# Patent

## Title
Method to prevent build-up of limestone in a lime slaker that is used for batchwise slaking of burnt lime

## Abstract

A method to prevent build-up of limestone in a slaker that is used for batchwise slaking of burnt lime is described, in which lime slurry is produced with a greater degree of fineness and prolonged sedimentation time, where for immediate cleansing of the slaker before next slaking, after said calibration of the load cell aggregate, a number of valves are opened for given time periods for addition of flushing water to respective nozzles, in that flushing water is supplied sequentially via each valve to associated nozzle(s), until a predetermined amount of flushing water is reached in the slaker.

## Background
The present invention relates to a method to prevent build-up of limestone in a slaker that is used for batchwise slaking of burnt lime, in which lime slurry is produced with a greater degree of fineness and prolonged sedimentation time, as described in the ingress of the independent claim 1.
Lime slakers of different types, where most of them are intended for continuous operation, have been applied industrially for some time. “W+T” and “BJF” slakers can be mentioned as examples.
U.S. Pat. No. 4,547,349 relates to a device for non-batchwise, continuous slaking of lime. In UK Patent Application GB 2048107A, a lime slaker is shown and described, also for non-batchwise operation. EP Patent Application 0510675A3 concerns a lime slaker for non-batchwise continuous operation. CA Patent Application 1212825 relates to a regulated process for batchwise production of slaked lime.
Lime slakers that are operated continuously have in common that they are difficult to control, very maintenance demanding, not suited to computer-controlled operation and costly to produce.
Further, U.S. Pat. No. 7,105,146 B2 discloses a lime slaker, with a flushing process. However, the flushing process is carried out between each slaking and before lime again is supplied to the slaker, as disclosed in column 5, line 24-30. No sequentially flushing is disclosed in U.S. Pat. No. 7,105,146 B2.
In NO Patent Application 19933084, previously submitted by the present applicant P R Stephansen, a method is described for batchwise slaking, so-called “batch slaking” of burnt lime, also in small amounts relative to the volume of the slaker, whereupon a final product with relatively low lime concentration is obtained.
The content of the present application is a further development of NO Application 19980435, previously submitted by the present applicant P R Stephansen, and is hereby incorporated by reference.
During operation of a lime slaker, impurities and dust can lead to build-up of limestone, which influences the slaking and can lead to blowouts at high temperatures. It is an aim of the present invention to provide a new, immediate cleaning method that prevents build-up of limestone and the disadvantages this leads to.
A closed system is provided that does not produce dust and with the background in the immediate cleaning, an installation is provided with at least reduced maintenance due to the reduction of the build-up of limestone.
With the present invention it is possible to flush the slaker internally, immediate after the lime is weighed in and before the dust normally produced when falling down has adhered to the interior construction above the liquid level in the slaker. The internal flushing is thus carried out as the slaking of the lime starts, and before carbon dioxide in the air can react with the lime dust and produce lime stone CaCo3, which over time can form a rock hard coating in the slaker. Today, this lime coating must be removed with acid treatment or be manually knocked of. Such manual labour is time consuming, costly, and not attractive, which is almost completely eliminated with the present invention.
The present invention is characterised by the characteristic part of claim 1, in that to prevent build-up of limestone in the slaker, after said lime dosing and said calibration of the load cell aggregate, a number of valves are opened after fixed time periods for addition of flushing water to respective nozzles for immediate cleaning of the slaker before next slaking, in that the flushing water is supplied sequentially via each valve to the associated nozzle(s), until a total predetermined amount of flushing water is reached in the slaker.
Alternative preferred embodiments of the invention are characterised by the dependent claims 2-5, in that a first valve is opened for flushing water for a given time period, whereupon it is closed, a second valve is thereafter opened for flushing water for a given time period, whereupon it is closed, a third valve is thereafter opened for flushing water until a predetermined amount of flushing water in total is weighed into the slaker, whereupon the valve is closed.
More specifically, five seconds after a butterfly valve in the slaker has been closed and after completed slaking, the first valve is opened for flushing water with a nozzle for 10 seconds, whereupon the first valve is closed and the second valve is opened for flushing water with three nozzles for eight seconds, whereupon the second valve is closed and the third valve is opened for flushing water with three nozzles on the opposite side of the slaker, until a predetermined amount of flushing water is weighed into the slaker, whereupon the valve is closed.
Flushing water is preferably added until a total amount of flushing water of 20 kg has been weighed-in. 20 seconds after the butterfly valve has been closed, a closing signal can be sent to a valve for dust suction, whereupon the dust suction is stopped, thereafter adjustable slaking time starts after a screw transporter has stopped.



The invention shall be described with the help of the enclosed FIGURE that shows an example embodiment of a lime slaker device.



In the execution of the method according to the invention for batchwise warm-slaking of burnt lime, a lime slaker device is used as shown and described in detail in said NO Patent Application 19933084, to which reference is made.
It shall be pointed out that values for given weights, volumes, temperatures, times, etc are given as examples, and said values must therefore not be regarded as absolute.
A preferred lime slaker device, which is schematically shown in FIG. 1, comprises in the main a lime slaker 2 with an effective volume, for example, of 2100 litres (weight scale range 0-2500 kg), with a cylindrical upper section 53 and a conical lower section 54, fitted on three load cells 7 for batchwise weighing of water and lime, and with a stirrer 16 with a specially constructed mixing body and drive motor 18, rotation monitor 20 and also a water-jet driven combined dust suction/weir appliance/baffle 15 that is supplied water through a pipeline with a valve 17, where the slaker 2 receives water through a pipeline with valves 8 and 9. The slaker lid 4 is connected to a specially constructed water-outlet-preventing valve that also separates the wet and the dry lime zone. The slaker is connected to a lime silo 1 with a level gauge and also a filter 52 with a drive motor 51 for mechanical cleaning. The silo can hold 80 tonnes of burnt lime, for example, of volumetric weight 1.1 (weight scale range 0-90 tonnes), and is equipped with load cells to read the weight. The load cells amplifier gives out a 4-20 mA signal to a PLS. The silo can also be fitted with three air activators that are started and follow a given cycle, if the dosing time for the screw transporter is exceeded.
The silo is filled with lime through the inlet pipe from, for example, a tank lorry. The weight of the amount in the silo is displayed from a cabinet at the silo filling location. When 95% of the weight (AH) has been reached, an alarm in the form of a sound/light signal is given as a warning that the filling must be stopped. The sound alarm can be set from the cabinet and/or automatically by the PLS, for example, after three minutes. At 100% weight (AHH), a filling valve is automatically shut and the feeding of lime is stopped. While the valve is shut, a red warning lamp in the cabinet indicates that the filling of the silo can not take place. The filling valve can be controlled manually from the panel in the control centre.
Load cells fitted on the silo emit an alarm signal and a trip signal:













at ≧AH
Alarm. The operator is warned about a high level in the silo.


at ≧AHH
Warns the operator and shuts the inlet valve.


at ≦ALZ
Alarm. Low level in the silo.









The filter motor is preferably fitted with a safety switch and a service vender (automatic/manual).
After the filling of lime in the silo has been completed, the filter motor 51 is started manually from a local cabinet. A signal is emitted from the cabinet to an outer PLS that starts the filter motor and monitors the operational state of the motor. The filter motor 51 stops automatically after three minutes.
EXAMPLE


    
    
        1. Start button in a local cabinet is activated
        2. Filter motor 51 starts and the operation light in the cabinet lights up.
        3. The filter motor stops after about three minutes
    
    


Lime is transferred with the screw transporter 6 from the silo 1 to the slaker 2 with the butterfly valves 11 and 12 open. The slaking is initiated in that the first batch is slaked manually. The addition of lime is thereafter automatic, whereby the slaker 2 is filled with a predetermined amount of diluting water. The slaker is thereafter emptied to a predetermined residual amount, into which the next batch of lime is to be slaked.
The lime slaking temperature is decided by the ratio between residual number of kilos diluted lime slurry in the slaker (EVL) and the number of kilos of added lime (EVH), or the chosen set-points on the load cells 7, i.e. the set-points on the scale one chooses. The concentration of fully slaked lime is determined finally by the number of kilos of water that are chosen at the last set-point (EVHH). The number of kilos of water that are chosen at the last set-point (EVHH) is determining for the concentration of fully slaked lime.
The load cells 7 generate five working contacts for use in sequence:
















at ≧EVHHH
Filling of water to the upper level.



at ≧EVHH
Reached amount of filled flushing water.



at ≧EVH
Reached amount of added lime.



at ≧EVL
New slaking level reached before new slaking.



at ≧EVLL
Stirrer is stopped.










Fully slaked lime is sent to storage tank 3 through the valve 22 with the help of a motor. The motor is preferably fitted with a safety switch and a service vender.
At the start, the slaker 2 is manually filled with 400 litres of water, followed by 120 kg lime under stirring. When the mixture has reached a stable temperature of about 80° C., registered by a temperature measuring element, automatic operation can start and water is added to a mixture weight of 1200 kg, which gives a 10% slurry with a temperature of about 30° C.
The slaker can now be emptied to a predetermined weight of, for example, 600 kg. This is followed by a break of 30 seconds for return from, for example, the pump. It is important that the control system can register the real value of the batch and is tared to 0 kg, which is necessary because inertia in the system can lead to a risk of more or less chemicals than predetermined being added to the slaker.
With automatic control, when the weight in the slaker 2 is 600 kg or a newly calculated value based on the temperature regulation and after a pause of 30 seconds has expired, the slaking process will start if it is not already underway and the valve 22 will be closed.
Butterfly valve 12 in the slaker lid receives an opening signal and is confirmed in an open position from limit switches, the opening signal is sent over to the valve 17, and a dust suction unit 15 is started. After five seconds time delay the butterfly valve 11 is opened at the outflow end of the screw transporter 6 and is confirmed as open from a limit switch. A rotation monitor controls that the stirring has begun and an alarm is given if this is not the case or if the valve is not open after the command. If stirring stops, the valve 9 is opened and the slaker is completely filled with water and the process is interrupted.
The screw transporter 6 is started five seconds after one limit switch has confirmed that valve 11 is in an open position, and initiates the timer for normal dosing time, for example 180 seconds. The correct dosing time is set at start up of the plant. If the time is exceeded by 100% (360 seconds in this example), the air stimulator will be opened and closed in a determined cycle (open for about 0.5 seconds for every 30 seconds) with a start in the pause part and limited to 180 seconds. If the predetermined weight in the mixer is still not achieved the cycle will be interrupted because the storage tank signals a low level and an alarm is given.
The screw transporter 6 is kept going until the required lime amount (120 kg) has been weighed-in. One second after the screw transporter has stopped the butterfly valve 11 is closed. Ten seconds after the valve is confirmed as closed, a magnetic valve is opened for three seconds for air to the outflow vibrator. The butterfly valve 12 is closed for 20 seconds after the butterfly valve 11 is confirmed as closed, and a limit switch controls that the valve is closed. When the valve has closed, the weight is recalibrated to 0 kg. An alarm is sounded if the valve is not closed after the command.
For immediate cleaning of the slaker 2 before the next slaking, after the mentioned recalibration of the load cell aggregate 7, a number of valves are opened for a fixed period of time for supply of flushing water to the respective nozzles, in that the flushing water is supplied sequentially via each valve to associated nozzles(s) until a predetermined amount of flushing water is reached in the slaker 2. For example, five seconds after the butterfly valve in the slaker 2 has signalled closed, the first valve 25 is opened for flushing water with a nozzle for ten seconds, after which the first valve 25 is closed and the second valve 26 is opened for flushing water with three nozzles for eight seconds, after which the second valve 26 is closed and the third valve 27 is opened for flushing water with three nozzles on the opposite side, until a total predetermined amount of flushing water has been weighed in by the slaker itself, for example 20 kg.
As shown in the FIGURE, the first valve 25 controls the delivery of water to one or more nozzles via a pipe 28, while the second valve controls delivery of water to one or more nozzles via a pipeline 29, and the third valve 27 controls delivery of water to one or more nozzles via a pipeline 30. Preferably, nozzles are placed on opposite sides in the slaker, for example, the nozzles can be placed in one half part of the slaker or in the whole of the slaker's perimeter with, for example, the same or different mutual spacing.
20 seconds after valve 12 is closed, the closing signal is given to valve 17 and the dust suction 15 is stopped. After the screw transporter is stopped, adjustable slaking time is begun, for example ten minutes. The chosen slaking time and the course of this should be indicated to the operator.
When the slaking time is finished, water is supplied through valve 8 and through the flushing nozzles 24 for 15 seconds. Thereafter 1180 kg of diluting water (calculated from the second 0-calibration which has already added 20 kg of water) is supplied through valve 9, which gives a 10% lime slurry at a temperature of 30° C. With an error in amount of lime added above +2% the amount of diluting water is adjusted.
The temperature in the slaker is monitored by a temperature measuring element. If a temperature of 83° C. is not reached during the slaking process, 15 kg more of the finished slurry is emptied out, whereby EVLL reduces to 485 kg or conversely if the temperature is too high (88° C.) to 515 kg.
If the temperature during the slaking process rises above 96° C., the valve 8 is also opened, the slaker is filled with water until full level EVHHH, the process is interrupted and an alarm is given, without the stirring being stopped.
As previously described, for preparation of a 10% lime slurry it is required to add 60 kg of lime and 600 kg of water. The total level will vary depending on the temperature regulation. The finished concentration grade of the lime slurry is determinative for the temperature of the slurry into which the lime is added for the next slaking. If a lime slurry with a higher concentration grade is wanted, the slaking should take place at a higher initial temperature. If a lower concentration grade is required at, for example, the point of use, the slurry should be diluted outside the slaker, for example, by proportional dosing between water and lime solution in the pipeline after the storage tank. Addition of water can be regulated with a flow meter and a regulation valve. Alternatively, measured amounts of water can be added in the storage tank at the same time as the slaker, from full weight in smaller batches, for example, four, adds proportional lime slurry amounts in the storage tank.
After completed slaking time the level in the storage tank is controlled, and when this is reduced to EVLL, valve 22 is opened and the batch is emptied into the storage tank.
Finished lime slurry is temporarily stored in the storage tanks 3 which are equipped with a level measure in the form of a pressure transmitter and also stirrer(s). The tank can generate signals for regulation of the slaking sequence. The level signal generates two working contacts for use in the sequence and also two signals for alarm at low and high level, respectively, and one signal for starting of pumps.













at ≧EVL:
Slaking can be initiated.


at ≧EVLL:
Signal for receipt of a new batch from slaker.


at ≧AHH:
Alarm, level too high. Valve is closed.


at ≧AL:
Alarm, level too low.


at ≧ALL:
Alarm, very low level. Pumping out from tank 3 is stopped.









The stirrer shall operate continuously and is monitored by PLS. An alarm is given in addition to stop.
For the dosing of the slurry, one or more pumps are used. The pumps are arranged “standby” for each other and can be reset manually. Sealing water is added to the packing box of the pumps through solenoid valves and has inbuilt flow switches for discharge of water if the sealing water does not appear for more than three minutes after start, an alarm is given and the pumps stop. The same will happen if sealing water is absent for three minutes during operation. Additionally, each pump is equipped with a flow detector and a pressure sensor which is fitted in the pipe on the pressure side of the pumps. If these do not register an amount of water and pressure after 15 seconds, an alarm is given. If the water and the pressure are absent for a further 15 seconds the pumps stop. A flow meter is used to measure the amount of slurry from the storage tank to the sand filter. This measuring unit sends a 4-20 mA signal back to the frequency converter(s). Sediment is emptied from the storage tank through a manually operated bottom valve.

## Claims

1. A method for batch wise slaking of burnt lime in a slaker, in which lime slurry is produced, comprising the following process steps:
after slaking burnt lime in a slaker, emptying the resulting completed slaked and diluted lime slurry from the slaker, until a predetermined amount of residual slurry is reached, which residual slurry is used for mixing with a next batch of burnt lime;
transportation of the next batch of burnt lime into the slaker;
calibration of a load cell aggregate to 0 kg;
automatic initiation of a control system for automatic operation after reaching a desired slaking temperature, which adds diluting water and thereafter burnt lime of a predetermined amount in the following steps;
automatic regulation of the slaking temperature, where the ratio of water and lime is adjusted if the required slaking temperature was not reached in the previous batch, or missed, and where the slaker is completely filled with water for interruption of the slaking if a given maximum temperature is exceeded; and
automatic registration of the slaker's remaining slurry weight amount after completion of the transportation of the next batch of burnt lime into the slaker and following the calibration of a load cell aggregate to 0 kg, before the next slaking, characterized in that
to prevent build-up of limestone in the slaker, after the transportation of the next batch of burnt lime into the slaker and the calibration of the load cell aggregate, a number of valves are opened after fixed time periods for addition of flushing water to respective nozzles for immediate cleaning of the slaker before the next slaking, in that the flushing water is supplied sequentially via each valve to associated nozzles, until a total predetermined amount of flushing water is reached in the slaker.

2. A method according to claim 1, characterized in that a first valve is opened for flushing water for a given period of time, after which the first valve is closed, thereafter a second valve is opened for flushing water for a given period of time, after which the second valve is closed, thereafter a third valve is opened for flushing water until a predetermined total amount of flushing water is weighed-in to the slaker, after which the third valve is closed.

3. A method according to claim 2, characterized in that the transportation of the next batch of burnt lime into the slaker is via a butterfly valve located at an inlet for passing burnt lime into the slaker, after which transportation the butterfly valve is closed, five seconds after the butterfly valve has signaled closed the first valve is opened for flushing water with a nozzle for ten seconds, thereafter the first valve is closed and the second valve is opened for flushing water with three nozzles for eight seconds, thereafter the second valve is closed and the third valve is opened for flushing water with three nozzles on the opposite side in the slaker, until a predetermined amount of flushing water is weighed-in to the slaker, after which the third valve is closed.

4. A method according to claim 1, characterized in that flushing water is added until a total amount of flushing water of 20 kg is weighed-in.

5. A method according to claim 3, characterized in that the transportation of the next batch of burnt lime into the slaker is accomplished by operating a screw transporter until the required amount of burnt lime has been transported into the slaker, then stopping the screw transporter, after which the butterfly valve is closed, 20 seconds after the butterfly valve has closed a closing signal is given to a valve for dust suction, after which dust suction is stopped, thereafter an adjustable slaking time begins.

6. A method according to claim 2, characterized in that flushing water is added until a total amount of flushing water of 20 kg is weighed-in.

7. A method according to claim 3, characterized in that flushing water is added until a total amount of flushing water of 20 kg is weighed-in.

8. A method according to claim 4, characterized in that the transportation of the next batch of burnt lime into the slaker is via a butterfly valve located at an inlet for passing burnt lime into the slaker and is accomplished by operating a screw transporter until the required amount of burnt lime has been transported into the slaker, then stopping the screw transporter, after which the butterfly valve is closed, 20 seconds after the butterfly valve has closed a closing signal is given to a valve for dust suction, after which dust suction is stopped, thereafter an adjustable slaking time begins.