# Patent

## Title
Thin film transistor and display substrate having the same

## Abstract

A display substrate includes a base substrate, a semiconductor active layer disposed on the base substrate, a gate insulating layer disposed on the semiconductor active layer, a first conductive pattern group disposed on the gate insulating layer and including at least a gate electrode, a second conductive pattern group insulated from the first conductive pattern group and including at least a source electrode, a drain electrode, and a data pad. The second conductive pattern group includes a first conductive layer and a second conductive layer disposed on the first conductive layer to prevent the first conductive layer from being corroded and oxidized.

## Background
CLAIM OF PRIORITY
This application makes reference to, incorporates into this specification the entire contents of, and claims all benefits accruing under 35 U.S.C. §119 from an application earlier filed in the Korean Intellectual Property Office on Jan. 15, 2013 and there duly assigned Serial No. 10-2013-0004527.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a thin film transistor and a display substrate having the same. More particularly, the present invention relates to a thin film transistor applied to an active type display device and a display substrate having the thin film transistor.
2. Description of the Related Art
In general, a display substrate is applied to a flat panel display device, e.g., a liquid crystal display device, an organic electroluminescent display device, etc., to realize lightweight and thin thickness of the flat panel display device.
The display substrate includes pixels arranged in a matrix form and displays an image by applying a source voltage to each pixel. The display substrate includes gate lines and data lines crossing the gate lines, and the gate lines are insulated from the data lines by an insulating layer. Each gate line is connected to a thin film transistor disposed in each pixel and applies a signal to the thin film transistor to control the thin film transistor. The thin film transistor switches a voltage applied to a corresponding pixel of the pixels. In addition, each data line applies the voltage to the corresponding pixel of the pixels.
Meanwhile, source and drain electrodes of the thin film transistor and the data line are formed of a conductive material, such as aluminum, copper, etc. However, aluminum and copper are vulnerable to corrosion and oxidation.
SUMMARY OF THE INVENTION
The present invention provides a thin film transistor capable of preventing source and drain electrodes from being corroded.
The present invention provides a display substrate having the thin film transistor.
Embodiments of the invention provide a thin film transistor including a semiconductor active layer that includes a source region and a drain region, a gate electrode insulated from the semiconductor active layer, a source electrode making contact with the source region, and a drain electrode making contact with the drain region. Each of the source and drain electrodes includes a first conductive layer that includes one of copper, a copper alloy, aluminum, and an aluminum alloy, and a second conductive layer disposed on the first conductive layer and including a molybdenum-nickel alloy.
The molybdenum-nickel alloy contains nickel of about 10 at % to about 50 at % with respect to an aggregate of the molybdenum-nickel alloy.
Each of the source electrode and the drain electrode further includes a third conductive layer disposed under the first conductive layer and including a same material as the second conductive layer. The second conductive layer and the third conductive layer include a molybdenum-nickel-titanium alloy. The molybdenum-nickel-titanium alloy contains nickel of about 15 at % to about 30 at % with respect to an aggregate of the molybdenum-nickel-titanium alloy and titanium of about 10 at % to about 20 at % with respect to the aggregate of the molybdenum-nickel-titanium alloy.
Embodiments of the invention provide a display substrate including a base substrate, a semiconductor active layer disposed on the base substrate, a first conductive pattern group insulated from the semiconductor active layer and including at least a gate electrode, a second conductive pattern group insulated from the first conductive pattern group and including at least a source electrode, a drain electrode and a data pad, and an organic light emitting device connected to the drain electrode. The second conductive pattern group includes a first conductive layer and a second conductive layer disposed on the first conductive layer, and the second conductive layer prevents the first conductive layer from being corroded and oxidized.
The first conductive layer includes one of copper, a copper alloy, aluminum, and an aluminum alloy, and the second conductive layer includes a molybdenum-nickel alloy.
The semiconductor active layer includes a semiconductor oxide, and the semiconductor oxide includes at least one of Zn, In, Ga, Sn, or a mixture thereof.
Embodiments of the invention provide a display substrate including a base substrate, a first thin film transistor disposed on the base substrate, a second thin film transistor disposed on the base substrate and electrically connected to the first thin film transistor, and an organic light emitting device connected to the second thin film transistor. The first thin film transistor includes a first semiconductor active layer, a first gate electrode, a first source electrode, and a first drain electrode, and the second thin film transistor includes a second semiconductor active layer, a second gate electrode, a second source electrode, and a second drain electrode. The first source electrode, the first drain electrode, the second source electrode, and the second drain electrode are disposed on a same layer, and each of the first source electrode, the first drain electrode, the second source electrode, and the second drain electrode includes a first conductive that includes one of copper, a copper alloy, aluminum, and an aluminum alloy, and a second conductive layer disposed on the first conductive layer and including a molybdenum-nickel alloy.
According to the above, each of the source electrode, the drain electrode, and the data line includes the conductive layer of molybdenum-nickel alloy, and thus the source electrode, the drain electrode, and the data line may be prevented from being corroded and oxidized.



BRIEF DESCRIPTION OF THE DRAWINGS
A more complete appreciation of the invention, and many of the attendant advantages thereof, will be readily apparent as the same becomes better understood by reference to the following detailed description when considered in conjunction with the accompanying drawings, in which like reference symbols indicate the same or similar components, wherein:
FIG. 1 is a circuit diagram showing a flat panel display device including a display substrate according to an exemplary embodiment of the present invention;
FIG. 2 is a plan view showing one pixel shown in FIG. 1;
FIG. 3 is a cross-sectional view taken along a line I-I′ shown in FIG. 2;
FIG. 4 is an enlarged view showing a portion PA shown in FIG. 1;
FIG. 5 is a cross-sectional view taken along a line II-II′ shown in FIG. 4;
FIG. 6 is a cross-sectional view showing a pixel of a display substrate according to another exemplary embodiment of the present invention;
FIG. 7 is a cross-sectional view showing a pad area of a display substrate according to another exemplary embodiment of the present invention;
FIG. 8 is a plan view showing a pixel of a display substrate according to another exemplary embodiment of the present invention;
FIG. 9 is a cross-sectional view taken along a line II-II′ shown in FIG. 8;
FIG. 10 is a cross-sectional view showing a pad area of a display substrate according to another exemplary embodiment of the present invention;
FIG. 11 is a plan view showing a pixel of a display substrate according to another exemplary embodiment of the present invention;
FIG. 12 is a cross-sectional view taken along a line III-III′ shown in FIG. 11;
FIG. 13 is a cross-sectional view showing a pad area of a display substrate according to another exemplary embodiment of the present invention;
FIG. 14 is a view showing an experimental result of corrosion and oxidation of a conductive layer of Mo/Al/Mo under high temperature and moisture conditions; and
FIG. 15 is a view showing an experimental result of corrosion and oxidation of a conductive layer of Mo—Ni—Ti alloy/Al/Mo—Ni—Ti alloy under high temperature and moisture conditions.



DETAILED DESCRIPTION OF THE INVENTION
It will be understood that, when an element or layer is referred to as being “on”, “connected to” or “coupled to” another element or layer, it can be directly on, connected or coupled to the other element or layer or intervening elements or layers may be present. In contrast, when an element is referred to as being “directly on,” “directly connected to” or “directly coupled to” another element or layer, there are no intervening elements or layers present. Like numbers refer to like elements throughout. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the present invention.
Spatially relative terms, such as “beneath”, “below”, “lower”, “above”, “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the exemplary term “below” can encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms, “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “includes” and/or “including”, when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention applies. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
Hereinafter, the present invention will be explained in detail with reference to the accompanying drawings.
FIG. 1 is a circuit diagram showing a flat panel display device including a display substrate according to an exemplary embodiment of the present invention.
Referring to FIG. 1, a display substrate DS may be applied to a flat panel display device, such as a liquid crystal display device, an organic electroluminescent display device, etc. In the present exemplary embodiment, the organic electroluminescent display device to which the display substrate DS is applied will be described as a representative example.
The organic electroluminescent display device includes the display substrate DS including a display part 10, a scan driver 20, and a data driver 30.
The scan driver 20 and the data driver 30 are electrically connected to the display part 10 through signal lines. The signal lines include scan lines SL1, SL2, and SLn, data lines DL1, DL2, and DLm, and source voltage supply lines VL, and any one of the signal lines crosses the other signal lines.
In detail, the scan driver 20 is electrically connected to the display part 10 by the scan lines SL1, SL2, and SLn. The scan driver 20 applies scan signals to the display part 10 through the scan lines SL1, SL2, and SLn. The scan lines SL1, SL2, and SLn are extended in a first direction on the display substrate DS.
The data driver 30 is electrically connected to the data lines DL1, DL2, and DLm through a pad (not shown) disposed in a pad area PA of the display substrate DS. Accordingly, the data driver 30 is electrically connected to the display part 10 through the data lines DL1, DL2, and DLm. The data driver 30 applies data signals to the display part 10 through the data lines DL1, DL2, and DLm.
The data lines DL1, DL2, and DLm are extended in a second direction different from the first direction so as to cross the scan lines SL1, SL2, and SLn. Thus, the data lines DL1, DL2, and DLm cross the scan lines SL1, SL2, and SLn.
The source voltage supply lines VL apply a source voltage to the display part 10. The source voltage supply lines VL cross the data lines DL1, DL2, and DLm and the scan lines SL1, SL2, and SLn.
The display part 10 includes a plurality of pixels PX. Each pixel PX is electrically connected to a corresponding data line of the data lines DL1, DL2, and DLm, a corresponding scan line of the scan lines SL1, SL2, and SLn, and a corresponding source voltage supply line of the source voltage supply lines VL. Each pixel PX includes a switching thin film transistor TRs, a driving thin film transistor TRd, a capacitor C, and an organic light emitting device OLED.
The switching thin film transistor TRs is connected to a corresponding data line of the data lines DL1, DL2, and DLm and to a corresponding scan line of the scan lines SL1, SL2, and SLn. Each of the switching thin film transistor TRs and the driving thin film transistor TRd includes a semiconductor active layer, a gate electrode insulated from the semiconductor active layer, and source and drain electrodes making contact with the semiconductor active layer.
According to the organic electroluminescent display device, the scan signals are applied to the pixels PX through the scan lines SL1, SL2, and SLn from the scan driver 20 and the data signals are applied to the pixels PX through the data lines DL1, DL2, and DLm from the data driver 30. The switching thin film transistor TRs of each pixel PX turns on or off the driving thin film transistor TRd in response to the scan signal and the data signal. The driving thin film transistor TRd applies a driving current to the organic light emitting device OLED according to the data signal. The organic light emitting device OLED generates light using the driving current.
Meanwhile, the capacitor C, which maintains the data signal during a predetermined time period, is connected between the drain electrode of the switching thin film transistor TRs and the gate electrode of the driving thin film transistor TRd. The data signal charged in the capacitor C applies the data signal to the gate electrode of the driving thin film transistor TRd after the switching thin film transistor TRs is turned off.
Although not shown in detail, the organic electroluminescent display device may further include additional thin film transistors and capacitors in order to compensate for a threshold voltage of the driving thin film transistor TRd.
Hereinafter, the structure of the display substrate DS will be described in detail with reference to FIGS. 2 and 3, and a direction in which the switching thin film transistor TRs, the driving thin film transistor TRd and the organic light emitting device OLED are disposed within the display substrate DS will be referred to as “upper portion”.
FIG. 2 is a plan view showing one pixel shown in FIG. 1, and FIG. 3 is a cross-sectional view taken along a line I-I′ shown in FIG. 2.
Referring to FIGS. 2 and 3, the pixel PX of the display substrate DS is electrically connected to the corresponding data line DL1 of the data lines DL1, DL2, and DLm, the corresponding scan line SL1 of the scan lines SL1, SL2, and SLn, and the corresponding source voltage supply line VL of the source voltage supply lines VL. Each pixel PX includes the switching thin film transistor TRs, the driving thin film transistor TRd, the capacitor C electrically connected to the switching thin film transistor TRs and the driving thin film transistor TRd, and the organic light emitting device OLED.
The switching thin film transistor TRs is connected to the corresponding data line DL1 and the corresponding scan line SL1. Each switching thin film transistor TRs and each driving thin film transistor TRd includes the semiconductor active layer SA, the gate electrode GE insulated from the semiconductor active layer SA, and source and drain electrodes SE and DE making contact with the semiconductor active layer SA.
In more detail, each switching thin film transistor TRs and each driving thin film transistor TRd includes the semiconductor active layer SA, the gate electrode GE insulated from the semiconductor active layer SA, and source and drain electrodes SE and DE making contact with the semiconductor active layer SA, which are disposed on a base substrate 100 formed of a transparent glass or plastic material.
The semiconductor active layer SA includes poly-silicon p-Si or oxide semiconductor. In addition, the semiconductor active layer SA includes a source region making contact with the source electrode SE, a drain region making contact with the drain electrode DE, and a channel region disposed between the source region and the drain region. To this end, the source and drain regions are doped with impurities. The oxide semiconductor includes at least one of Zn, In, Ga, Sn, or a mixture thereof. For instance, the oxide semiconductor may include indium-gallium-zinc oxide (IGZO).
Although not shown in the figures, when the semiconductor active layer SA includes the oxide semiconductor, a light blocking layer may be disposed on and under the oxide semiconductor active layer SA to block the light traveling to the oxide semiconductor active layer SA.
Meanwhile, a buffer layer 110 is disposed between the semiconductor active layer SA and the base substrate 100. The buffer layer 110 may be a silicon oxide layer or a silicon nitride layer, or may have a multi-layer structure of the silicon oxide layer and the silicon nitride layer. The buffer layer 110 prevents impurities from being diffused to the switching thin film transistor TRs, the driving thin film transistor TRd, and the organic light emitting device OLED, and prevents moisture or oxygen from being infiltrated into the switching thin film transistor TRs, the driving thin film transistor TRd, and the organic light emitting device OLED. In addition, the buffer layer 110 planarizes a surface of the base substrate 100.
A gate insulating layer 120 is disposed on the semiconductor active layer SA and the base substrate 100 to cover the semiconductor active layer SA and the base substrate 100, and thus the semiconductor active layer SA and the gate electrode GE are insulated from each other. The gate insulating layer 120 includes silicon oxide (SiO2) and/or silicon nitride (SiNx).
The scan line SL1 is disposed on the gate insulating layer 120 and extended in the direction. A portion of the scan line SL1 is extended to the pixel PX to serve as the gate electrode GE overlapped with the channel region of the semiconductor active layer SA.
An inter-insulating layer 130 is disposed on the gate insulating layer 120 and the gate electrode GE. The inter-insulating layer 130 includes silicon oxide or silicon nitride as the gate insulating layer 120. In addition, the inter-insulating layer 130 is provided with contact holes to expose a portion of the source region and a portion of the drain region.
The data line DL1 and the source voltage supply line VL, which cross the scan line SL1, and the source electrode SE and the drain electrode DE, which are insulated from the gate electrode GE, are disposed on the inter-insulating layer 130. The source electrode SE and the drain electrode DE make contact with the source region and the drain region, respectively, through the contact holes. The source electrode SE and the drain electrode DE include a conductive metal and a conductive polymer.
The data line DL1, the source voltage supply line VL, the source electrode SE, and the drain electrode DE include a first conductive layer 141 disposed on the inter-insulating layer 130 and a second conductive layer 145 disposed on the first conductive layer 141. The second conductive layer 145 blocks the diffusion of materials included in the first conductive layer 141 and prevents the first conductive layer 141 from being corroded or oxidized. For instance, the first conductive layer 141 includes copper (Cu), copper alloy (Cu-alloy), aluminum (Al), or aluminum alloy (Al-alloy) and the second conductive layer 145 includes molybdenum alloy (Mo-alloy). The molybdenum alloy includes molybdenum-nickel alloy (Mo—Ni alloy) and contains nickel of about 10 at % to about 50 at % with respect to an aggregate of the molybdenum-nickel alloy.
The capacitor C includes a first capacitor electrode C1 and a second capacitor electrode C2.
The first capacitor electrode C1 is formed of the same material as, and disposed on the same layer as, the scan lines SL1, SL2, and SLn and the gate electrode GE. That is, the first capacitor electrode C1 is disposed on the gate insulating layer 120.
The second capacitor electrode C2 is formed of the same material as, and disposed on the same layer as, the data line DL1, the source voltage supply line VL, the source electrode SE, and the drain electrode DE. That is, the second capacitor electrode C2 is disposed on the inter-insulating layer 130 and has a double-layer structure of the first conductive layer 141 and the second conductive layer 145. In this case, one of the first and second conductive layers 141 and 145 may be removed from the second capacitor electrode C2.
A protective layer 150 is disposed on the switching thin film transistor TRs, the driving thin film transistor TRd, and the capacitor C. The protective layer 150 may include at least one layer. In detail, the protective layer 150 includes an inorganic protective layer and an organic protective layer disposed on the inorganic protective layer. The inorganic protective layer includes at least one of silicon oxide or silicon nitride. In addition, the organic protective layer includes acryl, polyimide, polyamide, or benzocyclobutene. That is, the organic protective layer may have transparency and fluidity to planarize a lower layer thereof.
The organic light emitting device OLED is disposed on the protective layer 150. In addition, the organic light emitting device OLED includes a first electrode 160 making contact with the drain electrode DE of the driving thin film transistor TRd, a pixel definition layer PDL exposing a portion of the first electrode 160, an organic layer 170 disposed on the exposed portion of the first electrode 160, and a second electrode 180 disposed on the organic layer 170. Here, one of the first electrode 160 and the second electrode 180 is an anode electrode and the other one of the first electrode 160 and the second electrode 180 is a cathode electrode. In the present exemplary embodiment, the first electrode 160 serves as the anode electrode and the second electrode 180 serves as the cathode electrode.
The first electrode 160 includes a transparent conductive oxide, e.g., indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), gallium-doped zinc oxide (GZO), zinc tin oxide (ZTO), gallium tin oxide (GTO), fluorine-doped tin oxide (FTO), etc. The first electrode 160 may include a semi-transparent reflective layer to improve a light emitting efficiency of the organic light emitting device OLED.
The organic layer 170 is disposed on the portion of the first electrode 160 exposed by the pixel definition layer PDL. The organic layer 170 includes at least a light emitting layer EML and may have a multi-layer structure. For instance, the organic layer 170 includes a hole injection layer (HIL) that injects holes, a hole transport layer (HTL) that controls electrons, which are not combined with the holes in the light emitting layer EML, to enhance combination opportunities between the holes and the electrons, the light emitting layer EML that emits light using recombination of the holes and the electrons, a hole blocking layer (HBL) that controls movement of the holes not combined with the electrons, an electron transport layer (ETL) that transports the electrons to the light emitting layer EML, and an electron injection layer (EIL) that injects the electrons.
In addition, the light emitted from the organic layer 170 has one of red, green, blue, and white colors. For instance, when the organic light emitting device OLED is an RGB type, the color of the light emitting from the organic layer 170 of each pixel PX is one of the red, green, and blue colors. In addition, the organic light emitting device OLED is a WOLED type, the color of the light emitting from the organic layer 170 of each pixel PX being white. In the present exemplary embodiment, the color of the light emitted from the organic layer 170 is red, green, blue or white, but it should not be limited thereto or thereby. That is, the color of the light emitted from the organic layer 170 may be magenta, cyan, or yellow.
The second electrode 180 may include at least one of Mo, MoW, Cr, Al, AlNd, or aluminum alloy, has a work function lower than that of the first electrode 160, and reflects light.
In the present exemplary embodiment, the light emitted from the organic layer 170 travels to the first electrode 160, but it should not be limited thereto or thereby. For instance, in a case wherein the first electrode 160 includes a reflective layer (not shown) to reflect the light generated by the organic layer 170, and the second electrode 180 transmits the light, the light generated by the organic layer 170 may travel to the second electrode 180.
FIG. 4 is an enlarged view showing a pad area PA shown in FIG. 1 and FIG. 5 is a cross-sectional view taken along a line II-II′ shown in FIG. 4.
Referring to FIGS. 4 and 5, a data pad DP is disposed in the pad area PA of the display substrate DS of FIG. 1 and is electrically connected to the data line DL1.
The data pad DP has the same structure as the data line DL1. In detail, the data pad DP includes the first conductive layer 141 disposed on the inter-insulating layer 130 and the second conductive layer 145 disposed on the first conductive layer 141. The second conductive layer 145 blocks the diffusion of materials included in the first conductive layer 141 and prevents the first conductive layer 141 from being corroded or oxidized. For instance, the first conductive layer 141 includes copper (Cu), copper alloy (Cu-alloy), aluminum (Al), or aluminum alloy (Al-alloy) and the second conductive layer 145 includes molybdenum alloy (Mo-alloy). The molybdenum alloy includes molybdenum-nickel alloy (Mo—Ni alloy) and contains nickel of about 10 at % to about 50 at % with respect to an aggregate of the molybdenum-nickel alloy.
Hereinafter, a pixel of a display substrate will be described with reference to FIGS. 6 to 13 according to exemplary embodiments of the present invention. In FIGS. 6 to 13, the same reference numerals denote the same elements in as seen in FIGS. 1 to 5, and thus detailed descriptions of the same elements will be omitted.
FIG. 6 is a cross-sectional view showing a pixel of a display substrate according to another exemplary embodiment of the present invention, and FIG. 7 is a cross-sectional view showing a pad area of a display substrate according to another exemplary embodiment of the present invention.
Referring to FIGS. 6 and 7, each pixel of the display substrate DS includes a switching thin film transistor TRs, a driving thin film transistor TRd, a capacitor C electrically connected to the switching thin film transistor TRs and the driving thin film transistor TRd, and an organic light emitting device OLED making electrical contact with the driving thin film transistor TRd. In addition, a data pad DP is disposed in the pad area PA of the display substrate DS so as to be electrically connected to the data line DL1.
The switching thin film transistor TRs is connected to the scan line SL1 and the data line DL1 and the driving thin film transistor TRd is connected to the capacitor C and the source voltage supply line VL. Each of the switching thin film transistor TRs and the driving thin film transistor TRd includes a semiconductor active layer SA, a gate electrode GE insulated from the semiconductor active layer SA, and source and drain electrodes SE and DE making contact with the semiconductor active layer SA.
Each of the data line DL1, the source voltage supply line VL, the source electrode SE, the drain electrode DE, and the data pad DP includes the first conductive layer 141 disposed on the inter-insulating layer 130, the second conductive layer 145 disposed on the first conductive layer 141, and a third conductive layer 147 disposed under the first conductive layer 141.
The first conductive layer 141 includes one of copper (Cu), copper alloy (Cu-alloy), aluminum (Al), and aluminum alloy (Al-alloy).
The second and third conductive layers 145 and 147, respectively, may have the same material. The second and third conductive layers 145 and 147, respectively, block the diffusion of materials included in the first conductive layer 141 and prevent the first conductive layer 141 from being corroded or oxidized. The second and third conductive layers 145 and 147, respectively, may include molybdenum alloy (Mo-alloy). The molybdenum alloy may be molybdenum(Mo)-nickel(Ni)-titanium(Ti) alloy. The molybdenum alloy contains nickel of about 15 at % to about 30 at % with respect to an aggregate of the molybdenum alloy and titanium of about 10 at % to about 20 at % with respect to the aggregate of the molybdenum alloy.
The capacitor C includes a first capacitor electrode C1 and a second capacitor electrode C2. The first capacitor electrode C1 is formed of the same material as, and is disposed on the same layer as, the scan line SL1 and the gate electrode GE.
The second capacitor electrode C2 is formed of the same material as, and is disposed on the same layer as, the data line DL1, the source voltage supply line VL, the source electrode SE, and the drain electrode DE. That is, the second capacitor electrode C2 includes the first conductive layer 141 disposed on the inter-insulating layer 130, the second conductive layer 145 disposed on the first conductive layer 141, and the third conductive layer 147 disposed under the first conductive layer 141.
In addition, the organic light emitting device OLED includes the first electrode 160 making contact with the drain electrode DE of the driving thin film transistor TRd, the pixel definition layer PDL exposing the portion of the first electrode 160, the organic layer 170 disposed on the exposed portion of the first electrode 160, and the second electrode 180 disposed on the organic layer 170.
FIG. 8 is a plan view showing a pixel of a display substrate according to another exemplary embodiment of the present invention, FIG. 9 is a cross-sectional view taken along a line II-II′ shown in FIG. 8, and FIG. 10 is a cross-sectional view showing a pad area of a display substrate according to another exemplary embodiment of the present invention.
Referring to FIGS. 8 to 10, each pixel of the display substrate DS is electrically connected to the data line DL1, the scan line SL1, and the source voltage supply line VL. Each pixel includes a switching thin film transistor TRs, a driving thin film transistor TRd, a capacitor C electrically connected to the switching thin film transistor TRs and the driving thin film transistor TRd, and an organic light emitting device OLED making electrical contact with the driving thin film transistor TRd. In addition, a data pad DP is disposed in the pad area PA of the display substrate DS so as to be electrically connected to the data line DL1.
The switching thin film transistor TRs is connected to the scan line SL1 and the data line DL1 and the driving thin film transistor TRd is connected to the capacitor C and the source voltage supply line VL. One of the switching thin film transistor TRs and the driving thin film transistor TRd, e.g., the switching thin film transistor TRs, may have a top gate structure, and the other one of the switching thin film transistor TRs and the driving thin film transistor TRd, e.g., the driving thin film transistor TRd, may have a bottom gate structure.
The switching thin film transistor TRs includes a first semiconductor active layer SA1 disposed on the base substrate 100, a first gate electrode GE1 insulated from the first semiconductor active layer SA1, and a first source electrode SE1 and a first drain electrode DE1 which make contact with the first semiconductor active layer SA1.
The driving thin film transistor TRd includes a second gate electrode GE2 disposed on the gate insulating layer 120, a second semiconductor active layer SA2 insulated from and overlapped with the second gate electrode GE, and a second source electrode SE2 and a second drain electrode DE2 which make contact with the second semiconductor active layer SA2.
The capacitor C includes a first capacitor electrode C1 and a second capacitor electrode C2.
In detail, a buffer layer 110 is disposed on the base substrate 100 and the first semiconductor active layer SA1 is disposed on the buffer layer 110.
The first semiconductor active layer SA1 includes poly-silicon (p-Si) or oxide semiconductor. In the present exemplary embodiment, the first semiconductor active layer SA1 includes poly-silicon (p-Si).
A gate insulating layer 120 is disposed on the first semiconductor active layer SA1 and the buffer layer 110 so as to cover the first semiconductor active layer SA1, so that the first semiconductor active layer SA1 is insulated from the first gate electrode GE1.
The scan line SL1, the first gate electrode GE1 extended from the scan line SL1 and overlapped with the channel region of the first semiconductor active layer SA1, the first capacitor electrode C1, and the second gate electrode GE2 are disposed on the gate insulating layer 120.
A first inter-insulating layer 131 is disposed on the first gate electrode GE1, the first capacitor electrode C1, the second gate electrode GE2, and the gate insulating layer 120.
A second semiconductor active layer SA2 is disposed on the first inter-insulating layer 131 so as to overlap with the second gate electrode GE2. That is, the first inter-insulating layer 131 serves as the gate insulating layer of the driving thin film transistor TRd. In addition, the second semiconductor active layer SA2 includes amorphous silicon (a-Si) or oxide semiconductor. For instance, the second semiconductor active layer SA2 includes oxide semiconductor, and the oxide semiconductor includes at least one of Zn, In, Ga, Sn, or a mixture thereof.
A second inter-insulating layer 135 is disposed on the second semiconductor active layer SA2 and the first inter-insulating layer 131.
The data line DL1, the source voltage supply line VL, the first source electrode SE1, the first drain electrode DE1, the second capacitor electrode C2, the second source electrode SE2, and the second drain electrode DE2 are disposed on the second inter-insulating layer 135.
Each of the first source electrode SE1, the first drain electrode DE1, the second capacitor electrode C2, the data line DL1, the source voltage supply line VL, the second source electrode SE2, the second drain electrode DE2, and the data pad DP includes a first conductive layer 141 disposed on the second inter-insulating layer 131 and a second conductive layer 145 disposed on the first conductive layer 141. Here, the second conductive layer 145 blocks the diffusion of materials included in the first conductive layer 141 and prevents the first conductive layer 141 from being corroded or oxidized. For instance, the first conductive layer 141 includes copper (Cu), copper alloy (Cu-alloy), aluminum (Al), or aluminum alloy (Al-alloy) and the second conductive layer 145 includes molybdenum alloy (Mo-alloy). The molybdenum alloy includes molybdenum-nickel alloy (Mo—Ni alloy) and contains nickel of about 10 at % to about 50 at % with respect to an aggregate of the molybdenum-nickel alloy.
In addition, the organic light emitting device OLED includes the first electrode 160 making contact with the drain electrode DE of the driving thin film transistor TRd, the pixel definition layer PDL exposing a portion of the first electrode 160, the organic layer 170 disposed on the exposed portion of the first electrode 160, and the second electrode 180 disposed on the organic layer 170.
FIG. 11 is a plan view showing a pixel of a display substrate according to another exemplary embodiment of the present invention, FIG. 12 is a cross-sectional view taken along a line III-III′ shown in FIG. 11, and FIG. 13 is a cross-sectional view showing a pad area of a display substrate according to another exemplary embodiment of the present invention.
Referring to FIGS. 11 to 13, each pixel PX of the display substrate DS is electrically connected to the data line DL1, the scan line SL1, and the source voltage supply line VL. Each pixel PX includes a switching thin film transistor TRs, a driving thin film transistor TRd, a capacitor C electrically connected to the switching thin film transistor TRs and the driving thin film transistor TRd, and an organic light emitting device OLED making electrical contact with the driving thin film transistor TRd. In addition, a data pad PD is disposed in the pad area PA of the display substrate DS so as to be electrically connected to the data line DL1.
The switching thin film transistor TRs is connected to the scan line SL1 and the data line DL1 and the driving thin film transistor TRd is connected to the capacitor C and the source voltage supply line VL. Both the switching thin film transistor TRs and the driving thin film transistor TRd may have a bottom gate structure.
The switching thin film transistor TRs and the driving thin film transistor TRd include a semiconductor active layer SA, a gate electrode GE insulated from the semiconductor active layer SA, and a source electrode SE and a drain electrode DE which make contact with the semiconductor active layer SA.
The capacitor C includes a first capacitor electrode C1 and a second capacitor electrode C2.
Each of the data line DL1, the source voltage supply line VL, the source electrode SE, the drain electrode DE, and the data pad DP includes first conductive layer 141 disposed on the inter-insulating layer 130 and second conductive layer 145 disposed on the first conductive layer 141. A third conductive layer 147 could be disposed under the first conductive layer 141 as shown in FIG. 6 discussed above.
The first conductive layer 141 includes copper (Cu), copper alloy (Cu-alloy), aluminum (Al), or aluminum alloy (Al-alloy).
The second conductive layer 145 blocks the diffusion of materials included in the first conductive layer 141. The second conductive layer 145 includes molybdenum alloy (Mo-alloy). The molybdenum alloy includes molybdenum-nickel-titanium alloy (Mo—Ni—Ti alloy) and contains nickel of about 15 at % to about 30 at % with respect to an aggregate of the molybdenum alloy and titanium of about 10 at % to about 20 at % with respect to the aggregate of the molybdenum alloy. A third conductive layer 147 including molybdenum alloy (Mo-alloy) could be disposed under the first conductive layer 141 as shown in FIG. 6 discussed above so as to prevent the second conductive layer 145 from being corroded or oxidized.
In addition, the organic light emitting device OLED includes first electrode 160 making contact with the drain electrode DE of the driving thin film transistor TRd, pixel definition layer PDL exposing a portion of the first electrode 160, organic layer 170 disposed on the exposed portion of the first electrode 160, and second electrode 180 disposed on the organic layer 170.
FIG. 14 is a view showing an experimental result of corrosion and oxidation of a conductive layer of Mo/Al/Mo under high temperature and moisture conditions, and FIG. 15 is a view showing an experimental result of corrosion and oxidation of a conductive layer of Mo—Ni—Ti alloy/Al/Mo—Ni—Ti alloy under high temperature and moisture conditions.
Referring to FIG. 14, when the conductive layer having the structure of Mo/Al/Mo is exposed to the conditions of a temperature of about 85 degrees and an absolute humidity of about 85 percent during about 240 hours, corrosion occurs in the conductive layer.
Referring to FIG. 15, when the conductive layer having the structure of Mo—Ni—Ti alloy/Al/Mo—Ni—Ti alloy is exposed to the conditions of the temperature of about 85 degrees and the absolute humidity of about 85 percent during about 240 hours, corrosion does not occur in the conductive layer.
That is, the Al layer is prevented from being corroded by the Mo—Ni—Ti alloy disposed on and under the Al layer.
Although exemplary embodiments of the present invention have been described, it is understood that the present invention should not be limited to these exemplary embodiments but various changes and modifications can be made by one of ordinary skill in the art within the spirit and scope of the present invention as hereinafter claimed.

## Claims

1. A display substrate, comprising:
a base substrate;
a semiconductor active layer disposed on the base substrate;
a first conductive pattern group insulated from the semiconductor active layer and including a gate electrode and a first capacitor electrode insulated from the gate electrode;
a second conductive pattern group insulated from the first conductive pattern group; and
an organic light emitting device,
the second conductive pattern group comprises a source electrode, a drain electrode, a data line providing data signals to the organic light emitting device, a source voltage supply line extending along a same direction of the data line and receiving a source voltage different from a voltage applied to the data line, and a second capacitor electrode overlapped with the first capacitor electrode and protruding from the source voltage supply line;
each of the source electrode, the drain electrode, the data line, the source voltage supply line, and the second capacitor electrode including a first conductive layer comprising one of copper, a copper alloy, aluminum, and an aluminum alloy, a second conductive layer disposed on the first conductive layer, and a third conductive layer disposed under the first conductive layer; and
the second conductive layer and the third conductive layer comprise a molybdenum-nickel-titanium alloy, and the molybdenum-nickel-titanium alloy contains nickel of about 15 at % to about 30 at % with respect to an aggregate of the molybdenum-nickel-titanium alloy, and titanium of about 10 at % to about 20 at % with respect to the aggregate of the molybdenum-nickel-titanium alloy.

2. The display substrate of claim 1, wherein the semiconductor active layer comprises a semiconductor oxide.

3. The display substrate of claim 2, wherein the semiconductor oxide comprises at least one of Zn, In, Ga, Sn, and a mixture thereof.

4. A display substrate, comprising:
a base substrate;
a first thin film transistor disposed on the base substrate;
a second thin film transistor disposed on the base substrate and electrically connected to the first thin film transistor;
a data line;
a source voltage supply line extending along a same direction of the data line and receiving a source voltage different from a voltage applied to the data line;
a first capacitor electrode;
a second capacitor electrode overlapped with the first capacitor electrode and protruding from the source voltage supply line; and
an organic light emitting device connected to the second thin film transistor;
the first thin film transistor comprises a first semiconductor active layer, a first gate electrode, a first source electrode, and a first drain electrode;
the second thin film transistor comprises a second semiconductor active layer, a second gate electrode, a second source electrode, and a second drain electrode;
the first source electrode, the first drain electrode, the second source electrode, the second drain electrode, the data line, the source voltage supply line, and the second capacitor electrode are disposed on a same layer; and
each of the first source electrode, the first drain electrode, the second source electrode, the second drain electrode, the data line, the source voltage supply line, and the second capacitor electrode comprises:
a first conductive layer that includes one of copper, a copper alloy, aluminum, and an aluminum alloy;
a second conductive layer disposed on the first conductive layer; and
a third conductive layer disposed under the first conductive layer; and
the second conductive layer and the third conductive layer comprise a molybdenum-nickel-titanium alloy, and the molybdenum-nickel-titanium alloy contains nickel of about 15 at % to about 30 at % with respect to an aggregate of the molybdenum-nickel-titanium alloy, and titanium of about 10 at % to about 20 at % with respect to the aggregate of the molybdenum-nickel-titanium alloy.

5. The display substrate of claim 4, wherein at least one of the first semiconductor active layer and the second semiconductor active layer comprises a semiconductor oxide.

6. The display substrate of claim 5, wherein the semiconductor oxide comprises at least one of Zn, In, Ga, Sn, and a mixture thereof.

7. The display substrate of claim 4, further comprising:
a gate insulating layer disposed between the first semiconductor active layer and the first gate electrode, and between the second semiconductor active layer and the second gate electrode; and
an inter-insulating layer disposed on the first and second gate electrodes;
wherein the first and second semiconductor active layers are disposed on the base substrate.

8. The display substrate of claim 4, further comprising:
a gate insulating layer disposed between the first semiconductor active layer and the first gate electrode;
a first inter-insulating layer that covers the first gate electrode; and
a second inter-insulating layer disposed on the first inter-insulating layer;
wherein the first semiconductor active layer is disposed on the base substrate, the first and second gate electrodes are disposed on the gate insulating layer, and the second semiconductor active layer is disposed on the first inter-insulating layer.

9. The display substrate of claim 4, further comprising a gate insulating layer disposed between the first semiconductor active layer and the first gate electrode and between the second semiconductor active layer and the second gate electrode, wherein the first and second semiconductor active layers are disposed on the gate insulating layer.