**Company: Did you have 4 test runs?** 

**Plant:** If yes, Highlight Columns F and H, and right-click and select "Unhide". **Unit:** You will need to adjust the formulas in the Average Column for the runs you want to use.

**1 2**  **3 Av** **erage** Normal Normal Normal P May need to fix row height if text too long. 6/15/2011 6/15/2011 6/16/2011 13:32 16:34 9:32 15:16 18:14 11:14
1.04E-02 6.05E-03 7.04E-03 7.84E-03 P 9.41E-03 5.35E-03 6.37E-03 7.04E-03 P
1.84E-03 3.09E-03 4.57E-03 3.17E-03 1.66E-03 2.73E-03 4.14E-03 2.84E-03
2.46E-03 1.85E-03 1.17E-03 1.83E-03 P 2.21E-03 1.64E-03 1.06E-03 1.64E-03
1.23E-02 1.24E-02 3.40E-02 1.95E-02 P May need to hide rows if one fraction only

. 1.11E-02 1.09E-02 3.08E-02 1.76E-02 P
2.70E-02 2.33E-02 4.68E-02 3.24E-02 2.44E-02 2.06E-02 4.23E-02 2.91E-02
145.5 145.3 145.1 145.3 29.224 29.196 29.990 29.470 20.6 21.9 22.5 21.7 29.51 29.42 29.54 Average Flue Pressure, in. Hg Flue Gas Moisture, percent by volume **Total Hexavalent Chromium Emissions** mg/dscm lb/hr **Stack Parameters:** Average Gas Temperature, °F Average Gas Velocity, ft/sec mg/dscm lb/hr **M0 061-Backhalf Emissions**  mg/dscm lb/hr **M0 061-KOH Emissions**  lb/hr **M0 061-Rinse Cr Emissions**  mg/dscm lb/hr mg/dscm **HEXA VA** **LENT CHROMIUM (CR 6+) TEST RESULTS SUMMA RY** 

Motiva Enterprises LLC Norco Refinery RCCU Stack

**Test Run Number** Source Condition Date Start Time End Time **M0 061-Filter Emissions** 29.52 29.43 29.55 17.1 16.4 17.3 16.9 1.4 1.4 1.6 1.5 30.792 30.680 30.832 57.503 57.181 60.216 97.4 98.9 101.6 Isokinetic Variance Barometric Pressure, in. Hg Average %CO2by

volume, dry

basis Average %O2by

volume, dry

basis Dry Molecular Wt. of Gas, lb/lb-mole Gas Sample Volume, dscfIf yes, Highlight Columns F and H, and right-click and select "Unhide". You will need to adjust the formulas in the Average Column for the runs you want to use.

May need to fix row height if text too long.

May need to hide rows if one fraction only

.

### Norco Refinery **RCCU Stack Test 1 (13:40-16:58)**  **6/16/11**

**Sample Results**  **Concentration Emissions Rate**  **Parameter (ug)**  **(ug/dsM 3** **) (lbs/hr)**  **gr/dscf gr/acf**  **Comment** Antimony < 11.80 < 3.40 < 3.26E-03 < 1.48E-06 < 1.00E-06 DLL Arsenic < 1.20 < 0.35 < 3.31E-04 < 1.51E-07 < 1.02E-07 BDL Beryllium < 0.30 < 0.09 < 8.28E-05 < 3.77E-08 < 2.54E-08 BDL Cadmium < 0.30 < 0.09 < 8.28E-05 < 3.77E-08 < 2.54E-08 BDL Chromium 3.10 0.89 8.56E-04 3.90E-07 2.63E-07 ADL Cobalt 2.84 0.82 7.83E-04 3.57E-07 2.41E-07 ADL Lead < 0.60 < 0.17 < 1.66E-04 < 7.55E-08 < 5.09E-08 BDL Manganese 14.44 4.16 3.98E-03 1.82E-06 1.22E-06 ADL Nickel 47.79 13.76 1.32E-02 6.01E-06 4.05E-06 ADL Selenium < 4.00 < 1.15 < 1.10E-03 < 5.03E-07 < 3.39E-07 DLL

**Test Support Data** Sample Volume (Vmstd)

.................................................................................................................................................................... 122.665 Volumetric Flowrate (acfm)

.................................................................................................................................................................... 379,651Volumetric Flowrate (dscfm)

.................................................................................................................................................................... 255,913 %O2

.................................................................................................................................................................... 1.6 %CO2

.................................................................................................................................................................... 17.3

### Norco Refinery **RCCU Stack Test 2 (09:20-12:41)**  **6/17/11**

**Sample Results**  **Concentration Emissions Rate**  **Parameter (ug)**  **(ug/dsM 3** **) (lbs/hr)**  **gr/dscf gr/acf**  **Comment** Antimony < 8.13 < 2.37 < 2.25E-03 < 1.04E-06 < 6.98E-07 DLL Arsenic < 1.20 < 0.35 < 3.32E-04 < 1.53E-07 < 1.03E-07 BDL Beryllium < 0.30 < 0.09 < 8.31E-05 < 3.82E-08 < 2.58E-08 BDL Cadmium < 0.30 < 0.09 < 8.31E-05 < 3.82E-08 < 2.58E-08 BDL Chromium 1.97 0.57 5.46E-04 2.51E-07 1.69E-07 ADL Cobalt 1.85 0.54 5.12E-04 2.36E-07 1.59E-07 ADL Lead < 0.60 < 0.17 < 1.66E-04 < 7.64E-08 < 5.15E-08 BDL Manganese 22.24 6.49 6.16E-03 2.83E-06 1.91E-06 ADL Nickel 29.78 8.68 8.25E-03 3.79E-06 2.56E-06 ADL Selenium < 3.90 < 1.14 < 1.08E-03 < 4.97E-07 < 3.35E-07 DLL

**Test Support Data** Sample Volume (Vmstd)

.................................................................................................................................................................... 121.13 Volumetric Flowrate (acfm)

.................................................................................................................................................................... 376,405Volumetric Flowrate (dscfm)

.................................................................................................................................................................... 253,643 %O2

.................................................................................................................................................................... 1.6 %CO2

.................................................................................................................................................................... 17.3

### Norco Refinery **RCCU Stack Test 3 (13:50-17:11)**  **6/17/11**

**Sample Results**  **Concentration Emissions Rate**  **Parameter (ug)**  **(ug/dsM 3** **) (lbs/hr)**  **gr/dscf gr/acf**  **Comment** Antimony < 17.70 < 5.20 < 4.90E-03 < 2.27E-06 < 1.53E-06 DLL Arsenic < 1.20 < 0.35 < 3.33E-04 < 1.54E-07 < 1.04E-07 BDL Beryllium < 0.30 < 0.09 < 8.31E-05 < 3.85E-08 < 2.59E-08 BDL Cadmium < 0.30 < 0.09 < 8.31E-05 < 3.85E-08 < 2.59E-08 BDL Chromium 2.85 0.84 7.90E-04 3.66E-07 2.46E-07 ADL Cobalt 4.11 1.21 1.14E-03 5.28E-07 3.55E-07 ADL Lead < 0.60 < 0.18 < 1.66E-04 < 7.71E-08 < 5.19E-08 BDL Manganese 4.97 1.46 1.38E-03 6.38E-07 4.30E-07 ADL Nickel 46.57 13.69 1.29E-02 5.98E-06 4.03E-06 ADL Selenium < 3.20 < 0.94 < 8.87E-04 < 4.11E-07 < 2.77E-07 DLL

**Test Support Data** Sample Volume (Vmstd)

.................................................................................................................................................................... 120.164 Volumetric Flowrate (acfm)

.................................................................................................................................................................... 374,034Volumetric Flowrate (dscfm)

.................................................................................................................................................................... 251,755 %O2

.................................................................................................................................................................... 1.6 %CO2

.................................................................................................................................................................... 17.3

### Concentration **Emissions Rate**

**Parameter** Antimony < 3.66 < 3.47E-03 < 1.60E-06 < 1.08E-06 Arsenic < 0.35 < 3.32E-04 < 1.53E-07 < 1.03E-07 Beryllium < 0.09 < 8.30E-05 < 3.82E-08 < 2.57E-08 Cadmium < 0.09 < 8.30E-05 < 3.82E-08 < 2.57E-08 Chromium 0.77 7.30E-04 3.36E-07 2.26E-07 Cobalt 0.85 8.11E-04 3.73E-07 2.52E-07 Lead < 0.17 < 1.66E-04 < 7.63E-08 < 5.14E-08 Manganese 4.03 3.84E-03 1.76E-06 1.19E-06 Nickel 12.04 1.14E-02 5.26E-06 3.54E-06 Selenium < 1.08 < 1.02E-03 < 4.70E-07 < 3.17E-07

Volumetric Flowrate (acfm)

.................................................................................. 376,697 Volumetric Flowrate (dscfm)

..................................................................................................................................... 253,770 %O2

..................................................................................................................................... 1.6 %CO2

..................................................................................................................................... 17.3 **Test Support Data (mg/dsM** **3**

### ) **(lbs/hr) gr/dscf**  **gr/acf** 

### Motiva Enterprises LLC **Norco Refinery RCCU Stack**  **Av erage Results**  **June 16 and 17, 2011 Company:** 

**Plant: Unit:** 
**1 2**  **3 Av** **erage** Normal Normal Normal 6/16/2011 6/17/2011 6/17/2011 13:40 9:20 13:50 16:58 12:41 17:11 379,651 376,405 374,034 376,697 255,913 253,643 251,755 253,770 144.6 144.8 144.9 144.8 31.471 31.201 31.005 31.226 21.7 21.9 21.9 21.8 Flue Gas Moisture, percent by volume **Stack Parameters:** M2 Gas Volumetric Flow Rate, acfm M2 Gas Volumetric Flow Rate, dscfm Average Gas Temperature, °F Average Gas Velocity, ft/sec Date Start Time End Time Source Condition **ME TA** **LS TEST RESULTS SUMMA RY"** 

Motiva Enterprises LLC Norco Refinery RCCU Stack
**Test Run Number**

21.7 21.9 21.9 21.8 29.51 29.57 29.54 29.52 29.58 29.55 17.3 17.3 17.3 17.3 1.6 1.6 1.6 1.6 30.832 30.832 30.832 122.665 121.130 120.164 97.7 97.3 97.3 Isokinetic Variance Average Flue Pressure, in. Hg Barometric Pressure, in. Hg Average %CO2by

volume, dry

basis Average %O2by

volume, dry

basis Dry Molecular Wt. of Gas, lb/lb-mole Gas Sample Volume, dscf volume**SEM IVOLA**  **TILE TEST RESULTS SUMMA RY**  **Page 1 of 1** Company: Plant: Unit: Location:
Test Run Number 1 2 3 Average Source Condition Normal Normal Normal Date 6/20/2011 6/20/2011 6/21/2011 Start Time 12:20 16:50 10:00 End Time 15:40 20:17 13:43 Sample Duration (min): 192.0 192.0 192.0 192.0 Average Gas Temp (oF): 144.3 144.1 144.5 144.3 Average Gas Temp (oC): 62.4 62.3 62.5 62.4 Fractional Gas Moisture Content: 0.22 0.22 0.22 0.22 Gas CO2Content (%vol): 17.7 17.7 17.5 17.6 Gas O2Content (%vol): 1.6 1.6 1.5 1.6 Excess Air (%): 8.1 8.1 7.5 7.9 

### Lines denoted by yellow should always be left visible Gas Wet MW(lb/lbmole-mole): 28.06 28.05 28.03 28.05 

### Lines denoted by purple should be visible if measured Average Gas Vel (ft/sec): 31.69 33.15 32.23 32.36 Average Gas Vel (m/sec): 9.66 10.10 9.82 9.86 Measured Volumetric Flow Rate Q (actual ft3/min): 382,332 399,933 388,859 390,375 Q (actual m3/min): 10,827 11,325 11,011 11,054 Qstd(std ft3/min): 329,103 343,659 333,732 335,498 Qstd(Nm3/min): 8,682 9,081 8,830 8,864 Qstd(dry)(dry

std ft3/min): 256,772 267,946 260,341 261,686 Qstd(dry)(dry

Nm3/min): 6,774 7,081 6,888 6,914 Sample Volume(dry

std ft3): 115.828 118.473 115.407 116.569 Sample Volume (Nm3): 3.056 3.109 3.050 3.072 Isokinetic Variance 96.3 94.4 94.6 95.1

Motiva Enterprises LLC Norco Refinery RCCU 

# NEVER PUT EQUA **TIONS IN THE CELLS IN THIS TA** **BLE. IF A** **CHA NGE IS NEEDED,**  **CONSULT WITH THE TECHNICA** **L DIRECTOR.** Stack

### Lines denoted by yellow should always be left visible Lines denoted by purple should be visible if measured 

# NEVER PUT EQUA

**TIONS IN THE CELLS IN THIS TA** **BLE. IF A** **CHA NGE IS NEEDED,**  **CONSULT WITH THE TECHNICA** **L DIRECTOR.**Analy tes N-Nitrosodimethylamine 3.86 ND < 1.18 < 1.13E-03 3.85 ND < 1.17 < 1.15E-03 3.86 Pyridine 52.60 ND < 16.04 < 1.54E-02 52.60 ND < 16.04 < 1.57E-02 52.60 Phenol (CCC) 3.91 J 1.19 1.15E-03 3.25 ND < 0.99 < 9.72E-04 3.25 Aniline 3.47 ND < 1.06 < 1.02E-03 3.47 ND < 1.06 < 1.04E-03 3.47 bis(2-Chloroethyl)ether 3.94 ND < 1.20 < 1.16E-03 3.94 ND < 1.20 < 1.18E-03 3.94 2-Chloropenol 3.12 ND < 0.95 < 9.15E-04 3.12 ND < 0.95 < 9.33E-04 3.12 1,3-Dichlorobenzene 2.79 ND < 0.85 < 8.18E-04 2.79 ND < 0.85 < 8.35E-04 2.79 1,4-Dichlorobenzene (CCC) 2.64 ND < 0.80 < 7.74E-04 2.64 ND < 0.80 < 7.90E-04 2.64 Benzyl alcohol 3.50 ND < 1.07 < 1.03E-03 3.50 ND < 1.07 < 1.05E-03 3.50 1,2-Dichlorobenzene 2.79 ND < 0.85 < 8.18E-04 2.79 ND < 0.85 < 8.35E-04 2.79 2-Methylphenol 3.39 ND < 1.03 < 9.94E-04 3.39 ND < 1.03 < 1.01E-03 3.39 bis(2-Chloroisopropyl) ether 4.91 ND < 1.50 < 1.44E-03 4.91 ND < 1.50 < 1.47E-03 4.91 3/4-Methylphenol 2.95 ND < 0.90 < 8.65E-04 2.95 ND < 0.90 < 8.83E-04 2.95 N-Nitroso-di-n-propylamine (SPCC) 4.16 ND < 1.27 < 1.22E-03 4.16 ND < 1.27 < 1.24E-03 4.16 o-Toluidine 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 Hexachloroethane 3.16 ND < 0.96 < 9.27E-04 3.16 ND < 0.96 < 9.45E-04 3.16 Nitrobenzene 4.08 ND < 1.24 < 1.20E-03 4.08 ND < 1.24 < 1.22E-03 4.08 Isophorone 3.74 ND < 1.14 < 1.10E-03 3.74 ND < 1.14 < 1.12E-03 3.74 **(lb/hr) (ug)**  **(ug) (ug/dscm)**  **(lb/hr) (ug)**  **(ug/dscm) Emissions**  

### SEMIVOLA

**TILE A ND PA** **H EMISSIONS SUMMA RY**  **Motiva Enterprises LLC Norco Refinery**  **RCCU STA CK** 
**Run 1 Run 2**  **Sample Catch Conc.**  **Emissions Sample Catch**  **Conc. Sample Catch** 2,4-Dimethylphenol 3.64 ND < 1.11 < 1.07E-03 3.64 ND < 1.11 < 1.09E-03 3.64

2-Nitrophenol (CCC) 3.35 ND < 1.02 < 9.82E-04 3.35 ND < 1.02 < 1.00E-03 3.35 Benzoic acid 57.80 ND < 17.62 < 1.69E-02 57.80 ND < 17.62 < 1.73E-02 57.80 bis(2-Chloroethoxy)methane 3.66 ND < 1.12 < 1.07E-03 3.66 ND < 1.12 < 1.09E-03 3.66 2,4-Dichlorophenol (CCC) 3.26 ND < 0.99 < 9.56E-04 3.26 ND < 0.99 < 9.75E-04 3.26 a,a-Dimethylphenethylamine 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 1,2,4-Trichlorobenzene 3.09 ND < 0.94 < 9.06E-04 3.09 ND < 0.94 < 9.24E-04 3.09 4-Chloroaniline 4.24 ND < 1.29 < 1.24E-03 4.24 ND < 1.29 < 1.27E-03 4.24 Hexachlorobutadiene (CCC) 3.05 ND < 0.93 < 8.94E-04 3.05 ND < 0.93 < 9.12E-04 3.05 Quinoline 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 1,4-Phenylenediamine 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 4-Chloro-3 methylphenol (CCC) 3.31 ND < 1.01 < 9.71E-04 3.31 ND < 1.01 < 9.90E-04 3.31 Hexachlorocyclopentadiene (SPCC) 40.60 ND < 12.38 < 1.19E-02 40.60 ND < 12.38 < 1.21E-02 40.60 2,4,6-Trichlorophenol (CCC) 3.69 ND < 1.13 < 1.08E-03 3.69 ND < 1.13 < 1.10E-03 3.69 2,4,5-Trichlorophenol 2.70 ND < 0.82 < 7.92E-04 2.70 ND < 0.82 < 8.08E-04 2.70 Biphenyl 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 2-Chloronaphthalene 3.26 ND < 0.99 < 9.56E-04 3.26 ND < 0.99 < 9.75E-04 3.26 2-Nitroaniline 4.83 ND < 1.47 < 1.42E-03 4.83 ND < 1.47 < 1.44E-03 4.83 1,4-Dinitrobenzene 3.36 ND < 1.02 < 9.85E-04 3.36 ND < 1.02 < 1.01E-03 3.36 Dimethylphthalate 4.05 ND < 1.23 < 1.19E-03 4.05 ND < 1.23 < 1.21E-03 4.05 1,3-Dinitrobenzene 4.09 ND < 1.25 < 1.20E-03 4.09 ND < 1.25 < 1.22E-03 4.09 2,6-Dinitrotoluene 3.88 ND < 1.18 < 1.14E-03 3.88 ND < 1.18 < 1.16E-03 3.88 1,2-Dinitrobenzene 3.89 ND < 1.19 < 1.14E-03 3.89 ND < 1.19 < 1.16E-03 3.89 3-Nitroaniline 4.08 ND < 1.24 < 1.20E-03 4.08 ND < 1.24 < 1.22E-03 4.08 2,4-Dinitrophenol (SPCC) 25.30 ND < 7.71 < 7.42E-03 25.30 ND < 7.71 < 7.57E-03 25.30 4-Nitrophenol (SPCC) 28.90 ND < 8.81 < 8.47E-03 28.90 ND < 8.81 < 8.65E-03 28.902,4-Dinitrotoluene 4.02 ND < 1.23 < 1.18E-03 4.02 ND < 1.23 < 1.20E-03 4.02

Dibenzofuran 3.44 ND < 1.05 < 1.01E-03 3.44 ND < 1.05 < 1.03E-03 3.44 2,3,5,6-Tetrachlorophenol 3.80 ND < 1.16 < 1.11E-03 3.80 ND < 1.16 < 1.14E-03 3.80 2,3,4,6-Tetrachlorophenol 3.50 ND < 1.07 < 1.03E-03 3.50 ND < 1.07 < 1.05E-03 3.50 Diethlyphthalate 5.10 ND < 1.55 < 1.50E-03 5.10 ND < 1.55 < 1.53E-03 5.10 4-Chlorophenyl-phenylether 3.77 ND < 1.15 < 1.11E-03 3.77 ND < 1.15 < 1.13E-03 3.77 4-Nitroaniline 4.72 ND < 1.44 < 1.38E-03 4.72 ND < 1.44 < 1.41E-03 4.72 4,6-Dinitro2-methylphenol 25.80 ND < 7.87 < 7.57E-03 25.80 ND < 7.87 < 7.72E-03 25.80 N-Nitrosodiphenylamine (CCC) 3.58 ND < 1.09 < 1.05E-03 3.58 ND < 1.09 < 1.07E-03 3.58 Azobenzene 4.96 ND < 1.51 < 1.45E-03 4.96 ND < 1.51 < 1.48E-03 4.96 4-Bromophenyl-phenylether 3.35 ND < 1.02 < 9.82E-04 3.35 ND < 1.02 < 1.00E-03 3.35 Hexachlorobenzene 2.73 ND < 0.83 < 8.01E-04 2.73 ND < 0.83 < 8.17E-04 2.73 Pentachlorophenol (CCC) 2.83 ND < 0.86 < 8.30E-04 2.83 ND < 0.86 < 8.47E-04 2.83 Carbazole 3.53 ND < 1.08 < 1.04E-03 3.53 ND < 1.08 < 1.06E-03 3.53 Di-n-butylphthalate 5.19 ND < 1.58 < 1.52E-03 5.19 ND < 1.58 < 1.55E-03 5.19 Benzidine 114.00 ND < 34.76 < 3.34E-02 114.00 ND < 34.76 < 3.41E-02 114.00 4-Dimethylaminoazobenzene 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 Butylbenzylphthalate 4.05 ND < 1.23 < 1.19E-03 4.05 ND < 1.23 < 1.21E-03 4.05 3,3-Dimethylbenzidine 53.90 ND < 16.43 < 1.58E-02 53.90 ND < 16.43 < 1.61E-02 53.90 bis(2-Ethylhexyl)adipate 4.37 ND < 1.33 < 1.28E-03 4.37 ND < 1.33 < 1.31E-03 4.37 3,3-Dimethoxybenzidine 5.00 ND < 1.52 < 1.47E-03 5.00 ND < 1.52 < 1.50E-03 5.00 bis(2-Ethylhexyl)phthalate 8.71 ND < 2.66 < 2.55E-03 12.20 J 3.72 3.65E-03 8.71 3,3'-Dichlorobenzidine 46.80 ND < 14.27 < 1.37E-02 46.80 ND < 14.27 < 1.40E-02 46.80 Di-n-octylphthalate (CCC) 3.22 ND < 0.98 < 9.44E-04 3.22 ND < 0.98 < 9.63E-04 3.22
Naphthalene 1.30 0.397 3.82E-04 1.29 0.393 3.86E-04 0.682-Methylnaphthalene 0.11 0.034 3.25E-05 0.16 0.050 4.88E-05 0.05

1-Methylnaphthalene 0.06 0.018 1.73E-05 0.08 0.023 2.27E-05 0.05 Acenaphthylene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Acenaphthene (CCC) 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Fluorene 0.05 0.016 1.52E-05 0.08 0.024 2.32E-05 0.05 Phenanthrene 0.17 0.051 4.87E-05 0.15 0.044 4.34E-05 0.05 Anthracene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Fluoranthene (CCC) 0.18 0.055 5.28E-05 0.11 0.034 3.38E-05 0.09 Pyrene 0.42 0.128 1.23E-04 0.24 0.073 7.15E-05 0.22 Benzo(b)fluoranthene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Chrysene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 7,12-Dimethylbenz(a)anthracene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Benzo(b)fluoranthene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Benzo(k)fluoranthene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Benzo(e)pyrene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Benzo(a)pyrene (CCC) 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Perylene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 3-Methylcholanthrene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Indeno(1,2,3-cd)pyrene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Dibenz(a,h)anthracene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Benzo(g,h,i)perylene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Dibenzo(a,e)pyrene 0.05 ND < 0.015 < 1.47E-05 0.05 ND < 0.015 < 1.50E-05 0.05 Run 1 Run 2 **Sample volume (Vmstd, dscf)** 115.83 118.47 **Volumetric A ir Flow (DSCFM)**  256,772 267,946 **Av erage % CO** **2 by volume, dry**  17.70 17.70 **Av erage % O** **2 by volume, dry**  1.60 1.60ND < 1.18 < 1.15E-03 < 1.18 < 1.15E-03

ND < 16.04 < 1.57E-02 < 16.04 < 1.56E-02 ND < 0.99 < 9.70E-04 < 1.06 < 1.03E-03 ND < 1.06 < 1.04E-03 < 1.06 < 1.03E-03 ND < 1.20 < 1.18E-03 < 1.20 < 1.17E-03 ND < 0.95 < 9.31E-04 < 0.95 < 9.26E-04 ND < 0.85 < 8.33E-04 < 0.85 < 8.28E-04 ND < 0.80 < 7.88E-04 < 0.80 < 7.84E-04 ND < 1.07 < 1.04E-03 < 1.07 < 1.04E-03 ND < 0.85 < 8.33E-04 < 0.85 < 8.28E-04 ND < 1.03 < 1.01E-03 < 1.03 < 1.01E-03 ND < 1.50 < 1.47E-03 < 1.50 < 1.46E-03 ND < 0.90 < 8.80E-04 < 0.90 < 8.76E-04 ND < 1.27 < 1.24E-03 < 1.27 < 1.24E-03 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 0.96 < 9.43E-04 < 0.96 < 9.38E-04 ND < 1.24 < 1.22E-03 < 1.24 < 1.21E-03 ND < 1.14 < 1.12E-03 < 1.14 < 1.11E-03

**Conc. Emissions**  **Conc. Emissions**  **(ug/dscm) (lb/hr)**  **(ug/dscm) (lb/hr)**  **Run 3 Av** **erage Sample Catch** ND < 1.11 < 1.09E-03 < 1.11 < 1.08E-03

ND < 1.02 < 1.00E-03 < 1.02 < 9.95E-04 ND < 17.62 < 1.72E-02 < 17.62 < 1.72E-02 ND < 1.12 < 1.09E-03 < 1.12 < 1.09E-03 ND < 0.99 < 9.73E-04 < 0.99 < 9.68E-04 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 0.94 < 9.22E-04 < 0.94 < 9.18E-04 ND < 1.29 < 1.27E-03 < 1.29 < 1.26E-03 ND < 0.93 < 9.10E-04 < 0.93 < 9.06E-04 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 1.01 < 9.88E-04 < 1.01 < 9.83E-04 ND < 12.38 < 1.21E-02 < 12.38 < 1.21E-02 ND < 1.13 < 1.10E-03 < 1.13 < 1.10E-03 ND < 0.82 < 8.06E-04 < 0.82 < 8.02E-04 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 0.99 < 9.73E-04 < 0.99 < 9.68E-04 ND < 1.47 < 1.44E-03 < 1.47 < 1.43E-03 ND < 1.02 < 1.00E-03 < 1.02 < 9.98E-04 ND < 1.23 < 1.21E-03 < 1.23 < 1.20E-03 ND < 1.25 < 1.22E-03 < 1.25 < 1.21E-03 ND < 1.18 < 1.16E-03 < 1.18 < 1.15E-03 ND < 1.19 < 1.16E-03 < 1.19 < 1.16E-03 ND < 1.24 < 1.22E-03 < 1.24 < 1.21E-03 ND < 7.71 < 7.55E-03 < 7.71 < 7.51E-03 ND < 8.81 < 8.62E-03 < 8.81 < 8.58E-03ND < 1.23 < 1.20E-03 < 1.23 < 1.19E-03

ND < 1.05 < 1.03E-03 < 1.05 < 1.02E-03 ND < 1.16 < 1.13E-03 < 1.16 < 1.13E-03 ND < 1.07 < 1.04E-03 < 1.07 < 1.04E-03 ND < 1.55 < 1.52E-03 < 1.55 < 1.51E-03 ND < 1.15 < 1.12E-03 < 1.15 < 1.12E-03 ND < 1.44 < 1.41E-03 < 1.44 < 1.40E-03 ND < 7.87 < 7.70E-03 < 7.87 < 7.66E-03 ND < 1.09 < 1.07E-03 < 1.09 < 1.06E-03 ND < 1.51 < 1.48E-03 < 1.51 < 1.47E-03 ND < 1.02 < 1.00E-03 < 1.02 < 9.95E-04 ND < 0.83 < 8.15E-04 < 0.83 < 8.11E-04 ND < 0.86 < 8.44E-04 < 0.86 < 8.40E-04 ND < 1.08 < 1.05E-03 < 1.08 < 1.05E-03 ND < 1.58 < 1.55E-03 < 1.58 < 1.54E-03 ND < 34.76 < 3.40E-02 < 34.76 < 3.39E-02 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 1.23 < 1.21E-03 < 1.23 < 1.20E-03 ND < 16.43 < 1.61E-02 < 16.43 < 1.60E-02 ND < 1.33 < 1.30E-03 < 1.33 < 1.30E-03 ND < 1.52 < 1.49E-03 < 1.52 < 1.48E-03 ND < 2.66 < 2.60E-03 < 3.01 < 2.93E-03 ND < 14.27 < 1.40E-02 < 14.27 < 1.39E-02 ND < 0.98 < 9.61E-04 < 0.98 < 9.56E-04
0.209 2.04E-04 0.333 3.24E-040.016 1.54E-05 < 0.033 < 3.22E-05

ND < 0.015 < 1.49E-05 < 0.019 < 1.83E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.018 < 1.78E-05 0.016 1.61E-05 0.037 3.61E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 0.029 2.80E-05 0.039 3.82E-05 0.066 6.45E-05 0.089 8.65E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05 ND < 0.015 < 1.49E-05 < 0.015 < 1.48E-05

Run 3 115.41 260,341 17.50 1.50

# EPA **METHOD 308 DA**

**TA DETERMINA** 

**TION OF METHA NOL EMISSIONS FROM STA**  **TIONA RY SOURCES** 

**Test Date:** 6/20 and 6/21/2011 **Project: Number:** ZTSO0192 **Company:** Motiva Enterprises **Plant:** Norco **Test Location:** RCCU Stack

**Test Number:** 1 **Pressure, Barometric (Hg"):.........................** 29.48 **Pressure, Static (H 2** 

# O"):................................ **Pressure, Stack (Hg"):...................................** 29.48 **Initial Volume (liters):..................................** 8849.9 **Final Volume (liters):....................................** 8961.2 **Meter Temperature ( o** 

# F):............................... 95.5 **Meter Volume (dscM):....................................** 0.1043 **Meter Calibration (Y):...................................** 0.998 **Initial Wt. (grams or mls):.........................** 0.0

# Final Wt. (grams or mls):........................... 0.0 **Ave rage Delta H (** **H):..................................** 0.976 **Dry Standard Flow Rate (dscMm):..............**  6773.7

**Test Number:** 2 **Pressure, Barometric (Hg"):.........................** 29.43 **Pressure, Static (H 2** 

# O"):................................ **Pressure, Stack (Hg"):...................................** 29.43 **Initial Volume (liters):..................................** 8962.5 **Final Volume (liters):....................................** 9083.3 **Meter Temperature ( o** 

# F):............................... 0.0 **Meter Volume (dscM):....................................** 0.1365 **Meter Calibration (Y):...................................** 0.998 **Initial Wt. (grams or mls):.........................** 0.0 **Final Wt. (grams or mls):...........................** 0.0 **Ave rage Delta H (** **H):..................................** 1.024 **Dry Standard Flow Rate (dscMm):..............**  7018.0

**Test Number:** 3 **Pressure, Barometric (Hg"):.........................** 29.41

# Pressure, Static (H**2**

# O"):................................ **Pressure, Stack (Hg"):...................................** 29.41 **Initial Volume (liters):..................................** 9083.3 **Final Volume (liters):....................................** 9204.0 **Meter Temperature ( o** 

# F):............................... 0.0 **Meter Volume (dscM):....................................** 0.1363 **Meter Calibration (Y):...................................** 0.998 **Initial Wt. (grams or mls):.........................** 0.0 **Final Wt. (grams or mls):...........................** 0.0 **Ave rage Delta H (** **H):..................................** 1.036 **Dry Standard Flow Rate (dscMm):..............**  6888.0 **Ave rage Methanol lbs/hr:**  0.06 **Ave rage Methanol ppm:**  0.07 **Ave rage Methanol lbs/MMBtu:**  #VALUE! **Ave rage Flow** **Rate (dscfm)** 6893 Flowrate, moisture, O2 and CO2 values taken from M0010 train data sampled at the same time.

# EPA **METHOD 308 DA**

**TA** 

# g **DETERMINA**

**TION OF METHA NOL EMISSIONS FROM STA**  **TIONA RY SOURCES** 

**Condition:** Normal **Test Engineer:** E. Santibanez **Fuel Factor (Fd):** NA

**Time:** 1530-1730 **Carbon Dioxide Content (%):.................................** 17.7 **Oxygen Content (%):................................................** 1.6 **Nitrogen Content (%):..............................................** 80.70 **Methanol (mg)...........................................................** 0.0181 J **Water Vapor in Flue Gas (Bw s):...........................**  0.220 **Methanol (mg/m3):........................................................** 0.174J

# Methanol (lbs/hr):..................................................... 0.156J **Methanol (lbs/MMBtu):.............................................**#VALUE! J

**Time:** 1815-2015 **Carbon Dioxide Content (%):.................................** 17.70 **Oxygen Content (%):................................................** 1.60 **Nitrogen Content (%):..............................................** 80.70 **Methanol (mg)...........................................................** 0.00156J **Water Vapor in Flue Gas (Bw s):...........................**  0.220 **Methanol (mg/m3):........................................................** 0.0114J **Methanol (lbs/hr):.....................................................** 0.011 J **Methanol (lbs/MMBtu):.............................................**#VALUE! J

**Time:** 1020-1220 **Carbon Dioxide Content (%):.................................** 17.50

# Oxygen Content (%):................................................ 1.50 **Nitrogen Content (%):..............................................** 81.00 **Methanol (mg)...........................................................** 0.00180J **Water Vapor in Flue Gas (Bw s):...........................**  0.220 **Methanol (mg/m3):........................................................** 0.0132 J **Methanol (lbs/hr):.....................................................** 0.012 J **Methanol (lbs/MMBtu):.............................................**#VALUE! J

Flowrate, moisture, O2 and CO2 values taken from M0010 train data sampled at the same time.**ME THOD 5/202 PA** **RTICULA TE TEST RESULTS SUMMA** **RY** Company: Plant: Unit: Location:
Test Run Number 1 2 3 Average Source Condition Normal Normal Normal Date 6/16/2011 6/17/2011 6/17/2011 Start Time 13:40 9:20 14:10 End Time 16:20 12:01 16:48 Sample Duration (min): 144.0 144.0 144.0 144.0 Average Gas Temp (oF): 144.2 144.0 144.7 144.3 Fractional Gas Moisture Content: 0.21 0.18 0.22 0.20 Gas CO2Content (%vol): 17.3 17.1 17.0 17.1 Gas O2Content (%vol): 1.6 2.0 1.9 1.8 Gas Wet MW(lb/lbmole-mole): 28.11 28.52 27.99 28.21 

### Lines denoted by purple should be visible if measured Average Gas Vel (ft/sec): 31.41 31.15 30.91 31.16 Measured Volumetric Flow Rate Q (actual ft3/min): 378,977 375,778 372,882 375,879 Qstd(std ft3/min): 326,603 324,605 321,422 324,210 Qstd(dry)(dry

std ft3/min): 257,348 266,492 250,906 258,249 Fd(dscf/MMBtu): 8,710 8,710 8,710 8,710 Sample Volume(dry

std ft3): 88.427 88.607 86.618 87.884 PM Concentration (gr/dscf): Filterable 0.0096 0.0081 0.0118 0.0098 Aqueous Condensible: 0.0105 0.0090 0.0082 0.0092 Organic Condensible: 0.0012 0.0004 0.0001 0.0006 Total: 0.0213 0.0175 0.0201 0.0197 PM Concentration (mg/Nm3): Filterable: 23.6 20.2 29.1 24.3 Aqueous Condensible: 25.85 22.48 20.10 22.81 Organic Condensible: 2.910 0.948 0.345 1.401 Total: 52.3 43.6 49.5 48.5 PM Emission Rate (lb/hr based on measured volumetric flow rate):

Motiva Enterprises LLC Norco Refinery RCCU 

# NEVER PUT EQUA **TIONS IN THE CELLS IN THIS TA** **BLE. IF A** **CHA NGE IS NEEDED,**  **CONSULT WITH THE TECHNICA** **L DIRECTOR.** StackFilterable: 21.16 18.53 25.44 21.71

Aqueous Condensible: 23.21 20.65 17.59 20.48 Organic Condensible: 2.61 0.87 0.30 1.26 Total: 46.99 40.05 43.33 43.46 Isokinetic Variance 97.8 94.6 98.3 96.9

### Lines denoted by purple should be visible if measured 

# NEVER PUT EQUA

**TIONS IN THE CELLS IN THIS TA** **BLE. IF A** **CHA NGE IS NEEDED,**  **CONSULT WITH THE TECHNICA** **L DIRECTOR. PCDD/PCDF TEST RESULTS SUMMA** **RY Page 1 of 1** 

Company: Plant: Unit: Location:
Test Run Number 1 2 3 Average Source Condition Normal Normal Normal Date 6/15-16/2011 6/16/2011 6/16-17/2011 Start Time 21:55 2:45 0:43 End Time 0:44 6:17 0:34 Sample Duration (min): 192.0 192.0 192.0 192.0 Average Gas Temp (oF): 144.6 143.5 144.0 144.0 Fractional Gas Moisture Content: 0.22 0.22 0.22 0.22 Gas CO2Content (%vol): 16.9 17.3 17.1 17.1 Gas O2Content (%vol): 1.6 1.6 1.8 1.7 Gas Wet MW(lb/lbmole-mole): 27.94 28.07 28.03 28.02 

### Lines denoted by purple should be visible if measured Average Gas Vel (ft/sec): 30.96 31.34 31.85 31.38 Measured Volumetric Flow Rate Q (actual ft3/min): 373,453 378,059 384,212 378,575 Q (actual m3/min): 10,575 10,705 10,880 10,720 Qstd(std ft3/min): 320,662 325,840 330,241 325,581 Qstd(Nm3/min): 8,459 8,563 8,703 8,575 Qstd(dry)(dry

std ft3/min): 249,677 255,734 258,682 254,697 Qstd(dry)(dry

Nm3/min): 6,587 6,721 6,817 6,708 Isokinetic Variance 97.5 97.2 97.3 97.3

Motiva Enterprises LLC Norco Refinery RCCU 

# NEVER PUT EQUA **TIONS IN THE CELLS IN THIS TA** **BLE. IF A** **CHA NGE IS NEEDED,**  **CONSULT WITH THE TECHNICA** **L DIRECTOR.** Stack

### Lines denoted by purple should be visible if measured 

# NEVER PUT EQUA

**TIONS IN THE CELLS IN THIS TA** **BLE. IF A** **CHA NGE IS NEEDED,**  **CONSULT WITH THE TECHNICA** **L DIRECTOR. Sample**  **Catch Conc.**  **Emissions Sample**  **Catch Conc.**  **Emissions Sample**  **Catch Conc.**  **Emissions Conc.**  Analy tes **(pg) (ng/dscm)**  **(ng/dscm at 7% O** **2 )**  **(pg) (ng/dscm)**  **(ng/dscm at 7% O** **2 )**  **(pg) (ng/dscm)**  **(ng/dscm at 7% O** **2 )**  **(ng/dscm)** 2378-TCDD 1.1 3.41E-04 2.45E-04 1.1 3.34E-04 2.40E-04 1.1 3.30E-04 2.40E-04 3.35E-04 12378-PeCDD 1.1 3.41E-04 2.45E-04 1.1 3.34E-04 2.40E-04 1.0 3.00E-04 2.18E-04 3.25E-04 123478-HxCDD 1.2 3.72E-04 2.68E-04 1.2 3.64E-04 2.62E-04 1.1 3.30E-04 2.40E-04 3.55E-04 123678-HxCDD 1.2 3.72E-04 2.68E-04 1.2 3.64E-04 2.62E-04 1.1 3.30E-04 2.40E-04 3.55E-04 123789-HxCDD 1.1 3.41E-04 2.45E-04 1.1 3.34E-04 2.40E-04 1.0 3.00E-04 2.18E-04 3.25E-04 1234678-HpCDD 1.6 4.95E-04 3.57E-04 1.6 4.85E-04 3.49E-04 1.2 3.60E-04 2.62E-04 4.47E-04 OCDD 3.6 1.11E-03 8.03E-04 5.3 1.61E-03 1.16E-03 4.0 1.20E-03 8.72E-04 1.31E-03

2378 -TCDF 1.4 4.34E-04 3.12E-04 1.6 4.85E-04 3.49E-04 2.3 6.89E-04 5.01E-04 5.36E-04 12378-PeCDF 1.1 3.41E-04 2.45E-04 1.1 3.34E-04 2.40E-04 1.1 3.30E-04 2.40E-04 3.35E-04 23478-PeCDF 1.8 5.57E-04 4.01E-04 1.9 5.76E-04 4.15E-04 1.6 4.79E-04 3.49E-04 5.38E-04 123478-HxCDF 1.0 3.10E-04 2.23E-04 1.1 3.34E-04 2.40E-04 1.1 3.30E-04 2.40E-04 3.24E-04 123678-HxCDF 0.96 2.97E-04 2.14E-04 1.1 3.34E-04 2.40E-04 0.96 2.88E-04 2.09E-04 3.06E-04 234678-HxCDF 1.2 3.72E-04 2.68E-04 1.4 4.24E-04 3.06E-04 1.3 3.89E-04 2.83E-04 3.95E-04 123789-HxCDF 1.3 4.03E-04 2.90E-04 1.4 4.24E-04 3.06E-04 1.3 3.89E-04 2.83E-04 4.05E-04 1234678-HpCDF 1.0 3.10E-04 2.23E-04 1.3 3.94E-04 2.84E-04 1.3 3.89E-04 2.83E-04 3.64E-04 1234789-HpCDF 1.3 4.03E-04 2.90E-04 1.2 3.64E-04 2.62E-04 1.2 3.60E-04 2.62E-04 3.75E-04 OCDF 2.1 6.50E-04 4.68E-04 2.0 6.06E-04 4.37E-04 2.1 6.29E-04 4.58E-04 6.29E-04 

### PCDD/PCDF TEST RESULTS SUMMA**RY Motiva Enterprises LLC**  **Norco Refinery RCCU Stack**  **June 15 through 17, 2011 Test 1 - June 15 and 16**  **Test 2 - June 16 Test 3 - June 16 and 17**  **Av erage** Total TCDD 1.1 3.41E-04 2.45E-04 1.1 3.34E-04 2.40E-04 1.1 3.30E-04 2.40E-04 3.35E-04

Total PeCDD 1.7 5.26E-04 3.79E-04 2.0 6.06E-04 4.37E-04 2.6 7.79E-04 5.67E-04 6.37E-04 Total HxCDD 1.2 3.72E-04 2.68E-04 1.2 3.64E-04 2.62E-04 1.1 3.30E-04 2.40E-04 3.55E-04 Total HpCDD 1.6 4.95E-04 3.57E-04 1.6 4.85E-04 3.49E-04 1.2 3.60E-04 2.62E-04 4.47E-04 Total TCDF 2.8 8.67E-04 6.24E-04 3.1 9.40E-04 6.77E-04 3.5 1.05E-03 7.63E-04 9.52E-04 Total PeCDF 1.8 5.57E-04 4.01E-04 1.9 5.76E-04 4.15E-04 2.7 8.09E-04 5.89E-04 6.47E-04 Total HxCDF 1.1 3.41E-04 2.45E-04 1.2 3.64E-04 2.62E-04 1.1 3.30E-04 2.40E-04 3.45E-04 Total HpCDF 1.1 3.41E-04 2.45E-04 1.4 4.24E-04 3.06E-04 1.4 4.19E-04 3.05E-04 3.95E-04 **Total PCDD/PCDF** 18.1 5.60E-03 4.04E-03 20.8 6.31E-03 4.54E-03 20.8 6.23E-03 4.53E-03 6.05E-03 **TEQ A djusted Total**  Test 1 Test 2 Test 3 **Sample volume (Vmstd, dscf)** 114.049 116.474 117.879 *TEQ **Volumetric A ir Flow (DSCFM)**  249,677 255,734 258,682 **TEF **Av erage % CO** **2 by volume, dry**  16.9 17.3 17.1 TEF Factors from World Health Organization (WHO) **Av erage % O** **2 by volume, dry**  1.6 1.6 1.8 2005 Toxicity Equivalency

Factors and referenced in 40CFR63 Subpart DDDDD Table 11.

1.0142E-09 1.14E-03**Emissions** BLANK

**(ng/dscm at 7% O** **2 )**  **TEF  ** (ng/dscm)** **(ng/dscm at 7% O** **2 )**  2.42E-04 1.0 3.35E-04 2.42E-04 0 2.35E-04 1.0 3.25E-04 2.35E-04 0 2.56E-04 0.1 3.55E-05 2.56E-05 0 < 2.56E-04 0.1 3.55E-05 2.56E-05 0 2.35E-04 0.1 3.25E-05 2.35E-05 0 3.23E-04 0.01 4.47E-06 3.23E-06 0 9.44E-04 0.0003 3.92E-07 2.83E-07 0

3.88E-04 0.1 5.36E-05 3.88E-05 0 2.42E-04 0.03 1.00E-05 7.25E-06 0 3.88E-04 0.3 1.61E-04 1.17E-04 0 2.34E-04 0.1 3.24E-05 2.34E-05 0 2.21E-04 0.1 3.06E-05 2.21E-05 0 2.86E-04 0.1 3.95E-05 2.86E-05 0 2.93E-04 0.1 4.05E-05 2.93E-05 0 2.63E-04 0.01 3.64E-06 2.63E-06 0 2.71E-04 0.01 3.75E-06 2.71E-06 0 4.54E-04 0.0003 1.89E-07 1.36E-07 0

**TEQ* Factor Results** **Av erage** 2.42E-04 0

4.61E-04 0 2.56E-04 0 3.23E-04 0 6.88E-04 0 4.68E-04 0 2.49E-04 0 2.85E-04 0 4.37E-03 1.14E-03 8.26E-04
Toxicity Equivalents Toxicity Equivalency

Factor TEF Factors from World Health Organization (WHO) 2005 Toxicity

Equivalency

Factors and referenced in 40CFR63 Subpart DDDDD Table 11.

ng 6708 dscm 6.00E+01 lb dscm min hr 1000000000*453.59**Company: Did you have 4 test runs?** 

**Plant:** If yes, Highlight Columns F and H, and right-click and select "Unhide". **Unit:** You will need to adjust the formulas in the Average Column for the runs you want to use. **1 2**  **3 Av** **erage** Normal Normal Normal **P may need to adjust cell height and or width** 6/19/2011 6/19/2011 6/19/2011 P 9:45 12:22 14:50 11:54 14:32 16:58 0.248 0.133 0.103 0.162 0.38 0.20 0.16 0.25 P 0.3634 0.1947 0.1497 0.2359 P P 0.048 0.043 0.045 0.045 P 0.040 0.036 0.038 0.038 0.0382 0.0346 0.0359 0.0363 0.004 0.004 0.004 0.004 P 0.012 0.011 0.013 0.012 P 0.0119 0.0108 0.0123 0.0116 P P 383,296 382,967 379,432 381,898 257,461 257,197 254,997 256,552 144.3 144.5 144.3 144.4 31.773 31.745 31.452 31.657 22.2* 22.1 22.0 22.1 29.57 29.54 29.51 29.58 29.55 29.52 18.0 17.1 17.0 17.4 1.7 2.0 1.9 1.9 30.948 30.816 30.796 76.660 76.885 75.459 97.1 97.5 96.5 Isokinetic Variance * Theoretical maximum moisture content of the gas stream. Average Flue Pressure, in. Hg Barometric Pressure, in. Hg Average %CO2by

volume, dry

basis Average %O2by

volume, dry

basis Dry Molecular Wt. of Gas, lb/lb-mole Gas Sample Volume, dscf Flue Gas Moisture, percent by **Cl2 Emissions:** ppm mg/dscm lb/hr **Stack Parameters:** M2 Gas Volumetric Flow Rate, acfm M2 Gas Volumetric Flow Rate, Average Gas Temperature, °F Average Gas Velocity, ft/sec lb/hr Date Start Time End Time **HCl Emissions:** ppm mg/dscm lb/hr **HF Emissions:** ppm mg/dscm Source Condition **ME THOD 26A** 

**TEST RESULTS SUMMA RY**  Motiva Enterprises LLC Norco Refinery RCCU Stack **Test Run Number**If yes, Highlight Columns F and H, and right-click and select "Unhide". You will need to adjust the formulas in the Average Column for the runs you want to use.**Company: Did you have 4 test runs?** 

**Plant:** If yes, Highlight Columns F and H, and right-click and select "Unhide". **Unit:** You will need to adjust the formulas in the Average Column for the runs you want to use.

**1 2**  **3 Av** **erage** Normal Normal Normal P May need to fix row height if text too long. 6/15/2011 6/15/2011 6/15/2011 10:25 14:15 17:25 12:40 16:30 19:40

< 2.90E-06 < 2.95E-06 < 2.94E-06 < 2.93E-09 P
< 2.57E-06 < 2.58E-06 < 2.57E-06 < 2.57E-06 P
6.44E-05 5.30E-06 1.24E-05 2.73E-07 P 5.70E-05 4.65E-06 1.08E-05 2.42E-05

< 1.16E-05 < 1.18E-05 1.77E-05 < 1.37E-08 P May need to hide rows if one fraction only

. < 1.03E-05 < 1.03E-05 1.54E-05 < 1.20E-05 P

< 7.89E-05 < 2.00E-05 3.30E-05 < 4.40E-08 < 6.99E-05 < 1.76E-05 2.88E-05 < 3.87E-05
143.0 143.5 143.6 143.4 31.047 30.968 30.927 30.980 21.5* 21.9* 22.0 21.8 29.51 29.42 29.39 29.52 29.43 29.40 17.2 16.9 16.2 16.8 1.7 1.4 2.0 1.7 Barometric Pressure, in. Hg Average %CO2by

volume, dry

basis Average %O2by

volume, dry

basis Average Flue Pressure, in. Hg **Total Mercury Emissions** mg/dncm lb/hr **Stack Parameters:** Average Gas Temperature, °F Average Gas Velocity, ft/sec Flue Gas Moisture, % by volume mg/dncm lb/hr **Oxidized Mercury Emissions** mg/dncm lb/hr Date Start Time End Time **Particle Bound Mercury Emissions** mg/dncm lb/hr **Elemental Mercury Emissions** Source Condition **SPECIA TED MERCURY TEST RESULTS SUMMA** **RY** Motiva Enterprises LLC Norco Refinery RCCU Stack

**Test Run Number**30.820 30.760 30.672 65.351 64.312 64.376 100.9 100.5 100.9 Dry MWof Gas, lb/lb-mole Gas Sample Volume, dscf Isokinetic Variance**Did you have 4 test runs?** If yes, Highlight Columns F and H, and right-click and select "Unhide". You will need to adjust the formulas in the Average Column for the runs you want to use.

May need to fix row height if text too long.

May need to hide rows if one fraction only

.**Company: Did you have 4 test runs?** 

**Plant:** If yes, Highlight Columns I and L, and right-click and select "Unhide". **Unit:** You will need to adjust the formulas in the Average Column for the runs you want to use.

P May need to fix row height if text too long.

P Type of Analy

te < 3.83E-02 < 3.68E-02 < 4.00E-02 < 3.84E-05 < 3.71E-02 < 3.54E-02 < 3.85E-02 < 3.70E-02

Isokinetic Variance 101.1 100.6 100.0 * Theoretical maximum moisture content of the gas stream. Gas Sample Volume, dscf 30.083 29.769 29.566 Average %CO2by

volume, dry

basis 11.3 11.0 11.2 11.2 Average %O2by

volume, dry

basis 5.9 7.0 6.4 6.4 Average Flue Pressure, in. Hg 29.57 29.54 29.51 Flue Gas Moisture, percent by volume 22.3* 22.2* 22.1* 22.2 Gas Volumetric Flow Rate, dscfm 258,595 257,109 256,902 257,535 **Stack Parameters:** Gas Volumetric Flow Rate, acfm 385,586 383,081 382,538 383,735 ug/dscm: lb/hr: Fuel factor, dscf/MMBtu 8710 8710 8710 **HCN Emissions** Start Time 9:50 12:00 14:05 End Time 11:03 13:15 15:25 Source Condition Normal Normal Normal Date 6/19/2011 6/19/2011 6/19/2011 **OTM-029 TEST RESULTS SUMMA RY** 

Motiva Enterprises LLC Norco Refinery RCCU Stack
**Test Run Number 1**  **2 3**  **Av erage** **Did you have 4 test runs?** If yes, Highlight Columns I and L, and right-click and select "Unhide". You will need to adjust the formulas in the Average Column for the runs you want to use.

May need to fix row height if text too long.

HCN

### Company**: Date:**  **6/28/2011** Page 1 of 1



### Plant: **Norco, LA GE Energy**  **Project ZTSO0201**  **Unit: RCCU Scrubber Stack** 

Date 06/28/11 06/30/11 06/30/11 Start Time 16:39 12:00 15:40 End Time 18:51 14:08 17:50 Test Run 1 2 3 Average Flow Rate Stack Flow Method 2 dscfm 249457 251560 249597 250205 Moisture Moisture Method 320 % 20.1% 20.2% 20.1% 20.1%

Moisture fraction 0.201 0.202 0.201 0.201
Outlet Formaldehyde CH2O ppmvw 0.10 <0.04 0.041 <0.06 ppmvd 0.13 <0.06 0.051 <0.09 MW= 30.03 lb/hr 0.15 <0.061 0.060 <0.103 mg/dscm 125.4 <52 51.1 <88.3
Outlet Acetaldehyde C2H4O ppmvw <0.12 <0.15 <0.14 <0.13 M320 ppmvd <0.15 <0.18 <0.17 <0.18

MW= 44.05 lb/hr <0.26 <0.32 <0.29 <0.32 mg/dscm <221.2 <268.4 <252 <268.4
Outlet Acrolein C3H4O ppmvw <0.19 <0.24 <0.22 <0.22 M320 ppmvd <0.24 <0.3 <0.28 <0.3

MW= 56.06 lb/hr <0.53 <0.65 <0.6 <0.65 mg/dscm <454.4 <551.4 <517.7 <551.4
Outlet Propanal C3H6O ppmvw <0.087 <0.106 <0.099 <0.097 M320 ppmvd <0.11 <0.13 <0.12 <0.13

MW= 58.08 lb/hr <0.25 <0.3 <0.28 <0.3 mg/dscm <211.4 <256.5 <240.9 <256.5
Outlet Hydrogen Chloride HCl ppmvw 0.40 1.2 0.67 0.77 

### RCCU EMISSIONS TEST RESULTS SUMMA**RY - EPA METHOD 320**  **Motiva**M320 ppmvd 0.50 1.6 0.84 0.97 MW= 36.46 lb/hr 0.71 2.2 #REF! #REF! mg/dscm 0.61 1.9 #REF! #REF!
Outlet Hydrogen Cyanide HCN ppmvw <0.55 <0.49 <0.46 <0.5 M320 ppmvd <0.69 <0.61 <0.58 <0.61

MW= 27.03 lb/hr <0.72 <0.65 <0.61 <0.65 mg/dscm <620.5 <553.5 <524.1 <553.5
Outlet Hydrogen Fluoride HF ppmvw 2.3 2.0 2.1 2.1 M320 ppmvd 2.8 2.6 2.7 2.7

MW= 20.01 lb/hr 2.2 2.0 2.1 2.09 mg/dscm 1.9 1.7 1.8 1.8


### Company**: Date:**  **6/28/2011** Page 2 of 3 

### Plant: **Norco, LA GE Energy**  **Project ZTSO0201**  **Unit: RCCU Scrubber Stack** 

Test Run 1 2 3 Average Outlet Water H2O ppmvw 201448.6 201752.7 200972.1 201391.2 M320 MW= 18.016 ppmvd NA NA NA NA
Outlet Carbon Dioxide CO2 % wet 15.0% 14.9% 15.0% 14.97% M320 MW= 44.01 % dry 18.8% 18.6% 18.8% 18.74%
Outlet Carbon Monoxide CO ppmvw 1.6 2.2 3.2 2.4 M320 ppmvd 2.0 2.8 4.0 2.9

MW= 28.01 lb/hr 2.2 3.1 4.4 3.2
Outlet Nitric Oxide NO ppmvw 101.8 109.4 114.6 108.6 M320 ppmvd 127.5 137.0 143.4 136.0

MW= 30.01 lb/hr 148.6 161.1 167.3 159.0
Outlet Nitrogen Dioxide NO2 ppmvw <0.45 <0.52 <0.47 <0.48 M320 ppmvd <0.57 <0.65 <0.59 <0.65 

### RCCU EMISSIONS TEST RESULTS SUMMA**RY - EPA METHOD 320**  **Motiva**MW= 46.01 lb/hr <1.01 <1.16 <1.06 <1.16
Outlet Nitrous Oxide N2O ppmvw 10.9 13.9 12.9 12.6 M320 ppmvd 13.7 17.4 16.1 15.7

MW= 44.01 lb/hr 23.4 29.9 27.6 27.0
Outlet Sulfur Dioxide SO2 ppmvw 13.9 12.7 13.3 13.3 M320 ppmvd 17.4 15.9 16.6 16.6

MW= 64.07 lb/hr 43.3 39.8 41.5 41.5
Outlet Ammonia NH3 ppmvw 0.58 <0.2 <0.2 <0.33 M320 ppmvd 0.73 <0.24 <0.25 <0.73

MW= 17.03 lb/hr 0.48 <0.16 <0.17 <0.48
Outlet Methane CH4 ppmvw <0.13 <0.13 <0.12 <0.13 M320 ppmvd <0.17 <0.16 <0.15 <0.16

MW= 16.04 lb/hr <0.1 <0.1 <0.1 <0.1
Outlet Ethane C2H6 ppmvw <0.19 <0.18 <0.17 <0.18 M320 ppmvd <0.23 <0.22 <0.22 <0.22

MW= 30.069 lb/hr <0.27 <0.26 <0.25 <0.26
Outlet Ethylene C2H4 ppmvw <0.46 <0.44 <0.45 <0.45 M320 ppmvd <0.58 <0.55 <0.56 <0.55

MW= 28.05 lb/hr <0.6 <0.6 <0.6 <0.6
Outlet n-Octane C8H18 ppmvw 0.12 0.08 0.08 0.09 M320 ppmvd 0.15 0.09 0.09 0.11

MW= 56.06 lb/hr 0.33 0.21 0.20 0.25


### Company**: Date:**  **6/28/2011** Page 3 of 3 

### Plant: **Norco, LA GE Energy**  **Project ZTSO0201**  **Unit: RCCU Scrubber Stack** 

**Motiva RCCU EMISSIONS TEST RESULTS SUMMA** **RY - EPA METHOD 320** Example ppmvd as HCl = Hydrogen Chloride ppmvw x 1/(1-Water Fraction) Calculations 0.40 1/(1-0.165) 0.50 Method 320 lb/hr as HCl = ppmvd x dscfm x 60 min/hr x HCl MWx 1/3.853x108 0.50 249457 60 36.46 1/3.853x108 0.71 mg/dscm as HCl = lb/hr HCl x 28.32 ft3/m3 x 1/dcsfm x 1 hr/60 min x 453592.37 mg/lb

0.71 28.3 1/257197 1/60 453592.37 0.61