# Support Documents for

Significant New Use Rule (SNUR s ) on

Premanufacture Notice s (PMN s)

P-10- 471 and P -10-472

EPA Docket EPA

- HQ

- OPPT -2011-0577

# Index

A-001 Structure Activity Team (SAT) Report for

PMN s P-10- 471 and P -10-472

A-002 Initial R eview Engineering Report for

PMN s P-10- 471 and P -10-472

A-003 Initial Review Exposure Report for

PMN s P-10- 471 and P -10-472

A-004 TSCA Section 5(e) Consent Order and

Determinations Supporting Consent Order for

PMN s P-10-47 1 and P -10-472

# A-001

Structure Activity Team (SAT) Report

for PMN s P-10- 471 and P -10- 472

# A-002

Initial Review Engineering Report

for PMN s P-10- 471 and P -10- 472p10-471 standard review engineering report

INITIAL REVIEW ENGINEERING REPORT

PMN: 10-0471

Standard Review Draft 8/31/2010

ENGINEER: Avcin \ AH
PV (kg/yr):

SUBMITTER:

USE:

OTHER USES:

MSDS: Yes Label: No

Gen Eqpt:

Respirator:

Health Effects:

TLV/PEL:

CRSS :

Chemical Name:

S-H20: 0.000001 g/L @

VP: 1.0E-6 torr @

MW: Physical State and Misc CRSS Info: Neat: Liquid Mfg: Proc/Form:

End Use:

Submitted Data: WS = Insoluble; VP =
Negligible; Flash Point > 100 °C; Density = 1.07 g/cc..

An IR spectrum is included in the PMN submission.

Estimated Data: BP > 400 °C ; VP < 0.

000001 torr ; WS < 0.000001 g/L

.

Consumer Use: No

SAT (concerns) (08/10/2010):

Related Cases and Related Cases and Misc SAT Info:

PMN: Health 1 Eco 1; Degradation Product: Health 2 Eco 3
Migration to groundwater: Negligible
PBT rating: P3B2T2 PMN: P3B1T1; Degradation Product:

P3B2T2 Health: 2 Not Required

Eco: 3 Not Required

OCCUPATIONAL EXPOSURE RATING: 2-3C

Page 1p10-471 standard review engineering report

NOTES & KEY ASSUMPTIONS: Generated by the 06/07/2005 version of ChemSTEER.

POLLUTION PREVENTION CONSIDERATIONS:

P2 Claim:

EXPOSURE-BASED REVIEW:

INITIAL REVIEW ENGINEERING REPORT

PMN: 10-0471

Processing:

Number of Sites/ Location:

Days/yr:

Basis:

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below

Page 2p10-471 standard review engineering report may coincide with daily releases from the other sources

to the same medium.

High End:

to:

from:

basis:

Conservative:

to:

from:

basis:

RELEASE TOTAL

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY Tot. # of workers exposed via assessed routes:

Basis:

Inhalation:
negligible (VP < 0.001 torr)

Dermal:

Exposure to High End: Number of workers (all sites) with dermal exposure:

Basis:

INITIAL REVIEW ENGINEERING REPORT

PMN: 10-0471

Use:

Number of Sites/ Location:

Days/yr:

Basis:

Page 3p10-471 standard review engineering report

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below
may coincide with daily releases from the other sources

to the same medium. The submission provides no information on the coating application. As conservative, it is assumed that at least some of the coating processes

occur at separate sites, and that there are some releases from potential spray coating.

High End:

to:

from:

basis:

Output 2:

to:

from:

basis:

Output 2:

to:

from:

basis:

RELEASE TOTAL

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY Tot. # of workers exposed via assessed routes:

Basis:

Page 4p10-471 standard review engineering report

Inhalation:

Exposure to

What-If:
Number of workers (all sites) with inhalation exposure:

Basis:

INHALATION MONITORING DATA REVIEW 1) Uncertainty (estimate based on model, regulatory limit or data not specific to industry): Yes

2)a) Exposure level > 1 mg/day? No

OR b) Hazard Rating for health of 2 or greater? 2 Yes

Inhalation Monitoring Data Desired? Yes (both criteria

met)

Dermal:

Exposure to High End: Number of workers (all sites) with dermal exposure:

Basis:



CALL BY: Ariel Hou Organization: ERG for CEB

CALL TO:

Organization:

Date: 08/11/2010

Time: 11:30AM

Phone:

PMN: 10-0471

Page 5p10-471 standard review engineering report

CALL BY: Ariel Hou
Organization: ERG

CALL TO:

Organization:

Date: 08/16/2010

Time: 1:30PM

Phone:

PMN: 10-0471

Page 6p10-472 standard review engineering report

INITIAL REVIEW ENGINEERING REPORT

PMN: 10-0472

Standard Review Draft 8/31/2010

ENGINEER: Avcin \ AH
PV (kg/yr):

SUBMITTER:

USE:

OTHER USES:

MSDS: Yes Label: No

Gen Eqpt:

Respirator:

Health Effects:

TLV/PEL:

CRSS :

Chemical Name:

S-H20: Dispersible g/L @

VP: 1.0E-6 torr @

MW: Physical State and Misc CRSS Info: Neat: Liquid Mfg: Proc/Form:

End Use:

Submitted Data: WS = Insoluble;
VP = Negligible; Flash Point > 100 °C; Density = 1.07
g/cc.. An IR spectrum is included in the PMN submission.

Estimated Data: BP > 400 °C VP < 0.

000001 torr WS < 0.000001 g/L

with dispersible as the worst case.

Consumer Use: No

SAT (concerns) (08/10/2010):

Related Cases and Related Cases and Misc SAT Info:

PMN: Health 1-2 Eco 1; Degradation Product: Health 2 Eco 3
Migration to groundwater: Negligible
PBT rating: P3B2T2 PMN: P3B1T1; Degradation Product:

P3B2T2

Health: 2 Inhalation

Eco: 3 Water (All releases to water with a CC = 1000 ppb)

OCCUPATIONAL EXPOSURE RATING: 2-3C

Page 1p10-472 standard review engineering report

NOTES & KEY ASSUMPTIONS: Generated by the 06/07/2005 version of ChemSTEER.

POLLUTION PREVENTION CONSIDERATIONS:

P2 Claim:

EXPOSURE-BASED REVIEW: No

INITIAL REVIEW ENGINEERING REPORT

PMN: 10-0472

Processing:

Number of Sites/ Location:

Days/yr:

Basis:

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below

Page 2p10-472 standard review engineering report may coincide with daily releases from the other sources

to the same medium.

High End:

to:

from:

basis:

Conservative:

to:

from:

basis:

RELEASE TOTAL

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY Tot. # of workers exposed via assessed routes:

Basis:

Inhalation:
negligible (VP < 0.001 torr)

Dermal:

Exposure to High End: Number of workers (all sites) with dermal exposure:

Basis:

INITIAL REVIEW ENGINEERING REPORT

PMN: 10-0472

Use:

Number of Sites/ Location:

Days/yr:

Basis:

Page 3p10-472 standard review engineering report

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below
may coincide with daily releases from the other sources

to the same medium.

High End:

to:

from:

basis:

Output 2:

to:

from:

basis:

Output 2:

to:

from:

basis:

RELEASE TOTAL

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY Tot. # of workers exposed via assessed routes:

Basis:

Page 4p10-472 standard review engineering report

Inhalation:

Exposure to

What-If:
Number of workers (all sites) with inhalation exposure:

Basis:

INHALATION MONITORING DATA REVIEW 1) Uncertainty (estimate based on model, regulatory limit or data not specific to industry): Yes

2)a) Exposure level > 1 mg/day? Yes

OR b) Hazard Rating for health of 2 or greater? 2 Yes

Inhalation Monitoring Data Desired? Yes (both criteria

met)

Dermal:

Exposure to High End: Number of workers (all sites) with dermal exposure:

Basis:



CALL BY: Ariel Hou Organization: ERG for CEB

CALL TO:

Organization:

Date: 08/11/2010

Time: 11:30AM

Phone:

PMN: 10-0472

Page 5p10-472 standard review engineering report

Page 6

# A-003

Initial Review Exposure Report

for PMN s P-10- 471 and P -10- 4729/23/10 Page 1 of 23



### STANDARD REVIEW EXPOSURE REPORT –

This report is the same as the Initial Review Report

Chemical ID: P-10-0471 Reviewer: Delpire/SS

Results Table: Dose, Concentration, and Days Exceeded Results Summary

Exposure Scenario 1 Water Landfill Stack Air Fugitive Air

Drinking Water Fish Ingestion

ADR LADD ADR LADD 7Q10 4

CC =

1000 PDM

Days

Exceede

d LADD ADR LADD ADR LADD

Release

activity(ies) 2 ;

exposure

calculation(s) 3 mg/kg/day mg/kg/day mg/kg/day mg/kg/day μg/l # Days mg/kg/day mg/kg/day mg/kg/day mg/kg/day mg/kg/day

PROC: Max ADR:

max acute eco

PROC: PDM1

PROC: Max LADD

USE: Max ADR:

max acute eco

USE: PDM1

USE: Max LADD

1 Exposure scenario titles consist of release activity followed by exposure calculation abbreviation.

2 Release activities are from engineering report's Manufact uring (Mfg), Processing (Proc) and Use release activity

labels. Multiple release activities are combined in one exposu re scenario if their releases occur at same location.

3 Exposure calculations are Acute Dose Rate (ADR), Lifetime Average Daily Dose (LADD), and Probabilistic

Dilution Model (PDM). There may be one, two, or all three exposure calculations per exposure scenario.

CC is the aquatic concentration of concern.

4 This column displays concentration values for the 7Q10 streamflow, which is defined as the average daily

streamflow of the seven consecutive days of lowest flow within a ten year period.

Remarks:9/23/10 Page 2 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0471 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:1 Number of Release Sites:

Release Activity: PROC: Max ADR

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 3 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 4 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 5 of 239/23/10 Page 6 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0471 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:2 Number of Release Sites:

Release Activity: PROC: PDM1

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 7 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 8 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 9 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0471 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:3 Number of Release Sites

Release Activity: PROC: Max LADD

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 10 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 11 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 12 of 239/23/10 Page 13 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0471 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:4 Number of Release Sites:

Release Activity: USE: Max ADR

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 14 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 15 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 16 of 239/23/10 Page 17 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0471 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:5 Number of Release Sites:

Release Activity: USE: PDM1

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 18 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 19 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 20 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0471 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:6 Number of Release Sites:

Release Activity: USE: Max LADD

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 21 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 22 of 23

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04719/23/10 Page 23 of 239/23/10 Page 1 of 20



### STANDARD REVIEW EXPOSURE REPORT –

This report is the same as the STANDARD Review Report

Chemical ID: P-10-0472 Reviewer: Delpire/SS

Results Table: Dose, Concentration, and Days Exceeded Results Summary

Exposure Scenario 1 Water Landfill Stack Air Fugitive Air

Drinking Water Fish Ingestion

ADR LADD ADR LADD 7Q10 4

CC =

1000 PDM

Days

Exceede

d LADD ADR LADD ADR LADD

Release

activity(ies) 2 ;

exposure

calculation(s) 3 mg/kg/day mg/kg/day mg/kg/day mg/kg/day μg/l # Days mg/kg/day mg/kg/day mg/kg/day mg/kg/day mg/kg/day

PROC: Max ADR:

max acute eco

PROC: PDM1

PROC: Max LADD

USE: Max ADR: max

acute eco

USE: Max LADD

1 Exposure scenario titles consist of release activity followed by exposure calculation abbreviation.

2 Release activities are from engineering report's Manufact uring (Mfg), Processing (Proc) and Use release activity

labels. Multiple release activities are combined in one expo sure scenario if their releases occur at same location.

3 Exposure calculations are Acute Dose Rate (ADR), Lifetime Average Daily Dose (LADD), and Probabilistic

Dilution Model (PDM). There may be one, two, or all three exposure calculations per exposure scenario.

CC is the aquatic concentration of concern.

4 This column displays concentration values for the 7Q10 streamflow, which is defined as the average daily

streamflow of the seven consecutive days of lowest flow within a ten year period.

Remarks:9/23/10 Page 2 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0472 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:1 Number of Release Sites:

Release Activity: PROC: Max ADR

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases: 0

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 3 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 4 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 5 of 209/23/10 Page 6 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0472 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:2 Number of Release Sites:

Release Activity: PROC: PDM1

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 7 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 8 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 9 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0472 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:3 Number of Release Sites

Release Activity: PROC: Max LADD

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 10 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 11 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 12 of 209/23/10 Page 13 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0472 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:4 Number of Release Sites:

Release Activity: USE: Max ADR

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 14 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 15 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 16 of 209/23/10 Page 17 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-0472 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:5 Number of Release Sites:

Release Activity: USE: Max LADD

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(kg/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:9/23/10 Page 18 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 19 of 20

STANDARD REVIEW EXPOSURE REPORT

Chemical ID: P-10-04729/23/10 Page 20 of 20

# A-004

TSCA Section 5(e) Consent Order

A nd Determinations Supporting Consent Order

for PMNs P -10- 471 and P -10- 472