## Material Safety Data Sheet 

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This SDS adheres to the standards and regulatory requirements ofthe United States and may not meetthe regulatory requirements in othercountries. SECTION 1. PRODUCTAND COMPANY IDENTIFICATION 

### Product name Tradename/Synonym MSDS Number Manufacturer
Product Information Medical Emergency Transport Emergency 

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. Cyclooctadiene metal derivatives



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: '- CHEMTREC: +1-800-424-9300 (outside the u.S. ;1::703-527-3887)
SECTION 2. HAZARDS IDENTIFICATION 

### Emergency Overview

WARNING! Maycause cancer. Causes eye, skin, and respiratory tract irritation. Flammable solid. This product is for experimental uses only. The product has not been completely analysed and all ofthe hazards may not be known. Please use caution while handling this product. Potential Health Effects Skin Eyes Inhalation Ingestion Carcinogenicity Material Causes: Mild skin irritation, Prolonged or repeated contact may dryskin and cause irritation.. Causes: Mild eye irritation Causes respiratory tract irritation. Irritation ofmucous membranes Effects due to ingestion may include: Diarrhea, Weakness, Convulsions. IARC NTP OSHA 1/8 

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### Material Safety Data Sheet 

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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 

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SECTION 4. FIRSTAID MEASURES Skin contact Eye contact Inhalation Ingestion Wash offwith soap and water. Getmedical attention ifirritation develops and persists. Wash contaminated clothing before re-use. Immediatelyflush eyes for at least 15 minutes. Get medical attention. Ifinhaled, remove to fresh air. Ifbreathing is difficult, give oxygen. Ifnot breathing, give artificial respiration. Get medical attention. Ifswallowed DO NOT induce vomiting unlessdirected to do so by a physician or poison control center. Drink plenty ofwater. Call a physician or poison control centre immediately. SECTION 5. FIREFIGHTING MEASURES Flammable Properties

Flash point Fire and Explosion Hazard : notdetermined Flammable. Burning produces irritantfumes. Hazardous decomposition products formed underfire conditions. 

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## Material Safety Data Sheet 

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Suitable extinguishing media
Firefighting Instructions 

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Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Foam, Carbon dioxide (C02), Dry chemical Exposure to decomposition products may be a hazard to health. Wearfull protective clothing and self-contained breathing apparatus. Evacuate personnel to safe areas.
SECTION 6. ACCIDENTAL RELEASE MEASURES 

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NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel)
Spill Cleanup

Accidental Release Measures Avoid contactwith skin, eyes and clothing. Avoid dustformation. Ensure adequate ventilation. Wear personal protective equipment. Use the indicated respiratory protection ifthe occupational exposure limit is exceeded and/or in case ofproduct release (dust). Avoid dustformation. Clean-up methods- large spillageVentilate thearea. Use approved industrial vacuum cleanerfor removal. Do not create a powder cloud by using a brush orcompressed air. Clean-up methods -small spillage Forsmall spills, use cloth or papertowels and place collected material and towels in appropriate containerfor disposal. Moisten and remove. Clean contaminated floors and objects thoroughly while observing environmental regulations. Preventfurther leakage orspillage. Prevent productfrom entering drains. Clean contaminated floors and objects thoroughlywhile observing environmental regulations. Dispose of in accordancewith local regulations.

SECTION 7. HANDLING AND STORAGE Handling (Personnel) Avoid breathing dust. Keep containerclosed when not in use. Do not use in areaswithout adequate ventilation. Handle under nitrogen, protectfrom moisture. Handle in accordance with good industrial hygiene and safety practice. Avoid 

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## Material Safety Data Sheet · 

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Handling (Physical Aspects) Storage 

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contactwith skin, eyes and clothing. Contaminated work clothing should not be allowed out oftheworkplace. Remove contaminated clothing and protective equipment before entering eating areas. Remove andwash contaminated clothing before re-use. Keep awayfrom heat and sources ofignition. Handle and store in a DRYclosed system, preferably under DRY nitrogen. Keep awayfrom sources ofignition- No smoking. Do notstore orconsume food, drinkortobacco in areaswhere they may become contaminated with this material. Keep container closed when not in use. Do not reuse empty container.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls

Personal protective equipment

Respiratory protection

Hand protection Any process that has the potential to generate dustshould be performed using engineering controls, such as isolation, enclosures, local exhaust ventilation, wetting with coolant, or dust collection systems, to control airborne fibers and dusts below applicable limits. Provide appropriate exhaust ventilation at places where dust is formed. Provide adequateventilation. No personal respiratory protective equipment normally required. Where there is potential for airborne exposures in excess ofapplicable limits, wearapproved respiratory protection with dust/mist cartridge. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Consultthe respirator manufacturerto determine the appropriate type ofequipmentfor a given application. Observe respirator use limitations specified bythe manufacturer. Additional protection: Gloves must be inspected priorto use., Gloves should be discarded and replaced ifthere is any indication ofdegradation or chemical breakthrough., The choice ofan appropriate glove does notonly depend on its material but also on otherqualityfeatures and is differentfrom one producerto the other., The exact break through time can be obtained from the protective glove producer and this has to be observed., Please observe the instructions regarding permeabilityand breakthrough time which are provided by the supplier ofthe gloves. Also take into consideration the specific local conditions underwhich the product is used, such asthe danger ofcuts, abrasion, and the contacttime. 

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### Material Safety Data Sheet 

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Eye protection Skin and body protection
Exposure Guidelines

Exposure LimitValues 

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Wear safety glasses with side shields. Choose body protection in relation to its type, to the concentration and amountofdangerous substances, and to thespecificwork-place. Lightweight protective clothing Safety shoes


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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 

### Form Color Odor Melling point Watersolubility 

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SECTION 10.STABILITYAND REACTIVITY 

### Stability Conditions to avoid Incompatibility Hazardous decomposition products Hazardous reactions Air and moisture-sensitive material. Heat, flames and sparks. Exposure to air. Exposure to moisture. Strong oxidizing agents Hazardous decomposition products formed underfire conditions.: Carbon monoxide, Carbon dioxide (C02).[ ]oxides Hazardous polymerisation does not occur. 

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## Material Safety Data Sheet 

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SECTION 

### 11. TOXICOLOGICAL INFORMATION 

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### 12. ECOLOGICAL INFORMATION 

### CuaticToxicity

# ~o data available
SECTION 

### 13. DISPOSAL CONSIDERATIONS 

### Waste Disposal Container Disposal Ifrecycling is not practicable, dispose ofin compliance with local regulations. Neverplace unused product down any indoor orout doordrain. Do not reuse empty container. Contaminated/not cleaned containers should be treated/handled like product waste. Dispose ofcontainer properly. Refer to applicable Local, State/Provincial, and Federal Regulations, as well as industry Standards.
SECTION 

### 14. TRANSPORT INFORMATION 

### DOT UN number Propershipping name Class Packing group Labelling No. 1325 Flammable solids, organic, n.o.s.[ 

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### Material Safety Data Sheet 

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IATA_C Reportable Quantity UN number 

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## organ~n.o.s.[ 4.1 IMDG Class Packing group Labelling No. UN number II 

### 4.1 1325 Proper shipping name FLAMMABLE SOLID, ORGANIC, N.O.S [ Class 

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# ~ Packing group Labelling No. II 

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SECTION 15. REGULATORY INFORMATION 

### TSCA

SARA 

### 313 Regulated Chemical(s) CERCLA Reportable Quantity California Prop. 

### 65 NJ Right to Know Regulated Chemical(s) One or more constituents are not listed in the TSCA Chemical Substances Inventory. Restricted to research and development activities as defined in 40 CFR

### 720.36. These experimental samples are to be used by a technically qualified individual. 

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WARNING! This product contains a chemical or chemicals known to the State of California to cause cancer[ 

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SECTION 

### 16. OTHER INFORMATION



# [ Restrictions for use : For research use only. 

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The information provided in this Safety Data Sheet is correctto the bestofour knowledge, information and belief at the date ofits publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered a warranty or qualityspecification. The information relates onlyto the specific material designated and maynot bevalid forsuch material used in combination with any other materials orin any process, unlessspecified in the text. Significant change from previous version is denoted with a double bar.



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