Exploration and Production Waste Study 

Frequency Distribution of TCLP Data 

Number of Samples API Data 

0-0.5 0.5-5 5-10 10-20 20-30 

Benzene Concentration (mg/l) 

420 

Figure 1 
P.5 

<_f&£c-soo^3rg> 

ATTACHMENT 1 
P.6 

I. OVERVIEW 

This report presents the analytical results as well as supporting 

information to aid in the evaluation and interpretation of the data and is 

arranged in the following order: 

I. Overview 

II. Sample Description Information/Analytical Test Requests 

III. Analytical Results 

IV. Quality Control Report 

A. Standard Enseco QC 

B. Project-Specific QC 

Consistent with directives in the CLP protocol in SW-846 and other EPA 

methods, all GC/MS analyses were performed so that the maximum concentration 

of sample was analyzed. Some samples required dilutions to avoid saturation 

of the detector, to achieve linearity for a specific target compound or to 

reduce matrix interferences. As stated in Section 7.5.4 of Method 8270, 

7.4.1.16 of Method 8240 and Exhibit E of the CLP protocol these dilutions must 

be performed. The reporting limits for these samples are therefore 

proportionate to the dilution required. Surrogate compounds may not be 

measurable in samples which have been diluted. 

Samples 011772-0001 through -0005 for total volatiles and samples 011772-

0001 through -0004, -0001MS (matrix spike), and -0002MS for TCLP volatiles 

required dilutions due to concentrations of target or non-target compounds 

present beyond linear range. The reporting limits were increased accordingly. 

Samples 011772-0001 and -0001MS matrix spike generated two phases during 

the TCLP volatile and metals extractions. Per the TCLP method, each phase was 

analyzed separately and results then mathematically recombined. 

The reporting limits were increased for the barium analyses by ICP for 

TCLP samples 011772-0001 and -0003 through -0005 due to concentrations of 

barium detected in the method blank. 
P.7 

The recoveries of cadmium were irregular in the leachate analyses for 

samples 011772-0001MS and -0002MS. The spike recoveries were measured for non 

requested elements and found to be correct. The irregularity appears to be 

confined to the cadmium results only and may suggest matrix interferences. 

Per Enseco's QAPP, the laboratory does not control on matrix spike samples. 

Samples within this project have been analyzed for TCLP as finalized in 

the June 29, 1990 Federal Register (p. 26986 - 26998). TCLP leachates are 

prepared using Method 1310 and analyzed using Methods 6010, 7470, and 7740 for 

metals, 8240 for volatiles, 8270 for semivolatiles, 8080 for pesticides, and 

8150 for. herbicides. Every effort was made to achieve reporting limits below 

the regulated limit on each sample. However, as with all environmental 

analyses, matrix interferences or target compounds may. be present in some 

samples which limit the effectiveness of the analytical method to achieve 

these limits. 

The final TCLP rule contains a requirement that a matrix spike be 

analyzed for each analytical batch and that the bias determined from the 

matrix spike be used to correct the measured values. Enseco disagrees with 

the requirement to adjust sample results using spike recovery data and 

furthermore believes that if correction of data is to be performed, it should 

not be performed by the laboratory. Enseco has submitted formal comments to 

EPA concerning recovery correction (copies are available on request). Results 

are reported uncorrected for spike recoveries. The results rom the.QC sample 

analyses (surrogates, lab controls and matrix spikes) are contained in the 

report, should these data be of. interest in adjusting reported values. As 

stated in Method 1310, use of alternated methods may be needed when the 

recovery of the matrix spike is below the expected analytical performance. 
P.8 

II. SAMPLE DESCRIPTION INFORMATION/ANALYTICAL TEST REQUESTS 

Sample Description Information 

The Sample Description Information lists all of the samples received in 

this project together with the internal laboratory identification number 

assigned for each sample. Each project received at Enseco - RMAL is assigned 

a unique six digit number. Samples within the project are numbered 

sequentially. The laboratory identification.number is a combination of the 

six digit project code and the sample sequence number. 

Also given in the Sample Description Information is the Sample Type 

(matrix), Date of Sampling (if known) and Date of Receipt at the laboratory. 

Analytical Test Requests 

The Analytical Test Requests lists the analyses that were performed on 

each sample. The Custom Test column indicates where tests have been modified 

to conform to the specific requirements of this project. 
P.9 

III. ANALYTICAL RESULTS 

The analytical results for this project are presented in the following 

data tables. The results are presented by sample, by test, with tests 

reported in the following order: GC/MS, Chromatography, Metals and 

Inorganics. 

Each data table includes sample identification information, and when 

available and appropriate, dates sampled, received, authorized, prepared and • 

analyzed. The authorization data is the date when the project was defined by 

the client such that laboratory work could begin. The date prepared is 

typically the date an extraction or digestion was initiated. For volatile 

organic compounds in water, the date prepared is the date the screening of the 

sample was performed. 

Data sheets contain a listing of the parameters measured in each test, 

the analytical results and the Enseco reporting limit. Reporting limits are 

adjusted to reflect dilution of the sample, when appropriate. Solid and waste 

samples are reported on an "as received" basis, i.e. no correction is made for 

moisture content. 

Enseco-RMAL is no longer routinely blank-correcting analytical data. 

Uncorrected analytical results are reported, along with associated blank 

results, for all organic and metals analyses. Analytical results and blank 

results are reported for conventional inorganic parameters as specified in the 

method. This policy is described in detail in the Enseco Incorporated Quality 

Assurance Program Plan for Environmental Chemical Monitoring, Revision 3.3, 

May, 1989. 

In addition, surrogate recovery data is presented for all GC/MS analyses. 

The surrogate recovery is an indication of the affect of the sample matrix on 

the performance of the method. The results from the Standard Enseco QA/QC 

Program, which generates data which are independent of matrix effects, is 

given in Section IV. 

The analytical data reported are subject to the following limitations of 

the analytical methodology: 
P.10 

GC/MS 

Volatile Organics 

a) The cis- and trans-isomers of dichloroethylene cannot be 

distinguished using EPA Method 624. All dichloroethylene present is 

reported as trans-dichloroethylene. 

.Metals 

Arsenic, selenium and thallium are customarily determined by graphite 

furnace atomic absorption (GFAA). All mercury determinations are by cold 

vapor atomic absorption. All other metals are determined using Inductively 

Coupled Plasma Atomic Emission Spectroscopy (ICP). 

All metals nominal reporting limits are statistically determined by 

analyzing a reagent blank seven times on three non-consecutive days. The 

standard deviations from each group of analyses are then summed (reporting 

limit » three times the standard deviation of a blank). The ability to attain 

the quoted reporting limits is verified each quarter. Reporting limits above 

nominal values are often reported since sample matrix interferences must be 

compensated for by dilutions prior to analysis or by the use of Method of 

Standard Additions. All GFAA reporting limits and results are verified by 

spike recoveries and represent the lowest.attainable for each sample matrix. 

The metals reporting limits reported should not be viewed as quantitation 

limits. As recommended by the American Chemical Society Subcommittee on 

Environmental Analytical Chemistry (Analytical Chemistry 1980, 52, 2242-49), 

the Limit of Quantitation (LOQ) is equal to ten times the standard deviation 

of a blank or 3.3 times the reporting limit. 
P.11 ;\l)tn . Muai..Jll i 1— 

Anaivticai Ljooraiop 

ANALYTICAL RESULTS 

FOR 

AMERICAN PETROLEUM INSTITUTE 

ENSECO-RMAL NO. 006344 

OCTOBER 27, 1989 

Reviewed by: _v, U&L 

I /~ 

V 

Susan C. Wyat 

•rtf{~ 

Jeanne B. Howbert 

Enscci> Incorporated 

-i'-'')*" Yarrow Street 

Arvilila. r.i>inrj_o .Mil 11)2 

M>v42WiOll F.ix: ii.ij'J'l-TITl 
P.12 

Appendix IX Volatile Organics 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site A Tank Btms. Col. Tank 

Lab ID: 006344-0001-SA Enseco ID: 

Matrix: WASTE Sampled: 

Authorized: 31 AUG 89 Prepared: 

Parameter 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

Bromodichloromethane 

Bromoform 

Bromomethane • 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprene 

Chloroethane 

Chi orodibromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-chloropropane) 

EOB (1,2-Dibromoethane) 

Dibromomethane 

trans-1,4-Dichloro2-butene 

Di chlorodi f1uoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichloromethane 

1,2-Dichloropropane 

cis-1,3-Dichioropropene 

trans-1,3-Dichloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol 

Methacrylonitrile 

Methyl ethyl ketr-e 

4-Methyl-2-pentanone 

1050776 

30 AUG 89 

01 SEP 89 

esult 

ND 

ND 

ND 

ND 

ND 

57 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

57 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

/-M 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

•ng/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

:eived: 31 AUG 89 

ulyzed: 07 SEP 89 

Reporting 

Limit 

20 

200 

200 

200 

10 

10 

10 

10 

20 

10 

10 

10 

10 

20 

10 

10 

20 

10 

10 

10 

10 

20 

10 

10 

10 

10 

10 

10 

10 

10 

200 

10 

10 

20 

10 

200 

. 10 

20 

20 

(continued on followinq ->age) 

ND - Not detected 

NA * Not applicable 

Reported By: Diane Page Approved By: Jeff Lowry 

J 
P.13 

Appendix IX Volatile Organics (CONT.) 

Method 8240 

1ient Name: 

Client ID: 

Lab ID: 

latrix : 

,uthorized: 

'arameter 

American Petroleum Institute 

Site A Tank Btms. Col. Tank 

006344-0001-SA Enseco ID: 1050776 

WASTE Sampled: 30 AUG 89 

31 AUG 89 Prepared: 01 SEP 89 

Received: 

Analyzed: 

31 

07 

AUG 

SEP 

89 

89 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

1,1,1-Tri chloroethane 

1,1,2-Trichloroethane 

Trichloroethene 

Tri chlorofluoromethane 

1,2,3-TrichlorOpropane 

Vinyl acetate 

Vinyl chloride 

Total xylenes 

Toluene-d8 

4-Bromofluorobenzene 

(BFB1 

1,2-Di chloroethane-d4 

Result 

ND 

ND 

ND 

ND 

210 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

320 

104 

105 

97.3 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

% 

t. 

Reporting 

Limit 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

20 

20 

10 

ND •• Not detected 

NA - Not applicable 

Reported By: Diane Page Approved By: Jeff Lowry 
P.14 

„ i ient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum 

Site A Tank Btms. 

006344-0001-SA 

WASTE 

31 AUG 89 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Oichloroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Tri chloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromof1uorobenzene 

(BFB) 

1,2-0i chloroethane-d4 

0TC Volatile Organics 

TCLP Leachate 

Method 8240 

urn Institute 

. Col. Tank 

Enseco ID: 1050776 

Sampled: 30 AUG 89 

Prepared: 13 £'."• 89 

Result 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

7.7 

ND 

ND 

ND 

27 

ND 

98.8 

94.8 

107 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

Received: 31 AUG 89 

Analyzed: 19 SEP 89 

Reporting 

Limit 

4.4 

44 

2.2 

2.2 

2.2 

44 

2.2 

2.2 

4.4 

2.2 

2.2 

2.2 

2.2 

2.2 

2.2 

2.2 

2.2 

2.2 

2.2 

, --

--

ND = Not detected 

NA » Not applicable 

Reported By: Lisa Traut Approved By: Jeff Lowry 
P.15 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site A Tank Btms. Col. Tank 

006344-0001-SA Enseco ID: 1050776 

WASTE Sampled: 30 AUG 89 

31 AUG 89 Prepared: 06 SEP 89 

Received: 

Analyzed: 

31 

11 

AUG 

OCT 

89 

89 

Anthracene 

Benzo(a)anthracene 

8enzo(b)f1uoranthene 

Benzo(kmuoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

D ibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methylnaphthalene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitropnenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tribromophenol 

ND = Not detected 

NA - Not applicable 

Result 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

170 

78 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

54.9 

55.7 

71.3 

39.6 

38.6 

55.3 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

% 

% 

% 

% 

% 

Reporting 

Limit 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

30 

150 

150 

30 

Reported By: Marshall Tilbury Approved By: Jeff Lowry 
P.16 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

OTC 

American Petroleum 

Site A Tank Btms. 

006344-0001-SA 

WASTE 

31 AUG 89 

Pyridine 

Phenol 

bis(2-Chloroethyl)ether 

1,4-Dichlorobenzene 

1,2-Dichlorobenzene 

p-Cresol 

m _ p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlorobutadi ene 

2,4., 6-Tri chlorophenol 

2,4,5-Tri chlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tribromophenol 

Semivolatile Organic: 

TCLP Leachate 

Method 8270 

i Institute 

Col. Tank 

Enseco ID: 1050776 

Sampled: 30 AUG 

Prepared: 21 SEP 

Result 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NA 

NA 

NA 

NA 

NA 

NA 

89 

89 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

•q/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

r. 

% 

% 

% 

% 

% 

Received: ~-\ 

Analyzed: -2 

Reporting 

Limit 

0.22 

0.22 

0.22 

0.22 

0.22 

0.22 

0.22 

0.22 

0.22 

0.22 

1.1 

0.22 

0.22 

0.22 

1.1 

--

--

--

'--

--

AUG 89 

OCT 89 

ND = Not detected 

NA « Not applicable 

Reported By: Marshall Tilbury Approved By: Jeff Lowry 
P.17 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryl 1ium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

Metals 

Total Metals 

American Petroleum Institute 

Site A Tank Btms. Col. Tank 

006344-0001-SA Enseco ID: 1050776 

WASTE Sampled: 30 AUG 89 

31 AUG 89 Prepared: See Below 

Result 

Reporting Analytical 

Units Limit M 

ND 

ND 

ND 

3 

ND 

ND 

NO 

ND 

ND 

ND 

NO 

ND 

5 

ND 

ND 

ND 

ND 

ND 

ND 

25 

ND 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

10 

5 

0.5 

1 

0.2 

0.5 

30 

1 

1 

1 

5 

0.1 

4 

500 

0.5 

1 

500 

1 

11 

1 

1 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

Received: 31 AUG 89 

Analyzed: See Below 

.ical Prepared 

lod Date 

05 SEP 89 

05 SEP 89 

08 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

14 SEP 89 

05 SEP 89 

05 SEP 89 

08 SEP 89 

05 SEP 89 

05 SEP 89 

08 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

Analyzed 

Date 

18 SE? 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

17 SEP 89 

18 SEP 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

t 

m 

ND » Not detected 

NA - Not applicable 

Reported By: Fred Velasquez Approved By: Toni Lusk 
P.18 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

ir.?/MS Metals 

Total Metals 

American Petroleum Institute 

Site A Tank Btms. Col. Tank 

006344-0001-SA Enseco ID: 

WASTE Sampled: 

31 AUG 89 Prepared: 

1050776 

30 AUG 89 

See Below 

Received: 

Analyzed: 

Parameter 

Osmium (189) 

Result 

ND 

Reporting Analytical 

Units Limit Method 

31 AUG 89 

See Below 

Prepared 

Date 

Analyzed 

Date 

mg/kg 0.1 RMAL 07 OCT 89 14 OCT 39 

ND = Not detected 

NA - Not applicable 

-Reported By: Scott Heideman 

Approved By: Toni Tallarico 
P.19 

Metals 

TCLP Leachate 

Name: 

ID: 

CIient 

Client 

Lab ID: 

Matrix: 

Authorized 

American Petroleum Institute 

Site A Tank Btms. Col. Tank 

006344-0001-SA Enseco ID 

WASTE 

31 AUG 89 

1050776 

Sampled: 30 AUG 89 Received: 

Prepared: See Below Analyzed: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Silver 

Mercury 

Selenium 

Result Units 

Reporting Analytical 

Limit Method 

ND 

7.5 

ND 

0.08 

ND 

ND 

ND 

ND 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

0.6 

0.06 

0.03 

0.06 

0.3 

0.06 

0.003 

0.06 

200. 

200. 

200. 

200. 

200. 

200.7 

7471 

270.2 

31 AUG 89 

See Below 

Prepared 

Date 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

Analyzed 

Date 

20 SEP 89 

20 SEP 89 

20 SEP 89 

20. SEP 89 

20. SEP 89 

20 SEP 89 

14 SEP 89 

18 SEP 89 

1 

1 

ND - Not detected 

NA - Not applicable 

Reported By: Sandra Jones Approved By: Toni Lusk 
P.20 

General Inorganics 

Client Name: American Pel 

Client ID: . Site A 

Lab ID: 006344-

Matrix: WASTE 

Authorized: 31 AUG 

Parameter 

Chloride 

Cyanide, Reactive 

Ignitability 

Non-Volatile Oil 

Volatile Oil 

Oil 

Water 

Solids 

pH 

Sulfide, Reactive 

Tank 

•0001 

89 

iroleum 

Btms. C 

•SA E 

Result 

21600 

ND 

55 

16.8 

2.3 

19.1 

71.1 

9.0 

6.9 

1.9 

Institute 

ol. Tank 

nseco ID: 

Sampled: 

Prepared: 

Units 

mg/kg 

mg/kg 

deg. F 

ev 

% 

% 

tv 

10 

% 

units 

mg/kg 

1050776 

30 "JG 89 

See ielow 

Reporting 

Limit 

15 

0.1 

--

0.1 

.0.1 

0.1 

0.1 

0.1 

--

0.5 

Received: 

Analyzed: 

Analytical 

Method 

300.0 Mod. 

EPA-OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/0SW 

31 

See 

AUG 

Bel 

89 

ow 

Prepared 

Date 

1 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

SEP 89 

Analvzea 

Date 

13 SEP 89 

08 SEP 39 

12 OCT .39 

06 OCT 39 

06 OCT 89 

06 OCT 39 

06 OCT 89 

06 OCT 89 

23 SEP 89 

08 SEP 39 

1 

] 

Note o : This test is unreliable for any sample other than a 

non-aqueous liquid. 

Note 1 : Sample hazardous due to ignitability. 

ND = Not detected 

NA = Not applicable 

Reported By: Blake Besser Approved By: Tammy Bailey 

] 
P.21 

'A ient Name: 

Client ID: 

'.ab ID: 

Matrix: 

Authorized: 

Parameter 

Appendix IX Volatile Organics 

Method 8240 

American Petroleum Institute 

Site C Crude Tank Bottoms 

006344-0002-SA Enseco ID: 1050777 

WASTE Sampled: 30 AUG 89 

31 AUG 89 Prepared: 01 SEP 89 

Received: 

Analyzed: 

31 

07 

AUG 

SEP 

89 

89 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

Bromodi chloromethane 

Bromoform 

3romomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprene 

Chloroethane 

Chlorodi bromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-cnloropropane) 

EDB (1,2-Dibromoethane) 

Dibromomethane 

traps-l,4-Dichloro2-butene 

Di chlorodi f1uoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichloromethane 

1,2-Dichl oropropane 

ci s-1,3-Di ch1oropropene 

trans -1,3-Di chloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isdbutyl alcohol 

Methacrylonitrile 

Methyl ethyl ketone 

4-Methyl-2-pentanone 

Result 

ND 

ND 

ND 

ND 

ND 

180 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

NO 

NO 

NO 

NO 

NO 

ND 

220 

NO 

ND 

ND 

ND 

ND 

NO 

NO 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg * 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Reporting 

Limit 

20 

200 

200 

200 

10 

10 

10 

10 

20 

10 

10. 

10 

10 

20 

10 

10 

20 

10 

10 

10 

10 

20 

10 

10 

10 

10 

10 

10 

10 

10 

200 

10 

10 

20 

10 

200 

10 

20 

20 

(continued on following page) 

Reported By: Diane Page Approved By: Jeff Lowry 

ND - Not detected 

NA * Not applicable 
P.22 

Appendix IX Volatile Organics 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site C Crude Tank Bottoms 

Lab ID: 006344-0002-SA 

Matrix: WASTE 

Authorized: 31 AUG 89 

Parameter 

Styrene 

I.1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

1,1,1-Tri chloroethane 

1,1,2-Trichloroethane 

Trichloroethene 

Trichlorofluoromethane 

1,2,3-Trichloropropane 

Vinyl acetate 

Vinyl chloride 

Total xylenes 

Toluene-d8 

4-Bromoflucrobenzene 

(BFB) 

l,2-Dichloroethane-d4 

ND - Not detected 

NA » Not applicable 

Reported By: Diane Page 

Enseco ID: 1050777 

Samol=-: 30 AUG 89 

Prepared: 01 SEP 89 

Result 

ND 

ND 

ND. 

ND 

530 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

510 

109 

107 

98.5 

(CONT.) 

i 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

7. 

fa 

'-. .-" V"-

• 

deceived: 31 AUG 89 

Analyzed: 07 SEP 89 

Reporting 

Limit 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

20 

20 

10 

--

Approved By: Jeff Lowry 
P.23 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum 

Site C Crude Tank 

006344-0002-SA 

WASTE 

31 AUG 89 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichloroethene 

Isobutyl alcohol 

Chloroform 

1,2~Dichloroethane 

2-Butanone . 

1,1,1 -Tri chloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromofluorobenzene 

(BFB1 

1,2-Di chloroethane-d4 

OTC Volatile Organics. 

TCLP Leachate 

Method 8240 

urn Institute 

k Bottoms 

Enseco ID: 1050777 

Sampled: 30 AUG 89 

Prepared: 13 SEP 89 

Result 

NO 

ND 

NO 

ND 

ND 

NO 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

4.6 

ND 

ND 

ND 

13 

NO 

95.6 

95.9 

107 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

Received: 31 AUG 89 

Analyzed: 19 SEP 89 

Reporting 

Limit 

4.2 

42 

2.1 

2.1 

2.1 

42 

2.1 

2.1 

4.2 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

--

--

--

ND » Not detected 

NA - Not applicable 

Reported By: Lisa Traut Approved By: Jeff Lowry 

] 
P.24 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

Client Name: American Petroleum Institute 

Client ID: Site C Crude Tank Bottoms 

Lab ID: 006344-0002-SA Enseco ID: 

Matrix: WASTE Sampled: 

Authorized: 31 AUG 89 Prepared: 

Parameter 

Anthracene 

3enzo(a)anthracene 

Benzo(bj f1uoranthene 

Benzolkjfluoranthene 

3enzo(a)pyrene 

b.is(2-EthylhexyT) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Dibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichl.orobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methyl naphtha! ene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitrophenol 

4-Nitrophenol 

Phenol . 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

ND = Not detected 

NA = Not applicable 

Reported By: Marshall Tilbury Approved By: Jeff Lowry 

1C ..'77 

30 iUG 89 

06 SEP 89 

esult 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

ND 

NO 

ND 

ND 

ND 

NO 

NO 

ND 

NO 

ND 

140 

40 

ND 

NO 

ND 

NO 

NO 

ND 

ND 

ND 

NO 

ND 

ND 

71.6 

56.7 

66.8 

51.1 

46.0 

48.1 

Rec 

Ane 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

tv 

% 

% 

% 

% 

% 

:eived: 31 AUG 

ilyzed: 12 OCT 

Reporting 

Limit 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

--

40 

40 

40 

200 

200 

40 

--

--

--

--

--

89 

89 

\ 
P.25 

! 

1 

i 

I 

i 

1 

1 

1 1 

1 

1 

OTC Semivolatile Organic; 

TCLP Leachate 

Method 8270 

Client Name: American Petroleum Institute 

Client ID: Site C Crude Tank Bottoms 

Lab ID: 006344-0002-SA Enseco ID: 1050777 

Matrix: WASTE Sampled: 30 AUG 

Authorized: 31 AUG 89 Prepared: 21 SEP 

Parameter Result 

Pyridine ND 

Phenol ND 

bis(2-Chloroethyl)ether ND 

1,4-Dichlorobenzene ND 

1,2-Dichlorobenzene ND 

o-Cresol ND 

m & p-Cresol(s) ND 

Hexachloroethane ND 

Nitrobenzene ND 

Hexachlorobutadiene NO 

2,4,6-Trichlorophenol ND 

2,4,5-Trichlorophenol ND 

2,4-Dinitrotoluene ND 

Hexachlorobenzene ND 

2,3,4,6-Tetrachlorophenol ND 

Pentachlorophenol ND 

Nitrobenzene-d5 NA 

2-Fluorobiphenyl NA 

Terphenyl-dl4 NA 

PhenoT-d5 NA 

2-Fluorophenol NA 

2,4,6-Tribromophenol NA 

ND » Not detected 

NA - Not applicable 

89 

89 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

fa 

fa 

fa 

Received: 31 AUG 89 

Analyzed: 02 OCT 89 

Reporting 

Limit 

--

2.0 

2.0 

2.0 

2.0 

2.0 

2.0 

2.0 

2.0 

2.0 

2.0 

10 

2.0 

2.0 

2.0 

1 A 10 

--

• " 

• * • 

** *• 

" ** 

Reported By: Marshall Tilbury Approved By: Jeff Lowry 

. 

• . 
Metals 

Total Metals 

P.26 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryl l.i umr 

Cadmium 

Calcium

 := 

Chromium*5 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

American Petroleum Institute 

Site C Crude Tank Bottoms 

006344-0002-SA Enseco ID: 

WASTE Sampled: 

31 AUG 89 

1050777 

30 AUG 89 

Prepared: See Below 

Received: 

Analyzed: 

Result • Units 

13 

ND 

o.: 

70 

ND 

ND 

1340 

5 

ND 

33 

140 

ND 

5 

ND 

ND 

ND 

9510 

ND 

ND 

4 

63 

Reporting Analytical 

Limit Method 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

10 

5 

0.5 

• 1 

0.2 

0.5 

30 

1 

1 

1 

5 

0, 

4 

500 

0 

1 

500 

1 

11 

1 

1 

1 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

•7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

31 AUG 89 

See Below 

Preoared 

Date 

05 

05 

08 

05 

05 

05 

05 

05 

05 

05 

05 

14 

05 

05 

08 

05 

05 

08 

05 

05 

05 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

Analyzed 

Date 

18 SEP 39. 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

17 SEP 89 

18 SEP 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

_ 

ND = Not detected 

NA - Not applicable 

Reported By: Fred Velasquez Approved By: Toni Lusk 
P.27 

ICP/MS Metals 

Total Metals 

Client Name: American Petroleum Institute 

Client ID: Site C Crude Tank Bottoms 

Lab ID: 006344-0002-SA Enseco ID: 1050777, 

Matrix: WASTE • Sampled: 30 AUG 89 

Authorized: 31 AUG 89 Prepared: See Below 

Received: 31 AUG 89 

Analyzed: See Below 

Parameter 

Osmium (189) 

Result 

ND 

Units 

mg/kg 

Reporting Analytical 

Limit Method 

Prepared 

Date 

Analyzed 

Date 

0.1 RMAL 07 OCT 89 14 OCT 89 

ND » Not detected 

> NA - Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.28 

Metals 

TCLP Leachate 

Client Name: American Petroleum Institute 

Client ID: Site C Crude Tank Bottoms 

Lab ID: 006344-0002-SA Enseco ID: 1050777 

Matrix: WASTE Sampled: 30 AUG 89 Received: 31 AUG 89 

Authorized: 31 AUG 89 Prepared: See Below Analyzed: See Below 

Parameter Result Units 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead. 

Silver 

Mercury 

Selenium 

ND 

24 

ND 

ND 

2 

ND 

ND 

ND 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

Reporting 

Limit 

2 

0.2 

0.1 

0.2 

1 

0.2 

0.008 

0.08 

Analytical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

Prepared 

Date 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

Analyzed 

Date 

20 SEP 39 

20 SEP 39 

20 SEP 39 

20 SEP 89 

20 SEP 89 

20 SEP 89 

18 SEP 89 

18 SEP 89 

J 

J 

ND = Not detected 

-\ NA » Not applicable 

Reported By: Sandra Jones Approved By: Toni Lusk 

1 
General Inorganics 

P.29 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site C Crude Tank Bottoms 

006344-0002-SA Enseco ID: 

WASTE Sampled: 

31 AUG 89 Prepared: 

1050777 

30 AUG 89 

See Below 

Received: 

Analyzed: 

Chloride 

Cyanide, Reactive 

Ignitability 

Non-Volatile Oil 

Volatile Oil 

Oil 

Water 

Solids 

OH 

Sulfide, Reactive 

Result Units 

Reporting Analytical 

Limit Method 

14900 

ND 

66 

17.7 

1.5 

19.2 

71.4 

10.8 

6.9 

ND 

mg/kg 

mg/kg • 

deg. F 

0/ 

10 

0/ 

/a 

Of 

to 

% 

0/ 

to 

units 

•ng/kg 

15 

0.1 

--

0.1 

0.1 

0.1 

0.1 

0.1 

0.5 

300.0 Mod 

EPA-OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/OSW 

'31 AUG 39 

See Below 

Prepared 

Date 

01 SEP 89 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

Anai vzeo 

Date 

13 

08 

39 

39 

12 OCT 89 

06 OCT 89 

06 OCT 89 

06 OCT 89 

06 OCT 89 

06 OCT 89 

23 SEP 89 

08 SE? 99 

o 1 

Note o : This test is unreliable for any sample other than a 

non-aqueous liquid. 

Note 1 : Sample hazardous due to ignitability. 

ND = Not detected 

NA = Not applicable 

Reported By: Blake Besser Approved By: Tammy Bailey 
P.30 

FOR 

AMERICAN PETROLEUM INSTITUTE 

ENSECO-RMAL NO. 00629 9 

OCTOBER 27, 1989 

Rocky Mountain 

Anaivncai Laboratorv 

ANALYTICAL RESULTS JUTlSCCO 

Reviewed by: ^•^•vJHi^-

V iMjULJ^Jht^C 

Jeanne B. Howbert 

Enseco Incorporated 

j"-)^*" Yarrow Street 

^ Arvaua. (.".oiorado M>0<>2 

j 303/421-ooU Fa:<: 303-4M-7171 
P.31 

Appendix IX Volatile Organics 

Method 8240 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site #3 Produced Water Tank 

006299-0003-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

Bromodichloromethane 

Bromoform 

Bromomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprene 

Chloroethane 

Chlorodibromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-chloropropane) 

EDB (1,2-Dibromoethane) 

Dibromomethane 

trans-1,4-Dichloro2-butene 

Di chlorodi f1uoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Oichloroethene 

Dichloromethane 

1,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol 

Methacrylonitr.ile 

Methyl ethyl ketone 

4-Methyl-2-pentanone 

1050767 

24 AUG 89 

01 SEP 89 

esult 

ND 

ND 

NO 

NO 

ND 

270 

ND 

NO 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

NO 

NO 

ND 

600 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

Received: 25 AUG 

Analyzed: 06 SEP 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Reporting 

Limit 

200 

2000 

2000 

2000 

100 

100 

100 

100 

200 

100 

100 

100 

100 

200 

100 

100 

200 

100 

100 

100 

100 

200 

100 

100 

100 

100 

100 

100 

100 

100 

2000 

100 

100 

200 

100 

2000 

100 

200 

200 

89 

89 

NO - Not detected 

NA > Not applicable 

Reported By: Diane Page 

(continued on following page) 

Approved By: Jeff Lowry 
P.32 

Appendix IX Volatile Organics 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site #3 Produced Water Tank 

Lab ID: 006299-0003-SA Enseco ID: 1050767 

Matrix: WASTE Sampled: 24 AUG 89 

Authorized: 28 AUG 89 Prepared: 01 SEP 89 

Parameter Result 

Styrene ND 

1,1,1,2-Tetrachloroethane ND 

1,1,2,2-Tetrachloroethane NO 

Tetrachloroethene NO 

Toluene 630 

1,1,1-Trichloroethane ND 

1,1,2-Trichloroethane NO 

Trichloroethene ND 

Trichlorofluoromethane ND 

1,2,3-Trichloropropane ND 

Vinyl acetate ND 

Vinyl chloride ND 

Total xylenes 790 

Toluene-d8 103 

4-Bromof1uorobenzene 

(BFB) 95.6 

1,2-Dichloroethane-d4 94.1 

ND > Not detected 

NA « Not applicable 

(CONT.) 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

f. 

% 

% 

Received: 25 AUG 89 

Analyzed: 06 SEP 89 

Reporting 

Limit 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

200 

200 

100 

. . 

--

' 

Reported By: Diane Page Approved By: Jeff Lowry 
P.33 

OTC Volatile Organics 

TCLP Leachate 

Method 8240 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site #3 Produced Water Tank 

006299-0003-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

1050767 

24 AUG 89 

13 SEP 89 

Received: 25 AUG 89 

Analyzed: 19 SEP 89 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichlbroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Tri chloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Tri chloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromofluorobenzene 

(BFB) 

1,2-Di chloroethane-d4 

suit 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

12 

ND 

ND 

ND 

20 

ND 

95.1 

91.8 

109 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

Reporting 

Limit 

3.2 

32 

1.6 

1.6 

1.6 

32 

1.6 

1.6 

3.2 

1.6 

1.6 

1.6 

1.6 

1.6 

1.6 

1.6 

1.6 

1.6 

1.6 

--' 

--

--

ND - Not detected 

NA - Not applicable 

Reported By: Lisa Traut Approved By: Jeff Lowry 
P.34 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site #3 Produced Water Tank 

006299-0003-SA Enseco ID: 

WASTE 

28 AUG 89 

1050767 

1 

Anthracene 

Benzo(a)anthracene 

Benzo(b)f1uoranthene 

Benzolk)fluoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

D ibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Di chlorobenzene 

1,4-Di chlorobenzene 

Diethyl phthalate 

7,12-D1methylbenzanthracene 

Dimethyl phthalate 

Di-n-octyi phthalate 

Fluoranthene 

Indene 

1-Methylnaphthalene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol . 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitropnenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-FluorobiphenylTerphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

ND • Not detected 

NA - Not applicable 

Reported By: Belinda Guerra 

Sampled: 24 AUG 

Prepared: 05 SEP 

Result 

ND 

ND 

NO 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

110 

83 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

89 F 

89 / 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Received: 

Analyzed: 

25 AUG 

02 OCT 

89 

89 

Reporting 

Limit 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

200 

200 

40 

79.4 

80.8 

100 

56.0 

52.8 

50.0 

fa 

fa 

% 

% 

fa 

f. 

Approved- By: Jeff Lowry 

] 
P.35 

OTC Semivolatile Organics 

TCLP Leachate 

Method 8270 

Client Name: American Petroleum Institute 

Client ID: Site #3 Produced Water Tank 

Lab ID: 006299-0003-SA E"?eco ID: 1050767 

Matrix: WASTE :mp"ed: 24 AUG 89 

Authorized: 28 AUG 89 -pared: 21 SEP 89 

Parameter 

Pyridine 

Phenol 

bi s(2-Chloroethyl)ether 

1,4-Dichlorobenzene 

1,2-Dichlorobenzene 

o-Cresol 

m & p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlor jtadiene 

2,4,6-Tri ,

;orophenol 

2,4,5-Tri cnlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl -<114 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

Received: 25 AUC 39 

Analyzed: 04 OCT 89 

•suit 

ND 

ND 

ND 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

NO 

101 

68.4 

71.8 

62.1 

62.8 

65.5 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

% 

% 

fa 

Reporting 

L i - t 

0.049 

0.049 

0.049 

0.049 

0.049 

0.049 

0.049 

0.049 

0.049 

0.049 

0.24 

0.049 

0.049 

0.049 

0.24 

--

--

--

--

--

--

ND - Not detected 

NA - Not applicable 

Reported By: Dan Albritton Approved By: Jeff Lowry 
P.36 

Client Name: American Petroleum 

Client ID: Site #3 

Lab ID: 006299-

Matrix: WASTE 

Authorized: 28 AUG 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury . 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

ND - Not detected 

NA • Not applicable 

Metals 

Total Metals 

Institute 

Produced Water Tank 

0003-SA 

89 

Result 

974 

NO 

10 

180 

ND 

3 

35500 

54 

4 

190 

970 

ND 

61 

ND 

ND 

ND 

9420 

ND 

ND 

5 

370 

Reported By: Fred Velasquez 

inseco ID: 

Sampled: 

Prepared: 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg' 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

1050767 

24 AUG 89 

See Below 

Reporting 

Limit 

20 

10 

1 

2 

0.4 

1 

40 

2 

2 

2 

10 

0.1 

8 

1000 

5 

2 

1000 

10 

11 

2 

2 

, 

Received: 

Analyzed: 

Analytical 

Method 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

Approved By: Tammy Bailey 

25 AUG 

See Bel 

89 

ow 

Prepared 

Date 

05 

05 

06 

05 

05 

05 

05 

05 

05 

05 

05 

01 

05 

05 

06 

05 

05 

06 

05 

05 

05 

SEP 

SEP 

OCT 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

OCT 

SEP 

SEP 

OCT 

SEP 

SEP 

SEP 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

Ane ilvzed 

Date 

18 

18 

10 

18 

18 

18 

18 

18 

18 

18 

18 

11 

18 

18 

10 

18 

18 

10 

18 

18 

18 

SEP 

SEP 

OCT 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

SEP 

OCT 

SEP 

SEP 

OCT 

SEP 

SEP 

SEP 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 

89 
P.37 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

ICP/MS Metals 

Total Metals 

American Petroleum Institute 

Site #3 Produced Water Tank 

006299-0003-SA Enseco ID: 

WASTE Sampled: 

.28 AUG 89 Prepared: 

1050767 

24 AUG 39 

See Below 

Received: 25 "JG 89 

Analyzed: See .elow 

Parameter 

Osmium (189) 

Result Units 

Reporting Analytical 

Limit Method 

Prepared 

Date 

Analyzed 

Date 

NO mg/kg M RMAL 07 OCT 89 14.OCT 89 

ND * Not detected 

NA - Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.38 

Metals 

TCLP Leachate 

Client Name: American Petroleum Institute 

Client ID: Site #3 Produced Water Tank 

.ab ID 

Matrix 

006299-0003-SA Enseco ID: 1050767 

WASTE Sampled: 24 AUG 89 Received: 25 AUG 89 Authorized: 28 AUG 89 Prepared: See Below Analyzed: See Below 

Reporting Analytical Prepared Analyzed 

Parameter Result Units Limit Method Date Date 

Arsenic ND mg/L 0.6 200.7 14 SEP 89 20 SEP 89 

Barium 0.51 mg/L 0.06 200.7 14 SEP 89 20 SEP 89 

Cadmium ND mg/L 0.03 200.7 14 SEP 89 20 SEP 89 

Chromium NO mg/L 0.06 200.7 14 SEP 89 20 SEP 89 

Lead NO mg/L 0.3 200.7 14 SEP 89 20 SEP 89 

Silver ND mg/L 0.06 200.7 14 SEP 89 20 SEP 89 

Mercury NO mg/L 0.004 7471 . 14 SEP 89 14 SEP 89 

Selenium ND mg/L 0.07 270.2 14 SEP 89 18 SEP 89 

ND - Not detected 

NA - Not applicable 

Reported By: Sandra Jones Approved By: Tammy Bailey 
P.39 

General Inorganics 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Chloride 

American Pe 

Site #3 

006299-

WASTE 

28 AUG 

Cyanide, Reactive 

Ignitability 

Non-Volatile 

Volatile Oil 

Oil 

Water 

Solids 

pH 

Oil 

Sulfide, Reactive 

troleum Institute 

Produced Water Tank 

0003 

89 

-SA Enseco M . 

Result 

8510 

ND 

68 

22.1 

4.1 

26.2 

33.0 

45.7 

8.3 

34 

Sampl 

Prepar. : 

Units 

mg/kg 

mg/kg 

deg. F 

f. 

f. 

fa 

% 

fa 

units 

mg/kg 

1050767 

24 AUG 89 

See Below 

Reporting 

Limit 

15 

0.1 

--

0.1 

0.1 

0.1 

0.1 

0.1 

--

0.5 

Received: 

Analyzed: 

Analytical 

Method 

300.0 Mod. 

EPA-OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/OSW 

25 

See 

AUG 

Bel 

89 

ow 

Prepared 

Date 

07 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

SEP 89 

Analyzed 

Date 

13 SEP 89 

08 SEP 89 

10 OCT 89- ol 

19 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

11 SEP 89 

08 SEP 89 

Note o : This test is unreliable for any sample other than a 

non-aqueous liquid. 

Note 1 : Sample 3 is hazardous due to ignitability for flashpoint. 

NO - Not detected 

NA - Not applicable 

Reported By: Blake Besser Approved By: Tammy Bailey 
P.40 

Appendix IX Volatile Organics 

Method 8240 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site #1 Crude Tank Bottoms 

006299-0001-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

Bromodichloromethane 

Bromoform 

Bromomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlbroprene 

Chloroethane 

Chlorodibromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-chloropropane) 

EDB (1,2-Dibromoethane) 

Dibromomethane 

trans-1,4-Dichloro2-butene 

Di chlorodi f1uoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichloromethane 

1,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans -1,3-Di chloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol 

Methacrylonitrile 

Methyl ethyl ketone 

4^Methyl-2-pentanone 

1050765 

24 AUG 89 

01 SEP 89 

esult 

ND 

NO 

ND 

ND 

ND 

250 

ND 

ND 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

NO 

NO 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

240 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

Received: 25 AUG 89 

An 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

ilyzed: 06 SEP 89 

Reporting 

Limit 

100 

1000 

1000 

1000 

50 

50 

50 

50 

100. 

50 

50 

50 

50 

100 

50 

50 

100 

50 

50 

50 

50 

100 

50 

50 

50 

50 

50 

50 

50 

50 

1000 

50 

50 

100 

50 

1000 

50 

100 

100 

ND - Not detected 

NA - Not applicable 

Reported By: Diane Page 

(continued on following page) 

Approved By: Jeff Lowry 
P.41 

Appendix IX Volatile Organics 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site #1 Crude Tank Bottoms 

Lab ID: 006299-0001-SA Enseco ID: 1050765 

Matrix: WASTE Sampled: 24 AUG 89 

Authorized: 28 AUG 89 Prepared: 01 SEP 89 

Parameter Result 

Styrene ND 

1,1,1,2-Tetrachloroethane ND 

U1,2,2-Tetrachloroethane ND 

Tetrachloroethene ND 

Toluene 470 

1,1,1-Trichloroethane ND 

1,1,2-Trichloroethane ND 

Trichloroethene ND 

Trichlorofluoromethane ND 

1,2,3-Trichloropropane ND 

Vinyl acetate ND 

Vinyl chloride ND 

Total xylenes 570 

Toluene-c 

4-Bromofl 

(BFB; 

1,2-Dichl 

8 104 

uorobenzene 

101 

oroethane-d4 91.1 

(CONT.) 

, 

Received: 25 AUG 89 

Analyzed: 06 SEP 89 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

fa 

fa 

Reporting 

Limit 

50 

50 

50 

50 

50 

50 

50 

50 

50 

50 

100 

100 

50 

--

--

t' 

ND = Not detected 

NA - Not applicable 

Reported By: Diane Page Approved By: Jeff Lowry 
P.42 

OTC Volatile Organics 

TCLP Leachate 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site #1 Crude Tank Bottoms 

Lab ID: 006299-0001-SA Enseco ID: 1050765 

Matrix: WASTE Sampled: 24 AUG 89 

Authorized: 28 AUG 89 Prepared: 13 SEP 89 

Parameter Result 

Vinyl chloride ND 

Acrylonitrile ND 

Methylene chloride 3.2 

Carbon disulfide ND 

1,1-Dichloroethene ND 

Isobutyl alcohol NO 

Chloroform ND 

1,2-Dichloroethane ND 

2-Butanone NO 

1,1,1-Trichloroethane ND 

Carbon tetrachloride ND 

Trichloroethene ND 

1,1,2-Trichloroethane ND 

Benzene 20 

1,1,1,2-Tetrachloroethane NO 

1,1,2,2-Tetrachloroethane ND 

Tetrachloroethene ND 

Toluene 37 

Chlorobenzene ND 

Toluene-d8 105 

4-Bromof1uorobenzene 

(BFB) 99.5 

l,2-0ichloroethane-d4 100 

ND - Not detected 

NA « Not applicable 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

fa 

fa 

fa 

Received: 25 AUG 39 

Analyzed: 15 SEP 89 

Reporting 

Limit 

4.2 

42 

2.1 

2.1 

2.1 

42 

2.1 

2.1 

4.2 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

2.1 

. . 

Reported By: Lisa Traut Approved By: Jeff Lowry 

^1 

t 
P.43 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

American Petroleum Institute 

Site #1 Crude Tank Bottoms 

006299-0001-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

Anthracene 

Benzo(a)anthracene 

Benzo(b)fluoranthene 

Benzo(k)fluoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Dibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Oimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methylnaphthalene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol 

m & p-Cresol(s) 

2,4-Dimethyl phenol 

2,4-Dinitropnenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

ND - Not detected 

NA - Not applicable 

Reported By: Belinda Guerra 

1050765 

24 AUG 89 

05 SEP 89 

lesult 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

NO 

ND 

180 

110 

42 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

65.6 

62.4 

75.4 

67.4 

65.4 

68.9 

Rec 

An< 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

fa 

fa 

% 

% 

1 

% 

:eived: 25 AUG 

ilyzed: 02 OCT 

Reporting 

Limit 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

--

40 

--

40 

40 

40 

200 

200 

40 

--

--

--

--

Approved By: Jeff Lowry 

89 

89 
P.44 

1 

OTC 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Site #1 Crude 1 

006299-0001-SA 

WASTE 

28 AUG 89 

Pyridine 

Phenol 

bis(2-Chloroethyl)ether 

1,4-Di chlorobenzene 

1,2-Di chlorobenzene 

o-Cresol 

m & p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlorobutadi ene 

2,4,6-Tri chlorophenol 

2,4,5-Tri chlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

Semivolatile Organics 

TCLP Leachate 

Method 8270 

Institute 

Bottoms 

Enseco.ID: 1050765 

Sampled: 24 AUG 89 

Prepared: 21 SEP 89 

Result 

ND 

0.035 

NO 

NO 

NO 

0.040 

0.075 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

93.8 

81.9 

83.4 

80.0 

77.5 

82.0 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

X 

% 

% 

% 

fa 

Received: 25 AUG 89 

Analyzed: 04 OCT 89 

Reporting 

Limit 

0.029 

0.029 

0.029 

0.029 

0.029 

0.029 

0.029 

0.029 

0.029 

0.029 

0.14 

0.029 

0.029 

0.029 

0.14 

.. 

--

--

--

--

--

NO - Not detected 

NA - Not applicable 

Reported By: Dan Albritton Approved By: Jeff Lowry 
P.45 

Metals 

Total Metals 

Name: 

ID: 

Client 

Client 

Lab ID: 

Matrix: 

Authorized 

American Petroleum Institute 

Site #1 Crude Tank Bottoms 

006299-0001-SA Enseco ID: 1050765 

WASTE Samoled: 24 AUG 89 

28 AUG 89 Prepared: See Below 

Received: 

Analyzed: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

Result 

Reporting Analytical 

Units Limit Method 

35 

ND 

2 

23 

ND 

NO 

1230 

5 

ND 

14 

27 

ND 

16 

ND 

ND 

ND 

2040 

ND 

ND 

3 

34 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

10 

5 

1 

1. 

0. 

0. 

30 

1 

1 

1 

5 

0. 

4 

500 

0, 

1 

500 

10 

11 

1 

1 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

25 AUG 89 

See Below 

Prepared 

Date 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

01 SEP 89 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

Analyzed 

Date . 

18 SEP 89-

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

ll'SEP 89 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

ND - Not detected 

NA « Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
I 

P.46 

1 

ICP/MS Metals 

Total Metals 

Client Name: American Petroleum Institute 

Client ID: Site #1 Crude Tank Bottoms 

iff- ?: 2Sf|f9 - °001 -

S A £nseco ID: 1050765 Matrix: WASTE SamDled* 24 AUG 89 

Authorized: 28 AUG 89 Prepaid. See Below 

Received: 25 AUG 89 

Analyzed: See Below 

Parameter 

Osmium (189) 

Result . Units 

Reporting Analytical 

Limit Method 

Prepared 

Date 

Analyzed 

Date 

NO mg/kg 0.1 RMAL 07 OCT 89 14 OCT 89 

ND - Not detected 

NA - Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.47 

Metals 

TCLP Leachate 

Client Name: 

Client ID: 

Lab ICMatri: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Silver 

Mercury 

Selenium 

American Petroleum 

Site #1 Crude Ta* 

006299-0001-SA 

V ~TE-

,UG 89 

Result 

Institute 

3ottoms 

nseco ID: 

Sampled: 

Prepared: 

Units 

1050765 

24 AUG 89 

See Below 

Reporting Analytical 

Limit M< " 

ND 

0 

ND 

NO 

4.2 

NO 

ND 

ND 

99 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

0.6 

0.06 

0.03 

0.06 

0.3 

0.06 

0.004 

0.07 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

Received: 

A. yzed: 

ical 

od 

25 AL. 89 

See Below 

Prepared 

Date 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

14 SEP 89 

Analyzed 

Oate 

20 SEP 89 

20 SEP 89 

20 SEP 89 

20 SEP 89 

20 SEP 89 

20 SEP 89 

14 SEP 89 

18 SEP 89 

ND - Not detected 

NA • Not applicable 

Reported By: Sandra Jones Approved By: Tammy Bailey 
General Inorganics 

P.48 

Client Name: American Petroleum 

Client ID: Site #1 

Lab ID: 006299-

Matrix: WASTE 

Authorized: 28 AUG 

Parameter 

Chloride 

Cyanide, Reactive 

Ignitability 

Non-Volatile Oil 

Volatile Oil 

Oil 

Water 

Solids 

PH 

Sulfide, Reactive 

Crude Tank 

0001 

89 

•SA E 

Result 

6590 

ND 

72 

27.0 

8.3 

35.3 

48.1 

18.0 

8.0 

1.2 

Institute 

Bottoms 

nseco ID: 

Sampled: 

Prepared: 

Units 

mg/kg 

mg/kg 

deg. F 

fa 

% 

% 

% 

% 

units 

mg/kg 

1050765 

24 AUG 89 

See Below 

Reporting 

Limit 

15 

0.1 

--

0.1 

0.1 

0.1 

0.1 

0.1 

--

0.5 

Received: 

Analyzed: 

Analytical 

Method 

300.0 Mod. 

EPA-OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/0SW 

25 

See 

AUG 

Bel 

89 

ow 

Prepared 

Date 

07 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

SEP 89 

Analyzed 

Date 

13- SEP 89 

08 SEP 89 

09 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

11 SEP 89 

08 SEP 89 

0 1 

Note o : This test is unreliable for any sample other than a 

non-aqueous liquid. 

Note 1 : Sample 1 is hazardous due to ignitability for flashpoint. 

NO - Not detected 

NA - Not applicable 

Reported By: Blake Besser Approved By: Tammy Bailey 
P.49 

Name: 

ID: 

Client 

CIient 

Lab ID 

Matrix 

Authorized 

Appendix IX Volatile Organics 

Method 8240 

American Petroleum Institute 

Site #1 3S Pit Skimmings 

006299-^05-SA Enseco ID: 1050769 

WASTE Sampled: 24 AUG 89 

28 AUG b9 Prepared: 01 SEP 89 

Received: 

Analyzed: 

25 

06 

AUG 

SEP 

Parameter 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene. 

Bromod i chloromethane 

Bromoform 

Bromomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprene 

Chloroethane 

Chlorodi bromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-chloropropane) 

EDB (1,2-Dibromoethane) 

Dibromomethane 

trans-1,4-Dichloro2-butene 

Di chlorodi f1uoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichloromethane 

1,2-Di chloropropane 

c i s-1,3-Di chloropropene 

trans-1,3-Dichloropropene 

1,4-Oioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol 

Methacrylonitrile 

Methyl ethyl ketone 

4-Methyl-2ipentanone 

Result 

ND 

ND 

ND 

NO 

ND 

13 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

8.8 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg. 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Reporting 

Limit 

10 

100 

100 

100 

5. 

5. 

5, 

ND « Not detected 

NA * Not applicable 

Reported By: Oiane Page 

(continued on following page) 

89 

39 

0 

0 

0 

5.0 

10 

5.0 

5.0 

5.0 

5.0 

10 

5.0 

5.0 

10 

5.0 

5.0 

5.0 

5.0 

10 

5.0 

5.0 

5.0 

5.0 

5.0 

5.0 

5.0 

5.0 

100 

5.0 

5.0 

10 

5.0 

100 

5.0 

10 

- 10 

Approved By: Jeff Lowry 
P.50 

Appendix IX Volatile Organics (CONT.) 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site #1 BS Pit Skimmings 

Lab ID: 006299-0005-SA Enseco ID: 

Matrix: WASTE Sampled: 

Authorized: 28 AUG 89 Prepared: 

Parameter 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene. 

Toluene 

1,1,1-Trichloroethane 

1,1,2-Tri chloroethane 

Trichloroethene 

Tri chlorof1uoromethane 

1,2,3-Trichloropropane 

Vinyl acetate 

Vinyl chloride 

Total xylenes 

Toluene-d8 

4-Bromof1uorobenzene 

(BFB1 

1,2-Di ch1oroethane-d4 

1050769 

24 AUG 

01 SEP 

esult 

ND 

ND 

ND 

ND 

11 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

26 

104 

96.6 

94.0 

89 

89 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

fa 

% 

Received: 25 AUG 89 

Analyzed: 06 SEP-39 

Reporting 

Limit 

5.0 

5.0 

5.0 . 

5.0 

5.0 

5.0 

5.0 

5.0 

5.0 

5.0 

10 

10 

5.0 

--

ND = Not detected 

NA - Not applicable 

Reported By: Diane Page Approved By: Jeff Lowry 
P.51 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

OTC Volatile Organics 

TCLP Leachate 

Method 8240 

American Petroleum Institute 

Site #1 BS Pit Skimmings 

006299-0005-SA Enseco ID: 1050769 

WAM Sampled: 24 AUG 89 

28 nJG 89 Prepared: 13 SEP 89 

Received: 

Analyzed: 

25 AUG 89 

15 SEP 89 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichloroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Trichloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromofluorobenzene 

(BFB 

1,2-Di chloroethane-d4 

Result 

ND 

ND 

NO 

ND 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

0.083 

ND 

ND 

ND 

0.033 

ND 

109 

103 

100 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

r. 

% 

Reporting 

Limit 

0.050 

0.50 

0.025 

0.025 

0.025 

0.50 

0.025 

0.025 

0.050 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

ND • Not detected 

NA - Not applicable 

Reported By: Lisa Traut Approved By: Jeff Lowry 

I 
P.52 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

American Petroleum Institute 

Site #1 BS Pit Skimmings 

006299-0005-SA Enseco ID: 1050769 

WASTE Sampled: 24 AUG 89 

28 AUG 89 Prepared: 05 SEP 89 

1 

Anthracene 

Benzo(a)anthracene 

Benzo(b)fluoranthene 

Benzo(k)f1uoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Dibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2 -Di ch1orobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methyl naphtha! ene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethi.ol 

o-Cresol 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Oinitropnenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

ND - Not detected 

NA - Not applicable 

Reported By: Belinda Guerra 

Result Units 

NO 

NO 

ND 

ND 

ND 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

71 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

NO 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

. mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Received: 25 AUG 89 

Analyzed: 02 OCT 89 

Reporting 

Limit 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

200 

200 

40 

59.3 

64.3 

74.4 

64.6 

66.3 

73.8 

fa 

% 

% 

fa 

% 

fa 

Approved By: Jeff Lowry 

1 
P.53 

OTC Semivolatile Organics 

TCLP Leachate 

Method 8270 

Client Name: American Petroleum Institute 

Client ID: Site 1 BS Pit Skimmings 

Lab ID: 006299-0005-SA Enseco ID* 

Matrix: WASTE Samplea 

Authorized: 28 AUG 89 Prepared. 

Parameter 

Pyridine 

Phenol 

bis(2-Chloroethyl)ether 

1,4-Dichlorobenzene 

1,2-Dichlorobenzene 

o-Cresol 

m & p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlorobutadiene 

2,4,6-Tri chlorophenol 

2,4,5-Tri chlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tribromophenol 

1050769 

:4 AUG 89 

11 SEP 89 

esult 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

NO 

NO 

108 

85.8 

82.1 

79.0 

76.0 

77.0 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

nvj/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

X 

% 

% 

Receiv 

Analyz-

: 25 AUG 89 

: 04 OCT 89 

Reporting 

Li mit 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.10 

0.020 

0.020 

0.020 

0.10 

--

--

- -

--

--

--

NO - Not detected 

NA - Not applicable 

Reported By: Dan Albritton Approved By: Jeff Lowry 
Metals 

Total Metals 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

American Petroleum Institute 

Site #1 BS Pit Skimmings 

006299-0005-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

Result Units 

85 

ND 

1.1 

4 

ND 

ND 

2130 

3 

NO 

10 

44 

ND 

9 

ND 

ND 

ND 

800 

ND 

ND 

2 

22 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

1050769 

24 AUG 89 

See Below 

Reporting 

Limit 

10 

5 

0.5 

1 

0.2 

0.5 

30 

1 

1 

1 

5 

0.1 

4 

500 

0.5 

1 

500 

10 

11 

1 

1 

Received: 

Analyzed: 

Analytical 

Method 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

25 AUG 89 

See Below 

Prepared 

Date 

05 

05 

05 

01 

SEP 89 

SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

SEP 89 

SEP 89 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

Analyzed 

Date 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP'89 

18 SEP 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

ND - Not detected 

NA - Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.55 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

ICP/MS Metals 

Total Metals 

American Petroleum Institute 

Site #1 BS Pit Skimmings 

006299-0005-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

1050769 

24 AUG 89 

See Be'ow 

Received: 

Analyzed: 

Parameter 

Osmium (189) 

Result Units 

Reporting Analytical 

Limit Method 

25 AUG 89 

See Below 

Prepared 

Date 

Analyzed 

Date 

NO mg/kg 0.1 RMAL 07 OCT 89 14 OCT 89 

ND - Not detected 

NA -Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.56 

Metals 

TCLP Leachate 

Client Name: American Petroleum Institute 

Client ID: Site #1 BS Pit Skimmings 

Lab ID 

Matrix 

006299-0005-SA Enseco ID: 1050769 

WASTE Sampled: 24 AUG 89 Received: 25 AUG 89 Authorized: 28 AUG 89 Prepared: See Below Analyzed: See Below 

Reporting Analytical Prepared Analyzed 

Parameter Result Units Limit Method Date Date 

Arsenic ND mg/L 0.2 200.7 14 SEP 89 20 SEP 89 

Barium 0.17 mg/L 0.02 200.7 14 SEP 89 20 SEP 89 

Cadmium ND mg/L 0.01 200.7 14 SEP 89 20 SEP 89 

Chromium ND mg/L 0.02 200.7 14 SEP 89 20 SEP 89 

Lead ND mg/L 0.1 200.7 14 SEP 89 20 SEP 89 

Silver ND mg/L 0.02 200.7 14 SEP 89 20 SEP 89 

Mercury ND mg/L 0.002 7471 14 SEP 89 17 SEP 89 

Selenium ND mg/L 0.05 270.2 14 SEP 89 18 SEP 89 

ND - Not detected 

NA » Not applicable 

Reported By: Sandra Jones Approved By: Tammy Bailey 
P.57 

General Inorganics 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site #1 BS Pit Skimmings 

006299-0005-SA Enseco ID: 

WASTE Sampled: 

28 AUG 89 Prepared: 

Result Units 

Cyanide, Reactive 

Ignitability 

Non-Volatile Oil 

Volatile Oil 

Oil 

Water 

Solids 

PH 

Sulfide, Reactive 

ND 

>160 

68.2 

0.1 

68.3 

22.5 " 

8.7 

7.1 

1.2 

mg/kg 

deg. F 

fa 

fa 

fa 

fa 

fa 

units 

mg/kg 

1050769 

24 AUG 89 

See Below 

Reporting 

Limit 

0.1 

0.1 

0.1 

0.1 

0.1 

0.1 

0.5 

Received: 

Analyzed: 

Analytical 

Method 

25 AUG 89 

See ",-»low 

Prepared 

D?*e 

AnalyzedDate . 

EPA-0SW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/0SW 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

08 SEP 89 

11 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

19 OCT 89 

11 SEP 89 

08 SEP 39 

Note o * This test is unreli'Me for any sample other than a 

non-aqueous liquid 

ND - No. detected 

NA • Not applicable 

Reported By: Blake Besser Approved By: Tammy Bailey 
P.58 

Appendix IX Volatile Org 

Method 8240 

Client Name: American Petroleum Institute 

Client ID: Site #3 Crude Oil Bottom Str. 

Lab ID: 006299-0004-SA Enseco ID: 1050768 

Matrix: WASTE Sampled: 24 AUG 

Authorized: .28 AUG 89 Prepared: 01 SEP 

Parameter Result 

Acetone ND 

Acetonitrile ND 

Acrolein NO 

Acrylonitrile ND 

Allyl chloride ND 

Benzene . 110 

Bromodichloromethane ND 

Bromoform NO 

Bromomethane ND 

Carbon disulfide NO 

Carbon tetrachloride ND 

Chl orobenzene ND 

Chloroprene ND 

Chloroethane ND 

Chl orodibromomethane ND 

Chloroform ND 

Chloromethane ND 

DBCP (1,2-Dibromo3-chloropropane) ND 

EDB (1,2-Dibromoethane) NO 

Dibromomethane NO 

trans-1,4-Dichloro2-butene NO 

Dichlorodifluoromethane ND 

1,1-Dichloroethane ND 

1,2-Dichloroethane ND 

trans-1,2-0ichloroethene ND 

1,1-Dichloroethene ND 

Dichloromethane ND 

1,2-Dichloropropane ND 

cis-1,3-Dichloropropene ND 

trans-1,3-Dichloropropene NO 

1,4-Dioxane ND 

Ethyl benzene 510 

Ethyl cyanide ND 

2-Hexanone ND 

Iodomethane ND 

Isobutyl alcohol NO 

Methacrylonitrile NO 

Methyl ethyl ketone NO 

4-Methyl-2-pentanone ND 

(continued on following 

ND - Not detected 

NA - Not applicable 

anics 

89 Received: 25 AUG 

89 An< 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

page) 

Reported By: Diane Page Approved By: Jeff 

j 

ilyzed: 06 SEP 

Reporting 

Limit 

200 

2000 

2000 

2000 

100 

100 

100 

100 

200 

100 

100 

100 

100 

200 

100 

100 

200 

100 

100 

100 

100 

200 

100 

100 

100 

100 

100 

100 

100 

100 

2000 

100 

100 

200 

100 

2000 

100 

200 

200 

Lowry 

89 

89 

• 

. 
P.59 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Appendix IX Volatile Organics (CONT. 

Method 8240 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 

WASTE Sampled: 

2.8 AUG 89 Prepared: 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

1,1,1-Tri chloroethane 

1,1,2-Trichloroethane 

" -ichloroethene 

ichlorofluoromethane 

.,2,3-Trichloropropane 

Vinyl acetate 

Vinyl chloride 

Total xylenes 

Toluene 

4-Bromof 

(BFB 

1,2-Dich 

d8 

uorobenzene 

oroethane-d4 

1050768 

24 AUG 

01 SE.> 

esult 

ND 

ND 

ND 

ND 

520 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

710 

105 

94.6 

98.1 

89 

89 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

fa 

fa 

Received: 25 AUG 89 

Analyzed: 06 SEP 89 

Reporting 

Limit 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

200 

200 

100 

--

--

--

ND • Not detected 

NA - Not applicable 

Reported By: Oiane Page Approved By: Jeff Lowry 
P.60 

Name: 

ID: 

CIient 

Client 

Lab ID: 

Matrix: 

Authorized: 

OTC Volatile Organics 

TCLP Leachate 

Method 8240 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 1050768 

WASTE Sampled: 24 AUG 89 

28 AUG 89 Prepared: 13 SEP 89 

Parameter 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichloroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Tri chloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromof1uorobenzene 

(BFB) 

1,2-Dichloroethane-d4 

Result 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

NO 

2.2 

NO 

NO 

ND 

3.7 

ND 

104 

103 

98.8 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

fa 

fa 

Received: 25 AUG 89 

Analyzed: 15.SEP 89 

Reporting 

Limit 

0.25 

2.5 

0.12 

0.12 

0.12 

2.5 

0.12 

0.12 

0.25 

0.12 

0.12 

0.12 

0.12 

0.12 

0.12 

0.12 

0.12 

0.12 

0.12 

ND - Not detected 

NA * Not applicable 

Reported By: Lisa Traut Approved By: Jeff Lowry 
P.61 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 1050768 

WASTE Sampled: 24 AUG 89 

28 AUG 89 Prepared: 05 SEP 89 

Anthracene 

Benzo(a)anthracene 

Benzolb)fluoranthene 

Benzo(k)f1uoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Di benz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl r..:halate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methylnaphthalene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitropnenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

ND - Not detected 

NA - Not applicable 

Reported By: Belinda Guerra 

Result 

Received: 25 AUG 

Analyzed: 02 OCT 

Reporting 

Units Limit 

89 

89 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

59 

47 

14 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

NO 

NO 

ND 

61.2 

65.6 

78.8 

39.2 

34.2 

43.2 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kr 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

% 

% 

fa 

% 

% 

• 1 3 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

13 

'.3 

i3 

13 

13 

--

13 

--

13 

13 

13 

65 

65 

13 

--

--

--

--

--

Approved By: Jeff Lowry 
i62 _ 

Client Name: 

Hient ID: 

ab ID: 

.latrix: 

Authorized: 

Parameter 

OTC Semivolatile Organics 

TCLP Leachate 

Method 8270 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 1050768 

WASTE Sampled: 24 AUG 89 

28 AUG 89 Prepared: 21 SEP 89 

Received: 25 AUG 89 

Analyzed: 04 OCT 89 

3yridine 

Phenol 

bis(2-Chloroethyl)ether 

1,4-Di chlorobenzene 

1,2-Dichlorobenzene 

o-Cresol 

m & p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlorobutadi ene 

2,4,6-Tri chlorophenol 

2,4,5-Tri chlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluoroblphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

suit 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

95.6 

67.8 

68.4 

6.88 

3.82 

7.13 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

% 

% 

% 

Reporting 

Limit 

--

0.040 

0.040 

0.040 

0.040 

0.040 

0.040 

0.040 

0.040 

0.040 

0.040 

0.20 

0.040 

0.040 

0.040 

0.20 

--

--

--

--

--

--

i 

1 

NO - Not detected 

NA - Not applicable 

Reported By: Dan Albritton Approved By: Jeff Lowry 

r. 
P.63 

Client 

Client 

Lab ID 

Matrix 

Authori 

Name: 

ID: 

zed: 

Metals 

Total Metals 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 1050768 

WASTE Samplee 24 AUG 89 

28 AUG 89 Prepared. See Below 

Received: 

Analyzed: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

Result Units 

Reporting 

Limit 

329 

ND 

6.2 

58 

ND 

ND 

114000 

48 

5 

54 

320 

ND 

100 

NO 

ND 

ND 

12000 

NO 

ND 

NO 

54 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

50 

30 

0 

5 

1 

3 

100 

5 

5 

5 

30 

0 

20 

3000 

5 

5 

3000 

50 

30 

5 

5 

Analytical 

•ethod 

6, 

60u 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

25 

Set 

3 89 

?low 

Prepared 

Date 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

01 SEP 89 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

06 OCT 89 

05 SEP 89 

05 SEP 89 

05 SEP 89 

Analyzed 

Date 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

11 SEP 89 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

10 OCT 89 

18 SEP 89 

18 SEP 89 

18 SEP 89 

ND « Not detected 

NA » Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.64 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Osmium (189) 

ICP/MS Metals 

Total Metals 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 1050768 

WASTE Sampled: 24 AUG 89 

28 AUG 89 Prepared: See Below 

Received: 

Analyzed: 

Result Units 

Reporting Analytical 

Limit Method 

25 AUG 89 

See Below 

Prepared 

Date 

Analyzed 

Date 

ND mg/kg 0.1 RMAL 07 OCT 89 14 OCT 89 

ND •» Not detected 

NA - Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.65 

Metals 

TCLP Leachate 

Client Name: 

Client ID: 

Lab ID 

Matrix 

Authorized 

Parameter 

Arsenic 

Barium 

Cadmi urn 

Chromium 

'.ead 

:ilver 

Mercury 

Selenium 

American Petroleum Institute 

Site #3 Crude Oil Bottom Str. 

006299-0004-SA Enseco ID: 

STE Sampled: 

AUG 89 Prepared: 

Result Units 

1050768 

24 AUG 89 

See Below 

Received: 

Analyzed: 

Reporting Analytical 

Limit Method 

ND 

0.33 

NO 

ND 

ND 

ND 

NO 

ND 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

0.5 

0.05 

0.03 

0.05 

0.3 

0.05 

0.002 

0.05 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

25 AUG 89 

See Below 

Prepared 

Date 

SEP 89 

SEP 89 

SEP 89 

SEP 89 

SEP 89 

SEP 89 

SEP 89 

SEP 89 

Analyzed 

Date 

20 SEP 89 

20 SEP 89 

20 SEP 89-

20 SEP 89 

20 SEP 89 

20 SEP 89 

17 SEP 89 

18 SEP 89 

ND •» Not detected 

NA • Not applicable 

Reported By: Sandra Jones Approved By: Tammy Bailey 
P.66 

Append 

Client Name: American Petroleum 

Client ID: Ramsey-Crude Tank 

Lab ID: 011425-0001-SA 

Matrix: WASTE 

Authorized: 21 SEr 90 

Parameter 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

3romodichloromethane 

jromoform 

romomethane 

-arbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprene 

Chloroethane 

Dibromochloromethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-cnloropropane) 

EDB (1,2-Dibromoethane) 

Dibromomethane 

trans-1,4-Dichloro2-butene 

Di chl orodi f1uoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichloromethane 

1,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol 

Methacrylonitrile 

2-Butanone (MEK) 

4-Methyl-2-pentanone 

(conti 

ND - Not detected 

NA « Not applicable 

Reported By: Michael Blades 

ix IX Volatile Org 

Method 8240 

Institute 

Bottoms 

Sampled: 20 SEP 

Prepared: 25 SEP 

Result 

NO 

ND 

ND 

NO 

ND 

360 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

490 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

nued on following 

anics 

i 

90 Received: 21 SEP 90 

90 An 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

page) 

Approved By: Jeff 

alyzed: 27 SEP 90 

Reporting 

Limit 

500 

5000 

5000 

5000 

250 

250 

250 

250 

500 

250 

250 

250 

250 

500 

250 

250 

500 

250 

250 

250 

250 

500 ! 

250 

250 

250 

250 

250 

250 

250 

250 

5000 

250 

250 

500 

250 

5000 

250 

500 

500 

i 

Lowry 

i 

1 
P.67 

Rocky Mountain 

Analytical Laboratory 

ANALYTICAL RESULTS 

FOR 

AMERICAN PETROLEUM INSTITUTE 

ENSECO-RMAL NO. 011425 

NOVEMBER 1, 1990 

Enseco 

Reviewed by: 

°Susa n CjWyatSue Dal la 

Lnsctu Incorporated 

-W*5 Yarrow Street 

Arvaua. Colorado S0002 

.305/421-6611 Fax: 505/451-7171 
P.68 

General Inorganics 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Chloride 

American Petroleum Institute 

Crude 

007862 

WASTE 

15 DEC 

Cyanide, Reactive 

Ignitability 

Non-Volatile 

Volatile Oil 

Oil 

Water 

Solids 

pH 

Oil 

Sulfide, Reactive 

Tank Bottoms 

-0001-SA Enseco ID: 

Sampled: 

89 Prepared: 

1062911 

14 DEC ! 

See Bel 

Reporting 

Result Units 

350 mg/kg 

ND mg/kg 

>160 deg. F 

.34.1 f. 

ND % 

34-. 1 fa 

29.2 % 

37.7 f. 

8.3 units 

ND mg/kg 

Limit 

15 

0.1 

--

0.1 

0.1 

0.1 

0.1 

0.1 

--

0.5 

39 Rec 

3w Ana 

Analytical 

Method 

300.0 Mod. 

EPA/OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/OSW 

eived 

lyzed 

: 15 DEC 89 

: See Below 

Prepared 

Date 

18 DEC 89 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

Analyzed 

Date 

20 DEC 89 

21 DEC 89 

09 JAN 90 

05 JAN 90 

05 JAN 90 

05 JAN 90 

05 JAN 90 

05 JAN 90 

28 DEC 89 

19 DEC 89 

Note o : This test is unreliable for any sample other than a 

non-aqueous liquid. 

ND = Not detected 

NA = Not applicable 

Reported By: Pam Rosas Approved By: Kimberly Conroy 
P.69 

_l 

ICP/MS Metals 

Total Metals* 

Client Name: American Petroleum Institute 

Client ID: Crude Tank Bottoms 

Lab ID: 007862-0001-SA Enseco ID: 1062911 

Matrix: WASTE Sampled: 14 DEC 89 

Authorized: 15 DEC 89 Prepared: See Below 

Received: 15 DEC 89 

Analyzed: See Below 

Parameter 

Osmium (189) 

Result 

ND 

Units 

mg/kg 

Reporting Analytical 

Limit Method 

0.4 RMAL 

Prepared Analyzed 

Date Date 

29 DEC 89 03 JAN 90 

_j 

ND = Not detected 

NA - Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.70 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Silver 

Mercury. 

Selenium 

Metals 

TCLP Leachate 

American Petroleum Institute 

Crude Tank Bottoms 

007862-0001-SA Enseco ID: 1062911 

WASTE Sampled: 14 DEC 89 

15 DEC 89 Prepared: See Below 

Received: 

Analyzed: 

Result 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

Reporting Analytical 

Limit Method 

; 15 DEC 89 

: See Below 

Prepared 

Date 

Analyzed 

Date 

5 

3 

03 

05 

3 

05 

0.002 

0.05 

6010 

6010 

6010 

6010 

6010 

6010 

7470 

7740 

28 DEC 89 03 JAN 90 

28 DEC 89 03 JAN 90 

28 DEC 89 03 JAN 90 

28 DEC 89 03 JAN 90 

28 DEC 89 03 JAN 90 

28 DEC 89 03 JAN 90 

29 DEC 89 03 JAN 90 

28 DEC 89 02 JAN 90 

ND - Not detected 

NA • Not applicable 

Reported By: Fred Velasquez Approved By: Kimberly Conroy 
P.71 

1 

J 

J 

Name: 

ID: 

Client 

Client 

Lab ID 

Matrix 

Authorized 

Metals 

Total Metals 

American Petroleum Institute 

Crude Tank Bottoms 

007862-0001-SA Enseco ID: 1062911 

WASTE Sampled: 14 DEC 89 

15 DEC 89 Prepared: See Below 

Received: 

Analyzed: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

Result 

1200 

ND 

2.7 

26 

ND 

ND 

2800 

5 

1 

4 

ND 

ND 

25 

ND 

ND 

ND 

760 

NO 

NO 

6 

10 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Reporting Analytical 

Limit Method 

10 

5 

0.5 

1 

0.2 

0.5 

20 

1 

1 

1 

5 

0.1 

4 

500 

1 

1 

500 

0.5 

5 

1 

2 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

15 DEC 89 

See Below 

Prepared 

Date 

Analyzed 

Date 

03 JAN 

03 JAN 

02 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

03 JAN 

02 JAN 

03 JAN 

03 JAN 

02 JAN 

03 JAN 

03 JAN 

03 JAN 

90 08 

90 08 

90 04 

90 08 

90 08 

90 08 

90 08 

90 08 

90 08 

90 08 

90 08 

90 04 

90 08 

90 08 

90 04 

90 08 

90 08 

90 04 

90 08 

90 08 

90 08 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

JAN 90 

ND - Not detected 

NA » Not applicable 

Reported By: Harold Borquez Approved By: Kimberly Conroy 
P.72 

OTC Semivolatile Organics 

TCLP Leachate 

Method 8270 

Client Name: American Petroleum Institute 

Client ID: Crude Tank Bottoms 

Lab ID: 007862-0001-SA Enseco ID: 1062911 

Matrix: WASTE Sampled: 14 DEC 89 

Authorized: 15 DEC 89 Prepared: 02 JAN 90 

Parameter Result 

Pyridine ND 

Phenol ND 

bis(2-Chloroethyl) ether ND 

1,4-Dichlorobenzene ND 

1,2-Dichl orobenzene ND 

o-Cresol ND 

m. _ p-Cresol(s) ND 

Hexachloroethane ND 

Nitrobenzene ND 

Hexachlorobutadiene ND 

2,4,6-Trichlorophenol ND 

2,4,5-Trichlorophenol ND 

2,4-Dinitrotoluene ND 

Hexachl orobenzene ND 

2,3,4,6-Tetrachlorophenol ND 

Pentachlorophenol ND 

Nitrobenzene-d5 72.9 

2-Fluorobiphenyl 68.7 

Terphenyl-dl4 75.9 

Phenol-d5 72.5 

2-Fluorophenol 64.5 

2,4,6-Tribromophenol 80.0 

ND - Not detected 

NA - Not applicable 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

% 

% 

% 

% 

fa 

Received: 15 DEC 89 

Analyzed: 12 JAN 90 

Reporting 

Limit 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.020 

0.10 

0.020 

0.020 

0.020 

0.10 

--

--

-T 

--

' 

Reported By: Belinda Guerra Approved By: Jeff Lowry 

1 
P.73 

I 

Refinery Hazardous Constituent 

Method 8270 

Client Name: American Petroleum Insti 

Client ID: Crude Tank Bottoms 

Lab ID: 007862-0001-SA Ensecc 

tute 

) ID: 1062911 

Matrix: WASTE Sampled: 14 DEC 

Authorized: 15 DEC 89 Prepared: 21 DEC 

Parameter 

Anthracene 

Benzo(alanthracene 

Benzo(b)fluoranthene 

Benzo-( k) f 1 uoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Dibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichiorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methylnaphthal ene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitropnenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4. 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tribromophenol 

ND » Not detected 

! NA = Not applicable 

Reported By: Michael Blades 

1 

1 

Result 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

21 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

76.0 

95.6 

94.4 

46.2 

53.2 

93.2 

Semi volatil 

89 

89 

es 

Received: 15 DEC 89 

An 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

% 

% 

% 

fa 

f. 

alyzed: 12 JAN 90 

Reporting 

Limit 

20 

20 

20 

20 

20 

20 

20 

20 

t 20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

20 

--

20 

._ 

20 

20 

20 

100 

100 

20 

--

--

--

- -

Approved By: Jeff Lowry 

1 
P.74 

OTC 

Client Name: American Petroleum 

Client ID: Crude Tank Bottoms 

Lab ID: 007862-0001-SA E 

Matrix: WASTE 

Authorized: 15 DEC 89 

Parameter 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichloroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Trichloroethane 

Carbon tetrachloride 

Trichloroethene 

<*- 1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromof1uorobenzene 

1,2-Dichloroethane-d4 

ND = Not detected 

NA - Not applicable 

Reported By: Keith Beauvais 

1 • -

> 

1 

j 

Volatile 

TCLP 

Organics 

Leachate 

Method 

Instil 

inseco 

tute 

ID: 

Sampled: 

Prepared: 

8240 

1062911 

14 DEC 89 

. 27 DEC 89 

Result 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

0.092 

NO 

NO 

ND 

ND 

NO 

103 

105 

103 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

f. 

% 

fa 

i 

Received: 15 DEC 89 

Analyzed: 03 JAN 90 

Reporting 

Limit 

0.050 

0.50 

0.025 

0.025 

0.025 

0.50 

0.025 

0.025 

0.050 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

0.025 

--

Approved By: Jeff Lowry 
Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Appendix IX Volatile Organics (CONT.) 

Method 8240 

American Petroleum Institute 

Crude Tank Bottoms 

007862-

WASTE 

15 DEC 

0001-SA 

89 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

1,1,1-^Tri chl oroethane 

1,1,2-Trichloroethane 

Trichl oroethene 

Trichlorofluoromethane 

1,2,3-Trichloropropane 

Vinyl acetate 

Vinyl chloride 

Xylenes (total) 

Toluene-d8 

4-Bromofluorobenzene 

1,2-Di chloroethane-d4 

Enseco ID: 

Sampled: 

Prepared: 

1062911 

14 DEC 

20 DEC 

Result 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

11 

89 

89 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Received: 

Analyzed: 

15 

04 

DEC 

JAN 

89 

90 

Reporting 

Limit 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

2.0 

2.0 

1.0 

106 

107 

103 

% 

fa 

fa 

ND - Not detected 

i NA » Not applicable 

Reported By: Michael Blades Approved By: Jeff Lowry 
P.76 

Appendix IX Volatile Organics 

Method 8240 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

Crude Tank Bottoms 

007862-0001-SA Enseco ID: 

WASTE Snpled: 

15 DEC 89 Pr .ared: 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

Bromodichloromethane 

Bromoform 

Bromomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprene 

Chloroethane 

Chlorodibromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-chloropropane) 

EDB (1,2-0ibromoethane) 

Dibromomethane 

trans-1,4-Dichloro2-butene 

Di chlorodi fluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichloromethane 

1,2 -Di chloropropane 

cis-1,3-Dichloropropene 

trans -1,3-Di chloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol---

Methacrylonitrile 

Methyl ethyl ketone 

4-Methyl-2-pentanone 

1062911 

14 DEC 89 

20 DEC 89 

esult 

ND 

ND 

ND 

ND 

NO 

6.3 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

13 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

Received: 15 DEC 89 

An< 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mc/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

ilyzed: 04 JAN 90 

Reporting 

Limit 

2.0 

20 

20 

20 

1.0 

1.0 

1.0 

1.0 

2.0 

1.0. 

1.0 

1.0 

1.0 

2.0 

1.0 

1.0 

2.0 

1.0 

1.0 

1.0 

1.0 

2.0 

1.0 

1.0-

1.0 

1.0 

•1.0 

1.0 

1.0 

1.0 

20 

1.0 

1.0 

2.0 

1.0 

20 

1.0 

2.0 

2.0 

ND = Not detected 

NA » Not applicable 

(continued on following page) 

Reported.By: Mfchael Blades Approved By: Jeff Lowry 
P.77 

Rocky Mountain Enseco IncoroorateAnalytical Laboratory 

ANALYTICAL RESULTS 

FOR 

AMERICAN PETROLEUM INSTITUTE 

ENSECO-RMAL NO. 007862 

JANUARY 27, 1990 

Enseco 

Susan C. Wyatt ' 

V JSPtJi it i &Lb<X?htJJeanne t\. Howbert 

4955 Yarrow Strep 

Arvada. Colorado 80002 

303/421-6611 

Facsimile: 303/431-7171 
P.78 
General Inorganics 

P.79 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Chloride 

American Petrol< 

TANK BOTTOMS #2 

007531 

WASTE 

17 NOV 

Cyanide, Reactive 

Ignitability 

Non-Volatile 

Volatile Oil 

Oil 

Water 

Solids 

pH 

Oil 

Sulfide, Reactive 

-0004-SA 

89 

Result 

10900 

ND 

66 

27.2 

8.8 

36.0-

20.3 

40.1 

7.2 

0.7 

»um Institute 

Enseco 

Samp 

Prepai 

Units 

mg/kg 

mg/kg 

deg. F 

• % 

% 

% 

% 

% 

units 

mg/kg 

ID: 

ed: 

-ed: 

1060351 

15 NOV 

See Bel 

Reporting 

Limit 

15 

0.1 

--

0.1 

0.1 

0.1 

0.1 

0.1 

--

0.5 

39 Received 

ow Analyzed 

Analytical 

Method 

300.0 Mod. 

EPA/OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/OSW 

: 17 NOV 89 

: See Below 

Prepared 

Date 

06 DEC 89 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

Analyzed 

Date 

11 DEC 89 

30 NOV 89. 

19 DEC 89 oz 

08 DEC 89 

08 DEC 89 

08 DEC 89 

08 DEC 89 

08 DEC 89 

21 NOV 89 

30 NOV 89 

Note o : This. test, is unreliable for any sample other than a 

non-aqueous liquid. 

Note z : Sample exhibits a characteristic of hazardous waste. 

ND = Not detected 

NA = Not applicable 

Reported By: Pam Rosas Approved By: Toni Lusk 
P.80 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chr -ium 

Lee • 

Sil\. ir 

Mercury 

Selenium 

Metals 

TCLP Oil Filtrate 

American Petroleum Institute 

TANK BOTTOMS #2 

007531-0004-SA Enseco ID: 1060351 

WASTE San* ed: 15 NOV 89 

17 NOV 89 Prepa.ed: See Below 

Received: 17 NOV 89 

Analyzed: See Below 

Result 

ND 

ND 

ND 

0.8 

ND 

ND 

NO 

ND 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

Reporting 

Limit 

5 

0. 

0. 

0. 

3 

0. 

0. 

0, 

Analytical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

Prepared Analyzed 

Date Date 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

Z9 NOV 89 13 DEC 89 

06 DEC 89 08 DEC 89 

29 NOV 89 12 DEC 89 

ND = Not detected 

NA - Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.81 

Metals 

Aqueous Leachate 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Silver 

Mercury 

Selenium 

American Petroleum Institute 

TANK BOTTOMS #2 

007531-0004-SA Enseco ID 

WASTE 

17 NOV 89 

1060351 

Sampled: 15 NOV 89 

Prepared: See Below 

Received: 17 NOV 89 

Analyzed: See Below 

suit 

1.1 

4.1 

0.054 

0.07 

9.2 

ND 

ND 

NO 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

Reporting 

Limit 

0.1 

0.3 

0.005 

0.01 

0.05 

0.01 

0.002 

0.05 

Analytical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

Prepared 

Date 

29 NOV 89 

29 NOV 89 

29 NOV 89 

29 NOV 89 

29 NOV 89 

29 NOV 89 

06 DEC 89 

29 NOV 89 

Analyzed 

Date 

13 DEC 89 

13 DEC 89 

13 DEC 89 

13 DEC 89 

13 DEC 89 

13 DEC 89 

08 DEC 89 

12 DEC 89 

ND » Not detected 

NA - Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.82 

Metals 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Silver 

Mercury 

Selenium 

TCLP 

American Petroleum Insti 

TANK BOTTOMS #2 

007531 

WASTE 

17 NOV 

-0004-SA 

89 

Result 

1.1 

4.1 

0.055 

0.07 

9.2 

ND 

NO 

ND 

Enseco 

Samo 

Leachate 

tute 

ID: 

led: 

Prepared: 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

1060351 

15 NOV 

See Bel 

Reporting 

Limit 

0.2 

,0.4 

0.007 

0.02 

0.07 

0.02 

0.003 

0.06 

39 Rec 

DW Ana 

Analytical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

eived 

lyzed 

: 17 NOV 89 

: See Below 

Prepared Analyzed 

Date Date 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

06 DEC 89 03 JAN 90 1 

29 NOV 89 12 DEC 89 1 

Note 1 : Results based on multiphase analysis and mathematical 

recombination. 

ND = Not detected 

NA • Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.83 

ICP/MS Metals 

Total Metals 

Client Name: American Petroleum Institute 

Client ID: TANK-BOTTOMS #2 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Osmium (189) 

007531-0004-SA 

WASTE 

17 NOV 89 

Result 

ND 

Enseco ID: 1060351 

Sampled: 15 NOV 89 

Prepared: See Below 

Received: 17 NOV 89 

Analyzed: See Below 

Units 

mg/kg 

Reporting Analytical 

Limit Method 

0.4 RMAL 

Prepared Analyzed 

Date Date 

29 DEC 89 03 JAN 90 

ND = Not detected 

NA • Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
P.84 

Metals 

Total Metals 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryl!ium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin . 

Vanadium 

Zinc 

American Petroleum Institute 

TANK BOTTOMS #2 

007531-0004-SA Enseco ID: 

WASTE Sampled: 

17 NOV 89 Prepared: 

Result 

1060351 

15 NOV 89 

See Below 

Received: 

Analyzed: 

Units 

300 

ND 

32 

430 

ND 

2.3 

3400 

10 

NO 

210 

940 

ND 

9 

ND 

ND 

NO 

4500 

0.7 

ND 

2 

190 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Reporting 

Limit 

10 

5 

3 

1 

0.2 

0.5 

20 

1 

1 

1 

5 

0.1 

4 

500 

1 

1 

500 

0.5 

8 

1 

4 

Analytical 

Method 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 

7841 

6010 

6010 

6010 

17 NOV 89 

See Below 

Prepared Analyzed 

Date Date 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

DEC 89 

DEC 89 

DEC 89 

06 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 DEC 89 

21 

21 

21 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

08 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 DEC 89 

27 OEC 89 

27 DEC 89 

27 DEC 89 

ND = Not detected 

NA - Not applicable 

Reported By: Bryan Anderson 

Approved By: Tammy BMe y 
P.85 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

OTC Semivolatile Organics 

TCLP Leachate 

Method 8270 

American Petroleum Institute 

TANK BOTTOMS #2 

007531-0004-SA Enseco ID: 1060351 

WASTE Sampled: 15 NOV 89 

17 NOV 89 Prepared: 07 DEC 89 

Received: 

Analyzed: 

17 NOV 89 

12 JAN 90 

Pyridine 

Phenol 

bis(2-Chloroethyl) ether 

1,4-Dichlorobenzene 

1,2-Dichlorobenzene 

o-Cresol 

m _ p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlorobutadiene 

2,4,6-Trichlorophenol 

2,4,5-Tri chlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

Result Units 

ND mg/L 

ND mg/L 

ND mg/L 

ND mg/L 

ND mg/L 

ND mg/L 

ND mg/L 

ND mg/L 

NO mg/L 

ND mg/L 

NO mg/L 

ND mg/L 

NO mg/L 

ND mg/L 

ND . mg/L 

ND mg/L 

ND fa 

68.1 % 

70.0 % 

48.1 fa 

51.0 fa 

68.0 % 

Reporting 

Limit 

4.4 

4.4 

4.4 

4.4 

4.4 

4.4 

4.4 

4.4 

4.4 

4.4 

22 

4.4 

4.4 

4.4 

22 

NO ' Not detected 

NA - Not applicable 

Reported By: Belinda Guerra Approved By: Jeff Lowry 
P.86 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

Client Name. American Petroleum Institute 

Client ID: TANK BOTTOMS #2 

Lab ID: 007531-0004-SA Enseco ID: 

Matrix: WASTE Sampled: 

Authorized: 17 NOV 89 Prepared: 

Parameter 

Anthracene 

Berizo(a)anthracene 

Benzo(b)fluoranthene 

Benzo(k)f1uoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Dibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methyl naphthalene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline 

Benzenethiol 

o-Cresol 

m _ p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitrophenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tribromophenol 

ND = Not detected 

NA = Not applicable 

1060351 

15 NOV 89 

13 DEC 89 

esult 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

NO 

ND 

ND 

NO 

ND 

ND 

ND 

60.0 

72.6 

77.2 

30.3 

40.7 

67.4 

Received: 17 NOV 89 

Analyzed: 15 DEC 89 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

fa 

• % 

fa 

fa 

fa 

fa 

Reporting 

Limit 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

- -

70 

- -

70 

70 

70 

350 

350 

70 

_. 

- -

- -

- -

- -

- -

Reported By: Dan Albritton Approved By: Jeff Lowry 
P.87 

Name: 

ID: 

Client 

Client 

Lab ID: 

Matrix: 

Authorized: 

American Petroleum 

TANK BOTTOMS #2 

007531-0004-SA 

WASTE 

17 NOV 89 

Parameter 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichloroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Trichloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Bromof1uorobenzene 

1,2-Dichloroethane-d4 

OTC Volatile Organics 

TCLP Leachate 

Method 8240 

urn Institute 

Enseco ID: 1060351 

Sampled: 15 NOV 89 

Prepared: 30 NOV 89 

Result 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

7.1 

ND 

ND 

ND 

8.9 

ND 

99.3 

93.3 

89.9. 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

fa 

f. 

% 

Received: 17 NOV 89 

Analyzed: 12 DEC 89 

Reporting 

Limit 

0.94 

9.4 

0.47 

0.47 

0.47 . 

9.4 

0.47 

0.47 

0.94 

0.47 

0.47 

0.47 

0.47 

0.47 

0.47 

0.47 

0.47 

0.47 

0.47 

.. 

.---

ND - Not detected 

NA » Not applicable 

Reported By: Tim Miller Approved By: Jeff Lowry 
P.88 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Appendix IX Volatile Organics (CONT.) 

Method 8240 

American Petroleum Institute 

TANK BOTTOMS #2 

007531-0004-SA Enseco ID: 

WASTE Sampled: 

17 NOV 89 Prepared: 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroetnene 

Toluene 

1,1,1-Trichloroethane 

1,1,2-Tri chloroethane 

Trichloroethp**? 

Trichlorof!i ometnane 

1,2,3-Tri chloropropane 

Vinyl acetate 

Vinyl chloride 

Xylenes (total) 

Toluene-d8 

4-Bromofluorobenzene 

1,2-Di chloroethane-d4 

1060351 

15 NOV 

20 NOV 

Result 

ND 

ND 

NO 

NO 

810 

ND 

ND 

ND 

ND 

NO 

NO 

NO 

1200 

96.9 

95.8 

67.2 

I 

89 

89 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

% 

%. 

Received: 17 

Analyzed: 29 

Reporting 

Limit 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

200 

200 

100 

--

--

NOV 

NOV 

89 

89 

i 

ND = Not detected 

NA * Not applicable 

Reported By: Terry Riddle Approved By: Jeff Lowry 
P.89 

\ 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Appendix IX Volatile Organics 

Method 8240 

American Petroleum Institute 

TANK BOTTOMS #2 

007531-0004-SA Enseco ID: 1060351 

WASTE Sampled: 15 NOV 89 

17 NOV 89 Prepared: 20 NOV 89 

Received: 17 NOV 89 

Analyzed: 29 NOV 89 

Acetone 

Acetonitrile 

Acrolein 

Acrylonitrile 

Allyl chloride 

Benzene 

Bromodi chloromethane 

3romoform 

Bromomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroprehe 

Chloroethane 

Chlorodi bromomethane 

Chloroform 

Chloromethane 

DBCP (1,2-Dibromo3-chloropropane) 

EDB (1,2-Dibromoethane) 

Dibromomethane 

trans-1,4rDichloro2-butene 

Di chlorodi fluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

Dichl oromethane 

1,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,4-Dioxane 

Ethyl benzene 

Ethyl cyanide 

2-Hexanone 

Iodomethane 

Isobutyl alcohol.:-:: 

Methacrylonitrile" 

Methyl ethyl ketone 

4-Methyl-2-pentanone 

esult 

ND 

ND 

ND 

NO 

ND 

290 

ND 

ND 

NO 

NO 

NO 

NO 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

NO 

NO 

NO 

ND 

ND 

110 

NO 

NO 

ND 

ND 

NO 

NO 

ND 

Units 

. mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

Reporting 

Limit 

200 

2000 

2000 

2000 

100 

100 

100 

100 

200 

100 

100 

100 

100 

200 

100 

100 

200 

100 

100 

ioo 

100 

200 

100 

100 

100 

100 

100 

100 

100 

100 

2000 

100 

100 

200 

100 

2000 

100 

200 

200 

ND = Not detected 

NA « Not applicable 

Reported By: Terry Riddle 

(continued on following page) 

Approved By: Jeff Lowry 
General Inorganics 

P.90 

Client Name: American Petroleum Institute. 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

STOCK TANK BOTTOMS 

007531-OOr"-SA Enseco ID: 1060349 

WASTE Sampled: 15 NOV 89 

17 NOV 89 Prepared: See Below 

Chloride 

Cyanide, Reactive 

Ignitabilit y 

Non-Volatile Oil 

Volatile Oil 

Oil 

Water 

? M ids 

-H 

5ulfide, Reactive 

Result 

8080 

NO 

66 

24.1 

7.9 

32.0 

42.9 

24.9 

7.3 

ND 

Received: 17 NOV 89 

Analyzed: See Below 

Units 

mg/kg 

mg/kg 

deg. F 

% 

% 

% 

% 

% 

units 

mg/kg 

Reporting 

Limit 

15 

0. 

0.5 

Analytical 

Method 

300.0 Mod. 

EPA/OSW 

1010/1020 

Chevron 

Chevron 

Chevron 

Chevron 

Chevron 

9045/ASTM 

EPA/OSW 

Prepared 

Date 

Analyzed 

Date 

06 DEC 89 11 DEC 89 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

NA 

30 NOV 89 

19 DEC 89 oz 

04 DEC 89 

04 DEC 89 

04 DEC 89 

04 DEC 89 

04 DEC 89 

21 NOV 89 

30 NOV 89 

Note o : This test is unreliable for any sample other than a 

non-aqueous 1iquid. 

Note z : Sample exhibits a characteristic of hazardous waste. 

ND = Not detected 

NA = Not applicable 

Reported By: Pam Rosas Approved By: Toni Lusk 
P.91 

Metals 

TCLP Oil Filtrate 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead ' 

Silver 

Mercury 

Selenium 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA Enseco ID 

WASTE Sampled: 

17 NOV 89 Prepared: 

Result 

ND 

ND 

ND 

1.5 

ND 

ND 

ND 

ND 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

: 1060349 

: 15 NOV 89 

: See Below 

Reporting 

Limit 

5 

0.5 

0.3 

0.6 

3 

0.5 

0.1 

0.5 

Analyt 

Received 

Ana' 

ical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

yzed 

: 17 NOV 89 

: See Below 

Prepared Analyzed 

Date Date 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

29 NOV 89 13 DEC 89 

06 DEC 89 08 DEC 89 

29 NOV 89 12 DEC 89 

ND = Not detected 

NA » Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.92 

Metals 

Aqueous Leachate 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Bari urn 

Cadmium 

Chromium 

Lead 

Silver 

Mercury 

Selenium 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA Enseco ID: 1060349 

WASTE Sampled: 15 NOV i 

17 NOV 89 Prepared: See Bel< 

Reporting 

Result Units Limit 

ND mg/L 0.5 

1.8 mg/L 0.3 

ND mg/L 0.03 

ND mg/L -0.05 

1.0 mg/L 0.3 

ND mg/L 0.05 

ND mg/L 0.002 

ND mg/L 0.05 

39 Rec 

3W Ana 

Analytical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

17 NOV 89 

See Bel ov* 

Prepared 

Date 

29 

29 

29 

29 

29 

29 

06 

29 

NOV 

NOV 

NOV 

NOV 

NOV 

NOV 

DEC 

NOV 

89 

89 

89 

89 

89 

89 

89 

89 

i 

Analyzed 

Date 

13 

13 

13 

13 

13 

13 

08 

12 

DEC 

DEC 

DEC 

DEC 

DEC 

DEC 

DEC 

DEC 

89 

89 

89 

89 

89 

89 

89 

89 

ND = Not detected 

NA = Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 
P.93 

1 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Silver 

Mercury 

Selenium 

Metals 

TCLP Leachate 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA Enseco ID: 1060349 

WASTE Sampled: 15 NOV 89 

17 NOV 89 Prepared: See Below 

Received: 

Analyzed: 

17 NOV 89 

See Below 

Result 

ND 

1.4 

ND 

NO 

0.8 

ND 

ND 

ND 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

Reporting 

Limit 

0. 

0. 

0. 

0. 

0. 

0, 

0. 

0, 

5 

3 

03 

05 

3 

05 

003 

05' 

Analytical 

Method 

200.7 

200.7 

200.7 

200.7 

200.7 

200.7 

7471 

270.2 

Prepared 

Date 

Analyzed 

Date 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

29 NOV 89 03 JAN 90 1 

06 DEC 89 03 JAN 90 1 

29 NOV 89 12 DEC 89 1 

Note 1 : Results based on multiphase analysis and mathematical 

recombination. 

ND = Not detected 

NA • Not applicable 

Reported By: Fred Velasquez Approved By: Tammy Bailey 

1 
P.94 

ICP/MS Metals 

Total Metals 

Client Name: American Petroleum Institute 

Client ID: STOCK TANK BOTTOMS 

Lab ID: 007531-0OO2-SA Enseco ID: 1060349 

Matrix: WASTE Sampled: 15 NOV 89 Received: 17 NOV 8.9 

Authorized: 17 NOV 89 Prepared: See Below Analyzed: See Below 

Reporting Analytical Prepared Analyzed 

Parameter Result Units Limit Method Date Date 

Osmium (189) ND mg/kg 0.4 RMAL 29 DEC 89 03 JAN 90 

ND = Not detected 

NA = Not applicable 

Reported By: Scott Heideman Approved By: Toni Tallarico 
1 

Client Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryl!ium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Lead 

Mercury • 

Nickel . 

Potassium 

Selenium 

Silver 

Sodium 

Thallium 

Tin 

Vanadium 

Zinc 

Metals 

Total Metals 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA Enseco ID: 1060349 

WASTE Sampled: 

17 NOV 89 Prepared: 

Result 

200 

ND 

22 

36 

NO 

ND 

2600 

6 

1 

100 

140 

NO 

6 

NO 

ND 

ND 

3900 

ND 

9 

1 

120 

Units 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

: 15 NOV 

: See Bel 

Reporting 

Limit 

10 

5 

3 

1 

0.2 

0.5 

20 

1 

1 

1 

5 

0.1 

4 

500 

1 

1 

500 

1 

8 

1 

4 

89 

ow 

Analyt 

Received 

Analyzed 

ical 

Method 

6010 

6010 

7060 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

6010 

7471 

6010 

6010 

7740 

6010 

6010 • 

7841 

6010 

6010 

6010 

: 17 NOV 89 

: See Below 

Prepared Analyzed 

Date Date 

21 

21 

21 

21 

21 

21 

21 

21 

21 

21 

21 

06 

21 

21 

21 

21 

21 

21 

21 

21 

21 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

OEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 08 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

DEC 89 27 

OEC 89 27 

DEC 89 27 

DEC 89 27 

OEC 89 27 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89-

DEC 89 

DEC 89 

DEC 89 

OEC 89 

OEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

DEC 89 

ND - Not detected 

NA - Not applicable 

Reported By: Bryan Anderson Approved By: Tammy Bailey 
P.96 

OTC Semivolatile Organics 

TCLP Leachate 

Method 8270 

Name: 

ID: 

CIient 

CIient 

Lab ID 

Matrix 

Authorized: 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA 

WASTE 

17 NOV 89 

Parameter 

Pyridine 

Phenol 

bis(2-Chloroethyl) ether 

1,4-Dichlorobenzene 

1,2-Dichlorobenzene 

o-Cresol 

m & p-Cresol(s) 

Hexachloroethane 

Nitrobenzene 

Hexachlorobutadiene 

2,4,6-Tri chlorophenol 

2,4,5-Tri chlorophenol 

2,4-Dinitrotoluene 

Hexachlorobenzene 

2,3,4,6-Tetrachlorophenol 

Pentachlorophenol 

Nitrobenzene-d5 

2-Fluorobiphenyl 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

Enseco ID: 

Sampled: 

Prepared: 

106034S 

15 NO" 

07 DEC 

Result 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

NO 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

78.7 

67.4 

68.4 

56.5 

54.0 

58.5 

19 

.9 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

f. 

fa 

fa 

fa 

fa 

fa 

Received: 17 NOV 89 

Analyzed: 20 DEC 89 

Reporting 

Limit 

0.85 

0.85 

0.85 

0.85 

0.85 

0.85 

0.85 

0.85 

0.85 

0.85 

4.2 

0.85 

0.85 

0.85 

4.2 

--

--

--

--

--

ND = Not detected 

NA - Not applicable 

Reported By: Robert Martin Approved By: Jeff Lowry 
P.97 

Refinery Hazardous Constituent Semivolatiles 

Method 8270 

Name: 

ID: 

CIient 

Client 

Lab ID: 

Matrix: 

Authorized 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA Enseco ID: 1060349 

WASTE Sampled: 15 NOV 89 

17 NOV 89 Prepared: 20 NOV 89 

Received: 

Analyzed: 

17 NOV 89 

07 DEC 89 

Parameter Result Units 

Anthracene 

Benzo(alanthracene 

Benzo(b)f1uoranthene 

Benzo(klfluoranthene 

Benzo(a)pyrene 

bis(2-Ethylhexyl) 

phthalate 

Butyl benzyl phthalate 

Chrysene 

Dibenz(a,h)anthracene 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Diethyl phthalate 

7,12-Dimethylbenzanthracene 

Dimethyl phthalate 

Di-n-octyl phthalate 

Fluoranthene 

Indene 

1-Methylnaphthalene 

Naphthalene 

Phenanthrene 

Pyrene 

Pyridine 

Quinoline. 

Benzenethiol 

o-Cresol • 

m & p-Cresol(s) 

2,4-Dimethylphenol 

2,4-Dinitrophenol 

4-Nitrophenol 

Phenol 

Nitrobenzene-d5'-:

; 

2--Fluorobi phenyl/: 

Terphenyl-dl4 

Phenol-d5 

2-Fluorophenol 

2,4,6-Tri bromophenol 

ND = Not detected 

NA =» Not applicable 

Reported By: Bob Martin 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

NO 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

ND 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

NO 

ND 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

fa 

fa 

fa 

fa 

fa 

fa 

Reporting 

Limit 

200 

200 

200 

200 

200 

• 200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

200 

1000 

1000 

200 

Approved By: Jeff Lowry 
P.98 

OTC Volatile Organics 

TCLP Leachate 

Method 8240 

Name: 

ID: 

CIient 

CIient 

Lab ID 

Matrix 

Authorized 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-

WASTE 

17 NOV 

0002-SA 

89 

Enseco ID: 

Sampled: 

Prepared: 

106C" 

15 N 

30 Nt. 

•9 Received: 17 NOV 89 

,9 Analyzed: 11 DEC 89 

Parameter 

Vinyl chloride 

Acrylonitrile 

Methylene chloride 

Carbon disulfide 

1,1-Dichloroethene 

Isobutyl alcohol 

Chloroform 

1,2-Dichloroethane 

2-Butanone 

1,1,1-Trichloroethane 

Carbon tetrachloride 

Trichloroethene 

1,1,2-Trichloroethane 

Benzene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

Chlorobenzene 

Toluene-d8 

4-Brombf1uorobenzene 

1,2-Dichloroethane-d4 

JSUlt 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

4.6 

ND 

ND 

ND 

7.0 

NO 

102 

99.0 

113 

Units 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

% 

fa 

fa 

Reporting 

Limit 

1.5 

15 

0.7' 

0.75 

0.75 

IS0.75 

0.75 

1.5 

0.75 

0.75 

0.75 

0.75 

0.75 

0.75 

0.75 

0.75 

0.75 

0.75 

--

--

ND = Not detected 

NA = Not applicable 

Reported By: Deneen Miller Approved By: Jeff.Lowry 
P.99 

Appendix IX Volatile Organics (CONT.) 

Method 8240 

CIient Name: 

Client ID: 

Lab ID: 

Matrix: 

Authorized: 

Parameter 

American Petroleum Institute 

STOCK TANK BOTTOMS 

007531-0002-SA Enseco ID: 1060349 

WASTE Sampled: 15 NOV 89 

17 NOV 89 Prepared: 20 NOV 89 

Received: 

Analyzed: 

17 

28 

NOV 

NOV 

89 

89 

Result Units 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

1,1,1-Trichloroethane 

1,1,2-Trichloroethane 

Trichloroethene 

Trichlorofluoromethane 

1,2,3-Tri chloropropane 

Vinyl acetate 

Vinyl chloride 

Xylenes (total) 

Toluene-d8 

4-Bromofluorobenzene 

1,2-Di chloroethane-d4 

ND 

ND 

ND 

ND 

1500 

NO 

ND 

ND 

ND 

ND 

ND 

ND 

2100 

99.5 

102 

107 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

mg/kg 

% 

% 

% 

Reporting 

• Limi t 

• 500 

500 

500 

500 

500 

500 

500 

500 

500 

500 

1000 

1000 

500 

ND - Not detected 

NA - Not applicable 

Reported By: Terry Riddle Approved By: Jeff Lowry