~

=~ ~.,

~



### I 

# 11-1-027

ACID GAS EMISSIONS (HF, HC1, S0 2 )~ 

### T.LSTING ON THE WOOD MOLD AND ICILN #3 EXHA UST



## BORAL BRICK 7472 VAN WYCK ROAD VAN WYCK, SOUTH CAROLINA 29744

(803) 286-5566 

### MAY 14 & 15,1997 REPORT # 5887

ANALYTICAL TESTING CONSULTANTS, INC. 301 Brookdale Street P. O. Box 886 Kannapolis, N. C. 28083 Roswell, Georgia 30077 (704) 932-3193 (770) 587-5696 

### Distribution: Mr. Robert Maner (Five copies) Issue Date: _ June 19, 1997
i 

### _J 

## ~„i



### ~ 

## TABLE OF CONTENTS

. Page 

### Number 

## INTRODUCTION ............................................. CERTIFICATION OF RESULTS . . . . . . . . . . . . . . . . . . . . . . . . 1 PROCESS DESCRIPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 PROCESS FLOW DIAGRAMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 RESULTS SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 

### RESULTS, CONCLUSIONS AND COMMENTS . . . . . . . . . . . . . . . . . 8 SA1ViPLING AND ANALYTICAL PROCEDURES . . . . . . . . . . . . . . . 9 Sampling Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Analytical Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 DATA AND CALCULATIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . FI.OWRATE AND MOISTURE DETERMINATIONS . . . . . . . . 12 WOODMOLD STACK . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 

## KILN #3 .......................................13 ISOKINETIC DATA AND CALCULATIONS . . . . . . . . . . . . . . . . 

## RUN #1 ....................................... 14 

## RUN #2 ....................................... 15 RUN #3 .......................................16 

## RUN #4 ....................................... 17 

## RUN #5 ........:.............................. 18 

## RUN #6 ....................................... 19 METHOD 26 EMISSION RATE CALCULATIONS . . . . . . . . . . 20 S02 EMISSION RATE CALCULATION . . . . . . . . . . . . . . . . . . 22 STANDARD VOLUME CALCULATIONS . . . . . . . . . . 24 NOMENCLATURE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 CALCULATION FORMULAE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 DATA S HEETS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 ii i

## INTRODUCTION

This report presents the results of hydrogen flouride, hydrogen chloride, and sulfur dioxide emissions testing from the exhausts of the Woodmold and #3 kiln at Boral Brick's facility in Van Wyck, South Carolina. Testing was conducted on Wednesday, May 14 and Thursday, May 15, 1997. 

### The test was conducted by ANALYTICAL TESTING CONSULTANTS, INC. of Kannapolis, N. C. and Atlanta, Georgia. Members of the test team were Richard

~ 

### Westbrook and Shane Roberts. !;<tl 

### Mr. Thomas Lathom of SCDHEC witnessed sampling on behalf of the State of South Carolina. b~



### CERTIFICATION OF RESULTS

"By our sigizature we certify that the testing and the reportitig of the test results contained herein are prepared to the best of our abilities and that, to our knowledge, the data have been calculated and reported correctly. No data or information has knowingly been omitted. "


### W. Keith Poole Richard N. Westbrook Test Report Preparation Test Team Leader

1 •_J • J

# 0

~ 

## PROCESS DESCRIPTION 

# ~

.



### Wood Mold Process- Plant `B"

~ 

### Clay is delivered to the plant by truck from off site mines and deposited into an apron feeder that

feeds a primary crusher (EQ02), then a grinder. It is belt conveyed to one of four shaker screens that operate in parallel. Course material is conveyed back to the grinder for re-processing. Belt conveyors then load fine clay into one of five covered storage bins. As needed, clay is conveyed from' the fine clay storage bins to a lower, then upper pug mill, where fine clay is combined with water. A column is extruded from the brick machine and is cut into bricks. These "green" bricks are subsequently stacked on drying racks and placed in the rack dryer. Initial drying occurs in the tunnel dryer, which is supplied with waste heat from the cooling section of the kiln. From the tunnel dryer, bricks are re-stacked on kiln cars. The cars ~ 

### are moved to a pre-heater where the temperature of the brick is raised before entering the kiln. In

the natural gas heated kiln, final evaporation of free water, dehydration, oxidation, vitrification, flashing, and cooling occurs. Of the tunnel dryer, pre-heater, and kiln, only the kiln has a heat source. The tunnel dryer and pre-heater are supplied with waste heat from the kiln. After exiting .! the kiln, bricks are packaged and stored on site for sale. "-' Kiln 0-Plant "C" J 

### Crude clay is transferred by front end loader to feed hoppers on the Plant "C" line. It is then

conveyed to crushers. A twin feeder sends clay to dual grinders (an "A" and "C" line) and the
~ 

### ground material is screened. Both sides of the line have three screeners. Again, course marterial

that will not pass through the sizing screens is re-conveyed to the grinders. Side "A" and "C" i fine materials are then combined at conveyor belt #10 and transfen ed to one of three covered fine ' clay storage silos. F# , ;S As load demands require, fine clay is conveyed to a pug mill where is mixed with water.
~ 

### "Green" bricks are then cut and loaded at the setting machine and sent to the holding room (five
~ 

### tracks). Bricks are then sent to one of two tunnel dryers and the Harrop Kiln. After drying, bricks 1 are packaged and stacked on the brickyard for shipment. J

2


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# . _ - /,

## RESULTS SUMMARY


## ~ CLIENT: BORAL BRICK

LOCATION: VAN WYCK, SOUTH CAROLINA 

## ~ DATE: MAY 14, 1997



### SOURCE: WOOD MOLD EXHAUST ~ 

### PARAIVIETER RUN #1 RUN #2 RUN #3 AVG.

~ QS, ACFM 14,867 17,168 17,284 16,440



### Q STD DRY, SCFM 9,183 10,311 10,464 9,986 %M, MOISTURE 7.41 9.33 8.72

~~ . 

### PRODUCTION RATE, TPH - 8.05

(Product-Ballantyne Modular Size Woodmold Brick)' } :, 

### HYDROGEN FLOURIDE EMISSIONS

CONCENTRATION,MG/DSCM 41.47 105.56 106.31 84.45 HF, LBS/HR 1.43 4.08 4.17 3.23 Li LBS HF/TON 0.177 0.507 0.518 0.401 '° ' 

### HYDROGEN CHLORIDE ENIISSIONS CONCENTRATION,MG/DSCM 5.17 9.46 10.90 8.51 HCI, LBS/HR 0.18 0.37 0.43 0.327 LBS HCUTON 0.022 0.045 0.053 0.040 

### SULFUR DIOXIDE EMISSIONS

~ 

### CONCENT RATION,MG/DSCM

A 0.00 0.0112 0.0301 0.0138 B 0.0248 0.0230 0.1285 0.0588 

# ~ S0 2 , LBS/HR

A 0.00 0.539 1.468 1.003 B 1.062 1.106 6.299 2.822 

### LBS SO Z /TON A 0.00 0.067 0.182 0.083 B 0.132 0.137 0.783 0.351

l 

### Additional Kiln'parameters are provided in the DATA SHEETS section of this report.

, . 

### 6 i



# I~

~ 

## RESULTS SUMMARY

CLIENT: BORAL BRICK LOCATION: VAN WYCK, SOUTH CAROLINA DATE: MAY 15, 1997 SOURCE: #3 KILN EXHAUST PARAMETER RUN #4 RUN #5 QS, ACFM 28,965 , 30,440 

### Q STD DRY, SCFM 15,193 15,525 %M, MOISTURE 9.26 10.67 PRODUCTION RATE, TPH - (Product-Extruded Modular Size Craggy Mountain) Z HYDROGEN FLOURIDE EMISSIONS CONCENTRATION,MG/DSCM 93.77 101.29 HF, LBS/HR 5.34 5.89 LB S HFlTON 0.544 0.600 HYDROGEN CHLORIDE ENIISSIONS CONCENTRATION,MG/DSCM 7.42 8.27 HCI, LBS/HR 0.42 0.48 LBS HCIJTON 0.043 0.049 SULFUR DIOXIDE ENIISSIONS CONCENTRATION,MG/DSCM A 0.0012 0.00 B 0.00 0.0212 

### SO Z , LBS/HR A 0.092 0.000 B 0.000 1.538 

### LB S S O 2 /TON A 0.009 0.000 B 0.000 0.157 

### RUN #6 AVG. 27,879 29,095 14,354 15,024 10.49 9.81
102.42 99.16 5.51 5.58 0.561 0.568 8.10 7.93 0.44 0.45 0.044 0.045 _
0.0101 0.0038 0.0150 0.0121 0.678 0.257 1.010 0.849 0.069 0.026 0.103 0.087



### _ Z Additional Kiln'parameters are provided in the DATA SHEETS

section of this report. 7 

# I

# i~

~

,- 

# ~ i2ESULTS, CONCLUSIONS AND COMMENTS 

# i A summary of some pertinent results appear in the preceding RESULTS SUMMARY. For

additional information please consult the CALCULATIONS and DATA SHEETS sections of this report. Calculation of emission rates utilized the average standard volumetric flowrate (Q std dry, scfm), the total mass of each pollutant in question, the standard sample volume for the corresponding run, and conversion factors from mg/m 3 to pounds per hour. ~ 

### This equation is found on the emission concentration calculation page of the report.

~ 

### Woodinold Stack Exhaust

The mean velocity was determined to be 25.94 feet per second (ft/s) through the square 39" x 39" _ (A=10.56 ft Z ) exhaust stack. This yielded a mean actual volumetric flowrate of 16,440 cubic feet

per minute (ACFM). The standard flowrate was calculated by applying corrections for: 1) barometric pressure- 29.25" Hg, 2) static pressure of the stack- -0.10" H 2 O, 3) moisture content of each individual run- AVG.=8.49%, and 4) the corresponding stack temperature- AVG.=319.6° Fahrenheit. The corresponding mean standard volumetric flowrate was 9,986 SCFM:

~ 

### Hydrogen Flouride emissions averaged 3.23 pounds per hour or 0.401 lbs/ton. Samples were L-j also analyzed for Hydrogen Chloride and averaged 0.327 lbs/hr and 0.040 lbs/ton.

~ 

### Separate sampling trains were operated for determinations of sulfur dioxide emisisons (USEPA

~ 

### method 6). Duplicate runs were performed. Emission concentrations averaged 0.0363 from the

six runs. This yielded an emission rate of 1.913 lbs/hr and 0.217 lbs/ton: Kiln #3 Stack Exhaust The mean velocity was determined to be 48.36 feet per second (ft/s) through the square 38" x 38" =' (A=10.03 ft 2 ) exhaust stack. This yielded a mean actual volumetric flowrate of 29,095 cubic feet

~ 

### per minute (ACFM). The standard flowrate was calculated by applying corrections for: 1) j barometric pressure- 29.10" Hg, 2) static pressure of the stack- -0.35" H Z O, 3) moisture content

of each individual run- AVG.=10.14%, and 4) the corresponding stack temperatureAVG.=436.3° Fahrenheit. The corresponding mean standard volumetric flowrate was 15,024 SCFM. Hydrogen Flouride emissions averaged 5.58 pounds per hour or 0.568 lbs/ton. Hydrogen Chloride emissions averaged 0.45 lbs/hr and 0.0451bs/ton. Sulfur dioxide emission concentrations, as measured by USEPA 6, averaged 0.0080 from the six runs. This yielded an emission rate of 0.553 lbs/hr and 0.057 lbs/ton. 

# n : 

# 11

# m
SAMPLING AND ANALYTICAL PROCEDURES

~ 

### Sampling and analysis were performed according to procedures developed by the U. S.

Environmental Protection Agency (USEPA) and referred to as Methods 1, 2, 3, and 4. ~ 

### Additional sampling methodology included USEPA method 26 for halide compounds,

specifically Hydrogen Flouride and Hydrogen Chloride. 

### Sampling Procedures Prior to each sampling run, method 2 was utilized to develop velocity and temperature profiles across the square ducts. The method 26 sampling train was assembled and heated to operating conditions prior to leak-checks being conducted (ice was placed in the impinger case to maintain f 

### W~ 

### the temperature at < 68° F). Leak-checks, as recorded on the sampling data sheets, reflect

leakage rates in liters per ininute. The sampling train consisted of a borosilicate glass probe liner attached to a heated filter assembly containing a non-tared 25mm Teflon® filter. The heated

— 

### J three way stopcock followed the filter. Immediately after the filter, the stack gas passes through

three midget impingers containing 15 milliliters (ml) each of 0.1N H 2 SO 4 . This was followed in sequence by two midget impingers containing 15 mfof 0.1N NaOH. A sixth impinger contained an appropriate quantity of silica gel. After a successful completion of the leak-check, the heated

- ~ 

### three way stopcock was opened and the sampling probe and filter assembly was purged for five J minutes at a flowrate of 2.0 liters per minute. Three repetions were completed in this manner.

- ~ 

### The first and second impingers of each sampling train were recovered and combined. The third
, J impinger was recovered separately and utilized for breakthrough determinations. The contents of

the fourth and fifth impingers were not needed and were archived after recovery. The teflon filter "- ~ 

### was placed into the first container with the contents of the first and second impinger. An

~ 

### + appropriate chain of custody was completed and forwarded to the laboratory.



### Analytical Procedures As requested by the South Carolina Department of Health and Environmental Control (SCDHEC), the first/second and the third impinger of a single run (first run) were analyzed separately to determine breakthrough on one run per source. The remaining third impinger
— sample containers were archived until results of the analyses were received. No breakthrough ~ 

### was measured in either of these. The target QA/QC guideline was to detect less than 10% in the ~ 

### third impinger.

Resolution Analytics, Inc. performed the analyses. Results of the in-house audit sample exhibited a 0.78% difference on replicate injections. The matrix spike (spiked with 0.5 ml of a 50 ppm flouride standard) was 94.6% recovered. Field spike recovery rates were 94.0% and 97.1%, respectively.

~~


### ~~„ t

t:h 

# ~

~ . ,., 

## REFERENCES

l. CODE OF FEDERAL REGULATIONS, Title 40, Part 60, Appendix A, July 1, 1995. M

~

.>. ~



### 10 

# I -Z/

## DATA AND CALCULATIONS Flow Calculations Traverse Data Emission Rate Calculations Hydrogen Flouride Calculations Hydrogen Chloride Calculations Sulfur Dioxide Calculations Nomenclature Calculation Formulae



### i
J



## ~

~



## 11 

# 13LOCATION: BORAL BR/CK SOURCE: WOODMOLD STACK DATA RUN #1 RUN #2 RUN #3 A DATE 05/14/97 05/14/97 05/14/97 RUN T/ME (min) 60.00 60.00 60.00 AVG DH (in H20) 1.25 1.25 1.25 P ATM (in Hg) 29.25 29.25 29.26 Pm (in Hg) 29.34 29.34 29.34 Ps (GAUGE) -0.10 -0.10 -0.10 Ps (IN HG) 29.24 29.24 29.24 Tm (F) 73.58 82.33 84.25 Tm (R) 533.58 542.33 544.25 Vm (tt3) 38.31 38.56 38.66 Vm STD (ft3) 37.18 36.82 36.78 VLO (ml) 63.10 80.40 74.60 VV STD (0) 2.97 3.79 3.51 V STD (ff3) 40.15 40.60 40.30 %M 7.41 9.33 8.72 MD 0.93 0.91 0.91 MWD 29.38 29.24 29.32 M 28.54 28.19 28.33 Ts (F) 316.20 321.76 320.68 Ts (R) 776.20 781.76 780.68 SUM SORT DP 8.47 9.69 9.78

N DP 25.00 25.00 25.00 AVG SORT DP 0.34 0.39 0.39

CP 0.84 0.84 0.84 Vs (ft/s) 23.46 27.09 27.27 Ds (in) As (ft2) 10.56 10.56 10.56 OS, FLOW, ACFM 14867 17168 17284 O STD (fi3/min) 9918 11371 11464 Q STD DRY, FLOW SCFM 9183 10311 10464

% CO2 4.50 3.50 4.00 %02 16.50 17.00 17.00 % CO 0.00 0.00 0.00 %N2 79.00 79_50 79.00 

# ®

~ 1

~ 8.49

319.55 779.55

~ 25.94
16440 10918 9986 4.00 16.83 

## FLOWRATE AND MOISTURE DETERMINATION 

# I

12 

# l~

### a~

~ 

## FLOWRATE AND MOISTURE DETERMINATION
LOCATION: BORAL BR/CK SOURCE: K1LN #3 DATA RUN #4 RUN #5 RUN #6 AVERAGE DATE 05/15/97 05/15/97 05/15/97 RUN T1ME (min) 60.00 60.00 60.00 AVG DH (Pn H20) 1.25 1.25 1.25 P ATM (in Hg) 29.10 29.10 29.10 Pm (in Hg) 29.19 29.19 29.19 Ps (GAUGE) -0.35 -0.35 -0.35 Ps (IN HG) 29.07 29.07 29.07 Tm (F) 77.75 87.33 88.92 Tm (R) 537.75 547.33 548.92 Vm (ft3) 38.21 38.27 39.71 Vm STD (ft3) 36.60 36.02 37.27 VLO (ml) 79.30 91.30 92.70 VV STD (ft3) 3.74 4.30 4.37 V STD (ft3) 40.34 40.32 41.64 %M 9.26 10.67 10.49 10.14 MD 0.91 0.89 0.90 MWD 29.32 29.32 29.32 M 28.27 28.11 28.13 Ts (F) 431.16 442.28 435.56 436.33 Ts (R) 891.16 902.28 895.56 896.33 SUM SORT DP 16.10 16.77 15.42

N DP 25.00 25.00 25.00 AVG SORT DP 0.64 0.67 0.62

CP 0.84 0.84 0.84 Vs (ft/s) 48.14 50.59 46.34 48.36 Ds (in) As (ft2) 10.03 10.03 10.03 OS, FLOW, ACFM 28965 30440 27879 29095 Q STD (ft3/min) 16744 17379 16037 16720 Q STD DRY, FLOW SCFM 15193 15525 14354 15024

%CO2 4.00 4.00 4.00 4.00 % 02 17.00 17.00 17.00 17.00 % CO 0.00 0.00 0.00



### 13

... iRUN #1 POINT # 

### A1 A2 A3 A4 

### A5 B1 B2 B3 B4 

### B5 C1 C2 C3 C4 C5 

### D1 D2 

### D3 D4 

### D5 E1 E2 

### E3 E4 

### E5 t~

»~



### 4; r; dH SQRT DP % 02 % CO2 1.25 0.316 16.5 4.5 , 0.316 0.265 0.200 0.173 0.548 0.548 0.346 0.283 0.265 0.592 _ 0.500 0.300 0.200 0.224 0.574 0.529 0.200 0.173 0.224 0.520 0.424 0.332 0.245 0.173 1.25 8.469 16.50 % N2 (BY D/FFERENCE) 79. 

## ISOKINETIC DATA AND CALCULATIONS DATE 05/14/97 - 

### SOURCE WOOD MOLD STACK
Tm Ts dp 70 293 0.10 70 300 0.10 70 304 0.07 71 305 0.04 73 305 0.03 73 305 0.30 75 310 0.30 75 315 0.12 75 317 0.08 76 317 0.07 77 325 0.35 78 326 0.25

326 0.09 325 0.04 324 0.05 321 0.33 323 0.28 325 0.04 324 0.03 323 0.05 318 0.27 319 0.18 318 0.11 319 0.06 318 0.03 73.58 316.20 

### Vm(ft3) Initial 676.80

Final 715.11 Total 38.31



### 14 

# jb

# ~ 

# 0 B ~

~ 

## ISOKINETIC DATA AND CALCULATIONS

DATE 05/14/97 - 

### SOURCE WOOD MOLD STACK RUN #2 POINT # Tm Ts dp dH SQRT DP % 02 % CO2 A 1 79 301 0.32 1.25 0.566 17 3.5 A2 80 307 0.30 0.548 A3 81 313 0.25 0.500 A4 80 312 0.11 0.332 A5 81 309 0.05 0.224 B 1 83 314 0.29 0.539 B2 85 320 0.24 0.490 B3 83 322 0.14 0.374 B4 83 322 0.07 0.265 

### B5 85 322 0.05 0.224 C1 84 324 0.33 0.574 _ C2 84 327 0.22 0.469 C3 328 0.08 0.283 C4 328 0.04 0.200 C5 327 0.03 0.173 D 1 320 0.32 0.566 D2 323 0.24 0.490 D3 327 0.10 0.316 D4 330 0.05 0.224 D5 329 0.05 0.224 E1 321 0.27 0.520 E2 327 0.30 0.548 E3 330 0.18 0.424 E4 330 0.10 0.316 E5 331 0.09 0.300

82.33 321.76 1.25 9.686 17.00 3.50 Vm(tt3) Initial 715.40 % N2 (BY D/FFERENCE) 79.50

Final 753.96 Total 38.56



### 15 

## l~

## ISOKINETIC DATA AND CALCULATIONS DATE 05/14/97 . SOURCE _ WOOD MOLD STACK 

### RUN #3 PO/NT # Tm Ts dp dH SORT DP % 02 % CO2 A 1 83 307 0.31 1.25 0.557 17 4 A2 83 313 0.28 ' 0.529 A3 83 314 0.24 0.490 A4 83 316 0.17 0.412 A5 84 317 0.08 0.283 B 1 83 313 0.33 0.574 

### B2 83 315 0.28 0.529 B3 84 322 0_14 0.374 B4 85 323 0.06 0.245 B5 87 322 0.06 0.245 C1 87 314 0.33 0.574 _ C2 86 320 0.25 0.500 C3 323 0.09 0.300 C4 323 0.03 0.173 C5 322 0.04 0.200 D1 320 0.31 0.557 D2 322 0.23 0.474 D3 324 0.08 0.283 D4 325 0.03 0.173 D5 324 0.03 0.173 E7 324 0.30 0.548 E2 325 0.28 0.529 E3 330 0.17 0.412 E4 330 0.12 0.346 E5 329 0.09 0.300

84.25 320.68 1.25 9.782 17.00 4.00 Vm(ft3) Initial 754.10 % N2 (BY D/FFERENCE) 79.00

Final 792.76 Total 38.66



### 16 :_ 1

~

# ~ 0
~

~ 

## ISOKINETIC DATA AND CALCULATIONS

DATE 05/15/97 . 

### SOURCE - KILN #3 

### RUN #4 PO/NT # Tm Ts dp dH SQRT DP % 02 % CO2 A 1 71 388 0.16 1.25 0.400 17 4 A2 73 417 0.45 ' 0.671 A3 73 430 0.70 0.837 A4 75 436 0.78 0.883 A5 76 439 0.78 0.883 B 1 78 381 0.09 0.300 B2 79 430 0.47 0.686 B3 80 437 0.55 0.742 B4 81 442 0.61 0.781 

### B5 82 445 0.78 0.883 C1 82 390 0.04 0.200 C2 83 429 0.48 0.693 C3 440 0.44 0.663 C4 444 0.45 0.671 C5 448 0.63 0.794 D1 405 0.05 0.224 D2 443 0.41 0.640 D3 451 0.46 0.678 D4 454 0.53 0.728 D5 455 0.72 0.849 E1 415 0.11 0.332 E2 428 0.26 0.510 E3 435 0.40 0.632 E4 446 0.45 0.671 E5 451 0.56 0.748

77.75 431.16 1.25 16.098 17.00 4.00 Vm(ft3) Initial 793.10 % N2 (BY D/FFERENCE) 79.00

Final 831.31 Tofal 38.21



## 17
:J 

# 15

## ISOKINETIC DATA AND CALCULATIONS DATE 05/15/97
. SOURCE KILN #3 RUN #5 PO/NT # Tm Ts dp dH SORT DP % 02 % CO2 A 1 85 421 0.25 1.25 0.500 17 4 A2 85 436 0.27 ' 0.520 A3 86 447 0.43 0.656 A4 86 457 0.75 0.866 A5 86 459 0.82 0.906 B 1 87 440 0.30 0.548 B2 88 445 0.49 0.700 B3 88 454 0.51 0.714 B4 89 459 0.54 0.735 B5 89 461 0.65 0.806 C1 89 435 0.31 0.557 C2 90 442 0.46 0.678 C3 449 0.43 0.656 C4 454 0.45 0.671 C5 458 0.52 0.721 D1 410 0.31 0.557 D2 437 0.42 0.648 D3 439 0.45 0.671 D4 441 0.49 0.700 D5 444 0.64 0.800 E1 420 0.17 0.412 E2 430 0.32 0.566 E3 437 0.38 0.616 E4 439 0.51 0.714 E5 443 0.72 0.849

87.33 442.28 1.25 16.765 17.00 4.00 Vm(ft3) Initial 831.60 % N2 (BY D/FFERENCE) 79.00

Final 869.87 Total 38.27



## 18

~ 

# J

~ D

# t ~
~
~

. :•I ~ 

## ISOKINETIC DATA AND CALCULATIONS

DATE 05/15/97 - SOURCE KILN #3 RUN #6 PO/NT # Tm Ts dp dH SORT DP % 02 % CO2 A 1 87 420 0.30 1.25 0.548 17 4 A2 87 421 0.37 ' 0.608 A3 87 423 0.48 0.693 A4 87 437 0.65 0.806 A5 87 439 0.71 0.843 B 1 88 426 0.38 0.616 B2 89 438 0.45 0.671 B3 89 440 0.46 0.678 B4 90 443 0.49 0.700 B5 92 445 0.55 0.742 C1 92 420 0.15 0.387 C2 92 428 0.38 0.616 C3 434 0.36 0.600 C4 443 0.37 0.608 C5 450 0.48 0.693 D1 436 0.13 0.361 D2 442 0.32 0.566 D3 447 0.38 0.616 D4 450 0.42 0.648 D5 450 0.50 0.707 E1 420 0.14 0.374 E2 427 0.25 0.500 E3 435 0.30 0.548 E4 435 0.33 0.574 E5 440 0.51 0.714

88.92 435.56 1.25 15.418 17.00 4.00 Vm(ft3) Initial 870.10 % N2 (BY D/FFERENCE) 79.0

Final 909.81 Tota1 39.71



### 19 

## _J , 6 

## ~ /

# I METHOD 26 EMISSION RATE CALCULATIONS Hydrogen Flouride Emission Rate SECTION A: STANDARD VOLUME CALCULATION Vm std = Y X Vm X (Tstdrrm) X (Pbar/Pstd) WHERE: Vm std = DRY VOLUME AT STANDARD CONDITIONS, DSCM Y = METER CALIBRATION FACTOR, VOST#2 0.96 Vm = METER VOLUME AT METER CONDITIONS, LITERS Tstd = STD TEMPERATURE, DEG KELVIN, 293 Tm = KELVIN TEMPERATURE AT METER Pbar = BAROMETRIC PRESSURE, MM HG Pstd = STANDARD PRESSURE, MM HG 760 CLIENT:
' BORALBRICK Y FOR VOST #1 0.928 SOURCE: DATE- 5/14/97 & 5/15/97 STACK I.D. RUI4 A Vm, litem Tm, F Pbae, In. Hg Vm std M3 WOOD MOLD 1 60.13 72.6 29.25 0.0559 WOOD MOLD 2 120.18 81.8 29.25 0.1099 WOOD MOLD 3 12038 84.2 29.25 0.1101 KILN #3 4 119.30 75.21 29.10. 0.1062 KILN #3 5

61 121.00 85.81 29.101 0.1056 KILN #3 119.00 87.81 29.10 0.1035 SECTION 13: CALCULATION OF EMISSIONS, LBS/HR Production Rates, TPH

CONCENTRATION Wood Mold 8.05 C= M /Vrn std Kiln #3 9.81 WHERE C=CONCENTRATION OF HF, MGIDSCM M=MASS OF HF, MG Vm std= SAMPLE VOLUME, DSCM RUN.#,: VM 

### 3w MASS 

### c FLOW.'... =-EMRT EMRT STACK I.D. DSCM MG MGIDSCM SCFM LB R LBS/TON WOOD MOLD 1 0.0559 2.32 41.47 9183 1.43 0.177 WOOD MOLD 2 0.1099 11.6 105.56 10311 4.08 0.507 WOOD MOLD 3 0.1101 11.7 106.31 10464 4.17 0.518 KILN #3 4 0.10621 9.961 93.771 15193, 5.34 0.544 KILN #3 5 0.10561 10.71 101.291 155251 5.89 0.600 .KILN #3 

# 1 6 0.10351 10.61 102.421 143541 5.51 rzra



### plel

.. I 

# A9-

# 0
~

~

i



### ~ ;j


## lJ

~



# ~

~ h~
L.7 

## METHOD 26 EMISSION RATE CALCULATIONS Hydrogen Chloride Emission Rate SECTION A : STANDARD VOLUME CALCULATION Vm std = Y X Vm X(Tstd/Tm) X(Pbar/Pstd) WHERE: Vm std = DRY VOLUME AT STANDARD CONDITIONS, DSCM Y= METER CALIBRATION FACTOR, VOST#2 0.96 Vm = METER VOLUME AT METER CONDITIONS, LITERS Tstd = STD TEMPERATURE, DEG KELVIN, 293 Tm = KELVIN TEMPERATURE AT METER Pbar = BAROMETRIC PRESSURE, MM HG Pstd = STANDARD PRESSURE, MM HG 760 CLIENT: ;.:. :.:::;:. . BORAL BRICK _`: . Y FoR Vosr rt 0.928 SOURCE: DATE: ; '- `"' . ': 5/14/97 & 5/15197 STACK I.D. RUN # Vm, Iiters . Tm, F' .: Pbar, ln. Hg Vm std M3 WOOD MOLD 1 60.13 72.6 29.25 0.0559 WOOD MOLD 2 120.18 81.8 29.25 0.1099 WOOD MOLD 3 120.88 84.2 29.25 0.1101 KILN #3 4 119.301 75.2 29.10 0.1062 KILN #3 5 121.001 85.81 29.10 0.1056 KILN #3 6 119.001 87.81 29.10 0.1035 Production SECTION B: CALCULATION OF EMISSIONS, LBS/HR Rates, TPH

CONCENTRATION Wood Mold 8.05 C= M Nm std Kiln #3 9.81 WHERE C=CONCENTRATION OF HCI, MG/DSCM M=MASS OF HCI, MG Vm std= SAMPLE VOLUME, DSCM

':•_ . RUN #. . . . .. : _ `- Vm std MASS : C . ,. ;.:. FLOW - .'"

EMRT EMR STACK I.D. DSCM MG ":".. . MG/DSCM SCFM LBS/HR ..LBS/TON WOOD MOLD 1 0.0559 0.289 5.17 9183 0.18 0.022 WOOD MOLD 2 0.1099 1.04 9.46 10311 0.37 0.045 WOOD MOLD 3 0.1101 1.2 10.90 10464 0.43 0.053 KILN #3 41 0.10621 0.788 1 7.42 1 15193 0.42 0.043 KILN #3 51 0.10561 0.8741 8.271 155251 0.48 0.049 KILN #3 61 0.10351 0.8381 8.101 143541 0.44 0.044


### 21

~ 

### ~ 

## 3

## S02 EMISSION RATE CALCULATION-IMPINGER METHOD CUENT.. .

. :.... :: .. . , ~ . . .:.:: BORAL BRICK - coC.anOnr. VAN WYCK, SOUTH CAROLINA soURCE. . WOOD MOLD AND KILN #3 STACKS DATE. 5/14/97 & 5/15/97 C S02(Ib/Pt3) =((K)(N)(Vt-Vtb)(VsoWa))/Nm std C S02(Ib/ft3): CONCENTRATION OF SULFUR DIOXIDE COMPOUNDS, Ib/ft3

K:7.065E-05 ib/meq N: NORMALITY OF TITRANT .00962 0.0096 0.0096 Vt (avg):AVG. VOLUME OF TITRANT FOR ALIQUOT, 2 trlals Blank 1 Blank 2 Avg. Blank Vtb: VOLUME OF TITRANT FOR BLANK 0.03 0.03 0.03 Vsol: VOLUME OF SOLUTION 0.03 0.03 0.03 Va: VOLUME OF ALIQUOT TITRATED - Vm std:STANDARD GAS SAMPLE VOLUME, L
STACK RUN #. . V AVG -ml Vtb ml V sol ml . Va rni . Vm std-L C S02-Ib/ft OOD MOLD 14 0.03 0.03 100 201 19.20 O.00E+00 OOD MOLD 1 el 0.44 0.03 100 201 20.42 1.93E-06 OOD MOLD 24 0.2 0.03 100 20 18.74 8.71 E-07 OOD MOLD 281 0.37 0.03 100 20 18.26 1.79E-06 OOD MOLD 34 0.49 0.03 100 20 18.89 2.34E-06 OOD MOLD 34 2.03 0.03 100 20 19.14 1.00E-05 ILN #3 44 0.05 0.03 100 20 18.93 1.01 E-07 ILN #3 4EI 0.03 0.03 100 20 19.80 O.00E+00 ILN #3 54 0.03 0.03 100 20 18.95 O.00E+00 ILN #3 5EI 0.37 0.03 100 20 19.77 1.65E-06 ILN #3 6 0.19 0.03 100 20 19.52 7.87E-07 ILN #3 6EI 0.271 0.031 100 20 19.65 1.17E-06 

## IF

I



## 22

. 

## ~ 

# ;_J

# d ~

~

~ ~ EM/SSION RATE CALCULATION E S02 =(C S02)(Q std dry)(60) WHERE: E S02=EMISSION RATE OFSULFUR DIOXIDE, LB/HR O std dry=STANDARD EXHAUST FLOW RATE, CFM Production Rates, TPH Wood Mold 8.05 Kiln #3 9,81
STACK RUN # C.S02-Ib/it3.. ..'.. - O std d ry , scfm E S02= Ibs/hr ' S02-ppm ` EMRT,Ibs/to OOD MOLD 1A O.00E+00 9183 0.000 0.0 0.000 OOD MOLD 181 1.93E-06 9183 1.062 11.7 0.132 OOD MOLD 2A 8.71 E-07 10311 0.539 5.3 0.067 OOD MOLD 281 1.79E-06 10311 1.106 10.8 0.137 OOD MOLD 3A 2.34E-06 10464 1.468 14.1 0.182 OOD MOLD 3EI 1.00E-05 10464 6.299 60.6 0.783 ILN #3 JA 1.01 E-07 15193 0.092 0.6 0.009 ILN #3 481 0.00E+00 15193 0.000 0.01 0.000 ILN #3 5A O.00E+00 15525 0.000 0.0 0.000 ILN #3 5EI 1.65E-06 15525 1.538 10.0 0.157 ILN #3 6 7.87E-07 14354 0.678 4.81 0.069 ILN #3 6EI 1.17E-06 1 14354 1 1.010 7.11 0.103



## 23 td

! 

# ~

, a~~{

~ 

## STANDARD VOLUME CALCULATIONS

CLIENT: . ` . = BORAL BRICK DATE: - 5/14/97 & 5/15/97 STANDARD VOLUME CALCULATION Vm std = Y X Vm X(TstdlTm) X(Pbar/Pstd) WHERE: Vm std = DRY VOLUME AT STANDARD CONDITIONS, DSCM Y= METER CALIBRATION FACTOR, VOST#3 1.00 Vm = METER VOLUME AT METER CONDITIONS, LITERS Tstd = STD TEMPERATURE, DEG KELVIN, 293 Tm = KELVIN TEMPERATURE AT METER Pbar = BAROMETRIC PRESSURE, MM HG Pstd = STANDARD PRESSURE, MM HG 760
STACK RUN # Vm, liters . Tm, F Pbar, In. H. Vm std M OOD MOLD 14 20.10 78.3 29.25 19.20 OOD MOLD 1 El 21.65 85.0 29.25 20.42 OOD MOLD 24 20.05 90.0 29.25 18.74 OOD MOLD 2EI 19.50 89.0 - 29.25 18.26 OOD MOLD 34 20.10 87.0 29.25 18.89 OOD MOLD 3EI 20.40 87.8 29.25 19.14 I LN #3 44 19.85 76.3 29.10 18.93 ILN #3 4EI 20.80 77.3 29.10 19.80 ILN #3 54 20.20 85.0 29.10 18.95 ILN #3 5BI 21.10 85.8 29.10 19.77 ILN #3 .64 20.80 85.0 29.10 19.52 ILN #3 6 21.101 89.01 29sl0l 19.65 --,

I k~



## 24 

# s

# d
~ 

# e NOMENCLATURE

AN (square inches), Cross sectional area of nozzle AS (square feet), Cross sectional area of stack CP Pitot tube calibration coefficient % EA Percent Excess Air F (scfd/10 6 BTU), F factor DH (inches of water) Average orifice meter reading HI (million BTU/hr), Heat Input Rate % I Percent Isokineticity M (lb/lb mole), Molecular Weight of wet gas % M Percent Moisture MD Mole fraction of dry gas MWD (Ib/Ib mole) molecular weight of dry gas N DP Number of sample points P ATM (in Hg), Local atmospheric pressure PM (in Hg), Absolute pressure in dry gas meter PS (in Hg), Absolute stack pressure PS GAUGE (inches of water), Measured static stack pressure gauge P STD (29.92 in Hg), Standard pressure PMRC (lb/hr), Pollutant mass rate based on concentration PMRU (lb/million BTU), Specific emission rate


## 25 

# p- -)

# ~ ~ NOMENCLATURE (CONTINUED)

~ DP Velocity (inches of water), pressure .


### ~ QS (cubic feet/min.), Actual stack volume flow rate

Q STD (cubic feet/min.), Stack volume flow rate at standard

conditions TM (degrees R), Average dry gas meter temperature'

.

. •:i c 

### ~ TS (degrees R), Average stack temperature

; 

### T STD (528 degrees R), Standard temperature

.. 

### VLQ (ml), Liquid volume _ --., 

### VM (cubic feet), Sample volume measured by dry gas meter

~ 

### J VM STD (cubic feet), Sample volume at standard conditions

VS (ft/sec), stack velocity VV STD (cubic feet), Volume of water vapor collected,

~ 

### conrected to standard conditions

WT (gm), Total weight of particulate collected TIME (MIN.) Duration of test



## 26
d`~~

## CALCULATION FORMULAE

1. Absolute pressure in dry gas meter

PM = P ATM + DH/ 13.6 

## 2. Absolute Stack Pressure

PS = P ATM + PS gauge/13.6 3. Sample volume at standard conditions

VM STD =(GAMMA FACTOR, 0.983)(VM) (T STD/TM) (PM/P STD) 4. Volume of water collected, corrected to standard conditions

VV STD = (.00267) (VLQ) (T STD/P STD) 5. Total sample volume at standard conditions

V STD = VM STD + VV STD t~ 

## l 6. Percent moisture in stack gas 

# ~ %M = (100) (VV STD)/V STD

7. Mole Fraction of dry gas

MD = (100-%M)/ 100 8. Molecular weight of the wet gas

M = (MWD) (MD) + 18(1-MD) 9. Stack velocity

VS = (85.48)(CP)((TS/(PS)(M))"((Sum DP) v N DP)) 10. Stack volume flow rate

QS = (60)(VS)(AS)


## 27 

# a- I
~~



### _; 

## J 

## CALCULATION FORMULAE (CONTINUED)

11. Stack volume flow rate, standard conditions including . moisture 

### Q STD = (T STD/P STD)(PS/TS )(QS) 12. Stack volume flow rate standard conditions dry

Q STD DRY = (Q STD)(1-%M) ' 13. Pollutant mass rate, concentration basis

PMRC = (.1323)(WT)(Q STD)/V STD 14. Pollutant mass rate ratio of areas basis

PMRA = (.1323)(WT)(AS)(144)/(Time)(AN) 15. Percent Isokineticity

%I = (100) (PMRA)/PMRC 16. Average pollutant mass rate

PMR AVG = (PMRA + PMRC)/2 17. % Excess Air

%EA = (100) (%oxygen - (.5)(%carbon monoxide) (.264)(%nitrogen) - %oxygen + (.5) (%carbon monoxide) 18. Heat input rate

HI = ((.6) (Q STD DRY)/k)((20.9 - %oxygen)/20.9) 19. Specific emission rate

PMRU = PMR AVG/HI

28 

### i

## DATA SHEETS Woodmold Exhaust Stack Traverse Data Sheets Method 4 Sampling Data Sheets ' Method 26 Sampling Data Sheets Method 6 Sampling Data Sheets Source Test Survey

,nd i

~
-,
~ 

### Kiln #3 Exhaust Stack Traverse Data Sheets _ Method 4 Sampling Data Sheets Method 26 Sampling Data Sheets Method 6 Sampling Data Sheets Source Test Survey PLANT PROCESS DATA Kiln Throughput and Records -
Method 26 Laboratory Report u ~ 

### Impinger Data Sheet Calibration Information

~ ;
I



### 29 

# 31~



# I 

# w

~ cm
, 

# ~

l. t. (A-; ~ g. ) _ +460= T, (Rankin) 

### 2. Duct.Area=A= Ft 2 3. P.=P b , = ±SP in. Hg. 

### 4. Rho,* ( 530/T,) * (P,/29.92 ) = lbs/ft' 

### 5.K=constant= 1096.5/((G.D.) 1 ")=

~ 

### 6 . Velocity=K*F j * (V D avg) 1/2 £t/min. 7. VOLLTME ( avg )= A* V= ' 

### ACFM 8 . SCFM=Volume* ( 530/T.) * (P./29. 92) _



### SCFM(wet) Rho= specific weight of Air= 0.075 lbs/ft'

~ 

### != angle in degrees to yield _I • 

### dP of 0 SKETCH



## 3Z 

# ~ ANALYTICAL TESTING CONSULTANTS, INC. KANNAPOLIS, N.C. ATLANTA, GEORGIA 

# 8 TRAVERSE DATA AND FLOW COMPUTATION 

### CLIENT 

# 46"-.'a/ DATE ' LOCATION SOURCE TEST TEAM 

### Il4/ X/L RUN # 

## l 

# .. __.._______________________.._____------ K Pbar a9~.~ Dry Bulb ( ° F) Wet Bulb ( ° F) -+ ` Time /D%od .4*#! SP ( "Hg/"WG) -0•10 ~ v•c

. Pitot Type 

### - .SAtZ Pitot # 

## s7 Fs for Pitot 0 •8

~ 1 

### Stack I.D. l9 X d. 4


### TRAVERSE POINT 

### V a

inches 

### SQ. ROOT

V a 

### STACK

TEMP ., ° F 

### dP

0 ° REF . 

### ANGLE'

( 0 dP ) 

## &.ID .Z9 ~ 

## 0. o J f , .a D.! o 300 o, a z 3 3 0, 07 3oy p.o/ 

### y D•oy I 3oS 6

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## 1
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### 3 •o/ y 

## F/ 0. .2 7 I 3/8
. 

# 319 v o 3 0, ff /p G o y o, oG 319 0•0/ ~ S~

## ANALYTICAL TESTING CONSULTANTS, INC. KANNAPOLIS, N.C. ATLANTA, GEORGIA

TRAVERSE DATA AND FLOW COMPUTATION 

### CLIENT DATE 7 

### LOCATION Pa 

### 44 fS.

~ 

### . SOURCE
~ a~ ~~ 

### 515•..,E TEST TEA 

## M /L RUN # 

## .Z

------------------------------------------------------------------- Pbar Dry Bulb ( ° F) Wet Bulb ( ° F) 

### • Time 

### /: ?-o SP ("Hg/"WG) 

### —O./G f ''~ G Pitot Type 

### S,W''C Pitot # 

### Y'7 Fs for Pitot d• d f/ Stack I.D. JQXl ~ 

# --------------..---....-----------..-------'

~ 

# _..---------..---..---....--- TRAVERSE POINT 

### V n inches 

### SQ. ROOT

V p 

### STACK

TEMP ., ° F 

### dP ..

0 ° REF. 

### ANGLE'

( 0 dP ) 

## / v.3 ~ 

## o/ ,? p , 3 0 1 1 ;0 7 

## 3 d. A s - I 3i s - D• v, ~ 

### 30

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### o, / u p 33 0 l. t, (Avg. ) _ +460= T, (RanKin) 2. Duct Area=A= Ft 2 3. P s =P 5e1 a'SP iri. Hg. 4. Rho,* ( 530/T,) * (P,/29.92 ) = lbs/ft' 

### S.K=constant= 1096.5/((6.D.) 1/2 )= 6. Velocity=K*F,* (V D avg)'" ft/min. 7. VOLUME ( avg )= A* V= . ACFM 8. SCFM=Volusne* ( 530/T,) * (P,/29 . 92 ) _



### SCFM(wet) Rho= specific weight - of Air= 0.075 lbs/ft' 

### != angle in degrees to yield dP of 0 SKETCH



# ~ FORM 15

# ~ ANALYTICAL TESTING CONSULTANTS, INC. KANNAPOLIS, N.C. ATLANTA, GEORGIA 11 TRAVERSE DATA AND FLOW COMPUTATION 

### CLIENT gorM.l 8ric,F 

### DATE 

## _/p z 

# ~ LOCATION Viy ~ . t 

### SOURCE GCfpe,.l ~ f fT4rlf 

### TEST TEA 

## M w S,e RUN # 

# ----------------- _ ------------ _ ---------------

____ ~ 

# _____.... ~ Pbar
~ 

## Q• ~ 

## S Dry Bulb (°F) Wet Bulb (°F) Time 3•'/J' 401 " 

### SP ("Hg/"WG) •O./0 - " 4 '- 4 

### Pitot Type S.OEC 

### Pitot Fs for Pitot d• B4-* 

### Stack I.D. 39 1 XII

~~ 

# _-.._-__ ____..___..____..___..__....________ _.._........_-_...._.........._..........

~ 

### TRAVERSE POINT V p

inches SQ . ROOT

V D STACI{

TEMP ., °F dP ': .,

0 0 REF. ANGLE'

( 0 dP ) / 

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# 2 a, e I /I 3 a•A!' y 

## 4 I 31 y

0•17 d•o8 ( ~ 3/~ 

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## y ct

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### . t, vg. = +490= T, Ra in 

### 2. Duct Area=A= Ft 2 3. P s =P b . ±SP in. Hg. 4. Rho,* (530/T,) * (P./29.92) = lbs/ft' 

### 5.K=constant= 1096.5/((G'.D.) 1/2 )= 6 . Velocity=K*F,* (V D avg) 1/2 ft/min. 

### 7.VOLUME(avg)= A*V= ' 

### ACFM 8.SCFM=Volume* (530/T.) * (P,/29.92)=



### SCFM(wet) 

### Rho= specific weight of Air= 0.075 lbs/ft' 1= angle in degrees to yield dP of 0 SKETCH

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# ANALYTICAL TESTING CONSIJLTANTS SOURCE SURVEY , AND DESCRIPTION SYSTEM TYPE: BOII.ER 'f 

### PROCESS • 

### OTHER NARRATIVE DESCRIPTION: I_i 

### ~ 4 S 

### ~ aLIC —

PURPOSE OF TESTING: W ._ COMPLIANCE EVALUATION PROCESS RATE OR CAPACITY: DETERMINED BY: Pl4K4 'Re c.e"1 f 

### CONTROL EQUIPMENT: SCRUBBER ESP BAGHOUSE OTHER IJoN 6- CONTROL EQUIPMENT OPERATING PARAMETERS: PRESSURE DROP OTHER N/14 

### SAMPLING LOCATION DATA: DISTANCE DOWNSTREAM FROM FLOW DISTURBANCE: gt 7G " NATURE OF DISTURBANCE: BEND, FAN, EXPA.\iSION, BYPASS D C 

## OTHER DISTANCE UPSTREAM FROM FL A\CE: l g. 7S 

### NATURE OF DISTURBANCE:ACK EXHA SFAN, EXPANSION, DUCT, OT ER INDIVIDUAL STACK COMMON STACK 3. X 3 S 4 u ai G 

### STACK DIAMETER OR DIMENSIONS: NUMBER OF PORTS: S 

### POIl\
- I'S PER PORT: S 

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### ESTI1ViATED TEMPERATURE: 3 a S ~ 

### ESTL'vIATED MOISTURE: GAS COMPOSTTION BY: XYGEN METER, INSTRUMENTAL, LABORATORY INFORMATION: SAMPLE RECOVERY:ATC LABORATORY CLEAN FIELD AREA ~ 

### ATC VAN OTHER SAMPLE SHIPMENT: ATC VAN OTHERps SAMPLE ANALYSIS: ATC OTHER P.sol„ }iorJ A y~ lu ~ tc.s ~=~J 

### c.. FILTER MATERIAL: GELMAN A/E R' WHATMAN 934AH OTI-IER

~C ~

### 1. t, (Avg. ) _ +460= T, (RanKin)



### 2. Duct Area=A= Ft = 3. P,=P yar 

### + SP in. Hg. 4. Rho,* (530/T,) * (P,/29.92)= lbs/ft 3 5. K=constant= 1096. 5/ ((G. D. -' 6. Velocity=K*F,* (VDavg) 1/2 ft/min. 7. VOLUNDr ( avg )= A* V= ACFM 8. SCFM=Volume* (530/T,) * (P,/29.92) _



### SCFM(wet) Rho= specific weight.`of Air= 0.075 lbs/ft' 

### != angle in degrees to yield dP of 0

~ 

# 1 . SKETCH



# Ub 

# ~ ANALYTICAL TESTING CONSULTANTS, INC. KANNAPOLIS, N.C. ATLANTA, GEORGIA

TRAVERSE DATA ,A.ND FLOW COMPUTATION 

### CLIENT 

### ~ r... 

### ~~ r.'c 

### ~ _ DATE S /t !7 

### LOCATION 11,2a GtJ„t,/_ r C , 

### SOURCE •'/.. •4 ~ ~ 

### TEST TEAM



## nW, S'ie RUN ## 

## ~

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### ;1 /d Dry Bulb ( ° F) Wet Bulb ( ° F) Time J.'iSAA

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### 50 ~~ 

### Pitot # s 3 

### Fs for Pitot _ D• j f or 

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## ANALYTICAL TESTING CONSULTANTS, INC. KANNAPOLIS, N.C. ATLANTA, GEORGIA

TRAVERSE DATA AND FLOW COMPUTATION 

### C L I ENT DATE s"~~s'~ 97 

### ~ r~ 

### LOCATION SOURCE .0' l TEST TEAM S.0 

### RUN # S

------------------------------------------------------------------- Pbar . 2 9.10 _ _ Dry Bulb ( ° F) 'Wet Bulb ( ° F) Time SP (."Hg/"WG) 

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## s,w" 0, 72. 1. t, (Avg. ) = +460= T, (Rankin) 

### 2. Duct Area=A= Ft 2 3. P s =P b , r ±SP in. Hg. 

### 4. Rho,* ( 530/T,) * (P,/29.92) = lbs/ft' 

### 5.K=constant= 1096.5/((G.D.) 112 )= 6 .Velocity=K*F,* (V D avg)' 12 ft/min. 

### 7.VOLUME(avg)= A*V= ACFM 8 .SCFM=Volume* (530/T,) * (P,/29.92) _



### SCFM(wet) Rho= specific weight of Air= 0.075 lbs/ft' 

### != angle in degrees to yield dP of 0 SKETCH 

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# ~ ANALYTICAL TESTING CONSULTANTS, INC. KANNAPOLIS, N.C. ATLAIJTA, GEORGIA 

# ~ TRAVERSE DATA AND FLOW COMPUTATION 

### CLIENT DATE 

## _0"/! ~ 

# ~ LOCATION (~~ .~ ~ t/,, ~ S. G 

### SOURCE K. a IA 4 7 TEST TEAM 

## r.0 RUN #

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### 8.SCFM=Volume*(530/T.)*(P,/29.92)=

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SOURCE SURVEY AND DESCRIPTION SYSTEM TYPE: BOILER 

## ~ PROCESS OTHER NARRATIVE DESCRIPTION: X ; /N Z- 3

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## ~ COMPLIANCE EVALUATION PROCES S RATE OR CAPACITY: 

### t' 10 T' P H DETERMINED B Y: 

### T '4 c o. d; CONTROL EQUIPMENT: SCRUBBER ESP BAGHOUSE OTHER Af Olv& CONTROL EQUIPMENT OPERATING PARAMETERS: PRESSURE DROP N *+ 

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### 2733 LEE AvnvUE SarrFoxn, NC 27330 (919) 774-5557



# ANALYTICAL REPC)RT

, 

# • HCL (EPA METxoD 26A)

~ 

# 1 • HF (EPA 1VIETxoD 26A)
~

., . 

### 4:I CLTENT: ANALYTICAL TBSTING CONSULTANTS

a^c"• ~ t""""'.S ~" ~K~ ,,.. ~ .. .,.. .~ .FC_ 

# RFA#•

•. 

# ME

# ~

RESOLUTION ANALYTICS, INC. Specialists in High PerPotmance Liquid ChromatograPhY 

# REPORT SUMMARY RFA#: 77 

# 1

SAMTLE ID . I HCl HF
0.1 N H Z SO a Bt,ANK < 0.00631 mgs < 0.154 mgs 1-HCL 1&2 0.289 mgs 2.32 mgs 1-HCL 3RD nop < a.00947 mgs < 0.232 mgs 2-HCL 1&2 1.04 mgs 11.6 mgs 3-HCL 1&2 1.20 mgs 11.7 mgs 4-HCL 1&2 0.788 mgs 9.96 mgs 4-HCL 3RD IIvv < 0.00610 mgs < 0.149 mgs 5-HCL 1&2 0.874 mgs 10.7 mgs 6-HCL 1&2 0.838 mgs 10.6 mgs FIELD SPIKE -1 .4.83 mgs 3.91 mgs (94.0% Rec) (92.9% Rec) 

### FIELD SPIKE -2 4.99 mgs 3.80 mgs

' (97.1 % Rec) (90.2% Rec) 

# J,' ~off ?-; ; 

# ANALYTICAL TESTING CONSULTANTS, INC.

CHAIN OF CUSTODY RECORD 

## • ni CLIENT: PLANT LOCATION:

NOTE: PLEASE MARK LIQUID LEVEL ON ALL SAMPLE BOTTLES WITH GREASE PENCiL.

SEAL TIGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL. 

# rovq ~ 

# U

# DATA SHEETS 

# 0 ANALYTICAL 

# Q m , I ► ► ~ 

# „ . .

b~

# 0
~ ~ Ar®alvtical Narrative RFA # 

## Bora1 Brick Page 1 of I

Client/Plant Name: Analvtical Testing Consultants. Inc. 

### Date Rec'd in lab : 5/21/97



### Analyst: JBN 

### Date of Analysis: 6/03/97 

### Analysis Method: EPA Method 26 

### Analyte(s): HCI. HF 

### Sample Matrix & Components: 0.1 N H 2 SO 4 + DI H 2 0 rinses 

### Summary of Sample Prep: Samples were final volumed in the laboratory by JBN. No further ~ pretreatment of the samples was required. Field Spike samples were diluted 5-fold for HC1 analysis'.

- 

### J Summary of Instrumentation: "Clyde" PRP-X100 Column #2306 50 }:l Inj (HC1), 10 K1 Inj (HF) Eluent: 4mM Phthalic Acid pH 3.6 . Flow Rate: 2 mis/min Gain 0.2 uS/cm (HC1); Gain 0.4 μS/cm (HF) Temp: 40 ° C Analytical Detection Limit(s): 0.211 ppm HCl 5.15 ppm HF J Summary of QA Audit Sample Aaalysis:
~ For the HC1 analysis, a QA audit of 20.0 ppm chloride was prepared ~ and analyzed in the saine manner as the samples. A+0.18$ deviation from the expected value was obtained.
~ For the HF analysis, a QA audit of 100 ppm fluoride was prepared and analyzed in the same manner as the samples. A+0.78$ deviation from the expected value was obtained. 

### Summary of Sample Spike Analysis: For the HC1 analysis, 0.8 mis of sample 1-HC1-1 (IMP 1,2) was spiked ~ with 0.8 mis of a 5 ppm chloride standard. A 92.4$ recovery was obtained. For the HF analysis, 0.5 mis of sample 1-HC1-1 (IMP 1,2) was spiked

- ~ with 0.5 mis of a 50 ppm fluoride standard. A 94.6$ recovery was obtained. 

### Miscellaneous Comments Reaardine Samnle Analvsis: (Note unusual catch weights, interferences, odd 

# ~ sample behavior, and steps taken to confirm unusual results. Also note any deviations from standard

analytical procedures, together with justification and possible affect on results. Specify samples when applicable.) Low catch weights for both HC1 and HF for sample 1-HC1-1 (IMP 1,2) were confirmed by matrix spiking.



### ' Confirmation of Data Review:

J 

### Lab QA Officcr Signature Date

### Hydrogen Chloride Analytical Data Sheet

Client Name: Analytical Testing Consultants, Inc. Job Num. 52197 File Pathway: C:U0BSIATC1521971HCL.WB1 File: HCI Analyst J B Nemet Date: 06/02/97

Chloride Standard Calibration Curve by Llnear Regression 96 , CI- Calculated Deviadon Conc. Standard Areas Average % Std Conc. from (pp m) In'.1 In'.2 Area Diff. m Actuai 1.0 27860 27942 27901 0.15% 1.07 6.90% 5.0 130289 131444 130867 0.44% 4.96 -0.89 0 /o 10.0 262791 263529 263160 0.14 0 /* 9.95 -0.51%

~ 25.0 662219 663007 662613 0.06% 25.03 0.11 % 

# i Standard Curve S : 26493 Y-Int 420 LoD m: 0.205 Field Samples in: 0.1 N 112SO4 Sample HCI Expeeted FTeld Sample Inj. I. Inj. 2 Average % Dilution Volume Catch Fld Spk Spike ID Area Area Area DiS Factor (mis) (mgs) Cateh Recovery 0.1 N H2SO4 < 5000 < 5000 < 5000 0.00% 1 30 < 0.00631 1-HCL-1 (1,2) 127724 128451 128088 0.28% 1 58 0.289 1-HCL-1 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 45 < 0.00947 1-HCL-2 (1,2) 484813 484920 484867 0.01% 1 55 1.04 1-HCL-3 (1,2) 524632 523290 523961 0.13% 1 59 1.20 _ 1-HCL-4 (1,2) 382860 382224 382542 0.08% 1 53 0.788 1-HCL-4 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 29 < 0.00610 1-HCL-5 (1,2) 351206 351934 351570 0.10% 1 64 0.874 1-HCL-6 (1,2) 359262 359121 359192 0.02 0 /o 1 60 0.838 FIELD SPIKE -1 461063 459822 460443 0.13% 5 54 4.83 5.14 94.0% FIELD SPIKE -2 452149 449709 450929 0.27% 5 57 4.99 5.14 97.1% Average % Expeeted Calculated Percent In'. 1 In'. 2 Area Dev. ppm Cl- ppm CI- DifE IN-HOUSE 530844 529947 530396 0.08% 20.0 20.0 0.18%

. - ~ :-• : 8P 1iMTRJ;X >_ . UCE' ~ : Average % Expected Calculated % Sample I.D. In'. 1 In'. 2 Area Dev. ppm Cl- ppm Cl- Recov ery 1-HCL-1 (1,2) 125023 124847 124935 0.07% 2.50 2.31 92.4 0 /o Note: 0.8 mis of the above sample was spiked witll

0.8 mis of a 5 ppm chloride standard. Prtitbg f)ate 02,lun-97 PdnOng Time 01:07 PM



## ~~9 

# ~ ~ ~ .~

; 

## ~

~ 

# Chloride



# Calibration Curve
700000

500000
~ ~ 

# 0400000 

# CU 

# ~ 300000

~ 

## .. 

# < 200000 100000 

## 0 

# 0 5 10 15 20 25 

# Concentration 

# (ppm)

J

~~9 

### H dro en Fluoride Anallqical Data Sheet Client Name: Analytical Testing Consultants, inc. Job Num. 52197 File Pathway: C:IJOBSIATC1521971HF.WB1 File: HF Analyst - J B Nemet Date: 06l03/97

Fluoride Standard Calibration Curve by Unear Regression %. F- Calculated Deviation Conc. Standard Areas Average % Std Conc. from (pp m ) In'.1 In'.2 Area Diff. m Actual 10.0 14489 14430 14460 0.20% 10.55 5.48% 50.0 79572 83420 81496 2.36% 50.65 1.30% 100 158517 162726 160622 1.31% 97.98 -2.02% 200 320273 344775 332524 3.68% 200.82 0.41% Standard Curve Slo : 1672 Y-Int: -3173 LoD m: 4.89 Fieki Sampies in: 0.1 N H2SO4 Sample HF Expected Field Sample Inj. 1 Inj. 2 Average % Dilution Volume Catch Fld Spk Spike ID Area Area Area Diff. Factor (mis) (mgs) Catch Recovery 0.1 N H2SO4 < 5000 < 5000 < 5000 0.00% 1 30 < 0.154 1-HCL-1 (1,2) 62046 58562 60304 2.89 0 /o 1 58 2.32 1-HCL-1 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 45 < 0.232 1-HCL-2 (1,2) 340646 320078 330362 3.11% 1 55 11.6 1-HCL-3 (1,2) 309356 314604 311980 0.84% 1 59 11.7 _ 1-HCL-4 (1,2) 294663 295763 295213 0.19 0 /a 1 53 9.96 1-HCL-4 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 29 < 0.149 1-HCL-5 (1,2) 267208 257917 262563 1.77% 1 64 10.7 1-HCL-6 (1,2) 274064 281260 277662 1.30% 1 60 10.6 FIELD SPIKE -1 111217 112431 111824 0.54% 1 54 3.91 4.21 92.9% FIELD SPIKE -2 105263 100006 102635 2.56% 1 57 3.80 4.21 90.2% AUDIT REPORT Average % Expected Calculated Percent .

r Inj. 1 Inj. 2 Area Dev. ppm F- ppm F- Diff. r IN-HOUSE 163033 167573 165303 1.37% 100 101 0.78% 1WATRIX sPBtE=:*
~ . Average % Expected Calculated % Sample I. D. Inj. 1 Inj. 2 Area Dev. ppm F- ppm F- Recovery 1-HCL-1 (1,2) 68296 67914 —7—r--r 68105 — —T -- T

0.28% 25.0 23.6 94.6% Note: 0.5 mis of the above sample was spiked witfi

0.5 mis of a 50 ppm fluoride standard. Prtnft Dete 03Jun-97 Printing Thn 11:48 AM



# -I3

# nnI t~
~ 

# Fluoride



# Calibration CUrve
350000 300000
4 

# .., 250000 C: =3 O 200000 

# V CU 150000 L 

# Q 100000 50000 01 

## 0 50 100 150 200 

# Concentration (p-pm)

7~

# CHROMATOGRAMS

~

# .~
~

~ 

# ~

~ 

## ; ~

~ 

## iJ



## ~

'= 1 ,A "J 

### Inatrument: "Clyde - Column: Hamilton PAP-X10U 2 ~ Ux9.6 mm

Eluent: 9mM Phthalic Acid pH 3.6; Flov @ 2 mle/min; 5 pl Inj Vol Conductivity Detection Gain 0.9 pS/cm 40 C File : C:\EZCHAOM\CHAOM\15935.119 Method : C:\EZCHROM\METHODS\M26.MST ~ Sample ID e
- 1.0 PPM a Acquired : Jun 01, 1997 13:50:39

Channel A 

### C 0.01 

### 5 h



### 1 0 r d e 0.01 0

V 0 1 t 0. 00 5 a



### •m

0 5 10 15 20 Minutes



# --- Peak Name --- Aet. Time
-- Area -_ Chloride 2.88 27860

/ ~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 pl Inj Vol Conductivity Detection Gain 0.4 μS/cm 40 C File : C:\EZCHROM\CHROM\15935.002 Method : C:\EZCHItOM\METHODS\M26.MET Sample ID : 5.0 PPM a Acquired : May 30, 1997 17:36:55

Channel A 0.015

0.010

V 0 1 t 0. 005 9

~ ~~•

0 5 10. 15 20 

### Minutes

Peak Namo Ret. Time Area Chloride 2.90 130289



# li 7

# a 0

~

~ khI LV

~

~ KH

~ ~ 

## iJ


# ~

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### Inatrument: "Clyde" Column; Hn.milton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow 2 2 mla/min; 5 pl Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHFt0M\15935.003 Method : C:\EZCHItOM\METHODS\M26.MET Sample.ID : 10.0 PPM a Acquired : May 30, 1997 18:25:47

Channel A C 

### 06 h

1 0 r 05 i

d 

### e 04
03
02
01
00
ni

- 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Chloride 2.93 262791 0.
0.
V 0. O 1 t 3 0.
0 . 0 . -0.



### 'J I?

### Inatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pFi 3.6; Flov @ 2 mla/min; 5 μl I_3 vol Conductivity Detection Gain 0.4 pS/cm 40 C File : C:\EZCHItCM\CHAOM\15935.120 

### Method : C:\EZCHROM\METHODS\M26.MET Sample . ID : 1.0 PPM b Acquired : Jun 01, 1997 13:56:31

Channel A 0.015

0.010 C



### h 1 0 

### r d e



## v 0 1 t 0. 005 a

• •~~ 

# O 5 10 15 20



### Minutes

Peak Name Ret. Time Area Chloride 2.88 27942



# qy

# a ~ ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4._6 mm ..

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mla/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 {iS/cm 40 C File : C:\EZCHROM\CHROM\15935.116 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : 5
- .0 PFM b Acquired : Jua 01, 1997 10:05:59

Chanuel A 0.01 : i

0.01

V 0 1 t 0.00 

## 3m s 

# . N ••

0 5 10 15 20 Minutes

Peak Name Ret. Time Area --------------- ------ -------- Chloride 2.90 131444 ~

-10joil

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pI4 3.6; Flov @ 2 mis/min; 5 

### ul Inj vol Conductivity Detection Gain 0.4 }iS/cm 40 C File 

### : C:\EZCHROM\CHROX\l5935.117 Method : C:\EZCHROM\METHODS\M26.MET 3ample.ID :.10.0 PPM b Acquired : 

### Jun 01, 1997 10:11:51

Channel A 

# • . l5

0.010



### v 0 

### 1 t 

### 0. 005 3



### 0.000

0 5 10 Minutes 15 20

Peak Name Ret. Time Area Chloride 2.93 263529


# 0

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm _ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 μl Inj Vol Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHROM\15935.118 

# ~ Method : C:\EZCHROM\METHODS\M26.MET

Sample ID : 25.0 PPM b Acquired : Jun Ol, - 1997 11:00:44 

# ~ - 

### -1 Channel A

:•:•J '. ~

.:~

~ 

### iJ



## ~ 0.12

0.10

0.07 V G 

### 1 t 0. 05 a
;fxfN

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## rrm 5 C

h 1 a r 0 

### i

d 

### e 5

0

5

0 

### 5 10 15 20 Minutes

Peak Name Ret. Time Area Chloride 

### 2.98 663007

A92,

### Inztrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mis/min; 5g1 Inj Vol 

### Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\15935.005 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : Audit (20.0 ppm) a Acquired : ay 30, 1997 19:20:31

Channel A 

### 0.125

0.100 C

h 1 0 r 

### d e 0.075 V O 1 t 0.050 s
0.025

~ •~• 0 5 10 15 20 Minutes



### Peak Name Ret. Time Area Chloride 2.96 530844



# F3

# n 

# R

:<<



# ~ ~

~ J r, v 

# i

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## =~ ~

~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 pS/cm 40 C File : C:\EZCHROM\CHROM\52197.001 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : 0.1 N H2SO4 a Acquired : May 31, 1997 14:01:05

Channel A 0.01 5 C



### h 1 0 , r d 0.01 0 e

V 0 1 t 0.00 5 9

. .. 0

0 5 10 15 20



### Minutes

Peak Name Aet. Time Area --------------- ------ -------- 

### Chloride 2.85 3319



## ~~0.1

0.1

Aai; 

### V 0 1 t 0.0 s
0.0

0.0 25 F

1 

## u C o h 

## rl 00 1 0 

## d r e i d 75 e

50

25

00 

# i , f

~ ~ L L i Instrument: "Clyde" Column: Ham.ilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.002 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 1 a Acquired : May 31, 1997 14:49:59

Channel A

0 5 10 15 20



### Minutes

Peak Name Ret. Time Area --------------- ------ -------- 

### Fluoride 2.18 552589 

### Chloride 2.92 127724



# g~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 5 

### ul Inj Vol 

### Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.003 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RtJN 1 BT a Acquired : May 31, 1997 14:55:52

Channel 

### A 0.01 5 C

h 1 

## ' 0 

### r 0.01 0 1

d e 

## v 0 

### 1 t 

### 0. 00 5 s


# • •• 0

0 5 10 15 20 Minutes



### Peak Name Ret. Time Area Chloride 2.87 3803



# 96Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHIIOM\52197.004 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 2 a Acquired : Majr 31, 1997 15:44:46

Channel A 0.12

0.10

0.07 V 0 1 t 0.05 s
0.02 5 C

h 1 0 r , 0 i

d e 5

0

5

0 0 5 10 15 20 Minutes

Peak Name Ret. Time Area -------------- Chloride 3.03 484813

O 

## ~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

# ~ Eluent: 4mM Phthalic Acid pH 3.6; Floza @ 2 mis/min; 5 ul Inj Vol

Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHROM\52197.005 a Method : C:\EZCHROM\METHODS\M26.MET

Sample ID : AUN 3 a 

### Acquired : May 31, 1997 15:50:40 

# ~ . . 

# ~ Channel A 0.1

0.1

mi V 0 1 t 0.0 

### s
0.0

0.0 

### 25 C

h 1 0 r 

### 00 i

d 

### e 75

50

25

00 0 5 10 15 20 Minutes

Peak Name Ret. Time Area Chloride 3.03 524632



### ,r,f

### Instrument: "Clyde" Column: Hemilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 pS/cm 40 C File : C:\EZCHROM\CHROM\52197.006 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 4 a Acquired : May 31, 1997 16:39:34

Channel A 0.12

0.10

0.07 V 0 1 t 0.05 s
0.02

; o •rs, 5 C h 1 0 r ~ 0 i

d e 5

0

5

0 0 5 10 15 

### 20 Minutes

Peak Name Ret. Time Area Chloride 3.01 382860



### ~~

## ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}11 Inj Vol Conductivity Detection Gain 0.4 }1S/cm 40 C 

## ~ File : C:\EZCF 

## ~ tOM\CHROM\52197.007

Method : C:\ZZCHROM\METHODS\M26.MET 

### Sample ID : RUN 4 BT a Acquired : May 31, 1997 16:45:27



## ~ Channel A .~

- 0.015

i~
~ 0.010



### ~ O 1 t 0. 00 

# 3

• ••

5 10 15 

### Minutes



### Peak Name Ret. Time Area 

# i

~ ., 

### ,I 41~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.008 Method : C:\EZCHROM\METHODS\M26.MET Sample ID :
- RUN 5 a 

### Acquired : May 31, 1997 17:34:22

Channel A • 0.12

0.10

0.07 v 0 1 t 0.05 9
0.02

~ 

### •• 5 C

h 1 0 r 

### 0 i

d e 

### 5

0

5



### 0 0 5 10 15 20 Minutes

Peak Name Ret. Time Area 

### --------------- ------ -------- Chloride 3.00 351206

. C 

### ~ /r 

### Inmtrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

# ~ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mla/min; 5 ul Inj Vol

Conductivity Detection Gain 0.4 }:S/cm 40 C 

# ~ File : C:\EZCFROM\CHROM\52197.009

Method : C:\ •EZCHROM\METHODS\M26.MET Sample ID : RUN 6 a Acquired : May 31, 1997 17:40:15 O - . 

# ~ Channel A '- 0.12
0.10

0.07 V 0 1 t 0. 05 s
0.02

~ •~ 

### 5 C

h 

### 1 0 r , 0 i

d 

### e 5
0
5

0 0 5 10 15 20 Minutea

~ 4~ 

### Peak Name Ret. Time Area Chloride 3.00 359262



### ~ 

### JF C 6 1 h u 0 r 5 i
~ d e 4
3
2
1
0 1 0 ~ 1
0.0
0.0
V 0.0 0 1 t s 0.0
0.0
0.0 Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}il Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.010 Method : C:\EZCHROM\METHODS\M26.MET Sample ID :-ES 1 a Acquired : May 31, 1997 18:28:40

Channel A



## ~ ~ 5 10 15 20 Minutes

Peak Name Ret. Time Area Fluoride 2.12 231454 Chloride 2.93 461063



# 93

# A 0 9 Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 K1 Inj Vol Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHROM\52197.011 Method : C:\EZCHtOM\METHODS\M26.MET Sample ID : FS 2 a Acquired : May 31, 1997 18:34:05

Channel A 0.0
0.0
0.0
V 

### 0.0 0 

### 1 t s

### 0.0
0.0
0.0 F C 6 1 h u 0 

### r 5 i d it e 4
3
2
1 

# o—U 

# I 5 10 15 20

Minutes -'• i

Peak Name

_ Fluoride 

### Chloride Ret. Time 2.12 2.93 Area

226290 452149



# 9vInstrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 

### ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.012 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : 0.1 N H2SO4 b Acquired : May 31, 1997 18:49:59

Channel A 0.015

0.010

V 0 1 t 0. 005 s


# • •••

0 5 10 15 20 Minutes

Peak Neme Ret. Time Area --------------- ------ --------



# a;

### e In3trument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C 

# ~ File : C:\EZCHROM\CHROM\52197.013

Method : C:\ZZCHROM\METHODS\M26.MET Sample ID : RUN 1 b Acquired : May 31, 1997 18:55:51

~

r - , ;i 

### Channel A 0.12
0.10

0.07 V 0 1 t 0. 05 s
0.02

~ ~• ®0 0 5 10 15 20



### Minutes

Peak Name Ret. Time Area Fluoride 2.15 678264 

### Chloride 2.92 128451 

### 5 F 1 

### uC o h r 1 , 

### 0 i o d r i d e 5

0

5



# ~ ~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.014 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 1 BT b Acquired : May 31, 1997 19:44:45

Channel A 0.015 C ,

h 1 0 0.010 r

i d e 

### V 0 1 t 0. 005 s

. .. N

0 5 10 15 r~ 

### Minutes

Peak Name Ret. Time Area Chloride 2.88 3979



# q~

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}il Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.015 

# ~ Method : C:\ $ZCHROM\METHODS\M26.MET

Sample ID : RUN 2 b Acquired : May 31, 1997 19:50:39



### ~ Channel A " 0.12

- 0.10 

### ~ 0.07 V o 1 t 0.05

.. ~ s 

## J 0.02 

# Li

~ 0.00 0

~

~ 

### Peak Name 

# J ---------------

.. Chloride 5 10 15 20 

### Minutes

Ret. Time Area 3.03 484920



# 'W

### instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm v

Sluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C Hile : C:\EZCHROM\CHROM\52197.016 Method : C:\EZCHPOM\METHODS\M26.M :ET 

### Sample ID :-RUN 3 b Acquired : May 31, 1997 20:39:34

Channel A 

### 0.12

0.10

0.07 V 0 1 t 0. 05 9
0.02



### am 5 C

h 

### 1 0 r 

### 0 i

d e 5

0

5

0 7 

### 0 5 10 15 20

Minutes

Peak Name Ret. Time Area 

### --------------- ------ -------- Chloride 3.03 523290



# ~ 

# O

# ~ Instruments "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CIDtOM\52197.017 

# ~ Method : C:\EZCHAOM\METHODS\M26.MET

Sample ID : AUN 4 b Acquired : May 31, 1997 20:45:27

Channel A 0.1

0.1 

### ~ 0.0 V 1 t 0.0

.. 

### ~ i s

J 0.0 

### J



### ~ 0.0 0 5 10 1s 20 

### Minutes

Peak Name Aet. Time Area Chloride 3.00 382224



# 14
~ 

# 07

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm ' Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}:1 Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHFtOM\CHROM\52197.018 Method : C:\EZC1iROM\METHODS\M26.MET 

### Sample ID : RUN 4 BT b Acquired : May 31, 1997 21:34:20

Channel A 0.01 

# III

0.. 01

V 0 1 t 0. 00 s 

# III

~ •~

5 10 15 20 

### Minutes

Peak Name Ret. Time Area

i i

# ~ 0
~
,

~ 3
~ ~
~ ~ i
~ ~ ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.019 Method : C:\EZCHROM\METHODS\M26.MET Sample ID :
- RUN 5 b 

### Acquired : May 31, 1997 21:40:15

Channel A 

### 5 C

h 1 0 r , 

### 0 i

d e 

### 5

0

5



### o 

# l
~ 

# _j

0 5 10 15 20

Minutes

Peak Name Ret. Time Area Chloride 3.00 351934

J 0.12

0.10


### 0.07 

### v o. 1 t 0.05 

### s
0.02



### • ••

r 2,

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm .

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul 

### Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.020 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 6 b Acquired : May 31, 1997 22:29:08

Channel A 0.12

0.10

Aweiri 

### V 0 

### 1 t 0. 05 s
0.02



### n.nn 5 C

h 1 0 

### r 0 

### d

e 5

0

5

0 

# Li 0 5 10 15 20

Minutes

Peak Name Ret. Time Area --------------- ------ -------- Chloride 3.00 359121



## 103

### Peak Name Fluoride Chloride Ret. Time Area
------ -------- 2.10 248685 2.93 459822 <~

~

~ d :.~ 

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}il Inj Vol Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHROM\52197.021

~ I Method : C:\EZCHROM\METHODS\M26.MET 

### " Sample ID : FS 1 b

Acquired : May 31, 1997 22:34:33

~ .


### ! Channel A

~ ;:•i ~

.~ `. .

_. ~ ~)

~ 0.125

0.100

0.075 V 0 1 t 0. 050 s

• weWe 

### F C

1 h u 1 0 0 

### r r , i i d d e e

0 5 10 15 20



### Minutes

iDC(

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol Conductivity Detection Gain 0.4 }:S/cm 40 C File : C:\EZCHROM\CHItOM\52197.022 Method : C: \EZCHtOM\METHODS\M26.MET Sample ID : •FS 2 b 

### Acquired : May 31, 1997 23:22:59

Channel A 0.1

0.1

C•1

~ [•] V 0 1 t 0.0 s

• •

• • 

### 25 F C

1 h u 1 0 0 

### r r , 

### 00 i i d d e e 75

50

25

00 0 5 10 15 20



### Minutes

Peak Name Ret. Time Area Fluoride 2.12 220353 

### Chloride 2.93 449709

/ IQ~

## i~

...~~ s:a

J 

## _J 

# ~

,



# ~ _J 0.0
0.0
0.0
V . 0.0 0 1 t s 0.0
0.0 0.0
-o 0 0 5 10 15 20 

### Minutes FC 6 1 h ul 0 0 r r 

### 5 i i
~ 

### dd e e 4
3
2
1
0

, 

### ~ Instrument: "Clyde" Column: Hamilton PAP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mla/min; 5}l1 Inj Vol Conductivity Detection Gain 0.4 }:S/cm 40 C File : C:\EZCHROM\CHROM\52197.023



# ~ Method : C: \EZCHAOM\METHODS\M26.MET 

### ~ Sample ID : SPIKE a

Acquired : Jun 02, 1997 02:31:47



### ~ Channel A

Peak Name Aet. Time Area Fluoride 2.13 214522 

### Chloride 2.87 125023



# 1,1) 6

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 ml$/min; 5 

### ul Inj Vol Conductivity Detection Gain 0.4 pS/cm 40 C File : C:\EZCHROM\CHROM\52197.024 Method : C:\EZCHROM\METHODS\M26.MET Sample .ID : - SPIKE b Acquired : Jun 02, 1997 02:37:39

Channel A FC 0.0 6 lh

ul 00 

### rr 0.0 5 ii

dd ee 0.0 4
V 0.0 3 0 1 

### t s 0.0 2
0.0 1
0.0 0
-0 0 , . 10 

### 5 10 15 20 Minutes

Peak Name Ret. Time Area Fluoride 2.12 254397 Chloride 2.85 124847


# 10

# ~ ~ 

# e Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mis/min; 5 μl Inj vol Conductivity Detection Gain 0.4 }tS/cm 40 C £ile : C:\EZCHROM\CHROM\15935.114 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : Audit (20.0 ppm) b Acquired : Jun 01, 1997 09:11:15

Channel A 0.12
0.10

0.07 v 0 1 t 0. 05 s
0.02

mwono 5 C

h 1 0 r 0 i

d e 5

0
5

t 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Chloride 2.96 529947

/~?~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 

### ul Inj Vol Conductivity Detection Gain 0.4 pS/cm 40 C File 

### : C:\EZCHROM\CHROM\52197.031 Method : C:\EZCHROM\METHODS\M26.NET Sample ID : 10.0 PPM a Acquired : Jun 03, 1997 09:58:57

Channel A u. v
0.
0.
0. 

### v 0. 0 

### 1 t 0. s 0. 0. 0. -0 0 

### 07 F 

### 1 06 u

0 

### 05 

### r

i 

### d e 04 03 02 01 00 ni

.. O 

### 5 10 15 20 Minutes

Peak Name Ret. Time Area Fluoride 

### 2.08 14489



### /bq

# ~ Eluent: 4mM Phthalic Acid pH 3.6; Florr @ 2 mla/min; 10 ul Inj vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\3

- 2/9f oo / .;,;, 

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm



# ~ Method : C:\EZCHROM\METHODS\M26.MET

Sample ID 

### := ~ 

### "O P ~"~t a ~ •E

~ a' ~ L 

### Acquired : Jun 03, 1995 11:18:56

E 

# ~ Channel A 0.0" 0 

### F 7 1 0.0 

### u

0 6 r 0.0 i

d 

### 5 e 0.0 

### v 0.0 4 0 1 t 0.0 3 s 0.0 2 0.0 1 0 0.0

, -0 0 ~ 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.10 79572

/ M

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; FloLr 

### @ 2 mis/min; 10 

### ul Inj Vol Conductivity Detection Gain 0.4 }IS/cm 40 C File : C:\EZCHROM\CHROM\52197.003 Method : C:\EZCHROM\METHODS\M26-MET Sample ID : 100 PPM a Acquired : Jun 03, 1997 11:01:30

Channel A u.0 

### 0.0 0.0 0.0 V 0.0 0 

### 1 t 0.0 s 0.0 0.0 0.0 -0 0 a F

1 

### u 7 0 r 6 d e 5 

### 4 3 2 1 0

, 

### . +0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.12 158517

# e n e

~ 

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 m,m

Eluent: 4mM Phthalic Acid pH 3.6; Flow Q 2 mla/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHItOM\52197.002 Method : .C:\EZCHROM\METHODS\M26.MET Sample ID : , 200 PPM a Acquired ; Jun 03, 1997 10:24:53

Channel A 0.0° ~ F 1 

### u 0.0 7 0



### r i1 6 d 0.0 e 5 0.0 V 0.0 4 0 1 3 t 0.0 s 2 0.0 1 0.0 0 0.0

, -0 0 . 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area
--------------- ------ -------- 

### Fluoride 2.15 320273



# J/2.,08 07 F 06 OS 04 03 02 01 

# . 00 

# T-7— ni 

# I ) 5 10 15 20



### Minutes 0. 0. 0. 0. 

### V 0. 0 1 t 0. s

0. 0. -0. 1 

### u 0 

### r i d e 

### Instrument: "Clyde" Column: He

~ 

### milton PAP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 K1 Inj vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52l97.032 Method : C:\EZCHROM\METHODS\M26.MET 

### Sample ID : 10.0 PPM b Acquired : Jun 03, 1997 10:04:11

Channel A

Peak Name Aet. Time Area Fluoride 2.08 14430



### l~~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

# ~ Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 10 }il Inj Vol



### Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.028 

# ~ Method : C:\EZCHROM\METHODS\M26.MT



### Sample ID :•200 PPM b Acquired : Jun 03, 1997 02:13:57

~ - 

### Channel A 

## o.os i 0.0 0.0
o us

~ • ~ 0 1 t 0.0 s



# ~ ae; 0.0 0.0



## ~ 5 10 15 20 

### Minutes

•, 

### Peak Name Aet. Time Area Fluoride 2.15 344775



### F 1 u 7 0 

### r i ' 6 d e 5

3 2 1 0 i



### ~~~LT • ~ 0 1 t 0.0 s

~ xi; Wel 0.0 v F ,

1 u 7 0 r 6 d e 5
4 3 2
1 0 i U. 0° 0.0 0.0 

### Instrument: "Clyde" Column: Hamilton PAP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.005 Method : C:\EZCHAOM\METHODS\M26.MET Sample ID :.Audit (100 ppm) a Acquired : Jun 03, 1997 11:28:05

Channel A



## ~ 5 10 15 20 

### Minutes

Peak Name Aet. Time Area Fluoride 2.12 163033



# ll~♦ 

### ' Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

# ~ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj vol

Conductivity Detection Gain 0.4 pS/cm 40 C File : C:\EZCHROM\CHROM\52197.006 

# ~ Method : C:\EZCHROM\METHODS\M26.MET

Sample ID : RUN 1 a Acquired : Jun 02, 1997 19:40:20



# ~ Channel A 0. 0" 0.0
A 0.0 

# d 0.0 v 0.0 .,N 0 1 t 0.0 s 0.0 0.0 0.0 -0 0

~ 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.10 62046 

### Chloride 2.85 12225

0 

### 7 F 1 

### u C 

### 6 o h r 1 

### l o d r 5 e 

### i

d 4 e 3 2 1 0

~



# 116:2

### Instrument: "Clyde" Column: Hamilton PFtP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHROM\52197.007 Method : C:\EZCHROM\MZTHODS\M26.MET Sample ID :. RUN BT a Acquired : Jun 02, 1997 19:55:43

Channel A 0.08 0.07 0.06 0.05 V 0.04 0 

### 1 t 0.03 s 0.02 0.01 0.00 -0.010 5 10 15 20 Minutes

Peak Name Ret. Time Area --------------- ------ --------



# /0

# a ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm .

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.008 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 2 a Ac 

## m , ; red : Jun 02, 1997 20:01:07 

# i

~ 

## , ~



## ~ ~ ., 

# ~1

•i ~ 

### Channel A o F 

### 1 u 7 

### o C rh i 1
~ 6 

### do e r i 5 d

e 4 3 2 1 0 1 _ 0 5 10 15



### Minutes

Peak Name Ret. Time Area --------------- ------ -------- 

### Fluoride 2.15 340646 Chloride 2.87 46930 W. 0" 0.0 0.0 0.0 

### v 0.0 0 1 t 0.0 s 0.0 0.0 0.0 -0. 0

~ Ue



## Cl i"Inatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHROM\52197.009 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 3 a Acquired : Jun 02, 1997 20:49:31



### Channel A O.0 0. 0.
0.. V 0. 0 1 t 0. 

### s 0. 0. 0. o F

1 

### u 07 o C 

### rh i 1 , 06 d o e r 

### 05 d 

## e 04 03 02 01 00
ni 

### ~ 5 10 15 20 

### Minutes

Peak Name Aet. Time Area Fluoride 2.15 309356 

### Chloride 2.87 50728



## ~I ~

# I Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.010 Method : C:\EZCHROM\METHODS\M26.MET Sample ID :'RUN 4 a Acquired : Jun 02, 1997 20:54:54

Channel A u.u ~ 

### F

1 

### u 0.0 0.0 7 0 

### 6 d l i h ' r C
e o 

### r 5 1 0.0 

### d

e 

### v 0.0 4 0 1 t 0.0 3 s 0.0 2 0.0 1 0.0 0

, -0 0 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.15 294663 

### Chloride 2.87 36138



### 1 

# 12 v

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm
~ 

### Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.011 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 4 BT a Acquired : Jutn 02, 1997 21:10:18

Channel A 0.08 0.07 0.06 0.05 V 0.04 0 1 t 0.03 s 0.02 0.01 0.00
-0.010 5 10 15 20 

### Minutes

Peak Name Ret. Time Area

--------------- ------ --------



# 120~ ~ r R 

### h Instrument: "Clyde" Column: He.milton PRP-X100 250x4.6 mm Eluent: 4mM Phthali • c Acid pH 3,6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\EZCHROM\CHIROM\52197.0 29 Method : C:\EZCHRCM\METHODS\M26.MET 

### Sample'ID : 100 PPM b Acquired : Jun 03, 1997 11:06:55

~

• -•:n

~ ; 4 U.0
0.0 0.0
0.0 

### v 0.0 0 1. t 0.0 s 0.0 0.0 0.0 -0 0 . i0 

### Channel A

5 10 15 

### Minutes ~~ Jr{• 1

3

:Y~:~•~l

•{.
~ rcia
~ a{ 1 u 0 r i 

### d e

20



### ~ V
! 

### ~

.,. ~ 

### Peak Name Fluoride Ret. Time Area 2.12 162726



### 1 7/2

## r ~ . 

# s .. ~ 

# ~

.. 

# ~

n

..~ ~ ~

..., 

## ~ - 

# iJ ri

~



### , ` U Inszrument: ^Clyde ° COlumna He.milton PRP-X100 250x4.6 aua - Eluent: 4mM Phthalic Acid pH 3.6;= Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 gS/cm 40 C File : C:\EZCHROM\CHPOM\52197.027 Method : C:\EZCHROM\METHODS\M26.MET 

### Sample ID : 50 PPM b Acquired': Jun 03, 1997 02:08:34

Channel A O.G 0. 0. 0. v 0. 0 1 t 0. s G. 0. 0. -0 

### u F '



### 1 07 

### u

0 06 

### r i d e 05 04

~ 03 02 01 00

n~



### Peak Natne Ret. Time Area Fluoride 2.10 83420 ` `0 5 10 15 W 

### Minutes



## /23

### ` Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm e Eluent: 41M Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 K1 Inj Vol

Conductivity Detection Gain 0.4 KS/cm 40 C File : C:\E2CHROM\CHROM\52197.027 (~ Method : C:\EZCHR0M\METHODS\M26-MET [ w ] Sample ID :- 50 PP'M b



### Acquired : Jun 03, 1997 02:08:.34

~ 

### Channel A 0

i uel kd W. 0 0.0 0.0 0.0 V 0.0 0 1 t 0.0 s 0.0 0.0 0.0 -0 0 0 F 7 1 

### u 0 6 r ~ 

### i d e 5
4 3

2 1 0

, . +0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.10 83420



### ~ j z ~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 },1S/cm 40 C File : C:\EZCHROM\CHROM\52197.029 Method : C: \EZCHI3.OM\METHODS\M26.MET 

### Sample ID : 100 PPM b Acquired : Jun 03, 1997 11:06:55

Channel A 1 

### u 0 r 

### i d e 0.

0. 0. 0. v 0. 0 1 t 0. s 0. 0. 0. )6 )5 )4 )3 )2 01 00
n, 

### ME 5 10 

### Minutes 15 20



### Peak Name Ret. Time Area Fluoride 2.12 162726

/ 

## ~2~~ 

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

# ~ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol

Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHtOM\CHROM\52197.012 

# ~ Method : C:\EZCHROM\METHODS\M26.MET

Sample ID : RUN 5 a Acquired : Jun 02, 1997 21:15:41

- . ,. ~ ---- -

M:N ~ u.0 0.0 0.0 Wi; V 0.0 0 1 t 0.0 s

0.0 0.0 -0 0 o E ,

1 u 7 0 C 

### rh i l 6 d 0 e r 

### 5 1

d e 4 3 2 1 0

, . 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.13 267208 

### Chloride 2.85 34052



## 12, b

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 

### ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File 

### : C:\EZCHROM\CHROM\52197.013 Method : C:\EZCHROM\METHODS\M26.MET 

### Sample ID : .RUN 6 a Acquired : Jun 02, 1997 22:04:05

Channel A 0. 0. 0. 0. 

## v 0. 0 

### 1 t 0. s 0. 0. 0. -0. v a E ,

1 

### 07 u

0 

### r C 06 i 

### h d 1 e o r 05 1



### d e 04 03 02 01 00
ni 

### ) 5 10 15 20. Minutes

Peak Name Ret. Time Area Fluoride 2.15 274064 Chl.oride 2.87 34795



# /2"?t 

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 m19/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHtOM\CHROM\52197.014 

# ~ Method : C:`EZCHROM\METHODS\M26.MET

Sample ID : FS 1 a Acquired : Jun 02, 1997 22:09:29



# ~ Channel A 0.08 

### F C 1 h u 1
0.06 0.07 0 0



### r r dd e e 0.05 

### V 0.04 0 1 t 0.03 s

~ •: 0.01 0.00

~ 0 O1 . 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.10 111217 

### Chloride 2.92 228358

, ; 0 P"

### ° F C 1 h 

### 7 u 1 0 0 r r 6 

### d d e e 5 4 3 2 1 0

, U. 0° 0.0 0.0 0.0 

### V 0.0 0 1 t 0.0 a 0.0 0.0 0.0 -0 0 

### Instrument: "Clyde" Columna , Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHIZOM\CHROM\52197.015 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : FS 2 a Acquired : Jun 02, 1997 22:24:53

Channel A

. 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.10 105263 

### Chloride 2. 92 221521



### i 

# 2~t
. 

### p Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

# r E ] i Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol

Conductivity Detection Gain 0.4 }:S/cm 40 C File : C:\EZCHROM\CHROM\52197.016 n Method : C:\EZCHROM\METHODS\M26.MET



### Sample ID : RUN 1 b Acquired : Jun 02, 1997 22:30:15

J 

### Channel A
~

•'i r ~



## J

~ 0.0 0.0 0.0 0.0 V 0.0 0 1 t 0.0 s 0.0 0.0 0.0 -o 0 0 

### 7 F 1 

### uC , 6 oh r 1 

### i o 5 dr e i d 9 e 3 2 1 0

, + 0 5 10 15 20 

### Minutes =1



### Peak Name Ret. Time Area 

### ~ --------------- ----- 

### ~ -------- 

### ~ Fluoride 2 

### .10 58562

Chloride 2.85 12196

/-
~ ,?)

### Instrument: "Clyde" Column: Ha.milton PRP-X100 250x4.6 

### mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.017 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 1 BT b Acquired : 

### Jun 02, 1997 23:18:39

Channel A 0.08 0.07 0.06 0.05 V 0. 04 0 

### 1 t 0.03 9 

### 0.02 0.01 0. 00 -0.010 5 10 15 20 Minutes

Peak Name Ret. Time Area --------------- ------ --------



# 131

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.018 ('] Method : C:\EZCHRCM\METHODS\M26-MET i 

## ~ Sample ID :'RUN 2 b



### Acquired : Jun 02, 1997 23:24:03



# ~ Channel A 0.0 0.0 0.0 0.0 V 0.0 0 1 t 0.0 s 0.0 0.0 0.0 -0 0 o F

1 

### u 7 o C 

### rh i 1 ' 6 

### do e r i 5 d

e 4 3 2 1 0 i . 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.16 320078 

### Chloride 2.87 46742



# 13zInatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Floer @ 2 mis/min; 10 μl Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHROM\52197.019 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 3 b Acquired : Jun 02, 1997 23:39:26

Channel A U. UO F

1 u 0.0 7 o C

r h 0.0 6 do

e r i 0.0 5 d

e 

### V 0.0 4 0 1 t 0.0 3 s 0.0 2

0.0 1 0.0 0 -0 0 , 0 5 10 15 20 Minutes

Peak Name Ret. Time Area Fluoride 2.15 314604 Chloride 2.87 50360



# , ~ 

# 3.•t_;iyae" (.;olumn: Hamilton PRP-X100 250x4.6 mm 

### Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 )iS/cm 40 C File : C:\EZCHROM\CHROM\52197.020 Method : C:\EZCHROM\METHODS\M26.MET Sample ID :- RUN 4 b 

### Acquired : Jun 02, 1997 23:44:50

Channel A 

# 0.
0. 0. 0.



### v 0 

### • 0 1 t 0. s 0. 0. 0. -0 - 0 5 10 15 20 

### Minutes :-„



### Peak Name Ret. Time Area Fluoride 2.15 295763 

### -' Chloride 2.87 36183 

# ~
~

.~



# J i351Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/ain; 10 y1 Inj vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.021 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 4 BT b Acquired : Jun 03, 1997 00:33:14

Channel A 0.08 0.07

, 0.06 0.05 V 0.04 0 1 t 0.03 s 0.02 0.01 0.00 -0.0 0 5 10 15 20 

### Minutes

Peak Name Ret. Time Area

--------------- ------ --------

~

~~ j7

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCFiROM\CHROM\52197.022 

# ~ Method : C:\EZCHROM\METHODS\M26-MET



### Sample ID : RUN 5 b Acquired : Jun 03, 1997 00:38:37

" Channel A
•:c 0.08 0.0 0.0 0.0 V 0.0 0 1 t 0.0 s 0.0



### ~.. ~ 0.0



### ~ 0.0 -0 0 . 0



### Peak Name Fluoride Chloride 5 10 

### Minutes

Ret. Time 2.13 2.85 15



### Area 257917 33802 20 

### F 1 u 7 0 rC i 

### h 6 dl eo r 5 i 

### d e 4 3 2 1 0

,



# 1.3&-- i



### Irnatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mla/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 uS/cm 40 C File : C:\EZCHROM\CHItOM\52197.023 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : RUN 6 b Acquired : Juri 03, 1997 00:54:01

Channel A 0. 0. 0. 0. V 0. 0 1 t 0. s 0. 0. 0. -0. 08 F

1 07 

### u

0 

### r C 06 i 

### h

d 1 e o 

### r 05 1

d e 04 03 02 01 00
n ~ ) 5 10 15 20 

### Minutes

Peak Name Ret. Time Area Fluoride 2.15 281260 

### Chloride 2.87 34135



# /3"?

### ° F C 1 h u 1 07 0 0 

### r r i i 

### ~ 06 d d

e e 05 04 03 02 01 00 ni 1-0 5 10 15 20 

### Minutes 0. 0. 0. 

### V 0. 0 1 t 0. s 0. 0. 0. -0. 

### ~ Instrument: "Clyde" Column: Hamilton PAP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 10 Kl Inj Vol Conductivity Detection Gain 0.4 uSrcm 40 C File : C:\EZCHROM\CHROM\52197.024 

### ~ Method : C:\EZCHROM\METHODS\M26.MET

Sample ID : FS 1 b Acquired : Jun 03, 1997 00:59:25



### ~ Channel A

Peak Name Aet. Time Area Fluoride 2.10 112431 

### Chloride 2.90 228500

/ .3 

### ~

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 

### ul Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHROM\52197.025 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : FS 2 b Acquired : Cun 03, 1997 01:47:49

Channel A
0.0 0. 0° ° F C 7 u 1 1 h 0 0 

### r r i 1 , 

### 0.0 6 d d

e e 0.0 5 V 0.0 4 0 

### 1 t 0.0 3 s 

### o.a 2 0.0 1 0 0.0

, 

### -o 0 

### ' o 5 10 15 20 Minutes

Peak Name Ret. Time Area Fluoride 2.10 100006 Chloride 2.90 221176



# i31

# ~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 gl Inj Vol Conductivity Detection Gain 0.4 P.S/cm 40 C File : C:\EZCHROM\CHROM\52197.033 Method : C:\EZCHROM\METHODS\M26.MET 

### (J Sample ID : HF SPIKE a

Acquired : Jun 03, 1997 11:41:59



## ~ 

# ~ Channel A 

## e 0 F 7 1 

### u o C ~ 6 

### r h i 1 do 5 e r

i d 4 e 3 2
1 0 1 

# 1: 1 0 5 10 15 20 

### Minutes 0.0 0.0 0.0
~ 0.0 :J V 0.0 0 1 t 0.0 s 0.0 0.0 0.0 -0.0



### Peak Name Ret. Time Area --------------- 

### Fluoride 2.10 68296 

### Chloride 2.84 6185



### i~ 

## GInstrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 p1 Inj Vol Conductivity Detection Gain 0.4 }iS/cm 40 C File : C:\EZCHROM\CHIZOM\52197.034 Method : C:\EZCHROM\METHODS\M26.MET Sample ID : HF SPIKE b Accquired : Jun 03, 1997 11:47a21

Channel A U. OS F 0.0 7 1

u o C 0.0 6 r h

i 1 do 0.0 5 e r

i d V 0.0 4 e 0 1 t 0.0 3 s 0.0 2 0.0 1 0.0 0 -0 0 , . 1 0 5 10 15 20 Minutes

Peak Name Ret. Time Area Fluoride 2.10 67914 Chloride 2.84 6084


# j,,fj

### Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol Conductivity Detection Gain 0.4 }:S/cm 40 C File : C:\EZCHROM\CHROM\52197.026 Method : C:\EZCHtOM\METHODS\M26.MET Sample ID : Audit (100 ppm) b Acquired : Jun 03, 1997 11:33:27

Channel A

~ 

### 0.0 0.0 

### 0.0 0.0 V 0.0 0 1 

### t 0.0 s 0.0 

### 0.0 0.0 

### -0.0 Minutes

Peak Name Ret. Time Area --------------- ------ -------- Fluoride 2.12 167573 

# 0 ~ 0

a

IW2--

# 5'V ANALYTICAL TESTING CONSULTANTS, INC KANNAPOLIS, N.C. G=0=GIA

IMPINGEA DATA SHEa= CLI£NT 9 LOCATION y ~,~, ?.. ~ ; DA:S IMPING*_R COS:*_NSS RE.`i.LR1S5

~ 1 ~ 5'a ART 5 ~~~ ~G ~ 11 ~ ~ D Q /~ ~~ ~ OQl,

dv 

# 2~ ST,RT

~ 

# 2,q ~ 

## 12,1 

# ) _S-0 16

~ 

# t.,L la ~t,,~ ~ dv 6~t~. 4 © 

# 3 

# I_-

~ 

# T 3

~ 5 

# - 3,1 

# ~ t. 6 

# ~ _.~ 196 r 

# ~ LL I 0 y NL ( 

# ~ ldar,L JDac ~~I ~~ 

## 3c

~ 

## os 

# ' d~r 

# s ~J~~ O , ~~~l~S i



### ~ j,L r~~ 1 

# 7 1~ ~a~r",~ Q 

### z'~ 7~ hL 

## I ~ ! aTJ 

## ~ 3T 

# SrI; IVOh` 

## 3 V ~

~~~ 

## .7 10
~ 

## ' ,L D

DATA DY 

# _=- -- ;

~ 

# k3

# ~

, 

# n



# i BAROMETER #i CAL/BRATION

~ DATE STATION PRESSURE BAROMETER READING ADJUSTMENT INITIALS



### 05/24/96 29.77 29.58 0.19 JW 06/10/96 29.86 30.03 0.17 KP -.-, 07/15/96 29.97 29.91 0.06 SM

08/12/96 29.86 29.82 0.04 JW 09/17/96 30.07 30:04 0.03 KP 10/04/96 29.77 29.84 0.07 KP



## ~ + 11 /08/96 29.61 . 29.75 0.14 KP

12/02/96 30.02 29.99 0.03 KP 01 /06/97 29.75 29.54 0.21 J W 02110/97 29.77 29.69 0.08 CR 03/19/97 29.78 29.82 0.04 SM 

## ~ 04/21/97 29.66 29.60 0.06 SM

05/05/97 29.84 29.83 0.01 _ SM 06/06/97 29.45 29.32 0.13 - DA



# BAROMETER #2 CALlBRATION U . _

.~ 

## ~ " DATE STATION PRESSURE ;. BAROMETER READING ADJUSTMENT . INITIALS

05/24/96 29.77 29.79 0.02 JW 06/10/96 29.86 29.91 0.05 KP 07/15/96 29.97 29.96 0.01 SM 08/12/96 29.86 29.89 0.03 JW 09/17/96 30.07 29.88 0.19 KP 10/04/96 29.77 29.81 0.04 KP 

## ~ 11 /08/96 29.61 29.64 0.03 KP

12/02/96 30.02 30.11 0.09 KP 01/06/97 29.75 29.18 0.57 JW 02/10/97 29.77 29.81 0.04 CR 03/19/97 29.78 29.56 0.22 SM 04/21 /97 29.66 29.68 0.02 S M 05/05/97 29.84 29.95 0.11 SM 06/06/97 29.45 29.61 0.16 DA

/4(`f

## PRIMARY VOST MODULE CALIBRATION CALCULATION
DATE 12111196 P BAR 29.81 MODULE ID VosT #2 REFERENCE METER-WET TEST METER 

### BY - POOLE K Run • Vrt

~ 

### : . . Vrt ,. Tm , ~ 

### Trf . Tim e 

### Sp Y: Run

~ 

### •

. .. ._ ..: ,. net !C3 net tt3 : : a ;w av .:' .` tn. H20 Avera e::' one 0.1229 0.1210 67 63 10 1.80 0.973 two 0.1270 0.1210 67 63 10 1'80 0.941 three 0.1272 0.1200 67 63 10 ' 1.80 0.932 0.949 four 0.2652 0.2740 67 63 10 2.40 1.019 five 0.2934 0.2700 66 63 10 2.40 0.910 six 0.2747 0.2680 67 64 10 2.40 0.964 0.964 seven 0.4182 0.4130 67 64 10 3.30 0.974 eight 0.4165 0.4060 67 64 10 3.30 0.961 nine 0.4409 0.4310 67 64 10 3.30 0.964 0.966 Three run Average 0.960 LEGEND Vm= volume of sampling meter Vrf= volume of reference meter Tm= temperature of sampling meter TrF= temperature of reference meter Sp= static pressure 

### Y= calibration factor t

~ ~~ ~

# ~

~ 

# . _. ~ 

# ~ 

# cz W

~ = ~ cz 

# U U)

~■



### U/ 

# >
~ T 

# ~ _ E 

# O ~ ~ 

# CL LL C/) ~ ~ ~ ._ J - 0 qc 

# l - T 0 

# N TT



# ~ ~ 

# cz y Q 

# ~ T ~ ~
~ 

## O 

# M w
~ - 

# w 

# ~ cz i 

# O - CD ` v U C!) 

# n

~~~~~s ~,1~i, 

# 1 ;~~ 

### ~ ~ , , , ~ ~ 

# Cfl"tN - r - OOod'NO N T 

# T ,-- o 0 0 0 

# ain u i ua a ad sa aii - 1 ~ 

# - v I ~ 

# \ N 3 ~ •• 

# ~



# ,4b

## NOZZLE CALIBRATION DATA FORM DATE 03/13/97 CALIBRATED BY WELCH NOZZLE NOZZLE DIAMETER' DIAMETER AVERAGE I.D. D1 D2 ::.. D3 DIFF."' DIA.... NO: (iNCHES) INCHES) (INCHES) INCHES) (INCHES) 

## 50 0.305 0.305 0.305 0.000 0.305 51 0.312 0.310 0.312 0.002 0.311 53 0.320 0.319 0.322 0.002 0.320 54 0.306 0.307 0.308 0.002 0.307 55 0.335 0.336 0.336 0.001 0.336 56 0.312 0.313 0.313 0.001 0.313 57 0.305 0.307 0.308 0.003 0.307 58 0.315 0.315 0.317 0.002 0.316 59 0.305 0.305 0.306 0.001 0.305 where: *= THREE DIFFERENT NOZZLE DIAMETERS; EACH DIAMETER MUST BE WITHIN 0.001 iNCHES ~ = MAXIMUM DIFFERENCE BETWEEN ANY TWO DIAMETERS, IN. DIAMETER DIFFERENCE MUST BE LESS THAN OR EOUAL TO 0.004 INCHES *** = AVERAGE OF THREE DIAMETERS



# Li 

# u

~~~ ~

## 0.5 4.07 4.27 

## 60 90 10 1 5.73 5.98 63 87 .10 1.5 6.85 7.2 62 89 10 2 

## 7.8 8.18 62 90 10 3 9.39 9.91 62 90 10 1.59 1.007 1.63 1.000 1.70 0.997 1.74 

## 1.000 1.81 0.991 1.69 0.999 

# PRIMARY MODULE 

# CALIBRATION CALCULATION

DATE 01/28t97 P BAR 29.6 

### MODULE ID ATC 4

BY Raltz 

## JORIFICE 

## Vw 

## .,,.Vd TW 

## Td TIME DH@ Y


# 'J
I

~

## ►



## s

# POST TEST MODULE CALiBRAT/ON CALCULATION
DATE 5/28J97 P BAR 29.85 MODULE ID ATC 4

BY MEADOWS ORiF10E Vw ' Vd ., Tw Td TiME D H@ Y 

### 1.00 5.74 5.84 74 85 10 1.69 1.001 1.00 5.74 5.84 74 85 10 1.69 1.001 1.00 5.73 5.85 74 86 10 1.69 0.999 1.69 1.000

~ a 

### ;:~

# a ~ 

# a PRIMARY VOST MODULE CALIBRATION CALCULATION
DATE 12/11/96 P BAR 29.81 ' MODULE ID - VOST 81 REFERENCE METER-WET TEST METER

BY POOLE Run +1 Vm Vrf Tm Trf Ttm• Sp Y.. Run

net tt3 net tt3 avg avg In. N20 Avera • 56 10 1.00 0.923 56 10 1 1.00 0.925 58 10 *1 1.00 0.943 0.930 58 10 1.40 0.945 59 10 1.40 0.923 60 10 1.40 0.924 0.931 60 10 1.80 0.940 60 10 1.80 0.912 60 10 1.80 0.912 0.921

Three run Average Q,928 one 0.1570 0.1500 73 two 0.1614 0.1550 74 three 0.1555 0.1520 76 four 0.4145 0.4070 76 five 0.4188 0.4020 78 six 0.4159 0.3990 78 seven 0.5526 0.5410 79 eight 0.5524 0.5270 82 nine 0.5665 0.5410 82 

## LEGEND Vm= volume of sampling meter Vrf= volume of reference meter Tm= temperature of sampling meter Trf= temperature of reference meter Sp= static pressure 

### Y= calibration factor



# 00!K] 

## d i ~



# ~ 

# I O~ 

# i

~ I d 

### , .



# ._.._.......... _..._ . ~ 

## I
~ 

# CY) 1 C)

~ +• T

~ 

# cz ' •

~ 

# C ) cz 

# L — ~ aD

; 

# 4 .. CY)■ ~ ~ ,~ 

# ~ U, CO 

# ct (2) 

# L ~

~~ 

### l • - 

# o cZ 

# U) 

# u CL, :

~ '•-

~ -i- ~ ...:.. ~ ' ' . ~ . 

### .._ , 

# No000

. 

## d
- N~ 

# -ooC 

# o d-

. . . . . . . 

# T T T T. O o o 

# ainuiva aad saajij `aleannol-4 

# 2 1.i.. ~ 

# ~ ~



## 'I ~~

# ~ ~ ~

,

. ~



### U 

# 4 PRIMARY VOST MODULE CALIBRATION CALCULATION
DATE 12J11f98 P BAR 29.81 . MODULE ID - VOST /3 REFERENCE METER-WET TEST METER BY POOLE Run t Vm V
~ ! Tm ... T
~ t Ttme :: „. $p : Y Run ,.. net ft3. ,. . net fC3..: q

... e: . one 0.1488 0.1522 75 65 10 1.00 1.001 two 0.1493 0.1528 75 65 10 1.00 1.002 three 0.1492 0.1522 76 65 10 1.00 0.997 1.000 four 0.3900 0.3999 77 66 10 1.40 1.001 five 0.3904 0.4003 77 66 10 1.40 1.001 six 0.3894 0.3990 - 77 67 10 1.40 1.002 1.001 seven 0.5221 0.5341 78 67 10 1.80 0.998 eight 0.5228 0.5341 77 67 10 1.80 0.998 nine 0.5234 0.5344 77 68 10 1.80 0.999 0.998 Three run Average 1:000 

### LEGEND Vm= volume of sampling meter Vrf= volume of reference meter Tm= temperature of sampling meter Trf= temperature of reference meter Sp= static pressure 

### Y= calibration factor



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## POSTTEST VOST MODULE CALIBRATION CALCULATION

DATE 6119H7 P BAR 29.94 ~ MODULE ID vosT +ra REFERENCE METER-WET TEST METER

BY ALBRIGHT Runt Ym: ;:.;:.:.. : Vrr:.:::::r::::':.'::<;;Tm ::.::::;:::<:;. :.Trt. ..:::::..Tlms::> :::.:..:.::::;>::::<.: :::i:;:::::::.:.;::.: :; ...: :..> .:. 

### Run >.,. : .:.:.: : . ..... .: ... :. .:.. . .. ..: ::.::::;<.:..>:. :.. ;:..:;: .:.:..::;:::: .::.> :. ..:.. .:... ;..<.. <:. . : ... ..:::.::. :.. .. ~ net ro.;::::::.::':'.:. net ro . .,.:: . ,. . . ,:. :: >; :;::!:;`.:::;:;: a,► «::; :::h
~ : H2O:; : :::;:':;<;<;;'<,';.<::<':: :::: . :'.`'' Avera one 0.1478 0.1489 65 two 0.1493 0.1504 65 three 0.1493 0.1495 65

LEGEND Vm= volume of sampling meter Vrf= volume of reference meter Tm= temperature of sampling meter Trf= temperature of reference meter Sp= static pressure 

### Y= calibration factor 63 10 1.00 1.001 63 10 1.00 1.001 64 10 1.00 0.997 1.000

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## POSTTEST VOST MODULE CALIBRATION CALCULATION
DATE 6116197 P BAR 29.94 MODULE ID vosT.1 REFERENCE METER-WET TEST METER

BY ALBRIGHT Run Vm Vrf Tm Trf Time Sp Y. Run

net ff3 : net !tl avg avg ln. H20 Avera e one 0.1566 0.1465 68 two 0.1569 0.1466 68 three 0.1570 0.1466 69

LEGEND ° ., Vm= volume of sampling meter Vrf= volume of reference meter Tm= temperature of sampling meter Trf= temperature of reference meter Sp= static pressure 

### Y= calibration factor 65 10 1.00 0.928 66 1 Q 1.00 0.929 66 10 1.00 0.926 0.928

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## ., POSTTEST VOST MODULE CALIBRATION CALCULATION
DATE 6119/97 P BAR 28.94 . MODULE ID VosT #2 REFERENCE METER-WET TEST METER

BY ALBRIGFIT Run # Vm Vii Tm Trt;. =;,:..::.: T(me :.:.: :` :';: 5 Y: . ... Run ,.::. . p ...:..:::. :.:' . net ft3 net tt3 : . . :':::: .. av : :..: : .;;: . av :::°:: ':: : ; .:: ;:: ::' . In. H20 .:: :: :. . .. Avera one 0.1155 0.1120 69 two 0.1157 0.1120 69 three 0.1159 0.1124 70

LEGEND:,: :. ;,; Vm= volume of sampling meter Vrf= volume of reference meter Tm= temperature of sampling meter Trf= temperature of reference meter Sp= static pressure 66 10 1.50 0.961 66 10 1.50 0.959 66 10 1.50 0.959 0.960

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