# KLH 

# <<:'I ENGINEERS, INC.



### November.26, 2008 Ref. No. 220-02"003 Sent via: Hand Delivered Mr, Kevin Halloran, Water Quality Specialist Supervisor Water Management Pennsylvania Department ofEnvironmental Protection 400 Waterfront Drive Pittsburgh, PA 15222-4745 Dear Mr. Halloran: Municipal Authority ofthe City ofMcKeesport Technical Evaluation on Oil and Gas WellWastewaters As Required Under the PADEP Administrative OrderDated October 23, 2008 51 73 CAMPBELLS RUN ROAD PITTSBURGH, PA ,-S20S PHONE: 412-494- 051 [] ·F'AX: 412-494-0426 INF"O@KLI-!ENGINEERS.COM**WWW.KLHENGI~EERS'I?OM**



### Please find enclosed two (2) copies of the Teclmical Evaluation of the Impact of Oil and Gas Well Wastewaters on the Municipal Auth()rity ofthe City ofMcKeesport Wastewater Treatment Facility. This evaluation is a requirement of the Departments Administrative Order dated October 23,2008. Please contact me ifyou have any questions regarding this report. I can be reached directly at (412)_494-051O,extension 116. Very truly yours,

### KLHENGINEE.RS,~.~**~**

# ~~ Michael C. Sherrieb

Enclosure(s)

cc: Mr. Joe Rost, Municipal Authority ofthe City ofMcKeesport, 

### wi (2) enclosures Steve Greenberg, P£., KLH Engineers, Inc., 

### wi enclosure 

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## CITY OF McKEESPORT ALLEGHENY COUNTY, PENNSLYVANIA TECHNICAL EVALUATION OF THE IMPACT OF OIL AND GAS WELL WASTEWATERS ON THE MUNICIPAL AUTHORITY OF THE CITY OF McKEESPORT WASTEWATER TREATMENT FAC·ILITY

. NPOES PERMIT No. PA0026913 NovEMBeR 2008

5173 CAMPBELLS RUN ROAD 

# KLH<<3: ENGINEERS, INC. PITTSBURGH, PA 15205·9733,-.,. t'/**l~** 

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### City of McKeesport Technical Evaluation ofthe Impact of Oil and Gas Well Wastewaters on the Municipal Authority of the City of McKeesport Wastewater Treatment Facility

Table of Contents

1.0 

### Purpose
......**~**

### ...................................................................................,............................................... 1 

### 2.0 Description ofMACM Treatment Processes
..........................,..................................................... 1 

### 3.0 Evaluation ofTotal Dissolved Solids and Chlorides on Process Units.,
.......................................3 

### 4.0 MACM Sludge Treatment and Disposal
................................................:......................................6 5.0 Summary ofConclusions
................................................:.............................................................7



### Tables Table 1.0
Appendiees AppendixA AppendixB AppendixC AppendixD Net Impact ofMACM Efiluent on Background Levels ofIDS and Chlorides

Oil and Gas 

### Wastewater Manifest Spreadsheet MACM Process Flow Diagram Detailing Sample Locations MACM Chloride and IDS Analytical Data Table 3-16 

### "Typical Composition ofUn treated Domestic Wastewater,"

,Metcalf& 

### Eddy, Third Edition; Wastewater Engineering AppendixE MACM BOD and TSS Inter Process Data and MACM Weekly Operations**~poru** 

### ' AppendixF MACM Sludge Analysis

City of McKeesport Technical Evaluation ofthe Impact of Oil and Ga.Well Wastewaters on the WastewaterTreabnent Plant November 2008 Ref. No. 220-02 1 

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### City of McKeesport Technical Evaluation ofthe Impact of Oil and Gas Well Wastewaters on the Municipal Authority ofthe City of McKeesport Wastewater Treabnent Facility 1.0 Purpose The Pennsylvania Department of 

### Environmental Protection (P ADEP) issued an Administrative Order to the Municipal Authority of the City of McKeesport on October 23, 2008. The

.Administrative Order sets forth a series of requirements prescribed to MACM, in order for MACM to continue acceptance of oil and gas well production wastewater for treatment and processing at the MACM Wastewater Treatment Plant (WWTP).The purpose of this document is to provide a written technical evaluation of potential impacts of oil and gas production wastewaters on the MACM treatmentprocess. 

### This evaluation

### will contain, as prescribed inthe Order; an evaluation of the 

### effects on each major unit process; an estimate of the maximum Total Dissolved Solids (IDS) that 

### will occur in each process; a description of measures employed by MACM to monitor and minimize adverse effects on biological processes; quantitative estimates on anticipated changes to effluent characteristics for each newpollutant identified; a description ofhow MACM 

### will assure that theWWTP sludge 

### will notbe classified ashazardous waste as a result of accepting this new waste stream, and any resulting constraints on sludge treatment and disposal. 2.0 Description of MACM Treatment Processes The MACM WWTP is a conventional activated sludge, secondary wa'stewater treatment facility. The plant 

### has a permitted hydraulically treatment capacity of 11.50 million gallons per day (mgd), although the facility Car) 

### hydraulically handle

### peak daily flows of 20;0 mgd. The MACM

.2007 Annual Chapter 94 Waste Load Management Report indicates the annual average flow to the WWTP in 2007 was 10.33 mgd. The maximum monthly average day flow was 14.64 mgd,

.occurring in March of 2007, and the minimum monthly average flow was·7.75 rrigd, occurring in October 2007.
. The Order requires MACM to immediately restrict the daily volume of oil and gas well production wastewater to 1% of the average daily flow. To comply with this requirement MACM has limited the daily volume of oil.and gas well production wastewater introduced into the"VWTI' to 1% oftheWWTP's forward flow rateon any given day. The MACM has the ability to completely control the rate at which the oil and gas Well production wastewater is introduced into the WWTP process. MACM achieves this process control by utilizing two existing aeration basins as holding tanks. Each basin has a working volume of 334,000 gallons, and currently servestoprovide excess treatment capacity. The waste is received and stored in the basin, aerated, and subsequently introduced into the WWTP process at a controlled rate no greater than 1% ofthe forward flow into the**facility~** 

### Storing the waste stream in the aeration tanks offers MACM the ability to analyze the waste for TDS and chlorides and determine mass loadings for these pollutants to the plant process. This 

### gives City of McKeesport Techni<;al Evaluation ofthe Impact of Oil and Gas Well Wastewaters on the Wastewater Treatment Plant November 2008 Ref. No. 220-02 1**KLH<'<~** ENGINEERS.• INC.'.-' MACM greater control over the actual loads applied into the process to assure the biological

. process is protected against shock loads and potential interference.

. MACM monitors each individual waste load received from oil and gas well production

wastewater sources. Included in this record is the date received at MACM; the hauling company transporting the waste to MACM; the Truck ID number delivering the waste to MACM; the well orpoint source from which the wastewater was generated;the quantity ofthe. wastewater received; the type ofwastewater as itrelates to the well drilling process; the current plant flow rate of the MACM WWIP at the time the waste is received; the level of chlorides in the wastewater received in (mg!I); the corresponding maSs load of chlorides in the wastewater received, and the pH of the wastewater received. 

### This data is recorded and stored in a spreadsheet format by MACM operation staff. The information contained in this spreadsheet will be filed with the MACM monthly discharge monitoring report (DMR) to PADEP as required under the Order. A copy of the hauling records and chlorides data is contained in Appendix A of this report MACM's monitoring of chloride levels in the received wastewaters and MACM's ability to control the quantity and rate at which these wastewaters are introduced into·the treatment process provides MACM's operations staff with a level of control to protect the biological process from upset, and control 

### theleveld passthrough to assure water quality criteria is met. MACM employ's Pennsylvania state licensed operators who monitor, regulate and control all aspects of the WWIP process twenty four hours a day, seven days 

### per week, 

### fifty two weeks peryear. The professional training and experience of these state licensed wastewater treatment plant operators prOvides MACM another level of assurance the introduction of oil and gas well wastewaters can be conducted, monitored and controlled to achieve the desired water quality

.limits while preserving thebiological treatmentprocess. The MACM facility is comprised of the following treatmentunitprocess:

• Mechanical screening • Gritremoval • Aerationbasins • Primary clarifier settling tanks • Activated sludge process 

### tanks • Final clarifier settling tanks • Aerobic digestion • Sludge thickening tanks • Sludge dewatering (beltfilter press) • Chlorine disinfection system Oil and gas well production wastewaters received and stored in the aeration 

### tanks is drained to the raw sewage wet well at a rate no greater than 1% of the plants daily forward flow. 

### This combined waste stream is screened, and receives grit removal prior to discharging into the City of McKeesport Technical Evaluation ofthe Impact of Oil and Gas Well Wastewaters on the WastewaterTreabnent Plant November 2008 Ref. No. 220-02 2 K 

### LH**~'!.!IW!** 

### .. ENGiNEERS, INC.primary clarifier settling 

### tanks for solids removal. Solids which are removed during the

. primary settling process are sent to the dewatering facilities. The digested sludge is monitored

quarterly for all local limit parameters as contained in the MACM, EPA approved pretreatment program. MACM also conducts an annual priority pollutant scan onits produced sludgefor all
. Form43 listed parameters. After the primary clarification settling tanks the plants flow enters the activated sludge tanks. During this process the plant operators closely monitor control points for SludgeVolume Index 

### (SVl), and Food to Micro-organism Ratio 

### (FIM). By monitoring these control pojnts regularly the plant operationsstaff can determine 

### if any adverse effects to settling or treatmentcapability are observed. If any adverse effects were noticed the operating staff would immediately stop the introduction of the oil and gas well wastewater from the pre-aeration holding 

### tanks and stabilize the process. A biological microscopic eva,luation is also completed daily by the operating staff. Samples of activated sludge mixed liquor are collected and analyzed under a highpowered microscope to determine the overallhealth ofthe biological system•

..

When the forward flow leaves the activated sludge process it enters the final clarifier settling tanks. Here the mixed liquor activated sludge is settled and separated from the liquid stream and retuined to the activated sludge tanks via the return activated sludge pump system.

. Periodically, as required to maintain the des.ired sludge age and to maintain proper settling

characteristics; sludge

### willbe wasted to and aerobic digesters. After final settling the treated water is conveyed tothe chlorination system wnere pathogenic disinfection via chlorine gas injection is completed. After chlorination the flow 

### is transferred into the chlorine contact tanks to provide sufficient contact time for the disinfection process to be completed priorto discharge to the Monongahela River. 

### 3.0 

### Evaluation ofTotal Dissolved Solids and Chlorides on Process Units MACM began to collect 24 hour flow proportional composite samples to evaluate the levels of chlorides and IDS which occur under normal waste load conditions and which occur during days which the WWTP is processing oil and .gas well wastewater. MACM selected five sampling locations as key areas within the WWTP to monitor IDS and chloride levels. These sampling points can be seen on the MACM Process Flow Diagram included in Appendix B, which shows the location of each of the five sampling points. A complete listing of the sample results for IDS·and,chlorides at all five sampling locations is contained in Appendix 

### C of this
. report. The first sampling location monitored.by MACM is the influent sampling point. The purpose of collecting the influent sample is to provide MACM with the typical level of IDS and chlorides which OCcur in MACM's influent, without any contribution from oil and gas well wastewater. During the week long testing the influent test results for both IDS and chlorides were relatively consistent. IDS values in the influentranged from 399 mgll to 446 mgll. These levels of IDS would indicate concentrations that would be found in typical medium strength City 01 McKeesport Technical Eyaluation 01 the Impact 01 Oil and Gas Well Wastewaters on the Wastewater Treatment Plant November 2008 ReI. No. 220-02 3

### sewage. Chloride levels in the influent samples ranged from 101 

### mgll to 122.5 

### mgll. Chloride levels of 100 

### mgll are considered to be a strong concentration in untreated domestic sewage, according to Table 3-16, ofMetcalf and Eddy. Third Edition. Wastewater Engineering. Table 3- 16isincluded inAppendix 0 ofthis 

### report. . In 

### order to determine levels of chlorides and IDS in each of the process basins, 24 

### hour flow proportional composite samples were collected and analyzed at the grit tank, 

### primary clarifier effluent, and the treatmentplant effluent The analyticalresults for the five sample locations are listed inAppendix C. 

### Flow proportional composite samples were also taken and analyzed for oil and gas well waStewaters received and stored in the aeration holding tanks. Samples taken in the holding
. tanks indicate the strength of the oil and gas well wastewater being introduced into the treatmentprocess. The results ofthe samples taken and analyzed through the 

### MACM WW1P indicate that there is no red-qction in.concentration of TOS and chlorides through the plant processes. This is not unexpected as conventional sewage treatment facilities are not designed to remove dissolved constituents such as IDS and chlorides. Although there is no apparent reduction in IDS or chloride concentrations through the treatment process, the introduction of oil and gas well wastewaters haS 

### had no effect on the treatment ability of the 

### MACM system to trEiat and remove conventional pollutants such as Biochemical OxygenDemand (BODs) and Total Suspended Solids (TSS)
.. 

### Appendix E. 

### contains inter-process data for BODs and 

### TSS removals through the 

### MACM process during the introduction of oil and gas well waste water and also 

### on days which no oil and gas well

. wastewater was introduced. The data contained in Appendix E Shows the percent removal of

BODs during the November 1, .2008 

### to November 7, 2008 

### testing period waS consistently observed between 

### 95% and 

### 98%, and the percentremoval of

### TSS averaged 

### 91%. These levels of removal exceed the minimum 

### required removal rate of 

### 85% for these pollutants and provide a good indication the process is performing well during the introduction of oil and gas well wastewater into the process. Microscopic analysis conducted daily on the activated sludge mixed liquor has shown that the biological process has remained healthy and viable during the introduction andprocessing ofoil and gas well waste waters. To evaluate the potential impacts that the discharge of IDS and chlorides may have on the Monongahela River, an evaluation utilizing the same analytical approached 

### MAcM used in conducting their Head Works Loading analysis and development of Local Limits 

### has been utilized. The following Monongahela River flows were utilized in the 2005 

### Head Works Loading Evaluation for the DevelopmentofLocal Limits at

### MACM.
.**~**

City of McKeesport

.Technical Evaluation ofthe Impact of Oil and Gas Wen Wastewaters on the Wastewater Treatment Plant November 2008 Ref. No. 220-02 4Chronic Evaluation: (g.10 = 350 cfs, or 226 million gallons per day Acute Evaluation: Qt'IO

### =494 cis, or 319 million gallons per day HumanHealth: Harmonic Flow = 2860 cfs, or 1,847 million gallons per day By utilizing theMACM effluent data collected and analyzed for IDS and chlorides 

### we can**d~temtine** the effective impact these levels have on the Monongahela River during the above referenced .flow'periods. We 

### will analyze the impact of the effluent IDS and chlorides at the maximum effluent levels and at the average levels recorded during the one week testing period and apply these loads.to the various river flows to detemrine the net effect MACM's effluent has on the Monongahela River. Average IDS level = 516mg/I Maximum IDS level

### = 582mg/I AverageChloridelevel

### = 152mg/I Maximum Chloride level

## = 185.7 mg/I
. Applying each to the following formula the net effect for each can be determined atthe various river flows. Effluent cone. (mgLU x Plantflow rate (mgd) 

### =Net effect to background level(mg/I) Monongahela River Flow Rate (mgd) Table 1.0 NetJnipact ofMACM Effluent on Background Levels ofIDS and**Chloride~** Net Increase 

### inReceiving Water Levels Max Avg MaX Avg IDS IDS Chlorides Chlorides (mg/I) (mg/I) (mg/I) (mg/I) River Flow (mgd) 582 516 185.7 152 (g.10 226 19.31 17.12 6.16 5.04 Qt.IO 319 13.68 12.13 4.37 3.57 Harmonic 1,847 2.36 2.10 0.75 0.62

, Note: Average dailyplantflow of7.5 mgd utilized' for calculation
City of McKeesport Technical Evaluation ofthe Impact of Oil and Gas Well Wastewaters on the Wastewater Treatment Plant November 2008 Ref. No. 220-02 

### s·**KLH<~~ ENGINEE~S.INC.** 

### Table 1.0 clearly shows the resulting increase in levels of TOS and Chlorides attributable to the MACM effluent on

### the Monongahela River during the mostcritical (Q.,.

### river flow is very small, less than 20 mgll fot TOS, and less than 7 mgll for chlorides. The monthly average limit for
. potable water supply criteria in source waters for TOSis a monthly average of 

### 500 mgll and a maximum value of 750 mgll. The net increase in TOS of 20 mgll under (Q.l. 

### conditions is only

. 4% of this limitation and only 2.67% ofthe maximum allowed. The limit to meetpotable water

supply criteria for chlorides is 250 mgll in source waters. The net.increase from the MACM effluent of6.16 mgllunder (Q.IO 

### conditions is 2.5% ofthe limit. As 

### a result ofthe data presented and the analysis conducted it is the opinion ofKLH Engineers, Inc. that the introduction of oil and gas wastewaters under the conditions prescribed above causes no adverse effects to the MACM·biological treatment process and no**disc~ble** 

### impact on the receiving waters ofthe Monongahela River. 

### 4.0 MACM Sludge Treatment and Disposal The MACM currently employs two (2) aerobic digesters to digest and stabilize biologically active waste solids for its treatment process. Once stabilized the solids are thickened and dewatered via a belt filter press. 

### Dry, stabilized cake solids are then hauled to the Waste Management (Monroeville) landfill for final disposal. TheMACM as previously mentioned, has an EPA approved Industrial Pretreil.tment Program; Under this pretreatment program regular testing of the plant influent, effluent and sludge is conducted and evaluated for potential causes of interference ofthe biological processes. Annually the MACM also conducts a Form 43 analysis to maintain its permit with the landfill fro sludge disposal. To determine 

### if the acceptance of oil and gas well wastewaters poses any harmful effects to MACM's current method· of sludge stabilization and treatment a comparison of analytical data prior to the acceptance of oil and gas well waste water was and analytical data obtained 

### after the acceptance of oil and gas well wastewater was conducted. 

### This data is contained in Appendix F of this report. Comparison of sludge data prior to the acceptance of oil and gas well wastewaters and sludge data after the acceptance of oil and gas well wastewaters indicates there is little change in the consistency, or quality of sludge at MACM. Should levels of any monitored substance in their sludge begin to increase to a level which would cause the sludge treatment or disposal practices tei be come atrisk MACM will limit or haltreceiving oil and gaswell wastewaters contributing to this increase. MACM sludge is screened for radioactivity at the Waste. Management landfill prior to acceptance, but because low level, Normally Occurring Radioactive Materials (NORM) are known·to be present in oil and gas well waste waters in certain 

### areas, MACM has purchased

. Geiger Counter to monitor all wastewaters received from oil and gas well operations for NORM. MACM will 

### monitor and test each load received for NORM and will reject any load determined to contain such materials. In addition, MACM requires that 

### the generator and hauler certify that the wastewaterbeing received is notclassified as hazardous waste. City of McKeesport Technical Evaluation ofthe Impact of Oil and Gas Well Wastewaters on the Wastewater Treatment Plant November 2008 Ref. No. 220-02 6 K L H 

### 4S"!iW'""

. ENGINEERS .• INC.

### By continuing to closely monitor their sludge for metals, PCB's, Herbicides, Pesticides, Volatile, Semi-volatile Organics, and NORM, MACM: will be able 

### to assure that the current methods utilized 

### to treat, stabilize and dispose of their sludge are protected and maintained and that their sludge will notbe cIassifiedas a hazardous waste_ 

### 5.0 Summary of Conclusions In 

### conclusion, the current program for the acceptance of oil and gas well wastewater as it is**curr~tly** 

### being conducted at the MACM: WW1P provides for boththe protection of 

### the MACM process, .and· 

### the protection of the receiving waters of the Monongahela River for its intended use; and will not adversely impact the level of Total Dissolved Solids or Chlorides in the Monongahela River. MACM 

### has· instituted record keeping, quality control and process monitoririg programs to assure it can sufficiently monitor the treatnient plantprocess, and the effluent water quality to meetpermit compliance.

City of McKeesport Technical Evaluation of the Impact of Oil and Gas Well WasteWaters on the Waslewater Treatment Plant November 2008 Ref. No. 220-02 7 

## -""'-=E KLH<..."-=_ ENGINEERS, INc.ApPENDIX A OIL AND GAS WASTEWATER MANIFEST SPREA[)SHEETDATE eO.MPANY TRUCK# WELL. .GALLONS TYPE FLOW,CHb08!ElSS4mgtLl,ChlLOR]DES.Ub.s.t ..•

### a!i!. 10/23/2008 Hawg 120 Equitable-Burr # 81 3780 Brine 7.2 165000 5202 7.70 10/25/2008 Hawg 114**Equitable~** # 511062 3780 Flow Back 15.3 120000 3783 6.72 10/27/2008 Hawg 120 Equitable-Burr # 81 3780 Brine 8.3 155000 4886 6.34 114 Equitable- # 511062 3780 Flow Back 115000 3625 6.76 10/28/2008 Hawg 114 Eq\.litable-511602 3780 Flow Back 7.2 115000 3625 6.56 117**Che$~eeake-626750** 3780 Flow Back 60000 1892 6.95 10/30/2008 Hawg 113 Equitable-ROA-60 3780 Brine 7.4 120000 3783 7.01 119 Equltable-511062 3780 Brine 120000 3783 6.63 120 csuitable.Burr # 81 3780 Brine 145000 4571 6.89 10/31/2008 Hawg 114 Equitable-511602 3780 Flow Back 7.1 95000 2995 6.81

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### ,;::)";~.'J. . :- ·11/3/2008 Hawg 113 Equitable-Burr #81 3780 Brine 6.7 155000 4886 7.70

11/4/2008 Hawg 114 Esuitable-511264 3780 Flow Back 6.9 145000 4571 6.13 11/612008 Hawg 117 Equitable-511264 3780 Flow Back 7.0 155000 4886 7.09 11/10/2008 Hawg 119 Equitable-Burr #81 3780 Brine 7.0 145000 4571 6.33 11/12/2008 Hawg 119 Equitable-Burr #81 3780 Brine 7.3 155000 4886 6.94 11/17/2008 Hawg 116 Chesapeake-627033 3780 Pit 7.6 40000 1261 10.09 101
. Chesapeake-627033 3360 Pit 40000 1121 9.91 103 Chesapeake-627033 3360 Pit 40000 1121 9.78 11/18/2008 Hawg 120 Equitable-Burr #81 3780 Brine 7.8 145000 4571 6.62DATE COMPANY TRUCK# WELL GALLONS ,TYPE ,FLOW CldL,OBJDES,!mglL)CHLQRlDES,(lbs.l, 

### ",R!i 10/23/2008 Huntley VT03 Altman 

### #3 4620 Frae 7.2 30000 1156 6.30 VT01 Altman 

### #3 4620 Frae 30000 1156 6.01 VT05 Altman 

### #3 4620 Frae 30000, 1156 6.63 10/24/2008 Huntley VT05 Altman #3 4620 Frae 7.6 20000 771 6.61 VT04 Weston #2!Lav #4 2940 Brine 90000 2207 6.40 VT02 Altman 

### #3 4620 Frae 20000 771 6.75 VT05 Altman #3 4620 Frae 20000 771 6.69 VT05 Altman #3 4620 Frae 20000 771 6.80 VT05 Altman #3 4620· Pit 25000 963 11.17 VT02 Altman #4 4620 Brine 120000 4624 6.59 VT05 ' Altman #3 4620 Pit 25000 963 10.99 VT02 Altman #3 4620 Pit 25000 963 10.67 VT05 Altman 

### #3 1680 Pit 25000 963 10.50 10/3112008 Huntley VT02 Altman #4/Stratigos #1 4620 Brine 7.1 70000 2697 6.74



### -**.:'~'::** ", -;**,~.** . "',
. ',-**·>.~;i::-:''-·:C-.,** 11/6/2008**Huntle~** VT05**Leben~ood#1** 4620 Frae 7.0 20000 771 8.06 11/7/2008 Huntley VT02 Blissman#5 4620 Frae 6.9 20000 771 6.74 VT02 Blissrilan #5 4620 Frae 20000 771 6.68 VT02 BUssman #5 4620 Frae 20000 771 6.99 VT02 Blissman#5 4620 Frae 20000 771 7.11 11/10/2008 Huntley VT02 Blissman #5 4620 Frae 7.0 35000 1349 4.25 VT02 Blissman#5 4620 Frae 35000 1349 5.00 VT02 Blissman#5 4620 Frae 35000 1349 4.61 VT04 Blissman#5 4620 Frae 35000 1349 4.51 VT02 Blissman#5 4620 Frac 35000 1349 4.88 11/11/2008 Huntley VT02 Blissman #5 4620 Pit 6.5 35000 1349 11.59 VT02 Blissman#5 4620 Pit 35000 1349 10.78 11/1212008 Huntley VT02 Blissman#5 4620 Frae 7.3 55000 2119 5.81 VT02 Blissman #5 4620 Frae 55000 2119 6 VT02 Blissman#5 '4620 Frae 55000 2119 5.88 11/14/2008 Huntley
----- VT02 Blissman#5 4620 Pit 6.6 40000 1541 10.1 VT05 Blissman#5 4620 Pit 40000 1541 9.91 VT02 Blissman#5 4620 Pit 40000 1541 9.78 mrf/2008 Huntley VT04 Altman #4 4620 Pit 7.6 10000 385 9.07 VT02 Altman #4 4620 Pit 10000 385 9.00 11/18/2008 Huntley VT02 Oliver 55-2 4620 Pit 7.8 145000 5587 6.62· ApPENQIXB MACM·PROCESS FLOW DIAGRAM DETAILING SAMPLE LOCATIONS

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.

6·2APPENDIXC MACM CHLORIDE AND TDS ANAL YTICALDATAMunicipal Authority of the City of McKeesport Oil and Gas Well Wastewater Analytical Data for Chlorides and Total Dissolved Solids Nov-08
Influent Grit· Sample Date TDS Chlorides TDS Chlorides

11/1/2008 399 101 411 100.7 11/2/2008 413 107.5 433 96.1 11/3/2008 430 101.8 441 108.2 11/4/2008 415 103 452 104.4 11/5/2008 446 122.5 461 131.7 11/6/2008 432 109.2 446 103.4 11/7/2008 431 120.2 456 156.7 Minimum 399 101 411 96.1 Maximum 446 122.5 461 156.7 Average**~** 424 109 443 114 Holdina Tank Priman Effluent Effluent TDS Chlorides TDS Chlorides TDS Chlorides 419 104.8 506 139.5 411 104.9 452 98.6 23100 13187 454 114.2 493 156.9 19400 9603.2 474 122.8 582 181.6 416 127.3 536 15.9.2 27400 12679 485 134.5 505 141.1 2224 1090.9 437 120.8 535 185.7 2224 1090.9 411 104.8 452 98.6 27400 13187 485 134.5 582 185.7 18031 9140 442 118 516 152

### ENNTRO~NTALSERVICE



## .**LA.BORATORIE~_**

## INC. SAMPLE REQUEST& CHAIN OF CUSTODY PAGE OF HEADQUARTERS: 1803 Philadelphia SL IndIana, PA 15701 (724) 463·TEST (724)465-4209
Sample IdentIflcaHon Influent

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# ~ SOUTHERN DIVISION: 1276 aenUeyvllle Road Van VDcrhls, PA 15366 (724)2
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### ........................
............

# - .........

,1 DAY6OUJ. LAW.,

. ANUlO.

_ ..**LI.~r'lN** COSTS, MatrIx # ofContaIners ContaInerType AnalysIs Requested PlDlDrvaUVB WW 1 Plastic Ute, non. Tolel DIssolved Solids, Chloride WW 1 Plastic**~lter** Total DIssolved Solids, ChlorIde non. WW 1 Plastic Liter ngne Tolal Dissolvad Sonds, Chloride WW 1 Plastic Liter Total Dissolved Solids, Chloride 

# .... WW Plastic Liter Total Dissolved Solids, Chloride 

## non.

Natural Gas Water Study
All

# A~ /i/fybr I

### J,' jOiContactPerson: Recetv1d By: (SlgnBlUra) 

# j

. Date! TIme Ms. Klisti

## ~ jJ" 

# P&M 1 

## II-L/,n'i- 

# 1r;3.'< Datef TIme lBy: Datef 11me 

### IPhone: Fa'" 100 ll+lJ:llntil'! A\JQnIIP ,PA 15132 (412) 673-9701 x11 (412) 6 

# I

## ~

# r.JVi**i#t')t~**

# iiA**~**

# f<,jT

# 4 i •• ,. ....,_. ,.iwi •• ,. •• 

# 1t.. ,ERVICE LABORATORIES, INC. 803 Philadelphia street, Indiana, PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis**~ame:**
,ample Start Dale: lample End Date:**~eceipt** Date: leport Date: lampleSite:

Chloride McKeesportMunicipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 111112008 11:00 AM 111212008 11:00 AM I 11412008 4:31 PM 11/1012008 Natural Gas Water Study Analyte

. Analyst MS Total Dissolved Solids ('rDS) MAD

.

DEP Certification #s 32.00382 Sample IDI#: SampleType: Sample Source: Sampler: Client Sample ID:

Analysis ' Sample

Date Result 1110512008 104.8 1110712008 419

Appro ••

d By:

# ~~l!I~~!!!:~;::=-:':~~"""-:'=-;::;:"- ___ _ J01fQlhan Kon, TechnicalDirector 0831364 WasteWater Composite CLIENT (Client) Primary Effluent

Units
. Method mg/\ SM4500CIC mg/\ SM2540C 

### MDL 1.0 25

IND=Not Dc1ecled

Page 1 of 1

## I=f;.JVU~;(-jtJiii •• '11 Y ....._. 

### ,.IY. 

# 3ERVICE LABORATORIES, INC. 803 Philadelphia 

## street. Indiana, PA 15701 

### 7241-463-TEST FAX (724)-465-4209 Report ofAnalysis**~ame:** McKeesport Municipal Authority Attn: Mr. James Degnan SampIeID#: Sample Type: 100 Atlantic Avenue McKeesport, PA 15132 IJIl12008 1J ;00 AM Sample Source: Sampler: ,ample Star!Date: ,ample End Date: leceiptDate: iteport Date: ,ample Site: Client Sample ID: 111212008 1 I :00 AM 1J1412008 4:31 PM IJlJOI2008 NatoraJ Gas Water Study Analyte Analyst Analysis Sample



### . Date Result Chloride MS 1110512008 101.0 Total Dissolved Solids (TDS) MAD 11107i2oo8 399

Note: DEP CcrtificDtiDn.#s 32-00382
Approv.d By:

# --"7~..

# ~+,::::~~,-:::,~-,: . .:..;"""-,,:-:::::-
__ -'- Jonathan**Kan~** Tee/micalDirector • 0831362 WasteWater Composite CLIENT (Client) Influent

Units Method mgll SM4500CIC mgll SM2540C . MDL 1.0 25

IND=Not Detected

Page 1 of 1.

### := ii.. 

## ail Eii Fii.#=a. iii. - e -;::: iC. ii:;;: &' i 

### i""i"...:Viii#i 

### JrJMi-iuiAi

_ • .,. 1J ••, __ • ,. .... _ • .,... 

## 11._ 

# 3ERVICE LABORATORIES, INC. 803 Philadelphia Slreet. Indiana. PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnaJysis 'lame:
,ample Start Date: ,ample End Date: R.eceipt Date: R.eport Date: ,ample Site:

Chloride McKeesportMunicipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 111112008 II:00 AM 111212008 11:00 AM 1114120084:31 PM 1111012008 Natural Gas Water Study Anaiyte Analyst MS Total Dissolved Solids (TOS) MAD

Note: DEP Certification is32-00382 SampleID#: Sample Type: Sample Source: Sampler: Client Sample JD:

Aoalysis Sample

Date Result 11/0512008 100.7 1110712008 411

# APprOV'dBY:~;tLJ;'-"~='-~~7.·=-"'~~"""-;":';:::::""·-,.-__ _ Jonarhan Kon, TechnicalDirector 0831363 WasteWater Composite CLIENT (Client) Grit

Units Method mg/I SM4500CIC mg/l SM2540C MDL 1.0
. 25

IND=NOI Delecled

Page 1011

# j;NVi~O~fa.V.ei~N 

# t.Ai • I

... .... , i 

# "I ..... I. ,. ,ERVICE LABORATORIES, INC. 803 PhiladelphIa 

# street. IndIana, PA 15701 

### 724l-463-TEST FAX 1724)-465-4209 Report ofAnalysis 'lame: McKeesport Municipal Authority Attn: Mr. James Degnan· lample StartDat.: lampleEnd Date: teeeipt Date: teport Date: iampleSite:

chloride 100 Atlantic Avenue McKeesport, PA 15132 111112008 II :00 AM 111212008 11 :00 AM 1114/2008 4:31 PM llIto12008 Natural Gas Water Study ADalyte



## , Total Dissolved Solids (TDS)

Note: DEP Certificatfon Ds 32-00382 Analyst MS MAD Analysis Date 1110512008 11/07/2008 SampleID#: Sample

### TYPe: ·Sample Source:

. Sampler:

aient Sample ID:

Sample Result 139.5 506

Approved By:

# ~;r.t:E!S~'7"""""-';E=.;.~+ ..........

# ;-:-;::;;:--:-c-~ Jonathan**Kon~** TechnicalDirectDr 0831365 Waste Water Composite CLIENT (Client) Effluent

Units Methoi! mgIl SM4500cIC mgIl SM2540C MDL 1.0 25

IND-NDt Delected

Pagel of 1.,I.,;,J.**~** ".L.I.'\:.V.L**"'.LY~.L** "I**~.n..J.."** ":'.L!I.l.l.. v**.L~.L!I** 

## LABORATORIES, INC. SAMPLE REQUEST& 

### CHAIN 

### OF CUSTODY PAGE

__ OF ---.:..; HEADQUARTERS:**~** SOUTHERN DMSION: 12D3 Phll.delphle SL 1278 aenUeyvllie Road 

# D "
. Indiana, PA 157Dl Van Voorhis, PA 15366 (724) 4B;l·TEST (724) 258- TEST (724) 485-4209 17M) 25a.8378 FOR INTERNAl. /Jl ORATORY SampleTypa Sample Identification ESL# Composite I Gmb Matrix # ofContainers ContainerType Analysis Requested Date anlarr Time anlorf Date nme PraservaUva Innuent 

### C"iL \**-~,**

### •.**:~~::::**

### .......-::::::.. WVV 1 Pla.U.

### ~lIer 'Total Dissolved Solids, Chloride**-~** _... ....... none

Gril**I~,** 

### '-

_**~** 

### . , ..**---,.~._**

### .......--_......... . WVV 1 Plastlo Uler Total Dissolved Solids Chloride**I-~r~** 

### _................ ......_........- non.. I! Primary Effluent 

### I.'R_ '\**~** 

## '0 "'.

-......--...**~::._..** 

## _ ......_-:::::.. WVV , Plasll. Uter Total DI

.. olved Solids, Chloride I 

## r "-:) 1.c,tnl _"'--'

.....- nana Holding Tank
- ...**-::~::::**..............:::::::.. WW 1 PlasUe Lifer Tolal Dissolved Sonds. Chloride

__._ .... nona Effluent DK I**~ ~**  I
- ...**-~**......**~;... .-~--**  ..- ...**~..** WVV 1 Plastic Uter Tolal Dissolved Solids Chloride**I-~I** CoIn'
............-... • ..._.-........ nona t
I 

# -I

,

THE UNDERSIGNED ,.URCKASER ':1 EBY AGKCt;ti 0 PA BERvICECIVIRI: e& ON ACCOUNTS OVER31 DAYS OlD,

_ rOJ8Cl ",OLes: 1, 1lm&I!&ERVICE CHARGES WD.l.ACCRUEATTHERATE OF1 

### 'lIZ'" PER MaNnI (18% PERANNUMQR THe'MAXlMUM AUOWED BY LAW" ,**~** ntE UNOERBIGNED ,URetlABER AGREESTO PAY.'NTH!I!V!NT HIS ACCDIJIIl' "COMES DEUNOUI!NI'ANa IS TURNED OVER TO ANY Natural'Gas Water Study

ATrORNJiY FOR CQU.SCTJON, REABONABLEATTORNE'l'S fEES PLUll'ALL coURTAND ATTENDANT COIJ.ECTlON COSTS. 

# P A

### 'fi#jj.,h~~**11"~-4Y** 1/(/jJ

### ~ CompanylName: McKeesport Municipal Authority**SBmpI.~** By: (SI,na",;:,!..-..1 Dale! 11me 

### '7 

## /,4 / /**LN/~I,X~\.0 11_.?~g**  /lOt)
_ /(

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### l(/$'/o1, /J;J!J CDnlaciPerscn:

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... ) I 001011 TIme 

## IL 'AC, 

## -0-'fl'kJ? /t:fj 

## l«nltPA ('lAid 

## ll- ll-n';o I CI<. 

## I Address: 100 Atlantic Avenue RelinquIshed By: IS',
.. w

..

, 'Ca(e! TIm. ReceIved y: ,Sign"""') Cate! TIm. McKeesport, PA 15132 Rsllnqulshed ay: (sIgnalUre) Dale! TIm. Race""'d By: IS"nalUra) Cale! TIme Phon.: (412) 673-9701 xii CHAIN OF CUSTODY**SEA~** BROKEN: Yes No Fax: (412) 673-4283

## i=**~,rV';i ~~-j~ifli1~** **~J** i 

# l:. 

# i

.. I. 

# ..,_i•..._ ......_ SERVICE LABORATORIES, INC. ·803 Philadelphia street. Indiana, PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis**~ame:** McKeesportMunicipal Authority Attn: Mr. James Degnan ,ample Start Date: ,ample End Dale: leI:eipt Date: loporlDate: ,ample Site:

Chloride 100 Atlantic Avenue McKeesport, PA 15132 Ili212008 11:00 AM 11/312008 11:00 AM' 1114/20084:26 PM 11110/2008 Natural Gas Water Study Analyle
Total Dissolved Solids (TOS)

Note: DEP Certification is 32"()0382 Analyst MS MAD SampleID#: Sample Type: Sample Source: Sampler: Client Sample

### ID:

Analysis Sample

Date ReSnJt 11105/2008 107.5 11107/2008 413

Approved By:

# --"=:~",~,-+-,,,~:,;;.::::...,;,~:....,:-"""-.,.:-;;:;;,--:- __ JOJll1than Kon. Technical DlrecJor 0831358 Waste Water Composite CLlENT (Clieut) Influent

Units Method mgll SM4500CIC 

### m!¥l SM2540C MDL 1.0 25

lND=No! Dek<:!cd

Page 1 ofl

## i--INVii#nr~fui 

# Fi',iT4

# i

_ 'II 11' ••"_ ...i'r ••• 'i ..... 

# 3ERVICE 

# LABORATORIES, INC. ·803 Philadelphia Sireet, 

### Indiana, PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis 'iame: McKeesport Municipal An1hority Attn: 

### Mr. James Degnan Sample W/;!: SampleType: Sample Sonrce: Sampler: ,ample StartDate: lample End Date: 100 Atlantic Avenue McKeesport, PA 15132 111212008 11:00 AM ClientSample W: 0831359 WasteWater Composite CLIENT (Client) Grit IeeeiptDate: Ieport Date: lample Site:

Chloride ,. 111312008 11:00 AM 1114120084:26PM 1lI1012008 Na1llral Gas Water Study Analyte

Total Dissolved Solids (TDS)

Note: DEP CertificatiDn Is 32-00382 Analyst Analysis Sample .Date Result MS 1110512008 96.1 MAD 1110712008 433

Approved By:

# --"'J~"'~±"'''''''-:;;:::~~+''''''-i-i';'''''-:--­ Jonathan Kot; TecllnicalDfreclor .Units ;5 Method MDL mgll SM4500cIC 1.0 mgll SM2540C 25

IND=NDI Detected

Page 1011

### roo

# Jt.JVi ,*f1NfiJiri\J =

# iiI

....... , ......_ ........tl'w •• ". 

# ;ERVICE LABORATORIES, INC. 803 PhiladelphIa street.Jndlana, PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis iame: McKeesportMunicipal Authority Attn: Mr. James Degnan 1ample StartDate: lample End Date: teceipt Date: leportDate: 1ample Site:

Chloride 100 Atlantic Avenue McKeesport, PA 15132 1112/2008 11:00 AM 1113/2008 Il:OO AM 111412008 4:26 PM 1111012008 Natural Gas Water Study Analyte
Total Dissolved Solids (TOS)

Nole: DEP Certificotion lis 32-00382 Analyst MS MAD SampleJD#: Sample Type: Sample Source: Sampler: Client Sample ID:

Analysis Sample

Date Result 1110512008 \04.9 1110712008 411

,.

Approved By:

# --"'l~",~::;'**c"~~"'-:;;~(-.':';'~:-'=;;",-,-,,..,..,-­** Jonathan Kan, TichnicalDirector . 0831360 Waste Water Composite CLIENT (Client) PrimarY Effluent

Units ' Method mgIJ SM4500CIC mgll SM2540C MDL 1.0 25**~D=NDl** Detected

Page 1 011

## ~

# rJ\lii#,-jNfaJa**~**

# rJT 

# 4 i 

# .........

# ,_..................

# - ,ERVICE LABORATORIES, INC. 803 Philadelphia 

### Street, IndIana, PA 15701 

### 724)-463-TEST ,FAX (724)-465-4209 Report ofAnalysis 'ame: McKeesportMunicipal Authoriql Attn: Mr. James Degnan lample StartDate: /ample End Date: teeeiptDate: teportDate: /ample Site:

Chloride 100 Atlantic Avenue McKeesport, PA 15132 11121200811:00 AM 111312008 11:00 AM 111412008 4:26 PM 1111012008 Natural Gas Water Study Analyte
Total Dissolved Solids (TDS)

Note: DEP Certific.tiDn is 32-00382 Analyst MS MAD SampJeID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Analysis Sample

Date Result 1110512008 98.6 1110712008 452

Approved By:

# ~'f.£J;~7h.~~"""--~,,-;;;~~"""'-:;,;::,;;':-:c:,---- Jonothtm ICon. Tec!m;ca/Director 0831361 WasteWater Composite CLIENT (Client) Effluent

Units Method mgll SM4500CIC mgll SM2540C MDL 1.0 25

jND=NOII1Clecled

Page 1 of 1

### Jj,1'4 V lKU1'ollV.l...nl'4.lllL "J:!.KV**l~P** 

## LABORATORIES, INC. SAMPLE REQUEST

### & CHAIN 

### OF CUSTODY PAGE_OF

__ " HEADQUARTERS: 1803 Philadelphia SL 

# E.1: indiana, PA 15701 (724) 463·iEST (724) •• 5-'1209 FOR INTEIl1IJff:: SOUTHERN DIVISION: 1278 BenUeyvlll. Road Van Voorhis, PA 15366 (724l25S·TEST (724)
...... 7. rORYUSE'Oj 

# D

Sample Type Sample IdentlllcaUon ESl# « Innuenl

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Grtt

# ~':2$1 Prtmary effluant

### ~\-.:~

Holding Tank

# ~

effluent 

# F{l

....,.......,



# ...... , t1 PAV_ IN '1'HE

### ~;oj By:**(SI9l'lIlt~** Dale/lima t R!;AL ICHAINOFCL

.._----' No Yes Grab Matrix' Date TIm. WoN



### ........ WoN 

## ww WoN

### ,.~.I 

## wvJ



# - ,

-**~IIIUUOR.'** DEUNQUENTAND IS TURNED 0VJ!fI; 1"0 ANY # of Containers 1 1 1 

# , 

# , ContainerTYpe PlasUo Uler non. 

### BsUci:

no.. non. 

### BsUci:

non. 

### iOsiiCi:**'na.~**



### It'ro J 8Ct NDte&. Analysis Requested Total Dissolved SOlids, Chloride Tolal Dissolved Solids, Chlortde Total Dissolved Solids, Chloride 'Total Dissolved Solids, Chloride Total Dissolved SOlids, Chlortde

Natural Gas Water Study**~** Company/Name: , McKeesport Municipal AI

# ";;;~~~=:'_~_-4J~6~(;j.J~Wrf"-::-.!./~J.!..:!.?=:O~ Contact Parson:

# .!:M~s!:. • .!,!K;,::ris:ti:..::D:,::lc::::a::.:rl::.o

# -------1**~Recelve** By: (8Ign.1U1'II) 0 eJ TIme 

# 01rJ?'. 

# c.f4,l II-y'-OY' I

# G:Ztl AM._... inn Recelveli By: (SlgnDlure) Datal TJme , PA1!:it32

tteK;BIVed By: I Datal l1me 

# I Phone: Fax: (412) 673·9701 x11 (412) 

## e --

## I-

# fJVi**~r:;fd!\;i**

# i=

# fda

# i

.... y ••,,_ ............. ,.. 

# ,ERVICE LABORATORIES, INC. 803 PhOadelphla 

## street, Indiana, PA 15701



### .7241-463-TESTFAX (7241-465-4209 Report ofAnalysis \fame: McKeesport MWlicipaJ Authority Attn: Mr. James Degnan

, iampl. Start Date:

lampl. End Dat.: leceiptDate: teportDate: lample Site:

Chloride 100 Atlantic Avenue McKeesport, PA 15132 llf312008 11:00 AM 11/412008 11:00 AM 1114120084:26 PM 1111012008 Na1Ural Gas Water Study Aualyte
Total Dissolved Solids (TDS)

t!l!!!!; DEP CertifiClltioo Ns 32-00382 Analyst MS MAD SamplelD#: Sample Type: Sample Source: Sampler: Client Sample 

### m:

Analysis Sample

Date Result 1110512008 101.8 1110712008 430

Approved By:

# --'=1'-q'.,.;ih.::±:''''-'i2''-;;;'~-+'''''"'-i=i-'''''''''''''-­ Jonalha(lKon, TeclmicalDirector 0831353 WasteWater Composite CLIENT (Client) Influent

Units , Method mgII SM4500ClC mgll SM2540C MDL 1.0 25

fD=Not Detected

Page 1 of 1

# t:**t~Vi**

# KOt"

# rv,t

# t"iAL 5ERVICE LABORATORIES, INC. 803 Philadelphia 

## street. Indiana. PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis**~ame:** lample StartDate: lampl. EndOat.:**~eceipt** Date: leportDate: Iample Site:

Chloride McKeesport Municipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue. McKeesport, pA 15132 111312008 11 :00 AM 111412008 11 :00 AM 1114120084:26 PM 1111012008 Natural Gas Water Study Analyte Analyst MS Total Dissolved Solids (TDS) MAD

Note: DEP C.rtificnllon lis 32-00382 SampleID#: Sample Type: Sample Sonree: Sampler: Client Sample ID:

Analysis Sample

Date Result 1110512008 108.2 11/0712008 441

Approved By:

# ~1L'i',:"~::±,,,,'"""'-:,;:::=-,;;:~':i'''''''-~~=::--­ Jonathan IWn, Technical Director 0831354 Waste Water Composite CLIENT (Client) Grit

Units Method mg/J SM4500CIC mg/J SM2540C MDL 1.0 2S

IND=NOI Dotccl<:il

Page 1 of1

## i- 

# ;--J\j;**~OtJ**

# tu; i= 

# N =.6 

# i

.... wi., .............. 

# 1l. 5ERVICE LABORATORIES, INC. 803 Philadelphia street, Indiana, PA 15701 

### 724)-463-TEST

. FAX (724)-465-4209 R'eport ofAnalysis**~ame: ~ample**  StartDate: lampl. End Date: l.eceiptDate: l.eportDate: lampl. Site:

. Chloride McKeesportMunicipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 111312008 11:00AM 11/41200811 :00 AM 11/412008 4:26 PM 1111012008 Natural Gas Water Srudy Analyle . . Analyst MS Total Dissolved Solids (1DS) MAD

Note: DEP Certification is 32-00382 SamplelD#: Sample Type: Sample Source: Sampler: Client SampIe ID:

Analysis Sample

Date Result 1110712008 13187.0 1If0712008 23100

Approved By:

# -"1"""Ei~:,c;~;2~~"':-::~~;';--:--­ Jona/han Kon, Technical DirectDr 0831356 WasteWater Composite CLIENT (Clientr Holding Tank

Units Method mgll SM4500ClC mgll SM2540C MDL 1.0 25

INlFNDtDeteotcd

Pagel.fl·

# r=

# tJVi**~1-)tJ** 

# ';viS**~t~T** 

# Ai 

# c. 'II 11' •• , _. 'II. 11' 

# i••

# 'II.. .... 5ERVICE LABORATORIES, INC. 803 Philadelphia SJreet. Indiana. PA 15701 

### 724)-463-lEST

. FAX (724)-465-4209 Report ofAnalysis liame: McKeesport Municipal Authority Attn:· Mr. James Degnan lample Start Date: lampIe End Date: ;teeeiptDate: iteport Date: lample Site:

Chloride 100 Atlantic Avenue McKeesport, PA 15132 111312008 11 :00 AM 111412008 11 :00 AM 111412008 4:26 PM 1111012008 Natural Gas Water Study Analyte

. Total Dissolved Solids erOS)

Note: DEPCertification Is 32.00382 Analyst MS MAD Sample IDfI.: Sample Type: Sample Source: Sampler: Client Sample ID:

Analysis Sample

Date Result 1110512008 114.2 11/0712008 454

Approved

# BY:~~t!!~.!fJ~"""--;;::::=-;;;'~~~~~-,- __ JOnoJhan KOIl, TechnicalDirector 0831355 Waste Water Composite CLIENT (CUent) Primary Effluent

Units Method mgll SM4500CIC mgll SM2540C 

### MDL 1.0 25

INJ>oNot Detected

# i=-tJV!**~rjNft,4I=NT**

# Ai _. ,. ... ..,_. ,...... _. ,. .. 11._ SERVICE LABORATORIES, INC. 1803Phlladelphla Street Indiana, PA 15701 

### 724)-463-TEST FAX(724F465-4209 Report ofAnalysis "lame:
Sample StartDate: Sample End Date: Receipt Date: Report Date: Sample Site:

Chloride McKeesportMunicipalAuthority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 111312008 11:00 AM 111412008 11 :00 AM 111412008 4:26 PM 1111012008 Natural Gas Water Study Aaalyte Analyst MS Total Dissolved Solids (TOS) 

### MAD

Note: . DEP Certificillion lis 32-00382 SamplelD#: Sample Type: Sample Sonrce: Sampler: Client Sampie ID:

Analysis Sample

Date Result 1110712008 156.9 1110712008 493

Approved

# BY:-"'i1-C;lta.;th.",~IlA.-.-<;;::::~~:";:""'-~:;;,,--=__

.Jonathan Kon. TechnicalDirector 0831357 WasteWater Composite CLIENT (Client) Effluent

Units Method

. mgII SM4500CIC mgtl SM2540C MDL 1.0 25

(ND=Not Dcletled

Page 1 011..L.!IJ..,. 'Y .1.1'-"-.IJ.... .LTLJ..:I.L.,. .I....£'1.1...:f &:;J.l..!I.J.\.. Y**~'-'~** 

### LARO"RATORIES. 

## INC. SAMPLE REQUEST

### & CHAIN 

### OF CUSTODY PAGe

__ OF

__ ._ HEADQUARTERS: lB03 Philadelphia Sl 

# t;Q Indiana, PA 10701 (724) •• 3-TEST (724) 46.-4200

- FOR, Sample Identification ESl#
Influent 

## F"20J-=30

Gril

# ~(t")'2-\3\ Primary Effluant

# P~1J3Z

Holding Tank

# 1~2'~

Effluenl

## IG~~/..jj

IV'HESE'


# J17C· SOUTHeRN DIVISION: 1276 BenUeyvIIle Road Van Voomls, PA 15366 (724) 25I1-TEST

.(724) 2511-8376 bRATORYUSEONLY 

# D

!lampl.Type 

### GraJ>.**~_ate_..L.....T1me**



### .......

11 DAYS 0l.0. Matrix # of Containers 

### ww 1 

### ww 1 

### ww 1 

# - WW 1 

### ww 1

H (18% PSRANNUM CR1HEMAXlMUM AU.OWED BY LAW.) ll_"CllON COSTS,

# u-ll~LiJ If-T-o<g I U";3;.o 

### (0**Rrr.I""'lBy:}al~** ..-"'.Z-"1 

### J 

### II DelelTIme

## l!TYl\/~**~** 

## ll-h?J**~a'ff** Q!

## t/2 "' ReceTveb By: (5IgnaILlf1l) Dale! TIme dBy: =1"":1 UBIB' -lime RBC8IVBd By: , _No UalSl' 11m!:! (SEAt _Yea ContainerType Pl'8IIlIMIUve Pla.UeUler



# ..... Plastic Liter 

## """" Plastic Lller n...
nana PlasUe Liter nona AnalysIs Requested' Total DlssolvadSollds, Chlorida Total DIssolved Solids, Chloride Total Dissolved Solids, Chloride Total DIssolved Solid., Chloride Tolat Dissolved Solids, Chloride**~** Natural Gas WaterStudy

:l person:

t"nona: 

## IFax: Ms.. Kristi I**"11,...~rlr'l** 100 AII,mtl" Avenue

, PA 15132 (412)-673-9701 x11 (412) 673-4283

## FfJVi~l-RNilu'i-N 

# 141 

# c.......,_. wf\.......... . 

# SERVICE LABORATORIES, INC. 1803 Philadelphia street Indiana, PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis lIame: McKeesportMunicipal Alithority Attn: Mr. James Degnan SampleID#: Sample Type: 100 Atlantic Avenue McKeesport, PA 15132 1If4l2008 11:00 AM Sample Source: Sampler: ,ample SlartDate: ,ampleEnd Date: Client Sample ID: Receipt Date: 11/512008 9:00 AM 11110/20089:31 AM 11113/2008 Report Date: ,ample Site: Natural Gas Water Study #3 Aualyte '.. - 

## ,. Analyst Chloride MS Total Dissolved Solids (TOS) ... CLM



### t!l!.!!!i. DEP Certifie.tion Is 32-0038Z Analysis Sample Date Result 1111212008 103.0 1111112008 415

Approved By:

# ~'f-C!E!S~~~/lA.-..~,,--;;;~~"""""~=:::--'- __ _ Jonathan Kon, TechnIcalDirec/or . 0832130 Waste Water· Composite CLIENT (Client) Influent

Units Method mgIl SM4500ClC mgll SM2540C MIlL 

# I 1.0 25·

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# _. 5ERVlCE LABORATORIES, INC. 1803 Philadelphia S1reet, Indiana, PA 15701 

### 724)-463-TESl FAX (724)-465-4209 Report ofAnalysis lIame:
>ample StartDate:**~ample** End Date: Reeeipt Date: Report Date:**~ample** Site:

Chloride McKeesport Municipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 11/41200811:00 AM 111512008 9:00 AM 1Ifl012008 9:31 AM 1111312008 Natural Gas Water Study #3 Analyte
. Anatyst MS TotalDissolved Solids (TDS) CLM



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Note: DEP Certific.tion ils 32"()0382 SampleID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Analysis Sample

Date Resnlt 11f1212008 104.4 1lI1112008 452

Approved By:

# ~~~1.2~~~~~~':.::"""-;:.s:~.,.,--­ Jonathan Kon. TechrdcaJl!ire.ctor 0832131 Waste Water Composite CLIENT (Client) Grit

Units Method mgll SM4500CIC mgtl SM2540C 

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# ,ERVICE LABORATORIES, INC. 803 Philadelphia S1reet, Indiana, PA 15701 

### 724)-463-TEST FAX {724)-465-4209 

### Report ofAnalysis**~ame:** lampl. StartDate: lamp!. End Date:**~eeeipt** Date:**~eport** Date: lample Site: McKeesport Muoicipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 llf412008 II:00 AM 111512008 9:00 AM 1,1110120089:37AM 1111312008 Natural Gas Water Study #3 Analyt. Analystl Analysis Date ··Chloride MS 11112/2008

Total Dissolved Solids (TOS) CLM 11/1112008

Note: DEPCertificatiDn #s 32-00382 SampleID#: SampleType: Sample Source: Sampler: Client Sample ID: 

# I Sample
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### . Resnlt 9603.2 19400

Approved By:

# --""~"'~'±""'""'--';E=-;;;:~,+"""-;.:..;::;;;-.=,--__ Jonathan Kon j Techn;calDirector 0832133 Waste Water Composite CLIENT (Clieat) Holding Tank

Units Method mgIl SM4500CIC mgIl SM2540C 

### MDL 1.0 25

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# ;;.,. ........_.,........ ,. •• "&. 3ERVICE LABORATORIES, INC. 803 Philadelphia Street, IndIana, PA 15701 

### 724)-463-TEST FAX (724)-465-4209 Report ofAnalysis 'lame:
'ample StartDate: ,ample End Date: Ie.eiptDate: leportDate: ,ampleBite:

Chloride McKeesport Municipal Authority Attn: Mr. James Degnan 100 Atlantic Avenue McKeesport, PA 15132 111412008 11:00 AM 111512008 9:00 AM 11110120089:37 AM 1111312008 Natural Gas Water Study #3 Analyte Analyst MS Total Dissolved Solids (TOS) CLM

Note: DEP Cc:rlilicatioo C. 32'()0382 SampleJD#: Sample Type: Sample Source: Sampler: Client SampleJD:

AaalysiS Sample

Dnte Result 1111212008 122.8 1111112008 474

Approved By:

# ~tL!?:a:7;~~i-!!!:""'"-~=-;;:~~.!.:"'"'-;'::.**~;-c,---­** Jonalltan /(on, Tee/mlcalDirector 0832132 Waste Water Composite CLIENT (Client) Primaty Effluent
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Units Metbod mgIJ SM4S00CIC mgIJ SM2S40C MOL 1.0 2S

IND=Nol Deleclcd

Page 1 of 1

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# .......... ,ERVICE LABORATORIES, INC. 803 Philadelphia Street, Indiana. PA 15701 

### 724)-463-TEST FAX (724)-465-4209·· 

### ReportofAnalysis**~amc:** McKeesport Municipal Authority SampleID#: Atbt: Mr. James Degnan SampleType: 100 Atlantic Avenue Sample Snurce: McKeesport, PA 15132 Sampler: lampl. StartDate: 111412008 11 :00 AM Client Sample**~:** lample End Date: 111512008 9:00 AM receipt Date: 11/1012008 9:37 AM repnrt Date: 1111312008 lample Site: Nataral Gas Waler Study #3 Analyte Analyst Analysis Sample Date Result Chloride MS 1111212008 181.6 Total Dissolved Solids (TOS) CLM 1111112008 582

Note: DEP CertificntioD #Is 32..00382
Approved By:

# ~;W;~~S:!:=~~.**,,-:;::~:.:r::"""--~~=::---­** Jonathan Kon, TechnicalDirector 0832134 Waste Waler Composite CLIENT (Client) Effluent

Unit;; Method MDL mgll SM4S0.0ClC 1.0 rog/I SM2540C 25



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Page 10[1