November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: United States

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: Approx 50

Midland

1790 Building - Washington Street

The Dow Chemical Company

(989) 636-5895

jsdole@dow.com

SARAN Resins

564 Building

Midland

Jamie Dole
ers (PVC) Production Process Wastewater

State: Michigan Zip Code: 48674

hes, and related establishments owned): >1500

State: Michigan Zip Code: 48667
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: Vinyl Train

Process Equipment ID: N/A

Wastewater Feed Rate (lb/hr):

Feed Temperature (°F):

Feed Inlet Pressure (psia):

Liquid Loading Rate (liters/m2):

Steam Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater):

Operating Temperature (°F):

Operating Pressure (psig):

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent):

Number of Actual Trays:

Column Height (meters):

Year Equipment Installed:

Equipment Currently Regulated Under (cite regulations):

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: liters/hour

 liters

m design rate or capacity, please provide those values:

 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production fa

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wa

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for e

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3

Vinyl Train W-1

Vinyl Train W-3

Vinyl Train W-4

Vinyl Train W-5

Vinyl Train Wet Screener and Centrifuge W-7/6

Vinyl Train Dryer PM Scrubber W-8

Vinyl Train CTW Blowdown W-9

Vinyl Train SC-463 W-10

Vinyl Train Finishing End Equipment Washing W-11

Vinyl Train Reactor Gamma Washes W-12

Vinyl Train W-13

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

Caustic Scrubber

PVC Process 

Wastewater 

Stream ID

Water Scrubber

V-1145 Inert Evac System

Quench

Reactor Steady Bearing Flush

2
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6

Min

Vinyl Train K1/K2 KO Pot Other Batch W-2 0

Table 3. PVC Process Wastewater Destination Codes Table

Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment S

2 3

Min Max

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

Type of Process 

Wastewater 

Treatment System

1

N/A

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

PVC Process Wastewate

VC) Production Process Wastewater

hin the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process waste

VC production process wastewater treatment system.

ter treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC prod

tment System

4 5 6 7 8

Min Max Average

0 400 200 Estimated 365

0 79200 76320 Estimated 365

0 57600 53280 Estimated 365

0 13824 13680 Estimated 365

0 64800 50395 Estimated 275

0 79200 72000 Estimated 275

0 2401 1200 Estimated 365

0 1300 640 Estimated 365

0 10800 440 Estimated 365

0 36000 1550 Estimated 365

0 160 25 Estimated 365

Operating Days Per 

Year

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day)
7 8 9 10 11

Max Average

12000 3000 Estimated 365 WWT

Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

Wastewater Treatment System

4 5 6 7

Average

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Process Wastewater Destination D

Operating Days 

Per Year

water Stream Flow Rate 

ons per day)

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

VC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

eated by a PVC production process wastewater treatment system.

hat does not originate from the PVC production facility.

9 10

V-1145 Inert Evac Tank

T-1501 Quench

T-1502 Water Scrubber

T-1503 Caustic Scrubber

SC-702 and CF-702 Wet Screener and Centrifuge

V-812 PM Scrubber

CTW-1 Cooling Tower

SC-463 Screening Tank

Backend Process Equipment Washing operations between batches and/or for maintenance.

Process Reactors Washing operations between batches and/or for maintenance.

Process Reactors Washing operations between batches and/or for maintenance.

Originating PVC Process 

Equipment Description

Originating PVC Process 

Equipment ID
12 13

On-Site NPDES WWT, no MACT treatment required Yes

e of the wastewater treatment system

ere in the process the stream is recycled

Associated Destination 

Information

(Refer to Table 3 below)

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

11 12

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

WWT On-Site NPDES WWT, no MACT treatment required

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

Batch stripper

able 1 and Column 11 of Table 2

13

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Yes

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?
de a description of the process wastewaetr 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

The Dow Chemical Company

SARAN Resins

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C

SW-846-8015C

SW-846-8315A

SW-846-8315A

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8260B

SW-846-8260B 5 Non-detect

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B 0.5 Non-detect

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B 0.5 Non-detect

SW-846-8260B

SW-846-8260B

Sample Date -->

Suspension

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

109.4

240 gpm

02/05/13

445941

VOA13-07607

02/07/13

Flow Rate Determination Method --> Estimated
SW-846-8260B

SW-846-8260B 0.5 Non-detect

SW-846-8260B 0.5 Non-detect

SW-846-8260B

SW-846-8260B 0.5 Non-detect

EPA Method 107

SW-846-8260B1 Non-detect

SW-846-8260B
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

02/07/13

446103

1 2

127.4

240 gpm

02/06/13

VOA13-07614

Estimated Estimated
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

02/13/13

446214 446470

3

129.2 105.8

240 gpm 240 gpm

02/08/13 02/11/13

02/13/13

VOA13-07618 VOA13-07623

Estimated Estimated
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

1.11 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

446583

4 5

131

240 gpm

02/12/13

02/13/13

VOA13-07629

Estimated Estimated
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

129.2

240 gpm 240 gpm

446675 446878

6

02/13/13 02/15/13

132.8

02/13/13 02/19/13

VOA13-07631 VOA13-07641

Estimated Estimated
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

240 gpm

02/16/13

7 8

123.8

02/19/13

VOA13-07642

446960

Estimated Estimated
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

Estimated Estimated

240 gpm 240 gpm

02/18/13 02/19/13

9

131 132.8

02/19/13 02/19/13

VOA13-07646 VOA13-07650

447110 447228
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

Estimated

240 gpm

Estimated

02/21/13

10 11

123.8

02/25/13

447429

VOA13-07668
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

240 gpm 240 gpm

105.8 125.6

Estimated Estimated

02/22/13 02/23/13

12

02/25/13 02/25/13

447536 447603

VOA13-07677 VOA13-07678
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

240 gpm

125.6

Estimated Estimated

13 14

02/26/13

03/01/13

447858

VOA13-07685
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

240 gpm

104

Estimated

15

02/27/13 03/01/13

127.4

Estimated

03/01/13 03/05/13

447973

VOA13-07692 VOA13-07706

448267

240 gpm
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

16 17

03/02/13

Estimated Estimated

118.4

VOA13-07707

448268

03/05/13

240 gpm
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

18

03/04/13 03/06/13

Estimated Estimated

129.2 140

03/11/13

VOA13-07709 VOA13-07720

448413 448645

03/05/13

240 gpm 240 gpm
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 1.3
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

19 20

03/07/13

240 gpm

Estimated Estimated

122

03/11/13

VOA13-07725

448758
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

21

03/08/13 03/09/13

149

Estimated Estimated

129.2

VOA13-07728

03/11/13 03/11/13

240 gpm 240 gpm

448839 448925

VOA13-07730
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

Estimated Estimated

131

03/11/13

240 gpm

448968

VOA13-07731

03/10/13

22 23
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

131

03/11/13 03/14/13

VOA13-07735 VOA13-07740

449068 449165

240 gpm 240 gpm

03/11/13 03/12/13

24

118.4

Estimated Estimated
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

26

03/16/13

25

Estimated

240 gpm

131

449557

03/20/13

VOA13-07758

Estimated
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 Non-detect 5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

Suspension Suspension

27

03/17/13 03/18/13

240 gpm 240 gpm

111.2 147.2

449639 449723

03/20/13 03/20/13

VOA13-07760 VOA13-07766

Estimated Estimated
0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect

0.5 Non-detect 0.5 Non-detect 1 Non-detect 1 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

28

VOA13-07771

449836

29

03/19/13

240 gpm

152.6

03/20/13

Estimated Estimated
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s)

5 Non-detect

0.5 Non-detect

0.5 Non-detect

Suspension

03/22/13

VOA13-07773

Estimated

449925

30

03/20/13

240 gpm

145.4
0.5 Non-detect

0.5 Non-detect

0.5 Non-detect

1 Non-detect
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

The Dow Chemical Company

SARAN Resins

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C

SW-846-8015C

SW-846-8315A

SW-846-8315A

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

Sample Date --> 02/05/13

Resin Type (suspension, dispersion, bulk, etc.) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Stream Temperature (degrees F) -->

Analysis Date --> Duplicate sample not collected.

Lab Report ID -->

Lab Sample ID -->
SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

EPA Method 107

SW-846-8260B

SW-846-8260B
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

02/06/13

1 2

Duplicate sample not collected.

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

02/08/13 02/11/13

3

Duplicate sample not collected. Duplicate sample not collected.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

45

02/12/13

Suspension

240 gpm

Estimated

131

02/12/13

K2

704167
0.83

2.65
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

6

02/13/13 02/15/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

129.2 132.8

02/13/13 02/15/13

K1 K1

704267 704494
1.75 0.44

2.32 0.76
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

78

02/16/13

Suspension

240 gpm

Estimated Estimated

123.8

02/16/13

K1

704592
00
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

9

02/18/13 02/19/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

131 132.8

02/18/13 02/19/13

K2 K1

704815 704894
0 1.03

0.42 1.18
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 11

02/21/13

Suspension

240 gpm

Estimated Estimated

123.8

02/21/13

K2

705083
0.2

1.02
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

12

02/22/13 02/23/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

105.8 125.6

02/22/13 02/23/13

K1 K2

705217 705334
0.34 0.95

1.73 2.43
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

13 14

02/26/13

Suspension

240 gpm

Estimated Estimated

125.6

02/26/13

K2

705715
1.24

1.23
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

15

02/27/13 03/01/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

104 127.4

02/27/13 03/01/13

K1 K2

705847 706185
0.47 0.37

1.76 2.54
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

16 17

03/02/13

Suspension

240 gpm

Estimated Estimated

118.4

03/02/13

K1

706260
0.37

4.44
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

18

03/04/13 03/06/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

129.2 140

03/04/13 03/06/13

K2 K2

706454 706728
1.04 0.81

2.67 3.6
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

19 20

03/07/13

Suspension

240 gpm

Estimated Estimated

122

03/07/13

K1

706946
0

1.07
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

21

03/08/13 03/09/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

129.2 149

03/08/13 03/09/13

K2 K2

707018 707167
1.18

0

2.44 1.08
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

22 23

03/10/13

Suspension

240 gpm

Estimated Estimated

131

03/10/13

K1

707230
0.52

2.75
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

24

03/11/13 03/12/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

118.4 131

03/11/13 03/12/13

K2 K1

707350 707436
0.44 0.79

1.37 1.16
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

25 26

03/16/13

Suspension

240 gpm

Estimated Estimated

131

03/16/13

K2

707763
0

0.94
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

27

03/17/13 03/18/13

Suspension Suspension

240 gpm 240 gpm

Estimated Estimated

111.2 147.2

03/17/13 03/18/13

K1 K2

707847 707916
1.22 1.37

0.93 1.04
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

28 29

03/19/13

Suspension

240 gpm

Estimated Estimated

152.6

03/19/13

K1

708002
00
Concentration 

(ppmw) Non-Detect? Note(s)

30

03/20/13

Suspension

240 gpm

Estimated

145.4

03/20/13

K2

708063
0.76

0.01
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

The Dow Chemical Company

SARAN Resins

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C

SW-846-8015C

SW-846-8315A

SW-846-8315A

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

Sample Date --> 02/05/13

Resin Type (suspension, dispersion, bulk, etc.) --> Suspension

Stream Flow Rate (gallons per minute) --> 225 gpm

Flow Rate Determination Method --> Estimated

Stream Temperature (degrees F) --> 109.4

Analysis Date --> 02/05/13

Lab Report ID --> K1

Lab Sample ID --> 703491
SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

EPA Method 1070

SW-846-8260B0

SW-846-8260B
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

02/06/13

1 2

Suspension

225 gpm

Estimated Estimated

127.4

02/06/13

K2

703588
00
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

02/08/13 02/11/13

3

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

129.2 105.8

02/08/13 02/11/13

K2 K1

703831 704061
0.89 1.17

3.67 1.53
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

45

02/12/13

Suspension

225 gpm

Estimated Estimated

131

02/12/13

K2

704162
0.74

2.58
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

6

02/13/13 02/15/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

129.2 132.8

02/13/13 02/15/13

K1 K1

704263 704493
0 0.44 0 0.97
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

78

02/16/13

Suspension

225 gpm

Estimated Estimated

123.8

02/16/13

K1

704591
00
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

9

02/18/13 02/19/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

131 132.8

02/18/13 02/19/13

K2 K1

704813 704893
0 1.16

1.15 1.13
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 11

02/21/13

Suspension

225 gpm

Estimated Estimated

123.8

02/21/13

K2

705081
0.34

2.07
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

12

02/22/13 02/23/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

105.8 125.6

02/22/13 02/23/13

K1 K2

705216 705334
0.34 0.82

2.29 1.89
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

13 14

02/26/13

Suspension

225 gpm

Estimated Estimated

125.6

02/26/13

K2

705713
0.75

2.77
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

15

02/27/13 03/01/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

104 127.4

02/27/13 03/01/13

K1 K2

705846 706165
0.36 0.07

3.35 1.6
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

16 17

03/02/13

Suspension

225 gpm

Estimated Estimated

118.4

03/02/13

K1

706257
0.43

2.85
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

18

03/04/13 03/06/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

129.2 140

03/04/13 03/06/13

K2 K2

706450 706727
0.87 0.72

2.39 3.88
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

19 20

03/07/13

Suspension

225 gpm

Estimated Estimated

122

03/07/13

K1

706946
0.31

2.03
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

21

03/08/13 03/09/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

129.2 149

03/08/13 03/09/13

K2 K2

707019 707166
1.22

0

2.24 1.14
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

22 23

03/10/13

Suspension

225 gpm

Estimated Estimated

131

03/10/13

K1

707229
0.65

3.94
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

24

03/11/13 03/12/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

118.4 131

03/11/13 03/12/13

K2 K1

707349 707435
0.48 0.83

1.37 1.16
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

25 26

03/16/13

Suspension

225 gpm

Estimated Estimated

131

03/16/13

K2

707762
00

r
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

27

03/17/13 03/18/13

Suspension Suspension

225 gpm 225 gpm

Estimated Estimated

111.2 147.2

03/17/13 03/18/13

K1 K2

707835 707915
1.81 1.31

1.92 1.22
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

28 29

03/19/13

Suspension

225 gpm

Estimated Estimated

152.6

03/19/13

K1

708001
00
Concentration 

(ppmw) Non-Detect? Note(s)

30

03/20/13

Suspension

225 gpm

Estimated

145.4

03/20/13

K2

708062
0.77

0.18