Pesticide Data Program—Annual Summary, Calendar Year 2006 

# Pesticide Data Program Annual Summary, Calendar Year 2006

United States Department of Agriculture

Agricultural Marketing Service

Science and Technology Programs



## Visit the program Web site at: www.ams.usda.gov/pdp

December 2007Pesticide Data Program—Annual Summary, Calendar Year 2006 United States Department of Agriculture
Marketing and Regulatory Programs
Agricultural Marketing Service

1400 Independence Ave. Washington, DC 20250 

## December 2007

To the Reader:

I am pleased to present the Pesticide Data Program’s (PDP) 16 th

## Annual Summary, that includes data from calendar year 2006. PDP data continue to demonstrate that the Nation’s food supply is among the safest in the world.

The U.S. Department of Agriculture im plemented PDP in May 1991. Since then, PDP has tested a wide range of commod ities in the U.S. food supply. Using a rigorous statistical approach to sampling and the most current laboratory methods, PDP has tested fresh and processed fruit a nd vegetables, grains and grain products, nuts (almonds initiated in 2007), milk and dairy products, beef, pork, poultry, drinking water, bottled water, and gro undwater for pesticide residues.

PDP data are essential for the implemen tation of the 1996 Food Quality Protection Act, that directs the Secretary of Agricu lture to collect pesticide residue data on foods that are highly consumed by infants and children. The U.S. Environmental Protection Agency (EPA) uses PDP data as a critical component for dietary assessments of pesticide exposure. The ex tensive and reliable PDP results provide realistic exposure information to the EPA assessment process.

PDP is a partnership with cooperating St ate agencies that are responsible for sample collection and analysis. Twelve St ates participated in the program during 2006: California, Colorado, Florida, Maryland, Michigan, Minnesota, Montana, New York, Ohio, Texas, Washington, and Wisconsin. Sound conclusions about the U.S. food supply can be drawn from PDP results because together the sampling States represent all regions of the country and over half of the Nation’s population.

The format of this Annual Summary is in tended to provide the reader with thorough and accurate information. A detachable fo rm is included following this letter for your comments and suggestions on how we can further improve this summary.

Sincerely,

Lloyd C. Day Administrator

AMS-Agricultural Marketing Service
An Equal Opportunity Provider and EmployerPesticide Data Program—Annual Summary, Calendar Year 2006 

# Contents Page No.



## Acknowledgements ............................................................................................................... ................vii

Executive Summary .............................................................................................................. .................ix

Acronyms and Abbreviations ..................................................................................................... ..........xii

Section I--Introduction ........................................................................................................................1

Section II-- Sampling Operations .......................................................................................................4 Background.................................................................................................................... ............4 Fresh and Processed Fruit and Vegetables ................................................................................6 Wheat......................................................................................................................... ..............11 Poultry....................................................................................................................... ...............12 Peanut Butter ................................................................................................................. ..........13 Bottled Water and Municipal Drinking Water ........................................................................13

Section III--Laboratory Operations .................................................................................................14 Overview...................................................................................................................... ............14 Fresh and Processed Fruit and Vegetables ..............................................................................14 Peanut Butter ................................................................................................................ ..........15 Wheat......................................................................................................................... ..............16 Poultry....................................................................................................................... ...............16 Bottled Water................................................................................................................. ..........16 Drinking Water ................................................................................................................ ........16 Quality Assu rance Program..................................................................................................... 17

Section IV--Database Management ..................................................................................................19 Electronic Data Pathway....................................................................................................... ...19 Data Reporting................................................................................................................ .........19

Section V--Sample Results and Discussion ......................................................................................21 Sample Results................................................................................................................ .........21 Fresh vs. Processed........................................................................................................... .......23 Import vs. Domestic Residue Comparisons.............................................................................23 National Estimates ............................................................................................................ .......25 Postharvest Applications ...................................................................................................... ...25 Environmental Contaminants ..................................................................................................25 Multiple Pesticide Residue Detections ....................................................................................26 Tolerance Violations.......................................................................................................... ......26 Bottled Water Results......................................................................................................... .....27 Drinking Water Results ........................................................................................................ ...28

iiiPesticide Data Program—Annual Summary, Calendar Year 2006 

# Figures and Tables

Figures Page No.

1 PDP Program Operations Support and Data Users ...........................................................2 2 Program Participants ........................................................................................................ ..3 3 Commodity Origin ............................................................................................................ .8 4 Origin of Selected Fresh Commodities: Eggplant, Plums and Watermelon ....................10 5 Number of Samples Collected and Grower States for Wheat -- Crop Year 2005............11 6 Location and Number of Poultry Sample Collection Sites ..............................................12 7 Location of Drinking Water Collection Sites at Community Water Systems, 2006........14 8 PDP Data Pathway ...........................................................................................................2 0 9 Water Treatment Effects on Different Pesticides.............................................................29

Tables

1 PDP Commodity Collection Schedule for 2006 ................................................................5 2 Distribution of Samples Collected and Analyzed by Each Participating State..................7 3 Number of Samples Analyzed and Summary of Residues Detected by Commodity ......22 4 Selected Residue Comparisons for Fresh and Processed Commodities...........................24 5 Origin of Bottled Water Samples and Number of Residues Detected .............................28

Appendices A-M

Appendix A Commodity History Appendix B Distribution of Residues by Pesticide in Fruit and Vegetables Appendix C Distribution of Residues by Pesticide in Peanut Butter Appendix D Distribution of Residues by Pesticide in Wheat Appendix E Distribution of Residues by Pesticide in Poultry Appendix F Distribution of Residues by Pesticide in Bottled Water Appendix G Distribution of Residues by Pesticide in Drinking Water Appendix H Sample Origin by State or Country Appendix I Import vs. Domestic Pesticide Residue Comparisons Appendix J National Estimates for Concentration Percentiles vs. Tolerance Appendix K Cumulative Distributions of Residues for Selected Pesticide/Commodity Pairs Appendix L Number of Pesticides Detected per Sample Appendix M Fruit and Vegetable Samples Reported to FDA as Exceeding the Tolerance or Without Established Tolerance

vPesticide Data Program—Annual Summary, Calendar Year 2006 

# Acknowledgements
The States participating in the Pesticide Data Program (PDP) deserve special recognition for their contributions to the program. The dedication and flexibility of sample collectors allow the Agricultural Marketing Service (AMS) to adjust sampling protocols when responding to changing trends in commodity distribution and availability. PDP acknowledges the contributions of the State laboratories, U.S. Department of Agriculture’s (USDA) AMS National Sc ience Laboratory, and the Grain Inspection, P ackers, and Stockyards Administration Laboratory in providing testing services to the program, and the National Agricultural Statistics Service for providing statistical support. PDP also acknowledges the exceptional support of the Health Effects Division staff of the U.S. Environmental Protection Agency, Office of Pesticide Programs, in helping set the direction for PDP.

Data presented in this report were collected and processed through the efforts of the following organizations:

Program Administration

Agricultural Marketing Service Science and Technology Programs 1400 Independence Ave., SW South Building, Mail Stop 0270 Washington, DC 20250

Deputy Administrator Science & Technology Programs Robert L. Epstein (202) 720-5231, Facsimile (202) 720-6496

Monitoring Programs Office 8609 Sudley Rd., Suite 206 Manassas, VA 20110 Director: Martha Lamont (703) 330-2300 x117, Facsimile (703) 369-0678

Deputy Director: Diana Haynes (703) 330-2300 x134, Facsimile (703) 369-0678 Electronic-mail Address: amsmpo.data@usda.gov

Web Site: http://www.ams.usda.gov/pdp

Participating State Agencies

California Department of Food and Agriculture California Department of Pesticide Regulation Colorado Department of Agriculture Florida Department of Agriculture and Consumer Services Maryland Department of Agriculture Michigan Department of Agriculture Minnesota Department of Agriculture Montana Department of Agriculture New York Department of Agriculture and Markets Ohio Department of Agriculture Texas Department of Agriculture Washington State Department of Agriculture Wisconsin Department of Agriculture, Trade, and Consumer Protection

Participating Laboratories

California Department of Food and Agriculture Division of Inspection Services Center for Analytical Chemistry 3292 Meadowview Rd. Sacramento, CA 95832

Colorado Department of Agriculture Inspection & Consumer Services Division Laboratory Section 2331 West 31st Ave. Denver, CO 80211-3859

Florida Department of Agriculture and Consumer Services Chemical Residue Laboratory Building #3 3125 Conner Blvd. Tallahassee, FL 32399-1650

viiPesticide Data Program—Annual Summary, Calendar Year 2006 

## Texas Department of Agriculture Pesticide Laboratory 1500 Research Parkway, Ste. B100 College Station, TX 77845

United States Department of Agriculture Grain Inspection, Packers & Stockyards Administration Technical Services Division 10383 North Ambassador Dr. Kansas City, MO 64153-1394

United States Department of Agriculture Agricultural Marketing Service National Science Laboratory 801 Summit Crossing Pl. Gastonia, NC 28054

Washington State Department of Agriculture Chemical and Hop Laboratory 21 N. 1st Ave., Ste. 106 Yakima, WA 98902 Michigan Department of Agriculture Laboratory Division 1615 South Harrison Rd. East Lansing, MI 48823-5224

Minnesota Department of Agriculture Laboratory Services Division 601 N. Robert St. St. Paul, MN 55155-2531

Montana Department of Agriculture Laboratory Bureau McCall Hall, Montana State University Bozeman, MT 59717

New York Department of Agriculture And Markets Food Laboratory 1220 Washington Ave. State Office Campus, Bldg. 7 Albany, NY 12235

Ohio Department of Agriculture Consumer Analytical Laboratory 8995 East Main St. Reynoldsburg, OH 43068

viiiPesticide Data Program—Annual Summary, Calendar Year 2006 

## In 1991, the U.S. Department of Agriculture (USDA) Agricultural Marketing Service (AMS) was charged with designing and implementing the Pesticide Data Program (PDP) to collect data on pesticide residues in food. This 16 th 

## summary presents results for samples collected in 2006.

Program Operations: AMS, through its Monitoring Programs Office (MPO), oversees the planning and policy development for PDP.MPO meets regularly with the U.S. Environmental Protection Agency (EPA) and other stakeholders (e.g., industry and grower groups) to establish program prio rities and direction. Participating States have a prominent role in program planning activi ties and policy establishment, particularly policies relating to Quality Assurance (QA). The USDA National Agricultural Statistics Service (NASS) provides sampling support to PD P and statistically reliable data on chemical usage at the State level and collects economic data that link chemical usage with economic characteristics.

Data Uses: PDP data are used primarily by EPA to prepare realistic pesticide dietary exposures and continue pesticide re-registration activities in accordan ce with the 1996 Food Quality Protection Act (FQPA). PDP provides high-quality data on residues in food, particularly foods most likely consumed by infants and children, including minor crops. Minor crops are those grown on 300,000 acres or less in the U.S. – for example, many fruit and vegetable crops are defined as minor crops.

PDP data are also used by the U.S. Food andDrug Administration (FDA), USDA’s Economic Research Service (ERS) and Foreign Agricultural Service (FAS), participatingStates, academic institutions, chemical manufacturers, environmental interest groups, food safety organizations, and groups within the private sector representing food producers. PDP data are used by the U.S. Government and the agricultural community to examine pesticide residue issues affecting agricultural practices, integrated pest management and U.S. trade, particularly in the competitive global market. PDP additionally provides support for USDA’s participation in the Codex Alimentarius Commission.

Risk Assessment: In estimating the potential risks of consumption of pesticide residues from food, EPA uses a step-wise tiered approach. As afirst step, EPA may use a conservative, worstcase scenario and assume that a pesticide is applied to the fullest extent permitted by the pesticide label; that is, on every acre of each approved crop at the maximum rate and frequency allowed. EPA may also assume that residues on treated crops are present at the maximum allowable level. Exposure estimates based on such assumptions are likely to significantly exceed actual exposure. When an initial assessment indicates a potential risk, EPA refines its assessment using more realistic exposure data. Refinements may include the use of additional data such as: (1) the percent of a crop treated with a pestic ide; (2) studies of the effects of washing, c ooking, processing, and storage; and (3) residue monitoring data. During the refinements of this exposure assessment, PDP data can be pivotal. PDP sampling procedures were designed to capture residues in the food supply as close as possible to the time of consumption. PDP con centrates its efforts to provide realistic pesticid e residue data on foods that are most often co nsumed by infants and children and incorporates recommendations made in 1993 by the National Academy of Sciences (NAS) in its report “ Pesticides in the Diets of Infants and Children.”

Participants: In 2006, sampling and/or testing program operations were carried out with the support of 12 States: California, Colorado, Florida, Maryland, Michigan, Minnesota, Montana, New York, Ohio, Texas, Washington, and Wisconsin. Grain sampling was performed by USDA’s Grain Inspection, Packers, and Stockyards Administration (GIPSA) and poultry

ix 

# Executive SummaryPesticide Data Program—Annual Summary, Calendar Year 2006

x 

## sampling by USDA’s Food Safety and Inspection Service (FSIS). Two Federal laboratories also provided testing services: USDA’s AMS National Science Laboratory and USDA’s GIPSA Laboratory. Participating water utilities provided drinking water samples which were tested by the Colorado, Montana, and New York State laboratories. Bottled water samples were collected at food distribution centers and tested by the Minnesota laboratory. MPO is responsible for admini stering the program,coordinating sampling activities, directing technical performance issues and quality assurance measures, and managing database activities.

Sampling: PDP commodity sampling is based on a rigorous statistical design which ensures that the data are reliable for use in exposure assessments and that they can be used to draw various conclusions ab out the Nation’s food supply. Pesticides and commodities included each year in PDP are selected based on EPA data needs and on information about the types and amounts of food consumed by infants and children. Fruit and vegetabl e, peanut butter, and bottled water samples collected by each of the 10 sampling States (California, Colorado, Florida, Maryland, Michigan, New York, Ohio, Texas, Washington, and Wisconsin) areapportioned according to that State’s population. Samples are randomly chosen close to the time and point of consumption (i.e., distribution centers rather than at farmgate) and reflect whatis typically available to the consumer throughout the year. Samples are selected without regard to country of orig in, variety, or organic labeling. The monthly sampling rate is 62 samples per commodity, except for highlyseasonal commodities. For seasonal commodities, sampling rates are adjusted to reflect market availability. Sampling rates for grain and meat are based on production.

Results: During 2006, PDP tested fresh and processed fruit and vege tables, peanut butter, wheat grain, poultry, bottl ed water, and treated (finished) and untreated drinking water for various insecticides, herb icides, fungicides, and growth regulators. Of the 13,658 total samples collected and analyze d, 9,818 were fruit and vegetable commodities including applesauce,bananas, broccoli, carrots, cauliflower, cranberries, eggplant, grapef ruit, greens (collard/ kale), orange juice, peaches, fresh and dried plums (prunes), frozen potatoes, raisins, spinach, summer squash, frozen sweet peas, watermelon, and winter squash. PDP also tested 739 peanut butter, 687 wheat grain, 1,310 poultry (paired breast/thigh samples), 367 bottled water, and 737 treated (finished) a nd untreated drinking water samples.

Excluding drinking water samples, which were all from U.S. sources, approximately 80 percent of all samples tested were from U.S. sources, 18 percent were imports, 1 percent were of mixed origin, and 1 percent were of unknown origin. Approximately 32 percent of the orange juice samples were of mixed national origin.

Overall, 64 percent of fr esh fruit and vegetables and 59 percent of processed fruit and vegetables showed detectable residues. Residues were detected in 30 percent of the peanut butter samples, 69 percent of wheat grain samples, 7 percent of the poultry breast and thigh samples, and 19 percent of the bottled water samples.

Excluding drinking water, 46 percent of all samples tested contained no detectable pesticides [parent compound and metabolite(s) combined], 28 percent contained 1 pe sticide, and 26 percent contained more than 1 pesticide. Low levels of environmental contaminants were detected in broccoli, carrots, kale gr eens, peaches, frozen sweet peas, spinach, watermelon, winter squash, peanut butter and poultry at concentrations well below levels that trig ger regulatory actions.

Excluding samples for which no tolerances are set (bottled water and treated/untreated drinking water), residues exceeding the tolerance were detected in 0.2 percen t of the 12,554 samples tested in 2006 – 31 sample s with 1 residue each. A tolerance is the maximum amount of a pesticide residue allowable on a raw agricultural commodity. Established tolerances are listed in the Code of Federal Regulations, Title 40, PartPesticide Data Program—Annual Summary, Calendar Year 2006 

## of pesticides, metabolites, and isomers included in the PDP testing profiles were not detected. None of the detections in the finished water samples exceeded established EPA Maximum Contaminant Levels (MCL) or Health Advisory (HA) levels or establis hed Freshwater Aquatic Organism (FAO) criteria.

Data Availability: PDP continuousl y strives to improve methods for the collection, testing, and reporting of data. These data are freely available to EPA and other Federal and State agencies charged with regulating and setting policies on the use of pesticides. They also are available to all stakeholders by hard copy, Internet, or custom reports generate d by MPO. Additional copies of the PDP Annual Summary may be obtained by calling MPO at (703) 330-2300 or by mailing the form provided at the end of this report. This publication, the PDP database file for 2006, and annual summaries and database files for previous years are available on the PDP Web site at www.ams.usda.gov/pdp

.

xi 

## 180. Residues with no established tolerance were found in 3.1 percent of the samples (367 samples with 1 residue each, 17 samples with 2 residues each, 2 samples with 3 residues each, and 1 sample with 4 residues). In most cases, these residues were detected at very low levels and some residues might have resulted fromspray drift or crop rotations. PDP communicates these findings to FDA when they are reported by testing laboratories.

For bottled water, 12 different residues from 6 different pesticides were detected. Most samples with detectable residues contained only a single pesticide or metabolite. All detections were well below established FDA Standards of Quality (SOQs). In finished drinking water, PDP detected low levels (measured in parts per trillion) of some pesticides, primarily widely used herbicides and their metabolites. Forty-eight different residues were detected in the untreated intake water and 39 in the treated water. The majorityPesticide Data Program—Annual Summary, Calendar Year 2006

xii 

# Acronyms and Abbreviations

% C.V. Percent Coefficient of Variation AMS Agricultural Marketing Service BQL Below Quantifiable Level EMRL Extraneous Maximum Residue Limit EPA Environmental Protection Agency ERS Economic Research Service ESA Ethane Sulfonic Acid e-SIF Electronic-Sample Information Form FAO Freshwater Aquatic Organism FAS Foreign Agricultural Service FDA Food and Drug Administration FSIS Food Safety and Inspection Service FQPA Food Quality Protection Act GC Gas Chromatography GIPSA Grain Inspection, Packers, and Stockyards Administration GLP Good Laboratory Practices HA Health Advisory LC Liquid Chromatography LIB Laboratory Information Bulletin LOD Limit of Detection LOQ Limit of Quantitation MCL Maximum Contaminant Level MPO Monitoring Programs Office MRL Maximum Residue Limit MRM Multiresidue Method MS Mass Spectrometry NAS National Academy of Sciences NASS National Agricultural Statistics Service NSL National Science Laboratory OA Oxanilic Acid PAM Pesticide Analytical Manual PDP Pesticide Data Program ppm parts per millionPesticide Data Program—Annual Summary, Calendar Year 2006

xiii 

## PT Proficiency Testing QA Quality Assurance QAO Quality Assurance Officer QAU Quality Assurance Unit QC Quality Control RDE Remote Data Entry SIF Sample Information Form SOP Standard Operating Procedure

SPE Solid Phase Extraction SSL Secure Sockets Layer TPM Technical Program Manager USDA United States Department of Agriculture USGS United States Geological Survey SOQ Standards of QualityPesticide Data Program—Annual Summary, Calendar Year 2006 1 

# I. Introduction

The Pesticide Data Program (PDP), which was initiated in 1991 to collect data on pesticide residues in food, now has an important role in the implementation of the 1996 Food Quality Protection Act (FQPA). This law directs the Secretary of Agriculture to collect pesticide residue data on commodities most frequently consumed by infants and children. PDP data are used primarily by the U.S. Environmental Protection Agency (EPA) to assess dietary exposure during the review of the safety of existing pesticide tolerances (Maximum Residue Limits).

Because PDP collects data on food commodities primarily for exposure assessment, program operations differ markedly from those followed by regulatory monitoring programs for tolerance enforcement. PDP samples are collected closer to the point of consumption and are prepared emulating consumer practices. Sampling is based on EP A data needs and doesnot impede commodity distribution. Laboratory operations are designed to achieve the lowest detectable levels rather than quicksample turnaround. As a dietary risk assessment support program, PDP focuses its pesticide testing on registered uses for the commodities in the program rather than screening for all potential illegal uses.

Figure 1(a) illustrates PDP program policy development and planning operations. Primary contributors to these activities include the participating States, EPA, USDA’s National Agricultural Statistics Service (NASS), and additional stakeholders including industry andgrower groups. Figure 1(b) depicts PDP primary data users including EPA, the U.S. Food and Drug Administration (FDA), USDA’s Economic Research Service (ERS) and Foreign Agricultural Service (FAS), participating States, academic institutions, chemical manufacturers, environmental interest groups, food safety organizations, and groups within the privatesector representing food producers. Additionally, other Federal, St ate and foreign government agencies and industry have used PDP data to promote the export of U.S. commodities to international markets, and the Codex Alimentarius Committee on Pesticides Residues has proposed PDP methodologies for international adoption.

In 2006, sampling services were provided by 10 States (California, Colorado, Florida, Maryland,Michigan, New York, Ohio, Texas, Washington, and Wisconsin); the USDA GrainInspection, Packers, and Stockyards Administration (GIPSA); and the USDA Food Safety Inspection Service (FSIS). Additional sampling services were provided by participating drinking water facility personnel in 15 States (Alabama, Arizona, California, Florida, Georgia, Iowa, Louisiana, Michigan, Minnesota, Missouri, Montana, New Jersey, North Dakota, Pennsylvania, and South Carolina) and the District of Columbia. Laboratory services were provided by the States of California, Colorado, Florida, Michigan, Minnesota, Montana, New York, Ohio, Texas, and Washington; the Agricultural Marketing Service (AMS) National Science Laboratory (N SL); and the GIPSA Laboratory. The AMS Monitoring Programs Office (MPO) is responsible for overall management of PDP.

Figure 2 shows the States that participate in program sampling and/or testing as well as the States in their direct distribution network. Together, these States represent about 50 percent of the Nation's population and all 4 census regions of the U.S. These States also represent major producers of fruit and 

# Pesticide Data Program (PDP) Annual Summary, Calendar Year 2006
This summary consists of the following sections : (I.) Introduction, (II.) Sampling Operations, (III.) Laboratory Operations, (IV.) Database Manage ment, and (V.) Sample Results and DiscussionPesticide Data Program—Annual Summary, Calendar Year 2006 2 

## Figure 1. PDP Program Operations Support and Data Users. This figure illustrates (a) agencies/ groups that support PDP program policy and planning activities, and (b) agencies/groups that use PDP data. 

# Industry and Grower Groups

Academic Institutions Other Government

Agencies

Agricultural Industry CODEX

Chemical Manufacturers,

Environmental Interest

Groups, Food Safety Organizations (a) PDP Policy and Pl anning Contributions

(b) PDP Data Users 

# Participating States

National Agricultural Statistics Service Environmental Protection

Agency

Food and Drug Administration Participating States Environmental Protection

Agency

Foreign Agricultural Service Economic Research ServicePesticide Data Program—Annual Summary, Calendar Year 2006 3 

## vegetables in the U.S. AMS works closely with EPA to select commodities and pesticides for testing and in the selection of drinking water sites. The commodities selected are those representing the highest U.S. consumption, with an emphasis on foods consumed by infants andchildren. Appendix A provides a list of commodities tested by PDP from the beginning of the program in 1991 through 2007.

Fruit and vegetable samples are collected atterminal markets and large chain store distribution centers from which food commodities are supplied to supermarkets and grocery stores. Sampling at these locations allows for residue measurements that include pesticides applied during crop production and those applied after harvest (such as fungicides and growth regulators) and takes into account residue degradation while food commodities are in storage. Participation as a PDP sampling site is voluntary, which sets it apart from State and Federal enforcement programs. In 2006, more than 700 sites granted access and provided information, including site volume data, to sample collectors. This voluntary cooperation is important to PDP and makes it possible to adjust sampling protocols in response to fluctuations in food distribution and production.

Whole grain samples are collected by trained USDA GIPSA inspectors. Poultry samples are collected from designated slaughter facilities by trained USDA FSIS inspection program Figure 2. Program Participants. During 2006, AMS established coopera tive agreements with 12 States to sample and/or test PDP commodities. State laboratori es are responsible for anal yzing fresh and processed fruit and vegetable samples and drinking water samples. The Federal laboratory in Gastonia, North Carolina, analyzes meat, poultry, and dairy products, and the Fed eral laboratory in Kansas City, Missouri, analyzes whole and processed grain products. States that do not participate in PDP’s sampling program but are in the direct distribution networks of the participating States also are shown. Nevada Idaho Wyoming

New Mexico

Hawaii Alaska V i r

g

i nia 

### Delaware Connecticut Massachusetts Michigan Vermont

New Jersey New York



### Texas California

Oklahoma Washington

Wisconsin



### Florida

Participating State Minnesota

States where produce is directly marketed from Participating States
Location of Participating State (white stars)/Federal (black stars) Laboratories 

### Maryland Colorado Ohio MontanaPesticide Data Program—Annual Summary, Calendar Year 2006 4 

## personnel. Treated and untreated drinking watersamples are collected on-site by trained watertreatment personnel at selected water treatment facilities across the country.

Pesticides screened by PDP include those with current registered uses and compounds for which toxicity data and preliminary estimates of dietary exposure indicate the need for more extensive residue data. PDP also monitors pesticides forwhich EPA has instituted modified use directions (i.e., reduced application rates or frequency) as part of risk management activities.The following appendices list the specific pesticides tested in the program: fruit and vegetables (Appendix B), peanut butter (Appendix C), wheat (Appendix D), poultry (Appendix E), bottled water (Appendix F), and drinking water (Appendix G). 

# II. Sampling Operations

♦ Background

The goal of the PDP sampling program is to obtain a statistically defe nsible representation of the U.S. food supply. PD P data reflect actual pesticide residue exposure from food. Using a rigorous statistical de sign, PDP has developed extensive procedures to ensure that samples are randomly selected from the national food distribution system and re flect what is typically available to the consumer.

Fruit, vegetables, pean ut butter, and bottled water are randomly collected by trained State inspectors at terminal markets and large chain store distribution centers throughout the country. Surrogate or “proxy” sites (retail markets) are occasionally used to collect these samples when the commodity of interest is unavailable at a terminal market or distribution center. In these instances, the commodity is selected in the rear storage area of the retail facility so that possible contamination by the consumer is eliminated and to allow capture of sample information from the product boxes. In 2006, 8.9 percent of fruit, vegetable, peanut butter, and bottled water samples were collected at proxy sites. The commodities most often collected at these facilities were bottled water and processed commodities.

Wheat grain samples are collected from trains, trucks, and barges bytrained USDA GIPSA inspectors. Poultry samp les are collected from designated slaughter fa cilities by trained USDA FSIS inspection program personnel. Treated and untreated drinking water samples are collected on-site by trained wate r-treatment personnel at selected water treatment facilities across the country.
At all sampling locations, information is usually available about the identity and origin of the sample. Sample information is captured at the time of sample collection for inclusion in the PDP database. PDP sample origin data identify the State or country where the commodity was produced. A comparison of PDP sample origin data to State producti on and import data by USDA’s NASS shows that PDP sampling is representative of th e U.S. food supply. PDP sampling operations are adjusted according to product availability. The number of fruit, vegetable, peanut butter, and bottled water samples collected in eachparticipating State is determined by State population. The number and location of collected wh eat and poultry samples are determined by annual domestic production figures. The number and location of drinking water samples from water treatment facilities are determined by EPA pesticide registration information needs. Each local watershed has its own unique characteristics; therefore, sample collection for this commodity is not intended to reflect national trends. In this case, PDP collects samples in areas where it is known that targeted pesticides are heavily used. The quarterly collection schedule for all 2006 commodities is shown in Table 1.

PDP State sample collectors are trained to adhere to detailed program Standard Operating Procedures (SOPs) that pr ovide criteria for site selection and specific instructions for sampleselection, shipping and handling, and chain-ofcustody. SOPs are updated as needed and servePesticide Data Program—Annual Summary, Calendar Year 2006 5 

## Table 1. PDP Commodity Collection Schedule for 2006. Samples most often are collected for a 2-year time period. Commodities are initiated or terminated in different quarters of the year, so that new commodities are not brought into th e program all at the same time. This table illustrates time ranges for the listed commoditie s. See Appendix A for the complete PDP commodity history from May 1991 through December 2007. ** Spinach collection ended 3 months earlier than planned due to the unavailability of the product in the aftermath of the E.coli outbreak. Commodity Jan-Mar Apr-Jun Jul-Sep Oct-Dec End Date

Applesauce Dec-06

Bananas Dec-07

Broccoli Sep-08

Carrots Dec-07

Cauliflower Sep-06

Cranberries Dec-06 Eggplant Dec-06 Grapefruit Dec-06 Greens, Collard & Kale Sep-08 Orange Juice Sep-06

Peaches Sep-08

Peanut Butter Dec-06

Peas Dec-06 Plums, Dried (prunes) Dec-06
Plums, Fresh* Dec-06

Potatoes Dec-07 Poultry Dec-06

Raisins Jun-07 Spinach** Sep-06 Squash, Summer Sep-08
Water, Bottled Dec-06 Water, Finished Ongoing
Water, Untreated Ongoing

Watermelon Sep-06

Wheat Grain*** Jun-06 Winter Squash Jun-06

*** Wheat was collected in the 2005 Crop Year, Aug 2005-Jun 2006 and continued for the remainder of the year for the 2006 Crop Year. * Dried plums (prunes) were collected if fresh plums were unavailable.Pesticide Data Program—Annual Summary, Calendar Year 2006 6 

## as a technical reference in conducting program sampling reviews to ensure that program goals and objectives are met. SOPs for PDP sampling are available on the Internet at www.ams.usda. gov/pdp

. Temperature-sensitive samples are packed in heavy-duty, temperature- controlled containers. Holding temperatures are preserved throughout transit time with the inclusion of ample frozencold packs and insulating materials. Nontemperature-sensitive samples do not require temperature-controlled cont ainers; however, they are shipped in heavy-duty, well-cushioned containers. Samples are shipped the same day as collection by overnight de livery to preserve sample integrity. Wheat samples are collected in pesticide-free polyethylen e bags and are shipped in canvas pouches or boxes to the laboratory where the samples are refrigerated pending analysis. Poultry samples are collected inpesticide-free polyethylene bags, frozen overnight, and shipped by next-day delivery to the laboratory for analysis. Drinking water samples from water treatment pl ants are collected in specially prepared bottles containing dechlorinating agents to halt any potential compound degradation, packed w ith proper cushioning and cold packs, and shipped the same day as collection to their re spective laboratory by overnight delivery.

Electronic Sample Information Forms (e-SIFs) are used for chain-of-c ustody and to capture information needed to characterize the sample. Sample collectors use handheld or laptopcomputers in the field to record sample identification information such as: (1) State of sample collection, (2) collection date, (3) sampling site code, (4) commodity code, and (5) testing laboratory code. Inform ation from these five data elements is combined to form a unique PDP sample identification number for each sample. Other available informati on about each sample is also recorded, such as collector name, the State or country of origin, pr oduct variety, production claims such as organic, post-harvest chemical applications, and grower, packer, and/or distributor locations. The e-SIFs are emailed the same day as sample collection or, at the latest, by 8:00 a.m. the morni ng after collection to ensure that sample information is received at each laboratory by the time samples arrive for analysis. Refer to Section IV on Database Management for more information on the e-SIF system.

♦ Fresh and Processed Fruit and Vegetables

Of all samples collected and analyzed in 2006, 72 percent (9,818 of 13,658) were fruit and vegetables, including fr esh and processed products. The fresh commodities collected for PDP were bananas, broccoli, carrots, cauliflower, cranberries, eggplant, grap efruit, greens (collard greens and kale), peaches, plums, spinach, summer squash, watermelon, and winter squash. The processed commodities included applesauce, orange juice (ready-to-serve and frozen), dried plums (prunes), frozen potatoes, raisins, and frozen sweet peas. All fresh fruit and vegetable samples weighed either 3 or 5pounds (3 pounds were collected for lowweight commodities such as greens and spinachand 5 pounds were collected for larger, highweight commodities such as eggplant andgrapefruit). For relatively large-sized commodities, such as cauliflower, eggplant, grapefruit, and summer squash, a minimum of two units were collected to maintain sample representativeness. An exception for these large-sized commodities was watermelon; only one unit was collected per sample because of its unusually heavy shipping weight. The weights or volumes of processed commodities varied by commodity: applesauce, frozen potatoes, and frozen sweet peas - 3 pounds; orange juice - 1 quart; and dried plums and raisins - 15 ounces.

Participating State agencies compile and maintain lists of sampling sites. The States provideAMS and NASS with annual volume information for commodities distributed at each site. This information is used to weight the site to determine the probability for sample selection. For example, a weight of 10 may be given to a site that distributes 100,000 pounds of producePesticide Data Program—Annual Summary, Calendar Year 2006 7 

### State BN BR CA CF CR EP GF GK GL PC PU SP WM WS Total Fresh California 168 41 30 126 168 167 168 31 11 15 99 113 127 84 1,390
Colorado 24 6 8 18 24 24 24 1 5 3 17 18 - 12 190
Florida 84 21 62 63 84 84 84 7 14 17 53 57 189 42 882 Maryland 48 12 16 36 48 48 48 6 6 4 38 32 24 24 402 Michigan 72 18 28 54 72 72 72 8 10 10 55 47 - 36 572
New York 108 27 40 81 108 107 108 17 10 12 89 72 42 54 902
Ohio 70 18 56 54 72 72 72 10 8 5 46 53 - 36 590
Texas 96 24 33 72 96 94 96 10 13 16 75 70 168 45 932 Washington 48 12 35 36 48 48 47 4 8 5 28 34 - 24 389

Wisconsin 24 6 8 18 24 24 24 4 1 3 15 15 - 12 184
742 185 316 558 744 740 743 98 86 90 515 511 550 369 6,433 SS
42
6
21
12
18
27
18
24
12

6

186

State AC PZ RA Total Processed Total Fresh & Processed F&V California 168 168 84 779 2,169
Colorado 24 24 12 109 299 Florida 84 84 42 388 1,270 Maryland 48 48 24 212 614 Michigan 72 72 36 323 895 New York 108 108 54 478 1,380
Ohio 72 72 36 332 922 Texas 96 96 48 429 1,361 Washington 48 48 24 224 613
Wisconsin 24 24 12 111 295 744 744 372 3,385 9,818 PS
168
24
84
48
72
108
72
96
48
24
744 PD
66
7
31
8
17
19
26
21
20
9
224 OJ
125
18
63
36
54
81
54
72
36
18
557



## Table 2. Distribution of Samp les Collected and Analyzed by Each Participating State. This table includes those commodities collected at terminal mar kets and distribution centers. The distribution of wheat, poultry, and drinking water samples can be found in Figures 5, 6, and 7 respectively. AC = Applesauce GK = Greens, Kale PZ = Potatoes, Frozen

BN = Bananas GL = Greens, Collard RA = Raisins

BR = Broccoli OJ = Orange Juice SP = Spinach

CA = Cranberries PB = Peanut Butter SS = Summer Squash

CF = Cauliflower PC = Peaches WB = Bottled Water

EP = Eggplant PS = Sweet Peas, Frozen WS = Winter Squash GF = Grapefruit PU = Plums CR = Carrots PD = Plums, Dried (Prunes) WM = Watermelon 

### Commodity Legend PB WB 

### 166 88 24 14 83 36 48 25 72 35 108 48 70 36 96 49 48 24 24 12
739 367 Fresh Fruit and Vegetables

Processed Fruit and Vegetables Nut Product Water ProductPesticide Data Program—Annual Summary, Calendar Year 2006 8 

## annually and a weight of 1 is given to a site thatdistributes 10,000 pounds. The probabilityproportionate-to-size method of site selection then results in the larger site being 10 times more likely to be selected for sampling than the smaller site.

Participating States work with NASS to develop statistical procedures for site weighting and selection. States are also given the option to have NASS perform their quarterl y site selection. The number of sampling sites and the volume of produce distributed by th e sites vary greatly between States. Sampling plans that include sampling dates, sites (primary and alternate), targeted commodities, and testing laboratories are prepared by each State on a quarterly basis. Collection of commodities is randomly assigned to weeks of the month, prior to selection of specific sampling dates within a week. Because sampling sites are selected for an entire quarter, States may assign the site s to particular months based on geographic location.

State population figures ar e used to assign the number of fruit and vegetable samples scheduled for collection each month. These population- and distri bution-network-based numbers result in the following monthlycollection assignments for each State: California, 14; Colorado, 2; Flor ida, 7; Maryland, 4; Michigan, 6; New York, 9; Ohio, 6; Texas, 8;

A. Fresh Fruit and Vegetable Commodities

Bananas (742 Samples) Broccoli (185 Samples) Carrots (744 Samples)

Domestic 85.8% Domestic 94.6%

Import 3.2% Import 100% Unknown 2.2%



### Cauliflower (558 Samples) Cranberries (316 Samples) Eggplant (740 Samples)

Domestic 94.3%

Import 5.7% Domestic 61.5% Domestic 96.6%

Import 3.2% Unknown 0.2%

Import 37.3% Unknown 1.2% Import 13.5% Unknown 0.7%



### Grapefruit (743 Samples) Greens, Collard (86 Sample Greens, Kale (98 Samples)

Domestic 98.8%

Import 1.2% Domestic 85.7% Domestic 98.1%

Import 14.3% Import 1.8% 

### Greens, Collard (86 Samples)

Unknown 0.1%Pesticide Data Program—Annual Summary, Calendar Year 2006 9 

### Peaches (90 Samples) Plums (515 Samples) Spinach (511 Samples)

Import 5.5% Domestic 94.1% Domestic 73.3%

Import 26.7% Unknown 0.4%

Import 37.5% Domestic 61.9%



### Squash, Summer (186 Sam Peaches (751 Samples)

Domestic 27.9% Domestic 48.9%

Import 47.9% Unknown 0.5% Unknown 3.2% Import 71.6% 

### Squash, Winter (369 Samples) Mixed National 0.2% Unknown 0.4%



### Watermelon (550 Samples) Squash, Summer (186 Samples)

Unknown 1.8% Domestic 52.4%

Import 45.8%



### B. Processed Fruit and Vegetable Commodities

Green Beans Peaches (751 Samples)

Domestic 64.6% Domestic 96.9%

Import 3.0% Mixed National 32.0% Import 2.7% Unknown 0.1% 

### Orange Juice (557 Samples) Apple Sauce (744 Samples) 

### Peaches (751 Samples)

Domestic 96.4%

Mixed National 2.2% Import 0.9% 

### Plums, Dried (Prunes) (224 Samples)

Unknown 0.7% Unknown 0.5%



## Figure 3. Commodity Origin. This figure depicts the proportion of commodity origin (domestic vs. import vs. unknow n origin) for each fresh and processed fruit and vegetable product tested in 2006. Green Beans Peaches (751 Samples)

Domestic 98.9% Domestic 85.8%

Import 13.4% Import 0.8% Unknown 0.8% 

### Raisins (372 Samples) Potatoes, Frozen (744 Samples) 

### Peaches (751 Samples)

Domestic 86.9%

Import 12.4%



### Sweet Peas (744 Samples)

Unknown 0.3% Unknown 0.7%Pesticide Data Program—Annual Summary, Calendar Year 2006 10 

### Domestic Imported Unknown 0 10 20 30 40 50 60 70

J A

N F E

B M A

R A P

R M A

Y J U

N J U

L A U

G S E

P O C

T N O

V D E C 

## Origin of Eggplant Samples

0 10 20 30 40 50 60 70

J AN FEB MA R A PR MAY JUN J U

L A UG SEP 

### 0 10 20 30 40 50 60 70

J A

N F E

B M A

R A P

R M A

Y J U

N J U

L A U

G S E

P O C

T N O

V D E C



## Origin of Watermelon Samples Origin of Plum Samples

Figure 4. Origin of Selected Fresh Commodities: Eggplant, Plums and Watermelon. Differences in origin (domestic vs. import) are illustrated by month. The targeted number of samples is 62 per month for each commodity.Pesticide Data Program—Annual Summary, Calendar Year 2006 11 

## Washington, 4; and Wisc onsin, 2. This schedule results in a monthly target of 62 samples per commodity, or 744 samp les per commodity per year.
The total number of samples collected in each State for each commodity is listed in Table 2. Figure 2 illustrates the participating States and the laboratories to which samples were shipped. The total number of samples per commodity and the percentage of each that were either domestic, imported, or of unknown origin are shown in Figure 3. The origin of some fresh commodities can vary greatly throughout the year. Graphic examples of this variation can be found in Figure 4 where di fferences in origin (domestic vs. import) are depicted for eggplant, fresh plums, and watermelon by month. Fruit and vegetable samples originated from 41 States and 27 foreign countries (refer to Appendix H).

♦ Wheat

Trained USDA GIPSA insp ectors collected 687 wheat samples for PDP for the 2005 crop year (October 2005 through April 2006). Samplecollection rates, on a state-wide basis, were calculated on the basis of crop production totals averaged over a 3-year period. Samples were drawn from trucks (17% of samples), hopper cars (69% of samples), and barges (14% of samples). Wheat grain slated for export were excluded from the sampling scheme. PDP Michigan



## Figure 5. Number of Samples collected and Grower States for Wheat – Crop Year 2005. A total of 687 wheat samples were collected between October 2005 and June 2006. The samples originated from 27 States and were collected in proportion to their production volumes. Residue testing for all samples was performed by GIPSA, located in Kansas City, Missouri. South Dakota Minnesota

Arkansas North Dakota

12 3

6 8

2

3 13 72

5

132

13 8 8 22 18

8 50

56

Ohio

L o u i s i a n a

States where more than 30 samples originated

States where less than 30 samples originated

GIPSA laboratory—Kansas City, Missouri M i s s i s s i p p i Kansas M i s s o u r i Wisconsin

Nebraska Illinois

I n di a na

N

. C a

r o

l i n

a T

e n n essee

K

en

t uc

k y V ir

g

in

i a California 6 23 Colorado

Georgia 1 Idaho

44 Montana
43

Oklahoma
50

Texas

35 Washington 45

Utah
1Pesticide Data Program—Annual Summary, Calendar Year 2006 12 

## chain-of-custody procedures are similar to those used for fruit and vegetable samples. Sample information for wheat included: inspection location, inspection point code, field office location, official agency collecting the sample, carrier type (truck, hopper car, or barge), carrier identification code, Stat e of origin, collection date, and inspector’s name. Pesticide residue analysis was performed by the GIPSA Technical Services Division Laboratory located in Kansas City, Missouri. Wheat samples were collected from 9 GIPSA field offices across the country and originated from 27 States. There were no imported wheat samples; all were of domesticorigin. The origin and number of samples collected from each State is displayed in Figure 5. ♦ Poultry

Between January and December 2006, 1,310 poultry samples were collected for PDP bytrained FSIS inspectors. The inspectors collected samples from young hens and mature chickens at designated sl aughter facilities, separately bagged each tissue in pesticide-free polyethylene bags, labeled the samples, and froze the samples overnight. Once frozen, the samples were packed with frozen cold packs in tamper-proof boxes, and shipped by overnight delivery to the NSL in Gastonia, North Carolina, for analysis. FSIS used specially designed Unified Sampling Forms that contain all required PDP sample information. The forms were

Figure 6. Location and Number of Po ultry Sample Collection Sites. A total of 1,310 poultry samples were collected that included 655 breast tissue samples and 655 thigh tissue samples, with each set taken fr om a composite of 6 birds. All samples were approximately 1 pound. FSIS inspectors collected samples at designated slaughter facilities. The samples originated from 29 States and Puerto Rico. Residue testing for all samples was performed by the AMS National Science Laboratory in Gastonia, North Carolina. Michigan

N

. C ar

o

l i na 2

8

84 20 

### Ohio

54 

### California P en ns y l v ania



### Maryland (36)

146 6

Arkansas



### Georgia 8

198 I n d i a n a 

### Minnesota

Missouri 36



### Oklahoma Nebraska

44 2 

### South Dakota Oregon
8



### South Carolina 26 2



### Texas 104 V i r

g

i n i a 40 Wisconsin 4

States where more than 30 samples were collected.

States where less than 30 samples were collected.

USDA, National Science Laboratory, Gastonia, North Carolina A l a b a m a

134 

### Delaware (42)

Florida 8 

### K

e n

t u c

k

y 54

36



### Louisiana M i s s i s s i p p i

110



### T

e n n e s

s

e

e 38 

### Vermont

2 

### Washington 6



### Puerto Rico (2) West Virginia (24)Pesticide Data Program—Annual Summary, Calendar Year 2006 13 

## completed on-site and accompanied each sample during shipment. Each site sample consisted of breast muscle tissue from each of 6 chickens and thigh muscle tissue from each of the same 6 chickens for a total of 655 breast tissues and 655 thigh tissues, or 1,310 individual samples. All samples contained skin and were deboned. Samples were taken from 161 slaughter facilities in 29 States plus Puerto Rico at rates according to throughput volume (refer to Figure 6 for distribution of sample s in each State).

♦ Peanut Butter

PDP collected and analyzed 739 peanut buttersamples in 2006. Approximately 1-pound samples were collected from routine PDP sampling sites that included major chain-store distribution centers and terminal markets. Less than one percent of the samples we re collected from proxy sites. Only “creamy style” peanut butter samples containing not less than 90 percent peanuts were collected. Styles such as chunky, old fashioned, and jelly mixes were excluded. Analysis was performed by the GIPSA Technical Services Division Laboratory locat ed in Kansas City, Missouri.

♦ Bottled Water and Municipal Drinking Water

PDP State sample collectors collected 367 bottled water samples that represented a half sampling rate from the 10 participating States (California-7, Colorado- 1, Florida-3, Maryland2, Michigan-3, New York-4, Ohio-3, Texas-4, Washington-2, and Wisc onsin-1). Eighty-six percent of the samples we re of domestic origin, 13 percent were imported, and 1 percent were of mixed national origin. A minimum of 2 liters per sample was collected fromdistribution and retail facilities in each participating State. Bottled water types excluded fro m the sampling scheme were: natural sparkling bottled water and mineral water. Artificially carbonated water, seltzerwater, and flavored water, which are not regulated by FDA as bottled water, also were not included in the sampling scheme. Most bottled water sample collection was performed at proxy sites (retail stores) because local, as well as national brands, were in cluded in the survey. Sample information and packing procedures were the same as those for fruit and vegetables; however, the inclusion of cold packs for shipping was unnecessary. Sample information on bottled water also in cluded (1) bottle type and (2) brand name. Sample collection States are found in Table 2. Sample analysis was performed by the State laboratory in Minnesota.

In the municipal water sampling project, 737 drinking water samples were collected from 14 States and the District of Columbia community water systems that draw water from surfacewater sources. Samples were collected bimonthly by trained wate r treatment facility personnel and sent to St ate laboratories in Colorado, Montana, and New York for analysis. Samples included water collected from both the raw water intake and the finished drinking water after treatment. The untreated intake water and treated water were collected as paired samples, taking into account each individual plant’sprocessing time. Dechlorination and preservative chemicals were added to the samples at the time of collection. Samples were packed with frozen cold packs and shipped overnight to the testing laboratories.

The States and the number of sites in each State (in parentheses) from which municipal water samples were drawn included: Alabama (2), Arizona (1), California (1), Florida (1), Georgia (1), Iowa (1), Louisiana (1), Minnesota (1), Missouri (1), Montana (1), New Jersey (1), North Dakota (2), Pennsylvania (1), South Carolina (1), and the District of Columbia (1). Site selection was made in collaboration with EPA’s Office of Pesticide Programs and Office of Water. All selected sites met the following criteria: (1) use of surf ace water as the primary source of water and (2) location in regions of heavy agriculture where known amounts of targeted pesticides of interest were applied. Water treatment method was not a part of the selection criteria. General locations of water collection sites and te sting laboratories are illustrated in Figure 7.Pesticide Data Program—Annual Summary, Calendar Year 2006 14 

# III. Laboratory Operations

♦ Overview
Twelve laboratories (10 State and 2 Federal) performed analyses for PDP. These laboratories are equipped with instrumentation capable of detecting residues at verylow levels. Laboratory staff members receive intensive training and must demonstrate analytical proficiency on an ongoing basis. Program scientists continuously test new technologie s and develop new techniques to improve the levels of detection. Major changes in me thodology are evaluated and their soundness demonstrated and documented in accordance with PDP SOPs. ♦ Fresh and Processed Fruit and Vegetables

PDP participating laborat ories analyzing fruit and vegetables monitored 252 parent pesticides, metabolites, degradates, and/or isomers using Multiresidue Methods (MRMs). Upon arrival at the testing facility, samples are visually examined for acceptability and discarded if determined to be inedible (decayed, extensively bruised, or spoiled). Accepted samples are prepared emulating the pr actices of the average consumer to more closely represent actual exposure to residues. Fresh samples are prepared as follows: (1) bananas are peeled; (2) broccoli is visually examined, any damaged portion or wilted florets removed, any inedible Figure 7. Location of Drinking Water Collection Sites at Community Water Systems, 2006. A total of 17 water treatment fac ilities in the U.S. were sampled in paired units (coordinated treated and untrea ted samples). Sites represent areas of varied geographical settings but are loca ted in watersheds where pesticides were known to have been heavily applied. 1 1

1 

### Montana

Colorado

Sampled States (# of Sites)

Location of State laboratories that perform sample analysis N e w

Y

o r k



### California P en ns y l v ania



### Florida 1 

### Louisiana

1 2 

### North Dakota

A l ab am a

2 

### Arizona
1



### Georgia 1 

### Iowa

1 

### Minnesota
1



### Missouri

1 1



### New Jersey 1



### South Carolina Washington, D.C. (1)Pesticide Data Program—Annual Summary, Calendar Year 2006 15 

## portion of stem removed, and washed; (3) cranberries are washed; (4) carrots are washed, gently scrubbed, and stem cap portions removed; (5) cauliflower is visually examined, any damaged portions and wrapper leaves discarded, and washed; (6) eggplant, summer squash, and winter squa sh are washed and end pieces are removed; (7) grapefruit are peeled and excess white membrane is removed; (8) greens are visually examined, any damaged/ wilted and wrapper leaves discarded, and washed; (9) peaches and plums are washed, the stems and leaves removed, and pitted; (10) spinach is visually ex amined, damaged/wilted leaves and woody stems removed, and washed; and (11) watermelon is quartered and the rind removed; for large watermelon, alternate quarters of each fruit are homogenized (rind removed). Processed samples are prepared as follows: (1) applesauce, frozen peas, and frozen potatoes are homogenized with their entire contents, including any liquid present; and (2) fresh and reconstituted orange juice samples are mixed until homogeneous. In the case of dried plums and raisins, samples are rehydrated to facilitate commodity extraction.Laboratories are permitted to refrigerate incoming fresh fruit and vegetable samples of the same commodity for up to 72 hours to allow for different sample arrival times from collection sites. Frozen and canned commodities may be held in storage (freezer or shelf) until the entire sample set is ready for analysis.
Samples are homogenized using choppers and/or blenders and are separated into analytical portions (aliquots) for analysis. If testing cannot be performed immediately, the entire analytical set is frozen at -40°C or lower, according to PDP’s Quality Assurance/Quality Control (QA/ QC) requirements. Surplus aliquots not used for the initial testing are retained frozen in the event that replication of analys is or verification testing is required.
For analysis of fruit and vegetables, residues are extracted using organic solvents followed by various cleanup procedures such as Solid Phase Extraction (SPE). The California, Florida(Winter Haven), Texas, and Washington laboratories used modifications of the MRM developed by the California Department of Foodand Agriculture. The Florida Tallahassee laboratory used an acetonitrile extraction followed by an aminopropyl SPE cleanup procedure. The Michigan laboratory used a modified version of the QuEChERS method, developed and published in July 2003 by USDA’s Agricultural Research Service. The New York laboratory used a method based on the Agriculture and Agri-Food Canada SPE method with some modifications based on the Luke procedure. The Ohio laboratory usedvariations and combinations of the FDA Luke I [Section 302 of Pesticide Analytical Manual (PAM) I] and Luke II [FDA Laboratory Information Bulletin (LIB) 3896] extraction procedures. All MRMs are determined, prior to use and through appropriate method validation procedures, to produce equivalent data for PDP analytical purposes.
Gas chromatography (GC) and liquid chromatography (LC), coupled w ith selective detectors and mass spectrometry (MS) systems, are used for the initial identification and quantitation of pesticides. Laboratories are increasing their use of GC- and LC-MS system s and are specifically focusing on LC-MS/MS techniques to broaden the scope of testing and to keep pace with emerging analyte chemistries. All residuesinitially identified must be verified. Confirmation is accomplished by MS, alternate detection systems, or a lternate chromatographic behavior. Verification is considered crucial due to the complexity of commodity matrices and the low concentrations of detected residues. The verification process provides an extra measure of confidence in the identification of the analyte and its concentration.

♦ Peanut Butter

The USDA GIPSA laboratory in Kansas City, Missouri, analyzed peanut butter samples for 77 parent pesticides, metabolites, degradates, and/ or isomers. Upon arrival at the testing facility,Pesticide Data Program—Annual Summary, Calendar Year 2006 16

## samples were visually examined for acceptability and discarded if leaking, spoiled, or otherwise inedible. Peanut butter samples were refrigerated at 10° C, or lower, until time of analysis. Surplus sample aliquots, not used for the initial testing, were retained refrigerated in the event that replicat ion of analysis or verification testing was required. Extraction of peanut butter samples was accomplished using solvent extraction and SPE cleanup coupled with GC-MS and LC-MS/MS detection.

♦ Wheat
The USDA GIPSA laboratory in Kansas City, Missouri, analyzed wheat samples for 71 parent pesticides, metabolites, and/or isomers. Upon arrival at the testing facility, samples werevisually examined for acceptability and discarded if moldy or infe sted. Wheat samples were refrigerated at 7° C prior to grinding and then stored frozen at -80°C until time of analysis. Surplus sample aliquots, not used for the initial testing, were re tained at -80°C in the event that replication of analysis or verification testing was required. Extraction of wheatsamples was accomplished using solvent extraction and SPE cleanup coupled with GC-MS detection.

♦ Poultry
The AMS NSL in Gastonia, North Carolina, tested poultry meat (thigh/breast) samplesfor 96 parent pesticides, metabolites, degradates, and/or isomers. For both poultry breast and thigh tissues, approximately 1-pound samples were collected for shipment to the testing facility. Upon arrival at the testing facility, samples were visually examined for acceptability and discarded if warm to the touch, spoiled, or leaking. If not homogenized immediately after arrival, samples were frozen at 0°C or lower until homogenized. The tissue samples were homogenized by grinding it with dry ice in a large, high-speed food processor. The sample homogenates were placed into sample cups (approximately 60 grams per cup) and allowed to sublime at -20°C overnight before storing at -70°C prior to analysis. A 20- gram aliquot was weighed for each thigh or breast sample followed by organic solvent extraction and sample cleanup using ultra-lowrefrigeration (-70°C), centrifugation, and dispersive SPE. For each poultry breast or thigh sample, two extra sample homogenate cups, not used for the initial testing, were retained frozen in the event that replication of analysis or verification testing was required. Surplus poultry tissue homogenate remaining after the three sample cups were filled was thendiscarded. Samples were analyzed using GCMS and LC-MS/MS.

♦ Bottled Water

The Minnesota laborato ry analyzed bottled water for 84 parent pesticides, metabolites, and isomers. These compounds were determined to be of interest to EPA based on data needs for risk assessment as re quired under FQPA. Upon arrival at the testing laboratory, samples were visually examined for acceptability (within labeled expiration date, no leakage). Samples were refrigerated until time of analysis. One liter of the sample provided was extracted for compounds amenable to GC-MS analysis and one for chloroacetanilide compounds to be analyzed via LC-MS/MS.

♦ Drinking Water
The Colorado, Montana, and New York laboratories analyzed drinki ng water for 242 parentpesticides, metabolites, degradates, and isomers. These compounds were determined to be of interest to EPA. Paired samples of the raw intake water (untreated) and disinfected finished drinking water (treated) were collected for analysis. Treated water samples were collected after the untreated samples at a time interval consistent with the hydraulic residence. Hydraulic residence is the average time fromentry into the treatment facility until distribution as treated water. Each sample consisted of three 1-liter amber glass bottles collected at the water treatment facilit y. Upon arrival at the testing laboratory, samples were visually examined for acceptability and discarded if warm to the touch or leaking. Samples werePesticide Data Program—Annual Summary, Calendar Year 2006 17 

## refrigerated until time of analysis and extracted within 96 hours of collection. A 1-liter bottle was extracted for compounds amenable to GC analysis and another one for compounds amenable to LC analysis. The remaining bottle was held in reserve or extracted for specialty compounds requiring separate extraction/analytical procedures [e.g., ethane sulfonic acid (ESA) and oxanilic acid (OA) an alogs of alachlor, acetochlor, and metolachlor]. The extraction methods used were based on SPE methods developed by the U.S. Geological Survey (USGS) and were independently validated by each testing laboratory. Samples were analyzed using MS detection (sin gle and tandem GC and LC technologies) or selective detectors.

♦ Quality Assurance Program

The primary objectives of the QA/QC program are to ensure the reliabi lity of PDP data and the performance equivalency of the participating laboratories. Directi on for the PDP QA program is provided through SOPs based on EPA Good Laboratory Practices (GLPs). Written SOPs provide uniform admini strative, sampling, andlaboratory procedures. SOPs are revised annually to accommodate changes in the program. As laboratories continue to move toward accreditation to ISO 17025, program SOPs are being modified to align with these ISO requirements. Prior to submission to PDP, data are reviewed by each Quality Assurance Unit (QAU) for completeness and adherence to PDP requirements.

Laboratory Technical Advisory Group and Quality Assurance Officers: A TechnicalAdvisory Group comprised of laboratory Technical Program Managers (TPMs) and Quality Assurance Officers (QAOs) is responsible forannually reviewing program SOPs and addressing QA issues. For day-to-day QA oversight, PDP relies on the QAU at each participating facility. As required under EPA GLPs, the QAU operates independently from the laboratory staff and is responsible for performing quarterlyinternal program audits. Preliminary data review procedures are performed on-site by each laboratory’s QAU. Final review procedures are performed by MPO staff who are responsiblefor collating and reviewing data for conformance with SOPs.

Method Performance Requirements: Laboratories are required to determine and verify thelimits of detection (LODs) and limits of quantitation (LOQs) for each pesticide/commoditypair. LODs depend on matrix, analyte, and detector used. LODs for each pesticide/commodity pair are shown in the applicable crop results appendix. Additional method performance/ validation requirements include modules for consistent instrument response (linearity), method range, and precision and accuracy.

Confirmation: Verification by MS or a suitable alternate detection system is required for all preliminary results. Verified residue amounts greater than or equal to LOD and below LOQ are reported as below quantifiable level (BQL). BQLs are assigned values at one-half the LOQ, and are used along with values greater than or equal to LOQ and non-dete cts in dietary risk assessments, when appropriate.

Routine Quality Control Procedures: PDP procedures for QC are intended to assess method and analyst performance during sample preparation, extracti on, clean-up, and, where applicable, derivatizatio n. To maximize sample output and decrease the QC/sample ratio, samples are analyzed in analytical sets that include the test samples and the following components:
Reagent Blank - For analysis of fruit and vegetables, peanut butte r, wheat, and poultry, an amount of distilled wate r, equivalent to the natural moisture content of the commodity, is run through the entire analytical process to confirm glassware cleanliness and system integrity.

Matrix Blank - A previous ly analyzed sample of the same commodity, which contains either very low concentrations of known residues or no detectable residues, is divided into two portions.Pesticide Data Program—Annual Summary, Calendar Year 2006 18

## The first portion is used to determine background information on naturally occurring chemicals and the second is used to prepare a matrix spike.

Matrix Spike(s) - Prior to extraction, a portion of matrix blank is spiked with marker pesticides to determine the precision and accuracy of the analyst and instrumentperformance. Marker pesticides are compounds selected from different pesticideclasses (e.g., organochlorines, organophosphates, carbamates, conazoles, imidazolinones, neonicotinyls, phenoxy acid herbicides, pyrethroids, str obilurins, triazines),which have physical and chemical characteristics similar to those in the class they represent. Marker pesticides are used tomonitor recovery instead of spiking all pesticides. This use of marker pesticides optimizes the resources required to analyze the thousands of analyte/matrix combinations in the program while still allowing evaluation of daily recovery patterns. In addition, each laboratory must perform matrix spikes throughout the year for each analyte/crop combination reported by their laboratory.
During 2006, PDP laboratories quantitated a total of 51,605 matrix sp ikes, with an overall mean recovery of 93 percent and an overall percent coefficient of variation (% C.V.) of 27 percent. The % C.V. is calculated as the standard deviation divided by the mean.

Process Control Spike - A compound with physical and chemical characteristics similar to those of the pesticides being tested is used to evaluate the analytical process on asample-by-sample basis. Each of the analytical set components, except the reagent and matrix blanks, is spiked with process controls. During 2006, PDP laboratories quantitated a total of 50,010 process controls on 13,658 samples, with an overall mean recovery of 96 percent and an overall C.V. of 21 percent. Of thes e process controls, 459 (0.92 percent) were rerun due to initial failure to meet PDP recovery criteria. These rerun values are not included in these statistics.

Proficiency Testing: All facilities are required to participate in PDP’s Proficiency Testing (PT) program. For laboratories testing fresh and processed fruit and vegetables, grains, dairy products, and meats, multiresidue test samples containing pesticides of known quantities are periodically issued and analyzed under the same conditions as routine samples. The resulting data are used to determine performance equivalency among the testing laborato ries and to evaluate individual laboratory pe rformance. During 2006, PDP laboratories received 5 multiresidue fruit and vegetable PT sets consisting of 15 samples, 1 peanut butter set consisting of 3 samples, and 1 poultry set consisting of 3 samples. For fruit and vegetable multiresidue screening, the 15 sampleswere comprised of 5 commodities and were fortified with 51 compounds at levels generally 1 to10 times the LOQ. Five compounds were repeated twice and five compounds were repeated once. Reported results for fruit and vegetable samples yielded an overall mean recovery of 93 percent and an overall C. V. of 21 percent. For peanut butter and poultry, 2 samples were fortified with a total of 11 compounds for each commodity.
Additionally, PDP laboratories participated in the international AOAC ® 

## PT program. During 2006, PDP laboratories participat ed in three test rounds, one for cauliflower, one for grapefruit, and one for peaches. Each sample set was fortified with nine pesticides. Laboratories were evaluated based on z-scores for reported compounds, as well as any reported false negatives or false positives. Laboratories were not held responsible for reporting compounds not included in theirroutine screening method. Overall, PDP laboratories performed as well or better than other participating laboratories.
For water, two proficiency sample sets were analyzed during 2006. For th e first set, replicate samples from a site whose samples historically contained multiple pesticides were sent to each ofPesticide Data Program—Annual Summary, Calendar Year 2006 19 

## the water testing laboratories and reported results compared. For the other drinking water set, a commercial vendor supplied PT solutions to the testing laboratories. Solution profiles were based on common laboratory analytical profiles and detection limits. Test solutions were used for spiking, rather than distribution of spiked samples, due to stability concerns. For each PT set, the vendor supplie d the laboratory’s QAUwith a custom solution that was diluted according to program protocols by the on-site QAU and fortified into 1-liter of replicate sample received by each laboratory. The spiked samples were then presented to the staff members of each respective laboratory for analysis.

On-site Reviews: MPO staff perform on-site visits to determine compliance with PDP SOPs. Improvements in sampling, chain-of-custody, laboratory, recordkeeping, and electronic data transmission procedures are made as a result of on-site reviews.


# IV. Database Management

PDP maintains an electronic database at the MPO in Manassas, Virginia, that serves as a central data repository. The data captured and stored in the PDP database include samplecollection and product information, residue findings, and process control recoveries for each sample analyzed, in addition to QA/QC fortified recoveries for each set of samples. Each calendar-year survey is stored in a separate database structure, whic h allows easier administration and data reporting. The PDP data path is illustrated in Figure 8.

♦ Electronic Data Path

PDP utilizes the Remote Data Entry (RDE)system, which is a customized software application that allows particip ating State and Federallaboratories to enter and transmit data electronically. The RDE system is centralized with all user interface software and database files residing in Washington, D.C. The laboratory users need only a Web browser to interface with the RDE system. Access is controlled through separate user login/password accounts and user access rights for the various system functions based on position requirements. The RDE system utilizes Secure Sockets Layer (SSL) technology to encrypt all data passed between users’ computers and the central Web server.

A separate Windows ® 

## -based system allows sample collectors to ca pture the standardized Sample Information Form (SIF) electronically on handheld or laptop computers. The e-SIF system generates formatted text files containing sample information that are e-mailed to PDPheadquarters and then imported into the Webbased RDE system.

The RDE data entry screens have extensive editing functions and cro ss-checks built into the software to ensure that valid values are entered for all critical data elements. This task is made easier by the practice of capturing and storing standardized codes for all critical alphanumeric data elements rather than their complete names, meanings, or descriptions. This coding scheme allows for faster and more accurate data entry, saves disk storage space, and allows the user to perform ad-hoc queries (data searches) on the database easily. The data entry screens also perform automatic edits on numeric fields, dates, and other character fields to ensure that entries are within prescribed boundaries.

At PDP headquarters, the RDE system allows staff chemists to review the data on-line and then to mark the data as ready-for-upload to the central PDP database. A separate upload application converts and passes the data to the PDP database which is presently maintained using Microsoft ® 

## Access in a Windows ® 

## operating environment. Access to the central PDP database is limited to PDP staff personnel only and is controlled through passwordprotection and user access rights. System backups are performed each night and back-up tapes are sent to off-site storage once a week.Pesticide Data Program—Annual Summary, Calendar Year 2006 20 

## Figure 8. PDP Data Pathway. An illustration of PDP data path from sample collection through laboratory analysis and reporting. - 10 State labs + 2 USDA labs - Fruit and vegetable samples prepared for consumption - Detect residues at low levels - Pesticide residue data generated

- Multi-tiered QA data review process 

## Laboratory Analysis Sample Collection

- Collection in 10 States - Samples taken close to point of consumption - Standardized Sample Information Form - Data entry on handheld/laptop computers

- Web-based data entry software - Import data from other systems - Access controlled by user login - Extensive data cross-checks 

## Laboratory Remote Data Entry (RDE) Data Review at HQ

- Chemists review data on-screen - Upload data to central database



## Year-end Review

- Data reconciliation Internet

Internet

- Standard & adhoc reporting - Annual Summary - Custom data sets 

## Data ReportingPesticide Data Program—Annual Summary, Calendar Year 2006 21 

## ♦ Data Reporting

The PDP staff frequently receives requests for data from Government agencies and interested outside parties. Ad-hoc queries and custom reports are generated to fill such requests. An electronic library of data queries is maintained to generate standardized data summaries, including the data tables, charts, and appendices in this annual summary. Subsets of the PDP calendar year databases are made available for download from the PDP Web site. The data files on the Web site are fixed-length text files that contain a portion of the sampling data, all of the reported residue findings, and reference lists that can be used to interpret the standardized codes used in the PDP data. The data files can be imported into defined database structures and manipulated with the use of common database management software packages.


# V. Sample Results and Discussion

♦ Sample Results

In 2006, PDP conducted surveys on a variety of foods including fresh and processed fruit and vegetables, peanut butte r, wheat grain, poultry, bottled water, and treate d and untreated drinkingwater. Of the 13,658 samples that were collected and analyzed, 9,818 were fruit and vegetable commodities, 739 were peanut butter samples, 687 were wheat grain samples, 1,310 were paired breast and thigh poultry samples, 367 were bottled water samples, and 737 were drinking water samples.

Excluding drinking water samples, which were all from U.S. sources, approximately 80 percent of all samples were produced in the U.S., 18 percent were imports, 1 percent was of mixed origin, and 1 percent was of unknown origin. Appendix H shows the di stribution of sample origin by State or country. Of the domestic samples, approximately 39 percent (3,269 of 8,322) were grown, packed, and/or distributed in or from California. Ap proximately 32 percent (178 of 557) of the orange juice samples were of mixed national origin (i.e., the juice was comprised of orange concentrates from more than one country). Appendix I includes a comparison of residues for selected commodities with a significant import component.

Table 3 gives an overvie w of the number of residue detections for fresh and processed fruit and vegetables, peanut butter, wheat grain, poultry, and bottled water products determined during 2006. Overall, 64 percent of fresh fruit and vegetables and 59 percent of processed fruit and vegetables showed detectable residues. Residues were detected in 30 percent of the peanut butter samples, 69 percent of the wheat grain samples, 7 percent of the poultry breast and thigh samples, and 19 percent of the bottled water samples.

Appendix B tabulates the distribution of residues in fruit and vegetables for the complete 2006 data set. Information in cluded in this appendix are: number of samples analyzed for a particular compound; number and percent of samples with detections; range of c oncentrations detected; tolerance violations; range of analytical LODs; EPA tolerance levels or FDA action levels; and corresponding Codex Alimentarius MaximumResidue Limits (MRLs) and/or Extraneous Maximum Residue Limits (EMRLs), when applicable. Appendices C, D, E, F and G provide the distribution of residues fo r peanut butter, wheat grain, poultry, bottled wa ter, and treated and untreated drinking water respectively. The individual sample data can be downloaded from the PDP Web site or obtained by contacting MPO.

Food monitoring data, together with dietary consumption surveys, are used by EPA to estimate dietary exposure to pesticides to ensure the safety of existing pesticide uses. EPA uses all results reported by PDP, including sample results reported as below the LOD and thoseabove the tolerance. PDP laboratories are required to establish LODs and report anyinstrumental response below the LOD as a nondetect. LODs are established experimentally for each pesticide/commodity pair and are reported with each data set. The number of non-detectsPesticide Data Program—Annual Summary, Calendar Year 2006 22 

## Table 3. Number of Samples Analyzed and Su mmary of Residues Detected by Commodity. The distinction between the number of pesticides and different residues is made to differentiate a parent compound and its metabolite(s). A parent compound and its metabolites are reported as a single pesticide detection rather than as separate residue detections. TOTAL PROCESSED Number of Samples Analyzed Samples with Residues Detected Percent of Samples with Detections Different Pesticides Detected Different Residues Detected Total Residue Detections

Bananas 742 563 76 15 16 828 Broccoli 185 163 88 17 19 313 Carrots 744 623 84 21 25 1,462 Cauliflower 558 448 80 14 16 509 Cranberries 316 219 69 12 13 378 Eggplant 740 191 26 16 19 339 Grapefruit 743 345 46 9 11 512 Greens, Collard 86 63 73 21 24 158 Greens, Kale 98 69 70 29 33 249 Peaches 90 89 99 33 37 411 Plums 515 357 69 19 21 597

Summer Squash 186 176 95 23 29 462 Watermelon 550 136 25 25 28 207 Winter Squash 369 169 46 26 29 262 6,433 4,090 64 8,666

Applesauce 744 691 93 26 28 2,121

Raisins 372 233 63 28 29 604 Sweet Peas, Frozen 744 114 15 12 12 138 3,385 2,011 59 4,438 Spinach 511 479 94 48 58 1,979

Potatoes, Frozen 744 653 88 22 26 1,148 Plums, Dried (Prunes) 224 23 10 11 12 30 Orange Juice 557 297 53 8 9 397

Number of Samples Analyzed = 9,818 Number of Samples with Residues Detected = 6,101 Percent with Residue Detections = 62.1%

Peanut Butter 739 223 30 6 8 243

Number of Samples Analyzed = 12,921 Number of Samples with Residues Detected = 6,963 Percent with Residue Detections = 53.9% Fresh Fruit and Vegetables:

Processed Fruit and Vegetables: TOTAL FRESH

Grain Product: Processed Nut Product: 

### Fruit and Vegetables Totals:

All Commodities (excludes 737 drinking water samples):

Wheat 687 475 69 15 15 669 Total Number of Different Pesticides Detected = 113 Total Number of Different Residues Detected = 125 Total Number of Residue Detections = 13,104

Total Number of Different Pesticides Detected = 165 Total Number of Different Residues Detected = 178 Total Number of Residue Detections = 14,319 Meat Tissues:

Poultry, Breast 655 40 6 7 7 49 Poultry, Thigh 655 54 8 7 8 76 Total Poultry 1,310 94 7 125

Water Product:

Bottled Water 367 70 19 6 12 178Pesticide Data Program—Annual Summary, Calendar Year 2006 23 

## can be used in conjunc tion with percent crop treated data to determ ine what proportion of these values may be count ed as zero towards thedietary exposure. As shown in Table 3, 46 percent of the samples (excluding treated and untreated drinking water samples) were reported as having no residue detec tions (i.e., results were below the established LOD). For samples containing residues, the vast majority of the detections were well below established tolerances and/or action levels.

♦ Fresh vs. Processed
The 2006 residue data, as in past years, show that residue profiles for fresh products are significantly different th an for processed products. An increase in residue levels (concentration) or reduction in residue levels is likely a direct result of proc essing effects such as cooking, pasteurization, and other processing steps. A comparison of residues for selected fresh and processed products is shown in Table 4.
For fresh apples and/or applesauce, detection of pesticides in greater than 10 percent of thesamples included acetamiprid, carbaryl, carbendazim (a metabolite of benomyl and thiophanate methyl), diphenylamine, imidacloprid, phosmet,thiabendazole, and thiacloprid. All eight compounds were detected in both fresh apples andapplesauce. Acetamiprid, diphenylamine, imidacloprid, phosmet, and thiabendazole were detected more frequently in fresh apples than in applesauce. In contrast, the percent of samples with detections was higher for carbaryl, carbendazim and thiacloprid for applesauce than for fresh apples. For example, diphenylamine was present in 82.9 percent of fresh apples and 30.2 percent of the applesauce samples, whereas carbendazim was detected in 82.6 percent of the applesauce and 20.8 percent of fresh apples.
While raisins are primarily a domestic product, grapes are approximately half import and half domestic product. The majority of residues detected in greater than 10 percent of the samples occurred for grapes. These compoundsinclude captan, chlorpyrifos, cyprodinil, fludioxonil, imidacloprid, iprodione, and myclobutanil. The only residue detected in greater than 10 percent of the samples for raisins was the insecticide propargite; propargite was not detected in any of the fresh grape samples. Chlorpyrifos and fludioxonil were detected in fresh plums but not dried. Iprodione was found in 36.3 percent of fresh plums and 0.4 percent of dried plums. Phosmet was detected in 15.5 percent of fresh plums and 1.8 percent of dried plums.

♦ Import vs. Domestic Residue Comparisons
Information about the origin of each PDP sample is recorded when the sample is collected. Figure 3 illustrates the portion of the domestic and import component for each PDP fruit and vegetable commodity in 2006. The data generated by PDP reflect pesticide residues in foods available to the U.S. consumer, including both domestic and imported products. Many commodities are almost entirely of domestic origin such as grapefruit, greens, and raisins. However, some fresh commodities, such as eggplant, plums, and watermelon are from domestic growers part of the year and are imported during the remaining months, as illustrated in Figure 4. Comparisons of selected residues detected in im ported versus domestic winter squash and plums can be found in Appendix I.
Overall, there were no significant differences between the number of detections in domestic vs. winter squash from Mexico; however, the residue profiles do differ. Overall, samples of plums from Chile showed a higher percent of detections than the domestic samples. These sample sets were selected to compare data where residues are present in greater than 10 percent of the commodity and allow for the comparison of individual residues. These data also showed that the residue profiles for domestic and imported crops were significantly different.
The winter squash data in Appendix I indicate that in 2005-2006, residues were detected inPesticide Data Program—Annual Summary, Calendar Year 2006 24 

## 44.8 percent of the domestic samples and 41.4 percent of the samples from Mexico. Dieldrin was detected in 10.4 percent of the domestic samples and in 0.2 percent of the samples from Mexico. Endosulfan sulfate was detected more frequently in the winter squash samples from Mexico (26.3%) than do mestic winter squash samples (14.3%). For plums, 98.6 percent of the samples from Chile and 55.2 percent of the domestic samples had residues detected in 2005-2006. Chlorpyrifos and iprodione were detected more often in the imported plum samples than the domestic plum samples. For example, iprodione residues were detected in 94.7 percent of the plum samples from Chile Table 4. Selected Residue Comparis ons for Fresh and Processed Commodities. The percentage of samples with detections and the range of reporte d values for selected pestic ides recovered from fresh vs. processed apples, grapes, and plums are shown. Commodity/residue pairs w ere selected based on the following criteria: data availability for fresh and processed product within the same sampling timeframe; greater than 10% detection rate for a resi due in either the fresh or processed commodity; and number of samples analyzed sufficie nt to ensure adequate representation. Pesticide % of Samples

with Detects Minimum Value Detected, ppm Maximum Value Detected, ppm % of Samples

with Detects Minimum Value Detected, ppm Maximum Value Detected, ppm Acetamiprid 70.0 0.001 0.13 51.5 0.001 0.031 Carbaryl 7.1 0.0005 0.32 22.2 0.0005 0.23

Carbendazim 20.8 0.0002 0.16 82.6 0.0005 0.04 Diphenylamine 82.9 0.0048 2.9 30.2 0.0048 0.16 Imidacloprid 26.6 0.0002 0.015 17.5 0.0002 0.0027

Phosmet 19.4 0.008 0.28 1.7 0.008 0.008

Thiabendazole 88.0 0.0002 7.0 38.8 0.0002 1.2 Thiacloprid 3.0 0.003 0.018 12.8 0.0007 0.0062 

### APPLES -- Fresh (2005) APPLE SAUCE (2006)

Captan 16.8 0.0125 1.2 0.5 0.040 0.040 Chlorpyrifos 12.4 0.0063 0.19 0.8 0.007 0.022 Cyprodinil 26.8 0.0079 1.4 1.9 0.027 0.41
Fludioxonil 13.7 0.011 0.5 0.3 0.13 0.13 Imidacloprid 18.1 0.01 0.47 0.9 0.066 0.066 Iprodione 16.1 0.025 1.6 0.8 0.025 1.3 Myclobutanil 15.8 0.033 0.35 1.3 0.053 0.067 Propargite 0 0 0 31.5 0.0058 1.2 

### GRAPES -- Fresh (2005) RAISINS (2006)

Chlorpyrifos 17.1 0.005 0.18 0 0 0
Fludioxonil 18.8 0.18 1.8 0 0 0

Phosmet 15.5 0.005 0.18 1.8 0.005 0.16 Iprodione 36.3 0.065 6.9 0.4 0.36 0.36 

### PLUMS -- Fresh (2006) PLUMS -- Dried (2006)Pesticide Data Program—Annual Summary, Calendar Year 2006 25 

## compared to 2.1 percent of the domestic samples. Similarly, chlorpyrifos was detected in a higher percentage of samples from Chile (26.3%) in relation to domestic samples (3.0%). Conversely, fludioxonil and phosmet were detected more often in the domestic plum samples than the plum samples from Chile. Fludioxonil was not detected in any of the 419 plum samples from Chile, whereas it was detected in 32.5 percent of the domestic plum samples. Phosmet was found in 28.1 percent of the domestic samples and in 1.2 percent of the samples from Chile.

♦ National Estimates

National estimates for pesticide/commodity pairs with detections in at least 10 percent of samples tested are shown in Appendix J. In most cases for each pair, the levels of detected residues are a small fraction of the tolerance level. A range of values for the average sample residue concentration (mean) for each pair is provided. The lower value for the range is determined by treating a sample without detectable residues as if it had a residue concentration equal to ze ro. The upper value is determined by treating such a sample as if it had a residue concentration equal to the LOD. Calculations for the 50th, 75th, and 90th percentiles for each of the selected pairs are shown. The ratio of the 90th percentile to the tolerance, as a normalization factor is also provided. Percent detections and percentiles forbananas, carrots, cauliflower, cranberries, eggplant, orange juice, plums, spinach, and winter squash were weighted to reflect monthlyvariations in marketing. No weighting adjustments were made for applesauce, grapefruit, peanut butter, frozen potatoes, raisins, frozen sweet peas, or wheat grain.

Appendix K displays the estimated distributions of 12 representative pes ticide/commodity pairs. These graphs depict that the overwhelming majority of pesticide testing results and the respective means (average values) are at low concentrations. The range of values, the median at the 50th percentile, and the range in percentile representing the lowe r and upper bound for the sample mean are shown on each chart. The pesticide/commodity pairs included in Appendix K are acetamiprid/applesauce, imazalil/bananas,pyraclostrobin/carrots, trifuralin/carrots, imidacloprid/cauliflower, az oxystrobin/cranberries,fludioxonil/plums, chlorpropham/frozen potatoes, imidacloprid/frozen potatoes, boscalid/ raisins, dimethoate/froze n sweet peas, and chlorpyrifos methyl/wheat. In some cases, there is convergence of the mean upper and lower bound into a single line due to the insignificant differences between them (e.g., imidacloprid/ cauliflower).

♦ Postharvest Applications

Pesticides can be applied before and after harvest depending on the crop and approved label use. PDP data capture both preharvest and postharvest uses because samples are collected at points when all pest icide applications have already occurred. Pesticid es applied postharvest are used primarily as fungicides (e.g., imazalil, o-phenylphenol, and thiabendazole), but some insecticides (e.g., pipe ronyl butoxide) and sprouting inhibitors (e.g., chlorpropham) are important postharvest crop treatments. Some detections reported in Appendix B most likely reflect postharvest app lications to the raw agricultural commodity.

♦ Environmental Contaminants

DDT, DDD, and DDE

A total of 9,455 fruit and vegetable (Appendix B), 739 peanut butter (Appendix C), 687 wheat grain (Appendix D), 1,310 poultry samples (655 paired breast and thig h samples, Appendix E), and 235 treated (finishe d) drinking water and 236 untreated water samples (Appendix G) were screened for DDE p,p’, a metabolite of DDT. Use of DDT has been prohibited in the U.S. since 1972; however, due to its persistence in the environment, residues of the DDE p,p’ metabolite were detected in 4.2 percent (398 detections in 9,455 sample s) of the fruit and vegetable samples tested . Residues of DDE p,p’Pesticide Data Program—Annual Summary, Calendar Year 2006 26 

## were found in broccoli (1.1%), carrots (27.5%), kale greens (32.4%), peaches (1.1%), spinach (34.2%), summer squash (0.5%), watermelon (0.2%), and winter squash (0.5%). DDE p,p’ residues were also detected in peanut butter and poultry. Other DDT metabolites including DDD o,p’ (1,637 samples) and DDD p,p’ (9,440 samples) were analyzed in fruit and vegetables. There was only one detection for DDD o,p’ at 0.002 ppm on spinach and one detection of DDD p,p’ at 0.016 ppm on carrots. Residues of DDT o,p’ were detected only in spinach (5.2%). Resi dues of DDT p,p’ were detected in carrots (0.5 %), kale greens (32.4%), spinach (8.6%), and summer squash (1.9%). All detections of DDT and its metabolites were well below the established action levels for all commodities.

OTHER EXTRANEOUS PESTICIDES

In 1974, all aldrin and dieldrin uses were canceled in the U.S., an d in 1978, all heptachlor uses were canceled. In 1986, chlordane uses, except termiticide uses, were canceled. Despite these cancellations and due to their persistence in the environment, residues of dieldrin were detected in carrots, frozen potatoes, spinach, summer squash, and winter squash in 2006. Dieldrin was found in 0.1 percent of carrot, 0.4 percent of frozen potato, 0.2 percent of spinach, 9.1 percent of summer squash, and 1.6 percent of winter squash samples. Heptachlor epoxide, a metabolite of heptachlor, was detected in summer squash (1.6%) and winter squash (0.5%). The cis-chlordane isomer was detected in carrots (0.9%), spinach (0.4%), summer squash (4.3%), and winter squash (1.4%). Residues of trans-chlordane were found in spinach (0.2%), summer squash (1.6%), and winter squash (0.3%). All detections were well below the established action levels.

♦ Multiple Pesticide Residue Detections

By virtue of the MRMs employed, PDP provides novel data that can be used by EPA in evaluating exposure to multiple residues from the same commodity. The data are crucial for assessments which consider cumulative exposure to pesticides which are determined to have common mechanisms of t oxicity. The distribution of multiple pesticides occurring in samples tested during 2006 is presented in Appendix L.

These data indicate that 46 percent of all samples tested excluding treate d and untreated drinking water contained no detectable pesticides, 28 percent contained 1 pesticide, and 26 percent contained more than 1 pesticide. Parent compounds and their metabolites are combined to report the number of “pesticides” rather than the number of “residues,” as was reported in summaries prior to 2003. For example, a sample with positive detections for Endosulfan I, II, and sulfate would have been counted as three residues in the 2002 Appe ndix L. That sample would be counted as just one pesticide detected in Appendix L of this Summary.

Most multiple residue detections result from the application of more than one pesticide on a crop during a growing season; however, a number of other factors could contribute to multiple detections. Pesticide spray drift, residue transfer through crop rotation and at packing facilities, and/or presence of pers istent environmental contaminants could all contribute to residue detections.

It should be noted that, in most cases, samples analyzed by PDP are composites of 3 to 5 pounds of commodity from the same lot. Therefore, the estimated concentrations for multiple residue detections in these composite sample results might or might not reflect the number of pesticides per concentration in a single serving item of a commodity.

♦ Tolerance Violations

A tolerance is defined under Sectio n 408 of the Federal Food, Drug, and Cosmetic Act as the maximum quantity of a pesticide residue allowable on a raw agricultural commodity. Tolerances are also applicable to processed foods. A tolerance violation occurs when aPesticide Data Program—Annual Summary, Calendar Year 2006 27 

## residue is found that exceeds the tolerance level or when a residue is found for which there is no established tolerance. With the exception of meat, poultry, and egg products, for which USDA is responsible, FDA enforces tolerances for all imported and domestic foods that move through interstate commerce. Although PDP is not an enforcement program, samples found to contain residues exceeding the tolerance and/or residues for which there is no established tolerance are reported to the FDA. This notification is made in accordance with a Memorandum of Understanding between USDA and FDA for the purpose of pinpointing areas where closer surveillance might be needed.

Residues exceeding the established tolerance are noted with an “X” in Appendices B, C, D, and E. Similarly, residues for which a tolerance is not established are noted with a “V.” The “X” and “V” annotations are followed by a number indicating the number of samples reported to FDA.

An established toleran ce can apply to more than one residue because pesticides could break down into more than one metabolite or contain more than one isomer. For example, the tolerance for endosul fan combines residues of endosulfan I, endosulfan II, and endosulfan sulfate; and organophosphate tolerances may combine the parent compound and the sulfone and sulfoxide metabolites. Therefore, where applicable, the violations in Appendix M are combined residues of parent and any isomers and/or metabolites to count the total number of samples with tolerance violations.

In 2006, a total of 412 samples with 442 residues were reported to the FDA as Presumptive Tolerance Violations. Excluding samples for which no tolerances are set (bottled water and drinking water), residues exceeding the tolerance were detected in 0.2 percent of the 12,554 samples tested in 2006 - 31 samples with 1 residue each. Residues with no established tolerance we re found in 3.1 percent of the samples (367 samples with 1 residue each, 17 samples with 2 residues each, 2 samples with 3 residues each, and 1 sample with 4 residues). In most cases, these residues were detected at very low le vels and some residues could have resulted fro m spray drift or crop rotations. The residue levels and commodities are listed in Appendix M.

♦ Bottled Water Results

Bottled water is the second most consumed beverage in the United States. Due to its high consumption, PDP began testing bottled water in 2005 and continued through 2006. Bottled water is regulated as a packaged food product by the FDA and State regulatory agencies. FDA adopted EPA’s Maximum Contaminant Levels (MCLs) for municipal water systems as its Standards of Quality (SOQs) for bottled water. Bottled water meets similar standards as municipal water systems.

Bottled water can come from many sources. Waters sampled by PDP included water which was purified from muni cipal sources, spring water, and melt water from glaciers. It is not required for bottled water to identify a specific source on the label, but bo ttlers must adhere to the FDA Standard of Identity regulations that provide uniform definitions for the following bottled water classifications: bottled, drinking, artesian, ground, distilled, deionized, reverse osmosis, mineral, purified, sparkling, spring, sterile, and well water. Ninety-eight different brands of bottled water were sampled in 2006. These included small local brands of bottled waters as well as nationally sold brands. Some bottling companies may have multiple sources for their water and may list them on the label. Sampling these major brands of bottled water from various locations ac ross the country allows PDP to obtain samples from these multiple sources. Due to its wei ght and shipping cost, most bottled water comes from domestic sources; however, 51 samples were imports from Canada, Croatia, Fiji, France, Iceland, and Italy.Pesticide Data Program—Annual Summary, Calendar Year 2006 28 

## In 2006, PDP analyzed 367 bottled water samples using multiresidue methods to test for 84 pesticides and metabolites. Twelve different residues from 6 different pesticides were detected in 19 percent of the bottled water samples collected. All of the detections were commonly used herbicid es and their metabolites. Appendix F provides a distribution of residues detected in bottled water.

Table 5 shows the residues which were detected in the bottled water sampled by PDP in 2006. The bulk of the residue detections occurred in spring waters while only 3.5 percent of the samples purified from municipal sources contained any detectable residues. Most samples with detectable residues contained only a single pesticide or metabolite. A few of the samples contained multiple residues with a maximum of four detectable pesticides within a given sample. All detec tions were well below established FDA SOQs.

♦ Drinking Water Results

Figure 7 shows the distribution of drinking water sites for the 2006 PDP testing program. Untreated and finished drinking water samples were collected from community water systems in Alabama, Arizona, California, Florida, Georgia, Iowa, Louisiana, Minnesota, Missouri, Montana, New Jersey, North Dakota, Pennsylvania, South Carolina, and the District of Columbia. Each watershed reflects the local topography, watershe d size, geomorphology, soil types, geology, land use, land management practices, crop varieties, pesticides applied, and application methods. Due to the complexities associated with water quality assessments, these data reflect only the unique characteristics of the watersheds from which the samples were obtained.

PDP analyzed 737 water samples from community water systems using MRMs to test for more than 240 pesticides and metabolites. Treatment plants part icipating in the 2006 survey draw from surface water for primary source waters. The data presented here are for the untreated water collected at treatment plant intakes and treated wate r (post-disinfection) collected just prior to distribution to customers. Forty-eight different resi dues were detected in the untreated intake water and 39 in the finished water. Most of the detections were ofcommonly used herbicides and their metabolites. The majority of pesticides included in the PDP testing profiles were not detected and none of the detections in the finished water samples exceeded EPA MCL or Health Advisory (HA) levels.

Bottled Water Source Number of Samples Collected Number of Samples with Residues Number of Residues Detected Origin

Glacier 1 0 0 Domestic Purified Drinking Water 85 3 1-2 Domestic, Canada Spring Water 273 64 1-8 U.S., Canada, France
Unknown Source 8 3 1-4 Domestic


## Table 5. Origin of Bottled Water Samples and Number of Residues Detected. PDP analyzed 367 bottled water samples using multiresidue methods to test for 84 pesticides and metabolites. Twelve different residues from 6 different pesticides were detected in 19 percent of the bottled water samples. Spring water samples from Croatia, Fiji, Iceland, and Italy had no detectible residues. All of the detections were of co mmonly used herbicides and their metabolites. Appendix F provides a distribution of residues detected in bottled water.Pesticide Data Program—Annual Summary, Calendar Year 2006 29 

### 2,4-D - Finished Water - 2,4-D - Raw Intake Water 

### 2500

2000

1500

1000

500Concentration in parts per trillion



### January - June 2006 July - December 2006

January - June 2006 July - December 2006 Atrazine - Finished Water Atrazine - Raw Intake Water 

### 1200

1000

800

600

400

200Concentration in parts per trillion 

## Community Water System Drawing from the Potomac River

Figure 9. Water Treament Effects on Different Pesticides . Results are depicted for two herbicides; 2,4-D and Atrazine at a site drawing from the Potomac River. In the first graph, 2,4-D is effectively removed from a concentration of 2400 parts per trillion in the raw untreate d water to the limit of detection of the instrument analyzing the sample (6 parts per trillion) in the trea ted water. In the second graph, the treatment by the municipal water system shows no effect upon the atrazine concentration. Removal of a pesticide is a function of its physical properties and the type of trea tment being used by the water system.Pesticide Data Program—Annual Summary, Calendar Year 2006 30 

## Appendix G lists the MCL and/or HA values; however, many of the compounds in the PDP testing profiles do not have established regulatory standards. For comparative purposes, EPA Fresh Aquatic Organism (FAO) criteria, which are much lower than human-based MCLs or HA levels, also are given. These criteria are lower than MCL or HA levels due primarily to higher exposure to these compounds because aquatic organisms live all or most of their lives in water. During 2006, no detections exceededestablished FAO levels. Additional information regarding EPA drinking water standards is available at: http://www.epa.gov/safewater/ standard/setting.html

. Water treatment technologi es vary widely and may be based on the local water chemistry, targeted contaminants needing removal, and cost. Appendix G shows the concentration of detected residues in treated and untreated water. In most cases, there were more detections in the untreated water than the treated water. In a few cases, residues detected in the treated water were not detected in the untreated water. The da ta acquired to date indicate that the water treatment process removed matrix interferences, allowing for a more sensitive measurement in the treated water. Depending on the treatment process employed, individual pesticides ar e entirely, partially, or not removed during the treatment process.

Figure 9 shows concentrati ons of the herbicides 2,4-D and atrazine in both the untreated water and the treated (finished) water for the site in the District of Columbia. The figure shows that 2,4- D is effectively removed from the water during the treatment process at this treatment facility. At the same treatment facility, however, no difference in the concentration of atrazine is observed between the untreated water and the treated water. Due to the vast diversity in pesticide properties, no single water treatment method can remove all pesticides. Monitoring data provided to municipal systems can aid facilities in determining the most effective and cost-saving treatment method for their facilities.



# ♦♦♦♦♦

The U.S. Department of Agricult ure (USDA) prohibits discrimination in all its programs and activities on the basis of race, color, national origin, age, disability, and where applicable, sex, marital status, familial st atus, parental status, religion, sexual orientation, genetic information, po litical beliefs, reprisal, or because all or part of an individual’s income is deriv ed from any public assistance program (Not all prohibited bases apply to all programs. ) Persons with disabilities who require alternative means for communication of program information (B raille, large print, audiotape, etc.) should contact USDA’s TARGET Center at (202) 720 -2600 (voice and TDD). To file a complaint of di scrimination, write to US DA, Director, Office of Civil Rights, 1400 Independence Avenue, S. W., Washington, D.C. 20250-9410, or ca ll (800) 795-3272 (voice) or (202) 720- 6382 (TDD). USDA is an equal opportunity provider and employer.

# Appendix A

Commodity History

Appendix A identifie s commodities sampled by the Pesticide Data Program through December 2007. Updates to this list are posted on the PDP Web site at http:// www.ams.usda.gov/pdp

.

## Fresh Commodities

Commodit y Start Date End Date
Apples 1 

## Sep-91 Dec-96 Apples (S-1) Jan-99 Dec-99 Apples (S-2) Jan-99 May-99 Apples Oct-00 Sep-02 Apples Jan-04 Dec-05 Apples (T-1) Jan-03 Dec-03 Asparagus Jan-02 Jun-03 Bananas Sep-91 Sep-95
Bananas Jan-01 Dec-02
Bananas Jan-06 Dec-07 Bananas (TSP) Jul-03 Dec-03
Blueberries 2 

## Jan-07 Ongoing Broccoli Oct-92 Dec-94
Broccoli Jan-01 Dec-02 Broccoli Oct-06 Ongoing Cantaloupe Jul-98 Jun-00 Cantaloupe Oct-03 Sep-05
Carrots 1 

## Oct-92 Sep-96 Carrots Oct-00 Sep-02 Carrots Jan-06 Dec-07 Cauliflower Oct-04 Sep-06 Celery Feb-92 Mar-94 Celery Jan-01 Dec-02 Celery Jan-07 Ongoing
Cherries 3 

## May-00 Aug-01 Cherries May-07 Sep-07 Cranberries Oct-06 Dec-06 Cucumbers Jan-99 Dec-00 Cucumbers Oct-02 Sep-04 Eggplant Jan-05 Dec-06 Eggs (TSP) Jul-03 Dec-03 Grapefruit Aug-91 Dec-93 Grapefruit Jan-05 Dec-06 Grapes 1 

## May-91 Dec-96 Grapes Jan-00 Dec-01 

## COMMODITY HISTORY AS OF DECEMBER 2007

Appendix A. Page 1 of 6

## Commodit y Start Date End Date Grapes (TSP) Jul-03 Dec-03 Grapes Jan-04 Dec-05 Green Beans Feb-92 Dec-95 Green Beans Jan-00 Dec-01 Green Beans Apr-04 Mar-05 Green Beans Jan-07 Ongoing Greens (collard & kale) Oct-06 Ongoing Lettuce May-91 Dec-94 Lettuce Oct-99 Sep-01
Lettuce Jan-04 Dec-05 Mushrooms Oct-01 Sep-03
Nectarines 4 

## Jul-00 Sep-01 Nectarines Jan-07 Ongoing Onions Jan-02 Dec-03 Oranges 1 

## Aug-91 Dec-96 Oranges Jan-00 Dec-01 Oranges Jan-04 Dec-05 Peaches Feb-92 Sep-96 Peaches (S-3) Jan-00 Sep-00
Peaches 5 

## Jan-01 Sep-02 Peaches Oct-06 Ongoing Peaches (T-1) May-03 Sep-03
Pears Jan-97 Jun-99 Pears (S-1) Jul-98 Jun-99 Pears Oct-03 Sep-05 Pineapples Jul-00 Jun-02
Plums 6 

## Jan-05 Dec-06 Potatoes May-91 Dec-95 Potatoes (S-4) Dec-96 Dec-97
Potatoes Jul-00 Jun-02 Spinach 1 

## Jan-95 Sep-97 Spinach Jul-02 Dec-03 Spinach 7 

## Jan-06 Sep-06
Strawberries 2 

## Jan-98 Sep-00 Strawberries Jan-04 Dec-05 Summer Squash Oct-06 Ongoing Sweet Bell Peppers Jan-99 Dec-00 Sweet Bell Peppers Oct-02 Sep-04

Appendix A. Page 2 of 6

## Commodit y Start Date End Date

Sweet Potatoes 1 

## Jan-96 Jun-98 Sweet Potatoes Jan-03 Dec-04
Tomatoes 1 

## Jul-96 Jun-99
Tomatoes Jan-03 Dec-04 Tomatoes Jan-07 Ongoing
Watermelon 8 

## Oct-05 Sep-06 Winter Squash 2 

## Jan-97 Jun-99 Winter Squash Jul-04 Jun-06

1 

### Excludes sampling hiatus September - November 1996.

2 

### Frozen collected when fresh unavailable.
3 

### Sampling adjusted for market availability. Cherries were sampled for two years (May-00 - Aug-01) for a total of six months.

4 

### Sampling adjusted for market availability. Nectarines were sampled for two years (Jul-00 - Sep-01) for a total of six months.

5 

### Sam p lin g ad j usted for market availabilit y . Peaches were sam p led for two y ear s (Jan-01 - Sep-02) for a total of sixteen months.
6 

### Dried plums (prunes) were collected when fresh plums were not available.

7 

### S p inach ended 1earlier than p lanned due to the unavailibilit yof p roduct

. 8 

### Sam p les collected in California, Florida, and Texas onl y

. (S-1) Special single serving project testing for organophosphates. (S-2) Special single serving project testing for carbamates. (S-3) Special single serving project testing for carbamate, organochlorine, organophosphate, organonitrogen, and sulfur compounds. (S-4) Special single serving project testing for aldicarb. (T-1) Triazole parent and metabolite compounds only. (TSP) Triazole Sampling Project. Samples sent to contract laboratory.

Appendix A. Page 3 of 6

## Processed Commodities
Commodit y Start Date End Date Almonds Jul-07 Ongoing Apple Juice 1 

## Jul-96 Dec-98 Apple Juice Jan-02 Dec-02 Apple Juice Jul-07 Ongoing Applesauce Jul-02 Dec-02 Applesauce Jan-06 Dec-06 Asparagus, Canned Jul-03 Dec-03 Blueberries, Frozen 2 

## Jan-07 Ongoing Corn Syrup 3 

## Jan-98 Jun-99 Grape Juice Jan-98 Dec-99 Green Beans, Canned/Frozen 1 

## Jan-96 Jun-98 Green Beans, Canned Jan-03 Mar-04 Green Beans, Frozen Apr-05 Dec-05 Honey Oct-07 Ongoing Orange Juice Jan-97 Dec-98 Orange Juice Oct-04 Sep-06 Peaches, Canned Dec-96 Dec-97 Peaches, Canned Jan-03 Dec-04 Peaches, Canned (T-1) Jan-03 Mar-03 Peaches, Canned (T-1) Oct-03 Dec-03
Peanut Butter Jan-00 Dec-00
Peanut Butter Jan-06 Dec-06 Peanut Butter (TSP) Jul-03 Dec-03 Pear Juice, Concentrate/Puree Jul-02 Jun-03 Pears, Canned Jul-99 Jun-00 Peas, Canned/Frozen Apr-94 Jun-96 Peas, Canned/Frozen 4 

## Oct-01 Sep-03 Peas, Frozen Jan-06 Dec-06 Plums, Dried (Prunes) 5 

## Jan-05 Dec-06 Potatoes, Frozen Jan-06 Dec-07
Raisins Jul-06 Jun-07 Spinach, Canned Oct-97 Dec-98 Spinach, Frozen Jan-99 Dec-99 Spinach, Canned Jan-04 Jun-04 Strawberries, Frozen 2 

## Jan-98 Sep-00 Sweet Corn, Canned/Frozen Apr-94 Mar-96

Appendix A. Page 4 of 6

## Commodit y Start Date End Date
Sweet Corn, Canned/Frozen 4 

## Oct-01 Sep-03 Tomato Paste, Canned Jan-01 Jun-01 Tomatoes, Canned Jul-99 Jun-00 Winter Squash, Frozen 2 

## Jan-97 Jun-99

1 

### Excludes sampling hiatus September - November 1996
2 

### Frozen collected when fresh unavailable
3 

### Excludes sampling hiatus January 1999
4 

### Canned samples collected in first year and frozen samples in second year of testing.
5 

### Dried plums (prunes) were collected when fresh plums were not available. (T-1) Triazole parent and metabolite compounds only. (TSP) Triazole Sampling Project. Samples sent to contract laboratory.

Appendix A. Page 5 of 6

### Grains Commodity Start Date End Date Barley Oct-01 Sep-03 Corn Oct-06 Ongoing Oats Jul-99 Apr-00 Rice Oct-00 Sep-02 Soybeans Sep-96 Feb-98 Soybeans Oct-03 Sep-05 Soybean Rust/Aphid Oct-05 Dec-05 Wheat Feb-95 Jan-98 Wheat Sep-04 Jun-06 Wheat Flour Jan-03 Dec-04 Wheat Flour (T-1) Jan-03 Dec-03



### Dairy Commodity Start Date End Date
Butter Jan-03 Dec-03 Heavy Cream Jul-05 Dec-05 Heavy Cream Jan-07 Dec-07 Milk 1 

### Jan-96 Oct-98 Milk (TSP) Jul-03 Dec-03 Milk Jan-04 Dec-05



### Meat / Poultry Products Commodity Type Start Date End Date Poultry Young Chickens Apr-00 Mar-01 Poultry Young & Mature Chickens Jan-06 Dec-06 Beef Cows, Heifers, Steers Jun-01 Jul-02 Pork Gilt, Barrow Jan-05 Jun-05



### Drinking Water States Start Date End Date Finished Water Only California, Colorado, Kansas, New York, Texas Mar-01 Dec-03

Raw Intake and Finished Water Alabama, Arizona, California, Colorado, Florida, Jan-04 Ongoing Georgia, Indiana, Iowa, Kansas, Louisiana, Maryland, Michigan, Minnesota, Missouri, Montana, North Carolina, North Dakota, New Jersey, New York, Ohio, Oregon, Pennsylvania, South Carolina, Texas, Washington, Washington D.C.

Bottled Water 10 Participating States Jan-05 Dec-06

Groundwater 75 Private Wells in 33 States Jan-07 Ongoing

1 

### Excludes sam p lin g hiatus Se p tember - November 199 6 (T-1) Triazole parent and metabolite compounds only. (TSP) Triazole Sampling Project. Samples sent to contract laboratory.

Appendix A. Page 6 of 6

# Appendix B

Distribution of Residues by Pesticide in Fruit and Vegetables

Appendix B shows residue detections fo r all fruit and vegetable pesticide/ commodity pairs tested, including range ofvalues detected, range of Limits of Detection (LODs), Environmental Protec tion Agency (EPA) tolerances, and Codex Maximum Residue Limit/Extraneous Maximum Residue Limit (MRL/EMRL) references for each pair.
In 2006, 9,818 fruit and vegetable samples were analyzed, of which 6,433 were fresh product and 3,385 were processed product.

PDP reports tolerance violations to t he Food and Drug Administration (FDA) as part of an interagency Memorandum of U nderstanding between the U.S. Department of Agriculture and FDA. Residues reported to FDA are shown in the “ Pesticide/ Commodity ” column to the right of the commodity and are annotated as “ X” (if the residue exceeded the established tolerance) or “ V” [if the residue did not have a tolerance listed in the Code of Federal Regulations (CFR), Title 40, Part 180]. In both cases, these annotations are followed by a number indicating t he number of samples reported to FDA.
Action levels (ALs) are shown in this appendix, where applicable, and denote Action Level values established by FDA and/or Extraneous Maximum Residue Levels (EMRLs) established by the Codex A limentarius Commission. Under FQPA, responsibility for establishing tolerances in lieu of action levels has been transferred to EPA. In the interim, action levels are used.
Data to establish Codex MRLs are evaluated by the Food and Agriculture and World Health Organization-sponsored Joint Meeting on Pesticide Residues (JMPR) based on toxicology, residue occurrence in crops determined by supervised field trials, and dietary exposure. The Codex Committ ee on Pesticide Residues (CCPR) meets annually to discuss proposed MRLs and recommends approval to the Codex Alimentarius Commission. This means that Codex MRLs r epresent levels that are considered safe to humans. MRLs/EMRLs shown in this appendix are from the Codex Alimentarius: Proc. of Codex Committee on Pesticide Residues , 39 th 

## Session, May 7- 12, 2007, Beijing, China. Only Codex MRLs (CXLs) are listed.
The information herein is only intended to be an initial reference. Readers are reminded that international r egulations and MRLs can change and that it is important that information obtained from this table be verified with knowledgeable parties in the market of interest prior to sale or shipment of exports.Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Acephate (insecticide ) Applesauce 744 4 0.5 0.003 ^ 0.002 ^ 0.02 - Bananas 742 0 0.002 - 0.005 0.02 - Carrots 216 0 0.002 ^ 0.02 - Cranberries 84 21 25.0 0.003 - 0.14 0.002 ^ 0.5 - Eggplant (X-3 ) 740 5 0.7 0.008 - 0.70 0.005 ^ 0.02 - Grapefrui t 743 0 0.002 - 0.004 0.02 - Greens, Collard 86 0 0.002 - 0.030 0.02 - Greens, Kale 98 0 0.002 - 0.030 0.02 - Orange Juice 557 0 0.002 ^ 0.02 - Peaches 90 0 0.002 ^ 0.02 - Plums 515 0 0.005 ^ 0.02 - Plums, Dried (Prunes) 224 0 0.005 ^ 0.02 - Potatoes, Frozen 744 0 0.002 ^ 0.02 - Raisins 372 0 0.004 - 0.005 0.02 - Spinach (X-1) 511 13 2.5 0.003 - 0.081 0.002 - 0.007 0.02 - Summer Squash 186 0 0.002 - 0.005 0.02 - Sweet Peas, Frozen 744 0 0.002 - 0.005 0.02 - Watermelon (X-13) 550 19 3.5 0.003 - 0.31 0.002 - 0.005 0.02 - Winter Squash (X-1) 369 9 2.4 0.008 - 0.041 0.002 - 0.005 0.02 - TOTA L 8,315 71

Acetamiprid (insecticide) Applesauce 744 383 51.5 0.001 - 0.031 0.0006 - 0.001 1.0 - Broccoli 185 10 5.4 0.001 - 0.007 0.0006 ^ 1.20 - Cauliflowe r 558 3 0.5 0.001 ^ 0.0006 ^ 1.20 - Greens, Collard 86 2 2.3 0.013 - 0.13 0.001 - 0.010 1.20 - Greens, Kale 98 7 7.1 0.014 - 0.98 0.001 - 0.010 1.20 - Potatoes, Frozen 744 0 0.001 ^ 0.01 - Raisins 372 11 3.0 0.002 - 0.075 0.001 - 0.050 0.20 - Spinach (X-4) 511 37 7.2 0.001 - 0.55 0.0006 - 0.001 0.20 - TOTA L 3,298 453

Acibenzolar S methyl (plant activator) Applesauce 528 0 0.007 ^ NT - Broccoli 185 0 0.007 ^ 1.0 - Cauliflowe r 558 0 0.007 ^ 1.0 - Spinach 366 0 0.007 ^ 1.0 - TOTA L 1,637 0

Alachlor (herbicide) Winter Squash 261 0 0.016 ^ NT - TOTA L 261 0

Aldicarb (insecticide) Applesauce 528 0 0.001 ^ NT - Bananas 526 0 0.010 ^ NT - Broccoli 185 0 0.001 ^ NT - Cauliflowe r 558 0 0.001 ^ NT - Grapefrui t 216 0 0.007 - 0.008 0.3 0.2 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 557 0 0.001 - 0.010 0.3 0.2 Potatoes, Frozen 744 0 0.001 - 0.008 1 0.5 Spinach 352 0 0.001 ^ NT - Sweet Peas, Frozen 528 0 0.010 - 0.018 NT - Watermelon 189 0 0.010 ^ NT - Winter Squash 261 0 0.020 ^ NT - TOTA L 4,774 0



## APPENDIX B. DISTRIBUTION OF RESIDUES BY PESTICIDE IN FRUIT AND VEGETABLES

Appendix B. Page 1 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Aldicarb sulfone (metabolite of Aldicarb ) Applesauce 514 0 0.003 ^ NT - Bananas 526 0 0.010 - 0.050 NT - Broccoli 185 0 0.010 ^ NT - Cauliflowe r 542 0 0.003 ^ NT - Grapefrui t 743 1 0.1 0.015 ^ 0.009 - 0.012 0.3 0.2 Orange Juice 557 0 0.001 - 0.010 0.3 0.2 Potatoes, Frozen 744 23 3.1 0.002 - 0.020 0.001 - 0.009 1 0.5 Spinach 366 0 0.003 ^ NT - Sweet Peas, Frozen 528 0 0.010 - 0.020 NT - Watermelon 189 0 0.010 ^ NT - Winter Squash 261 0 0.038 ^ NT - TOTA L 5,155 24

Aldicarb sulfoxide (metabolite of Aldicarb ) Applesauce 469 0 0.002 - 0.003 NT - Bananas 526 0 0.010 - 0.050 NT - Cauliflowe r 386 0 0.004 ^ NT - Grapefrui t 216 4 1.9 0.008 - 0.063 0.005 ^ 0.3 0.2 Orange Juice 557 37 6.6 0.002 - 0.005 0.001 - 0.010 0.3 0.2 Potatoes, Frozen 744 60 8.1 0.002 - 0.039 0.001 - 0.009 1 0.5 Spinach 295 0 0.002 - 0.003 NT - Sweet Peas, Frozen 528 0 0.010 - 0.018 NT - Watermelon 189 0 0.010 ^ NT - Winter Squash 261 0 0.038 ^ NT - TOTA L 4,171 101

Aldrin (insecticide) (parent of Dieldrin) Applesauce 729 0 0.003 - 0.007 0.03 AL 0.05 Bananas 742 0 0.002 - 0.003 0.02 AL - Broccoli 185 0 0.007 ^ 0.03 AL - Carrots 743 0 0.003 - 0.023 0.1 AL 0.1 Cauliflowe r 558 0 0.007 ^ 0.03 AL - Cranberries 316 0 0.003 - 0.012 NT - Eggplan t 740 0 0.006 ^ 0.05 AL - Grapefrui t 743 0 0.003 - 0.008 0.02 AL 0.05 Greens, Collard 17 0 0.003 ^ 0.05 AL 0.05 Greens, Kale 37 0 0.003 ^ 0.05 AL 0.05 Orange Juice 557 0 0.003 - 0.008 0.02 AL 0.05 Peaches 90 0 0.003 ^ 0.02 AL - Plums 515 0 0.006 ^ 0.3 AL - Plums, Dried (Prunes) 224 0 0.006 ^ 0.3 AL - Potatoes, Frozen 744 0 0.003 ^ 0.1 AL 0.1 Spinach 511 0 0.003 - 0.007 0.05 AL 0.05 Summer Squash 186 0 0.002 - 0.003 0.1 AL 0.1 Sweet Peas, Frozen 744 0 0.002 - 0.003 0.03 AL 0.05 Watermelon 550 0 0.002 - 0.003 0.1 AL 0.1 Winter Squash 108 0 0.003 ^ 0.1 AL 0.1 TOTA L 9,039 0

Allethrin (insecticide) Applesauce 216 0 0.010 ^ 4 - Bananas 526 0 0.015 ^ NT - Cranberries 316 0 0.010 - 0.040 NT - Grapefrui t 743 0 0.010 - 0.040 NT - Orange Juice 535 0 0.010 ^ 4 - Peaches 90 0 0.010 ^ NT - Plums 515 0 0.021 ^ 4 - Plums, Dried (Prunes) 224 0 0.021 ^ 4 - Raisins 372 3 0.8 0.033 - 0.085 0.020 - 0.030 4 - Sweet Peas, Frozen 308 0 0.015 ^ NT - Watermelon (V-4) 189 4 2.1 0.017 - 0.029 0.015 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 4,295 7
Appendix B. Page 2 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Ametryn (herbicide) Bananas 706 0 0.010 ^ 0.25 - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 44 0 0.010 ^ NT - Sweet Peas, Frozen 286 0 0.010 ^ NT - Watermelon 189 0 0.010 ^ NT - TOTA L 1,355 0

Anilazine (fungicide) Sweet Peas, Frozen 220 0 0.006 ^ NT - TOTA L 220 0

Atrazine (herbicide) Applesauce 528 0 0.002 ^ NT - Bananas 526 0 0.008 ^ NT - Broccoli 171 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Orange Juice 44 0 0.010 ^ NT - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.008 - 0.015 NT - Watermelon 189 0 0.008 ^ NT - Winter Squash 261 0 0.024 ^ NT - TOTA L 3,171 0

Azinphos (insecticide) Sweet Peas, Frozen 220 0 0.010 ^ NT - TOTA L 220 0

Azinphos methyl (insecticide) Applesauce 744 4 0.5 0.013 - 0.020 0.008 - 0.012 1.5 2 Bananas 526 0 0.011 ^ NT 1 Cranberries 316 0 0.008 - 0.014 0.5 0.1 Eggplan t 740 0 0.004 ^ 0.3 0.5 Grapefrui t 216 0 0.008 ^ 2.0 1 Greens, Collard 69 0 0.011 ^ NT 0.5 Greens, Kale 61 0 0.011 ^ NT 0.5 Orange Juice 557 0 0.008 ^ 2.0 1 Peaches 90 20 22.2 0.002 - 0.83 0.001 - 0.008 2.0 2 Plums 515 17 3.3 0.007 - 0.017 0.004 ^ 2.0 2 Plums, Dried (Prunes) 224 1 0.4 0.014 ^ 0.004 ^ 2.0 2 Potatoes, Frozen 744 0 0.001 - 0.008 0.2 0.05 Raisins 372 1 0.3 0.020 ^ 0.012 - 0.015 4.0 1 Spinach 511 0 0.008 - 0.025 2.0 0.5 Sweet Peas, Frozen 528 0 0.010 - 0.011 NT 0.5 Watermelon 550 0 0.008 - 0.012 2.0 0.2 Winter Squash 261 0 0.012 ^ NT 0.5 TOTA L 7,024 43

Azoxystrobin (fungicide) Applesauce 528 0 0.0009 - 0.002 NT - Bananas 742 19 2.6 0.0008 - 0.019 0.0005 - 0.010 2.0 - Broccoli 185 11 5.9 0.002 - 0.10 0.0009 ^ 3.0 - Carrots 744 117 15.7 0.0008 - 0.046 0.0005 - 0.0008 0.5 - Cauliflowe r 558 0 0.002 ^ 3.0 - Cranberries 316 102 32.3 0.0001 - 0.012 0.0001 - 0.0005 0.50 - Grapefrui t 743 28 3.8 0.0004 - 0.002 0.0004 - 0.0005 10.0 - Greens, Collard 86 33 38.4 0.002 - 4.2 0.0005 - 0.002 25 - Greens, Kale 98 33 33.7 0.0008 - 3.0 0.0005 - 0.002 25 - Orange Juice 557 0 0.0005 - 0.010 10.0 - Peaches 90 2 2.2 0.005 - 0.024 0.0005 - 0.001 1.5 - Potatoes, Frozen 744 6 0.8 0.0008 ^ 0.0005 - 0.001 1.5 -

Appendix B. Page 3 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Raisins 372 6 1.6 0.0008 - 0.031 0.0005 - 0.030 1.0 - Spinach 511 59 11.5 0.0008 - 3.4 0.0005 - 0.002 30.0 - Summer Squash 186 5 2.7 0.0008 - 0.039 0.0005 - 0.030 0.3 - Sweet Peas, Frozen 700 1 0.1 0.065 ^ 0.0005 - 0.005 3.0 - Watermelon 550 2 0.4 0.0008 - 0.002 0.0005 - 0.020 0.3 - Winter Squash 108 4 3.7 0.0008 - 0.002 0.0005 ^ 0.3 - TOTA L 7,818 428

Bendiocarb (insecticide)

Applesauce 744 0 0.002 - 0.040 SU - Bananas 742 0 0.002 - 0.005 SU - Broccoli 185 0 0.040 ^ SU - Carrots 744 0 0.002 - 0.004 SU - Cauliflowe r 558 0 0.040 ^ SU - Cranberries 316 0 0.002 - 0.021 SU - Eggplan t 740 0 0.010 ^ SU - Grapefrui t 743 0 0.002 - 0.010 SU - Greens, Collard 86 0 0.002 - 0.005 SU - Greens, Kale 98 0 0.002 - 0.005 SU - Orange Juice 557 0 0.001 - 0.010 SU - Peaches 90 0 0.001 - 0.002 SU - Plums 515 1 0.2 0.017 ^ 0.010 ^ SU - Plums, Dried (Prunes) 224 0 0.010 ^ SU - Potatoes, Frozen 744 0 0.001 - 0.002 SU - Raisins 372 0 0.002 - 0.030 SU - Spinach 511 0 0.002 - 0.040 SU - Summer Squash 186 0 0.002 - 0.015 SU - Sweet Peas, Frozen 502 0 0.002 - 0.005 SU - Watermelon 550 0 0.002 - 0.016 SU - Winter Squash 108 0 0.002 ^ SU - TOTA L 9,315 1

Benoxacor (herbicide safener)

Cranberries 84 0 0.004 ^ 0.5 - Peaches 90 0 0.003 - 0.004 0.01 - Potatoes, Frozen 744 0 0.003 - 0.004 0.01 - Sweet Peas, Frozen 216 0 0.004 ^ 0.01 - TOTA L 1,134 0

BHC alpha (insecticide)

Applesauce 744 0 0.002 - 0.007 0.05 AL - Bananas 526 0 0.002 ^ NT - Broccoli 169 0 0.007 ^ 0.5 AL - Carrots 743 0 0.002 - 0.026 0.3 AL - Cauliflowe r 558 0 0.007 ^ 0.05 AL - Cranberries 316 0 0.002 - 0.025 NT - Eggplan t 740 0 0.004 ^ 0.05 AL - Grapefrui t 743 0 0.002 - 0.005 0.05 AL - Greens, Collard 17 0 0.002 ^ 0.05 AL - Greens, Kale 37 0 0.002 ^ 0.05 AL - Orange Juice 557 0 0.002 ^ 0.05 AL - Peaches 90 0 0.002 ^ 0.05 AL - Plums 515 0 0.003 ^ 0.05 AL - Plums, Dried (Prunes) 224 0 0.003 ^ 0.05 AL - Potatoes, Frozen 744 0 0.002 ^ 0.05 AL - Spinach 511 0 0.002 - 0.007 0.05 AL - Summer Squash 186 0 0.002 ^ 0.05 AL - Sweet Peas, Frozen 744 0 0.0009 - 0.002 0.05 AL - Watermelon 550 0 0.002 ^ 0.05 AL - Winter Squash 369 0 0.002 - 0.004 0.05 AL - TOTA L 9,083 0

Appendix B. Page 4 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm BHC beta (isomer of BHC alpha)

Sweet Peas, Frozen 220 0 0.0009 ^ NT - TOTA L 220 0

Bifenazate (acaricide)

Applesauce 216 0 0.020 ^ 0.75 1 Peaches 19 1 5.3 0.033 ^ 0.020 ^ 2.5 2 Potatoes, Frozen 744 0 0.001 - 0.020 0.05 - Raisins 108 0 0.040 ^ 1.2 2 Summer Squash 54 0 0.020 ^ 0.75 0.7 Watermelon 181 0 0.020 ^ 0.75 0.3 Winter Squash 369 0 0.013 - 0.020 0.75 0.7 TOTA L 1,691 1

Bifenthrin (insecticide)

Applesauce 744 0 0.003 - 0.010 0.05 - Bananas 742 0 0.010 - 0.011 0.1 - Broccoli 185 2 1.1 0.005 ^ 0.003 ^ 0.6 - Carrots 743 0 0.010 - 0.015 0.05 - Cauliflowe r 558 0 0.003 ^ 0.6 - Cranberries 316 0 0.005 - 0.010 NT - Eggplan t 740 1 0.1 0.047 ^ 0.028 ^ 0.05 - Grapefrui t 743 0 0.010 ^ 0.05 0.05 Greens, Collard 17 0 0.010 ^ 3.5 - Greens, Kale 37 0 0.010 ^ 3.5 - Orange Juice 557 0 0.010 ^ 0.05 0.05 Peaches 90 0 0.010 ^ NT - Plums 515 0 0.037 ^ 0.05 - Plums, Dried (Prunes) 224 0 0.037 ^ 0.05 - Potatoes, Frozen 744 0 0.010 ^ 0.05 0.05 Raisins 372 0 0.020 - 0.030 0.2 - Spinach 511 9 1.8 0.005 ^ 0.003 - 0.010 0.05 - Summer Squash 186 18 9.7 0.007 - 0.043 0.004 - 0.010 0.4 - Sweet Peas, Frozen 744 0 0.010 - 0.025 0.6 - Watermelon 550 3 0.5 0.007 - 0.017 0.004 - 0.011 0.4 - Winter Squash 369 0 0.010 - 0.016 0.4 - TOTA L 9,687 33

Bitertanol (fungicide) Bananas 526 0 0.010 - 0.050 0.2 0.05 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Watermelon 189 0 0.010 ^ NT - TOTA L 845 0

Boscalid (fungicide)

Applesauce 744 5 0.7 0.004 - 0.010 0.003 - 0.006 3.0 - Bananas 526 0 0.010 - 0.050 0.20 - Broccoli 185 0 0.006 ^ 3.0 - Carrots 743 63 8.5 0.004 - 0.085 0.003 - 0.025 0.7 - Cauliflowe r 558 0 0.006 ^ 3.0 - Greens, Collard 86 4 4.7 0.004 - 0.92 0.003 - 0.010 18.0 - Greens, Kale 98 6 6.1 0.004 - 0.046 0.003 - 0.010 18.0 - Peaches 90 34 37.8 0.002 - 0.30 0.001 - 0.003 1.7 - Potatoes, Frozen 744 10 1.3 0.002 - 0.004 0.001 - 0.003 0.05 - Raisins 372 133 35.8 0.004 - 0.36 0.003 - 0.030 8.5 - Spinach 511 18 3.5 0.004 - 0.013 0.003 - 0.006 60 - Summer Squash 186 0 0.003 - 0.030 1.6 - Sweet Peas, Frozen 744 1 0.1 0.004 ^ 0.003 - 0.010 1.6 - Watermelon 550 2 0.4 0.004 - 0.010 0.003 - 0.010 1.6 - Winter Squash 369 13 3.5 0.004 - 0.065 0.003 - 0.039 1.6 - TOTA L 6,506 289

Appendix B. Page 5 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Bromacil (herbicide)

Grapefrui t 743 0 0.015 - 0.067 0.1 - Orange Juice 557 16 2.9 0.002 ^ 0.001 - 0.025 0.1 - Potatoes, Frozen 176 0 0.001 ^ NT - TOTA L 1,476 16

Buprofezin (insecticide)

Applesauce 744 2 0.3 0.0002 ^ 0.0001 - 0.015 4.0 - Bananas 742 0 0.015 ^ 0.20 - Broccoli 185 0 0.0001 ^ NT - Cauliflower (V-1 ) 558 1 0.2 0.0002 ^ 0.0001 - 0.0002 NT - Eggplan t 740 0 0.029 ^ NT - Grapefrui t 743 0 0.0005 - 0.015 2.5 - Orange Juice 557 0 0.015 ^ 2.5 0.5 Peaches 90 0 0.015 ^ 9.0 - Raisins 372 1 0.3 0.21 ^ 0.030 - 0.050 0.60 - Spinach 366 0 0.0001 ^ NT - Summer Squash 186 0 0.015 - 0.040 0.50 - Sweet Peas, Frozen 308 0 0.015 ^ NT - Watermelon 550 0 0.012 - 0.015 0.50 - Winter Squash 108 0 0.015 ^ 0.50 - TOTA L 6,249 4

Cadusafos (insecticide) Bananas 216 0 0.005 ^ 0.01 0.01 TOTA L 216 0

Captafol (fungicide) (parent of THPI) Bananas 526 0 0.015 ^ NT - Watermelon 189 0 0.015 ^ NT - TOTA L 715 0

Captan (fungicide) (parent of THPI)

Applesauce 216 0 0.012 ^ 25 25 Bananas 526 0 0.008 ^ NT - Carrots 162 0 0.012 ^ 2 - Eggplan t 740 1 0.1 0.030 ^ 0.018 ^ 25 - Greens, Collard 17 0 0.012 ^ 2 - Greens, Kale 37 0 0.012 ^ 2 - Orange Juice 396 0 0.012 ^ NT - Peaches 90 1 1.1 0.042 ^ 0.012 ^ 50 15 Plums 515 1 0.2 0.027 ^ 0.016 ^ 100 - Plums, Dried (Prunes) 224 1 0.4 0.027 ^ 0.016 ^ 100 - Potatoes, Frozen 664 0 0.012 ^ 25 0.05 Raisins 372 2 0.5 0.040 ^ 0.010 - 0.024 50 - Spinach 19 0 0.012 ^ 100 - Summer Squash 186 1 0.5 0.017 ^ 0.010 - 0.012 25 - Sweet Peas, Frozen 90 0 0.012 ^ 2 - Watermelon 449 0 0.008 - 0.012 25 - Winter Squash 20 0 0.012 ^ 25 - TOTA L 4,723 7

Carbaryl (insecticide)

Applesauce 744 165 22.2 0.0005 - 0.23 0.0003 - 0.002 10 5 Bananas 742 1 0.1 0.003 ^ 0.002 - 0.010 10 - Broccoli 185 0 0.001 ^ 10 - Carrots 744 0 0.002 - 0.006 10 0.5 Cauliflowe r 558 0 0.0003 ^ 10 - Cranberries 316 12 3.8 0.003 ^ 0.002 - 0.018 10 - Eggplan t 740 12 1.6 0.017 - 0.18 0.010 ^ 10 1 Grapefrui t 743 3 0.4 0.003 ^ 0.002 - 0.006 10 7 Greens, Collard 86 0 0.002 - 0.010 12 -

Appendix B. Page 6 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Greens, Kale 98 0 0.002 - 0.010 12 - Orange Juice 557 165 29.6 0.002 - 0.016 0.001 - 0.010 10 7 Peaches 90 25 27.8 0.002 - 0.45 0.001 - 0.002 10 10 Plums 515 50 9.7 0.017 - 0.56 0.010 ^ 10 - Plums, Dried (Prunes) 224 1 0.4 0.043 ^ 0.010 ^ 10 - Potatoes, Frozen 744 0 0.001 - 0.002 0.2 - Raisins 372 9 2.4 0.008 - 0.036 0.002 - 0.006 10 5 Spinach 511 8 1.6 0.0005 - 0.093 0.0003 - 0.002 12 - Summer Squash 186 0 0.002 - 0.006 10 - Sweet Peas, Frozen 722 1 0.1 0.052 ^ 0.002 - 0.010 10 - Watermelon 550 1 0.2 0.007 ^ 0.002 - 0.010 10 - Winter Squash 369 0 0.002 - 0.008 10 - TOTA L 9,796 453

Carbendazim - MBC (fungicide) (metabolite of Benomyl)

Applesauce 528 436 82.6 0.0005 - 0.040 0.0003 - 0.0005 7.0 3 Bananas 526 2 0.4 0.015 - 0.032 0.010 ^ 1.0 0.2 Broccoli 185 0 0.0003 ^ 0.2 - Cauliflowe r 558 1 0.2 0.001 ^ 0.0006 ^ 0.2 - Grapefrui t 286 0 0.045 ^ 10.0 - Greens, Collard 69 1 1.4 0.037 ^ 0.010 ^ 0.2 - Greens, Kale 61 0 0.010 ^ 0.2 - Potatoes, Frozen 22 0 0.001 ^ NT - Spinach 366 5 1.4 0.0005 - 0.001 0.0003 - 0.0005 0.2 - Sweet Peas, Frozen 308 0 0.010 ^ NT 0.02 Watermelon 189 0 0.010 ^ 1.0 - TOTA L 3,098 445

Carbofuran (insecticide) (parent of 3-Hydroxycarbofuran )

Applesauce 528 0 0.0003 ^ NT - Bananas 742 0 0.002 - 0.010 0.1 0.1 Broccoli 185 0 0.0003 ^ NT - Cauliflowe r 558 0 0.0003 ^ NT - Cranberries 316 0 0.002 - 0.019 0.5 - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 396 0 0.001 - 0.010 NT - Potatoes, Frozen 744 0 0.001 - 0.002 2 0.1 Raisins 372 0 0.002 - 0.006 0.4 - Spinach 366 0 0.0003 ^ NT - Summer Squash 186 0 0.002 - 0.006 0.6 - Sweet Peas, Frozen 528 0 0.010 - 0.015 NT - Watermelon 550 6 1.1 0.006 - 0.13 0.002 - 0.010 0.4 - Winter Squash 369 0 0.002 - 0.008 0.8 - TOTA L 5,970 6

Carbophenothion (insecticide)

Applesauce 528 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - TOTA L 1,637 0

Carfentrazone ethyl (herbicide)

Applesauce 744 0 0.001 - 0.002 0.10 - Bananas 742 0 0.002 - 0.008 0.20 - Broccoli 185 0 0.001 ^ 0.10 - Carrots 744 0 0.002 - 0.004 0.10 - Cauliflowe r 558 0 0.001 ^ 0.10 - Eggplan t 740 0 0.030 ^ 0.10 - Greens, Collard 86 0 0.002 - 0.008 0.10 - Greens, Kale 98 0 0.002 - 0.008 0.10 -

Appendix B. Page 7 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Peaches 19 0 0.002 ^ 0.10 - Potatoes, Frozen 216 0 0.002 ^ 0.10 - Raisins 372 0 0.002 - 0.030 0.10 - Spinach 511 0 0.001 - 0.002 0.10 - Summer Squash 186 0 0.002 - 0.020 0.10 - Sweet Peas, Frozen 524 0 0.002 - 0.008 0.10 - Watermelon 550 0 0.002 - 0.008 0.10 - TOTA L 6,275 0

Chlordane cis (insecticide) (isomer of Chlordane)

Applesauce 744 0 0.0007 - 0.002 0.1 AL 0.02 Bananas 742 0 0.002 ^ 0.1 AL 0.02 Broccoli 185 0 0.0007 ^ 0.1 AL 0.02 Carrots 743 7 0.9 0.003 ^ 0.002 - 0.004 0.1 AL 0.02 Cauliflowe r 558 0 0.0007 ^ 0.1 AL 0.02 Cranberries 316 0 0.002 - 0.012 NT 0.02 Eggplan t 740 0 0.003 ^ 0.1 AL 0.02 Grapefrui t 743 0 0.002 - 0.020 0.1 AL 0.02 Greens, Collard 17 0 0.002 ^ 0.1 AL 0.02 Greens, Kale 37 0 0.002 ^ 0.1 AL 0.02 Orange Juice 557 0 0.002 - 0.012 0.1 AL 0.02 Peaches 90 0 0.002 ^ 0.1 AL 0.02 Plums 515 0 0.003 ^ 0.1 AL 0.02 Plums, Dried (Prunes) 224 0 0.003 ^ 0.1 AL 0.02 Potatoes, Frozen 744 0 0.002 ^ 0.1 AL 0.02 Spinach 511 2 0.4 0.001 ^ 0.0007 - 0.002 0.1 AL 0.02 Summer Squash 186 8 4.3 0.003 - 0.016 0.002 ^ 0.1 AL 0.02 Sweet Peas, Frozen 744 0 0.002 - 0.015 0.1 AL 0.02 Watermelon 550 0 0.002 ^ 0.1 AL 0.02 Winter Squash 369 5 1.4 0.003 ^ 0.002 - 0.004 0.1 AL 0.02 TOTA L 9,315 22

Chlordane trans (insecticide) (isomer of Chlordane)

Applesauce 744 0 0.0007 - 0.002 0.1 AL 0.02 Bananas 742 0 0.002 ^ 0.1 AL 0.02 Broccoli 185 0 0.0007 ^ 0.1 AL 0.02 Carrots 743 0 0.002 - 0.004 0.1 AL 0.02 Cauliflowe r 558 0 0.0007 ^ 0.1 AL 0.02 Cranberries 316 0 0.002 - 0.012 NT 0.02 Eggplan t 740 0 0.003 ^ 0.1 AL 0.02 Grapefrui t 216 0 0.002 ^ 0.1 AL 0.02 Greens, Collard 17 0 0.002 ^ 0.1 AL 0.02 Greens, Kale 37 0 0.002 ^ 0.1 AL 0.02 Orange Juice 557 0 0.002 - 0.012 0.1 AL 0.02 Peaches 90 0 0.002 ^ 0.1 AL 0.02 Plums 515 0 0.003 ^ 0.1 AL 0.02 Plums, Dried (Prunes) 224 0 0.003 ^ 0.1 AL 0.02 Potatoes, Frozen 744 0 0.002 ^ 0.1 AL 0.02 Spinach 511 1 0.2 0.001 ^ 0.0007 - 0.002 0.1 AL 0.02 Summer Squash 186 3 1.6 0.003 - 0.008 0.002 ^ 0.1 AL 0.02 Sweet Peas, Frozen 744 0 0.002 - 0.015 0.1 AL 0.02 Watermelon 550 0 0.002 ^ 0.1 AL 0.02 Winter Squash 369 1 0.3 0.007 ^ 0.002 - 0.004 0.1 AL 0.02 TOTA L 8,788 5

Chlorethoxyfos (insecticide)

Winter Squash 261 0 0.016 ^ NT - TOTA L 261 0

Chlorfenapyr (insecticide) Eggplan t 740 3 0.4 0.048 ^ 0.029 ^ 1.0 - TOTA L 740 3

Appendix B. Page 8 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Chlorfenvinphos (insecticide)

Applesauce 528 0 0.004 ^ NT - Broccoli 185 0 0.004 ^ NT - Cauliflowe r 558 0 0.004 ^ NT - Spinach 366 0 0.004 ^ NT - TOTA L 1,637 0

Chlorothalonil (fungicide) Bananas 742 0 0.002 - 0.008 0.5 0.01 Carrots 216 0 0.008 ^ 1 1 Cranberries 84 47 56.0 0.013 - 0.60 0.008 ^ 5.0 5 Eggplant (V-3) 740 3 0.4 0.012 - 0.045 0.007 ^ NT - Greens, Collard (V-1) 1 1 100.0 0.013 ^ 0.008 ^ NT - Greens, Kale (V-1) 1 1 100.0 0.45 ^ 0.008 ^ NT - Orange Juice 396 0 0.008 ^ NT - Peaches 90 0 0.008 ^ 0.5 0.2 Plums 515 0 0.008 ^ 0.2 - Plums, Dried (Prunes) 224 1 0.4 0.013 ^ 0.008 ^ 0.2 - Potatoes, Frozen 744 0 0.008 ^ 0.1 0.2 Spinach (V-3) 3 3 100.0 0.013 - 0.13 0.008 ^ NT - Summer Squash 186 9 4.8 0.013 - 0.13 0.008 - 0.010 5 5 Watermelon 550 2 0.4 0.004 ^ 0.002 - 0.010 5 - Winter Squash 109 9 8.3 0.013 - 0.10 0.007 - 0.008 5 5 TOTA L 4,601 76

Chlorpropham (herbicide, growth regulator)

Applesauce 528 0 0.006 ^ NT - Bananas 526 0 0.011 ^ NT - Broccoli 137 0 0.020 ^ NT - Cauliflowe r 558 0 0.006 ^ NT - Greens, Collard 69 0 0.038 ^ NT - Greens, Kale 61 0 0.038 ^ NT - Orange Juice 44 0 0.010 ^ NT - Potatoes, Frozen 744 457 61.4 0.017 - 3.5 0.010 ^ 50 30 Spinach 511 0 0.006 - 0.010 NT - Sweet Peas, Frozen 528 0 0.006 - 0.011 NT - Watermelon 189 0 0.011 ^ NT - Winter Squash 261 0 0.017 ^ NT - TOTA L 4,156 457

Chlorpyrifos (insecticide)

Applesauce 714 0 0.001 - 0.004 1.5 1 Bananas 742 0 0.004 ^ 0.1 2 Broccoli 185 13 7.0 0.002 - 0.006 0.001 ^ 1 2 Carrots 743 1 0.1 0.024 ^ 0.004 - 0.020 0.1 0.1 Cauliflowe r 558 1 0.2 0.002 ^ 0.001 ^ 1 0.05 Cranberries 316 71 22.5 0.005 - 0.093 0.004 - 0.005 1.0 - Eggplan t 740 1 0.1 0.013 ^ 0.008 ^ 0.1 - Grapefrui t 743 6 0.8 0.001 - 0.007 0.0008 - 0.004 1.0 1 Greens, Collard 86 4 4.7 0.007 - 0.035 0.004 ^ 0.1 - Greens, Kale 98 11 11.2 0.007 - 0.067 0.004 ^ 0.1 - Orange Juice 557 3 0.5 0.007 ^ 0.004 ^ 1.0 1 Peaches 90 12 13.3 0.007 - 0.054 0.004 ^ 0.05 0.5 Plums (X-2) 515 88 17.1 0.005 - 0.18 0.003 - 0.008 0.05 0.5 Plums, Dried (Prunes) 224 0 0.003 - 0.008 0.05 0.5 Potatoes, Frozen 744 0 0.004 ^ 0.1 2 Raisins 372 3 0.8 0.007 - 0.022 0.004 - 0.008 0.5 0.1 Spinach 511 16 3.1 0.002 - 0.093 0.001 - 0.004 0.1 - Summer Squash 186 1 0.5 0.007 ^ 0.004 ^ 0.1 - Sweet Peas, Frozen 744 0 0.004 - 0.005 0.05 0.01 Watermelon 550 0 0.004 ^ 0.1 - Winter Squash 369 8 2.2 0.007 ^ 0.004 ^ 0.1 - TOTA L 9,787 239
Appendix B. Page 9 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Clofentezine (insecticide)

Applesauce 730 0 0.007 - 0.022 0.5 0.5 Broccoli 169 0 0.022 - 0.093 NT - Cauliflowe r 328 0 0.022 - 0.045 NT - Peaches 19 0 0.007 - 0.023 1.0 0.2 Raisins 108 0 0.007 ^ 1.0 1 Spinach 366 0 0.022 ^ NT - TOTA L 1,720 0

Clomazone (herbicide)

Applesauce 528 0 0.002 ^ NT - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Orange Juice 44 0 0.008 ^ NT - Spinach 366 0 0.002 ^ NT - Summer Squash 186 0 0.008 - 0.020 0.1 - Sweet Peas, Frozen 744 0 0.006 - 0.015 0.05 - Watermelon 550 0 0.005 - 0.015 0.05 - Winter Squash 369 0 0.008 - 0.040 0.1 - TOTA L 4,056 0

Clothianidin (insecticide) (also a metabolite of Thiamethoxam)

Applesauce 216 0 0.002 ^ 1.0 - Bananas 526 0 0.010 - 0.050 NT - Carrots 744 0 0.002 - 0.014 NT - Cranberries 84 0 0.002 ^ NT - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale (V-1) 61 1 1.6 0.011 ^ 0.010 ^ NT - Peaches 90 0 0.002 - 0.003 NT - Potatoes, Frozen 744 22 3.0 0.003 - 0.008 0.002 - 0.003 0.05 - Summer Squash (V-3) 54 3 5.6 0.003 ^ 0.002 ^ NT - Sweet Peas, Frozen 524 0 0.002 - 0.010 NT - Watermelon (V-3) 370 3 0.8 0.003 - 0.040 0.002 - 0.010 NT - TOTA L 3,482 29

Coumaphos (insecticide)

Applesauce 528 0 0.006 ^ NT - Spinach 366 0 0.006 ^ NT - TOTA L 894 0

Coumaphos oxygen analog (metabolite of Coumaphos)

Applesauce 528 0 0.008 ^ NT - Spinach 306 0 0.008 ^ NT - TOTA L 834 0

Cyazofamid (fungicide) Potatoes, Frozen 396 0 0.001 ^ 0.02 - TOTA L 396 0

Cycloate (herbicide)

Applesauce 528 0 0.0006 - 0.002 NT - Broccoli 185 0 0.0006 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 3 0.8 0.002 - 0.007 0.002 ^ 0.05 - Winter Squash 261 0 0.016 ^ NT - TOTA L 1,898 3

Cyfluthrin (insecticide)

Applesauce 744 0 0.030 - 0.041 0.5 0.5 Bananas 742 0 0.023 - 0.030 0.05 - Broccoli 185 0 0.14 ^ 2.5 -

Appendix B. Page 10 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Carrots 743 0 0.030 - 0.050 0.20 - Cauliflowe r 558 0 0.14 ^ 2.5 - Cranberries 316 0 0.030 - 0.050 0.05 - Eggplan t 740 0 0.067 ^ 0.5 - Grapefrui t 743 0 0.021 - 0.030 0.2 - Greens, Collard 17 0 0.030 ^ 7.0 - Greens, Kale 37 0 0.030 ^ 7.0 - Orange Juice 557 0 0.030 - 0.060 0.2 - Peaches 90 0 0.015 - 0.030 0.3 - Plums 515 0 0.068 ^ 0.3 - Plums, Dried (Prunes) 224 0 0.068 ^ 0.3 - Potatoes, Frozen 744 0 0.015 - 0.030 0.01 - Raisins 372 0 0.050 - 0.060 3.5 - Spinach 511 1 0.2 0.51 ^ 0.030 - 0.27 6.0 - Summer Squash 186 0 0.030 - 0.050 0.1 - Sweet Peas, Frozen 744 0 0.015 - 0.030 0.25 - Watermelon 550 0 0.023 - 0.030 0.1 - Winter Squash 369 0 0.030 ^ 0.1 - TOTA L 9,687 1

Cyhalothrin, Total (Cyhalothrin-L + R157836 epimer) (insecticide) **

Applesauce 528 0 0.006 ^ 0.3 0.2 Bananas 526 0 0.015 ^ 0.01 - Broccoli 185 0 0.006 ^ 0.4 - Carrots 527 0 0.008 ^ 0.01 - Cauliflowe r 558 0 0.006 ^ 0.4 - Cranberries 232 0 0.015 ^ 0.01 - Grapefrui t 527 0 0.008 ^ 0.01 - Greens, Collard (X-1 ) 69 1 1.4 0.14 ^ 0.050 ^ 0.01 - Greens, Kale 61 0 0.050 ^ 0.01 - Raisins 264 0 0.050 ^ 0.01 - Spinach (X-1) 366 2 0.5 0.010 - 0.12 0.006 ^ 0.01 - Summer Squash 132 0 0.025 ^ 0.01 - Sweet Peas, Frozen 308 0 0.015 ^ 0.2 - Watermelon 369 0 0.015 ^ 0.01 - Winter Squash 261 0 0.016 ^ 0.01 - TOTA L 4,913 3

Cyhalothrin, Lambda (insecticide) (includes gamma isomer)

Applesauce 216 0 0.006 ^ 0.3 0.2 Bananas 216 0 0.006 ^ 0.01 - Carrots 216 0 0.006 ^ 0.01 - Cranberries 84 0 0.006 ^ 0.01 - Eggplan t 740 1 0.1 0.063 ^ 0.038 ^ 0.20 - Grapefrui t 216 0 0.006 ^ 0.01 - Greens, Collard 17 0 0.006 ^ 0.01 - Greens, Kale (X-2) 37 2 5.4 0.027 - 0.050 0.006 ^ 0.01 - Orange Juice 557 0 0.006 - 0.060 0.01 - Peaches 90 10 11.1 0.005 - 0.020 0.003 - 0.006 0.50 - Plums 515 0 0.039 ^ 0.50 - Plums, Dried (Prunes) 224 0 0.039 ^ 0.50 - Potatoes, Frozen 744 0 0.003 - 0.006 0.01 0.02 Raisins 108 0 0.012 ^ 0.01 - Spinach (X-1) 145 2 1.4 0.010 - 0.14 0.006 ^ 0.01 - Summer Squash 54 0 0.006 ^ 0.01 - Sweet Peas, Frozen 436 0 0.006 - 0.012 0.2 - Watermelon 181 0 0.006 ^ 0.01 - Winter Squash 108 0 0.006 ^ 0.01 - TOTA L 4,904 15

Cyhalothrin, epimer R157836 (insecticide)

Applesauce 216 0 0.006 ^ 0.3 0.2 Bananas 216 0 0.006 ^ 0.01 -
Appendix B. Page 11 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Carrots 216 1 0.5 0.010 ^ 0.006 ^ 0.01 - Cranberries 84 0 0.006 ^ 0.01 - Eggplan t 740 0 0.038 - 0.077 0.20 - Grapefrui t 216 0 0.006 ^ 0.01 - Greens, Collard 17 0 0.006 ^ 0.01 - Greens, Kale 37 0 0.006 ^ 0.01 - Orange Juice 557 0 0.006 - 0.060 0.01 - Peaches 90 0 0.003 - 0.006 0.50 - Plums 515 0 0.047 ^ 0.50 - Plums, Dried (Prunes) 224 0 0.047 ^ 0.50 - Potatoes, Frozen 744 0 0.003 - 0.006 0.01 0.02 Raisins 108 0 0.012 ^ 0.01 - Spinach 145 1 0.7 0.018 ^ 0.006 ^ 0.01 - Summer Squash 54 0 0.006 ^ 0.01 - Sweet Peas, Frozen 436 0 0.006 - 0.012 0.2 - Watermelon 181 0 0.006 ^ 0.01 - Winter Squash 108 0 0.006 ^ 0.01 - TOTA L 4,904 2

Cypermethrin (insecticide)

Applesauce 744 0 0.030 - 0.17 NT 2 Bananas 526 0 0.023 ^ NT - Broccoli 185 0 0.051 ^ 2.0 1 Carrots 743 0 0.030 - 0.059 NT 0.05 Cauliflowe r 558 0 0.17 ^ 2.0 1 Cranberries 316 0 0.030 - 0.18 NT 0.5 Eggplan t 740 0 0.057 ^ 0.2 0.2 Greens, Collard 86 8 9.3 0.083 - 2.3 0.030 - 0.075 14.0 1 Greens, Kale 98 18 18.4 0.050 - 1.3 0.030 - 0.075 14.0 1 Orange Juice 396 0 0.035 ^ NT 2 Peaches 90 0 0.015 - 0.030 1 2 Plums 515 0 0.067 ^ NT 1 Plums, Dried (Prunes) 224 0 0.067 ^ NT 1 Potatoes, Frozen 744 0 0.015 - 0.030 NT 0.05 Spinach 511 78 15.3 0.050 - 3.6 0.030 - 0.17 10.00 2 Summer Squash 186 0 0.030 - 0.066 0.2 - Sweet Peas, Frozen 744 0 0.015 - 0.030 0.5 0.05 Watermelon 550 0 0.020 - 0.030 NT - Winter Squash 369 0 0.030 ^ NT - TOTA L 8,325 104

Cyprodinil (fungicide)

Applesauce 216 0 0.008 ^ 0.1 0.05 Bananas 526 0 0.008 ^ NT - Carrots 743 0 0.008 - 0.009 0.75 - Greens, Collard 86 0 0.008 ^ 10.0 - Greens, Kale 98 0 0.008 ^ 10.0 - Peaches 19 3 15.8 0.087 - 0.20 0.008 ^ 2.0 2 Plums 515 1 0.2 0.12 ^ 0.008 ^ 2.0 2 Plums, Dried (Prunes) 224 5 2.2 0.013 - 0.058 0.008 ^ 2.0 5 Raisins 372 7 1.9 0.027 - 0.41 0.016 - 0.050 3.0 5 Sweet Peas, Frozen 308 0 0.008 ^ NT - Watermelon 189 0 0.008 ^ NT - TOTA L 3,296 16

Cyromazine (insect growth regulator)

Applesauce 528 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ 1.0 - Cauliflowe r 558 0 0.002 ^ 10.0 - Spinach 366 63 17.2 0.004 - 1.4 0.002 ^ 7.0 - TOTA L 1,637 63

Appendix B. Page 12 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm DCPA (herbicide)

Applesauce 528 0 0.0007 ^ NT - Bananas 526 0 0.002 ^ NT - Broccoli 185 86 46.5 0.001 - 0.028 0.0007 ^ 5 - Cauliflowe r 558 41 7.3 0.001 - 0.005 0.0007 ^ 5 - Eggplan t 740 0 0.006 ^ 1 - Greens, Collard 17 13 76.5 0.005 - 0.22 0.003 ^ 5 - Greens, Kale 37 24 64.9 0.005 - 0.41 0.003 ^ 5 - Orange Juice 396 0 0.006 ^ NT - Peaches 71 0 0.003 ^ NT - Potatoes, Frozen 744 0 0.003 ^ 2 - Spinach (V-33) 367 33 9.0 0.001 - 0.043 0.0007 - 0.003 NT - Summer Squash 186 0 0.003 - 0.030 1 - Sweet Peas, Frozen (V-2) 529 2 0.4 0.004 - 0.005 0.002 - 0.003 NT - Watermelon 550 0 0.002 - 0.008 1 - Winter Squash 369 0 0.003 - 0.007 1 - TOTA L 5,803 199

DDD o,p' (metabolite of DDT)

Applesauce 528 0 0.001 ^ 0.1 AL - Broccoli 185 0 0.001 ^ 0.5 AL - Cauliflowe r 558 0 0.001 ^ 0.5 AL - Spinach 366 1 0.3 0.002 ^ 0.001 ^ 0.5 AL - TOTA L 1,637 1

DDD p,p' (metabolite of DDT)

Applesauce 729 0 0.001 - 0.004 0.1 AL - Bananas 526 0 0.005 ^ NT - Broccoli 185 0 0.001 ^ 0.5 AL - Carrots 743 1 0.1 0.016 ^ 0.004 - 0.006 3 AL 0.2 Cauliflowe r 542 0 0.001 ^ 0.5 AL - Cranberries 316 0 0.004 - 0.006 NT - Eggplan t 740 0 0.005 ^ 0.1 AL - Grapefrui t 743 0 0.004 - 0.016 0.1 AL - Greens, Collard 17 0 0.004 ^ 0.5 AL - Greens, Kale 37 0 0.004 ^ 0.5 AL - Orange Juice 557 0 0.004 - 0.008 0.1 AL - Peaches 90 0 0.004 ^ 0.2 AL - Plums 515 0 0.007 ^ 0.2 AL - Plums, Dried (Prunes) 224 0 0.007 ^ 0.2 AL - Potatoes, Frozen 744 0 0.004 ^ 1 AL - Raisins 372 0 0.008 - 0.030 0.05 AL - Spinach 511 0 0.001 - 0.004 0.5 AL - Summer Squash 186 0 0.004 - 0.030 0.1 AL - Sweet Peas, Frozen 744 0 0.004 - 0.005 NT - Watermelon 550 0 0.004 - 0.008 0.1 AL - Winter Squash 369 0 0.004 - 0.020 0.1 AL - TOTA L 9,440 1

DDE p,p' (metabolite of DDT)

Applesauce 744 0 0.002 - 0.004 0.1 AL - Bananas 526 0 0.005 ^ NT - Broccoli 185 2 1.1 0.003 ^ 0.002 ^ 0.5 AL - Carrots 743 204 27.5 0.003 - 0.12 0.003 - 0.004 3 AL 0.2 Cauliflowe r 542 0 0.002 ^ 0.5 AL - Cranberries 316 0 0.003 - 0.004 NT - Eggplan t 740 0 0.005 ^ 0.1 AL - Grapefrui t 743 0 0.004 - 0.010 0.1 AL - Greens, Collard 17 0 0.004 ^ 0.5 AL - Greens, Kale 37 12 32.4 0.007 - 0.038 0.004 ^ 0.5 AL - Orange Juice 557 0 0.004 - 0.007 0.1 AL - Peaches 90 1 1.1 0.007 ^ 0.004 ^ 0.2 AL - Plums 515 0 0.006 ^ 0.2 AL -
Appendix B. Page 13 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Plums, Dried (Prunes) 224 0 0.006 ^ 0.2 AL - Potatoes, Frozen 744 0 0.004 ^ 1 AL - Raisins 372 0 0.008 - 0.030 0.05 AL - Spinach 511 175 34.2 0.003 - 0.045 0.002 - 0.004 0.5 AL - Summer Squash 186 1 0.5 0.007 ^ 0.004 - 0.015 0.1 AL - Sweet Peas, Frozen 744 0 0.004 - 0.015 NT - Watermelon 550 1 0.2 0.007 ^ 0.004 - 0.005 0.1 AL - Winter Squash 369 2 0.5 0.007 - 0.012 0.004 - 0.007 0.1 AL - TOTA L 9,455 398

DDT o,p' (insecticide)

Applesauce 528 0 0.001 ^ 0.1 AL - Broccoli 185 0 0.001 ^ 0.5 AL - Cauliflowe r 558 0 0.001 ^ 0.5 AL - Spinach 366 19 5.2 0.002 ^ 0.001 ^ 0.5 AL - TOTA L 1,637 19

DDT p,p' (insecticide)

Applesauce 744 0 0.002 - 0.004 0.1 AL - Bananas 526 0 0.005 ^ NT - Broccoli 185 0 0.002 ^ 0.5 AL - Carrots 743 4 0.5 0.007 ^ 0.004 - 0.030 3 AL 0.2 Cauliflowe r 558 0 0.002 ^ 0.5 AL - Cranberries 316 0 0.004 - 0.016 NT - Eggplan t 740 0 0.007 ^ 0.1 AL - Grapefrui t 743 0 0.004 - 0.029 0.1 AL - Greens, Collard 17 0 0.004 ^ 0.5 AL - Greens, Kale 37 12 32.4 0.007 ^ 0.004 ^ 0.5 AL - Orange Juice 557 0 0.004 - 0.008 0.1 AL - Peaches 90 0 0.004 ^ 0.2 AL - Plums 515 0 0.010 ^ 0.2 AL - Plums, Dried (Prunes) 224 0 0.010 ^ 0.2 AL - Potatoes, Frozen 744 0 0.004 ^ 1 AL - Raisins 108 0 0.008 ^ 0.05 AL - Spinach 511 44 8.6 0.003 - 0.012 0.002 - 0.004 0.5 AL - Summer Squash 54 1 1.9 0.007 ^ 0.004 ^ 0.1 AL - Sweet Peas, Frozen 744 0 0.004 - 0.005 NT - Watermelon 370 0 0.004 - 0.005 0.1 AL - Winter Squash 108 0 0.004 ^ 0.1 AL - TOTA L 8,634 61

Deltamethrin (includes parent Tralomethrin) (insecticide)

Applesauce 744 0 0.015 - 0.33 0.2 0.2 Bananas 742 0 0.015 - 0.023 0.05 - Carrots 743 0 0.015 - 0.030 0.2 0.02 Cauliflowe r 542 0 0.080 - 0.33 0.05 0.1 Cranberries 316 0 0.015 - 0.061 0.05 - Eggplan t 740 0 0.052 ^ 0.3 - Grapefrui t 743 0 0.015 - 0.055 0.05 0.02 Greens, Collard 86 0 0.015 - 0.075 0.05 2 Greens, Kale 98 0 0.015 - 0.075 0.05 2 Orange Juice 557 0 0.015 - 0.018 0.05 0.02 Peaches 90 0 0.008 - 0.015 0.05 0.05 Plums 515 0 0.052 ^ 0.05 0.05 Plums, Dried (Prunes) 224 0 0.052 ^ 0.05 0.05 Potatoes, Frozen 744 0 0.008 - 0.015 0.04 0.01 Raisins 372 0 0.030 - 0.050 0.05 0.2 Spinach 145 0 0.015 ^ 0.05 2 Summer Squash 186 0 0.015 - 0.050 0.2 0.2 Sweet Peas, Frozen 524 0 0.015 - 0.023 0.05 0.2 Watermelon 550 1 0.2 0.025 ^ 0.015 - 0.077 0.2 0.2 Winter Squash 369 0 0.015 - 0.24 0.2 0.2 TOTA L 9,030 1
Appendix B. Page 14 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Diazinon (insecticide)

Applesauce 744 0 0.002 ^ 0.5 0.3 Bananas 742 0 0.002 - 0.005 0.2 - Carrots 743 25 3.4 0.003 - 0.11 0.002 - 0.004 0.75 0.5 Cranberries 84 0 0.002 ^ 0.5 - Grapefrui t 743 0 0.001 - 0.002 0.7 - Greens, Collard 86 2 2.3 0.008 ^ 0.002 - 0.005 0.7 0.05 Greens, Kale 98 5 5.1 0.018 - 0.14 0.002 - 0.005 0.7 0.05 Orange Juice 557 0 0.002 ^ 0.7 - Peaches 90 11 12.2 0.003 - 0.033 0.002 ^ 0.7 0.2 Plums 515 2 0.4 0.012 - 0.021 0.007 ^ 0.5 1 Plums, Dried (Prunes) 224 0 0.007 ^ 0.5 1 Potatoes, Frozen 744 0 0.002 ^ 0.1 0.01 Raisins 372 0 0.004 ^ 0.75 - Spinach 511 4 0.8 0.003 ^ 0.002 ^ 0.7 0.5 Summer Squash 186 0 0.002 - 0.004 0.5 0.05 Sweet Peas, Frozen 744 0 0.002 - 0.005 0.5 0.2 Watermelon 550 0 0.002 - 0.005 0.75 - Winter Squash 369 0 0.002 - 0.007 0.75 0.05 TOTA L 8,102 49

Diazinon oxygen analog (metabolite of Diazinon)

Applesauce 744 0 0.003 ^ NT - Bananas 742 0 0.001 - 0.003 NT - Broccoli 155 0 0.003 ^ NT - Carrots 744 0 0.001 - 0.003 NT - Cauliflowe r 558 0 0.003 ^ NT - Cranberries 84 0 0.003 ^ NT - Grapefrui t 216 0 0.003 ^ NT - Greens, Collard 86 0 0.001 - 0.003 NT - Greens, Kale 98 0 0.001 - 0.003 NT - Orange Juice 557 0 0.003 ^ NT - Peaches 90 0 0.003 ^ NT - Plums 515 0 0.011 ^ NT - Plums, Dried (Prunes) 224 0 0.011 ^ NT - Potatoes, Frozen 744 0 0.003 ^ NT - Raisins 372 0 0.004 - 0.006 NT - Spinach (V-1) 511 1 0.2 0.005 ^ 0.003 ^ NT - Summer Squash 186 0 0.003 - 0.004 NT - Sweet Peas, Frozen 744 0 0.001 - 0.010 NT - Watermelon 550 0 0.001 - 0.012 NT - Winter Squash 369 0 0.003 - 0.016 NT - TOTA L 8,289 1

Dichlobenil (herbicide)

Applesauce 744 0 0.005 - 0.019 0.5 - Bananas 526 0 0.013 ^ NT - Broccoli 169 0 0.019 ^ NT - Cauliflowe r 558 0 0.019 ^ NT - Cranberries 84 0 0.005 ^ 0.1 - Greens, Collard 69 0 0.013 ^ NT - Greens, Kale 61 0 0.013 ^ NT - Orange Juice 396 0 0.005 ^ NT - Peaches 90 0 0.005 ^ 0.15 - Plums 515 0 0.011 ^ 0.15 - Plums, Dried (Prunes) 224 0 0.011 ^ 0.15 - Raisins 372 0 0.010 - 0.030 0.15 - Spinach 366 0 0.019 ^ NT - Sweet Peas, Frozen 308 0 0.013 ^ NT - Watermelon 189 0 0.013 ^ NT - TOTA L 4,671 0

Appendix B. Page 15 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Dichlorvos - DDVP (insecticide) (also a metabolite of Naled)

Applesauce 744 0 0.002 - 0.003 0.5 - Bananas 720 0 0.002 ^ 0.5 - Cranberries 84 0 0.002 ^ 0.5 - Eggplan t 740 0 0.004 ^ 0.5 - Grapefrui t 743 0 0.0006 - 0.002 3 - Greens, Collard 86 0 0.002 - 0.050 3 - Greens, Kale 98 0 0.002 - 0.050 3 - Orange Juice 557 0 0.002 ^ 3 - Peaches 90 0 0.002 ^ 0.5 - Plums 515 0 0.004 ^ 0.5 - Plums, Dried (Prunes) 224 0 0.004 ^ 0.5 - Potatoes, Frozen 744 0 0.002 ^ 0.5 - Raisins 372 0 0.003 - 0.004 0.5 - Spinach 511 0 0.002 - 0.003 3 - Summer Squash 186 0 0.002 - 0.003 0.5 - Sweet Peas, Frozen 744 0 0.002 - 0.006 0.5 - Watermelon 550 0 0.002 - 0.003 0.5 - Winter Squash 369 0 0.002 - 0.003 0.5 - TOTA L 8,077 0

Dicloran (fungicide)

Applesauce 528 0 0.002 ^ NT - Bananas 526 0 0.004 ^ NT - Broccoli (V-5) 185 5 2.7 0.003 ^ 0.002 ^ NT - Carrots 743 0 0.006 - 0.025 10 15 Cauliflowe r 558 0 0.002 ^ NT - Cranberries 232 0 0.050 ^ NT - Greens, Collard 56 0 0.013 ^ NT - Greens, Kale (V-2) 53 2 3.8 0.010 - 0.020 0.006 - 0.013 NT - Orange Juice 396 0 0.008 ^ NT - Peaches 90 3 3.3 0.63 - 2.3 0.006 ^ 20 7 Plums 515 8 1.6 0.017 - 0.32 0.010 ^ 15 - Plums, Dried (Prunes) 224 1 0.4 0.037 ^ 0.010 ^ 15 - Potatoes, Frozen 744 0 0.006 ^ 0.25 - Raisins 372 0 0.012 - 0.030 10 7 Spinach (V-12) 366 12 3.3 0.003 - 0.010 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.002 - 0.004 NT - Watermelon 189 0 0.004 ^ NT - Winter Squash 261 0 0.010 ^ NT - TOTA L 6,566 31

Dicofol o,p' (insecticide)

Applesauce 528 0 0.003 ^ 5 - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Cranberries 232 0 0.049 ^ NT - Spinach 366 0 0.003 ^ NT - TOTA L 1,869 0

Dicofol p,p' (insecticide) (isomer of Dicofol o,p')

Applesauce 744 0 0.003 - 0.010 5 - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Cranberries 232 0 0.30 ^ NT - Eggplan t 740 1 0.1 0.095 ^ 0.010 ^ 5 - Grapefrui t 743 0 0.010 - 0.022 10 5 Orange Juice 557 0 0.010 ^ 10 5 Peaches 90 0 0.010 ^ 10 5 Plums 515 4 0.8 0.040 ^ 0.024 ^ 5 1 Plums, Dried (Prunes) 224 0 0.024 ^ 5 1 Raisins 372 3 0.8 0.22 - 0.60 0.020 - 0.050 5 5
Appendix B. Page 16 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Spinach 366 0 0.003 ^ NT - Summer Squash 186 0 0.010 - 0.030 5 1 Sweet Peas, Frozen 220 0 0.009 ^ NT - Watermelon 550 0 0.010 - 0.015 5 - Winter Squash 369 0 0.010 - 0.018 5 1 TOTA L 7,177 8

Dieldrin (insecticide) (also a metabolite of Aldrin)

Applesauce 744 0 0.003 - 0.005 0.03 AL 0.05 Bananas 742 0 0.003 - 0.005 0.02 AL - Broccoli 185 0 0.005 ^ 0.03 AL - Carrots 743 1 0.1 0.014 ^ 0.003 - 0.015 0.1 AL 0.1 Cauliflowe r 558 0 0.005 ^ 0.03 AL - Cranberries 316 0 0.003 - 0.030 NT - Eggplan t 740 0 0.004 ^ 0.05 AL - Grapefrui t 743 0 0.003 - 0.004 0.02 AL 0.05 Greens, Collard 17 0 0.003 ^ 0.05 AL 0.05 Greens, Kale 37 0 0.003 ^ 0.05 AL 0.05 Orange Juice 557 0 0.003 - 0.006 0.02 AL 0.05 Peaches 90 0 0.003 ^ 0.02 AL - Plums 515 0 0.005 ^ 0.3 AL - Plums, Dried (Prunes) 224 0 0.005 ^ 0.3 AL - Potatoes, Frozen 744 3 0.4 0.005 ^ 0.003 ^ 0.1 AL 0.1 Spinach 511 1 0.2 0.005 ^ 0.003 - 0.005 0.05 AL 0.05 Summer Squash 186 17 9.1 0.005 - 0.045 0.003 ^ 0.1 AL 0.1 Sweet Peas, Frozen 744 0 0.003 - 0.015 0.03 AL 0.05 Watermelon 550 0 0.003 - 0.005 0.1 AL 0.1 Winter Squash 369 6 1.6 0.005 - 0.055 0.003 - 0.018 0.1 AL 0.1 TOTA L 9,315 28

Difenoconazole (fungicide) Bananas 526 0 0.005 ^ 0.2 - Sweet Peas, Frozen 286 0 0.005 ^ NT - Watermelon 189 0 0.005 ^ NT - Winter Squash 261 0 0.072 ^ NT - TOTA L 1,262 0

Diflubenzuron (insecticide)

Applesauce (V-24) 528 24 4.5 0.011 ^ 0.007 ^ NT 5 Broccoli 169 0 0.007 ^ NT - Cauliflowe r 558 0 0.007 ^ NT - Grapefrui t 216 0 0.007 ^ 0.5 0.5 Orange Juice 557 0 0.001 - 0.010 0.5 0.5 Peaches 90 0 0.001 - 0.007 0.07 - Potatoes, Frozen 176 0 0.001 ^ NT - Spinach 366 0 0.007 ^ NT - TOTA L 2,660 24

Dimethenamid (herbicide) Potatoes, Frozen 528 0 0.001 ^ 0.01 0.01 Winter Squash 261 0 0.016 ^ NT - TOTA L 789 0

Dimethoate (insecticide) (parent of Omethoate)

Applesauce 744 3 0.4 0.004 ^ 0.002 ^ 2 - Bananas 526 0 0.005 ^ NT - Broccoli 155 1 0.6 0.013 ^ 0.008 ^ 2 - Cauliflowe r 558 17 3.0 0.004 - 0.067 0.002 ^ 2 2 Grapefrui t 743 0 0.002 - 0.003 2 5 Greens, Collard 86 0 0.002 - 0.005 2 - Greens, Kale 98 0 0.002 - 0.005 2 - Orange Juice 557 1 0.2 0.003 ^ 0.002 ^ 2 5

Appendix B. Page 17 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Potatoes, Frozen 744 2 0.3 0.003 ^ 0.002 ^ 0.2 0.05 Raisins 372 0 0.004 - 0.005 1 - Spinach 511 14 2.7 0.003 - 1.0 0.002 ^ 2 - Summer Squash 54 0 0.002 ^ NT - Sweet Peas, Frozen 744 90 12.1 0.003 - 0.064 0.002 - 0.005 2 1 Watermelon 550 10 1.8 0.003 - 0.21 0.002 - 0.005 1 - Winter Squash 261 0 0.007 ^ NT - TOTA L 6,703 138

Dimethomorph (fungicide)

Applesauce 528 0 0.002 ^ NT - Broccoli 185 3 1.6 0.003 ^ 0.002 ^ 2.0 - Cauliflowe r 558 0 0.002 ^ NT - Eggplan t 740 0 0.084 ^ 1.5 - Greens, Collard 17 1 5.9 0.003 ^ 0.002 ^ 20.0 - Greens, Kale 37 4 10.8 0.015 - 0.039 0.002 ^ 20.0 - Orange Juice 44 0 0.030 ^ NT - Potatoes, Frozen 744 0 0.001 - 0.002 0.05 - Raisins 372 0 0.002 - 0.10 6.0 - Spinach (V-8) 366 8 2.2 0.003 - 0.010 0.002 ^ NT - Summer Squash 186 0 0.002 - 0.10 0.5 - Watermelon 361 0 0.002 - 0.040 0.5 - TOTA L 4,138 16

Dinotefuran (insecticide)

Applesauce 176 0 0.006 ^ NT - Broccoli 185 3 1.6 0.021 - 0.037 0.006 ^ 1.4 - Cauliflowe r 46 0 0.006 ^ 1.4 - Greens, Collard (V-5) 69 5 7.2 0.017 - 0.29 0.010 ^ NT - Greens, Kale (V-1) 61 1 1.6 0.45 ^ 0.010 ^ NT - Potatoes, Frozen 744 0 0.001 - 0.005 0.05 - Raisins 108 0 0.005 ^ 2.5 - Spinach 163 0 0.005 - 0.006 5.0 - Summer Squash 54 0 0.005 ^ 0.5 - Watermelon 181 0 0.0005 - 0.005 0.5 - TOTA L 1,787 9

Diphenamid (herbicide)

Applesauce 528 0 0.010 ^ NT - Broccoli 185 0 0.010 ^ NT - Cauliflowe r 558 0 0.010 ^ NT - Orange Juice 44 0 0.006 ^ NT - Spinach 366 0 0.010 ^ NT - Sweet Peas, Frozen 220 0 0.015 ^ NT - Winter Squash 261 0 0.018 ^ NT - TOTA L 2,162 0

Diphenylamine - DPA (fungicide)

Applesauce 744 225 30.2 0.005 - 0.16 0.003 - 0.010 10 10 Bananas (V-1) 526 1 0.2 0.10 ^ 0.015 ^ NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Greens, Collard 69 0 0.015 ^ NT - Greens, Kale 61 0 0.015 ^ NT - Orange Juice 44 0 0.010 ^ NT - Spinach 366 0 0.003 ^ NT - Sweet Peas, Frozen 528 0 0.015 - 0.030 NT - Watermelon 189 0 0.015 ^ NT - Winter Squash 261 0 0.008 ^ NT - TOTA L 3,531 226

Appendix B. Page 18 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Disulfoton (insecticide)

Applesauce 528 0 0.002 ^ NT - Bananas 526 0 0.004 ^ NT - Broccoli 155 0 0.002 ^ 0.75 0.5 Cauliflowe r 558 1 0.2 0.004 ^ 0.002 ^ 0.75 0.5 Potatoes, Frozen 744 0 0.003 ^ 0.75 0.5 Spinach 511 0 0.002 - 0.003 0.75 0.5 Sweet Peas, Frozen 744 0 0.003 - 0.006 0.75 0.1 Watermelon 189 0 0.004 ^ NT - Winter Squash 261 0 0.007 ^ NT 0.5 TOTA L 4,216 1

Disulfoton sulfone (metabolite of Disulfoton)

Applesauce 528 0 0.006 ^ NT - Bananas 526 0 0.004 ^ NT - Broccoli 185 0 0.006 ^ 0.75 0.5 Cauliflowe r 558 1 0.2 0.010 ^ 0.006 ^ 0.75 0.5 Potatoes, Frozen 744 0 0.004 ^ 0.75 0.5 Spinach 511 0 0.004 - 0.006 0.75 0.5 Sweet Peas, Frozen 744 0 0.004 - 0.010 0.75 0.1 Watermelon 189 0 0.004 ^ NT - Winter Squash 261 0 0.009 ^ NT 0.5 TOTA L 4,246 1

Diuron (herbicide)

Applesauce 744 0 0.008 - 0.012 1 - Bananas 216 0 0.012 ^ 0.1 - Broccoli 185 0 0.008 ^ NT - Cauliflowe r 558 0 0.008 ^ NT - Grapefrui t 216 0 0.012 ^ 1 - Orange Juice 557 0 0.001 - 0.012 1 - Peaches 90 0 0.001 - 0.012 0.1 - Potatoes, Frozen 744 0 0.001 - 0.012 1 - Raisins 108 0 0.012 ^ 1 - Spinach 366 0 0.008 ^ NT - Sweet Peas, Frozen 216 0 0.012 ^ 1 - TOTA L 4,000 0

Endosulfan I (insecticide)

Applesauce 743 0 0.003 - 0.006 2.0 1 Bananas 526 0 0.002 ^ NT - Broccoli 185 5 2.7 0.010 - 0.044 0.006 ^ 3.0 0.5 Carrots 743 0 0.003 - 0.025 0.2 0.2 Cauliflowe r 558 0 0.006 ^ 2.0 0.5 Cranberries 232 0 0.026 ^ NT - Eggplan t 740 21 2.8 0.007 - 0.14 0.004 ^ 1.0 - Greens, Collard 17 0 0.003 ^ 2.0 1 Greens, Kale 37 0 0.003 ^ 2.0 1 Orange Juice 396 0 0.005 ^ NT 0.5 Peaches 90 3 3.3 0.005 - 0.032 0.003 ^ 2.0 1 Plums 515 2 0.4 0.007 - 0.059 0.004 ^ 2.0 1 Plums, Dried (Prunes) 224 0 0.004 ^ 2.0 1 Potatoes, Frozen 744 0 0.003 ^ 0.2 0.2 Raisins 372 0 0.003 - 0.006 2.0 1 Spinach 511 3 0.6 0.005 - 0.010 0.003 - 0.006 2.0 2 Summer Squash 186 118 63.4 0.005 - 0.32 0.003 ^ 1.0 0.5 Sweet Peas, Frozen 744 0 0.002 - 0.025 2.0 0.5 Watermelon 519 0 0.002 - 0.007 2.0 - Winter Squash 369 10 2.7 0.005 - 0.030 0.003 - 0.007 1.0 0.5 TOTA L 8,451 162

Appendix B. Page 19 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Endosulfan II (isomer of Endosulfan)

Applesauce 744 0 0.004 - 0.006 2.0 1 Bananas 526 0 0.004 ^ NT - Broccoli 185 2 1.1 0.010 ^ 0.006 ^ 3.0 0.5 Carrots 743 2 0.3 0.007 ^ 0.004 - 0.030 0.2 0.2 Cauliflowe r 558 0 0.006 ^ 2.0 0.5 Cranberries 232 0 0.030 ^ NT - Eggplan t 740 101 13.6 0.007 - 0.11 0.004 ^ 1.0 - Greens, Collard 17 0 0.004 ^ 2.0 1 Greens, Kale 37 0 0.004 ^ 2.0 1 Orange Juice 396 0 0.006 ^ NT 0.5 Peaches 90 5 5.6 0.007 - 0.072 0.004 ^ 2.0 1 Plums 515 2 0.4 0.023 - 0.070 0.004 ^ 2.0 1 Plums, Dried (Prunes) 224 2 0.9 0.007 ^ 0.004 ^ 2.0 1 Potatoes, Frozen 744 0 0.004 ^ 0.2 0.2 Raisins 372 0 0.003 - 0.008 2.0 1 Spinach 511 6 1.2 0.007 - 0.027 0.004 - 0.006 2.0 2 Summer Squash 186 51 27.4 0.005 - 0.029 0.003 - 0.004 1.0 0.5 Sweet Peas, Frozen 744 0 0.004 - 0.025 2.0 0.5 Watermelon 519 0 0.003 - 0.007 2.0 - Winter Squash 369 6 1.6 0.007 - 0.033 0.004 - 0.007 1.0 0.5 TOTA L 8,452 177

Endosulfan sulfate (metabolite of Endosulfan)

Applesauce 744 0 0.004 - 0.020 2.0 1 Bananas 526 0 0.004 ^ NT - Broccoli 171 0 0.020 ^ 3.0 0.5 Carrots 743 2 0.3 0.010 ^ 0.004 - 0.009 0.2 0.2 Cauliflowe r 558 0 0.020 ^ 2.0 0.5 Cranberries 232 0 0.019 ^ NT - Eggplan t 740 129 17.4 0.010 - 0.21 0.006 ^ 1.0 - Greens, Collard 77 3 3.9 0.024 - 1.6 0.004 - 0.015 2.0 1 Greens, Kale 85 1 1.2 0.007 ^ 0.004 - 0.015 2.0 1 Orange Juice 396 0 0.006 ^ NT 0.5 Peaches 90 7 7.8 0.007 - 0.032 0.004 ^ 2.0 1 Plums 515 2 0.4 0.074 - 0.23 0.006 ^ 2.0 1 Plums, Dried (Prunes) 224 2 0.9 0.010 ^ 0.006 ^ 2.0 1 Potatoes, Frozen 744 31 4.2 0.007 - 0.014 0.004 ^ 0.2 0.2 Raisins 372 0 0.003 - 0.008 2.0 1 Spinach 511 25 4.9 0.007 - 0.81 0.004 - 0.020 2.0 2 Summer Squash 186 155 83.3 0.005 - 0.16 0.003 - 0.004 1.0 0.5 Sweet Peas, Frozen 744 0 0.004 - 0.025 2.0 0.5 Watermelon 519 11 2.1 0.005 - 0.016 0.003 - 0.007 2.0 - Winter Squash 369 108 29.3 0.007 - 0.077 0.004 - 0.007 1.0 0.5 TOTA L 8,546 476

Endrin (insecticide)

Applesauce 528 0 0.007 ^ NT - Bananas 526 0 0.002 ^ NT - Broccoli 185 0 0.007 ^ 0.05 AL - Carrots 743 0 0.004 - 0.015 0.05 AL - Cauliflowe r 558 0 0.007 ^ 0.05 AL - Eggplan t 740 0 0.004 ^ 0.05 AL - Greens, Collard 17 0 0.004 ^ 0.05 AL - Greens, Kale 37 1 2.7 0.007 ^ 0.004 ^ 0.05 AL - Peaches 71 0 0.004 ^ NT - Potatoes, Frozen 744 0 0.004 ^ 0.05 AL - Spinach 511 0 0.004 - 0.007 0.05 AL - Summer Squash 186 1 0.5 0.020 ^ 0.004 ^ 0.05 AL 0.05 Sweet Peas, Frozen 744 0 0.002 - 0.015 0.05 AL - Watermelon 550 0 0.002 - 0.004 0.05 AL 0.05 Winter Squash 369 0 0.004 - 0.040 0.05 AL 0.05 TOTA L 6,509 2

Appendix B. Page 20 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm EPTC (herbicide)

Applesauce 528 0 0.064 ^ NT - Broccoli 185 0 0.064 ^ 0.1 - Carrots 528 0 0.008 ^ 0.1 - Cauliflowe r 558 0 0.064 ^ 0.1 - Eggplan t 740 0 0.016 ^ 0.1 - Orange Juice 353 0 0.020 ^ 0.1 - Potatoes, Frozen 528 0 0.020 ^ 0.1 - Spinach 366 0 0.064 ^ 0.1 - TOTA L 3,786 0

Esfenvalerate (insecticide) (isomer of Fenvalerate) Eggplan t 740 0 0.054 ^ 0.05 - Plums 515 0 0.060 ^ 0.05 - Plums, Dried (Prunes) 224 0 0.060 ^ 0.05 - TOTA L 1,479 0

Esfenvalerate+Fenvalerate Total (insecticide)

Applesauce 744 0 0.015 - 0.029 2.0 2 Bananas 742 0 0.015 - 0.038 0.1 - Broccoli 185 0 0.009 - 0.058 2.0 2 Carrots 743 0 0.015 - 0.025 0.5 0.05 Cauliflowe r 542 0 0.029 - 0.12 0.5 2 Cranberries 316 0 0.015 - 0.050 0.05 1 Grapefrui t 743 0 0.013 - 0.015 0.05 2 Greens, Collard 86 0 0.015 - 0.13 10.0 10 Greens, Kale 98 0 0.015 - 0.13 0.05 10 Orange Juice 557 0 0.015 - 0.051 0.05 2 Peaches 90 11 12.2 0.013 - 0.077 0.008 - 0.015 10.0 5 Potatoes, Frozen 744 0 0.008 - 0.015 0.05 0.05 Raisins 372 0 0.030 - 0.050 0.05 1 Spinach 511 0 0.015 - 0.12 0.05 - Summer Squash 186 0 0.015 - 0.050 0.5 0.5 Sweet Peas, Frozen 744 0 0.015 - 0.038 1.0 0.1 Watermelon 370 0 0.015 - 0.038 1.0 0.5 Winter Squash 369 0 0.015 - 0.042 1.0 0.5 TOTA L 8,142 11

Ethalfluralin (herbicide)

Applesauce 513 0 0.017 ^ NT - Broccoli 171 0 0.017 ^ NT - Cauliflowe r 541 0 0.017 ^ NT - Orange Juice 396 0 0.015 ^ NT - Peaches 71 0 0.008 ^ NT - Spinach 352 0 0.017 ^ NT - Summer Squash 186 0 0.007 - 0.050 0.05 - Sweet Peas, Frozen 216 0 0.007 ^ NT - Watermelon 361 0 0.007 - 0.015 0.05 - Winter Squash 369 0 0.007 - 0.040 0.05 - TOTA L 3,176 0

Ethiofencarb (insecticide)

Applesauce 528 0 0.015 ^ NT - Bananas 526 0 0.010 ^ NT - Broccoli 169 0 0.015 ^ NT - Cauliflowe r 558 0 0.015 ^ NT - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Spinach 351 0 0.015 ^ NT - Sweet Peas, Frozen 286 0 0.010 ^ NT - Watermelon 189 0 0.010 ^ NT - TOTA L 2,737 0

Appendix B. Page 21 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Ethion (insecticide)

Applesauce 528 0 0.001 ^ NT - Bananas 526 0 0.005 ^ NT - Broccoli 185 0 0.001 ^ NT - Cauliflowe r 558 0 0.001 ^ NT - Grapefrui t 743 0 0.0007 - 0.002 10 - Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Orange Juice 557 0 0.002 - 0.005 5.0 - Potatoes, Frozen (V-1) 1 1 100.0 0.008 ^ 0.005 ^ NT - Spinach 366 0 0.001 ^ NT - Sweet Peas, Frozen 528 0 0.005 ^ NT - Watermelon 189 0 0.005 ^ NT - Winter Squash 261 0 0.004 ^ NT - TOTA L 4,572 1

Ethion di oxon (metabolite of Ethion)

Grapefrui t 743 0 0.002 - 0.006 10 - Orange Juice 557 0 0.003 - 0.005 5.0 - TOTA L 1,300 0

Ethion mono oxon (metabolite of Ethion)

Applesauce 528 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Grapefrui t 743 0 0.0007 - 0.002 10 - Orange Juice 557 0 0.002 ^ 5.0 - Spinach 366 0 0.002 ^ NT - TOTA L 2,937 0

Ethoprop (insecticide)

Applesauce 528 0 0.0009 ^ NT - Bananas 216 0 0.002 ^ 0.02 0.02 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 396 0 0.002 ^ NT - Potatoes, Frozen 744 0 0.002 ^ 0.02 0.05 Spinach 366 0 0.0009 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 2,641 0

Etoxazole (acaricide)

Applesauce 528 0 0.0001 - 0.0002 0.20 - Broccoli 185 0 0.0001 ^ NT - Cauliflowe r 558 0 0.0001 - 0.0002 NT - Raisins 264 0 0.050 ^ 1.5 - Spinach (V-2) 366 2 0.5 0.0002 ^ 0.0001 ^ NT - TOTA L 1,901 2

Etridiazole (fungicide) Bananas 526 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.002 - 0.003 NT - Watermelon 189 0 0.002 ^ NT - TOTA L 1,243 0

Famoxadone (fungicide) Eggplan t 740 0 0.051 ^ 4.0 - Potatoes, Frozen 216 0 0.002 ^ 0.02 0.02 Raisins 372 0 0.002 - 0.050 4.0 5 Summer Squash 186 0 0.002 - 0.050 0.30 0.2 Watermelon 361 0 0.002 - 0.030 0.30 - Winter Squash 369 2 0.5 0.003 ^ 0.002 - 0.13 0.30 0.2 TOTA L 2,244 2

Appendix B. Page 22 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Fenamidone (fungicide) Potatoes, Frozen 216 0 0.003 ^ 0.02 - Raisins 372 0 0.003 - 0.030 1.0 - Summer Squash 186 0 0.003 - 0.015 0.15 - Watermelon 361 0 0.003 - 0.004 0.15 - TOTA L 1,135 0

Fenamiphos (insecticide)

Applesauce 744 0 0.002 - 0.004 0.25 0.05 Bananas 742 0 0.004 - 0.005 0.10 0.05 Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Eggplan t 740 0 0.007 ^ 0.1 - Grapefrui t 743 0 0.001 - 0.004 0.60 - Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Orange Juice 557 0 0.004 ^ 0.60 - Peaches 90 0 0.004 ^ 0.25 - Raisins 372 0 0.004 - 0.008 0.3 - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 220 0 0.008 ^ NT - Watermelon 189 0 0.005 ^ NT - Winter Squash 261 0 0.006 ^ NT - TOTA L 5,897 0

Fenamiphos sulfone (metabolite of Fenamiphos)

Applesauce 744 0 0.002 - 0.004 0.25 0.05 Bananas 742 0 0.002 - 0.005 0.10 0.05 Eggplan t 740 0 0.016 ^ 0.1 - Grapefrui t 216 0 0.002 ^ 0.60 - Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Orange Juice 557 0 0.002 - 0.008 0.60 - Peaches 90 0 0.002 - 0.008 0.25 - Raisins 372 0 0.002 - 0.004 0.3 - Spinach 351 0 0.004 ^ NT - Sweet Peas, Frozen 528 0 0.005 - 0.012 NT - Watermelon 189 0 0.005 ^ NT - Winter Squash 261 0 0.024 ^ NT - TOTA L 4,920 0

Fenamiphos sulfoxide (metabolite of Fenamiphos)

Applesauce 744 0 0.002 - 0.004 0.25 0.05 Bananas 742 0 0.002 - 0.005 0.10 0.05 Eggplan t 740 0 0.044 ^ 0.1 - Grapefrui t 216 0 0.002 ^ 0.60 - Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Orange Juice 557 0 0.002 - 0.012 0.60 - Peaches 90 0 0.002 - 0.006 0.25 - Raisins 108 0 0.002 ^ 0.3 - Spinach 366 0 0.004 ^ NT - Sweet Peas, Frozen 308 0 0.005 ^ NT - Watermelon 189 0 0.005 ^ NT - TOTA L 4,190 0

Fenarimol (fungicide)

Applesauce 744 0 0.010 - 0.015 0.1 0.3 Bananas 742 0 0.015 - 0.025 0.5 0.2 Broccoli 185 0 0.010 ^ NT - Cauliflowe r 558 0 0.010 ^ NT - Raisins 108 0 0.030 ^ 0.6 0.2

Appendix B. Page 23 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Spinach 366 0 0.010 ^ NT - Sweet Peas, Frozen 308 0 0.025 ^ NT - Watermelon 189 0 0.025 ^ NT - TOTA L 3,200 0

Fenbuconazole (fungicide)

Applesauce 528 0 0.0009 ^ NT 0.1 Bananas 742 0 0.005 - 0.050 0.3 0.05 Broccoli 185 0 0.0009 ^ NT - Cauliflowe r 558 0 0.0009 ^ NT - Grapefrui t 743 4 0.5 0.0007 ^ 0.0004 - 0.030 0.5 - Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Orange Juice 205 0 0.030 ^ NT - Peaches 19 1 5.3 0.050 ^ 0.030 ^ 1.0 0.5 Spinach 366 0 0.0009 ^ NT - Watermelon 189 0 0.005 ^ NT - TOTA L 3,665 5

Fenhexamid (fungicide) Plums 515 40 7.8 0.032 - 0.59 0.019 ^ 2.5 1 Plums, Dried (Prunes) 224 0 0.019 ^ 2.5 1 TOTA L 739 40

Fenitrothion (insecticide)

Applesauce 528 0 0.003 ^ NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Spinach 366 0 0.003 ^ NT - TOTA L 1,637 0

Fenpropathrin (insecticide)

Applesauce 744 0 0.016 - 0.020 5.0 5 Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.016 ^ 3.0 - Cauliflowe r 558 0 0.016 ^ 3.0 - Eggplan t 740 1 0.1 0.037 ^ 0.022 ^ 1.0 0.2 Grapefrui t 743 0 0.007 - 0.020 2.0 - Greens, Collard 17 0 0.020 ^ NT - Greens, Kale 37 0 0.020 ^ NT - Orange Juice 557 0 0.020 ^ 2.0 - Raisins 372 14 3.8 0.067 - 0.39 0.040 - 0.050 10.0 5 Spinach 366 0 0.016 ^ NT - Summer Squash 186 1 0.5 0.033 ^ 0.020 - 0.050 0.5 - Sweet Peas, Frozen 308 0 0.015 ^ 0.02 - Watermelon 550 0 0.015 - 0.020 0.5 - Winter Squash 369 0 0.016 - 0.020 0.5 - TOTA L 6,258 16

Fenpyroximate (acaricide)

Applesauce 528 1 0.2 0.001 ^ 0.0006 ^ 0.40 - Broccoli 185 0 0.0006 ^ NT - Cauliflowe r 558 0 0.0006 ^ NT - Raisins 264 0 0.050 ^ 1.0 - Spinach 366 0 0.0006 ^ NT - TOTA L 1,901 1

Fenthion (insecticide)

Applesauce 528 0 0.002 ^ NT - Bananas (V-1) 526 1 0.2 0.012 ^ 0.008 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT -

Appendix B. Page 24 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Greens, Collard 69 0 0.008 ^ NT - Greens, Kale 61 0 0.008 ^ NT - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.008 - 0.010 NT - Watermelon 189 0 0.008 ^ NT - TOTA L 3,010 1

Fenvalerate (insecticide) (isomer of Esfenvalerate)

Watermelon 180 0 0.030 ^ 1.0 - TOTA L 180 0

Flonicamid (insecticide)

Summer Squash 132 1 0.8 0.045 ^ 0.040 ^ 0.40 - TOTA L 132 1

Fluazifop butyl (herbicide)

Applesauce 528 0 0.0003 ^ NT - Broccoli 185 0 0.0003 ^ NT - Cauliflowe r 558 0 0.0003 ^ NT - Spinach 366 0 0.0003 ^ 6 - TOTA L 1,637 0

Fludioxonil (fungicide)

Applesauce 743 0 0.002 - 0.040 5.0 - Bananas 460 0 0.010 ^ NT - Broccoli 169 0 0.012 - 0.17 2.0 0.7 Carrots 546 0 0.002 - 0.003 0.75 0.7 Cauliflowe r 542 0 0.040 ^ 2.0 - Cranberries 84 0 0.002 ^ NT - Eggplan t 740 0 0.13 ^ 0.01 0.3 Greens, Collard 86 0 0.002 - 0.010 10 - Greens, Kale 98 0 0.002 - 0.010 10 - Orange Juice 44 0 0.015 ^ 10 7 Peaches 90 48 53.3 0.025 - 2.0 0.002 - 0.015 5.0 5 Plums 515 97 18.8 0.18 - 1.8 0.11 ^ 5.0 5 Plums, Dried (Prunes) 224 0 0.11 ^ 5.0 5 Potatoes, Frozen 744 0 0.002 - 0.015 0.02 0.02 Raisins 372 1 0.3 0.13 ^ 0.002 - 0.050 1.0 2 Spinach 366 0 0.040 ^ 0.01 - Summer Squash 186 0 0.002 - 0.050 0.01 0.3 Sweet Peas, Frozen 700 0 0.002 - 0.025 0.01 0.3 Watermelon 529 0 0.002 - 0.030 0.03 - Winter Squash 369 0 0.002 - 0.036 0.01 0.3 TOTA L 7,607 146

Flumioxazin (herbicide) Eggplan t 740 0 0.050 ^ NT - TOTA L 740 0

Fluridone (herbicide)

Applesauce 216 0 0.001 - 0.002 0.1 - Carrots 744 0 0.0003 - 0.002 0.1 - Grapefrui t 655 0 0.001 - 0.004 0.1 - Greens, Collard 86 0 0.001 - 0.010 0.1 - Greens, Kale 98 0 0.001 - 0.010 0.1 - Orange Juice 557 0 0.001 - 0.036 0.1 - Peaches 90 0 0.001 - 0.036 0.1 - Potatoes, Frozen 744 0 0.001 - 0.036 0.1 - Raisins 372 0 0.001 - 0.050 NT - Spinach 145 0 0.001 ^ 0.1 - Summer Squash 186 0 0.001 - 0.050 0.1 - Sweet Peas, Frozen 216 0 0.001 ^ 0.1 -

Appendix B. Page 25 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Watermelon 361 0 0.001 - 0.016 0.1 - Winter Squash 369 0 0.001 - 0.016 0.1 - TOTA L 4,839 0

Flutolanil (fungicide) Potatoes, Frozen 528 4 0.8 0.002 - 0.004 0.001 ^ 0.20 - TOTA L 528 4

Folpet (fungicide)

Applesauce 216 0 0.015 ^ 25 10 Bananas 526 0 0.015 ^ NT - Cranberries 271 0 0.015 - 0.059 25 - Orange Juice 396 0 0.012 ^ NT - Peaches 71 0 0.015 ^ NT - Raisins 372 0 0.008 - 0.030 25 40 Watermelon 550 0 0.008 - 0.015 15 - TOTA L 2,402 0

Fonofos (insecticide)

Applesauce 528 0 0.002 ^ NT - Bananas (V-1) 742 1 0.1 0.008 ^ 0.002 - 0.005 NT - Broccoli 155 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Potatoes, Frozen 744 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 308 0 0.005 ^ NT - Watermelon 189 0 0.005 ^ NT - TOTA L 3,720 1

Forchlorfenuron (plant growth regulator)

Applesauce 352 0 0.0001 - 0.0002 0.01 - Spinach 29 0 0.0005 ^ NT - TOTA L 381 0

Halosulfuron methyl (herbicide) Summer Squash 54 0 0.001 ^ 0.5 - Watermelon 181 0 0.001 ^ 0.1 - Winter Squash 108 0 0.001 ^ 0.5 - TOTA L 343 0

Heptachlor (insecticide)

Applesauce 528 0 0.002 ^ 0.05 AL - Bananas 526 0 0.0008 - 0.003 NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ 0.05 AL - Cranberries 316 0 0.003 - 0.035 NT - Eggplan t 740 0 0.004 ^ 0.03 AL - Grapefrui t 743 0 0.003 - 0.004 0.05 AL 0.01 Greens, Collard 17 0 0.003 ^ 0.05 AL - Greens, Kale 37 0 0.003 ^ 0.05 AL - Orange Juice 557 0 0.003 - 0.006 0.05 AL 0.01 Peaches 90 0 0.003 ^ 0.05 AL - Plums 515 0 0.004 ^ 0.05 AL - Plums, Dried (Prunes) 224 0 0.004 ^ 0.05 AL - Spinach 511 0 0.002 - 0.003 0.05 AL - Summer Squash 186 0 0.002 - 0.003 0.05 AL - Sweet Peas, Frozen 528 0 0.0008 - 0.002 NT - Watermelon 550 0 0.0008 - 0.003 0.05 AL - Winter Squash 369 0 0.003 - 0.004 0.05 AL - TOTA L 7,180 0

Appendix B. Page 26 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Heptachlor epoxide (metabolite of Heptachlor)

Applesauce 527 0 0.004 ^ 0.05 AL - Bananas 526 0 0.002 - 0.005 NT - Broccoli 185 0 0.004 ^ NT - Cauliflowe r 542 0 0.004 ^ 0.05 AL - Cranberries 316 0 0.004 - 0.010 NT - Grapefrui t 743 0 0.004 ^ 0.05 AL 0.01 Greens, Collard 17 0 0.004 ^ 0.05 AL - Greens, Kale 37 0 0.004 ^ 0.05 AL - Orange Juice 557 0 0.004 - 0.006 0.05 AL 0.01 Peaches 90 0 0.004 ^ 0.05 AL - Spinach 511 0 0.004 ^ 0.05 AL - Summer Squash 186 3 1.6 0.007 - 0.022 0.002 - 0.004 0.05 AL - Sweet Peas, Frozen 528 0 0.0009 - 0.002 NT - Watermelon 550 0 0.002 - 0.004 0.05 AL - Winter Squash 369 2 0.5 0.006 - 0.007 0.004 ^ 0.05 AL - TOTA L 5,684 5

Heptachlor epoxide cis (metabolite of Heptachlor) Eggplan t 740 0 0.004 ^ 0.03 AL - Plums 515 0 0.004 ^ 0.05 AL - Plums, Dried (Prunes) 224 0 0.004 ^ 0.05 AL - TOTA L 1,479 0

Heptachlor epoxide trans (metabolite of Heptachlor) Eggplan t 740 0 0.004 ^ 0.03 AL - Plums 515 0 0.004 ^ 0.05 AL - Plums, Dried (Prunes) 224 0 0.004 ^ 0.05 AL - TOTA L 1,479 0

Hexachlorobenzene - HCB (impurity of Quintozene)

Applesauce 528 0 0.001 ^ NT - Bananas 526 0 0.0008 ^ NT - Broccoli 185 0 0.001 ^ 0.1 - Cauliflowe r 558 0 0.001 ^ 0.1 - Greens, Collard 77 0 0.001 - 0.002 0.2 - Greens, Kale 85 0 0.001 - 0.002 0.2 - Potatoes, Frozen 744 0 0.002 ^ 0.1 - Spinach 366 0 0.001 ^ NT - Sweet Peas, Frozen 528 0 0.0008 - 0.002 NT - Watermelon 189 0 0.0008 ^ NT - Winter Squash 261 0 0.003 ^ NT - TOTA L 4,047 0

Hexaconazole (fungicide) Bananas 742 1 0.1 0.11 ^ 0.010 - 0.050 0.7 - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 44 0 0.020 ^ NT - Watermelon (V-1) 190 1 0.5 0.033 ^ 0.010 - 0.020 NT - Winter Squash (V-2) 2 2 100.0 0.033 - 0.35 0.020 ^ NT - TOTA L 1,108 4

Hydroprene (insect growth regulator)

Applesauce 528 0 0.013 ^ 0.2 - Broccoli 185 0 0.013 ^ 0.2 - Cauliflowe r 558 0 0.013 ^ 0.2 - Spinach 366 0 0.013 ^ 0.2 - Summer Squash 132 0 0.015 ^ 0.2 - Watermelon 180 0 0.010 ^ 0.2 - Winter Squash 261 3 1.1 0.022 ^ 0.013 ^ 0.2 - TOTA L 2,210 3

Appendix B. Page 27 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm 3-Hydroxycarbofuran (metabolite of Carbofuran ) Applesauce 528 0 0.0006 ^ NT - Bananas 742 0 0.004 - 0.010 0.1 - Broccoli 185 0 0.0006 ^ NT - Cauliflowe r 558 0 0.0006 ^ NT - Cranberries 316 0 0.004 - 0.030 0.5 - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale (V-1) 61 1 1.6 0.018 ^ 0.010 ^ NT - Orange Juice 396 0 0.001 - 0.010 NT - Potatoes, Frozen 744 0 0.001 - 0.004 2 - Raisins 372 0 0.004 - 0.006 0.4 - Spinach (V-2) 366 2 0.5 0.001 - 0.004 0.0006 ^ NT - Summer Squash 186 1 0.5 0.052 ^ 0.004 - 0.006 0.8 - Sweet Peas, Frozen 506 0 0.010 - 0.018 NT - Watermelon 550 5 0.9 0.007 - 0.075 0.004 - 0.010 0.4 - Winter Squash 369 0 0.004 - 0.012 0.8 - TOTA L 5,948 9

5-Hydroxythiabendazole (metabolite of Thiabendazole ) Applesauce 216 40 18.5 0.002 - 0.019 0.001 ^ 10 - Bananas 216 14 6.5 0.002 ^ 0.001 ^ 3 - Carrots 216 0 0.001 ^ 10 - Grapefrui t 216 6 2.8 0.002 ^ 0.001 ^ 10 - Orange Juice 161 4 2.5 0.002 ^ 0.001 ^ 10 - Potatoes, Frozen 744 58 7.8 0.002 - 0.046 0.001 - 0.005 10 - Winter Squash 108 0 0.001 ^ 1.0 - TOTA L 1,877 122

Imazalil (fungicide)

Applesauce 528 0 0.010 ^ NT 5 Bananas 742 228 30.7 0.006 - 0.085 0.004 - 0.010 3.0 2 Broccoli 185 0 0.010 ^ NT - Cauliflowe r 558 0 0.010 ^ NT - Grapefrui t 739 293 39.6 0.006 - 0.51 0.004 - 0.045 10.0 5 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 557 66 11.8 0.006 - 0.23 0.004 - 0.030 10.0 5 Peaches (V-1) 30 1 3.3 0.050 ^ 0.030 ^ NT - Spinach 366 0 0.010 ^ NT - Sweet Peas, Frozen 484 0 0.010 - 0.15 NT - Watermelon (V-1) 189 1 0.5 0.016 ^ 0.010 ^ NT - Winter Squash 261 0 0.030 ^ NT - TOTA L 4,769 589

Imidacloprid (insecticide)

Applesauce 744 130 17.5 0.0002 - 0.003 0.0001 - 0.009 0.6 0.5 Bananas 742 0 0.009 - 0.050 0.50 0.05 Broccoli 185 149 80.5 0.0005 - 0.045 0.0003 ^ 3.5 0.5 Carrots 216 0 0.009 ^ 0.40 - Cauliflowe r 558 427 76.5 0.0002 - 0.045 0.0001 - 0.0003 3.5 0.5 Cranberries 316 0 0.009 - 0.047 0.05 - Grapefrui t 743 0 0.009 - 0.014 0.7 1 Greens, Collard 86 15 17.4 0.010 - 0.11 0.009 - 0.010 3.5 - Greens, Kale 98 28 28.6 0.011 - 0.50 0.009 - 0.010 3.5 - Orange Juice 557 0 0.001 - 0.010 0.7 1 Peaches 90 4 4.4 0.002 - 0.016 0.001 - 0.009 3.0 0.5 Potatoes, Frozen 744 246 33.1 0.002 - 0.032 0.001 - 0.009 0.40 0.5 Raisins 108 1 0.9 0.066 ^ 0.009 ^ 1.5 1 Spinach 511 368 72.0 0.0002 - 0.52 0.0001 - 0.009 3.5 - Summer Squash 54 11 20.4 0.015 - 0.035 0.009 ^ 0.5 1 Sweet Peas, Frozen 700 0 0.009 - 0.10 4.0 -

Appendix B. Page 28 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Watermelon 370 19 5.1 0.010 - 0.051 0.009 - 0.010 0.5 0.2 Winter Squash 108 7 6.5 0.015 - 0.042 0.009 ^ 0.5 1 TOTA L 6,930 1,405

Indoxacarb (insecticide)

Applesauce 216 1 0.5 0.008 ^ 0.005 ^ 1.0 0.5 Bananas 526 0 0.010 ^ NT - Cranberries 84 0 0.005 ^ 0.50 - Greens, Collard 86 6 7.0 0.042 - 1.1 0.005 - 0.010 3.0 - Greens, Kale (V-4) 98 4 4.1 0.008 - 0.073 0.005 - 0.010 NT - Peaches 90 0 0.003 - 0.005 10 0.3 Potatoes, Frozen 744 0 0.003 - 0.005 0.01 0.02 Sweet Peas, Frozen 308 0 0.010 ^ NT - Watermelon 189 0 0.010 ^ NT - TOTA L 2,341 11

Iprodione (fungicide)

Applesauce 528 0 0.008 ^ NT 5 Bananas 526 0 0.023 ^ NT - Broccoli 169 0 0.008 ^ 25.0 25 Carrots 743 99 13.3 0.025 - 0.13 0.015 - 0.035 5.0 10 Cauliflower (V-2 ) 558 2 0.4 0.014 ^ 0.008 ^ NT - Cranberries 209 0 0.025 ^ NT - Peaches 90 30 33.3 0.078 - 7.4 0.015 ^ 20.0 10 Plums 515 187 36.3 0.065 - 6.9 0.039 ^ 20.0 - Plums, Dried (Prunes) 224 1 0.4 0.36 ^ 0.039 ^ 20.0 - Potatoes, Frozen 744 0 0.015 ^ 0.5 - Raisins 372 3 0.8 0.025 - 1.3 0.015 - 0.030 300 10 Spinach (V-5) 368 5 1.4 0.014 - 0.074 0.008 - 0.015 NT - Sweet Peas, Frozen 528 0 0.012 - 0.023 NT - Watermelon 189 0 0.023 ^ NT - Winter Squash 261 0 0.008 ^ NT - TOTA L 6,024 327

Iprodione metabolite isomer (metabolite of Iprodione)

Applesauce 527 0 0.098 ^ NT - Broccoli 185 0 0.098 ^ 25.0 - Cauliflowe r 558 0 0.098 ^ NT - Spinach 366 0 0.098 ^ NT - TOTA L 1,636 0

Iprovalicarb (fungicide) Raisins 264 0 0.030 ^ NT - TOTA L 264 0

Kresoxim-methyl (fungicide)

Applesauce 528 0 0.003 ^ 0.5 0.2 Broccoli 185 0 0.003 ^ NT - Spinach 366 0 0.003 ^ NT - TOTA L 1,079 0

Lindane - BHC gamma (insecticide)

Applesauce 744 0 0.002 - 0.003 NT - Bananas 526 0 0.002 ^ NT - Broccoli 169 0 0.003 ^ 1.0 - Carrots 743 0 0.002 - 0.025 0.5 AL - Cauliflowe r 558 0 0.003 ^ 1.0 AL - Cranberries 316 0 0.002 - 0.020 NT - Eggplan t 740 0 0.005 ^ NT - Grapefrui t 743 0 0.002 - 0.005 0.5 AL - Orange Juice 557 0 0.002 ^ 0.5 AL - Peaches 90 0 0.002 ^ NT -

Appendix B. Page 29 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Plums 515 0 0.004 ^ NT - Plums, Dried (Prunes) 224 0 0.004 ^ NT - Potatoes, Frozen 744 0 0.002 ^ 0.5 AL - Raisins 372 0 0.002 - 0.004 NT - Spinach 511 0 0.002 - 0.003 NT - Summer Squash 186 0 0.002 ^ NT - Sweet Peas, Frozen 744 0 0.0009 - 0.002 0.5 AL - Watermelon 550 0 0.002 ^ NT - Winter Squash 369 0 0.002 - 0.006 NT - TOTA L 9,401 0

Linuron (herbicide)

Applesauce 528 0 0.003 ^ NT - Bananas 526 0 0.008 ^ NT - Broccoli 185 0 0.003 ^ NT - Carrots 216 169 78.2 0.003 - 0.22 0.002 ^ 1 - Cauliflowe r 558 0 0.003 ^ NT - Potatoes, Frozen 744 3 0.4 0.002 ^ 0.001 - 0.002 1 - Spinach (V-10) 366 10 2.7 0.005 - 0.031 0.003 ^ NT - Sweet Peas, Frozen 528 0 0.008 - 0.012 NT - Watermelon 189 0 0.008 ^ NT - TOTA L 3,840 182

Malathion (insecticide)

Applesauce 744 0 0.003 - 0.004 8 0.5 Bananas 526 0 0.004 ^ NT - Broccoli 185 0 0.003 ^ 8 - Carrots 744 0 0.002 - 0.004 8 0.5 Cauliflowe r 558 0 0.003 ^ 8 - Cranberries 316 1 0.3 0.007 ^ 0.002 - 0.004 8 - Eggplan t 740 1 0.1 0.013 ^ 0.008 ^ 8 - Grapefrui t 743 0 0.001 - 0.004 8 7 Greens, Collard 86 0 0.004 ^ 8 - Greens, Kale 98 7 7.1 0.007 - 0.19 0.004 ^ 8 - Orange Juice 557 0 0.004 ^ 8 7 Peaches 90 3 3.3 0.007 ^ 0.004 ^ 8 - Plums 515 0 0.008 ^ 8 - Plums, Dried (Prunes) 224 0 0.008 ^ 8 - Potatoes, Frozen 744 0 0.004 ^ 8 0.5 Raisins 372 0 0.006 - 0.008 12 5 Spinach 511 3 0.6 0.007 - 0.015 0.003 - 0.004 8 3 Summer Squash 186 0 0.004 - 0.006 8 - Sweet Peas, Frozen 744 0 0.004 - 0.010 8 - Watermelon 550 0 0.004 - 0.006 8 - Winter Squash 369 0 0.004 - 0.007 8 - TOTA L 9,602 15

Malathion oxygen analog (metabolite of Malathion)

Applesauce 744 0 0.003 ^ NT - Bananas 526 0 0.006 ^ NT - Broccoli 185 0 0.010 ^ NT - Carrots 744 0 0.001 - 0.003 NT - Cauliflowe r 558 0 0.003 ^ NT - Cranberries 316 0 0.0001 - 0.004 NT - Eggplan t 740 0 0.019 ^ NT - Grapefrui t 743 0 0.001 - 0.003 NT - Greens, Collard 86 0 0.003 - 0.006 NT - Greens, Kale 98 0 0.003 - 0.006 NT - Orange Juice 557 0 0.003 ^ NT - Peaches 90 0 0.003 ^ NT - Plums 515 0 0.019 ^ NT - Plums, Dried (Prunes) 224 0 0.019 ^ NT - Potatoes, Frozen 744 0 0.003 ^ NT -
Appendix B. Page 30 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Raisins 372 0 0.006 - 0.008 NT - Spinach 511 0 0.003 - 0.010 NT - Summer Squash 186 0 0.003 - 0.006 NT - Sweet Peas, Frozen 744 0 0.003 - 0.010 NT - Watermelon 550 0 0.003 - 0.006 NT - Winter Squash 369 0 0.003 - 0.007 NT - TOTA L 9,602 0

Mepanipyrim (fungicide) Raisins 264 0 0.030 ^ NT - TOTA L 264 0

Metalaxyl (fungicide)

Applesauce 744 0 0.006 - 0.010 0.2 1 Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.006 ^ 2.0 0.5 Carrots 743 19 2.6 0.017 - 0.033 0.010 - 0.018 0.5 0.05 Cauliflowe r 542 0 0.006 ^ 1.0 0.5 Cranberries 316 0 0.010 - 0.035 4.0 - Eggplan t 740 0 0.020 ^ 1.0 - Grapefrui t 743 0 0.010 - 0.040 1.0 5 Greens, Collard 86 2 2.3 0.017 - 0.037 0.010 - 0.015 0.1 - Greens, Kale 98 3 3.1 0.017 - 0.022 0.010 - 0.015 0.1 - Orange Juice 557 0 0.010 ^ 1.0 5 Peaches 90 0 0.010 ^ 1.0 - Plums 515 0 0.020 ^ 1.0 - Plums, Dried (Prunes) 224 0 0.020 ^ 1.0 - Potatoes, Frozen 744 0 0.010 ^ 0.5 0.05 Raisins 372 0 0.020 - 0.030 6.0 1 Spinach 511 4 0.8 0.010 - 0.080 0.006 - 0.010 10.0 2 Summer Squash 186 5 2.7 0.017 - 0.043 0.010 - 0.015 1.0 0.2 Sweet Peas, Frozen 744 0 0.010 - 0.015 0.2 0.05 Watermelon 550 4 0.7 0.017 - 0.074 0.008 - 0.015 1.0 - Winter Squash 369 0 0.008 - 0.010 1.0 0.2 TOTA L 9,585 37

Methamidophos (insecticide) (also a metabolite of Acephate)

Applesauce 744 1 0.1 0.002 ^ 0.001 - 0.002 0.02 - Bananas 742 0 0.002 - 0.008 0.02 - Carrots 216 0 0.002 ^ 0.02 - Cranberries 84 13 15.5 0.003 - 0.009 0.002 ^ 0.5 - Eggplan t 740 32 4.3 0.007 - 0.19 0.004 ^ 1.0 - Grapefrui t 216 0 0.002 ^ 0.02 - Greens, Collard 86 0 0.002 - 0.050 0.02 - Greens, Kale 98 0 0.002 - 0.050 0.02 - Orange Juice 557 0 0.002 ^ 0.02 - Peaches 90 9 10.0 0.003 - 0.021 0.002 ^ 0.02 - Plums 515 0 0.004 ^ 0.02 - Plums, Dried (Prunes) 224 0 0.004 ^ 0.02 - Potatoes, Frozen 744 3 0.4 0.003 ^ 0.002 ^ 0.1 0.05 Raisins 108 0 0.004 ^ 0.02 - Spinach 511 4 0.8 0.002 - 0.018 0.001 - 0.002 0.02 - Summer Squash 186 0 0.002 - 0.004 0.02 - Sweet Peas, Frozen 744 1 0.1 0.008 ^ 0.002 - 0.008 0.02 - Watermelon 550 24 4.4 0.003 - 0.083 0.002 - 0.008 0.5 - Winter Squash 369 7 1.9 0.003 - 0.025 0.002 - 0.004 0.02 - TOTA L 7,524 94

Methidathion (insecticide)

Applesauce 744 0 0.002 - 0.004 0.05 0.5 Bananas 526 0 0.004 ^ NT - Broccoli 185 0 0.008 ^ NT -

Appendix B. Page 31 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Cauliflowe r 558 0 0.002 ^ NT - Grapefrui t 216 0 0.004 ^ 2.0 2 Orange Juice 557 0 0.004 - 0.005 2.0 2 Peaches 90 0 0.004 ^ 0.05 0.2 Plums 515 0 0.003 ^ 0.05 0.2 Plums, Dried (Prunes) 224 0 0.003 ^ 0.05 0.2 Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.004 - 0.010 NT 0.1 Watermelon 189 0 0.004 ^ NT - Winter Squash 261 0 0.010 ^ NT - TOTA L 4,959 0

Methiocarb (insecticide) (analyzed as sulfoxide)

Applesauce 528 0 0.0006 ^ NT - Bananas 526 0 0.010 ^ NT - Broccoli 185 0 0.0006 ^ NT - Cauliflowe r 558 0 0.0006 ^ NT 0.1 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Spinach 366 0 0.0006 ^ NT - Sweet Peas, Frozen 506 0 0.010 - 0.015 NT 0.1 Watermelon 189 0 0.010 ^ NT - TOTA L 2,988 0

Methomyl (insecticide)

Applesauce 744 0 0.004 - 0.014 1 2 Bananas 506 0 0.010 - 0.050 NT - Broccoli 185 5 2.7 0.004 - 0.14 0.002 ^ 3 - Carrots 744 1 0.1 0.023 ^ 0.008 - 0.014 0.2 - Cauliflowe r 558 4 0.7 0.002 - 0.13 0.001 - 0.002 2 2 Eggplan t 740 9 1.2 0.020 - 0.12 0.012 ^ 0.2 - Grapefrui t 743 0 0.014 ^ 2 1 Greens, Collard 86 0 0.010 - 0.014 6 - Greens, Kale 98 1 1.0 0.023 ^ 0.010 - 0.014 6 - Orange Juice 557 0 0.003 - 0.014 2 1 Peaches 90 11 12.2 0.017 - 0.49 0.001 - 0.014 5 0.2 Potatoes, Frozen 744 0 0.001 - 0.014 0.2 0.02 Raisins 372 0 0.006 - 0.014 5 5 Spinach 511 36 7.0 0.005 - 0.89 0.002 - 0.014 6 - Summer Squash 186 4 2.2 0.010 - 0.034 0.006 - 0.014 0.2 - Sweet Peas, Frozen 744 0 0.010 - 0.015 5 5 Watermelon 550 20 3.6 0.007 - 0.14 0.004 - 0.014 0.2 0.2 Winter Squash 369 2 0.5 0.023 ^ 0.012 - 0.014 0.2 - TOTA L 8,527 93

Methoprene (insect growth regulator)

Applesauce 528 0 0.014 ^ NT - Broccoli 185 0 0.014 ^ NT - Cauliflowe r 558 0 0.048 ^ NT - Spinach 366 0 0.014 ^ NT - TOTA L 1,637 0

Methoxychlor Total (insecticide)

Applesauce 528 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ NT - Carrots 527 0 0.025 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Cranberries 232 0 0.051 ^ NT - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 220 0 0.003 ^ NT - TOTA L 2,616 0

Appendix B. Page 32 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Methoxychlor olefin (metabolite of Methoxychlor )

Applesauce 527 0 0.001 ^ NT - Broccoli 185 0 0.001 ^ NT - Cauliflowe r 558 0 0.001 ^ NT - Spinach 366 0 0.001 ^ NT - TOTA L 1,636 0

Methoxychlor p,p' (isomer of Methoxychlor) Bananas 526 0 0.008 ^ NT - Carrots 216 0 0.010 ^ NT - Orange Juice 396 0 0.020 ^ NT - Peaches 71 0 0.011 ^ NT - Sweet Peas, Frozen 308 0 0.008 ^ NT - Watermelon 189 0 0.008 ^ NT - Winter Squash 261 0 0.009 ^ NT - TOTA L 1,967 0

Methoxyfenozide (insecticide)

Applesauce 216 55 25.5 0.002 - 0.021 0.001 ^ 1.5 2 Carrots 612 15 2.5 0.0005 - 0.013 0.0005 - 0.001 0.5 - Cranberries 316 44 13.9 0.002 - 0.036 0.001 - 0.008 0.5 - Greens, Collard 86 17 19.8 0.003 - 2.1 0.001 - 0.010 30 - Greens, Kale 98 28 28.6 0.002 - 3.4 0.001 - 0.010 30 - Peaches 90 25 27.8 0.002 - 0.10 0.001 ^ 3.0 2 Potatoes, Frozen 744 0 0.001 ^ 0.1 - Raisins 108 81 75.0 0.002 - 0.16 0.001 ^ 1.5 3 Spinach 145 7 4.8 0.029 - 0.44 0.001 ^ 30 - Summer Squash 54 0 0.001 ^ 0.3 - Sweet Peas, Frozen 216 0 0.001 ^ 1.5 - Watermelon 181 0 0.001 ^ 0.3 - Winter Squash 108 3 2.8 0.002 - 0.012 0.001 ^ 0.3 - TOTA L 2,974 275

Metolachlor (herbicide)

Applesauce 528 0 0.001 ^ NT - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.001 ^ 0.6 - Cauliflowe r 558 0 0.001 ^ 0.6 - Cranberries 316 0 0.010 ^ NT - Greens, Collard 86 0 0.010 - 0.015 NT - Greens, Kale 98 0 0.010 - 0.015 NT - Orange Juice 44 0 0.010 ^ NT - Peaches 90 0 0.010 ^ 0.1 - Plums 515 0 0.023 ^ 0.1 - Plums, Dried (Prunes) 224 0 0.023 ^ 0.1 - Potatoes, Frozen 744 0 0.010 ^ 0.2 - Spinach 511 2 0.4 0.002 ^ 0.001 - 0.010 0.5 - Sweet Peas, Frozen 744 0 0.009 - 0.015 0.3 - Watermelon 189 0 0.015 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 5,619 2

Metribuzin (herbicide)

Applesauce 528 0 0.013 ^ NT - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.013 ^ NT - Carrots 744 0 0.006 - 0.030 0.3 - Cauliflowe r 558 0 0.044 ^ NT - Orange Juice 44 0 0.030 ^ NT - Potatoes, Frozen 744 0 0.030 ^ 0.6 - Spinach (V-4) 366 4 1.1 0.022 - 0.084 0.013 ^ NT - Sweet Peas, Frozen 744 0 0.015 - 0.030 0.1 -

Appendix B. Page 33 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Watermelon 189 0 0.015 ^ NT - Winter Squash (V-1) 262 1 0.4 0.11 ^ 0.016 - 0.030 NT - TOTA L 4,890 5

Mevinphos (insecticide)

Applesauce 528 0 0.002 - 0.005 NT - Bananas 526 0 0.008 ^ NT - Greens, Collard 69 0 0.008 ^ NT - Greens, Kale 61 0 0.008 ^ NT - Orange Juice 396 0 0.004 ^ NT - Raisins 372 0 0.004 ^ 0.5 - Spinach 511 0 0.002 ^ NT - Summer Squash 186 0 0.002 - 0.004 0.25 - Sweet Peas, Frozen 744 0 0.002 - 0.012 0.25 - Watermelon 550 0 0.002 - 0.008 0.5 - Winter Squash 261 0 0.012 ^ NT - TOTA L 4,204 0

Monocrotophos (insecticide) Bananas 526 0 0.008 ^ NT - Greens, Collard 69 0 0.008 ^ NT - Greens, Kale 61 0 0.008 ^ NT - Sweet Peas, Frozen 308 0 0.008 ^ NT - Watermelon 189 0 0.008 ^ NT - Winter Squash 261 0 0.007 ^ NT - TOTA L 1,414 0

Myclobutanil (fungicide)

Applesauce 744 5 0.7 0.002 ^ 0.0009 - 0.020 0.5 0.5 Bananas 742 2 0.3 0.038 ^ 0.020 - 0.023 4.0 2 Broccoli 185 0 0.0009 ^ 0.03 - Carrots 744 5 0.7 0.0006 - 0.001 0.0006 - 0.020 0.03 - Cauliflowe r 558 0 0.0009 ^ 0.03 - Eggplan t 740 0 0.040 ^ 0.03 - Greens, Collard 86 0 0.020 - 0.075 0.03 - Greens, Kale 98 0 0.020 - 0.075 0.03 - Orange Juice 396 0 0.020 ^ NT - Peaches 90 12 13.3 0.002 - 0.026 0.001 - 0.020 2.0 2 Plums 515 1 0.2 0.055 ^ 0.033 ^ 2.0 0.2 Plums, Dried (Prunes) 224 0 0.033 ^ 2.0 0.5 Potatoes, Frozen 744 1 0.1 0.002 ^ 0.001 - 0.020 0.03 - Raisins 372 5 1.3 0.053 - 0.067 0.040 - 0.050 10.0 1 Spinach 511 0 0.0009 - 0.020 0.03 - Summer Squash 186 1 0.5 0.033 ^ 0.020 - 0.025 0.20 - Sweet Peas, Frozen 744 0 0.015 - 0.023 1.0 - Watermelon 550 0 0.020 - 0.023 0.20 - Winter Squash 369 4 1.1 0.014 ^ 0.008 - 0.020 0.20 - TOTA L 8,598 36

Napropamide (herbicide)

Applesauce 744 0 0.007 - 0.020 0.1 - Broccoli 185 0 0.007 ^ 0.1 - Cauliflowe r 558 0 0.007 ^ 0.1 - Cranberries 232 0 0.040 ^ NT - Eggplan t 740 0 0.033 ^ 0.1 - Grapefrui t 743 0 0.020 ^ 0.1 - Greens, Collard 86 0 0.010 - 0.020 0.1 - Greens, Kale 98 0 0.010 - 0.020 0.1 - Orange Juice 557 0 0.020 ^ 0.1 - Peaches 90 0 0.020 ^ 0.1 - Plums 515 0 0.033 ^ 0.1 - Plums, Dried (Prunes) 224 0 0.033 ^ 0.1 -

Appendix B. Page 34 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Spinach 366 0 0.007 ^ NT - Summer Squash 186 0 0.020 - 0.066 0.1 - Watermelon 361 0 0.020 ^ 0.1 - Winter Squash 369 0 0.020 - 0.040 0.1 - TOTA L 6,054 0

1-Naphthol (metabolite of Carbaryl )

Applesauce 216 10 4.6 0.017 ^ 0.010 ^ 10 - Bananas 216 0 0.010 ^ 10 - Carrots 216 0 0.010 ^ 10 - Cranberries 84 40 47.6 0.017 - 0.20 0.010 ^ 10 - Grapefrui t 216 0 0.010 ^ 10 - Greens, Collard 64 0 0.010 - 0.10 12 - Greens, Kale 75 0 0.010 - 0.10 12 - Orange Juice 161 0 0.010 ^ 10 - Peaches 90 18 20.0 0.017 - 0.27 0.010 ^ 10 - Potatoes, Frozen 726 0 0.010 ^ 0.2 - Raisins 108 1 0.9 0.033 ^ 0.020 ^ 10 - Spinach 145 0 0.010 ^ 12 - Summer Squash 54 0 0.010 ^ 10 - Sweet Peas, Frozen 198 0 0.010 ^ 10 - Watermelon 181 0 0.010 ^ 10 - Winter Squash 369 0 0.010 - 0.16 10 - TOTA L 3,119 69

Norflurazon (herbicide)

Applesauce 729 0 0.005 - 0.020 0.1 - Bananas 526 0 0.010 ^ NT - Broccoli 185 0 0.005 - 0.032 NT - Cranberries 84 0 0.020 ^ 0.1 - Grapefrui t 216 0 0.020 ^ 0.2 - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 557 0 0.020 ^ 0.2 - Peaches 90 0 0.020 ^ 0.1 - Plums 515 0 0.053 ^ 0.1 - Plums, Dried (Prunes) 224 0 0.053 ^ 0.1 - Raisins 372 0 0.030 - 0.040 0.1 - Spinach 366 0 0.005 ^ NT - Sweet Peas, Frozen 484 0 0.010 - 0.040 NT - Watermelon 189 0 0.010 ^ NT - Winter Squash 261 0 0.018 ^ NT - TOTA L 4,928 0

Norflurazon desmethyl (metabolite of Norflurazon)

Applesauce 744 0 0.030 - 0.060 0.1 - Bananas 526 0 0.010 - 0.050 NT - Broccoli 185 0 0.018 - 0.12 NT - Cauliflowe r 528 0 0.060 - 0.12 NT - Cranberries 84 0 0.030 ^ 0.1 - Grapefrui t 216 0 0.030 - 0.10 0.2 - Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 557 0 0.030 ^ 0.2 - Peaches 90 0 0.030 ^ 0.1 - Plums 515 0 0.041 ^ 0.1 - Plums, Dried (Prunes) 224 0 0.041 ^ 0.1 - Raisins 108 0 0.060 ^ 0.1 - Spinach 351 0 0.018 ^ NT - Sweet Peas, Frozen 484 0 0.010 - 0.040 NT - Watermelon 189 0 0.010 ^ NT - TOTA L 4,931 0

Appendix B. Page 35 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Novaluron (insecticide) Peaches 71 0 0.015 ^ NT - Potatoes, Frozen 528 0 0.015 ^ 0.05 0.01 TOTA L 599 0

Omethoate (metabolite of Dimethoate)

Applesauce 744 0 0.002 - 0.004 2 - Bananas 526 0 0.008 ^ NT - Broccoli 64 0 0.008 ^ 2 - Cauliflowe r 558 4 0.7 0.004 - 0.014 0.002 ^ 2 - Grapefrui t 216 0 0.004 ^ 2 - Greens, Collard 86 0 0.004 - 0.050 2 - Greens, Kale 98 0 0.004 - 0.050 2 - Orange Juice 557 0 0.004 ^ 2 - Potatoes, Frozen 744 0 0.004 ^ 0.2 - Raisins 372 0 0.008 ^ 1 - Spinach 511 66 12.9 0.004 - 1.2 0.002 - 0.004 2 - Sweet Peas, Frozen 744 17 2.3 0.007 - 0.019 0.004 - 0.008 2 - Watermelon 550 13 2.4 0.007 - 0.17 0.004 - 0.008 1 - Winter Squash 261 0 0.018 ^ NT - TOTA L 6,031 100

Oryzalin (herbicide) Bananas 460 0 0.020 ^ NT - Greens, Collard 69 0 0.020 ^ NT - Greens, Kale 61 0 0.020 ^ NT - Sweet Peas, Frozen 308 0 0.020 ^ NT - Watermelon 168 0 0.020 ^ NT - TOTA L 1,066 0

Oxadixyl (fungicide)

Applesauce 528 0 0.013 ^ NT - Broccoli 185 0 0.013 ^ NT - Cauliflowe r 558 0 0.013 ^ NT - Orange Juice 44 0 0.015 ^ NT - Spinach 366 0 0.013 ^ NT - Winter Squash 261 0 0.008 ^ NT - TOTA L 1,942 0

Oxamyl (insecticide)

Applesauce 700 0 0.002 - 0.008 2 2 Bananas 742 0 0.008 - 0.050 0.3 - Broccoli 185 0 0.006 ^ NT - Carrots 744 0 0.004 - 0.008 0.1 0.1 Cauliflowe r 542 0 0.0009 - 0.002 NT - Eggplan t 740 13 1.8 0.025 - 0.14 0.015 ^ 2.0 - Grapefrui t 743 0 0.004 - 0.008 3 5 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 557 0 0.001 - 0.010 3 5 Potatoes, Frozen 744 17 2.3 0.002 - 0.009 0.001 - 0.008 0.1 0.1 Spinach 366 0 0.002 - 0.003 NT - Summer Squash 186 10 5.4 0.010 - 0.036 0.006 - 0.008 2.0 - Sweet Peas, Frozen 528 0 0.010 - 0.018 NT - Watermelon 550 12 2.2 0.010 - 0.16 0.004 - 0.010 2.0 - Winter Squash 369 0 0.008 ^ 2.0 - TOTA L 7,826 52

Oxamyl oxime (metabolite of Oxamyl )

Applesauce 216 1 0.5 0.017 ^ 0.010 ^ 2 2 Bananas 720 9 1.2 0.014 - 0.027 0.010 - 0.050 0.3 - Carrots 744 0 0.010 - 0.014 0.1 0.1

Appendix B. Page 36 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Grapefrui t 743 0 0.010 - 0.014 3 5 Orange Juice 557 0 0.001 - 0.010 3 5 Potatoes, Frozen 744 65 8.7 0.002 - 0.023 0.001 - 0.010 0.1 0.1 Summer Squash 54 2 3.7 0.017 - 0.059 0.010 ^ 2.0 - Sweet Peas, Frozen 308 0 0.010 ^ NT - Watermelon 370 15 4.1 0.017 - 0.081 0.010 ^ 2.0 - Winter Squash 108 0 0.010 ^ 2.0 - TOTA L 4,564 92

Oxychlordane (metabolite of Chlordane )

Applesauce 528 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - TOTA L 1,637 0

Oxydemeton methyl (insecticide) Grapefrui t 483 0 0.020 ^ 1 - TOTA L 483 0

Oxydemeton methyl sulfone (metabolite of Oxydemeton methyl )

Applesauce 730 0 0.009 - 0.015 1 - Bananas 526 0 0.023 ^ NT - Eggplan t 740 0 0.028 ^ 1 - Grapefrui t 743 0 0.005 - 0.015 1 - Greens, Collard 69 0 0.010 ^ NT 0.01 Greens, Kale 61 0 0.010 ^ NT 0.01 Orange Juice 557 0 0.015 ^ 1 - Plums 515 0 0.028 ^ 1 - Plums, Dried (Prunes) 224 0 0.028 ^ 1 - Raisins 372 0 0.012 - 0.030 0.1 - Spinach 323 0 0.009 - 0.012 NT - Summer Squash 186 0 0.012 - 0.015 1 - Sweet Peas, Frozen 528 0 0.023 - 0.024 NT - Watermelon 550 0 0.012 - 0.023 0.3 - Winter Squash 108 0 0.015 ^ 0.3 - TOTA L 6,232 0

Oxyfluorfen (herbicide)

Applesauce 744 0 0.010 - 0.030 0.05 - Bananas 742 0 0.025 - 0.030 0.05 - Broccoli 185 0 0.003 ^ 0.05 - Cauliflowe r 558 0 0.010 ^ 0.05 - Orange Juice 44 0 0.030 ^ NT - Peaches 19 0 0.030 ^ 0.05 - Plums 515 0 0.032 ^ 0.05 - Plums, Dried (Prunes) 224 0 0.032 ^ 0.05 - Raisins 372 0 0.030 - 0.060 0.05 - Spinach 366 0 0.003 ^ NT - Watermelon 189 0 0.025 ^ NT - TOTA L 3,958 0

Parathion (insecticide)

Applesauce 528 0 0.003 - 0.005 NT - Bananas 526 0 0.008 ^ NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 - 0.005 NT - Orange Juice 396 0 0.003 ^ NT - Spinach 366 0 0.003 - 0.005 NT - Sweet Peas, Frozen 528 0 0.008 - 0.010 NT - Watermelon 189 0 0.008 ^ NT - Winter Squash 261 0 0.006 ^ NT - TOTA L 3,537 0

Appendix B. Page 37 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Parathion methyl (insecticide)

Applesauce 528 0 0.002 ^ NT 0.2 Bananas (V-1) 262 1 0.4 0.007 ^ 0.004 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Greens, Collard 69 0 0.004 ^ NT - Greens, Kale 61 0 0.004 ^ NT - Potatoes, Frozen 744 0 0.002 ^ 0.1 0.05 Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 744 0 0.002 - 0.006 1.0 - Watermelon 63 0 0.004 ^ NT - Winter Squash 261 0 0.006 ^ NT - TOTA L 3,841 1

Parathion methyl oxygen analog (metabolite of Parathion methyl )

Applesauce 528 0 0.005 ^ NT - Broccoli 152 0 0.005 ^ NT - Cauliflowe r 558 0 0.005 ^ NT - Potatoes, Frozen 744 0 0.003 ^ NT - Spinach 366 0 0.005 ^ NT - Sweet Peas, Frozen 700 0 0.003 - 0.012 NT - TOTA L 3,048 0

Parathion oxygen analog (metabolite of Parathion)

Applesauce 528 0 0.003 ^ NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Orange Juice 396 0 0.003 ^ NT - Spinach 366 0 0.003 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 2,294 0

Pendimethalin (herbicide) Bananas 526 0 0.015 ^ NT - Greens, Collard 69 0 0.015 ^ NT - Greens, Kale 61 0 0.015 ^ NT - Orange Juice 44 0 0.020 ^ 0.1 - Potatoes, Frozen 216 0 0.020 ^ 0.1 - Sweet Peas, Frozen 744 0 0.015 - 0.020 0.1 - Watermelon 189 0 0.015 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 2,110 0

Pentachloroaniline - PCA (metabolite of Quintozene)

Applesauce 528 0 0.001 ^ NT - Bananas 526 0 0.005 ^ NT - Broccoli 185 0 0.001 ^ 0.1 - Cauliflowe r 558 0 0.001 ^ 0.1 - Greens, Collard 60 0 0.030 ^ 0.2 - Greens, Kale 48 0 0.030 ^ 0.2 - Potatoes, Frozen 528 1 0.2 0.017 ^ 0.010 ^ 0.1 - Spinach (V-3) 366 3 0.8 0.002 ^ 0.001 ^ NT - Sweet Peas, Frozen 528 0 0.003 - 0.005 0.1 - Watermelon 189 0 0.005 ^ NT - TOTA L 3,516 4

Pentachlorobenzene - PCB (metabolite of Quintozene)

Applesauce 514 0 0.002 ^ NT - Bananas 526 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ 0.1 - Carrots (V-1) 1 1 100.0 0.003 ^ 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ 0.1 -

Appendix B. Page 38 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Greens, Collard 77 0 0.002 - 0.005 0.2 - Greens, Kale 85 0 0.002 - 0.005 0.2 - Potatoes, Frozen 722 8 1.1 0.003 ^ 0.002 ^ 0.1 - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.002 - 0.003 NT - Watermelon 189 0 0.002 ^ NT - Winter Squash 261 0 0.002 ^ NT - TOTA L 4,012 9

Pentachlorophenyl methyl sulfide (metabolite of Quintozene )

Applesauce 528 0 0.001 ^ NT - Bananas 526 0 0.005 ^ NT - Broccoli 169 0 0.001 ^ 0.1 - Cauliflowe r 558 0 0.005 ^ 0.1 - Greens, Collard 60 0 0.005 ^ 0.2 - Greens, Kale 48 0 0.005 ^ 0.2 - Potatoes, Frozen 528 0 0.010 ^ 0.1 - Spinach 366 0 0.001 ^ NT - Sweet Peas, Frozen 528 0 0.003 - 0.005 NT - Watermelon 189 0 0.005 ^ NT - TOTA L 3,500 0

Permethrin Total (insecticide) Bananas 526 0 0.038 ^ NT - Greens, Collard 69 5 7.2 0.19 - 4.9 0.10 - 0.13 20.0 5 Greens, Kale (V-1) 61 1 1.6 0.25 ^ 0.10 - 0.13 NT 5 Summer Squash 132 0 0.050 ^ 3.0 0.5 Sweet Peas, Frozen 308 0 0.038 ^ NT 0.1 Watermelon 369 0 0.030 - 0.038 3.0 - Winter Squash 261 3 1.1 0.048 - 0.18 0.029 ^ 3.0 0.5 TOTA L 1,726 9

Permethrin cis (isomer of Permethrin)

Applesauce 744 0 0.002 - 0.012 0.05 2 Broccoli 185 4 2.2 0.004 - 0.071 0.002 ^ 1.0 2 Cauliflowe r 558 1 0.2 0.004 ^ 0.002 ^ 1.0 0.5 Cranberries 232 0 0.025 ^ NT - Eggplan t 740 2 0.3 0.022 ^ 0.013 ^ 1.0 1 Greens, Collard 17 1 5.9 0.020 ^ 0.012 ^ 20.0 5 Greens, Kale (V-1) 37 1 2.7 0.067 ^ 0.012 ^ NT 5 Orange Juice 44 0 0.012 ^ NT 0.5 Peaches 90 0 0.012 ^ 5.0 2 Potatoes, Frozen 744 0 0.012 ^ 0.05 0.05 Spinach 511 289 56.6 0.004 - 4.5 0.002 - 0.012 20.0 2 Summer Squash 54 0 0.012 ^ 3.0 0.5 Sweet Peas, Frozen 220 0 0.006 ^ NT 0.1 Watermelon 181 1 0.6 0.025 ^ 0.015 ^ 3.0 - Winter Squash 108 0 0.012 ^ 3.0 0.5 TOTA L 4,465 299

Permethrin trans (isomer of Permethrin)

Applesauce 744 0 0.002 - 0.012 0.05 2 Broccoli 185 4 2.2 0.004 - 0.055 0.002 ^ 1.0 2 Cauliflowe r 558 1 0.2 0.004 ^ 0.002 ^ 1.0 0.5 Cranberries 232 0 0.025 ^ NT - Eggplan t 740 2 0.3 0.022 ^ 0.013 ^ 1.0 1 Grapefrui t 18 0 0.012 ^ NT 0.05 Greens, Collard 17 0 0.012 ^ 20.0 5 Greens, Kale (V-1) 37 1 2.7 0.062 ^ 0.012 ^ NT 5 Orange Juice 44 0 0.012 ^ NT 0.5 Peaches 90 0 0.012 ^ 5.0 2 Potatoes, Frozen 744 0 0.012 ^ 0.05 0.05

Appendix B. Page 39 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Spinach 511 287 56.2 0.004 - 5.3 0.002 - 0.012 20.0 2 Summer Squash 54 0 0.012 ^ 3.0 0.5 Sweet Peas, Frozen 220 0 0.006 ^ NT 0.1 Watermelon 181 1 0.6 0.025 ^ 0.015 ^ 3.0 - Winter Squash 108 0 0.012 ^ 3.0 0.5 TOTA L 4,483 296

Phenmedipham (herbicide)

Winter Squash 261 0 0.097 ^ NT - TOTA L 261 0

Phenothrin (insecticide) Bananas 526 0 0.075 ^ NT - Sweet Peas, Frozen 308 0 0.075 ^ NT - Watermelon 189 0 0.075 ^ NT - TOTA L 1,023 0

Phenthoate (insecticide)

Applesauce 528 0 0.006 ^ NT - Broccoli 185 0 0.006 ^ NT - Cauliflowe r 558 0 0.006 ^ NT - Spinach 366 0 0.006 ^ NT - TOTA L 1,637 0

o-Phenylphenol (fungicide) Applesauce 744 8 1.1 0.005 - 0.048 0.003 - 0.033 25 - Bananas (V-31) 742 31 4.2 0.034 - 0.068 0.015 - 0.033 NT - Broccoli 185 0 0.003 ^ NT - Carrots 216 7 3.2 0.034 - 0.041 0.033 ^ 20 - Cauliflowe r 558 0 0.003 ^ NT - Cranberries 316 0 0.033 - 0.076 NT - Grapefrui t 743 3 0.4 0.034 - 0.088 0.033 - 0.076 10 10 Greens, Collard 86 0 0.015 - 0.033 NT - Greens, Kale (V-4) 98 4 4.1 0.035 - 0.038 0.015 - 0.033 NT - Orange Juice 557 50 9.0 0.017 - 0.064 0.010 - 0.033 10 0.5 Peaches 90 0 0.010 - 0.033 20 - Plums 515 2 0.4 0.017 ^ 0.010 ^ 20 - Plums, Dried (Prunes) 224 0 0.010 ^ 20 - Potatoes, Frozen (V-32) 744 32 4.3 0.017 - 0.084 0.010 - 0.033 NT - Raisins 108 0 0.033 ^ NT - Spinach 511 0 0.003 - 0.033 NT - Summer Squash (V-11) 54 11 20.4 0.036 - 0.052 0.033 ^ NT - Sweet Peas, Frozen (V-17) 524 17 3.2 0.039 - 0.19 0.015 - 0.033 NT - Watermelon 370 0 0.015 - 0.033 NT - Winter Squash (V-3) 369 3 0.8 0.034 - 0.037 0.008 - 0.033 NT - TOTA L 7,754 168

Phorate (insecticide)

Applesauce 528 0 0.002 ^ NT - Bananas 526 0 0.004 ^ NT - Potatoes, Frozen 744 0 0.003 ^ 0.5 0.2 Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.004 - 0.005 NT - Watermelon 189 0 0.004 ^ NT - Winter Squash 261 0 0.012 ^ NT - TOTA L 3,142 0

Phorate oxygen analog (metabolite of Phorate)

Applesauce 528 0 0.001 ^ NT - Spinach 366 0 0.001 ^ NT - TOTA L 894 0

Appendix B. Page 40 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Phorate sulfone (metabolite of Phorate)

Applesauce 528 0 0.003 ^ NT - Bananas 526 0 0.012 ^ NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Potatoes, Frozen 744 0 0.004 ^ 0.5 0.2 Spinach 366 0 0.003 ^ NT - Sweet Peas, Frozen 528 0 0.010 - 0.012 NT - Watermelon 189 0 0.012 ^ NT - Winter Squash 261 0 0.012 ^ NT - TOTA L 3,885 0

Phorate sulfoxide (metabolite of Phorate)

Applesauce 528 0 0.009 ^ NT - Broccoli 185 0 0.009 ^ NT - Cauliflowe r 558 0 0.009 ^ NT - Potatoes, Frozen 528 0 0.006 ^ 0.5 0.2 Spinach 366 0 0.009 ^ NT - Sweet Peas, Frozen 220 0 0.012 ^ NT - TOTA L 2,385 0

Phosalone (insecticide)

Applesauce 744 6 0.8 0.004 - 0.010 0.002 - 0.006 10.0 2 Bananas 526 0 0.015 ^ NT - Peaches 90 0 0.006 ^ 15.0 2 Plums 515 0 0.039 ^ 15.0 2 Plums, Dried (Prunes) 224 0 0.039 ^ 15.0 2 Raisins 372 0 0.005 - 0.012 20.0 - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.009 - 0.015 NT - Watermelon 189 0 0.015 ^ NT - TOTA L 3,554 6

Phosmet (insecticide)

Applesauce 744 13 1.7 0.008 ^ 0.005 ^ 10 10 Bananas 526 0 0.008 ^ NT - Cranberries 316 0 0.005 - 0.012 10 - Grapefrui t 216 0 0.005 ^ 5 5 Greens, Collard 69 0 0.008 ^ NT - Greens, Kale 61 0 0.008 ^ NT - Orange Juice 557 0 0.005 ^ 5 5 Peaches 90 34 37.8 0.008 - 0.92 0.005 ^ 10 10 Plums 515 80 15.5 0.005 - 0.18 0.003 ^ 5 - Plums, Dried (Prunes) 224 4 1.8 0.005 - 0.16 0.003 ^ 5 - Potatoes, Frozen 744 0 0.005 ^ 0.1 0.05 Raisins 372 13 3.5 0.007 - 0.23 0.004 - 0.010 10 10 Spinach 366 0 0.005 ^ NT - Sweet Peas, Frozen 744 0 0.005 - 0.017 0.5 - Watermelon 189 0 0.008 ^ NT - Winter Squash 261 0 0.012 ^ NT - TOTA L 5,994 144

Phosphamidon (insecticide)

Applesauce 528 0 0.003 ^ NT - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.010 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Spinach 366 0 0.003 ^ NT - Sweet Peas, Frozen 528 0 0.014 - 0.015 NT - Watermelon 189 0 0.015 ^ NT - Winter Squash 261 0 0.029 ^ NT - TOTA L 3,141 0

Appendix B. Page 41 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Piperonyl butoxide (insecticide)

Applesauce 739 0 0.005 - 0.010 8 - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.005 ^ NT - Cauliflowe r 558 0 0.005 ^ NT - Eggplan t 740 0 0.012 ^ NT - Grapefrui t 216 0 0.010 ^ NT 5 Greens, Collard 86 0 0.010 - 0.015 NT - Greens, Kale 98 0 0.010 - 0.015 NT - Orange Juice 557 0 0.010 ^ 8 0.05 Peaches 90 0 0.010 ^ 8 - Plums 515 2 0.4 0.020 - 0.28 0.012 ^ 8 - Plums, Dried (Prunes) 224 10 4.5 0.020 - 0.10 0.012 ^ 8 0.2 Potatoes, Frozen 744 2 0.3 0.017 ^ 0.010 ^ 0.25 0.5 Raisins 372 2 0.5 0.082 - 0.20 0.020 - 0.050 10 0.2 Spinach (V-3) 367 3 0.8 0.008 - 0.040 0.005 - 0.010 NT 50 Summer Squash 186 0 0.010 - 0.025 NT 1 Sweet Peas, Frozen 744 0 0.010 - 0.030 8 - Watermelon 189 0 0.015 ^ NT 1 Winter Squash (V-4) 369 4 1.1 0.014 ^ 0.008 - 0.010 NT 1 TOTA L 7,505 23

Pirimicarb (insecticide)

Applesauce 528 0 0.010 ^ NT 1 Bananas 526 0 0.005 ^ NT - Broccoli 185 0 0.010 ^ NT 1 Cauliflowe r 558 0 0.010 ^ NT 1 Greens, Collard 69 0 0.005 ^ NT - Greens, Kale 61 0 0.005 ^ NT - Spinach 366 0 0.010 ^ NT 1 Sweet Peas, Frozen 308 0 0.005 ^ NT 0.2 Watermelon 189 0 0.005 ^ NT - TOTA L 2,790 0

Pirimiphos methyl (insecticide)

Applesauce (V-1) 528 1 0.2 0.004 ^ 0.002 ^ NT - Bananas 526 0 0.004 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach (V-4) 366 4 1.1 0.004 - 0.018 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.004 - 0.008 NT - Watermelon 189 0 0.004 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 3,141 5

Prallethrin (insecticide)

Applesauce 216 0 0.010 ^ 1.0 - Bananas 742 0 0.010 ^ 1.0 - Carrots 743 0 0.010 - 0.075 1.0 - Cranberries 316 0 0.010 - 0.10 1.0 - Eggplan t 740 0 0.028 ^ 1.0 - Grapefrui t 743 0 0.010 - 0.064 1.0 - Greens, Collard 86 0 0.010 ^ 1.0 - Greens, Kale 98 0 0.010 ^ 1.0 - Orange Juice 557 0 0.005 - 0.010 1.0 - Peaches 90 0 0.005 - 0.010 1.0 - Plums 515 0 0.028 ^ 1.0 - Plums, Dried (Prunes) 224 0 0.028 ^ 1.0 - Potatoes, Frozen 744 0 0.005 - 0.010 1.0 - Raisins 372 1 0.3 0.066 ^ 0.020 - 0.050 1.0 - Spinach 145 0 0.010 ^ 1.0 - Summer Squash 186 0 0.010 - 0.033 1.0 -

Appendix B. Page 42 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Sweet Peas, Frozen 524 0 0.010 ^ 1.0 - Watermelon 550 0 0.010 ^ 1.0 - Winter Squash 369 0 0.010 - 0.024 1.0 - TOTA L 7,960 1

Prochloraz (fungicide) Bananas 526 0 0.002 - 0.005 NT 7 Sweet Peas, Frozen 528 0 0.002 - 0.003 NT - Watermelon 189 0 0.002 ^ NT - TOTA L 1,243 0

Procymidone (fungicide) Bananas 526 0 0.005 ^ NT - Raisins 264 0 0.050 ^ NT 5 Sweet Peas, Frozen 308 0 0.005 ^ NT 1 Watermelon 189 0 0.005 ^ NT - TOTA L 1,287 0

Profenofos (insecticide)

Applesauce 528 0 0.002 ^ NT - Bananas 526 0 0.011 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.010 - 0.011 NT - Watermelon 189 0 0.011 ^ NT - TOTA L 2,880 0

Prometryn (herbicide)

Applesauce 426 0 0.007 ^ NT - Broccoli 185 0 0.007 ^ NT - Carrots 708 0 0.0005 - 0.010 0.1 - Cauliflowe r 433 0 0.007 ^ NT - Orange Juice 44 0 0.010 ^ NT - Spinach 323 0 0.007 ^ NT - Winter Squash 261 0 0.049 ^ NT - TOTA L 2,380 0

Pronamide (herbicide)

Applesauce 744 0 0.006 - 0.008 0.1 - Bananas 526 0 0.008 ^ NT - Broccoli 185 0 0.006 ^ NT - Cauliflowe r 557 0 0.006 ^ NT - Cranberries 84 4 4.8 0.013 ^ 0.008 ^ 0.05 - Peaches 90 0 0.008 ^ 0.1 - Plums 515 0 0.014 ^ 0.1 - Plums, Dried (Prunes) 224 0 0.014 ^ 0.1 - Raisins 372 0 0.016 - 0.030 0.1 - Spinach 366 0 0.006 ^ NT - Sweet Peas, Frozen 744 0 0.005 - 0.008 NT - Watermelon 189 0 0.008 ^ NT - Winter Squash 261 0 0.018 ^ NT - TOTA L 4,857 4

Propamocarb hydrochloride (fungicide) Bananas 526 0 0.010 ^ NT - Potatoes, Frozen 22 0 0.001 ^ 0.06 - Sweet Peas, Frozen 286 0 0.010 ^ NT - Watermelon 189 0 0.010 ^ 1.5 - TOTA L 1,023 0

Appendix B. Page 43 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Propargite (insecticide)

Applesauce 528 0 0.026 ^ NT 3 Bananas 482 0 0.015 ^ NT - Broccoli 185 0 0.026 ^ NT - Cauliflowe r 558 0 0.026 ^ NT - Grapefrui t 607 0 0.004 - 0.030 5 3 Orange Juice 557 0 0.004 - 0.020 5 0.3 Peaches (V-14) 75 14 18.7 0.033 - 0.53 0.020 ^ NT 4 Potatoes, Frozen 744 0 0.004 - 0.020 0.1 0.1 Raisins 372 117 31.5 0.006 - 1.2 0.004 - 0.050 10 12 Spinach 366 0 0.026 ^ NT - Sweet Peas, Frozen 308 0 0.015 ^ NT - Watermelon 189 0 0.015 ^ NT - Winter Squash 261 0 0.008 ^ NT - TOTA L 5,232 131

Propetamphos (insecticide)

Applesauce 744 0 0.002 - 0.003 0.1 - Bananas 742 0 0.003 - 0.004 0.1 - Broccoli 155 0 0.002 ^ 0.1 - Carrots 744 0 0.002 - 0.003 0.1 - Cauliflowe r 558 0 0.002 ^ 0.1 - Cranberries 316 0 0.003 - 0.008 0.1 - Grapefrui t 216 0 0.003 ^ 0.1 - Greens, Collard 86 0 0.003 - 0.010 0.1 - Greens, Kale 98 0 0.003 - 0.010 0.1 - Orange Juice 557 0 0.003 ^ 0.1 - Peaches 90 0 0.003 ^ 0.1 - Plums 515 0 0.008 ^ 0.1 - Plums, Dried (Prunes) 224 0 0.008 ^ 0.1 - Potatoes, Frozen 744 0 0.003 ^ 0.1 - Raisins 372 0 0.006 ^ 0.1 - Spinach 511 0 0.002 - 0.003 0.1 - Summer Squash 186 0 0.003 - 0.006 0.1 - Sweet Peas, Frozen 744 0 0.003 - 0.010 0.1 - Watermelon 550 0 0.003 - 0.006 0.1 - Winter Squash 369 0 0.003 - 0.008 0.1 - TOTA L 8,521 0

Propham (herbicide)

Watermelon 361 0 0.008 - 0.010 NT - TOTA L 361 0

Propiconazole (fungicide)

Applesauce 528 0 0.005 ^ NT - Bananas 742 0 0.010 - 0.020 0.2 0.1 Broccoli 185 0 0.015 ^ NT - Cauliflowe r 558 0 0.005 ^ NT - Cranberries 316 0 0.001 - 0.020 1.0 - Orange Juice 44 0 0.036 ^ NT - Peaches 90 16 17.8 0.033 - 1.4 0.020 - 0.036 1.0 1 Plums 515 8 1.6 0.060 - 0.21 0.036 ^ 1.0 1 Plums, Dried (Prunes) 224 0 0.036 ^ 1.0 1 Spinach 366 0 0.005 ^ NT - Sweet Peas, Frozen 308 0 0.010 ^ NT - Watermelon 189 0 0.010 ^ NT - Winter Squash 261 0 0.016 ^ NT - TOTA L 4,326 24

Pymetrozine (insecticide) Broccoli 169 0 0.005 ^ 0.5 - Cauliflowe r 558 0 0.005 ^ 0.5 -

Appendix B. Page 44 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Potatoes, Frozen 22 0 0.003 ^ NT - Spinach 366 10 2.7 0.008 - 0.046 0.005 ^ 0.6 - TOTA L 1,115 10

Pyraclostrobin (fungicide)

Applesauce 744 0 0.001 ^ 1.5 - Bananas 742 0 0.001 - 0.003 0.04 0.02 Broccoli 185 3 1.6 0.002 - 0.006 0.001 ^ 5.0 - Carrots 744 279 37.5 0.0005 - 0.045 0.0005 - 0.001 0.4 0.5 Cauliflowe r 558 0 0.001 ^ 5.0 - Eggplan t 740 0 0.030 ^ 1.4 - Grapefrui t 743 20 2.7 0.0003 - 0.002 0.0003 - 0.001 2.0 1 Greens, Collard 86 19 22.1 0.002 - 2.8 0.001 - 0.003 16.0 - Greens, Kale 98 19 19.4 0.002 - 0.17 0.001 - 0.003 16.0 - Orange Juice 161 0 0.001 ^ 2.0 1 Peaches 90 23 25.6 0.002 - 0.068 0.001 ^ 0.9 0.5 Potatoes, Frozen 744 0 0.001 ^ 0.04 0.02 Raisins 108 60 55.6 0.002 - 0.13 0.001 ^ 7.0 5 Spinach 511 123 24.1 0.002 - 5.4 0.001 ^ 29.0 - Summer Squash 54 7 13.0 0.004 - 0.032 0.001 ^ 0.5 0.3 Sweet Peas, Frozen 700 3 0.4 0.002 ^ 0.001 - 0.005 0.2 - Watermelon 370 1 0.3 0.002 ^ 0.001 - 0.003 0.5 - Winter Squash 108 10 9.3 0.002 - 0.012 0.001 ^ 0.5 0.3 TOTA L 7,486 567

Pyraflufen ethyl (herbicide) Potatoes, Frozen 528 0 0.036 ^ 0.02 - TOTA L 528 0

Pyridaben (insecticide, acaricide)

Applesauce 216 0 0.015 ^ 0.5 - Bananas (V-1) 1 1 100.0 0.025 ^ 0.015 ^ NT - Cranberries 84 0 0.015 ^ 0.5 - Grapefrui t 743 0 0.001 - 0.015 0.5 - Orange Juice 535 0 0.010 - 0.015 0.5 - Peaches 90 0 0.010 - 0.015 2.5 - Plums 515 0 0.041 ^ 2.5 - Plums, Dried (Prunes) 224 1 0.4 0.068 ^ 0.041 ^ 2.5 - Raisins 372 1 0.3 0.27 ^ 0.030 ^ 1.5 - TOTA L 2,780 3

Pyrimethanil (fungicide)

Applesauce 744 48 6.5 0.0005 - 0.19 0.0003 - 0.003 3.0 - Bananas 742 30 4.0 0.003 - 0.008 0.003 - 0.12 0.10 - Broccoli 185 0 0.0003 ^ NT - Cauliflowe r 558 0 0.0003 ^ NT - Greens, Collard 69 0 0.003 ^ NT - Greens, Kale 61 0 0.003 ^ NT - Peaches 19 3 15.8 0.14 - 0.42 0.003 ^ 3.0 - Potatoes, Frozen 238 0 0.003 - 0.005 0.05 - Raisins 372 1 0.3 0.024 ^ 0.003 - 0.050 8.0 - Spinach (V-3) 366 3 0.8 0.0005 - 0.005 0.0003 ^ NT - Sweet Peas, Frozen 308 0 0.003 ^ NT - Watermelon 189 0 0.003 ^ NT - TOTA L 3,851 85

Pyriproxyfen (insecticide, growth regulator )

Applesauce 744 0 0.008 - 0.013 0.2 - Bananas 742 0 0.008 - 0.015 0.10 - Broccoli 185 0 0.013 ^ 0.70 - Carrots 744 0 0.0004 - 0.008 0.10 -

Appendix B. Page 45 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Cauliflowe r 558 0 0.013 ^ 0.70 - Cranberries 84 0 0.008 ^ 0.10 - Eggplan t 740 0 0.012 ^ 0.2 - Grapefrui t 216 0 0.008 ^ 0.3 0.5 Greens, Collard 17 0 0.008 ^ 2.0 - Greens, Kale 37 0 0.008 ^ 2.0 - Orange Juice 557 0 0.008 ^ 0.3 0.5 Peaches 90 0 0.008 ^ 1.0 - Plums 515 2 0.4 0.020 ^ 0.012 ^ 1.0 - Plums, Dried (Prunes) 224 0 0.012 ^ 1.0 - Potatoes, Frozen 744 0 0.008 ^ 0.10 - Raisins 372 0 0.016 - 0.030 2.5 - Spinach 511 0 0.008 - 0.013 0.10 - Summer Squash 186 0 0.008 - 0.015 0.10 - Sweet Peas, Frozen 744 0 0.008 - 0.030 0.20 - Watermelon 550 0 0.004 - 0.015 0.10 - Winter Squash 108 0 0.008 ^ 0.10 - TOTA L 8,668 2

Quinoxyfen (fungicide) Raisins 372 12 3.2 0.0008 - 0.012 0.0005 - 0.030 0.6 - Watermelon 341 0 0.0005 - 0.004 0.3 - TOTA L 713 12

Quintozene - PCNB (fungicide) (parent of HCB, PCA and PCB )

Applesauce 513 0 0.010 ^ NT - Bananas 526 0 0.002 ^ NT - Broccoli 185 0 0.010 ^ 0.1 0.05 Carrots (V-2) 2 2 100.0 0.012 - 0.079 0.003 ^ NT - Cauliflowe r 558 0 0.003 - 0.040 0.1 - Greens, Collard 77 0 0.003 - 0.005 0.2 - Greens, Kale 85 0 0.003 - 0.005 0.2 - Orange Juice 396 0 0.003 ^ NT - Potatoes, Frozen 744 0 0.003 ^ 0.1 - Spinach 366 0 0.003 - 0.019 NT - Sweet Peas, Frozen 528 0 0.0009 - 0.002 NT - Watermelon 189 0 0.002 ^ NT - Winter Squash 261 0 0.004 ^ NT - TOTA L 4,430 2

Resmethrin (insecticide)

Applesauce 216 0 0.010 ^ 3.0 - Bananas 742 0 0.010 - 0.030 3.0 - Carrots 743 0 0.010 - 0.030 3.0 - Cranberries 84 0 0.010 ^ 3.0 - Grapefrui t 743 0 0.010 - 0.015 3.0 - Greens, Collard 86 0 0.010 - 0.033 3.0 - Greens, Kale 98 0 0.010 - 0.033 3.0 - Orange Juice 557 0 0.010 ^ 3.0 - Peaches 90 0 0.010 ^ 3.0 - Potatoes, Frozen 744 0 0.010 ^ 3.0 - Raisins 372 0 0.020 - 0.030 3.0 - Spinach 145 0 0.010 - 0.033 3.0 - Summer Squash 186 0 0.010 - 0.030 3.0 - Sweet Peas, Frozen 744 0 0.010 - 0.060 3.0 - Watermelon 550 0 0.010 - 0.030 3.0 - Winter Squash 369 0 0.010 - 0.032 3.0 - TOTA L 6,469 0

Resmethrin-c (isomer of Resmethrin)

Applesauce 528 0 0.002 ^ 3.0 - Broccoli 185 0 0.002 ^ 3.0 -

Appendix B. Page 46 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Cauliflowe r 558 0 0.002 ^ 3.0 - Spinach 366 0 0.002 ^ 3.0 - TOTA L 1,637 0

Resmethrin-t (isomer of Resmethrin)

Applesauce 528 0 0.002 ^ 3.0 - Broccoli 185 0 0.002 ^ 3.0 - Cauliflowe r 542 0 0.002 ^ 3.0 - Spinach 366 0 0.002 ^ 3.0 - TOTA L 1,621 0

Sethoxydim (herbicide) Cauliflowe r 466 0 0.001 ^ 4.0 - Spinach 320 0 0.001 ^ 4.0 - Watermelon 20 0 0.050 ^ 4.0 - TOTA L 806 0

Simazine (herbicide)

Applesauce 744 0 0.002 ^ 0.25 - Bananas 742 0 0.002 - 0.011 0.2 - Broccoli 185 0 0.006 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Cranberries 84 0 0.002 ^ 0.25 - Grapefrui t 216 0 0.002 ^ 0.25 - Orange Juice 557 0 0.002 - 0.010 0.25 - Peaches 90 0 0.002 - 0.010 0.25 - Plums 515 0 0.036 ^ 0.25 - Plums, Dried (Prunes) 224 0 0.036 ^ 0.25 - Raisins 372 0 0.002 - 0.030 0.25 - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.009 - 0.011 NT - Watermelon 189 0 0.011 ^ NT - Winter Squash 261 0 0.018 ^ NT - TOTA L 5,631 0

Spinosad Total (insecticide)

Applesauce 216 0 0.003 ^ 0.20 0.1 Carrots 216 0 0.003 ^ 0.10 - Cranberries (X-1 ) 84 2 2.4 0.013 - 0.025 0.003 ^ 0.01 - Greens, Collard 17 2 11.8 0.015 - 0.032 0.003 ^ 10.0 10 Greens, Kale 37 2 5.4 0.005 - 0.030 0.003 ^ 10.0 10 Peaches 19 2 10.5 0.005 - 0.025 0.003 ^ 0.20 0.2 Potatoes, Frozen 216 0 0.003 ^ 0.10 0.01 Raisins 108 0 0.003 ^ 0.70 1 Spinach 145 55 37.9 0.005 - 0.65 0.003 - 0.004 8.0 10 Summer Squash 54 0 0.003 ^ 0.3 0.2 Sweet Peas, Frozen 216 2 0.9 0.005 ^ 0.003 - 0.004 0.3 0.3 Watermelon 181 0 0.003 ^ 0.3 0.2 Winter Squash 108 0 0.003 ^ 0.3 0.2 TOTA L 1,617 65

Spinosad A (isomer of Spinosad) Bananas 526 0 0.002 ^ 0.25 - Greens, Collard 68 6 8.8 0.003 - 0.084 0.002 ^ 10.0 10 Potatoes, Frozen 22 0 0.001 ^ 0.10 0.01 Sweet Peas, Frozen 308 0 0.002 ^ 0.3 0.3 Watermelon 189 0 0.002 ^ 0.3 0.2 TOTA L 1,113 6

Spinosad D (isomer of Spinosad) Bananas 526 0 0.002 ^ 0.25 - Greens, Collard 69 3 4.3 0.002 - 0.028 0.002 ^ 10.0 10

Appendix B. Page 47 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Greens, Kale 61 5 8.2 0.007 - 0.54 0.002 ^ 10.0 10 Potatoes, Frozen 22 0 0.001 ^ 0.10 0.01 Sweet Peas, Frozen 264 0 0.002 ^ 0.3 0.3 Watermelon 189 0 0.002 ^ 0.3 0.2 TOTA L 1,131 8

Spirodiclofen (acaricide) Bananas 526 0 0.010 ^ NT - Raisins 242 0 0.050 ^ 4.0 - Watermelon 189 0 0.010 ^ NT - TOTA L 957 0

Spiromesifen (insecticide) Bananas 526 0 0.002 ^ NT - Broccoli 185 2 1.1 0.010 - 0.037 0.006 ^ 2.0 - Cauliflowe r 46 0 0.006 ^ 2.0 - Greens, Collard 56 0 0.002 ^ 12 - Greens, Kale 53 0 0.002 ^ 12 - Spinach 18 0 0.006 ^ 12 - Sweet Peas, Frozen 308 0 0.002 ^ NT - Watermelon 189 0 0.002 ^ 0.10 - TOTA L 1,381 2

Sulfentrazone (herbicide) Potatoes, Frozen 216 1 0.5 0.006 ^ 0.002 ^ 0.15 - Sweet Peas, Frozen 216 0 0.002 - 0.004 0.15 - TOTA L 432 1

Sulprofos (insecticide)

Applesauce 528 0 0.002 ^ NT - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - TOTA L 1,637 0

Tebuconazole (fungicide) Applesauce 528 0 0.002 ^ NT 0.5 Bananas 742 0 0.020 - 0.023 0.05 0.05 Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Orange Juice 44 0 0.020 ^ NT - Peaches 19 2 10.5 0.033 ^ 0.020 ^ 1.0 1 Raisins 372 6 1.6 0.059 - 0.072 0.040 - 0.050 5.0 3 Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.015 - 0.023 NT - Watermelon 189 0 0.023 ^ NT - TOTA L 3,531 8

Tebufenozide (insecticide) Applesauce 744 0 0.003 ^ 1.0 1 Bananas 460 0 0.005 ^ NT - Broccoli 185 0 0.003 ^ 5.0 0.5 Cauliflowe r 558 0 0.003 ^ 5.0 - Cranberries 316 20 6.3 0.005 - 0.054 0.003 - 0.051 1.0 0.5 Greens, Collard 86 0 0.003 - 0.005 10.0 10 Greens, Kale 98 0 0.003 - 0.005 10.0 10 Raisins 108 10 9.3 0.005 - 0.039 0.003 ^ 3.0 2 Spinach 511 1 0.2 0.049 ^ 0.003 ^ 10.0 10 Sweet Peas, Frozen 308 0 0.005 ^ NT - Watermelon 168 0 0.005 ^ NT - TOTA L 3,542 31

Appendix B. Page 48 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Tecnazene (plant growth regulator) Bananas 526 0 0.001 ^ NT - Broccoli 169 0 0.005 ^ NT - Spinach 366 0 0.005 ^ NT - Sweet Peas, Frozen 528 0 0.001 - 0.002 NT - Watermelon 189 0 0.001 ^ NT - TOTA L 1,778 0

TEPP (insecticide) Applesauce 322 0 0.006 ^ NT - TOTA L 322 0

Terbacil (herbicide) Applesauce 744 0 0.006 - 0.020 0.3 - Bananas 526 0 0.015 ^ NT - Broccoli 185 0 0.006 ^ 5.0 - Cauliflowe r 558 0 0.006 ^ NT - Peaches 90 0 0.020 ^ 0.2 - Spinach 366 0 0.006 ^ NT - Sweet Peas, Frozen 308 0 0.015 ^ NT - Watermelon 550 0 0.015 - 0.080 0.4 - Winter Squash 261 0 0.018 ^ NT - TOTA L 3,588 0

Terbufos (insecticide) Applesauce 528 0 0.002 ^ NT - Bananas 742 0 0.005 - 0.006 0.025 0.05 Broccoli 155 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - Sweet Peas, Frozen 528 0 0.005 - 0.010 NT - Watermelon 189 0 0.005 ^ NT - Winter Squash 261 0 0.015 ^ NT - TOTA L 3,327 0

Terbufos sulfone (metabolite of Terbufos) Applesauce 528 0 0.002 ^ NT - Bananas 216 0 0.004 ^ 0.025 0.05 Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.002 ^ NT - Spinach 366 0 0.002 ^ NT - Winter Squash 261 0 0.018 ^ NT - TOTA L 2,114 0

Tetrachlorvinphos (insecticide) Applesauce 528 0 0.003 ^ NT - Broccoli 185 0 0.010 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Spinach 366 0 0.003 ^ NT - Winter Squash 261 0 0.008 ^ NT - TOTA L 1,898 0

Tetradifon (insecticide) Applesauce 744 0 0.006 - 0.010 5 - Bananas 526 0 0.004 ^ NT - Broccoli 185 0 0.010 ^ NT - Cauliflowe r 557 0 0.032 ^ NT - Grapefrui t 743 0 0.006 - 0.007 2 - Orange Juice 557 0 0.006 - 0.012 2 - Peaches 90 0 0.006 ^ NT - Plums 515 0 0.011 ^ 5 - Plums, Dried (Prunes) 224 0 0.011 ^ 5 -

Appendix B. Page 49 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Raisins 372 0 0.012 - 0.030 NT - Spinach 366 0 0.010 ^ NT - Sweet Peas, Frozen 528 0 0.004 - 0.005 NT - Watermelon 550 0 0.004 - 0.024 1 - Winter Squash 369 0 0.006 - 0.028 1 - TOTA L 6,326 0

Tetrahydrophthalimide - THPI (metabolite of Captafol and Captan ) Applesauce 744 162 21.8 0.033 - 0.17 0.020 - 0.040 25 - Bananas 526 0 0.075 ^ NT - Broccoli 185 0 0.020 ^ 2 - Carrots 216 7 3.2 0.067 - 0.14 0.040 ^ 2 - Cauliflowe r 558 0 0.020 - 0.13 2 - Greens, Collard 17 0 0.039 ^ 2 - Greens, Kale 37 0 0.039 ^ 2 - Peaches 68 2 2.9 0.065 - 0.16 0.039 - 0.040 50 - Potatoes, Frozen 216 0 0.040 ^ 25 - Raisins 108 0 0.080 ^ 50 - Spinach 493 0 0.020 - 0.040 100 - Summer Squash 38 3 7.9 0.067 - 0.19 0.040 ^ 25 - Sweet Peas, Frozen 524 0 0.040 - 0.075 2 - Watermelon 370 0 0.040 - 0.080 25 - Winter Squash 369 0 0.009 - 0.040 25 - TOTA L 4,469 174

Tetramethrin (insecticide) Bananas 526 0 0.015 ^ NT - Sweet Peas, Frozen 308 0 0.015 ^ NT - Watermelon 189 0 0.015 ^ NT - TOTA L 1,023 0

Thiabendazole (fungicide) (parent of 5-hydroxythiabendazole ) Applesauce 744 289 38.8 0.0002 - 1.2 0.0001 - 0.030 10 3 Bananas 742 486 65.5 0.002 - 0.74 0.001 - 0.030 3 5 Broccoli (V-3) 185 3 1.6 0.0002 ^ 0.0001 ^ NT - Carrots 744 3 0.4 0.002 - 0.004 0.001 - 0.030 10 - Cauliflower (V-3 ) 558 3 0.5 0.0002 - 0.001 0.0001 - 0.0002 NT - Grapefrui t 216 144 66.7 0.002 - 0.16 0.001 - 0.030 10 10 Greens, Collard 69 0 0.010 ^ NT - Greens, Kale 61 0 0.010 ^ NT - Orange Juice 557 55 9.9 0.002 - 0.062 0.001 - 0.030 10 10 Peaches (V-3) 31 3 9.7 0.002 - 0.13 0.001 - 0.030 NT - Potatoes, Frozen 744 28 3.8 0.002 - 0.15 0.001 - 0.030 10 15 Spinach (V-14) 375 14 3.7 0.0008 - 0.007 0.0005 - 0.001 NT - Sweet Peas, Frozen (V-2) 486 2 0.4 0.002 ^ 0.001 - 0.050 NT - Watermelon (V-2) 190 2 1.1 0.005 - 0.017 0.001 - 0.010 NT - Winter Squash 369 1 0.3 0.075 ^ 0.001 - 0.045 1.0 - TOTA L 6,071 1,033

Thiacloprid (insecticide) Applesauce 744 95 12.8 0.0007 - 0.006 0.0004 - 0.001 0.3 - Broccoli 185 0 0.002 ^ NT - Cauliflowe r 558 0 0.0004 - 0.0005 NT - Spinach (V-1) 366 1 0.3 0.0007 ^ 0.0004 ^ NT - TOTA L 1,853 96

Thiamethoxam (insecticide) (also a parent of Clothianidin) Applesauce 744 0 0.001 - 0.10 0.2 - Bananas 526 0 0.010 - 0.050 NT - Broccoli 185 0 0.10 ^ NT - Carrots 744 0 0.001 - 0.003 0.02 - Cauliflowe r 542 0 0.060 ^ NT -

Appendix B. Page 50 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Cranberries 84 1 1.2 0.003 ^ 0.001 ^ 0.02 - Greens, Collard (V-4) 69 4 5.8 0.021 - 0.026 0.010 ^ NT - Greens, Kale (V-2) 61 2 3.3 0.050 - 0.058 0.010 ^ NT - Peaches 90 0 0.001 ^ 0.5 - Potatoes, Frozen 744 63 8.5 0.002 - 0.015 0.001 ^ 0.25 - Spinach 337 0 0.050 ^ NT - Summer Squash 186 10 5.4 0.002 - 0.023 0.001 - 0.040 0.2 - Sweet Peas, Frozen 700 1 0.1 0.002 ^ 0.001 - 0.10 0.02 - Watermelon 550 23 4.2 0.002 - 0.025 0.001 - 0.050 0.2 - Winter Squash 108 23 21.3 0.002 - 0.011 0.001 ^ 0.2 - TOTA L 5,670 127

Thiazopyr (herbicide) Grapefrui t 527 0 0.001 ^ 0.05 - Orange Juice 396 0 0.010 ^ 0.05 - TOTA L 923 0

Thiobencarb (herbicide) Applesauce 528 0 0.0006 ^ NT - Broccoli 185 0 0.0006 ^ 7.0 - Cauliflowe r 558 0 0.0006 ^ NT - Orange Juice 44 0 0.010 ^ NT - Spinach 366 0 0.0006 ^ NT - TOTA L 1,681 0

Tri-Allate (herbicide) Bananas 526 0 0.015 ^ NT - Sweet Peas, Frozen 524 0 0.010 - 0.015 0.05 - Watermelon 189 0 0.015 ^ NT - TOTA L 1,239 0

Triadimefon (fungicide) (also a parent of Triadimenol) Applesauce 744 0 0.0009 - 0.025 1.0 0.5 Bananas 742 0 0.011 - 0.025 NT - Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.0009 ^ NT - Orange Juice 44 0 0.025 ^ NT - Raisins 372 0 0.050 ^ 1.0 0.5 Spinach 366 0 0.0009 ^ NT - Summer Squash 186 0 0.025 - 0.030 0.3 0.1 Sweet Peas, Frozen 528 0 0.011 - 0.012 NT 0.05 Watermelon 550 0 0.011 - 0.025 0.3 0.1 Winter Squash 369 0 0.023 - 0.025 0.3 0.1 TOTA L 4,644 0

Triadimenol (fungicide) (also a metabolite of Triadimefon) Applesauce 216 0 0.015 ^ NT 0.5 Bananas 742 0 0.011 - 0.015 0.2 0.2 Raisins 372 0 0.030 - 0.050 NT 2 Summer Squash 186 0 0.015 - 0.050 NT 2 Sweet Peas, Frozen 308 0 0.011 ^ NT 0.1 Watermelon 370 0 0.011 - 0.015 NT 2 Winter Squash 108 0 0.015 ^ NT 2 TOTA L 2,302 0

Trifloxystrobin (fungicide) Applesauce 744 4 0.5 0.0002 - 0.0006 0.0001 - 0.001 0.5 0.7 Bananas 742 0 0.001 - 0.005 0.10 0.05 Broccoli 185 0 0.0004 ^ NT 0.5 Carrots 744 0 0.0004 - 0.001 0.10 0.1 Cauliflowe r 558 0 0.0001 - 0.0004 NT 0.5 Grapefrui t 743 0 0.0004 - 0.001 0.3 0.5

Appendix B. Page 51 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm Greens, Collard 69 0 0.005 ^ NT - Greens, Kale (V-1) 61 1 1.6 0.006 ^ 0.005 ^ NT - Orange Juice 557 0 0.001 - 0.010 0.3 0.5 Peaches 90 1 1.1 0.047 ^ 0.0007 - 0.001 2 3 Potatoes, Frozen 744 1 0.1 0.006 ^ 0.001 ^ 0.04 0.02 Raisins 372 96 25.8 0.002 - 0.18 0.001 - 0.030 5.0 5 Spinach 366 0 0.0001 - 0.0004 NT - Summer Squash 186 0 0.001 - 0.010 0.5 0.3 Sweet Peas, Frozen 308 0 0.005 ^ NT - Watermelon 550 0 0.001 - 0.005 0.50 0.3 Winter Squash 108 4 3.7 0.002 - 0.048 0.001 - 0.002 0.50 0.3 TOTA L 7,127 107

Triflumizole (fungicide) Applesauce 216 0 0.050 ^ 0.5 - Bananas 526 0 0.003 ^ NT - Greens, Collard 86 0 0.003 - 0.050 20 - Greens, Kale 98 0 0.003 - 0.050 20 - Raisins 372 0 0.050 - 0.10 2.5 - Summer Squash 186 0 0.050 ^ 0.5 - Sweet Peas, Frozen 308 0 0.003 ^ NT - Watermelon 410 0 0.003 - 0.050 0.5 - Winter Squash 369 0 0.040 - 0.050 0.5 - TOTA L 2,571 0

Trifluralin (herbicide) Applesauce 528 0 0.0005 ^ NT - Bananas 526 0 0.015 ^ NT - Carrots 743 427 57.5 0.002 - 0.19 0.002 - 0.017 1.0 - Cauliflowe r 417 1 0.2 0.0008 ^ 0.0005 ^ 0.05 - Cranberries 232 0 0.003 ^ NT - Grapefrui t 743 0 0.001 - 0.017 0.05 - Greens, Collard 86 0 0.015 - 0.017 0.05 - Greens, Kale 98 0 0.015 - 0.017 0.05 - Orange Juice 557 0 0.017 ^ 0.05 - Peaches 90 0 0.017 ^ 0.05 - Plums 515 0 0.021 ^ 0.05 - Plums, Dried (Prunes) 224 0 0.021 ^ 0.05 - Potatoes, Frozen 744 0 0.017 ^ 0.05 - Raisins 372 0 0.030 - 0.034 0.05 - Spinach 511 6 1.2 0.0008 - 0.006 0.0005 - 0.017 0.05 - Summer Squash 186 0 0.017 - 0.030 0.05 - Sweet Peas, Frozen 744 0 0.015 - 0.017 0.05 - Watermelon 550 0 0.015 - 0.017 0.05 - Winter Squash 369 0 0.008 - 0.017 0.05 - TOTA L 8,235 434

Triforine (fungicide) Applesauce 528 0 0.003 ^ NT 2 Broccoli 185 0 0.003 ^ NT - Cauliflowe r 558 0 0.003 ^ NT - Spinach 366 0 0.003 ^ NT - TOTA L 1,637 0

V inclozolin (fungicide) Applesauce 528 0 0.004 ^ NT 1 Bananas 526 0 0.003 ^ NT - Broccoli 185 0 0.004 ^ NT - Cauliflowe r 558 0 0.004 ^ NT 1 Cranberries 232 0 0.050 ^ NT - Orange Juice 396 0 0.003 ^ NT - Peaches 71 0 0.008 ^ NT 5

Appendix B. Page 52 of 53Pesticide / Commodity Number of Samples Samples with Detections % of Samples with Detections Range of Values Detected, ppm Range of LODs, ppm EPA Tolerance Level, ppm Codex MRL/EMRL, ppm
Raisins 372 0 0.014 - 0.050 6.0 5 Spinach 366 0 0.004 ^ NT - Sweet Peas, Frozen 528 0 0.003 ^ NT 1 Watermelon 189 0 0.003 ^ NT - Winter Squash 261 0 0.014 ^ NT - TOTA L 4,212 0

Zoxamide (fungicide) Raisins 264 0 0.050 ^ 15.0 - Summer Squash 132 0 0.050 ^ 1.0 - Watermelon 180 0 0.025 ^ 1.0 - TOTA L 576 0

NOTES ^ Only one distinct detected concentration or LOD value was reported for the pair. NT = No tolerance level was set for that pesticide/commodity pair. AL = Numbers shown are Action Levels established by FDA and Codex Extraneous Maximum Residue Levels (EMRLs) for som e pesticides. Under FQPA, responsibility for establishing tolerances in lieu of action levels has been transferred to EPA. In t he interim, action levels are used. SU Safe use in spot and/or crack and crevice treatments. (V) = Residue was found where no tolerance was established by EPA. Following "V" are the number of occurrences. (X) = Residue was found which exceeds EPA tolerance or FDA action level. Following "X" are the number of occurrences.
** = Previously reported as lambda cyhalothrin total, which included lambda cyhalothrin (a 1:1 mixture of the cis-(1R,3R),S-enantiom e r and the cis-(1S,3S),R-enantiomer) as well as R157836 (a 1:1 mixture of the cis-(1S,3S),S-enantiomer and the cis-(1R,3R), R-enantiomer). 

## M

any of the listed tolerances and MRLs are the sum of a parent compound and metabolite(s)/isomer(s). The reader is advised to refer to EPA for the complete listing of compounds in tolerance expressions and to Codex for the complete listing of compounds in MRL expressions.

Appendix B. Page 53 of 53

# Appendix C
Distribution of Residues by Pesticide in Peanut Butter

Appendix C shows residue detections fo r all peanut butter compounds tested, including range of values detected, range of Limits of Detection (LODs), and Environmental Protection Agency (EPA) and Codex Maximum Residue Limit/ Extraneous Maximum Residue Limit (MRL/EMRL) tolerance references for each pair.
In 2006, PDP analyzed 739 peanut butter samples. A total of 223 samples (30 percent) were reported with residue detections . All residue detections were much lower than the established tolerances.
See Appendix B for definition of ALs and MRLs.
MRLs/EMRLs shown in this appendix ar e from the Codex Alimentarius: Proc. of Codex Committee on Pesticide Residues , 39 th 

## Session, May 7-12, 2007, Beijing, China. Only Codex MRLs (CXLs) are listed.
EPA tolerances as published in 40 CFR Part 180 are expressed in parts per million (ppm). Because peanut butter residues are expressed in parts per billion (ppb), EPA Tolerances and Codex MRLs have been multip lied by a factor of 1,000 as a basis for comparison using a single sc ale. There is no intention to imply any more exactness in the value than that origina lly expressed by EPA and Codex.
The information herein is only intended to be an initial reference. Readers are reminded that international r egulations and MRLs can change and that it is important that information obtained from this table be verified with knowledgeable parties in the market of interest prior to sale or shipment of exports.Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*



### Alachlor H 739 3.0 ^ 50 -

Aldicarb I 668 10 ^ 50 20

Aldicarb sulfone IM 706 10 ^ 50 20

Aldicarb sulfoxide IM 662 10 ^ 50 20

Aldrin I 689 6.0 ^ 50 AL -
Azoxystrobin F 739 1.0 ^ 200 -

Bendiocarb I 713 3.0 ^ SU -

Benfluralin H 719 3.0 ^ 50 -

Benoxacor S 739 3.0 ^ 10 -

Bifenthrin I 739 13 ^ 50 -

Boscalid F 724 10 ^ 50 - Carbaryl I 739 10 ^ 5,000 -

Carboxin F 734 1 0.1 17 ^ 10 ^ 200 - Carfentrazone ethyl H 719 1.0 ^ 100 -

Chlordane cis I 739 3.0 ^ 100 AL 20

Chlordane trans I 739 36 ^ 100 AL 20 Chlorpyrifos I 739 27 ^ 200 - Cyfluthrin I 739 75 ^ 10 -
Cyhalothrin, Total (Cyhalothrin-L + R157836) I 739 12 ^ 50 - Cypermethrin I 739 100 ^ NT 50
DDD p,p' IM 739 14 ^ 200 AL -
DDE p,p' IM 739 27 3.7 7.0 ^ 4.0 ^ 200 AL -
DDT p,p' I 734 6.0 ^ 200 AL -
Deltamethrin (includes parent Tralomethrin) I 734 50 ^ 50 -
Dichlorvos (DDVP) I 699 7.0 ^ 500 4 -

Dieldrin I 738 3.0 ^ 50 AL -

Dimethenamid H 739 3.0 ^ 10 10

Disulfoton I 619 10 ^ 750 100

Disulfoton sulfoxide IM 734 55 ^ 750 100

Esfenvalerate+Fenvalerate Total I 661 20 ^ 50 100

Ethalfluralin H 719 2.0 ^ 50 - 

## APPENDIX C. DISTRIBUTION OF RESIDUES BY PESTICIDE IN PEANUT BUTTER

Appendix C. Page 1 of 3Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb* 

### Ethoprop I 739 6.0 ^ 20 -
Fenamiphos I 739 3.0 ^ 20 50
Fenamiphos sulfone IM 719 3.0 ^ 20 50
Fenamiphos sulfoxide IM 635 4.0 ^ 20 50
Fenoxaprop ethyl H 739 4.0 ^ 50 -
Fenpropathrin I 739 50 ^ 10 -

Fluazinam F 701 2 0.3 17 ^ 10 ^ 20 -

Fludioxonil F 739 9.0 ^ 10 -

Flumioxazin H 720 5.0 ^ 20 -

Flutolanil F 739 7.0 ^ 500 - Hexachlorobenzene (HCB) FM 719 3.0 ^ 1,000 -
Hydroprene R 739 8.0 ^ 200 -

Indoxacarb I 739 10 ^ 10 20
Iprodione F 739 50 ^ 500 -

Lactofen H 736 9.0 ^ 10 -
Malathion I 739 1 0.1 17 ^ 10 ^ 8,000 -
Malathion oxygen analog IM 739 10 ^ NT -
Metalaxyl F 739 20 ^ 200 100
Methamidophos I 700 10 ^ 200 -
Methomyl I 674 10 ^ 100 -

Metolachlor H 739 10 ^ 500 -

Norflurazon H 739 6.0 ^ 50 -
Norflurazon desmethyl HM 739 11 ^ 50 -
Oxamyl I 739 10 ^ 200 50
Parathion methyl I 739 25 ^ 1,000 -
Parathion methyl oxygen analog IM 655 5.0 ^ NT -

Pendimethalin H 739 20 ^ 100 -
Pentachloroaniline (PCA) FM 739 7 0.9 25 ^ 15 ^ 1,000 -
Pentachlorobenzene (PCB) FM 719 1 0.1 27 ^ 16 ^ 1,000 -
Pentachlorophenyl methyl sulfide FM 739 7.0 ^ 1,000 -

Phorate I 719 10 ^ 100 -

Phorate sulfone IM 739 10 ^ 100 -

Phorate sulfoxide IM 720 44 ^ 100 -

Appendix C. Page 2 of 3Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*


### Piperonyl butoxide I 739 200 27.1 33 - 136 20 ^ 8,000 1,000
Prallethrin I 718 50 ^ 1,000 -
Propargite I 659 8.0 ^ 100 100
Propetamphos I 720 2.0 ^ 100 -
Propiconazole F 739 45 ^ 200 100
Pyraclostrobin F 733 1.0 ^ 50 20
Pyriproxyfen I 739 1.0 ^ 100 -
Quintozene (PCNB) F 739 4 0.5 10 - 162 6.0 ^ 1,000 500
Resmethrin I 739 9.0 ^ 3,000 -
Spinosad A I 739 15 ^ 20 -

Tebuconazole F 688 10 ^ 100 50
Trifloxystrobin F 733 1.0 ^ 50 20

Trifluralin H 739 2.0 ^ 50 -



### NOTES * = EPA Tolerances and Codex MRLs have been multiplied by a factor of 1000 as a basis for comparison

using a single scale. There is no intention to imply any more exactness in the value than that originally expressed by EPA and Codex. ^ = Only one distinct detected concentration or LOD value was reported for the pair. NT = No tolerance level was set for that pesticide/commodity pair. AL = Numbers shown are Action Levels established by FDA and Codex Extraneous Maximum Residue Levels (EMRLs)

for some pesticides. Under FQPA, responsibility for establishing tolerances in lieu of action levels has been transferred to EPA. In the interim, action levels are used.

Pesticide Types: F = Fungicide, FM = Fungicide Metabolite H = Herbicide, HM = Herbicide Metabolite I = Insecticide, IM = Insecticide Metabolite R = Insect Growth Regulator
S = Herbicide Safener



## M

any of the listed tolerances and MRLs are the sum of a parent compound and metabolite(s)/isomer(s). The reader is advised to refer to EPA for the complete listing of compounds in tolerance expressions and to Codex for the complete listing of compounds in MRL expressions.

Appendix C. Page 3 of 3

# Appendix D

Distribution of Residues by Pesticide in Wheat

Appendix D shows residue detections for all wheat compounds tested, including range of values detected, range of Limits of Detection (LODs), and Environmental Protection Agency (EPA) and Codex Maxi mum Residue Limit/Extraneous Maximum Residue Limit (MRL/EMRL) toleranc e references for each pair.
In 2006, PDP analyzed 687 wheat samples. A total of 475 samples (69 percent) were reported with residue detections. All but one of the residue detections were much lower than the established tolerances.
See Appendix B for definition of ALs and MRLs.
MRLs/EMRLs shown in this appendix ar e from the Codex Alimentarius: Proc. of Codex Committee on Pesticide Residues , 39 th 

## Session, May 7-12, 2007, Beijing, China. Only Codex MRLs (CXLs) are listed.
EPA tolerances as published in 40 CFR Part 180 are expressed in parts per million (ppm). Because wheat residues are expressed in parts per billion (ppb), EPA Tolerances and Codex MRLs have been multiplied by a factor of 1,000 as a basis for comparison using a single scale . There is no intention to imply any more exactness in the value than than originally expressed by EPA and Codex.
The information herein is only intended to be an initial reference. Readers are reminded that international r egulations and MRLs can change and that it is important that information obtained from this table be verified with knowledgeable parties in the market of interest prior to sale or shipment of exports.Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*



### Acetochlor H 687 3.0 ^ 20 -
Allethrin I 667 3.0 ^ 2,000 -

Atrazine H 687 13 1.9 5.0 ^ 3.0 ^ 250 -

Bromuconazole 46 FM 687 6.0 ^ NT -

Bromuconazole 47 FM 687 4.0 ^ NT - Carbaryl I 687 6.0 ^ 3,000 2,000
Carbofuran (X-1) I 667 1 0.1 169 ^ 34 ^ 100 -

Carboxin F 687 3.0 ^ 200 - Carfentrazone ethyl H 687 3.0 ^ 100 - Chlorpyrifos I 687 4 0.6 10 ^ 6.0 ^ 500 500 Chlorpyrifos methyl I 687 115 16.7 32 - 1081 19 ^ 6,000 10,000 Clodinafop propargyl H 667 3.0 ^ 100 - Cyanazine H 667 5.0 ^ NT - Cyfluthrin I 682 8 1.2 38 - 914 23 ^ 4,000 -
Cyhalothrin, Total (Cyhalothrin-L + R157836) I 665 7 1.1 7.0 ^ 4.0 ^ 50 - Cyproconazole F 687 11 ^ NT -
DDE p,p' IM 687 3.0 ^ 500 100

Diazinon I 687 3.0 ^ NT -
Diazinon oxygen analog IM 665 6.0 ^ NT -
Diclofop methyl H 687 3.0 ^ 100 -

Dieldrin I 687 6.0 ^ 20 AL 20

Difenoconazole F 668 1 0.1 7.0 ^ 4.0 ^ 100 -

Dimethoate I 687 28 ^ 40 50
Dimethomorph F 687 19 ^ 50 -

Disulfoton I 687 3.0 ^ 300 200

Disulfoton sulfone IM 687 13 ^ 300 200

Endosulfan I I 687 6.0 ^ 100 200

Endosulfan II IM 687 6.0 ^ 100 200

Endosulfan sulfate IM 687 3.0 ^ 100 200
Epoxiconazole F 687 4.0 ^ NT -

Etridiazole F 667 10 ^ 50 -

Fenbuconazole F 667 18 ^ NT 100 

## APPENDIX D. DISTRIBUTION OF RESIDUES BY PESTICIDE IN WHEAT

Appendix D. Page 1 of 3Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*


### Fenitrothion I 687 6.0 ^ NT 10,000

Fludioxonil F 687 9.0 ^ 20 50
Flufenacet H 687 6.0 ^ 1,000 -

Fluridone H 667 3.0 ^ 100 -
Heptachlor epoxide IM 687 3.0 ^ NT 20

Hexaconazole F 687 4.0 ^ NT -
3-Hydroxycarbofuran IM 476 6.0 ^ 200 -

Imazalil F 687 1 0.1 47 ^ 28 ^ 50 10 Lindane (BHC gamma) I 687 6.0 ^ 100 AL 10

Linuron H 687 25 ^ 250 -
Malathion I 687 433 63.0 5.0 - 2370 3.0 ^ 8,000 500
Malathion oxygen analog IM 687 5.0 ^ NT -
Metalaxyl F 687 6.0 ^ 200 50
Methoprene (V-18) R 667 18 2.7 22 - 362 13 ^ NT 10,000
Methoxychlor p,p' (V-29) IM 687 29 4.2 8.0 ^ 5.0 ^ NT -

Metolachlor H 687 3.0 ^ 100 -

Metribuzin H 531 6.0 ^ 750 -
Myclobutanil F 687 13 ^ 30 -

Omethoate IM 687 3.0 ^ 40 -
Parathion ethyl I 687 5.0 ^ 1,000 -
Parathion oxygen analog IM 687 19 ^ NT -

Phorate I 343 8.0 ^ 50 50

Phorate sulfone IM 687 5.0 ^ 50 50
Piperonyl butoxide I 687 16 2.3 10 ^ 6.0 ^ 20,000 30,000
Pirimiphos methyl (V-11) I 687 11 1.6 5.0 - 12 3.0 ^ NT 7,000
Propanil H 687 10 1.5 8.0 ^ 5.0 ^ 200 -
Propiconazole F 687 11 ^ 100 50
RH 9129 (fenbuconazole metab.) FM 687 5.0 ^ NT -
RH 9130 (fenbuconazole metab.) FM 687 4.0 ^ NT -

TCMTB F 607 25 ^ 100 -

Tebuconazole F 687 10 ^ 50 50

Tetraconazole F 687 4.0 ^ NT -
Thiabendazole F 582 13 ^ 1,000 -

Appendix D. Page 2 of 3Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*



### Thiamethoxam I 667 3.0 ^ 20 -

Tri Allate H 687 6.0 ^ 50 -
Triadimefon F 687 3.0 ^ 1,000 100

Triadimenol F 559 6.0 ^ 50 200

Trifluralin H 687 2 0.3 10 ^ 6.0 ^ 50 -

Triticonazole F 687 4.0 ^ 50 -



### NOTES * = EPA Tolerances and Codex MRLs have been multiplied by a factor of 1000 as a basis for comparison

using a single scale. There is no intention to imply any more exactness in the value than that originally expressed by EPA and Codex. ^ = Only one distinct detected concentration or LOD value was reported for the pair. NT = No tolerance level was set for that pesticide/commodity pair. AL = Numbers shown are Action Levels established by FDA and Codex Extraneous Maximum Residue Levels (EMRLs)

for some pesticides. Under FQPA, responsibility for establishing tolerances in lieu of action levels has been transferred to EPA. In the interim, action levels are used. (X) = Residue was found which exceeds EPA tolerance. Following "X" are the number of occurrences. (V) = Residue was found where no tolerance was established by EPA. Following "V" are the number of occurrences.

Pesticide Types: F = Fungicide, FM = Fungicide Metabolite
H = Herbicide I = Insecticide, IM = Insecticide Metabolite R = Insect Growth Regulator



## M

any of the listed tolerances and MRLs are the sum of a parent compound and metabolite(s)/isomer(s). The reader is advised to refer to EPA for the complete listing of compounds in tolerance expressions and to Codex for the complete listing of compounds in MRL expressions.

Appendix D. Page 3 of 3

# Appendix E

Distribution of Residues by Pesticide in Poultry

Appendix E shows residue detections for all poultry compounds tested, including range of values detected, range of Limits of Detection (LODs), and Environmental Protection Agency (EPA) and Codex Maxi mum Residue Limit/Extraneous Maximum Residue Limit (MRL/EMRL) toleranc e references for each pair.
In 2006, PDP analyzed poultry tissue samples which included 655 breast samples and 655 thigh samples, primarily from young chickens. A total of 40 breast samples (6 percent) and 54 thigh samples (8 percent) were reported with residue detections. None of the poultry sample s contained residues that exceeded the established EPA tolerance.
See Appendix B for definition of ALs and MRLs.
MRLs/EMRLs shown in this appendix ar e from the Code x Alimentarius: Proc. of Codex Committee on Pesticide Residues , 39 th 

## Session, May 7-12, 2007, Beijing, China. Only Codex MRLs (CXLs) are listed.
EPA tolerances as published in 40 CFR Pa rt 180 are expressed in parts per million (ppm). Because poultry residues are expressed in parts per billion (ppb), EPA Tolerances and Codex MRLs have been multipli ed by a factor of 1,000 as a basis for comparison using a single scale. There is no intention to imply anymore exactness in the value than that originally expressed by EPA and Codex.
The information herein is only intended to be an initial reference. Readers are reminded that international r egulations and MRLs can change an d that it is important that information obtained from this table be verified with knowledgeable parties in the market of interest prior to sale or shipment of exports.Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*


### Acephate I Poultry, Breast 655 15 ^ 100 10 Poultry, Thigh 655 15 ^ 100 10
Acetamiprid I Poultry, Breast I 655 6.9 ^ 10 - Poultry, Thigh I 655 6.9 ^ 10 -

Alachlor H Poultry, Breast 655 1.5 ^ 20 - Poultry, Thigh 655 1.5 ^ 20 -

Aldicarb I Poultry, Breast 655 0.21 ^ NT 10 Poultry, Thigh 655 0.21 ^ NT 10

Aldicarb sulfone IM Poultry, Breast 655 1.2 ^ NT 10 Poultry, Thigh 655 1.2 ^ NT 10

Aldicarb sulfoxide IM Poultry, Breast 655 6.8 ^ NT 10 Poultry, Thigh 655 6.8 ^ NT 10

Atrazine H Poultry, Breast 655 0.30 ^ NT - Poultry, Thigh 655 0.30 ^ NT -
Azoxystrobin F Poultry, Breast 655 3.0 ^ NT - Poultry, Thigh 655 3.0 ^ NT -

Benoxacor S Poultry, Breast 655 0.30 ^ 10 - Poultry, Thigh 655 0.30 ^ 10 -

Bifenthrin I Poultry, Breast 655 0.90 ^ 50 50 Poultry, Thigh 655 0.90 ^ 50 50

Boscalid F Poultry, Breast 655 1 0.2 1.5 ^ 0.30 ^ 50 - Poultry, Thigh 655 0.30 ^ 50 -
Buprofezin I Poultry, Breast 655 1.8 ^ NT - Poultry, Thigh 655 1.8 ^ NT -
Carbaryl I Poultry, Breast 655 9 1.4 0.50 - 1.5 0.30 ^ 5,000 50 Poultry, Thigh 655 15 2.3 0.50 - 2.1 0.30 ^ 5,000 50

Carbofuran I Poultry, Breast 655 0.15 ^ NT - Poultry, Thigh 655 0.15 ^ NT - 

## APPENDIX E. DISTRIBUTION OF RESIDUES BY PESTICIDE IN POULTRY

Appendix E. Page 1 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*



### Carboxin F Poultry, Breast 655 1.5 ^ 100 - Poultry, Thigh 655 1.5 ^ 100 -

Chloroneb F Poultry, Breast 655 1.8 ^ NT - Poultry, Thigh 655 1.8 ^ NT -
Chlorpyrifos I Poultry, Breast 655 1.5 ^ 100 10 Poultry, Thigh 655 1.5 ^ 100 10
Chlorpyrifos methyl I Poultry, Breast 655 0.45 ^ 500 500 Poultry, Thigh 655 0.45 ^ 500 500

Clofentezine I Poultry, Breast 655 0.45 ^ NT 50 Poultry, Thigh 655 0.45 ^ NT 50
Cyfluthrin I Poultry, Breast 655 2.4 ^ 10 - Poultry, Thigh 655 2.4 ^ 10 -
Cyhalothrin, Lambda I Poultry, Breast 655 0.90 ^ 10 - Poultry, Thigh 655 0.90 ^ 10 -
Cypermethrin I Poultry, Breast 655 3.0 ^ 50 50 Poultry, Thigh 655 3.0 ^ 50 50
DDE p,p' IM Poultry, Breast 655 9 1.4 0.75 - 2.7 0.45 ^ 5,000 300 Poultry, Thigh 655 20 3.1 0.75 - 3.6 0.45 ^ 5,000 300
Deltamethrin (includes parent Tralomethrin) I Poultry, Breast 655 4.5 ^ 20 100 Poultry, Thigh 655 4.5 ^ 20 100
Dichlorvos (DDVP) I Poultry, Breast 655 1.5 ^ 50 50 Poultry, Thigh 655 1.5 ^ 50 50

Difenoconazole F Poultry, Breast 655 2.4 ^ 50 - Poultry, Thigh 655 2.4 ^ 50 -

Diflubenzuron I Poultry, Breast 655 0.30 ^ 50 50 Poultry, Thigh 655 0.30 ^ 50 50

Dimethoate I Poultry, Breast 655 3.0 ^ 20 50 Poultry, Thigh 655 3.0 ^ 20 50

Appendix E. Page 2 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*


### Diphenamid H Poultry, Breast 655 0.60 ^ NT - Poultry, Thigh 655 0.60 ^ NT -

Esfenvalerate+Fenvalerate Total I Poultry, Breast 655 1.5 ^ 50 1,000 Poultry, Thigh 655 1.5 ^ 50 1,000

Ethalfluralin H Poultry, Breast 655 0.60 ^ NT - Poultry, Thigh 655 0.60 ^ NT -

Ethofumesate H Poultry, Breast 655 0.90 ^ NT - Poultry, Thigh 655 0.90 ^ NT -

Etridiazole F Poultry, Breast 655 0.90 ^ 100 - Poultry, Thigh 655 0.90 ^ 100 -

Fenarimol F Poultry, Breast 655 0.90 ^ NT - Poultry, Thigh 655 0.90 ^ NT -

Fenbuconazole F Poultry, Breast 655 1.2 ^ NT 50 Poultry, Thigh 655 1.2 ^ NT 50
Fenoxaprop ethyl H Poultry, Breast 655 0.90 ^ NT - Poultry, Thigh 655 0.90 ^ NT -
Fenpropathrin I Poultry, Breast 655 0.90 ^ 50 20 Poultry, Thigh 655 0.90 ^ 50 20
Fipronil I Poultry, Breast 655 1 0.2 1.0 ^ 0.60 ^ 20 10 Poultry, Thigh 655 2 0.3 1.0 - 1.2 0.60 ^ 20 10

Flufenacet H Poultry, Breast 655 4.5 ^ NT - Poultry, Thigh 655 4.5 ^ NT -

Fluridone H Poultry, Breast 655 0.90 ^ 50 - Poultry, Thigh 655 0.90 ^ 50 -
Fluroxypyr 1-methylheptyl ester H Poultry, Breast 655 0.90 ^ NT - Poultry, Thigh 655 0.90 ^ NT -

Flutolanil F Poultry, Breast 655 0.30 ^ 50 50 Poultry, Thigh 655 0.30 ^ 50 50

Appendix E. Page 3 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*



### Fluvalinate I Poultry, Breast 655 1.5 ^ NT - Poultry, Thigh 655 1.5 ^ NT -
Heptachlor I Poultry, Breast 655 0.45 ^ 200 200 Poultry, Thigh 655 0.45 ^ 200 200
Heptachlor epoxide IM Poultry, Breast 655 3.0 ^ 200 200 Poultry, Thigh 655 3.0 ^ 200 200

Hexazinone H Poultry, Breast 655 2.4 ^ NT - Poultry, Thigh 655 2.4 ^ NT -
Hydroprene R Poultry, Breast 655 1.5 ^ 200 - Poultry, Thigh 655 1.5 ^ 200 -
3-Hydroxycarbofuran IM Poultry, Breast 655 0.60 ^ NT - Poultry, Thigh 655 0.60 ^ NT -
Imidacloprid I Poultry, Breast 655 1.5 ^ 50 20 Poultry, Thigh 655 1.5 ^ 50 20

Indoxacarb I Poultry, Breast 655 0.15 ^ NT 10 Poultry, Thigh 655 0.15 ^ NT 10
Iprodione F Poultry, Breast 655 5.4 ^ 1,000 - Poultry, Thigh 655 5.4 ^ 1,000 -

Isoxaflutole H Poultry, Breast 655 1.8 ^ 200 - Poultry, Thigh 655 1.8 ^ 200 -

Malathion I Poultry, Breast 655 1.5 ^ 4,000 - Poultry, Thigh 655 1.5 ^ 4,000 -
Malathion oxygen analog IM Poultry, Breast 655 7.5 ^ NT - Poultry, Thigh 655 7.5 ^ NT -
Metalaxyl F Poultry, Breast 655 1.2 ^ 50 - Poultry, Thigh 655 1.2 ^ 50 -
Methamidophos I Poultry, Breast 655 6.0 ^ 100 10 Poultry, Thigh 655 6.0 ^ 100 10

Appendix E. Page 4 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*


### Methoxyfenozide I Poultry, Breast 655 0.15 ^ 20 10 Poultry, Thigh 655 0.15 ^ 20 10

Metolachlor H Poultry, Breast 655 0.90 ^ 40 - Poultry, Thigh 655 0.90 ^ 40 -

Metribuzin H Poultry, Breast 655 4.5 ^ 700 - Poultry, Thigh 655 4.5 ^ 700 -

MGK-264 I Poultry, Breast (V-13) 655 13 2.0 5.0 - 81 3.0 ^ NT - Poultry, Thigh (V-14) 655 14 2.1 5.0 - 221 3.0 ^ NT -
MGK-326 (dipropyl isocinchomeronate) I Poultry, Breast 655 0.90 ^ NT - Poultry, Thigh 655 0.90 ^ NT -

Mirex I Poultry, Breast 655 0.90 ^ NT - Poultry, Thigh 655 0.90 ^ NT -
Myclobutanil F Poultry, Breast 655 1.8 ^ 20 10 Poultry, Thigh 655 1.8 ^ 20 10
1-Naphthol IM Poultry, Breast 655 1.5 ^ 5,000 - Poultry, Thigh 655 1 0.2 2.5 ^ 1.5 ^ 5,000 -
Nitrapyrin N Poultry, Breast 655 0.90 ^ 50 - Poultry, Thigh 655 0.90 ^ 50 -

Norflurazon H Poultry, Breast 655 0.30 ^ 100 - Poultry, Thigh 655 0.30 ^ 100 -

Omethoate IM Poultry, Breast 655 6.0 ^ 20 - Poultry, Thigh 655 6.0 ^ 20 -

Oxadiazon H Poultry, Breast 655 0.60 ^ NT - Poultry, Thigh 655 0.60 ^ NT -
Oxyfluorfen H Poultry, Breast 655 0.60 ^ 50 - Poultry, Thigh 655 0.60 ^ 50 -

Permethrin Total IM Poultry, Breast 655 3.0 ^ 50 100 Poultry, Thigh 655 3.0 ^ 50 100

Appendix E. Page 5 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*


### Piperonyl butoxide I Poultry, Breast 655 15 2.3 7.5 - 85 4.5 ^ 3,000 7,000 Poultry, Thigh 655 22 3.4 7.5 - 218 4.5 ^ 3,000 7,000

Prallethrin I Poultry, Breast 655 5.4 ^ 1,000 - Poultry, Thigh 655 5.4 ^ 1,000 -

Profenofos I Poultry, Breast 655 3.0 ^ NT 50 Poultry, Thigh 655 3.0 ^ NT 50

Pronamide H Poultry, Breast 655 0.30 ^ 20 - Poultry, Thigh 655 0.30 ^ 20 -
Propachlor H Poultry, Breast 655 3.6 ^ 20 - Poultry, Thigh 655 3.6 ^ 20 -
Propanil H Poultry, Breast 655 1.2 ^ 100 - Poultry, Thigh 655 1.2 ^ 100 -
Propargite I Poultry, Breast 655 3.6 ^ 100 100 Poultry, Thigh 655 3.6 ^ 100 100
Propetamphos I Poultry, Breast 655 1.5 ^ 100 - Poultry, Thigh 655 1.5 ^ 100 -
Propiconazole F Poultry, Breast 655 1.5 ^ NT 50 Poultry, Thigh 655 1.5 ^ NT 50
Pyrethrins I Poultry, Breast 655 1 0.2 100 ^ 60 ^ 200 - Poultry, Thigh 655 1 0.2 100 ^ 60 ^ 200 -
Pyridaben I Poultry, Breast 655 1.8 ^ NT - Poultry, Thigh 655 1.8 ^ NT -
Pyriproxyfen I Poultry, Breast 655 1.2 ^ 100 - Poultry, Thigh 655 1.2 ^ 100 -

Resmethrin-t IM Poultry, Breast 655 1.5 ^ 3,000 - Poultry, Thigh 655 1.5 ^ 3,000 -
Sethoxydim H Poultry, Breast 655 0.30 ^ 200 - Poultry, Thigh 655 0.30 ^ 200 -

Appendix E. Page 6 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb*



### Simazine H Poultry, Breast 655 2.0 ^ 20 - Poultry, Thigh 655 2.0 ^ 20 -

Tebufenozide I Poultry, Breast 655 0.15 ^ NT 20 Poultry, Thigh 655 0.15 ^ NT 20
Tetrachlorvinphos I Poultry, Breast 655 1.2 ^ 750 - Poultry, Thigh 655 1.2 ^ 750 -

Tetraconazole F Poultry, Breast 655 2.4 ^ 10 - Poultry, Thigh 655 2.4 ^ 10 -
Tetrahydrophthalimide (THPI) FM Poultry, Breast 655 6.0 ^ NT - Poultry, Thigh 655 6.0 ^ NT -

Thiabendazole F Poultry, Breast 655 3.0 ^ 100 50 Poultry, Thigh 655 1 0.2 5.0 ^ 3.0 ^ 100 50

Thiobencarb H Poultry, Breast 655 0.60 ^ 200 - Poultry, Thigh 655 0.60 ^ 200 -

Triadimefon F Poultry, Breast 655 1.5 ^ 40 50 Poultry, Thigh 655 1.5 ^ 40 50

Triadimenol F Poultry, Breast 655 2.4 ^ 10 50 Poultry, Thigh 655 2.4 ^ 10 50
Trifloxystrobin F Poultry, Breast 655 0.90 ^ 40 40 Poultry, Thigh 655 0.90 ^ 40 40

Triflumizole F Poultry, Breast 655 0.90 ^ 50 - Poultry, Thigh 655 0.90 ^ 50 -

Vinclozolin F Poultry, Breast 655 0.30 ^ 100 - Poultry, Thigh 655 0.30 ^ 100 -



### NOTES * = EPA Tolerances and Codex MRLs have been multiplied by a factor of 1000 as a basis for comparison using a single scale.

There is no intention to imply any more exactness in the value than that originally expressed by EPA and Codex. ^ = Only one distinct detected concentration or LOD value was reported for the pair.



## M

any of the listed tolerances and MRLs are the sum of a parent compound and metabolite(s)/isomer(s). The reader is advised to refer to EPA for the complete listing of compounds in tolerance expressions and to Codex for the complete listing of compounds in MRL expressions.

Appendix E. Page 7 of 8Pesticide / Commodity Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppb Range of LODs, ppb EPA Tolerance Level, ppb* Codex MRL/EMRL, ppb* NT = No tolerance level was set for that pesticide/commodity pair. AL = Numbers shown are Action Levels established by FDA and Codex Extraneous Maximum Residue Levels (EMRLs) for some

pesticides. Under FQPA, responsibility for establishing tolerances in lieu of action levels has been transferred to EPA. In the interim, action levels are used. (V) = Residue was found where no tolerance was established by EPA. Following "V" are the number of occurrences.

Pesticide Types: F = Fungicide, FM = Fungicide Metabolite
H = Herbicide I = Insecticide, IM = Insecticide Metabolite N = Nitrification Inhibitor R = Insect Growth Regulator S = Herbicide Safener

Appendix E. Page 8 of 8

# Appendix F

Distribution of Residues by Pesticide in Bottled Water

Appendix F shows residue detections fo r all bottled water compounds tested, including range of values detected and range of Limits of Detection (LODs) for each pair. The Food and Drug Administration (FDA) Standards of Quality (SOQ) values for bottled water are also shown.
In 2006, PDP analyzed 367 bottled water sa mples. A total of 70 samples (19%) were reported with residue detections. Twelve different residues from six different pesticides were detected. Most sample s with detectable residues contained only a single pesticide or metabolite. A few of t he samples contained mult iple residues with a maximum of four detectable pe sticides within a given sample . All detections were well below established FDA SOQs.
Bottled water is regulated by the FDA an d State regulatory agencies for the same list of pesticides currently regulated in public drinking water by EPA. The Safe Drinking Water Act amendments of 1996 require that FDA consider applicability of all EPA MCLs and monitoring for bottled wate r. FDA has adopted EPA’s MCLs for municipal water systems as its SOQs for bottled water. The SOQ values can be referenced in the Code of Federal Regu lations (CFR), Title 21, Part 165.110.
FDA SOQ values are expressed in parts per million (ppm). Because bottled water residues are expressed in parts per tr illion (ppt), the FDA SOQ values have been multiplied by a factor of 1,000,000 as a basis for comparison using a single scale. There is no intention to imply any more ex actness in the value than that originally expressed by FDA.Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppt Range of LODs, ppt FDA SOQ, ppt 1



### 2,4 DB H 367 4.0 ^
2,4-D H 367 2 0.5 3.2 - 4.2 2.5 ^ 70,000

Acetochlor H 367 1 0.3 30 ^ 10 ^ Acetochlor ethanesulfonic acid (ESA) HM 367 1 0.3 15 ^ 9.0 ^ Acetochlor oxanilic acid (OA) HM 367 10 ^

Alachlor H 367 10 ^ 2,000 Alachlor ethanesulfonic acid (ESA) HM 367 21 5.7 15 - 87.8 12.5 ^ Alachlor oxanilic acid (OA) HM 367 10 ^

Atrazine H 367 12 3.3 10 - 33.1 10 ^ 3,000 Bensulfuron methyl H 367 5.0 ^

Bentazon H 1 1 100 1.2 ^ 0.30 ^

Boscalid F 367 100 ^

Bromacil H 367 6.0 ^ Carbaryl I 367 7.5 ^

Carbofuran I 367 4.0 ^ 40,000 Chlorimuron ethyl H 367 6.0 ^

Chlorothalonil F 367 30 ^ Chlorpyrifos I 367 30 ^

Clomazone H 367 30 ^ Clopyralid H 367 12.5 ^ Cyanazine H 367 50 ^

DCPA H 367 30 ^ Desethyl Atrazine HM 367 41 11.2 17 - 120 10 ^ Desethyl-desisopropyl Atrazine HM 367 17 4.6 20.5 - 124 15 ^ Desisopropyl atrazine HM 367 8 2.2 50 - 83 50 ^

Diazinon I 367 30 ^

Dimethenamid H 367 10 ^

Dimethenamid ESA HM 367 2.0 ^ Dimethenamid oxanilic acid (OA) HM 367 3.0 ^

Dimethoate I 367 50 ^

Disulfoton sulfone IM 367 6.0 ^

Diuron H 367 4.0 ^

EPTC H 367 30 ^

Ethalfluralin H 367 30 ^ 

## APPENDIX F. DISTRIBUTION OF RESIDUES BY PESTICIDE IN BOTTLED WATER

Appendix F. Page 1 of 3Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppt Range of LODs, ppt FDA SOQ, ppt 1



### Flufenacet H 63 2.5 ^

Flufenacet OA HM 304 2.5 ^

Fonofos I 367 30 ^

Halosulfuron H 367 9.0 ^ Hydroxy Atrazine HM 367 17 4.6 3.0 - 31.5 2.0 ^

Imazamethabenz acid H 367 3.0 ^ Imazamethabenz methyl H 367 1.5 ^

Imazamox H 367 4.0 ^ Imazapic H 367 3.0 ^ Imazapyr H 367 2.5 ^ Imazaquin H 367 5.0 ^ Imazethapyr H 367 2.0 ^

Linuron H 367 6.0 ^

Malathion I 367 30 ^

MCPA H 367 1.5 ^

MCPB H 367 3.0 ^ Metalaxyl F 367 2.5 ^

Metolachlor H 367 15 ^ Metolachlor ethanesulfonic acid (ESA) HM 367 39 10.6 5.0 - 2020 3.0 ^ Metolachlor oxanilic acid (OA) HM 367 18 4.9 3.5 - 66.9 3.0 ^

Metribuzin H 367 30 ^ Metsulfuron methyl H 367 7.0 ^ Myclobutanil F 367 50 ^

Neburon H 367 3.0 ^

Nicosulfuron H 367 8.0 ^ Parathion methyl I 367 30 ^

Pendimethalin H 367 30 ^

Phorate I 367 30 ^

Picloram H 367 12.5 ^ 500,000

Prometon H 367 30 ^ Prometryn H 367 1.0 ^ Propachlor H 367 30 ^ Propachlor OA HM 367 3.0 ^ Propanil H 367 30 ^ Propazine H 367 30 ^

Appendix F. Page 2 of 3Pesticide Pest. Type Number of Samples Samples with Detections % of Samples w/

Detects Range of Values Detected, ppt Range of LODs, ppt FDA SOQ, ppt 1


### Propiconazole F 367 50 ^ Propoxur I 367 3.0 ^

Siduron H 367 2.0 ^

Simazine H 367 30 ^ 4,000 Sulfometuron methyl H 367 2.5 ^

Tebuconazole F 367 50 ^ Tebupirimfos I 367 30 ^

Tebuthiuron H 367 30 ^

Terbufos I 367 30 ^

Tetraconazole F 367 30 ^

Thifensulfuron H 367 5.0 ^

Thiobencarb H 367 2.5 ^

Tri Allate H 367 30 ^

Triasulfuron H 367 7.0 ^

Trifluralin H 367 30 ^



### NOTES

1 

### = FDA SOQ values have been multiplied by a factor of 1,000,000 as a basis for comparison using a single scale.

There is no intention to imply any more exactness in the value than that originally expressed by FDA. ^ = Only one distinct detected concentration or LOD value was reported for the pair.

Pesticide Types: F = Fungicide H = Herbicide, HM = Herbicide Metabolite
I = Insecticide

Appendix F. Page 3 of 3

# Appendix G

Distribution of Residues by Pesticide in Drinking Water

Appendix G shows residue detections for all drinking water compounds tested, including range of values detected and range of Limits of Detection (LODs). The Environmental Protection Agency (EPA) Nati onal Primary Drinking Water Regulation (NPDWR) Maximum Contaminant Levels (MCLs) for drinking water, Health Advisory (HA) values for drinking water, and Freshwat er Aquatic Organism (FAOs) Criteria for ambient water are also shown. Units for LODs, MCLs, HAs, and FAOs are shown in parts per trillion (ppt).
In 2006, PDP analyzed 737 drinking wate r samples, including 368 finished drinking water samples and 369 untreated (raw intake) drinking water samples. PDP detected 39 different pesticide residues in fi nished drinking water and 48 residues in the untreated intake water; most of the detections were herbicides. None of the finished drinking water samples exceeded EPA MCLs or HAs for any pesticide detected. In fact, the majority of pesti cides included in the PDP screens were not detected.
The MCLs are legally enfor ceable standards that apply to public water systems. EPA’s regulations for MCLs can be referenced at http://www.epa.gov/safewater/ mcl.html . The HAs are an estimate of acceptabl e drinking water levels for a chemical substance based on health effects information. The values published are for lifetime HA, which is the concentration of a chemical in drinking water that is not expected to cause any adverse noncarcinogenic effects fo r a lifetime of exposure. The HA values can be referenced at http://www.epa. gov/waterscience/criteria/drinking . FAO criteria are set by EPA and are the concentration of a chemical in water at or below which aquatic life are protected from acute and chronic adverse effe cts of the chemical. The FAO values can be referenced at http ://www.epa.gov/water science/criteria/ wqcriteria.html . Health Advisories and FAO criteria are not legally enforceable Federal standards, but serve as technical guidance to a ssist Federal, State, and local officials.
EPA MCL, HA, and FAO values are expre ssed in parts per million (ppm). Because drinking water residues are expre ssed in parts per trillion (ppt), EPA MCL, HA, and FAO values have been multiplied by a factor of 1,000,000 as a basis for comparison using a single scale . There is no intention to imply any more exactness in the value than that originally expressed by EPA.Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### 1,2,4-Triazole FM Water, Finished 114 220 ^ Water, Untreated 89 220 ^

2 4 5 T H Water, Finished 365 1.6 - 22 70,000 Water, Untreated 367 1.6 - 22
2,4 DB H Water, Finished 365 14 - 151 Water, Untreated 367 14 - 151
2,4-D H Water, Finished 365 180 49.3 1.1 - 313 0.65 - 90 70,000 Water, Untreated 367 197 53.7 1.1 - 2416 0.65 - 90

Acetochlor H Water, Finished 363 3 0.8 15.3 - 82.4 9.2 - 49.5 Water, Untreated 364 7 1.9 15.3 - 435 9.2 - 49.5

Acetochlor ethanesulfonic acid (ESA) HM Water, Finished 368 66 17.9 2.7 - 163 1.6 - 45 Water, Untreated 369 78 21.1 2.7 - 191 1.6 - 45 Acetochlor oxanilic acid (OA) HM Water, Finished 368 63 17.1 2.3 - 176 0.68 - 45 Water, Untreated 369 75 20.3 1.1 - 151 0.68 - 45

Acifluorfen H Water, Finished 117 79 - 80 Water, Untreated 118 79 - 80

Alachlor H Water, Finished 363 7.8 - 45 2,000 Water, Untreated 364 7.8 - 45

Alachlor ethanesulfonic acid (ESA) HM Water, Finished 368 70 19.0 2.8 - 357 1.7 - 45 Water, Untreated 369 90 24.4 2.8 - 186 1.7 - 45 Alachlor oxanilic acid (OA) HM Water, Finished 368 27 7.3 1.0 - 4.6 0.61 - 45 Water, Untreated 369 40 10.8 1.0 - 20 0.61 - 45

Aldicarb I Water, Finished 209 9.8 - 1500 3,000 7,000 Water, Untreated 211 9.8 - 1500

Aldicarb sulfone IM Water, Finished 117 200 ^ 2,000 7,000 Water, Untreated 118 200 ^ 

## APPENDIX G. DISTRIBUTION OF RESIDUES BY PESTICIDE IN DRINKING WATER

Appendix G. Page 1 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Aldicarb sulfoxide IM Water, Finished 117 0.50 ^ 4,000 7,000 Water, Untreated 118 0.50 ^

Aldrin I Water, Finished 251 5.0 - 25 Water, Untreated 251 5.0 - 25 3,000

Atrazine H Water, Finished 368 312 84.8 1.1 - 1838 0.66 - 25 3,000 Water, Untreated 369 304 82.4 1.1 - 2474 0.66 - 25 Azinphos methyl I Water, Finished 245 10 - 12 Water, Untreated 246 10 - 12 Azinphos methyl oxygen analog IM Water, Finished 133 8.7 ^ Water, Untreated 133 8.7 ^

Benfluralin H Water, Finished 235 9.8 - 50 Water, Untreated 236 9.8 - 50 Benomyl F Water, Finished 117 30 ^ Water, Untreated 118 30 ^ Bensulfuron methyl H Water, Finished 345 1.2 - 54 Water, Untreated 347 1.2 - 54

Bentazon H Water, Finished 365 49 13.4 0.30 - 16 0.18 - 209 200,000 Water, Untreated 367 90 24.5 0.30 - 18 0.18 - 209 BHC alpha I Water, Finished 118 20 ^ Water, Untreated 118 20 ^

Bifenthrin I Water, Finished 251 3.2 - 5.0 Water, Untreated 251 3.2 - 5.0

Bromacil H Water, Finished 248 2.5 - 9.6 70,000 Water, Untreated 249 3 1.2 4.2 - 16 2.5 - 9.6 Bromoxynil H Water, Finished 232 6.0 - 39 Water, Untreated 234 6.0 - 39

Bromuconazole 46 FM Water, Finished 133 6.5 ^ Water, Untreated 133 6.5 ^

Bromuconazole 47 FM Water, Finished 133 9.4 ^ Water, Untreated 133 9.4 ^

Appendix G. Page 2 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Butachlor H Water, Finished 245 1.9 - 5.3 Water, Untreated 246 1.9 - 5.3 Butylate H Water, Finished 251 1.8 - 10 400,000 Water, Untreated 251 1.8 - 10 Carbaryl I Water, Finished 365 12 - 23 Water, Untreated 367 1 0.3 20 ^ 12 - 23 Carbendazim (MBC) F Water, Finished 115 1.8 ^ Water, Untreated 116 5 4.3 3.0 - 11 1.8 ^

Carbofuran I Water, Finished 365 4 1.1 1.0 - 2.0 0.60 - 17 40,000 Water, Untreated 367 1 0.3 2.0 ^ 0.60 - 17 Carbophenothion I Water, Finished 235 5.3 - 11 Water, Untreated 236 5.3 - 11

Chloramben H Water, Finished 100 60 ^ 100,000 Water, Untreated 101 60 ^

Chlordane cis I Water, Finished 235 2.3 - 5.0 2,000 4 

### Water, Untreated 236 2.3 - 5.0 2,400

Chlordane trans I Water, Finished 235 2.3 - 5.0 2,000 4 

### Water, Untreated 236 2.3 - 5.0 2,400 Chlorfenvinphos Total I Water, Finished 368 7.5 - 24 Water, Untreated 369 7.5 - 24 Chlorimuron ethyl H Water, Finished 203 8.4 - 13 Water, Untreated 205 1 0.5 14 ^ 8.4 - 13

Chlorothalonil F Water, Finished 118 50 ^ Water, Untreated 118 50 ^ Chlorpyrifos I Water, Finished 235 6.0 - 11 2,000 83 Water, Untreated 236 6.0 - 11 Chlorpyrifos methyl I Water, Finished 235 11.3 - 14 Water, Untreated 236 11.3 - 14 Chlorpyrifos oxygen analog IM Water, Finished 118 510 ^ Water, Untreated 118 510 ^

Appendix G. Page 3 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### Clopyralid H Water, Finished 360 58 16.1 5.7 - 77 3.4 - 151 Water, Untreated 362 59 16.3 5.7 - 170 3.4 - 151 Coumaphos I Water, Finished 225 3.8 - 61 Water, Untreated 226 3.8 - 61 Cyanazine H Water, Finished 368 1.7 - 25 1,000 Water, Untreated 369 1.7 - 25 Cycloate H Water, Finished 205 3.3 - 6.0 Water, Untreated 204 3.3 - 6.0 Cyfluthrin I Water, Finished 251 40 - 75 Water, Untreated 251 40 - 75 Cyhalothrin, Lambda I Water, Finished 32 21 ^ Water, Untreated 32 21 ^ Cyhalothrin, Total (Cyhalothrin-L + R157836 epimer) I Water, Finished 219 21 - 75 Water, Untreated 219 21 - 75 Cypermethrin I Water, Finished 251 74 - 90 Water, Untreated 251 74 - 90 Cyphenothrin I Water, Finished 180 14 - 75 Water, Untreated 180 14 - 75 Cyproconazole F Water, Finished 133 3.1 ^ Water, Untreated 133 3.1 ^

DCPA H Water, Finished 235 4 1.7 1.3 ^ 0.80 - 2.5 70,000 Water, Untreated 236 0.75 - 2.5

DCPA monoacid H Water, Finished 115 222 ^ Water, Untreated 116 222 ^
DDD o,p' IM Water, Finished 112 3.8 ^ Water, Untreated 113 3.8 ^
DDD p,p' IM Water, Finished 117 3.8 ^ Water, Untreated 118 3.8 ^

Appendix G. Page 4 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### DDE o,p' IM Water, Finished 118 4.0 ^ Water, Untreated 118 4.0 ^
DDE p,p' IM Water, Finished 235 2.5 - 7.5 Water, Untreated 236 2.5 - 7.5
DDT o,p' I Water, Finished 117 3.7 - 3.8 Water, Untreated 118 3.7 - 3.8
DDT p,p' I Water, Finished 117 3.8 ^ Water, Untreated 118 3.8 ^ DEF (Tribufos) H Water, Finished 118 8.0 ^ Water, Untreated 118 8.0 ^ Deltamethrin (includes parent Tralomethrin) I Water, Finished 133 84 ^ Water, Untreated 133 84 ^ Desethyl Atrazine HM Water, Finished 368 220 59.8 0.72 - 584 0.43 - 25 Water, Untreated 369 244 65.6 0.72 - 366 0.43 - 25 Desisopropyl atrazine HM Water, Finished 368 126 34.2 5.2 - 98 3.1 - 50 Water, Untreated 369 136 36.6 5.2 - 312 3.1 - 50

Diazinon I Water, Finished 368 3.3 - 7.5 1,000 170 Water, Untreated 369 3.3 - 7.5 Diazinon oxygen analog IM Water, Finished 235 9.0 - 49 Water, Untreated 236 9.0 - 49

Dicamba H Water, Finished 117 266 - 270 400,000 Water, Untreated 118 266 - 270

Dichlobenil H Water, Finished 235 6.5 - 45 Water, Untreated 236 4 1.7 11.2 - 25 6.5 - 45 Dichlorprop H Water, Finished 248 1.7 - 1.8 Water, Untreated 249 1 0.4 7.5 ^ 1.7 - 1.8 Dichlorvos (DDVP) I Water, Finished 230 11.3 - 22.5 Water, Untreated 231 11.3 - 22.5

Appendix G. Page 5 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Dicloran F Water, Finished 117 7.5 ^ Water, Untreated 118 7.5 ^ Dicofol p,p' I Water, Finished 235 5.0 - 11.3 Water, Untreated 236 5.0 - 11.3 Dicrotophos I Water, Finished 118 132 ^ Water, Untreated 118 132 ^

Dieldrin I Water, Finished 235 5.0 - 25 Water, Untreated 236 5.0 - 25 240

Difenoconazole F Water, Finished 133 12 ^ Water, Untreated 133 12 ^

Dimethenamid H Water, Finished 233 4 1.7 1.0 - 6.4 0.60 - 45 Water, Untreated 234 9 3.8 1.0 - 12 0.60 - 45

Dimethenamid ESA HM Water, Finished 118 45 ^ Water, Untreated 118 45 ^

Dimethenamid oxanilic acid (OA) HM Water, Finished 251 22 8.8 1.0 - 3.0 0.63 - 45 Water, Untreated 251 54 21.5 1.0 - 48 0.63 - 45

Dimethenamid/Dimethenamid P H Water, Finished 133 7 5.3 4.2 - 58 2.5 ^ Water, Untreated 133 22 16.5 4.2 - 160 2.5 ^

Dimethoate I Water, Finished 368 5.3 - 52 Water, Untreated 369 5.3 - 52

Dinoseb H Water, Finished 248 0.60 - 0.78 7,000 7,000 Water, Untreated 249 0.60 - 0.78 Diphenamid H Water, Finished 117 24 ^ 200,000 Water, Untreated 118 24 ^

Disulfoton I Water, Finished 368 6.0 - 8.8 700 Water, Untreated 369 6.0 - 8.8

Disulfoton sulfone IM Water, Finished 250 3.8 - 12.5 Water, Untreated 251 3.8 - 12.5

Appendix G. Page 6 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Diuron H Water, Finished 248 27 10.9 5.8 - 16 3.5 - 9.6 Water, Untreated 249 49 19.7 5.8 - 183 3.5 - 9.6

Endosulfan I I Water, Finished 235 5.0 - 50 Water, Untreated 236 5.0 - 50 220

Endosulfan II IM Water, Finished 235 12 - 50 Water, Untreated 236 12 - 50 220

Endosulfan sulfate IM Water, Finished 112 30 - 46.8 Water, Untreated 113 30 - 46.8

Endrin I Water, Finished 235 22 - 52.5 2,000 2,000 Water, Untreated 236 22 - 52.5 86 Epoxiconazole F Water, Finished 133 13 ^ Water, Untreated 133 13 ^

EPTC H Water, Finished 368 2.5 - 117.8 Water, Untreated 369 1 0.3 8.0 ^ 2.5 - 117.8

Esfenvalerate I Water, Finished 118 50 ^ Water, Untreated 118 50 ^

Esfenvalerate+Fenvalerate Total I Water, Finished 133 19 ^ Water, Untreated 133 19 ^

Ethalfluralin H Water, Finished 230 50 - 100 Water, Untreated 231 50 - 100

Ethion I Water, Finished 368 2.3 - 25 Water, Untreated 369 2.3 - 25

Ethion di oxon IM Water, Finished 118 35 ^ Water, Untreated 118 35 ^

Ethion mono oxon IM Water, Finished 235 3.8 - 51 Water, Untreated 236 3.8 - 51
Ethoprop I Water, Finished 368 4.5 - 6.0 Water, Untreated 369 4.5 - 6.0 Fenamiphos I Water, Finished 235 7.5 - 26 700 Water, Untreated 236 7.5 - 26

Appendix G. Page 7 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### Fenamiphos sulfone IM Water, Finished 118 193 ^ Water, Untreated 118 193 ^

Fenarimol F Water, Finished 117 37.5 ^ Water, Untreated 118 37.5 ^

Fenbuconazole F Water, Finished 223 3.0 - 4.8 Water, Untreated 224 3.0 - 4.8

Fenitrothion I Water, Finished 363 6.0 - 52 Water, Untreated 364 6.0 - 52 Fenpropathrin I Water, Finished 250 14 - 60 Water, Untreated 251 14 - 60

Fenthion I Water, Finished 368 6.0 - 22 Water, Untreated 369 6.0 - 22 Fenthion-O analog IM Water, Finished 230 7.5 - 99 Water, Untreated 231 7.5 - 99

Fenuron H Water, Finished 232 15 - 27 Water, Untreated 234 15 - 27 Fipronil I Water, Finished 80 12 ^ Water, Untreated 81 12 ^

Fludioxonil F Water, Finished 117 37.5 ^ Water, Untreated 118 37.5 ^

Flufenacet H Water, Finished 118 45 ^ Water, Untreated 118 45 ^

Flufenacet ESA HM Water, Finished 118 45 ^ Water, Untreated 118 45 ^

Flufenacet OA HM Water, Finished 133 0.75 ^ Water, Untreated 133 0.75 ^

Flumetsulam H Water, Finished 365 6.0 - 129 Water, Untreated 367 6.0 - 129

Fluometuron H Water, Finished 248 24 9.7 2.0 - 19 1.2 - 4.2 90,000 Water, Untreated 249 24 9.6 2.0 - 7.0 1.2 - 4.2

Appendix G. Page 8 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Fluvalinate I Water, Finished 133 130 ^ Water, Untreated 133 130 ^

Fonofos I Water, Finished 117 7.5 ^ 10,000 Water, Untreated 118 7.5 ^ Halosulfuron methyl H Water, Finished 133 3.3 ^ Water, Untreated 133 3.3 ^
Heptachlor I Water, Finished 118 5.0 - 50 400 Water, Untreated 118 5.0 - 50 520 Heptachlor epoxide IM Water, Finished 235 5.0 - 25 200 Water, Untreated 236 5.0 - 25 520 Hexachlorobenzene (HCB) FM Water, Finished 118 10 ^ 1,000 Water, Untreated 118 10 ^

Hexaconazole F Water, Finished 133 20 ^ Water, Untreated 133 20 ^ Hydroxy Atrazine HM Water, Finished 133 92 69.2 2.0 - 38 1.2 ^ Water, Untreated 133 91 68.4 2.0 - 100 1.2 ^ 3-Hydroxycarbofuran IM Water, Finished 232 24 - 46 Water, Untreated 234 24 - 46

Imazamethabenz acid H Water, Finished 133 14 10.5 1.0 - 8.4 0.60 ^ Water, Untreated 133 15 11.3 1.0 - 7.9 0.60 ^ Imazamethabenz methyl H Water, Finished 365 4 1.1 0.52 - 4.0 0.31 - 4.2 Water, Untreated 367 5 1.4 0.52 - 4.8 0.31 - 4.2

Imazamox H Water, Finished 248 2.4 - 3.1 Water, Untreated 249 2.4 - 3.1 Imazapic H Water, Finished 248 0.90 - 2.4 Water, Untreated 249 1 0.4 1.5 ^ 0.90 - 2.4 Imazapyr H Water, Finished 248 88 35.5 1.5 - 15 0.90 - 1.0 Water, Untreated 249 80 32.1 1.5 - 21 0.90 - 1.0 Imazaquin H Water, Finished 365 1.1 - 9.3 Water, Untreated 367 1.1 - 9.3

Appendix G. Page 9 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### Imazethapyr H Water, Finished 365 17 4.7 2.0 - 4.0 1.0 - 7.9 Water, Untreated 367 24 6.5 2.0 - 8.3 1.0 - 7.9 Imidacloprid I Water, Finished 365 15 4.1 2.5 - 5.5 1.5 - 42 Water, Untreated 367 19 5.2 2.5 - 202 1.5 - 42 Isofenphos I Water, Finished 235 4.5 - 9.5 Water, Untreated 236 4.5 - 9.5 Isofenphos oxygen analog IM Water, Finished 118 52 ^ Water, Untreated 118 52 ^ Lindane (BHC gamma) I Water, Finished 363 10 - 20 200 Water, Untreated 364 10 - 20 950

Linuron H Water, Finished 365 3.0 - 189 Water, Untreated 367 3.0 - 189

Malathion I Water, Finished 363 6.0 - 21 100,000 Water, Untreated 364 6.0 - 21 Malathion oxygen analog IM Water, Finished 117 6.0 ^ Water, Untreated 118 6.0 ^

MCPA H Water, Finished 365 7 1.9 1.3 - 12 0.78 - 91 30,000 Water, Untreated 367 12 3.3 1.3 - 188 0.78 - 91

MCPB H Water, Finished 365 6.6 - 228 Water, Untreated 367 6.6 - 228 Mecoprop (MCPP) H Water, Finished 117 52 ^ Water, Untreated 118 52 ^ Metalaxyl F Water, Finished 368 3.0 - 25 Water, Untreated 369 3.0 - 25

Methidathion I Water, Finished 230 5.3 - 31 Water, Untreated 231 5.3 - 31 Methidathion oxygen analog IM Water, Finished 230 22.5 - 915 Water, Untreated 231 22.5 - 915

Methiocarb I Water, Finished 227 15 - 22 Water, Untreated 229 15 - 22

Appendix G. Page 10 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### Methomyl I Water, Finished 365 3.6 - 75 200,000 Water, Untreated 367 3.6 - 75 Methoxychlor olefin IM Water, Finished 117 3.8 ^ 40,000 40,000 Water, Untreated 118 3.8 ^ Methoxychlor Total I Water, Finished 235 7.5 - 40 40,000 40,000 Water, Untreated 236 7.5 - 40

Metolachlor H Water, Finished 363 113 31.1 2.5 - 463 1.5 - 45 700,000 Water, Untreated 364 136 37.4 2.5 - 522 1.5 - 45

Metolachlor ethanesulfonic acid (ESA) HM Water, Finished 368 231 62.8 0.60 - 2167 0.36 - 45 Water, Untreated 369 246 66.1 0.60 - 3236 0.36 - 45 Metolachlor oxanilic acid (OA) HM Water, Finished 368 136 37.0 5.3 - 547 3.2 - 45 Water, Untreated 369 143 38.4 5.3 - 456 3.2 - 45

Metribuzin H Water, Finished 235 35 - 45 70,000 Water, Untreated 236 35 - 45 Metsulfuron methyl H Water, Finished 228 1.5 - 28 Water, Untreated 229 1.5 - 28 Mevinphos Total I Water, Finished 230 6.0 - 15 Water, Untreated 231 6.0 - 15

Molinate H Water, Finished 235 9.8 - 12 Water, Untreated 236 9.8 - 12

Monuron H Water, Finished 232 6.0 - 54 Water, Untreated 234 6.0 - 54 Myclobutanil F Water, Finished 366 5.0 - 50 Water, Untreated 367 5.0 - 50 Napropamide H Water, Finished 235 24 - 25 Water, Untreated 236 24 - 25

Neburon H Water, Finished 365 1.2 - 75 Water, Untreated 367 1.2 - 75

Appendix G. Page 11 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Nicosulfuron H Water, Finished 228 7 3.1 2.8 - 9.5 1.7 - 4.8 Water, Untreated 229 27 11.8 2.8 - 80 1.7 - 4.8

Norflurazon H Water, Finished 234 2 0.9 79 - 87 18.8 - 31 Water, Untreated 236 4 1.7 31.3 - 132 18.8 - 31 Norflurazon desmethyl HM Water, Finished 234 37.5 - 72 Water, Untreated 236 37.5 - 72

Omethoate IM Water, Finished 97 0.30 ^ Water, Untreated 97 0.30 ^

Oxadiazon H Water, Finished 235 15 ^ Water, Untreated 236 15 ^ Oxadixyl F Water, Finished 117 48.8 ^ Water, Untreated 118 48.8 ^ Oxamyl I Water, Finished 168 15 - 20 200,000 Water, Untreated 172 15 - 20 Oxychlordane IM Water, Finished 117 7.5 ^ Water, Untreated 118 7.5 ^ Oxydemeton methyl I Water, Finished 118 255 ^ Water, Untreated 118 255 ^ Oxyfluorfen H Water, Finished 235 11.3 - 75 Water, Untreated 236 11.3 - 75 Parathion ethyl I Water, Finished 250 7.5 - 15 Water, Untreated 251 7.5 - 15 Parathion methyl I Water, Finished 245 4.5 - 53 Water, Untreated 246 4.5 - 53 Parathion methyl oxygen analog IM Water, Finished 363 9.8 - 195 Water, Untreated 364 9.8 - 195 Parathion oxygen analog IM Water, Finished 230 7.5 - 104 Water, Untreated 231 7.5 - 104

Pebulate H Water, Finished 235 2.3 - 25 Water, Untreated 236 2.3 - 25

Appendix G. Page 12 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Pendimethalin H Water, Finished 235 4.5 - 25 Water, Untreated 236 4.5 - 25

Permethrin cis IM Water, Finished 251 4.5 - 8.0 Water, Untreated 251 4.5 - 8.0

Permethrin trans I Water, Finished 133 7.5 ^ Water, Untreated 133 7.5 ^

Phenothrin I Water, Finished 133 1 0.8 45 ^ 27 ^ Water, Untreated 133 27 ^

Phenthoate I Water, Finished 112 15 ^ Water, Untreated 113 15 ^

Phorate I Water, Finished 368 5.2 - 12 Water, Untreated 369 5.2 - 12 Phorate oxygen analog IM Water, Finished 235 5.3 - 10 Water, Untreated 236 5.3 - 10

Phorate sulfone IM Water, Finished 235 6.0 - 16 Water, Untreated 236 6.0 - 16

Phorate sulfoxide IM Water, Finished 235 37.5 - 199 Water, Untreated 236 37.5 - 199

Phosalone I Water, Finished 235 4.5 - 52 Water, Untreated 236 4.5 - 52 Phosalone oxygen analog IM Water, Finished 118 631 ^ Water, Untreated 118 631 ^

Phosmet I Water, Finished 118 227 ^ Water, Untreated 118 227 ^ Phosphamidon I Water, Finished 235 12 - 297 Water, Untreated 236 12 - 297

Picloram H Water, Finished 365 1 0.3 37 ^ 22 - 447 500,000 Water, Untreated 367 1 0.3 37 ^ 22 - 447 Piperonyl butoxide I Water, Finished 117 18.8 ^ Water, Untreated 118 18.8 ^

Appendix G. Page 13 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Pirimicarb I Water, Finished 117 37.5 ^ Water, Untreated 118 37.5 ^ Pirimiphos methyl I Water, Finished 235 5.3 - 8.8 Water, Untreated 236 5.3 - 8.8

Prallethrin I Water, Finished 180 25 ^ Water, Untreated 180 25 ^

Profenofos I Water, Finished 235 3.8 - 30 Water, Untreated 236 3.8 - 30

Prometon H Water, Finished 368 190 51.6 0.28 - 16 0.17 - 50 100,000 Water, Untreated 369 217 58.3 0.28 - 19 0.17 - 50 Prometryn H Water, Finished 368 1 0.3 25 ^ 0.17 - 24 Water, Untreated 369 5 1.3 25 ^ 0.17 - 24

Pronamide H Water, Finished 235 5.0 - 22.5 Water, Untreated 236 5.0 - 22.5
Propachlor H Water, Finished 363 0.64 - 16 Water, Untreated 364 0.64 - 16
Propachlor OA HM Water, Finished 133 1.4 ^ Water, Untreated 133 1.4 ^ Propanil H Water, Finished 250 6.7 - 24.8 Water, Untreated 251 6.7 - 24.8 Propargite I Water, Finished 235 60 - 180 Water, Untreated 236 60 - 180 Propazine H Water, Finished 225 3.3 - 4.5 Water, Untreated 226 6 2.7 5.5 - 7.5 3.3 - 4.5
Propetamphos I Water, Finished 235 6.0 - 8.4 Water, Untreated 236 6.0 - 8.4
Propham H Water, Finished 115 18 ^ 100,000 Water, Untreated 116 18 ^ Propiconazole F Water, Finished 365 6.0 - 55 Water, Untreated 367 6.0 - 55

Appendix G. Page 14 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1


### Propoxur I Water, Finished 117 24.8 ^ Water, Untreated 118 24.8 ^ Quintozene (PCNB) F Water, Finished 112 11.3 ^ Water, Untreated 113 11.3 ^

Resmethrin I Water, Finished 180 7.8 - 50 Water, Untreated 180 7.8 - 50 S-(2-hydroxy)propyl EPTC HM Water, Finished 71 125 ^ Water, Untreated 71 125 ^

Siduron H Water, Finished 248 2.1 - 2.4 Water, Untreated 249 2 0.8 4.0 ^ 2.1 - 2.4

Simazine H Water, Finished 368 128 34.8 1.2 - 284 0.71 - 50 4,000 Water, Untreated 369 139 37.4 1.2 - 590 0.71 - 50 Sulfometuron methyl H Water, Finished 340 1.9 - 15 Water, Untreated 342 1 0.3 3.2 ^ 1.9 - 15 Sulfotep I Water, Finished 235 2.4 - 4.5 Water, Untreated 236 2.4 - 4.5 Sulprofos I Water, Finished 235 6.0 - 11 Water, Untreated 236 6.0 - 11 Sulprofos oxygen analog IM Water, Finished 118 37 ^ Water, Untreated 118 37 ^

Tebuconazole F Water, Finished 365 2 0.5 10.3 ^ 4.8 - 62 Water, Untreated 367 4 1.1 8.0 - 10.3 4.8 - 62 Tebupirimfos I Water, Finished 235 7.5 - 12 Water, Untreated 236 7.5 - 12 Tebupirimfos oxygen analog IM Water, Finished 235 9.0 - 13 Water, Untreated 236 9.0 - 13

Tebuthiuron H Water, Finished 365 148 40.5 0.35 - 7.6 0.21 - 10 500,000 Water, Untreated 367 182 49.6 0.35 - 7.3 0.21 - 10

Tecnazene P Water, Finished 112 18.8 ^ Water, Untreated 113 18.8 ^

Appendix G. Page 15 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Tefluthrin I Water, Finished 251 2.1 - 5.0 Water, Untreated 251 2.1 - 5.0

Terbacil H Water, Finished 117 22.5 ^ 90,000 Water, Untreated 118 22.5 ^

Terbufos I Water, Finished 251 5.2 - 6.3 400 Water, Untreated 251 5.2 - 6.3

Terbufos sulfone IM Water, Finished 235 4.5 - 7.7 Water, Untreated 236 4.5 - 7.7 Terbufos-O analog IM Water, Finished 235 6.0 - 13 Water, Untreated 236 6.0 - 13 Tetrachlorvinphos I Water, Finished 363 6.0 - 63 Water, Untreated 364 6.0 - 63

Tetraconazole F Water, Finished 223 9 4.0 6.2 - 57 1.8 - 3.7 Water, Untreated 224 9 4.0 6.2 - 30 1.8 - 3.7

Tetradifon I Water, Finished 297 7.2 - 75 Water, Untreated 298 7.2 - 75

Tetramethrin I Water, Finished 180 28 - 75 Water, Untreated 180 28 - 75

Thifensulfuron H Water, Finished 133 8.9 ^ Water, Untreated 133 8.9 ^

Thiobencarb H Water, Finished 248 7.7 - 24.8 Water, Untreated 249 7.7 - 24.8 Tolclofos methyl F Water, Finished 118 5.0 - 8.0 Water, Untreated 118 5.0 - 8.0

Tralomethrin I Water, Finished 118 300 ^ Water, Untreated 118 300 ^

Tri Allate H Water, Finished 368 10.5 - 24.8 Water, Untreated 369 10.5 - 24.8

Triadimefon F Water, Finished 366 3.4 - 50 Water, Untreated 367 3.4 - 50

Appendix G. Page 16 of 17Pesticide / Commodity Pest. Type Number of Samples Samples with Detects % of Samples

with Detects Range of Values Detected, ppt Range of LODs, ppt EPA MCL, ppt 1 EPA HA 2

, ppt 1 EPA FAO 3

, ppt 1



### Triadimenol F Water, Finished 133 39 ^ Water, Untreated 133 39 ^

Triasulfuron H Water, Finished 133 3.1 ^ Water, Untreated 133 3.1 ^ Triazole acetic acid (TAA) FM Water, Finished 122 30 ^ Water, Untreated 109 30 ^ Triazole alanine (TA) FM Water, Finished 112 13 ^ Water, Untreated 124 13 ^ Triclopyr H Water, Finished 365 41 11.2 2.7 - 26 1.6 - 43 Water, Untreated 367 48 13.1 2.7 - 47 1.6 - 43

Trifluralin H Water, Finished 235 1.5 - 75 10,000 Water, Untreated 236 1.5 - 75

Triticonazole F Water, Finished 133 28 ^ Water, Untreated 133 28 ^

Vinclozolin F Water, Finished 191 5.0 - 35 Water, Untreated 191 5.0 - 35

NOTES

1 = EPA MCL, HA, and FAO values have been multiplied by a factor of 1,000,000 as a basis for comparison using a single scale. There is no intention to imply any more exactness in the value than that originally expressed by EPA.

2 = EPA Health Advisory values shown are for lifetime exposure.

3 = The FAO value applies to ambient water rather than drinking water.

4 = The MCL for chlordane is inclusive of the isomers.

^ = Only one distinct detected concentration or LOD value was reported for the pair.

Pesticide Types: F = Fungicide, FM = Fungicide Metabolite H = Herbicide, HM = Herbicide Metabolite I = Insecticide, IM = Insecticide Metabolite P = Plant Growth Regulator

Appendix G. Page 17 of 17

# Appendix H

Sample Origin by State or Country (Determined by Grower, Packer, or Distributor)

Appendix H gives the number of fruit and vegetables, peanut butter, and bottled water samples per State or country of or igin and the number of samples of unknown origin. Where available, the origin of fres h commodities is taken from the grower or packer information. For proc essed commodities, origin is determined primarily by packer or distributor.
As shown in Appendix H, fruit and v egetable, peanut butter, and bottled water samples originated from 41 States and 27 fore ign countries. There were 404 domestic and 39 imported samples from unknown States and countries, respectively. There were an additional 67 samples from unknown countries of origin. Poultry and wheat samples were all of domestic origin. Overall, for all samples except drinking water, 80 percent were from U.S. sour ces, 18 percent were imports , 1 percent were of mixed origin, and approximately 1 perc ent were of unknown origin.

### Part 1. Domestic Samples

Nuts H 2 O # of % of States = 41 BN BR CA CF CR EP GF GK GL PC PU SP SS WM WS AC OJ PD PS PZ RA PB WB Samp. Total

Alabama 1 1 <0.1

Alaska 1 1 <0.1
Arizona 2 7 10 8 1 2 2 3 4 3 20 4 1 67 0.6
Arkansas 1 1 3 12 2 5 19 7 2 14 4 70 0.6
California 139 38 493 497 127 345 39 18 39 283 317 11 83 27 61 39 139 87 72 227 117 71 3269 29.9
Colorado 14 2 4 12 1 2 1 3 39 0.4
Connecticut 1 133 1 56 191 1.7
Florida 4 2 5 8 83 225 1 2 2 3 12 25 52 13 19 177 8 37 36 8 15 8 745 6.8 Georgia 21 70 8 21 1 19 7 8 10 16 2 3 17 20 223 2.0
Hawaii 2 2 <0.1
Idaho 5 3 2 51 26 8 72 81 17 28 2 295 2.7
Illinois 1 3 1 1 1 34 5 3 28 22 8 29 3 139 1.3
Indiana 2 2 4 <0.1 Kentucky 1 1 1 2 2 7 0.1
Maine 4 1 1 2 7 5 4 4 1 29 0.3 Maryland 4 1 3 1 1 8 5 3 23 4 1 13 24 2 10 3 106 1.0
Massachusetts 239 1 2 2 1 1 5 251 2.3 Michigan 3 1 42 27 28 3 1 36 3 13 45 29 6 31 5 273 2.5
Minnesota 4 1 4 2 2 2 3 1 1 10 6 2 36 13 5 11 4 107 1.0
Missouri 4 2 3 3 12 0.1
Montana 1 1 2 <0.1
Nebraska 33 33 0.3 New Hampshire 3 3 <0.1 New Jersey 3 16 6 2 4 8 3 6 2 3 11 3 3 109 179 1.6
New Mexico 1 1 2 <0.1
New York 4 2 11 1 1 1 2 1 3 6 32 3 6 108 27 4 22 27 261 2.4
North Carolina 4 1 2 2 1 2 1 13 0.1
North Dakota 8 8 0.1
Ohio 3 5 9 3 3 1 2 1 2 37 16 7 32 25 14 183 21 364 3.3
Oklahoma 5 5 <0.1 Oregon 19 1 7 31 32 7 4 5 106 1.0 Pennsylvania 29 1 91 16 137 2 17 18 311 2.8
Rhode Island 1 1 <0.1
South Carolina 1 7 1 1 1 2 13 0.1
Tennessee 1 4 4 9 0.1
Texas 10 1 12 11 18 120 8 4 1 7 15 8 69 3 55 33 3 59 46 17 12 14 526 4.8
Vermont 4 4 <0.1 Virginia 1 2 1 15 1 2 1 23 0.2 Washington 7 7 1 1 2 14 2 7 1 69 4 8 46 2 8 179 1.6 West Virginia 1 1 <0.1
Wisconsin 1 1 2 2 1 3 2 16 4 2 8 2 44 0.4
Unknown State 2 6 15 12 72 23 12 16 3 14 29 8 55 17 4 10 4 9 13 38 20 22 404 3.7
No. of Domestics 0 175 298 539 638 455 729 84 85 66 319 481 91 288 103 721 360 216 647 638 368 705 316 8,322

% of Total 0 95 94 97 86 61 98 86 99 73 62 94 49 52 28 97 65 96 87 86 99 95 86 76.2
Number and Percentage computed with 1,310 Poultry samples and 687 Wheat samples of domestic origin added: 10,319 79.9 

## APPENDIX H. SAMPLE ORIGIN BY STATE OR COUNTRY 1 

## (Determined by Grower, Packer, or Distributor)

Fresh F&V Processed F&V



### Appendix H. Page 1 of 3

### Part 2. Imported Samples

Nuts H 2 O # of % of Countries = 26 BN BR CA CF CR EP GF GK GL PC PU SP SS WM WS AC OJ PD PS PZ RA PB WB Samp. Total Argentina 2 1 2 5 <0.1
Bahamas 5 5 <0.1
Belize 1 1 <0.1
Brazil 12 12 0.1 Canada 1 18 7 77 4 5 1 2 22 76 97 26 6 342 3.1 Chile 24 192 1 1 218 2.0 Colombia 59 59 0.5 Costa Rica 193 9 202 1.8 Croatia 1 1 <0.1 Dominican Repub. 2 2 <0.1
Ecuador 217 217 2.0 Fiji 12 12 0.1
France 1 23 24 0.2 Grenada 1 1 <0.1 Guatemala 158 23 1 1 183 1.7
Honduras 65 12 1 26 14 118 1.1
Iceland 4 4 <0.1
Israel 1 1 <0.1 Italy 2 2 <0.1
Mexico 12 5 11 23 260 7 13 1 23 88 183 237 2 1 1 867 7.9
Netherlands 3 3 <0.1
New Zealand 6 6 0.1 Nicaragua 1 5 9 15 0.1
Panama 2 2 4 <0.1
Peru 1 1 <0.1
Poland 5 5 <0.1 Unknown Country 34 1 1 3 39 0.4 No. of Imports 742 6 18 18 101 276 13 14 1 24 194 28 89 252 264 22 15 2 92 100 3 27 48 2349

% of Total 100 3 6 3 14 37 2 14 1 27 38 5 48 46 72 3 3 1 12 13 1 4 13 21.5 Percentage computed with 1,310 Poultry samples and 687 Wheat samples of domestic origin added: 18.2



### Part 3. Mixed National Origin Samples

Nuts H 2 O # of % of AC OJ PD PS PZ RA PB WB Samp. Total Argentina / Chile / France / USA 1 1 <0.1 Argentina / Chile / USA 1 1 <0.1 Argentina / Australia / Chile / France / USA 3 3 <0.1
Belize / Brazil / Mexico / USA 2 2 <0.1
Belize / Brazile / USA 1 1 <0.1
Belize / Mexico / USA 1 1 <0.1
Belize / USA 1 1 <0.1
Brazil / Costa Rica 4 4 <0.1
Brazil / Costa Rica / Mexico 1 1 <0.1
Brazil / Costa Rica / Mexico / USA 5 5 <0.1
Brazil / Costa Rica / USA 19 19 0.2
Brazil / Mexico 5 5 <0.1
Brazil / Mexico / USA 57 57 0.5
Brazil / USA 79 79 0.7
Canada / USA 3 3 <0.1

Mexico / USA 3 3 <0.1 No. of Mixed National Origin Samples 178 5 3 186

% of Total 32 2 1 1.7 Processed F&V

Processed F&V Fresh F&V



### Appendix H. Page 2 of 3

### Part 4. Unknown Origin Samples

Nuts H 2 O # of % of
BN BR CA CF CR EP GF GK GL PC PU SP SS WM WS AC OJ PD PS PZ RA PB WB Samp. Total

Unknown Origin 4 1 5 9 1 2 2 6 10 2 1 4 1 5 6 1 7 67
% of Total 2 <1 1 1 <1 <1 <1 3 2 1 <1 1 <1 1 1 <1 1 0.6

Sample TOTALS 742 185 316 558 744 740 743 98 86 90 515 511 186 550 369 744 557 224 744 744 372 739 367 10,924 Grand Total computed with with 1,310 Poultry samples and 687 Wheat samples added: 12,921



### NOTE

1 Excludes wheat, poultry, and treated/untreated drinking water samples.

Commodity Legend AC = Applesauce GK = Greens, Kale PZ = Potatoes, Frozen BN = Bananas GL = Greens, Collard RA = Raisins BR = Broccoli OJ = Orange Juice SP = Spinach CA = Cranberries PB = Peanut Butter SS = Summer Squash
CF = Cauliflower PC = Peaches WB = Bottled Water CR = Carrots PD = Plums, Dried (Prunes) WM = Watermelon EP = Eggplant PS = Sweet Peas, Frozen WS = Winter Squash GF = Grapefruit PU = Plums, Fresh Fresh F&V Processed F&V



### Appendix H. Page 3 of 3

# Appendix I

Import vs. Domestic Pesticide Residue Comparisons

PDP is designed to provide a comprehensi ve statistical picture of pesticide residues in the U.S. food s upply, representing all source s, including imports. Most commodities consumed are generally produc ed in the United St ates with import components that vary by commodity. Howeve r, several commodities tested over the past several years were cyclical; that is, par t of the year the commodity was produced domestically and part of the y ear it was imported.
Appendix I compares residue data reported for samples or iginating in the United States with those of the same commodity from major exporting countries. Residue data for domestic winter squash are compar ed with data for sample s originating in Mexico for 2005 and 2006. Residue data for fr esh plums from the United States are compared with data for samples originating in Chile for 2005 and 2006. Only residues detected in more than 10 percent of all sa mples are included in each comparison. All pesticides detected were regi stered in the United States. However, the profiles of residue findings were markedly different in the United States samples versus samples from these exporting countries. The diffe rences in residue detections between countries were due likely to the pesticides used in response to pest pressures based on differing environmental, climat ic, and growing conditions.

### Origin Year # of Samples Analyzed # of Samples w/ Detections % of Samples w/ Detections # of Residues Detected

United States 2005 408 177 43.4 250 2006 103 52 50.5 80 2005-2006 511 229 44.8 330

Mexico 2005 258 98 38.0 147 2006 237 107 45.1 162 2005-2006 495 205 41.4 309

Pesticide Origin # of Samples Analyzed # of Samples w/ Detections % of Samples w/ Detections

Dieldrin United States 511 53 10.4 Mexico 495 1 0.2

Endosulfan sulfate United States 511 73 14.3 Mexico 495 130 26.3

NOTE: The Limits of Detection (LODs) for pesticide detections in winter squash are listed in Appendix B. 

# Originating in Mexico vs. United States (Only Pesticides with Residue Detections in at least 10 Percent of all Samples)



# Appendix I. Import vs. Domestic Pesticide Residue Comparisons

2005-2006 Distribution of Residues for Winter Squash United States Samples vs. Samples Originating in Mexico

2005-2006 Distribution of Residues for Winter Squash Samples

Appendix I. Page 1 of 2

### Origin Year # of Samples Analyzed # of Samples w/ Detections % of Samples w/ Detections # of Residues Detected

United States 2005 340 197 57.9 273 2006 319 167 52.4 233 2005-2006 659 364 55.2 506

Chile 2005 227 224 98.7 372 2006 192 189 98.4 363 2005-2006 419 413 98.6 735

Pesticide Origin # of Samples Analyzed # of Samples w/ Detections % of Samples w/ Detections
Chlorpyrifos United States 659 20 3.0 Chile 419 110 26.3

Fludioxonil United States 659 214 32.5 Chile 419 0 0

Iprodione United States 659 14 2.1 Chile 419 397 94.7

Phosmet United States 659 185 28.1 Chile 419 5 1.2

NOTE: The Limits of Detection (LODs) for pesticide detections in plums are listed in Appendix B. 

# 2005-2006 Distribution of Residues for Fresh Plum Samples Originating in Chile vs. United States (Only Pesticides with Residue Detections in at least 10 Percent of all Samples) 

# 2005-2006 Distribution of Residues for Fresh Plums United States Samples vs. Samples Originating in Chile

Appendix I. Page 2 of 2

# Appendix J

National Estimates for Concentration Percentiles vs. Tolerance (Pairs With Residue Detections in at Least 10 Percent of Samples)

Appendix J shows 51 pesticide/commodity pai rs (including metabolites, isomers, and degradates) with detections in at leas t 10 percent of the samples tested. Concentrations detected are arranged in percent iles. The 90th percentile is compared to the Environmental Protection Agency to lerance established for each pesticide/ commodity pair.
The meaning of a percentile can be most ea sily explained through an example. For the bananas/thiabendazole pair, the 50th perc entile, or median, is estimated to be 0.014 ppm. This means that PDP estimate s that at least 50 percent of bananas available to U.S. consumer s had thiabendazole residues of 0.014 ppm or less, while at least 50 percent had residues of 0.014 ppm or more. Similarl y, the 75th percentile (or the upper quartile) for this pair is estimated to be 0.036 ppm, which means that at least 75 percent of bananas had thiabendazole residues of 0.036 ppm or less, while at least 25 percent had residues of 0.036 ppm or mo re. Finally, the 90th percentile is estimated to be 0.066 ppm, meaning that at least 90 percent of all bananas had thiabendazole residues of 0.066 ppm or less, while at least 10 percent had residues of 0.066 ppm or more.
Percent detections and percentiles fo r bananas, carrots, cauliflower, cranberries, eggplant, orange juice, plums, spi nach, and winter squash were weighted based on marketing data.

### APPENDIX J. NATIONAL ESTIMATES FOR CONCENTRATION PERCENTILES vs. TOLERANC E (Pairs With Residue Detections in at Least 10 Percent of Samples 1 

### )

% of Ratio of Samples with Mean (ppm) 2 

### Percentiles (ppm) 90th Percentile Commodity / Pesticide Detections Lower Upper 50th 75th 90th to Tolerance 1 Applesauce Acetamiprid 51.5 0.003 0.003 0.001 0.003 0.007 0.007 Carbaryl 22.2 0.002 0.003 * * 0.002 < 0.001 Carbendazim (MBC) 82.6 0.008 0.009 0.008 0.012 0.018 0.003 Diphenylamine 30.2 0.010 0.013 * 0.007 0.033 0.003 Imidacloprid 17.5 < 0.001 0.003 * * < 0.001 0.001 Tetrahydrophthalimide (THPI) 21.8 0.011 0.032 * * 0.049 0.002 Thiabendazole 38.8 0.037 0.038 * 0.006 0.13 0.013 Thiacloprid 12.8 <0.001 0.001 * * 0.001 0.003

2 Bananas (W) Imazalil 31.0 0.006 0.012 * 0.010 0.019 0.006 Thiabendazole 65.6 0.026 0.030 0.014 0.036 0.066 0.022

3 Carrots (W) Azoxystrobin 15.7 0.001 0.001 * * 0.002 0.005 DDE p,p' 27.1 0.003 0.005 * 0.003 0.011 0.004 Iprodione 13.1 0.007 0.033 * * 0.038 0.008 Linuron 78.3 0.025 0.025 0.012 0.035 0.058 0.058 Pyraclostrobin 37.5 0.002 0.003 * 0.002 0.007 0.018 Trifluralin 57.4 0.021 0.025 0.003 0.034 0.066 0.066

4 Cauliflower (W) Imidacloprid 76.4 0.002 0.002 0.001 0.003 0.007 0.002

5 Cranberries (W) (October - December only) Azoxystrobin 31.4 0.001 0.001 * 0.001 0.004 0.008 Chlorpyrifos 22.4 0.006 0.010 * * 0.026 0.026 Methoxyfenozide 14.4 0.002 0.007 * * 0.009 0.018

6 Eggplant (W) Endosulfan II 13.8 0.002 0.006 * * 0.008 0.008 Endosulfan sulfate 17.3 0.004 0.009 * * 0.015 0.015

7 Grapefruit Imazalil 38.4 0.022 0.046 * 0.029 0.067 0.007

8 Orange Juice (W) (January - September only) Carbaryl 33.2 0.001 0.004 * 0.020 0.004 < 0.001 Imazalil 12.1 0.003 0.025 * * 0.005 0.001

9 Peanut Butter Piperonyl butoxide 27.1 0.012 0.026 * 0.023 0.049 0.006

Appendix J. Page 1 of 2

### % of Ratio of Samples with Mean (ppm) 2 

### Percentiles (ppm) 90th Percentile Commodity / Pesticide Detections Lower Upper 50th 75th 90th to Tolerance
10 Plums (W) Chlorpyrifos 8.9 0.001 0.004 * * * * Fludioxonil 27.8 0.107 0.19 * * 0.34 0.068 Iprodione 10.9 0.107 0.14 * * 0.098 0.005 Phosmet 23.9 0.004 0.006 * * 0.011 0.002

11 Potatoes, Frozen Chlorpropham 61.4 0.42 0.43 0.21 0.72 1.2 0.024 Imidacloprid 33.1 0.002 0.005 <0.001 0.003 0.007 0.018

12 Raisins (July - December only) Boscalid 35.8 0.017 0.034 * 0.015 0.055 0.006 Methoxyfenozide 75.0 0.023 0.023 0.007 0.034 0.063 0.042 Propargite 31.5 0.030 0.059 * 0.020 0.089 0.009 Pyraclostrobin 55.6 0.007 0.007 0.003 0.008 0.017 0.002 Trifloxystrobin 25.8 0.005 0.025 * 0.001 0.012 0.002

13 Spinach (W) (January - October only) Azoxystrobin 10.6 0.041 0.042 * * 0.001 < 0.001 Cypermethrin 14.7 0.056 0.17 * * 0.21 0.021 Cyromazine 19.0 0.031 0.033 * * 0.039 0.006 DDE p,p' 37.6 0.003 0.005 * * 0.010 0.020 Imidacloprid 71.7 0.020 0.021 0.003 0.017 0.051 0.015 Omethoate 13.1 0.014 0.017 * * 0.006 0.003 Permethrin cis 56.5 0.42 0.42 0.019 0.69 1.4 0.070 Permethrin trans 56.2 0.41 0.42 0.019 0.63 1.3 0.065 Pyraclostrobin 23.1 0.048 0.049 * * 0.068 0.002

14 Sweet Peas, Frozen Dimethoate 12.1 0.001 0.005 * * 0.005 0.002

15 Wheat Chlorpyrifos methyl 16.7 0.020 0.036 * * 0.048 0.008 Malathion 63.0 0.061 0.062 0.010 0.034 0.12 0.015

16 Winter Squash (W) (January - September only) Endosulfan sulfate 29.1 0.006 0.011 * 0.008 0.023 0.023 Thiamethoxam 21.6 0.001 0.002 * * 0.004 0.018

NOTES

1 Includes some pairs with detections in more than 10 percent of the samples, but with estimated detections in less than 10 percent of the population. Excludes pairs with less than 100 sample observations, with observations from less than three States, or with observations from less than six months of the year (except for fresh cranberries, which are available almost exclusively in the winter).

2 The mean is estimated with a range of values. The lower bound is calculated with non-detections valued at zero. The upper bound is calculated using the LOD.



### * The percentile value is estimated to be below the Limit of Detection (LOD)
(W) Weighted for utilization. The Percent of Samples with Detections was recalculated to reflect national estimates.

Appendix J. Page 2 of 2

# Appendix K

Cumulative Distributions of Residues for Selected Pesticide/ Commodity Pairs

In Appendix K, the concentrations detect ed (in parts per million, except where otherwise noted) are plotted versus the calculated percentiles for the following 12 pesticide/commodity pairs:
Acetamiprid / Applesauce Imazalil / Bananas Pyraclostrobin / Carrots Trifluralin / Carrots Imidacloprid / Cauliflower Azoxystrobin / Cranberries Fludioxonil / Plums Chlorpropham / Frozen Potatoes Imidacloprid / Frozen Potatoes Boscalid / Raisins Dimethoate / Frozen Sweet Peas Chlorpyrifos methyl / Wheat

The distribution of residues for all of the PDP pesticide/commodity pairs has the same curved shape. For each pesticide/co mmodity pair, the highest percentile graphed in the appendix (99 th 

## ) is lower than the highest concentration detected in the sample (refer to the va lue shown in each graph ’ s legend). Inclusion of the highest concentration would cause graph distortion, which would ob scure concentrations in the low ranges. The tolerance for the pesticide/c ommodity pair is also indicated in the legend of each graph. The large dots show the percenta ge of the commodity at or below a given level of residue concentration . For example, an estimated 50 percent of carrots available to U.S. consumers in 2006 had trifluralin residue concentrations of 0.003 ppm or less. The solid lines, tailing th e large dots, depict percentage values. The lowest value of these solid lines in dicates the estimated percentage of the commodity available to U.S. consumers with no detectable residues. For trifluralin in carrots, this is 43 percent. The shaded bar denotes the range of va lues estimated for the mean. In some cases, there is convergence of t he mean upper and lower bound into a single line due to the insignificant differences between them . For trifluralin in carrots, the mean range is approximately 0.021 – 0.025 ppm, corresponding to the 66th percentile.

### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024

LEGEND Tolerance is 1 ppm Highest Level Detected is 0.031 ppm

MEAN



### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024



### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024

LEGEND Tolerance is 1 ppm Highest Level Detected is 0.031 ppm

MEAN 

# Acetamiprid / Applesauce

PercentilesConcentration - (parts per million)

60 65 70 75 80 85 90 95 100 0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

LEGEND Tolerance is 3 ppm Highest Level Detected is 0.085 ppm

MEAN



### PercentilesConcentration - (parts per million)

60 65 70 75 80 85 90 95 100 0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07



### PercentilesConcentration - (parts per million)

60 65 70 75 80 85 90 95 100 0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

LEGEND Tolerance is 3 ppm Highest Level Detected is 0.085 ppm

MEAN 

# Imazalil / Bananas

Appendix K. Page 1 of 6 

# Appendix K. Cumulative Di stributions of Residues for Selected Pesticide/Commodity Pairs

### PercentilesConcentration - (parts per million)

40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

LEGEND Tolerance is 0.4 ppm Highest Level Detected is 0.045 ppm

MEAN



### PercentilesConcentration - (parts per million)

40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022



### PercentilesConcentration - (parts per million)

40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

LEGEND Tolerance is 0.4 ppm Highest Level Detected is 0.045 ppm

MEAN 

# Pyraclostrobin / Carrots

PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13

0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13

LEGEND Tolerance is 1 ppm Highest Level Detected is 0.19 ppm

MEAN



### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13

0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13



### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13

0.0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13

LEGEND Tolerance is 1 ppm Highest Level Detected is 0.19 ppm

MEAN 

# Trifluralin / Carrots

Appendix K. Page 2 of 6

### PercentilesConcentration - (parts per million)

10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016

LEGEND Tolerance is 3.5 ppm

MEAN



### PercentilesConcentration - (parts per million)

10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016



### PercentilesConcentration - (parts per million)

10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016

LEGEND Tolerance is 3.5 ppm

MEAN 

# Imidacloprid / Cauliflower

Highest Level Detected is 0.045 ppm



### Percentiles 50 55 60 65 70 75 80 85 90 95 100 0.0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012

0.0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012

LEGEND Tolerance is 0.5 ppm Highest Level Detected is 0.012 ppm

MEAN



### Percentiles 50 55 60 65 70 75 80 85 90 95 100 0.0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012

0.0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012



### Percentiles 50 55 60 65 70 75 80 85 90 95 100 0.0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012

0.0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012

LEGEND Tolerance is 0.5 ppm Highest Level Detected is 0.012 ppm

MEANConcentration – (parts per million) 

# Azoxystrobin / Cranberries

Appendix K. Page 3 of 6

### PercentilesConcentration - (parts per million)

60 65 70 75 80 85 90 95 100 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

LEGEND Tolerance is 5 ppm Highest Level Detected is 1.8 ppm

MEAN



### PercentilesConcentration - (parts per million)

60 65 70 75 80 85 90 95 100 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1



### PercentilesConcentration - (parts per million)

60 65 70 75 80 85 90 95 100 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

LEGEND Tolerance is 5 ppm Highest Level Detected is 1.8 ppm

MEAN 

# Fludioxonil / Plums

PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4

0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4

LEGEND Tolerance is 50 ppm Highest Level Detected is 3.5 ppm

MEAN



### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4

0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4



### PercentilesConcentration - (parts per million)

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4

0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4

LEGEND Tolerance is 50 ppm Highest Level Detected is 3.5 ppm

MEAN 

# Chlorpropham / Po tatoes (Frozen)

Appendix K. Page 4 of 6

### PercentilesConcentration - (parts per million)

50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

LEGEND Tolerance is 0.4 ppm Highest Level Detected is 0.032 ppm

MEAN



### PercentilesConcentration - (parts per million)

50 55 60 65 70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022

LEGEND Tolerance is 0.4 ppm Highest Level Detected is 0.032 ppm

MEAN 

# Imidacloprid / Potatoes (Frozen)

PercentilesConcentration - (parts per million)

50 55 60 65 70 75 80 85 90 95 100 0.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18

0.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18

LEGEND Tolerance is 8.5 ppm Highest Level Detected is 0.36 ppm

MEAN



### PercentilesConcentration - (parts per million)

50 55 60 65 70 75 80 85 90 95 100 0.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18

0.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18



### PercentilesConcentration - (parts per million)

50 55 60 65 70 75 80 85 90 95 100 0.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18

0.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18

LEGEND Tolerance is 8.5 ppm Highest Level Detected is 0.36 ppm

MEAN 

# Boscalid / Raisins

Appendix K. Page 5 of 6

### PercentilesConcentration - (parts per million)

70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024 0.026

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024 0.026

LEGEND Tolerance is 2 ppm Highest Level Detected is 0.064 ppm

MEAN



### PercentilesConcentration - (parts per million)

70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024 0.026

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024 0.026



### PercentilesConcentration - (parts per million)

70 75 80 85 90 95 100 0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024 0.026

0.0 0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.020 0.022 0.024 0.026

LEGEND Tolerance is 2 ppm Highest Level Detected is 0.064 ppm

MEAN 

# Dimethoate / Sweet Peas (Frozen)

PercentilesConcentration - (parts per BILLION)

80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 50 100 150 200 250 300 350 400 450

50 100 150 200 250 300 350 400 450
LEGEND Tolerance is 6000 ppb Highest Level Detected is 1081 ppb

MEAN



### PercentilesConcentration - (parts per BILLION)

80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 50 100 150 200 250 300 350 400 450

50 100 150 200 250 300 350 400 450



### PercentilesConcentration - (parts per BILLION)

80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 50 100 150 200 250 300 350 400 450

50 100 150 200 250 300 350 400 450
LEGEND Tolerance is 6000 ppb Highest Level Detected is 1081 ppb

MEAN 

# Chlorpyrifos methyl / Wheat

Appendix K. Page 6 of 6

# Appendix L

Number of Pesticides Detected per Sample

Appendix L shows the percentage of samp les versus the number of pesticides detected per sample, excluding drinking wa ter samples. The graph and data on page 1 show the overall number of samples and percentages (of total number of samples analyzed) for each detection group across al l commodities. The table on page 2 shows the number of pesticides detected by i ndividual commodity. For the 12,921 samples analyzed, 46.1 percent of th e samples had no detectable pesticides, 27.7 percent had 1 pesticide, and 26.2 percent of the sa mples had more than 1 pesticide.
This appendix reports t he number of distinct pesticides rather than residues, as was reported in summaries prior to 2003. A parent compound and its metabolites are reported as a single pesticide. For example, a single applicat ion of the pesticide endosulfan may result in residues of t he parent compound endosulfan I, its endosulfan II isomer, and its endosulfan su lfate metabolite. Thus, th ree residue detections could result from the use of a single pesticide. In the 2002 and previous summaries, the corresponding appendix would have counted thes e results as three distinct residues, while this appendix counts the findings as just one distinct pesticide.

## APPENDIX L. SAMPLES vs. NUMBER OF PESTICIDES 1 

## DETECTED PER SAMPLE 2



## 50

40

30

20

10

0 1 2 3 4 5 6 7 8 9 10 11

0 1 2 3 4 5 6 7 8 9 10 11

Number of Samples 5,958 3,581 1,819 767 400 217 119 41 12 5 1 1
Percent of Total Samples 46.1 27.7 14.1 5.9 3.1 1.7 0.9 0.3 0.1 0.04 0.01 0.01 

## TOTAL NUMBER OF SAMPLES = 12,921

NOTES
1 Parent compounds and their metabolites are combined to report the number of "pesticides" rather than the number of "residues," as was reported in summaries prior to 2003. For example, a sample with positive detections for Endosulfan I, II, and sulfat e would have been counted as three residues detected in the 2002 Appendix L. That same sample would be counted as just one pesticide detected in this appendix.

2 Excludes treated/untreated drinking water samples. 

## Number of Pesticides Detected per Sample

Number of Pesticides Detected per SamplePercent of Samples 46.1

14.1 27.7

1.7 3.1 5.9

0.04 0.1 0.3 0.9



## Multiple pesticide detections may result from: application of more than one pesticide, spray drift, crop rotation, cross-contamination, and/or indicate the presence of environmental contaminants. 0.01 0.01

Appendix L. Page 1 of 2Commodity (# of samples) 

## 0 1 2 3 4 5 6 7 8 9 10 11 Fresh Fruit and Vegetables:

Bananas (742) 24.1 45.4 27.8 2.6

-- -- -- -- 0.1

-- -- -- Broccoli (185) 11.9 32.4 38.9 12.4 3.2 1.1 -- -- -- -- -- -- Carrots (744) 16.3 28.4 23.1 16.5 9.7 3.6 2.3 -- 0.1 -- -- -- Cauliflower (558) 19.7 71.5 7.2 1.4 0.2

-- -- -- -- -- -- -- Cranberries (316) 30.7 44.3 10.4 8.2 5.4 0.6 0.3 -- -- -- -- -- Eggplant (740) 74.2 21.9 3.2 0.7 -- -- --

-- -- -- -- -- Grapefruit (743) 53.6 26.2 18.7 1.5 -- -- --

-- -- -- -- -- Greens, Collard (86) 26.7 31.4 12.8 8.1 10.5 7.0 2.3 -- 1.2 -- -- -- Greens, Kale (98) 29.6 17.3 13.3 13.3 7.1 7.1 3.1 3.1 2.0 3.1 1.0 -- Peaches (90) 1.1 5.6 12.2 16.7 17.8 18.9 14.4 12.2 1.1 -- -- -- Plums (515) 30.7 33.8 26.6 7.6 1.4 --

-- -- -- -- -- -- Spinach (511) 6.3 11.9 18.0 22.9 18.6 12.7 6.1 2.5 0.8 0.2 -- -- Summer Squash (186) 5.4 50.0 31.2 11.8 1.1 0.5 -- -- -- -- -- -- Watermelon (550) 75.3 17.1 6.0 1.1 0.4 -- 0.2 -- -- -- -- -- Winter Squash (369) 54.2 29.3 11.9 4.1 0.5 --

-- -- -- -- -- -- 

### Processed Fruit and Vegetables:

Apple Sauce (744) 7.1 15.1 24.1 22.0 16.9 8.7 5.0 0.8 0.1 0.1 -- -- Orange Juice (557) 46.7 39.0 12.0 1.8 0.5 -- -- -- -- -- -- -- Plums, Dried (224) 89.7 8.5 1.3 -- 0.4 -- -- -- -- -- -- -- Potatoes, Frozen (744) 12.2 43.4 32.0 10.9 1.5 -- -- -- -- -- -- -- Raisins (372) 37.4 27.2 13.2 4.3 4.8 6.7 3.8 2.2 0.3 -- -- 0.3 Sweet Peas, Frozen (744) 84.7 12.6 2.2 0.5

-- -- -- -- -- -- -- -- Percent of Total Samples 37.9 30.0 16.7 7.4 4.0 2.2 1.2 0.4 0.1 0.05 0.01 0.01
Actual Number of Samples 3,717 2,949 1,637 724 395 217 119 41 12 5 1 1



### Processed Nut Product:

Peanut Butter (739) 69.8 28.0 2.2 -- -- -- -- -- -- -- -- --
Actual Number of Samples 516 207 16 -- -- -- -- -- -- -- -- --


### Grain Product:

Wheat (687) 30.9 45.4 19.8 3.3 0.6 -- -- -- -- -- -- --
Actual Number of Samples 212 312 136 23 4 -- -- -- -- -- -- --


### Meat Tissues:

Poultry, Breast (655) 93.9 4.9 1.1 0.2 -- -- -- -- -- -- -- -- Poultry, Thigh (655) 91.8 5.6 2.0 0.6 -- -- -- -- -- -- -- --
Percent of Total Samples 92.8 5.3 1.5 0.4 -- -- -- -- -- -- -- -- Actual Number of Samples 1,216 69 20 5 -- -- -- -- -- -- -- --


### Water Product:

Bottled Water (367) 80.9 12.0 2.7 4.1 0.3 -- -- -- -- -- -- --
Actual Number of Samples 297 44 10 15 1 -- -- -- -- -- -- --

NOTES
1 Parent compounds and their metabolites are combined to report the number of "pesticides" rather than the number of "residues."
2 Excludes the 737 drinking water samples. 

## Number of Pesticides 1 

## Detected per Sample 2 

## APPENDIX L. SAMPLES vs. NUMBER OF PESTICIDES DETECTED PER SAMPLE

TOTAL NUMBER OF FRUIT & VEGETABLE SAMPLES = 9,818 

## Percent

Appendix L. Page 2 of 2

# Appendix M

Fruit and Vegetable Samples Reported to the U.S. Food and Drug Administration as Exceeding the Tolerance or Without Established Tolerance (per Code of Federal Regulations, Title 40, Part 180)

Appendix M shows residues reported to FDA as exceeding the tolerance or residues for which no established tolerance was listed under the Code of Federal Regulations (CFR), Title 40, Part 180. In 2006, a total of 412 samples with 442 residues were reported to the FDA as Presumptive Tolerance Violations.
A total of 30 fruit and vegetable samples and 1 wheat sample were found to have residues at levels exceeding the established tolerance. Fruit and vegetable samples containing a residue exceeding an established tolerance included 1 cranberry sample, 3 eggplant samples, 1 collard green sample, 1 kale sample, 2 plum samples, 7 spinach samples, 13 watermelon samples, and 1 winter squash sample. Of those 31 samples, 12 were reported as imported produce.
In addition, 387 samples were found to have residues for which no tolerance was established, including 304 fruit and vegetable samples, 13 poultry breast samples, 14 poultry thigh samples, and 56 wheat samples.

 367 samples contained 1 residue for which no tolerance was established.

 17 samples contained 2 residues for which no tolerance was established.

 2 samples contained 3 residues for which no tolerance was established.

 1 sample contained 4 residues for which no tolerance was established.
Six of the 387 samples also contained 1 residue each that exceeded an established tolerance.
The columns under the Sample Origin heading provide the number of samples that were of domestic, import, or unknown origin for each pesticide/commodity pair listed.
Appendix M also notes if metabolites (or isomers) were detected as part of the same sample. In instances where both parent and metabolite (or isomer) were detected, PDP accounted for both as part of the same tolerance expression.

## Residues Exceeding Established Tolerance

Commodity / Pesticide Limit of Detection, ppm Concentration Detected,

ppm EPA Tolerance Level, ppm Sample Origin



### 1 

### Cranberries / Spinosad 0.003 0.025 0.01 U.S.

2 

### Eggplant / Acephate 0.005 0.70 0.02 U.S.

3 

### Eggplant / Acephate 0.005 0.18 0.02 U.S.

4 

### Eggplant / Acephate 0.005 0.050 0.02 U.S.

5 

### Greens, Collard / Cyhalothrin, Total (Cyhalothrin-L + R157836 epimer) 0.050 0.14 0.01 U.S.

6 

### Greens, Kale / Cyhalothrin, Lambda 0.006 0.050 0.01 U.S.

7 

### Greens, Kale / Cyhalothrin, Lambda 0.006 0.027 0.01 U.S.

8 

### Plums / Chlorpyrifos 0.003 0.18 0.05 Import

9 

### Plums / Chlorpyrifos 0.008 0.068 0.05 Import

10 

### Spinach / Acephate 0.002 0.081 0.02 U.S.

11 

### Spinach / Acetamiprid 0.0006 0.55 0.20 U.S.

12 

### Spinach / Acetamiprid 0.001 0.24 0.20 U.S.

13 

### Spinach / Acetamiprid 0.0006 0.24 0.20 U.S.

14 

### Spinach / Acetamiprid 0.0006 0.24 0.20 U.S.

15 

### Spinach / Cyhalothrin, Lambda 0.006 0.14 0.01 U.S.

16 

### Spinach / Cyhalothrin, Total (Cyhalothrin-L + R157836 epimer) 0.006 0.12 0.01 U.S.

17 

### Watermelon / Acephate 0.002 0.31 0.02 Import

18 

### Watermelon / Acephate 0.005 0.27 0.02 U.S.

19 

### Watermelon / Acephate 0.002 0.24 0.02 Import

20 

### Watermelon / Acephate 0.005 0.20 0.02 Import

21 

### Watermelon / Acephate 0.005 0.19 0.02 Import

22 

### Watermelon / Acephate 0.002 0.16 0.02 Import

23 

### Watermelon / Acephate 0.005 0.14 0.02 Import

24 

### Watermelon / Acephate 0.005 0.13 0.02 Import

25 

### Watermelon / Acephate 0.005 0.092 0.02 U.S.

26 

### Watermelon / Acephate 0.002 0.081 0.02 Import

27 

### Watermelon / Acephate 0.002 0.069 0.02 Import

28 

### Watermelon / Acephate 0.005 0.069 0.02 U.S.

29 

### Watermelon / Acephate 0.005 0.032 0.02 U.S.

30 

### Wheat / Carbofuran 34 (ppb) 169 (ppb) 100 (ppb) U.S.

31 

### Winter Squash / Acephate 0.005 0.041 0.02 Import 

## APPENDIX M. SAMPLES REPORTED TO FDA AS EXCEEDING THE TOLERANC E OR WITHOUT ESTABLISHED TOLERANC E (per Code of Federal Regulations, Title 40, Part 180)

Appendix M. Page 1 of 4Commodity / Pesticide U.S. Import Unk. 

### 1 Applesauce Diflubenzuron 528 24 4.5 0.011 ^ 0.007 ^ 24 0 0 Pirimiphos methyl 528 1 0.2 0.004 ^ 0.002 ^ 1 0 0

2 Bananas Diphenylamine (DPA) 526 1 0.2 0.10 ^ 0.015 ^ 0 1 0 Fenthion 526 1 0.2 0.012 ^ 0.008 ^ 0 1 0 Fonofos 742 1 0.1 0.008 ^ 0.002 - 0.005 0 1 0 o-Phenylphenol 1 

### 742 31 4.2 0.034 - 0.068 0.015 - 0.033 0 31 0 Parathion methyl 262 1 0.4 0.007 ^ 0.004 ^ 0 1 0 Pyridaben 1 1 100 0.025 ^ 0.015 ^ 0 1 0

3 Broccoli Dicloran 185 5 2.7 0.003 ^ 0.002 ^ 5 0 0 Thiabendazole 185 3 1.6 0.0002 ^ 0.0001 ^ 2 0 1

4 Carrots Pentachlorobenzene (PCB) 2 

### 1 1 100 0.003 ^ 0.002 ^ 1 0 0 Quintozene (PCNB) 2 

### 2 2 100 0.012 - 0.079 0.003 ^ 2 0 0

5 Cauliflower Buprofezin 558 1 0.2 0.0002 ^ 0.0001 - 0.0002 0 1 0 Iprodione 558 2 0.4 0.014 ^ 0.008 ^ 0 2 0 Thiabendazole 558 3 0.5 0.0002 - 0.001 0.0001 - 0.0002 2 1 0

6 Eggplant Chlorothalonil 740 3 0.4 0.012 - 0.045 0.007 ^ 2 0 1

7 Greens, Collard Chlorothalonil 1 1 100 0.013 ^ 0.008 ^ 1 0 0 Dinotefuran 69 5 7.2 0.017 - 0.29 0.010 ^ 5 0 0 Thiamethoxam 69 4 5.8 0.021 - 0.026 0.010 ^ 4 0 0

8 Greens, Kale 3-Hydroxycarbofuran 61 1 1.6 0.018 ^ 0.010 ^ 1 0 0 Chlorothalonil 1 1 100 0.45 ^ 0.008 ^ 1 0 0 Clothianidin 61 1 1.6 0.011 ^ 0.010 ^ 1 0 0 Dicloran 53 2 3.8 0.010 - 0.020 0.006 - 0.013 2 0 0 Dinotefuran 61 1 1.6 0.45 ^ 0.010 ^ 1 0 0 Indoxacarb 98 4 4.1 0.008 - 0.073 0.005 - 0.010 4 0 0 o-Phenylphenol 1 

### 98 4 4.1 0.035 - 0.038 0.015 - 0.033 4 0 0 Permethrin cis 3 

### 37 1 2.7 0.067 ^ 0.012 ^ 1 0 0 Permethrin Total 61 1 1.6 0.25 ^ 0.10 - 0.13 1 0 0 Permethrin trans 3 

### 37 1 2.7 0.062 ^ 0.012 ^ 1 0 0 Thiamethoxam 61 2 3.3 0.050 - 0.058 0.010 ^ 2 0 0 Trifloxystrobin 61 1 1.6 0.006 ^ 0.005 ^ 0 1 0 Sample Origin 

## Distribution of Residues with No Tolerance Listed in 40 CFR, Part 180,

Range of LODs, ppm Number of Samples Samples Reported % of Samples Range of Values Detected, ppm 

## by Commodity/Pesticid e

Appendix M. Page 2 of 4Commodity / Pesticide U.S. Import Unk.



### 9 Peaches Imazalil 30 1 3.3 0.050 ^ 0.030 ^ 0 1 0 Propargite 75 14 18.7 0.033 - 0.53 0.020 ^ 14 0 0 Thiabendazole 31 3 9.7 0.002 - 0.13 0.001 - 0.030 0 3 0

10 Potatoes, Frozen Ethion 1 1 100 0.008 ^ 0.005 ^ 0 1 0 o-Phenylphenol 1 

### 744 32 4.3 0.017 - 0.084 0.010 - 0.033 28 3 1

11 Poultry, Breast (in parts per billion) (ppb) (ppb) MGK-264 655 13 2 5.0 - 81 3.0 ^ 13 0 0

12 Poultry, Thigh (in parts per billion) (ppb) (ppb) MGK-264 655 14 2.1 5.0 - 221 3.0 ^ 14 0 0

13 Spinach 3-Hydroxycarbofuran 366 2 0.5 0.001 - 0.004 0.0006 ^ 2 0 0 Chlorothalonil 3 3 100 0.013 - 0.13 0.008 ^ 3 0 0 DCPA 367 33 9 0.001 - 0.043 0.0007 - 0.003 30 3 0 Diazinon oxygen analog 511 1 0.2 0.005 ^ 0.003 ^ 1 0 0 Dicloran 366 12 3.3 0.003 - 0.010 0.002 ^ 12 0 0 Dimethomorph 366 8 2.2 0.003 - 0.010 0.002 ^ 8 0 0 Etoxazole 366 2 0.5 0.0002 ^ 0.0001 ^ 2 0 0 Iprodione 368 5 1.4 0.014 - 0.074 0.008 - 0.015 5 0 0 Linuron 366 10 2.7 0.005 - 0.031 0.003 ^ 8 2 0 Metribuzin 366 4 1.1 0.022 - 0.084 0.013 ^ 4 0 0 Pentachloroaniline (PCA) 366 3 0.8 0.002 ^ 0.001 ^ 3 0 0 Piperonyl butoxide 367 3 0.8 0.008 - 0.040 0.005 - 0.010 3 0 0 Pirimiphos methyl 366 4 1.1 0.004 - 0.018 0.002 ^ 3 1 0 Pyrimethanil 366 3 0.8 0.0005 - 0.005 0.0003 ^ 3 0 0 Thiabendazole 375 14 3.7 0.0008 - 0.007 0.0005 - 0.001 14 0 0 Thiacloprid 366 1 0.3 0.0007 ^ 0.0004 ^ 0 1 0

14 Summer Squash Clothianidin 54 3 5.6 0.003 ^ 0.002 ^ 0 3 0 o-Phenylphenol 1 

### 54 11 20.4 0.036 - 0.052 0.033 ^ 4 7 0

15 Sweet Peas, Frozen DCPA 529 2 0.4 0.004 - 0.005 0.002 - 0.003 2 0 0 o-Phenylphenol 1 

### 524 17 3.2 0.039 - 0.19 0.015 - 0.033 17 0 0 Thiabendazole 486 2 0.4 0.002 ^ 0.001 - 0.050 2 0 0 Range of LODs, ppm Sample Origin Number of Samples Samples Reported % of Samples Range of Values Detected, ppm

Appendix M. Page 3 of 4Commodity / Pesticide U.S. Import Unk.



### 16 Watermelon A llethrin 189 4 2.1 0.017 - 0.029 0.015 ^ 0 4 0 Clothianidin 370 3 0.8 0.003 - 0.040 0.002 - 0.010 0 3 0 Hexaconazole 190 1 0.5 0.033 ^ 0.010 - 0.020 1 0 0 Imazalil 189 1 0.5 0.016 ^ 0.010 ^ 0 1 0 Thiabendazole 190 2 1.1 0.005 - 0.017 0.001 - 0.010 0 2 0

17 Wheat (in parts per billion) (ppb) (ppb) Methoprene 667 18 2.7 22 - 362 13 ^ 18 0 0 Methoxychlor p,p' 687 29 4.2 8.0 ^ 5.0 ^ 29 0 0 Pirimiphos methyl 687 11 1.6 5.0 - 12 3.0 ^ 11 0 0

18 Winter Squash Hexaconazole 2 2 100 0.033 - 0.35 0.020 ^ 0 2 0 Metribuzin 262 1 0.4 0.11 ^ 0.016 - 0.030 0 1 0 o-Phenylphenol 1 

### 369 3 0.8 0.034 - 0.037 0.008 - 0.033 1 2 0 Piperonyl butoxide 369 4 1.1 0.014 ^ 0.008 - 0.010 3 1 0

NOTES

1 o-Phenylphenol is a disinfectant approved for use in food handling establishments, including production facilities for commodities identified above.

2 Pentachlorobenzene (PCB) metabolite was detected within the same sample as Quintozene (PCNB).

3 Permethrin cis and trans isomers were detected within the same sample.

Note: For those pesticide/commodity pairs where the minimum detected value is less than the limit of quantitation (three times the limit of detection), the reported values are estimates. In a few cases, this may apply to the maximum detected value. Range of LODs, ppm Sample Origin Number of Samples Samples Reported % of Samples Range of Values Detected, ppm

Appendix M. Page 4 of 4

# PESTICIDE DATA PROGRAM

Annual Summary Calendar Year 2006
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