No.2FuelOil Note No.6FuelOil NoteBituminousCoal NoteSub‐bituminousCoal Note PetCoke NoteNaturalGas Note CleanWood Note Gasoline NoteOrganicHAPs(sum) 20840mg/Kg 1 12653mg/Kg 1 NF NF NF NF NF 264100mg/Kg 5Formaldehyde NF NF NF NF NF NF 7ppm 4 NF 4TOCorVOCinMaterial 100% 2 100% 2 NF NF NF 100% 2 20,000ppm 3 100% 2OrganicChlorides NF NF NF NF NF NF NF NFNF NotFound1 AlistofHAPsandothercompoundsfromFuelOilswasobtainedfromEPADoc.No.745‐B‐99‐003Datafromthatdocumentareshownontheworksheetnamed"CmpdsFuelOil".ThevaluesprovidedarethesumofHAPsfromthatdocument2 EssentiallyallthecompoundsinFuelOilsandNaturalgaswouldfallunderthecategoryTOCorVOC,thesefuelsarecomposedalmostentirelyofvolatileorsemi‐volatileorganiccompounds3 ThisvalueisobtainedfromtheturpentinecontentofVirginiaPine.Turpentineisgenerally70%ormorealpha‐andbeta‐pineneandalmostalloftheremainingcompoundshaveidenticalmolecularweights(allterpenes).ThissampleofVirginiaPinecontained2%turpentine.4 Seeworksheetnamed"FormaldehydeCleanWood"5 Seeworksheetnamed"Gasoline"Notes:Datafororganichalidesandorganiccompoundsinfuelsaredifficulttoobtain.Basedonthesearchconducted,itcannotbesaidthatthedataarenotavailable,asanexhaustivesearchwasnotconducted.ThusNF,forNotFound,isusedinthetableinsteadofNAfornotavailable.Clearlyformaldehdye,individualorganiccompound,andindividualorganichalidedataarenotgenerallyavailable.Thesearecompoundsattracelevelsinthefuelsthatwillbecombusted.Thetraceorganicsdifferfromthemetalsbecausemetalsarenotdestroyedincombustion,whereasthetraceorganicsare.Sincethereislittleornorelationshipbetweenthetraceorganicsgoingintoaboilerandtheamountreleasedfromthestack,therehasbeenno"driver"orneedforsuchinformation.Additionally,thesetracecompoundsdonotaffectthefuelqualityandareofnorealinteresttotheusers.Itislikelythatadeepenoughsearchthroughperiodicalswouldturnupsomeresearchontraceorganicsinthesefuels,but,asstated,anexhaustivesearchwasnotconducted.FromEPA745‐B‐99‐003,Jan,99 No.2FuelOil No.6FuelOil HAPs,mg/Kg HAPs,mg/Kg AppendixD,%,No.2FuelOilHAP weight% weight% No.2FuelOil No.6FuelOil min maxY Benzene 8.00E‐04 0.001 8.00 10.00Y Biphenyl 0.1 na 1000 na 0.006 0.009N Bromine na 3.00E‐06 0.03N Chlorine na 0.0131 131Y Ethylbenzene 0.013 0.0022 130 22 0.028 0.04Y n‐Hexane 1 na 10000 naY Naphthalene 0.55 0.1 5500 1000 0.009 0.4N Phenanthrene 0.125 na na 0.009 0.17Y Phenol 0.064 na 640 naN PACs na 1.13 11300Y Styrene 0.032 na 320 naY Toluene 0.0342 0.006 342 60 0.025 0.11N 1,2,4‐Trimethlybenzene 1 na naY xylene 0.29 0.013 2900 130AllDataasppmbyweight(mg/kg)27 cleanwood26 drypine,cleanwood3.59 cleanwood,Beech1.55 cleanwood,Beech5.17 cleanwood,Douglas‐fir2.07 cleanwood,Douglas‐fir5.97 cleanwood,Oak1.88 cleanwood,Oak3.34 cleanwood,Spruce2.77 cleanwood,Spruce2.17 cleanwood,Pine2.33 cleanwood,Pine6.5 oak,initial6.7 oak,5days5.6 oak,10days8.5 pineMin 1.55Max 27.00Median 4.38Mean 6.95StDev 7.9180thPercentile 6.7090thPercentile 17.25Count 16FromUSDept.ofHealth,Sept.1999,TOXICOLOGICALPROFILEFOR TOTALPETROLEUMHYDROCARBONS(TPH)FractionCompoundGasolineWeightPercentRangeGasolineWeightPercentMeanC6AromaticsBenzene 0.12‐3.50 2.34C3‐C6Aliphaticn‐Hexane 0.24‐3.50 2.61C7‐C8AromaticsToulene 2.73‐21.80 8.21Ethylbenzene 0.36‐2.86 1.9o‐Xylene 0.68‐2.86 2.71m‐Xylene 1.77‐3.87 3.5p‐Xylene 0.77‐1.58 3.5StyreneC7‐C8Aliphatics2,2,4‐Trimethylpentan 0.32‐4.58 1.64C9‐C10AromaticsIsopropylbenzene(Cum<0.01‐0.23Naphthalene 0.09‐0.49C11‐C12AromaticsBiphenyl mg/KgSum 26.41 264100CompoundswithDataforNo.2FuelOiln‐octanen‐nonanen‐decanen‐undecanen‐dodecanen‐tridecanen‐pentadecanen‐hexadecanen‐heptadecanen‐octadecanen‐nonadecanen‐eicosanen‐heneicosanen‐docosanebenzenetolueneethylbenzenebiphenylacenaphtheneacenaphthylenefluorenefluoranthene2,3‐benzofluorene1,2‐benzofluorenebenzo(a)fluorenebenzo(ghi)fluoranthenebenz(b)fluoranthenebenz(k)fluorantheneindeno(1,2,3‐cd)pyrenenaphthalene1methyl‐naphthalene2‐methyl‐naphthalene1,4‐dimethyl‐naphthaleneAnthracene2‐Methylanthracene2‐ethylanthracenephenanthrene1‐methyl‐phenanthrene2‐methyl‐phenanthrenepyrenechrysenetriphenylenebenzo(a)pyrenebenzo(e)pyrenebenzo(ghi)pyreneperylene3‐methyl‐cholanthrenebenzo(b)chrysenebenz(ghi)perylenepicenecoronene