTRIC ARC FURNACE AND LADLE METALLURGY FURNACE TOGETHER: 71.06 T/ROLLING 12-MO FROM ALL GRADES OF STEEL EXCEPT RESULFURIZED GRADES.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.2000 LB/H Emission Limit 2: 7.2000 T/YR Standard Emission: 0.0024 GR/DSCF FROM MELTSHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.6500 LB/H Emission Limit 2: 5.3200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: VACUUM OXYGEN DEGASSER VESSEL W/ FLARE

Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: STEAM Throughput: 150.00 T/H STEEL

Process Notes: VACUUM PUMP EQUIPPED VESSEL, FOR DEGASSING, DECARBURIZATION, AND ALLOYING OF STEEL; WITH ARGON, OXYGEN

LANCE, AND STEAM FROM BOILER; WITH FLARE TO CONTROL CO FROM LOW CARBON AND STAINLEES STEEL PRODUCTION ONLY. 150 TPH CAPACITY, OPERATING AT 100 TPH 710,600 TONS OF LOW CARBON AND STAINLESS STEEL PER ROLLING 12-MONTHS

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 23.3100 LB/H O2 LANSING DEGASSING LOW C & STAINLESS Emission Limit 2: 82.8000 T/YR O2 LANSING DEGASSING LOW C & STAINLESS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: SIP Control Method: (A) FLARE TO CONTROL CO FOR LOW CARBON AND STAINLESS STEEL ONLY; NOT DURING NATURAL DECARBURIZATION Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSIONS FROM FLARE'S NATURAL GAS COMBUSTION: 1.32 LB CO/H AND 5.78 T CO/YR

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H FROM FLARE NATURAL GAS COMBUSTION Emission Limit 2: 0.5200 T/YR FROM FLARE NATURAL GAS COMBUSTION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS FROM NATURAL GAS COMBUSTION FROM FLARE; ONLY DURING OXYGEN LANCING DEGASSING PROCESS FOR LOW CARBON AND STAINLESS STEEL PRODUCTION.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.5700 LB/H FROM FLARE NATURAL GAS COMBUSTION Emission Limit 2: 6.8700 T/YR FROM FLARE NATURAL GAS COMBUSTION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIPControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS FROM NATURAL GAS COMBUSTION FROM FLARE; ONLY DURING OXYGEN LANCING DEGASSING PROCESS FOR LOW CARBON AND STAINLESS STEEL PRODUCTION.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0900 LB/H FROM FLARE NATURAL GAS COMBUSTION Emission Limit 2: 0.3900 T/YR FROM FLARE NATRUAL GAS COMBUSTION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS FROM NATURAL GAS COMBUSTION FROM FLARE; ONLY DURING OXYGEN LANCING DEGASSING PROCESS FOR LOW CARBON AND STAINLESS STEEL PRODUCTION.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0090 LB/H FROM FLARE NATURAL GAS COMBUSTION Emission Limit 2: 0.0400 T/YR FROM FLARE NATURAL GAS COMBUSTION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes: EMISSIONS FROM NATURAL GAS COMBUSTION FROM FLARE; ONLY DURING OXYGEN LANCING DEGASSING PROCESS FOR LOW CARBON AND STAINLESS STEEL PRODUCTION.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITY Emission Limit 2: Standard Emission: % OPACITY NO VISIBLE EMISSIONS Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: VACUUM OXYGEN DEGASSER W/O FLARE

Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: STEAM Throughput: 110.00 T/H STEEL

Process Notes: VACUUM PUMP EQUIPPED VESSEL, FOR DEGASSING, DECARBURIZATION, AND ALLOYING OF STEEL; WITH ARGON, OXYGEN

LANCE, AND STEAM FROM BOILER; WITHOUT FLARE DURING NATURAL DECARBURIZATION PROCESS OF STEEL.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 25.0000 LB/H NATURAL DECARBURIZATION OF STEEL Emission Limit 2: 59.2200 T/YR NATURAL DECARBURIZATION OF STEELStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STACK TESTING CONDUCTED DURING THE NATURAL DECARBURIZATION OF STEEL, ONLY, NOT DURING LOW C OR STAINLESS STEEL PRODUCTION

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: % OPACITY Emission Limit 2: Standard Emission: % OPACITY NO VISIBLE EMISSIONS Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER FOR VACUUM OXYGEN DEGASSER VESSEL

Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 28.60 MMBTU/H

Process Notes: VACUUM OXYGEN DEGASSER VESSEL BOILER, WITH LOW NOX BURNER MODIFIED FROM 25 TO 28.6 MMBTU/HR IN

ADMINISTRATIVE MODIFICATION DATED 2/12/08POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H FROM NATURAL GAS COMBUSTION Emission Limit 2: 0.0700 T/YR FROM NATURAL GAS COMBUSTION Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1500 LB/H FROM NATURAL GAS COMBUSTION Emission Limit 2: 0.6800 T/YR FROM NATURAL GAS COMBUSTION Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s):Pollutant Group(s):

Emission Limit 1: 20.0000 % OPACITY 6 MINUTE AVERAGE Emission Limit 2: 20.0000 % OPACITY AS A 6-MINUTE AVERAGE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VE MAY EXCEED 20% OPACITY, AS A 6-MINUTE AV, FOR NOT MORE THAN 6 CONSECUTIVE MINUTES IN ANY 60 MINUTES, BUT SHALL NOT EXCEED 60% OPACITY AS A 6-MINUTE AV AT ANY TIME.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2100 LB/H FROM NATURAL GAS COMBUSTION Emission Limit 2: 0.9300 T/YR FROM NATURAL GAS COMBUSTION Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.3500 LB/H FROM NATURAL GAS COMBUSTION Emission Limit 2: 10.3000 T/YR FROM NATURAL GAS COMBUSTIONStandard Emission: NOT AVAILABLE

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.8000 LB/H FROM NATURAL GAS COMBUSTION Emission Limit 2: 12.2700 T/YR FROM NATURAL GAS COMBUSTION Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) LOW NOX BURNER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HANDLING OF STEEL SCRAP Process Type: 81.380 (Scrap Handling & Preparation Processes) Primary Fuel: Throughput: 120.00 T/H SCRAP

Process Notes: HANDLING OF STEEL SCRAP CONDUCTED INSIDE BUILDING.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PMCAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.5200 LB/H Emission Limit 2: 8.1200 T/YR Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) INSIDE BUILDING Est. % Efficiency: 70.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY FUGITIVE DUST, AS A 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) INSIDE BUILDING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LADLE PREHEATER AND DRYER, 4 UNITS

Process Type: 81.340 (Ladle Mettallurgy Processes)Primary Fuel: NATURAL GAS

Throughput: 10.00 MMBTU/H

Process Notes: FOUR NATURAL GAS FIRED LADLE PREHEATERS AND DRYERS CHANGED FROM 6 PREHEATERS TO 4 PREHEATERS IN THE

ADMINISTRATIVE MODIFICATION OF 2/12/08

POLLUTANT NAME: Hydrocarbons, Total

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.1000 LB/H FROM COMBUSTION OF NATURAL GAS Emission Limit 2: 0.4400 T/YR FROM COMBUSTION OF NATURAL GAS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: REGULATED POLLUTANT IS ORGANICS. LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALL PREHEATERS

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0060 LB/H FROM COMBUSTION OF NATURAL GAS Emission Limit 2: 0.0300 T/YR FROM COMBUSTION OF NATURAL GAS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALLPollutant/Compliance Notes: LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALL PREHEATERS

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 3.0000 % OPACITY OPACITY FROM MELTSHOP BAGHOUSE STACK Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS , SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0740 LB/H FROM COMBUSTION OF NATURAL GAS Emission Limit 2: 0.3200 T/YR FROM COMBUSTION OF NATURAL GAS Standard Emission: 0.0024 GR/DSCF FROM MELTSHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALL PREHEATERSPOLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8200 LB/H FROM COMBUSTION OF NATURAL GAS Emission Limit 2: 3.5900 T/YR FROM COMBUSTION OF NATURAL GAS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALL PREHEATERS

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.9800 LB/H FROM COMBUSTION OF NATURAL GAS Emission Limit 2: 4.2900 T/YR FROM COMBUSTION OF NATURAL GAS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALL PREHEATERS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H FROM COMBUSTION OF NATURAL GAS Emission Limit 2: 0.2400 T/YR FROM COMBUSTION OF NATURAL GAS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS ARE FOR EACH PREHEATER; LIMIT TIMES 4 EQUALS TOTAL EMISSIONS FROM ALL PREHEATERS



## Process/Pollutant Information

PROCESS NAME: CONTINUOUS CASTER Process Type: 81.350 (Casting & Pouring Processes) Primary Fuel: Throughput: 110.00 T/H STEEL

Process Notes: CONTINUOUS CASTING OF STEEL

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1000 LB/H Emission Limit 2: 3.5500 T/YR Standard Emission: 0.0024 GR/DSCF MELT SHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 3.0000 % OPACITY 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 3.0000 % OPACITY OPACITY FROM MELTSHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: RACT Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TUNDISH PREHEATER, 3 UNITS Process Type: 81.340 (Ladle Mettallurgy Processes) Primary Fuel: NATURAL GAS Throughput: 12.00 MMBTU/H

Process Notes: 3 UNITS, MODIFIED FROM 20 TO 12 MMBTU/HR EACH IN ADMINISTRATIVE MODIFICATION DATED 2/12/08

POLLUTANT NAME: Hydrocarbons, Total

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds ) Emission Limit 1: 0.1300 LB/H ORGANICS Emission Limit 2: 0.5700 T/YR ORGANICS Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: POLLUTANT REGULATED IS ORGANICS. LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISH PREHEATERS

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0070 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISH PREHEATERS

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 3.0000 % OPACITY 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 3.0000 % OPACITY OPACITY FROM MELTSHOP BAGHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A)Control Method: (A)

Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0900 LB/H Emission Limit 2: 0.3900 T/YR Standard Emission: 0.0024 GR/DSCF FROM MELTSHOP BAGFHOUSE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (A) BAGHOUSE Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISH PREHEATERS

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.9900 LB/H Emission Limit 2: 4.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISHPollutant/Compliance Notes: LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISH PREHEATERS

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.1800 LB/H Emission Limit 2: 5.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISH PREHEATERS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR EACH UNIT; LIMIT TIMES 3 EQUALS TOTAL EMISSIONS FROM ALL TUNDISH PREHEATERS

## Process/Pollutant Information

PROCESS NAME: SILOS CARBON AND LIME Process Type: 81.380 (Scrap Handling & Preparation Processes) Primary Fuel: Throughput: 1200.00 ACFM

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4500 T/YR Emission Limit 2: 0.1000 LB/H Standard Emission: 0.0100 GR/DSCF FROM BIN VENT Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , SIP Control Method: (A) BIN VENT Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS FOR EACH SILO; LIMIT TIMES 2 EQUALS TOTAL EMISSIONS FROM 2 SILOS, ONE FOR CARBON, ONE FOR LIME

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 10.0000 % OPACITY 6-MINUTE AVERAGE Emission Limit 2: Standard Emission: 10.0000 % OPACITY AS A 6-MINUTE AVERAGE, FROM BIN VENT Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: NSPS , SIPControl Method: (A) BIN VENT

Est. % Efficiency: 99.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SLAG PROCESSING OPERATION Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: Throughput: 250.00 T/H

Process Notes: 250 T/HR SLAG PROCESSING OPERATION, INCLUDES: DROP BALL CRUSHING, MATERIAL HANDLING, DUMPING

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7900 LB/H Emission Limit 2: 0.5600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) ENCLOSURE WHERE PRACTICLE Est. % Efficiency: Compliance Verified: No Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 15.0000 % OPACITY AS A 6-MINUTE AVERAGE Emission Limit 2:Standard Emission: 15.0000 % OPACITY 6-MINUTE AVERAGE

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (P) ENCLOSURE WHERE PRACTICLE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER Process Type: 81.390 (Other Steel Foundry Processes) Primary Fuel: Throughput: 25000.00 GAL/MIN

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5000 LB/H Emission Limit 2: 6.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS FROM 6 COOLING TOWERS TOGETHER WITH TOTAL THROUGHPUT OF 25,000 GAL/M AND 1.5 MILLION GALLONS PER YEAR FOR COOLING PROCESS WATER

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS FROM 6 COOLING TOWERS TOGETHER WITH TOTAL THROUGHPUT OF 25,000 GAL/M AND 1.5 MILLION GALLONS PER YEAR FOR COOLING PROCESS WATER



## Facility Information

RBLC ID: 

## WV-0021 (final) Date Determination Last Updated: 09/20/2004 Corporate/Company Name: CABOT CORPORATION Permit Number: R14-0021

Facility Name: OHIO RIVER PLANT Permit Date: 06/09/2004 (actual) Facility Contact: CHRISTINE BURKETT 3046652441 FRS Number: Facility Description: AN EXISTING 3-UNIT, 4-REACTOR CARBON BLACK PRODUCTION FACILITY. TRADITIONALLY, HAS FLARED OR COMBUSTED ALL TAIL GAS. **THIS FACILITY HAS BEEN PERMANENTLY SHUTDOWN*** SIC Code: 2895

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 325182 Permit URL: EPA Region: 3 COUNTRY: USA Facility County: PLEASANTS Facility State: WV Facility ZIP Code: 26184 Permit Issued By: WEST VIRGINIA DEPT. OF ENVRIONMENTAL PROTECTION; DIV. OF AIR QUALITY (Agency Name) MR. JOE KESSLER, PE(Agency Contact) (304)926-0499X1219 Joseph.r.kessler@wv.govOther Agency Contact

Info: JOE KESSLER, PE 601 57TH ST., SE CHARLESTON, WV 25304 304-926-0499 X1219 JOSEPH.R.KESSLER@WV.GOV Permit Notes: AN EXISTING 3-UNIT, 4-REACTOR CARBON BLACK PRODUCTION FACILITY CONSTRUCTED IN 1967. TRADITIONALLY, HAS FLARED OR COMBUSTED ALL TAIL GAS. FOR THIS ACTION, CABOT CAPPED TOTAL SO2 EMISSIONS TO EQUAL PAST ACTUAL EMISSIONS. THEREFORE, SO2 WAS NOT SUBJECT TO PSD. NOX AND PM INCREASED AND WERE SUBJECT TO PSD AS A RESULT OF THE COMBUSTION OF THE WASTE TAIL GAS IN THE FLARES AND DRYERS AND NATURAL GAS IN ONE DRYER AND A BOILER. CO IS IN THE TAIL GAS AND IS DESTROYED BY COMBUSTION, BUT INCREASED SIGNIFICANTLY DUE TO PRODUCTION INCREASES AND WAS SUBJECT TO PSD REVIEW. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 WV Dolly Sods 100km - 50km CLASS1 VA James River Face > 250 km CLASS1 WV Otter Creek 100km - 50km CLASS1 VA Shenandoah NP > 250 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 6620.0000 (Tons/Year) Nitrogen Oxides (NOx) 2134.0000 (Tons/Year) Particulate Matter (PM) 177.0000 (Tons/Year) Sulfur Oxides (SOx) 0 (Tons/Year) Volatile Organic Compounds (VOC) 20.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: BOILER, NATURAL GAS, 39.00 MMBTU Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 365.00 MMSCF/YR

Process Notes: Boiler has MDHI of 39.00 mmbtu and combusts natural gas only.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.0800 PPH Emission Limit 2: 9.1300 T/YR Standard Emission: 0.0500 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) LOW-NOX BURNERS/FLUE-GAS RECIRCULATION Est. % Efficiency: 50.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.5000 PPH Emission Limit 2: 15.3400 T/YR Standard Emission: 0.0900 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3200 PPH Emission Limit 2: 1.3900 T/YR Standard Emission: 0.0080 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRYER HEATER, UNIT #2, 40.00 MMBTU

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NATURAL GAS Throughput: 365.00 MMSCF/YR

Process Notes: Unit 2 Reactor has 2 identical Dryers in parallel: both combust only natural gas and have the same MDHI 40 mmbtu/h each, and emission rates.

Therefore, only entered into RBLC once.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.5000 PPH Emission Limit 2: 15.3400 T/YR Standard Emission: 0.0900 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3200 PPHEmission Limit 2: 1.3900 T/YR

Standard Emission: 0.0090 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.0900 PPH Emission Limit 2: 9.1300 T/YR Standard Emission: 0.0500 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW-NOX BURNERS/FLUE-GAS RECIRCULATION Est. % Efficiency: 50.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRYER HEATER, UNIT #3, 40.00 MMBTU Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: TAIL GAS Throughput: 5358.00 MMSCF/YR

Process Notes: Unit 3 Dryer has MDHI 40.00 mmbtu and combusts tail gas. Not considered a source of CO but a control device.

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 68.0000 PPH Emission Limit 2: 298.0000 T/YR Standard Emission: 1.7000 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOx produced from constituent N contained in tail gas. Thermal NOx not considered significant source of NOx from this source.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 5.9800 PPH Emission Limit 2: 26.2100 T/YR Standard Emission: 0.1500 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DRYER HEATER, UNIT #1, 40.00 MMBTU Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters)Primary Fuel: TAIL GAS

Throughput: 4386.00 MMSCF/YR

Process Notes: Unit 1 Dryer has MDHI 40.00 mmbtu and combusts tail gas. Not considered a source of CO but a control device.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 5.0300 PPH Emission Limit 2: 22.0500 T/YR Standard Emission: 0.1300 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 57.0000 PPH Emission Limit 2: 251.0000 T/YR Standard Emission: 1.4500 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: CARBON BLACK REACTOR, UNIT #1

Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput: 151501.00 T/YR

Process Notes: Reactor produces carbon black and waste tail gas. Carbon black captured in the Main Unit Filter, tail gas combusted in either the flare or dryers.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 853.0000 PPH Emission Limit 2: 3736.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1700 PPH Emission Limit 2: 5.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) MAIN UNIT FILTER

Est. % Efficiency: 99.950 Compliance Verified: Unknown Pollutant/Compliance Notes: Carbon Black not captured in Main Unit Filter pass out through flare stack. Emission rates above only reflect uncaptured carbon black and not PM emissions created from flare combustion.



## Process/Pollutant Information

PROCESS NAME: CARBON BLACK REACTOR, UNIT #2

Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput: 206302.00 T/YR

Process Notes: Reactor produces carbon black and waste tail gas. Carbon black captured in the Main Unit Filter, tail gas combusted in either the flare or dryers.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1200 PPH Emission Limit 2: 4.9100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) MAIN UNIT FILTER Est. % Efficiency: 99.950 Compliance Verified: Unknown Pollutant/Compliance Notes: Carbon Black emissions not captured in Main Unit Filter pass out through flare stack. Emission rates above only reflect uncaptured carbon black and not PM emissions created from flare combustion.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Pollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 714.0000 PPH Emission Limit 2: 3129.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CARBON BLACK REACTOR, UNIT #3

Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput: 191658.00 T/YR

Process Notes: Reactor produces carbon black and waste tail gas. Carbon black captured in the Main Unit Filter, tail gas combusted in either the flare or dryers.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 618.0000 PPH Emission Limit 2: 2705.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9000 PPH Emission Limit 2: 3.9400 T/YR Standard Emission: 0.9000 PPH Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) MAIN UNIT FILTER Est. % Efficiency: 99.950 Compliance Verified: Unknown Pollutant/Compliance Notes: Carbon Black not captured in Main Unit Filter pass out through flare stack. Emission rates above only reflect uncaptured carbon black and not PM emissions created from flare combustion.



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT #1 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: TAIL GAS Throughput: 14659.00 MMSCF/YR

Process Notes: Combustion of tail gas in the flare creates NOx and PM emissions.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 206.0000 PPH Emission Limit 2: 901.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Nox created from constituent Nitrogen in tail gas, not considered thermal NOx. Therefore, thermal Nox controls not considered feasible.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 18.5400 PPH Emission Limit 2: 81.1900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT #2 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: TAIL GAS Throughput: 18969.00 MMSCF/YR

Process Notes: Combustion of tail gas in the flare creates NOx and PM emissions.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 197.0000 PPH Emission Limit 2: 861.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOx created from constituent Nitrogen in tail gas, not considered thermal NOx. Therefore, thermal Nox controls not considered feasible.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 18.0000 PPH Emission Limit 2: 78.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE, UNIT #3 Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: TAIL GAS Throughput: 18120.00 MMSCF/YRProcess Notes: Combustion of tail gas in the flare creates NOx and PM emissions.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 159.0000 PPH Emission Limit 2: 696.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Nox created from constituent Nitrogen in tail gas, not considered thermal NOx. Therefore, thermal Nox controls not considered feasible.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 14.0000 PPH Emission Limit 2: 63.0000 T/R Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: CARBON BLACK HANDLING

Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes: Includes carbon black handling, bagging, and loading.

POLLUTANT NAME: Particulate matter, fugitive

CAS Number: PM Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 99.5000 % REDUCTION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) PROCESS AND DUST FILTERS, BAG COLLECTORS, AND BIN VENTS. Est. % Efficiency: 99.500 Compliance Verified: Unknown Pollutant/Compliance Notes: All handling operations controlled by filters, minimum required efficiency is 99.5%. No other emission rate limits.



## Facility Information

RBLC ID: 

## TX-0451 (final) Date Determination Last Updated: 06/19/2007 Corporate/Company Name: DIAMOND SHAMROCK REFINING COMPANY LP Permit Number: P1017 Facility Name: DIAMOND SHAMROCK REFINING VALERO Permit Date: 05/20/2004 (actual) Facility Contact: MS. LISA TROWBRIDGE 3617868286 FRS Number: 110028248689 Facility Description: SULFUR PLANT EXPANSION PROJECT SIC Code: 2911 Permit Type: U: Unspecified NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USAFacility County: LIVE OAK

Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes:



## Process/Pollutant Information

PROCESS NAME: COMBUSTION UNITS, TANKS, PROCESS VENTS, LOADING, FLARES, FUGITIVES (4), WASTEWATER, COOLING TOWERS

Process Type: 19.900 (Other Misc. Combustion) Primary Fuel: Throughput:

Process Notes: SOURCES ARE COMBUSTION UNITS, TANKS, PROCESS VENTS, LOADING, FLARES, FUGITIVES (4), WASTEWATER, COOLING

TOWERS

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.0500 LB/H Emission Limit 2: 10.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 392.6200 LB/H Emission Limit 2: 1051.6200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 341.9800 LB/H Emission Limit 2: 1462.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5654.2700 LB/H Emission Limit 2: 2132.4600 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 466.3800 LB/H Emission Limit 2: 1831.0501 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 69.2100 LB/H Emission Limit 2: 264.4400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 17.6700 LB/H Emission Limit 2: 34.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0449 (final) Date Determination Last Updated: 07/10/2007 Corporate/Company Name: UNION CARBIDE CORPORATION - A SUBSIDIARY OF DOW CC Permit Number: P118M4 Facility Name: UCC SEADRIFT OPERATIONS Permit Date: 04/03/2004 (actual) Facility Contact: MS. RONDA A WOODS 3615532224 FRS Number: 110011451623 Facility Description: LOW PRESSURE POLYETHYLENE LPPE UNIT NO. 1 & NO. 2 SIC Code: 2869 Permit Type: U: Unspecified NAICS Code: 325188 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: CALHOUNFacility State: TX

Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes:



## Process/Pollutant Information

PROCESS NAME: RXN AND ETHYLENE PURIFICATION FUGITIVES (8) Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.0400 LB/H Emission Limit 2: 25.5600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ANALYZER VENTS Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel:Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2200 LB/H Emission Limit 2: 0.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SMALL FLARE Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 52.8600 LB/H Emission Limit 2: 70.3100 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MEET HEATING VALUE AND VELOCITY REQUIREMENT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 17.0800 LB/H Emission Limit 2: 22.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) MEET HEATING VALUE AND VELOCITY REQUIREMENT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 48.3400 LB/H Emission Limit 2: 62.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MEETS HEATING VALUE AND VELOCITY REQUIREMENTEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CYCLE GAS COMPRESSOR OIL VENT Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CATALYST TRANSFER TANK VENT FILTER (2) Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: G-3 REACTOR SED BED VENT Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM), Organic Condensables

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 8.1300 LB/H Emission Limit 2: 0.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: POLYETHYLENE DUST



## Process/Pollutant Information

PROCESS NAME: CATALYST VENT FILTER Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LARGE FLARE Process Type: 19.310 (Chemical Plant Flares) Primary Fuel:Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 22.6900 LB/H Emission Limit 2: 2.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MEETS HEATING VALUES AND VELOCITY REQ. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 4.4500 LB/H Emission Limit 2: 0.4100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MEETS HEATING VALUES AND VELOCITY REQ. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 48.7800 LB/H Emission Limit 2: 5.2200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MEETS HEATING VALUES AND VELOCITY REQ. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LARGE FLARE START-UP, SHUTDOWN, MAINTENANCE Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 280.6300 LB/H Emission Limit 2: 1.6800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES DURING THESE EVENTSEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 55.0700 LB/H Emission Limit 2: 0.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES DURING THESE EVENTS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 610.0000 LB/H Emission Limit 2: 3.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: FLARE BEFOER THE RECYCLE COMPRESSOR PROJECTS IS COMPLETE Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 100.7700 LB/H Emission Limit 2: 141.2300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERSEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 12.0700 LB/H Emission Limit 2: 16.4800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.3800 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 105.6100 LB/H Emission Limit 2: 137.7300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE AFTER THE RECYCLE COMPRESSOR PROJECTS IS COMPLETE Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 92.9800 LB/H Emission Limit 2: 90.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERSEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 11.1600 LB/H Emission Limit 2: 10.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.3800 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 98.6600 LB/H Emission Limit 2: 92.8100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE NATURAL GAS COMBUSTION (6) Process Type: 19.310 (Chemical Plant Flares)Primary Fuel: NATURAL GAS

Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 86.1800 LB/H Emission Limit 2: 74.6900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.5000 LB/H Emission Limit 2: 0.4300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 10.0500 LB/H Emission Limit 2: 8.7100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.0000 LB/H Emission Limit 2: 2.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) MEETS HEATING VALUES AND VELOCITY REQ. AND BTU ANALYZERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STARTUP, SHUTDOWN, MAINTENANCE BEFORE THE RECYCLE PROJECT IS COMPLETE (5) Process Type: 19.310 (Chemical Plant Flares)Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 380.8100 LB/H Emission Limit 2: 6.8500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 44.5000 LB/H Emission Limit 2: 0.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.3800 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: 319.9000 LB/H

Emission Limit 2: 5.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STARTUP, SHUTDOWN, MAINTENANCE AFTER THE RECYCLE PROJECT IS COMPLETE (5) Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 386.7900 LB/H Emission Limit 2: 10.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 45.2000 LB/H Emission Limit 2: 1.1900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 1.3800 LB/H

Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 325.2500 LB/H Emission Limit 2: 8.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: AREA FUGITIVES (4) Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4.9900 LB/H Emission Limit 2: 21.8400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## AZ-0042 (final) Date Determination Last Updated: 05/24/2005 Corporate/Company Name: NORTHWEST REGIONAL LANDFILL Permit Number: V97016 Facility Name: NORTHWEST REGIONAL LANDFILL Permit Date: 10/27/2003 (actual) Facility Contact: DAVE BEARDEN (602) 708-9815 FRS Number: 110001693392 Facility Description: MUNICIPAL LANDFILL SIC Code: 4953 Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 562212

Permit URL: EPA Region: 9 COUNTRY: USA Facility County: MARICOPA Facility State: AZ Facility ZIP Code: 85374 Permit Issued By: MARICOPA CO AIR POLLUTION CONTROL, AZ (Agency Name) MR. WILLIAM WILEY(Agency Contact) (602) 506-6904 WWILEY@MARICOPA.GOV Other Agency Contact Info: DALE A LIEB AZ (602) 506-6738Permit Notes:

Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 AZ Superstition < 100 km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 225.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: FLARE, ENCLOSED Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: LANDFILL GAS Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0410 LB/MMBTU Emission Limit 2: Standard Emission: 0.0410 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1300 LB/MMBTUEmission Limit 2:

Standard Emission: 0.1300 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: INTERNAL COMBUSTION ENGINE Process Type: 17.150 (Other Gaseous) Primary Fuel: LANDFILL GAS Throughput: 1410.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.6000 G/B-HP-H Emission Limit 2: 4500.0000 PPM Standard Emission: 0.6000 G/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.5000 G/B-HP-H Emission Limit 2: 280.0000 PPM Standard Emission: 2.5000 G/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## WI-0204 (final) Date Determination Last Updated: 12/09/2003 Corporate/Company Name: UNITED WISCONSIN GRAIN PRODUCERS Permit Number: 03-DCF-048

Facility Name: UWGP - FUEL GRADE ETHANOL PLANT Permit Date: 08/14/2003 (actual) Facility Contact: CARL T. BENEK (920) 484-3943 FRS Number: 110016896705 Facility Description: FERMENTATION BASED PROCESS WITH DISTILLATION, MOLECULAR SIEVES FOR FINAL WATER REMOVAL. ETHANOL DENATURED USING GASOLINE. SIC Code: 2869

Permit Type: A: New/Greenfield Facility NAICS Code: 325193 Permit URL: EPA Region: 5 COUNTRY: USA Facility County: COLUMBIA Facility State: WI Facility ZIP Code: 53935 Permit Issued By: WISCONSIN DEPT OF NATURAL RESOURCES; AIR MGMT. PROGRAM (Agency Name) MR. ANDREW M. STEWART(Agency Contact) (608)266-6876 andrew.stewart@wisconsin.govOther Agency Contact

Info: DON C. FAITH III WI (608) 267-3135 Permit Notes: 50 MILLION GALLON PER YEAR FUEL GRADE ETHANOL FACILITY; SYNTHETIC MINOR SOURCE (NOT SUBJECT TO PSD). APPLICATION COMPLETE ON 6/9/03.



## Process/Pollutant Information

PROCESS NAME: BOILER /OXIDIZER ( DRYER / DISTILLATION), P10

Process Type: 12.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 140.00 MMBTU/H

Process Notes: Boiler works as control device. RECEIVES VOC'S FROM DISTILLATION AND RELATED PROCESSES AND FROM Distillers dried grain with

solubles (DDGS) DRYER (85 MMBTU/HR.). SUBJECT TO DB

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.7000 LB/H Emission Limit 2: 0.3650 LB/T TON DDGS AT 11% MOISTURE Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) PROCESS IS THE CONTROL FOR OTHER SOURCES LISTED IN PROCESS ENTRY. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: SYNTHETIC MINOR SOURCE. PROPOSED TO AVOID PSD / TITLE V MAJOR SOURCE STATUS. BOILER / OXIDIZER GENERATES STEAM AND CONSUMES VOC'S FROM DISTILLATION, DDGS DRYING AND OTHER OPERATIONS; EST. 99% DEST.; 98% OVERALL CONTROL.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: UnspecifiedTest Method: Unspecified

Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 5.5000 LB/H Emission Limit 2: 0.3000 LB/T TON DDGS AT 11% MOISTURE Standard Emission: 0.0400 LB/MMBTU calculated Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 90.000 Compliance Verified: Unknown Pollutant/Compliance Notes: SYNTHETIC MINOR SOURCE. BOILER / OXIDIZER CONSUMES COMBUSTABLE PARTICULATE MATTER WHICH ESCAPES DDGS DRYER.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 18.4000 LB/H Emission Limit 2: Standard Emission: 0.1300 LB/MMBTU calculated Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: 90.000 Compliance Verified: Unknown Pollutant/Compliance Notes: SYNTHETIC MINOR SOURCE. BOILER / OXIDIZER CONSUMES CO PRODUCED BY DDGS DRYER

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0950 LB/MMBTU Emission Limit 2:Emission Limit 2:

Standard Emission: 0.0950 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) BOILER / BURNER DESIGN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: SYNTHETIC MINOR SOURCE: LIMIT (SLIGHTLY) MORE STRINGENT THAN NSPS



## Process/Pollutant Information

PROCESS NAME: BYPASS FLARE, BIOMETHANATOR - P11 Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: NATURAL GAS Throughput: 6.40 MMBTU/H

Process Notes: FLARE USED TO CONSUME ANEROBIC DIGESTION BYPRODUCTS WHEN DDGS DRYER IS NOT IN OPERATION.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) OPERATION LIMIT: NO MORE THAN 5040 H/YR Est. % Efficiency: 94.000 Compliance Verified: Unknown Pollutant/Compliance Notes: FLARE USED TO CONSUME ANAEROBIC DIGESTION BYPRODUCTS WHEN DDGS DRYER IS NOT IN OPERATION.POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: Standard Emission: 0.0090 LB/MMBTU calculated Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.4000 LB/H Emission Limit 2: Standard Emission: 0.3750 LB/MMBTU calculated Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) OPERATION LIMIT: NO MORE THAN 5040 H/YR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GRAIN RECEIVING / TRANSPORT / STORAGE, P20 Process Type: 70.290 (Other Grain Handling )Primary Fuel:

Throughput: 18000000.00 BU/YR

Process Notes: throughput is annual maximum

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0000 LB/H Emission Limit 2: Standard Emission: see note Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) ENCLOSURE; BAGHOUSE (10:1 A/C); FUGITIVE DUST CONTROL Est. % Efficiency: 97.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LB/H limit is set by State Reg. in permit, emission limit in gr/dscf is not available



## Process/Pollutant Information

PROCESS NAME: CORN MILLING / MILLED CORN TRANSPORT, P30 Process Type: 70.290 (Other Grain Handling ) Primary Fuel: Throughput: 18000000.00 BU/YR

Process Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8000 LB/H Emission Limit 2: Standard Emission: see noteDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) ENCLOSURE; BAGHOUSE (10:1 A/C) Est. % Efficiency: 97.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LB/H limit is set by State Reg. in permit, emission limit in gr/dscf is not available



## Process/Pollutant Information

PROCESS NAME: FERMENTATION PROCESS, P40 Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 1091000.00 GAL/D

Process Notes: Throughput is GAL/D FERM. SLURRY

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 7.4000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) WET SCRUBBER (PACKED TOWER); WATER RECYCLED TO PROCESS Est. % Efficiency: 98.700 Compliance Verified: Unknown Pollutant/Compliance Notes: SYNTHETIC MINOR SOURCE.



## Process/Pollutant Information

PROCESS NAME: LOADING RACK WITH FLARE, P50PROCESS NAME: LOADING RACK WITH FLARE, P50

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput: 50000000.00 GAL/YR

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.4000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) FLARE / VAPOR COLLECTION Est. % Efficiency: 94.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: LARGE STORAGE TANKS, T61, T62, T63, T64, T65 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput: 50000000.00 GAL/YR

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: see noteEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) INTERNAL FLOATING ROOF (NSPS) STORAGE TANKS, GOOD OPERATING PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Permit limit is internal floating roof and good operation practices. ALL NOTED TANKS > 40,000 GAL W/ MAX. TRUE VAPOR PRESSURES OF 0.91 PSIA.



## Process/Pollutant Information

PROCESS NAME: STORAGE TANK, 2000 GAL, CORROSION INHIBITOR, T66 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes: 2000 GAL. STORAGE TANK USED FOR GASOLINE ADDITIVE (CORROSION INHIBITOR). FIXED ROOF TANK.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: see note Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) 2000 GAL. FIXED ROOF TANK, PRESSURE/VACUUM CONSERVATION VENT, SUBMERGED FILL PIPE. (NSPS BUT ONLY RECORDKEEPING) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: Permit limit is controls and recordkeeping

## Process/Pollutant Information

PROCESS NAME: DDGS COOLER / TRANSPORT, P70 Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4.6100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO ADD ON VOC CONTROL; DDGS DRYER OPERATION NEEDS TO ASSURE COMPLIANCE WITH LIMIT.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 3.0000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-CaseOther Applicable Requirements:

Control Method: (A) CYCLONE WITH INTEGRATED BAGHOUSE (10:1 A/C); EST. 97% + EFF. COLLECTION. Est. % Efficiency: 97.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWERS, P80 Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 22000.00 GAL/MIN

Process Notes: 0.005% DRIFT MAX.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.1000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 0.005% MAX. DRIFT RATE; 2000 PPM SOLIDS; MAX FLOW OF 22,000 GPM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1000 LB/HEmission Limit 2:

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 0.005% MAX. DRIFT RATE; 124 PPM VOCS; MAX FLOW OF 22,000 GPM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVE VOC, FROM EQUIPMENT, F01 Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: Subject to NSPS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: see note Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) SOCMI LEAK DETECTION AND REPAIR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: permit limit is SOCMI control, no detectable emissions

## Process/Pollutant Information

PROCESS NAME: DDGS LOADOUT, P90 Process Type: 70.120 (Alcohol Fuel Production) Primary Fuel: Throughput: 13470.00 T/MO

Process Notes: DDGS - DISTILLERS DRIED GRAIN W/ SOLUBLES; TONNAGE BASED ON 11% MOISTURE CONTENT.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.4100 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) ENCLOSURE, BAGHOUSE (10:1 A/C); FUGITIVE DUST CONTROL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVE DUST, F02 Process Type: 99.999 (Other Miscellaneous Sources) Primary Fuel: Throughput:

Process Notes: Paved roads and misc. activities

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 30.0000 % REDUCTION see note Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FUGITIVE DUST CONTROL (PAVING, CLEANING, TRANSPORTATION AND STORAGE). CLEAN AND SWEEP ROADS, WATER AND CHEMICAL CONTROLS FOR DUST, PLASTIC COVERINGS, ENCLOSURES, AND TRUCK SPEED AND WEIGHT LIMITS Est. % Efficiency: 30.000 Compliance Verified: Unknown Pollutant/Compliance Notes: permit limit is controls



## Facility Information

RBLC ID: 

## LA-0199 (final) Date Determination Last Updated: 08/07/2007 Corporate/Company Name: SHELL CHEMICAL LP Permit Number: PSD-LA-693

Facility Name: NORCO CHEMICAL PLANT, M-UNIT Permit Date: 03/21/2003 (actual) Facility Contact: RANDY ARMSTRONG 5044657220 FRS Number: 110024471668 Facility Description: UNIT MANUFACTURES MEK & SECONDARY BUTANOL PRODUCTS. PSD ADDRESSES THE M-UNIT DEBOTTLENECK PROJECT, WHICH INCREASED CAPACITY OF PUMPS, INCREASED PHASE SEPARATION CAPACITY, AND REROUTED EXISTING HEAT EXCHANGERS. SIC Code: 2869

Permit Type: C: Modify process at existing facility NAICS Code: 325199 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: ST. CHARLES Facility State: LA Facility ZIP Code: 70079 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOVPermit Notes: APPLICATION ACCEPTED DATE REFLECTS DATE REVISED APPLICATION RECEIVED.

Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 9.6500 (Tons/Year) Nitrogen Oxides (NOx) 0.8100 (Tons/Year) Particulate Matter (PM) 1.7500 (Tons/Year) Sulfur Oxides (SOx) 0.0500 (Tons/Year) Volatile Organic Compounds (VOC) 103.3900 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: DEHYDROGENATION FURNACES (4) Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 7.70 MMBTU/H

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0400 LB/H HOURLY MAXIMUM Emission Limit 2: 0.1800 T/YR ANNUAL MAXIMUM Standard Emission: 0.0050 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES AND ENGINEERING DESIGN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DISTILLATION POLYMER RUNDOWN TANK (T-M942) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020))Primary Fuel:

Throughput:

Process Notes: 32,000 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.4900 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FINISHED SBA RUNDOWN TANKS (T-M943, T-M944) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 144,000 GALLONS EA.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5400 LB/H HOURLY MAXIMUM Emission Limit 2: 2.3700 T/YR ANNUAL MAXIMUM Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CRUDE SBA TANK (T-M955) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 352,000 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2300 LB/H HOURLY MAXIMUM Emission Limit 2: 1.0200 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DISTILLATION POLYMER RUNDOWN TANK (T-M946)PROCESS NAME: DISTILLATION POLYMER RUNDOWN TANK (T-M946)

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 23,700 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1100 LB/H HOURLY MAXIMUM Emission Limit 2: 0.4900 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SBA FEED TANK (T-M955) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 285,000 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3800 LB/H HOURLY MAXIMUMEmission Limit 2: 1.6500 T/YR ANNUAL MAXIMUM

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SBA WATER CUTS TANK (T-S941) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 126,800 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1000 LB/H HOURLY MAXIMUM Emission Limit 2: 0.4400 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: HEXANE STORAGE TANK (T-S954) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 20,000 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1200 LB/H HOURLY MAXIMUM Emission Limit 2: 0.5100 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MEK BARGE TANK (T-B901) Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: 1,680,000 GALLONS

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 0.5300 LB/H HOURLY MAXIMUM Emission Limit 2: 2.3200 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) INTERNAL FLOATING ROOF AND SUBMERGED FILL PIPE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: W.S. GROUND FLARE

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: CONTROLS EMISSIONS FROM SOLVENT TANK TRUCK LOADING, SOLVENT TANK CAR LOADING, AND MEK BARGE LOADING.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 241.7100 LB/H HOURLY MAXIMUM Emission Limit 2: 18.5000 T/YR ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , OPERATING PERMIT Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0193 (final) Date Determination Last Updated: 06/29/2006 Corporate/Company Name: COS-MAR COMPANY Permit Number: PSD-LA-690

Facility Name: STYRENE MONOMER PLANT Permit Date: 02/11/2003 (actual) Facility Contact: MARK STAFFORD 2256424763 MARK.STAFFORD@TOTAL.COM FRS Number: 110000597319 Facility Description: PLANT PRODUCES STYRENE MONOMER THROUGH THE ALKYLATION OF BENZENE AND

ETHYLENE TO ETHYLBENZENE, FOLLOWED BY DEHYDROGENATION OF ETHYLBENZENE TO STYRENE. PROJECT EXPANDS STYRENE MONOMER CAPACITY FROM 1.9 TO 2.55 BILLION POUNDS PER YEAR. SIC Code: 2865

Permit Type: C: Modify process at existing facility NAICS Code: 325110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: IBERVILLE Facility State: LA Facility ZIP Code: 70721 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name)

MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: BRYAN JOHNSTON, 225-219-3181

Permit Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE GQ-1306 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1561.7000 LB/H HOURLY MAXIMUM Emission Limit 2: 64.9000 T/YR *SEE NOTES. ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND MAINTENANCE PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: *ANNUAL CO EMISSIONS FROM FLARES GQ-1306, GQ-2310, & GQ-304 ARE CAPPED AT 64.9 TPY.



## Process/Pollutant Information

PROCESS NAME: FLARE GQ-2310 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 895.6000 LB/H HOURLY MAXIMUM Emission Limit 2: 64.9000 T/YR *SEE NOTES. ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMITControl Method: (P) PROPER DESIGN AND MAINTENANCE PRACTICES

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: *ANNUAL CO EMISSIONS FROM FLARES GQ-1306, GQ-2310, & GQ-304 ARE CAPPED AT 64.9 TPY.



## Process/Pollutant Information

PROCESS NAME: FLARE GQ-304 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1475.3000 LB/H HOURLY MAXIMUM Emission Limit 2: 64.9000 T/YR *SEE NOTES. ANNUAL MAXIMUM Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) PROPER DESIGN AND MAINTENANCE PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: *ANNUAL CO EMISSIONS FROM FLARES GQ-1306, GQ-2310, & GQ-304 ARE CAPPED AT 64.9 TPY.



## Process/Pollutant Information

PROCESS NAME: PROCESS SUPERHEATER HF-1201/1219 Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: PROCESS GASThroughput: 298.90 MMBTU/H

Process Notes: 194.9 MMBTU/HR PROCESS GAS 104.3 MMBTU/HR NATURAL GAS

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.2000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS AND PROCESS GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 24.6000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A,Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Process/Pollutant Information

PROCESS NAME: REGENERATION GAS HEATER HS-2102 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Throughput: 14.40 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.2000 LB/H HOURLY MAXIMUM Emission Limit 2:Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE

Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Process/Pollutant Information

PROCESS NAME: BZ RECOVERY COLUMN HEATER HS-2103 Process Type: 12.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Throughput: 182.10 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.4000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY:Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 15.0000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Process/Pollutant Information

PROCESS NAME: EB RECOVERY COLUMN HEATER HS-2104 Process Type: 11.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: Throughput: 269.30 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 22.2000 LB/H HOURLY MAXIMUMEmission Limit 2:

Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.0000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Process/Pollutant Information

PROCESS NAME: PEB RECOVERY COLUMN HEATER HS-2105 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel:Throughput: 25.20 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.1000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1900 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY:Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Process/Pollutant Information

PROCESS NAME: PROCESS SUPERHEATER HS-8201/8219 Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: PROCESS GAS Throughput: 280.00 MMBTU/H

Process Notes: 166.0 MMBTU/HR PROCESS GAS 114.0 MMBTU/HR NATURAL GAS

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.1000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS AND PROCESS GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 23.1000 LB/H HOURLY MAXIMUM Emission Limit 2:Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE

Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Process/Pollutant Information

PROCESS NAME: REHEATER HS-8220 Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: NATURAL GAS Throughput: 195.00 MMBTU/H

Process Notes: 84.6 MMBTU/HR PROCESS GAS 110.4 MMBTU/HR NATURAL GAS

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0100 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) USE OF CLEAN BURNING FUELS (NATURAL GAS AND PROCESS GAS) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY:Pollutant/Compliance Notes: ANNUAL PM10 EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 108.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 16.1000 LB/H HOURLY MAXIMUM Emission Limit 2: Standard Emission: 0.0800 LB/MMBTU ANNUAL AVERAGE Did factors, other then air pollution technology considerations influence the BACT decisions: N Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (P) GOOD COMBUSTION PRACTICES - GOOD EQUIPMENT DESIGN, USE OF GASEOUS FUELS FOR GOOD MIXING, AND PROPER COMBUSTION TECHNIQUES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ANNUAL CO EMISSIONS FROM THE FOLLOWING SOURCES ARE CAPPED AT 953.3 TPY: 145-02-A, 145-02-B, 145-02-C, 145-02-D, 145-02-E, 145-02-F, 145-02-G, 145-02-H, 145-02-I, 145-02-J, 145-02-K, 145-02-L, 145-02-M, 145-02-N, 145-02-O, & 145-02-P.



## Facility Information

RBLC ID: 

## VA-0294 (final) Date Determination Last Updated: 08/28/2006 Corporate/Company Name: WM ATLANTIC WASTE DISPOSAL INC. Permit Number: 51278

Facility Name: ATLANTIC WASTE DISPOSAL LANDFILL Permit Date: 02/05/2003 (actual) Facility Contact: D RICHARD GUIDRY 8043633313 FRS Number: 110020667580 Facility Description: MUNICIPAL SOLID WASTE LANDFILL. EQUIPMENT TO BE CONSTRUCTED (SUBJECT TO NSPS

WWW AND NESHAP AAAA) AT THIS FACILITY CONSISTS OF: MUNICIPAL SOLID WASTE LANDFILL CELLS 5A,5B,6B,7A-C,8A,8B,9A,9B,10A-C,11A-C,12A-C WITH A TOTAL CAPACITY OF 92,106,543 YD3 (ASSUMED MAXIMUM COMPACTION OF 1900 LBS/YD3) OF COMBINED WASTE. THREE LFG&E TRITION UTILITY FLARES MODEL CF-3500 OR EQUIVALENT (CF-4,CF-5,AND CF-6) SIC Code: 4953EACH WITH A FLOW RATING OF 3500 SCFM, INCLUDING BLOWERS AND OTHER EQUIPMENT TO COLLECT LANDFILL GAS TO ROUTE TO THE FLARES OR TREATMENT PROCESS. Permit Type: C: Modify process at existing facility NAICS Code: 562212 Permit URL: EPA Region: 3 COUNTRY: USA Facility County: SUSSEX Facility State: VA Facility ZIP Code: 23890 Permit Issued By: VIRGINIA DEPT. OF ENVIRONMENTAL QUALITY; DIVISION OF AIR QUALITY (Agency Name)

MR. YOGESH DOSHI(Agency Contact) (804)698-4017 Yogesh.doshi@deq.virginia.gov Other Agency Contact Info: THE PERMIT WRITER FOR THIS FACILITY IS ALISON SINCLAIR. SHE MAY BE REACHED AT (804)527-5155 OR E-MAILED AT

AMSINCLAIR@DEQ.VIRGINIA.GOV Permit Notes:



## Process/Pollutant Information

PROCESS NAME: FLARES, 3500 SCFM LFG (3) Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: LANDFILL GAS Throughput: 630000.00 scf/h

Process Notes: 3 3500 SCFM LFG FLARES

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.2000 LB/H Emission Limit 2: Standard Emission: 0.0220 LB/MMBTU CALCULATED SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000Est. % Efficiency: 98.000

Compliance Verified: Unknown Pollutant/Compliance Notes: THE EMISSION RATE IS FOR ONE OF THREE FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.9000 LB/H Emission Limit 2: Standard Emission: 0.0190 LB/MMBTU CALCULATED, SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NESHAP , MACT , NSPS Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: THE EMISSON RATE IS FOR ONE OF THREE FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 5.1000 LB/H Emission Limit 2: Standard Emission: 0.0510 LB/MMBTU CALCULATED SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF AControl Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR ONE OF 3 FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 17.3000 LB/H Emission Limit 2: Standard Emission: 0.0170 LB/MMBTU CALCULATED SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING %METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR 1 OF 3 FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6000 LB/H Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF AControl Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.4000 LB/H NONMETHANE ORGANIC CARBON Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR NONMETHANE ORGANIC CARBON. EMISSIONS ARE FOR 1 OF 3 FLARES.



## Process/Pollutant Information

PROCESS NAME: FLARES, 2500 SCFM LGF (2) Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: Throughput: 300000.00 scf/h

Process Notes: EMISSIONS ARE FOR 1 OF 2 FLARES

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: 98.0000 % REDUCTION

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR 1 OF 2 FLARES

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 12.3000 LB/H Emission Limit 2: Standard Emission: 0.1700 LB/MMBTU CALCULATED SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: MACT , NSPS , NESHAP Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR 1 OF 2 FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.0000 LB/H NONMETHANE ORGANIC CARBON Emission Limit 2:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR NONMETHANE ORGANIC CARBON. EMISSIONS ARE FOR 1 OF 2 FLARES

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.6000 LB/H Emission Limit 2: Standard Emission: 0.0500 LB/MMBTU CALCULATED, SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING %METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR 1 OF 2 FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.6000 LB/H Emission Limit 2: Standard Emission: 0.0200 LB/MMBTU CALCULATED NOT PERMIT LIMIT Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: NESHAP , MACT , NSPS Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR 1 OF 2 FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.4000 LB/H Emission Limit 2: Standard Emission: 0.0200 LB/MMBTU CALCULATED SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING %METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSIONS ARE FOR 1 OF 2 FLARES. STANDARD EMISSION LIMIT IS CALCULATED USING AN ASSUMPTION OF 475 BTU/SCF LGF. PERMIT DOES NOT INCLUDE A LIMIT IN LB/MMBTU UNITS.



## Process/Pollutant Information

PROCESS NAME: FLARES, COMBINED Process Type: 19.320 (Digester and Landfill Gas Flares) Primary Fuel: Throughput: 930000.00 scf/h

Process Notes: TOTAL EMISSIONS FOR ALL 5 FLARES: TWO 2500 SCFM AND THREE 3500 SCFM

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 41.6000 T/YR Emission Limit 2: Standard Emission: SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: TOTAL EMISSIONS FOR 5 FLARES. STANDARD EMISSIONS IN 2500 SCFM AND 3500 SCFM FLARE ENTRIES.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 36.3000 T/YR Emission Limit 2: Standard Emission: SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: TOTAL EMISSIONS FOR 5 FLARES. STANDARD EMISSIONS IN 2500 SCFM AND 3500 SCFM FLARE ENTRIES.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 97.8000 T/YR Emission Limit 2: Standard Emission: SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: TOTAL EMISSIONS FOR 5 FLARES. STANDARD EMISSIONS IN 2500 SCFM AND 3500 SCFM FLARE ENTRIES.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 334.0000 T/YR Emission Limit 2: Standard Emission: SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING %METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: TOTAL EMISSIONS FOR 5 FLARES. STANDARD EMISSIONS IN 2500 SCFM AND 3500 SCFM FLARE ENTRIES.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: UnspecifiedPollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 26.5000 T/YR NONMETHANE ORGANIC CARBON Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (P) PROPER MAINTENANCE OF THE FLARE, INCLUDING MONITORING FOR THE PRESENCE OF A FLAME, LGF FLOW RATE, 0% OPACITY, MEASURING % METHANE IN LFG Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: LIMIT IS FOR NONMETHANE ORGANIC CARBON. TOTAL EMISSIONS FOR 5 FLARES

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.2000 T/YR Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , NESHAP , MACT Control Method: (N) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: TOTAL EMISSIONS FOR 5 FLARES



## Facility Information

RBLC ID: 

## TX-0364 (final) Date Determination Last Updated: 01/04/2005 Corporate/Company Name: EXXON MOBIL CORPORATION Permit Number: PSD-TX-795M2Facility Name: SALT CREEK GAS PLANT Permit Date: 01/31/2003 (actual) Facility Contact: LAURA JOHNSON 7134311213 FRS Number: 110017419220 Facility Description: EXXON MOBILE REQUESTED AN AMENDMENT TO PERMIT 20660 AND A PSD MAJOR

MODIFICATION TO PSD-TX-795M1 TO UPDATE THE FLARE EMISSIONS TO REFLECT REVISED GAS VOLUMES AND INCREASES IN ACID GAS CONTENT. THE AMENDMENT UPDATES THE PROCESS FLARE EMISSIONS BUT DOES NOT AUTHORIZE EMERGENCY OR MAINTENANCE EMISSIONS WHEN THE FLARES ARE USED AS EMERGENCY FLARES. IN ADDITION, REVISED CALCULATIONS FOR SOME OF THE PREVIOUSLY PERMITTED COMPRESSOR ENGINES BASED UPON UPDATED EMISSION FACTORS FROM THE MANUFACTURERS WERE PROVIDED. THERE ARE NO PHYSICAL OR OPERATIONAL MODIFICATIONS TO THE COMPRESSOR ENGINES. SIC Code: 1321

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 211112 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: KENT Facility State: TX Facility ZIP Code: 772104358 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: JAMES LINVILLE

PO BOX 13087 AUSTIN, TX 78711-3087 512-239-1261 Permit Notes: NAT GAS PRODUCTION FACILITY



## Process/Pollutant Information

PROCESS NAME: COOPER-BESSEMER ENGINE, #GMVH-12, EPN1 Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NAT GAS Throughput: 2400.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 44.4000 LB/H Emission Limit 2: 162.0600 T/YR Standard Emission: 0.1900 G/B-HP-H CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARD EMISSIONS FOR NOX WERE CALCULATED BY DIVIDING THE HOURLY EMISSION LIMIT BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.3500 LB/H Emission Limit 2: 23.1700 T/YR Standard Emission: 1.2000 G/B-HP-H CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARD EMISSIONS FOR CO WERE CALCULATED BY DIVIDING THE HOURLY EMISSION RATE BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2:Standard Emission: 5.0000 % OPACITY 6 MIN AV

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.3500 LB/H Emission Limit 2: 23.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3600 LB/H Emission Limit 2: 1.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements:Control Method: (P) USE PIPELINE QUALITY SWEET NATURAL GAS

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6200 LB/H Emission Limit 2: 2.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) CLARK ENGINE, #TLAB-6, EPN2&3 Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NAT GAS Throughput: 2000.00 HP EACH

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5300 LB/H EACH Emission Limit 2: 1.9300 T/YR EACHStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 84.5800 LB/H EACH Emission Limit 2: 308.7200 T/YR EACH Standard Emission: 19.2000 G/B-HP-H CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N) NONE INDICATED

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX STANDARD EMISSION LIMIT CALCULATED BY DIVIDING THE HOURLY EMISSION LIMIT BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.9900 LB/H EACH Emission Limit 2: 32.8000 T/YR EACH Standard Emission: 2.0400 G/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO STANDARD EMISSION LIMIT CALCULATED BY DIVIDING THE HOURLY EMISSION LIMIT BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.3200 LB/H EACH Emission Limit 2: 4.8000 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3100 LB/H EACH Emission Limit 2: 1.1200 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) INGERSOLL-RAND ENGINES, #IR-SVG-8, EPN4&5 Process Type: 17.230 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NAT GAS Throughput: 440.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 18.4100 LB/H EACH Emission Limit 2: 80.6400 T/YR EACH Standard Emission: 19.0000 G/B-HP-H CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX STANDARD EMISSION LIMITS CALCULATED BY DIVIDING THE HOURLY EMISSION RATE BY THE THROUGHPUT AND CONVERTING LBS INTO GRAMS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.6800 LB/H EACH Emission Limit 2: 2.9800 T/YR EACH Standard Emission: 0.7000 G/B-HP-H CALCULATED, SEE POLLUTANT NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO STANDARD EMISSION LIMITS CALCULATED BY DIVIDING THE HOURLY EMISSION LIMIT BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4800 LB/H EACH Emission Limit 2: 2.1000 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATEDEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.7000 LB/H EACH Emission Limit 2: 3.1000 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H LESS THAN Emission Limit 2: 0.0100 T/YR LESS THAN Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HOT OIL HEATER, EPN6 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NAT GAS Throughput: 12.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.4100 LB/H Emission Limit 2: 5.1500 T/YR Standard Emission: 0.1180 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATEDEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.1900 LB/H Emission Limit 2: 4.3300 T/YR Standard Emission: 0.0992 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.2800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: 0.0008 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4000 T/YR Standard Emission: 0.0092 LB/MMBTU CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

## Process/Pollutant Information

PROCESS NAME: (2) INGERSOLL-RAND ENGINES, #IR-SVG-8, EPN10A&B Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NAT GAS Throughput: 1330.00 HP

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.7600 LB/H EACH Emission Limit 2: 7.6400 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3300 LB/H EACH Emission Limit 2: 1.2000 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATEDEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.4900 LB/H EACH Emission Limit 2: 12.7300 T/YR EACH Standard Emission: 1.1900 G/B-HP-H CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: CO STANDARD EMISSION LIMITS WERE CALCULATED BY DIVIDING THE HOURLY EMISSION LIMIT BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS. SEE PREVIOUS PERMITS FOR BASIS OF DETERMINATION.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 59.3100 LB/H EACH Emission Limit 2: 216.4900 T/YR EACH Standard Emission: 20.2000 G/B-HP-H CALCULATED, SEE NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NOX STANDARD EMISSION LIMITS CALCULATED BY DIVIDING THE HOURLY EMISSION LIMITPollutant/Compliance Notes: NOX STANDARD EMISSION LIMITS CALCULATED BY DIVIDING THE HOURLY EMISSION LIMIT BY THE THROUGHPUT AND CONVERTING LBS TO GRAMS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H EACH Emission Limit 2: 0.4300 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: GLYCOL REBOILER, EPN11 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NAT GAS Throughput: 2.50 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 1.0700 T/YR Standard Emission: 0.1160 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2500 LB/H Emission Limit 2: 0.9000 T/YR Standard Emission: 0.1000 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements:Control Method: (N) NONE INDICATED

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: 0.0080 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSIONPollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: 0.0080 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.



## Process/Pollutant Information

PROCESS NAME: GLYCOL STILL VENT, EPN14 Process Type: 50.005 (Petroleum Refining Separation Processes (distillation and light ends recovery)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3400 LB/H Emission Limit 2: 1.4700 T/YR Standard Emission:Standard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.4200 LB/H Emission Limit 2: 41.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (3) COOPER-BESSEMER ENGINES, #GMVH-12C2, EPN21-23 Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NAT GAS Throughput: 3105.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 21.8900 LB/H EACH Emission Limit 2: 2.0000 G/B-HP-H ANNUALY, EACH Standard Emission: 3.2000 G/B-HP-H HOURLY, EACH Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS: 59.91 T/YR, EACH

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 32.8300 LB/H EACH Emission Limit 2: 3.0000 G/B-HP-H ANNUALY, EACH Standard Emission: 4.8000 G/B-HP-H HOURLY, EACH Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS: 89.87 T/YR, EACH

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.9400 LB/H EACH Emission Limit 2: 29.9600 T/YR EACHStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS: 1.6 G/B-HP-H HOURLY OR 1.0 G/B-HP-H ANNUALY, EACH.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2600 LB/H EACH Emission Limit 2: 1.1400 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0900 LB/H EACH Emission Limit 2: 4.7900 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements:Control Method: (N) NONE INDICATED

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV, EACH Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV, EACH Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HOT OIL HEATER, EPN26 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NAT GAS Throughput: 32.50 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.9500 LB/H Emission Limit 2: 8.5400 T/YRStandard Emission: 0.0600 LB/MMBTU CALCULATED, SEE NOTES

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMIT IN STANDARDIZED UNITS WAS CALCULATED BY DIVIDING THE HOURLY LIMIT BY THE THROUGHPUT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.2100 LB/H Emission Limit 2: 11.7300 T/YR Standard Emission: 0.0990 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2100 LB/H Emission Limit 2: 0.7700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-CaseCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: 0.0006 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 1.0600 T/YR Standard Emission: 0.0090 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency:Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.



## Process/Pollutant Information

PROCESS NAME: (2) FLARES, EPN 9 & 29

Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: THIS AMENDMENT IS TO ACCURATELY REPRESENT THAT EITHER FLARE CAN BE USED AS A PROCESS FLARE AND TO USE 2001

ACTUAL GAS FLOWS TO PREDICT THE VOLUME OF GAS PROCESSED. CURRENT GAS ANALYSES WERE PROVIDED TO ACCURATELY REPRESENT THE CO2, H2S, AND VOC CONTENT OF THE GAS STREAMS.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 4.3700 LB/H EACH Emission Limit 2: 15.8500 T/YR COMBINED Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 37.2000 LB/H EACH

Emission Limit 2: 135.8000 T/YR COMBINED Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 42.8200 LB/H EACH Emission Limit 2: 156.3100 T/YR COMBINED Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) THE FLARE IS A VOC CONTROL Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 50.4800 LB/H EACH Emission Limit 2: 184.2400 T/YR COMBINED Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5500 LB/H EACH Emission Limit 2: 2.0000 T/YR COMBINED Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) THE FLARE IS AN H2S CONTROL Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HP TEG FIREBOX, EPN30 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NAT GAS Throughput: 3.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 0.0100 LB/H

Emission Limit 2: 0.0100 T/YR Standard Emission: 0.0030 LB/MMBTU CALCULATED, SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: 0.0060 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 1.2900 T/YR Standard Emission: 0.0967 LB/MMBTU SEE NOTEDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2500 LB/H Emission Limit 2: 1.0800 T/YR Standard Emission: 0.0833 LB/MMBTU SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT CALCULATED FROM HEAT RATING AND HOURLY EMISSION LIMIT.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-CaseOther Applicable Requirements:

Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES, NGLFUG Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.0800 LB/H Emission Limit 2: 39.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ASSUMED NSPS SUBPART KKK IS THE BASIS OF THIS DETERMINATION.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/HEmission Limit 2: 0.2000 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES, CO2FUG Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.3300 LB/H Emission Limit 2: 41.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ASSUMED NSPS SUBPART KKK IS THE BASIS OF THIS DETERMINATION.

POLLUTANT NAME: Hydrogen SulfideCAS Number: 7783-06-4

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.2700 LB/H Emission Limit 2: 5.6700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0465 (final) Date Determination Last Updated: 07/05/2007 Corporate/Company Name: EXXON MOBIL CORPORATION Permit Number: P795M2

Facility Name: SALT CREEK GAS PLANT Permit Date: 01/31/2003 (actual) Facility Contact: MR. NEIL J RYAN, JR. 7134311219 FRS Number: 110000721452 Facility Description: OVER TIME THE H2S AND CO2 CONTENT OF THE GAS PROCESSED AT THE SALT CREEK GAS

PLANT HAS INCREASED AND THE VOLUME OF GAS PROCESSED HAS CHANGED. THIS AMENDMENT WILL UPDATE THE TWO FLARES (EPNS 9 & 29) TO REFLECT THAT EITHER CAN BE A PROCESS FLARE , REVISE THE EMISSIONS TO REFLECT THE INCREASED CO2 AND H2S IN THE INLET GAS, AND UPDATE THE VOLUME TO REFLECT ACTUAL GAS VOLUMES FROM 2001. THE EMISSION CALCULATIONS FOR THE OLDER ENGINES THAT WERE ORIGINALLY IN PERMIT 5037A/PSD-TX-702M2 HAVE BEEN UPDATED BASED UPON REVISED VENDOR DATA RATHER THAN AP-42. HEATER EMISSIONS HAVE BEEN UPDATED TO REFLECT THE LATEST AP-42 FACTORS AND A PREVIOUSLY EXEMPTED HEATER WAS INCLUDED SINCE IT REPRESENTS BACT FOR THIS SIZE HEATER. SIC Code: 1321

Permit Type: U: Unspecified NAICS Code: 221210 Permit URL: EPA Region: 6 COUNTRY: USAFacility County: KENT

Facility State: TX Facility ZIP Code: Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: EXXONMOBIL REQUESTED AN AMENDMENT TO PERMIT 20660 TO UPDATE THE FLARE EMISSIONS CALCULATIONS TO

REFLECT NEW PROCESS FLARE VOLUMES AND CHANGES TO THE GAS COMPOSITION BASED UPON THE REINJECTION OF A PORTION OF THE SOUR GAS FROM THE AMINE UNIT AUTHORIZED IN 1993. THEY ALSO ORIGINALLY REQUESTED UPDATED EMISSION LIMITS CALCULATED WITH REVISED AP-42 FACTORS FOR THE COMPRESSOR ENGINES.



## Process/Pollutant Information

PROCESS NAME: COOPER-BESSEMER ENGINE Process Type: 17.190 (Other/Unknown Fuel) Primary Fuel: Throughput: 2400.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 44.4000 LB/H Emission Limit 2: 162.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0CAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.3500 LB/H Emission Limit 2: 23.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.3500 LB/H Emission Limit 2: 23.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3600 LB/HEmission Limit 2: 1.3100 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6200 LB/H Emission Limit 2: 2.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CLARK ENGINE (2) Process Type: 17.190 (Other/Unknown Fuel) Primary Fuel: Throughput: 2000.00 HP

Process Notes: EMISSIONS ARE PER ENGINE

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 84.5800 LB/H Emission Limit 2: 308.7200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.9900 LB/H Emission Limit 2: 32.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.3200 LB/HEmission Limit 2: 4.8000 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3100 LB/H Emission Limit 2: 1.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5300 LB/H Emission Limit 2: 1.9300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: INGERSOLL-RAND ENGINE Process Type: 17.290 (Other/Unknown Fuel) Primary Fuel: Throughput: 440.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 18.4100 LB/H Emission Limit 2: 80.6400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.6800 LB/HEmission Limit 2: 2.9800 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4800 LB/H Emission Limit 2: 2.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.7000 LB/H Emission Limit 2: 3.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HOT OIL HEATER Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput: 12.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0800 LB/HEmission Limit 2: 0.2800 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.4100 LB/H Emission Limit 2: 5.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.1900 LB/H Emission Limit 2: 4.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: INGERSOLL-RAND ENGINE 1330 HP Process Type: 17.190 (Other/Unknown Fuel) Primary Fuel: Throughput: 1330.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 59.3100 LB/H Emission Limit 2: 216.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.6800 LB/H Emission Limit 2: 2.9800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.7600 LB/H Emission Limit 2: 7.6400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.3300 LB/H Emission Limit 2: 1.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1200 LB/H Emission Limit 2: 0.4300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GLYCOL REBOILER Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput: 2.50 MMBUT/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 1.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2500 LB/H Emission Limit 2: 0.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: GLYCOL VENT

Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3400 LB/H Emission Limit 2: 1.4700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.4200 LB/H Emission Limit 2: 41.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOPER-BESSEMER ENGINE 3105 HP Process Type: 17.190 (Other/Unknown Fuel) Primary Fuel: Throughput: 3105.00 HP

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 21.8900 LB/H Emission Limit 2: 59.9100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 32.8300 LB/H Emission Limit 2: 89.8700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.2600 LB/H Emission Limit 2: 1.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 10.9400 LB/H Emission Limit 2: 29.9600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0900 LB/H Emission Limit 2: 4.7900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAN COMBUSTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HOT OIL HEATER Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput: 32.50 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.9500 LB/H Emission Limit 2: 8.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 1.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.2100 LB/H Emission Limit 2: 11.7300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2100 LB/H Emission Limit 2: 0.7700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: FLARES (2)

Process Type: 19.310 (Chemical Plant Flares)

Primary Fuel: Throughput:

Process Notes: INLET GAS COMPOSITION AND VOLUMES HAVE CHANGED OVER THE YEARS SINCE REINJECTION OF CO2 WAS STARTED. IN 1998

THE SO2 EMISSION WERE REDUCED FROM 1020 T/YR TO APPROXIMATELY 174 T/YR IN PERMIT 5037A DUE TO THE REINJECTION OF THE CO2 BUT THE OTHER EMISSIONS HAVE NEVER BEEN REPRESENTED PROPERLY. THIS AMENDMENT IS TO ACCURATELY REPRESENT THAT EITHER FLARE CAN BE USED AS A PROCESS FLARE AND TO USE 2001 ACTUAL GAS FLOWS TO PREDICT THE VOLUME OF GAS PROCESSED. CURRENT GAS ANALYSES WERE PROVIDED TO ACCURATELY REPRESENT THE CO2, H2S AND VOC CONTENT OF THE GAS STREAMS. CALCULATED INCREASE IN NOX, CO AND VOC ARE GREATER THAN THE PSD SIGNIFICANCE LEVEL AND RECALCULATED INCREASES IN H2S AND SO2 ARE LESS THAN SIGNIFICANCE.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 50.4800 LB/H Emission Limit 2: 184.2400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 0.5500 LB/H

Emission Limit 2: 2.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 4.3700 LB/H Emission Limit 2: 15.8500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 37.2000 LB/H Emission Limit 2: 135.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 42.8200 LB/H Emission Limit 2: 156.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HP TEG FIREBOX Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 0.2900 LB/H

Emission Limit 2: 1.2900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2500 LB/H Emission Limit 2: 1.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES (4) Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.0800 LB/H Emission Limit 2: 39.7600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 9.3300 LB/H Emission Limit 2: 41.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 1.2700 LB/H

Emission Limit 2: 5.6700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0434 (final) Date Determination Last Updated: 12/30/2004 Corporate/Company Name: DEGUSSA ENGINEERED CARBONS LP Permit Number: PSD-TX-1010 Facility Name: BAYTOWN CARBON BLACK PLANT Permit Date: 12/31/2002 (actual) Facility Contact: DON BIRTELL 8062731432 FRS Number: 110000463132 Facility Description: FACILITY IS LOCATED AT 9300 NEEDLEPOINT ROAD. EXISTING CARBON BLACK PLANT SIC Code: 2895

Permit Type: C: Modify process at existing facility NAICS Code: 325182 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: HARRIS Facility State: TX Facility ZIP Code: 79008 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: PERMIT MODIFICATION TO CORRECT NOX EMISSIONS AND CONDUCT A RETROACTIVE PSD REVIEW OF PLANT PROJECTS SINCE 1982. ADDITIONAL PERMIT NO.: 9294, REGULATED ENTITY ID: RN100209899 Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 9.9000 (Tons/Year) Nitrogen Oxides (NOx) 712.9700 (Tons/Year) Particulate Matter (PM) 18.6800 (Tons/Year) Volatile Organic Compounds (VOC) 0.5300 (Tons/Year)

## Process/Pollutant Information

PROCESS NAME: DRYERS, BOILERS, FLARE Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: TAIL GAS Throughput:

Process Notes: MULTIPLE SMALL SOURCES: WASTE HEAT BOILER, DRYERS, FLARE.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/MMBTU Emission Limit 2: Standard Emission: 0.1000 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES AND DESIGN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BAGHOUSES Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)CAS Number: PM

Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 GR/DSCF Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0354 (final) Date Determination Last Updated: 01/05/2005 Corporate/Company Name: ATOFINA CHEMICALS INCORPORATED Permit Number: PSD-TX-1016

Facility Name: ATOFINA CHEMICALS INCORPORATED Permit Date: 12/19/2002 (actual) Facility Contact: MR. GERRY MATA 4098383981299 GERARDO.MATA@ATOFINA.COM FRS Number: 110000464168 Facility Description: ACROLEIN (AC) IS PRODUCED BY THE SELECTIVE OXIDATION OF PROPYLENE ACROSS A FIXED

BED CATALYST REACTOR IN A CONTINUOUS PROCESS. PROPYLENE IS DELIVERED TO THE SITE VIA PIPELINE REQUIRING NO ON SITE STORAGE. THIS REACTION IS EXOTHERMIC AND HEAT IS RECOVERED AS STEAM. AC IS RECOVERED AND PURIFIED THROUGH A SERIES OF ABSORBERS AND DISTILLATION COLUMNS. AN INHIBITOR IS INJECTED THROUGHOUT AC PRODUCTION TO PREVENT POLYMERIZATION. AC WASTE GAS IS SENT TO THE NEW THERMAL OXIDIZER (EPN SULFOX-TO). AC IS TRANSFERRED TO AC STORAGE TANKS PRIOR TO USE AS MMP FEED. TWO AC TANKS PROVIDE SURGE CAPACITY AND TANK STORAGE TEMPERATURE IS LIMITED TO 68F. AC TANKS WILL NORMALLY VENT BACK TO THE PROCESS FOR AC RECOVERY AND AC IS TRANSFERRED BY CLOSED PIPE. AC TANK VENTS ARE SENT TO THE SULFOX THERMAL OXIDIZER AND EMERGENCY VENTS ARE SENT TO THE FLARE. NO AC LEAVES THE SITE AND IT IS ALL CONSUMED IN THE MMP UNIT. WASTEWATER (WW) STREAMS ARE GENERATED IN THE ADSORPTION STEPS WHERE THE WW IS STORED AND NEUTRALIZED BEFORE IT IS SENT TO OFFSITE TREATMENT. THE OTHER WW IS NON HAZARDOUS AND IT IS ATOMIZED BEFORE SIC Code: 2869BURNED IN EPN SULFOX-TO.

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 325199 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: JEFFERSON Facility State: TX Facility ZIP Code: 77704 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: STEPHEN A. ANDERSON

TNRCC, PO BOX 13087 AUSTIN, TX 78711 512-239-1287 Permit Notes: ATOFINA FILED A PERMIT AMENDMENT TO BUILD A NEW PRODUCTION UNIT CALLED THE SULFOX UNIT WITH A NEW

THERMAL OXIDIZER (EPN SULFOX-TO), INSTALL A UNIT TO PRODUCE ACROLEIN AS A FEEDSTOCK FOR THE SULFOX UNIT, DELETE REPRESENTATIONS OF A DECEMBER 1999 PERMIT AMENDMENT FOR THE BEAUMONT III UNIT (SINCE IT WILL NOT BE BUILT), AND INCLUDE MAINTENANCE SHUTDOWN AND START UP (SSM) EMISSIONS FROM THE FLARE (EPN FLARE) AND NEW SULFOX THERMAL OXIDIZER (EPN SULFOX-TO). THE NEW ACROLEIN EQUIPMENT IS SUBJECT TO A DISASTER REVIEW. THE NEW PRODUCT FROM THE SULFOX UNIT IS CALLED METHYLMERCAPTOPPROPIONALDEHYDE (MMP) WHICH IS SOLID AT ROOM TEMPERATURE. THE CO, NOX, AND SO2 EMISSION INCREASES FOR THE PROJECT ARE GREATER THAN THE MAJOR MODIFICATION LIMITS OF 100 T/YR AND 40 T/YR AT A NAMED MAJOR STATIONARY SOURCE. PSD REVIEW IS REQUIRED. THE OTHER CRITERIA POLLUTANT INCREASES ARE LESS THAN THEIR PSD MAJOR MODIFICATION SIGNIFICANCE LEVELS AND PSD REVIEW DOES NOT APPLY. TARA EXPRESSED CONCERN WITH THE POTENTIAL ACTUAL INCREASE IN METHYL MERCAPTAN EMISSIONS ASSOCIATED WITH THIS PROJECT DUE TO NOTING ODORS DURING A RECENT MONITORING TRIP IN THE AREA. METHYL MERCAPTAN EMISSIONS ARE PRIMARILY FUGITIVE AND ARE MINIMIZED THORUGH AN AVO MONITORING PROGRAM. IN ADDITION, ALLOWABLE MERCAPTAN EMISSIONS WILL BE LOWER THAN WERE AUTHORIZED IN A JULY 1999 PERMIT AMENDMENT THAT WILL NOW NOT BE CONSTRUCTED.



## Process/Pollutant Information

PROCESS NAME: ACROLEIN UNIT COLUMN/ FILTER CLEANING Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput:

Process Notes: EPN: COLUMNMAIN.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIESEL TANK, D-215 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHANOL TANK, D-307

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: ADDITIONAL SCC CODE: 40715802. LIMITED TO AN ANNUAL METHANOL THROUGHPUT SPECIFIED IN THE CONFIDENTIAL

SECTION OF THE APPLICATION SUBMITTED ON 12/21/1998. THE SITE WILL MAINTAIN MONTHLY RECORDS OF ANNUAL THROUGHPUT OF THE TANK. THE THROUGHPUT OF THE TANK SHALL BE TABULATED ON A 12-MO ROLLING BASIS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHANOL TANK, D-310

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020))Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020))

Primary Fuel: Throughput:

Process Notes: ADDITIONAL SCC CODE: 40715802. THE TANK SHALL BE LIMITED TO AN ANNUAL METHANOL THROUGHPUT SPECIFIED IN THE

CONFIDENTIAL SECTION OF THE APPLICATION SUBMITTED ON 12/21/1998. THE SITE WILL MAINTAIN MONTHLY RECORDS OF ANNUAL THROUGHPUT OF THE TANK. THE THROUGHPUT WILL BE TABULATED ON A 12-MO ROLLING BASIS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.3600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GASOLINE TANK, D-398 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Pollutant Group(s): ( Volatile Organic Compounds (VOC) )

Emission Limit 1: 4.5600 LB/H Emission Limit 2: 0.2200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIESEL TANK, D-399 Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: METHANOL TANK, D-2307

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: ADDITIONAL SCC CODE: 40715802. THE STORAGE TANK SHALL BE LIMITED TO AN ANNUAL METHANOL THROUGHPUT

SPECIFIED IN THE CONFIDENTIAL SECTION OF THE APPLICATION SUBMITTED ON 12/21/1998. THE SITE WILL MAINTAIN MONTHLY RECORDS OF ANNUAL THROUGHPUT OF EACH TANK. THE THROUGHPUT OF EACH TANK SHALL BE TABULATED ON A 12-MO ROLLING BASIS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) DIESEL TANKS, 3191A - 3191B Process Type: 42.009 (Volatile Organic Liquid Storage)Primary Fuel:

Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H EACH Emission Limit 2: 0.0100 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFICATIONS FOR ROOF, SEAL, VENTS, AND MAINTENANCE AS DIRECTED BY NSPS ACCORDING TO YEAR OF CONSTRUCTION, CAPACITY, AND PRESSURE OF CONTENTS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CAUSTIC TANK, D8540 Process Type: 62.020 (Inorganic Liquid/Gas Storage & Handling) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sodium Hydroxide

CAS Number: 1310-73-2 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFURIC ACID TANK, D8600 Process Type: 62.020 (Inorganic Liquid/Gas Storage & Handling) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS

NAME: FLARE, STEADY STATE OPERATION

Process Type: 19.310 (Chemical Plant Flares)

Primary Fuel: Throughput:

Process Notes: 416 H/YR OPERATION AS THE BACKUP CONTROL DEVICE WHEN EPN SULFOX-TO IS NOT OPERATING. WASTE GAS STREAMS

FROM THE SULFOX UNIT VENTS CANNOT GO TO EPN FLARE AND EPN SULFOX-TO AT THE SAME TIME. THE FLARE SHALL BE DESIGNED AND OPERATED WHERE THE COMBINED NATURAL GAS AND WASTE STREAM TO THE FLARE TIP SHALL MEET THE 40 CFR 60.18 SPECIFICATIONS FOR MINIMUM NET HEATING VALUE AND MAXIMUM TIP VELOCITY UNDER NORMAL AND SSM CONDITIONS. A FLAME IS PRESENT AT ALL TIMES AND HAS A CONSTANT PILOT FLAME. THE PILOT FLAME SHALL BE MONITORED BY A THERMOCOUPLE, AN ULTRAVIOLET MONITOR, AND INFRARED MONITOR, OR OTHER EQUIVALENT DEVICE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 322.9700 LB/H Emission Limit 2: 80.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW SPECIFICATIONS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 13.9200 LB/H Emission Limit 2: 1.0500 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW SPECIFICATIONS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 3665.9700 LB/H Emission Limit 2: 395.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW SPECIFICATIONS OF 40 CFR 60.18. SEE POLLUTANT NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: TAC CHAPTER 112 REQUIREMENT: WHEN THE DISTRIBUTIVE CONTROL SYSTEM ENUNCIATES THAT EPN FLARE SO2 EMISSIONS EXCEED 5193 LB/H, THE FOLLOWING MEASURES SHALL BE TAKEN AS APPROPRIATE TO CONTROL TO THE EXTENT PRACTICABLE SO2 IMPACTS AT THE CAMS54 MONITOR: 1) PLANT PERSONNEL SHALL EVALUATE ALL RELEVANT METEORLOGICAL CONDITIONS TO DETERMINE WHETHER ADDITIONAL SO2 EMISSIONS FROM THE FLARE WOULD LIKELY RESULT IN INCREASED SO2 IMPACTS IN THE VICINITY OF THE CAMS54 MONITOR; 2) PLANT PERSONNEL SHALL EVALUATE AMBIENT AIR QUALITY DATA PROVIDED BY THE CAMS54 MONITOR TO DETERMINE IF CURRENT SO2 CONCENTRATIONS ARE GREATER THAN 160 PPB; 3) IF IT IS DETERMINED THAT ADDITIONAL SO2 EMISSIONS FROM THE FLARE WOULD LIKELY RESULT IN INCREASED SO2 IMPACTS FROM THE FLARE AT THE CAMS54 MONITOR, AND THAT THE IMPACTS AT THE CAMS54 MONITOR ARE ABOVE 160 PPB, PLANT PERSONNNEL SHALL CURTAIL PERMITTED ACTIVITIES, AS APPROPRIATE, TO REDUCE SO2 EMISSIONS FROM THE FLARE TO THE MAXIMUM EXTENT PRACTICABLE, BUT TO AT LEAST AT OR BELOW 5193 LB/H.

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 37.6700 LB/H Emission Limit 2: 9.4100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW SPECIFICATIONS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 41.3500 LB/H Emission Limit 2: 5.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW REQUIREMENTS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 32.3300 LB/HEmission Limit 2: 7.5800 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) THE FLARE IS A VOC CONTROL DEVICE Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: THE VENT CATCH TANK SHALL VENT TO THE THERMAL OXIDIZER UNDER NORMAL OPERATIONS AND IT SHALL VENT TO THE FLARE IN AN EMERGENCY. THE FLARE SHALL OPERATE WITH NO LESS THAN 98% EFFICIENCY IN DESTROYING THE VOC SENT TO IT.



## Process/Pollutant Information

PROCESS NAME: FLARE, SSM

Process Type: 19.310 (Chemical Plant Flares)

Primary Fuel: Throughput:

Process Notes: POLLUTANT INFORMATION LISTED UNDER THIS ENTRY IS FOR THE FLARE DURING START-UP, SHUT-DOWN, AND MAINTENANCE

PERIODS. THE FLARE IS LIMITED TO 416 H/YR OPERATION AS THE BACKUP CONTROL DEVICE WHEN EPN SULFOX-TO IS NOT OPERATING. WASTE GAS STREAMS FROM THE SULFOX UNIT VENTS CANNOT GO TO EPN FLARE AND EPN SULFOX-TO AT THE SAME TIME. THE FLARE SHALL BE DESIGNED AND OPERATED WHERE THE COMBINED NATURAL GAS AND WASTE STREAM TO THE FLARE TIP SHALL MEET THE 40 CFR 60.18 SPECIFICATIONS FOR MINIMUM NET HEATING VALUE AND MAXIMUM TIP VELOCITY UNDER NORMAL AND SSM CONDITIONS. A FLAME IS PRESENT AT ALL TIMES AND HAS A CONSTANT PILOT FLAME. THE PILOT FLAME SHALL BE MONITORED BY A THERMOCOUPLE, AN ULTRAVIOLET MONITOR, AND INFRARED MONITOR, OR OTHER EQUIVALENT DEVICE. IN THE EVENT THE FLARE SHUTS DOWN FOR MAINTENANCE PURPOSES DURING A PLANT SHUTDOWN, A TEMPORARY FLARE MEETING THE REQUIREMENTS OF SPECIAL CONDITION NO. 10 SHALL BE INSTALLED IN A LOCATION NEAR THE EXISTING FLARE. THE TEMPORARY FLARE SHALL BE OPERATED DURING THE TIME THE FLARE IS SHUT DOWN.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 322.9700 LB/HEmission Limit 1: 322.9700 LB/H

Emission Limit 2: 80.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MEET THE REQUIREMENTS OF 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 14.4100 LB/H Emission Limit 2: 0.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 37.6700 LB/H Emission Limit 2: 9.4100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) FOLLOW REQUIREMENTS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2541.3700 LB/H Emission Limit 2: 106.4400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18. SEE THE POLLUTANT NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: TAC CHAPTER 112 REQUIREMENT: WHEN THE DISTRIBUTIVE CONTROL SYSTEM ENUNCIATES THAT EPN FLARE SO2 EMISSIONS EXCEED 5193 LB/H, THE FOLLOWING MEASURES SHALL BE TAKEN AS APPROPRIATE TO CONTROL TO THE EXTENT PRACTICABLE SO2 IMPACTS AT THE CAMS54 MONITOR: 1) PLANT PERSONNEL SHALL EVALUATE ALL RELEVANT METEORLOGICAL CONDITIONS TO DETERMINE WHETHER ADDITIONAL SO2 EMISSIONS FROM THE FLARE WOULD LIKELY RESULT IN INCREASED SO2 IMPACTS IN THE VICINITY OF THE CAMS54 MONITOR; 2) PLANT PERSONNEL SHALL EVALUATE AMBIENT AIR QUALITY DATA PROVIDED BY THE CAMS54 MONITOR TO DETERMINE IF CURRENT SO2 CONCENTRATIONS ARE GREATER THAN 160 PPB; 3) IF IT IS DETERMINED THAT ADDITIONAL SO2 EMISSIONS FROM THE FLARE WOULD LIKELY RESULT IN INCREASED SO2 IMPACTS FROM THE FLARE AT THE CAMS54 MONITOR, AND THAT THE IMPACTS AT THE CAMS54 MONITOR ARE ABOVE 160 PPB, PLANT PERSONNNEL SHALL CURTAIL PERMITTED ACTIVITIES, AS APPROPRIATE, TO REDUCE SO2 EMISSIONS FROM THE FLARE TO THE MAXIMUM EXTENT PRACTICABLE, BUT TO AT LEAST AT OR BELOW 5193 LB/H.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 24.2700 LB/H Emission Limit 2: 0.5100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 32.3800 LB/H Emission Limit 2: 0.8500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) THE FLARE IS A VOC CONTROL DEVICE Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: THE VENT CATCH TANK SHALL VENT TO THE THERMAL OXIDIZER UNDER NORMAL OPERATIONS AND IT SHALL VENT TO THE FLARE IN AN EMERGENCY. THE FLARE SHALL OPERATE WITH NO LESS THAN 98% EFFICIENCY IN DESTROYING THE VOC SENT TO IT.



## Process/Pollutant Information

PROCESS NAME: FLARE, TOTAL HOURLY AND ANNUAL

Process 19.310 (Chemical Plant Flares)Process

Type: 19.310 (Chemical Plant Flares)

Primary Fuel: Throughput:

Process Notes: EMISSIONS LISTED UNDER THIS ENTRY ARE FOR THE TOTAL HOURLY AND ANNUAL EMISSIONS FROM BOTH STEADY STATE

AND SSM. 416 H/YR OPERATION AS THE BACKUP CONTROL DEVICE WHEN EPN SULFOX-TO IS NOT OPERATING. WASTE GAS STREAMS FROM THE SULFOX UNIT VENTS CANNOT GO TO EPN FLARE AND EPN SULFOX-TO AT THE SAME TIME. THE FLARE SHALL BE DESIGNED AND OPERATED WHERE THE COMBINED NATURAL GAS AND WASTE STREAM TO THE FLARE TIP SHALL MEET THE 40 CFR 60.18 SPECIFICATIONS FOR MINIMUM NET HEATING VALUE AND MAXIMUM TIP VELOCITY UNDER NORMAL AND SSM CONDITIONS. A FLAME IS PRESENT AT ALL TIMES AND HAS A CONSTANT PILOT FLAME. THE PILOT FLAME SHALL BE MONITORED BY A THERMOCOUPLE, AN ULTRAVIOLET MONITOR, AND INFRARED MONITOR, OR OTHER EQUIVALENT DEVICE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 322.9700 LB/H Emission Limit 2: 80.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW REQUIREMENTS OF 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 28.3300 LB/H Emission Limit 2: 1.4400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 37.6700 LB/H Emission Limit 2: 9.4100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 6207.3400 LB/H Emission Limit 2: 501.5700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18. SEE POLLUTANT NOTES. Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: TAC CHAPTER 112 REQUIREMENT: WHEN THE DISTRIBUTIVE CONTROL SYSTEM ENUNCIATES THAT EPN FLARE SO2 EMISSIONS EXCEED 5193 LB/H, THE FOLLOWING MEASURES SHALL BE TAKEN AS APPROPRIATE TO CONTROL TO THE EXTENT PRACTICABLE SO2 IMPACTS AT THE CAMS54 MONITOR: 1) PLANT PERSONNEL SHALL EVALUATE ALL RELEVANT METEORLOGICAL CONDITIONS TO DETERMINE WHETHER ADDITIONAL SO2 EMISSIONS FROM THE FLARE WOULD LIKELY RESULT IN INCREASED SO2 IMPACTS IN THE VICINITY OF THE CAMS54 MONITOR; 2) PLANT PERSONNEL SHALL EVALUATE AMBIENT AIR QUALITY DATA PROVIDED BY THE CAMS54 MONITOR TO DETERMINE IF CURRENT SO2 CONCENTRATIONS ARE GREATER THAN 160 PPB; 3) IF IT IS DETERMINED THAT ADDITIONAL SO2 EMISSIONS FROM THE FLARE WOULD LIKELY RESULT IN INCREASED SO2 IMPACTS FROM THE FLARE AT THE CAMS54 MONITOR, AND THAT THE IMPACTS AT THE CAMS54 MONITOR ARE ABOVE 160 PPB, PLANT PERSONNNEL SHALL CURTAIL PERMITTED ACTIVITIES, AS APPROPRIATE, TO REDUCE SO2 EMISSIONS FROM THE FLARE TO THE MAXIMUM EXTENT PRACTICABLE, BUT TO AT LEAST AT OR BELOW 5193 LB/H.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 65.6200 LB/H Emission Limit 2: 5.6800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW THE REQUIREMENTS OF 40 CFR 60.18 Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 64.7100 LB/H Emission Limit 2: 8.4300 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) THE FLARE IS A VOC CONTROL DEVICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEAT TRANSFER FLUID HEATER, H202 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 31.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.5900 LB/H Emission Limit 2: 11.3200 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.0800 LB/H Emission Limit 2: 13.4800 T/YR Standard Emission: 0.1000 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: 0.0006 LB/MMBTU CALCULATED, USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FUEL GAS SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1700 LB/H Emission Limit 2: 0.7400 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2300 LB/H Emission Limit 2: 1.0200 T/YR Standard Emission: 0.0100 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) SULFUR/METHANE HEATERS

Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: Throughput:

Process Notes: THIS ENTRY INCLUDES EPNS: H401/H402 AND H501/H502. H401/H402 SHARE A COMMON EXHAUST STACK AND H501/H502

SHARE A COMMON EXHAUST STACK.POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0900 LB/H EACH COMMON STACK Emission Limit 2: 0.3800 T/YR EACH COMMON STACK Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.3200 LB/H EACH COMMON STACK Emission Limit 2: 5.7700 T/YR EACH COMMON STACK Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 1.6100 LB/H EACH COMMON STACK

Emission Limit 2: 7.0400 T/YR EACH COMMON STACK Standard Emission: 0.1000 LB/MMBTU EACH COMMON STACK Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LOW-NOX TECHNOLOGY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H EACH COMMON STACK Emission Limit 2: 0.5200 T/YR EACH COMMON STACK Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H EACH COMMON STACK Emission Limit 2: 0.0500 T/YR EACH COMMON STACK Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: Control Method: (P) FUEL GAS SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEAT TRANSFER FLUID HEATER, H2202 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 31.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: 0.0006 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FUEL GAS SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 0.5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 2.5900 LB/H

Emission Limit 2: 11.3200 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.0800 LB/H Emission Limit 2: 13.4800 T/YR Standard Emission: 0.1000 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2300 LB/H Emission Limit 2: 1.0200 T/YR Standard Emission: 0.0070 LB/MMBTU CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: Other Case-by-Case

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1700 LB/H Emission Limit 2: 0.7400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: INCINERATOR

Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput:

Process Notes: EPN: INCIN. THE INCINERATOR AND THERMAL OXIDIZER SHALL BE OPERATED WITH NOT LESS THAN 5% O2 FROM EPN INCIN

AND NOT LESS THAN 2% O2 FROM EPN SULFOX-TO. EPN INCIN MINIMUM INCINERATOR FIREBOX EXIT TEMPERATURE SHALL NOT BE LESS THAN 1600 DEGREES F. THE FIREBOX EXIT TEMPERATURE AND % O2 SHALL BE CONTINUOUSLY MONITORED AND RECORDED. THE VALUES CAN BE CHANGED BASED ON STACK SAMPLING RESULTS DEMONSTRATING COMPLIANCE WITH THE PERCENT DESTRUCTION AND REMOVAL EFFICIENCY OR VOC OUTLET CONCENTRATION.POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.3900 LB/H Emission Limit 2: 6.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.4200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 1.0600 LB/H Emission Limit 2: 4.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.5500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6900 LB/H Emission Limit 2: 7.4100 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 139.0000 LB/H Emission Limit 2: 83.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR STORAGE TANK, S-1 Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.2300 LB/H Emission Limit 2: 1.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) SEE POLLUTANT NOTES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE H2S CONCENTRATION IN THE VPOR SPACE OF THE MOLTEN SULFUR STORAGE TANKS SHALL NOT EXCEED 250 PPMV. THE TANK VAPORS SHALL BE SAMPLED AND ANALYZED FOR H2S AT LEAST ONCE QUARTERLY DURING LOADING ACTIVITIES. IF ANY SCHEDULED ANALYSIS INDICATED AN EXCEEDANCE OF THIS LIMIT, MATERIAL TRANSFERS TO THE TANK SHALL BE REDUCED UNTIL ADDITIONAL SAMPLING, TO BE CONDUCTED AT LEAST EVERY 8 H, INDICATES THAT THE H2S CONCENTRATION IS BELOW 250 PPMV.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.8600 LB/H Emission Limit 2: 3.7500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR PIT, S-2Process Type: 64.999 (Other SOCMI Processes)

Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.1700 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: SULFUR TRUCK, S-3 Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements:Control Method: (N) NONE INDICATED

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFOX CHILLER SYSTEM, SULFOX-CHLR

Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes: SULFOX PROCESS UNITS SHALL NEVER OPERATE UNLESS THE SULFOX THERMAL OXIDIZER IS PROPERLY OPERATING. WHEN

EPN SULFOX- TO FAILS TO OPERATE THE SULFOX PROCESS UNITS SHALL BE SHUTDOWN IN AN ORDERLY MANNER.

POLLUTANT NAME: Hydrochlorofluorocarbons (HCFC)

CAS Number: HCFC Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds , Ozone Depleting Substance (ODS) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFOX COOLING TOWER, SULFOX-CTProcess Type: 99.009 (Industrial Process Cooling Towers)

Primary Fuel: Throughput:

Process Notes: SULFOX PROCESS UNITS SHALL NEVER OPERATE UNLESS THE SULFOX THERMAL OXIDIZER IS PROPERLY OPERATING. WHEN

EPN SULFOX- TO FAILS TO OPERATE THE SULFOX PROCESS UNITS SHALL BE SHUTDOWN IN AN ORDERLY MANNER.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6100 LB/H Emission Limit 2: 2.6500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (B) SEE POLLUTANT NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE COOLING TOWER SHALL BE EQUIPPED WITH DRIFT ELIMINATORS. THE VOC ASSOCIATEDPollutant/Compliance Notes: THE COOLING TOWER SHALL BE EQUIPPED WITH DRIFT ELIMINATORS. THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS.



## Process/Pollutant Information

PROCESS NAME: BAGFILTER, SULFOX-INH

Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput:

Process Notes: SULFOX PROCESS UNITS SHALL NEVER OPERATE UNLESS THE SULFOX- TO IS PROPERLY OPERATING WHEN EPN-TO FAILS TO

OPERATE THEN THE SULFOX PROCESS UNITS SHALL BE SHUTDOWN IN AN ORDERLY MANNER.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) BAGFILTER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS

NAME: THERMAL OXIDIZER, STEADY STATE SERVICE

Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels))

Primary Fuel: Throughput: 134.50 MMBTU/H

Process Notes: EPN: SULFOX-TO. THIS ENTRY IS FOR THE TO IN STEADY STATE SERVICE. THE SULFOX-TO OPERATION IS LIMITED TO 735 H/YR IN

SSM SERVICE. SSM EVENTS FOR THE SULFOX PROCESS UNIT SHALL BE RECORDED UPON EACH OCCURRENCE. SULFOX PROCESS UNITS SHALL NEVER OPERATE UNLESS THE SULFOX-TO IS PROPERLY OPERATING. WHEN EPN SULFOX-TO FAILS TO OPERATE, THE SULFOX PROCESS UNITS SHALL BE SHUTDOWN IN AN ORDERLY MANNER. THE ACROLEIN REACTOR SHALL AUTOMATICALLY SHUT DOWN WHEN THE SULFOX-TO SHUTS DOWN. PRODUCTION OF METHYL MERCAPTAN, ETHYL MERCAPTAN, TERITARY BUTYL MERCAPTAN, DIMETHYL DISULFIDE, DIMETHYL SULFIDE AND H2S SHALL BE LIMITED TO THE AMOUNTS SPECIFIED IN THE CONFIDENTIAL SECTION OF THE APPLICATION SUBMITTED ON 1/2002. ACROLEIN PRODUCED FROM THE SULFOX UNIT IS LIMITED TO 114.5 MM POUNDS ON A ROLLING 12 MO BASIS. MMP PRODUCTION FROM THE SULFOX UNIT IS LIMITED TO 210 MM POUNDS ON A ROLLING 12-MO BASIS. THE SITE WILL MAINTAIN MONTHLY RECORDS OF DAILY AND ANNUAL PRODUCTION OF EACH PRODUCT. THE ANNUAL PRODUCTION OF EACH PRODUCT SHALL BE TABULATED ON A 12-MO ROLLING BASIS. WASTE GAS STREAMS FROM THE SULFOX UNIT VENTS CANNOT GO TO EPN FLARE AND EPN SULFOX-TO AT THE SAME TIME. EPNS INCIN AND SULFOX-TO SHALL BE OPERATED WITH NOT LESS THAN 5% O2 FROM EPN INCIN AND NOT LESS THAN 2% O2 FROM EPN SULFOX-TO. EPN SULFOX-TO MINIMUM OXIDIZER FIREBOX EXIT THEMPERATURE SHALL NOT BE LESS THAN 1800 DEGREES F. EACH FIREBOX EXIT TEMPERATURE AND % O2 SHALL BE CONTINUOUSLY MONITORED AND RECORDED. THE VALUES CAN BE CHANGED BASED ON STACK SAMPLING RESULTS DEMONSTRATING COMPLIANCE WITH THE % DESTRUCTION AND REMOVAL EFFICIENCY OR VOC OUTLET CONCENTRATION.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 9.5600 LB/H Emission Limit 2: 41.8700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 8.3500 LB/H Emission Limit 2: 36.5700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.9500 LB/H Emission Limit 2: 8.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.8900 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 7.8400 LB/H Emission Limit 2: 29.2800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) THE INCINERATOR IS A VOC CONTROL Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes: WASTE GAS AND ATOMIZED LIQUID STREAMS FROM THE SULFOX UNITS SHALL BE ROUTED TO THE SULFOX TO. THE SULFOX TO SHALL DESTROY THE VOC STREAMS SENT TO IT AT A MINIMUM OF 99.9% OR AT A VOC OUTLET CONCENTRATION OF 10 PPMV.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 4.2100 LB/H Emission Limit 2: 16.8800 T/YREmission Limit 2: 16.8800 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FUEL GAS COMBUSTED IN EACH COMBUSTION EMISSION POINT NUMBER SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: THERMAL OXIDIZER, SSM

Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels))

Primary Fuel: Throughput: 134.50 MMBTU/H

Process Notes: EPN: SULFOX-TO. THIS ENTRY IS FOR PERIODS OF START-UP, SHUTDOWN, AND MAINTENANCE (SSM). THE SULFOX-TO

OPERATION IS LIMITED TO 735 H/YR IN SSM SERVICE. SSM EVENTS FOR THE SULFOX PROCESS UNIT SHALL BE RECORDED UPON EACH OCCURRENCE. SULFOX PROCESS UNITS SHALL NEVER OPERATE UNLESS THE SULFOX-TO IS PROPERLY OPERATING. WHEN EPN SULFOX-TO FAILS TO OPERATE, THE SULFOX PROCESS UNITS SHALL BE SHUTDOWN IN AN ORDERLY MANNER. THE ACROLEIN REACTOR SHALL AUTOMATICALLY SHUT DOWN WHEN THE SULFOX-TO SHUTS DOWN. PRODUCTION OF METHYL MERCAPTAN, ETHYL MERCAPTAN, TERITARY BUTYL MERCAPTAN, DIMETHYL DISULFIDE, DIMETHYL SULFIDE AND H2S SHALL BE LIMITED TO THE AMOUNTS SPECIFIED IN THE CONFIDENTIAL SECTION OF THE APPLICATION SUBMITTED ON 1/2002. ACROLEIN PRODUCED FROM THE SULFOX UNIT IS LIMITED TO 114.5 MM POUNDS ON A ROLLING 12 MO BASIS. MMP PRODUCTION FROM THE SULFOX UNIT IS LIMITED TO 210 MM POUNDS ON A ROLLING 12-MO BASIS. THE SITE WILL MAINTAIN MONTHLY RECORDS OF DAILY AND ANNUAL PRODUCTION OF EACH PRODUCT. THE ANNUAL PRODUCTION OF EACH PRODUCT SHALL BE TABULATED ON A 12-MO ROLLING BASIS. WASTE GAS STREAMS FROM THE SULFOX UNIT VENTS CANNOT GO TO EPN FLARE AND EPN SULFOX-TO AT THE SAME TIME. EPNS INCIN AND SULFOX-TO SHALL BE OPERATED WITH NOT LESS THAN 5% O2 FROM EPN INCIN AND NOT LESS THAN 2% O2 FROM EPN SULFOX-TO. EPN SULFOX-TO MINIMUM OXIDIZER FIREBOX EXIT THEMPERATURE SHALL NOT BE LESS THAN 1800 DEGREES F. EACH FIREBOX EXIT TEMPERATURE AND % O2 SHALL BE CONTINUOUSLY MONITORED AND RECORDED. THE VALUES CAN BE CHANGED BASED ON STACK SAMPLING RESULTS DEMONSTRATING COMPLIANCE WITH THE % DESTRUCTION AND REMOVAL EFFICIENCY OR VOC OUTLET CONCENTRATION.

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 8.3500 LB/H Emission Limit 2: 36.5700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.9500 LB/H Emission Limit 2: 8.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1156.4700 LB/HEmission Limit 2: 1.5500 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) FUEL GAS SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8900 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 9.5600 LB/H Emission Limit 2: 41.8700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 7.8400 LB/H Emission Limit 2: 29.2800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) THE OXIDIZER IS A VOC CONTROL. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: WASTE GAS AND ATOMIZED LIQUID STREAMS FROM THE SULFOX UNITS SHALL BE ROUTED TO THE SULFOX TO. THE SULFOX TO SHALL DESTROY THE VOC STREAMS SENT TO IT AT A MINIMUM OF 99.9% OR AT A VOC OUTLET CONCENTRATION OF 10 PPMV.



## Process/Pollutant Information

PROCESS NAME: THERMAL OXIDIZER, TOTAL HOURLY AND ANNUAL

Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels))

Primary Fuel: Throughput: 134.50 MMBTU/H

Process EPN: SULFOX-TO. THIS ENTRY IS FOR THE TOTAL ANNUAL AND HOURLY FROM BOTH STEADY STATE SERVICE AND SSM. THEProcess

Notes: EPN: SULFOX-TO. THIS ENTRY IS FOR THE TOTAL ANNUAL AND HOURLY FROM BOTH STEADY STATE SERVICE AND SSM. THE

SULFOX-TO OPERATION IS LIMITED TO 735 H/YR IN SSM SERVICE. SSM EVENTS FOR THE SULFOX PROCESS UNIT SHALL BE RECORDED UPON EACH OCCURRENCE. SULFOX PROCESS UNITS SHALL NEVER OPERATE UNLESS THE SULFOX-TO IS PROPERLY OPERATING. WHEN EPN SULFOX-TO FAILS TO OPERATE, THE SULFOX PROCESS UNITS SHALL BE SHUTDOWN IN AN ORDERLY MANNER. THE ACROLEIN REACTOR SHALL AUTOMATICALLY SHUT DOWN WHEN THE SULFOX-TO SHUTS DOWN. PRODUCTION OF METHYL MERCAPTAN, ETHYL MERCAPTAN, TERITARY BUTYL MERCAPTAN, DIMETHYL DISULFIDE, DIMETHYL SULFIDE AND H2S SHALL BE LIMITED TO THE AMOUNTS SPECIFIED IN THE CONFIDENTIAL SECTION OF THE APPLICATION SUBMITTED ON 1/2002. ACROLEIN PRODUCED FROM THE SULFOX UNIT IS LIMITED TO 114.5 MM POUNDS ON A ROLLING 12 MO BASIS. MMP PRODUCTION FROM THE SULFOX UNIT IS LIMITED TO 210 MM POUNDS ON A ROLLING 12-MO BASIS. THE SITE WILL MAINTAIN MONTHLY RECORDS OF DAILY AND ANNUAL PRODUCTION OF EACH PRODUCT. THE ANNUAL PRODUCTION OF EACH PRODUCT SHALL BE TABULATED ON A 12-MO ROLLING BASIS. WASTE GAS STREAMS FROM THE SULFOX UNIT VENTS CANNOT GO TO EPN FLARE AND EPN SULFOX-TO AT THE SAME TIME. EPNS INCIN AND SULFOX-TO SHALL BE OPERATED WITH NOT LESS THAN 5% O2 FROM EPN INCIN AND NOT LESS THAN 2% O2 FROM EPN SULFOX-TO. EPN SULFOX-TO MINIMUM OXIDIZER FIREBOX EXIT THEMPERATURE SHALL NOT BE LESS THAN 1800 DEGREES F. EACH FIREBOX EXIT TEMPERATURE AND % O2 SHALL BE CONTINUOUSLY MONITORED AND RECORDED. THE VALUES CAN BE CHANGED BASED ON STACK SAMPLING RESULTS DEMONSTRATING COMPLIANCE WITH THE % DESTRUCTION AND REMOVAL EFFICIENCY OR VOC OUTLET CONCENTRATION.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 8.3500 LB/H Emission Limit 2: 36.5700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1157.4400 LB/H Emission Limit 2: 18.4300 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE FUEL GAS SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: WASTE GAS AND ATOMIZED LIQUID STREAMS FROM THE SULFOX UNITS SHALL BE ROUTED TO THE SULFOX TO. THE SULFOX TO SHALL DESTROY THE VOC STREAMS SENT TO IT AT A MINIMUM OF 99.9% OR AT A VOC OUTLET CONCENTRATION OF 10 PPMV.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 7.8400 LB/H Emission Limit 2: 29.2800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) THE INCINERATOR IS A VOC CONTROL. Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 9.5600 LB/H Emission Limit 2: 41.8700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.9500 LB/H Emission Limit 2: 8.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.8900 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: WASTEWATER TREATMENT PLANT, WWTP Process Type: 64.006 (Wastewater Collection & Treatment) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1200 LB/H Emission Limit 2: 0.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: NSPS Control Method: (A) EMISSIONS FROM ANY VOC WATER SEPARATION EQUIPMENT SHALL BE VENTED TO A PERMITTED CONTROL DEVICE OR RECYCLED TO THE PROCESS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) STEAM BOILERS, X-426A AND X-426B Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 15.80 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.3300 LB/H EACH Emission Limit 2: 5.8100 T/YR EACH Standard Emission: 0.0800 LB/MMBTU EACH, CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.1200 LB/H EACH Emission Limit 2: 0.5300 T/YR EACH Standard Emission: 0.0080 LB/MMBTU EACH, CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H EACH Emission Limit 2: 0.0400 T/YR EACH Standard Emission: 0.0006 LB/MMBTU EACH, CALCULATED USING THROUGHPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FUEL GAS SHALL BE SWEET NATURAL GAS CONTAINING NO MORE THAN 5 GR S/100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0900 LB/H EACH Emission Limit 2: 0.3800 T/YR EACH Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.0500 LB/H EACH Emission Limit 2: 9.0000 T/YR EACH Standard Emission: 0.1300 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACROLEIN PROCESS FUGITIVES, ACRO-FUG

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE EMISSION

RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.3100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) GOOD ENGINEERING PRACTICES AND PROCEDURES OF LEAK DETECTION (28 VHP LDAR), ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACROLEIN STORAGE TANKS FUGITIVES, ACRO-TKSFUG

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE EMISSION

RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPSControl Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR.

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ACROLEIN WASTEWATER FUGITIVES, ACRO-WWFUG

Process Type: 64.006 (Wastewater Collection & Treatment) Primary Fuel: Throughput:

Process Notes: FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE EMISSION

RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (B) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. ALL ACROLEIN WW STORAGE TANKS SHALL VENT TO EPN SULFOX-TO. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS B1/B2 UNITS CHILLER SYSTEMPROCESS

NAME: B1/B2 UNITS CHILLER SYSTEM

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED AS A MAXIMUM ALLOWABLE EMISSION

RATE.

POLLUTANT NAME: Hydrochlorofluorocarbons (HCFC)

CAS Number: HCFC Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds , Ozone Depleting Substance (ODS) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TRAIN 1- ETSH OR TBM PRODUCTION FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: BMT-1E/T. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE. THE BMT-1 UNIT CAN PRODUCE EITHER MESH, ETSH, OR TBM. THEREFORE, EMISSIONS FROM BMT-1M AND BMT-1E/T DO NOT OCCUR SIMULTANEOUSLY.

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3000 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28 CNTA Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/HEmission Limit 2: 0.0100 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PROCEDURES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TRAIN 1 - MESH PRODUCTION FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: BMT-1M. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE. THE BMT-1 UNIT CAN PRODUCE EITHER MESH, ETSH, OR TBM. THEREFORE, EMISSIONS FROM BMT-1M AND BMT-1E/T DO NOT OCCUR SIMULTANEOUSLY.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28CNTA LDAR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PROCEDURES FOR LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS TRAIN 2- MESH PRODUCTION FUGITIVESPROCESS

NAME: TRAIN 2- MESH PRODUCTION FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: BMT-2M. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28 CNTA Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PROCEDURES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency:Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0800 LB/H Emission Limit 2: 0.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIMETHYL DISULFIDE AREA PROCESS FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: DMDS. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0600 LB/HEmission Limit 2: 0.2400 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: DIMETHYL SULFIDE AREA PROCESS FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: DMS. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PROCEDURES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS H2S PLANT PROCESS FUGITIVESPROCESS

NAME: H2S PLANT PROCESS FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE EMISSION

RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28CNTA LDAR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE H2S PLANT SHALL OPERATE AT CAPACITIES WHERE THE TOTAL H2S PRODUCTION IS CONSUMED ON-SITE.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR.Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE AREA FUGITIVES

Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: Throughput:

Process Notes: EPN: FAREFUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED AS A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/HEmission Limit 2: 0.0100 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: INCINERATOR PROCESS FUGITIVES

Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput:

Process Notes: EPN: FUG-INCIN. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28CNTA LDAR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) 28VHP LDAR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MMP PROCESS AREA FUGITIVES

Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: MMP-FUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.5500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MMP RAILCAR LOADING AREA PROCESS FUGITIVES Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: MMPRC-FUG

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) SEE POLLUTANT NOTES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: VISUAL INSPECTION AND REPAIR/REPLACEMENT OF DAMAGED LINES. MMP RAILCAR LOADING WILL USE CLOSED LOOP VAPOR BALANCE SYSTEMS CONNECTED TO THE MMP STORAGE TANK OR THE SULFOX TO. UPON COMPLETION OF MMP LOADING OPERATIONS THE LOADING LINE WILL BE PURGED INTO THE RAILCAR OR THE MMP STORAGE TANK. WHEN UNHOOKING THE RAILCAR FROM THE LOADING LINE, AN ACETIC ACID OR EQUIVALENT WASH WILL BE DONE AFTER EACH MMP LOADING. THE WASH MATERIAL WILL BE NEUTRALIZED AND MANAGED IN THE ON-SITE WASTEWATER SYSTEM. THE WASH MATERIAL TANK WILL VENT TO THE SULFOX TO.

## Process/Pollutant Information

PROCESS NAME: MMP STORAGE AREA PROCESS FUGITIVES

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020)) Primary Fuel: Throughput:

Process Notes: EPN: MMPTKS-FUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) SEE POLLUTANT NOTES. FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: MMP DAY STORAGE TANKS WILL VENT TO THE MMP BULK STORAGE TANK WHICH WILL THEN VENT TO EPN SULFOX- TO. UNDER NO CIRCUMSTANCES SHALL THE MMP DAY STORAGE TANKS AND BULK STORAGE TANK VENT TO THE ATMOSPHERE. ALL ACROLEIN WASTEWATER STORAGE TANKS SHALL VENT TO EPN SULFOX-TO.



## Process/Pollutant Information

PROCESS NAME: PRODUCT RECOVERY TOWER FUGITIVES

Process Type: 64.999 (Other SOCMI Processes)Primary Fuel:

Throughput:

Process Notes: EPN: PR-TOWER. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28CNTA LDAR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: RAILCAR LOADING/UNLOADING FUGITIVES

Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: RCSHIP. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHALL NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: NSPS Control Method: (P) SEE POLLUTANT NOTES. FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL LOADING LINES SHALL BE INSPECTED VISUALLY FOR POSSIBLE LEAK SITES BEFORE THE START OF ANY LOADING OPERATIONS. DAMAGED HOSES SHALL BE REPAIRED OR REPLACED BEFORE ANY LOADING OPERATIONS COMMENCE. UPON COMPLETION OF LOADING OPERATIONS, ALL LOADING LINES (EXCEPT FOR MMP) SHALL BE PURGED WITH INERT GAS TO THE FLARE BEFORE ANY CONNECTIONS BETWEEN THE LOADING RACKS AND LOADED VESSELS ARE BROKEN. MMP RAILCAR LOADING WILL USE CLOSED LOOP VAPOR BALANCE SYSTEMS CONNECTED TO THE MMP STORAGE TANK OR THE SULFOX-TO. UPON COMPLETION OF MMP LOADING OPERATIONS THE LOADING LINE WILL BE PURGED INTO THE RAILCAR OR THE MMP STORAGE TANK. WHEN UNHOOKING THE RAILCAR FROM THE LOADING LINE, AN ACETIC ACID OR EQUIVALENT WASH WILL BE DONE AFTER EACH MMP LOADING. THE WASH MATERIAL WILL BE NEUTRALIZED AND MANAGED IN THE ON-SITE WASTEWATER SYSTEM. THE WASH MATERIAL TANK WILL VENT TO THE SULFOX-TO.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) SEE POLLUTANT NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL LOADING LINES SHALL BE INSPECTED VISUALLY FOR POSSIBLE LEAK SITES BEFORE THE START OF ANY LOADING OPERATIONS. DAMAGED HOSES SHALL BE REPAIRED OR REPLACED BEFORE ANY LOADING OPERATIONS COMMENCE. UPON COMPLETION OF LOADING OPERATIONS, ALL LOADING LINES (EXCEPT FOR MMP) SHALL BE PURGED WITH INERT GAS TO THE FLARE BEFORE ANY CONNECTIONS BETWEEN THE LOADING RACKS AND LOADED VESSELS ARE BROKEN. MMP RAILCAR LOADING WILL USE CLOSED LOOP VAPOR BALANCE SYSTEMS CONNECTED TO THE MMP STORAGE TANK OR THE SULFOX-TO. UPON COMPLETIONOF MMP LOADING OPERATIONS THE LOADING LINE WILL BE PURGED INTO THE RAILCAR OR THE MMP STORAGE TANK. WHEN UNHOOKING THE RAILCAR FROM THE LOADING LINE, AN ACETIC ACID OR EQUIVALENT WASH WILL BE DONE AFTER EACH MMP LOADING. THE WASH MATERIAL WILL BE NEUTRALIZED AND MANAGED IN THE ON-SITE WASTEWATER SYSTEM. THE WASH MATERIAL TANK WILL VENT TO THE SULFOX-TO.



## Process/Pollutant Information

PROCESS NAME: RUNDOWN TANK FUGITIVES

Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput:

Process Notes: EPN: RUNDOWN. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) MMP DAY STORAGE TANKS WILL VENT TO THE MMP BULK STORAGE TANK WHICH WILL VENT TO SULF0X-TO. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (B) MMP DAY STORAGE TANKS WILL VENT TO THE MMP BULK STORAGE TANK WHICH WILL VENT TO SULF0X-TO. FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (B) MMP DAY STORAGE TANKS WILL VENT TO THE MMP BULK STORAGE TANK WHICH WILL VENT TO SULF0X-TO. FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: STORAGE TANKS FUGITIVES

Process Type: 64.004 (Storage Tanks (SOCMI only - also see 42.001-42.999 and 62.020))Primary Fuel:

Throughput:

Process Notes: EPN: STORAGE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.6400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (B) MMP DAY STORAGE TANKS WILL VENT TO THE MMP BULK STORAGE TANK WHICH WILL VENT TO SULF0X-TO. FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1600 LB/H Emission Limit 2: 0.6900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (B) MMP DAY STORAGE TANKS WILL VENT TO THE MMP BULK STORAGE TANK WHICH WILL VENT TO SULF0X-TO. FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFOX CHILLER SYSTEM FUGITIVES

Process Type: 64.999 (Other SOCMI Processes) Primary Fuel: Throughput:

Process Notes: EPN: SULFOXCHLR. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrochlorofluorocarbons (HCFC)

CAS Number: HCFC Test Method: Unspecified Pollutant Group(s): ( Organic Compounds (all) , Organic Non-HAP Compounds , Ozone Depleting Substance (ODS) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SOUR WATER STRIPPERS FUGITIVES

Process Type: 64.006 (Wastewater Collection & Treatment) Primary Fuel:Throughput:

Process Notes: EPN: SWS. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (B) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. EMISSIONS FROM ANY VOC WATER SEPARATION EQUIPMENT SHALL BE VENTED TO A PERMITTED CONTROL DEVICE OR RECYCLED TO THE PROCESS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) 28CNTA LDAR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: THERMAL OXIDIZER PROCESS FUGITIVES

Process Type: 64.003 (Processes Vents (emissions from air oxidation, distillation, and other reaction vessels)) Primary Fuel: Throughput:

Process Notes: EPN: TO-FUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHALL NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TANK TRUCK LOADING/UNLOADING FUGITIVES

Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes: EPN: TTSHIP. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE.

POLLUTANT NAME: Sulfur, Total Reduced (TRS)

CAS Number: 7704 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) SEE POLLUTANT NOTES. FOLLOW PRACTICES OF LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL LOADING LINES SHALL BE INSPECTED VISUALLY FOR POSSIBLE LEAK SITES BEFORE THE START OF ANY LOADING OPERATIONS. DAMAGED HOSES SHALL BE REPAIRED OR REPLACED BEFORE ANY LOADING OPERATIONS COMMENCE. UPON COMPLETION OF LOADING OPERATIONS, ALL LOADING LINES (EXCEPT FOR MMP) SHALL BE PURGED WITH INERT GAS TO THE FLARE BEFORE ANY CONNECTIONS BETWEEN THE LOADING RACKS AND LOADEDVESSELS ARE BROKEN. MMP RAILCAR LOADING WILL USE CLOSED LOOP VAPOR BALANCE SYSTEMS CONNECTED TO THE MMP STORAGE TANK OR THE SULFOX-TO. UPON COMPLETION OF MMP LOADING OPERATIONS THE LOADING LINE WILL BE PURGED INTO THE RAILCAR OR THE MMP STORAGE TANK. WHEN UNHOOKING THE RAILCAR FROM THE LOADING LINE, AN ACETIC ACID OR EQUIVALENT WASH WILL BE DONE AFTER EACH MMP LOADING. THE WASH MATERIAL WILL BE NEUTRALIZED AND MANAGED IN THE ON-SITE WASTEWATER SYSTEM. THE WASH MATERIAL TANK WILL VENT TO THE SULFOX-TO.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) SEE POLLUTANT NOTES. FOLLOW PRACTICES OF GOOD ENGINEERING, LEAK DETECTION, ISOLATION, AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ALL LOADING LINES SHALL BE INSPECTED VISUALLY FOR POSSIBLE LEAK SITES BEFORE THE START OF ANY LOADING OPERATIONS. DAMAGED HOSES SHALL BE REPAIRED OR REPLACED BEFORE ANY LOADING OPERATIONS COMMENCE. UPON COMPLETION OF LOADING OPERATIONS, ALL LOADING LINES (EXCEPT FOR MMP) SHALL BE PURGED WITH INERT GAS TO THE FLARE BEFORE ANY CONNECTIONS BETWEEN THE LOADING RACKS AND LOADED VESSELS ARE BROKEN. MMP RAILCAR LOADING WILL USE CLOSED LOOP VAPOR BALANCE SYSTEMS CONNECTED TO THE MMP STORAGE TANK OR THE SULFOX-TO. UPON COMPLETION OF MMP LOADING OPERATIONS THE LOADING LINE WILL BE PURGED INTO THE RAILCAR OR THE MMP STORAGE TANK. WHEN UNHOOKING THE RAILCAR FROM THE LOADING LINE, AN ACETIC ACID OR EQUIVALENT WASH WILL BE DONE AFTER EACH MMP LOADING. THE WASH MATERIAL WILL BE NEUTRALIZED AND MANAGED IN THE ON-SITE WASTEWATER SYSTEM. THE WASH MATERIAL TANK WILL VENT TO THE SULFOX-TO.



## Facility InformationRBLC ID: 

## TX-0422 (final) Date Determination Last Updated: 12/15/2004 Corporate/Company Name: BP AMOCO CHEMICAL CO. Permit Number: PSD-TX-984

Facility Name: BP TEXAS CITY CHEMICAL PLANT B Permit Date: 12/05/2002 (actual) Facility Contact: JACK BRINLY 4099424501 FRS Number: 110012628246 Facility Description: B.P. AMOCO CHEMICAL COMPANY IS REQUESTING AUTHORIZATION TO CONSTRUCT A NEW CHEMICAL MANUFACTURING UNIT TO PRODUCE 1,4-BUTANEDIOL (BDO) AND TETRAHYDROFURAN (THF). FACILITY IS LOCATED AT 2899 FM 519 EAST, TEXAS CITY. SIC Code: 2869

Permit Type: B: Add new process to existing facility NAICS Code: 325192 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: GALVESTON Facility State: TX Facility ZIP Code: 77590 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: ADDITIONAL PERMIT NO.: 46046, REGULATED ENTITY ID: RN102536307 Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 329.3400 (Tons/Year) Nitrogen Oxides (NOx) 39.4400 (Tons/Year) Particulate Matter (PM) 119.5300 (Tons/Year) Sulfur Oxides (SOx) 24.8200 (Tons/Year) Volatile Organic Compounds (VOC) 133.1800 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: FUGITIVES Process Type: 64.002 (Equipment Leaks (valves, compressors, pumps, etc.)) Primary Fuel: Throughput:

Process Notes: PIPING, VALVES, CONNECTORS, PUMPS, AND COMPRESSORS

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LEAK INSPECTION AND MONITORING, REPAIR AND MAINTENANCE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT IS CONTROL, NO EMISSION RATE LIMIT.



## Process/Pollutant Information

PROCESS NAME: TANKS, INTERNAL FLOATING ROOF & FIXED ROOF

Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes: APPLIES TO VOC WITH AN AGGREGATE PARTIAL PRESSURE OF > 0.5 PSIA AT THE MAXIMIM EXPECTED OPERATING

TEMPERATURE, AND TO STORAGE TANKS > 25,000 GALLONS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) INTERNAL FLOATING ROOF INSTALLED IN ALL TANKS, CLOSURE DEVICES, TANKControl Method: (P) INTERNAL FLOATING ROOF INSTALLED IN ALL TANKS, CLOSURE DEVICES, TANK EXTERIORS PAINTED WHITE OR ALUMINUM, OPERATION WITHOUT VISIBLE LEAKS AND SPILLS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT IS INTERNAL FLOATING ROOF, OPERATION. LIMITS FOR INDIVIDUAL TANKS RANGE FROM < 0.01 LB/H TO 1.04 LB/H



## Process/Pollutant Information

PROCESS NAME: HEATER, STARTUP, MALEIC ANHYDRIDE REACTOR Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters) Primary Fuel: NATURAL GAS Throughput: 160.70 mmbtu/h

Process Notes: ALSO MAY COMBUST PROCESS GAS/LIQUID FUELS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0100 T/YR LESS THAN Standard Emission: 6.2200 E-5 MMBTU/H CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 2.2100 LB/H

Emission Limit 2: 0.7900 T/YR Standard Emission: 0.0140 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.2000 LB/H Emission Limit 2: 0.4300 T/YR Standard Emission: 0.0070 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.6400 LB/H Emission Limit 2: 0.2300 T/YR Standard Emission: 0.0040 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) PIPELINE QUALITY NATURAL GAS < 2.0 GR S PER 1000 DSCF Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H LESS THAN Emission Limit 2: 0.0100 T/YR LESS THAN Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) HEATER BURNS OFF GAS AS CONTROL Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE, BDO UNIT Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: NATURAL GAS Throughput:

Process Notes: FUEL IS NATURAL GAS AND WASTE GAS

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 4.1900 LB/H

Emission Limit 2: 11.8800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 15.0800 LB/H Emission Limit 2: 36.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 21.3500 LB/H Emission Limit 2: 60.5300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MATERIAL LOADING, THF, TRUCK AND RAIL Process Type: 64.005 (Transfer of SOCMI Chemicals (loading/unloading, filling, etc.)) Primary Fuel: Throughput:

Process Notes: THF TRUCK AND RAIL LOADING

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: 19.9200 LB/H

Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCRUBBER, 95% COLLECTION EFFICIENCY Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER, SCRUBBER OFF-GAS Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.1100 LB/H Emission Limit 2: 26.7700 T/YR Standard Emission: NOT AVAILABLE - SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LB/MMBTU RATE IS CONFIDENTIALPOLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 12.5100 LB/H Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BOILER CONTROLS SCRUBBER OFF-GAS, 99.9% DESTRUCTION. Est. % Efficiency: 99.900 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Oxides (SOx)

CAS Number: 7446 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 7.7500 LB/H Emission Limit 2: Standard Emission: SEE NOTE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: STANDARDIZED EMISSION LIMIT UNAVAILABLE.



## Facility Information

RBLC ID: 

## TX-0408 (final) Date Determination Last Updated: 11/18/2004Corporate/Company Name: INDIAN ROCK GATHERING COMPANY LP Permit Number: PSD-TX-1002

Facility Name: INDIAN ROCK GATHERING COMPANY LP Permit Date: 11/22/2002 (actual) Facility Contact: FRED WHITTED 7138218900 FRS Number: 110007203427 Facility Description: NATURAL GAS PROCESSING FACILITY SIC Code: 2819 Permit Type: C: Modify process at existing facility NAICS Code: 211112 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: UPSHUR Facility State: TX Facility ZIP Code: 75644 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: JOHNNY VERMILLION TX 512-239-1292 Permit Notes: PURPOSE OF THE PERMIT IS TO INCREASE THE PROCESSING OF THE GAS PLANT TO A MAXIMUM OF 80 MILLION CUBIC FEET PER DAY OF GAS, AND TO PRODUCE UP TO 20 LONG TONS PER DAY OF TOTAL SULFUR. PROJECT NO.: 77592, REG ENTITY ID: RN100209477 Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 9.6200 (Tons/Year) Nitrogen Oxides (NOx) 3.3500 (Tons/Year) Particulate Matter (PM) 6.6000 (Tons/Year) Sulfur Oxides (SOx) 135.4600 (Tons/Year) Volatile Organic Compounds (VOC) 4.4200 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: AUXILIARY BOILER, (2) Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 6.00 MMBTU/H

Process Notes: BOILERS ARE UNCONTROLLED BECAUSE BOILER DUTY IS

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.5000 LB/H EACH Emission Limit 2: 2.1600 T/YR EACH Standard Emission: 0.0830 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: UNCONTROLLED BECAUSE BOILER IS LESS THAN 40 MMBTU/H.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H EACH Emission Limit 2: 0.0200 T/YR EACH Standard Emission: 0.0017 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: UNCONTROLLED BECAUSE BOILER IS LESS THAN 40 MMBTU/H.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.5900 LB/H EACH Emission Limit 2: 2.5800 T/YR EACH Standard Emission: 0.0980 LB/MMBTUDid factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: UNCONTROLLED BECAUSE BOILER IS LESS THAN 40 MMBTU/H.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0500 LB/H EACH Emission Limit 2: 0.2000 T/YR EACH Standard Emission: 0.0083 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: UNCONTROLLED BECAUSE BOILER IS LESS THAN 40 MMBTU/H.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H EACH Emission Limit 2: 0.0500 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes: UNCONTROLLED BECAUSE BOILER IS LESS THAN 40 MMBTU/H.



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNIT Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput: 20.00 LT/D

Process Notes: TOTAL SULFUR PRODUCTION LIMITED TO 20 LONG TONS PER DAY (LT/D) BASED ON 98.5 SRU EFFICIENCY.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 1.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.5000 LB/H Emission Limit 2: 6.5700 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 61.8600 LB/H Emission Limit 2: 270.9200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZEREst. % Efficiency: 98.500

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Disulfide

CAS Number: 75-15-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.8500 LB/H Emission Limit 2: 12.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Carbonyl Sulfide

CAS Number: 463-58-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.1400 LB/H Emission Limit 2: 0.6300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: 98.500 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: IC ENGINE COMPRESSOR, (5) Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas))Primary Fuel: NATURAL GAS

Throughput: 800.00 HP

Process Notes: FIVE 800 HP INLET GAS COMPRESSOR ENGINES

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.1400 LB/H Emission Limit 2: 9.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT: 1.2 G/B-HP-H

POLLUTANT NAME: Formaldehyde

CAS Number: 50-00-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3400 LB/H Emission Limit 2: 1.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.0000 LB/H Emission Limit 2: 26.2700 T/YR Standard Emission: 3.0000 G/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 6.8800 LB/H

Emission Limit 2: 30.1300 T/YR Standard Emission: 2.0000 G/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3000 LB/H Emission Limit 2: 1.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE, LOW PRESSURE Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: NATURAL GAS Throughput:

Process Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.8200 LB/H Emission Limit 2: 2.3300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) 98% VOC DESTRUCTION OF FLARE MEETS 40 CFR 60.18. FLARE IS THE CONTROL. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSION RATES INCLUDE BENZENE, ETHYLBENZENE, N-HEAXANE, TOLUENE, AND XYLENE EMISSIONS



## Process/Pollutant Information

PROCESS NAME: FLARE, HIGH PRESSURE Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006)) Primary Fuel: NATURAL GAS Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.0800 LB/H Emission Limit 2: 4.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (A) 98% VOC DESTRUCTION OF FLARE MEETS 40 CFR 60.18. FLARE IS THE CONTROL.

Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: VOC EMISSION RATES INCLUDE BENZENE, ETHYLBENZENE, N-HEAXANE, TOLUENE, AND XYLENE EMISSIONS



## Facility Information

RBLC ID: 

## TX-0436 (final) Date Determination Last Updated: 12/30/2004 Corporate/Company Name: DEGUSSA ENGINEERED CARBONS INC. Permit Number: PSD-TX-416M1 Facility Name: BORGER CARBON BLACK PLANT Permit Date: 10/03/2002 (actual) Facility Contact: JIMMY BOYD FRS Number: 110000607068 Facility Description: LOCATED AT HWY. 136 & FM 1559, BORGER, TX. EXISTING CARBON BLACK PLANT. SIC Code: 2895

Permit Type: C: Modify process at existing facility NAICS Code: 325182 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: HUTCHINSON Facility State: TX Facility ZIP Code: 79008 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name) MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Permit Notes: PROJECT PROPOSES MODIFICATIONS TO INCREASE PRODUCTION AND CONTROL OF HAPS. ADDITIONAL PERMIT NO. : 8780, REGULATED ENTITY ID: RN100209659 Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide -5139.0000 (Tons/Year) Nitrogen Oxides (NOx) 523.0000 (Tons/Year) Particulate Matter (PM) -83.8000 (Tons/Year) Sulfur Oxides (SOx) 4820.0000 (Tons/Year) Volatile Organic Compounds (VOC) -70.0000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: DRYERS, BOILERS, FLARE Process Type: 19.600 (Misc. Boilers, Furnaces, Heaters)Primary Fuel: TAIL GAS

Throughput:

Process Notes: MULTIPLE SMALL SOURCES: WASTE HEAT BOILER, DRYERS, FLARE

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.1000 LB/MMBTU Emission Limit 2: Standard Emission: 0.1000 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES AND DESIGN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BAGHOUSES Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0100 GR/DSCF Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BAGHOUSES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CARBON BLACK MFG Process Type: 69.015 (Carbon Black Manufacturing) Primary Fuel: Throughput: 96.00 gal/min

Process Notes: THROUGHPUT IS PERMIT LIMIT FOR CARBON BLACK FEEDSTOCK OIL.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) REDUCTION OF CARBON BLACK FEEDSTOCK SULFUR LEVEL TO 2.8% TOTAL SULFUR CONTENT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT IS LOW SULFUR FEEDSTOCK.



## Facility InformationRBLC ID: 

## OK-0059 (final) Date Determination Last Updated: 10/28/2002 Corporate/Company Name: CONOCO INC Permit Number: 2001-194-C PSD Facility Name: PONCA CITY REFINERY Permit Date: 07/01/2002 (actual) Facility Contact: NICK SPENCER 580-767-5944 FRS Number: 110017414154 Facility Description: REFINERY SIC Code: 2911 Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110

Permit URL: EPA Region: 6 COUNTRY: USA Facility County: KAY Facility State: OK Facility ZIP Code: Permit Issued By: OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY (Agency Name) MR. JERRY GOOCHEY(Agency Contact) (405)702-4189 JERRY.GOOCHEY@DEQ.OK.GOV Other Agency Contact Info: PHILLIP FIELDER PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 405-702-4203 Permit Notes: Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 OK Wichita Mountains 100km - 50km Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 308.2900 (Tons/Year) Nitrogen Oxides (NOx) 154.6100 (Tons/Year) Particulate Matter (PM) 28.4000 (Tons/Year) Sulfur Oxides (SOx) 132.8200 (Tons/Year) Volatile Organic Compounds (VOC) 237.3400 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: HYDROGENATION/NAPHTHA SPLITTER Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: REFINERY GAS Throughput: 149.00 MMBTU/H

Process Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0350 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW-NOX BURNER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0824 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: UnspecifiedPollutant Group(s): ( Particulate Matter (PM) )

Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE AND GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0054 LB/MMBTU Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) REFINERY FUEL GAS H2S LIMIT OF 0.10 GR/DSCF NO SO2 LIMIT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER Process Type: 11.900 (Other Fuels and Combinations (>250 million BTU/H)(e.g., solid/liquid, liquid/gas)) Primary Fuel: REFINERY GAS Throughput: 483.20 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0824 LB/MMBTU Emission Limit 2: Standard Emission: 0.0824 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 0.0350 LB/MMBTU Emission Limit 2: Standard Emission: 0.0350 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA-LOW NOX BURNER (ULBN) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: Emission Limit 2: Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) USE OF REFINERY FUEL GAS H2S LIMIT OF 0.10 GRAINS/DSCF. NO SO2 EMISSION LIMIT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission: 0.0075 LB/MMBTUDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE AND GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0054 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDRODESULFURIZATION UNIT Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: REFINERY GAS Throughput: 44.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) REFINERY FUEL GAS H2S LIMIT OF 0.10 GRAINS/DSCF NO SO2 EMISSION LIMIT Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0054 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES AND GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0350 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW-NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0824 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICESEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ISOMERIZATION UNIT Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: REFINERY GAS Throughput: 33.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES AND GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0350 LB/MMBTU Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW-NOX BURNER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0824 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0054 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICEEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) REFINERY FUEL GAS H2S LIMIT OF 0.10 GRAINS/DSCF NO SO2 EMISSION LIMIT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HYDROGEN PLANT Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput: 90.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0350 LB/MMBTU Emission Limit 2: Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA-LOW NOX BURNER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) PIPELINE QUALITY NATURAL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0824 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICEEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0075 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE AND GASEOUS FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0054 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: NATURAL GAS Throughput: 0.20 LB/MMBTU

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0680 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LIMIT FUEL TO PIPELINE GRADE NATURAL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: SMOKELESS OPERATION Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SMOKELESS FLAREEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0006 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) USE OF PIPELINE QUALITY NATURAL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1400 LB/MMBTU Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: COOLING TOWER Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATORSEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TANKS Process Type: 42.006 (Petroleum Liquid Storage in Floating Roof Tanks) Primary Fuel: Throughput: VARIES

Process Notes: All tanks subject ot refinery MACT

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: REFINERY MACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) REFINERY MACT REQUIRES CERTAIN CONTROL DEVICES WHICH ARE INSTALLED ON THE STORAGE TANKS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVE COMPONENTS/EQUIPMENT LEAKS Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:Throughput:

Process Notes: All equipment leaks subject to refinery MACT standards

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: REFINERY MACT Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) REFINERY MACT REQUIRES INSPECTION AND MAINTENANCE OF PUMP SEALS, VALVES, FLANGES, AND PIPES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0235 (final) Date Determination Last Updated: 08/25/2006 Corporate/Company Name: VALERO REFINING COMPANY- CORPUS CHRISTI REFINERY Permit Number: 38754

Facility Name: VALERO REFINING COMPANY- CORPUS CHRISTI REFINERY Permit Date: 06/11/2002 (actual) Facility Contact: GEORGE E KAIN 3612896000 FRS Number: 110000465103 Facility Description: MODIFICATIONS OF EXISTING REFINERY INCLUDING INCREASING THE CAPACITY OF THE

CATALYTIC REFORMING UNIT, INCREASING THE HEAVY OIL CRACKING (HOC) THROUGHPUT, INCREASING THROUGHPUTS AT THE HYDRODESULFURIZATION (HDS) UNIT AND HDS DESALTER UNIT, INCREASING ALKY UNIT PRODUCTION, REVAMPING THE MTBE/TAME DEPENETANIZER SYSTEM TO INCREASE CAPACITY, AND OTHER CONSTRUCTION ACTIVITIES INCREASING FUGITIVE EMISSIONS. FLEXIBLE PERMIT TO COVER EXISTING PERMITTED AND EXEMPTED FACILITIES AT THE REFINERY UNDER PERMITS 2041A, 7147, 19819, 8373, 21601, AND EXEMPTIONS, 30282, 30281, 31514, 32045. SIC Code: 2911Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 320000

Permit URL: EPA Region: 6 COUNTRY: USA Facility County: NUECES Facility State: TX Facility ZIP Code: 78469 Permit Issued By: TEXAS, OTHER (Agency Name) Other Agency Contact Info: ANGEL TOMASINO

TEXAS NATURAL RESOURCE CONSERVATION COMMISSION, PO BOX 13087 AUSTIN, TX 78711 512-239-1300 Permit Notes: AGENCY CONTACT: KURT KIND, CHEMICAL AND COATINGS SECTION, AIR PERMITS, PH: 512-239-1337 DIVISION, TEXAS

NATURAL RESOURCE CONSERVATION COMMISSION REFINERY



## Process/Pollutant Information

PROCESS NAME: FIRED UNITS

Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.))

Primary Fuel: Throughput:

Process Notes: FIRED UNITS INCLUDE: CRUDE HEATER, VACUUM UNIT HEATER, DESALTER HEATER, HDS CHARGE HEATERS, HDS HEAVY OIL

PREHEATER, ALKY FRACT REBOILER, HYDROGEN REFORMER HEATER, SULFTEN HEATER, BUTAMER HEATER, CRUDE PREFLASH HEATER, CRUDE STABILIZER HEATER, HCU HEATER, NHT HEATER, CRU HEATERS, BOILER 30-B-02, OLEFLEX HEATERS, RSU HEATER, SPLITTER REBOILER, 49HO2, 49H05, 49HDIC6, VACUUM PF HEATER, MTBE FLARE, API SEPARATOR COMBUSTOR, TRUCK LOADING COMBUSTOR. THE API SEPARATOR COMBUSTOR SHALL ACHIEVE AT LEAST 98 PERCENT DESTRUCTION EFFICIENCY. THE VAPOR COMBUSTOR COMBUSTION TEMPERATURE SHALL BE MAINTAINED AT OR ABOVE 1600 DEGREES F (BASED ON A FIVE-MINUTE AVERAGING PERIOD) WHEN THE SEPARATOR IS IN SERVICE. THIS TEMPERATURE SHALL BE RECORDED AND THE RECORDS MAINTAINED ON-SITE. THE VAPOR COMBUSTOR OPERATING TEMPERATURE MAY BE LOWERED IF IT HAS BEEN TESTED AT THE LOWER TEMPERATURE IN ACCORDANCE WITH SPECIAL CONDITION TO DEMONSTRATE COMPLIANCE WITH THIS EMISSION LIMIT. RECORDKEEPING ASSOCIATED WITH THIS PERMIT CONDITION SHALL COMMENCE ON APRIL 1, 1999. NO VISIBLE EMISSIONS ARE ALLOWED FROM THE HEATERS. AIR CONTAMINANTS FROM THE HEATERS AND BOILERS TO BE TESTED FOR INCLUDE (BUT ARE NOT LIMITED TO) NITROGEN OXIDE AND CARBON MONOXIDE. SEE SPECIFICATIONS FOR NOX AND CO EMISSIONS FOR INDIVIDUAL HEATERS AS WELL. MUST REPORT UNDER 30 TAC SECTIONS 101.6 OR 101.7 ANY TIME THE SRU, SULFTEN, OR TAIL GAS INCINERATOR IS NOT OPERATING PROPERLY. UPON REQUEST BY THE EXECUTIVE DIRECTOR OF THE TNRCC, THE EPA, OR ANY LOCAL AIR POLLUTION CONTROL PROGRAM HAVING JURISDICTION, THE HOLDER OF THE PERMITSHALL PROVIDE A SAMPLE AND/OR ANALYSIS OF THE FUEL(S) UTILIZED IN THE FACILITIES OR SHALL ALLOW AIR POLLUTION CONTROL AGENCY REPRESENTATIVES TO OBTAIN A SAMPLE FOR ANALYSIS.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1190.0000 LB/H Emission Limit 2: 5053.0000 T/YR Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 883.0000 LB/H Emission Limit 2: 3717.0000 T/YR Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 474.0000 LB/H Emission Limit 2: 1925.0000 T/YR Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4013.0000 LB/H Emission Limit 2: 1544.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 223.3000 LB/H Emission Limit 2: 966.6000 T/YRStandard Emission: NOT AVAILABLE

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 26.0000 LB/H Emission Limit 2: 11.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CRU HEATER Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/MMBTU Emission Limit 2: Standard Emission: 0.0700 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/MMBTU Emission Limit 2: Standard Emission: 0.0300 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CRU CRR Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel:Throughput:

Process Notes:

POLLUTANT NAME: Hydrochloric Acid

CAS Number: 7647-01-0 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0700 LB/H Emission Limit 2: 0.2900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CU/VRU COOLING TOWER

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))

Primary Fuel: Throughput:

Process Notes: THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING

SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY, BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS. THE RECORDS SHALL BE MADE AVAILABLE TO THE TNRCC EXECUTIVE DIRECTOR UPON REQUEST.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2100 LB/H Emission Limit 2: 0.9200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SEE PROCESS/COMPLIANCE NOTES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: MARINE LOADING (BARGE AND SHIP)

Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading))

Primary Fuel: Throughput: 35000.00 BBL/H

Process Notes: MARINE LOADING WITH EMISSIONS THAT ARE CONTROLLED WITH THE MARINE VAPOR RECOVERY UNIT (VRU) SHALL BE

LIMITED TO A MAX OF 35000 BBL/H. 1) THE LIQUIDS THAT ARE LOADED AT THIS RATE, AND CONTROLLED WITH THE VRU AT THIS FACILITY ARE LIMITED TO MTBE, GASOLINE, NATURAL GASOLINE, NAPHTHA, CAT GASOLINE, ALKYLATE, AND REFORMATE. THE BT CONCENTRATE, MIXED XYLENES, HEARTCUT, AND TOLUENE CONCENTRATE MAY ALSO BE LOADED INTO MARINE VESSELS WITH EMISSIONS CONTROLLED BY THE VRU, AT A RATE NOT TO EXCEED 5000 BBL/H. ONLY ONE OF THESE PRODUCTS MAY BE LOADED AT A TIME. 2) MARINE LOADING WITH UNCONTROLLED VAPOR EMISSIONS SHALL BE LIMITED TO THE FOLLOWING SERVICES AT THE INDICATED RATES UNLESS ALLOWED BY SPECIAL CONDITION: DIESEL, 8500 BBL/H; KEROSENE, 5000 BBL/H; GAS OIL, 6000 BBL/H; ATB, 6000 BBL/H; VTB, 6000 BBL/H; SLURRY, 6000 BBL/H; BUNKER, 6000 BBL/H. 3) DIESEL AND KEROSENE SHALL NOT BE LOADED ONTO SHIPS AND BARGES CONCURRENTLY. 4) ALL MARINE LOADING EMISSIONS OF LIQUIDS WITH VAPOR PRESSURES GREATER THAN 0.5 PSIA MUST BE VENTED TO THE VRU IF THE VESSEL BEING LOADED HAS THE APPROPRIATE CONNECTIONS TO THE VRU. UNCONTROLLED LOADING IS LIMITED TO GASOLINE, NATURAL GASOLINE, CAT CASOLINE, ALKYLATE, AND REFORMATE. UNCONTROLLED MARINE LOADING RATES FOR THESE LIQUIDS IS LIMITED TO A MAX OF 20000 BBL/H TO SHIPS AND 8000 BBL/H TO BARGES. 5) A VACUUM OF AT LEAST ONE-INCH WATER COLUMN SHALL BE ESTABLISHED DOWNSTREAM OF THE DOCK PRESSURE CONTROL VALVE PRIOR TO COMMENCING MARINE LOADING. A VACUUM SHALL ALSO BE ESTABLISHED ON THE BARGE OR SHIP BEING LOADED IF POSSIBLE. THE VACUUM SHALL BE MAINTAINED AND MONITORED CONTINUALLY, OR AN ALARM ACTIVATED IF THE VACUUM IS NOT MAINTAINED. IF THE VACUUM IS NOTMONITORED CONTINUALLY, OR AN ALARM ACTIVATED IF THE VACUUM IS NOT MAINTAINED. IF THE VACUUM IS NOT MAINTAINED, LOADING SHALL BE SECURED AND THE CAUSE OF THE LOW VACUUM DETERMINED AND REPAIRED.

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 14.1000 LB/H Emission Limit 2: 7.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE ANNUAL EMISSIONS OF BENZENE FROM THE LOADING OF GASOLINE PRODUCTS SHALL NOT EXCEED 3.6 TONS. UNCONTROLLED MARINE LOADING RATES IS LIMITED TO A MAX OF 20000 BBL/H TO SHIPS AND 8000 BBL/H TO BARGES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1655.0000 LB/H Emission Limit 2: 1142.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) SEE POLLUTANT NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE MARINE VRU SHALL LIMIT VOC EMISSIONS FROM EPN VRU TO 5 MG/L OF LIQUIDPollutant/Compliance Notes: THE MARINE VRU SHALL LIMIT VOC EMISSIONS FROM EPN VRU TO 5 MG/L OF LIQUID LOADED. THE VRU VOC CONCENTRATION AS MEASURED BY THE CEM SALL NOT EXCEED 7621 PPM OVER ANY 1HR PERIOD WHILE THE MARINE LOADING EMISSIONS ARE VENTED.



## Process/Pollutant Information

PROCESS NAME: MAIN FLARE

Process Type: 19.330 (Refinery Flares)

Primary Fuel: Throughput:

Process Notes: FLARES SHALL BE DESIGNED AND OPERATED IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING SPECIFICATIONS OF MINIMUM

HEATING VALUE OF THE WASTE GAS, MAXIMUM TIP VELOCITY, AND PILOT FLAME MONITORING. IF NECESSARY TO INSURE ADEQUATE COMBUSTION, SUFFICIENT FUEL GAS SHALL BE ADDED TO MAKE THE GASES COMBUSTIBLE. AN INFRARED MONITOR IS CONSIDERED EQUIVALENT TO A THERMOCOUPLE FOR FLAME MONITORING PURPOSES. EXCEPT AS PROVIDED FOR BY THIS PERMIT, ALL WASTE GAS FROM POINT SOURCES CONTAINING VOC AND/OR OTHER ORGANIC COMPOUNDS (HYDROCARBONS AND/OR HYDROCARBON DERIVATIVES EXCLUDING CARBON DIOXIDE [CO2]) SHALL BE ROUTED TO A FLARE. THE FLARE SHALL OPERATE WITH NO LESS THAN 98 % EFFICIENCY IN DISPOSING OFTHE CARBON COMPOUNDS CAPTURED BY THE COLLECTION SYSTEM. THE WASTE GAS STREAMS SHALL INCLUDE PROCESS VENTS, RELIEF VALVES NOT IN VACUUM SERVICE, ANALYZER VENTS, STEAM JET EXHAUSTS, UPSET EMISSIONS, START-UP AND SHUTDOWN-RELATED EMISSIONS OR PURGES, BLOWDOWNS, OR OTHER SYSTEM EMISSIONS OF WASTE GAS. STORAGE TANK VENTS, COOLING TOWER EXHAUST, AND PROCESS FUGITIVE EMISSIONS ARE EXCLUDED FROM THIS REQUIREMENT. ANY OTHER EXCEPTION TO THIS CONDITION REQUIRES PRIOR REVIEW AND APPROVAL BY THE TNRCC EXECUTIVE DIRECTOR, AND SUCH EXCEPTIONS MAY BE SUBJECT TO STRICT MONITORING REQUIREMENTS.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 75.8000 LB/H Emission Limit 2: 18.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 51.1000 LB/H Emission Limit 2: 12.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 26.0000 LB/H Emission Limit 2: 11.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 472.0000 LB/H Emission Limit 2: 90.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS HOC COOLING TOWERPROCESS

NAME: HOC COOLING TOWER

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))

Primary Fuel: Throughput:

Process Notes: THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING

SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY, BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS. THE RECORDS SHALL BE MADE AVAILABLE TO THE TNRCC EXECUTIVE DIRECTOR UPON REQUEST.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 6.0900 LB/H Emission Limit 2: 26.6700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SEE PROCESS/COMPLIANCE NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ALKY COOLING TOWER

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))

PrimaryPrimary

Fuel: Throughput:

Process Notes: THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING

SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY, BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS. THE RECORDS SHALL BE MADE AVAILABLE TO THE TNRCC EXECUTIVE DIRECTOR UPON REQUEST.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.2600 LB/H Emission Limit 2: 5.5200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) MONITORING AND LDAR PROGRAM. SEE PROCESS NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY, BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS. THE RECORDS SHALL BE MADE AVAILABLE TO THE TNRCC EXECUTIVE DIRECTOR UPON REQUEST.



## Process/Pollutant Information

PROCESS NAME: BUP COOLING TOWER

Process 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))Process

Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing))

Primary Fuel: Throughput:

Process Notes: THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING

SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY, BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS. THE RECORDS SHALL BE MADE AVAILABLE TO THE TNRCC EXECUTIVE DIRECTOR UPON REQUEST.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6800 LB/H See Notes Emission Limit 2: 7.3600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SEE PROCESS/COMPLIANCE NOTES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THE VOC ASSOCIATED WITH COOLING TOWER WATER SHALL BE MONITORED MONTHLY WITH AN APPROVED AIR STRIPPING SYSTEM OR EQUIVALENT. THE APPROPRIATE EQUIPMENT SHALL BE MAINTAINED SO AS TO MINIMIZE FUGITIVE VOC EMISSIONS FROM THE COOLING TOWER. FAULTY EQUIPMENT SHALL BE REPAIRED AT THE EARLIEST OPPORTUNITY, BUT NO LATER THAN THE NEXT SCHEDULED SHUTDOWN OF THE PROCESS UNIT IN WHICH THE LEAK OCCURS. THE RESULTS OF THE MONITORING AND MAINTENANCE EFFORTS SHALL BE RECORDED, AND SUCH RECORDS SHALL BE MAINTAINED FOR A PERIOD OF TWO YEARS. THE RECORDS SHALL BE MADE AVAILABLE TO THE TNRCC EXECUTIVE DIRECTOR UPON REQUEST.



## Process/Pollutant Information

PROCESS ACID GAS FLARE EMERGENCY USE ONLYPROCESS

NAME: ACID GAS FLARE EMERGENCY USE ONLY

Process Type: 19.330 (Refinery Flares)

Primary Fuel: Throughput:

Process Notes: FLARES SHALL BE DESIGNED AND OPERATED IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING SPECIFICATIONS OF MINIMUM

HEATING VALUE OF THE WASTE GAS, MAX TIP VELOCITY, AND PILOT FLAME MONITORING. IF NECESSARY TO INSURE ADEQUATE COMBUSTION, SUFFICIENT FUEL GAS SHALL BE ADDED TO MAKE THE GASES COMBUSTIBLE. AN INFRARED MONITOR IS CONSIDERED EQUIVALENT TO A THERMOCOUPLE FOR FLAME MONITORING PURPOSES. EXCEPT AS MAY BE PROVIDED FOR IN THIS PERMIT, ALL WASTE GAS FROM POINT SOURCES CONTAINING VOC AND/OR OTHER ORGANIC COMPOUNDS (HYDROCARBONS AND/OR HYDROCARBON DERIVATIVES EXCLUDING CARBON DIOXIDE) SHALL BE ROUTED TO A FLARE. THE FLARE SHALL OPERATE WITH NO LESS THAN 98 PERCENT EFFICIENCY IN DISPOSING OF THE CARBON COMPOUNDS CAPTURED BY THE COLLECTION SYSTEM. THE WASTE GAS STREAMS SHALL INCLUDE PROCESS VENTS, RELIEF VALVES NOT IN VACUUM SERVICE, ANALYZER VENTS, STEAM JET EXHAUSTS, UPSET EMISSIONS, START- UP AND SHUTDOWN-RELATED EMISSIONS OR PURGES, BLOWD0WNS, OR OTHER SYSTEM EMISSIONS OF WASTE GAS. STORAGE TANK VENTS, COOLING TOWER EXHAUST, AND PROCESS FUGITIVE EMISSIONS ARE EXCLUDED FROM THIS REQUIREMENT. ANY OTHER EXCEPTION TO THIS CONDITION REQUIRES PRIOR REVIEW AND APPROVAL BY THE TNRCC EXECUTIVE DIRECTOR, AND SUCH EXCEPTIONS MAY BE SUBJECT TO STRICT

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: see notes Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: NO EMISSIONS OR LIMITS GIVEN IN PERMIT



## Process/Pollutant InformationPROCESS

NAME: FACILITIES VENTED TO MAIN FLARE- GROUP ONE

Process Type: 19.330 (Refinery Flares)

Primary Fuel: Throughput:

Process Notes: 126 REFORMER PRESSURE SWING ABSORBER, CATALYTIC REFORMER UNIT FUEL GAS DRUM NO.2, CRUDE PREFLASH OH

ACCUMULATOR, STABILIZER OH ACCUMULATOR, CRUDE TOWER OH ACCUMULATOR, AND PURGE GAS VENTED TO THE MAIN FLARE. FLARES SHALL BE DESIGNED AND OPERATED IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING SPECIFICATIONS OF MINIMUM HEATNG VALUE OF THE WASTE GAS, MAXIMUM TIP VELOCITY, AND PILOT FLAME MONITORING. IF NECESSARY TO INSURE ADEQUATE COMBUSTION, SUFFICIENT FUEL GAS SHALL BE ADDED TO MAKE THE GASES COMBUSTIBLE. AN INFRARED MONITOR IS COSIDERED EQUIVALENT TO A THERMOCOUPLE FOR FLAME MONITORING PURPOSES.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 226.0000 LB/H Emission Limit 2: 39.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE. SEE POLLUTANT NOTES. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes: EXCEPT AS PROVIDED FOR IN THE PERMIT, ALL WASTE GAS FROM POINT SOURCES CONTAINING VOC SHALL BE ROUTED TO A FLARE. THE FLARE SHALL OPERATE IN NO LESS THAN 98% EFFICIENCY IN DISPOSING OF THE C COMPOUNDS CAPTURED BY THE COLLECT



## Process/Pollutant Information

PROCESS NAME: FACILITIES VENTING TO MAIN FLARE- GROUP TWO

Process Type: 19.330 (Refinery Flares)Primary Fuel:

Throughput:

Process Notes: FACILITIES VENTING TO MAIN FLARE NOT COVERED IN GROUP ONE. FLARES SHALL BE DESIGNED AND OPERATED IN

ACCORDANCE WITH 40 CFR 60.18 INCLUDING SPECIFICATIONS OF MINIMUM HEATING VALUE OF THE WASTE GAS, MAXIMUM TIP VELOCITY, AND PILOT FLAME MONITORING. IF NECESSARY TO INSURE ADEQUATE COMBUSTION, SUFFICIENT FUEL GAS SHALL BE ADDED TO MAKE THE GASES COMBUSTIBLE. AN INFRARED MONITOR IS CONSIDERED EQUIVALENT TO A THERMOCOUPLE FOR FLAME MONITORING PURPOSES.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4013.0000 LB/H Emission Limit 2: 1544.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE. SEE POLLUTANT NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EXCEPT AS PROVIDED FOR IN THIS PERMIT, ALL WASTE GAS FROM PONT SOURCES CONTAING VOC SHALL BE ROUTED TO A FLARE. THE FLARE SHALL OPERATE W/NO LESS THAN 98% EFFICIENCY IN DISPOSING OF THE C COMPNDS CAPTURED BY COLLECTION SYSTEM



## Process/Pollutant Information

PROCESS NAME: ANALYZER VENTS AE-49601 A/B, 49900 A/B, 49901 A/B Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: EXEMPT FROM SPECIAL REQUIREMENT FOR CARBON COMPOUND WASTE GAS STREAMS.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0100 LB/H (LESS THAN) Emission Limit 2: 0.0100 T/YR (LESS THAN) Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) SEE PROCESS NOTES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EXEMPT FROM SPECIAL REQUIREMENT FOR CARBON COMPOUND WASTE GAS STREAMS.



## Process/Pollutant Information

PROCESS NAME: SCRUBBER/SRU INCINERATOR

Process Type: 50.008 (Petroleum Refining Flares and Incinerators (except acid gas/SRU incinerators - 50.006))

Primary Fuel: Throughput:

Process Notes: THE HOLDER OF THE PERMIT SHALL REPORT UNDER 30 TAC SECTIONS 101.6 OR 101.7 ANYTIME THE SRU IS NOT OPERATING

PROPERLY. IF THE SRU TRAIN IS NOT OPERATING PROPERLY, THE ACID GAS FEED STREAM MAY BE ROUTED TO AN EMERGENCY FLARE FOR A PERIOD NOT TO EXCEED 12HRS. IF THE SULFTEN UNIT IS NOT OPERATING PROPERLY, SRU TAIL GAS SHALL BE INCINERATED, THEN ROUTED TO THE HOC FLUE GAS SCRUBBER UNLESS THE SCRUBBER STACK IS OUT OF SERVICE, IN WHICH CASE SRU TAIL GAS WILL BE ROUTED TO THE FLARE. THE INOPERABLE EQUIPMENT SHALL BE REPAIRED AND RESTORED TO SERVICE AS SOON AS POSSIBLE. THE PH OF THE HOC SCRUBBER CIRCULATING CAUSTIC SOLUTION SHALL BE CONTINUALLY MONITORED AND BE MAINTAINED AT A LEVEL BETWEEN 6.0 AND 9.0 BY THE ADDITITON OF FRESH CAUSTIC SOLUTION AS REQUIRED. THE PH SHALL BE RECORDED AT LEAST HOURLY, AND THE RECORDS MAINTAINED AT THE PLANT SITE FOR A PERIOD OF TWO YEARS. THESE RECORDS SHALL BE MADE AVAILABLE FOR INSPECTION BY THE EXECUTIVE DIRECTOR OF THE TNRCC OR HIS DESIGNATED REPRESENTATIVE.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 474.0000 LB/H

Emission Limit 2: 1925.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SULFUR RECOVERY EFFICIENCY DETERMINED BY CALCULATION, EFFICIENCY= (S RECOVERED) * (100) (S ACID GAS) (SEE PERMIT FOR EXPLANATION). COMPLIANCE TESTING. INSTALL, CALIBRATE, & MAINTAIN A CEMS FOR SO2 EXHAUSTED TO SRU. Est. % Efficiency: 99.800 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 222.3000 LB/H Emission Limit 2: 966.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THE COKE BURN-OFF PM EMISSIONS MAY NOT EXCEED 0.57 LB/1000 LBS COKE BURN-OFF. COMPLIANCE TESTING. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1190.0000 LB/H Emission Limit 2: 5053.0000 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) COMPLIANCE TESTING. INSTALL, CALIBRATE, AND MAINTAIN A CEMS TO MEASURE THE EXHAUST FROM CAUSTIC SCRUBBER TO SRU. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) COMPLIANCE TESTING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 9.4000 LB/H Emission Limit 2: 40.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) THE MINIMUM SULFUR RECOVERY FOR THE SRU SHALL BE 99.8%. EFFICIENCY SHALL BE CALCULATED BY: EFFICIENCY = S(RECOVERED*100)/(S ACID GAS). SEE PERMIT FOR EXPLANATION. COMPLIANCE TESTING. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) MAINTAIN LIQUID TO FILTERING MODULES AT PRESSURE GREATER THAN 45LBS PSI AND FLUE GAS PRESURE DROP ACROSS FILTERING MODULES & CYCLOLABS AT NO LESS THAN 5 IN. OF WATER. MAINTAIN/RECORD LIQUID PRESSURE/DROP FOR 2 YEARS. Est. % Efficiency: 20.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 883.0000 LB/H Emission Limit 2: 3717.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N) INSTALL, CALIBRATE, MAINTAIN A CEMS TO MEASURE AND RECORD THE IN-STACK CONCENTRATION OF NOX FROM THE CAUSTIC SCRUBBER AND SRU. MUST MEET REQUIREMENTS FOR CEMS IN PERMIT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 26.0000 LB/H Emission Limit 2: 11.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) COMPLIANCE TESTING. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur / Sulfates

CAS Number: 7704-34-9 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) ) Emission Limit 1: 58.3000 LB/H SULFATES Emission Limit 2: 256.0000 T/YR SULFATES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THE MIN S RECOVERY EFFICIENCY FOR THE SRU SHALL BE 99.8%. CALCULATED ASControl Method: (A) THE MIN S RECOVERY EFFICIENCY FOR THE SRU SHALL BE 99.8%. CALCULATED AS FOLLOWS: EFFICIENCY=(S RECOVERED) * 100* (S ACID GAS), SEE PERMIT FOR EXPLANATION. COMPLIANCE TESTING. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: LIMITS ARE FOR SULFATES.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4013.0000 LB/H Emission Limit 2: 1544.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: FUGITIVE EMISSION POINTS INCLUDE CRUDE UNIT, VACUUM UNIT, LEU, DESALTER UNIT, HDS UNIT, SMR, HRLEU UNIT, LRU,

HOC UNIT, BO2F, 30-B-02, 30-B-03, HF ALKYLATION UNIT, BUTAMER UNIT, MTBE, OLEFLEX, SULF/SEU/SRU, HCU, PSA, HNT, CRU, MTBE/TAME UNIT, POWERHOUSE, 49-RSU/XFU, DOCKS, FUEL GAS DRUM, GAS BLENDING, LPG STORAGE, MVRU, TERMINALS, TRUCK RACK. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED AS A MAXIMUM ALLOWABLE EMISSION RATE. EXTENSIVE SPECIAL CONDITIONS FOR MAINTENANCE AND OPERATION OF FUGITIVE EMISSIONS CONTROL ANDEQUIPMENT, SEE PERMIT.

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 14.1000 LB/H Emission Limit 2: 7.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) EMISSION LIMITS ARE ESTIMATES, NOT MAXIMUM ALLOWABLE RATES. SEE PERMIT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) EMISSIONS ARE ESTIMATES AND NOT MAXIMUM ALLOWABLE RATES. SEE PERMIT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1655.0000 LB/H Emission Limit 2: 1142.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) EMISSIONS ARE ESTIMATES, NOT MAXIMUM ALLOWABLE RATES. SPECIAL CONDITIONS APPLY FOR MAINTENANCE AND COMPLIANCE OF EQUIPMENT RELATED TO FUGITIVE EMISSIONS OF VOC, SEE PERMIT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: GROUND FLARE

Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: FLARES SHALL BE DESIGNED AND OPERATED IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING SPECIFICATIONS OF MINIMUM

HEATING VALUE OF THE WASTE GAS, MAXIMUM TIP VELOCITY, AND PILOT FLAME MONITORING. IF NECESSARY TO INSURE ADEQUATE COMBUSTION, SUFFICIENT FUEL GAS SHALL BE ADDED TO MAKE THE GASES COMBUSTIBLE. AN INFRARED MONITOR IS CONSIDERED EQUIVALENT TO A THERMOCOUPLE FOR FLAME MONITORING PURPOSES.

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 14.1000 LB/H Emission Limit 2: 7.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 51.1000 LB/H Emission Limit 2: 12.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 75.8000 LB/H Emission Limit 2: 18.8000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 472.0000 LB/H Emission Limit 2: 90.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 226.0000 LB/H Emission Limit 2: 39.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) TOTAL VOC VENTED TO GROUND FLARE FROM SPECIFIED FACILITIES (SEE PERMIT), SHALL NOT EXCEED 39.6 T/YR ON POST-CONTROL BASIS. IF THE WASTE STREAMS FROM SPECIFIED FACILITES ARE VENTED TO A FLARE, MUST MONITOR, SAMPLE/PER QUARTE Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: OLEFLEX SCRUBBER

Process Type: 50.999 (Other Petroleum/Natural Gas Production & Refining Sources (except 42 - Liquid Marketing)) Primary Fuel: Throughput:

Process Notes: THE OLEFLEX AND CONTINUOUS CATALYST REGENERATOR SCRUBBER LIQUIDS SHALL BE SAMPLED AT LEAST DAILY FOR

CAUSTIC INVENTORY. THE CAUSTIC CONCENTRATIONS SHALL BE MAINTAINED GREATER THAN THAT REPRESENTED IN THE CONFIDENTIAL PORTION OF THE PERMIT AMENDMENT APPLICATION DATED JULY 15, 1994.

POLLUTANT NAME: Chlorine / Chlorine Compounds

CAS Number: 7782-50-5 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) ) Emission Limit 1: 0.0100 LB/H CHLORINE GAS Emission Limit 2: 0.0400 T/YR CHLORINE GAS Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: U

Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0100 LB/H (LESS THAN) Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Hydrochloric Acid

CAS Number: 7647-01-0 Test Method: Unspecified Pollutant Group(s): ( Acid Gasses/Mist , Hazardous Air Pollutants (HAP) , InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: Control Method: (N)Est. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TANKS

Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading))

Primary Fuel: GASOLINE

Throughput: 60000.00 GAL/H

Process Notes: 1) THE TOTAL TRANSFER RATE OF RESID, BUNKER, ATMOSPHERIC TOWER BOTTOMS, VACUUM TOWER BOTTOMS, SLURRY,

HYDRODESULFURIZATION (HDS) FEED, HEAVY OIL CRACKING (HOC) FEED, VACUUM FEED, AND GAS OIL TO AND FROM TANKS AT THIS SITE SHALL NOT EXCEED 91000 BBL/H. THE TOTAL TRANSFER RATE OF GAS OIL TO AND FROM TANKS SHALL NOT EXCEED 26000BBL/H. 2) MAX OF EIGHT TANKS ON THE SITE MAY BE IN NAPHTHA SERVICE AT ANY TIME. THE TOTAL SITEWIDE NAPHTHA TRANSFER RATE SHALL NOT EXCEED 10000 BBL/H FOR ANY TANK OR A TOTAL OF 13150 BBL/H FOR ALL TANKS IN NAPHTHA SERVICE. 3) A MAXIMUM OF 11 TANKS MAY BE IN CRUDE OIL SERVICE AT ANY TIME. THE TOTAL SITEWIDE CRUDE OIL TRANSFER RATE SHALL NOT EXCEED A TOTAL OF 81000 BBL/H FOR ALL TANKS IN CRUDE OIL SERVICE. 4) A MAX OF 6 TANKS MAY BE IN DIESEL SERVICE AT ANY TIME. THE TOTAL SITEWIDE DIESEL TRANSFER RATE SHALL NOT EXCEED 12500 BBL/H FOR ANY TANK OR A TOTAL OF 17000 BBL/H FOR ALL TANKS IN DIESEL SERVICE. 5) TANK TRUCK LOADING OPERATIONS ARE LIMITED TO THE FOLLOWING LIQUIDS AND MAX LOADING RATES: KEROSENE (30000 GAL/H), DIESEL (30,000 GAL/H), GASOLINE (60,000 GAL/H) 6) OPERATION WITHOUT VISIBLE LIQUID LEAKS OR SPILLS SHALL BE MAINTAINED AT ALL LOADING/UNLOADING FACILITES. THIS DOES NOT APPLY TO MOMENTARY DRIPPING ASSOCIATED WITH THE INITIAL CONNECTION OR DISCONNECTION OF FITTINGS. 7) EMISSIONS RESULTING FROM THE TANK TRUCK LOADING OF GASOLINE SHALL BE ROUTED TO THE VAPOR COMBUSTOR 8) ALL TANK TRUCKS LOADING GASOLINE SHALL BE LEAK-TIGHT TESTED A MIN OF 1/YR 9) ALL TANK TRUCK LOADING OF KEROSENE AND DIESEL SHALL BE CONDUCTED USING SUBMERGED LOADING PROCEDURES 10) AN INTERNAL FLOATING ROOF OR EQUIVALENT CONTROL SHALL BE INSTALLED ON ALL TANKS. 11) UNINSULATED TANK EXTERIOR SURFACES EXPOSED TO THE SUN SHALL BE WHITE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) CONTINUOUS MONITORING WITH 1 H AVERAGING PERIOD. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 4013.0000 LB/H Emission Limit 2: 1544.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) INTERNAL FLOATING ROOF, MONTHLY EMISSIONS RECORD Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 26.0000 LB/H Emission Limit 2: 11.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## TX-0375 (final) Date Determination Last Updated: 01/03/2005 Corporate/Company Name: LYONDELL - CITGO REFINING, LP Permit Number: PSD-TX-985

Facility Name: LYONDELL - CITGO REFINING, LP Permit Date: 03/14/2002 (estimated) Facility Contact: FRS Number: 110015737210 Facility Description: LYONDELL-CITGO PROPOSES TO CONSTRUCT NEW FACILITIES AND MODIFY EXISTING

FACILITIES TO IMPLEMENT THEIR CLEAN AIR PROJECT, ENABLING THE FACILITY TO MANUFACTURE LOW SULFUR GASOLINE AND DIESEL FUEL IN COMPLIANCE WITH EPA AND STATE REGULATIONS. THE SCOPE OF THE PROJECT WILL INCLUDE THE CONSTRUCTION OF SEVERAL NEW TREATING UNITS, MODIFICATION OF EXISTING TREATING UNITS, INSTALLATION OF POLLUTION CONTROLS ON EXISTING EQUIPMENT, AND THE SHUTDOWN OF OTHER EQUIPMENT THAT CANNOT BE REASONABLY CONTROLLED TO MEET THE NEW NOX REQURIEMENTS DICTATED BY THE SIP. THIS CONTINUOUS CONSTRUCTION CAMPAIGN IS SCHEDULED TO CONTINUE UNTIL COMPLETION IN 2007. SIC Code: 2911

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: HARRIS Facility State: TX Facility ZIP Code: 77017 Permit Issued By: TEXAS COMMISSION ON ENVIRONMENTAL QUALITY (TCEQ) (Agency Name)

MR. JOHNNY VERMILLION(Agency Contact) (512) 239-1292 John.Vermillion@tceq.texas.gov Other Agency Contact Info: JOHNNY VERMILLION

TX 512-239-1292Permit Notes: THE INFORMATION ENTERED IN THE DATABASE WAS TAKEN FROM THE DRAFT PRELIMINARY DETERMINATION AND PERMIT FOR THIS FACILITY. THE FILE DID NOT INDICATE THAT ANY CHANGES WERE MADE FOR THE FINAL PERMIT, AND THE RBLC CONTACT PERSON FOR TEXAS INDICATED THAT THE DRAFT INFORMATION SHOULD BE ENTERED. THE PHYSICAL LOCATION OF THE FACILITY IS LATITUDE 29 DEGREES, 43 MINUTES AND LONGITUDE 98 DEGREES, 13 MINUTES, 51 SECONDS.



## Process/Pollutant Information

PROCESS NAME: BENZENE STABILIZER HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: PETRO REFIN GAS Throughput: 38.34 MMBTU/H

Process Notes: EMISSION PT. NO. ARU-H501

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.8000 LB/H Emission Limit 2: 16.5000 T/YR Standard Emission: 0.0990 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.0000 LB/H Emission Limit 2: 4.3000 T/YRStandard Emission: 0.0260 LB/MMBTU CALCULATED

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2100 LB/H Emission Limit 2: 0.9100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.2900 LB/H Emission Limit 2: 1.2500 T/YR Standard Emission: 0.0070 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 HControl Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.2000 LB/H Emission Limit 2: 13.8000 T/YR Standard Emission: 0.0830 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER NO. 12 Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 245.00 MMBTU/H

Process Notes: EMISSION PT NO: BOILER-12. SHALL BE SHUTDOWN.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Emission Limit 1: 19.6000 LB/H

Emission Limit 2: 85.8000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 20.2000 LB/H Emission Limit 2: 88.4000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 6.3000 LB/H Emission Limit 2: 27.6000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.8300 LB/H Emission Limit 2: 8.0000 T/YR Standard Emission: 0.0070 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.3200 LB/H Emission Limit 2: 5.7900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/AOther Applicable Requirements: NSPS

Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1200 LB/H Emission Limit 2: 0.5300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILER NO. 13 Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 366.83 MMBTU/H

Process Notes: EMISSION POINT NO. BOILER-13. UNIT WILL BE SHUTDOWN.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 29.3000 LB/H Emission Limit 2: 128.5000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 30.2000 LB/H Emission Limit 2: 132.3000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 9.4000 LB/H Emission Limit 2: 41.3000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.7300 LB/H Emission Limit 2: 11.9700 T/YR Standard Emission: 0.0070 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 HControl Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.9800 LB/H Emission Limit 2: 8.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1800 LB/H Emission Limit 2: 0.7900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BOILERS 14 AND 15 Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: PETRO REFIN GAS Throughput: 586.00 MMBTU/H EA

Process Notes: BOTH BOILERS WILL BE SHUT DOWN.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY EACH Emission Limit 2: Standard Emission: 5.0000 % OPACITY EACH Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 46.9000 LB/H EACH Emission Limit 2: 205.3000 T/YR EACH Standard Emission: 0.0800 LB/MMBTU EACH, CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 48.3000 LB/H EACH Emission Limit 2: 211.4000 T/YR EACH Standard Emission: 0.0800 LB/MMBTU EACH, CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION DESIGN AND PROTOCOL Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 15.1000 LB/H EACH Emission Limit 2: 33.0000 T/YR EACH Standard Emission: 0.0250 LB/MMBTU EACH, CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 4.3700 LB/H EACH Emission Limit 2: 19.1200 T/YR EACH Standard Emission: 0.0070 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.1600 LB/H EACH Emission Limit 2: 13.8400 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2900 LB/H EACH Emission Limit 2: 1.2600 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: BTU-NO. 1 REACTOR FEED HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 121.74 MMBTU/H

Process Notes: EMISSION POINT NO. BTU-HF103.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 4.4000 LB/H SEE NOTES Emission Limit 2: 19.2000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS: PRE-INSTALLATION OF SCR: 8.50 LB/H AND 37.30 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 10.0000 LB/H Emission Limit 2: 43.9000 T/YR Standard Emission: 0.0820 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATEDEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.7000 T/YR Standard Emission: 0.0250 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.5600 LB/H SEE NOTES Emission Limit 2: 6.8000 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED FROM FINAL HOURLY EMISS LIMIT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: ADDITONAL EMISSION LIMITS PRIOR TO INSTALLATION OF SCR: 0.91 LB/H AND 3.97 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.6600 LB/H Emission Limit 2: 2.8800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0600 LB/H Emission Limit 2: 0.2600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5000 LB/H SEE NOTES Emission Limit 2: 2.1700 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMIT: 10 PPMVD @ 3% O2. EMISSION LIMITS ARE POST-INSTALLATION OF SCR.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BTU-NO.2 REACTOR FEED HEATERProcess Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)

Primary Fuel: Throughput: 69.68 MMBTU/H

Process Notes: EMISSION POINT NO. BTU-HF104

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.5000 LB/H SEE NOTES Emission Limit 2: 11.0000 LB/H SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 4.90 LB/H AND 21.40 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 5.7000 LB/H Emission Limit 2: 25.1000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2800 LB/H SEE NOTES Emission Limit 2: 1.2400 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR. ADDITIONAL EMISSION LIMIT: 10 PPMDV @ 3% O2.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)CAS Number: 7446-09-5

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.8000 LB/H Emission Limit 2: 7.9000 T/YR Standard Emission: 0.0250 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.8900 LB/H SEE NOTES Emission Limit 2: 3.8900 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.52 LB/H AND 2.27 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 1.6500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BTU- NO.3 REACTOR FEED HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures)Primary Fuel:

Throughput: 58.95 MMBTU/H

Process Notes: EMISSION POINT NO. BTU-HF105.

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2400 LB/H Emission Limit 2: 1.0500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR. ADDITIONAL EMISSION LIMIT: 10 PPMDV @ 3% O2.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.1000 LB/H SEE NOTES Emission Limit 2: 9.3000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 4.10 LB/H AND 18.10 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 4.9000 LB/H Emission Limit 2: 21.3000 T/YR Standard Emission: 0.0830 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.5000 LB/H Emission Limit 2: 6.6000 T/YR Standard Emission: 0.0250 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7500 LB/H SEE NOTES Emission Limit 2: 3.2900 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.44 LB/H AND 1.92 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOCTest Method: Unspecified

Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3200 LB/H Emission Limit 2: 1.3900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BTU-NO.4 REACTOR FEED HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel:Throughput: 49.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2000 LB/H SEE NOTES Emission Limit 2: 0.8700 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 1.8000 LB/H SEE NOTES Emission Limit 2: 7.7000 T/YR SEE NOTES Standard Emission: 0.0400 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 3.40 LB/H AND 15.00 T/YR,

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 4.0000 LB/H Emission Limit 2: 17.7000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.3000 LB/HEmission Limit 1: 1.3000 LB/H

Emission Limit 2: 5.5000 T/YR Standard Emission: 0.0270 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6300 LB/H SEE NOTES Emission Limit 2: 2.7400 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.37 LB/H AND 1.60 T/YR.

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , VolatilePollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.2600 LB/H Emission Limit 2: 1.1600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BTU-REFORMATE STABILIZER REBOILER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 54.77 MMBTU/HProcess Notes: EMISSION POINT NO. BTU-HF107.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7000 LB/H SEE NOTES Emission Limit 2: 3.0600 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.41 LB/H AND 1.79 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.3000 LB/H Emission Limit 2: 1.2900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.1200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.4000 LB/H Emission Limit 2: 6.2000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2200 LB/H Emission Limit 2: 0.9800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMIT: 10 PPMVD @ 3% O2. EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.0000 LB/H SEE NOTES Emission Limit 2: 8.6000 T/YR SEE NOTES Standard Emission: 0.0370 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 3.80 LB/H AND 16.80 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 4.5000 LB/HEmission Limit 1: 4.5000 LB/H

Emission Limit 2: 19.8000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ISOM II WEST REACTOR FEED HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 104.25 MMBTU/H

Process Notes: EMISSION POINT NO. BTU-HF106.POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.3300 LB/H SEE NOTES Emission Limit 2: 5.8200 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.78 LB/H AND 3.40 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5600 LB/H Emission Limit 2: 2.4600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2Test Method: Unspecified

Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.4200 LB/H Emission Limit 2: 1.8600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITYEmission Limit 2:

Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.8000 LB/H SEE NOTES Emission Limit 2: 16.4000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 7.30 LB/H AND 32.00 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 8.6000 LB/H Emission Limit 2: 37.6000 T/YR Standard Emission: 0.0820 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.7000 LB/H Emission Limit 2: 11.7000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ISOM II COMBINATION SPLITTER HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 77.62 MMBTU/H

Process Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7Test Method: Unspecified

Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3200 LB/H Emission Limit 2: 1.3800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9900 LB/H SEE NOTES Emission Limit 2: 4.3300 T/YR SEE NOTESStandard Emission: 0.0130 LB/MMBTU CALCULATED

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.58 LB/H AND 2.53 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4200 LB/H Emission Limit 2: 1.8300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.8000 LB/H SEE NOTES Emission Limit 2: 12.2000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 5.40 LB/H AND 23.80 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.4000 LB/H Emission Limit 2: 28.0000 T/YR Standard Emission: 0.0820 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.0000 LB/H Emission Limit 2: 8.7000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 HControl Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ISOM II XYLENE RERUN TOWER HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 83.70 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

Emission Limit 1: 3.0000 LB/H SEE NOTES Emission Limit 2: 13.2000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 5.90 LB/H AND 25.70 T/YR.

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.2000 LB/H Emission Limit 2: 9.4000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITYEmission Limit 2:

Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0600 LB/H SEE NOTES Emission Limit 2: 4.6700 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.62 LB/H AND 2.73 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4500 LB/H Emission Limit 2: 1.9800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3400 LB/H SEE NOTES Emission Limit 2: 1.4900 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements:Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR. ADDITIONAL EMISSION LIMIT: 10 PPMVD @ 3% O2.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.9000 LB/H Emission Limit 2: 30.2000 T/YR Standard Emission: 0.0800 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ISOM II EAST REACTOR FEED HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 75.00 MMBTU/H

Process Notes: EMISSION POINT NO. ISOMII-F5.

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.9600 LB/H SEE NOTESEmission Limit 2: 3.3200 T/YR SEE NOTES

Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.56 LB/H AND 2.45 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4000 LB/H Emission Limit 2: 1.7700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.1600 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3100 LB/H SEE NOTES Emission Limit 2: 1.3400 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR. ADDITIONAL EMISSION LIMIT: 10 PPMDV @ 3% O2.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/AOther Applicable Requirements: SIP

Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 2.7000 LB/H SEE NOTES Emission Limit 2: 11.8000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 5.30 LB/H AND 23.00 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 6.2000 LB/H Emission Limit 2: 27.1000 T/YR Standard Emission: 0.0830 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.9000 LB/H Emission Limit 2: 4.2000 T/YR Standard Emission: 0.0250 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW S FUEL: FUEL GAS WITH H2S CONTENT NO MORE THAN 0.1 GR/DSCF OVER A 3 H ROLLING BASIS, OR NATURAL GAS WITH H2S CONTENT NO MORE THAN 0.25 GR/100 DSCF AND TOTAL S CONTENT NO MORE THAN 5.0 GR/ 100 DSCF. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ORTHOXYLENE I HEATER Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 96.23 MMBTU/H

Process Notes: EMISSION POINT NO. ORTHOI-H1.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.5000 LB/H SEE NOTES Emission Limit 2: 15.2000 T/YR SEE NOTESStandard Emission: 0.0360 LB/MMBTU CALCULATED

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 6.70 LB/H AND 29.50 T/YR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.9000 LB/H Emission Limit 2: 34.7000 T/YR Standard Emission: 0.0820 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 2.5000 LB/H Emission Limit 2: 10.8000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) LOW SULFUR CONTENT FUEL: USE REFINERY FUEL GAS WITH NO MORE THAN 0.1 GR/DSCF H2S OR USE NATURAL GAS WITH NO MORE THAN 0.25 GR/100 DSCF H2S AND NO MORE THAN 5.0 GR/100 DSCF TOTAL S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.2300 LB/H SEE NOTES Emission Limit 2: 5.3700 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR CONTENT FUEL: USE REFINERY FUEL GAS WITH NO MORE THAN 0.1 GR/DSCF H2S OR USE NATURAL GAS WITH NO MORE THAN 0.25 GR/100 DSCF H2S AND NO MORE THAN 5.0 GR/100 DSCF TOTAL S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 0.72 LB/H AND 3.14 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.5200 LB/H Emission Limit 2: 2.2700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/AOther Applicable Requirements: NSPS

Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.0500 LB/H Emission Limit 2: 0.2100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3900 LB/H SEE NOTES Emission Limit 2: 1.7200 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM. Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes: EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR. ADDITIONAL EMISSION LIMIT: 10 PPMDV @ 3% O2.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: ORTHOXYLENE II HEATER Process Type: 12.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 226.42 MMBTU/H

Process Notes: EMISSION POINT NO.: ORTHOII-H2.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 18.6000 LB/H Emission Limit 2: 81.7000 T/YR Standard Emission: 0.0820 LB/MMBTU CALCULATEDDid factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 5.8000 LB/H Emission Limit 2: 25.5000 T/YR Standard Emission: 0.0260 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR CONTENT FUEL: USE REFINERY FUEL GAS WITH NO MORE THAN 0.1 GR/DSCF H2S OR USE NATURAL GAS WITH NO MORE THAN 0.25 GR/100 DSCF H2S AND NO MORE THAN 5.0 GR/100 DSCF TOTAL S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.8900 LB/H SEE NOTES Emission Limit 2: 12.6500 T/YR SEE NOTES Standard Emission: 0.0130 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Other Applicable Requirements:

Control Method: (P) LOW SULFUR CONTENT FUEL: USE REFINERY FUEL GAS WITH NO MORE THAN 0.1 GR/DSCF H2S OR USE NATURAL GAS WITH NO MORE THAN 0.25 GR/100 DSCF H2S AND NO MORE THAN 5.0 GR/100 DSCF TOTAL S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO THE INSTALLATION OF SCR: 1.69 LB/H AND 7.39 T/YR.

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.2200 LB/H Emission Limit 2: 5.3500 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Benzene

CAS Number: 71-43-2 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , Organic Compounds (all) , Organic Non-HAP Compounds , Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NESHAPControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Ammonia (NH3)

CAS Number: 7664-41-7 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.9200 LB/H SEE NOTES Emission Limit 2: 4.0400 T/YR SEE NOTES Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL LIMIT OF 10 PPMVD @3% O2. EMISSION LIMITS ARE APPLICABLE POST INSTALLATION OF SCR.

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY Emission Limit 2: Standard Emission: 5.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 8.2000 LB/H SEE NOTES Emission Limit 2: 35.7000 T/YR SEE NOTES Standard Emission: 0.0360 LB/MMBTU CALCULATED Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) SCR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMITS APPLICABLE PRIOR TO INSTALLATION OF SCR: 15.80 LB/H AND 69.40 T/YR.



## Process/Pollutant Information

PROCESS NAME: BACKUP AIR COMPRESSOR ENGINES (1-5)

Process Type: 19.800 (Misc. Internal Combustion Engines) Primary Fuel: Throughput:

Process Notes: COMBINED EMISSION LIMITS FOR 5 ENGINES WITH EMISSION POINT NO. ENG-AIR1 THROUGH ENG-AIR5. THESE ENGINES WILL

BE SHUT DOWN. TOTAL OPERATING TIME FOR ALL 5 ENGINES SHALL NOT EXCEED 20,000 H/ROLLING 12-MO. THROUGHPUT AND FUEL TYPE NOT PROVIDED, BUT ASSUMED FUEL TO BE NATURAL GAS FOR THE PURPOSE OF ASSIGNING AN SCC CODE.

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 33.9400 LB/H Emission Limit 2: 67.8900 T/YRStandard Emission: NOT AVAILABLE

Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 4.7200 LB/H Emission Limit 2: 9.4300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR CONTENT FUEL: USE REFINERY FUEL GAS WITH NO MORE THAN 0.1 GR/DSCF H2S OR USE NATURAL GAS WITH NO MORE THAN 0.25 GR/100 DSCF H2S AND NO MORE THAN 5.0 GR/100 DSCF TOTAL S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.0600 LB/H Emission Limit 2: 2.1300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: N/A

Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate Matter (PM)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.5600 LB/H Emission Limit 2: 1.1100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR CONTENT FUEL: USE REFINERY FUEL GAS WITH NO MORE THAN 0.1 GR/DSCF H2S OR USE NATURAL GAS WITH NO MORE THAN 0.25 GR/100 DSCF H2S AND NO MORE THAN 5.0 GR/100 DSCF TOTAL S. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 4.2600 LB/H Emission Limit 2: 8.5100 T/YR Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATEDEst. % Efficiency:

Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 633 DHT FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION PT NO: 633-FUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TAIL GAS THERMAL OXIDIZERS (2)

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.))Primary Fuel:

Throughput:

Process Notes: THE TWO TAIL GAS THERMAL OXIDIZERS (TGU-ICN AND TGU-ICN2) ARE PART OF THE SULFUR RECOVERY UNIT (SRU)

COMPLEX.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0600 LB/H EACH Emission Limit 2: 0.2800 T/YR COMBINED Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) LEAK DETECTION AND REPAIR PROGRAM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: BARGE LOADING Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. LL19DOCKD

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.7900 LB/H Emission Limit 2: 3.2600 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) LEAK DETECTION AND REPAIR. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TANK TRUCK LOADING Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1900 LB/H Emission Limit 2: 2.5000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) LEAK DETECTION AND REPAIR Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: (2) SOUR WATER TANKS

Process Type: 50.009 (Petroleum Refining Wastewater and Wastewater Treatment) Primary Fuel: Throughput:

Process Notes: COMBINED ENTRY FOR EMISSION POINT NOS. TK921 AND TK922

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0400 LB/H EACH Emission Limit 2: 0.1100 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (B) SPECIFIC GUIDELINES IN PERMIT FOR PROPER COVER, MAINTENANCE, LDAR OF TANK. EMISSIONS WILL BE COLLECTED BY A VAPOR COLLECTION SYSTEM AND ROUTED TO A CONTROL DEVICE WITH A DESTRUCTION EFFICIENCY OF 98%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) MOLTEN SULFUR STORAGE TANKS Process Type: 62.020 (Inorganic Liquid/Gas Storage & Handling) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: UnspecifiedPollutant Group(s): ( InOrganic Compounds )

Emission Limit 1: 0.0010 LB/H LESS THAN, EACH Emission Limit 2: 0.0010 T/YR LESS THAN, EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (B) SPECIFIC GUIDELINES IN PERMIT FOR PROPER COVER, MAINTENANCE, LDAR OF TANK. EMISSIONS WILL BE COLLECTED BY A VAPOR COLLECTION SYSTEM AND ROUTED TO A CONTROL DEVICE WITH A DESTRUCTION EFFICIENCY OF 98%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: (2) SULFURIC ACID STORAGE TANKS Process Type: 62.020 (Inorganic Liquid/Gas Storage & Handling) Primary Fuel: Throughput:

Process Notes: COMBINED ENTRY FOR EMISSION PTS VES202 AND VES203

POLLUTANT NAME: Sulfuric Acid (mist, vapors, etc)

CAS Number: 7664-93-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) ) Emission Limit 1: 0.0010 LB/H LESS THAN, EACH Emission Limit 2: 0.0010 T/YR LESS THAN, EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW SPECIFIC PROCEDURES IN PERMIT FOR PROPER COVER, MAINTENANCE, LEAK DETECTION AND REPAIR ACCORDING TO THE VAPOR PRESSURE OF THE TANK CONTENTS. Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR PLANT FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. SRU-FE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.5100 LB/H Emission Limit 2: 2.2200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (A) EMISSIONS FROM S PITS, SEAL LEGS, AND SULFUR STORAGE TANKS WILL BE COLLECTED BY A VAPOR COLLECTION SYSTEM AND ROUTED TO A CONTROL DEVICE WITH AN EFFICIENCY OF 98% FOR THE H2S VAPORS ROUTED TO IT. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbonyl Sulfide

CAS Number: 463-58-1 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H LESS THANEmission Limit 2: 0.0100 T/YR LESS THAN

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) ACID GAS OR OTHER WASTE GAS SHALL BE BURNED IN THE TGTOS AND/OR FLARE (EMERGENCY USE). Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Disulfide

CAS Number: 75-15-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H LESS THAN Emission Limit 2: 0.0100 T/YR LESS THAN Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) ACID GAS AND OTHER WASTE GAS SHALL BE BURNED IN THE TGTOS AND/OR FLARE (EMERGENCY USE) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SOUR WATER SYSTEM FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:Process Notes: EMISSION POINT NO. SWS-FE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDRED A MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H LESS THAN Emission Limit 2: 0.0100 T/YR LESS THAN Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (A) EMISSIONS WILL BE COLLECTED BY A VAPOR COLLECTION SYSTEM AND ROUTED TO A CONTROL DEVICE WITH A DESTRUCTION EFFICIENCY OF 98%. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: AMINE TREATING UNITS NOS. 14 & 15 FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. 1415-FE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM

ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2300 LB/H Emission Limit 2: 0.9900 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (A) ALL WASTE GAS STREAMS FROM THE AMINE REGENERATION UNITS CONTAINING H2S &/OR VOC SHALL BE ROUTED TO THE SRUS. ONLY UNDER SSEM CONDITIONS SHALL THE STREAMS BE SENT TO THE FLARE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NEW AMINE TREATING UNIT FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. AMINE-FE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A

MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1100 LB/H Emission Limit 2: 0.4900 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (A) ALL WASTE GAS STREAMS FROM THE AMINE REGENERATION UNITS CONTAINING H2S AND/OR VOC SHALL BE ROUTED TO THE SRUS. ONLY UNDER SSEM CONDITIONS SHALL THE STREAMS BE SENT TO THE FLARE. Est. % Efficiency: Compliance Verified: UnknownCompliance Verified: Unknown

Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 50-TON AMINE TREATING UNIT FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. 50TN-FE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A

MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.6600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (A) ALL WASTE GAS STREAMS FROM THE AMINE REGENERATION UNITS CONTAINING H2S AND/OR VOC SHALL BE ROUTED TO THE SRUS. ONLY UNDER START- UP, SHUT-DOWN, OR EMERGENCY CONDITIONS SHALL THE STREAMS BE SENT TO THE FLARE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 100-TON AMINE TREATING UNIT FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions)Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions)

Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. 100TN-FE. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A

MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H LESS THAN Emission Limit 2: 0.0100 T/YR LESS THAN Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (A) ALL WASTE GAS STREAMS FROM THE AMINE REGENERATION UNITS CONTAINING H2S AND/OR VOC SHALL BE ROUTED TO THE SRUS. ONLY UNDER START- UP, SHUT-DOWN, OR EMERGENCY CONDITIONS SHALL THE STREAMS BE SENT TO THE FLARE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FCCU CO BOILER WET GAS SCRUBBER Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Antimony / Antimony Compounds

CAS Number: 7440-36-0 Test Method: Unspecified Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds )Pollutant Group(s): ( Hazardous Air Pollutants (HAP) , InOrganic Compounds )

Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 15.0000 % OPACITY Emission Limit 2: Standard Emission: 15.0000 % OPACITY Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 737 FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:Process Notes: EMISSION POINT NO. 737-FUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 636 FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. FU66HDS. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A

MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H Emission Limit 2: 0.0500 T/YR Standard Emission:Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown

Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 537 FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. 537-FUG. FUGITIVE EMISSIONS ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A

MAXIMUM ALLOWABLE EMISSION RATE.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H LESS THAN Emission Limit 2: 0.0100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: TANK 599A

Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. TK599A. H2S EMISSIONS FROM CRUDE OIL ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A

MAXIMUM ALLOWABLE EMISSION RATE. HOWEVER, AT NO TIME SHALL THE EMISSIONS CAUSE A NUISANCE CONDITION.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/H Emission Limit 2: 1.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PROCEDURES SPECIFIED IN PERMIT FOR PROPER COVER, MAINTENANCE, LEAK DETECTION AND REPAIR ACCORDING TO VAPOR PRESSURE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TANKS 885 THROUGH 888

Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel: Throughput:

Process Notes: COMBINED ENTRY FOR 4 TANKS WITH EMISSION PT NOS. TK885, TK886, TK887, AND TK888. H2S EMISSIONS FROM CRUDE OILProcess Notes: COMBINED ENTRY FOR 4 TANKS WITH EMISSION PT NOS. TK885, TK886, TK887, AND TK888. H2S EMISSIONS FROM CRUDE OIL ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE EMISSION RATE. HOWEVER, AT NO TIME SHALL THE EMISSIONS CAUSE A NUISANCE CONDITION.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.3700 LB/H EACH Emission Limit 2: 1.5800 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) FOLLOW PROCEDURES IN PERMIT FOR PROPER COVER, MAINTENANCE, LEAK DETECTION AND REPAIR ACCORDING TO VAPOR PRESSURE. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: CRUDE OIL FUGITIVES

Process Type: 50.007 (Petroleum Refining Equipment Leaks/Fugitive Emissions) Primary Fuel: Throughput:

Process Notes: H2S EMISSIONS FROM CRUDE OIL ARE AN ESTIMATE ONLY AND SHOULD NOT BE CONSIDERED A MAXIMUM ALLOWABLE

EMISSION RATE. HOWEVER, AT NO TIME SHALL THE EMISSIONS CAUSE A NUISANCE CONDITION.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0900 T/YREmission Limit 2: 0.0900 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARES

Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: COMBINED ENTRY FOR 4 FLARES WITH EMISSION POINT NOS. FL-3- COK (736 COKER FLARE), FL38 (MEROX FLARE), P-FL-4 (NO.

4 PLANT FLARE) AND HOUST-FL (HOUSTON STREET FLARE).

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0100 LB/H LESS THAN, EACH Emission Limit 2: 0.0100 T/YR LESS THAN, EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) OPERATE IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING MINIMUM HEATING VALUE OF WASTE GAS, MAX TIP VELOCITY, AND PILOT FLAME MONITORING. FUEL GAS WILL BE ADDED FOR SUFFICIENT COMBUSTION IF NECESSARY. Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NO. 1 PLANT FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. P-FL-1.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.9500 LB/H Emission Limit 2: 2.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/AOther Applicable Requirements: NSPS

Control Method: (P) OPERATE IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING MINIMUM HEATING VALUE OF WASTE GAS, MAX TIP VELOCITY, AND PILOT FLAME MONITORING. FUEL GAS WILL BE ADDED FOR SUFFICIENT COMBUSTION IF NECESSARY. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Trioxide

CAS Number: 7446-11-9 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 0.0400 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) OPERATE IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING MINIMUM HEATING VALUE OF WASTE GAS, MAX TIP VELOCITY, AND PILOT FLAME MONITORING. FUEL GAS WILL BE ADDED FOR SUFFICIENT COMBUSTION IF NECESSARY. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIPControl Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NO. 2 PLANT FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. P-FL-2

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.9900 LB/H Emission Limit 2: 2.1700 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) OPERATE IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING MINIMUM HEATING VALUE OF WASTE GAS, MAX TIP VELOCITY, AND PILOT FLAME MONITORING. FUEL GAS WILL BE ADDED FOR SUFFICIENT COMBUSTION IF NECESSARY. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s):Emission Limit 1: 5.0000 % OPACITY 6 MIN AV

Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: NO. 3 PLANT FLARE Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput:

Process Notes: EMISSION POINT NO. P-FL-3.

POLLUTANT NAME: Hydrogen Sulfide

CAS Number: 7783-06-4 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.0300 LB/H Emission Limit 2: 0.0200 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: NSPS Control Method: (P) OPERATE IN ACCORDANCE WITH 40 CFR 60.18 INCLUDING MINIMUM HEATING VALUE OF WASTE GAS, MAX TIP VELOCITY, AND PILOT FLAME MONITORING. FUEL GAS WILL BE ADDED FOR SUFFICIENT COMBUSTION IF NECESSARY. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Visible Emissions (VE)

CAS Number: VE Test Method: Unspecified Pollutant Group(s): Emission Limit 1: 5.0000 % OPACITY 6 MIN AV Emission Limit 2: Standard Emission: 5.0000 % OPACITY 6 MIN AV Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: N/A Other Applicable Requirements: SIP Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0120 (final) Date Determination Last Updated: 10/02/2007 Corporate/Company Name: SHELL CHEMICAL LP Permit Number: PSD-LA-647

(M-2) Facility Name: GEISMAR PLANT Permit Date: 02/26/2002 (actual) Facility Contact: L.R. BROERING FRS Number: 110000743394 Facility Description: RE-EVALUATION OF BACT FOR OLEFIN AND ALCOHOL PROJECT. THIS PROJECT WAS

APPROVED EARLIER UNDER PSD PERMIT NO. PSD-LA-647 (M-1) DATED JUNE 26, 2001. THE CURRENT PERMIT IS FOR THE MODIFICATION OF REGENERATIVE FURNACE, EMISSION POINT 620-99, TO INCLUDE PREMIX STYLE BURNERS IN PLACE OF ULTRA-LOW NOX BURNERS AS BACT. REFER TO RBLC ENTRY LA-0146 FOR THE ORIGINAL PERMIT, PSD-LA-647. SIC Code: 5169

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 425120 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: ASCENSION PARISHFacility State: LA

Facility ZIP Code: 70734 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name)

MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: DAN NGUYEN, (225) 219-3181

Permit Notes: PSD-LA-647(M3), ISSUED JULY 23, 2007, REVISED EMISSION LIMITS FOR SEVERAL SOURCES BASED ON UPDATED EMISSION

FACTORS AND CURRENT OPERATING CONDITIONS. INCREASES WERE BELOW APPLICABLE SIGNIFICANCE LEVELS; THEREFORE, BACT WAS NOT REEVALUATED. ALSO, NOX EMISSIONS FROM THE FLARE WERE CORRECTLY LISTED AS 176.91 TPY. BOTH THE M1 & M2 PERMITS SET 17.20 TPY AS THE NOX LIMIT; HOWEVER, THIS FIGURE IS IN ERROR. A VALUE OF 177.62 TPY WAS REPORTED IN THE APPLICATION ASSOCIATED WITH THE M1 PERMIT AND WAS USED IN THE APPLICABILITY AND MODELING ANALYSES, BUT IT WAS NOT CARRIED FORWARD PROPERLY INTO THE FINAL PERMIT. Affected Boundaries: Boundary Type: Class 1 Area State: Boundary: Distance: CLASS1 LA Breton 100km - 50km



## Process/Pollutant Information

PROCESS NAME: REGENERATOR FURNACE #620-99 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 3.30 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.0200 LB/H Emission Limit 2: 0.0700 T/YR Standard Emission: 0.0100 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2600 LB/H Emission Limit 2: 0.7700 T/YR Standard Emission: 0.0800 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.4000 LB/H Emission Limit 2: 1.1600 T/YR Standard Emission: 0.1200 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) PREMIX STYLE BURNERS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant InformationPROCESS NAME: (2) COGENERATION UNITS POINT # 720-99 AND 721-99

Process Type: 15.210 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 40.00 MW EACH

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 14.5000 LB/H EACH Emission Limit 2: 58.7100 T/YR EACH Standard Emission: 5.0000 PPM @ 15% O2 EACH, WITH OR WITHOUT DUCT BURNER Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) LOW NOX BURNERS AND A SELECTIVE CATALYTIC REDUCTION SYSTEM. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: AVERAGE COST EFFECTIVENESS PER TON FOR SCONOX IS $6200 (EACH), BUT INFORMATION IS NOT PROVIDED IN COMBINATION WITH SCR.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 44.0000 LB/H EACH Emission Limit 2: 178.7000 T/YR EACH Standard Emission: 24.8000 PPM @ 15% O2 CONVERTED USING THROUGPUT Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES WITH NATURAL GAS AS FUEL. Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: PERMIT LISTS A LIMIT OF 15 PPM @ 15% O2 FROM EACH TURBINE AND 10 PPM @ 15% O2 FROM EACH DUCT BURNER. THE STANDARDIZED EMISSIONS FOR THE COGENERATION UNIT WERE CALCULATED USING THE THROUGHPUT.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 10.8000 LB/H EACH Emission Limit 2: 45.9000 T/YR EACH Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) USE OF CLEAN NATURAL GAS WITH GOOD COMBUSTION PRACTICES AND NO ADD-ON CONTROLS. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PLANT FLARE, #03-73 Process Type: 19.310 (Chemical Plant Flares) Primary Fuel: NATURAL GAS Throughput: 204.00 MMBTU/H

Process Notes: THE PLANT FLARE SYSTEM IS A STEAM ASSISTED FLARE USED TO CONTROL VOC EMISSIONS.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 213.6000 LB/H Emission Limit 2: 23.3900 T/YREmission Limit 2: 23.3900 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) THE FLARE WILL BE OPERATED UNDER THE REQUIREMENTS OF 40 CFR PART 60 SUBPART A. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1801.1800 LB/H Emission Limit 2: 183.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) PLANT FLARE WILL BE OPERATED UNDER THE REQUIREMENTS OF 40 CFR PART 60 SUBPART A Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 325.1900 LB/H Emission Limit 2: 17.2000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) THE FLARE WILL BE OPERATED UNDER THE REQUIREMENTS OF NSPS SUBPART A. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SYLTHERM FURNACE, #321-99 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 53.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.3800 LB/H Emission Limit 2: 1.3500 T/YR Standard Emission: 0.0100 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds )Emission Limit 1: 4.2500 LB/H

Emission Limit 2: 14.8900 T/YR Standard Emission: 0.0800 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES AND ENGINEERING DESIGN Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.3700 LB/H Emission Limit 2: 11.1700 T/YR Standard Emission: 0.0400 LB/MMBTU SEE POLLUTANT NOTES Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW NOX BURNERS OR COMBINATION FUEL BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: THIS HEATER IS PERMITTED TO USE ULTRA LOW NOX BURNERS AS CONTROL WITH AN EMISSION LIMIT OF 0.04 LB/MMBTU OR COMBINATION BURNERS AS CONTROL WITH AN EMISSION LIMIT OF 0.06 LB/MMBTU.



## Process/Pollutant Information

PROCESS NAME: COOLING WATER TOWER, #343-99 Process Type: 99.009 (Industrial Process Cooling Towers) Primary Fuel: Throughput: 23000.00 GAL/MINProcess Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.7200 LB/H Emission Limit 2: 7.5400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) DRIFT ELIMINATORS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HOT OIL FURNACE, #621-99 Process Type: 13.310 (Natural Gas (includes propane and liquefied petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 20.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.6200 LB/H Emission Limit 2: 5.6800 T/YR Standard Emission: 0.0800 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 0.8100 LB/H Emission Limit 2: 2.8400 T/YR Standard Emission: 0.0400 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) ULTRA LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.1500 LB/H Emission Limit 2: 0.5100 T/YR Standard Emission: 0.0100 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:



## Facility Information

RBLC ID: 

## LA-0141 (final) Date Determination Last Updated: 09/29/2003 Corporate/Company Name: DUKE ENERGY FIELD SERVICES - MINDEN Permit Number: PSD-LA-614 (M-2) Facility Name: DUKE ENERGY FIELD SERVICES - MINDEN Permit Date: 01/24/2002 (actual) Facility Contact: JOE KUCHINSKI FRS Number: 110000545269 Facility Description: NATURAL GAS PROCESSING FACILITY DESIGNED TO RECOVER PROPANE PLUS NATURAL GAS LIQUIDS. NEW COMPANY NAME: DCP MIDSTREAM, LP NEW FACILITY NAME: MINDEN GAS PLANT SIC Code: 1321

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 211112 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: WEBSTER PARISH Facility State: LA Facility ZIP Code: 71055 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: BRIAN ROBSON LA 225-765-0557 Permit Notes: PERMIT IS FOR A MINOR MODIFICATION OF EXISTING NATURAL GAS PROCESSING FACILITY - AS A RESULT, THERE WILL BE NO SIGNIFICANT INCREASES IN EMISSIONS DUE TO THIS PROJECT AND A FULL PSD REVIEW IS NOT NECESSARY. MODIFICATION INCLUDES: THE REMOVAL OF THE REMAINING COMPONENTS OF THE LEAN OIL PLANT (EMISSION POINTS 19-82, 1-81, 2-81, 4-81, 5- 90, 3-81A, 3-81B, 1-85, 6-98, 7-98, 8-98); A CHANGE TO THE AMINE UNIT (EMISSION POINTS 1-98 AND 20-81); RELOCATION OF ENGINE (EMISSION POINT 3-91); INCREASED Y-GRADE TRUCK LOADING AND UNLOADING (EMISSION POINT 16-81D). REFER TO RBLC ENTRY LA-0154 FOR THE FIRST MODIFICATION TO PERMIT PSD-LA-614. PERMIT PSD-LA-614(M3) WAS ISSUED JANUARY 26, 2011. VOC AND CO EMISSIONS FROM VARIOUS EQUIPMENT WERE ADJUSTED. TOTAL INCREASE WAS NOT MORE THAN THE PSD SIGNIFICANCE LEVELS. BACT WAS NOT REQUIRED TO BE CHANGED. Facility-wide Emissions: Pollutant Name: Facility-wide Emissions Increase: Carbon Monoxide 555.9100 (Tons/Year) Nitrogen Oxides (NOx) 571.0000 (Tons/Year) Particulate Matter (PM) 3.7300 (Tons/Year) Sulfur Oxides (SOx) 0.5200 (Tons/Year)Sulfur Oxides (SOx) 0.5200 (Tons/Year) Volatile Organic Compounds (VOC) 192.4000 (Tons/Year)



## Process/Pollutant Information

PROCESS NAME: Y-GRADE TRUCK LOADING AND UNLOADING Process Type: 50.002 (Natural Gas/Gasoline Processing Plants) Primary Fuel: Throughput: 22.00 MM GAL/YR

Process Notes: EMISSION POINT 16-81D

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.6500 LB/H Emission Limit 2: 8.0400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT NOT REQUIRED FOR MINOR MODIFICATIONS. BACT ANALYSIS FROM PREVIOUS PERMIT MODIFICATION DETERMINED TO BE ADEQUATE.



## Process/Pollutant Information

PROCESS NAME: FLARE Process Type: 19.390 (Other Flares) Primary Fuel: Throughput:

Process Notes: EMISSION POINT 20-81POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 2.8200 LB/H Emission Limit 2: 8.7300 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT NOT REQUIRED FOR MINOR MODIFICATION. BACT ANALYSIS FROM LAST PERMIT MODIFICATION DETERMINED TO BE ADEQUATE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.2600 LB/H Emission Limit 2: 1.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT NOT REQUIRED FOR MINOR MODIFICATION. BACT ANALYSIS FROM LAST PERMIT MODIFICATION DETERMINED TO BE ADEQUATE.



## Process/Pollutant InformationPROCESS NAME: WAUKESHA COMPRESSOR ENGINE

Process Type: 17.130 (Natural Gas (includes propane & liquified petroleum gas)) Primary Fuel: NATURAL GAS Throughput: 1478.00 HP

Process Notes: EMISSION POINT 3-91

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1.6300 LB/H Emission Limit 2: 7.1400 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMIT: 0.5 G/B-HP-H. BACT NOT REQUIRED FOR MINOR MODIFICATION. BACT ANALYSIS FROM LAST PERMIT MODIFICATION DETERMINED TO BE ADEQUATE.

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 9.7800 LB/H Emission Limit 2: 42.8200 T/YR Standard Emission: 3.0000 G/B-HP-H Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency:Compliance Verified: Unknown

Pollutant/Compliance Notes: BACT NOT REQUIRED FOR MINOR MODIFICATION. BACT ANALYSIS FROM LAST PERMIT MODIFICATION DETERMINED TO BE ADEQUATE.



## Process/Pollutant Information

PROCESS NAME: AMINE VENT Process Type: 50.002 (Natural Gas/Gasoline Processing Plants) Primary Fuel: Throughput:

Process Notes: EMISSION POINT 1-98

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 3.6800 LB/H Emission Limit 2: 16.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: BACT NOT REQUIRED FOR MINOR MODIFICATION. BACT ANALYSIS FROM LAST PERMIT MODIFICATION DETERMINED TO BE ADEQUATE.



## Facility Information

RBLC ID: 

## LA-0166 (final) Date Determination Last Updated: 05/10/2006Corporate/Company

Name: ORION REFINING CORP (NOW VALERO) Permit Number: PSD-LA-619

Facility Name: ORION REFINING CORP (NOW VALERO) Permit Date: 01/10/2002 (actual) Facility Contact: MR. CLARK JOHNSON FRS Number: 110000448659 Facility Description: PETROLEUM REFINERY, 190,000 BARRELS PER DAY TOTAL DESIGN THROUGHPUT. REFINERY OPTIMIZATION PROJECT INCLUDING NEW EQUIPMENT, PHYSICAL MODIFICATIONS, CHANGES IN THE METHOD OF OPERATIONS, CAPACITY INCREASES DUE TO DEBOTTLENECKING AND THE INCORPORATION OF 86 STORAGE TANKS PURCHASED FROM GATX. SIC Code: 2911

Permit Type: D: Both B (Add new process to existing facility) &C (Modify process at existing facility) NAICS Code: 324110 Permit URL: EPA Region: 6 COUNTRY: USA Facility County: ST. CHARLES PARISH Facility State: LA Facility ZIP Code: 70078 Permit Issued By: LOUISIANA DEPARTMENT OF ENV QUALITY (Agency Name) MR. BRYAN D. JOHNSTON(Agency Contact) (225)219-3450 BRYAN.JOHNSTON@LA.GOV Other Agency Contact Info: CATHY LU, 225-219-3181

Permit Notes: VALERO REFINING - NEW ORLEANS, LLC BECAME OWNER OF THE REFINERY ON JULY 1, 2003. PSD-LA-619(M-1), ISSUED 6/2/05, REPLACED THE FACILITY''''''''''''''''S DESIGN THROUGHPUT CONDITION (FORMERLY



## Process/Pollutant Information

PROCESS NAME: FCC REGENERATOR Process Type: 50.003 (Petroleum Refining Conversion Processes (cracking, reforming, etc.)) Primary Fuel: Throughput: 110.00 TO 130 MBBL/D

Process Notes: BELCO WET GAS SCRUBBER FOR SO2 AND PM10. HIGH TEMPERATURE REGENERATION FOR CO CONTROL.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 86.1000 LB/HEmission Limit 2: 327.0000 T/YR

Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BELCO WET GAS SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 450.0000 LB/H Emission Limit 2: 1314.0000 T/YR Standard Emission: NOT AVAILABLE Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) BELCO WET GAS SCRUBBER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 444.0000 LB/H Emission Limit 2: 1684.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEATER F-72-703 Process Type: 11.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: REFINERY FUEL GAS Throughput: 528.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.6000 LB/H Emission Limit 2: 11.6000 T/YR Standard Emission: 0.0050 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) BURNING CLEAN FUEL (NATURAL GAS AND FUEL GAS), AND UTILIZING GOOD COMBUSTION PRACTICES. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )Emission Limit 1: 14.2000 LB/H

Emission Limit 2: 62.2000 T/YR Standard Emission: 0.0270 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW SULFUR REFINERY FUEL GAS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 41.7000 LB/H Emission Limit 2: 183.0000 T/YR Standard Emission: 0.0790 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 21.5000 LB/H Emission Limit 2: 92.5000 T/YR Standard Emission: 0.0410 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: UnknownCase-by-Case Basis: BACT-PSD

Other Applicable Requirements: Control Method: (P) GOOD DESIGN/OPERATION/COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.7400 LB/H Emission Limit 2: 3.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMIT: 001 LB/MMBTU



## Process/Pollutant Information

PROCESS NAME: MARINE TANK VESSEL LOADING OPERATIONS

Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes: EMISSIONS FOR THE MARINE TANK VESSEL LOADING OPERATIONS IN THE PERMIT ARE LISTED UNDER THE MARINE VAPOR

RECOVERY (MVR) THERMAL OXIDIZER. THE THERMAL OXIDIZER HAS A THROUGHPUT OF 200 MMBTU/H. EMISSIONS INFORMATION HAS BEEN REORGANIZED FOR PURPOSES OF THIS DATABASE TO REFLECT THAT THE PROCESS IS LOADING AND THE CONTROL DEVICE IS THE THERMAL OXIDIZER.

POLLUTANT NAME: Nitrogen Oxides (NOx)CAS Number: 10102

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 28.0000 LB/H Emission Limit 2: 123.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 7.0000 LB/H Emission Limit 2: 30.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 2.7000 LB/HEmission Limit 2: 12.0000 T/YR

Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 3.3000 LB/H Emission Limit 2: 4.9000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 512.0000 LB/H Emission Limit 2: 229.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSDOther Applicable Requirements:

Control Method: (A) HIGH VAPOR PRESSURE MATERIAL (>1.5 PSIA) LOADED WITH VAPORS DIRECTED TO THERMAL OXIDIZER FOR VOC DESTRUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: PETROLEUM PRODUCTS LOADING DOCKS Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 687.0000 LB/H Emission Limit 2: 155.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) HIGH VAPOR PRESSURE MATERIAL (>1.5 PSIA) LOADED WITH VAPORS IS DIRECTED TO THE MARINE VAPOR RECOVERY THERMAL OXIDIZER FOR VOC DESTRUCTION Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: TANK TRUCK/RAIL CAR LOADINGProcess Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading))

Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 261.0000 LB/H Emission Limit 2: 6.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NOT SUBJECT TO BACT, ALL LOW PRESSURE MATERIALS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: FLARE NO.1 (EMISSION PT. 15-77) Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput: 60.70 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0000 LB/H Emission Limit 2: 0.5800 T/YRStandard Emission:

Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 133.0000 LB/H Emission Limit 2: 87.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 33.6000 LB/H Emission Limit 2: 45.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 149.0000 LB/H Emission Limit 2: 98.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 25.4000 LB/H Emission Limit 2: 16.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) 98% OF VOC IN FLARE, FLARE IS CONTROL DEVICE. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:

## Process/Pollutant Information

PROCESS NAME: FLARE NO. 2 (EMISSION PT. 12-81) Process Type: 19.330 (Refinery Flares) Primary Fuel: Throughput: 60.70 MMBTU/H

Process Notes:

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 1.0000 LB/H Emission Limit 2: 0.5800 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 133.0000 LB/H Emission Limit 2: 87.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (N)

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 33.6000 LB/H Emission Limit 2: 45.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 149.0000 LB/H Emission Limit 2: 98.3000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 25.4000 LB/H Emission Limit 2: 16.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) FLARE IS CONTROL DEVICE FOR VOC EMISSIONS. 98% DESTRUCTION OF VOC IN FLARE. Est. % Efficiency: 98.000 Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SPENT SULFURIC ACID STORAGE Process Type: 42.005 (Petroleum Liquid Storage in Fixed Roof Tanks) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.1000 LB/H Emission Limit 2: 5.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements:Control Method: (B) FIXED ROOF STORAGE TANK AND SUBMERGED FILL LOADING

Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SPENT SULFURIC LOADING Process Type: 50.004 (Petroleum Refining Feedstock (blending, loading and unloading)) Primary Fuel: Throughput:

Process Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.1000 LB/H Emission Limit 2: 5.0000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (B) FIXED ROOF STORAGE TANK AND SUBMERGED FILL LOADING Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEATER H-15-01A Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel:Throughput: 46.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 6.4000 LB/H Emission Limit 2: 28.2000 T/YR Standard Emission: 0.1391 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 1.6000 LB/H Emission Limit 2: 7.1000 T/YR Standard Emission: 0.0348 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD DESIGN/OPERATION/ COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)CAS Number: VOC

Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.5600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMIT: 0.0028 LB/MMBTU.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6400 LB/H Emission Limit 2: 2.8000 T/YR Standard Emission: 0.0139 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL, GOOD COMBUSTION PROCESSES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.2000 LB/HEmission Limit 2: 5.4000 T/YR

Standard Emission: 0.0261 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) COMBUSTION OF LOW SULFUR FUEL Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: HEATER H-15-01B Process Type: 13.390 (Other Gaseous Fuel & Gaseous Fuel Mixtures) Primary Fuel: Throughput: 46.00 MMBTU/H

Process Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.8000 LB/H Emission Limit 2: 16.7000 T/YR Standard Emission: 0.0826 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) LOW NOX BURNERS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 2.8000 LB/H Emission Limit 2: 12.3000 T/YR Standard Emission: 0.0609 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GOOD DESIGN/ OPERATION/ COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.1300 LB/H Emission Limit 2: 0.5600 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: ADDITIONAL EMISSION LIMIT: 0.0028 LB/MMBTU.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.6400 LB/HEmission Limit 2: 2.8000 T/YR

Standard Emission: 0.0139 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) GASEOUS FUEL/ GOOD COMBUSTION PRACTICES Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 1.2000 LB/H Emission Limit 2: 5.4000 T/YR Standard Emission: 0.0261 LB/MMBTU Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) COMBUSTION OF LOW SULFUR FUELS Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNITS 1 AND 2

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: EMISSIONS INFORMATION IN THE PERMIT WAS LISTED UNDER THERMAL OXIDIZER 1. INFORMATION HAS BEEN REORGANIZEDProcess Notes: EMISSIONS INFORMATION IN THE PERMIT WAS LISTED UNDER THERMAL OXIDIZER 1. INFORMATION HAS BEEN REORGANIZED FOR PURPOSES OF THIS DATABASE TO DEMONSTRATE THAT THE PROCESS IS THE SULFUR RECOVERY UNIT AND THE THERMAL OXIDIZER IS AN ADD-ON CONTROL DEVICE WITH A THROUGHPUT OF 50 MMBTU/H.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 0.7000 LB/H Emission Limit 2: 3.1000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 103.0000 LB/H Emission Limit 2: 452.0000 T/YR Standard Emission: 250.0000 PPMV @ O% EXCESS AIR Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) EFFICIENCY OF SULFUR RECOVERY PROCESS TOGETHER WITH OXIDATION OF RESIDUAL SULFUR COMPOUNDS LIMITS SO2 EMISSIONS TO 250 PPM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 5.2000 LB/H Emission Limit 2: 22.7000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon Monoxide

CAS Number: 630-08-0 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) )Emission Limit 1: 0.1400 LB/H

Emission Limit 2: 0.6100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: SULFUR RECOVERY UNIT NO. 3

Process Type: 50.006 (Petroleum Refining Treating Processes (hydrotreating, acid gas removal, SRU's, etc.)) Primary Fuel: Throughput:

Process Notes: EMISSIONS INFORMATION IN THE PERMIT WAS LISTED UNDER THERMAL OXIDIZER 2, BUT HAS BEEN REORGANIZED HERE TO

DEMONSTRATE THAT THE PROCESS IS THE SULFUR RECOVERY UNIT AND THAT THE THERMAL OXIDIZER, WITH A 50 MMBTU/H THROUGHPUT, IS AN ADD-ON CONTROL DEVICE.

POLLUTANT NAME: Particulate matter, filterable < 10 μ (FPM10)

CAS Number: PM Test Method: Unspecified Pollutant Group(s): ( Particulate Matter (PM) ) Emission Limit 1: 82.7400 LB/H Emission Limit 2: 362.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: UnknownPollutant/Compliance Notes:

POLLUTANT NAME: Sulfur Dioxide (SO2)

CAS Number: 7446-09-5 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) ) Emission Limit 1: 5.0000 LB/H Emission Limit 2: 22.0000 T/YR Standard Emission: 250.0000 PPMV @ 0% EXCESS AIR Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (P) EFFICIENCY OF SULFUR RECOVERY PROCESS TOGETHER WITH OXIDATION OF RESIDUAL SULFUR COMPOUNDS LIMITS SO2 EMISSIONS TO 250 PPM Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Nitrogen Oxides (NOx)

CAS Number: 10102 Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) ) Emission Limit 1: 3.1000 LB/H Emission Limit 2: 13.4000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Carbon MonoxideCAS Number: 630-08-0

Test Method: Unspecified Pollutant Group(s): ( InOrganic Compounds ) Emission Limit 1: 0.1000 LB/H Emission Limit 2: 0.6000 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (N) NONE INDICATED Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 0.4400 LB/H Emission Limit 2: 1.9100 T/YR Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: Unknown Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Control Method: (A) THERMAL OXIDIZER Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes:



## Process/Pollutant Information

PROCESS NAME: 86 TANKS UNDER TANK CAP Process Type: 42.009 (Volatile Organic Liquid Storage) Primary Fuel:Throughput: 190000.00 BBL/D

Process Notes: 86 STORAGE TANKS UNDER ONE CAP, 190000 BBL/DAY

POLLUTANT NAME: Volatile Organic Compounds (VOC)

CAS Number: VOC Test Method: Unspecified Pollutant Group(s): ( Volatile Organic Compounds (VOC) ) Emission Limit 1: 1108.0000 T/YR CAP: SEE NOTE Emission Limit 2: Standard Emission: Did factors, other then air pollution technology considerations influence the BACT decisions: U Case-by-Case Basis: BACT-PSD Other Applicable Requirements: OPERATING PERMIT Control Method: (N) NO CONTROLS REQUIRED, UNDER CAP. Est. % Efficiency: Compliance Verified: Unknown Pollutant/Compliance Notes: PSD-LA-619(M-1), ISSUED 6/2/05, REPLACED THE FACILITY''''''''S DESIGN THROUGHPUT CONDITION (FORMERLY