WIARAZ ZI IN usa 

AugList 18, 2009 

Mr. Jeffery Telander 

U.S. EPA Mailroom (D2430-02) 

U.S. Environmental Protection Agency 

4ffice of Air Quality Pla.nning and Standards 

Research Triangle Park, NC 27711 

Re: American Marazzi Tile, Inc. 

April 14, 2005 Stack Test Report Non Confidential Busines`s Information Version 

Dear Mr. Telander: 

As requested, American Marazzi Tile, Inc. (AMT) is providing you with a second copy 

of the Apri114, 2005 Stack Test Report of its Kiln 1 emissions testing with all 

Confidential Business Informa.tion (CBI) redacted. 

Should you have any questions concerning the information contained in our response 

please feel free to contact me by email at swiederwax@marazzitile.com or by telephone 

at 972-226-0110. 

Sincerely, 

Stev T. ' ax 

Safety and Environmental Manager 

Enclosure 

Apri124, 2005 American Marazzi Tile, Inc. Stack Test Report (Non-CBI) 

,merican Marazzi Tile, Inc. Headquarters and Telephone 

Manufacturing Plant 972.226.0110 

359 Clay Road Fax 

Sunnyvale, TX 75182-9710 972.226.2263 

USA Customer Service Fax 

972.226.5629 

wvwv. 

marazzitile.com 

E-mail 

contact@marazzitile.com 
AM E RC gAN M A RAZZI T IL E 

SIJNNYYA.LEpTEXAS 

Em ISSIONS 'g'ESTIiVG 

ifilti .l 

Main Stsacic and 

Hyclrogen Fluorgde rand Hydpogeta ClYloYid'e 

April 1 4, 2005 

Fiie NuuBbcr 05-8005 

Emp?.nyee Owraed ugtd (3perated 

'; ai ESTERN 

~,IVVIROIVMENTAL 

S-ERITICES AP1D 

TESTlNG, INC. 

P.O. Box 1625 

2626 Fliun*ea° Ron-J, Qvitc 1Bv 

Sama Mara;Ds, Te:xPva 7366f 

~ 51 2; 392-'y7i~~: 

;~fht~ l J9Z-~~.=~:~ 

Fux: 1 -1.::} 39;27"190 

~ {. 

J ry J. Kn p 

~ Pr ~ect Manifgl// 
Elmerican Marazzi 'Cile 

Sunnyvale, Texas 

1. INTROD11TCTION AND RESULTS S3JM iNIARY 

Western Environrnental Services a.nd '1'esting, Inc. ( 17Vestern Environ.mental) of San Marcos, 

Texas, condticted a Stacl-c Er,nissions Sui-vLy a.t the Anierican 1V.larazzi Ti1e facility in Sunnyvale, 

Texas April 14, 2005. The production rate during testing, was pov.nds per hour fired 

product. 

Testing was conducted on Kiln 3 for the sources listed t?elow for the followin; com.pounds. 

Source Compounds 

IVlain Stack 

Cooli.nl;Stack 

Hydrogen Chlor'tde 

~~ydrogen Fluorade 

Summaries of the tcst restzlts are presented on the follovrring pages. 

The sampling followed the procedures set forth in the Appendix to the Code of Federal 

Regulations, Title 40, Farts 51, 60 and 63. 

Testing was coordinated 'by Mr. Steve Wiederwax, American IViarazzi Tile, and Mr. 3eff Knapp, 

Western Environmental. '1'he production rate for the testing vras ,)ounds per hour f'ired 

product. 

`'. 

~ 

+1 t ~ • ♦ • v~Lste~•ra ~~avirue~ sree ~e~~f ~ee~~aa~s ~~ d'APste ~g, ~nc. 3D5-8Q3f35 
`lfABLE Dfl' C®NTE+ IYTS 

Page 

i. INTRODUCTIDN AND RESffJLTS SUMMAR`4I 1 

It. '1` EST RESULTS 2 

NU. TEST PRDC1GDITRES 4 

IiT. SDURCE EMgSSIONS CALC'U'LATIONS 11 

LIST OF TABLES 

Table 1: Kiln 1 Main Staek Hydrogen Fluoride and Hydrogen Chloride 2 

'1'able 3: Kiln 1 Main Stack Sampling Locations 4 

LIST OF FIGUR1CS 

Figure 1: Moisture Sampling Train 6 

Figure 2: F'TTR Sampling System $ 

LIST ®F APP]ENDICES 

Appendix A Sainpling Loca.tions 

Appendix B Field Testing Data 

Appendix C Computer Data Entry 

Appendix D Ana.lytical Data 

Appendix E Calibration of Equipment 

Appendix F Resumes of Test Personnel 
11. TlL'JST RES g.l,1JT1J . 

Tab9e 1 

HF and HCI [Uiain Stack Kilin 1 

America.n Ma•aczi lile 

Sunnyvale, Texas 

. 

Run Number: Cerantic 1 ParceiaM 2Porcelain 3Porcalain AyerAae 

Start Date/'rfine 4114/2005 10:00 4114/2005 12:15 411412005 13:35 4114/2005 14:40 Porcelain 

Stop Date1T{me 4/1412005 10:35 4114/2005 12:50 4115/2005 14:10 411512005 15:15 

7'as'EsParam®ters tJnits 

Pa;,, (9arometric nressure, abso ute) in. Hg 29.80 29.80 29.80 28.80 29.80 

Y(Dry Gas P,r1eter Gatibration ractor) dit-nensioniess 0.9960 0.9960 0.9960 0.9960 0.9960 

C. (Pitot tube Coeificient) dimensiontess 0.842 0.842 . 0.842 0.842 0.842 

J(Total Sampling i ime of Teat) Minutes 35.0 36.0 35.0 35.0 35.0 

AH (Qrifice Pressure Drop) In. H20 1.50 1.50 1.50 1.50 1.50 

V,„ (Valurne of Dry Gas Sampied - as measured) 'ie (dr71) 26.818 26.353 25.158 24.727 25.079 

1',„ (Gas Meter "remperature, avg.) Degr. F 89 92 96 98 95 

Vi. (Condensats - impingers and silica gel) ml or g 77.8 72.2 35.7 60.6 36.2 

I,ocationlProc2ss F'aram~ters 

A, (Crass-sectional Area o€ Stack) ft2 5.37 5.37 5.37 5.37 5.37 

Ps(Static Presssure of Stack Gas) tn. H20 -0.22 -0.22 -0.22 -0.22 -0.22 

Tg(Temper°ature of Stack Gas) Deg. F 426 438 425 431 431 

,/A-p (Sq. root of vetociiy head of gas) ~ In. H20 0.4013 0.3980 0.4286 0.4213 0.4153 

COx (Carbon Dioxide) % 3.2 3 3.2 3.2 3.1 

Oz(Oxygen) °k 14.2 14.4 14.4 14.2 14.3 

N..) (iVitrogen) °fo 82.6 82.6 82.4 82.6 82.5 

Catculations 

V,Etd (Gas Sampled, standard conditions (std)) ft3 25.67 24.16 24.91 24.54 24.54 

V,,,td (Water Vapor iri Gas Sampled, std) h3 3.66 3.40 1.68 2.85 2.64 

B,M(Water Vapor in Gas, Proportion by Vol.) % 12.49 12.33 12.41 12.37 12.37 

Gd (Proportion of Dry Gas in stacic) a/o 87.6 87.7 87.8 87.6 87.63 

EA (Excess Air) % 187 194 196 187 192.31 

Md(Moiecutar Weight of Dry Stack Gas) lblib-rnoie 29.08 29.06 29.09 29.08 29.07 

Ms(MoEc:cular UVeight of Wet Stack Gas) €b/lb-mole 27.70 27.69 27.71 27.71 27.70 

P. (Pressure of Stack Gas, Absolute) In. Hg 29.78 29.78 29.78 29.78 29.78 

Flow Results 

Vs(Average Stack Gas Vetocity) ftlm (fpm) 1796 1782 1917 1891 1863 

Qytd (Dry Volumetric Flovu Rate, std.) 1`13/m (dscfm) 5006 4922 5351 5244 5172 

Q. (Measured Volumetric Flow Rate, Actual) ft31m (cfm) 9641 9866 10294 10152 10004 

Hydroaten Chloride 

Concentration ppmw 9.976 28.333 26.917 27.880 27.710 

Concentration PPmd 11.40 32.32 30.73 31.82 31.62 

Em issions Ib/hr 0.32 0.90 0.93 0.95 0.93 

Hvdroaen Fluaride 

Concentration ppmw 27.811 62.452 57.827 58.858 59.712 

Concentration APmd 31.78 71.24 66.02 67.17 68.14 

Em issions ib/hr 0.50 1.09 1.10 1.10 1.10 

,..i~ 

Western n nvie-onmen#:s<l Scrrraces ans9 Testang, Inc. 05-$005 2 
?►mcrican ATarar/i 'rilC 

Sunnyvale, Texas 

1111. TEST PROCEDURES 

"I'he sampling and analytical procedures used followed the p rocedures outiv2ed by the Appendi - ~~ 

to the Code of Fcderal IZeg~uiations, Titic 40, P3its 60 and 63. A brief description of each 

rnethod is provided below. 

Part 60, Annend'ax A 

Method i "Sample and Velocity Z raverses for Stationary Sources" 

Method 2 "Determination of Stack Gas Velocity and Volumetric Flow Rate" 

Method 3 "Gas Analysis for the Determination of Dry Molecular Weight" 

Method 4 "Determination of Moisture Content 

in Stack Oas" 

Part 63, Appendix A 

1l/Iethod 320 "Measuremerrt of Vapor Phase Organic and [norganic Emissions by 

Extractive Fourier Tmnsformed Infrared (FTIR) Spectroscopy" 

Samplling Nln$ Determenati®n (Method 1) 

EPA Method 1 was used to determine the location of velocity sampling points. Stack sampling points are 

based on the sta.ck diameter and the distance from the sampling ports to flow disturbances. 

'U'able 3 

Saflmp6ing Lmcaglons 

Kgln 1 

Main Stack 

Main Stacic 

Stack Diameter, inches 31 3l8 

Upstream Diameters to Flow Disturbance 5.74 (180 inches) 

Downstream Diameters to Flow Disturbance 5.74 (180 iinches) 

,. 

, . 

Western Enyironfin!,Sntal Services nnd Tcsti -pa, Ia~ c. tl5-84U5 4 
Ainerican Marazi Tile 

Sunnyvale, Texas 

Vel®ci>ty and Fl®w Rate Determinatl®n (Method 2) 

Velocity and temperature were rneasured at the points determined ny Method 1 during isolcinetic 

testing. Wind tunnet calibrated Pitot tubes were used to measure velocity head. Type K 

t.hermocouples with digital pyrometers were u.sed to measure temperature. 

Carb®n Daoxide9 ~~~eag and Da'~ I~®~ecaaBa ~ ~Tei~~a>x_~ete~-a~a~~~$1®~a ~'I~ eth®d ~~ 

A portion of the gas from the sampling trains was collected in Tedla.r bags. Analysis of carbon 

dioxide (CO2) and oxygen (02) were performed with an Orsat Gas Analyzer. Dry molecular 

v4reight was calculated frOm COZ and 02 concentrati.ons. 

iMoisgure Conteng Dettermenatiton (Method 4) 

Water entrained in the stack ;as was condensed and collected in chilled impingers in conjunction 

with the i.sokin.etic sampling. The volume of gas sampled was measured with a calibrated dry 

ga.s meter. Moisture content was calciilated from the gas and liquid volumes. 

A schematic of the moisture sampling system is shown in Figure 1. 

Westre•n Environmental Services arad Testing, ine. 05-8005 
.4merican vlartzzzi '1'i le 

Sunnyvale, Texas 

Temperature Sensor 

Heated Probe / Impingers 

Type S Pitot ; ~ 

~ 3 E ~ • ,. IGe 

13aU1 

Heated ~~Z .tiT~fi~ adified 

Filter GreenBurg - Grcenburg- ~.eenbur - Gree~urgSmith (I(10 Smith (I00 Smith g Smith 

ml HZO) ml H40) (Empty) (Silica Gel) 

Temperatiu•e Scnsors 

By-Pass Valve Vacuum 

Gauge 

Dry ca.s lviain 

1Vleter Q Valve 

Manometer 

'r Tight Pump 

- --- Figuire I 

Moisture Sampl"nang Train 

T~ , r 

~~ . Western Environmentai Services and Testimg, Inc. 05-8005 6 
American Mara-r.~i Tile 

Sunnyvale, Texais 

I+'aurierTransf®rm Infr2red Monit®n• (fTgR. ~ 

Pollutant concentrations were c}uantified in accordance with EPA Reference Method 320. Test 

contaminants measured and reported using the FTIR include the following: 

* Hydrogen Chloride 

® Hydrogen Fluoride 

Western Environmental operates an extractive Fourier transform infrared (FTIR) spectrometer 

manufactured by Industria! Monitor and Control Coiporation (IiV[ACC) of Austin, Texas. The 

FTIR is composed of four main systems; the analytical bench, the cell, analytical software, and 

e:ctractive sampling system. 

© The IMACC FTIR operates on a Nicolet bench with a zinc selenide beam splitter, fieNe 

laser, an IR sour ce, and an MCT-A detector. 

© The cell is composed of objective and field mirrors, which are gold plated. The cell is 

designed as part of the FTIR unit, which is capable of operating at a path length of 10 

3neters. 'i'he celi volurne is 2.728 liters. The cell is operated at a temperature of 185 C 

and is coated with nickel to prevent corrosion. Analytical system leak checks were 

performed prior to any testing. Results of the leak check are -provided on the field data 

sheets contained in the Appendices. 

o The analytical soflware used by Western Environmental is Nicolet based so$ware with 

1MACC modifications to improve the softvvare suitability for extractive FTIR 

monitoriuig. T'he rnain programs utilized in the collection of data are Omnic and 

Getconcs. All Graphical presentation dtuuig sampling was performed by Concview. 

0 The extractive sarnpling system is composed of a heated probe and heated Iilter assembiy 

operated at 185 C. The fiher assembly was connected to a heated sample line that 

delivers the sample to the FTIR cell. The sample was drawn through the cell at 10 liters 

per minute by a heated sample puinp connected to the exha.ust port of the cell. 

.~ 

; Western E nvircanuncntai Services aanci Te5timg, dnc. 05-8005 7 
-- Stack Wall 

with port 

~~ ff 

i fiylt`.~'SYY[77.ti iiCL:ls45 

I 

Heated S,,unple 

f'rCn ~inl f i ~n 

\ 

Heatecl Glass 

Probe 

American Mararzi Tile -

Sunnyvate, Texas 

Sclaemat$c ®f Metrh®d 320 Samflplang Trann 

1Figure 2 

FTA.R SampOng Sysgenn 

This method applies to the analysis of vapor phase or;anic or inorganic compounds, which 

absorb energy i.n the mid-infrared spectral region, about 400 to 4500 cm 1 (25 to 2.5 μm). 'This 

method is used to determine compound-specific concerrtrations in a multi-component vapor 

phase sample, which is contained in a closed-path gas cell. Spectra of samples are collected 

using double beam infrared absorption spectroscopy. Omn.ic is used to analyze the sample 

spectra and report the compound concentrations. Exa.mple absorbance spectra may be found in 

the Appendices. 

Analytical range and sensitivity depend on the frequency-dependent analyte absorptivity, 

instrument conf guration, data collection parameters, and gas stream composition. Instniment 

factors include: 

® spectral resolution, 

Western Environrnenta! Servdces and '1'vsting, Inc. 05-8005 8 
American Maazzi Tile 

Sunnyvale, Texas 

m interferoineter signal averaging time 

® detector sensitivity and response, and 

® absoiption path length. 

Due to the unique nature of hydrogen chloride and hydro;en fluoride the following QA/QC 

efforts were performed in addition to the requirements of EPA 320. 

* Line loss detenni.nation was conducted at various concentrations using Hydrogen 

Chloride. Pcrccnt recovei-y was 99.23%. Documentation is provided in the Appendices. 

* Sainple line conditioning was perfor.med for a minimum of 18 hours to ensure proper 

sample acquisition and spike recovery due to inherent line permeation of HF and HCI. 

* Multiple backgrotmds were performed during the testing period. 

An estunate of gas composition was inade based on previous test data, and duritlg preliminaty 

scr.eening. The spiking for hydrogen chloride was perfonned ili accordance with EPA 320 in fhat 

the spike value was based on preliminary observatio.ns and expected co.ncentrations. Optimal 

resolution for the INIACC -unit is 0.5 cm 1. In accordance with the MACT standard similar 

source spiking has been provided as docw -nentation of spilcing. Instrumental conf guration shall 

be selected based upon manufacturer suggestions and previous experience. Spectral interferants 

shall be identified using the selected band areas from reference spectra and interferant spectra. 

.Example spectra of interferants may be found in the Appendices. Analytical method 

dcvelopment included linearization of compounds over the range of detection, line slv.fl 

adjustment, and inclusion of interferants. The baseline noise of the system was measured in each 

ana.lytical region to determine the Maximum Analytical Uncertainty (MATJ) of the instrument 

configuration for the analyte(s) of interest. All cotnpounds measured in this test program were 

above the detection limits for the compounds. The Appendices contain the baseline noise of the 

instrument. A hard copy of the analytical methodology may be found in the Appendices. 

In extractive sampling a probe assembiy and putnp wili be used to extract gas from the exhaust 

of the source and transport the sample to the FTIR gas cell. Typically, the sarnpling apparatus is 

simzlar to that used for a single-component emissions monitor. The digitized infrared spectrum 

of the sanaple in the FTIR gas cell rs measured and stored on a compu#er with a backup stored on 

a separate disk. A copy of the spectral data is included in this report. 

.. Westca-o Enwirnnmenta ➢ Services and'Tes#ing,'tne. 05-8005 9 
Ainerican Marar.zi Tile 

Sunnyvale, Texas 

Specifications for the I1l/IACC FTIR. and testing pararneters are provided below: 

m Appodization — Happ-Genzel 

* Resolution — 0.5 as detei-mined at 1149 cin 1 

0 Detector -- MC"T-A 

Ij CelI Vol«nie — 2.728 liters 

Indeperadent iarnple Tirne -- (at 10 lpxn) 1.36 min 

P re anad P ast T est Evaluations 

Q Pre- and Post-test CTS spectra were gathered and evaluated. 

o Pre- and Post-test NEA (Noise Equivalent Absorbance) and Background 

measurements were made for each source. 'Three independent spectrra were gathered 

at the source prior to testuig. Spike ilow rate was 1 liter per minute as measured by 

a mass flow controllcr. An independent sample is on.e that is gathered after 5 cell 

volumes have passed through the ce11(Section 3.6.2 Method 320). Because the cell 

volume was 2.728 liters and the system flow rate was at least 101iters per minute the 

independent sample tirne was less than 1.36 minutes. Spiking was performed on a 

2-nninute integration interval and therefore the spike measurements vsrere obtained 

with a min.imum two-minute separation. 

a Path length determi.nation. Path length was determined prior to tcsting using 

chlorodifluoroniethane in nitrogen at a concentration of 10.1 ppm. [7sing in:legrated 

area ratios against a reference standard concentration the path length was 

deterrriined. A copy of the calibration cerrif cates may tie found in. the Appendices. 

m A complete system leak check was performed prior to testing. Results of the system 

leak check are provided on the field data sheets. 

'S 

r 

{9 J-~~~}~J ~ ~ a u~ `:. ~filesteF m En~rmnme ~atal Serviceg as ~ t8 '~'estang, tnc. 
3. Modsture contemt, % 

Bws — 

v

'Y("d) x100% 

um(sW) '+' uw(sW) 

~ 3.66 x100 °/n 

25.67 + 3.66 

- 12.49 % 

B„7= Percent by volunie of water vapor in the gas strecuit 

v„t,,d)= Volume 0t 3) of water collected, at standard 

cornditioirs 

V,,, (,,,o— Vol tctne {V) of gas tiv -ough the dry gas nieter, at 

Standard conditio)1S 

American Marazzi Tile 

Sunnyvale, Tocas 

TV. S®URCE EMISSI®NS CALCIJLATI®NS 

The values in the sample calculations shown below are from the 1Viain Stack Run 1. Computer 

generated numbers were used to eliminate rounding error. 

1. b'olume of water collected, staudai•d cond'ations (wscf): 

Vt.(std) = it(Vjc) 

= 0.04707(77.8) 

= 3.66 wscf 

yqrrd) = L'olume (1?) of iyater collected at stcindard 

r:rnzditialar 

Vr, = Vollrnie of'll yriid vollec•ted ln iia:pingers 

K — 0.0=1707 , C'onverslonfcrclar (ft;/ml) 

V,,, = Vol icune (ft 3) o, f'gas tlrrough the clry gas ineter, at 

standard conditions 

V,. — Volume (fi 3) ofgas sample through the dry gas meter, 

ambient conclftions 

P&,. — Baron:etric pressure (inches of Hg) 

dH = Average pressure drop across meter orifice (in. H~O) 

Y— Drygas nteter conversion factor 

?',,, — Average dry ga,s meter ten:peratw-e (°F) 

K= 17. 647 — Conversion factor (°IUinch Hg) 

13.6 = Conversion factor (inch H2O/inch Hg) 

460 = Comersion constant (°F to °P) 

Z. b'olume of gas nueterecl, staud:ard comditeoas (dsct) 

(K)(V m)(Pbar + 

~ 3 ~ )(Y) 

(460 + Tm) 

(17.647)(26.818)( 29 .80 + l3 6 )(0•996) 

(460 + 89) 

= 25 .67 dscf 

_.~ 

' Western Environmental Services aroct Testing, gnc. 05-8005 11 
American Marar.zi Tile 

Sunnyvale, Texas 

4. Dry Gas, % 

Gd = 100-B,s• 

= 100-(12.49) 

= 87.5% 

5. Mr>lecalar zreaght ol' dry Mas streaua (1b/1b-niole) 

( ". ~ Ct)2) (°b0z) (°.~,CO + 06 ,42) 

~d = NI co: - -~• Ma: ---- -I-( M r.c► „ ~ M N: ) 

(100) (IQO) (IOO) 

~ 44.0 (3.2) + 32.0 (14.2) + 28.0 (82.G) 

(100) (100) (l 0U) 

— 29.08 lb/lb mole 

streatn 

100 -- = Conversion from percent to decirnal fraction 

Gd= Percent oj'dry gas by volutne in the gas stream 

B,,, — Percent by volume of ivater vapor in the gas stream 

~,I,j ~ Dry tnolec•rtlar ti;efght o•f'santple ga.s (lh/lb•tnole) 

11t~02— rUlolecttlar• sviglit of cat-bon clioxicle (Ib%lb ~ tr:ole) 

Ho;— :blolectllar weight of oxygen (lb/lb'tnole) 

~c.n ~rva =~ .rllolecular weiglzt of CO or 1V2 

(1 b/1 b -ntole) (Sante) 

CO2= Percent by voltime of CO2 ln tlze ga.s stream 

02 = Percent by volume of axygen in t/te gas stream 

CO+N2= Per-cent by volurne of CO and Naln the gas 

6. IYdolecular weight of sannple gas (15/lb-mole) 

MS= (K)(G(I/ 100)+(MH2o)(Bws/ 100) 

= (29.08)(87.5/100)+(18)(12.49/100) 

=27.71b/lb rnole 

7. Sainple gas pressure (iuches of Hg) 

ps = 

(N) 

(13.6) 

=(29.75)+ (-0'Z2) 

(13.6) 

=29.78 in. Hg 

8. Velocity of sample gas (ft/miaa) 

V$=(K p XC p X60 XVAP 

TS+ 460 

(M s Xps ) 

476 + 460 = (85.49 )(0.842 XC~O ~'(0.4013 ) 

27 .70 x29 .7Y 

= 1,796 fpm 

Ms= Molecular weight of sample gas, wet (lb/Ib•mole) 

UJ= Dty molecular weight ofsatrtple oas (1b/lb-tnole) 

G,j Percent of drygas by volittne in the gas stream 

B, vs= Percent by volume of water vapor in tlze gas str•eam 

MFtzo = Molecular wefght of watet• (Ib/lb-mole) 

P, L Ahsolttte santple gas pressure (inches of Hg) 

Pbl,. — Rarometric pressure (inches of Hg ~ 

Px= Saatple gas static pressure (inches of HZO) 

13.6 — Conver.sion factor (lnches 11?01inches of •Hg) 

CP— Pitot tttbe constant 

kp= Yeloctty pressure coefficient (dlmensionless) 

60 —Conversion factor (sec•/tnin) 

A,f, = t1?olecular velght of sample gas, wet (lb/!b•mole) 

Pa— Absolute snrttple gas pressure (inches nf Ng) 

T, = ilverage santple gas tetttperature (°F) 

LJ = Sample gas veloclly (fi/lnin) 

Q p a .lverage sqttare rorlts of veloc•itv heads of stack gas (in 

Ff,U) 

460 = Conversion constant (°Fto °R) 

: %A' Wesgee•aa iEsavirowmecagat Sea•v9ces and '1'estiug, Ilrnc. m5-8005 12 
,Aineriean MRrazci Tile 

Sunnyvate, Texas 

9. TOta@ $larw of samplc gas, stctusal conditn,aats 

(acfm) 

Qo = (As)(Vs) 

= (5.3'1)( I,796) 

= 9,641 cfm 

Qavolrcnteti•fc floiv t•ate at actzral conclitions (acfm) 

A, = Cyoss sectional area of satnpling locatfora (fV) 

i~r = Satrrple gas velociry O/urin) 

10. Tt)#al flU'fiV UY SaMple ozas, sta7t(12rd cORd=.tlO[I5 

{~s~~m} • 

(QA)(PS)( f 7.647)` 

1100~ 

(T!, -t- 460) 

(9,641)(29.78)(17.647) 87.5 _ 100 

(426 +460) 

= 5,006 dscf 

Q.rrr! 'VolutFUtricflotiv rate at statadard condtions, diy basis 

(dscfiri) 

Q„ --- Y'olumetric flotv rcrte at actrral cotiditiorrs (acf n) 

I',. — ilbsol2cte sample gas presszu•e (iszches of'11;) 

G,r -= Percent of cliy gres by volittrte an the gas str•eam 

1; ~ tverage sample gas tenaperature (°F~ 

17.647 — Corn.erstoii factor (°IZ'itach I:fg) 

460 — Canver.sion constant (°I' lo °R) 

Westcrn Etavirvuniental Serareccs ttncl Tes -Ling, Inc. 05-8405 13 
APPENDICES 

A. Sam;pH!ng Locati®ifts 

Bo Fteld D'ata Sheets 

C. COMPUler Dat-a Entir-Y 

& ADalyt-ac- al Da$a 

E. Calibrgti®n o' f Equipm-ent 

F. 9. 0- sagoes of'Test Peirs:onnel 
APPET"I 

slalAlplin 'g, LO-C atib-as 
~aIM I 

Sq.- ~r~pSung 'Le«adeas 

Malua stack 

inside Sfwk Diameter = 31 3{8 inckes 

Pozt md Wati ''thickness = 3 5I8 incfies 

Sampte % of ludes frvm 

E£tln-t ho. ~~~ Il~~GI' ~ 

T 2.1 'N ~! 

2 6.7 

3 1118 3' 1/1s 

4 17.7 5,111 s 

3 25.0 713116 

6 35.6 i 1 3It6 

7 64.4 f-20311(, 

~ '?~.4~ ~3 1

12 

9 32.3 2513ljG 

i#D 8 S.12 7.7i'I1 4 

11 93.3 29'14 

12 97.9 ''3031g 

'Iftint iacated at I" *om -vvaii per EPA. iMethod I 
APPENDIX B 

Fie. ld Testing Data 
_ Clent; 

LACBdon: 

Operator: ` 1117 

Job No.: 

Pott A 

Part & imsfde Dba.: 

Port & 3mide Wail 1'tftk: 

Snside 

"JIesgern Environnieratat SeQ+.rfcee erad Tsetin8, lna. 

Prea3nwtSTy vetociiy ®o4a 

Sourae ldanti€icetton ~-4 ~ 0 

Port B. Part C Port O 

TDME: Pt3RTi cA "?CRT B PCiRT C PQRT O 

D'si.fram 

Point Ra9. point, aist. ftm Ref. 

No. 9'o F)ia. 0.011, Poi;1t, 1/1 fi ° _„p 1 Ternp ! GYd. _P /'temp t Cya1. ,_.P ! Temp J Gycl. _P / Tc;mp / G~rd. 

2 ~-`"1 "Z..1 ~9 'Z ~ 1c. 

3 

a i`? •-T ts 

—7~ 

7 ~ .~ '~.'~ ~ `~~ . i~ 

g .C~ 2~ -~'j `~.~ I Z I / 1 1 1 I 1 1 

9 at a ' 1 1 1 I I I 1 ! 

10 'z7. o;~7 —e7 1 (o 

11 'Z4j• -Z`]. -zq 

12 • ~' 20-1-z so~ 

Aver39e: 

Pitot No. % Moisture Velocgym 

C CO2 ''ime of °Tesf - 

Pb 02 Assumed SCIFM 

Ps Co Assumed Vrnstd 

As N2 Dn 

A.._._P Md SCPM Earn te 

Av . v P tUIUVd / H 

Av .Ts mU4! K Pactor 

Ayp.C clonic !/mstd 

Area og Stack: !soldnefic 

ACPU SCFM 

SEE BACK POR g3fl1bWIN43 AND PUFffHEA 1NPC}RMATIOiV 

'S1andard. 628 R. 29-92 "Hg, (20 C., 760 rtm M9) 
oparBCrR► a74iaf=88%8%8Qs 

"lient: 

rm S#ack at Sample Locatson: 

:i ® / rectenguiar 

3ism®ter, equit aient: 

:pstream Equivaierit Diarrleters: 

?ownsgrearn EguZvatent DianZeters: 

*or rectanguiar siack, De Caiculaiion: I

x ier&gih x-yttidth _ 

length + }Mdth 

-;derior St,ack Schemagc: 

ndicate BD, p'&W, P&MQD) 

Rec8engulae:llLack iP®int Cabudadoae , 

Side dirnenstOR/nuraber ot points 

First iaointis baEf tfiatdi'stance #ram the tront viaii 

~ 

,~ - 

d ~ 

a, 

- ~l ~ ~ t0 `K ~ 

`~"~ 
Paceiify 6~~' Job i~®: ~~ 

Run f~o.~ Cate: ~ /y o5— 

SourceJ I.D. No. d2&g :.5;~c 

Stack: Area in2A3) Dia (in) 

Operators 

Meter Box #2Y_Ca1ib. Pactor(Y) d• 

Nozzte k -- Diame4er (Da..=_ 

Pitot t.D. L-%,Q Caitb.Factor(CO.QaZ-- 

FloOd Data 

AWestern Endiro,ifhantal$ervic;es and Testing, Inc. 

o9Stsck Cnass Secdon K Factor -- 

Barometric Pressure (P b),~~ 

Amb. °F ._75~—Assurned Mofsture °la 15 ~ 

Static Stack Pressure "H20 

,$ Probe Lenyrh ! Material 1156 

. Befare t~lddla Afit 

Pltot ~'ube Leait Check ,~~ r__._.. 

lnhlaf Leait(d,} ,,d~„RHg =- g- Ornin 

oF' Up Gas Now Ou41 i Pinal Leak @ fJ" . O ui•ig = e.gX ff/rnin 

~~ IF)M b~ PA. M. m K~aI

~e~mi 

1 

~

~WAWA~~~~ lmom~:a~aa~~~~~~~~~ r~-s ~~wact~ai 

~a~ ~e~~~a~~a~~~~~~~~m~~~; 

AM munmim~~ 

Im~~~~~~r s~~~~~~~ ~ar~; 

~M.M! m =No~~~~DF~~i 

WE ~~Y ~~~'~i~~~~ 

Uncorrected Vra, __„_ „+ft3 %CO2 ' _ %CO_____, Sampfe Purae: in3#ia! F'tnal~ 

Corrected V,,,. _„_ fi3 %02 ~~, ~ °IoN2_„_ !lolurne Collected 1lj .,r,______ mi Sample Time, 8 min. 
.aob No:0~2 900 'rZ) Run ~ 

Faeld DaM Samgs9e Box l:to:,_~____._ 

Source !D 111o: 1'-Nkvz-:~ Filter No: 

# 2 ~ 5 

Loonisnmivmo ~~ ~~~ ~~-~ ~ , G-. • : 

,nP style P-%03> ce - ~- ~~~~ v C=;D 

RBBal 

~~. Set- o aa. t) s,~. '' -1 •.1~ 

Initial Wt. S ~(~ ~~ l .~ SFs''Z ` t 16142- ~5 

D9fferQnce 

T®w (VIC) 

f Me= 

~ ot-!= 

Ts= 

Tn„= 

1/MsW= 

% iw 

Md= 

1twaas = 

Mwa= 

VS 

8CfIT1 

dscfm 

EA 

°!o flSO 

Catculatioras 

Vvx= 0.04707(Vic) 

VM4.o _(17 647)(Vn}(Pt,+Z)(Y) 

(460+T.) ~ 

Bvs = 

V 

xI00% 

~c~ + V~c~~ 

Gd = '100-BH,S, 

Md = 0.44(%C42) + 0.32(0/1642) + 0.2${°/bN2 + %CO} 

MS = (Md) (Gd/i 00)+0 8)M,.-Jl 00) 

Psz (PL ~ }(P8) 

(13.6) 'r 

P )(C,)(6Ox1APk j ~~s + 46Q

vs ~~ 

(MS xps ) 

Qa = (As)(VS) (acfin) 

(Qa)(Ps)(17-647)(to~~,O -

fTs 

G~~ — , 

 + ~60) 

K(Ts+ 460~ Vm (std )) 

i ° 

(Ps )~~~( ~-) ° { ~ ~ 

Vy,= Volums aftlquid CaMwed (grsms ornt# 

8fld = Dry nroleaularvyelghf cf sempfe yas (ltrlfbumols) 

Ms= Mabauler tvaJght af sXrtple gas, wet (1hOfb*ma/e) 

96CO2 = PerCnt hy valuma of CO2 fn tha ga.s sbeSm 

°60$ = PgwrJt,ey vvfctrns ofaxyggn In !he gas siream 

gSC04%lUa = Pensntby volums Qf CO arrd Alz In Hre gas 

Gd M F+sMent af dry gas 8y sralunge ln the gas s&erm 

fi6 = % by votuumofwaterYaWIn ft gasstwm 

Pa =Absafuto sarnpla gespraum (l,rejies oftEg) 

P6, = BaJamebfc pvwm ('iuhes af Ng) 

Po= SeMPle 9as stsft MMMM (Fiudtes of H20) 

136 a Ca;wm&nfaafarr'mchw H20lfnch¢s of NgJ 

Cp = Pllat trtbe constent 

Kp = Velaaity prssscag coelTtcfent (dTmsnslcrilsss} = 85 49 

G!? a Carrvnrsion fector (secftTq) 

M, =1tllaleaularwsighf of samp/a gas, wet (1Mb-mole) 

P;, = AbsolrAg sample ga.s pnwura ('mahes of Ffg) 

T?s Aver8ge 38mp1@ g8s hammpmture (79 

!Iaa Sampde gas vsl404y (3t/se4 

d P= Avwage squsm mata cf yefacFly heads of grts (in N20) 

460 = Ccrtverslan canstant (°F to °R) 

Qa= Vofumstlfa flow rob st Qrtuel aonditlons (8c.lfm) 

A, = Craw ss.atlana/ aram of sampl;rrg loccatlan lW) 

V. = samPlb 9as velocdy (rdnzfn) 

Qzw = VaL flaw rsts et stenriard condilfcns, dry (ct,scfm) 

K = 0.09460 = corzterrt 

D. =Avsmga d1ameter of nazda W) 

0 = To#al samFling tims (min) 
Faciiity ..al'I ,'

. , 

~ job W a 0'5-7;P0 

Run fvo, - Date: 

Source/ I.D. No._ ~~ ~~~,_....~ 

Stac~t: ,~rea in2(AL) Dia (in),_______„ 

flp$rators, ~~rj° _ 

l~teter Box # 2t Calib. Factor(Y),~,,.,~9 4 

No~e # = Dlameter 

wito# t.i~. ~ ~a Callb.Factor(Co.~~Z„ 

~i-v,~~ Fge9d Data 

Ar 

Westertt Environrrceritial Services and Testing, ltic. 

K Factor 

Baromafrio Pressure (Pb).RM 

Amb. °F .~t Assumed illioistufe a/a 6E 

Static Siac€c Pressure "H20 

Probe Length / Nia9e(ai 

Before twaer 

Pitot Tube ~ak Cberk ~ ~ 

lnttiai Lsak 0 0 "Hg ~ ~Z)ft 3/cnin 

Final L.eak 0 o j'Hg- W/rnin 

I ~:~.~~. — 

. . . ~ Com 

M-.~~~~~ 

~~MIFA IMIWWA RIM 

LEE 

W, il

M~~M som . . .... 

y

I~ 

M~ ~—~-. MON= 

NO 

_~~ 

Uncorrected V, , __fi3 °!oCO2 . D %Cq~ Sampte Rurge: tMa l ..Fka! 

Corrected V,

,--,ff %02 • %AJ~,~ Volume CoiiWed V~„_ mi Sampte Time, 8-,min. 
.9ob No: OS R¢sn #~ 

Field Datq_e/& .I&re Sampl® B®x No:_______ 

Source 8D No: lcz Pi ~it~eP No: 

VI~ 

AHM — 

, • 4 5 Ts 

Qmpinger # TM= 1 2 3 

Contentwoto 57 fca .P/ /PI 

Tp ~ ~. ~..,~ 

~~~s.~ ~ ~. ► ~ ~. rvt.~s~ 

C~ t 

~ J~ 

~~~ ~ 

r 

~t►R~U~ 

Vs• 

acfrn' 

g~ 

ZT"'F1f73~tB ti`1S74a 

rr '~ `7 

~ 7J ~ L✓ ~~Uea~ ~/ ~ 

C ~" 

+YJ i ~J 

4nliflaa Wte 

~89- ~ 09V ~ - ~ ,.~~, o 

Defference 

dsafm 

EA

. T®tai (vw) 

% 080 

~ 

Calcu[ataons 

~I,z 0.04707(Vic) 

_(I7.647)(V.j jF6 + °H )('Y) 

(460+''~,) 

~..i~ 

~ss ~ 

VWAmy xl0a'p/o 

VM(%* +VW(S* 

Gd -= I OD-Kvm 

IMd= 33.44(°foCO2) + 0.32(°fo02) + 0.28(%N2 + °loCO) 

K = (Md)(GdI 00)+0 8)(8vd9 d30) 

P's ~ + (P8) 

(13.6) 

Vs - (K P XC P X60XVa) ~ 

+ 

~

464 

~Ms ~'s) 

Qa = (As)(Vs) (acfm) 

(Qa)('z)(l7 647)( a~ 

$~~ = 

(fa -1-46Q) 

K(T9 + 460)( Vm (std0 

1~ 

(PS ~~ 6d 

N

~ 4~1 ® ( 0 ) 

Ve= Vckrmer sifdoprtd Callbcted (grams or mlJ 

M 13rymaboutarmeFght o,t'stimFle 8n P/Mnncta) 

Me lYlatoattfer woW of wmpte 9as, tsre# (WbemuEs) 

46CO2 = F'encentby sraluw cf COa hr the gges sbasm 

9602 = Pement by vclumm ef axygen ln tfie gas sLream 

°,6C0+%N2 = Penerlt by valume cf CO arzd N? In ttle Qes 

Ga = Penaent afdtygas by volume fn ffte gassbwm 

@6 = 9d by vdume of osnQtereraporfn Lh+s ges sftem 

Pa- Absofute 88mp#e gas "^ara (hiche8 of Hgj 

P6r= Barcmatde prsssura (fnthes afHgj 

Pg - Sample gas staftpmwwe {indres aFNA) 

43.6 = Ccntrarskn gacl`or (lncPres HgOrrraobss cf Ng) 

Co = phw bbe coastant 

Kp= veMclty prassurra cnsffcferrt (dlrlferrsfonles)= 85.49 

50 a Canverssan fecta-{seclmfn) 

Mo = ABolecaar taneiglit cf sam#e gas, wet (f.ir/Ib-rnore) 

Pa= Altso/ute sampfs gas Rreswm (lnch,es nf Hg} 

T, = Averag$ sarnplP gss iemAmkm f°Fj 

Va = Sampla 9as VOW* (ffwc) 

a P= Avmge squam mais aF vidav7y bEads cf gas fn Hs0) 

460 = Cmvetean cnrssfairtrF to-°R) 

Qn= VoJumeft f7aw rate at tdual aartcWWs (aefrn) 

As = Crvss seeftrtd area of sampfft lacellon (t'+ ) a

Na rs Sarajvl8 gas vsj,pav (Rlrnivt) 

Qcm - Nal ftwtate atstandarti ccndk#cns, dry (dscfm) 

K = 0.05460 = csnstarlt 

Dn=Avcrags diamster cef aoale M 

9 n TWsamplFrig ffine (mfn) 
FaciBifcy}JIA ,*r Job lVo: 457I 

Run No,~_Date: 

Source/ I.D. No._~6r 

Stack: Area in2 (AsI,_„_©la (in)_ 

Operators,, 

Meter 6ox #, Calib. Faotor(Y~~;.Y2,/ 

Nozzle # _ Diameter (Cn)_.=. 

Pitot I.D. –ie> Catib.FactortCO —a. ,&,~ 

,,~L~vre F6eld ®ata 

8chsmsft a! Star* Crm 8ecwn ' 

; 

AJ l 

oi' U Gas Faow ®u$ I in 

VUestem Environmental Services and ies4ing, Inc. 

K Factor -- 

Baromefric pressure (Pb) -__ 9_ ~ r__, 

Amb. °Fjf~ Assumed iWotsture %!~ 

5tatic Staclt Pressure "HzC ( }~ _o •_? ~ _ 

probe Length 1 Material 

't3efore Mtk% After 

Pitot Tube Leak Checit 4t 

tnitial Leak ('c,~/,5- d , ~ 'Hg = agog ft3lrnin 

Final Leak (a~ A- 0 "i•ig =0 dxO fi3lmin 

~~~~ 

~s~r~ar~~~~~~ a~~a~'I VA~~e~; 

MEMN 

A, 

~

r.~~~ MIWe~WAIWAM~we~»; 

I~im~e~s~~~r~a~~~~~~~~~~c~~~~~; .

e~e~~~~~~~av~~~~m~~~; 

mr~~~es~~ae~~ss~ ~ ~~. 

Uncorrected vm - - - fi3 %co231 2 %Co,,.,._..q, Sample "e: iniUat Fin - - - 

Correct®d Vm ~n3 % %Nz Volume Collected Vl,, mi Sampte Time, 0 ?r" min. 
Jolb tVo: © S'_Mi? 5 Run # "S 

Fissd t?aga or,s~v~-P Sample sou lLto:,~ 

source 10 No: lo-ol.9~ FoTmr No:_______, 

~ lmpinger # 2 3 4 ~ 

. . 

~ 

CY.asatan1KlNole 

. 

,nP style 

;~~ ~..~ . .~~► ~ a~ 

Fina8 1pjt. 

/ d. 0 4"'~7 0 f 2D- 2 6y 

an"stea, M. 

~~-~ ~a . ~ s-, ~. 

®bfferance 

T®tal (Vtc) 

~l~P= 

v1c~ 

nt~= 

TS= 

Tre 

vMw= 

~~O bm 

mdw 

~aas

Y= 

MWC= 

~= 

Vs 

acfan 

dsofM 

EA 

sro HS® 

Caicaa9ations 

V,,,. = 0.04707(VO 

{i?.647}('ET6)(Pb~+~~al{Y~ 

~ ) 

(460+Tns) 

 

v

~ ¢ . 

~ Vm =sd) -~- gT. m) 

 xfll~fl /o 

Gd - 1 00-Bwa, 

#UId=- 0.44(°IocO2) fi- 0.32(°lcC32) + 0.2$(°JoN2 + %G:o) 

Ms = (Md3(Gd19 00)+(1 8)(Bws11 CO) 

ps (pta)} (Pa) 

(13.6) 

vs = ( I (MAO 

Cia (As)(Us) (acFm) 

{Q1M)Po}{17.64 Gd 

~ 100~ 

(Ta + 460) 

IC (Ts+ 460 )( V m (std )) 

I m ~ 

~ps X~)( ~-~ ° (~) 

Vep ddinw oflfquid CvlWcftd Egrams ormQ 

!!~ ~ QrymalsautarweJrt ofsample gas {ui/ffrnrole) 

l39aleoulsr€vaFgftP afmmpfe gm wet(thilb*mole} 

4&COp = F'emmt by valturra of CO2 fn Me gas stream 

q602 = Penaealsy volume of exygm In the gas sbearrl 

g6C0¢°.6Na c Perraent by vafrtrrm oF CO arzd IVQ in lbe gas 

Ga= Panehtafrfry8as by volus:e ln fhe ges shmm 

Bn = 96 by vcfirrne af watet tiawin the gas stresm 

P. m Absadrtte SBniW9 Q.48 pmsstFle {irlChes Qf Haj 

P&, = Beromeb"'~a pressm (fitefrBS ofHiV 

Pg= S'ample gss sWo Pmsaum (krclrss af N-,0) 

116 a Com/emfcn f8dar(btcfl83 F120/Tnahes of Hg} 

Cp s Pltat &ibe canstatrt 

KD ~ Ve{car7yMeSMrrs caefircfant {dlmsnsiaRlegsJ - 86.49 

HQ Cammrstan featvr (seafinir# 

RN, = Marooelarwefg3rtafsamyo g=, wer(fwlb-mcte) 

P. = Absoktte sempfe gas Fressm (Fnakss of hfg) 

Ta= Avemge sampls gast lbnrF$retuna (°F) 

V? = Sarnple gas v+slacityWtoo 

d► P= Amsgs squsra mots of valoaltyhssds cf gas (la 1410) 

4&g g CoAversfw aansteat {°F fb °i?) 

00 a VoGurraMa tlaKr Pate at acwal condlltorts (eofr») 

A Qo Ctam secffarttt/ eract ofsolupl'irtg loaetfvn t0 

V, - Sear#e gas velcc!!y (Wmfn) 

Q,w = Vot BOtiv taib et standatd cotsdiBa/:s. dry (dscf}r) 

K 3 0.09460 = corrstaat 

D„ n Avemge tG8lti8terafnoszb {!ej 

e = Totalaenipting time fraa# 
a aci6ity 4y/—f Job No: G. , ~

iZun No. ~_ Date:/Lto-5:- 

Source! I.D. No.Aw/•u S;~ 

Stack: Area in2( ) Dia (in) 

Operatom._ 

Meter Box #_2K Caiib. FactorM D• 

Nozzle 0 --- Diameter (D~_ ""' _ 

Pitot i.D. 4-0 . Cal1b.Factor(Cp)&.-22 

et. ~ Fie9d Data 

SahemaUa af Stack Cmss SeciJon 

~uN ~ 

Gas NoW ®ut / on 

Western Environrnenta! 8ervices and TestiRg, inc. 

K Factor 

Barometric pressure (P ~} 

Amb. ° ~ Assumed Moisture ° _______ 

Static Stack Pressure 'i•120 (+/ 0•2 Z 

~~ 

Probe Length l Matesia! f

I ~~ 

Before MWe A~ier 

1'itot Tubo Leak Checic 

initial Leaic @ "Hg =_ a- _,_ft3lMin 

Final Leak @ "Hg =&WiO ft3lmin 

1~~~~+r~Q~,~l 

r, ale~r-~~mm~~ ~al 

WA W,AWiMA mi ~~ 

MIrm~~~~~~~~M'.- ~ 

~~~~~~~~~~~ 

~o~ar~~avverame~v~~l~~ 

wm~~Mlt~~~~ 

UnconWed Vu_------ e 96CO2 3,2--_ °YoCO~ 8ample Furge: Ini#3a! Fouf 

Corrected 1!m ,,_ ft3 %02 %N2_____ Voiume Coilected Vi G, ml Sampie Time, 8min. 
Job 'N®a AX- ADO 5— Run # .22! 

Field ~~a~~r~.. Samp8e Box No:_ 

saurce BL4 No: Fi1Uer No: 

MpIngeor ?"F I ~ 3 4 ~ 

~ ~o~n~o~a 1,PtM-0 ~! D ly,C4. - 

~ '- 

~ T i~ ~~ygeo -4 ~ ~- ~ ° ~~! ~" o'•%~ v ' ~ 

lnvtiag Wt 790 _0 1 .5-ey-'7. SS:;v . 2- 

otw (Vtr.) 

XAc= 

AH= 

Ten 

Ti,= 

vmste 

olo M 

M6w 

Mw= 

vs 

acfrn 

dsGhn 

EA 

"!0 6 aO 

Cagculations 

tIb= tlolutne afL7qutd Co1/ed1Ed (gtarns ormi} 

Vv, c = 0.04"107(Vtc) R9a-D)lrrnalecularwelghtofsemplegas(6MPmcie) 

A9, s li9creaulerwelgfit ofssarplegsstfrsvetM/lbPmcle) 

(I? 64~~nexPEm -3-~ 

~ t7'~, = 

~'Q9 = P87C@Af 13y vQ1WJ7@ i?f L'Q2 Ir1 fNtB {~8s sii88nJ 

(460 +Tm) 

1 

°.dOt = PefCent by voluMe af axygen fn tha gas straarn 

%CO+46111a = Penaent by svlums of CO ertd AfP In the gas 

~vs = ~T"~ 7t1E00o~o 

Qd = Pancerrt of dry gss fiy valume t'n the ges sGream 

f ~1~ 

8,~, =°.6 bY valume af watartrarperirr ttis gas siream 

P= AI=satute sampls 9g,s grassure (Incfrs.s of l49) 

Cd = I L30-%a Pasr = t3alama#ric pressdsre (Inchas of Hg1 

Md= 0.44(°IoGO~) + 0.32(%a02) + {1.28(%N2 + °loGd3) Pg= Sampfe gas ststic prsssw+s (Inr,lies of¢1--3) 

116 = Comremian factor(lnchas HzUlhrcles oFHg) 

lWs •° (Mct)(Gd/9 OONI 8)($3vdl 00) Op = Riw fttbe constent 

_ ~g

) 

~s M } 

Ka x ~dYl~ressur,s co~i'ralrant(d"rnansiunlsss) = 85.49 

(13.6) 80 = ccrsywwvn factcr(secwr# 

LTS -~ 460) 

NJ, = NlolecrsJarwefghtofsomple ga% vyef (Ihllfrmole) 

PS = Absol~te samltle g$s presswe (hrch~ of Hg} 

~s ~ ~~P XOPX6~~~~ 

~MS ~~ps ~ 

T, = AYSrsge ssmple gas teneperatura (°17 

V. = Semple gss velocfiy(fbYsW) 

Qa =(As)(1/s) (acfn1) A P = Avarege squsre mats of trelacliy heads of gas (in FIaO) 

(Qa)(A 

 ~'d l ~SED = CollTfBlsfOA ColJstBnf {° c ti0 °R~ 

°)(17.64r /j TOO ffI QA= Yalumetrlc Haw rat$ at ectual cwdffians (aofi») 

(ra + 460) A m= Crass sacflan$1 staa of snmptfng locstiorr (fi2) 

lJs= SamFia gas velaclfy (ftJtnin) 

K (Ts+ 460 )

( v ) 

Qda = VoL 13aiv re!'e ot stamierri ccndldcn.% dty (dscfm) 

m (std ) I = ~c = O.1i89~0 w 

~ aanstant 

~ps ~~ S4 ~ ~ ~ ~ ~ fl ( D$~ Dn= Avarage dismeter of noala (R2) 

4 100 B= TnfsJ sempllirg tlma (mfn) 

~'' ~v ~ , ~/ ;4. ' •;i:. t ' ~ 4.~ ~~ S i 

w . 

. . , 

. . .~ AIAL. . . . 

K . •. ., . • 

,~ ~, s, ,' ~~ ~ ; ; ~,,, ~~ :_ t, :i~~ , 

, ~ ~• • ~ • s.:' ,~1!i:ia E~rL~~ 1:E'L'•i ~,~

-, 

, . . _.... , . . . . ._ . . . . . - s.._.__....... . ... .. ~... - --_. _ . .. :.... ._ _ ... .. ... .. .... _-..._ ------ - .._...... :rr 
Mstern gnvh.ronpntal SeMm and ToNno, Om 

F4f . ~► MI 

a paftao colbralon a 

r 

VMM Leak ~° ° tc---~.~,~~ ax„ 
~~~~ ~ ~ 05~ ~,_,~„~~1~~~~19` •, ~'g~l~- ~a 

woa 

A _ r f 

f~`_#f':7,j 1r `; f i d'~ ; ~ j,] 

N EA Nr~'~~ 

eve FUO 

~ • • • • • . 
A PF EN,,D...IX- C 

Com.pu'ter Diat'a Entry 
American Marazzi Tila Run Ceramlc Westem l:nvironmerital 

Sunn vale, Texas Main Stack 1,hethod 4 

Meti,od: 4 Statllc Pressure: -0.221n. M20 Meter No: 24 

For Mois4ure Barometric: 29.80 in. Ng M®tsr Correction Faator: 0.998 

Area: 5.37 sq.ft. Slllca Gef: 9.3grams Sample Box Na APFX 

TimelPoint: 5.0 min. Condensate: 68.5grrams Pitot Tutse Cp: 0.842 

Sample Tirne: 36.0 min. Tota! UIlt. 77.8grams Probe Tip Diameter 

Filtar No: 

DatslStaft Tirn$ 4114105 10:00 DatelStop i"ime 4!1 4105 10:35:00 °k CO2 3.2 

Pretest Leak Rate 0.000 cfm @ 15 in.Ng Posttest Leak Rate 0.000 cfm aQ 15 in.t-#g °!0 02 14.2 

Clack Dry Gas Pltot Actua! Stask Gas Meter TemA. ya. psr 

adhl Time Meter in. 24 ©H imp. {r etOutiet PQint 

A'12 10:00:00 412.453 0.16 1.60 420 87 87 3.80 

11 10:05:00 416.250 0.18 1.50 426 89 89 4.76 

10 10:1 0:00 421.010 0.19 1.50 428 89 89 4.23 

9 10:16:00 425.240 0.19 1.50 426 9i} 90 2.51 

8 10:20:00 427.750 0.18 1.50 428 so 90 4.00 

7 10:25:00 431.750 0.17 1.60 430 90 90 3.40 

6 10:30:00 435.150 0.14 1.50 433 90 90 4.12 

5 10:36:00 439.271 0.15 433 

4 0.1& 430 

3 0.15 428 

2 0.15 424 

1 0.13 418 

B 12 017 425 

11 0.18 424 

10 0.18 422 

9 0.19 422 

8 0.18 424 

7 0.17 425 

6 0.14 425 

5 0.11 425 

4 0.15 425 

3 0.15 425 . 

2 0.16 426 

1 0.15 424 

End 

1.500 426 89 26.818 
American Marazzi Tila Run 1 Porcelain HVestarn Bnvironmarial 

Sunnyvala, Texas Main Stack Method 4 

Method: 4 Static Pressure: -0.22 [n. H20 Meter Na: 24 

For Pariiculata Earcrmetric: 29.80 #n. -Hg Meter Correction Factor: 0.996 

Area: 5.37 sq.tt. Siiica Gal: 7.3grams Sampfa Box Pto: APEX 

Time/Polnt: 6.0 min. Condensate: 64.9grams Pitot Tuba Cp: 0.842 

Sample Time: 35.0 min. Totaf Wt. 72.2grams Probe Tip Diametcar 

Filter No: 

Date/Start Tlme 4/14/0512:15 Da#pJStop T'm 4/1410512:50,00 % CO2 3.0 

Pretest Leak Rate 0.000 cfm @ 151n.Hg Posttest Leak Rate 0.000 cfm @ 15 in.Hg °10 {72 14.4 

G'iack Dty Gaa Pitot Actuaf Stack Gas MsLK Tama. 1,~,a w 

E!~MA ~ r Metar in. H20 &H ci. {ntat OM EW 

A 12 12:16:00 439.608 0.16 1.50 429 90 90 3.79 

11 12:20:00 443.400 0.17 1.50 429 91 91 3.50 

10 12:25:00 446.900 0.19 1.50 433 91 91 3.80 

9 12:30:00 450.700 0.19 1.50 435 91 91 3.60 

8 12:35:00 454.300 0.18 1.50 439 92 92 3.52 

7 12:40:00 457.820 0.14 1.50 442 93 93 3.48 

6 12:45:00 461.300 0.16 1.50 444 94 94 3.66 

v 12:50:00 484.969 0.17 445 

4 0.15 444 

3 0.13 436 

2 0.12 428 

1 0.11 422 

B 12 0.18 426 

11 0.19 428 

10 0.19 430 

9 0.19 434 

8 0.18 437 

7 0.14 43$ 

6 0.17 440 

5 0.17 441 

4 0.14 441 

3 0.12 438 

2 0.13 435 

1 0.12 429 

Bnd 

1.500 435 92 25.353 
Arnerican Marazzi THe Run 2Porcelain Westem Cnviror+menia! 

Sunnyvafe, Texas Main Stack Meti:oai 4 

Method: 4 Stattc Pressure: -0.22 in. H20 Metsr No: 24 

For Particulate Barometric: 29.80 in. Hg Meter CorrBction Factor: 0.995 

Area: 5.37 sq.ft. Sifica Ge1: 3.3grams Sampig Box No: APEX 

TlmelPoint: 5.0 min. Condensate: 32.4grams Pi#ot Tube Cp: 0.842 

Sampie T'ur+e: 35.0 min. Totai Wt. 35.7grams Probe Tip Diameter 

Fiiter No: 

DatelStart Time 4l14/0513:35 DatelStop Ttme 411510514:10:00 °10 CO2 3.2 

Pretest 1.sak Rate 0.000 cfm aQ 18 in.Hg Posttest l.eak Rate 0.000 cfm @ 15 in.Hg % 42 14.4 

Ciock Dry Gas Pitot Actual Stack Gas iaf(eter Temp. Vol, oes 

aini Time Mgie_r in. O Aj Tettip. mm 99t at Point 

A 12 13:35:00 485.175 0.23 1.50 410 95 95 3.83 

1'E 13:40:00 468.800 0.24 1.50 420 95 98 3.62 

10 13:45:00 472.420 0.24 1.50 422 95 95 3.62 

9 13:60:00 476.040 0.24 'i.SO 425 95 95 3.51 

8 1 3:55:00 479.550 0.23 1.50 428 96 98 3.62 

7 14:00:00 483.170 0.12 1.50 432 96 88 4.13 

6 14:05:00 ' 487.300 0.19 1.50 435 97 97 3.03 

5 14:10:00 490.333 0.20 438 

4 0.17 435 

3 0.16 431 

2 0.13 410 

1 0.12 395 

B 12 0.21 420 

11 0.22 421 

10 0.22 423 

9 0.29 426 

8 0.20 430 

7 0.13 434 

5 0.18 437 

5 0.18 438 

4 0.18 438 

3 0.17 437 

2 0.15 414 

1 0.15 411 

End 

1.600 425 96 25.158 
;4mericaii Marazzi Tile Run 3Porcelain VllGstem Environmental 

Sunn als, Texas Main S#as~c Method 4 

Method: 4 Static PreSsure: -0.22 In. H20 Meter Ho: 24 

For Particulat® Barametric: 29.80 in. Hg Meter Carrectian Pactor: 0.996 

Area: 5.37 sqft Silir.a Gaf: 7.4grams Sampi$ Box Na: APEX 

TirneiPoint: 5.0 min. Condensate: 53.2grams Pitot Tuba Cp: 0.842 

Sample Time: 35.0 min. Total Wt. 60.6grams Proba Tip Djarneter 

Fliter No: 

DatelStart The 4J14/0514:40 f)ate/Stop 7ime 4115105 15:15:00 °:o CO2 3.2 

Prete.st Leak Rate 0.000 afm @ 15 in.Hg Posttest Lea4c Ra#e 0.000 cfm Q 151n.l+ig % 02 14.2 

Cbek ary Gas Pitot Actaa! Stack Gas fi~stc~r Tema. i. ar 

Pain T'fne Meter (In U20) AH-_ Tema. Inlet Qutlat ain 

A 12 14:40:00 490.600 0.22 1.50 423 96 98 3.85 

11 14:45:00 494.450 0.23 1.50 427 97 97 3.31 

10 14:50:00 497.760 0.24 1.50 430 98 98 3.66 

9 14:55:00 501.420 0.24 1.50 435 98 98 3.49 

8 15:00:00 504.910 0.23 1.50 438 98 98 3.41 

7 15:05:00 608.320 0.12 1.60 438 99 99 3.52 

6 1 5:10:00 511.840 0.17 1.50 437 99 99 3.49 

5 15:15:00 515.327 0.20 438 

4 0.16 435 

3 0.14 431 

2 0.13 424 

1 0.12 419 

B 12 0.20 428 

11 0.21 431 

10 0.21 435 

9 0.20 437 

8 0.20 437 

7 0.14 436 

6 0.17 438 

5 0.18 435 

4 0.17 435 

3 0.16 429 

2 0.14 421 

11 0.13 417 

End 

1.500 431 98 24.727 
` . .~~~ ~ ~ .S'LI;~s~~ 1 ~~ • - ~ , . 

. , .. ~~ . ' . ~ . ~ . 

t~~~k~~r~~~~~~~_~~~s~~ 

. ~ . 

Ceramic Main Stack 

TamEstamp HCL MF 

419412005 1.0:'! 't 9.946 30.542 

4/1412005 10: 16 8.911 2+E.294 

411 412005 1 0:2 7 8.643 26.208 

4114f200510:26 8.520 25.504 

411412005 1 0:32 9.093 26.230 

4!1 412005 9 0:37 '1 0.270 29.244 

4!14/2005 1 0:42 '10.203 29_293 

411 412005 1 0:47 11.133 31.087 

4114J2005 1 0: 52 11. 51 0 31.377 

411412005 1 0:57 1 0.550 29.461 

4/1 4I2005 1 1 :'14 11 .060 20.684 

.1Avera9es T/sWIS I'7d81 I 

Rasn 1 Poeceiaen Meaav Stack 

rosasstamp HCL MF 

4/14/200512:18 25.079 54.957 

4114/200512:23 25.290 58.040 

4/14l200512:28 24.621 57.369 

4/14/200512:33 24.586 56.974 

4/14/200512:38 27.163 62.470 

4/14/2005 12:43 25.766 59.035 

4/14/200512:43 33.887 67.940 

4/14/200512:54 31.951 66.468 

4194/200512:59 27.705 62.952 

4/1 412005 13:04 27.456 63.476 

4114/200513:09 30.600 67.648 

.4/141200513:14 35.894 72.196 

Average 28.333 62,452 

Run 2 P®rceiain 

3imestramp HCL HF 

4/141200513:29 18.20758 37.73916 

4/141200513:34 11.5062 35.38136 

4114/2005 13:39 16.36104 46.52527 

41141200513:44 13.20118 48.66049 

41141200513:49 20.30849 47.15999 

4/14/2005 '! 3:54 25.73835 56.35747 

41141200513:59 25.16755 55.32917 

4/14/200514:04 26.31197 55.89006 

4/14/2005 14:09 26.73735 56.80736 

4/141200514:14 28.86682 59.42829 

4/14/200514:20 27.18558 58.65652 

41141200514:25 31.47818 65.23201 

4/14/200514:30 48.05984 85.5748 

4/14/200514:35 32.58806 58.3003 

Aveirage 28.91704 57.82681 

Run 3 Porceiaeea 

'i'imeStamp B-iCL HF 

4/14/200514:40 23.91718 50.18526 

4/141200514:45 23.80354 54.12422 

4/14/200514:50 24.70584 57.97817 

411412005 14:56 26.'i 8465 60.54983 

4/141200515:00 30.72614 65.77795 

4/141200515:05 27.35456 60.3729 

4/141200515:10 27.87803 60.06103 

4114/200515:15 29.6814 60.84264 

4/141200515:20 29.83673 59.48223 

419 4/2005 1 5:25 27.43583 55.361 

411 412005 15:31 31.86564 59.64195 

411412005 15: 36 31.1 C862 61. 92034 

A►verage 27.97984 58.86813 
Llne Lcss Evegul-asgon 

Client AMT 

t.ocaftn: Synnyvaie. xas 

Soume: K31n 9 Ugin S#sck 

$ivilCe Gas: Hydrogen Chloride 

iDate: 4'i-4/2Q05 

Vi'ime Start: 1 , i:24:00 

Acro8ein 

Spike I tpike 2 Spike 3 

Time iD 11:51 Time ID 11:55 Time iD 'i 1:59 

SF6 Direct 4.60 SF6 Direct 4.60 SF6 Direct 4.60 

SF6 Measured 0.61 SFQ iUleasured 0.41 SF6 I#lleasured 0.62 

DifuSon Factor 7.54 Dituffon Factor 11.22 Dilufion Factor 7.42 

HCI Baseline 9.98 HCi Baseiine 9.98 HCI Baseiine 9.98 

HCI Cyi 201.40 HCI Cyl 201.40 HCI Cyi 201.40 

HCI Measured 37.20 HCI Nleasured 30.13 i-iCl Alteasured 34.90 

HCI Predicted 38.69 HCI Predicted 27.93 HCI Predicted 37.13 

HCi Over 47.69 hiC! Qver 36.31 HCI flver 48.26 

HCI Under 25.68 HCI Under 19.55 MCI Under 25.99 

%Recovery 98.62 92.70 106.38 

Avg. Recovery 99.23 
Coyffind®r EvaBuadon 

# pathlangth 1 8.95 

# raethod(s) L:1I%AcMACME3.mefhcsd 

TimeEtamp SF6 HCL 

04.92.05 1D:51:14 4.59228 198.333 

04.12.05 9tt:53:14 4.6086 203.468 

Avg 4.60044 201.4E105 
Un@ L®ss EvaluaUon 

Gas: Hydrogen Chloride 

Yimes4amp SFG MCL 

4114/20051 1:5'I 0.509555 37.15035 

4/1412005 11:53 0.373187 33.05359 

411 4f2Q05 1 9:55 t3.4'! 5449 30. 12529 

411 412005 91:57 0.54't491 33.01 028 

.4114/2005 1 1:59 0.61952 34.88f43 

4/14/2005 9 2:0 1 0.61 3829 38.1741 
5,21 

0.52 

10.02 

45.00 

113.57 

54.74 

66.34 

73.24 

39.43 

Pass 

spike 3 

SF6 Direct 5.21 

SF6 Nleasured 0.52 

Dilution Facfor 10.02 

HC! Baseline 45.00 

1'RRCi Cyl 113.57 

HCl Measured 49.17 

HC) Predicted 56.34 

HCI Qver 73.24 

NC! Under 39.43 

Pass 

spike 2 

SF6 d3irect 

SF6 Measured 

Ditution Factor 

HC{ Caseline 

HCl Cyl 

HCI Measured 

#-iCl Predicted 

HCI Over 

HCl Under 

Date 10127303 

spike'i 

SFG DEreci; 5.21 

SF6 Measured 0.52 

Diiuflon Factor 10.02 

HCI Basefine 45.00 

1•1Ci Cyl 113.57 

HC1 Measured 50.45 

HCi Predicifed 56.34 

HCl 4ver 73.24 

l:-iCl Under 39.43 

Pass 
Date 10I2812003 

spike1 spike 2 spike 3 

SF6 Direct 5.21 SF6 Direct 5.21 S176 Direcf 5.21 

SF6 Measured 0.49 S176 Measured 0.49 SF6 Measured 0.49 

Diiution Factor 10.63265 Di#ution Factor 10.6326531 Dilution Factor 10.83265 

(-tC! Basetine 5.595 i-ICI Basetine 5.815 HCl Baseline 5.71 

HCI Cy1 113.57 HCI Cyl 113.57 HC1 Cyl 113.57 

HCI Measured 1 18.2 HCI Measured 18.92 HCI Measured 19.3 

HCI Predscted 16.27625 HC1 Predicted 16.4962476 HCI Predicted 16.39125 

HCi Over 21.15912 HCi Over 21.4451219 HCI Over 21.30862 

HCt Under 11.39337 HCI Under 11.5473733 HCI Under 11.47387 

Pass Pass Pass 

aci dl ow 

imacc Quant method : 

- ---~ 

fi 1 ename = C:\l\Acid\Aci dl ow . method 

Shift znformation: 

sh i ft-reference = C:\IMACC\ACME\3 . 8%H2O. spa 

start = 3158 

stap = 3270 

;naxdel a = 5 

3nterpoTate-count = 5 

shi ft-count = 5 

Quant informati on : 

di gi t--tol erance = 3 

data-s-rze-tolerance = 5 

use-dynamic-references = true 

use-bias = true 

use- radi ance = •Fa7 se 

report-zero = fal se 

References : 

~ set-fi 1 Qna.me ; 

Co, c:\zmACc\method\CO-150.spa 

CO2, C:\YMACC\Method\CO2-8%-68m.SPA 

N2CO 3 Co\IMACC~AC~IE\H2C0-50.spa 

H2O , C:\I\ACI d\H20-20k-0.9icm-1.SPA 

F~ CL, c:\I\meedfulThi ngs\R.EF185\SERIES\HCL_500ppb. spa 

HF, C: \1\Needful Thin s\REF185\SERIES\HF1.5ppm.spa 

MH3 , C:\IMACC\vtethoPg NH3_185 .185 

SF6 1 C:\IMACCy~tethod\s 6_76.185 

S02, C:\ImACC\ACME\502_896.185 

code shortname pres(Torr) temp(C) conc(ppm) pathlength(rn) 

____ ~~-~~•~•~-~ ~. ~.-~~~~~~----_~_--~~~-~----~•-~~:.~..~~ 

~ Co c0-150 760 185 150 10 

CO2 CO2-69o-68m 755 185 60000 68.5 

H2C0 H2C0-50 760 185 50 10 

H20 H2O-20k-0.94cm-1 700 185 20000 9 

NCL HCL...500ppb 650 185 0.5 25.5 

HF HF1.5ppm 650 185 1.5 25.1 

NH3 NH3_185 650 185 54.3 3.4 

SF6 sf6_76 755 185 20 3.8 

So2 S02_..896 765 185 SS 10.5 

Regions: 

start stop seport interference 

_--________ ---•-~~~-.•-r 

86 6. 2- 

-=.~~~~~~~~=~~~~~~~~~~..;. 

993.7 NH3 - CO2 , H2O, S F6 

923 . 6-- 1097.9 CO2 - H20, NH3, SF6, S02 

930 -- 952.8 SF6 - CO2 1 H2O 9 NH3 

2092.2 - 2210.8 co - CO2 1 H2O 

2092.4 - 2201.8 H2CO - CO2,H2O 

2462.2 - 2528.6 S02 - Co2,H2O 

2673.2 - 2848.2 HCL - H20 

3172.7 - 3331.5 m2o -, 

3999.6 - 4285.1 HF - H20 

Region ( 866.2 - 993.7 ): 

wa ndows ; 

Page 1 
acidiow 

866.2 - 869.5 

923,3 - 936.2 

961.3 - 969.5 

990.9 - 993.7 

report-compounds = WH3 

i nterference-compounds = CO2, H20, SFF 

Li neari ty ; 

name = NH3 

flrder = 2 

f os^ce-zero = true 

mi ni mi ze-percent-error = fai se 

dynamic-reference = true 

use-dyanami c = fal se 

use-7 i neari ty = fa 1 se 

use-shi ft = fal se 

coefficents = 0.845185 9 0.0001.85922 

setname = NH3 

tteferences: 

set-fi 1 ena:ne = C: \gMACC\Method\nh3 . set 

MH3, C:\IMACC\Method\NH3OlOa2a.SPA 

, C:\IMACC\Method\NH3O1Oa2.sPA 

, C:\?MACC\Method\NH3020a2a.SPA 

, C:\YMACC\Method\NH3020a2pSPA 

, C: \iNtACC\method\HH3000a2 . SPA 

, C: \I~ CC\Method\HH3430a2 o SPA 

f~D~3 , C:\IMACC\Method\NH3O4Oa2.spA 

, C: \ImACC\Method\MH3050a2 . SPA 

code shortname pres(Torr) temp(C) conc(ppm) path7ength(m) 

WH3 NH3010a2a 761 185 11 26 

MH3010a2 761 185 11 26 

NH3020a2a 761 185 22 26 

MH3020a2 761 185 22 26 

MH3000a2 762 185 33 26 

NH3030a2 762 185 33 26 

NH3 NH3040a2 762 185 55 26 

NH3050a2 762 185 110 26 

Regi on { 923.6 - 1097.9 ) : 

wi ndows ; 

923.6 - 1097.9 

report-compounds = CO2 

i nte rference-compounds = H20, A9W3 , SF6, S02 

Li neari ty: 

name = CO2 

order = 2 

force-zero = true 

m-inimize-percent-error = faise 

dynamic-reference = true 

use-dyanami c = fal se 

use-1 i neari ty = fal se 

use-shi ft = fal se 

coeffi cents = 0, 529252 ,1. 23.205e-007 

setname = CO2 

References : 

set-filename = C:\zMACC\Method\coZlow.set 

CO2, Cp\IMACC\Method\CU2-IO.spa 

Page 2 
aci dl ow 

CO2, c:\aMACC\method\CO2-20.spa 

CO2 1C:\IMACC\Method\CO2-SO.spa 

Co2, C :\IMACC\Method\CO2 -100.spa 

CO2, C:\YMACC\Method\CO2-150.spa 

CO2, C: \IMACC\Niethod\CO2-200. spa 

CO2, C:\Z ~G4CC\Method\CO2-300.spa 

CO2, C:\1twACC\Method\co2-500.spa 

CQ2 , c:\imAcc\method\cO2_1k.sPa 

cade shortname pres(zorr) temp(C) conc(ppm) pathlengt+h(m) 

~-^ CO2 CO2-10 760 185 10 10 

CO2 CO2 - 20 760 18 5 20 10 

CO2 CO2-50 760 185 50 10 

CO2 CO2-100 760 185 100 10 

CO2 CO2-150 760 185 150 10 

CO2 CO2-200 760 18s 200 10 

CO2 CO2-300 760 i8S 300 10 

CO2 co2-500 760 185 S40 10 

CO2 CO2_1k 760 185 1000 10 

Region ( 930 - 952.8 ): 

wi ndows ; 

930 - 952.8 

report-compounds = SF6 

# nterferenEe-compounds = CO2 , H2o, Nw3 

Li neari ty : 

name a S F6 

order = 0 

force-zero = true 

mi ni mi ze-percent-error a fal se 

dynami+c-reference = false 

use-dxahamic = false 

use-1 inear ity ~ fal se 

use-shi ft = Fal se 

coeffi cents = 

setname = SF6 

References: 

set-fi l ename = 

Region ( 2092 

bti ndows ; 

2092.25 

2118.11 

2143.43 

2164.77 

2188.97 

.25 - 2210.8 ) : 

- 2112.81 

- 2133.39 

- 2159.99 

- 2184.42 

- 2210.8 

report-compounds 3 Co 

i nterference-compounds = CO2, H20 

Li neari ty: 

name = CO 

order = 5 

force-zero = true 

mi nimi ze-percent-er ror = t rue 

dynami c-reference = true 

use--dXanami c = fal se 

use-1 i neari ty = fal se 

Page 3 
aci dl ow 

use-shi ft - fa7 se 

coefficents = 0.55085,0.000130645,1.53981e-007,-2.92281e-011,2.07788e-03.5 

setname = Co 

References : 

sst-f-i i ename = 

Co, C:\IMACe\Method\CO-5.spa 

Co, c:\IMACC\Method\c0-850.spa 

co, C:\IMACC\Method\co-750.spA 

Co, C:\2MACC\Method\Co-650.spa 

Co, C:\?MACC\Method\CO-600.spa 

Co, C:\iMACC\Method\Co-500.spa 

CO , C : \Ii4ACC\Method\CO- 50 , spa 

CO 3 C:\iMACC\Method\CC1-9SO.spa 

Co, C:\IMACC\Method\CO-1.spa 

CO 3 C:\2MACC\Method\CO-40.spa 

CO 3 C:\iMACC\Method\Co-300.spa 

CO 3C:\I;~IACC\P~9ethod\CO-30. spa 

C0 9 C : \aMACC\Method\CO-200 . spa 

Co, C:\IMACE\Method\Co-20.spa 

Co, C:\IMACC\Method\CO-3.SOO.spa 

Cc3, C:\IMACC\Method\CO-150.spa 

Co, C:\3MACC\Method\co-100.spa 

co, cevMACC\Method\co-10.spa 

CO 3 C:\3MACC\Method\CO-400.spa 

code shortname pres(Tora^) temp(C) conc(ppm) path3ength(m) 

Co CO-5 760 185 5 Zo 

Co c0-850 760 185 850 10 

Co Co-750 760 185 750 10 

co C©-650 760 185 650 10 

Co Ca-600 760 185 600 10 

CO Co-S00 760 185 500 10 

Co CO-50 760 185 50 10 

co CO-950 760 185 950 10 

Co co-1 760 185 1 10 

Go CO-40 760 185 40 10 

co Co-300 760 185 300 10 

Co CO-30 760 185 30 10 

co CO-200 760 185 200 10 

Co CO-20 760 185 .20 10 

Co CO-1500 760 185 1500 10 

c0 CO-150 760 185 150 10 

CO co-100 760 185 100 10 

co co-10 760 185 10 10 

CO CO-400 760 i85 400 10 

Regi on ( 2092.36 - 2201. 78 ): 

vgindaws; 

2092.36 - 2112.99 

2118.14 - 2134.06 

2167.92 - 2201.78 

report-compounds = H2C0 

i nterference-compounds = CO2 , H2Q 

L i neari ty : 

name = H2Co 

order = 4 

force-zero = faise 

mi ni m-t ze-percent-e r ror = fal se 

dynamic-reference s fa7se 

Page 4 
aci di ow 

use-dy anam-~ c= fal se 

use-1 

, 

~ nearz ty = fal se 

use-shi ft = fial se 

coef¢i cents = 0, 0, 0, 0, 0 

setname = H2C0 

References: 

set-fi 1 ename = 

tZegi on ( 2462.15 - 2528.55 a 

ttd7 Yldows ; 

. 2462.15 " 2528.55 

repart-compounds = S02 

interference-compounds = CO2,H2O 

Li neari ty: 

name S02 

order = 4 

force-zero = false 

mi ni m-i ze-percent-error = fal se 

dynami c- reference = fal se 

use-dyanamic = faise 

use-1 i neari ty fal se 

use-shi ft ~ fal se 

coeffi cents = 0, 0, 0, 0, 0 

setname = S02 

References : 

set-fi 1 ename = 

Regi on ( 2673.15 - 2848.18 ) ; 

windows; 

2673.15 - 2848.18 

report-compounds = HCL 

interference-Compounds = H20 

Linearity: 

name = HCL 

order = 3 

force-zero = true 

minimize-percent-error = true 

dynamic-reference = true 

use-dxanasrri c = fal se 

use-1 i neRr-1 ty = fai se 

use-shi ft m fal se 

coefficents = 1.03621 9 0.000234244,8.21206e-007 

setname = HCL 

References: 

set-filename = C:\IMa CC\Method\hcllow.set 

HCL, C:\1\NeedfulThings\REF185\SERIES\HCL-50ppb_185C.spc 

tiCL, C:\1\Needful Things\REF185\SERIES\HCl _100ppb .sa 

HCL, C:\1\NeedfuiThings\REF185\SERIES\HCL_.200ppb_1 5C.spc 

HCL, C:\l\Needful Thi ngs\REF185\SERIES\HG.....500ppb_185C. spc 

HCL, C:\1\NeedfulThings\REF185\SERIES\HC1.-750ppb.spa 

HCL, Cp\1\Needful ~'hings\REF~,85\SERZES\HCL_1250ppb_185C.spc 

HCL, C: \1\Needfu7 Thi ngs\REF185\SERZES\HCl 3.ppm. s pa 

HCL, C:\1\NeedfulThings\REF185\SERIES\HCL.1ppm_185C.spc 

HCL, C:\1\l~eedful Things\REF18S\SERIES\hcl-.6.5_20m.185 

HCL, C:\1\NeedfulThings\REF185\SERIES\HC1 Sppm.spa 

HCL, C:\1\NeedfulThings\REF185\SERIES\HC1 10ppm.spa 

HCL, C:\1\NeedfulThings\REF185\SERIES\HC1 25ppm.spa 

Page 5 
aci dl ow 

code shortname pres(Torr) temp(C) comt(pprn) path'I ength (m) 

HCL HCL_54ppb_185C 650 185 0.05 25.5 

HCL HCi _,3.00ppb 650 185 0.1 25.5 

HCL HCL_200ppb_185C 650 185 0.2 25.5 

HCL 'HCL_500ppb_185C 650 185 0.5 25.5 

HCL HCi_750ppb 650 25.5 0.75 25.5 

HCL HCL_1250ppb_185C 650 1.85 1.25 25.5 

l-~ CL s HCl ~.ppm 760 185 1. 7 32 

HCL ,~Ct.-.2pp~t..l85C 650 185 2 7 5.5 

HCL hc ~t_6.5-.20m 689 185 6.5 _0.9 

;tCL kiCl Sppm 760 385 5 32 

I-iCL HCI lOppm 760 185 10 32 

HCL HCi 25ppm 760 185 25 32 

Zegion ( 3172.7 - 3331.5 ) : 

wi ndo6Vs ; 

3172.7 - 3331.5 

report-compounds = H20 

znterference-compounds = 

Linearity: 

name = H20 

order 3 

farce-zero = true 

m-inimize-percent-error = true 

dynamic-reference = true 

use-dyanami c fal se 

use-1 i neari ty = fal se 

use-shift = false 

coefficents = 0.97062 y 1.S629e-006,-6.23876e-013 

setname = H20 

t4efe rences : 

set-fi3ename = C:\ztwACC\twethod\h20.set 

H2O, C:\1\Acid\H2O-20k-0.94cm-3..5PA 

H2O, C: \1\Aci d\H2O-40k-0. 94cm-1. SPA 

H2O, C:\1\AcId\H20-60k-.94cm-I.SPA 

H2o, C: \3\Aci d\H2o-90k- .94cm-1. SPA 

H2O, c:\1\Acid\H20-11Ok-0.94cm-1.SPA 

H20, C:\1\ACid\H20-125k-0.94cm-1 .SPA 

code shortname pres(Torr) temp(C) conc(ppm) pathlength (m) 

H20 H20-20k-0.94cm-1 700 185 20000 9 

H20 H2O-40k-0.94cm-1 700 185 44000 9 

H20 H2O-60k-.94cm-1 700 185 60000 9 

H20 H2O-90k-.94cm-1 700 18S 90000 9 

H20 H2O-110Gc-0.94cm-3. 700 1$5 1.1e+005 

H20 H2O-125k-0.94cm-1 700 185 1.25e+005 

Regi on ( 3999.64 

wi ndows ; 

4037.69 - 

4072.18 - 

4108.56 - 

4173.49 - 

4201.68 - 

4228.58 - 

4254.23 - 

- 4285.13 ): 

4040.98 

4077.82 

4111.29 

4175.17 

4205.65 

4232.72 

4258.37 

Page 6 
aci dl ow 

repart--compounds = HF 

i nterference-compounds = H2o 

Li neari ty: 

narne = HF 

order = 3 

forc4--zero = true 

m-i ni mi ze--percent-error = fai se 

dynami c-reference = true 

use-dyanam-i c = fal se 

use-7 i neari ty = fal se 

use-shift = false 

coefficents = ©.900098,0.00236984, 7, 53245e-4306 

setname = HF 

References c 

set-fiienarne = o:\IMACC\Method\HF.set 

NF 4 C:\1\NeedfulThings\REf185\SEttIES\HF100p b.spa 

HF, C: \I\NeedfulThings\REF185\sERIES\HFSO p ~ .spa 

HF,C:\I\NeedfulThi ngs\REF185\SERYES\HFI.. ~ppm. spa 

code shortname pres(Torr) temp(f) conc(ppm) path7ength(rn) 

HF HF100ppb 650 185 0.1 25.1 

HF HF50ppb 650 185 0.05 25.1 

HF HF1.5ppm 650 185 1.5 25.1 

Bi as : 

r=_`^" 

~ ... ~.~ 

Page 7 
aci d 

Imacc Quant method t 

fi'3 ertame = C:\1\Acid\Acid.method 

Shi ft Informati on : 

shi ft-reference C:\I\oldomn! c\H2o_5C3k. spa 

start 3158 

stop 3270 

maxdel a 

-~ 

= 5 

nte ~^po~ate-count = S 

shi ft-count = 5 

Quant Informati on R 

da gi t-tol e rance = 3 

data-size-toierance = 5 

use--dynamzc-referen+ces true 

use-bi as = t.rue 

use-radi ance = fal se 

report-zero - fal 5e 

References: 

~.~_ 

 -....w.... 

set-f i l enam,e ~ 

Co, C: \IMACC\Method\CU-3.5[1. s a 

co2 , C. ~,S~t~4Ce\MethodlCoa-6%-6~itl. SP'A 

H2eo, e:\i\EthanolScraabberlH2CO_std--4--10m.spa 

"2cD, c:\l\old omn1 c\H2o_SUHc. spa 

HCL, C:\1\Spectra\REF185\NCL_136.185 

HF, C.\I\Spectra\Misc\oMNIC\HF--so-o.94cm-I.SPA 

NN3 , C:\1\spectva\REF185\NH3_185.185 

sF6, C:\1\Spectra\REF185\SF6_76.185 

So2 , C°. \l\Spectra\REF38S\SO2_896. 18a 

code shortname p res(Torr) temp(C) conc (ppm) pathlength(m) 

co cpo~/-3,~+..5o 760 185~.r ~. 150 

~- 

~.0 

.r~/2 C©2-'`✓/V-V8m 75 5 ~.SJ V0oQ4 6$.5 

H2CO H2co_std--4--10m 754 l8s 4.2 10.1 

M20 Qow50k 760 18 S 50000 10 

HCL HCL~..136 689 i85 6.5 20.9 

HF HF-10-0 a 94cm-1 700 i8,5 10 9 

iNJH3 wH3-185 650 185 54.3 3.4 

SF6 SF6_76 755 185 20 398 

S02 S02_896 765 185 85 10.5 

Regi ans o 

_~-----~~ 

start stop report interference 

866.2 - 

__w~~w __M ~wY_rrwrw►r~rw+wY ~ti 

993.7 

Y-~~riCSi 

NH3 

~~i~w«w~Y.~~ Y~~i~~ 

" Co2 4 H20, SF6 

923.6 - ~,i397. 9 co2 - m 2o, mH 3 p SF6, S02 

930 -- 952.8 SF6 - Co2,H2o,Nii3 

2Q92.2 - 223.0.8 co - ~o2, H20 

2092. 4 !' '"' 

~'q 

G2o1. 8 H2.aV - L02 g H20 

2462.2 - 2528.6 So2 - CO2 9 0~~20 

2673.2 3 - 2848.2 H4L - f'b20 

3172 .7 - 3331.5 H20 -- 

4067.3 -- 4285.1 HF - H20 

Ptegi on ( 866.2 - 993.7 ~ n 

{rii ndows ; 

Page I 
aci d 

866.2 -- 869.5 

923.3 - 936.2 

961.3 - 969.5 

990.9 - 993.7 

report-compounds = NH3 

i nterference-compounda = CO2, H2O, 5F6 

L-a neari ty a 

narne = MH3 

order = 2 

force-zero = true 

m-i ni m-i ze-percent-error = fa3 se 

dynamic-reference = true 

use-dyanami c = i=a1 se 

use-7 i near-i ty = fal se 

use-shi ft = fal se 

caei"fi cents = 0. 839627, 0. 0at1183653 

setname = MH3 

References: 

set-fi 1 ersaine = Co\ImqCC\ ethod\nh3 . set 

W , C:\IMACC\Method\mH3O1Oa2a.SPA 

, C: \IMACC\iyte t hod\mH3t310a2 . SPA 

, C: \IMACC\Method\NW3020a2a. SPA 

, C: \IMACC\Method\NH302aa2 . SPA 

, C: \IMACC\Method\NH3000a2 a 5PA 

, C.\xmACC\method\Nm3030a2.sPA 

, C:\IMACC\Method\NH3040a2.5PA 

, c:\iMAcc\method\mH3O5Oa2.SPA 

code shortname pres(Torr) temp(C) conc(ppm) pathlength(m) 

MH3 HH3010a2a 761 185 11 26 

N"3010a2 761 i8s 11 26 

NH3020a2a 761 185 .22 26 

NH3020a2 761 185 22 26 

MO000a2 762 185 33 26 

NH3030a2 762 i8S 33 26 

NH3040a2 762 185 55 26 

NH3050a2 762 iSS 110 26 

Region ( 923.6 - 1097.9 

tvi ndows ; 

923.6 - 1097.9 

report-compounds =. CO2 

i nterference-compounds = H20, NH3, SF6, 502 

L-i neari ty: 

name = CO2 

order 2 

force-zer°o = traae 

mi ni mi ze-percent-error =fal se 

dynamic-reference = true 

use-dyanamic = false 

use-1 i neari ty = fal se 

use--shi ft = fal se 

coeffi cents - 

setttame = CO2 

References : 

set-fi l ename w Cp \gmAcC\metho+dl,co2low. set 

CO2 p = o \IMACC\Method\CO2-I0 . spa 

Fage 2 
aci d 

t02 9C:\1MACC\Method\CO2-20.spa 

CO2 , C:\1MAtC\method\CO2-50.spa 

CO2, C:\xNlACC\Method\CO2-100.spa 

CO2, C:\1MACC\Method\CO2-150.spa 

CO2, C:\IMACC\Method\CO2-200.spa 

Co2, C:\1MACC1Meth0d\Co2-30O.spa 

CO2, C:\1MACC\Nlethed\co2-500.spa 

CO2, C:\1MACC\Method\e02_1kAspa 

code shortname pres(Torr) temp(C) conc(ppm) pathlength(m) 

c02 r.02-10 760 185 10 10 

CO2 CO2- 20 760 185 20 10 

c02 CO2-50 760 185 50 10 

Co2 CO2-100 760 185 100 10 

Caz CO2-150 760 l85 ISO 10 

CO2 CO2-200 760 185 200 10 

CO2 CO2- 3(30 760 185 300 10 

CO2 c02--50O 760 185 500 10 

CO2 CO2_1k 760 185 1000 10 

Region ( 930 - 952.3 ): 

idi ndows ; 

930 - 952.8 

repvrt-compounds = SF6 

i nterference-campounds = CO2, H20, NH3 

L3 neari ty : 

name = 5F6 

order = 0 

force-zero M true 

m i ni mi ze-percent-error = fal se 

dynamic-reference = fa7se 

use-dyanami c = fal se 

use-i v neari ty = fal se 

use-shift = false 

coeffi cents = 

setname = SF6 

References: 

set-filename = 

Region ( 2092 

wi ndows ; 

2092Q .2 5 

211 ~7 .11 

2143.43 

2164.77 

2188.97 

.25 - 2210.8 ) : 

- 2112.81 

- 2133.39 

- 2159.99 

- 2184.42 

- 2210.8 

report-compounds = co 

interferente-compounds = CO2,H20 

Li neari ty: 

name CO 

order = 5 

force-zero = true 

minimize-percent-error = true 

dynamic--reference = true 

use-dyanami c = fal se 

use-1 i nearity fal se 

Page 3 
aci d 

use-shift = false 

coeffi cents = 

setname = CO 

References: 

set-fi 1 ename = 

c0, C4\IMACC\Method\Co-5.spa 

Ca, Co\IMACC\Method\CO-850.spa 

co, C:\iMACC\Method\co-750.spA 

co, C: \IMACC\Metod\CO-650.spa 

c®, ca\IMACC\Method\CO-600.spa 

cLl, C:\IMACC\Method\Co-500. spa 

c.o, c:\imACC\Method\c4-50.spa 

co, C:\ ~rMACC\Method\Ca-950.spa 

CO, C:\IMACC\Method\CO-1.spa 

Co, C:\IMACC\Nethod\CO-40.spa 

Ca, Ce\IMACC\Method\CO-300.spa 

CO, . C.\IMACC\Method\CO-30. spa 

ca, co\xmACC\Method\CO-200.spa 

co, C:\iMAcc\Method\CO-20.spa 

c0, C:\IMAEC\Method\CO-1S00.spa 

CO 3 C:\IMACC\Method\CO-150.spa 

CO, C:\IMACC\Method\co-3.00.spa 

co, C:\xMAc[\method\Co-IO.spa 

Ctf, C:\IMACC\Method\Co-400.spa 

code shortname pres(Torr) temp(C) conc(pprn) pathlength(m) 

c0 co- 5 76+0 185 5 10 

Co C0-850 760 385 850 10 

Co CO-750 760 185 750 10 

co CO-650 760 185 €50 10 

Co CO-600 760 185 600 10 

Co CO-500 760 185 500 10 

c0 co- SO 760 185 50 10 

co CO-950 760 185 950 10 

Cfl c0-i 760 185 1 10 

co CO-40 760 185 40 10 

co C®-300 760 185 300 10 

co Co-30 760 185 30 10 

Co Co-200 760 185 200 10 

c© Co-20 760 185 20 10 

co CO-1500 760 185 1500 10 

co c0-150 760 185 150 10 

C© co-100 760 185 100 10 

c0 c4-10 760 185 10 10 

co CO-400 760 185 400 10 

rtegion ( 2092.36 - 2201.78 }: 

ndaws ; 

2092.36 - 2112.99 

2118.14 - 2134.06 

2167.92 - 2201.78 

report-compounds = H2Co 

interference-compounds s CO2,N20 

Li neari ty o 

rame = H2C0 

orderw4 

force-zero = fa1se 

minimize-percent-error = rals2 

dynami c-reference = fal se 

Page 4 
aci d 

use-dyanami c fal se 

use-1 i neari ty fal se 

ose-shi ft = fa7 se 

coeffi cents =O, 4} m0, 0, 0 

setname = 112co 

References : 

]et-fzlename = 

Reg-i on ( 2462.15 - 2528.55 ) a 

w-i nr#ows ; 

2462125 - 2528.55 

rneport-compounds = S02 

i nterference--cosnponnds = CO2 sH20 

Li neari ty o 

name = So2 

order 4 

force-zero = false 

mi ni mi ze-percent-error = fa1 se 

dynami c- reference = fai se 

use-dyanam-i c = fal se 

use-i -i neari ty = fa1 se 

use-shi ft = fa1 se 

coefficents W 0,0,0,0,0 

setname = s02 

References : 

set-fi 1 enanie = 

Regi On t 2673.15 - 2848 . 3.8 ~ e 

wi ndows ; 

2673.3S - 2848.18 

report-compounds = NCL 

i nterferente-compovnds = H20 

Li neari ty a 

name = HCL 

order 4 

force-zero = fal se 

mi ni mi ze-percent-error = fa1 se 

dynami c- reference = fai se 

use-dyanami c = fa1 se 

use-1 -i rieari ty = fal se 

use-shift = fa1 se 

coefficents = 0,0,0,0,0 

setnatne = HCL 

Refe renceS : 

set-filename = 

Regi on ( 3172 . 7- 3331.5 

W i ndovus ; 

3172.7 - 3331.5 

report-compounds = H20 

interference-compounds = 

Li neari ty : 

name = H20 

order = 4 

Rage 5 
aci d 

force-zero = false 

minimize-percent-error = false 

dynamic-reference = false 

use-dyanami c = fal se 

use-linearity = false 

use-shi ft = fa7 se 

coeffiicents = 0,0,0,0,0 

setname x Fi20 

References : 

set-fi 1 ename = 

Reg7 on ( 4067 

w i ndows ; 

4108.4 

4140.7 

4172.76 

.31 -- 4285.13 ) : 

4111.29 

4144.43 

- 4175.22 

report-compounds = HF 

interference-compounds = H20 

Li neari ty o 

name = HF 

order = 1 

force-zero = true 

minimize-percent-error = true 

dynam-i c-reference = true 

use-dyanami c = fa7 se 

use-1 i neari t= fal se 

use-sf~ i ft = ~al se 

coeffi cents = 

setname = HF 

References: 

set-filename = 

HF, C:\1\Spectra\Misc\oMNIC\HF-10-0.94cm-l. SPA 

HF, C:\3\spectra\Misc\OM1vIC\HF-40-0.94cm-1.SPA 

HF, C:\1\Spectra\Misc\OMU=C\HF-20-0.94cm-l.SPA 

HF, C:`1\Spectra\Misc\oMNZC\HF-15-0.94cm-1 .SPA 

HF, C:\1\Spectra\Misc\OMNIC\HF-120-0.94cm-1.SPA 

HF, C:\I\Spectra\Misc\oMNIC\HF-100-0.94cm-1.SPA 

HF, C:\1\Spectra\Misc\OMNIC\HF-5-0.94cm-1.SPA 

code shortname pres(Torr) temp(C) concCppma patfi7ength(cn) 

HF HF-10-0.94cm-1 700 i85 10 9 

HF HF-40-0.94cm-1 700- 185 40 9 

HF HF-20-0.94cm-1 700 185 20 9 

HF HF-15-0.94cm-1 700 3.85 15 9 

HF HF-120-0.94cm-1 700 185 120 9 

HF HF-100-0.94cm-1 700 185 100 9 

HF HF-5-0.94cm-1 700 185 5 9 

~-i as : 

Page 6 

Ni colet CO2 40K 760T/10m/185C Synthetic 

45 

40 

35 

~ 30 

~ 

,a 25 

0 

~ 

Q 20 

15 

10 

5 

1 1 ~ ~ ~ ~ ■ iit 2500 2000 1500 1000 500 

Uilavenumbers (crn-1 ) 

Number of sample scans: 'i 

Number of background scans: 0 

Resolufiion: Unknovun 

Sarnpte gain: 1.0 

iUlirror velocity: 0.0000 

Aperfure: 0.00 

Example Spectra 
~ y~

hermo Nicolet ~

£~ 3.8%H20 1851755/10.31JW 

6 

5 

4 

U 

G 

itY 

42 3 0 

~ 

.~ 

~ 

2 

1 

0 

4500 4000 3500 3000 2500 2000 1500 1000 

1fVavenumbers (cm-1) 

Example Spectra 

Number of sampfe sccans: 179 

Number of background scans: 179 

Resolutian: 0.500 

Sample gain: 1.0 

Mirror velocity: 1.8988 

Aperrture: 10.00 
ormoN

0 

ICOlet FiCI 10ppm 760/32m/185C Synthetic 

0.10 

'iWm 

0.04 

0.02 

3400 3200 3000 2800 2600 2400 

Wavenumbers (cm-1) 

Exampie Spectra 

Number of sampie scans: 1 

Number ofi background scans: 

Resolution: 0.500 

Sample gain: 1.0 

Mirror detocity: 0.0000 

Apertu re: 0.00 
'~ 1 ~ ` 1 J ~it~ ~ . ~3~

,+'• H F 0.1 ppm 650T/25.1 m/'I 85C Synthetic 

0.0045 

0.0040 

0.0035 

0.0030 

c~ 

~

0.0025 

0 

~ 0.0020 

0.0015 

0.0010 

0.0005 

0.0000 

4400 4200 4000 3800 3600 

Wavenumbers (cm-1) 

Example Spectra 

Number of sample scans: 1 

Number of backgraund scans: 

i~tesoiution: 0.500 

Sample gain: 1.0 

Niirrar velocity: 0.0000 

Aperture: 0.00 
1

~ ~'-rh- ~rniaNicolet Thu Apr 14 1 5:58:57 2005 (GMT-05:00) 

-1.0 

-1.2 

~ I ~ 

-e 

~ -2.o I t 

-2.2 ~rv 

-2.4 

1 

 ~ 

i, 

~ 1 

., 

•' ~ v : ~ 

-2.6 

1C4 -L 

2500 2480 2480 2440 2420 

Vltavenumbers (cm-1) 

' Example Spectra 

Nurriber of sample scans: 32 

Number of background scans: 32 

Resolution: 4.000 

Sample gain: 1.0 

Mirror velocity: 1.8988 

Aperture: 10.00 
a 

Ormo.-Nicoet Thu Apr 14 Or: 1 8:03 2005 (GMT-05: 0U) 

0.30 

0.25 

~ 0.20 

C 

o 0.15 

N • 

.~ 

~ 

0.10 

0.05 

0.00 j 

1250 1200 1150 1100 1054 1000 950 

Wavenumbei-s (cm-71 

Eacample Specfira 

Number of sampie scans: 178 

Number of background scan$: V9 

Resoiution: 0.500 

Sample gain: 1.0 

t1/lirror vefocity: 1.8988 

Apertu re: 10.00 
~~~-: o { ~., r_ ~; - :, - - r • _ Nco et Background, Thu Apr 14 07:08:50 2005 (GMT-05:00) 

.. 

50 

~ 40 

~ 

m 

~ 

30 ~ 

G 

:4] 

20 

W 

'~ ,~ ,(#''~`~'• ";. !n` 

. ~ 

~ E ~ 

~ f ~ 

aIlt 3500 3000 2500 2000 1500 1000 500 

UUavenumbers (cm-1) 

Exampie Spectra 

Number of sample scans: 179 

Number ofi background scans: 0 

Resolution: 0.500 

Sample gain: 1.0 

Mirror veiocity: 1.8988 

Aperture: 10.00 
APPENDIX.,~ 
~'`~ 

~.`r~"~.. ~.~ ~ .. ~,~ + ~~ i~~~ ta` 

~

=•.... ; 1'1 4 

~' ~ : ~ ~ i ~ r, ~~,. ~~i ~ .. ~ ~ '~r' ~ t + ~ ~ ~._ ~E ~ ! ~~. e.. 

, ~ , , - ~ -- , 

~ ri., I -<- ;~~ ! ~ ~ ~ Z~ _. _ .j ! ~~ }i~, ;, , ~ ,i. 

i k ~ ~~ ~ -- ~' ~ - ; ~ 

°itot Tube iD No. : A-10 (-iigh side calibration factor : 0.842 

Pei-forrned b}/: SH Low side calibrafion factor : 0.841 

Caiibration Date : 3J23l2005 Comrnents: 

A Side Calibration hi h side 

OPs ' A s Cp ev. 

(in.) (in.) 

Hz0 H20 

0.580 0.810 0.843 0.001 

0.580 0.810 0.843 0.001 

0_580 1 0_815 0_840 1 -0.002 

i - - Avera - -C ' 0.842 

B-Side Calibration ow side 

epstd' 

(in. ) 

H20 

OPs' 

(in. ) 

H20 

Cp (S)a Dev. 

0.580 0.815 0.840 -0.001 

0.580 0.815 0.840 -0.001 

0.580 1 0.810 0.843 0.002 

I Avera e C' 0.841 

apstd Ternperature (°F) : 67 

CP ( Q ~ = CP(std) 

L1Ps Humidity (%) : 42 

Dev.b= Cp (S)a- Cp' (must be < 0.01) Date: 312312005 

Cp' (A) - Cp' (B) = 0.001 (must be <0.01) Cp (std)* : 0.996 

Cp' (A) = 0.842 Cp' (B) _ 0.841 Standard Pitot No. : 3 

*Cp (std) obtained frrom Dwyer tnstruments air veEocity calcuiator. 

Cafibrations were done in accordance with CFR Tit1e 40, Part 60, Appendix A, July 1, 1994. 
WESTERN ENVBRONMENTA9. SERV9CES AN® TES1°ING 9NC. 

METER BOX CALIBRAT9ON FORM 

Meter Box Num: 24 Average DGM Y= 0.996 Tech: W-lINES 

P6 = 24.90 Deita hi Q= 1.583 Date: 3I10/2005 

Orifice 1.D.a 48 K1= 0.3510 OritTce t.D.= 55 K1= 0.4625 

1 2 1 2 

DGM Flnal 504.689 506.981 510.107 513.109 

tn'rtial 502.410 504.689 507.104 510.107 

m 2.279 2292 3.003 3.002 

em In/0ut 66 66 66 1 66 1 67 67 671 67 

vg. Tm °RPF 526 66 526 66 527 S7 527 67 

elta H 0.47 0.47 0.84 0.83 

fme: 5 0.44 5.007 5 0.06 E5.001 5 0.27 1 5.005 5 0.28 1 5.005 

Orifice Tem . 68 68 69 69 

acuum "Hg 15.0 15.0 14.0 14.5 

m std 1.907 1.918 2.511 2.510 

cr (std) 1.905 1.902 2.506 2.506 

DGMCF Y 0.999 0.992 0.998 0.999 

elta H@ 1.533 1.533 1.581 1.562 

Orifice I.D.= 63 K1 = 0.5983 CaRbaration Resadb" 

Orifi~ce I.D.= 48 

DGhIiCF Y= 0.995 Dbfference= 0.085°l0 

Avg. Vm (std)= 1.912 

Difference (1)= 0.284% (2)= -0.284°!0 

aritr#ce I,D.= 55 

DGMCF Y= 0.998 Difference= -0.211 % 

Avg. Vm (std)= 2.510 

Difference (1)= -0.018% (2)= 0.018% 

OrMce I.D.= 63 

DGMCF Y= 0.995 Difference= 0.126% 

vg. Vm (std)= 3.253 

Dffference 1)= 0.051 % (2)= -0.051% 

1 2 

GM Final 521.231 525.117 

Initia! 517.349 521.231 

m 3.882 3.886 

em In1Out 67 67 67 67 

vg. Tm °Rf°F 527 67 527 67 

Delta H 1.45 1.45 

nne: 50.00 1 5.000 50.17 1 5.003 

Orifsce Tem . 70 - 70 

acuum "Hg 13.0 13.0 

m std 3.251 3.255 

cr std 3.236 3.237 

DGMCF Y 0.995 0.995 

Deita H 1.640 1_640 

"Results cornuiv with iVtetEsod 5 calihretinn stanrlarclA whara • rlrA/K:F difrxsranrac ara Lc ec 'khmn .&L9 noii. 

and average Vm (std) differences are less than f/-0.5%. 
ORiFICE CAUBRATION 

Meter Box No. ?4 Initials: N.HINES 

Date of Calibration 3l10120DI DGMCF: 0.996 

Date of Expiration 611012095 Pb: 24.90 

ACFM=DGMF-DGRiII 

TIt1f1E 

SCFNI = ACFM (DGMCF) 528, Pb 

TM 29.92 

IoltITtAL INITIAL FIAlAL FINAL TS411 

AHI DGMF DGMI T IN T OUT T IiV T OUT R TI11AE ACFIiA SCFAA 

0.11 526.070 525.855 66 66 526 1 0.215 0.179 

0.21 526.378 526.070 66 66 526 1 0.308 0.256 

0.31 526.754 526.378 66 66 526 11 0.376 0.313 

0.4 527.190 526.754 67 67 527 1 0.436 0.362 

0.5 527.667 527.190 67 67 527 11 0.477 0.396 

0.6 528.180 527.667 67 67 527 1 1 0.513 0.426 

0.7 528.706 528.186 67 67 527 11 0.520 0.432 

0.751 529.281 528.706 67 67 527 1 0.575 0.478 

0.8 529.861 529.281 67 67 527 1 0.580 0.482 

0.9 530.484 529.861 67 67 527 1 0.623 0.517 

1 531.150 530.484 67 67 527 1 0.666 0.553 

1.51 531.939 531.150 67 67 527 1 0.789 0.655 

21 532.874 531.939 67 67 627 1 0.935 0.776 

2.5 533.892 532.874 67 67 527 1 1.018 0.845 

3 534.998 533.892 67 67 527 1 1.106 0.918 

3.5 536.216 534.998 67 67 527 11 1.218 1.012 

4 537.4911 536.2161 681 68 5281 11 1.2751 1.057 

THERMOCOUPLE CALbBRA7'ION SHEET 

MeteP Bou ig8o : 24 T®ch : MRC Date : 3J1012005 

Refeaence: Mercas a-iee-Glase 1 A:TPA 3F 

Referenoe T'herMomeLer "d'herMocou„piR Offeren ~e 

~~~~~ie. °F Q!\ °F °R °R 

Meter In : 

!ce Bath 

Boiling Water 

Hot Oit 

PAeter t)ut : 

tce Bath 33 493 34 494 -0.20 

Boi#ing Water 214 674 215 675 -0.15 

Hot 00 310 770 311 771 -0.13 

Probe : 

lce Bath 33 493 34 494 -0.20 

Boiling Water 219 679 220 680 -0.15 

Hot 05 312 772 311 771 0.13 

Steck : 

!ce Bath 33 493 33 493 0.00 

Boiling Ulfater 215 675 215 675 0.00 

HoY Oil 317 777 317 777 0.00 

Oven : 

lce Bath 34 494 34 494 0.00 

Boiling Water 215 675 214 674 0.15 

Hot Oil 317 777 317 777 0.00 

Exit : 

!ce Bath 33 493 .33 493 0.00 

Boiling Water 212 672 212 672 0.00 

Hot Ol 311 771 312 772 -0.13 

Auxivia : 

!ce 8ath 32 492 33 493 -0,20 

Boiling V!latei 218 678 219 679 -0.15 

Hot Oil 312 772 311 771 0.13 
WESTERN ENV9RONMENTAL SERVICEaS AN® TES'TRNG QNCo. 

METER BOX CALIBRAT4®N FORM 

;Uleter Sox Klum: 21 Average DGiUJ Y= 0.991 Tech: N.HIiVES 

Pb = ~ 24.70 Deita H @ = 1.632 Date: 3/22/2005 

~ Uriflce l.D.= 48 Kl= 0.3510 OrMce I.D = 55 K1= 0.4625 

~ 1 2 '! 2 

DGM Finai 225.645 227.961 243.906 247.130 

lnitial 223.329 225.645 240.784 244.118 

rn 2.316 2.316. 3.122 3.012 

Temp In/Out 641 64 64 fi4 64 63 64 64 65 64 66164 66 64 66 64 

v. Tm °R1°F 524 64 524 1 64 524 1 65 525 1 65 

tta H 0.48 0.48 0.84 0.84 

rime: 5 0.21 5.004 50.26 1 5.004 510.871 5.181 4 59.9!

68 

4.999 

Or~ce Tem . 69 69 68 

acuum "Hg 12.0 12.0 11.0 11.0 

rn(std) 1.930 1.931 2.604 2.507 

cr std 1.886 1,886 2.576 2.485 

DGMCF Y 0.977 0.977 0.989 0.991 

ita H 1.587 1.588 1.600 1.597 

Oriffce I.D.= 63 K1= 0.5983 Calibradon RSesgst~~ 

ffice I.®.0 48 

DGIVICF Y= 0.977 Difference= 1.389°!0 

Avg.1/m (std)= 1.930 

Difference (1)= 0.024°!0 (2)= -0.024% 

OrMce L0.= 55 

DGMCF Y= 0.990 Dffference= 0.086% 

Avg. Vm (std)= 2.558 

Difference (1 )= -1.889% (2)= 1.889°!0 

Ort$dcrr Y.D.= 63 

DGMCF Y= 1.006 Difference= -1 .475% 

Avg. Vm (std)= 3.200 

Difference (1)= -0.089% (2)= 0.089% 

1 2 

DGM Final 244.052 247.878 

Initiai 240.221 244.052 

m 3.831 3.826 

em inlOut 64 63 65 163 . 651 63 65 63 

vg. Tm °R!°F 524 1 64 524 1 64 

Delta H 1.50 1.50 

ime: 50.04 5.OQ1 459.881 4.998 

rifice Tem . 67 67 

acuum "H_g 12.0 12.0 

m std 3.203 3.197 

cr sfd 3.219 3.217 

GtVtCF Y 1.005 1.006 

Delta H 1.712 1.711 

*Resutts comt)fv with Method 5 catibration standards uvhera_ DGilItCF differannes ara [ass than +/ 2_4a% 

and average Vm (std) differences are tess 'than +l-0.5°!0. 
(3FUFICE ~rALiBRA'fdON '

'Metei Box No. 21 fnitials: IV-LJt.NE9„ 

Date of Cafibrafion 3L2212(10-5 DGjlflCF: 0.991 

Date of Expiration W2=05 Pb: 24.70 

ACFM= DGMF-DGNIi 

TiME 

SCFM = ACFM (DGiUICF) 528 w 

TM 29.92 

lNITlAL INIT[AL FENAL FtNAL TM 

AH DGtUIF DGM1 T IN T OUT T tN T OUT R TIME ACFM SCFM 

0.1 251.388 251.159 64 64 64 64 524 1 0.229 0.189 

0.2 251.693 251.388 64 641 64 64 524 1 0.305 0.251 

0.3 252.066 251.693 65 64 65 64 524.5 1 0.373 0.307 

OAI 252.493 252.066 65 64 65 64 524.5 1 0.427 0.352 

0.51 252.964 252.493 65 64 86 64 524.75 1 0.471 0.388 

0.61 253.484 252.964 66 64 66 64 525 1 0.520 0.428 

0.71 254.048 253.484 66 641 67 64 525.25 1 0.564 0.464 

0.75 254.630 254.048 67 641 67 641 525.5 1 0.582 0.478 

0.8 255.224 254.630 67 641 67 64 525.5 1 0.594 0.488 

0.9 255.851 255.224 67 641 68 64 525.75 11 0.627 0.515 

1 256.525 255.851 68 641 68 64 526 1 0.674 0.553 

1.51 257.301 256.525 68 64 69 64 526.25 1 0.776 0.637 

21 258.213 257.301 69 64 69 64 526.5 1 0.912 0.748 

2.5 259.214 258.213 69 64 70 64 526.75 1 1.001 0.821 

3 260.311 259.214 69 64 70 64 526.75 1 1.097 0.900 

3.5 261.5081 260.3111 701 641 711 64 527.25 1 1.195 0.979 

4 262.779 261.506 70 64 71 64 527.25 1 1.2731 1.043 

THERM000UPLE CAL.IBRATION SHEET 

Meter Box No : 21 Tech : mC Date : 3f22/2005 

Re#®rence: MePcury-In-GBasa ASTM3F 

Referermce Thermomgter Thermocoutole 72 pffkPe~ 

3murce' °F °R oF aR o

R 

Me2er ! n : 

Ice Bath 460 460 0.00 

Qoiling Water 460 460 0.00 

Hot Oil 460 gt60 0.00 

imeter Ouf : 

Ice Bath 33 493 33 493 0.00 

Boiling Water 210 670 210 670 0.00 

Hot 00 355 815 355 815 0.00 

Probe : 

Ice Bath 34 494 34 494 0.00 

Boiling Water 211 671 210 670 0.15 

Hot Oil 245 705 245 705 0.00 

Steck : 

!ce Bath 32 492 33 493 -020 

Boiling Water 211 671 210 670 0.15 

Hot Oil 352 812 351 811 0.12 

Oven : 

!ce Bath 33 493 33 493 0.00 

Boiling Water 211 671 212 672 -0.15 

Hot 00 359 819 358 818 0.12 

Exit : 

Ice Bath 33 493 33 493 0.00 

Boifing Water 212 672 213 673 -0.15 

Hot Oil 358 818 358 818 0.00 

Auxiiiary : 

Ice Bath 33 493 32 492 0.20 

Boiling Water 210 670 211 671 -0.15 

Hot Oil 382 842 381 841 0.12 
Area Caiibratioa 

FT-IR Celfl Calgbration 

AMT Main 4/1412ao~ 

$!'rt°aeon 22 most accurate Integration Range a 1204 -1050 cm-1 

Arca Reference 8.055 Area Sam le 3.124 

Referencc Conc. (p m) 10.9 Cal gas Conc. 10.1 

EteEerence Pressure (To_-r) 760 Cal gas Pressure (Torr) 757 _ 

Rc rerence '"emperature (C) 185 Cal gas Tem (IQ 1,85 

Re:erciice Pathiength (mete rs) 16.89 Ca1 gas Patlilength (nieters) 7.04 

Ethylene (C2H4) Integration Range = 960 - 935 cm-1 

Ama Referen,ce 1.231 Area Sam le 

Reference Conc. (p m) 30.2 Cal gas Conc. 

Reference Pressure (Torr) 650 Cat gas Pxessure (Torr) 

Rcference Tem eratare (C) 100 C.ai gas Temp (C) 

Refercnce Path3ength (nieters) 20 Ca1 gas Patlilengr.l3 (meters) 

Catrb®a Monoxide (C®) least accurate Integration Range = 2250 - 2025 cm-1 

Area Reference 8.162 Area Sa~ e 

Reference Conc. m) 100 Cal gas Conc. 

Reference Pressure (Torr) 650 CaI gas Pressure (Torr) 

Reference Temperature (C) 100 Cal gas Tem (C) 

Rerertnce Pathlength (meters) 20 Cal gas Pathletigth (mcters) 

Page 1 
Area Caii6ration 

FT-IR Cell Calibrati®n 

AMT Cooler 4/14/2005 

]Frwn 22 most acCurate Integration Range — 1200 -1050 cm-1 

Area Reference 8.055 Area Sample 9.762 

Reference Conc. (nprn) 10.9 Cal gas Conc. 10.1 

Reference PressiEre ('4'orr) 760 Cal gas .Pressure (Torr) 748 

Refcrence Tem eraitire (C) 135 Cal gas Tem (K) 135 ~ 

ReFerence Path:length (meters) 16.88 Cal gas Pathlengtli (meters) 22.43 

Ekl®me C2H4) Integration Range = 960 - 935 cm-I 

Area Reference 1.231 Area Sample 

Reference Conc. pm) 30.2 Cal gas Conc. 

Rcference Pressure (Torr) 650 Cal gas Pressure (Torr) 

Reference Tcm erature (C) 100 Cal gm Temp (C) 

Reference Pathlenodt (meters) 20 Cal gas Pathlength (meters) 

Carbon MOn®idde (tC®) least accurate Integration Range = 2250 - 2025 cin-1 

Area Referetzce 8.162 Area Sample 

Reference Conc. ( m) 100 Ca1 gas Conc. 

Reference Pressure (Torr) 650 Cal gas Pressure (Torr) 

Rcference Tem erature (C) I0o Cal gas Temp (C) 

Refercnce Pafihlcngth (meters) 20 Cal gas Patlilength (meters) 

Page 1 
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er -http://www.spectm-gases-com 

SHIPPED FRQNI: 80 IHDUSTRtAL DRIVE ALPHA, NJ. 08865 TEl.: (908) 454-7455 

SHIiPPED TO: A1Uestem Envirommen#a! Senrices 

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+CERTIF@CATE 

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ANAL.YSIS 

SGI ORDER # : 0051017 

! T EW : '1 C',lLIIldDF-R # : CC-98158 

{CERWICA-nC+N DATE. 03/24/2004 CYUNDER {PRES. 2000 psig 

r'.O.# : 03-042 GYUilUDER VALVE: CGA 350 

BLE6lI® TYPE: CEI4TIFiED 

A$1IALYT9CAL ACCURAGY: -¢ ! - 5% 

REQlESTED fiAS ANALY'SiS 

CDMPONENT DONC 

Chlorodifluoromethane 10.0 ppm 10.1 PPn► 

N'strogen Balance Baiance 

..~, 

ANALYST: DATE: 03/24f2004 

Ted iveerne 

USA o Unked Kirgdom o genmany ® Japan 

IJO SQ0'1 
~ 

3434 Raute 22 V4bd o Braruftttg. N,1 Q387f USA Tel: {808) 252-9300 s(800) 932-C824 Q Fax (908) 2'i2-0811 

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SL.END TVPE: CERTiFiED 

AALYM,AI. A+CCi3RACV: ¢ ! - 5°to 

REQUEST1ED GAS ANALYSES 

DOMPONlENT CaNG 

SuiTur i-lexafluoride 4.00 ppm 4.03 ppm 

Hydrogen Chloride 300 ppm 295 ppm 

iVitrogen Baiance Balance 

10/14f2003 
~;lf ~-.~~~ ~ 

~~~~~~s ~~'~~~~: ~e~°~~~~:e,~:. ~ 

. ~ - 

. ~~ . . ... 

. 
PROFESSIONALPROFILE 

. ~ 

; JEFFERY J. K1 V .CY,PP 

 ., 

~ Projecct Manager 

f~ ® Doxnesd.c & International 

"recknAcal ® Eva.luuation of Air Pollutzon Control T3evices 

° + gperdse: 

® FTTR 

a CEMS Emrission Testing & Operation 

o Source Emission Testing 

e Caltbration and Mairrtenance of Sampling Equ.ipment 

m Monitoring Equipm.ent Repair 

, . ® Test Method Regulations 

Technicafl Mr. Knapp lnas prov3ded enviucouYnental source testing since 1989. His experience 

Egperlemeeo in,ciudes operation, znaintenance, troubleshooting and supervision of tests on various 

cognbusrion systems. He is proficient in El'A methods 1- 6, 7, 8, 9, 10, 12, 17, 20, 

22, 232251, 26229, 2013202, 316, 3189320 and 321; Analogous AQMD Methods 

1.1, 2.1, 4.1, 5.195.2, 5.3, and 6.1; as well as, CARB Methods 430, 522, 524, 410A, 

and 433. Mr. Knapp has considerable exFerience in FTIR sampling having 

perforrned over 2000 FTIR evaluations throughout the country. He also has 

substantial experience 3n CEMS and sample recovery. He has experience in Part 75 

~ (Tit1e 40) RATA investigations accross the country. 

Ealucaflono Nuclear Engineering, Hampton University, VA 

Mecha7mcal Engineering, Uni.versity of Southern California, I,os Angeles, CA 

Irvine iTalley College, Irviae, CA 

Cerfflcatlon: ' 'I'CEQ, Texas Visible Enaissions Evaluaxor 

®SHA 40-13our Safetr Training Course 

H2S Sa,fety Training 

MSHA Safety '1'raining Course 

Safety Council of Southwest Louisiana 

Western Construct Trauung Trust 

D.O.T. Certified 
{'~ ~"'. 

~~ ~ ~ `~ `~ ~ ~!~' " ~► ~~ ~~' ~~ $~s ~ i ~ 

Tecbnicaa 

Expertisea 

Jake Crowder 

Environmentag Specnialist 

® Domestic & International 

o Evaluation of Air Pollution Control Devices 

® Source Emission Testing 

o Ca1i`bration and Maintenance of Sampling Equipment 

Q Hazardous Material Trial Burns 

o Test Method R.egulations 

o Prolect Manager for 40 Turbine eva.tuations and compliance tests in 

Cameroon aad Chad. 

Tesianical 

Expericncea . 

Ceufflcad®no 

Mr. Hinchey has provided emrironmental source testang since 2000. His experience 

includes operation, mainter3ance, troubleshooting aand supervision of tests on various 

emission sources. He is proficient in EPA methods 1- 6, 8, 12, 13, 15, 17, 20, 21, 

26, 231, 201 and 202. Mr. Crovvder has considerable experience in sample recovery 

and cbairrof--custody procedures for partzculate, HCL, metals, S02, and organics. 

OSHA 40-Hour Safety Training Course 

H2S Safety Training 

MSHA Safety Tra.ining Course 

PEC 
W ~ 

EnvaronmentaD Specnalnst 

Technicafl 

+ xpemsee o Source Emission Testing 

® Field Sampling 

Q VOC Sampling 

o Calibration and Maintenance of Sampling Equipment 

Techaaicad 

Egpezreemee: 

Edancataon: 

Oeatffleatgoua: 

IVIr. Cordell has 4-years experisnce in environmental testing. He has assi.sted in 

numerous source emission surveys throughout the United States. Mr. Cordell has 

experience working with EPA methods 1-12, 23, 25, 26, and 29 and saoaple train 

preparation for various EPA naethods. 

I1/Ir. Cordell has completed several cotirses in Business Adnamiiiustration tbru Boise 

State Universrty. 

H2S Safety Training 

Vi.sibie Emissions Training 

MSJH[A Safety Trainung Course 

CPR Certified 

40 Hr. HAZ NIAT Trai.ning 

OSHA Approved 

D.O.T. Certified