p.1 

OAR Box 1384 

Prepped by Charmelle Mathews 

Document Number: 

93) ll-E-53 

Docket Number: 

A-94-52 

Printed 7/2/2008 8:42:06 AM Sheet 93 of 264 
P.2 

SEC-03-1996 09:29 BRISTOLITE SKYLIGHTS P. 02 

m -A-94-52 

From: 

Date: 

Contact: 

Company: 

Contact Report 

Meianie Proctor, Pacific Environmental Services, Inc. (PES) 

October 31,1996 

Mr. Charles Van Liew, Director of Operations 

Bristol Fiberlite Industries 

Telephone Number: (714) 540-8950 

Fax Number: (714) 540-5415 

Contact Summary: 

Mr. Van Liew was contacted to verify to the content of hazardous air pollutants in the 

resins used by BristolFJgrHte. Mr. Van Liew explained that Bristol Fiberlite uses only two 

different resins, whiMrare both vapor suppressed. In 1995, the company used 34,000 pounds of 

i/fif**- $A? resi n * a t conta "

ls 2* Percent styrene by weight and contains no methyl methacrylate (MMA). 

«^>^~w.BristoI Fiberlite used^O.OOO pounds of another resin that contains 23 percent styrene and 5 

percent MMA by weight. A total of 1,498 pounds of styrene per year were added to the resins at 

Bristol before the resins were applied. Mr. Van Liew offered to send material safety data sheets 

of the two resins used to PES. 

INFORMATION IS ACCURATE t? &L. ^£ _ I 
P.3 

5EC-03-1996 09:29 BRISTOLITE SKYLIGHTS P. 03 

MATERIAL SAFETY OATA SHEET 

Ashland Chemical Co. 

LB 1043-11 

Page 001 

Date Prepared: 01/05/96 

Date Printed: 01/20/96 

MSDS No: 0301846-002.001 

1 . CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Material Identity 

product Name: LB 1043-11 

General or Generic ID: UNSATURATED POLYESTER RESIN 

Company 

Ashland Chemical Co. 

P.O. Box 2219 

Columbus, OH 43216 

614-790-3333 

Emergency Telephone Number; 

1-800-ASHLAND (1-800-274-5263) 

24 hours everyday 

Regulatory Information Number: 

1-800-325-3751 

2 . COMPOSITION/INFORMATION ON INGREDIENTS 

Ingredient(s) CAS Number 

POLYESTER RESIN 

STYRENE 

FLAKE RETARDANT 

ESTER 

Trade Secret 

100-42-5 

Trade Secret 

Trade Secret 

% (by veight) 

55.0- 60.0 

28.0 

5.0- 10.0 

1.0- 5.0 

.ISLr 3. HAZARDS IDENTIFICATION 

Potential Health Effects 

Eye 

Exposure causes eye irritation, 

redness, and swelling. 

Symptoms may include stinging, tearing, 

Skin 

Exposure causes slcin irritation. Prolonged or repeated exposure may dry the 

skin. Symptoms may include redness, burning, drying amd cracking, skin burns 

and skin damage. Skin absorption is possible, but harmful effects are not 

expected from this route of exposure under normal conditions of handling and 

use. 

Swallowing 

Single dose oral toxicity is low. swallowing small amounts during normal 

handling is not likely to cause harmful effects; swallowing large amounts nay 

be harmful. This material can enter the lungs during swallowing or vomiting 

and cause lung inflammation and/or damage. 

Inhalation 

Exposure to vapor or mist is possible. Exposure to aerosol and/or mist is 

possible when material is sprayed. Aerosol and mist may present a greater risk 

of injury because more material may be present in the air than from vapor 

alone. Short-term inhalation toxicity is low. Breathing small amounts during 

normal handling is not likely to cause harmful effects; breathing large amounts 

may be harmful. Symptoms are more typically seen at air concentrations 

exceeding the recommended exposure limits. 

Continued on next page 

2__ 
P.4 

ITjEC-03-1996 09-29 

MATERIAL SAFETY 

' DATA SHEET 

BRISTOLITE SKYLIGHTS 

Ashland ui vision et ASnland inc. 

P.O. BOX 2219 

COLUMBUS, OHIO 43216 

(614) 790-3333 

P. 04 

Emergency 

Telephone 

(800) 274-5263 or 

(800) ASHLAND 

00070S LB 1043-02 

THIS MSOS COMPLIES WITH 29 CPR 1910.1200 (THE HAZARD CC*J*WICATIC*) STANDARD) 

Page: 

Product Nana: LS 1043-02 

BRISTOL FIBERLITE INDUSTRIES 

401 EAST GOETZ STREET 

SANTA ANA CA 92707 

ATTN: PLANT MGR./SAPETV OIR. 

03 56 041 1326100-

PRODUCT: 505119 

INVOICE: 410197 

INVOICE DATE: 05/11/95 

TQ3 SAME 

Oata Sheet No: 0301790-001.000 

Preparedt 04/14/95 

Supersedes: ( N/A ] 

Print Date: OS/20/95 

ON I -PRODUC T I Dfc N T I F I C AT I ON 

General er Generic 10: UNSATURATED POLYESTER RESIN 

DOT Hazard Classification; 3 (FUMWIABLE LIQUIO) 

SECTIO N I I - COMPONENT S 

IP PRESENT. IARC. NTP ANO 091* CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. 

SEE DEFINITION PAGE FOR CLARIFICATION 

INGREDIENT 

POLYESTER RESIN • 

Percent 

58-62 

PEL TLV Note 

( O 

STYRENE 

CAS *. 100-42-5 

METHYL METHACRYUTE 

CAS *: 80-62-6 

23 

5 

50 PPM 

100 PPM 

50 PPM 

100 PPM 

( 2] 

( 3) 

FLAME RETARDANT • 

ESTER • 

OIMETHYL METHYLPHOSPHONATE 

O S *x 756-79-6 

1-S 

1-5 

1-5 

(4) 

{ 5) 

( 6) 

Notes: 

( 1) PEL/TLV NOT ESTA8LI»E D FOR THIS MATERIAL 

( 2) ACGIH /OS * SHORT TERM EXPOSURE LIMIT (STEL) FOR STYRENE MONOMER IS 100 PPM. NIOSH RECOKMENDS A LIMIT OP 

SO PPM. 8-HOUR THA. 100 PPM 15 MINUTE CEILING. 

THIS CHEMICAL IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OP SARA TITLE III. 

( 3) THIS CHEMICAL IS SUBJECT TO THE REPORTING REQUIREMENTS OP SECTION 313 OF SARA TIUE III. 

( 4) PEL/TLV NOT ESTA6U9CD FOR THIS MATBHAL 

( 5) PEL/TLV NOT ESTABLISUD FOR THIS MATERIAL 

( 6) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL 

• THE SPECIFIC CHEMICAL NAME OP THIS COMPONENT IS BEING WWEL O AS A TRAOE SECRET. 

SECTIO N 111-PHYSiCA L DAT A 

Boiling Point 

Vaoor Pressure 

Specific vapor Density 

Specific Gravity 

Percent volatiles 

Evaporation Rate 

State 

Form 

for C0MP0NENT( S») 207.00 Oeg F 

97.22 Deg C) 

760.00 BIB Hg 

for COMPONENTf 

AIR = 1 

S%) 

\ 

9 

( 

35.00 nm Ho 

68.00 Oeg F 

20.00 Oeg C) 

3.60 

1.100 

77.00 Deg F 

25.00 Deg C) 

28-32% 

SLOWER THAN ETHER 

LIOUID 

K K K SOLN 

3 

TOTfiL P.04