# V ?IMEFCO Ei1lJIFiO(1fT1FfjTAI P.O. Box 598 Addison, TX 75001 (972) 931-7127



### SOURCE EMISSIONS SURVEY

OF OXYVINYLS, LP INCINERATORS A AND B SCRUBBER STACKS (EPNS IND101A AND IND101 B) LA PORTE, TEXAS TCEQ PERMIT 3855B/PSD-TX-876

JUNE 2008

FILE NUMBER 08-203

" I certify that I have personally checked and am familiar with the information submitted herein, and based on my inquiries of those individuals immediately responsible for obtaining the information, I believe the submitted information is trt e, accurat , and complete. "

J s R. Monfries Senior Quality Assurance Manager

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TABLE OF CONTENTS
PAGE 1 2 6 8 9 11 14 16 

### INTRODUCTION SUMMARY OF RESULTS DISCUSSION OF RESULTS DESCRIPTION OF PROCESS DESCRIPTION OF SAMPLING LOCATIONS SAMPLING AND ANALYTICAL PROCEDURES DESCRIPTION OF TESTS APPENDICES A. Location of Sampling Points B. Source Emissions Calculations C. Calibration Data D. Field Testing Data E. Analytical Data F. Plant Operational Data G. TCEQ Permit H. Chain of Custody I. Resumes of Test Personnel

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I SOURCE EMISSIONS.SURVEY OXYVINYLS, LP INCINERATORS A AND B SCRUBBER STACKS (EPNS IND101A AND IND101 B) LA PORTE, TEXAS TCEQ PERMIT 3855B/PSD-TX-876 FILE NUMBER 08-203
INTRODUCTION METCO Environmental, 1100 Gulf Freeway, Calder Ridge.Business Park, Suite 100, League City, Texas, conducted a source emissions survey of Oxyvinyls, LP, located at 2400 Miller Cutoff Road, La Porte, Texas, on June 3, 4, and 5, 2008. The purpose of these tests was to determine the concentrations of hydrogen chloride and chlorine being emitted to the atmosphere via the Incinerators A and B Scrubber Stacks (EPNs IND101A and IND101 B), in order to comply with TCEQ Permit 3855B/PSD-TX-876 and 40 CFR, Part 63, Subpart G. The results demonstrated that the units were in compliance with TCEQ Permit 3855B/PSD-TX-876 and 40 CFR, Part 63, Subpart G. The sampling was performed by the following METCO personnel: Jeff Knapp - Project Supervisor and Jerry McDonald. The sampling followed the procedures set forth in the Code of Federal Regulations, Title 40, Chapter I, Part 60, Appendix A, Methods 1, 2, 313, 4, and 26A; and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985".

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## Run Number 

## 1 3 Average Allowable Emission Rate

Run Number 

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## Average Allowable Emission Rate , 

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~ Hydrogen Chloride Emissions d m Ibs/hr 8.3 1.68 8.1 1.65

. 5.4 1.08 

### 7.3 1.47

<_ 2.08*

Hydrogen Chloride Emissions (dry ppm) 

### Ibs/hr 2.0 0.46 3.6 0.82 3_7 0.84 

### 3.1 0.71

<_ 2.08* Chlorine Emissions d m Ibs/hr 4.6 1.81 4.9 1.96 3.4 1.32 

### 4.3 1.70

---- <_ 4.00*

Chlorine Emissions d m Ibs/hr 2.8 1.25 3.9 1.72 6_0 2.66 

### 4.2 1.88

---- 5 4.00* SUMMARY OF RESULTS Incinerator A Scrubber Stack (EPN IND101A)

Incinerator B Scrubber Stack (EPN IND101 B)

* TCEQ Permit 3855B/PSD-TX-876 allowable.

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### Run

Number. 

### 1 2 3 Average Allowable

Run Number 

### 1 2 3 Average Allowable 

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SUMMARY OF RESULTS
Incinerator A Scrubber

I 

### nputs* Hydrogen Chloride Concentrations Ibs/hr 3,588.56 3,493.27 3,347.43 

### 3,476.42

I 

### nputs* Hydrogen Chloride Concentrations Ibs/hr 2,892.27 3,338.38 3,578.62 

### 3,269.76 Stack (EPN IND101A) 

### HC1 2 /C1 2 Emissions Ibs/hr 3.49 3.61 2.40 

### 3.17

Stack (EPN IND101 B) 

### HC1 2 /C1 2 Emissions Ibs/hr 1.71 2.54 3.50 

### 2.58 Incinerator B Scrubber 

## Removal Efficiency ( 0 /0) 99.9 99.9 99.9 

### 99.9 ? 99%**

Removal Efficiency ( 0 /0) 99.9 99.9 99.9 

### 99.9 ? 99%**



## ~ r I * Provided by Oxyvinyls, L.P.

** 4u CFR, Part 63, Subpart G allowable.

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SUMMARY OF RESULTS Incinerator A Scrubber Stack (EPN IND101A)

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) ** Assumed moisture at saturation.



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### Run Number 1 2 3 Date 06/04/08 06/04/08 06/04/08 Time 1130-1238 1321-1432 1508-1616 Stack Flow Rate - ACFM 42,664 42,687 41,852 Stack Flow Rate - DSCFM* 35,756 36,095 35,236 % Water Vapor -% Vol.** 8.93 8.43 8.68 %CO 2 -%Vol. 11.2 11.0 11.2 %O Z -%Vol. 5.2 5.4 4.8 % Excess Air @ Sampling Point 30.7 32.2 27.5 Stack Temperature -°F 111 109 110 Stack Pressure -"Hg 29.67 29.67 29.67 Percent Isokinetic 97.3 96.1 95.9 Volume Dry Gas Sampled - DSCF* 37.676 37.544 36.572 Hydrogen Chloride - Ng 13,385.16 12,976.40 8,459.51 Hydrogen Chloride Emissions - dry ppm 8.3 8.1 5.4 Hydrogen Chloride Emissions - Ibs/hr 1.68 1.65 1.08 Chlorine - Ng 14,376.03 15,434.40 10,386.41 Chlorine Emissions - dry ppm 4.6 4.9 3.4 Chlorine Emissions - Ibs/hr

, 

### 1.81 1.96 1.32

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SUMMARY OF RESULTS Incinerator B Scrubber Stack (EPN IND101 B)

* 29.92 "Hg, 68°F (760 mm Hg, 20°C)

08-203 -5- Run Number 1 2 3 Date 06/05/08 06/05/08 06/05/08 Time 1005-1115 1143-1253 1315-1420 Stack Flow Rate - ACFM 50,951 50,054 49,785 Stack FlowRate - DSCFM* 40,947 40,065 39,996 % Water Vapor -% Vol. 11.35 11.27 10.92 % CO 2 -% Vol. 10.4 10.8 10.6 %O Z -%Vol. 5.0 4.8 4.8 % Excess Air @ Sampling Point 28.7 27.3 27.2 Stack Temperature -°F 120 123 123 Stack Pressure -"Hg 29.69 29.69 29.69 Percent Isokinetic 97.8 98.5 97.9 Volume Dry Gas Sampled - DSCF* 43.344 42.731 42.376 Hydrogen Chloride - Ng 3,694.41 6,604.09 6,704.63 Hydrogen Chloride Emissions - dry ppm 2.0 3.6 3.7 Hydrogen Chloride Emissions - Ibs/hr 0.46 0.82 0.84 Chlorine - pg 9,995.18 13,857.44 21,322.22 Chlorine Emissions - dry ppm 2.8 3.9 6.0 Chlorine Emissions - Ibs/hr 1.25 1.72 2.66

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DISCUSSION OF RESULTS Incinerator A Scrubber Stack (EPN IND101A) The three tests for hydrogen chloride and chlorine appeared to be valid representations of the actual emissions during the tests. AII leak checks performed on the sampling train and the pitot tubes showed no leaks before or after each test. The indicative parameters calculated from the field data were in close agreement. The measured flow rates (QS) for the tests were within 1.3 percent of the mean value. The rates of sampling for the three tests were within the specified limits (90 to 110 percent isokinetic). The greatest deviation from 100 percent isokinetic was 4.1 percent. The calculated emissions (pounds per hour) of hydrogen chloride for the three tests showed a range of -26.5 percent to +14.3 percent variation from the mean value. The calculated emissions (pounds per hour) of chlorine for the three tests showed a range of -22.2 percent to +15.5 percent variation from the mean value. Incinerator B Scrubber Stack (EPN IND101 B) The three tests for hydrogen chloride and chlorine appeared to be valid representations of the actual emissions during the tests. AII leak checks performed on the sampling train and the pitot tubes showed no leaks before or after each test. The indicative parameters calculated from the field data were in close agreement. The moisture percentages for the three tests were within 2.3 percent of the mean value. The measured flow rates (Q s ) for the tests were within 1.5 percent of the mean value. The rates of sampling for the three tests were within the specified limits (90 to 110 percent isokinetic). The greatest deviation from 100 percent isokinetic was 2.2 percent.

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The calculated emissions (pounds per hour) of hydrogen chloride for the three tests showed a range of -34.9 percent to +18.9 percent variation from the mean value. The calculated emissions (pounds per hour) of chlorine for the three tests showed a range of -33.4 percent to +41.7 percent variation from the mean value.

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# s DESCRIPTION OF PROCESS

The Incinerator Scrubbers (DA-4701A/B) provide the final cleaning for plant effluent from the Incinerators before it goes to atmosphere. The gases enter the bottom of each scrubber and travel countercurrent to the water, which flows down through the two sections of each scrubber. Any hydrogen choride or chlorine remaining in the exhaust gases from the thermal oxidizers is removed by the water spray in the scrubbers. Wash water is provided from softened water. Fire water is used in emergency situations. Each vertical vessel is approximately 100 feet tall, including the stack, and 12 feet in diameter at the base. The column is fabricated from fiberglass reinforced plastic (FRP: Hetron 980) using a vinyl ester resin suitable for both acid and caustic service. The inlet nozzle from the waste heat boiler is fitted with spray nozzles and constructed from tantalum lined carbon steel. The Scrubber is divided into two sections ("Acid" bottom section and "Caustic" top section) with each section having its own spray header system. Hydrochloric Acid solution generated in the bottom section is collected for use in the plant to neutralize alkaline streams. Any excess acid is neutralized with caustic soda on the waste water treatment section of the plant. The scrubber contains one permanent chimney tray, between the two sections, with four chimneys. The Acid and Caustic Sections internal spray headers are fabricated of FRP. The 90 spray nozzles are fabricated from PTFE (Teflon). The Scrubber contains a top section Teflon demister pad with Hastelloy C grids.
Dimensions: 100' tall 12' dia. Material: Fiberglass reinforced plastic (FRP: Fetron 980) using a vinyl ester resin Wall Thickness: '/z inch Design pressure: 5 psig Design temperaturee: 148.8° C (300°F)
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DESCRIPTION OF SAMPLING LOCATIONS The sampling locations on the Incinerators A and B Scrubber Stacks (EPNs IND101A and IND101 B) are approximately 89 feet above the ground. The sampling ports are located 26 feet (5.31 stack diameters) downstream from a constriction in the stacks and 9 feet (1.84 stack diameters) upstream from the outlet of the stacks.



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SAMPLING LOCATION Incinerators A and B Scrubber Stacks (EPNs IND101A and IND101 B)

Not to Scale

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SAMPLING AND ANALYTICAL PROCEDURES The sampling followed the procedures set forth in the.Code of Federal Regulations, Title 40, Chapter I, Part 60, Appendix A, Methods 1, 2, 313, 4, and 26A; and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985". A preliminary velocity traverse was made at each of the two ports on the Incinerator A Scrubber Stack (EPN IND101A), in order to determine the uniformity and magnitude of the flow prior to testing. AII traverse points were checked for cyclonic flow and the average angle of flow was equal to 3.4 degrees. Alternate procedures would be required if the angle of flow was greater than 20 degrees. Ten traverse points were sampled from each of the two ports for a total of twenty traverse points. A preliminary velocity traverse was made at each of the two ports on the Incinerator B Scrubber Stack (EPN IND101 B), in order to determine the uniformity and magnitude of the flow prior to testing. AII traverse points were checked for cyclonic flow and the average angle of flow was equal to 5.0 degrees. Alternate procedures would be required if the angle of flow was greater than 20 degrees. ' Ten traverse points were sampled from each of the two ports for a total of twenty traverse points. The sampling train was leak-checked before each test, and again after each test at the highest vacuum reading recorded during the test. This was done to predetermine the possibility of a diluted sample. The pitot tube lines were checked for leaks before and after each test under both a vacuum and a pressure. The lines were also checked for clearance and th , ~ 

### manometer was zeroed before each test.
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A grab orsat sample was collected and analyzed according to EPA Method 3B during each test. Hydrogen Chloride and Chlorine 

### Triplicate samples for hydrogen chloride and chlorine were collected from each source. The samples were taken according to EPA Methods 1, 2, 3B, 4, and 26A; and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985". For each run, samples of three-minute duration were taken isokinetically at each of the twenty traverse points for a total sampling time of 60 minutes. Reagent blanks were submitted. The " front-half " of the sampling train for the stack contained the following components: Glass Nozzle Heated Glass Probe @ 248°F ± 25°F Heated Quartz Fiber Filter and Teflon Support @ 248°F ± 25°F The " back-half " of the sampling train contained the following components: Impinger Number Contents Amount Parameter Collected 

### 1 0.1 N Sulfuric Acid 100 ml Hydrogen Chloride 2 0.1 N Sulfuric Acid 100 ml Hydrogen Chloride 3 0.1 N Sodium Hydroxide 100 ml Chlorine 4 0.1 N Sodium Hydroxide 100 ml Chlorine 5 Silica Gel 200 g Moisture The hydrogen chloride and chlorine samples were analyzed by ion chromatography.

08-203 -12- I ~

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I DESCRIPTION OF TESTS

Personnel from METCO Environmental arrived at the plant at 2:30 p.m. on Tuesday, June 3, 2008. After meeting with plant personnel and attending a brief safety orientation, the equipment was moved onto the Incinerator A Scrubber Stack (EPN IND101A). The equipment was secured for the night and all work was completed at 4:15 p.m. On Wednesday, June 4, work began at work began at 6:15 a.m. The equipment was prepared for testing: The preliminary data was collected. The first test for hydrogen chloride and chlorine began at 11:30 a.m. Testing continued until completion of the third test at 4:16 p.m. The samples were recovered. The equipment was moved off of the Incinerator A Scrubber Stack (EPN IND101A) and onto the Incinerator B Scrubber Stack (EPN IND101 B). The equipment was secured for the night and all work was completed at 6:00 p.m. On Thursday, June 5, work began at work began at 6:15 a.m. The equipment was prepared for testing. The preliminary data was collected. The first test for hydrogen chloride and chlorine began at 10:05 a.m. Testing continued until completion of the third test at 2:20 p.m. The equipment was moved off of the stack and loaded into the sampling van. The samples were recovered and transported to METCO Environmental's laboratory in Dallas, Texas, for analysis and evaluation.

08-203 -14-

### Operations at OxyVinyls, LP, Incinerators A and B Scrubber Stacks (EPNs IND101A

and IND101 B), located in La Porte, Texas, were completed at 4:15 p.m. on Thursday, June 5, 2008.

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APPENDICES

A. Location of Sampling Points B. Source Emissions Calculations C. Calibration Data D. Field Testing Data E. Analytical Data F. Plant Operational Data G. TCEQ Permit H. Chain of Custody I. Resumes of Test Personnel

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### APPENDIX A Location of Sampling Points Incinerators A and B Scrubber Stacks (EPNs IND101A and IND101 B) The sampling ports are located 26 feet (5.31 stack diameters) downstream from a constriction in the stacks and 9 feet (1.84 stack diameters) upstream from the outlet of the stacks. The locations of the sampling points were calculated as follows:
Port and Wall Thickness = 8 1/4 inches Inside Stack Diameter = 58 3/4 inches
Point Percent of Diameter Distance Number From Wall From Wall 1 2.6 1 112 " 2 8.2 4 13/16 " 3 14.6 8 9/16 " 4 22.6 13 1 /4 " 5 34.2 20 1 /16 " 6 65.8 38 11 /16 " 7 77.4 45 1 /2 " 8 85.4 50 3/16 " 9 91.8 53 15/16 " 10 97.4 57 1 /4 "

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APPENDIX A Location of Sampling Points Incinerators A and B Scrubber Stacks (EPNs IND101A and IND10113)

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APPENDIX B Nomenclature and Equations



## for Calculation of Source Emissions

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# 1 NOMENCLATURE FOR EXAMPLE CALCULATIONS English Metric Symbol 

### Units Units 

# A s i n n C p D„ in. m %EA g 32.174 ft/sec 2 

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## M d mf mg mg fl/lwater 18Ib/Ib-mole mt mg mg MW Ib/Ib-mole g/g-mole MW a i r 28.961b/

Ib-mole MW d Ib/Ib-mole g/g-mole Pb "Hg mm Hg

Absolute 

## P m 11 

## 1-1 2 0 mm H 2 0 * 29.92 " Hg, 68 ° F(760 mm Hg, 20 ° C) Description 

### Stack Area Pitot Tube Calibration Factor Sampling Nozzle Diameter Percent Excess Air at sampling point Acceleration of Gravity Percent Isokinetic Percent Moisture in the stack gas by volume Mole fraction of dry gas Particulate - probe, cyclone, and filter Molecular Weight of water Particulate - total Molecular Weight of stack gas Molecular Weight of air Molecular Weight of dry stack gas Barometric Pressure Orifice Pressure drop



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Symbol Units Units 

### P s "Hg mm Hg

Absolute oP "H 2 0 mm H20 Psta 29.92 "Hg 760 mm Hg Q a ACFM m 3 /hr

Qg 

### DSCFM* dscm/hr*

- 

### 0 21.83 "Hgft 3 /Ib-mole°R 

# T m OF .0 T t min min 

### T s OF °C

Tstd 

### 528°R 

### 293°K 

## V m ft 3 

## m 3

VmSta dscf* dscm*

V S fpm m/sec V, ml ml Description 

### Stack Pressure Velocity Head of stack gas Standard Barometric Pressure Stack Gas Volume at actual stack conditions Stack Gas Volume at 29.92 "Hg, 528°R, dry Universal Gas Constant Average Gas Meter Temperature Net time of test Stack Temperature Standard Temperature Volume of dry gas sampled @ meter conditions Volume of dry gas sampled @ standard conditions Stack velocity @ stack conditions Total water collected in impingers and silica gel
* 29.92 " Hg, 68 ° F(760 mm Hg, 20 ° C)
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English Metric Symbol Units Units 

### Vw 9as scf * scm *
pair 0.07521bs/ft 3
pwater 

### 1 g/ml pman 62.32Ibs/ft 3 Description 

### Volume of water vapor collected @ standard conditions Density of Air Density of Water Density of Manometer Oil

* 29.92 " Hg, 68 ° F(760 mm Hg, 20 ° C) 08-203 .

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EXAMPLE CALCULATIONS
1. Volume of dry gas sampled at standard conditions.
Pb 

### + Pm 

### Vmstd = Vm T Std 13.6



### (T, + 460 Pstd

Pb 

### + PR' 

### Vmstd =17. 65 Vm 13.6 

### dscf

Tm+460

Vmstd = dscf x 0.028317 = dscm


### 2. Volume of water vapor collected at standard conditions. *

VWgas 

### _ (Vw - 9ms S0 2 **) Pwater R Tstd

— 

### Pstd Mwater 

### 453.6

VW g as= 0 

### .0 4 72(VW=9'mSS02**) = SCf

Vw g as 

### = scf x 0. 028317 = scm


### 3. Percent moisture in stack gas.

%M = 

### VW gas 

### x 100 = % Vmstd + VW

gas 

### * 29.92 " Hg, 68 ° F(760 mm Hg, 20 ° C) ** gms S0 2 subtracted only when S0 2 is collected in the sampling train being used to determine the volume of water vapor collected. 

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4. Mole fraction of dry gas.



### 100 - %M Ma = 100

5. Average molecular weight of dry stack gas.


### MWd = % CO2 

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### 32 +% N2 x 28 + 

# C % CO x 28 

### = Ib/Ib - mole 

## [ 100] [ 100 [ 100 

# 1 1 

# 001 = g/g - mole 

### 6. Molecular weight of stack gas. MW=MWaxMd+18(1-Md)= 

### Ib =g/g-mole 

## Ib - mole

7. Percent excess air at sampling point. %EA —_ 

### 100 10/0 0 2 - (0. 5 % CO)J 0.265 

### (% N2) - (% 02 - (0-5 %CO)]

8. Stack Pressure.

Stack Pressure "/,

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_ „ PS = Pb + ' Hg Absolute

13.6
P s ="HgAbs.x25.4=mmHg



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### 9. Stack velocity at stack conditions.

1/2



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V S = fpm x 0.00508 = m/sec

10. Dry stack gas volume at standard conditions. * 

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### 460x S 

### 144 P T S 

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S + 460 Q S = 

### DSCFM x 1. 6990 = dscm/hr

11. Actual stack gas volume at stack conditions. 

### Q a = VsxA S 

### =ACFM 

## 144 Q a = 

### ACFM x 1.6990 = m 3 /hr

*A9 2 %" Hg, 68 ° F(760 mm Hg, 20 ° C) B-7

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12. Percent Isokinetic. 

### // —_ Vmsrd x(TS + 460) x pstd x 100 x 144 in 

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2 

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( 4) % I- 1039 x Vmsra x(T

S +.460)



### _ MdxPSxTtxVsxDn

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EXAMPLE CALCULATIONS

Ibs/hr = c

m _ 

### x 2.205 x 10 -6 Ibs/mg x DSCFM* x 60 min/hr Vmstd VmSta = Volume of dry gas sampled (dscf*) DSCFM* = Stack Flow Rate

ppm ` m -q_ 

### x 24.04 

### Vmstd (m) MW 24.04 = Ideal Gas Constant liters/g-mole Vmstd = Volume of dry gas sampled (m 3 *) MW = Molecular Weight
Compound Molecular Weight 

### Hydrogen Chloride 36.45 Chlorine 70.90 * 29.92 "Hg, 68°F (760 mm Hg, 20°C)

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SOURCE EMISSION SURVEY
JOB NUMBER: 08-203 JOB NAME: OXYVINYLS, L.P. LOCATION: LA PORTE, TEXAS UNIT TESTED: INCINERATOR A SCRUBBER STACK
SOURCE EMISSION CALCULATIONS RUN NUMBER SYMBOL DESCRIPTION UNITS 1 2 3
DATE 06/04/08 06/04/08 06/04/08 BEGIN TIME 1130 1321 1508 END TIME 1238 1432 1616 P(b) BAROMETRIC PRESSURE "Hg Abs. 29.70 29.70 29.70 (mm H (754.00) (754.00) (754.00) P(m) ORIFICE PRESSURE DROP "H20 0.940 0.938 0.900 (mm H20) (23.900) (23.800) 22.900) DGM CALIBRATION FACTOR 0.998 0.998 0.998 V(m) VOLUME DRY GAS SAMPLED ft.^3 38.434 38.371 37.521

@ METER CONDITIONS (m^3) (1.088) (1.087) (1.062) LEAK CHECK VOLUME ft.^3 0.000 0.000 0.000 T(m) AVERAGE GAS METER DEG.F 76 77 79

TEMPERATURE (DEG.C) (24) (25) (26) V(m[std])* VOLUME DRY GAS SAMPLED DSCF 37.676 37.544 36.572

@ STANDARD CONDITIONS* (DSCM) (1.067) (1.063) (1.036) V(w) TOTAL WATER COLLECTED, ml 79.4 92.8 80.1

IMPINGERS & SILICA GEL V(w[gas]) VOLUME WATER VAPOR. SCF 3.748 4.380 3.781

COLLECTED @ STANDARD (SCM) (0.106) (0.124) (0.107) CONDITIONS* %M MOISTURE IN STACK GAS %** 8.93 8.43 8.68

BY VOLUME Md MOL FRACTION OF D.RY GAS 0.9107 0.9157 0.9132 Tt NET TIME OF TEST MINUTES 60 60 60 * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) ** Assumed moisture at saturation. 08-203 B-10r • . '•

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SOURCE EMISSION CALCULATIONS JOB NUMBER: 08-203 JOB NAME: OXYVINYLS, L.P. LOCATION: LA PORTE, TEXAS UNIT TESTED: INCINERATOR A SCRUBBER STACK RUN NUMBER SYMBOL DESCRIPTION UNITS 1 2 3 CO2 % 11.2 11.0 11.2 02 % 5.2 5.4 4.8 CO % 0.0 0.0 0.0 N2 % 83.6 83.6 84.0 %EA EXCESS AIR @ SAMPLING % 30.7 32.2 27.5

POINT MWd MOLECULAR WEIGHT OF LB/LB-MOLE 30.00 29.98 29.98

DRY STACK GAS (g/ -MOLE) (30.00) (29.98) 29.98) MW MOLECULAR WEIGHT OF LB/LB-MOLE 28.93 28.97 28.94

STACK GAS (g/ -MOLE) (28.93) (28.97) (28.94) Cp PITOT TUBE CALIBRATION 0.813 0.813 0.813 DELTA P VELOCITY HEAD OF STACK "H20 0.447 0.449 0.430

GAS (mm H20) (11:400) (11.400) (10.900) DELTA P^(1/2) "H20 0.667 0.669 0.655 Ts STACK TEMPERATURE DEG. F 111 109 110 (DEG. C) 44 (43 (43) Ps STACK PRESSURE "Hg Abs. 29.67 29.67 29.67 (mm Hg) (754.00) (754.00) (754.00) "H20 -0.40 -0.40 -0.40 Vs STACK VELOCITY @ STACK FPM 2,266 2,267 2,223

CONDITIONS (m/SEC.) (12) (12) (11) As STACK AREA (SQ.INCHES) 2,711 2,711 2,711 (SQ.METERS) (2) (2) (2) Qs DRY STACK GAS VOLUME @ DSCFM 35,756 36,095 35,236

STANDARD CONDITIONS* (DSCM/HR) (60,749) (61,325) (59,866) WET STACK GAS VOLUME @ WSCFH 2,355,726 2,365,076 2,315,112 STANDARD CONDITIONS* Qa ACTUAL STACK GAS VOLUME ACFM 42,664 42,687 41,852

@ STACK CONDITIONS (m^3/HR) (72,486) (72,525) (71,107) Dn SAMPLING NOZZLE DIAM. IN. 0.250 0.250 0.250 (m) (0.006) (0.006) (0.006) %I IPERCENT ISOKINETIC % 97.31 96.1 1 95.9 * 68 veg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg)



### 08-203 B-11

# METCO.

SOURCE EMISSION SURVEY
JOB NUMBER: 08-203 JOB NAME: OXYVINYLS, L.P. LOCATION: LA PORTE, TEXAS UNIT TESTED: INCINERATOR B SCRUBBER STACK
SOURCE EMISSION CALCULATIONS RUN NUMBER SYMBOL DESCRIPTION UNITS 1 2 3
DATE 06/05/08 06/05/08 06/05/08 BEGIN TIME 1005 1143 1315 END TIME 1115 1253 1420 P(b) BAROMETRIC PRESSURE "Hg Abs. 29.70 29.70 29.70 (mm Hg) -(754.00) (754.00) (754.00) P(m) ORIFICE PRESSURE DROP "H20 1.288 1.240 1.230 (mm H20) (32.700) (31.500) (31.200) DGM CALIBRATION FACTOR 0.998 0.998 0.998 V(m) VOLUME DRY GAS SAMPLED ft.^3 44.096 43.721 43.520

@ METER CONDITIONS (m^3) (1.249) (1.238) (1.232) LEAK CHECK VOLUME ft."3 0.000 0.000 0.000 T(m) AVERAGE GAS METER DEG.F 75 78 80

TEMPERATURE (DEG.C) (24) (26) (27) V(m[std])* VOLUME DRY GAS SAMPLED DSCF 43.344 42.731 42.376

@ STANDARD CONDITIONS* (DSCM) (1.227) (1.210) (1:200) V(w) TOTAL WATER COLLECTED, ml 117.6 115.0 110.1

IMPINGERS & StLICA GEL V(w[gas]) VOLUME WATER VAPOR. SCF 5.551 5.428 5.197

COLLECTED @ STANDARD (SCM) (0.157) (0.154) (0.147) CONDITIONS* %M MOISTURE IN STACK GAS % 11.35 11.27 10.92

BY VOLUME Md MOL FRACTION OF DRY GAS 0.8865 0.8873 0.8908 Tt NET TIME OF TEST MINUTES 60 1 601 60 * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg)


### 08-203 B-12SOURCE EMISSION CALCULATIONS

JOB NUMBER: 08-203 JOB NAME: OXYVINYLS, L.P. LOCATION: LA PORTE, TEXAS UNIT TESTED: INCINERATOR B SCRUBBER STACK RUN NUMBER SYMBOL DESCRIPTION UNITS 1 2 3 CO2 % 10.4 10.8 10.6 02 % 5.0 4.8 4.8 CO % 0.0 0.0 0.0 N2 % 84.6 84.4 84.6 %EA EXCESS AIR @ SAMPLING % 28.7 27.3 27.2

POINT MWd MOLECULAR WEIGHT OF LB/LB-MOLE 29.86 29.92 29.89

DRY STACK GAS ( / -MOLE) (29.86) (29.92) (29.89) MW MOLECULAR WEIGHT OF LB/LB-MOLE 28.52 28.58 28.59

STACK GAS ( / -MOLE) (28.52) (28.58) (28.59) Cp PITOT TUBE CALIBRATION 0.813 0.813 0.813 DELTA P VELOCITY HEAD OF STACK "H20 0.618 0.594 0.589

GAS (mm H20) (15.700) (15.100) (15.000) DELTA P^(1/2) "H20 0.785 0.770 0.766 

### Ts STACK TEMPERATURE DEG. F 120 123 123 (DEG. C) (49) (51) (51) Ps STACK PRESSURE "Hg Abs. 29.69 29.69 29.69 (mm Hg) (754.00) (754.00) (754.00) "H20 -0.20 -0.20 -0.20 Vs STACK VELOCITY @ STACK FPM 2,706 2,659 2,644

CONDITIONS (m/SEC.) (14) (14) (13) As STACK AREA (SQ.INCHES) 2,711 2,711 2,711 (SQ.METERS) (2) (2) (2) 

### Qs DRY STACK GAS VOLUME @ DSCFM 40,947 40,065 39,996

STANDARD CONDITIONS* (DSCM/HR) (69,569) (68,070) (67,953) WET STACK GAS VOLUME @ WSCFH 2,771,371 2,709,230 2,693,938 STANDARD CONDITIONS* 

### Qa ACTUAL STACK GAS VOLUME ACFM 50,951 50,054 49,785

@ STACK CONDITIONS (m^3/HR)

. (86,566) (85,042) (84,585) Dn SAMPLING NOZZLE DIAM. IN. 0.250 0.250 0.250 (m) (0.006) (0.006) (0.006) %I IPERCENT ISOKINETIC % 97.81 98.5 1 97.9 * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 

### mm Hg)



### 08-203 B-13

# r • -

~ 

# • I ,. ~ 

# .

APPENDIX C
Calibration Data Eguipment Calibration Factor Calibration Date 

### Pitot Tube #53-5-1 0.813 10/23/07 Probe Tip #08-203-1 0.250 06/04/08 Dry Gas Meter #53-2 0.998 04/15/08 Stack Unit Orifice #53-2 04/15/08 Digital Temperature Indicator #53-2 04/14/08 Barometer #53-1 03/26/08

08-203 

### C-1

## ~

~ ~ I

~

~ 

# ~



# ~

~ a

. 1 i 

## I



# ~

~



# ~

~ ~ 

### PITOT TUBE CALIBRATION

Date: i Q 

### Time: 

# 1q n5 Pitot No.: 5

~ 

### 3

~ 

### 5 - 1 

### T 8 : - 72 

### OF Pitot Dimensions: 

## /w X_i5 e ~ 

### C• 0.990 P

~ d.



### Motor

. . Setting`'° fps

marlc Calibration

Standard Start End, Standard :

Average High High cal. Factor -

Low Low ~ 

### I,

Factor 7 20 c) , oq o o,4i D,82'y 14 30 o.20 0,Nq7 o.SoS 0,30 0< <"48 o.32'A . 20 . 40 o, 511Z 0,7Z9 0,6 0 5 0,51 o.'rI Lr , D, g2o 28 50 

### o; 55' o, n;5' to . 7N:2 . p. 8 z a
~ 

### qo6 n:
~ 

### tt ' ~ 

### o. SO o, goy o, SZ t 35 60 00 3`1y I , Zo P,oqs' D, ~~Q ✓ ~ j.2 , O ,1.075 p, s08 41 70 i.io (,Jo 1.oq 0 1 i,6a J.zis 0,S2f l,bo i.Z6S o,sz! 

### 50 80 i, 1, f 

### g3 Z•lo f.qr{g 

### C,Bca L, lo i.qqq 

### o. 508 62 90 /,sn J,So f,

~~ f2 ~ u.65 9,

~ z8 o,
~ i6 2•"70 1.6L13 o..BeS'

28 50. o .7y2 Fc6 o.sit " 0.80 0.8qq ✓ c:_82i 28 50 v.5'S o, ri5 d- 7qZ D, gz 0.ex , 6- o.
~ (1



### Average c: 3 t 

### 3 

## Summary of Results: Normal high side calibration factor 1 -3 '~ 

### variation + i , :3 s" % 

### ✓ variation - o o rf 15 "/L 

## Normal low side.calibration factor o: Si5 ~



## variation + variation - a • .3 E % 

### Calibrator: ~~ ~- ~ ~ c tti ~ 1 

### Checked By: VERSION 1 C-2 0$-203 22 OCTOBER 2002

# ~ ~~~ nYTML

NOZZLE CALIBRATION Nozzle Set No. 0~~ - 0 

### 3 Date ~ Ly ~ ~~ 

### Calibrator: 1 2 3 4 

### Reading 1 

### Reading 2 

## p.zyW

_ Reading 3 Q.LSo


### _ Reading 4 0- Z-SQ



### _ Reading 5 Reading 6 Reading 7 p. L5

- 0


### _ Reading 8 Reading 9 Reading 10 C9.L5 ~ 

### Average
7 8 9 10 

### Reading 1 Reading 2 Reading 3 Reading 4 Reading 5 Reading 6 Reading 7 Reading 8 Reading 9 Reading 10 Average 

### C-3 1: 1 5 0



### 11 12

VERSION 1 22 OCTOBER 2002

# i 1 .1

~
~ '' ~ ... .

b
. ,



## Dry Gas Meter Calibration Dry Gas Meter No.: Date:



# AH

~ .G pC,- 

### 0.5 ~



# o S5S 1.0 

# p. 1.5 

# /: ovo ✓ 2.0 3.0 4.0 05 3 ~ 

## Average Variation: + 6. 1 4 ~~- ~


# 2 a:o ~ 

### Calibrator: Checked By:

C-4 08-203

VERSION 1 22 OCTOBER 2002

# ~
,
_1 J 

# 1 Meter Number: S3
- 'L

## Date: DRY GAS METER CALIBRATION


## Calibrator: 2 w ,' (. •,) w--N


### Wet Test Meter Vms,, Calibration Factor (C oa ) = Dry Gas Meter Vmstd



## Run No:: 1 @ o• s° 

## ✓ p b: 3 o. zs- 

## "Hg Control Module Vacuum: 3" 0 

## "Hg

Wet Test Meter 

## (No. 2 ) D[y Gas Meter Meter Meter Temp. 

## I1II7e BeadiD9 IemR..
~ 

## „ Head

- 

## iA9 ltl 91dt .P_, r , End N-2t r • 0c7 " cf 33 °F "H 2 0 

### gn-Z'Le cf 

### kS °F 7y °F fl•.ra °H 2 0 Start 0 -c-a cf OF - 1•5 11 'H 2 O iIu. o cf 

### ~l °F IW °F 0- So "H 2 0 Avg. I1;2z

~ cf 73

~ °F ~ 

### ` i,sv "H 2 0 cf oF ✓ v•ssa "H 2 0



### 30.zr + 13.6 

## Wet Test Meter Vm s ~ 

## = 17.65. 

## x;• ~~ 

## o x ~, U ,~ 

## (C) _; ~ ~~ 

## 4 dcsf

~ 

### , 3 + 460

3~•2~ 

### 13.6 

## Dry Gas Meter .Vmsra = 

# 17.65 x~ 

## Z z ~ 

# _ ~ 

# ,1 ~ 

# 3 dcsf

-~ 

### y + 460

✓ C'DG - 

### S- /

. :~ 

### '4 

### = Q `5.r



# S.ld3 C-5 08-203

VERSION 1 22 OCTOBER 2002

### Meter 8eadin9 8 Z5. n S7, cf R 7- . 3 S`tZ 

### cf 

## S.zta cf )[y Gas Meter

Temp. 

## ln S2llt R.I. 

## ff~ °F -4y °F )• °e "H20 RZ °F .
-

1.4 °F 

## ~ "H 2 0 °F i• , Q "H 2 0 

# _)

~ 

### "H 2 0
- Z•4° 

### "H O

✓ 2

U 

### H 2 O 

# i ~ 

# . ..• . ~ 

# •

DRY GAS METER CALIBRATION
Meter Number: 53 - 7L
~ 

## Cafibrator: Date: L/-( ti



### - 

### Wet Test Meter Vm sm

Calibration Factor (C aQ ) - Dry Gas Meter Vmstd



### Run No:: 1 @ I
- °`' J 

### P b : 3 a• 2 S 

### "Hg Control Module Vacuum: S=o 

### "Hg

Wet Test Meter 

### (No. --2 Meter 

## Tltne Heading IemR... End S=64 S . l°o cf F Start 43 

### cf F

~ ✓ 

### Avg. S. I o o cf F

+ ` Z•lzy 3~ 

### Zs 13.6
~ 

### Wet Test Meter Vmstd = 17.65. 

### x 6.io ~ 

### x )-o,c, 

### (C) = S,tsg 

### dcsf }3 + 460

+ .°U 

### 3u. z. ~ 

### 13.6 ~ 

### Dry 

## Gas Meter Vm std

= 

## 17.65 x 

## s.z % 

## u = dcsf gv + 460



### CoG= S. sh = ~
- ~ 

### iy5 ~



### C-6 08-203,

VERSION 1 22 OCTOBER 2002

# ~

DRY GAS METER CALIBRATION
Meter Number: S'3 - L 

## 1 

## Calibrator: r~ 

### LJ• ' ~ ~ -~ 

## Date: 1 -1- rS ~ak 

### Wet Test Meter Vmstd



## Calibration Factor (C oa ) _ Dry Gas Meter Vm std

Run No.: ) @ r • c`' ~ 

### p b: 3 0. Z S" 

### "Hg Control Module Vacuum: S" o 

### "Hg
Wet Test Meter 

## (No. Z

Meter 

## T1nOg Haadin.9 IemR.. End 13.0% io•'o'> cf 71 °F Start. 0:4 4 b-,o 

### cf ° F Avg. I]:a ~ 

### w.t-v cf

~~ 

### °F 

## ____) 

## R. - 3 3 "H 2 0 -3,3 a 

### "H 2 O ` 3 , 3O"H 2 0 

## Q1y Gas Meter

Meter Temp. 

## HeadtaQ ln D-U.t E.

~ '► 

### 4•SI ~ 

### cf e10 °F 7S °F l•So 

### "H 2 0

~ u• ts 

### cf fu 

### °F 3q °F , 9
- " "H 2 0 /a•Ifro'

~ 

### cf ib ~ 

### °F 1 -s"(J"H 2 0

+ ` ]•7 ~ 

### . ° 13.6 

### Wet Test Meter Vms id 

### = 17.65 x i v. l v ~ ~ z 

### S 

### + 460 x l . o t 4 (C) = )o .
~ 

### y7 dcsf
~ 

### 3

+ 

## /•

~ 

## v Dry Gas Meter .Vmsta = 17.65 x/n ,2g b ~ °i Zs 

### 13.6 z o~ 

### dcsf 8v + 460

! o. ~S ~


### _ l. 

# C vtJu

~ 

# _ -

lv.Z

~ 

### t 

# C-7 08-203

VERSION 1 22 OCTOBER 2002

# PATm .e

:



### DRY GAS METER CALIBRATION

~ 

### Meter Number: S3
- 7- 

## Calibrator: Date: il- is- (3 b

_ 

## Wet Test Meter VmsId



## Calibration Factor (C DQ ) _ Dry Gas Meter Vms,,

Run No:: ) a 2-0 o. -z 

### p b: 30, Z s- 

### "H9 Control Module Vacuum: 3" o 

### "Hg

Wet Test Meter 

### (No. Z 

### ) prv Gas Meter Meter Meter Temp.

~ 

## m S' Hea.din9 IemJ. E Headin9 !n DJut R. End 1t 35 tu.u5 ~ 

### cf 

## 7 3 °F -z/.

~ 

### o "H 2 0 ~ 

### 35.k

~ 

### 1h cf ~j~ °F ~~ °F "H 2 

### 0 Start 0 :oc

, o-otie 

### Cf

~ - 3 °F 'q-oe 

### "H 2 0 ~ 

### ZS•543 cf L/ 

### °F l'f



### °F "H 2 0 AVg. u - 3S io-o5s cf ~~~ °F ~ - "H 2 

### 0 /o.Z&t 

### cf ~ 

### 3 L I °F 2 o6 "H 2 0

+ 

### y

~ 

### o 

### Wet Test Meter Vm 

## 17.66 x

~ 

## 0.05 s s°-ZS 13.6 

### x I•o► 4 

### (C t ) = fu.l 

# ~ dcsf 

## std = + 460

~ 

## 3



## D Gas Meter Vm 17.65 

## x 7S 13.6



## __ , ry std — CG • Z b l 

### + 460 ~0`~S~ 

## dcsf 

## g3

CpG = /0.1
-

4 '-( 

# _ 1 .00. - I,/ lU. (j 8 

## C-8 08-203

VERSION 1 22 OCTOBER 2002

### 1 

# , .~

. 

## ~ . .!



# ~ DRY GAS METER CALIBRATION
Meter Number: S 3- z' ~ 

## Calibrator: Date: 

## k Wet Test Meter Vm sm

Calibration Factor (C oa ) _ Dry Gas Meter Vm W

Run No:: t@ 

### ✓ P b : 3a 2s 2j 

### H9 Control Module Vacuum: °Hg

Wet Test Meter 

### (No. Dry Gas Meter Meter Meter Temp. 

## TiM Beasitnq Iemp., P Heading ln Qui P-1„ End ~ ;2q /o.Ia5 

### cf ?3 -F -S. sa "H 2 0

~ Uo.uSo 

### cf / o o °F 3g °F 3•oc "H 2 0 Start 0:"0 0.0oG 

### cf

- 43 

### °F

- S•go 

### "H 2 0 ?`I5.I ko 

### cf

~ 

### o_OF 3?- 

### °F 3 •-uo 

### "H 2 0 Avg. 5;2 ~ lo.r v ~ `~cf

~ 3 ~~ 

### F `S So "H 2 0 /0,3

~ 

### o cf ~ 

### E/ o F ~.~~ "~..~20

+ 

### `S•So

~ 

### o•zS 13.6 

### Wet Test Meter VmSid = 

### 17.65 x io. i o ~ 

### - x 7.011, (C) dcsf

~ 

### 3 + 460

~o~ 

### + ✓ 

### 3o.
- ts 

## Dry Gas Meter Vmsid = 17.65 

## x J v• 3 ~ 

### 13.6 

## o + 460 

## = 16' 1 3 S dcsf

~ ~

CDG= yO

### C-9 08-203

~ q VERSION 1 I 22 OCTOBER 2002.!



## DRY GAS METER CALIBRATION
Meter Number: S3 - Z ~ 

## Calibrator: Q 

### Date: 

## Wet Test Meter Vmsld



## Calibration Factor (C o(3

) _ Dry Gas Meter Vm std

Run No:: ) @ 4.0 0 ' ✓ p b: 3o. 2S 

### "Hg 

## Control Module Vacuum: Sc 

## "Hg

W t Test Meter 

## (No. ~_ 

## ) Dly Gas Meter Meter Meter Temp. 

## T .~~ Read! is.wK. E. uscaxuiid L1 yus L m End ~ :S3 /Z•.jco cf - 33 OF

- - 4•ob "H 2 0 b
- ~ 3,344cf fUl ° F }fs ° F tjlcn "H 2 0 Start O:oo o.oao cf - 33 o F - }.vo "H 2 O 9(.I u , f cf q,3 °F OF 4oa "H20 

### Avg. S
:



### S.7 — ~ –

,/ ✓ 

### Z•lo ~ 

### cf

~ 

### 3 O 

### F `

~ 

### •oo"H 2 0 ✓ 

### I Z.3 ~ 

### Z cf

~ ✓ 

### °F

f ~ ~



### t,

~ 

### uo°H 2 0



### 6 13. 

### Wet Test Meter Vm s ~ = 

### 17.65 x~ 

### Z. r

~ 

### :: x 1 , C) + 4 (C) = 17. r o ~ ~ 

### dcsf

~ 3 

### + 460

+ 1 /,00 

### Dry Gas Meter VmStd = 17.65 

### x I Z.3 ~ 

### z ~ 

### S 13.6 + 460 

### 1

. 

### ) 53'

~ 

### dcsf & ~



### CDG= 7 2• ~`~



### C-10 08-203

VERSION 1 22 OCTOBER 2002

### Mercury Temperature DTI CF ~

? 

## q 

# 3Z



# Zso

~ G c ~


# s3J
No ~ SZ "

Zjv ~



### 33 y v 

# ~ ~ 

# • . ' •

~ 

# . •

DIGITAL TEMPERATURE INDICATOR NO: S3 - Z. 

### CALIBRATION DATA

DATE:

Media Time


### Ambient Air 

### ~ 3 0 

### Ice Bath 

### ~ 3 s 

## Boiling Water 

# `%yy Oven ~ 

# q s Oven °C 1 ~ 

### Oven j o00 

### Oven /vrv 

### Meter Adjusted? YES
Reference Thermometer No. +4 ~ 

### Calibrator Checked By:

C-12 08-203

VERSION 2 15 APRIL 2004

# MEFCO.

BAROMETER CALIBRATION
Barometer No.

Date: Time: 

# s o ' l S

~ 

### Barometric Pressure @ Hobby Airport @ 45 ft. 

# _
- 0.045 Absolute Pressure @ Hobby Airport = ?>0' io! ~ -
+ 0.024 Absolute Pressure @ METCO (§ 21 Barometer Reading C ) < < ~ Variation Os' ~ Barometer Adjusted? Yes ~ No Barometer Reading (after adjustment)



## ~
- 

### Signature of Calibrator

C-13 08-203

VERSION 1 22 OCTOBER 2002

### APPENDIX D Field Testing Data

08-203 D-1

### E E



### r V 

### V w 

## L O

~ \

~ .0 O

~ a

a ~ ~ 

### 1 ~ ~ E y c w Ua C~ _d E ~ -~ J E N i U. ' C 

## Q Q n. U 5 li F



# ~ R t •' 0 G
~

~ 

### o c 

### U.

~

Y t~ m 

## L

~ U 

### E ~

.. 

### > > ~ a n. a 

### a l ~ 

# J N
V` 

# z M
~ ~ xo 

## O N
~ ~ 

## m a < 

## t ~ ~ Q L 

### ~ Q~ O 

# 0 ~ _ N 1 O z

L ~ 

# m ~ 

# ` O



# m E ~ 

## I z Z 

### ~
~ .. w 

### ~

a

_ J -°~ -°~ 

# ~ O

s" Q$ 

# U u) ~ 

### E °



### r
W ~ ~ Y n cC ;C J ! X 

# o a E z a ~C (

~ ~ ~ c 

# m w F 

# ; tL I 

### aQ c 

### ~ 

# y O I

c 

### l0 J + m + m m

~ 

### o 'm 

### z O 

### eo 

### m

~ O m, Q ~

6 

### 0 

## m
~ 

## °- > ~



### ob c 

# V z 0
1 M 

# , —' 

# N O a' z H p ~ 

## a 0 m ~ 

## a O-' 

## ` 

## t= ` 

## h V 

### :°

~ 

### o~ 

# m"

O ~ 

## o t3 O m

-

M \ 

### W

o ~~ ~ Q ~ 

### LL M o c O E 1 ++ > 3



### ~ 0 > a .0 

# m _ ... ~ 

## W

~ 

## y N 

## M U 'o ~ 

## d p ° m E :°. a> 3 m ~ 08-203 N O O N lY



### ~ 

### w z 0° a o i--

~ 

# O

~ 

# N Y 

### N 

### E
~



### m~

.. d a 

## 'o 0 - ~a E +0 

## °~ ,~ ,• r r h~, ~ r r~ ( 

## r r I ~. ~ ~' t 5- -

~ LL ~ 

## Q E c t~ 

## rn D.

~ 

### • r t ~ I~ ep 

# =a SE 

### W~~~ `°~9~ r ~ 

## l cV 

## tn ~t nh V)

0 H LL ~ VJ ~ 4



## N

> a ~9 

### a ~ N ~ j 

### I ~ `v 

### ~. 

### ~ a~ LLt`v9N NNN ~ 

### q 

### N~~N~ 

# J NNNNry r c`lC`l
E``O C Q ~

E~ Cm 

### c~ a ~ 41 D

~ 

### '~ ~A ~i P 

## >= N 

## N

~



## V N N In 

## tV N{v ni ti ~ 

## N N tV N N N

~ ° 

### ~ O 40 

### Q 

### ~ O 

### o 0° 

### ~ o ~ ~+ ~ ~ Q 

## m o m ~ ~r~ o O (r

. 

### d o O O ~ • Q Q b p 0 0 ~ 

# , P n ~ 

# - r o

✓ ~ 

# o a: . O 0 p~~ ~~~ LL c ~ 1 N ~ 

### m O N► O ~ ~-~ .~ 

### ~ ~ o p ~ tr a- 

### ~ ~.. ~n ~ N~ o o• ao



## ° E 'r
j tA
~ 1/~ l~n N Q c. i N N N
a 

### a ° ,u c 

### t



### IsT ,in er Box No. 

# ~ Im p, 

# 2 g 

# -

- ~ Impinger 1 r Weight Gain Fnal Weight 76 ? ~) Impinger 1 Initial Weight !3. f 

# ~ Increase Impinger2

~ ' I Impinger 2 Fnal Weight Impinger 3 

# ~ Initial Weight Incnease ' Impinger 4 2. Z



## ~ Impinger 3 Fnal Weight - 

### 7 Sa • ~ 

### g S0

2 ._ - Impinger 5
~ 

### ° 7 tni6al Weight 7
~ 

### 3•g V w = 

## ~ Incnease Impinger 6 

### lmpinger 4 Final Weight


## . - 73 8, y Impinger 7

Initial Weight • 7-3G_ Z- 

## ~ Increase ` Total 

## ~ 9 • 

## ~ = V M


## ~ Impinger 5. Final Weight 92 r(o P b = 

### Z'1• ✓ %CO z = 

### 11 • 2 ✓ Initiat Weight:::;. / 

## ~~ V. = 

### 3 

### a. 4, 3 ✓ %O Z = 

### -S ~ ✓ 

### (ncrease V w = ✓ °/°CO

~ 

### 27
~ 

### = ~ 1 

## l P. = 

### a. 5l t (/ ~ % 

## A'

"2 = Impinger 6 Final Weight Avg aP = A, = Z7 V1 ✓

Ini6al Weight ol 

# ~ ` `i` 7 ✓ p = b z

~ ✓ 

# ~ Increase Avg =. AP y•~~~ T, CU v C D = p. SL3 ✓ 

### Impinger 7 Fnal Weight P, _ 

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### ~ .9 

### ~ y ^ 

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### Q D-14 

## ~ I : 1

### 1



## ~ Irnpinger Box No. Water Weight Gain


## ~ Impinger 1 Fnal Weight 

### 7 

## /~~ Impinger 1 Initial Weight `/•S 1 Increase Impinger 2 I, 

### Impinger 2 Fnal Weight Impinger 3 3 

### ' d 

# ~ Initia! Weight 73J ~ 8 

### Increase Impinger 4


# ~ Impinger 3 Fnal Weight 7~ 

### 91 8 

### V. = g SO Z ._ - Impinger 5 Initial Weight 72 e, •$ V. _ l 

### Jncrease lmpinger 6

1 

### Impinger 4 Fnal Weight 6 Impinger 7 Initial Weight 

# ~ Increase

. ::: Total V.


# ~ Impinger 5. Fnal Weight. 

### 93
~ 

### 0, o P b = 

### 2 9, 7 a V / %CO Z 

# =~ Initial Weight::;`' ~



### ~ 

## a7 i V m = ~ /3• Z ✓ %0 2

. = Y ~ Increase 

## V. = 

### / %CO = 

# ~ P m = ~ 2 y a ~ °~°N 2 

# _ ~Y.~ Impinger 6 Fnal Weight Avg OP = 

### o. 3 95' v A. = 

### 27 ! ~ ✓

Initial Weight e,770 1,/ 

# D= 6,7,50 1/ 

# ~ Increase Avg AP = O T, = 

### 6.0 ~ 

### D P 

## = o ,9l3 } Impinger7 Fnal Weight P. = 

### — a.2o V 1-1 2 0 

### 29. (0 ° 

# 1 H J IniUal Weight T. = 7

~ °F 

## 5 38 

## v °R



### Increase T, = 

# I~ °F 

### S' 3 °R 

# ~ Moisture Content : ., 

# ~ %M =

~ 

### !/ 2 7 / M d = 

### ✓ o• 7- ~ 

## Mw

d = 

## a 9 . `I Z 

## - ~ 

### ,/

MW

~ Vm 

## — 17.65 P b + 

## Vm P

m 13.6 = 17.65 

## x y

3 

## .7z 1 A ly ~ 

### a9- ~ + 

### 13.6 ~ 

### /Z, 73 

### / V

sft 

## ' 2 

### ✓

~ d 

## T

m + 460 

## . ^ 

## _ 0

~ 

### 7/ 

### sc(m

- 7~ 

### + 460

~ Vw 9 „ = 0.0472 x Vw = 0.0472 x 

## Gl 6

- . 6 = Sq 7,6 1/ sft3 f % Moisture = Vw y „ x 100 = _ S, YZ 8 x 100 1 Vm, w + Vw 9 „ 1 /2, 7 3 / + S', Y t$ I V, = 5123.8 x ~•~~~ 5~ x (34 V~ pm 

### ✓ 9g. SfR


## ~ %I = 1,039 x 'Yz . 73 1 x 

### 58 3


## _ ~~ ✓ °1° ! 2. 

## zy, 2

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### x,8873 x 6o x(o,25

~ 

### ) 2-
` VERSION 1 D-1 -5 J 22 OCTOBER 2002 

### So, oSy V rx E/Il/v g ACFI4i. 

### sD L

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# j0
D-17 08-203Impinger Box No. 

### ? I " I
Fnal 

### 12 (F. Water Weight Gain Impinger 1 Weight Impinger 1

Initial Weight

- TLt 5 • Increase Impinger 2 Irnpinger 2 Fnal Weight _• 

### ~ Impinger 3

Initial Weight `~ 1 Increase Impinger 4 1J.8 

## Impinger 3 Fnal Weight


# - 7 K- 2- V 

## g SO Z ._ - Impinger 5 

## g 

# ' ~ Initial Weight V= w Increase Impinger 6 Impinger 4 Fnal Weight 

### 776 -O Impinger 7

Initial Weight Increase Total 

# = V . Impinger 5. Final Weight` ` 7 

### ~ ? `/ L 

### P

b = 0 

### v %CO Z = / I nitial Weight :` 

### `~lS~ V ° , = Y3 SZ a 

### ✓ 

### %O Z = 8 Increase V w = //0• / `/ 

### %CO = P. = 

### !, Z 3 ~ ~ %N 2 = Impinger 6 Fnal Weight Avg OP = ff q 

### ~ 5 'S 9 ~ A. = 

### 27 tt ~ 

## Ini6al Weight D.'766 r d g 

## C n = -6•7 Increase Avg AP = 

### $ T I = 

### 6 a ✓ C - P 

### Ar ~ 

### r. ~ - 

### ✓ O• $13 

## Impinger 7 Fnal Weight P, = "l~ 

### • Z 

# ~ FI Z O o?

~ 

# V

' 

## lig

Initial Weight 

## T. = 

### _BD °F —~ ✓ z °R Incnease T. = 

### 10 ✓ °F 

### V °R

Moisture Content 

### : , %M ✓ 

### 2- M d = d ,/

. y



### MW d = ~ 7

r '~ `~



### Mw = 

### 09, S 

### ~

Pb + 

## P 13.6

~~ 

### 70 + ?'?~ ~ /?.37 

# 6 ✓ sft



### p Vm

~ d 

### = 17.65 Vm = 17.65 x t/

~ 

### S 2 D 13.6 pb 

### cfin 

### T m + 460 

### 8 + 460
Vw o , = 0.0472 x Vw = 0.0472 x 

### // 4 -~ 

### = S,'/ 96 7 ✓ S 

### ft3 % Moisture = 

### Vw-„ x 100 = 

### S, i rd 7 x 100 ~ 

### - v %

---- ~ Vm, d + Vw 9a , 

### 5'Z,37/ + 5,467 vl 7bb D.9'/3
~ V, = 5123.8 x 

### 0_.76
-

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~ 

### 5, 6 x

~ 

### E'. s"

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### 1 97 , ~ 

## I

~ 

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### 1,039 x Y2 , 3 ' 2 (o x S ~ 

### 3 3 = -. ~ 

### % x a9,65' x C),

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~ ~ 

## yy VERSION 1 

### D-18 22 OCTOBER 2002 , 

### 19, 785`' ACFM: y-fg,,,e 39; SCFM: ~ %EA: 

### 08-203c

~

t~ d
Z

~ ~ 

# ~ ~ 

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# I

N O 0 N 

### a 

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# rr -

.. 

# .

; Moisture Saturation Table i l

I i I r

1 Temp.

( ° F) Saturation*

(%)

32 = 0.60 33 = 0.63 34 = 0.65 35 = 0:68 36 = 0.71 37 = 0.74 38 = 0.77 39 = 0.80 40 = 0.83 41 = 0.86 42 = 0.89 43 = 0.93 44 = 0.97 45 = 1.00 46 = 1.04 47 = 1.08 48 = 1.12 49 = 1.17 50 = 1.21 51 = 1.26 52 = 1.30 53 = 1.35 54 = 1.40 55 = 1.46 56 = 1.51 57 = 1.57 58 = 1.62 59 = 1.68 60 = 1.74 61 = 1.81 62 = 1.87 63 = 1.94 64 = 2.01 65 = 2.08 66 = 2.15 67 = 2.23 68 = 2.31 69 = 2.39 70 = 2.47 71 = 2.56 72 = 2.64 73 = 2.73 74 = 2.83 75 = 2.92 76 = 3.02 77 = 3.13 78 = 3.23 79 = 3.34 Temp. ( ° F) Saturation*

(%) 80 = 3.45 81 = 3.56 82 = 3.68 83 = 3.80 84 = 3.93 85 = 4.06 86 = 4.19 87 = 4.32 88 = 4.46 89 = 4.61 90 = 4.75 91 = 4.90 92 = 5.06 93 = 5.22 94 = 5.38 95 = 5.55 96 = 5.72 97 = 5.90 98 = 6.08 99 = 6.27 100 = 6.46 101 = 6.66 102 = 6.86 103 = 7.07 104 = 7.28 105 = 7.50 106 = 7.72 107 = 7.95 108 = 8.19 109 - 8.43 110 = 8.68 111 = 8.93 112 - 9.19 113 = 9.46 114 = 9.73 115 = 10.01 116 = 10.30 1.17 - 10.60 118 = 10.90 119 = 11.21 120 = 11.52 121 = 11.85 122 = 12.18 123 = 12.52 124 = 12.87 125 = 1122 126 = 13.59 127
. = 13.96 128 = 14.34 129 - 14.73 Temp. ( ° F) Saturation*

(%) 130 = 15.13 131 = 15.54 132 = 15.96 133 = 16.39 134 = 16.82 135 = 17.27 136 = 17.73 137 = 18.20 138 = 18.68 139 = 19.17 140 = 19.67 141 = 20.18 142 - 20.70 143 = 21.23 144 = 21.78 145 = 22.34 146 = 22.91 147 = 23.49 148 = 24.08 149 = 24.69 150 = 25.31 151 = 25.94 152 = 26.59 153 = 27.25 154 = 27.92 155 = 28.61 156 = 29.31 157 = 30.03 158 = 30.76 159 = 31.51 160 = 32.27 161 = 33.05 162 = 33.84 163 = 34.65 164
. = 35.48 165 = 36.32 166 = 37.18 167 = 38.05 168 = 38.95 169 = 39.86 170 = 40.79 171 = 41.73 172 = 42.70 173 = 43.68 174 = 44.69 175 176 = 45.71 = 46.75 177 = 47.81 178 = 48.89 179 = 50.00 Temp. ( ° F) Saturation*

(%) 180 = 51.12 181 = 52.26 182 = 53.43 183 = 54.62 184 = 55.83 185 = 57.06 186 = 58.31 187 = 59.59 188 = 60.89 189 = 62.21 190 = 63.56 191 = 64.93 192 = 66.33 193 = 6775 194 = 69.20 195 = 70.67 196 = 72.17 197 = 73.70 198 = 75.25 199 = 76.83 200 = 78.44 201 = 80.07 202 = 81.73 203 = 83.43 204 = 85.15 205 = 86.90 206 = 88.68 207 = 90.49 208 = 92.33 209 = 94.20 210 = 96.10 211 = 98.04 212 = 100.00

* At 29.92 "Hg (760 mm Hg) 

### D-20 08-2031

1 

# l i 29 24 Pitot Tube No. C P c o. d ~ J ✓


## ~ P p = ~9~ "fi f ~ ~ "Hg ✓

P. - 

### "Hz 0 ~j~ 

### 'H9 j A, = 27/ 

### ~ ~ in? Point 

### Number Percent



### Diameter Distance from

Ref. Po 

## ~ t 

### (decimal in.) Distance from Ref. Point 

### (ftactional in.) Port A



### AP/Tfa Port B



### APtr,ja Pott C



### OPlr,(a Port D



### APlrfa 1 Z•L ~ . Sz8 ✓ /'/a 093 

### 2 s. 2 `t. 8 ~ 

### Q ✓ y' 3 /~~ . Y81112j ~ sl nil l l l l l 

### 3

~ 

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### 2 z, 6

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### 7 . y
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### 41,

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### . 223 57'/y ~ 

### $ i --(
~ 11 12 13 14 15 16 17 18 19

~ 2,

/ ! ./ / / / Average oP D. Lf y.r Average dP' -2 

### 3 ~ Average T, 

## ~

~ a G °F Average a 

## 3
, r ✓ degrees 

### D-21 08_203 VERSION 1 22 OCTOBER 2002 ~ PRELIMINARY VELOCITY TRAVERSE DATA 

### ~ AND SAMPLING LOCATION DATA Job Number g98-2 0 '3


## ~ Job Name 

### 0x 1 4 y t w LS Samping Location 

### Sc CLkbe 

## I - 1~

~ Date 

## G I L

A ID8 Time Port A -- r Port & Inside Diameter (in.) 6 7 I Pott Z£ Wall Thickness (in.) 81 t`t t 5 ~ Inside Stack Diameter (n.)



## ~ SampNng Ports are 2 6 ft. 6 in.



## ~ SampGng Ports are ~ ft. 6 in. Stack HegM

__ ~ 3 ft. Samp6ng Port HeigM Above Ground ~~1 ft.
Port B Port C Port D Average



### ~ 

## 6 7

t' 3/ stadc diameters) downstream irom disturbance

(nlet, s o bend, expansion) 

### / t ~~ V stadc diameters) upstream from disturbar>ce 

## u~ t constriction, bend, e>pansion)

# ~ PRELIMINARY VELOCITY TRAVERSE DATA 

### AND SAMPLING LOCATION DATA Number 

### 6 S' Zo 3



# ~ Job Job Name 

### 0x.y u ~ 

### s Samp6ngLocation 

### 1rlean" 

# ~ Date ~ > '

~ 

### fa8 Time 

### Port A j Port & Inside Diameter (n.) 

### L7 1 1 - Port & Wall Thiclviess (in.) 

## g'

~ 

## y Inside Stadc Diameter (n.) 

# _I ' SampGng Ports are 

### 2/o ft. in. 

# l Sampkng Ports are ` ft. 0 in. Stacic Height fL SampSng Port Height Above Ground ~ 9 ft.
Port B Port C Port D Average 

## b

- 7 6?

~ 

### `/


## ~ s~ L3

~ / 

## ( s31 stadc diameters) downstream from d•isturbance 

### V (inlet,nsficti bend, expansion) 

### I, g stack diameters) upstream from disturbance

~ constriction, bend, expansion)

Point Number Percent

Diameter Distance from

Ref. Point (decamal in.) Distance from Ref. Point (fractional in.) Port A

AP/T,(a Port B

dP/f fa Port C

AP/Tfa Port D

dP/T,la 1 Z. 1 I JZ. ✓ 'ye 1/1( 1-6

~ lI / i L f ! l ! l 2 

### 8.2 y. ~ 

### l$ t{ 13f1 L ✓ .SZ..lII 1'6 Sb ltZll 3 ly. ~. 8.b`78 9 /~ ~ ,(.o n2 i /",/ ,b2 lrZDl 7 4 2z . f

o i, 278 )3 l i!{ v &q 11 2 21 b .a I 1 / b 5 3`}• Z ZD,OS 3 2o II /b V ,(oy lla/•

~ - G/G2 / 2 - I I I l 6 J~~ 3~•~SS 3S" ~~ ✓ .(,,S ^ l l'i 6/2 /© l l l l 7 ~~ .~I ~ 5 - ~ ~ 

### l 7 3 45 I1 i y .(0 12Z1 cF 10 lltt l- l! l l 

### 8 $S, s'

~ 

### , t73 5 p rb 

### , 7_/l22/ 6 r6 2 !!tl l
-- G l l l l 

### s 91, S S3. 93 3 .57 /NL/ 

### 12- , S 8 /!ZL/ O 10 9 1.Li s'?. ZZ 3 s - 7'/ S/ 211 7 , 61 / It

12 13 14 15 16 17 18

20 I l l l I l l l 21 22 23 24 Pitot Tube No. 5



### 3- S — 1 ✓ D 

## = 6.21 S - ✓ P, = 

### a g . 7 '

/ °Hg ✓ 

### P, = -p • Z - V "HZO 29• 6 ..7 ° Hg A. _ Z 71 1 V in? Average OP 4 , 5- y Average AP' a 

### 9,76
~ 

### S Average T, 

### °F Average a

~ ' - D degrees 

### D-22 0$-203 VERSION 1 22 OCTOBER 2002

# r+ - .

APPENDIX E Analytical Data



# , I

, ~ 

### 08-203 E-1>o ° N U ( M p O R ~ C6 O O) ~ 0

U (3 ~ V: m o 0 ~ o 0 

### o ~ ~

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~ O) O> O > > U o

- ° o O O 0 0

0 0 00 O O

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~ C N 7 p O C ~ cl) U

~

N
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~ N d

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V ~ O U') O M O ~ ~ M m l9 M < co H ❑ o o ° o 0 0 0

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~ o0 00 Ci

~ rn n ao v o ~ M ~ 00 I ~ V ~ ao

~ o v, ti Q N N N ~ c~ M N U W 0- O N I E N O N Cfl ` Qj N N N ~ U c` r v~ o~ ~~ W O I
- M ~ E N O N Qj N N N
0

~ SI N M N V N V

N 7 00 M h'R O(D p N N N N c7 N

~ N C N'I N

~ ct N V' M — M — c`7 a x Mc °) c r :3 — I N Ta R

~ X O O J N M



### 08-203 E-2n oQ rO (0 ❑ O O ❑

~ O 

### a L a) 3 c -o o y L x 

### .3

~ 

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mlyuo 

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p N ( > O ~ tn O t n II ~ 

### 2 U ~ m ~ 0 0 O O

0 0 O O O O



### ° O ° o O O
O O 

### ° o o ° 0 0

O O O O o O 0 0 0

OO o
~~ ~ o O O 

### m (D G Y C y ~ E 11 D. ~ ❑ ` [C to •o II ~ ~ U (9
~ E ❑ 

# m ❑ N O C7



### U

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### (n O O O

~ C

~ o U O

~ ui r ln c\i

N fV CD O) co M O O ~ N 

# ~

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N rn ~ r' U ° '

~

°• ) v ~ r` r
- I l o In ~ E~C6 o0 0 oi cfl

~ Q) O N OJ lf) ~ U W O O M ln O OD C+0 c`7 M E cD

O CI j lfl tf) O 0 E ° 

### ~ ~ M N 

### v~

M N 

### °c N o M N

~

N c N V N V N V .- ri — ri — co E

c`MC

_ O C ° I ~ 7 c• 4 ~, d ° ~ x O O J N M N

. y

~ l6 Q d C ~L
~

~ U

~ C lC d

~ U C d
~ ~ T 

# _

08-203 E-3METCc? ET3tTIROiJME;AITP? ~ Data Rev-oc.essed Dn 06I10(2008 08:31:98 S { 3ainple iJante: Rl I1-2 2X NCN S::.RB A Date: 06I0912008 13:52`94 { { Data Fi1e C:\DX\DATA\ANIqNB\0E-203\06-09001.D17 { I l;ethod : C: ;DX\METHc}D`.H

~ _I,2.h`ET { At_I ACi_Iress: i S;?stertt: 1 lnjeo'Lff: 17 DeteCtor:c_DM-2. I

~ { ATiaiyst AfCG ;'-oluunn: iyS 19 , 9rnm, STD 2-21-05 I}J At'ID (
i: aiibrat].oIL `JCi.iUltt

~ .' D].ilttion FolIit-s T?a'Le . ° iT

~ i7T

. ° ,trsp nrFa R6j = cF.

---------------------------------------------------------------- j ----- EXternal 1 1 9200 5Hz 0.00 11A.00 2000 i..oi(Ponetll. C.ePorT..; 0xLg}olieriTi

- ` ^

i Foilnd i:u't CsJri"Tj'Jn[



## - nt ArBa Heiarat Conceritr•atioli Tirtie N?rLc;? PU.(t

~ .. ------------------------------------------------------------

3.73 c,l in acid 559740380 57964582 2- 1 2.824

------------------------------------ 1559740880 [G i O
~ • T~ 'LC

~ '. ~3 JI 6~r~ VL feG.VL

~ ] =iie: 06-0=001 .^? 7Sample: F_1 I1-2 2:=' PJCPl 

### 7~ e 

### 60 50 4~ l
U3 

## 30 

## 20

10 

### A 

## 0 2 4 6 14

i

~ t



### ~ 08-203 E-4 

## 1METCO ENVIRONMENTAL. Data Reprocessed On 06/10/2008 02:32:01 1 Sample Nmie; RI 11-2 2X NC-li SCR-B A Date; 06/091 1 2 1 ,08 - 14:08:03 I Data File I Method I AC.-T Address: 1 1 Systerm 1 Inject'.; 18 Detector: CI IXM-2 1 Analyst I-VCG Colurim: AS14,4 , m8n,STD 2-21

- -05 !N ACID
Calibrallion Volwme Dilution Points Rate Star', ' 5 1top Area Reject

-------------------------------------------------------------------- External 1 1 4200 =Hz 0.00 14,00 20clo Courgoonent Repo•t: Components Found Ret Corqrjonent Axea Height r-'oncentration Time •ame

------------------------------------------------------------- 73 Cl in acid 5 6 0 4 7 2 5 2 0 5 8 0 7 8 1 3 61 2 2. 85 31

------------------------------------- Totals 5FC)47 , 520 580i8361 21 2, 8 31
File: 06-0900I.D18 Sample: RI 11-2 2X NCN SCR- B A -80 

## 70 60 5.0 U 

## 40

~ 

## I


## 20 10 0

Li 0- 

## 14 w4inuteS



## 08-203 E-5File: 06-09001.D25 q -amle: Rl 11-121 4K I

- .7CN SCR A-L!O PPI-I 

### 80 70 GCI 50 40 u 30

0 FIETCO ENVIR-ONMENTA• Data Reprocessed On 06/10, 1 2008 OL , ..JL;Gl Saimc-le. Nanie: Rl 11-2 4X MC-N SCR A+10 PPI-I Date: 06/09/2008 15:4s:47 i Data File ; I Method : --:\DX\ITMTHOD\HCT.2..METACI Address: 1 3ystem: 1 Inject#; 25 L---tector:C'DII- 2- Analyst JMCG Colum: A514,4rm,-3TD- 2-2

- 1-05 1-K ACID Calibration Volunie. Dilution Points Rate Start Stop

- 1 --e.a Reject

-------------------------------------------------------------------- Exterm;I 1 1 3900 5H2 00 11-3. 

### co 2 0 

### cl cl C,- griponent Report: Couponents Found r-c-t Coupo

-

fien

- '- Area Height Coricent-ration Tilme Name pprft

------------------------------------------------------------- 3.73 

### cl in acid 524599300 5492 , 1700 21,511

------------------------------------ Totals 5245913-00 5A 9217rjO Z1 .511

-n n 

### 1 -p 0 L Q 

### 6 10 C

### Minutes

08-203 E-6MBTCO ENVIRONMENTAL Data Reprocessed On 06/10/2008 08:32:33 Saniple kilame: Ri 11-2 4X NCK F-CR A+10 PPM Date: 06/09/2008 16:04:09 Data File C: Method C: \D.K 1 ,1- 1 BTHOD\ffCL2. MET ACI Address: 1 S•stem: 1 Inject*: 26 Detectox; CUM- 2 Anal j rst MCG Colimin: ASl4,4rvpi,STD 2-21-05 IN ACID Calibration Volwme Diltition Points Rate Stait -3top, Area Reject
-------------------------------------------------------------------- External i 1 3900 5Hz 0.00 13.010 2000 Couponent Report; Cummonents Found Ret Component A r ea Fe-ight Con cent rat i---xn Ttan Nalpave pril"A

------------------------------------------------------------- 3.73 Cl in acid 52 , 2943460 55272253 Z , I . ---; C, 2
------------------------------------ Totals 522943460 55272253 21.382
06-09001,D26 Swyln Rl il-2 4X NC-N SCR A+10 PPM 

### rIci



### 60 50 A .0 US 

### 30 20 10 0

i-k --k A 

### C, M it 

### mites

08-203 E-7File: 06-10001.D03 Sample: Rl 13,4 31 1 , NCN SCRB A 

### .140 

## 1 100 80 LIS 

### 60 40 

## 20 0 ME ETC0 EVVIRONMENTI-1 , Data Reprocessed On 06/10/2008 13:41:47 •ample Naine: Ri 13,4 3X IICN SCRB A Date: 06/10/2008 09:il;36 Data File C:\L_

~ ;\DATA\ANIONS\08-203\06-10001.DO:-3 Method C: \DX\METHOD\HCL2A. MET ACI ACidress: I System: I In
- ject#: = Derector:CDM-2 Analyst I-ICG Colurmn; AS14,4m, STD 1-1- 9 -01 50 iLL LOOP

Calibration voluitte Dilution Poi-nts Rate "tart Stop Area Peject- , -..: ------------------------------------------------------------------ External 1 1 6300 5Hz 0.00 19.43 2000 Coirponent Report: Coicoonerills Found Ret ComDonent A.re-a Height Concentration T- -ute Naitte ppift
------------------------------------------------------------- 4.02 Cl in NaOH 461162 1 070 10561903a 20.055
------------------------------------ Totals 461162010 105619038 20.055

-f c i 

### Minule-s


# 1 08-203 E-8Fil le: 06-10001

1 .DN Sarcfple. P.1 13,4 3 , X NCN SCRB A 

### 14U lu 100 80 60

zu 0 BIA 7 1PONYMENTAL Data Re-processed On 06/10, 1 2008 1-

1 :42:07
I Sample Name: RI !3,4 3X 1404 -CRB A Date: 06/10/2008 09:33:57 Data File C:\DY,\DATA\

~ ll"

- jNS\08-203\06-10001,D04 I-le-thod C:\DY,iME.Tfi--D"Hk - -L',A.1-IFT ACI Address: 1 System: 1 Inject#: 4 Detector:CUA-2 Analvst I-ICG Coltuiin; AS14,4ruci, SI'D 1-12-01 SO uL LOOP

Calibration Voliime Dilution Points Ralle "tart Sto-p Area Reject

-------------------------------------------------------------------- 'z 1 6300 5H 0100 i9.8 0 2 0 Ol 0
c r gc p r

, nen ~ Report: Components Found Pet CoroDonent Area Height Concentration -lime liame ppi - ft
------------------------------------------------------------- 4.02 Cl in NaOH 464899400 10221490- 9 20.214

------------------------------------ Tot-Ri ls 464899400 102214902 20.2
- 14

21 

## 14 16 is 

## Minutes

08-203 E-9-

' | /

-

' \ Mmroo ENVIRONMENTAL ' oeta nevc000aaw6 ou 0611012008 08.32,51 | / oomnzo mam*` az 11-2 za M-711 acxa A oate, 06/09/20010 14:23:23 } ' | oatm rize C:\ \08-203\06-090n1.o19 ( | arthod c`\oz\muzH»o\HrT j,2.MEr | i ! ACz audroos: z oyato-ni; z zu3eut#; zp ootoctor:ccM-o } \ / auazy-qt : *cG cozuxm , Aa14,4um,nzo 2-21-05 zm aV,7zo } oaliuroticm Vozuue oizntion poiuta aate ytazt
----------------------------------------------- outwrual 1 1 4200 ouo 0.00 °°+~°°w-p°+°+~°°°°*°** oompoueot nswort , oonq: , ~ oumnaat comVouout »ree oei«ut o zi

- fwa manie
------------------------------------------------- 3.73 oI iu acid 550609200 579MOn

________________________ Totml'o 555659200 57e2I208 Stor, Areaaeject '----------------- 14.00 unoo

- -o pomnu mcentratbon

PPTU

__________ 2%.7oo

_________ ~ 2.701 File; 06-0900z.o19 SaW-le: no 11-2 az NTCN

~ PB- a

~~

~~ ~~

03 10

~ 7 ~ 6 8 1 ~ 7 14 

## Minutes

08-2030 4 ~ 18 17 14 MEzC

- O EhTVIRCiNMENTAL Data manr000saod ou 06/10/2008 08:33-::4 | nanpuo mamv/ mz 11-2 oz »uoJ aonE u zmtm/ oo/ny/unox 114/38:42 | | oatu rii-e- , c ~\~~\o~o~ \amznmo\nn-000\on-opnnz.00n | | Metumd ) acz auureoo. I aystam: z zuject#: un uetoctoz: C911-2 ) | euazrat eme oozomu ~ ASl*,4mm.ozo 21-21-0

- 5 zmAnzD / cmziucatiou volum* oizotiou poiuta note Start atop azoa aojoct
----------------------------------------------------------------- o ~ tecuaz l l 4200 5oo 0.00 14.On zoVo nommoueot aenort: 000Voueuta rouuu aat coupouout axea Hoinut n0000utratiou zonCB maum rDR!
------------------------------------------------------------- 3'73 cz iu ooib 560503280 57801u76 22'.007
------------------------------------ roteza 55no6a2

, 8n 5710,01276 22.o57

80 70 | 60

)

| 40

) -D

1 ~ ' n



## Minuiv08-203 E-11

## 80

60 US

I ~~



## 20
0 Fille; 06-J-000l.D05 Sample; R2 13,4 4XI lq'CN ISCRB • 

## 120 METCO BNVIRONMENTAT,

Data Reprocessed On 06/10/2008 13:42:32 SaffiDle Naiiie: R2 13,4 4X MCN SCRB A Date: 061101
~ 008 09:56:19 I Data File C:\DX\DA, - A\ANION3\.08-203\06-10001.D05 Method C: \DY,\METHOD\.HCL2A.ME.T AC-I Address; I System: 1 In3ect#: 5 Detector: CDI- 4 1-2 Anal yst MCG Colimm: A314,4mim F STD 1-12-01 50 LiL LOOP
Cali'Dration Vollule Dilution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- Egternal 1 i 6300 5H2 0.00 i9.04 2000
cr maDonent Report: Components Found Pet Corcc-Onent Area Height Concentration Time Nwme pprIl'i

---------------------------------- --------------------------- 4.03 1,71 in NaOH 366536050 80748743 16.104

------------------------------------- Totals 366536050 80"[48743 1C-,.104



### Cs ? 

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## 08

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## 203 E- 1 

## 3I-IETCO ENVIRONMENTAL Data Reprocessed On 06/10/2008 13:43:07 Sample Nante: R2 13, 4 BX NC-N SCR A+5 PPM Date: 06/10/2006 12:11:35 Data File C:\DX\DATA

- \ANIO-NTS\08-203\06-1000!.Dl1 Method ACI Address: 1 System; 1 inject#: 11 Detectoo: clkpi? Anal•st 1 , IC G ColLmin: A314,4Rim, STD 1-12-01 50 ul, LOOP
Calibration Volume Diltition Points Rate Start Stop I—rea Reject
-------------------------------------------------------------------- External i 1 5850 SHz 0.00 19.50 2000 ConipoLent Report: Ccli

- cponents Found Pet Corip-onent Area Height Concentration Ti:tte 'NaMe ppm ------------------------------------------------------------- 1. 05 cl in 1 , ,TaOF 288017944 71429798 13,061
------------------------------------- Totals 288017944 7i429798 13.C

- 16i
File: 06-10001.D11 Sarc(ple: R2 i-3,4 8X NCN SCR A+5 PPM 

## 80 70 60 5 10 

## 40 3 1

. 1 

## 20 10 0

A 14 im b 

## 18 

## Won

08-203 E-14Data Reprocessed On 06110•2008 13:43:17

I Sancie Nanie: R2 13,4 8X JXTCN SC-R A+5 PPIl Date: 06/10/2008 12:32:26 Data File C: \DY\. Method C: \DX\METHOD\FK

- .T2 .A. MET ACI Address: 1 3

-

ystem: 1 Injecti: 12 Detector: CDM-2 1 Analyst * 1 1 4CG ColLiuLn: AS!4,4ri1R1, STD 1-12-01 50 iCL LOOP
Calib , ration Volu-me Dilution Points Rate 5ta1't Stop Area Reject --------------------------------------------------------- 7 ---------- External 1 1 5850 5Hz 110.00 19

~ 50 20cic , Coup•rient ReDort: Components Found Pp-t Cor(L- ponent Area Height •oncentration Til(le !-'alme ppift
------------------------------------------------------------- 4.05 Cl in NaOH 288451116 71446050 i3.080
------------------------------------ Totp-is 288451118 13.080
File: 06-10001.D12 Bwtcple: F- , 2 13A BX NCN SCR A+5 PP!i
00 

## 70 60 50 

## LL 40 210 20

c n 

### ? 1 

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### 4 

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## 14 16 

## minutet

08-203 E-150 ~ 4 8 1 ~ ~7 - | ' !

| »4Ez:o / oata meproceasou ou 06/10/2008 08:33:17 | | oaoyPlo »munm/ ma zl

- 1-2. ox mcw s«ya a oate/ oo/nn/onon ~~, 53`05 / ' | oalla piln o:\cm\oaxA\alizoNS\08-203\06-09001.D 1 ! ' | mothod C.\ou\mmraoo\mo

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~ ---_----------_-----'__---------------_-----------------_--__----_-- oxterual z z aeon 000 0.00 13100 znon coopoueut x ort: 000ponenta ruuuu

~ e*t Conmou*ut A-rea ooioht nouceutcatiou Time oaox, namn ------------------------------------------------------------ \ 3 '7 2 ol io anid' 29945124o 30948835 z3.366 / ------------------------------------ Totmla 2-99*s12«0 310948on5 13.365

~ 40

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### Minutet

08-20 ' '

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### mETo
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### } -------------------------------------------------------------------- mxtoruaz z z 3 , 631 oHo 0.00 121.10 uVnn nmxpoueut nomtpoueuta Fouuu ' nR-t Comwow*ut arem Hoinut ooucoutzmtiou

maoe ( --------------------------------------------------------- ) 3.72 cz io aciu 4,03073320 30725522 13.521 '

______________________________ Totalo 30a073a20 3U7co5oc l3.azz '

' 40

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### 7 4 1 n 1~

### wETCO

/ aanrjlo »xme; x3 13,4 oo 14Cm Sono a oate/ 06,110/2008 10:4-1:01 / | oeta rile r:\uo\uAzx\amzoma\0n-zna\:o-1nooz'o07 | | mothou ~ 

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### --------------------------------------------------------- 4.03 cl iu uaoa 211700506 501*7556 9.784

___________________________________ zotazs 211700506 50147556 ».7n11

70 

# so 50 ,S 40

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### t08-203 E18oote peprooesseu :u 00/10/2008 13:43.46

| Sanmue wame' az 13,4 oo mcN ooua A omte/ 06/10/20oo 11:oz:11c | | oeta rile / | | mathou : c: mar | | arz Addrmaa: 1 uystem: I zujoot§: V ootootoz ~ oz ~ +x |

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- 1 , -zz-oz uo uL L000 ! oozi»ratioa vozumo oIzutiou roiuta noto Stazt otop azaa aoject
-------------------------------------------------------------------- uutezumz z z 5911 I roo 0.00 I9.70 000O cmnnunout aePort , noopouento rouuu mot nomoouout r:oa Hoight comreutrax1ou zioe »mom paxn
------------------------------------------------------------- *.na Cl iu mans 2z2330z56 4 Si7o79n5 y.nza
------------------------------------ zotm
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______________________________________________________________ oxt*coal z z ouOU soz 0.00 14.00 2000 oompouout ~ 

### nanoct: comgpououta rouuu mat Commou*ut Acoa Heinht cnuooutretiou Time. mame nnm ------------------------------------------------------------- --------------------------------- rotala n o n.Onn

0 7 4 6 8 10 12 14 Win u 'tes

O8-203

### aoeco ENVIRONMENTAL 

### oeta mepuoceaood ou 06/10/200X 06:35 1:59 / Samnzm Namo/ a2304 ozamK--oCu A oute; no/nn/000a | Data rile ~ o~ 

### \oo\z

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### Ariazyst mco oozumu: aSl«,«mm.ozo u-uz-no Imaozo | caliuzatiou vnlnmo oizutiou Poiuta nete otart atcw Area Reject
-------------------------------------------------------------------- outocuaI z 11 4200 5uu 01.00 1*.1fiO znSJ 000C5ouout napol-t. oouwoueuto rm/ud mat Coug-poueut aroe oeiuut nouceotratiou zime aaote. mpif`
-------------------------------------------------------------

____________________________________ motmza O n 3.no0

20

~ 

### D

LlMETCO BNVJIROIRF6

~ NTX- J - '- Data Reprocessed Or, 0611012008 10:27: Sani ✓ le Name; NAoH BLANK--SCRB A Date: 06/05/2-008 -19,41:49 Data File : Me-thod : C: \DX\METHOD\HM2A. MET AC-I Address: 1 3ystem: 1 Inject#: 40 D -e-tector:CEIM-2

7, Analyst YiCG ColLmn: AS!4-, , djrffr,, STD 1-12-1)1 50 tiL LOOP
Calibration "Iolume. Dilution Points Rate Start 3,tu i p Ar & Re j -t

-------------------------------------------------------------------- Exte-rnal 6300 5Hz 0.00 21.00 2000 

# `~ FF

~ F'i FT tii T ~ f## r=Tr Crjr,° x

~ -'onent Report; Corq)onents Found Pet corf(Tjorlent

- 7 -z - ea Hc-i-ght Concentration TircLe- Name pprft

------------------------------------------------------------- To- a I s - C) 0 0,000 Fiie., OE5-09001,NO Swfiple , . •AOH BLANK—SCR-B A

r~ LI'D 10

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### 5 lu 

## M inutes

08-203 E-22pli



### } u5 | ' ENVIPONMENTAL

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- f It Couoeutretiou zima m

~ oo
------------------------------------------------------------- p ~ m 3.72 cl io aciu 257792800 27514436
------------------------------------ lz.sns Totala 257792

, n0O 2 , 75z4«3s 11.589

### 50

40 30 US 

### 20 10 0 -10 Fils: 06-09001,D24 SarfVle; Rl il-2 ix mrm srpp, R

### 60 IAETCO EIJViRC)k4MEkqTAJ,

Data ReProcessed On 06/10/2008 08 : 33 : 51 I Sam-pie Narfie: Ri 11-2 1X NC_K SC.RB B Date; 06/09/200a 15 : 35 ; 23 -----

" c R D

- qt a Fii C; \DX\DATA\AMIC*L3\0E -20.3 \06-09001 3 . D24 C:\DA\MET !-,OD1HC-T-2JIET I ACI Address: 

### i SYsteril: 1 inject#: 24 Detector: 

### vvsz Anal yst MCG C 70 l 'urim; —R-14,4rmI,5TD 2, 2 1-05 114 ACID Calibratioy, Volur j e Dilution Points R_ate Start Stop P-rea Reject
-------------------------------------------------------------------- Bxternal 1 3900 5Hz 0.00 13.00 2000 Ccrnvponent RePOrt: CONEriOnents Founid Pet Corttponent Area- Height Concer i tration Tirfie •Taimfle

------------------------------------------------------------- 3.72 Cl iri acid 257865080

------------------------------------

27485511 K.592 Tcltals 2•786500() 27485511 11. 5 92



### 12 IMinuftes

08-203 E-25

### 40

30

UL.
- 

### 20

10

0 I-IETCO ENTVIROR4ENTAI, Data Reprocessed On 06/10/2008 08:35:13 I San

- ple Name; Rl 11,2 2X NCN SCRB B+5 PP1 , 1, Date: 06109/2008 17:44:50 Data File : C:\DY ,\DATA\ANII,)k,'-q\08-203\06-09001.D33 I Me-thod : C: \DY,\MZTHOD\HCL2.MZT I ACI Address: 1 Systeni: 1 inject#: 33 Detector: I DFkl- 2 1 Analyst WG Column: A514,4mm,SM 2-21-05 1 IN AC-ID Calibration Volurtie. Dilution Point-r- Rate Start Stop Area Reject
-------------------------------------------------------------------- Ex l ternal 1 1 3900 5Hz 0.00 13.00 2f CoLm.p .oment RRport! Components Found Ret CoT(Poneht Irea Height- Conceritrati-on Time , Nawte PPI(I ------------------------------------------------------------- 3.72 Cl in acid 237317840 25008681 10.715
------------------------------------ Totals 237317840 25008681 10.715
File: 06-0900l.DI

-, '3 Sample ,

Rl 11,2 , 2 11 NCN IOCPP, B+S PP1•



### 0 2 4 8 10 J? Minutes

08-2 2 93 E-2620

U S qu

= Q 

# E

1cl

e ~ ~ 4 8 1a 12 ` auzon ENVIRONMENTAL

oata moprooe000d ou 06/10/2008 08:35:25 | aooipl* mame; nu 11,-1 uK »Cm ncgB n+s PmM zmto. os/oy/unoo 17;5e:1* ! | oata r1Io C.\oo 1 1cw:mA\Amznma\08-203\06-0900!,o34 | | anthod ' «:\oo\I

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- , ' u«o Cozumu. aez4,4mm'eT: 2-211-0* oxAcz» |
oal i13ratiou vnzomo oizotiou poiuta nate ytart nton aroa uejoct
-------------------------------------------------------------------- oxtorual z z 3900 ICaz 0.00 111.00 2000 000ipmueut aerjort: oouwoueata rouuu nat ocmw000ut arna neinht C

. ouceutratiou Timo uamo PPm
------------------------------------------------------------- J.7o c ~ iu aciu 2387oeano u 49

~ »zoz 10.776
------------------------------------ rotmla 238728300 24953I221 10.776

M irt 

### u te

### 14 1 ~ ~~



### 10
us 20

0 MEzCO cmta re-nz000aaod Vu oo/m/zonn 13:44-0T / aauoze m

~ 

### ne/ oz za'o Inu xxzx SogB a oate; 06/10/200n 11/23/04 | | oata ril* c:\oz\cmsA\aazoxm\ox-203\06-zo:nz.009 / | metuou c:\rX\MosHno\azLua'mEr | ! ACz Amuresa: z oretem: z zujoct#: n Eet 2 ) / xualnst »eC- e oolimm/ 1o14'4mm, azu 1,12-01 50 uL Loop | cmli»ratiou vozumo Dilutiou eoiota aate otart ntmnazeo nmjoct

____________________________________________________________________ ox ~o~ua~ 

### z z 5850 oaa 0.00 I9.50 11000 000poueut nemozt: coopnuoiita Fouuu uet oompouout arom aeiout ouuoeutratiou ri-ime mame npm ------------------------------------------------------------- 4.03 cl iu waua 74026314 1687s027 a.onn

------------------------------------ rotala 740263

, 1* 16875027 3.600~ MErCO

/ | aampze mamo/ pu 13,4 znr Nrm acno o oate` 06/z0/2008 11`50`43 /

~ | umta rize c:\oo\zAMzk\AmromS\08-203\ow-10n01.oIn | | methou c:\oz\

~ io:s

~ o\acL3a.yF-jT | ) aCz aumzeao: z uratom: z zujeot#: zn netoctoz:cz-1-1-o | l / A:alrot ` McG --oluoin' Ae14,4mm, aTo z-110-o1 , 50 uL zmon |
oalibratiou volume oiIutiou roiuta umte ntert | ---------------------------------------------------------------- aton x-rea ueloct | auterual z z c85n 5ac 0.00 18,50 20100 ComPouent manoct: oompou*uta coouu _] a*t commmuout area meinht oouooutzetiou

zinm msmm
------------------------------------------------------------- xPI» / 1.03 Cl iu

~ ------------------------------------

maus 73839446 I5659444 3.565 zotals 738n9446 zssoeu«* a.aoo

us 20

10

~ ~

~ 7 4 6 10 17 14 16 1p 

### Minutes

### 50

40 30 lis

' 0

0 60

7 4 6 8 10 12 oatu mewcncoamod ou 06/10/2008 08:34:Om | aoupl* uariie: ac 11,2 !-X mc ~ 

### acno a oato: 06/09/2008 16:47;17 ~ 

### | outa rilm / c:\oo\cAzA\omzoNS\0e-203\06-09001.o29 ( | aotumJ n:\oz\Moraoo\e(

- L2.moz \ | Arz Muzeya: I aratem: z zojectar: 29 netoctor`oom-o | / auazyst xeCo onzunm; Ae14,4mm,aM u-21-05 zm xuzco i Cmzibratioo volomo oilutinu eoiuta mato ytart otom x(rna xajmot

___________________________________________________________________ Euterual z z 5900 5oo 0.00 13.00 2000 000poueut **mort: oonpououta rouuu

~~~ 

### cnnwounut ar-oa oeight couooutratiou zi-Tae Name ppm ----------------------------------------------------------- 3'72 ol iu ooid 44Bo6579Oo 47230207 18.892
---------------------------------- cotalo 448067e60 47230207 18'89u



## Minutes7 4 6 0 10 12 /0

~~ us



## AD

~

0 60 _

} j

-

- aETm oata nemroceaoeu om 08/10/2008 ' | / aamnze wame' uu zz,o zn wc ~ acna a mam,; oo/oo/unon 17/01/40 | ' | oata rile r:\nz\zmTA\amzmIIa\0n-2n3\oo-09nOz.o":'V | i aetuuu o`\os\moraOo\ocLo.sZ -r i i xcz Aduroao: I Syotam: I zujoot#; am oetmctoc:nmy-o | | | aualrat / uCs ozlunm: Aul4,dmm,aro 2-21-05 zmaczD | oalibration volnme uilutiou puiuta nmte Stact yton Aroo nejoot { ---------_--_-------_------------_--_-__--_--_-------_-------------- uutocuml- l z - 1 , 900 5ar O.Vn 13.00 %nOO coupouout pxpozt , ocmwoueuta rmuuu -' nat comwoueut arem eoigut c000eutratiou

zimo aem ~ Dcm ~ ' ----------------------------------------------------------- i a.7 2 o l

iu aciu o45 2 oa9no 4 7z56ozx 18 .77e / -------------_-__-----_----------_- cotmly 44526

-

1 , 900 47a56018 18.77e



## Minutes

### MErro
na ~ 

### e ae ~ 

### cocoaaou on on/zn/unoo
~ 4 

### `a9 : 

### n 7 

### | namnze xiame: a2 13,4 so mom onno a omte; 06/10/2008 13:33:41 | | oate rile c:\Ux\opuA\emIoma\08-203\06-10001.oz5 | | Metuou o:\oz\MEzomo\aoL2x.MEc | | AI«z auureao: z oratem: z zujoot-lu: 1-5 ootootoz:ozI-u 2 | / auazyat / ano columu/ Aoz*,*mm, azD 11-12-01 50 uL zz"Op | nmlibuatioz volume oilution eoiuto aat* ntart aton azea nmjoct

____________________________________________________________________ axtaruaz I z snon ooz 0,00 15.50 2000 m*port: oouqpououta rouuu net compouout area ooi«ht oouoeotratiou zime mane zpi«
------------------------------------------------------------- 3.90 cz io mauH 237877032 50064109 10.838
------------------------------------ cotmza 237877032 50304109 1 1O.nao

~ 

### le. 06-1000l.o11

c Saffiple: a2 13.4 5XmCN SC

- PB a

FQ
40 .30

~ 7 ~ 1~ 1~ ~4 1~ 1~ ~ ~ 

### minufAsMETCO' B EN
- VIROMM-NTAL Data Reprocessed On 06110/2001 0 14:39:20 Sample N-mie: RL/ 123,4 5X kJCN SCRB B Date: 06/10/2008 13-54:32 Data File C:\DX\.Ci.ATA\ANIC)NS\OE , -203\06-iOOOI.Di5 Me-thod C:\DX\METHoD\HC-12A.KBT ACI Address: I System: 1 Inject#: 16 Detector;CDM-2 1 Analyst MC. G Coliuiin: A314,4nmi, STD 1-12-01 50 tiL L-0 OP

Calibration Volvatie Diluti-n -n Points P-ate Start Stop -
- krea ReDect

-------------------------------------------------------------------- Bxte•nal 1 1 5850 5Hz 0.00 19.50 2000

n oul p one nt Peport: CoTqponents Found Ret Cor(ponent I—rea Height Concenllration Tiffte N31fie PP-ift
------------------------------------------------------------- 3,90 Cl in NTaOH 235450912 52181387 10.730

------------------------------------
2 181 3 87 0 . 7 33 0 T o t a I a , 2 4 5 0 91 -

1- 2 Ic
~
F:.le-- 06-1000,1.D16 Semple. R2 1 - 3,4 5X NCN 5CPB E-1 

## 70 60 50 40 tis 

## 30 20 10 0

f - .



## 4 1

- 2 

## 14 16 10 

## Minutes

08-203 E-331 ~ ~8 MP,TCo
| aampzo wamo ~ n.2 13,4 zus mcN ocRB a+5 esM oeto/ 0*/in/2008 14/15:24 | \ / oata rile C/\oo\cAx

~ \xmzomS\08-o03\00-zonoz.oz7 { | *etuok-, --:\oo\

~ 1oTHoo\eoT,uA.ousr | aor Addcmau; z arstom: I ru1oct#; 17 uotoctor;oc14-21 | / Avalyst / uCo oozoum: Aozu,wmm, n.mo 1-12-01 50 uz z-)op /
oalibzetioo volume oilutiou roiuta nato otart _----_-_-----------------------------_--__--_----_-_-_-------------- aton acoa majont

~ \` outozuml z z 5850 5az 0.00 19.50 2000 ouupouout ueport: noopou*uta roxuu mnt nouwoueut u
~ oa oo
~~ ut couoeo

~ zaz i ou r1ne mame

. ------------------------------------------------------------- Pnm 4.08 «l iu maua 222100366 5I297692 , ------------------------------------ 10.253 \ zotalo 2221003(56 o12976e2 10.253
/ Fizo: 06-10001.oz7 aempIa; ac z3,4 10z mom Scan o+u pPMI

..

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, \ / 10 l7 14

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~ '

~ .| MinQ*e*;~

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### 80



## 70 60 50 40

~~ ~~ I-IBTCC) ENVIRONMENTA•

Data Reprocessed On 06/10/2001 0 14:39:49 Saniple. Name: R2 13,4 IOX NC.N SCRB B+5 PPM Liate: 06/10/2008 14:36;15 1 Data File. C: ! kDX\DATA\At4IC)N,3E0,R-203\06-iOOOI.DIB f Me-thod C.:\DX
~ MZTHOD\HC-L2A.M-ET I ACI Address: 1 System: 1 Injectn: 18 Detector;I-D rIff,2 i Arialy-qt W-G ColLirtin: A-914,4nurL, STD 1-1- 2 -01 50 uL LOOP
Cali ✓ ration Vol

luttie Di-lution Points Rate StaLt Stop Area Reject

-------------------------------------------------------------------- 1 5850 SHz 0.00 19150 2000 corcconent Report: Corrponents Found Ret Ccriccionent Area He - ght Concentration I _4 L L T , I iunte Naicte ppift
------------------------------------------------------------- 4.08 Cl in h'aOH 223441, 0 44 52 - 302385 10,314

------------------------------------ Tor-Als 221,441844 S-- oz-'

~ c .13 1 V I 10 13 14
E'ile: 06 

### - 10001.D18 low(ple! P..2 !3 r 4 10-K 

### NI.CN SCP—B B+5 

### PPM



## a 2 

## 4 6 el 

## 14 -1 6 18 tyl 

## inutes

08-203 E-352 4 6 P, 10 17 40

- 33 's

0

~ Gfi morCo oata ns-procooaeu ou 06/10/2008 08:34:23 / aamplo woxo: xn 11,2 zo mcm Soao m oate: oo/no/moo& 17/16:03 / | oata rile : C:\oo\cu :uA\xnzomo\0o-20a\06-09001.o3i | | Methou : c ~ \o7X\MFrono\m- L2.aoz ~ / aoz Atmroaa: I oyotom; z zuject#: 31 uetootuc:com-z ) | Auazrat / Mcu C-olumu: Ao14,4mm,Szo 2-21-05 zmAczo | Colibratiuu volnme uilutiom poiuta omto otazt atop Axee no

~ ect
-------------------------------------------------------------------- oxtorum ~ z z ayoo 5er 0.00 I - ~ .0O 2000 oomoouoot nm»ozt: oompuuouta rouud aet coxponeut axoa aeiOUt «ounoutration riue aam* mPI«
------------------------------------------------------------- 3.72 ol io ucid *68824120 48989363 19.315

------------------------------------ cotaza 4688241%0 48989363 19.1115,

08-203 E-36~

-

,

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-

,

` MEcCO oata maorooe000u oo 010/10/2008 08:34:40 | aanwzmxamm: R3 11,2 11 - mom ecRu a omte , no/oe/2oox 17/30 , 27 | i oata rilo c:\oz\ua:.A\ymznmo\08-203\06-0900I.o3u | | Metumd | aCz Addresa: z exatem: l zuject

~ ' au matectoe ~o~~ 2 | | auazyot / Moa Cozumu/ aa14,4mm,arD u-221-05 zm nozD |
oalibratiou volume uilotiou Poiuta nete otazt nton — 1--oe maject

-------------------------------------------------------------------- Eutozuaz z z 3900 5ao 0.00 13.00 z000 nourjouout napozt: 000pououts rouTid net comQoueut azoa oeiohc ronceutcmtiou ciote mume npm ------------------------------------------------------------- 3.72 ol. iu aciu 461903660 48614542 1e.0*2

------------------------------------ Totaza 461903

, 650 , 46s14512 le.n«a

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## Minutes

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~ MEzCC) ENVIRONMENTAL uatu xamrooamoed nu 06/10/2008 15:21:32 / namnlo meme: n3 13,* oX xCm e:nB a oato: 06/10/2008 14:56:25 | | oatm rile o:\oz\zP.oA\P.mzomo\n10-oon\ns-zonn1.oue | | metuou c:\oo\MoTH0n\aoL2a.Moz | | aCz addreys: z oyatmu: 1 iuJeot#: zp notactor:Cou-o | | Arialyat : MCa cozumm' x314,4mm, yTo 1-12-01 en LiL Looe | calibratiou nvluicto oilutiou poiuta nate atart atop aroa majoct
---------------------------------------------------------------- Euterual z z 55m uor 0.00 18.82 on30 oomc000ut aeDort; Com oueota rooud uet oomnoueut acea ooimut couoeutzatiou rime name mum ------------------------------------------------------------- 3.88 nl zn maou J73u47350 7076-2338 16.3e1

----------------------------------- rotala 3732«7350 70762338 I:.asz
File' 0

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0 2 4 6 ~ 10 1 ~ ~~ 16 le '`~~~~~-

08-203

# ! ~ METCO EINVIRONMENTA.L Data Re

- processed On 06/10/2008 15:21:46 Saxknle •ame: R3 13,4 5X NCN SCRB B Date. , 06110 1 1 2008 15,17:43 1 Data File C;\DXIDATA\&NIONII\08-203\06-lGOOl,D20 Method C:\DX

I \MBTHOD\HCL2A.MBT
3 kC.I Add-ress: 1 System: I Inject'r: 20 Detector; CIDM-2 Arialyst MCG Colunin: AS14,4nuii, STD 1-12-01 50 LIL LOOP
Calibration Volume Dilution Points R.ate Star - , Stop A-rea Reject

-------------------------------------------------------------------- External L 1 5850 5HZ 0.00 19.50 2000 Couponent Rp-port• Components FourLd P'2et Area Height Concentration T

- _rae Name PDM , -------------------------------------------------------------
1

~ 88 Cl in NaOH 367883650 7175263'6 16.162

------------------------- ----- ------

-- :6 Tota
- ts , 367 6 ,18-361 5 0 .7 4 7 " 26

~ " I G Ir2
Piie. 0 Serjple.: R3 13,4 EX NIC-N 3--RB B

D2 - - 1- 

## 80

bo 90 C tj 30 

## 20 10 0 0 2 

## 4 6 e 10 1 

## --) 14 16 18 Minutes



## 08-203 E-39

### MErCO BINVIRONPLENTAL 

### nata xaPcooeoaed o^ 0*/I0/20010 nn:ao:z« | oenplm maoe: ouaoo azA^m--ooau a nate: 06/0e/2008 10:*4;219 / | oata rilo c:\or\cAzA\amzmm-q\Ou-ooz\o0-oa0nz'cma | I matuou «:\oo\mmrmOo\eoL 1u.Mmc | | xCz auuzosu: z oyetam: z zujoct#: o ootmotoz;cz*-2 | I aualrat mco nuznmu/ aazo,«mm,aro 2-21-05 ov AzID / omlibretiou voztmte oizutiou goiuta nmto ntar', etop a—rea mejoot
-------------------------------------------------------------------- oxterual l uznn oao 0.00 14.00 21000 nomnomant manort: 000tpouoota Fouuu mut CooFJouout Aree eoiOht r-ouoeutrmtiou zioLe uwu* xPICI
-------------------------------------------------------------

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-------------------------------------------------------------------- Euteroaz l z 4200 oHo 0.00 14.00 2000 ocmwnmout nenort; ooupouooto rouud aet Cou

~ -ouout acea maight couoemtracium ziore aamo IwrIL
------------------------------------------------------------- ------------------------------------ zotals n o 0.000
rilo: 00-0

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~ ~ 4 R 1il 1 ~ 141 ' ` '( '

-- E-41METCO ENVIRONMENTAL Data Re-Drocessed On 06/10/ 1 ,008 10:21

0 :00
I Saniple Nanie. NAOH BLANK--SCRB B Date.: 06/09/2

- 008 - 2 0:26.30 I Data File : C:\DX\DATA\ANIONS\08-203\06-09001.D4

~ " Method : C:\DX\METHOD\F (- LZ-A.! , IBT AcIAddress: 1 System: I Inject#: 42 Detector: CEII-1-2 1.

- -nalyst I-ICG 11

- olLuiin: ASI4,4nwt, STD 1-12-01 50 ,LL LOOP
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-------------------------------------------------------------------- External 1 1 6•Q0 IcHz 0.00 21.00 2000 CoaTionent Report; Conip

- onents F;sund kiet C•T(trionent e a Height C-oncentratIon Tiifie Nelfic- PPICI
-------------------------------------------------------------
------------------------------------ Totals 0 0 0.000 FIle: 06-09001.D42 Sample: NAOH BLPSK--SCRB B



# us - 1 C.

N

10 15 210 Minutes


# 1 08-203 E-42'

)
) Muzoo -' uata aenzooeaaeu ou 06/10/2006 10:28:10
~ \ | oauwle Name: muOH azJAmK--ocRB B ooto` no/no/onon 20/:10/50 | ' | cmta File : c;\oo\cAzA\amzomT\0n-una\06-Osn0z.o*a | | Metum1 ; C

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~ acz aduceoa: z oyatem: z Iuject#; 41- oetootor;oL*+o ) \ | aualrst mco cuzumu: Aazu,«mm, IITu 1-12-01 on uL Looe | oalibzatiou vulume Dilutiou eoiutu nmte atart otoP Aree aojoct / --------------_-----_------------------------_----_--_-------------- `-/ Exteruel 1 z naoo sux 0.00 21.00 cnon Coowounut nm-port/ coopooeuty nuunu / '.` aat oompouout aroa oeioht Couooutratiou

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j.Izear r t - il . J f V 17 3 alttt = kes 

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oalibzmtiou volnmo uizutiou eoiuta ueto otmct etop Area najeot
-------------------------------------------------------------------- Eutoruaz z z 4200 5ao 0.00 14.00 2GnV 000p000ut neriort: Coopououta rouud mot oompouout aree Heiuht Counentratiou zinve memm nnm ---------------------------------------------------- 3.82 ol io aoid 7202827 n%O2 , 9n 0.50z
------------------------------------ rotala 7262827 ou0u9V 0.501

I ~ 12

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### inutes

08- 03 E-45_ /

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- »aencV ENIVIROYMBNTAL oata uo.Dcoceooed ou 06/10/2008 09:1

- 16:50 \ | oauw l o mamo ~ z pz*« c ~ zcv ~ ato/ oo/op/ 000V oata rilo C:\zX\uszA\amznmo\001-u03\06-nBn01.uO8 | | method C:\oo\eEz0Oo\oc-Lz.uoz | | arz auozeao: l Syutam: z zujocti: 8 moteotoz:cc?.-2 ~ ( | auuzyut Mce ooluom: a5z4,4mm,oTu o-oz-uo zx ACzu ( cozibzatiou Yolnmo oil-utiou roiuta xate ftazt ytop a-rea aejoot | -------------------------------------------------------------------- ) outeruuz 1 z 4200 5ox 0.00 I«.oG %0o0 ocmqpoueut usport: conipoueuts ruuuu ) .| aat conooueut xxoa Heiyht couooutrmtiou

zimo mmxe ppm ------------------------------------------------------------- / 3'72 cl iu noiu 15066751 1791853 z.000 

# _\

------------------------------------ Totalu 16066751 I791853 1.000

-

12 ' 10

- | A -/ ~

6 | yD / 4 '

~

( ~ 7 4 ^> 

## tAinutes

~ \ ~ 17 141el 14 `

- /
~ -' METCo EITVIRONTIMBNTAL ' oatm xoprocosaed ou 06/10/2008 09:37:02
- \ | aao p

a* yam e ` 2 . 5 nz 1 , 1 o~ !C v oate, 06 / 0 9/ 2nno 11:45/47 |

~ | omta File ' C:\uo\c

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~ \oo-%0J\oo-O9Ooz.o09 | | *otuwu ~ C:\oX\ ~ar~~ o\on

~ %.»osz | ' | Arz xuxnrona: z aystem: 11 zujent#: y neteotor:oom-2 ( uuazvat mnn oolumu/ AAolo,omm,aTu 2-21-05 zw m«zu /

- oalibrotiou rolume oiluziou pniuta nmto otert atoP aroa Dojoct | -------------------------------------------------------------------- / Eutoruaz z z 4200 5er 0.00 z«.On 2000 noopouout neport: ooutpomouto romud \ ` mot Corupoueut xurea seioht omuooutratiou Tiote mane xnon ---------------------------------------------------------- / 3.72 CI iu acifi 42583880 4012001 2.504

- ~ -_-----------_----_------_--_------ rotolo 42583880 4612 , 061 2.5o4

12

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# mi

08-203 E-47MR-TCo NITVIRONMENTAL Data nepcooesood ou 06/10/200e 0e:37;12 | yanw,zo xame , a peu cl z/n/ oate` oo/nw/cnon 12:011 07 / | oata riIo C:\ox\cmzA\AmIo
~ o\08-203\0*-09001.ozo | { m»thoU -C:\oo\mnzano\oz
~ %.mor { 1 xcz Audcoaa: 1 aystem: z zujyct#: 10 ootoctor;oDm-z \ I An*lrst / *oo Columu; A314,4mm,3co 2-21-05 zmaozo | oaIibzatiou volnmo oilutiou roiuta nate otazt atom acea Reject
-------------------------------------------------------------------- oxtocual I I 42 , O0 5H7- 0.00 14.00 2000 oomnoueut smmozt: onmpououta eouuu mot Compouent ezea Geigut nunooutratioo rinLe Beute zno« ------------------------------------------------------------- 3.73 cI iu aoid e2754080 9812325 5.049

------------------------------------ rotaIo 92754080 9812326 5.049

US ~~ =

~ ~ 4 8 10 12 14 

## Minutes

. 08-203 E-48- | | / ` `

' / »Ezco
~ _ _--_-__ uata nepzoreaood ou 06/10/2008 0e:317:23 U | aample m,me./ zo peFi f-L zcr zato/ ns/ox/conn 12/20/47 | omta rilo | Metuou C:\o3\mBzaoo\aCL,2.emr ~ i aC-z ureaa: z eratem: z zujooi-A; !z matootor:«oMj-2 > / | aualvst mcu oolumu: ao14,4mm,3rD o-12z-no 114 a:zo | oaziuratimu rolome uizutiou roiuta nmto otart atop area nm-ject ) --------------_-----------------------_-------------_------------_-_ out*r-ual l I 4200 5ao 0.00 z«.nV 00O Cnmwouout uspmrt: oumVoueuto rmriuu

~ nmt Coomuuout acoa uai«ut onun*utcutiou

~iu~ aaoe m ~~ . ' ---_-----_--__-_--_----------------_------------------------- / 3' 7z ol io ac ^ u 221 727 000 22 94 6 7 61 zn.ou0 ( '' ------------_--_------_-----__--__ zotal 'a 2 , 21727000 2
~ 946761 10.0110 \ ' 4U / ] ` '

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08-203 E-49 \METCO EWIROYMBNTAT, Data Re-pro•essed On 06/10/2008 09:37:33 3 1.5aniDle Name; 15 PPM LT, Ic7V Date: 06/09/200

. 8 12 , :36:07 Data File C:\DX\DATA\ANIC7N

~ "08-203\06-09001.D22 Method C:=K\MBTHOD\HC

- L2.1 , 1ET ACI Address: 1

1 Systeni: 1 Inject#: 12 Detector: CD, 11 -2 Analyst MiCG Column: AS14,4mm,STD 2-21-05 IN ACID Calibration Voluifte Dilution Poi-nts Rate Start Stop Area Reject

-------------------------------------------------------------------- External 1 4200 5Hz 0.00 14.00 2000 Component Report: C!,ort(Donents Fotind Ret C01(porlent Area Height C•ncentratioR Tiicte 1 , 1 4affLte ppla
------------------------------------------------------------- 3.72 Cl in acid 349514560 35567288 14.901

------------------------------------ Totals 349514560 35567288 14.901

b 

## 12 14 t-Ainutes er , File: 06-09001.D12 "ample: 15 PPIl CL icv 

## Eia 4'u' -i f , -3 

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## 203 E - 

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~ z7pIa
. . / ------------------------------------ zotazo 0265125040 64417913 25.443

' -/ 80 '
Go
- | ~~ - 40



## Minutes '

` - -' \ /

-' 08-203 E-51 - i ? 14METCC , r-MVIRONMENTAL Data Reprocessed On 06/10/2008 09:37:53 Saniple Name; 313.33 PPM 

### = !C - V Date. 061/09/2002 13:06:46 Data File C:\DX\r.,A.TA % ,ANIONS\08-203\06-090OI.Dl4 Method C: \DX\1

- 4ETHQD1HC-M2.14ET► ACI Address: I System: 1 Inject#: 14 Detector:CDM-2 Analyst 

### MCG Column: AS14,4nuft,STD 2-21-05 IIJ AC-ID
Calibration Voltufte Dilution Poirits Rate Start Stop Area Reject

-------------------------------------------------------------------- ENternal 1 1 4200 5Hz 0.00 14..00 2 1 000 Comr- , •ue snt Report: Conponents Found Re-t Comporient Ax

- ea He'Lght Conceritration

~ ime I-Tame pprt , ------------------------------------------------------------- 3 34.716 ,73 Cl in aci-d 863047680 86861410

------------------------------------ Totals 863047680 86861410 34,716
Fi-le. 06-09001.D14 S-

~ uanle; 33.33 PPM C - 1 !- V 

### 1 

## 2-ri

6 - 0 60 us 40 

## 20 0

-1 0 

## 2 4 6 8 i pi 

## 1? 14 minites



## 08-203 E-52METCO BNVIRONMENTAL cmto aworoceaved ou 06/10/2008 09:38;07 \ | oaripuo Narfie: uo PPM nM CHK STD Dalle: 06/09/2008 13/22:04 | ' ( oata rilo c:\ca\cocca\Awznm'Z,\oJ-%OJ\0h-n9onz.ol5 | ( Ile-thou | arz Audreau: l orotom: 1 zujeot*: 15 Detector;ccaA,c | | / aumzrst / MCe coiuonri/ xaz4,4mm'aru2-2I-05 zu ~ czo /
' noIibratiou voznmo oiluticm Poiato aato otart atq*p -Acea majeot / -----_------_--_--------------__---_--_-------------_-----_--------_ mutocual I z 4200 3Hz 0.00 1 14.00 2000 Coupumnot nepnrt; noorpuuouta rouud |
~ nmt Compoueut aroa oeiout couoentratiou n/o r±om mane Ppm A ~ ------------------------------------------------------------- \. ' /^~~ ( 3.73 ol iu aoid *87132660 51349630 %o.Ooo ~

. ~ ------------------------------------ cotuza 487132660 51J49630 20.036

/ 40 ( / ~ S ~~ ~ O

20
10 '! ! / Ff ` G Q 1C, \ -

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~ ~
/ `| j 08-203 E-53 1 - ~ 14METt=t, Etr'VIkClNitENT1iL Data ReprocessedOn 0£I10l2008 0-9:318:18 L I Sample PJanie: 20 PPR4 t_ 

## ~ C.HI{ S TD Date: 06I09/2000 13: 3 7: 24 1 1 E Data Pile : C:iDX\DATR\ANIONS\04-

-
~ , 0 1 1\06-09001,D16 1 1 Method : C DXl.METHOD\HCL2.MET ; l i

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------------------------------------ Tr,tals 487756640 51113486 20.060

1 Fiie: 06-00001.D16 Sartple: 20 PPhi CL CHK STD



## 50

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- 4 ~ ~ 1~ 1~METCC) ENVIRONMENTAL Data Reprocessed On 06/10/200• 09:1 1 8:43
---------- Sainple N-me: 20 PPM C
- L CHK STDICCV Date; 06/09/2008 16:32 , :54 Data Fi-le C:\DX\DATA\A.NIONTs\08-203\06-09001.D28 Method C

- : \DX' , lMzTffODlxHC--2.MBT ACT Address: I -lysteni: 1 Inject#: 28 Detector: CDM-2 Analyst MCG Column: AS14,4mrn,STD 2-21-05 IN ACID

Dilution -voints Rate start C&1 4 -rat.

- 'Lon Volurae Stop Ar

~ a Reject

-------------------------------------------------------------------- 1 3 , 900 5Hz 0.00 i3.00 2000 Component Report: Components Found

Y

- e~ Corciponp-nt I - L J- , I Ax

- ea Hej-gh
~ ~ oncen

~ rat 4 on

~ r: ime 1-lanip- ppift

------------------------------------------------------------- 3,73 Cl i-n acicl 488001020 51- 5 13967

------------------------------------ Totals 488001020 1 5 1513967 20.070
-Fille. Sarop-le: —90 PPxM C7— CHK STDICCV 

## 60' 53 

## 40 21) 

## Us 

## 20 10 0 -10 0 2 4 

## 6 Minutes



## 08-203 E-56-

— /

- / j
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~ | oax ~~e m~oo~ ~ rp~ cz rcv oa ~ o/ oo/n9/uonn zo

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### i ----------------------------------------------------------------- / muteruaz z l 3900 5ox 0.00 13100 2000 000pouout aenoct , Comnoueuta roouu ) net ~~o~ ut urea ooightmmnentratioo zinte meofte . nmTL
------------------------------------------------------------- | n.70 oI iu ociu I60740e5 1779445 i.Vnz rotala 16074095 I77e445 i.001

-

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-

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## Minutes

### 40



## 20 Us
10

a Fi- -, e. , . 06-09001,D36 Sarciple; 10 PPM CL CC- - V 

## 40

4 6 8 1 

## 12 METC0 BNVIRONMENTAI , Data Re-processed On 06/10/2008 09:39:04 Barimle Narcie: 10 PPM Ci

- , CCV Date; 06/09/200• 18:"&: Vz , I Data File (7;1DXlDATA , ,AN!Oklb'lfjl,'-

~ 03"0u-09001.17

~ 36 Method C:\DX\METHOD\-HC-L2.MET ACI Address: 1 Systera: 1 Inject#: 36 Detector:CUM,' , Analyst -MCG Column: A-;14,4nvt,,--'TD 22-2j-05 IN ACID
Calibration Voltime Di-ltztion Points

-------------------------------------------------------------------- Rate Start Stop Area Reject
1 1 3900 S-Hz 0.00 1-3.0n 21 C , 0 0 Cf-;Joporjent Rqp-ortz Components Elound Ret Components, A-rep Height Concentration Tiicts Name

, PPICI 3. 7 2 Cl in acici 2 2 , 15 9 62 r,- ri 2 2 - -- 9 9 4 10.045

---------------------------------- Totals 22

, 1596260 2-2297094 10.045



## Minutes

08-203 E-58~
oeta oe-pzoceaa*U oo 06/10/2008 09:39-12 | aempin maime/ 25 PnaoM ocV oatm' oo/nn/onon 18/42:26 | | oata rile o:\oo\unoA\amzomz\08-

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-------------------------------------------------------------------- oxteruez z 1 3900 sHo 0100 1n.00 unoo 000

~ ouent Deport: oonVoueuto ronud aot nonipouout aroa nnioht ooucoutraticm zime muue rpm ------------------------------------------------------------- 3.73 nl io aoiu 615318840 63751705 25.003

------------------------------------ rotalo 615318840 63751705 21a'11

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nolibretiou volziine oi1utiouPoiuto aato etazt etmp- 11'eo aejoot / ----_---------_---------------------------------------------_------- / Extorua1 z 1 anoo ooz 0.00 za.ay 2000

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-------------------------------------------------------------------- oatorual 1 z nnno 5uu 0.00 211.00 2000 000ipooaut neport: omxpouoata rouuu aot commoueut aroe ooight Couoeutcmtiou cima Nsiae Ppm
------------------------------------------------------------- 4'23 ol in meuo 7956200 23895-99 0.504

____________________________________ zotula 7956200 2389529 0.50*

10 8 6

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## Wiinutes

### MErm ENVIRONMENTAL 

### uata xopcoc000ed oo 06/10/2008 10:28;51 / oaomuo None/ z npm oz zmr omto/ 06/0e/2008 o1`a3'310 | | omta rizo o:\oa\oauA\amzoma\08-203\06-09001.u45 | | eothod C:\oo\M9Taoo\Hz1,2a.1az ~ 

### | acz Auureoo: z oretem; z znjeot0: 45 Detector ozIA-2 | | Aualyet / uCo oozumu` ae14,4mm, arD 1-12-01 50 uo LOoe | omIibratiou Volomo nilotiou eoiuto natm atart otonarea majoot -_------------------------------_---------_----------_----------_-_- outerual z z 6300 5ao 0.00 21.00 2000
nnm
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### ouout gmpozt: ooummueuta rouuu a*t Cooponeut azem oeioht oouooutratiou rime naite Mm
------------------------------------------------------------- 4.23 Cl io u*ns 1e241360 4280o27 1.002

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### Moroo ElAURONMENTAL 

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omziuratiou rolume oilutiun Poiuta
------------------------------------------------------------------- mate atmrt aton azoa n*jeot

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### z 6-Ao0 5ox 0.00 21.00 2000 oompoueut nxmjort: 000pououta rooyid not C-nni7joueut Azoa oeioht couoeutzatiou ziom maum
------------------------------------------------------------- ppin 4.22 Cz iu uana 49137460 120744207

____________________________________ 2.499 ' zo
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## If

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### 5 10 70 MinW

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### :~ ~ 1~ 15 7 ~ MErm BNWIRONMENTAL oatu maprocesueu ou 06/10/2008 10:29:14 aanwle Name/ u peu oz zcv zmto: ns/ne/onnn 2o/11n'11 / | oata rizm C:\oo\cmz— I\e

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_ --------_--------------_-----------_-----------_-_--_-------- n«ox | 4.22 nz iu maoa 102283n74 > 2»u897oo 4.8*7
------------------------------------ zotalo zn2

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_ oata maproceaaeu ou 0611012008 10:29:31 | / aaoipzm mame; 7'5 pxM

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Time muoe nxTCL
--------------------------------------------------------- | 4.ou cI iu maoo 1611 5 40 5 0 38139000 7. 506 / ------------------------------------- zotalo 181164050 aoiosVnn 7.506

50

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20

10

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~ ~ 1~ 15 20lu File: 06-09001.D49 Sample: 10 PPM C

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## 60 59 40! 

## 30 U-a 2u



## -10 =20 

## 0 F, -1 ? 

### al MDTCO BNVIRONMENTAI, Data Reprocessed On 06[1012008 10:2a:44 Saiiiple liazie: 110 PPM C. - J, IC-v Date: 06/09/200ti 23:02.r. ~ Data File C;\DX\DATA\ANIONS'loB-20'\06-09001.DI9 Method C: \DK1METHOD1HCL2- I.MBIX ACI I-ddress; 1 Systemi: 1 Inj-ect#: 49 Detector; CEN-2 , AnaIVS

- L MCG ColiLmri: AS14,4nm, STD 1-12-01 50 ViL T-OOP
Calibration Volume Dilution Points Rate •tart stop A-rea Reject

-------------------------------------------------------------------- ExternAl 1 1 6300 SHz 0.00 21.00 2000 rCojtponent- Pe-port: Coicponents Fourid Pet Component, Area Height concentration Tinto Narfte PPlli
------------------------------------------------------------- 4.22 1 Cl in NaOH 218012704 52441800 110,069

------------------------------------ TotAls 21,2012704 52441800 10.069



## 08-203 mmu

~ 40 100

~~
N" uozCo ENVIRONMENTAL oata meprou0000d ou 06/116/2008 10!29:5 -8 } yamnlo mame: za ppm CM zor omto` u6/nn/2'non 23;25:113 } | Deta rilo ; C:\Do\cmsA\eNzomo\o8-20a\01- =-090nz.o50 ( | mwtuoa ; C:\oo\mozso )o\oz.--oA.emz | ! aCz Auuzeao: l enntem: l zujeot#: on uetootur`CcM-12 , | | Aualvst ] , K-'s oozumu' ae14,4mm, ero 1-121-01 ou uL Looe | oaliuraticm volome oizutioo Poiuto nate atazt nton Aroa nejoot
-------------------------------------------------------------------- mxtozuuz 1 z el 3100 oax n.nn 21.00 uoon compoueut peport; nompououto pnuud met CcmDoueut aioa s*ight couooutcatiou rinm momo mpm ------------------------------------------------------------- 4.22 Cl iu maoH 335II0754 82622500 zi.701

------------------------------------ rotuIa 3351-10754 02022600 14176z

~ ~ 1~ 1~ ~O~ ~

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~ roueouo ~ ou n*/zn/unnX 10/30/15 ' \ / Somple.mame: uu pzY.cz zcv oate: oo/oy/onoo oa`m:a« | ' ( ooca rile / «/\oX\couoA\

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~ uterual l z 6300 5ao 0.00 21.00 2000 oomPoneut neport: oomnomouta rouud ' mat oompoueut aroo oeiout couooutratiou zime Nlaote- PcUI
-------------------------------------------------------- | 4.22 ol iu maue 464956328 1!3973348 20.u16 / --------------------------------- zotala 4649566

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## 0 30 MET"o BNVIpIOI , ]MFjNJTAL Data Reprocessed On 06/1012001 0 SanTde Name: 5 PPM C.I. CHK STDICC.

- V fiate.; 061 1 ICY12 , 008 13:12;4 - 1 , Data File ; Method ; C: \D7,\ME.THOD\Hc

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### ci 1 1 ; Canponent Reaort: Conponents Found Ret Component Area Height Coricentration Tiicte Niame 1- IrDift ------------------------------------------------------------- 4- 9 2 Cl in 1 , .TaC7H 1041196- 2 0 25742317 4.981
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## 08-203 E-76L 

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------------------------------------ Totals 2191521976 S 1 2- 0 5 - 10 b iri. 008
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______________________________________________________ oxtoruaz z 1 5850 5az 0.00 19.50 onoo comno - neot mepmzt: oompooeuta FCuuu net nonmoueut acea aoiobt nouoentzatiou zime maxe mvm ------------------------------------------------------------- 4.25 Cl iu Maoo 578068578 .11731 , *9*4 25.0%z
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------------------------------------------------------------- - 4.2 1 5 Cl in J-,TaOH 1104168670 2457416.5 4,983

------------------------------------ Totals 104168670 24574165 4,983

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## 08-203 E-81

# ,RJCCA CHEMICAL COMPANY I Arlington, TX 76012 Pocomoke City, MD 21851 Batesville, IN 47006



# ~ ~ 

### ^ Certificate of Analysis httP://www •riccachemical.com

~ 1-888-GO-RICCA Wstomerservice@dccachemical.com 1Chloride Standard,l mL = 1 mg CI-, 1000 ppm CI- (0.0282 Normal) Lot Number: 1703163 Product Number: 1955 Expiration lTate: AUG 2008 Manufacture Date:3/12/2007
Contains I Name CAS# Grade Sodium Chloride, NaCI 7647-14-5 ACS 

# ~ Water, Deionized, H20 7732-18-5 ACS, ASTM D 1193 (Type I), EP, USP
est Name Assay Method Specification Result



# ~ Appearance Clarity, Color, Odor Clear, colorless, odorless Passed Test Assay at 20°C (traceable to NIST Tttrimetric vs. Silver Nitrate (Potassium 1000 t I ppm CI 1000 ppm CI SRM 999) Chromate Indicator)



# ~ pedflcation Reference Method Number Chloride Solution Stock (1.00 mL = 1.00 mg ASTM D 5542 chloride) Chloride Solution, Stock (1000 mg/I,) ASTM D 512 C



# ~ Standard Chloride Solution, 1000 mg/L APHA 4110 B Stock Chloride Solution APHA 4500-C1- E Sodium Chloride Calibration Standard (1 μg EPA (SW-846) 9023 

### l C1-/μL) { Sodium Chloride Calibration Standard (1 μg EPA (SW-846) 9021 alolide Stock Solution (I.00 mL = 1.00 mg EPA (SW-846) 9056



# ~ Cl-) Sodium Chloride, NaCI, stock standard EPA (SW-846) 9047 solution Chloride Calibration Stock Solution (1,000 EPA (SW-846) 9212 

# 1 mg/L CI-) J Chloride solution (1000 ppm) TAPPI T 700 om-93 Chloride solution (1000 ppm) TAPPI T 699 om-87 ] Sodium Chloride Solution, 1 mL = 1 mg Cl- ASTM D 4458



# ~ Chloride Stock Solution (1.00 mL = 1.00 mg ASTM D 4327 ' Cl-) Chloride Solution, Stock (1.00 mL = 1.00 mg ASTM D 5996 

# 1 Cl) ,Volumetdc glassware complies with Class A tolerance requirements of ASTM E 288 and NIST Circular 434; it is calibrated before first use and recalibrated regularly in accordance with ASTM E 542 and NIST Procedure NBSIR 74-461. Balances are calibrated regularly with

, Neights certified traceable to the NIST national mass standard. Thermometers and temperature probes are calibrated before first use and `ecalibrated regularly with a thermometer traceable to NIST standards. AII products are prepared according to master documents that assure manufacture according to validated methods. Batch records document raw material traceability and production and testing history for each lot manufactured. 

### j ,helf Life (unopened container)

, 1 Part Number Shelf Life 1955-4 18 months f1955-8 18 months 

## 1Z 55-16 18 months orrtmended Storage: 15°C - 30°C (59°F - 86°F) i 

# l~ Versiun: 1 

### 08-203 E-82( Joan Lutkenhaus ) Director of Quality Assurance and Regulatory Affairs



## ~ Tl#i:ertificate of Analysis is designed to comply with ISO Guide 31 "Reference Materials — Contents of Certificates and Labels." To determine manufacturing site using lot number, visit www.riccachemical.coMAboutUsllot.pdf.



# ~ t Version: 1 

### 08-203 E-83

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08-203 E-87

# MEFCO.

APPENDIX F Plant Operational Data

08-203 F-1Acid Circ Soft Water to Acid Caustic Circ

June 4th, Scrubber A Stack Flow Rate Acid Section Strength Flow Time ACF gpm gpm % gpm 1130-1238 2025000 398.58 96.66 7.96 2250.08 1321-1432 2034000 398.58 96.80 7.88 2250.08 1508-1616 2028000 398.58
. 96.89 7.84 2250.08 Average 2029000 398.58 96.78 7.89 2250.08

Acid Circ Soft Water to Acid Caustic Circ June 5th, Scrubber B Stack Flow Rate Acid Section Strength Flow Time ACF gpm gpm % gpm 1005-1115 2016000
. 394.95 94.18 7.70 2597.66 1143-1253 1975000 394.95 94.33 7.70 2597.66 1315-1420 2003000 394.95 94.39 8.43 2597.66 Average 1998000 394.95 94.30 7.94 2597.66 vcM HCI Feed Production Average pH Rate HRA Rates pH Ib/hr mmlbs/day 7.95 3588.56 8.04 3493.27 8.04 3347.43 8.01 3476.42 6.97

vCM HCI Feed Production Average pH Rate HRA Rates pH Ib/hr mmlbs/day 7.99 2892.27 7.96 3338.38 7.82 3578.62 7.92 3269.76 7.00

F-2 08-203

# .~ 

# i. .•

APPENDIX G
TCEQ Permit

08-203 G-1~ Kathleen Hartnett White, Chairman

~ Larry R. Soward, Commissioner H. S. Buddy Garcia, Commissioner

~ Glenn Shankle, Executive Director t> 'r :;- \. _. ~ 

### \ _ .. 

## TEXAS COMMISSION ON ENVIRONMENTAL QUALITY ]

. Protecting Texas by Reducing and Preuenting Pollution 

### } August 27, 2007 

## i ~


# ~ Mr. Scott Willis

Assistant Plant Manager Vinyl Chloride Monomer Production Plants 

# ~ Oxy Vinyls, L.P.

2400 Miller Cut Off Road La Porte, Texas 77571 Re: Permit Amendment Permit Numbers: 3855B and PSD-TX-876 Vinyl Chloride Monomer Production Unit La Porte, Harris County Regulated Entity Number: RN100224674 Customer Reference Number: CN600129126 Account Number: HG-0193-B Dear Mr. Willis: This is in response to your letter received May 3, 2007, and your Form PI-1 (General Application for Air Preconstruction Permits and Amendments) concerning the proposed amendment to Permit Numbers 3855B and PSD-TX-876. We understand that you propose to incorporate into these permits several existing permit by rule (PBR) registrations, increase the hourly emission rates for cracking furnaces and incinerators, and perform several administrative changes as represented in your permit application. Also, this will acknowledge that your application for the above-referenced amendment is technically complete as of May 24 ; 2007. With this amendment, the following PBR registrations will be incorporated into this permit and their separate registrations will be voided: j PBR Nos. 54263, 55409, 79212, 79379, 79479, and 80249

~ ~ ~ 

### As indicated in Title 30 Texas Administrative Code § 116.116(b) and based on our review, Permit

Numbers 3855B and PSD-TX-876 are hereby amended. This information will be incorporated into 

# ~ the existing permit file. Enclosed are revised special conditions pages and a maximum

allowable emission rates tabie to replace those currently attached to your permit. We appreciate 

# ~ your careful review of the special conditions of the permit and assuring that all reo ; .::irements are f consistently met.

P.O. Box 13087 ® Austin, Texas 78711-3087 ® 512-239-1000 ® Internet address: www.tceq.state.tx.us inir.!ru ,,,. . •.:ICd

~ •,per usie:; s.?•-7
- ,;y;:d inL. G-2 08-203

# .~ Mr. Scott Willis

~ 

### Page 2

~ 

### August 27, 2007

~ 

### Re: Permit Numbers 3855B and PSD-TX-876

You may file a motion to overturn with the Chief Cl'erk. A motion to overturn is a request for the commission to review the Texas Commission on Environmental Quality (TCEQ) Executive Director's approval of the application. Any motion must explain why the commission should review the TCEQ Executive Director's action. A motion to overturn must be received by the Chief Clerk within 23 days after the date of this letter. An original and 11 copies of a motion must be filed with the Chief Clerk in person or by rnail. The Chief Clerk's mailing address is Office of the Chief Clerk (MC-105), Texas Conunission on Environrnental Quality, P.O. Box 13087, Austin, Texas 78711-3087. On the same day the motion is transmitted to the Chief Clerk, please provide copies to Mr. Robert Martinez, Director, Environmental Law Division (MC-173), and Mr. Blas J. Coy, Jr., Public Interest Counsel (IvIC-103), both at the same TCEQ address above. If a motion is not acted on by the connnission within 45 days affter the date of this letter, then the motion shall be deemed overruled.

~ 

### Thank you for your cooperation and interest in air pollution control. Ifyou need further information

or have any questions, please contact Mr. Palinda de Silva at (512) 239-1464 or write to the Texas

~ 

### Commission on Environmental Quality, Office of Permitting; Remediation, and Registration, Air

~ 

### Permits Division (MC-163), P.O. Box 13087, Austin, Texas 78711-3087.

, 

### This action is taken under authority delegated by the Executive Director of the TCEQ

Sincerely,



### Richard A. Hyde, P.E., fffD ~~~ ir~~ 

### \ ector Air Permits Division Office of Permitting, Remediation, and Registration Texas Commission on Environmental Quality RAH/PDS/ssl Enclosures cc: Mr. Stuart L. Keil, P.E., Keil Environmental, Austin Director, PolIution Control Department, Harris County Public Health and Environmental Services, Pasadena Air Section Manager, Region 12 - Houston Air Permits Section Chief, New Source Review, Section (6PD-R), U.I , Environmental Protection Agency, Region 6, Dallas Project Number: 129133

G-3 08-203

## TEXAS COMMISSION ON ENVIRONMENTAL QUALITY

AIR QUALITY PERMIT - GENERAL CONDITIONS `► ~ , (E ~ ' ? 

### AND PERTINENT RULES EFFECTIVE FOR PERMITS ISSUED 

# ~ OR AMENDED ON OR AFTER AUGUST 16, 1994 

# TCEO

Facilities covered by this permit shall be constructed and operated as specified in the application for the permit. All representations regarding construction plans and operation procedures contained in the permit application shall be conditions upon which the permit is issued. Variations from these representations shall be unlawful unless the permit holder first makes application to the Texas Commission on Environmental Quality (commission) Executive Director to amend this permit in that regard and such amendment is approved. [Title 30 Texas Administrative Code § 116.116 (30 TAC § 116.116)] Voiding of Permit. A pennit or permit amendment is automatically void if the holder fails to begin construction within 18 months of the date of issuance, discontinues construetion for more than 18 months prior to completion, or fails to complete construction within a reasonable time. Upon request, the executive director may grant an 18-month extension. Before the extension is granted the permit may be subject to revision based on best available control technology, lowest achievable emission rate, and netting or offsets as applicable. One additional extension of up to 18 months may be granted if the permit holder demonstrates that emissions from the facility wil! comply with all rules and regulations of the commission, the intent of the Texas Clean Air Act (TCAA), including protection of tlte public's health and physical property; and (b)(1)the permit holder is a party to litigation not of the permit holder's initiation regarding the issuance of the permit; or (b)(2) the permit holder has spent, or committed to spend, at Ieastl0% of the estimated total cost of the project up to a maximum of $5 million. A permit holder granted an extension urider subsection (b)(1) of this section may receive one subsequent extension if the pennit holder meets the conditions of subsection (b)(2) of this section. [30 TAC § 116.120(a), (b) and (c)] J. Construction Progress. Start of construction, construction interruptions exceeding 45 days, and completion of construction shall be reported to the appropriate regional office of the commission not later than 15 working days after occurrence of the event. [30 TAC § 116.115(b)(2)(A)] Start-up Noti6cation. The appropriate air program regional office shall be notified prior to the commencement of operadons of the facilities authorized by the permit in such a manner that a representative of the commission may be present. The permit holder shall provide a separate notification for the commencement of operations for each unit of phased construction, which may involve a series of units commencing operations at different times. Prior to operation of the facilities authorized by the permit, the permit holder shall identify to the Office of Permitting, Remediation, and Registration the source or sources of allowances to be utilized for compliance with Chapter 101, Subchapter H, Division 3 of this title (relating to Mass Emissions Cap and Trade Program). [30 TAC § 116.115(b)(2)(B)] Sampling Requirements. If sampling is required, the perniit holder shall contact the commission's Office of Compliance and Enforcement prior to sampling to obtain the proper data forms and procedures. All sampling and testing procedures must be approved by the executive director and coordinated with the regional representatives of the commission. The permit holder is also responsible for providing sampling facilities and conducting the sampling operations or contracting with an independent sampling consultant. [30 TAC § 116.115(b)(2)(C)] Equivalency of Methods. The permit holder must demonstrate or otherwise justify the equivalency of emission control methods, sampling or other emission testing methods, and monitoring methods proposed as altematives to methods indicated in the conditions of the permit. Alternative methods shall be applied for in writing aild must be reviewed and approved by the executive director prior to their use in fulfilling any requirements of the permit. [30 TAC § 116.115(b)(2)(D)] Recordkeeping. The permit holder shall maintain a copy of the permit along with records containing the information and data sufficient to demonstrate compliance with the permit, including production records and operating hours; keep all required records in a file at the plant site. lf, however, the facility normally operates unattended, records shall be maintained at the nearest staffed location within Texas specified in the application; make the records available at the request of personnel from the commission or any air pollution control program having jurisdiction; comply with any additional recordkeeping requirements specified in special conditions attached to the permit; and retain information in the file for at least two years following the date that the infomiation or data is obtained. [30 TAC § 116.115(b)(2)(E)] 8. Maximum Allowable Emission Rates. The total emissions of air contaminants from any of the sources of emissions must not exceed the values stated on the table attached

, to the permit entitled "Emission Sources - Maximum Allowable Emission Rates." [30 TAC § 116.115(b)(2)(F)] j Maintenance of Emission Control. The permitted facilities shall not be operated unless all air pollution emission capture and abatement equipment is maintained in good working order and operating properly during normal facility operations. The permit holder shall provide notification for upsets and maintenance in accordance with §§ 101.201, 101.211, and 101.221 of this title (relating to Emissions Event Reporting and Recordkeeping Requirements; Scheduled Maintenance, Startup and Shutdown 

### ~ Reporting and Recordkeeping Requirements; and Operational Requirements). [30 TAC § I 16.1 15(b)(2xG)] 0. Compliance with Rules. Acceptance of a permit by an applicant constitutes an acknowledgment and agreement that the permit holder will comply with all mles, regulations, and orders of the commission issued in conformity with the TCAA and the conditions precedent to the granting of the permit. If more than one state or federal 

### ~ rule or regulation or permit condition are applicable, the most stringent limit or condition shall govem and be the standard by which compliance shall be demonstrated. Acceptance includes consent to thc entrance of commission employees and agents into the permitfed premises at reasonable times to investigate conditions relating to the 

### ~ emission or concentration of air contaminants, including compliance with the permit. [30 TAC § 116. kl5(b)(2)(H)] 11, This pennit may be appealed pursuant to 30 TAC § 50.139. }2. This perniit may not be transferred, assigned, or conveyed by the holder except as provided by rule. [30 TAC § 116.110(e)] 13. There may be additional special conditions attached to a permit upon issuance or modification of the permit. Such conditions in a pemzit may be more restrictive than the requirements of Title 30 of the Texas Administrative Code. [30 TAC § 116.115(c)] 

# 1 1. Emissions from this facility must not cause or contribute to a condition of "air pollution" as defined in TCAA § 382.003(3) or violate TCAA § 382.085, as codified in the Texas Health and Safety Code. If the executive director determines that such a condition or violation occurs, the holder shall implement additional abatement measures as necessary to control or prevent the condition or violation.

Rev. July 24, 2003 G-4 08-203

### EMISSION STANDARDS

1. This permit authorizes emissions only frorn those points listed in the attached table entitled "Emission Sources - Maximum Aliowable Emission Rates," and the facilities covered by this permit are authorized to emit subject to the emission rate limits on that table and other operating conditions specified in this permit. (8/07)


### FEDERAL PROGRAM APPLICABILITY 2. These facilities shall comply with all applicable requirements of the U.S. Environmental j 

### Protection Agency (EPA) regulations on National Emission Standards for Hazardous Air 

# 1 Pollutants (NESHAPS) promulgated for Benzene Waste Operations in Title 40 Code of

Federal Regulations (40 CFR) Part 61, Subparts A and FF. (8/07) 

# ~ 3. These facilities shall comply -with all applicable requirements of the EPA regulations for

NESHAPS for the Synthetic Organic Chemical Manufacturing Industry (SOCMI), for 

# ~ SOCMI Process Vents, Storage Vessels, Transfer Operations, and Wastewater, for

SOCMI Equipment Leaks, and for Industrial, Conumercial and Institutional Boilers and Process Heaters in 40 CFR Part 63, Subparts A, F, G, and H. (8/07) ETHYLENE DICHLORIDE (EDC) PRODUCTION LIMITATIONS AND REQUIREMENTS 4. The fuel fired in each combustion device at this facility is limited to pipeline-quality, sweet natural gas. Use of any other fuel will require an amendment to the permit. (8/07)
EMISSION STANDARDS AND OI'ERATIONAL LIMITATIONS 5. In the event that the permit holder loses the service ofboth incinerators, the permit holder shall attempt to restore the operation of the incinerators as soon as is practicable. In the event that one or both of the incinerators cannot be restarted in a timely manner, operating rates in the vinyl chloride producing plant (including the oxyhydr©chlorination EDC facility) shall be reduced until the plant can be safely shutdown. The rate of reduction in production rates shall be controlled to minimize the total quantity of emissions. (9/98) 6. Polychlorinated biphenyls (PCBs), other than PCBs incidentally produced during the 

# ~ EDC/vinyl chloride monomer (VCM) manufacturing proces."t, shall not be handled at this

facility. Records of incidental PCB production will be maintained in accordance with 40 CFR Part 761.

G-5 08-203

### 7. Oxy Vinyls, L.P., shall operate the incinerators in a manner which will prevent visible fu.gitive

emissions from the incinerators before the stack.

DISASTER PREVENTION AND MITIGATION 

### 8. The holder of this permit shall install, operate, and maintain monitoring, surveillance, and alarm systems for detection of and notification of chlorine (Cl Z ) releases. Chlorine concentrations shall be continuously monitored by a sufficient number of ambient monitors in the area of the C1 2 facilities. The detection level for the Cl Z monitors shall be 1 part per million by volurrie (ppmv). The monitors shall be checked monthly to ensure the proper function of sensors and alarms. Corrective action`shall be taken to minimize C1 2 leaks whenever Cl Z concentrations of 1 ppmv are detected. 9. The holder of this permit shall maintain and operate a release plume modeling program that Oxy Vinyls' La Porte Plant personnel will use to initiate the Chlorine Contingency Plan (dated December 20, 1995). The contingency plan 

### shall be implemented immediately following an accidental release of a potentially hazardous volume of C1 2 . The contingency plan shall include (but is not limited to) a call list of company personnel and local public safety personnel and a list of evacuation routes and procedures for notifying the general public that an emergency exists and for requesting assistance to evacuate the public from the area of exposure. A copy of the contingency plan shall be retained at the plant, and all operating personnel shall be thoroughly trained for implementing the procedures of this plan. (8/07) 10. The permit holder shall observe applicable safety guidelines, to include set brakes and chocked wheels, regarding the location and protection from collision of standing railcars while they are situated on loading side tracks. 11. Chlorine storage tanks will be protected from damage by location away from traffic within the protected perimeter of the permitted facility. 12. Immediately upon detection of a leak within the area of facility operations, company personnel shall take the following actions toward repairing the le4k: A. The operator on duty shall isolate the leak. B. Unloading operatioins shall shut down for the affected car or cars.

G-6 08-203-

I 

### SPECIAL CONDITIONS 

# ~ Permit Numbers 3855B and PSD-TX-876

Page 3
C. Leaking equipment shall be repaired or replaced and shall not be returned to service before being repaired or replaced. Unloading operations shall resume only after the leak has been repaired. 13. All personnel involved in C1 2 transfer operations at the permitted facility shall be properly trained in these operations, in the recognition of C1 2 leaks, and in all routine and emergency response procedures to be enacted in the event of minor and emergency releases. New employees shall be trained as part of their initial orientation, and all employees shall be retrained at least once per year. 14. Automatic and manual process shutdown capability shall be maintained in the C1 2 1oading area. 15. A visual inspection of the condition of all transfer hoses used in the transfer of C1 2 to or from railcars shall be conducted by qualified Oxy Vinyls personnel and found to be serviceable before each loading. At least annually, the transfer hoses shall either be replaced or pass a hydro test at two times maximum allowable working pressure. 16. Maintenance operations which require lifting of heavy equipment over the C1 2 transfer lines between processing areas, header areas, and storage areas are permitted only when no other equipment transfer pathway is practically available. Under these circumstances, maintenance operations shall be controlled by a work permit approved by plant management. (8/07) 17. Inspections for integrity of flange gaskets at the surge tank shall be conducted at least semiannually.


# ~ 18. All plant personnel assigned to C1 2 operations shall participate in continuing training in

Chlorine Institute Safety Guidelines (Chlorine Transfer Operations), to be conducted no less frequently than biannually; new/transferred personnel shall complete all training required for their specific assignments prior to assumption of their duties in C1 2 operations. 19. Capability for application of water spray and foam to a C1 2 release shall be available to the C1 2 operations area. 6
CARBON COMPOUND WASTE GAS.STREAMS 20. The incinerators' firebox exit temperatures shall be continuously monitored and recorded to ensure a minimum 99.9 percent destruction efficiency for volatile organic compounds (VOC). The incinerator firebox exit temperatures shall be maintained at not less than 1560°F.

G-7 08-203

### 21. Incinerators A and B shall be equipped with flue gas scrubbers in place to control hydrogen 

# ~ chloride (HCl) and C1 2 emissions. The caustic scrubbing solution's circulation rate shall be

no less than 200 gallons per minute. The circulation rate of the caustic scrubbing solution shall be continuously monitored and recorded. (9/98)



# ~ 22. The scrubbing solution pH for the incinerator caustic scrubbers shall be continuously

monitored and recorded. The pH of the caustic scrubbing solution shall be maintained at 

# ~ greater than 8.0 (hourly average in the scrubber effluent) or greater than the pH determined

by testing (according to Special Condition No. 27) that demonstrates compliance with the requirements of this permit. (8/07) 23. Except as may be provided for in the special conditions of this permit, all waste gas from point .sources containing VOC and/or other organic compounds and hydrocarbon and/or hydrocarbon derivatives, excluding carbon dioxide, shall be routed to an incinerator/scrubber system. The incinerator/scrLibber system shall operate with no less than 99.9 percent efficiency in disposing of the carbon compounds captured by the collection system. The waste gas streams shall include process vents, analyzer vents, steam jet exhausts, start-up and shutdown related em`issions or purges, blowdowns, or other system emissions of waste gas. Storage tank vents, cooling tower exhaust, and process fugitive emissions are excluded from this requirement. Any other exception to this condition requires prior review and approval of the Texas Commission on Environmental Quality (TCEQ) Executive Director, and such exceptions may be subject to strict monitoring requirements.



# ~ 24. The EDC reactor shutdown purge stream and relief valves (1) monitored in accordance with

Special Condition No. 29 or (2) equipped with a rupture disc upstream are exempt from the 

# ~ requirements of Special Condition No. 23. A disc failure detection device shall notify 4 operating personnel of a disc failure. All leaking discs shall be replaced at the earliest

opportunity but no later than the next process shutdown. 25. Within 60 days after start of operation of the fifth cracking furnace, and with the exception of maintenance, start-up, and shutdown (MSS) operations authorized in Special Condition No. 33, carbon monoxide (CO) and C12 concentrations in each of the incinerator stacks shall not exceed 100 and 50 ppmv, dry, no excess air (hourly average), respectively. (8/07)
CONTINUOUS DETERMINATION OF COMPLIANCE . (8/07) 26. The permit holder shall install, calibrate, an' maintain a continuous emission monitoring system (CEMS) to measure and record the in-stack concentration of CO from each incinerator.

G-8 08-203

### SPECIAL CONDITIONS 

# ~ Permit Numbers 3855B and PSD-TX-876

Page 5



# ~ A. The CEMS shall meet the desi 

## im p p and erformance s ecifications, pass the field tests, and meet the installation requirements and the data analysis and reporting requirements

, specified in the applicable Performance Specification Nos. 1 through 9, 40 CFR Part 60,

Appendix B. If there are no applicable performance specifications in 40 CFR Part 60, 

# ~ Appendix B, contact the TCEQ Office of Permitting, Remediation, and Registration, Air

Permits Division for requirements to be met. B. Section 1 below applies to sources subject to the quality-assurance requirements of 40 CFR Part 60, Appendix F; Section 2 applies to all other sources: (1) The permit holder shall assure that the CEMS meets the applicable quality- 

# ~ assurance requirements specified in 40 CFR Part 60, Appendix F, Procedure 1. Relative accuracy exceedances, as specified in 40 CFR Part 60, Appendix F, § 5.2.3 and any CEMS downtime shall be reported to the appropriate TCEQ Regional 

# ~ Manager, and necessary corrective action shall be taken. Supplemental stack concentration measurements may be required at the discretion of the appropriate

, 

### TCEQ Regional Manager. ' (2) The system shall be zeroed and spanned daily, and corrective action taken when the 24-hour span drift exceeds two times the amounts specified in the applicable 

# ~ Performance Specification Nos. 1 through-9, 40 CFR Part 60, Appendix B, or as specified by the TCEQ if not specified in Appendix B. Zero and span is not required on weekends and plant holidays if instrument technicians are not normally 

# ~ scheduled on those days. Each monitot shall be quality-assured at least quarterly using Cylinder Gas Audits (CGA) in accordance with 40 CFR Part 60, Appendix F, Procedure 1, Section 5.1.2, with the following exception: a relative accuracy test audit (RATA) is not required once every four quarters (i.e., four successive quarterly CGA may be conducted). An equivalent quality-assurance method approved by the TCEQ may also be used. Successive quarterly audits shall occur no closer than two months. All CGA exceedances of +15 percent accuracy indicate that the CEMS is out of control. (3) The requirements of 40 CFR 60, Appendix F apply only to those sources for which a New Source Performance Standards (NSPS) subpart specifically requires both a continuous monitoring system and that the continuous monitoring system be used to demonstrate compliance with emission limits on a continuous basis.

G-9 08-203

### SPECIAL CONDITIONS

Permit Numbers 3855B and PSD-TX-876 Page 6
C. The monitoring data shall be reduced to one-hour average concentrations at least once every day, using a minimum of four equally-spaced data points from each one-hour period. The individual average concentrations shall be reduced to units of pounds per hour dry at least once every week as follows: The measured one-hour average concentration from the CEMS shall be multiplied by the exhaust flow rate as measured by an annubar to determine the hourly emission rate. The flow measurement monitoring device shall be installed and calibrated at a frequency in accordance with the manufacturer's specifications or at least annually, whichever is more frequent. .D. All monitoring data and quality-assurance data shall be maintained by the source. The data from the CEMS may, at the discretion of the TCEQ, be used to determine compliance with tlie conditions of this permit.

1 

### E. The appropriate TCEQ Regional Office shall be notified at least 30 days prior to any 

# I required RATA in order to provide them the opportunity to observe the testing.

F. Quality-assured (or valid) data must be generated when the incinerator is operating except during the performance of a daily zero and span check. Loss of valid data due to periods of monitor break down, out-of-control operation (producing inaccurate data), repair, maintenance, or calibration may be exempted provided it does not exceed 5 percent of the time (in minutes) that the incinerator operated over the previous rolling 12-month period. The measurements missed shall be estimated using engineering judgement and the methods used recorded. Options to increase system reliability to an acceptable value, including a redundant CEMS, may be required by the TCEQ Regional Manager. INITIAL DETERMINATION OF COMPLIANCE (8/07) 27. The permit holder shall perform stack sampling and other testing as required to establish the actual pattern and quantities of air contaminants being ejnitted into the atrnosphere from the Incinerator A and B Scrubbers to demonstrate compliance with the maximum allowable
~ 

### emission rates table (MAERT) and Special Condition No. 25.

The permit holder is responsible for providing sampling and testing facilities and conducting
~ 

### the sampling and testing operations at'_.

- ~ 

### s expense. Sampling shall be conducted in accordance

with the appropriate procedures of the TCEQ Sampling Procedures Manual and the EPA reference methods. 

# -, I

G-10 08-203

# ~ SPECIAL CONDITIONS

Permit Numbers 3855B and PSD-TX-876 

# ~ Page 7



# ~ Requests to waive testing for any pollutant specified in this condition shall be submitted to the

TCEQ Office of Permitting, Remediation, and Registration, Air Permits Division. Test ! waivers and alternate/equivalent procedure proposals for 40 CFR Part 60 testing which must f have EPA approval shall be submitted to the TCEQ Office of Compliance and Enforcement

(OCE), Compliance Support Division. A. The appropriate TCEQ Regional Office shall be notified not less than 45 days prior to sampling. The notice shall include:


# ~ (1) Proposed date for pretest meeting.

(2) Date sampling will occur. (3) Name of firm conducting sampling. i (4) Type of sampling equipment to be used. 

# ~ (5) Method or procedure to be used in sampling.


# ~ The purpose of the pretest meeting is to review the necessary sampling and testing

procedures, to provide the proper data forms for recording pertinent data, and to review the format procedures for the test reports. The TCEQ Regional Director or the TCEQ OCE, Compliance Support Division must approve any deviation from specified sampling 

# ~ procedures.

B. Air contaminants emitted from the incinerator scrubbers to be tested for include (but are not limited to) total VOC, EDC, VCM, nitrogen oxides, CO, HCl, and C1 2

. C. Sampling shall occur within 60 days after achieving the maximum operating rate, but no later than 180 days.after initial start-up of the facilities and at such other times as may be required by the TCEQ Executive Director. Requests for additional time to perform sampling shall be submitted to the appropriate TCEQ Regional Office. D. The facility being sampled shall operate at maximum VCM production rates during stack emission testing ofthe incinerator scrubbers. The EDC cracking furnace subject to stack testing shall operate at the respective maxim,um heat input capacities. These conditions/parameters and any other primary operating parameters that affect the emission rate shall be monitored and recorded during the stack test. Any additional parameters shall be determined at the pretest meeting and shall be stated in the sampling report. Permit conditions and parameter limits may be waived during stack testing performed under this condition if ti_.; proposed condition/parameter range is identified in the test notice specified in paragraph A and accepted by the TCEQ Regional Office. Permit allowable emissions and emission control requirements are not waived and still apply during stack testing periods.

G-11 08-203.~

~ 3 

### SPECIAL CONDITIONS 

# ~ Permit Numbers 3855B and PSD-TX-876 

# ~ Page 8
During subsequent operations, if the production rate or the maximum heat input is greater 

# ~ than that recorded during the test period, stack sampling shall be performed at the new

operating conditions within 120 days. This sampling may be waived by the TCEQ Air Section Manager for the region. j E. Copies of the final sampling report shall be forwarded to the offices below within 60 days

after sampling is completed. Sampling reports shall comply with the attached provisions 

# i ~ entitled "Chapter 14, Contents of Sampling Reports" of the TCEQ Sampling Procedures

Manual. The reports shall be distributed as follows:



# ~ One copy to the appropriate TCEQ Regional Office.

One copy to each local air pollution control program. One copy to the TCEQ OCE, Compliance Support Division, Austin. 28. The initial stack emission testing for the fifth and sixth cracking furnaces and the incinerator scrubbers required by Special Condition No. 27 of Permit No. 385513 as renewed on October 6, 1997 was conducted on May 20 through 24, 1996 and March 11 through 13,1997 (incinerator scrubbers only). Additional stack emission testing of the fifth and sixth cracking furnaces performed in accordance with the requirements of Special Condition No. 27 may be required in the future at the discretion of the TCEQ. (8/07)
FUGITIVE EMISSION LEAK DETECTION AND REPAIR PROGRAMS Piping, Valves, Connectors, Pumps, and Compressors in VOC Service - Intensive Directed Maintenance - 28MID 29. Except as may be provided for in the special conditions of this permit, the following requirements apply to the above-referenced equipment. (9/98) A. These conditions shall not apply (1) where the VOC has an aggregate partial pressure or vapor pressure of less than 0.044 psia at 68°F or (2) where the operating pressure is at least 5 kilopascals

. (0.725 psi) below ambient presqure. Equipment excluded from this condition shall be identified in a list to be made available upon request. B. Construction of new and reworked piping, valves, pump systems, and compressor systems shall conform to applicable American National Sfandards Institute, American Petroleum Institute, American Society of Mechanical Engineers, or equivalent codes.

G-12 08-203~ T 

## ~ SPECIAL CONDITIONS


## ~ Penmit Numbers 3855B and PSD-TX-876

Page 9

C. New and reworked underground process pipelines shall contain no buried valves such that fugitive emission monitoring is rendered impractical. D. To the extent that good engineering practice will permit, new and reworked valves and piping connections shall be so located to be reasonably accessible for leak-checking during plant operation. Non-accessible valves, as defined by 30 TAC Chapter 115 shall be identified in a list to be made available upon request.



## ~ E. New and reworked piping connections shall be welded or flanged. Screwed connections

are permissible only on piping smaller than two-inch diameter. No later than the next scheduled quarterly monitoriing after initial installation or replacement, all new or reworked connections shall be gas-tested or hydraulically-tested at no less than normal operating pressure and adjustments made as necessary to obtain leak-free performance.

~ 

### Connectors shall be inspected by visual, audible, and/or olfactory means at least weekly I, by operating personnel walk-through.



## ~ Each open-ended valve ar line shall be equipped with a cap, blind flange, plug,.or a


## ~ second valve. Except during sampling, the second valve shall be closed.



## ~ F. Accessible valves shall be monitored by leak-checking for fugitive emissions at least

quarterly using an approved gas analyzer with a directed maintenance program. Sealless/leakless valves (including, but not limited to, welded bonnet bellows and diaphragm valves) and relief valves equipped with a rupture disc upstream or venting to a control device are not required to be monitored. For valves equipped with rupture discs, a pressure-sensing device

. shall be installed between the relief valve and rupture disc to


## ~ monitor disc integrity. All leaking discs shall be replaced at the earliest opportunity but


## ~ no later than the next process shutdown.

An approved gas analyzer shall conform to requireinents listed in 40 CFR § 60.485(a)-(b). A directed maintenance program shall consist of the repair and maintenance of 1 components assisted simultaneously by the use of an approved gas analyzer such that a

minimum concentration of leaking VOC is oblained for each component being maintained. Replaced components shall be re-monitored within 15 days of being placed back into VOC service. 

## I l

G-13 08-203_: _,... _ ..... ~ ..;



### SPECIAL CONDITIONS Permit Numbers 3855B and PSD-TX-876 Page 10

G. All new and replacement pumps and compressors shall be equipped with a shaft sealing system that prevents or detects emissions of VOC from the seal. These seal systems need not be monitored and may include (but are not limited to) dual pump seals with barrier fluid at higher pressure than process pressure, seals degassing to vent control systerris kept in good working order, or seals equipped with an automatic seal failure detection and alarm system. Submerged pumps or sealless pumps (including, but not limited to, diaphragm, canned, or magnetic-driven pumps) may be used to satisfy the requirements of this condition and need not be monitored. All other pump and compressor seals emitting VOC shall be monitored with an approved gas analyzer at least quarterly. H. Damaged or leaking valves, connectors, compressor seals, and pump seals found to be emitting VOC in excess of 500 ppmv or found by visual inspection to be leaking (e.g., dripping process fluids) shall be tagged and replaced or repaired. Every reasonable effort shall be made to repair a leaking component, as specified in this paragraph, within 15 days after the leak is found. If the repair of a component would require a unit shutdown, the repair may be delayed until the next scheduled shutdown. All leaking components which cannot be repaired until a scheduled shutdown shall be identified for such repair by tagging. The TCEQ Executive Director, at his discretion, may require early unit shutdown or other appropriate action based on the number and severity of tagged leaks awaiting shutdown. I. In lieu of the monitoring frequency specified in paragraph F, valves in gas and light liquid service may be monitored on a semiannual basis if the percent of valves leaking for two consecutive quarterly monitoring periods is less than 0.5 percent. Valves in gas and light liquid service may be monitored on an annual basis if the percent of valves leaking for two consecutive semiannual monitoring periods is less than 0.5 percent. If the percent of valves leaking for any semiannual or annual monitoring period is 0.5 percent or greater, the facility shall revertoto quarterly monitoring until the facility again qualifies for the alternative monitoring schedules previously outlined in this paragraph. 

# I

G-14 08-203

# ~ SPECIAL CONDITIONS 

# ~ Permit Numbers 3855B and PSD-TX-876 Page 11

• ~~ 

### J. The percent of valves leaking used in paragraph I shall be determined using the following formula:



## ~ V V + L s) 

### x100=Vp VT


# ~ Where: V L = the number of valves found leaking by the end of the monitoring period, either by Method 21 or sight, sound, and smell. V S = the number of valves for which repair has been delayed and are listed on the facility shutdown log. V T = the total number of valves in the facility subject to the monitoring

requirements, as of the last day of the monitoring period, not including non-accessible and unsafe-to-monitor valves. V P = the percentage of leaking valves for the monitoring period. 1 K. The results of the required fugitive instrument monitoring and maintenance program shall 

# ~ be made available to the TCEQ Executive Director or his designated representative upon

request. Records shall indicate appropriate dates, test methods, instrument readings, 

# ~ repair results, and corrective actions taken. Records of physical inspections are not

required unless a leak is detected. i L. Compliance with the requirements of this condition does not assure compliance

with requirements of 30 TAC Chapter 115, an applicable NSPS, or an applicable NESHAPS and does not constitute.approval of alternative standards for these regulations.

~ 

### (9/98) 

### 30. A. In addition to the weekly physical inspection - for connectors specified in Special 

# ~ Condition No. 29E, all connectors shall be monitored by leak-checking for fugitive

emissions at least annually using an approv6d gas analyzer with a directed maintenance program as specified in Special Condition No. 29F. B. In addition to the weekly physical inspection for connectors specified in Special Condition No. 29E, all connectors adj acent to valves shall be monitored by leak-checking for fiigitive ernissions at least quarterly using an approved gas an":yzer with a directed maintenance program as specified in Special Condition No. 29F. (8/07)

G-15 08-203

# I SPECIAL CONDITIONS 

# ~ Permit Numbers 3855B and PSD-TX-876 

# ~ Page 12

i • ~ A 

### 31. A. Audio, olfactory, and visual checks for ammonia, C1 2 , and HCl leaks within the operating

- area shall be made every four hours during plant operations.



# ~ lant ersonnel shall take the followin actions:

B. Immediately, after detection of a leak, p p g - p (8/07)



### (1) Identify the leak. (2) Commence repair or replacement, or other actions to stop the leak including using a leak collection/containment system to minimize emissions from the leak until repair or replacement can be made. (3 ) If the repair of the component requires a shutdown, the repair may be delayed until the next scheduled shutdown, provided that the leak can be contained.
RECORDKEEPING AND NOTIFICATION REOUIREMENTS 32. The following records shall be maintained in accordance with General Condition No. 6: (8/07)

~ 

### ( A. Records of incidental PCB production in accordance with Special Condition No. 6.

B. Records of the monthly inspections for each of the ambient Cl Z monitors in accordance with Special Condition No. 8.



# ~ C. Records of all hydro testing of the C1 2 transfer hoses, or records of all transfer

hose replacements, as applicable, to demonstrate compliance with Special Condition No. 15. 

## i D. Records of the incinerators' firebox exit temperatures in accordance with Special 

# ~ Condition No. 20.

E. Records of the incinerator flue gas scrubbers' caustic solution circulation rates and pH in accordance with Special Condition Nos. 21 and 22. The facility record shall also indicate periods of routine scrubber maintenance and any related records and notifications to the TCEQ Houston Regional Office and the Harris County Pollution Control Department pursuant to Title 30 Texas Administrative Code § 101.211. F. Records of the incinerator CEMS in accordance with Special Condition Nos. 26D and 

## E.

I G-16 08-203

# .~ SPECIAL CONDITIONS 

# ~ Permit Numbers 3855B and PSD-TX-876

Page 13

G. Records of all stack emission testing performed in accordance with Special Condition Nos. 27 and 28. H. Records of the facility's fugitive emission leak detection and repair programs in 

# ~ accordance with Special Condition Nos. 29, 30, and 31. 1 4



### 33. This permit authorizes emissions from the Incinerators (Emission Point Nos. IND101A and 

# ~ IND101B) for the following planned MSS activities: (8/07)

A. Shutdown to clean or replace scrubber packing or other scrubber component parts followed by start-up. B. Shutdown to replace incinerator, scrubber, or heat recovery component parts that have reached or are near the end of their useful life followed by start-up. C. Shutdown to replace worn or failed high temperature refractory linings, including slow 

# ~ fire, low temperature extended start-up to dry and cure newly installed refractory or

refractory that has cooled due to extended downtime.


# ~ D. Shutdown and start-up to allow required periodic safety or mechanical integrity

inspections. 1 E. Transition periods for changing from two incinerator operations to one incinerator 

# l operation due to the need for planned maintenance or due to loss of use of one

incinerator. F. Transition periods resulting from a change in vent gas flow from Oxy Vinyls Deer Park PVC plant due to process operations.



# ~ G. Transition periods created by peak vent flow due to purging storage tanks or process

vessels to prepare for planned maintenance repairs or required safety and mechanical 1 integrity inspections. ( ~



### H. Maintenance, start-up, and shutdown activities not in the above list are not authorized by } this permit. These emissions are subject to the maximum allowable emission rates j indicated on the MAERT. The performance of each MSS activity and the emissions

associated with it shall be recorded and the rolling 12-month emissions shall be l updated on a monthly basis. These records shall in('ude at least the following 

# ~ information:
1

~ ,
G-17 08-203

### SPECIAL CONDITIONS

Permit Numbers 3855B and PSD-TX-876 Page 14

(1) The physical location at which emissions from the MSS activity occurred, including

the emission point number, common name, and any other identifier for the point at which the emissions were released into the atmosphere; (2) The type of planned MSS activity and the reason for the planned activity; (3) The conunon name and the facility identification number of the facilities at which the MSS activity and emissions occurred; (4) The date and time of the MSS activity and its duration; (5) The quantity of CO "emissions emitted according to the available CEMS data.

Dated 

### August 27, 2007

~

G-18 08-203

# ~

._~ EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES

; 

### i Permit Numbers 3855B and PSD-TX-876



## ~ This table lists the maximum allowable emission rates and all sources of air contaminants on the applicant's property covered by this permit. The emission rates shown are those derived from information submitted as part

~ of the application for permit and are the maximum rates allowed for these facilities. Any proposed increase in emission rates may require an application for a modification of the facilities covered by this permit.


# ~ AIR CONTAMINANTS DATA Emission Source Air Contaminant Emission Rates * Point No (1) Name (2) Name (3) lb/hr TPY** 

# ~ F-PO1 VCM Prodi.iction Fugitives (4) VOC 0.89 3.88 HCl 0.14 0.60 

# ~ VCM 0.68 3.00 C1 2 0.01 0.05


# ~ F-P-13D "D" Oxy-Chlorination Reactor VOC 0.21 0.90 Process Fugitives (4) HCl 0.08 0.35 F-P03B Chlorine Uriloading Fugitives (4) C1 2 0.06 0.27 103 Cracking Furnace 103 PM, o 0.71 2.45



# ~ IND (95 MMBTU/Hour) SO Z 0.06 0.22 NO X 15.11 47.30 CO 1.24 3.90 

# ~ VOC 0.51 1.76 

### IND 104 Cracking Furnace 104 PM, 0 0.71 2.45 

# ~ (95 MMBTU1Hour) S0 2 0.06 0.22 NO X 15.11 47.30 CO . 1.24 3.90 

# ~ VOC 0.51 1.76 

### IND 105 Cracking Furnace 105 PM, 0 0.71 2.45 

# ~ (95 MMBTU/Hour) S0 2 

# ~ 0.06 0.22 NO,, 15.11 47.30 

# ~ CO 1.24 3.90 ; VOC



# ~ 0.51 1.76

r 

### 1 

# 1 G-19 08-203

# ~ . EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

# ~ . AIR CONTAMINANTS DATA ` I Emission Source Air Contaminant Emission Rates * Point No (1) Name (2) Narne (,3) lb/hr

_ TPY** IND 106 Cracking Furnace 106 PM, 0 0.71 2.45 (95 MMBTU/Hour) S0 2 0.06 0.22 

# ~ NO x 15.11 47.30 

# ~ CO 1.24 3.90 VOC 0.51 1.76



# ~ IND 107 Cracking Furnace 107 PM 10 0.71 2.35 (95 MMBTU/Hour) S0 2 0.06 0.21 NO X 5.32 17.50 

# ~ CO 1.33 .3.90 VOC 0.51 1.70



# ~ IND108 Cracking Furnace 108 PM, o 0.71 2.35 (95 MMBTU/Hour) S0 2 0.06 0.21. P _ NO X 5.32 17.50 

# ~ CO 1.33 3.90 VOC 0.51 1.70 

# l IND101A Incinerator A Scrubber VOC 2.00 8.80 NO X 9.18 26.79 CO 2.21 9.43 

# ~ CO (5) 50.00 S0 2 0.10 0.40 

# ~ PM, a 2.00 8.80 

# ~ HCl 2.08 8.83 CI z 4.00 17.50 1 1 

### VCM

~ 

### 0.05 0.22

G-20 08-203- i 3 A 

### Permit Numbers 3855B and PSD-TX-876 

# ~ Page 3



# ~ EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES

. 

### AIR CONTAMINANTS DATA


# ~ Emission Source Air Contaminant Emission Rates * Point No. (1) 

# 1 Name (2) Name (3) lb/hr TPY** _


# ~ IND101B Incinerator B Scrubber VOC 2.00 8.80 NO X 9.18 26.79 

# ~ CO 2.21 9.43 CO (5) 50.00 SO Z 0.10 0.40 

# ~ PM, o 2.00 8.80 HCI 2.08 8.83 C1 2 4.00 17.50 

# ~ VCM 0.05 0.22 CYC-1 Decoking Cyclone CO 43.80 3.20


# ~ EEDC-SUMP East EDC Tank Farm Sump EDC <0.01 <0.01


# ~ EDCTF-SUMP West EDC Tank Farm Sump EDC <0.01 <0.01 

# J IM-SUMP Intermediate Sump EDC <0.01 <0.01


# ~ LTC SUMP LTC Sump . EDC <0.01 <0.01 j NO1-SUMP No. 1 Sump EDC <0.01 <0.01 

# f NO2-SUMP No. 2 Sump EDC <0.01 <0.01


# ~ COXY-SUMP C-Oxy Sump EDC <0.01 <0.01 j EOXY-SUMP J 

### E-Oxy Sump EDC & 

### <0.01 <0.01 HYDRO-SUMP i 

### Hydroblast Pad Sump EDC <0.01 <0.01 HYDRO-WEIR Hydroblast Pad Weir EDC 0.14 0.62 VCM 0.07 0.31 I WW-1 Wastewater Treatment EDC 0.17 0.42


# J CHC1 3 0.35 0.87

G-21 08-203

### AIR CONTAMINANTS DATA


# ~ Emission Source Air Contaminant Emission Rates * Point No. (1) Name (2) Name (3) lb/hr TPY**


# ~ DEGREASER Parts Degreaser VOC 0.08 0.24 4


# ~ FB-6473 LOPS Tank UOC 0.08 0.03 GT-1 Gasoline Storage Tank Gasoline 44.23 1.13 I DT-I-FWP Diesel Storage Tank Diesel 0.01 <0.01 l DT-2-FWP Diesel Storage Tank Diesel . 0.01 <0.01
1 

### DT-3-FWP Diesel Storage Tank Diesel 0.01 <0.01


# ~ DT-4-FWP Diesel Storage Tank Diesel 0.01 <0.01 

# j DT-5-FWP Diesel Storage Tank Diesel 0.01 <0.01 DT-6-UTIL Diesel Storage Tank Diesel 0.01 <0.01 

# 1 DT-7-EG Diesel Storage Tank Diesel 0.01 <0.01


# ~ FA-4605 10 percent Hydrochloric Acid Tank HCl 0.10 <0.01 i 

### FA-4609 10 percent Hydrochloric Acid Tank HCl 0.10 <0.01 

# J FA-4610 10 percent Hydrochloric Acid Tank HCI 0.10 <0.01


# ~ FA-3204 J 

### 10 percent Ethylene Glycol Tank EG a 

### 0.10 <0.01 FB-6404 i 

### Sodium Hydroxide Tank

. 

### NaOH 0.49 0.07



## ~ FB-6480 Sodium Hydroxide Tank NaOH 0.20 0.03 ; FB-6470 Solvent Storage Tank VOC 25.74 0.96 ) COOLTWR Cooling Tower PM <0.01 <0.01 

# i Cl 2 0.91 4.00

G-22 08-203J



### Permit Numbers 3855B and PSD-TX-876 

# ~ Page 5
EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES AIR CONTAMINANTS DATA

~ 

### Emission Source Air Contaminant Emission Rates * Point No (1) Name (2) Name (3) lb/hr TPY** 

# ~ COOLTWR Cooling Tower 

## PM <0.01 <0.01 ` C1 2 0.91 4.00 

# i COOLTWR-2 East Cooling Tower PM <0.01 <0.01 Cl 2 0.91 4.00



# ~ (1) Emission point identification - either specific equipment designation or emission point number from plot plan. (2) Specific point source name. For fugitive sources use area name or fugitive source name. VOC volatile organic compounds as defined in Title 30 Texas Administrative Code .§ 10 1. 1 

# ~ (3) HCl = hydrogen chloride VCM - vinyl chloride monomer C1 2 PM = chlorine 

# ~ particulate matter, suspended in the atmosphere, including PM, o . PM, o - particulate matter less than 10 microns in diameter. Where PM is not listed, it shall be
_ 

# ~ assumed that no PM greater th 

## an 10 microns is emitted. SO Z - sulfur dioxide NO x - total oxides of nitrogen CO carbon monoxide 

# ~ EDC = ethylene dichloride CHCL 3 - chloroform 

# ~ NaOH - sodium hydroxide 4(4) Fugitive emissions are an estimate only and should not be considered as a maximum allowable emission rate. (5) Maintenance operations only. Emissions from these EPNs are only from these permitted facilities * Emission rates are based on and the facilities are limited by the following maximum operating schedule: Hrs/day Days/week Weeks/year or 8.760 Hrs/year

r 

### ** Compliance with annual emission limits is based on a rolling 12-month period.

Dated August 27, 2007



## 1 G-23 08-203

# _-~ a 

# M~ 

# iiwLce . '61 I MA I I.

~

~



### APPENDIX H Chain of Custody



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! , 08-203 H-1 

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APPENDIX I
Resumes of Test Personnel



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.~ ~ ~



### 08-203 I-1 

# l

# MEFCO. ErMROnrnEnML

ROBERT M. PATTERSON; President
Education 

### B. S. 1983, Central Michigan University; Mt. Pleasant, Michigan,

in Geology and Earth Science-Meteorology.
Professional 

### Attended a two-day short course, "Performing and Observing Trainin Source Sampling" in Dallas, Texas. Courses 

### Attended a one-day short course on basic supervision.

Attended a four-week management course presented by the American Management Association, 1991-1992.
Certification 

### Certified Visible Emissions Evaluator

Certified Cabot Full-Face Respirator Fit Tester
Professional 

### Source Evaluation Society Memberships 

### American Management Association
Technical 

### Participated in the sampling of over 1,000 sources, including Experience 

### several of which were sampled simultaneously using more

than one sampling train. Thoroughly trained in all EPA testing procedures, 1986-present. Over nineteen years experience with EPA and Texas Air Control Board methods of sampling - both stationary sources and ambient air. CFR, Title 40, Chapter I, Part 60, EPA Methods 1 through 25, and 101 through 110. Performance Specifications 1 through 5. CFR, Title 40, Chapter I, Part 50, Appendix A through F. "Sampling Procedures Manual, Texas Air Control Board, January 1983." Parts 1-1 through 14-6, Appendix B through Appendix M. Experienced with sampling Method 0010, Modified Method 5 Sampling Train; Method 0030, Volatile Organic Sampling Train; and various EPA and "Site Specific" mu

~~ 

### iple metal and acid gas sampling trains.

(continued) 

### 1-2

# ,r

. 0 T 

### _•

PATTERSON, Rob (cont'd)

Technical 

### Over twenty one years experience with EPA and Texas Air Experience 

### Control Board methods of analysis of both stationary and (cont'd) ambient air samples. Particulate matter, S0 3 , S0 2 , H 2 SO 4

,



### NO X , CO, CO 2 , 0 2 , H 2 S, F, TRS, HCI, C1 2 , NH 3 , VOC, C l -C 7 , and other organics. Both laboratory and on-site analyses were performed. Experienced in the sampling and analysis of commercial calibration gas cylinders for sulfur dioxide, oxides of nitrogen, carbon dioxide, oxygen, carbon monoxide, and Cl-C7 hydrocarbons. Thoroughly trained in the operation and routine maintenance of the following: • MSA LIRA Model 202S Infrared Analyzer • Analytical Instrument Development, Inc. Model 340A Calibration System • Shimadzu GC-Mini 2 Gas Chromatograph • Thermo Environmental Model 10AR Oxides of Nitrogen Analyzer • Thermo Oxygen Analyzer • Teledyne Model 326 Oxygen Analyzer • Thermo Environmental Model 48 Carbon Monoxide Analyzer • Thermo Environmental Model 40 Sulfur Dioxide Analyzer • Ratfisch Model RS 100 Total Hydrocarbon Analyzer • Western Research Model 721AT Sulfur Dioxide Analyzer • Horiba Model PIR 2000 Carbon Dioxide Analyzer • Ratfisch Model RS 55 Total Hydrocarbon Analyzer • J.U.M. Model VE-7 Total Hydrocarbon Analyzer

08-203 1-3

# METC , ofto

JAMES R. MONFRIES; Senior Quality Assurance Manager
Education B. S. 1975, University of Texas. at Arlington; Arlington, Texas,

in Biology with a minor in Chemistry. Graduate work at the University of Texas at Dallas in the Environmental Science Department. Professional Attended a two-day short course, "Performing and Observing Training Source Sampling" in Dallas, Texas, July 1976. Courses
Certification Certified Visible Emissions Evaluator
Professional Air and Waste Management Association Memberships Source Evaluation Society - Past President
Technical Participated in the sampling of over 700 sources, serving in the Experience supervisory capacity on over 500 sources. Many of the sources

were sampled simultaneously using more than one sampling train at several points in the flue gas stream, 1976-present. Has also supervised several ambient air monitoring studies, including a permanent five-station high volume air sampling network in South Texas, a permanent four-station high volumeair sampling network in Pennsylvania, and a permanent sevenstation sulfur dioxide sampling network in East Texas. Was Quality Assurance Manager for several ambient air monitoring studies; including a four-station high volume air sampling network for TSP and PM10 in Midlothian, Texas; a single-station high volume air sampling network for PM10 in South Texas; a two-station high volume air sampling network for TSP 

## in Wichita Falls, Texas; and a four-station continuous air sampling network for TSP and PM10 in Jewett, Texas using Thermo Andersen FH 62 C14 Beta Gauge Dust Monitors.

(continued) 08-203 

# 2

# ~ m ~ 

# rco

MONFRIES, James (cont'd)

Twenty years experience with EPA and Texas Commission on Environmental Quality methods of analysis of both source and ambient air samples for particulates, S0 2 , S0 3 , H 2 SO 4 , 1-1 2 S, HCI, C1 2 , NO X , Hydrocarbons, and TRS. Experienced in the analysis of commercial calibration gas cylinders for sulfur dioxide and oxides of nitrogen. Experienced with VOST and Modified Method 5 Sampling Procedures. Thoroughly trained in the operation and routine maintenance of the following: • Lear Siegler, Inc. SM800 Stack Gas Monitor • Du Pont Model 460/1 Photometric Analyzer System • Lear Siegler, Inc. SM1000 Ambient S02 Monitor • Calibrated Instruments Ultragas S02 Monitor • Meloy 285E S02 Analyzer • Meloy SA-700 Fluorescent S02 Analyzer • MSA LIRA Model 202S Infrared Analyzer • Analytical Instrument Development, Inc. Model 340A Calibration System • Shimadzu GC-Mini 2 Gas Chromatograph • Thermo Environmental Model 10S NO x Analyzer • Thermo Oxygen Analyzer • Teledyne Model 326 Oxygen Analyzer • Thermo Environmental Model 48 Carbon Monoxide Analyzer • Thermo Environmental Model 40 Sulfur Dioxide Analyzer • RatFisch Model RS 103 Total Hydrocarbon Analyzer • Western Research Model 721AT Sulfur Dioxide Analyzer • Horiba Model PIR 2000 Carbon Dioxide Analyzer • RatFisch Model RS 55 Total Hydrocarbon Analyzer • J.U.M. Model VE-7 Total Hydrocarbon Analyzer • Thermo Andersen Model FH 62 C14 Dust Monitor

08-203 1-5

# ~ 

# •

JEFF KNAPP; Project Manager
Education 

### Nuclear Engineering, 1994 — U. S. Navy
Professional 

### Dangerous Good Shipping Training
Certifications 

### HAZMAT certified

Adult CPR certified Standard First Aid certified MSHA certified
Technical 

### Participated in the sampling of over 250 sources, including several Experience 

### of which were sampled simultaneously using more than one

sampling train. Thoroughly trained in all EPA testing procedures, 2006-present. Successfully perFormed over 200 compliance tests using FTIR for a variety of industries. Experienced with all SW846 and 40 CFR 60 sampling trains.

08-203 

### a

# r . !

JERRY McDONALD; Environmental Scientist I
Education B. S. Wildlife Biology, December 2006; Texas State, San Marcos,

Texas. Technical Experience Participated in the sampling of over 25 sources, including

several of which were sampled simultaneously using more than one sampling train. Thoroughly trained in all EPA testing procedures, 2008-present.

08-203 1-7