# Patent

## Title
Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides

## Abstract

Fungicidal mixtures, comprising as active components

    1) at least one 1-methylpyrazol-4-ylcarboxanilides of the formula I






    
    
        where X=O or S, R1=C1-C4-alkyl or C1-C4-haloalkyl, R2=hydrogen or halogen, R3, R4 and R5=independently of one another cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio;
        and
    
    
    2) at least one active compound II, selected from the active compound groups A) to F):
    
        A) azoles;
        B) strobilurins;
        C) carboxamides;
        D) heterocyclic compounds;
        E) carbamates;
        F) other fungicides;

in a synergistically effective amount, methods for controlling harmful fungi using mixtures of at least one compound I and at least one active compound II and the use of the compound(s) I with active compounds II for preparing such mixtures, and also compositions and seed comprising such mixtures.

## Background
This application is a National Stage application of International Application No. PCT/EP2006/064907, filed Aug. 1, 2006, the entire contents of which is hereby incorporated herein by reference. This application also claims the benefit under 35 U.S.C. §119 of German Patent Application No. 102005037677.0, filed Aug. 5, 2005 and European Patent Application No. 06101198.7, filed Feb. 2, 2006.
The present invention relates to fungicidal mixtures comprising, as active components,

    1) at least one 1-methylpyrazol-4-ylcarboxanilides of the formula I






    
    
        in which the substituents are as defined below:
        X is oxygen or sulfur;
        R1 is C1-C4-alkyl or C1-C4-haloalkyl;
        R2 is hydrogen or halogen;
        R3, R4 and R5 independently of one another are cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio;

and

    
    
    2) at least one active compound II selected from the active compound groups A) to F):
    
        A) azoles selected from the group consisting of bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexazole;
        B) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, methyl (2-chloro-5-[1-(3-methyl-benzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate and methyl 2-(ortho-(2,5-dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate;
        C) carboxamides selected from the group consisting of carboxin, benalaxyl; boscalid, fenhexamid, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil,
        
            3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide, dimethomorph, flumorph, flumetover, fluopicolide (picobenzamid), zoxamide, carpropamid, diclocymet, mandipropamid, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propionate, compounds of the formula III
        
        
    
    






    
    
        
        
            in which R4 is methyl or ethyl,
            N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide, N-(3′,4′-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-ylcarboxamide and N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide;
        
        
        D) heterocyclic compounds selected from the group consisting of fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, procymidone, vinclozolin, famoxadone, fenamidone, octhilinone, probenazole, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine,
        
            anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, the compound of the formula IV (2-butoxy-6-iodo-3-propylchromen-4-one)
        
        
    
    






    
    
        
        
            acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quinoxyfen and
            N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide of the formula V
        
        
    
    






    
    
        E) carbamates selected from the group consisting of mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb, 4-fluorophenyl N-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)carbamate, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propanoate of the formula VI
    
    






    
    
        
        
            and carbamate oxime ethers of the formula VII
        
        
    
    






    
    
        
        
            in which Z is N or CH;
        
        
        F) other fungicides selected from the group consisting of guanidine, dodine, iminoctadine, guazatine, antibiotics: kasugamycin, streptomycin, polyoxin, validamycin A, nitrophenyl derivatives: binapacryl, dinocap, dinobuton, sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane, organometallic compounds: fentin salts such as fentin acetate, organophosphorus compounds: edifenphos, iprobenfos, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl,
        
            organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate-methyl, tolylfluanid,
            inorganic active compounds: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenone and spiroxamine;

in a synergistically effective amount.

        
        
    
    


Moreover, the invention relates to a method for controlling harmful fungi using a mixture of at least one compound I and at least one of the active compounds II, to the use of the compound(s) I with active compound(s) II for preparing such mixtures, and also to compositions and seed comprising such mixtures.
The 1-methylpyrazol-4-ylcarboxanilides of the formula I, referred to above as component 1), their preparation and their action against harmful fungi are known from the literature (cf., for example, EP-A 545 099, EP-A 589 301 and WO 99/09013), or they can be prepared in the manner described therein.
The compounds I in which X is sulfur can be prepared, for example, by sulfurizing the corresponding compounds I in which X is oxygen (cf. e.g. D. Petrova & K. Jakobcic, Croat. Chem. Acta 48, 49 (1976) and WO 01/42223).
However, the known 1-methylpyrazol-4-ylcarboxanilides of the formula I are, in particular at low application rates, not entirely satisfactory.
The active compounds II mentioned above as component 2, their preparation and their action against harmful fungi are generally known (cf., for example, http://www.hclrss.demon.co.uk/index.html); they are commercially available.

    Benalaxyl, methyl N-(phenylacetyl)-N-(2,6-xylyl)-DL-alaninate (DE 29 03 612);
    metalaxyl, methyl N-(methoxyacetyl)-N-(2,6-xylyl)-DL-alaninate (GB 15 00 581);
    ofurace, (RS)-α-(2-chloro-N-2,6-xylylacetamido)-γ-butyrolactone [CAS RN 58810-48-3];
    oxadixyl; N-(2,6-dimethylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)acetamide (GB 20 58 059);
    aldimorph, “4-alkyl-2,5(or 2,6)-dimethylmorpholine”, comprising 65-75% of 2,6-dimethylmorpholine and 25-35% of 2,5-dimethylmorpholine, comprising more than 85% of 4-dodecyl-2,5(or 2,6)-dimethylmorpholine, where “alkyl” also includes octyl, decyl, tetradecyl and hexadecyl, with a cis/trans ratio of 1:1 [CAS RN 91315-15-0];
    dodine, 1-dodecylguanidinium acetate (Plant Dis. Rep., Vol. 41, p. 1029 (1957));
    dodemorph, 4-cyclododecyl-2,6-dimethylmorpholine (DE-A 1198125);
    fenpropimorph, (RS)-cis-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethyl-morpholine (DE-A 27 52 096);
    fenpropidin, (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine (DE-A 27 52 096);
    guazatine, mixture of the reaction products from the amidation of technical grade iminodi(octamethylene)diamine, comprising various guanidines and polyamines [CAS RN 108173-90-6];
    iminoctadine, 1,1′-iminodi(octamethylene)diguanidine (Congr. Plant Pathol., 1., p. 27 (1968);
    spiroxamine, (8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-yl)diethylamine (EP-A 281 842);
    tridemorph, 2,6-dimethyl-4-tridecylmorpholine (DE-A 11 64 152);
    pyrimethanil, 4,6-dimethylpyrimidin-2-ylphenylamine (DD-A 151 404);
    mepanipyrim, (4-methyl-6-prop-1-ynylpyrimidin-2-yl)phenylamine (EP-A 224 339);
    cyprodinil, (4-cyclopropyl-6-methylpyrimidin-2-yl)phenylamine (EP-A 310 550);
    cycloheximide, 4-{(2R)-2-[(1S,3S,5S)-3,5-dimethyl-2-oxocyclohexyl]-2-hydroxyethyl}piperidine-2,6-dione [CAS RN 66-81-9];
    griseofulvin, 7-chloro-2′,4,6-trimethoxy-6′-methylspiro[benzofuran-2(3H), 1′-cyclohex-2′-ene]-3,4′-dione [CAS RN 126-07-8];
    kasugamycin, 3-O-[2-amino-4-[(carboxyiminomethyl)amino]-2,3,4,6-tetradeoxy-α-D-arabino-hexopyranosyl]-D-chiro-inositol [CAS RN 6980-18-3];
    natamycin, (8E,14E,16E,18E,20E)-(1R,3S,5R,7R,12R,22R,24S,25R,26S)-22-(3-amino-3,6-dideoxy-β-D-mannopyranosyloxy)-1,3,26-trihydroxy-12-methyl-10-oxo-6,11,28-trioxatricyclo[22.3.1.05,7]octacosa-8,14,16,18,20-pentaene-25-carboxylic acid [CAS RN 7681-93-8];
    polyoxin, 5-(2-amino-5-O-carbamoyl-2-deoxy-L-xylonamido)-1-(5-carboxy-1,2,3,4-tetrahydro-2,4-dioxopyrimidin-1-yl)-1,5-dideoxy-β-D-allofuranuronic acid [CAS RN 22976-86-9];
    streptomycin, 1,1′-{1-L-(1,3,5/2,4,6)-4-[5-deoxy-2-O-(2-deoxy-2-methylamino-α-L-glucopyranosyl)-3-C-formyl-α-L-lyxofuranosyloxy]-2,5,6-trihydroxycyclohex-1,3-ylene}diguanidine (J. Am. Chem. Soc. Vol. 69, p. 1234 (1947));
    bitertanol, β-([1,1′-biphenyl]-4-yloxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (DE-A 23 24 020);
    bromuconazole, 1-[[4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl]methyl]-1H-1,2,4-triazole (Proc. 1990 Br. Crop. Prot. Conf.—Pests Dis. Vol. 1, p. 459);
    cyproconazole, 2-(4-chlorophenyl)-3-cyclopropyl-1-[1,2,4]triazol-1-ylbutan-2-ol (U.S. Pat. No. 4,664,696);
    difenoconazole, 1-{2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-[1,3]dioxolan-2-ylmethyl}-1H-[1,2,4]triazole (GB-A 2 098 607);
    diniconazole, (βE)-β-[(2,4-dichlorophenyl)methylene]-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (Noyaku Kagaku, 1983, Vol. 8, p. 575);
    enilconazole (imazalil), 1-[2-(2,4-dichlorophenyl)-2-(2-propenyloxy)ethyl]-1H-imidazole (Fruits, 1973, Vol. 28, p. 545);
    epoxiconazole, (2RS,3SR)-1-[3-(2-chlorophenyl)-2,3-epoxy-2-(4-fluorophenyl)propyl]-1H-1,2,4-triazole (EP-A 196 038);
    fenbuconazole, α-[2-(4-chlorophenyl)ethyl]-α-phenyl-1H-1,2,4-triazole-1-propanenitrile (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 33);
    fluquinconazole, 3-(2,4-dichlorophenyl)-6-fluoro-2-[1,2,4]-triazol-1-yl-3H-quinazolin-4-one (Proc. Br. Crop Prot. Conf.—Pests Dis., 5-3, 411 (1992));
    flusilazole, 1-{[bis(4-fluorophenyl)methylsilanyl]methyl}-1H-[1,2,4]triazole (Proc. Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 413 (1984));
    flutriafol, α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol (EP-A 15 756);
    hexaconazole, 2-(2,4-dichlorophenyl)-1-[1,2,4]triazol-1-ylhexan-2-ol (CAS RN 79983-71-4);
    ipconazole, 2-[(4-chlorophenyl)methyl]-5-(1-methylethyl)-1-(1H-1,2,4-triazol-1-yl-methyl)cyclopentanol (EP-A 267 778),
    metconazole, 5-(4-chlorobenzyl)-2,2-dimethyl-1-[1,2,4]triazol-1-ylmethylcyclopentanol (GB 857 383);
    myclobutanil, 2-(4-chlorophenyl)-2-[1,2,4]triazol-1-ylmethylpentanenitrile (CAS RN 88671-89-0);
    penconazole, 1-[2-(2,4-dichlorophenyl)pentyl]-1H-[1,2,4]triazole (Pesticide Manual, 12th Ed. 2000, p. 712);
    propiconazole, 1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole (BE 835 579);
    prochloraz, N-(propyl-[2-(2,4,6-trichlorophenoxy)ethyl])imidazole-1-carboxamide (U.S. Pat. No. 3,991,071);
    prothioconazole, 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro[1,2,4]triazole-3-thione (WO 96/16048);
    simeconazole, α-(4-fluorophenyl)-α-[(trimethylsilyl)methyl]-1H-1,2,4-triazole-1-ethanol [CAS RN 149508-90-7],
    tebuconazole, 1-(4-chlorophenyl)-4,4-dimethyl-3-[1,2,4]triazol-1-ylmethylpentan-3-ol (EP-A 40 345);
    tetraconazole, 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]-1H-1,2,4-triazole (EP-A 234 242);
    triadimefon, 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone (BE 793 867);
    triadimenol, β-(4-chlorophenoxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (DE-A 23 24 010);
    triflumizol, (4-chloro-2-trifluoromethylphenyl)-(2-propoxy-1-[1,2,4]triazol-1-ylethylidene)-amine (JP-A 79/1.19 462);
    triticonazole, (5E)-5-[(4-chlorophenyl)methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (FR 26 41 277);
    iprodione, N-isopropyl-3-(3,5-dichlorophenyl)-2,4-dioxoimidazolidine-1-carboxamide (GB 13 12 536);
    myclozolin, (RS)-3-(3,5-dichlorophenyl)-5-methoxymethyl-5-methyl-1,3-oxazolidine-2,4-dione [CAS RN 54864-61-8];
    procymidone, N-(3,5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide (U.S. Pat. No. 3,903,090);
    vinclozolin, 3-(3,5-dichlorophenyl)-5-methyl-5-vinyloxazolidine-2,4-dione (DE-A 22 07 576);
    ferbam, iron(3+) dimethyldithiocarbamate (U.S. Pat. No. 1,972,961);
    nabam, disodium ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,317,765);
    maneb, manganese ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,504,404);
    mancozeb, manganese ethylenebis(dithiocarbamate) polymer complex zinc salt (GB 996 264);
    metam, methyldithiocarbaminic acid (U.S. Pat. No. 2,791,605);
    metiram, zinc ammoniate ethylenebis(dithiocarbamate) (U.S. Pat. No. 3,248,400);
    propineb, zinc propylenebis(dithiocarbamate) polymer (BE 611 960);
    polycarbamate, bis(dimethylcarbamodithioato-κS,κS′)[μ-[[1,2-ethanediylbis[carbamodithioato-κS,κS′]](2−)]]di[zinc] [CAS RN 64440-88-6];
    thiram, bis(dimethylthiocarbamoyl)disulfide (DE-A 642 532);
    ziram, dimethyldithiocarbamate [CAS RN 137-30-4];
    zineb, zinc ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,457,674);
    anilazine, 4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazine-2-amine (U.S. Pat. No. 2,720,480);
    benomyl, N-butyl-2-acetylaminobenzimidazole-1-carboxamide (U.S. Pat. No. 3,631,176);
    boscalid, 2-chloro-N-(4′-chlorobiphenyl-2-yl)nicotinamide (EP-A 545 099);
    carbendazim, methyl (1H-benzimidazol-2-yl)carbamate (U.S. Pat. No. 3,657,443);
    carboxin, 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiine-3-carboxamide (U.S. Pat. No. 3,249,499);
    oxycarboxin, 5,6-dihydro-2-methyl-1,4-oxathiine-3-carboxanilide 4,4-dioxide (U.S. Pat. No. 3,399,214);
    cyazofamid, 4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1H-imidazole-1-sulfon-amide (CAS RN 120116-88-3];
    dazomet, 3,5-dimethyl-1,3,5-thiadiazinane-2-thione (Bull. Soc. Chim. Fr. Vol. 15, p. 891 (1897));
    diflufenzopyr, 2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinic acid [CAS RN 109293-97-2];
    dithianon, 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin-2,3-dicarbonitrile (GB 857 383);
    famoxadone, (RS)-3-anilino-S-methyl-5-(4-phenoxyphenyl)-1,3-oxazolidine-2,4-dione [CAS RN 131807-57-3];
    fenamidone, (S)-1-anilino-4-methyl-2-methylthio-4-phenylimidazolin-5-one [CAS RN 161326-34-7];
    fenarimol, α-(2-chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol (GB 12 18 623);
    fuberidazole, 2-(2-furanyl)-1H-benzimidazole (DE-A 12 09 799);
    flutolanil, α,α,α-trifluoro-3′-isopropoxy-o-toluanilide (JP 1104514);
    furametpyr, 5-chloro-N-(1,3-dihydro-1,1,3-trimethyl-4-isobenzofuranyl)-1,3-dimethyl-1H-pyrazole-4-carboxamide [CAS RN 123572-88-3];
    isoprothiolane, diisopropyl 1,3-dithiolan-2-ylidenemalonate (Proc. Insectic. Fungic. Conf. 8. Vol. 2, p. 715 (1975));
    mepronil, 3′-isopropoxy-o-toluanilide (U.S. Pat. No. 3,937,840);
    nuarimol, α-(2-chlorophenyl)-α-(4-fluorophenyl)-5-pyrimidinemethanol (GB 12 18 623);
    fluopicolide (picobenzamid), 2,6-dichloro-N-(3-chloro-5-trifluoromethylpyridin-2-ylmethyl)benzamide (WO 99/42447);
    probenazole, 3-allyloxy-1,2-benzothiazole 1,1-dioxide (Agric. Biol. Chem. Vol. 37, p. 737 (1973));
    proquinazid, 6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one (WO 97/48684);
    pyrifenox, 2′,4′-dichloro-2-(3-pyridyl)acetophenone (EZ)-O-methyloxime (EP 49 854);
    pyroquilon, 1,2,5,6-tetrahydropyrrolo[3,2,1-ij]quinolin-4-one (GB 139 43 373) quinoxyfen, 5,7-dichloro-4-(4-fluorophenoxy)quinoline (U.S. Pat. No. 5,240,940);
    silthiofam, N-allyl-4,5-dimethyl-2-(trimethylsilyl)thiophene-3-carboxamide [CAS RN 175217-20-6];
    thiabendazole, 2-(1,3-thiazol-4-yl)benzimidazole (U.S. Pat. No. 3,017,415);
    thifluzamide, 2′,6′-dibromo-2-methyl-4′-trifluoromethoxy-4-trifluoromethyl-1,3-thiazole-5-carboxanilide [CAS RN 130000-40-7];
    thiophanate-methyl, 1,2-phenylenebis(iminocarbonothioyl)bis(dimethylcarbamate) (DE-A 19 30-540);
    tiadinil, 3′-chloro-4,4′-dimethyl-1,2,3-thiadiazole-5-carboxanilide [CAS RN 223580-51-6];
    tricyclazole, 5-methyl-1,2,4-triazolo[3,4-b][1,3]benzothiazole [CAS RN 41814-78-2];
    triforine, N,N′-{piperazine-1,4-diylbis[(trichloromethyl)methylene]}diformamide (DE-A 19 01 421);
    5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine (WO 98/46607);
    Bordeaux mixture, mixture of CuSO4×3Cu(OH)2×3CaSO4 [CAS RN 8011-63-0] copper acetate, Cu(OCOCH3)2 [CAS RN 8011-63-0];
    copper oxychloride, CU2Cl(OH)3 [CAS RN 1332-40-7];
    basic copper sulfate, CuSO4 [CAS RN 1344-73-6];
    binapacryl, (RS)-2-sec-butyl-4,6-dinitrophenyl 3-methylcrotonate [CAS RN 485-31-4];
    dinocap, mixture of 2,6-dinitro-4-octylphenylcrotonate and 2,4-dinitro-6-octyl-phenylcrotonate, where “octyl” is a mixture of 1-methylheptyl, 1-ethylhexyl and 1-propylpentyl (U.S. Pat. No. 2,526,660);
    dinobuton, (RS)-2-sec-butyl-4,6-dinitrophenyl isopropyl carbonate [CAS RN 973-21-7];
    nitrothal-isopropyl, diisopropyl 5-nitroisophthalate (Proc. Br. Insectic. Fungic. Conf. 7., Vol. 2, p. 673 (1973));
    fenpiclonil, 4-(2,3-dichlorophenyl)-1H-pyrrole-3-carbonitrile (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 65);
    fludioxonil, 4-(2,2-difluorobenzo[1,3]dioxol-4-yl)-1H-pyrrole-3-carbonitrile (The Pesticide Manual, publ. The British Crop Protection Council, 10th ed. 1995, p. 482);
    acibenzolar-S-methyl, methyl 1,2,3-benzothiadiazole-7-carbothioate [CAS RN 135158-54-2];
    flubenthiavalicarb (benthiavalicarb), isopropyl {(S)-1-[(1R)-1-(6-fluorobenzothiazol-2-yl)-ethylcarbamoyl]-2-methylpropyl}carbamate (JP-A 09/323,984);
    carpropamid, 2,2-dichloro-N-[1-(4-chlorophenyl)ethyl]-1-ethyl-3-methylcyclopropane-carboxamide [CAS RN 104030-54-8];
    chlorothalonil, 2,4,5,6-tetrachloroisophthalonitrile (U.S. Pat. No. 3,290,353);
    cyflufenamid, (Z)—N-[α-(cyclopropylmethoxyimino)-2,3-difluoro-6-(trifluoromethyl)benzyl]-2-phenylacetamide (WO 96/19442);
    cymoxanil, 1-(2-cyano-2-methoxyiminoacetyl)-3-ethylurea (U.S. Pat. No. 3,957,847);
    diclomezine, 6-(3,5-dichlorophenyl-p-tolyl)pyridazin-3(2H)-one (U.S. Pat. No. 4,052,395) diclocymet, (RS)-2-cyano-N—[(R)-1-(2,4-dichlorophenyl)ethyl]-3,3-dimethylbutyramide [CAS RN 139920-32-4];
    diethofencarb, isopropyl 3,4-diethoxycarbanilate (EP-A 78 663);
    edifenphos, O-ethyl S,S-diphenyl phosphorodithioate (DE-A 14 93 736) ethaboxam, N-(cyano-2-thienylmethyl)-4-ethyl-2-(ethylamino)-5-thiazolecarboxamide (EP-A 639 574);
    fenhexamid, N-(2,3-dichloro-4-hydroxyphenyl)-1-methylcyclohexanecarboxamide (Proc. Br. Crop Prot. Conf.—Pests Dis., 1998, Vol. 2, p. 327);
    fentin-acetate, triphenyltin (U.S. Pat. No. 3,499,086);
    fenoxanil, N-(1-cyano-1,2-dimethylpropyl)-2-(2,4-dichlorophenoxy)propanamide (EP-A 262 393);
    ferimzone, (Z)-2′-methylacetophenone-4,6-dimethylpyrimidin-2-ylhydrazone [CAS RN 89269-64-7];
    fluazinam, 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl]-5-(trifluoromethyl)-2-pyridinamine (The Pesticide Manual, publ. The British Crop Protection Council, 10th ed. (1995), p. 474);
    fosetyl, fosetyl-aluminum, ethylphosphonate (FR 22 54 276);
    iprovalicarb, isopropyl [(1S)-2-methyl-1-(1-p-tolylethylcarbamoyl)propyl]carbamate (EP-A 472 996);
    hexachlorobenzene (C. R. Seances Acad. Agric. Fr., Vol. 31, p. 24 (1945));
    mandipropamid, (RS)-2-(4-chlorophenyl)-N-[3-methoxy-4-(prop-2-ynyloxy)phenethyl]-2-(prop-2-ynyloxy)acetamide (WO 03/042166);
    metrafenone, 3′-bromo-2,3,4,6′-tetramethoxy-2′,6-dimethylbenzophenone (U.S. Pat. No. 5,945,567);
    pencycuron, 1-(4-chlorobenzyl)-1-cyclopentyl-3-phenylurea (DE-A 27 32 257);
    penthiopyrad, (RS)—N-[2-(1,3-dimethylbutyl)-3-thienyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide (JP 10/130,268);
    propamocarb, isopropyl 3-(dimethylamino)propylcarbamate (DE-A 15 67 169);
    phthalide (DE-A 16 43 347);
    toloclofos-methyl, O-2,6-dichloro-p-tolyl O,O-dimethyl phosphorothioate (GB 14 67 561);
    quintozene, pentachloronitrobenzene (DE-A 682 048);
    zoxamide, (RS)-3,5-dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-p-toluamide [CAS RN 156052-68-5];
    captafol, N-(1,1,2,2-tetrachloroethylthio)cyclohex-4-ene-1,2-dicarboximide (Phytopathology, Vol. 52, p. 754 (1962));
    captan, N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide (U.S. Pat. No. 2,553,770);
    dichlofluanid, N-dichlorofluoromethylthio-N′,N′-dimethyl-N-phenylsulfamide (DE-A 11 93 498);
    folpet, N-(trichloromethylthio)phthalimide (U.S. Pat. No. 2,553,770);
    tolylfluanid, N-dichlorofluoromethylthio-N′,N′-dimethyl-N-p-tolylsulfamide (DE-A 11 93 498);
    dimethomorph, 3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-yl-propenone (EP-A 120 321);
    flumetover, 2-(3,4-dimethoxyphenyl)-N-ethyl-α,α,α-trifluoro-N-methyl-p-toluamide [AGROW no. 243, 22 (1995)];
    flumorph, 3-(4-fluorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-ylpropenone (EP-A 860 438);
    N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,
    N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-chloro-3′-7-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide (WO 03/66610);
    N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide and N-(3′,4′-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO 03/70705);
    N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide (WO 99/24413);
    N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide (WO 04/49804);
    3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine (EP-A 10 35 122);
    2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103);
    N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfon-amide (EP-A 10 31 571);
    methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate,
    methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate (EP-A 12 01 648);
    methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propionate (EP-A 10 28 125);
    azoxystrobin, methyl 2-{2-[6-(2-cyano-1-vinylpenta-1,3-dienyloxy)pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate (EP-A 382 375),
    dimoxystrobin, (E)-2-(methoxyimino)-N-methyl-2-[α-(2,5-xylyloxy)-o-tolyl]acetamide (EP-A 477 631);
    fluoxastrobin, (E)-{2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yloxy]phenyl}(5,6-dihydro-1,4,2-dioxazin-3-yl)methanone O-methyloxime (WO 97/27189);
    kresoxim-methyl, methyl (E)-methoxyimino[α-(o-tolyloxy)-o-tolyl]acetate (EP-A 253 213);
    metominostrobin, (E)-2-(methoxyimino)-N-methyl-2-(2-phenoxyphenyl)acetamide (EP-A 398 692);
    orysastrobin, (2E)-2-(methoxyimino)-2-{2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-dien-1-yl]phenyl}-N-methylacetamide (WO 97/15552);
    picoxystrobin, methyl 3-methoxy-2-[2-(6-trifluoromethylpyridin-2-yloxymethyl)phenyl]-acrylate (EP-A 278 595);
    pyraclostrobin, methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate (WO 96/01256);
    trifloxystrobin, methyl (E)-methoxyimino-{(E)-α-[1-(α,α,α-trifluoro-m-tolyl)ethylidene-aminooxy]-o-tolyl}acetate (EP-A 460 575);
    methyl 2-[ortho-(2,5-dimethylphenyloxymethylene)phenyl]-3-methoxyacrylate (EP-A 226 917);
    5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine (WO 98/46608);
    3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide (WO 99/24413), compounds of the formula III (WO 04/049804);
    N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide and N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide (WO 03/66609);
    2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103);
    N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide (WO 03/053145);
    methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propanoate (EP-A 1028125).


It is an object of the present invention, with a view to reducing the application rates and broadening the activity spectrum of the active compounds I and II, to provide mixtures which, at a reduced total amount of active compounds applied, have improved activity against harmful fungi, in particular for certain indications.
We have accordingly found that this object is achieved by the mixtures, defined at the outset, of the active compounds I and II. Moreover, we have found that simultaneous, that is joint or separate, application of at least one compound I and at least one of the active compounds II or successive application of the compound(s) I and at least one of the active compounds II allows better control of harmful fungi than is possible with the individual compounds alone (synergistic mixtures).
The compounds I can be used as synergists for a large number of different fungicidal active compounds. By simultaneous, that is joint or separate, application of compound(s) I with at least one active compound II, the fungicidal activity is increased in a superadditive manner.
The compounds I can be present in different crystal modifications, which may differ in biological activity.
In the formula I, halogen is fluorine, chlorine, bromine or iodine, preferably fluorine or chlorine;
C1-C4-alkyl is methyl, ethyl, n-propyl, 1-methylethyl, n-butyl, 1-methylpropyl, 2-methylpropyl or 1,1-dimethylethyl, preferably methyl or ethyl;
C1-C4-haloalkyl is a partially or fully halogenated C1-C4-alkyl radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, heptafluoropropyl or nonafluorobutyl, in particular halomethyl, with particular preference CH2—Cl, CH(Cl)2, CH2—F, CHF2, CF3, CHFCl, CF2Cl or CF(Cl)2, in particular CHF2 or CF3;

C1-C4-alkoxy is OCH3, OC2H5, OCH2—C2H5, OCH(CH3)2, n-butoxy, OCH(CH3)—C2H5, OCH2—CH(CH3)2 or OC(CH3)3, preferably OCH3 or OC2H5;

C1-C4-haloalkoxy is a partially or fully halogenated C1-C4-alkoxy radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy, heptafluoropropoxy or nonafluorobutoxy, in particular halomethoxy, particularly preferably OCH2—Cl, OCH(Cl)2, OCH2—F, OCH(F)2, OCF3, OCHFCl, OCF2Cl or OCF(Cl)2;

C1-C4-alkylthio is SCH3, SC2H5, SCH2—C2H5, SCH(CH3)2, n-butylthio, SCH(CH3)—C2H5, SCH2—CH(CH3)2 or SC(CH3)3, preferably SCH3 or SC2H5.

Preferred 1-methylpyrazol-4-ylcarboxanilides I are, on the one hand, those in which X is oxygen.
On the other hand, preferred compounds I are those in which X is sulfur.
For the mixtures according to the invention, preference is given to compounds of the formula I in which R1 is methyl or halomethyl, in particular CH3, CHF2, CH2F, CF3, CHFCl or CF2Cl.
Preference is furthermore given to compounds I in which R2 is hydrogen, fluorine or chlorine, in particular hydrogen.
Preference is furthermore given to those compounds I in which R3 is halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio, preferably halogen, methyl, halomethyl, methoxy, halomethoxy or methylthio, in particular F, Cl, CH3, CF3, OCH3, OCHF2, OCF3 or SCH3, particularly preferably fluorine.
Moreover, preference is given to those compounds I in which R4 is halogen, in particular fluorine.
Preference is furthermore given to those compounds I in which R5 is halogen, in particular fluorine.
Particular preference is given to the compounds I listed in Table 1 below in which X is oxygen.













TABLE 1





Compound
R1
R2
R3
R4
R5
M.p. [° C.]







No. 1
CH3
H
2-F
3-F
4-F



No. 2
CH3
H
2-F
3-F
5-F



No. 3
CH3
H
2-F
4-F
5-F



No. 4
CH3
H
2-F
4-F
6-F



No. 5
CH3
H
3-F
4-F
5-F



No. 6
CH3
H
3-F
5-F
6-F



No. 7
CH2F
H
2-F
3-F
4-F



No. 8
CH2F
H
2-F
3-F
5-F



No. 9
CH2F
H
2-F
4-F
5-F



No. 10
CH2F
H
2-F
4-F
6-F



No. 11
CH2F
H
3-F
4-F
5-F



No. 12
CH2F
H
3-F
5-F
6-F



No. 13
CHF2
H
2-F
3-F
4-F



No. 14
CHF2
H
2-F
3-F
5-F



No. 15
CHF2
H
2-F
4-F
5-F



No. 16
CHF2
H
2-F
4-F
6-F



No. 17
CHF2
H
3-F
4-F
5-F



No. 18
CHF2
H
3-F
5-F
6-F



No. 19
CF3
H
2-F
3-F
4-F



No. 20
CF3
H
2-F
3-F
5-F



No. 21
CF3
H
2-F
4-F
5-F



No. 22
CF3
H
2-F
4-F
6-F



No. 23
CF3
H
3-F
4-F
5-F



No. 24
CF3
H
3-F
5-F
6-F



No. 25
CHFCl
H
2-F
3-F
4-F



No. 26
CHFCl
H
2-F
3-F
5-F



No. 27
CHFCl
H
2-F
4-F
5-F



No. 28
CHFCl
H
2-F
4-F
6-F



No. 29
CHFCl
H
3-F
4-F
5-F



No. 30
CHFCl
H
3-F
5-F
6-F



No. 31
CF2Cl
H
2-F
3-F
4-F



No. 32
CF2Cl
H
2-F
3-F
5-F



No. 33
CF2Cl
H
2-F
4-F
5-F



No. 34
CF2Cl
H
2-F
4-F
6-F



No. 35
CF2Cl
H
3-F
4-F
5-F



No. 36
CF2Cl
H
3-F
5-F
6-F



No. 37
CH3
F
2-F
3-F
4-F



No. 38
CH3
F
2-F
3-F
5-F



No. 39
CH3
F
2-F
4-F
5-F



No. 40
CH3
F
2-F
4-F
6-F



No. 41
CH3
F
3-F
4-F
5-F



No. 42
CH3
F
3-F
5-F
6-F



No. 43
CH2F
F
2-F
3-F
4-F



No. 44
CH2F
F
2-F
3-F
5-F



No. 45
CH2F
F
2-F
4-F
5-F



No. 46
CH2F
F
2-F
4-F
6-F



No. 47
CH2F
F
3-F
4-F
5-F



No. 48
CH2F
F
3-F
5-F
6-F



No. 49
CHF2
F
2-F
3-F
4-F



No. 50
CHF2
F
2-F
3-F
5-F



No. 51
CHF2
F
2-F
4-F
5-F



No. 52
CHF2
F
2-F
4-F
6-F



No. 53
CHF2
F
3-F
4-F
5-F



No. 54
CHF2
F
3-F
5-F
6-F



No. 55
CF3
F
2-F
3-F
4-F



No. 56
CF3
F
2-F
3-F
5-F



No. 57
CF3
F
2-F
4-F
5-F



No. 58
CF3
F
2-F
4-F
6-F



No. 59
CF3
F
3-F
4-F
5-F



No. 60
CF3
F
3-F
5-F
6-F



No. 61
CHFCl
F
2-F
3-F
4-F



No. 62
CHFCl
F
2-F
3-F
5-F



No. 63
CHFCl
F
2-F
4-F
5-F



No. 64
CHFCl
F
2-F
4-F
6-F



No. 65
CHFCl
F
3-F
4-F
5-F



No. 66
CHFCl
F
3-F
5-F
6-F



No. 67
CF2Cl
F
2-F
3-F
4-F



No. 68
CF2Cl
F
2-F
3-F
5-F



No. 69
CF2Cl
F
2-F
4-F
5-F



No. 70
CF2Cl
F
2-F
4-F
6-F



No. 71
CF2Cl
F
3-F
4-F
5-F



No. 72
CF2Cl
F
3-F
5-F
6-F



No. 73
CH3
Cl
2-F
3-F
4-F



No. 74
CH3
Cl
2-F
3-F
5-F



No. 75
CH3
Cl
2-F
4-F
5-F



No. 76
CH3
Cl
2-F
4-F
6-F



No. 77
CH3
Cl
3-F
4-F
5-F



No. 78
CH3
Cl
3-F
5-F
6-F



No. 79
CH2F
Cl
2-F
3-F
4-F



No. 80
CH2F
Cl
2-F
3-F
5-F



No. 81
CH2F
Cl
2-F
4-F
5-F



No. 82
CH2F
Cl
2-F
4-F
6-F



No. 83
CH2F
Cl
3-F
4-F
5-F



No. 84
CH2F
Cl
3-F
5-F
6-F



No. 85
CHF2
Cl
2-F
3-F
4-F



No. 86
CHF2
Cl
2-F
3-F
5-F



No. 87
CHF2
Cl
2-F
4-F
5-F



No. 88
CHF2
Cl
2-F
4-F
6-F



No. 89
CHF2
Cl
3-F
4-F
5-F



No. 90
CHF2
Cl
3-F
5-F
6-F



No. 91
CF3
Cl
2-F
3-F
4-F



No. 92
CF3
Cl
2-F
3-F
5-F



No. 93
CF3
Cl
2-F
4-F
5-F



No. 94
CF3
Cl
2-F
4-F
6-F



No. 95
CF3
Cl
3-F
4-F
5-F



No. 96
CF3
Cl
3-F
5-F
6-F



No. 97
CHFCl
Cl
2-F
3-F
4-F



No. 98
CHFCl
Cl
2-F
3-F
5-F



No. 99
CHFCl
Cl
2-F
4-F
5-F



No. 100
CHFCl
Cl
2-F
4-F
6-F



No. 101
CHFCl
Cl
3-F
4-F
5-F



No. 102
CHFCl
Cl
3-F
5-F
6-F



No. 103
CF2Cl
Cl
2-F
3-F
4-F



No. 104
CF2Cl
Cl
2-F
3-F
5-F



No. 105
CF2Cl
Cl
2-F
4-F
5-F



No. 106
CF2Cl
Cl
2-F
4-F
6-F



No. 107
CF2Cl
Cl
3-F
4-F
5-F



No. 108
CF2Cl
Cl
3-F
5-F
6-F









Particular preference is furthermore given to 1-methylpyrazol-4-ylcarboxanilides of the formula Ia (I where X=O, R1=CF3 and R2=H)




in particular to the compounds Ia.1 to Ia.1009 listed in Table 2 below:














TABLE 2





Compound





M.p.


No.
R1
R2
R3
R4
R5
[° C.]







Ia.1
CF3
H
2-fluoro
3-fluoro
4-fluoro
123-125


Ia.2
CF3
H
2-fluoro
3-chloro
4-fluoro



Ia.3
CF3
H
2-fluoro
3-CN
4-fluoro



Ia.4
CF3
H
2-fluoro
3-methyl
4-fluoro



Ia.5
CF3
H
2-fluoro
3-CF3
4-fluoro



Ia.6
CF3
H
2-fluoro
3-OCH3
4-fluoro



Ia.7
CF3
H
2-fluoro
3-OCF3
4-fluoro



Ia.8
CF3
H
2-chloro
3-fluoro
4-fluoro



Ia.9
CF3
H
2-chloro
3-chloro
4-fluoro



Ia.10
CF3
H
2-chloro
3-CN
4-fluoro



Ia.11
CF3
H
2-chloro
3-methyl
4-fluoro



Ia.12
CF3
H
2-chloro
3-CF3
4-fluoro



Ia.13
CF3
H
2-chloro
3-OCH3
4-fluoro



Ia.14
CF3
H
2-chloro
3-OCF3
4-fluoro



Ia.15
CF3
H
2-CN
3-fluoro
4-fluoro



Ia.16
CF3
H
2-CN
3-chloro
4-fluoro



Ia.17
CF3
H
2-CN
3-CN
4-fluoro



Ia.18
CF3
H
2-CN
3-methyl
4-fluoro



Ia.19
CF3
H
2-CN
3-CF3
4-fluoro



Ia.20
CF3
H
2-CN
3-OCH3
4-fluoro



Ia.21
CF3
H
2-CN
3-OCF3
4-fluoro



Ia.22
CF3
H
2-methyl
3-fluoro
4-fluoro



Ia.23
CF3
H
2-methyl
3-chloro
4-fluoro



Ia.24
CF3
H
2-methyl
3-CN
4-fluoro



Ia.25
CF3
H
2-methyl
3-methyl
4-fluoro



Ia.26
CF3
H
2-methyl
3-CF3
4-fluoro



Ia.27
CF3
H
2-methyl
3-OCH3
4-fluoro



Ia.28
CF3
H
2-methyl
3-OCF3
4-fluoro



Ia.29
CF3
H
2-CF3
3-fluoro
4-fluoro



Ia.30
CF3
H
2-CF3
3-chloro
4-fluoro



Ia.31
CF3
H
2-CF3
3-CN
4-fluoro



Ia.32
CF3
H
2-CF3
3-methyl
4-fluoro



Ia.33
CF3
H
2-CF3
3-CF3
4-fluoro



Ia.34
CF3
H
2-CF3
3-OCH3
4-fluoro



Ia.35
CF3
H
2-CF3
3-OCF3
4-fluoro



Ia.36
CF3
H
2-OCH3
3-fluoro
4-fluoro



Ia.37
CF3
H
2-OCH3
3-chloro
4-fluoro



Ia.38
CF3
H
2-OCH3
3-CN
4-fluoro



Ia.39
CF3
H
2-OCH3
3-methyl
4-fluoro



Ia.40
CF3
H
2-OCH3
3-CF3
4-fluoro



Ia.41
CF3
H
2-OCH3
3-OCH3
4-fluoro



Ia.42
CF3
H
2-OCH3
3-OCF3
4-fluoro



Ia.43
CF3
H
2-OCF3
3-fluoro
4-fluoro



Ia.44
CF3
H
2-OCF3
3-chloro
4-fluoro



Ia.45
CF3
H
2-OCF3
3-CN
4-fluoro



Ia.46
CF3
H
2-OCF3
3-methyl
4-fluoro



Ia.47
CF3
H
2-OCF3
3-CF3
4-fluoro



Ia.48
CF3
H
2-OCF3
3-OCH3
4-fluoro



Ia.49
CF3
H
2-OCF3
3-OCF3
4-fluoro



Ia.50
CF3
H
2-fluoro
3-fluoro
4-chloro



Ia.51
CF3
H
2-fluoro
3-chloro
4-chloro



Ia.52
CF3
H
2-fluoro
3-CN
4-chloro



Ia.53
CF3
H
2-fluoro
3-methyl
4-chloro



Ia.54
CF3
H
2-fluoro
3-CF3
4-chloro



Ia.55
CF3
H
2-fluoro
3-OCH3
4-chloro



Ia.56
CF3
H
2-fluoro
3-OCF3
4-chloro



Ia.57
CF3
H
2-chloro
3-fluoro
4-chloro



Ia.58
CF3
H
2-chloro
3-chloro
4-chloro



Ia.59
CF3
H
2-chloro
3-CN
4-chloro



Ia.60
CF3
H
2-chloro
3-methyl
4-chloro



Ia.61
CF3
H
2-chloro
3-CF3
4-chloro



Ia.62
CF3
H
2-chloro
3-OCH3
4-chloro



Ia.63
CF3
H
2-chloro
3-OCF3
4-chloro



Ia.64
CF3
H
2-CN
3-fluoro
4-chloro



Ia.65
CF3
H
2-CN
3-chloro
4-chloro



Ia.66
CF3
H
2-CN
3-CN
4-chloro



Ia.67
CF3
H
2-CN
3-methyl
4-chloro



Ia.68
CF3
H
2-CN
3-CF3
4-chloro



Ia.69
CF3
H
2-CN
3-OCH3
4-chloro



Ia.70
CF3
H
2-CN
3-OCF3
4-chloro



Ia.71
CF3
H
2-methyl
3-fluoro
4-chloro



Ia.72
CF3
H
2-methyl
3-chloro
4-chloro



Ia.73
CF3
H
2-methyl
3-CN
4-chloro



Ia.74
CF3
H
2-methyl
3-methyl
4-chloro



Ia.75
CF3
H
2-methyl
3-CF3
4-chloro



Ia.76
CF3
H
2-methyl
3-OCH3
4-chloro



Ia.77
CF3
H
2-methyl
3-OCF3
4-chloro



Ia.78
CF3
H
2-CF3
3-fluoro
4-chloro



Ia.79
CF3
H
2-CF3
3-chloro
4-chloro



Ia.80
CF3
H
2-CF3
3-CN
4-chloro



Ia.81
CF3
H
2-CF3
3-methyl
4-chloro



Ia.82
CF3
H
2-CF3
3-CF3
4-chloro



Ia.83
CF3
H
2-CF3
3-OCH3
4-chloro



Ia.84
CF3
H
2-CF3
3-OCF3
4-chloro



Ia.85
CF3
H
2-OCH3
3-fluoro
4-chloro



Ia.86
CF3
H
2-OCH3
3-chloro
4-chloro



Ia.87
CF3
H
2-OCH3
3-CN
4-chloro



Ia.88
CF3
H
2-OCH3
3-methyl
4-chloro



Ia.89
CF3
H
2-OCH3
3-CF3
4-chloro



Ia.90
CF3
H
2-OCH3
3-OCH3
4-chloro



Ia.91
CF3
H
2-OCH3
3-OCF3
4-chloro



Ia.92
CF3
H
2-OCF3
3-fluoro
4-chloro



Ia.93
CF3
H
2-OCF3
3-chloro
4-chloro



Ia.94
CF3
H
2-OCF3
3-CN
4-chloro



Ia.95
CF3
H
2-OCF3
3-methyl
4-chloro



Ia.96
CF3
H
2-OCF3
3-CF3
4-chloro



Ia.97
CF3
H
2-OCF3
3-OCH3
4-chloro



Ia.98
CF3
H
2-OCF3
3-OCF3
4-chloro



Ia.99
CF3
H
2-fluoro
3-fluoro
4-CN



Ia.100
CF3
H
2-fluoro
3-chloro
4-CN



Ia.101
CF3
H
2-fluoro
3-CN
4-CN



Ia.102
CF3
H
2-fluoro
3-methyl
4-CN



Ia.103
CF3
H
2-fluoro
3-CF3
4-CN



Ia.104
CF3
H
2-fluoro
3-OCH3
4-CN



Ia.105
CF3
H
2-fluoro
3-OCF3
4-CN



Ia.106
CF3
H
2-chloro
3-fluoro
4-CN



Ia.107
CF3
H
2-chloro
3-chloro
4-CN



Ia.108
CF3
H
2-chloro
3-CN
4-CN



Ia.109
CF3
H
2-chloro
3-methyl
4-CN



Ia.110
CF3
H
2-chloro
3-CF3
4-CN



Ia.111
CF3
H
2-chloro
3-OCH3
4-CN



Ia.112
CF3
H
2-chloro
3-OCF3
4-CN



Ia.113
CF3
H
2-CN
3-fluoro
4-CN



Ia.114
CF3
H
2-CN
3-chloro
4-CN



Ia.115
CF3
H
2-CN
3-CN
4-CN



Ia.116
CF3
H
2-CN
3-methyl
4-CN



Ia.117
CF3
H
2-CN
3-CF3
4-CN



Ia.118
CF3
H
2-CN
3-OCH3
4-CN



Ia.119
CF3
H
2-CN
3-OCF3
4-CN



Ia.120
CF3
H
2-methyl
3-fluoro
4-CN



Ia.121
CF3
H
2-methyl
3-chloro
4-CN



Ia.122
CF3
H
2-methyl
3-CN
4-CN



Ia.123
CF3
H
2-methyl
3-methyl
4-CN



Ia.124
CF3
H
2-methyl
3-CF3
4-CN



Ia.125
CF3
H
2-methyl
3-OCH3
4-CN



Ia.126
CF3
H
2-methyl
3-OCF3
4-CN



Ia.127
CF3
H
2-CF3
3-fluoro
4-CN



Ia.128
CF3
H
2-CF3
3-chloro
4-CN



Ia.129
CF3
H
2-CF3
3-CN
4-CN



Ia.130
CF3
H
2-CF3
3-methyl
4-CN



Ia.131
CF3
H
2-CF3
3-CF3
4-CN



Ia.132
CF3
H
2-CF3
3-OCH3
4-CN



Ia.133
CF3
H
2-CF3
3-OCF3
4-CN



Ia.134
CF3
H
2-OCH3
3-fluoro
4-CN



Ia.135
CF3
H
2-OCH3
3-chloro
4-CN



Ia.136
CF3
H
2-OCH3
3-CN
4-CN



Ia.137
CF3
H
2-OCH3
3-methyl
4-CN



Ia.138
CF3
H
2-OCH3
3-CF3
4-CN



Ia.139
CF3
H
2-OCH3
3-OCH3
4-CN



Ia.140
CF3
H
2-OCH3
3-OCF3
4-CN



Ia.141
CF3
H
2-OCF3
3-fluoro
4-CN



Ia.142
CF3
H
2-OCF3
3-chloro
4-CN



Ia.143
CF3
H
2-OCF3
3-CN
4-CN



Ia.144
CF3
H
2-OCF3
3-methyl
4-CN



Ia.145
CF3
H
2-OCF3
3-CF3
4-CN



Ia.146
CF3
H
2-OCF3
3-OCH3
4-CN



Ia.147
CF3
H
2-OCF3
3-OCF3
4-CN



Ia.148
CF3
H
2-fluoro
3-fluoro
4-methyl



Ia.149
CF3
H
2-fluoro
3-chloro
4-methyl



Ia.150
CF3
H
2-fluoro
3-CN
4-methyl



Ia.151
CF3
H
2-fluoro
3-methyl
4-methyl



Ia.152
CF3
H
2-fluoro
3-CF3
4-methyl



Ia.153
CF3
H
2-fluoro
3-OCH3
4-methyl



Ia.154
CF3
H
2-fluoro
3-OCF3
4-methyl



Ia.155
CF3
H
2-chloro
3-fluoro
4-methyl



Ia.156
CF3
H
2-chloro
3-chloro
4-methyl



Ia.157
CF3
H
2-chloro
3-CN
4-methyl



Ia.158
CF3
H
2-chloro
3-methyl
4-methyl



Ia.159
CF3
H
2-chloro
3-CF3
4-methyl



Ia.160
CF3
H
2-chloro
3-OCH3
4-methyl



Ia.161
CF3
H
2-chloro
3-OCF3
4-methyl



Ia.162
CF3
H
2-CN
3-fluoro
4-methyl



Ia.163
CF3
H
2-CN
3-chloro
4-methyl



Ia.164
CF3
H
2-CN
3-CN
4-methyl



Ia.165
CF3
H
2-CN
3-methyl
4-methyl



Ia.166
CF3
H
2-CN
3-CF3
4-methyl



Ia.167
CF3
H
2-CN
3-OCH3
4-methyl



Ia.168
CF3
H
2-CN
3-OCF3
4-methyl



Ia.169
CF3
H
2-methyl
3-fluoro
4-methyl



Ia.170
CF3
H
2-methyl
3-chloro
4-methyl



Ia.171
CF3
H
2-methyl
3-CN
4-methyl



Ia.172
CF3
H
2-methyl
3-methyl
4-methyl



Ia.173
CF3
H
2-methyl
3-CF3
4-methyl



Ia.174
CF3
H
2-methyl
3-OCH3
4-methyl



Ia.175
CF3
H
2-methyl
3-OCF3
4-methyl



Ia.176
CF3
H
2-CF3
3-fluoro
4-methyl



Ia.177
CF3
H
2-CF3
3-chloro
4-methyl



Ia.178
CF3
H
2-CF3
3-CN
4-methyl



Ia.179
CF3
H
2-CF3
3-methyl
4-methyl



Ia.180
CF3
H
2-CF3
3-CF3
4-methyl



Ia.181
CF3
H
2-CF3
3-OCH3
4-methyl



Ia.182
CF3
H
2-CF3
3-OCF3
4-methyl



Ia.183
CF3
H
2-OCH3
3-fluoro
4-methyl



Ia.184
CF3
H
2-OCH3
3-chloro
4-methyl



Ia.185
CF3
H
2-OCH3
3-CN
4-methyl



Ia.186
CF3
H
2-OCH3
3-methyl
4-methyl



Ia.187
CF3
H
2-OCH3
3-CF3
4-methyl



Ia.188
CF3
H
2-OCH3
3-OCH3
4-methyl



Ia.189
CF3
H
2-OCH3
3-OCF3
4-methyl



Ia.190
CF3
H
2-OCF3
3-fluoro
4-methyl



Ia.191
CF3
H
2-OCF3
3-chloro
4-methyl



Ia.192
CF3
H
2-OCF3
3-CN
4-methyl



Ia.193
CF3
H
2-OCF3
3-methyl
4-methyl



Ia.194
CF3
H
2-OCF3
3-CF3
4-methyl



Ia.195
CF3
H
2-OCF3
3-OCH3
4-methyl



Ia.196
CF3
H
2-OCF3
3-OCF3
4-methyl



Ia.197
CF3
H
2-fluoro
3-fluoro
4-CF3



Ia.198
CF3
H
2-fluoro
3-chloro
4-CF3



Ia.199
CF3
H
2-fluoro
3-CN
4-CF3



Ia.200
CF3
H
2-fluoro
3-methyl
4-CF3



Ia.201
CF3
H
2-fluoro
3-CF3
4-CF3



Ia.202
CF3
H
2-fluoro
3-OCH3
4-CF3



Ia.203
CF3
H
2-fluoro
3-OCF3
4-CF3



Ia.204
CF3
H
2-chloro
3-fluoro
4-CF3



Ia.205
CF3
H
2-chloro
3-chloro
4-CF3



Ia.206
CF3
H
2-chloro
3-CN
4-CF3



Ia.207
CF3
H
2-chloro
3-methyl
4-CF3



Ia.208
CF3
H
2-chloro
3-CF3
4-CF3



Ia.209
CF3
H
2-chloro
3-OCH3
4-CF3



Ia.210
CF3
H
2-chloro
3-OCF3
4-CF3



Ia.211
CF3
H
2-CN
3-fluoro
4-CF3



Ia.212
CF3
H
2-CN
3-chloro
4-CF3



Ia.213
CF3
H
2-CN
3-CN
4-CF3



Ia.214
CF3
H
2-CN
3-methyl
4-CF3



Ia.215
CF3
H
2-CN
3-CF3
4-CF3



Ia.216
CF3
H
2-CN
3-OCH3
4-CF3



Ia.217
CF3
H
2-CN
3-OCF3
4-CF3



Ia.218
CF3
H
2-methyl
3-fluoro
4-CF3



Ia.219
CF3
H
2-methyl
3-chloro
4-CF3



Ia.220
CF3
H
2-methyl
3-CN
4-CF3



Ia.221
CF3
H
2-methyl
3-methyl
4-CF3



Ia.222
CF3
H
2-methyl
3-CF3
4-CF3



Ia.223
CF3
H
2-methyl
3-OCH3
4-CF3



Ia.224
CF3
H
2-methyl
3-OCF3
4-CF3



Ia.225
CF3
H
2-CF3
3-fluoro
4-CF3



Ia.226
CF3
H
2-CF3
3-chloro
4-CF3



Ia.227
CF3
H
2-CF3
3-CN
4-CF3



Ia.228
CF3
H
2-CF3
3-methyl
4-CF3



Ia.229
CF3
H
2-CF3
3-CF3
4-CF3



Ia.230
CF3
H
2-CF3
3-OCH3
4-CF3



Ia.231
CF3
H
2-CF3
3-OCF3
4-CF3



Ia.232
CF3
H
2-OCH3
3-fluoro
4-CF3



Ia.233
CF3
H
2-OCH3
3-chloro
4-CF3



Ia.234
CF3
H
2-OCH3
3-CN
4-CF3



Ia.235
CF3
H
2-OCH3
3-methyl
4-CF3



Ia.236
CF3
H
2-OCH3
3-CF3
4-CF3



Ia.237
CF3
H
2-OCH3
3-OCH3
4-CF3



Ia.238
CF3
H
2-OCH3
3-OCF3
4-CF3



Ia.239
CF3
H
2-OCF3
3-fluoro
4-CF3



Ia.240
CF3
H
2-OCF3
3-chloro
4-CF3



Ia.241
CF3
H
2-OCF3
3-CN
4-CF3



Ia.242
CF3
H
2-OCF3
3-methyl
4-CF3



Ia.243
CF3
H
2-OCF3
3-CF3
4-CF3



Ia.244
CF3
H
2-OCF3
3-OCH3
4-CF3



Ia.245
CF3
H
2-OCF3
3-OCF3
4-CF3



Ia.246
CF3
H
2-fluoro
3-fluoro
4-OCH3



Ia.247
CF3
H
2-fluoro
3-chloro
4-OCH3



Ia.248
CF3
H
2-fluoro
3-CN
4-OCH3



Ia.249
CF3
H
2-fluoro
3-methyl
4-OCH3



Ia.250
CF3
H
2-fluoro
3-CF3
4-OCH3



Ia.251
CF3
H
2-fluoro
3-OCH3
4-OCH3



Ia.252
CF3
H
2-fluoro
3-OCF3
4-OCH3



Ia.253
CF3
H
2-chloro
3-fluoro
4-OCH3



Ia.254
CF3
H
2-chloro
3-chloro
4-OCH3



Ia.255
CF3
H
2-chloro
3-CN
4-OCH3



Ia.256
CF3
H
2-chloro
3-methyl
4-OCH3



Ia.257
CF3
H
2-chloro
3-CF3
4-OCH3



Ia.258
CF3
H
2-chloro
3-OCH3
4-OCH3



Ia.259
CF3
H
2-chloro
3-OCF3
4-OCH3



Ia.260
CF3
H
2-CN
3-fluoro
4-OCH3



Ia.261
CF3
H
2-CN
3-chloro
4-OCH3



Ia.262
CF3
H
2-CN
3-CN
4-OCH3



Ia.263
CF3
H
2-CN
3-methyl
4-OCH3



Ia.264
CF3
H
2-CN
3-CF3
4-OCH3



Ia.265
CF3
H
2-CN
3-OCH3
4-OCH3



Ia.266
CF3
H
2-CN
3-OCF3
4-OCH3



Ia.267
CF3
H
2-methyl
3-fluoro
4-OCH3



Ia.268
CF3
H
2-methyl
3-chloro
4-OCH3



Ia.269
CF3
H
2-methyl
3-CN
4-OCH3



Ia.270
CF3
H
2-methyl
3-methyl
4-OCH3



Ia.271
CF3
H
2-methyl
3-CF3
4-OCH3



Ia.272
CF3
H
2-methyl
3-OCH3
4-OCH3



Ia.273
CF3
H
2-methyl
3-OCF3
4-OCH3



Ia.274
CF3
H
2-CF3
3-fluoro
4-OCH3



Ia.275
CF3
H
2-CF3
3-chloro
4-OCH3



Ia.276
CF3
H
2-CF3
3-CN
4-OCH3



Ia.277
CF3
H
2-CF3
3-methyl
4-OCH3



Ia.278
CF3
H
2-CF3
3-CF3
4-OCH3



Ia.279
CF3
H
2-CF3
3-OCH3
4-OCH3



Ia.280
CF3
H
2-CF3
3-OCF3
4-OCH3



Ia.281
CF3
H
2-OCH3
3-fluoro
4-OCH3



Ia.282
CF3
H
2-OCH3
3-chloro
4-OCH3



Ia.283
CF3
H
2-OCH3
3-CN
4-OCH3



Ia.284
CF3
H
2-OCH3
3-methyl
4-OCH3



Ia.285
CF3
H
2-OCH3
3-CF3
4-OCH3



Ia.286
CF3
H
2-OCH3
3-OCH3
4-OCH3



Ia.287
CF3
H
2-OCH3
3-OCF3
4-OCH3



Ia.288
CF3
H
2-OCF3
3-fluoro
4-OCH3



Ia.289
CF3
H
2-OCF3
3-chloro
4-OCH3



Ia.290
CF3
H
2-OCF3
3-CN
4-OCH3



Ia.291
CF3
H
2-OCF3
3-methyl
4-OCH3



Ia.292
CF3
H
2-OCF3
3-CF3
4-OCH3



Ia.293
CF3
H
2-OCF3
3-OCH3
4-OCH3



Ia.294
CF3
H
2-OCF3
3-OCF3
4-OCH3



Ia.295
CF3
H
2-fluoro
3-fluoro
4-OCF3



Ia.296
CF3
H
2-fluoro
3-chloro
4-OCF3



Ia.297
CF3
H
2-fluoro
3-CN
4-OCF3



Ia.298
CF3
H
2-fluoro
3-methyl
4-OCF3



Ia.299
CF3
H
2-fluoro
3-CF3
4-OCF3



Ia.300
CF3
H
2-fluoro
3-OCH3
4-OCF3



Ia.301
CF3
H
2-fluoro
3-OCF3
4-OCF3



Ia.302
CF3
H
2-chloro
3-fluoro
4-OCF3



Ia.303
CF3
H
2-chloro
3-chloro
4-OCF3



Ia.304
CF3
H
2-chloro
3-CN
4-OCF3



Ia.305
CF3
H
2-chloro
3-methyl
4-OCF3



Ia.306
CF3
H
2-chloro
3-CF3
4-OCF3



Ia.307
CF3
H
2-chloro
3-OCH3
4-OCF3



Ia.308
CF3
H
2-chloro
3-OCF3
4-OCF3



Ia.309
CF3
H
2-CN
3-fluoro
4-OCF3



Ia.310
CF3
H
2-CN
3-chloro
4-OCF3



Ia.311
CF3
H
2-CN
3-CN
4-OCF3



Ia.312
CF3
H
2-CN
3-methyl
4-OCF3



Ia.313
CF3
H
2-CN
3-CF3
4-OCF3



Ia.314
CF3
H
2-CN
3-OCH3
4-OCF3



Ia.315
CF3
H
2-CN
3-OCF3
4-OCF3



Ia.316
CF3
H
2-methyl
3-fluoro
4-OCF3



Ia.317
CF3
H
2-methyl
3-chloro
4-OCF3



Ia.318
CF3
H
2-methyl
3-CN
4-OCF3



Ia.319
CF3
H
2-methyl
3-methyl
4-OCF3



Ia.320
CF3
H
2-methyl
3-CF3
4-OCF3



Ia.321
CF3
H
2-methyl
3-OCH3
4-OCF3



Ia.322
CF3
H
2-methyl
3-OCF3
4-OCF3



Ia.323
CF3
H
2-CF3
3-fluoro
4-OCF3



Ia.324
CF3
H
2-CF3
3-chloro
4-OCF3



Ia.325
CF3
H
2-CF3
3-CN
4-OCF3



Ia.326
CF3
H
2-CF3
3-methyl
4-OCF3



Ia.327
CF3
H
2-CF3
3-CF3
4-OCF3



Ia.328
CF3
H
2-CF3
3-OCH3
4-OCF3



Ia.329
CF3
H
2-CF3
3-OCF3
4-OCF3



Ia.330
CF3
H
2-OCH3
3-fluoro
4-OCF3



Ia.331
CF3
H
2-OCH3
3-chloro
4-OCF3



Ia.332
CF3
H
2-OCH3
3-CN
4-OCF3



Ia.333
CF3
H
2-OCH3
3-methyl
4-OCF3



Ia.334
CF3
H
2-OCH3
3-CF3
4-OCF3



Ia.335
CF3
H
2-OCH3
3-OCH3
4-OCF3



Ia.336
CF3
H
2-OCH3
3-OCF3
4-OCF3



Ia.337
CF3
H
2-OCF3
3-fluoro
4-OCF3



Ia.338
CF3
H
2-OCF3
3-chloro
4-OCF3



Ia.339
CF3
H
2-OCF3
3-CN
4-OCF3



Ia.340
CF3
H
2-OCF3
3-methyl
4-OCF3



Ia.341
CF3
H
2-OCF3
3-CF3
4-OCF3



Ia.342
CF3
H
2-OCF3
3-OCH3
4-OCF3



Ia.343
CF3
H
2-OCF3
3-OCF3
4-OCF3



Ia.344
CF3
H
3-fluoro
4-fluoro
5-fluoro
120-124


Ia.345
CF3
H
3-chloro
4-fluoro
5-fluoro



Ia.346
CF3
H
3-CN
4-fluoro
5-fluoro



Ia.347
CF3
H
3-CH3
4-fluoro
5-fluoro



Ia.348
CF3
H
3-CF3
4-fluoro
5-fluoro



Ia.349
CF3
H
3-OCH3
4-fluoro
5-fluoro



Ia.350
CF3
H
3-OCF3
4-fluoro
5-fluoro



Ia.351
CF3
H
3-fluoro
4-fluoro
5-chloro



Ia.352
CF3
H
3-chloro
4-fluoro
5-chloro



Ia.353
CF3
H
3-CN
4-fluoro
5-chloro



Ia.354
CF3
H
3-CH3
4-fluoro
5-chloro



Ia.355
CF3
H
3-CF3
4-fluoro
5-chloro



Ia.356
CF3
H
3-OCH3
4-fluoro
5-chloro



Ia.357
CF3
H
3-OCF3
4-fluoro
5-chloro



Ia.358
CF3
H
3-fluoro
4-fluoro
5-CN



Ia.359
CF3
H
3-chloro
4-fluoro
5-CN



Ia.360
CF3
H
3-CN
4-fluoro
5-CN



Ia.361
CF3
H
3-CH3
4-fluoro
5-CN



Ia.362
CF3
H
3-CF3
4-fluoro
5-CN



Ia.363
CF3
H
3-OCH3
4-fluoro
5-CN



Ia.364
CF3
H
3-OCF3
4-fluoro
5-CN



Ia.365
CF3
H
3-fluoro
4-fluoro
5-CH3



Ia.366
CF3
H
3-chloro
4-fluoro
5-CH3



Ia.367
CF3
H
3-CN
4-fluoro
5-CH3



Ia.368
CF3
H
3-CH3
4-fluoro
5-CH3



Ia.369
CF3
H
3-CF3
4-fluoro
5-CH3



Ia.370
CF3
H
3-OCH3
4-fluoro
5-CH3



Ia.371
CF3
H
3-OCF3
4-fluoro
5-CH3



Ia.372
CF3
H
3-fluoro
4-fluoro
5-CF3



Ia.373
CF3
H
3-chloro
4-fluoro
5-CF3



Ia.374
CF3
H
3-CN
4-fluoro
5-CF3



Ia.375
CF3
H
3-CH3
4-fluoro
5-CF3



Ia.376
CF3
H
3-CF3
4-fluoro
5-CF3



Ia.377
CF3
H
3-OCH3
4-fluoro
5-CF3



Ia.378
CF3
H
3-OCF3
4-fluoro
5-CF3



Ia.379
CF3
H
3-fluoro
4-fluoro
5-OCH3



Ia.380
CF3
H
3-chloro
4-fluoro
5-OCH3



Ia.381
CF3
H
3-CN
4-fluoro
5-OCH3



Ia.382
CF3
H
3-CH3
4-fluoro
5-OCH3



Ia.383
CF3
H
3-CF3
4-fluoro
5-OCH3



Ia.384
CF3
H
3-OCH3
4-fluoro
5-OCH3



Ia.385
CF3
H
3-OCF3
4-fluoro
5-OCH3



Ia.386
CF3
H
3-fluoro
4-fluoro
5-OCF3



Ia.387
CF3
H
3-chloro
4-fluoro
5-OCF3



Ia.388
CF3
H
3-CN
4-fluoro
5-OCF3



Ia.389
CF3
H
3-CH3
4-fluoro
5-OCF3



Ia.390
CF3
H
3-CF3
4-fluoro
5-OCF3



Ia.391
CF3
H
3-OCH3
4-fluoro
5-OCF3



Ia.392
CF3
H
3-OCF3
4-fluoro
5-OCF3



Ia.393
CF3
H
3-fluoro
4-chloro
5-fluoro



Ia.394
CF3
H
3-chloro
4-chloro
5-fluoro



Ia.395
CF3
H
3-CN
4-chloro
5-fluoro



Ia.396
CF3
H
3-CH3
4-chloro
5-fluoro



Ia.397
CF3
H
3-CF3
4-chloro
5-fluoro



Ia.398
CF3
H
3-OCH3
4-chloro
5-fluoro



Ia.399
CF3
H
3-OCF3
4-chloro
5-fluoro



Ia.400
CF3
H
3-fluoro
4-chloro
5-chloro



Ia.401
CF3
H
3-chloro
4-chloro
5-chloro



Ia.402
CF3
H
3-CN
4-chloro
5-chloro



Ia.403
CF3
H
3-CH3
4-chloro
5-chloro



Ia.404
CF3
H
3-CF3
4-chloro
5-chloro



Ia.405
CF3
H
3-OCH3
4-chloro
5-chloro



Ia.406
CF3
H
3-OCF3
4-chloro
5-chloro



Ia.407
CF3
H
3-fluoro
4-chloro
5-CN



Ia.408
CF3
H
3-chloro
4-chloro
5-CN



Ia.409
CF3
H
3-CN
4-chloro
5-CN



Ia.410
CF3
H
3-CH3
4-chloro
5-CN



Ia.411
CF3
H
3-CF3
4-chloro
5-CN



Ia.412
CF3
H
3-OCH3
4-chloro
5-CN



Ia.413
CF3
H
3-OCF3
4-chloro
5-CN



Ia.414
CF3
H
3-fluoro
4-chloro
5-CH3



Ia.415
CF3
H
3-chloro
4-chloro
5-CH3



Ia.416
CF3
H
3-CN
4-chloro
5-CH3



Ia.417
CF3
H
3-CH3
4-chloro
5-CH3



Ia.418
CF3
H
3-CF3
4-chloro
5-CH3



Ia.419
CF3
H
3-OCH3
4-chloro
5-CH3



Ia.420
CF3
H
3-OCF3
4-chloro
5-CH3



Ia.421
CF3
H
3-fluoro
4-chloro
5-CF3



Ia.422
CF3
H
3-chloro
4-chloro
5-CF3



Ia.423
CF3
H
3-CN
4-chloro
5-CF3



Ia.424
CF3
H
3-CH3
4-chloro
5-CF3



Ia.425
CF3
H
3-CF3
4-chloro
5-CF3



Ia.426
CF3
H
3-OCH3
4-chloro
5-CF3



Ia.427
CF3
H
3-OCF3
4-chloro
5-CF3



Ia.428
CF3
H
3-fluoro
4-chloro
5-OCH3



Ia.429
CF3
H
3-chloro
4-chloro
5-OCH3



Ia.430
CF3
H
3-CN
4-chloro
5-OCH3



Ia.431
CF3
H
3-CH3
4-chloro
5-OCH3



Ia.432
CF3
H
3-CF3
4-chloro
5-OCH3



Ia.433
CF3
H
3-OCH3
4-chloro
5-OCH3



Ia.434
CF3
H
3-OCF3
4-chloro
5-OCH3



Ia.435
CF3
H
3-fluoro
4-chloro
5-OCF3



Ia.436
CF3
H
3-chloro
4-chloro
5-OCF3



Ia.437
CF3
H
3-CN
4-chloro
5-OCF3



Ia.438
CF3
H
3-CH3
4-chloro
5-OCF3



Ia.439
CF3
H
3-CF3
4-chloro
5-OCF3



Ia.440
CF3
H
3-OCH3
4-chloro
5-OCF3



Ia.441
CF3
H
3-OCF3
4-chloro
5-OCF3



Ia.442
CF3
H
3-fluoro
4-CN
5-fluoro



Ia.443
CF3
H
3-chloro
4-CN
5-fluoro



Ia.444
CF3
H
3-CN
4-CN
5-fluoro



Ia.445
CF3
H
3-CH3
4-CN
5-fluoro



Ia.446
CF3
H
3-CF3
4-CN
5-fluoro



Ia.447
CF3
H
3-OCH3
4-CN
5-fluoro



Ia.448
CF3
H
3-OCF3
4-CN
5-fluoro



Ia.449
CF3
H
3-fluoro
4-CN
5-chloro



Ia.450
CF3
H
3-chloro
4-CN
5-chloro



Ia.451
CF3
H
3-CN
4-CN
5-chloro



Ia.452
CF3
H
3-CH3
4-CN
5-chloro



Ia.453
CF3
H
3-CF3
4-CN
5-chloro



Ia.454
CF3
H
3-OCH3
4-CN
5-chloro



Ia.455
CF3
H
3-OCF3
4-CN
5-chloro



Ia.456
CF3
H
3-fluoro
4-CN
5-CN



Ia.457
CF3
H
3-chloro
4-CN
5-CN



Ia.458
CF3
H
3-CN
4-CN
5-CN



Ia.459
CF3
H
3-CH3
4-CN
5-CN



Ia.460
CF3
H
3-CF3
4-CN
5-CN



Ia.461
CF3
H
3-OCH3
4-CN
5-CN



Ia.462
CF3
H
3-OCF3
4-CN
5-CN



Ia.463
CF3
H
3-fluoro
4-CN
5-CH3



Ia.464
CF3
H
3-chloro
4-CN
5-CH3



Ia.465
CF3
H
3-CN
4-CN
5-CH3



Ia.466
CF3
H
3-CH3
4-CN
5-CH3



Ia.467
CF3
H
3-CF3
4-CN
5-CH3



Ia.468
CF3
H
3-OCH3
4-CN
5-CH3



Ia.469
CF3
H
3-OCF3
4-CN
5-CH3



Ia.470
CF3
H
3-fluoro
4-CN
5-CF3



Ia.471
CF3
H
3-chloro
4-CN
5-CF3



Ia.472
CF3
H
3-CN
4-CN
5-CF3



Ia.473
CF3
H
3-CH3
4-CN
5-CF3



Ia.474
CF3
H
3-CF3
4-CN
5-CF3



Ia.475
CF3
H
3-OCH3
4-CN
5-CF3



Ia.476
CF3
H
3-OCF3
4-CN
5-CF3



Ia.477
CF3
H
3-fluoro
4-CN
5-OCH3



Ia.478
CF3
H
3-chloro
4-CN
5-OCH3



Ia.479
CF3
H
3-CN
4-CN
5-OCH3



Ia.480
CF3
H
3-CH3
4-CN
5-OCH3



Ia.481
CF3
H
3-CF3
4-CN
5-OCH3



Ia.482
CF3
H
3-OCH3
4-CN
5-OCH3



Ia.483
CF3
H
3-OCF3
4-CN
5-OCH3



Ia.484
CF3
H
3-fluoro
4-CN
5-OCF3



Ia.485
CF3
H
3-chloro
4-CN
5-OCF3



Ia.486
CF3
H
3-CN
4-CN
5-OCF3



Ia.487
CF3
H
3-CH3
4-CN
5-OCF3



Ia.488
CF3
H
3-CF3
4-CN
5-OCF3



Ia.489
CF3
H
3-OCH3
4-CN
5-OCF3



Ia.490
CF3
H
3-OCF3
4-CN
5-OCF3



Ia.491
CF3
H
3-fluoro
4-CH3
5-fluoro



Ia.492
CF3
H
3-chloro
4-CH3
5-fluoro



Ia.493
CF3
H
3-CN
4-CH3
5-fluoro



Ia.494
CF3
H
3-CH3
4-CH3
5-fluoro



Ia.495
CF3
H
3-CF3
4-CH3
5-fluoro



Ia.496
CF3
H
3-OCH3
4-CH3
5-fluoro



Ia.497
CF3
H
3-OCF3
4-CH3
5-fluoro



Ia.498
CF3
H
3-fluoro
4-CH3
5-chloro



Ia.499
CF3
H
3-chloro
4-CH3
5-chloro



Ia.500
CF3
H
3-CN
4-CH3
5-chloro



Ia.501
CF3
H
3-CH3
4-CH3
5-chloro



Ia.502
CF3
H
3-CF3
4-CH3
5-chloro



Ia.503
CF3
H
3-OCH3
4-CH3
5-chloro



Ia.504
CF3
H
3-OCF3
4-CH3
5-chloro



Ia.505
CF3
H
3-fluoro
4-CH3
5-CN



Ia.506
CF3
H
3-chloro
4-CH3
5-CN



Ia.507
CF3
H
3-CN
4-CH3
5-CN



Ia.508
CF3
H
3-CH3
4-CH3
5-CN



Ia.509
CF3
H
3-CF3
4-CH3
5-CN



Ia.510
CF3
H
3-OCH3
4-CH3
5-CN



Ia.511
CF3
H
3-OCF3
4-CH3
5-CN



Ia.512
CF3
H
3-fluoro
4-CH3
5-CH3



Ia.513
CF3
H
3-chloro
4-CH3
5-CH3



Ia.514
CF3
H
3-CN
4-CH3
5-CH3



Ia.515
CF3
H
3-CH3
4-CH3
5-CH3



Ia.516
CF3
H
3-CF3
4-CH3
5-CH3



Ia.517
CF3
H
3-OCH3
4-CH3
5-CH3



Ia.518
CF3
H
3-OCF3
4-CH3
5-CH3



Ia.519
CF3
H
3-fluoro
4-CH3
5-CF3



Ia.520
CF3
H
3-chloro
4-CH3
5-CF3



Ia.521
CF3
H
3-CN
4-CH3
5-CF3



Ia.522
CF3
H
3-CH3
4-CH3
5-CF3



Ia.523
CF3
H
3-CF3
4-CH3
5-CF3



Ia.524
CF3
H
3-OCH3
4-CH3
5-CF3



Ia.525
CF3
H
3-OCF3
4-CH3
5-CF3



Ia.526
CF3
H
3-fluoro
4-CH3
5-OCH3



Ia.527
CF3
H
3-chloro
4-CH3
5-OCH3



Ia.528
CF3
H
3-CN
4-CH3
5-OCH3



Ia.529
CF3
H
3-CH3
4-CH3
5-OCH3



Ia.530
CF3
H
3-CF3
4-CH3
5-OCH3



Ia.531
CF3
H
3-OCH3
4-CH3
5-OCH3



Ia.532
CF3
H
3-OCF3
4-CH3
5-OCH3



Ia.533
CF3
H
3-fluoro
4-CH3
5-OCF3



Ia.534
CF3
H
3-chloro
4-CH3
5-OCF3



Ia.535
CF3
H
3-CN
4-CH3
5-OCF3



Ia.536
CF3
H
3-CH3
4-CH3
5-OCF3



Ia.537
CF3
H
3-CF3
4-CH3
5-OCF3



Ia.538
CF3
H
3-OCH3
4-CH3
5-OCF3



Ia.539
CF3
H
3-OCF3
4-CH3
5-OCF3



Ia.540
CF3
H
3-fluoro
4-CF3
5-fluoro



Ia.541
CF3
H
3-chloro
4-CF3
5-fluoro



Ia.542
CF3
H
3-CN
4-CF3
5-fluoro



Ia.543
CF3
H
3-CH3
4-CF3
5-fluoro



Ia.544
CF3
H
3-CF3
4-CF3
5-fluoro



Ia.545
CF3
H
3-OCH3
4-CF3
5-fluoro



Ia.546
CF3
H
3-OCF3
4-CF3
5-fluoro



Ia.547
CF3
H
3-fluoro
4-CF3
5-chloro



Ia.548
CF3
H
3-chloro
4-CF3
5-chloro



Ia.549
CF3
H
3-CN
4-CF3
5-chloro



Ia.550
CF3
H
3-CH3
4-CF3
5-chloro



Ia.551
CF3
H
3-CF3
4-CF3
5-chloro



Ia.552
CF3
H
3-OCH3
4-CF3
5-chloro



Ia.553
CF3
H
3-OCF3
4-CF3
5-chloro



Ia.554
CF3
H
3-fluoro
4-CF3
5-CN



Ia.555
CF3
H
3-chloro
4-CF3
5-CN



Ia.556
CF3
H
3-CN
4-CF3
5-CN



Ia.557
CF3
H
3-CH3
4-CF3
5-CN



Ia.558
CF3
H
3-CF3
4-CF3
5-CN



Ia.559
CF3
H
3-OCH3
4-CF3
5-CN



Ia.560
CF3
H
3-OCF3
4-CF3
5-CN



Ia.561
CF3
H
3-fluoro
4-CF3
5-CH3



Ia.562
CF3
H
3-chloro
4-CF3
5-CH3



Ia.563
CF3
H
3-CN
4-CF3
5-CH3



Ia.564
CF3
H
3-CH3
4-CF3
5-CH3



Ia.565
CF3
H
3-CF3
4-CF3
5-CH3



Ia.566
CF3
H
3-OCH3
4-CF3
5-CH3



Ia.567
CF3
H
3-OCF3
4-CF3
5-CH3



Ia.568
CF3
H
3-fluoro
4-CF3
5-OCF3



Ia.569
CF3
H
3-chloro
4-CF3
5-CF3



Ia.570
CF3
H
3-CN
4-CF3
5-CF3



Ia.571
CF3
H
3-CH3
4-CF3
5-CF3



Ia.572
CF3
H
3-CF3
4-CF3
5-CF3



Ia.573
CF3
H
3-OCH3
4-CF3
5-CF3



Ia.574
CF3
H
3-OCF3
4-CF3
5-CF3



Ia.575
CF3
H
3-fluoro
4-CF3
5-OCH3



Ia.576
CF3
H
3-chloro
4-CF3
5-OCH3



Ia.577
CF3
H
3-CN
4-CF3
5-OCH3



Ia.578
CF3
H
3-CH3
4-CF3
5-OCH3



Ia.579
CF3
H
3-CF3
4-CF3
5-OCH3



Ia.560
CF3
H
3-OCH3
4-CF3
5-OCH3



Ia.561
CF3
H
3-OCF3
4-CF3
5-OCH3



Ia.562
CF3
H
3-fluoro
4-CF3
5-OCF3



Ia.563
CF3
H
3-chloro
4-CF3
5-OCF3



Ia.564
CF3
H
3-CN
4-CF3
5-OCF3



Ia.565
CF3
H
3-CH3
4-CF3
5-OCF3



Ia.566
CF3
H
3-CF3
4-CF3
5-OCF3



Ia.567
CF3
H
3-OCH3
4-CF3
5-OCF3



Ia.568
CF3
H
3-OCF3
4-CF3
5-OCF3



Ia.569
CF3
H
3-fluoro
4-OCH3
5-fluoro



Ia.570
CF3
H
3-chloro
4-OCH3
5-fluoro



Ia.571
CF3
H
3-CN
4-OCH3
5-fluoro



Ia.572
CF3
H
3-CH3
4-OCH3
5-fluoro



Ia.573
CF3
H
3-CF3
4-OCH3
5-fluoro



Ia.574
CF3
H
3-OCH3
4-OCH3
5-fluoro



Ia.575
CF3
H
3-OCF3
4-OCH3
5-fluoro



Ia.576
CF3
H
3-fluoro
4-OCH3
5-chloro



Ia.577
CF3
H
3-chloro
4-OCH3
5-chloro



Ia.578
CF3
H
3-CN
4-OCH3
5-chloro



Ia.579
CF3
H
3-CH3
4-OCH3
5-chloro



Ia.580
CF3
H
3-CF3
4-OCH3
5-chloro



Ia.581
CF3
H
3-OCH3
4-OCH3
5-chloro



Ia.582
CF3
H
3-OCF3
4-OCH3
5-chloro



Ia.583
CF3
H
3-fluoro
4-OCH3
5-CN



Ia.584
CF3
H
3-chloro
4-OCH3
5-CN



Ia.585
CF3
H
3-CN
4-OCH3
5-CN



Ia.586
CF3
H
3-CH3
4-OCH3
5-CN



Ia.587
CF3
H
3-CF3
4-OCH3
5-CN



Ia.588
CF3
H
3-OCH3
4-OCH3
5-CN



Ia.589
CF3
H
3-OCF3
4-OCH3
5-CN



Ia.590
CF3
H
3-fluoro
4-OCH3
5-CH3



Ia.591
CF3
H
3-chloro
4-OCH3
5-CH3



Ia.592
CF3
H
3-CN
4-OCH3
5-CH3



Ia.593
CF3
H
3-CH3
4-OCH3
5-CH3



Ia.594
CF3
H
3-CF3
4-OCH3
5-CH3



Ia.595
CF3
H
3-OCH3
4-OCH3
5-CH3



Ia.596
CF3
H
3-OCF3
4-OCH3
5-CH3



Ia.597
CF3
H
3-fluoro
4-OCH3
5-CF3



Ia.598
CF3
H
3-chloro
4-OCH3
5-CF3



Ia.599
CF3
H
3-CN
4-OCH3
5-CF3



Ia.600
CF3
H
3-CH3
4-OCH3
5-CF3



Ia.601
CF3
H
3-CF3
4-OCH3
5-CF3



Ia.602
CF3
H
3-OCH3
4-OCH3
5-CF3



Ia.603
CF3
H
3-OCF3
4-OCH3
5-CF3



Ia.604
CF3
H
3-fluoro
4-OCH3
5-OCH3



Ia.605
CF3
H
3-chloro
4-OCH3
5-OCH3



Ia.606
CF3
H
3-CN
4-OCH3
5-OCH3



Ia.607
CF3
H
3-CH3
4-OCH3
5-OCH3



Ia.608
CF3
H
3-CF3
4-OCH3
5-OCH3



Ia.609
CF3
H
3-OCH3
4-OCH3
5-OCH3



Ia.610
CF3
H
3-OCF3
4-OCH3
5-OCH3



Ia.611
CF3
H
3-fluoro
4-OCH3
5-OCF3



Ia.612
CF3
H
3-chloro
4-OCH3
5-OCF3



Ia.613
CF3
H
3-CN
4-OCH3
5-OCF3



Ia.614
CF3
H
3-CH3
4-OCH3
5-OCF3



Ia.615
CF3
H
3-CF3
4-OCH3
5-OCF3



Ia.616
CF3
H
3-OCH3
4-OCH3
5-OCF3



Ia.617
CF3
H
3-OCF3
4-OCH3
5-OCF3



Ia.618
CF3
H
3-fluoro
4-OCF3
5-fluoro



Ia.619
CF3
H
3-chloro
4-OCF3
5-fluoro



Ia.620
CF3
H
3-CN
4-OCF3
5-fluoro



Ia.621
CF3
H
3-CH3
4-OCF3
5-fluoro



Ia.622
CF3
H
3-CF3
4-OCF3
5-fluoro



Ia.623
CF3
H
3-OCH3
4-OCF3
5-fluoro



Ia.624
CF3
H
3-OCF3
4-OCF3
5-fluoro



Ia.625
CF3
H
3-fluoro
4-OCF3
5-chloro



Ia.626
CF3
H
3-chloro
4-OCF3
5-chloro



Ia.627
CF3
H
3-CN
4-OCF3
5-chloro



Ia.628
CF3
H
3-CH3
4-OCF3
5-chloro



Ia.629
CF3
H
3-CF3
4-OCF3
5-chloro



Ia.630
CF3
H
3-OCH3
4-OCF3
5-chloro



Ia.631
CF3
H
3-OCF3
4-OCF3
5-chloro



Ia.632
CF3
H
3-fluoro
4-OCF3
5-CN



Ia.633
CF3
H
3-chloro
4-OCF3
5-CN



Ia.634
CF3
H
3-CN
4-OCF3
5-CN



Ia.635
CF3
H
3-CH3
4-OCF3
5-CN



Ia.636
CF3
H
3-CF3
4-OCF3
5-CN



Ia.637
CF3
H
3-OCH3
4-OCF3
5-CN



Ia.638
CF3
H
3-OCF3
4-OCF3
5-CN



Ia.639
CF3
H
3-fluoro
4-OCF3
5-CH3



Ia.640
CF3
H
3-chloro
4-OCF3
5-CH3



Ia.641
CF3
H
3-CN
4-OCF3
5-CH3



Ia.642
CF3
H
3-CH3
4-OCF3
5-CH3



Ia.643
CF3
H
3-CF3
4-OCF3
5-CH3



Ia.644
CF3
H
3-OCH3
4-OCF3
5-CH3



Ia.645
CF3
H
3-OCF3
4-OCF3
5-CH3



Ia.646
CF3
H
3-fluoro
4-OCF3
5-CF3



Ia.647
CF3
H
3-chloro
4-OCF3
5-CF3



Ia.648
CF3
H
3-CN
4-OCF3
5-CF3



Ia.649
CF3
H
3-CH3
4-OCF3
5-CF3



Ia.650
CF3
H
3-CF3
4-OCF3
5-CF3



Ia.651
CF3
H
3-OCH3
4-OCF3
5-CF3



Ia.652
CF3
H
3-OCF3
4-OCF3
5-CF3



Ia.653
CF3
H
3-fluoro
4-OCF3
5-OCH3



Ia.654
CF3
H
3-chloro
4-OCF3
5-OCH3



Ia.655
CF3
H
3-CN
4-OCF3
5-OCH3



Ia.656
CF3
H
3-CH3
4-OCF3
5-OCH3



Ia.657
CF3
H
3-CF3
4-OCF3
5-OCH3



Ia.658
CF3
H
3-OCH3
4-OCF3
5-OCH3



Ia.659
CF3
H
3-OCF3
4-OCF3
5-OCH3



Ia.660
CF3
H
3-fluoro
4-OCF3
5-OCF3



Ia.661
CF3
H
3-chloro
4-OCF3
5-OCF3



Ia.662
CF3
H
3-CN
4-OCF3
5-OCF3



Ia.663
CF3
H
3-CH3
4-OCF3
5-OCF3



Ia.664
CF3
H
3-CF3
4-OCF3
5-OCF3



Ia.665
CF3
H
3-OCH3
4-OCF3
5-OCF3



Ia.666
CF3
H
3-OCF3
4-OCF3
5-OCF3



Ia.667
CF3
H
2-fluoro
4-fluoro
5-fluoro
110-113


Ia.668
CF3
H
2-fluoro
4-fluoro
5-chloro



Ia.669
CF3
H
2-fluoro
4-fluoro
5-CN



Ia.670
CF3
H
2-fluoro
4-fluoro
5-CH3



Ia.671
CF3
H
2-fluoro
4-fluoro
5-CF3



Ia.672
CF3
H
2-fluoro
4-fluoro
5-OCH3



Ia.673
CF3
H
2-fluoro
4-fluoro
5-OCF3



Ia.674
CF3
H
2-chloro
4-fluoro
5-fluoro



Ia.675
CF3
H
2-chloro
4-fluoro
5-chloro



Ia.676
CF3
H
2-chloro
4-fluoro
5-CN



Ia.677
CF3
H
2-chloro
4-fluoro
5-CH3



Ia.678
CF3
H
2-chloro
4-fluoro
5-CF3



Ia.679
CF3
H
2-chloro
4-fluoro
5-OCH3



Ia.680
CF3
H
2-chloro
4-fluoro
5-OCF3



Ia.681
CF3
H
2-CN
4-fluoro
5-fluoro



Ia.682
CF3
H
2-CN
4-fluoro
5-chloro



Ia.683
CF3
H
2-CN
4-fluoro
5-CN



Ia.684
CF3
H
2-CN
4-fluoro
5-CH3



Ia.685
CF3
H
2-CN
4-fluoro
5-CF3



Ia.686
CF3
H
2-CN
4-fluoro
5-OCH3



Ia.687
CF3
H
2-CN
4-fluoro
5-OCF3



Ia.688
CF3
H
2-methyl
4-fluoro
5-fluoro



Ia.689
CF3
H
2-methyl
4-fluoro
5-chloro



Ia.690
CF3
H
2-methyl
4-fluoro
5-CN



Ia.691
CF3
H
2-methyl
4-fluoro
5-CH3



Ia.692
CF3
H
2-methyl
4-fluoro
5-CF3



Ia.693
CF3
H
2-methyl
4-fluoro
5-OCH3



Ia.694
CF3
H
2-methyl
4-fluoro
5-OCF3



Ia.695
CF3
H
2-CF3
4-fluoro
5-fluoro



Ia.696
CF3
H
2-CF3
4-fluoro
5-chloro



Ia.697
CF3
H
2-CF3
4-fluoro
5-CN



Ia.698
CF3
H
2-CF3
4-fluoro
5-CH3



Ia.699
CF3
H
2-CF3
4-fluoro
5-CF3



Ia.700
CF3
H
2-CF3
4-fluoro
5-OCH3



Ia.701
CF3
H
2-CF3
4-fluoro
5-OCF3



Ia.702
CF3
H
2-OCH3
4-fluoro
5-fluoro



Ia.703
CF3
H
2-OCH3
4-fluoro
5-chloro



Ia.704
CF3
H
2-OCH3
4-fluoro
5-CN



Ia.705
CF3
H
2-OCH3
4-fluoro
5-CH3



Ia.706
CF3
H
2-OCH3
4-fluoro
5-CF3



Ia.707
CF3
H
2-OCH3
4-fluoro
5-OCH3



Ia.708
CF3
H
2-OCH3
4-fluoro
5-OCF3



Ia.709
CF3
H
2-OCF3
4-fluoro
5-fluoro



Ia.710
CF3
H
2-OCF3
4-fluoro
5-chloro



Ia.711
CF3
H
2-OCF3
4-fluoro
5-CN



Ia.712
CF3
H
2-OCF3
4-fluoro
5-CH3



Ia.713
CF3
H
2-OCF3
4-fluoro
5-CF3



Ia.714
CF3
H
2-OCF3
4-fluoro
5-OCH3



Ia.715
CF3
H
2-OCF3
4-fluoro
5-OCF3



Ia.716
CF3
H
2-fluoro
4-chloro
5-fluoro



Ia.717
CF3
H
2-fluoro
4-chloro
5-chloro



Ia.718
CF3
H
2-fluoro
4-chloro
5-CN



Ia.719
CF3
H
2-fluoro
4-chloro
5-CH3
106-108


Ia.720
CF3
H
2-fluoro
4-chloro
5-CF3



Ia.721
CF3
H
2-fluoro
4-chloro
5-OCH3
119-121


Ia.722
CF3
H
2-fluoro
4-chloro
5-OCF3



Ia.723
CF3
H
2-chloro
4-chloro
5-fluoro



Ia.724
CF3
H
2-chloro
4-chloro
5-chloro



Ia.725
CF3
H
2-chloro
4-chloro
5-CN



Ia.726
CF3
H
2-chloro
4-chloro
5-CH3



Ia.727
CF3
H
2-chloro
4-chloro
5-CF3



Ia.728
CF3
H
2-chloro
4-chloro
5-OCH3



Ia.729
CF3
H
2-chloro
4-chloro
5-OCF3



Ia.730
CF3
H
2-CN
4-chloro
5-fluoro



Ia.731
CF3
H
2-CN
4-chloro
5-chloro



Ia.732
CF3
H
2-CN
4-chloro
5-CN



Ia.733
CF3
H
2-CN
4-chloro
5-CH3



Ia.734
CF3
H
2-CN
4-chloro
5-CF3



Ia.735
CF3
H
2-CN
4-chloro
5-OCH3



Ia.736
CF3
H
2-CN
4-chloro
5-OCF3



Ia.737
CF3
H
2-methyl
4-chloro
5-fluoro



Ia.738
CF3
H
2-methyl
4-chloro
5-chloro



Ia.739
CF3
H
2-methyl
4-chloro
5-CN



Ia.740
CF3
H
2-methyl
4-chloro
5-CH3



Ia.741
CF3
H
2-methyl
4-chloro
5-CF3



Ia.742
CF3
H
2-methyl
4-chloro
5-OCH3



Ia.743
CF3
H
2-methyl
4-chloro
5-OCF3



Ia.744
CF3
H
2-CF3
4-chloro
5-fluoro



Ia.745
CF3
H
2-CF3
4-chloro
5-chloro



Ia.746
CF3
H
2-CF3
4-chloro
5-CN



Ia.747
CF3
H
2-CF3
4-chloro
5-CH3



Ia.748
CF3
H
2-CF3
4-chloro
5-CF3



Ia.749
CF3
H
2-CF3
4-chloro
5-OCH3



Ia.750
CF3
H
2-CF3
4-chloro
5-OCF3



Ia.751
CF3
H
2-OCH3
4-chloro
5-fluoro



Ia.752
CF3
H
2-OCH3
4-chloro
5-chloro



Ia.753
CF3
H
2-OCH3
4-chloro
5-CN



Ia.754
CF3
H
2-OCH3
4-chloro
5-CH3



Ia.755
CF3
H
2-OCH3
4-chloro
5-CF3



Ia.756
CF3
H
2-OCH3
4-chloro
5-OCH3



Ia.757
CF3
H
2-OCH3
4-chloro
5-OCF3



Ia.758
CF3
H
2-OCF3
4-chloro
5-fluoro



Ia.759
CF3
H
2-OCF3
4-chloro
5-chloro



Ia.760
CF3
H
2-OCF3
4-chloro
5-CN



Ia.761
CF3
H
2-OCF3
4-chloro
5-CH3



Ia.762
CF3
H
2-OCF3
4-chloro
5-CF3



Ia.763
CF3
H
2-OCF3
4-chloro
5-OCH3



Ia.764
CF3
H
2-OCF3
4-chloro
5-OCF3



Ia.765
CF3
H
2-fluoro
4-CN
5-fluoro



Ia.766
CF3
H
2-fluoro
4-CN
5-chloro



Ia.767
CF3
H
2-fluoro
4-CN
5-CN



Ia.768
CF3
H
2-fluoro
4-CN
5-CH3



Ia.769
CF3
H
2-fluoro
4-CN
5-CF3



Ia.770
CF3
H
2-fluoro
4-CN
5-OCH3



Ia.771
CF3
H
2-fluoro
4-CN
5-OCF3



Ia.772
CF3
H
2-chloro
4-CN
5-fluoro



Ia.773
CF3
H
2-chloro
4-CN
5-chloro



Ia.774
CF3
H
2-chloro
4-CN
5-CN



Ia.775
CF3
H
2-chloro
4-CN
5-CH3



Ia.776
CF3
H
2-chloro
4-CN
5-CF3



Ia.777
CF3
H
2-chloro
4-CN
5-OCH3



Ia.778
CF3
H
2-chloro
4-CN
5-OCF3



Ia.779
CF3
H
2-CN
4-CN
5-fluoro



Ia.780
CF3
H
2-CN
4-CN
5-chloro



Ia.781
CF3
H
2-CN
4-CN
5-CN



Ia.782
CF3
H
2-CN
4-CN
5-CH3



Ia.783
CF3
H
2-CN
4-CN
5-CF3



Ia.784
CF3
H
2-CN
4-CN
5-OCH3



Ia.785
CF3
H
2-CN
4-CN
5-OCF3



Ia.786
CF3
H
2-methyl
4-CN
5-fluoro



Ia.787
CF3
H
2-methyl
4-CN
5-chloro



Ia.788
CF3
H
2-methyl
4-CN
5-CN



Ia.789
CF3
H
2-methyl
4-CN
5-CH3



Ia.790
CF3
H
2-methyl
4-CN
5-CF3



Ia.791
CF3
H
2-methyl
4-CN
5-OCH3



Ia.792
CF3
H
2-methyl
4-CN
5-OCF3



Ia.793
CF3
H
2-CF3
4-CN
5-fluoro



Ia.794
CF3
H
2-CF3
4-CN
5-chloro



Ia.795
CF3
H
2-CF3
4-CN
5-CN



Ia.796
CF3
H
2-CF3
4-CN
5-CH3



Ia.797
CF3
H
2-CF3
4-CN
5-CF3



Ia.798
CF3
H
2-CF3
4-CN
5-OCH3



Ia.799
CF3
H
2-CF3
4-CN
5-OCF3



Ia.800
CF3
H
2-OCH3
4-CN
5-fluoro



Ia.801
CF3
H
2-OCH3
4-CN
5-chloro



Ia.802
CF3
H
2-OCH3
4-CN
5-CN



Ia.803
CF3
H
2-OCH3
4-CN
5-CH3



Ia.804
CF3
H
2-OCH3
4-CN
5-CF3



Ia.805
CF3
H
2-OCH3
4-CN
5-OCH3



Ia.806
CF3
H
2-OCH3
4-CN
5-OCF3



Ia.807
CF3
H
2-OCF3
4-CN
5-fluoro



Ia.808
CF3
H
2-OCF3
4-CN
5-chloro



Ia.809
CF3
H
2-OCF3
4-CN
5-CN



Ia.810
CF3
H
2-OCF3
4-CN
5-CH3



Ia.811
CF3
H
2-OCF3
4-CN
5-CF3



Ia.812
CF3
H
2-OCF3
4-CN
5-OCH3



Ia.813
CF3
H
2-OCF3
4-CN
5-OCF3



Ia.814
CF3
H
2-fluoro
4-CH3
5-fluoro



Ia.815
CF3
H
2-fluoro
4-CH3
5-chloro



Ia.816
CF3
H
2-fluoro
4-CH3
5-CN



Ia.817
CF3
H
2-fluoro
4-CH3
5-CH3



Ia.818
CF3
H
2-fluoro
4-CH3
5-CF3



Ia.819
CF3
H
2-fluoro
4-CH3
5-OCH3



Ia.820
CF3
H
2-fluoro
4-CH3
5-OCF3



Ia.821
CF3
H
2-chloro
4-CH3
5-fluoro



Ia.822
CF3
H
2-chloro
4-CH3
5-chloro



Ia.823
CF3
H
2-chloro
4-CH3
5-CN



Ia.824
CF3
H
2-chloro
4-CH3
5-CH3



Ia.825
CF3
H
2-chloro
4-CH3
5-CF3



Ia.826
CF3
H
2-chloro
4-CH3
5-OCH3



Ia.827
CF3
H
2-chloro
4-CH3
5-OCF3



Ia.828
CF3
H
2-CN
4-CH3
5-fluoro



Ia.829
CF3
H
2-CN
4-CH3
5-chloro



Ia.830
CF3
H
2-CN
4-CH3
5-CN



Ia.831
CF3
H
2-CN
4-CH3
5-CH3



Ia.832
CF3
H
2-CN
4-CH3
5-CF3



Ia.833
CF3
H
2-CN
4-CH3
5-OCH3



Ia.834
CF3
H
2-CN
4-CH3
5-OCF3



Ia.835
CF3
H
2-methyl
4-CH3
5-fluoro



Ia.836
CF3
H
2-methyl
4-CH3
5-chloro



Ia.837
CF3
H
2-methyl
4-CH3
5-CN



Ia.838
CF3
H
2-methyl
4-CH3
5-CH3



Ia.839
CF3
H
2-methyl
4-CH3
5-CF3



Ia.840
CF3
H
2-methyl
4-CH3
5-OCH3



Ia.841
CF3
H
2-methyl
4-CH3
5-OCF3



Ia.842
CF3
H
2-CF3
4-CH3
5-fluoro



Ia.843
CF3
H
2-CF3
4-CH3
5-chloro



Ia.844
CF3
H
2-CF3
4-CH3
5-CN



Ia.845
CF3
H
2-CF3
4-CH3
5-CH3



Ia.846
CF3
H
2-CF3
4-CH3
5-CF3



Ia.847
CF3
H
2-CF3
4-CH3
5-OCH3



Ia.848
CF3
H
2-CF3
4-CH3
5-OCF3



Ia.849
CF3
H
2-OCH3
4-CH3
5-fluoro



Ia.850
CF3
H
2-OCH3
4-CH3
5-chloro



Ia.851
CF3
H
2-OCH3
4-CH3
5-CN



Ia.852
CF3
H
2-OCH3
4-CH3
5-CH3



Ia.853
CF3
H
2-OCH3
4-CH3
5-CF3



Ia.854
CF3
H
2-OCH3
4-CH3
5-OCH3



Ia.855
CF3
H
2-OCH3
4-CH3
5-OCF3



Ia.856
CF3
H
2-OCF3
4-CH3
5-fluoro



Ia.857
CF3
H
2-OCF3
4-CH3
5-chloro



Ia.858
CF3
H
2-OCF3
4-CH3
5-CN



Ia.859
CF3
H
2-OCF3
4-CH3
5-CH3



Ia.860
CF3
H
2-OCF3
4-CH3
5-CF3



Ia.861
CF3
H
2-OCF3
4-CH3
5-OCH3



Ia.862
CF3
H
2-OCF3
4-CH3
5-OCF3



Ia.863
CF3
H
2-fluoro
4-CF3
5-fluoro



Ia.864
CF3
H
2-fluoro
4-CF3
5-chloro



Ia.865
CF3
H
2-fluoro
4-CF3
5-CN



Ia.866
CF3
H
2-fluoro
4-CF3
5-CH3



Ia.867
CF3
H
2-fluoro
4-CF3
5-CF3



Ia.868
CF3
H
2-fluoro
4-CF3
5-OCH3



Ia.869
CF3
H
2-fluoro
4-CF3
5-OCF3



Ia.870
CF3
H
2-chloro
4-CF3
5-fluoro



Ia.871
CF3
H
2-chloro
4-CF3
5-chloro



Ia.872
CF3
H
2-chloro
4-CF3
5-CN



Ia.873
CF3
H
2-chloro
4-CF3
5-CH3



Ia.874
CF3
H
2-chloro
4-CF3
5-CF3



Ia.875
CF3
H
2-chloro
4-CF3
5-OCH3



Ia.876
CF3
H
2-chloro
4-CF3
5-OCF3



Ia.877
CF3
H
2-CN
4-CF3
5-fluoro



Ia.878
CF3
H
2-CN
4-CF3
5-chloro



Ia.879
CF3
H
2-CN
4-CF3
5-CN



Ia.880
CF3
H
2-CN
4-CF3
5-CH3



Ia.881
CF3
H
2-CN
4-CF3
5-CF3



Ia.882
CF3
H
2-CN
4-CF3
5-OCH3



Ia.883
CF3
H
2-CN
4-CF3
5-OCF3



Ia.884
CF3
H
2-methyl
4-CF3
5-fluoro



Ia.885
CF3
H
2-methyl
4-CF3
5-chloro



Ia.886
CF3
H
2-methyl
4-CF3
5-CN



Ia.887
CF3
H
2-methyl
4-CF3
5-CH3



Ia.888
CF3
H
2-methyl
4-CF3
5-CF3



Ia.889
CF3
H
2-methyl
4-CF3
5-OCH3



Ia.890
CF3
H
2-methyl
4-CF3
5-OCF3



Ia.891
CF3
H
2-CF3
4-CF3
5-fluoro



Ia.892
CF3
H
2-CF3
4-CF3
5-chloro



Ia.893
CF3
H
2-CF3
4-CF3
5-CN



Ia.894
CF3
H
2-CF3
4-CF3
5-CH3



Ia.895
CF3
H
2-CF3
4-CF3
5-CF3



Ia.896
CF3
H
2-CF3
4-CF3
5-OCH3



Ia.897
CF3
H
2-CF3
4-CF3
5-OCF3



Ia.898
CF3
H
2-OCH3
4-CF3
5-fluoro



Ia.899
CF3
H
2-OCH3
4-CF3
5-chloro



Ia.900
CF3
H
2-OCH3
4-CF3
5-CN



Ia.901
CF3
H
2-OCH3
4-CF3
5-CH3



Ia.902
CF3
H
2-OCH3
4-CF3
5-CF3



Ia.903
CF3
H
2-OCH3
4-CF3
5-OCH3



Ia.904
CF3
H
2-OCH3
4-CF3
5-OCF3



Ia.905
CF3
H
2-OCF3
4-CF3
5-fluoro



Ia.906
CF3
H
2-OCF3
4-CF3
5-chloro



Ia.907
CF3
H
2-OCF3
4-CF3
5-CN



Ia.908
CF3
H
2-OCF3
4-CF3
5-CH3



Ia.909
CF3
H
2-OCF3
4-CF3
5-CF3



Ia.910
CF3
H
2-OCF3
4-CF3
5-OCH3



Ia.911
CF3
H
2-OCF3
4-CF3
5-OCF3



Ia.912
CF3
H
2-fluoro
4-OCH3
5-fluoro



Ia.913
CF3
H
2-fluoro
4-OCH3
5-chloro



Ia.914
CF3
H
2-fluoro
4-OCH3
5-CN



Ia.915
CF3
H
2-fluoro
4-OCH3
5-CH3



Ia.916
CF3
H
2-fluoro
4-OCH3
5-CF3



Ia.917
CF3
H
2-fluoro
4-OCH3
5-OCH3



Ia.918
CF3
H
2-fluoro
4-OCH3
5-OCF3



Ia.919
CF3
H
2-chloro
4-OCH3
5-fluoro



Ia.920
CF3
H
2-chloro
4-OCH3
5-chloro



Ia.921
CF3
H
2-chloro
4-OCH3
5-CN



Ia.922
CF3
H
2-chloro
4-OCH3
5-CH3



Ia.923
CF3
H
2-chloro
4-OCH3
5-CF3



Ia.924
CF3
H
2-chloro
4-OCH3
5-OCH3



Ia.925
CF3
H
2-chloro
4-OCH3
5-OCF3



Ia.926
CF3
H
2-CN
4-OCH3
5-fluoro



Ia.927
CF3
H
2-CN
4-OCH3
5-chloro



Ia.928
CF3
H
2-CN
4-OCH3
5-CN



Ia.929
CF3
H
2-CN
4-OCH3
5-CH3



Ia.930
CF3
H
2-CN
4-OCH3
5-CF3



Ia.931
CF3
H
2-CN
4-OCH3
5-OCH3



Ia.932
CF3
H
2-CN
4-OCH3
5-OCF3



Ia.933
CF3
H
2-methyl
4-OCH3
5-fluoro



Ia.934
CF3
H
2-methyl
4-OCH3
5-chloro



Ia.935
CF3
H
2-methyl
4-OCH3
5-CN



Ia.936
CF3
H
2-methyl
4-OCH3
5-CH3



Ia.937
CF3
H
2-methyl
4-OCH3
5-CF3



Ia.938
CF3
H
2-methyl
4-OCH3
5-OCH3



Ia.939
CF3
H
2-methyl
4-OCH3
5-OCF3



Ia.940
CF3
H
2-CF3
4-OCH3
5-fluoro



Ia.941
CF3
H
2-CF3
4-OCH3
5-chloro



Ia.942
CF3
H
2-CF3
4-OCH3
5-CN



Ia.943
CF3
H
2-CF3
4-OCH3
5-CH3



Ia.944
CF3
H
2-CF3
4-OCH3
5-CF3



Ia.945
CF3
H
2-CF3
4-OCH3
5-OCH3



Ia.946
CF3
H
2-CF3
4-OCH3
5-OCF3



Ia.947
CF3
H
2-OCH3
4-OCH3
5-fluoro



Ia.948
CF3
H
2-OCH3
4-OCH3
5-chloro



Ia.949
CF3
H
2-OCH3
4-OCH3
5-CN



Ia.950
CF3
H
2-OCH3
4-OCH3
5-CH3



Ia.951
CF3
H
2-OCH3
4-OCH3
5-CF3



Ia.952
CF3
H
2-OCH3
4-OCH3
5-OCH3



Ia.953
CF3
H
2-OCH3
4-OCH3
5-OCF3



Ia.954
CF3
H
2-OCF3
4-OCH3
5-fluoro



Ia.955
CF3
H
2-OCF3
4-OCH3
5-chloro



Ia.956
CF3
H
2-OCF3
4-OCH3
5-CN



Ia.957
CF3
H
2-OCF3
4-OCH3
5-CH3



Ia.958
CF3
H
2-OCF3
4-OCH3
5-CF3



Ia.959
CF3
H
2-OCF3
4-OCH3
5-OCH3



Ia.960
CF3
H
2-OCF3
4-OCH3
5-OCF3



Ia.961
CF3
H
2-fluoro
4-OCF3
5-fluoro



Ia.962
CF3
H
2-fluoro
4-OCF3
5-chloro



Ia.963
CF3
H
2-fluoro
4-OCF3
5-CN



Ia.964
CF3
H
2-fluoro
4-OCF3
5-CH3



Ia.965
CF3
H
2-fluoro
4-OCF3
5-CF3



Ia.966
CF3
H
2-fluoro
4-OCF3
5-OCH3



Ia.967
CF3
H
2-fluoro
4-OCF3
5-OCF3



Ia.968
CF3
H
2-chloro
4-OCF3
5-fluoro



Ia.969
CF3
H
2-chloro
4-OCF3
5-chloro



Ia.970
CF3
H
2-chloro
4-OCF3
5-CN



Ia.971
CF3
H
2-chloro
4-OCF3
5-CH3



Ia.972
CF3
H
2-chloro
4-OCF3
5-CF3



Ia.973
CF3
H
2-chloro
4-OCF3
5-OCH3



Ia.974
CF3
H
2-chloro
4-OCF3
5-OCF3



Ia.975
CF3
H
2-CN
4-OCF3
5-fluoro



Ia.976
CF3
H
2-CN
4-OCF3
5-chloro



Ia.977
CF3
H
2-CN
4-OCF3
5-CN



Ia.978
CF3
H
2-CN
4-OCF3
5-CH3



Ia.979
CF3
H
2-CN
4-OCF3
5-CF3



Ia.980
CF3
H
2-CN
4-OCF3
5-OCH3



Ia.981
CF3
H
2-CN
4-OCF3
5-OCF3



Ia.982
CF3
H
2-methyl
4-OCF3
5-fluoro



Ia.983
CF3
H
2-methyl
4-OCF3
5-chloro



Ia.984
CF3
H
2-methyl
4-OCF3
5-CN



Ia.985
CF3
H
2-methyl
4-OCF3
5-CH3



Ia.986
CF3
H
2-methyl
4-OCF3
5-CF3



Ia.987
CF3
H
2-methyl
4-OCF3
5-OCH3



Ia.988
CF3
H
2-methyl
4-OCF3
5-OCF3



Ia.989
CF3
H
2-CF3
4-OCF3
5-fluoro



Ia.990
CF3
H
2-CF3
4-OCF3
5-chloro



Ia.991
CF3
H
2-CF3
4-OCF3
5-CN



Ia.992
CF3
H
2-CF3
4-OCF3
5-CH3



Ia.993
CF3
H
2-CF3
4-OCF3
5-CF3



Ia.994
CF3
H
2-CF3
4-OCF3
5-OCH3



Ia.995
CF3
H
2-CF3
4-OCF3
5-OCF3



Ia.996
CF3
H
2-OCH3
4-OCF3
5-fluoro



Ia.997
CF3
H
2-OCH3
4-OCF3
5-chloro



Ia.998
CF3
H
2-OCH3
4-OCF3
5-CN



Ia.999
CF3
H
2-OCH3
4-OCF3
5-CH3



Ia.1000
CF3
H
2-OCH3
4-OCF3
5-CF3



Ia.1001
CF3
H
2-OCH3
4-OCF3
5-OCH3



Ia.1002
CF3
H
2-OCH3
4-OCF3
5-OCF3



Ia.1003
CF3
H
2-OCF3
4-OCF3
5-fluoro



Ia.1004
CF3
H
2-OCF3
4-OCF3
5-chloro



Ia.1005
CF3
H
2-OCF3
4-OCF3
5-CN



Ia.1006
CF3
H
2-OCF3
4-OCF3
5-CH3



Ia.1007
CF3
H
2-OCF3
4-OCF3
5-CF3



Ia.1008
CF3
H
2-OCF3
4-OCF3
5-OCH3



Ia.1009
CF3
H
2-OCF3
4-OCF3
5-OCF3









Particular preference is furthermore given to 1-methylpyrazol-4-ylcarboxanilides of the formulae Ib to If, in particular to

    
    
        the compounds Ib.1 to Ib.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R2 is fluorine:
    
    






    
    
        the compounds Ic.1 to Ic.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R2 is chlorine:
    
    






    
    
        the compounds Id.1 to Id.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R1 is difluoromethyl:
    
    














Id








 










Compound
M.p. [° C.]







No. Id. 721
150-152



No. Id. 719
120-122



No. Id. 667
122-125



No. Id. 344
156-158










    
    
        the compounds Ie.1 to Ie.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R1 is difluoromethyl and R2 is fluorine:
    
    






    
    
        the compounds If.1 to If.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R1 is difluoromethyl and R2 is chlorine:
    
    






    
    
        the compounds Ig.1 to Ig.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R1 is fluoromethyl:
    
    














Ig








 










Compound
M.p. [° C.]







No. Ig. 344
152-156



No. Ig. 1
126-129










    
    
        the compounds Ih.1 to Ih.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R1 is CF2Cl:
    
    














Ih








 










Compound
M.p. [° C.]







No. Ih. 344
158-161










    
    
        the compounds Ij.1 to Ij.1009 which differ from the corresponding compounds Ia.1 to Ia.1009 only in that R1 is chlorofluoromethyl:
    
    














Ij








 










Compound
M.p. [° C.]







No. Ij. 344
154-157










Very particular preference is given to
N-(2′-fluoro-4′-chloro-5′-methoxybiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′-fluoro-4′-chloro-5′-methylbiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoro-methyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-tri-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′-fluoro-4′-chloro-5′-methoxy-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′,3′,4′-tri-fluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′-fluoro-4′-chloro-5′-methylbiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoro-methyl-1-methyl-1H-pyrazole-4-carboxamide and N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.
Preference is given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles.
Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins.
Preference is given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides.
Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds.
Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates.
Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides.
Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl, carbendazim and ethaboxam.
Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl and carbendazim.
Very particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of epoxiconazole, fluquinconazole, flutriafol, metconazole, tebuconazole, triticonazole, prochloraz and carbendazim.
Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin and trifloxystrobin.
Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins selected from the group consisting of kresoxim-methyl, orysastrobin and pyraclostrobin.
Very particular preference is also given to mixtures of a compound of the formula I with pyraclostrobin.
Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, flumorph, fluopicolide (picobenzamid), zoxamide, carpropamid and mandipropamid.
Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, zoxamide and carpropamid.
Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds selected from the group consisting of fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen, in particular fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen.
Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds selected from the group consisting of pyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione, vinclozolin, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluoro-phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine and quinoxyfen, in particular pyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione, vinclozolin and quinoxyfen.
Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates selected from the group consisting of mancozeb, metiram, propineb, thiram, iprovalicarb, flubenthiavalicarb and propamocarb.
Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates selected from the group consisting of mancozeb and metiram.
Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides selected from the group consisting of dithianon, fentin salts, such as fentin acetate, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, chlorothalonil, dichlofluanid, thiophanate-methyl, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, cymoxanil, metrafenone and spiroxamine.
Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides selected from the group consisting of phosphorous acid and its salts, chlorothalonil and metrafenone.
Preference is also given to three-component mixtures of one compound of the formula I with two of the active compounds II mentioned above.
Preferred active compound combinations are listed in Tables 3 to 9 below:







TABLE 3







Active compound combinations of compounds


I with active compounds II of group A):









Mixture
Compound of the formula I (X = oxygen)
Active compound II





No. A.1
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.2
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.3
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.4
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.5
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.6
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.7
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.8
R1 = CHF2; R2 = Cl; R6 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.9
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.10
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.11
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.12
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.13
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.14
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.15
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.16
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.17
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.18
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.19
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.20
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.21
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.22
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.23
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.24
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
epoxiconazole


No. A.25
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.26
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.27
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.28
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.29
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.30
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.31
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.32
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.33
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.34
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.35
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.36
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.37
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.38
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.39
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.40
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.41
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.42
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.43
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.44
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.45
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.46
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.47
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.48
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metconazole


No. A.49
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.50
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.51
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.52
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.53
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.54
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.55
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.56
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.57
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.58
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.59
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.60
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.61
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.62
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.63
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.64
R1 = CH2F; R2 - H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.65
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.66
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No, A.67
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R& = 5-F
tebuconazole


No. A.68
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R6 = 5-F
tebuconazole


No. A.69
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.70
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.71
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.72
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
tebuconazole


No. A.73
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.74
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.75
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.76
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.77
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.78
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.79
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.80
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R6 = 5-F
fluquinconazole


No. A.81
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.82
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.83
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.84
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.85
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.86
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.87
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.88
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.89
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.90
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.91
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.92
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.93
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.94
Ri = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.95
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.96
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
fluquinconazole


No. A.97
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.98
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.99
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.100
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.101
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.102
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.103
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.104
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.105
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.106
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.107
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.108
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.109
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.110
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.111
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.112
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.113
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.114
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.115
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.116
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.117
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.118
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.119
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.120
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
flutriafol


No. A.121
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.122
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.123
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.124
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.125
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.126
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.127
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.128
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.129
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.130
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.131
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.132
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.133
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.134
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.135
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.136
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.137
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.138
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.139
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.140
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.141
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.142
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.143
R1 = CF3; R2 = F; RJ = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.144
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
triticonazole


No. A.145
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R6 = 5-F
prochloraz


No. A.146
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.147
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.148
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.149
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.150
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.151
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.152
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.153
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.154
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.155
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.156
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.157
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.158
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.159
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.160
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.161
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.162
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.163
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.164
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.165
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.166
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.167
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.168
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
prochloraz


No. A.169
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.170
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.171
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.172
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.173
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.174
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.175
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.176
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.177
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.178
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.179
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.180
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.181
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F;. R5 = 5-F
carbendazim


No. A.182
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.183
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.184
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.185
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.186
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.187
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.188
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.189
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.190
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.191
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim


No. A.192
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
carbendazim
















TABLE 4







Active compound combinations of compounds I with active compounds II of group B):











Active compound


Mixture
Compounds of the formula I (X = oxygen)
II





No. B.1
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.2
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.3
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.4
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.5
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.6
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.7
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.8
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.9
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.10
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.11
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.12
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.13
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.14
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.15
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.16
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.17
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.18
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.19
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.20
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.21
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.22
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.23
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.24
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
kresoxim-methyl


No. B.25
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.26
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.27
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.28
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.29
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.30
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.31
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.32
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.33
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.34
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.35
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.36
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.37
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.38
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.39
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.40
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.41
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.42
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.43
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.44
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.45
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.46
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.47
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.48
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyraclostrobin


No. B.49
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.50
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.51
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.52
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.53
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.54
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.55
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.56
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.57
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.58
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.59
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.60
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.61
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.62
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.63
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.64
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.65
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.66
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.67
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.68
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.69
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.70
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.71
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin


No. B.72
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
orysastrobin
















TABLE 5







Active compound combinations of compounds I with active compounds II of group C):











Active compound


Mixture
Compounds of the formula I (X = oxygen)
II





No. C.1
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.2
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.3
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.4
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.5
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.6
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.7
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.8
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.9
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.10
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.11
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.12
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.13
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.14
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.15
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.16
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.17
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.18
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.19
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.20
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.21
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.22
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.23
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph


No. C.24
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
dimethomorph
















TABLE 6







Active compound combinations of compounds I with active compounds II of group D):









Mixture
Compounds of the formula I (X = oxygen)
Active compound II





No. D.1
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.2
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.3
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.4
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.5
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.6
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.7
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.8
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.9
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.10
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.11
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.12
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.13
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.14
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.15
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.16
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.17
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.18
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.19
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.20
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.21
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.22
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.23
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.24
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
pyrimethanil


No. D.25
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.26
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.27
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.28
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.29
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.30
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.31
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.32
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.33
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.34
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.35
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.36
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.37
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.38
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.39
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.40
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.41
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.42
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.43
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.44
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.45
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.46
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.47
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.48
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
5-chloro-7-(4-methyl-




piperidin-1-yl)-6-(2,4,6-




trifluorophenyl)-[1,2,4]tri-




azolo[1,5-a]pyrimidine


No. D.49
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.50
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.51
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.52
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.53
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.54
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.55
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.56
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.57
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.58
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.59
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.60
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.61
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.62
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.63
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.64
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.65
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.66
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.67
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.68
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.69
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.70
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.71
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.72
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
dodemorph


No. D.73
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.74
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.75
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.76
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.77
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.78
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.79
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.80
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.81
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.82
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.83
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.84
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.85
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.86
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.87
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.88
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.89
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.90
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.91
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.92
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.93
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.94
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.95
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.96
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
fenpropimorph


No. D.97
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


No. D.98
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


No. D.99
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


No.
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.100


No.
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.101


No.
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.102


No.
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.103


No.
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.104


No.
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.105


No.
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.106


No.
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.107


No.
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
tridemorph


D.108


No.
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.109


No.
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.110


No.
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.111


No.
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.112


No.
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.113


No.
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.114


No.
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.115


No.
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.116


No.
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.117


No.
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.118


No.
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.119


No.
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
tridemorph


D.120


No.
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.121


No.
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.122


No.
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.123


No.
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.124


No.
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.125


No.
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.126


No.
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.127


No.
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.128


No.
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.129


No.
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.130


No.
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.131


No.
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
iprodione


D.132


No.
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.133


No.
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.134


No.
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.135


No.
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.136


No.
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.137



No.
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.138


No.
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.139


No.
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.140


No.
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.141


No.
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.142


No.
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.143


No.
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
iprodione


D.144


No.
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.145


No.
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.146


No.
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.147


No.
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.148


No.
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.149


No.
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.150


No.
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.151


No.
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.152


No.
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.153


No.
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.154


No.
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.155


No.
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.156


No.
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.157


No.
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.158


No.
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.159


No.
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.160


No.
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.161


No.
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.162


No.
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.163


No.
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.164


No.
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.165


No.
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.166


No.
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.167


No.
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
vinclozolin


D.168
















TABLE 7







Active compound combinations of compounds I with active compounds II of group E):











Active compound


Mixture
Compounds of the formula I (X = oxygen)
II





No. E.1
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.2
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.3
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.4
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.5
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.6
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.7
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.8
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.9
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.10
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.11
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.12
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.13
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.14
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.15
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.16
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.17
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.18
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.19
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.20
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.21
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.22
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.23
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.24
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
mancozeb


No. E.25
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.26
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.27
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.28
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.29
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.30
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.31
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.32
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.33
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.34
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.35
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.36
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metiram


No. E.37
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.38
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.39
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.40
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.41
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.42
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.43
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.44
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.45
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.46
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.47
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram


No. E.48
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metiram
















TABLE 8







Active compound combinations of compounds I with active compounds II of group F):











Active compound


Mixture
Compounds of the formula I (X = oxygen)
II





No. F.1
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.2
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.3
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.4
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.5
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.6
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.7
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.8
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.9
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.10
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.11
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.12
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.13
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.14
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.15
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.16
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.17
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.18
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.19
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.20
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.21
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.22
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.23
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.24
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
chlorothalonil


No. F.25
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.26
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.27
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.28
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.29
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.30
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.31
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.32
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.33
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.34
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.35
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.36
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.37
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.38
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.39
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.40
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.41
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.42
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.43
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.44
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.45
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.46
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.47
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.48
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
metrafenone


No. F.49
R1 = CH3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.50
R1 = CH3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.51
R1 = CH3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.52
R1 = CH2F; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.53
R1 = CHFCl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.54
R1 = CHF2; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.55
R1 = CHF2; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.56
R1 = CHF2; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.57
R1 = CF2Cl; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.58
R1 = CF3; R2 = H; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.59
R1 = CF3; R2 = F; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.60
R1 = CF3; R2 = Cl; R3 = 3-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.61
R1 = CH3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.62
R1 = CH3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.63
R1 = CH3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.64
R1 = CH2F; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.65
R1 = CHFCl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.66
R1 = CHF2; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.67
R1 = CHF2; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.68
R1 = CHF2; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.69
R1 = CF2Cl; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.70
R1 = CF3; R2 = H; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.71
R1 = CF3; R2 = F; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid


No. F.72
R1 = CF3; R2 = Cl; R3 = 2-F; R4 = 4-F; R5 = 5-F
phosphorous acid
















TABLE 9







Active compound combinations of compounds I with two active compounds II:












Active compound
Active compound


Mixture
Compound of the formula I
II
II





I-II-II.1
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
epoxiconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.2
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
epoxiconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.3
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
epoxiconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.4
N-(2′,4′-5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
epoxiconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.5
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
epoxiconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.6
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
metconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.7
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.8
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.9
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.10
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.11
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
triticonazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.12
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
triticonazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.13
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
triticonazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.14
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
triticonazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.15
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
triticonazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.16
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
fluquinconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.17
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fluquinconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.18
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fluquinconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.19
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fluquinconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.20
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fluquinconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.21
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
prothioconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.22
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
prothioconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.23
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
prothioconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.24
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
prothioconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.25
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
prothioconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.26
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
tebuconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.27
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
tebuconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.28
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
tebuconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.29
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
tebuconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.30
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
tebuconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.31
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.32
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.33
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.34
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.35
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.36
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.37
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.38
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.39
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.40
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.41
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.42
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.43
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.44
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.45
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.46
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.47
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.48
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.49
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.50
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.51
N-(2′-fluoro-4′-chloro-5′-methyl-
pyraclostrobin
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.52
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.53
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.54
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.55
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
pyraclostrobin
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.56
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
epoxiconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.57
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
epoxiconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.58
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
epoxiconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.59
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
epoxiconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.60
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
epoxiconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.61
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
metconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.62
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.63
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.64
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.65
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.66
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
triticonazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.67
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
triticonazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.68
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
triticonazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.69
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
triticonazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.70
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
triticonazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.71
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
fluquinconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.72
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fluquinconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.73
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fluquinconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.74
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fluquinconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.75
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fluquinconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.76
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
prothioconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.77
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
prothioconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.78
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
prothioconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.79
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
prothioconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.80
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
prothioconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.81
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
tebuconazole



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.82
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
tebuconazole



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.83
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
tebuconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.84
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
tebuconazole



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.85
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
tebuconazole



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.86
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.87
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.88
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
carbendazim



1-methyl-3-difluoromethyl-1H



pyrazole-4-carboxamide


I-II-II.89
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.90
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.91
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.92
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.93
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.94
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.95
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.96
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.97
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.98
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.99
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.100
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.101
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.102
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.103
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.104
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.105
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.106
N-(2′-fluoro-4′-chloro-5′-methyl-
kresoxim-methyl
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.107
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.108
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.109
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.110
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
kresoxim-methyl
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.111
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
5-chloro-7-



biphenyl-2-yl)-1-methyl-3-

(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-

1-yl)-6-(2,4,6-tri-



4-carboxamide

fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.112
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
5-chloro-7-



1-methyl-3-trifluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.113
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.114
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.115
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
5-chloro-7-



3-chlorofluoromethyl-1-methyl-

(4-methylpiperidin-



1H-pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.116
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.117
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.118
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.119
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.120
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.121
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.122
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.123
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.124
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.125
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.126
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.127
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.128
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.129
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.130
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.131
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.132
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.133
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.134
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.135
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.136
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.137
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.138
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.139
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.140
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.141
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
metalaxyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.142
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metalaxyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.143
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.144
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide d


I-II-II.145
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
metalaxyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.146
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
iprodione



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.147
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
iprodione



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.148
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.149
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.150
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
iprodione



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.151
N-(2′-fluoro-4′-chloro-5′-methyl-
epoxiconazole
pyrimethanil



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.152
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
pyrimethanil



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.153
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.154
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.155
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
epoxiconazole
pyrimethanil



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.156
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
5-chloro-7-



biphenyl-2-yl)-1-methyl-3-

(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-

1-yl)-6-(2,4,6-tri-



4-carboxamide

fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.157
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
5-chloro-7-



1-methyl-3-trifluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.158
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.159
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.160
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
5-chloro-7-



3-chlorofluoromethyl-1-methyl-

(4-methylpiperidin-



1H-pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.161
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.162
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.163
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.164
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.165
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.166
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.167
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.168
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.169
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.170
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.171
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.172
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.173
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.174
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.175
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.176
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.177
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.178
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.179
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.180
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.181
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.182
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.183
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.184
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.185
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.186
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
metalaxyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.187
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metalaxyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.188
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.189
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.190
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
metalaxyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.191
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
iprodione



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.192
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
iprodione



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.193
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.194
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.195
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
iprodione



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.196
N-(2′-fluoro-4′-chloro-5′-methyl-
metconazole
pyrimethanil



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.197
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
pyrimethanil



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.198
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.199
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.200
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
metconazole
pyrimethanil



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.201
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
5-chloro-7-



biphenyl-2-yl)-1-methyl-3-

(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-

1-yl)-6-(2,4,6-tri-



4-carboxamide

fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.202
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
5-chloro-7-



1-methyl-3-trifluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.203
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.204
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.205
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
5-chloro-7-



3-chlorofluoromethyl-1-methyl-

(4-methylpiperidin-



1H-pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.206
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.207
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.208
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.209
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.210
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.211
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.212
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.213
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.214
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.215
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.216
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.217
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.218
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.219
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide id


I-II-II.220
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.221
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.222
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.223
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.224
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.225
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.226
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.227
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.228
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.229
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.230
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.231
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
metalaxyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.232
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metalaxyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.233
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.234
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.235
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
metalaxyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.236
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
iprodione



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.237
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
iprodione



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.238
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.239
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.240
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
iprodione



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.241
N-(2′-fluoro-4′-chloro-5′-methyl-
triticonazole
pyrimethanil



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.242
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
pyrimethanil



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.243
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.244
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
triticonazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.245
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
pyrimethanil



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.246
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
5-chloro-7-



biphenyl-2-yl)-1-methyl-3-

(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-

1-yl)-6-(2,4,6-tri-



4-carboxamide

fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.247
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
5-chloro-7-



1-methyl-3-trifluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.248
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.249
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.250
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
5-chloro-7-



3-chlorofluoromethyl-1-methyl-

(4-methylpiperidin-



1H-pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.251
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.252
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.253
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.254
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.266
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.267
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.268
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.269
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.270
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.271
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.272
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.273
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.274
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.275
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.276
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
metalaxyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.277
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metalaxyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.278
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.279
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.280
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
metalaxyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.281
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
iprodione



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.282
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
iprodione



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.283
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.284
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.285
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
iprodione



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.286
N-(2′-fluoro-4′-chloro-5′-methyl-
fluquinconazole
pyrimethanil



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.287
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
pyrimethanil



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.288
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.289
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.290
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
fluquinconazole
pyrimethanil



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.291
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
5-chloro-7-



biphenyl-2-yl)-1-methyl-3-

(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-

1-yl)-6-(2,4,6-tri-



4-carboxamide

fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.292
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
5-chloro-7-



1-methyl-3-trifluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.293
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.294
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.295
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
5-chloro-7-



3-chlorofluoromethyl-1-methyl-

(4-methylpiperidin-



1H-pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.296
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.297
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.298
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.299
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.300
N-(3,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.301
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.302
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.303
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.304
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.305
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.306
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.307
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.308
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.309
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.310
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.311
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.312
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.313
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.314
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.315
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.316
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.317
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.318
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.319
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.320
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.321
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
metalaxyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.322
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metalaxyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.323
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.324
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.325
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
metalaxyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.326
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
iprodione



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.327
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
iprodione



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.328
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.329
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.330
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
iprodione



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.331
N-(2′-fluoro-4′-chloro-5′-methyl-
prothioconazole
pyrimethanil



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.332
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
pyrimethanil



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.333
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.334
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.335
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
prothioconazole
pyrimethanil



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.336
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
5-chloro-7-



biphenyl-2-yl)-1-methyl-3-

(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-

1-yl)-6-(2,4,6-tri-



4-carboxamide

fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.337
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
5-chloro-7-



1-methyl-3-trifluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.338
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.339
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
5-chloro-7-



1-methyl-3-difluoromethyl-1H-

(4-methylpiperidin-



pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.340
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
5-chloro-7-



3-chlorofluoromethyl-1-methyl-

(4-methylpiperidin-



1H-pyrazole-4-carboxamide

1-yl)-6-(2,4,6-tri-





fluorophenyl)-





[1,2,4]triazolo[1,5-





a]pyrimidine


I-II-II.341
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
carbendazim



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.342
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
carbendazim



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.343
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.344
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
carbendazim



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.345
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
carbendazim



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.346
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
thiophanate-



biphenyl-2-yl)-1-methyl-3-

methyl



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.347
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
thiophanate-



1-methyl-3-trifluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.348
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.349
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
thiophanate-



1-methyl-3-difluoromethyl-1H-

methyl



pyrazole-4-carboxamide


I-II-II.350
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
thiophanate-



3-chlorofluoromethyl-1-methyl-

methyl



1H-pyrazole-4-carboxamide


I-II-II.351
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
benomyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.352
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
benomyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.353
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.354
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
benomyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.355
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
benomyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.356
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
fenpropimorph



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.357
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
fenpropimorph



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.358
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.359
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
fenpropimorph



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.360
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
fenpropimorph



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.361
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
metrafenone



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.362
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metrafenone



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.363
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.364
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metrafenone



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.365
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metrafenone



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.366
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
metalaxyl



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.367
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metalaxyl



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.368
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.369
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metalaxyl



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.370
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
metalaxyl



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.371
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
iprodione



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.372
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
iprodione



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.373
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.374
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
iprodione



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.375
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
iprodione



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.376
N-(2′-fluoro-4′-chloro-5′-methyl-
tebuconazole
pyrimethanil



biphenyl-2-yl)-1-methyl-3-



trifluoromethyl-1H-pyrazole-



4-carboxamide


I-II-II.377
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
pyrimethanil



1-methyl-3-trifluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.378
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.379
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
pyrimethanil



1-methyl-3-difluoromethyl-1H-



pyrazole-4-carboxamide


I-II-II.380
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
tebuconazole
pyrimethanil



3-chlorofluoromethyl-1-methyl-



1H-pyrazole-4-carboxamide


I-II-II.381
N-(2′-fluoro-4′-chloro-5′-methyl-
5-chloro-7-
carbendazim



biphenyl-2-yl)-1-methyl-3-
(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-
1-yl)-6-(2,4,6-tri-



4-carboxamide
fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.382
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
carbendazim



1-methyl-3-trifluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.383
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
carbendazim



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.384
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
carbendazim



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.385
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
carbendazim



3-chlorofluoromethyl-1-methyl-
(4-methylpiperidin-



1H-pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.386
N-(2′-fluoro-4′-chloro-5′-methyl-
5-chloro-7-
thiophanate-



biphenyl-2-yl)-1-methyl-3-
(4-methylpiperidin-
methyl



trifluoromethyl-1H-pyrazole-
1-yl)-6-(2,4,6-tri-



4-carboxamide
fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.387
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
thiophanate-



1-methyl-3-trifluoromethyl-1H-
(4-methylpiperidin-
methyl



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.388
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
thiophanate-



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-
methyl



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.389
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
thiophanate-



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-
methyl



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.390
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
thiophanate-



3-chlorofluoromethyl-1-methyl-
(4-methylpiperidin-
methyl



1H-pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.391
N-(2′-fluoro-4′-chloro-5′-methyl-
5-chloro-7-
benomyl



biphenyl-2-yl)-1-methyl-3-
(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-
1-yl)-6-(2,4,6-tri-



4-carboxamide
fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.392
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
benomyl



1-methyl-3-trifluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.393
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
benomyl



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.394
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
benomyl



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.395
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
benomyl



3-chlorofluoromethyl-1-methyl-
(4-methylpiperidin-



1H-pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.396
N-(2′-fluoro-4′-chloro-5′-methyl-
5-chloro-7-
fenpropimorph



biphenyl-2-yl)-1-methyl-3-
(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-
1-yl)-6-(2,4,6-tri-



4-carboxamide
fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.397
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
fenpropimorph



1-methyl-3-trifluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.398
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
fenpropimorph



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo[1,5-




a]pyrimidine


I-II-II.399
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
fenpropimorph



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.400
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
fenpropimorph



3-chlorofluoromethyl-1-methyl-
(4-methylpiperidin-



1H-pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.401
N-(2′-fluoro-4′-chloro-5′-methyl-
5-chloro-7-
metrafenone



biphenyl-2-yl)-1-methyl-3-
(4-methylpiperidin-



trifluoromethyl-1H-pyrazole-
1-yl)-6-(2,4,6-tri-



4-carboxamide
fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.402
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
metrafenone



1-methyl-3-trifluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.403
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
metrafenone



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.404
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
metrafenone



1-methyl-3-difluoromethyl-1H-
(4-methylpiperidin-



pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine


I-II-II.405
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-
5-chloro-7-
metrafenone



3-chlorofluoromethyl-1-methyl-
(4-methylpiperidin-



1H-pyrazole-4-carboxamide
1-yl)-6-(2,4,6-tri-




fluorophenyl)-




[1,2,4]triazolo-




[1,5-a]pyrimidine









The mixtures of compound(s) I and at least one of the active compounds II, or at least one compound I and at least one of the active compounds II applied simultaneously, that is jointly or separately, have excellent activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Basidiomycetes, Deuteromycetes and Peronosporomycetes (syn. Oomycetes). Some of them are systemically effective and can be employed in crop protection as foliar fungicides, as fungicides for seed dressing and as soil fungicides. They can also be used for treating seed.
They are particularly important in the control of a multitude of fungi on various cultivated plants, such as wheat, rye, barley, oats, rice, corn, lawns, bananas, cotton, soybean, coffee, sugar cane, grapevines, fruits and ornamental plants, and vegetables such as cucumbers, beans, tomatoes, potatoes and cucurbits, and on the seeds of these plants.
They are especially suitable for controlling the following plant diseases:

    
    
        Alternaria species on vegetables, oilseed rape, sugar beet and fruit and rice, for example, A. solani or A. alternata on potatoes and tomatoes;
        Aphanomyces species on sugar beet and vegetables;
        Ascochyta species on cereals and vegetables;
        Bipolaris and Drechslera species on corn, cereals, rice and lawns, for example, D. maydis on corn;
        Blumeria graminis (powdery mildew) on cereals;
        Botlytis cinerea (gray mold) on strawberries, vegetables, flowers and grapevines;
        Bremia lactucae on lettuce;
        Cercospora species on corn, soybeans, rice and sugar beet;
        Cochliobolus species on corn, cereals, rice, for example Cochliobolus sativus on cereals, Cochliobolus miyabeanus on rice;
        Colletotricum species on soybeans and cotton;
        Drechslera species, Pyrenophora species on corn, cereals, rice and lawns, for example, D. teres on barley or D. tritici-repentis on wheat;
        Esca on grapevines, caused by Phaeoacremonium chlamydosporium, Ph. Aleophilum and Formitipora punctata (syn. Phellinus punctatus),
        Exserohilum species on corn;
        Erysiphe cichoracearum and Sphaerotheca fuliginea on cucumbers;
        Fusarium and Verticillium species on various plants, for example, F graminearum or F. culmorum on cereals or F. oxysporum on a multitude of plants, such as, for example, tomatoes;
        Gaeumanomyces graminis on cereals;
        Gibberella species on cereals and rice (for example Gibberella fujikuroi on rice);
        Grainstaining complex on rice;
        Helminthosporium species on corn and rice;
        Michrodochium nivale on cereals;
        Mycosphaerella species on cereals, bananas and peanuts, for example, M. graminicola on wheat or M. fijiensis on bananas;
        Peronospora species on cabbage and bulbous plants, for example, P. brassicae on cabbage or P. destructor on onions;
        Phakopsara pachyrhizi and Phakopsara meibomiae on soybeans;
        Phomopsis species on soybeans and sunflowers;
        Phytophthora infestans on potatoes and tomatoes;
        Phytophthora species on various plants, for example, P. capsici on bell pepper;
        Plasmopara viticola on grapevines;
        Podosphaera leucotricha on apples;
        Pseudocercosporella herpotrichoides on cereals;
        Pseudoperonospora on various plants, for example, P. cubensis on cucumber or P. humili on hops;
        Puccinia species on various plants, for example, P. triticina, P. striformins, P., hordei or P. graminis on cereals or P. asparagi on asparagus;
        Pyrlcularia oryzae, Corticium sasakii, Sarocladium oryzae, S. attenuatum, Entyloma oryzae on rice;
        Pyricularia grisea on lawns and cereals;
        Pythium spp. on lawns, rice, corn, cotton, oilseed rape, sunflowers, sugar beet, vegetables and other plants, for example, P. ultiumum on various plants, P. aphanidermatum on lawns;
        Rhizoctonia species on cotton, rice, potatoes, lawns, corn, oilseed rape, sugar beet, vegetables and on various plants, for example, R. solani on beet and various plants;
        Rhynchosporium secalis on barley, rye and triticale;
        Sclerotinia species on oilseed rape and sunflowers;
        Septoria tritici and Stagonospora nodorum on wheat;
        Erysiphe (syn. Uncinula) necator on grapevines;
        Setospaeria species on corn and lawns;
        Sphacelotheca reilinia on corn;
        Thievaliopsis species on soybeans and cotton;
        Tilletia species on cereals;
        Ustilago species on cereals, corn and sugar cane, for example, U. maydis on corn;
        Venturia species (scab) on apples and pears, for example, V. inaequalis on apples.
    
    


The mixtures according to the invention are also suitable for controlling harmful fungi in the protection of materials (for example wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products. In the protection of wood, particular attention is paid to the following harmful fungi: Ascomycetes, such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes, such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Deuteromycetes, such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichoderma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes, such as Mucor spp., additionally in the protection of materials the following yeasts: Candida spp. and Saccharomyces cerevisae. 
The compound(s) I and at least one of the active compounds II can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
When preparing the mixtures, it is preferred to employ the pure active compounds I and II, to which further compounds active against harmful fungi or other pests, such as insects, arachnids or nematodes, or else herbicidal or growth-regulating active compounds or fertilizers can be added.
Such mixtures of three active compounds comprise, for example, a compound of the formula I, in particular N-(2′-fluoro-4′-chloro-5′-methylbiphenyl-2-yl)-1-methyl-3-trifluoro-methyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-1-methyl-3-tri-fluoromethyl-1H-pyrazole-4-carboxamide, N-(3′,4′,5′-trifluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(2′,4′,5′-trifluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide or N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, an azole from group A), in particular epoxiconazole, metconazole, triticonazole or fluquinconazole, and an insecticide, suitable insecticides being in particular fipronil and neonicotinoids, such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam.
Usually, mixtures of at least one compound I and at least one active compound II are employed. However, mixtures of at least one compound I with two or, if desired, more active components may also offer particular advantages.
Suitable further active components in the above sense are particularly the active compounds II mentioned at the outset and in particular the preferred active compounds II mentioned above.
Compound(s) I and active compound(s) II are usually employed in a weight ratio of from 100:1 to 1:100, preferably from 20:1 to 1:20, in particular from 10:1 to 1:10.
The further active components are, if desired, mixed in a ratio of from 20:1 to 1:20 to the compound I.
Depending on the type of the compounds I and II and the desired effect, the application rates of the mixtures according to the invention, especially on agricultural crop areas, are from 5 g/ha to 2000 g/ha, preferably from 20 to 1500 g/ha, in particular from 50 to 1000 g/ha.
Correspondingly, the application rates for the compound(s) I are generally from 1 to 1000 g/ha, preferably from 10 to 900 g/ha, in particular from 20 to 750 g/ha.
Correspondingly, the application rates for the active compound II are generally from 1 to 2000 g/ha, preferably from 10 to 1500 g/ha, in particular from 40 to 1000 g/ha.
In the treatment of seed, application rates of mixture are generally from 1 to 1000 g per 100 kg of seed, preferably from 1 to 750 g per 100 kg, in particular from 5 to 500 g per 100 kg of seed.
The method for controlling harmful fungi is carried out by the separate or joint application of compound(s) I and at least one of the active compounds II, or a mixture of compound(s) I and at least one of the active compounds II, by spraying or dusting the seeds, the plants or the soils before or after sowing of the plants or before or after emergence of the plants.
The fungicidal mixtures according to the invention, or the compound(s) I and at least one of the active compounds II, can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes and granules. The use form depends on the particular intended purpose; in each case, it should ensure as fine and even a distribution of the mixture according to the invention as possible.
The formulations are prepared in a manner known per se, for example by extending the active compounds with solvents and/or carriers, if desired using emulsifiers and dispersants. Solvents/auxiliaries suitable for this purpose are essentially:

    
    
        water, aromatic solvents (for example Solvesso® products, xylene), paraffins (for example mineral oil fractions), alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone), acetates (glycol diacetate), glycols, fatty acid dimethylamides, fatty acids and fatty acid esters. In principle, solvent mixtures may also be used.
        carriers such as ground natural minerals (for example kaolins, clays, talc, chalk) and ground synthetic minerals (for example highly disperse silica, silicates); emulsifiers such as nonionogenic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose.
    
    


Suitable surfactants used are alkali metal, alkaline earth metal and ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxy-ethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol and fatty alcohol ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors and methylcellulose.
Substances which are suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, highly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water.
Powders, materials for spreading and dustable products can be prepared by mixing or concomitantly grinding the active substances with at least one solid carrier.
Granules, for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to at least one solid carrier. Examples of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
In general, the formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the compound(s) I and at least one of the active compounds II or the mixture of compound(s) I with at least one of the active compounds II. The active compounds are employed in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR or HPLC spectrum).
The following are examples of formulations: 1. Products for dilution with water
A) Water-Soluble Concentrates (SL)
10 parts by weight of a mixture according to the invention are dissolved in 90 parts by weight of water or in a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. The active compounds dissolve upon dilution with water. In this way, a formulation having a total content of 10% by weight of active compound is obtained.
B) Dispersible Concentrates (DC)
20 parts by weight of a mixture according to the invention are dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active compound content is 20% by weight
C) Emulsifiable Concentrates (EC)
15 parts by weight of a mixture according to the invention are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has an active compound content of 15% by weight.
D) Emulsions (EW, EO)
25 parts by weight of a mixture according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an active compound content of 25% by weight.
E) Suspensions (SC, OD)
In an agitated ball mill, 20 parts by weight of a mixture according to the invention are comminuted with addition of 10 parts by weight of dispersants and wetting agents and 70 parts by weight of water or an organic solvent to give a fine active compound suspension. Dilution with water gives a stable suspension of the active compounds. The active compound content in the formulation is 20% by weight.
F) Water-Dispersible Granules and Water-Soluble Granules (WG, SG)
50 parts by weight of a mixture according to the invention are ground finely with addition of 50 parts by weight of dispersants and wetting agents and prepared as water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active compounds. The formulation has an active compound content of 50% by weight.
G) Water-Dispersible Powders and Water-Soluble Powders (WP, SP)
75 parts by weight of a mixture according to the invention are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetting agents and silica gel. Dilution with water gives a stable dispersion or solution of the active compounds. The active compound content of the formulation is 75% by weight.
2. Products to be Applied Undiluted
H) Dustable Powders (DP)
5 parts by weight of a mixture according to the invention are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable product having an active compound content of 5% by weight.
J) Granules (GR, FG, GG, MG)
0.5 part by weight of a mixture according to the invention is ground finely and associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted having an active compound content of 0.5% by weight.
K) ULV Solutions (UL)
10 parts by weight of a mixture according to the invention are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted having an active compound content of 10% by weight.
The active compounds can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading or pouring. The use forms depend entirely on the intended purposes; they are intended to ensure in each case the finest possible distribution of the active compounds.
Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. However, it is also possible to prepare concentrates composed of active substance, wetting agent, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water.
The active compound concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.01 to 1%.
The active compounds may also be used successfully in the ultra-low-volume process (ULV), it being possible to apply formulations comprising over 95% by weight of active compound, or even to apply the active compound without additives.
Oils of various types, wetting agents, adjuvants, herbicides, other pest control agents or bactericides may be added to the active compounds, even, if desired, not until immediately prior to use (tank mix). These agents are typically mixed with the mixtures according to the invention in a weight ratio of from 1:100 to 100:1, preferably from 1:10 to 10:1.
Suitable adjuvants in this context are, in particular: organically modified polysiloxanes, e.g. Break Thru S 240®; alcohol alkoxylates, e.g. Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON 30®; EO/PO block polymers, e.g. Pluronic RPE 2035® and Genapol B®; alcohol ethoxylates, e.g. Lutensol XP 80®; and sodium dioctylsulfosuccinate, e.g. Leophen RA®.
The compounds I and II or the mixtures or the corresponding formulations are applied by treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them with a fungicidally effective amount of the mixture or, in the case of separate application, of the compounds I and II. Application can be before or after the infection by harmful fungi.


USE EXAMPLES
The fungicidal action of the individual compounds and of the mixtures according to the invention was demonstrated by the tests below.
The active compounds, separately or jointly, were prepared as a stock solution comprising 25 mg of active compound which was made up to 10 ml using a mixture of acetone and/or dimethyl sulfoxide and the emulsifier Uniperol® EL (wetting agent having an emulsifying and dispersing action based on ethoxylated alkylphenols) in a ratio by volume of solvent/emulsifier of 99:1. The mixture was then made up to 100 ml with water. This stock solution was diluted with the solvent/emulsifier/water mixture described to give the concentration of active compound stated below.
As an alternative, the active compounds epoxiconazole, triticonazole and pyraclostrobin were used as commercially available ready-to-use formulation and diluted to the specified active compound concentration with water.
The visually determined percentages of infected leaf areas were converted into efficacies in % of the untreated control:
The efficacy (E) is calculated as follows using Abbot's formula:

E=(1−α/β)·100

α corresponds to the fungicidal infection of the treated plants in % and

β corresponds to the fungicidal infection of the untreated (control) plants in %

An efficacy of 0 means that the infection level of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants are not infected.
The expected efficacies of active compound combinations were determined using Colby's formula (Colby, S. R. “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds, 15, 20-22, 1967) and compared with the observed efficacies.
Colby's formula:

E=x+y−x·y/100

    E expected efficacy, expressed in % of the untreated control, when using the mixture of the active compounds A and B at the concentrations a and b;
    x efficacy, expressed in % of the untreated control, when using the active compound A at the concentration a;
    y efficacy, expressed in % of the untreated control, when using the active compound B at the concentration b.


Use Example 1
Activity Against Early Blight of Tomato Caused by Alternaria solani 
Leaves of potted tomato plants were sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. The next day, the leaves were infected with an aqueous spore suspension of Alternaria solani in a 2% biomalt solution having a density of 0.17×106 spores/ml. The plants were then placed in a water vapor-saturated chamber at temperatures between 20 and 22° C. After 5 days, the disease on the untreated but infected control plants had developed to such an extent that the infection could be determined visually in %.


















Activity


Active


Observed
calculated


compounds/active
Concentration

activity
according to


compound mixture
[mg/l]
Ratio
(% infection)
Colby (%)







(Control)
—
—
0 (90%
—





infection)



No. Ia.719
 4
—
0
—


prochloraz
16
—
30
—


pyraclostrobin
 4
—
50
—


metiram
63
—
0
—


chlorthalonil
63
—
0
—


No. Ia.719 +
4 + 16
1:4
60
30


prochloraz


No. Ia.719 +
4 + 4 
1:1
93
50


pyraclostrobin


No. Ia.719 +
4 + 63
1:4
70
0


metiram


No. Ia.179 +
4 + 63
1:4
70
0


chlorthalonil









Use Example 2
Activity Against Gray Mold on Bell Pepper Leaves Caused by Botrytis cinerea, 1 Day of Protective Application
Bell pepper seedlings of the cultivar “Neusiedler Ideal Elite” were, after 2-3 leaves were well developed, sprayed to runoff point with an aqueous suspension in the active compound concentration specified below. The next day, the treated plants were inoculated with a spore suspension of Botrytis cinerea which contained 1.7×106 spores/ml in a 2% strength aqueous biomalt solution. The test plants were then placed in a climatized chamber at 22 to 24° C., darkness and high atmospheric humidity. After 5 days, the extent of the fungal infection on the leaves could be determined visually in %.


















Activity


Active


Observed
calculated


compounds/active
Concentration

activity
according to


compound mixture
[mg/l]
Ratio
(% infection)
Colby (%)







(Control)
—
—
0(100%
—





infection)



No. Id.344
1
—
40
—


No. Ia.344
16
—
60
—


No. Ij.344
4
—
22
—



1
—
0
—


triticonazole
4
—
0
—


prochloraz
4
—
11
—


dimethomorph
63
—
0
—



16
—
0
—



4
—
0
—


metiram
16
—
0
—


metrafenone
63
—
0
—



16
—
0
—



4
—
0
—


No. Id.344 +
1 + 4 
1:4
80
40


dimethomorph


No. Id.344 +
1 + 16
 1:16
70
40


metiram


No. Id.344 +
1 + 4 
1:4
60
40


metrafenone


No. Ia.344 +
16 + 63
1:4
85
60


dimethomorph


No. Ia.344 +
16 + 63
1:4
90
60


metrafenone


No. Ij.344 +
4 + 4 
1:1
78
22


triticonazole


No. Ij.344 +
1 + 4 
1:4
92
11


prochloraz


No. Ij.344 +
4 + 16
1:4
78
22


dimethomorph


No. Ij.344 +
4 + 16
1:4
100
22


metrafenone









Use Example 3
Curative Activity Against Brown Rust of Wheat Caused by Puccinia recondita 
Leaves of potted wheat seedlings of the cultivar “Kanzler” were inoculated with a spore suspension of brown rust (Puccinia recondita). The pots were then placed in a chamber with high atmospheric humidity (90 to 95%) and 20 to 22° C. for 24 hours. During this time, the spores germinated and the germ tubes penetrated into the leaf tissue. The next day, the infected plants were sprayed to runoff point with the above-described active compound solution having the active compound concentration stated below. After the spray coating had dried on, the test plants were cultivated in a greenhouse at temperatures between 20 and 22° C. and 65 to 70% relative atmospheric humidity for 7 days. The extent of the rust fungal development on the leaves was then determined.


















Activity


Active


Observed
calculated


compounds/active
Concentration

activity
according to


compound mixture
[mg/l]
Ratio
(% infection)
Colby (%)







(Control)
—
—
0 (90%
—





infection)



No. Id.344
1
—
0
—


No. Ij.344
1
—
0
—


No. Ia.719
0.25
—
0
—


epoxiconazole
0.063
—
0
—


triticonazole
1
—
0
—


pyraclostrobin
1
—
0
—


chlorthalonil
16
—
0
—


5-chloro-7-
4
—
40
—


(4-methyl-


piperidin-1-yl)-


6-(2,4,6-


trifluorophenyl)-


[1,2,4]tri-


azolo[1,5-


a]pyrimidine


No. Id.344 +
1 + 1
1:1
56
0


triticonazole


No. Id.344 +
1 + 1
1:1
83
0


pyraclostrobin


No. Id.344 +
 1 + 16
 1:16
78
0


chlorthalonil


No. Ij.344 +
1 + 4
1:4
100
40


5-chloro-7-(4-


methylpiperidin-


1-yl)-6-(2,4,6-


trifluorophenyl)-


[1,2,4]tri-


azolo[1,5-


a]pyrimidine


No. Ia.719 +
 0.25 + 0.063
4:1
30
0


epoxiconazole









Use Example 4
Activity Against Net Blotch of Barley Caused by Pyrenophora teres, 1 Day Protective Application
Leaves of potted barley seedlings were sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. 24 hours after the spray coating had dried on, the test plants were inoculated with an aqueous spore suspension of Pyrenophora [syn. Drechslera] teres, the net blotch pathogen. The test plants were then placed in a greenhouse at temperatures between 20 and 24° C. and 95 to 100% relative atmospheric humidity. After 6 days, the extent of the development of the disease was determined visually in % infection of the entire leaf area.


















Activity


Active


Observed
calculated


compounds/active
Concentration

activity
according to


compound mixture
[mg/l]
Ratio
(% infection)
Colby (%)







(Control)
—
—
0 (90%
—





infection)



No. Id.344
0.25
—
67
—


epoxiconazole
0.063
—
0
—


No. Id.344 +
 0.25 + 0.063
4:1
83
67


epoxiconazole









The test results show that, by virtue of the synergism, the mixtures according to the invention are considerably more active than had been predicted using Colby's formula.

## Claims

1. A fungicidal mixture comprising,
1) at least one compound of formula I





wherein:
X is oxygen;
R1 is C1-C4-alkyl or C1-C4-haloalkyl;
R2 is hydrogen;
R3, R4 and R5 independently of one another are halogen;

and
2) at least one active compound II selected from the group consisting of:
A) bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole,
ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexazole;

B) azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate and methyl 2-(ortho-(2,5-dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate;
C) carboxin, benalaxyl, boscalid, fenhexamid, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil,
3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide, dimethomorph, flumorph, flumetover, fluopicolide (picobenzamid), zoxamide, carpropamid, diclocymet, mandipropamid, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propionate, compounds of formula III








wherein: R4 of formula III is methyl or ethyl, N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide, N-(3′,4′-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide and N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide;

D) fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, procymidone, vinclozolin, famoxadone, fenamidone, octhilinone, probenazole, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine,
anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, a compound of formula IV (2-butoxy-6-iodo-3-propylchromen-4-one)








acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quinoxyfen and
N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide of formula V







E) mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb, 4-fluorophenyl N-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)carbamate, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methyl-butyrylamino)propanoate of formula VI







and carbamate oxime ethers of formula VII








wherein: Z is N or CH;

F) guanidine, dodine, iminoctadine, guazatine,
kasugamycin, streptomycin, polyoxin, validamycin A,
binapacryl, dinocap, dinobuton,
dithianon, isoprothiolane,
fentin salts,
edifenphos, iprobenfos, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl,
chlorothalonil, dichlofluanid, flusulfamide, hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate-methyl, tolylfluanid,
Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride,
basic copper sulfate, sulfur,
cyflufenamid, cymoxanil, dimethirimol, ethirimol,
furalaxyl, metrafenone and spiroxamine;


wherein the at least one compound of formula I and the at least one active compound II are present in a synergistically effective amount.

2. The fungicidal mixture of claim 1, wherein the at least one compound I is selected from the group consisting of:
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3 trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3 difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N (3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1 methyl-1H-pyrazole-4-carboxamide

and
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3 fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.

3. The fungicidal mixture of claim 1, wherein the at least one compound of formula I and the at least one active compound II are present in a weight ratio of from 100:1 to 1:100.

4. The fungicidal mixture of claim 1, wherein the at least one compound of formula I and the at least one active compound II are present in a weight ratio of from 100:1 to 1:100.

5. The fungicidal mixture of claim 2, wherein the at least one compound of formula I and the at least one active compound II are present in a weight ratio of from 100:1 to 1:100.

6. The fungicidal mixture of claim 1, further comprising at least one liquid or solid carrier.

7. The fungicidal mixture of claim 1, further comprising at least one liquid or solid carrier.

8. The fungicidal mixture of claim 2, further comprising at least one liquid or solid carrier.

9. A method for controlling phytopathogenic harmful fungi
comprising,
contacting fungi, their habitat or the plants, soil, seeds, areas, materials or spaces to be protected against fungal attack with a fungicidal mixture of claim 1,
wherein the at least one compound of formula I and the at least one active compound II are present in a synergistically effective amount;
wherein phytopathogenic harmful fungi are controlled.

10. The method of claim 9, wherein the at least one compound of formula I and the at least one active compound II are applied simultaneously, separately, or in succession.

11. The method of claim 9, wherein the at least one compound of formula I and the at least one active compound II are applied in an amount of from 5 g/ha to 2000 g/ha.

12. The method of claim 9, wherein the at least one compound of formula I and the at least one active compound II are applied in an amount of from 1 g to 1000 g per 100 kg of seed.

13. The method of claim 9, wherein the at least one compound I is selected from the group consisting of:
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3 trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3 difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N (3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1 methyl-1H-pyrazole-4-carboxamide

and
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3 fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.

14. A seed, treated with a fungicidal mixture of claim 1, wherein the at least one compound of formula I and the at least one active compound II are present in a synergistically effective amount.

15. The seed of claim 14, wherein the at least one compound of formula I and the at least one active compound II are present in an amount of from 1 g to 1000 g per 100 kg of seed.

16. The seed of claim 14, wherein the at least one formula I is selected from the group consisting of:
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3 trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3 difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N (3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,
N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1 methyl-1H-pyrazole-4-carboxamide

and
N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3 fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.