## P. 1


# OAR Box 1500 Prepped byOllie Stewart



# Document

Number: 

# 52 ) ll-C-7 8 Docket Number: 

# A-94-5 2

Printed 8/5/20081:51:29PM

Sheet 52 of 343

## P. 2

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PACIFI C ENVIRONMENTA L SERVICES
. INC . 

# I a ^z-199 6 

# A-94-5 2 Centra l Par k

West 500 1 Sout h Miam i Boulevard , Suite 30 0 P.O . Bo x1207 7 Researc h Triangl e Park , N C 27709-207 7 (919)941-033 3 FA X(919 ) 941-023 4 

# FAXCOMMUNICATIO N Date : ////1/f7 FROM : Jttctini'f

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# TO : Name : Address : 3o k> 1^4 £<>\r<ls



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# Phon e Number : FA XNUMBER

: (? >5) 7? I - 066 $ 

# REFERENCE CODE : A*?0



# /- **) THI S COMMUNICATIO NCOMPRISE S £ PAGE S INCLUDINGTHI S PAGE . COMMENTS : &'*>. 

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WASHINQTON
. D.C
. • RESEARC H TRIANGL E PARK
. N C •LO S ANQELES , C A• CINCINNATI
. O HPacifi c Environmenta l Services , Inc .

Projec t No . N80 1 •Reinforce d Plasti c / Composite s NESHA P Tabl e 1 : Compariso n o fth e Differen t Reinforce d Plasti c / Composite s MAC TMode l Equations . 

# WAT 

# 7

Doe s Equatio n Meet s Adoptabilit yCriteria ? 2n d Orde rPolynomial . y= m,x ' •m, x•b (b°0 ) 

# i^fflP^P^STEiiui^oi^^^^^^^^^^Sg^^r : 

# sKssa^a^^ s t^msas^ii^aMH^assasaj ^ y= m , x(%HAP) ' + m , x(%HAP) y= c , xm , x(%HAP) + c , xm , HA P emitted HA P emitted increase s a s % HA P increases . no t equa l t o zero a

t zer o % HAP . N o Power , y= mx

* + b ( n ° constant , b = 0 ) y= m,x(%HAP) ' y= c,xm,x(%HAP) " HA P emitted HA P emitted increase s a s % HA P increases . equa l t o zero a

t zero % HAP . Ye s Linear : y= m

x+ b ( b = constant

) y= m , x(%HAP) •b y= cxm . + c,xb / (%HAP) HA P emitted HA P emitted decreases a s % HA P inaeases .

equa l t o infinit ya t zer o % HAP . 

## N o Linear : y= m

x•b (b°0 ) y= m,x(%HAP ) 

## y = cxm . HA P emitte d HA P emitte d remain s constan t a s % HA P increases .

equal s a constan t a t zer o % HAP . 

## N o
Not e 1 : Th e equation s show n abov e ar e possibl e equation s t o b e use d i n a MAC Tmode l poin t valu e syste m designe d t o accuratel yreflec t emissio n reductio n credit s t o th e variou s emissio n reductio n technique s tha t a facilit ycoul d

chos e t o mee t th e MAC Tstandard . Th e equation s show n shoul d no t b e use d fo rpredictin g emissions . Not e 2 : Criteri a fo racceptability : 1. ) equatio n mus t produc e zer o emission s @ 0 % HA P conten t an d 2. ) Increasin g emission s wit h increasin g HA P content , whe n expressin g emission s i n lb s HAP/to n resi n end . lb s HAP/lb s Availabl e HAP . Not e 3 : Equation s fo rEmission s a s lb s HAP/lb s Availabl e HA P obtaine d b ydividin g Equation s fo rEmission s a s lb s HAP/to n Resi n b yth e % HAP/100 . Not e 4 : Discussio n assume s constan t resi n tonnage . Tabl e 2 : Compariso n o fth e MAC TMode l Result s Obtaine d fro m th e 2n d Orde rPolynomia l Equation , Powe rEquatio n an d Linea rEquatio n ( b * 0 ) Compare d

t o th e MAC TMode l Result s Obtaine d fro m th e Linea rEquatio n wher e b a constan t fo rManua l an d Mechanica l Resi n Applications . 

## IIB*3tSrfT8SlM ^ 

# I * 0. 0

5. 0 10. 0 1 5 0 20. 0 2 5 0 30 0 35. 0 40. 0 4 5 0 50. 0 0

5 1 3 24 3 8 54 7 4 9 6 12 2 150 18 1 N/ A 200 % 200 % 200 % 68 % 20 % 5 %

~ 0 % 1 % 1 % 4 % 0

3 1 0 2 1 3 5 5 2 7 2 -9 4 11 9 14 6 17 6 N/ A 200 % 200 % 200 % 62 % 16% 2 % 2 % 3 % 1 % 1 % 0

1 5 3 0 4 5 6 0 7 5 90 10 5 12 0 135 149 N/ A 200 % 200 % 200 % 105 % 51 % 24 % 8 % 2 % 10% 15% 0

0 0 0 : 1 9 4 4 70 98 122 14 8 17 4 ' N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 0

0 0 0 0 2 3 7 3 13 8 21 7 31 2 42 2 N/ A

N/ A N/ A N/ A N/ A 200 % 28 % 0 % 1 % 3 % 9 % 0

0 2 8 2 2 4 6 84 •13 9 21 6 31 9 45 2 N/ A 200 % 200 % 200 % 200 % 200 % 42 % 1 % 2 % 5 % 16 % 0

2 6 5 2 7 8 104 12 9 15 5 18 1 -20 7 23 3 25 9 N/ A 200 % 200 % 200 % 200 % 200 % 96 % 27 % 6 % - 26 % 40 % 0

0 0 0 0 0 5 5 13 8 220 - 30 3 38 6 N/ A

N/ A N/ A N/ A N/ A N/ A N/ A N/ A 

## N/A N/ A N/ A Tabl e 3 : Compariso n o fth e MAC TMode l Result s Obtaine d fro m th e 2n d Orde rPolynomia l Equation , Powe rEquatio n an d Linea rEquatio n ( b = 0 ) Compare d

t o th e MAC TMode l Result s Obtaine d fro m th e Linea rEquatio n wher e b •constan t fo rFilamen t Windin g an d Ge l Coa t Applications .

N/ A 5. 0 1 4 200 % 1 0 200 % 2 0 200 % N/ A 1 7 200 % 1 1 200 % 5 2 200 % N/ A 10. 0 3 0 148 % 2 6 141 % 40 160 % N/ A 4 4 200 % 3 6 200 % 104 200 % N/ A 15. 0 4 7 45 % 4 3 37 % 6 0 67 % 3 0 N/ A 8 2 200 % 7 5 200 % 15 5 200 % N/ A 20. 0 6 6 18 % 6 3 13 % 80 36 % 5 5 N/ A 13 1 65 % 12 5 62 % 20 7 103 % 6 6 N/ A 25. 0 8 6 6 % 84 4 % 100 21 % 8 1 N/ A 19 0 19 % 186 16 % 25 9 48 % 15 8 N/ A 30. 0 10

8 1 % 10

6 0 % 11 9 12 % 10 6 N/ A 26 0 4 % 25 8 3 % 31 1 22 % 25 0 N/ A '•iSJOi 131 S :;4% * 

## ;13o y ^1% " 139 . 

## -vkj !=«2 < N/A - J341 3 

## <;o%5 ; ^339; : a0% 3 J&Zi i?6% 3 *H5 i 3»/'A : !;J.?j40.o

y ;.1tW?
. rf.1%* ; MM' ' y2%v 159 - ; "1% f 

## £I»M N/ A P33 y '•iVkl 8431 * 

# mm VA.M S45CS •3433 * 

## %HM< ?4fc0 > ;il8l * 

## asi% % SIBO: % ii% " '179 ^ ;-2%J ;1BSy i N/ A 53 5 2 % 53 2 1 % 46 6 12 % 52 4 N/ A 50. 0 20 9 0 % 20 6 1 % 19 9 4 % 208 N/ A 64 8 5 % 64 1 4 % 51 8 17 % 61 6 N/ A Not e 5 : Percen t Differenc e ( % Diff. ) i s define d a s {[|( a - b) | / (0. 5 x(a+b)) ] x100) . Not e 6 : BokJe d an d shade d emissio n an d percen t differenc e value s ar e value s withi n th e HA P conten t rang e teste d b yth e Composit e Fabricator s Associatio n (CFA) .
T J C O

# ypfrTT Reinforce d Plastic/Composite s MACTMode l fo rManua l Resi n Applicatio n



# ^ P tn

< D 

# Ct 

# c o +• » 

# C L < X tn A tn c o '3 5 

# tn 

# 1 U J C L < X 20 0 18 0 

# 16 0 14 0 12 0 10 0

1 0 1 5 2 0 2 5 3 0 

# Resi n Monome rConten t ( % HAP ) 3 5 4 0 4 5


# a X 0.04 1 in./15min./50fp m 0.08 8 inV1 5 min75 0 fp m O 0.04 1 in./15min./10 0 fp m

- 0.08 8 in/1 5 minV100 fp m A O 0.04 1 in./3 0 min./5 0 fp m 0.08 8 in./3 0 minV5 0 fp m X



# + 0.04 1 inV3 0 min./10 0 fp m 0.08 8 in./30min710 0 fp m

- 2n d Orde rPoly . 

# 5 0

T I 4 ^

# y/fArr'- Reinforce d Plastic/Composite s MAC TMode l fo rGe l Coa t Applicatio n 70 0

60 0

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# c

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# Ct 

# c o + * 

# a. < X mQ 

# "-^ tn 

# c o C O C O 

# E L U Q L 

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400

30 0

200



# 10 0

1 0 1 5 2 0 2 5 3 0 3 5 

# Resi n Monome rConten t (% HAP ) 4 0 4 5

O 0.01 8 in/1 0 min/2 lb s pe rmin
. o 0.01 8 i n 710 min/ 4 lb s pe rmin
. A0.01 8 in./2 0 min/ 2 lb s pe rmin
. x0.01 8 in./2 0 min/4 lb s pe rmin
. X0.02 4 in/1 0 min/2 lb s pe rmin
. - 0.02 4 in./1 0 min/4 lb s pe rmin
. O 0.02 4 in./2 0 min/ 2 lb s pe rmin
. + 0.02 4 in/2 0 min/ 4 lb s pe rmin
. Linea r( b = 0 ) tjnea r( b * constant ) Powe r( n = constant ) 2n d Orde rPoly
. 

# 5 0



# -a

# y/r/trr 7 

# "

Reinforce d Plastic/Composite s MAC TMode l fo rMechanica l Resi n Applicatio n 45 0 40 0
-7=- 35 0

< ^ResAP/ton(IbsHssionsAPEmis



# X 30 0 2b0 20 0 15 0
10 0 5 0

1 0 1 5 2 0 2 5 3 0 Resi n Monome rConten t (% HAP ) 3 5 4 0 4 5 5 0

O 0.04 0 in/1 5 min/ 2 lbs pe rmin . © 0.04 0 in71 5 min7 4 lbs pe rmin . A0.04 0 in./3 0 min./ 2 lbs pe rmin . x0.04 0 in73 0 min7 4 lbs pe rmin . X0.08 0 in/1 5 min/ 2 lbs pe rmin . •0.080in715min7 4 lbs pe rmin . o 0.08 0 in73 0 min./ 2 lbs pe rmin . + 0.08 0 in./3 0 min7 4 lbs pe rmin . Linea r( b = 0 ) Linea r( b » constant) Powe r( n = constant) 2n d Orde rPoly . 

# T D

# ^/PA'TT

Reinforce d Plastic/Composite s MAC TMode l fo rFilamen t Windin g Applicatio n 25 0

15 0 20 0 

# c o 

# fi 

# s c o < X C O 

# J O tn 

# < T ^ | 10

0 C O 

# I U J 

## C L < X 5 0 

# Linea r(f r= p ) 3.9804X. ;



# -~— : : . - - -.:. . tear( b = constant ) 

# !^0889xV : 

# 46.4333 J



## Orde rPolynomia l 

# :'a0293x 2 

# ^2.7145 x Th e equation s shown.ar e possibl e equation s t o b e use d MAC Tmodel'poin t ".valu e syste m designe d t o accuratel yreflec t e r variou s emissio n re c coul d choos e t o r

r equation s show n s h emissions . luctio n credit s t o th e .cilit y Th e o d fo rpredictin g


# 1 0 1 5 20 2 5 3 0

Resi n Monome rConten t (%HAP ) 3 5 4 0 4 5 5 0

O 7 3 degrees/ 6 inche s o 7 3 degrees/3 3 inche s A8 5 degrees/ 6 inche s x8 5 degrees/3 3 inche s Linea r( b = 0 ) Linea r( b •constant ) Powe r( n = constant ) 2n d Orde rPoly
.