~ =~ 

~., 

~ 

I 

11-1-027 

ACID GAS EMISSIONS (HF, HC1, S0 2)~ T.LSTING 

ON THE WOOD MOLD AND ICILN #3 EXHA UST 

BORAL BRICK 

7472 VAN WYCK ROAD 

VAN WYCK, SOUTH CAROLINA 29744 

(803) 286-5566 

MAY 14 & 15,1997 

REPORT # 5887 

ANALYTICAL TESTING CONSULTANTS, INC. 

301 Brookdale Street P. O. Box 886 

Kannapolis, N. C. 28083 Roswell, Georgia 30077 

(704) 932-3193 (770) 587-5696 

Distribution: 

Mr. Robert Maner 

(Five copies) 

Issue Date: _ 

June 19, 1997 

i 

_J ~ 
„i 

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TABLE OF CONTENTS 

. Page 

Number 

INTRODUCTION ............................................. 

CERTIFICATION OF RESULTS . . . . . . . . . . . . . . . . . . . . . . . . 1 

PROCESS DESCRIPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 

PROCESS FLOW DIAGRAMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 

RESULTS SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 

RESULTS, CONCLUSIONS AND COMMENTS . . . . . . . . . . . . . . . . . 8 

SA1ViPLING AND ANALYTICAL PROCEDURES . . . . . . . . . . . . . . . 9 

Sampling Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 

Analytical Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 

REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 

DATA AND CALCULATIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 

FI.OWRATE AND MOISTURE DETERMINATIONS . . . . . . . . 12 

WOODMOLD STACK . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 

KILN #3 .......................................13 

ISOKINETIC DATA AND CALCULATIONS . . . . . . . . . . . . . . . . 

RUN #1 ....................................... 14 

RUN #2 ....................................... 15 

RUN #3 .......................................16 

RUN #4 ....................................... 17 

RUN #5 ........:.............................. 18 

RUN #6 ....................................... 19 

METHOD 26 EMISSION RATE CALCULATIONS . . . . . . . . . . 20 

S02 EMISSION RATE CALCULATION . . . . . . . . . . . . . . . . . . 22 

STANDARD VOLUME CALCULATIONS . . . . . . . . . . 24 

NOMENCLATURE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 

CALCULATION FORMULAE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 

DATA S HEETS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 

ii 

i 
INTRODUCTION 

This report presents the results of hydrogen flouride, hydrogen chloride, and sulfur dioxide 

emissions testing from the exhausts of the Woodmold and #3 kiln at Boral Brick's facility in Van 

Wyck, South Carolina. Testing was conducted on Wednesday, May 14 and Thursday, May 15, 

1997. 

The test was conducted by ANALYTICAL TESTING CONSULTANTS, INC. of Kannapolis, N. 

C. and Atlanta, Georgia. Members of the test team were Richard ~Westbrook and Shane Roberts. 

!;<tl Mr. Thomas Lathom of SCDHEC witnessed sampling on behalf of the State of South Carolina. 

b~ 

CERTIFICATION OF RESULTS 

"By our sigizature we certify that the testing and the reportitig of the test results contained herein are 

prepared to the best of our abilities and that, to our knowledge, the data have been calculated and reported 

correctly. No data or information has knowingly been omitted. " 

W. Keith Poole Richard N. Westbrook 

Test Report Preparation Test Team Leader 

1 

•_J • J 
0 

~ 

PROCESS DESCRIPTION 

~ . 

Wood Mold Process- Plant `B" 

~ 

Clay is delivered to the plant by truck from off site mines and deposited into an apron feeder that 

feeds a primary crusher (EQ02), then a grinder. It is belt conveyed to one of four shaker screens 

that operate in parallel. Course material is conveyed back to the grinder for re-processing. Belt 

conveyors then load fine clay into one of five covered storage bins. 

As needed, clay is conveyed from' the fine clay storage bins to a lower, then upper pug mill, 

where fine clay is combined with water. A column is extruded from the brick machine and is cut 

into bricks. These "green" bricks are subsequently stacked on drying racks and placed in the rack 

dryer. Initial drying occurs in the tunnel dryer, which is supplied with waste heat from the 

cooling section of the kiln. From the tunnel dryer, bricks are re-stacked on kiln cars. The cars 

~ are moved to a pre-heater where the temperature of the brick is raised before entering the kiln. In 

the natural gas heated kiln, final evaporation of free water, dehydration, oxidation, vitrification, 

flashing, and cooling occurs. Of the tunnel dryer, pre-heater, and kiln, only the kiln has a heat 

source. The tunnel dryer and pre-heater are supplied with waste heat from the kiln. After exiting 

.! the kiln, bricks are packaged and stored on site for sale. 

"-' Kiln 0-Plant "C" 

J 

Crude clay is transferred by front end loader to feed hoppers on the Plant "C" line. It is then 

conveyed to crushers. A twin feeder sends clay to dual grinders (an "A" and "C" line) and the 

~ ground material is screened. Both sides of the line have three screeners. Again, course marterial 

that will not pass through the sizing screens is re-conveyed to the grinders. Side "A" and "C" 

i fine materials are then combined at conveyor belt #10 and transfen ed to one of three covered fine 

' clay storage silos. 

F#,;S As load demands require, fine clay is conveyed to a pug mill where is mixed with water. 

~ "Green" bricks are then cut and loaded at the setting machine and sent to the holding room (five 

~ tracks). Bricks are then sent to one of two tunnel dryers and the Harrop Kiln. After drying, bricks 

1 are packaged and stacked on the brickyard for shipment. 

J 

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RESULTS SUMMARY 

~ CLIENT: BORAL BRICK 

LOCATION: VAN WYCK, SOUTH CAROLINA 

~ DATE: MAY 14, 1997 

SOURCE: WOOD MOLD EXHAUST 

~ 

PARAIVIETER RUN #1 RUN #2 RUN #3 AVG. 

~ QS, ACFM 14,867 17,168 17,284 16,440 

Q STD DRY, SCFM 9,183 10,311 10,464 9,986 

%M, MOISTURE 7.41 9.33 8.72 

~~. PRODUCTION RATE, TPH - 8.05 

(Product-Ballantyne Modular Size Woodmold Brick)' 

} 

:, 

HYDROGEN FLOURIDE EMISSIONS 

CONCENTRATION,MG/DSCM 41.47 105.56 106.31 84.45 

HF, LBS/HR 1.43 4.08 4.17 3.23 

Li LBS HF/TON 0.177 0.507 0.518 0.401 

'° 

' 

HYDROGEN CHLORIDE ENIISSIONS 

CONCENTRATION,MG/DSCM 5.17 9.46 10.90 8.51 

HCI, LBS/HR 0.18 0.37 0.43 0.327 

LBS HCUTON 0.022 0.045 0.053 0.040 

SULFUR DIOXIDE EMISSIONS 

~ 

CONCENT RATION,MG/DSCM 

A 0.00 0.0112 0.0301 0.0138 

B 0.0248 0.0230 0.1285 0.0588 

~ S02 , LBS/HR 

A 0.00 0.539 1.468 1.003 

B 1.062 1.106 6.299 2.822 

LBS SOZ/TON 

A 0.00 0.067 0.182 0.083 

B 0.132 0.137 0.783 0.351 

l Additional Kiln'parameters are provided in the DATA SHEETS 

section of this report. 

, . 

6 

i 

I 
~ 

~ 

RESULTS SUMMARY 

CLIENT: BORAL BRICK 

LOCATION: VAN WYCK, SOUTH CAROLINA 

DATE: MAY 15, 1997 

SOURCE: #3 KILN EXHAUST 

PARAMETER RUN #4 RUN #5 

QS, ACFM 28,965 

, 

30,440 

Q STD DRY, SCFM 15,193 15,525 

%M, MOISTURE 9.26 10.67 

PRODUCTION RATE, TPH - 

(Product-Extruded Modular Size Craggy Mountain) Z 

HYDROGEN FLOURIDE EMISSIONS 

CONCENTRATION,MG/DSCM 93.77 101.29 

HF, LBS/HR 5.34 5.89 

LB S HFlTON 0.544 0.600 

HYDROGEN CHLORIDE ENIISSIONS 

CONCENTRATION,MG/DSCM 7.42 8.27 

HCI, LBS/HR 0.42 0.48 

LBS HCIJTON 0.043 0.049 

SULFUR DIOXIDE ENIISSIONS 

CONCENTRATION,MG/DSCM 

A 0.0012 0.00 

B 0.00 0.0212 

SOZ , LBS/HR 

A 0.092 0.000 

B 0.000 1.538 

LB S S O2/TON 

A 0.009 0.000 

B 0.000 0.157 

RUN #6 AVG. 

27,879 29,095 

14,354 15,024 

10.49 

9.81 

102.42 99.16 

5.51 5.58 

0.561 0.568 

8.10 7.93 

0.44 0.45 

0.044 0.045 _ 

0.0101 0.0038 

0.0150 0.0121 

0.678 0.257 

1.010 0.849 

0.069 0.026 

0.103 0.087 

_ Z Additional Kiln'parameters are provided in the DATA SHEETS 

section of this report. 

7 

I 
i~ ~ 

,- 

~ i2ESULTS, CONCLUSIONS AND COMMENTS 

i 

A summary of some pertinent results appear in the preceding RESULTS SUMMARY. For 

additional information please consult the CALCULATIONS and DATA SHEETS sections of 

this report. 

Calculation of emission rates utilized the average standard volumetric flowrate (Q std dry, scfm), 

the total mass of each pollutant in question, the standard sample volume for the corresponding 

run, and conversion factors from mg/m3to pounds per hour. ~ This equation is found on the 

emission concentration calculation page of the report. 

~ 

Woodinold Stack Exhaust 

The mean velocity was determined to be 25.94 feet per second (ft/s) through the square 39" x 39" 

_ (A=10.56 ftZ) exhaust stack. This yielded a mean actual volumetric flowrate of 16,440 cubic feet 

per minute (ACFM). The standard flowrate was calculated by applying corrections for: 1) 

barometric pressure- 29.25" Hg, 2) static pressure of the stack- -0.10" H 2O, 3) moisture content 

of each individual run- AVG.=8.49%, and 4) the corresponding stack temperature- AVG.=319.6° 

Fahrenheit. The corresponding mean standard volumetric flowrate was 9,986 SCFM: 

~ Hydrogen Flouride emissions averaged 3.23 pounds per hour or 0.401 lbs/ton. Samples were 

L-j also analyzed for Hydrogen Chloride and averaged 0.327 lbs/hr and 0.040 lbs/ton. 

~ Separate sampling trains were operated for determinations of sulfur dioxide emisisons (USEPA 

~ method 6). Duplicate runs were performed. Emission concentrations averaged 0.0363 from the 

six runs. This yielded an emission rate of 1.913 lbs/hr and 0.217 lbs/ton: 

Kiln #3 Stack Exhaust 

The mean velocity was determined to be 48.36 feet per second (ft/s) through the square 38" x 38" 

=' (A=10.03 ft2) exhaust stack. This yielded a mean actual volumetric flowrate of 29,095 cubic feet 

~ per minute (ACFM). The standard flowrate was calculated by applying corrections for: 1) 

j barometric pressure- 29.10" Hg, 2) static pressure of the stack- -0.35" H ZO, 3) moisture content 

of each individual run- AVG.=10.14%, and 4) the corresponding stack temperatureAVG.=436.3° Fahrenheit. The corresponding mean standard volumetric flowrate was 15,024 

SCFM. 

Hydrogen Flouride emissions averaged 5.58 pounds per hour or 0.568 lbs/ton. Hydrogen 

Chloride emissions averaged 0.45 lbs/hr and 0.0451bs/ton. 

Sulfur dioxide emission concentrations, as measured by USEPA 6, averaged 0.0080 from the six 

runs. This yielded an emission rate of 0.553 lbs/hr and 0.057 lbs/ton. 

n: 

11 
m 

SAMPLING AND ANALYTICAL PROCEDURES 

~ Sampling and analysis were performed according to procedures developed by the U. S. 

Environmental Protection Agency (USEPA) and referred to as Methods 1, 2, 3, and 4. 

~ Additional sampling methodology included USEPA method 26 for halide compounds, 

specifically Hydrogen Flouride and Hydrogen Chloride. 

Sampling Procedures 

Prior to each sampling run, method 2 was utilized to develop velocity and temperature profiles 

across the square ducts. The method 26 sampling train was assembled and heated to operating 

conditions prior to leak-checks being conducted (ice was placed in the impinger case to maintain 

fW~ the temperature at < 68° F). Leak-checks, as recorded on the sampling data sheets, reflect 

leakage rates in liters per ininute. The sampling train consisted of a borosilicate glass probe liner 

attached to a heated filter assembly containing a non-tared 25mm Teflon® filter. The heated 

—J three way stopcock followed the filter. Immediately after the filter, the stack gas passes through 

three midget impingers containing 15 milliliters (ml) each of 0.1N H 2SO4 . This was followed in 

sequence by two midget impingers containing 15 mfof 0.1N NaOH. A sixth impinger contained 

an appropriate quantity of silica gel. After a successful completion of the leak-check, the heated 

- ~ three way stopcock was opened and the sampling probe and filter assembly was purged for five 

J minutes at a flowrate of 2.0 liters per minute. Three repetions were completed in this manner. 

-~ The first and second impingers of each sampling train were recovered and combined. The third 

,J impinger was recovered separately and utilized for breakthrough determinations. The contents of 

the fourth and fifth impingers were not needed and were archived after recovery. The teflon filter 

"- ~ was placed into the first container with the contents of the first and second impinger. An 

~+ appropriate chain of custody was completed and forwarded to the laboratory. 

Analytical Procedures 

As requested by the South Carolina Department of Health and Environmental Control 

(SCDHEC), the first/second and the third impinger of a single run (first run) were analyzed 

separately to determine breakthrough on one run per source. The remaining third impinger 

— sample containers were archived until results of the analyses were received. No breakthrough 

~ was measured in either of these. The target QA/QC guideline was to detect less than 10% in the 

~ third impinger. 

Resolution Analytics, Inc. performed the analyses. Results of the in-house audit sample 

exhibited a 0.78% difference on replicate injections. The matrix spike (spiked with 0.5 ml of a 

50 ppm flouride standard) was 94.6% recovered. Field spike recovery rates were 94.0% and 

97.1%, respectively. 

~~ 

~~ 
„ t 

t:h 

~ 

~ 

. ,., 

REFERENCES 

l. CODE OF FEDERAL REGULATIONS, Title 40, Part 60, Appendix A, July 1, 1995. 

M 

~ 

.>.~ 

10 

I -Z/ 
DATA AND CALCULATIONS 

Flow Calculations 

Traverse Data 

Emission Rate Calculations 

Hydrogen Flouride Calculations 

Hydrogen Chloride Calculations 

Sulfur Dioxide Calculations 

Nomenclature 

Calculation Formulae 

i 

J 

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11 

13 
LOCATION: BORAL BR/CK 

SOURCE: WOODMOLD STACK 

DATA RUN #1 RUN #2 RUN #3 A 

DATE 05/14/97 05/14/97 05/14/97 

RUN T/ME (min) 60.00 60.00 60.00 

AVG DH (in H20) 1.25 1.25 1.25 

P ATM (in Hg) 29.25 29.25 29.26 

Pm (in Hg) 29.34 29.34 29.34 

Ps (GAUGE) -0.10 -0.10 -0.10 

Ps (IN HG) 29.24 29.24 29.24 

Tm (F) 73.58 82.33 84.25 

Tm (R) 533.58 542.33 544.25 

Vm (tt3) 38.31 38.56 38.66 

Vm STD (ft3) 37.18 36.82 36.78 

VLO (ml) 63.10 80.40 74.60 

VV STD (0) 2.97 3.79 3.51 

V STD (ff3) 40.15 40.60 40.30 

%M 7.41 9.33 8.72 

MD 0.93 0.91 0.91 

MWD 29.38 29.24 29.32 

M 28.54 28.19 28.33 

Ts (F) 316.20 321.76 320.68 

Ts (R) 776.20 781.76 780.68 

SUM SORT DP 8.47 9.69 9.78 

N DP 25.00 25.00 25.00 

AVG SORT DP 0.34 0.39 0.39 

CP 0.84 0.84 0.84 

Vs (ft/s) 23.46 27.09 27.27 

Ds (in) 

As (ft2) 10.56 10.56 10.56 

OS, FLOW, ACFM 14867 17168 17284 

O STD (fi3/min) 9918 11371 11464 

Q STD DRY, FLOW SCFM 9183 10311 10464 

% CO2 4.50 3.50 4.00 

%02 16.50 17.00 17.00 

% CO 0.00 0.00 0.00 

%N2 79.00 79_50 79.00 

® 

~ 1 

~ 

8.49 

319.55 

779.55 

~ 

25.94 

16440 

10918 

9986 

4.00 

16.83 

FLOWRATE AND MOISTURE DETERMINATION 

I 

12 

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a~ 

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FLOWRATE AND MOISTURE DETERMINATION 

LOCATION: BORAL BR/CK 

SOURCE: K1LN #3 

DATA RUN #4 RUN #5 RUN #6 AVERAGE 

DATE 05/15/97 05/15/97 05/15/97 

RUN T1ME (min) 60.00 60.00 60.00 

AVG DH (Pn H20) 1.25 1.25 1.25 

P ATM (in Hg) 29.10 29.10 29.10 

Pm (in Hg) 29.19 29.19 29.19 

Ps (GAUGE) -0.35 -0.35 -0.35 

Ps (IN HG) 29.07 29.07 29.07 

Tm (F) 77.75 87.33 88.92 

Tm (R) 537.75 547.33 548.92 

Vm (ft3) 38.21 38.27 39.71 

Vm STD (ft3) 36.60 36.02 37.27 

VLO (ml) 79.30 91.30 92.70 

VV STD (ft3) 3.74 4.30 4.37 

V STD (ft3) 40.34 40.32 41.64 

%M 9.26 10.67 10.49 10.14 

MD 0.91 0.89 0.90 

MWD 29.32 29.32 29.32 

M 28.27 28.11 28.13 

Ts (F) 431.16 442.28 435.56 436.33 

Ts (R) 891.16 902.28 895.56 896.33 

SUM SORT DP 16.10 16.77 15.42 

N DP 25.00 25.00 25.00 

AVG SORT DP 0.64 0.67 0.62 

CP 0.84 0.84 0.84 

Vs (ft/s) 48.14 50.59 46.34 48.36 

Ds (in) 

As (ft2) 10.03 10.03 10.03 

OS, FLOW, ACFM 28965 30440 27879 29095 

Q STD (ft3/min) 16744 17379 16037 16720 

Q STD DRY, FLOW SCFM 15193 15525 14354 15024 

%CO2 4.00 4.00 4.00 4.00 

% 02 17.00 17.00 17.00 17.00 

% CO 0.00 0.00 0.00 

13 

... i 
RUN #1 

POINT # 

A1 

A2 

A3 

A4 

A5 

B1 

B2 

B3 

B4 

B5 

C1 

C2 

C3 

C4 

C5 

D1 

D2 

D3 

D4 

D5 

E1 

E2 

E3 

E4 

E5 

t~ 

»~ 

4; 

r; 

dH SQRT DP % 02 % CO2 

1.25 0.316 16.5 4.5 

, 

0.316 

0.265 

0.200 

0.173 

0.548 

0.548 

0.346 

0.283 

0.265 

0.592 _ 

0.500 

0.300 

0.200 

0.224 

0.574 

0.529 

0.200 

0.173 

0.224 

0.520 

0.424 

0.332 

0.245 

0.173 

1.25 8.469 16.50 

% N2 (BY D/FFERENCE) 79. 

ISOKINETIC DATA AND CALCULATIONS 

DATE 05/14/97 - 

SOURCE WOOD MOLD STACK 

Tm Ts dp 

70 293 0.10 

70 300 0.10 

70 304 0.07 

71 305 0.04 

73 305 0.03 

73 305 0.30 

75 310 0.30 

75 315 0.12 

75 317 0.08 

76 317 0.07 

77 325 0.35 

78 326 0.25 

326 0.09 

325 0.04 

324 0.05 

321 0.33 

323 0.28 

325 0.04 

324 0.03 

323 0.05 

318 0.27 

319 0.18 

318 0.11 

319 0.06 

318 0.03 

73.58 316.20 

Vm(ft3) Initial 676.80 

Final 715.11 

Total 38.31 

14 

jb 
~ 

0 

B 

~ 

~ 

ISOKINETIC DATA AND CALCULATIONS 

DATE 05/14/97 - 

SOURCE WOOD MOLD STACK 

RUN #2 

POINT # Tm Ts dp dH SQRT DP % 02 % CO2 

A 1 79 301 0.32 1.25 0.566 17 3.5 

A2 80 307 0.30 0.548 

A3 81 313 0.25 0.500 

A4 80 312 0.11 0.332 

A5 81 309 0.05 0.224 

B 1 83 314 0.29 0.539 

B2 85 320 0.24 0.490 

B3 83 322 0.14 0.374 

B4 83 322 0.07 0.265 

B5 85 322 0.05 0.224 

C1 84 324 0.33 0.574 _ 

C2 84 327 0.22 0.469 

C3 328 0.08 0.283 

C4 328 0.04 0.200 

C5 327 0.03 0.173 

D 1 320 0.32 0.566 

D2 323 0.24 0.490 

D3 327 0.10 0.316 

D4 330 0.05 0.224 

D5 329 0.05 0.224 

E1 321 0.27 0.520 

E2 327 0.30 0.548 

E3 330 0.18 0.424 

E4 330 0.10 0.316 

E5 331 0.09 0.300 

82.33 321.76 1.25 9.686 17.00 3.50 

Vm(tt3) Initial 715.40 % N2 (BY D/FFERENCE) 79.50 

Final 753.96 

Total 38.56 

15 

l~ 
ISOKINETIC DATA AND CALCULATIONS 

DATE 05/14/97 . 

SOURCE _ WOOD MOLD STACK 

RUN #3 

PO/NT # Tm Ts dp dH SORT DP % 02 % CO2 

A 1 83 307 0.31 1.25 0.557 17 4 

A2 83 313 0.28 ' 0.529 

A3 83 314 0.24 0.490 

A4 83 316 0.17 0.412 

A5 84 317 0.08 0.283 

B 1 83 313 0.33 0.574 

B2 83 315 0.28 0.529 

B3 84 322 0_14 0.374 

B4 85 323 0.06 0.245 

B5 87 322 0.06 0.245 

C1 87 314 0.33 0.574 _ 

C2 86 320 0.25 0.500 

C3 323 0.09 0.300 

C4 323 0.03 0.173 

C5 322 0.04 0.200 

D1 320 0.31 0.557 

D2 322 0.23 0.474 

D3 324 0.08 0.283 

D4 325 0.03 0.173 

D5 324 0.03 0.173 

E7 324 0.30 0.548 

E2 325 0.28 0.529 

E3 330 0.17 0.412 

E4 330 0.12 0.346 

E5 329 0.09 0.300 

84.25 320.68 1.25 9.782 17.00 4.00 

Vm(ft3) Initial 754.10 % N2 (BY D/FFERENCE) 79.00 

Final 792.76 

Total 38.66 

16 

:_ 1 ~ 
~ 

0 

~ 

~ 

ISOKINETIC DATA AND CALCULATIONS 

DATE 05/15/97 . 

SOURCE - KILN #3 

RUN #4 

PO/NT # Tm Ts dp dH SQRT DP % 02 % CO2 

A 1 71 388 0.16 1.25 0.400 17 4 

A2 73 417 0.45 ' 0.671 

A3 73 430 0.70 0.837 

A4 75 436 0.78 0.883 

A5 76 439 0.78 0.883 

B 1 78 381 0.09 0.300 

B2 79 430 0.47 0.686 

B3 80 437 0.55 0.742 

B4 81 442 0.61 0.781 

B5 82 445 0.78 0.883 

C1 82 390 0.04 0.200 

C2 83 429 0.48 0.693 

C3 440 0.44 0.663 

C4 444 0.45 0.671 

C5 448 0.63 0.794 

D1 405 0.05 0.224 

D2 443 0.41 0.640 

D3 451 0.46 0.678 

D4 454 0.53 0.728 

D5 455 0.72 0.849 

E1 415 0.11 0.332 

E2 428 0.26 0.510 

E3 435 0.40 0.632 

E4 446 0.45 0.671 

E5 451 0.56 0.748 

77.75 431.16 1.25 16.098 17.00 4.00 

Vm(ft3) Initial 793.10 % N2 (BY D/FFERENCE) 79.00 

Final 831.31 

Tofal 38.21 

17 

:J 15 
ISOKINETIC DATA AND CALCULATIONS 

DATE 05/15/97 . 

SOURCE KILN #3 

RUN #5 

PO/NT # Tm Ts dp dH SORT DP % 02 % CO2 

A 1 85 421 0.25 1.25 0.500 17 4 

A2 85 436 0.27 ' 0.520 

A3 86 447 0.43 0.656 

A4 86 457 0.75 0.866 

A5 86 459 0.82 0.906 

B 1 87 440 0.30 0.548 

B2 88 445 0.49 0.700 

B3 88 454 0.51 0.714 

B4 89 459 0.54 0.735 

B5 89 461 0.65 0.806 

C1 89 435 0.31 0.557 

C2 90 442 0.46 0.678 

C3 449 0.43 0.656 

C4 454 0.45 0.671 

C5 458 0.52 0.721 

D1 410 0.31 0.557 

D2 437 0.42 0.648 

D3 439 0.45 0.671 

D4 441 0.49 0.700 

D5 444 0.64 0.800 

E1 420 0.17 0.412 

E2 430 0.32 0.566 

E3 437 0.38 0.616 

E4 439 0.51 0.714 

E5 443 0.72 0.849 

87.33 442.28 1.25 16.765 17.00 4.00 

Vm(ft3) Initial 831.60 % N2 (BY D/FFERENCE) 79.00 

Final 869.87 

Total 38.27 

18 

~J ~ D 
t~ 

~ 

~ 

. :•I 

~ 

ISOKINETIC DATA AND CALCULATIONS 

DATE 05/15/97 - 

SOURCE KILN #3 

RUN #6 

PO/NT # Tm Ts dp dH SORT DP % 02 % CO2 

A 1 87 420 0.30 1.25 0.548 17 4 

A2 87 421 0.37 ' 0.608 

A3 87 423 0.48 0.693 

A4 87 437 0.65 0.806 

A5 87 439 0.71 0.843 

B 1 88 426 0.38 0.616 

B2 89 438 0.45 0.671 

B3 89 440 0.46 0.678 

B4 90 443 0.49 0.700 

B5 92 445 0.55 0.742 

C1 92 420 0.15 0.387 

C2 92 428 0.38 0.616 

C3 434 0.36 0.600 

C4 443 0.37 0.608 

C5 450 0.48 0.693 

D1 436 0.13 0.361 

D2 442 0.32 0.566 

D3 447 0.38 0.616 

D4 450 0.42 0.648 

D5 450 0.50 0.707 

E1 420 0.14 0.374 

E2 427 0.25 0.500 

E3 435 0.30 0.548 

E4 435 0.33 0.574 

E5 440 0.51 0.714 

88.92 435.56 1.25 15.418 17.00 4.00 

Vm(ft3) Initial 870.10 % N2 (BY D/FFERENCE) 79.0 

Final 909.81 

Tota1 39.71 

19 

_J 

, 

6~ / 
I 

METHOD 26 EMISSION RATE CALCULATIONS 

Hydrogen Flouride Emission Rate 

SECTION A: STANDARD VOLUME CALCULATION 

Vm std = Y X Vm X (Tstdrrm) X (Pbar/Pstd) 

WHERE: 

Vm std = DRY VOLUME AT STANDARD CONDITIONS, DSCM 

Y = METER CALIBRATION FACTOR, VOST#2 0.96 

Vm = METER VOLUME AT METER CONDITIONS, LITERS 

Tstd = STD TEMPERATURE, DEG KELVIN, 293 

Tm = KELVIN TEMPERATURE AT METER 

Pbar = BAROMETRIC PRESSURE, MM HG 

Pstd = STANDARD PRESSURE, MM HG 760 

CLIENT: 'BORALBRICK Y FOR VOST #1 0.928 

SOURCE: 

DATE- 5/14/97 & 5/15/97 

STACK I.D. RUI4 A Vm, litem Tm, F Pbae, In. Hg Vm std M3 

WOOD MOLD 1 60.13 72.6 29.25 0.0559 

WOOD MOLD 2 120.18 81.8 29.25 0.1099 

WOOD MOLD 3 12038 84.2 29.25 0.1101 

KILN #3 4 119.30 75.21 29.10. 0.1062 

KILN #3 5 

61 

121.00 85.81 29.101 0.1056 

KILN #3 119.00 87.81 29.10 0.1035 

SECTION 13: CALCULATION OF EMISSIONS, LBS/HR Production Rates, TPH 

CONCENTRATION Wood Mold 8.05 

C= M /Vrn std Kiln #3 9.81 

WHERE 

C=CONCENTRATION OF HF, MGIDSCM 

M=MASS OF HF, MG 

Vm std= SAMPLE VOLUME, DSCM 

RUN.#,: VM 3w MASS c FLOW.'... =-EMRT EMRT 

STACK I.D. DSCM MG MGIDSCM SCFM LB R LBS/TON 

WOOD MOLD 1 0.0559 2.32 41.47 9183 1.43 0.177 

WOOD MOLD 2 0.1099 11.6 105.56 10311 4.08 0.507 

WOOD MOLD 3 0.1101 11.7 106.31 10464 4.17 0.518 

KILN #3 4 0.10621 9.961 93.771 15193, 5.34 0.544 

KILN #3 5 0.10561 10.71 101.291 155251 5.89 0.600 

.KILN #3 1 6 0.10351 10.61 102.421 143541 5.51 

rzra 

plel 

..I A9- 
0 

~ 

~ 

i 

~ 

;j 

lJ 

~ 

~ 

~ 

h~ 

L.7 

METHOD 26 EMISSION RATE CALCULATIONS 

Hydrogen Chloride Emission Rate 

SECTION A: STANDARD VOLUME CALCULATION 

Vm std = Y X Vm X(Tstd/Tm) X(Pbar/Pstd) 

WHERE: 

Vm std = DRY VOLUME AT STANDARD CONDITIONS, DSCM 

Y= METER CALIBRATION FACTOR, VOST#2 0.96 

Vm = METER VOLUME AT METER CONDITIONS, LITERS 

Tstd = STD TEMPERATURE, DEG KELVIN, 293 

Tm = KELVIN TEMPERATURE AT METER 

Pbar = BAROMETRIC PRESSURE, MM HG 

Pstd = STANDARD PRESSURE, MM HG 760 

CLIENT: ;.:. :.:::;:. . BORAL BRICK _`: . Y FoR Vosr rt 0.928 

SOURCE: 

DATE: ; '- `"' . ': 5/14/97 & 5/15197 

STACK I.D. RUN # Vm, Iiters . Tm, F' .: Pbar, ln. Hg Vm std M3 

WOOD MOLD 1 60.13 72.6 29.25 0.0559 

WOOD MOLD 2 120.18 81.8 29.25 0.1099 

WOOD MOLD 3 120.88 84.2 29.25 0.1101 

KILN #3 4 119.301 75.2 29.10 0.1062 

KILN #3 5 121.001 85.81 29.10 0.1056 

KILN #3 6 119.001 87.81 29.10 0.1035 

Production 

SECTION B: CALCULATION OF EMISSIONS, LBS/HR Rates, TPH 

CONCENTRATION Wood Mold 8.05 

C= M Nm std Kiln #3 9.81 

WHERE 

C=CONCENTRATION OF HCI, MG/DSCM 

M=MASS OF HCI, MG 

Vm std= SAMPLE VOLUME, DSCM 

':•_ . 

RUN #. 

. . . .. : _ 

`- Vm std MASS : C 

. ,. ;.:. 

FLOW 

- .'" 

EMRT EMR 

STACK I.D. DSCM MG ":".. . MG/DSCM SCFM LBS/HR ..LBS/TON 

WOOD MOLD 1 0.0559 0.289 5.17 9183 0.18 0.022 

WOOD MOLD 2 0.1099 1.04 9.46 10311 0.37 0.045 

WOOD MOLD 3 0.1101 1.2 10.90 10464 0.43 0.053 

KILN #3 41 0.10621 0.788 1 7.421 15193 0.42 0.043 

KILN #3 51 0.10561 0.8741 8.271 155251 0.48 0.049 

KILN #3 61 0.10351 0.8381 8.101 143541 0.44 0.044 

21 

~ 

~ 3 
S02 EMISSION RATE CALCULATION-IMPINGER METHOD 

CUENT.. . . :.... :: .. . ,~. . .:.:: BORAL BRICK - 

coC.anOnr. VAN WYCK, SOUTH CAROLINA 

soURCE. . WOOD MOLD AND KILN #3 STACKS 

DATE. 5/14/97 & 5/15/97 

C S02(Ib/Pt3) =((K)(N)(Vt-Vtb)(VsoWa))/Nm std 

C S02(Ib/ft3): CONCENTRATION OF SULFUR DIOXIDE COMPOUNDS, Ib/ft3 

K:7.065E-05 ib/meq 

N: NORMALITY OF TITRANT .00962 0.0096 0.0096 

Vt (avg):AVG. VOLUME OF TITRANT FOR ALIQUOT, 2 trlals Blank 1 Blank 2 Avg. Blank 

Vtb: VOLUME OF TITRANT FOR BLANK 0.03 0.03 0.03 

Vsol: VOLUME OF SOLUTION 0.03 0.03 0.03 

Va: VOLUME OF ALIQUOT TITRATED - 

Vm std:STANDARD GAS SAMPLE VOLUME, L 

STACK RUN #. . V AVG -ml Vtb ml V sol ml . Va rni . Vm std-L C S02-Ib/ft 

OOD MOLD 14 0.03 0.03 100 201 19.20 O.00E+00 

OOD MOLD 1 el 0.44 0.03 100 201 20.42 1.93E-06 

OOD MOLD 24 0.2 0.03 100 20 18.74 8.71 E-07 

OOD MOLD 281 0.37 0.03 100 20 18.26 1.79E-06 

OOD MOLD 34 0.49 0.03 100 20 18.89 2.34E-06 

OOD MOLD 34 2.03 0.03 100 20 19.14 1.00E-05 

ILN #3 44 0.05 0.03 100 20 18.93 1.01 E-07 

ILN #3 4EI 0.03 0.03 100 20 19.80 O.00E+00 

ILN #3 54 0.03 0.03 100 20 18.95 O.00E+00 

ILN #3 5EI 0.37 0.03 100 20 19.77 1.65E-06 

ILN #3 6 0.19 0.03 100 20 19.52 7.87E-07 

ILN #3 6EI 0.271 0.031 100 20 19.65 1.17E-06 

IF 

I 

22 

;_J . ~
d ~ 

~ 

~ 

~ 

EM/SSION RATE CALCULATION 

E S02 =(C S02)(Q std dry)(60) 

WHERE: 

E S02=EMISSION RATE OFSULFUR DIOXIDE, LB/HR 

O std dry=STANDARD EXHAUST FLOW RATE, CFM 

Production Rates, TPH 

Wood Mold 8.05 

Kiln #3 9,81 

STACK RUN # C.S02-Ib/it3.. ..'.. - O std dry, scfm E S02= 

Ibs/hr 

' S02-ppm ` EMRT,Ibs/to 

OOD MOLD 1A O.00E+00 9183 0.000 0.0 0.000 

OOD MOLD 181 1.93E-06 9183 1.062 11.7 0.132 

OOD MOLD 2A 8.71 E-07 10311 0.539 5.3 0.067 

OOD MOLD 281 1.79E-06 10311 1.106 10.8 0.137 

OOD MOLD 3A 2.34E-06 10464 1.468 14.1 0.182 

OOD MOLD 3EI 1.00E-05 10464 6.299 60.6 0.783 

ILN #3 JA 1.01 E-07 15193 0.092 0.6 0.009 

ILN #3 481 0.00E+00 15193 0.000 0.01 0.000 

ILN #3 5A O.00E+00 15525 0.000 0.0 0.000 

ILN #3 5EI 1.65E-06 15525 1.538 10.0 0.157 

ILN #3 6 7.87E-07 14354 0.678 4.81 0.069 

ILN #3 6EI 1.17E-06 1 14354 1 1.010 7.11 0.103 

23 

td 

!~ 

, 

a~ 
~{ ~ 

STANDARD VOLUME CALCULATIONS 

CLIENT: . ` . = BORAL BRICK 

DATE: - 5/14/97 & 5/15/97 

STANDARD VOLUME CALCULATION 

Vm std = Y X Vm X(TstdlTm) X(Pbar/Pstd) 

WHERE: 

Vm std = DRY VOLUME AT STANDARD CONDITIONS, DSCM 

Y= METER CALIBRATION FACTOR, VOST#3 1.00 

Vm = METER VOLUME AT METER CONDITIONS, LITERS 

Tstd = STD TEMPERATURE, DEG KELVIN, 293 

Tm = KELVIN TEMPERATURE AT METER 

Pbar = BAROMETRIC PRESSURE, MM HG 

Pstd = STANDARD PRESSURE, MM HG 760 

STACK RUN # Vm, liters . Tm, F Pbar, In. H. Vm std M 

OOD MOLD 14 20.10 78.3 29.25 19.20 

OOD MOLD 1 El 21.65 85.0 29.25 20.42 

OOD MOLD 24 20.05 90.0 29.25 18.74 

OOD MOLD 2EI 19.50 89.0 - 29.25 18.26 

OOD MOLD 34 20.10 87.0 29.25 18.89 

OOD MOLD 3EI 20.40 87.8 29.25 19.14 

I LN #3 44 19.85 76.3 29.10 18.93 

ILN #3 4EI 20.80 77.3 29.10 19.80 

ILN #3 54 20.20 85.0 29.10 18.95 

ILN #3 5BI 21.10 85.8 29.10 19.77 

ILN #3 .64 20.80 85.0 29.10 19.52 

ILN #3 6 21.101 89.01 29sl0l 19.65 

--, 

I 

k~ 

24 

s 
d 

~ 

e 

NOMENCLATURE 

AN (square inches), Cross sectional area of nozzle 

AS (square feet), Cross sectional area of stack 

CP Pitot tube calibration coefficient 

% EA Percent Excess Air 

F (scfd/10 6 BTU), F factor 

DH (inches of water) Average orifice meter reading 

HI (million BTU/hr), Heat Input Rate 

% I Percent Isokineticity 

M (lb/lb mole), Molecular Weight of wet gas 

% M Percent Moisture 

MD Mole fraction of dry gas 

MWD (Ib/Ib mole) molecular weight of dry gas 

N DP Number of sample points 

P ATM (in Hg), Local atmospheric pressure 

PM (in Hg), Absolute pressure in dry gas meter 

PS (in Hg), Absolute stack pressure 

PS GAUGE (inches of water), Measured static stack pressure gauge 

P STD (29.92 in Hg), Standard pressure 

PMRC (lb/hr), Pollutant mass rate based on concentration 

PMRU (lb/million BTU), Specific emission rate 

25 

p- -) 
~ 

~ 

NOMENCLATURE (CONTINUED) 

~ DP (inches of water), Velocity pressure . 

~ QS (cubic feet/min.), Actual stack volume flow rate 

Q STD (cubic feet/min.), Stack volume flow rate at standard 

conditions 

TM (degrees R), Average dry gas meter temperature' 

. 

. •:i 

c ~ TS (degrees R), Average stack temperature 

; T STD (528 degrees R), Standard temperature 

.. 

VLQ (ml), Liquid volume _ 

--., 

VM (cubic feet), Sample volume measured by dry gas meter 

~ 

J VM STD (cubic feet), Sample volume at standard conditions 

VS (ft/sec), stack velocity 

VV STD (cubic feet), Volume of water vapor collected, 

~ 

conrected to standard conditions 

WT (gm), Total weight of particulate collected 

TIME (MIN.) Duration of test 

26 

d`~~ 
CALCULATION FORMULAE 

1. Absolute pressure in dry gas meter 

PM = P ATM + DH/ 13.6 

2.Absolute Stack Pressure 

PS = P ATM + PS gauge/13.6 

3. Sample volume at standard conditions 

VM STD =(GAMMA FACTOR, 0.983)(VM) (T STD/TM) (PM/P STD) 

4. Volume of water collected, corrected to standard conditions 

VV STD = (.00267) (VLQ) (T STD/P STD) 

5. Total sample volume at standard conditions 

V STD = VM STD + VV STD 

t~ l 

6. Percent moisture in stack gas 

~ %M = (100) (VV STD)/V STD 

7. Mole Fraction of dry gas 

MD = (100-%M)/ 100 

8. Molecular weight of the wet gas 

M = (MWD) (MD) + 18(1-MD) 

9. Stack velocity 

VS = (85.48)(CP)((TS/(PS)(M))"((Sum DP) v N DP)) 

10. Stack volume flow rate 

QS = (60)(VS)(AS) 

27 

a- I~ 
~ 

_; 

J 

CALCULATION FORMULAE (CONTINUED) 

11. Stack volume flow rate, standard conditions including . 

moisture 

Q STD = (T STD/P STD)(PS/TS )(QS) 

12. Stack volume flow rate standard conditions dry 

Q STD DRY = (Q STD)(1-%M) ' 

13. Pollutant mass rate, concentration basis 

PMRC = (.1323)(WT)(Q STD)/V STD 

14. Pollutant mass rate ratio of areas basis 

PMRA = (.1323)(WT)(AS)(144)/(Time)(AN) 

15. Percent Isokineticity 

%I = (100) (PMRA)/PMRC 

16. Average pollutant mass rate 

PMR AVG = (PMRA + PMRC)/2 

17. % Excess Air 

%EA = (100) (%oxygen - (.5)(%carbon monoxide) 

(.264)(%nitrogen) - %oxygen + (.5) (%carbon monoxide) 

18. Heat input rate 

HI = ((.6) (Q STD DRY)/k)((20.9 - %oxygen)/20.9) 

19. Specific emission rate 

PMRU = PMR AVG/HI 

28 

i 
DATA SHEETS 

Woodmold Exhaust Stack 

Traverse Data Sheets 

Method 4 Sampling Data Sheets ' 

Method 26 Sampling Data Sheets 

Method 6 Sampling Data Sheets 

Source Test Survey 

,nd 

i 

~ 

-, 

~ 

Kiln #3 Exhaust Stack 

Traverse Data Sheets _ 

Method 4 Sampling Data Sheets 

Method 26 Sampling Data Sheets 

Method 6 Sampling Data Sheets 

Source Test Survey 

PLANT PROCESS DATA 

Kiln Throughput and Records - 

Method 26 Laboratory Report 

u~ Impinger Data Sheet 

Calibration Information 

~ 

; 

I 

29 

31 

~ 

I 

w ~ 

cm 

, ~ 

l. t. (A-;~ g. ) _ +460= T, (Rankin) 

2. Duct.Area=A= Ft2 

3. P.=Pb, =±SP in. Hg. 

4. Rho,* ( 530/T,) * (P,/29.92 ) = lbs/ft' 

5.K=constant= 1096.5/((G.D.) 1 ")= 

~ 6 . Velocity=K*Fj * (VD avg) 1/2 £t/min. 

7. VOLLTME ( avg )= A* V=' ACFM 

8 . SCFM=Volume* ( 530/T.) * (P./29. 92) _ 

SCFM(wet) 

Rho= specific weight of Air= 0.075 lbs/ft' 

~ != angle in degrees to yield 

_I • 

dP of 0 

SKETCH 

3Z 

~ ANALYTICAL TESTING CONSULTANTS, INC. 

KANNAPOLIS, N.C. ATLANTA, GEORGIA 

8 TRAVERSE DATA AND FLOW COMPUTATION 

CLIENT 46"-.'a/ DATE 

' LOCATION SOURCE 

TEST TEAM Il4/ X/L RUN # l 

.. __.._______________________.._____------ 

K Pbar a9~.~ Dry Bulb ( °F) Wet Bulb ( °F) -+ ` 

Time /D%od .4*#! SP ( "Hg/"WG) -0•10 ~v•c. Pitot Type- .SAtZ 

Pitot # s7 Fs for Pitot 0•8 ~1 Stack I.D. l9 X d.4 

TRAVERSE 

POINT 

Va 

inches 

SQ. ROOT 

Va 

STACK 

TEMP ., °F 

dP 

0°REF . 

ANGLE' 

( 0 dP ) 

&.ID .Z9~ 0. o J f, 

.a D.! o 300 o, a z 3 

3 0,07 3oy p.o/ 

y D•oy I 3oS 6, 0 0 

D• o> I 3o s• o. z 7 

o. 3 0 3ot i 

,? 0.30 I 3~0 •o / G 

3 a•! .2 

y 0.09- 1 317 o• v / I y 

f 0-0 -7 ( 317 4. O/ 

= 1 0. :ct I 3.~ c o• o I I /y 

3 0• o p ~ 3.LL Co 0 

y o•o fe 3~ t o.o t Xo 

f !J•os 3~ y o 0 

0-3 .7 1 ~~/ o•o/ iL 

.? 0.119 1 

3 O.oy 1 ~ r 

y v, o? 1 3~5~ . o/ 7 

~ ot a s 3.~ 3 •o/ y 

F/ 0. .2 7 I 3/8 . 

319 v o 

3 0, ff /p G o 

y o, oG 319 0•0/ ~ 

S~ 
ANALYTICAL TESTING CONSULTANTS, INC. 

KANNAPOLIS, N.C. ATLANTA, GEORGIA 

TRAVERSE DATA AND FLOW COMPUTATION 

CLIENT DATE 7 

LOCATION Pa 44 fS. ~. SOURCE ~a~ ~~ 515•..,E 

TEST TEAM /L RUN #.Z 

------------------------------------------------------------------- 

Pbar Dry Bulb ( °F) Wet Bulb ( °F) • 

Time /: ?-o SP ("Hg/"WG)—O./G f''~ G Pitot TypeS,W''C 

Pitot #Y'7 Fs for Pitot d• d f/ Stack I.D. JQXl ~ 

--------------..---....-----------..-------'~_..---------..---..---....--- 

TRAVERSE 

POINT 

Vn 

inches 

SQ. ROOT 

Vp 

STACK 

TEMP ., °F 

dP .. 

0 °REF. 

ANGLE' 

( 0 dP ) 

/ v.3 ~ o/ 

,? p , 3 0 1 1 ;0 7 

3 d. A s- I 3i 

s- D• v,~ 30 

~ 0 •1 y I 3-~ 0 

3 O•/y 3,Z 

y o•o ~ ; 3.~~ 

r o •o ~ 1 ~-~ ~ 

c/ 

2 3.t7 

3 D•o8 3.~ 8 

y v, a y 

3 0 • ~o I -7 

~i c •of ~ jd 

~ 3 2-1 " / O, •~ 7 I 

? , 30 .~ Z7 

o, /up 33 0 

l. t, (Avg. ) _ +460= T, (RanKin) 

2. Duct Area=A= Ft2 

3. P s =P5e1a'SP iri. Hg. 

4. Rho,* ( 530/T,) * (P,/29.92 ) = lbs/ft' 

S.K=constant= 1096.5/((6.D.) 1/2 )= 

6. Velocity=K*F,* (VD avg)'" ft/min. 

7. VOLUME ( avg )= A* V= . ACFM 

8. SCFM=Volusne* ( 530/T,) * (P,/29 . 92 ) _ 

SCFM(wet) 

Rho= specific weight -of Air= 0.075 lbs/ft' 

!= angle in degrees to yield dP of 0 

SKETCH 

~ 

FORM 15 
~ ANALYTICAL TESTING CONSULTANTS, INC. 

KANNAPOLIS, N.C. ATLANTA, GEORGIA 

11 TRAVERSE DATA AND FLOW COMPUTATION 

CLIENT gorM.l 8ric,F DATE_/p z 

~ LOCATION Viy ~ . t SOURCE GCfpe,.l ~ f fT4rlf 

TEST TEAM w S,e RUN # 

----------------- _ ------------ _ --------------- ____ ~ _____.... 

~ Pbar ~ Q• ~ S Dry Bulb (°F) Wet Bulb (°F) 

Time 3•'/J' 401" SP ("Hg/"WG) •O./0 -"4'-4 Pitot Type S.OEC 

Pitot Fs for Pitot d• B4-* Stack I.D. 391 XII 

~~ _-.._-__ ____..___..____..___..__....________ _.._........_-_...._.........._.......... ~ 

TRAVERSE 

POINT 

Vp 

inches 

SQ . ROOT 

VD 

STACI{ 

TEMP ., °F 

dP ': ., 

0 0REF. 

ANGLE' 

( 0 dP ) 

/ 6•3/ I 1 30;, 

2 a, e I /I 

3 a•A!' 

y 

4 I 31y 

0•17 

d•o8 ( ~ 3/~ 

z v• z8 I I 3 ~~ 

3 o•15f 

y a -o ! 

s- a•o 

i C~ •33 I 3~~ 

2 

3 0.0 

y p, v3 

4" 

I 1 1 

0105, 1 

0.31• 3z o 

,2 0. lz lz . 0.01 My 

y 0.0,3 1 ~ s 

d•vj ~ y 

ct ~ 3 p 3~ y 

y S u r 

o. j7 3 0 

y o•iz 330 

I . t, vg. = +490= T, Ra in 

2. Duct Area=A= Ft2 

3. Ps =Pb. ±SP in. Hg. 

4. Rho,* (530/T,) * (P./29.92) = lbs/ft' 

5.K=constant= 1096.5/((G'.D.) 1/2 )= 

6 . Velocity=K*F,* (VD avg) 1/2 ft/min. 

7.VOLUME(avg)= A*V= ' ACFM 

8.SCFM=Volume* (530/T.) * (P,/29.92)= 

SCFM(wet) 

Rho= specific weight of Air= 0.075 lbs/ft' 

1= angle in degrees to yield dP of 0 

SKETCH 

~Y 

:-_i 

~ 

~ ~ 

J 
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x x 

I . I 

a I I 

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~ H ~ ro m w04 0al 

~ 

` • 

~ ~ \ 

~ 33 

i ct 

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Z ~ H 

aow uaH 

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~ 

:.1 

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u~ ~ 

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9 11 

9 

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~ 

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.~~ 

ror-4 0 

0 . ~ .~ I I z w w 

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~ w , oa .. 

+ h ~ tn 

w 

b 

c 

d ' '[ ~ 

~ 

H ~ ~ 

x 

cn aa

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H 

a INU 

H ~ I 0 ~ I 

ra 

h H ~ U 44:I 

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SOURCE SURVEY, AND DESCRIPTION 

SYSTEM TYPE: BOII.ER 'fPROCESS • OTHER 

NARRATIVE DESCRIPTION: I_i 

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PURPOSE OF TESTING: W._ COMPLIANCE EVALUATION 

PROCESS RATE OR CAPACITY: DETERMINED BY: Pl4K4 'Re c.e"1f 

CONTROL EQUIPMENT: SCRUBBER ESP BAGHOUSE 

OTHER IJoN 6- 

CONTROL EQUIPMENT OPERATING PARAMETERS: PRESSURE DROP 

OTHER N/14 

SAMPLING LOCATION DATA: 

DISTANCE DOWNSTREAM FROM FLOW DISTURBANCE: gt7G " 

NATURE OF DISTURBANCE: BEND, FAN, EXPA.\iSION, BYPASS D C 

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LABORATORY INFORMATION: 

SAMPLE RECOVERY:ATC LABORATORY CLEAN FIELD AREA ~ 

ATC VAN OTHER 

SAMPLE SHIPMENT: ATC VAN OTHERps 

SAMPLE ANALYSIS: ATC OTHER P.sol„ }iorJ A y~lu ~tc.s ~=~Jc.. 

FILTER MATERIAL: GELMAN A/E R' WHATMAN 934AH 

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5. K=constant= 1096. 5/ ((G. D. 

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8. SCFM=Volume* (530/T,) * (P,/29.92) _ 

SCFM(wet) 

Rho= specific weight.`of Air= 0.075 lbs/ft' 

!= angle in degrees to yield dP of 0 

~ 1 

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~ ANALYTICAL TESTING CONSULTANTS, INC. 

KANNAPOLIS, N.C. ATLANTA, GEORGIA 

TRAVERSE DATA ,A.ND FLOW COMPUTATION 

CLIENT ~r...~~r.'c~ _ DATE S /t !7 

LOCATION 11,2a GtJ„t,/_ r C, SOURCE •'/.. •4~ ~ 

TEST TEAM nW, S'ie RUN ## ~ 

--------------- ---------------------------------------------------- 

Pbar;1 /d Dry Bulb ( °F) Wet Bulb ( °F) 

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ANALYTICAL TESTING CONSULTANTS, INC. 

KANNAPOLIS, N.C. ATLANTA, GEORGIA 

TRAVERSE DATA AND FLOW COMPUTATION 

C L I ENT DATE s"~~s'~ 97 ~ r~ 

LOCATION SOURCE .0' l 

TEST TEAM S.0 RUN # S 

------------------------------------------------------------------- 

Pbar .2 9.10 _ _ Dry Bulb ( °F) 'Wet Bulb ( °F) 

Time SP (."Hg/"WG) -O•Jf"b.~'. Pitot Type 37,04-r 

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7.VOLUME(avg)= A*V= ACFM 

8 .SCFM=Volume* (530/T,) * (P,/29.92) _ 

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CLIENT DATE _0"/!~ 

~ LOCATION (~~ .~ ~t/,,~ S. G SOURCE K. a IA4 7 

TEST TEAM r.0 RUN # 

- -------------------------------------------------- ----------------- 

Pbar 1f. eU Dry Bulb ( °F) Wet Bulb ( °F) 

Time /'OO~~ SP ("Hg/ "WG) - O~~vL. Pitot Type S E'T, 

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ANALYTICAL TESTING CONSiJLTANTS 

SOURCE SURVEY AND DESCRIPTION 

SYSTEM TYPE: BOILER ~ PROCESS OTHER 

NARRATIVE DESCRIPTION: X ; /N Z- 3 

PURPOSE OF TESTING: ~COMPLIANCE EVALUATION 

PROCES S RATE OR CAPACITY: t' 10 T' P H DETERMINED B Y:T '4 c o. d; 

CONTROL EQUIPMENT: SCRUBBER ESP BAGHOUSE 

OTHER Af Olv& 

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OTHER 

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i 

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NATURE OF DISTURBANCE: BEND, FAN, EXPANSION, BYPASS, 

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SAMPLE RECOVERY:ATC LABORATORY C.._EAN FIELD AREA ✓ 

ATC VAN OTHER 

S AMPLE S HIPMENT: ATC VAN O'EERU S 

SAMPLE ANALYSIS: ATC O'TlER$aSolv-I-{oo AsIxlwGics. 

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ANALYTICAL 

REPC)RT 

, 

• HCL (EPA METxoD 26A) 

~ 1 • HF (EPA 1VIETxoD 26A) 

~ 

., . 

4:I CLTENT: ANALYTICAL TBSTING CONSULTANTS 

a^c"•~ t""""'.S~" 

~K~,,.. ~ 

...,...~ .FC_ 

RFA#• •. 

ME 
~ 

RESOLUTION ANALYTICS, INC. 

Specialists in High PerPotmance Liquid ChromatograPhY 

REPORT SUMMARY 

RFA#: 771 

SAMTLE ID . I HCl HF 

0.1 N HZSOaBt,ANK < 0.00631 mgs < 0.154 mgs 

1-HCL 1&2 0.289 mgs 2.32 mgs 

1-HCL 3RD nop < a.00947 mgs < 0.232 mgs 

2-HCL 1&2 1.04 mgs 11.6 mgs 

3-HCL 1&2 1.20 mgs 11.7 mgs 

4-HCL 1&2 0.788 mgs 9.96 mgs 

4-HCL 3RD IIvv < 0.00610 mgs < 0.149 mgs 

5-HCL 1&2 0.874 mgs 10.7 mgs 

6-HCL 1&2 0.838 mgs 10.6 mgs 

FIELD SPIKE -1 .4.83 mgs 3.91 mgs 

(94.0% Rec) (92.9% Rec) 

FIELD SPIKE -2 4.99 mgs 3.80 mgs 

' (97.1 % Rec) (90.2% Rec) 

J,'~ 
off 

?-; ; 

ANALYTICAL TESTING CONSULTANTS, INC. 

CHAIN OF CUSTODY RECORD 

• ni 

CLIENT: 

PLANT LOCATION: 

NOTE: 

PLEASE MARK LIQUID LEVEL ON ALL SAMPLE BOTTLES WITH GREASE PENCiL. 

SEAL TIGHTLY AND RE-CHECK UPON DELIVERY TO LAB PERSONNEL. 

rovq ~ 

U 
DATA SHEETS 

0 

ANALYTICAL 

Q m, I ► ► ~ 

. . „ 

b~ 
0 

~ 

~ 

Ar®alvtical Narrative RFA #Bora1 Brick Page 1 of I 

Client/Plant Name: Analvtical Testing Consultants. Inc. Date Rec'd in lab: 5/21/97 

Analyst:JBN Date of Analysis:6/03/97 

Analysis Method:EPA Method 26 Analyte(s):HCI. HF 

Sample Matrix & Components: 

0.1 N H2 SO4+ DI H2 0 rinses 

Summary of Sample Prep: 

Samples were final volumed in the laboratory by JBN. No further 

~ pretreatment of the samples was required. Field Spike samples were 

diluted 5-fold for HC1 analysis'. 

- J 

Summary of Instrumentation: 

"Clyde" PRP-X100 Column #2306 50 }:l Inj (HC1), 10 K1 Inj (HF) 

Eluent: 4mM Phthalic Acid pH 3.6 . Flow Rate: 2 mis/min 

Gain 0.2 uS/cm (HC1); Gain 0.4 μS/cm (HF) Temp: 40 ° C 

Analytical Detection Limit(s): 0.211 ppm HCl 

5.15 ppm HF 

J 

Summary of QA Audit Sample Aaalysis: 

~ For the HC1 analysis, a QA audit of 20.0 ppm chloride was prepared 

~ and analyzed in the saine manner as the samples. A+0.18$ deviation 

from the expected value was obtained. 

~ For the HF analysis, a QA audit of 100 ppm fluoride was prepared and 

analyzed in the same manner as the samples. A+0.78$ deviation from 

the expected value was obtained. 

Summary of Sample Spike Analysis: 

For the HC1 analysis, 0.8 mis of sample 1-HC1-1 (IMP 1,2) was spiked 

~ with 0.8 mis of a 5 ppm chloride standard. A 92.4$ recovery was 

obtained. 

For the HF analysis, 0.5 mis of sample 1-HC1-1 (IMP 1,2) was spiked 

-~ with 0.5 mis of a 50 ppm fluoride standard. A 94.6$ recovery was 

obtained. 

Miscellaneous Comments Reaardine Samnle Analvsis: (Note unusual catch weights, interferences, odd 

~ sample behavior, and steps taken to confirm unusual results. Also note any deviations from standard 

analytical procedures, together with justification and possible affect on results. Specify samples when 

applicable.) 

Low catch weights for both HC1 and HF for sample 1-HC1-1 (IMP 1,2) 

were confirmed by matrix spiking. 

' Confirmation of Data Review: 

J Lab QA Officcr Signature Date 
Hydrogen Chloride Analytical Data Sheet 

Client Name: Analytical Testing Consultants, Inc. Job Num. 52197 

File Pathway: C:U0BSIATC1521971HCL.WB1 File: HCI 

Analyst J B Nemet Date: 06/02/97 

Chloride Standard Calibration Curve by Llnear Regression 

96 , 

CI- Calculated Deviadon 

Conc. Standard Areas Average % Std Conc. from 

(ppm) In'.1 In'.2 Area Diff. m Actuai 

1.0 27860 27942 27901 0.15% 1.07 6.90% 

5.0 130289 131444 130867 0.44% 4.96 -0.890/o 

10.0 262791 263529 263160 0.140/* 9.95 -0.51% 

~ 25.0 662219 663007 662613 0.06% 25.03 0.11 % 

i Standard Curve S : 26493 Y-Int 420 LoD m: 0.205 

Field Samples in: 0.1 N 112SO4 

Sample HCI Expeeted FTeld 

Sample Inj. I. Inj. 2 Average % Dilution Volume Catch Fld Spk Spike 

ID Area Area Area DiS Factor (mis) (mgs) Cateh Recovery 

0.1 N H2SO4 < 5000 < 5000 < 5000 0.00% 1 30 < 0.00631 

1-HCL-1 (1,2) 127724 128451 128088 0.28% 1 58 0.289 

1-HCL-1 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 45 < 0.00947 

1-HCL-2 (1,2) 484813 484920 484867 0.01% 1 55 1.04 

1-HCL-3 (1,2) 524632 523290 523961 0.13% 1 59 1.20 _ 

1-HCL-4 (1,2) 382860 382224 382542 0.08% 1 53 0.788 

1-HCL-4 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 29 < 0.00610 

1-HCL-5 (1,2) 351206 351934 351570 0.10% 1 64 0.874 

1-HCL-6 (1,2) 359262 359121 359192 0.020/o 1 60 0.838 

FIELD SPIKE -1 461063 459822 460443 0.13% 5 54 4.83 5.14 94.0% 

FIELD SPIKE -2 452149 449709 450929 0.27% 5 57 4.99 5.14 97.1% 

Average % Expeeted Calculated Percent 

In'. 1 In'. 2 Area Dev. ppm Cl- ppm CI- DifE 

IN-HOUSE 530844 529947 530396 0.08% 20.0 20.0 0.18% 

: . - ~:-• >_ . 1iMTRJ;X 8P UCE'~ : Average % Expected Calculated % 

Sample I.D. In'. 1 In'. 2 Area Dev. ppm Cl- ppm Cl- Recovery 

1-HCL-1 (1,2) 125023 124847 124935 0.07% 2.50 2.31 92.40/o 

Note: 0.8 mis of the above sample was spiked witll 

0.8 mis of a 5 ppm chloride standard. 

Prtitbg f)ate 02,lun-97 PdnOng Time 01:07 PM 

~~ 
9 

~ 

~ 

~ 

.~ 

; 

~ ~ 

Chloride 

Calibration Curve 

700000 

500000 

~ 

~ 

0400000 

CU 

~ 300000 

~.. 

< 200000 

100000 

0 

0 5 10 15 20 25 

Concentration (ppm) 

J 

~~ 
9 

H dro en Fluoride Anallqical Data Sheet 

Client Name: Analytical Testing Consultants, inc. Job Num. 52197 

File Pathway: C:IJOBSIATC1521971HF.WB1 File: HF 

Analyst - J B Nemet Date: 06l03/97 

Fluoride Standard Calibration Curve by Unear Regression 

%. 

F- Calculated Deviation 

Conc. Standard Areas Average % Std Conc. from 

(ppm) In'.1 In'.2 Area Diff. m Actual 

10.0 14489 14430 14460 0.20% 10.55 5.48% 

50.0 79572 83420 81496 2.36% 50.65 1.30% 

100 158517 162726 160622 1.31% 97.98 -2.02% 

200 320273 344775 332524 3.68% 200.82 0.41% 

Standard Curve Slo : 1672 Y-Int: -3173 LoD m: 4.89 

Fieki Sampies in: 0.1 N H2SO4 

Sample HF Expected Field 

Sample Inj. 1 Inj. 2 Average % Dilution Volume Catch Fld Spk Spike 

ID Area Area Area Diff. Factor (mis) (mgs) Catch Recovery 

0.1 N H2SO4 < 5000 < 5000 < 5000 0.00% 1 30 < 0.154 

1-HCL-1 (1,2) 62046 58562 60304 2.890/o 1 58 2.32 

1-HCL-1 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 45 < 0.232 

1-HCL-2 (1,2) 340646 320078 330362 3.11% 1 55 11.6 

1-HCL-3 (1,2) 309356 314604 311980 0.84% 1 59 11.7 _ 

1-HCL-4 (1,2) 294663 295763 295213 0.190/a 1 53 9.96 

1-HCL-4 (3rd Imp) < 5000 < 5000 < 5000 0.00% 1 29 < 0.149 

1-HCL-5 (1,2) 267208 257917 262563 1.77% 1 64 10.7 

1-HCL-6 (1,2) 274064 281260 277662 1.30% 1 60 10.6 

FIELD SPIKE -1 111217 112431 111824 0.54% 1 54 3.91 4.21 92.9% 

FIELD SPIKE -2 105263 100006 102635 2.56% 1 57 3.80 4.21 90.2% 

AUDIT REPORT 

Average % Expected Calculated Percent . 

r 

Inj. 1 Inj. 2 Area Dev. ppm F- ppm F- Diff. 

r 

IN-HOUSE 163033 167573 165303 1.37% 100 101 0.78% 

1WATRIX sPBtE=:* ~. Average % Expected Calculated % 

Sample I. D. Inj. 1 Inj. 2 Area Dev. ppm F- ppm F- Recovery 

1-HCL-1 (1,2) 68296 67914 

—7—r--r 

68105 

— —T--T 

0.28% 25.0 23.6 94.6% 

Note: 0.5 mis of the above sample was spiked witfi 

0.5 mis of a 50 ppm fluoride standard. 

Prtnft Dete 03Jun-97 Printing Thn 11:48 AM 

-I3 
n 

nI 

t~ 

~ 

Fluoride 

Calibration CUrve 

350000 

300000 

4.., 250000 

C: 

=3 

O 200000 

V 

CU 150000 

L 

Q 100000 

50000 

01 

0 50 100 150 200 

Concentration (p-pm) 

7~ 
CHROMATOGRAMS 

~ 
.~ 

~ 

~ 

~ 

~ 

; 

~ 

~ 

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~ 

'= 1 

,A 

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Inatrument: "Clyde-Column: Hamilton PAP-X10U 2 ~ Ux9.6 mm 

Eluent: 9mM Phthalic Acid pH 3.6; Flov @ 2 mle/min; 5 pl Inj Vol 

Conductivity Detection Gain 0.9 pS/cm 40 C 

File : C:\EZCHAOM\CHAOM\15935.119 

Method : C:\EZCHROM\METHODS\M26.MST ~ 

Sample ID e - 1.0 PPM a 

Acquired : Jun 01, 1997 13:50:39 

Channel A 

C 

0.01 5 h 

1 

0 

r 

d 

e 

0.01 0 

V 

0 

1 

t0. 00 5 

a 

•m 

0 5 10 15 20 

Minutes 

--- Peak Name --- Aet. Time --Area-_ 

Chloride 2.88 27860 

/ ~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 pl Inj Vol 

Conductivity Detection Gain 0.4 μS/cm 40 C 

File : C:\EZCHROM\CHROM\15935.002 

Method : C:\EZCHItOM\METHODS\M26.MET 

Sample ID : 5.0 PPM a 

Acquired : May 30, 1997 17:36:55 

Channel A 

0.015 

0.010 

V 

0 

1 

t 0. 005 

9 

~ ~~• 

0 5 10. 15 20 

Minutes 

Peak Namo Ret. Time Area 

Chloride 2.90 130289 

li 7 
a 

0 

~ 

~ 

khI 

LV 

~ 

~ KH 

~ ~ 

iJ 

~ 

~ 

,.y 

~ .J 

Inatrument: "Clyde" Column; Hn.milton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow 2 2 mla/min; 5 pl Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHFt0M\15935.003 

Method : C:\EZCHItOM\METHODS\M26.MET 

Sample.ID : 10.0 PPM a 

Acquired : May 30, 1997 18:25:47 

Channel A 

C 

06 h 

1 

0 

r 

05 i 

d 

e 

04 

03 

02 

01 

00 

ni 

-0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.93 262791 

0. 

0. 

V 0. 

O 

1 

t 

3 0. 

0 . 

0 . 

-0. 

'J I? 
Inatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pFi 3.6; Flov @ 2 mla/min; 5 μl I_3 vol 

Conductivity Detection Gain 0.4 pS/cm 40 C 

File : C:\EZCHItCM\CHAOM\15935.120 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample . ID : 1.0 PPM b 

Acquired : Jun 01, 1997 13:56:31 

Channel A 

0.015 

0.010 

C 

h 

1 

0 

r 

d 

e 

v 

0 

1 

t0. 005 

a 

• •~~ 

O 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.88 27942 

qy 
a 

~ 

~ 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4._6 mm .. 

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mla/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 {iS/cm 40 C 

File : C:\EZCHROM\CHROM\15935.116 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : 5- .0 PFM b 

Acquired : Jua 01, 1997 10:05:59 

Chanuel A 

0.01 : i 

0.01 

V 

0 

1 

t 0.00 3m 

s 

. N •• 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Chloride 2.90 131444 

~ 

-10joil 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pI4 3.6; Flov @ 2 mis/min; 5 ul Inj vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROX\l5935.117 

Method : C:\EZCHROM\METHODS\M26.MET 

3ample.ID :.10.0 PPM b 

Acquired : Jun 01, 1997 10:11:51 

Channel A 

• . l5 

0.010 

v 

0 

1 

t0. 005 

3 

0.000 

0 5 10 

Minutes 

15 20 

Peak Name Ret. Time Area 

Chloride 2.93 263529 

0 
~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm _ 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 μl Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHROM\15935.118 

~ Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : 25.0 PPM b 

Acquired : Jun Ol, -1997 11:00:44 

~ - 

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'.~ 

.:~ 

~ 

iJ 

~ 

0.12 

0.10 

0.07 

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e 

5 

0 

5 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.98 663007 

A92, 
Inztrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mis/min; 5g1 Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\15935.005 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : Audit (20.0 ppm) a 

Acquired : ay 30, 1997 19:20:31 

Channel A 

0.125 

0.100 

C 

h 

1 

0 

r 

d 

e 

0.075 

V 

O 

1 

t 0.050 

s 

0.025 

~ •~• 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.96 530844 

F3 
n 

R 

:<< 

~ 

~ 

~ 

J 

r, 

v 

i 

-J 

=~ 

~ 

~ 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 pS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.001 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : 0.1 N H2SO4 a 

Acquired : May 31, 1997 14:01:05 

Channel A 

0.01 5 C 

h 

1 

0 

, 

r 

d 

0.01 0 e 

V 

0 

1 

t 0.00 5 

9 

. .. 0 

0 5 10 15 20 

Minutes 

Peak Name Aet. Time Area 

--------------- ------ -------- 

Chloride 2.85 3319 

~~ 
0.1 

0.1 

Aai; 

V 

0 

1 

t 0.0 

s 

0.0 

0.0 

25 F 

1 

u C 

o h 

rl 

00 10 d r 

e i 

d 

75 

e 

50 

25 

00 

i 

, f 

~ 

~ L 

L 

i 

Instrument: "Clyde" Column: Ham.ilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.002 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 1 a 

Acquired : May 31, 1997 14:49:59 

Channel A 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Fluoride 2.18 552589 

Chloride 2.92 127724 

g~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.003 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RtJN 1 BT a 

Acquired : May 31, 1997 14:55:52 

Channel A 

0.01 5 

C 

h 

1 ' 

0 

r 

0.01 0 1 

d 

e 

v 

0 

1 

t0. 00 5 

s 

• •• 0 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.87 3803 

96 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHIIOM\52197.004 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 2 a 

Acquired : Majr 31, 1997 15:44:46 

Channel A 

0.12 

0.10 

0.07 

V 

0 

1 

t 0.05 

s 

0.02 

5 C 

h 

1 

0 

r , 

0 i 

d 

e 

5 

0 

5 

0 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

-------------- 

Chloride 3.03 484813 

O ~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

~ Eluent: 4mM Phthalic Acid pH 3.6; Floza @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.005 

a Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : AUN 3 a 

Acquired : May 31, 1997 15:50:40 

~ . . 

~ Channel A 

0.1 

0.1 

mi 

V 

0 

1 

t 0.0 

s 

0.0 

0.0 

25 C 

h 

1 

0 

r 

00 i 

d 

e 

75 

50 

25 

00 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 3.03 524632 

,r,f 
Instrument: "Clyde" Column: Hemilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 pS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.006 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 4 a 

Acquired : May 31, 1997 16:39:34 

Channel A 

0.12 

0.10 

0.07 

V 

0 

1 

t 0.05 

s 

0.02 

;o •rs, 

5 C 

h 

1 

0 

r ~ 

0 i 

d 

e 

5 

0 

5 

0 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 3.01 382860 

~~ 
~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}11 Inj Vol 

Conductivity Detection Gain 0.4 }1S/cm 40 C 

~ File : C:\EZCF~tOM\CHROM\52197.007 

Method : C:\ZZCHROM\METHODS\M26.MET 

Sample ID : RUN 4 BT a 

Acquired : May 31, 1997 16:45:27 

~ Channel A 

.~ 

- 

0.015 

i~ 

~ 

0.010 

~ O 

 1 

t 0. 00 

3 

• •• 

5 10 15 

Minutes 

Peak Name Ret. Time Area 

i 

~., 

,I 41~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.008 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : -RUN 5 a 

Acquired : May 31, 1997 17:34:22 

Channel A • 

0.12 

0.10 

0.07 

v 

0 

1 

t 0.05 

9 

0.02 

~ •• 

5 C 

h 

1 

0 

r 

0 i 

d 

e 

5 

0 

5 

0 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Chloride 3.00 351206 

. C~ / 
r 

Inmtrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

~ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mla/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }:S/cm 40 C 

~ File : C:\EZCFROM\CHROM\52197.009 

Method : C:\•EZCHROM\METHODS\M26.MET 

Sample ID : RUN 6 a 

Acquired : May 31, 1997 17:40:15 

O - . 

~ Channel A 

'- 0.12 

0.10 

0.07 

V 

0 

1 

t 0. 05 

s 

0.02 

~ •~ 

5 C 

h 

1 

0 

r 

, 

0 i 

d 

e 

5 

0 

5 

0 

0 5 10 15 20 

Minutea 

~ 

4~ 

Peak Name Ret. Time Area 

Chloride 3.00 359262 

~J 
F C 

6 1 h 

u 

0 

r 

5 i ~ 

d 

e 

4 

3 

2 

1 

0 

10 ~1 

0.0 

0.0 

V 0.0 0 

1 

t 

s 0.0 

0.0 

0.0 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}il Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.010 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID :-ES 1 a 

Acquired : May 31, 1997 18:28:40 

Channel A 

~ 

~ 

5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.12 231454 

Chloride 2.93 461063 

93 
A 

0 

9 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 K1 Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.011 

Method : C:\EZCHtOM\METHODS\M26.MET 

Sample ID : FS 2 a 

Acquired : May 31, 1997 18:34:05 

Channel A 

0.0 

0.0 

0.0 

V0.0 

0 

1 

t 

s0.0 

0.0 

0.0 

F C 

6 1 h 

u 

0 

r 

5 i 

d it 

e 

4 

3 

2 

1 

o—U 

I 5 10 15 20 

Minutes 

-'• i 

Peak Name 

_ Fluoride 

Chloride 

Ret. Time 

2.12 

2.93 

Area 

226290 

452149 

9v 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.012 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : 0.1 N H2SO4 b 

Acquired : May 31, 1997 18:49:59 

Channel A 

0.015 

0.010 

V 

0 

1 

t 0. 005 

s 

• ••• 

0 5 10 15 20 

Minutes 

Peak Neme Ret. Time Area 

--------------- ------ -------- 

a; 
e In3trument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

~ File : C:\EZCHROM\CHROM\52197.013 

Method : C:\ZZCHROM\METHODS\M26.MET 

Sample ID : RUN 1 b 

Acquired : May 31, 1997 18:55:51 

~ 

r-, 

;i Channel A 

0.12 

0.10 

0.07 

V 

0 

1 

t 0. 05 

s 

0.02 

®0 ~ ~• 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.15 678264 

Chloride 2.92 128451 

5 F 

1 

uC 

o h 

r 1 , 0 i o 

d r 

i 

d 

e 

5 

0 

5 

~

~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.014 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 1 BT b 

Acquired : May 31, 1997 19:44:45 

Channel A 

0.015 

C , 

h 

1 

0 

0.010 r 

i 

d 

e 

V 

0 

1 

t 0. 005 

s 

. .. N 

0 5 10 15 r~ 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.88 3979 

q~ 
~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}il Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.015 

~ Method : C:\$ZCHROM\METHODS\M26.MET 

Sample ID : RUN 2 b 

Acquired : May 31, 1997 19:50:39 

~ Channel A 

" 0.12 

- 0.10 

~ 

0.07 

V 

o 

1 

t 0.05 

..

~ s 

J 

0.02 

Li 

~ 0.00 

0 

~ 

~ 

Peak Name J --------------- 

.. Chloride 

5 10 15 20 

Minutes 

Ret. Time Area 

3.03 484920 

'W 
instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm v 

Sluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

Hile : C:\EZCHROM\CHROM\52197.016 

Method : C:\EZCHPOM\METHODS\M26.M:ET 

Sample ID :-RUN 3 b 

Acquired : May 31, 1997 20:39:34 

Channel A 

0.12 

0.10 

0.07 

V 

0 

1 

t 0. 05 

9 

0.02 

am 

5 C 

h 

1 

0 

r 

0 i 

d 

e 

5 

0 

5 

0 7 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Chloride 3.03 523290 

~O 
~ Instruments "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CIDtOM\52197.017 

~ Method : C:\EZCHAOM\METHODS\M26.MET 

Sample ID : AUN 4 b 

Acquired : May 31, 1997 20:45:27 

Channel A 

0.1 

0.1 

~ 

0.0 

V 

1 

t 0.0 

..~ 

i 

s 

J 

0.0 

J 

~ 0.0 

0 5 10 1s 20 

Minutes 

Peak Name Aet. Time Area 

Chloride 3.00 382224 

14~07 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm ' 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}:1 Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHFtOM\CHROM\52197.018 

Method : C:\EZC1iROM\METHODS\M26.MET 

Sample ID : RUN 4 BT b 

Acquired : May 31, 1997 21:34:20 

Channel A 

0.01 III 

0.. 01 

V 

0 

1 

t 0. 00 

s III 

~ •~ 

5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

i i 
~ 

0 

~ 

, 

~ 

3 

~ 

~ 

~ 

~ 

i 

~ 

~ 

~ 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.019 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : -RUN 5 b 

Acquired : May 31, 1997 21:40:15 

Channel A 

5 C 

h 

1 

0 

r , 

0 i 

d 

e 

5 

0 

5 

o l ~_j 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 3.00 351934 

J 

0.12 

0.10 

0.07 

v 

o. 

1 

t 0.05 

s 

0.02 

• •• 

r 2, 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm . 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.020 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 6 b 

Acquired : May 31, 1997 22:29:08 

Channel A 

0.12 

0.10 

Aweiri 

V 

0 

1 

t 0. 05 

s 

0.02 

n.nn 

5 C 

h 

1 

0 

r 0 

d 

e 

5 

0 

5 

0 

Li 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Chloride 3.00 359121 

103 
Peak Name 

Fluoride 

Chloride 

Ret. Time Area 

------ -------- 

2.10 248685 

2.93 459822 

<~ 

~ 

~ d 

:.~ 

~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5}il Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.021 

~I Method : C:\EZCHROM\METHODS\M26.MET 

" Sample ID : FS 1 b 

Acquired : May 31, 1997 22:34:33 

~ 

. 

! Channel A 

~ ;:•i 

~ 

.~`. . 

_. ~ 

~) 

~ 

0.125 

0.100 

0.075 

V 

0 

1 

t 0. 050 

s 

• weWe 

F C 

1 h 

u 1 

0 0 

r r , 

i i 

d d 

e e 

0 5 10 15 20 

Minutes 

iDC( 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 }:S/cm 40 C 

File : C:\EZCHROM\CHItOM\52197.022 

Method : C: \EZCHtOM\METHODS\M26.MET 

Sample ID : •FS 2 b 

Acquired : May 31, 1997 23:22:59 

Channel A 

0.1 

0.1 

C•1~ [•] 

V 

0 

1 

t 0.0 

s 

• • 

• • 

25 F C 

1 h 

u 1 

0 0 

r r , 00 i i 

d d 

e e 

75 

50 

25 

00 

0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.12 220353 

Chloride 2.93 449709 

/ 

IQ~ 
i~ 

...~~ 

s:a 

J 

_J 

~ 

, 

~ 

_J 

0.0 

0.0 

0.0 

V 0.0 . 

0 

1 

t 

s 0.0 

0.0 

0.0 

-o 0 0 5 10 15 20 

Minutes 

FC 

6 1 h 

ul 

0 0 

r r 

5 i i ~ 

dd 

e e 

4 

3 

2 

1 

0 

, 

~ Instrument: "Clyde" Column: Hamilton PAP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mla/min; 5}l1 Inj Vol 

Conductivity Detection Gain 0.4 }:S/cm 40 C 

File : C:\EZCHROM\CHROM\52197.023 

~

Method : C: \EZCHAOM\METHODS\M26.MET 

~ Sample ID : SPIKE a 

Acquired : Jun 02, 1997 02:31:47 

~ Channel A 

Peak Name Aet. Time Area 

Fluoride 2.13 214522 

Chloride 2.87 125023 

1,1) 6 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 ml$/min; 5 ul Inj Vol 

Conductivity Detection Gain 0.4 pS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.024 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample .ID : - SPIKE b 

Acquired : Jun 02, 1997 02:37:39 

Channel A 

FC 

0.0 6 lh 

ul 

00 

rr 

0.0 5 ii 

dd 

ee 

0.0 4 

V 0.0 3 

0 

1 

t 

s 0.0 2 

0.0 1 

0.0 0 

-0 0 , 

. 10 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.12 254397 

Chloride 2.85 124847 

10 
~ 

~ 

e 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mis/min; 5 μl Inj vol 

Conductivity Detection Gain 0.4 }tS/cm 40 C 

£ile : C:\EZCHROM\CHROM\15935.114 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : Audit (20.0 ppm) b 

Acquired : Jun 01, 1997 09:11:15 

Channel A 

0.12 

0.10 

0.07 

v 

0 

1 

t 0. 05 

s 

0.02 

mwono 

5 C 

h 

1 

0 

r 

0 i 

d 

e 

5 

0 

5 

t 

5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Chloride 2.96 529947 

/~?~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 pS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.031 

Method : C:\EZCHROM\METHODS\M26.NET 

Sample ID : 10.0 PPM a 

Acquired : Jun 03, 1997 09:58:57 

Channel A 

u. v 

0. 

0. 

0. 

v 0. 

0 

1 

t 0. 

s 

0. 

0. 

0. 

-0 

0 

07 

F 

06 1 

u 

0 

05 r i 

d 

e 

04 

03 

02 

01 

00 

ni 

.. O 

5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.08 14489 

/bq 
~ Eluent: 4mM Phthalic Acid pH 3.6; Florr @ 2 mla/min; 10 ul Inj vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\3-2/9f oo / .;,;,~ 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

~ Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID :=~"O P~"~t a ~•E~a'~L 

Acquired : Jun 03, 1995 11:18:56 

E~ Channel A 

0.0" 0

F 

0.0 7 1 

u 

0 

0.0 6 r i 

d 

5 e 

0.0 

v 0.0 4 

0 

1 

t 0.0 3 

s 

0.0 2 

0.0 1 

0.0 0 

-0 0 , 

~ 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 79572 

/ M 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; FloLr @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }IS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.003 

Method : C:\EZCHROM\METHODS\M26-MET 

Sample ID : 100 PPM a 

Acquired : Jun 03, 1997 11:01:30 

Channel A 

u.0 

0.0 

0.0 

0.0 

V0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-0 0 

a F 

1 

u 

7 0 

r 

6 d 

e 

5 

4 

3 

2 

1 

0 

, 

. +0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.12 158517 
e 

n 

e 

~ 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 m,m 

Eluent: 4mM Phthalic Acid pH 3.6; Flow Q 2 mla/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHItOM\52197.002 

Method : .C:\EZCHROM\METHODS\M26.MET 

Sample ID : , 200 PPM a 

Acquired ; Jun 03, 1997 10:24:53 

Channel A 

0.0° 

~ F 

1 

u 

0.0 7 0 

r 

6 d 

i1 

0.0 

e 

0.0 5 

V 0.0 4 

0 

1 

t 0.0 3 

s 

0.0 2 

0.0 1 

0.0 0 

, -0 0 

. 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Fluoride 2.15 320273 

J/2., 
08 

07 

F 

06 

OS 

04 

03 

02 

01. 

00 

ni T-7— I 

) 5 10 15 20 

Minutes 

0. 

0. 

0. 

0. 

V 0. 

0 

1 

t 0. 

s 

0. 

0. 

-0. 

1 

u 

0 

r 

i 

d 

e 

Instrument: "Clyde" Column: He ~ milton PAP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 K1 Inj vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52l97.032 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : 10.0 PPM b 

Acquired : Jun 03, 1997 10:04:11 

Channel A 

Peak Name Aet. Time Area 

Fluoride 2.08 14430 

l~~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

~ Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 10 }il Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.028 

~ Method : C:\EZCHROM\METHODS\M26.MT 

Sample ID :•200 PPM b 

Acquired : Jun 03, 1997 02:13:57 

~ - 

Channel A 

o.os i 

0.0 

0.0 

o us 

~ • ~ 

0 

1 

t 0.0 

s 

~ae; 

0.0 

0.0 

~ 5 10 15 20 

Minutes 

•, 

Peak Name Aet. Time Area 

Fluoride 2.15 344775 

F 

1 

u 

7 0 

r 

i ' 

6 d 

e 

5 

3 

2 

1 

0 

i 

~~~ 
LT • ~ 

0 

1 

t 0.0 

s 

~xi; 

Wel 

0.0 

v F, 

1 

u 

7 0 

r 

6 d 

e 

5 

4 

3 

2 

1 

0 

i 

U. 0° 

0.0 

0.0 

Instrument: "Clyde" Column: Hamilton PAP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.005 

Method : C:\EZCHAOM\METHODS\M26.MET 

Sample ID :.Audit (100 ppm) a 

Acquired : Jun 03, 1997 11:28:05 

Channel A 

~ 5 10 15 20 

Minutes 

Peak Name Aet. Time Area 

Fluoride 2.12 163033 

ll~ 
♦ 

' Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

~ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj vol 

Conductivity Detection Gain 0.4 pS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.006 

~ Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 1 a 

Acquired : Jun 02, 1997 19:40:20 

~ Channel A 

0. 0" 

0.0 

A 0.0 

d 

0.0 

v 0.0 

.,N 0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-0 0 

~ 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 62046 

Chloride 2.85 12225 

0 

7 F 

1 

uC 

6 o h 

r 1 

l o 

d r 

5 e i 

d 

4 e 

3 

2 

1 

0 

~ 

116:2 
Instrument: "Clyde" Column: Hamilton PFtP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.007 

Method : C:\EZCHROM\MZTHODS\M26.MET 

Sample ID :. RUN BT a 

Acquired : Jun 02, 1997 19:55:43 

Channel A 

0.08 

0.07 

0.06 

0.05 

V0.04 

0 

1 

t 0.03 

s 

0.02 

0.01 

0.00 

-0.010 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

/0 
a 

~ 

Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm . 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.008 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 2 a 

Acm, ; red : Jun 02, 1997 20:01:07 

i 

~ 

, 

~ 

~ 

~ ., 

~1 

•i 

~ 

Channel A 

o F 

1 

u 

7 o C 

rh 

i 1 ~ 

6 do 

e r 

i 

5 d 

e 

4 

3 

2 

1 

0 

1 _ 

0 5 10 15 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

Fluoride 2.15 340646 

Chloride 2.87 46930 

W. 0" 

0.0 

0.0 

0.0 

v 0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-0. 0 

~Ue 

Cl i" 
Inatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.009 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 3 a 

Acquired : Jun 02, 1997 20:49:31 

Channel A 

O.0 

0. 

0. 

0.. 

V0. 

0 

1 

t 0. 

s 

0. 

0. 

0. 

o F 

1 

u 

07 o C 

rh 

i 1 , 

06 d o 

e r 

05 d 

e 

04 

03 

02 

01 

00 

~ 

ni 

5 10 15 20 

Minutes 

Peak Name Aet. Time Area 

Fluoride 2.15 309356 

Chloride 2.87 50728 

~I ~ 
I Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.010 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID :'RUN 4 a 

Acquired : Jun 02, 1997 20:54:54 

Channel A 

u.u ~ F 

1 

u 

0.0 

0.0 

7 0 

6 d l i h ' 

r C 

e o 

r 

0.0 5 1 

d 

e 

v 0.0 4 

0 

1 

t 0.0 3 

s 

0.0 2 

0.0 1 

0.0 0 

-0 0 , 

 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.15 294663 

Chloride 2.87 36138 

112 v 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm ~ 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.011 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 4 BT a 

Acquired : Jutn 02, 1997 21:10:18 

Channel A 

0.08 

0.07 

0.06 

0.05 

V 0.04 

0 

1 

t 0.03 

s 

0.02 

0.01 

0.00 

-0.010 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

120 
~ 

~ 

r R 

h 

Instrument: "Clyde" Column: He.milton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthali• c Acid pH 3,6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\EZCHROM\CHIROM\52197.0 29 

Method : C:\EZCHRCM\METHODS\M26.MET 

Sample'ID : 100 PPM b 

Acquired : Jun 03, 199711:06:55 

~ 

• -•:n ~

; 4 

U.0 

0.0 

0.0 

0.0 

v 0.0 

0 

1. 

t 0.0 

s 

0.0 

0.0 

0.0 

-0 0 

. i0 

Channel A 

5 10 15 

Minutes 

~~ Jr{• 1 

3 

:Y~:~•~l 

•{.~rcia~ a{ 

1 

u 

0 

r 

i 

d 

e 

20 

~ V 

!~ 

.,. ~ 

Peak Name 

Fluoride 

Ret. Time Area 

2.12 162726 

1 7/2 
r 

~ . s.. 

~ 

~ 

.. ~ 

n 

..~ ~ ~ 

...,~ - 

iJ 

ri 

~ 

, 

` U 

Inszrument: ^Clyde ° COlumna He.milton PRP-X100 250x4.6 aua - 

Eluent: 4mM PhthalicAcid pH 3.6;= Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 gS/cm 40 C 

File : C:\EZCHROM\CHPOM\52197.027 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : 50 PPM b 

Acquired': Jun 03, 1997 02:08:34 

Channel A 

O.G 

0. 

0. 

0. 

v 0. 

0 

1 

t 0. 

s 

G. 

0. 

0. 

-0 

u 

F ' 

07 1 

u 

0 

06 r i 

d 

e 

05 

04 

~ 

03 

02 

01 

00 

n~ 

Peak Natne Ret. Time Area 

Fluoride 2.10 83420 

 ` `0 5 10 15 W 

Minutes 

/23 
` Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

e Eluent: 41M Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 K1 Inj Vol 

Conductivity Detection Gain 0.4 KS/cm 40 C 

File : C:\E2CHROM\CHROM\52197.027 

(~ Method : C:\EZCHR0M\METHODS\M26-MET 

[w] Sample ID :- 50 PP'M b 

Acquired : Jun 03, 1997 02:08:.34 

~ Channel A 

0 

i uel 

kd 

W. 0 

0.0 

0.0 

0.0 

V 0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-0 0 

0 

F 

7 1 

u 

0 

6 r ~ i 

d 

e 

5 

4 

3 

2 

1 

0 

, 

. +0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 83420 

~ jz ~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 },1S/cm 40 C 

File : C:\EZCHROM\CHROM\52197.029 

Method : C: \EZCHI3.OM\METHODS\M26.MET 

Sample ID : 100 PPM b 

Acquired : Jun 03, 1997 11:06:55 

Channel A 

1 

u 

0 

r 

i 

d 

e 

0. 

0. 

0. 

0. 

v 0. 

0 

1 

t 0. 

s 

0. 

0. 

0. 

)6 

)5 

)4 

)3 

)2 

01 

00 

ME n, 

5 10 

Minutes 

15 20 

Peak Name Ret. Time Area 

Fluoride 2.12 162726 

/ 

~2~ 
~ 

 Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

~ Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHtOM\CHROM\52197.012 

~ Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 5 a 

Acquired : Jun 02, 1997 21:15:41 

- . ,.~

---- - 

M:N 

~ 

u.0 

0.0 

0.0 

Wi; 

V 0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

-0 0 

o E, 

1 

u 

7 0 

C 

rh 

6 d il 

0 

e 

r 

5 1 

d 

e 

4 

3 

2 

1 

0 

, 

. 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.13 267208 

Chloride 2.85 34052 

12, b 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.013 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : .RUN 6 a 

Acquired : Jun 02, 1997 22:04:05 

Channel A 

0. 

0. 

0. 

0. 

v 0. 

0 

1 

t 0. 

s 

0. 

0. 

0. 

-0. 

v a E, 

1 

07 

u 

0 

r C 

06 

i h 

d 1 

e o 

r 

05 1 

d 

e 

04 

03 

02 

01 

00 

ni 

) 5 10 15 20. 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.15 274064 

Chl.oride 2.87 34795 

/2"? 
t 

~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 m19/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHtOM\CHROM\52197.014 

~ Method : C:`EZCHROM\METHODS\M26.MET 

Sample ID : FS 1 a 

Acquired : Jun 02, 1997 22:09:29 

~ Channel A 

 0.08 F C 

1 h 

u 1 

0.06 

0.07 0 0 

r r 

dd 

e e 

0.05 

V 0.04 

0 

1 

t 0.03 

s 

~ •: 

0.01 

0.00 

~ 0 O1 

. 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 111217 

Chloride 2.92 228358 

, ;0 P" 
° F C 

1 h 

7 u 1 

0 0 

r r 

6 d d 

e e 

5 

4 

3 

2 

1 

0 

, 

U. 0° 

0.0 

0.0 

0.0 

V 0.0 

0 

1 

t 0.0 

a 

0.0 

0.0 

0.0 

-0 0 

Instrument: "Clyde" Columna , Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHIZOM\CHROM\52197.015 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : FS 2 a 

Acquired : Jun 02, 1997 22:24:53 

Channel A 

. 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 105263 

Chloride 2. 92 221521 

i 2~ 
t . 

p Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Er i ] Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol 

Conductivity Detection Gain 0.4 }:S/cm 40 C 

File : C:\EZCHROM\CHROM\52197.016 

n Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 1 b 

Acquired : Jun 02, 1997 22:30:15 

J Channel A 

~ 

•'i 

r~ 

J 

~ 

0.0 

0.0 

0.0 

0.0 

V 0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-o 0 

0 

7 F 

1 

uC , 

6 oh 

r 1 

i o 

5 dr 

e i 

d 

9 e 

3 

2 

1 

0 

, 

 +0 5 10 15 20 

Minutes 

=1 

Peak Name Ret. Time Area 

~ --------------- 

-----~ -------- 

~ Fluoride 2 .10 58562 

Chloride 2.85 12196 

/-~ ,?) 
Instrument: "Clyde" Column: Ha.milton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.017 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 1 BT b 

Acquired : Jun 02, 1997 23:18:39 

Channel A 

0.08 

0.07 

0.06 

0.05 

V0. 04 

0 

1 

t 0.03 

9 

0.02 

0.01 

0. 00 

-0.010 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

131 
~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flov @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.018 

('] Method : C:\EZCHRCM\METHODS\M26-MET 

i ~ Sample ID :'RUN 2 b 

Acquired : Jun 02, 1997 23:24:03 

~ Channel A 

0.0 

0.0 

0.0 

0.0 

V 0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-0 0 

o F 

1 

u 

7 o C 

rh 

i 1 ' 

6 do 

e r 

5 d i 

e 

4 

3 

2 

1 

0 

i 

. 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.16 320078 

Chloride 2.87 46742 

13z 
Inatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Floer @ 2 mis/min; 10 μl Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.019 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 3 b 

Acquired : Jun 02, 1997 23:39:26 

Channel A 

U. UO F 

1 

u 

0.0 7 o C 

r h 

0.0 6 do 

e r 

i 

0.0 5 d 

e 

V 0.0 4 

0 

1 

t 0.0 3 

s 

0.0 2 

0.0 1 

0.0 0 

-0 0 , 

 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.15 314604 

Chloride 2.87 50360 

, ~3 
.•t_;iyae" (.;olumn: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 )iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.020 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID :- RUN 4 b 

Acquired : Jun 02, 1997 23:44:50 

Channel A 0. 

0. 

0. 

0. 

v 0 • 

0 

1 

t 0. 

s 

0. 

0. 

0. 

-0 

- 0 5 10 15 20 

Minutes 

:-„ 

Peak Name Ret. Time Area 

Fluoride 2.15 295763 

-' Chloride 2.87 36183 

~ 

~ 

.~ 

J i351 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/ain; 10 y1 Inj vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.021 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 4 BT b 

Acquired : Jun 03, 1997 00:33:14 

Channel A 

0.08 

0.07 

, 

0.06 

0.05 

V0.04 

0 

1 

t 0.03 

s 

0.02 

0.01 

0.00 

-0.0 0 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

--------------- ------ -------- 

~ 

~~j7 
~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 }il Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCFiROM\CHROM\52197.022 

~ Method : C:\EZCHROM\METHODS\M26-MET 

Sample ID : RUN 5 b 

Acquired : Jun 03, 1997 00:38:37 

" Channel A 

•:c 

0.08 

0.0 

0.0 

0.0 

V 0.0 

0 

1 

t 0.0 

s 

0.0 

~.. ~ 

0.0 

~ 

0.0 

-0 0 

. 0 

Peak Name 

Fluoride 

Chloride 

5 10 

Minutes 

Ret. Time 

2.13 

2.85 

15 

Area 

257917 

33802 

20 

F 

1 

u 

7 0 

rC 

i h 

6 dl 

eo 

r 

5 i 

d 

e 

4 

3 

2 

1 

0 

, 

1.3& 
-- i 

Irnatrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mla/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 uS/cm 40 C 

File : C:\EZCHROM\CHItOM\52197.023 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : RUN 6 b 

Acquired : Juri 03, 1997 00:54:01 

Channel A 

0. 

0. 

0. 

0. 

V 0. 

0 

1 

t 0. 

s 

0. 

0. 

0. 

-0. 

08 F 

1 

07 

u 

0 

r C 

06 

ih 

d 1 

e o 

r 

05 1 

d 

e 

04 

03 

02 

01 

00 

n ~ 

) 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.15 281260 

Chloride 2.87 34135 

/3"? 
° F C 

1 h 

u 1 07 0 0 

r r 

i i ~ 06 d d 

e e 

05 

04 

03 

02 

01 

00 

ni 1-0 

5 10 15 20 

Minutes 

0. 

0. 

0. 

V 0. 

0 

1 

t 0. 

s 

0. 

0. 

0. 

-0. 

~ Instrument: "Clyde" Column: Hamilton PAP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Floyr @ 2 mis/min; 10 Kl Inj Vol 

Conductivity Detection Gain 0.4 uSrcm 40 C 

File : C:\EZCHROM\CHROM\52197.024 

~ Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : FS 1 b 

Acquired : Jun 03, 1997 00:59:25 

~ Channel A 

Peak Name Aet. Time Area 

Fluoride 2.10 112431 

Chloride 2.90 228500 

/ .3~ 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHROM\52197.025 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : FS 2 b 

Acquired : Cun 03, 1997 01:47:49 

Channel A 

0.0 

0. 0° ° FC 

7 u1 1 h 

0 0 

r r i 1 , 

0.0 6 dd 

e e 

0.0 5 

V0.0 4 

0 

1 

t 0.0 3 

s 

o.a 2 

0.0 1 

0.0 0 

, -o 0 ' o 5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 100006 

Chloride 2.90 221176 

i31 
~ Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 gl Inj Vol 

Conductivity Detection Gain 0.4 P.S/cm 40 C 

File : C:\EZCHROM\CHROM\52197.033 

Method : C:\EZCHROM\METHODS\M26.MET 

(J Sample ID : HF SPIKE a 

Acquired : Jun 03, 1997 11:41:59 

~ 

~ Channel A e 0 

F 

7 1 

u 

o C ~ 6 r h 

i 1 

do 

5 e r 

i 

d 

4 e 

3 

2 

1 

0 

1 1: 1 

0 5 10 15 20 

Minutes 

0.0 

0.0 

0.0 

~ 

0.0 

:J 

V 0.0 

0 

1 

t 0.0 

s 

0.0 

0.0 

0.0 

-0.0 

Peak Name Ret. Time Area 

--------------- 

Fluoride 2.10 68296 

Chloride 2.84 6185 

i~G 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 p1 Inj Vol 

Conductivity Detection Gain 0.4 }iS/cm 40 C 

File : C:\EZCHROM\CHIZOM\52197.034 

Method : C:\EZCHROM\METHODS\M26.MET 

Sample ID : HF SPIKE b 

Accquired : Jun 03, 1997 11:47a21 

Channel A 

U. OS 

F 

0.0 7 1 

u 

o C 

0.0 6 r h 

i 1 

do 

0.0 5 e r 

i 

d 

V 0.0 4 e 

0 

1 

t 0.0 3 

s 

0.0 2 

0.0 1 

0.0 0 

-0 0 , 

. 10 

5 10 15 20 

Minutes 

Peak Name Ret. Time Area 

Fluoride 2.10 67914 

Chloride 2.84 6084 

j,,fj 
Instrument: "Clyde" Column: Hamilton PRP-X100 250x4.6 mm 

Eluent: 4mM Phthalic Acid pH 3.6; Flow @ 2 mis/min; 10 ul Inj Vol 

Conductivity Detection Gain 0.4 }:S/cm 40 C 

File : C:\EZCHROM\CHROM\52197.026 

Method : C:\EZCHtOM\METHODS\M26.MET 

Sample ID : Audit (100 ppm) b 

Acquired : Jun 03, 1997 11:33:27 

Channel A 

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Peak Name Ret. Time Area 

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Fluoride 2.12 167573 

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ANALYTICAL TESTING CONSULTANTS, INC 

KANNAPOLIS, N.C. G=0=GIA 

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ni BAROMETER #i CAL/BRATION 

~ DATE STATION PRESSURE BAROMETER READING ADJUSTMENT INITIALS 

05/24/96 29.77 29.58 0.19 JW 

06/10/96 29.86 30.03 0.17 KP 

-.-, 07/15/96 29.97 29.91 0.06 SM 

08/12/96 29.86 29.82 0.04 JW 

09/17/96 30.07 30:04 0.03 KP 

10/04/96 29.77 29.84 0.07 KP 

~+ 11 /08/96 29.61 . 29.75 0.14 KP 

12/02/96 30.02 29.99 0.03 KP 

01 /06/97 29.75 29.54 0.21 J W 

02110/97 29.77 29.69 0.08 CR 

~ 03/19/97 29.78 29.82 0.04 SM 

04/21/97 29.66 29.60 0.06 SM 

05/05/97 29.84 29.83 0.01 _ SM 

06/06/97 29.45 29.32 0.13 - DA 

BAROMETER #2 CALlBRATION 

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" DATE STATION PRESSURE ;. BAROMETER READING ADJUSTMENT . INITIALS 

05/24/96 29.77 29.79 0.02 JW 

06/10/96 29.86 29.91 0.05 KP 

07/15/96 29.97 29.96 0.01 SM 

08/12/96 29.86 29.89 0.03 JW 

09/17/96 30.07 29.88 0.19 KP 

~ 10/04/96 29.77 29.81 0.04 KP 

11 /08/96 29.61 29.64 0.03 KP 

12/02/96 30.02 30.11 0.09 KP 

01/06/97 29.75 29.18 0.57 JW 

02/10/97 29.77 29.81 0.04 CR 

03/19/97 29.78 29.56 0.22 SM 

04/21 /97 29.66 29.68 0.02 S M 

05/05/97 29.84 29.95 0.11 SM 

06/06/97 29.45 29.61 0.16 DA 

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PRIMARY VOST MODULE CALIBRATION CALCULATION 

DATE 12111196 

P BAR 29.81 

MODULE ID VosT #2 REFERENCE METER-WET TEST METER 

BY - POOLE 

K Run • Vrt~ : . . Vrt ,. Tm ,~ Trf . Time Sp Y: Run ~ • ,. . .. ._ ..: net !C3 net tt3 : : a ;w av .:' .` tn. H20 Avera e::' 

one 0.1229 0.1210 67 63 10 1.80 0.973 

two 0.1270 0.1210 67 63 10 1'80 0.941 

three 0.1272 0.1200 67 63 10 ' 1.80 0.932 0.949 

four 0.2652 0.2740 67 63 10 2.40 1.019 

five 0.2934 0.2700 66 63 10 2.40 0.910 

six 0.2747 0.2680 67 64 10 2.40 0.964 0.964 

seven 0.4182 0.4130 67 64 10 3.30 0.974 

eight 0.4165 0.4060 67 64 10 3.30 0.961 

nine 0.4409 0.4310 67 64 10 3.30 0.964 0.966 

Three run Average 0.960 

LEGEND 

Vm= volume of sampling meter 

Vrf= volume of reference meter 

Tm= temperature of sampling meter 

TrF= temperature of reference meter 

Sp= static pressure 

Y= calibration factor 

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NOZZLE CALIBRATION DATA FORM 

DATE 03/13/97 

CALIBRATED BY WELCH 

NOZZLE NOZZLE DIAMETER' DIAMETER AVERAGE 

I.D. D1 

D2 ::.. D3 DIFF."' DIA.... 

NO: (iNCHES) INCHES) (INCHES) INCHES) (INCHES) 

50 0.305 0.305 0.305 0.000 0.305 

51 0.312 0.310 0.312 0.002 0.311 

53 0.320 0.319 0.322 0.002 0.320 

54 0.306 0.307 0.308 0.002 0.307 

55 0.335 0.336 0.336 0.001 0.336 

56 0.312 0.313 0.313 0.001 0.313 

57 0.305 0.307 0.308 0.003 0.307 

58 0.315 0.315 0.317 0.002 0.316 

59 0.305 0.305 0.306 0.001 0.305 

where: 

*= THREE DIFFERENT NOZZLE DIAMETERS; EACH DIAMETER MUST BE 

WITHIN 0.001 iNCHES ~ 

= MAXIMUM DIFFERENCE BETWEEN ANY TWO DIAMETERS, IN. 

DIAMETER DIFFERENCE MUST BE LESS THAN OR EOUAL TO 0.004 INCHES 

*** = AVERAGE OF THREE DIAMETERS 

Li 

u 

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0.5 4.07 4.27 60 90 10 

1 5.73 5.98 63 87 .10 

1.5 6.85 7.2 62 89 10 

2 7.8 8.18 62 90 10 

3 9.39 9.91 62 90 10 

1.59 1.007 

1.63 1.000 

1.70 0.997 

1.74 1.000 

1.81 0.991 

1.69 0.999 

PRIMARY MODULE CALIBRATION CALCULATION 

DATE 01/28t97 

P BAR 29.6 

MODULE ID ATC 4 

BY Raltz 

JORIFICE Vw .,,.Vd TW Td TIME DH@ Y 

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POST TEST MODULE CALiBRAT/ON CALCULATION 

DATE 5/28J97 

P BAR 29.85 

MODULE ID ATC 4 

BY MEADOWS 

ORiF10E Vw ' Vd ., Tw Td TiME D H@ Y 

1.00 5.74 5.84 74 85 10 1.69 1.001 

1.00 5.74 5.84 74 85 10 1.69 1.001 

1.00 5.73 5.85 74 86 10 1.69 0.999 

1.69 1.000 

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PRIMARY VOST MODULE CALIBRATION CALCULATION 

DATE 12/11/96 

P BAR 29.81 ' 

MODULE ID - VOST 81 REFERENCE METER-WET TEST METER 

BY POOLE 

Run +1 Vm Vrf Tm Trf Ttm• Sp Y.. Run 

net tt3 net tt3 avg avg In. N20 Avera • 

56 10 1.00 0.923 

56 10 11.00 0.925 

58 10 *1 1.00 0.943 0.930 

58 10 1.40 0.945 

59 10 1.40 0.923 

60 10 1.40 0.924 0.931 

60 10 1.80 0.940 

60 10 1.80 0.912 

60 10 1.80 0.912 0.921 

Three run Average Q,928 

one 0.1570 0.1500 73 

two 0.1614 0.1550 74 

three 0.1555 0.1520 76 

four 0.4145 0.4070 76 

five 0.4188 0.4020 78 

six 0.4159 0.3990 78 

seven 0.5526 0.5410 79 

eight 0.5524 0.5270 82 

nine 0.5665 0.5410 82 

LEGEND 

Vm= volume of sampling meter 

Vrf= volume of reference meter 

Tm= temperature of sampling meter 

Trf= temperature of reference meter 

Sp= static pressure 

Y= calibration factor 

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PRIMARY VOST MODULE CALIBRATION CALCULATION 

DATE 12J11f98 

P BAR 29.81 . 

MODULE ID - VOST /3 REFERENCE METER-WET TEST METER 

BY POOLE 

Run t Vm V~! Tm ... T~t Ttme :: „. $p : Y Run 

,.. 

net ft3. ,. . net fC3..: q 

... e: . 

one 0.1488 0.1522 75 65 10 1.00 1.001 

two 0.1493 0.1528 75 65 10 1.00 1.002 

three 0.1492 0.1522 76 65 10 1.00 0.997 1.000 

four 0.3900 0.3999 77 66 10 1.40 1.001 

five 0.3904 0.4003 77 66 10 1.40 1.001 

six 0.3894 0.3990 - 77 67 10 1.40 1.002 1.001 

seven 0.5221 0.5341 78 67 10 1.80 0.998 

eight 0.5228 0.5341 77 67 10 1.80 0.998 

nine 0.5234 0.5344 77 68 10 1.80 0.999 0.998 

Three run Average 1:000 

LEGEND 

Vm= volume of sampling meter 

Vrf= volume of reference meter 

Tm= temperature of sampling meter 

Trf= temperature of reference meter 

Sp= static pressure 

Y= calibration factor 

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POSTTEST VOST MODULE CALIBRATION CALCULATION 

DATE 6119H7 

P BAR 29.94 ~ 

MODULE ID vosT +ra REFERENCE METER-WET TEST METER 

BY ALBRIGHT 

Runt Ym: ;:.;:.:.. : Vrr:.:::::r::::':.'::<;;Tm ::.::::;:::<:;. :.Trt. ..:::::..Tlms::> :::.:..:.::::;>::::<.: :::i:;:::::::.:.;::.: :; ...: :..> .:. Run >.,. : .:.:.: : . ..... .: ... :. .:.. . .. ..: ::.::::;<.:..>:. :.. ;:..:;: .:.:..::;:::: .::.> :. ..:.. .:... ;..<.. <:. . : ... ..:::.::. :.. .. 

~ net ro.;::::::.::':'.:. net ro . .,.:: . ,. . . ,:. :: >; :;::!:;`.:::;:;: a, ► «::; :::h~ : H2O:; : :::;:':;<;<;;'<,';.<::<':: :::: . :'.`'' Avera 

one 0.1478 0.1489 65 

two 0.1493 0.1504 65 

three 0.1493 0.1495 65 

LEGEND 

Vm= volume of sampling meter 

Vrf= volume of reference meter 

Tm= temperature of sampling meter 

Trf= temperature of reference meter 

Sp= static pressure 

Y= calibration factor 

63 10 1.00 1.001 

63 10 1.00 1.001 

64 10 1.00 0.997 1.000 

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POSTTEST VOST MODULE CALIBRATION CALCULATION 

DATE 6116197 

P BAR 29.94 

MODULE ID vosT.1 REFERENCE METER-WET TEST METER 

BY ALBRIGHT 

Run Vm Vrf Tm Trf Time Sp Y. Run 

net ff3 : net !tl avg avg ln. H20 Avera e 

one 0.1566 0.1465 68 

two 0.1569 0.1466 68 

three 0.1570 0.1466 69 

LEGEND ° ., 

Vm= volume of sampling meter 

Vrf= volume of reference meter 

Tm= temperature of sampling meter 

Trf= temperature of reference meter 

Sp= static pressure 

Y= calibration factor 

65 10 1.00 0.928 

66 1 Q 1.00 0.929 

66 10 1.00 0.926 0.928 

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POSTTEST VOST MODULE CALIBRATION CALCULATION 

DATE 6119/97 

P BAR 28.94 . 

MODULE ID VosT #2 REFERENCE METER-WET TEST METER 

BY ALBRIGFIT 

Run # Vm Vii Tm Trt;. =;,:..::.: T(me :.:.: :` :';: 5 Y: . ... Run 

,.::. . p ...:..:::. :.:' . net ft3 net tt3 : . . :':::: .. av : :..: : .;;: . av :::°:: ':: : ; .:: ;:: ::' . In. H20 .:: :: :. . .. Avera 

one 0.1155 0.1120 69 

two 0.1157 0.1120 69 

three 0.1159 0.1124 70 

LEGEND:,: :. ;,; 

Vm= volume of sampling meter 

Vrf= volume of reference meter 

Tm= temperature of sampling meter 

Trf= temperature of reference meter 

Sp= static pressure 

66 10 1.50 0.961 

66 10 1.50 0.959 

66 10 1.50 0.959 0.960 

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