# PROPYLENE

CAUT I ONARY RESPO NSE I N FOR MA TION Common Synonyms Uqu&fied OOR,:>tes&M 

## co1or reu 

# -Ode< Met hylet h'flene 

### Propene 

### II"**F~ts** 

### ano bOll$ 

### on water . F tatrrnable . 'VI S«ble vapor CfOud ;s produced , K eep people a way S hut off tgntt! on so ur ces a!Y.i call 

### h e**ce partr'e~**  S t a y upw.rd and u se water sp-ay t o 'kn oc k dow n" v apor ::vacuat e a tea tn c ase of l a r ge diS Ch a r ge Avo t

d contact Wi t h 1 - Qu t

d N o t

dy l oca l neall h and po ll l.t•on oc ntro l agenc ! es 

# Fire FLAMMABL E .**Co nt** **iner** 

### may explocte m fi re F !aShbiJ ck 

### a t ong vapor tra • may oeour . May explOde i f 

### IQI'Ifed in a n e/'lQO$eO**Cit ~**  

### $1op ftow · ot gas i f PQ$$tble 

### Cool expos.ect cON:a ine:t"$ and**pr~ec;t** 

### men**tf ~**  

### snvto ff 'Mth 

### water Le t fire 

### tun 

# Exposure CALL F OR MEOtCAL AID . 

### VAPOR If 

### W! a )!.d, wil 

### call$& (I ZZJ06Ss or lo$$ 

### o r eonsaousne ss . Move to fresh ai r . If b'eatl'ing has s t opped.**g~v e**  a rti fiCia l res p rauo n. If 

### tteatting is diftiM,**~~** 

### oxygen. LI QUI D Will**ea~** frOStbit& . F lus h affected a reas. 'Mttl plen t y 

## ot wate r 

### DO NOT RUB AFFECTED AAEAS . 

# Water**Notha rrrtu** **to~~ e**  

# Pollution

1 . CORRECTIVE RESPONSE ACTIONS 

### Stop <l scharge C hi! IT'ica l ard PhyS•cat Trt-at ment : Bu rn 

### 2 . CHEMICAL DESIGNATIONS 2..1 CG Compatibility Group : 30 . Ofefin 2.2 Formula :**C~** 2 . 3 

### IMOIUN O..lgnlllion : 

### 1011077 2 .4 DOT ro No.: t on 2.5 CASRegiattyNo .: 1 1 $-0 7 - 1 

### 2.6 NAERG Gukle 

### No .: 115 2.7 Standafd l tldustrlal T rade Clas.sification : 5 1 1 19 

### 3. HEALTH HAZARDS 3.1 Peraon.al Proltc:tive 

### Equipment Orgattri c vapo r ca1'11Sief or**a.r s~**  trGS k ; goggles o r**t~ce** - shiekj (for liQ ui d) . prote d ive eiOi t-. rg (for b QJ.Id) . 3 . 2 Symptomt Following Exposure: Moderate ooooent ra tion i n atr caU$M ctzziness. d rOWSiness . al'lCl unconsciousness . Cortact 'Mitl l quefleCI**pr~ne** 'Mil 

### ca>Ae .. freezing b.l'n . " 3 . 3 Treatment Of E.lcpoture: I N-W.. ATIO tt r errove victim f ro m elQX)S ure ; i f 

### tna tni og $$**l't' r**  Of has stQA:le <i. sta n resU$ci t3t'iort give oxvgen , ca!l a 

### doctot 

### 3.4 fLV·lWA: J>o-rt 

### 3 .5 TLV.STEL: fl.bt 

### isted . 

### 3.& Tt..V.CeUing: Noc l isted 3 . 7**Tox lcltybyl~tion** **:Not pe** **rn ne** **rc** 3.8 T oxioity by I nhalation: C urr e ntly not 3\13J i atjt . 3 . 0 Chronic T oxicity: None 3.10 Vapor { Gaa) l:ff i tant Characteri s tiu : vapl)fS are notW n tjtJng t o t he eyes 

### an:i ttY oat 3 . 11 1..1qoi d or Solid Char'ac1er ia tU :**No app~iatie**  haZard. P ta cticalty N u mleSs t o the ski n becaus.e it evapo r ates quiCkly 3-.12 Odor Threshotd: C urrently not ava il able 

### 3..1310LH Value : 

### No t bled . 3.14 OSHA PEL · TWA: 

### Nol liSted . 3.150SHAPEL.STE L : 

### Not lste<S. 3 . 16 OSHA 

### PE.L-CeiUng : 

### Not ksted 

### 3.17 EPA AEGL : NottSied 

### • . FI R E HAZARDS 4.1 Aaah Poi nt :



### - t6 2" F C . C (gas) 4 . 2 Flammabk! Umita in Ai r:**0% 11%**  4 . 3 Fire Ex.tinguilhin.g Agents : SlOP 

# now of 

### gas , 4 . 4 Fire 

### Extinguls t'tlng 

## ,ooents Not 

### to 

### 8e Used : 

### Not pertine:rt 4 .5 Special Huafdt 

### ol Combustion 

### Products : 

### Not peninent 4 . & Behaviot 

### in Fire: Contanus l'r'By explode . Vapx is heav i e r tha n air an::! may t r avet c ons idera ble d i stance to a**SO UI** **~** 

### o• igriti<)n and l'la$ h baCk 

### 4.7 Auto 

### tgnition Temperature: 851• F 4 . 8 Etec1rical Hazard&: Ctass I , Gto u p 0 4.9 Burning 

### Rate : 81"MVI'nt'l . (lq u ld) 4.10 

### AdiaNtic Flame**T~perature:** 25 18 . (E s t) 4.11 SIOk:homeerieAir to F uel Ratto : 2 1 . 4 

### ( eat. ) 4.12**F1a~** Temperature : 

### Cts rentt,t noc**ava.la~** 4 ,13 Combuttion 

### Mol• Ratio 

### CReactant to Procluc:t): 6 . 0 ( calc . ) 4 , 14 Mlnlm um**Oxygtt~** Concentradon 

### fOf Coml>uotlon (MOCC) : 

### N> dit ue ..- 1 15%; COl dl l uent 14 0 % 

## 5 . CHEMICAL REACTIVITY 

### 5.1 Reaetivity w4th 

### W*' : No re.cti o n 

### 5..2 R NCtiVIty 

### wilh COmmon**~lals :**  No rea cti o n $.3 Stabllity During Transport: Stable 

### 5.4 

### Neutraliting 

### Ag..,ts for Ac:id:l and c ..



### u.stict : 

### Not pertJnef1 

### 5.5 Potymeriza1ion: Nol pertinen 

### 5 . 8 l nhibilof of Polymerization : 

### NO' pefti ne ,. 

### 7 . SHIPPING INFOR MATION 7 . 1 

### Gra::l•ciPurity::**C~nica :**  92+% , polyl'l'ltri zation : 99+% , 

### res ea r Ch. 99•%. propt l ene conoen(rate ; 80•% 

### 7 . 2 Stolage Tempetature · : 

### Arl'O t nt 7 

### ..3 Inert Atmotophefe : No**r~retrett** 

### 7.4 Vonling : 5afe t y 

### re-iat 7 . 5 IMO POllutiOn Category : C urrently' not avad at.ee 

### 7.8 Shi p Type : C l.l'l'e ntly 

### no t avai.,ble 7.7 

### Bargo Hull TyPe : Cur r ent.ty not ava • labie 

### 8. HAZARD CLASSIFICATIONS 8 . 1 40 C F A Categoty: 

### fla rrnatle gas 8 . 2 49 CFA Claaa: 2 1 

### 8 . 3 .-9 

### CfR Package 

### Group : Nat 

### pMi nent 8 . 4 Maline Pottutant 

### No 8 . 5 NFPA Hazard Clasaifk:ation:

# ~~rd**(81uel~** ...

# ~.~ Flommablllly (Rod). .......... .. lnolabilily**(Yellow ~......** **.. ..** **..** 

### 1 U 

### EPA Repor10ble Quantity: Not 

### is1od. 

### 8. 7 EPA PoUutlon**~y:** Not l iSted 8.8 FtCAA Waste Numbef: 

### Not listed 

### 8 . 0 EPA FWPCA 

### Utt: Not l isted 

### 9. PHYSICAL & 

### C H EM ICAL PROPERTIES 9.1 Phyaeal State at 

### 15• c and1 nn : 

### Gas 9..2 Molecular Woi9M : 42 . 08 

### 9.3 Boili ng Point 

### at 1 

### atm:**53 9~F**  

## = 4 7 7•c 

# = 22s . s •K 9 . .. FrMZ:ing Point - 301 4*F •**185 ;;**  68'1< g

_ s Critieat Tempet'..wre : 1 97**~** • 91 8-c:: 

## ._

________________________**~ ~5** **~** 

### 6 . WATER POLLUTION 8.1 Aquatic Toxidty : None &.2 Watecfowl Toxicity : None 8.3 Biologica l O•ygon Domand (900) : ..,.... 

## 6 . ' Food Chain Concentrati on 

### Potential: None 6 . 5 G E SAMP Hazard Profile : Not l sted



### NOT ES 9.8 Crl1i eat Pressure: 670p6ia = 45.6 atm = 4 . 62 

# "'"'"' 9. 7 

### Specific 

### Gravity: 0 . 609 a t 

### --4 

# r c ( li QUid ) 9. 8 Uqukl 

### Surf-ace Tension : 1 6 . 7 

### OyneSicm:: o . o ·1 6 7 wmat 

### -47•c 9.9 Liquid Watw lntedaeial Tension : Not pertinent**10** 

### v_. (Gao)**Sl)«:~lc** 

### Gravity : 1 .4 9 . 11 Ratio of**Sl)«:~lc** 

### ... .,. of 

### Vapor (Gas) : 

### ' 152 i . 12 L.atentHeatofVapof i zation: 1 878tult)= 

### t04collg: 435X 10'JII<g i. 13 Heat of 

### CombUstion: -19 . 69 2 Stutb 

### =

- 1 0 ,940 eaVg : -<56 . 04 X 

### 10' Jll<g 9.1 .. 

### Heat o1 Decomposition : Not peru nett 9.15 Heat of Solution : Not pertinete 9. 1& Heat of 

### Polymerization: NOI partlntt"l 9.17 

### Heat of FutiOn: 1 7 . 06caVg 

### 9.18 Uml1ing Value : C u rentty no1**i'Vj ble**  9 . 19 Reid Vapor Pressure : 22 7 . 2 

### psia



## JUNE 1999

# PROPYLENE P P

L

9.20 9 , 21 

### g , 22 g

_ 23 

### SATURATED LIQUID DENSITY UQUID HEAT CAPACITY UOOD THERMAL CONDUCTIVITY LIQUID VISCOSITY Temperature Pouncts Ptf cubic 

### foo t 

### Tompera1ure Br itis h the rmal un it pet' T empe1ature 

### Britilh thermal 

### unit i nch Temperature 

### Cent i poise (deglaeof) 

### lde9reeo f') pound-F (dogr-F) ptf hour _.quare foot-F 

### (dogr- F ) 

### -145 41 .760 

### -70 0.553 

# c · 92 0 . 184

· 140 41 .550 

## -«> 0 . 561 

## u .lK) 

### 0 . 182

- 135 41 . 3 50 

### R**~** 

### 0.180



### · 130 41.140 

### R -a6 

### 0 . 178 -125 

### 40.930 

### E 

### -84 0. 1 7&



### · 120 40 . 720 N -82 

### 0 . 174 -115 

### 40 . 510 

### T -80 0 . 172

- 110 

### 40.300 

### L -7 8 0 . 170 -105 

### 40.100 y 

### · 78 0.1&8 

### ·100 39 . 8gQ -74 0 . 166 -95 39.680 N 

# . n 0 . 185



### - 00 39 . 470 0 -70 0 . 183 

### -3 5 39.2e0 

### T .e8 0 .1 81 -80 

### 39 . 060 -66 

### 0 . 160



### -75 38.850 

### A 

### -84 0.158



### - 70 38,640 

## v -32 0 . 156 

### -65 38,430 

### A -30 

### 0.155 -30 

### 38 . 220 

### I ·58 0.153 -55 38 . 020 

### L . 58 0 . 1 52 

### A -S4 0 . 150 

### B 

### L E

9 .24 

### g,2 5 9.28 9.27 SOLU BIUN IN WATER SATU RATED VAPOR P R ESSURE SAT U RATED VAPOR DENS I TY 

### I DEAL GAS HEA T CAPACITY Tem petature P oui'Mia per 100 pound s Tem perature Pounds per a.quate inch Temperature Pounds Pef cubic 

### foo t T emperahue 

### Bfitia.h thofmal unit pet 

### (dog r -F) 

# ,._ (dogr-F) (dogr- F ) 

## (cie91'""' F ) pound -F 

### I -165 0.251 

### · 165 0.00333 0 0.323 N 

### . 160 0 . 325 - 160 0 . 00425 25 0 . 336 

# s - 155 0 .417 

### · 155 0.00537 50 0.349 0 · 150 0.531 

### - 1 50 0 . 00672 75 0.382 L - 145 

# o .seg - 14 - 5 

### 0 . 00834 100 0.375 

## u · 140 0 . 837 · 140 0.01026 

### 125 0 . 387 B 

### - 135 1 . 037 

### -US 0 . 0 1 252 150 0.400 L 

### . 130 1 .278 

### -130 0 . 01518 

### 175 0 .412 

### E - 125 1 . 559 

### -12.5 0.018 2 6 200 0 .424



### · 120 1.892 · 120 0.02183 

### 225 

### OA36

- 115 

### 2.281 - 1 1 5 

### 0 . 02594 250 0 . 448

· 110 

### 2 . 731 .. 1 10 

### 0.03063 275 0 . 460

- 105 

### 3 . 254 - 105 

### 0.03597 300 

## o .. u2

· 100 3 . 854 ·100 0 . 04200 325 0.484 -95 4.!)4() 

### · 95 0 .04860 350 

### 0 . 495



### . go 5 . 322 . 90 0 . 05643 375 0 . 507 -65 6 . 207 - 85 

### 0 . 08494 400 0 . 518 -30 

### 7 . 207 -30 0 . 07441 

### 425 0 . 530 -75 8 .331 

### . 75 0.08489 450 

### 0 . 541

· 10 9 . 589 -70 0 . - 47 5 0 . 552 -6 5 10 . 900 -35 0.10920 500 0 . 563 -30 

### 12. 550 -30 0 . 12310 

### 525 0 .574 

### -55 14.280 . $$ 

### 0.13830 550 0 . 585 -50 16. 190



### -50 0 . 1$400 575 0 . 595 -45 18. 290 -45 

# o . nm 600 0 . 606 -40 

### 20 . 600 -40 

### 0.19240



## JUNE 1 99 9