2540..PM-BWM0347
ReV. 112011 **~pennsylvania** - **OOWITMENTQ'~...mcrJON** COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT

OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERATOR This fonn must be

must typed or legibly printed in the spaces provided.

If additional space Is necessary, Identify each attached &heel as Fonn 26R, reference the Item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. 287.54 c. Physical Appearance Number of Solid or Uquid Phases of Separation

2 Describe each phase of **separation.~~--------------;** -1

-2540-PMBWM0347Re\<.1!2011b.Apollutioncontrolprocessesproducingthewaste,asspecifiedintheInstructions,Isattached.c.portionsareconfidential,thesubstantiationforaconfidentialityclaim,asdescribedintheinstructions,isattached.b.FacilityNamec.AddressLine1AddressLine1AddressCityStateZIPMunicipalityFacilityContactNameTitlePhonesteve@pabrine.comfacilityInthepreviousgal0lb0ton(checkone)AddressLine1AddressLine1AddressCityStateZIPMunicipalityc.FacilityContactNamerrtlePhoneIf"Yes",listthepermitnumberorapprovalnumber.b.Volumeofwastebeneficiallyusedintheyear.0cuydDgal0lb0ton(checkone)- --

. B40=PM:oawMo347
Rev.
1 I certify, under penalty of law, that
1 have personally examined and am familiar with the Information submitted

In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is bue, accurate and complete

to the best of my knowledge.

I understand that the submission

of false Information herein is made subject
to the penalties
of 18 Pa. C.S. §4904, relating
to unsworn falsification

to authorities, which Include fine and Imprisonment Check the following,

If applicable: D

I certify the Information required
In Section B-1, General Properties was supplied
to the Department for the year __ and has not changed. Form Submitted:

D Form26R D Other (specify) Date Submitted: D

I certify the information required

In Section B-2, Chemical Analysis was supplied
to the Department for the year __ and has not changed. Form Submitted:

D Form26R D Other (specify) Date Submitted: D

I certify the Information required
In Section **~.** Process Description and Schematic, was supplied
to the Department for the year __ and has not changed.

· Form Submitted:

D Form 26R D Other (specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date 2-28-11 -3-February

9, 2011 Form 26R: Section 81e GENERATOR KNOWLEDGE All Foim 26R Waste Forms have been compiled, and future testing has been scheduled,

to obtain samples
of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every
5 years for each waste stream unless the process that generates any particular waste stream

is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation
as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February8,2011Form26R:SectionB2bWASTESAMPLINGMETHODSi·Allsampleswereobtainedasgrabtypesampleswithacompositefunctionwhichwasmaximizedbutsometimeslimitedbyprevailingsafety,sitespecificrationaland/or.environmentalconcerns.Brinefluidsarecompositedwithinthestorageproductiontankortankbatteryateachwellsitewheregasproductionisoccurring.Eachautomaticormanualejectionofformationfluidsisdepositedintothetank(s)andaddedtothepreviouslyejectedandstoredquantity.TanksareemptiedintotanktrucksfordisposalatvariousPaDEPpermittedwastedisposalfacilitiesondifferentschedulesdeterminedbyindividualwellcharacteristics.Grabsamplesofthecompositedfluidswereobtainedattherepresentedwellpadsdirectlyfromthestoragetankdrainports.Alldrainportshadsmall"builtin"containmentandstorage"buckets"capableofretainingsmallamountsoflostfluids.Sarr:'pleswereobtainedwithbottlesetspreparedatthelaboratorywhichcontainedappropriatepreservatives,asnecessary,dependingonthespecifictestrunrequested.Allchainofcustodyandhandling/holdingtimerequirementsweremet.Insomecases,alargersamplewasbrokenintoappropriatesamplingcontainersandsmalleraliquotportionsatthelaboratory.Flowbacksampleswerecompositedtotheextentpossibleduringtheflowbackprocessprimarilyduringtimeswheresafetyissuesdidnotoverridesamplecollectionrequirements.Generally,alargercompositesamplewasbrokenintoappropriatesamplingcontainersandsmalleraliquotportionsatthelaboratoryoronthewelllocationuponcompletionofthecompositesamplingprocess.Samplesweredistributedintobottlesetspreparedatthelaboratorywhichcontainedappropriatepreservatives,asnecessary,dependingonthespecifictestrunrequested.Allchainofcustodyandhandling/holdingtimerequirementsweremet.Drillcuttingswerecompositesampledduringthedrillingprocessatvarioustimesandcombinedintoacompositesampleforanalysesatthelaboratory.Onseveralwells,cuttingsfromtheverticalportionofthewellboreweresegregatedfromcuttingsfromthetargetMarcellusFormationandseparatetestingwascompletedonbothsamplecomposites.Insomeearliercasesduringtheutilizationofopenpits,compositesampleswereobtainedfrominactivedrillpits.Safetyconcernsusuallylimitedtherandomnessofthecompositesampleandcompositegridsamplepositionswerevariedtotheextentpossible.Pitwater(drillfluid)iscurrentlydischargedtoclosedcontainmentandisre-conditionedandreusedfromwelltowell.i·February9,2011Form26R:SectionB3aWASTEGENERATIONPROCESSPitWater"DrillFluids"Remnantdrillfluidsaregeneratedinthewellboreduringthepenetrationofthedrillstemasitinterceptsbothgroundwaterandformationfluids.Thesefluidsarebroughttothesurfacealongwiththedrillcuttings,piecesoftheinterceptedrockstrata,bythereturnflowsystemofthedrillingprocess.Drillcuttingsanddrillfluidsareisolatedintoseparatewastestreams.Cuttingsaremixedwithsawdusttoabsorbremnantfluidandloadedoutfordisposalatalandfill.Fluidsarecurrentlystoredinclosedcontainerstobeprocessedforreuse.Flowback:"FracingFluid"Flowbackisproducedfromallfluidsthatflowbacktosurfaceduringthe"hydrofracing"processwhichoccursunderpressureandresultsinthesettingofapropantwithintheformationfractures.ProductionFluid"Brine"Duringtheproductionofnaturalgas,formationpressuresbringremnantfracfluids,duringtheinitialproductionphase,andformationfluidstothesurfacealongwithproducedgas.Well I. D.# (various) Well I.D.# . (various) '\/

**~**

-0 -y- /v, /1' COUNTY A I\ I \ / Well I. D.# (various) \ \! \ I **~0/** \ I //I' \ I / \ I // \ I // . \ I / Well I. D.# (various) \ 1 // '\/ / \ I / -0.- / "

- COUNTYB / **~o~--** { . **~** C(

**~~ FIO<o>~.....\<.**  **~7 "'i''O~**  Mobile Tank Truck

**'fr-o~IX.-·ho.f\** Ocu
**1\\~~~ ~;**  . . Road Transport

**\OJ\~S** "• **~** :: br1ne (TYP.) ote: .

...... .. . Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction with natural gas. These fluids are brought to the surface utilizing either mechanical or phy$.icallift procedur . es.

- --------Landfill or **Treu.+~U\+** 'Pl(Mt

(.) **~ ~**  w ::r:: (..) (/) z 0 **~ ~**  0 0.. (/) **~** 1- **'~illf ~~~~**  **~** .. **~ ~** 

i I **~** I **~ ~~**  **~**

**~** i - lC **~** Cl -

I
t= l **~~ ~**  **i~** .

**~ ~!**  **~ ~**  **l~** u·

# .. . . ...... 

# - 

# ENVIRONMENTAL SERVICE SAMPLE REQUEST 

# & CHAIN OF CUSTODY 

# LABORATORIES, INC. . PAGE __ OF_ 

# ,__

... HEADQUARTERS: SOUTHERN DIVISION: 1803 Philadelphia Sl 

# KJ 1278 BenUeyville Road 

# D 

# 8 Indiana, PA 15701 Van Voorhis, PA 15388 

# REC'D NOV 

# -4 2009

**·** 

# (724) 463-TEST (724) 258-TEST (724) 465-4209 (724) 258-8378 

# .. FOR INTERNAL LA BORA I UI<Y 

# Use ONL 

# 'Y Sample Type Sample Identification ESL# Composite 

# Grab Matrix 

# # of Containers Container Type Analysis Requested Date on/off Time on/off Da

. te Time · Preoervatlve 

# lf,q 

# If ;R'/31 fl. O[<J5'!1J 

# ----- 

# ---- /6 /_
.. 

# !. 

# ww Plastic Liter pH, SC , Choride, Sulfate , 

# ----- 

# ---- ttrtS 1 Alkalinity, Acidity, Bromide /

**'~L..,** 

# none



# ~ 

# ----- fe> It 

# <>t.:l:.

**~** 

# 1t ww 2 Plastic Liter TSS, TDS, Dissolved Iron,



# ----- 

# ---- **I~** none Boron, BOD, MSAS Surfactants 

# ---- _.;....-- 

# 1!081:. ww Plastic Liter AI, 

# As, Sa, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg, 

# ---- ---- /0



# ~ 

# ' 1.5 1 HN03 Mn, Hg, Ni, Se, Ag, Sr, Zn, 

# ll, Na, Ca, Mo,

**HardnE~s** 

# ---- ----

**~"** '1 

# t5 ww 1 Plastic Liter 

# ---- ---- 10 Nitrate+Nitrite, TKN, Ammonia, COD H:zSO,



# ~ 

# ----

**lf~~k** (2) 

# 1000 mL Plastic Liter Gross Alpha, Gross Seta 

# ___..--

**~**



# ~ 

# ' ww Radium 226, Radium 228 

# -to 

# 1,5 (3) 

# 500 ml HN0 3 

# Thorium, Uranium



# ----- 

# ---- Cj 

# 1.5 ww Amber Glass L


# ----- 

# ---- /0 

# o8 1 Oil & 

# Grease HCI 

# ---- ----

**lf::>gk~** ww Amber Glass L



# ---- ---- /0 

# ' 1:1> 1 Total Phenolics H2so,


# ----- 

# ---- b8"-

**~** Amber VOA Vials 

# ---- ---- /o

**I~** 

# ww 2 Ethylene Glycol none 

# ---- ---- 1cy, 

# ot/o• 1

**I~** 

# ww 2 Amber VOA Vials



# ----- 

# ---- HCI Benzene, Toluene

TRIP BLANK 

# t:J-9 

# ---- ---- :::::::::-

**~** Water 

# 2 · f.mber VOA VIals



# '21~11 

# ---- ---- HCI Benzene, Toluene

THE UNDERSIGNED PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS 

# OVEIU1

**~YS** 

# Ol.O
. 

# Project Notes: 1

. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1112% PER MOI'ffii (18% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW

. ) 2. THE UNDERSIGNED PURCHASER AGREES TO PAY. IN THE EVENT HIS ACCOUrorT BECOMES DEUNOUErorT AND IS TURNED OVER TO ANY

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENOArorT COLLECTION COSTS.



# /L_~/~,.d'



# tc?nJ~ 9
...

/$".,tf'A? Company/Name : 

# XTO ENERGY H_

**Sampl~** 

# By: (Signature)

**~** 

# Date/ Time



# ~-~

'( 

# A d'_g:



# ~ **lr>~'1?-e>Cf rl{~~.;-**  **.** I o -'6-ocf



# 1'1"-),~ Address: 

# 395 AIRPORT ROAD

**Relinquish~:** 

# (Signatural., Date/ Time



# ~:y.(SIV 

# r-1£

**dat~Time** 

# Nl/3 INDIANA, PA 15701



# -:g·~ (o-g-cq ( l.f\



# ~s- 

# wd. ··uu I 

# N) 

# -rf",- tJ"1 Reiin'quished By: (Signature) Date/ Time 'Weceived By: (Signature)

**~**

**Oat~** 

# Time Contact Person: 

# MR. MIKE HAHN Relinquished By: (Signature) Date/ Time Received By: (Signature) Date/ Time Phone: 

# (724) 349-0600
CHAIN OF CUSTODY SEAL BROKEN : Yes No 

# Fax : 

# (724) 349-8489



# - 1-/Q.I/ 

# f'/J/ 

# f.l**!=i\1\ii~ilNi\Aa;t~**

i 4 -I:L •• ... Y **••'-~•** ••w•••

• •• " SERVICE LABORATORIES,
INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST

FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42PM 10/30/2009 Analyte Acidity to pH-8.3 Alkalinity

to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Bromide Chloride Kjeldahl Nitrogen
as N pH(SM) SulfateASTM Total Nitrate
+ Nitrite as N Aluminum

- ICP Arsenic-ICP Barium- ICP Beryllium

- ICP Boron Cadmium

- ICP Calcium- ICP Chromium- ICP Cobalt- ICP Copper- ICP Hardness
Report of Analysis Analyst BF JS szc MAD MAD AJD BF MAD LL LMB AID GIT GIT GJT GIT MAD GIT GJT GIT GJT GJT GIT Sample ID#: Sample Type: Sample Source:
09 29510 Waste Water Grab Sampler: Client Sample ID: NEW (Client) Hall8431

H ? ;tUt 4 Analysis Sample Units Method Date Result 10/11/2009
ND mg/1 as CaC03 SM2310B 10/1212009

175 mg/1 as CaC03 SM2320B 10/1212009 68.7 mg/1 SM5210B 10/1512009 1002.5 mg/1 SM5220D 10/19/2009 62.73 mg/1 sM4500NH3B

&
I 1012112009 554.00 mg/1 01246-99 10/09/2009 51663.1 mg/1 SM4500ClC 10/1912009
33.1 mg/1 SM4500Norg-C,D 10/0812009 6.60

su SM4500H-B 10/1212009
ND mg/1 0516-02 10/1912009
ND mg/1 SM4500N03E 1012112009
ND mg/1
200

. 7/6010 1012212009
ND mg/1
200

. 7/6010 1012112009 388.800 mg/1 200.7/6010 1012212009
ND mg/1 200.7/6010 10/2612009 15.00 mg/1 SM4500B-B 10122/2009
ND mg/1

. 200.7/6010 1012212009 4248.800 mg/1 200.7/6010 1012112009
ND mg/1 200.7/6010 10/2112009
ND mg/1 200.7/6010 1012112009
ND mg/1 200.7/6010 10/23/2009 12192 mg/1 SM2340B RPL 2 20 2.0 500.0 1.00 20.00 1.0 5.5 0.01 5 0.05 1.000 l
. QOO 0.500 0.500 12.50 0.500 50.000 0.500 0.500 0.500 1 Comments: Radiologicals done by Benchmark Analytical

fD'"Not Detected Note: DEP Certification

#s 32-00382 Data Qualifiers:

D = The reported value
is from dilution

.
E = Estimated value.

S "' Surrogate out of control limits. R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received

in incorrect container

. B = Analyte was detected

in both sample and methods blank

. x = User defined data qualifier

.i=N\/ii#C-1N• **ii~NTb..i** ......... ".._.,

. .. N .•. • •• "• SERVICE LABORATORIES,
INC. 18 03 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST

FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/812009 9:15AM 10/812009 2:42PM 10/30/2009 Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium- ICP Magnesium-ICP Manganese

- ICP Mercury Molybedenum

- ICP Nickel- ICP Selenium-ICP Silver-ICP . Sodium

- ICP Strontium

- ICP Zinc- ICP Detergents, MBAS Ethylene Glycol Oil and Grease

- HEM Phenolics,

as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Radiologicals
Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result GIT 10121/2009 38.600 GIT 1012112009 21.200 GIT 1012112009
ND GIT 1012212009 72.500 GIT 1012312009 384.400 GIT 1012112009 4.000 DMM 10/1512009
ND GIT 10/2112009
ND GIT 10/2112009
ND GIT 1012112009
ND GJT 1012212009
ND GIT 1012212009 26743.000 GIT 1012312009 720.700 GIT 10121/2009
ND TL 10/0912009 0.614 !MetPeal< 10120/2009 <25.000 CLM

· 10/20/2009
ND MAD 10/13/2009
ND LL 10/08/2009 112400 CLM 10/14/2009 104800 ALD 10/13/2009
472 enchmru 10/30/2009

* Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification

#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431

H Units mgll mgll mgll mgll mgll. mgll mgll mgll mgll mgll mgll mgll mgll mgll mgll mg/kg · mgll mgll uS/em mgll mg/1 mg/1 Data Qualifiers:

D = The reported value
is from dilution.

E = Estimated value.

S = Surrogate out of control limits. Method RPL 200.7/6010 1.000 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 50.000 200.7/6010 50.000 200.7/6010 0.500 245.1 0.0002 200.7/6010 0.500 200.7/6010 0.500 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 500.000 200.7/6010 1.000 200.7/6010 0.500 SM5540C 0200 300.0M 25.000 l664A

5.0 420.1 0.500 SM2510B

1 SM2540C

25 SM2540D

5 RAD-CTDHS 0.000

I IND=Not Detected R = Sample received out of holding time.

H = Sample analyzed out of holding time.

C = Sample received

in incorrect container

. B = Analyte was detected

in both sample and methods blank.

x = User defined data qualifier.

Page
2 of, - LAB ID #: 39-00401 SEND OATA TO: NAME: Mike Moyer .UL.11,V.I.I.IU.l'U.'\.I

. \. **ZUU\.LI.I. .I..L'V~**  .Ll.,V BENCHMARK ANAL YTICS, INC. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100 **FPU<(610)974~104**

Work Order. 09101656 WO#: 09101656 COMPANY: EnVIronmental Service Laboratories,
Inc ADDRESS

: 1803 PhUadelphla

St

PAGE: 2of2 Indiana, PA 15701 PHONE: (724) 463-8378 (724) 465-4209 FAX: 09 29350
& 09 29510 RECEIVED FOR LAB BY: DMB SAMPLE:
09 29510 SAMPLED BY

: David A. Stile l!m
Result Thorium

< 0.0131 --- SAMPLE

: 09 29510 SAMPlED BY: David A. Stile Iu1 **~** Gross Alpha
1971 Gross Beta 2285 SAMPLE:
09 29510 SAMPLED BY: David A Stie

PO#: DAS10092009 TEST REPORT PWSID# DATE

: 10/121200910:00

Pagc2 Clf2 Leb 10: **091016~E** Grab SamPle T.ne 10/0812009 9:15 **~** MQA Units Method t: 0.00

0 mgiL EPA200.8 Leb ID: 09101656-002A Sample Time 1010&'2009 9:1S **~**

g Units **~** :t221.3 746

. 9 pCUL EPA900.0 t 140

. 7 682.4 pClll EPA900.0 t.Q. 6llii!Ysfs Start Analysis End Anatvst

• 10113109 8:30 1(){16109 GSR-CV --- Grab MQ!,. Analysis Start MaJym End **~** 10113109 8:50 10116109 BP$-CV 10/13m 8:50 1()(16109 BP5-CV --------· Lab 10: 09101656-0028 Grab Sarf1Jie Tine 1010812009 9:15 **~ ~**  tmA Units

M,g. t-nalysis Start AnalySis End 6oi!xC Radlurrt-226
464.9

:t 15.84 59.4 pCi/L EP.I\$03.0 10116109 11:15 10129109 BH.CV ---··---
------

·· -·--- SAMPLE:
09 29510

Lab 10: 09101656-002C Grab SAMPLED BY: Davia A. Stile Sample Tme 1010812009 9:15 rm Radium-228 Result **~** MQ6 1.!ntTl 148

. 7

t 11.10 14.16 pCi/l EPA904

. 0 m Analysis Start Analy!iS End **~il!** 10121109 **8:0~** 10127109 NLB-CV SAMPLE:
09 29510 SAMPLED BY: David A. Stile

·· ·------

. ___ _ , _ _ Lab 10:
- **091016~**
Grab Sample Tme 1010812009 9:15 **~** Result **~** MDA !.!nl1i **~** MCL Ane.l)lsis Start Analy!is End **~** Uranium

< 13.13

t: 0.00

0 llQ/l. MS EPA200.8

30 1011910910:00 Uranium <8.93

t 0.00

0 pCiiL EPA200.S 10/19109 10:00 ··--·

· - ·

. . ·--

. . .. ... REMARKS: The **~bove** test procedures meet all the tequirements

of NELAC and relate only to these samples

. " CV = Benchmar1< Analytics, Inc

. Center Valley, PA; SA"' Benchmark Analytics

, Inc

. Sayre, PA MS Umit of detection increased due to matrtx interference **~d** spike reetJvery data MANAGER **~t?kL** o

•

a

0

•

DATE

: 10123109 GSR.CV 10123109 GSR-CV ··· --- 1013012009=== **~** ii 'i.
•
i ;:::a At,.- iii. ;c ;= ii. ;= ..

i ;.. ru \tllifl Jl\lnfi t-ru
1 A L ..
I '11 Y
I ·'- **~**

I '11 I Y I -I '11 II

' SERVICE LABORATORIES,
INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST

FAX (724}-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42PM 10/30/2009 Analyte Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO .10/09/2009 26.40 RO 10/09/2009
ND Comments: Radiologicals done by Benchmark Analytical . **~** DEP Certification

#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431

H Units ug!L ugiL Data Quiilifiers:

D =The reported value
is from dilution.

E = Estimated value.

S = Surrogate out of control limits. Method RPL 624/8260B 20.00 624/8260B 20.00 \ND=Not Detected R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received

in incorrect container. B = Analyte was detected

in both sample and methods blank.

x =User defined data qualifier

.&= NVI **~(1Ni\ii** -NTA

i -

I 'W Y

I I "tl. **~**

I 'WI Y I t
I 'W 1• ... SERVICE LABORATORIES,
INC. 1803 Philadelphia Street, Indiana, PA 15 701 1724}-463-TEST

FAX (724)-465-4209 Name: XTOEnergy Sample Start Date:
395 Airport Road Indiana, PA 15701 10/8/2009 10/8/2009 2:42PM 10/1212009 Receipt Date: Report Date: Analyte I) Benzene 47) Toluene Comments:
DEP Certification

#s 32-00382 Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009
ND RO 10/09/2009
ND

09 29511 Waste Water Grab NEW (Client) Trip Blank Units ug/L ug/L Method MDL 624/8260B
1.00 624/8260B
1.00 \ND=Not Detected2540..PM-BWM0347 **Rev.1~G11** COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT
OF ENVIRONMENTAL PROTECT10N BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERATOR required infonnation must be typed or legibly printed In the spaces

If additional space Is necessary. Identify each attached sheet as Fonn 26R. reference the Item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. Une2 c.
Number of Solid or Uquid Phases of Separation

No Describe each phase of **separation.~~--------------!** -1

-2540-PM-BWM0347 Rev.112011 a. b. c.

A

of the and/or POIIIUllon as specified

In the instructions,

Is attached. If
of the infonnation

are a confidentiality claim, as described

In the instructions,

is attached. Address Une

1 Address Une
1 Address City State ZIP Municipality c. Facility Contact Name TiUe Address Une

1 Address Une

1 Address City State ZIP Municipality c. Facility Contact Name TiUe Phone

Indiana (check one) d. **~;n•nrv~n** to processing
or disposal facility the year. 0 cu yd
0 gal
0 lb
0 ton (check one) 0 ton (check one) -2-

No N/A2540:PMOSWM0347 Rev.112011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted

In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is true, accurate and complete

to the best of my knowledge.

I understand that the submission

of false information herein Is made subject to the penalties
of 18 Pa. C.S. §4904, relating
to unsworn falsification

to authorities, which Include fine and Imprisonment Check the following,

If applicable: 0

I certify the Information required
In Section B-1, General Properties was supplied
to the Department for the year _and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: 0

I certify the Information required
In Section B-2, Chemical Analysis was supplied
to the Department for the year __ and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: 0

I certify the Information required
In Section B-3, Process Description and Schematic, was supplied
to the Department for the year_ and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date

1 - 3-February

9, 2011 Form 26R: Section 81 e GENERA TOR KNOWLEDGE

l• All Form 26R Waste Forms have been compiled, and future testing has been scheduled,

to obtain samples
of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every

5 years for each waste stream unless the process that generates any particular waste stream

is substantially altered. Attached analytical results for this waste stream have been obtained from
a similar waste stream producing waste from the same geologic formation
as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February

8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I• All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic
or manual ejection
of formation fluids
is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal
at various PaDEP permitted waste disposal facilities on different schedules determined
by individual well characteristics. Grab samples
of the composited fluids were obtained
at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts
of lost fluids

. Samples were obtained with bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory. Flowback samples were composited

to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory
or on the well location upon completion

of the composite sampling process. Samples were distributed into bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested.
All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process
at various times and combined into a composite sample for analyses
at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed
on both sample composites.

In some earlier cases during the utilization
of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness

of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged

to closed containment and is re-conditioned and reused from well to well.February

9, 2011 Fonn 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated

in the well bore during the penetration

of the drill stem as it intercepts both ground water and fonnation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust
to absorb remnant fluid and loaded out for disposal
at a landfill. Fluids are currently stored
in closed containers

to be processed for reuse. Flowback: "Fracing Fluid" Flowback

is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results
in the setting of a propant within the fonnation fractures. Production Fluid "Brine" During the production
of natural gas, fonnation pressures bring remnant frac fluids, during the initial production phase, and fonnation fluids to the surface along with produced gas.Well I. D.# (various) Well I . . D.# . (various) '\/

**~**

-a **-~-** / · ' /1' COUNTY A I\ I \ / Well I. D.# (various) \ \ I \ I **~0/** \ I /II' \ I / \ I // \ I // \ I / Well I. D.# (various) \ 1 // '\\/ / \ I / -0.- / " ,...-------.

COUNTYB / **~o---** ( . **~** (Y ;/

**Flow~~~/ ~"ib'fo,~**  Mobile Tank Truck **~t"oblvc..tl~.f\ Ocutt,:,.~~**  **\w.~s ~;**  **~** . . \_ s Road Transport :: br1ne (TYP.) ..... ... . - -----Landfill orote: Process producing waste: Gas well produced fluids (brines) are typically produced · in conjuction with natural gas. These fluids are brought to the surface utilizing either - , mechanical or physical lift procedures.

**Tr-eu.+~V\+** 'Pl(AAt

0 **~** w :r: (.) (/) z 0 **~ ~**  **~** (f) . . z **~** 1- :it If **~~~-** t ...

**~ ~** 

i I § I **~ ~**  **~ s~**  S2 ...... - **~ ~**  0 I

t: **~ ~~**  C)

**~** I **~ ~!**  Z **~N** l3 :i,.. 15 **~** HI . **e~**

# ENVIRONMENTAL SERVICE LABORATORIES, INC. SAMPLE REQUEST 

# & CHAIN OF CUSTODY PAGE

__ OF,

__ HEADQUARTERS: 1803 Philadelphia Sl Indiana, PA 15701 (724) 463-TEST (724) 465-4209 

# rKJ SOUTHERN DIVISION: 1276 BenUeyvllle Road Van Voorhis, PA 15366 (724) 258-TEST 

# D REC'D NOV 

# -4 2009 (724) 258-8376 

# FOR

**INTERNAL~ATORY** 

# USE ORIT
Sample Identification 

# I ESL# 

# lf141/,g'131 

# nl 0 

# l95! ()

TRIP 

# BLANK 

# 09 

# '295""11 Composite Sample Type
Date

THE UNDERSIGNED PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVER 31 DAYS 

# 01.0. 

# Grab Time



# Cjt;l~


# t5 '15

1

. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 112" PER MONTH (18" PER ANNUM OR 

# niE MAXIMUM ALLOWED BY V.W

. ) 2

. THE UNDERSIGNED PURCHASER AGREES TO PAY , IN THE EVENT HIS ACCOUNT BECOMES O!UNQUENT ANO IS TVRNI!D OVER TO Alf'f

ATTORNEY FOR COLLECTION , REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENDANT COLLECTION COSTS

. 

# Matrix 

# I
VWI 

# I
VWI 

# I
VWI 

# I VWI 

# I
VWI 

# I
VWI 

# I VWI 

# I
VWI 

# I VWI 

# I
Water 

# I fl. of Containers 

# I Container Type PreaetVetive 

# 1 

# I Plastic Liter 

# none 2 

# I Plastic Liter none 

# 1 

# I Plastic Liter HN03 

# 1 

# I Plastic Liter

**H2so~** 

# (2) 1000 mL 

# I Plastic Liter 

# (3) 500 mL HN03 1 

# I Amber Glass 

# L HCI 

# 1 

# I Amber Glass L

**H2so~** 

# 2 

# I Amber VOA Vials none 

# 2 

# I Amber VOA Vials HCI 

# 2 

# I

**~berVOA** 

# VIals HCI 

# Project Notes:

Company/Name:
Address:



# ~~~~~--~~~~~--~~ Dale/ Time 

# (0-



# g~o::c 

# ( 'ft

**~s-** Dale/ Time Relinquished By : (S i gnelure) 

# Date/ Time 

# CHAIN OF CUSTODY SEAL BROKEN: Yes 

# _No 

# Heceived By: 

# (SJgneiJ.)

. - 

# 7 Date/ Time 

# Contact Person:



# ~R~~~~~B~y.- **c~s~~--~)--------------0-a-t~~Ti~m-e-----------;,PhDne :**  Fax: 

# 8

. ,j '



# I Analysis Requested pH, SC, Chorlde , Sulfate, / AlkaUnlty, Acidity , Bromide TSS, TDS, Dissolved Iron , Boron, BOD, MBAS Surladants AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe , Pb,

**~** 

# Mn, Hg, Ni, Se, Ag, Sr, Zn, 

# ll, Na, Ca, Mo, H ness Nitrate+Nitrite, TKN, Ammon i a, COD Gross Alpha, Gross Beta Radium 226, Radium 228 Thorium , Uranium

Oil &Grease 

# I Total Phenolics 

# I Ethylene Glycol 

# I Benzene, Toluene 

# I Benzene, Toluene



# XTO ENERGY 395 AIRPORT ROAD INDIANA, PA 15701

MR. MIKE HAHN (724) 349-0600 (724) 349-8489 

# /Jo 

# t1 

# 'i'!JI 

# JAi= f\J\i·

1 - **~nNi\ii** &;NT A

i -I .._ Y .,....,.

I 'WIYI ..
I 'W 16 ,. SERVICE **LABORATORIES~**
INC. 1803 Philadelphia Street, Indiana, PA 15701 (724)-463-lEST

FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/812009 2:42PM 10/30/2009 Analyte Acidity
to pH=8.3 Alkalinity

to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia

as N I Distilled Bromide Chloride Kjeldahl Nitrogen

as N pH(SM) Sulfate ASTM Total Nitrate +Nitrite
as N Aluminum- ICP Arsenic-ICP Barium- ICP Beryllium

- ICP Boron Cadmium

- ICP Calcium

- ICP Chromium- ICP Cobalt- ICP Copper- ICP Hardness
Report of Analysis Analyst BF JS szc MAD MAD AJD BF MAD LL LMB AJD GIT GJT GJT GJT MAD GJT GJT GJT GJT GIT GJT SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result

09 29510 Waste Water Grab NEW (Client) Hall8431

H ? ;:rc.At **~** Units Method 10/1112009
ND rng/1 as CaC03 SM2310B 10/1212009

175 rng/1 as CaC03 SM2320B 10/1212009 68.7 rng/1 SM5210B 10/1512009 1002.5 mg/1 SM5220D 10/1912009 62.73 mg/1 :;M4500NH3B

& I 1012112009 554.00 mg/1 01246-99 10/0912009 51663.1 mg/1 SM4500ClC 10/19/2009
33.1 mg/1 SM4500Norg-C,D 10/08/2009 6.60

su SM4500H-B 10/1212009
ND mg/1 D516-02 10/1912009
ND mg/1 SM4500N03E 1012112009
NO mg/1 200.7/6010 1012212009
ND mg/1 200.7/6010 1012112009 388.800 mg/1 200.7/6010 10/2212009
NO mg/1 200.7/6010 10/2612009 15.00 mg/1 SM4500B-B 10/2212009
ND mg/1. 200.7/6010 10/2212009 4248.800
mg/1 200.7/6010 10121/2009
NO mg/1 200.7/6010 10/21/2009
NO mg/1 200.7/6010 10121/2009
NO mg/1 200.7/6010 10/23/2009 12192 mg/1 SM2340B RPL 2 20 2.0 500.0 1.00 20.00 1.0 5.5 0.01 5 0.05 1.000 1.000 0.500 0.500 12.50 0.500 50.000 0.500 0.500 0.500 1 Comments: Radiologicals done by Benclunark Analytical

\ND=Not Detected Note: DEP Certification

lis 32-00382 Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits. R = Sample received out of holding time.

H = Sample analyzed out of holding time.

C = Sample received

in incorrect container. B = Analyte was detected

in both sample and methods blank.

X = User defined data qualifier.

Page

1 of-
- -- --- ........ - -- --- --
- - - - =.. • .. --,..-,....

• ... - - .. ·-=- ..
.. ;- ru v liifi JNnni-N IAL ..

I .. ..

• " ""'-"'

I 11 I ..

I - I 11 I.

" SERVICE LABORATORIES,
INC. 1803 Philadelphia Street, Indiana, PA 15701 (724)-463-TEST

FAX (724}-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42PM 10/30/2009 Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium

- ICP Magnesium-ICP Manganese

- ICP Mercury Molybedenum

- ICP Nickel- ICP Selenium-ICP Silver-ICP Sodium- ICP Strontium

- ICP Zinc -ICP Detergents, MBAS Ethylene Glycol Oil and Grease

- HEM Phenolics,

as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Radiologicals
Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result GJT 10/2112009 38.600 GJT 10/21/2009 21.200 GJT 10/2112009
ND GJT 10122!2009 72.500 GJT 10/23/2009 384.400 GJT 10/21/2009 4.000 DMM 10/1512009
ND GJT 10121/2009
ND GJT 10121/2009
ND GJT 10121/2009
ND GJT 10/22/2009
ND GJT 10/22!2009 26743.000 GJT 10123/2009 720.700 GIT 10121/2009
ND 1L 10/09/2009 0.614 MetPeal 10/20/2009 <25.000 CLM '1012012009
ND MAD 10/1312009
ND LL 10/0812009 112400 CLM 10/1412009 104800 ALD 10/13/2009
472 enchmru 10/3012009

"' Comments: Radiologicals done by Benchmark Analytical **~** DEP Certification

#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431

H Units mgll mgll mgll mgll mg/lmgll mgll mgll mgll mgll mg/1 mgll mg/1 mg/1 mg/1 mglkg - mgll mgll uS/em mg/1 mg/1 mg/1 Data Qualifiers:

D = The reported value
is from dilution.

E = Estimated value.

S = Surrogate out of control limits. Method RPL 200.7/6010 1.000 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 50.000 200.7/6010 50.000 200.7/6010 0.500 245.1 0.0002 200.7/6010 0.500 200.7/6010 0.500 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 500.000 200.7/6010 1.000 200.7/6010 0.500 SM5540C 0.200 300

. 0M 25.000 1664A

5.0 420.1 0.500 SM2510B

1 SM2540C

25 SM2540D

5 RAD-CTDHS

0
. 000 fD=Not Detected R = Sample received out of holding time.

H = Sample analyzed out of holding time.

C = Sample received

in incorrect container. B = Analyte was detected

in both sample and methods blank.

x = User defined data qualifier

.

Page
2 of• ..,, vv1 .. vvv

... v
• .. .., **•~......, v~vv•**  **-.v~v-.** - , LAB ID #· 39-00401 SEND DATA TO: NAME: Mike Moyer BENCHr.J.ARK ANALYTICS, INC. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100 FAX (610) **974~ 8104**  COMPANY: EnVIronmental Service Laboratories,
Inc ADDRESS: 1803 Phnadelphia

St PHONE: FAX: Indiana, PA 15701 (724) 463-8378 (724) 465-4209
TEST REPORT

Work Order: 09101656 WO#: 09101656 PAGE: 2of2 PO#: OAS1 0092009 PWSIO# 09 29350
& 09 29510 REGEIVED FOR lAB BY: OMB DATE: 10/121200910:00

Pagc2 (lf2 SAMPLE:

09 29510

Lab 10: 09101656-0026 Grab SAMPLED BY: David A. Stile Sample TII'I'IG 1010812009 9:15 Thorium SAMPLE:
09 29510 Result **~ ~**  Y!!!m < 0.0131

:t 0.00

0 mgiL Method EPA200.8 Lab 10: 09101656-002A
G. 6aa!Ysls Start Analysis End Analyst• 10113109 8:30 10116109 GSR-CV --- Grab SAMPLED BY: David A. Stile Sample Time 1010612009 &:15 !m **~ ~**  Gross Alpha
1971

;I; 221.3 Gross Beta 2285

t 140.7 SAMPLE:
09 29510

MQA 746.9 682.4 Units **~** pCIIL **~** EPA900.0 EPA900.0 **~** Analysis Start Ana!y&!s Enc! **~** 10113109 8:50 10116109 BP$-CV 10113109 8:50 10/16109 BPS.CV ---

· ------ Lab 10: 09101656o0028 Grab SAMPLED BY: David A. Stile SaJ'11)1e T.me 10/0812009 9:15 Radlum-226 ---··--- SAMPLE:
09 29510 **~** Uncert. MQA **~** 464.9

;I; 15

. 84 59.4 pCliL **~** EPA$03.0 yg, Analysis Start Al\alySI$ End 611i!m! 1011610911:15 10129109 BH.CV LabiD: **09101~2C ~b**  SAMPLED BY: Davlcl A. Stile Sample Tme 1010812009 9:15 II!S Redium-228 SAMPLE:
09 29510 B!!!!!!l 1.!JDd. MQ6 **~** 148.7

:1: 11.10 14.16 pCIIL EPA904.0 **~** 6na!Y!Is Start **Ana!ys~** En<! **~** 10121109 **8:0~** 10127109 NLB-CV .. .. ____

. ---·--- Lab 10:- 0910165$-0020 Gr.b SAMPLED BY: David A. Stile Sample Tme 1010612009 9:15 J)§t Uranium Urinlum REMARKS:

Result **~** < 13.13

:1: 0.00 <8

. 93
:1: 0.00 ··---

· -· MQA 0 0 !.!niSl IJQJI.. pCil\. **~** EPA200.8 EPA200.8 ---·· ---

..
· ··· MCl 6naMis Start Anatvsls End **~i!!** 30 10119109 10:00 10123109 GSR..CV 10/19109 10:00 10123109 GSR-CV The above test procedures meet all the requirements

of NELAC and relate only to these sample$. " CV;::; Benchmark Analytics, Inc

. Center Valley, PA; SA
• Benchmark An<tlytics, Inc. Sayre, PA MS Umit of detection **incre~ed** due to matrix interference ""d spike recovery (lata MANAGER **~I?Jd_** ...

. **--~**

...

DATE: 10/30/2009-- -- --- ....... - -- --- ---- i= **i\i\iilf0Ni\ii~NT6i** ..
I 'W Y

I ...... **~**

I 'WI Y I -I 'W II ,. SERVICE LABORATORIES,
INC. 1803 Philadelphia Street Indiana, PA 15 701 (724)-463-TEST

FAX (724}-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42PM 10/30/2009 Analyte Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 26.40 RO 10/09/2009
ND Comments: Radiologicals done by Benchmark Analytical _ **~** DEP Certification

lis 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431

H Units ug/L ug/L Data Qualifiers:

D =The reported value is from dilution.

E = Estimated value

. S = Surrogate out of control limits

. Method RPL 624/8260B 20.00 624/8260B 20.00 \ND=Not Detected R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received

in incorrect container

. B = Analyte was detected

in both sample and methods blank.

x = User defined data qualifier

.

Page
3 of:-- -- --- **~** - -- --- -- - - -=- - .. .. • • o-f.;. **I!~~** IS -!:'a. 1!-=-

-
• NV I_..( .In; u;i-lu IAI t . .. Y
I ..... **~**

I 11 1f I - I 11 II '-• SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15 701 [724)-463-TEST

FAX (724)-465-4209 Name: XTOEnergy Sample Start Date:
395 Airport Road Indiana, PA 15701 10/8/2009 10/8/2009 2:42PM 10/1212009 Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Comments:
DEP Certification

lis 32-00382 Report of Analysis Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009
ND RO 10/09/2009
ND

09 29511 Waste Water Grab NEW (Client) Trip Blank Units ug/L ug/L Method MDL 624/8260B
1.00 624/8260B
1.00 IND=Not Detected Page

1 of 1254Q.PM-BWM0347

Ray 112011 COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT
OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERATOR This fonn must be fully and accurately typed or legibly printed
In the spaces provided.

If additional space is necessary, Identify each attached sheet as Fonn 26R, reference the Item number and identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised
219/11

. Company Mailing Address Une 2 c.

-1

-

10# No254o.PM..awJI0347

Rev 112011 c. Address Une
1 Address Une
1 Address City State ZIP Municipality Title Phone Name d. Volume of waste a. c. b. Address Une

1 Address Une
1 Address City State ZIP Municipality Title Phone Contact Name Volume of waste

Indiana gal D lb (check one) processing
or utilized. or disposal facility In the previous year. D gal D lb D ton (check one) year. D lb D ton (check one) -2

-I certify, under penalty of law, that

I have peraonally examined and am familiar with the Information submitted

in this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible for obtaining the lnfonnation,

I verify that the aubmltled Information

Is true, accura18 and complete
to the best of my knowledge.

I undenstand that the submission

of false lnfonnation herein Is made **a~bject** to the penalties
of 18 Pa. C.S. §4904, relating to unsworn falsification

to authorities, which Include fine and Imprisonment. Check the following,

If applicable: 0

I certify the Information required
In Section B-1, General Properties was supplied
to the Department for the year _and has not changed. Fonn Submitted:

0 Fonn 26R 0 Other (specify) Date Submitted: 0

I certify the Information required
In Section B-2, Chemical Analysis was supplied
to the Department for the year _and has not changed. Fonn Submitted:

0 Fonn 26R D Other (specify) Date Submitted: D

I certify the Information required
In Section B-3, Process Description and Schematic, was supplied
to the Department for the year_ and has not changed. Fonn Submitted:

0 Fonn 26R 0 Other (specify) Date Submitted: Name of Responsible Official

Title EH & 5 Man er Marcellus Shale Bernhardt Kissel Signature

Date 2-28-11 -3
-February

8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I• All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are com posited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic
or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal
at various PaDEP permitted waste disposal facilities on different schedules determined

by individual well characteristics. Grab samples
of the composited fluids were obtained
at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts
of lost fluids. Samples were obtained with bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory. Flowback samples were composited

to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory
or on the well location upon completion

of the composite sampling process. Samples were distributed into bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested.
All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process
at various times and combined into a composite sample for analyses
at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed
on both sample composites.

In some earlier cases during the utilization
of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness

of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged

to closed containment and is re-conditioned and reused from well to well.I• February

9, 2011 Form 26R: Section 83a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated

in the well bore during the penetration

of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust
to absorb remnant fluid aod loaded out for disposal
at a landfill. Fluids are currently stored
in closed containers

to be processed for reuse. Flowback: "Fracing Fluid" Flowback

is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results
in the setting of a propant within the formation fractures

. Production Fluid "Brine" During the production
of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.• -

Well I. D.# (various) '\\/ -a- /· ....... 1\ \ \ \ \ \ \ \ COUNTYB ote: .

\ \ Process producing waste: Gas well produced fluids (brines) are typically produced · in conjuction with natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur . es.

/ /

COUNTY A Well I. D.# (various) \ I .::-oy"' / / / / //I' / _ :::::;::: Road Transport -----Landfill or**Treu.f~U\+** 'PlGV\t

(..) i w ::r: (.) (/') z 0 **~ ~**  0 a.. (/') z **~** 1- **~~ ~**  ; i - !e **~** u - **~] i~**  **~ ~I**  **~ ~!**  z ... **~ ~**  **~** .. ;c! ii uT E STING Environmental and Energy Analys

i s Friday, February 04, 2011 RICK BONAZZA RESOURCE MANAGEMENT SERVICES 65 FENTON ROAD INDIANA, PA 15701 RE: 26R Analysis Dear RICK BONAZZA:
OrderNo.: G1012349 Geochemical Testing received

1 sample(s) on 12/10/2010
for the analyses presented

in the following report. There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory specifications except where noted in the Case Narrative
or Laboratory Results. If you have any questions regarding these tests results, please feel free to call. Sincerely, Timothy W. Bergstresser Director of Technical Services
PaQe

1 of 5

2005 N Center Ave Somerset PA 15501 814/443-1671 814/445-6666 FAX: 814/445-6729 1.0. 56-00306 PA OEPGeochemical Testine CLIENT: Project: Lab Order: RESOURCE MANAGEMENT SERVICES 26R Analysis Gl012349

.

Date: 04-Feb-11 CASE NARRATIVE No problems were encountered during analysis of this workorder, except if noted in this report. REVISED REPORT (2/4/11): Sample description changed. The ethylene glycol analysis was subcontracted

to Free Col. A copy of the subcontractor's laboratory report
is enclosed with this Analytical Report. The radiological analysis was subcontracted

to Pace Analytical.

A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. Legend:
NO

- Not Detected

at the Quantitation Limit J - Indicates
an estimated value

. U -The analyte was not detected

at or above the listed concentration

, which
is below the laboratory quantitation limit. B - Analyte detected
in the associated Method Blank Q - Qualifier
QL -Quantitation Limit OF- Dilution Factor

S -Spike Recovery outside accepted recovery limits R - RPD outside accepted recovery limits E- Value above quantitation range •• -Value exceeds Action Limit H - Method Hold Time Exceeded MCL- Contaminant Limit

J.D

. 56-00306 PA DEP Page

. 2 of 5Laboratory Results Geochemical Testing

Date: 04-Feb-1

1 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES 01012349

Client Sample ID: ICA Well 8431H RMS 1/12/8 Project:
26R Analysis Lab ID: 01012349-001 Matrix: AQUEOUS Analyses INORGANIC NON-METALS Ac

i dity to pH 8
. 2 INORGANIC NON-METALS Alkalinity

to pH 4

. 5 PHYSICAL TESTS Specific Conductance PH BY SM 4500 H+B Lab pH INORGANIC NON

- ME:TALS Total dissolved solids PHYSICAL TESTS Total suspended solids INDICATOR ORGANIC PARAMETERS **BOD~ay**

Result 470 <;5 209000 4.00 298000 52 6 Finish Date/Time 12115/201012

: 55 INDICATOR ORGANIC PARAMETERS Chemical Oxygen Demand INORGANIC NON-METALS Bromide Chloride Sulfate INORGANIC NON-METALS MBAS NOTES:

15000 1240 169000 <; 100 0

. 12 Sampled By: Client Collection Date: 12/8/20

I 0 I
: 20:00 PM Received Date: 12/10/2010 8:34:18 AM ,. QL Q Units SM 231 08(4A) 0 mg/LCaC03 SM 18 23208 5 mg!LCaC03 EPA 120

. 1 JJmhos/cm SM4500-H+B
0
su SM 2540C 100 mg!L SM 2540D 5 mg/L SM 5210
B 3 mg!L 0 mg/L HACH 8000 200 mg/L EPA300.0 40.0 mg/L 200 mg/L 100 mg!L SM 5540C 0.050

s mg/L as LAS DF 5 3 3 20 200 200 50 Date Analyzed Analyst: LNW 12116/2010

9
: 16:00 AM Analyst: LNW 12/15/2010

4
: 52

: 00 PM Analyst: LNW 12/15/2010

4

: 52:00 PM Analyst: LNW 12/15/20104

: 52:00 PM Analyst: KLS 12/10/2010 10:03

: 00 AM Analyst: KLS 12/10/2010

6
: 57:42 AM Analyst: MMR 12/10/2010

1 : 00

: 00 PM 12/10/2010

1
: 00:00 PM Analyst: MGV 12/15/2010 Analyst: CAS 12/17/2010

7
: 28:00 PM 12/17/2010

7
: 28:00 PM 12/16/201010

: 41:00 PM Analyst: MMR 12/10/2010

10

: 05:00 AM S - Spike recovery indicates

a possible matrix effect

. The method

is in control as indicated
by the LCS

. INORGANIC NON-METALS

EPA 350.1 Ammonia Nitrogen

- Distilled

258

10

. 0 INORGANIC NON-METALS

EPA 353.2 Nitrate

- Nitrite

0

. 72

0

. 05 INDICATOR ORGANIC PARAMETERS EPA420.1 Phenolics

<; 100
100 INORGANIC NON-METALS

EPA 351.2 Total Kjeldahl Nitrogen

227

20

. 0 INORGANIC METALS

EPA 200.7 Paae
3 of 5 mg/L as N mg/l as N JJg/l mg/L as N Analyst: SLY 100 12/28/201010

: 43:39 AM Analyst: SLY 12/16/2010

9
: 06

: 14 AM Analyst: SAG 5 12/17/20101

: 11

: 00 PM Analyst: SLY 20 12/21/2010

2
: 44:00 PM Analyst: MS LD

. 56-00306 PA DEPLaboratoryResultsGeochemicalTestingDate:04-Feb-1ICLIENT:LabOrder:RESOURCEMANAGEMENTSERVICESGl012349ClientSampleID:ICAWell8431HRMS1/12/8Project:26RAnalysisLabID:G I012349-00IMatrix:AQUEOUSAnalysesINORGANICMETALSIron,dissolvedINORGANICMETALSMercuryINORGANICMETALSAluminumArsenicBariumBerylliumBoronCadmiumCalciumChromiumCobaltCopperIronLeadLithiumMagnesiumManganeseMolybdenumNickelSeleniumSilverSodiumStrontiumZincHardness(SM2340B)INORGANICMETALSThoriumUraniumVOLATILEORGANICCOMPOUNDSBenzeneTolueneSurr:1,2-Dichloroethane-d4Surr:4-BromofluorobenzeneSurr:Toluene-dBINDICATORORGANICPARAMETERSOil&GreaseResult106<0.200.2<0.0215000<0.00116.00.01743400<0.010.8660.02128<0.02196301048.5<0.02<0.01<0.02<0.00581800154000.12121000<50.0<50.0<1.0<1.0120108102<5SampledBy:ClientCollectionDate:12/8/20101:20:00PMReceivedDate:12/10/20108:34:18AMQLQUnitsEPA200.70.05mg/LSM311280.20(Jg/LEPA200.70.1mg/L0.02mg/L20.0mg/L0.001mg/L0.50mg/L0.002mg/L10.0mg/L0.01mg/L0.005mg/L0.01mg/L0.05mg/L0.02mgll10.0mg/L10.0mg/L0.10mg/L0.02mg/L0.01mg/L0.02mg/L0.005mg/L100mg/L20.0mg/L0.01mg/L100mg/LCaC03EPA200.8·50.0(Jg/L50.0(Jg/LEPA82601.0IJg/L1.0(Jg/L70-130%REC70-130%REC70-130%RECEPA16645mg/LPage4of5DFDateAnalyzedAnalyst:MS12/20/20101:51:00PMAnalyst:MS12/14/20101:03:35PMAnalyst:MS12/16/20108:21:00PM12/16/20108:21:00PM200012/29/20103:48:00PM112116/20108:21:00PM1012/22/20101:37:00AM12/16/20108:21:00PM10012/22/20101:20:00AM112/16/20108:21:00PM12/16/20108:21:00PM12116/20108:21:00PM12/16/20108:21:00PM12/16/20108:21:00PM50012/28/20102:18:00PM10012/22/20101:20:00AM1012122/20101:37:00AM12/16/20108:21:00PM12/16/20108:21:00PM12/16/20108:21:00PM112/16/20108:21:00PM5001/13/20111:42:00PM200012/29/20103:48:00PM12/16/20108:21:00PM10012/22/20101:20:00AMAnalyst:JEK5012/21/20101:42:42PM5012/16/20101:29:00PM1.03Analyst:JAW12/15/201011:31:00AM12/15/201011:31:00AM12/15/201011:31:00AM12/15/201011:31:00AM12/15/201011:31:00AMAnalyst:JDH12/14/20108:42:00AMI.D.56-00306PADEPLaboratoryResultsGeochemicalTestingCLIENT:LabOrder:Project:LabID:Matrix:RESOURCEMANAGEMENTSERVICES0101234926RAnalysis.G1012349-001AQUEOUSDate:04-Feb-11ClientSampleID:ICAWell8431HRMS1/12/8SampledBy:ClientCollectionDate:12/8/20101:20:00PMReceivedDate:12/10/20108:34:18AM-···---·····------------·--AnalysesVOLATILEORGANICCOMPOUNDSEthyleneGlycolRADIOLOGICALTESTINGGrossAlphaGrossBetaRADIOLOGICALPARAMETERSRadium226RADIOLOGICALPARAMETERSRadium228Result<119391+-21871432+-8101540+-2913089+-606QLQEPA801511EPA900.03.004.00EPA903.11.00EPA904.01.00-------------------------------··------------------Page5of5UnitsDFDateAnalyzedAnalyst:SUBmg/L1212212010Analyst:SUBpCill12118/2010pCill12118/2010Analyst:SUBpCill12128/2010Analyst:SUBpCi/L1/7/2011I.D.56-00306PADEP2540.PM-BWM0347 Rev.1

1 COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT

OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR must typed or legibly printed
In the spaces provided.

If additional space is necessary, identify each attached sheet as Form 26R, reference the item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised

219/11 c. Physical Appearance

-1

-

ID# 22540-PM-BWM0347Rev.1/2011b.b.c.d.PA0095273FacilityNameAddressUne1AddressUne1AddressCityStateZIPMunicipality-AddressUne1AddressLine1AddressCityStateZIPMunicipalityTitlePhonewasteshippedtoprocessingordisposalfacilityinDcuydDgalDlbVolumeofwaste-2-Indianasteve@pabrine.com(checkone)(checkone)0ton(checkone)2540..PMooBWM034TRev.112011Icertify,underpenaltyoflaw,thatIhavepersonallyexaminedandamfamiliarwiththeinformationsubmittedinthisAnnualReportandallattacheddocumentsandthatbaseduponmyInquiryofthoseIndividualsImmediatelyresponsibleforobtainingtheInformation,IverifythatthesubmittedInformationistrue,accurateandcompletetothebestofmyknowledge.Iunderstandthatthesubmissionoffalseinformationhereinismadesubjecttothepenaltiesof18Pa.C.S.§4904,relatingtounswornfalsificationtoauthorities,whichincludefineandimprisonmentCheckthefollowing,ifapplicable:DIcertifytheInformationrequiredinSectionB-1,GeneralPropertieswassuppliedtotheDepartmentfortheyear__andhasnotchanged.FormSubmitted:DForm26RDOther(specify)DateSubmitted:DIcertifytheInformationrequiredInSectionB-2,ChemicalAnalysiswassuppliedtotheDepartmentfortheyear__andhasnotchanged.FormSubmitted:DForm26RDOther(specify)DateSubmitted:DIcertifytheInformationrequiredInSectionB-3,ProcessDescriptionandSchematic,wassuppliedtotheDepartmentfortheyear__andhasnotchanged.FormSubmitted:DForm26R0Other(specify)DateSubmitted:NameofResponsibleOfficialBernhardtKisselSignatureDate2-28-11-3-February

9, 2011 Form 26R: Section 81 e GENERATOR KNOWLEDGE All Form 26R Waste Forms have been compiled, and future testing has been scheduled,

to obtain samples
of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every
5 years for each waste stream unless the process that generates any particular waste stream

is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation
as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February

8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

i· All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic
or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal
at various PaDEP permitted waste disposal facilities on different schedules determined
by individual well characteristics. Grab samples
of the composited fluids were obtained
at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts
of lost fluids. Samples were obtained with bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory. Flowback samples were composited

to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory
or on the well location upon completion

of the composite sampling process. Samples were distributed into bottle

. sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested.
All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process
at various times and combined into a composite sample for analyses
at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed
on both sample composites.

In some earlier cases during the utilization
of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness

of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged

to closed containment and is re-conditioned and reused from well to well.February

9, 2011 Form 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids• Remnant drill fluids are generated

in the well bore during the penetration

of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought
to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust
to absorb remnant fluid and loaded out for disposal
at a landfill. Fluids are currently stored
in closed containers

to be processed for reuse. Flowback: "Fracing Fluid" Flowback

is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results
in the setting of a propant within the formation fractures. Production Fluid "Brine" During the production

of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.Well I. D.# (various) Well I. · D.# . (various) ,,/

**~**

-0 -y- /v, /1' COUNTY A I \ I \ / Well I. D.# (various) \ \! I .::o/ \ I II' \ I // \ I / \ I // \ / . . \ I / Well I. D.# (various) \ 1 // '\\/ / \ I /

- COUNTYB -0.- / " **~** CJ-:_.1

**'<'"Qfloo.>~~; ~~**  Mobile Tank Truck **'\)r-o~\X-·h~.l\** Ocu
**1\\~~~** . **~;** . Road Transport

**\CIJ\~S** "• **~** , ;: br1ne (TYP.) .... . . ... ote: . Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction wi.th natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur . es.

- -----Landfill or**Tr-ev..+M.~** + 'P\(AA t

(.) **~ ~**  w :r: (.) (/) z 0 **~ ~**  0 0.. (/) **~** 1- **~~** a! **I~ ~**  I

t: -g ;.., a **~!!I** " **~ill** z !!! I

: I **~I .;**  f **~ ~**