# Polyvinyl Chloride and Copolymers (PVC) Production

**Beyond The Floor Analysis**

**Resins**

**February 7, 2012**

**Worksheet Name** MACT Floor Emissions BTF Calcs TO Cost Summary Dryer Summary Emission Point Flow Rate Data Non-CBI Production Information CostIndex DataforPollutant Concentrations

# Polyvinyl Chloride and Copolymers (PVC) Production

**Beyond The Floor Analysis**

**Description** Summary of MACT Floor Emissions to use as Baseline for BTF Analysis Summary of Beyond the Floor Impacts - Resins Air Compliance Advisor Program Input-Outputs for Thermal Oxidizers Dryer Flow Rate Estimation for Facilities Facility Submitted Dryer Information Non-CBI Resin Production Information Chemical Engineering Cost Index OxyVinyls Dryer Stack Test Data

# ATTACHMENT B. BEYOND THE FLOOR ANALYSIS FOR RESINS

02/08/2012

**BEYOND THE FLOOR CALCULATIONS AND SUMMARY**

**Moisture Temperature**  **Supp Fuel Electricity**  **Vinyl Chloride Total Non-VC HAP**  **(fraction) Vinyl Chloride**  **Total Organic HAP DSCFM**  **Vinyl Chloride Total Non-VC HAP**  **% oF**  **2010 2010**  **Ft^3/yr kWh/yr**  Formosa - Delaware City Dispersion, Copolymer 32.1 33.0 0.98 31.4 32.4 101,882 7.634 7.863 8.9 130.6 $3,917,879 $369,820 $1,099,642 122,680,858 6,770,114 PolyOne - Henry Suspension, Dispersion, Suspension Blending 5.0 4.2 0.98 4.9 4.1 89,343 1.198 0.997 8.9 130.6 $2,409,618 $227,451 $936,040 107,847,525 5,936,871 PolyOne - Pedricktown Dispersion 2.9 1.3 0.98 2.8 1.3 92,477 0.684 0.307 8.9 130.6 $3,620,766 $341,775 $1,010,244 111,536,304 6,145,171 Dow - Midland Copolymer 0.0 0.0 0.98 0.004 0.02 15,357 0.001 0.005 8.9 130.6 $676,134 $63,822 $250,951 18,210,000 1,020,481 Formosa - Baton Rouge Suspension 0.2 18.2 0.98 0.242 17.88 652,045 0.059 4.345 8.9 130.6 $21,998,070 $2,076,462 $6,394,439 786,867,987 43,328,714 Formosa - Point Comfort Suspension 1.3 14.9 0.98 1.286 14.64 1,112,865 0.312 3.556 8.9 130.6 $37,255,660 $3,516,670 $10,839,013 1,344,871,287 73,950,429 Georgia Gulf - Aberdeen Suspension 9.3 113.1 0.98 9.108 110.81 711,606 2.213 26.921 8.9 130.6 $23,879,753 $2,254,079 $6,966,456 859,376,238 47,286,571 Georgia Gulf - Plaquemine Suspension 2.2 141.2 0.98 2.154 138.39 852,674 0.523 33.622 8.9 130.6 $28,336,452 $2,674,760 $8,307,374 1,026,528,053 56,660,571 OxyVinyls - Pasadena Suspension 5.8 81.1 0.98 5.672 79.50 1,493,747 1.378 19.314 8.9 130.6 $49,987,856 $4,718,499 $14,504,200 1,801,709,571 99,260,286 OxyVinyls - Pedricktown Suspension 1.2 6.9 0.98 1.183 6.80 249,219 0.287 1.652 8.9 130.6 $8,572,627 $809,195 $2,511,001 300,841,584 16,560,714 Shintech - Addis Suspension 1.9 21.3 0.98 1.869 20.89 443,578 0.454 5.074 8.9 130.6 $14,712,950 $1,388,798 $4,368,024 534,287,129 29,476,000 Shintech - Freeport Suspension 5.8 108.3 0.98 5.701 106.13 2,272,752 1.385 25.784 8.9 130.6 $75,297,743 $7,107,572 $22,002,896 2,746,501,650 151,025,714 Shintech - Plaquemine Suspension 2.2 44.2 0.98 2.152 43.32 924,775 0.523 10.525 8.9 130.6 $31,313,481 $2,955,770 $9,035,925 1,116,996,700 61,451,714 Westlake - Calvert City Suspension 7.5 136.3 0.98 7.305 133.54 782,065 1.775 32.444 8.9 130.6 $26,105,744 $2,464,197 $7,640,876 944,408,581 51,968,571 Westlake - Geismar Suspension 8.8 0.3 0.98 8.6 0.26 407,528 2.089 0.063 8.9 130.6 $13,573,966 $1,281,286 $4,028,385 492,574,257 27,080,429 **Totals 84.44**  **709.89 $341,658,699**  **$32,250,155 $99,895,466** 

**Facility Stream Parameters**  **Estimated Dryer Flow Rate**  **Pollutant Mass Flow Rate - ACA Input lb/hr**  **Part 63 Floor Emissions, tons/yr**  **TO Annual Cost Secondary Impacts**  **BTF Reductions, tons/yr TO TCI ($)**  **TO Redux Part 63**  **TO Total Annualized Capital Cost ($/yr)** 

# ATTACHMENT B. BEYOND THE FLOOR ANALYSIS FOR RESINS

02/08/2012

**RTO Cost Summary**

**TCI (2008 Dollars) $413,923,096**  In-Cell Calculation **Total Ann. Costs (2008 Dollars) $143,507,188**  Note: use "x" in include in summation line to select which facilities are included in the industry total cost estimate **TCI (2010 Dollars) $348,707,092**  **Total Ann. Costs (2010 Dollars) $134,742,473** 

**Include in Summation (x=yes)** x x x x x x x x x x x x x x **Dow Baton Rouge**  **Delaware Point Comfort**  **Aberdeen Plaquemine**  **Deer Park Pasadena**  **Pedricktown Henry**  **Pedricktown Addis**  **Freeport Plaquemine**  **Midland Calvert City**  **Geismar** Formosa - Baton RougeFormosa - Delaware City Formosa - Point Comfort Georgia Gulf - Aberdeen Georgia Gulf - Plaquemine

OxyVinyls - Deer ParkOxyVinyls - Pasadena OxyVinyls - Pedricktown PolyOne - Henry PolyOne - Pedricktown Shintech - Addis Shintech - Freeport Shintech - Plaquemine Dow - Midland Westlake - Calvert CityWestlake - Geismar 1 **Program Inputs** 2 Hours of Operation (per year) 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 8400 3 Total Dryer Exhaust Flow Rate (SCFM) 715,746.09 111,835.33 1,221,585.88 781,126.75 935,975.66 #REF! 1,639,677.95 273,566.42 98,070.98 101,512.07 486,913.81 2,494,788.06 1,015,120.66 16,857.21 858,468.96 447,341.31 4 Total Dryer Exhaust Flow Rate (DSCFM) 652,045 101,882 1,112,865 711,606 852,674 #REF! 1,493,747 249,219 89,343 92,477 443,578 2,272,752 924,775 15,357 782,065 407,528 5 Stream Temperature (F) 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 130.6 6 VC Flow Rate (lb/hr) (Assumed ALL TOH) 4 8 4 27 34 #REF! 19 2 1 0 5 26 11 0 32 0 7 Op. Labor Cost 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 34.6 8 Electricity Cost ($/kWh) 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 9 Interest Rate 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 10 Equipment Life 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 11 **Program Outputs** 12 Min % O2 Required 19.8 13 Op. Temp (R) 2660 14 Auxiliary Air Req (CFM) 0 15 Min Fuel Req (CFM) 1534 16 Auxiliary Fuel Req (CFM) 1561 243 2668 1705 2037 939 3575 597 214 221 1060 5449 2216 36 1874 977 17 Auxiliary Fule Req (Ft^3 per year) 786867987 122680858 1344871287 859376238 1026528053 473485149 1801709571 300841584 107847525 111536304 534287129 2746501650 1116996700 18210000 944408581 492574257 18 Electricity Requirments (kWh/yr) 43328714 6770114 73950429 47286571 56660571 26038857 99260286 16560714 5936871 6145171 29476000 151025714 61451714 1020481 51968571 27080429 19 Auxiliary Fuel Cost ($/yr) $2,384,210 20 Equipment Cost* 1.37E+07 21 Auxilary Equipment Cost 0 22 Total Equipment Cost 1.37E+07 23 Instrumentation Cost 1.37E+06 24 Sales Tax $412,341 25 Freight Cost $687,235 26 Purchased Equipment Cost 1.62E+07 27 Foundation Cost 1.30E+06 28 Equipment Erection Cost 2.27E+06 29 Electrical Cost $648,750 30 Piping Cost $324,375 31 Insulation Cost $162,188 32 Painting Cost $162,188 33 Direct Installation Cost 4.87E+06 34 Total Direct Capital Cost 2.11E+07 35 Engineering Cost 1.62E+06 36 Field Cost $810,938 37 Contractor Cost 1.62E+06 38 Start Up Cost $324,375 39 Performance Test Cost $162,188 40 Contingencies Cost $486,562 41 Total Indirect Capital Cost 5.03E+06 42 **Total Capital Investment (2008 Dollars) 2.61E+07**  **4.65E+06 4.42E+07**  **2.83E+07 3.36E+07**  **1.55E+07 5.93E+07**  **1.02E+07 2.86E+06**  **4.30E+06 1.75E+07**  **8.94E+07 3.72E+07**  **$802,586 3.10E+07**  **1.61E+07** 43 **Total Capital Investment (2010 Dollars) $21,998,070.20**  **$3,917,879.20 $37,255,660.49**  **$23,879,753.46 $28,336,451.51**  **$13,078,776.98 $49,987,855.94**  **$8,572,627.45 $2,409,617.74**  **$3,620,766.00 $14,712,950.14**  **$75,297,742.59 $31,313,480.66**  **$676,133.88 $26,105,743.64**  **$13,573,965.65** 44 Operating Labor $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 $18,152 45 Supervisory Labor $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 $2,723 46 Maintenance Labor $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 47 Maintenance Materials $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 48 Replacement Parts $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 49 Utilities 5.42E+06 $845,631 9.25E+06 5.91E+06 7.08E+06 3.26E+06 1.24E+07 2.07E+06 $742,359 $768,117 3.68E+06 1.89E+07 7.69E+06 $126,610 6.50E+06 3.39E+06 50

Electricity** 3.03E+06 $473,908 5.18E+06 3.31E+06 3.97E+06 1.82E+06 6.95E+06 1.16E+06 $415,581 $430,162 2.06E+06 1.06E+07 4.30E+06 $71,434 3.64E+06 1.90E+06 51 Total Direct Annual Cost 5.48E+06 $906,441 9.31E+06 5.97E+06 7.14E+06 3.32E+06 1.25E+07 2.13E+06 $803,169 $828,927 3.74E+06 1.90E+07 7.75E+06 $187,420 6.56E+06 3.45E+06 52 Overhead $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 $36,486 53 Administrative Charges $522,244 $93,012 $884,466 $566,916 $672,719 $310,497 1.19E+06 $203,518 $57,206 $85,959 $349,291 1.79E+06 $743,395 $16,052 $619,761 $322,252 54 Property Taxes $261,122 $46,506 $442,233 $283,458 $336,360 $155,248 $593,367 $101,759 $28,603 $42,979 $174,646 $893,801 $371,698 $8,026 $309,881 $161,126 55 Insurance $261,122 $46,506 $442,233 $283,458 $336,360 $155,248 $593,367 $101,759 $28,603 $42,979 $174,646 $893,801 $371,698 $8,026 $309,881 $161,126 56 Capital Recovery Factor 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 57 Capital Recovery 2.46E+06 $438,984 4.17E+06 2.68E+06 3.18E+06 1.47E+06 5.60E+06 $960,532 $269,990 $405,694 1.65E+06 8.44E+06 3.51E+06 $75,758 2.93E+06 1.52E+06 58 Total Indirect Annual Cost 3.55E+06 $661,495 5.98E+06 3.85E+06 4.56E+06 2.12E+06 8.01E+06 1.40E+06 $420,887 $614,098 2.38E+06 1.20E+07 5.03E+06 $144,348 4.20E+06 2.20E+06 59 Recovery Credit $0 $0 $0 $0 $0 60 **Total Annualized Cost (2008 Dollars) 9.02E+06**  **1.57E+06 1.53E+07**  **9.82E+06 1.17E+07**  **5.44E+06 2.05E+07**  **3.54E+06 1.22E+06**  **1.44E+06 6.13E+06**  **3.10E+07 1.28E+07**  **$331,768 1.08E+07**  **5.65E+06** 61 62 **2010 Cost Calculations** 63 Overhead (2010 Dollars) $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 64 Administrative Charges (2010 Dollars) $439,961.40 $78,357.58 $745,113.21 $477,595.07 $566,729.03 $261,575.54 $999,757.12 $171,452.55 $48,192.35 $72,415.32 $294,259.00 $1,505,954.85 $626,269.61 $13,522.68 $522,114.87 $271,479.31 65 Property Taxes (2010 Dollars) $219,980.70 $39,178.79 $372,556.60 $238,797.53 $283,364.52 $130,787.77 $499,878.56 $85,726.27 $24,096.18 $36,207.66 $147,129.50 $752,977.43 $313,134.81 $6,761.34 $261,057.44 $135,739.66 66 Insurance (2010 Dollars) $219,980.70 $39,178.79 $372,556.60 $238,797.53 $283,364.52 $130,787.77 $499,878.56 $85,726.27 $24,096.18 $36,207.66 $147,129.50 $752,977.43 $313,134.81 $6,761.34 $261,057.44 $135,739.66 67 Capital Recovery Factor 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 0.0943929 68 Capital Recovery (2010 Dollars) $2,076,461.64 $369,819.98 $3,516,669.83 $2,254,079.18 $2,674,759.83 $1,234,543.69 $4,718,498.69 $809,195.17 $227,450.81 $341,774.60 $1,388,798.03 $7,107,572.29 $2,955,770.25 $63,822.24 $2,464,196.85 $1,281,285.98 69 Total Indirect Annual Cost (2010 Dollars) $2,992,871 $563,021 $5,043,382 $3,245,755 $3,844,704 $1,794,181 $6,754,499 $1,188,586 $360,322 $523,091 $2,013,802 $10,155,968 $4,244,796 $127,354 $3,544,913 $1,860,731 70 Recovery Credit 71 **Total Annualized Cost (2010 Dollars) $8,470,901**  **$1,469,462 $14,355,682**  **$9,220,535 $10,982,134**  **$5,112,361 $19,222,699**  **$3,320,196 $1,163,491**  **$1,352,018 $5,756,822**  **$29,110,468 $11,991,696**  **$314,774 $10,105,073**  **$5,309,671** 72

* - Does not include auxialiary equipment ** - Represented as subpart of Utilities **Shintech Westlake**  **Formosa Georgia Gulf**  **OxyVinyls PolyOne** 

# ATTACHMENT B. BEYOND THE FLOOR ANALYSIS FOR RESINS

02/08/2012

DRYER DATA SUMMARY

Min Max Avg Formosa - Baton Rouge 9 323,496 240,226 917,121,920 652,045 Formosa - Delaware City2 143,300,300 101,882 Formosa - Point Comfort1 1,565,280,200 1,112,865 Georgia Gulf - Aberdeen 7 1,000,897,480 711,606 Georgia Gulf - Plaquemine 16 1,199,313,280 852,674 OxyVinyls - Deer Park 2 551,155,000 391,854 OxyVinyls - Pasadena 7 325,468 2,101,002,860 1,493,747 OxyVinyls - Pedricktown 3 81,055 350,534,580 249,219 PolyOne - Henry 7 154,826 96,576 76,007,292 145 668 125,663,340 89,343 PolyOne - Pedricktown 2 39,809,584 130,072,580 92,477 Shintech - Addis 1 623,907,460 443,578 Shintech - Freeport 1 3,196,699,000 2,272,752 Shintech - Plaquemine 1 1,300,725,800 924,775 Dow - Midland 1 21,600,000 41 15,357 1 Westlake - Calvert City 5 1,100,000,000 2,093 800,277,060 782,065 2 Westlake - Geismar 1 33,000 76,000 44,250 476,390,000 906 49 573,201,200 407,528

*Estimate from Survey Submission **358**DSCF/Lb of Dry Resin Produced

1No Capacity Info - Based on Non-CBI Survey Response 2Survey Response > Capacity Info - Based on Non-CBI Survey Response Average of Avg Dry Flow Rate per Lb Production Sum of Dryer Flow Rates (DSCFM) Number of Dryers* Company Note 2006 Production Capacity (lbs) Dryer Flow Rate Based on Capacity &

Avg Flow Per Production (DSCFM) Annual Production (Lbs)Annual Production (lbs/min) Avg Dryer Flow Rate per

Production (DSCF/LB)**Emission Point Flow Rate Data**

CompanyName FacilityName ProcessUnitIDEmissionPointIDControl Equip Desc Process Equip Desc MinOfMinOfFlowRateMin_Dscfm

MaxOfMaxOfFlowRateMax_Dscfm AvgOfAvgOfFlowRateAvg_Dscfm Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-10 Scrubber Resin Dryer 0 28310 24715 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-11 Scrubber Resin Dryer 0 55500 48720 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-13 Scrubber Resin Dryer 48350 48350 48350 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-6 Scrubber Resin Dryer 0 45909 36721 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-7 Scrubber Resin Dryer 0 45909 33672 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-8 Scrubber Resin Dryer 0 45909 28174 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 EP-9 Scrubber Resin Dryer 0 53609 19874 **Baton Rouge Sum 48350**  **323496 240226**  OxyVinyls, LP OxyVinyls Pasadena P-3 EP-319 Fabric Filter Resin Dryer 43278 OxyVinyls, LP OxyVinyls Pasadena P-4 EP-419 Fabric Filter Resin Dryer 43278 OxyVinyls, LP OxyVinyls Pasadena P-5 EP-519 Fabric Filter Resin Dryer 43278 OxyVinyls, LP OxyVinyls Pasadena P-6 EP-619 Fabric Filter Resin Dryer 43278 OxyVinyls, LP OxyVinyls Pasadena P-7 EP-719 Fabric Filter Resin Dryer 43278 OxyVinyls, LP OxyVinyls Pasadena P-8 EP-819 Fabric Filter Resin Dryer 43278 OxyVinyls, LP OxyVinyls Pasadena P-9 EP-919 Fabric Filter Resin Dryer 65800 **Pasadena Sum 0**  **0 325468**  OxyVinyls, LP OxyVinyls Pedricktown P-1 EP-102 Scrubber Resin Dryer 0 33455 2200 OxyVinyls, LP OxyVinyls Pedricktown P-2 EP-201 Scrubber Resin Dryer 0 25800 OxyVinyls, LP OxyVinyls Pedricktown P-2 EP-202 Scrubber Resin Dryer 0 21800 **Pedricktown Sum 0**  **81055 2200**  PolyOne Corporation PolyOne Henry P-2 EP-2 Fabric Filter Resin Dryer 4500 102900 44650 PolyOne Corporation PolyOne Henry P-3 EP-2 Fabric Filter Resin Dryer 6786 6786 PolyOne Corporation PolyOne Henry P-4 EP-2 Fabric Filter Resin Dryer 7800 7800 PolyOne Corporation PolyOne Henry P-4 EP-3 Fabric Filter Resin Dryer 8500 8500 PolyOne Corporation PolyOne Henry P-5 EP-2 Fabric Filter Resin Dryer 28840 28840 **Henry Sum 4500**  **154826 96576**  Westlake Chemical Corporation Westlake Geismar P-1 EP-4 Resin Dryer 33000 76000 44250 **Geismar Sum** 33000 76000 44250

# Non-CBI Production Information

2008 Production From Survey

CompanyName CertainTeed Corporation Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP PolyOne Corporation PolyOne Corporation The Dow Chemical Company Union Carbide Corporation Westlake Chemical Corporation Westlake Chemical Corporation

2006 Capacity

Information

**CompanyName** 

# CertainTeed Corporation Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Georgia Gulf Corporation Georgia Gulf Corporation Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP PolyOne Corporation PolyOne Corporation Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office The Dow Chemical Company Union Carbide Corporation Westlake Chemical Corporation Westlake Chemical Corporation

# FacilityName

Lake Charles Polymer Plant Formosa Plastics Corporation Baton Rouge Formosa Plastics Corporation Deleware City Formosa Plastics Corporation Point Comfort - PVC Unit Formosa Plastics Corporation, Point Comfort - Specialty Poly vinyl Chloride (SPVC) Unit Oxy Vinyls Deer Park Oxy Vinyls Pasadena Oxy Vinyls Pedricktown PolyOne Henry PolyOne Pedricktown Dow Midland - SARAN Resins Union Carbide Texas City Westlake Calvert City Westlake Geismar

**FacilityName** 

# Lake Charles Formosa Baton Rouge Formosa Deleware City Formosa Point Comfort Formosa (SPVC) Unit Georgia Gulf Aberdeen Georgia Gulf Plaquemine Oxy Vinyls Deer Park Oxy Vinyls Pasadena Oxy Vinyls Pedricktown PolyOne Henry PolyOne Pedricktown Shintech Addis Shintech Freeport Shintech Plaquemine Dow Midland Union Carbide Texas City Westlake Calvert City Westlake Geismar

# SumOfProduction_LbsOfResin 447348640

76007291.85 39809584 21600000 41990283 1100000000 476390000

**US Tons (x1000)** 

# Lbs

240.30358 480,607,160 458.56096 917,121,920 71.65015 143,300,300 782.64011,565,280,200

500.448741,000,897,480 599.656641,199,313,280 275.5775 551,155,000 1050.501432,101,002,860 175.26729 350,534,580 62.83167 125,663,340 65.03629 130,072,580 311.95373 623,907,460 1598.34953,196,699,000 650.36291,300,725,800

70.54784 141,095,680 400.13853 800,277,060 286.6006 573,201,200

# 1999 **2008 2010** 

CE Index 392.1 619.3 539.1 Equipment 436.8 761 641.1 Heat exchangers and tanks 371.5 784.2 587.3 Process machinery 437.5 680.7 610.3 pipe, valves & fittings 540.9 881.5 796.1

Process instruments 364.3 457.8 420.5 pumps and compressors 657.8 872.9 903.4 electrical equipment 336.1 468.1 468.4 structural supports & misc. 415.6 843.9 660 Construction Labor 295 325.3 330.2 Buildings 382.9 529.8 500.5 Engineering and Supervision 339.5 352.3 342.4

Aug. 99' FinalAug . 08 FinalFeb. '10 Final **CE Index**

# Data For Pollutant Concentrations

**Company Facility**  **Emission Point Compound**  **Run1 (ppbv) Run 2 (ppbv)**  

# Oxy VinylsPedricktown

DR-1H Rotary

Dryer 2-Propanone 849 1820 Oxy VinylsPedricktown

DR-1H Rotary

Dryer Vinyl Chloride 126 137 Oxy VinylsPedricktown

DR-1H Rotary

Dryer Toluene 207 264 Oxy VinylsPedricktown

DR-1H Rotary

Dryer 2-propanol 161 254 Oxy VinylsPedricktown

DR-1H Rotary

Dryer Ethanol 106 140 Oxy VinylsPedricktown

DR-1H Rotary

Dryer Carbon Disulfide 108 173 Oxy VinylsPedricktown

DR-1H Rotary

Dryer Methylene Chlordie(Dichloromethane) 54 79 Oxy VinylsPedricktown

DR-1V Second Stage Venturi Vinyl Chloride 449 456 Oxy VinylsPedricktown

DR-1V Second Stage Venturi 2-Propanone 27 28 Oxy VinylsPedricktown

DR-1V Second Stage Venturi Chloroethane 12.5 12.2 Oxy VinylsPedricktown

DR-2v First Stage Venturi Vinyl Chloride 3 Oxy VinylsPedricktown

DR-2v First Stage Venturi Ethanol Oxy VinylsPedricktown

DR-2v First Stage Venturi chloroethane Oxy VinylsPedricktown

DR-2v First Stage Venturi 2-propanone 4.4 Oxy VinylsPedricktown

DR-2v First Stage Venturi Toluene

Data CompanyFacility Compound Min of Avg of Runs Max of Avg of Runs

Average of Avg of Runs Oxy VinylsPedricktown

2-propanol 170 170 170 2-Propanone 8.2 890.3333333 308.0666667 Carbon Disulfide 95.66666667 95.66666667 95.66666667 Chloroethane 12.53333333 13.2 12.86666667 Ethanol 28 98 63 Methylene Chlordie(Dichloromethane) 46 46 46 Toluene 3.5 235.5 119.5 Vinyl Chloride 48.4 439 265.9111111

Compound HC (Kj/mol) Btu/SCF* LFL (%) 2-propanol 1834 2014.887623 2.2 2-Propanone 1659 1822.627353 2.6 Carbon Disulfide 1076.9 1183.114766 1.3 Chloroethane 1284.9 1411.629829 3.8 Ethanol 1235 1356.808186 3.3 Methylene Chlordie(Dichloromethane) 513.88 564.5640411 14 Toluene 3734 4102.284832 1.2 Vinyl Chloride 1178 1294.18627 3.6 * SCF = 1 atm 25C Perry's Perry's

# Run 3 (ppbv) **Avg of Runs Percent**  **Percent Add Use Data?**  

# 2 890.3 45.9% 45.9%x 668 310.3 16.0% 61.9%x

235.5 12.1% 74.0%x 95 170.0 8.8% 82.8%x 48 98.0 5.1% 87.8%x 6 95.7 4.9% 92.8%x 5 46.0 2.4% 95.1%x 412 439.0 87.0% 87.0%x 22 25.7 5.1% 92.1%x 12.9 12.5 2.5% 94.6%x 93.8 48.4 44.2% 44.2%x 28 28.0 25.6% 69.8%x 13.2 13.2 12.1% 81.9%x 12 8.2 7.5% 89.4%x 3.5 3.5 3.2% 92.6%x

Min of Flow (DSCFM)Max of Flow (DSCFM) Avg of Flow (DSCFM) Avg Temp 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6

Auto Ignition Temps (Cel)

Auto Ignition (Far) 399 750.2 465 869 90 194 518.85 965.93 356 672.8 615 1139 535.85 996.53 471.85 881.33 Perry's

# Run 1 Date **Run 2 Date Run 3 Date**  **Run 1 Flow (DSCFM) Run 2 Flow (DSCFM)** 

**Run 3 Flow (DSCFM)**

**Avg Flow (DSCFM)**

**Run 1 Temp (F) Run 2 Temp (F)**  

# 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/8/2007 8/8/2007 8/8/2007 18,122 18,021 17,922 18,022 117 116 8/8/2007 8/8/2007 8/8/2007 18,122 18,021 17,922 18,022 117 116 8/8/2007 8/8/2007 8/8/2007 18,122 18,021 17,922 18,022 117 116 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131

Average Moisture 8.902222% Average Temperature 130.6

# Run 3 Temp (F) **Avg Temp Run 1 Moisture (%)**  **Run 2 Moisture (%)**

**Run 3 Moisture (%)**

**Run 1 CO2 % Run 2 CO2 %**  **Run 3 CO2 % Run 1 O2 %**  

# 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137139.3333 11.5 12.4 11 0.6 0.61 0.47 20 114115.6667 5.4 5.1 5.1 0.4 0.54 0.6 20.3 114115.6667 5.4 5.1 5.1 0.4 0.54 0.6 20.3 114115.6667 5.4 5.1 5.1 0.4 0.54 0.6 20.3 130127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4

# Run 2 O2% **Run 3 O2% Run 1 PM (gr/dscf)**  **Run 2 PM (gr/dscf)**

**Run 3 PM (gr/dscf)** 

# 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20.3 20.2 0.0034 0.0036 0.0039 20.3 20.2 0.0034 0.0036 0.0039 20.3 20.2 0.0034 0.0036 0.0039 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015