### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions** Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information** Parent Company

Name: Address: City : Country : United States Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):
**PVC Production Facility General Information** Facility Name: Facility Address: Facility City : Facility Technical Contact Name: Technical Contact Telephone Number: Technical Contact Email: Number of employees attached to the PVC production facility : Approx 50 Midland 1790 Building - W ashington Street The Dow Chemical Company

(989) 636-5895 jsdole@dow.com SARAN Resins 564 Building Midland Jamie Dole

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater** 

State: Michigan Zip Code: 48674

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): >1500

State: Michigan Zip Code: 48667

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER** Process Unit ID: Viny l Train Process Equipment ID: N/A Wa stewater Feed Rate (lb/hr): Feed Temperature (°F): Feed Inlet Pressure (psia): Liquid Loading Rate (liters/m2): Steam Feed Rate (lb/hr): Steam to Feed Ratio (kg steam/liter of wastewater): Operating Temperature (°F): Operating Pressure (psig): Total Number of Stages: Overall Calculated Tray Efficiency : Stripping Factor: Flow configuration (countercurrent, cocurrent): Number of Actual Trays: Colum n Height (meters): Year Equipm ent Installed: Equipm ent Currently

Regulated Under (cite regulations): 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions** Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:
If the above stripper feed rate or capacity does not equal the maximum design rate or capacity , please provide those values: 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessaryPlease also provide the stripper feed rate in liters per hour, or liters for batch strippers: liters/hour liters If the above stripper feed rate or capacity does not equal the maximum design rate or capacity , please provide those values: liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

Vinyl Train W- 1 Vinyl Train W- 3 Vinyl Train W- 4 Vinyl Train W- 5 Vinyl Train We t Screener and Centrifuge W- 7/6 Vinyl Train Dryer PM Scrubber W- 8 Vinyl Train CTW Blowdown W- 9 Vinyl Train SC-463 W- 10 Vinyl Train Finishing End Equipm ent W ashing W- 11 Vinyl Train Reactor Gamma W ashes W- 12 Vinyl Train W- 13 **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream**

Caustic Scrubber **PVC Process Wastewater**  **Stream ID**

Wa ter Scrubber V-1145 Inert Evac System Quench

Reactor Steady

Bearing Flush **2 Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System**  **1 2**  **3 4**  **5 6** 

**Min** Vinyl Train K1/K2 KO Pot Other Batch W- 2 0

**Table 3. PVC Process Wastewater Destination Codes Table**
Wa stewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3**

**Min Ma** **x Destination Description**  **PVC Process Wastewater**  **Treatment System ID**  **PVC Process Unit ID**  **PVC Process Wastewater**  **Stream ID Is this**  **process wastewater**  **treatment system batch**  **or continuous operation?**  **Ty pe of Process**  **Wastewater Treatment System** 

**1**

N/A **Process Wastewater Stream Flow Rate (gallons per day)**  **Source of Process Wastewater Stream PVC Process Wastewater Stream Flow Rate** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av**  **erage**

0 400 200 Estimated 365 0 79200 76320 Estimated 365 0 57600 53280 Estimated 365 0 13824 13680 Estimated 365 0 64800 50395 Estimated 275 0 79200 72000 Estimated 275 0 2401 1200 Estimated 365 0 1300 640 Estimated 365 0 10800 440 Estimated 365 0 36000 1550 Estimated 365 0 160 25 Estimated 365 **Operating Days Per Year**  **Flow Rate Determination**  **Me thod**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) 7**  **8 9**  **10 11** 

**Ma x**  **Av erage**  12000 3000 Estimated 365 WWT

**Code** WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 4**  **5 6**  **7**

**Av erage**  **PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below)

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Operating Days**  **Per Year**

**Process Wastewater Stream Flow Rate**

**(gallons per day) Flow Rate**  **Determination Me**  **thod PVC Process**  **Wastewater Treatment**  **System ID PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Flow Rate**  **Determination Me**  **thod**

**Operating Days Per Year** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

V-1145 Inert Evac Tank T-1501 Quench T-1502 Wa ter Scrubber T-1503 Caustic Scrubber SC-702 and CF-702 We t Screener and Centrifuge V-812 PM Scrubber CTW -1 Cooling Tower SC-463 Screening Tank Backend Process Equipment Wa shing operations between batches and/or for maintenance. Process Reactors Wa shing operations between batches and/or for maintenance. Process Reactors Wa shing operations between batches and/or for maintenance. **Originating PVC Process Equipment Description**  **Originating PVC Process Equipment ID** **12 13** 

On-Site NPDES W WT , no MACT treatment required Yes

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recycled **As sociated Destination**  **Information** (Refer to Table 3 below)

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Is this PVC process wastewater**  **stream exposed to the atmosphere at any point between the outlet of**  **the PVC process wastewater treatment system and its**  **destination? 11**  **12**

WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required WWT On-Site NPDES W WT , no MACT treatment required **PVC Process Wastewater Stream Destination Code**  (Refer to Table 3 below) **As sociated Destination Information** **14**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

Batch stripper

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 13** 

Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? If your response in Column 3 is "Other" then please provide a description of the process wastewaetr** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P**  107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethy lpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethy lene) 1330207 Xylenes (isomers and mixtures)

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

The Dow Chemical Company SARAN Resins

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?**  SW -846-8015C SW -846-8015C SW -846-8315A SW -846-8315A SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8260B SW -846-8260B 5 Non-detect SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B 0.5 Non-detect SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B 0.5 Non-detect SW -846-8260B SW -846-8260B **Sample Date -->** Suspension

**Lab Sample ID --> Lab Report ID -->**  **An alysis Date -->**  **Stream Temperature (degrees F) --> Stream Flow Rate (gallons per minute) -->**  **Resin Type (suspension, dispersion, bulk, etc.) -->**

109.4 240 gpm 02/05/13

445941 VOA13-07607 02/07/13 **Flow Rate Determination Method -->** EstimatedSW -846-8260B

SW -846-8260B 0.5 Non-detect SW -846-8260B 0.5 Non-detect SW -846-8260B SW -846-8260B 0.5 Non-detect EPA Method 107 SW -846-8260B 1 Non-detect SW -846-8260B1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension

02/07/13 446103 **1 2** 

127.4 240 gpm 02/06/13

VOA13-07614 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension

02/13/13 446214 446470 **3**

129.2 105.8 240 gpm 240 gpm 02/11/13 02/08/13

02/13/13 VOA13-07618 VOA13-07623 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1.1 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension

446583 **4 5** 

131 240 gpm 02/12/13

02/13/13 VOA13-07629 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension

129.2 240 gpm 240 gpm

446675 446878 **6** 02/13/13 02/15/13

132.8 02/13/13 02/19/13 VOA13-07631 VOA13-07641 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension 240 gpm 02/16/13 **7 8** 

123.8 02/19/13 VOA13-07642 446960 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension Estimated Estimated 240 gpm 240 gpm 02/18/13 02/19/13 **9**

131 132.8 02/19/13 02/19/13 VOA13-07646 VOA13-07650 447110 4472280.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension Estimated 240 gpm Estimated 02/21/13 **10 11** 

123.8 02/25/13 447429 VOA13-076680.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension 240 gpm 240 gpm 105.8 125.6 Estimated Estimated 02/22/13 02/23/13 **12**

02/25/13 02/25/13 447536 447603 VOA13-07677 VOA13-076780.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension 240 gpm 125.6 Estimated Estimated **13 14**  02/26/13

03/01/13 447858 VOA13-076850.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension 240 gpm 104 Estimated **15** 02/27/13 03/01/13

127.4 Estimated 03/01/13 03/05/13 447973 VOA13-07692 VOA13-07706 448267 240 gpm0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension **17 16**  03/02/13

Estimated Estimated 118.4 VOA13-07707 448268 03/05/13 240 gpm0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension **18** 03/06/13 03/04/13

Estimated Estimated 129.2 140 03/11/13 VOA13-07720 VOA13-07709 448413 448645 03/05/13 240 gpm 240 gpm0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 1.3**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension **19 20**  03/07/13 240 gpm Estimated Estimated 122 03/11/13 VOA13-07725 4487580.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension **21** 03/08/13 03/09/13

149 Estimated Estimated 129.2 VOA13-07728 03/11/13 03/11/13 240 gpm 240 gpm

448839 448925 VOA13-077300.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension Estimated Estimated 131 03/11/13 240 gpm

448968 VOA13-07731 03/10/13 **22 23** 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension

131 03/11/13 03/14/13 VOA13-07735 VOA13-07740 449068 449165 240 gpm 240 gpm 03/11/13 03/12/13 **24**

118.4 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension **26** 03/16/13 **25**

Estimated 240 gpm 131

449557 03/20/13 VOA13-07758 Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect Suspension Suspension **27** 03/17/13 03/18/13 240 gpm 240 gpm 111.2 147.2

449639 449723 03/20/13 03/20/13 VOA13-07760 VOA13-07766 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension **28**

VOA13-07771 449836 **29** 03/19/13 240 gpm 152.6 03/20/13 Estimated Estimated0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s)**

5 Non-detect

0.5 Non-detect

0.5 Non-detect Suspension

03/22/13 VOA13-07773 Estimated

449925 **30** 03/20/13 240 gpm 145.40.5 Non-detect 0.5 Non-detect 0.5 Non-detect 1 Non-detect

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P**  107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethy lpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethy lene) 1330207 Xylenes (isomers and mixtures)

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

The Dow Chemical Company SARAN Resins

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?**  SW -846-8015C SW -846-8015C SW -846-8315A SW -846-8315A SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B **Sample Date -->** 02/05/13 **Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**An alysis Date -->**  Duplicate sample not collected. **Lab Report ID --> Lab Sample ID -->** SW -846-8260B

SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B EPA Method 107 SW -846-8260B SW -846-8260B1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)** 02/06/13 **1 2** 

Duplicate sample not collected.**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  02/08/13 02/11/13 **3**

Duplicate sample not collected. Duplicate sample not collected.**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 4**  **5** 02/12/13 Suspension 240 gpm Estimated 131 02/12/13 K2 7041670.83 2.65**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **6** 02/13/13 02/15/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 129.2 132.8 02/13/13 02/15/13 K1 K1 704267 7044941.75 0.44 2.32 0.76**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 7**  **8** 02/16/13 Suspension 240 gpm Estimated Estimated 123.8 02/16/13 K1 7045920 0**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **9** 02/18/13 02/19/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 131 132.8 02/18/13 02/19/13 K2 K1 704815 7048940 1.03 0.42 1.18**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 10**  **11** 02/21/13 Suspension 240 gpm Estimated Estimated 123.8 02/21/13 K2 7050830.2 1.02**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **12** 02/22/13 02/23/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 105.8 125.6 02/22/13 02/23/13 K1 K2 705217 7053340.34 0.95 1.73 2.43**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 13**  **14** 02/26/13 Suspension 240 gpm Estimated Estimated 125.6 02/26/13 K2 7057151.24 1.23**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **15** 02/27/13 03/01/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 104 127.4 02/27/13 03/01/13 K1 K2 705847 7061850.47 0.37 1.76 2.54**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 16**  **17** 03/02/13 Suspension 240 gpm Estimated Estimated 118.4 03/02/13 K1 7062600.37 4.44**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **18** 03/04/13 03/06/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 129.2 140 03/04/13 03/06/13 K2 K2 706454 7067281.04 0.81 2.67 3.6**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 19**  **20** 03/07/13 Suspension 240 gpm Estimated Estimated 122 03/07/13 K1 7069460 1.07**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **21** 03/09/13 03/08/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 149 129.2 03/08/13 03/09/13 K2 K2 707018 7071671.18 0 2.44 1.08**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 22**  **23** 03/10/13 Suspension 240 gpm Estimated Estimated 131 03/10/13 K1 7072300.52 2.75**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **24** 03/11/13 03/12/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 118.4 131 03/11/13 03/12/13 K2 K1 707350 7074360.44 0.79 1.37 1.16**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 25**  **26** 03/16/13 Suspension 240 gpm Estimated Estimated 131 03/16/13 K2 7077630 0.94**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **27** 03/17/13 03/18/13 Suspension Suspension 240 gpm 240 gpm Estimated Estimated 111.2 147.2 03/17/13 03/18/13 K1 K2 707847 7079161.22 1.37 0.93 1.04**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 28**  **29** 03/19/13 Suspension 240 gpm Estimated Estimated 152.6 03/19/13 K1 7080020 0**Concentration**

**(ppmw) Non-Detect?**  **Note(s) 30**  03/20/13 Suspension 240 gpm Estimated 145.4 03/20/13 K2 7080630.76 0.01

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P**  107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethy lpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethy lene) 1330207 Xylenes (isomers and mixtures)

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

The Dow Chemical Company SARAN Resins

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?**  SW -846-8015C SW -846-8015C SW -846-8315A SW -846-8315A SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B **Sample Date -->** 02/05/13 **Resin Type (suspension, dispersion, bulk, etc.) -->** Suspension

**Stream Flow Rate (gallons per minute) -->** 225 gpm **Flow Rate Determination Method -->** Estimated **Stream Temperature (degrees F) -->** 109.4

**An alysis Date -->**  02/05/13 **Lab Report ID -->** K1 **Lab Sample ID -->** 703491SW -846-8260B

SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B EPA Method 107 0 SW -846-8260B 0 SW -846-8260B1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)** 02/06/13 **1 2**  Suspension 225 gpm Estimated Estimated 127.4 02/06/13 K2 7035880 0**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  02/08/13 02/11/13 **3** Suspension Suspension 225 gpm 225 gpm Estimated Estimated 129.2 105.8 02/08/13 02/11/13 K2 K1 703831 7040610.89 1.17 3.67 1.53**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 4**  **5** 02/12/13 Suspension 225 gpm Estimated Estimated 131 02/12/13 K2 7041620.74 2.58**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **6** 02/13/13 02/15/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 129.2 132.8 02/13/13 02/15/13 K1 K1 704263 7044930 0.44 0 0.97**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 7**  **8** 02/16/13 Suspension 225 gpm Estimated Estimated 123.8 02/16/13 K1 7045910 0**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **9** 02/18/13 02/19/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 131 132.8 02/18/13 02/19/13 K2 K1 704813 7048930 1.16 1.15 1.13**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 10**  **11** 02/21/13 Suspension 225 gpm Estimated Estimated 123.8 02/21/13 K2 7050810.34 2.07**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **12** 02/22/13 02/23/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 105.8 125.6 02/22/13 02/23/13 K1 K2 705216 7053340.34 0.82 2.29 1.89**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 13**  **14** 02/26/13 Suspension 225 gpm Estimated Estimated 125.6 02/26/13 K2 7057130.75 2.77**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **15** 02/27/13 03/01/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 104 127.4 02/27/13 03/01/13 K1 K2 705846 7061650.36 0.07 3.35 1.6**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 16**  **17** 03/02/13 Suspension 225 gpm Estimated Estimated 118.4 03/02/13 K1 7062570.43 2.85**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **18** 03/04/13 03/06/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 129.2 140 03/04/13 03/06/13 K2 K2 706450 7067270.87 0.72 2.39 3.88**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 19**  **20** 03/07/13 Suspension 225 gpm Estimated Estimated 122 03/07/13 K1 7069460.31 2.03**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **21** 03/09/13 03/08/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 149 129.2 03/08/13 03/09/13 K2 K2 707019 7071661.22 0 2.24 1.14**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 22**  **23** 03/10/13 Suspension 225 gpm Estimated Estimated 131 03/10/13 K1 7072290.65 3.94**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **24** 03/11/13 03/12/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 118.4 131 03/11/13 03/12/13 K2 K1 707349 7074350.48 0.83 1.37 1.16**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 25**  **26** 03/16/13 Suspension 225 gpm Estimated Estimated 131 03/16/13 K2 7077620 0

r**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **27** 03/17/13 03/18/13 Suspension Suspension 225 gpm 225 gpm Estimated Estimated 111.2 147.2 03/17/13 03/18/13 K1 K2 707835 7079151.81 1.31 1.92 1.22**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 28**  **29** 03/19/13 Suspension 225 gpm Estimated Estimated 152.6 03/19/13 K1 7080010 0**Concentration**

**(ppmw) Non-Detect?**  **Note(s) 30**  03/20/13 Suspension 225 gpm Estimated 145.4 03/20/13 K2 7080620.77 0.18