Support Documents for 

Significant New Use Rules (SNUR) on 

Premanufacture Notice (PMN) 

P-09-72 

EPA Docket EPA-HQ-OPPT-2010-1075 

 

EPA SANITIZED Page 1 of 57
Index

A-001 Structure Activity Team (SAT) Report for 

PMN P-09-72 

A-002 Initial Review Engineering Report for 

PMN P-09-72 

A-003 Initial Review Exposure Report for 

PMN P-09-72 

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A-001 

Structure Activity Team (SAT) Report 

for PMN P-09-72 

 

EPA SANITIZED Page 3 of 57
SAT Report

PMN Number: P-09-0072

SAT Date: 11/25/2008

Related cases:

Health related cases: 

Ecotox related cases: 

Concern levels:

Type of Concern: Health Eco Comments

Level of Concern: 1-2 3

 Persistence Bioaccum Toxicity Comments

 1 1 1

Exposure Based Review:

Health: No

Ecotox: No

Routes of exposure: Health: Inhalation, dermal, ingestion, drinking water

Ecotox: All releases to water

Fate: ;

Keywords:

 Keywords: IRR-E

DEVEL

UNCERT MUTA

Summary of Assessment:

 Fate:

Fate Summary: P-09-0072

FATE: 

Liquid with MP = -62.4 EC (M)

log Kow = 1.81 (M); 

S = 83 mg/L at 25 EC (M)

VP = 1.3E-2 torr at 25 EC (NOMO5)

BP = 269.1 EC (M)

H < 1.00E-8 (E)

log Koc = 2.32 (E)

log Fish BCF = 0.69 (E) 

POTW removal (%) = 90 via biodegradation; OECD 301F(Mano Resp): 14.7%/28d.

Time for complete ultimate aerobic biodeg = wk

EPA SANITIZED Page 4 of 57
Sorption to soils/sediments = low

PBT Potential: P1B1

*CEB FATE: Migration to ground water = moderate

 Health:

 Health Summary: Absorption is good all routes, based on analogs. There 

are concerns for eye irritation and developmental toxicity, and uncertain concern for 

mutagenicity, based on phenols.

 Test Data: Submitted with the PMN:

Salmonella assay negative with and without activation;

Not a dermal sensitizer in guinea pigs;

Moderate eye irritant in rabbits;

Not a dermal irritant in rabbits;

Rat acute oral (gavage) LD50 > 2000 mg/kg

Submitted with 

Salmonella assay negative with and without activation;

Not a dermal sensitizer in guinea pigs;

Not a photosensitizer in guinea pigs;

Moderate eye irritant in rabbits;

Mouse acute oral LD50 > 2800 mg/kg

Submitted with 

Not a dermal sensitizer in guinea pigs;

Not a photosensitizer in guinea pigs;

Moderate eye irritant in rabbits;

Mouse acute oral LD50 > 1800 mg/kg

 Ecotox:

Test 

Organism

Test 

Type

Test End 

Point

Predicted Measured Comments

fish 96-h LC50 25

daphnid 48-h LC50 9

green algal 96-h EC50 41

fish _ chronic value 1.9/0.006 30-day/60-day

daphnid _ chronic value 1.7

algal _ chronic value 19

Sewage Sludge 3-h EC50 _

Sewage Sludge _ Chronic Value _

Ecotox Values Comments: Predictions are based on SARs for phenols; SAR chemical class 

= phenol; MW 196; log Kow = 2.10 (EPI); pH7; effective concentrations based on 100% 

active ingredients and nominal concentrations; hardness <180.0 mg/L as CaCO3; and TOC 

<2.0 mg/L;

EPA SANITIZED Page 5 of 57
Factors Values Comments

Assessment Factor 10

Concentration of Concern 

(ppb)

1

SARs

SAR Class

Ecotox Factors Comments: 

 SAT Chair: J. Kwiat

EPA SANITIZED Page 6 of 57
A-002 

Initial Review Engineering Report 

for PMN P-09-72 

 

EPA SANITIZED Page 7 of 57
INITIAL REVIEW ENGINEERING REPORT

P-09-0072

Focus Ready Draft 12/18/2008

ENGINEER: Macek \ JAS

PV (kg/yr): 

Revision Notes/Assessment Overview:

SUBMITTER: Mane, USA (submitter)

USE:

OTHER USES: None found.

MSDS: Yes LABEL: No

Gen Eqpt: rubber or synthetic gloves/ conventional eye/face protection

Respirator: respirator not normally required, if prolonged exposure to high concentrations, use OSHA respirator

Health Effects: avoid contact with skin and eyes/ slightly irritating to skin/ moderately irritating to eyes

TLV/PEL: - none established.

CRSS: 

Chemical Name: Phenol, 2-ethoxy-4-(ethoxymethyl)-

S-H2O: 0.083 g/L @ 

VP: 1.3E-2 torr @ 

MW: 196 0.0%<500 0.0%<1000

Physical State and Misc CRSS Info:

Neat: Liquid Mfg: NK, imported

Proc/Form: Solution End Use: Solid/liquid in finished products. Submitted data: 

vanilla, amber, sandalwood scent, mp = -62.4°C, bp = 269.1°C, vp <0.001 torr (calculated), ws = 83 mg/L, log P = 

1.81, d = 1.072-1.082 g/cc, flash point = 100.7°C. The structure is consistent with IR, 1H- and 13C-NMR spectra 

provided. Estimated data: EPI (with mp entered as -62.4°C, bp as 269.1°C, ws as 0.83 g/L, log P as 1.81): bp = 

297.63°C, vp = 0.00372 torr, ws = 4.285 g/L, log P = 2.10. NOMO5 for bp = 269.1°C: vp = 0.013 torr. ACD Labs 

(Prop database): bp = 291.7°C, vp = 1.1E-3 torr, ws = 2.4 g/L, log P = 1.988.

Consumer Use: Yes

SAT (concerns):

Migration to groundwater: Moderate

PBT rating: P1 B1 T1

Health: 1-2, Dermal, Inhalation

Eco: 3, Water (All releases to water with a CC = 100 ppb)

OCCUPATIONAL EXPOSURE RATING: 1-2C

NOTES & KEY ASSUMPTIONS:

Generated by the 06/07/2005 version of ChemSTEER. 

EPA SANITIZED Page 8 of 57
 

POLLUTION PREVENTION CONSIDERATIONS:

None.

P2 REC:

EXPOSURE-BASED REVIEW: 

EPA SANITIZED Page 9 of 57
P-09-0072

Proc1: 

Number of Sites/Location: 1 submitter site(s) 

MANE, USA Wayne NJ 07470

Basis: 

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY

IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources 

to the same medium.

Water

Conservative: 10.0E-2 kg/site-day over 20 day/yr from 1 sites or 2.0E+0 kg/yr

to: POTW, per submission

Air

Output 2: 9.0E-4 kg/site-day over 20 day/yr from 1 sites or 1.8E-2 kg/yr

to: Air

Air

Typical: 6.9E-7 kg/site-day over 20 day/yr from 1 sites or 1.4E-5 kg/yr

Worst Case: 1.4E-6 kg/site-day over 20 day/yr from 1 sites or kg/yr

to: Air

Air

Typical: 6.9E-7 kg/site-day over 20 day/yr from 1 sites or 1.4E-5 kg/yr

Worst Case: 1.4E-6 kg/site-day over 20 day/yr from 1 sites or kg/yr

to: Air

Air

Output 2: 8.4E-8 kg/site-day over 20 day/yr from 1 sites or 1.7E-6 kg/yr

to: Air

Water or Incineration or Landfill

EPA SANITIZED Page 10 of 57
High End: 1.1E-1 kg/site-day over 11 day/yr from 1 sites or 1.2E+0 kg/yr

to: uncertain

Air

Typical: 3.3E-6 kg/site-day over 20 day/yr from 1 sites or 6.6E-5 kg/yr

Worst Case: 2.6E-5 kg/site-day over 20 day/yr from 1 sites or kg/yr

to: 

from: Sampling Liquid Raw Material

basis: 

RELEASE TOTAL

3.3E+0 kg/yr - all sites

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

Tot. # of workers exposed via assessed routes: 15

Basis:

Dermal:

Exposure to Liquid 

High End: 3.5E+2 mg/day over 20 days/yr

Number of workers (all sites) with Dermal exposure: 5

Basis: 

Inhalation:

Exposure to Vapor 

Typical: 3.3E-4 mg/day over 20 days/yr

Worst Case: 2.0E-2 mg/day over 20 days/yr

Number of workers (all sites) with Inhalation exposure: 5

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

EPA SANITIZED Page 11 of 57
Exposure to Liquid 

High End: 1.8E+3 mg/day over 20 days/yr

Number of workers (all sites) with Dermal exposure: 10

Basis: 

Inhalation:

Exposure to Vapor 

Typical: 3.3E-4 mg/day over 20 days/yr

Worst Case: 2.0E-2 mg/day over 20 days/yr

Number of workers (all sites) with Inhalation exposure: 10

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

Exposure to Liquid 

High End: 8.8E+2 mg/day over 20 days/yr

Number of workers (all sites) with Dermal exposure: 10

Basis: 

Inhalation:

Exposure to Vapor 

Typical: 1.6E-3 mg/day over 20 days/yr

Worst Case: 3.8E-1 mg/day over 20 days/yr

Number of workers (all sites) with Inhalation exposure: 10

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

EPA SANITIZED Page 12 of 57
P-09-0072

Proc2: 

Number of Sites/Location: 1 submitter site(s) 

unknown customer site 

Basis: 

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY

IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources 

to the same medium.

Air

Typical: 1.4E-6 kg/site-day over 200 day/yr from 1 sites or 2.7E-4 kg/yr

Worst Case: 2.7E-6 kg/site-day over 200 day/yr from 1 sites or kg/yr

to: Air

Air

Output 2: 4.6E-8 kg/site-day over 200 day/yr from 1 sites or 9.2E-6 kg/yr

to: Air

Water or Incineration or Landfill

High End: 3.1E-1 kg/site-day over 19 day/yr from 1 sites or 5.9E+0 kg/yr

to: uncertain

Air

Typical: 1.4E-7 kg/site-day over 200 day/yr from 1 sites or 2.7E-5 kg/yr

Worst Case: 2.7E-7 kg/site-day over 200 day/yr from 1 sites or kg/yr

to: Air

Water or Air or Landfill

Output 2: 6.8E-3 kg/site-day over 200 day/yr from 1 sites or 1.4E+0 kg/yr

to: water, landfill or air 

EPA SANITIZED Page 13 of 57
Air

Typical: 6.6E-7 kg/site-day over 200 day/yr from 1 sites or 1.3E-4 kg/yr

Worst Case: 5.3E-6 kg/site-day over 200 day/yr from 1 sites or kg/yr

to: Air

Air

Output 2: 

6.6E-4 kg/site-day over 200 day/yr from 1 sites or 1.3E-1 kg/yr

to: Air

Air

Output 2: 1.4E-3 kg/site-day over 200 day/yr from 1 sites or 2.9E-1 kg/yr

to: Air

Water or Incineration or Landfill

Conservative: 2.0E-2 kg/site-day over 200 day/yr from 1 sites or 4.0E+0 kg/yr

to: uncertain

RELEASE TOTAL

1.2E+1 kg/yr - all sites

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

Tot. # of workers exposed via assessed routes: 29

Basis: 

Dermal:

Exposure to Liquid 

High End: 8.8E+1 mg/day over 200 days/yr

Number of workers (all sites) with Dermal exposure: 29

Basis: 

EPA SANITIZED Page 14 of 57
Inhalation:

Exposure to Vapor 

Typical: 6.6E-4 mg/day over 200 days/yr

Worst Case: 3.9E-2 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Inhalation:

Exposure to Vapor 

Typical: 6.6E-5 mg/day over 200 days/yr

Worst Case: 3.9E-3 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

Exposure to Solid 

High End: 1.6E+2 mg/day over 200 days/yr

Number of workers (all sites) with Dermal exposure: 29

Basis: 

Inhalation:

Exposure to Particulate 

Upper Bound: 7.5E-1 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Inhalation:

EPA SANITIZED Page 15 of 57
Exposure to Vapor 

Typical: 3.2E-4 mg/day over 200 days/yr

Worst Case: 7.6E-2 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

Exposure to Liquid 

High End: 8.8E+1 mg/day over 200 days/yr

Number of workers (all sites) with Dermal exposure: 29

Basis:

Inhalation:

Exposure to Vapor 

Typical: 1.7E-2 mg/day over 200 days/yr

Worst Case: 7.9E-2 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

EPA SANITIZED Page 16 of 57
INITIAL REVIEW ENGINEERING REPORT

P-09-0072

Focus Ready Draft 12/18/2008

ENGINEER: Macek \ JAS

PV (kg/yr): 

Revision Notes/Assessment Overview:

SUBMITTER: Mane, USA (submitter)

USE:

OTHER USES: None found.

MSDS: Yes LABEL: No

Gen Eqpt: rubber or synthetic gloves/ conventional eye/face protection

Respirator: respirator not normally required, if prolonged exposure to high concentrations, use OSHA respirator

Health Effects: avoid contact with skin and eyes/ slightly irritating to skin/ moderately irritating to eyes

TLV/PEL: - none established.

CRSS:

Chemical Name: Phenol, 2-ethoxy-4-(ethoxymethyl)-

S-H2O: 0.083 g/L @ 

VP: 1.3E-2 torr @ 

MW: 196 0.0%<500 0.0%<1000

Physical State and Misc CRSS Info:

Neat: Liquid Mfg: NK, imported

Proc/Form: Solution End Use: Solid/liquid in finished products. Submitted data: 

vanilla, amber, sandalwood scent, mp = -62.4°C, bp = 269.1°C, vp <0.001 torr (calculated), ws = 83 mg/L, log P = 

1.81, d = 1.072-1.082 g/cc, flash point = 100.7°C. The structure is consistent with IR, 1H- and 13C-NMR spectra 

provided. Estimated data: EPI (with mp entered as -62.4°C, bp as 269.1°C, ws as 0.83 g/L, log P as 1.81): bp = 

297.63°C, vp = 0.00372 torr, ws = 4.285 g/L, log P = 2.10. NOMO5 for bp = 269.1°C: vp = 0.013 torr. ACD Labs 

(Prop database): bp = 291.7°C, vp = 1.1E-3 torr, ws = 2.4 g/L, log P = 1.988.

Consumer Use: Yes

SAT (concerns):

Migration to groundwater: Moderate

PBT rating: P1 B1 T1

Health: 1-2, Dermal, Inhalation

Eco: 3, Water (All releases to water with a CC = 100 ppb)

OCCUPATIONAL EXPOSURE RATING: 1-2C

NOTES & KEY ASSUMPTIONS:

Generated by the 06/07/2005 version of ChemSTEER. 

EPA SANITIZED Page 17 of 57
 

POLLUTION PREVENTION CONSIDERATIONS:

None.

P2 REC:

EXPOSURE-BASED REVIEW: 

EPA SANITIZED Page 18 of 57
P-09-0072

Proc1: 

Number of Sites/Location: 1 submitter site(s) 

MANE, USA Wayne NJ 07470

Basis: 

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY

IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources 

to the same medium.

Water

Conservative: 10.0E-2 kg/site-day over 20 day/yr from 1 sites or 2.0E+0 kg/yr

to: POTW, per submission

Air

Output 2: 9.0E-4 kg/site-day over 20 day/yr from 1 sites or 1.8E-2 kg/yr

to: Air

Air

Typical: 6.9E-7 kg/site-day over 20 day/yr from 1 sites or 1.4E-5 kg/yr

Worst Case: 1.4E-6 kg/site-day over 20 day/yr from 1 sites or kg/yr

to: Air

Air

Typical: 6.9E-7 kg/site-day over 20 day/yr from 1 sites or 1.4E-5 kg/yr

Worst Case: 1.4E-6 kg/site-day over 20 day/yr from 1 sites or kg/yr

to: Air

Air

Output 2: 8.4E-8 kg/site-day over 20 day/yr from 1 sites or 1.7E-6 kg/yr

to: Air

Water or Incineration or Landfill

EPA SANITIZED Page 19 of 57
High End: 1.1E-1 kg/site-day over 11 day/yr from 1 sites or 1.2E+0 kg/yr

to: uncertain

Air

Typical: 3.3E-6 kg/site-day over 20 day/yr from 1 sites or 6.6E-5 kg/yr

Worst Case: 2.6E-5 kg/site-day over 20 day/yr from 1 sites or kg/yr

to: 

from: 

basis: 

RELEASE TOTAL

3.3E+0 kg/yr - all sites

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

Tot. # of workers exposed via assessed routes: 15

Basis:

Dermal:

Exposure to Liquid 

High End: 3.5E+2 mg/day over 20 days/yr

Number of workers (all sites) with Dermal exposure: 5

Basis: 

Inhalation:

Exposure to Vapor 

Typical: 3.3E-4 mg/day over 20 days/yr

Worst Case: 2.0E-2 mg/day over 20 days/yr

Number of workers (all sites) with Inhalation exposure: 5

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

EPA SANITIZED Page 20 of 57
Exposure to Liquid 

High End: 1.8E+3 mg/day over 20 days/yr

Number of workers (all sites) with Dermal exposure: 10

Basis: 

Inhalation:

Exposure to Vapor 

Typical: 3.3E-4 mg/day over 20 days/yr

Worst Case: 2.0E-2 mg/day over 20 days/yr

Number of workers (all sites) with Inhalation exposure: 10

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

Exposure to Liquid 

High End: 8.8E+2 mg/day over 20 days/yr

Number of workers (all sites) with Dermal exposure: 10

Basis: 

Inhalation:

Exposure to Vapor 

Typical: 1.6E-3 mg/day over 20 days/yr

Worst Case: 3.8E-1 mg/day over 20 days/yr

Number of workers (all sites) with Inhalation exposure: 10

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

EPA SANITIZED Page 21 of 57
P-09-0072

Proc2: 

Number of Sites/Location: 1 submitter site(s) 

unknown customer site 

Basis: 

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY

IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources 

to the same medium.

Air

Typical: 1.4E-6 kg/site-day over 200 day/yr from 1 sites or 2.7E-4 kg/yr

Worst Case: 2.7E-6 kg/site-day over 200 day/yr from 1 sites or kg/yr

to: Air

Air

Output 2: 4.6E-8 kg/site-day over 200 day/yr from 1 sites or 9.2E-6 kg/yr

to: Air

Water or Incineration or Landfill

High End: 3.1E-1 kg/site-day over 19 day/yr from 1 sites or 5.9E+0 kg/yr

to: uncertain

Air

Typical: 1.4E-7 kg/site-day over 200 day/yr from 1 sites or 2.7E-5 kg/yr

Worst Case: 2.7E-7 kg/site-day over 200 day/yr from 1 sites or kg/yr

to: Air

Water or Air or Landfill

Output 2: 6.8E-3 kg/site-day over 200 day/yr from 1 sites or 1.4E+0 kg/yr

to: water, landfill or air (

EPA SANITIZED Page 22 of 57
Air

Typical: 6.6E-7 kg/site-day over 200 day/yr from 1 sites or 1.3E-4 kg/yr

Worst Case: 5.3E-6 kg/site-day over 200 day/yr from 1 sites or kg/yr

to: Air

Air

Output 2: 

6.6E-4 kg/site-day over 200 day/yr from 1 sites or 1.3E-1 kg/yr

to: Air

Air

Output 2: 1.4E-3 kg/site-day over 200 day/yr from 1 sites or 2.9E-1 kg/yr

to: Air

Water or Incineration or Landfill

Conservative: 2.0E-2 kg/site-day over 200 day/yr from 1 sites or 4.0E+0 kg/yr

to: uncertain

RELEASE TOTAL

1.2E+1 kg/yr - all sites

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

Tot. # of workers exposed via assessed routes: 29

Basis: 

Dermal:

Exposure to Liquid 

High End: 8.8E+1 mg/day over 200 days/yr

Number of workers (all sites) with Dermal exposure: 29

Basis: 

EPA SANITIZED Page 23 of 57
Inhalation:

Exposure to Vapor 

Typical: 6.6E-4 mg/day over 200 days/yr

Worst Case: 3.9E-2 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Inhalation:

Exposure to Vapor 

Typical: 6.6E-5 mg/day over 200 days/yr

Worst Case: 3.9E-3 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

Exposure to Solid 

High End: 1.6E+2 mg/day over 200 days/yr

Number of workers (all sites) with Dermal exposure: 29

Basis: 

Inhalation:

Exposure to Particulate 

Upper Bound: 7.5E-1 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Inhalation:

EPA SANITIZED Page 24 of 57
Exposure to Vapor 

Typical: 3.2E-4 mg/day over 200 days/yr

Worst Case: 7.6E-2 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

Dermal:

Exposure to Liquid 

High End: 8.8E+1 mg/day over 200 days/yr

Number of workers (all sites) with Dermal exposure: 29

Basis:

Inhalation:

Exposure to Vapor 

Typical: 1.7E-2 mg/day over 200 days/yr

Worst Case: 7.9E-2 mg/day over 200 days/yr

Number of workers (all sites) with Inhalation exposure: 29

Basis: 

INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes

2) (a) Exposure level > 1 mg/day? No

 (b) Hazard Rating for health of 2 or greater? No

Inhalation Monitoring Data Desired? No

EPA SANITIZED Page 25 of 57
A-003 

Initial Review Exposure Report

for PMN P-09-72 

EPA SANITIZED Page 26 of 57
12/10/08 Page of 

 

INITIAL REVIEW EXPOSURE REPORT (IRExR) 

 Chemical ID: P090072 Reviewer: Cinalli 

 

Results Table: Dose, Concentration, and Days Exceeded Results Summary 

Exposure Scenario1 Water Landfill Stack Air Fugitive Air 

Drinking Water Fish Ingestion 

ADR LADD ADR LADD 

7Q10 

CC=100 

PDM 

Days 

Exceeded

LADD ADR LADD ADR LADD 

Release activity(ies)2; 

exposure 

calculation(s)3

mg/kg/day mg/kg/day mg/kg/day mg/kg/day μg/l # Days mg/kg/day mg/kg/day mg/kg/day mg/kg/day mg/kg/day 

PROC1: max acute 

eco --- --- --- --- 20.21 --- --- --- --- --- --- 

PROC1: max PDM --- --- --- --- 9.62 0 --- --- --- --- --- 

PROC2: max acute 

eco --- --- --- --- 320.75 --- --- --- --- --- ---- 

PROC2: max PDM --- --- --- --- 25.28 3 --- --- --- --- --- 

1

 Exposure scenario titles consist of release activity followed by exposure calculation abbreviation. 2 Release activities are from engineering report's Manufacturing (Mfg), Processing (Proc) and Use release activity 

labels. 

Multiple release activities are combined in one exposure scenario if their releases occur at same location. 3

 Exposure calculations are Acute Dose Rate (ADR), Lifetime Average Daily Dose (LADD), and Probabilistic 

Dilution Model (PDM). There may be one, two, or all three exposure calculations per exposure scenario. 

CC is the aquatic concentration of concern. 

Remarks: 

Fate test recommendations?: (default is NA) 

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Summary Table: Endpoints assessed 

 

 

 

 

 

 

 

 

 

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Chemical ID: P090072 Assessor: Cinalli 

ENVIRONMENTAL RELEASES 

 

 

 

 

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 Chemical ID: P090072 

WWT 

REMOVAL 

(%) 

RELEASE 

DAYS 

PRETREATMENT 

RELEASE 

(kg/site/day) 

POSTTREATMENT 

RELEASE 

(kg/site/day) 

DWT 

(%) BCF 

(L/kg) 

0.00 11. 0.21 0.21 0.00 4.94 

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER 

PLANT 

TYPE 

% ILE 

FACILITY 

STREAM FLOW (MLD) STREAM CONC. (μg/l) 

Harmonic 

Mean 30Q5 7Q10 1Q10 

Harmonic 

Mean 30Q5 7Q10 1Q10 

ALL 50 413.73 144.88 85.50 75.59 0.51 1.45 2.46 2.78 

ALL 10 47.35 23.64 10.39 11.73 4.44 8.88 20.21 17.90 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 1.19E-07 1.04E-06 mg/kg/day 2.53E-09 2.21E-08 mg/kg/day 

LADCpot 6.12E-06 5.35E-05 mg/L 3.02E-05 2.64E-04 mg/kg 

Acute 

ADRpot 1.21E-04 7.42E-04 mg/kg/day 4.50E-06 3.94E-05 mg/kg/day 

SIC Code Comments: 

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Chemical ID: P090072 Assessor: 

ENVIRONMENTAL RELEASES 

 Scenario#:2 Number of Release Sites: 1. 

 Release Activity: PROC1: max PDM 

 Release Description: WATER LANDFILL 

Non-sludge/Sludge 

STACK FUGITIVE 

Total Releases: 2.00 N/A N/A N/A 

 (kg/yr) (kg/yr) (kg/yr) (kg/yr) 

 

 Non-sludge/Sludge 

Release Days/yr: 20.00 0.00/0.00 N/A N/A 

Per Site Release: 0.10 N/A/0.00 N/A N/A 

 (kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day) 

Remarks: 

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 Chemical ID: P090072 

SIC-CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES 

SCENARIO #: 2 Number of Sites: 1 RELEASE ACTIVITY:PROC1: 

max PDM 

 

 

 

Comments: 

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 Chemical ID: P090072 

SIC CODE EXPOSURES TO SURFACE WATER RELEASES 

SCENARIO #: 2 RELEASE ACTIVITY: PROC1: max PDM 

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Chemical ID: P090072 Assessor: 

ENVIRONMENTAL RELEASES 

 

 

 

 

 

 

Remarks: 

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 Chemical ID: P090072 

SIC-CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES 

SCENARIO #: 3 Number of Sites: 1 RELEASE ACTIVITY:PROC2: 

max acute eco 

 

 

 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 1.10E-06 1.24E-05 mg/kg/day 2.33E-08 2.63E-07 mg/kg/day 

LADCpot 5.64E-05 6.37E-04 mg/L 2.79E-04 3.15E-03 mg/kg 

Acute 

ADRpot 6.45E-04 1.46E-02 mg/kg/day 2.40E-05 2.72E-04 mg/kg/day 

SIC Code Comments: 

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Chemical ID: P090072 Assessor: 

ENVIRONMENTAL RELEASES 

 

 

 

 

 

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 Chemical ID: P090072 

SIC-CODE BASED HUMAN AND AQUATIC EXPOSURES TO SURFACE WATER RELEASES 

SCENARIO #: 4 Number of Sites: 1 RELEASE ACTIVITY:PROC2: 

max PDM 

WWT 

REMOVAL 

(%) 

RELEASE 

DAYS 

PRETREATMENT 

RELEASE 

(kg/site/day) 

POSTTREATMENT 

RELEASE 

(kg/site/day) 

DWT 

(%) BCF 

(L/kg) 

0.00 200. 0.0268 2.68E-02 0.00 4.94 

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER 

PLANT 

TYPE 

% ILE 

FACILITY 

STREAM FLOW (MLD) STREAM CONC. (μg/l) 

Harmonic 

Mean 30Q5 7Q10 1Q10 

Harmonic 

Mean 30Q5 7Q10 1Q10 

ALL 50 125.56 44.02 26.80 22.53 0.21 0.61 1.00 1.19 

ALL 10 11.11 1.94 1.06 0.96 2.41 13.81 25.28 27.92 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 9.12E-07 1.03E-05 mg/kg/day 1.93E-08 2.18E-07 mg/kg/day 

LADCpot 4.68E-05 5.29E-04 mg/L 2.31E-04 2.61E-03 mg/kg 

Acute 

ADRpot 5.09E-05 1.15E-03 mg/kg/day 1.89E-06 2.14E-05 mg/kg/day 

SIC Code Comments: 

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 Chemical ID: P090072 

SIC CODE EXPOSURES TO SURFACE WATER RELEASES 

SCENARIO #: 4 RELEASE ACTIVITY: PROC2: max PDM 

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LEGEND FOR NEW CHEMICALS EXPOSURE REPORT 

This new chemicals exposure report was prepared by the Exposure Assessment Branch (EAB) of the Economics, 

Exposure and Technology Division, Office of Pollution Prevention and Toxics, USEPA. 

The goals of these reports are to calculate conservative (protective) estimates of exposure endpoints for consumers, 

the general population, and the environment. 

For each exposure scenario to industrial releases, the following three endpoints are calculated: 

(1) maximum possible acute concentrations and doses 

(2) maximum possible chronic concentrations and doses 

(3) for water releases ≥ 20 days, the probability of exceedence of the aquatic concentration of concern 

These endpoints are identified by abbreviations on the Release Activity line, e.g., (1) max ADR, (2) max 

LADD, (3) max PDM. Depending on the release inputs, these endpoints may be calculated and presented on 

the same page or different pages. That is, a release activity ID of mfg; max ADR, max PDM, max LADD

indicates that all the exposure endpoints were calculated from common manufacturing release values; 

conversely, a release activity ID of mfg &proc; max ADR indicates that only the maximum acute exposure 

values were calculated for manufacturing and processing releases that occurred at the same site. 

For each consumer product use exposure scenario, whether exposure is to the user directly or to the general 

population/environment, the maximum exposure values are calculated and presented together. 

In addition to the exposure values above, EPA policy directs that exposure and release values be compared to 

criteria threshold values for Exposure-based and PBT Exposure-based cases. 

Exposure-based (YX) cases (those with ≥ 100,000 kg/yr production volume) 

Criteria are exceeded under the following conditions: 

 Presence in consumer product with likely exposure 

≥ 3E-3 mg/kg/d exposure via air, fish ingestion or drinking water 

≥ 10,000 kg/yr release to environment (post-treatment) 

≥ 1,000 kg/yr release to water (post-treatment) 

Persistent, Bioaccumulative, Toxic (PBT) chemicals of P2B2 rating or higher and production volume ≥ 20,000 kg/yr 

Criteria are exceeded as for YX cases, with the following differences: 

≥ 2,000 kg/yr release to environment (post-treatment) 

≥ 200 kg/yr release to water (post-treatment) 

Bolding rules in the Report: Values for endpoints above that are also health or eco concerns are bolded. 

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Remarks: 

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Chemical ID: P090072 Assessor: Sherer 

ENVIRONMENTAL RELEASES 

 Scenario#:1 Number of Release Sites: 1. 

 Release Activity: 

 Release Description: WATER LANDFILL 

Non-sludge/Sludge 

STACK FUGITIVE 

Total Releases: 2.31 N/A N/A N/A 

 (kg/yr) (kg/yr) (kg/yr) (kg/yr) 

 

 Non-sludge/Sludge 

Release Days/yr: 11.00 0.00/0.00 N/A N/A 

Per Site Release: 0.21 N/A/0.00 N/A N/A 

 (kg/site/day) (kg/site/day) (kg/site/day) (kg/site/day) 

Remarks: 

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 Chemical ID: P090072 

SCENARIO #: 1 Number of Sites: 1 RELEASE ACTIVITY:PROC1: 

SIC-CODE DESCRIPTION: 

SIC-CODE (S): EXPOSED POPULATION: Adult 

WWT 

REMOVAL 

(%) 

RELEASE 

DAYS 

PRETREATMENT 

RELEASE 

(kg/site/day) 

POSTTREATMENT 

RELEASE 

(kg/site/day) 

DWT 

(%) BCF 

(L/kg) 

0.00 11. 0.21 0.21 0.00 4.94 

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER 

PLANT 

TYPE 

% ILE 

FACILITY 

STREAM FLOW (MLD) STREAM CONC. (μg/l) 

Harmonic 

Mean 30Q5 7Q10 1Q10 

Harmonic 

Mean 30Q5 7Q10 1Q10 

ALL 50 413.73 144.88 85.50 75.59 0.51 1.45 2.46 2.78 

ALL 10 47.35 23.64 10.39 11.73 4.44 8.88 20.21 17.90 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 1.19E-07 1.04E-06 mg/kg/day 2.53E-09 2.21E-08 mg/kg/day 

LADCpot 6.12E-06 5.35E-05 mg/L 3.02E-05 2.64E-04 mg/kg 

Acute 

ADRpot 1.21E-04 7.42E-04 mg/kg/day 4.50E-06 3.94E-05 mg/kg/day 

SIC Code Comments: 

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Chemical ID: P090072 Assessor: 

 

 

 

 

 

 

 

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 Chemical ID: P090072 

SCENARIO #: 2 Number of Sites: 1 RELEASE ACTIVITY:PROC1: 

max PDM 

WWT 

REMOVAL 

(%) 

RELEASE 

DAYS 

PRETREATMENT 

RELEASE 

(kg/site/day) 

POSTTREATMENT 

RELEASE 

(kg/site/day) 

DWT 

(%) BCF 

(L/kg) 

0.00 20. 0.1 0.10 0.00 4.94 

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER 

PLANT 

TYPE 

% ILE 

FACILITY 

STREAM FLOW (MLD) STREAM CONC. (μg/l) 

Harmonic 

Mean 30Q5 7Q10 1Q10 

Harmonic 

Mean 30Q5 7Q10 1Q10 

ALL 50 413.73 144.88 85.50 75.59 0.24 0.69 1.17 1.32 

ALL 10 47.35 23.64 10.39 11.73 2.11 4.23 9.62 8.53 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 1.03E-07 9.03E-07 mg/kg/day 2.19E-09 1.91E-08 mg/kg/day 

LADCpot 5.30E-06 4.63E-05 mg/L 2.62E-05 2.29E-04 mg/kg 

Acute 

ADRpot 5.77E-05 3.53E-04 mg/kg/day 2.15E-06 1.87E-05 mg/kg/day 

SIC Code Comments: 

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 Chemical ID: P090072 

SCENARIO #: 2 RELEASE ACTIVITY: PROC1: max PDM 

SIC CODE RESULTS 

COC (μg/L) 

Percent of 

Year COC 

Exceeded 

Number of 

Days COC 

Exceeded 

Release 

days/year 

Loading 

(kg/site/day) 

Waste Water 

Treatment (%) 

High/Avg 

Analysis 

1.00 5 19 20.00 0.10 0.00 High 

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 Chemical ID: P090072 

SCENARIO #: 3 Number of Sites: 1 RELEASE ACTIVITY:PROC2: 

max Acute Eco 

SIC-CODE DESCRIPTIO

EXPOSED POPULATION: Adult 

WWT 

REMOVAL 

(%) 

RELEASE 

DAYS 

PRETREATMENT 

RELEASE 

(kg/site/day) 

POSTTREATMENT 

RELEASE 

(kg/site/day) 

DWT 

(%) BCF 

(L/kg) 

0.00 19. 0.34 0.34 0.00 4.94 

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER 

PLANT 

TYPE 

% ILE 

FACILITY 

STREAM FLOW (MLD) STREAM CONC. (μg/l) 

Harmonic 

Mean 30Q5 7Q10 1Q10 

Harmonic 

Mean 30Q5 7Q10 1Q10 

ALL 50 125.56 44.02 26.80 22.53 2.71 7.72 12.69 15.09 

ALL 10 11.11 1.94 1.06 0.96 30.60 175.26 320.75 354.17 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 1.10E-06 1.24E-05 mg/kg/day 2.33E-08 2.63E-07 mg/kg/day 

LADCpot 5.64E-05 6.37E-04 mg/L 2.79E-04 3.15E-03 mg/kg 

Acute 

ADRpot 6.45E-04 1.46E-02 mg/kg/day 2.40E-05 2.72E-04 mg/kg/day 

SIC Code Comments: 

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 Chemical ID: P090072 

SCENARIO #: 3 RELEASE ACTIVITY: PROC2: max Acute Eco 

SIC CODE RESULTS 

COC (μg/L) 

Percent of 

Year COC 

Exceeded 

Number of 

Days COC 

Exceeded 

Release 

days/year 

Loading 

(kg/site/day) 

Waste Water 

Treatment (%) 

High/Avg 

Analysis 

1.00 5 19 19.00 0.34 0.00 High 

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 Chemical ID: P090072 

SCENARIO #: 4 Number of Sites: 1 RELEASE ACTIVITY:PROC2: 

max PDM 

WWT 

REMOVAL 

(%) 

RELEASE 

DAYS 

PRETREATMENT 

RELEASE 

(kg/site/day) 

POSTTREATMENT 

RELEASE 

(kg/site/day) 

DWT 

(%) BCF 

(L/kg) 

0.00 200. 0.0268 2.68E-02 0.00 4.94 

AQUATIC EXPOSURE ESTIMATES - SURFACE WATER 

PLANT 

TYPE 

% ILE 

FACILITY 

STREAM FLOW (MLD) STREAM CONC. (μg/l) 

Harmonic 

Mean 30Q5 7Q10 1Q10 

Harmonic 

Mean 30Q5 7Q10 1Q10 

ALL 50 125.56 44.02 26.80 22.53 0.21 0.61 1.00 1.19 

ALL 10 11.11 1.94 1.06 0.96 2.41 13.81 25.28 27.92 

DRINKING WATER AND FISH INGESTION EXPOSURE ESTIMATES 

Exposure Units 

Drinking Water Results Drinking 

Water Units Fish Ingestion Results 

Fish 

Ingestion 

Units 

50% 10% 50% 10% 

Cancer 

LADDpot 9.12E-07 1.03E-05 mg/kg/day 1.93E-08 2.18E-07 mg/kg/day 

LADCpot 4.68E-05 5.29E-04 mg/L 2.31E-04 2.61E-03 mg/kg 

Acute 

ADRpot 5.09E-05 1.15E-03 mg/kg/day 1.89E-06 2.14E-05 mg/kg/day 

SIC Code Comments: 

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 Chemical ID: P090072 

SCENARIO #: 4 RELEASE ACTIVITY: PROC2: max PDM 

SIC CODE RESULTS 

COC (μg/L) 

Percent of 

Year COC 

Exceeded 

Number of 

Days COC 

Exceeded 

Release 

days/year 

Loading 

(kg/site/day) 

Waste Water 

Treatment (%) 

High/Avg 

Analysis 

1.00 38 140 200.00 2.68E-02 0.00 High 

Remarks: COC exceeded for > 20 days. 

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Lifetime Average Daily Dose (mg/kg-day) 

 ADR - Acute Dose Rate (mg/kg-day) 

 

 

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