prepared. The date on attached sheets needs to match the date noted below. 

287.54 

c. Physical Appearance 

Number of Solid or Uquid Phases of Separation 

2 

Describe each phase of separation.~~--------------; 

-1 -
b. Facility Name 

c. 

Address Line 1 Address Line 1 

Address City State ZIP 

Municipality 

Facility Contact Name 

Title 

Phone steve@pabrine.com 

facility In the previous 

gal 0 lb 0 ton (check one) 

Address Line 1 Address Line 1 Address City State ZIP 

Municipality 

c. Facility Contact Name 

rrtle 

Phone 

If "Yes", list the permit number or approval number. 

b. Volume of waste beneficially used in the year. 0 cuyd D gal 0 lb 0 ton (check one) 
Form Submitted: D Form26R 

D Other (specify) 

Date Submitted: 

D I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

__ and has not changed. 

Form Submitted: D Form26R 

D Other (specify) 

Date Submitted: 

D I certify the Information required In Section ~. Process Description and Schematic, was supplied to the Department 

for the year __ and has not changed. · 

Form Submitted: D Form 26R 

D Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 2-28-11 

-3-
GENERATOR KNOWLEDGE 

All Foim 26R Waste Forms have been compiled, and future testing has been scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Sarr:'ples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions atthe laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.D.#.(various) 

-0 

'\/ -y-

~ /v, /1' 

COUNTY A 

I\ I 

\ / Well I. D.# (various) 

\ \! 

\ I ~0/ 

\ I //I' 

\ I / 

\ I // 

\ I // 

. \ I / 

Well I. D.# (various) \ 1 // 

'\/ / \ I / 

-0.- / " 

-

COUNTYB 

C( / 

~~ ~o~-- FIO<o>~.....\<. ~7 { 

"'i''O~ . ~ Mobile Tank Truck 

'fr-o~IX.-·ho.f\ Ocu 1\\~~~ \OJ\~S ~; . . Road Transport "• ~ :: br1ne (TYP.) 

ote: . 

...... 

.. . 

Process producing waste: Gas well produced 

fluids (brines) are typically produced in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or phy$.icallift procedur.es. 

- --------Landfill or 

Treu.+~U\+ 'Pl(Mt 

(.) 

~ ~ w 

::r:: 

(..) 

(/) 

z 

0 

~ 

~ 0 

0.. 

(/) 

~ 1-

'~illf 

~~~~ ~ .. ~ ~ 

i I ~ I ~ 

~~ ~ 

~ i - lC ~ Cl -

I

t= l ~~ 

~ i~ . ~ ~! ~ ~ l~ 

u· 
... ....... -

ENVIRONMENTAL SERVICE SAMPLE REQUEST & CHAIN OF CUSTODY LABORATORIES, INC. . PAGE __ OF_ ,__ 

... HEADQUARTERS: SOUTHERN DIVISION: 

1803 Philadelphia Sl KJ 1278 BenUeyville Road D 8 Indiana, PA 15701 Van Voorhis, PA 15388 REC'D NOV -4 2009 · 

(724) 463-TEST (724) 258-TEST 

(724) 465-4209 (724) 258-8378 .. 

FOR INTERNAL LA BORA I UI<Y Use ONL 'Y 

Sample Type 

Sample Identification ESL# Composite Grab Matrix # of Containers Container Type Analysis Requested 

Date on/off Time on/off Da.te Time · Preoervatlve 

lf,q If ;R'/31 fl. O[<J5'!1J ----- ---- /6 /_ .. !. ww 

Plastic Liter pH, SC, Choride, Sulfate, 

----- ---- ttrtS 1 Alkalinity, Acidity, Bromide / '~L.., none 

~ 

----- fe> It <>t.:l:. ~ 1t ww 2 

Plastic Liter TSS, TDS, Dissolved Iron, 

----- ---- I~ none Boron, BOD, MSAS Surfactants 

---- _.;....--

1!081:. ww 

Plastic Liter AI, As, Sa, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg, 

---- ---- /0 ~ ' 1.5 1 

HN03 Mn, Hg, Ni, Se, Ag, Sr, Zn, ll, Na, Ca, Mo, HardnE~s 

---- ---- ~" '1 t5 ww 1 Plastic Liter 

---- ----

10 Nitrate+Nitrite, TKN, Ammonia, COD 

H:zSO, 

~ 

---- lf~~k (2) 1000 mL Plastic Liter Gross Alpha, Gross Seta 

___..-- ~ ~ ' ww Radium 226, Radium 228 

-to 1,5 (3) 500 ml HN03 Thorium, Uranium 

----- ---- Cj 1.5 ww Amber Glass L 

----- ---- /0 o8 1 Oil & Grease 

HCI 

---- ---- lf::>gk~ ww 

Amber Glass L 

---- ---- /0 ' 

1:1> 1 Total Phenolics 

H2so, 

----- ---- b8"- ~ Amber VOA Vials 

---- ----

/o I~ ww 2 Ethylene Glycol none 

---- ---- 1cy, ot/o• 1 I~ ww 2 

Amber VOA Vials 

----- ----

HCI 

Benzene, Toluene 

TRIP BLANK t:J-9 ---- ---- :::::::::-~ Water 2 · f.mber VOA VIals 

'21~11 ---- ---- HCI 

Benzene, Toluene 

THE UNDERSIGNED PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVEIU1 ~YS Ol.O. Project Notes: 

1. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1112% PER MOI'ffii (18% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW.) 

2. THE UNDERSIGNED PURCHASER AGREES TO PAY. IN THE EVENT HIS ACCOUrorT BECOMES DEUNOUErorT AND IS TURNED OVER TO ANY 

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENOArorT COLLECTION COSTS. 

/L_~/~,.d' tc?nJ~ 9 ... /$".,tf'A? Company/Name: XTO ENERGY 

H_ 

Sampl~ By: (Signature) ~ Date/ Time 

'( A d'_g: ~ lr>~'1?-e>Cf rl{~~.;- . ~-~ I o -'6-ocf 1'1"-),~ Address: 395 AIRPORT ROAD 

Relinquish~: (Signatural., Date/ Time ~:y.(SIV r-1£ dat~Time Nl/3 INDIANA, PA 15701 

-:g·~ (o-g-cq ( l.f\ ~s- wd. ··uu I N) -rf",-tJ"1 

Reiin'quished By: (Signature) Date/ Time 'Weceived By: (Signature) ~ Oat~ Time 

Contact Person: MR. MIKE HAHN 

Relinquished By: (Signature) Date/ Time 

Received By: (Signature) Date/ Time Phone: (724) 349-0600 

CHAIN OF CUSTODY SEAL BROKEN: Yes No 

Fax: (724) 349-8489 

- 1-/Q.I/ f'/J/ f.l 
(

)

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42PM 

10/30/2009 

Analyte 

Acidity to pH-8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Bromide 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

SulfateASTM 

Total Nitrate + Nitrite as N 

Aluminum - ICP 

Arsenic-ICP 

Barium- ICP 

Beryllium - ICP 

Boron 

Cadmium - ICP 

Calcium- ICP 

Chromium- ICP 

Cobalt- ICP 

Copper- ICP 

Hardness 

Report of Analysis 

Analyst 

BF 

JS 

szc 

MAD 

MAD 

AJD 

BF 

MAD 

LL 

LMB 

AID 

GIT 

GIT 

GJT 

GIT 

MAD 

GIT 

GJT 

GIT 

GJT 

GJT 

GIT 

Sample ID#: 

Sample Type: 

Sample Source: 

09 29510 

Waste Water 

Grab 

Sampler: 

Client Sample ID: 

NEW (Client) 

Hall8431 H 

? ;tUt 4 

Analysis Sample Units Method 

Date Result 

10/11/2009 ND mg/1 as CaC03 SM2310B 

10/1212009 175 mg/1 as CaC03 SM2320B 

10/1212009 68.7 mg/1 SM5210B 

10/1512009 1002.5 mg/1 SM5220D 

10/19/2009 62.73 mg/1 sM4500NH3B & I 

1012112009 554.00 mg/1 01246-99 

10/09/2009 51663.1 mg/1 SM4500ClC 

10/1912009 33.1 mg/1 SM4500Norg-C,D 

10/0812009 6.60 su SM4500H-B 

10/1212009 ND mg/1 0516-02 

10/1912009 ND mg/1 SM4500N03E 

1012112009 ND mg/1 200.7/6010 

1012212009 ND mg/1 200.7/6010 

1012112009 388.800 mg/1 200.7/6010 

1012212009 ND mg/1 200.7/6010 

10/2612009 15.00 mg/1 SM4500B-B 

10122/2009 ND mg/1 . 200.7/6010 

1012212009 4248.800 mg/1 200.7/6010 

1012112009 ND mg/1 200.7/6010 

10/2112009 ND mg/1 200.7/6010 

1012112009 ND mg/1 200.7/6010 

10/23/2009 12192 mg/1 SM2340B 

RPL 

2 

20 

2.0 

500.0 

1.00 

20.00 

1.0 

5.5 

0.01 

5 

0.05 

1.000 

l .QOO 

0.500 

0.500 

12.50 

0.500 

50.000 

0.500 

0.500 

0.500 

1 

Comments: Radiologicals done by Benchmark Analytical fD'"Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S "' Surrogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/812009 9:15AM 

10/812009 2:42PM 

10/30/2009 

Analyte 

Iron- ICP 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium- ICP 

Magnesium-ICP 

Manganese - ICP 

Mercury 

Molybedenum - ICP 

Nickel- ICP 

Selenium-ICP 

Silver-ICP 

. Sodium - ICP 

Strontium - ICP 

Zinc- ICP 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

GIT 10121/2009 38.600 

GIT 1012112009 21.200 

GIT 1012112009 ND 

GIT 1012212009 72.500 

GIT 1012312009 384.400 

GIT 1012112009 4.000 

DMM 10/1512009 ND 

GIT 10/2112009 ND 

GIT 10/2112009 ND 

GIT 1012112009 ND 

GJT 1012212009 ND 

GIT 1012212009 26743.000 

GIT 1012312009 720.700 

GIT 10121/2009 ND 

TL 10/0912009 0.614 

!MetPeal< 10120/2009 <25.000 

CLM ·10/20/2009 ND 

MAD 10/13/2009 ND 

LL 10/08/2009 112400 

CLM 10/14/2009 104800 

ALD 10/13/2009 472 

enchmru 10/30/2009 * 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

mgll 

mgll 

mgll 

mgll 

mgll. 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mg/kg 

·mgll 

mgll 

uS/em 

mgll 

mg/1 

mg/1 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

200.7/6010 1.000 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 50.000 

200.7/6010 50.000 

200.7/6010 0.500 

245.1 0.0002 

200.7/6010 0.500 

200.7/6010 0.500 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 500.000 

200.7/6010 1.000 

200.7/6010 0.500 

SM5540C 0200 

300.0M 25.000 

l664A 5.0 

420.1 0.500 

SM2510B 1 

SM2540C 25 

SM2540D 5 

RAD-CTDHS 0.000 I 

IND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 2 of 
ADDRESS: 1803 PhUadelphla St PAGE: 2of2 

Indiana, PA 15701 

PHONE: (724) 463-8378 

FAX: (724) 465-4209 

09 29350 & 09 29510 

RECEIVED FOR LAB BY: DMB 

SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

l!m Result 

Thorium < 0.0131 

---

SAMPLE: 09 29510 

SAMPlED BY: David A. Stile 

Iu1 

~ 

Gross Alpha 1971 

Gross Beta 2285 

SAMPLE: 09 29510 

SAMPLED BY: David A Stie 

PO#: DAS10092009 

TEST REPORT PWSID# 

DATE: 10/121200910:00 Pagc2 Clf2 

Leb 10: 091016~E Grab 

SamPle T.ne 10/0812009 9:15 

~ MQA Units Method 

t: 0.00 0 mgiL EPA200.8 

Leb ID: 09101656-002A 

Sample Time 1010&'2009 9:1S 

~ g Units 

~ 

:t221.3 746.9 pCUL EPA900.0 

t 140.7 682.4 pClll EPA900.0 

t.Q. 6llii!Ysfs Start Analysis End Anatvst • 

10113109 8:30 1(){16109 GSR-CV 

---

Grab 

MQ!,. Analysis Start MaJym End ~ 

10113109 8:50 10116109 BP$-CV 

10/13m 8:50 1()(16109 BP5-CV 

--------· 

Lab 10: 09101656-0028 Grab 

Sarf1Jie Tine 1010812009 9:15 

~ 

~ tmA Units M,g. t-nalysis Start AnalySis End 6oi!xC 

Radlurrt-226 464.9 :t 15.84 59.4 pCi/L EP.I\$03.0 10116109 11:15 10129109 BH.CV ---··--- ------··-·---

SAMPLE: 09 29510 Lab 10: 09101656-002C Grab 

SAMPLED BY: Davia A. Stile Sample Tme 1010812009 9:15 

rm 

Radium-228 

Result ~ MQ6 1.!ntTl 

148.7 t 11.10 14.16 pCi/l EPA904.0 

m Analysis Start Analy!iS End ~il! 

10121109 8:0~ 10127109 NLB-CV 

SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

···------

. 

____ ,_ _ 

Lab 10:- 091016~ Grab 

Sample Tme 1010812009 9:15 ~ Result 

~ 

MDA !.!nl1i 

~ 

MCL Ane.l)lsis Start Analy!is End ~ 

Uranium < 13.13 t: 0.00 0 llQ/l. MS EPA200.8 30 1011910910:00 

Uranium <8.93 t 0.00 0 pCiiL EPA200.S 10/19109 10:00 

··--··-· .. ·--.... ... 

REMARKS: 

The ~bove test procedures meet all the tequirements of NELAC and relate only to these samples. " CV = Benchmar1< Analytics, Inc. Center Valley, PA; SA"' Benchmark Analytics, Inc. Sayre, PA 

MS Umit of detection increased due to matrtx interference ~d spike reetJvery data 

MANAGER 

o • ~t?kL a 0 • 

DATE: 

10123109 GSR.CV 

10123109 GSR-CV 

···---

1013012009 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1) Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42PM 

10/30/2009 

Analyte 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO .10/09/2009 26.40 

RO 10/09/2009 ND 

Comments: Radiologicals done by Benchmark Analytical 

. ~ DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

ug!L 

ugiL 

Data Quiilifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

624/8260B 20.00 

624/8260B 20.00 

\ND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x =User defined data qualifier. 
}

AX (724)

465

4209 

Name: XTOEnergy 

Sample Start Date: 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 

10/8/2009 2:42PM 

10/1212009 

Receipt Date: 

Report Date: 

Analyte 

I) Benzene 

47) Toluene 

Comments: 

DEP Certification #s 32-00382 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 ND 

RO 10/09/2009 ND 

09 29511 

Waste Water 

Grab 

NEW (Client) 

Trip Blank 

Units 

ug/L 

ug/L 

Method MDL 

624/8260B 1.00 

624/8260B 1.00 

\ND=Not Detected 
prepared. The date on attached sheets needs to match the date noted below. 

Une2 

c. 

Number of Solid or Uquid Phases of Separation 

No 

Describe each phase of separation.~~--------------! 

-1 -
Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

TiUe 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

TiUe 

Phone 

Indiana 

(check one) 

d. 

~;n•nrv~n to processing or disposal facility the year. 0 cu yd 0 gal 0 lb 0 ton (check one) 

0 ton (check one) 

-2-
6

0 Other (specify) 

Date Submitted: 

0 I certify the Information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

__ and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the Information required In Section B-3, Process Description and Schematic, was supplied to the Department 

for the year_ and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 1 

- 3-
Form 26R: Section 81 e 

GENERA TOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been 

scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample 

analyses will be conducted every 5 years for each waste stream unless the process that 

generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar 

waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this 

well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Fonn 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and fonnation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

fonnation fractures. 

Production Fluid "Brine" 

During the production of natural gas, fonnation pressures bring remnant frac fluids, 

during the initial production phase, and fonnation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I .. D.#.(various) 

-a 

'\/ -~-

~ / · ' /1' 

COUNTY A 

I\ I 

\ / Well I. D.# (various) 

\ 

\ I 

\ I ~0/ 

\ I /II' 

\ I / 

\ I // 

\ I // 

\ I / 

Well I. D.# (various) \ 1 // 

'\\/ / \ I / 

-0.- / " ,...-------. 

COUNTYB 

(Y / 

;/ ~o---Flow~~~/ ( 

~"ib'fo,~ . ~ Mobile Tank Truck 

~t"oblvc..tl~.f\ Ocutt,:,.~~ \w.~s ~; ~ . . \_ s Road Transport 

:: br1ne (TYP.) ..... 

... . - -----Landfill orote: 

Process producing waste: Gas well produced 

fluids (brines) are typically produced· in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

- , mechanical or physical lift procedures. 

Tr-eu.+~V\+ 'Pl(AAt 

0 

w 

~ :r: 

(.) 

(/) 

z 

0 

~ 

~ 

~ (f) 

.. z 

~ 1-

:it If ~~~- t ... ~ ~ 

i I § I ~ 

~ ~ 

S2 

s~ ...... - ~ ~ 0 

I

t: ~ ~~ C) ~ I 

~ ~! Z ~N l3 :i,.. 

15 ~ 

HI . 

e~ 
ENVIRONMENTAL SERVICE 

LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE __ OF, __ 

HEADQUARTERS: 

1803 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

rKJ 

SOUTHERN DIVISION: 

1276 BenUeyvllle Road 

Van Voorhis, PA 15366 

(724) 258-TEST D REC'D NOV -4 2009 

(724) 258-8376 

FOR INTERNAL~ATORY USE ORIT 

Sample Identification I ESL# 

lf141/,g'131 nl0

l95! () 

TRIP BLANK 09 

'295""11 

Composite 

Sample Type 

Date 

THE UNDERSIGNED PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVER 31 DAYS 01.0. 

Grab 

Time 

Cjt;l~ 

t5 

'15 

1. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 112" PER MONTH (18" PER ANNUM OR niE MAXIMUM ALLOWED BY V.W.) 

2. THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES O!UNQUENT ANO IS TVRNI!D OVER TO Alf'f 

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENDANT COLLECTION COSTS. 

Matrix I 

VWI I 

VWI I 

VWI I 

VWI I 

VWI I 

VWI I 

VWI I 

VWI I 

VWI I 

Water I 

fl. of Containers I Container Type 

PreaetVetive 

1 I Plastic Liter 

none 

2 I Plastic Liter 

none 

1 I Plastic Liter 

HN03 

1 I Plastic Liter 

H2so~ 

(2) 1000 mL I Plastic Liter 

(3) 500 mL HN03 

1 I Amber Glass L 

HCI 

1 I Amber Glass L 

H2so~ 

2 I Amber VOA Vials 

none 

2 I Amber VOA Vials 

HCI 

2 I ~berVOA VIals 

HCI 

Project Notes: 

Company/Name: 

Address: 

~~~~~--~~~~~--~~ 

Dale/ Time 

(0- g~o::c ( 'ft ~s- Dale/ Time 

Relinquished By: (Signelure) Date/ Time 

CHAIN OF CUSTODY SEAL BROKEN: Yes _No 

Heceived By: (SJgneiJ.) . - 7 Date/ Time 

Contact Person: 

~R~~~~~B~y.-c~s~~--~)--------------0-a-t~~Ti~m-e-----------;,PhDne: 

Fax: 

8 . ,j' 

I Analysis Requested 

pH, SC, Chorlde, Sulfate, / 

AlkaUnlty, Acidity, Bromide 

TSS, TDS, Dissolved Iron, 

Boron, BOD, MBAS Surladants 

AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, ~ 

Mn, Hg, Ni, Se, Ag, Sr, Zn, ll, Na, Ca, Mo, H ness 

Nitrate+Nitrite, TKN, Ammonia, COD 

Gross Alpha, Gross Beta 

Radium 226, Radium 228 

Thorium, Uranium 

Oil &Grease 

I Total Phenolics 

I Ethylene Glycol 

I Benzene, Toluene 

I Benzene, Toluene 

XTO ENERGY 

395 AIRPORT ROAD 

INDIANA, PA 15701 

MR. MIKE HAHN 

(724) 349-0600 

(724) 349-8489 

/Jo t1 'i'!JI JA 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/812009 2:42PM 

10/30/2009 

Analyte 

Acidity to pH=8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Bromide 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

Sulfate ASTM 

Total Nitrate +Nitrite as N 

Aluminum- ICP 

Arsenic-ICP 

Barium- ICP 

Beryllium - ICP 

Boron 

Cadmium - ICP 

Calcium - ICP 

Chromium- ICP 

Cobalt- ICP 

Copper- ICP 

Hardness 

Report of Analysis 

Analyst 

BF 

JS 

szc 

MAD 

MAD 

AJD 

BF 

MAD 

LL 

LMB 

AJD 

GIT 

GJT 

GJT 

GJT 

MAD 

GJT 

GJT 

GJT 

GJT 

GIT 

GJT 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

? ;:rc.At ~ 

Units Method 

10/1112009 ND rng/1 as CaC03 SM2310B 

10/1212009 175 rng/1 as CaC03 SM2320B 

10/1212009 68.7 rng/1 SM5210B 

10/1512009 1002.5 mg/1 SM5220D 

10/1912009 62.73 mg/1 :;M4500NH3B & I 

1012112009 554.00 mg/1 01246-99 

10/0912009 51663.1 mg/1 SM4500ClC 

10/19/2009 33.1 mg/1 SM4500Norg-C,D 

10/08/2009 6.60 su SM4500H-B 

10/1212009 ND mg/1 D516-02 

10/1912009 ND mg/1 SM4500N03E 

1012112009 NO mg/1 200.7/6010 

1012212009 ND mg/1 200.7/6010 

1012112009 388.800 mg/1 200.7/6010 

10/2212009 NO mg/1 200.7/6010 

10/2612009 15.00 mg/1 SM4500B-B 

10/2212009 ND mg/1. 200.7/6010 

10/2212009 4248.800 mg/1 200.7/6010 

10121/2009 NO mg/1 200.7/6010 

10/21/2009 NO mg/1 200.7/6010 

10121/2009 NO mg/1 200.7/6010 

10/23/2009 12192 mg/1 SM2340B 

RPL 

2 

20 

2.0 

500.0 

1.00 

20.00 

1.0 

5.5 

0.01 

5 

0.05 

1.000 

1.000 

0.500 

0.500 

12.50 

0.500 

50.000 

0.500 

0.500 

0.500 

1 

Comments: Radiologicals done by Benclunark Analytical \ND=Not Detected 

Note: DEP Certification lis 32-00382 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42PM 

10/30/2009 

Analyte 

Iron- ICP 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium - ICP 

Magnesium-ICP 

Manganese - ICP 

Mercury 

Molybedenum - ICP 

Nickel- ICP 

Selenium-ICP 

Silver-ICP 

Sodium- ICP 

Strontium - ICP 

Zinc -ICP 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

port of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

GJT 10/2112009 38.600 

GJT 10/21/2009 21.200 

GJT 10/2112009 ND 

GJT 10122!2009 72.500 

GJT 10/23/2009 384.400 

GJT 10/21/2009 4.000 

DMM 10/1512009 ND 

GJT 10121/2009 ND 

GJT 10121/2009 ND 

GJT 10121/2009 ND 

GJT 10/22/2009 ND 

GJT 10/22!2009 26743.000 

GJT 10123/2009 720.700 

GIT 10121/2009 ND 

1L 10/09/2009 0.614 

MetPeal 10/20/2009 <25.000 

CLM '1012012009 ND 

MAD 10/1312009 ND 

LL 10/0812009 112400 

CLM 10/1412009 104800 

ALD 10/13/2009 472 

enchmru 10/3012009 "' 

Comments: Radiologicals done by Benchmark Analytical 

~ DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

mgll 

mgll 

mgll 

mgll 

mg/lmgll 

mgll 

mgll 

mgll 

mgll 

mg/1 

mgll 

mg/1 

mg/1 

mg/1 

mglkg 

-mgll 

mgll 

uS/em 

mg/1 

mg/1 

mg/1 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

200.7/6010 1.000 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 50.000 

200.7/6010 50.000 

200.7/6010 0.500 

245.1 0.0002 

200.7/6010 0.500 

200.7/6010 0.500 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 500.000 

200.7/6010 1.000 

200.7/6010 0.500 

SM5540C 0.200 

300.0M 25.000 

1664A 5.0 

420.1 0.500 

SM2510B 1 

SM2540C 25 

SM2540D 5 

RAD-CTDHS 0.000 

fD=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 2 of 
PHONE: 

FAX: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

PO#: OAS1 0092009 

PWSIO# 

09 29350 & 09 29510 

REGEIVED FOR lAB BY: OMB DATE: 10/121200910:00 Pagc2 (lf2 

SAMPLE: 09 29510 Lab 10: 09101656-0026 Grab 

SAMPLED BY: David A. Stile Sample TII'I'IG 1010812009 9:15 

Thorium 

SAMPLE: 09 29510 

Result ~ 

~ Y!!!m 

< 0.0131 :t 0.00 0 mgiL 

Method 

EPA200.8 

Lab 10: 09101656-002A 

G. 6aa!Ysls Start Analysis End Analyst• 

10113109 8:30 10116109 GSR-CV 

---

Grab 

SAMPLED BY: David A. Stile Sample Time 1010612009 &:15 

!m 

~ 

~ 

Gross Alpha 1971 ;I; 221.3 

Gross Beta 2285 t 140.7 

SAMPLE: 09 29510 

MQA 

746.9 

682.4 

Units 

~ 

pCIIL 

~ 

EPA900.0 

EPA900.0 

~ Analysis Start Ana!y&!s Enc! ~ 

10113109 8:50 10116109 BP$-CV 

10113109 8:50 10/16109 BPS.CV 

---·------

Lab 10: 09101656o0028 Grab 

SAMPLED BY: David A. Stile SaJ'11)1e T.me 10/0812009 9:15 

Radlum-226 

---··---

SAMPLE: 09 29510 

~ Uncert. MQA ~ 

464.9 ;I; 15.84 59.4 pCliL 

~ 

EPA$03.0 

yg, Analysis Start Al\alySI$ End 611i!m! 

1011610911:15 10129109 BH.CV 

LabiD: 09101~2C 

~b 

SAMPLED BY: Davlcl A. Stile Sample Tme 1010812009 9:15 

II!S 

Redium-228 

SAMPLE: 09 29510 

B!!!!!!l 1.!JDd. MQ6 ~ 

148.7 :1: 11.10 14.16 pCIIL EPA904.0 

~ 6na!Y!Is Start Ana!ys~ En<! 

~ 

10121109 8:0~ 10127109 NLB-CV 

.. .. ____ . 

---·---

Lab 10:- 0910165$-0020 Gr.b 

SAMPLED BY: David A. Stile Sample Tme 1010612009 9:15 

J)§t 

Uranium 

Urinlum 

REMARKS: 

Result 

~ 

< 13.13 :1: 0.00 

<8.93 :1: 0.00 

··---·-· 

MQA 

0 

0 

!.!niSl 

IJQJI.. 

pCil\. 

~ 

EPA200.8 

EPA200.8 

---·· ---.. · ··· 

MCl 6naMis Start Anatvsls End ~i!! 

30 10119109 10:00 10123109 GSR..CV 

10/19109 10:00 10123109 GSR-CV 

The above test procedures meet all the requirements of NELAC and relate only to these sample$. " CV;::; Benchmark Analytics, Inc. Center Valley, PA; SA • Benchmark An<tlytics, Inc. Sayre, PA MS Umit of detection incre~ed due to matrix interference ""d spike recovery (lata 

MANAGER 

...

~I?Jd_ 

. 

--~ ... 

DATE: 10/30/2009 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1) Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42PM 

10/30/2009 

Analyte 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 26.40 

RO 10/09/2009 ND 

Comments: Radiologicals done by Benchmark Analytical 

_ ~ DEP Certification lis 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

ug/L 

ug/L 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

624/8260B 20.00 

624/8260B 20.00 

\ND=Not Detected 

R 

B 

= Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 3 of: 
Name: XTOEnergy 

Sample Start Date: 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 

10/8/2009 2:42PM 

10/1212009 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Comments: 

DEP Certification lis 32-00382 

Report of Analysis 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 ND 

RO 10/09/2009 ND 

09 29511 

Waste Water 

Grab 

NEW (Client) 

Trip Blank 

Units 

ug/L 

ug/L 

Method MDL 

624/8260B 1.00 

624/8260B 1.00 

IND=Not Detected 

Page 1 of 1 
prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

Date Prepared/Revised 219/11 . 

Company Mailing Address Une 2 

c. 

-1 -

10# 

No 
c. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Title 

Phone 

Name 

d. Volume of waste 

a. 

c. 

b. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Title 

Phone 

Contact Name 

Volume of waste 

Indiana 

gal D lb (check one) 

processing or utilized. 

or disposal facility In the previous year. D gal D lb D ton (check one) 

year. D lb D ton (check one) 

-2 -
Fonn Submitted: 0 Fonn 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the Information required In Section B-2, Chemical Analysis was supplied to the Department for the year _and has not changed. 

Fonn Submitted: 0 Fonn 26R 

D Other (specify) 

Date Submitted: 

D I certify the Information required In Section B-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. 

Fonn Submitted: 0 Fonn 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official Title EH & 5 Man er Marcellus Shale 

Bernhardt Kissel 

Signature Date 2-28-11 

-3 -
Brine fluids are com posited within the storage production tank or tank battery at each well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness of the composite sample and composite grid sample positions were varied to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section 83a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid aod loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
• 

-

Well I. D.# (various) 

'\\/ 

-a- /· ....... 

1\ 

\ 

\ 

\ 

\ 

\ 

\ 

\ COUNTYB 

ote: . 

\ 

\ 

Process producing waste: Gas well produced 

fluids (brines) are typically produced· in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedur.es. 

/ 

/ 

COUNTY A 

Well I. D.# (various) 

\ I 

.::-oy"' 

/ 

/ 

/ 

/ 

//I' 

/ 

_ :::::;::: Road Transport 

-----Landfill orTreu.f~U\+ 'PlGV\t 

(..) 

i 

w 

::r: 

(.) 

(/') 

z 

0 

~ 

~ 0 

a.. 

(/') 

z 

~ 1-

~~ ~ 

;i - !e ~ u -

~] i~ ~ ~I 

~ z ~! ... ~ ~ ~ .. ;c! ii 

u 
RICK BONAZZA 

RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, PA 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: OrderNo.: G1012349 

Geochemical Testing received 1 sample(s) on 12/10/2010 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 

PaQe 1 of 5 

1.0. 56-00306 PA OEP 
REVISED REPORT (2/4/11): Sample description changed. 

The ethylene glycol analysis was subcontracted to Free Col. A copy of the subcontractor's laboratory 

report is enclosed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's 

laboratory report is enclosed with this Analytical Report. 

Legend: NO - Not Detected at the Quantitation Limit 

J - Indicates an estimated value. 

U -The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit. 

B - Analyte detected in the associated Method Blank 

Q - Qualifier QL -Quantitation Limit OF- Dilution Factor 

S -Spike Recovery outside accepted recovery limits 

R - RPD outside accepted recovery limits 

E- Value above quantitation range 

•• -Value exceeds Action Limit 

H - Method Hold Time Exceeded 

MCL- Contaminant Limit 

J.D. 56-00306 PA DEP 

Page. 2 of 5 
Matrix: AQUEOUS 

Analyses 

INORGANIC NON-METALS 

Acidity to pH 8.2 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 

PHYSICAL TESTS 

Specific Conductance 

PH BY SM 4500 H+B 

Lab pH 

INORGANIC NON-ME:TALS 

Total dissolved solids 

PHYSICAL TESTS 

Total suspended solids 

INDICATOR ORGANIC PARAMETERS 

BOD~ay 

Result 

470 

<;5 

209000 

4.00 

298000 

52 

6 

Finish Date/Time 12115/201012:55 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 

INORGANIC NON-METALS 

Bromide 

Chloride 

Sulfate 

INORGANIC NON-METALS 

MBAS 

NOTES: 

15000 

1240 

169000 

<; 100 

0.12 

Received Date: 12/10/2010 8:34:18 AM 

,. 

QL Q Units 

SM 231 08(4A) 

0 mg/LCaC03 

SM 18 23208 

5 mg!LCaC03 

EPA 120.1 

JJmhos/cm 

SM4500-H+B 

0 su 

SM 2540C 

100 mg!L 

SM 2540D 

5 mg/L 

SM 5210 B 

3 mg!L 

0 mg/L 

HACH 8000 

200 mg/L 

EPA300.0 

40.0 mg/L 

200 mg/L 

100 mg!L 

SM 5540C 

0.050 s mg/L as LAS 

DF 

5 

3 

3 

20 

200 

200 

50 

Date Analyzed 

Analyst: LNW 

12116/2010 9:16:00 AM 

Analyst: LNW 

12/15/2010 4:52:00 PM 

Analyst: LNW 

12/15/2010 4:52:00 PM 

Analyst: LNW 

12/15/20104:52:00 PM 

Analyst: KLS 

12/10/2010 10:03:00 AM 

Analyst: KLS 

12/10/2010 6:57:42 AM 

Analyst: MMR 

12/10/2010 1:00:00 PM 

12/10/2010 1 :00:00 PM 

Analyst: MGV 

12/15/2010 

Analyst: CAS 

12/17/2010 7:28:00 PM 

12/17/2010 7:28:00 PM 

12/16/201010:41:00 PM 

Analyst: MMR 

12/10/2010 10:05:00 AM 

S - Spike recovery indicates a possible matrix effect. The method is in control as indicated by the LCS. 

INORGANIC NON-METALS EPA 350.1 

Ammonia Nitrogen - Distilled 258 10.0 

INORGANIC NON-METALS EPA 353.2 

Nitrate - Nitrite 0.72 0.05 

INDICATOR ORGANIC PARAMETERS EPA420.1 

Phenolics <; 100 100 

INORGANIC NON-METALS EPA 351.2 

Total Kjeldahl Nitrogen 227 20.0 

INORGANIC METALS EPA 200.7 

Paae 3 of 5 

mg/L as N 

mg/l as N 

JJg/l 

mg/L as N 

Analyst: SLY 

100 12/28/201010:43:39 AM 

Analyst: SLY 

12/16/2010 9:06:14 AM 

Analyst: SAG 

5 12/17/20101 :11 :00 PM 

Analyst: SLY 

20 12/21/2010 2:44:00 PM 

Analyst: MS 

LD. 56-00306 PA DEP 
Matrix: AQUEOUS 

Analyses 

INORGANIC METALS 

Iron, dissolved 

INORGANIC METALS 

Mercury 

INORGANIC METALS 

Aluminum Arsenic 

Barium 

Beryllium Boron 

Cadmium Calcium Chromium Cobalt Copper 

Iron 

Lead Lithium 

Magnesium Manganese Molybdenum Nickel 

Selenium Silver Sodium Strontium 

Zinc 

Hardness (SM 2340B) 

INORGANIC METALS 

Thorium 

Uranium 

VOLA TILE ORGANIC COMPOUNDS 

Benzene 

Toluene 

Surr: 1 ,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Toluene-dB 

INDICATOR ORGANIC PARAMETERS 

Oil & Grease 

Result 

106 

< 0.20 

0.2 

< 0.02 

15000 

< 0.001 

16.0 

0.017 

43400 

< 0.01 

0.866 

0.02 

128 

<0.02 

196 

3010 

48.5 

< 0.02 < 0.01 

< 0.02 

< 0.005 

81800 

15400 

0.12 

121000 

< 50.0 < 50.0 

< 1.0 

< 1.0 

120 108 102 

<5 

Received Date: 12/10/2010 8:34:18 AM 

QL Q Units 

EPA 200.7 

0.05 mg/L 

SM 31128 

0.20 (Jg/L 

EPA 200.7 

0.1 mg/L 

0.02 mg/L 

20.0 mg/L 

0.001 mg/L 

0.50 mg/L 

0.002 mg/L 

10.0 mg/L 

0.01 mg/L 

0.005 mg/L 

0.01 mg/L 

0.05 mg/L 0.02 mgll 

10.0 mg/L 10.0 mg/L 

0.10 mg/L 

0.02 mg/L 

0.01 mg/L 

0.02 mg/L 

0.005 mg/L 

100 mg/L 

20.0 mg/L 

0.01 mg/L 

1 00 mg/L CaC03 

EPA 200.8 · 

50.0 (Jg/L 50.0 (Jg/L 

EPA 8260 

1.0 IJg/L 1.0 (Jg/L 

70-130 %REC 

70-130 %REC 

70-130 %REC 

EPA 1664 

5 mg/L 

Page 4 of 5 

DF Date Analyzed 

Analyst: MS 

12/20/20101:51:00 PM 

Analyst: MS 

12/14/2010 1 :03:35 PM 

Analyst: MS 

12/16/2010 8:21:00 PM 12/16/2010 8:21:00 PM 

2000 12/29/2010 3:48:00 PM 

1 12116/2010 8:21:00 PM 10 12/22/2010 1 :37:00 AM 

12/16/2010 8:21 :00 PM 

100 12/22/2010 1:20:00AM 1 12/16/2010 8:21 :00 PM 

12/16/2010 8:21:00 PM 

12116/2010 8:21:00 PM 12/16/2010 8:21:00 PM 

12/16/2010 8:21:00 PM 

500 12/28/2010 2:18:00 PM 

100 12/22/2010 1 :20:00 AM 10 12122/2010 1:37:00AM 

12/16/2010 8:21 :00 PM 

12/16/2010 8:21:00 PM 12/16/2010 8:21:00 PM 

1 12/16/2010 8:21:00 PM 

500 1/13/2011 1 :42:00 PM 

2000 12/29/2010 3:48:00 PM 

12/16/2010 8:21 :00 PM 

100 12/22/2010 1:20:00AM 

Analyst: JEK 

50 12/21/20101:42:42 PM 50 12/16/20101:29:00 PM 

1.03 

Analyst: JAW 

12/15/2010 11 :31:00 AM 12/15/2010 11:31:00 AM 12/15/2010 11 :31:00 AM 

12/15/2010 11:31:00 AM 

12/15/2010 11 :31:00 AM 

Analyst: JDH 

12/14/2010 8:42:00 AM 

I. D. 56-00306 PA DEP 
- ···-- -· · ···- -----------·--

Analyses 

VOLA TILE ORGANIC COMPOUNDS 

Ethylene Glycol 

RADIOLOGICAL TESTING 

Gross Alpha Gross Beta 

RADIOLOGICAL PARAMETERS 

Radium 226 

RADIOLOGICAL PARAMETERS 

Radium 228 

Result 

< 11 

9391 +- 2187 

1432 +- 810 

1540 +- 291 

3089 +- 606 

QL Q 

EPA 8015 

11 

EPA900.0 

3.00 

4.00 

EPA 903.1 

1.00 

EPA904.0 

1.00 

-------------------------------··--------------

----

Page 5 of 5 

Units DF Date Analyzed 

Analyst: SUB 

mg/L 1212212010 

Analyst: SUB 

pCill 12118/2010 pCill 12118/2010 

Analyst: SUB 

pCill 12128/2010 

Analyst: SUB 

pCi/L 1/7/2011 

I. D. 56-00306 PA DEP 
d below. 

General Reference 287.54 

Date Prepared/Revised 219/11 

c. Physical Appearance 

-1 -

ID# 

2 
b. 

b. 

c. 

d. 

PA 0095273 

Facility Name 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality -

Address Une 1 

Address Line 1 Address City State ZIP 

Municipality 

Title 

Phone 

waste shipped to processing or disposal facility in D cuyd D gal D lb 

Volume of waste 

-2-

Indiana 

steve@pabrine.com 

(check one) 

(check one) 

0 ton (check one) 
D Other (specify) 

Date Submitted: 

D I certify the Information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

__ and has not changed. 

Form Submitted: D Form 26R 

D Other (specify) 

Date Submitted: 

D I certify the Information required In Section B-3, Process Description and Schematic, was supplied to the Department 

for the year __ and has not changed. 

Form Submitted: D Form 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 2-28-11 

-3 -
GENERATOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle.sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
WASTE GENERATION PROCESS 

Pit Water "Drill Fluids• 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.·D.#.(various) 

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ote: . Process producing waste: Gas well produced 

fluids (brines) are typically produced in 

conjuction wi.th natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedur.es. 

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