KLH <<:'I 

ENGINEERS, INC. 

November.26, 2008 

Ref. No. 220-02"003 

Sent via: Hand Delivered 

Mr, Kevin Halloran, Water Quality Specialist Supervisor 

Water Management 

Pennsylvania Department of Environmental Protection 

400 Waterfront Drive 

Pittsburgh, PA 15222-4745 

Dear Mr. Halloran: 

Municipal Authority of the City of McKeesport 

Technical Evaluation on Oil and Gas Well Wastewaters 

As Required Under the 

P ADEP Administrative Order Dated October 23, 2008 

51 73 CAMPBELLS RUN ROAD 

PITTSBURGH, PA ,-S20S 

PHONE: 412-494- 051 [] 

·F'AX: 412-494-0426 

INF"O@KLI-!ENGINEERS.COM 

WWW.KLHENGI~EERS'I?OM 

Please find enclosed two (2) copies of the Teclmical Evaluation of the Impact of Oil and Gas 

Well Wastewaters on the Municipal Auth()rity of the City of McKeesport Wastewater Treatment 

Facility. This evaluation is a requirement of the Departments Administrative Order dated 

October 23,2008. 

Please contact me if you have any questions regarding this report. I can be reached directly at 

(412)_494-051O,extension 116. 

Very truly yours, 

KLHENGINEE.RS,~.~ ~ 

~~ 

Michael C. Sherrieb 

Enclosure( s) 

cc: Mr. Joe Rost, Municipal Authority of the City of McKeesport, wi (2) enclosures 

Steve Greenberg, P£., KLH Engineers, Inc., wi enclosure 

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CITY OF McKEESPORT 

ALLEGHENY COUNTY, PENNSLYVANIA 

TECHNICAL EVALUATION OF THE IMPACT OF 

OIL AND GAS WELL WASTEWATERS ON THE 

MUNICIPAL AUTHORITY OF THE CITY OF McKEESPORT 

WASTEWATER TREATMENT FAC·ILITY . 

NPOES PERMIT No. PA0026913 

NovEMBeR 2008 

5173 CAMPBELLS RUN ROAD 

KLH<<3: 

ENGINEERS, INC. 

PITTSBURGH, PA 15205·9733 
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City of McKeesport 

Technical Evaluation of the Impact of Oil and Gas Well Wastewaters on the 

Municipal Authority of the City of McKeesport 

Wastewater Treatment Facility 

Table of Contents 

1.0 Purpose ...... ~ ................................................................................... , ............................................... 1 

2.0 Description ofMACM Treatment Processes .......................... , ..................................................... 1 

3.0 Evaluation of Total Dissolved Solids and Chlorides on Process Units., ....................................... 3 

4.0 MACM Sludge Treatment and Disposal ................................................ : ...................................... 6 

5.0 Summary of Conclusions ................................................ : ............................................................. 7 

Tables 

Table 1.0 

Appendiees 

AppendixA 

AppendixB 

AppendixC 

AppendixD 

Net Impact ofMACM Efiluent on Background Levels of IDS and Chlorides 

Oil and Gas Wastewater Manifest Spreadsheet 

MACM Process Flow Diagram Detailing Sample Locations 

MACM Chloride and IDS Analytical Data 

Table 3-16 "Typical Composition of Un treated Domestic Wastewater," 

, Metcalf & Eddy, Third Edition; Wastewater Engineering 

AppendixE MACM BOD and TSS Inter Process Data and MACM Weekly Operations ~poru ' 

AppendixF MACM Sludge Analysis 

City of McKeesport 

Technical Evaluation of the Impact of 

Oil and Ga. Well Wastewaters on the 

WastewaterTreabnent Plant 

November 2008 Ref. No. 220-02 

1 

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City of McKeesport 

Technical Evaluation of the Impact of Oil and Gas Well Wastewaters on the 

Municipal Authority of the City of McKeesport 

Wastewater Treabnent Facility 

1.0 Purpose 

The Pennsylvania Department of Environmental Protection (P ADEP) issued an Administrative 

Order to the Municipal Authority of the City of McKeesport on October 23, 2008. The 

. Administrative Order sets forth a series of requirements prescribed to MACM, in order for 

MACM to continue acceptance of oil and gas well production wastewater for treatment and 

processing at the MACM Wastewater Treatment Plant (WWTP).The purpose of this document 

is to provide a written technical evaluation of potential impacts of oil and gas production 

wastewaters on the MACM treatment process. This evaluation will contain, as prescribed in the 

Order; an evaluation of the effects on each major unit process; an estimate of the maximum 

Total Dissolved Solids (IDS) that will occur in each process; a description of measures 

employed by MACM to monitor and minimize adverse effects on biological processes; 

quantitative estimates on anticipated changes to effluent characteristics for each new pollutant 

identified; a description of how MACM will assure that the WWTP sludge will not be classified 

ashazardous waste as a result of accepting this new waste stream, and any resulting constraints 

on sludge treatment and disposal. 

2.0 Description of MACM Treatment Processes 

The MACM WWTP is a conventional activated sludge, secondary wa'stewater treatment facility. 

The plant has a permitted hydraulically treatment capacity of 11.50 million gallons per day 

(mgd), although the facility Car) hydraulically handle peak daily flows of 20;0 mgd. The MACM 

. 2007 Annual Chapter 94 Waste Load Management Report indicates the annual average flow to 

the WWTP in 2007 was 10.33 mgd. The maximum monthly average day flow was 14.64 mgd, 

. occurring in March of 2007, and the minimum monthly average flow was· 7.75 rrigd, occurring 

in October 2007. . 

The Order requires MACM to immediately restrict the daily volume of oil and gas well 

production wastewater to 1% of the average daily flow. To comply with this requirement 

MACM has limited the daily volume of oil.and gas well production wastewater introduced into 

the"VWTI' to 1% of the WWTP's forward flow rate on any given day. 

The MACM has the ability to completely control the rate at which the oil and gas Well 

production wastewater is introduced into the WWTP process. MACM achieves this process 

control by utilizing two existing aeration basins as holding tanks. Each basin has a working 

volume of 334,000 gallons, and currently serves to provide excess treatment capacity. The waste 

is received and stored in the basin, aerated, and subsequently introduced into the WWTP 

process at a controlled rate no greater than 1% of the forward flow into the facility~ Storing the 

waste stream in the aeration tanks offers MACM the ability to analyze the waste for TDS and 

chlorides and determine mass loadings for these pollutants to the plant process. This gives 

City of McKeesport 

Techni<;al Evaluation of the Impact of 

Oil and Gas Well Wastewaters on the 

Wastewater Treatment Plant 

November 2008 Ref. No. 220-02 

1 KLH<'<~ 

ENGINEERS .• INC. 
'.-' 

MACM greater control over the actual loads applied into the process to assure the biological 

. process is protected against shock loads and potential interference. 

. MACM monitors each individual waste load received from oil and gas well production 

wastewater sources. Included in this record is the date received at MACM; the hauling 

company transporting the waste to MACM; the Truck ID number delivering the waste to 

MACM; the well or point source from which the wastewater was generated; the quantity of the. 

wastewater received; the type of wastewater as it relates to the well drilling process; the current 

plant flow rate of the MACM WWIP at the time the waste is received; the level of chlorides in 

the wastewater received in (mg!I); the corresponding maSs load of chlorides in the wastewater 

received, and the pH of the wastewater received. This data is recorded and stored in a 

spreadsheet format by MACM operation staff. The information contained in this spreadsheet 

will be filed with the MACM monthly discharge monitoring report (DMR) to P ADEP as 

required under the Order. A copy of the hauling records and chlorides data is contained in 

Appendix A of this report 

MACM's monitoring of chloride levels in the received wastewaters and MACM's ability to 

control the quantity and rate at which these wastewaters are introduced into· the treatment 

process provides MACM's operations staff with a level of control to protect the biological 

process from upset, and control the level d pass through to assure water quality criteria is met. 

MACM employ's Pennsylvania state licensed operators who monitor, regulate and control all 

aspects of the WWIP process twenty four hours a day, seven days per week, fifty two weeks 

per year. The professional training and experience of these state licensed wastewater treatment 

plant operators prOvides MACM another level of assurance the introduction of oil and gas well 

wastewaters can be conducted, monitored and controlled to achieve the desired water quality 

. limits while preserving the biological treatment process. 

The MACM facility is comprised of the following treatment unit process: 

• Mechanical screening 

• Grit removal 

• Aeration basins 

• Primary clarifier settling tanks 

• Activated sludge process tanks 

• Final clarifier settling tanks 

• Aerobic digestion 

• Sludge thickening tanks 

• Sludge dewatering (belt filter press) 

• Chlorine disinfection system 

Oil and gas well production wastewaters received and stored in the aeration tanks is drained to 

the raw sewage wet well at a rate no greater than 1% of the plants daily forward flow. This 

combined waste stream is screened, and receives grit removal prior to discharging into the 

City of McKeesport 

Technical Evaluation of the Impact of 

Oil and Gas Well Wastewaters on the 

Wastewater Treabnent Plant 

November 2008 Ref. No. 220-02 

2 K LH ~'!.!IW! .. ENGiNEERS, INC. 
primary clarifier settling tanks for solids removal. Solids which are removed during the 

. primary settling process are sent to the dewatering facilities. The digested sludge is monitored 

quarterly for all local limit parameters as contained in the MACM, EPA approved pretreatment 

program. MACM also conducts an annual priority pollutant scan on its produced sludge for all . 

Form 43 listed parameters. 

After the primary clarification settling tanks the plants flow enters the activated sludge tanks. 

During this process the plant operators closely monitor control points for Sludge Volume Index 

(SVl), and Food to Micro-organism Ratio (FIM). By monitoring these control pojnts regularly 

the plant operations staff can determine if any adverse effects to settling or treatmentcapability 

are observed. If any adverse effects were noticed the operating staff would immediately stop 

the introduction of the oil and gas well wastewater from the pre-aeration holding tanks and 

stabilize the process. A biological microscopic eva,luation is also completed daily by the 

operating staff. Samples of activated sludge mixed liquor are collected and analyzed under a 

high powered microscope to determine the overall health of the biological system • 

. . When the forward flow leaves the activated sludge process it enters the final clarifier settling 

tanks. Here the mixed liquor activated sludge is settled and separated from the liquid stream 

and retuined to the activated sludge tanks via the return activated sludge pump system . 

. Periodically, as required to maintain the des.ired sludge age and to maintain proper settling 

characteristics; sludge will be wasted to and aerobic digesters. 

After final settling the treated water is conveyed to the chlorination system wnere pathogenic 

disinfection via chlorine gas injection is completed. After chlorination the flow is transferred 

into the chlorine contact tanks to provide sufficient contact time for the disinfection process to 

be completed prior to discharge to the Monongahela River. 

3.0 Evaluation of Total Dissolved Solids and Chlorides on Process Units 

MACM began to collect 24 hour flow proportional composite samples to evaluate the levels of 

chlorides and IDS which occur under normal waste load conditions and which occur during 

days which the WWTP is processing oil and .gas well wastewater. MACM selected five 

sampling locations as key areas within the WWTP to monitor IDS and chloride levels. These 

sampling points can be seen on the MACM Process Flow Diagram included in Appendix B, 

which shows the location of each of the five sampling points. A complete listing of the sample 

results for IDS· and ,chlorides at all five sampling locations is contained in Appendix C of this . 

report. 

The first sampling location monitored. by MACM is the influent sampling point. The purpose 

of collecting the influent sample is to provide MACM with the typical level of IDS and 

chlorides which OCcur in MACM's influent, without any contribution from oil and gas well 

wastewater. During the week long testing the influent test results for both IDS and chlorides 

were relatively consistent. IDS values in the influent ranged from 399 mgll to 446 mgll. These 

levels of IDS would indicate concentrations that would be found in typical medium strength 

City 01 McKeesport 

Technical Eyaluation 01 the Impact 01 

Oil and Gas Well Wastewaters on the 

Wastewater Treatment Plant 

November 2008 ReI. No. 220-02 

3 
sewage. Chloride levels in the influent samples ranged from 101 mgll to 122.5 mgll. Chloride 

levels of 100 mgll are considered to be a strong concentration in untreated domestic sewage, 

according to Table 3-16, of Metcalf and Eddy. Third Edition. Wastewater Engineering. Table 3-

16 is included in Appendix 0 of this report. . 

In order to determine levels of chlorides and IDS in each of the process basins, 24 hour flow 

proportional composite samples were collected and analyzed at the grit tank, primary clarifier 

effluent, and the treatment plant effluent The analytical results for the five sample locations are 

listed in Appendix C. 

Flow proportional composite samples were also taken and analyzed for oil and gas well 

waStewaters received and stored in the aeration holding tanks. Samples taken in the holding . 

tanks indicate the strength of the oil and gas well wastewater being introduced into the 

treatment process. 

The results of the samples taken and analyzed through the MACM WW1P indicate that there is 

no red-qction in.concentration of TOS and chlorides through the plant processes. This is not 

unexpected as conventional sewage treatment facilities are not designed to remove dissolved 

constituents such as IDS and chlorides. 

Although there is no apparent reduction in IDS or chloride concentrations through the 

treatment process, the introduction of oil and gas well wastewaters haS had no effect on the 

treatment ability of the MACM system to trEiat and remove conventional pollutants such as 

Biochemical Oxygen Demand (BODs) and Total Suspended Solids (TSS) .. Appendix E. contains 

inter-process data for BODs and TSS removals through the MACM process during the 

introduction of oil and gas well waste water and also on days which no oil and gas well 

. wastewater was introduced. The data contained in Appendix E Shows the percent removal of 

BODs during the November 1, .2008 to November 7, 2008 testing period waS consistently 

observed between 95% and 98%, and the percent removal of TSS averaged 91%. These levels of 

removal exceed the minimum required removal rate of 85% for these pollutants and provide a 

good indication the process is performing well during the introduction of oil and gas well 

wastewater into the process. Microscopic analysis conducted daily on the activated sludge 

mixed liquor has shown that the biological process has remained healthy and viable during the 

introduction and processing of oil and gas well waste waters. 

To evaluate the potential impacts that the discharge of IDS and chlorides may have on the 

Monongahela River, an evaluation utilizing the same analytical approached MAcM used in 

conducting their Head Works Loading analysis and development of Local Limits has been 

utilized. 

The following Monongahela River flows were utilized in the 2005 Head Works Loading 

Evaluation for the Development of Local Limits at MACM. . ~ 

City of McKeesport 

. Technical Evaluation of the Impact of 

Oil and Gas Wen Wastewaters on the 

Wastewater Treatment Plant 

November 2008 Ref. No. 220-02 

4 
Chronic Evaluation: (g.10 = 350 cfs, or 226 million gallons per day 

Acute Evaluation: Qt'IO = 494 cis, or 319 million gallons per day 

Human Health: Harmonic Flow = 2860 cfs, or 1,847 million gallons per day 

By utilizing the MACM effluent data collected and analyzed for IDS and chlorides we can 

d~temtine the effective impact these levels have on the Monongahela River during the above 

referenced .flow' periods. We will analyze the impact of the effluent IDS and chlorides at the 

maximum effluent levels and at the average levels recorded during the one week testing period 

and apply these loads. to the various river flows to detemrine the net effect MACM's effluent 

has on the Monongahela River. 

Average IDS level = 516mg/I 

Maximum IDS level = 582mg/I 

Average Chloride level = 152mg/I 

Maximum Chloride level = 185.7 mg/I . 

Applying each to the following formula the net effect for each can be determined at the various 

river flows. 

Effluent cone. (mgLU x Plant flow rate (mgd) = Net effect to background level (mg/I) 

Monongahela River Flow Rate (mgd) 

Table 1.0 

Net Jnipact of MACM Effluent on Background Levels of IDS and Chloride~ 

Net Increase in Receiving Water Levels 

Max Avg MaX Avg 

IDS IDS Chlorides Chlorides 

(mg/I) (mg/I) (mg/I) (mg/I) 

River 

Flow (mgd) 582 516 185.7 152 

(g.10 226 19.31 17.12 6.16 5.04 

Qt.IO 319 13.68 12.13 4.37 3.57 

Harmonic 1,847 2.36 2.10 0.75 0.62 , 

Note: Average daily plant flow of 7.5 mgd utilized' for calculation 

City of McKeesport 

Technical Evaluation of the Impact of 

Oil and Gas Well Wastewaters on the 

Wastewater Treatment Plant 

November 2008 Ref. No. 220-02 

s· KLH<~~ 

ENGINEE~S.INC. 
Table 1.0 clearly shows the resulting increase in levels of TOS and Chlorides attributable to the 

MACM effluent on the Monongahela River during the most critical (Q.,. river flow is very small, 

less than 20 mgll fot TOS, and less than 7 mgll for chlorides. The monthly average limit for . 

potable water supply criteria in source waters for TOSis a monthly average of 500 mgll and a 

maximum value of 750 mgll. The net increase in TOS of 20 mgll under (Q.l. conditions is only 

. 4% of this limitation and only 2.67% of the maximum allowed. The limit to meet potable water 

supply criteria for chlorides is 250 mgll in source waters. The net.increase from the MACM 

effluent of 6.16 mgll under (Q.IO conditions is 2.5% of the limit. 

As a result of the data presented and the analysis conducted it is the opinion of KLH Engineers, 

Inc. that the introduction of oil and gas wastewaters under the conditions prescribed above 

causes no adverse effects to the MACM·biological treatment process and no disc~ble impact 

on the receiving waters of the Monongahela River. 

4.0 MACM Sludge Treatment and Disposal 

The MACM currently employs two (2) aerobic digesters to digest and stabilize biologically 

active waste solids for its treatment process. Once stabilized the solids are thickened and 

dewatered via a belt filter press. Dry, stabilized cake solids are then hauled to the Waste 

Management (Monroeville) landfill for final disposal. TheMACM as previously mentioned, 

has an EPA approved Industrial Pretreil.tment Program; Under this pretreatment program 

regular testing of the plant influent, effluent and sludge is conducted and evaluated for 

potential causes of interference of the biological processes. Annually the MACM also conducts 

a Form 43 analysis to maintain its permit with the landfill fro sludge disposal. To determine if 

the acceptance of oil and gas well wastewaters poses any harmful effects to MACM's current 

method· of sludge stabilization and treatment a comparison of analytical data prior to the 

acceptance of oil and gas well waste water was and analytical data obtained after the acceptance 

of oil and gas well wastewater was conducted. This data is contained in Appendix F of this 

report. 

Comparison of sludge data prior to the acceptance of oil and gas well wastewaters and sludge 

data after the acceptance of oil and gas well wastewaters indicates there is little change in the 

consistency, or quality of sludge at MACM. Should levels of any monitored substance in their 

sludge begin to increase to a level which would cause the sludge treatment or disposal practices 

tei be come at risk MACM will limit or halt receiving oil and gas well wastewaters contributing 

to this increase. 

MACM sludge is screened for radioactivity at the Waste. Management landfill prior to 

acceptance, but because low level, Normally Occurring Radioactive Materials (NORM) are 

known·to be present in oil and gas well waste waters in certain areas, MACM has purchased 

. Geiger Counter to monitor all wastewaters received from oil and gas well operations for 

NORM. MACM will monitor and test each load received for NORM and will reject any load 

determined to contain such materials. In addition, MACM requires that the generator and 

hauler certify that the wastewater being received is not classified as hazardous waste. 

City of McKeesport 

Technical Evaluation of the Impact of 

Oil and Gas Well Wastewaters on the 

Wastewater Treatment Plant 

November 2008 Ref. No. 220-02 

6 K L H 4S"!iW'"" . ENGINEERS .• INC. 
By continuing to closely monitor their sludge for metals, PCB's, Herbicides, Pesticides, Volatile, 

Semi-volatile Organics, and NORM, MACM: will be able to assure that the current methods 

utilized to treat, stabilize and dispose of their sludge are protected and maintained and that 

their sludge will not be cIassifiedas a hazardous waste_ 

5.0 Summary of Conclusions 

In conclusion, the current program for the acceptance of oil and gas well wastewater as it is 

curr~tly being conducted at the MACM: WW1P provides for both the protection of the MACM 

process, .and· the protection of the receiving waters of the Monongahela River for its intended 

use; and will not adversely impact the level of Total Dissolved Solids or Chlorides in the 

Monongahela River. MACM has· instituted record keeping, quality control and process 

monitoririg programs to assure it can sufficiently monitor the treatnient plant process, and the 

effluent water quality to meet permit compliance. 

City of McKeesport 

Technical Evaluation of the Impact of 

Oil and Gas Well WasteWaters on the 

Waslewater Treatment Plant 

November 2008 Ref. No. 220-02 

7 KLH<..."-=_ -""'-=E 

ENGINEERS, INc. 
ApPENDIX A 

OIL AND GAS WASTEWATER 

MANIFEST SPREA[)SHEET 
DATE eO.MPANY TRUCK# WELL. .GALLONS TYPE FLOW,CHb08!ElSS4mgtLl,ChlLOR]DES.Ub.s.t ..• a!i!. 

10/23/2008 Hawg 120 Equitable-Burr # 81 3780 Brine 7.2 165000 5202 7.70 

10/25/2008 Hawg 114 Equitable~ # 511062 3780 Flow Back 15.3 120000 3783 6.72 

10/27/2008 Hawg 120 Equitable-Burr # 81 3780 Brine 8.3 155000 4886 6.34 

114 Equitable- # 511062 3780 Flow Back 115000 3625 6.76 

10/28/2008 Hawg 114 Eq\.litable-511602 3780 Flow Back 7.2 115000 3625 6.56 

117 Che$~eeake-626750 3780 Flow Back 60000 1892 6.95 

10/30/2008 Hawg 113 Equitable-ROA-60 3780 Brine 7.4 120000 3783 7.01 

119 Equltable-511062 3780 Brine 120000 3783 6.63 

120 csuitable.Burr # 81 3780 Brine 145000 4571 6.89 

10/31/2008 Hawg 114 Equitable-511602 3780 Flow Back 7.1 95000 2995 6.81 

,- ""', . : --~:. '-'''''". ' . -,;:);;:~~;:~~:---'.";,,,:: "','il:-"";:'-" ,;::)";~.'J . . :-

·11/3/2008 Hawg 113 Equitable-Burr #81 3780 Brine 6.7 155000 4886 7.70 

11/4/2008 Hawg 114 Esuitable-511264 3780 Flow Back 6.9 145000 4571 6.13 

11/612008 Hawg 117 Equitable-511264 3780 Flow Back 7.0 155000 4886 7.09 

11/10/2008 Hawg 119 Equitable-Burr #81 3780 Brine 7.0 145000 4571 6.33 

11/12/2008 Hawg 119 Equitable-Burr #81 3780 Brine 7.3 155000 4886 6.94 

11/17/2008 Hawg 116 Chesapeake-627033 3780 Pit 7.6 40000 1261 10.09 

101 . Chesapeake-627033 3360 Pit 40000 1121 9.91 

103 Chesapeake-627033 3360 Pit 40000 1121 9.78 

11/18/2008 Hawg 120 Equitable-Burr #81 3780 Brine 7.8 145000 4571 6.62 
DATE COMPANY TRUCK# WELL GALLONS ,TYPE ,FLOW CldL,OBJDES,!mglL)CHLQRlDES,(lbs.l, ",R!i 

10/23/2008 Huntley VT03 Altman #3 4620 Frae 7.2 30000 1156 6.30 

VT01 Altman #3 4620 Frae 30000 1156 6.01 

VT05 Altman #3 4620 Frae 30000, 1156 6.63 

10/24/2008 Huntley VT05 Altman #3 4620 Frae 7.6 20000 771 6.61 

VT04 Weston #2!Lav #4 2940 Brine 90000 2207 6.40 

VT02 Altman #3 4620 Frae 20000 771 6.75 

VT05 Altman #3 4620 Frae 20000 771 6.69 

VT05 Altman #3 4620 Frae 20000 771 6.80 

VT05 Altman #3 4620· Pit 25000 963 11.17 

VT02 Altman #4 4620 Brine 120000 4624 6.59 

VT05 ' Altman #3 4620 Pit 25000 963 10.99 

VT02 Altman #3 4620 Pit 25000 963 10.67 

VT05 Altman #3 1680 Pit 25000 963 10.50 

10/3112008 Huntley VT02 Altman #4/Stratigos #1 4620 Brine 7.1 70000 2697 6.74 - .:'~':: 

", -; ,~. . "', . ',- ·>.~;i::-:''-·:C-., 

11/6/2008 Huntle~ VT05 Leben~ood#1 4620 Frae 7.0 20000 771 8.06 

11/7/2008 Huntley VT02 Blissman#5 4620 Frae 6.9 20000 771 6.74 

VT02 Blissrilan #5 4620 Frae 20000 771 6.68 

VT02 BUssman #5 4620 Frae 20000 771 6.99 

VT02 Blissman#5 4620 Frae 20000 771 7.11 

11/10/2008 Huntley VT02 Blissman #5 4620 Frae 7.0 35000 1349 4.25 

VT02 Blissman#5 4620 Frae 35000 1349 5.00 

VT02 Blissman#5 4620 Frae 35000 1349 4.61 

VT04 Blissman#5 4620 Frae 35000 1349 4.51 

VT02 Blissman#5 4620 Frac 35000 1349 4.88 

11/11/2008 Huntley VT02 Blissman #5 4620 Pit 6.5 35000 1349 11.59 

VT02 Blissman#5 4620 Pit 35000 1349 10.78 

11/1212008 Huntley VT02 Blissman#5 4620 Frae 7.3 55000 2119 5.81 

VT02 Blissman #5 4620 Frae 55000 2119 6 

VT02 Blissman#5 '4620 Frae 55000 2119 5.88 

11/14/2008 Huntley ----- VT02 Blissman#5 4620 Pit 6.6 40000 1541 10.1 

VT05 Blissman#5 4620 Pit 40000 1541 9.91 

VT02 Blissman#5 4620 Pit 40000 1541 9.78 

mrf/2008 Huntley VT04 Altman #4 4620 Pit 7.6 10000 385 9.07 

VT02 Altman #4 4620 Pit 10000 385 9.00 

11/18/2008 Huntley VT02 Oliver 55-2 4620 Pit 7.8 145000 5587 6.62 
· ApPENQIXB 

MACM·PROCESS FLOW DIAGRAM 

DETAILING SAMPLE LOCATIONS 
_ ... ,-',.- MONONGAHHLA RIVER 

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·ellnUI!NT 

_PLE 

POINT 

Iel'Fl.UeNT 

NEW 

CHLORINIe 

CONTACT 

TANKB 

o ACTIVATeD S'UDOIf TANK 

o MROBIC DIGEtlTlIR 

WASTE ACTIVATED SLUDGE 

r-----~-----., 

I RETURN I 

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1M 

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CHLDRINIf 

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TANK 

PRIMARY 

SlITTING 

TANKS 

I . SLUDOB I v-....... RAW SLUDGe I I r ==== ----.=I._--HOLDINtJTANK L _____ .. _ ____ ...I IP,u. I BAMPLIf POINT 

WASTIfACTlVATe'DfI'UDOIf rO t=:;o _ ~ : 

r--I ).l.-~--.J'- -.- ..J 

: LQ' SLUDGE 

I BELT FILTER THIt:eNINtI 

t PREII6 TANKfI 

GRIT SAMPU POINT 

I 

I 

I 

SLUDGe 

TO 

LAND"'LL 

ORITCHAMBI!R 

MECHANICAL SCRUNS 

PLANT PUM". STATION 

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f 

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Iwing No. . 

6·2 
APPENDIXC 

MACM CHLORIDE AND TDS 

ANAL YTICALDATA 
Municipal Authority of the City of McKeesport 

Oil and Gas Well Wastewater 

Analytical Data for Chlorides and Total Dissolved Solids 

Nov-08 

Influent Grit· 

Sample Date TDS Chlorides TDS Chlorides 

11/1/2008 399 101 411 100.7 

11/2/2008 413 107.5 433 96.1 

11/3/2008 430 101.8 441 108.2 

11/4/2008 415 103 452 104.4 

11/5/2008 446 122.5 461 131.7 

11/6/2008 432 109.2 446 103.4 

11/7/2008 431 120.2 456 156.7 

Minimum 399 101 411 96.1 

Maximum 446 122.5 461 156.7 

Average ~ 424 109 443 114 

Holdina Tank Priman Effluent Effluent 

TDS Chlorides TDS Chlorides TDS Chlorides 

419 104.8 506 139.5 

411 104.9 452 98.6 

23100 13187 454 114.2 493 156.9 

19400 9603.2 474 122.8 582 181.6 

416 127.3 536 15.9.2 

27400 12679 485 134.5 505 141.1 

2224 1090.9 437 120.8 535 185.7 

2224 1090.9 411 104.8 452 98.6 

27400 13187 485 134.5 582 185.7 

18031 9140 442 118 516 152 
ENNTRO~NTALSERVICE 

. LA.BORATORIE~_ INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE OF 

HEADQUARTERS: 

1803 Philadelphia SL 

IndIana, PA 15701 

(724) 463·TEST 

(724)465-4209 

Sample IdentIflcaHon 

Influent 

GrIt 

PrimBlY Emu.nl 

HoldIng Tank 

Emuent 

By: {5!j 

ct By: I 

~ SOUTHERN DIVISION: 

1276 aenUeyvllle Road 

Van VDcrhls, PA 15366 

(724)2 .... TEST 

I (724)26.8-8378 

~NA~ LABORATORY USE ONLY 

ESL# 

EOF1 ' 

;( 

Oalef 71me 

iCHAIN OF CUSTODY SEAL Yes No 

D 

• Type 

Grab 

Date TIme 

.-............... .. ' .............. ....... - '-"'-'-::: ... ................... .................. -... ..... -..... ,~~ 

.. ..-... -..... _ ... ... -............ .-

........................ 

............ -......... 

,1 DAY6OUJ. 

LAW., 

. ANUlO. _ .. 

LI.~r'lN COSTS, 

MatrIx # of ContaIners ContaIner Type AnalysIs Requested 

PlDlDrvaUVB 

WW 1 Plastic Ute, 

non. Tolel DIssolved Solids, Chloride 

WW 1 Plastic ~lter Total DIssolved Solids, ChlorIde non. 

WW 1 Plastic Liter 

ngne 

Tolal Dissolvad Sonds, Chloride 

WW 1 Plastic Liter Total Dissolved Solids, Chloride .... WW Plastic Liter Total Dissolved Solids, Chloride non. 

Natural Gas Water Study 

All 

A~ /i/fybr I J,' jOiContactPerson: 

Recetv1d By: (SlgnBlUra) j . Date! TIme 

Ms. Klisti 

~ jJ" P&M 1 II-L/,n'i- 1r;3.'< 

Datef TIme 

lBy: Datef 11me 

I

Phone: 

Fa'" 

100 ll+lJ:llntil'! A\JQnIIP 

,PA 15132 

(412) 673-9701 x11 

(412) 6 

I 
~ r.JVi i#t')t~ iiA ~ f<,jT 4 i 

•• ,. .... ,_. ,.iwi •• ,. •• 1t.. 

,ERVICE LABORATORIES, INC. 

803 Philadelphia street, Indiana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

~ame: 

,ample Start Dale: 

lample End Date: 

~eceipt Date: 

leport Date: 

lampleSite: 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

111112008 11:00 AM 

111212008 11:00 AM 

I 11412008 4:31 PM 

11/1012008 

Natural Gas Water Study 

Analyte 

. 

Analyst 

MS 

Total Dissolved Solids ('rDS) MAD . 

DEP Certification #s 32.00382 

Sample IDI#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis ' Sample 

Date Result 

1110512008 104.8 

1110712008 419 

Appro •• d By: ~~l!I~~!!!:~;::=-:':~~"""-:'=-;::;:"-___ _ J01fQlhan Kon, Technical Director 

0831364 

WasteWater 

Composite 

CLIENT (Client) 

Primary Effluent 

Units . Method 

mg/\ SM4500CIC 

mg/\ SM2540C 

MDL 

1.0 

25 

IND=Not Dc1ecled 

Page 1 of 1 
I=f;.JVU~;(-jtJiii •• '11 Y ..... _. ,.IY. 

3ERVICE LABORATORIES, INC. 

803 Philadelphia street. Indiana, PA 15701 

7241-463-TEST FAX (724)-465-4209 

Report of Analysis 

~ame: McKeesport Municipal Authority 

Attn: Mr. James Degnan 

SampIeID#: 

Sample Type: 

100 Atlantic Avenue 

McKeesport, PA 15132 

IJIl12008 1J ;00 AM 

Sample Source: 

Sampler: 

,ample Star! Date: 

,ample End Date: 

leceipt Date: 

iteport Date: 

,ample Site: 

Client Sample ID: 

111212008 1 I :00 AM 

1J1412008 4:31 PM 

IJlJOI2008 

NatoraJ Gas Water Study 

Analyte Analyst Analysis Sample . Date Result 

Chloride MS 1110512008 101.0 

Total Dissolved Solids (TDS) MAD 11107i2oo8 399 

Note: DEP CcrtificDtiDn.#s 32-00382 

Approv.d By: --"7~ .. ~+,::::~~,-:::,~-,: . .:..;"""-,,:-:::::-__ -'- Jonathan Kan~ Tee/mical Director 

• 

0831362 

WasteWater 

Composite 

CLIENT (Client) 

Influent 

Units Method 

mgll SM4500CIC 

mgll SM2540C 

. MDL 

1.0 

25 

IND=Not Detected 

Page 1 of 1. 
:= ii.. ail Eii Fii.#=a. iii. - e -;::: iC. ii:;;: &' i 

i""i"...:Viii#i JrJMi-iuiAi _ • .,. 1J •• , __ • ,. .... _ • .,... 11._ 

3ERVICE LABORATORIES, INC. 

803 Philadelphia Slreet. Indiana. PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report ofAnaJysis 

'lame: 

,ample Start Date: 

,ample End Date: 

R.eceipt Date: 

R.eport Date: 

,ample Site: 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

111112008 II :00 AM 

111212008 11:00 AM 

1114120084:31 PM 

1111012008 

Natural Gas Water Study 

Anaiyte Analyst 

MS 

Total Dissolved Solids (TOS) MAD 

Note: DEP Certification is 32-00382 

SampleID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample JD: 

Aoalysis Sample 

Date Result 

11/0512008 100.7 

1110712008 411 

APprOV'dBY:~;tLJ;'-"~='-~~7.·=-"'~~"""-;":';:::::""· -,.-__ _ Jonarhan Kon, Technical Director 

0831363 

WasteWater 

Composite 

CLIENT (Client) 

Grit 

Units Method 

mg/I SM4500CIC 

mg/l SM2540C 

MDL 

1.0 . 

25 

IND=NOI Delecled 

Page 1011 
j;NVi~O~fa.V.ei~N t.Ai • I ... .... , i "I ..... I. ,. 

,ERVICE LABORATORIES, INC. 

803 PhiladelphIa street. IndIana, PA 15701 

724l-463-TEST FAX 1724)-465-4209 

Report of Analysis 

'lame: McKeesport Municipal Authority 

Attn: Mr. James Degnan· 

lample Start Dat.: 

lample End Date: 

teeeipt Date: 

teport Date: 

iample Site: 

chloride 

100 Atlantic Avenue 

McKeesport, PA 15132 

111112008 II :00 AM 

111212008 11 :00 AM 

1114/2008 4:31 PM 

llIto12008 

Natural Gas Water Study 

ADalyte 

, 

Total Dissolved Solids (TDS) 

Note: DEP Certificatfon Ds 32-00382 

Analyst 

MS 

MAD 

Analysis 

Date 

1110512008 

11/07/2008 

SampleID#: 

Sample TYPe: 

·Sample Source: 

. Sampler: 

aient Sample ID: 

Sample 

Result 

139.5 

506 

Approved By: ~;r.t:E!S~'7"""""-';E=.;.~+ .......... ;-:-;::;;:--:-c-~ Jonathan Kon~ Technical DirectDr 

0831365 

Waste Water 

Composite 

CLIENT (Client) 

Effluent 

Units Methoi! 

mgIl SM4500cIC 

mgIl SM2540C 

MDL 

1.0 

25 

IND-NDt Delected 

Pagel of 1 
.,I.,;,J. ~ ".L.I.'\:.V.L "'.LY~.L "I ~.n..J.." ":'.L!I.l.l.. v .L~.L!I LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE __ OF ---.:..; 

HEADQUARTERS: ~ SOUTHERN DMSION: 

12D3 Phll.delphle SL 1278 aenUeyvllie Road D " . Indiana, PA 157Dl Van Voorhis, PA 15366 

(724) 4B;l·TEST (724) 258-TEST 

(724) 485-4209 17M) 25a.8378 

FOR INTERNAl. /Jl ORATORY 

SampleTypa 

Sample Identification ESL# Composite I Gmb Matrix # of Containers Container Type Analysis Requested 

Date anlarr Time anlorf Date nme PraservaUva 

Innuent C"iL \ -~, •. :~~:::: ....... -::::::.. WVV 1 Pla.U. ~lIer 'Total Dissolved Solids, Chloride -~ _... ....... none 

Gril I~, '- _ ~ . , .. ---,.~._ ....... --_......... . WVV 1 Plastlo Uler Total Dissolved Solids Chloride I-~r~ _................ ... ... _ ........ - non.. I! 

Primary Effluent I.'R_ '\ ~ '0 "'. -...... --... ~::._.. _ ...... _-:::::.. WVV , Plasll. Uter Total DI .. olved Solids, Chloride I 

r "-:) 1 .c,tnl _"'--' ..... - nana 

Holding Tank - ... -::~:::: .............. :::::::.. WW 1 PlasUe Lifer Tolal Dissolved Sonds. Chloride __._ .... nona 

Effluent DK I ~ ~ I - ... -~ ...... ~;... .-~--.. - ... ~.. WVV 1 Plastic Uter Tolal Dissolved Solids Chloride I-~I CoIn' ............ -... • ... _.-........ nona t 

I -I 

, 

THE UNDERSIGNED ,.URCKASER ':1 EBY AGKCt;ti 0 PA BERvICECIVIRI: e& ON ACCOUNTS OVER31 DAYS OlD, _ rOJ8Cl ",OLes: 

1, 1lm&I!&ERVICE CHARGES WD.l.ACCRUEATTHERATE OF1 'lIZ'" PER MaNnI (18% PERANNUMQR THe'MAXlMUM AUOWED BY LAW" , 

~ ntE UNOERBIGNED ,URetlABER AGREESTO PAY.'NTH!I!V!NT HIS ACCDIJIIl' "COMES DEUNOUI!NI' ANa IS TURNED OVER TO ANY Natural' Gas Water Study 

ATrORNJiY FOR CQU.SCTJON, REABONABLEATTORNE'l'S fEES PLUll'ALL coURT AND ATTENDANT COIJ.ECTlON COSTS. 

P A 'fi#jj.,h~~ 11"~-4Y 1/(/jJ ~ CompanylName: McKeesport Municipal Authority 

SBmpI.~ By: (SI,na",;:,!..-..1 Dale! 11me '7 /,4 / / LN/~I,X~\.0 11_.?~g /lOt) _ /( /~ l(/$'/o1, /J;J!J CDnlaciPerscn: ..!:M~s",.!::Kr!!;,ls~t1~D~ica~, ~rl~o _____ _ 

IR.~)Il"d.7l~'um) 08",. -R8r Iv.. y: ISIgmo' ... ) I 001011 TIme 

IL 'AC, -0-'fl'kJ? /t:fj l«nltPA ('lAid ll- ll-n';o I CI<. I Address: 100 Atlantic Avenue 

RelinquIshed By: IS', .. w .. , 'Ca(e! TIm. ReceIved y: ,Sign"""') Cate! TIm. McKeesport, PA 15132 

Rsllnqulshed ay: (sIgnalUre) Dale! TIm. Race""'d By: IS"nalUra) Cale! TIme Phon.: (412) 673-9701 xii 

CHAIN OF CUSTODY SEA~ BROKEN: Yes No Fax: (412) 673-4283 
i= ~,rV';i ~~-j~ifli1~ ~J i l:. i .. I. ..,_i •... 

_ ...... _ 

SERVICE LABORATORIES, INC. 

·803 Philadelphia street. Indiana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

~ame: McKeesport Municipal Authority 

Attn: Mr. James Degnan 

,ample Start Date: 

,ample End Dale: 

leI:eipt Date: 

loporlDate: 

,ample Site: 

Chloride 

100 Atlantic Avenue 

McKeesport, PA 15132 

Ili212008 11:00 AM 

11/312008 11:00 AM' 

1114/20084:26 PM 

11110/2008 

Natural Gas Water Study 

Analyle 

Total Dissolved Solids (TOS) 

Note: DEP Certification is 32"()0382 

Analyst 

MS 

MAD 

SampleID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date ReSnJt 

11105/2008 107.5 

11107/2008 413 

Approved By: --"=:~",~,-+-,,,~:,;;.::::...,;,~:....,:-"""-.,.:-;;:;;,--:-__ JOJll1than Kon. Technical DlrecJor 

0831358 

Waste Water 

Composite 

CLlENT (Clieut) 

Influent 

Units Method 

mgll SM4500CIC 

m!¥l SM2540C 

MDL 

1.0 

25 

lND=No! Dek<:!cd 

Page 1 ofl 
i--INVii#nr~fui Fi',iT4 i _ 'II 11' •• "_ ... i'r ••• 'i ..... 

3ERVICE LABORATORIES, INC. 

·803 Philadelphia Sireet, Indiana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

'iame: McKeesport Municipal An1hority 

Attn: Mr. James Degnan 

Sample W/;!: 

Sample Type: 

Sample Sonrce: 

Sampler: 

,ample Start Date: 

lample End Date: 

100 Atlantic Avenue 

McKeesport, PA 15132 

111212008 11:00 AM Client Sample W: 

0831359 

WasteWater 

Composite 

CLIENT (Client) 

Grit 

Ieeeipt Date: 

Ieport Date: 

lample Site: 

Chloride 

,. 

111312008 11:00 AM 

1114120084:26 PM 

1lI1012008 

Na1llral Gas Water Study 

Analyte 

Total Dissolved Solids (TDS) 

Note: DEP CertificatiDn Is 32-00382 

Analyst Analysis Sample 

.Date Result 

MS 1110512008 96.1 

MAD 1110712008 433 

Approved By: --"'J~"'~±"'''''''-:;;:::~~+''''''-i-i';'''''-:--­ Jonathan Kot; Tecllnical Dfreclor 

. Units ;5 Method MDL 

mgll SM4500cIC 1.0 

mgll SM2540C 25 

IND=NDI Detected 

Page 1011 
roo Jt.JVi ,*f1NfiJi ri\J = ii I ....... , ...... _ ........ tl'w •• ". 

;ERVICE LABORATORIES, INC. 

803 PhiladelphIa street. Jndlana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

iame: McKeesport Municipal Authority 

Attn: Mr. James Degnan 

1ample Start Date: 

lample End Date: 

teceipt Date: 

leport Date: 

1ample Site: 

Chloride 

100 Atlantic Avenue 

McKeesport, PA 15132 

1112/2008 11:00 AM 

1113/2008 Il:OO AM 

111412008 4:26 PM 

1111012008 

Natural Gas Water Study 

Analyte 

Total Dissolved Solids (TOS) 

Nole: DEP Certificotion lis 32-00382 

Analyst 

MS 

MAD 

SampleJD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

1110512008 \04.9 

1110712008 411 

,. 

Approved By: --"'l~",~::;' c"~~"'-:;;~(-.':';'~:-'=;;",-,-,,..,..,-­ Jonathan Kan, Tichnical Director . 

0831360 

Waste Water 

Composite 

CLIENT (Client) 

PrimarY Effluent 

Units ' Method 

mgIJ SM4500CIC 

mgll SM2540C 

MDL 

1.0 

25 

~D=NDl Detected 

Page 1 011 
~ rJ\li i#,-jNfaJa ~ rJT 4 i 

......... ,_ .................. -

,ERVICE LABORATORIES, INC. 

803 Philadelphia Street, IndIana, PA 15701 

724)-463-TEST ,FAX (724)-465-4209 

Report of Analysis 

'ame: McKeesport Municipal Authoriql 

Attn: Mr. James Degnan 

lample Start Date: 

/ample End Date: 

teeeipt Date: 

teport Date: 

/ample Site: 

Chloride 

100 Atlantic Avenue 

McKeesport, PA 15132 

11121200811:00 AM 

111312008 11:00 AM 

111412008 4:26 PM 

1111012008 

Natural Gas Water Study 

Analyte 

Total Dissolved Solids (TDS) 

Note: DEP Certific.tiDn is 32-00382 

Analyst 

MS 

MAD 

SampJeID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

1110512008 98.6 

1110712008 452 

Approved By: ~'f.£J;~7h.~~"""--~,,-;;;~~"""'-:;,;::,;;' :-:c:,---- Jonothtm ICon. Tec!m;ca/ Director 

0831361 

WasteWater 

Composite 

CLIENT (Client) 

Effluent 

Units Method 

mgll SM4500CIC 

mgll SM2540C 

MDL 

1.0 

25 

jND=NOII1Clecled 

Page 1 of 1 
Jj,1'4 V lKU1'ollV.l...nl'4.lllL "J:!.K V l~P 

LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE_OF __ " 

HEADQUARTERS: 

1803 Philadelphia SL E.1: 

indiana, PA 15701 

(724) 463·iEST 

(724) •• 5-'1209 

FOR INTEIl1IJff:: 

SOUTHERN DIVISION: 

1278 BenUeyvlll. Road 

Van Voorhis, PA 15366 

(724l25S·TEST 

(724) ...... 7. 

rORYUSE'Oj 

D 

Sample Type 

Sample IdentlllcaUon ESl# « 

Innuenl p~\~ 

Grtt ~':2$1 Prtmary effluant ~\-.:~ 

Holding Tank ~ effluent F{l ... .,......., 

...... , 

t1 PAV_ IN '1'HE 

~;oj 

By: (SI9l'lIlt~ 

Dale/lima 

t R!;AL ICHAINOFCL .. _----' Yes No 

Grab Matrix' 

Date TIm. 

WoN 

........ WoN 

ww 

WoN 

,.~.I wvJ 

- , 

-

~IIIUUOR.' 

DEUNQUENT AND IS TURNED 0VJ!fI; 1"0 ANY 

# of Containers 

1 

1 

1 

, 

, 

Container TYpe 

PlasUo Uler 

non. 

BsUci: 

no .. 

non. 

BsUci: non. 

iOsiiCi: 

'na.~ 

It'roJ8Ct NDte&. 

Analysis Requested 

Total Dissolved SOlids, Chloride 

Tolal Dissolved Solids, Chlortde 

Total Dissolved Solids, Chloride 

'Total Dissolved Solids, Chloride 

Total Dissolved SOlids, Chlortde 

Natural Gas Water Study 

~ Company/Name: , McKeesport Municipal AI 

";;;~~~=:'_~_-4J~6~(;j.J~Wrf"-::-.!./~J.!..:!.?=:O~ Contact Parson: .!:M~s!:. • .!,!K;,::ris:ti:..::D:,::lc::::a::.:rl::.o -------1 ~Recelve By: (8Ign.1U1'II) 0 eJ TIme 01rJ?'. c.f4,l II-y'-OY' I G: Ztl AM._... inn 

Recelveli By: (SlgnDlure) Datal TJme , PA1!:it32 

tteK;BIVed By: I Datal l1me IPhone: 

Fax: 

(412) 673·9701 x11 

(412) e 

--
I-fJVi ~r:;fd!\;i i= fda i .... y •• ,,_ ............. ,.. 

,ERVICE LABORATORIES, INC. 

803 PhOadelphla street, Indiana, PA 15701 

. 7241-463-TESTFAX (7241-465-4209 

Report of Analysis 

\fame: McKeesport MWlicipaJ Authority 

Attn: Mr. James Degnan 

, iampl. Start Date: 

lampl. End Dat.: 

leceipt Date: 

teport Date: 

lample Site: 

Chloride 

100 Atlantic Avenue 

McKeesport, PA 15132 

llf312008 11:00 AM 

11/412008 11:00 AM 

1114120084:26 PM 

1111012008 

Na1Ural Gas Water Study 

Aualyte 

Total Dissolved Solids (TDS) 

t!l!!!!; DEP CertifiClltioo Ns 32-00382 

Analyst 

MS 

MAD 

SamplelD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample m: 

Analysis Sample 

Date Result 

1110512008 101.8 

1110712008 430 

Approved By: --'=1'-q'.,.;ih.::±:''''-'i2''-;;;'~-+'''''"'-i=i-'''''''''''''-­ Jonalha(l Kon, Teclmical Director 

0831353 

WasteWater 

Composite 

CLIENT (Client) 

Influent 

Units , Method 

mgII SM4500ClC 

mgll SM2540C 

MDL 

1.0 

25 

fD=Not Detected 

Page 1 of 1 
t: t~Vi KOt" rv, t t"iAL 

5ERVICE LABORATORIES, INC. 

803 Philadelphia street. Indiana. PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

~ame: 

lample Start Date: 

lampl. End Oat.: 

~eceipt Date: 

leport Date: 

Iample Site: 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue. 

McKeesport, pA 15132 

111312008 11 :00 AM 

111412008 11 :00 AM 

111412008 4:26 PM 

1111012008 

Natural Gas Water Study 

Analyte Analyst 

MS 

Total Dissolved Solids (TDS) MAD 

Note: DEP C.rtificnllon lis 32-00382 

SampleID#: 

Sample Type: 

Sample Sonree: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

1110512008 108.2 

11/0712008 441 

Approved By: ~1L'i',:"~::±,,,,'"""'-:,;:::=-,;;:~':i'''''''-~~=::--­ Jonathan IWn, Technical Director 

0831354 

Waste Water 

Composite 

CLIENT (Client) 

Grit 

Units Method 

mg/J SM4500CIC 

mg/J SM2540C 

MDL 

1.0 

2S 

IND=NOI Dotccl<:il 

Page 1 of1 
i-;--J\j; ~OtJ tu; i= N =.6 i .... wi., .............. 1l. 

5ERVICE LABORATORIES, INC. 

803 Philadelphia street, Indiana, PA 15701 

724)-463-TEST . FAX (724)-465-4209 

R'eport of Analysis 

~ame: 

~ample Start Date: 

lampl. End Date: 

l.eceipt Date: 

l.eport Date: 

lampl. Site: 

. 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

111312008 11:00 AM 

11/41200811 :00 AM 

11/412008 4:26 PM 

1111012008 

Natural Gas Water Srudy 

Analyle . . Analyst 

MS 

Total Dissolved Solids (1DS) MAD 

Note: DEP Certification is 32-00382 

SamplelD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client SampIe ID: 

Analysis Sample 

Date Result 

1110712008 13187.0 

1If0712008 23100 

Approved By: -"1"""Ei~:,c;~;2~~"':-::~~;';--:--­ Jona/han Kon, Technical DirectDr 

0831356 

WasteWater 

Composite 

CLIENT (Clientr 

Holding Tank 

Units Method 

mgll SM4500ClC 

mgll SM2540C 

MDL 

1.0 

25 

INlFNDt Deteotcd 

Pagel.fl· 
r= tJVi ~1-)tJ ';viS ~t~T Ai c. 'II 11' •• , _. 'II. 11' i •• 'II.. .... 

5ERVICE LABORATORIES, INC. 

803 Philadelphia SJreet. Indiana. PA 15701 

724)-463-lEST . FAX (724)-465-4209 

Report of Analysis 

liame: McKeesport Municipal Authority 

Attn:· Mr. James Degnan 

lample Start Date: 

lampIe End Date: 

;teeeipt Date: 

iteport Date: 

lample Site: 

Chloride 

100 Atlantic Avenue 

McKeesport, PA 15132 

111312008 11 :00 AM 

111412008 11 :00 AM 

111412008 4:26 PM 

1111012008 

Natural Gas Water Study 

Analyte 

. 

Total Dissolved Solids erOS) 

Note: DEPCertification Is 32.00382 

Analyst 

MS 

MAD 

Sample IDfI.: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

1110512008 114.2 

11/0712008 454 

Approved BY:~~t!!~.!fJ~"""--;;::::=-;;;'~~~~~-,-__ JOnoJhan KOIl, Technical Director 

0831355 

Waste Water 

Composite 

CLIENT (CUent) 

Primary Effluent 

Units Method 

mgll SM4500CIC 

mgll SM2540C 

MDL 

1.0 

25 

INJ>oNot Detected 
i=-tJV! 

_. ~rjNft,4I=NT Ai ,. ... .., _. ,. ..... _. ,. .. 11._ 

SERVICE LABORATORIES, INC. 

1803Phlladelphla Street Indiana, PA 15701 

724)-463-TEST FAX(724F465-4209 

Report of Analysis 

"lame: 

Sample Start Date: 

Sample End Date: 

Receipt Date: 

Report Date: 

Sample Site: 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

111312008 11:00 AM 

111412008 11 :00 AM 

111412008 4:26 PM 

1111012008 

Natural Gas Water Study 

Aaalyte Analyst 

MS 

Total Dissolved Solids (TOS) MAD 

Note: . DEP Certificillion lis 32-00382 

SamplelD#: 

Sample Type: 

Sample Sonrce: 

Sampler: 

Client Sampie ID: 

Analysis Sample 

Date Result 

1110712008 156.9 

1110712008 493 

Approved BY:-"'i1-C;lta.;th.",~IlA.-.-<;;::::~~:";:""'-~:;;,,--= __ . Jonathan Kon. Technical Director 

0831357 

WasteWater 

Composite 

CLIENT (Client) 

Effluent 

Units Method . 

mgII SM4500CIC 

mgtl SM2540C 

MDL 

1.0 

25 

(ND=Not Dcletled 

Page 1 011 
..L.!IJ..,. 'Y .1.1'-"-.IJ. ... .LTLJ..:I.L.,. .I....£'1.1...:f &:;J.l..!I.J.\.. Y ~'-'~ 

LARO"RATORIES. INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGe __ OF __ ._ 

HEADQUARTERS: 

lB03 Philadelphia Sl t;Q Indiana, PA 10701 

(724) •• 3-TEST 

(724) 46.-4200 -

FOR, 

Sample Identification ESl# 

Influent F"20J-=30 

Gril ~(t") '2-\3 \ 

Primary Effluant P~1J3Z Holding Tank 1~2'~ Effluenl IG~~/..jj 

IV'HESE' 

J17C· 

SOUTHeRN DIVISION: 

1276 BenUeyvIIle Road 

Van Voomls, PA 15366 

(724) 25I1-TEST 

. (724) 2511-8376 

bRATORYUSEONLY 

D 

!lampl.Type 

GraJ>. ~_ate_..L.....T1me 

....... 

11 DAYS 0l.0. 

Matrix # of Containers 

ww 1 

ww 1 

ww 1 

-

WW 1 

ww 1 

H (18% PSRANNUM CR1HEMAXlMUM AU.OWED BY LAW.) 

ll_"CllON COSTS, 

u-ll~LiJ If-T-o<g I U";3;.o 

(0 

Rrr.I""'lBy:}al~ .. -"'.Z-"1 J II DelelTIme 

l!TYl\/~ ~ ll-h?J ~a'ff Q! t/2 "' 

ReceTveb By: (5IgnaILlf1l) Dale! TIme 

d By: 

=1"":1 

UBIB' -lime RBC8IVBd By: , 

_No 

UalSl' 11m!:! 

(SEAt _Yea 

Container Type 

Pl'8IIlIMIUve 

Pla.UeUler 

..... Plastic Liter 

"""" Plastic Lller 

n ... 

nana 

PlasUe Liter 

nona 

AnalysIs Requested' 

Total DlssolvadSollds, Chlorida 

Total DIssolved Solids, Chloride 

Total Dissolved Solids, Chloride 

Total DIssolved Solid., Chloride 

Tolat Dissolved Solids, Chloride 

~ 

Natural Gas Water Study 

:l person: 

t"nona: 

IFax: 

Ms .. Kristi I "11,...~rlr'l 

100 AII,mtl" Avenue 

, PA 15132 

(412)-673-9701 x11 

(412) 673-4283 
c FfJVi~l-RNilu'i-N 141 ....... ,_. wf\ .......... . 

SERVICE LABORATORIES, INC. 

1803 Philadelphia street Indiana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

lIame: McKeesport Municipal Alithority 

Attn: Mr. James Degnan 

SampleID#: 

Sample Type: 

100 Atlantic Avenue 

McKeesport, PA 15132 

1If4l2008 11:00 AM 

Sample Source: 

Sampler: 

,ample Slart Date: 

,ample End Date: 

Client Sample ID: 

Receipt Date: 

11/512008 9:00 AM 

11110/20089:31 AM 

Report Date: 11113/2008 

,ample Site: Natural Gas Water Study #3 

Aualyte ' .. - ,. Analyst 

Chloride MS 

Total Dissolved Solids (TOS) ... CLM 

t!l!.!!!i. DEP Certifie.tion Is 32-0038Z 

Analysis Sample 

Date Result 

1111212008 103.0 

1111112008 415 

Approved By: ~'f-C!E!S~~~/lA.-..~,,--;;;~~"""""~=:::--'-__ _ Jonathan Kon, TechnIcal Direc/or 

. 

0832130 

Waste Water· 

Composite 

CLIENT (Client) 

Influent 

Units Method 

mgIl SM4500ClC 

mgll SM2540C 

MIlL I 

1.0 

25· 

IND=NO' Deteeted 

Page 1011 
;: ii. ='i:. I"'; ===~ =- = ~ ii po &. 5==-.ii. ;; i-IoU u i iiFli. Ji\,i IU; ... ni Ii A. Ii ..... ,. .. "._ .................. _. 

5ERVlCE LABORATORIES, INC. 

1803 Philadelphia S1reet, Indiana, PA 15701 

724)-463-TESl FAX (724)-465-4209 

Report of Analysis 

lIame: 

>ample Start Date: 

~ample End Date: 

Reeeipt Date: 

Report Date: 

~ample Site: 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

11/41200811:00 AM 

111512008 9:00 AM 

1 Ifl012008 9:31 AM 

1111312008 

Natural Gas Water Study #3 

Analyte . Anatyst 

MS 

TotalDissolved Solids (TDS) CLM - .... 

Note: DEP Certific.tion ils 32"()0382 

SampleID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Resnlt 

1 1f1212008 104.4 

1lI1112008 452 

Approved By: ~~~1.2~~~~~~':.::"""-;:.s:~.,.,--­ Jonathan Kon. TechrdcaJ l!ire.ctor 

0832131 

Waste Water 

Composite 

CLIENT (Client) 

Grit 

Units Method 

mgll SM4500CIC 

mgtl SM2540C 

MDL 

1.0 

25 

IND=No\ Deteo1cd 

P;lge 1 of 1 
~ i\lViYi-l~Jfr..A ~ NT li. i .1 .. 11' .i"_ .... 11' .......... . 

,ERVICE LABORATORIES, INC. 

803 Philadelphia S1reet, Indiana, PA 15701 

724)-463-TEST FAX {724)-465-4209 

Report of Analysis 

~ame: 

lampl. Start Date: 

lamp!. End Date: 

~eeeipt Date: 

~eport Date: 

lample Site: 

McKeesport Muoicipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

llf412008 II :00 AM 

111512008 9:00 AM 

1, 1110120089:37 AM 

1111312008 

Natural Gas Water Study #3 

Analyt. Analystl Analysis 

Date 

··Chloride MS 11112/2008 

Total Dissolved Solids (TOS) CLM 11/1112008 

Note: DEPCertificatiDn #s 32-00382 

SampleID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

I Sample .. . 

Resnlt 

9603.2 

19400 

Approved By: --""~"'~'±""'""'--';E=-;;;:~,+"""-;.:..;::;;;-. =,--__ Jonathan Konj Techn;cal Director 

0832133 

Waste Water 

Composite 

CLIENT (Clieat) 

Holding Tank 

Units Method 

mgIl SM4500CIC 

mgIl SM2540C 

MDL 

1.0 

25 

Page 1 of1 
i.-r-J\ij i#(-lN f\.4~ r-J ii 4 i ;;.,. ........ _.,. ....... ,. •• "&. 

3ERVICE LABORATORIES, INC. 

803 Philadelphia Street, IndIana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

'lame: 

'ample Start Date: 

,ample End Date: 

Ie.eipt Date: 

leport Date: 

,ample Bite: 

Chloride 

McKeesport Municipal Authority 

Attn: Mr. James Degnan 

100 Atlantic Avenue 

McKeesport, PA 15132 

111412008 11:00 AM 

1 11512008 9:00 AM 

11110120089:37 AM 

1111312008 

Natural Gas Water Study #3 

Analyte Analyst 

MS 

Total Dissolved Solids (TOS) CLM 

Note: DEP Cc:rlilicatioo C. 32'()0382 

SampleJD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client SampleJD: 

AaalysiS Sample 

Dnte Result 

1111212008 122.8 

1111112008 474 

Approved By: ~tL!?:a:7;~~i-!!!:""'"-~=-;;:~~.!.:"'"'-;'::. ~;-c,---­ Jonalltan /(on, Tee/mlcal Director 

0832132 

Waste Water 

Composite 

CLIENT (Client) 

Primaty Effluent . 

J 

Units Metbod 

mgIJ SM4S00CIC 

mgIJ SM2S40C 

MOL 

1.0 

2S 

IND=Nol Deleclcd 

Page 1 of 1 
~~jTAi .......... 

,ERVICE LABORATORIES, INC. 

803 Philadelphia Street, Indiana. PA 15701 

724)-463-TEST FAX (724)-465-4209·· 

Report of Analysis 

~amc: McKeesport Municipal Authority SampleID#: 

Atbt: Mr. James Degnan Sample Type: 

100 Atlantic Avenue Sample Snurce: 

McKeesport, PA 15132 Sampler: 

lampl. Start Date: 111412008 11 :00 AM Client Sample ~: 

lample End Date: 1 11512008 9:00 AM 

receipt Date: 11/1012008 9:37 AM 

repnrt Date: 1111312008 

lample Site: Nataral Gas Waler Study #3 

Analyte Analyst Analysis Sample 

Date Result 

Chloride MS 1111212008 181.6 

Total Dissolved Solids (TOS) CLM 1111112008 582 

Note: DEP CertificntioD #Is 32..00382 

Approved By: ~;W;~~S:!:=~~. ,,-:;::~:.:r::"""--~~=::---­ Jonathan Kon, Technical Director 

0832134 

Waste Waler 

Composite 

CLIENT (Client) 

Effluent 

Unit;; Method MDL 

mgll SM4S0.0ClC 1.0 

rog/I SM2540C 25 

!ND'"JllDI De.ected 

Page 10[1