V?IMEFCO 

 Ei1lJIFiO(1fT1FfjTAI 

P.O. Box 598 

Addison, TX 75001 

(972) 931-7127 

SOURCE EMISSIONS SURVEY 

OF 

OXYVINYLS, LP 

INCINERATORS A AND B SCRUBBER STACKS 

(EPNS IND101A AND IND101 B) 

LA PORTE, TEXAS 

TCEQ PERMIT 3855B/PSD-TX-876 

JUNE 2008 

FILE NUMBER 08-203 

" I certify that I have personally checked and am familiar with the information 

submitted herein, and based on my inquiries of those individuals immediately 

responsible for obtaining the information, I believe the submitted information is 

trt e, accurat , and complete. " 

J s R. Monfries 

Senior Quality Assurance Manager 
MEFCO. 

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TABLE OF CONTENTS 

PAGE 

1 

2 

6 

8 

9 

11 

14 

16 

INTRODUCTION 

SUMMARY OF RESULTS 

DISCUSSION OF RESULTS 

DESCRIPTION OF PROCESS 

DESCRIPTION OF SAMPLING LOCATIONS 

SAMPLING AND ANALYTICAL PROCEDURES 

DESCRIPTION OF TESTS 

APPENDICES 

A. Location of Sampling Points 

B. Source Emissions Calculations 

C. Calibration Data 

D. Field Testing Data 

E. Analytical Data 

F. Plant Operational Data 

G. TCEQ Permit 

H. Chain of Custody 

I. Resumes of Test Personnel 

1 08-203 1 
, METCO. 

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SOURCE EMISSIONS.SURVEY 

OXYVINYLS, LP 

INCINERATORS A AND B SCRUBBER STACKS 

(EPNS IND101A AND IND101 B) 

LA PORTE, TEXAS 

TCEQ PERMIT 3855B/PSD-TX-876 

FILE NUMBER 08-203 

INTRODUCTION 

METCO Environmental, 1100 Gulf Freeway, Calder Ridge.Business Park, Suite 100, 

League City, Texas, conducted a source emissions survey of Oxyvinyls, LP, located at 

2400 Miller Cutoff Road, La Porte, Texas, on June 3, 4, and 5, 2008. The purpose of 

these tests was to determine the concentrations of hydrogen chloride and chlorine being 

emitted to the atmosphere via the Incinerators A and B Scrubber Stacks (EPNs IND101A 

and IND101 B), in order to comply with TCEQ Permit 3855B/PSD-TX-876 and 40 CFR, 

Part 63, Subpart G. The results demonstrated that the units were in compliance with 

TCEQ Permit 3855B/PSD-TX-876 and 40 CFR, Part 63, Subpart G. 

The sampling was performed by the following METCO personnel: Jeff Knapp - Project 

Supervisor and Jerry McDonald. 

The sampling followed the procedures set forth in the Code of Federal Regulations, 

Title 40, Chapter I, Part 60, Appendix A, Methods 1, 2, 313, 4, and 26A; and in the 

"Sampling Procedures Manual, Texas Air Control Board, Revised July 1985". 

08-203 -1- 
Run 

Number 

1 

3 

Average 

Allowable 

Emission Rate 

Run 

Number 

1 

3 

Average 

Allowable 

Emission Rate 

, 

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1 

1 

~ 

~ 

.~ 

~ 

.~ 

~ 

~ ~ 

, 

, ~ 

~ 

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Hydrogen Chloride 

Emissions 

d m Ibs/hr 

8.3 1.68 

8.1 1.65 

. 5.4 1.08 

7.3 1.47 

<_ 2.08* 

Hydrogen Chloride 

Emissions 

(dry ppm) Ibs/hr 

2.0 0.46 

3.6 0.82 

3_7 0.84 

3.1 0.71 

<_ 2.08* 

Chlorine 

Emissions 

d m Ibs/hr 

4.6 1.81 

4.9 1.96 

3.4 1.32 

4.3 1.70 

---- <_ 4.00* 

Chlorine 

Emissions 

d m Ibs/hr 

2.8 1.25 

3.9 1.72 

6_0 2.66 

4.2 1.88 

---- 5 4.00* 

SUMMARY OF RESULTS 

Incinerator A Scrubber Stack (EPN IND101A) 

Incinerator B Scrubber Stack (EPN IND101 B) 

* TCEQ Permit 3855B/PSD-TX-876 allowable. 

08-203 -2- 
Run 

Number. 

1 

2 

3 

Average 

Allowable 

Run 

Number 

1 

2 

3 

Average 

Allowable 

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MEFCOoft. 

SUMMARY OF RESULTS 

Incinerator A Scrubber 

I nputs* 

Hydrogen Chloride 

Concentrations 

Ibs/hr 

3,588.56 

3,493.27 

3,347.43 

3,476.42 

I nputs* 

Hydrogen Chloride 

Concentrations 

Ibs/hr 

2,892.27 

3,338.38 

3,578.62 

3,269.76 

Stack (EPN IND101A) 

HC12/C12 

Emissions 

Ibs/hr 

3.49 

3.61 

2.40 

3.17 

Stack (EPN IND101 B) 

HC12/C12 

Emissions 

Ibs/hr 

1.71 

2.54 

3.50 

2.58 

Incinerator B Scrubber 

Removal 

Efficiency 

( 0/0) 

99.9 

99.9 

99.9 

99.9 

? 99%** 

Removal 

Efficiency 

(0/0) 

99.9 

99.9 

99.9 

99.9 

? 99%** 

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* Provided by Oxyvinyls, L.P. 

** 4u CFR, Part 63, Subpart G allowable. 

m 

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~T-C- ErmRonmmmC a 

SUMMARY OF RESULTS 

Incinerator A Scrubber Stack (EPN IND101A) 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

** Assumed moisture at saturation. 

08-203 -4- 

Run Number 1 2 3 

Date 06/04/08 06/04/08 06/04/08 

Time 1130-1238 1321-1432 1508-1616 

Stack Flow Rate - ACFM 42,664 42,687 41,852 

Stack Flow Rate - DSCFM* 35,756 36,095 35,236 

% Water Vapor -% Vol.** 8.93 8.43 8.68 

%CO2 -%Vol. 11.2 11.0 11.2 

%OZ -%Vol. 5.2 5.4 4.8 

% Excess Air @ Sampling Point 30.7 32.2 27.5 

Stack Temperature -°F 111 109 110 

Stack Pressure -"Hg 29.67 29.67 29.67 

Percent Isokinetic 97.3 96.1 95.9 

Volume Dry Gas Sampled - DSCF* 37.676 37.544 36.572 

Hydrogen Chloride - Ng 13,385.16 12,976.40 8,459.51 

Hydrogen Chloride Emissions - dry ppm 8.3 8.1 5.4 

Hydrogen Chloride Emissions - Ibs/hr 1.68 1.65 1.08 

Chlorine - Ng 14,376.03 15,434.40 10,386.41 

Chlorine Emissions - dry ppm 4.6 4.9 3.4 

Chlorine Emissions - Ibs/hr , 1.81 1.96 1.32 
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SUMMARY OF RESULTS 

Incinerator B Scrubber Stack (EPN IND101 B) 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

08-203 -5- 

Run Number 1 2 3 

Date 06/05/08 06/05/08 06/05/08 

Time 1005-1115 1143-1253 1315-1420 

Stack Flow Rate - ACFM 50,951 50,054 49,785 

Stack FlowRate - DSCFM* 40,947 40,065 39,996 

% Water Vapor -% Vol. 11.35 11.27 10.92 

% CO2-% Vol. 10.4 10.8 10.6 

%OZ -%Vol. 5.0 4.8 4.8 

% Excess Air @ Sampling Point 28.7 27.3 27.2 

Stack Temperature -°F 120 123 123 

Stack Pressure -"Hg 29.69 29.69 29.69 

Percent Isokinetic 97.8 98.5 97.9 

Volume Dry Gas Sampled - DSCF* 43.344 42.731 42.376 

Hydrogen Chloride - Ng 3,694.41 6,604.09 6,704.63 

Hydrogen Chloride Emissions - dry ppm 2.0 3.6 3.7 

Hydrogen Chloride Emissions - Ibs/hr 0.46 0.82 0.84 

Chlorine - pg 9,995.18 13,857.44 21,322.22 

Chlorine Emissions - dryppm 2.8 3.9 6.0 

Chlorine Emissions - Ibs/hr 1.25 1.72 2.66 
~ErMRonrrEnTAL Q 

DISCUSSION OF RESULTS 

Incinerator A Scrubber Stack (EPN IND101A) 

The three tests for hydrogen chloride and chlorine appeared to be valid representations 

of the actual emissions during the tests. AII leak checks performed on the sampling 

train and the pitot tubes showed no leaks before or after each test. The indicative 

parameters calculated from the field data were in close agreement. The measured flow 

rates (QS) for the tests were within 1.3 percent of the mean value. The rates of 

sampling for the three tests were within the specified limits (90 to 110 percent 

isokinetic). The greatest deviation from 100 percent isokinetic was 4.1 percent. 

The calculated emissions (pounds per hour) of hydrogen chloride for the three tests 

showed a range of -26.5 percent to +14.3 percent variation from the mean value. 

The calculated emissions (pounds per hour) of chlorine for the three tests showed a 

range of -22.2 percent to +15.5 percent variation from the mean value. 

Incinerator B Scrubber Stack (EPN IND101 B) 

The three tests for hydrogen chloride and chlorine appeared to be valid representations 

of the actual emissions during the tests. AII leak checks performed on the sampling 

train and the pitot tubes showed no leaks before or after each test. The indicative 

parameters calculated from the field data were in close agreement. The moisture 

percentages for the three tests were within 2.3 percent of the mean value. The 

measured flow rates (Qs) for the tests were within 1.5 percent of the mean value. The 

rates of sampling for the three tests were within the specified limits (90 to 110 percent 

isokinetic). The greatest deviation from 100 percent isokinetic was 2.2 percent. 

08-203 -6- 
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The calculated emissions (pounds per hour) of hydrogen chloride for the three tests 

showed a range of -34.9 percent to +18.9 percent variation from the mean value. 

The calculated emissions (pounds per hour) of chlorine for the three tests showed a 

range of -33.4 percent to +41.7 percent variation from the mean value. 

08-203 -7- 
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DESCRIPTION OF PROCESS 

The Incinerator Scrubbers (DA-4701A/B) provide the final cleaning for plant effluent 

from the Incinerators before it goes to atmosphere. The gases enter the bottom of 

each scrubber and travel countercurrent to the water, which flows down through the two 

sections of each scrubber. Any hydrogen choride or chlorine remaining in the exhaust 

gases from the thermal oxidizers is removed by the water spray in the scrubbers. Wash 

water is provided from softened water. Fire water is used in emergency situations. 

Each vertical vessel is approximately 100 feet tall, including the stack, and 12 feet in 

diameter at the base. The column is fabricated from fiberglass reinforced plastic 

(FRP: Hetron 980) using a vinyl ester resin suitable for both acid and caustic service. 

The inlet nozzle from the waste heat boiler is fitted with spray nozzles and constructed 

from tantalum lined carbon steel. The Scrubber is divided into two sections ("Acid" 

bottom section and "Caustic" top section) with each section having its own spray header 

system. Hydrochloric Acid solution generated in the bottom section is collected for use 

in the plant to neutralize alkaline streams. Any excess acid is neutralized with caustic 

soda on the waste water treatment section of the plant. The scrubber contains one 

permanent chimney tray, between the two sections, with four chimneys. The Acid and 

Caustic Sections internal spray headers are fabricated of FRP. The 90 spray nozzles 

are fabricated from PTFE (Teflon). The Scrubber contains a top section Teflon 

demister pad with Hastelloy C grids. 

Dimensions: 100' tall 12' dia. 

Material: Fiberglass reinforced plastic (FRP: Fetron 980) 

using a vinyl ester resin 

Wall Thickness: '/z inch 

Design pressure: 5 psig 

Design temperaturee: 148.8° C (300°F) 

08-203 -8- 
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DESCRIPTION OF SAMPLING LOCATIONS 

The sampling locations on the Incinerators A and B Scrubber Stacks (EPNs IND101A 

and IND101 B) are approximately 89 feet above the ground. The sampling ports are 

located 26 feet (5.31 stack diameters) downstream from a constriction in the stacks and 

9 feet (1.84 stack diameters) upstream from the outlet of the stacks. 

I 

08-203 -9- 
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SAMPLING LOCATION 

Incinerators A and B Scrubber Stacks (EPNs IND101A and IND101 B) 

Not to Scale 

08-203 -10- 
~M7 ' 

SAMPLING AND ANALYTICAL PROCEDURES 

The sampling followed the procedures set forth in the.Code of Federal Regulations, 

Title 40, Chapter I, Part 60, Appendix A, Methods 1, 2, 313, 4, and 26A; and in the 

"Sampling Procedures Manual, Texas Air Control Board, Revised July 1985". 

A preliminary velocity traverse was made at each of the two ports on the Incinerator A 

Scrubber Stack (EPN IND101A), in order to determine the uniformity and magnitude of 

the flow prior to testing. AII traverse points were checked for cyclonic flow and the 

average angle of flow was equal to 3.4 degrees. Alternate procedures would be 

required if the angle of flow was greater than 20 degrees. Ten traverse points were 

sampled from each of the two ports for a total of twenty traverse points. 

A preliminary velocity traverse was made at each of the two ports on the Incinerator B 

Scrubber Stack (EPN IND101 B), in order to determine the uniformity and magnitude of 

the flow prior to testing. AII traverse points were checked for cyclonic flow and the 

average angle of flow was equal to 5.0 degrees. Alternate procedures would be 

required if the angle of flow was greater than 20 degrees. ' Ten traverse points were 

sampled from each of the two ports for a total of twenty traverse points. 

The sampling train was leak-checked before each test, and again after each test at the 

highest vacuum reading recorded during the test. This was done to predetermine the 

possibility of a diluted sample. 

The pitot tube lines were checked for leaks before and after each test under both a 

vacuum and a pressure. The lines were also checked for clearance and th ,~ 

manometer was zeroed before each test. 

08-203 -11- 
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A grab orsat sample was collected and analyzed according to EPA Method 3B during 

each test. 

Hydrogen Chloride and Chlorine 

Triplicate samples for hydrogen chloride and chlorine were collected from each source. 

The samples were taken according to EPA Methods 1, 2, 3B, 4, and 26A; and in the 

"Sampling Procedures Manual, Texas Air Control Board, Revised July 1985". For each 

run, samples of three-minute duration were taken isokinetically at each of the twenty 

traverse points for a total sampling time of 60 minutes. Reagent blanks were 

submitted. 

The " front-half " of the sampling train for the stack contained the following components: 

Glass Nozzle 

Heated Glass Probe @ 248°F ± 25°F 

Heated Quartz Fiber Filter and Teflon Support @ 248°F ± 25°F 

The " back-half " of the sampling train contained the following components: 

Impinger 

Number Contents Amount Parameter Collected 

1 0.1 N Sulfuric Acid 100 ml Hydrogen Chloride 

2 0.1 N Sulfuric Acid 100 ml Hydrogen Chloride 

3 0.1 N Sodium Hydroxide 100 ml Chlorine 

4 0.1 N Sodium Hydroxide 100 ml Chlorine 

5 Silica Gel 200 g Moisture 

The hydrogen chloride and chlorine samples were analyzed by ion chromatography. 

08-203 -12- 

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08-203 -13- 
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I DESCRIPTION OF TESTS 

Personnel from METCO Environmental arrived at the plant at 2:30 p.m. on Tuesday, 

June 3, 2008. After meeting with plant personnel and attending a brief safety 

orientation, the equipment was moved onto the Incinerator A Scrubber Stack 

(EPN IND101A). The equipment was secured for the night and all work was completed 

at 4:15 p.m. 

On Wednesday, June 4, work began at work began at 6:15 a.m. The equipment was 

prepared for testing: The preliminary data was collected. The first test for hydrogen 

chloride and chlorine began at 11:30 a.m. Testing continued until completion of the 

third test at 4:16 p.m. The samples were recovered. The equipment was moved off of 

the Incinerator A Scrubber Stack (EPN IND101A) and onto the Incinerator B Scrubber 

Stack (EPN IND101 B). The equipment was secured for the night and all work was 

completed at 6:00 p.m. 

On Thursday, June 5, work began at work began at 6:15 a.m. The equipment was 

prepared for testing. The preliminary data was collected. The first test for hydrogen 

chloride and chlorine began at 10:05 a.m. Testing continued until completion of the 

third test at 2:20 p.m. 

The equipment was moved off of the stack and loaded into the sampling van. The 

samples were recovered and transported to METCO Environmental's laboratory in 

Dallas, Texas, for analysis and evaluation. 

08-203 -14- 
Operations at OxyVinyls, LP, Incinerators A and B Scrubber Stacks (EPNs IND101A 

and IND101 B), located in La Porte, Texas, were completed at 4:15 p.m. on Thursday, 

June 5, 2008. 

08-203 -15- 
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APPENDICES 

A. Location of Sampling Points 

B. Source Emissions Calculations 

C. Calibration Data 

D. Field Testing Data 

E. Analytical Data 

F. Plant Operational Data 

G. TCEQ Permit 

H. Chain of Custody 

I. Resumes of Test Personnel 

08-203 -16- 

I 
Ara7 . '• . •• ~ 

APPENDIX A 

Location of Sampling Points 

Incinerators A and B Scrubber Stacks (EPNs IND101A and IND101 B) 

The sampling ports are located 26 feet (5.31 stack diameters) downstream from a 

constriction in the stacks and 9 feet (1.84 stack diameters) upstream from the outlet of 

the stacks. The locations of the sampling points were calculated as follows: 

Port and Wall Thickness = 8 1/4 inches 

Inside Stack Diameter = 58 3/4 inches 

Point Percent of Diameter Distance 

Number From Wall From Wall 

1 2.6 1 112 " 

2 8.2 4 13/16 " 

3 14.6 8 9/16 " 

4 22.6 13 1 /4 " 

5 34.2 20 1 /16 " 

6 65.8 38 11 /16 " 

7 77.4 45 1 /2 " 

8 85.4 50 3/16 " 

9 91.8 53 15/16 " 

10 97.4 57 1 /4 " 

08-203 A-1 
METO 

APPENDIX A 

Location of Sampling Points 

Incinerators A and B Scrubber Stacks (EPNs IND101A and IND10113) 

A-2 
~ 

APPENDIX B 

Nomenclature and Equations 

for 

Calculation of Source Emissions 

08-203 B-1 
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NOMENCLATURE FOR EXAMPLE CALCULATIONS 

English Metric 

Symbol Units Units As i n n 

Cp 

D„ in. m 

%EA 

g 32.174 ft/sec2 

%I 

%M 

Md 

mf mg mg 

fl/lwater 18Ib/Ib-mole 

mt mg mg 

MW Ib/Ib-mole g/g-mole 

MWa ir 28.961b/ 

Ib-mole 

MWd Ib/Ib-mole g/g-mole 

Pb "Hg mm Hg 

Absolute 

Pm 11 1-1 2 0 mm H20 

* 29.92 " Hg, 68° F(760 mm Hg, 20° C) 

Description 

Stack Area 

Pitot Tube Calibration Factor 

Sampling Nozzle Diameter 

Percent Excess Air at sampling point 

Acceleration of Gravity 

Percent Isokinetic 

Percent Moisture in the stack gas by 

volume 

Mole fraction of dry gas 

Particulate - probe, cyclone, and filter 

Molecular Weight of water 

Particulate - total 

Molecular Weight of stack gas 

Molecular Weight of air 

Molecular Weight of dry stack gas 

Barometric Pressure 

Orifice Pressure drop 

~ 08-203 B-2 
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English Metric 

Symbol Units Units 

Ps "Hg mm Hg 

Absolute 

oP "H20 mm H20 

Psta 29.92 "Hg 760 mm Hg 

Qa ACFM m3/hr 

Qg DSCFM* dscm/hr* 

-0 21.83 "Hgft3/Ib-mole°R 

Tm OF .0 

Tt min min 

Ts OF °C 

Tstd 528°R 293°K 

Vm ft3 m3 

VmSta dscf* dscm* 

VS fpm m/sec 

V, ml ml 

Description 

Stack Pressure 

Velocity Head of stack gas 

Standard Barometric Pressure 

Stack Gas Volume at actual stack 

conditions 

Stack Gas Volume at 29.92 "Hg, 

528°R, dry 

Universal Gas Constant 

Average Gas Meter Temperature 

Net time of test 

Stack Temperature 

Standard Temperature 

Volume of dry gas sampled @ meter 

conditions 

Volume of dry gas sampled @ standard 

conditions 

Stack velocity @ stack conditions 

Total water collected in impingers and 

silica gel 

* 29.92 " Hg, 68 ° F(760 mm Hg, 20° C) 

08-203 LI-IN 
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English Metric 

Symbol Units Units 

Vw9as scf* scm* 

pair 0.07521bs/ft3 

pwater 1 g/ml 

pman 62.32Ibs/ft3 

Description 

Volume of water vapor collected @ 

standard conditions 

Density of Air 

Density of Water 

Density of Manometer Oil 

* 29.92 " Hg, 68°F(760 mm Hg, 20°C) 

08-203 

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d.. • 

EXAMPLE CALCULATIONS 

1. Volume of dry gas sampled at standard conditions. 

Pb 

+ Pm 

Vmstd = Vm T Std 13.6 

(T, + 460 Pstd 

Pb + PR' 

Vmstd =17. 65 Vm 13.6 dscf 

Tm+460 

Vmstd = dscf x 0.028317 = dscm 

2. Volume of water vapor collected at standard conditions. * 

VWgas

_ (Vw - 9ms S02 **) Pwater R Tstd 

— 

Pstd Mwater 453.6 

VWgas= 0.04 72(VW=9'mSS02**) = SCf 

Vwgas = scf x 0. 028317 = scm 

3. Percent moisture in stack gas. 

%M = VW gas x 100 = % 

Vmstd + VW gas 

* 29.92 " Hg, 68°F(760 mm Hg, 20°C) 

** gms S02subtracted only when S0 2 is collected in the sampling train being used to determine 

the volume of water vapor collected. 

08-203 B-5 
r • .• .° 

4. Mole fraction of dry gas. 

100 - %M 

Ma = 100 

5. Average molecular weight of dry stack gas. 

MWd = % CO2 x 44 +/ ~2 x32 +% N2 x 28 +

C

% CO x 28 = Ib/Ib - mole 

[ 100] [ 100 [ 100 1 1001 

= g/g - mole 

6. Molecular weight of stack gas. 

MW=MWaxMd+18(1-Md)= 

 Ib =g/g-mole Ib - mole 

7. Percent excess air at sampling point. 

%EA —_ 100 10/0 02 - (0. 5 % CO)J 

0.265 (% N2) - (% 02 - (0-5 %CO)] 

8. Stack Pressure. 

Stack Pressure "/,~ 2 0 _ „ 

PS = Pb + ' Hg Absolute 

13.6 

Ps ="HgAbs.x25.4=mmHg 

08-203 B-6 
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9. Stack velocity at stack conditions. 

1/2 

29' x Ama~ x Pstd x MW arr x(T s+ 460) V S= CP 60 x-~,—AP average 

12xpa,r XPsxMWxTstv 

1!2 

+ 460) vs=5,123.8CP (TS 

- ~fl—dPaverage=fpm 1 ps xmw l 

VS = fpm x 0.00508 = m/sec 

10. Dry stack gas volume at standard conditions. * 

_  1 

QS VsxAsxMdx 460x 

S 

144 

P 

T S + Psrd 

_0.123 ~/sxASxMaxPs _DSCFM 

QS TS + 460 

QS= DSCFM x 1. 6990 = dscm/hr 

11. Actual stack gas volume at stack conditions. 

Qa = VsxAS =ACFM 

144 

Qa= ACFM x 1.6990 = m3/hr 

*A92%" Hg, 68°F(760 mm Hg, 20°C) B-7 
MEFCO. 

12. Percent Isokinetic. 

// —_ Vmsrd x(TS + 460) x pstd x 100 x 144 in2 l ft2 

n MdxTsraxPsxTrxVs ~ xD ( 4) 

% I- 1039 x Vmsra x(T S +.460) _ MdxPSxTtxVsxDn 

08-203 B-8 
MEFCO. 

EXAMPLE CALCULATIONS 

Ibs/hr = m _ c x 2.205 x 10-6Ibs/mg x DSCFM* x 60 min/hr 

Vmstd 

VmSta = Volume of dry gas sampled (dscf*) 

DSCFM* = Stack Flow Rate 

ppm ` m -q_ x 24.04 

Vmstd (m) MW 

24.04 = Ideal Gas Constant liters/g-mole 

Vmstd = Volume of dry gas sampled (m3*) 

MW = Molecular Weight 

Compound Molecular Weight 

Hydrogen Chloride 36.45 

Chlorine 70.90 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

08-203 B-9 
MB'METCO. 

ROnrnErTTAL 

SOURCE EMISSION SURVEY 

JOB NUMBER: 08-203 

JOB NAME: OXYVINYLS, L.P. 

LOCATION: LA PORTE, TEXAS 

UNIT TESTED: INCINERATOR A SCRUBBER STACK 

SOURCE EMISSION CALCULATIONS 

RUN NUMBER 

SYMBOL DESCRIPTION UNITS 1 2 3 

DATE 06/04/08 06/04/08 06/04/08 

BEGIN TIME 1130 1321 1508 

END TIME 1238 1432 1616 

P(b) BAROMETRIC PRESSURE "Hg Abs. 29.70 29.70 29.70 

(mm H (754.00) (754.00) (754.00) 

P(m) ORIFICE PRESSURE DROP "H20 0.940 0.938 0.900 

(mm H20) (23.900) (23.800) 22.900) 

DGM CALIBRATION FACTOR 0.998 0.998 0.998 

V(m) VOLUME DRY GAS SAMPLED ft.^3 38.434 38.371 37.521 

@ METER CONDITIONS (m^3) (1.088) (1.087) (1.062) 

LEAK CHECK VOLUME ft.^3 0.000 0.000 0.000 

T(m) AVERAGE GAS METER DEG.F 76 77 79 

TEMPERATURE (DEG.C) (24) (25) (26) 

V(m[std])* VOLUME DRY GAS SAMPLED DSCF 37.676 37.544 36.572 

@ STANDARD CONDITIONS* (DSCM) (1.067) (1.063) (1.036) 

V(w) TOTAL WATER COLLECTED, ml 79.4 92.8 80.1 

IMPINGERS & SILICA GEL 

V(w[gas]) VOLUME WATER VAPOR. SCF 3.748 4.380 3.781 

COLLECTED @ STANDARD (SCM) (0.106) (0.124) (0.107) 

CONDITIONS* 

%M MOISTURE IN STACK GAS %** 8.93 8.43 8.68 

BY VOLUME 

Md MOL FRACTION OF D.RY GAS 0.9107 0.9157 0.9132 

Tt NET TIME OF TEST MINUTES 60 60 60 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

** Assumed moisture at saturation. 

08-203 B-10 
r • . '• . ~ 

SOURCE EMISSION CALCULATIONS 

JOB NUMBER: 08-203 

JOB NAME: OXYVINYLS, L.P. 

LOCATION: LA PORTE, TEXAS 

UNIT TESTED: INCINERATOR A SCRUBBER STACK 

RUN NUMBER 

SYMBOL DESCRIPTION UNITS 1 2 3 

CO2 % 11.2 11.0 11.2 

02 % 5.2 5.4 4.8 

CO % 0.0 0.0 0.0 

N2 % 83.6 83.6 84.0 

%EA EXCESS AIR @ SAMPLING % 30.7 32.2 27.5 

POINT 

MWd MOLECULAR WEIGHT OF LB/LB-MOLE 30.00 29.98 29.98 

DRY STACK GAS (g/ -MOLE) (30.00) (29.98) 29.98) 

MW MOLECULAR WEIGHT OF LB/LB-MOLE 28.93 28.97 28.94 

STACK GAS (g/ -MOLE) (28.93) (28.97) (28.94) 

Cp PITOT TUBE CALIBRATION 0.813 0.813 0.813 

DELTA P VELOCITY HEAD OF STACK "H20 0.447 0.449 0.430 

GAS (mm H20) (11:400) (11.400) (10.900) 

DELTA P^(1/2) "H20 0.667 0.669 0.655 

Ts STACK TEMPERATURE DEG. F 111 109 110 

(DEG. C) 44 (43 (43) 

Ps STACK PRESSURE "Hg Abs. 29.67 29.67 29.67 

(mm Hg) (754.00) (754.00) (754.00) 

"H20 -0.40 -0.40 -0.40 

Vs STACK VELOCITY @ STACK FPM 2,266 2,267 2,223 

CONDITIONS (m/SEC.) (12) (12) (11) 

As STACK AREA (SQ.INCHES) 2,711 2,711 2,711 

(SQ.METERS) (2) (2) (2) 

Qs DRY STACK GAS VOLUME @ DSCFM 35,756 36,095 35,236 

STANDARD CONDITIONS* (DSCM/HR) (60,749) (61,325) (59,866) 

WET STACK GAS VOLUME @ WSCFH 2,355,726 2,365,076 2,315,112 

STANDARD CONDITIONS* 

Qa ACTUAL STACK GAS VOLUME ACFM 42,664 42,687 41,852 

@ STACK CONDITIONS (m^3/HR) (72,486) (72,525) (71,107) 

Dn SAMPLING NOZZLE DIAM. IN. 0.250 0.250 0.250 

(m) (0.006) (0.006) (0.006) 

%I IPERCENT ISOKINETIC % 97.31 96.1 1 95.9 

* 68 veg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

08-203 B-11 
METCO. 

SOURCE EMISSION SURVEY 

JOB NUMBER: 08-203 

JOB NAME: OXYVINYLS, L.P. 

LOCATION: LA PORTE, TEXAS 

UNIT TESTED: INCINERATOR B SCRUBBER STACK 

SOURCE EMISSION CALCULATIONS 

RUN NUMBER 

SYMBOL DESCRIPTION UNITS 1 2 3 

DATE 06/05/08 06/05/08 06/05/08 

BEGIN TIME 1005 1143 1315 

END TIME 1115 1253 1420 

P(b) BAROMETRIC PRESSURE "Hg Abs. 29.70 29.70 29.70 

(mm Hg) -(754.00) (754.00) (754.00) 

P(m) ORIFICE PRESSURE DROP "H20 1.288 1.240 1.230 

(mm H20) (32.700) (31.500) (31.200) 

DGM CALIBRATION FACTOR 0.998 0.998 0.998 

V(m) VOLUME DRY GAS SAMPLED ft.^3 44.096 43.721 43.520 

@ METER CONDITIONS (m^3) (1.249) (1.238) (1.232) 

LEAK CHECK VOLUME ft."3 0.000 0.000 0.000 

T(m) AVERAGE GAS METER DEG.F 75 78 80 

TEMPERATURE (DEG.C) (24) (26) (27) 

V(m[std])* VOLUME DRY GAS SAMPLED DSCF 43.344 42.731 42.376 

@ STANDARD CONDITIONS* (DSCM) (1.227) (1.210) (1:200) 

V(w) TOTAL WATER COLLECTED, ml 117.6 115.0 110.1 

IMPINGERS & StLICA GEL 

V(w[gas]) VOLUME WATER VAPOR. SCF 5.551 5.428 5.197 

COLLECTED @ STANDARD (SCM) (0.157) (0.154) (0.147) 

CONDITIONS* 

%M MOISTURE IN STACK GAS % 11.35 11.27 10.92 

BY VOLUME 

Md MOL FRACTION OF DRY GAS 0.8865 0.8873 0.8908 

Tt NET TIME OF TEST MINUTES 60 1 601 60 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

08-203 B-12 
SOURCE EMISSION CALCULATIONS 

JOB NUMBER: 08-203 

JOB NAME: OXYVINYLS, L.P. 

LOCATION: LA PORTE, TEXAS 

UNIT TESTED: INCINERATOR B SCRUBBER STACK 

RUN NUMBER 

SYMBOL DESCRIPTION UNITS 1 2 3 

CO2 % 10.4 10.8 10.6 

02 % 5.0 4.8 4.8 

CO % 0.0 0.0 0.0 

N2 % 84.6 84.4 84.6 

%EA EXCESS AIR @ SAMPLING % 28.7 27.3 27.2 

POINT 

MWd MOLECULAR WEIGHT OF LB/LB-MOLE 29.86 29.92 29.89 

DRY STACK GAS ( / -MOLE) (29.86) (29.92) (29.89) 

MW MOLECULAR WEIGHT OF LB/LB-MOLE 28.52 28.58 28.59 

STACK GAS ( / -MOLE) (28.52) (28.58) (28.59) 

Cp PITOT TUBE CALIBRATION 0.813 0.813 0.813 

DELTA P VELOCITY HEAD OF STACK "H20 0.618 0.594 0.589 

GAS (mm H20) (15.700) (15.100) (15.000) 

DELTA P^(1/2) "H20 0.785 0.770 0.766 

Ts STACK TEMPERATURE DEG. F 120 123 123 

(DEG. C) (49) (51) (51) 

Ps STACK PRESSURE "Hg Abs. 29.69 29.69 29.69 

(mm Hg) (754.00) (754.00) (754.00) 

"H20 -0.20 -0.20 -0.20 

Vs STACK VELOCITY @ STACK FPM 2,706 2,659 2,644 

CONDITIONS (m/SEC.) (14) (14) (13) 

As STACK AREA (SQ.INCHES) 2,711 2,711 2,711 

(SQ.METERS) (2) (2) (2) 

Qs DRY STACK GAS VOLUME @ DSCFM 40,947 40,065 39,996 

STANDARD CONDITIONS* (DSCM/HR) (69,569) (68,070) (67,953) 

WET STACK GAS VOLUME @ WSCFH 2,771,371 2,709,230 2,693,938 

STANDARD CONDITIONS* 

Qa ACTUAL STACK GAS VOLUME ACFM 50,951 50,054 49,785 

@ STACK CONDITIONS (m^3/HR) . (86,566) (85,042) (84,585) 

Dn SAMPLING NOZZLE DIAM. IN. 0.250 0.250 0.250 

(m) (0.006) (0.006) (0.006) 

%I IPERCENT ISOKINETIC % 97.81 98.5 1 97.9 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

08-203 B-13 
r • - ~ • I ,. ~ . 

APPENDIX C 

Calibration Data 

Eguipment Calibration Factor Calibration Date 

Pitot Tube #53-5-1 0.813 10/23/07 

Probe Tip #08-203-1 0.250 06/04/08 

Dry Gas Meter #53-2 0.998 04/15/08 

Stack Unit Orifice #53-2 04/15/08 

Digital Temperature 

Indicator #53-2 04/14/08 

Barometer #53-1 03/26/08 

08-203 C-1 
~ ~ ~ I 

~ 

~ 

~ 

~ 

~ 

a 

.

1 

i 

I 

~ ~ 

~ 

~ ~ 

PITOT TUBE CALIBRATION 

Date: i Q Time: 1q n5 

Pitot No.: 5~ 3 ~ 5 - 1 T8: -72 OF 

Pitot Dimensions: /w X_i5e ~ C• P~d. 0.990 

Motor

. 

 . 

Setting`'° 

fps 

marlc 

Calibration 

Standard 

Start End, 

Standard : 

Average High High 

cal. 

Factor 

- 

Low Low 

~I, 

Factor 

7 20 c) , oq o,4i o D,82'y 

14 30 o.20 0,Nq7 o.SoS 0,30 0< <"48 o.32'A. 

20 . 40 o, 511Z 0,7Z9 0,605 0,51 o.'rI Lr , D, g2o 

28 50 o; 55' o, n;5' to . 7N:2 . p. 8 z a ~ qo6 n: ~ tt '~ o. SO o, goy o, SZ t 

35 60 00 3`1y I

, Zo P,oqs' D, ~~Q✓ ~ j.2 ,O ,1.075 p, s08 

41 70 i.io (,Jo 1.oq01 i,6a J.zis 0,S2f l,bo i.Z6S o,sz! 

50 80 i, 1, f g3 Z•lo f.qr{g C,Bca L, lo i.qqq o. 508 

62 90 /,sn J,So f, ~~f2 ~ u.65 9, ~ z8 o, ~ i6 2•"70 1.6L13 o..BeS' 

28 50. o .7y2 Fc6 o.sit " 0.80 0.8qq ✓ c:_82i 

28 50 v.5'S o, ri5 d- 7qZ D, gz 0.ex, 6- o. ~ (1 

Average c: 3 t 3 

Summary of Results: 

Normal high side calibration factor 1 -3 '~ 

variation + i , :3 s" % ✓ 

variation - o o rf 15 "/L 

Normal low side.calibration factor o: Si5 ~ 

variation + 

variation - a • .3 E % 

Calibrator: ~~ ~- ~ ~ c tti ~1 

Checked By: 

VERSION 1 C-2 0$-203 

22 OCTOBER 2002 
~ ~~~nYTML 

NOZZLE CALIBRATION 

Nozzle Set No. 0~~ - 03 

Date ~ Ly ~ ~~ Calibrator: 

1 2 3 4 

Reading 1 

Reading 2 p.zyW _ 

Reading 3 Q.LSo _ 

Reading 4 0- Z-SQ _ 

Reading 5 

Reading 6 

Reading 7 p. L5-0 _ 

Reading 8 

Reading 9 

Reading 10 

C9.L5 ~ 

Average 

7 8 9 10 

Reading 1 

Reading 2 

Reading 3 

Reading 4 

Reading 5 

Reading 6 

Reading 7 

Reading 8 

Reading 9 

Reading 10 

Average C-3 1: 1 

5 0 

11 12 

VERSION 1 

22 OCTOBER 2002 
i 

1 

.1 

~ ~ 

''~ ... . b., 

Dry Gas Meter Calibration 

Dry Gas Meter No.: 

Date: 

AH 

~.GpC,- 

0.5 

~ o S5S 

1.0 p. 

1.5 /: ovo ✓ 

2.0 

3.0 

4.0 05 3 ~ 

Average Variation: + 6. 14 ~~- ~ 

Calibrator: 2 a:o~ 

Checked By: 

C-4 08-203 

VERSION 1 

22 OCTOBER 2002 
~ 

, 

_1 

J 

1 Meter Number: S3 -'LDate: 

DRY GAS METER CALIBRATION 

Calibrator:2w ,' (. •,) w--N 

Wet Test Meter Vms,, 

Calibration Factor (Coa

) = Dry Gas Meter Vmstd 

Run No:: 1 @ o• s° 

✓ 

pb: 3 o. zs- "Hg 

Control Module Vacuum: 3"0 "Hg 

Wet Test Meter (No. 2 ) D[y Gas Meter 

Meter Meter Temp. 

I1II7e BeadiD9 IemR.. ~„ Head-iA9 ltl 91dt .P_,r, 

End N-2t r • 0c7 " cf 33 °F "H20 gn-Z'Le cf kS °F 7y °F fl•.ra °H20 

Start 0-c-a cf OF - 1•5 11 'H2O iIu. o cf ~l °F IW °F 0-So"H20 

Avg. I1;2z ~cf 73 ~ °F 

~ 

` i,sv "H20 cf oF 

✓ 

v•ssa "H20 

30.zr + 13.6 Wet Test Meter Vms~ = 17.65. x;• ~~ o x ~, U ,~ (C) _;~ ~~4 dcsf 

~, 3+ 460 

3~•2~ 13.6 Dry Gas Meter .Vmsra = 17.65 x~ Z z ~ _ ~,1 ~ 3 dcsf 

-~ y + 460 

✓ 

C'DG - S- /.

:~'4 = Q `5.r 

S.ld3 

C-5 08-203 

VERSION 1 

22 OCTOBER 2002 
Meter 

8eadin9 

8 Z5. n S7, cf 

R 7- . 3 S`tZcf 

S.zta cf 

)[y Gas Meter 

Temp. 

ln S2llt R.I. 

ff~ °F -4y °F )• °e "H20 

RZ °F . -1.4 °F~ "H20 

°F i• ,Q "H20 

_) 

~ 

"H20 

- Z•4° "H O 

✓ 2 

U H2O 

i 

~ . ..• .~ • 

DRY GAS METER CALIBRATION 

Meter Number: 53 - 7L ~ Cafibrator: 

Date: L/-( ti 

- Wet Test Meter Vmsm 

Calibration Factor (CaQ) - 

Dry Gas Meter Vmstd 

Run No:: 1 @ I - °`' J Pb: 3 a• 2 S "Hg 

Control Module Vacuum: S=o "Hg 

Wet Test Meter (No. --2 

Meter 

Tltne Heading IemR... 

End S=64 S . l°o cf F 

Start 43 cf F 

~ ✓ 

Avg. S. I o o cf F 

+` Z•lzy 

3~ Zs 13.6 ~ Wet Test Meter Vmstd = 17.65. x 6.io ~ x )-o,c, (C) = S,tsg dcsf 

}3 + 460 

+ .°U 

3u. z.~ 13.6 ~ Dry Gas Meter Vmstd = 17.65 x s.z % u = dcsf 

gv + 460 

CoG= S. sh = ~ - ~iy5 ~ 

C-6 08-203, 

VERSION 1 

22 OCTOBER 2002 
~ 

DRY GAS METER CALIBRATION 

Meter Number: S'3 - L 

 1 

Calibrator: r~ LJ• ' ~ ~ -~ 

Date: 1-1- rS~ak 

Wet Test Meter Vmstd Calibration Factor (Coa) _ Dry Gas Meter Vmstd 

Run No.: ) @ r • c`' ~ 

pb: 3 0. Z S" "Hg 

Control Module Vacuum: S" o "Hg 

Wet Test Meter (No. Z 

Meter 

T1nOg Haadin.9 IemR.. 

End 13.0% io•'o'> cf 71 °F 

Start. 0:4 4 b-,o cf ° F 

Avg. I]:a ~ w.t-v cf ~~ °F 

____) 

R. 

- 3 3 "H20 

-3,3 a

"H2O 

` 3 , 3O"H20 

Q1y Gas Meter 

Meter Temp. 

HeadtaQ ln D-U.t E. 

~'► 4•SI ~ cf e10 °F 7S °F l•So "H20 

~u• ts cf fu °F 3q °F , 9-" "H20 

/a•Ifro'~ cf ib ~ °F 1-s"(J"H20 

+ ` ]•7 ~ . 

° 13.6 Wet Test Meter Vmsid = 17.65 x i v. l v ~ ~zS 

 + 460

x l . o t 4 (C) = )o . ~ y7 dcsf 

~ 3 

+/• ~v 

Dry Gas Meter .Vmsta = 17.65 x/n ,2gb ~

°i Zs 13.6 z o~ dcsf 

8v + 460 

! o. ~S ~ _ l. C vtJu 

~ _ - 

lv.Z ~ t 

C-7 08-203 

VERSION 1 

22 OCTOBER 2002 
PATm .e: 

DRY GAS METER CALIBRATION 

~ 

Meter Number: S3 -7- Calibrator: 

Date: il- is- (3 b _ 

Wet Test Meter VmsId Calibration Factor (CDQ) _ 

Dry Gas Meter Vms,, 

Run No:: ) a 2-0 o.-z pb: 30, Z s- "H9 

Control Module Vacuum:3" o "Hg 

Wet Test Meter (No. Z ) prv Gas Meter 

Meter Meter Temp. 

S' ~m Hea.din9 IemJ. E Headin9 !n DJut R. 

End 1t 35 tu.u5 ~ cf 7 3 °F -z/. ~ o "H20 ~ 35.k ~ 1h cf ~j~ °F ~~ °F "H20 

Start 0 :oc, o-otie Cf ~ -3 °F 'q-oe "H20 ~ ZS•543 cf L/ °F l'f °F "H20 

AVg. u - 3S io-o5s cf ~~~ °F 

~ 

- "H20 /o.Z&t cf ~ 3 LI °F 2 o6 "H20 

+y ~ o 

Wet Test Meter Vm 17.66 x ~ 0.05 s s°-ZS 13.6 x I•o► 4 (Ct) = fu.l ~ dcsf std = + 460 ~ 3 

D Gas Meter Vm 17.65 x 

7S 13.6__ 

, ry std — CG • Z b l + 460 ~0`~S~ dcsf 

g3 

CpG = /0.1 -4 '-( _ 1 .00. - I,/ 

lU. (j 8 

C-8 08-203 

VERSION 1 

22 OCTOBER 2002 
1 

, 

.~ . ~ . .! 

~ 

DRY GAS METER CALIBRATION 

Meter Number: S 3- z'~ Calibrator: 

Date: k 

Wet Test Meter Vm sm Calibration Factor (Coa) _ 

Dry Gas Meter VmW 

Run No:: t@ ✓ Pb: 3a 2s2jH9 

Control Module Vacuum: °Hg 

Wet Test Meter (No. Dry Gas Meter 

Meter Meter Temp. 

TiM Beasitnq Iemp., P Heading ln Qui P-1„ 

End ~ ;2q /o.Ia5 cf ?3 -F -S. sa "H20 ~ Uo.uSo cf /oo °F 3g °F 3•oc "H20 

Start 0:"0 0.0oG cf -43 °F - S•go "H20 ?`I5.I ko cf ~ o_OF 3?- °F 3 •-uo "H20 

Avg. 5;2 ~ lo.r v ~ `~cf ~ 3 ~~ F `S So "H20 /0,3 ~ o cf ~ E/ oF ~.~~ "~..~20 

+`S•So 

~ o•zS 13.6 Wet Test Meter VmSid = 17.65 x io. io ~- x 7.011, (C) dcsf 

~ 3 + 460 

~o~ + ✓ 

3o. -ts Dry Gas Meter Vmsid = 17.65 x J v• 3 ~ 13.6 o 

+ 460 = 16' 1 3 S dcsf 

~ ~ 

CDG= yOC-9 08-203 

~q VERSION 1 

I 22 OCTOBER 2002 
.! 

DRY GAS METER CALIBRATION 

Meter Number: S3 - Z ~ Calibrator:Q 

Date: 

Wet Test Meter Vmsld Calibration Factor (Co(3) _ 

Dry Gas Meter Vm std 

Run No:: ) @ 4.0 0 '✓ pb: 3o. 2S "Hg 

Control Module Vacuum:Sc "Hg 

W t Test Meter (No. ~_) Dly Gas Meter 

Meter Meter Temp. 

T.~~ Read! is.wK. E. uscaxuiid L1 yus Lm 

End ~ :S3 /Z•.jco cf -33 OF - -4•ob "H20 b -~ 3,344cf fUl ° F }fs ° F tjlcn "H20 

Start O:oo o.oao cf -33 o F - }.vo "H2O 9(.I u ,f cf q,3 °F OF 4oa "H20 

Avg. S : S.7 

,/ ✓ —~– 

Z•lo~ cf ~ 3 O F ` ~ •oo"H20 

✓ 

I Z.3 ~ Z cf ~

✓ 

f~ °F 

~ 

t, ~ uo°H20 

13. 6 

Wet Test Meter Vms~ = 17.65 x~ Z. r ~ :: x 1 , + 4 C) (C) = 17. r o~ ~ dcsf 

~ 3+ 460 

+ 

1

/,00 

Dry Gas Meter VmStd = 17.65 x I Z.3 ~ z ~ S 13.6 

+ 460 

1 . ) 53'~dcsf 

& ~ 

CDG= 

7 2• ~`~ 

C-10 08-203 

VERSION 1 

22 OCTOBER 2002 

Mercury 

Temperature DTI 

CF ~ 

?q 

3Z 

Zso 

~ G c~ 

s3J 

No ~ 

SZ " 

Zjv ~ 

33 y v 

~

~ • . ' • ~ . • 

DIGITAL TEMPERATURE INDICATOR NO: S3 - Z. 

CALIBRATION DATA 

DATE: 

Media Time 

Ambient Air ~ 3 0 

Ice Bath ~ 3 s 

Boiling Water `%yy 

Oven ~ q s 

Oven °C 1~ 

Oven j o00 

Oven /vrv 

Meter Adjusted? YES 

Reference Thermometer No. +4 ~ 

Calibrator 

Checked By: 

C-12 08-203 

VERSION 2 

15 APRIL 2004 
MEFCO. 

BAROMETER CALIBRATION 

Barometer No. 

Date: 

Time: 

so Barometric Pressure @ Hobby Airport @ 45 ft. _ 

' l S~ 

- 0.045 

Absolute Pressure @ Hobby Airport = 

?>0' io!~- 

+ 0.024 

Absolute Pressure @ METCO (§ 21 

Barometer Reading C) < < ~ 

Variation Os' ~ 

Barometer Adjusted? Yes ~ No 

Barometer Reading (after adjustment) 

~- 

Signature of Calibrator 

C-13 08-203 

VERSION 1 

22 OCTOBER 2002 
APPENDIX D 

Field Testing Data 

08-203 D-1 
E E 

r V V 

w L O 

~ \ 

~ .0 

O 

~ a 

a ~ ~ 

~ 1 ~ 

E 

y 

c w Ua C~ 

_d E ~ -~ J 

E N i U. ' C 

Q Q n. U 5 li 

F 

~ R 

t

•'0 G 

~ 

~o c U. 

~ 

Y 

t~ m L 

~ U 

E ~ 

.. 

> > ~ 

a n. a 

a 

l ~ 

J N 

V` 

z M ~ 

~ xo 

O 

N 

~ ~ m a 

< 

t ~ ~ 

QL 

~ 

Q~ O 

~ 0 _ 

N 

1 

O 

z 

~ L m ~ ` O m 

~ E I z Z ~ ~ .. w ~ 

a 

_ 

J -°~ -°~ 

~ 

O 

s"Q$ U u) 

~ 

E 

° 

r 

W ~ 

~ Y 

n 

cC ;C J 

! X 

o a E 

z 

a ~C 

( 

~ ~ ~ c m w F; 

tL I aQ c ~ 

y O I 

c 

l0 

J +m+ m m 

~ 

o 'm 

z eo O ~ m 

m, O Q ~ 

60 

m ~°- > ~ 

ob 

c V z 

0 

1 M 

, 

—' 

N O a' z H p ~ 

a 

0 m ~ a O-'` t= ` h V :° 

~ 

o~ 

m" O ~ o t3 O m 

- 

M \ W 

o 

~~ ~ Q ~ LL M o 

c O E 1 

++ > 3 

~ 0 > a 

.0 m ... ~ _ W ~ y N 

M U 'o ~ d 

p ° m E :°. a> 3 m ~ 

08-203 

N O O 

N 

lY ~ w 

z 0° 

a oi-- 

~ O 

~ N 

Y 

N E 

~ 

m~ .. 

d a 

'o 

0 - 

~aE+0 °~ ,~ ,• r r h~, ~ r r~ ( r r I~. ~ ~' t5-

- 

~ LL ~ 

Q E c 

t~ 

rn 

~• r t~ I~ ep D. 

=a 

SE 

W~~~ `°~9~ r ~ l 

cV 

tn ~tnh V) 

0 H LL ~ VJ ~ 4 N 

> 

a ~9 

a 

~ N ~j I ~ `v ~. 

~ 

a~ LLt`v9N NNN 

~q 

N~~N~ J NNNNry 

r c`lC`l 

E``O C 

Q~ 

E~ Cm 

a c~ ~ 41 D 

~ 

'~ ~A ~i P 

>= N N ~V N N 

In 

tV N{v ni ti ~ N N tV N N N 

~ °~ O 40 Q ~ O o 0°~ 

o ~ ~+ ~ ~ Q 

m o m ~ ~r~ o O (r 

. 

d 

o 

O 

O ~• 

Q Q b p 

0 0 ~, P n ~- r o 

✓~ o 

a: . 

O 0 p~~ ~~~ 

LL c~1 N~ 

m 

O N► O ~ ~-~ 

.~ 

~ ~ o p ~ tr a-~ ~.. ~n ~ N~ o o• ao 

° E 'rj tA ~ 1/~ l~n N Q c.i 

N N N 

aa° ,u ct 

IsT, 
~ Imp, in er Box No. 2 g - 

- 

~ 

Impinger 1 

r Weight Gain 

Fnal Weight 76 ? ~) Impinger 1 

Initial Weight !3. 

f ~ Increase Impinger2 ~ ' I 

Impinger 2 Fnal Weight Impinger 3 

~ Initial Weight 

Incnease ' Impinger 4 2. Z 

~ Impinger 3 Fnal Weight -7 Sa • ~ g S02._ - Impinger 5 ~° 7 

tni6al Weight 7~3•g Vw= 

~ Incnease Impinger 6 

lmpinger 4 Final Weight .-73 8, y Impinger 7 

Initial Weight • 7-3G_ Z- 

~ Increase ` Total ~ 9 • ~ = V M 

~ Impinger 5. Final Weight 92 r(o Pb= Z'1• ✓ %COz = 11 • 2 ✓ 

Initiat Weight:::;. /~~ V. = 3a. 4, 3 ✓ %OZ = -S ~ ✓ 

(ncrease Vw= ~

27 ~ ✓ °/°CO = ~ 

1 l P. = a. 5lt (/ ~ %A' 

"2 

= 

Impinger 6 Final Weight Avg aP = A, = Z7 V1 ✓ 

~ Ini6al Weight ol ~` `i` 7 ✓ p = b z ~✓ 

Increase Avg AP =. y•~~~ T, CU v 

C

D = p. SL3 ✓ 

Impinger 7 Fnal Weight P, _ -a .`/C7 y 'HZO ~ 9, G 7 v 'Hg 

IniUal Weight T. = 1(, °F S'3 ~~ °R 

Increase T. = // ~ °F S7 ~ ~ °R 

] 

~'.93'~ 0,9/07 ✓ 

✓ 

30)~ 

2E.~t3~ 

Moisture Content:. %M = W d' ✓ Md = 4Ao°1'~ MWd = MW 

l P+ Pm b z`~ 7O d,9y~ 3~.(~~4 ✓ S~ 

} Vm~d = 17.65 Vm — 17.65 x 3 8, k3 ~. 

.e + 

~' 13.6 _ ~~ sofm T+ 60 

m 116 + 460 

1 ~ '/ Vw9„ _ _ 0.0472 x Vw = 0.0472 x 9• 7 = 3. • ~ y7✓ 

7 yfe 

i °1° Moisture =_ ~ 

Vwqm x 100 = 3. ~~{7 ~ x 100 = 9, D~ % 

Vm~,, + Vwg„ 37•(a76 

~ V = 5123.8 x 6 6~7~ . ~~ 1 ✓~ s x~_~~'~ ~ tpm ACRi1,:`~~T ,S-~ 

g, (~7 ~'~ 

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x21,V2 x,~~ x Gb X(.73 )2 %E4: 

. ~~0 7 

~ VERSION 1 D-3 08-203 22 OCTOBER 2002 
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~ Impinger Box No. 

Water Weight Gain 

~ Impinger 1 Fnal Weight ~7~ •S Impinger 1 SS3 -C. 

Initial Weight 

~ Increase Impinger 2 Z° - 0 

Inipinger 2 Fnal Weight '7 1 l 7. Impinger 3 3• ~ 

Initial Weight 72 -7. 

Increase Impinger4 ~ 3 

- V. =- 

~ Impinger 3 Final Weight 72S• -7 g SO Z= - Impinger 5 ~~ S 

Initial Weight 2Z> V. = 

~ Increase Impinger 6 

Impinger 4 Fnal Weight K 7• 8 Irripinger 7 

~ Initial Weight 6`l1• SIncrease Total 

M 

`j Impinger5 . Final Weight ` ~Z9 ~' Pb = , 70 ✓ %CO = _ I`l. D V 

Initial Weight,:. ~2~• V. = 38,3'1 

Z 

~ q°02 = S. V 

- - Increase Vw = ~► 2• %CO = ~ 

P. =0 . ! ~ ~ %Nz_ 

Impinger 6 Fnal Weight Avg AP = " y ~' ~ A. = Z,7 t 

~ Initial Weight q ✓ p=o, Z SC) ✓ 

~ Increase Avg AP = .fo(fl T = 60 V 

CP= a:${,~ ✓0.8t3 ` 

~ Impinger 7 Final Weight P. = - 'H20 29.0 7 V 'Hg 

Initial Weight T. = 71 °F ~ s°R 

Incnease T. = I 6 (/ °F ~°R 

g. y3 ~`~ o, 9/5r/ ~ ~-g, 9~ ✓ ~"~- 

Moisture Content , %M = Ma= D-~~M~ya= nQ — MW = 1 ''~~ssumed A ~ SG~urv~ o~• 

P a.93~ 3~ SY ~ ~ Pb+ 13.6 2 5.70 + sft~ ~ Vm~d = 17.65 Vm 

Tm 

= 17.65 x~.3~1 13.6 _ ©~ scfm + 460 -7 7 + 460 0.v 

~ Vw = 0.04 o„ 72 x Vw _ 0.0472 x - 9Z, g = ~{ ~~d Z ~ sft' 

~ % Moisture =_ Vw x 100 = V. 38 o z- x 100 = _~o~ s~ °i° 

Vrrt~,, + Vw9. 3"7 , St1 cy+ 

l V, = 5123.8 x P ~8~ ~ _ 56 `1 x o.~,_ - ~ b7 ''~R ~/i,/o s v2, 6 ~ 7 ✓ 

1 ag•(o~ x , ~ ACFM: L~ 

~~ ~ 36, 0 95 

SCFM:3~ 

%I = 1,039 x 37. SyLl x % 

r ~2-#~-f~ x 29.67 x,-8~~ x 6c5 xc ~ 2> ~ )2 °~°EA: 3 2 ~~~ 

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~ Impinger Box No. Z ~ • ~ 

~ Impinger 1 Fnal Weight ► 

Water Weight Gain 

Impinger 1 

-7 

y~~ ./ 

Initial Weight "X14S 

lncrease Impinger 2 ),0 

l 

Impinger 2 Fnal Weight ~ S7- 5 Impinger 3 ~ 9 

~ Initial Weight b5Y8-S 

Increase Impinger 4 y~ 2 

~ Impinger 3 Fnal Weight 

V. = 

g S02__ - Impinger 5 /0 • 3 

-Initial Weight 7 ZS . ~ V = 

w . 

Incnease lmpinger 6 i 

Impmger 4 Final Weight 

~. 

-7 "7 Z- Impinger 7 

Initial Weight 77 y• ~ 

~ Incnease Total ~ • f V= V. 

~ Impinger 5 . Fnal Weight `; Pb = ✓ %COz = //• 2 ✓ 

~ Initial Weight.,: V. = 37.52-4 ✓ %O2 = , ~~ 

-~ Increase Vw = ~~ %CO = 

) Pm = 0, 50 ~ '~ %N2 

Y Impinger 6 Fnal Weight Avg DP = 0, y 3 0~ A. = Z -7 y/ ✓ 

Initial Weight ; S ✓ D. =o. Z Sa ~ 

~ Increase Avg OP = b.GS` TI = G ) ✓ 

C = ✓ O.g ~3 

P / 

~ Impinger 7 Fnal Weight P, = a• y I

'F{ZO 0 9 r~o Y 'Hg 

j. Initial Weight Tm = I c ✓°F 5- -3 °R 

Increase T, = tl Q ✓ °F S7 0. ~ °R 

. ~ ~.✓ 0.2 913 ✓ 1 a8 ~ 9y ✓ 

Moisture Content .. %M Ma MWd = ~ MW 

~ 

Pm 

Z J 

~ Vm = 17.65 Vm Pb+ 13.6 = 17. x 37•52J 

65 

2 q'~ + 13.6 = 

-~6• ~ S~3 0•6 10 scfm ~ s'd Tm + 460 

-7 9 + 460 

~ ~ ✓ 

I Vw9., = 0.0472 x Vw = 0.0472 x RO • ~ = 3. 78A~ sft3 

) % Moisture = Vw- ~, x 100 = 9.7867 x 100 = 9• 3-7 % 

I V% + Vw9a, .3~ 36.571 + 3.7g07 ~ 

V. - 5123.8 x ~ 5-7 ~ x c~- f~ _ ~~%~ fpm ACFM: ~7e 

i, a 9 ~ 67 x ~7 2g,gy 3s Z36 ✓ 

z SCFM: ~ 

%1 = 1,039 x 36,5 '7-~- x S~(~ _ `,~%, 

1 2~~x.2 9. 6 7 x, ~;3 x G p x( . 2 S~2 %EA: 

7 2a3 o. 3z 

' VERSION 1 p_9 0$_203 ! 22 OCTOBER 2002 
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1 

Impinger Box No. 2°~ —1 

Water Weight Gain 

Impinger 1 Fnal Weight 830 . 3 Impinger 1 

Initial Weight 

'4 ~ 

, 

Increase Impinger 2 

Impinger 2 Fnal Weight Impinger 3 2.7 

Initial Weight 9 

Increase Impinger 4 2,1 

Vw = 

Impinger 3 Fnal Weight 7 Z6• 9 g S02 =- Impinger 5 9•~ 

Initial Weight ~2 Y. Z- V = w 

Increase Impinger 6 

Impinger 4 Fnal Weight Impinger 7 

Initial Weight 77Y,8 

Increase Total _t I 7, ~ ✓ = V 

w 

Impinger 5. Fnal Weight 4~ ~ ~ p b ~ 9~ ° /o CO2 = /D : c ✓ 

Initial Weight.., ~ - C~ Vm = o f6 ~ %OZ = s l~ ✓ 

Increase Vw = 112.6 %CO = ~ 

P. = /. Z 37 9 V/ %NZ = 

Impinger 6 Fnal Weight Avg DP = A. = 

Ini6a! Weight ,/ D= Q. LS-o ✓ 

Increase Avg OP = ~ 78 5 T, 60 

CP = a ~~✓0 g/3 

Irripinger 7 Fnal Weight P, =--D . Z ~'~0 ~ 9 6 9' '~ ~Hg 

Initial Weight T„ = °F 

Increase T. = / ZC ✓ °F ~a ✓ °R 

J 

Moisture Content ... %M =!/• 5 - / Md = ~~cC~' 

o, 8~6 

MWd = -? MW = ZS. S~}' 

Pb + 

Pm 

136 . a9, o ~ + ~ •?88 

/ 

3. 34 . sftg Vm~d= 17.65 Vm 

Tm+ 460 

= 17.65 x yS:o 46_ 13.6 

- 

- 

-~ 0, scim 

7 5' + 460 

I 

Vw9g, = 0.0472 x Vw= 0.0472 x 117• 6 = f. s-- -7 v Sft3 

% Moisture = 

-- 

Vw, ~ ,. x 100 = S~SS x 100 = /!, 3 S—✓ % 

Vrnw + Vw9a, q3. 3 Y + S, SSO'7 

0•8/3 ~i'706 ✓ tf ~/ia/og 

V, = 5123.8 x i7ff x ~_ ~rZ- fpm 

a 9, 69 x -2~ 

2S•5z 97, ~ ~ /~ 6//z/og 

%I = 1,039 x C3• S

9 3Y~/ x D = 9-7rY- % 

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so, 95'/ / 

ACFM: 

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%FA: aF~~ 

~ 

VERSION 1 

22 OCTOBER 2002 

D-12 08-203 
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D-14 ~I : 1 
1 

~ Irnpinger Box No. 

Water Weight Gain 

~ Impinger 1 Fnal Weight 7/~~ Impinger 1 

Initial Weight `/•S 

1 Increase Impinger 2 I, 

Impinger 2 Fnal Weight Impinger 3 3 ' d 

~ Initia! Weight 73J~ 8 

Increase Impinger 4 

~ Impinger 3 Fnal Weight 7~91 8 

V. = 

g SOZ._ - Impinger 5 

Initial Weight 72 e, •$ V. _ 

l Jncrease lmpinger 6 

1 Impinger 4 Fnal Weight 6 Impinger 7 

~ Initial Weight 

Increase . ::: Total V. 

~ Impinger 5. Fnal Weight. 93~0, o Pb= 2 9, 7 a V/ %CO 

Initial Weight::;`' ~a7 i ~ Vm = ~/3• Z 

✓ Z 

=~ %02 . = Y ~ 

Increase V. = / %CO = 

~ Pm = ~ 2 y a ~ °~°N2 _ ~Y.~ 

Impinger 6 Fnal Weight Avg OP = o. 3 95'v A. = 27 ! ~ ✓ 

~ Initial Weight e,770 1,/ D= 6,7,50 1/ 

Increase Avg AP = O T, = 6.0 ~ 

D

P = 

o ,9l3 

} Impinger7 Fnal Weight P. = — a.2o V

1-120 29. (0°1 H 

J IniUal Weight T. = 7 ~ °F 538 v °R 

Increase T, = I~ °F S' 3 °R 

~ 

Moisture Content : ., 

~ 

%M = ~ !/ 2 7 / Md = 

✓ 

o• 7-~ Mwd = a 9. `I Z-~ 

,/ 

MW 

~ Vm

— 

17.65 

Pb + 

Vm 

P 

m 13.6 = 17.65 x y3 .7z 1 

Aly~ 

a9- ~ 

 + 

13.6 

~/Z, 73 / V sft' 

2 ✓ 

~d Tm + 460 

. 

^ 

_ 0 ~ 7/ sc(m 

-7~ + 460 

~ Vw9„ = 0.0472 x Vw = 0.0472 x Gl 6-. 6 = Sq 7,6 1/ sft3 

f % Moisture = Vwy„ x 100 = _ S, YZ 8 x 100 

1 Vm,w + Vw9„ 1/2, 73/ + S', Yt$ 

I V, = 5123.8 x ~•~~~ 5~ x (34 V~ pm 

✓ 9g. SfR 

~ %I = 1,039 x 'Yz . 73 1 x 58 3 _ ~~✓ °1° 

! 2.zy, ~ x 9.b9 2 x,8873 x 6o x(o,25~

)2- 

` VERSION 1 D-1 -5J 

22 OCTOBER 2002 

So, oSy V rx E/Il/v g 

ACFI4i. sDL~7 

9o,o65yf~ 6/1,/c 

SCFM: 

%EA:D7 - 3 y 

08-203 
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O ~ ` 

O ° ~ N W-4 d ~ ~ `. t 

S ~ 

a ~` 

~ 

~~~ 

r9 qo 

om~~~° 

IFj - tn 

05 N A`M` N ~ l~!► o 

M~ e3 M ~ 

M~~ s`~s ?-ya I p p 

v. 

~2 ° t-~ m 

~ 

.~ 

~ 

~ 

° 0 

0 ~ i 

II 

Of II 

Z 

LL~ 

} 

1 

 d y 

O 

~ 

= ~ 

l 

F 

_d E 

C 

J w 

X d 

 J_ 

Y 

~o 

J 

1 w ~ 

~ 

C 

-a o ~

~ 

G1 

LL 

y 

d 

a. 

t 

jp 

C 

r m LL 

ol

d 

0 

u) , = 

U m 

O 

U 

7E 

Y 

~ ~ 

~ 

~ CD E R 

r 

n 

co 

' 

N 

I L ~ M 

I j 

Z x 

N ~ 

0 

m a 

w 

r N 

O z 

.a y~ O O 

E ~ a 

z z z _ 

~ -°~ IX ❑ O cn 

E 

~ 

m 

o ~ 

o~ X CE 

E 

o ~ Ulu ~ 1 aa C ~ 

~ y d O ~ I

U c 

d ~ 

z 

o~ 

~ 

~ 

~ ~ 

~ ~ ~ 

w 3 IA 

10 

E > o t9 

tO m i~- > ~ 

1 

= co `Q 

tA 

b° cli c N 

U ~ 

d a 

z y 'p ~ Y 

m ~ U) 

o ° o O « U O ~ 

cim n,` e o Q 

k* 

C~lzl 

E 

O 

o - p 

~ 4 ~ 

C O E ' 

w 

> 

~ 

a 

~ 

d

_ 

 O m pyj oyr! 

a U o F- m 

~ E 0 

n. 

Y 

a>° 3 ~ v~ 

N. 

°o 

N 

tY 

~ W 

Z~ O~ 

j0 

D-17 08-203 
Impinger Box No. ? I " I 

Fnal 12 (F. 

Water Weight Gain 

Impinger 1 Weight Impinger 1 

Initial Weight -TLt 5 • 

Increase Impinger 2 

Irnpinger 2 Fnal Weight _• ~ Impinger 3 

Initial Weight `~ 1 

Increase Impinger 4 1J.8 

Impinger 3 Fnal Weight -7 K- 2- 

V 

g SOZ._ - Impinger 5 g' 

 ~ 

Initial Weight V= w 

Increase Impinger 6 

Impinger 4 Fnal Weight 776 -O Impinger 7 

Initial Weight 

Increase Total = V. 

Impinger 5. Final Weight` ` 7~ ? `/ L Pb= 0v %COZ = / 

I nitial Weight :` `~lS~ V°, = Y3 SZ a ✓ %OZ = 8 

Increase Vw = //0• / `/ %CO = 

P. = !, Z 3 ~ ~ %N2 = 

Impinger 6 Fnal Weight Avg OP =

ff q~ 5'S 9 ~ A. = 27 tt ~ 

Ini6al Weight D.'766 r d g Cn = -6•7 

Increase Avg AP = $ TI = 6 a ✓ 

C - P Ar~r.~- ✓ O•$13 

Impinger 7 Fnal Weight P, = "l~ • Z ~ FIZO o? ~ V ' lig 

Initial Weight T. = _BD °F —~ ✓ z °R 

Incnease T. = 10 ✓ °F V °R 

Moisture Content : , %M 

✓ 

2- Md = d 

,/ 

. 

y 

MWd = ~ 7r'~ 

`~ 

Mw = 09, S ~ 

Pb + 

P 

13.6 ~~ 70 +?'?~ ~/?.376 ✓sftp 

Vm~d= 17.65 Vm = 17.65 x t/~ S2D 13.6 pb cfin Tm+ 460 8 + 460 

Vwo, = 0.0472 x Vw = 0.0472 x // 4-~ = S,'/ 96 7 ✓ Sft3 

% Moisture = 

----

Vw-„ x 100 = S, i rd 7 x 100 ~- v % 

~ 

Vm, d + Vw9a, 5'Z,37/ + 5,467 

vl 7bb D.9'/3~ 

V, = 5123.8 x 0_.76-66 ~ 3 x ~i3 =~~ tpm 

~5, 6 x ~E'. s"~1 

97, ~I ~,e&/~./oP 

%I = 1,039 x Y2 , 3'2 (o x S~3 3 = -.~ % 

x a9,65' x C), ~

Spsx &D x( O.zs'O)z 

~ ~yy 

VERSION 1 D-18 22 OCTOBER 2002 

,19, 785`' 

ACFM: y-fg,,,e 

39; 

SCFM: ~ 

%EA: 

08-203 
c 

~ 

t~ 

d 

Z 

~ 

~ 

~ 

~ ii ui n ii 

n 

n i i 

Y 1 

u-1 y VO

-LVJ 

I 

N O 

0 

N 

a W 

m 

o O ~ O 

~ N 
rr-.. . 

; 

Moisture Saturation Table 

il 

Ii 

I 

r 

1 

Temp. 

(°F) 

Saturation* 

(%) 

32 = 0.60 

33 = 0.63 

34 = 0.65 

35 = 0:68 

36 = 0.71 

37 = 0.74 

38 = 0.77 

39 = 0.80 

40 = 0.83 

41 = 0.86 

42 = 0.89 

43 = 0.93 

44 = 0.97 

45 = 1.00 

46 = 1.04 

47 = 1.08 

48 = 1.12 

49 = 1.17 

50 = 1.21 

51 = 1.26 

52 = 1.30 

53 = 1.35 

54 = 1.40 

55 = 1.46 

56 = 1.51 

57 = 1.57 

58 = 1.62 

59 = 1.68 

60 = 1.74 

61 = 1.81 

62 = 1.87 

63 = 1.94 

64 = 2.01 

65 = 2.08 

66 = 2.15 

67 = 2.23 

68 = 2.31 

69 = 2.39 

70 = 2.47 

71 = 2.56 

72 = 2.64 

73 = 2.73 

74 = 2.83 

75 = 2.92 

76 = 3.02 

77 = 3.13 

78 = 3.23 

79 = 3.34 

Temp. 

(°F) 

Saturation* 

(%) 

80 = 3.45 

81 = 3.56 

82 = 3.68 

83 = 3.80 

84 = 3.93 

85 = 4.06 

86 = 4.19 

87 = 4.32 

88 = 4.46 

89 = 4.61 

90 = 4.75 

91 = 4.90 

92 = 5.06 

93 = 5.22 

94 = 5.38 

95 = 5.55 

96 = 5.72 

97 = 5.90 

98 = 6.08 

99 = 6.27 

100 = 6.46 

101 = 6.66 

102 = 6.86 

103 = 7.07 

104 = 7.28 

105 = 7.50 

106 = 7.72 

107 = 7.95 

108 = 8.19 

109 - 8.43 

110 = 8.68 

111 = 8.93 

112 - 9.19 

113 = 9.46 

114 = 9.73 

115 = 10.01 

116 = 10.30 

1.17 - 10.60 

118 = 10.90 

119 = 11.21 

120 = 11.52 

121 = 11.85 

122 = 12.18 

123 = 12.52 

124 = 12.87 

125 = 1122 

126 = 13.59 

127 . = 13.96 

128 = 14.34 

129 - 14.73 

Temp. 

(°F) 

Saturation* 

(%) 

130 = 15.13 

131 = 15.54 

132 = 15.96 

133 = 16.39 

134 = 16.82 

135 = 17.27 

136 = 17.73 

137 = 18.20 

138 = 18.68 

139 = 19.17 

140 = 19.67 

141 = 20.18 

142 - 20.70 

143 = 21.23 

144 = 21.78 

145 = 22.34 

146 = 22.91 

147 = 23.49 

148 = 24.08 

149 = 24.69 

150 = 25.31 

151 = 25.94 

152 = 26.59 

153 = 27.25 

154 = 27.92 

155 = 28.61 

156 = 29.31 

157 = 30.03 

158 = 30.76 

159 = 31.51 

160 = 32.27 

161 = 33.05 

162 = 33.84 

163 = 34.65 

164 . = 35.48 

165 = 36.32 

166 = 37.18 

167 = 38.05 

168 = 38.95 

169 = 39.86 

170 = 40.79 

171 = 41.73 

172 = 42.70 

173 = 43.68 

174 = 44.69 

175 

176 

= 45.71 

= 46.75 

177 = 47.81 

178 = 48.89 

179 = 50.00 

Temp. 

(°F) 

Saturation* 

(%) 

180 = 51.12 

181 = 52.26 

182 = 53.43 

183 = 54.62 

184 = 55.83 

185 = 57.06 

186 = 58.31 

187 = 59.59 

188 = 60.89 

189 = 62.21 

190 = 63.56 

191 = 64.93 

192 = 66.33 

193 = 6775 

194 = 69.20 

195 = 70.67 

196 = 72.17 

197 = 73.70 

198 = 75.25 

199 = 76.83 

200 = 78.44 

201 = 80.07 

202 = 81.73 

203 = 83.43 

204 = 85.15 

205 = 86.90 

206 = 88.68 

207 = 90.49 

208 = 92.33 

209 = 94.20 

210 = 96.10 

211 = 98.04 

212 = 100.00 

* At 29.92 "Hg (760 mm Hg) D-20 08-203 
1 

1 

l 

i 29 

24 

Pitot Tube No. 

CP c o. d~J ✓ 

~ Pp = ~9~ "fi f~ ~ "Hg ✓ 

P. - "Hz0 ~j~ 'H9 

j A, =27/ ~ ~ in? 

Point 

Number 

Percent 

Diameter 

Distance from 

Ref. Po~t 

(decimal in.) 

Distance from 

Ref. Point 

(ftactional in.) 

Port A 

AP/Tfa 

Port B 

APtr,ja 

Pott C 

OPlr,(a 

Port D 

APlrfa 

1 Z•L ~ . Sz8 ✓ /'/a 093 

2 s. 2 `t. 8 ~ Q ✓ y'3/~~ . Y81112j ~ sl nil l l l l l 

3 ~y. ~ ,578 ~ ~ 9/i~ ,0'l ~ tU ,sr lu~l y ! ! l ! 

4 2 z, 6 ~ 3.2~ g /3 `Iy ✓ ,5~8 rTiol Z s2 /rJV/ 

5 3 ~f. L 2o.D5 3v 20 '/ib / .S3 /~$/ D.S3 ,✓41/ e l 1 ! r 

s Co~ ~'•~~~ ✓ v: o/~ost - Z ~ l!a$l 2 1 1 ! J 

7 . y ~ 5.''473 ~ `~S 

s 8.5. y o, 17 3 So 3//6 ✓ SZ /io3J 0, yFl/Q61 o / 

9 41, ~3. 933 ✓ 5~ ~ s/iE ✓ . s—Z l oSl -6 , y7 ,va6~ - 1 ! l ! 

10 9 7• . 223 57'/y ~ $ i --(~ 

11 

12 

13 

14 

15 

16 

17 

18 

19 

~ 

2, 

/ ! ./ 

/ / / 

Average oP D. Lf y.r 

Average dP'-2 3 ~ 

Average T, 

~ 

~a G °F 

Average a 3, r ✓ degrees 

D-21 08_203 VERSION 1 

22 OCTOBER 2002 

~ PRELIMINARY VELOCITY TRAVERSE DATA 

~ AND 

SAMPLING LOCATION DATA 

Job Number g98-20'3 

~ Job Name 0x14 y t w LS 

Samping Location Sc CLkbe I- 1~ 

~ Date G I LA ID8 Time 

Port A 

-- r Port & Inside Diameter (in.) 6 7 

I Pott Z£ Wall Thickness (in.) 81 t`tt 

Inside Stack Diameter (n.) 5~ 

~ SampNng Ports are 2 6 ft. 6 in. 

~ SampGng Ports are ~ ft. 6 in. 

Stack HegM __ ~ 3 ft. 

Samp6ng Port HeigM Above Ground ~~1 ft. 

Port B Port C Port D Average 

~ 67 

t' 3/stadc diameters) downstream irom disturbance 

(nlet, s o bend, expansion) 

t /~~ Vstadc diameters) upstream from disturbar>ce 

u~t constriction, bend, e>pansion) 
~ PRELIMINARY VELOCITY TRAVERSE DATA 

AND 

SAMPLING LOCATION DATA 

Number 6 S' Zo 3 

~

Job 

Job Name 0x.y u ~ s 

Samp6ngLocation 1rlean" 

~ Date ~ >'~fa8 Time 

Port A 

j Port & Inside Diameter (n.) L7 

11 - Port & Wall Thiclviess (in.) g' ~y 

Inside Stadc Diameter (n.) 

_I 

' SampGng Ports are 2/o ft. in. 

l Sampkng Ports are ` ft. 0 in. 

Stacic Height fL 

SampSng Port Height Above Ground ~ 9 ft. 

Port B Port C Port D Average 

b -7 6? 

~ `/ 

~ ~s~L3/ 

( s31 stadc diameters) downstream from d•isturbance 

V (inlet,nsficti bend, expansion) 

I, g stack diameters) upstream from disturbance 

~ constriction, bend, expansion) 

Point 

Number 

Percent 

Diameter 

Distance from 

Ref. Point 

(decamal in.) 

Distance from 

Ref. Point 

(fractional in.) 

Port A 

AP/T,(a 

Port B 

dP/f fa 

Port C 

AP/Tfa 

Port D 

dP/T,la 

1 Z. 1 I JZ. ✓ 'ye 1/1( 1-6 ~lI / i Lf ! l ! l 

2 8.2 y. ~l$ t{ 13f1 L ✓ .SZ..lII 1'6 Sb ltZll 

3 ly. ~. 8.b`78 9/~ ~ ,(.o n2 i /",/ ,b2 lrZDl 7 

4 2z . fo i, 278 )3 li!{ v &q 11 221 b .a I 1 / b 

5 3`}• Z ZD,OS 3 2o II /b V ,(oy lla/• ~- G/G2 / 2- I I I l 

6 J~~ 3~•~SS 3S" ~~ ✓ .(,,S^ l l'i 6/2 /© l l l l 

7 ~~ .~I ~ 5-~ ~l 7 3 45 I1 i y .(0 12Z1 cF 10 lltt l- l! l l 

8 $S, s'~, t73 5p rb , 7_/l22/ 6 r62 !!tl l --G l l l l 

s 91, S S3. 933 .57 /NL/ 12- , S8 /!ZL/ O 

10 9 1.Li s'?. ZZ 3 s-7'/ S/ 211 7 , 61 / It 

12 

13 

14 

15 

16 

17 

18 

20 I l l l I l l l 

21 

22 

23 

24 

Pitot Tube No.5 3- S— 1 ✓ 

D= 6.21 S- ✓ 

P, = a g. 7 '/ °Hg ✓ P, = -p• Z- V "HZO 29• 6..7 °Hg 

A. _ Z 71 1 V in? 

Average OP 4 , 5- y 

Average AP'a 9,76 ~S 

Average T, °F 

Average a ~' -D degrees 

D-22 0$-203 VERSION 1 

22 OCTOBER 2002 
r+- . 

APPENDIX E 

Analytical Data 

, 

I 

, 

~ 08-203 E-1 
>o ° N 

U (Mp OR 

~ C6 O O) ~ 

0 

U m o 0 (3~ V: 

~ o 0 o ~ ~ 

~ o 0 

~ 

o O O 

N N c_UM o 

O E ~ 

N 

c ~ I~ o

O ~ 

N 

~ 

N 

~E 

 N O 

~ 

IE 

 M ~ co O 

N (D 

N 

N 

C (N V 

ri 

E~ 

a~ 

O 

O 

O 

O 

O 

~ Q 

2 Z 

m 

Of 

Lo 

V 

U') 

M 

Ln ~ 

v, ~ 

M C 

C C n O O E_ 

7 7 2 

o 

N N ~ 

E E > > o Z 

0 0 -a 

> > a> 

E E ~ C O_ (o 

fl_ fl_ p 

O) m ~ 

N f0 ~ 

N O 

L 

2 U ~ ~ 

O) O> O 

> > U 

o-°o 

O O 

0 0 

0 0 

00 

O O 

00 

0 °O 

O O 

00 

0 oo 

O O 

Q 

m 

~ 

a 

2 

U ~ 

O O7 + O 

~ C N 7 

p O C ~ 

cl) U 

~ 

N . y 

lC 

C 

Q 

d 

C .` 

O 

t 

U 

'O 

~ 

N 

d 

~ 

'C 

O 

t 

U 

C 

d 

~ 

O 

~ 

_ 

~ ~ M c0 

~p M V M 

O I 

H 

V ~ 

O U')

M M m 

O ~ O ~ 

l9 M < 

co 

H 

❑ o o°o 0 0 0 

~I ~2 cD (O M ~ O C'7

~ o0 00 Ci 

~ rn n ao v o ~ M ~ 00 I~ V ~ 

ao ~ o v, ti 

Q N N N ~ c~ 

M N 

U W N 0- O 

IE N O N Cfl ` Qj 

N N N ~ 

U c`r

v~ o~ ~~ 

W O I

- 

M ~ 

E N O N Qj 

N N N 

0 

~

SI N M N V N V 

N 

7 00 M h'R O(D 

p N N N N c7 N 

~ 

N 

C N'I N ~ ct N V' 

M — M — c`7 

a 

x 

Mc °) c r :3 — I 

N Ta R~ 

X 

O O J 

N M 

08-203 E-2 
n o Q rO (0 ❑ 

O O ❑ 

~ O 

a L 

a) 3 

c -o o y 

L x .3 ~ E 

-o o n ~ 

_x E 

E y 

N -O 

d O 

E 

w ~ 

a n 

N N c C O O 

> o 0 

o~ v U (p Iy ~ O O 

m O 

0 

> o 0 

U m N 

~ ~ ~ 

N 

rl: 

O ~

c U ~ ,~ 

oEo 0 

in M 

~ UI ~ N 

o E o 0 

D O ~ O O "O 

0 

ca 

rn 00 

ELr'• pl-: C. 

N E T v 

cv 

ri 

°o 

O 

O = ~ O m 

2 Z 

m 

lyuo v 

LO 

M 

N In 

~ m 

M ❑ Q 

O O E_ 

7 2 

~ a U 

~ ~ Z 

~ ~ o 

0 0 •o 

o. a 

n n m ❑_ o 

0) 0) ~p 

N (>O ~ 

tn O 

t 

n II ~ 

2 U ~ m ~ 0 

0 O 

O 

0 0 

O O 

O O °O °o 

O O 

O O °o o° 

0 0 

O O 

O O o O 

0 0 

0 

O O o 

~~ ~ 

o O O 

m 

(D G Y C 

y ~ 

E 11 

D. ~ 

❑ 

`[C 

to •o 

II ~ 

~ U 

(9 

~ 

E 

❑ 

m ❑ 

N O 

C7 U 

~ 

N .❑ 3 

(n 

OO O 

~ C ~ o 

U O 

~ ui r ln c\i N 

fV CD O) co M ~ O O ~ N 

U 

= o Cl) v 

~ 01 O O 

~ O M co 

O 

H 

~I O ~ CO O 

~ O O O — 

~ ~ ~ ~ ~ 

~p Q1 ~ 11') M oo ~ I~ 

Lq 

N U rn 

~r' ° ' r`

~°•) 

v ~ 

r

- I In ~ l o 

E~C6 o0 0 oi cfl 

~ Q) O N OJ lf) 

U W O O M ~ 

ln O OD C+0 c`7 M 

E cD 

O 

CI 

j lfl tf) 

O 

0 

E ° ~ ~ M N v~ 

M N 

°cNo 

M N 

~ 

N 

c N V N V N V .- ri — ri — co 

E 

c`MC_ O C 

° 

~ 

I 7 

c•

4 

 ~, d° ~ 

x 

O O J 

N M 

N .y 

~ 

l6 

Q 

d 

C 

~L 

~ 

~ 

U 

~ 

C lC 

d 

~ 

U 

C 

d 

~ 

~ 

T _ 

08-203 E-3 
METCc? ET3tTIROiJME;AITP?~ 

Data Rev-oc.essed Dn 06I10(2008 08:31:98 

S { 3ainple iJante: Rl I1-2 2X NCN S::.RB A Date: 06I0912008 13:52`94 { 

{ Data Fi1e C:\DX\DATA\ANIqNB\0E-203\06-09001.D17 { 

I l;ethod : C: ;DX\METHc}D`.H ~_I,2.h`ET { 

At_I ACi_Iress: i S;?stertt: 1 lnjeo'Lff: 17 DeteCtor:c_DM-2. I 

~ { ATiaiyst AfCG ;'-oluunn: iyS 19 , 9rnm, STD 2-21-05 I}J At'ID ( 

i: aiibrat].oIL `JCi.iUltt~.' D].ilttion FolIit-s T?a'Le .°iT ~i7T .°,trsp nrFa R6j = cF. 

j ---------------------------------------------------------------- ----- 

EXternal 1 1 9200 5Hz 0.00 11A.00 2000 

i..oi(Ponetll. C.ePorT..; 0xLg}olieriTi -

`

^

i Foilnd 

i:u't CsJri"Tj'Jn[- nt ArBa Heiarat Conceritr•atioli 

Tirtie N?rLc;? PU.(t 

~ .. ------------------------------------------------------------ 

3.73 c,l in acid 559740380 57964582 2-1 2.824 

------------------------------------ 

1559740880 [G i O ~• T~'LC~'. ~3 JI 6~r~ VL feG.VL ~] 

=iie: 06-0=001 .^? 7Sample: F_1 I1-2 2:=' PJCPl 

7~e 

60 

50 

4~l 

U3 

30 

20 

10 

A 

0 2 4 6 14 

i 

~ t 

~ 08-203 E-4 

1 
METCO ENVIRONMENTAL. 

Data Reprocessed On 06/10/2008 02:32:01 

1 Sample Nmie; RI 11-2 2X NC-li SCR-B A Date; 06/0911 21,08 -14:08:03 

I Data File 

I Method 

I AC.-T Address: 11 Systerm 1 Inject'.; 18 Detector: CIIXM-2 

1 Analyst I-VCG Colurim: AS14,4, m8n,STD 2-21--05 !N ACID 

Calibrallion Volwme Dilution Points Rate Star', '51top Area Reject 

-------------------------------------------------------------------- 

External 1 1 4200 =Hz 0.00 14,00 20clo 

Courgoonent Repo•t: Components Found 

Ret Corqrjonent Axea Height r-'oncentration 

Time •ame 

------------------------------------------------------------- 

73 Cl in acid 5 6 0 4 7 2 5 2 0 5 8 0 7 8 1361 2 2. 85 31 

------------------------------------- 

Totals 5FC)47 ,520 580i8361 21 2, 8 31 

File: 06-0900I.D18 Sample: RI 11-2 2X NCN SCR-B A 

-80 

70 

60 

5.0 

U 40 ~I 

20 

10 

0 

Li 0- 14 

w4inuteS 

08-203 E-5 
File: 06-09001.D25 q-amle: Rl 11-121 4K I-.7CN SCR A-L!O PPI-I 

80 

70 

GCI 

50 

40 

u 

30 

0 

FIETCO ENVIR-ONMENTA• 

Data Reprocessed On 06/10,1 2008 OL, ..JL;Gl 

Saimc-le. Nanie: Rl 11-2 4X MC-N SCR A+10 PPI-I Date: 06/09/2008 15:4s:47 i 

Data File ; 

I Method : --:\DX\ITMTHOD\HCT.2..METACI Address: 1 3ystem: 1 Inject#; 25 L---tector:C'DII- 2- 

Analyst JMCG Colum: A514,4rm,-3TD- 2-2- 1-05 1-K ACID 

Calibration Volunie. Dilution Points Rate Start Stop -

1--e.a Reject 

-------------------------------------------------------------------- 

Exterm;I 1 1 39005H2 00 11-3. co 2 0 cl cl 

C,- griponent Report: Couponents Found 

r-c-t Coupo-fien-'- Area Height Coricent-ration 

Tilme Name pprft 

------------------------------------------------------------- 

3.73 cl in acid 524599300 5492, 1700 21,511 

------------------------------------ 

Totals 5245913-00 5A 9217rjO Z1.511 

-n n 1 -p 0 L 6 Q 10 CMinutes 

08-203 E-6 
MBTCO ENVIRONMENTAL 

Data Reprocessed On 06/10/2008 08:32:33 

Saniple kilame: Ri 11-2 4X NCK F-CR A+10 PPM Date: 06/09/2008 16:04:09 

Data File C: 

Method C: \D.K 1,1-1BTHOD\ffCL2. MET 

ACI Address: 1 S•stem: 1 Inject*: 26 Detectox; CUM- 2 

Anal jrst MCG Colimin: ASl4,4rvpi,STD 2-21-05 IN ACID 

Calibration Volwme Diltition Points Rate Stait -3top, Area Reject 

-------------------------------------------------------------------- 

External i 1 3900 5Hz 0.00 13.010 2000 

Couponent Report; Cummonents Found 

Ret Component A r ea Fe-ight Con cent rat i---xn 

Ttan Nalpave pril"A 

------------------------------------------------------------- 

3.73 Cl in acid 52, 2943460 55272253 Z,I . ---; C, 2 

------------------------------------ 

Totals 522943460 55272253 21.382 

06-09001,D26 Swyln Rl il-2 4X NC-N SCR A+10 PPM 

rIci 

60 

50 

A .0 

US 

30 

20 

10 

0 

i-k --k A C, 

M it mites 

08-203 E-7 
File: 06-10001.D03 Sample: Rl 13,4 311, NCN SCRB A 

.140 

1 

100 

80 

LIS 60 

40 

20 

0 

MEETC0 EVVIRONMENTI-1, 

Data Reprocessed On 06/10/2008 13:41:47 

•ample Naine: Ri 13,4 3X IICN SCRB A Date: 06/10/2008 09:il;36 

Data File C:\L_~ ;\DATA\ANIONS\08-203\06-10001.DO:-3 

Method C: \DX\METHOD\HCL2A. MET 

ACI ACidress: I System: I In-ject#: = Derector:CDM-2 

Analyst I-ICG Colurmn; AS14,4m, STD 1-1-9 -01 50 iLL LOOP 

Calibration voluitte Dilution Poi-nts Rate "tart Stop Area Peject-, 

-..: ------------------------------------------------------------------ 

External 1 1 6300 5Hz 0.00 19.43 2000 

Coirponent Report: Coicoonerills Found 

Ret ComDonent A.re-a Height Concentration 

T--ute Naitte ppift 

------------------------------------------------------------- 

4.02 Cl in NaOH 4611621 070 10561903a 20.055 

------------------------------------ 

Totals 461162010 105619038 20.055 

-f ci 

Minule-s 

1 08-203 E-8 
Fille: 06-100011 .DN Sarcfple. P.1 13,4 3, X NCN SCRB A 

14U 

lu 

100 

80 

60 

zu 

0 

BIA71PONYMENTAL 

Data Re-processed On 06/10,1 2008 1-1 :42:07 

I Sample Name: RI !3,4 3X 1404 -CRB A Date: 06/10/2008 09:33:57 

Data File C:\DY,\DATA\~ll"-jNS\08-203\06-10001,D04 

I-le-thod C:\DY,iME.Tfi--D"Hk--L',A.1-IFT 

ACI Address: 1 System: 1 Inject#: 4 Detector:CUA-2 

Analvst I-ICG Coltuiin; AS14,4ruci, SI'D 1-12-01 SO uL LOOP 

Calibration Voliime Dilution Points Ralle "tart Sto-p Area Reject 

-------------------------------------------------------------------- 

6300 5H 'z 0100 i9.8 1 0 2 0 Ol 0 

cr gcpr,nen~ Report: Components Found 

Pet CoroDonent Area Height Concentration 

-lime liame ppi-ft 

------------------------------------------------------------- 

4.02 Cl in NaOH 464899400 10221490-9 20.214 

------------------------------------ 

Tot-Rils 464899400 102214902 20.2-14 

21 14 16 is 

Minutes 

08-203 E-9 
- 

' 

| / 

- 

' 

\ Mmroo ENVIRONMENTAL ' 

oeta nevc000aaw6 ou 0611012008 08.32,51 

| / oomnzo mam*` az 11-2 za M-711 acxa A oate, 06/09/20010 14:23:23 } ' | oatm rize C:\ \08-203\06-090n1.o19 ( 

| arthod c`\oz\muzH»o\HrTj,2.MEr | 

i ! ACz audroos: z oyato-ni; z zu3eut#; zp ootoctor:ccM-o } 

\ / auazy-qt : *cG cozuxm ,Aa14,4um,nzo 2-21-05 zm aV,7zo } 

oaliuroticm Vozuue oizntion poiuta aate ytazt 

----------------------------------------------- 

outwrual 1 1 4200 ouo 0.00 

°°+~°°w-p°+°+~°°°°*°** oompoueot nswort

,oonq:,~ oumnaat comVouout »ree oei«ut o 

zi-fwa manie 

------------------------------------------------- 

3.73 oI iu acid 550609200 579MOn 

________________________ 

Totml'o 555659200 57e2I208 

Stor, Areaaeject 

'----------------- 

14.00 unoo 

--o pomnu 

mcentratbon 

PPTU 

__________ 

2%.7oo 

_________ 

~ 2.701 

File; 06-0900z.o19 SaW-le: no 11-2 az NTCN ~PB- a 

~~ 

~~ ~~ 

03 

10 

~ 7 ~ 6 8 1 ~ 7 14 

Minutes 

08-203 
0 4 ~ 18 17 14 

MEzC-O EhTVIRCiNMENTAL 

Data manr000saod ou 06/10/2008 08:33-::4 

| nanpuo mamv/ mz 11-2 oz »uoJ aonE u zmtm/ oo/ny/unox 114/38:42 | 

| oatu rii-e- , c ~\~~\o~o~\amznmo\nn-000\on-opnnz.00n | 

| Metumd 

) acz auureoo. I aystam: z zuject#: un uetoctoz: C911-2 ) 

| euazrat eme oozomu ~ ASl*,4mm.ozo 21-21-0- 5 zmAnzD / 

cmziucatiou volum* oizotiou poiuta note Start atop azoa aojoct 

----------------------------------------------------------------- 

o~tecuaz l l 4200 5oo 0.00 14.On zoVo 

nommoueot aenort: 000Voueuta rouuu 

aat coupouout axea Hoinut n0000utratiou 

zonCB maum rDR! 

------------------------------------------------------------- 

3'73 cz iu ooib 560503280 57801u76 22'.007 

------------------------------------ 

roteza 55no6a2, 8n 5710,01276 22.o57 

80 

70 

| 60) 

| 40 

) -D 

1 ~ 

' n 

Minuiv08-203 E-11 
80 

60 

US 

I ~~ 

20 

0 

Fille; 06-J-000l.D05 Sample; R2 13,4 4XI lq'CN ISCRB • 120 

METCO BNVIRONMENTAT, 

Data Reprocessed On 06/10/2008 13:42:32 

SaffiDle Naiiie: R2 13,4 4X MCN SCRB A Date: 061101 ~ 008 09:56:19 

I Data File C:\DX\DA,-A\ANION3\.08-203\06-10001.D05 

Method C: \DY,\METHOD\.HCL2A.ME.T 

AC-I Address; I System: 1 In3ect#: 5 Detector: CDI-41-2 

Analyst MCG Colimm: A314,4mim F STD 1-12-01 50 LiL LOOP 

Cali'Dration Vollule Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

Egternal 1 i 6300 5H2 0.00 i9.04 2000 

cr maDonent Report: Components Found 

Pet Corcc-Onent Area Height Concentration 

Time Nwme pprIl'i 

---------------------------------- --------------------------- 

4.03 1,71 in NaOH 366536050 80748743 16.104 

------------------------------------- 

Totals 366536050 80"[48743 1C-,.104 

Cs ? 4 6 8 10 1? - 14 

~~~~~~~: 

08-203 E-12 
.. 

| 

- 

/| xao Co 

|

' 

 oata memr000s e*u ou 06/ 10 / 2 008 13:42 / 48 

sempl s wamo : au 13 , 4 mz mc~ e«x B A Du ro/ no/zn/oonn 10 / 18 , 3 g / 

} | oa t a ri l e ~ c~ \oz\zu~za\umzomr\oo- ~ nn\ot- ~ onO ~ .on ~ | 

| metuou ~ o : \oo\mozrmo\mrL~A .e Ez | 

. | aozaddzeao : z oyotem : ~ zui eotl: o ootector: oom- 2 | 

| | auol vst ~ ecG cnzumn: Aa1 «, 4mm, azo z- 1u-Vz 50 uc z*op / 

~~~~ 

- 

. cozibratimu rolumo oilntiou poiuto uete utart atop Arem nejocz 

| ------------------------------------------------------------- 

| uutorua l 1 z 6300 5oz 0,00 lS.77 2000 

cumpouaut uem~ nrt : oon~ooeuta rounm 

} uot oonwouout azea aoiout Couooutcatiou 

zime Nanm mvm 

------------------------------------------------------------- 

\ 4 . 03 o~ ia Nooa 3052 e0202 5756454 5 16 . 05 z 

| --------------------------------- ' 

rotazu n 6azenunu s7»s«s ~ n zo.nxz 

~ ~ ~ ~ 1~ 17 14 1 6 1 8 

~~W~~ 

rize` om-zo0o ! .un 6 eaowlo` n2 za,* «o mom aca ~ A -' 

lZU 

~ 

ua 

~ 

08-203 E- 1 3 
I-IETCO ENVIRONMENTAL 

Data Reprocessed On 06/10/2008 13:43:07 

Sample Nante: R2 13, 4 BX NC-N SCR A+5 PPM Date: 06/10/2006 12:11:35 

Data File C:\DX\DATA- \ANIO-NTS\08-203\06-1000!.Dl1 

Method 

ACI Address: 1 System; 1 inject#: 11 Detectoo: clkpi? 

Anal•st 1,IC G ColLmin: A314,4Rim, STD 1-12-01 50 ul, LOOP 

Calibration Volume Diltition Points Rate Start Stop I—rea Reject 

-------------------------------------------------------------------- 

External i 1 5850 SHz 0.00 19.50 2000 

ConipoLent Report: Ccli-cponents Found 

Pet Corip-onent Area Height Concentration 

Ti:tte 'NaMe ppm 

------------------------------------------------------------- 

1. 05 cl in 1,,TaOF 288017944 71429798 13,061 

------------------------------------- 

Totals 288017944 7i429798 13.C-16i 

File: 06-10001.D11 Sarc(ple: R2 i-3,4 8X NCN SCR A+5 PPM 

80 

70 

60 

5 10 

40 

31.1 

20 

10 

0 

A 14 

im 

b 18 

Won 

08-203 E-14 
Data Reprocessed On 06110•2008 13:43:17 

I Sancie Nanie: R2 13,4 8X JXTCN SC-R A+5 PPIl Date: 06/10/2008 12:32:26 

Data File C: \DY\. 

Method C: \DX\METHOD\FK-.T2.A. MET 

ACI Address: 1 3-ystem: 1 Injecti: 12 Detector: CDM-2 

1 Analyst * 114CG ColLiuLn: AS!4,4ri1R1, STD 1-12-01 50 iCL LOOP 

Calib,ration Volu-me Dilution Points Rate 5ta1't Stop Area Reject 

--------------------------------------------------------- 7 ---------- 

External 1 1 5850 5Hz 110.00 19 ~ 50 20cic, 

Coup•rient ReDort: Components Found 

Pp-t Cor(L-ponent Area Height •oncentration 

Til(le !-'alme ppift 

------------------------------------------------------------- 

4.05 Cl in NaOH 288451116 71446050 i3.080 

------------------------------------ 

Totp-is 288451118 13.080 

File: 06-10001.D12 Bwtcple: F-, 2 13A BX NCN SCR A+5 PP!i 

00 

70 

60 

50 

LL 40 

210 

20 

c n ? 1 e ci Q 4 10 1 14 16 

minutet 

08-203 E-15 
0 ~ 4 8 1 ~ ~7 

- 

| 

' 

! 

| »4Ez:o / 

oata meproceasou ou 06/10/2008 08:33:17 

| | oaoyPlo »munm/ ma zl-1-2. ox mcw s«ya a oate/ oo/nn/onon ~~, 53`05 / ' | oalla piln o:\cm\oaxA\alizoNS\08-203\06-09001.D 1 ! 

' | mothod C.\ou\mmraoo\mo~o. ~oz | 

| aoz Auuresa: I Srotem: 1 zu1oot*: oetootoz`CoM-u } 

} / uua!rot xoo Columu. A524,4mm,azu c-oz-oo zmaoro } / 

oazibratiou volumo oizntiou pniuta xoto atart otor, azea xojeot 

~ 

---_----------_-----'__---------------_-----------------_--__----_-- 

oxterual z z aeon 000 0.00 13100 znon 

coopoueut x ort: 000ponenta ruuuu 

~ e*t Conmou*ut A-rea ooioht nouceutcatiou 

Time oaox, namn 

------------------------------------------------------------ 

\ 3 '72 ol io anid' 29945124o 30948835 z3.366 

/ ------------------------------------ 

Totmla 2-99*s12«0 310948on5 13.365 

~ 40 

uS 20 

/ 1M 

Minutet 

08-20 ' ' 

. . 
mETo 

( | aamplo uamw ,mo rz-u 2o mC-N ocoa A zmto. Vo/oe/uoon 15/0 1

6`3r | 

| Data rizo ; { 

| mathod ~ 1-:\oo\MuzsKo\mrL2.*oT | 

} mrz Auuzeaa: 1 Syocmm: 1 zu1ect*: 22 natoctox:com-u | 

/ Aoalv~~~ ~ ncs ooznun/ aazo,omm,oro 2-2z-05 zwAnzu / 

Cal-ibzatiou volome niIntiou roiuto uat* atact Ston acea noject 

~ } -------------------------------------------------------------------- 

mxtoruaz z z 3, 631 oHo 0.00 121.10 uVnn 

nmxpoueut nomtpoueuta Fouuu 

' nR-t Comwow*ut arem Hoinut ooucoutzmtiou 

maoe 

( --------------------------------------------------------- 

) 3.72 cz io aciu 4,03073320 30725522 13.521 ' ______________________________ 

Totalo 30a073a20 3U7co5oc l3.azz ' 

' 

40 

- 

US 

10 

0 

~ 7 4 1

n 

1~ 
wETCO 

/ aanrjlo »xme; x3 13,4 oo 14Cm Sono a oate/ 06,110/2008 10:4-1:01 / 

| oeta rile r:\uo\uAzx\amzoma\0n-zna\:o-1nooz'o07 | 

| mothou ~ C:\o~ \mmc000\oc~2~.m~z | 

| acz axmcesa: z oystem: z zuiect0-' 7 ~otoctoz ~cz~~ u | 

/ auaz ~~~ ~ ~oo co ~umu~ ~azo' ~mm, oc~ ~-~~-o~ on uz Luup | 

caIibratiou volume Dizotiou roiuts aete atazt "toP Area aejeot 

-------------------------------- _----------------------------------- 

nutozual z z 6300 sau 0.00 21.00 cnnn 

ooW-oueut mP-port: cm^Lpnueuua rouuu 

xet componeut Acea ooioht :ouoeutcatiou 

ciommeo~ p~x 

--------------------------------------------------------- 

4.03 cl iu uaoa 211700506 501*7556 9.784 

___________________________________ 

zotazs 211700506 50147556 ».7n11 

70 

so 

50 

,S 40 

~ 

7~ 

N4i n Jh~t08-203 E18 
oote peprooesseu :u 00/10/2008 13:43.46 

| Sanmue wame' az 13,4 oo mcN ooua A omte/ 06/10/20oo 11:oz:11c | 

| oeta rile / | 

| mathou : c: mar | 

| arz Addrmaa: 1 uystem: I zujoot§: V ootootoz ~ oz~+x | 

Mcu cozuom: Aazo^4nm' oco 1-,-zz-oz uo uL L000 ! 

oozi»ratioa vozumo oIzutiou roiuta noto Stazt otop azaa aoject 

-------------------------------------------------------------------- 

uutezumz z z 5911 Iroo 0.00 I9.70 000O 

cmnnunout aePort ,noopouento rouuu 

mot nomoouout r:oa Hoight comreutrax1ou 

zioe »mom paxn 

------------------------------------------------------------- 

*.na Cl iu mans 2z2330z56 4 Si7o79n5 y.nza 

------------------------------------ 

zotm~ a uzuaanzo0 ~ e7o7ona ~ .nzJ 

~ 0 

50 

LiS 40 

JU 

1~ 

~ 

~ 7 4 6 12 1D 14 

WInQtes, 
10 

us 

20 

O 

_ 

| 

' 

~ Mmrno 

_ oetn mepzooeoaedou 06/I012008 08:35:40 

~ 

| aaoiplo mamo` s2ao4 oLAmx--ocaA uate, n*/nu/unnn zn'za:sz 1 

| oata rilo ~ ~~\c~\cmz~\;~znun\on-2O3\oa-nSooz.onn | 

| aotboo c:\oz\aaz-Hno\HCLo.uuz } 

~ | aoz Aduress: 1 oyetem: z znjoct#: .3 ceteotor:orM-u | 

/ | aoalret mco oozun~~ »a!4,4mm,ozo zwAozo / 

Calibrat1on volime Dilotion Points Rate 'Otart Stop Areaneject 

______________________________________________________________ 

oxt*coal z z ouOU soz 0.00 14.00 2000 

oompouout ~ nanoct: comgpououta rouuu 

mat Commou*ut Acoa Heinht cnuooutretiou 

Time. mame nnm 

------------------------------------------------------------- 

--------------------------------- 

rotala n o n.Onn 

0 7 4 6 8 10 12 14 

Winu'tes 

O8-203 
aoeco ENVIRONMENTAL 

oeta mepuoceaood ou 06/10/200X 06:351:59 

/ Samnzm Namo/ a2304 ozamK--oCu A oute; no/nn/000a 

| Data rile ~ o~ \oo\z~za\amznxm\no- ~ na\no-oso0z.004 | 

~ uetumu 

| Aoz Aducoos; I zujoct@/ 4 notectoz'.cza+2, | 

~ Ariazyst mco oozumu: aSl«,«mm.ozo u-uz-no Imaozo | 

caliuzatiou vnlnmo oizutiou Poiuta nete otart atcw Area Reject 

-------------------------------------------------------------------- 

outocuaI z 11 4200 5uu 01.00 1*.1fiO znSJ 

000C5ouout napol-t. oouwoueuto rm/ud 

mat Coug-poueut aroe oeiuut nouceotratiou 

zime aaote. mpif` 

------------------------------------------------------------- 

____________________________________ 

motmza O n 3.no0 

20 

~ D 

Ll 
METCO BNVJIROIRF6 ~ NTX-J-'- 

Data Reprocessed Or, 0611012008 10:27: 

Sani ✓le Name; NAoH BLANK--SCRB A Date: 06/05/2-008 -19,41:49 

Data File : 

Me-thod : C: \DX\METHOD\HM2A. MET 

AC-I Address: 1 3ystem: 1 Inject#: 40 D-e-tector:CEIM-27, 

Analyst YiCG ColLmn: AS!4-, ,djrffr,, STD 1-12-1)1 50 tiL LOOP 

Calibration "Iolume. Dilution Points Rate Start 3,tuip Ar & Re j -t 

-------------------------------------------------------------------- 

Exte-rnal 6300 5Hz 0.00 21.00 2000 

`~ FF ~ F'i FT tii T ~ f## r=Tr Crjr,°x~

-'onent Report; Corq)onents Found 

Pet corf(Tjorlent -7-z- ea Hc-i-ght Concentration 

TircLe- Name pprft 

------------------------------------------------------------- 

To- a I s- C) 0 0,000 

Fiie., OE5-09001,NO Swfiple ,. •AOH BLANK—SCR-B A 

r~ 

LI'D 

10 

Wi 

5 lu 

M inutes 

08-203 E-22 
pli 

} u5 

| ' 

 ENVIPONMENTAL 

~. 

~z~ 

oata uopr000ao*u ou no/In/ 2 OO 8 ~o :2 7 : oy 

i | eamp l e mame` »ou~~ ez A~n--yon E A uato: oo/no/onnn umn 4: zo | ' { oata rizo ~ o~ \zm\oaza\e~zom~ \nn-oox\n*-nynnz.r~ l | 

1 metuou 

1 xcz Auureay ; 1 aVotem; l zu4 eotl / 41 netec tor ; cz~-~ | 

/ | aua lrat ~ Mna oo1 umu/ aoz 4 'wmm, Iro ~ -z 2-0 1 :0 uL zmop ! 

calb,zat iom volumo oilutiou eoiuts nate otozt Stm~ o roa ae~ ent 

o~ter~al ~ 

----_----_-_--------------------------------__--------_----------_-- 

I l 6300 ~ oz 0 .00 2 l. 00 2000 

oom~ouout aspozt : roupoueuta rouud 

' aet oomooueu t azoa oei«ut Couceutratiou 

rin~ aeum 

- ------------------------------------------------------------ 

~~, 

\ ' 

--------------------------------- 

aotala o o o.3VV 

A ~ 1~ 1 b 9C 

"^"u"°° 
RO 

40 

3ci 

. u

s 

10 

~ 

0 

~~ 

2 4 6 ~ 1 a 17 

aETcV 

oata mevzooeuaeu ou o-6/1n/2OOe 08:33:42 

| oumpze mame/ az 11-2 IX mov oCnu a omte; 06109/2008 15`21:01 | 

~ oota Filo o:\or\cAzA\awznmn\08-203\06-09001'u33 | 

| metuoU 1-:\cm\~acano\oc~2.^m~z i 

~ acr audzeaa: z Systen: z zuJect#; oa omteo--nz:CzV-2 | 

malibzatiou roltuiie uilutio eoiut-s 

----------------------------------------------------------------- 

Rate Start Stop Are-aneject 

Extyruml 1 l s900 5ao 0.00 I3.00 2000 

nouwunout moport: oouwououta rouuu 

mot coupouout ax-oa 8oig-fIt Couoeutretiou 

zima m~oo 

------------------------------------------------------------- 

p~m 

3.72 cl io aciu 257792800 27514436 

------------------------------------ 

lz.sns 

Totala 257792, n0O 2, 75z4«3s 11.589 
50 

40 

30 

US 

20 

10 

0 

-10 

Fils: 06-09001,D24 SarfVle; Rl il-2 ix mrm srpp, R60 

IAETCO EIJViRC)k4MEkqTAJ, 

Data ReProcessed On 06/10/2008 08 : 33 : 51 

I Sam-pie Narfie: Ri 11-2 1X NC_K SC.RB B Date; 06/09/200a 15 : 35 ; 23 ----- 

D " c R -qt a Fii C; \DX\DATA\AMIC*L3\0E -20.3 \06-090013. D24 

C:\DA\MET!-,OD1HC-T-2JIET 

I ACI Address: i SYsteril: 1 inject#: 24 Detector: vvsz Analyst MCG C70l'urim; —R-14,4rmI,5TD 2,2 1-05 114 ACID 

Calibratioy, Volurje Dilution Points R_ate Start Stop P-rea Reject 

-------------------------------------------------------------------- 

Bxternal 1 3900 5Hz 0.00 13.00 2000 

Ccrnvponent RePOrt: CONEriOnents Founid 

Pet Corttponent Area- Height Conceritration 

Tirfie •Taimfle 

------------------------------------------------------------- 

3.72 Cl iri acid 257865080 

------------------------------------ 

27485511 K.592 

Tcltals 2•786500() 27485511 11. 5 92 

12 

IMinuftes 

08-203 E-25 
40 

30 

UL. - 

 20 

10 

0 

I-IETCO ENTVIROR4ENTAI, 

Data Reprocessed On 06/10/2008 08:35:13 

I San-ple Name; Rl 11,2 2X NCN SCRB B+5 PP1,1, Date: 06109/2008 17:44:50 

Data File : C:\DY,\DATA\ANII,)k,'-q\08-203\06-09001.D33 

I Me-thod : C: \DY,\MZTHOD\HCL2.MZT 

I ACI Address: 1 Systeni: 1 inject#: 33 Detector: IDFkl- 2 

1 Analyst WG Column: A514,4mm,SM 2-21-05 1 IN AC-ID 

Calibration Volurtie. Dilution Point-r- Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

Ex l ternal 1 1 3900 5Hz 0.00 13.00 2f 

CoLm.p.oment RRport! Components Found 

Ret CoT(Poneht Irea Height- Conceritrati-on 

Time,Nawte PPI(I 

------------------------------------------------------------- 

3.72 Cl in acid 237317840 25008681 10.715 

------------------------------------ 

Totals 237317840 25008681 10.715 

File: 06-0900l.DI-, '3 Sample ,Rl 11,2, 211 NCN IOCPP, B+S PP1• 

0 2 4 8 10 J? 

Minutes 

08-22 93 E-26 
20 

US 

qu 

=

Q E 

1cl 

e 

~ ~ 4 8 1a 12 

` auzon ENVIRONMENTAL 

oata moprooe000d ou 06/10/2008 08:35:25 

| aooipl* mame; nu 11,-1 uK »Cm ncgB n+s PmM zmto. os/oy/unoo 17;5e:1* ! 

| oata r1Io C.\oo11cw:mA\Amznma\08-203\06-0900!,o34 | 

| anthod ' «:\oo\I~ mrHOo\mzo2.mmz 

i aoz audzeaa: z aretem: 1 zujoot0: 34 matector:o ~«-~ ~ 

/ aualrsi-, ' u«o Cozumu. aez4,4mm'eT: 2-211-0* oxAcz» | 

oali13ratiou vnzomo oizotiou poiuta nate ytart nton aroa uejoct 

-------------------------------------------------------------------- 

oxtorual z z 3900 ICaz 0.00 111.00 2000 

000ipmueut aerjort: oouwoueata rouuu 

nat ocmw000ut arna neinht C.ouceutratiou 

Timo uamo PPm 

------------------------------------------------------------- 

J.7o c~ iu aciu 2387oeano u 49 ~ »zoz 10.776 

------------------------------------ 

rotmla 238728300 24953I221 10.776 

M irtute 
14 1 ~ ~~ 

10 

us 

20 

0 

MEzCO 

cmta re-nz000aaod Vu oo/m/zonn 13:44-0T 

/ aauoze m~ne/ oz za'o Inu xxzx SogB a oate; 06/10/200n 11/23/04 | 

| oata ril* c:\oz\cmsA\aazoxm\ox-203\06-zo:nz.009 / 

| metuou c:\rX\MosHno\azLua'mEr | 

! ACz Amuresa: z oretem: z zujoct#: n Eet 2 ) 

/ xualnst »eC- e oolimm/ 1o14'4mm, azu 1,12-01 50 uL Loop | 

cmli»ratiou vozumo Dilutiou eoiota aate otart ntmnazeo nmjoct 

____________________________________________________________________ 

ox ~o~ua~ z z 5850 oaa 0.00 I9.50 11000 

000poueut nemozt: coopnuoiita Fouuu 

uet oompouout arom aeiout ouuoeutratiou 

ri-ime mame npm 

------------------------------------------------------------- 

4.03 cl iu waua 74026314 1687s027 a.onn 

------------------------------------ 

rotala 740263, 1* 16875027 3.600 
~ MErCO 

/ | aampze mamo/ pu 13,4 znr Nrm acno o oate` 06/z0/2008 11`50`43 / 

~ | umta rize c:\oo\zAMzk\AmromS\08-203\ow-10n01.oIn | 

| methou c:\oz\ ~io:s~o\acL3a.yF-jT | 

) aCz aumzeao: z uratom: z zujeot#: zn netoctoz:cz-1-1-o | 

l / A:alrot ` McG --oluoin' Ae14,4mm, aTo z-110-o1, 50 uL zmon | 

 oalibratiou volume oiIutiou roiuta umte ntert 

| ---------------------------------------------------------------- 

aton x-rea ueloct 

| auterual z z c85n 5ac 0.00 18,50 20100 

ComPouent manoct: oompou*uta coouu 

_] a*t commmuout area meinht oouooutzetiou 

zinm msmm 

------------------------------------------------------------- 

xPI» 

/ 1.03 Cl iu 

~ ------------------------------------ 

maus 73839446 I5659444 3.565 

zotals 738n9446 zssoeu«* a.aoo 

us 

20 

10 

~ 

~ 

~ 7 4 6 10 17 14 16 1p 

Minutes 
50 

40 

30 

lis 

'

0 

0 

60 

7 4 6 8 10 12 

oatu mewcncoamod ou 06/10/2008 08:34:Om 

| aoupl* uariie: ac 11,2 !-X mc~ acno a oato: 06/09/2008 16:47;17 ~ 

| outa rilm / c:\oo\cAzA\omzoNS\0e-203\06-09001.o29 ( 

| aotumJ n:\oz\Moraoo\e(-L2.moz \ 

| Arz Muzeya: I aratem: z zojectar: 29 netoctor`oom-o | 

/ auazyst xeCo onzunm; Ae14,4mm,aM u-21-05 zm xuzco i 

Cmzibratioo volomo oilutinu eoiuta mato ytart otom x(rna xajmot 

___________________________________________________________________ 

Euterual z z 5900 5oo 0.00 13.00 2000 

000poueut **mort: oonpououta rouuu 

~~~ cnnwounut ar-oa oeight couooutratiou 

zi-Tae Name ppm 

----------------------------------------------------------- 

3'72 ol iu ooid 44Bo6579Oo 47230207 18.892 

---------------------------------- 

cotalo 448067e60 47230207 18'89u 

Minutes 
7 4 6 0 10 12 

/0 

~~ 

us 

AD 

~ 

0 

60 

_ 

} j 

- 

- 

aETm 

oata nemroceaoeu om 08/10/2008 ' 

| / aamnze wame' uu zz,o zn wc ~ acna a mam,; oo/oo/unon 17/01/40 | ' | oata rile r:\nz\zmTA\amzmIIa\0n-2n3\oo-09nOz.o":'V | 

 i aetuuu o`\os\moraOo\ocLo.sZ-r i 

i xcz Aduroao: I Syotam: I zujoot#; am oetmctoc:nmy-o | 

| | aualrat / uCs ozlunm: Aul4,dmm,aro 2-21-05 zmaczD | 

oalibration volnme uilutiou puiuta nmte Stact yton Aroo nejoot 

{ 

---------_--_-------_------------_--_-__--_--_-------_-------------- 

uutocuml- l z 1-, 900 5ar O.Vn 13.00 %nOO 

coupouout pxpozt ,ocmwoueuta rmuuu 

-' nat comwoueut arem eoigut c000eutratiou 

zimo aem~ Dcm~ ' 

----------------------------------------------------------- 

i a.7 2 ol iu aciu o452 oa9no 4 7z56ozx 18 .77e 

/ -------------_-__-----_----------_- 

cotmly 44526-1, 900 47a56018 18.77e 

Minutes 
MErro 

na~e ae~cocoaaou on on/zn/unoo ~ 4 `a9 : n 7 

| namnze xiame: a2 13,4 so mom onno a omte; 06/10/2008 13:33:41 | 

| oate rile c:\Ux\opuA\emIoma\08-203\06-10001.oz5 | 

| Metuou o:\oz\MEzomo\aoL2x.MEc | 

| AI«z auureao: z oratem: z zujoot-lu: 1-5 ootootoz:ozI-u 2 | 

/ auazyat / ano columu/ Aoz*,*mm, azD 11-12-01 50 uL zz"Op | 

nmlibuatioz volume oilution eoiuto aat* ntart aton azea nmjoct 

____________________________________________________________________ 

axtaruaz I z snon ooz 0,00 15.50 2000 

m*port: oouqpououta rouuu 

net compouout area ooi«ht oouoeotratiou 

zime mane zpi« 

------------------------------------------------------------- 

3.90 cz io mauH 237877032 50064109 10.838 

------------------------------------ 

cotmza 237877032 50304109 11O.nao 

~le. 06-1000l.o11c Saffiple: a2 13.4 5XmCN SC-PB a 

FQ 

40 

.30 

~ 7 ~ ~ ~ 1~ 1~ ~4 1~ 1~ 

minufAs 
METCO' BEN-VIROMM-NTAL 

Data Reprocessed On 06110/20010 14:39:20 

Sample N-mie: RL/ 123,4 5X kJCN SCRB B Date: 06/10/2008 13-54:32 

Data File C:\DX\.Ci.ATA\ANIC)NS\OE, -203\06-iOOOI.Di5 

Me-thod C:\DX\METHoD\HC-12A.KBT 

ACI Address: I System: 1 Inject#: 16 Detector;CDM-21 

Analyst MC. G Coliuiin: A314,4nmi, STD 1-12-01 50 tiL L-0OP 

Calibration Volvatie Diluti-n-n Points P-ate Start Stop --krea ReDect 

-------------------------------------------------------------------- 

Bxte•nal 1 1 5850 5Hz 0.00 19.50 2000 

noulponent Peport: CoTqponents Found 

Ret Cor(ponent I—rea Height Concenllration 

Tiffte N31fie PP-ift 

------------------------------------------------------------- 

3,90 Cl in NTaOH 235450912 52181387 10.730 

------------------------------------ 

T o t a I a,2 4 5 0 91 -1- 2 Ic ~ 2181 3 87 0 . 7 33 0 

F:.le-- 06-1000,1.D16 Semple. R2 1 -3,4 5X NCN 5CPB E-1 

70 

60 

50 

40 

tis 30 

20 

10 

0 

f-. 4 1 -2 14 16 10 

Minutes 

08-203 E-33 
1 ~ ~8 

MP,TCo 

| aampzo wamo ~ n.2 13,4 zus mcN ocRB a+5 esM oeto/ 0*/in/2008 14/15:24 | 

\ / oata rile C/\oo\cAx~\xmzomS\08-o03\00-zonoz.oz7 { 

| *etuok-, --:\oo\ ~1oTHoo\eoT,uA.ousr | 

aor Addcmau; z arstom: I ru1oct#; 17 uotoctor;oc14-21 | 

/ Avalyst / uCo oozoum: Aozu,wmm, n.mo 1-12-01 50 uz z-)op / 

oalibzetioo volume oilutiou roiuta nato otart 

_----_-_-----------------------------_--__--_----_-_-_-------------- 

aton acoa majont 

~ \` outozuml z z 5850 5az 0.00 19.50 2000 

ouupouout ueport: noopou*uta roxuu 

mnt nouwoueut u~oa oo ~~ut couoeo ~ zaz i ou 

r1ne mame 

. ------------------------------------------------------------- 

Pnm 

4.08 «l iu maua 222100366 5I297692, 

------------------------------------ 

10.253 

 \ 

zotalo 2221003(56 o12976e2 10.253 

/ Fizo: 06-10001.oz7 aempIa; ac z3,4 10z mom Scan o+u pPMI 

.. 

~~ 

~ / 

4fj 

\ 

.. .— 

, 

\ 

/ 

10 l7 14 

~. 

/\ 

| ~ 

' 

~ 

.| 

MinQ*e* 
;~ 

,~ 

80 

70 

60 

50 

40 

~~ ~~ 

I-IBTCC) ENVIRONMENTA• 

Data Reprocessed On 06/10/20010 14:39:49 

Saniple. Name: R2 13,4 IOX NC.N SCRB B+5 PPM Liate: 06/10/2008 14:36;15 

1 Data File. C: !kDX\DATA\At4IC)N,3E0,R-203\06-iOOOI.DIB f 

Me-thod C.:\DX ~MZTHOD\HC-L2A.M-ET I 

ACI Address: 1 System: 1 Injectn: 18 Detector;I-DrIff,2 i 

Arialy-qt W-G ColLirtin: A-914,4nurL, STD 1-1-2 -01 50 uL LOOP 

Cali ✓ration Volluttie Di-lution Points Rate StaLt Stop Area Reject 

-------------------------------------------------------------------- 

1 5850 SHz 0.00 19150 2000 

corcconent Report: Corrponents Found 

Ret Ccriccionent Area He - 

I _4 ght Concentration L L 

T,Iiunte Naicte ppift 

------------------------------------------------------------- 

4.08 Cl in h'aOH 223441,0 44 52- 302385 10,314 

------------------------------------ 

Tor-Als 221,441844 S-- oz-' ~ c .13 1 V I 10 13 14 

E'ile: 06- 10001.D18 low(ple! P..2 !3 r 4 10-K NI.CN SCP—B B+5 PPM 

a 2 4 6 el 14 -16 18 

tyl inutes 

08-203 E-35 
2 4 6 P, 10 17 

40 

-33 

's 

0 

~ 

Gfi 

morCo 

oata ns-procooaeu ou 06/10/2008 08:34:23 

/ aamplo woxo: xn 11,2 zo mcm Soao m oate: oo/no/moo& 17/16:03 / 

| oata rile : C:\oo\cu:uA\xnzomo\0o-20a\06-09001.o3i | 

| Methou : c ~ \o7X\MFrono\m-L2.aoz ~ 

/ aoz Atmroaa: I oyotom; z zuject#: 31 uetootuc:com-z ) 

| Auazrat / Mcu C-olumu: Ao14,4mm,Szo 2-21-05 zmAczo | 

Colibratiuu volnme uilutiom poiuta omto otazt atop Axee no ~ ect 

-------------------------------------------------------------------- 

oxtorum~ z z ayoo 5er 0.00 I-~ .0O 2000 

oomoouoot nm»ozt: oompuuouta rouud 

aet coxponeut axoa aeiOUt «ounoutration 

riue aam* mPI« 

------------------------------------------------------------- 

3.72 ol io ucid *68824120 48989363 19.315 

------------------------------------ 

cotaza 4688241%0 48989363 19.1115, 

08-203 E-36 
~ 

- 

, 

- 

~ | 

' 

' 

- 

, 

` 

MEcCO 

oata maorooe000u oo 010/10/2008 08:34:40 

| aanwzmxamm: R3 11,2 11- mom ecRu a omte ,no/oe/2oox 17/30 , 27 | 

i oata rilo c:\oz\ua:.A\ymznmo\08-203\06-0900I.o3u | 

| Metumd 

| aCz Addresa: z exatem: l zuject ~ ' au matectoe ~o~~ 2 | 

| auazyot / Moa Cozumu/ aa14,4mm,arD u-221-05 zm nozD | 

oalibratiou volume uilotiou Poiuta nete otazt nton —1--oe maject 

-------------------------------------------------------------------- 

Eutozuaz z z 3900 5ao 0.00 13.00 z000 

nourjouout napozt: 000pououts rouTid 

net comQoueut azoa oeiohc ronceutcmtiou 

ciote mume npm 

------------------------------------------------------------- 

3.72 ol. iu aciu 461903660 48614542 1e.0*2 

------------------------------------ 

Totaza 461903, 650, 46s14512 le.n«a 

60 

50 

/0 

U

~l 

Q 

~ 7 ~ ~ 

C. 1 ~ 17 

Minutes 

~~011K 
) 

~ 

80 

70 

50 

40 

~ 

- 

/ 

/ 

— 

~ 

.~. 

'- 

~ 

x

' 

\| 

, 

~ 

MEzCC) ENVIRONMENTAL 

uatu xamrooamoed nu 06/10/2008 15:21:32 

/ namnlo meme: n3 13,* oX xCm e:nB a oato: 06/10/2008 14:56:25 | 

| oatm rile o:\oz\zP.oA\P.mzomo\n10-oon\ns-zonn1.oue | 

| metuou c:\oo\MoTH0n\aoL2a.Moz | 

| aCz addreys: z oyatmu: 1 iuJeot#: zp notactor:Cou-o | 

| Arialyat : MCa cozumm' x314,4mm, yTo 1-12-01 en LiL Looe | 

calibratiou nvluicto oilutiou poiuta nate atart atop aroa majoct 

---------------------------------------------------------------- 

Euterual z z 55m uor 0.00 18.82 on30 

oomc000ut aeDort; Com oueota rooud 

uet oomnoueut acea ooimut couoeutzatiou 

rime name mum 

------------------------------------------------------------- 

3.88 nl zn maou J73u47350 7076-2338 16.3e1 

----------------------------------- 

rotala 3732«7350 70762338 I:.asz 

File' 0~1000z.D19 mample. P31' !3,4 5K NCN SCRE, a 

0 2 4 6 ~ 10 1 ~ ~~ 16 le 

'`~~~~~- 

08-203 
! ~ 

METCO EINVIRONMENTA.L 

Data Re-processed On 06/10/2008 15:21:46 

Saxknle •ame: R3 13,4 5X NCN SCRB B Date. , 06110 11 2008 15,17:43 1 

Data File C;\DXIDATA\&NIONII\08-203\06-lGOOl,D20 

Method C:\DXI\MBTHOD\HCL2A.MBT 

3kC.I Add-ress: 1 System: I Inject'r: 20 Detector; CIDM-2 

Arialyst MCG Colunin: AS14,4nuii, STD 1-12-01 50 LIL LOOP 

Calibration Volume Dilution Points R.ate Star -, Stop A-rea Reject 

-------------------------------------------------------------------- 

External L 1 5850 5HZ 0.00 19.50 2000 

Couponent Rp-port• Components FourLd 

P'2et Area Height Concentration 

T-_rae Name PDM, 

------------------------------------------------------------- 

1 ~ 88 Cl in NaOH 367883650 7175263'6 16.162 

------------------------- ----- ------ 

--:6 Tota -ts,367 6,18-3615 0 .7 4 7 " 26~" I G Ir2 

Piie. D2 0 Serjple.: R3 13,4 - - 1- EX NIC-N 3--RB B 

80 

bo 

90 

C tj 

30 

20 

10 

0 

0 2 4 6 e 10 1 --) 14 16 18 

Minutes 

08-203 E-39 
MErCO BINVIRONPLENTAL 

nata xaPcooeoaed o^ 0*/I0/20010 nn:ao:z« 

| oenplm maoe: ouaoo azA^m--ooau a nate: 06/0e/2008 10:*4;219 / 

| oata rilo c:\or\cAzA\amzmm-q\Ou-ooz\o0-oa0nz'cma | 

I matuou «:\oo\mmrmOo\eoL1u.Mmc | 

| xCz auuzosu: z oyetam: z zujoct#: o ootmotoz;cz*-2 | 

I aualrat mco nuznmu/ aazo,«mm,aro 2-21-05 ov AzID / 

omlibretiou voztmte oizutiou goiuta nmto ntar', etop a—rea mejoot 

-------------------------------------------------------------------- 

oxterual l uznn oao 0.00 14.00 21000 

nomnomant manort: 000tpouoota Fouuu 

mut CooFJouout Aree eoiOht r-ouoeutrmtiou 

zioLe uwu* xPICI 

------------------------------------------------------------- 

____________________________________ 

Totala o 0 01000 

^ 

` 

ui 

210 

0 

~ 7 4 6 8 10 12 14 

inutes 

` 

/ 
21) 

1 

~~

0 

_ 

_ 

) 

~ -/ 

~ 

~ 

| 

~ 

'| 

\ / 

| `^ 

MEzCO 

oata uonronraaeu ou 06/10/2008 08:36:2* 

~~~ ~~~~~~~~~~~~~~~_~ ~~~~~~~~~ ~~ 

| aauiple mamm/ azo04 ozAwK--uonm B oato: 06/09/20010 zo,sm/oe | 

| oata rilo c:\zm\rmz.2k\amzmve\O8-una\oo-n9ooz.000 / 

| Matuou o oo\uoz HoD\*xrc2.moz | 

| uoz adUzoea: l oyatem: z zujoot#' o oetector; Ca-1-2 > 

| Aoazyat ems coznnm/ Ael4,4mm,oro 2-21-05 zmAC-zo | 

oaz1Uzatiou volumo nizotiou roiuta nmto atart otmvaroa meject 

-------------------------------------------------------------------- 

Euteroaz l z 4200 oHo 0.00 14.00 2000 

ocmwnmout nenort; ooupouooto rouud 

aet Cou~-ouout acea maight couoemtracium 

ziore aamo IwrIL 

------------------------------------------------------------- 

------------------------------------ 

zotals n o 0.000 

rilo: 00-0,9001.o05 oomirnIo. o2501 Bza1JK7-aonB B 

~ ~ 4 R 1il 1 ~ 141 

' 

` 

'( ' 

-- 

E-41 
METCO ENVIRONMENTAL 

Data Re-Drocessed On 06/10/ ,008 1 10:210 :00 

I Saniple Nanie. NAOH BLANK--SCRB B Date.: 06/09/2- 008 -2 0:26.30 

I Data File : C:\DX\DATA\ANIONS\08-203\06-09001.D4 ~" 

Method : C:\DX\METHOD\F(- LZ-A.!,IBT 

AcIAddress: 1 System: I Inject#: 42 Detector: CEII-1-2 1. --nalyst I-ICG 11-olLuiin: ASI4,4nwt, STD 1-12-01 50 ,LL LOOP 

c.al'-Drai- ion Uclume DiluLion Poi-nts 'Rat ~-Start Sts-- jw Area xeject 

-------------------------------------------------------------------- 

External 1 1 6•Q0 IcHz 0.00 21.00 2000 

CoaTionent Report; Conip- onents F;sund 

kiet C•T(trionent e a Height C-oncentratIon 

Tiifie Nelfic- PPICI 

------------------------------------------------------------- 

------------------------------------ 

Totals 0 0 0.000 

FIle: 06-09001.D42 Sample: NAOH BLPSK--SCRB B 

us 

-1C. 

N 

10 15 210 

Minutes 

1 08-203 E-42 
' 

) 

) Muzoo -' 

uata aenzooeaaeu ou 06/10/2006 10:28:10 

~ 

\ | oauwle Name: muOH azJAmK--ocRB B ooto` no/no/onon 20/:10/50 | ' | cmta File : c;\oo\cAzA\amzomT\0n-una\06-Osn0z.o*a | 

| Metum1 ; C ~ \oo\ml3zsC)o\H(z~~&.k-~Er i 

~ acz aduceoa: z oyatem: z Iuject#; 41- oetootor;oL*+o ) 

\ | aualrst mco cuzumu: Aazu,«mm, IITu 1-12-01 on uL Looe | 

 oalibzatiou vulume Dilutiou eoiutu nmte atart otoP Aree aojoct 

/ --------------_-----_------------------------_----_--_-------------- 

`-/ Exteruel 1 z naoo sux 0.00 21.00 cnon 

Coowounut nm-port/ coopooeuty nuunu 

/ '.` aat oompouout aroa oeioht Couooutratiou 

zime mane pvm ' 

---------------- 

| ------------------------------------ 

- ~ Tote1 ~ n 0 0.000 

lifa, 

~~ = 

0 5 1 ~ 1~ ~~ 

`~ 
Metrtori: HCI,L,aiEZ - Last tTDd3tei?: 13:19 on TdllIlt 09 J11Il 2008 

CoI(p-f?IleIlt: Cl 1Ii avid 

E'lt {;rQB: T j.Izear 

r t - il . J f V 17 3 

alttt = kes~a *3. 321e-«» + 0,6787 

P,esr = amt 2.551e+007 + -2.241e+007 

stendardizntion: Er.ternal 

Calibration: I-ren 

R 

p 

n 

Ii 

B 

ge+40a F 

2 e+o o 8 k 

7 e+qDi' 

5e+9l18 

5e+i?fl8 ~ 

4e+{Jfi$ ~ 

3i3+008 

 ~ 

=e+ijf;8 

~ 

1e+0 ~~8 ~ 

J. Dt+ ~ 

0 . !1[t 5.00 lr. Otz 15 . ~'0 

Anount(gpm) 

25 =0 3ti 

I 

, 

. y 

08-203 .. 
amrno o»VzaomMomszL. 

oata nemrooeoueu ou 06/10/2008 Oy;Jo`*n 

/ nomnln mAmo` 0.5 xnnM ~1, rcV oato/ no/nn/znoo 11/15;08 | 

} oeta riIe c:\oo\zAza\amzomI\08-z03\06-0900I.007 | 

| methmd o:\oo\MEzmxo\acL%.aoz } 

| a«z auureoo: 1 System: z zujoct#: 7 Detector;oEm-% | 

| »malrst MCo oolonm: aa14,4mm,--co u-az-no zm ACzo i 

oalibzmtiou volnmo uizutiou eoiuta ueto otmct etop Area najeot 

-------------------------------------------------------------------- 

Eutoruaz z z 4200 5ao 0.00 14.00 2GnV 

000p000ut neriort: Coopououta rouud 

mot oompouout aree Heiuht Counentratiou 

zinve memm nnm 

---------------------------------------------------- 

3.82 ol io aoid 7202827 n%O2, 9n 0.50z 

------------------------------------ 

rotala 7262827 ou0u9V 0.501 

I~ 

12 

~ 

~ 

~ 

-i .9a 

a ~ 4 K ~

n 1? 14 

inutes 

08- 03 E-45 
_ 

/ ~ 

~ 

.~ 

- 

»aencV ENIVIROYMBNTAL 

oata uo.Dcoceooed ou 06/10/2008 09:1-16:50 

\ | oauwlo mamo ~ z pz*« c~ zcv ~ato/ oo/op/ 000V 

oata rilo C:\zX\uszA\amznmo\001-u03\06-nBn01.uO8 | 

| method C:\oo\eEz0Oo\oc-Lz.uoz | 

 | arz auozeao: l Syutam: z zujocti: 8 moteotoz:cc?.-2 ~ 

( | auuzyut Mce ooluom: a5z4,4mm,oTu o-oz-uo zx ACzu ( 

cozibzatiou Yolnmo oil-utiou roiuta xate ftazt ytop a-rea aejoot 

| -------------------------------------------------------------------- 

) outeruuz 1 z 4200 5ox 0.00 I«.oG %0o0 

ocmqpoueut usport: conipoueuts ruuuu 

) 

.| aat conooueut xxoa Heiyht couooutrmtiou 

zimo mmxe ppm 

------------------------------------------------------------- 

/ 3'72 cl iu noiu 15066751 1791853 z.000 _\ ------------------------------------ 

Totalu 16066751 I791853 1.000 

- 

12 

' 

10 

- 

| A -/ ~ 

6 

| yD / 

4 ' 

~ 

( ~ 7 4 

^> 

tAinutes 

~ 

\ ~ 

17 14 
1el 14 

` 

- 

/ 

~ 

-' 

METCo EITVIRONTIMBNTAL 

' 

oatm xoprocosaed ou 06/10/2008 09:37:02 

- 

\ | aao pa* yame ` 2 . 5 nz 1,1 o~ !Cv oate, 06/ 0 9/ 2nno 11:45/47 | 

~ | omta File ' C:\uo\c~zo\aazom~ \oo-%0J\oo-O9Ooz.o09 | 

| *otuwu ~ C:\oX\~ar~~o\on~%.»osz | ' | Arz xuxnrona: z aystem: 11 zujent#: y neteotor:oom-2 ( 

uuazvat mnn oolumu/ AAolo,omm,aTu 2-21-05 zw m«zu / 

- oalibrotiou rolume oiluziou pniuta nmto otert atoP aroa Dojoct 

| 

-------------------------------------------------------------------- 

/ Eutoruaz z z 4200 5er 0.00 z«.On 2000 

noopouout neport: ooutpomouto romud 

\ ` mot Corupoueut xurea seioht omuooutratiou 

Tiote mane xnon 

---------------------------------------------------------- 

/ 3.72 CI iu acifi 42583880 4012001 2.504 

- ~ -_-----------_----_------_--_------ 

rotolo 42583880 4612, 061 2.5o4 

12 

- 

10 

{ 8 

~ 

( uli 

4 

'\ 7 

~ 

mi 

08-203 E-47 
MR-TCo NITVIRONMENTAL 

Data nepcooesood ou 06/10/200e 0e:37;12 

| yanw,zo xame ,a peu cl z/n/ oate` oo/nw/cnon 12:011 07 / 

| oata riIo C:\ox\cmzA\AmIo~o\08-203\0*-09001.ozo | 

{ m»thoU -C:\oo\mnzano\oz~%.mor { 

1 xcz Audcoaa: 1 aystem: z zujyct#: 10 ootoctor;oDm-z \ 

I An*lrst / *oo Columu; A314,4mm,3co 2-21-05 zmaozo | 

oaIibzatiou volnmo oilutiou roiuta nate otazt atom acea Reject 

-------------------------------------------------------------------- 

oxtocual I I 42,O0 5H7- 0.00 14.00 2000 

oomnoueut smmozt: onmpououta eouuu 

mot Compouent ezea Geigut nunooutratioo 

rinLe Beute zno« 

------------------------------------------------------------- 

3.73 cI iu aoid e2754080 9812325 5.049 

------------------------------------ 

rotaIo 92754080 9812326 5.049 

US 

~~ = 

~ ~ 4 8 10 12 14 

Minutes 

. 08-203 E-48 
- 

| 

| / 

` 

` 

' 

/ »Ezco 

~ 

_ _--_-__ 

uata nepzoreaood ou 06/10/2008 0e:317:23 

U | aample m,me./ zo peFi f-L zcr zato/ ns/ox/conn 12/20/47 | 

omta rilo 

| Metuou C:\o3\mBzaoo\aCL,2.emr ~ 

 i aC-z ureaa: z eratem: z zujooi-A; !z matootor:«oMj-2 > 

/ | aualvst mcu oolumu: ao14,4mm,3rD o-12z-no 114 a:zo | 

oaziuratimu rolome uizutiou roiuta nmto otart atop area nm-ject 

) 

--------------_-----------------------_-------------_------------_-_ 

out*r-ual l I 4200 5ao 0.00 z«.nV 00O 

Cnmwouout uspmrt: oumVoueuto rmriuu 

~ nmt Coomuuout acoa uai«ut onun*utcutiou 

~iu~ aaoe m~~ 

. ' ---_-----_--__-_--_----------------_------------------------- 

/ 3' 7z ol io ac ^ u 221 727 000 22 94 6 7 61 zn.ou0 ( '' ------------_--_------_-----__--__ 

zotal'a 2, 21727000 2 ~ 946761 10.0110 

\ ' 4U 

/ 

] 

` 

' 

~ 

~ u~

0 

\ 1O 

0 

n L- ~ ~ ~ 1~ 1

, 

~~ 

08-203 E-49 

\ 
METCO EWIROYMBNTAT, 

Data Re-pro•essed On 06/10/2008 09:37:333 

1.5aniDle Name; 15 PPM LT, Ic7V Date: 06/09/200. 8 12, :36:07 

Data File C:\DX\DATA\ANIC7N~ "08-203\06-09001.D22 

Method C:=K\MBTHOD\HC-L2.1,1ET 

ACI Address: 11 Systeni: 1 Inject#: 12 Detector: CD,11-2 

Analyst MiCG Column: AS14,4mm,STD 2-21-05 IN ACID 

Calibration Voluifte Dilution Poi-nts Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 4200 5Hz 0.00 14.00 2000 

Component Report: C!,ort(Donents Fotind 

Ret C01(porlent Area Height C•ncentratioR 

Tiicte 1,14affLte ppla 

------------------------------------------------------------- 

3.72 Cl in acid 349514560 35567288 14.901 

------------------------------------ 

Totals 349514560 35567288 14.901 

b 12 14 

t-Ainutes 

er, File: 06-09001.D12 "ample: 15 PPIl CL icv 

Eia 

4'u' 

-if, -3 Li 

us 20 

10 

ri 

-10 

0 

08-203 E-50 
' 

' 

/ 

, 

' 

/ 

.1 

-

~ / 

| Mozr-o -` 

oata xepzooeyaod ou 06/10/2"008 09:37:*5 ' 

\ | aaxipzo mamn/ us Ps*I oz zcv Daxe' na/n*/onnn 12/51/26 } ' | oata rizo c/\oo\u»zA\Amzox ~q\08-203\06-09001.cu3 | 

 | mothod : ~ \oo\yozaou\HCI~ 2.14oz | 

| m:z Addzeu,: z yyntem: z zuject#; 13 oetector;CzM-% | 

| | Auazyat / mCo oozunm ,aal4,4mm,azo u-oz-no ovaozD | 

` Calibcatiou vozuomo oizntion roiuto nate atart aton acea aejeot 

` _---------_---------_----------------------------------------------- 

) Exteruml z 4200 soz 0.00 14.00 2000 

om«pomeut emPozt: cnmpououto souu4 

/ aot Cumwmuout aroa oei«ut couooutretiou 

ziue oanne P-Pili ' --_--__----_------_-----------------------------_-__------_-- 

i i %5 ooz / a.7a cl u oo u 6%hs25O*o o* ~

z7pIa . 

. / ------------------------------------ 

zotazo 0265125040 64417913 25.443 

' 

-/ 

80 

' 

Go 

- 

| ~~ - 

40 

Minutes 

' 

` - 

-' 

\ 

/ 

-' 

08-203 E-51 

-i ? 14 
METCC, r-MVIRONMENTAL 

Data Reprocessed On 06/10/2008 09:37:53 

Saniple Name; 313.33 PPM = !C-V Date. 061/09/2002 13:06:46 

Data File C:\DX\r.,A.TA %,ANIONS\08-203\06-090OI.Dl4 

Method C: \DX\1-4ETHQD1HC-M2.14ET 

► ACI Address: I System: 1 Inject#: 14 Detector:CDM-2 

Analyst MCG Column: AS14,4nuft,STD 2-21-05 IIJ AC-ID 

Calibration Voltufte Dilution Poirits Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

ENternal 1 1 4200 5Hz 0.00 14..00 21 000 

Comr-, •uesnt Report: Conponents Found 

Re-t Comporient Ax- ea He'Lght Conceritration 

~ ime I-Tame pprt, 

------------------------------------------------------------- 

3,73 Cl in aci-d 863047680 86861410 34.716 

------------------------------------ 

Totals 863047680 86861410 34,716 

Fi-le. 06-09001.D14 S-~uanle; 33.33 PPM C-1 !-V 

1 2-ri 

6-0 

60 

us 

40 

20 

0 

-1 0 2 4 6 8 i pi 1? 14 

minites 

08-203 E-52 
METCO BNVIRONMENTAL 

cmto aworoceaved ou 06/10/2008 09:38;07 

\ | oaripuo Narfie: uo PPM nM CHK STD Dalle: 06/09/2008 13/22:04 | 

' ( oata rilo c:\ca\cocca\Awznm'Z,\oJ-%OJ\0h-n9onz.ol5 | 

( Ile-thou 

| arz Audreau: l orotom: 1 zujeot*: 15 Detector;ccaA,c | 

| / aumzrst / MCe coiuonri/ xaz4,4mm'aru2-2I-05 zu ~czo / 

' noIibratiou voznmo oiluticm Poiato aato otart atq*p -Acea majeot 

/ 

-----_------_--_--------------__---_--_-------------_-----_--------_ 

mutocual I z 4200 3Hz 0.00 114.00 2000 

Coupumnot nepnrt; noorpuuouta rouud 

| ~ nmt Compoueut aroa oeiout couoentratiou n/o 

r±om mane Ppm 

------------------------------------------------------------- A~ \. ' /^~~ 

( 3.73 ol iu aoid *87132660 51349630 %o.Ooo ~ 

. ~ ------------------------------------ 

cotuza 487132660 51J49630 20.036 

/ 40 

( / ~S ~~ ~O 

20 

10 

'! 

! / Ff 

` 

G Q 1C, 

\ 

- 

----- ' 

~ ~ 

/ 

`| 

j 

08-203 E-53 

1 -~ 14 
METt=t, Etr'VIkClNitENT1iL 

Data ReprocessedOn 0£I10l2008 0-9:318:18 

L I Sample PJanie: 20 PPR4 t_~ C.HI{ S TD Date: 06I09/2000 13: 3 7: 24 1 

1 E Data Pile : C:iDX\DATR\ANIONS\04- -~, 0 1\06-09001,D16 1 1 

1 Method : C DXl.METHOD\HCL2.MET ; 

l i -f1CI-ACki?'ess== 1==Sy5=°m=-°== lri3ect#===~ ),et?ctw.i-c:D:S--==== 1 

Ij (~Sic^aiySt }St't~ {'. ~7].till'IYI: rs 14 , 4''ZQZCt i 5 TD L.-G;I-U` ip~ f?S=.ID I 

, , . 

~ a ~ n .-..~. c_all~r?tsoZ1 Vrltune Lzlutz ~rl P~ irlt5 ti.ai,e ~~ tnY'L ..~Li~~? rv.c ~ 1?.ejcCt 

---------------------------------------------------------- 

~ E2kteY'iz;l 1 i 9200 5HZ 0.0 14.00 2000 . 

~~'?Ci~7~~ rieitt c~='b+f~ _'%` ~v..r`_C~~t~~ rEeiit=; L~`[,i-i Ik=i 

l F:e; ~`r}ri4'~C~ tLeY"I= ~ n.z r__._:. ~e 'r'.tiit_ht t ~ari A t=C~ i1e_eriti'r~ ' ~ 

T:i.itte N3~tt e ~~Itt "~ q - ~. 3 --- --- ~ ----------- --------- --------- --- 

 5111-------_------------^- ~ 9Pe 

~ 

~ 3.7,. C1 in acir~ 48775b8 ~70 2n.9a0 

00 

------------------------------------ 

Tr,tals 487756640 51113486 20.060 

1 Fiie: 06-00001.D16 Sartple: 20 PPhi CL CHK STD 

50 

~ 

~ 40 

1 ,'8 ~1 L 

I 20 

I 

10 ~ 

J Mirutes 

, 

; 08-203 E-54 

I 

J2 14 
` 

/> 

/ 

-) 

08-203 E-55 

- 

.| 

' 

' 

_ 

~ 

_] 

~ 

( xauzoo ENVIRONMENTAL 

_! 

oata ne-prooeoueu ou Oa/lo/unOo 09:38;3"' 

\ | aaow,l o mame : oo nmu -c C-oK aUo/ CoIV oo to` no / oo/ uoon 16/zn/32 | 

outa rizo c:\oo\onTx\Am1014~q\08-m03\00-09001.o27 | 

~ Me-thmci m\oX\xauz000\Hzux.1-4 or ) 

' | acz Auucoso: z orsteVI: z zuject 4n; ooteotuc:omy-2, i ' | Mazrst / 1110~. o~ aal~,~~~~ ~-~-~ zm ~~ | 

 oalibratiou volnme uizutiou poiuta mato Start utop araa ae-oct 

\ -----_---------_-----------_-----_--------------------------------- 

-) outerual I z 3900 5oo 0.D0 13.00 2000 

ouo~ouomt ounort: ooumououta roond 

l uot noupoueut aroa oeiuht 00000utcotiou 

T1ma monue mp-« ^^~ 

------------------------------------------------------------- ~~(n

iX\ 

3.72 o ~ io ooid 484754180 onaxu*on z9'9yo C~

c\,Y/ D 

( ' 

_________________________________ 

\ ` 

-- 

Totelo 48475410Vn 50382623 ze.s«2 

-J 50 

' 

40 

_ 

' 30 

( u~ 

/ 20 

~

) ~ M 

_) '- 

0 

-' 

- 

4 ~ ~ 1~ 1~ 
METCC) ENVIRONMENTAL 

Data Reprocessed On ---------- 06/10/200• 09:11 8:43 

Sainple N-me: 20 PPM C-L CHK STDICCV Date; 06/09/2008 16:32, :54 

Data Fi-le C:\DX\DATA\A.NIONTs\08-203\06-09001.D28 

Method C- : \DX',lMzTffODlxHC--2.MBT 

ACT Address: I -lysteni: 1 Inject#: 28 Detector: CDM-2 

Analyst MCG Column: AS14,4mrn,STD 2-21-05 IN ACID 

C&1 4 -rat.-'Lon Volurae Dilution -voints Rate start Stop Ar~a Reject 

-------------------------------------------------------------------- 

1 3, 900 5Hz 0.00 i3.00 2000 

Component Report: Components Found 

Y -, I e~ Corciponp-nt Ax- ea Hej-gh ~ ~ I - oncen~L rat J- 4 on 

~r: ime 1-lanip- ppift 

------------------------------------------------------------- 

3,73 Cl i-n acicl 488001020 51-5 13967 

------------------------------------ 

Totals 488001020 15 1513967 20.070 

-Fille. Sarop-le: —90 PPxM C7— CHK STDICCV 

60' 

53 

40 

21) 

Us 

20 

10 

0 

-10 

0 2 4 6 

Minutes 

08-203 E-56 
- 

— 

/ 

- 

/ 

j 

/ aoron 

'\ 

____--__ 

oata nmDr000ysed ou 05/10/2008 09:38:54 

~ | oax~~e m~oo~ ~ rp~ cz rcv oa ~ o/ oo/n9/uonn zo ~~~~ np / 

/ | oata ril* C:\oa\c~zA\ahTzoNI\o8- ~ 0a\oo-uenO1.om5 | 

| ee-thm2 m\oz\MaTamu\DC.TLu.Maz { — | Arz aLiuzeoa/ z Syaterm 1 zu1e ~t0~ a5 ootectoz'cr~-% | 

} / ~~~~ W. ~~m~/~~4,~~S~~o~-~ zm~~ ~ 

| 

cmzibcatiou voltuqo oilutiou poiuto nate ntazt eto -D areu mejeot 

i ----------------------------------------------------------------- 

/ muteruaz z l 3900 5ox 0.00 13100 2000 

000pouout aenoct ,Comnoueuta roouu 

) net ~~o~ut urea ooightmmnentratioo 

zinte meofte . nmTL 

------------------------------------------------------------- 

| n.70 oI iu ociu I60740e5 1779445 i.Vnz 

rotala 16074095 I77e445 i.001 

- 

12 

— 

1 ~ 

- 

~ 

6 

\ u~ ' 

~ 7 4 ~ ~ 1~ 17 

Minutes 
40 

20 

Us 

10 

a 

Fi--, e. ,. 06-09001,D36 Sarciple; 10 PPM CL CC--V 

40 

4 6 8 1 12 

METC0 BNVIRONMENTAI, Data Re-processed On 06/10/2008 09:39:04 

Barimle Narcie: 10 PPM Ci-, CCV Date; 06/09/200• 18:"&: Vz, 

I Data File (7;1DXlDATA ,,AN!Oklb'lfjl,'- ~03"0u-09001.17 ~36 

Method C:\DX\METHOD\-HC-L2.MET 

ACI Address: 1 Systera: 1 Inject#: 36 Detector:CUM,', Analyst -MCG Column: A-;14,4nvt,,--'TD 22-2j-05 IN ACID 

Calibration Voltime Di-ltztion Points 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject 

1 1 3900 S-Hz 0.00 1-3.0n 21 C,0 0 

Cf-;Joporjent Rqp-ortz Components Elound 

Ret Components, A-rep Height Concentration 

Tiicts Name, PPICI 

3. 7 2 Cl in acici 2 2,15 9 62 r,- ri 2 2 --- 9 9 4 10.045 

---------------------------------- 

Totals 22, 1596260 2-2297094 10.045 

Minutes 

08-203 E-58 
~ 

oeta oe-pzoceaa*U oo 06/10/2008 09:39-12 

| aempin maime/ 25 PnaoM ocV oatm' oo/nn/onon 18/42:26 | 

| oata rile o:\oo\unoA\amzomz\08- ~ 03\06-0e001'o37 | 

( yethou o:\ox\moxsn)D\ouLo.u3tz | 

| acz Auuzraa: 1 aymtam: 1 zujeot#: 37 oetootor/ozIM-u | 

/ aualyst Mro Culuom: ael4,6mm,3ro 21-21-05 zmaczo | 

Caliuratinu Yolume oilutiou poiuta uato atart atmv aroe nmject 

-------------------------------------------------------------------- 

oxteruez z 1 3900 sHo 0100 1n.00 unoo 

000~ouent Deport: oonVoueuto ronud 

aot nonipouout aroa nnioht ooucoutraticm 

zime muue rpm 

------------------------------------------------------------- 

3.73 nl io aoiu 615318840 63751705 25.003 

------------------------------------ 

rotalo 615318840 63751705 21a'11-103 

LIE, 

/0 

20 

A 

0 c Q 1? 

0&-203*1 E-59 
1 ~ 

' 

MEcoo ENVIROMMENTAL 

ualla xe-pc0000aem ou 06/10/2008 09:319:26 

/ | uato Filo c:\ \010-203\0o-0900I.o38 | 

| xetuou c ~ \oX\Muraoo\arLc.14az | 

 | xCz mmuzeaa: I oyotom: z zuject#- 310 ceteotor:ocM-2 | 

| | Anazyst ' ME-G ~uirtri/ Ab'14'4rrffL,STD 2-21-05 IN ACID 

] 

/ 

CeIibratiou volnmo xdIutiou roiuto aate Stert 5to» Acem xeject 

/ _--------_----------__-----_-------_----_-_-----_---_----_--_--_ 

/ Bxteruaz 1 1 3900 5Ho O.On l3.00 2000 

omxpouont m*pmrt: nnoponouto rouuu 

 x~ n ~t com~ouout a~eo ~e~qut ~ouceutcat1oo [} \ 

Tiue maue ppm \0D' 

~ 

~ 

------------------------------------------------------------- 

} z.73 ol iu ooid 4863e8040 51347+04 _71n.no7 

~ ------------------------------------ 

cotmlo 4263e8040 51347404 20.007 

J rile. 0:-09001.oa8 Sanplo: 20 pgu «L o-Hm oru/ocv 

- 

) -50 

- 

\ u~ 

- 

20 1 

< 1Q ~ 

~ 

- 

~A 

. 

\ 0 

j 

. . . . 

7 4 6 

. 

10 

M. i 

. 

.. 

03-203 E-60 
_ 

{ _) 

— 

' 

\ ' 

unrCw E",I"°~,E°T,L 

- 

oota nenr000aoed ou 06/10/2008 09:39:51 

aample mamo. uo peMccoaoazo/ccV oato/ 06/05V2008 zn:zy/us / 

} | outa rilw o:\oo\zAza\emzomo\08-203\06-090oz.o39 ~ 

| Methou o:\oa\a-PzoVo\acLo 'MEz | 

) ACz acluroaa: z Srstem: 1 zujmct#: a* »eteotor:CU4-2 | 

| / aualyat / MCu «mzunm/ aoz4,4mm,oTo 2-21-05 zmaozu ! 

nolibretiou volziine oi1utiouPoiuto aato etazt etmp-11'eo aejoot 

/ ----_---------_---------------------------------------------_------- 

/ Extorua1 z 1 anoo ooz 0.00 za.ay 2000 

- 000poneut xenurt: Comwououta ruouu 

-] 

/ 

xmt oompmueut acoa 1-leiaut 0000eutratiou 

ziommeoe Dpm 

- ------- ------- ---- ------------------ ----------- -------------- 

/ / 3.73 cl iu 

( ------------------------------------ 

eciu 486260800 513*01e0 20'001 

"otaza 486260800 51340190 20,001 

' > Filo; os-npoUl.o~ y oanplo: %D ppucL caK nco/ooV 

/ == oz iu aoiu 

{ 

50 

- 

40 

( ~~ J 0

~ 

e-U 

10 

0 

~ ~ 4 P, R 1 ~ 1~ 
»ethod: aoL.2A.mur - Laat nDuateu: 10:26 ou zoo, "o J"uu 2008 

oouipoueut: uu iu maoo 

rit rspo: Liuyar 

r` ~ 0.999121 

amt ~ aesp ° «.u«po-non + 0.4666 

acse = umt + e'254e+007 + -1'099c+007 

otanuazuizatioo: oxtezoaz 

caziuzatioo: -krea 

R 

e 4e+Ono 

5 

p 

» 3e+o08 

u 

s 

e os+noo 

0.00 2.50 5'00 r.so 10.00 iu.0 z ~ 27. ~ 
MErCC) 

oate uewruooan*d ou 06/10/2008 ~0~2V~n8 

| aawze momo/ 0'5 PsM oz zcv mato: 06/09/2008 -21/1z:zn | 

| cmtu File C:\oz\zAzA\AwzVmr\OX- ~ 03\Oo-Oyonl.uw« | 

| met&m1 c ~ \om\mozso0o\H ~~2u.yaT | 

| acz nduresa' 1 oyntem. z zujoot#. 44 ootootor;cc~-a | 

/ Aoazsmt mCu colomn/ a814,4mm, aTo z-1c-n11 oo un ZmOe } 

Caliuratiou vozumo Dilutiou Poiuta mute atazt at-op -1-roa xejpot 

-------------------------------------------------------------------- 

oatorual 1 z nnno 5uu 0.00 211.00 2000 

000ipooaut neport: omxpouoata rouuu 

aot commoueut aroe ooight Couoeutcmtiou 

cima Nsiae Ppm 

------------------------------------------------------------- 

4'23 ol in meuo 7956200 23895-99 0.504 

____________________________________ 

zotula 7956200 2389529 0.50* 

10 

8 

6 

uS 7 

0 5 10 15 20 

Wiinutes 
MErm ENVIRONMENTAL 

uata xopcoc000ed oo 06/10/2008 10:28;51 

/ oaomuo None/ z npm oz zmr omto/ 06/0e/2008 o1`a3'310 | 

| omta rizo o:\oa\oauA\amzoma\08-203\06-09001.u45 | 

| eothod C:\oo\M9Taoo\Hz1,2a.1az ~ 

| acz Auureoo: z oretem; z znjeot0: 45 Detector ozIA-2 | 

| Aualyet / uCo oozumu` ae14,4mm, arD 1-12-01 50 uo LOoe | 

omIibratiou Volomo nilotiou eoiuto natm atart otonarea majoot 

-_------------------------------_---------_----------_----------_-_- 

outerual z z 6300 5ao 0.00 21.00 2000 

nnm~ouout gmpozt: ooummueuta rouuu 

a*t Cooponeut azem oeioht oouooutratiou 

rime naite Mm 

------------------------------------------------------------- 

4.23 Cl io u*ns 1e241360 4280o27 1.002 

________________________________ 

rotelo znz«znsn 42802217 1.002 

cL-Ie ~ 06-09001.o45 amowle. 1 rpm oz zcY 

^8

~ 

4 

uS 2 

~ ~ 

1Li 15 ~~ 
 Moroo ElAURONMENTAL 

nata pe-pzooeao*d ou 06/10/2008 10:2e:03 

| aaoTiplo mame: 2.5 pzH oL zcv oate` oo/Vm/uVon 21:55:51 | 

| Data rile o:\oY,\cAsA\amroua\0o-2on\0o-ng0o1.000 / 

| Motuo« o:\cm\mazsmo\Hc.12u.usT | 

| acz uuuroao: z oyatem: l zujeot#: 46 oeteutoz:Com-u | 

| nuazyst : mms nolumu` aa14,4mm, aTn 1-12-01 no tiLzooP | 

omziuratiou rolume oilutiun Poiuta 

------------------------------------------------------------------- 

mate atmrt aton azoa n*jeot 

~xte~ua~ z z 6-Ao0 5ox 0.00 21.00 2000 

oompoueut nxmjort: 000pououta rooyid 

not C-nni7joueut Azoa oeioht couoeutzatiou 

ziom maum 

------------------------------------------------------------- 

ppin 

4.22 Cz iu uana 49137460 120744207 

____________________________________ 

2.499 

' zo~~ zu «y ~ n7000 zaU7«2n7 2.*e9 

us 

Q~ 

~~ 

If 

~ 5 10 70 

MinW~: 
~ ~ 1~ 15 7~ 

MErm BNWIRONMENTAL 

oatu maprocesueu ou 06/10/2008 10:29:14 

aanwle Name/ u peu oz zcv zmto: ns/ne/onnn 2o/11n'11 

/ | oata rizm C:\oo\cmz—I\e ~\Tzomo\08-203\06-09001~ .r47 | 

! me-thud 

- | aoz auureay: z oyatam: z zudact#: 47 Det*ctor;nzM-% | 

| | aualyot aoe columu ~ J4e14,4mm, a~- o I-lo-nz 6n uo L0op / 

oaIilDratiou vozunm oiIntiou poiuts 

-------------------------------------------------------------------- 

uate etazt aton Acea a*jwut 

| / autocual z I 5300 5nn 0.00 21.00 2000 

omunouoot napozt: Compoaauto rouuu 

 / net Comnouont ar*a aeioht ooaooutrmtioo 

zine meme 

_ --------_--------------_-----------_-----------_-_--_-------- 

n«ox 

| 4.22 nz iu maoa 102283n74 

> 

2»u897oo 4.8*7 

------------------------------------ 

zotalo zn2,2e3, nl4 234ne76a 4.897 

/ 

_) 

~~ ~~ 

' 

20 

.. 
_ 

| / 

~ ~ 

' 

- 

MErCM, ENVIRONMENTAL 

_ oata maproceaaeu ou 0611012008 10:29:31 

| / aaoipzm mame; 7'5 pxM ~1, zo-V oate/ 06/09/2008 u2/40:32, ( 

| oeta riIm C:\on\zAzn\amzom"\nn-oO3\no-o9no1.o48 | 

_ 

| Method o:\D_X\METH0o\aCL%A1.1-4_ET | 

| aoz audzooa: l nratam: z zujoct#: 48 u*toctor:oc11-2 ~ 

( ! auolyat Wo Columu/ Ao14,4mm, *To on uc zmop | 

Colibratiou voluoe oilotiou roiutu nmte etart otop aroe uejeot 

| 

-------------------------------------------------------------------- 

ou~e~u~ z z 1 oann 5oo 0.00 21z.00 2000 

onmipounut nsport: 000pooeuto couud 

| -' not Cumwouout ur*a oei«ut cuuoontratiou 

Time muoe nxTCL 

--------------------------------------------------------- 

| 4.ou cI iu maoo 1611 5405 0 38139000 7. 506 

/ ------------------------------------- 

zotalo 181164050 aoiosVnn 7.506 

50 

40 

20 

10 

0 

~ ~ 1~ 15 20 
lu 

File: 06-09001.D49 Sample: 10 PPM C-L ICV 

60 

59 

40! 

30 

U-a 2u 

-10 

=20 

0 F, -1 ?al 

MDTCO BNVIRONMENTAI, 

Data Reprocessed On 06[1012008 10:2a:44 

Saiiiple liazie: 110 PPM C.-J, IC-v Date: 06/09/200ti 23:02.r. ~ 

Data File C;\DX\DATA\ANIONS'loB-20'\06-09001.DI9 

Method C: \DK1METHOD1HCL2-I.MBIX 

ACI I-ddress; 1 Systemi: 1 Inj-ect#: 49 Detector; CEN-2, 

AnaIVS -L MCG ColiLmri: AS14,4nm, STD 1-12-01 50 ViL T-OOP 

Calibration Volume Dilution Points Rate •tart stop A-rea Reject 

-------------------------------------------------------------------- 

ExternAl 1 1 6300 SHz 0.00 21.00 2000 

rCojtponent- Pe-port: Coicponents Fourid 

Pet Component, Area Height concentration 

Tinto Narfte PPlli 

------------------------------------------------------------- 

4.221 Cl in NaOH 218012704 52441800 110,069 

------------------------------------ 

TotAls 21,2012704 52441800 10.069 

08-203 mm 
u~ 

40 

100 

~~ 

N" 

uozCo ENVIRONMENTAL 

oata meprou0000d ou 06/116/2008 10!29:5-8 

} yamnlo mame: za ppm CM zor omto` u6/nn/2'non 23;25:113 } 

| Deta rilo ; C:\Do\cmsA\eNzomo\o8-20a\01-=-090nz.o50 ( 

| mwtuoa ; C:\oo\mozso)o\oz.--oA.emz | 

! aCz Auuzeao: l enntem: l zujeot#: on uetootur`CcM-12, | 

| Aualvst ],K-'s oozumu' ae14,4mm, ero 1-121-01 ou uL Looe | 

oaliuraticm volome oizutioo Poiuto nate atazt nton Aroa nejoot 

-------------------------------------------------------------------- 

mxtozuuz 1 z el 3100 oax n.nn 21.00 uoon 

compoueut peport; nompououto pnuud 

met CcmDoueut aioa s*ight couooutcatiou 

rinm momo mpm 

------------------------------------------------------------- 

4.22 Cl iu maoH 335II0754 82622500 zi.701 

------------------------------------ 

rotuIa 3351-10754 02022600 14176z 

~ ~ 1~ 1~ ~O 
~ ~ 

| 

~ uoroo 

natu ma~roueouo~ ou n*/zn/unnX 10/30/15 ' 

\ / Somple.mame: uu pzY.cz zcv oate: oo/oy/onoo oa`m:a« | ' ( ooca rile / «/\oX\couoA\~, zoNa\06-203\06-V9ooz.o5z ( 

' 

| uethod « ~ \oa\~-aTaoo\HzT- ~a.aoz \ - 

| P.cz AUuceoa: 1 ayetom/ l zuject#: 5z oeteotoc:crw1,21 | 

| | uuazrst ' woo Cozuon/ A-e!4,omm, nco 1-12-oz Sn uL zmoe / 

caliuratiou volumo oizutiou poiota nato atmrt ytop area meject 

/ 

-------------------------------------------------------------------- 

~uterual l z 6300 5ao 0.00 21.00 2000 

oomPoneut neport: oomnomouta rouud 

' mat oompoueut aroo oeiout couooutratiou 

zime Nlaote- PcUI 

-------------------------------------------------------- 

| 4.22 ol iu maue 464956328 1!3973348 20.u16 / --------------------------------- 

zotala 4649566- 20 1z-397334n 2n.216 

/ 120 

| 1OM 

| ~~ 

/ 

80 

60- 

| 40 

[ 
| yarco 

oata nepr000aaed Vu 06/I0/2008 10:30`36 

\ ! aampze marne; ua Peu oz zov oate; 06/10/2008 00:09:54 | ' | uata zizs C:\oa\oazA\amrmmn\08-20n\06-09noz.o5a i 

| Metbou o;\oo\mocHOo\acau.A.J1oz ~ 

i acz Auuzess: z eyatmm: z zujoot#: 52 ootootoz:crN-2 } 

i | Auazrst MCo oozumu: xa14,*mm. ezu 1-12-01 50 uL zOVr | 

oalibratiou vnlume oizutiou roiuta uato Stazt nton aroa ue-J ---nt 

/ 

----__-_--------_---_--_---_-_---------_---_------------------------ 

outeruul z z 53O0 5uo 0.00 21,00 2000 

noowouout a*pwrt: 000poaeuta ronuu 

' smt oompoueut A-roa oaiglit ooucoutratioa 

eime mame PPHI 

 ----_------------------------_----------------------------_-_ 

~ g.%% cl iu NaoH 578927574 142017633 25,057 

~ ---------------------------------- 

zotala 578927574 1*2017632, 25.057 

16LI 

140 

120 

100 

/ |80 ua 

-- 

| 40 

~M 

. 

~ 

7LI 

fAinWte* 
MErCOENVIRONMENTAL 

oata mnpzooeoeou ou 06/10/2008 lo:ao:*y 

\ | oomwzo Name./ s Ppu cz CaIK aco uate' oo/zn/unnn nn,uo/a« ~ ' | oaca rizo C:\cX\cAzA\amzomo\nn-cna\os-znnoz.00z | 

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} aCz audreoo/ 1 oratoiri: z zu ~ ectM; ~ cmtector;oom-% | 

| | uriol , st / sCo cozonui/ Aa14,4mm, azn 1-12-01 sn uc zxx)e } 

~------------- ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 

oalibcetiom volumo nilotiou Poiuto uate atort otop Aroa »mjnot 

| 

-------------------------------------------------------------------- 

 mxtozual 1 I nnnn oHz 0.00 21.00 2000 

noowuueut aeport; oompoueuta rouom 

] nat oomnmueut Acoa ae1«ut cnu000tcatioa 

Timo aaom ppm o1 ~

~ 

------------------------------------------------------------- '|v 0/ 

| 4.22 ~~ iu mao~ zOan ~ an90 ~~zn~oa~ x yon 8 

1 . . , 

------------------------------------ 

rotaze 103, 843V92 2, 61016n2 4.968 

20 

1 ~ 

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08-203 E-72 
US20 

1ri 

MErCO ~~RC)Nl-lo~,'.L 

outa xepcoomaaed ou 0011 10/2000V 10:31`02 

_ 

| | aemnze umuuo: s pzIA cc (HK nTD oatm: 06/10/2008 on:«p/zo / 

oata rizm c:\or\DoA\amzomn\oo-u03\o*-1000z.00u ( 

| yetbou o:\oz\xo~zaoo\acL2a.moc | 

| Aoz Auuzeso: l eyatem: 1 zujoct#: 2 ooteotoz:oou-2 i 

} | Auozyot / Mno noluufu/ AS14,4mm' ezu 11-122-01 50 uuIDowp | 

oalibracium volomo Dilutiou eoiuta nato atort otop azea Dejent 

~ 

----_-_-----------------_---------------_---_----------------------- 

Eutecua1 l 1 *aOV 5Hz 0.00 zz.nn 301)n 

Cm^pouout ne.portz oouT~ ououto nouuu 

^ aot oom-pouoot A-roa Beight counoutratiou n >» TiirLe Namo mprft 

~ ---------_---_----------_-_-__---_-----------_------_---_--_ ~' ~ 

^ ~ o. 23 oI in x qoa l0O79O7 4 o 2578 9961 ~ .8u9 

/ ----------------------------_-_-_-_ ~ 

~ zotmzo 100790740 25789981 4'1028 

~ ~ 1~ 15 ~~ 

08-203 
\ 08-203 E-74 

| 

/ 

- 

/ 

- 

~ 

- 

\ / 

| MEzm ENVIRONMENTAL 

oata uepzoceeaed ou 06/10/2008 13:*4:49 

' ----------- ----------------------------------------------------- 

) | oample mame` 5 Pm-I cc cHa xTo/cc.V oate: 06/10/2008 12:53:110 / 

/ { oata riI: : o/\oo\oaca\ ~wznma\on- ~ ua\0s- ~ 000z.ozn | 

| method ` C:\nX\emcono\-H :Loa.mEr | 

} aoz audrasy: z oyatam: I zu1eot0: 13 oetootor:cc,11,1-2- | 

* ~ zo nz oo | ) ! ~ua~ra~ ` mos oozuu~~ ae~~ , mm, aco - - u~ ~oop 

calibratiou voluma oilutiou Poiuto note ntmrt a'Lop azea maject 

\ --------------------------------_-__-_----_---_----_----_-------- 

Eutocua1 1 z 5850 5ao 0.00 19.50 2000 

000pouout n*nott: cooponputo Fouud 

/ not compouout azee oeiout nouooutratiou 

~ riov~-mame poXft /0 

------------------------------------------------------------- 

\ 4.221 ol 1a maoH 105574ay0 25771160 5.000 

------------------------------------ 

~ 

zotalo 10557*590 2,5771160 5.000 

/ 30 

/ 20 

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| ~ 

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| 

^ 

~ ? 4 1 ~ ~

? 14 16 18 
20 

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30 

MET"o BNVIpIOI,]MFjNJTAL 

Data Reprocessed On 06/10120010 

SanTde Name: 5 PPM C.I. CHK STDICC.-V fiate.; 0611 ICY12, 008 13:12;4 -1, 

Data File ; 

Method ; C: \D7,\ME.THOD\Hc-L2A..IAET 

ACI I-ddress: 1 Sy-qteMi: I TnjeCt#: 14 - Deatecror. CDM- 2, 

Anaivst MCC, ColLmin ,AS14,4ffmn, STD 1-12-011 50 uL LOOP 

Calibration Volume Dilution Points Rate Stait Stm Area Reject 

--------------------------------------------------------------------- 

External- 1 1 5404 5Hz 0.00 17.77 21 1) ci 11; 

Canponent Reaort: Conponents Found 

Ret Component Area Height Coricentration 

Tiicte Niame 1- IrDift 

------------------------------------------------------------- 

4-92 Cl in 1,.TaC7H 1041196-2 0 25742317 4.981 

------------------------------------ 

Tritals 104119620 2 5 7 4 2-3 1 7, 419lo i 

lile; r, 6-1000l.Dl4 cpffvle: Fi PPr-I C-I CHK -TDICC-V 

6 8 10 1 14 16 

Wnule'-, 

08-203 E-75 
4 

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-2 

A 

-e+ 

-61 

ri 

Li 6 rr" 10 i 2 14 F, 

METCO EN-VIROYMENT-AL 

Data Reprocessed On 06/10/2008 !6:00:27 

Sample Narrte: I PPI-i CI CCIV Date: 06/10/2008 115 :— 

Data File- C:',.DY\DATA\,Ab!I--lqS\g8-203\06-10001.D21 

i'llethod, C * k UX*,,ME-TH0D\HCl ~ 2A. MET 

A-CI AAK, 're-"S. lystelfi ,I in3ect#: 2,1 Detector:CD14-2 

Analyst 1--A.CG Collmn: A314,4rfm, -IM 1-12-01 50 izL LCX:P 

vol"IrRe roilutio-ri Points Pp-te Start "tor) Area Reject 

-------------------------------------------------------------------- 

Externp-I 1 1 58.50 5Hz 0.00 19.50 21000 

Repor-11: 07-uporients Found 

P,et Compoi-ent A-rea Height Concent rat i-,:-.n 

Tircte Nwae PPIft 

------------------------------------------------------------- 

4.25 Cl in NaOH 18028664 4734751 0,992 

------------------------------------ 

1=~ tals 118 028 ,664 47-34781 Cl. 992 

File: Sample ,1 OPi-I CL CcV, 

08-203 E-76 
L 1 Lri 4 

"~ 

.~ 

:1 

1 

1-W,TCO ENVIRONMENTAL 

Data Rep-rocessed On 06/10/20010 16: 110:59 

~ampleName .: 10 PPM CL CCV Date; 

06' 

1 10/2008 16:13:14 

Data File C:\DY,\DATA\ " ANIONS\08-203\06-1000I.D22 

Method C:\DX\METHCD\HCZ2A.IiET 

I ACI Address: 1 SvsteNt: 1 Inlect#: 22 Detector: CUM-2 

I Analyst MVC G Coltunn.,AS14,ftffft, STD 11-121-01 50 uL LOOP 

Cali brat ion Vollmcie Di-lution Points Pp-te Start Stop Az- ea reeject 

-------------------------------------------------------------------- 

Externa'L 1 1 5.0 50 5Hz 0.00 19.50 20clio 

'--on-ponent Re~jcurt: Cewiponents Found 

Ret Corra-*nent A-rea Heigtit-,ConcentrRtion 

Tirrae Name PPIT, 

------------------------------------------------------------- 

4.25 Ci 'Ln NTa0H 2 1 S-'l -5 2 9 7 CS 51-2-05706 i0.008 

------------------------------------ 

Totals 2191521976 S 12- 0 5 -10 b iri. 008 

File. 06-10001.D22 Sarctple: 11) PPM CL C-m! 

70 

p 10 

50 

c 

313 

20 

1 

08-203 E-77 
METCO 

/ 

' 

nata meproneoaou ou 06/10/3008 16:33:56 

~~~ 

/ } aaople Namo/ 20 reu oz ocV ueto: 06/10/2,008 16;32:n7 ! 

\ | oata rilo o;\oo\cmzA\Amzmma\nn-zna\os-zonnz.00n | 

| Mathou c oa\mLPr000\ooL2a.moT | 

^ | acz auureas: z erstom: z zuioot0: o" ootontor:ocM-2 ( 

/ | auazrst ' woo colunm/ a314,4mm' szo sD uM Looe } 

nali~z~tiou voluum oizutiom goiuto 

-------------------------------------------------------------------- 

nate atmrt atom areo s~ eot 

| / outerooz z z 5387 5Hr 0.00 17.p6 oVoO 

ocmpoueut aaport; oompouputa rouuu °++°°° ~ ~+°+ ~+~ +°+ 

`| mot onupouont Axem Hoinht nouueutzatioo 

` zioe ayua 

------------------------------------------------------------- 

nPm 

~ 4 . 2e cz iu mauo ------------------------------------ 4 * 9* 53014 y/ 3 /xzx x i9 .5 5n 

rotalu 449*530, 14 973l82e8 19.55-n 

80 

US 

~ci 

40 

M 

~ 

~ 7 4 6 ~ 10 1 ~ 14 1 ~ 

~ 

— ~ 

08-203 
mF-Tc 

Data ooprooeaaod Vu 06/11/2008 07:41:517 

/ aamnzo mamo: us pP* oz ccn oatp: 06/10/2008 zo:on:z* | 

| cmta Fila o:\oz\cmz~\~wznma\n8-uon\on-znnnz.o ~ « | 

| m~tuou ~ C:\DYIIMETHCuD\HC-L2A.M—nT 

| aoz euureaa, z nyatom: z zujoot#: 214 uotentox: Ccm-o | 

| xualyut ; yoo oozomu: nazu,4mm' aro 1-12-01 on "z Lo^P | 

na-zibzmtiou voluoe uizution roiuta xate Start atnn Azea ua1ect 

______________________________________________________ 

oxtoruaz z 1 5850 5az 0.00 19.50 onoo 

comno-neot mepmzt: oompooeuta FCuuu 

net nonmoueut acea aoiobt nouoentzatiou 

zime maxe mvm 

------------------------------------------------------------- 

4.25 Cl iu Maoo 578068578 .11731, *9*4 25.0%z 

------------------------------------ 

zotazo o78062578 zz7az6-3o« z5.ouz 

160 

140 

120 

~~ 

~~ 

60 

40 

Lo 

~ 

~j 4 ~ ~ ~~ 17 14 16 1e 

'--- 

08-203 E-79 
YIETCo ENVILPOMMENIZUT 

oata xeproceoyao Vu 06/11/2008 07 ~ 42:35 

/ aanwlo mame: u nRM CL ca-K oco/co -V mate' 0611012008 17:zi`2I | 

/ Data -mize o;\ ~r\o~ox ~xo;zo~a\on- ~ oa\no-z000 ~ 'o~o | 

~ Me-thou c:\oz\aoza")o\acL2A.Moc | 

| _N-r xddroaa: 1 oyotem; I zuject#` 25 oot ec toz:ozI-1-2 ~ 

/ Auolrmt ' ecC- CoILomu' An14'4mm, STD 1-12-02 sV uzzmoP | 

calibzatiou volume o1zutiou poiuta nato otazt Ston xzem na ~ioct 

-------------------------------------------------------------------- 

Exterual z z snon oHz 0.00 19.50 2000 

nunp-ouout mapnzt: Coupououta ruuud 

net comnouent areu ooinbt couooutratiou 

zim* ma-ima 

------------------------------------------------------------- 

«.us Cl lu mams 10322,2970 2503944u 4.p:0 

------------------------------------ 

Totalm zo3, %u2e7n 25Va9o4c u.eoo 

rilo: 06-10001.o25 aomwzo; o pPm cI con ozu/Ccv 

U~ "~ 

20 

70 

0 

~ 7 4 6 8 1 ~ 1~ 14 16 18 

Minutes 

08-203 
METC0 E-N-VIRONMENTAJ, 

Data Reprocessed On 06/11/2008 011:43t2i 

Sariiple 14an7e: 5 PPM C.T, CHK STD/CCV Date: 06/10/2008 17;31=;12 

Data File C:1 , D,,(\E.!A.T.k\Al~ll'ONS\010-203\06-10001,D26 

Method C.\.r9 11METHOD 1XHC.L2A,Y1ET 

ACIAddresS: 1 System.: 1 !Djectff: 26 

Analvs;t MCG COILMin: A,0 14,4nvii, 3TD 1-112-01 50 LLT~ T,0OP 

---------- 

Calibration Volume Di-lution Points Rate Start Stop A-Y- ea Reject 

--------------------------------------------------------------------- 

External- 1 1 5850 5Hz 0.00 19.50 -2000 

Report: CoPqporients Found 

ReT Comonent Area Height Concentration 

Tii(ie Nafur-- pprIt 

------------------------------------------------------------- - 

4.21 5 Cl in J-,TaOH 1104168670 2457416.5 4,983 

------------------------------------ 

Totals 104168670 24574165 4,983 

File.: 06- 1000!.D26 Sample: S PPM (--L CHK STD/CC-V 

M 

20 

us10 

IT 

in 

1 -! -'4 1 f~ 

08-203 E-81 
,RJCCA CHEMICAL COMPANY I Arlington, TX 76012 

Pocomoke City, MD 21851 

Batesville, IN 47006 

~ ~ ^ Certificate of Analysis httP://www•riccachemical.com 

~ 

1-888-GO-RICCA 

Wstomerservice@dccachemical.com 

1Chloride Standard,l mL = 1 mg CI-, 1000 ppm CI- (0.0282 Normal) 

Lot Number: 1703163 Product Number: 1955 Expiration lTate: AUG 2008 Manufacture Date:3/12/2007 

Contains 

I Name CAS# Grade 

Sodium Chloride, NaCI 7647-14-5 ACS 

~ Water, Deionized, H20 7732-18-5 ACS, ASTM D 1193 (Type I), EP, USP 

est Name Assay Method Specification Result 

~

Appearance Clarity, Color, Odor Clear, colorless, odorless Passed Test 

Assay at 20°C (traceable to NIST Tttrimetric vs. Silver Nitrate (Potassium 1000 t I ppm CI 1000 ppm CI 

SRM 999) Chromate Indicator) 

~

pedflcation Reference Method Number 

Chloride Solution Stock (1.00 mL = 1.00 mg ASTM D 5542 

chloride) 

Chloride Solution, Stock (1000 mg/I,) ASTM D 512 C 

~

Standard Chloride Solution, 1000 mg/L APHA 4110 B 

Stock Chloride Solution APHA 4500-C1- E 

Sodium Chloride Calibration Standard (1 μg EPA (SW-846) 9023 

l C1-/μL) 

{ Sodium Chloride Calibration Standard (1 μg EPA (SW-846) 9021 

alolide Stock Solution (I.00 mL = 1.00 mg EPA (SW-846) 9056 

~

Cl-) 

Sodium Chloride, NaCI, stock standard EPA (SW-846) 9047 

solution 

Chloride Calibration Stock Solution (1,000 EPA (SW-846) 9212 1 mg/L CI-) 

J Chloride solution (1000 ppm) TAPPI T 700 om-93 

Chloride solution (1000 ppm) TAPPI T 699 om-87 

] Sodium Chloride Solution, 1 mL = 1 mg Cl- ASTM D 4458 

~ Chloride Stock Solution (1.00 mL = 1.00 mg ASTM D 4327 

' Cl-) 

Chloride Solution, Stock (1.00 mL = 1.00 mg ASTM D 5996 

1 Cl) 

,Volumetdc glassware complies with Class A tolerance requirements of ASTM E 288 and NIST Circular 434; it is calibrated before first use 

and recalibrated regularly in accordance with ASTM E 542 and NIST Procedure NBSIR 74-461. Balances are calibrated regularly with 

,Neights certified traceable to the NIST national mass standard. Thermometers and temperature probes are calibrated before first use and 

`ecalibrated regularly with a thermometer traceable to NIST standards. AII products are prepared according to master documents that 

assure manufacture according to validated methods. Batch records document raw material traceability and production and testing history 

for each lot manufactured. 

j

,helf Life (unopened container) 

,1Part Number Shelf Life 

1955-4 18 months 

f1955-8 18 months 

1Z

55-16 18 months 

orrtmended Storage: 15°C - 30°C (59°F - 86°F) 

i 

l~ 

Versiun: 1 

08-203 E-82 
( Joan Lutkenhaus 

) Director of Quality Assurance and Regulatory Affairs 

~ Tl#i:ertificate of Analysis is designed to comply with ISO Guide 31 "Reference Materials — Contents of Certificates and Labels." 

To determine manufacturing site using lot number, visit www.riccachemical.coMAboutUsllot.pdf. 

~ t 

Version: 1 

08-203 E-83 
1O 

~ 

6 

7 

~ 

oata aopr0000aed ou 06/10/2008 09:36:17 

| aumnz° mame/ zAa vgTBn ozAxJK oato; no/og/uonn oo:oo:i2 | 

| omta rile c-,\on\orTu\anzomo\ne-2oo\no-noOnz.o0 -, | 

| metuou C:\oo\uozmoo\o~~~ .woz | 

| Aoz edureaa: z oystam: z zujoot#: l oeteotor: Cou-2 | 

| x^alrat 14ce columu/ ASzo,omm,aTo 2-2z-05 zmAozo ! 

Caliucatiou voluove uilutioo poiuts nate atart atop szoa nejoct 

------------------------------------------------------------------- 

~ute~uaz z 1 4200 5ao 0.00 i-11.00 znno 

oQ1«p0Dout aeport: couipoueuta ouuuu 

not onmmuuout Acea aeioUt Cou000tratiou 

rinm manm znx« 

_____________________________________________________________ 

------------------------------------ 

rotmlo n n 0.000 

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oata aopcooesoe« ou 06/10/2008 09:36:28 

~ eamnlemame: zmo nmzEauzauvs oato/ 0*/00/2008 ne.ow/no / 

{ oota silo C:\oo\cmT~k\amzsN-R\08-203\06-09001.o03 | 

| yethou c:\no\moTowo\ac-T2.mor | 

| acz ALiureao: z onntem: z zu1eot#` o notector:ozM 2 \ 

| aoalrat : umo :ozumu aa14,4mm,ozn u-221-05 zNaczD | 

Cazibratiou volumo nizutiou poiuta neto ytmzt Stop arwa xejoot 

-__------------_---------_--_---__-_----_--------_-__-----------_- 

oxtecuaz z 1 4200 oHz o.no 14.00 2000 

oonmouout n*lDort; commououto rouum 

set Cormoueut »x-ea eoioht Couoeutrutiou 

Tiom okno xmi(L 

------------------------------------------------------------- 

------------------------------------ 

cotmla o n o.00n 

rize: 06-o90O1.o02 nampze ~ zaa vmzoa z-Ia14K 

08-203 E-85 
DIC;NEX SCHEDULE - C: \DY:\SCHE»;oiC%r-rD 

Ir1jr Sample ivarc)e MetPiod Data File Vol. Dil. int.3t,i. 

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3 H2%9 $LAATk: -tiC.R A \HC—LZ.MET .. ip6-09`3vl.DQ1 1 1 1 

1 4 H2SO4 BLAi~7F: -SGF: A \HCILZ,MET a,\06-0900l.D01 1 1 1 

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08-203 E-86 
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08-203 E-87 
MEFCO. 

APPENDIX F 

Plant Operational Data 

08-203 F-1 
Acid Circ Soft Water to Acid Caustic Circ 

June 4th, Scrubber A Stack Flow Rate Acid Section Strength Flow 

Time ACF gpm gpm % gpm 

1130-1238 2025000 398.58 96.66 7.96 2250.08 

1321-1432 2034000 398.58 96.80 7.88 2250.08 

1508-1616 2028000 398.58 . 96.89 7.84 2250.08 

Average 2029000 398.58 96.78 7.89 2250.08 

Acid Circ Soft Water to Acid Caustic Circ 

June 5th, Scrubber B Stack Flow Rate Acid Section Strength Flow 

Time ACF gpm gpm % gpm 

1005-1115 2016000 . 394.95 94.18 7.70 2597.66 

1143-1253 1975000 394.95 94.33 7.70 2597.66 

1315-1420 2003000 394.95 94.39 8.43 2597.66 

Average 1998000 394.95 94.30 7.94 2597.66 

vcM 

HCI Feed Production 

Average pH Rate HRA Rates 

pH Ib/hr mmlbs/day 

7.95 3588.56 

8.04 3493.27 

8.04 3347.43 

8.01 3476.42 6.97 

vCM 

HCI Feed Production 

Average pH Rate HRA Rates 

pH Ib/hr mmlbs/day 

7.99 2892.27 

7.96 3338.38 

7.82 3578.62 

7.92 3269.76 7.00 

F-2 08-203 
.~i. .• 

APPENDIX G 

TCEQ Permit 

08-203 G-1 
~ Kathleen Hartnett White, Chairman 

~ Larry R. Soward, Commissioner 

H. S. Buddy Garcia, Commissioner 

~ Glenn Shankle, Executive Director 

t>

'r

:;- 

\. _. 

~ 

\ _ .. 

TEXAS COMMISSION ON ENVIRONMENTAL QUALITY 

] . Protecting Texas by Reducing and Preuenting Pollution 

} August 27, 2007 

i 

~ 

~ Mr. Scott Willis 

Assistant Plant Manager 

Vinyl Chloride Monomer Production Plants 

~ Oxy Vinyls, L.P. 

2400 Miller Cut Off Road 

La Porte, Texas 77571 

Re: Permit Amendment 

Permit Numbers: 3855B and PSD-TX-876 

Vinyl Chloride Monomer Production Unit 

La Porte, Harris County 

Regulated Entity Number: RN100224674 

Customer Reference Number: CN600129126 

Account Number: HG-0193-B 

Dear Mr. Willis: 

This is in response to your letter received May 3, 2007, and your Form PI-1 (General Application 

for Air Preconstruction Permits and Amendments) concerning the proposed amendment to Permit 

Numbers 3855B and PSD-TX-876. We understand that you propose to incorporate into these 

permits several existing permit by rule (PBR) registrations, increase the hourly emission rates 

for cracking furnaces and incinerators, and perform several administrative changes as 

represented in your permit application. Also, this will acknowledge that your application for the 

above-referenced amendment is technically complete as of May 24 ;2007. 

With this amendment, the following PBR registrations will be incorporated into this permit and their 

separate registrations will be voided: 

j PBR Nos. 54263, 55409, 79212, 79379, 79479, and 80249 

~ ~ 

~ 

As indicated in Title 30 Texas Administrative Code § 116.116(b) and based on our review, Permit 

Numbers 3855B and PSD-TX-876 are hereby amended. This information will be incorporated into 

~ the existing permit file. Enclosed are revised special conditions pages and a maximum 

allowable emission rates tabie to replace those currently attached to your permit. We appreciate 

~ your careful review of the special conditions of the permit and assuring that all reo ; .::irements are 

f consistently met. 

P.O. Box 13087 ® Austin, Texas 78711-3087 ® 512-239-1000 ® Internet address: www.tceq.state.tx.us 

 inir.!ru ,,,. . •.:ICd ~ •,per usie:; s.?•-7-,;y;:d inL. 

 G-2 08-203 
.~ 

Mr. Scott Willis 

~ Page 2 

~ August 27, 2007 

~ Re: Permit Numbers 3855B and PSD-TX-876 

You may file a motion to overturn with the Chief Cl'erk. A motion to overturn is a request for the 

commission to review the Texas Commission on Environmental Quality (TCEQ) Executive 

Director's approval of the application. Any motion must explain why the commission should review 

the TCEQ Executive Director's action. 

A motion to overturn must be received by the Chief Clerk within 23 days after the date of this letter. 

An original and 11 copies of a motion must be filed with the Chief Clerk in person or by rnail. The 

Chief Clerk's mailing address is Office of the Chief Clerk (MC-105), Texas Conunission on 

Environrnental Quality, P.O. Box 13087, Austin, Texas 78711-3087. On the same day the motion 

is transmitted to the Chief Clerk, please provide copies to Mr. Robert Martinez, Director, 

Environmental Law Division (MC-173), and Mr. Blas J. Coy, Jr., Public Interest Counsel (IvIC-103), 

both at the same TCEQ address above. If a motion is not acted on by the connnission within 

45 days affter the date of this letter, then the motion shall be deemed overruled. 

~ Thank you for your cooperation and interest in air pollution control. Ifyou need further information 

or have any questions, please contact Mr. Palinda de Silva at (512) 239-1464 or write to the Texas 

~ Commission on Environmental Quality, Office of Permitting; Remediation, and Registration, Air 

~ Permits Division (MC-163), P.O. Box 13087, Austin, Texas 78711-3087. 

, 

This action is taken under authority delegated by the Executive Director of the TCEQ 

Sincerely, 

Richard A. Hyde, P.E., 

fffD~~~ 

ir~~ector \

Air Permits Division 

Office of Permitting, Remediation, and Registration 

Texas Commission on Environmental Quality 

RAH/PDS/ssl 

Enclosures 

cc: Mr. Stuart L. Keil, P.E., Keil Environmental, Austin 

Director, PolIution Control Department, Harris County Public Health and 

Environmental Services, Pasadena 

Air Section Manager, Region 12 - Houston 

Air Permits Section Chief, New Source Review, Section (6PD-R), U.I ,Environmental 

Protection Agency, Region 6, Dallas 

Project Number: 129133 

G-3 08-203 
TEXAS COMMISSION ON ENVIRONMENTAL QUALITY 

► ~ , AIR QUALITY PERMIT - GENERAL CONDITIONS ` 

(E ' ? ~ 

AND PERTINENT RULES EFFECTIVE FOR PERMITS ISSUED ~ 

OR AMENDED ON OR AFTER AUGUST 16, 1994 TCEO 

Facilities covered by this permit shall be constructed and operated as specified in the application for the permit. All representations regarding construction plans and 

operation procedures contained in the permit application shall be conditions upon which the permit is issued. Variations from these representations shall be unlawful unless 

the permit holder first makes application to the Texas Commission on Environmental Quality (commission) Executive Director to amend this permit in that regard and such 

amendment is approved. [Title 30 Texas Administrative Code § 116.116 (30 TAC § 116.116)] 

Voiding of Permit. A pennit or permit amendment is automatically void if the holder fails to begin construction within 18 months of the date of issuance, discontinues 

construetion for more than 18 months prior to completion, or fails to complete construction within a reasonable time. Upon request, the executive director may grant an 

18-month extension. Before the extension is granted the permit may be subject to revision based on best available control technology, lowest achievable emission rate, and 

netting or offsets as applicable. One additional extension of up to 18 months may be granted if the permit holder demonstrates that emissions from the facility wil! comply 

with all rules and regulations of the commission, the intent of the Texas Clean Air Act (TCAA), including protection of tlte public's health and physical property; and 

(b)(1)the permit holder is a party to litigation not of the permit holder's initiation regarding the issuance of the permit; or (b)(2) the permit holder has spent, or committed to 

spend, at Ieastl0% of the estimated total cost of the project up to a maximum of $5 million. A permit holder granted an extension urider subsection (b)(1) of this section may 

receive one subsequent extension if the pennit holder meets the conditions of subsection (b)(2) of this section. [30 TAC § 116.120(a), (b) and (c)] 

J. Construction Progress. Start of construction, construction interruptions exceeding 45 days, and completion of construction shall be reported to the appropriate regional 

office of the commission not later than 15 working days after occurrence of the event. [30 TAC § 116.115(b)(2)(A)] 

Start-up Noti6cation. The appropriate air program regional office shall be notified prior to the commencement of operadons of the facilities authorized by the permit in 

such a manner that a representative of the commission may be present. The permit holder shall provide a separate notification for the commencement of operations for each 

unit of phased construction, which may involve a series of units commencing operations at different times. Prior to operation of the facilities authorized by the permit, the 

permit holder shall identify to the Office of Permitting, Remediation, and Registration the source or sources of allowances to be utilized for compliance with Chapter 101, 

Subchapter H, Division 3 of this title (relating to Mass Emissions Cap and Trade Program). [30 TAC § 116.115(b)(2)(B)] 

Sampling Requirements. If sampling is required, the perniit holder shall contact the commission's Office of Compliance and Enforcement prior to sampling to obtain the 

proper data forms and procedures. All sampling and testing procedures must be approved by the executive director and coordinated with the regional representatives of the 

commission. The permit holder is also responsible for providing sampling facilities and conducting the sampling operations or contracting with an independent sampling 

consultant. [30 TAC § 116.115(b)(2)(C)] 

Equivalency of Methods. The permit holder must demonstrate or otherwise justify the equivalency of emission control methods, sampling or other emission testing 

methods, and monitoring methods proposed as altematives to methods indicated in the conditions of the permit. Alternative methods shall be applied for in writing aild must 

be reviewed and approved by the executive director prior to their use in fulfilling any requirements of the permit. [30 TAC § 116.115(b)(2)(D)] 

Recordkeeping. The permit holder shall maintain a copy of the permit along with records containing the information and data sufficient to demonstrate compliance with the 

permit, including production records and operating hours; keep all required records in a file at the plant site. lf, however, the facility normally operates unattended, records 

shall be maintained at the nearest staffed location within Texas specified in the application; make the records available at the request of personnel from the commission or 

any air pollution control program having jurisdiction; comply with any additional recordkeeping requirements specified in special conditions attached to the permit; and 

retain information in the file for at least two years following the date that the infomiation or data is obtained. [30 TAC § 116.115(b)(2)(E)] 

8. Maximum Allowable Emission Rates. The total emissions of air contaminants from any of the sources of emissions must not exceed the values stated on the table attached 

, to the permit entitled "Emission Sources - Maximum Allowable Emission Rates." [30 TAC § 116.115(b)(2)(F)] 

j Maintenance of Emission Control. The permitted facilities shall not be operated unless all air pollution emission capture and abatement equipment is maintained in good 

working order and operating properly during normal facility operations. The permit holder shall provide notification for upsets and maintenance in accordance with 

§§ 101.201, 101.211, and 101.221 of this title (relating to Emissions Event Reporting and Recordkeeping Requirements; Scheduled Maintenance, Startup and Shutdown 

~ Reporting and Recordkeeping Requirements; and Operational Requirements). [30 TAC § I 16.1 15(b)(2xG)] 

0. Compliance with Rules. Acceptance of a permit by an applicant constitutes an acknowledgment and agreement that the permit holder will comply with all mles, 

regulations, and orders of the commission issued in conformity with the TCAA and the conditions precedent to the granting of the permit. If more than one state or federal 

~ rule or regulation or permit condition are applicable, the most stringent limit or condition shall govem and be the standard by which compliance shall be demonstrated. 

Acceptance includes consent to thc entrance of commission employees and agents into the permitfed premises at reasonable times to investigate conditions relating to the 

~ emission or concentration of air contaminants, including compliance with the permit. [30 TAC § 116. kl5(b)(2)(H)] 

11, This pennit may be appealed pursuant to 30 TAC § 50.139. 

}2. This perniit may not be transferred, assigned, or conveyed by the holder except as provided by rule. [30 TAC § 116.110(e)] 

13. There may be additional special conditions attached to a permit upon issuance or modification of the permit. Such conditions in a pemzit may be more restrictive than the 

requirements of Title 30 of the Texas Administrative Code. [30 TAC § 116.115(c)] 

11. Emissions from this facility must not cause or contribute to a condition of "air pollution" as defined in TCAA § 382.003(3) or violate TCAA § 382.085, as codified in the 

Texas Health and Safety Code. If the executive director determines that such a condition or violation occurs, the holder shall implement additional abatement measures as 

necessary to control or prevent the condition or violation. 

Rev. July 24, 2003 

G-4 08-203 
EMISSION STANDARDS 

1. This permit authorizes emissions only frorn those points listed in the attached table entitled 

"Emission Sources - Maximum Aliowable Emission Rates," and the facilities covered by this 

permit are authorized to emit subject to the emission rate limits on that table and other 

operating conditions specified in this permit. (8/07) 

FEDERAL PROGRAM APPLICABILITY 

2. These facilities shall comply with all applicable requirements of the U.S. Environmental 

j Protection Agency (EPA) regulations on National Emission Standards for Hazardous Air 

1 Pollutants (NESHAPS) promulgated for Benzene Waste Operations in Title 40 Code of 

Federal Regulations (40 CFR) Part 61, Subparts A and FF. (8/07) 

~ 3. These facilities shall comply -with all applicable requirements of the EPA regulations for 

NESHAPS for the Synthetic Organic Chemical Manufacturing Industry (SOCMI), for 

~ SOCMI Process Vents, Storage Vessels, Transfer Operations, and Wastewater, for 

SOCMI Equipment Leaks, and for Industrial, Conumercial and Institutional Boilers and 

Process Heaters in 40 CFR Part 63, Subparts A, F, G, and H. (8/07) 

ETHYLENE DICHLORIDE (EDC) PRODUCTION LIMITATIONS AND REQUIREMENTS 

4. The fuel fired in each combustion device at this facility is limited to pipeline-quality, sweet 

natural gas. Use of any other fuel will require an amendment to the permit. (8/07) 

EMISSION STANDARDS AND OI'ERATIONAL LIMITATIONS 

5. In the event that the permit holder loses the service ofboth incinerators, the permit holder shall 

attempt to restore the operation of the incinerators as soon as is practicable. In the event that 

one or both of the incinerators cannot be restarted in a timely manner, operating rates in the 

vinyl chloride producing plant (including the oxyhydr©chlorination EDC facility) shall be 

reduced until the plant can be safely shutdown. The rate of reduction in production rates shall 

be controlled to minimize the total quantity of emissions. (9/98) 

6. Polychlorinated biphenyls (PCBs), other than PCBs incidentally produced during the 

~ EDC/vinyl chloride monomer (VCM) manufacturing proces."t, shall not be handled at this 

facility. Records of incidental PCB production will be maintained in accordance with 40 CFR 

Part 761. 

G-5 08-203 
7. Oxy Vinyls, L.P., shall operate the incinerators in a manner which will prevent visible fu.gitive 

emissions from the incinerators before the stack. 

DISASTER PREVENTION AND MITIGATION 

8. The holder of this permit shall install, operate, and maintain monitoring, surveillance, and 

alarm systems for detection of and notification of chlorine (Cl Z) releases. Chlorine 

concentrations shall be continuously monitored by a sufficient number of ambient monitors 

in the area of the C1 2facilities. The detection level for the Cl Zmonitors shall be 1 part per 

million by volurrie (ppmv). The monitors shall be checked monthly to ensure the proper 

function of sensors and alarms. Corrective action`shall be taken to minimize C1 2leaks 

whenever ClZconcentrations of 1 ppmv are detected. 

9. The holder of this permit shall maintain and operate a release plume modeling program that 

Oxy Vinyls' La Porte Plant personnel will use to initiate the Chlorine Contingency Plan 

(dated December 20, 1995). The contingency plan shall be implemented immediately 

following an accidental release of a potentially hazardous volume of C1 2 . The contingency 

plan shall include (but is not limited to) a call list of company personnel and local public 

safety personnel and a list of evacuation routes and procedures for notifying the general public 

that an emergency exists and for requesting assistance to evacuate the public from the area of 

exposure. A copy of the contingency plan shall be retained at the plant, and all operating 

personnel shall be thoroughly trained for implementing the procedures of this plan. (8/07) 

10. The permit holder shall observe applicable safety guidelines, to include set brakes and 

chocked wheels, regarding the location and protection from collision of standing railcars 

while they are situated on loading side tracks. 

11. Chlorine storage tanks will be protected from damage by location away from traffic within the 

protected perimeter of the permitted facility. 

12. Immediately upon detection of a leak within the area of facility operations, company personnel 

shall take the following actions toward repairing the le4k: 

A. The operator on duty shall isolate the leak. 

B. Unloading operatioins shall shut down for the affected car or cars. 

G-6 08-203 
-I 

SPECIAL CONDITIONS 

~ Permit Numbers 3855B and PSD-TX-876 

Page 3 

C. Leaking equipment shall be repaired or replaced and shall not be returned to service 

before being repaired or replaced. 

Unloading operations shall resume only after the leak has been repaired. 

13. All personnel involved in C12 transfer operations at the permitted facility shall be 

properly trained in these operations, in the recognition of C1 2leaks, and in all routine and 

emergency response procedures to be enacted in the event of minor and emergency releases. 

New employees shall be trained as part of their initial orientation, and all employees shall be 

retrained at least once per year. 

14. Automatic and manual process shutdown capability shall be maintained in the C1 2 1oading area. 

15. A visual inspection of the condition of all transfer hoses used in the transfer of C1 2to or from 

railcars shall be conducted by qualified Oxy Vinyls personnel and found to be serviceable 

before each loading. At least annually, the transfer hoses shall either be replaced or pass a 

hydro test at two times maximum allowable working pressure. 

16. Maintenance operations which require lifting of heavy equipment over the C1 2 transfer lines 

between processing areas, header areas, and storage areas are permitted only when no other 

equipment transfer pathway is practically available. Under these circumstances, maintenance 

operations shall be controlled by a work permit approved by plant management. (8/07) 

17. Inspections for integrity of flange gaskets at the surge tank shall be conducted at least 

semiannually. 

~ 18. All plant personnel assigned to C1 2operations shall participate in continuing training in 

Chlorine Institute Safety Guidelines (Chlorine Transfer Operations), to be conducted no less 

frequently than biannually; new/transferred personnel shall complete all training required for 

their specific assignments prior to assumption of their duties in C1 2 operations. 

19. Capability for application of water spray and foam to a C1 2release shall be available to the C1 2 

operations area. 6 

CARBON COMPOUND WASTE GAS.STREAMS 

20. The incinerators' firebox exit temperatures shall be continuously monitored and recorded to 

ensure a minimum 99.9 percent destruction efficiency for volatile organic compounds (VOC). 

The incinerator firebox exit temperatures shall be maintained at not less than 1560°F. 

G-7 08-203 
21. Incinerators A and B shall be equipped with flue gas scrubbers in place to control hydrogen 

~ chloride (HCl) and C12emissions. The caustic scrubbing solution's circulation rate shall be 

no less than 200 gallons per minute. The circulation rate of the caustic scrubbing solution 

shall be continuously monitored and recorded. (9/98) 

~ 22. The scrubbing solution pH for the incinerator caustic scrubbers shall be continuously 

monitored and recorded. The pH of the caustic scrubbing solution shall be maintained at 

~ greater than 8.0 (hourly average in the scrubber effluent) or greater than the pH determined 

by testing (according to Special Condition No. 27) that demonstrates compliance with the 

requirements of this permit. (8/07) 

23. Except as may be provided for in the special conditions of this permit, all waste gas from point 

.sources containing VOC and/or other organic compounds and hydrocarbon and/or 

hydrocarbon derivatives, excluding carbon dioxide, shall be routed to an incinerator/scrubber 

system. The incinerator/scrLibber system shall operate with no less than 99.9 percent 

efficiency in disposing of the carbon compounds captured by the collection system. The waste 

gas streams shall include process vents, analyzer vents, steam jet exhausts, start-up and 

shutdown related em`issions or purges, blowdowns, or other system emissions of waste gas. 

Storage tank vents, cooling tower exhaust, and process fugitive emissions are excluded from 

this requirement. Any other exception to this condition requires prior review and approval of 

the Texas Commission on Environmental Quality (TCEQ) Executive Director, and such 

exceptions may be subject to strict monitoring requirements. 

~ 24. The EDC reactor shutdown purge stream and relief valves (1) monitored in accordance with 

Special Condition No. 29 or (2) equipped with a rupture disc upstream are exempt from the 

~ requirements of Special Condition No. 23. A disc failure detection device shall notify 

4 operating personnel of a disc failure. All leaking discs shall be replaced at the earliest 

opportunity but no later than the next process shutdown. 

25. Within 60 days after start of operation of the fifth cracking furnace, and with the exception 

of maintenance, start-up, and shutdown (MSS) operations authorized in Special Condition 

No. 33, carbon monoxide (CO) and C12 concentrations in each of the incinerator stacks shall 

not exceed 100 and 50 ppmv, dry, no excess air (hourly average), respectively. (8/07) 

CONTINUOUS DETERMINATION OF COMPLIANCE . (8/07) 

26. The permit holder shall install, calibrate, an' maintain a continuous emission monitoring 

system (CEMS) to measure and record the in-stack concentration of CO from each incinerator. 

G-8 08-203 
SPECIAL CONDITIONS 

~ Permit Numbers 3855B and PSD-TX-876 

Page 5 

~ A. The CEMS shall meet the desiim and erformance s ecifications, pass the field tests, and p p 

meet the installation requirements and the data analysis and reporting requirements 

, specified in the applicable Performance Specification Nos. 1 through 9, 40 CFR Part 60, 

Appendix B. If there are no applicable performance specifications in 40 CFR Part 60, 

~ Appendix B, contact the TCEQ Office of Permitting, Remediation, and Registration, Air 

Permits Division for requirements to be met. 

B. Section 1 below applies to sources subject to the quality-assurance requirements of 

40 CFR Part 60, Appendix F; Section 2 applies to all other sources: 

(1) The permit holder shall assure that the CEMS meets the applicable quality- 

~ assurance requirements specified in 40 CFR Part 60, Appendix F, Procedure 1. 

Relative accuracy exceedances, as specified in 40 CFR Part 60, Appendix F, § 5.2.3 

and any CEMS downtime shall be reported to the appropriate TCEQ Regional 

~ Manager, and necessary corrective action shall be taken. Supplemental stack 

concentration measurements may be required at the discretion of the appropriate 

, TCEQ Regional Manager. 

' (2) The system shall be zeroed and spanned daily, and corrective action taken when the 

24-hour span drift exceeds two times the amounts specified in the applicable 

~ Performance Specification Nos. 1 through-9, 40 CFR Part 60, Appendix B, or as 

specified by the TCEQ if not specified in Appendix B. Zero and span is not 

required on weekends and plant holidays if instrument technicians are not normally 

~ scheduled on those days. 

Each monitot shall be quality-assured at least quarterly using Cylinder Gas Audits 

(CGA) in accordance with 40 CFR Part 60, Appendix F, Procedure 1, Section 5.1.2, 

with the following exception: a relative accuracy test audit (RATA) is not required 

once every four quarters (i.e., four successive quarterly CGA may be conducted). 

An equivalent quality-assurance method approved by the TCEQ may also be used. 

Successive quarterly audits shall occur no closer than two months. 

All CGA exceedances of +15 percent accuracy indicate that the CEMS is out of 

control. 

(3) The requirements of 40 CFR 60, Appendix F apply only to those sources for which 

a New Source Performance Standards (NSPS) subpart specifically requires both a 

continuous monitoring system and that the continuous monitoring system be used 

to demonstrate compliance with emission limits on a continuous basis. 

G-9 08-203 
SPECIAL CONDITIONS 

Permit Numbers 3855B and PSD-TX-876 

Page 6 

C. The monitoring data shall be reduced to one-hour average concentrations at least once 

every day, using a minimum of four equally-spaced data points from each one-hour 

period. The individual average concentrations shall be reduced to units of pounds per 

hour dry at least once every week as follows: 

The measured one-hour average concentration from the CEMS shall be multiplied by the 

exhaust flow rate as measured by an annubar to determine the hourly emission rate. 

The flow measurement monitoring device shall be installed and calibrated at a frequency 

in accordance with the manufacturer's specifications or at least annually, whichever is 

more frequent. 

.D. All monitoring data and quality-assurance data shall be maintained by the source. The 

data from the CEMS may, at the discretion of the TCEQ, be used to determine 

compliance with tlie conditions of this permit. 

1 E. The appropriate TCEQ Regional Office shall be notified at least 30 days prior to any 

I

required RATA in order to provide them the opportunity to observe the testing. 

F. Quality-assured (or valid) data must be generated when the incinerator is operating except 

during the performance of a daily zero and span check. Loss of valid data due to periods 

of monitor break down, out-of-control operation (producing inaccurate data), repair, 

maintenance, or calibration may be exempted provided it does not exceed 5 percent of the 

time (in minutes) that the incinerator operated over the previous rolling 12-month period. 

The measurements missed shall be estimated using engineering judgement and the 

methods used recorded. Options to increase system reliability to an acceptable value, 

including a redundant CEMS, may be required by the TCEQ Regional Manager. 

INITIAL DETERMINATION OF COMPLIANCE (8/07) 

27. The permit holder shall perform stack sampling and other testing as required to establish the 

actual pattern and quantities of air contaminants being ejnitted into the atrnosphere from the 

Incinerator A and B Scrubbers to demonstrate compliance with the maximum allowable 

~ emission rates table (MAERT) and Special Condition No. 25. 

The permit holder is responsible for providing sampling and testing facilities and conducting 

~ the sampling and testing operations at'_. - ~ s expense. Sampling shall be conducted in accordance 

with the appropriate procedures of the TCEQ Sampling Procedures Manual and the EPA 

reference methods. 

-, 

I 

G-10 08-203 
~ SPECIAL CONDITIONS 

Permit Numbers 3855B and PSD-TX-876 

~ Page 7 

~ Requests to waive testing for any pollutant specified in this condition shall be submitted to the 

TCEQ Office of Permitting, Remediation, and Registration, Air Permits Division. Test 

! waivers and alternate/equivalent procedure proposals for 40 CFR Part 60 testing which must 

f have EPA approval shall be submitted to the TCEQ Office of Compliance and Enforcement 

(OCE), Compliance Support Division. 

A. The appropriate TCEQ Regional Office shall be notified not less than 45 days prior to 

sampling. 

The notice shall include: 

~ (1) Proposed date for pretest meeting. 

(2) Date sampling will occur. 

(3) Name of firm conducting sampling. 

i (4) Type of sampling equipment to be used. 

~ (5) Method or procedure to be used in sampling. 

~ The purpose of the pretest meeting is to review the necessary sampling and testing 

procedures, to provide the proper data forms for recording pertinent data, and to review 

the format procedures for the test reports. The TCEQ Regional Director or the TCEQ 

OCE, Compliance Support Division must approve any deviation from specified sampling 

~ procedures. 

B. Air contaminants emitted from the incinerator scrubbers to be tested for include (but are 

not limited to) total VOC, EDC, VCM, nitrogen oxides, CO, HCl, and C1 2. 

C. Sampling shall occur within 60 days after achieving the maximum operating rate, but no 

later than 180 days.after initial start-up of the facilities and at such other times as may be 

required by the TCEQ Executive Director. Requests for additional time to perform 

sampling shall be submitted to the appropriate TCEQ Regional Office. 

D. The facility being sampled shall operate at maximum VCM production rates during stack 

emission testing ofthe incinerator scrubbers. The EDC cracking furnace subject to stack 

testing shall operate at the respective maxim,um heat input capacities. These 

conditions/parameters and any other primary operating parameters that affect the emission 

rate shall be monitored and recorded during the stack test. Any additional parameters 

shall be determined at the pretest meeting and shall be stated in the sampling report. 

Permit conditions and parameter limits may be waived during stack testing performed 

under this condition if ti_.; proposed condition/parameter range is identified in the test 

notice specified in paragraph A and accepted by the TCEQ Regional Office. Permit 

allowable emissions and emission control requirements are not waived and still apply 

during stack testing periods. 

G-11 08-203 
.~ 

~ 3 

SPECIAL CONDITIONS 

~ Permit Numbers 3855B and PSD-TX-876 

~ Page 8 

During subsequent operations, if the production rate or the maximum heat input is greater 

~ than that recorded during the test period, stack sampling shall be performed at the new 

operating conditions within 120 days. This sampling may be waived by the TCEQ Air 

Section Manager for the region. 

j E. Copies of the final sampling report shall be forwarded to the offices below within 60 days 

after sampling is completed. Sampling reports shall comply with the attached provisions i ~ entitled "Chapter 14, Contents of Sampling Reports" of the TCEQ Sampling Procedures 

Manual. The reports shall be distributed as follows: 

~ One copy to the appropriate TCEQ Regional Office. 

One copy to each local air pollution control program. 

One copy to the TCEQ OCE, Compliance Support Division, Austin. 

28. The initial stack emission testing for the fifth and sixth cracking furnaces and the incinerator 

scrubbers required by Special Condition No. 27 of Permit No. 385513 as renewed on 

October 6, 1997 was conducted on May 20 through 24, 1996 and March 11 through 13,1997 

(incinerator scrubbers only). Additional stack emission testing of the fifth and sixth cracking 

furnaces performed in accordance with the requirements of Special Condition No. 27 may be 

required in the future at the discretion of the TCEQ. (8/07) 

FUGITIVE EMISSION LEAK DETECTION AND REPAIR PROGRAMS 

Piping, Valves, Connectors, Pumps, and Compressors in VOC Service - Intensive Directed 

Maintenance - 28MID 

29. Except as may be provided for in the special conditions of this permit, the following 

requirements apply to the above-referenced equipment. (9/98) 

A. These conditions shall not apply (1) where the VOC has an aggregate partial pressure or 

vapor pressure of less than 0.044 psia at 68°F or (2) where the operating pressure is at 

least 5 kilopascals .(0.725 psi) below ambient presqure. Equipment excluded from this 

condition shall be identified in a list to be made available upon request. 

B. Construction of new and reworked piping, valves, pump systems, and compressor systems 

shall conform to applicable American National Sfandards Institute, American Petroleum 

Institute, American Society of Mechanical Engineers, or equivalent codes. 

G-12 08-203 
~ T 

~ 

SPECIAL CONDITIONS 

~ Penmit Numbers 3855B and PSD-TX-876 

Page 9 

C. New and reworked underground process pipelines shall contain no buried valves such that 

fugitive emission monitoring is rendered impractical. 

D. To the extent that good engineering practice will permit, new and reworked valves and 

piping connections shall be so located to be reasonably accessible for leak-checking 

during plant operation. Non-accessible valves, as defined by 30 TAC Chapter 115 shall 

be identified in a list to be made available upon request. 

~ E. New and reworked piping connections shall be welded or flanged. Screwed connections 

are permissible only on piping smaller than two-inch diameter. No later than the next 

scheduled quarterly monitoriing after initial installation or replacement, all new or 

reworked connections shall be gas-tested or hydraulically-tested at no less than normal 

operating pressure and adjustments made as necessary to obtain leak-free performance. 

~ Connectors shall be inspected by visual, audible, and/or olfactory means at least weekly 

I, by operating personnel walk-through. 

~ Each open-ended valve ar line shall be equipped with a cap, blind flange, plug,.or a 

~ second valve. Except during sampling, the second valve shall be closed. 

~ F. Accessible valves shall be monitored by leak-checking for fugitive emissions at least 

quarterly using an approved gas analyzer with a directed maintenance program. 

Sealless/leakless valves (including, but not limited to, welded bonnet bellows and 

diaphragm valves) and relief valves equipped with a rupture disc upstream or venting to 

a control device are not required to be monitored. For valves equipped with rupture discs, 

a pressure-sensing device .shall be installed between the relief valve and rupture disc to 

~ monitor disc integrity. All leaking discs shall be replaced at the earliest opportunity but 

~ no later than the next process shutdown. 

An approved gas analyzer shall conform to requireinents listed in 40 CFR § 60.485(a)-(b). 

A directed maintenance program shall consist of the repair and maintenance of 

1 components assisted simultaneously by the use of an approved gas analyzer such that a 

minimum concentration of leaking VOC is oblained for each component being 

maintained. Replaced components shall be re-monitored within 15 days of being placed 

back into VOC service. 

I 

l 

G-13 08-203 
~ _: _,... _ ..... ..; 

SPECIAL CONDITIONS 

Permit Numbers 3855B and PSD-TX-876 

Page 10 

G. All new and replacement pumps and compressors shall be equipped with a shaft 

sealing system that prevents or detects emissions of VOC from the seal. These seal 

systems need not be monitored and may include (but are not limited to) dual pump seals 

with barrier fluid at higher pressure than process pressure, seals degassing to vent control 

systerris kept in good working order, or seals equipped with an automatic seal failure 

detection and alarm system. Submerged pumps or sealless pumps (including, but not 

limited to, diaphragm, canned, or magnetic-driven pumps) may be used to satisfy the 

requirements of this condition and need not be monitored. 

All other pump and compressor seals emitting VOC shall be monitored with an 

approved gas analyzer at least quarterly. 

H. Damaged or leaking valves, connectors, compressor seals, and pump seals found 

to be emitting VOC in excess of 500 ppmv or found by visual inspection to 

be leaking (e.g., dripping process fluids) shall be tagged and replaced or 

repaired. Every reasonable effort shall be made to repair a leaking component, as 

specified in this paragraph, within 15 days after the leak is found. If the repair of a 

component would require a unit shutdown, the repair may be delayed until the 

next scheduled shutdown. All leaking components which cannot be repaired until 

a scheduled shutdown shall be identified for such repair by tagging. The 

TCEQ Executive Director, at his discretion, may require early unit shutdown or 

other appropriate action based on the number and severity of tagged leaks awaiting 

shutdown. 

I. In lieu of the monitoring frequency specified in paragraph F, valves in gas and light 

liquid service may be monitored on a semiannual basis if the percent of valves leaking 

for two consecutive quarterly monitoring periods is less than 0.5 percent. 

Valves in gas and light liquid service may be monitored on an annual basis if the percent 

of valves leaking for two consecutive semiannual monitoring periods is less than 

0.5 percent. 

If the percent of valves leaking for any semiannual or annual monitoring period is 

0.5 percent or greater, the facility shall revertoto quarterly monitoring until the 

facility again qualifies for the alternative monitoring schedules previously outlined in 

this paragraph. 

I 

G-14 08-203 
~ SPECIAL CONDITIONS 

~ Permit Numbers 3855B and PSD-TX-876 

Page 11 

• ~~ 

J. The percent of valves leaking used in paragraph I shall be determined using the following 

formula: 

~ V + V L s) x100=Vp 

VT 

~ Where: 

VL = the number of valves found leaking by the end of the monitoring 

period, either by Method 21 or sight, sound, and smell. 

VS= the number of valves for which repair has been delayed and are 

listed on the facility shutdown log. 

VT= the total number of valves in the facility subject to the monitoring 

requirements, as of the last day of the monitoring period, not 

including non-accessible and unsafe-to-monitor valves. 

VP= the percentage of leaking valves for the monitoring period. 

1 K. The results of the required fugitive instrument monitoring and maintenance program shall 

~ be made available to the TCEQ Executive Director or his designated representative upon 

request. Records shall indicate appropriate dates, test methods, instrument readings, 

~ repair results, and corrective actions taken. Records of physical inspections are not 

required unless a leak is detected. 

i L. Compliance with the requirements of this condition does not assure compliance 

with requirements of 30 TAC Chapter 115, an applicable NSPS, or an applicable 

NESHAPS and does not constitute.approval of alternative standards for these regulations. 

~ (9/98) 

30. A. In addition to the weekly physical inspection - for connectors specified in Special 

~ Condition No. 29E, all connectors shall be monitored by leak-checking for fugitive 

emissions at least annually using an approv6d gas analyzer with a directed 

maintenance program as specified in Special Condition No. 29F. 

B. In addition to the weekly physical inspection for connectors specified in Special 

Condition No. 29E, all connectors adj acent to valves shall be monitored by leak-checking 

for fiigitive ernissions at least quarterly using an approved gas an":yzer with a directed 

maintenance program as specified in Special Condition No. 29F. (8/07) 

G-15 08-203 
I 

SPECIAL CONDITIONS 

~ Permit Numbers 3855B and PSD-TX-876 

~ Page 12 

i • ~ 

A 

31. A. Audio, olfactory, and visual checks for ammonia, C1 2 , and HCl leaks within the operating 

- area shall be made every four hours during plant operations. 

~ B. Immediately, after detection of a leak, p lant ersonnel shall take the followin actions: p g 

- p (8/07) 

(1) Identify the leak. 

(2) Commence repair or replacement, or other actions to stop the leak including using 

a leak collection/containment system to minimize emissions from the leak until 

repair or replacement can be made. 

(3 ) If the repair of the component requires a shutdown, the repair may be delayed until 

the next scheduled shutdown, provided that the leak can be contained. 

RECORDKEEPING AND NOTIFICATION REOUIREMENTS 

32. The following records shall be maintained in accordance with General Condition No. 6: (8/07) 

~ 

( A. Records of incidental PCB production in accordance with Special Condition No. 6. 

B. Records of the monthly inspections for each of the ambient Cl Zmonitors in accordance 

with Special Condition No. 8. 

~ C. Records of all hydro testing of the C1 2transfer hoses, or records of all transfer 

hose replacements, as applicable, to demonstrate compliance with Special 

Condition No. 15. 

i D. Records of the incinerators' firebox exit temperatures in accordance with Special 

~ Condition No. 20. 

E. Records of the incinerator flue gas scrubbers' caustic solution circulation rates and pH in 

accordance with Special Condition Nos. 21 and 22. The facility record shall also indicate 

periods of routine scrubber maintenance and any related records and notifications to 

the TCEQ Houston Regional Office and the Harris County Pollution Control 

Department pursuant to Title 30 Texas Administrative Code § 101.211. 

F. Records of the incinerator CEMS in accordance with Special Condition Nos. 26D and 

E. 

I G-16 08-203 
.~ 

SPECIAL CONDITIONS 

~ Permit Numbers 3855B and PSD-TX-876 

Page 13 

G. Records of all stack emission testing performed in accordance with Special Condition 

Nos. 27 and 28. 

H. Records of the facility's fugitive emission leak detection and repair programs in 

~ accordance with Special Condition Nos. 29, 30, and 31. 

1 4 

33. This permit authorizes emissions from the Incinerators (Emission Point Nos. IND101A and 

~ IND101B) for the following planned MSS activities: (8/07) 

A. Shutdown to clean or replace scrubber packing or other scrubber component parts 

followed by start-up. 

B. Shutdown to replace incinerator, scrubber, or heat recovery component parts that have 

reached or are near the end of their useful life followed by start-up. 

C. Shutdown to replace worn or failed high temperature refractory linings, including slow 

~ fire, low temperature extended start-up to dry and cure newly installed refractory or 

refractory that has cooled due to extended downtime. 

~ D. Shutdown and start-up to allow required periodic safety or mechanical integrity 

inspections. 

1 E. Transition periods for changing from two incinerator operations to one incinerator 

l

operation due to the need for planned maintenance or due to loss of use of one 

incinerator. 

F. Transition periods resulting from a change in vent gas flow from Oxy Vinyls Deer Park 

PVC plant due to process operations. 

~ G. Transition periods created by peak vent flow due to purging storage tanks or process 

vessels to prepare for planned maintenance repairs or required safety and mechanical 

1 integrity inspections. 

( ~ 

H. Maintenance, start-up, and shutdown activities not in the above list are not authorized by 

} this permit. These emissions are subject to the maximum allowable emission rates 

j indicated on the MAERT. The performance of each MSS activity and the emissions 

associated with it shall be recorded and the rolling 12-month emissions shall be 

l updated on a monthly basis. These records shall in('ude at least the following 

~ information: 

1 

~ 

, 

G-17 08-203 
SPECIAL CONDITIONS 

Permit Numbers 3855B and PSD-TX-876 

Page 14 

(1) The physical location at which emissions from the MSS activity occurred, including 

the emission point number, common name, and any other identifier for the point at 

which the emissions were released into the atmosphere; 

(2) The type of planned MSS activity and the reason for the planned activity; 

(3) The conunon name and the facility identification number of the facilities at which 

the MSS activity and emissions occurred; 

(4) The date and time of the MSS activity and its duration; 

(5) The quantity of CO "emissions emitted according to the available CEMS data. 

DatedAugust 27, 2007 

~ 

G-18 08-203 
~ 

._~ 

EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

; 

i Permit Numbers 3855B and PSD-TX-876 

~ This table lists the maximum allowable emission rates and all sources of air contaminants on the applicant's 

property covered by this permit. The emission rates shown are those derived from information submitted as part 

~

of the application for permit and are the maximum rates allowed for these facilities. Any proposed increase in 

emission rates may require an application for a modification of the facilities covered by this permit. 

~ AIR CONTAMINANTS DATA 

Emission Source Air Contaminant Emission Rates * 

~ Point No (1) Name (2) Name (3) lb/hr TPY** 

F-PO1 VCM Prodi.iction Fugitives (4) VOC 0.89 3.88 

~ HCl 0.14 0.60 

VCM 0.68 3.00 

C12 0.01 0.05 

~ F-P-13D "D" Oxy-Chlorination Reactor VOC 0.21 0.90 

Process Fugitives (4) HCl 0.08 0.35 

F-P03B Chlorine Uriloading Fugitives (4) C12 0.06 0.27 

103 Cracking Furnace 103 PM,o 0.71 2.45 

~

IND 

(95 MMBTU/Hour) SOZ 0.06 0.22 

NOX 15.11 47.30 

~ CO 1.24 3.90 

VOC 0.51 1.76 

~ IND 104 Cracking Furnace 104 PM, 0 0.71 2.45 

(95 MMBTU1Hour) S02 0.06 0.22 

NOX 15.11 47.30 

~ CO . 1.24 3.90 

VOC 0.51 1.76 

~ IND 105 Cracking Furnace 105 PM, 0 0.71 2.45 

(95 MMBTU/Hour) S02~ 0.06 0.22 

NO,, 15.11 47.30 

~ CO 1.24 3.90 

; VOC 

~ 

0.51 1.76 

r 

1 

1 G-19 08-203 
~ . EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

~ . AIR CONTAMINANTS DATA 

` I Emission Source Air Contaminant Emission Rates * 

Point No (1) Name (2) Narne (,3) lb/hr _ TPY** 

IND 106 Cracking Furnace 106 PM, 0 0.71 2.45 

(95 MMBTU/Hour) S02 0.06 0.22 

~ NOx 15.11 47.30 

~ CO 1.24 3.90 

VOC 0.51 1.76 

~ IND 107 Cracking Furnace 107 PM10 0.71 2.35 

(95 MMBTU/Hour) S02 0.06 0.21 

~ NOX 5.32 17.50 

CO 1.33 .3.90 

VOC 0.51 1.70 

~ IND108 Cracking Furnace 108 PM, o 0.71 2.35 

(95 MMBTU/Hour) S02 0.06 0.21. P_ ~ NOX 5.32 17.50 

CO 1.33 3.90 

VOC 0.51 1.70 

l IND101A Incinerator A Scrubber VOC 2.00 8.80 

NOX 9.18 26.79 

~ CO 2.21 9.43 

CO (5) 50.00 

S02 0.10 0.40 

~ PM,a 2.00 8.80 

~ HCl 2.08 8.83 

CIz 4.00 17.50 

1 

1 

VCM 

~ 

0.05 0.22 

G-20 08-203 
- i 3 

A 

Permit Numbers 3855B and PSD-TX-876 

~ Page 3 

~ 

EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

. 

AIR CONTAMINANTS DATA 

~ Emission Source Air Contaminant Emission Rates * 

Point No. (1) 

1 

Name (2) Name (3) lb/hr TPY** _ 

~ IND101B Incinerator B Scrubber VOC 2.00 8.80 

NOX 9.18 26.79 

~ CO 2.21 9.43 

CO (5) 50.00 

SOZ 0.10 0.40 

~ PM,o 2.00 8.80 

HCI 2.08 8.83 

C12 4.00 17.50 

~ VCM 0.05 0.22 

CYC-1 Decoking Cyclone CO 43.80 3.20 

~ EEDC-SUMP East EDC Tank Farm Sump EDC <0.01 <0.01 

~ EDCTF-SUMP West EDC Tank Farm Sump EDC <0.01 <0.01 

J IM-SUMP Intermediate Sump EDC <0.01 <0.01 

~ LTC SUMP LTC Sump . EDC <0.01 <0.01 

j NO1-SUMP No. 1 Sump EDC <0.01 <0.01 

f NO2-SUMP No. 2 Sump EDC <0.01 <0.01 

~ COXY-SUMP C-Oxy Sump EDC <0.01 <0.01 

j EOXY-SUMP 

J 

E-Oxy Sump EDC 

& 

<0.01 <0.01 

HYDRO-SUMP i Hydroblast Pad Sump EDC <0.01 <0.01 

HYDRO-WEIR Hydroblast Pad Weir EDC 0.14 0.62 

VCM 0.07 0.31 

I WW-1 Wastewater Treatment EDC 0.17 0.42 

J 

CHC13 0.35 0.87 

G-21 08-203 
AIR CONTAMINANTS DATA 

~ Emission Source Air Contaminant Emission Rates * 

Point No. (1) Name (2) Name (3) lb/hr TPY** 

~ DEGREASER Parts Degreaser VOC 0.08 0.24 4 

~ FB-6473 LOPS Tank UOC 0.08 0.03 

GT-1 Gasoline Storage Tank Gasoline 44.23 1.13 

I DT-I-FWP Diesel Storage Tank Diesel 0.01 <0.01 

l DT-2-FWP Diesel Storage Tank Diesel . 0.01 <0.01 

1 DT-3-FWP Diesel Storage Tank Diesel 0.01 <0.01 

~ DT-4-FWP Diesel Storage Tank Diesel 0.01 <0.01 

j

DT-5-FWP Diesel Storage Tank Diesel 0.01 <0.01 

DT-6-UTIL Diesel Storage Tank Diesel 0.01 <0.01 

1 DT-7-EG Diesel Storage Tank Diesel 0.01 <0.01 

~ FA-4605 10 percent Hydrochloric Acid Tank HCl 0.10 <0.01 

i 

FA-4609 10 percent Hydrochloric Acid Tank HCl 0.10 <0.01 

J FA-4610 10 percent Hydrochloric Acid Tank HCI 0.10 <0.01 

~ FA-3204 

J 

10 percent Ethylene Glycol Tank EG 

a 

0.10 <0.01 

FB-6404 i Sodium Hydroxide Tank 

. NaOH 0.49 0.07 

~ FB-6480 Sodium Hydroxide Tank NaOH 0.20 0.03 

; FB-6470 Solvent Storage Tank VOC 25.74 0.96 

) COOLTWR Cooling Tower PM <0.01 <0.01 

i

Cl2 0.91 4.00 

G-22 08-203 
J 

Permit Numbers 3855B and PSD-TX-876 

~ Page 5 

EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

AIR CONTAMINANTS DATA 

~ Emission Source Air Contaminant Emission Rates * 

Point No (1) Name (2) Name (3) lb/hr TPY** 

~ COOLTWR Cooling Tower PM <0.01 <0.01 ` 

C12 0.91 4.00 

i COOLTWR-2 East Cooling Tower PM <0.01 <0.01 

Cl2 0.91 4.00 

~ (1) Emission point identification - either specific equipment designation or emission point number from plot plan. 

(2) Specific point source name. For fugitive sources use area name or fugitive source name. 

~ (3) VOC volatile organic compounds as defined in Title 30 Texas Administrative Code .§ 10 1. 1 

HCl 

= 

hydrogen chloride 

VCM - vinyl chloride monomer 

C12 

PM 

~ = chlorine 

particulate matter, suspended in the atmosphere, including PM, o . 

PM, o - particulate matter less than 10 microns in diameter. Where PM is not listed, it shall be _ ~ assumed that no PM greater th an 10 microns is emitted. 

SOZ 

- 

sulfur dioxide 

NOx - total oxides of nitrogen 

~ CO carbon monoxide 

EDC 

= 

ethylene dichloride 

CHCL3 - chloroform 

~ NaOH - sodium hydroxide 

4(4) Fugitive emissions are an estimate only and should not be considered as a maximum allowable emission rate. 

(5) Maintenance operations only. Emissions from these EPNs are only from these permitted facilities 

* Emission rates are based on and the facilities are limited by the following maximum operating schedule: 

Hrs/day Days/week Weeks/year or 8.760 Hrs/year 

r 

** Compliance with annual emission limits is based on a rolling 12-month period. 

Dated August 27, 2007 

1 

G-23 08-203 
_-~ 

a 

M~iiwLce 

 . '61 I MA I I. 

~ 

~ 

APPENDIX H 

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APPENDIX I 

Resumes of Test Personnel 

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08-203 I-1 

l 
MEFCO. ErMROnrnEnML 

ROBERT M. PATTERSON; President 

Education B. S. 1983, Central Michigan University; Mt. Pleasant, Michigan, 

in Geology and Earth Science-Meteorology. 

Professional Attended a two-day short course, "Performing and Observing 

Trainin Source Sampling" in Dallas, Texas. 

Courses 

Attended a one-day short course on basic supervision. 

Attended a four-week management course presented by the 

American Management Association, 1991-1992. 

Certification Certified Visible Emissions Evaluator 

Certified Cabot Full-Face Respirator Fit Tester 

Professional Source Evaluation Society 

Memberships American Management Association 

Technical Participated in the sampling of over 1,000 sources, including 

Experience several of which were sampled simultaneously using more 

than one sampling train. Thoroughly trained in all EPA testing 

procedures, 1986-present. 

Over nineteen years experience with EPA and Texas Air Control 

Board methods of sampling - both stationary sources and ambient 

air. CFR, Title 40, Chapter I, Part 60, EPA Methods 1 through 

25, and 101 through 110. Performance Specifications 1 through 

5. CFR, Title 40, Chapter I, Part 50, Appendix A through F. 

"Sampling Procedures Manual, Texas Air Control Board, January 

1983." Parts 1-1 through 14-6, Appendix B through Appendix M. 

Experienced with sampling Method 0010, Modified Method 5 

Sampling Train; Method 0030, Volatile Organic Sampling Train; 

and various EPA and "Site Specific" mu ~~ iple metal and acid 

gas sampling trains. 

(continued) 

1-2 
,r . 0 T

_• 

PATTERSON, Rob (cont'd) 

Technical Over twenty one years experience with EPA and Texas Air 

Experience Control Board methods of analysis of both stationary and 

(cont'd) ambient air samples. Particulate matter, S0 3 , S02, H2SO4 , 

NOX, CO, CO2 , 02 , H2S, F, TRS, HCI, C12 , NH3 , VOC, Cl-C7 , 

and other organics. Both laboratory and on-site analyses 

were performed. 

Experienced in the sampling and analysis of commercial 

calibration gas cylinders for sulfur dioxide, oxides of nitrogen, 

carbon dioxide, oxygen, carbon monoxide, and Cl-C7 

hydrocarbons. 

Thoroughly trained in the operation and routine maintenance 

of the following: 

• MSA LIRA Model 202S Infrared Analyzer 

• Analytical Instrument Development, Inc. 

Model 340A Calibration System 

• Shimadzu GC-Mini 2 Gas Chromatograph 

• Thermo Environmental Model 10AR Oxides of 

Nitrogen Analyzer 

• Thermo Oxygen Analyzer 

• Teledyne Model 326 Oxygen Analyzer 

• Thermo Environmental Model 48 Carbon Monoxide 

Analyzer 

• Thermo Environmental Model 40 Sulfur Dioxide 

Analyzer 

• Ratfisch Model RS 100 Total Hydrocarbon Analyzer 

• Western Research Model 721AT Sulfur Dioxide 

Analyzer 

• Horiba Model PIR 2000 Carbon Dioxide Analyzer 

• Ratfisch Model RS 55 Total Hydrocarbon Analyzer 

• J.U.M. Model VE-7 Total Hydrocarbon Analyzer 

08-203 1-3 
METC,

ofto 

JAMES R. MONFRIES; Senior Quality Assurance Manager 

Education B. S. 1975, University of Texas. at Arlington; Arlington, Texas, 

in Biology with a minor in Chemistry. 

Graduate work at the University of Texas at Dallas in the 

Environmental Science Department. 

Professional Attended a two-day short course, "Performing and Observing 

Training Source Sampling" in Dallas, Texas, July 1976. 

Courses 

Certification Certified Visible Emissions Evaluator 

Professional Air and Waste Management Association 

Memberships Source Evaluation Society - Past President 

Technical Participated in the sampling of over 700 sources, serving in the 

Experience supervisory capacity on over 500 sources. Many of the sources 

were sampled simultaneously using more than one sampling 

train at several points in the flue gas stream, 1976-present. 

Has also supervised several ambient air monitoring studies, 

including a permanent five-station high volume air sampling 

network in South Texas, a permanent four-station high volume 

air sampling network in Pennsylvania, and a permanent sevenstation sulfur dioxide sampling network in East Texas. 

Was Quality Assurance Manager for several ambient air 

monitoring studies; including a four-station high volume air 

sampling network for TSP and PM10 in Midlothian, Texas; 

a single-station high volume air sampling network for PM10 in 

South Texas; a two-station high volume air sampling network 

for TSP in Wichita Falls, Texas; and a four-station continuous 

air sampling network for TSP and PM10 in Jewett, Texas using 

Thermo Andersen FH 62 C14 Beta Gauge Dust Monitors. 

(continued) 

08-203 2 
~m~rco 

MONFRIES, James (cont'd) 

Twenty years experience with EPA and Texas Commission on 

Environmental Quality methods of analysis of both source and 

ambient air samples for particulates, S0 2, S03 , H2SO4, 1-12S, 

HCI, C12 , NOX, Hydrocarbons, and TRS. 

Experienced in the analysis of commercial calibration gas 

cylinders for sulfur dioxide and oxides of nitrogen. 

Experienced with VOST and Modified Method 5 Sampling 

Procedures. 

Thoroughly trained in the operation and routine maintenance 

of the following: 

• Lear Siegler, Inc. SM800 Stack Gas Monitor 

• Du Pont Model 460/1 Photometric Analyzer System 

• Lear Siegler, Inc. SM1000 Ambient S02 Monitor 

• Calibrated Instruments Ultragas S02 Monitor 

• Meloy 285E S02 Analyzer 

• Meloy SA-700 Fluorescent S02 Analyzer 

• MSA LIRA Model 202S Infrared Analyzer 

• Analytical Instrument Development, Inc. 

Model 340A Calibration System 

• Shimadzu GC-Mini 2 Gas Chromatograph 

• Thermo Environmental Model 10S NO x Analyzer 

• Thermo Oxygen Analyzer 

• Teledyne Model 326 Oxygen Analyzer 

• Thermo Environmental Model 48 Carbon Monoxide Analyzer 

• Thermo Environmental Model 40 Sulfur Dioxide Analyzer 

• RatFisch Model RS 103 Total Hydrocarbon Analyzer 

• Western Research Model 721AT Sulfur Dioxide Analyzer 

• Horiba Model PIR 2000 Carbon Dioxide Analyzer 

• RatFisch Model RS 55 Total Hydrocarbon Analyzer 

• J.U.M. Model VE-7 Total Hydrocarbon Analyzer 

• Thermo Andersen Model FH 62 C14 Dust Monitor 

08-203 1-5 
~ • 

JEFF KNAPP; Project Manager 

Education Nuclear Engineering, 1994 — U. S. Navy 

Professional Dangerous Good Shipping Training 

Certifications HAZMAT certified 

Adult CPR certified 

Standard First Aid certified 

MSHA certified 

Technical Participated in the sampling of over 250 sources, including several 

Experience of which were sampled simultaneously using more than one 

sampling train. Thoroughly trained in all EPA testing procedures, 

2006-present. 

Successfully perFormed over 200 compliance tests using FTIR for 

a variety of industries. 

Experienced with all SW846 and 40 CFR 60 sampling trains. 

08-203 a 
r . ! 

JERRY McDONALD; Environmental Scientist I 

Education B. S. Wildlife Biology, December 2006; Texas State, San Marcos, 

Texas. 

Technical 

Experience Participated in the sampling of over 25 sources, including 

several of which were sampled simultaneously using more 

than one sampling train. 

Thoroughly trained in all EPA testing procedures, 2008-present. 

08-203 1-7