CnmpoMnt Dala ~ 

1X1o" 

1x1d' 

-' 

II 1X1o' _, .. ~ 

7X1o' ..J 

3x1o' 

0 

111.40 21.00 28.80 sa no ........... 

VES 006200 
Calibration Update Report 

· Sample Name : CALm Sml 080902 

Data File Name : C:\PFA KNET\DATA\AN10 N\10-23_AASOOJ.DXD 

Method File Name : c:\peak:net\roethodlmelhod\120anionsmet 

Schedule File Nan1e : c:\peala>ellschedulelschedule\schedule\l20anions\2008\l2Qanion0902.scb 

Date Time Collected : 2008-09.02 4:23:48 PM 

Calibration Date : 2008-09.02 4:32:58 PM 

Sys1em Operator : LLE 

Peak lnfonnation : All Components 

Peat# Component Name Retention Tillle Cal Response Cal Response 

(PrevioU$) (Measured) 

0 (null) 0.00 0 0 

Chloride 

Nitrite 

Bromide 

Nittate 

Phosphate 

Sulphate 

CALIB STDJ 0809()2 

16.0 

14.0. 

12.0 

10.0 

"' 8.0 

"' 6.0 

4.0 

2.0 

o, 

-2.oL . ' 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 ... 

Pa.e;e I of I 

Cal Response 

(New) 

0 

' 

9.0 

O.M'retli D.ltc: 2008-09-Ql 

Cu«cilt Time : 1&.32;59 

VES 006201 
Calibration Update Report 

Samplo Nome: CALmSTD2 080902. 

. Data Flit Name : C:\l'EAKNE:r\DA TAIANlON\1 0-23_AA T002..DXD 

Method File Name: c:\peaknet\methodlmctbodll20unlons.mct 

Schedule File Na.= : c:lpealo.let\scbedule\schcdulc\.wl\cdulc\J20anionsi2008\J20union0902.sch 

Date Time Collected : 2008-09-02 6:07:38 PM 

Calibration Date: 2008-09-02 6:16:16 PM 

Systcan Opcr310r : LLE 

Peale lnfonnalion : AU Componeots 

Peak #I Compone.nt Name Reteotioa Tlmt Col Response Cal Rt:sponse 

(l'r~us) (Musured) 

I Fluoride 1.02 3572 3816 

2 Chloride 1.62 4822 3649 

3 Nitrite 1.98 4899 5334 

4 Bromide 3.07 2296 2392 

s Nilmle 3.53 6040 6399 

6 Phosphate 5.8) 21162 23257 

7 Sulphate 7.82 3305 2538 

CALIB STD2 080901 

16.0f 14.0 

12.0 

JO.Ot 

'i 8.0 

6.0 

::1 2 3 4 s 6 

I I I I I 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 

: ~kNt:RtE S.IOd f'a~~:s 1 ofl 

Cal R .. ponse 

(Now) 

3816 

3649 

5334 

2392 

6399 

23257 

2538 

7 

I 

8.0 

Cllmnl Dm: 2008.00.02 

C11ncnt 1""-: 18:-16:18 

VES 006202 
Calibration Update Report 

· Sample Name : CALIB STD3 081)902 

l>ata.File Name: C:\PEAKNEl'IDATA\ANION\10-23_AATOOJ.DXD 

Melhod File Name: c:\peaknet\method\method\120anioos.rnei 

Schedule File Name : c:\peaknet\scbedule\schedule\scbedulell20anioos\20081120anion0902.seb 

Date Time Collected : 2008-09-02 6:17:07 PM 

Calibnltion Date : 2008..09-02 6:25:47 PM 

System Operator : LLE 

Peak Information : All Components 

Peak # Component Name Retention Time Cal Response Cal Respo1ou 

(Previous) (Measund) 

I Fluoride 1.00 33292 35210 

2 Chloride 1.62 38508 37713 

3 Nitrite 1.97 31469 33632 

4 Bromide 3.05 30~;27 33099 

5 Nitrate 3.52 . 60219 64144 

6 Phosphate 5.83 60108 63741 

? Sulphate 1.n 103170 107881 

. 

CALIB STD3 080902 

16.0 

14.0 

12.0 

10.0 . 

"' 8.0 

"- 6.0 

4.0 

I 2 3 4 5 6 2.0 ~ ~ i I ), I 

0 -... -2.0 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 . .. 

~~ :Peak.Net-SES.IOd 

. Cal Response 

(New) 

35210 

3n13 

33632 

33099 

64144 

63741 

107881 

7 

I 

.----..__ 

8.0 

Ottrent Date : 2008·09-0:l 

<.\ttTeM Time.: 1&2.5:49 

VES 006203 
Calibration Update Report 

Somple Name : CALIB STD4 080902 

Data File Name: C:\PEAKNE'I\DATA\ANlON\10-23_AAS004.DXD 

Method File Name: c:\peaknet\medtod'.notbod\120anions.met 

Schedule File Name: c:lpeakne1\scbcdule\scbcdulc\9<:bedule\120anions\2008\l20anion0902 .. sch 

Date Time Collected: 2008-09..()2 6:26:38 PM 

Calibration Date : 2008-09..()2 6:35:19 PM 

SyslO!n Operator : LLB 

Peak lnfonnaiion : All Components 

Peok II Component Na- !Utflltloo TIJne Col Rospoll$0 Cal R<Spoll$0 

2 

3 

4 

5 

6 

7 

8 

Fluoride 

Chloride 

Nitrite 

Bro.mide 

Nilmte 

Phosphate 

Sulphate 

16.0 

14.0 

12.0 

10.0 

8.(> 

0.98 

1.60 

1.97 

3.03 

3.48 

5.78 

7.73 

(l'revions) (M..uurc:d) 

196784 192132 

199137 192682 

184267 182878 

168919 164438 

340458 328604 

351467 341755 

578245 560950 

CALJ1J STD4 080902 

6.0 2 3 4 6 8 

Col R<spoJUe 

(New) 

192132 

192682 

182878 

164438 

328604 

341755 

560950 

I l S I 7 1 

:~ .. Jl-U_}J\'-----·---' I '--~~~~~-::-::-- 0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 

h M.elori 

C\ltRnt Otoe : 4~9-02 

CW'rem. Time: 18;l.S:l0 

VES 006204 
Calibration Update Report 

Sample Name : CALJB STDS 080902 

Data File Name : C:\PEAKNE'I\I)ATA\ANJON\lll-23 _AASOOS.DXD 

Method File N.ame : c:lpeaknetlmethod\method\120anions.met 

Schedule File Name: c:\peaknet\schedule\scltedulclscbedulc\120anionsl200&\120anion0902.scb 

Date Time Collected : 2008-09-02 6:36:08 PM 

Cahl>ration Date: 2008-09-02 6:44:51l'M 

System Operator : LLE 

Peak lnfonnation : All Components 

Peak# Component Name Retention Tinte Cal Response 

(Previous) 

Cal Response 

(Measatred) 

Cal Response 

(New) · 

------· ---------~-------------

2 

3 

4 

5 

6 

7 

3 

Fluoride 

Chloride 

Nitrite 

Bromide 

Nitrate 

Phospbalc 

Sulphate 

0.98 

1.60 

1.97 

3.02 

. 3.45 

5.15 

7.68 

400612 

404166 

332606 

340805 

690717 

718726 

1163556 

CALIB SID5 080902 

16.0 

14.0 

12.0 

10.0 2 3 6 

4 I 

M 1 ~ 

~ t '---.../~ I ~~--.~1 '-- '- . V !--"7--:-~ -- --..,.,,.---::-. 0 LO 2.0 3.0 4.0 5.0 

423787 

426352 

406593 

358816 

723267 

756481 

1224368 

3 

I 

423787 

426352 

406593 

358816 

723267 

756481 

1224368 

7 

I 

'----Jl 

6.0 7.0 8.0 

Cw-rent Date : lootl-09-02 

CutrentTill'lt' : 18:44:$1 

VES 006205 
Calibration Update Report 

Sample Name : CALIB STD6 080902 

Data File Name: C:IPEAKNE1\DATA\ANION\10-lJ_AAS006.DXD 

Method File Name: c:lpeaknet\mel~od\met od 0anio niel 

Schedule File Name: c:lpeaknetlscbedule\schcdulc\schedu.lc\120anions\2008\120anion0902.sch 

Date Time O>Uected : 2008-09-02 6:45:41 PM 

Calib<ation Date : 2008-09-02 6:54:22 PM 

S}'$\cm Operatoc: LL.E 

Peak lnformal.ioo : All Components 

Peak# Co.mpones1t Name Retention nmc Cal Response Cal RespGnse 

(Previous) (Measllrtd) 

2 Fluoride ().98 6S09S6 63839'7 

3 Chloride 1.6() 662215 647991 

4 Nitrite 1.9'7 618954 609174 

s Bromide 3.02 551959 540670 

6 Nitrate 3.43 I 129195 1103812 

7 Phosphate 5.70 1174736 1150612 

& Sulphate 7.65 1893428 1847423 

CA.LIB STD6 080902 

16.() 2 

14.() I 6 

I 

12.() 4 

I 

10.0 s 7 

I I 

"' 8.0 .. 6.0 

4.0 

2.0 

~ I \. I 

0 \... 

·2.0 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 ... 

: fldkNe•·Se s.Jod PDJ:l: I of l 

8 

I 

Gal Response 

(New) 

63839'7 

647991 

609174 

540670 

11 03812 

I 150612 

1847423 

8.0 

O.rt<onl O.c-: 2 

CwreotTirnc: tt:.s4aJ 

VES 006206 
Sample Analysis Report 

Sample Name : ICB 

Data File Nam.e : C:\PEAl<NET\DATA\ANION\10-23_AASU07.l>XD 

Detector Type : DX-120 

Method File· Name : c:lpeal<net\method\metbod\120anions.met 

Schedule File Naine : c:lpealcnet\..:hedule\•cbedule\scbedule\l2()anions\2008\120anion0902.sch 

Date Time Collected : 2008-09-02 6:ss: II PM . 

System Operator : LLE 

Cah'briltion Date : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor : 1.00 

Peak Information : All Peaks 

Pe•k # Compoaeut Name Amount (mg/L} Retention Time Peak Area 

ICB 

16.0 

14.0 

12.0 

10.0 

V> s.o :1.. 6.0 

4.0 

2.0 

0 

-2.0 . ·~ · ··-· .... 0 !.0 2.0 3.0 4.0 s.o 6.0 7.0 . .. 

hRelofl 

Peak Height 

8.0 

OlmM [hte : 2008-09-03 

eurrecu fime:·: 13:23:02 

VES 006207 
Sample Analysis Report 

Sample Name: ICV 

Data File Name: C:\PEAKNE'ru>ATAIANION\IG-Z3_AAR008.DXD 

Dc~tot· Type : DX-120 

Method File Nrune : c:lpeaknetlmeU!Od\methodll20•nious.met 

Schedule File Name: c:lpeaknet\scbedulelschedule\<;cbcdule\120anionsl200811 20aruon0902.sch 

Date Time Collected : 2008·09-02 7:04:44 PM 

S)'l!iem Operator : LLE 

Calibration Date : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 1.00 

Peak lnfoanatlon :All Peaks 

P ... t # Compoaeot Name Amoaat (mg!L) Reto11tioD Time 

l 0.0000 0.80 

2 Fluoride 3.0200 0.98 

3 Chloride 4.5195 1.60 

4 Nitrite 2.2869 1.97 

s Bromide 8.9963 3.03 

6 Nitrate 3.0023 3.47 

7 Phosphate 9.0262 5.15 

8 Sulphate 18.0669 7:70 

JCV 

l6.0I 

14.0 

12.0 

10.0 

8.0 2 3 6 

V> 

,. l 4 I 

6.0 :lc I 5 7 

4.0 l I 

2.0 

0 

·2.0 

0 1.0 2.0 3.0 4.0 5.0 . .. 

loti 

-----~--------------~--

. 

6.0 

PealcArta Peai<U~lrt 

--- 12050 2032 

308859 61128 

309234 62950 

298761 48613 

260615 37662 

526424 60746 

548537 39374 

892603 52088 

8 

I 

7.0 8.0 

C\ltrclrt .O..Ie ; 2Q08.09r..02 

CUn'entTi.me : 19:1;5!'26 

VES 006208 
Sample Analysis Report 

Sample Name : QCS 1CMIX6 

o a .. File Name: C:IP£AJOIIE1\DATA\ANION\JQ..l3_AAQ009.DXD 

Detector Type: OX-120 

Method l'ile Name : c:~et\method\method\120anioruo met 

Schedule File Name: c:\pealmet\sehedule\scbedulelsclledule\120nnions12008\120anion0902.seh 

Date Time Collected : 2008..09-02 7:14:45 PM 

Sys:em ~ralor : LLE 

Calil>.ratioo Date : 2008-09-02 6:54:22 PM 

Calibration Type: EX'l"ERNAL 

Compontnl Amouol Unl:s : mgiL 

Dilution Factor : LOO 

1' .. 1< Information : All Peaks 

Peak II Component Name Amount (me/L) Retention Time 

- .... .. I 0.0000 0.80 

2 Fluoride 2.0503 ' 0.98 

3 Chloride 5.0858 1.60 

4 Nilrite 2.7528 1.97 

5 Bromide 10.0092 3.03 

6 Nitrate 2.4422 3.48 

7 Pbospb•te 4.8332 5.78 

8 Sulphate 15.1582 1.n 

QCSTCM!X6 

16.0 

14.0 

. 12.0 

10.0 

8.0 3 4 'fi I 5 6 

6.0 :LL I 

4.0 

'"'r~ 7 

2.0 I 

0 

-2.0 

0 1.0 2.0 3.0 4.0 S.O 6.0 .. 

Ill : PeaJdfa..Se S.IOd 

Peak Are• PeakJleigbt 

11310 1906 

205833 37945 

350<122 65825 

3630SO 57538 

291326 40341 

423616 49110 

283356 20368 

743170 43307 

8 

I 

7.0 8.0 

C\tJ:rCIU I.MU : 1()()3.09.(Jl 

C'lmetll T"tmc- : 19:23:23 

VES 006209 
Sample Analysis Report 

Sample Nome : MllLANK 

Data File Name : C:\PEAJOIIET\DATAIANION\JO-l3_AA0018.DXD 

Dctcct~rType: DX-120 

Method File Name : c:lpeaknet\methodlmeU10d\120unions.met 

Schedule File Name: c:lpeabwt\scbedulclsehedulelscbedulo\120anionsl2008\120anion0902.sch 

Date Time CoUccted : 2008-09-02 8:39:41 PM 

Sysu:m Operator : LLE 

Calibration Date : 200&-09-02 6:54:22 PM 

GaUbnttion Type : EXTERNAL 

Compoocot A.moun1 Units : mgiL 

Dilution Factor : 1.00 

Peak tnfo1'11)8tioo : All Peaks 

Puk # Component Name Amount {mg/L) Retention Tune Peak Area 

·- - ·"-- -·- · -·· 

MBLANK 

16.01 . 

l<lOf 

. 

12.0 

10.0 

"' 8.0 ... 6.0 

4.0 

2.0 

0 

-2.01-. 

0 1.0 2,0 3.0 4.0 5.0 6.0 7.0 

. -

P~w; I otl 

Peak ffeigllt 

8.0 

Clll'lolll DoJc-: 2008..()9...03 

Cur;mc Time : 16:04:29 

VES 006210 
Sample Analysis Report 

SampJt Name: MSPIKE 

Dota FUt Name : C:\PEAKNET\DATA\ANION\JO..l3_AA0019.DXD 

Detector Type : DX·l20 · 

Method File Nam.e: c:lpeatnct\method\mcthodll20unions.mct 

Sehedule File Name : c:\peaknet\sched\llelschedulc\scho:dule\120anions\2008\ 120anion0902.sch 

Date Time Collected: 2008-09·02 8:49:12 PM 

System Operator : LLE 

Calibration Date : 2008-09..02 6:54:22 PM 

Calibration Type : EXTERNAL 

Compoo""l Amount Units : mgiL 

Dilution l'aciOr: 1.00 

Peak lnfotmalion : All Peaks 

Peak It Compoa ent Name Amount (m&IL) Rttenllon Time Peak Arto Peak Htig;bt 

------------------------------------------------------ I 

2 

3 

4 

s 

6 

7 

8 

0.0000 0.80 8185 

l'luoride 2.0081 0.98 201406 

Chloride 3.1331 1.60 210535 

Nibite 1.4848 1.97 19Q088 

Bro;nide 5.9109 3.05 170328 

·N itrate 1.9856 350 3411)57 

Phosphate 5.9598 5.78 353592 

Sulphate 12.01 28 7.72 583476 

/lfSPIK£ 

16.0 

14.0 

12.0· 

10.0 

8.0 

6.0 2 3 4 6 8 

:~ rj~U_jj___)L__)\___ ·2.0.__ __ _ 

0 1.0 2.0 0 ...... M '' 

3.0 - ··.,-s.::-o ----:6:-:: .o,..--"'?."'o----:s::-:.a.--

1369 

37977 . 

39816 

30353 

24663 

40804 

25877 

33899 

liJ : PMNtt.SE S.IOd lo'~lo l 

t\IUC111 Dcue : 200!•09-02 

Curtcnt Ti" : 20'".S7:A9 

VES 006211 
Sample Analysis Report 

Sample Name : B-BLANK 

Data File Name: C:IPEAKNET\DATA\ANION\10-23_AAN020.DXD 

Detector Type: DX-120 

Method File Name: e:lpealmel\methodlmeehod\120aniQns . .met 

Schedule File Name: c:\pealcnetlscl!edulelschedule\schedute\120anionsl20081!20anion0902.sch 

Date Time CoUected·: 2008-09-02 8:58:38 PM 

System Operator : LLE 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibcati~m Type : ExTERNAL 

Component Amount Units : mg!L 

Dilution Facto.r : 1.00 

Peak Information : All Peaks 

Peak# Component Name Amount (rng/L) · Retention Time 

---··· -··· .... 

I fluoride 0.2742 1.02 

2 0.0000 1.13 

3 Chlot'ide 0.3906 1'.62 

4 Nitrite 0.9378 L.97 

5 0.0000 3.28 

6 Sulphate 2.0213 7.77 

B-BLANK 

t6oi 

14.0 I 

12.0 I IO.otl) 8.0 

:1. 6.0 

4.0 

2.0 

-~ •1 ':~ \ 0 

-2.0 - 0 1.0 2.0 3.0 4.0 5.0 ... 

I of I 

6.0 

Peak Area Peak Height 

22911 5522 

51871 9269 

23390 5186 

117368 19051 

7394443 645188 

88524 5299 

6 

~ 

I 

7.0 

.. 8.0 

Current J)w: : 1008-09-Ul 

Cuneot 'Time: 21:01:20 

VES 006212 
Sample Analysis Report 

Sample Name : Jl.Sl'IKE 

Data File m~: C:IPEAKNn\DATA\ANIONU0-23_AAN021.DXD 

Detector Type: DX-120 

Method Fil.e Name : c:'opeaknet\method\method\120anions.met 

Schedule File Name: c:'l!eaJ<net\schedule\scbcdule\<ehedule\120aniol'ls\2008\120anion0902.sclJ 

Date Time Collected: 2008-09-02 9:08:08 PM 

Systt111 Operator : LLE 

Calibration Date : 2008-()9-02 6:54:22 PM 

Calibration Type : BXTERNAL 

Comp<>net>l Amowit Units : mgiL 

Dilution Factor : 2.00 

Peak lnfonnation : Ali Peaks 

Peak# Component Name Amount (mg/L) Retention Time Peak Area Peak :Helgbt 

--- - I 0.0000 0.80 1904 491 

2 Fluoride 0.6023 1.02 25629 1066 

3 0.0000 1.42 22289 2782 

4 Chloride 9.9845 1.62 343581 62652 

5 Nitrite 1.6512 1.98 102581 13471 

6 Bromide -3401.0721 3.15 24280884 1857692 

7 Sulphate 4.6584 7.78 103512 6013 

B-SPTKE . 

16.0r ' 

14.0 I 12.0 

10.0 

8.0 4 

\ "' I :1. 6.0 lJ 4.0 5 ( 7 2.0 I I I 

0 1--· '"'---

·2.0 ~_ _ _ , 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 . .. 

Current OILtc : al08·09-01. 

Pu.e I oft Current Time : ~1 Sl 

YES 006213 
Sample Ana.lysis Report 

Sample Name·: AH3046 

Data File Name: C:\l'EAXNI!;'N>ATA\ANION\10-23_AAM022.0XO 

Detector Type: DX-120 

Melhod File Name : c:\peaknet\method\method\120anions.met 

Schedule File Name: c:\peaknetlscbedulelschedulelschedule\120anions\2008\120anion0902.sch 

Date Time Collected: 2008-09.{)2 !): 17:40 PM 

System Operator : LLE 

Calibration Date : 2008.{)!).{)2·6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 25.00 

Peak lnfoml>tion : All Peaks 

Peak # Component Name Amount (mg/L). Retention Time 

1 0.0000 . 0.80 

2 Fluoride 2.9994 1.00 

3 Chloride 133.7599 1.62 

4 Nitrite 2.4629 1.98 

5 Nitrate 54.8229 3.48 

6 Phosphate 10.6849 5.83 

7 Sulphate 48.2226 7.77 

AH3046 

16.0 

14.0 

12.0 

10.0 3 

I 

t/.1 8.0 :1. 6.0 5 

I 

4.0 

2.0 _A I 2 4 

___ I _!---.J ~ l 

0 

-2.0 -·--- - - o · 1.0 2.0 3.0 4.0 5.0 ... 

• : ~~ct.S£S.1 0c;l • Pa~lqfl 

6 

l 

6.0 

Peak Area PeakHelgbt 

2187 460 

7353 1633 

369849 85362 

7839 1387 

378405 43746 

153 14 1152 

84033 4931 

. 

7 

)--._ 

7.0 8.0 

C1lntnO Date: 101)8:..09-02 

C1lnenl Time : 21:26d7 

VES 006214 
Sample Analysis Report 

Sample Name : AH3046 

Data File Name: C:IPEAKNE'I\DATAIANION110-23_AAQ016.DXD 

Detector Type: DX-120 

Method File Name : c:\peaknet\me1bod\metbod\120anions.met 

Schedule File Name : c:\peaknet\s<:bedule\scbedtile\schedule\120aniOns\2008\120anion0902.sch 

Date Time Collected : 2008-09-02 3:40:48 PM 

System Operator: LLB 

Calibration Date: 2008-09-02 12:27:39 PM 

Calibration Type: EXTERNAL 

Component Amooru Units : mgiL 

Dilutioo Factor: 100.00 

Peak Infonnation : All Peaks 

Peak # Cornponent Name Amount (mg/l;) Retention Tim_e 

.. -.. ·- - ·-· ·-· 

I Fluoride 5.0157 1.03 

2 Chloride 130.7067 1.62 

3 Nitrate 56.6328 3.55 

4 Pbospl1llte 17.2320 5.85 

5 Sulphate 46.0796 7.80 

AH3046 

16.0 

14.0 

12.0 

10.0 

'a 8.0 

6.0 

4.0 2 3 

2.0 I I I 

f--__l__j\_ 0 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 . .. 

P~lofl 

4 

I 

6.0 

Peak Area P~k elght 

4046 396 

84m 17770 

86706 10494 

3004 267 

15715 1058 

5 

I 

7.0 8.0 

Currtnt DMt : 2001.00-02 

CuneaiT'tme : IM9!31 

VES 006215 
Sample Analysis Report 

Sample Name : AH3047 

·Data File Name: C:IPEAKNET\DATA\ANION\10-23_AAM023.DXD 

Detector Type: DX-120 

Melhod File Name: c:lpeaknet\melhod\method\J20aoions.met 

Schedule File Name: c:lpeaknet\schedule\sclledule\schedule\I20anionsl2008\120anion0902.scb 

Date Time Collected : 2008~9-02 9:27:06 PM 

System Operator : LLE 

Calibration Date : 2008-09~2 6:54:22 PM 

Ca.lib<"ation Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution factor: 25.00 

Peak Inforination : AU Peaks 

l'e.alt # Component Name Autouut (mg/L) Retention Time 

I 0.0000 0.80 

2 Fluoride ·4.4583 1.00 

3 Chloride 171.5442 1.60 

4 Nitrite 3.0412 1.97 

5 Nitrate 73.0177 3.47 

6 Phosphate 7.6813 5.83 

7 Sulphate 44.8596 7:17 

AHJQ47 

. 16.0 

14.0 

12.0 3 

10.0 

8.0 5 (/) 

:1. I 6.0 

l_. ~ 4.0 

2.0 I 2 

I I 

0 

·2.0 --· 0 1.0 2.0 3.0 4.0 5.0 

. 

~~ : Pe~k~et·SE S. l(ld 

6 

I 

6.0 

l'eskArea PeakBeigbt 

- 2458 467 

13232 3225 

483162 9%97 

10825 1465 

511346 60377 

8146 597 

17493 4573 

. 

7 

~ 

I 

7.0 8.0 

C\IITMt D:nt: 2008-09·01 

Curre.""'t Time.: 2:1 ::OS:48: 

VES 006216 
., 

Sample AJJalysis Report 

Santplt Name: AH3048 .. _ __ • • _. . . 

Data File Name : C:IPEAKNE'ru>ATA\ANION\10.23 _AAM024.DJCD 

De!ectorType : DX-120, 

Metl10d File Name : c:\peaknet\melbodlmethod\120aoions.met 

Schedule File Name: e:\peaknet\sehcclulelschedulc\schedule\ t20anions\2008\120aoiol10902.sch 

Dote rune Collected: 2008-09-{)2 9:.36:38 PM 

System Operator: LLE 

Ca.libntion Date : 2008-09-02 6:54:22 PM 

Calibnilion Type : llX1'EJ!NAL 

Component Amount Uruts : nw'L lu~on Fa<:tor : 25.00 

Puk illformalion : All Peaks 

PukN Component Name Amo .. nt (mg!L) Retention Time Peak Area PeakHeigbt 

.. -- L 0.0000 0.80 2707 486 

2 Fluoride 20.9801 1.00 80329 15354 

3 0.0000 1.37 6681 835 

4 Chloride 297.8141 1.62 896549 201154 

s Nitrite 2.6801 .2.00 8960 1271 

6 Bromide 5.1347 3.07 3807 580 

7 Nitrate 109.9700 3.45 790604 89782 

8 Phosphate 11.8565 5.83 18112 1378 

9 Sulphate 107.1758 7.75 199185 11556 

AH31J48 

16.0 

14.0 

12.0 

7 

10.0 l 

"' 8.0 

2 ~ :::1. 6.0 

4.0 9 

2.0 8 I 

0 

-2.0 

0 

113 

I J

1.0 

\.J..... LJ~ 

2.0 

I 

3.0 

J 

4.0 

~ 

. -

~l l 

5.0 6.0 7.0 8.0 

CurTinC O.IC t 200S Ii9~ 

Om:n1 Time : 21.45:15 

VES 006217 
Sample Analysis Report 

Sample-Name : AH3049 

Data File Name : C:\.l'li:AK.NE1\DATA\A1'HONI10·23_AAM025.DXD 

Deteeror Type : OX-120 

Method File Name : c:\peaknet\rnethod\methodll20anions.met 

Schedule File Name : c:\pealmet\schedulelschedule\schedule\120anions\2008\120anion0902.sch 

Dale Time Collected: 2008-09-0i 9:46:04 PM · 

System Opecator: LLE 

Calibration Date : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Corrponent Amount Units : rog!L 

Dilution Factor : 1.00 

Peak Infoonation : All Peaks 

Peak# Component Name Amount (mg/L} Retention Time· 

I 0.0000 0.78 

2 Fluoride 0.3372 1.02 

3 0.0000 1'.13 

4 0.0000 1.40 

s Chloride 1.6101 1.63 

6 Nitrite 11.5160 2.00 

7 0.0000 2.25 

s Nitrate 18.6776 332 

9 Phosphate 0.3885 5.85 

tO Sulphate 4.1310 7.75 

Ill : PctkNet·SE 5.l0d - J>AAe 1 6f2 

.Peak An11 

44908 

29279 

52846 

36156 

105352 

1803971 

80487 

5240008 

12991 

220975 

Peak Belglat 

6795 

5687 

8380 

;3857 

24596 

32~122 

11616 

474473 

1028 

12834 

Cement Date: .2008-<19-02 

CWTel'lt TUne : 21:S4:46 

VES 006218 
Sample Analysis Report 

Samplt Namt : AH3049 

Data File Name: C:\PEAKNET\DATAIANION\10-23_AAMOZS.DXD 

AH3049 

16.01 '14.0 . 

12.01 

10.0 

Cll 8.0 I 

:1. 6.0 ( 4.0 \ 7 

2.

0 

0 

~ ·2.0 

0 1.0 2.0 3.0 . 4.0 5.0 

P;~ee 2of2 

9 

I 

6.0 

10 

I 

._._A._ 

7.0 -··- - - 8.0 

Oli'Tefll Oat~: 200s.o9-0'2 

CurretVTime: l•:S4i46 

VES 006219 
Sample Analysis Report 

Sample Name _: AH3049 

Data File Name: C:\PEA.Kl'I£T\DATA\ANION\10-23_AAP017.DXD 

Detector Type : DX-120 

Metllod File Name: c:\peakoetlmethod\method\120anions.met 

Schehde File Name : e:\peaknet\schedule\schedule\schedulc\120anions\2008\120anion0902.sch 

Date Time Collected: 2008~9 02 3:50:20 PM 

System Opecator : LLE 

Calitrarion Date: 2008-09-02 12:27:39 PM 

Calihnlrion Type : EXTERNAL 

~onent Amount Units : mg/L 

Diluli<>ll Factor : 10.00 

Peak Infonnation : All Peaks 

Peak# Component Name Amount (mg!L) Retentloll Time Peak Area 

I 0.0000 0.80 6867 

2 Chloride 1.5258 1.63 9297 

3 Nitrite 10.4305 1.98 136332 

4 Nitrate 24.1444 3.50 396850 

l Sulphate 4.5370 7.80 15397 

AH3049 

16.0 

14.0 

12.0 

10.0 

fl) 8.0 :L 6.0 4 

I 

4.0 3 n I j 2.0 I U\ 5 

I I 

-~ t 0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 . .. 

r~e 1of t 

Peak Height 

1322 

2174 

24513 

46560 

1012 

c..,-e,,, oa~~ : WQ3.Q9..()2 

CU:m::nt Time : 15:..59:00 

VES 006220 
Sample Analysis Report 

Sample Name.: AB3050 

Data F~e Name : C:IPEAKNE1\DATA\ANJON\10-23_AAR026.DXD 

Dete<torType: DX-120 

Metmd File Name: c:lpealcnet\melbod\method\120anions.met 

Sclledule File Name : c:lpealcnet\scbedu1elscbedule\scbedule\ 120anions\2008\120anion09Q2.scll 

Date 'rime Collected : 2008-09-02 9:55:34 PM 

System Operntor : LLE 

Calilration Date : 2008-09-02 6:54:22 PM 

Calilration Type : EXTERNAL 

Component Amount Units : mg!L 

Dilullon Factor : 1.00 

Peak Information : All Peaks 

Peak II Component Name Amount (mg/L) Retention Time 

l 0.0000 0.78 

2 Fluoride 0.2346 1.03 

3 0.0000 1.13 

4 0.0000 1.38 

5 Chloride 0.5154 1.63 

6 Nitrite 10.88()4 2.00 

1 Nitrate 18.5042 3.33 

g Phosphate 0.2268 5.85 

9 Sulphate 33210 7.77 

AH305() 

16.0 I 14.0 

12.0 

10.0 I '1 

8.0 

, ~ . , I 6.01 4.0 

2.0 

Of ·- __ l.)J-J.Jj \.,_ ~ 

Puk Area 

17826 

18906 

78966 

21784 

31692 

1678423 

5107340 

3347 

151893 

9 8 I I 

ei~t 

2960 

4553 

12543 

2708 

6568 

291208 

476336 

292 

8851 

-2.0y 

0 1.0 2.0 3.0 4.0 5.0 --s.oP~ec l of I 

Cttmnt Dste : lOOS·09.Q2 

Cwrem Tune : 22:04:12 

VES 006221 
Sample Analysis Report 

Sample Name: AHJOSI 

ata Fil Nam : C:IPEAKNE'f\DATA\ANJON\10-13_AA0027.DXD 

DetectOr Type : DX-120 

Method file Name: c:\peaknet\rnethod\metbod\120anions.met 

Schedule File Name : c:lpeaknetlschedule\schedule\<cbedule\120ani01\s\2008\120anion0902.scb 

Date Time Collected : 2008-09-02 10:05:01 PM 

System Operator : LLB 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibration Type: EXTERNAL . 

Component Amount Units : mg/L 

Dilution Factor: 1.00 

Peak# Component Name 

·Peak Information : AU Peaks 

Amount (mgfL) Retention Time Peak Area Peak Height 

-·-· ····----- ------------- -------.. - - 1 

2 Fluoride 

3 

4 

5 Chloride 

6 Nitrite 

7 

8 Nitrate 

9 Sulphate 

16.0 

14.0 

12.0 

10.0 

'i 8.0 

6.0 

4.0 3 2.oc1 21 4 5 

0 f

, •.J 

-2.0 

0 1.0 2.0 

~~~ : P~et·SE S.IOd 

7 

! 

0.0000 

0.3909 

0.0000 

0.0000 

0.6176 

12.9.827 

0.0000 

17.7602 

3.8039 

AH3Q51 

J \ 

'--

-3:0-- 4.0 5.0 

0.78 

1.02 

Ll3 

1.38 

1.63 

2.00 

2.25 

3.33 

7.71 

24415 

34706 

126489 

26901 

38500 

2114353 

151176 

4634564 

175513 

9 

t 

3982 

7255 

19419 

3077 

7442 

372244 

16566 

436918 

10323 

__ ___/'-..,_ 

6.0 7.0 8.0 

C~n~ Otte: 2QOS.()!.l.02 

C\l~nl Time : 22:13;4) 

VES006222 
Sample Analysis Report 

Samplo Namt: AB3052 

D•t• F'lle Name: C:\PEAKN.E'J:\DATA\ANION\ I 0-2J_AA0028.DXD 

Detector Type: DX-120 

Method File Name: e:\peaknet'method\method\120unioos.met 

Schedule File Name : c:\peaknet\.schedulc\sehedulc\scbedule\120anions\2008\120anion0902.&ch 

Dou:Time CoUected: 2008-09.()2 10:14:31 PM 

System Operator : LLE 

Ca1ibralion Date : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Ol~l Amount Units : mg/L 

Dilulion Focloc: I 0.00 

PeU lnfonnation : All Peaks 

PHI<# Compoa emName Amo•nt (mg/L) Retention Time 

- •. .. .. . I 0.0000 0.78 

2 Fluoride 2.0546 1.00 

3 Chloride 32.1010 1.60 

4 Nitrite 1.3809 1.98 

5 Nitrate 87.1.342 3.42 

6 Sulpbgte 120.5047 7.72 

A.ll30S2 

16.0 I 14.0 

12.0 

10.0 

'a 8.0 . 6.0· 3 

4.0 

2.0 12 LJ ·2.~ 1 I I I "-- \ 

- 0 1.0 2.0 3.0 4.0 5.0 

-

II : PclllNct.SIB.IOd Pttc luf l 

6.0 

J!eak Aru Peak Height 

4255 812 

15968 3878 

215939 42598 

12950 2135 

1694873 184243 

585377 34118 

6 

_f\_ 

7.0 8.0 

C1111nt Ott'C.: 2.008 09~ 

OJrtt:rU Time- : 22:23:14 

VES 006223 
' 

Sample Analysis Report 

Sample Name : AH305l 

l)atA File Name: C:\PEAl{NET\DATA\ANION\10-23_AAN018.DXD 

Detector Type : DX-120 

Meibod File Name : c:lpealmet\metbod\roethod\120anions.met 

Seh<du.te File Name: c:\pealmetlscbedule\sch<dule\scbedule\120anions\2008\120anion0902.scll 

Date Time CoUected : 2008-09-02 3:59:50 PM 

System Operator: LLE 

Calibration Date : 2008-09-02 12:27:39 PM 

Calibration Type: EXtERNAL 

Component Amount Units : mgiL 

Dilution Factor: 5.00 

Peak loformation : All Peaks 

Peak# Component Name AmoUllt (mg/L) Retention Time Peak Area PeakHelgbt 

-

1 0.0000 0.78 10970 1785 

2 Fluoride 3.5292 J:OO 68424 9080 

3 0.0000 1.35 7133 1057 

4 Chloride 35.2156 1.62 508697 113417 

5 Nitrite 1.2671 1.98 28963 4537 

6 Nitrate 58.4445 335 4073577 392033 

7 Sulphate 134.1116 7.70 1330476 77739 

AR30S2 

16.0 

14.0 4 

12.0 

. 10.0 7 

8.0 

\ 

I 

'a 

6.0, _}\_ 4.0 

2.0• I 2 3 s 

0 d I I ~ -2.0 

-··" 0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 ... 

C~nent O..le : 100~2 . 

Pne· I ofl Corn:m Tit~~e : t6:oa:27 

VES 006224 
Sample Analysis Report 

Sample Name : AH3052D 

Data FUt Name: C:\PEAKNETIDATAIANIONU0-23_AAN029.DXD 

Detector Type: DX-120 

Method File Name: c:\peaknet\methodlmcdlod\120anioos.mct 

Schedule File Name: c:\peaknet\schedule\.<Chedule\schedule\120anions\2008\120anion0902.scll 

Date TUne Collected : 2008-09-{)2 I 0:24:03 PM 

SY.stcm Operntor : LLE 

Calibration Date : 2008-09-{)2 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 10.00 

Peak Information : All Peaks 

Peak # Component Name Amount (mg/L} Retention Time 

l 0.0000 0.80 

2 FIUO(ide 4.3298 1.00 

3 0.0000 1.37 

4 Chloride 27.5926 1.62 

5 Nitrite 1.6432 1.98 

6 Nitrnte 84.5652 3.42 

7 Sulphate 119.9763 7.72 

AH3052D 

16.0 

14.0 

12.0 

10.0 

rn 8.0 

"" 6.0 4 

4.0 

2.0 

0 

I 

I 

2 

I LJL -2.0L._ 

0 J.O 2.0 3.0 4.0 5.0 ... 

PtRe I of1 

6.0 

Peak Area Peak Height 

- 6344 1052 

38973 4978 

5333 665 

184413 41051 

16339 2668 

1636469 175734 

582710 33831 

7 

I 

_j\__ 

7.0 8.0 

Ctinent lhte: : 200l,.()9.oz 

CUtrent Tune : 21:31;40 

VES 006225 
Sample Analysis Report 

. 'sample Name : A1130S3 

Data File Name : C:IPEAKN'E':N>ATA\i~NlON\10-23_AAN039.DXD 

Detector Type : DX-120 

Method File Name: c:lpeaknet\metbodlmethod\120anions.met 

Schedule File Name : c:lpeaknetlschedulelscbedulelschedulel 12Qo&nions\2008\120anion0902.sch 

Dare iirne Collected: 2008-09-02 10:33:29 PM 

System Operator : LLE 

Calibration Date : 2008·09-02 6:54:22 PM 

Calib.ration Type: EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 10.00 

Peak lnfonnation : All Peaks 

.Peak# Component Name Amount (mg/L) Retenlloa Time 

··-·--- . 1 0.0000 0.78 

2 Fluoride 2.4828 1.00 

3 0.0000 1.35 

4 Chloride 34.6631 1.60 

5 Nitrire 1.6380 1.98 

6 Nitrate 124.4844 3.38 

1 Sulphate 141.4927 7.70 

AH30S3 

16.0 

' \ 

14.0 

12.0 

10.0 . I 

8.0 (I) 

4 

\ 

:1. 6.0 

4.0 

2.0 ~5 I 

0 - - ~ 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 ... 

PaJC 1 on 

Peak Area Peak Height 

·--- - --··--------··--

6.0 

5076 1014 

20289 4850 

4103 805 

233989 45820 

16273 2799 

2638790 272150 

691734 40244 

-

7 

I 

/\ _./ '--

7.0 8.0 

Cun'tnt ()a.Je ; 1008.()9.()~ 

Cwrrent 1'imt:: 22:42: II 

VES 006226 
Sample Analysis Report 

Sample Name : Al130s4 

Data File Name-: C:\PEAKNE'l\DATA\ANION\10.23_AAN03 l.DXD 

Detector Type : DX-120 

Method File Name : c:lpeaknet~odlmethodl120anions.met 

Schedule File N"Jlle.: c:lpeaknetlscbedule\sebedulelschedolcll20ani<ms\2008\120anion0902.scb 

Daw Time Collected: 2008·09.02 10:43:00 PM 

System Operator : LLE 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibrntioo Type : EXTBRi"'AL 

Component Amount Units : mg/L 

Dilution Factor: 10.00 

Peak Information : All Peaks 

Peak# Component Name Amount (mg/L) 

-·------·---------- I 

2 Fluoride 

3 Cbloride 

4 Nitrite 

5 Nitrate 

6 Sulphate 

12.0 

10.0 

0.0000 

2.2132 

36.8316 

1.5643 

86.0967 

126.6170 

Retention TilDe 

0.80 

1.00 

1.62 

1.98 

3.42 

7.72 

AH3054 

Peak Area 

4388 

17568 

249341 

15319 

1671205 

616262 

:~: ,.\ 

8.0 3 \ 6 

!:~ 2 ~ . j\1 

2.0, :1 ll_11 ' ' 

0-; ~----~1 ------------~- '- 2.0 i___,;----;;:·-;c-·- -:-;;:----:-::---~-=- --,:---~-;:-- 0 1.0 2.0 3.0 4.0 . 5.0 6.0 7.0 8.0 

Peak l:lelgllt 

852 

4262 

57161 

2531 

180311 

35913 

~~ : PnkNec-SE .S.Hid' Pa~re I or I 

Cl.lrrMI [hit(: : 1008-09-02 

~~Time : 2.2:Si:37 

VES 006227 
Sample Analysis Report 

Sample Name : A£1.3055 

Data FU~ ame: C:IPEAKNET\DATAIANION\l0-23_AAM032.DXD 

Detector Type: DX-120 

Method File Name: c:\peaknet\method\l:nethod\120anions.met 

Schedule File Name : c:\peaknet\schedule\sebcdule\schedule\l20anions\2008\120anion0902.sch 

Date Time Collected : 2008-09-02 10:52:25 PM 

System Operator : LLE 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibnu~ Type : EXTERNAL 

Component Amount ni~ : mg!L 

Dilution Factor : 1.00 

Peak lnfonnation : A.ll Peaks 

Pcilk # Component Name Amount (mg/L) Retention Time 

------- I 0.0000 0.80 

2 Fluoride 0.4756 1.02 

3 0.0000 1.15 

4 0.0000 1.38 

5 Chloride 2.2725 1.62 

-6 Nitrite 1.1624 1.98 

7 Nitrate 19.5531 3.30 

'8 Phosphate 0.2080 5.87 

9 Sulphate 12.3411 7.72 

AH3055 

16.0 

\ 

14.0 

12.0 

10.0 

en 8.0 :1. 6.0 

5 6 4.0 

2.0 I z3 11 4 . u. 

o · -.. 0t\..'J \. 

-2.0 

,-- -- - 0 1.0 2.0 3.0 4.0 5.0 ... 

fl : PeUNcc·SE SJOd 

Pl\llk A.rea Peak Heil;bt 

5086 892 

43292 83"/8 

79875 12715 

10933 1480 

150705 30457 

147097 24125 

6516306 564837 

2227 202 

600053 34885 

9 ' 

I 

~-·-_}\_ 6.0 7.0 8.0 

Currertt DINe : 2003-1)1).02 

Cun:ent Time: 23:01:02 

VES 006228 
Sample Analysis Report 

Sample Name: AHJOSS 

Data File Name : C:ll'EAKNET\l)ATA\ANION\16--23_AAN019.DXD 

DeteetorType: OX-120 

Method File Name: c:\peal<nel\methodlmetbod\120anions.met 

Sebedule FileName: c:lpeaknet\scbedule\schedulelscbedule\120anionsi2008\120anionQ902.sch 

Th!tc Time Collected: 200&-09~2 4:09:16 PM 

Syslem Operator : LLE 

Calibration Date : 2008..o9-02 ·12:27:39 PM 

Cahbration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 5.00 

Peak Information : AU Peaks 

Ptak. # Component Name. Amount (mg/L) Retention Time 

. 

1 0.0000 0.80 

2 Fluoride 0.4400 1.02 

3 0.0000 1.15 

4 Chloride 2.3979 1.62 

5 Nitrite 1.0889 1.98 

6 Nitrate 29.0821 3.45 

7 Phosphate 0.7968 5.87 

8 Sulphate 12.6163 7,78 

A.H3055 

16:0 

14.0 6 

12.0 I 

~ 10.0 

., 8.0 

:i. 6.0 

4.0 

2.0 1 23 4 5 

. ··· --j L __ ._ 

I ll ~ I 

0 

-2.0 

0 1.0 20 3.0 4.0 5.0 ... 

II ' Puklle..SES.IOd Pt~tt I of I 

7 

I 

-·· . 6.0 

Peak Area PeakHelgbt 

9083 1586 

7718 1552 

11057 2281 

30256 6047 

24231 4203 

1061467 120070 

2i66 212 

108906 6484 

8 

I 

7.0 8.0 

C\><Teot o.<e , 200S-&.>.02 

C\ln'ellll Time : 16;17;$3 

VES006229 
· Sample Analysis Report 

Sample Name: CCB 

Dan File Name: C:\PEAKNE'l'\DATA\ANION\10-23_AAL033.DXD 

Detector Type : DX-120 

Method File Name : c:lpeaknet\metbod\rnelhod\120anions.mct 

Schedule File Name : c:\pealcnet\schedule\scbedule\scbedule\l20anions\2008\120airloo0902.sch 

Date Time Collected : 2008-09.02 11:01:51 PM · 

System {)petator : LLE 

calibration Date : 2008·09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 1.00 

Peak Information : All Peak.-

Peak# Component Name Amount (mg/L) Retentloll Time 

l, 

2 

V) 

::1. 

'"I 14.0 

12.0 

10.0 

8.0 

6.0 

4.0 

2.0 

or-

-2.0t_ __ 

0 1.0 2.0 

0.0000 

0.0000 

2 

I 

3.0 

CCB 

4.0 

l';•,ee t of I 

5.0 

1.35 

3.58 

6.0 

Peak Area 

3523 

6661 

-·- - ·-·- .. · 

Peak Ileight 

541 

591 

7.0 -s:oCurrent Oa.le ; 2008-o9.o2 

ClmcDl Time: l);J0:)3 

VES 006230 
I 

Sample Analysis Report 

Somple Nome : CCV 

Data File Name: C:\PEA.KNET\DA IA\AN10N\10-l3_AAL034.DXD 

Detector Type : DX-120 

Method File Name: c:lpeaknetlmelhod\melhod\120nniom.met 

Schedule File Name : c:lpeakne!\schedule\sohedulelschodule\12Qanions\20081120nnion0902.sch 

Dnte Time Collected : 2008-09-02 II: I I :22 PM 

System Operator : LLE 

Calibration Dare : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

CoJ11>ooent Amount Units : mgfL 

Dilurian Factor : 1.00 

Peak Information : All Peaks 

P~•k # Component Nome Amount (m&fL) Retentlou Time 

I 0.0000 0.80 

2 Fluoride 1.8968 0.98 

3 Chloride 3.0506 1.60 

4 Nitrite LSOOS 1.97 

s Bromide 6.0870 3.05 

6 Nitrate 2.0273 3.50 

1 Phosphate 6.0685 ·5.77 

g Sulphate 12.1 910 7.70 

CCY 

16.0r 

' 14 ~ 

12.0i ' 

10.0 ~ 

., 8.0t ::L 6.0·f 2 3 6 

:1~ 4 5 I 7 I I I 

PeakAr~ 

? ISS 

189738 

204751 

192193 

173753 

348538 

360403 

592470 

8 

I 

1319 

38765 

39109 

30474 

24740 

41337 

26041 

34146 

0 LO 2.0 3.0 4.0 s.o 6.0 7.0 8.0 

l!J ; P.nkM:t..se S,,Od Pt~te s of I 

C.m:ru DIMe : 1008--09-0.l 

O.nutTimc : 23:19:$9 

. ·-· ----·- -----------

VES 006231 
Sample Analysis Report 

Sample Na.me : AH3056 

Data File Name: C:\PEAKNETIDATA\A~10Nil0-2J AA 03S.DXD 

Detector Type : DX-120 

Method File Name : c:\peaknetlmethod\metbod\120anions.met 

Schedule File Name: c:lpeaknetlschedulc\scbedule\scbedule\120anions\2008\120anion0902.sch 

Date Time Collected : 2008-09-02 II :20:47 PM 

System Operator : LLE 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Compooent Amount Units : mg!L 

Dilution Factor : 1.00 

Peak Information : All Peaks 

Peak# Component Name Amount (mg/1,) Retention Time 

·-

I 0.0000 Q.80 

2 Fluoride 0.4172 1.02 

3 0.0000 1.1.5 

4 Chloride 2.0899 1.62 

5 Nitrite 1.2067 !.98 

6 0.0000 3.28 

7 Sulphate I 1.3200 7.73 

AH3056 

16.01 

14.0 

12.0 

10.0 

(/) 8.0 • ::1. 

6.0 

\ 4 5 4.0 23 I I 

2.0 

() ___ Jj~Ju\ ' ~ ·2.0 - 0 1.0 2.0 3.0 4.0 5.0 . -

Iii : Pc.kNec-SE S.10d ~ee 1o l 

·- 6.0 

. 

Peak Area Peakll~ght 

.. 

3563 7os 

37375 .7493 

53409 9694 

138140 28549 

152982 25625 

8253438 697145 

548562 32014 

7 

I A _ 

7.0 8.0 

C\lrrtnt 011tt : 200$-09-0Z 

Currerd Time. : 23:29:24 

VES 006232 
Sample Analysis Report 

S•mple Name : AH3058 

Data File Name : C:\PEAKNE1\DATA \ANIONU 0-23_AAL036.DXD 

Oete:.torType: DX-120 

Metbod File Name: c:\peaknet\inethod\melbod\J20anions.met 

Schedule File Name : c:\peakJJet\schedule\scbedule\scheduleU20anioos\2008\120anion0902.scll 

Date Time Collected : 2008..09.()2 I I :30: 13 PM 

System Operator : LLE 

Ca1ilration Date: 2008-09-02 6:54:22 PM 

Calilration Type : EXTERNAL 

Co~onent Amount Units : mg/L 

Dilution Factor : 1.00 

peak Informa\ioo : All Peaks 

Peak # Component Name Amount (mg!L) Retention Time 

I 0.0000 0.80 

2 Fluoride 0.7671 1.02 

J 0.0000 LIS 

l o.oooo 1.38 

j Chloride 4.3628 1.62 

6 Nitrite 1.1397 1.98 

1 Nitrate 19.43'29 3.32 

& Phosphate 0.2930 5.85 

9 Sulphate. 25.8852 7.68 

I 

A.H3058 

16.0 

14.0 

12.0 

1.0.0 

8.0 . s 

\ 

'i 6.0 

4.0 "J 2.0 I !I 4 ~ 

0 I I U \,__ ,_, .. \ 

'------- -2.0 :--· . ... .... 0 1.0 2.0 3.0 4.0 5.0 - .. 

8 

I 

6] __ _ 

Peak Area . Peak Relg,bt 

5156 879 

72964 14182 

91479 14447 

12348 1669 

297926 57569 

t440n 23006 

6115611 542592 

7293 548 

1303121 76051 

9 

I 

Jl 

·7-:-o-·-s.oOJrrer,t Da1e: 4:000:·09-0l 

CU!Tent Titne : 23:l8!SO 

VES 006233 
Sample Analysis Report 

Saniple Name: AH93Z5 

Dab File Name : C:\PEAKII'E1\DATA\ANTON\11)..23_AAL037.DXD 

Detector Type: DX-120 

Method File Name : c:lpeaknetlmetbodlmcthod\120aoio,.•.mct 

Schedule File Name : c:lpeaknet\scbedulelschedulclsohedule\120anions12008\120anion0902.sch 

Date Time Collected: 2008-09-02 II :39:38 PM 

Syslem Operator : LLE 

Ollibrnlion Date : 2008-09-02 6:54:22 PM 

Cahbrotion Type: EXTERNAL 

Component Amount Units : mg/L 

Dil1lion Fac:tor : 10.00 

Peale Information cAll Peaks 

Pt1k N Component Name Amount (mg/L) Reteation T=e 

- . 1 0.0000 0.80 

2 Fluoride 1.3341 1.03 

3 0.0000 1.15 

4 Chloride 54.4485 1.62 

5 Nitrite 3.4982 1.98 

6 Bromide 141.9363 3.05 

7 Nilnlte 20.8588 3.50 

8 Sulphate 8.0387 7.77 

9 0.0000 8.30 

AH9J1J 

16.0 

14.0 

12.0 

10.0 4 

I 

8.0 6 

'Q 6.0 

_AA_ 4.0 

!23 5 2.0 . 

o~ 

I I I u_ 

-2.0 

0 1.0 2.0 3:o 4.0 5.0 ... 

a~ I O(l 

. 6.0 

. 

PtakArea Pealc Height 

12223 2064 

8706 2146 

13836 2897 

376812 84493 

40382 . n04 

420927 60916 

359090 41147 

29434 1871 

2639 253 

. 

8 9 

I 

·7-:o-- &:o 

C\wrent Oate = 1'003 0~ 

Currcntltmo : ll:ti;IS 

VES 006234 
Sample Analysis Report 

Satnple Name : AH932S 

Data_Flle Name: C:IPEAKNE'I\DATAIANION\10-23_AAU014.DXl> 

Octee10rType: DX-120 

Method File Name : c:lpcaknetlmethodlmetbod\120anions.met 

Schedule File Name: c:\peaknetlschedulelschedule\schedulell20anions\20081120anion0902.scb 

Date Time Collected: 2008-09-02 3:21:51 PM 

System Operator : LLE 

Calibration Date: 2008-09·02 12:27:39 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 10.00 

Peak Information : All P03ks 

Pe•k # Con1ponent Name . Amo1111t (mg/L) Retention Time 

I 

2 Fluoride 

3 

4 Chloride 

5 Nitrite 

6 Bromide 

7 Nitrate 

8 Sulphate 

:::~! 

4 

I 

0.0000 

1.0009 

0.0000 

51.9005 

3.3447 

134.7260 

2l.l775 

7.0815 

6 

AH9315 

0.78 

1.03 

1.15 

1.62 

1.98 

3.07 

3.53 

7.78 

PellkArea 

12869 

8892 

13302 

360149 

39764 

407203 

345127 

26822 

12.0f 

10.0 

8.0 

6.0 

4.0 

2.0 

0 

~ i 

f '-.~J'.f _ _ _/.

1

\1\ __________ .--'---

Peak Heigbt 

2070 . 

2170 

2640 

79875 

6690 

56715 

39793 

1774 

2.0 !---.-::--;:-.,--~-.----:--:- -:-:----:-~ -=---,::-::-- o LO 2.0 3.0 4.0 S.O 6.0 7.0 8.0 

~~ ; PeakNa.SlH.IOd Pt~ I ofl 

Cwellt Ihttc : 2003-09.()2 

Cl.ll'l'eot iitne: IS:30:J) 

VES 006235 
Sample Analysis Report · 

Sample Nanie : AH937.6 

Data File Name: C:IPEAKNE1\DATA\ANJON\l0-23_AAL038.DXD 

Detector Type: DX-120 

Method File Name : c:\peaknetlmethodlmethod\120anioos.met 

Schedule File Name : c:lpeaknetlscbedule\schedule\schedule\J 20anions\2008\ 120anion0902.scl• 

Date Time Collected: 2008-09-0211:49:03 PM 

System Operator : LLE 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibration Type : llXTERNAL 

Component Amount Units : mg/L 

Dilution Factor : 10.00 

Peak Information :All Peaks 

P .. k # COttlpottentNa.me Amount (mg/L) Retention Time Peak Area Peak Helgbl 

---------·------------- - ....,.------ ·-- 0.0000 0 .. 80 

2 Fluoride 1.3643 1.03 

3 0.0000 1.15 

4 0.0000 1.37 

s Chloride 5?.8582 1.62 

6 Nitrite 2.3253 1.98 

7 Bromide 138.6178 3.05 

g Ni!r3te 14.7040 3.52 

9 Sulphate 8.1433 7.78 

10 0.0000 8.30 

Pate I of2 

12912 

. 9010 

i5141 

7949 

365096 

25166 

410482 

249157 

29941 

2587 

2084 

2078 

2737 

1063 

80827 

4368 

59095 

29285 

1901 

249 

COTTenl Olltt : 2()08..o9.02 

Currtnt Ti:mt : 23:$1:4() 

VES 0062.36 
· Sample Analysis Report 

SamJ>Ie Name : AH9326 

Data File Name: C:\PEAKNET\DATAIANION\10·23_AAL038.DXD 

16.or 

14.0t 

12.0j 

IO.O:f 5 

8.01 !' 7 6.0' · I 

4.0; \ I 

11H9326 

. _j 8 

0~ ~i J 6 \J\ 2-~ c~ ~ ------ 0 1.0 2.0 3.0 4.0 5.0 6.0 

m 

Ia : PtakNet.SE S.JOd 

7.0 

9 10 

I I 

8.o· 

0.111'ftt4 [)~ : 2008-09-02 

Cment Time : 2J!S?!40 

VES 006237 
Sample Analysis Repo.rt 

Sample Name : AH9327 

Datal'Ue Name: C:ll'EAKNETIDATAIANlON\10-23_AAL039.DXD 

Detc:tor!ype: DX·I20 

Method File Name : c:\peaknet\metbodlmethod\ 120anions.met 

Schedule File Name : c:lpealo:let\schedulelscbadule\scbedule\120anions\2008\120anion0902.scb 

Date Time Collected : 2008-09·02 11:58:30 PM 

System Operator : LLE 

Calibration Date: 2008-09-02.6:54:22 PM 

Calibration Type : EXTERNAL 

Cc~Tponeot Amount Units : rngiL 

Dilution Faetor: 10.00 

Peak Information : AH Peaks 

Peak # Component Nam<> Amouot {mg/L) Retention Time 

I 0.0000 0.78 

2 Fluoride 1.4534 1.03 

3 0.0000 1.15 

4 0.0000 1.35 

5 Chloride 51.7965 1.62 

6 Nitrite 4.3108 1.98 

7 Bromide 135.0473 3.03 

8 Nitrate 23.9498 3.48 

9 Sulj>hate 9.1251 7.77 

10 0.0000 8.30 

Peak Area 

13016 

9908 

18397 

9949 

357299 

50949 

399277 

415031 

34697 

2705 

Peak Height 

-------1935 

2275 

3192 

1343 

83105 

8056 

55888 

47300 

2162 

253 

OlrTenl Oa~ : 2003-09·03 

Ct.~tnni imc ;00:07:12 

VES 006238 
Sample Analysis Report 

Sample Name : AH9327 

Data File Name : C:\PEAKNEl\DATA\ANION\10-:U _AAL039.DXD 

AH9327 

16.0 

14.0 

12.0 

10.0 s 

I 

Cll 8.0 uh ' . :1. 6.0 fi j 

4.0 

2.0 . 123 I I I _j~ . 0 -· --~ 

-2.0 

0 ~-1.0 2.0 3.0 . 4.0 s.o 6.0 7.0 

9 10 

I I - 8.0 

O..rrent ~¢ : l008-0!NJ3 

Co!Telll Tiro~ : 00:07:12 

VES 006239 
Sample Analysis Report 

Sample Name: AH9328 

Data FileName: C:\PEAKNET\DATA\ANION\10-:Z3_AAR01S.DXD 

Detector Type: DX-120 

Method File Name: c:lpeaknetlmethodlmethod\120anions.met 

Schedule File Name : c:\peaknetlschedule\schedule\-.chedule\l20aruons\2008\l20anioo0902.sch 

Date Time Collected: 2008-09..02 3:31:22 PM · · 

Sy!;tem Operator: LLE 

Calibration Date: 2008·09-02 12:27:39 PM 

Calibration Type : EXTERNAL 

Component Amount Unit< : mg/L 

Dilution Fact(!r: 10.00 

Peak Womtation : AU Peaks 

P .. l< # Component Narne Amount (me/L) Retention Time 

M OM . .. 

I 0.0000 0.78 

2 Fluoride 2.0459 1.00 

3 0.0000 1.35 

4 Chloride 150.2626 1.63 

5 Nitrite 2.5327 . 2.00 

6 Bromide 2.4468 3.08 

7 Nitrate 118.1004 3.38 

8 Sulphate 4.3326 7.80 

AH9328 

l6.0f I I 14.0 

12.0 :....-

"'I .• 

Vl 8.0 

::1. 6.0 

4.01 

2.0 l 2 3 5 6 

1 l l I I \ 0 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 ... 

IIJ :Peal:Ntt·SE S.IOd a~ J,of l 

6.0 

Peak Area Peak HelgJtt 

6909 1241 

19064 3049 

7412 1099 

1473170 328008 

28945 4329 

5599 925 

3710693 358551 

14480 966 

8 

I 

7.0 8.0 

CunetU OMc : '2008-09·02 

Cutreot Tirne : I.S:)?:S9 

VES 006240 
Sample Analysis Report 

Sample Name : AH9328 

Data File Name: C:IPEAKNET\DATA\AN10Nit0-23_AAL040.DXll 

DetectOTType: DX-120 

Method File Name: c:lpealcnet\metbod\melbod\J20anions.met 

Schedule File Name : c:'q>ealmet\schedulelscbedule\scbedule\120anioosl20081120anion0902.sch 

Da.teTime Collected: 2008-09-03 12:08:00 AM · · System Operator : LLB 

Calibration Date : 2008-09-02 6:54:22 PM 

Calil...-ation Type : EXTERNAL 

Co~onent Amount Units : mg!L 

Dilution Factor : 50.00 

Peak Information : All Peaks 

Pe~k # Component Name Amount {mg/L) Retention Time PukArea Peak Helgbt 

_____________ .:.._ _____________________ _ 

l Fluoride 

2 Chloride 

} Nitrite 

4 Nitrate 

16.0I 

14.0 

12.0 

10.0 

4.1589 

173.4513 

3.6028 

165.5579 

4 

8.0 2 I 

AH9328 

1.02 

1.62 

2.00 

3.48 

6.0 I f\ 

t-"--'--JU ~------·-

3649 

234180 

4424 

583866 

594 

52088 

660 

67815 

2.0~ --.--~----~-=-----:-c=- 0 1.0 2.0 3.0 4.0 5.0 6.0 ---:7.0 -- 8.0 -

Iii : PeakNet·SE S.IOd ha<: l o( l 

Cum:11t Otte: 2(1Q8.(;9.()3 

Cllmn.t TllfPe ~ 00:14-.37 

VES 000241 
Sample Analysis Report 

Sample Name: AH9329 

Da111Flle Name : C:\PEAJ<NEl\DATAIAN10N\10-l3_AAL041.DXD 

Detettor Type : DX-120 

Method File Name: c:lpeaknet\methodlmethod\120anions.met 

Schedule File Name : c:lpeaknet\schedule\scbedule\scbedule\ 120anions\2008\ 120anion0902.scb . 

Date TIDle Collected : 2008-09..03 12:17:26 AM 

System Operator : LLE 

Calibration Date : 2008..()9..02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor: 50.00 

Peak'Infonnalion : AU Peaks 

Peak # Component Name Amount (tng/L) lletealion Time 

... _. ____ 

I 0.0000 1.15 

2 0.0000 1.37 

J Chloride 204.661 I 1.62 

4 Nitrnte 139.7288 3.50 

5 Sulphate 12.1669 7.78 

AH9329 

f6.0f 

14.0 

12.0l 

10.0 

.., 8.0 ~ 3 4 

j =!. 6.0t I 

4.0 ~ 

2.0t )L_,_ ' 0 

·2.0 

0 1.0 2.0 3.0 4.0 5.0 ... 

E :PnkNet.SES.tOd P-...e I of l 

6.0 

. 

Peak Area Peak Height 

·- --· 

9979 1323 

5659 899 

278571 60035 

488101 57630 

2312 182 

5 

I 

·· ···- - 7.0 8.0 

Cn:m11 o.te : 2008 .Q9-0) 

C\ln'«!t Time : 00:26;(t) 

VES 006242 
Sample Analysis Report 

Sampl e Name: AH9330 

Data File Name: C:\PEAKNETIDATAIAN10N\10-23_AAL042.DXD 

Dete<tOr Type : DX-120 

Metl»d File Name: c:~knet\methodlmethod\120anions.met 

Schedule File Name : c:lpealrnet\scbedule\schedulelschedule\ 120anionsl2008\l20anion0902.scb 

Date Time Collecied : 2008-Q9-03 12:26:51 AM · · 

Syst'l'll Operator : LLB 

Calibration Date : 2008-09..02 6:$4:22 PM 

Calibration Type: EXTERNAL 

ComponC<lt Amount Units : mg!L 

Dilution Factor : 50.00 

Peak Information : All Peaks 

Peak# Component Name 

I Fluoride 

2 

J Chloride 

4 Nitrite 

S Nitrate 

6 Sulphate 

16.o1 14.0 1 

12.01 

Amount (mg/L) 

3.3104 

0.0000 

219.9493 

3.7680 

170.5476 

12.4262 

JO.ot 5 

8~ f I 

Retention Tiine 

AH9330 

1.02 

1.35 

1.62 

2.00 

3.48 

7.78 

Peak Area 

1942 

4765 

300536 

4851 

602$40 

2562 

Pe.ok Heigbl 

476 

683 

67487 

720 

69480 

191 

:~0 _:1.0 _~-~-'\-- ...,. 21 .0 ===::3.0 :_J\_,_--: 4.0 ~-·-5,_.0 ----~~=~~~==·~ 6.0 7 .0 ~--"-~== 8.0 

IIi : f>e1kNc:1.SE $.10d Puc I ofl 

----------------

Currtnt ~e : 2QO$.Q9-0J 

Cun~t Time : OO:JS:Z8 

VES 006243 
Sample Analysis Report 

Sample Name : B-SPIKED 

Data File Name : C:\PEAKNETIDATA\ANION\10-23_AAL043.DXD 

DetettorType: DX-120 . 

Meth>d File Name : c:lpeaknet\mefuod\metbod\120anions.met 

Schedule File Name: c:\peaknet\schedule\scbedule\schedule\120anions\2008\J20anion0902.sch 

Date Time Collected: 2008-09-03 12:36:17 AM 

Sysl!m Operalor : U.E 

Calibration Date: 2008-09-02 6:54:22.PM 

Calibration Type : EXTERNAL . 

Con"I""''nt Amount Units : mg/L 

Oilulion Factor : 2.00 

Peak Information : All Peaks 

Peak II Component Name Amount (mg/L) Relelllion T:ime 

I 0.0000 0.80 

l Fluoride 0.1423 1.02 

3 . 0.0000 1.40 

4 Chloride 8.3674 1.62 

s Nitrite 1. 7~4 1.98 

6 0.0000 3.17 

7 Sulphate 3.4120 7.78 

8-SPIKED 

16.0f 

\ 

14.0 

12.01 

10.0 

\ v.> 8.0 4 ::r.. 6.0 I 

4.0 

I 2 · 3 fU_ \ 2.0 

0 

I I _j_, 

-2 .0 o'-· 1.0 2.0 3.0 4.0 5.0 . .. 

~~~ : f'mNet-SE SJOd ~e!otl 

6.0 

Peak Area PeakHelgbl 

- 1702 433 

2440 586 

23754 2525 

285055 51311 

91029 11938 

22690100 1699467 

73198 4334 

7 

. I 

-- 7.0 s.o 

Qln-ent ~ : 200S..()c)·Ol 

Cum.nt Time: 00:44:59 

VES 006244 
Sample Analysis Report 

Sample Name : CCB 

Datt File Name : C:\PEAKNETIDATA\ANJON\10-2J_AAJ044.DXl> 

Deteotor Type : DX·120 

Metllod File Name: c:\pealmet\metbod\method\120anions.rnet . 

Schedule File Name: c:'pealmcl\schedole\schedule\schedule\120anionsl2008\120anion0902.sch 

Date Time CoUected : 2008-09.03 12:45:48 AM 

System Operator: LLE 

Calilmltion Date :2008-09-02 6:54:22 PM 

Calibration Type : BXTERNAL 

COI'Jl>Onent Amount Units : mgiL 

Ditulion Factor : 1.00 

Peak Infonnation : All Peaks 

Peak II Component Name Amount (mg/L) Retention Time Peak Area 

CCB 

16.0 

14.0 

12.0 

10.0 . 

<n 8.0 

:0. 6.0 

4.0 

2.0 

0 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 . .. 

h~ I ofl 

Peak Height 

8.0 

O:lr:rtnl ()ale : 2(10&.{)9-oJ 

Ctne1\4 Time : 16:07:32 

VES 006245 
Sample Analysis Report 

Sample Name : CCV 

Data File Name: C:IPEAKNE1\DATAIANION\10-23_AAJ04S.DXD 

Deteetor Type : DX-120 

Meth>d File Name : c:\peaknet\metbod\metbod\129anions.met 

Schedule File Name : c:\peaknet\schedule\schedule\schedule\120anions\2008\120anion0902.scb 

DateTimeCollected: 2008-09-0312:55:19AM 

Systtm Operator : LLE 

Calilt-alion Date : 2008-09-QZ 6:54:22 PM 

Cali.tcalion Type : EXTERNAL 

Co~oncnt Amount Units : mg/L 

Dillllion Factor : 1.00 

Peak Infonnatiou : All Peaks 

Peak II Compon.ent Name Amo•nt (mg/L) Retentlou Tlme.. Peak Area Peak Height 

·---·---·--------------------------- I 0.0000 0.80 6812 

2 Fluoride 1.8226 1.00 181977 

> Chloride 2.9523 1.62 197875 

4 Nitrite 1.4363 1.98 183601 

S Bromide 5.8612 3.07 167093 

6 Nitrate 1.9580 3.52 336086 

7 Phosphate 5.7957 5.71 343313 

S Sulphate 11.7117 7.72 568292 

CCII 

16.0. 

14.0f 

12.0" 

IO.Oj 

s.oj 

6.0j 2 ~ 4 6 8 

1254 

38564 

43131 

·30163 . 

23679 

39538 

24722 

32978 

4.0t IJ I ~ I ; 1 

~t-JJ \JL_JVL __ __ _!\. ___ 1\ __ 

h~e toil 

Omenl Dalll ! 2(}03...()JJ.O) 

Current Time : 0 1 :OJ;s-6 

VES 006246 
Sample Analysis Report 

Sample Name : CALIB STDl 

Data File Name: C:\l'EAKNE1\DATA\ANlON\10-23_AAE08S.DXD 

Detector Type: DX-120 

MetllOd Fiie Name : c:\peaknet\rnethod\melhod\120anions.met 

Schedule File.Name : c:\peaknet\s<:bedulelschedule\schedule\120anions\2008\120.nion0902.scll 

Date Time Collected : 2008-09.03 7:13:58 AM 

Systtrn Operator : LLE 

Calibration Date: 2008-09.()2 6:54:22 PM 

Calibration Type : EXTERNAL 

Corrponent Amount Units : mg/L 

Dilution Factor: 1.00 

Peak Information : Al.l Peaks 

Peak# Component Name Amoont (mg/L) Reteotloo Tlme Peak Area Peakllelgbt 

--·-- .. -- -·-·----·----------- -------·------·---···-· 

16.0J 

14.0 

12.0i 

IO.Of 

8.0 

6.0 

4.0 

0.0000 

CALlBSTDl 

1.37 

2.0 . 'l . 0 r---··------ --- ·---- ----- --·- --- - ------

8413 

-2. ·'--- -:---.,- -:--·---:----"7-:--~::- -----·--·------- 0 1.0 2.0 --3.0 4.0 5.0 6.0 7.0 8.0 

1253 

15 ~ : PolcNei·SE S.IOd Pa.t.c I of I 

Cunenl Date : 2008.00·03 

Cuo-ont im~ : 07:22:3S 

VES 006247 
Sample Analysis Report 

Saltll'le Name: CALIB STD2 

Dais File Name: C:IPEAKNETIJ)ATAIANION\J0..23_AAE086.DXD 

DetertorType: DX-120 

Metllo<l File Name : c:\peaknet\methodlmetbod\120anions.met 

Schedule File Name : c:lpeaknetlschedulelschedule\schedule\ 120anionsl20081120anion0902.scb 

DateTime Collected: 2008-09-03.7:23:23 AM 

Systan Operator: LLE 

Calibration Date: 2008-09;02 6:54:22 PM 

Calibration Type: EXTERNAL 

Component Amount Units : mg/L 

Dihiiion Factor: 1.00 

Peak lnformation : All Peaks 

Petk # Component Name Amount (mg/L) Retention Time Peak Area PeokHelg)lt 

·- -- ·· -·----,- ~------ -···- -- ------· -·-·····--··-. - ·-

I Fluoride 

l 

3 Chloride 

4 Nitrite 

5 

6 Phosphate 

7 Sulphate 

16.0 

14.0 

12.0 

10.0 

8.0 

6.ol 

0.0874 

0.0000 

0.1210 

0.0776 

0.0000 

0.5383 

0.2581 

CAUBSTD2 

1.02 4071 

1.37 10509 

1.65 5520 

2.00 5145 

3.58 6144 

5.82 21937 

7.78 3026 

4.0t 

2.0·. 1 2 3 4 5 6 7 

815 

1428 

1140 

849 

788 

1665 

220 

I I I I 1 i · l 

-2 0 L==-= 1.0 2.0 ==3.0 ~-~~~-=~~=~~=~~= 4.0 5.0 6.0 ~=~~~-7.0 :-~~-=··-~ 8.0 :~ 

(..'u:Ttnl- Date : l()0$..@.0) 

Cwm.c. Tiotac·! 07:32:01 

VES 006248 
Sample Analysis Report 

So~ It N:une : CALIB STD2 

Dato FUe Nome: C:\PEA.KN'E'I\DATAIAN10N\10-l3_AAE086.DXD 

. Detector Type: DX-120 

Method File Name : c:\peaknetlmetbo<l\methO:CJI 120anious.met 

S<:h<dule File Name : c:lpeakncrlscbedulelsclladulelschcdulell20anionsl20081120anion0902.seh 

Date Tame Collected: 2008.09..03 7:23:23 AM 

Systm1 Operator: LLE 

Colibntion Date: 2008-09..02 6:54:22 PM 

Cal il>rotion Type : EXTERNAL 

~~Amount Units: mg/L 

Dih.tion Factor : 1.00 

Peak Information : All Peaks 

Peol< # CompoDent Nlllllt Amount (mg/L) Retentioo TilDe 

. I Fluoride 0.0874 1.02 

2 0.0000 1.37 

l Chloride 0.1210 1.65 

<f. Nitrite 0.0776 2.00 

s 0.0000 3.58 

6 Pbospbate o.sm 5.82 

7 Sulphate 0.2544 7.78 

CAU!JSJ'Dl 

16.0 

14.0 

12.0 

10.0 

'a 8.0 

6.0 

4.0 

2.0 I 2 3 4 . 5 , I ! I j! l I I I ! 0 

' ' ·2.0 

0 1.0 2.0 3.0 4.0 5.0 

. -

Paltf: J o(l 

. 

6 

I I 

' 

6.0 

PeakArtll Peak flelg)lt 

~071 815 

10509 1428 

5520 1140 

5145 849 

6144 788 

21937 1665 

2847 214 

7 , 

I i 

7.0 8.0 

Cvncnt Dille ; 2:008-(;9.0.) 

C~onm.l Tinw! U}:l.l:02 

VES 006249 
!· Sample Analysis Report 

Sar11ple Name : CALl~ STD3 

Data File Name: C:\PEAKNETIDATA\ANION\10-23_AAE087.DXO 

·Detector Type :DX-120 

Method File Name: c:\peaknet\method\method\120'.snions.met 

Scbcdllle file Name : c:\p!:akn&\scbedule\schedulelschedule\120anions\20Q8\ 120anion0902.scb 

Oatt1ime Collected: 2008.09-03 7:32:49 AM 

System Operator : LLE 

Calibntion Date : 2008..()9-02 6:54:22 PM 

Calibratio!l Type: EX'l'ERNAL 

Conponent Amount Units : mg/L 

Dih.otion Factor: 1.00 

Peak Information : All Peaks 

Peak II Component Name Amount (mg!L) Retention Time 

I 

2 

3 

4 

s· 

6 

7 

g 

Fluoride 

Chloride 

Nitrite 

Bromide 

Nilrate 

Phosphate 

Sulphate 

16.{) 

14.0 

12.0 

10.0 

M 

4.0 . 

0.3993 1.00 

0.0000 1.35 

0.6437 1.62 

0.3004 1.98 

1.2066 3.08 

0.4044 · 3.57 

1.2427 5.80 

2.4408 7.73 

CALifJSTD3 

Peak Area 

35558 

9929 

40241 

33%6 

32231 

63096 

64155 

108949 

Peak Heigh( 

7015 

1309 

7914 

5511 

4518 

7818 

4714 

6331 

6.0! 

-~ t ___ _l_: __ Lt _____ ll .. . _________ _l_···-··-__ ___ L. ·2.oL· =-= ---~ -...:,-: 0 1.0 2.0 3.0---4.0 

Pe;te l of I 

G'UtTent. Oa.te: 2008-09·03 

Cunel)l Tme : 07:41:32 

VES 006250 
Sample Analysis Report 

Sample Name : CALIB STD4 

Dab File Name : C:IPEAKNET\DATAIANION\l0-23_AAE088.DXD 

Dclcctor Type : DX-120 

Melli()() File Name : e:lpeaknetlmetbodl.metbodll20aoions.met 

Schtdule File Name: c:lpeaknetlscbedulelsehedule\scbedule\120aoions\2008\120aoion0902.scb 

Date Time Collected: 2008-09..03 7:42:21 AM 

~ySiem O,rerator : LLE . · 

Calibration Date: 2008-09-02 6:54:22 PM 

Cali\> ration Type : EXTERNAL 

Component Amount !Jnits : mgiL 

Dilution Factor : 1.00 

Peak Information : All Peaks 

Pf2k# Component Name. Amount (mg/L) Retention Time 

I 

2 

} 

• 5 

6 

7 

g 

Sl 

Fluoride 

Chloride 

Nitrite 

Bromide 

Nill'llte 

Phosphate 

Sulphate 

16.01 

l4.0j 

12.0l 

IO.Oj' 

8.0 

0.0000 0.80 

1.9914 1.00 

0.0000 1.37 

3.1075 1.62 

1.5030 1.98 

!'.0876 3.08 

2.0298 3.53 

6.0585 5.77 

12.2208 7.70 

G:ALIBSTD4 

Peak Area 

8983 

199650 

10422 

208741 

192532 

mm 

348986 

359779 

593975 

Peak Height 

1531 

39881 

1264 

40943 

30099 

247n 

41008 

26276 

34397 

6

·

0

1 Tj 4 s 6 ~ 8 ; 4.0 1 ~ I I ~ 1 , 

2.~,_ _____ ll\ ~ JL_ju ~j\_ _ __ _) \_ 

-2.01 L ___ _ _ _ ... .. . . . .. . .. .. 0 1.0 2.0 3.0 4.0 

C.'Ufl"e:lt Oil$e : 2008.c»-03 

Curren! T'm-~ · 07:$1>:S8 

VES 006251 
Sample Analysis Report 

Sample Name : CALIB STDS 

Dat> File Name: C:\PEAKNET\DATA\ANION\10..23_AAE089.DXD 

Detector Type: DX-120 

Metbod File Name : c:'4>eak.net\metbodlmethod\120anions.met 

Schedule File Name: c:'4>ealcnetlscb.edule\scl"!dnle\scbedule\l20anions\2008\l20anion0902.sch 

Datt Time Collected : 2008-(19-03 7:5 I :47 AM 

Sysiom Operator : LLE 

Calil>ration Date : 2008..09-02 6:54:22 PM 

Cal oration Tyl'l': EXTERNAL 

Component Amount Units : mg!L 

Dillltion Factor: 1.00 

Peak Information : All Peaks 

Peak II Component Name mo~tnt (mg/L) Retention Time 

I 0.0000 0.78 

2 Fluoride 3.9S38 0.98 

3 Chloride 6.2762 . 1.62 

4 Nitrite 3.0441 1.97 

s Bromide 12.4953 3.05 

6 Nitrate 4.1863 3.48 

7 Phosphate 12.5537 .5.70 

8 Sulphate 25.1317 7.65 

CAL!BSTD5 

Ill : Prak.Nc.t·SES.IOd Pare lor ! 

Peal< Area 

14675 

410354 

438n2 

403698 

367779 

749645 

780158 

1262.971 

Peak Height 

2574 

86713 

99725 

61586 

52298 

85193 

55699 

73549 

Cum:nt D;~ -e : 2008·09·03 

Current 'Time: 0$:()0:29 

VES 006252 
Sample Analysis Report 

Sample Name : CALIB STD6 

Data File Name: C:IPEAKNETIJ)ATA\AN ON\10-~ AAE090.riXD 

Detector Type: DX-120 

Melhod file Name: c:\peak.D<':t\metbodlmethod\120anions.met 

Schedule File Name: c:lpealcnet\scb.edulelscbedulelschcdule\120anions\2008\120anion0902.sch 

Date :rime Collected : 2008-09·03 8:0 I: 18 AM · 

SyS1em Operat<>r : LLE 

Calbration Date: 2008-09·02 6:54:22 PM 

Calibration Type :EXTERNAL 

Component Amount .Units : mgiL 

Dilution Factor : 1.00 

Peak Information': All Peaks 

P<ak # Contpoutnt Name Amouot (mg/L) Retention Time 

I . 0.0000 0.80 

2 Fluoride 6.3617 0.98 

3 Chloride 9.5995 1.62 

4 Nitrite 4.7237 1.98 

5 Bromide 18.9206 3.05 

6 Nitrate 6.3150 3.45 

7 Phosphate 18.9026 5.67 

8 Sulphate 37.9068 7.62 

C4L.lBSTD6 

Pe.okArea 

24516 

683628 

699817 

645461 

573099 

1173776 

1219751 

1962066 

16.01 ' 2 6 1~ 0 ~ I 8 

:::: I 1 i ! ; /AI 

· 2.0 

PeakHeigbt 

4259 

134582 

153465 

105871 

83600 

125573 

S6203 

113434 

-·- ··- ~----- - ·- --·-- -···-··-·-----·-··---·--....--- - .. - 0 LO 2.0 3.0 4.0 5.0 6.0 7.0 8.0 

II PtakN~-SBS IOd PaJe 1 of I 

OJ~nt ().nc ; 1008-o9-0J 

OJrrer~tTunt: 08: 10:01 

VES 006253 
Sample Analysts. Report 

Sample Name : MBLANK 

Dato Fi~ Name: C:\PEAKNE1\DATAIAN10N\10-23_AAE091.DXO 

Det~ or Type : DX-120 

Metl>od File Name: e:lpeaknet\methodlmelhod\120anions.met 

Schedule File Name : c:\peaknet\schedule\sebedule\schedule\120anions\2008\120anion0902.sch 

Date Time Collected: 2008-o9-o3 10:46:09 AM 

Sys 1m! Oper•tor : LLE 

Calibration Date: 2008-09-02 6:54:22 PM 

Calibration Type : BXTERNAL 

Component Amount Units : rngiL 

DiiUiion Foetor : 1.00 

Peak Information : All Peaks 

e~k It Component Name Amount (mg/L) Retention Time 

MBUNK 

16.01 

14.0 

12.0 

10.0 

"' 8.0 - "- 6.0 

4.0 

2.0 

0 --

-2.0 

0 1.0 2.0 3.0 4.0 5.0 ... 

~~~ : PetkNet-SES.IOd P-.e l ofl 

6.0 

Peak Area Peal< Height 

.... __ 

7.0 8.0 

Cum:tlt ~e ; 201)8.()9.03 

C\Jrr'QII1'tnle : IO:j4:47 

VES 006254 
a~ple Analysis Report 

Sample Name : MSPlKE 

Dato FileName: C:IPEAKNET\DA A\AN N\ l-23 AAE09 .DXD 

Detl>'torType: DX-120 

Met!Jod File Name : c:\peal01et\method\method\120anions.met 

Schedule File Name: c:\peaknet\scbedulelschedule\whedule\12Qanions\2008\J2Qanion0902.sch 

Date Time Collected: 2008-09-03 10:55:36 AM 

Sysitm Operator : LLE 

Calibration Date : 2008-09-02 6:54:22 PM 

Calibration Type : EJ{TERNAL 

Corrpooent Amount Units : mg/L 

Dilulion Factor : 1.00 

Peak Information : All Peaks 

P .. k # .Component Name Amount (mg/L) Retention Time 

I 

2 

3 

4 

5 

6 

7 

8 

Fluoride 

Chloride 

Nitrite 

Bromide 

Nitrate 

Phosphate 

Sulphate 

16.0 . 

14.0 

12.0 

10.0 

8.0 

- 0.0000 0.80 

2.0255 0.98 

3.0263 1.62 

1.5079 1.98 

6.0307 3.07 

1.9993 3.52 

6.0235 5.77 

12.1600 7.68 

MSPIKE 

Peak Area 

8919 

203228 

203049 

193189 

172093 

343519 

357583 

590905 

Ill 

:s. 

6.0 2 t 4 1 8 

Peak Height 

1490 

33083 

42374 

30135 

23579 

39413 

2'5876 

33891 

4.0 I ~ r 7 . I 

-~+--~: uJL_JJL _ _A_j\_ _ _ -2.0 ---=~--=-:,.-----:-:--- 0 -· ..... ro~-...,'"'.,_--,-,.0-- --:: .o----,.-::- .o .. - 6.0 7.0 8.0 

~clo(l 

OJrrent 0.~; l008.()9.0) 

OJrrcnt Time· : II :04: 19 

VES 006255 
Sample Analysis Report 

Sample Name : AH3048 

Data File Namt: C:\PEAKNE'J\DATA\ANlON\lO-Z3_AAD097.DXD 

Detector Type : OX· I 20 

Method File Name : c:\peaknet\method\method\J20anions.met 

Scbedule File Name : c:\peliknetlschedule\sclledule\scbedule\ 120anions\2008\120anion0902.sch 

Date Time Collected : 2008-09-03 II :43:07 AM 

Sysr:m Operator : LLE 

Calibration Date : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mWJDilu!ion Factor : 50.00 

Peak Information : All Ptaks 

Pe..k # Component Namt Amount (mg!L) Retention Time 

.. ·-.- -....... · 

l Fluoride 19.6175 1.00 

2 Chloride 280.5242 1.62 

3 Nitrate 104.5367 3.50 

4 Phosphate 16.0138 5.83 

s Sulphate 106.8870 7.75 

AH3048 

16.0 

14.0 

12.0 

10.0 2 

I 

'a 

8.0 

6.0 3 

I 

4.0 

2.0 _A 1 

0 ~ 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 

Pale I of I 

--- - ------ --·-·-·-·-· · 

4 

I 

6.0 

Peak Area Peak Height 

34857 6225 

389060 86263 

359965 42599 

8922 .698 

94192 5408 

5 

I 

~-

7.0 8.0 

Cun'MI Date : 200$-$..():) 

CWrcnltime: 11:51:44 

VES 006256 
Sample Analysis Report 

Sanple Name: All305l 

Dab File Name: C:IPEAKNET\DATA\ANION\10..2J_AAD098J>XD 

Detector Type: DX-120 

Mc(hod File Name : c:\peaknet\tnetlJod\method\120anions.met 

S<:hedulo FileName: c:\pealmt:t\schedule\scbcdulc\schedule\120anions\2008\120anion0902.sch 

Date Time Collected: 2008-09·03 11:52:33 AM 

System Operator : LLB 

Calibration Date: 2008-09·02·6::54:2.2 PM 

Calibration Type : llXTERNAL 

Compooent Amount Units : mg/L 

Dilootioo Factor : I 0.00 

Peak Information : AD Peaks 

P.,.k • Compollent Nome Amount (mg/L) Retention Tome 

1 0.0000 0.80 

2 Fluoride 3.8157 1.00 

3 0.0000 1.35 

4 Chloride 36.6889 1.62 

s Nitrite 1.3000 1.98 

6 Nitrale 96.9567 3.40 

7 Sulphate 135.1404 7.70 

AH3052 

16.0 

II 14,() 

12.0 

10.0 

V> 8.0 4 ::1. 6.0 I 

4.0 

2.0 I 2 3 s 

I ! I I \ 0 

·2.() 

0 1.0 2.0 3.0 4.0 5.0 

. -

II : fCIJcNcc ·SE SJOd P•ac tor I 

PeskArea Peak He(gllt 

2397 460 

33766 4266 

9104 1209 

248329 54180 

11904 1748 

1924826 204233 

6S94S2 38133 

7 

I 

,__}\_ 

6.0 7.0 8.0 

c.-· -: l0041-09·0J CW'tcAt Tlt~llt : ll:Ot: IS 

VES 006257 
Sample Analysis Report 

Sample Name: AB3052D 

Daia File Name : C:\PEAKNETIDATA\ANION\10-23_AAD099.DXD 

DettctorType: DX-120 

Me1bod File Name: c:\peaknet\meihodlmetbod\120anions.met 

Schedule File Name: c:\peaknetlscbedule\sclledule\scl.>edule\120anionsl2008\120onion0902.sch 

Datt Time Collected : 2008-09-03 12:02:04 PM 

· SyS1Cm Operator : LLE 

Calibration Date : 2008-09-02 6:54:22 PM 

Ca~ ration Type : EXTERNAL 

Component Amount Units : ~ 

Dihltion Fa<:tor: 10.00 

Peak Information ; All Peaks 

P tak # Component Name Amount {mg/L) · Retention Time 

1 0.0000 o.so 

2 Fluoride 4.0923 1.00 

3 0.0000 1.35 

4 Cbloride 27.8332 1.62 

5 Nitrite 1.3192 1.9& 

6 Nitrate 84.8629 3.40 

7 Sulphate 119.7498 7.70 

AH30S2D 

16.0 

\ 

14;0 

i2.0 

10.0 

4 ' \ "' s.o ::1. 6.0 

4.0 

2.0 

0 

1 

I 

2 

I LJ~ -2.0 

0 1.0 2.0 3.0 4.0 5.0 . - 6.0 

Peak Area Peak Height 

2566 481 

36567 4578 

8158 1114 

186088 40582 

12152 1870 

1643204 )74478 

581567 33352 

7 

I 

·)\_ 

7.0 8.0 

CWT~nt,Da1e : 2008-09·03 

t\lm:nt Ti;m.e :,1 2.: t 0:4 7 

VES 006258 
Sample Analysis Report 

Sample Name : CCll 

Data File Name: C:IPEAJ<NE'I\DATA\ANION\10-23_AAD193.DXD 

Detector Type : DX-120 

Method File Name : c:\peaknet\method\metbodl 120anions.met 

Schedule File Name : c:lpeaknet\...:bedule\schedule\<;ebedule\120anions\2008\12funion0902.sch 

Date Time Collected : 2008-09-03 3:18:35 PM 

System Operator : LLE 

Calibration Date : 2008-09-02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dilution Factor : 1.00 

Peale lJlfonnation : AU Peaks 

Peak II Compoaent Name Amount (mg/L) Retention Time Pellk Area 

·-··- ··-·-

CCB 

16.0 

14.0 

12.0 

10.0. 

'1 &.o 

6.0 

4.0 

2.0 

0 

-2.0 

0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 . .. 

~~~~ : PetakNec·SS 5.10d P&f!e I of t 

Peak Height 

. 

. 

8.0 

Oureot Dale : 2008·09.03 

Qlncnt Time: I.S:V:ll 

VES 006259 
Sample Analysis Report 

Sanple Name: CCV 

Data File Name : C:\PEAKNE1\DATA\ANION\10-23_AAD104.DXD 

Dettctor Type : OX-120 

. Melliod File Name : c:\peaknetlmetbod\rnethod\120aniolls.met 

Schedule File Name : c:~laJet\~bedu e\sehedule\~edule\120anious\2008\120anion0902.s b 

Date Time Collected: 2008-09-03 3:28:01 PM 

SySiem Operator : LLE 

Calibratiou Date : 2008-09·02 6:54:22 PM 

Calibration Type : EXTERNAL 

Component Amount Units : mg/L 

Dillltiou Factor : 1.00 

Peak Infomutiou : All Peaks 

Peak # Component Name Ao•ount (mg!L) Retention Time 

1 0.0000 0.78 

2 Fluoride 2.0141 0.98 

3 Chloride 3.0343 1.60 

4 Nitrite 1.4935 1.95 

s Bromide 6.0489 3.00 

6 Nitrate 2.0100 3.45 

7 Phosphate 6.0180 5.77 

8 Sulphate 12.0977 7.68 

CCV 

16.0 

14.0 

12.0 

10.0 

tl) 8.0 ::1, 6.0 2 3 6 

7 

P eak Area 

8676 

202035 

203614 

191251 

172628 

345438 

357239 

587759 

8 

Peak Height 

1425 

39609 

44008 

30752 

24598 

41416 

25937 

33975 

4.0 ~ ll_ ~ j, I 

_;\_,_A_ .::~t · __ lJL ___)\_ \ 

0 1.0 2.0 3.0 4.0 

h~lo l 

5.0 6.0 7.0 8.0 

C\Jnent Dale ; l.OOS-09.0) 

Cus:r~n1Time : 1S }6;-4) 

VES 006260 
Method 7471A -Mercury In Solid Or 

Semisolid Waste 

Maxxom Analytics Inc. 

6740 Campobello Rd. 

Mississauga, Ontario, Canada 

LSN2L8 

1-800-668-0639 

www .maxxamaoalytics.com 

VES 006261 
.. 

l.lor<ury In Sea by CVAA • SOil 

{ug/O) 

I . . 

' ' ' . . -.m 

WO<kaho« Number: 1602842 

VES 006262 
RUSH 

Report Name: Woi1< Sh«t- (Liquids and Solids} #' 1602842 

A.$si&oment Date: Wcxin:esday; September Ol. 2008 

Assigned co: HASAN BAYDAR 

Te!t Code: HG-S lnsttument Id' 

Tcu Descrip<ion' TO DI!.TE.RMINI! MERCURY BY COW 

VAPOURAA.· 

Job S•mple % 

'Nurobet Number D s ..... te!D F Moist 

M=SPK lv lCP2 AIDOSS-0 1 

REF MAT ~n SS2RM 

BLANK 

'A&94939 AiilosZ:ot R CS-04-lU ~I --F.Yr 

'A894939 AJI30S3-0IR CS-04-IU I .,._ 7·U 

' A894939 AH30S4-0IR CS-04-Rl .l Hi. 

•AS94939 AJ.I30S5-0IR 0 BS-04-RI o.~ 

' A&94939 A.HlOSS-OIR I BS-U4-!U n. ill 

' A894939 Alll056-0IR BS-04-R2 ,.-- 0. ,t; ~ 

'A894939 Ali3058-0IR .BS-04-Rl ~ 'l ~~~ 

.td 

q, .r 

/ 

/ 

/ 

/ 

/ 

v 

/ 

r 

_./" 

Recntn\$; 

Wt 

or 

Vol 

IHO 

h-rl 

0.500 

0.490 

0.510 

0.490 

0 •f('J 

0.490 

OSOD 

I 

,od 

,V '/ y--tlf 

S ampl« e:x.uacted by: f!ASAN BA YDAJ< 

ln.strv.rnenb.tion ptrlonnod by: 

Ca ell lOJl$ pe

V

rf

ali

o

d

rmed 

n.ced b

b

y

y

: 

: 

~ 

Final 

Vol 

)f).,J 

A 

)/ 

~ 

1'1ge#' lofl 

DF 

or I( E<p!Jy Test 

M Cont Date Deadline Criteria 

2 2008/08128 2008109/03 17,00 

2 2008/08128 2008/09103 17,00 

2 2008108n8 2008109/03 n,oo 

2 2008108128 2008109/03 17,00 

2 2008108128 2008109/03 17,00 

2 2008108128 2008109/03 17,00 

2 2008108128 2008/091!)3 17,00 

/ 

/ 

/ 

/ 

/ 

..... 

.. 

£ 

Dace: JB)'l.7 o~7 a:;') 

Date:: 

'i' Date: 

: t>a.~: 

VES 006263 
·' I 

! 

! 

Job No. &e Clien<Name 

GAS94939MDCENSR lntematicrn31 

Surro .. <<SIS.ik .. 

Somole Preoar!ltion Rem"rlcs 

: 

Sa,nole ln.strUJDeD:tAtion Renu\rks 

-::-

RUSH 

#: 1602$42 

~ 

· 1effGorman 

-

fJ!11 Remarks 

· (315) 437-0509 , .. RUSW .. tCP+HG. TOTAL CHLORIDE.~, 

BTU&.% ASH ()()lfi'ENT SUS TO 

PSC.REPUBUC. Projec< #: 10002-022 

NATION.$!.: J!IISR INTERNATIONAL 

Metb<XI Snike Sanmlts 

VES 006264 
Maxxam A.Mtytic-s-lnc 

CAM fC0~48/1 

P~ 1 of1 

Prep Batch Reagent Tracking Record Work~heet# j 6t>J..f tJE_ 

Volume lui\ 

SurrogatefSplke solutions Solution 10 # Cone. Blk·Spk MS Samples 

. 

· ICPMS 

ICAP ICP Soil Spk. A(SPK·08.09}&B Variable 1ml./50ml. 

GFAAS 

Hg Hg Splke(Hg Spk·08·10) 0.25ppm 1ml./50ml. ,h' 

Solvent Supplier Lot No. Spiked by: 

HN03 Fisher 308172 !/Ill!-

HCI Fisher 208051 Spiking Witnoued by: 

H202 

HtSQ• . Spike Date (yyyy/mmldcl) 

(j{~il00!/2":> 

Comments 

·. 

VES 006265 
.. I Data I - Metals and Wet Chem 

I 

,, 

t 1 yea no nil 

/ .-- c-.?-

-:?-

v ' 

' ··~ 

I L.,...: 

L..-

/. ~ 

~ 

~ 

I ' 

I bv: • /7tlr::#f? /C/7/f/:S 

·- no n/a 

"" / 

• crileria , 

, 

, 

, 

, " I Chat! ~mn<!.Y!Q!~;t ~PO meets ilic:e Citttrla I I M•""' ool< I meets I crlloo1o 

/ 

/ 

~ 

,-··---,.._-

!lor -_, 

--:? 

/ 

I 

~b~ TL. l001e: -z:iif I 'I /D~ 

, 

I 

td aamoi<O-rewl!s land 

3 toto

1

::'do< ~s 

' a ;Pro.> 

/ 

· voa no ova 

/ 

I I - -.:94A/~ ----1 

VES 006266 
-----,·~- ===~~-------~=====--- -------- Method Name : SOP-0112 

Method Description: Soi1--Caapobello Rd. (500 uL loop] 

Eltment : Hg 

Dat8: 2008 - 09- 03 

Technique :FI- MHS C~libration 1ype: 

Hg, terQ Inte tcept : J .. inear 

Wa•elongth: 25 3.7 nm. Saople I nto Name: 8- 9-03A.SIF Results Data Set Name: 8- 9- 03a 

~.,-.,.~--... ------.-·-·----------======~-~- ---- -=--- Elernent: llg Seq. No. : 9 

S~ e ID: Calib Blank 

Repl 

f 

l 

2 

Heon: 

SampleConc ag/L StndConc 

mg/L 

Auto- zero per-foread. 

liS Loc.: 9 Date : 00 -0~-03 

Poak 

HeiQht 

0.0003 

0.0002 

Tiae Peak 

Stored 

09:08:23 Ho 

09:09:04 Ho 

Ele...,nt : llg Seq. No,: 10 AS Loc.: 10 Do te: 2008-09- 03 

So•ple 10: 0.25 ppb ----------------------------------.. --... -.... ----------------------.. --... -... -.. ---.. -------..... - Repl 

I 

I 

2 

Hea n: 

Samp1eConc o>q/L StndConc 

mg/L 

Peak 

Height 

o.oon 

0.0017 

'\'ime Peak 

Stored 

09: 10 :02 No 09: 10 :43 No 

( H9l Standard number 1 aPPlied. (0 .0"002$) 

Cor:ce..la.tion Coefficient: 1 4 00000 Slope: 5. 93 494 

------ Sleoent: Hg ... ---Seq. ----=-----· No . : 11 - =-===----...... =~- -···----

Saple 10: 0 . 5 ppb 

RA!;>l 

l ' 

2 

Mean: 

Satnp le"'....ooc 

1119/L 

StndConc 

109/L 

liS Loc.: 11 Date: 2008 0~ 03 

Peak 

Re.!9hl 

o. 0040 

0 . 0040 

Title Peak 

Stored 

09 :11:41 llo 

09:12:23 No 

(llg] Stondar<l nural:>er 2 applied. (0.00050 ) 

Correlation Co tf~ lent: 0. 96321 Slope: 7 . 207 52 

Elon1ent: Hg Seq. No.: 12 liS Loc. : 12 Date: 2008- 09-03 

Sonple l O: 1.0 ppb 

------------- ---- ---- -- --~---- -----.. -------------------------...... --------------- 1\opl 

I 

l 

2 

tia.an: 

srunpleConc 

mg/L 

StndConc 

mg/L 

Peak 

He1Qht 

0.0080 

0.0019 

Time Peal< 

Stored 

09:13:21 No 

09:14:03 !lo 

[Hg) Standard ~r 3 applied. (0.00100) 

Correlation Coeft~cient: 0.99422 Slope: 1 . 61031 

Element: P.g Seq. No.: 13 

=-·----------

Soaple ID: 2 .0 ppb 

AS Loc . : 13 Date : 2008-09-03 

-·---------------------------------------------------·-----·---·------4----------------- 1\tpl 

I 

I 

~ 

sampleconc 

mq/L 

StndConc 

lfl9/L 

Peak 

Height 

O. OlGO 

0.0160 

T i&e Peak. 

Stored 

09:15:40 No 

09:16:21 No 

Page - 4-

VES 006267 
Hem: 

(H9) Standard .nUttber 4 applied. (0.00200) 

Correlation Coefficient: 0.99812 

£lm>ent: -·----Hg ·--------~---- Seq . No.: 14 -== liS Loc. : l4 

Sa•ple IO: S.O ppb 

Slope.: 7. 82089 

Date: 2008-09-03 

------ ------~-------------------------------------- ------------------------ ---~ --~--- Repl 

• l 

2 

f.W!an: 

SampleConc 

mg/L 

StndConc 

mq/L 

Pnk 

HelQht 

0.0411 

0.0406 

'l'lro.e Pea k 

Stored 

09: 18 :00 No 

09:16 : 42 No 

!Hg) Standar d number 5 appliod. (0.00500) 

Correla tion Co•ffieient: 0.99963 Slope: 8 . 07641 

&lft~nt: Hq Seq. No.: 15 AS Loc.: 15 D•te: 2008-09-03 S~le ID: 10. 0 ppb 

Ropl 

1 '

2 

Mom: 

saapleConc 

roq/L 

SmdConc 

mg/L Pea~ 

Height 

0.0768 

0 . 0759 

Time Peat 

Store<! 

09:20:21 No 

09:21:03 No 

! Hql Standard ouoooer 6 applied. [0.01001 

Correl ation Coefficient: 0.99933 Sl ope : 7 . 72409 

Calibration data for Hg 

~n ered calculated 

Mean Siqnal Concentxation Concentration Standard 

Sta nda.rd 10 ( Pk Hei ght) (rug/L) (mg/Ll l)eviation 

Calib Blank 0.0002 

0 . 25 ppb 0 .0015 0.00025 0.00019 0.000030 

o.s ppb 0. 0037 0.00050 0.00048 0.000010 

l.O ppb 0 . 0077 0.00100 0.00100 0 . 000030 

2.0 ppb 0.0158 0.00200 0.00204 0 . 000012 ~-0 ppb 0.0406 0.00500 0 . 00526 0.000371 

10. 0 ppb 0.0761 0.01000 0.00985 0.000594 Cor~el ~ion Coefficient: 0.99933 Slope: 1. 72409 

tRSD 

z.o 

0.3 

0.4 

0.9 

0.8 

- ···-·-------- . 

VES 006268 
' . 

o.oa --r 

' ' 

~ 

o.oo -r 

. 

; 

0.04 ·~ 

0 

Hg 

,/ 

0.005 0.010 0.015 

,; 

Concentration 

VES 006269 
Perk!n-£Lner AAWinLAb: 2008-09-03, 02:12:25 PM 

SaDple xntor.atioo File C:\AAUSBR\SAMPINI0\8-9-0JA.SIF 

Descriptl.o·n 

!latch I D 

volwue Units 

!Oeight Unlts 

Analyst 

Sample Volume 

AS SIUOple ID 

Loo 

17 1602S&O: REFMAT 

19 ))LANK 

19 HTI\X SPK 

20 AI269&-01:01 

21 AI269&-Ql 

22 AH931S-02 

23 AI2011-Q3 

24 1112013-03 

25 AI201S-03 

26 1112681- 0l 

27 AI2691-01 

28 1116362-01 

29 REFI1A1 

30 111687·01 X 2 

31 1602721 : R~ntA:r 

32 llLANK 

33 rrRx s PK 

34 1118093-01: Dl 

35 AI809l•01 

36 Al8091-0l 

37 AI8095-0l 

38 AIBO!I&-01 

39 AI809l-Ol 

<0 1118098-01 

41 1115522-01 

42 A1636t·01 

43 AI6361-0l 

44 AJ6363-0l 

C5 l\l6372-0l 

46 1116371-0l 

47 1116375-01 

48 AI6371-0l 

49 1116379-01 

50 1\16381-01 

51 1\16382-01 

52 REFMA1 

53 CCB 

5 4 CCV 

55 l602842:REfMAT 

56 BLIIIIK 

57 MTI\X SPK 

58 11113051-0l: Dl 

59 IIJ!3051-0l 

60 A/!3052-01 

61 IUI305l·Ol 

62 A!130SI- Ol 

63 AH305,-0l 

64 Afl3051-01 

6S R£FMA7 

66 CCB 

67 CCV 

8- 9-0Ja 

1602560/2721/1602842 

Lily 

0.00 

s..,.ple 8.-.ple 

W<dqht UDi ta 

0.5100 

o.sooo 

0 .5000 

0.5100 

0 .5000 

0.5000 

0 . 5000 

0.5100 

0.4900 

0. 4900 

0.5100 

0.5000 

0.5100 

0.5100 

0.5100 

o.sooo 

0.5100 

0.5000 

0.5100 

0.5000 

0.5000 

0.5100 

o. 5000 

0.5000 

0.5100 

0.5100 

0.5000 

0 .5000 

0.5100 

0.5000 

0.5000 

0.5000 

0 . 5100 

0.5000 

0. 5000 

0 . 5100 

o. 5100 

0. 5000 

0.5100 

0.5000 

0 .4900 

0 . 5000 

0.4900 

0.5100 

0. 4900 

0.5000 

0.5100 

Uaor 

Dilution 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

100 .0000 

50.0000 

50 . 0000 

50.0000 

50 .. 0000 

50.0000 

50.0000 

50.0000 

50.0000 

50. 0000 

50. 0000 

.50.0000 

50.0000 

50.0000 

50.0000 

50.0000 

50 . 0000 

50 . 0000 

50.0000 

50.0000 

50. 0000 

50 .0000 

50.0000 

50.0000 

50.0000 

50. 0000 

50.0000 

50.0000 

500. 0000 

500.0000 

500.0000 

50. 0000 

soo.oooo 

50.0000 

Page -21-

Remar ko 

VES 006270 
. (pO '{). 

tw 

7· Y'f 

EleDent: Aq Seq. No.: 71 

Sunple ID: 602842:RE~'l' 

Sampleconc 

mg/L 

0.302 

0.298 

0 . 300 

StndConc 

mg/L 

0 . 00308 

0.00303 

0 . 00306 

AS Loc.: 55 

Pea k 

Heigh t 

0. 0241 

0 .0237 

Time 

02:14: 32 

02:15:13 

Date: 2006 - 09- 03 

Peak 

Stored 

No 

No 

)M:o•-· - •-'!"--••• ,__rl=a=m= ~•==== ~--- =====- --

£1ement: Hg Seq. No.: 72 AS Loc . : 56 Date: 2008 -09-03 

S.mple. I D: B~NK 

-~---~ --------~---- -~-- -- --- -------~-- ------ --- ---- --- --- -- ------ ------ -- Repl SampleConc St.ndConc Peak Time Peak 

l mg/L mg/~ Height St.ored 

I -0.00078 - 0. 00001 0.0002 02:16: 47 11o 

2 - 0.00122 - 0.00001 0.0001 02:17 :29 No 

Moan: - 0.00100 - 0.00001 

==-=-====--•-===------====-=- --=•-•=-=-•---=-•--====e::o::d!r.==,..-•,.-•••- Ele11ent: Hg Seq. No . : 73 AS Loc.: 57 Date : 2008- 09- 03 

Sunple ID: MTRX SPK 

Repl SampleConc StndGonc Peak Time Peak 

I mg/L mg/1 Heigh t Stored 

I 1.02 0. 0104 0.0807 02:18:26 No 

! 1. 01 0.0103 0 . 0799 02: 19: 07 No 

Mean: 1.02 0 .0104 

EleDent : Hg Seq. No.: 74 AS Loc. : 58 Date: 2008- 09-03 

Sunple I D: AH3055-01 :Dl 

Repl SampleConc StndConc Peak Tirae Peak 

I mg/L mg/L Height Stored 

1 0 . 599 0 .00599 0 . 0465 02:20:43 No 

l 0.594 0 . 00594 0 . 0461 02:21:24 No ~an : 0.591 0. 00597 

Element: Hg Seq . No.: 75 AS Loc.: 59 oats: 2008 - 09- 03 

Sample ID: AH3055 -0l 

------------·y------------------------------------------------------------------------- !<epl 

' I 

2 

Mean: 

Sampl eConc 

mg/L 

0.693 

0 .678 

0.686 

StndConc 

l>IJ/L 

0 . 00679 

0.00665 

0.00672 

Peak 

Height 

0.0527 

0.0516 

t ime Peak 

S~o:red 

02:23:00 No 

02: 23:42 No 

- ,...,.,. ... ""'. - ====--===--==--... ·---- ........ -------=-c==--====-=------·---- ELement: Hg Saq. No.: 76 AS Loc.: 60 Data: 2008-09-03 

Saropl e ro: AH3052 - 0l 

Repl Sampl eConc StndConc Peak 'rime Peak 

I tllg/L 1ng/L Height Stored 

1 8.35 0. 00835 0.0648 02 :25:20 No 2 8 . 20 0.00820 0.0636 02:26: 02 No 

Naan: 8. 28 0.008~8 

El em•nt: Hg Seq. No. : 77 /\SLoe. : 61 Date: 2008 - 09- 03 

sample ID: AH3053-01 

Ropl SampleConc StndConc Pe-ak Time Peak 

I mg/L l<lg/L Hei ght Stored 

1 1.41. 0. 00726 0.0563 02: 27 : 40 No 

2 7.18 0.00704 0.0546 02: 28 : 22 No 

t-:ean: 7.29 o. 00715 

Page - 23-

VES 006271 
G· 'fY 

O·~ 

(( ;r( 

Element: llg Seq. No . : 78 l\S Loc.: 62 Date: 2008- 09- 03 

Sample ID: AH3054-01 

--------------------------------------------------------------------------------------- Rep!. SampleConc StndConc Peak Time Peak 

# mg/L . mg/L . Hei ght Stored 

1 6. 49 0.00662 0 .05l3 02:30: 00 No 

2 6.36 0 . 00649 0.0503 02:30: 42 No 

Met an: 6. 42 0.00655 

---===--IW--==,..._..,==:o:•o::oo==-•••----- = ==--===-:--=-·-= --.c::=:== Element: Hg Seq. No.: 79 l\S Loc. : 63 Date: 2008-09- 03 

Sample 10: AH3056-01 

---- -- -~---------------~- -- -------- -------------- ---- -~ -- ----- ------ Repl Sall\pl eConc StndConc P.eak Time Pea)f 

•• mg/L mg/t Height stored 

l 0. 589 0.00577 0. 04 48 02:32:21 No 

2 0.578 0. 00567 0. 04 40 02: 33:03 No 

Mean: 0.584 0.00572 

-----------------=----........ ····---==-====---=--·------= em~nt: Hg Seq. No.: 80 ~S Loc.: 64 Date: 2008- 09-03 

SU~ple ID: l\H3058- 01 tO~ .J. ' · -1.1 . 

-- ---- -- -- ----- ---- ---~ ------ --- -- ----------- ----- ----- -- ----- Repl SampleConc StndConc · Peale Time Peak 

J mg/L mg/L Height Stored 

l 0.889 0.00089 0.0071 02 :34 ; 35 No 

2 0.846 0.00085 0.0068 02:35:17 No 

Mean: 0.868 0.00087 

----=-----.. ----- --------------=--......,.====----... -.... ------ Element: Hg Seq. No .: 81 

sample !0: lU'FMAT 

R&pl -SampleConc StndConc 

t mg/L mg/L 

L 0 . 315 0 . 00322 

2 0.312 0.00318 

Mean: 0.314 0.00320 

Element: Hg Seq. No . : 82 

S~ple Io: AH3058·01 

Sampl eConc 

mg/ L 

0 . 636 

0.613 

0.624 

StndCooc 

mg/t 

0 . 0 0636 

0.00613 

0 .00624 

Element: Hg Seq . No.: 8 3 

Sample ID: CCB 

AS' Loc . : 65 oat@: 2008- 09- 03 

Peak time Paak 

He ight Stored 

0.0251 02 :36:49 No 

0.0248 02:37:31 No 

AS Loc . : 66 Date: 2008- 09-03 

Peak 

Height 

0 . 04 93 

0.0476 

Time Peak· 

·stored 

02:40:03 No 

02:40: 44 No 

AS toe.: 67 Date: 2008 - 09- 03 

... -----... ------... _ --.. 00 -00--------.--------......... -..,_ .. -...... ---. M ___ - - - - - ---- - --- _ ... ---- ......... _ ... ------.. -

Repl· Sample-Cone StndConc 

t mg/L mq/L 

l - 0 . 00003 - 0 . 00003 

2 - 0. 00003 - 0.00003 

M&an: - 0 . 00003 -0.00003 

Element: Hg Seq. No.: 84 

Sa11ple ID: CCV 

Repl 

t 

l 

2 

M;!an: 

Sampl eConc 

mg/L 

0 . 00384 

0.00386 

0 .00385 

StndConc 

mg/L 

0 .00384 

0.00386 

0.00385 

Pea le Tiltte 

Heiqht 

0 . 0000 02:42:15 

0. 0000. 02:42:56 

AS Loc.: 68 

Peak 

Height 

0. 0299 

0. 0301 

Time 

02: 43 : 53 

02: 44 :34 

Peak 

Stored 

No 

No 

Oate: 2008-09- 03 

Puk 

Stored 

No 

No 

Page -24-

VES 006272 
Perkin- Elmer AA»inLab : 2008- 09-03, 02 : 45:21 PH 

Page - 25-

VES 006273 
t . 

# Wartuho.-t HUmbtr. 1603354-

____ :J __ -

VES 006274 
• • 0 ... 6 

Regulation Water - RUSH ,.---· 

Repon l;fome: Wo:k Sheet· (Liquids ond s<>lid$) 1: 1603)58 

Assignmc~t ))aot: 

Assi&ned to: 

Tell Code: HG·I.. 1-ruld: 

Test o..aiption: TodeotnnlneHgby cv..y;_ Nov 16,2000 

MOL. <hanged from O.OOipPO>IO 

O.OOOippm. 

Job Sornple % 

Number Number D SamoleiD · ·F Moist 

M'ffiXSPK OC23C Al0220o04 

SPIJ<E OC23C 

·BLANK 

•A894939 AH.J046'01R HBTU.U4-R1 n·f 

'A894939 AH3047.01R llllTU·U4·R2 " -( 

'A894939 AH3048.01R IIBTU·U4·R3 ~·'"" ·<' . 

•A894?39 AH30~9-0IR LBTU-U4·RI I 

•A894939 AH.JOlO.OIR LBTU-U4-R2 

'A894939 AH.JOS 1.0 I R LBTU-U4-RJ 

' A894939 AH30S9.01R MS-U4-RJ 'A •• s 

•A894939 AH3060.01R MS·U4-R2 ... .n ' 1 

•A894939 AH.J061.01R· MSoU4·R3 )< 

•A89S312 AH4S76.()6R SCHF..t>ULE 23124 I 

AS%582 . A!0220-04R 0. MILES-WELL WATER 

A896582 A!0220-04R I MILES· WELL WA lER 

A896696 A10781.()6R DP· Tl·S 108/26108l 

A896n8 JJ0974-02R FIELDBLANIC 

A89679S JJ1368·09R SANJT ARY SEWER 

A89:7040, JJ2467.()lR •• ' 0 " 82149 .. 

JJ2410-02R 821S2 

A897040 ' JJ2472-0lR 82158 

A89'i040 AI2474.01R . 82168 

A897040 AI247S.OIR 82169 

A897049 AI2S22.Q2R :W2 .ALWOODSPO 

1'-· , ... 

...., 

Remrri<s: 

Sample$ elCb'a.Ctod by: 

Wt 

"' Flnal 

Vol Vol 

''1-f -1 

. .., - I 

..., ..1 

I h.,;.. .f 

n.r. ~~ 

h r . ./ J 

... O o 

• 

~- 0 ;;>· -

lnstrumento.licm perionned by: 

Calculations perfoo:nOO by: 0 

: ~ 

Validated by: 

,. 

.OF 

or I Expiry Test 

AF COni Il3te Deadline Qlrtria 

1-

' 0 

2 2008108128 2008109/03 17:00 

l 1008108123 l008109103 17:00 

2 2008108128 2008109/03 17:00 

.l 2008108128 2008109/03 17:00 

2 2008108123 2008109/03 17:00 

2 ' 2008108128 2008109/03 11:00 

I 2008108128 2008109/03 17:00 

... I 2008108128 2008109/03 17:00 

0 I 2008108128 2008109/03 17:00 

[:j ·I 2008/09102 2008109104 11:00 170 

I 2008109/03 2008/09104 18:00 

I 2008/09.'03 2008/09/04 18:()0 

I 2o0ai09102 2008109104 18:00 

1 2008/09102 2008109/04 18:00 

1 20o8/09104 2008109/08 18:00 

0 • . I 200&'09/03. 0 2008/09104..18:00 . 

I 200l!l09/03 2008109104 18:00 . 

1 2008109/03 200&'09/04 18:00 

I 2008109/03 2008109104 18:00 

I 2008/09/0) 2008/09/04 18:00 

I 2008109/03 :ioosto9I04 18:00 170 

~ 0 A-, 

I _..I 

Date: 

Date: 01

Date: -:I~L r 

Date: 

-

0 ___ 0 _ _ _____ _ 

VES 006275 
~. Ba Ojmc.Namc 

OI\894939Ml>CENSR lottmotlonal 

MA89SJ t 3A Christi'" Horl:<ons 

0 A8965tlC<R Well Wi>e Centre 

0AS96'79SA11J Slctlln& Trvd< Moau&c<urinr; 

MAa97C4alAS Rcsloo ofPcd (VS952) 

MA897049A . TownofOra.n.g.eviUe 

SurrM•t~<IS•Ikcs 

~mn c l'rcno tion Rtmarks nl 

' 

R~ulation Water - RUSH 

f : IISOJJSI 

Chrl:s Da.ldwln 

PAIJI.A STANUY 

Kon-Md l.al 

TUn Tboropson 

nu " .r ·" 

fs blm 

(31l)437·05Q9 •••RUSH,.• ICI'•HO. TOTAI.CHLORIDES, 

BTU & % 1\SH COlmlNT SUB TO 

PSC,REPUBUC. Prqjc<t N: 10002.0:!1 

NATIONAL: ENSR INI'ERNATI!)NAL 

(90l) 693-9267 MOH Info: tlallon Rcgio.,, Phnoe J 90}-825-6060, 

Fax I 90S·IlS-8797 Project N: CHRJS11AN 

HOIUZON PtlEI. S WELL (US£ MDL) 

NAn ONAL: Gtolfp bteweea JK..SK 

(90S) 983·9941 II'C Projoa 1: 08-00242 

(70S} 335-6070 IO'C f'lojocll: SCHEDULil OW 

NATIONAL: ACRJUM 

(519) 836-2493 Proj~ 1: 160960419 

NATIONAL: Stoo!K Couollloc L14. 

(S 19) 637-6130 

(90S} 5615-4621 llXCEEDENC£ NO'ITPlCA TION NOT REQUIREI: 

Projeet l : 82147-82170 

NATIONAL: R<81onofPoct 

(519) 941-.5303 rc 1 WW22<1008$l2/11tTI31'rojcct N: 

• CARDINAL WOODS SUBDIVISION WSL (USE 

MDL) 

NATIONAl.: Town or Or•ngn Uie. 

Method ""ike SnlkM Sam•le$ 

.... ·-

4 H...J-o--6-o- - · ~ . 'it. l· ., 0 0 •) t -/. ( J 

A ;; I . . ::;; . r 

- (> ·J.: -"> . ._.,., ·- .... ~.~ -~--;:- . .~:- .t. ~ )~ _,f{ ~ 3 ~ 1 

VES 006276 
·'. 

WOI"kSheet 16033581nsvument Sequences Page 1 

MTRXSPK 1. 111111111111111 MTRXSPK 

SPIKE 2. IIIIIIIIIIIIIB SPIKE 

BLANK 3. 111111110110 BLANK 

AH3048-01 •· IIIIIIIIIIIIIIIHIIIU HBTU-U4-R1 

AH3047-o1 s. IIIII II IIIfi~llll HBT\J-U4-R2 

AH304B-01 s. Ulllll llliiii aO~I HBTU·U4-R3 

AH3049-01 1. Ulllllflllllllllll!lllll LBTU-U.C-R1 

AH3050-01 a. l~lllll ll~mD III LBT\J-U4-R2 

AH3051-01 9. 11 111~ 11 ~11 11111 LBT\J-U4-R3 

AH3059-o1 10. IIUIIIIIIRIIIIIIIIIIIID " MS·U4-R1 

AH3060-01 11. llllllllmiiii RIIII ftiD I ~ MS-U4-R2 

AH3061 -01 12. IIIUIIIIIDIIIIIIIINIBIEI ?<. M.S-U4-R3 

AH4576·00 13. tlllntllllllmllllllllltn SCHEDULE 23124 

AJ0220-0<I ~14. 1111111111111111011111110 MiLE$-WELL WATER 

AJ022044:D1 1s. IIIIIIIUIIIIIIIIIIUIIRIIIIIIIIII MILE$-WELL WATER :DI 

AJ0781..()6 - 1s. IIJIIIIOIIIIIIIIIIHIEIIID DP-T2-5 (08126/08) 

AJ0974-02 11. ~IJIIIIU IJIIIIIIUII U FIELD BLANK 

AJ1~ 10. llllllllltiiiiiiiiiii!IIB SA-NI'fARY SEWER 

AJ2467..()2 19. 1011110111[1101111111 82149 

AJ2470-02 20. IBIIIJI.IHIIIIDUD 82152 

Al2472-02 21 . IIIIIIIUIIIUDIIIIliiD 82158 

AJ2474-01 22. llllllllllllBII!IIIU 82168 

Al2475-01 23. 11111111111111111111111 82169 

A12522-02 24 IOIIIIItllmiiDIIIIIUIB CW2-CAROINAL WOODS POE 

VES 006277 
MIIOCttn ~ !ftc .. CAM 'CO.oofWI '• ,.,, 

Prep Bitch Reagent Tracking Record Worbheai iJ - 1603 358 

YlllumeluU 

SunogUIS4>ikeiO!utioM Solution 10 I B!~-$p k MS Samplu 

ICPMS 

ICAP 

GFAAS 

Hg ~ 0517.5mL 0517.5ml 20 

' 

Solvent Supplier Lot No. Spiked by: 

HNO, Fisher 307292 2008-08·29 /c... - l-J NH20H~CL Fisher 72276 ' 200-09.02 Spiking WHnauld by: 

MaC! Fisher 67655 200.0S.02 

H2S04 Fisher 108003 ' 2008··08·29 Splko Oatt (yyyy/mmldd) 

K2S208 Fisher 75812 2008··09.02 2008·>09.03 

KMN04 Fisher SC6354483 2008··08·19 

Comments 

- VES 006278 
·' ; .... 

I Data 1- lA"bl'l.a nd.Wet Chern . 

1..1 r. , 

I 

' 10 verified aaainst ~::era: IS Dlklnil I to ' IV1XI 

• mairix $1llke ~ os wen as 

llnltial aatnole I and I flna1 VOlUme, Cl""'fy 

I extrad 

If I anv I dHuGon cloa~v 

~ 

~ >IOL~ s~records IS01111>fo s and 

f reaoentlfackina recotd 1 an~ lgnecl 

I 

!Dato: 

, and 

~ 'Ch::~~ee! 'crKetia 

Svslem ho<:i<s 

h~ al and ' Checks meet 

ISamola VIlli I aaalns1 Tabla 

lelhod~ meels t Clile~ 

foiierooce Material 1 moola 

:on1rc1 ~ . Trend 1 

erttona 

~~ ;;a: \IP < •-'"ke ' crileria 

1 above · """"" • I an lraCtlnQ rec:onl an~ \'G111iod · 

I hioh 10\lel i cfleckad 

;I 

aw ' enlansd in UMS 

; Given 

I ISamota Proo sedion labovel 

I 

lbv: 

/.\ ,r,~ .... , .:. 

ll.~ l ••• ' 

~ samolaresul 

~ataandQC lin LIMS 

or 

land 

' reloo1; lin flle 

f daled. 

land lwltl>ln ~ 

.I I II 

l--61· loate: 

~ 

-c- v' 

--,;;:;;r • I . ~ 

'<. .'j-"11 

.f A 80:: 7i<r • oo.l . G/ I A-LJ '?or.: 

''~ ,.,J .. 1 •• • d • lT 

I vas na nla 

1--

VES 006279 
\ \ 

CEt A C Hg Analysis Report 

Analyst: ll:onapath 

Worksheet rue: C:\Program Files\QuickTrue\Worbheetsl8·9·4a.wsz 

DateStart<d : 2008/09/04 12:54:15 PM 

Comtnent: 

Results 

S"'"f,)le N~ Type COOe ..- %RSO Flags WI • Vol. 

(ppb) 

Clllil>ratiM 8Jod< STO 0.000 70 3.03 1.00 1.00 

R~s 67.4 72.$ 70.1 70.1 

S1>1)(13rd " STO 0.100 357 .. 0.64 1.00 1.00 

Rep<Oc:ales 357.7 359.6 354.9 354.9 

St3r.ctarct#2 STO 0.200 $73 1.10 1.00 1.00 

l'(epJ;cale$ &&2.0 &74.9 679.2 674.3 

Standard 113 STD o.soo 1$04 0.56 • 1.00 1.00 

R.epl~ 1592.2 1610.0 1$1 1.4 160 .~ 

Ston<t3rd #4 STD 1.000 ~36 0.87 . 1.00 1.00 

Rtplicaces 3095.4 3146.8 3158.5 3144.0 

Stondard 115 STO 2.000 01207 0.90 1.00 1.00 

Repiiatas 6128.1 6225.7 5254.0 =· 

StaOOal'd #6 STD 5.000 155n 0.75 t.OO 1.00 

Repllc<te$ 15539.8 15T3& 1 ~.4 15627.6 

Clli brolion 15,000. 

• 

Equation: A·= :is.876 + 312t.923C • ~ 10.000 

Cor"*ation: 0.99996 ls 

SEE: 45.3041 t 5,000 

FlaOf: 0 

0 3 4 5 

COO<enlratbn (ppb) 

ICV· LOW UNK 0.250 817 1.32 1.00 1.00 

~ce:tei 8 10.$ 62<!.5 829.1 805.6 

tCV·A UNK 0.983 3105 0.31 1.00 1.00 

Reo<lcates 3075.6 3118.3 313<.1 3094.0 

ICV-B IJNK 3.000 12215 0.81 1.00 t.OO 

Rep! cates 12103.1 12m.• 12317.6 12162..4 

~008/09/04 7:23:55 PM 8-9-4a .. wsz Page I 

VES 006280 
SampltName Type Cone pAl>• %1\SD Flags Wl. Vol. 

(J>pb) 

CCV CCV 0.992 3132 0.90 too 1.00 

R&plca!e$ 3092.6 3131.4 3152.9 3152.4· 

CCB cce 0.012 73 2.16 1.00 1.00 

Ro~ 69,8 73.9 74.2 72.3 

SPIKE WS#16J)3789 liNK 1.430 4505 1.05 1.00 1.00 

R.-s 4450.5 4517.2 4481l.6 4563.1 

BLANK UNK 0.001 39 6.70 1.00 1.00 

ROJ)RcoieS 35.1 40.5 40.5 39.7 

MTRXSPI< UNK 1.a20 $732 1.03 1.00 1.00 

RepliCates 5651.6 5725.2 5765.1 5785.5 

Al8661-05;01 UNK 0.012 74 3.77. 1.00 1.00 

RepHC3Jes 70.9 72.9 72.9. 77.4 

Al8661.Q6 UNK 0.009 63 4,16 1.00 1.00 

Replicat.es 85.0 64.8 59.7 61.5 

MTRX SPK UNK 1.720 5397 1.79 1.00 1.00 

Repncates 5278.5 5366.9 5436.9 5504.5 

A.J4304-01 UNK 0.660 173 0.80 .50 1.50 

. fl.epl\eJtes 171.3 174.5 .o~ o 173.1 

SPIKY' WS!f1!038S8 liNK 1.310 4128 2.07 1.00 1.00 

qr Reptlcotes 4023.0 4098.3 4174 . 9 4216.2 

BlANK liNK . 0.021 101 2m 1.00 1.00 

t-1~ """11"" .. 104.1 100.3 100.5 99.• 

MTRX.SPK UNI< 1.790 s6ia 1.79 1.00 1.00 

r-z.-. 'j. RepUc:ot .. 54a7.7 M83.3 5661.3 5720.4 ~ c·-:r<>! 

1\10936-02:01 liNK 0.701 2225 3.07 1.00 1.00 

I Ropicates 2284.6 2218.0 2192.6 2143.7 

.-> o-tiJ() 1-

Al0936-02 UNK 0.766 :1428 2.49 1.00 1.00 

Replicates 2493.0 2.446,1 2426.6 2347.8 

-::>o·<C<>C gAH5757·01 liNK 0.020 97 2.15 1.00 1.00 

N.)> ROQI!c;ate$ 9Q.5 95.7 99.9 95.4 

AH5843-11 UNK 0.033 138 4.35 1.0-3 1.00 

~Replicates 129.2 140.4 140.7 \42.2 

Al0453-07 liNK 0.091 320 5.11 1.00 1.00 

~<Ol<a <$ 297.5 318,0 329.8 334. 1 

20011109/04 7:23:55 PM 8-9-4a.wsz Page 2 

~---- -----'------- ---· .. ·-·-- .. ---·--- - - - -

VES 006281 
. . 

SaMple Hame Type Cone ...- %RSD Fr..gs Wt. Vol • 

(ppb) 

~ UN!( 1.680 $267 4.A1 1.00 1.00 

~ 5124.0 5090.6 1 -.v 

_-:;:> 0• c:'o I'=\- UHK 0.081 2M 2.01 1.00 1.00 

T'/_5) R.-s 2798 2118.8 292.3 2910 

AJ078().06 ,__ 0.021 100 3.72 1.00 1.00 

f}P Re1)broo 104.3 100JI ~~e. a 96.5 

AIO!IJ4.(J2 UNK 1.010 3182 Z-62 1.00 1.00 

Rcplates l2A50 3229.8 311111.3 30!2.0 

-? O·eo l 

A!0937-o2 UNK 0.586 186$ 1.25 1.00 1.00 

Roplcales 1872.4 1882.1 1&74.0 1830.2 

">0•000" 

Al2U9-06 UNK 0.012 73 2.86 . 1.00 1.00 

r5> Roplcaleo TOA 72.8 74.& 75.0 

At2100.06 UNK 0.014 81 3.07 1.00 1.00 

@> Replicates n.o &3.0 82.4 79.9 

Al2153-00 UNK 0.017 89 3.&0 1.00 1.00 

~lea 83.8 91.7 81l.O 89.1 

A12"l8.06 UNK 0.018 92 3.30 1.00 1.00 

cj5) Repli(ates 91.0 95.9 91.8 88.7 

A12466·02 UNI( 0.021 103 3.03 1.00 1.00 

"'P'Roplatel 98.1 103.5 103.5 105.3 

Al2~.()2 1M< 0.023 107 2JJ6 1.00 1.00 

('I Ropllca1es 104.6 108.0 108.9 104.9 

At247\-01 IJNK 0.023 107 4.53 1.00 1.00 

riS>R ... Icolel 101.1 IOU 112.4 109.1 

CCV liM< 1.000 3171 t,.ro 1.00 1.00 

vR-1es 3115.2 3161.2 3111i.3 .12111.6 

cca 4 ... IJNK 0.011 89 1.98 1.QO 1.00 

1111.4 70.0 87.2 87.5 

~~ ...... t.t.'!< 0.018 92 4.62 \.00 100 

87. 1 01.2 03.4 07.3 

A12476-02. UNK 0.020 99 2.15 1.00 t.OG 

~P.opb, .. 98.7 95 8 1000 100.6 

A\2489-02 UNK 0.031 131 2.70 \,00 1.00 "!Y(lfAic>l .. \28.4 133.3 13<L.4 13 1.8 

200810911>4 7:2J:Sl PM &-9-4a.wsz Poge3 

VES 006282 
' 

Sample- Typo CCno ...- %RSD Fblg$ Wt. Vol, 

(ppb) 

~~~~78-<16 lH( 0.()24 110 1.88 1.00 1.00 

tfJ Repllr;ateo 112.4 IOU 107.1 110.8 

SPIKE WSI16<»35e 1.0« 1.340 Q)< 0.88 1.00 1.00 

ft!l/ /-...,. 4158.9 <193.5 4211.2 4:140.4 

l>lanlc ~ 0.()52 191 1.39 1.00 1.00 

r'!J> R<t>bleS I GilA 200.7 194. 1 186.7 

"""' £Pic UNK 1.350 • 237 1.<06 1.00 1.00 

I (/ 1'/ RepMat;,. 4158.4 •m.e ~rT4.1 4294.9 - O· ~"'\ 

oi02-1 · UNK 0.009 64 C,Sol 1.00 1.00 

'9 Riplleotos 603 65.2 117.2 8•U 

oi0220.Q.C UNK 0.011 TO 4.01 1.00 1.00 

0) Replicates 156.8 13.0 71.8 G9.3 

eh~ FILTEREO lJNK O<R 1873a 1.11 0 .50 1.50 

-~"S;~83 8 14700.7 1884S.3 18941.5 

ah3047.01FILTERED UNK 15.900 3345 1.38 .50 7.60 

RepHcal.. 3262.2 3339.4 3362.8 3377.3 Jw.; ;. PL..!:> D• "0 )..',)" 

-"> o · 01:S: (' \ -f.•l/t;;;.....J 'u. -~ .• , •y 

3h3048-01 OILY FilTERED d"' ~ UNK 78.500 1124 4,33 1.00 225.00 

RfPIIellll 1100.8 1073.2 1138.3 11ti5.6 '\')L-~ (). 7> 2. ·>..S 

?> 0· 1?1- e-.s;- a~9-01 UN!< .0.005 20 30.66 1.00 1.00 

r'-. ~ic:stes 12.2 18.2 2U 2U 

ah3()5Q.01 UNK 0.1'77 590 1.68 1.00 1.00 

Replcalot S82.3 580.3 004.2 565.4 

--;, "' • .0 <!) 0 2._ 

ah3051-01 UNK .0.001 34 14.28 1,00 1.00 

N$> Replta"" %7.8 3U JU 39.5 

al\305!141 UNK O<R c951l6 1.08 0 1.00 5000.CO 

~ ... 48764,1 48528.2 49!1:1.9.8 4aao5.2 

BLK 

~~~ UNK .0.053 •t31 ~ 1.00 100 

~, .. -120 .• ·129,1 ·129.7 ·143.9 

ai>3Q60.01 UNX OIR 51¥70 1,1)3 0 '.00 5000.00 

Roplc:l ... 51233.0 5193JA !12253.8 !WOO. a 

till< LINK 4 .020 ·21 7.75 1.00 1.00 

R~lcatel: ·281 ·238 ·28.2 ·26.8 

CCV UNK 1.030 3286 0.30 1.00 1.00 

Replic4te• 3262.3 3275.2 3274. 1 3~.4 

~ 

2008/09/04 7:13:55 Pill 8·9-'la.wsz Pogc4 

VES 006283 
: 

Sample' .Name Type Cone .....,. •!,RSO Flags: Wl Vol. 

(ppb) 

CCB ~NK 0.1)13 n 3.76 1.00 1.00 

ReplbJ!e s 78.2 80.6 ni. 73.6 

..... 7(>(>6 UNK 0.06'7 244 8.95 1.00 1.00 

~ Replicai<U 263.1 259.5 234.4 2 17.4 

Al0781.()6 UNK 0.018 9 1 ' 1,72 1.00 1.00 

r§:> Rllplicat&s 90.0 &1.3 90.1 93.4 

AJ0974·02 UHK 0.014 78 3.73 1.00 1.00 

sl'9 Rop!ICIIe$ 75.8 80.3 81.4 75.9 

AJ1368-09 UNK 0.080 266 2.n 1.00 1.00 

opRepll-. 274.6 287.2 289.1 292.9 

Al2467·02 VNK 0.042 166 1.95 1.00 1.00 

rj5) R.,cic;<eo '167.! 161.5 164.7 169.0 

AJ2470.02 UNK 0. ~0 473 1.64 1.00 1.00 

Rep6c:!es 463.8 471.0 481.6 477.4 

-::::> "''"'., .o I 

AI2472.Q2 UNK 0.077 276 2.30 1.00 1.00 

(\jt> R~pl ca!e$ 268.3 . 273.0 282.6 278.9 

. Al24 7 <IL-01 UNK 0.136 461 0.76 1.00 1.00 

Repliciea 456.1 461.7 463.8 462.9 

--?:> 0 • D "' o { 

AI247S.01 UNK ,,130 12915 uo 1.00 1.00 

Repli<;al"' 12698.7 12909.2 13023.8 13028.9 

:.> 

AJ2522.Q2 

0 ' OE>-:+ I 

UNK ..0.003 25 17.42 1.00 1.00 

t:JD Replicates 28.1 28.6 23.8 1ii.J 

ah3046-0; · liNk . 157.000 . 2220 1.42 1.00 22MO' 

Rel)l C~<eS :nn.8 2218.3 2235.4 2250.7 <!:> l-,::, o·o ·u ... r -

;1).305~ 0' 1>"1-0 

UNK ()IR 15769 1.13 0 1.00 0000.00 

Rep1icakJs 15524.4 15759.7 15862.1 15930.5 

ah3000-01 IJtiK OIR 16390 1.30 0 1.00 0000.00 

Replicates 16102.9 16357.2 16524.4 16578.4 

all806Hl1 UNK 0/R 17609 1.12 0 1.00 0000.00 

Repll~es 11345.7 17577.3 17718.3 17793.3 

CCV UNK 1.030 3253 0.58 1.00 1.00 

Repllcuo 3226.4 3252.3 3282.0 3289.7 

,/ 

CCB UNK 0.011 11 3.14 1.00 1.00 

~es 74.3 71.7 69.6 ' 69.6 

2008109/04 7:l3:SS PM 8·9·4•.ws-t P•s• S 

VES 006284 
: 

Sampat NamC! Type CCnc ,.AI>• %RSD Flags Wl V<A. 

(ppb) 

SPIKE W$6110402A UNK 1.300 4104 1.4\ 1.00 1.00 

. qg--1 ~plt;Uet 4029.0 <1090.0 4137.1 4160.4 

9lANl< UNK 0.003 45 4.23 1.00 1.00 

tN.9 Repbtot 44.& 4&.2 48.1 44.1 

MmXSPk UNK 1.360 4288 1.6 1: 1.00 1.00 

roof. Roplcoles 419U •ms 4324.5 4351.8 -0· 17'2-~ 

AJA82S.08:01 UNl< 0.()31 132 4 ,50 1.00 1.00 

~ Aepibt .. 136.7 1».8 133.8 123.2 

A~ UNI< 0.027 120 3.71 1.00 1.00 

<:1> F<epblH 125.A 121.0 117.7 115.1 

A~~ UNI( 0.059 219 2.02 1.00 1.00 

cp Replielt .. 219.3 221.3 223.8 213.4 

AG4729-® UNK 0 .006 55 6.99 1.00 1.00 

fj) Replicab!s ~.8 51.2 58.3 58.9 

AH3612.Q6 UNK 0 .009 55 6.37 1.00 1,00 

I)P Replcates 63.1 1)0,8 70.4 64.0 

AH9357·13 UNK 0.009 64 3.80 1.00 1.00 

c:P ReDIIitatca 80.5 63.9 00.2 6<.9 

AH941g.11 UNK 0.033 155 2.78 1.00 1,00 

~ Replicates 160.0 154.6 161.1 155.5 

AIOA~7 UNK O.Q35 145 1.99 1.00 1.00 

-N) Rljlll"'l<s 143.3 146.0 149.0 142.7 

AI045648 UNK 0.08< 291 1.73 1.00 1.00 

N;:> ~'"''" 292.1 302.4 301. I 293.9 

CCII ._ 0.995 3144 0.87 t:OO 1.00 

vRcpfi"" .. 3104.8 a1 ... e 3 105.4 3180. 1 

CC8 IH< 0.013 75 2.42 1,00 1.00 

/Replb ... 7U 76.8 74.2 76..2 

AI0450-01 UNK 0.014 19 2.05 100 1.00 

~ RotlllcaiU 81.2 74.7 n.• 71.3 

AI0461-08 UNl< 0.006 51 4.70 tOO 1.00 

c{) Repltatts :18.2 61.3 64.5 58.6 

04~-07 UNK 0.036 156 2.29 1.00 1.00 

~ Ropllc"IH 154.9 m.o tGO.S 152.0 

2008109/04 1:2l:lS I'M S-9-4a.wsz. P•gc6 

VES 006285 
' . 

• S.mpl~ Niltne Type Cone ..- %RSO Flag; WI. Vol. 

(Wb) 

AI0939·02 UNK 4 .800 15020 4.02 1.00 1.00 

• RGI)Iica~Bcs 15414.5 15354.8 1~185 3 14128.5 

0941 ~ 0 010\tg-- ON!< 0.784 2485 2.49 1.00 >.00 

Repjlca»s 2539.8. 2509.9 2492.~ 2398.9 

--~ e v o~o · coog--- UNK 0.022 105 4.72 1.00 1.00 1110975-02 

(\!> Repllclres 105.2 108.7 109.0 98.3 

Al2392.Q9 UNK 0.021 100 4.58 1.00 1.00 

·tp R~pllcabS 94.9 98.6 105.9 99.7 

AJ 46~2 UI!K 0.026 116 0.95 1.00 1.00 

<9 Rep~ 115.9 117.2 114.6 115.3 

AJ246S.02 UNK 0.024 110 4.12 1.00 1.00 

119 ROQi ca'eS 105.6 107.7 113.4 115.2 

Al4824-06 UNK 0.040 161 1.01 1.00 ·1.00 

t'!/Repll-s 159.8 162.9 162.5 159.9 

Al586S.01 UNK 0.022 100 3.50 1.00 1.00 

/'f>Reptlc!!c.s 102.1 101.3 109.2 106;1 

!-15872-01 UNK .1 30 12937 1.29 1.00 1.00 

Re~"" 12898.7 13010.5 13000.1 12960-4 

~ 0 Clf\ 

AH3059-0 1 UNK 11200000.000 10360 1.22 1.00 5000.00 

Repllc;O.cs 10191.0 10341.2 10429.9 10477.8 

~ ll:? q"' 

UNK 11600000.000 10782 1.13 1.00 5000.00 t>L :::. 

Repr.ates 106Ge..O 10787.1 10873.3 10660.5 h t!JPd I .X.. 

- 7 "'/:,•0 3. 3, fS. OP,O 

AH3061.01 ON!< 1250000o.OOO 11624 r.o> 1.00 5000.00 

~licatM 11455.1 11632.3 t 1712.5 1 1695.8 

,.....-- . : 331·5"" ~ 12910 

SPIKE UNK 1.320 41119 0.82 1.00 1.00 

Rep!IO>tes 4110.2 4173.5 4168.3 4164.3 

CCV UNl< 0.986 3115 1.0 1 1.00 1.00· 

Repfl~fes. 3070.4 31'17.3 3134.3 3139.6 

CCB liNK 0.007 57 3.80 1.00 1.00 

Replical~ 57.7 59.7 54 ~ 57.~ 

, -> lr:rvO (t7VO 

e::- ;;·r rJ · 33 r!{'ooo 0 ·> - ) I J,..... ~ ()•"' -;:;::;'f ·[ n--

Page 7 Z008109/04 7:23;55 PM 0 . ~ --? ?- ::J·· 8·9-4a. vm 

VES 006286 
Method 6010 -Test Method for Total 

Metals by ICP 

Maxxam Analytics Inc. 

6740 Campobello Rd. 

Mississauga, Ontario, Canada 

LSN2L8 

1-800-668-0639 

www.maxxamanalytics.com 

VES 006287 
Unique Calibration Standards I. D. table for ICP-5 (Axial) 

(Standards prepared in 2% HN03) 

General J.D. Unique 1.0. 

BLANK /ICB/ CCB ICP-WG-0834 

STD · A ICP·WC-0835 

. STD • B ICP-WC-Q836 

CAL-15KNa ICP-WC-Q833 

Hi-Kna ICP·W0:0856 

ICV /CCV ICP-WQ-0858 

ICS-AB ICP-WQ-0841 

CR) ICP-WQ-0852 

u Buffer ICP-WQ-0857 . 

Analys\ InitialS: kc. 

Date: 'UJ(i~ At /] . ' 

Maxxam ·Analytics Inc. 

CAM FCD-00279/1 

Page 1 of1 

. 

VES 006288 
AutoSampler Report Table : SEPT03A 09/03/06 05:25: 21 PH 

Autosampler Type: TYPE TJA 

QC Positions: 13/19 # Sets: 1 

Table Name: SEPT03A 

Sample Positions: 42/192 

Rinse Station loca t ion is rack - 1 , pos . - 1. 

--- Racks ---

Rack# Type ua·age · IIPos Left Anal.yses I Pos 

------ -------------- -- ~--- ------------ --------- -------.----- 1 Aux. (L) Rack STD/QC/BLANK 13 20 ·2 Sainple (16mm) Samples 0 1 

3 Sample {16mml samples 0 1 

4 Sample ( 16tnm) Samples 0 1 

5 Sample (16mm) Sampl e s 42 1 

page 1 

Sample Se ts 

Set# Type Prepa re? Description Method IIPos· Rack# StartPos 

1 Normal No maxxam 

-- - Pr eparation I nfo ---

Set# Uptake Uptake#2 Final 

No Sampl es Prepared . 

Ra ck #1 

Pos Row Col Sample Name 

-------------------- l 1 1 NONE 

2 l 2 knahi 15 

3 l 3 STO· A4 1 4 STD-B 

5 1 5 CAL-BLK 

6 l 6 HCL 

(7 ... 19 Not Used) 

Rack #2 

Pos Row Col Sample Name 

-------------------- 1 1 l 1CVAX 

2 1 2 lCB 

3 1 3 CRI 

4 1 4 ICSABAX 

5 1 5 HI KNA 

6 1 6 1602743:BLANK:l.l1 

7 1 7 1602743:SPIKE:1.11 

8 l 8 1602743 ITRX SPK:10 

9 1 9 1602743:AH3049:DUP 

10 1 10 l 602743 :AH3049: 10 

11 l 11 l602743:AH3049:DUP 

12 1 12 1602743 :AH3049:100 

13 i l l602743 :AH3046:10 

14 2 2 1602743 : AH3046 : 100 

15 2 3 l602743 :AH3047: 10 

PSC34 150 2 1 

Dil. Factor 

Set # #Used Type 

------------ · NA- l Standard 

-NA- 1 St andard 

· NA- l Standard 

-NA- 1 Standard 

-NA- l Standard 

· NA- 1 Qc Standard 

Set II #Used Type 

------------ 1 · NA- sample 

l -NA- Sample· 

l -NA· Sample 

1 - NA - Sampl e 

l -NA- Sampl e 

l -NA- Sample 

1 -NA- Sample 

1 -NA- Sample 

l -NA- Sample 

l -NA- Sample 

1 - NA- Sample 

l · NA• Sample 

1 - NA- Sample 

1 -NA- Sample 

l -NA- Sampl e 

VES 006289 
.. AutoSampler Report Table : SEPT03A 09/03/08 05 :25:21 PM page 2 

Rack #2 

Pos Row Col Sample Name set # #Use d Type 

-- --- ~--- ----------.. - 16 2 4 l6027 43 :AH3 047 : 100 1 -NA- Sample 

17 2 5 1 602743 :AH3048: 10 1 -NA- Sample 

18 2 6 1602743 :AH3048:100 1 - NA- Sample 

19 2 7 1602743:AH3050 : 10 1 - NA- Sample 

20 2 8 1602743 :AH3050 : 100 1 - NA- Sample 

21 2 9 16027 43 :AH30Si : 10 1 · NA- Sample 

22 2 10 1602743:AH30Sl: l 0 0 l -NA- Sample 

23 2 ll 1 602743 : AH3048: 100 0 l -NA· Sampl e 

2 4 2 12 CCV 1 . - NA- Sample 

2 5' 3 1 CCB 1 -NA- Sample 

26 3 2 1 6 02838 : BLANK : l00 1 -NA- Sample 

27 3 3 1 602838:RBFMAT : 98 1 · NA- Sample 

28 3 4 1 602838:RBFMAT:980 1 -NA- Sample 

29 3 5 1 602838 : MTRX SPK: 96 1 -NA- Sample 

30 3 6 1602 838:AH3058:DUP 1 -NA- Sample 

31 3 ? 1602838 : AH3058:96 1 -NA- Sample 

32 3 8 1602838 :AH3055:98 1 · NA- Sample 

33 3 9 l602838 :AH3056: 10 4 1 -NA· Sample 

34 3 10 CCV 1 -NA- Sample 

35 3 11 CCB 1 · NA- Sample 

3 6 3 12 1602838:AH3052: 104 1 -NA- Sample 

37 4 1 1602838 :AH3052 :1040 1 -NA- sample 

38 4' 2 1602838 :AH3052:10400 1 - NA· Sample · 

39 4 3 1602838:AH3053:104 1 -NA- Sampl e 

40 4 4 16b2838 :AH3 053 : 1040 1 -NA- Sampl e 

4 1 4 5 1602838:AH3053 : l0400 1 -NA- sample 

42 4 6 1602838 :AH3054:100 l - NA- Sample 

43 4 7 1602838 :AH3054 : 1000 l · NA- Sample 

44 4 8 l602838 :AH3054 :10000 1 - NA- Sample 

45 4 9 l602838 :RBFMAT:98 1 -NA- Sample 

4'6 4 10 CCV 1 -NA· Sampl e 

47 4 ll CCB 1 -NA- sample 

48 4 12 1602946:8~:0.2 1 NA ·samJ)le 

Rack #3 

Pos Row Col Sample Name Se t # #Used Type 

-------------------- ------------ 1 1 1 1 602946:REFMAT:O.l9 l -NA- sample 

2 1 2 1602946 : MTRX SPK: 0. 2 1 · NA- Sample 

3 1 3 1 60 2946 :AH9649:DUP 1 -NA- Sample 

4 1 4 1602946 :AH9649 :0 .19 1 - NA· Sample 

5 l 5 1 602946:AHJ403:0.2 1 · NA- sa·mple · 

6 1 6 1602946 : AH7404:0.2 1 -NA· Sample 

7 1 7 .1 602946 :AH8 360 : 0.19 l -NA- Sample 

8 1 8 1602946:AH8361:0.2 1 · NA- Sampl e 

9 1 9 1602946 :AH9648:0 .2 1 -NA- Sampl e 

10 1 10 1602946:AH9650:0 . 2 1 ' 

-NA- sample 

11 1 11 1602946:AH965l : 0 .2 1 -NA· Sample 

12 l 12 CCV 1 · NA- Sample 

13 2 l CCB 1 -NA· Sampl e 

14 2 2 1602946 :AH9652 :.0 . 2 l -NA- Sample 

15 2 3 1602946 :AH9653 :0 . 1 9 l - NA- Samp~e 

VES 006290 
AutoSamp l er Report Table: SEPT03A 09/03/08 05:25:21 PM page 3 

Rack # 3 

Pos Row Col Sample Name Set It #Used Type 

-------------------- ------------ 16 2 4 1602946:AH9654 : 0 .2 1 -NA- Sample 

17 2 5 1602946:AH9655 : 0 . 2 1 - NA - Sample 

18 2 6 160294 6 :AH9 656:0.19 1 -NA- Sample 

19 2 1 1602946 :AH9 6 57 :0. 2 1 - NA- Sample 

20 2 8 1 602946 :Al6192 : 0.2 1 -NA- Sampl e 

21 2 9 1 602946:AI 6"193 :0.19 1 - NA- Sampl e 

22 2 1 0 1 60294 6:A.I622l:0.19 1 -NA- Sample 

23 2 11 1602946: A.I6222:0. 19 1 -NA- sample 

2 4 2 12 l 602946:AI6223:0.19 1 -NA- Sample 

25 3 l 1602946 :AI6825:0. 1 9 l - NA- Sampl e 

26 3 2 CCV l - NA- Sample 

27 3 3 CCB l - NA - Sample 

28 3 4 15997 04 :BLANK : 50 l - NA- Sample 

29 3 5 1599704:REAGBL: 50 l -NA- Sample 

30 3 6 1599704 : SPIKE:DUP 1 - NA- Sample 

3 1 3 7 1599704:SPIKE:50 1 - NA- sampl e 

32 3 · 8 1599704:AH2002:SO 1 ··NA- Sample 

33 3 . 9 1599704: AH2003 : 50 l - NA- Sample 

34 3 10 l 599704 :AH2 004 : 50 l -NA- Sampl e 

35 3 ll 1599704 :AH2005 : 50 l - NA- Sampl e 

36 3 12 1 599704:AH2006:50 1 - NA- Sampl e 

37 4 l l599704:AH2007:50 1 -NA- Sampl e 

38 4 2 1599704:AH2008:50 1 -NA- Sample 

39 4 3 1599704 :AH200.9 : 50 1 - NA- Sample 

40 4 4 CCV 1 - NA- Sample 

4 1 4 5 CCB 1 -NA- Sample 

42 4 6 1599704:AH2010:50 1 -NA- Sample 

43 4 7 1 59 9704:AH2011:50 1 " - NA- Sample 

44 4 8 1599704:AH2012: 5 0 1 -NA- Sample 

45 4 9 l 5997 04:AH20l3:50 1 -NA- Sample 

46 4 10 1599704 :AH2014:50 l -NA- Sample 

47 4 u 59~7Q4 20l5 50 1 -NA- SamP,le 

48 4 12 1599704: AH2.016: 50 l - NA- Sample 

Rack #4 

Pes Row Col Sample Name Set # #Used Type 

-------------------- _________ _ .. _ 

l l l 1599704:AH2017:50 l -NA- Sample 

2 1 2 1599704:AH2018:50 l -NA- Sampl e 

3 1 3 1599704: AH20l9 : 50 1 - NA- Sample 

4 1 4 1599704:AH2020: 50 1 - NA- Sample 

5 1 5 l599704: AH2021 : 50 1 -NA - sample. 

6 1 6 CCV l - NA·- Sample 

7 1 7 CCB l - NA- Sample 

8 1 8 l599707 :BLANK: 50 1 - NA- Sample 

9 1 9 l599707 :REAGBL:50 1 -NA- Sample 

10 l 10 159970 7 : SPIKE :DUP l - NA- Sample 

11 1 11 l 599707:SPIKE : 50 1 "NA- Sampl e 

12 1 12 l 599707:AH2022 :50 1 - NA- Sample 

1 3 2 1 1599707:AH2023 : 50 l. - NA- Sample 

14 2 2 1 599707:AH2024 : 50 l - NA- Sample 

1 5 2 3 1599707:AH2 025:50 l -NA- Sample 

VES 006291 
AutoSampler Report Table: SEPT03A 09/03/08 05:25:21 PM page 4 

Rack 114 

Pos Row Col Sample Name Set: ff #Used Type 

-------------------- --------·--- 16 2 4 1599707:AH2026:50 1 -NA· Sample 

17 2 5 l599707 :AH2027:50 1 · NA· Sample 

18 2 6 1599707:AH2028:50 1 -NA- Sample 

19 2 7 CCV 1 · NA· sample 

20 2 8 CCB l -NA- Sample 

21 2 9 1599707 :AH2029:50 1 -NA- Sample 

22 2 10 1599707:AH2030:50 1 -NA- Sample 

23 2 11 l599707:AH2031:50 1 -NA· Sample 

24 2 12 1599707:AH2032:50 1 -NA- Sample 

25 3 1 1599707:AH2033:50 l -NA- Sample 

26 3 2 1599707:AH2034:50 1 -NA- Sample 

27 3 3 1599707:A82035:50 1 -NA- Sample 

28 3 4 1599707:AH2036:50 1 -NA- Sample 

29 3 5 l599707:AH2037:50 1 -NA- Sample 

30 3 6 15997 07 :AH2038:50 1 - NA- Sample 

31 3 7 1599707:AH2039:50 1 -NA- sample 

32 3 8 CCV 1 -.NA- Sample 

33 3 9 CCB 1 ·NA- Sample 

34 3 10 ( empty ) l -NA- -NA35 3 11 ( empty ) 1 -NA- -NA36 3. 12 ( empty ) 1 -NA- - NA37 4 l ( empty ) 1 - NA- -NA38 4 2 ( empty ) 1 -NA- - NA39 4 3 ( empty ) 1 - NA· -NA40 4 4 ( empty ) 1 - NA- - NA41 4 5 ( empty ) l - NA· -NA42 4 6 ( empty ) 1 - NA- -NA43 4 7 ( empty ) 1 -NA- -NA44 4 8 ( empty ) l -NA· -NA45 • 9 ( empty ) 1 - NA- · NA46 • 10 ( empty ) 1 - t<"A- -NA47 4 11 ( empty ) 1 -NA- -NA48 4 12 ( empty ) 1 -NA .. - NARack #5 

Pos Row Col Sample Name set # #Used Type 

-------------------- ------------ l l 1 ( empty ) 1 - NA· -NA2 1 2 ( empty ) 1 -NA- -NA3 1 3 ( empty ) 1 · NA· - NA4 1 4 ( empty ) 1 · NA- - NA5 l 5 { empty ) l -NA- -NA6 l 6 ( empty ) 1 · NA· - NA-

(7 ... 48 Not used) 

VES 006292 
1681 

0 

ll 

" .. 

~ • "' c 

.. 

.-31 0 

Profile line : As ~89.042/ 

Peak Position : -.029863 

Peak Intensity: 1534.04 

Peak Nidth : 9.52765 

New Spe~. Shift at : 0 

31 

~pectrUM Shifter Position I 

VES 006293 
Analysis Report · qc Stan dard 09/03/08 11:27 : 0 2 AM page 1 

r~ ethod : PSC34 Sample Name : HCL Operator: gbu 

Run Time: 09/ 0.3/08 11 :21: 36 

Comment : 

Mode: CCNC Co rr. Factor: 1 

Elem A.g Al As B Ba Be Bi 

Units ppm p pm ppm ppm ppm ppm ppm 

Avge - . 0 017 . 04 78 .0014 . 0185 -.00023 .00017 - . 0079 

#1 - . 0005 . 0653 .0054 .01( 3 -. 00007 . 00023 - . 0091 

#2 -. 0029 . 0447 - .0047 .0180 - . 00037 . 0 0014 - . 0030 

#3 - .001 6 .0333 . 0035 .0201 - . 00026 .00016 -. 0 117 

Elem Ca Cd Co Cr Cu Fe K 

Units ppm p pm ppm ppm ppm ppm p pm 

Avge .0555 - . 000 66 -. 0015 - . 0017 - .002 7 . 0016 - . 0598 

#1 .0569 - . 00005 . 0 0 05 - .0004 . 0004 .0037 -. 0831 

#2 .0546 -. 00116 - . 0014 - . 0036 - . 0028 . 0002 -. 0841 

#3 .0551 - ,00076 - . 0035 - .0011 - . 0057 .0010 - . 0 122 

Elem Mg Mn 140 Na Ni · p 2203/l 

Units ppm ppm ppm ppm ppm ppm ppm 

Avge . 0012 - . 00002 - . 0012 . 0625 . 0 003 .0190 - .0027 

#1 .0167 . 00014 -. 0003 .0660 . 0012 . 0193 - . 0048 

#2 -. 0060 -. 00023 - . 0027 .0626 -. 0004 . 0232 - . 0022 

#3 • . 0071 .00003 - .0007 . 0588 .0003 . 0.146 -. 0011 

Slem 2203/2 s Sb 1960/1 3:960/2 Si Pb 

Units ppm p pm ppm ppm ppm ppm ppm 

Avge - . 0009 . 0 185 - .0042 .0064 -·. 0 000 .0407 - . 0015 

#1 - . 0003 . 0219 - . 0045 . 0034 .0042 . .0447 - . 0018 

#2 - . 0010 . 0 187 - .0078 .0095 ·. 0047 . 0381 - . 0 014 

#3 · .0013 .0149 -.0002 .0065 . 0 004 .0393 - . 0012 

Elem Se · Sn Sr Ti Tl u v 

Units ppm p pm ppm ppm ppm ppm ppm 

Av ge . 0021 .0015 . 00011 -.00041 . 0010 - .0399 - . 0015 

#1 .0040 . 0035 .00017 .00025 . 0020 .004 0 .0002 

112 .0000 -. 0005 . 00011 - . 00046 . 001 6 - . 1004 - . 0030 

1#3 .0024 .0016 . 00006 - . 00102 - . 0007 .023~ -. 0017 

Elem y 213Zn zn Zr 

Units pprn ppm ppm ppm 

Avge 49.07 . 0005 - . 0005 - . 0022 

#l 48 . 79 .0010 . 0011 - . 0004 

112 49.29 . 0003 - . 00 12 - .0024 

1!3 49.15 . 0003 -. 0014 • - . 0038 

VES 006294 
St andardizat ion Rpt. 09/03/08 11:34: 5 9 AM page 1 

Meth od : PSC34 Standa rd : CAL- BLK / 

Run Time: 09/03/08 11 : 29:30 

Elem Ag ·Al As B Ba Be Bi 

Avge . 0267 .7986 - . 0053 .31 82 . 02266 - . 10 128 .0536 

lfl .0520 . 8446 - .0050 . 3568 . 03098 -. 09095 .1699 

#2 . 0430 .7666 - . 0080 . 3 1 38 .01.899 ·- .10495 . 0910 

113 - . 0150 .7846 - .0030 .2839 . 01799 - .10795 - .1000 

Elem Ca Cd Co Cr Cu Fe Fe 

Avge .0366 .09762 - .0243 . 0107 . 2499 .0340 . 0916 

#1 .0400 . 145.93 .0740 .0180 . 3378 .0790 . 1149 

112 .0340 . 08996 -. 0500 . 0040 .2159 .0190 . 0730 

#3 .0360 . 05697 - . 0970 . 01 00 . 1 959 . 0040 .0870 

El e m K Mg Mg Mn Mo Na Ni 

Av g e - . 6567 . 0210 . 0463 . 00500 - . 0160 34 . 31 .04 1.3 

#1. - . 7586 .0360 .1429 .00700 .0730 35 . 66 . 0780 

112 - . 5607 .0290 . ()050 . 00600 - .0520 33.52 . 0430 

#3 - . 6507 - . 0020 - .0090 .00200 - . 0690 33.75 . 0030 

Bl e m p 2203/1 2203/2 s Sb 1.960/ 1 1 960/2 

Avge . .3711 .1003 .061.3 . 3332 .0956 - . 04 63 .01.17 

Ill .3968 -·. 3118 . 1959 . 324.8 . 1959 - . 1199 .1059 

lf.2 . 38'1.8 . 6 107 .0320 .3408 . 1209 .0450 - . 0940 

#3 .3348 . 0020 7. 0440 .3338 - . 0300 - . 0640 . 0230 

El em Si Sn Sr Ti Tl u v 

Avge .1593 .0330 . 0726 3 .021 99 - . 0370 .1.039 .0077 

#1 . 2159 .05'90 .08296 .16392 . 0040 . 1339 . 02 90 

#12 . . 1 339 . 0390 .06997 - . 03098 - .0210 . 12 19 .0010 

»3 .1279 .0010 . 06497 -. 066.97 -·. o9"4o .OS60 - . 0070 

Elem 2l3Zn Zn Zr 

A.vge - . 0030 - . 03 33 - 1 . 102 

U1 .00 20 .0440 -1.31.6 

#2 - . 0050 -. 0650 -1..871. 

#3 - . 0 060 - . 0790 - 1. . 918 

VES006295 
Standardization Rpt. 09/03/ 08 11 3~:45 AM page 1 

Method: PSC34 Standard: STO·B ./ 

Run Time: 09/03/08 11:35:03 

Elem Ag Pe Mg Ko p s Sb 

Avge l3 . 14. 4.0.29 5 .232 22.24 20.36 9 . 603 5.658 

#1 13.21 4 0.25 5.228 21.87 20.29 9 . 569 5.477 

#2 13.19 4 0.41 5.265 22.43 20.52 9. 710 5.821 

#3 l3 . 03 40 . 20 5.203 22.42 20. 26 9 .530 5.674 

Ele m Si Sn Ti 213Zn Zr 

Avge 14.21 12 .6~ 180.04 5.695 212. 1 

. Ill 14.22 12.70 180.06 5 .702 212.6 

#2 14 .31 12.77 180.60 5 . 714 212.6 

lt3 1'1 . 11 12.61 179 . 46 5.668 2H.2 

VES 006296 
Standardization Report 09/03/08 11 :39:45 AM page 1 

Method: PSC34 Slope s Conc(SIR)/IR 

Element wavelen High std Low std Slope Y- intercept Date Standardized 

Ag 328.068 STD-B CAL-BLK .038308 - . 001021 09/03/08 11 : 35 : 03 

Al 308.215 STD-A CAL-BLK . 280175. -. 223748 09/03/08 11:35:03 

As 189.042 STD-A CAL-BLK .087507 .000466 09/03/08 11:35:03 

B H9.678 STD-A CAL-BLK . 040724 - . 012957 09/03/08 11:35:03 

Ba 455.404 STD-A CAL-BLK .026968 -. 000611 09/03/08 11:35:03 

Be 313.042 STD-A CAL-BLK . 006340 .000642 09/03/08 11:35:03 

8i 223.061 STO-A CAL-8LK . 080459 - .004316 09/03/08 11:35:03 

Ca 317.933 STD-A CAL-BLK .614555 - .022522 09/03/08 11:35:03 

Cd 126.502 STO-A CAL-BLK . 004679 - .000457 09/03/08 11:35:03 

Co 228.616 STO-A CAL-BLK .026438 . 000643 09/03/08 11:35:03 

Cr 267.716 STD-A CAL-BLK .069487 - . 000711 09/03/08 11:35:03 

Cu 324.753 STD-A CAL-BLK .034165 - . 008537 09/03/08 11:35:03 

Fe 259.940 . STD-8 CAL-BLK .049758 - . 004559 09/03/08 11:35 :03 

Fe 271.441 STD-A CAL-BLK . 985811 -. 033501 09/03/08 11:35:03 

K 766.491 knahi 15 CAL-BLK .784520 . 041072 09/03/08 11:35:03 

Mg 279.078 STD-B- CAL-BLK . 19284 1 -. 008931 09/03/08 11:35:03 

Mg 383 .231 STD-A CAL-BLK . ?26263 -.015244 09/03/08 11:35:03 

Mn 257 . 610 STD-A CAL-BLK .037608 - . 0001.88 09/03/08 11:35:03 

Mo 202.000 STD-8 CAL-BLK . 022468 .000359 09/03/08 11:35:03 

Na 588.995 knahi 15 CAL-BI,K . 767437 -37 . 2071 09/03/08 11:35:03 

Ni 23l.604 STD-A- CAL-8LK . 033002 -. 001363 09/03/08 1 1: 35:03 

p 178.287 STO- B CAL-8LK .250183 - .092855 09/03/08 11 : 35:03 

2203/1 220.351 STD-A CA!,-8LK .01 7987 -.001804 09/03 /08 1 1:35:03 

2203/2 220.352 $1'0-A CAL-8LK . 034151 - . 002094 09/03/08 11:35:03 

s t82 .040 STD- 8 CAL-BLK . 215749 -. 071880 09/03/08 11:35:03 

Sb 206.838 STD-B CAL-8LK . 089113 - . 008521 09/03/08 11:35:03 

1960/1 196.021 STD·A CAL-BLK .078576 .003639 09/03/08 11:35:03 

1960/2 t96. 022 STO-A CAL-BLK .075300 -. o·oo878 09/03/08 11:35 :03 

Si 251.612 ST0-8 CAL-BLK . 071702 -. 011419 09/03/08 11:35:03 

Pb 220.353 NONS NONE .000000 .000000 *NOT STANDARDIZED 

se 196 . 026 NONE NONE .000000 .000000 *NOT STANDARDIZED 

Sn 189 . 989 STO-B CAL-BLK .079085 -.002609 09/03/08 11:35:03 

Sr 407.771 STO-A CAL-BLK . 006924 .0()0~03 09/03/08 11:35:03 

Ti 334 . 941 STD-B CAL-BLK .005555 - . 000122 09/03/08 11:35:03 

Tl 190 .864 STD-A CAL-BLK .162254 .006000 09/03/08 11:35:03 

u 367.000 STD-A CAL-BLK 1. 01504 - .105512 09/03/08 11:35:03 

v 292.402 STD-A CAL-8LK .065509 -. 000502 09/03/08 11:35:03 

y 371.000 NONE NONE 1.00000 .000000 *NOT STANDARDIZED 

213Zn 213.856 STD-B CAL-8LK .087766 .000263 09/03/08 11:35:03 

Zn 206.200 STD-A CAL-BLK .016837 . 000561 09/03/08 11: 35:03 

Zr 339.198 ST0-8 CAL-8LK .004682 .007968 09/03/08 11:35:03 

VES 006297 
Sr.andardi.zar.ion Rpt. 09/03/08 11:4 5 : 5 7 AM page 1 

Method : PSC34 St andard : STD-A / 

Run Time: 09/03/08 11 : 40 : 27 

Blem Al As B Ba Be Bi Ca 

· Avge 6.625 5. 748 23.07 32 . 329 77.22 0 5 . 780 16. 4 9 

#1 . 6.597 5. ?88 23.06 32 .279 76 . 978 5 . 776 16.47 

112 6.587 5 . 7 8 3 2 3 '. 0 6 32 .274 77 . 104 5 . 704 16 ..44 

#3 6 . 693 5 . 673 23.10 32.435 77 . 577 5 . 8 61 1~. 57 

Elem Cd .Co Cr Cu Fe Mg Mn 

Avge 112 .40 38.07 14.32 26.58 10 . 14 6 .249 25 . 708 

# 1 112 . 2 1 3 7 .99 14.31 26.60 10 . 14 6 .247 2 5 .683 

112 112.20 38.01 14 . 29 26.52 10.08 6. 203 25 . 655 

#3 112 . 80 38 . 22 14 .35 26 . 61 10.1 8 6 .296 25.785 

El em Ni 2203/l 2203 / 2 1960/1 1960/2 Sr Tl 

Avge 15 .42 .58 . 12 30.70 6 .3]:1 6 .350 64 .874 6 . 128 

IU 15 . 37 57.65 30.58 6 . 173 6.228 64. 728 6.030 

112 15 . 33 58.78 30 . 72 6 .481 6.398 64.771 6.061 

U3 15.54 57.91 30 . 80 6. 278 6.425 65.123 6 . 294 

Elem u v Zn 

Avge 4.537 7 . 353 130.1 

11 1 4 . 555 7 . 348 12 9. 9 

112 4.450 7.333 129 . 8 

113 4 . 608' 7 . 3 7 7 130 . 5 

h ? 2$, 7o S· 

---- - Clf .i%. 58 

- f)' ? 

VES 006298 
Standardization Report 09/03/08 11 : 45:57 AM page l 

Metho d: I?SC34 ' Slope a Conc(SIR)/IR 

El ement tolavelen High std Low std Slope ¥ -intercept Dat e Standardized 

Ag 328 . 068 STD- B CAL- BLK .038308 - .001021 09/03/08 1 1: 40 : 27 

Al 308.21 5 STD-A CAL-BLK . 336005 - .268334 09/03/08 11:40:27 

As 1 89 . 042 STD-A CAL-BLK . 086904 . 000463 09/03/08 1 1:40: 27 

B 249 . 678 STD-A CAL-BLK . 044071 -.014022 09/03/08 11:40: 27 

Ba 455'.404 STD-A CAL-BLK . 030954 - .000701 09/03/08 11:40:27 

Be 313.042 STD-A CAL- BLK .006468 . 0 0 0655 09/03/08 11:40 : 27 

Bi ' 2 23 . 061 STD-A CAL- BLK .087354 - .004686 09/03/08 11:40:27 

Ca 317.933 STD- A CAL-BLK . 607898 - .022278 09/03/08 1 1:40: 27 

Cd . 226 . 502 STD-A CAL- BLK .Q04457 - -0004 35 09/03/08 11 :40:27 

Co 228 . 616 STD-A CAL- BLK . 026260 .00 0639 09/03/08 11 :40 : 27 

Cr 267.716 STD-A CAL- BLK . 07002 9 - .000747 09/03/08 1 1 ; 4 0:27 

Cu 324.753 STD-A CAL-BLK . 038153 - .009534 09/03/08 11:40 : 27 

Fe 259 . 940 STD- B CAL-BLK .049758 - . 004559 09/03/08 1 1 :40 : 27 

Fe 271. 441 STD- A CAL-BLK .989973 - . 033642 09/03/08 11 : 40 : 27 

K 766 . 491 knahi_15 CAL- BLK .784520 . 041072 -09/03/08 11:40:27 

~lg 279.078 STD- B CAL- BLK . 192841 -.008931 09/03/08 11 : 40 : 27 

Mg 383 . 231 STD- A CAL- BLK . 802884 - -01 6852 09/03/08 1 1 : 4 0:27 

Mn 2 57.61 0 STD- A CAL-BLK -0389 25 - .0001.95 09/03/08 11 : 40 : 27 

Mo 202.000 STD-B CAL- BLK . 022468 .000359 09/03/08 1 1:40:27 

Na 588.995 knahi 15 CAL-BLK . 7674 37 -37 - 2071 09/03/08 1~:40 27 

Ni 231.604 STD-A - CAL- BLK .032462 - . 001341 09/03/08 1 1 : 40 : 27 

p • 178.287 STD- B CAL-BLK . 250183 • -092855 09/03/08 11:40:27 

2203/1 220.351 STD-A CAL- BLK .017296 . - .001734 09/03/08 11:40: 2 7 

2203/2 220.3S2 STD- A CAL- BLK .032815 - . 002012 09/03/08 11:4 0:27 

s 182.04 0 STD- B CAL- BLK . 21574 9 - . 071880 09/03/08 1 1 :40:27 

Sb 2.06-838 STD- B CAL-BLK .089113 _._ 008521 09/03/08 11:40:27 

1 960/1 196.021 STD-A CAL-BLK . 078514 .003636 09/03/08 11 : 40:27 

1960/2 1 96 . 022 STD- A CAL-BLK . 078300 - -000913 09/03/08 11:40: 2 7 

Si 251. 612 STD- B CAL-BLK . 071702 -.01141 9 09/03/08 11:40:27 

Pb 220.353 NONE NONE . 000000 .00 0000 *NOT STANDARDIZED 

Se 196 . 026 NONE NONE . 000000 . 000000 *NOT STANDARDIZED 

So 189.989 S'I'D-B CAL-BLK .079085 - .002609 09/03/08 1 1 :40:27 

Sr 407 . 771 STD-A CAL- BLK . 007716 - .000560 09/03/08 1 1:40:27 

Ti )34. 9'41 STD- B " CAL-BLi< :oo55SS : oooi:22 o·9/03/0"8 11:~0 :2 ' 

T1 190.864 STD- A CAL-BLK .1645 66 .006066 0 9/03/08 1 1 :40 :2 7 

u 367.000 STD- A CAL-BLK 1. 1 4083 - .118587 09/03/08 11:40 : 27 

v 292.402 STD-A CAL- BLK .067981 -. 000521 09/03/08 11:40 : 27 

y )71. 000 NONE NONE 1 .00000 .000000 *NOT STANDARDIZED 

21 3Zn 213.856 STD-B CAL-BLK .087766 -000263 09/03/08 1 1 : 40 : 27 

Zn 206.200 STD- A CAL- BLK .015381 . 000512 09/03/08 1 1: 40 : 27 

Zr )39.198 STD- B CA):,-BLK .004682 . 007968 09/03/08 11:40 : 27 

VES 006299