# WIARAZ ZI IN usa

AugList 18, 2009 Mr. Jeffery Telander U.S. EPA Mailroom (D2430-02) U.S. Environmental Protection Agency 4ffice of Air Quality Pla.nning and Standards Research Triangle Park, NC 27711
Re: American Marazzi Tile, Inc. April 14, 2005 Stack Test Report Non Confidential Busines`s Information Version
Dear Mr. Telander: As requested, American Marazzi Tile, Inc. (AMT) is providing you with a second copy of the Apri114, 2005 Stack Test Report of its Kiln 1 emissions testing with all Confidential Business Informa.tion (CBI) redacted. Should you have any questions concerning the information contained in our response please feel free to contact me by email at swiederwax@marazzitile.com or by telephone at 972-226-0110. Sincerely,

Stev T. ' ax Safety and Environmental Manager
Enclosure Apri124, 2005 American Marazzi Tile, Inc. Stack Test Report (Non-CBI)

,merican Marazzi Tile, Inc. Headquarters and Telephone Manufacturing Plant 972.226.0110 359 Clay Road Fax Sunnyvale, TX 75182-9710 972.226.2263 USA Customer Service Fax 972.226.5629 wvwv. marazzitile.com E-mail contact@marazzitile.com

# AM E RC gAN M A RAZZI T IL E

SIJNNYYA.LEpTEXAS Em ISSIONS 'g'ESTIiVG 

### ifilti .l Main Stsacic and Hyclrogen Fluorgde rand Hydpogeta ClYloYid'e

April 1 4, 2005
Fiie NuuBbcr 05-8005 Emp?.nyee Owraed ugtd (3perated



### '; ai ESTERN

~ , 

### IVVIROIVMENTAL S -ERITICES AP1D TESTlNG, INC.

P.O. Box 1625 2626 Fliun*ea° Ron-J, Qvitc 1Bv Sama Mara;Ds, Te:xPva 7366f

~ 51 2; 392-'y7i

~~ :

;~ fht

~ l J9Z- ~~.=~:~ Fux: 1 -1.::} 39; 2 7"190

~ {. 

### J ry J. Kn p

~ 

### Pr

~ 

### ect Manifgl



# //Elmerican Marazzi 'Cile Sunnyvale, Texas



### 1. INTROD11TCTION AND RESULTS S3JM iNIARY
Western Environrnental Services a.nd '1'esting, Inc. ( 1 7Vestern Environ.mental) of San Marcos, Texas, condticted a Stacl-c Er,nissions Sui

- vLy a.t the Anierican 1V.larazzi Ti1e facility in Sunnyvale, Texas April 14, 2005. The production rate during testing, was pov.nds per hour fired product.
Testing was conducted on Kiln 3 for the sources listed t?elow for the followin; com.pounds.

Source Compounds
IVlain Stack
Cooli.nl ; Stack Hydrogen Chlor'tde

~~ 

### ydrogen Fluorade
Summaries of the tcst restzlts are presented on the follovrring pages.

The sampling followed the procedures set forth in the Appendix to the Code of Federal Regulations, Title 40, Farts 51, 60 and 63.
Testing was coordinated 'by Mr. Steve Wiederwax, American IViarazzi Tile, and Mr. 3eff Knapp, Western Environmental. '1'he production rate for the testing vras
, 

### )ounds per hour f'ired product.

`'.

~ +1 t ~ •♦ •

v~Ls 

### t e~ •ra

~~ avirue

~ sree ~e~~f ~ee~~aa~s ~~ d'APste

~ g,

~ nc. 3D5-8Q3f35

### `lfABLE Dfl' C®NTE+ IYTS Page



### i. INTRODUCTIDN AND RESffJLTS SUMMAR`4I 1
It. '1` EST RESULTS 2 NU. TEST PRDC1GDITRES 4
IiT. SDURCE EMgSSIONS CALC'U'LATIONS 11

LIST OF TABLES Table 1: Kiln 1 Main Staek Hydrogen Fluoride and Hydrogen Chloride 2 '1'able 3: Kiln 1 Main Stack Sampling Locations 4

LIST OF FIGUR1CS Figure 1: Moisture Sampling Train 6 Figure 2: F'TTR Sampling System $ 

### LIST ®F APP]ENDICES Appendix A Sainpling Loca.tions Appendix B Field Testing Data Appendix C Computer Data Entry Appendix D Ana.lytical Data Appendix E Calibration of Equipment Appendix F Resumes of Test Personnel11. TlL'JST RES g.l,1JT1J

. Tab9e 1 HF and HCI [Uiain Stack Kilin 1 America.n Ma•aczi lile Sunnyvale, Texas

.

Run Number: Cerantic 1 ParceiaM 2Porcelain 3Porcalain AyerAae Start Date/'rfine 4114/2005 10:00 4114/2005 12:15 411412005 13:35 4114/2005 14:40 Porcelain Stop Date1T{me 4/1412005 10:35 4114/2005 12:50 4115/2005 14:10 411512005 15:15 7'as'E s Param®ters tJnits P a; ,, (9arometric nressure, abso ute) in. Hg 29.80 29.80 29.80 28.80 29.80 Y(Dry Gas P,r1eter Gatibration ractor) dit

- nensioniess 0.9960 0.9960 0.9960 0.9960 0.9960 C. (Pitot tube Coeificient) dimensiontess 0.842 0.842

. 0.842 0.842 0.842 J(Total Sampling i

ime of Teat) Minutes 35.0 36.0 35.0 35.0 35.0 AH (Qrifice Pressure Drop) In. H20 1.50 1.50 1.50 1.50 1.50 V,„ (Valurne of Dry Gas Sampied - as measured) 'ie (dr71) 26.818 26.353 25.158 24.727 25.079 1',„ (Gas Meter "remperature, avg.) Degr. F 89 92 96 98 95 V i . (Condensats - impingers and silica gel) ml or g 77.8 72.2 35.7 60.6 36.2 I,ocationlProc2ss F'aram

~ ters A, (Crass-sectional Area o€ Stack) ft2 5.37 5.37 5.37 5.37 5.37 P s (Static Presssure of Stack Gas) tn. H20 -0.22 -0.22 -0.22 -0.22 -0.22 T g (Temper°ature of Stack Gas) Deg. F 426 438 425 431 431 ,/A

- p (Sq. root of vetociiy head of gas) ~ In. H20 0.4013 0.3980 0.4286 0.4213 0.4153 COx (Carbon Dioxide) % 3.2 3 3.2 3.2 3.1 O z (Oxygen) °k 14.2 14.4 14.4 14.2 14.3 N..) (iVitrogen) °fo 82.6 82.6 82.4 82.6 82.5 Catculations V, Et d (Gas Sampled, standard conditions (std)) ft 3 25.67 24.16 24.91 24.54 24.54 V,,,td (Water Vapor iri Gas Sampled, std) h 3 3.66 3.40 1.68 2.85 2.64 B, M (Water Vapor in Gas, Proportion by Vol.) % 12.49 12.33 12.41 12.37 12.37 G d (Proportion of Dry Gas in stacic) a/o 87.6 87.7 87.8 87.6 87.63 EA (Excess Air) % 187 194 196 187 192.31 M d (Moiecutar Weight of Dry Stack Gas) lblib-rnoie 29.08 29.06 29.09 29.08 29.07 M s (MoEc:cular UVeight of Wet Stack Gas) €b/lb-mole 27.70 27.69 27.71 27.71 27.70 P. (Pressure of Stack Gas, Absolute) In. Hg 29.78 29.78 29.78 29.78 29.78 Flow Results V s (Average Stack Gas Vetocity) ftlm (fpm) 1796 1782 1917 1891 1863 Q yt d (Dry Volumetric Flovu Rate, std.) 1`1 3 /m (dscfm) 5006 4922 5351 5244 5172 Q. (Measured Volumetric Flow Rate, Actual) ft 3 1m (cfm) 9641 9866 10294 10152 10004 Hydroaten Chloride Concentration ppmw 9.976 28.333 26.917 27.880 27.710 Concentration PPmd 11.40 32.32 30.73 31.82 31.62 Em issions Ib/hr 0.32 0.90 0.93 0.95 0.93
Hvdroaen Fluaride Concentration ppmw 27.811 62.452 57.827 58.858 59.712 Concentration APmd 31.78 71.24 66.02 67.17 68.14 Em issions ib/hr 0.50 1.09 1.10 1.10 1.10

,..i ~ Western n nvie-onmen#:s<l Scrrraces ans9 Testang, Inc. 05-$005 2?► mcrican ATarar/i 'rilC Sunnyvale, Texas



### 1111. TEST PROCEDURES


### "I'he sampling and analytical procedures used followed the p

- rocedures outiv2ed by the Appendi

~~ 

### to the Code of Fcderal IZeg

~ 

### uiations, Titic 40, P3its 60 and 63. A brief description of each rnethod is provided below.
Part 60, Annend'ax A Method i "Sample and Velocity Z raverses for Stationary Sources" Method 2 "Determination of Stack Gas Velocity and Volumetric Flow Rate" Method 3 "Gas Analysis for the Determination of Dry Molecular Weight" Method 4 "Determination of Moisture Content



### in Stack Oas"
Part 63, Appendix A 

### 1l/Iethod 320 "Measuremerrt of Vapor Phase Organic and [norganic Emissions by

Extractive Fourier Tmnsformed Infrared (FTIR) Spectroscopy" Samplling Nln$ Determenati®n (Method 1) 

### EPA Method 1 was used to determine the location of velocity sampling points. Stack sampling points are based on the sta.ck diameter and the distance from the sampling ports to flow disturbances.
'U'able 3 Saflmp6ing Lmcaglons 

### Kgln 1 Main Stack Main Stacic Stack Diameter, inches 31 3l8 Upstream Diameters to Flow Disturbance 5.74 (180 inches) Downstream Diameters to Flow Disturbance 5.74 (180 iinches)

,.

, . Western Enyironfin!, Sntal Services nnd Tcsti

- pa, Ia

~ c. tl5-84U5 4Ainerican Marazi Tile Sunnyvale, Texas



### Vel®ci>ty and Fl®w Rate Determinatl®n (Method 2) Velocity and temperature were rneasured at the points determined ny Method 1 during isolcinetic testing. Wind tunnet calibrated Pitot tubes were used to measure velocity head. Type K t.hermocouples with digital pyrometers were u.sed to measure temperature.

Carb®n Daoxide9

~~~ 

### eag and Da' ~ I~®~ 

### ecaaBa ~ ~ 

### Tei

~~ 

### a>x_ ~ete~-a~a~~~$1®~a ~'I~ 

### eth®d ~~ 

### A portion of the gas from the sampling trains was collected in Tedla.r bags. Analysis of carbon dioxide (CO2) and oxygen (02) were performed with an Orsat Gas Analyzer. Dry molecular v4reight was calculated frOm COZ and 02 concentrati.ons.
iMoisgure Conteng Dettermenatiton (Method 4) Water entrained in the stack ;as was condensed and collected in chilled impingers in conjunction with the i.sokin.etic sampling. The volume of gas sampled was measured with a calibrated dry ga.s meter. Moisture content was calciilated from the gas and liquid volumes. A schematic of the moisture sampling system is shown in Figure 1.

Westre•n Environmental Services arad Testing, ine. 05-8005.4merican vlartzzzi '1'i le Sunnyvale, Texas

Temperature Sensor Heated Probe / Impingers

Type S Pitot ; ~

~ 3 E ~ • ,. IGe 13aU1



### Heated ~~Z

. tiT ~fi~ 

### adified Filter GreenBurg - Grcenburg-

~ 

### .eenbur - Gree
~ 

### urg Smith (I(10 Smith (I00 Smith g Smith ml HZO) ml H40) (Emp t y) (Silica Gel)
Temperatiu•e Scnsors By-Pass Valve Vacuum Gauge

Dry ca.s lviain 1Vleter Q Valve Manometer 'r Tight Pump - --- Figuire I 

### Moisture Sampl"nang Train

T~ , r

~~ . Western Environmentai Services and Testimg, Inc. 05-8005 6American Mara

- r.

~ i Tile Sunnyvale, Texais


### I+'aurierTransf®rm Infr2red Monit®n• (fTgR. ~ 

### Pollutant concentrations were c}uantified in accordance with EPA Reference Method 320. Test contaminants measured and reported using the FTIR include the following:
* Hydrogen Chloride ® Hydrogen Fluoride
Western Environmental operates an extractive Fourier transform infrared (FTIR) spectrometer manufactured by Industria! Monitor and Control Coiporation (IiV[ACC) of Austin, Texas. The FTIR is composed of four main systems; the analytical bench, the cell, analytical software, and e:ctractive sampling system.
© The IMACC FTIR operates on a Nicolet bench with a zinc selenide beam splitter, fieNe laser, an IR sour ce, and an MCT-A detector.

© The cell is composed of objective and field mirrors, which are gold plated. The cell is designed as part of the FTIR unit, which is capable of operating at a path length of 10 3neters. 'i'he celi volurne is 2.728 liters. The cell is operated at a temperature of 185 C and is coated with nickel to prevent corrosion. Analytical system leak checks were performed prior to any testing. Results of the leak check are - provided on the field data sheets contained in the Appendices.
o The analytical soflware used by Western Environmental is Nicolet based so$ware with 1MACC modifications to improve the softvvare suitability for extractive FTIR monitoriuig. T'he rnain programs utilized in the collection of data are Omnic and Getconcs. All Graphical presentation dtuuig sampling was performed by Concview.

0 The extractive sarnpling system is composed of a heated probe and heated Iilter assembiy operated at 185 C. The fiher assembly was connected to a heated sample line that delivers the sample to the FTIR cell. The sample was drawn through the cell at 10 liters per minute by a heated sample puinp connected to the exha.ust port of the cell.

.~ ; Western E nvircanuncntai Services aanci Te5timg, dnc. 05-8005 7-- Stack Wall with port

~~ ff i fiylt`.
~ 'SYY[77.ti iiCL:ls45

I Heated S, , unple f'rCn

~ inl f i

~ n 

# \ Heatecl Glass Probe American Mara

- rzi Tile Sunnyvate, Texas



### Sclaemat$c ®f Metrh®d 320 Samflplang Trann



### 1Figure 2 FTA.R SampOng Sysgenn
This method applies to the analysis of vapor phase or;anic or inorganic compounds, which absorb energy i.n the mid-infrared spectral region, about 400 to 4500 cm 1 (25 to 2.5 μm). 'This method is used to determine compound-specific concerrtrations in a multi-component vapor phase sample, which is contained in a closed-path gas cell. Spectra of samples are collected using double beam infrared absorption spectroscopy. Omn.ic is used to analyze the sample spectra and report the compound concentrations. Exa.mple absorbance spectra may be found in the Appendices.

Analytical range and sensitivity depend on the frequency-dependent analyte absorptivity, instrument conf guration, data collection parameters, and gas stream composition. Instniment factors include: ® spectral resolution,

Western Environrnenta! Servdces and '1'vsting, Inc. 05-8005 8American Maazzi Tile Sunnyvale, Texas

m 

### interferoineter signal averaging time ® detector sensitivity and response, and ® absoiption path length. Due to the unique nature of hydrogen chloride and hydro;en fluoride the following QA/QC efforts were performed in addition to the requirements of EPA 320. * Line loss detenni.nation was conducted at various concentrations using Hydrogen Chloride. Pcrccnt recovei

- y was 99.23%. Documentation is provided in the Appendices. * Sainple line conditioning was perfor.med for a minimum of 18 hours to ensure proper sample acquisition and spike recovery due to inherent line permeation of HF and HCI. * Multiple backgrotmds were performed during the testing period. An estunate of gas composition was inade based on previous test data, and duritlg preliminaty scr.eening. The spiking for hydrogen chloride was perfonned ili accordance with EPA 320 in fhat the spike value was based on preliminary observatio.ns and expected co.ncentrations. Optimal resolution for the INIACC

- unit is 0.5 cm 1. In accordance with the MACT standard similar source spiking has been provided as docw

- nentation of spilcing. Instrumental conf guration shall be selected based upon manufacturer suggestions and previous experience. Spectral interferants shall be identified using the selected band areas from reference spectra and interferant spectra. .Example spectra of interferants may be found in the Appendices. Analytical method dcvelopment included linearization of compounds over the range of detection, line 

## slv.fl adjustment, and inclusion of interferants. The baseline noise of the system was measured in each ana.lytical region to determine the Maximum Analytical Uncertainty (MATJ) of the instrument configuration for the analyte(s) of interest. All cotnpounds measured in this test program were above the detection limits for the compounds. The Appendices contain the baseline noise of the instrument. A hard copy of the analytical methodology may be found in the Appendices.

In extractive sampling a probe assembiy and putnp wili be used to extract gas from the exhaust of the source and transport the sample to the FTIR gas cell. Typically, the sarnpling apparatus is simzlar to that used for a single-component emissions monitor. The digitized infrared spectrum of the sanaple in the FTIR gas cell 

## rs measured and stored on a compu#er with a backup stored on a separate disk. A copy of the spectral data is included in this report.

.. Westca-o Enwirnnmenta ➢ Services and'Tes#ing,'tne. 05-8005 9Ainerican Marar.zi Tile Sunnyvale, Texas 

### Specifications for the I1l/IACC FTIR. and testing pararneters are provided below: m Appodization — Happ-Genzel * Resolution — 0.5 as detei

- mined at 1149 cin 1
0 Detector -- MC"T-A Ij CelI Vol«nie — 2.728 liters Indeperadent iarnple Tirne -- (at 10 lpxn) 1.36 min
P re anad P ast T est Evaluations Q Pre- and Post-test CTS spectra were gathered and evaluated. o Pre- and Post-test NEA (Noise Equivalent Absorbance) and Background measurements were made for each source. 'Three independent spectr ra were gathered at the source prior to testuig. Spike ilow rate was 1 liter per minute as measured by a mass flow controllcr. An independent sample is on.e that is gathered after 5 cell volumes have passed through the ce11(Section 3.6.2 Method 320). Because the cell volume was 2.728 liters and the system flow rate was at least 101iters per minute the independent sample tirne was less than 1.36 minutes. Spiking was performed on a 2-nninute integration interval and therefore the spike measurements vsrere obtained with a min.imum two-minute separation. a Path length determi.nation. Path length was determined prior to tcsting using chlorodifluoroniethane in nitrogen at a concentration of 10.1 ppm. [7sing in:legrated area ratios against a reference standard concentration the path length was deterrriined. A copy of the calibration cerrif cates may tie found in. the Appendices. m A complete system leak check was performed prior to testing. Results of the system leak check are provided on the field data sheets.

'S r {9

~ J-~~~}~J ~ a u~ 

### `:.

~ 

### filesteF m En

~ 

### rmnme

~ 

### atal Serviceg as

~ 

### t8 '

~ 

### 'estang, tnc.3. Modsture contemt, %
B ws — v

' Y( " d) x100% um(sW) '+' uw(sW)

~ 

### 3.66 x100 °/n 25.67 + 3.66 - 12.49 % B„ 7 = Percent by volunie of water vapor in the gas strecuit
v„ t ,, d) = Volume 0t 3

) of water collected, at standard cornditioirs V,,, ( ,,, o — Vol tctne {V) of gas tiv

- ough the dry gas nieter, at Standard conditio)1S American Marazzi Tile Sunnyvale, Tocas


### TV. S®URCE EMISSI®NS CALCIJLATI®NS The values in the sample calculations shown below are from the 1Viain Stack Run 1. Computer generated numbers were used to eliminate rounding error.
1. b'olume of water collected, staudai•d cond'ations (wscf):
Vt.(std) = it(Vjc) = 0.04707(77.8) 

### = 3.66 wscf yqrrd) = L'olume (1?) of iyater collected at stcindard r:rnzditialar V r , = Vollrnie of'll yriid vollec•ted ln iia:pingers K — 0.0=1707 , C'onverslonfcrclar (ft ; /ml)

V,,, = Vol icune (ft 3

) o, f'gas tlrrough the clry gas ineter, at
standard conditions V,. — Volume (fi 3

) ofgas sample through the dry gas meter, ambient conclftions P&,. — Baron:etric pressure (inches of Hg) dH = Average pressure drop across meter orifice (in. H

~ O) Y— Drygas nteter conversion factor ?',,, — Average dry ga,s meter ten:peratw-e (°F) K= 17. 647 — Conversion factor (°IUinch Hg) 13.6 = Conversion factor (inch H 2 O/inch Hg) 460 = Comersion constant (°F to °P) Z. b'olume of gas nueterecl, staud:ard comditeoas (dsct)

(K)(V m)(Pbar +

~ 3

~ )(Y) 

### (460 + Tm) (17.647)(26.818)( 29 

### .80 + l3 6 

### )(0•996) (460 + 89) = 25 .67 dscf

_.~
' Western Environmental Services aroct Testing, gnc. 05-8005 

### 11American Marar.zi Tile Sunnyvale, Texas

4. Dry Gas, % Gd = 100-B, s• = 100-(12.49) = 87.5%

5. Mr>lecalar zreaght ol' dry Mas streaua (1b/1b-niole)

( ".

~ Ct)2) (°b0z) (°.

~ ,CO + 0 6 , 42)

~ d = NI co:

- - ~ • Ma: ----

- I - ( M r.c

► „ ~ M N: )

(100) (IQO) (IOO)

~ 44.0 (3.2) + 32.0

(14.2) + 28.0

(82.G) (100) (100) (l 0U) — 29.08 lb/lb mole

streatn 100 - - = Conversion from percent to decirnal fraction G d = Percent oj'dry gas by volutne in the gas stream B,,, — Percent by volume of ivater vapor in the gas stream

~,I, j ~ Dry tnolec•rtlar ti;efght o • f'santple ga.s (lh/lb•tnole) 11t

~ 0 2 — rUlolecttlar• sviglit of cat-bon clioxicle (Ib%lb

~ tr:ole) H o; — :blolectllar weight of oxygen (lb/lb'tnole)

~ c.n

~ rva =

~ .rllolecular weiglzt of CO or 1V 2 (1 b/1 b -ntole) (Sante) CO 2 = Percent by voltime of CO2 ln tlze ga.s stream 02 = Percent by volume of axygen in t/te gas stream CO+N 2 = Per-cent by volurne of CO and N a ln the gas

6. IYdolecular weight of sannple gas (15/lb-mole) M S = (K)(G (I / 100)+(M H2o )(B ws / 100) = (29.08)(87.5/100)+(18)(12.49/100) =27.71b/lb rnole

7. Sainple gas pressure (iuches of Hg)

p s = 

### (N)

(13.6) =(29.75)+ 

### (-0'Z2)

(13.6) 

### =29.78 in. Hg

8. Velocity of sample gas (ft/miaa)

V $ =(K p XC p X60 XVAP T S + 460 (M s Xps )
476 + 460 = (85.49 )(0.842 XC

~ O

~ '(0.4013 ) 27 .70 x29 .7Y = 1,796 fpm M s = Molecular weight of sample gas, wet (lb/Ib•mole) U J = Dty molecular weight ofsatrtple oas (1b/lb-tnole) G,j Percent of drygas by volittne in the gas stream B, vs = Percent by volume of water vapor in tlze gas str•eam MFtzo = Molecular wefght of watet• (Ib/lb-mole)
P, L Ahsolttte santple gas pressure (inches of Hg) Pbl,. — Rarometric pressure (inches of Hg
~

P x = Saatple gas static pressure (inches of H Z O) 13.6 — Conver.sion factor (lnches 11 ? 01inches of •Hg)

C P — Pitot tttbe constant k p = Yeloctty pressure coefficient (dlmensionless) 60

— Conversion factor (sec•/tnin) A , f, = t1?olecular velght of sample gas, wet (lb/!b•mole) P a — Absolute snrttple gas pressure (inches nf Ng) T, = ilverage santple gas tetttperature (°F) LJ = Sample gas veloclly (fi/lnin) Q p 

# a .lverage sqttare rorlts of veloc•itv heads of stack gas (in Ff,U) 460 = Conversion constant (°Fto °R) 

# % A' : Wesgee•aa iEsavirowmecagat Sea•v9ces and '1'estiug, Ilrnc. m5-8005 

### 12,Aineriean MRrazci Tile Sunnyvate, Texas 9. TOta@ $larw of samplc gas, stctusal conditn,aats (acfm) Qo = (As)(Vs) = (5.3'1)( I,796) = 9,641 cfm Q a volrcnteti•fc floiv t•ate at actzral conclitions (acfm) A, = Cyoss sectional area of satnpling locatfora (fV) i~ r = Satrrple gas velociry O/urin)

10. Tt)#al flU'fiV UY SaMple ozas, sta7t(12rd cORd=.tlO[I5

{~s~~ m} • (QA)(PS)( f 7.647)`

1100 

## ~ (T!, -t- 460) (9,641)(29.78)(17.647) 8 7.5



# _ 100

(426 +460) = 5,006 dscf Q.rrr! 'VolutFUtricflotiv rate at statadard condtions, diy basis (dscfiri) Q„ --- Y'olumetric flotv rcrte at actrral cotiditiorrs (acf n) I',. — ilbsol2cte sample gas presszu•e (iszches of'11;) G,r -= Percent of

cliy gres by volittrte an the gas str•eam 1;
~ tverage sample gas tenaperature (°F
~ 17.647 — Corn.erstoii factor (°IZ'itach I:fg) 460 — Canver.sion constant (°I' lo °R)

Westcrn Etavirvuniental Serareccs ttncl Tes

- Ling, Inc. 05-8405 

### 13

# APPENDICES A. Sam;pH!ng Locati®ifts Bo Fteld D'ata Sheets 

## C. COMPUler 

# Dat-a 

# Entir-Y & ADalyt-ac

- al Da$a E. Calibrgti®n o' f Equipm

- ent F. 9. 0 - 

## sagoes of'Test Peirs:onnel

## APPET"I slalAlplin 'g , LO

- C 

## atib-as~ 

### aIM I Sq .- ~r~ 

### pSung 'Le«adeas Malua stack 

### inside Sfwk Diameter = 31 3{8 inckes Pozt md Wati ''thickness = 3 5I8 incfies



### Sampte % of ludes frvm E£tln

- t ho.

~~~

Il ~~GI' ~ T 2.1 'N

~ ! 2 6.7 3 1118 3' 1 /1s 4 17.7 5 ,1 11 s 3 25.0 7 13 116 6 35.6 i 1 3 It6 7 64.4 f-20 3 11(,

~ '?~.4~ ~3 1 12 9 32.3 25 13 ljG 

### i#D 8 S. 1

2 7.7 i 'I 1 4 11 93.3 29'14 

### 12 97.9 ''30 3 1g 'Iftint iacated at I" *om

-

vvaii per EPA. iMethod I

# APPENDIX B Fie

. ld Testing Data_ Clent;

LACBdon: Operator: ` 1117 Job No.: Pott A
Part & imsfde Dba.:

Port & 3mide Wail 1'tftk:

Snside "JIesgern Environnieratat SeQ+.rfcee erad Tsetin8, lna. Prea3nwtSTy vetociiy ®o4a

Sourae ldanti€icetton

~ -4 ~ 0 Port B. Part C Port O

TDME: Pt3RTi cA "?CRT B PCiRT C PQRT O

D' si.fram Point Ra9. point, aist. ftm Ref. No. 9'o F)ia. 0.01 1, Poi;1t, 1/1 fi ° _„p 1 Ternp ! GYd. _P /'temp t Cya1. ,_.P ! Temp J Gycl. _P / Tc;mp / G

~ rd.



### 2

~ 

### -`"1 "Z..1

~ 

### 9 'Z ~ 

### 1c. 3 

### a i`? •

- T ts

— 

### 7~

7 ~ .~ '~.'~ ~ `~~ . i~ g .C

~ 2~ -~'j `~.~ I Z I / 1 1 1 I 1 1 9 at a ' 1 1 1 I I I 1 ! 10 'z7. o; ~ 7 

### — e7 1 (o 11 'Z 4

j• -Z`]. -zq 12 • ~ ' 

### 2 0-1

- z so ~ Aver39e: 

### Pitot No. % Moisture Velocgym C CO2 ''ime of °Tesf - 

### Pb 02 Assumed SCIFM Ps Co Assumed Vrnstd As N2 Dn 

### A.._._P Md SCPM Earn te Av . v P tUIUVd / H Av .Ts mU4! K Pactor Ayp.C clonic !/mstd 

### Area og Stack: !soldnefic

ACPU SCFM SEE BACK POR g3fl1bWIN43 AND PUFffHEA 1NPC}RMATIOiV 'S1andard. 628 R. 29-92 "Hg, (20 C., 760 rtm M9)oparBCrR► a74iaf=88%8%8Qs "lient: 

### rm S#ack at Sample Locatson: :i ® / rectenguiar
3ism®ter, equit aient: :pstream Equivaierit Diarrleters: 

### ?ownsgrearn EguZvatent DianZeters: *or rectanguiar siack, De Caiculaiion: I x ier&gih x-yttidth _ 

### length + }Mdth -;derior St,ack Schemagc: ndicate BD, p'&W, P&MQD) 

### Rec8engulae:llLack iP®int Cabudadoae , Side dirnenstOR/nuraber ot points 

### First iaoint is baEf tfia 

### t di'st 

### ance #ram the tront viaii


# ~

,~ - 

# d 

# ~

a,

- ~l ~ ~ t0 ` K ~

`~ "~

### Paceiify 6~~' 

### Job i ~®: ~~



### Run f ~o.~ 

### Cate: ~ 

### /y o5 — SourceJ I.D. No. 

## d2&g :.5;

~ 

## c Stack: Area in 2 A 3 ) Dia (in) Operators Meter Box #2Y_Ca1ib. Pactor(Y) d• 

### Nozzte k -- Diame4er (Da..=_ 

### Pitot t.D. L-%,Q Caitb.Factor(CO.QaZ--



### FloOd DataA

### Western Endiro,ifhantal$ervic;es and Testing, Inc.

o9Stsck Cnass Secdon K Factor -- 

### Barometric Pressure (P b ) ,~~ 

### Amb. ° F ._75

~ — 

### Assurned Mofsture °la 15 ~ 

### Static Stack Pressure "H20 ,$ Probe Lenyrh ! Material 1 1 

### 56

. Befare t~ lddla 

### Afit 

### Pltot

~ 

### 'ube Leait Check , ~~ 

### r__._.. 

### lnhlaf Leait(d,} ,,d

~ 

### „RHg =- g- Ornin oF' Up Gas Now Ou41 i Pinal Leak @ fJ" . O ui•ig = e.gX ff/rnin



# ~~ IF)M 

# b~

PA. M

. 

# m K ~a I ~e~ 

# mi 1

~ 

# ~ 

# WAWA ~~~~ 

# lmom ~:a~aa~~~~~~~~~ 

# - r~ s ~~ 

# wact

~ 

# ai
~a~ ~e~~~a~~a~~~~~~~~m~~~; AM 

# munmim ~~ Im~~~~~~r s~~~~~~~ ~ar~;



# ~ 

# M

. 

# M! m =No ~~~~DF~~i

WE ~~Y ~~~'~i~~~~

Uncorrected Vra, __„_ „ + ft 3 %CO2 

# ' _ %CO_____, Sampfe Purae: in3#ia! F'tna l~ 

### Corrected V,,,. _„_ fi 3 %02

~~ 

### , ~ 

### °IoN2_„_ !lolurne Collected 1l j

. , r ,______ mi Sample Time, 8 min..aob No: 0

~ 2 900 'rZ) 

### Run

~ 

### Faeld DaM Samgs9e Box l:to:,_

~ 

### ____._ Source !D 111o: 

## 1'-Nkvz

- :~ 

### Filter No:



### # 2 ~ 

### 5 Loonisnmivmo ~~ ~~~ ~~-~ ~ 

### , G-. • :



### , nP style P

- %03> ce - ~- ~~~~ v C=; D 

### RBBal

~~ 

## . Set- o aa. t) s,

. ~ 

## ''

- 1 •.1 ~ 

### Initial Wt. S ~(~ ~~ l .~ 

### SFs''Z ` t 1 6 142- ~ 

### 5 D9fferQnce 

### T®w (VIC) f Me=

~ ot-!= Ts= Tn„= 1/MsW= % iw Md = 

### 1tw aas = 

### Mwa=
VS 8CfIT1 

### dscfm 

## EA °!o flSO
Catculatioras

V vx = 0.04707(Vi c ) VM4.o _ (17 647)(Vn}(Pt,+Z)(Y)

(460+T.) ~

Bvs = V xI00%

~c~ + V~c~~ Gd = '100-BH,S,
M d = 0.44(%C42) + 0.32( 0 /164 2 ) + 0.2${°/bN2 + %CO} MS = (Md) (Gd/i 00)+0 8)M,.-Jl 00) P s z (PL


### ~ } (P8)

(13.6) 

# 'r
P )(C,)(6Ox1APk 

# j

~~ s + 46Q
v s ~~ (MS x p s ) Qa = (As)(VS) (acfin) (Qa)(Ps)(17-647)( 

# to

~~ , O

- 

### fTs G~~ —

,



### + ~ 

### 60)

K(T s + 460 ~ Vm (std )) i ° 

## (Ps ) 

# ~~~( ~ -) ° { 

# ~ ~ Vy,= Volums aftlquid CaMwed (grsms ornt# 8fld = Dry nroleaularvyelghf cf sempfe yas (ltrlfbumols) M s = Mabauler tvaJght af sXrtple gas, wet (1hOfb*ma/e) 96CO2 = PerCnt hy valuma of CO2 fn tha ga.s sbeSm °60$ = PgwrJt,ey vvfctrns ofaxyggn In !he gas siream gSC04%lUa = Pensntby volums Qf CO arrd Alz In Hre gas Gd M F+sMent af dry gas 8y sralunge ln the gas s&erm fi6 = % by votuumofwaterYaWIn ft gasstwm P a =Absafuto sarnpla gespraum (l,rejies oftEg) P6, = BaJamebfc pvwm ('iuhes af Ng) P o = SeMPle 9as stsft MMMM (Fiudtes of H20) 136 a Ca;wm&nfaafarr'mchw H20lfnch¢s of NgJ Cp = Pllat trtbe constent Kp = Velaaity prssscag coelTtcfent (dTmsnslcrilsss} = 85 49 G!? a Carrvnrsion fector (secftTq) M, =1tllaleaularwsighf of samp/a gas, wet (1Mb-mole) P ; , = AbsolrAg sample ga.s pnwura ('mahes of Ffg) T ? s Aver8ge 38mp1@ g8s hammpmture (79 !I a a Sampde gas vsl404y (3t/se4 d P= Avwage squsm mata cf yefacFly heads of grts (in N20) 460 = Ccrtverslan canstant (°F to °R) Q a = Vofumstlfa flow rob st Qrtuel aonditlons (8c.lfm) A, = Craw ss.atlana/ aram of sampl;rrg loccatlan lW) V. = samPlb 9as velocdy (rdnzfn) Q z w = VaL flaw rsts et stenriard condilfcns, dry (ct,scfm) K = 0.09460 = corzterrt D. =Avsm g

a d1ameter of nazda W) 0 = To#al samFling tims (min)

### Faciiity

.. 

### al'I , '



### . , ~ 

### job W a 0'5

- 7;P0 

## Run fvo, - Date: Source/ I.D. No. _ ~~ ~~~ 

# ,_.... ~ 

## S t 

## ac

~ 

## t: ,

~ 

## rea in 2 (A L ) Dia (in),_______„ flp$rators , ~~ 

## rj°

_ l~ 

### teter Box # 2t Calib. Factor(Y) ,~ 

# ,,., ~



# 9 4 No~e # = Dlameter wito# t.i~. ~ ~a Callb.Factor(Co .~~ 

### Z„

~ 

### i-v, ~~ 

### Fge9d Data



## A r 

## Westertt Environrrceritial Services and Testing, ltic. K Factor Baromafrio Pressure (Pb) 

# .RM Amb. ° F . 

# ~ t Assumed illioistufe a/a 

# 6E Static Siac€c Pressure "H20 Probe Length / Nia9e(ai Before twaer 

### P itot Tube ~a 

### k Cber 

### k ~ ~ 

### lnttiai Lsak 0 0 "Hg ~ ~Z ) 

### ft 3 /cnin Final L.eak 0 o j'Hg- W/rnin



# ~:~.~~. 

# I —

. . . 

## ~ 

# Com

~~ 

# MIFA IMIWWA RIM

M-.~~~~~



# LEE 

# W, i l som M~~M

. . ....

y 

# I~ M~
~—~ 

# -. MON= NO
_~~

Uncorrected V, , __fi 3 °!oCO2 . D %Cq

~ 

### Sampte Rurge: tMa l

.. 

### Fka! Corrected V,
, --,ff %02 • %AJ

~,~ 

### Volume CoiiWed V

~ 

### „_ mi Sampte Time, 8-,min..9ob No: OS R¢sn # ~



## Field Datq_e/&

.I&re Sampl® B®x No:_______ Source 8D No: lcz Pi

~ it

~ eP No: VI~ AHM —

, • 

### 4 5 T s 

### TM= Qmpinger # 1 2 3 57 fca 

### Contentwoto .P/ /PI

~ ~. 

## T p ~ ~. ~..,~ ~~~s.~► ~ ~ 

### . rvt. ~s~

C~ t ~ J~



### ~~~ ~ r

~ t►R ~U~ 

### Vs• 

### acfrn' g ~ ZT"'F1f73 ~ tB ti`1S74a r r '~ `7 ~ 7J ~ L ✓ ~~U e a~
~ / ~ C ~ "

+YJ i

~ J 

### 4nliflaa Wte

~ 

### 89- ~

~ 

### - ~ 

### o

09V ,. ~~ 

### , Defference 

### dsafm EA . T®tai (vw) % 080

~ Calcu[ataons

~ I,z 0.04707(V ic )



## _ (I7.647)(V.j jF6 + °H ) ('Y )

(460+''

~ ,) ~ ..i ~

~ 

## ss ~ VWAmy 

## xl0a'p/o VM(%* +VW(S* Gd -= I OD-K

vm IMd= 33.44( °

foCO2) + 0.32(°fo02) + 0.28(%N2 + °loCO) K = (Md)(GdI 00)+0 8)(8 v d9 d30)
P 's ~ + (P8)

(13.6)


### V s - (K P XC P X60XVa) ~ 

### +



### ~ 464



### ~ Ms 

### ~ 's) 

### Qa = (As)(Vs) (acfm) (Qa)('z)(l7 

# a~

647)( $~~ = (fa -1-46Q)
K(T 9 + 460)( Vm (std0 1~ (PS ~~ 6d N ~ 4~1 ® ( 0 ) Ve= Vckrmer sifdoprtd Callbcted (grams or mlJ M 13rymaboutarmeFght o,t'stimFle 8n P/Mnncta) M e lYlatoattfer woW of wmpte 9as, tsre# (WbemuEs) 46CO2 = F'encentby sraluw cf COa hr the gges sbasm 9602 = Pement by vclumm ef axygen ln tfie gas sLream °,6C0+%N2 = Penerlt by valume cf CO arzd N? In ttle Qes Ga = Penaent

afdtygas by volume fn ffte gassbwm @6 = 9d by vdume of osnQtereraporfn Lh+s ges sftem P a - Absofute 88mp#e gas "^ara (hiche8 of Hgj P6 r = Barcmatde prsssura (fnthes afHgj P g - Sample gas staftpmwwe {indres aFNA) 43.6 = Ccntrarskn gacl`or (lncPres HgOrrraobss cf Ng) C o = phw bbe coastant K p = veMclty prassurra cnsffcferrt (dlrlferrsfonles)= 85.49 50 a Canverssan fecta-{seclmfn) M o = ABolecaar taneiglit cf sam#e gas, wet (f.ir/Ib-rnore) P a = Altso/ute sampfs gas Rreswm (lnch,es nf Hg} T, = Averag$ sarnplP gss iemAmkm f°Fj V a = Sampla 9as VOW* (ffwc) a P= Avmge squam mais aF vidav7y bEads cf gas fn Hs0) 460 = Cmvetean cnrssfairtrF to-°R) Q n = VoJumeft f7aw rate at tdual aartcWWs (aefrn) A s = Crvss seeftrtd area of sampfft lacellon (t' a + ) N a rs Sarajvl8 gas vsj,pav (Rlrnivt) Q cm - Nal ftwtate atstandarti ccndk#cns, dry (dscfm) K = 0.05460 = csnstarlt D n =Avcrags diamster cef aoale M 9 n TWsamplFrig ffine (mfn)

### FaciBifcy 

# }JIA ,* 

# r Job lVo: 45 7 I 

## Run No,

~ 

# _ Date: Source/ I.D. No. 

# _~ 6r Stack: Area in 2 (A s 

# I,_„_ ©la (in)_ Operators 

# ,, Meter 6ox #, Calib. Faotor(Y

~~ ; 

### .Y2,/ 

## Nozzle #

_ Diameter (C n )_.=. Pitot I.D. –ie> Catib.FactortCO — a. , 

### &,~

,,~L~ 

### vre F6eld ®ata 8chsmsft a! Star* Crm 8ecwn '


### ;

AJ l



## oi' U Gas Faow ®u$ I in VUestem Environmental Services and ies4ing, Inc. K Factor

-- 

## Baromefric pressure (Pb) -

~



## __ 9_ r __, Amb. ° Fjf ~ 

## Assumed iWotsture %! ~ 5tatic Staclt Pressure "HzC ( } ~ 

### _o • _? ~ 

### _ 

## probe Length 1 Material 't3efore Mtk% After 

### Pitot Tube Leak Checit 4t tnitial Leak ('

c,

~ , /,5- d ~ 

### 'Hg = agog ft 3 lrnin Final Leak (a

~ 

# A- 0 "i•ig =0 dxO fi 3 lmin



# ~~~~ ~s~r~ar~~~~~~ a~~a~'I VA~~e~; 

# MEMN A, ~ 

# r.~~~ 

# M 

# I We~WA

I 

# WAM~we~»; 

# I~ ~e~s~~~r~a~~~~~~~~~~c~~~~~; 

# im
. e~e~~~~~~~av~~~~m~~~;
mr~~~es~~ae~~ss~ ~ ~~ 

# .

Uncorrected vm - - - fi 3 %co231 2 %Co,,.,._.. q , Sample "e: iniUat Fin - - - Correct®d V m ~n 3 

## % %Nz Volume Collected V l ,, mi Sampte Time, 0 ?r" min.Jolb tVo:



## © S'_Mi? 5 Run # "S Fissd t?aga 

### or,s ~v~-P 

### Sample sou lLto:, ~ source 10 No: lo-ol.9 

## ~ FoTmr No:_______,



# ~ lmpinger # 2 3 4 

# ~

. .
~ 

### CY.asatan1KlNole

.

, 

### nP style ;~~ ~..~ . .~~► ~ a~ 

### Fina8 1pjt. / 

### d. 0 4"'

~ 

### 7 0 f 2D- 2 6y 

## an"stea, M.

~~-~ ~ a . ~ s-, ~ . 

### ®bfferance T®tal (V tc ) ~l~ 

### P= v1c ~ 

## nt

~ 

## = TS= Tre 

### vMw=

~~ O bm
mdw

~ 

### a as

Y= MWC=

~ 

# = Vs acfan dsofM EA 

### sro HS®
Caicaa9ations V,,,. = 0.04707(VO
{i?.647}('ET6)(Pb ~+~~ a l{Y~

~ ) (460+Tns)

v ~ 

### ¢ .

~ V

m 

### =sd ) - ~ 

### - gT

. 

### m ) 

### xfll

~ 

### fl /o
G d - 1 00-B wa , #UI d =- 0.44(°IocO 2

) fi- 0.32(°lcC32) + 0.2$(°JoN2 + %G:o) Ms = (Md3(Gd19 00)+(1 8)(Bws11 CO) p s (pta)} (Pa)

(13.6)

v s = ( 

# I (MAO Cia (As)(Us) (acFm) {Q1M)Po}{17.64 

### G d 

# ~ 100 

# ~ (Ta + 460)

IC (T s + 460 )( V m (std )) I m
~



# ~ ps X 

# ~ )( 

# ~

- 

# ~ ° ( 

# ~ ) Vep ddinw oflfquid CvlWcftd Egrams ormQ

!!~ ~ QrymalsautarweJrt ofsample gas {ui/ffrnrole) l39aleoulsr€vaFgftP afmmpfe gm wet(thilb*mole} 4&COp = F'emmt by valturra of CO2 fn Me gas stream q602 = Penaealsy volume of exygm In the gas sbearrl g6C0¢°.6Na c Perraent by vafrtrrm oF CO arzd IVQ in lbe gas Ga= Panehtafrfry8as by volus:e ln fhe ges shmm Bn = 96 by vcfirrne af

watet tiawin the gas stresm P. m Absadrtte SBniW9 Q.48 pmsstFle {irlChes Qf Haj P&, = Beromeb"'

~ a pressm (fitefrBS ofHiV P g = S'ample gss sWo Pmsaum (krclrss af N-,0) 116 a Com/emfcn f8dar(btcfl83 F120/Tnahes of Hg} Cp s Pltat &ibe canstatrt

K D ~ Ve{car7yMeSMrrs caefircfant {dlmsnsiaRlegsJ - 86.49 HQ Cammrstan featvr (seafinir# RN, = Marooelarwefg3rtafsamyo g=, wer(fwlb-mcte) P. = Absoktte sempfe gas Fressm (Fnakss of hfg) T a = Avemge sampls gast lbnrF$retuna (°F) V ? = Sarnple gas v+slacityWtoo
d► P= Amsgs squsra mots of valoaltyhssds cf gas (la 1410) 4&g g CoAversfw aansteat {°F fb °i?) 0 0 a VoGurraMa tlaKr Pate at acwal condlltorts (eofr») A Q o Ctam secffarttt/ eract ofsolupl' irtg loaetfvn t0 V, - Sear#e gas velcc!!y (Wmfn) Q,w = Vot BOtiv taib et standatd cotsdiBa/:s. dry (dscf}r ) K 3 0.09460 = corrstaat D„ n Avemge tG8lti8terafnoszb {!ej e = Totalaenipting time fraa#

### a aci6ity 

### 4y/

— f Job No: G.

~



### , iZun No.

~ 

### _ Date:/L to- 5 : - Source! I.D. No.Aw/•u S; ~ 

### Stack: Area in 2 ( ) Dia (in) Operatom._ 

### Meter Box # 

# _2K Caiib. FactorM D• Nozzle 0 --- Diameter (D

~ 

### _ ""' _ Pitot i.D. 4-0 . Cal1b.Factor(Cp) 

### &.-22 

## et.

~ 

## Fie9d Data SahemaUa af Stack Cmss SeciJon



# ~ uN 

# ~

Gas NoW ®ut / on Western Environrnenta! 8ervices and TestiRg, inc. K Factor 

## Barometric pressure (P

~ 

## } Amb. °

~ 

## Assumed Moisture ° _______ Static Stack Pressure 'i•120 (+/ 0•2 Z

~~ 

### P ro 

### be Length l 

### Matesia! f I
~~ 

### Before MWe A~ ier 

### 1'itot Tubo Leak Checic initial Leaic @ "Hg =_ a- _,_ft 3 lMin 

### Final Leak @ "Hg =&W i O ft 3 lmin 

# 1~~~~+r~Q~,~l 

# r, a le ~r-~~mm~~ ~al 

# WA W,AWiMA mi
~~



## ~~~~~~~~ 

# M'.- ~ 

# MIrm

~~~~~~~~~~~



# ~o~ar~~ 

# avverame ~v~~l~~

wm~~Mlt~~~~

UnconWed Vu_------ e 96CO2 

## 3,2--_ °YoCO

~ 

### 8ample Furge: Ini#3a! Fouf Corrected 1!m ,,_ ft 3 %02 %N2_____ Voiume Coilected Vi G , ml Sampie Time, 8min.Job 'N®a 

### AX- ADO 5 — Run # 

# .22!

Field ~~a ~~ 

### r ~ 

### .. Samp8e Box No:_ 

### saurce BL4 No: Fi1Uer No: 

### MpIngeor ?"F I ~ 

## 3 

## 4 ~

~ ~ 

# o

~ 

# n

~ 

# o ~a 

### 1,PtM-0 ~ ! D ly , C4. -

~ '- ~ T i~ ~~ 

### ygeo -4 ~ ~- ~ ° ~~! ~ 

### " o'•%

~ 

### v ' ~ 

## lnvtiag Wt 790 _0 

# 1 .5

- ey - '7. S S

:;v . 2-
otw (V tr .) 

### XAc= AH= Ten Ti,=
vmste 

### olo M M 6 w



### Mw= 

### vs acfrn dsGhn 

### EA "!0 6 aO Cagculations tIb= tlolutne afL7qutd Co1/ed1Ed (gtarns ormi} Vv, c = 0

. 0 4" 107 (Vtc) R9a-D)lrrnalecularwelghtofsemplegas(6MPmcie) A9, s li9creaulerwelgfit ofssarplegsst f rsvetM/lbPmcle) (I? 64 ~~ nexPEm -3- ~

~ t7'

~ , = ~ 'Q9 = P87C@Af 13y vQ1WJ7@ i?f L'Q2 Ir1 fNtB { ~ 8s sii88nJ

( 4 60 +Tm) 1 °.dOt = PefCent by voluMe af axygen fn tha gas straarn %CO+46111a = Penaent by svlums of CO ertd AfP In the gas

~ vs =
~ T "~ 7t1E00o

~ o Qd = Pancerrt of dry gss fiy valume t'n the ges sGream

f ~1~ 8,

~ , =°.6 bY valume af watartrarperirr ttis gas siream P= AI=satute sampls 9g,s grassure (Incfrs.s of l49) Cd = I L30-%a Pasr = t3alama#ric pressdsre (Inchas of Hg1 

### Md= 0.44(°IoGO

~



### ) + 0.32(%a02) + {1.28(%N2 + °loGd3) P g = Sampfe gas ststic prsssw+s (Inr,lies of¢1--3) 116 = Comremian factor(lnchas HzUlhrcles oFHg) lWs •° (Mct)(Gd/9 OONI 8)($3vdl 00) Op = Riw fttbe constent

_ 

### ~ g
)



### ~ s M } K a x 

### ~ dYl 

### ~ ressur

, s co

~ i' ralrant(d"rnansiunlsss) = 85. 4 9 (13.6) 80 = ccrsywwvn factcr(secwr# 

# L TS - 

### ~ 460) NJ, = NlolecrsJarwefghtofsomple ga% vyef (Ihllfrmole) P S = Absol

~ te samltle g$s presswe (hrch
~ of Hg}



### ~ s ~ ~~ P XO 

### PX 6 ~~~~

~ MS ~~ ps ~ T, 

### = AYSrsge ssmple gas teneperatura (°17 V. = Semple gss velocfiy(fbYsW) Qa =(As)(1/s) (acfn 1 ) A P = Avarege squsre mats of trelacliy heads of gas (in FIaO)

(Qa)(A ~ 'd l

~ SED = C o llTfBlsfOA ColJstBnf { ° c ti0 ° R~ °)(17.64r /j TOO ff

I Q A = Yalumetrlc Haw rat$ at ectual cwdffians (aofi») (ra + 460) A m = Crass sacflan$1 staa of snmptfng locstiorr (fi 2 ) lJ s = SamFia gas velaclfy (ftJtnin) K (T s + 460 )

( v ) Qda = VoL 13aiv re!'e ot stamierri ccndldcn.% dty (dscfm)

m (std ) I = 

### ~ c = O.1i89 ~0 w

~ aanstant 

### ~p s ~~ S4 ~ ~ ~ ~ ~ fl ( D$ 

### ~ D n = Avarage dismeter of noala (R 2 ) 4 100 B= TnfsJ sempllirg tlma (mfn)~'' ~v ~ , ~/ ;4. ' •;i:. t ' ~ 4.~ ~~ S i

w

.

. . ,



### .
. . ~ 

## A IA L.

. . . K

. .

•. ., • ,~ ~ , s, ,' ~~ ~ ; ; ~

,,, ~~ :_ t, :i ~~ , , ~ ~ • • ~ • s.:' , ~ 1 !i:i a E~rL~~ 1:E'L'•i ~

,~
-, , . . 

### , . . .. . . ._ . . . . . - s.._.__....... . ...

~ 

### ... _.... - --_. _ . .. :.... ._ _ ... .. ... .. .... _-..._ ------ - .._...... :rr

## Mstern gnvh.ronpntal SeMm and ToNno, Om

F4f .

~► 

### MI 

## a paftao colbralon a

r 

# VMM Leak

~ 

## °

° tc--- ~.~,~~ ax„~~~~ ~ ~ 05~ ~,_,~„~~1~~ ~~ 

### 19` •, ~'g~l~- 

### ~ 

## a



## woa

A

_ r f f~ `_#f': 7, j 1r `; f i d'

~ ;

~ j,]



## N EA Nr

~ '~~ eve FUO


## ~ • • • • •
.

# A PF EN, , D ...IX- C Com.pu 'ter Diat'a EntryAmerican Marazzi Tila Run Ceramlc Westem l:nvironmerital Sunn vale, Texas Main Stack 1,hethod 4 Meti,od: 4 Statllc Pressure: -0.221n. M20 Meter No: 24 For Mois4ure Barometric: 29.80 in. Ng M®tsr Correction Faator: 0.998 Area: 5.37 sq.ft. Slllca Gef: 9.3grams Sample Box Na APFX TimelPoint: 5.0 min. Condensate: 68.5grrams Pitot Tutse Cp: 0.842 Sample Tirne: 36.0 min. Tota! UIlt. 77.8grams Probe Tip Diameter Filtar No: DatslStaft Tirn$ 4114105 10:00 DatelStop i"ime 4!1 4105 10:35:00 °k CO2 3.2 Pretest Leak Rate 0.000 cfm @ 15 in.Ng Posttest Leak Rate 0.000 cfm aQ 15 in.t-#g °!0 02 14.2

Clack Dry Gas Pltot Actua! Stask Gas Meter TemA. 

### ya. psr adhl Time Meter in. 24 

### ©H 

## imp. {r et Outiet PQint A'12 10:00:00 412.453 0.16 1.60 420 87 87 3.80 11 10:05:00 416.250 0.18 1.50 426 89 89 4.76 10 10:1 0:00 421.010 0.19 1.50 428 89 89 4.23 9 10:16:00 425.240 0.19 1.50 426 9i} 90 2.51 8 10:20:00 427.750 0.18 1.50 428 

### so 90 4.00 7 10:25:00 431.750 0.17 1.60 430 90 90 3.40 6 10:30:00 435.150 0.14 1.50 433 90 90 4.12 5 10:36:00 439.271 0.15 433 4 0.1& 430 3 0.15 428 2 0.15 424 1 0.13 418
B 12 017 425 11 0.18 424 10 0.18 422 9 0.19 422 8 0.18 424 7 0.17 425 6 0.14 425 5 0.11 425 4 0.15 425 3 0.15 425

. 2 0.16 426 1 0.15 424 End
1.500 426 89 26.818American Marazzi Tila Run 1 Porcelain HVestarn Bnvironmarial Sunnyvala, Texas Main Stack Method 4 Method: 4 Static Pressure: -0.22 [n. H20 Meter Na: 24 For Pariiculata Earcrmetric: 29.80 #n. -Hg Meter Correction Factor: 0.996 Area: 5.37 sq.tt. Siiica Gal: 7.3grams Sampfa Box Pto: APEX Time/Polnt: 6.0 min. Condensate: 64.9grams Pitot Tuba Cp: 0.842 Sample Time: 35.0 min. Totaf Wt. 72.2grams Probe Tip Diametcar Filter No: Date/Start Tlme 4/14/0512:15 Da#pJStop T'm 4/1410512:50 , 00 % CO2 3.0 Pretest Leak Rate 0.000 cfm @ 151n.Hg Posttest Leak Rate 0.000 cfm @ 15 in.Hg °10 {72 14.4

G'iack Dty Gaa Pitot Actuaf Stack Gas MsLK Tama. 1 , ~ ,a w E!

~ MA r

~ Metar in. H20 &H ci. {ntat OM EW A 12 12:16:00 439.608 0.16 1.50 429 90 90 3.79 11 12:20:00 443.400 0.17 1.50 429 91 91 3.50 10 12:25:00 446.900 0.19 1.50 433 91 91 3.80 9 12:30:00 450.700 0.19 1.50 435 91 91 3.60 8 12:35:00 454.300 0.18 1.50 439 92 92 3.52 7 12:40:00 457.820 0.14 1.50 442 93 93 3.48 6 12:45:00 461.300 0.16 1.50 444 94 94 3.66 v 12:50:00 484.969 0.17 445 4 0.15 444 3 0.13 436 2 0.12 428 1 0.11 422

B 12 0.18 426 11 0.19 428 10 0.19 430 9 0.19 434 8 0.18 437 7 0.14 43$ 6 0.17 440 5 0.17 441 4 0.14 441 3 0.12 438 2 0.13 435 1 0.12 429 Bnd
1.500 435 92 25.353Arnerican Marazzi THe Run 2Porcelain Westem Cnviror+menia! Sunnyvafe, Texas Main Stack Meti:oai 4 Method: 4 Stattc Pressure: -0.22 in. H20 Metsr No: 24 For Particulate Barometric: 29.80 in. Hg Meter CorrBction Factor: 0.995 Area: 5.37 sq.ft. Sifica Ge1: 3.3grams Sampig Box No: APEX TlmelPoint: 5.0 min. Condensate: 32.4grams Pi#ot Tube Cp: 0.842 Sampie T'ur+e: 35.0 min. Totai Wt. 35.7grams Probe Tip Diameter Fiiter No: DatelStart Time 4l14/0513:35 DatelStop Ttme 411510514:10:00 °10 CO2 3.2 Pretest 1.sak Rate 0.000 cfm aQ 18 in.Hg Posttest l.eak Rate 0.000 cfm @ 15 in.Hg % 42 14.4

Ciock Dry Gas Pitot Actual Stack Gas iaf(eter Temp. Vol, oes aini Time Mgie_r in. O Aj Tettip. 

# mm 99t at Point A 12 13:35:00 485.175 0.23 1.50 410 95 95 3.83 1'E 13:40:00 468.800 0.24 1.50 420 95 98 3.62 10 13:45:00 472.420 0.24 1.50 422 95 95 3.62 9 13:60:00 476.040 0.24 'i.SO 425 95 95 3.51 8 1 3:55:00 479.550 0.23 1.50 428 96 98 3.62 7 14:00:00 483.170 0.12 1.50 432 96 88 4.13 6 14:05:00 ' 487.300 0.19 1.50 435 97 97 3.03 5 14:10:00 490.333 0.20 438 4 0.17 435 3 0.16 431 2 0.13 410 1 0.12 395

B 12 0.21 420 11 0.22 421 10 0.22 423 9 0.29 426 8 0.20 430 7 0.13 434 5 0.18 437 5 0.18 438 4 0.18 438 3 0.17 437 2 0.15 414 1 0.15 411 End

1.600 425 96 25.158;4mericaii Marazzi Tile Run 3Porcelain VllGstem Environmental Sunn als, Texas Main S#as

~ c Method 4 Method: 4 Static PreSsure: -0.22 In. H20 Meter Ho: 24 For Particulat® Barametric: 29.80 in. Hg Meter Carrectian Pactor: 0.996 Area: 5.37 sqft Silir.a Gaf: 7.4grams Sampi$ Box Na: APEX TirneiPoint: 5.0 min. Condensate: 53.2grams Pitot Tuba Cp: 0.842 Sample Time: 35.0 min. Total Wt. 60.6grams Proba Tip Djarneter Fliter No: DatelStart The 4J14/0514:40 f)ate/Stop 7ime 4115105 15:15:00 °:o CO2 3.2 Prete.st Leak Rate 0.000 afm @ 15 in.Hg Posttest Lea4c Ra#e 0.000 cfm Q 151n.l+ig % 02 14.2

Cbek ary Gas Pitot Actaa! Stack Gas fi

~ stc

~ r Tema. i. ar Pain T'fne Meter (In U20) AH-_ Tema. Inlet Qutlat ain A 12 14:40:00 490.600 0.22 1.50 423 96 98 3.85 11 14:45:00 494.450 0.23 1.50 427 97 97 3.31 10 14:50:00 497.760 0.24 1.50 430 98 98 3.66 9 14:55:00 501.420 0.24 1.50 435 98 98 3.49 8 15:00:00 504.910 0.23 1.50 438 98 98 3.41 7 15:05:00 608.320 0.12 1.60 438 99 99 3.52 6 1 5:10:00 511.840 0.17 1.50 437 99 99 3.49 5 15:15:00 515.327 0.20 438 4 0.16 435 3 0.14 431 2 0.13 424 1 0.12 419

B 12 0.20 428 11 0.21 431 10 0.21 435 9 0.20 437 8 0.20 437 7 0.14 436 6 0.17 438 5 0.18 435 4 0.17 435 3 0.16 429 2 0.14 421 11 0.13 417 End
1.500 431 98 24.727` . . ~~~ ~ ~ .S'LI ;~ s ~~ 1 ~~ • - ~ , .

. ,
.. ~~ . '

. ~
. ~
. t~~~k~~r~~~~~~~_~~~s~~ . ~ .

### Ceramic Main Stack

TamEstamp HCL MF 419412005 1.0:'! 't 

### 9.946 30.542 4/1412005 10: 16 8.911 2+E.294 411 412005 1 0:2 7 8.643 26.208 4114f200510:26 8.520 25.504 411412005 1 0:32 9.093 26.230 4!1 412005 9 0:37 '1 0.270 29.244 4!14/2005 1 0:42 '10.203 29_293 411 412005 1 0:47 11.133 31.087 4114J2005 1 0: 52 11. 51 0 31.377 411412005 1 0:57 1 0.550 29.461 4/1 4I2005 1 1 :'14 11 .060 20.684 .1Avera9es T/sWIS I'7d81 IRasn 1 Poeceiaen Meaav Stack

rosasstamp HCL MF 4/14/200512:18 25.079 54.957 4114/200512:23 25.290 58.040 4/14l200512:28 24.621 57.369 4/14/200512:33 24.586 56.974 4/14/200512:38 27.163 62.470 4/14/2005 12:43 25.766 59.035 4/14/200512:43 33.887 67.940 4/14/200512:54 31.951 66.468 4194/200512:59 27.705 62.952 4/1 412005 13:04 27.456 63.476 4114/200513:09 30.600 67.648 .4/141200513:14 35.894 72.196 Average 28.333 62,452
Run 2 P®rceiain 3imestramp HCL HF 4/141200513:29 18.20758 37.73916 4/141200513:34 11.5062 35.38136 4114/2005 13:39 16.36104 46.52527 41141200513:44 13.20118 48.66049 41141200513:49 20.30849 47.15999 4/14/2005 '! 3:54 25.73835 56.35747 41141200513:59 25.16755 55.32917 4/14/200514:04 26.31197 55.89006 4/14/2005 14:09 26.73735 56.80736 4/141200514:14 28.86682 59.42829 4/14/200514:20 27.18558 58.65652 41141200514:25 31.47818 65.23201 4/14/200514:30 48.05984 85.5748 4/14/200514:35 32.58806 58.3003 Aveirage 28.91704 57.82681
Run 3 Porceiaeea 'i'imeStamp B-iCL HF 4/14/200514:40 23.91718 50.18526 4/141200514:45 23.80354 54.12422 4/14/200514:50 24.70584 57.97817 411412005 14:56 26.'i 8465 60.54983 4/141200515:00 30.72614 65.77795 4/141200515:05 27.35456 60.3729 4/141200515:10 27.87803 60.06103 4114/200515:15 29.6814 60.84264 4/141200515:20 29.83673 59.48223 419 4/2005 1 5:25 27.43583 55.361 411 412005 15:31 31.86564 59.64195 411412005 15: 36 31.1 C862 61. 92034 A► 

### verage 27.97984 58.86813

### Llne Lcss Evegul-asgon 

### Client AMT t.ocaftn: 

### Synnyvaie. xas Soume: 

### K31n 9 

## Ugin S#sck 

### $ivilCe Gas: Hydrogen Chloride

iDate: 4'i-4/2Q05 Vi'ime Start: 1 , i:24:00 Acro8ein Spike I tpike 2 Spike 3 Time iD 11:51 Time ID 11:55 Time iD 'i 1:59 SF6 Direct 4.60 SF6 Direct 4.60 SF6 Direct 4.60 SF6 Measured 0.61 SFQ 

### iUleasured 0.41 SF6 I#lleasured 0.62 DifuSon Factor 7.54 Dituffon Factor 11.22 Dilufion Factor 7.42 HCI Baseline 9.98 HCi Baseiine 9.98 HCI Baseiine 9.98 HCI Cyi 201.40 HCI Cyl 201.40 HCI Cyi 201.40 HCI 

### Measured 37.20 HCI Nleasured 30.13 i-iCl Alteasured 34.90 HCI Predicted 38.69 HCI Predicted 27.93 HCI Predicted 37.13 HCi Over 

### 47.69 hiC! Qver 36.31 HCI flver 48.26 HCI Under 25.68 HCI Under 19.55 MCI Under 25.99 %Recovery 98.62 92.70 106.38 Avg. Recovery 99.23Coyffind®r EvaBuadon

# pathlangth 1 8.95 # raethod(s) L:1I%AcMACME3.mefhcsd TimeEtamp SF6 HCL 04.92.05 1D:51:14 4.59228 198.333 04.12.05 9tt:53:14 4.6086 203.468 Avg 4.60044 201.4E105

### Un@ L®ss EvaluaUon

Gas: Hydrogen Chloride 

### Yimes4amp SFG MCL 4114/20051 1:5'I 0.509555 37.15035 4/1412005 11:53 0.373187 33.05359 

### 411 4f2Q05 1 9:55 t3.4'! 5449 30. 12529 411 412005 91:57 0.54't491 33.01 028 .4114/2005 1 1:59 0.61952 34.88f43 4/14/2005 9 2:0 1 0.61 3829 38.1741

### 5,21 0.52 10.02 45.00
113.57 54.74 66.34 73.24 39.43 Pass spike 3

SF6 Direct 5.21 SF6 Nleasured 0.52 Dilution Facfor 10.02 HC! Baseline 45.00 1'RRCi Cyl 113.57 HCl Measured 49.17 HC) Predicted 56.34 HCI Qver 73.24 NC! Under 39.43

Pass spike 2 SF6 d3irect SF6 Measured Ditution Factor HC{ Caseline HCl Cyl HCI Measured #-iCl Predicted HCI Over HCl Under Date 10127303


### spike'i SFG DEreci; 5.21 SF6 Measured 0.52 Diiuflon Factor 10.02 HCI Basefine 45.00 1•1Ci Cyl 113.57 HC1 Measured 50.45 HCi Predicifed 56.34 HCl 4ver 73.24 l:-iCl Under 39.43

PassDate 10I2812003

spike1 spike 2 spike 3 SF6 Direct 5.21 SF6 Direct 5.21 S176 Direcf 5.21 SF6 Measured 0.49 S176 Measured 0.49 SF6 Measured 0.49 Diiution Factor 10.63265 Di#ution Factor 10.6326531 Dilution Factor 10.83265 (-tC! Basetine 5.595 i-ICI Basetine 5.815 HCl Baseline 5.71 HCI Cy1 113.57 HCI Cyl 113.57 HC1 Cyl 113.57 HCI Measured 1 18.2 HCI Measured 18.92 HCI Measured 19.3 HCI Predscted 16.27625 HC1 Predicted 16.4962476 HCI Predicted 16.39125 HCi Over 21.15912 HCi Over 21.4451219 HCI Over 21.30862 HCt Under 11.39337 HCI Under 11.5473733 HCI Under 11.47387 Pass Pass Pass

### aci dl ow

i 

### macc Quant met hod :

- --- ~ 

### fi 1 ename = C:\l\Aci d\Aci dl ow . method Shift znformation: 

### sh i ft-reference = C:\IMACC\ACME\3 . 8%H2O. spa start = 3158 stap = 3270 

### ;naxdel a = 5 3nterpoTate-count = 5 

### shi ft-count = 5 Quant informati on : di gi t--tol erance = 3 data-s

- rze-tolerance = 5 use-dynamic-references = true use-bias = true 

### use- radi ance = •Fa7 se report-zero = fal se 

### References : ~ set-fi 1 Qna.me ;

Co, c:\zmACc\method\CO-150.s 

### p a CO2, C:\YMACC\Method\CO2-8 % -68m.SPA N2CO 3 Co\IMACC 

### ~ AC 

### ~ IE\H2C0-50.spa 

### H2O , C:\I\ACI 

### d\ H20-20k-0.9icm-1.SPA F~ 

### CL, c:\I\meed 

### ful Thi ngs\R.EF185\SERIES\HCL 

### _500ppb. spa HF, C: 

### \1\Needful Thin s\REF185\SERIES\HF1.5ppm.spa 

### MH3 , C:\IMACC\vtethoP g 

### NH3_185 .185 SF6 1 C:\ I MACCy

~ tethod\s 6_76.185 

### S02, C:\ImACC\ACME\502_896.185 code sh 

## ortname pres(Torr) temp(C) conc(ppm) pathlength(rn)



### ____ ~~-~~•~•~-~ ~. ~. -~~~~~~ 

### _

---- ~_

--~~~ -~ ---- ~•-~~:.~..~~ 10

~ Co c0-150 760 185 150 CO2 CO2-69o-68m 755 185 60000 68.5 H2C0 H2C0-50 760 185 50 10 H20 H2O-20k-0.94cm-1 700 185 20000 9 

### NCL HCL...500ppb 650 185 0.5 25.5 HF HF1.5ppm 650 185 1.5 25.1 NH3 NH3_185 650 185 54.3 3.4 SF6 sf6_76 755 185 20 3.8 

### So2 S02_..896 765 185 SS 10.5 Regions: start stop seport interference


### _--________ ---•-

~~~ 

### -.

•-r 86 6. 2- -=.

~~~~~~~~=~~~~~~~~~~ 

### ..;.

993.7 NH3 - CO2 , H2O, S F6 

### 923 . 6-- 1097.9 CO2 - H20, NH3, SF6, S02 930 -- 952.8 SF6 - CO2 1 H2O 9 NH3 

### 2092.2 - 2210.8 co - CO2 1 H2O 2092.4 - 2201.8 H2CO - CO2,H2O 2462.2 - 2528.6 S02 - Co2,H2O 2673.2 - 2848.2 HCL - H20 3172.7 - 3331.5 m2o -, 3999.6 - 4285.1 HF - H20 Region ( 866.2 - 993.7 ): 

### wa ndows ; Page 1acidiow 866.2 - 869.5 923,3 - 936.2 961.3 - 969.5 990.9 - 993.7 report-compounds = WH3 

### i nterference-compounds = CO2, H20, SFF Li neari ty ; name = NH3 

### flrder = 2 f os^ce-zero = true 

### mi ni mi ze-percent-error = fai se dynamic-reference = true 

### use-dyanami c = fal se use-7 i neari ty = fa 1 se use-shi ft = fal se coefficents = 0.845185 9 0.0001.85922 

### setname = NH3 tteferences: 

### set-fi 1 ena:ne = C: \gMACC\Method\nh3 . set MH3, C:\IMACC\Method\NH3OlOa2a.SPA

, C:\IMACC\Method\NH3O1Oa2.sPA , C:\ ?MACC\Method\NH3020a2a.SPA , C:\YMACC\Method\NH3020a2pSPA 

### , C: \iNtACC\method\HH3000a2 . SPA , C: \ I

~ 

### CC\ M



### ethod \ 

### HH3430a2 o SPA f~D~ 

### 3 , C:\IMACC\Method\NH3O4Oa2.spA , C : \ImACC\Method\MH3050a2 . SPA code shortname pres(Torr) temp(C) conc(ppm) path7ength(m) WH3 NH3010a2a 761 185 11 26



### MH3010a2 761 185 11 26 NH3020a2a 761 185 22 26 MH3020a2 761 185 22 26 MH3000a2 762 185 33 26 NH3030a2 762 185 33 26 NH3 NH3040a2 762 185 55 26



### NH3050a2 762 185 110 26 Regi on { 923.6 - 1097.9 ) : wi ndows ; 923.6 - 1097.9 report-compounds = CO2 

### i nte rference-compounds = H20, A9W3 

### , SF6, S02 Li neari ty: name = CO2 order = 2 force-zero = true 

### m
- inimize-percent-error = faise dynamic-reference = true 

### use-dyanami c = fal se use-1 i neari ty = fal se use-shi ft = fal se coeffi cents = 0, 529252 ,1. 23.205e-007 

### setname = CO2 References : set-filename = C:\zMACC\Method\coZlow.set CO2, Cp\IMACC\Method\CU2-IO.spa Page 2

### aci dl ow CO2, c:\aMACC\method\CO2-20.spa CO2 1 C:\IMACC\Method\CO2-SO.spa 

### Co2, C :\IMACC\Method\CO2

- 100.spa CO2, C:\YMACC\Method\CO2-150.spa 

### CO2, C: \IMACC\Niethod\CO2-200. spa CO2, C:\Z

~ G4CC\Method 

### \ CO2

- 300.spa 

### CO2, C:\1twACC\Method\co2-500.spa 

### CQ2 , c:\imAcc\method\cO2_1k.sPa cade shortname pres(zorr) temp(C) conc(ppm) pathlengt+h(m) 10 10
~-^ CO2 CO2-10 760 185 CO2 CO2 - 20 760 18 5 20 10 CO2 CO2-50 760 185 50 10 CO2 CO2-100 760 185 100 10 CO2 CO2-150 760 185 150 10 CO2 CO2-200 760 18s 200 10 CO2 CO2-300 760 i8S 300 10 CO2 co2-500 760 185 S40 10 CO2 CO2_1k 760 185 1000 10 Region ( 930 - 952.8 ): 

### wi ndows ; 930 - 952.8 report-compounds = SF6 

### # nterferenEe-compounds = CO2 , H2o, Nw3 Li neari ty : name a S F6 order = 0 force-zero = true 

### mi ni mi ze-percent-error a fal se dynami+c-reference = false use-dxahamic = false 

### use-1 inear it y
~ 

### fal se use-shi ft = Fal se coeffi cents = setname = SF6 References: 

### set-fi l ename = Region ( 2092 bti ndows ; 2092.25 2118.11 2143.43 2164.77 2188.97 .25 - 2210.8 ) :

- 2112.81 - 2133.39 - 2159.99 - 2184.42 - 2210.8 report-compounds 3 Co i nterference-compounds = CO2, H20 

### Li neari ty: name = CO order = 5 force-zero = true 

### m i n 

### i m 

### ize-percent-er ror = t rue dynami c-reference = true use--dXanami c = fal se use-1 i neari ty = fal se 

### Page 3

### aci dl ow

use-shi ft - fa7 se coefficents = 0.55085,0.000130645,1.53981e-007,-2.92281e-011,2.07788e-03.5 

### setname = Co 

### References : sst-f

- i i ename = Co, C:\IMACe\Method\CO-5.spa Co, c:\IMACC\Method\c0-850.spa co, C:\IMACC\Method\co-750.spA Co, C:\2MACC\Method\Co-650.spa Co, C:\ ?MACC\Method\CO-600.spa Co, C:\iMACC\Method\Co-500.spa 

### CO , C : \Ii4ACC\Method\CO- 

### 50 , spa CO 3 C:\iMACC\Method\CC1-9SO.spa Co, C:\IMACC\Method\CO-1.spa CO 3 C:\2MACC\Method\CO-40.spa CO 3 C:\iMACC\Method\Co-300.spa 

### CO 3 C:\I ;

~ 

### IACC\P

~



### 9ethod\CO-30. spa C0 9 C : \aMACC\Method\CO-200 . spa Co, C:\IMACE\Method\Co-20.spa Co, C:\IMACC\Method\CO-3.SOO.spa Cc3, C:\IMACC\Method\CO-150.spa Co, C:\3MACC\Method\co-100.spa 

### co, cevMACC\Method\co-10.spa CO 3 C:\3MACC\Method\CO-400.spa code shortname pres(Tora^) temp(C) conc(ppm) path3ength(m) Co CO-5 760 185 5 Zo Co c0-850 760 185 850 10 Co Co-750 760 185 750 10 co C©-650 760 185 650 10 Co Ca-600 760 185 600 10 CO Co-S00 760 185 500 10 Co CO-50 760 185 50 10 co CO-950 760 185 950 10 Co co-1 760 185 1 10 Go CO-40 760 185 40 10 co Co-300 760 185 300 10 Co CO-30 760 185 30 10 co CO-200 760 185 200 10 Co CO-20 760 185 .20 10 Co CO-1500 760 185 1500 10 c0 CO-150 760 185 150 10 CO co-100 760 185 100 10 co co-10 760 185 10 10 CO CO-400 760 i85 400 10 Regi on ( 2092.36 - 2201. 78 ): vgindaws; 2092.36 - 2112.99 2118.14 - 2134.06 2167.92 - 2201.78 report-compounds = H2C0 

### i nterference-compounds = CO2 , H2Q L i neari ty : name = H2Co order = 4 

### force-zero = faise 

### mi ni m

- t ze-percent-e r ror = fal se dynamic-reference s fa7se Page 4

### aci di ow

use-dy anam

- ~ 

### c= fal se use-1 

### ,

~ 

### nearz t y 

### = fal se use-shi ft = fial se coef¢i cents = 0, 0, 0, 0, 0 setname = H2C0 

### References: set-fi 1 ename =
tZegi on ( 2462.15 - 2528.55 a ttd7 

### Yldows ; . 2462.15 " 2528.55 

### repart-compounds = S02 interference-compounds = CO2,H2O Li neari ty: name S02 

### order = 4 force-zero = false 

### mi ni m

- i ze-percent-error = fal se dynami c- reference = fal se use-dyanamic = faise 

### use-1 i neari ty fal se use-shi ft
~ 

### fal se coeffi cents = 0, 0, 0, 0, 0 setname = S02 References : set-fi 1 ename = Regi on ( 2673.15 - 2848.18 ) ; windows; 2673.15 - 2848.18 report-compounds = HCL interference-Compounds = H20 Linearity: 

### name = HCL 

### order = 3 force-zero = true 

### minimize-percent-error = true dynamic-reference = true 

### use-dxanasrri c = fal se use-1 i neRr

- 1 ty = fai se use-shi ft m fal se 

### coefficents = 1.03621 9 0.000234244,8.21206e-007 setname = HCL References: set-filename = C:\IMa CC\Method\hcllow.set HCL, C:\1\Needful Things\REF185\SERIES\HCL-50ppb_185C.spc 

### tiCL, C:\1\Needful Things\REF185\SERIES\HCl 

### _100ppb 

# .sa HCL, C:\1\Needfui Things\REF 1 

### 85\SERIES\HCL_.200ppb 

# _1 5C.spc HCL, C:\l\Needful Thi ngs\REF185\SERIES\HG.....500ppb_185C. spc HCL, C:\1\Needful Things\REF185\SERIES\HC1.-750ppb.spa HCL, Cp\1\Needful

~ 'hings\REF

~ ,85\SERZES\HCL_1250ppb_185C.spc 

### HCL, C: \1\Needfu7 Thi ngs\REF185\SERZES\HCl 3.ppm. s p 

### a HCL, C:\1\Needful Things\REF185\SERIES\HCL.1p 

### p m_185C.spc 

### HCL, C:\1\l

~ 

### eedful Things\REF18S\SERIES\hcl-.6.5_20m.185 HCL, C:\1\Needful Things\REF185\SERIES\HC1 Sppm.spa 

### HCL, C:\1\Needful Things\REF185\SERIES\HC1 10ppm.spa HCL, C:\1\Needful Things\REF185\SERIES\HC1 25ppm.spa 

## Page 5

### aci dl ow code 

### sh ortname 

### p res 

### (Torr) temp(C) 

### co mt(pprn) path'I ength 

### (m) HCL HCL_54 

### p pb_185C 650 185 0.05 25.5 HCL HCi _,3.00ppb 650 185 0.1 25.5 HCL HCL_200ppb_185C 650 185 0.2 25.5 HCL 'HCL_500 

### p pb_185C 650 185 0.5 25.5 HCL HCi_750p 

### p b 650 25.5 0.75 25.5 HCL HCL_1250p 

### p b_185C 650 1.85 1.25 25.5 32 l

- ~ CL HCl

~ .p 

### p m

s 7 6 0 185 1. 7 

### HCL ,~ 

### Ct.-.2pp

~ 

### t..l85C 650 185 2 

## 7 5.5 HC L hc

~ t_6.5-.20m 6 89 185 6.5 _0.9 ;tCL kiCl Sppm 760 385 5 32 I

- iCL HCI lOppm 760 185 10 32 

### HCL HCi 25ppm 760 185 25 32 Zegion ( 3172.7 - 3331.5 ) : 

### wi ndo6Vs ; 3172.7 - 3331.5 report-compounds = H20 

### znterference-compounds = Linearity: 

### name = H20 order 3 

### farce-zero = true m

- inimize-percent-error = true 

### dynamic-reference = true 

### use-d y 

### anami c fal se use-1 i neari ty = fal se use-shift = false coefficents = 0.97062 y 1.S629e-006,-6.23876e-013 

### setname = H20 t4efe rences : 

### set-fi3ename = C:\ztwACC\twethod\h20.set H2O, C:\1\Acid\H2O-20k-0.94cm-3..5PA 

### H2O, C: \1\Aci d\H2O-40k-0. 94cm

- 1. SPA 

### H2O, C:\1\AcId\H20-60k-.94cm-I.SPA H2o, C: \3\Aci d\H2o-90k- .94cm-1. SPA H2O, c:\1\Acid\H20-11Ok-0.94cm-1.SPA H20, C:\1\ACid\H20-125k-0.94cm-1 .SPA code shortname pres(Torr) temp(C) conc(ppm) pathlength 

### (m ) H20 H20-20k-0.94cm-1 700 185 20000 9 H20 H2O-40k-0.94cm-1 700 185 44000 9 H20 H2O-60k-.94cm-1 700 185 60000 9 H20 H2O-90k-.94cm-1 700 18S 90000 9 H20 H2O-110Gc-0.94cm-3. 700 1$5 1.1e+005 H20 H2O-125k-0.94cm-1 700 185 1.25e+005 Regi on ( 3999.64 

### wi ndows ; 4037.69 - 4072.18 - 4108.56 - 4173.49 - 4201.68 - 4228.58 - 4254.23 - - 4285.13 ):



### 4040.98 4077.82 4111.29 4175.17 4205.65 4232.72 4258.37 

### Page 6

### aci dl ow

repart--compounds = HF i nterference-compounds = H2o Li neari ty: 

### narne = HF order = 3 forc4--zero = true 

### m
- i ni mi ze--percent-error = fai se dynami c-reference = true use-dyanam-i c = fal se use-7 i neari ty = fal se use-shift = false coefficents = ©.900098,0.00236984, 7, 53245e-4306 

### setname = HF References c set-fiienarne = o:\IMACC\Method\HF.set 

### NF 4 C:\1\Needful Things\REf185\SEtt 

### I ES\HF100p b.spa 

### HF, C: \I\Needful Things\REF185\sERIES\HFSO p 

# ~ .spa 

### HF, 

### C:\I\Needful Thi ngs\REF185\SERYES\HFI.. 

# ~ ppm. spa code shortname pres(Torr) temp(f) conc(ppm) path7ength(rn) HF HF100ppb 650 185 0.1 25.1 HF HF50ppb 650 185 0.05 25.1 HF HF1.5ppm 650 185 1.5 25.1


### Bi as :

r= 

## _`^"

~
... ~.~



### Page 7aci d



### Imac c Q 

### uan t me 

### thod t fi'3 ertame = C:\1\Acid\Acid.method Shi ft Informati on : shi ft-reference C:\I\old omn! c\H2o_5C3k. spa start 3158 stop 3270 

### maxdel a

- ~ 

### = 5 nte

~ ^po

~ ate-count = S 

### shi ft-count = 5 Q 

### ua nt Informati on R da gi t-tol e rance = 3 

### data-size-toierance = 5 use--dynamzc-referen+ces true 

### use-bi as = t.rue use-radi ance = fal se report-zero - fal 5e References:

~.~_ -....w.... 

### set-f i l enam,e

~ Co, C: \IMACC\Method\CU-3.5[1. s a 

### c 

### o 2 

### , C. ~,S~t~4Ce 

### \ 

### MethodlCoa-6 %

- 

### 6

~ 

### itl. SP'A 

### H2eo, e:\i\Ethanol ScraabberlH2CO_std--4--10m.spa "2cD, c:\l\old omn1 c\H2o_SUHc. spa HCL, C:\1\Spectra\REF185\NCL_136.185 

### HF, C.\I\Spectra\Misc\oMNIC\HF--so-o.94cm-I.SPA 

### NN3 , C:\1\spectva\REF185\NH3_185.185 sF6, C:\1\Spectra\REF185\SF6_76.185 

### So2 , C°. \l\Spectra\REF38S\SO2_896. 18a cod e 

### shortname p res( 

### Torr) temp(C) conc (pp 

### m) pathlength(m)


### co c

p o

~ / -3 , ~ + . . 5o 760 185

~ .r 1 5 0

~ . ~ 

### -

~ .0 .r

~ /2 

### C ©2-'` ✓ /V-V 

### 8m 75 5

~ .SJ V0oQ4 6$.5 H2CO H2co_std--4--10m 754 l8s 4.2 10.1 M20 Qo w 50k 760 18 S 50000 10 HCL HCL

~ ..136 689 i85 6.5 20.9 HF HF-10-0 a 94cm-1 700 i8,5 10 9 iNJH3 wH3-185 650 185 54.3 3.4 SF6 SF6_76 755 185 20 398 S02 S02_896 765 185 85 10.5 

### Regi ans o

_~-

---- ~~ 

### start stop 

### report interference

866.2 - __w~~ w __M

~ wY_rrwrw ►r~ rw+wY ~ti 

### 993.7 Y-~~ riCS i 

### NH3 ~~

i~w«w~Y.~~

Y
~~

i~~ 

### " Co2 4 H20, SF6 923.6 - ~ ,i397. 9 

### c o2 - 

### m 2o, 

### mH 3 p SF6, S02 

### 930 -- 952.8 SF6 - Co2,H2o,Nii3 2Q92.2 - 223.0.8 co - ~ 

### o2, H 20 2092. 

### 4 !' '"' ~ 'q

G2o1. 8 H2.aV - L02 g H20 246 

### 2.2 - 2528.6 

### S o2 - 

### C O2 9 0~~20 26 7 3.2 3 - 2848.2 H4L - f'b20 3172 .7 - 3331.5 H20 -- 4067.3 -- 4285.1 HF - H20 Ptegi on ( 866.2 - 993.7 ~ n {rii ndows ; 

### Page I

### aci d 866.2 -- 869.5 923.3 - 936.2 961.3 - 969.5 990.9 - 993.7 report-compounds = NH3 i nterference-compounda = CO2, H2O, 5F6 L

- a 

### neari ty a narne = MH3 order = 2 force-zero = true 

### m
- i ni m

- i ze-percent-error = fa3 se dynamic-reference = true use-dyanami c = i=a1 se use-7 i near

- i ty = fal se use-shi ft = fal se caei"fi cents = 0. 839627, 0. 0at1183653 setname = MH3 

### References: set-fi 1 ersaine = Co\ImqCC\ ethod\nh3 . set W , C:\IMACC\Method\mH3O1Oa2a.SPA , C: \IMACC\iyte t 

### hod\mH3t310a2 . SPA , C: \IMACC\Method\NW3020a2a. SPA , C: \IMACC\Method\NH302aa2 . SPA , C: \IMACC\Method\NH3000a2 a 5PA , C.\xmACC\method\Nm3030a2.sPA , C:\IMACC\Method\NH3040a2.5PA

, c:\iMAcc\method\mH3O5Oa2.SPA code shortname pres(Torr) temp(C) conc(ppm) pathlength(m) 

### MH3 HH3010a2a 761 185 11 26



### N"3010a2 761 i8s 11 26 

### NH3020a2a 761 185 .22 26 NH3020a2 761 185 22 26 MO000a2 762 185 33 26 NH3030a2 762 i8S 33 26 NH3040a2 762 185 55 26 NH3050a2 762 iSS 110 26 Region ( 923.6 - 1097.9 tvi ndows ; 923.6 - 1097.9 report-compounds =. CO2 i nterference-compounds = 

### H20, NH3, SF6, 502 L

- i neari ty: name = CO2 order 2 force-zer°o = traae mi ni mi ze-percent-error =fal se dynamic-reference = true use-dyanamic = false use-1 i neari ty = fal se use--shi ft = fal se coeffi cents - 

### setttame = CO2 

### References : 

### set-fi l ename w 

### Cp 

### \gmAcC\metho+dl,co2low. set CO2 p = o \IMACC\Method\CO2-I0 . spa 

### Fage 2aci d t02 9 C:\1MACC\Method\CO2-20.spa 

### CO2 , C:\1MAtC\method\CO2-50.spa CO2, C:\xNlACC\Method\CO2-100.spa CO2, C:\1MACC\Method\CO2-150.spa CO2, C:\IMACC\Method\CO2-200.spa Co2, C:\1MACC1Meth0d\Co2-30O.spa CO2, C:\1MACC\Nlethed\co2-500.spa 

### CO2, C:\1MACC\Method\e02_1kAspa 

### code shortname pres(Torr) temp(C) conc(ppm) pathlength(m) c02 r.02-10 760 185 10 10 CO2 CO2- 20 760 185 20 10 c02 CO2-50 760 185 50 10 Co2 CO2-100 760 185 100 10 Caz CO2-150 760 l85 ISO 10 CO2 CO2-200 760 185 200 10 CO2 CO2- 3(30 760 185 300 10 CO2 c02--50O 760 185 500 10 CO2 CO2_1k 760 185 1000 10 Region ( 930 - 952.3 ): 

### idi ndows ; 930 - 952.8 

### repvrt-compounds = SF6 i nterference-campounds = CO2, H20, NH3 L3 neari ty : name = 5F6 

## order = 0 force-zero M true 

### m i ni mi ze-percent-error = fal se dynamic-reference = fa7se 

### use-dyanami c = fal se use-i v neari ty = fal se use-shift = false coeffi cents = 

### setname = SF6 References: set-filename = Region ( 2092 

### wi ndows ; 2092 Q .2 5 211

~ 7 .11 2143.43 

### 2164.77 2188.97 .25 - 2210.8 ) :

- 2112.81 - 2133.39 - 2159.99 - 2184.42 - 2210.8 report-compounds = co interferente-compounds = CO2,H20 

### Li neari ty: name CO order = 5 force-zero = true 

### minimize-percent-error = true dynamic--reference = true use-dyanami c = fal se use-1 i nearity fal se Page 3

### aci d

use-shift = false coeffi cents = setname = CO References: 

### set-fi 1 ename = c0, C4\IMACC\Method\Co-5.spa Ca, Co\IMACC\Method\CO-850.spa co, C:\iMACC\Method\co

- 750.spA 

### co, C: \IMACC\Met od\CO

- 650.spa 

### c®, ca\IMACC\Method\CO-600.spa cLl, C:\IMACC\Method\Co-500. spa c.o, c:\imACC\Method\c4-50.spa 

### co, C:\

~ 

### rMACC\Method\Ca-950.spa CO, C:\IMACC\Method\CO-1.spa Co, C:\IMACC\Nethod\CO-40.spa Ca, Ce\IMACC\Method\CO-300.spa 

### CO, . C.\IMACC\Method\CO-30. spa ca, co\xmACC\Method\CO-200.spa co, C:\iMAcc\Method\CO-20.spa c0, C:\IMAEC\Method\CO-1S00.spa CO 3 C:\IMACC\Method\CO-150.spa CO, C:\IMACC\Method\co-3.00.spa 

### co, C:\xMAc [\method\Co-IO.spa Ctf, C:\IMACC\Method\Co-400.spa code shortname pres(Torr) temp(C) conc(pprn) pathlength(m) c0 co- 5 76+0 185 5 10 Co C0-850 760 385 850 10 Co CO-750 760 185 750 10 co CO-650 760 185 €50 10 Co CO-600 760 185 600 10 Co CO-500 760 185 500 10 c0 co- SO 760 185 50 10 co CO-950 760 185 950 10 Cfl c0-i 760 185 1 10 co CO-40 760 185 40 10 co C®-300 760 185 300 10 co Co-30 760 185 30 10 Co Co-200 760 185 200 10 c© Co-20 760 185 20 10 co CO-1500 760 185 1500 10 co c0-150 760 185 150 10 C© co-100 760 185 100 10 c0 c4-10 760 185 10 10 co CO-400 760 185 400 10 rtegion ( 2092.36 - 2201.78 }: 

### ndaws ; 2092.36 - 2112.99 2118.14 - 2134.06 2167.92 - 2201.78 report-compounds = H2Co interference-compounds s CO2,N20 

### Li neari ty o rame = H2C0 

### orderw4 force-zero = fa1se minimize-percent-error = rals2 dynami c-reference = fal se Page 4

### aci d

use-dyanami c fal se use-1 i neari ty fal se ose-shi ft = fa7 se coeffi cents =O, 4} m 0, 0, 0 setname = 112co 

### References : ]et-fzlename = Reg

- i on ( 2462.15 - 2528.55 ) a 

### w - i nr#ows ; 2462125 - 2528.55 rneport-compounds = S02 

### i nterference--cosnponnds = CO2 s H20 Li neari ty o name = So2 order 4 

### force-zero = false mi ni mi ze-percent-error = fa1 se dynami c- reference = fai se use-dyanam

- i c = fal se use-i

- i neari ty = fa1 se use-shi ft = fa1 se coefficents W 0,0,0,0,0 

### setname = s02 References : 

### set-fi 1 enanie =
Regi On t 2673.15 - 2848 . 3.8 ~ e 

### wi ndows ; 2673.3S - 2848.18 report-compounds = NCL 

### i nterferente-compovnds = H20 Li neari ty a name = HCL 

### order 4 force-zero = fal se mi ni mi ze-percent-error = fa1 se dynami c- reference = fai se use-dyanami c = fa1 se use-1

- i rieari ty = fal se use-shift = fa1 se coefficents = 0,0,0,0,0 

### setnatne = HCL 

### Refe renceS : set-filename = Regi on ( 3172 . 7- 3331.5 

### W i ndovus ; 3172.7 - 3331.5 

### report-compounds = H20 interference-compounds = Li neari ty : name = H20 

### order = 4 Rage 5

### aci d force-zero = false minimize-percent-error = false dynamic-reference = false 

### use-dyanami c = fal se use-linearity = false 

### use-shi ft = fa7 se coeffiicents = 0,0,0,0,0 

### setname x Fi20 References : set-fi 1 ename = 

### Reg7 on ( 4067 

### w i ndows ; 4108.4 4140.7 4172.76 .31 -- 4285.13 ) :

4111.29 

### 4144.43 - 4175.22 

### report-compounds = HF interference-compounds = H20 

### Li neari ty o name = HF order = 1 force-zero = true minimize-percent-error = true dynam

- i c-reference = true 

### use-dyanami c = fa7 se use-1 i neari t= fal se use-sf

~ 

### i ft =

~ 

### al se coeffi cents = setname = HF 

### References: set-filename = 

### HF, C:\1\Spectra\Mi sc\oMNIC\HF-10-0.94cm-l. SPA HF, C:\3\spectra\Misc\OM1vIC\HF-40-0.94cm-1.SPA HF, C:\1\Spectra\Misc\OMU =C\HF-20-0.94cm-l.SPA HF, C:`1\Spectra\Misc\oMNZC\HF-15-0.94cm-1 

### .SPA HF, C:\1\Spectra\Misc\OMNIC\HF-120-0.94cm-1.SPA HF, C:\I\Spectra\Misc\oMNIC\HF-100-0.94cm-1.SPA HF, C:\1\Spectra\Misc\OMNIC\HF-5-0.94cm-1.SPA 

### code shortname pres(Torr) temp(C) concCppma patfi7ength(cn) HF HF-10-0.94cm-1 700 i85 10 9 HF HF-40-0.94cm-1 700- 185 40 9 HF HF-20-0.94cm-1 700 185 20 9 HF HF-15-0.94cm-1 700 3.85 15 9 HF HF-120-0.94cm-1 700 185 120 9 HF HF-100-0.94cm-1 700 185 100 9 HF HF-5-0.94cm-1 700 185 5 9

~ - 

### i as :



### Page 6

# N i colet CO2 40K 760T/10m/185C Synthetic

45
40
35

~ 30

~ 

### ,a 25
0

~ 

## Q 20
15
10


### 5

1 1 ~ ~ ~ ~■ iit 

### 2500 2000 1500 1000 500 Uilavenumbers (crn-1 ) 

## Number of sample scans: 'i Number of background scans: 0 Resolufiion: Unknovun Sarnpte gain: 1.0 

## iUlirror velocity: 0.0000 Aperfure: 0.00 Example Spectra~ y ~ 

# h 

# ermo N i cole 

# t

~
£~ 

# 3.8%H20 1851755/10.31JW

6

5

4 

# U G itY 

### 4 2 3 0

~ .~
~ 

### 2

1

0 

### 4500 4000 3500 3000 2500 2000 1500 1000 

## 1fVavenumbers (cm-1) 

## Example Spectra Number of sampfe sccans: 179 Number of background scans: 179 Resolutian: 0.500 Sample gain: 1.0 Mirror velocity: 1.8988 

## Aperrture: 10.00ormoN 

# 0

ICOlet FiCI 10ppm 760/32m/185C Synthetic

0.10

'iW

# m

0.04

0.02

3400 3200 3000 2800 2600 2400 Wavenumbers (cm-1) Exampie Spectra 

## Number of sampie scans: 1 Number ofi background scans: Resolution: 0.500 

### Sample gain: 1.0 Mirror detocity: 0.0000 Apertu re: 0.00'~ 1 ~ ` 1 J ~it~ ~ . ~3~ ,+'• 

## H F 0.1 ppm 650T/25.1 m/'I 85C Synthetic

0.0045
0.0040

0.0035

0.0030 c 

### ~



# ~ 0.0025 0 

# ~ 0.0020
0.0015
0.0010
0.0005 0.0000 4400 4200 4000 3800 3600 

## Wavenumbers (cm-1) 

## Example Spectra Number of sample scans: 1 Number of backgraund scans: i~tesoiution: 0.500 

## Sample gain: 1.0 Niirrar velocity: 0.0000 Aperture: 0.00

# 1

~ '- 

# rh - ~ ~ 

# rniaN i cole 

# t Thu Apr 14 1 5:58:57 2005 (GMT-05:00)

-1.0


### -1.2



# ~ I ~ 

# -e 

# ~ -2.o I t
-2.2

~ rv 

### -2.4 1 ~ 

# i,

~ 

### 1

., 

### •' ~ ~ 

# v :

-2.6 

## 1C4 -L 2500 2480 2480 2440 2420 Vltavenumbers (cm-1) 

## ' Example Spectra Nurriber of sample scans: 32 

## Number of background scans: 32 Resolution: 4.000 

## Sample gain: 1.0 Mirror velocity: 1.8988 

## Aperture: 10.00a



# Ormo

.- Nicoe 

# t Thu Apr 14 Or: 1 8:03 2005 (GMT-05: 0U)

0.30



### 0.25

~ 

### 0.20

C 

### o 0.15 N •
.~
~ 

### 0.10

0.05
0.00 j 

### 1250 1200 1150 1100 1054 1000 950 

## Wavenumbei

- s (cm-71 

## Eacample Specfira Number of sampie scans: 178 Number of background scan$: V9 Resoiution: 0.500 Sample gain: 1.0 t1/lirror vefocity: 1.8988 Apertu re: 10.00~~~ -: o



## {

~ 

## ., r_

~ 

## ; - :, - - r •

_ 

# Nco e 

# t Background, Thu Apr 14 07:08:50 2005 (GMT-05:00)

..



### 50

~ 

### 40

~ 

### m

~ 30

~ G :4] 

### 20

W '~ ,~ ,(#'' ~`~ '• ";. !n `

. ~



### ~ E ~

~ f ~

aIlt 

### 3500 3000 2500 2000 1500 1000 500 

## UUavenumbers (cm-1) Exampie Spectra 

## Number of sample scans: 179 Number ofi background scans: 0 Resolution: 0.500 

## Sample gain: 1.0 Mirror veiocity: 1.8988 Aperture: 10.00

# APPEND IX

. , ~~'`~ ~.`r~"~.. ~.~ ~ .. ~,~ + ~~ i~~~ ta` ~ =•.... ; 1'1 4 ~' ~ : ~ ~ i ~ r, ~~,. ~~i ~ .. ~ ~ '~r' ~ t + ~ ~ ~._ ~E ~ ! ~~ 

## . e..

, ~ , , - ~ -- , ~ ri., 

# I -<- ; ~~ ! ~ ~ ~ Z~ _. _ .j ! ~~ }i~ , ;, , ~ ,i. i k ~ ~~ ~ -- ~' ~ - ; ~

°itot Tube iD No. : A-10 (-iigh side calibration factor : 0.842


### Pei

- forrned b}/: SH 

### Low side calibrafion factor : 0.841


### Caiibration Date : 3J23l2005 

### Comrnents:



### A Side Calib 

### ration hi h side OPs ' A s Cp ev. (in.) (in.) H z 0 H 2 0 0.580 0.810 0.843 0.001 0.580 0.810 0.843 0.001 0_580 1 0_815 0_840 1

- 0.002 

# i -

- Avera - - C ' 0.842 

### B

- 

### Side Calibration ow side epstd' (in. ) 

### H 2 0 OPs'

(in. ) 

### H 2 0 Cp (S) a Dev.

0.580 0.815 0.840 -0.001 0.580 0.815 0.840 -0.001 0.580 1 0.810 0.843 0.002



### I Avera e C' 0.841



### apstd Ternperature ( ° F) : 67 

### CP ( Q = CP(std) ~ 

### L1Ps Humidity (%) : 

### 42
Dev. b = Cp (S) a - Cp' (must be < 0.01) Date: 312312005 Cp' (A) - Cp' (B) = 0.001 (must be <0.01) Cp (std)* : 0.996 Cp' (A) = 0.842 Cp' (B) _ 0.841 Standard Pitot No. : 3 *Cp (std) obtained frrom Dwyer tnstruments air veEocity calcuiator. 

### Cafibrations were done in accordance with CFR Tit1e 40, Part 60, Appendix A, July 1, 1994.

### WESTERN ENVBRONMENTA9. SERV9CES AN® TES1°ING 9NC. METER BOX CALIBRAT9ON FORM

Meter Box Num: 24 Average DGM Y= 0.996 Tech: W-lINES

P6 = 24.90 Deita hi Q= 1.583 Date: 3I10/2005

Orifice 1.D.a 48 K1= 0.3510 OritTce t.D.= 55 K1= 0.4625

1 2 1 2 DGM Flnal 504.689 506.981 510.107 513.109 tn'rtial 502.410 504.689 507.104 510.107
m 2.279 2292 3.003 3.002
em In/0ut 66 66 66 1 66 1 67 67 671 67 vg. Tm °RPF 526 66 526 66 527 S7 527 67 elta H 0.47 0.47 0.84 0.83 fme: 5 0.44 5.007 5 0.06 E5.001 5 0.27 1 5.005 5 0.28 1 5.005 Orifice Tem . 68 68 69 69 acuum "Hg 15.0 15.0 14.0 14.5 m std 1.907 1.918 2.511 2.510 cr (std) 1.905 1.902 2.506 2.506 DGMCF Y 0.999 0.992 0.998 0.999 elta H@ 1.533 1.533 1.581 1.562

Orifice I.D.= 63 K1 = 0.5983 CaRbaration Resadb"
Orifi

~ ce I.D.= 48 DGhIiCF Y= 0.995 Dbfference= 0.085°l0 Avg. Vm (std)= 1.912 Difference (1)= 0.284% (2)= -0.284°!0

aritr#ce I,D.= 55 DGMCF Y= 0.998 Difference= -0.211 % Avg. Vm (std)= 2.510 Difference (1)=



### - 0.018% (2)= 0.018%

OrMce I.D.= 63 DGMCF Y= 0.995 Difference= 0.126% 

### vg . Vm (std)= 3.253 Dffference 1)= 0.051 % (2)= -0.051% 1 2 GM Final 521.231 525.117 Initia! 517.349 521.231
m 3.882 3.886


### em In1Out 67 67 67 67 vg. Tm ° Rf ° F 527 67 527 67 Delta H 1.45 1.45
nne: 50.00 

# 1 5.000 50.17 1 5.003 Orifsce Tem . 70 - 70 

### acuum "Hg 13.0 13.0 m std 3.251 3.255 cr std 3.236 3.237 DGMCF Y 0. 

### 995 0.995 Deita H 1.640 1_640 "Results cornuiv with iVtetEsod 5 calihretinn stanrlarclA whara • rlrA/K:F difrxsranrac ara Lc ec 'khmn .&L9 noii. and average Vm (std) differences are less than f/-0.5%.

### ORiFICE CAUBRATION

Meter Box No. ?4 Initials: N.HINES 

### Date of Calibration 3l10120DI DGMCF: 0.996 Date of Expiration 611012095 Pb: 24.90

ACFM= DGMF-DGRiII

TIt1f1E

SCFNI = ACFM (DGMCF) 528, Pb TM 29.92

IoltITtAL INITIAL FIAlAL FINAL TS411 AHI DGMF DGMI T IN T OUT T IiV T OUT R TI11AE ACFIiA SCFAA 0.11 526.070 525.855 66 66 526 1 0.215 0.179 0.21 526.378 526.070 66 66 526 1 0.308 0.256 0.31 526.754 526.378 66 66 526 11 0.376 0.313 0.4 527.190 526.754 67 67 527 1 0.436 0.362 0.5 527.667 527.190 67 67 527 

### 11 0.477 0.396 0.6 528.180 527.667 67 67 527 1 

### 1 0.513 0.426 0.7 528.706 528.186 67 67 527 11 0.520 0.432 0.751 529.281 528.706 67 67 527 1 0.575 0.478 0.8 529.861 529.281 67 67 527 1 0.580 0.482 0.9 530.484 529.861 67 67 527 1 0.623 0.517 1 531.150 530.484 67 67 527 1 0.666 0.553 1.51 531.939 531.150 67 67 527 1 0.789 0.655 21 532.874 531.939 67 67 627 1 0.935 0.776 2.5 533.892 532.874 67 67 527 1 1.018 0.845 3 534.998 533.892 67 67 527 1 1.106 0.918 3.5 536.216 534.998 67 67 527 

## 11 1.218 1.012 4 537.4911 536.2161 681 68 5281 11 1.2751 1.057

### THERMOCOUPLE CALbBRA7'ION SHEET

MeteP Bou ig8o : 24 T®ch : MRC Date : 3J1012005
Refeaence: Mercas 1

a-iee-Glase A:TPA 3F 

### Referenoe T'herMomeLer "d'herMocou„piR Offeren

~ 

### e

~~~~~

ie. 

## ° F Q!\ °F ° R ° R
Meter In : 

### !ce Bath Boiling Water Hot Oit 

### PAeter t)ut :
tce Bath 33 493 34 494 -0.20 

### Boi#ing Water 214 674 215 675 -0.15 Hot 00 310 770 311 771 -0.13 

### Probe :
lce Bath 33 493 34 494 -0.20 Boiling Water 219 679 220 680 -0.15 Hot 05 312 772 311 771 0.13 

### Steck : !ce Bath 33 493 33 493 0.00 

### Boiling Ulfater 215 675 215 675 0.00 HoY Oil 317 777 317 777 0.00 

### Oven :
lce Bath 34 494 34 494 0.00 

### Boiling Water 215 675 214 674 0.15 Hot Oil 317 777 317 777 0.00 

### Exit :
!ce Bath 33 493 .33 493 0.00 Boiling Water 212 672 212 672 0.00 Hot Ol 311 771 312 772 -0.13 

### Auxivia : !ce 8ath 32 492 33 493 -0,20 

### Boiling V!latei 218 678 219 679 -0.15 Hot Oil 312 772 311 771 0.13

## WESTERN ENV9RONMENTAL SERVICEaS AN® TES'TRNG QNCo. METER BOX CALIBRAT4®N FORM

;Uleter Sox Klum: 21 Average DGiUJ Y= 0.991 Tech: N.HIiVES

Pb =

~ 24.70 Deita H @ = 1.632 Date: 3/22/2005



# ~ Uriflce l.D.= 48 Kl= 0.3510 OrMce I.D = 55 K1= 0.4625 

# ~ 1 2 '! 2 DGM Finai 225.645 227.961 243.906 247.130 lnitial 223.329 225.645 240.784 244.118
rn 2.316 2.316. 3.122 3.012 Temp In/Out 641 64 64 fi4 64 63 64 64 65 64 66164 66 64 66 64 v. Tm °R1°F 524 64 524 

# 1
64 524 

# 1
65 525 

# 1
65 tta H 0.48 0.48 0.84 0.84 rime: 5 0.21 5.004 50.26 1 5.004 510.871 5.181 4 59.9! 68 4.999 Or

~ ce Tem . 69 69 68 

### acuum "Hg 12.0 12.0 11.0 11.0 rn(std) 1.930 1.931 2.604 2.507 cr std 1.886 1,886 2.576 2.485 DGMCF Y 0.977 0.977 0.989 0.991 ita H 1.587 1.588 1.600 1.597

Oriffce I.D.= 63 K1= 0.5983 Calibradon RSesgst
~~ ffice I.®.0 48 DGIVICF Y= 0.977 Difference= 1.389°!0 Avg.1/m (std)= 1.930 Difference (1)= 0.024°!0 (2)= -0.024%

OrMce L0.= 55 DGMCF Y= 0.990 Dffference= 0.086% Avg. Vm (std)= 2.558 Difference (1 )= -1.889% (2)= 1.889°!0

Ort$dcrr Y.D.= 63 DGMCF Y= 1.006 Difference= -1 .475% Avg. Vm (std)= 3.200 Difference (1)= -0.089% (2)= 0.089% 1 2 DGM Final 244.052 247.878 Initiai 240.221 244.052
m 3.831 3.826
em inlOut 64 63 65 163 

# . 651 63 65 63 vg. Tm ° R! ° F 524 

# 1
64 524 

# 1
64 Delta H 1.50 1.50 ime: 50.04 5.OQ1 459.881 4.998 rifice Tem . 67 67 acuum "H

_

g 12.0 12.0 m std 3.203 3.197 cr sfd 3.219 3.217 GtVtCF Y 1.005 1.006 Delta H 1.712 1.711 *Resutts comt)fv with Method 5 catibration standards uvhera_ DGilItCF differannes ara [ass than +/ 2_4a% and average Vm (std) differences are tess 'than +l-0.5°!0.

### (3FUFICE

~ 

### ' rALiBRA'fdON

'Metei Box No. 21 

### fnitials: IV-LJt.NE9„ 

### Date of Cafibrafion 3L2212(10-5 

### DGjlflCF: 0.991 Date of Expiration W2=05 Pb: 24.70

ACFM= DGMF-DGNIi

TiME

SCFM = ACFM (DGiUICF) 528 

# w TM 29.92



### lNITlAL INIT[AL FENAL FtNAL TM AH DGtUIF DGM1 T IN T OUT T tN T OUT R TIME ACFM SCFM 0.1 251.388 251.159 64 64 64 64 524 1 0.229 0.189 0.2 251.693 251.388 64 641 64 64 524 1 0.305 0.251 0.3 252.066 251.693 65 64 65 64 524.5 1 0.373 0.307 OAI 252.493 252.066 65 64 65 64 524.5 1 0.427 0.352 0.51 252.964 252.493 65 64 86 64 524.75 1 0.471 0.388 0.61 253.484 252.964 66 64 66 64 525 1 0.520 0.428 0.71 254.048 253.484 66 641 67 64 525.25 1 0.564 0.464 0.75 254.630 254.048 67 641 67 641 525.5 1 0.582 0.478 0.8 255.224 254.630 67 641 67 64 525.5 1 0.594 0.488 0.9 255.851 255.224 67 641 68 64 525.75 11 0.627 0.515 1 256.525 255.851 68 641 68 64 526 1 0.674 0.553 1.51 257.301 256.525 68 64 69 64 526.25 1 0.776 0.637 21 258.213 257.301 69 64 69 64 526.5 1 0.912 0.748 2.5 259.214 258.213 69 64 70 64 526.75 1 1.001 0.821 3 260.311 259.214 69 64 70 64 526.75 1 1.097 0.900 3.5 261.5081 260.3111 701 641 711 64 527.25 1 1.195 0.979 4 262.779 261.506 70 64 71 64 527.25 1 1.2731 1.043

### THERM000UPLE CAL.IBRATION SHEET

Meter Box No : 21 Tech : m C Date : 3f22/2005 

### Re#®rence: MePcury-In-GBasa ASTM3F

Referermce Thermomgter Thermocoutole 

### 7 2 pffkPe
~ 3murce' °F °R o F a R o R 

### Me2er ! n : Ice Bath 460 460 0.00 

### Qoiling Water 460 460 0.00 Hot Oil 460 gt60 0.00 

### imeter Ouf

: Ice Bath 33 493 33 493 0.00 Boiling Water 210 670 210 670 0.00 Hot 00 355 815 355 815 0.00 

### Probe :
Ice Bath 34 494 34 494 0.00 Boiling Water 211 671 210 670 0.15 Hot Oil 245 705 245 705 0.00 

### Steck :
!ce Bath 32 492 33 493 -020 Boiling Water 211 671 210 670 0.15 Hot Oil 352 812 351 811 0.12 

### Oven : !ce Bath 33 493 33 493 0.00 Boiling Water 211 671 212 672 -0.15 Hot 00 359 819 358 818 0.12 

### Exit : Ice Bath 33 493 33 493 0.00 

### Boifing Water 212 672 213 673 -0.15 Hot Oil 358 818 358 818 0.00 

### Auxiiiary :
Ice Bath 33 493 32 492 0.20 Boiling Water 210 670 211 671 -0.15 Hot Oil 382 842 381 841 0.12

### Area Caiibratioa 

# FT-IR Celfl Calgbration AMT Main 4/1412ao ~ 

### $!'rt°aeon 22 most accurate Integration Range a 1204 -1050 cm-1 Arca Reference 8.055 Area Sam le 3.124 Referencc Conc. (p m) 10.9 Cal gas Conc. 10.1 EteEerence Pressure (To_

- r) 760 Cal gas Pressure (Torr) 757

_ Rc rerence '"emperature (C) 185 Cal gas Tem (IQ 1,85 Re:erciice Pathiength (mete 

### rs) 16.89 Ca1 gas Patlilength (nieters) 

### 7.04

Ethylene (C2H4) Integration Range = 960 - 935 cm-1 Ama Referen,ce 1.231 Area Sam le Reference Conc. (p m) 30.2 Cal gas Conc. Reference Pressure (Torr) 650 Cat gas Pxessure (Torr) Rcference Tem eratare (C) 100 C.ai gas Temp (C) Refercnce Path3ength (nieters) 20 Ca1 gas Patlilengr.l3 (meters)

Catrb®a Monoxide (C®) least accurate Integration Range = 2250 - 2025 cm-1 Area Reference 8.162 Area Sa
~ 

### e Reference Conc. m) 100 Cal gas Conc. Reference Pressure (Torr) 650 CaI gas Pressure (Torr) Reference Temperature (C) 100 Cal gas Tem (C) Rerertnce Pathlength (meters) 20 Cal gas Pathletigth (mcters)

Page 1

### Area Caii6ration 

# FT-IR Cell Calibrati®n AMT Cooler 4/14/2005 ]Frwn 22 most acCurate Integration Range — 1200 -1050 cm-1 Area Reference 8.055 Area Sample 9.762 Reference Conc. (nprn) 10.9 Cal gas Conc. 10.1 Reference PressiEre ('4'orr) 760 Cal gas .Pressure (Torr) 748 Refcrence Tem eraitire (C) 135 Cal gas Tem (K) 135

~ ReFerence Path:length (meters) 16.88 Cal gas Pathlengtli (meters) 

### 22.43

Ekl®me C2H4) Integration Range = 960 - 935 cm-I Area Reference 1.231 Area Sample Reference Conc. pm) 30.2 Cal gas Conc. Rcference Pressure (Torr) 650 Cal gas Pressure (Torr) Reference Tcm erature (C) 100 Cal gm Temp (C) Reference Pathlenodt (meters) 20 Cal gas Pathlength (meters)

Carbon MOn®idde (tC®) least accurate Integration Range = 2250 - 2025 cin-1 Area Referetzce 8.162 Area Sample Reference Conc. ( m) 100 Ca1 gas Conc. Reference Pressure (Torr) 650 Cal gas Pressure (Torr) Rcference Tem erature (C) I0o Cal gas Temp (C) Refercnce Pafihlcngth (meters) 20 Cal gas Patlilength (meters)

Page 1f Rmite 22VVbsto Bmnchbizg

. MM76 USA Tat SM .S f•1 1 ! ' ! • .. e Fmc 908 f . er -http://www



### . spectm-gases



### - co 

### m SHIPPED FRQNI: 80 IHDUSTRtAL DRIVE ALPHA, NJ. 08865 TEl.: (908) 454-7455

SHIiPPED TO: A1Uestem Envirommen#a! Senrices 2826 Hunter Road San Marcos, '

~ 7t 78666


## +CERTIF@CATE 

## OF ANAL.YSIS SGI ORDER # : 0051017 ! T EW : '1 C',lLIIldDF-R # : CC-98158 {CERWICA

- nC+N 

### DATE. 03/24/2004 CYUNDER {PRES. 2000 psig r'.O.# : 03



### - 042 GYUilUDER VALVE: CGA 350 

### BLE6lI® TYPE: CEI4TIFiED

A$1IALYT9CAL ACCURAGY: -¢ ! - 5%
REQlESTED fiAS ANALY'SiS CDMPONENT DONC

Chlorodifluoromethane 10.0 ppm 10.1 PPn► N'strogen Balance Baiance

.. ~ , ANALYST: DATE: 03/24f2004 Ted iveerne

USA o Unked Kirgdom o genmany ® Japan IJO SQ0'1~ 3434 Raute 22 V4bd o Braruftttg. N,1 Q387f USA Tel: {808) 252-9300 s(800) 932-C824 Q Fax (908) 2'i2-0811

~ Jllebsite: http:/lwww spectra-gases.com 

### SliiPPED FROt1t1: 80 INDUS3RlAL DRf1lE ALPtiA,NJ. 08865 TEL (908) 454-7455

SHIPPEDT®: lNestem Environmental Senvices 4105 Hunter #Zd, UNi# 23 San Ntascos; TX 78$68-9382



### CCERMFICATE 

## OF ANALYSIS S 9 ORDER # Y 0043134 ATEW : 2 ' C11UNDER # : CC-143718 CERMF1fGA'D®N DA TE: 1014412003 CYUPIDER PRES: 2000 pstg 

### P.09 : 03-104 CgfUNDER VAL1lE: CGA 330 

### SL.END TVPE: CERTiFiED
AALYM,AI. A+CCi3RACV: ¢ ! - 5°to
REQUEST1ED GAS ANALYSES DOMPONlENT 

## CaNG

SuiTur i-lexafluoride 4.00 ppm 4.03 ppm Hydrogen Chloride 300 ppm 295 ppm
iVitrogen Baiance Balance

10/14f2003

### ~ ;lf 

### ~-.~~~ ~ ~~~~~~s ~~'~~~~: ~e~°~~~~:e,~:. ~

. ~ -

. ~~

. . ... .

# PROF 

# E SSIONA 

# L PROFILE

. ~



## ; J 

# E FF 

# E RY J. K1 V .CY,PP

.,
~ 

### Projecct Manager

f~ 

### ® Doxnesd.c & International "recknAcal ® Eva.luuation of Air Pollutzon Control T3evices ° + gperdse: 

### ® FTTR

a CEMS Emrission Testing & Operation o Source Emission Testing e Caltbration and Mairrtenance of Sampling Equ.ipment m Monitoring Equipm.ent Repair

, . 

### ® Test Method Regulations

Technicafl Mr. Knapp lnas prov3ded enviucouYnental source testing since 1989. His experience Egperlemeeo in,ciudes operation, znaintenance, troubleshooting and supervision of tests on various

cognbusrion systems. He is proficient in El'A methods 1- 6, 7, 8, 9, 10, 12, 17, 20, 22, 23 2 25 1 , 26 2 29, 201 3 202, 316, 318 9 320 and 321; Analogous AQMD Methods 1.1, 2.1, 4.1, 5.1 9 5.2, 5.3, and 6.1; as well as, CARB Methods 430, 522, 524, 410A, and 433. Mr. Knapp has considerable exFerience in FTIR sampling having perforrned over 2000 FTIR evaluations throughout the country. He also has substantial experience 3n CEMS and sample recovery. He has experience in Part 75



### ~ (Tit1e 40) RATA investigations accross the country.
Ealucaflono Nuclear Engineering, Hampton University, VA

Mecha7mcal Engineering, Uni.versity of Southern California, I,os Angeles, CA Irvine iTalley College, Irviae, CA
Cerfflcatlon: ' 'I'CEQ, Texas Visible Enaissions Evaluaxor

®SHA 40-13our Safetr Training Course H 2 S Sa,fety Training MSHA Safety '1'raining Course Safety Council of Southwest Louisiana Western Construct Trauung Trust 

### D.O.T. Certified{'~ ~ "'. ~~ ~ ~ `~ `~ ~ ~!~ ' " ~► ~~ ~~' ~~ $~s ~ i ~

Tecbnicaa Expertisea 

# Jake Crowder

Environmentag Specnialist ® Domestic & International o Evaluation of Air Pollution Control Devices ® Source Emission Testing o Ca1i`bration and Maintenance of Sampling Equipment Q Hazardous Material Trial Burns o Test Method R.egulations o Prolect Manager for 40 Turbine eva.tuations and compliance tests in Cameroon aad Chad.

Tesianical Expericncea .



### Ceufflcad®no 

### Mr. Hinchey has provided emrironmental source testang since 2000. His experience

includes operation, mainter3ance, troubleshooting aand supervision of tests on various emission sources. He is proficient in EPA methods 1- 6, 8, 12, 13, 15, 17, 20, 21, 26, 23 1 , 201 and 202. Mr. Crovvder has considerable experience in sample recovery and cbairrof--custody procedures for partzculate, HCL, metals, S02, and organics. OSHA 40-Hour Safety Training Course H2S Safety Training MSHA Safety Tra.ining Course 

## PECW

~



## EnvaronmentaD Specnalnst

Technicafl 

### + xpemsee 

### o Source Emission Testing

® Field Sampling Q VOC Sampling o Calibration and Maintenance of Sampling Equipment

Techaaicad Egpezreemee:



### Edancataon:

Oeatffleatgoua: 

### IVIr. Cordell has 4-years experisnce in environmental testing. He has assi.sted in

numerous source emission surveys throughout the United States. Mr. Cordell has experience working with EPA methods 1-12, 23, 25, 26, and 29 and saoaple train preparation for various EPA naethods. I1/Ir. Cordell has completed several cotirses in Business Adnamiiiustration tbru Boise State Universrty. H2S Safety Training Vi.sibie Emissions Training MSJH[A Safety Trainung Course CPR Certified 40 Hr. HAZ NIAT Trai.ning OSHA Approved D.O.T. Certified