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1 

First Quarter 2005 

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I 

Groundwater Sampling ~ gcfoo sj 

RED HILL FUEL STORAGE FACILITY, HAWAII ol (CC/ ~~ 

a-2,0M4' 

t 

April 2005 

Department of the Navy 

Commander, Pacific Division 

Naval Facilities Engineering Command 

Pearl Harbor, HI 96860-3134 

Naval Facilities Engineering Command 

NAVFAC PACIFIC 

Contract Number N62742-01-D-1806, CTO 0013 
First Quarter 2005 

Gr®untlwater Sarnpling 

RED HILL FUEL STORAGE FACILITY, HAWAII 

April 2005 

Prepared for: 

v 

n~el Pacmae s Enan,ee rmn crnirnerw 

' xwr.cvurrw 

Department of the Navy 

Commander, Pacific Division 

Naval Facilities Engineering Command 

258 Makalapa Drive, Suite #100 

Pearl Harbor, HI 96860-3134 

Prepared by: 

DAWSON GROUP, INC. 

3375 Koapaka Street, Suite B200 

Honolulu, Hawaii 96819-1862 

Prepared under: 

Contract Number N62742-01-D-1806, CTO 0013 
wAVrAl, rAt,trR. Kea rnll l ljUn~ liw 

Contract No.: N62742-01-D-1806, CTO 0013 Page iii 

First Quarter 2005 

Groundwater Sampling 

Red Hill Fuel Storage Facility, Hawaii 

April 2005 

Prepared by: 

DAWSON GROUP, INC. 

3375 Koapaka Street, Suite B-200 

Honolulu, Hawaii 96819 

~~~t ~2&~ 

Heather Kerr 

Project Manager / Environmental Scientist 

[2001022. 013 Red Hill 1Q05 GWJ Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No' N62742-01-D-1806. CTO 0013 Pe¢e iv 

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Contract No.: N62742-01-D-1806, CTO 0013 Page v 

EXECUTIVE SUMMARY 

The Department of the Navy, Naval Facilities Engineering Command, Pacific (NAVFAC PACIFIC) has 

retained Dawson Group, Inc. (DAWSON) to perform groundwater monitoring activities at the Red Hill 

Fuel Storage Facility (FSF), Hawaii. The Red Hill FSF consists of 20 active underground storage tanks 

(USTs) operated by the Fleet Industrial Supply Center (FISC) Pearl Harbor. Figure 1, Site Vicfnity Map, 

i[lustrates the location of the project site. 

This work was performed under NAVFAC PACIFIC Contract Number N62742-01-D-1806, Contract 

Task Order (CTO) 0013. This document is the first quarterly report and summarizes the following: field 

investigation, IDW disposal, sample results, and conclusions and recommendations for next sampling 

event. 

Site Backaround 

From 1998 to 2001, the Navy conducted an investigation at the facility to assess potential releases from 

the fuel storage facility. In February 2001, the Navy installed a one-inch diameter sentinel well (MWV I D) to monitor for contamination of the basal aquifer underlying the storage facility (AMEC Earth and 

Environmental, Inc. [AMEC], 2002). Sentinel well MW-V1D was installed and completed at 

approximately 100 feet below grade (tbg). At the time of well completion, depth to water in MW-V I D 

was measured at 86 fbg. The groundwater level at the project site fluctuates from dry season to wet 

season (AMEC, 2002). 

A second monitoring well (MW-V2S) was installed and completed above the water-bearing zone at 

approximately 52 fbg. This monitoring well is located southwest of sentinel well MW-V1D and does not 

contain either groundwater or product. MW-V2S was intentionally completed above the water-bearing 

zone in order to avoid creation of a possible direct conduit to the basal aquifer (AMEC, 2002). 

In February 2001, groundwater samples collected from sentinel well MW-VID contained detectable 

amounts of TPH ranging from 0.883 milligrams per liter (mg(L) to 1.05 mg/L and total lead ranging from 

0.0104 mg/L to 0.015 mg/L. The maximum total lead concentration in the samples was equal to the 

primary drinking water standard of 0.015 mg/L for lead and exceeded the State of Hawaii Department of 

Health (HDOH) Tier I groundwater action [evel (G WAL) of 0.0056 mg/L (US Navy, 2004). 

Following discussions with HDOH, a program was initiated to monitor the sentinel wel[ MW-V1D and 

the Navy Public Works Center (PWC) potable water stilling basin for indications of contamination from 

the upgradient tank farm. The recommended parameters for analyses were total petroleum hydrocarbons 

(TPH) as diesel, TPH as gasoline; benzene, toluene, ethylbenzene, and total xylenes (BTEX); 1,2- 

dichloroethane (DCA); polynuclear aromatic hydrocarbons (PAHs); total lead; and 1,2-dibromoethane 

(EDB) (US Navy, 2004). 

Field Activities 

Three surface water samples (two primary and one duplicate) were collected from the PWC potable water 

stilling basin and analyzed for TPH as diesel, TPH as gasoline, 1,2-DCA, BTEX, methyl-tert-butyl ether 

(MtBE), total lead, and EDB on 16 February 2005. 

Two groundwater samples (one primary and one duplicate) were collected from the sentinel well, 

MW-V1D and analyzed for TPH-D, TPH-G, 1,2-DCA, BTEX, Total Lead, and EDB on 17 February 

2005. 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Page vf 

Conclusions and Recommendations 

The following conclusions are based on the findings of previous investigations and the data collected 

during this investigation. 

Stillina Basin 

Total lead and toluene were the only constituents detected at concentrations above the 

laboratory MRLs in the stilling basin samples. AII detected concentrations were below 

HDOH Tier 1 GWALs. Toluene was present in the trip blank associated with these 

samples. 

Sentinel Well 

• Total lead was detected at a concentration above the HDOH Tier 1 GWAL but below the 

HDOH drinking water standard in the sentinel well samples. The February 2005 results 

were also below the 2002 investigation results (AMEC, 2002). 

• TPH as diesel was detected at a concentration above the laboratory MRL in both of the 

sentinel well samples. No action level has been established for this analyte. 

• Numerous PAHs (naphthalene, 2-methylnaphthalene, acenaphthene, dibenzofuran, 

fluorene, phenanthrene, fluoranthene, pyrene, chrysene, benzo(b)fluoranthene, and 

benzo(a)pyrene) were detected above the laboratory MRLs in both of the sentinel well 

samples. None of the detected concentrations exceeded the established HDOH Tier 1 

G WALs. 

• The groundwater in the upgradient sentinel well (MW-V1D) shows evidence of COPC 

contamination in the basal aquifer. 

Based on the findings during this investigation, DAWSON recommends the following actions: 

• Continue sampling at the stilling basin and the sentinel well during the next quarter (April 

through June 2005). 

[2001 022.013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806. CTO 0013 PaRe vii 

TABLE OF CONTENTS 

1. INTRODUCTION .................................................................................1-1 

1.1 ProjectObjectives ......................................................................................................................1-1 

1.2 Scope of Work ............................................................................................................................1-1 

2. BACKGROUND ..................................................................................2-1 

2.1 Site Location ..............................................................................................................................2-1 

2.2 Facility Description ....................................................................................................................2-1 

2.3 Previous Environmental Actions/Studies ...................................................................................2-1 

3. PROJECT ORGANIZATION ...............................................................3-1 

4. QUALITY OF DATA OBJECTIVES ....................................................4-1 

S. GENERAL WORK PROCEDURES ....................................................5-1 

5.1 Health and Safety Procedures .....................................................................................................5-1 

5.2 Equipment Decontamination ......................................................................................................5-1 

5.3 Investigation Derived Waste ......................................................................................................5-1 

5.3.1 Storage and Sampling .................................................................................................5-1 

5.3.2 IDW Disposal .............................................................................................................5-2 

6. SAMPLING METHODOLOGIES AND PROCEDURES ......................6-1 

6.1 Laboratory Analysis ...................................................................................................................6-1 

6.2 Stilling Basin Sampling Methodo[ogy .......................................................................................6-1 

6.2.1 Non-Entry Sampling in the Stilling Basin ..................................................................6-1 

6.2.2 Surface Water Sampling Methodology ......................................................................6-1 

6.2.3 Field Quality Control Sampling ..................................................................................6-2 

6.3 Sentinel Well Samp[ing Methodology .......................................................................................6-2 

6.3.1 Measurement of Static Water Level and Detection of an Immiscible Phase ..............6-2 

6.3.2 Well Purging Methodology ........................................................................................6-2 

6.3.3 Sample Collection Procedures ....................................................................................6-3 

6.3.4 Field Quality Control Sampling ..................................................................................6-3 

7. INVESTIGATION RESULTS ...............................................................7-5 

7.1 Stilling Basin Water Sample Results ..........................................................................................7-5 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill 1Q05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Page viii 

7.1.1 Total Lead ...................................................................................................................7-5 

7.1.2 Total Petroleum Hydrocarbons (TPH) ........................................................................7-5 

7.1.3 1,2-Dibromoethane (EDB) .........................................................................................7-5 

7.1.4 Volatile Organic Compounds (VOCs) ........................................................................7-5 

7.1.5 Polynuclear Aromatic Hydrocarbons (PAHs) ............................................................7-5 

7.2 Sentinel Well Groundwater Sample Results ..............................................................................7-6 

7.2.1 Total Lead ...................................................................................................................7-6 

7.2.2 Total Petroleum Hydrocarbons (TPH) ........................................................................7-6 

7.2.3 1,2-Dibromoethane (EDB) .........................................................................................7-6 

7.2.4 Volatile Organic Compounds (VOCs) ........................................................................7-6 

7.2.5 Polynuclear Aromatic Hydrocarbons (PAHs) ............................................................7-6 

7.3 Trip Blank Analytical Results ....................................................................................................7-7 

7.4 Data Quality Review ..................................................................................................................7-7 

7.4.1 Field Quality Assurance/Quality Control ...................................................................7-7 

7.4.2 Laboratory/Quality Control Data Assessment ............................................................7-7 

8. CONCLUSIONS AND RECOMMENDATIONS ...................................8-1 

9. REFERENCES ....................................................................................9-1 

[2001 022.013 Red Hill IQ05 GW] Dawson Group, Inc. 
NA VFAC PACIFIC Red Hill 1 Q05 G W 

Contraet No.: N62742-01-D-1806, CTO 0013 Page ix 

LIST OF FIGURES 

FIGURES 

1 Site Vicinity Map 

2 Site Plan 

LIST OF TABLES 

TABLES 

1 Summary of Groundwater Sample Results for Stilling Basin 

2 Summary of Groundwater Sample Results for M W-V I D 

3 Summary of Trip Blank Results 

LIST OF APPENDICES 

APPENDICES 

A Laboratory Reports and Chain-of-Custody Records for Primary and QC 

Groundwater and Stilling Basin Samples 

B Monitoring Well Sampling Logs 

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NAVFAC PACIFIC Red Hill IQ05 GW 

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ACRONYMS AND ABBREVIATIONS 

ACRONYM/ 

ABBREVIATION DEFINITION/MEANING 

1,2 DCA 1,2 dichloroethane 

AMEC AMEC Earth and Environmental, Inc. 

BTEX benzene, toluene, ethylbenzene, and total xylene 

CAS Columbia Analytical Services 

CFR Code of Federal Regulations 

COPC contaminants of potential concern 

COTR Contracting Officer's Technical Representative 

CTO contract task order 

DAWSON Dawson Group, lnc. 

DOT Department of Transportation 

DQO Data Quality Objectives 

DW drinking water 

EDB 1,2-dibromoethane 

EM Engineering Manual 

EPA United States Environmental Protection Agency 

fbg feet below grade 

FISC Fleet Industrial Supply Center 

FSF fue[ storage facility 

FSP Field Sampling Plan 

GWAL groundwater action level 

HASP Health and Safety Plan 

HAZWOPER Hazardous Waste Emergency Operations 

HDOH State of Hawaii Department of Health 

IDW investigation derived waste 

IP interface probe 

IRP Installation Restoration Program 

mg/L milligrams per liter 

MRL method reporting limit 

MtBE methyl tert-butyl ether 

NAVFAC PACIFIC Nava[ Facilities Engineering Command, Pacific 

OSHA Occupational Safety and Health Administration 

PAH polynuclear aromatic hydrocarbon 

PVC polyvinyl chloride 

PWC Public Works Center 

QA quality assurance 

QC quality control 

RPM/NTR Remedial Project Manager / Navy Technical Representative 

SSHO Site Safety and Health Officer 

TPH total petroleum hydrocarbons 

U.S. Army United States Department of the Army 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc 
NAVFAC PACIFIC Red Hdl 1Q05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Page xii 

ACRONYMS AND ABBREVIATIONS 

ACRONYM/ 

ABBREVIATION DEFINITION/MEANING 

UST underground storagetank 

VOC volatile organic compound 

WP Work Plan 

[2001 022.013 Red Hill IQ05 GWI Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill 1Q05 GW 

Contraot No.: N62742-01-D-1806, CTO 0013 Page 1-1 

1. INTRODUCTION 

The Department of the Navy, Naval Facilities Engineering Command, Pacific (NAVFAC PACIFIC) has 

retained Dawson Group, Inc. (DAWSON) to perform groundwater monitoring activities at the Red Hill 

Fuel Storage Facility (FSF), Hawaii. The Red Hill FSF consists of 20 active underground storage tanks 

(USTs) operated by the Fleet Industrial Supply Center (FISC) Pearl Harbor. Figure l, Site Viciniry Map, 

illustrates the location of the project site. 

This work was performed under NAVFAC PACIFIC Contract Number N62742-01-D-1806, Contract 

Task Order (CTO) 0013. This document is the first quarterly report and summarizes the following: field 

investigation, IDW disposal, sample results, and conclusions and recommendations for the next sampling 

event. 

1.1 Project Objectives 

The project objective is to detennine if petroleum-related groundwater contamination is present 

downgradient of the 20 active USTs. In order to achieve this objective, the following tasks will be 

conducted: 

Conduct quarterly sampling of surface water located in the stilling basin located at the. 

potable water infiltration tunnel operated by the Navy Public Works Center (PWC). 

Conduct quarterly sampling of groundwater from the sentinel monitoring well (MW-V 1 D) 

located downgradient of the 20 USTs. 

Present data in a quarterly report, which will include a description of the nature and extent 

of contamination, if any. 

1.2 Scope of Work 

The scope of work for this project consists of the following: 

Planning. A Work Plan/Field Sampling Plan (WP/FSP) and Site Health and Safety Plan 

(HASP) were prepared (DAWSON, 2005a and 2005b). 

Site Preparation. The project site was prepared for fieldwork by obtaining site access, 

right-of-entry clearances, necessary permits and any approvals for work. 

Quarterly Groundwater Sampling. Primary samples and quality control (QC) samples 

(i.e., field duplicates) are collected at two locations (stilling basin and sentinel well). 

The Scope of Work, specific to the Stilling Basin, consists of the following: 

• Notify Navy PWC personnel at the potable water infiltration tunnel to shut-off pumps 

for 24 hours prior to sampling activities. 

• Collect one primary surface water sample in the stilling basin. 

• Collect one field duplicate (QC) surface water sample in the stilling basin. 

• After the pumps have been tumed on and run for at least 20 to 25 minutes, collect one 

primary surface water sample in the stilling basin. 

[2001 022. 013 Red Hill IQ05 G W] Dawson Group, Inc. 
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ContractNo. N62742-01-D-1806,CT00013 Pagel-2 

The Scope of Work, specific to the Sentinel Well (MW-V1D), consists of the following: 

Collect one primary groundwater sample from sentinel well MW-1 VD. 

• Collect one field duplicate (QC) groundwater sample from sentinel well MW-1 VD. 

Laboratory Analysis. Submit all samples to Columbia Analytical Services (CAS) for the 

following analyses: 

— Benzene, toluene, ethylbenzene, and total xylenes (BTEX); methyl tert-butyl 

ether (MtBE); and 1,2 dichloroethane (1,2 DCA) by United States Environmental 

Protection Agency (EPA) Method 8260B, 

— Total petroleum hydrocarbons (TPH) as gasoline by EPA Method 8015M, 

— Ethylene dibromide (EDB) by EPA Drinking Water (DW) Method 504.1, 

— TPH as diesel by EPA Method 8015M, 

— Polynuclear aromatic hydrocarbons (PAHs) by EPA Method 8270C/SIM-PAHs, 

and 

— Total lead by EPA Method 6020. 

Place a laboratory-supplied trip blank and temperature blank in every cooler. 

IDW Disposal. Dispose of all investigation-derived waste (IDW) by a certified disposal 

contractor, immediately following receipt of sample results. 

Reporting. The First Quarter 2005, Groundwater Samplfng Report documents the field 

investigation, IDW disposal, sample results, and conclusions and recommendations for the 

next sampling event. 

12001 022. 013 Red Hill 1Q05 GWI Dawson Group, Inc. 
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Contract No.: N62742-01 -D- 1806, CTO 0013 Page 2-1 

2. BACKGROUND 

2.1 Site Location 

The Red Hill FSF project site is located in Halawa Heights on Oahu, Hawaii. Access is via Halawa 

Valley Road, located north of the project site. Primary highways in the vicinity of the project site are 

Interstate Highways H-1 and H-3. 

Land adjacent to the north of the project site is occupied by Halawa High and Medium Security 

Facility and private businesses. Land to the south and west of the project site includes the Coast 

Guard Reservation. Moanalua Valley is located east of the facility (Figure l, Site Vfcinfty Map). 

2.2 Facility Description 

The Red Hill FSF consists of 20 active USTs operated by Navy FISC Pearl Harbor. Each UST has a 

capacity of 12.5 million gallons. The facility is located approximately 100 feet above the basal 

aquifer. Approximately 1,550 feet hydraulically downgradient from the tank farm, the Navy PWC 

opemtes a potable water infiltration tunnel (Figure 2, Sfte Plan). 

2.3 Previous Environmental Actions/Studies 

From 1998 to 2001, the Navy conducted an investigation at the facility to assess potential releases 

from the fuel storage facility. In February 2001, the Navy installed a one-inch diameter sentinel well 

(MW-V 1 D) to monitor for contamination of the basal aquifer underlying the storage facility (AMEC 

Earth and Environmental, Inc. [AMEC], 2002). Sentinel well MW-V1D was installed and 

completed at approximately 100 feet below grade (tbg). At the time of we[I completion, depth to 

water in MW-VID was measured at 86 fbg. The groundwater at the project site fluctuates from dry 

season to wet season (AMEC, 2002). 

A second monitoring well (MW-V2S) was installed and completed above the water-bearing zone at 

approximately 52 fbg. This monitoring well is located southwest of sentinel well MW-V1D and 

does not contain either groundwater or product. MW-V2S was intentionally completed above the 

water-bearing zone in order to avoid creation of a possible direct conduit to the basal aquifer 

(AMEC, 2002). 

In February 2001, groundwater samples collected from sentinel well MW-V 1D contained detectable 

amounts of TPH ranging from 0.883 milligrams per liter (mg/L) to 1.05 mg/L and total lead ranging 

from 0.0104 mg/L to 0.015 mg/L. The maximum total lead concentrations in the samples was equal 

to the primary drinking water standard of 0.015 mg/L for lead and exceeded the State of Hawaii 

Department of Health (HDOH) Tier I groundwater action level (GWAL) of 0.0056 mg/L (US Navy, 

2004). 

Following discussions with HDOH, a program was initiated to monitor the sentinel well MW-V1D 

and the PWC potable water stilling basin for indications of contamination from the upgradient tank 

farm. The recommended parameters for analyses were TPH; BTEX; 1,2 DCA; PAHs; total lead; and 

EDB (US Navy, 2004). 

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' Contract No.: N62742-01 -D- 1806, CTO 0013 Page 3-1 

3. PROJECT ORGANIZATION 

The following individuals are identified as the key personnel for this project: 

NAVFAC PACIFIC 

Contracting Officer's Technical Ms Debbie Loo 1 (808) 472-1234 

Re resentative COTR) _ 

Altemative COTR Ms. K_ay O'Keefe ' 80~ 472-1435 _ 

Remedial Project Manager/Nary 

Technical Re resentative RPM/NTR I Mr. Glenn Yoshina a ~08 472-1416 

DAWSON 

Project Manager / I Ms. Heather Kea (808) 536-5500 ext. 341 

En_vironmental Scientist _ ' _ __ 

ns 

_ 

O eratio_Manager / QC Mana eg r_ Mr. James Frifeldt r 808 536-5500 ext. 305 

Project Superintendent / Site Safety 

and Health Officer (SSHO) I Mr. Ro ce Yni ues 808 536-5500 ext. 331 

SUBCONTRACTORS 

lolumbia Analytical 

ie_rvices _ Laboratory Services Ms. Tracie Sober i(808) 682-1767 

'acific Commercial Soil/Water 

iervices Disposal Services ! I Mr. Jingbo Chang j(808) 545-4599 

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[2001 022. 013 Red Hill IQ05 G W] Dawson Group, Inc. 
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Contract No.: N62742-01-D-1806. CTO 0013 Paae 4-1 

4. DATA QUALITY OBJECTIVES 

Environmental data are needed to: 1) determine if groundwater contamination is present at the project 

site; 2) determine the best course of action; and 3) characterize IDW wastewater for disposal. 

Chemical data must be of sufficient quality and quantity to confirm the presence or absence of 

contaminants of potential concem (COPC) in the groundwater beneath the Red Hill FSF. The COPCs for 

this investigation include TPH as diesel and as gasoline; BTEX; MtBE; 1,2 DCA; total lead; and EDB. 

The data quality objectives were designed to comply with the HDOH's Technfcal Guidance Manual for 

Underground Storage Tank Closure and Release Response, Second Edition (HDOH, 2000) and RtskBased Corrective Actton and Decision Making at Sftes With Contaminated Sofl and Groundwater, 

['olume I and 1I (HDOH, 1996). 

The screening levels for this investigation will draw on the HDOH Tier I GWALs for sites receiving less 

than 200 centimeters of rainfall per year and threatening a drinking water source (HDOH, 2000). 

To evaluate the absence or presence of contaminants, the following quality criteria will be followed: 1) 

laboratory analytical methods will provide reporting limits that are lower than regulatory action levels, 2) 

chemical analyses of COPC will be performed using EPA publication SW-846, Test Methoda for 

Evaluating Solfd Waste, Physical/Chemical Methods, Third Edition methodology (EPA, 1998), and 3) 

laboratory chemical data will be used to assess each analyte's concentration exceeding HDOH Tier 1 

GWALs. 

[2001 022.013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

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Contract No.: N62742-01-D-1806, CTO 0013 Page 5-1 

5. GENERAL WORK PROCEDURES 

This section, along with Section 6, Sampling Methodologtes and Procedures, describes the methods used 

to conduct the work at the site in February 2005. The stilling basin and the sentinel well, M W-V 1 D, were 

sampled. The general locations of the samples are illustrated on Figure 2, Site Plan. 

5.1 Health and Safety Procedures 

The HASP (DAWSON, 2005a) was prepared and completed in general conformance with 

appropriate guidelines from the Occupational Safety and Health Administration (OSHA) and the 

United States Department of the Army (U.S. Army) Engineering Manual (EM) 385-1-1, Safety and 

Health Requfrements Manual (U.S. Army, 1996). The HASP identifies hazards associated with the 

tasks performed on this project, and addresses the appropriate management techniques required to 

reduce related risks. The HASP was kept at a known and easily accessible place during project field 

activities. 

Prior to commencing work at the project site, the 1IASP was reviewed by Contractor personnel and 

their subcontractors. In addition, the I-IASP was presented to approved visitors to provide them with 

an awareness to avoid hazards associated with this project. 

Daily health and safety tailgate meetings were held on site at the beginning of each workday to 

discuss the HASP and the activities to be conducted that day. These meetings summarize sitespecific hazards, safety equipment, and emergency procedures. AII on-site personnel attended and 

signed the daily tailgate safety meeting log. Before starting activities, the site safety and health 

officer (SSHO) established site access control and work zones, and set up emergency equipment. 

All Contractor and subcontractor personnel present onsite had completed the 40-hour Hazardous 

Waste Operations and Emergency Response (HAZWOPER) training, Title 29 Code of Federal 

Regulations (CFR) Part 1910 Section 120 (CFR, 2005). A[l current training certificates for field 

personnel were presented in the HASP (DAWSON, 2005a). 

5.2 Equipment Decontamination 

AIl water-level measuring and water sampling equipment were decontaminated at the start and end 

of the project, as well as between locations, to reduce possibility of cross-contamination. The 

equipment was first washed in potable water and non-phosphate detergent. Then it was rinsed in 

potable water, rinsed in deionized/distilled water, sprayed with isopropyl alcohol, and rinsed with 

deionized/distilled water. Decontamination washwater was placed in a Department of 

Transportation (DOT)-approved, open-head, steel, 15-gallon drum and handled appropriately as 

described in detail in Section 5.3, Investigatfon Dertved Waste. 

5.3 Investigation Derived Waste 

5.3.1 Storage and Sampling 

IDW generated during this investigation included monitoring well purge water and 

decontamination wastewater. Wastewater was stored in a 5-gallon plastic bucket within a DOTapproved, open-head, steel, 15-gallon drum (secondary containment). The drum was labeled 

[2001 022. 013 Red Hill 1Q05 GWI Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Page 5-2 

and marked and stored within the Red Hill Fuel Storage Facility near MW-VID until disposal. 

IDW management practices are described in detail in the WP/FSP (DAWSON, 2005b). 

5.3.2 IDW Disposal 

AIl IDW generated during the sampling period (February 2005) were detennined to be nonhazardous wastes and are currently awaiting disposal. 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
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Contract No.: N62742-01-D-1806, CTO 0013 Page 6-1 

6. SAMPLING METHODOLOGIES AND PROCEDURES 

6.1 Laboratory Analysis 

The laboratory used standard analytical methods as outlined in the EPA's publication SW846 — Test 

Methods for Evaluating Solfd Waste, Thfrd Editton (EPA, 1998). The Iaboratory followed the EPA's 

method-specific quality control procedures as outline in SW846. 

The groundwater samples collected from the stilling basin and the sentinel well were analyzed by 

Columbia Analytical Services for the following analyses: 

• TPH as Diesel and TPH as Gasoline using EPA Method 8015M; 

• BTEX, 1,2-DCA, and MtBE using EPA Method 8260B; 

• EDB using EPA Method 504.1; 

• PAHs using EPA Method 8270C SIM/PAHs; and 

• Total Lead by EPA Method 6020. 

The analytical methods were requested by the NAVFAC PACIFIC in the Statement of Work (SOW) 

(U.S. Navy, 2004) and are industry standards. Site investigation activities were conducted in 

accordance with the WP/FSP (DAWSON, 2005b) and the Project Procedures Manual, U.S. Navy 

PACDIV Installation Restoration Program (IRP) (PACDI V, 1998). Copies of laboratory reports and 

chain-of-custody records for groundwater samples are included in Appendix A, Laboratory Reports 

and Chain-of-Custody Records for Primary and QC Groundwater and Stilling Basin Samples. 

6.2 Stilling Basin Sampling Methodology 

This section describes the methodology for sampling the stilling basin. The cheracteristics of the 

stilling basin identify it as a permit-required confrned space. Thus, entry into the stilling basin was 

not permitted during sampling activities. 

6.2.1 Non-Entry Sampling in the Stilling Basin 

Non-entry access to the stilling basin requires opening an entrance hatch (approximately 24 

inches in diameter). A lockout/tagout procedure was used to prevent accidental closure. From 

the open entrance hatch, the depth to water to the nearest 0.01 foot was measured using an 

interface probe (IP). The measurement and time was recorded on the Surface Water Field 

Sampling Log (Appendix B, Monitoring Well Samplfng Forms). 

6.2.2 Surface Water Sampling Methodology 

The samples were collected using a new weighted, disposable, single-check valve bailer that 

remained sealed in plastic (by the manufacturer) until use. These bailers are equipped with 

bottom-discharging devices. The sampling system was a combination of a polyvinyl chloride 

(PVC) casing and a disposable bailer, where the bailer was inserted inside the PVC casing, and 

an IP probe was attached to the outside of the PVC casing. Together, the assembly was lowered 

to approximately six inches above the water surface, and then the bailer was lowered into the 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, lnc 
NAVFAC PACfFIC Red Hill IQ05 GW 

Contract No - N62742-01-D-1806, CTO 0013 Page 6-2 

water to collect a sample. Once full, the bailer was raised into the PVC casing and the assembly 

was raised up through the entrance hatch, where the sample bottles were filled. 

This procedure was repeated until all required primary and field duplicate (QC) samples were 

collected. 

6.2.3 Field Quality Contro/ Sampling 

Surface water field duplicate (QC) samples were collected once per sampling event, following 

the sample collection procedures listed in Section 6.2.2, Surface Water Sampling Methodology. 

A laboratory-supplied trip blank was placed in the sample cooler containing the VOC samples 

to be shipped to the laboratory. 

A temperature blank was placed in one sample cooler per shipment to be shipped to the 

laboratory. 

6.3 Sentinel Well Sampling Methodology 

This section describes the sampling methodology employed to collect groundwater samples. 

6.3.1 Measurement of Static Water Level and Detection of an Immfscible Phase 

Before sampling, the depth to standing water, depth to an immiscible layer (if any), and the total 

depth of the well was measured to the nearest 0.01 foot using an IP to provide baseline data. 

This data was recorded on the Monitoring Well Field Sampling Log (Appendix B). 

In accordance with the SOW, if an immiscible phase is detected with the IP, the Project 

Manager and the Navy RPM/NTR are to be notified immediately. No groundwater sample is 

collected unless otherwise directed by the Project Manager and/or Navy RPM/NTR. 

lf no immiscible phase is detected with the IP, the measurements of depth to water and total 

depth of the well are used to calculate the volume of water in the well and the amount of water 

to be purged, as well as provide information on the integrity of the wel[ (e.g., identification of 

siltation problems). 

6.3.2 Well Purging Methodo/ogy 

Purging was accomplished by removing groundwater from the well using a dedicated bailer 

approximately 12 feet in length and 0.5 inch in diameter attached to a new, dedicated rope. The 

bailer was lowered into the well with as little disturbance of the water as possible to minimize 

aeration of the water in the well. Once the bailer was full, it was slowly brought out of the 

water and the water was transferred to a clean container for evaluation of field parameters. The 

purge water was evaluated on a regular basis during purging and analyzed in the field for 

temperature, pH, specific conductivity, salinity, dissolved oxygen, redox potential, and turbidity 

using a YSl® water quality meter. At least four readings were taken during the purging 

process. The purging procedure was repeated until the calculated purge volume was removed 

or when three consecutive field parameter measurements had stabilized to within approximately 

10 percent. AII information was recorded on the Monitoring Well Field Sampling Log 

(Appendix B). The purge water was placed in a 5-gallon plastic bucket with lid and stored 

onsite inside a 15-gallon, open-head, steel drum (i.e., secondary containment). 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQOS GW 

Contract No.: N62742-01-D-1806, CTO 0013 Paae 6-3 

6.3.3 Sample Colfection Procedures 

The sentinel well was sampled when groundwater within it was representative of aquifer 

conditions and after it had recovered sufficiently to provide enough volume for the groundwater 

sample. A period of no more than two hours elapsed between purging and sampling to prevent 

groundwater interaction with the casing and atmosphere. Depth to water was measured and 

recorded prior to sampling to demonstrate the degree of recovery of the well. 

A new length of polyethylene rope was tied securely to the top end of the dedicated bailer. 

Once the bailer was full, it was brought out of the water and the sample transferred directly into 

the laboratory-supplied containers. This procedure was repeated until all required primary and 

field duplicate (QC) samples were collected. 

6.3.4 Fleld Quality Control Sampling 

Groundwater field duplicate (QC) samples were collected once per sampling event, following 

the sample collection procedures listed in Section 6.3.3, Sample Collection Procedures. 

A laboratory supplied trip blank was placed in the sample cooler containing the VOC samples 

to be shipped to the laboratory. 

A temperature blank was placed in one sample cooler per shipment to be shipped to the 

laboratory. 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contraet No.: N62742-01-D-1806, CTO 0013 Page 6-4 

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[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
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Contract No.: N62742-01 -D- 1806, CTO 0013 Page 7-5 

7. INVESTIGATION RESULTS 

7.1 Stilling Basin Water Sample Results 

Three surface water samples (two primary and one duplicate) were collected from the PWC potable 

water stilling basin and analyzed for TPH-D, TPH-G, 1,2-DCA, BTEX, MtBE, Total Lead, and EDB 

on 16 February 2005. The results are presented in Table 1, Summary of Groundwater Sample 

Results of this report. The laboratory analytical reports are presented in Appendix A, Laboratory 

Reports and Chafn-of-Custody Records for Primary and QC Groundwater and Stillfng Basfn 

Samples. 

7.1.1 Total Lead 

Tota[ lead was detected above the laboratory method reporting limits (MRLs) at concentrations 

ranging from 0.00005 mg/L to 0.00033 mgJL (Table 1). These concentrations were below the 

HDOH Tier 1 GWAL of 0.0056 mg/L. 

7.1.2 Tota/ Petroleum Hydrocarbons (TPH) 

TPH was not detected above the laboratory MRLs in any stilling basin samples (Table 1). 

7.1.3 1,2-Dibromoethane (ED8) 

EDB was not detected above the [aboratory MRLs in any stilling basin samples (Table 1). 

7.1.4 Volatile Organic Compounds (VOCs) 

Toluene was detected above the laboratory MRL at concentrations ranging from 0.00081 mg/L 

to 0.0012 mgfL (Table 1). These concentrations were below the HDOH Tier 1 GWAL of 2.1 

mg/L. 

No other VOCs were detected above the laboratory MRLs in any stilling basin samples (Table 

1). 

7.1.5 Polynuclear Aromatic Hydrocarbons (PAHs) 

No PAHs were detected above the laboratory MRL in any stilling basin samples (Table 1). 

[2001 022.013 Red Hiil 1Q05 GWl Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill 1Q05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Page 7-6 

7.2 Sentinel Well Groundwater Sample Results 

Two groundwater samples (one primary and one duplicate) were collected from the sentinel well, 

MW-VID and analyzed for TPH-D, TPH-G, 1,2-DCA, BTEX, MtBE, Total Lead, and EDB on 17 

February 2005. The results are presented in Table 2 of this report. The laboratory analytical reports 

are presented in Appendix A. 

7.2.1 Total Lead 

Total lead was detected above the laboratory MRL at concentrations ranging from of 0.0102 

mg/L to 0.0119 mg/L (Table 2). Both of these results are above the HDOH Tier 1 GWAL of 

0.0056 mg/L; however, the results are below the HDOH DW standard of 0.015 mg/L (HDOH, 

2002). 

7.2.2 Total Petroleum Hydrocarbons (TPH) 

TPH as diesel was detected at concentrations ranging from 1.4 mg/L to 1.5 mg/L. (Table 2). 

7.2.3 1,2-Dibromoethane (EDB) 

No concentrations of EDB were detected above the laboratory MRLs in any sentinel well 

samples (Table 2). 

7.2.4 Voiatile Organic Compounds (VOCs) 

No concentrations of EDB were detected above the laboratory MRLs in any sentinel well 

samples (Table 2). 

7.2.5 Polynucfear Aromatic Hydrocarbons (PAHs) 

• Naphthalene was detected above the laborratory MRL at concentrations ranging from 

0.00021 mg/I, to 0.00025 mg/L. 

• 2-Methylnaphthalene was detected above the laboratory MRL at concentrations 

ranging from 0.000057 mg/L to 0.00014 mg/L. 

• Acenaphthene was detected above the laboratory MRL at concentrations ranging from 

0.000052 mg/l. to 0.000054 mg/L. 

• Dibenzofuran was detected above the laboratory MRL at concentration ranging from 

0.00011 mg/L to 0.00013 mg/L. 

• Fluorene was detected above the laboratory MRL at concentrations ranging from 

0.000043 mg/L to 0.000053 mg/L. 

• Phenanthrene was detected above the laboratory MRL at concentrations ranging from 

0.000082 mgfL to 0.00012 mglL. 

• Fluoranthene was detected above the laboratory MRL at concentrations ranging from 

0.000021 mg/I, to 0.000035 mg/L. 

• Pyrene was detected above the laboratory MRL at concentrations ranging from 

0.000029 mg/L to 0.000056 mg/L. 

• Chrysene was detected above the laboratory MRL at a concentration of 0.00002 mg/L. 

[2001 022. 013 Red Hill IQOS GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-e1-D-1806, CTO 0013 Page 7-7 

• Benzo(b)fluoranthene was detected above the laboratory MRL at a concentration of 

0.000025 mg/L. 

• Benzo(a)pyrene was detected above the laboratory MRL at a concentration of 0.00002 

mg/L (Table 2) 

None of the detected concentmtions exceeded the established HDOH Tier 1 GWALs. 

7.3 Trip Blank Analytical Results 

One trip blank sample was submitted and analyzed for VOCs by EPA Method 8260b. The results 

are presented in Table 3, Summary of Trip Blank Resulls. The laboratory analytical reports are 

presented in Appendix A. 

Toluene was detected in the trip blank above the laboratory MRL at 0.0014 mg/L. This 

concentration was below the HDOH Tier 1 GWAL of 2.1 mg/L. No other VOCs were detected 

above the laboratory MRLs. 

7.4 Data Quality Review 

7.4.1 Field Quality Assurance/Quality Control 

Quality Assurance/Quality Control (QA/QC) checks employed during the collection of field 

data and sampling activities included the following: 

• Collection of samples and field measurements by DAWSON. DAWSON personnel 

were familiar with EPA protocols concerning equipment decontamination, sample 

collection, sample and project documentation, and QA/QC procedures. 

• Use of certified clean laboratory sample containers. 

• Preservation of sample integrity by chilling samples in the field and maintaining 

proper temperature until receipt at the laboratory. 

7.4.2 Laboratory/Quality Control Data Assessment 

As part of the QC of this project, the DAWSON completed a desktop review of the data 

packages received from Columbia Analytical Services. The desktop review included a review 

of the hold times, reagent blanks, sun•ogate recoveries, sample duplicates, matrix spike/matrix 

spike duplicates recoveries, relative percent differences, blank spike recovery and reporting 

limits. DAWSON concluded that the laboratory analyses meet QC criteria and can be used for 

the intended purpose. The QC results were consistent with all primary sample results and thus 

valid and useable. 

Data Discrenancfes 

There were no significant data discrepancies between the two sets of primary/QC groundwater 

samples. Columbia Analytical Services performed analyses on the primary and QC samples. 

The results of the QC samples are included in Tables 1 and 2(listed as duplicate samples). 

[2001 022. 013 Red Hill 1Q05 GWI Dawson Group, )nc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Paae 7-8 

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[2001 022 013 Red Hill 1 Q05 GW] Dawson Group, lnc 
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Contract No.: N62742-01-D-1806, CTO 0013 PaRe 8-1 

8. CONCLUSIONS AND RECOMMENDATIONS 

The following conclusions are based on the findings of previous investigations and the data collected 

during this investigation. 

Stilling Basin 

• Total lead and toluene were the only constituents detected at concentrations above the 

laboratory MRLs in the stilling basin samples. AII detected concentrations were below 

HDOH Tier 1 GWALs. Toluene was present in the trip blank associated with these 

samples. 

Sentine/ Well 

• Total lead was detected at a concentration above the HDOH Tier 1 GWAL but below the 

HDOH drinking water standard in the sentinel well samples. The February 2005 results 

were below the 2002 investigation results (AMEC, 2002). 

• TPH as diesel was detected at a concentration above the laboratory MRL in both of the 

sentinel well samples. No action level has been established for this analyte. 

• Numerous PAHs (naphthalene, 2-methylnaphthalene, acenaphthene, dibenzofuran, 

fluorene, phenanthrene, fluoranthene, pyrene, chrysene, benzo(b)fluoranthene, and 

benzo(a)pyrene) were detected above the [aboratory MRLs in both of the sentinel well 

samples. None of the detected concentrations exceeded the established HDOH Tier 1 

GWALs. 

• The groundwater in the upgradient sentinel wel[ (MW-V1D) shows evidence of COPC 

contamination in the basal aquifer. 

Based on the findings duringthis investigation, DAWSON recommends the fol[owing actions: 

• Continue sampling at the sti[ling basin and the sentinel well during the next quatter (April 

through June 2005). 

[2001 022.013 Red HiI11Q05 GWl Dawson Group, Inc. 
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Contract No.: N62742-01 -D- 1806, CTO 0013 Page 8-2 

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Contract No.: N62742-01-D-1806, CTO 0013 Page 9-1 

9. REFERENCES 

AMEC Earth and Environmental, Inc., 2002. Red Hill Bulk Fuel Storage Facflity Investfgation Report, 

Yolume I oflll (Ftnal) for Fleet Industrial Supply Center (FISC), Oahu, Hawait. August 2002. 

Code of Federal Regulations, 2005. Hazardous Waste Operations and Emergency Response: Tftle 29, 

Part 1910, Sectton 120. Office of Federal Register, National Archives and Record 

Administration. United States Government Printing Office, Washington DC. 

Dawson Group, Inc., 2005a. Site Health and Safety Plan, Groundwater Sampling, Red Hill Fuel Storage 

Facility, Hawaii. February 2005. 

Dawson Group, Inc., 2005b. Work Plan/FEeld Sampling Plan, Groundwater Sampling, Red Hfll Fuel 

Storage Facflfty, Hawaii. February 2005. 

State of Hawaii Department of Health, 1996. Risk-based Correctfve Actfon and Decisfon Making at Sites 

wfth Contaminated Sotl and Groundwater, Yolume I and 1I. 

State of Hawaii Department of Health, 2000. Technfcal Guidance Manual for Underground Storage 

Tank Closure and Release Response, Second Edition. March 2000. 

State of Hawaii Department of Health, 2002. Hawafi Admfnistrative Rules, Title 11 Chapter 20, Rules 

Relating to Potable Water Systems. November 2002. 

United States Department of the Anny, 1996. Safery and Health Requfrements Manual. EM 385-1-1. 3 

September 1996 

United States Environmental Protection Agency, 1998. Test Methods for Evaluating Solid Waste, 

Physical/Chemtcal Methods, Third Editfon. 

United States Navy, 2004. Statement of Work —10 May 2004. May 2004. 

United States Navy, 1998. Project Procedures Manual, U.S. Navy PACDIV Installation Restoration 

Program (IRP). October 1998. 

[2001 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Figuree 

FIGURES 

Site Vicinity Map— Figure I 

Site Plan— Figure 2 

[2001 022.013 Red Hill 1Q05 GW] Dawson Group, lnc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Page 9-2 

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13 Red Hill IQ05 GW] Dawson Group, Inc. 
NAV FAC PACI F[C Red Hill 1 Q05 G W 

Contract No.: N62742-01-D-1806. CTO 0013 Fie.ures 

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[2001 022. 013 Red Hill IQ05 GW] Dawson Group, lnc. 
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Contract No.. N62742-01-D-1806, CTO 0013 Tables 

This page fntentiona!!y lejt blank. 

[2001 022.013 Red Hill 1Q05 GW] Dawson Group, lnc. 
IIlfi1-34=111i1 

Summary of Groundwater Sample Results 

Stilling Basin 

Red Hill Fuel Storage Facility 

Red Hill, Oahu, Hawaii 

PumpeOMline PampsOnllne 

SAMPLEIDENTIFICATION NN-S-0a1 RN-B-002 RH-B-Dal 

SAMPLETYPE Pnmary Pnmary DurArate 

DATECOLLECTED 021161]005 p2/1fl2005 o]/182o05 REOULATORY 

ACTON 

ANIILYSIS LEVELS UNITS EPA METNOD MRL ' F T ~! ~J"~ 

~r,~S.;μg ~~ 

25:sY4+Ar~ 

Metals ToMlLeed 6020 0.00002 0.00033 Q00006 0.00005 00056 mg/L 

Hydrocarbons TPHasDiesel 8015M 005 ND ND I00~1 ND NE mg/L 

TPH as Resldual Range 8015M 0l ND ND I 011 I ND NE mg2 

TPHasGasollne 8015M 005 ND ND ND NE mBnEDB 1,2-Dlbromcethane(EDB) 5041 00000083 I.rD ND l0000aosll ND lu000uaexl NE mg/L 

VGCs Benzene 8260B 00005 ND ND ND 170 ® mg/L 

Methyl tert-Butyl Ether 8260B 00005 ND ND ND 002 O mP/L 

Toluene 8260B 0.0005 0.001 0.0012 0.00081 21 (D mP/L 

Ethylben2ene 8260B 00005 ND ND ND 014 O mg/Lm,p-Xylenes 8260B 0.0005 ND ND ND 10 o O mg/l. 

o-Xylene 8260B 00005 ND ND ND loo (D mg/1- 

1,2-Dlchloroethane(DCA) 8260B 00005 ND ND ND 0005 ® mg/L 

PAHs Naphthalene 8270CSIM 000002 ND ND ND 024 mg/L 

2-Methylnaphthalene 8270CSIM 000002 ND ND ND NE mg/L 

Acenaphthylene 8270C SIM 000002 ND ND ND NE mF/L 

Acenaphthene 8270CSIM 000002 ND ND ND 032 mg/L 

Dlbenzofuren 8270CSIM 000002 ND ND ND NE mgnFluorene 8270CSIM 000002 ND ND ND NE mg(L 

Phenanthrene 8270CSIM 000001 ND ND ND NE mp/L 

Anthracene 8270CSIM 000001 ND ND ND NE mg/L 

Fluomnthene 8270CSIM 000002 ND ND ND 001 mg/L 

Pyrene 8270CSIM 000002 ND ND ND NE mg/<- 

Benz(a)anthracene 8270CSIM 000002 ND ND ND NE mg/L 

Chrysene 8270CSIM 000001 ND ND ND NE mP/L 

12001022.013 Red Hill] Page 1 of 2 Dawson Group, Inc. 
TABLE 1 

Summary of Groundwater Sample Results 

Stilling Basin 

Red Hill Fuel Storage Facility 

Red Hill, Oahu, Hawaii 

Pumpe ORllne Pumps Online 

SAMPLEIUENTIFN:ATON RN-S-0O1 RN-B-002 RN-B007 

SAMPLETYPE Pnmary Pnmary Duplirete 

DAIECOLLECTED 02/1e12005 02/164005 071162005 REGULATORY 

ACTION 

ANALYSIS EPAMETNOD MRL LEVELS UNITS '.Y."„ •d#'%Tk$' - 

~~ 3+ .a .. 

~ ~ YS,.?^y. 

~ . i ' . ~ F' L ~ . 

-~ ~ k w.r.-+es• 

e., 3 " ~~:s 

Benm(b)Ouorunlhcnc 8270CSIM 000002 ND ND ND NE m8/tBenzo(k)Fluoran0lene 8270C SIM 0.00002 ND ND ND NE mg/L 

Benm(a)pyrene 8270CSIM 000002 ND ND ND 00002 mg/L 

Indeno(1,2,3-cd)pyrene 8270CSIM 000002 ND ND ND NE mg/L 

Dlbenz(a,h)arlthrscene 8270CSIM 000002 ND ND ND NE mgnBenzo(g,h,l)perylene 8270CSIM 000002 ND ND ND NE mgnNotes EPA Unned Srotes Environmental Protecuon Agency 

I^°s°'I method reporbng hmd s: otherthan stated 

PAHs polyerometro hyrdocerbone 

mg/L milhgramsperhter 

MRL methad raporang hmd 

ND Not deteded at or above the MRL 

B SLlling Basln 

RH Red HIII Fuel Staaon Facillty 

Bold, Nallo value Is greater than labomtory MRL 

Bold value ut greater then regulatory actlon level 

NE noneestabllshed 

vOCs volatAeorganxwrbons 

® State oF Hawau Deperbnem of HeaNh, 2000 Hawen Untlergmund Storege Tank (UST) Technlaal Guldance Manuel March 2000 

® State oF Hawan, DepelMent o( Health, 2002 Hawan Adminlstratwe Rules Chapter 11, Title 20 Poteble Water Dnnking Water Standards 

12001022.013 Red Hill] Page 2 of 2 Dawson Group, lnc. 
TABLE 2 

Summary of Groundwater Sample Results 

MW-V1 D 

Red Hill Fuel Storage Facility 

Red Hill, Oahu, Hawaii 

MW.,VD 

REGULATORY 

AC➢ON 

LE9EL5 UNITS 

SAMPLE IDENTIFICATION RN-WJfO, ® RILW-003 

$AMPLETYPE Pnrtuvy Dup4rete 

DATECOLLECTED 07/172005 02J1712D05 

A NALY&a EPA METNOD MRL ~' F" ' ' ~~-N.q?'n~ 0..ta~o-ti~_ 

` 

'. ~ tR- , 

Metals Tota1 Lead 6020 000002 0.0102 0.0119 00056 mg/L 

Hydrocarbons TPH as Diesel 8015M 005 1,4 V 1.S NE mP/L 

TPH ac Residual Range 8015M 0! 0.77 0 0.89 NE mP/L 

TPH as Gasoline 8015M 0.05 ND ND NE mg/L 

EDB I,2-Dthromoethane(EDB) 5041 00000083 ND ND I0°°°°°MI NE mg/L 

BTEX Benzene 8260B 00005 ND ND 170 Or mgnMethyl tert-Butyl Ether 8260B 00005 ND ND 002 O mg/L 

Toluene 8260B 00005 ND ND 21 O mg1L 

Ethylbenune 8260B 00005 ND ND 014 O mg/L 

m,p-Xylenes 8260B 00005 ND ND 100 O mg1L 

o-Xylene 8260B 00005 ND ND 100 T mg1L 

1,2-Dtchloroethane(DCA) 8260B 00005 ND ND 0005 ® mg/L 

PAHs Naphthalene 8270CSIM 000002 0.00025 0.00011 024 mg/L 

2-Methylnaphthalene 8270CSIM 000002 0.00014 0.000057 NE m2/L 

Acenaphthylene 8270CSIM 000002 ND ND NE mg/L 

Acenaphthene 8270CSIM 000002 0.000052 0.000054 032 mg/L 

DtbenzoFuran 8270CSIM 000002 000013 QOOO)I NE mg/l. 

Fluorene 8270CSIM 000001 0.000053 0.000043 NE mg1L 

PhenantFuene 8270C SIM 000001 0.00012 0.000082 NE mg/L 

Anthrecene 8270C SIM 000001 ND ND NE mp/L 

Fluoranthene 8270CSIM 000002 0.000035 0.000011 001 mF/L 

Pyrene 8270C SIM 000002 0.000056 0.000029 NE mg/L 

Benz(a)anthtacene 8270CSIM 000002 ND ND NE mg/L 

Chrysene 8270CSIM 000002 0.00002 ND NE mg/L 

12001022.013 Red Hill] Page 1 of2 Dawson Group, Inc. 
TABLE 2 

Summary of Groundwater Sample Results 

MW-V1 D 

Red Hill Fuel Storage Facility 

Red Hill, Oahu, Hawaii 

MW1VD 

REGULATORY 

ACTn)N 

LEVELB UNITS 

SAMPLEIDENnFICATION RH-W-0bt ® RII-1111402 

6AMPLETYPE Pnrtwry Dupbcate 

DATECOLLECTED 02/172005 n2/1711005 

ANALYSI6 EPA METNOD MRL ~'" i k;.~~ ~~ e._ .v..'` : 0. 

Benzo(b)Ouoranthene 8270CSIM 000002 0.000015 ND NE m2nBenzo(k)Fluaranthene 8270C SIM 0.00002 ND ND NE mB/LBenzo(a)pyrene 8270CSIM 0.00002 0.000012 ND 00002 mpJtIndeno(1,2,3-cd)pyrene 8270CSIM 000002 ND ND NE mg/tDlbenz(a,hkmhracene 8270CSIM 000002 ND ND NE mlr/tBenza(g,h,l)perylene 8270CSIM 000002 1 ND I ND NE I m8/1- 

Notes EPA Unded States Envlmnmental Protacbon Agency B Bblhng Basin at PVJC Potable Water Facihty 

t° 0°°'I meUod repnrbng limit is otherthan stated RH Red HIII Fuel Stabon Faaldy 

PAHs pdyammabo hyrdocarbons BolQ ItaOe value is greater than laboratory MRL 

mglL milligrams per lder Bold value Is greater than regulalory aclwn level 

MRL metltod reporbng bmit NE none established 

ND NonedetectedatnrabovetheMRL VOCe volableorganrocarbons 

Y The chromatographic fingerpnnt oF the semple rasembles a petroleum protluct elubng in appronmately the cortec 

cerbon renge, but the elubon pattem does not match the callbreton standard 

o The chromatcgrephlc fingerpnnt of the sample resembles an oil, but does not match the calibrabon standartl 

~ State of Hawan Deparbnent of Health, 2000 Hawan Undergrountl Sturege Tank (UST) Tachnlcal Guldance Manual Mamh 2000 

® State of Hawan, Deparenent of Heanh, 2002 Hawan Atlminlstrabve Rulea Chapter 11, Ttlle 20 Potable Water Dnnking Water Standards 

® Sample RH-B-007 was recelved wnh a pH abuve the methotl preservabon crdere ol pH Q 

[2001022.013 Red Hill] Page 2 of 2 Dawson Group, Inc. 
TABLE 3 

Summary of Trip Blank Results 

Stilling Basin 

Red H[II Fuel Storage Facility 

Red H[il, Oahu, Hawaii 

REOUTATORY 

ACTION 

LEVELS UNITS 

SAMPLEIDENTIFICATION Trlp&ank' 

SAMPLE TYPE Tnp Blenk 

DATECOLLECTED 02117/2005 

ANALYSIS EPAMETNOD MRL ~'..~~.~,~~~,~"r`~~Zi;j 

BTEX Benzene 

Methylten-ButylEther 

Toluene 

8260B 

8260B 

8260B 

OOOOS 

OOOOS 

00005 

ND 

ND 

0.0014 

170 O 

002 O 

21 O 

m8(1- 

mB/lmB/lEthylbenzene 

m,p-Xylenes 

o-Xylene 

8260B 

8260B 

8260B 

00005 

0.0005 

0.0005 

ND 

ND 

ND 

014 O 

100 O 

100 (D 

m8/L 

m8/1. 

mg/L 

1,2-Dtchlomethane(DCA) I 8260B 0.0005 ND 1 0005 ® I mg/L 

Notes EPA Unded States Envlronmental Protschon Agency 

I0 °°01 I method reporbng Ilmrt Is other Ihan statetl 

PAHs polyaromatic hyrdocarbone Bold, Iralic value is greaterthan lahoratory MRL 

mgR mllhgrems per laer Bold value Is greater than regulatory aclon level 

MRL methotl reporhng limn NE none establishetl 

ND NunetletectedatorabovetheMRL VQCs volableorganlcrarbons 

' The semple'rnp Blank" analyzed wM thls sample contalned low levels of target Toluene above the MRL Thr 

assoGatetl Storage Blank. which was preparad and stored at the laboretory the same hme the Tnp Blank war 

prepared, was analyzed as a Qualny,Assurance (QA) check The Storege Blank did not contain tl1e analyle in quesbon 

~ State of Hawan Deperbnem cf Health, 2000 Hewan Undelground Storage Tank (UST) 

Technlcal Guulance Manuel Mach 2000 

® State of Hewan, DepaNnent of Health, 2002 Hawan Adminis6aOve Rules Chapter 11, 

Title 20 Potable Water Dnnking Water Standams 

[2001022.013 Red Hill] Page 1 of 1 Dawson Group, Inc. 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Appendix A 

APPENDtX A 

Laboratory Reports and Chain-of-Custody Records for Primary and QC Groundwater and Stilling Basin 

Samples 

[2001 022. 013 Red Hdl IQ05 G W] Dawson Group, Inc. 
. - 

~ Auonyms 

~( ndumbre 

 AnWytlrnl ASTM Amertcan Sonery for Tesung and Mawrals 

nm m~n om ml ,,,lw rn nc. nm las,n, waa,naain gaeza ~ aam snaz?s M l9rm sae ora, r,,r 

SI~~Ila~~~ A2LA Amencan Assomauon for labomtory Accredttauon 

CARB Cahfonaa Atr Resources Bozrd 

CAS Number Chemlcal Abstmet 3ervtce regtstry Number 

CFC ChloroFluorocarbon 

CFU Colony-Fonnmg Unn 

DEC Depanment of Envtrunmemsl Conaervatton March 15, 2005 Service Request No K2501266 

DEQ Depanmem of Envuonmenul Quality 

DHS DepanmemofHwlfiServices 

HeuthcrKcrt 

DOE Depnrtmcnl of Ecology Dawson Group, lnc 

AtrponlndustrielPark DOH DepertmentofHealrh 

3375 Koupuku Slreel, E-200 EPA U. S. Envtronmemal Prutection Agency 

Honolulu, Hl 86819 

ELAP Enviromnenral Laboralory Aceredimtion Progmm 

RS: Red Hill GW Sampling / 2001022.013 GC Gas Chnxnatography 

GC/MS Gas Chromatogmphy/Mass Specvometry 

Dear Heathcr 

LUFP Leaking Underground Fuel Tank 

Enclosed are the results of the sample(s) submuted to our laboratory on Pebruary 19, 2005 fror M Modified 

yourmle®nce,theseanelyseshavebeenassignedourservicerequcstnumberK2501266. MCL Maximum Contamitum l.evtl is Ihe lughest pemussrble concemration of a 

AII anxlyses wem performcd accoNing to our Inboratory's quuluy assumnce program The test subsmnee allowed tn dnnktng water as esmbhshed by the USEPA. 

rcsults meet requtrcments of the NELAC slandards except as nuted tn lhc case nmrauve repnrt MDL Method Detectlon Lrmit 

All resulu arc rnlended to be constdercd m thetr entuery, and Columbta Analybcul Sernces, Inc 

MPN Most Probable Num6er (CAS) ts not responslble for use of less Ihan the complete ropon. Resufls npply unly lo the rtems 

submttted to lhe labomtury for enalysis and tndivtdual Itcros (samples) analyzed, ac heted in lhe MRL Medsod Reponing Limlt 

report. NA Not Applicable 

Plcasc call If you have any questions My exrension ie 3260 NC Nol Cakulaled 

NCASI National Courcd of the Peper Industry for Air and Stream Improvement 

Respectfully submttted. ND Not Delected 

Columb Analy{jcel Services, Inc. NIOSH Natiosul fnsumte lor Occupstiunzl Ssfery and Health 

PQL Practical Quanu®uon Ltmn 

H~ ey Joc ~ 

~ 

RCRA Rcsource Conservation and Recwvery Acl 

Projecl Chemlct SfM Selected lon Moniwring 

~ f TPH Total Petroleum Hydrocarbons 

NJ/Jeb Pxge I nf ' ~ 

tr Trace level is Ihc concennation of an analyte tlwt rs less llun Ne PQL bur grealer 

than or equal to Ne MDL 

ouu ,z 

NI rl ~ ,ir,IlLrl NII Y.rlr,rl ~ r.Il,ulieMwu,l 
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F F 

. : mw ~~ -x . m w gzmp 3 -x • + . . <mu p w-.z a. ,~ -x ° -+ ~ O > n 
COLUMBIA ANALYTICAL SERVICES, INC. 

CIRnt: Dawsun Gmup, lnc Servux Rrqunt No.: K7501266 

Profee4 RedHiOGWSamp4ng/20010]3013 DahRecelvN: ]/19105 

SempkMa[nx: Wmm 

CASENARRATIVfi 

Surrvgale Exeepbuns: 

Tle cronwl cnlem wert exaeded RsrtM Toluened8 smmgeh in LCS KWG03U55061 1Le msocuued masfu spike 

mcovenes oftargcs compuunds were in w000l, mdimbng Ne ana)yais wm m wnaol The aunoga[e outher is nagged 

acmrdingly Nofiusbttcantt[nea-tmnwasaPWOprmsc 

Sampk Nofes notl DaseuamA 

The Trip BIaNs amlyxed with Ihls sample mmamed bw levels of reign Toluene abuve the Mnhcd Repuning Umn 

(MRL) The msomnted Stmge Blenk, whsch wes prepeml md swrtd m the labornory the same ume the Trip Blank 

wm pmpaM, was mnlyzed as a Quah[y Assunnce (QA) check The 9rorege Blenk did nu[ conmm Ihe nndyle m 

qumtlon 

ue)eer Aromntk Hvdrourbcos br E 

AII analyses wsrt perfonned cons6tem wnh Ne quehsy assurmue progrmn of Columbm Analynml Servia; Inc 

(CAS). Thisrepnncon[amsanalyunlmvl[s(orsampbfdeflgnetMPorTSnlldmadeliverebkv Whenappmprwteto 

Ne mudnd, nelhod blank msulR have bmn reponed wM eech analyncal tesl Sunogale secovmes heve been mported 

far ail apphcable orgonrc emlyso AddsumW quelity connol anelyses reponM berem mclude lebnmlary Duphcme 

(DUP), Memx Spske (MS), MomrJDuplarem Matnx Spuke (MStUMS), end lAbormory Cpmcl Smnpk(LCS) 

Samnle Rerolnl 

Slx weler samples wert raeind for mulysis ef Columble Analyliul Smrem on L19A5 The samplet werc 

mcelved in good cnndmen and mnsisten[ wnh she awompanysng chun of oustody fmsn The mmples were s[arcd 

m e r<6igermor e[ 4°C upnn [eenpt n dm labnmmry 

Tnsal Me[eh 

No anomalles assoclawd wllh Ihe analysis ofshese semples werc nbservW 

Dleul Ranee Oreanlss bv EPA Mnbod BOISB 

No anomabee msoemmd wnh Ine analyso of [hese mmpks wem observed 

Gesohne Banee Orzema bv EPA Methad BOISB 

Sampk Nascs and Dlscussmn: 

Samples RH-B-001 and RH-B-0OIMS were recelved wnh a pH abnve the melhod prcservmmn cntena ufpH Q 

EDB bv EPA Mnhnd SOd 

Nn ermmalles assanatM wlth 1he amlysn oftheu semples were ubxrved 

Volaeile Onan c Comnoonds bv EPA MeWod 8260B 

Inlliel Cebbmlbn (ICAL) Exnpllom: 

The pnmery evaluatuon anenan was exoteded brc BtomomelNne nM Methylene Chlonde sn ICAL ID CAI4205 In 

eccmdance with CAS suMmd openung ptaoedmee. Ibe ahemmrve evebutmn specifed in the EPA metbud was 

performeE mmg dm mean Relauve Smndard Devimmn (RSD) uf all mmlyles in Ihe calibmtien The resul[ of rhe mean 

RSD cakuletion was 5 9% The wbLeauen mens Ihe allcmmwc evelunlon cmena Nae fnat CASIKeIso polrcy does 

rat allow tlsc use ofaverryyng dany mmly[e m she ICAL exceeds 30% RSD 

Notes nf Ducuulan 

Insulfmlms sempk mlunse wm rtxsved to peAbrsn a Mebix SpikeR.Aausx Splhe Duplluu: (MS/MSD) A Isbommry 

Conpvl Samplr/DUplsule Isbmebry Conbul Semple (LCS(DLCS) wes anelyeed and seponed in lieu ofthe MSIMSD 

for these smnpks 

Appmved by ~Dn4 Qf O 0 O( 5 APpmvetl by e Dah_~~ /c 

000(s 
CHAIN OF CUSTODY sr+> !(,2sr,i ~L.L Snah1N'al 

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Collambia Analytical5ervices laa PC~_ 

Coolerfie<eipt and Preservallon Form 

Cuolerreceivedoa atdopenedon --1/`/%/Z) by I LT—A—f~ 

1 Werecustodywlsonout4:deufceolen2 / / 

oo ' ~ ."`.-C/~6~ C','/.c n ~ ``— 

y~ N 

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4 la Ihe sWppei e a:Mll aw:lebk end filed+ lf no, m utd eubdl uumba ~ Y N 

5 COC® _ 

Temperamrc of eooleHr) upon ncefpt (T) ~ • ~ 

~ 

_ 

TempenlureHlenh: ('C) 

WetesmtplcehaMdeL•eiedondcnmedaYmeallecuoo? 

_ 

Y ~ N

6 WertcuuaadypaFrmproperlyfilletlompnk..ugn<d,em)7 L /—Y) N 

l. Typeofpxkmgmatmelprtrcm / ) S•IJ°.f.i.J {'u :~1~ i:H ~~ /// ~~, 

8 Dld YI bouln arrNe m good mndllfon (unbroken)? N 

9 Werc all bonle labels complete N. evslyns, pneavsvoq e¢ )+ ~y, -, I N 

10 D:dellboalelebelrandmgsagnemNcmuMYPapnx+ ~,~ N 

11. Werethemrreerrypesofbote®uredforNeteGaindkated? ;J 

12 WercallofWeprerervedboaleaacavedatWelabmthl6<appropnalepH? x ~,~ 

13 WertYO/.vmtacheckedlorebsmceufaububblee,anddpnsmt,ueudbeloW+ r~Y~ N 

14. DultheboNraortgmakfromCASOCorabmochlebumtoM YU N 

15. AreCWAh9crabiolagyawpinreceivedwith>IRtheT4hr.holdOVUremainiagfromeolleetloa7 N 

16 WeaCiNRerrcgenve" , Y J N 

Explma aoY diu'tapencus• . 

Metals 
Ware ICY Snlaralmnt eorraetion6 appinedi 

Naia lCP backgseund cosracLVOea appllaQ) 

II yea-vara z v da4a yenenatsd before 

applieatson oP backgsaunE eorreetu0ne5 

Yez/Ne YE9 

Yac/Ne Y8S 

Yea/tle NO 

Cofumbia Analylic•a( Services Columbia Aun(yrica[ Services 

METALS METALS 

- Cover Payt- -iRvOROANICANALF$IS DaTA PAC7(AGE INORGANIC ANALYSIS DATA SHEET 

Clzant. Dax000 0mnv, Inc. 9ervvm Fnqeeat. N2501266 

Pzo]eat No.: 2001022.013 

Prolact Naae: Bad Hill ON 9amgling 

Baapla No. Lab Bae,la ID 

AN-B-001 It2501266-001 

9tl-B-009 R2501266-002 

NH-B-003 II1501266-003 

NH-N-001 %2501266-006 

RH-N-002 H2501266-005 

Nethad Bslnk 52501266-NB 

Batch 4C H2501269-OO1D 

eatch OC H2501269-0015 

Claant: Deraen Grovp, Ine. 9ervloo Naqueat: %3S01266 

Pze]act N. . 2001022.013 Dete Collacled: 02/16/05 

Pzo]act Har: Md Hill aN 9ampli:g Date Neeeiwd: 02/19/05 

Nntrla. NATBR Unice p0/i 

Baavo Nw 

Basgple Nam: [W-B-COl Lab Ceda: R2501266-001 

AaalYte 

A:ulyaie 

Nathod HAL 

Dtlutraa 

yaoto: 

Data 

Hatrwted 

Data 

Analyzad I IbaOlt C D 

Leed 6020 0.02 1 3!3/05 3/9/OS 0 33 

9lgnatuza: Data: 3 A. 105' 

9 So11de: 0 0 

COVBR PAOS - ZN 

00011 Co®ente: 00012 

loim I - IN 
Columbia Analytical Servicev Columbia Analyltcod Servlces 

METALS METALS 

.1- .1. 

1:`10RCANIC ANALySIS DATA SHEF.T INOBCANIC ANALYSIS DATA SHEET 

Claant. Daweon Osou" Ino. 90zviee BeQuaet: N25U1266 c11.nt: Uawaan OreeG i Ino. 9etvsce Requeet: R2501266 

Pro3ect Na : 2001023.013 Deto calleeted: 02116/05 Pio]act N, 2001022.013 Data Cellected: 02/16/05 

Pxeleet Hame- 9ed N111 UB 6avililq Date 9eeeLwd: 02/19/05 Pee3aet tlama. Nd Bxll GB eaepli:y Data Rawaved• 02119/05 

Natriz NATElI Unitc yG/4 Natsax: NAPER UnitY PO/L 

Baele 10\ Baeae NA 

9aqsle Namo• PH-B-002 Lei Ccde: 82501366-003 9avple Name: BH-B-005 Lab Code R2501266-005 

Aanlyta 

Aoalyeve 

NetAod M11. 

D11ut1on 

lsnter 

Date 

Bxtraated 

Dete 

Melysed I Nasult C Q 

Lead 6020 1 0.02 1 1 1 3/3/05 3/9/05 0.06 

Analyta 

Analyeis 

HeMCd NRL 

DllOtlon 

laetoi 

Oata 

Extracted 

Cata 

Analyaed I Nemlt C Q 

Laad 6020 0.02 1 3/3/05 3/9/05 0.05 

8 seLds. 0.0 6 9olvde: 0 0 

Coomtents: 00013 a.teo001a 

!orn I - IN Peim I - IN 
Columbia Ana[yBcai Servicer 

METALS 

d. 

INORGANIC ANALYSIS DATA SHEET 

Claent. Devoon Ozovp, Inc 9ervica Faguast- N2501266 

Pzojee[ No.: 2001022 013 Date Colleeted. 02/17/05 

Pzolcet Neme: Pad Nall OM 8aoqling Date Aeaolved: 02/19/05 

lYtzax. NA1IIi Doats YO/L 

9esis NA 

semPle Nas:e: Nx-N-001 Leb Code: N2501266-009 

w..iyte NetAod 

Malysis 

NRL 

I DcluGOn 

Deeter 

Date 

Eetraetsd 

Dete 

Malysed Wault c Q 

LsW 6020 0 02 1 9/I/o5 9/9/OS 10 2 

Columbia Analyfical Servicer 

METALS 

.1. 

INORGANIC ANALYSIS DATA SHEET 

Claenb Davson Ozou" Ina. 9eavice Pnquest: N2501266 

FzDlee! No.: 3001022.013 Dete Colleeted: 03/11/05 

Fselsot Neee: Ped Hill DN 6aspling Dete Reeeived: 02/19/05 

Nstziz NATPA Dnike YO/L 

Basis NA 

eemple Nome: RN-N-002 Leb Code: N2501266-005 

Melyta 

Mslysa• 

NstDOd MRL 

Dllvtaon 

Peetez 

Dete 

2stcectetl 

Dste 

Melyred Mcult 1 C Q 

Led 6020 0.02 1 3/3/05 3/910S 11.9 

9 eolids: 0 0 9 9olids: 0.0 

Conventa• uoois Co:ooents 

00016 

POZm I - IN Pozm I - IN 
Co[umbia Ana(ytica[ Servtces 

IOIETALS 

-1- 

INORCANIC ANALYSIS DATA SNEET 

Claant Ueveon Otuup, lne 9ervaca prquaet: A2501266 

Psexaet No.: 2003022.013 Dete Collaeud: NA 

Gcoxaat Nane Aad Nall ON 9uqalvng Dsta 8acesvsd' NA 

Na4zcx: MATiR Unate y0/L 

Bsnie NA 

sauq:le Nnre: NetAod Balnk Leb Cedv- A2501266-M 

Melyta 

Mnlynle 

NethoA NRL 

Dilutlon 

pactoc 

Date 

Bat[aoted 

Date 

Malyret Accult C q 

Leed 6020 0 02 1 3/3/OS 3/9/05 0.02 U 

Columbla Analyticaf Services 

,w{TALS 

-56- 

SPIKE SAh1PLE RECOVERY 

Cl:ant: Daaaen Oconp :I.C. 6emce Begueet - N2501266 

Prejeet No •£q01023 013 Un1Ga: pg/L 

Proxe[t Nsms- Retl 9111 ON esvq,lvng Baa1s. NA 

Na[tar. NA1RR ! 9elvda. 0 0 

9anpla Nama. BataA QC Lab Cade: N2501269-0019 

Control eyike 9em1ile 6p1ka 

Mslyte . ~~~ . ae e..... C e...... C eww.w I 6R Q NeU:od 

9 6o11rL: 0.0 

C.ntc: 0001 t 

 - 000is 7 An n::pty ffeld ln tl:o Cont[O1 LSOLLt coln:m indlcatbe tM oontrol ]lmtt 1a no< applleaLla. 

rotv I- IN 

Pom V IPABS 11 - 1N 
Colunlbta Analylical Services 

METALS 

•6- 

DUPLIC.ITP3 

C11ent. Dcvcon G[ouP, lnc. 

Pro]eot No : 20010I1.019 

ProJoot Neme: Hed H>11 OH 9>nplang 

HsCSlz: NATLF 

SenPle Hema:9etcA QC 

eerviee Heqea>t: x2501266 

Oaltc: yq/L 

Besa.: HA 

e 9.1ia>: 0 C 

L.b Cnde- H2501969-0010 

I 4n.lyc. ~ ~ I s+.ple (9) C I Duplacete (D) C IPPD I Q I Nethod I 

Diesel & Residual Range Organics 

An eenty tield ln tDe Contiol Limte oolwm Sndl=>ta. tLe c.ntrnl 13mtt le nac ryPlleml.. 0 0 Q 19 00020 

Feam VI - IH 
COLUMBSAANALYTICALSERVICES.INC COLUMBIA ANALYTICAL SF.RVICFS, INC. 

AmlynW ltuum amlwWlRmmn 

ChenS: D.mmnGmnp Inc 

Frolccl: Iicd Hill GW S.imphnp/2001022013 

Sample M.Ine. 55'mcr 

Servkelkquesl: K25012Gb Clieet: 

DateCollaled: 02116RU05 pnJcct: 

DatnReteiwd: 02/192005 SampleMasro: 

Dnwton Gmup, Inc 

R<d Hdl OW SampbnN200102201t 

Wmcr 

Servlae ReYUe4: K2501266 

Dale Calleel<tl: 02/I4R005 

Date ReeeiseJ: 02It92005 

Dkxl and Re.udual RenFe OrKmiu D:ecel aod Rcvdu.d Ronpe OrKnnW 

Samph:Name. RH-B-MI 

LabCudc: K251112664101 

EctncOnnMclhod CPASSIUC 

AnalraeMmM1al• xlll'M 

Unils. upJl. SempMName: 

Bave: NA Lab Codr. 

Lccd- Low EslncYon Mclhnd: 

Malyw Mmhnd: 

RH-B-IM12 

K25012/6-(M)2 

EPA 351UC 

KISISM 

Unm: ulyL 

Bmn: NA 

Lc,icL Low 

Dipnlan Dale Dale Eatrardon 

An 1 t Name Rcvull Q MRL Futor Ertractd MWrrcJ Lal Note 

DuaelRmWelliynm~.D)Kn) ND U 50 7 02/22N5 03Po]N5 KWWSU3781 

Res:tlualRaneeUrb'nmIs(OtU) ND U IUO 1 OL2LU5 03N2N5 KWWSO781 

Comrvl Dafa 

SumproNwe %Ree U.N. Mal)tql NeM1 

o-TCrphcmd 81 52-128 OtNLtl5 Aa¢cpmDle 

n-Tnucornn.nx: `JO 50-150 ONI2Po5 Accepmblc 

Dilullon Data D.I. EmncOan 

AnnlvleName Rmult Q MRL Facmr EstraetW Andy¢tl la Nm_e 

IheselRaipxUrguma(DliD) ND U 55 1 OL27A3 03AY2/05 KWGp502181 

RceJiulRnn➢c(hmimv.:Nlt01 ND U I10 1 02!22N5 03NL05 KWO0301791 

Ceowl DmC 

6urngueName X.Rec 4min Anil)tnl Nme 

o-TCryhpM 82 52-128 031'02/05 Acceplablc 

n-TruuvnWnc 89 50-150 03A)N)5 Amcylabblc 

C. C.uummr 

00021 VVVGG 

Prmad O1m92005 IOIYd] rmm1A-Oteoow PuF> 1 nr L 0mui 03ro72005 I01728 ramin.Drgwc Poge 2 or 1 

u~weupvn.w.n ~ ,..i.m v~mm Npnra&6.eix 0.R46m9 m>ateaelc.ma RNNW]M 
COLOMBIA ANALVTICAL SERVICES, INC. 

Amlyvud Itmullr 

Cllenl: UaumnGloup Inc ScrviaRequut: 142501146 

PmJccl: ItcdH01GW SnmplmpJ2W1023013 DahCollecicd: OL16120115 

Sample.Nulnr. \V:ncr DRIeRecefved: ONI9/2005 

Dled and R<aidual Rang<Orpoke 

Snmple Name: RH-B-IM)l Unile uglL 

LabCode• K2501206-MH Darlr. NA 

Enr.utmn Nctlrnl rPa *vnc LcveL Low 

Anulv.inMrlbnA '.uNM 

Dlluma Dule DaSe ErtrueRUn 

AnalYle Nwne Ruult Q MRL FRelur Erlractetl Analpcd Lat Nme 

DluclRmSqc(npz—(ORO) ND U 50 1 02J22Po5 113fi2A1S KWC4503781 

RuIJuolRmlpeOrBmuca(RIR5) NO U IW 1 02122105 03102105 KW00502]B] 

Comml Dalc 

SurropntoN.m. Y.Rec Ilmn. Annh9<d Nub - 

a-Terpacayl )] 51-128 OS/OL215 Ac¢plubk 

n-Tnamntnne 84 50-I50 03112N5 Aazplablc 

COLUMBIA ANALttICALSF.RVICFb.INC. 

Amlyer+IRvrup, - 

Cheal: OausonGmup.Inc SenlqRequut. R250(Z(u5 

ProJeuF. RMHJIGWSamVlm(/2W1022013 DelcCnllrmW: O2117/2003 

Sampk Matnr• W.ncr Date ReceiveJ -02119Rt815 

Dkxl aoJ Iluialual Rane OrBeniex 

SnmpleName- RH-W-I)III Ilnitr• uyJL 

LnbCotle K1X1126fi4)Ot BaaN. NA 

ERracbnn MetboJ, GPA itI(IC Lctul. Low 

AnulymMmhnd: %OHM 

Dliutlon DAte D.I. Ectrwtlan 

AndyleName Rmult Q MRL Farlor Lttractctl Andy¢d L91 Nme 

DInelRnnqeOri•nhv(PROI I4110 Y 50 1 02122A15 05N'JU5 KW(1050228) 

RolnuulRUnμeOiyimolNNO) )ln 0 101) 1 OL2295 03rDJJ05 KW11050278I 

Camml Dalc 

SurrvRSUNeme Y.N. LImIN AnelyMll Nwe 

o-Tcrpbcnyl 11 52-128 01m2A15 Aaeplable 

n-Truusn5nnc "li 50-I51) 03102A15 Acceplabk 

a mmmmu 

00023 

Pom.d (ItnIT/IUnS N' IV 29 tunn IA-Orywc 1'osc 1 a< 1 

uviryou7ruunl....i.i,. AI>c.a aqvenN.finem 0.0.em19 

CbmmnN 

00024 

PlmloS 03/021W05 IOITtI I'olmlA-thypnlc P.I. I o< 1 

uUVLYe'ryu9 ~ummlmF ~ rlape tyu'JnR.fease pRVAM 
COLUMUtA ANALVTICAL SERV ICES, INC COLUMBIA ANALYIICAL SERVICFS, INC. 

Analvuwl Rnulu NmlSacnl RcsWts 

Client: O.IUwnGroup.IM ServiceRequut: K2501266 Cbeot: DnuaonOmup Inc SenicaRaqueat: K2501266 

pmjeet: RcdHJIGWSmnplmp/3001032013 DahCollecUd: ONI12005 projecl- RodHJIGWSemphnpJ2001023013 DaleCollMed: NA 

SvmpicMaUfa. Walcr DateReceired: OLI)R005 SampkM.nrne \V.mr DateReeerv¢d• NA 

Dleml aad Rmdual RanBe Olppmn Dicrel untl Raitlurl Ranpe Orpamee 

SampleName RH-W-OIIi Unite: ug(L SampleNama: MclhodOlank UnM. u8/L 

LabCade: K2s0126(HU)5 Bah: NA LubCwle: KWG0 50 218 1-1 Bnrb• NA 

Ealiattmnhlaund. iPntal(IC Isvel: Low - EatraclinoMelhnJ- EPA3510C Isrcl. Imv 

Anu)SrtxMetbW. 8015M AnaI511nMelhoJ 8015M 

Dilutlnn Uste Due Esnractlon DJUthm Date D.I. Enruttmn 

AnalylaName Rnult Q MRL Paetor EDracted Amlyted Lot Nute Anel,eN.ime Naull 0 MRL Faetor Entratled AnalYacJ 1ut N.I. 

DISeIReeBeOqnnm.(DRO) IMp 50 1 02122/05 03/02N5 KWCA502781 - ITmJRnnL IB,nnvvUeul 1\011 50 1 02/22tl)5 II]A)2R)5 KW(i)502181 

RendutlRaryleORamv.(RRD) 890 100 1 02R2N5 02102105 KWC0SOY781 Re+NwlRmiy 0iunnvaRlltl) VD U IW 1 02/IIPoS OSN)LOS KWW50P81 

Cumnd Da]e ContM Date 

SurniauteN ~ me %Rn Lmin Analy[uJ N"D BurnquteNeme %Rec lunin AnN)ze11 Nnm 

a-Teryhen)a 13 52-I28 01fl12N5 Ac¢pinble o-Telpbetql 11 52-128 0301105 Acceplebk 

n-Tnucnntonc 13 50-I50 01Po2N15 Aasplublc n-Tnacmnana 84 30-ISO 113m2N5 Acceplable 

Cixrvnnu tommwm 

ODazS 0 0 026 

I'rma;l ntln'q201N l0 1] 1 ? 1'orm1A-Orpmx Pugc t of 1 Mated 0]A1112(N15 1017 11 6um IA - (h•ynn PaBe 1 of I 

NupY kpMReknue 0.P., 60A iupsSnnduvae RnArlAN 
Surl = o-TClphcnvl 

Sur2 = n-Tnaconlanc 

51-128 

suaeo 

Rmb M1mN n IJ nln, rltl4 rmhal ... 

RrvYY n,p,tl xIN, Fx.tl I.1 iMene IMUw1Nm11N1,MryNbNe 

Yr'wil Ulftl)RUn; In I] lyl 

COLUMBIAANALI'TICALSERVICES.INC. COLUMBIAANALYTICALSERVICES,INC. - 

IM@C RcNn QArt)C Rryon 

Client: U.mwnGmup.inc Scr.iceRCquerr: K250I266 Clknt: DnomnGroupinc SerWeeRequml: K2501266 

ProJeck Red HIII GW Snmplmp)2001022011 Pml•+'r: ItM 11111 CiW S,imPbngflMIO22011 Dale Eatraeled. 02/22I2005 

Sempk:MOlm: Wolcr SampleMu., 'vlrrr DateAOalyceJ: UV02005 

SurragRte Rero.ery Summary 

D4ve1 avJ RnlLaal Ranee Olp,nnirr Malril, Splke Summary 

Dlerel end RpNuxl RanRe Orpaolct 

EclrnclmnMMM1omP F.PAlTIOC Um, PERCENT 

Ann6rnMabml• uniM l.arel: Inw SampleName: RH-BalUl UnllR: uSIL 

Lab C.ode: K25012fi(414II Bauc: NA 

EalraebonMmhW- FPAl510C Lercl: Iqw 

SRmnleNnmc LubCWe url Sur2 

MRIylnMmhnA: SI115M EslramionLUl: KWCA502781 

RH-B-0tll K25O1266-001 83 '10 

RH-B-002 K25(11246-002 52 89 

RH-t1001 K2]O1266403 n M RH-B-0OIMS 

RH-Wa101 K250126G-004 71 77 KWGU50]181A 

RH-WLlO K250126RM5 "/1 '/3 Mnarrspke %Rie 

Mc11mEBlank KWGUSU2l81-3 T) Ma ~mqr 

RII-B-0UIMS KWG(15027814 88 94 ApalyleName Rerl'Ir Rewlt EaptttcG %Iler Lmb. 

LabConuol5:unnlc LlVG050278I-1 74 R6 lh, RunycUFncs(URU) ND 3040 3200 95 57-158 

DuPlrutcl.dbCmveniti.mrylc KtVGI13111781-2 W 87 RmWudN.wgcUrp+mu(ItR)) ND 15e0 1600 96 I5-I37 

1 

SRrmRete Re.mep G'ntnA Lmit. (%) 

R~up, M1pN ~ nllln=.u,eY I'1 uulinre Wu[,auloJemnMamav 

RmM, M1Ob ~'Y. P^.N Iq ~ .tluw. Ye enW mulY nM.YNY.W 

a.~.~.~..,_.n„rr.,.F=.m'.ur..n...rRCm,mm ~,mctlerm.tln...m..n.._w...mr.n.I.eW,..R.,e.rF.me 

00028 0002i 

1,ann2A-Org.mn. Pngc l nfl Pnnlad 031072IX15 IU 1742 Fu1mlA-U.pPm. Pnpc 1 MI 

1puSrRefomm IIIItlN119 R.fm1u RN<60N 
Clirnt: Dewaun Gmup- Dlc 

ProjM: RcdHdIGWSnmphny1001022013 

EampleMatu: Wmcr 

Lnb Control SplktlUnphesu Lvb Cuntml Jp,ke Summary 

Diccel mtl IkdJUal RnnRC Or{tRmer 

EVinctlnn Mv11mJ LPA lilOC 

AnnWmMethal: MOISM 

Leb Caulml Semple DupLrale Lnb Contml5nmple 

KWG0507T81-I KWGt15029E1-2 

IabCUnlmlSpNa DupllmleLbCnmmlSplYe 

AunI5leNnmc Rwlll EaVeeted 9611ee Rault Epperled V.Ree 

❑nn.I0.m,pcttr•μmulUttU) 294I1 12W 92 299n 1271 93 

RaNmlltuuYrlb..nn..11lll'n 153n 16W 95 I4JU ILIm 91 

Service Rwluent: K2$01366 

Date ExtructcJ: 02112l1005 

DateAnalrteJ: m/WQOOE 

Dnile: uR/L 

BPne: NA 

Lnx: I.ow 

EatnclbnLm: KWGOEOi)tll 

•ARee RPD 

Ilmm RPD Ilmlt 

61-I31 1 30 

59-1e6 2 30 

COLDMBIA ANALYTICAL SERVICES.INC 

ONQC R 9un 

Gasoline Range Organics 

p.vn.nvm.wu ............. ~.~ n...ux..n.w.,unv.,arum. 

00029 

00030 

Ihmtal 03A1W2005 I01946 Furm3C-O+pemc Puye Ipt 1 

uMWNtYyYpmumVN,.p RRNYl9 
COLUMBIA ANALYTICAL SERVICES, INC. COLUMBIA ANALYTICAL SERVICES, INC. 

Amlyncil R>uh. AnR1yRJ ltesulL+ 

Clicm: DRnsonGrimp.lnc ServiceRepueaL K250126G CBrnI: DensonGroup.lne ServaeRe9uests: K2501366 

Prolal: RcdHdIGWSemplingl2001022011 DareColkrld: 02/16r~0115 Pmlec.r• NNIItl1GWSempbu`IJ2001022U13 DRreCNlttted. 0211612005 

SampleMelrvx. Wnter DateRereivN: 02/19121)[15 SwpleMarm Wulcr DIDeRerened: 02/19RW5 

Gemllne Rao¢ Orynicr Gxmlme Rsnge OrARmee 

Sampla Name: RH-BL01 Unrrr uPfL Swple Namc• RII-B 002 Umb: upJL 

LabCodc: 0,50126G+101 Buir: NA LebCodr: K25012664X02 Bsr:a NA 

Estrxbon HvlbnO: FPA 51130B Lecel: Low , Earnctiun Mclhod. EPA 50308 1-mel Low 

AnnlywoMarhW: c0I50 AnslyalrMelhod: X0158 

Dilurlm Datc Dalc Exlraclmn Dlluriao Dale Dale ExlrReuon 

AnRLteMame Rnulr O MRL Faeror Ertrened Anal3zed Lof Nol_e An.1yerN Remll O MRL fector EmrarlW AealYa.al LM Nete 

GatROnpeOrgamulGH07 ND U SU 1 01425105 112/25/05 KWG0503UV GeenbneRanpcOre.n.matttptA ND U 50 1 O2115tt15 ON25p15 Ku'U15011117 

Conrrul Dxle 

9orrqateNvme 4.Ra Lmna AnRlytaJ Nnre 

1,4-OtnumWxvun 95 15-12I1 02125IJ5 Acapable 

Comrol D.I. 

SurrRawName •%Ra IAmlu Amlyi,d Nnle 

1-4-Ddluorobeniam 95 75-120 02f25M5 Aecepinble 

Cmw..u. 

00031 

PMtN 01tl17124111 i In 1] 3G Fmm IA-0yam. Paye 1 of I 

• ~'ue,u+Cn,u ~ m".m~i~~n ~bpJ Syr5n0.ef 0.R ~W]8 

Prmkd 0i/117/2W5 101235 Fmm1A-OrBoou 1'oge 1 0 1 

..a ~ una~'SI^YTNmn ~ nT M.'W L`W1G4fomu RAKOIF 
COLUDIBIA ANALYTICAL SERVICES, ING 

Mohv ~ vlRnuW 

Clmnr UmtwnGrnnp.lnc ScniceRCquruL K25012G4 

PrOlttt: RWIIIdIGWSemphnS/100102201J DateCollectul: 02/I612IX)5 

SamplcMatrix: Wnmr DateRecci.N: 02/19R005 

Gew1iM RanKC OrBnn:cr 

Sample Numc: RH-B/:Oi Untur up/L 

Lab Cwle- K25tIl24hal0i . Eute NA 

Exltactinn Ma•Ihnd: CPA lnillD Lerel: LUw 

Anelyae Mctlwl. IuU 515 

Dilutiun Date Dnte EatnebUn 

AnalyteName Remlt Q MRL Rartor Ertrscled AnNyad Lot Nnle 

GomWrlLmBC(hplNC.l(IRO) ND U 50 1 02/25A15 0225N5 KW1i0503101 

Cun4W Dale 

RurtnpaluNim. %Rer [Jmib Annlyud Nnm 

I,C-D:Rumdr,lvun 95 75-120 0225/O3 Aceepmble 

COLUMBIA ANALYTICAL SERVICPS, INC. 

Amlyucal Resvlu 

❑lent• D.'mn Craip, Inc Scrrt¢e Requeel: K2501266 

prolat• RetlN:11GWSamplmyZ00102]OIJ DaleCollected: 021I12005 

SumplrMntrn Wnmr DateReeeh•ud: 02/19RO05 

Guoliuu RanBe OrUUnlrs 

SumpleName: RN-W4KII Un:b' np/L 

LabCoUC: K2501264-OO4 Buru. NA 

Ertraulon Methal: EPA 50300, Le.xl. Low 

Aoalym Method. 81115B 

DRUUan U.I. Latc Extraahon 

AnnlrmName Re.ull Q MRL Vaetnr Exlruted AnulSUd Int NMc 

6onl ND U 50 1 0225Po5 02/25/05 KWG0501107 

Cumrol Date 

SurroBattNUme %Rec Llmlu Antlycd Nutr 

l6-D0w:alvwutc 90 75-120 02125103 Acaylablc 

CMIIM11h Cwwmu 

Pnno.rl IItN1112:XR III 12 19 lrnn IA-(TBUmc PnRr 1 oI 1 

v.4WWMtmam+.-InT .w.e'~ F•T~Cram. NNWPJr 

Pnnutl 03A)112005 101241 1wmIA-aymN Paec 1 af 1 

uNUnnVSnYT'f^mlmnn Nuyd lyvinad RPa6078 
COLUMDIA ANALYTICAL SERVICES.INC. COLUMBIA ANALYTICAL SERVICFS, INC. 

pmilylruilMLKUIrs ArWylrrnlRevulu 

CIknL• UmsonGronp,lnc ScrvtceRe4ucvt: K]501266 Chent: D.mmnGmupinc SmfceRequeet. K25M266, 

ProiecL RMHtlIGW$arnplmt/2001032013 DateColiee5cd: U2/I712005 Pmlecv RMIiJIGWS.rInplln0/2001021011 UaleCUlleelW' NA 

Sam4lE Wlcr DRCRCCCivad: 021192005 SempleMnrrr.: 55'a¢r DnteRttnved. NA 

Gauollne RanRU Organla Gawbne RnnLe Orqnmca 

BamPlaYnrnr: I2H-w.On2 Unb: uE/L SRmpleName: McllwtlBl:ulk Unitx: IrE/L 

LabCm, 6231112644065 Bblr. NA LRbCak: KWGIS503107-5 Bastc NA 

Extracuun MctM1nO CPA SniOB L<rch Low EnlraemrnMetbuO. EPA 501119 Lcrxl. Lon' 

AnalSnaMctlrml: 80158 AnolyRrMClhnO: 91115B 

Ddullan Datc Dete Entraellon Dllution Date Date Exlrullan 

AnalytnNnme Rmlt Q MBL Factor Eatraded Analne0 Lat Nolc AnnhteNnma Remh Q MKL Faclor ExtrncteJ Mxlycc0 Lol Note 

GnmluklL.yr(hynu.(I,RO) ND U 50 I 0221U5 02/25A5 KW(A50310) Gumbneltonp•Unmmtldt(17 ND U 50 1 0225/05 0225105 KW(305010) 

Cnnlrnl Date Cnmrul Dne 

SumeuleNnm 6Rar Umus AnalyzeU Nale $urlryWNama S:Rtt lamro Anelyrell Nole 

1.4-DtBuorobcncam 93 75-120 02ASN5 AcspLlble 14-DlDuolabcvsnc 96 75-120 02/25N3 Axcpubk 

c.mm.rru Onruneenr 

00036 

PmrIN 03nl72pR 1012J2 Fwm1A-(hFomc PoRC 1 nfI Rmlul 03N72W5 1111215 4amIA-ITry- Poge I aC 1 

•weJn'uyunmvmmimnr ~ (up fqvA ~lRRnmw 0.RrW7x uuuYV]yetlqrcmrnn" MuM y. a.lm... ItRlnnla 
COLUh58IAANALYTICALSERVICLB.INC. 

OAIQ(: ReWn 

Cllcut: DawnnGraup.lm 

Pru3etl: RrdHIIIGWSnmpbnp/20U1022013 

SamplcMrina: Wmer 

Surru¢ate Rew]ary Summary 

GaYolinc RenRC Orqanu:t 

EEnt[eCIInnMPllmrl I.Pa51t1lIR 

AnAlv]nMellmd: %(IISB 

Samnle Name LJb CM, Sarl 

RH-B-001 1(251112(6-001 95 

RH-BJIO] K25012fd-002 95 

R11-B-001 K2501266403 'IS 

RH-W-00I K25U1266-DD4 90 

RH-W41112 K251112664)U5 0 

McthoEDlenk KWCd1503107-5 96 

RIi-U4101MS KWG0503107-2 11MI 

RII-B4101UM\ KWGU501107-1 98 

LSbCOnIrolSamplC KWG01131074 101 

COLUMBIA ANALVTICAL SERVICES, INC 

(jAlfK:ltpat 

SemceRe4um1: K2501266 Cllenl: WuamGrm:V.lne ServleeRequutr K2501266 

Proleu ItcIIHdIGWB.unplmg/211UIn22013 DaleExlr.uted: U2/252005 

SumllleMalnr: W.n.r Du[eAOalyicd: 0225/2005 

Mnlria Spike/Duplmale Matrix Sp[kc Summary 

GaWlneRanKeOrPAnin 

Doitx: PERCENf 

Level- Low Sampk Namu: RH-B4001 Unilv: up/l. 

Leb Cmie' K25111266-001 BaYla: NA 

Eztractlon MeIM1M• EPA 5115110 Le.el: Lmv 

Analva.arthal• xnlsH ExtnebonLol: KWG0501107 

RH B-OOIMS RH-BamIDMS 

KWG0501107-2 KWG0503107-1 

Sumple 

Mntrlx 5plle Du pllat[MnrIYSVIke H.R¢ RPD 

AnalyteNamc Raull Rwlt Eapeeled •GRee Runlll Eapcaml %Ree Lrmlu RPD umtt 

Gaml:vtRe:geDrYUn:u((iRD) ND 489 SW YN 451 500 90 69-128 R 30 

Surrnqvin Rn[ur[n Cun:rol 4m1Y 

Surl • 1 J-DlBuotabcn.cnc 

Nvulu nn[rd xuY ae vwnJl'IUnIUMr r[Iw•rM.We[mlvla[Ilma 

Amnr II vnd xrll.. r ~ nnw I[r.Nr.n. rYmm~A tW.erM1 NaMatV./a[M 

PnnIW IIitl1713(R)5 IIII347 hmm24-(hYnmc 

u vr..uln]nal mu r..e ru 

I wwun.e+•M[v.wr.Yrlwm[mwa..w•r.mxarwrs 

MWanaqNNrpa{wi~IN11u0NUe111eunarAnlYahN W vOtanme 

00037 

Mn'r[nwti~ aMrt4TeA YJIluavvinM]IanavmnJWaoullwmrlryraWnllsukWaMnMTmrcmYSeruML 000ae 

Pnge I of 1 

pnnlal II1N7fXM15 11112 ill Imm1A-(1rY+mc P+YC 1 al I 

4yvw ~mxe kA1f4]P unuLiYt ryrYT'I ~mVMM1rn 9xr5[IP<IV.re< Mn<411Y 
COLUMBIA ANALYTICAL SERVICRS, INC 

QA/Q(: RyWI 

Clienl. OnumnGroup,lnc Serv+teRC9uetl: K2501266 

pmjerl: Ratl Hdl GW SumpOnt/2003022013 Date ExtraeteJ: 0223R005 

SRmpleMatnx - WRRr DamAnnl2avl: 02252005 

Lab CRn[rvl Sp1Ee SummRry 

Ga.uline Ranqe Orpymcn 

ExtrJcn+w MethnJ• IiPA 5010B Unlb: uy/I. 

ARalya.MctMN: snISB Bnls: NA 

Le•,el: Luw 

Extrucliunlut: KWG0501109 

lab Cnnlrol5amplc 

KWG05071094 

LbCwtmlSNW %Ra 

Anulpte Name Rqult ExpeeleJ %R<r IAmlb 

CJmhu<h.Il+.ulA:•In+..a;ltnl .lul 500 98 71-128 

EPA Method 504.1 

Rw4, IYpM wyY anv.ieJy I'+pWl.-iY ~+Nn.u+JJetwW vYaN 

Ibmn ntwn.~ ml+,+nrvt nn, ~ n SII.nw,IRl'1)IwalweYE b Ikvup+~a uur„dvam+p tyaJWnN.MMe nYtm ~ vM6 

Pm+uxt 07m7/201). 10125'1 PO^^x-OrWm. 

u~~WNYVrryJTJmmntiT "r+++MUC® RRJ(AIR 

00039 

Pu6< 1 ur1 

00040 
COLUMSIA ANALYTICAL SERVICES, INC. 

AnulSVmlResuln 

Client DaxsonGtoup Inc SenierRequm: K2501266 

Pm3ect• Red Htll GW SamphnFJ2001022 DII Dnte Colleeted: ULI612005 

SempleMatrfa: Waw DRteRCCeivcd: 02/19/2005 

EPA Method 503.1 

SRmpleName: RH-B-001 UnHa: uy/L 

LebCode: K2501266-001 Banr: NA 

Eatracdon Method: METHOD LerrJ Lon' 

Analytm Melhod: 506 1 

Bllutlun Dule Date Eatraellon 

AnelyteName Rpult Q MRL paetor Ertmetcd AnalyacU Lot Note 

12-D1brvmcethanc(EDB7 ND U UW83 1 OT/28/05 02118N5 !CWCO503282 

CuntrW 

SumpeteNnms °/.Rm I.mm Nem 

COLUMBIA ANALYTICAL SERVICES. MC. ~ 

nwlNmal N.11a 

Cllent: DawsonGmup.lnc BerMCeRcqumt K2501266 

Pmjecl: Red H01 GW S.ImpImF/2001022013 Dele Culleeted: 02/I(d21)05 

SempleMRlrm: Waler DeleRecebxd: 02119I2W5 

EPA Melhod 503,1 

SampleName RB-B-002 llnite. ul✓l. 

I.ebCode: KI5111366S102 Bana: NA 

Ertraelian M<Ihod: ' MEIHOD Level: Low 

AnalyJr Melhml: 5041 

DlluLon Date Dnle Eatract:un 

AnalyteName RemU Q NRL Faelnr ELracled Anatynd lul Nule 

1,2-Dibtomoethene(ED8) ND U 00081 1 02/28tl15 02R805 KW0050321 

CRntml 

3Rrlv{ebName Y.Rea Um14 Nme 

Cmmumt fmm mue 

000e1 00042 

Pnntcd O3NI20(15 085813 FonolA-VWSmu Pnye I of 1 Pnmd 03Po1/3005 085815 I~onn1A-Orgruuc Nnp: I nf 1 

u~NnN ~ ISmYmY.m, ~ m,p Mvpl SupeYasRef RRe59M hp4nMelvaee nReSY]e 
COLUMBIA ANALYTICAL SERVICES, INC. 

Awlyt:wl Raults 

Clknt. DawwnGrouF.l:w SerWreReyuett: K250126L 

Proleet: ReGHtlIGWSemphng/2001022017 DateCellemeW OLI6/2005 

SemPleMalriw: Watcr DamRecerved: 02/192005 

EPA Melhod SOJ.1 

SempleNrn¢ RN-11.011 Unitr nF/L 

Lab Cotic: K25012664307 Beriv: NA 

Extnmlon Methotl: METHOD Leve1: Low 

MaIYDr M6botl: 504 1 

Dilullon Dale Detc EstrRCbon 

MnlYle Name Reatll Q MEL Factur Estnctad Ndyied Lut Nde 

1,2-Dlbmmoe0lane(HDB) ND U 00012 1 OL2EN5 02128105 KWG0503282 

Camral 

$urrryyleNUmu XRaa l4nar NoM 

COLUMBIA ANALYTICAL 9ERVIC[S, INC 

Anellt ~ mlRexW:s 

Cllent: Daxion GrouP, InG Semrc Re4uest: K2501266 

ProRel: ReCH:11GW5amphnn001022012 DrteCollevled• 02/I7/2005 

SamPleMetrim. Woler DateReceired: 02/19RI105 

BPA MrUwU SU4.1 

Sampletlamee RH•W+ml Umn• ug/L 

Leb Cotle: K2301266-004 Basn: NA 

ErtraeDon MetbOa: bIERIOD 4ve6 Lmr 

Atu15Rr MethOd: 5041 

Dllatloe Dale Date ErtracBon 

AoalykNeme Rewlt Q MRL Famor EaDaeocJ Anelyrt0 Lot Note 

1,2-Dlbmmoe0une(BDB) ND U 0C083 1 U22B105 02128103 %WG050)282 

Cumrul 

SarrvRUteNVms Y.Reu IJmin Nerc 

C'umomu tbeumM 

00043 00044 

PrmIeO 03/012005 OB 59 17 fom IA - Orgamc 1'ugr 1 e< 1 P.maxl 03101f2005 UE 59 19 Yrgc 1 of 1 

•wnNkfryaam`rmntmT 1'tiW 9WC9nRelnms RRa59M . ~ rWUNWmVmm~ nm Wml 9eμKnae'uae RR9f929 
COLUMBIA ANALYTICAL SERVICES, INC. 

Anxlyuul R-1N 

Client: Dauron Graup.Ioc Senitt Requat: K2501240 

ProjM: RedHdIGWSamphn8rz001012013 DatcCulleeled. ULI712005 

Smnpl<Metna: Wmer DmeRecelved: OL19/2DI5 

EPA Mabad 500.1 

SampkName: RH-W4102 Uane: ug4 

Lub Cadc: K2501266-005 Basis: NA 

EnrerUon Method: MEI'HOD Lacl: Low 

AnalSrir Melhod- SM 1 

Dllorlon D.I. Date Evtrxdmn 

Analytc Name Brmll Q MRL Faetor Ertracted Aeslyaed 1-ot Nocc 

1.2-D,bmmocUUnc(EDB) ND U 13W82 1 011I8/DS 02/2%MS KWG05031ex 

ComM 

Sur,oRr,e Nzme !4Rev Lmll. Nnte 

COLUMDIA ANALVTICAL SERVICES. INC. 

A,nln,ral xow ~ 

Cheno Da,rsunGroup.Inc SenittRaquul: K2501260 

P,njat: Red}BIIGWSemplmgy21N110220P1 DaerCollalcJ: NA 

SampleMatnc: Wazer Da4Remxed: NA 

EPA Mctbad SOC.1 

SampleName: MetbodBlank Units: ngM1. 

LabCodc. KWO0503182-3 Baeie: NA 

Enrammn MMOd: N4THOD Isrel: Lox 

Analysis Mathatl: SDi l 

DduOUn Datt Dah Eqractlun 

MalpteNmne Raull Q MRL Factur Eatracted Analymd Lot Nam 

1,2-DbmmoeU,ane(EDB) ND U 0011 I 022&05 02/28105 KWG0503182 

ContrW 

Sarto[aallome YrRer laml4 Nua 

Caumnu 

Pnniea 03101/2W5 085821 tamlA - [heanu. Poer I or I 

.muunyw ~un~.~ni.m iwra sy.nax.rt~.~ xxasnu 

Conmwrr 

PnnNe 03N1/2005 085823 ronnlA - Orgomc Page I ot I 

.uwarnanaumei ~ ..m umW i~xwh ~we RMYrie 
COLUMBIA ANALYTICAL SERVICES, IRC. 

QANCItWVn 

Cllcnl: Dneson Group. lnc Service Reyunl: K2501266 

Pro)eet; RedN01GWSamplrng/2001022013 DateEatracteU: IDR8I2005 

SempleMetria: Waler D.IteAnalyud: 02128ROOS 

Mvtriz Sprke Summary 

EPA Methotl 506.1 

SampleName: RH-B-003 UoNa. u8/L 

f.nbCaJe- K25012664)(11 Bafie: NA 

ETtracemn Metbod: MEiHOD Lerel: Luw 

AnalyanMtlhod: 5061 BxtrammnLot: KWG0501282 

RH-B-0U7M5 

KWG0503282-2 

BrmPle MrtNxSptr Y.Rer 

AnalyteName Result RpyN Enpnctetl 9Reu 1/min 

12-Drbmmoclhulm(EDB) ND 00596 011591 101 65-135 

COLUMBW ANALYTICALSERVICES, INC 

QA/QC R pM 

Clirnt: Dewaon Group, lrc Serrice Requext: K2501266 

Projetl: Rcd Wll GW Samphngr2001022013 Dalt Extnctetl: 02l1&2005 

SampleMetrix. Weler DatrAnul3ysd: OL282005 

Lxb Coutml Spike Summary 

E.PA MdboO 507.1 

Enrallon tle11ro0: ME7gOD Unite: u8lL 

AualYrlaMethoO: SOaI Baab: NA 

Le,el• Low 

Enrvctlon Lnt KWGOSO1282 

Lah COmrul Samplc 

KWG0503282-2 

labCamrol8ptlw %P.r 

AnalyteNeme Rcmlt ExpMtetl ARer Om:n 

1,2-DlbmmocthaM(®B) 00744 00714 ItN 70-I30 

x..Jn mma.m..ww~ (•Irr,l...w., Wwx ~ a+,aom.. 

MJU ney,J ~M ~ peueMlNaueisewutl m:avnwpMWns4 r(mM1 ~ aqW JY u wnYl'I IWNU rJmuutleeuuN<xnM 

easw ~ vo.00Wubmesvmiseauevinnnme,anw,ehwufw.evnwneuwdWasmween6n. ~ ne.e.iv.aea QOOdI OOOdtt 

PrmteA U310V2005 085827 FdmlA <kgans P.J. 1 0l 1 1'nntal 03N1/1005 085830 CmmlC-[hMnw PnBe 1 ul 1 

u.:d1mW RRI5919 
COLUMBiA A.VALYi1CAL SERVICES,IWC 

Asu15aW RevJb 

Clienk OexYpu Group. im SelNee Ecpueet: K2501266 

YSOJccI: RedFWIGV15aniplmpJ2001U12013 DetaCulleeled: 02/16Q005 

SampkMahtr: Waler DNeReeebW: 02119ltl105 

Valatlle OrFloie Comy6Rnds 

Sample Napu: RN-B-001 Uuiu: uy/L. 

LeDC6Ee: K2501266U01 . Rede: NA 

EalrsBOn Mtl6od: EPA 5030B Isse3: L. 

Aoalyei6 Me068: 9260B 

DOuUon Dne Dete EeeMlon 

AnRlym Neme ResiD O MRL FeMOe ErtroctM Anelyeed Lm Nole 

Benrtoe ND U 050 1 03N2115 03/02/05 KWCA503506 

Melhylle¢-ButylElhv ND U 050 1 03102105 03102/05 KWG0503506 

Tdurae 1.0 050 1 03/02105 0316L05 KWCA503506 

Eery@ev<a< ND U 050 1 03/02A5 03/02105 6W005o3506 

m,P-Xykircs N25 U O30 1 03NLJ5 03/02/05 KWO0503506 

o-Xylme ND U 050 _ 1 03103N3 O3/02105 1:Wa0503506 

1,2-ACLlomethanclEDC) ND U 050 ~ 1 03NL95 03/OL05 KWfA503506 

Coeaeol Dm 

Volatile Organic Compounds S""°"'°Nem` XR ~ "' A°"''~" N"` 

MbnyRolhuOmpiqN9aC IUS HO-119 03ro]A5 Acceplable 

EPA Method 8260B T°I°eRe" 113 E3-113 03'°7ro5 °.mepal'l' 

9-Br6nwBmmbenttpe 99 72-113 03N2005 AaxPlebie 

0U0At1 

1kwW 0311311005 12 37 31 Fer.nlA - Oagao¢ Pe8< 1 of 1 

°~T'FmmlmT MnM 9p9nRef RR1611'I 
COLUMBIAANALYTICAL SeBVICES, INC. 

A:Wynd PmM 

CBmt: DaxsovGnm0.lrc SeninReqom• K2501266 

projal: RedHdIGVlSampLngJ2001022013 DtleCoBeNed: 02116Q005 

Sempk Motris: Weler DUC Baehsd: 02I1914005 

COLUMBLt ANAI.VTICAL SEBVICES, DiC. 

Rortyod Keadu 

CUmt: Dawme OmuV, lm 

Pmlect: FrdHdIGWSempl:np/2001022013 

SampleMafrfa: Wara 

Service Requal: KI501266 

Dm Coueeted: 021162005 

Dace Rcedrcd: 02119/2005 

Vulatlk OrKWt Compomde VdxUk OrBeuk Compouudr 

Semple Name: RH-B-002 0u14: up/1. Semple Nume: RH$003 Udle up/L 

I.rb Cotle: K2501266-003 Brdr: NA Lsb Code: 12501266-003 Bn4: NA 

6atnefanMetGod: EPA5030B Levtl: Low EalnetisvMelhod: EPA5030B Level: L. 

Aeelytle Mahod: 82608 MWydr MeWOd: 82608 

Oiludm Dale Dote Calnrtbn DButbu Dife Dale Kqnetlm 

AvalyleName Bemk Q MRL peelar EnrcGed Ae lyxd Iol Note AnetyOeNwe BewB Q MRL Rertor ErIne1M Auelyaed Lal Noce 

Bmmm ND U 050 1 03/01/05 03/01105 KWCAw3a98 Bmmue ND U 0.30 1 031OlN3 03101/05 KWO050349B 

Mdhyltan-BmylEtMr ND U 050 1 O3N1105 03iD1/05 KWU0503498 Methyl[all-ButylEtM ND U 050 1 0310I,U5 03PoIPo5 KWCOw3198 

Tolueue 1.2 050 1 03101/05 031OIA05 KWG050J49H TOlarx O.BI 050 1 0310105 0310V05 KW00503a98 

Ethymma:ro ND U 050 1 03101105 03101)05 KWCA503498 ElbylMerene I.'D U 030 1 03/01105 03/01/05 KWCA503i98 

tqp-Xylmu ND U 050 1 03A1/05 03N105 KWG0503490 m,p-Xylenn ND U 050 1 03/01/OS D3/OIN5 KW00503a98 

o-Xyleae ND U 050 1 0310TA0S 03AIPo5 KWOO SON99 o-Xylu:c ND U 050 1 0310 1/OS 03rU1/D5 KWGO5o3498 

1,2-IDWatoesane(EDC) ND U 050 1 0310I05 03AIPo5 KW00503n98 1,2-Dichlwvdhem(EDC) ND U 050 1 03PoI/05 03101/05 KWGOmM98 

Caetrol Dah Cootml DaR 

SvrrqrkNeme °ABU Dmiu ApylY&O Note SurragYrNwe %Ree Ilmltt ApyysM Note 

DbmmoOUommtllum 95 SO-Il9 03NI105 AwepDMe Dtbrmm0umomdhooe 94 80-119 03101N5 Aary:ebte 

Taluem-0S 91 33-113 03101105 Ac9epleble TolumWB 91 33-I13 03101105 Aaxplable 

<-BtomOBoombemeoe 93 72-I14 03/0I105 Ameplabk 4-13mv:ofM1mmbeomm 92 72-114 03101/05 Aceplable 

Cmmmm 

0005 00052 

Pnnut 03/1511005 @3733 Fam1A-Oteaoc F+ee t of1 Pm1W 03/I5R005 123736 FmmIA-Qyauc Pye 1 of 1 

uWW6lryuYp(Swlm,p Yep] 9qv9tlWnvu RAKJrI aWetlM]pYryN®Imp Mepl SmS.Pdwo RHK31] 
COLUMB7A ANALYTICAL SEHVICSS, INC. WLUMBIA ANALYTSCAL SEEVICES, DIC. 

AodynW RevWu nWynal RaWO 

Clknt: Dewsoo Oroup, loc 

ProjeM: RadN01GW'Semphog12U01022013 

SxmPlrMtlric WDv 

Vo1Wle Orgadc Canpwoda 

SsmpleNOee; EB-W-001 

LaU Code: K2501266404 

EalneOm Melhod: EPA 5030B 

AmlYUe MNNod: 82606 

Servire BCpuM: K2501266 Clker: Dawmo G:oup OK 

Dak Collee¢d: 02117I3005 PmJeeL F<d Hdl GW SemPllogl2001022013 

DemBeceired: 01/1912005 SampkMrtria: Wamr 

Velatik @yolc Compouvdr 

UeiD: ugyL SrmykName: RIl-W-002 

8N6: NA LabCade: K2501266-005 

Lee4: lm• Eelne6anMnbud: EPA503U8 

AoalydeMelhod: 8260B 

9enieeAeqoen: K2501266 

Dcte CoBeeled: 02117f2005 

Dale Recelved: 021192005 

Uolec ug/L 

Bnlr: NA 

levtl: L. 

ODNbo Date Dtle ELrreDOa 

AmlyteNeme RedB Q MRL FWOr Ertnrled AodYUd I-al Noro 

Benzme ND U 0.50 1 03102105 03N2.05 KW0o50>a9B 

MeDryl¢D-BurylEther ND U 050 l 0102105 03102105 KWG050349B 

Taloae ND U 050 1 03102105 03102175 KWOOSWa98 

EIhylBrnzene ND U 050 1 03N2105 03Po2A5 KtVG0501498 

:qp-Xylenes ND U 050 1 03102/05 03r02105 KW00503498 

o-Xylene ND U 050 1 03/02105 03N2Po5 KWOOS0349B 

1,2-DwtJomeNeneCEDC) ND U 050 1 03102/05 03102/OS KWGOSm498 

Creod Dtle 

BarrvKrhNrmr '<Nrc Limlb AprlyrM Nah 

DlblomoSWOmoKllune 93 80-119 03tD2/05 Aompuble 

Toluened8 89 83-113 03N2105 Aaxpabir 

4-DlomoOuoropenzem 92 72-114 03N7N5 Aaxploble 

DIBUUOV Drh Dah E>ase0on 

Aual9leNam! Rcmlt Q MRI. Famr EararuA Aoalymd Lal Note 

Benn+m NO U 050 1 03102105 03103/D5 KWOOSO3e98 

MMhylmrt-DmylEWa ND U 050 1 07l02/05 03002N5 KWG0501498 

Tol:wo: ND U 050 1 031020 03/02/D5 KWGO50)498 

ND u 0 SO 1 O3Nb05 03N2N5 KWGOSW998 

ND u 030 1 03103A15 03102105 KWOUSWO98 

Cwwl DNe 

Smroprc Nrmr llmlb Aeylyi<d Note 

93 33413 03N2N5 

9-10romOBwmbenxeoe 93 72-114 03N2105 

00053 

Pe:okd 03/1512005 12.3738 PonolA-Orgme Pyr 1 ee 5 

uV ~ eIP`6uJq,Fan ~ mry Meptl 9qa9ePCei R1,631f 

00054 

PnoNd 031152005 133740 FonvlA-Qynu Fw 1 01 1 

eWYWIW,{l6ewlmT MnN SyureAefum¢ e8i6Jll 
AlWyaeal RvWla 

Clknt: Dnw50n Gmup, lnc Servke RequM: K25012fi6 

Frajeq: RadHdIGWSemplulyJ2001022013 DateCollected: 02/16I4005 

SwpleMaeris: Waler DpeRasivtd: 02/1912005 

VaMlk Olgank Camp9nnar 

SampkNamc TnpBlaNc Units: aF/L 

I.eb CoOe: K730126b006 Batle: NA 

KNUtion MelEoO: BYA 5030B Itvcl: Low 

AnolyrisMelWC: 92608 

AoW5lsNeme Bealk Q MRL 

DButlon 

Feetor 

Dute 

EalruaA 

Dtle 

Andyud 

Ertrarlko 

Lm Nme 

BC:Dene ND U 050 1 03N2Po5 03/07J0S K7003039% 

Mqbyl tat-Baryl Ether ND U 0 50 1 03102q3 03N2/OS KWGO50309a 

Taluene IA 050 1 03102105 03/02Po5 KWG0503698 

EOtylOanzenc ND U 050 I 03N2105 03/02105 KWG0503498 

mp-Xylmes ND U 050 1 03102105 03107A5 KW00503498 

a.Xyleoe ND U 050 1 03102N5 03N2105 KWOO503a98 

ContrW Dak 

Sarrqrleleame xRee IImW AmlyreE Nqe 

DlbtumnDuommeDlaae 94 80-119 03N2A7 Aooeqebte 

Tolumed8 91 83-113 OlNLDS Aocepeble 

4-BtomoBaombe:vrne 92 72-114 03N2J05 Ao:eplabk 

COLUMBIAANALYTICAL SKRVICES, INC. „ 

Aulyaml Remlls 

Cllrst: DausonGml:p.lnc ServlreAequeat: K2501266 

PmJect: DedILUGWSumphapJ2001022013 DahCaDecled: NA 

Bampk MstAr: Water Da1e Receiv<A: NA 

Vaktlk OrourIr CampamOr 

SwpleNeme: Me1LudBlank UnW: ug/L 

LebCOE¢ KWG05033914 BMk: NA 

EarartimMeOOC: EPA5030B LeM: Lwv 

Annlyrk Me0o0: 9260B 

Dllutlon Date Dete Laeractlon 

"Myte Name Remlt MEL Faqar EerrncteE ArWyned Loe Note 

Bemcne ND U 050 1 03/OINS 03NI105 KWG0503391 

Metllylztl-BurylEOttt ND U 050 1 03N1,05 0310NNS KW00503391 

Tolaene ND U 050 1 03N1/0 03107/05 KWG0503391 

EU:yOxvane 1.'D U 050 1 03/01/05 03101105 KW00503391 

mp-X)kaes ND U 050 1 03101/OS 03/01/DS KWCA503391 

o-Xyleue ND U 050 1 OJPoIN5 0310IAS KW00503391 

1.2-DldOome:lune(EDCE ND U OSO 1 03A0I105 03/OI107 KW00503391 

cantml Dqa 

SarmyueNwe xRer IJmlu Aoelynd Nooe 

DlbmvmDlmmmGhane 101 80-119 0310IN5 AcueptaNe 

Tolueoe-OB 113 83-113 03Pob05 AcoeplaNe 

4-Bromo0uom6wuene 99 72-114 0310I105 AwepteDle 

PnaM1 03/I511005 123742 Fa®IA-Otpruc 40 4 1 

°q°'46qWIN ~F°°I^"p 4bWl sTaRelees RR4019 

Comm:: 

00056 

Ftlotrd 03115(!WS 123745 FonolA-O:puac Pege I M 1 

uVbN'Oryl9(l'm~ lwp NvgY 9~e5CRC e RRWI9 
COLUMBIA ANALYTICAL SERVICBS, OIC COLUMBIA ANALVTSCAL SBRVICES, BiG 

AmlYlvel Keadb AmlJUw Radb 

CB®l: Dawson Gbwpp, lnc Servim Itripmot X2501266 Clknt: Daamn G 

F.ojnt RedHBIGWBUOpLng~l001022013 DaleCo4eefeE: NA Ftojecp FeAIW1GWSemplmg/2001012013 DahCelleets0: NA507266 

SwpkMdJic Wazer DdeR~A: N SampkMa[Nc Weov DeleBecePoe& NA 

VOlaalc Olyavic ConpmnEN Vdelile Oryode CompOenUe 

SempkName: MChodBlsnk Uolb: oyL SampleName: MoWOCB1eWc Udts up/L 

LebCoOe: KWG05034984 Beur. NA IsbCnde: KWG0503506-3 Baw: NA 

ErteecYOV Me000: EPA 5030B Levd: Low 1CLnctlnb MeUoO; BPA 5030B Level: Ww 

Avdyae Meehotl: 826pB Amlytle MeOJoG; 93609 

AbeqfeName Bemle Q MRI. Faemr Frtnded AaapaJ Ed1.~d~ Nott AndyleNme RewN Q MRL Fuwr EnrameY AmlyuJ E~~O Nole 

Benzeoe ND U 050 1 0310IPo5 03rU1l05 KW00f03498 Brnxene ND U 050 I 03/02/95 03Po2l05 KWO0501506 

Mphyltclt-Bu4'IEOrer ND U 050 1 WAINS 03NIN5 KWG0303498 Mqhyllen-BulylElhu ND U 050 l 03N2005 03Po2/05 KWCA5035o6 

Tdoem ND U 050 1 03NIPo5 03101405 KW00503098 TOhxoe Im U 050 1 03/02105 03102/05 KWCA503505 

EOIyIDenxne ND U 050 1 03A1A05 031D1105 KWOOSOS98 ElpyOxom;e NU U 050 1- 03/O205 03102/05 KW0o503506 

m.o-Xyleon ND U 050 1 03101405 03101Po5 KWCA503I98 m,p-Xykm ND U 050 1 03O2N5 03/Ob05 KWa0503506 

o-XyleM Np U 050 1 03NI105 0310IrU5 KwW50J499 o-%ylene ND U 050 1 03N295 03102rtl5 KWG0503505 

1,2-D;c6lomqAone(BDC) NO U 050 1 03101/05 03N1NS KWG0503398 l,24DichlOmnMne(EDC) ND U 050 1 03/0)A5 03Po2A15 I:W00503506 

ceevel DeEe comea Daa SLmqeuNeew Y.Rec IINU "dymd Note SarrvphNeme Y.Ree IJmib Aydyaml Nas 

DlWoomOoommeihaoe 92 BP119 03rolro5 Aaepuple Dlbro17o11uom113mha0e 106 80419 03N3A5 Auylabie 

TOloene-08 91 83-113 03/OI105 AaeqaMe Tdoe0e48 113 83413 03MN5 Acccplable 

4-Bronwflu0mpev.nc 91 

Cnaamw 

72-114 0310L106 AcaquGle 4-Bromdluumknxmle 104 

Cymearay. 

72-114 03lO2tO5 Accepleple 

00057 ~0 ~ 0 

Fcmbd 03/15/1005 12 37 47 Fmm1A-Otganlc Fqe 1 af 1 FImIeE 03/ISl2005 123749 Fmm1A-ppmu 1 d 1 

oVea10'fiJStlqYmlmT Vvyd fepvSqqeemra pAW117 u~rpPUmlmM Mmp ]yaSeteele~e 86KJ1) 
COLUMBIA ANALYTICAL SERVl'CES, INC COLUMBIA ANALYTICAL SERVIC88. B7C. 

QAMx peWn QA'Ql:IteWn 

CBenC DawrmGrmm.ivc ServittReyves K2501266 Cllan: DansunGmup.Ine Serv4sNeqoen: K2501266 

proje9C 11rd3WIGWSemplln8r10010220U pruJect RedFWiGWSemphu8/2001022013 DateErtrecfed: 03/OU1W5 

Sempk Mh4ii: Wamr Semple Malrit.: Wa2r Due Analysetl: 031012005 

Svrmym Recmery Svmmbry 

VWmOe OrBanie Compmmde 

Malris SpIWNuplleefe MatAr SpUx Summary 

Volad4 Orpmle COmppuuEt 

EaruBOn MeebaE: BPA 3030B UNb: p2RCENf 

AnalyeleMeqmd: 9260B levd+ law SampleBamc: BateLQC UaiD: upJL 

LeD Cotlr. K3501197-001 B®le: NA 

Samok Name Leb CaEe Sarl SL4 Su,3 Erireatim Melhod: EPA 5030B lerel: Lor 

Aeelyut MeMOS: 82008 Eslrn9tlnn I.ct KWG0503391 

RR-8~01 K3501266001 105 113 99 

RH-B-002 K2501266-002 95 91 93 

RN-B-003 K2501266-003 94 91 92 BelehQalS BmcbQCDhLS 

RH-W-0OI K25UlMGqde 93 89 92 KWG0503391-1 KWOINO3391-2 

RH-W-002 K2501266005 95 92 93 Umph BLnle SFDa DuplleMa 84trn SpOm wRx, HIM 

TnpBWlk K2501266406 9e 91 93 AoWyteName R°°It Remlt E[paYW Remlt EspeclN V.Rec I.mur RPD Ilmit 

MeWaGBiank KWG03033914 101 113 99 

BeNmle ND 108 100 LM I08 I00 IW 7i13e 0 30 

MC1hOdB10Nt KWG05036984 92 91 91 Melhyllat-BmylElher ND 996 100 100- 9G I00 98 50-152 1 30 MethodBlank KWGO503506-3 IM 113 109 

Toluene 098 119 100 109 119 IOU 109 T!-132 0 l0 

BmehQC K250119'/-001 101 113 98 

Ethy1lIDN.mm ND 115 I00 115 115 IOU 115 61-130 0 ]0 

BatcbQMS KWG9503391-1 106 113 Ipl 

m.p-Xlleom Nn u7 300 113 223 200 112 M-133 ] 30 BeIrAQCDMS KWG0503391-2 106 113 106 

o-Xyleue 1'ID 112 100 112 112 100 I12 83-128 0 10 

LabComralSample KWG0503391-3 103 111 100 

1,1•DMNpMMenC(FDC) ND 105 Ih0 105 103 100 103 74-123 2 30 LebCentrolSemplC KWGD503498-3 93 97 102 

I.abConhulSanlple KWG0503506-1 I07 lla 103 

Suemgate Eamvery Cbmml Limlo (Y.) • 

Surl = Dlbmmo9uotomeWeoe 8D-119 

Sult ^ To1eved8 83-113 

SurJ = 4-BmmoBOOmbevetrc 71d14 

xe.mlla+.mv.w~ e.nma.m..im...r.a,wel.eA rzwwmwr.e....m.r•Im.m..m.m.u......lorr 

RYi~O~Y NO ~ OwmNl bLItW MOYOaIaYeYbm[YVV~ 

Aae4lhYd,rY ~ Mtl p9NYW W meOtleXUYhtl yrbW f~ (1C 

000J 4 OI:YVO PaeamwabueN~s~p~aemiSemmplWlmwnrah'moeEwu ~ uMxmsYpeWYmmMS~ bwvb~w 

Ftmret 031IS/2005 123754 Fann2A-Oremuc Fye I o1 1 prmled 03115(L005 1137'58 Fam3A-Orgume FeEe I af 1 

~WeW`(1yeYpveNM apSVBSB~ we RRMl19 u

~

o Syv4nR~ 8&e6311 
COLUMBIA ANALYTICAL SRRVICCB, IXG COLIIMBIA ANAL!'TICAL SERVICRB, BIC w 

QA/QC BryM QADQCItepon 

Ciknt: DawmnG:oup.lm 9eevlceAequat: K2501266 CBent: Daww¢Gmv➢.IOc ServleeReqxet: K2501266 

proJM: KWHOIGWSampl:agi7001022013 BaeHarund: 03AUZ005 P:oJ¢t: RedFMIGW3unplmg/2001022013 DenRatncnd: 03/01/1005 

SempleMatrlv Wanc DeteAnWyad: 0317112005 SeepkMabia: WeW DenAVClprcd: 03ro1/1005 

Leb Cmtml SpIQe Sm:mery Le0 Contr915pOn Sammary 

vdatlk oegaole Compmotlt vaaUle Organle COmpoand, 

Eatnclbu MetOOd: EPA 5030B UND: up/L BaruUm MeNoO: EPA 5030B Uoln: u91L 

AnalyNe MeRnd: 8260B Beab: NA Analyda Met6ad: 8260B Bed¢ NA 

LeN: I.ow level: I.aw 

pntraelop8q{: KWG0503391 Latnetlovlqv ICWCO503498 

Leb CooOnl Ssmple Isb Cowrol Smnple 

KW00503191-3 XWG0503498-3 

IabCoetMSpO:c xRr [abCustml8pilu XMee 

AaalyleNwe Rerll 81peelN °ARv Lm:b AndynNann Reodt Bapetfed 'Apec IJm10 

Bevuc 103 l00 103 78-121 Bem=c 891 100 89 78-121 

MnLylten-BurylEWC 969 I00 99 63-I32 MeMylrtn-ButylEOws 908 100 91 83-132 

Toluene l09 100 109 76-122 Tduem 858 100 86 761122 

EtCylbeoxeoe 9.96 100 100 24422 Ethylbcnzeue 881 IUO 88 84-122 

m.P-Xylmcs l98 200 99 83-125 m,P-Xylenm 179 200 90 83-125 

yXylene 983 100 98 81-122 o-Xylaw 891 100 89 83-122 

1.2-1)¢8bmeduin(L+OC) 100 100 100 7F121 l,2-1)leWarcdrene(EDC) 9PL 100 94 94-121 

wwn~.u. u.wr/e.v.w...ouw emoaan.t. 

A..wrwalsmewrm~eebawPwlrsmsa hrsrtue ~.+ane. 

Aw1eC 03)13R005 12 3B 01 Fmm lC-Orymc 

ulvreW'OfeeMa'antIF3N 

w.n. ma.+wie m.mm rl wm..w aw...mm.~ vs 

000G2 

OOOGI 

Wpe 19 1 rimlm 031UllO07 12'3801 Fam1C-Cageuc PeBe 1 of ) 

eVV3uReleno RB~WIf •W.LLYSNIR~ ILCOM 4M>✓ xtev~ FA~WI'! 
COLUMBIA ANALYTICAL 86RVIC8% UVC. 

QA/QCRspmt 

L71em: DRwmuOmup,lvc Bervke RequetC 1C25012fi6 

Projecp RcdIb8GW8empM1n8R001U22013 Date Barecle6: 03)0N1005 

Sempb:Mehia: WRter DRIe Aealyred: 03A212005 

Iab Cootrol Spike BammRry 

VWRtlIe O.gaooe Compaun0e 

Rrtnelbn Me16o0: EPA 5030B DWtR: oyL 

AuR1yW Me1ho0: 8260B BWS: NA 

I.erel: l.av 

Ezlreetloolut: XWG05111306 

Lab Control Sample 

xWCA5035o( I 

LbcaermlSy@e 

Awyte Name Rm6 6apexbtl °bRx uoM 

Beozene 102 100 102 78-121 

Mabylttn-ButylEOmr 942 100 94 63-132 

Toluwe 107 100 107 76-122 

ENy@envmR 107 l00 107 84-122 

m,p•xyleaes 212 200 106 83-II5 

o-Xylene 104 100 100 83-122 

1.2-DICIOOmethave(EDC) 105 100 105 74-121 

Polynuclear Aromatic Hydrocarbons 

F.«M.r 00063 00064 

PMVeI 03/1512005 12 38 07 Fme3C-Orloc Pe¢e 

uvuun~pp~~pv.mMam 97CfaRGams RRW17 
Climt: Dewwo Gmup, loc Serrke Repaal: K2501266 

Pmfeel: BeGIWIGWSampllogR001022013 Dats CallreteG: 02/16/2003 

SempleMeMx; WDer Dale l7eeelved: 07/19R005 

Polfoocleer Armnotic Nydmce:bom 

SwpkNmle: RN-B-0O2 Uaite: uyJl. 

Leb Cotle: K2501266-002 BYfn NA 

ErtruUUnMeWod: EPA3535 LevtL tutv 

AoJy>iB Method: 8270C SP1 

Diluli0o Dau Date Eanctlon 

Nepmnateoe ND U 0022 1 02122A5 03IOIPo5 KWGOw2797 

2-MqbyblaphOWene Np U 0021 1 02/22/05 03101/05 KW00502797 

Aamphthylene ND U 0022 1 02/22/05 03/0U05 KW0n502797 

Acmeph0u:oe ND U 0022 1 0]l27A5 03l01105 KWGO50]797 

Dbevnfulul ND U 0022 I 02r22rU3 03/01A5 KWG0503799 

Fluorem ND U 0022 1 0227N5 03I01I05 KWCO5ozro7 

1 02/21A5 01f011D5 KWG0502797 

AnUUaceoe 'M U 0022 I 02/22/05 03NI105 KWCA502799 

Fluonutlheue ND U 0022 1 02R7A5 03NIA5 KWW5027ff1 

Pyrtlle ND U 0022 1 OIRLLIS 03rDIPo5 KWGOSUL-197 

Benz(e)mlhracene ND U 0022 1 02122105 03NIN5 KWGU501799 

Chryune ND U 0022 1 021E2105 0301105 KWGU302797 

Benzn(b)flumen0lrne ND U 0022 1 02nzb5 03ro1P05 KW00503797 

lkmn(k)IluMUlhme ND U 002 1 02/27Po5 03ro1ro5 xWG050379'I DenaMahyrtne ND U 0021 1 02l12ro5 03ro1105 xw0o50797 

A. 

1 02l22/05 03/01/05 KWGO502/97 

I 0222/05 03N1105 KWCA50279] 

Acaqpable 

AcQpuble 

D6enz(4Wauuuamoe 

9en2qg,h,l)polylene 

ND u 

ND U 

0020 

0020 

Contml llatt 

Samoge4Nwe '/.be IlmlN Aoelyttd 

Fluurene-0l0 74 37-107 031O1/05 

FluaranUrne-d10 77 18-137 03/0I105 

Tapheoyl-0I4 85 I9-153 03/OI/OS 

ND U 0022 1 ON22105 03/0I105 KWCAS6-19'/ 

PII1 U 0022 1 02/12A5 03/01r05 KW00302797 

ContlN Bale 

SurmBneNeme KSa Gmlu Aneln:ell Nn:e 

Fluonx4l0 66 37-107 031O1Po5 Aaepable 

FluoremLened10 75 I8-131 0310IN5 Aocepublc 

Taphmyl-0I4 86 IB-153 0310I105 Acuepleble 

COLUMBG ANALYTICALSBRVICCS, INC. I COLUMBIA ANALYTICAL SBRVICES.INC. 

mlytrcel 

y 

A ltadn Arelyll®1 Rsuln 

Chenl: Dewmnfiroup.lvc ServweRequpl: K2501266 

ProjecO Red}hIlGWS9mpImPJ2001022013 DNeCellxled: 02l162003 

SamVkMalrix: Wuer poleRuehsd: 02119/1005 

Polynuehr AMamelk Rydrwrbom 

Swple Numc RH-B-001 Uoiu: uyL 

I.ab Code: K2501266-001 Baefe: NA 

6arvctioo Melbod: EPA 3535 Loo 

AodyVe Medlad: 8270C SIM 

Dllutko Dete Date fstroetbn 

Andyte Neme ReMN Q MRL PMOr Laracted AnxlSaed Lot N te 

NaphWdeoe Np U 0020 1 0222A15 03NU05 KWC~ u5N797 

2-MahYloephOmlem ND U 0.020 1 0722105 03101Po5 KWGOSOZI9] 

Acenxph0ylene ND U 0020 1 0222/OS 03I01103 KWG0502797 

AacnapNheue ND U 0020 1 0222N5 03NL05 KW00502797 

Dlbemnbuen ND U 0020 l 02122105 03101/OS KW(30501797 

Fluorea ND U 0020 1 0227/OS 03NU05 KWG0503797 

Pheoenlhttm ND U 0020 1 011tyN5 03AI/OS KWCA502197 

AnOuaceoe ND U 0020 1 02R2/05 0310IPo3 KWGp50T/99 

Fluo®nfbeue ND U 0020 1 02f22/05 03101/U5 KWCA50sro7 

Pyrcne ND U 0020 1 0LE2105 0361rD5 KW450502797 

l3enz(a)enlMaem ND U 0020 1 02112N5 03/01N5 KWG0502TY! 

Cht3sene 

_ 

ND U 0020 1 0222AI5 03/01105 KWGO50279] 

Be[ua(b)fluolanthene ND U 0020 1 02rz2105 03101ro5 KWCO502797 

5wva(kl0umevllleoa ND u 0020 1 02rz7105 03roU05 KWOOSOYI97 

Beva(a)py:eoe ND G 0.030 1 o222J05 03roD05 KWCA50279] 

C.- Ce~ 

P+ullod 03/IW2003 131216 FamIA-pgvoc Poee I of 1 PnmA 03110/I00S 13.1219 PonnIA-Otymue ABC 1 af f 

obldm'uv~M`+emleuq Mnst SeM~

xSeva Per6J15 uWeulorstl W46113 
COLUMBIA ANALYTICAL SERYIC6S. INC CpLUMBLI ANALYTICAL SERVICES, INC .. 

Am1YV®I Reoilu AmlYarel Rudls 

Clleat: Dawwn OSwp, Inc SnvkeRequep: K2501266 Client Dawmo Group, ine Servirc Relryeat: K2501266 

Pmject RadH01GWSemp11nS2ro10220t3 DneCWleeted: 01/162005 PSyket R<d11dIGWSempbng/100102D013 DateCalleaed: 02/17l2005 

Suepk Malriz: Wner Dme Recnred: 01/19/2005 Semple MarriR: Waler Date Raelved: 02/1912005 

Pd2naeWr Aromatie Hydroeerbanr Polynuekar AramaHr Hydrvurbaor 

SempleNmc RN-5-003 Unitr: ug/L SmnpleNemr. RH-W-0OI UWh: ug/L 

Lnb Codr- K25D1266-003 Bedr: NA Lab C.ade: K2501266-W4 Bmir: NA 

EMmim Metbod: P.PA 3535 - 1<vN: L. Ralreetlan Mel6ad: HPA 3535 Lertl: LuW 

Anrtyur MeOOd: 8270C SDrf AnalyM Methad: 8270C SOd 

DOmba Dare Du1e Eatnctlov Dllutlov Dme DRM Raeufioo 

2-MeNyllupllUlelrae ND U 0021 1 ON22r05 03ADI105 KWW50Y/97 

Aceaapl501ylene ND U 0021 1 02(22N5 03101/05 KWW502797 

AcrrephNrne I-ID U 0021 1 o222ro5 03ro1ro5 KWW5itt797 

D,benanlu5ml ND U D021 l 0322105 03/OlA5 KWW502797 

Fluorcne ND U 0021 1 0222/05 03101105 KW14)50279'! 

Pbdunlhrene ND U 0021 1 0222b5 03NIN5 KWW50279] 

AMhnaae ND U 0021 L 02/22/05 03AIPoS KWW5027Y! 

Flvmamhene ND U 0021 1 022L05 03/01105 KWW5079'! 

PyRTU ND U 11021 I 02l12115 03NIPo5 KWW50YlY1 

Benz(a)amhmcene ND U 0021 1 02/2105 03/DI/05 KWCO502797 

Chrysrne ND U 0021 1 02/2].tl5 0310IN5 KWW502797 

Bema(k)tluulanNeot ND U 0021 1 022btl5 0310IAS KWWSO799 

Bwa(apryrtne ND U 0.011 1 0222A5 03101105 1cWW502v/ 

Ivdeno(1,2,3-cdWj5eae ND U 0011 1 0222105 03NIN5 KWW502797 

DLeoe(eJμimhSacme ND U 0021 1 02!22/05 03RIIN5 KW00502791 

BenmfaAlloervleue ND U 0021 1 03ldLU5 03AlU05 KWW503797 

Cmlml Dele 

SLrnqemNrm[ XRer ulmlb AaVyrpd Nme 

Fluortned10 65 37-107 03N1/05 Aorepeble 

Fluolwhece-010 70 18-137 0310Iro5 Aaoeptable 

Tmplqnyl-014 83 18-153 03/OIPoS At%qNeble 

Nepbthalmr 0.23 0020 I 02/22A5 03031/05 KWW502797 

bMatbylnophlbalene 414 0020 1 02/22105 03NLU5 KWWSOn97 

Aeamphthylenc ND u 0010 1 02ltL05 03ro1/OS KWW5on97 

DBSeOaMuran 0.13 00E0 1 0221115 03/01N5 KW0p502797 

Flumene 0.053 00215 1 0222N5 03NIN5 KWCA502799 

Pbmuatbreoe 0.12 0020 1 OL22A5 03A1IN5 KWW503797 

AnllvaWb ND U 0020 1 0222N5 03/01/05 KWW502797 

Flaoraa0ene 0.015 0020 1 02122Po5 0310I105 KWW502797 

Pyrear 0.056 0020 1 0222r05 03/OIPoS KW00501797 

Beor;a)entbrarene ND U 0020 1 0222105 03/01N5 KWW501797 

Cbryame 0.020 0020 1 02,72r05 03ro1/05 KWW502197 

Beom(b)Ilmranlhene OA25 0020 1 0222105 03d01/05 KWU0902797 

Beum(k)fluawMn< ND U 0020 1 0222/05 03101105 KWW5an97 

Bemm(a)p35mlr 0.022 0030 1 02/22U5 03/01105 KWW502757 

ND U 0.020 1 OU12A15 031OIA5 KWGOSD3797 

ND U 0020 1 021L7N5 03iDIN5 KWW502799 

Cmorul Oafe 

SurtqUeNRme Y.&c IJmltr An9lyeed Nole 

FlunreaC-010 73 37-107 03ro1d15 Axeqabl[ 

PlumeOWene-010 72 18-137 03101105 Aaepuble 

TmpbE0yld14 88 18-153 031110)5 Aweplable 

0006-4 0006b 

Pnntd 031102005 131232 FonvlA-QBwc Poge 1 of 1 Pnnled 03/102005 131226 FonnlA-Ordenw Pe8[ 1 efI 

uW~`ONaN'fam ~mT .15eyV ~ NR4315 SW9tlRfeve R110115 
ING CObUMB1A ANALVTICAL SERVICPS. ffiC. ~ 

Au159rN RaW4 

Servlce Rcqueq: K2501266 CIk.MC Dauson Gruup Inc Servke Reqoesp K2501266 

DaSeCoDee4d: OL17/2005 Peojeel: PWHdIGWSampbng/20010220U DateCaDrcted: NA 

DNe Recdved: 0211912005 Sample Metelx: Waler Date Rteepved: NA 

Palyvurlur AumYic flydrocerbooe 

Ue&e ug/L SampEe Name: MeOwd Blenk Uudc u8/L 

BWr: NA IJbCode: KWG0502797-3 DaeD: NA 

LtvO: Imv EteucOOUMeWod: EPA3535 Lerel: Low 

Anaryrir MethoO: 8170C SD4 

AmlSUCd Reml4 

Clfut: Dawsun Gmup, lm 

PrnjeeC Ked HYI GW SemP194/2001022 013 

SamVk Matrix: Wmer 

Polyuuekar AeomaUe Bytluevbom 

Sample Namr. RN-W-002 

IsbCode: K2501266-0OS 

Hawellon Method: P-PA 3515 

AnalSe4 MnLOd: 8270C SDd 

Dimeou Dm Date Emaceim 

AnNyfe N. Rmlt Q MRL Fert9r Krtraeled Anelyud Lol Nme 

Napbthakue 021 OONI 1 0712L05 03NI105 KW00503797 

2-MedhylnephthNea 0.037 0020 1 oY22.05 03rolros KWCASOD99 

AuImplLLhykne ND U 0020 1 0]l22Po5 0310IADS KWCA50279] 

AnwphWene 0.05e 0020 1 02l12/O3 03N1/05 KWG0502797 

DlbeeruPoun 0.11 0020 1 OL22AS 03A7105 KW00501797 

Muortne 0.043 0020 1 02/1]Po5 03N1/05 KWG0502]9T 

PFenanWreoe 0.0R 0020 1 02/22/05 0310Iro5 KWG0502771 

Anthnaue ND U 0010 1 02/23/05 03/01/OS KWCASOTl9] 

plmorao0lene 0.031 0020 1 02I22/OS 03N1/05 KWGO50l741 

PSrene 0.039 0,020 1 02R2/05 03/01/05 KW00502M 

Bcnz(aqanfhuceva ND U 0020 1 0227A5 03101/05 KWG0502797 

Chrywle ND U 0.020 1 02/22Po5 03RI/05 KWCO502797 

Benm(b~uanNBem ND U 0.020 1 OYt2q3 07PoIN5 KWGp303]9] 

Benwlkuluolanthem ND U 0020 1 OL2]!O3 03/OIA1S KWG0502797 

Bana(n)pyrene ND U 0.020 1 02/22pS 03/OINS KWOOSO2N! 

IMmn(1,2,3W)pyrcne ND U 0020 1 0222105 03/01/05 KWGOSOYIO! 

Dbwp,hpnihrettne ND U 0020 1 02l22Po5 03101AS KWG05029p1 

Devnfgh,l)petylea fm U 0020 1 0122N5 03101/05 KW0050274I 

Cm4o1 Dale 

SumyW Nsmr V.Rer IJmib Anyyzed No4 

Fluortve410 65 77-107 03701Po5 Aecep401e 

Fluonn111med10 36 18-137 031DIM135 AacpDbk 

TetphenyldlC 51 18.153 03A31/05 Accep4hle 

DDuSkn Date Dale BatrMfon 

AualyteNanu: Re4Jt Q MRL FrCtOr Ee1rMIW AnllyKd Lar Nofe 

Naphthalede ND U 0020 1 OL27105 02/28/05 KWCO502397 

2-MtlhSlouph0udene ND U 0010 1 02f121p5 02418J05 KWG0502799 

Attmphthylene ND U 0020 1 02/22105 02R8N5 KWCA50279'1 

Amllephthene ND U 0020 l 02122/O3 02(18Po5 KWQ0502799 

Dlbeuao8uan ND U 0020 I 02/22105 ON18/05 KWGa502197 

FIUOrtne ND U 0020 l 02I22AD5 0L2&OS KW00501]9'i 

PhenelW:ene ND U 00]A 1 07!l.7A15 02/28d)5 KWG0502797 

An5lwcme ND U 0020 I 02!l105 02f28N5 KW430502191 

Fluwuuhene ND U 0020 1 02l22105 0228A15 KW305o2797 

py'leuo ND U 0020 1 02122Po5 02138N5 KWCASOnYI 

HeOZ(a)aolMazne ND U 0020 1 02/22105 02/28NS KWCA502797 

Chrysene ND U 0020 1 02/22q5 02/2&95 KWUO5tR197 

Delvo(b)flvmeNhue ND U 0020 1 02RLD5 02/28N5 KW00503297 

Dmm(kplun4n0iene ND U 0020 1 02122.D5 02/28N5 KW00502797 

Dmlm(e)Pytme ND U 0020 1 07R2N5 02/28N5 KWG0502797 

[odeuo(1,2,3-rd)pyleua ND U 0020 1 02122105 02J28N5 KWGO.Y12797 

D1eoz(a,h)mnhmmle ND U 0020 1 0222105 0228/OS KWCAN¢l9'I 

DenvKg,h,l),layleue ND U 0020 1 0222105 02(28105 KWCA50219) 

Cuntml Date 

Smrta<ate M. XHrc IIm14 Analynd No4 

FlupteueElO 63 77-107 07/211VDS Acarylnble 

Flhounthene-010 73 18-137 0211105 Acccp461c 

TO11henSl-dla 83 1&153 0228115 Acceplabie 

0^OGu 

PnntW 03/1OR005 13 12 29 Form1A-0gemc Pege I of 1 

LL~nNanlmM MuW rY3aRef YRKRI5 

90070 

PmlleB 03/IQQOOS 13 12 32 FomllA-oaeeou Pepe 1 of 1 

a~am'FKYnWM1.~ImT Mwpl 4WWIMrmm 0.n.6115 
Ea/netbv Llethvd: EPA 3535 

Avalyrir Method: 8270C SB.i 

SAmole Name tAbCode vrl &r-2 ~4p}r 

R31-D-0OI K2501266-001 74 -17 85 

RH-B-1102 K2501366-002 66 75 86 

RH-0a03 K2301266-0O1 63 z0 83 

RH-W-001 K2501266-006 73 72 88 

RH-W-002 K2301266-0D3 65 56 51 

MelbudBlYNc KW00502797-3 63 73 83 

LebCuvWlBampk KW00502797-1 69 'u 94 

Dupbwte Lab Catuzol Sumple KWG0502797-2 '10 73 73 

UWD: PBRCBNF 

1<vel: Law 

CDLUMBIA ANALYTICAL SERVICES, INC. COLUMBIA AWAI.VTICAL SERVICES, DiC r 

QAIQC 8rym QAQC Rcpmt 

Cbm1: Dawmv Gmup, Iuc 

PrvjerL• RrdHdIGWSrmpltngf2001022013 

SsmPkMrtrir: Wmer 

SurmSate Recmery Summap 

Polymrlrer Aromatk Hydrorsr0utm 

SeMttReqvM: K2301266 CUmL• Dawsov Gaotq, Inc 

PrvfeM: Red1h11GWSempbug/2001072013 

SwpkMtlru: Waler 

Lab Canrrul5pike/DOpbrale IaU Cmttol Sptbe Svmmery 

POlyvoekar AtumaDr Rydtmutbmr 

8erv4e Requmt: K2501266 

Dale Ertncmd: ON27n005 

DmAValyttd: 03ADI/2005 

Eitraetluv MethOd: FPA 3535 

AoalyeD MCbod: 8270C SUN 

Avdyle Name 

Naplplukne 

2-Mabyloapbthsleve 

Acenfpblhylmm 

Amu@h0e:oe 

Dtbemy6Yab 

F10orM< 

PheOamluwrc 

FluormWUe 

Pyrcve 

Ben2(9)anWmmve 

Den>ab)BmtauuY:m 

Demn(kyhmao0¢ne 

Denrq6),ymm 

Izukm(1,2,Jd)pymnc 

Dibavz(4h1HV0uuame 

B--(8.h.t)pmYi= 

Uvim: ug/L 

Badr: NA 

Levd: L. 

EvrvehovLa: KWG0502797 

]ab Cvmzol Semple Dupbute I.eb Contml Sumple 

KWG0502797-1 BWG0502797-2 

IebCmtmlSpiYe DupllmroLbCoattalSpltr y~a RI'D 

RmN Bapected 't4Ba Remll erpecmd %4Ra Ilmm RPD Lmu 

224 250 90 227 250 91 42408 1 30 

210 2 50 84 216 250 87 29-121 3 30 

233 250 93 2 33 250 93 0-112 0 30 

241 2 50 96 242 230 97 42-115 1 30 

234 2 50 94 239 250 93 34-121 2 30 

239 250 96 243 250 97 47-117 2 30 

1 36 250 94 236 250 94 50-I IS 0 30 

241 2 50 96 241 250 96 54-115 0 30 

290 250 112 269 250 108 50-127 4 30 

246 250 99 247 250 99 45-133 0 30 

233 250 93 235 250 94 44-127 1 30 

247 2 50 99 249 230 99 16-137 0 30 

2 53 250 102 255 250 102 47-127 0 30 

254 250 102 252 250 101 30-144 1 30 

238 2 50 95 239 250 95 36-136 0 30 

229 250 92 230 250 92 20-150 0 30 

222 250 89 226 250 90 50-127 2 30 

227 250 91 231 250 92 56-119 1 30 

SLmBam Bamtsry Cmntl Lmib ( A) 

Surl - Fluo2ne-010 37-107 

SuYt = FluonvDmoedt0 18-137 

Sur3 ' TetpLevyl-d14 18-153 

x.w mr.4 w. em+rl md...m.m9. mwx mmc 

RaNU:l1m.4.m. Pm M Yeh. W®udNmLYm.mre.lY 

00071 

Pnntt1 03/101i0D5 13 12 39 Fmm2A-08wc P.S. 1 ot 1 

. ~ a.YVap+mv.mzm rur~r+mr artrllf 

n.mn w.r w m emr rl eaae..m wa. mma wn. 

Pma ~ rsmavN WV+r~~ iQm®UVOI o4meolbuemMwmt.abnMwbinbnMerA YmmlaemYeG 

00072 

PrBe 1 of1 

swnanem~ xaa611z 

Ptmmd 031I0R005 13.1243 

-~m 

F. 3C -Otgmm 
NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Aooendix B 

~ 

~ 

_" MIj:U_- 

Monitoring Well Sampling Forms 

[200I 022. 013 Red Hill IQ05 GW] Dawson Group, Inc. 
\` 

( - 

NAVFAC PACIFIC Red Hill IQ05 GW 

Contract No.: N62742-01-D-1806, CTO 0013 Appendix A 

This page intentionally left blank 

[2001 022.013 Red Hill 1Q05 GW] Dawson Group, I.nc. 
r J 

Dawson 

Group, Inc. 

MON1TOIt11dG 11NELL FIELD SAMPLIPIG LOG 

PROJECT Groundwater Samphng, Red Hdl Fuel Storage Facdity, Hawau - duwngmdlent of USTs • 

CONTRACTNO N62742-01-D-1806,CT00013 JOBNO2001_022013 

DATE 2/172005 TIME 935 CLIMATICCONDITIONSovercast 

PERSONNEL 1 Bofr, H Kerr 

WELL INFORMATlON PURGE VOLUME EQUIPMENT 

Well NemeMumlxr M W-V 1 D Ve =(def x(h) x 0.041 Instrumenqs) YSI 

Well Locetion • 

Casing Diemeter(inches) . 1 ~ (de ) Vdume of water In Ca6brabon Time 7:30 

Total Wdl Depth (feet) 100 rasing (gallons) 0.7118 (Ve) CahbreUon Result / Comments _ 

Intlial Deplh Io Water (feet) 8264 OK 

DepN N Product (feet) NMP Minimum Pmge

~ 

2:135' 

Helght of Water Column (teet) 1736 (h) Volume (gallonc) ~ . 

PURGE LOG Measurements of temperature, pFl, aperfic conducoMy, furWdrty, dissolved oxygen, and redox wsl/ be rnlMCted(n aally, aflerevery urell 

volumne removed, and at tlre and 

METHOD OF REMOVAL DetliCeted Bdller PUMPINO RATE N/A 

DATE TIME 

CUMULATIYE 

GALLONS 

REMOVED 

1EMP. 

PH 

SP.COND. TURBIDITy dSSOLVEDOr REDOX 

(°C) ( US/Cm ) ( NTU ) ( m L ) ( RIV ) 

2/17/2005 9:35 0 24.0 9.33 1.477 2.68 9.42 37.1 

2/17/2005 9:50 0.25 22.32 9.18 1.559 NM 11.8 25.9 

2/1712005 10:14 0.5 23.6 9.4 1.499 53.2 11.35 9 

2/1712005 10:26 0.75 23.3 9.39 1.523 96.4 11.9 4.6 

SAMPLE INFORMATION 

SAMPLENATHDRAWALMETHOD Bader Dedicated SAMPLED BY JB, HK 

SAMPLEID P,OCOR011 IIMECOLLECTED DATECOLLECTED NOTES 

RH-W-OOI P 10:42 1 2/17/2005 

RH-W-002 QC 12:35 1 2117/2005 

Naes P= pnmarysampJa QC = quNirycomml (duplr,ete) semple. QA = quahty assurense (rnplmare) sempb 

APPEARANCE OF SAMPLE Color yellow-belge Temp 2285 DO 7 64 mglL 

TurbidM1y pH 811 Redox -1174mV 

Sedlment shght Sp Cond 1 596 

LAB ANALYSIS PARAMETERS (1)BTEX,MIBE,I,2-DCA-EPAMethud8260B (2)EDB-EPADWMethod5041 

(3) TPH as euobne - EPA Melhod 8015B (4) TPH u d,esel - EPA Medwd 8015B 

(5)PAHs-EPAMethod8270CorSIM-PAHs (6)Totallead-EPAMahod6020 

NUMBER 8 TYPE OF SAMPLE CONTAINERS USED (include preseroatrves, rf any) (1) 3 40-mL VOAs wnh HCL 

(2)3 40-mLVOASwnhsodmmrhwsulrate (3)3 40-mLVOAswnhHCL (4)2 500-mLGlessAmberwuhHCL 

(5) 2 1-L Glass Amber (none) (6) 1 500-mL alesnc wnh HNO3 

DECONTAMINATION PROCEDURES see PACDIV IRP procedures 

SAMPLES DELIVERED TO T. Sober, CAS _ DATE 2/18I2005 

TRANSPORTER FedEx- TIME 

13 1Q05 GW Sampling Form.xls 
111_"~ 

Dawson 

Group, Inc.: 

SURFACE dVATER FIELD SAMPLIOdG LOG 

PROJECT Groundweter Samphng, Red Hdl Fuel Storage Faclhty, Hawan - Potable Weter lnfiltrauon Tunnel • 

CONTRACTNO N62742-01-0.1806,CT00013 JOBNO 2001_022013 

DATE 2/1612005 TIME 927 CLIMATICCONDITIONS sunny 

PERSONNEL J Borr, H Kert 

WELL INFORMATION URGE VOLUME EQUIPMENT 

Well Name/Number Sti111nR Besin Ve =(de)a x(h) x 0 04 InsWment(s) Soltnst Interface Pmbe 

Well Locabon • 

CasingDiameler(tnchea)4, I CalibretanTime NA ~,~~,cNA `jp~';j(de) Vdumeofwaterl 

Tofal Well DaDln(feeq ;. ~ NA; •-,;;i;i casmg (gello NA (Ve) Cehbratron Result / Comments NA InNal Deplh to Water (feel) 86 48c — Depm ro Product (feet) NA Helghtof Wster Column (feet) NA (h) Imum Purge Vdame (gallcns) • ~ ~' ~' 

PURGE LOG Measuremenfs of tempereAura, pH, speafic conducawry, mrddry, ddsoNed oxygen, and redaz wrll be ccllecfedimhalty, aRarevery well 

rolumne rennrved, antl at Me end METHOD OF REMOVAL New, dlsposable, pDlyethylene bailer PUMPING RATE NA 

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SAMPLE INFORMATI'ON 

SAMPLE WITHDRAWAL METHOD New, dtsposable, polyethylene bader SAMPLED BY JB, HK 

SAMPLEID P,QC,ORQA TIMECOI.LECTED DATECOLLECTED NOTEB 

RH-B-001 P 9:34 2/16/2005 Pumps were offline 24 holus prior to sample 

RH-B-002 QC 11:15 2/16/2005 Pumps were offline 24 hours prior to sample 

RH-B-003 P 12:41 2/16/2005 1 Pum s online for 15-20 minutes (tumed on at 12:08 

Nmes Y= pnmaa sampra oc = 4uelaymnea (auprere) samqa. a4 = 4us(iryassurams Orpxcefe) semple 

APPEARANCE OF SAMPLE Cdor Cleer Temp NA DO 

Turbldity NA pH NA Redox 

Sedlment None Sp Cond NA 

LAB ANALYSIS PARAMETERS. (1)BTEX,MtBE,1,2-DCA-EPAMedrod8260B (2)EDB-EPADWMetAod5041 

(3) TPH u 8arohne - EPA Methad 8015B (4) TPH ss dteul - EPA Met6od 8015B 

(5)PAHs-EPAMethod8270CorSIM-PAHs (6)Tmallead-EPAMeIhod6020 

NUMBER & TYPE OF SAMPLE CONTAINERS USED (InClude preservahves, rf any) (1) 3 40-mL VOAswnh HCL 

(2) 3 40-mL VOAS wM sodmm thwsdfete (3) 3 40-mL VOAs wrlh HCL (4) 2 500-mL Glass Amber wrth HCL 

(5) 2 1-L Glass Amba (oone) (6) 1 500-mL nlssln; wnh HNO3 

DECONTAMINATION PROCEDURES 8ee PACDIV IRP PrOcedures 

SAMPLES DELIVERED TO T. Sober, Columbia Analytical Services DATE 211812005 

TRANSPORTERFed6r- TIME 

13 1Q05 GW SampHng Form xls