TS- CCGL81



### Attachment #1

Material Safety Data Sheet s

# MATERIAL SAFETY DATA SHEET

Page 1

Substa nce key: Revision Date: 12/09/2014

Version : 3 - 1 / USA Date of printing :12/09/2014



### Section 01 - Product and company identification

Identification of the

company:

Information of the substance/preparation:

Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name:

Material number:

Primary product use: Raw material for detergents

Chemical family: in aqueous-alcoholic solution



### Section 02 - Hazards identification

Emergency overview: Light yellow paste Causes moderate to strong eye irritation.

Expected Route of entry:

Inhalation: Vapors and/or mists are probably irritating to respiratory passages, nose, and throat.

Skin contact: Not expected to be irritating to skin. Eye contact: Causes eye irritation. Danger of serious damage to eyes. Ingestion: Not expected to be toxic.

Known effects on other illnesses: None known.

Listed carcinogen: OSHA Specifically Regulated Chemicals/Carcinogens: Not listed

NTP - National Toxicology Program Report: Not

listed

International Agency for Research on Cancer (IARC) - Overall Evaluations of Carcinogenicity to

Humans.: Not listed

Other: No

HMIS:

Health: 2 Flammability: 1 Reactivity: 0 Personal protection: D

# MATERIAL SAFETY DATA SHEET

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### Section 03 - Composition/information on ingredients

Hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

26 - 40 % Glycerine 56-81-5 2 - 4 %



### Section 04 - First aid measures

After inhalation: Remove person to fresh air. If signs/symptoms continue, get medical attention.

After contact with skin: Immediately flush skin with plenty of water while removing contaminated clothing. Wash contaminated clothing before reuse. If redness or irritation occurs, seek medical attention.

After contact with eyes: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

After ingestion: If swallowed give patient 2 glasses of water.

Get immediate medical advice/ attention.

Advice to doctor / Treatment: Treat symptomatically.



### Section 05 - Fire fighting measures

Flashpoint: not tested.

Lower explosion limit: not tested.

Upper explosion limit: not tested.

Self ignition: > 275 °F

Method: EC A.16 Source: Analogy

Ignition temperature: not tested.

Hazardous combustion products: In case of fire hazardous decomposition products may be produced such as: Nitrogen oxides (NOx)

Carbon monoxide

Extinguishing media: Water spray jet

Alcohol-resistant foam Carbon dioxide (CO2) Dry powder

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Special fire fighting procedure: Wear full protective clothing and self-contained breathing apparatus.



### Section 06 - Accidental release measures

Steps to be taken in case of spill or leak: Wearing appropriate personal protective equipment, contain spill, ventilate area of spill or leak, remove all sparking devices or ignition sources, collect onto inert absorbent, and place

in a suitable container.



### Section 07 - Handling and storage

Advice on safe handling: Use only with adequate ventilation and proper protective eyewear, gloves, and clothing. Wash thoroughly after handling.

Further info on storage conditions: Keep container closed.



### Section 08 - Exposure controls / personal protection

Respiratory protection: If airborne concentrations pose a health hazard, become irritating, or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29CFR1910.134.

Hand protection: Chemical resistant gloves (butyl rubber, nitrile rubber, polyvinyl alcohol). However, please note that PVA degrades in water.

Eye protection: Safety goggles or full face shield to protect against splashes.

Other protective equipment: Wear suitable protective equipment.

Advice on system design: Local ventilation recommended - mechanical ventilation may

be used.



### Section 09 - Physical and chemical properties

Form: paste

Color: white yellowish

Odor: characteristic

Odor limit: not tested.

pH: 8 - 9 (35 °C, 10 g/l)

Solubility in water: (40 °C)

soluble

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Soluble in ... : 1-octanol 39 g/l ( 20 °C)

Method: OECD Test Guideline 105 Data corresponds to that of the active component

Density: approx. 1.046 g/cm3 (50 °C)

Method: DIN 51757

Melting point : approx. 89 °F

Boiling point : approx. 212 °F

Based on water-content.

Evaporation number: not tested.

Vapor pressure: 1.73 Torr (25 °C)

Method: EEC 84/449 A.4 Corresp. to vapour pressure of water

Bulk density: Not applicable

Relative vapor density: not tested.

Partitioning coef.

octanol/water: 2.9

Method: Calculated from the solubilities Information refers to the main component.

Viscosity / (dynamic): not tested.

Viscosity / (kinematic): not tested.



### Section 10 - Stability and reactivity

Thermal decomposition: > 200 °C (Heating rate:3 K/min)

Method: DSC

Chemical stability: Stable under normal conditions.

Hazardous Polymerization: Hazardous polymerisation does not occur.

Conditions to avoid: None known.



### Section 11 - Toxicological information

Product information:

Acute oral toxicity: LD50 > 2,000 mg/kg (Rat)

Method: OECD Test Guideline 401 Source: Analogy By analogy with a product of similar composition

Acute inhalation toxicity: not tested.

# MATERIAL SAFETY DATA SHEET

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Acute dermal toxicity: LD50 > 2,000 mg/kg (Rabbit)

Method: OECD Test Guideline 402 Source: Analogy By analogy with a product of similar composition

Skin irritation: No skin irritation (Rabbit)

Method: OECD Test Guideline 404 Source: Analogy

Eye irritation: Risk of serious damage to eyes. (rabbit eye)

Method: OECD Test Guideline 405 Source: Analogy

Sensitization: non-sensitizing

Method: OECD Test Guideline 406 Source: Analogy



### Section 12 - Ecological information

Product information:

Biodegradation: > 80 %

Method: OECD Test Guideline 301B Source: Analogy

Fish toxicity: LC50 7.5 mg/l (96 h, Danio rerio (zebra fish))

Method: OECD Test Guideline 203 Source: Analogy

Daphnia toxicity: EC50 5.91 mg/l (48 h, Daphnia magna (Water flea))

Method: OECD Test Guideline 202 The values mentioned are those of the active ingredient.

Algae toxicity: EC50 30 mg/l (72 h, Selenastrum capricornutum (green algae))

Method: OECD Test Guideline 201 Source: Analogy

NOEC 5.6 mg/l (Selenastrum capricornutum (green algae)) Source: Analogy The values mentioned are those of the active ingredient.

Bacteria toxicity: not tested.

Remarks:

no data available



### Section 13 - Disposal considerations

Waste disposal information: Consult local, state, and federal regulations.

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RCRA hazardous waste:

No -- Not as sold.



### Section 14 - Transport information

DOT not restricted

IATA not restricted

IMDG not restricted



### Section 15 - Regulatory information

TSCA Status: One or more of the components of this product is not listed on the Toxic Substances Control Act (TSCA ) Inventory. The product is thus sold under the restriction that it is only for use in research and development. This product must be used under the supervision of a technically qualified individual capable of understanding its potential hazards.

SARA (section 311/312):

Acute Health Hazard

SARA 302 information: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 information: This product is not subject to SARA Title III Section 313 reporting requirements under 40 CFR

372.

Clean Water Act: Contains no known priority pollutants at concentrations greater than 0.1%.



### Section 16 - Other information

Other precautions: Observe national and local legal requirements

Label information:

WARNING!

Causes eye irritation. The TSCA Inventory status of the product has not been evaluated. It is provided only for research and development under the supervision of an individual technically qualified to understand its potential hazards.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

EYE CONTACT: Immediately flush eyes with water, occasionally lifting upper and
lower lids, until no evidence of chemical remains. After contact with skin, wash immediately with plenty of water. Consult a physician after significant exposure. Get

# MATERIAL SAFETY DATA SHEET

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medical attention immediately if irritation develops and persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician if irritation persists.

This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications.

# MATERIAL SAFETY DATA SHEET

Page 1

Substa nce key: Revision Date: 12/09/2014

Version : 4 - 2 / USA Date of printing :12/09/2014



### Section 01 - Product and company identification

Identification of the

company:

Information of the substance/preparation:

Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name:

Material number:

Primary product use: Auxiliary for formulating plant protection products

Primary product use: Raw material for detergents

Primary product use: Raw material for cosmetics

Chemical family: in aqueous/alcoholic solution



### Section 02 - Hazards identification

Emergency overview: Colorless liquid with characteristic odor. Causes severe eye irritation.

Expected Route of entry:

Inhalation: Vapors and/or mists are probably irritating to respiratory passages, nose, and throat.

Skin contact: Not expected to be irritating to skin. Eye contact: Causes serious eye irritation. Danger of serious damage to eyes. Ingestion: The acute oral toxicity of this material is between 500 and 5000 mg/kg. Relative to other materials, this material is classified as slightly toxic by ingestion. Skin absorption: Eye contact Ingestion

Inhalation

Health effects of exposure:

Severe eye iritant with a risk of serious damage to the eyes.

Propylene Glycol ( 57-55-6 ) In addition to any hazardous ingredients listed in the OSHA Hazardous Ingredient Section of the Material Safety Data Sheet (MSDS), this product contains propylene glycol. As part of , we wish to notify you that the American Industrial

# MATERIAL SAFETY DATA SHEET

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Hygiene Association (AIHA) has recommended an 8 hour Time Weighted Average (TWA) Workplace Environmental Exposure Level (WEEL) for propylene glycol. See Section 08 - Exposure controls / personal protection for details.

Known effects on other illnesses: None known.

Listed carcinogen: Other: No

NTP - National Toxicology Program Report: Not

listed

International Agency for Research on Cancer (IARC) - Overall Evaluations of Carcinogenicity to

Humans.: Not listed

OSHA Specifically Regulated Chemicals/Carcinogens: Not listed

HMIS:

Health: 2 Flammability: 1 Reactivity: 0 Personal protection: D



### Section 03 - Composition/information on ingredients

Hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

45 - 48 %

Non-hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

Propylene Glycol 57-55-6 <= 10 %



### Section 04 - First aid measures

After inhalation:

Move the victim to fresh air. Give oxygen or artificial respiration if needed.

Get immediate medical advice/ attention. Never give anything by mouth to an unconscious person.

After contact with skin: Immediately flush skin with plenty of water while removing contaminated clothing. Wash contaminated clothing before reuse. If redness or irritation occurs, seek medical attention.

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After contact with eyes: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical

attention.

After ingestion: If conscious, give the patient 1-2 glasses of water (8-16 oz.) and call a doctor. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a

doctor or nurse.

Advice to doctor / Treatment: Treat symptomatically.



### Section 05 - Fire fighting measures

Flashpoint: Method: EN 22719 (closed cup) No flash point - Measure made up to the boiling point.

Lower explosion limit: not tested.

Upper explosion limit: not tested.

Self ignition: > 752 °F

Method: EC A.16 Information refers to the main component.

Ignition temperature: not tested.

Hazardous combustion products: In case of fire hazardous decomposition products may be produced such as: Nitrogen oxides (NOx)

Carbon monoxide

Extinguishing media: Water spray jet

Alcohol-resistant foam Carbon dioxide (CO2) Dry powder

Special fire fighting procedure: Wear full protective clothing and self-contained breathing apparatus.



### Section 06 - Accidental release measures

Steps to be taken in case of spill or leak: Wearing appropriate personal protective equipment, contain spill, ventilate area of spill or leak, remove all sparking devices or ignition sources, collect onto inert absorbent, and place

in a suitable container.



### Section 07 - Handling and storage

Advice on safe handling: Use only with adequate ventilation and proper protective eyewear, gloves, and clothing.

# MATERIAL SAFETY DATA SHEET

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Further info on storage conditions: Keep container closed.



### Section 08 - Exposure controls / personal protection

Occupational exposure limits:

Component CAS

number: Regulatory list Type of value Values / Remarks

propylene glycol 57-55-6 USA. Workplace

Environmental Exposure Levels (WEEL) 8-hr TWA 10 mg/m3

Respiratory protection: If airborne concentrations pose a health hazard, become irritating, or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29CFR1910.134.

Hand protection: Chemical resistant gloves (butyl rubber, nitrile rubber, polyvinyl alcohol). However, please note that PVA degrades in water.

Eye protection: Safety goggles or full face shield to protect against splashes.

Other protective equipment: Wear suitable protective equipment.



### Section 09 - Physical and chemical properties

Form: Liquid

Color: colourless

Odor: characteristic

Odor limit: not tested.

pH: 8 - 10 (20 °C, 10 g/l)

Solubility in water: (40 °C)

soluble

Soluble in ... : 1-octanol 47 g/l ( 20 °C)

Method: OECD Test Guideline 105 Data corresponds to that of the active component

Density: approx. 1.078 g/cm3 (20 °C)

Method: DIN 51757

Melting point : approx. 50 °F

Boiling point : approx. 212 °F

Based on water-content.

Evaporation number: not tested.

# MATERIAL SAFETY DATA SHEET

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Vapor pressure: 1.73 Torr (25 °C)

Method: EEC 84/449 A.4 Corresp. to vapour pressure of water

Bulk density: Not applicable

Relative vapor density: not tested.

Partitioning coef.

octanol/water: 1.43

Method: Calculated from the solubilities Information refers to the main component.

Viscosity / (dynamic): approx. 36.4 mPa.s (40 °C)

Method: ISO 2555

Viscosity / (kinematic): approx. 35 mm2/s ( 40 °C)

Method: ISO 2555



### Section 10 - Stability and reactivity

Thermal decomposition: > 200 °C (Heating rate:3 K/min)

Method: DSC

Chemical stability: Stable under normal conditions.

Hazardous Polymerization:

Conditions to avoid: None known.



### Section 11 - Toxicological information

Product information:

Acute oral toxicity: LD50 5,000 mg/kg (Rat)

Method: OECD Test Guideline 423

Acute inhalation toxicity: LC50 > 1 - 5 mg/l (4 h, Rat )

Method: OECD Test Guideline 436

Acute dermal toxicity: LD50 > 2,000 mg/kg (Rat)

Method: OECD Test Guideline 402 Information refers to the main component.

Skin irritation: No skin irritation (EPISKIN Human Skin Model Test)

Method: OECD Test Guideline 439 Information refers to the main component.

Eye irritation: strongly irritant (Bovine cornea)

Method: OECD Test Guideline 437 Information refers to the main component.

Sensitization: non-sensitizing (Guinea pig)

Method: OECD Test Guideline 406 Information refers to the main component.

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### Section 12 - Ecological information

Product information:

Biodegradation: > 80 % (28 d)

Method: OECD Test Guideline 301B

The data refer to the technical active substance

Fish toxicity: LC50 > 100 mg/l (96 h, Danio rerio (zebra fish))

Method: OECD Test Guideline 203 The values mentioned are those of the active ingredient.

Daphnia toxicity: EC50 > 100 mg/l (48 h, Daphnia magna (Water flea))

Method: OECD Test Guideline 202 The values mentioned are those of the active ingredient.

Algae toxicity: EC50 > 100 mg/l (72 h, Desmodesmus subspicatus (Scenedesmus subspicatus))

Method: OECD Test Guideline 201 The values mentioned are those of the active ingredient.

NOEC 100 mg/l (72 h, Desmodesmus subspicatus (Scenedesmus subspicatus))

Method: OECD Test Guideline 201 The values mentioned are those of the active ingredient.

Bacteria toxicity: EC50 > 1,000 mg/l (activated sludge)

Method: OECD Test Guideline 209 The values mentioned are those of the active ingredient.

Remarks:

no data available



### Section 13 - Disposal considerations

Waste disposal information: Consult local, state, and federal regulations.

RCRA hazardous waste:

No -- Not as sold.



### Section 14 - Transport information

DOT not restricted

IATA not restricted

IMDG not restricted



### Section 15 - Regulatory information

TSCA Status:

# MATERIAL SAFETY DATA SHEET

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One or more of the components of this product is not listed on the Toxic Substances Control Act (TSCA ) Inventory. The product is thus sold under the restriction that it is only for use in research and development. This product must be used under the supervision of a technically qualified individual capable of understanding its potential hazards.

SARA (section 311/312):

Acute Health Hazard

SARA 302 information: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 information: This product is not subject to SARA Title III Section 313 reporting requirements under 40 CFR

372.

Clean Water Act: Contains no known priority pollutants at concentrations greater than 0.1%.



### Section 16 - Other information

Other precautions: Observe national and local legal requirements

Warning: This product is to be used for purposes of research and development only. It must be used under the direct supervision of a technically qualified individual. Any other use will subject the user to penalties under the Toxic Substances Control Act and the regulations

issued thereunder.

Label information:

WARNING!

Causes serious eye irritation. Risk of serious damage to eyes. Not listed on TSCA It is provided only for research and development under the supervision of an individual technically qualified to understand its potential hazards.

Wash thoroughly with soap and water after handling.

IF IN EYES: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. Skin contact: wash thoroughly with soap and water for 15 minutes. If skin irritation occurs, seek medical attention. Wash contaminated clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician if irritation persists. Ingestion: if conscious, give the patient 1-2 glasses of water (8-16 oz.) Seek medical attention. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a doctor or nurse.

This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are

# MATERIAL SAFETY DATA SHEET

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believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications.

# MATERIAL SAFETY DATA SHEET

Page 1

Substa nce key: Revision Date: 12/09/2014

Version : 2 - 3 / USA Date of printing :12/09/2014



### Section 01 - Product and company identification

Identification of the

company:

Information of the substance/preparation:

Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name:

Primary product use: Raw material for detergents

Chemical family: in Propylenglykol



### Section 02 - Hazards identification

Emergency overview: Yellow solid Causes severe eye irritation.

Expected Route of entry:

Inhalation: Vapors and/or mists are probably irritating to respiratory passages, nose, and throat.

Skin contact: Not expected to be irritating to skin. Eye contact: Causes serious eye irritation. Danger of serious damage to eyes. Ingestion: The acute oral toxicity of this material is between 500 and 5000 mg/kg. Relative to other materials, this material is classified as slightly toxic by ingestion. Skin absorption: Eye contact Ingestion

Inhalation

Health effects of exposure:

Severe eye iritant with a risk of serious damage to the eyes.

Propylene Glycol ( 57-55-6 ) In addition to any hazardous ingredients listed in the OSHA Hazardous Ingredient Section of the Material Safety Data Sheet (MSDS), this product contains propylene glycol. As part of , we wish to notify you that the American Industrial Hygiene Association (AIHA) has recommended an 8 hour Time Weighted Average (TWA) Workplace Environmental Exposure Level (WEEL) for propylene glycol. See Section 08 - Exposure controls / personal protection for details.

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Glycerine ( 56-81-5 ) Glycerine: In the form of a mist it is an inhalation irritant. Essentially no significant irritation upon skin and eye contact. Not absorbed through the skin.

Known effects on other illnesses: None known.

Listed carcinogen: OSHA Specifically Regulated Chemicals/Carcinogens: Not listed

NTP - National Toxicology Program Report: Not

listed

International Agency for Research on Cancer (IARC) - Overall Evaluations of Carcinogenicity to

Humans.: Not listed

Other: No

HMIS:

Health: 2 Flammability: 1 Reactivity: 0 Personal protection: D



### Section 03 - Composition/information on ingredients

Hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

>= 60 - <= 80 % Glycerine 56-81-5 >= 5 - <= 10 %

Non-hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

Propylene Glycol 57-55-6 >= 15 - <= 25 %



### Section 04 - First aid measures

After inhalation:

Move the victim to fresh air. Give oxygen or artificial respiration if needed.

Get immediate medical advice/ attention. Never give anything by mouth to an unconscious person.

After contact with skin: Immediately flush skin with plenty of water while removing contaminated clothing. Wash contaminated clothing before reuse. If redness or irritation occurs, seek medical attention.

# MATERIAL SAFETY DATA SHEET

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After contact with eyes: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical

attention.

After ingestion: If conscious, give the patient 1-2 glasses of water (8-16 oz.) and call a doctor. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a

doctor or nurse.

Advice to doctor / Treatment: Treat symptomatically.



### Section 05 - Fire fighting measures

Flashpoint: Not applicable

Lower explosion limit: not tested.

Upper explosion limit: not tested.

Self ignition: Method: EC A.16 no relative self-ignition temperature below 400 °C

Ignition temperature: not tested.

Hazardous combustion products: In case of fire hazardous decomposition products may be produced such as: Nitrogen oxides (NOx)

Carbon monoxide

Extinguishing media: Water spray jet

Alcohol-resistant foam Carbon dioxide (CO2) Dry powder

Special fire fighting procedure: Wear full protective clothing and self-contained breathing apparatus.



### Section 06 - Accidental release measures

Steps to be taken in case of spill or leak: Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent, and place in a suitable container. Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.



### Section 07 - Handling and storage

Advice on safe handling: Use only with adequate ventilation and proper protective eyewear, gloves, and clothing.

Further info on storage conditions: Keep container closed.

# MATERIAL SAFETY DATA SHEET

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### Section 08 - Exposure controls / personal protection

Occupational exposure limits:

Component CAS

number: Regulatory list Type of value Values / Remarks

propylene glycol 57-55-6 USA. Workplace

Environmental Exposure Levels (WEEL) 8-hr TWA 10 mg/m3

Glycerin (mist) ( Dust and mist) 56-81-5 USA. OSHA -

TABLE Z-1 Limits

for Air

Contaminants -

1910.1000 8-hour time weighted

average 10 mg/m3

Glycerin (mist) ( Dust and mist) 56-81-5 USA. OSHA -

TABLE Z-1 Limits

for Air

Contaminants -

1910.1000 8-hour time weighted

average 5 mg/m3

Glycerin mist ( Mist) 56-81-5 USA. ACGIH

Threshold Limit Values (TLV) 8-hour, timeweighted

average 10 mg/m3

glycerin ( Mist) 56-81-5 USA. Occupational Exposure Limits (OSHA) - Table Z-1

Limits for Air

Contaminants 8-hour time weighted

average 15 mg/m3

glycerin ( Mist) 56-81-5 USA. Occupational Exposure Limits (OSHA) - Table Z-1

Limits for Air

Contaminants 8-hour time weighted

average 5 mg/m3

glycerin 56-81-5 USA. Occupational Exposure Limits (OSHA) - Table Z-1

Limits for Air

Contaminants 8-hour time weighted

average 5 mg/m3

glycerin 56-81-5 USA. Occupational Exposure Limits (OSHA) - Table Z-1

Limits for Air

Contaminants 8-hour time weighted

average 15 mg/m3

Glycerin 56-81-5 USA. OSHA -

TABLE Z-1 Limits

for Air

Contaminants -

1910.1000 8-hour time weighted

average 10 mg/m3

Glycerin 56-81-5 USA. OSHA -

TABLE Z-1 Limits

for Air

Contaminants -

1910.1000 8-hour time weighted

average 5 mg/m3

# MATERIAL SAFETY DATA SHEET

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Respiratory protection: If airborne concentrations pose a health hazard, become irritating, or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29CFR1910.134.

Hand protection: Wear protective gloves. Rubber gloves Neoprene gloves

Eye protection: Tightly fitting safety goggles

Other protective equipment: Wear suitable protective equipment.

Advice on system design: Local ventilation recommended - mechanical ventilation may

be used.



### Section 09 - Physical and chemical properties

Form: solid

Color: white yellowish

Odor: characteristic

Odor limit: not tested.

pH: 8 - 10 (50 °C, 10 g/l)

Solubility in water: soluble

Soluble in ... : 1-octanol 36 g/l ( 20 °C)

Method: OECD Test Guideline 105

Density: 1.09 g/cm3 (22.8 °C)

Method: OECD Test Guideline 109

Melting point : approx. 122 °F

Method: OECD Test Guideline 102

Boiling point : Method: OECD Test Guideline 103 Decomposes below the boiling point.

Evaporation number: Not applicable

Vapor pressure: < 0 Torr (20 °C)

Method: OECD Test Guideline 104

Bulk density: not tested.

Relative vapor density: Not applicable

Partitioning coef.

octanol/water: 3.8

Method: Calculated from the solubilities

Viscosity / (dynamic): not tested.

Viscosity / (kinematic): not tested.

# MATERIAL SAFETY DATA SHEET

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### Section 10 - Stability and reactivity

Thermal decomposition: > 450 °C (Heating rate:3 K/min)

Method: DSC Source: Analogy

Chemical stability: Stable under normal conditions.

Hazardous Polymerization:

Hazardous Polymerization: no

Conditions to avoid: None known.



### Section 11 - Toxicological information

Product information:

Acute oral toxicity: LD50 > 2,000 mg/kg (Rat)

Method: OECD Test Guideline 423 Source: Analogy

Acute inhalation toxicity: not tested.

Acute dermal toxicity: LD50 Dermal > 2,000 mg/kg (Rat)

Method: OECD Test Guideline 402

Skin irritation: No skin irritation

Method: OECD Test Guideline 439

Eye irritation: non-irritant (rabbit eye)

Method: OECD Test Guideline 405

Sensitization: non-sensitizing

Method: OECD Test Guideline 406 Source: Analogy



### Section 12 - Ecological information

Product information:

Biodegradation: > 60 % (28 d)

Method: OECD Test Guideline 301B

Fish toxicity: LC50 2 mg/l (96 h, Danio rerio (zebra fish))

Method: OECD Test Guideline 203 Source: Analogy

Daphnia toxicity: EC50 > 1 mg/l (48 h, Daphnia magna (Water flea))

Method: OECD Test Guideline 202

Algae toxicity: EC50 > 80 mg/l (72 h, Selenastrum capricornutum (green algae))

Method: OECD Test Guideline 201

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NOEC 80 mg/l (72 h, Selenastrum capricornutum (green algae))

Method: OECD Test Guideline 201

Bacteria toxicity: EC50 > 5,000 mg/l (3 h, activated sludge)

Method: OECD Test Guideline 209

Remarks:

no data available



### Section 13 - Disposal considerations

Waste disposal information: Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.

RCRA hazardous waste:

No -- Not as sold.



### Section 14 - Transport information

DOT not restricted

IATA not restricted

IMDG not restricted



### Section 15 - Regulatory information

TSCA Status: One or more of the components of this product is not listed on the Toxic Substances Control Act (TSCA ) Inventory. The product is thus sold under the restriction that it is only for use in research and development. This product must be used under the supervision of a technically qualified individual capable of understanding its potential hazards.

SARA (section 311/312):

Acute Health Hazard

SARA 302 information: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 information: This product is not subject to SARA Title III Section 313 reporting requirements under 40 CFR

372.

Clean Water Act: Contains no known priority pollutants at concentrations greater than 0.1%.

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### Section 16 - Other information

Other precautions: Observe national and local legal requirements

Warning: This product is to be used for purposes of research and development only. It must be used under the direct supervision of a technically qualified individual. Any other use will subject the user to penalties under the Toxic Substances Control Act and the regulations

issued thereunder.

Label information:

WARNING!

Causes serious eye irritation. Risk of serious damage to eyes. Not listed on TSCA It is provided only for research and development under the supervision of an individual technically qualified to understand its potential hazards.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

IF IN EYES: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. Skin contact: wash thoroughly with soap and water for 15 minutes. If skin irritation occurs, seek medical attention. Wash contaminated clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician if irritation persists. Ingestion: if conscious, give the patient 1-2 glasses of water (8-16 oz.) Seek medical attention. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a doctor or nurse.

This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications.

# MATERIAL SAFETY DATA SHEET

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### Section 01 - Product and company identification

Identification of the

company:

Information of the substance/preparation:

Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name:

Material number:

Primary product use: Raw material for cosmetics

Primary product use: Raw material for detergents

Chemical family: in aqueous-alcoholic solution



### Section 02 - Hazards identification

Emergency overview: Light yellow paste

Flammable Causes severe eye irritation.

Expected Route of entry:

Inhalation: Vapors and/or mists are probably irritating to respiratory passages, nose, and throat.

Skin contact: Not expected to be irritating to skin. Eye contact: Causes serious eye irritation. Danger of serious damage to eyes. Ingestion: The acute oral toxicity of this material is between 500 and 5000 mg/kg. Relative to other materials, this material is classified as slightly toxic by ingestion.

Health effects of exposure:

Causes s evere eye irritation with the risk of serious eye damage.

Ethanol ( 64-17-5 ) Ethanol: Concentrations exceeding 1000 ppm may cause irritation to the eyes and upper respiratory tract. If exposure at high concentrations is prolonged, stupor and drowsiness may occur. A central nervous system depressant. Can cause glandular effects in humans. Reported to be an equivocal tumorigenic agent and a suspect teratogen. Ingestion may cause nausea vomiting, abdominal pain, headache, and dizziness, shortness of breath, drunken behavior, visual disturbances drowsiness, coma, or death. Visual effects include blurred

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vision, diplopia, restriction of visual fields and complete blindness. According to IARC Monograph vol.44, there is inadequate evidence for the carcinogenicity of ethanol and alcoholic beverages in experimental animals. There is sufficient evidence for the carcinogenicity of alcoholic beverages in humans.

Propylene Glycol ( 57-55-6 ) In addition to any hazardous ingredients listed in the OSHA Hazardous Ingredient Section of the Material Safety Data Sheet (MSDS), this product contains propylene glycol. As part of , we wish to notify you that the American Industrial Hygiene Association (AIHA) has recommended an 8 hour Time Weighted Average (TWA) Workplace Environmental Exposure Level (WEEL) for propylene glycol. See Section 08 - Exposure controls / personal protection for details.

Known effects on other illnesses: None known.

Listed carcinogen: OSHA Specifically Regulated Chemicals/Carcinogens: Not listed

NTP - National Toxicology Program Report: Not

listed

International Agency for Research on Cancer (IARC) - Overall Evaluations of Carcinogenicity to

Humans.: Not listed

Other: No

HMIS:

Health: 2 Flammability: 1 Reactivity: 0 Personal protection: H



### Section 03 - Composition/information on ingredients

Hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

50 - 60 %

Ethyl alcohol 64-17-5 < 11 %

Non-hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

1,2-Propanediol 57-55-6 <= 10 %



### Section 04 - First aid measures

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After inhalation:

Move the victim to fresh air. Give oxygen or artificial respiration if needed.

Get immediate medical advice/ attention. Never give anything by mouth to an unconscious person.

After contact with skin: Immediately flush skin with plenty of water while removing contaminated clothing. Wash contaminated clothing before reuse. If redness or irritation occurs, seek medical attention.

After contact with eyes: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

After ingestion: If swallowed give patient 2 glasses of water.

Get immediate medical advice/ attention.

Advice to doctor / Treatment: Treat symptomatically.



### Section 05 - Fire fighting measures

Flashpoint: not tested.

Lower explosion limit: 3.1 %(V)

Data relate to solvent

Upper explosion limit: 27.7 %(V)

Data relate to solvent

Self ignition: > 275 °F

Method: EC A.16

Ignition temperature: not tested.

Hazardous combustion products: In case of fire hazardous decomposition products may be produced such as: Nitrogen oxides (NOx)

Carbon monoxide

Extinguishing media: Water spray jet

Alcohol-resistant foam Carbon dioxide (CO2) Dry powder

Special fire fighting procedure: Wear suitable protective equipment.



### Section 06 - Accidental release measures

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Steps to be taken in case of spill or leak: Wearing appropriate personal protective equipment, contain spill, ventilate area of spill or leak, remove all sparking devices or ignition sources, collect onto inert absorbent, and place

in a suitable container.



### Section 07 - Handling and storage

Advice on safe handling: Keep away from heat, sparks and open flames. - Avoid breathing vapors or contact with skin, eyes, and clothing.- Use only with adequate ventilation and proper protective eyewear, face shield, gloves and clothing. Wash thoroughly after handling. Keep container closed.

Further info on storage conditions: Keep container closed.



### Section 08 - Exposure controls / personal protection

Occupational exposure limits:

Component CAS

number: Regulatory list Type of value Values / Remarks

Ethanol 64-17-5 USA. ACGIH

Threshold Limit Values (TLV) 8-hour, timeweighted

average 1,000 ppm

ethyl alcohol

ethanol 64-17-5 USA. Occupational Exposure Limits (OSHA) - Table Z-1

Limits for Air

Contaminants 8-hour time weighted

average 1,000 ppm; 1,900 mg/m3

Ethyl alcohol

Ethanol 64-17-5 USA. OSHA -

TABLE Z-1 Limits

for Air

Contaminants -

1910.1000 8-hour time weighted

average 1,000 ppm; 1,900 mg/m3

Ethanol 64-17-5 USA. ACGIH

Threshold Limit Values (TLV) Short-term exposure limit 1,000 ppm

Occupational exposure limits:

Component CAS

number: Regulatory list Type of value Values / Remarks

propylene glycol 57-55-6 USA. Workplace

Environmental Exposure Levels (WEEL) 8-hr TWA 10 mg/m3

Respiratory protection: If airborne concentrations pose a health hazard, become irritating, or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29CFR1910.134.

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Hand protection: Chemical resistant gloves

Eye protection: Safety goggles or full face shield to protect against splashes.

Other protective equipment: Wear suitable protective equipment.



### Section 09 - Physical and chemical properties

Form: paste

Color: yellow

Odor: characteristic

Odor limit: not tested.

pH: 8 - 10 (35 °C, 10 g/l)

Solubility in water: (40 °C)

soluble

Soluble in ... : 1-octanol 28 g/l ( 20 °C)

Method: OECD Test Guideline 105 Data corresponds to that of the active component

Density: 1.03 g/cm3 (50 °C)

Method: DIN 51757

Melting point : approx. 93 °F

Boiling point : 172 °F

Data relate to solvent

Evaporation number: not tested.

Vapor pressure: 1.05 Torr (25 °C)

Method: EEC 84/449 A.4

Bulk density: Not applicable

Relative vapor density: not tested.

Partitioning coef.

octanol/water: 2.25 Information refers to the main component.

Viscosity / (dynamic): not tested.

Viscosity / (kinematic): not tested.



### Section 10 - Stability and reactivity

Thermal decomposition: > 200 °C (Heating rate:3 K/min)

Method: DSC

Chemical stability: Stable under normal conditions.

Hazardous Polymerization: Hazardous polymerisation does not occur.

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Conditions to avoid: None known.



### Section 11 - Toxicological information

Product information:

Acute oral toxicity: LD50 > 2,000 mg/kg (Rat)

Method: OECD Test Guideline 401

Acute inhalation toxicity: not tested.

Acute dermal toxicity: LD50 > 2,000 mg/kg (Rabbit)

Method: OECD Test Guideline 402 By analogy with a product of similar composition

Skin irritation: No skin irritation (Rabbit)

Method: OECD Test Guideline 404

Eye irritation: Risk of serious damage to eyes. (rabbit eye)

Method: OECD Test Guideline 405

Sensitization: non-sensitizing

Method: OECD Test Guideline 406 Source: Analogy



### Section 12 - Ecological information

Product information:

Biodegradation: > 80 %

Method: OECD Test Guideline 301B

Fish toxicity: LC50 7.5 mg/l (96 h, Danio rerio (zebra fish))

Method: OECD Test Guideline 203

NOEC 4.8 mg/l (35 d, Pimephales promelas (fathead minnow)) The values mentioned are those of the active ingredient.

Daphnia toxicity: EC50 18 mg/l (48 h, Daphnia magna (Water flea))

NOEC 4.3 mg/l (21 d, Daphnia magna (Water flea)) The values mentioned are those of the active ingredient.

Algae toxicity: EC50 30 mg/l (72 h, Selenastrum capricornutum (green algae))

Method: OECD Test Guideline 201

NOEC 5.6 mg/l (Selenastrum capricornutum (green algae)) The values mentioned are those of the active ingredient.

Bacteria toxicity: not tested.

Remarks:

no data available

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### Section 13 - Disposal considerations

Waste disposal information: Consult local, state, and federal regulations.

RCRA hazardous waste:

Yes -- If it becomes a waste as sold.

RCRA number: D001



### Section 14 - Transport information

DOT not restricted

IATA not restricted

IMDG not restricted



### Section 15 - Regulatory information

TSCA Status: One or more of the components of this product is not listed on the Toxic Substances Control Act (TSCA ) Inventory. The product is thus sold under the restriction that it is only for use in research and development. This product must be used under the supervision of a technically qualified individual capable of understanding its potential hazards.

SARA (section 311/312):

Acute Health Hazard

SARA 302 information: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 information: This product is not subject to SARA Title III Section 313 reporting requirements under 40 CFR

372.

Clean Water Act: Contains no known priority pollutants at concentrations greater than 0.1%.

# MATERIAL SAFETY DATA SHEET

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### Section 16 - Other information

Other precautions: Observe national and local legal requirements

Warning: This product is to be used for purposes of research and development only. It must be used under the direct supervision of a technically qualified individual. Any other use will subject the user to penalties under the Toxic Substances Control Act and the regulations

issued thereunder.

Label information:

WARNING!

Flammable Causes serious eye irritation. Risk of serious damage to eyes. It is provided only for research and development under the supervision of an individual technically qualified to understand its potential hazards. Not listed on TSCA

Avoid breathing dust or vapour. Avoid contact with skin, eyes and clothing. Keep container closed when not in use. Use ventilation and/or respiratory protection in order to keep exposure levels to a minimum. Wash thoroughly after handling.

IF IN EYES: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. SKIN CONTACT: immediately remove contaminated clothing and shoes and wash affected area thoroughly with soap and water. Get medical attention immediately if irritation persists. Wash clothing before reuse. Ingestion: if conscious, give the patient 1-2 glasses of water (8-16 oz.) Seek medical attention. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a doctor or nurse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician if irritation persists.

This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications.

# MATERIAL SAFETY DATA SHEET

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### Section 01 - Product and company identification

Identification of the

company:

Information of the substance/preparation:

Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name:

Material number:

Primary product use: Raw material for cosmetics

Chemical family: in aqueous-alcoholic solution



### Section 02 - Hazards identification

Emergency overview: Light yellow paste Causes severe eye irritation.

Expected Route of entry:

Inhalation: Vapors and/or mists are probably irritating to respiratory passages, nose, and throat.

Skin contact: Not expected to be irritating to skin. Eye contact: Causes serious eye irritation. Danger of serious damage to eyes. Ingestion: The acute oral toxicity of this material is between 500 and 5000 mg/kg. Relative to other materials, this material is classified as slightly toxic by ingestion. Skin absorption: Eye contact Ingestion

Inhalation

Known effects on other illnesses: None known.

Listed carcinogen: Other: No

NTP - National Toxicology Program Report: Not

listed

International Agency for Research on Cancer (IARC) - Overall Evaluations of Carcinogenicity to

Humans.: Not listed

OSHA Specifically Regulated

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Chemicals/Carcinogens: Not listed

HMIS:

Health: 2 Flammability: 1 Reactivity: 0 Personal protection: D



### Section 03 - Composition/information on ingredients

Hazardous ingredients:

Component CAS-no. (Trade secret no.) Concentration

20 - 35 %

Methanol 67-56-1 < 0.2 %



### Section 04 - First aid measures

After inhalation:

Move the victim to fresh air. Give oxygen or artificial respiration if needed.

Get immediate medical advice/ attention. Never give anything by mouth to an unconscious person.

After contact with skin: Immediately flush skin with plenty of water while removing contaminated clothing. Wash contaminated clothing before reuse. If redness or irritation occurs, seek medical attention.

After contact with eyes: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical

attention.

After ingestion: If conscious, give the patient 1-2 glasses of water (8-16 oz.) and call a doctor. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a

doctor or nurse.

Advice to doctor / Treatment: Treat symptomatically.



### Section 05 - Fire fighting measures

Flashpoint: Not applicable

Lower explosion limit: not tested.

Upper explosion limit: not tested.

Self ignition: > 275 °F

Method: EC A.16 Source: Analogy

Ignition temperature: not tested.

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Hazardous combustion products: In case of fire hazardous decomposition products may be produced such as: Nitrogen oxides (NOx)

Carbon monoxide

Extinguishing media: Water spray jet

Alcohol-resistant foam Carbon dioxide (CO2) Dry powder

Special fire fighting procedure: Wear full protective clothing and self-contained breathing apparatus.



### Section 06 - Accidental release measures

Steps to be taken in case of spill or leak: Contain spill. Ensure adequate ventilation and wear appropriate personal protective equipment. Collect onto inert absorbent. Place in sealable container. Do not allow to

contaminate water sources or sewers.



### Section 07 - Handling and storage

Advice on safe handling: Use only with adequate ventilation and proper protective eyewear, gloves, and clothing. Wash thoroughly after handling.

Further info on storage conditions: Keep container closed.



### Section 08 - Exposure controls / personal protection

Respiratory protection: If airborne concentrations pose a health hazard, become irritating, or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29CFR1910.134.

Hand protection: Wear protective gloves.

PVC

Nitrile rubber Neoprene gloves

Eye protection: Safety goggles or full face shield to protect against splashes.

Other protective equipment: Wear suitable protective equipment.



### Section 09 - Physical and chemical properties

Form: paste

Color: white yellowish

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Odor: characteristic

Odor limit: not tested.

pH: 5 - 7 (35 °C, 10 g/l)

Solubility in water: (40 °C)

soluble

Soluble in ... : 1-octanol 35 g/l ( 20 °C)

Method: OECD Test Guideline 105 Data corresponds to that of the active component

Density: approx. 1.025 g/cm3 (50 °C)

Method: DIN 51757

Melting point : approx. 99 °F

Boiling point : approx. 212 °F

Based on water-content.

Evaporation number: Not applicable

Vapor pressure: 1.73 Torr (25 °C) Corresp. to vapour pressure of water

Bulk density: not tested.

Relative vapor density: Not applicable

Partitioning coef.

octanol/water: 3.43 Information refers to the main component.

Viscosity / (dynamic): not tested.

Viscosity / (kinematic): not tested.



### Section 10 - Stability and reactivity

Thermal decomposition: > 200 °C (Heating rate:3 K/min)

Method: DSC

Chemical stability: Stable under normal conditions.

Hazardous Polymerization:

Conditions to avoid: None known.



### Section 11 - Toxicological information

Product information:

Acute oral toxicity: LD50 > 2,000 mg/kg (Rat)

Method: OECD Test Guideline 401 Source: Analogy By analogy with a product of similar composition

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Acute inhalation toxicity: not tested.

Acute dermal toxicity: LD50 > 2,000 mg/kg (Rabbit)

Method: OECD Test Guideline 402 Source: Analogy By analogy with a product of similar composition

Skin irritation: No skin irritation (Rabbit)

Method: OECD Test Guideline 404 Source: Analogy

Eye irritation: Risk of serious damage to eyes. (rabbit eye)

Method: OECD Test Guideline 405 Source: Analogy

Sensitization: non-sensitizing

Method: OECD Test Guideline 406 Source: Analogy



### Section 12 - Ecological information

Product information:

Biodegradation: > 80 %

Method: OECD Test Guideline 301B Source: Analogy

Fish toxicity: LC50 7.5 mg/l (96 h, Danio rerio (zebra fish))

Method: OECD Test Guideline 203 Source: Analogy

NOEC 4.8 mg/l (35 d, Pimephales promelas (fathead minnow)) Source: Analogy The values mentioned are those of the active ingredient.

Daphnia toxicity: EC50 approx. 7 mg/l (48 h, Daphnia magna (Water flea))

Method: OECD Test Guideline 202 The values mentioned are those of the active ingredient.

NOEC 1.84 mg/l (21 d, Daphnia magna (Water flea)) The values mentioned are those of the active ingredient.

Algae toxicity: EC50 30 mg/l (72 h, Selenastrum capricornutum (green algae))

Method: OECD Test Guideline 201 Source: Analogy

NOEC 5.6 mg/l (Selenastrum capricornutum (green algae)) Source: Analogy The values mentioned are those of the active ingredient.

Bacteria toxicity: not tested.

Remarks:

no data available

# MATERIAL SAFETY DATA SHEET

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### Section 13 - Disposal considerations

Waste disposal information: Consult local, state, and federal regulations.

RCRA hazardous waste:

No -- Not as sold.



### Section 14 - Transport information

DOT not restricted

IATA not restricted

IMDG not restricted



### Section 15 - Regulatory information

TSCA Status: This product is not listed on the TSCA Inventory. It is to be used as a cosmetic ingredient only. Any other use will subject the user to penalties under the Toxic Substances Control Act and the regulations issued thereunder.

SARA (section 311/312):

Acute Health Hazard

SARA 302 information: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 information: This product is not subject to SARA Title III Section 313 reporting requirements under 40 CFR

372.

CERCLA information: Component CAS no. Percentage RQ

Methanol Methyl alcohol 67-56-1 <= 0.2 % 5000

lbs

FDA: FDA regulated cosmetic ingredient.

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### Section 16 - Other information

Other precautions: Observe national and local legal requirements

Label information:

WARNING!

Causes serious eye irritation. Risk of serious damage to eyes. Not listed on TSCA Do not use for purposes other than as a cosmetic ingredient. It cannot be used for any commercial purposes except as a bona fide cosmetic or cosmetic adjuvant, additive or ingredient; or for use in Research and Development under the supervision of a technically qualified individual to understand its potential hazards.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

IF IN EYES: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. Skin contact: wash thoroughly with soap and water for 15 minutes. If skin irritation occurs, seek medical attention. Wash contaminated clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician if irritation persists. Ingestion: if conscious, give the patient 1-2 glasses of water (8-16 oz.) Seek medical attention. Never give anything by mouth to an unconscious person. Induce vomiting only at the instructions of a doctor or nurse.

This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications.