November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country:

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility:
ers (PVC) Production Process Wastewater

State: Zip Code:

hes, and related establishments owned):

State: Zip Code:
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID:

Process Equipment ID:

Wastewater Feed Rate (lb/hr):

Feed Temperature (°F):

Feed Inlet Pressure (psia):

Liquid Loading Rate (liters/m2):

Steam Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater):

Operating Temperature (°F):

Operating Pressure (psig):

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent):

Number of Actual Trays:

Column Height (meters):

Year Equipment Installed:

Equipment Currently Regulated Under (cite regulations):

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: liters/hour

 liters

m design rate or capacity, please provide those values:

 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production fa

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wa

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for e

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

PVC Process 

Wastewater 

Stream ID

2
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6

Min

Table 3. PVC Process Wastewater Destination Codes Table

Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment S

2 3

Min Max

Type of Process 

Wastewater 

Treatment System

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

1

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

PVC Process Wastewate

VC) Production Process Wastewater

hin the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process waste

VC production process wastewater treatment system.

ter treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC prod

tment System

4 5 6 7 8

Min Max Average

Operating Days Per 

Year

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day)
7 8 9 10 11

Max Average

Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

Wastewater Treatment System

4 5 6 7

Average

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Operating Days 

Per Year

Process Wastewater Destination D

water Stream Flow Rate 

ons per day)

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

VC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

eated by a PVC production process wastewater treatment system.

hat does not originate from the PVC production facility.

9 10

Originating PVC Process 

Equipment Description

Originating PVC Process 

Equipment ID
12 13

e of the wastewater treatment system

ere in the process the stream is recycled

Associated Destination 

Information

(Refer to Table 3 below)

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

11 12

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

able 1 and Column 11 of Table 2

13

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?
de a description of the process wastewaetr 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

0

0

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C

SW-846-8015C

SW-846-8315A

SW-846-8315A

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->
SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

EPA Method 107

SW-846-8260B

SW-846-8260B
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

1 2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

3

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

4 5

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

6

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

7 8

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

9

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 11

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

12

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

13 14

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

15

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

16 17

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

18

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

19 20

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

21

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

22 23

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

24

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

25 26

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

27

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

28 29

Concentration 

(ppmw) Non-Detect? Note(s)

30