### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**
**Instructions** Please complete this worksheet for y our parent company and PVC production facility

.
**Parent Company General Information** Parent Company

Name: Address: City : Country : Size of Com pany

(approximate number of employ ees including all subsidiaries, branches, and related establishments owned): **PVC Production Facility General Information** Facility Name: Facility Address: Facility City : Facility Technical Contact Name: Technical Contact Telephone Number: Technical Contact Email: Number of employ ees attached to the PVC production facility :

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater** 

State: Zip Code:

Size of Com pany

(approximate number of employ ees including all subsidiaries, branches, and related establishments owned):

State: Zip Code:

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy**  **stem Information Update**
**Instructions**
2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA**  **M STRIPPER** Process Unit ID: Process Equipment ID: Wa stewater Feed Rate (lb/hr): Feed Temperature (°F): Feed Inlet Pressure (psia): Liquid Loading Rate (liters/m2): Steam Feed Rate (lb/hr): Steam to Feed Ratio (kg steam/liter of wastewater): Operating Temperature (°F): Operating Pressure (psig): Total Number of Stages: Overall Calculated Tray Efficiency : Stripping Factor: Flow configuration (countercurrent, cocurrent): Number of Actual Trays: Colum n Height (meters): Year Equipm ent Installed: Equipm ent Currently

Regulated Under (cite regulations): 1. A copy

of your facility 's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions** Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: If the above stripper feed rate or capacity does not equal the maximum design rate or capacity , please provide those values: 1. A copy

of your facility 's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessaryPlease also provide the stripper feed rate in liters per hour, or liters for batch strippers: liters/hour liters If the above stripper feed rate or capacity does not equal the maximum design rate or capacity , please provide those values: liters/hour (max design) liters (max design) 1. A copy

of y our facility 's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 
**Instructions** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment sy stem but that does not originate from the PVC production facility

.
**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

**PVC Process Unit ID**  **Name of PVC Process Wastewater Stream PVC Process**  **Wastewater Stream ID**  **2 Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System**  **1 2**  **3 4**  **5 6** 

**Min**

**Table 3. PVC Process Wastewater Destination Codes Table** Wa stewater treatment system Discharge without treatment by pipeline, sewer, or other convey ance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recy cle to process Other
**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3**

**Min Ma**  **x Ty**  **pe of Process Wastewater**  **Treatment System**

**Destination Description PVC Process**  **Wastewater Treatment**  **System ID PVC Process**  **Unit ID PVC Process**  **Wastewater Stream ID**  **Is this process**  **wastewater treatment**  **system batch or continuous**  **operation?**

**1 Process Wastewater Stream Flow Rate**  **(gallons per day) Source of Process Wastewater Stream**  **PVC Process Wastewater Stream Flow Rate**

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment sy stem but that does not originate from the PVC production facility

.
**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma**  **x Av**  **erage Operating Days Per**  **Year Flow Rate**  **Determination Me**  **thod PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) 7**  **8 9**  **10 11** 

**Ma x**  **Av erage** 

**Code** WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recy cled OTHER Describe
**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 4**  **5 6**  **7**

**Av erage**  **PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below) **Operating Days Per Year** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**Process Wastewater Stream Flow Rate**

**(gallons per day) Flow Rate**  **Determination Me**  **thod PVC Process**  **Wastewater Treatment**  **System ID PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Flow Rate**  **Determination Me**  **thod**

**Operating Days Per Year** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment sy stem but that does not originate from the PVC production facility

.

**9 10** 

**Originating PVC Process Equipment Description**  **Originating PVC Process Equipment ID** **12 13** 

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recy cled **As sociated Destination**  **Information** (Refer to Table 3 below) **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 11**  **12**

**PVC Process Wastewater Stream Destination Code**  (Refer to Table 3 below) **As sociated Destination Information** **14**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 13** 

**Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? If your response in Column 3 is "Other" then please provide a description of the process wastewaetr** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 
**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P**  107211 Ethy lene gly col 67561 Methanol 75070 Acetaldehy de 50000 Formaldehy de 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethy lhexy l) phthalate (DEHP) 123319 Hy droquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethy lpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethy l chloride (Chloroethane) 100414 Ethy lbenzene 107062 Ethy lene dichloride (1,2-Dichloroethane) 75343 Ethy lidene dichloride (1,1-Dichloroethane) 74873 Methy l chloride (Chloromethane) 75092 Methy lene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methy l chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Viny l acetate 593602 Viny l bromide 75014 Viny l chloride 75354 Viny lidene chloride (1,1-Dichloroethy lene) 1330207 Xy lenes (isomers and mixtures)

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

0 0

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?**  SW -846-8015C SW -846-8015C SW -846-8315A SW -846-8315A SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B **Sample Date -->**

**Lab Sample ID --> Lab Report ID -->**  **An alysis Date -->**  **Stream Temperature (degrees F) --> Stream Flow Rate (gallons per minute) -->**  **Resin Type (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**SW -846-8260B

SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B EPA Method 107 SW -846-8260B SW -846-8260B1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 1**  **2 Concentration** 

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **3 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **4 5** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **6 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **7 8** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **9 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **10 11** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **12 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **13 14** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **15 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **17 16** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **18 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **19 20** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **21 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **22 23** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **24 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **26 25** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **27 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **28 29** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) 30**