## (918) 307-8865 or (888) 461-8778 www.airhygiene.com Corporate Headquarters 5634 S. 122nd E. Ave. Ste. F Tulsa, Oklahoma 74146 West Coast Field Office 5925 E. Lake Mead Blvd. Las Vegas, Nevada 89156 East Coast Field Office 8900 State Road Philadelphia, Pennsylvania 19136 

## Gulf Coast Field Offices Humble, Texas 77338 Ft. Worth, Texas 76028 Shreveport, Louisiana 71115 

# S T A C K E M I S S I O N S S T U D Y F O R T H E 3 8 0 C U B I C I N C H ( 6

. 2 L I T E R )

, 8 0 H O R S E P O W E R G A S

- F I R E D 4

- S T R O K E R I C H B U R N E N G I N E P R E P A R E D F O R B P A M E R I C A P R O D U C T I O N C O M P A N Y A N D C H E S A P E A K E E N E R G Y I N T U L S A C O U N T Y

, O K L A H O M A M A R C H 5

, 2 0 1 0

# STACK EMISSIONS STUDY FOR THE 380 CUBIC INCH (6.2 LITER), 80

HORSEPOWER GAS-FIRED 4- STROKE RICH B URN ENGINE PREPARED FOR BP AMERICA PRODUCTION COMPANY AND CHESAPEAKE ENERGY IN TULSA COUNTY, OKLAHOMA MARCH 5, 2010

Prepared and Reviewed by:

Paul R.Little, Dir. of Customer Service Thom as K. Graham, PE, QSTI, Dir. of Operations

Mars A. Sharief, QSTI, Dir. of Specialty Testing

# i 

# Table of Contents

1.0 INTRODUCTION __________________________________________________________________ 1
1.1 TEST PURPOSE AND OBJECTIVES ______________________________________________________ 1
1.2 SUMMARY OF TEST PROGRAM _________________________________________________________ 1 1.2.1 Participating Organizations ________________________________________________________________________ 1 1.2.2 Plant Location __________________________________________________________________________________ 1 1.2.3 Equipment Te sted _______________________________________________________________________________ 1 1.2.4 Emission Points _________________________________________________________________________________ 1 1.2.5 Pollutants Measured _____________________________________________________________________________ 1 1.2.6 Date of Emissi on Test ____________________________________________________________________________ 1 

# 1.3 KEY PERSONNEL ______________________________________________________________________ 2 

# 2.0 SUMMARY OF TEST RESULTS ____________________________________________________ 2
3.1 PROCESS DESCRIPTION _______________________________________________________________ 3
3.2 SAMPLING LOCATION __________________________________________________________________ 3 

# 4.0 SAMPLING AND ANALYTICAL PROCEDURES ______________________________________ 3
4.1 TEST METHODS ________________________________________________________________________ 3
4.2 INSTRUMENT CONFIGURATION AND OPERATIONS FOR GAS ANALYSIS __________________ 3



# APPENDICES
Appendix A Test Results and Calculations
Appendix B Emission Data Records
Appendix C Calibration Gas Certifications
Appendix D Quality Assurance and Quality Control Data
Appendix E Fuel Analysis Records

# bp-10-hinton.ok-ftir#1-rpt 1 

# Stack Emissions Study 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine BP America Production Company and Chesapeake Energy Tulsa County, Oklahoma March 5, 2010

1.0 INTRODUCTION

Air Hygiene International, Inc. (A ir Hygiene) has completed the stack sampling survey for formaldehyde (HCHO) and oxygen (O 2 

# ) from the exhaust of the 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine for BP America Production Compan y and Chesapeake Energy in Tulsa County, Oklahoma. This report details the background, results, process descr iption, and the sampling/analysis methodology of the stack sampling survey conducted on March 5, 2010.



# 1.1 TEST PURPOSE AND OBJECTIVES

The purpose of the test was to conduct an emission test to document levels of selected pollutants at normal operation levels of the unit. The specific objective was to determine the emission concentration of HCHO and O 2 

# from the exhaust of a 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine.



# 1.2 SUMMARY OF TEST PROGRAM

The following list details pertinent inform ation related to this specific project:
1.2.1 Participating Organizations

 BP America Production Company and Chesapeake Energy

 Chesapeake Energy

 OneOK

 Arrow Engine Company

 Innovative Environmental Solutions, Inc.

 Air Hygiene 1.2.2 Plant Location

 Tulsa County, Oklahoma 1.2.3 Equipment Tested

 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine 1.2.4 Emission Points

 Exhaust from the 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine 1.2.5 Pollutants Measured

 HCHO

 O 2 

# 1.2.6 Date of Emission Test

 March 5, 2010

# bp-10-hinton.ok-ftir#1-rpt 2 

# 1.3 KEY PERSONNEL

BP America Production Company: Jeff Adams 281-366-3173 Arrow Engine Company: David Reak 918-583-5711 Chesapeake Energy: Donny Wallis 405-879-3613 OneOK: Lynn Reed 918-588-7380 Innovative Environmental Solutions, Inc.: Thomas McGrath 714-315-4040 Air Hygiene: Mars Sharief 918-307-8865



# 2.0 SUMMARY OF TEST RESULTS

Results from the sampling conducted on the 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine located in Tulsa County, Oklahoma on March 5, 2010 are summarized in the following table.

Parameter High Load Mid Load

Start Time (hh:mm:ss) 9:36:25 14:40:25 End Time (hh:mm:ss) 13:50:25 16:59:55 Run Duration (min / run) 60 30 Bar. Pressure (in. Hg) 29.09 29.03 Amb. Temp. (°F) 69 78 Rel. Humidity (%) 31 24 Spec. Humidity (lb water / lb air) 0.004634 0.005037 Avg. Stack Temp. (°F) 1,234 1,166 Stack Moisture (% ) 17.0 16.9 Rated Horsepower (hp) 80.4 80.4 Brake Horsepower (bhp) 75 65 Engine Speed (rpm) 1,800 1,800 Torque (ft-lbf) 219 189 HCHO (ppmvd) 44.12 50.50 HCHO (ppmvw) 36.64 41.97 O 2 (%) 1.32 2.35 

# TABLE 2.1 SUMMARY OF 380 CUBIC INCH (6.2 LITER), 80 HOR SEPOWER GAS-FIRED 4-STROKE RICH BURN ENGINE RESULTS

# bp-10-hinton.ok-ftir#1-rpt 3 

# 3.0 SOURCE OPERATION

3.1 PROCESS DESCRIPTION

The unit tested was an 380 Cubic Inch (6.2 Liter), 80 Ho rsepower Gas-Fired 4-Stroke Rich Burn Engine. The engine is rated at 80.4 horsepower. Th e engine emissions are vented to the atmosphere through an exhaust system extending from the engine. All exhaust samples were continuously drawn from the exhaust stack at the sample ports.



# 3.2 SAMPLING LOCATION

The sample ports were located approximately 70 inches above grade level on the exhaust system. The stack measures 2 inches in diameter with an elevation at the top of 70 inches above grade. The ports were 4.5 duct diameters downstream from the last point of interference and 5.5 duct diameters upstream from the stack exit to the atmosphere. All exhaust samples for gaseous emissions were continuously drawn from the exhaust system at the sample ports from a single point.



# 4.0 SAMPLING AND AN ALYTICAL PROCEDURES

4.1 TEST METHODS

The emission test on the 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine was performed following the United States Environmental Prot ection Agency (EPA) methods described by the Code of Federal Regulations (CFR). Table 4.1 outlin es the specific methods performed on March 5, 2010.

TABLE 4.1 SUMMARY OF SAMPLING METHODS

Pollutant or Parameter Sampling Method Analysis Method

Oxygen EPA Method 3a Paramagnetic Cell
Formaldehyde and H 2 

## O EPA Method 320 Fourier Transform Infrared



# 4.2 INSTRUMENT CONFIGURATION AND OPERATIONS FOR GAS ANALYSIS

The sampling and analysis procedures used during these t ests conform with the methods outlined in the Code of Federal Regulations (CFR), Title 40, Part 60, Appendix A, Methods 3a; and 40 CFR 63, Appendix A, Method 320.
Figure 4.1 depicts the sample system used for the HCHO and O 2 

# tests. A stainless steel probe was inserted into the sample port of the stack to extract gas measurements from the emission stream at a single point near the center of the stack. The gas sample was continuously pulled thro ugh the probe and transported, via a 35 foot heat-traced flexible stainless steel tubing, to a heated head pump and into the FTIR then to a stainless steel minimum-contact condenser designed to dry the sample. Transportation of the sample, through Teflon® tubing, continued into the sample manifold within the mobile laboratory via a stainless steel/Teflon® diaphragm pump. From the manifold, the sample was partitioned to the O 2 

# analyzer through rotameters that cont rolled the flow rate of the sample.

# bp-10-hinton.ok-ftir#1-rpt 4 Figure 4.1 shows that the sample system was also equippe d with a separate path through which a calibration gas could be delivered to the probe and back through the entire sampling system. This allowed for convenient performance of system bias checks and spiking procedures as required by the testing methods.

All instruments were housed in an air-conditioned, tr ailer-mounted mobile laborat ory. Gaseous calibration standards were provided in aluminum cylinders with the concentrations certified by the vendor. EPA Protocol No. 1 was used to determine the cylinder concentrations where applicable (i.e. O 2 

# calibration gases).
Table 4.2 provides a description of the analyzers used for the instrument portion of the tests. All data from the continuous monitoring instruments were recorded on a Logic Beach Portable Data Logging System Hyperlogger which retrieves calibrated electronic data from each inst rument every one second and reports an average of the collected data every 30 seconds. For target compounds me asured with the Fourier transform infrared (FTIR) spectrometer, interferograms consisting of 30 co-added scan s were recorded continuously during the test periods, and provided approximately 30-second av erage concentrations. Spectral data was analyzed by the MKS MG2000 software. Data records can be found in Appendix A and B of this report.
Three test runs of approximately 60 minutes each at the high load and three test runs of approximately 30 minutes each at the mid load were conducted on the 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine for HCHO and O 2 

# . The stack gas analysis for O 2 

# concentrations was performed in accor dance with procedures set forth in EPA Method 3a. The O 2 

# analyzer uses a paramagnetic cell detector.

An MKS Instruments - MultiGasTM Four ier Transform Infrared (FTIR) sp ectrometer was used for HCHO and H 2 

# O analysis per EPA Method 320. The FTIR spectrometer spectral resolution was 0.5 cm -1 

# . The system employed a silicon carbide infrared source at 1200oC, a helium neon reference laser, beam splitters, potassium bromide (KBr) cell window, front-surface optical tran sfer mirrors, and multi-pass absorption cells. MCT detectors were used and cooled with liquid nitrogen in or der to maintain a constant temperature of 77 Kelvin. The approximately 5.11-meter multi-pass path cells incorpor ated aspheric, aberration-correcting mirrors to increase the optical throughput and the detection sensitivity. Tr ansducers and thermocouples were connected directly to the insulated sample cells that provide the pressure and te mperatures of the sample streams. During testing, the temperature of the absorption cells was set at 191oC. El evated temperature prevented gas condensation within the cell and minimized compound adhesion to the cell walls and mirrors. The volume of the absorption cell was 0.5 liters, so at a sample gas flow rate of 4.0 liters per minut e, the sample gas in the cell is refreshed approximately four times during each measurement (30 seconds). Interfe rograms consisting of 30 co-added scans were recorded continuously during the test periods, and provided approximately 30-second average concentrations.

TABLE 4.2 ANALYTICAL INSTRUMENTATION

Parameter Model and Manufacturer Range Sensitivity Detection Principle

HCHO and H 2 

## O MKS 2030 User may select from multiple ranges 0.1 ppm Fourier Transform Infrared – FTIR

O 2 

## SERVOMEX 1440 0-25% 0.1% Paramagnetic cell, inherently linear.Figure 4.1EMISSIONS TESTING LABE:\SHARED\DRAWINGS\EMISSIONS TESTING LAB.PPT04/18/08 DRAWING:08-001 TKG COPYRIGHT©2008 AIR HYGIENE INTERNATIONAL, INC.5634 S. 122ndEast Ave, Suite FTulsa, Oklahoma 74146www.airhygiene.com(888) 461-8778 STACK EXHAUST

dual line heated sample umbilical



## FLOW CONTROL MANIFOLD

GAS CONDITIONER

CALIBRATION/ BIAS GAS BOTTLESHOT/WET ANALYZERSDATARECORDERVENTShown fully equipped. Some labs may not contain these featuresand others may contain additional features specific to certainscopes.COLD/DRY ANALYZERSO2, CO2, NOx, CO, SO2THC, VOCGAS DILUTERFTIRTEST TRAILER EXTERIORTEST TRAILER INTERIOR PROBE

HEATED PROBE FILTERHeated Teflon Tubing (pre-conditioned sample)Unheated Teflon Tubing (conditioned sample)Diluted Calibration GasCalibration GasElectronic Input/Output

LEGEND COMPUTER



# PROCESS INLET OR 2 ND 

# STACK

dual line heated sample umbilical



# PROBE HEATED PROBE FILTERVENTMANIFOLDCOLD/DRYANALYZERSHOT/WETO2, CO2, NOx,CO, SO2THC, VOC 

## CONDITIONERMOBILESECONDARYANALYZERSFIXEDPRIMARYANALYZERS

# APPENDIX A

TEST RESULTS AND CALCULATIONS

## Load Test Type Run Date Start Stop Time Sync High R&D 1-1 03/05/10 9:36:25 10:35:55 CST High R&D 1-2 03/05/10 11:22:25 12:21:55 CST High R&D 1-3 03/05/10 12:50:55 13:50:25 CST Mid R&D 2-1 03/05/10 14:40:25 15:09:55 CST Mid R&D 2-2 03/05/10 15:33:25 16:02:55 CST Mid R&D 2-3 03/05/10 16:30:25 16:59:55 CST TABLE A.1: EMISSIONS TESTING SCHEDULE

bp-10-hinton.ok-ftir#1-rpt

## Parameter High Load, Run - 1-1 High Load, Run - 1-2 High Load, Run - 1-3 Average

Start Time (hh:mm:ss) 9:36:25 11:22:25 12:50:55 9:36:25 End Time (hh:mm:ss) 10:35:55 12:21:55 13:50:25 13:50:25 Run Duration (min / run) 60 60 60 60 Bar. Pressure (in. Hg) 29.15 29.09 29.03 29.09 Amb. Temp. (°F) 61 72 74 69 Rel. Humidity (%) 37 29 26 31 Spec. Humidity (lb water / lb air) 0.004299 0.004914 0.004689 0.004634 Avg. Stack Temp. (°F) 1,235 1,232 1,233 1,234 Stack Moisture (% ) 16.8 16.5 17.6 17.0 Rated Horsepower (hp) 80.4 80.4 80.4 80.40 Brake Horse power (bhp) 75 75 75 75 Engine Speed (rpm) 1,800 1,800 1,800 1,800 Torque (ft-lbf) 219 219 219 219 HCHO (ppmvd) 44.00 44.64 43.71 44.12 HCHO (ppmvw) 36.62 37.29 36.00 36.64 O 2 (%) 1.31 1.37 1.28 1.32

Parameter Mid Load, Run - 2-1 Mid Load, Run - 2-2 Mid Load, Run - 2-3 Average

Start Time (hh:mm:ss) 14:40:25 15:33:25 16:30:25 14:40:25 End Time (hh:mm:ss) 15:09:55 16:02:55 16:59:55 16:59:55 Run Duration (min / run) 30 30 30 30 Bar. Pressure (in. Hg) 29.03 29.03 29.03 29.03 Amb. Temp. (°F) 77 78 79 78 Rel. Humidity (%) 26 26 21 24 Spec. Humidity (lb water / lb air) 0.005188 0.005454 0.004471 0.005037 Avg. Stack Temp. (°F) 1,164 1,166 1,167 1,166 Stack Moisture (% ) 16.9 16.9 16.8 16.9 Rated Horsepower (hp) 80.4 80.4 80.4 80.40 Brake Horse power (bhp) 65 65 65 65 Engine Speed (rpm) 1,800 1,800 1,800 1,800 Torque (ft-lbf) 188 189 189 189 HCHO (ppmvd) 50.61 50.58 50.33 50.50 HCHO (ppmvw) 42.04 42.02 41.86 41.97 O 2 (%) 2.34 2.34 2.38 2.35 380 CUBIC INCH (6.2 LITER), 80 HO RSEPOWER GAS-FIRED 4-STROKE RICH BURN ENGINE HIGH LOAD DATA SUMMARY TABLE A.2

TABLE A.3 380 CUBIC INCH (6.2 LITER), 80 HORSEPOWER GAS-FIRED 4-STROKE RICH BURN ENGINE MID LOAD DATA SUMMARY

bp-10-hinton.ok-ftir#1-rpt App. AEXAMPLE CALCULATIONS (FFACTOR)

Mark's Std Hdbk, 10th ed.,pg 4-26 High Heat Value Dry (HHV dry ), calc for Methane (single component for the fuel gas)

%

Mark's Std Hdbk, 10th ed., pg 4-26 Low Heat Value Dry (LHV dry ), calc for Methane (single component for the fuel gas)

%

Civil Eng. Ref. Man.,7th Ed.,pg 14-9/GPA Ref. Bulletin 181-86, App. C High Heat Value Wet (HHV wet ), calc for entire sample (all components of the fuel gas)

Btu/SCF

Civil Eng. Ref. Man.,7th Ed.,pg 14-9/GPA Ref. Bulletin 181-86, App. C Low Heat Value Wet (LHV wet ), calc for entire sample (all components of the fuel gas)

Btu/SCF

Lbs Component per Lb-Mol of Gas (CM), calc for Methane (single component for the fuel gas)

% lb

ASTM D 3588 Btu per Lb of Gas Gross ( GCV ) Fuel Molecular Weight (MW Fuel ) MW Fuel = lb/lb-mol + lb/lb-mol x + etc. =

lb/lb-mol Btu per Lb of Gas Net ( NCV )

=

x

Weight Percent of Component (C % ), methane

Weight Percent of Volatile Organic Compounds (VOC % )

lb/lb-mol lb/lb-mol VOC % = % + % + % + etc. = %

RM 19, (07-19-6), 12.1 Nomenclature

H C S N 2 O 2

Note: Lack of significant figures may cause rounding errors between actual calculations and example calculations. RM 19, (12-17-09), 12.2 Emission Rates of PM, SO 2 , and NOx. Select from the following sections the applicable procedure to compute the PM, SO 2 , or NOx emission rate (E) in lb/MMBtu. The pollutant concentration must be in lb/scf and the F factor must be in scf/MMBtu. If the pollutant concentration (C) is not in the appropriate units, use Table 19–1 in Section 17.0 to make the proper conversion. An F factor is the ratio of the gas volume of the products of combustion to the heat content of the fuel. The dry F factor (F d ) includes all components of combustion less water, the wet F factor (F w ) includes all components of combustion, and the carbon F factor (F c ) includes only carbon dioxide.

% ft 3 /lbmol

1.02 % x 10 6 Btu + K (scf/lb)/%

1.53

0.46 3.64

0.14 0.57 F d = x

% 8,650.83 SCF 22,940.58 Btu MMBtu - lb

= x lb . % lb . %

lb . % x 23.93 %

0.14 SCF x 0.46 SCF 2.17 0.57 SCF x lb . % % 20,674.57 Btu/lb Btu/SCF

MMBtu lb . % RM 19, (12-17-09), 12.3.2 Determined F Factors . If the fuel burned is not listed in Table 19–2 or if the owner or operator chooses to determine an F factor rather than use the values in Table 19–2, use the procedure below: 12.3.2.1 Equations. Use the eq

+ 3.64 SCF 0.69

72.88 SG =

0.06 0.5807

90.84 % 16.82

385.23 ft 3 /lbmol

C % = = 16.818 lb/lb-mol NCV = 902.61

16.82 15.28 x 100 =

+ x 0.00 lb/lb-mol

= 22,940.58 Btu/lb = 15.28

lb/lb-mol

28.96 lb/lb-mol

0.93 Btu/SCF 1.0236 = Btu SCF 853.04

Btu/SCF 978.44 =

881.80

CM = 95.23 100.00

lb/lb-mol 16.04 lb-mol

Btu/SCF

16.818 LHV wet = 902.61

x

GCV = 1,001.54 =

LHV dry = 95.23 x 895.75 100.00 Btu

= SCF 947.41 Btu SCF HHV dry = 95.23 x 994.85 100.00 SCF Btu

0.09

Eq. 19-13 385.23

1.53 SCF RM 19, (12-17-09), 2.0 Summary of Method, 2.1 Emission Rates. Oxygen (O 2 ) or carbon dioxide (CO 2 ) concentrations and appropriate F factors (ratios of combustion gas volumes to heat inputs) are used to calculate pollutant emission rates from pollutant concentrations.

ASTM D 3588 (SG) Specific Gravity 15.28 0.78 16.818 HHV wet = 1,001.54 1.0236 

##        
      

 GCM M SCF Btu HHV dry 

### 100 / %



##        

      

 NCM M SCF Btu LHV dry 

### 100 / %



##        

      

  MW M mol lb lb CM 100 / %



#    

#      CM mol lb lb MW Fuel 

### / 

#         


Fuel dry 

### MW G HHV lb Btu GCV /



#         


Fuel dry 

### MW G LHV lb Btu NCV /



##          

        

 100 % % Fuel 

### MW

CM C 

###      


AIR Fuel 

### MW MW SG



##        

 

#  18 8

8 3 % % 

### % H C

H C 

### M VOC factor D W HHV SCF Btu HHV dry

wet



### . / ) / ( 



### factor D W LHV SCF Btu LHV dry
wet



### . / ) / ( 



##  
GCV O K N K S K C K H K K F o n s c hd d 

### % % % % %

   



bp-10-hinton.ok-ftir#1-rpt App. AEXAMPLE CALCULATIONS (MKS FTIR SPIKE)

Dilution Factor (unitless)

or % 1 - % % %

Ideal matrix spike yield (ppmvw)

Percent Recovery (%)

- x

x 1 -

EXAMPLE CALCULATIONS (CALIBRATION)

Analyzer Calibration Error

% - % %

EXAMPLE CALCULATIONS (BIAS, DRIFT, AND CORRECTED RAW AVERAGE)

System Bias

% - % %

Drift Assessment

Eq. 7E-4 % - % %

Alternative Drift and Bias

Eq. Section 13.2 and 13.3 % - % %

Bias Adjusted Average

% % - %

Moisture Correction

ppmvw 1 -

Note: Lack of significant figures may cause rounding errors between actual calculations and example calculations. = 0.8983 11.02

41.67 44.04 0.898 25.0 1 - 0.8983 44.04 ppmvw DF = = DF = 1.12

ppmvw + ppmvw x 0.898 =

Y ideal = Y ideal = 25.00 ppmvw x

0.898 =

-0.17 12.10

C W = Eq. 7E-5b x 100 = -0.17 6.01

SB = Eq. 7E-2 RM 7E, (12-17-09), 12.2 Analyzer Calibration Error. For non-dilution systems, use Equation 7E-1 to calculate the analyzer cal ibration error for the low-, mid-, and high-level calibration gases. (calc for O 2 analyzer mid gas, if applicable)

Eq. 7E-1

RM 7E, (12-17-09), 12.6 Effluent Gas Concentration. For each test run, calculate Cavg, the arithmetic average of all valid O 2 concentration values (e.g., 1- minute averages). Then adjust the value of Cavg for bias, using Equation 7E-5b. (calc for O 2 analyzer, Run 1, if applicable)

1.31 | = %

-0.01 %

| = x 100 =

0.25 RM 7E, (12-17-09), 12.3 System Bias. For non-dilution systems, use Equation 7E-2 to calculate the system bias separately for the low-level and upscale calibration gases. (calc for O 2 analyzer upscale gas, Run 1 initial bias, if applicable)

% -0.01 5.99 12.10

RM 7E, (12-17-09), 12.5 Drift Assessment. Use Equation 7E-4 to separately calculate the low-level and upscale drift over each test run. (calc for O 2 analyzer upscale drift, Run 1, if applicable)

D = |

RM 7E, (12-17-09), 13.2 / 13.3 System Bias and Drift. Alternatively, the results are acceptable if |Cs – Cdir| is ≤ 0.5 ppmv or if |Cs – Cv| is ≤ 0.5 ppmv (as applicable). (calc for O 2 analyzer initial upscale, Run 1, if applicable)

5.99 6.01 0.02

RM 7E, (12-17-09), 12.10 Moisture Correction. Use Equation 7E-10 if your measurements need to be corrected to a dry basis. (c alc for O 2 analyzer, Run 1, if applicable) Note: Calculations may not match as Run 1 results are typically also bias adjusted

Eq. 7E-10 C D = ppmvd 1 - = 5.98 = 1.30 C Gas =

36.62 = 16.77 ppmvw 44.00 6.01

% -

or inversely, 44.00 ACE =

16.77 ppmvd x 36.62 % x -0.17 -0.41

6.03 SB / D Alt = | 6.03 42.1

82.9%



### 100       


 CS C C ACE V Dir

WS W D 

### B C C

  1 100       


 CS C C SB Dir S

i final 

### SB SB D





Dir S Alt 

### C C D SB

  /



#          

 

 
O M MA O Avg Gas 

### C C C C C C



##   WS D W 

### B C C

   1 

##   DF AVG DF Cert Y stack conc ideal 

###  

   1



##     DF Cert DF etAvg T etAvg T ery

conc stack spike



###   



 1 arg arg (%) cov Re stack spike

tracer no 

### DiluentAvg DiluentAvg ctor DilutionFa 

 cylinder spike

tracer with 

### DiluentAvg DiluentAvg ctor DilutionFa 



 

### 1

bp-10-hinton.ok-ftir#1-rpt App. ARM 7E, (08-15-06), 12.1 Nomenclature. The terms used in the equations are defined as follows:

ACE = Analyzer calibration error, percent of calibration span. B WS = Moisture content of sample gas as measured by Method 4 or other approved method, percent/100. C Avg = Average unadjusted gas concentration indicated by data recorder for the test run. C D = Pollutant concentration adjusted to dry conditions. C Dir = Measured concentration of a calibration gas (low, mid, or high) when introduced in direct calibration mode. C Gas = Average effluent gas concentration adjusted for bias. C M = Average of initial and final system calibration bias (or 2-point system calibration error) check responses for the upscale calibration gas. C MA

= Actual concentration of the upscale calibration gas, ppmv. C O

= Average of the initial and final system calibration bias (or 2-point system calibration error) check responses from the low-level (or zero) calibration gas. C S = Measured concentration of a calibration gas (low, mid, or high) when introduced in system calibration mode. C SS = Concentration of NOx measured in the spiked sample. C Spike = Concentration of NOx in the undiluted spike gas. C Calc = Calculated concentration of NOx in the spike gas diluted in the sample. C V

= Manufacturer certified concentration of a calibration gas (low, mid, or high). C W = Pollutant concentration measured under moist sample conditions, wet basis. CS = Calibration span. D = Drift assessment, percent of calibration span. E p = The predicted response for the low-level and mid-level gases based on a linear response line between the zero and high-level response. Eff NO2 = NO 2 to NO converter efficiency, percent. H = High calibration gas, designator. L = Low calibration gas, designator. M = Mid calibration gas, designator. NOFinal = The average NO concentration observed with the analyzer in the NO mode during the converter efficiency test in Sectio n 16.2.2. NOxCorr = The NOx concentration corrected for the converter efficiency. NOxFinal = The final NOx concentration observed during the converter efficiency test in Section 16.2.2. NOxPeak = The highest NOx concentration observed during the converter efficiency test in Section 16.2.2. Q Spike = Flow rate of spike gas introduced in system calibration mode, L/min. Q Total = Total sample flow rate during the spike test, L/min. R = Spike recovery, percent. SB = System bias, percent of calibration span. SB i = Pre-run system bias, percent of calibration span. SB f

= Post-run system bias, percent of calibration span. SB / D Alt = Alternative absolute difference criteria to pass bias and/or drift che cks. SCE = System calibration error, percent of calibration span. SCE i = Pre-run system calibration error, percent of calibration span. SCE final = Post-run system calibration error, percent of calibration span. Z = Zero calibration gas, designator.

Small Engine and FTIR Nomenclature. The terms used in the equations are defined as follows:

bhp = brake horsepower hp = horsepower Q sys = system flow (lpm) Q m

= matrix spike flow (lpm)

bp-10-hinton.ok-ftir#1-rpt App. ARM 19, (07-29-06), 12.1 Nomenclature. The terms used in the equations are defined as follows:

AdjFactor = Percent oxygen or carbon dioxide adjustment applied to a target pollutant B wa = Moisture fraction of ambient air, percent. Btu = British thermal unit % C = Concentration of carbon from an ultimate analysis of fuel, weight percent. % CO2d ,% CO2w = Concentration of carbon dioxide on a dry and wet basis, respectively, percent. CIP / CDP = Combustor inlet pressure / compressor discharge pressure (mm Hg); note, some manufactures reference as PCD. E = Pollutant emission rate, ng/J (lb/million Btu). E a = Average pollutant rate for the specified performance test period, ng/J (lb/m illion Btu). E ao , E ai = Average pollutant rate of the control device, outlet and inlet, respectively, for the performance test period, ng/J (lb/mill ion Btu). E bi = Pollutant rate from the steam generating unit, ng/J (lb/m illion Btu). E bo = Pollutant emission rate from the steam generating unit, ng/J (lb/m illion Btu). E ci = Pollutant rate in combined effluent, ng/J (lb/m illion Btu). E co = Pollutant emission rate in combined effluent, ng/J (lb/m illion Btu). E d = Average pollutant rate for each sampling period (e.g.,24-hr Method 6B sample or 24-hr fuel sample) or for each fuel lot (e.g ., amount of fuel bunkered), ng/J (lb/m illion Btu). E di = Average inlet SO 2 rate for each sampling period d, ng/J (lb/million Btu). E g = Pollutant rate from gas turbine, ng/J (lb/million Btu). E ga = Daily geometric average pollutant rate, ng/J (lbs/m illion Btu) or ppm corrected to 7 percent O 2 . E jo ,E ji = Matched pair hourly arithmetic average pollutant rate, outlet and inlet, respectively, ng/J (lb/m illion Btu) or ppm corrected to 7 percent O 2 . E h = Hourly average pollutant, ng/J (lb/m illion Btu). E hj = Hourly arithmetic average pollutant rate for hour "j," ng/J (lb/m illion Btu) or ppm corrected to 7 percent O 2 . EXP = Natural logar ithmic base (2.718) raised to the value enclosed by brackets. Fc = Ratio of the volume of carbon dioxide produced to the gross calorific value of the fuel from Method 19 F d , F w , F c = Volumes of combustion components per unit of heat content, scm/J (scf/m illion Btu). ft 3 = cubic feet G = ideal gas conversion factor

(385.23 SCF/lb-mol at 68 deg F & 14.696 psia) GCM = gross Btu per SCF (constant, compound based) GCV = Gross calorific value of the fuel consistent with the ultimate analysis, kJ/kg (Btu/lb). GCV p , GCV r = Gross calorific value for the product and raw fuel lots, respectively, dry basis, kJ/kg (Btu/lb). % H = Concentration of hydrogen from an ultimate analysis of fuel, weight percent. H b = Heat input rate to the steam generating unit from fuels fired in the steam generating unit, J/hr (m illion Btu/hr). H g = Heat input rate to gas turbine from all fuels fired in the gas turbine, J/hr (m illion Btu/hr). % H2O = Concentration of water from an ultimate analysis of fuel, weight percent. H r = Total numbers of hours in the performance test period (e.g., 720 hours for 30-day performance test period). K = volume of combustion component per pound of component (constant) K = Conversion factor, 10 − 5 (kJ/J)/(%) [10 6 Btu/million Btu]. K c = (9.57 scm/kg)/% [(1.53 scf/lb)/%]. K cc = (2.0 scm/kg)/% [(0.321 scf/lb)/%]. K hd = (22.7 scm/kg)/% [(3.64 scf/lb)/%]. K hw

= (34.74 scm/kg)/% [(5.57 scf/lb)/%]. K n = (0.86 scm/kg)/% [(0.14 scf/lb)/%]. K o = (2.85 scm/kg)/% [(0.46 scf/lb)/%]. K s = (3.54 scm/kg)/% [(0.57 scf/lb)/%].
K sulfur = 2x10 4 Btu/wt%-MMBtu K w

= (1.30 scm/kg)/% [(0.21 scf/lb)/%]. lb = pound ln = Natural log of indicated value. L p ,L r = Weight of the product and raw fuel lots, respectively, metric ton (ton). % N = Concentration of nitrogen from an ultimate analysis of fuel, weight percent. M % = mole percent mol = mole MW = molecular weight (lb/lb-mol) MW AIR = molecular weight of air ( lb/lb-mole) 1 NCM = net Btu per SCF (constant based on compound) % O

= Concentration of oxygen from an ultimate analysis of fuel, weight percent. % O2d , % O2w = Concentration of oxygen on a dry and wet basis, respectively, percent. P B = barometirc pressure, in Hg P s = Potential SO2 emissions, percent. % S = Sulfur content of as-fired fuel lot, dry basis, weight percent. S e = Standard deviation of the hourly average pollutant rates for each performance test period, ng/J (lb/m illion Btu). % Sf

= Concentration of sulfur from an ultimate analysis of fuel, weight percent. S(wt%) = weight percent of sulfur, per lab analysis by appropriate ASTM standard S i = Standard deviation of the hourly average inlet pollutant rates for each performance test period, ng/J (lb/m illion Btu). S o = Standard deviation of the hourly average emission rates for each performance test period, ng/J (lb/m illion Btu). %S p , %S r = Sulfur content of the product and raw fuel lots respectively, dry basis, weight percent. SCF = standard cubic feet SH = specific humidity, pounds of water per pound of air t 0.95 = Values shown in Table 19-3 for the indicated number of data points n.
T amb = ambient temperature, o F W/D Factor = = conv. at 14.696 psia and

68 deg F (ref. Civil Eng. Ref. Manual, 7th Ed.) X CO2 =CO 2 Correction factor, percent. X k

= Fraction of total heat input from each type of fuel k. 1.0236 28.9625

bp-10-hinton.ok-ftir#1-rpt App. A

## The following information supports the spreadsheets for this testing project.

Given Data:

High Heating Values (HHV) are used for the Fuel Heating Value, F-Factor, and Fuel Flow Data per EPA requirements.

Molecular Weight of NOx (lb/lb-mole) = 46.01 Conversion Constant for NOx = Molecular Weight of CO (lb/lb-mole) = 28.00 Conversion Constant for CO = Molecular Weight of SO 2 (lb/lb-mole) = 64.00 Conversion Constant for SO 2 = Molecular Weight of THC (propane) (lb/lb-mole) = 44.00 Conversion Constant for THC = Molecular Weight of VOC (methane) (lb/lb-mole) = 16.00 Conversion Constant for VOC (methane) = Molecular Weight of NH 3 (lb/lb-mole) = 17.03 Conversion Constant for NH 3 = Molecular Weight of HCHO (lb/lb-mole) = 30.03 Conversion Constant for HCHO = NOTE: units are lb/ppm*ft 3 

## Formulas: 1. Corrected Raw Average (C Gas 

### ), 40CFR60, App. A, RM 7E, Eq. 7E-5 (08/15/06) 5. Emission Rate in lb/hr

2. Correction to % O 2 

### , 40CFR60, App. A, RM 20, Eq. 20-5 (11/26/02) 6. Emission Rate in tons per year

3. Correction to % O 2 

### and ISO Conditions 7. Emission Concentration in lb/MMBtu (O 2 

### based)

4. Method 19 stack exhaust flow (scfh) 8. Emission Concentration in g/hp*hr 0.0000000726839 0.0000001661345

0.0000000779534 

### ASTM D 3588

0.0000000442074 0.0000001142175 0.0000000415336 0.0000001194351 

# Calculations , Formulas , and Constants

40CFR60, App. A., RM 19, Table 19-1 Ideal Gas Conversion Factor = 385.23 SCF/lb-mol at 68 deg F & 14.696 psia Fuel Heating Value is based upon Air Hygiene's fuel gas calculation sheet. All calculations are based upon a correction to 68 deg F & 14.696 psia



#          

 

 
O M MA O Avg Gas 

## C C C C C C



#        

    ) 2 ( ) arg ( 

# % 9

. 20 %

9

. 20

O Gas et T Gas adj 

# C AdjFactor C C

) 2 ( / 

# % 9

. 20 % 9

. 20

O Gas C d Gas MMBtu lb 

# C Conv Factor F C E

   

 

# G MW Q C E S Gas hr lb 

#    6 / 

# 10

       

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 ) 2 ( 

## % 9

. 20 % 9

. 20 000
, 000
, 1 O Gas f S 

## C HHV Q FFactor Q 

# 2000 / / year hr lb
yr ton 

# hr E E 



    53

. 1
00633

. 0 19 

# 288        

     

a

H

o r Adj ISO 

# T e P P C C O



## hp E or mw E E hr lb hr lb hr hp g 

## 6

. 453 022

. 1314 6

. 453 / / / 

## 

 







## bp-10-hinton.ok-ftir#1-rpt App. A

# APPENDIX B

EMISSION DATA RECORDS

## UNITS 1-1 1-2 1-3 2-1 2-2 2-3
Start Time hh:mm:ss 

## 09:36:25 11:22:25 12:50:55 14:40:25 15:33:25 16:30:25


## End Time hh:mm:ss 

## 10:35:55 12:21:55 13:50:25 15:09:55 16:02:55 16:59:55


## Bar. Pressure in. Hg 

## 29.15 29.09 29.03 29.03 29.03 29.03 Amb. Temp. °F 

## 61 72 74 77 78 79 Rel. Humidity % 

## 37 29 26 26 26 21 Spec. Humidity lb water / lb air 

### 0.004299 0.004914 0.004689 0.005188 0.005454 0.004471 

## Load Designator High High High Mid Mid Mid Avg. Stack Temp. °F 

## 1235 1232 1233 1164 1166 1167
Stack Moisture % 

## 16.8 16.5 17.6 16.9 16.9 16.8 Rated Horsepower hp 

## 80.4 80.4 80.4 80.4 80.4 80.4 Brake Horsepower bhp 

## 75 75 75 65 65 65 Engine Speed rpm 

## 1,800 1,800 1,800 1,800 1,800 1,800 Torque ft-lbf 

## 219 219 219 188 189 189

Manufacturer & Equipment: Tulsa County, Oklahoma

bp-10-hinton.ok-ftir#1 Plant Name or Location:
Date: Project Number: 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-

Stroke Rich Burn Engine 

# BP America Production Company and Chesapeake Energy

March 5, 2010

Test Load:



## RUN M. Sharief, 504, 212, and 120 

## Tester(s) / Test Unit(s): Multiple



## bp-10-hinton.ok-ftir#1-rptFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.15 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 37 % 61 o F Unit Data 0.004299 lb H 2 O / lb air Unit Load 75.0 horsepower Meas. Stack Moisture 16.8 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw)

03/05/10 09:36:25 8040 1.2947 36.5732 03/05/10 09:36:55 8070 1.2868 36.6867 03/05/10 09:37:25 8100 1.2556 36.5822 03/05/10 09:37:55 8130 1.2702 36.0353 03/05/10 09:38:25 8160 1.2622 36.3014 03/05/10 09:38:55 8190 1.2560 35.9772 03/05/10 09:39:25 8220 1.2643 36.4277 03/05/10 09:39:55 8250 1.2762 35.9313 03/05/10 09:40:25 8280 1.2771 36.7137 03/05/10 09:40:55 8310 1.2761 36.2156 03/05/10 09:41:25 8340 1.2751 36.6181 03/05/10 09:41:55 8370 1.2778 36.5373 03/05/10 09:42:25 8400 1.2840 37.0702 03/05/10 09:42:55 8430 1.2914 36.4662 03/05/10 09:43:25 8460 1.2903 36.8328 03/05/10 09:43:55 8490 1.2938 36.2469 03/05/10 09:44:25 8520 1.3012 37.0899 03/05/10 09:44:55 8550 1.2874 36.7262 03/05/10 09:45:25 8580 1.2917 36.6396 03/05/10 09:45:55 8610 1.2936 36.3261 03/05/10 09:46:25 8640 1.2895 36.5256 03/05/10 09:46:55 8670 1.2853 36.6754 03/05/10 09:47:25 8700 1.2823 36.8148 03/05/10 09:47:55 8730 1.2910 37.0257 03/05/10 09:48:25 8760 1.2813 36.1006 03/05/10 09:48:55 8790 1.2897 36.6848 03/05/10 09:49:25 8820 1.2856 36.9865 03/05/10 09:49:55 8850 1.2880 36.4612 03/05/10 09:50:25 8880 1.2891 36.2226 03/05/10 09:50:55 8910 1.2954 36.4348 03/05/10 09:51:25 8940 1.3069 36.6097 03/05/10 09:51:55 8970 1.2953 36.3657 03/05/10 09:52:25 9000 1.2924 36.3135 03/05/10 09:52:55 9030 1.2996 36.8415 03/05/10 09:53:25 9060 1.2876 36.6721 03/05/10 09:53:55 9090 1.2778 37.0009 03/05/10 09:54:25 9120 1.2870 36.5743 03/05/10 09:54:55 9150 1.2857 36.4475 03/05/10 09:55:25 9180 1.2862 36.8888 03/05/10 09:55:55 9210 1.2814 36.6750 03/05/10 09:56:25 9240 1.2879 36.0360 03/05/10 09:56:55 9270 1.2973 36.0474 03/05/10 09:57:25 9300 1.3023 36.6925 03/05/10 09:57:55 9330 1.2996 36.3384 03/05/10 09:58:25 9360 1.3010 36.6168 03/05/10 09:58:55 9390 1.2798 36.4380 03/05/10 09:59:25 9420 1.2794 36.1162 03/05/10 09:59:55 9450 1.2823 36.6935 03/05/10 10:00:25 9480 1.2894 37.0025 03/05/10 10:00:55 9510 1.2836 37.3103 03/05/10 10:01:25 9540 1.2813 36.3106 03/05/10 10:01:55 9570 1.2889 36.1343 03/05/10 10:02:25 9600 1.2848 36.2127 03/05/10 10:02:55 9630 1.2813 36.3960 03/05/10 10:03:25 9660 1.3107 36.5303 03/05/10 10:03:55 9690 1.2798 36.8667 03/05/10 10:04:25 9720 1.2808 36.2928 03/05/10 10:04:55 9750 1.2870 36.6174 03/05/10 10:05:25 9780 1.2987 36.2816 03/05/10 10:05:55 9810 1.3002 36.4966 03/05/10 10:06:25 9840 1.3129 36.3022 03/05/10 10:06:55 9870 1.3052 36.9779 03/05/10 10:07:25 9900 1.3132 36.3955 03/05/10 10:07:55 9930 1.3005 36.9208 03/05/10 10:08:25 9960 1.3102 37.1848 03/05/10 10:08:55 9990 1.3032 36.6609 03/05/10 10:09:25 10020 1.2975 36.6345 03/05/10 10:09:55 10050 1.3004 36.1725 03/05/10 10:10:25 10080 1.3183 36.8486 03/05/10 10:10:55 10110 1.3112 36.5682 03/05/10 10:11:25 10140 1.3075 37.1836 03/05/10 10:11:55 10170 1.3108 36.4030 Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

High Load, Run - 1-1

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.15 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 37 % 61 o F Unit Data 0.004299 lb H 2 O / lb air Unit Load 75.0 horsepower Meas. Stack Moisture 16.8 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw) Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

High Load, Run - 1-1

03/05/10 10:12:25 10200 1.3069 37.0560 03/05/10 10:12:55 10230 1.3033 36.3159 03/05/10 10:13:25 10260 1.3012 36.6266 03/05/10 10:13:55 10290 1.2889 36.5147 03/05/10 10:14:25 10320 1.2981 36.7160 03/05/10 10:14:55 10350 1.2942 36.6211 03/05/10 10:15:25 10380 1.2910 37.0447 03/05/10 10:15:55 10410 1.2951 36.8014 03/05/10 10:16:25 10440 1.2942 36.9498 03/05/10 10:16:55 10470 1.2997 37.0954 03/05/10 10:17:25 10500 1.3045 36.1948 03/05/10 10:17:55 10530 1.3085 36.5349 03/05/10 10:18:25 10560 1.2987 36.5107 03/05/10 10:18:55 10590 1.2974 36.4144 03/05/10 10:19:25 10620 1.3064 36.0775 03/05/10 10:19:55 10650 1.3014 36.9577 03/05/10 10:20:25 10680 1.3193 36.4489 03/05/10 10:20:55 10710 1.3071 36.2409 03/05/10 10:21:25 10740 1.3027 36.1946 03/05/10 10:21:55 10770 1.3140 37.2211 03/05/10 10:22:25 10800 1.3035 36.3887 03/05/10 10:22:55 10830 1.3070 36.9683 03/05/10 10:23:25 10860 1.3045 36.5261 03/05/10 10:23:55 10890 1.3079 37.1329 03/05/10 10:24:25 10920 1.3093 37.3029 03/05/10 10:24:55 10950 1.3125 37.0066 03/05/10 10:25:25 10980 1.3105 36.3824 03/05/10 10:25:55 11010 1.3204 37.1496 03/05/10 10:26:25 11040 1.3124 37.2747 03/05/10 10:26:55 11070 1.3020 36.3092 03/05/10 10:27:25 11100 1.3181 36.4401 03/05/10 10:27:55 11130 1.3123 36.2827 03/05/10 10:28:25 11160 1.3066 37.2753 03/05/10 10:28:55 11190 1.3062 36.4748 03/05/10 10:29:25 11220 1.3153 36.6759 03/05/10 10:29:55 11250 1.3209 36.6740 03/05/10 10:30:25 11280 1.3214 36.7532 03/05/10 10:30:55 11310 1.3159 36.8928 03/05/10 10:31:25 11340 1.3186 36.9561 03/05/10 10:31:55 11370 1.3087 36.6966 03/05/10 10:32:25 11400 1.3057 37.1147 03/05/10 10:32:55 11430 1.3066 36.6385 03/05/10 10:33:25 11460 1.3059 37.0713 03/05/10 10:33:55 11490 1.3057 37.4673 03/05/10 10:34:25 11520 1.3057 36.6001 03/05/10 10:34:55 11550 1.3233 36.5824 03/05/10 10:35:25 11580 1.3210 36.3139 03/05/10 10:35:55 11610 1.3080 36.7680

RAW AVERAGE 1.2968 36.6222

O 2 INST-22-0002 (%) Initial Zero -0.01 Final Zero 0.00 Avg. Zero -0.01

Initial UpScale 5.99 Final UpScale 5.96 Avg. UpScale 5.98

Upscale Cal Gas 6.03

O 2 HCHO 1.31 44.00 1.09 36.62 Serial Number:

Corrected Raw Average (ppm/% wet basis)Bias

EMISSIONS DATA

Corrected Raw Average (ppm/% dry basis)

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.09 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 29 % 72 o F Unit Data 0.004914 lb H 2 O / lb air Unit Load 75.0 horsepower Meas. Stack Moisture 16.5 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw)

03/05/10 11:22:25 14400 1.2741 37.1628 03/05/10 11:22:55 14430 1.2708 38.0666 03/05/10 11:23:25 14460 1.2784 36.6274 03/05/10 11:23:55 14490 1.2874 37.8663 03/05/10 11:24:25 14520 1.2789 37.1485 03/05/10 11:24:55 14550 1.2774 37.2726 03/05/10 11:25:25 14580 1.2797 36.8753 03/05/10 11:25:55 14610 1.2707 37.2580 03/05/10 11:26:25 14640 1.2729 37.1388 03/05/10 11:26:55 14670 1.2812 37.0914 03/05/10 11:27:25 14700 1.2762 36.7920 03/05/10 11:27:55 14730 1.2656 36.4460 03/05/10 11:28:25 14760 1.2737 36.4293 03/05/10 11:28:55 14790 1.2772 37.4703 03/05/10 11:29:25 14820 1.2772 36.1067 03/05/10 11:29:55 14850 1.2830 37.3790 03/05/10 11:30:25 14880 1.2882 37.2728 03/05/10 11:30:55 14910 1.2813 36.8192 03/05/10 11:31:25 14940 1.2827 36.6244 03/05/10 11:31:55 14970 1.2910 37.9194 03/05/10 11:32:25 15000 1.2889 36.8062 03/05/10 11:32:55 15030 1.2935 37.2607 03/05/10 11:33:25 15060 1.3031 36.6084 03/05/10 11:33:55 15090 1.3022 36.8951 03/05/10 11:34:25 15120 1.2960 37.5087 03/05/10 11:34:55 15150 1.2973 36.9914 03/05/10 11:35:25 15180 1.2899 37.8184 03/05/10 11:35:55 15210 1.2944 38.6002 03/05/10 11:36:25 15240 1.3185 37.8315 03/05/10 11:36:55 15270 1.3057 38.0490 03/05/10 11:37:25 15300 1.3116 37.4350 03/05/10 11:37:55 15330 1.3075 36.9712 03/05/10 11:38:25 15360 1.3071 36.8452 03/05/10 11:38:55 15390 1.3087 38.5038 03/05/10 11:39:25 15420 1.3123 37.5688 03/05/10 11:39:55 15450 1.3128 37.8672 03/05/10 11:40:25 15480 1.3139 36.2186 03/05/10 11:40:55 15510 1.3063 36.9092 03/05/10 11:41:25 15540 1.2999 37.2028 03/05/10 11:41:55 15570 1.2951 38.4809 03/05/10 11:42:25 15600 1.2866 37.2180 03/05/10 11:42:55 15630 1.2862 36.8704 03/05/10 11:43:25 15660 1.2963 37.0798 03/05/10 11:43:55 15690 1.3037 36.9666 03/05/10 11:44:25 15720 1.3044 36.7200 03/05/10 11:44:55 15750 1.3062 36.0951 03/05/10 11:45:25 15780 1.3066 37.1928 03/05/10 11:45:55 15810 1.3112 37.0381 03/05/10 11:46:25 15840 1.3057 37.0665 03/05/10 11:46:55 15870 1.3083 37.2369 03/05/10 11:47:25 15900 1.3010 36.9643 03/05/10 11:47:55 15930 1.3113 38.1512 03/05/10 11:48:25 15960 1.3209 37.0809 03/05/10 11:48:55 15990 1.3225 38.4001 03/05/10 11:49:25 16020 1.3262 37.3074 03/05/10 11:49:55 16050 1.3153 37.4840 03/05/10 11:50:25 16080 1.3038 36.5749 03/05/10 11:50:55 16110 1.3111 37.4644 03/05/10 11:51:25 16140 1.3108 36.7791 03/05/10 11:51:55 16170 1.3089 37.4080 03/05/10 11:52:25 16200 1.3095 37.6871 03/05/10 11:52:55 16230 1.3087 37.0068 03/05/10 11:53:25 16260 1.3105 37.3860 03/05/10 11:53:55 16290 1.3183 37.6018 03/05/10 11:54:25 16320 1.3144 36.7558 03/05/10 11:54:55 16350 1.3107 38.3442 03/05/10 11:55:25 16380 1.3160 37.2847 03/05/10 11:55:55 16410 1.3220 37.3555 03/05/10 11:56:25 16440 1.3160 36.2669 03/05/10 11:56:55 16470 1.3131 37.8038 03/05/10 11:57:25 16500 1.3166 37.0048 03/05/10 11:57:55 16530 1.3207 37.5443 Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

High Load, Run - 1-2

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.09 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 29 % 72 o F Unit Data 0.004914 lb H 2 O / lb air Unit Load 75.0 horsepower Meas. Stack Moisture 16.5 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw) Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

High Load, Run - 1-2

03/05/10 11:58:25 16560 1.3166 36.1728 03/05/10 11:58:55 16590 1.3112 37.2963 03/05/10 11:59:25 16620 1.3110 36.6657 03/05/10 11:59:55 16650 1.3184 38.9158 03/05/10 12:00:25 16680 1.3069 37.0454 03/05/10 12:00:55 16710 1.3106 37.3135 03/05/10 12:01:25 16740 1.3087 37.7220 03/05/10 12:01:55 16770 1.3055 36.6791 03/05/10 12:02:25 16800 1.3106 36.1561 03/05/10 12:02:55 16830 1.3152 37.4601 03/05/10 12:03:25 16860 1.3126 37.1678 03/05/10 12:03:55 16890 1.3067 37.5071 03/05/10 12:04:25 16920 1.3072 37.4593 03/05/10 12:04:55 16950 1.3105 37.8650 03/05/10 12:05:25 16980 1.3135 37.7016 03/05/10 12:05:55 17010 1.3051 36.4976 03/05/10 12:06:25 17040 1.2943 37.9373 03/05/10 12:06:55 17070 1.3009 37.2905 03/05/10 12:07:25 17100 1.3043 36.9616 03/05/10 12:07:55 17130 1.3090 36.2060 03/05/10 12:08:25 17160 1.3195 37.1618 03/05/10 12:08:55 17190 1.3197 37.8776 03/05/10 12:09:25 17220 1.3234 37.4414 03/05/10 12:09:55 17250 1.3201 36.9582 03/05/10 12:10:25 17280 1.3164 37.8714 03/05/10 12:10:55 17310 1.3286 37.9055 03/05/10 12:11:25 17340 1.3398 37.5214 03/05/10 12:11:55 17370 1.3384 37.8309 03/05/10 12:12:25 17400 1.3297 37.1738 03/05/10 12:12:55 17430 1.3169 39.2445 03/05/10 12:13:25 17460 1.3183 37.9337 03/05/10 12:13:55 17490 1.3174 36.6387 03/05/10 12:14:25 17520 1.3210 36.8606 03/05/10 12:14:55 17550 1.3218 36.5583 03/05/10 12:15:25 17580 1.3246 37.2361 03/05/10 12:15:55 17610 1.3292 37.1212 03/05/10 12:16:25 17640 1.3249 38.2877 03/05/10 12:16:55 17670 1.3196 37.0220 03/05/10 12:17:25 17700 1.3269 37.4981 03/05/10 12:17:55 17730 1.3257 38.2160 03/05/10 12:18:25 17760 1.3175 36.8820 03/05/10 12:18:55 17790 1.3145 36.9756 03/05/10 12:19:25 17820 1.3099 38.2828 03/05/10 12:19:55 17850 1.3150 37.8804 03/05/10 12:20:25 17880 1.3173 36.8911 03/05/10 12:20:55 17910 1.3160 37.5706 03/05/10 12:21:25 17940 1.3160 37.5752 03/05/10 12:21:55 17970 1.3144 36.9962

RAW AVERAGE 1.3061 37.2893

O 2 INST-22-0002 (%) Initial Zero 0.00 Final Zero -0.10 Avg. Zero -0.05

Initial UpScale 5.96 Final UpScale 5.91 Avg. UpScale 5.94

Upscale Cal Gas 6.03

O 2 HCHO 1.37 44.64 1.15 37.29 Serial Number:

Corrected Raw Average (ppm/% wet basis)Bias

EMISSIONS DATA

Corrected Raw Average (ppm/% dry basis)

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.03 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 26 % 74 o F Unit Data 0.004689 lb H 2 O / lb air Unit Load 75.0 horsepower Meas. Stack Moisture 17.6 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw)

03/05/10 12:50:55 19710 1.1680 36.4222 03/05/10 12:51:25 19740 1.1639 35.2614 03/05/10 12:51:55 19770 1.1671 35.2426 03/05/10 12:52:25 19800 1.1648 35.6762 03/05/10 12:52:55 19830 1.1643 35.5884 03/05/10 12:53:25 19860 1.1646 36.2774 03/05/10 12:53:55 19890 1.1754 35.6634 03/05/10 12:54:25 19920 1.1747 35.8784 03/05/10 12:54:55 19950 1.1613 36.3377 03/05/10 12:55:25 19980 1.1583 36.3982 03/05/10 12:55:55 20010 1.1675 35.9206 03/05/10 12:56:25 20040 1.1723 36.1731 03/05/10 12:56:55 20070 1.1798 35.9500 03/05/10 12:57:25 20100 1.1819 36.0952 03/05/10 12:57:55 20130 1.1899 35.8771 03/05/10 12:58:25 20160 1.1897 36.1882 03/05/10 12:58:55 20190 1.1724 35.9730 03/05/10 12:59:25 20220 1.1728 36.5688 03/05/10 12:59:55 20250 1.1750 36.1545 03/05/10 13:00:25 20280 1.1720 36.1031 03/05/10 13:00:55 20310 1.1554 35.6213 03/05/10 13:01:25 20340 1.1583 35.4132 03/05/10 13:01:55 20370 1.1476 35.7029 03/05/10 13:02:25 20400 1.1581 36.2895 03/05/10 13:02:55 20430 1.1650 35.8079 03/05/10 13:03:25 20460 1.1682 36.3876 03/05/10 13:03:55 20490 1.1713 36.3587 03/05/10 13:04:25 20520 1.1706 36.0888 03/05/10 13:04:55 20550 1.1677 35.8403 03/05/10 13:05:25 20580 1.1748 36.3113 03/05/10 13:05:55 20610 1.1665 35.5491 03/05/10 13:06:25 20640 1.1819 36.0295 03/05/10 13:06:55 20670 1.1718 35.6664 03/05/10 13:07:25 20700 1.1732 36.5697 03/05/10 13:07:55 20730 1.1742 36.5213 03/05/10 13:08:25 20760 1.1751 36.3604 03/05/10 13:08:55 20790 1.1837 36.2812 03/05/10 13:09:25 20820 1.1835 36.0781 03/05/10 13:09:55 20850 1.1782 35.4344 03/05/10 13:10:25 20880 1.1683 35.9882 03/05/10 13:10:55 20910 1.1751 35.9486 03/05/10 13:11:25 20940 1.1724 35.9968 03/05/10 13:11:55 20970 1.1616 36.4069 03/05/10 13:12:25 21000 1.1671 36.9301 03/05/10 13:12:55 21030 1.1625 35.6482 03/05/10 13:13:25 21060 1.1604 35.2507 03/05/10 13:13:55 21090 1.1606 35.6978 03/05/10 13:14:25 21120 1.1565 36.0649 03/05/10 13:14:55 21150 1.1594 36.4588 03/05/10 13:15:25 21180 1.1587 36.5898 03/05/10 13:15:55 21210 1.1690 36.1608 03/05/10 13:16:25 21240 1.1709 35.6304 03/05/10 13:16:55 21270 1.1681 35.8177 03/05/10 13:17:25 21300 1.1676 36.2627 03/05/10 13:17:55 21330 1.1602 36.4444 03/05/10 13:18:25 21360 1.1811 35.9437 03/05/10 13:18:55 21390 1.1777 35.7199 03/05/10 13:19:25 21420 1.1796 35.8458 03/05/10 13:19:55 21450 1.1687 36.4501 03/05/10 13:20:25 21480 1.1618 36.2940 03/05/10 13:20:55 21510 1.1659 35.6799 03/05/10 13:21:25 21540 1.1645 35.8088 03/05/10 13:21:55 21570 1.1579 35.8965 03/05/10 13:22:25 21600 1.1641 36.2515 03/05/10 13:22:55 21630 1.1563 35.8908 03/05/10 13:23:25 21660 1.1563 35.3258 03/05/10 13:23:55 21690 1.1592 35.7367 03/05/10 13:24:25 21720 1.1595 36.2202 03/05/10 13:24:55 21750 1.1659 36.5861 03/05/10 13:25:25 21780 1.1774 35.9331 03/05/10 13:25:55 21810 1.1747 36.2778 03/05/10 13:26:25 21840 1.1846 35.4508 Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

High Load, Run - 1-3

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.03 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 26 % 74 o F Unit Data 0.004689 lb H 2 O / lb air Unit Load 75.0 horsepower Meas. Stack Moisture 17.6 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw) Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

High Load, Run - 1-3

03/05/10 13:26:55 21870 1.1773 35.5059 03/05/10 13:27:25 21900 1.1766 38.4211 03/05/10 13:27:55 21930 1.1739 36.9409 03/05/10 13:28:25 21960 1.1725 35.5857 03/05/10 13:28:55 21990 1.1724 35.9353 03/05/10 13:29:25 22020 1.1667 35.3468 03/05/10 13:29:55 22050 1.1628 35.9998 03/05/10 13:30:25 22080 1.1570 35.4134 03/05/10 13:30:55 22110 1.1556 35.4062 03/05/10 13:31:25 22140 1.1534 35.6334 03/05/10 13:31:55 22170 1.1488 36.4199 03/05/10 13:32:25 22200 1.1491 35.2358 03/05/10 13:32:55 22230 1.1490 35.7795 03/05/10 13:33:25 22260 1.1462 35.9600 03/05/10 13:33:55 22290 1.1579 36.0313 03/05/10 13:34:25 22320 1.1600 36.0046 03/05/10 13:34:55 22350 1.1622 36.4357 03/05/10 13:35:25 22380 1.1503 35.7789 03/05/10 13:35:55 22410 1.1559 35.8353 03/05/10 13:36:25 22440 1.1588 35.6787 03/05/10 13:36:55 22470 1.1722 38.4850 03/05/10 13:37:25 22500 1.1710 37.2116 03/05/10 13:37:55 22530 1.1652 35.9878 03/05/10 13:38:25 22560 1.1698 35.2190 03/05/10 13:38:55 22590 1.1729 35.2360 03/05/10 13:39:25 22620 1.1700 35.3294 03/05/10 13:39:55 22650 1.1642 36.2930 03/05/10 13:40:25 22680 1.1612 35.9371 03/05/10 13:40:55 22710 1.1675 35.4169 03/05/10 13:41:25 22740 1.1606 35.6034 03/05/10 13:41:55 22770 1.1491 35.8589 03/05/10 13:42:25 22800 1.1586 35.4989 03/05/10 13:42:55 22830 1.1598 36.1512 03/05/10 13:43:25 22860 1.1536 35.2952 03/05/10 13:43:55 22890 1.1471 38.9547 03/05/10 13:44:25 22920 1.1454 36.2938 03/05/10 13:44:55 22950 1.1508 35.3286 03/05/10 13:45:25 22980 1.1597 35.5038 03/05/10 13:45:55 23010 1.1611 35.5050 03/05/10 13:46:25 23040 1.1581 35.0053 03/05/10 13:46:55 23070 1.1568 37.6901 03/05/10 13:47:25 23100 1.1552 37.2987 03/05/10 13:47:55 23130 1.1606 35.3169 03/05/10 13:48:25 23160 1.1540 35.0122 03/05/10 13:48:55 23190 1.1519 35.2526 03/05/10 13:49:25 23220 1.1570 35.1992 03/05/10 13:49:55 23250 1.1675 36.2918 03/05/10 13:50:25 23280 1.1666 35.4451

RAW AVERAGE 1.1654 35.9970

O 2 INST-22-0002 (%) Initial Zero -0.10 Final Zero -0.11 Avg. Zero -0.11

Initial UpScale 5.91 Final UpScale 5.84 Avg. UpScale 5.88

Upscale Cal Gas 6.03

O 2 HCHO 1.28 43.71 1.07 36.00 Serial Number:

Corrected Raw Average (ppm/% wet basis)Bias

EMISSIONS DATA

Corrected Raw Average (ppm/% dry basis)

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.03 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 26 %
77 o F Unit Data 0.005188 lb H 2 O / lb air Unit Load 65.0 horsepower Meas. Stack Moisture 16.9 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw)

03/05/10 14:40:25 26280 2.2144 42.5917 03/05/10 14:40:55 26310 2.2135 42.4319 03/05/10 14:41:25 26340 2.2061 42.1946 03/05/10 14:41:55 26370 2.2154 41.7298 03/05/10 14:42:25 26400 2.2124 42.8514 03/05/10 14:42:55 26430 2.2172 41.6719 03/05/10 14:43:25 26460 2.1979 42.6025 03/05/10 14:43:55 26490 2.2104 41.8065 03/05/10 14:44:25 26520 2.2182 42.2691 03/05/10 14:44:55 26550 2.2211 41.6831 03/05/10 14:45:25 26580 2.2211 42.1894 03/05/10 14:45:55 26610 2.2291 42.0597 03/05/10 14:46:25 26640 2.2335 42.2922 03/05/10 14:46:55 26670 2.2186 41.0986 03/05/10 14:47:25 26700 2.2170 41.9900 03/05/10 14:47:55 26730 2.2241 42.0999 03/05/10 14:48:25 26760 2.2255 42.3306 03/05/10 14:48:55 26790 2.2279 41.5395 03/05/10 14:49:25 26820 2.2339 41.5258 03/05/10 14:49:55 26850 2.2326 41.8707 03/05/10 14:50:25 26880 2.2291 42.7028 03/05/10 14:50:55 26910 2.2282 42.3705 03/05/10 14:51:25 26940 2.2016 41.9755 03/05/10 14:51:55 26970 2.2406 41.7673 03/05/10 14:52:25 27000 2.2432 41.6732 03/05/10 14:52:55 27030 2.2456 42.0100 03/05/10 14:53:25 27060 2.2355 41.1536 03/05/10 14:53:55 27090 2.2381 41.3661 03/05/10 14:54:25 27120 2.2330 42.1373 03/05/10 14:54:55 27150 2.2236 41.9464 03/05/10 14:55:25 27180 2.2179 42.1664 03/05/10 14:55:55 27210 2.2131 42.1124 03/05/10 14:56:25 27240 2.2173 41.6870 03/05/10 14:56:55 27270 2.2233 42.9292 03/05/10 14:57:25 27300 2.2245 41.3412 03/05/10 14:57:55 27330 2.2205 41.9388 03/05/10 14:58:25 27360 2.2249 41.6672 03/05/10 14:58:55 27390 2.2233 41.8926 03/05/10 14:59:25 27420 2.2253 42.7312 03/05/10 14:59:55 27450 2.2333 41.8102 03/05/10 15:00:25 27480 2.2340 41.9410 03/05/10 15:00:55 27510 2.2269 41.7319 03/05/10 15:01:25 27540 2.2147 41.9223 03/05/10 15:01:55 27570 2.2249 41.7493 03/05/10 15:02:25 27600 2.2266 42.0957 03/05/10 15:02:55 27630 2.2306 41.2047 03/05/10 15:03:25 27660 2.2313 42.0706 03/05/10 15:03:55 27690 2.2278 41.5120 03/05/10 15:04:25 27720 2.2264 42.0822 03/05/10 15:04:55 27750 2.2166 42.4532 03/05/10 15:05:25 27780 2.2110 42.7582 03/05/10 15:05:55 27810 2.2209 42.1525 03/05/10 15:06:25 27840 2.2261 42.0371 03/05/10 15:06:55 27870 2.2255 41.7198 03/05/10 15:07:25 27900 2.2263 41.9210 03/05/10 15:07:55 27930 2.2308 43.2294 03/05/10 15:08:25 27960 2.2264 42.0565 03/05/10 15:08:55 27990 2.2197 41.9882 03/05/10 15:09:25 28020 2.2162 42.7534 03/05/10 15:09:55 28050 2.2253 42.8777

RAW AVERAGE 2.2237 42.0411

O 2 INST-22-0002 (%) Initial Zero -0.11 Final Zero -0.07 Avg. Zero -0.09

Initial UpScale 5.84 Final UpScale 5.91 Avg. UpScale 5.88

Upscale Cal Gas 6.03

O 2 HCHO 2.34 50.61 1.96 42.04 Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

Serial Number:

Corrected Raw Average (ppm/% wet basis)Bias

EMISSIONS DATA

Corrected Raw Average (ppm/% dry basis) Mid Load, Run - 2-1

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.03 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 26 % 78 o F Unit Data 0.005454 lb H 2 O / lb air Unit Load 65.0 horsepower Meas. Stack Moisture 16.9 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw)

03/05/10 15:33:25 29460 2.2317 42.2637 03/05/10 15:33:55 29490 2.2403 42.0197 03/05/10 15:34:25 29520 2.2364 42.7533 03/05/10 15:34:55 29550 2.2337 42.4804 03/05/10 15:35:25 29580 2.2147 41.5783 03/05/10 15:35:55 29610 2.2257 41.5040 03/05/10 15:36:25 29640 2.2261 42.4139 03/05/10 15:36:55 29670 2.2239 42.3781 03/05/10 15:37:25 29700 2.2205 42.0032 03/05/10 15:37:55 29730 2.2282 41.8764 03/05/10 15:38:25 29760 2.2364 42.5035 03/05/10 15:38:55 29790 2.2299 41.7954 03/05/10 15:39:25 29820 2.2230 41.2672 03/05/10 15:39:55 29850 2.2227 42.5569 03/05/10 15:40:25 29880 2.2234 42.0627 03/05/10 15:40:55 29910 2.2170 41.9017 03/05/10 15:41:25 29940 2.2145 43.0937 03/05/10 15:41:55 29970 2.2231 41.8586 03/05/10 15:42:25 30000 2.2307 41.5639 03/05/10 15:42:55 30030 2.2308 42.1250 03/05/10 15:43:25 30060 2.2302 42.0905 03/05/10 15:43:55 30090 2.2318 41.1817 03/05/10 15:44:25 30120 2.2349 42.6072 03/05/10 15:44:55 30150 2.2354 42.0725 03/05/10 15:45:25 30180 2.2376 42.1400 03/05/10 15:45:55 30210 2.2240 43.2736 03/05/10 15:46:25 30240 2.2364 41.5050 03/05/10 15:46:55 30270 2.2339 41.4855 03/05/10 15:47:25 30300 2.2371 42.1314 03/05/10 15:47:55 30330 2.2451 41.8534 03/05/10 15:48:25 30360 2.2417 41.5020 03/05/10 15:48:55 30390 2.2364 42.5409 03/05/10 15:49:25 30420 2.2394 41.8203 03/05/10 15:49:55 30450 2.2346 42.4816 03/05/10 15:50:25 30480 2.2334 42.9490 03/05/10 15:50:55 30510 2.2303 42.7348 03/05/10 15:51:25 30540 2.2258 41.9657 03/05/10 15:51:55 30570 2.2360 41.8837 03/05/10 15:52:25 30600 2.2296 42.2614 03/05/10 15:52:55 30630 2.2283 42.4366 03/05/10 15:53:25 30660 2.2288 41.4529 03/05/10 15:53:55 30690 2.2242 41.3005 03/05/10 15:54:25 30720 2.2363 41.7190 03/05/10 15:54:55 30750 2.2308 41.7345 03/05/10 15:55:25 30780 2.2263 41.7304 03/05/10 15:55:55 30810 2.2349 42.8408 03/05/10 15:56:25 30840 2.2307 41.9817 03/05/10 15:56:55 30870 2.2243 41.5756 03/05/10 15:57:25 30900 2.2250 42.3578 03/05/10 15:57:55 30930 2.2369 42.3119 03/05/10 15:58:25 30960 2.2394 40.5143 03/05/10 15:58:55 30990 2.2418 41.3565 03/05/10 15:59:25 31020 2.2390 41.1754 03/05/10 15:59:55 31050 2.2329 42.2078 03/05/10 16:00:25 31080 2.2460 41.7296 03/05/10 16:00:55 31110 2.2459 42.0389 03/05/10 16:01:25 31140 2.2358 41.8003 03/05/10 16:01:55 31170 2.2372 42.7630 03/05/10 16:02:25 31200 2.2390 42.4833 03/05/10 16:02:55 31230 2.2414 41.3336

RAW AVERAGE 2.2319 42.0221

O 2 INST-22-0002 (%) Initial Zero -0.07 Final Zero -0.11 Avg. Zero -0.09

Initial UpScale 5.91 Final UpScale 5.90 Avg. UpScale 5.91

Upscale Cal Gas 6.03

O 2 HCHO 2.34 50.58 1.96 42.02 Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

Serial Number:

Corrected Raw Average (ppm/% wet basis)Bias

EMISSIONS DATA

Corrected Raw Average (ppm/% dry basis) Mid Load, Run - 2-2

bp-10-hinton.ok-ftir#1-rpt App. BFuel Data Weather Data Fuel Fd factor 8,651 SCF exh/MMBtu 29.03 in. Hg Fuel Heating Value (HHV) 1,002 Btu/SCF fuel 21 % 79 o F Unit Data 0.004471 lb H 2 O / lb air Unit Load 65.0 horsepower Meas. Stack Moisture 16.8 %

Date/Time Elapsed Time O 2 HCHO (mm/dd/yy hh:mm:ss) (seconds) (%) (ppmvw)

03/05/10 16:30:25 32880 2.2537 41.9668 03/05/10 16:30:55 32910 2.2630 42.2795 03/05/10 16:31:25 32940 2.2529 41.6832 03/05/10 16:31:55 32970 2.2588 42.2892 03/05/10 16:32:25 33000 2.2437 41.5651 03/05/10 16:32:55 33030 2.2465 41.4659 03/05/10 16:33:25 33060 2.2520 41.8781 03/05/10 16:33:55 33090 2.2632 42.0270 03/05/10 16:34:25 33120 2.2673 42.4823 03/05/10 16:34:55 33150 2.2603 42.5842 03/05/10 16:35:25 33180 2.2509 41.9982 03/05/10 16:35:55 33210 2.2645 41.8762 03/05/10 16:36:25 33240 2.2707 42.3857 03/05/10 16:36:55 33270 2.2729 41.8669 03/05/10 16:37:25 33300 2.2750 42.1544 03/05/10 16:37:55 33330 2.2767 41.6008 03/05/10 16:38:25 33360 2.2746 41.6348 03/05/10 16:38:55 33390 2.2765 41.9776 03/05/10 16:39:25 33420 2.2712 42.0214 03/05/10 16:39:55 33450 2.2650 42.1124 03/05/10 16:40:25 33480 2.2639 41.2358 03/05/10 16:40:55 33510 2.2647 42.0723 03/05/10 16:41:25 33540 2.2668 41.7283 03/05/10 16:41:55 33570 2.2526 41.1042 03/05/10 16:42:25 33600 2.2565 42.3924 03/05/10 16:42:55 33630 2.2726 41.4852 03/05/10 16:43:25 33660 2.2662 41.4472 03/05/10 16:43:55 33690 2.2757 41.0252 03/05/10 16:44:25 33720 2.2823 41.8971 03/05/10 16:44:55 33750 2.2728 41.5308 03/05/10 16:45:25 33780 2.2758 41.6660 03/05/10 16:45:55 33810 2.2776 41.5376 03/05/10 16:46:25 33840 2.2737 42.2809 03/05/10 16:46:55 33870 2.2711 42.2242 03/05/10 16:47:25 33900 2.2699 42.5847 03/05/10 16:47:55 33930 2.2628 42.5959 03/05/10 16:48:25 33960 2.2641 41.7484 03/05/10 16:48:55 33990 2.2686 42.5905 03/05/10 16:49:25 34020 2.2766 41.5940 03/05/10 16:49:55 34050 2.2708 41.9311 03/05/10 16:50:25 34080 2.2754 42.2657 03/05/10 16:50:55 34110 2.2629 42.2643 03/05/10 16:51:25 34140 2.2659 41.2336 03/05/10 16:51:55 34170 2.2620 41.7951 03/05/10 16:52:25 34200 2.2552 42.4577 03/05/10 16:52:55 34230 2.2611 40.7782 03/05/10 16:53:25 34260 2.2671 41.6273 03/05/10 16:53:55 34290 2.2806 41.3198 03/05/10 16:54:25 34320 2.2744 42.5119 03/05/10 16:54:55 34350 2.2714 41.5832 03/05/10 16:55:25 34380 2.2798 41.9193 03/05/10 16:55:55 34410 2.2639 42.3097 03/05/10 16:56:25 34440 2.2570 42.2854 03/05/10 16:56:55 34470 2.2590 42.0669 03/05/10 16:57:25 34500 2.2646 41.2632 03/05/10 16:57:55 34530 2.2679 41.4014 03/05/10 16:58:25 34560 2.2708 41.5177 03/05/10 16:58:55 34590 2.2788 41.5952 03/05/10 16:59:25 34620 2.2758 41.0186 03/05/10 16:59:55 34650 2.2720 41.8637

RAW AVERAGE 2.2668 41.8600

O 2 INST-22-0002 (%) Initial Zero -0.11 Final Zero -0.11 Avg. Zero -0.11

Initial UpScale 5.90 Final UpScale 5.90 Avg. UpScale 5.90

Upscale Cal Gas 6.03

O 2 HCHO 2.38 50.33 2.00 41.86 Barometric Pressure Relative Humidity Ambient Temperature Specific Humidity BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

Serial Number:

Corrected Raw Average (ppm/% wet basis)Bias

EMISSIONS DATA

Corrected Raw Average (ppm/% dry basis) Mid Load, Run - 2-3

bp-10-hinton.ok-ftir#1-rpt App. B

# APPENDIX C

CALIBRATION GAS CERTIFICATIONS

# APPENDIX D

QUALITY ASSURANCE AND QUALITY CONTROL DATA

# bp-10-hinton.ok-ftir#1-rpt 

# QA/QC PROGRAM

Air Hygiene ensures the quality and validity of its emission meas urement and reporting procedures through a rigorous quality assurance (QA) program. The program is developed and administer ed by an internal QA team and encompasses five major areas:
1. QA reviews of reports, labo ratory work, and field testing 2. Equipment calibration and maintenance 3. Chain-of-custody 4. Training 5. Knowledge of current test methods
Each of these areas is discussed individually below.

QA Reviews
Air Hygiene’s review procedure includes revi ew of each source test report, along with la boratory and fieldwork, by the QA Team. The most important review is the one that takes place before a test program begins. The QA Team works closely with technical division personnel to prepare and review test protocols. Test protocol review includes selection of appropriate test procedure s, evaluation of interferences or other restrictions that might preclude use of standard test procedures, and evaluation and/or de velopment of alternate procedures.
Equipment Calibration and Maintenance
The equipment used to conduct the emission measurements is ma intained according to the manufactur er’s instructions to ensure proper operation. In addition to the maintenance program, calibrations ar e carried out on each measurement device according to the schedule outlined by the Environmental Protection Agency. Quality control checks are also conducted in the field for each test program. Chain-of-Custody
Air Hygiene maintains full chain-of-custody documentation on all samples and data sheets. In addition to normal documentation of changes between field sample custodians, laboratory personnel, and field test personnel, Air Hygiene documents every individual who handles any test component in the field (e .g., probe wash, impinger loading and recove ry, filter loading and recovery, etc.). Samples are stored in a locked area to which only Air Hygiene personnel have access. Field data sheets are secured at Air Hygiene’s of fices upon return from the field.
Training
Personnel’s training is essential to ensure quality testing. Air Hygiene has formal and informal training programs, which incl ude:
1. Attendance at EPA-sponsored training courses 2. Enrollment in EPA correspondence courses 3 A requirement for all technicians to re ad and understand Air Hygiene’s QA manual 4. In-house training and QA meetings on a regular basis 5. Maintenance of training records
Knowledge of Current Test Methods
With the constant updating of standard test methods and the wide variety of emerging test procedures, it is essential that any qualified source tester keep abreast of new developm ents. Air Hygiene subscribes to services, which provide updates on EPA reference methods, rules, and regulations. Additionally, source test personn el regularly attend and present papers at testing and emissi on-related seminars and conferences. Air Hygiene personnel maintain memb ership in the Air and Waste Management Association and the American Industrial Hygiene Association.

# bp-10-hinton.ok-ftir#1-rpt 

# COMBUSTION TESTING QUAL ITY ASSURANCE ACTIVITIES

A number of quality assurance activities were undertaken before, dur ing, and after this testing project. This section of the r eport combined with the documentation in Appe ndix C describes each of those activities.
Each instrument’s response was checked and adjusted in the field prior to the collection of data via multi-point calibration. The instrument’s linearity was checked by adjusting its zero and span responses to zero nitrogen an d an upscale calibration gas in the range of the expected concentrations. The instru ment response was then challenged with other calibration gases of known concentratio n and accepted as being linear if the response of the other calibration ga ses agreed within plus or mi nus two percent of the range of predicted values. NO 2 

## to NO conversion was checked via direct connect with an EPA Protocol certified concentration of NO 2 

## in a balance of nitrogen. Conversion was verified to be between 90 and 110 percent.
After each test run, the analyzers were chec ked for zero and span drift. This allowe d each test run to be bracketed by calibra tions and documents the precision of the data just co llected. The criterion for acceptable data is that the instrument drift is no more than three percent of the full-scale response. The quality assurance worksheets in the following pages summarize all multipoint calibrati on checks and zero to span checks pe rformed during the tests. These worksheets (as prepared from the data records of Appendix A) show that no drifts in excess of three percent occurre d in the zero to span check s following each test run.
The sampling systems were leak checked by demonstrating that a vacuum greater than 10 in Hg could be held for at least one minu te with a decline of less than one inch of Hg. A leak test was c onducted after the sample system was set up and before the system was dismantled. This test was conducted to ensure that ambient air had not diluted the sample. Any leakage detected prior to the tests would be repaired and another leak check conducted before testing commenced. No leaks were found during the pre or post-test l eak checks.
The absence of leaks in the sampling system was also verified by a sampling system bi as check. The sampling system’s integrity was tested by comparing the responses of the analyzers to the calibration gases introduced via two paths. The first path was direc tly into the analyzer and the second path via the sample system at the sample probe. An y difference in the instru ment responses by thes e two methods was attributed to sampli ng system bias or leakage. Th e criterion for acceptance is agreem ent within five percent of th e span of the analyzer.
The control gases used to calibrate the instruments were analyzed and certified by the compressed gas vendors to plus or minus one percent accuracy for all gases. EPA Protocol No. 1 was used, wh ere applicable to assign the co ncentration values traceable to the National Institute of Standards and Technology (NIST), Standard Reference Materials (SRM’s). The gas calibration sheets as prepared by the vendor are contained in Appendix C.
Air Hygiene collected and reported the enclosed test data in accordance with the procedures and quality assurance activities de scribed in this test report. Air Hygiene makes no warranty as to the suitability of the test methods. Air Hygiene also assumes no lia bility relating to the interpretation and use of the test data.

INSTRUMENTAL ANALYSIS QUALITY ASSURANCE DATA


# Date: March 5, 2010 Company: BP America Production Company and Chesapeake Energy Location: Tulsa County, Oklahoma Techs: MS
Sample System Leak Check



# Date Sample System Leak Rate (l/min)
March 5, 2010 1 0

### Calibration Date: Client: BP America Production Company and Chesapeake Energy

O 2 Span (%) = 12.10

0.00 -0.07 -0.58 0.07 YES (%) 6.03 6.01 -0.17 0.02 YES (%) 12.10 12.08 -0.17 0.02 YES (%)

Linearity = 0.996 

### March 5, 2010

Instrument Response (%) Calibration Error (%) 

### SERVOMEX 1440 (O 2 Analyzer) Linearity Plot

Absolute

Conc.

(%) 

### SERVOMEX 1440 (O
2 

### Analyzer)

Pass or Fail (±2%,

≤ 0.5%) Certified Concentration (%)

0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00

0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00Instrument Response (%)

Certified Concentrations (%)

bp-10-hinton.ok-ftir#1-rpt App. DO 2 1.30 1.31 -0.01 0.00 -0.01 5.99 5.96 5.98 -0.07 6.01 6.03 0.50% 0.58% 0.08% -0.17% -0.41% 0.25% Initial Zero 0.06 Final Zero 0.07 Initial Upscale 0.02 Final Upscale 0.05 12.10 0.36 0.61

O 2 1.31 1.37 0.00 -0.10 -0.05 5.96 5.91 5.94 -0.07 6.01 6.03 0.58% -0.25% 0.83% -0.41% -0.83% 0.41% Initial Zero 0.07 Final Zero 0.03 Initial Upscale 0.05 Final Upscale 0.10 12.10 0.36 0.61

O 2 1.17 1.28 -0.10 -0.11 -0.11 5.91 5.84 5.88 -0.07 6.01 6.03 -0.25% -0.33% 0.08% -0.83% -1.40% 0.58% Initial Zero 0.03 Final Zero 0.04 Initial Upscale 0.10 Final Upscale 0.17 12.10 0.36 0.61 Avg. UpScale Sys Resp (Zero) Initial Zero Final Zero Avg. Zero DRIFT AND BIAS CHECK High Load, Run - 1-1 Raw Average Corrected Average

Initial UpScale Final UpScale

Sys Resp (Upscale)

Upscale Cal Gas Initial Zero Bias Final Zero Bias Zero Drift Initial Upscale Bias Final Upscale Bias Upscale DriftAlternativeSpecificationAbs Diff

Calibration Span 3% of Cal. Span (drift) 5% of Cal. Span (bias)

High Load, Run - 1-2 Raw Average DRIFT AND BIAS CHECK

Corrected Average Initial Zero Final Zero Avg. Zero Initial UpScale Final UpScale

Zero Drift Initial Upscale BiasAlternativeSpecificationAbs Diff

Calibration Span

Sys Resp (Zero) Sys Resp (Upscale)

Initial Upscale Bias Final Upscale Bias

Upscale Cal Gas Initial Zero Bias

Upscale DriftAlternativeSpecificationAbs Diff

5% of Cal. Span (bias)

DRIFT AND BIAS CHECK

Corrected Average Avg. UpScale Sys Resp (Zero) Sys Resp (Upscale)

Upscale Cal Gas Initial Zero Bias Final Zero Bias

Final Zero Bias Zero Drift Final Upscale Bias Upscale Drift

Final UpScale Avg. UpScale 3% of Cal. Span (drift) 5% of Cal. Span (bias)

High Load, Run - 1-3 Raw Average

Initial Zero Final Zero Avg. Zero Initial UpScale

Calibration Span 3% of Cal. Span (drift)

bp-10-hinton.ok-ftir#1-rpt App. DO 2 2.22 2.34 -0.11 -0.07 -0.09 5.84 5.91 5.88 -0.07 6.01 6.03 -0.33% 0.00% 0.33% -1.40% -0.83% 0.58% Initial Zero 0.04 Final Zero 0.00 Initial Upscale 0.17 Final Upscale 0.10 12.10 0.36 0.61

O 2 2.23 2.34 -0.07 -0.11 -0.09 5.91 5.90 5.91 -0.07 6.01 6.03 0.00% -0.33% 0.33% -0.83% -0.91% 0.08% Initial Zero 0.00 Final Zero 0.04 Initial Upscale 0.10 Final Upscale 0.11 12.10 0.36 0.61

O 2 2.27 2.38 -0.11 -0.11 -0.11 5.90 5.90 5.90 -0.07 6.01 6.03 -0.33% -0.33% 0.00% -0.91% -0.91% 0.00% Initial Zero 0.04 Final Zero 0.04 Initial Upscale 0.11 Final Upscale 0.11 12.10 0.36 0.61 DRIFT AND BIAS CHECK

DRIFT AND BIAS CHECK

DRIFT AND BIAS CHECK Initial Zero Final Zero Avg. Zero Mid Load, Run - 2-1

Initial Upscale Bias Initial UpScale Final UpScale Avg. UpScale Raw Average Corrected Average

Corrected Average

Upscale Cal Gas Initial Zero Bias Final Zero Bias Zero Drift

Final Upscale Bias Upscale DriftAlternativeSpecificationAbs Diff

Calibration Span 3% of Cal. Span (drift) 5% of Cal. Span (bias)

Mid Load, Run - 2-2 Sys Resp (Zero) Sys Resp (Upscale)

Raw Average

Initial Upscale Bias Final Upscale Bias Final Zero Bias Zero Drift Avg. Zero Initial UpScale Initial Zero Final Zero

Upscale Cal Gas Initial Zero Bias

Upscale DriftAlternativeSpecificationAbs Diff Final UpScale Avg. UpScale Sys Resp (Zero) Sys Resp (Upscale)

Final UpScale Avg. UpScale Calibration Span 3% of Cal. Span (drift) 5% of Cal. Span (bias)

Mid Load, Run - 2-3 Raw Average Corrected Average Initial Zero Final Zero Avg. Zero Initial UpScale

Calibration Span 3% of Cal. Span (drift) Sys Resp (Zero) Sys Resp (Upscale)

Upscale Cal Gas Initial Zero Bias Final Zero Bias Zero Drift Initial Upscale Bias Final Upscale Bias Upscale DriftAlternativeSpecificationAbs Diff

5% of Cal. Span (bias)

bp-10-hinton.ok-ftir#1-rpt App. D

### PRE-SPIKE (SF 6 Cylinder Conc.) Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:26:40 BP_SPK1_000038.LAB 

### 23.3805 10.6047 03/05/10 8:28:41 BP_SPK2_000001.LAB 

### 23.6156 11.0265 03/05/10 8:28:56 BP_SPK2_000002.LAB 

### 23.8858 11.0059 03/05/10 8:29:10 BP_SPK2_000003.LAB 

### 24.3208 10.9880 03/05/10 9:01:28 BP_SPK2_000135.LAB 

### 24.2999 11.0561 03/05/10 9:01:43 BP_SPK2_000136.LAB 

### 24.6018 11.0587 03/05/10 9:01:58 BP_SPK2_000137.LAB 

### 24.6369 11.0861 03/05/10 9:02:12 BP_SPK2_000138.LAB 

### 24.3894 11.0889 03/05/10 9:02:27 BP_SPK2_000139.LAB 

### 24.3188 11.0962 03/05/10 9:02:42 BP_SPK2_000140.LAB 

### 24.4966 11.0895 03/05/10 9:02:56 BP_SPK2_000141.LAB 

### 24.4631 11.0739 03/05/10 9:03:11 BP_SPK2_000142.LAB 

### 24.9707 11.1116

RAW AVERAGE 24.28 11.02

PRE-SPIKE (NATIVE) #1 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:22:01 BP_SPK1_000019.LAB 

### 44.0896 0.0000 03/05/10 8:22:16 BP_SPK1_000020.LAB 

### 44.8203 0.0000 03/05/10 8:22:31 BP_SPK1_000021.LAB 

### 42.1802 0.0000 03/05/10 8:22:45 BP_SPK1_000022.LAB 

### 43.7135 0.0000 03/05/10 8:23:00 BP_SPK1_000023.LAB 

### 43.5399 0.0000 03/05/10 8:23:15 BP_SPK1_000024.LAB 

### 44.8679 0.0000 03/05/10 8:23:29 BP_SPK1_000025.LAB 

### 43.8520 0.0000 03/05/10 8:23:44 BP_SPK1_000026.LAB 

### 42.0398 0.0000 03/05/10 8:23:59 BP_SPK1_000027.LAB 

### 42.6390 0.0000 03/05/10 8:24:13 BP_SPK1_000028.LAB 

### 43.5073 0.0000 03/05/10 8:24:28 BP_SPK1_000029.LAB 

### 44.5804 0.0000 03/05/10 8:24:43 BP_SPK1_000030.LAB 

### 44.6463 0.0000

RAW AVERAGE 43.71 0.00

SPIKE #1 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:29:54 BP_SPK2_000006.LAB 

### 42.1167 1.1650 03/05/10 8:30:09 BP_SPK2_000007.LAB 

### 41.7905 1.1510 03/05/10 8:30:24 BP_SPK2_000008.LAB 

### 41.8344 1.1393 03/05/10 8:30:39 BP_SPK2_000009.LAB 

### 41.0832 1.1430 03/05/10 8:30:53 BP_SPK2_000010.LAB 

### 41.6028 1.1293 03/05/10 8:31:08 BP_SPK2_000011.LAB 

### 41.3757 1.1263 03/05/10 8:31:23 BP_SPK2_000012.LAB 

### 41.7716 1.1276 03/05/10 8:31:37 BP_SPK2_000013.LAB 

### 41.4869 1.0961 03/05/10 8:31:52 BP_SPK2_000014.LAB 

### 41.5994 1.0945 03/05/10 8:32:07 BP_SPK2_000015.LAB 

### 41.9671 1.0973 03/05/10 8:32:21 BP_SPK2_000016.LAB 

### 41.5575 1.0967 03/05/10 8:32:36 BP_SPK2_000017.LAB 

### 41.8483 1.0931

RAW AVERAGE 41.6695 1.1216

PRE-SPIKE (NATIVE) #2 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:38:58 BP_SPK2_000043.LAB 

### 42.2382 0.0000 03/05/10 8:39:12 BP_SPK2_000044.LAB 

### 43.6596 0.0000 03/05/10 8:39:27 BP_SPK2_000045.LAB 

### 44.3045 0.0000 03/05/10 8:39:42 BP_SPK2_000046.LAB 

### 44.5421 0.0000 03/05/10 8:39:56 BP_SPK2_000047.LAB 

### 44.6184 0.0000 03/05/10 8:40:11 BP_SPK2_000048.LAB 

### 44.1893 0.0000 03/05/10 8:40:26 BP_SPK2_000049.LAB 

### 43.6282 0.0000 03/05/10 8:40:40 BP_SPK2_000050.LAB 

### 44.6329 0.0000 03/05/10 8:40:55 BP_SPK2_000051.LAB 

### 44.5720 0.0000 03/05/10 8:41:10 BP_SPK2_000052.LAB 

### 46.1940 0.0000 03/05/10 8:41:24 BP_SPK2_000053.LAB 

### 45.2220 0.0000 03/05/10 8:41:39 BP_SPK2_000054.LAB 

### 44.7310 0.0000

RAW AVERAGE 44.3777 0.0000 BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

bp-10-hinton.ok-ftir#1-rpt App. D

### BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

SPIKE #2 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:42:53 BP_SPK2_000059.LAB 

### 41.0406 1.5359 03/05/10 8:43:07 BP_SPK2_000060.LAB 

### 40.1857 1.5462 03/05/10 8:43:22 BP_SPK2_000061.LAB 

### 39.6279 1.5607 03/05/10 8:43:37 BP_SPK2_000062.LAB 

### 40.7046 1.5576 03/05/10 8:43:51 BP_SPK2_000063.LAB 

### 40.4455 1.5597 03/05/10 8:44:06 BP_SPK2_000064.LAB 

### 40.9481 1.5633 03/05/10 8:44:21 BP_SPK2_000065.LAB 

### 40.3227 1.5693 03/05/10 8:44:35 BP_SPK2_000066.LAB 

### 40.5634 1.5609 03/05/10 8:44:50 BP_SPK2_000067.LAB 

### 40.8212 1.5633 03/05/10 8:45:05 BP_SPK2_000068.LAB 

### 42.2135 1.5521 03/05/10 8:45:19 BP_SPK2_000069.LAB 

### 41.9751 1.5611 03/05/10 8:45:34 BP_SPK2_000070.LAB 

### 40.5655 1.5498

RAW AVERAGE 40.7845 1.5567

PRE-SPIKE (NATIVE) #3 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:46:33 BP_SPK2_000074.LAB 

### 41.1263 0.0000 03/05/10 8:46:47 BP_SPK2_000075.LAB 

### 44.0033 0.0000 03/05/10 8:47:02 BP_SPK2_000076.LAB 

### 44.1330 0.0000 03/05/10 8:47:17 BP_SPK2_000077.LAB 

### 44.3398 0.0000 03/05/10 8:47:32 BP_SPK2_000078.LAB 

### 45.0956 0.0000 03/05/10 8:47:46 BP_SPK2_000079.LAB 

### 44.4070 0.0000 03/05/10 8:48:01 BP_SPK2_000080.LAB 

### 44.4377 0.0000 03/05/10 8:48:15 BP_SPK2_000081.LAB 

### 44.3224 0.0000 03/05/10 8:48:30 BP_SPK2_000082.LAB 

### 44.5311 0.0000 03/05/10 8:48:45 BP_SPK2_000083.LAB 

### 44.6512 0.0000 03/05/10 8:49:00 BP_SPK2_000084.LAB 

### 43.8803 0.0000 03/05/10 8:49:14 BP_SPK2_000085.LAB 

### 44.1769 0.0000

RAW AVERAGE 44.0921 0.0000

SPIKE #3 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:50:28 BP_SPK2_000090.LAB 

### 43.2249 1.0229 03/05/10 8:50:42 BP_SPK2_000091.LAB 

### 42.1598 0.8980 03/05/10 8:50:57 BP_SPK2_000092.LAB 

### 42.1199 0.8621 03/05/10 8:51:12 BP_SPK2_000093.LAB 

### 42.5083 0.8507 03/05/10 8:51:26 BP_SPK2_000094.LAB 

### 43.5288 0.8305 03/05/10 8:51:41 BP_SPK2_000095.LAB 

### 42.5939 0.8230 03/05/10 8:51:56 BP_SPK2_000096.LAB 

### 41.2562 1.3336 03/05/10 8:52:10 BP_SPK2_000097.LAB 

### 41.0239 1.1354 03/05/10 8:52:25 BP_SPK2_000098.LAB 

### 41.2754 1.0910 03/05/10 8:52:40 BP_SPK2_000099.LAB 

### 41.0183 1.0939 03/05/10 8:52:54 BP_SPK2_000100.LAB 

### 41.0430 1.0771 03/05/10 8:53:09 BP_SPK2_000101.LAB 

### 41.1488 1.0791

RAW AVERAGE 41.9084 1.0081

bp-10-hinton.ok-ftir#1-rpt App. D

### BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

POST-SPIKE (NATIVE) #3 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 8:56:20 BP_SPK2_000114.LAB 

### 44.8999 0.0000 03/05/10 8:56:35 BP_SPK2_000115.LAB 

### 44.2860 0.0000 03/05/10 8:56:49 BP_SPK2_000116.LAB 

### 44.1478 0.0000 03/05/10 8:57:04 BP_SPK2_000117.LAB 

### 43.8094 0.0000 03/05/10 8:57:19 BP_SPK2_000118.LAB 

### 43.8366 0.0000 03/05/10 8:57:33 BP_SPK2_000119.LAB 

### 43.4817 0.0000 03/05/10 8:57:48 BP_SPK2_000120.LAB 

### 43.3690 0.0000 03/05/10 8:58:03 BP_SPK2_000121.LAB 

### 43.6913 0.0000 03/05/10 8:58:17 BP_SPK2_000122.LAB 

### 43.4388 0.0000 03/05/10 8:58:32 BP_SPK2_000123.LAB 

### 43.2360 0.0000 03/05/10 8:58:47 BP_SPK2_000124.LAB 

### 43.8534 0.0000 03/05/10 8:59:01 BP_SPK2_000125.LAB 

### 42.2709 0.0000

RAW AVERAGE 43.6934 0.0000


## Spiking Results Analyzer Make: MKS Analyzer Model: 2030 44.06 ppm 11.02 ppm 25.00 ppm

Spike Run No. Dilution Factor Ideal Spike Yield (ppm) Percent Recovery Pass/Fail (70-130%) Spike 1 0.8983 42.105 82.9% PASS Spike 2 0.8588 41.519 79.2% PASS Spike 3 0.9086 42.165 88.8% PASS

QA Notes: Certified Analyte (HCHO) cylinder concentration

1. Section 8.6.2 of EPA Method 320 requires the aver age spiked percent recovery must be between 70% to 130%. 2. Calibration and run spectral data are not included in this report. Electronic copies of this data are available upon request. Average Analyte ( HCHO) stack concentration Average Diluent (SF 6 ) concentration

bp-10-hinton.ok-ftir#1-rpt App. D

### PRE-SPIKE (NATIVE) #4 Date Time Spectrum NO 2 CH 4 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 10:32:51 BP_RUN1_000175.LAB 

### 17.0312 679.6944 03/05/10 10:33:21 BP_RUN1_000176.LAB 

### 16.6420 666.0416 03/05/10 10:33:50 BP_RUN1_000177.LAB 

### 16.9514 673.1234 03/05/10 10:34:20 BP_RUN1_000178.LAB 

### 17.2057 674.9401 03/05/10 10:34:49 BP_RUN1_000179.LAB 

### 17.3860 669.9728 03/05/10 10:35:18 BP_RUN1_000180.LAB 

### 16.9664 666.4608 03/05/10 10:35:48 BP_RUN1_000181.LAB 

### 17.0968 673.2807 03/05/10 10:36:17 BP_RUN1_000182.LAB 

### 17.2608 676.8401 03/05/10 10:36:46 BP_RUN1_000183.LAB 

### 16.6836 666.6027 03/05/10 10:37:16 BP_RUN1_000184.LAB 

### 17.2663 673.9172 03/05/10 10:37:45 BP_RUN1_000185.LAB 

### 17.0532 679.8010 03/05/10 10:38:14 BP_RUN1_000186.LAB 

### 17.4028 674.6746

RAW AVERAGE 17.0788 672.9458

SPIKE #4 Date Time Spectrum NO 2 CH 4 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 10:51:29 BP_SPK3_000052.LAB 

### 21.5989 543.6478 03/05/10 10:51:44 BP_SPK3_000053.LAB 

### 20.9310 522.7558 03/05/10 10:51:58 BP_SPK3_000054.LAB 

### 21.5871 524.0087 03/05/10 10:52:13 BP_SPK3_000055.LAB 

### 21.7992 532.9342 03/05/10 10:52:28 BP_SPK3_000056.LAB 

### 21.9134 528.6304 03/05/10 10:52:42 BP_SPK3_000057.LAB 

### 21.7124 536.1399 03/05/10 10:52:57 BP_SPK3_000058.LAB 

### 22.0378 513.2448 03/05/10 10:53:12 BP_SPK3_000059.LAB 

### 22.6378 496.4511 03/05/10 10:53:26 BP_SPK3_000060.LAB 

### 22.5916 493.8164 03/05/10 10:53:41 BP_SPK3_000061.LAB 

### 22.4788 490.9451 03/05/10 10:53:56 BP_SPK3_000062.LAB 

### 22.5065 452.3554 03/05/10 10:54:11 BP_SPK3_000063.LAB 

### 22.8083 528.2066

RAW AVERAGE 22.0502 513.5947



# Spiking Results Analyzer Make: MKS Analyzer Model: 2030 17.08 ppm 672.95 ppm 47.60 ppm

Spike Run No. Dilution Factor Ideal Spike Yield (pp m ) Percent Recover y Pass/Fail ( 70-130% ) Spike 4 0.7632 24.306 80.0% PASS

QA Notes: Certified Analyte (NO 2 ) cylinder concentration

1. Section 8.6.2 of EPA Method 320 requires the average spiked percent recovery must be between 70% to 130%. 2. Calibration and run spectral data are not included in this report. Electronic copies of this data are available upon request. BP America Production Company and Chesapeake Energy March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

Average Analyte (NO 2 ) stack concentration Average Diluent (CH 4 ) stack concentration

bp-10-hinton.ok-ftir#1-rpt App. D

### PRE-SPIKE (NATIVE) #5 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 13:44:35 BP_RUN3_000113.LAB 

### 35.0053 0.0000 03/05/10 13:45:05 BP_RUN3_000114.LAB 

### 37.6901 0.0000 03/05/10 13:45:34 BP_RUN3_000115.LAB 

### 37.2987 0.0000 03/05/10 13:46:03 BP_RUN3_000116.LAB 

### 35.3169 0.0000 03/05/10 13:46:33 BP_RUN3_000117.LAB 

### 35.0122 0.0000 03/05/10 13:47:02 BP_RUN3_000118.LAB 

### 35.2526 0.0000 03/05/10 13:47:31 BP_RUN3_000119.LAB 

### 35.1992 0.0000 03/05/10 13:48:01 BP_RUN3_000120.LAB 

### 36.2918 0.0000 03/05/10 13:48:30 BP_RUN3_000121.LAB 

### 35.4451 0.0000 03/05/10 13:48:59 BP_RUN3_000122.LAB 

### 35.3810 0.0000 03/05/10 13:49:29 BP_RUN3_000123.LAB 

### 35.7029 0.0000 03/05/10 13:49:58 BP_RUN3_000124.LAB 

### 36.0998 0.0000

RAW AVERAGE 35.8080 0.0000

SPIKE #5 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 13:53:47 BP_SPK5_000009.LAB 

### 34.9950 1.3839 03/05/10 13:54:02 BP_SPK5_000010.LAB 

### 35.7234 1.3858 03/05/10 13:54:17 BP_SPK5_000011.LAB 

### 34.6119 1.3527 03/05/10 13:54:31 BP_SPK5_000012.LAB 

### 35.5320 1.3401 03/05/10 13:54:46 BP_SPK5_000013.LAB 

### 35.0267 1.3389 03/05/10 13:55:01 BP_SPK5_000014.LAB 

### 34.8278 1.3407 03/05/10 13:55:15 BP_SPK5_000015.LAB 

### 34.0841 1.3308 03/05/10 13:55:30 BP_SPK5_000016.LAB 

### 34.5732 1.3319 03/05/10 13:55:45 BP_SPK5_000017.LAB 

### 33.8718 1.3247 03/05/10 13:55:59 BP_SPK5_000018.LAB 

### 34.5702 1.3237 03/05/10 13:56:14 BP_SPK5_000019.LAB 

### 33.3671 1.3220 03/05/10 13:56:29 BP_SPK5_000020.LAB 

### 34.4200 1.3196

RAW AVERAGE 34.6336 1.3412

PRE-SPIKE (NATIVE) #6 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 14:00:09 BP_SPK5_000035.LAB 

### 36.1652 0.0000 03/05/10 14:00:24 BP_SPK5_000036.LAB 

### 37.5939 0.0000 03/05/10 14:00:38 BP_SPK5_000037.LAB 

### 37.0717 0.0000 03/05/10 14:00:53 BP_SPK5_000038.LAB 

### 37.0054 0.0000 03/05/10 14:01:08 BP_SPK5_000039.LAB 

### 36.7091 0.0000 03/05/10 14:01:22 BP_SPK5_000040.LAB 

### 36.3749 0.0000 03/05/10 14:01:37 BP_SPK5_000041.LAB 

### 36.7921 0.0000 03/05/10 14:01:52 BP_SPK5_000042.LAB 

### 37.3422 0.0000 03/05/10 14:02:06 BP_SPK5_000043.LAB 

### 36.0903 0.0000 03/05/10 14:02:21 BP_SPK5_000044.LAB 

### 37.3926 0.0000 03/05/10 14:02:36 BP_SPK5_000045.LAB 

### 36.8131 0.0000 03/05/10 14:02:50 BP_SPK5_000046.LAB 

### 37.3059 0.0000

RAW AVERAGE 36.8880 0.0000

SPIKE #6 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 14:04:48 BP_SPK5_000054.LAB 

### 35.9751 0.9880 03/05/10 14:05:03 BP_SPK5_000055.LAB 

### 35.3484 0.9693 03/05/10 14:05:17 BP_SPK5_000056.LAB 

### 35.5070 0.9493 03/05/10 14:05:32 BP_SPK5_000057.LAB 

### 35.9499 0.9508 03/05/10 14:05:47 BP_SPK5_000058.LAB 

### 35.8083 0.9386 03/05/10 14:06:01 BP_SPK5_000059.LAB 

### 34.5096 0.9253 03/05/10 14:06:16 BP_SPK5_000060.LAB 

### 36.1017 0.9220 03/05/10 14:06:31 BP_SPK5_000061.LAB 

### 35.4924 0.9156 03/05/10 14:06:45 BP_SPK5_000062.LAB 

### 35.7173 0.9143 03/05/10 14:07:00 BP_SPK5_000063.LAB 

### 35.0285 0.9086 03/05/10 14:07:15 BP_SPK5_000064.LAB 

### 35.1067 0.9014 03/05/10 14:07:29 BP_SPK5_000065.LAB 

### 35.1751 0.9005

RAW AVERAGE 35.4767 0.9320 BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

bp-10-hinton.ok-ftir#1-rpt App. D

### BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma

PRE-SPIKE (NATIVE) #7 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 14:10:25 BP_SPK5_000077.LAB 

### 37.1983 0.0000 03/05/10 14:10:40 BP_SPK5_000078.LAB 

### 37.3003 0.0000 03/05/10 14:10:55 BP_SPK5_000079.LAB 

### 36.7630 0.0000 03/05/10 14:11:10 BP_SPK5_000080.LAB 

### 37.1874 0.0000 03/05/10 14:11:24 BP_SPK5_000081.LAB 

### 37.5707 0.0000 03/05/10 14:11:39 BP_SPK5_000082.LAB 

### 37.2848 0.0000 03/05/10 14:11:54 BP_SPK5_000083.LAB 

### 36.4514 0.0000 03/05/10 14:12:08 BP_SPK5_000084.LAB 

### 37.7881 0.0000 03/05/10 14:12:23 BP_SPK5_000085.LAB 

### 36.9974 0.0000 03/05/10 14:12:38 BP_SPK5_000086.LAB 

### 36.9669 0.0000 03/05/10 14:12:52 BP_SPK5_000087.LAB 

### 36.4672 0.0000 03/05/10 14:13:07 BP_SPK5_000088.LAB 

### 36.5887 0.0000

RAW AVERAGE 37.0470 0.0000

SPIKE #7 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 14:14:20 BP_SPK5_000093.LAB 

### 36.3754 1.5483 03/05/10 14:14:35 BP_SPK5_000094.LAB 

### 35.3694 1.4683 03/05/10 14:14:50 BP_SPK5_000095.LAB 

### 34.3117 1.4713 03/05/10 14:15:04 BP_SPK5_000096.LAB 

### 34.1440 1.4701 03/05/10 14:15:19 BP_SPK5_000097.LAB 

### 33.8791 1.4767 03/05/10 14:15:34 BP_SPK5_000098.LAB 

### 34.4111 1.4645 03/05/10 14:15:48 BP_SPK5_000099.LAB 

### 33.0403 1.4756 03/05/10 14:16:03 BP_SPK5_000100.LAB 

### 34.3789 1.4693 03/05/10 14:16:18 BP_SPK5_000101.LAB 

### 34.1109 1.4673 03/05/10 14:16:32 BP_SPK5_000102.LAB 

### 33.9922 1.4666 03/05/10 14:16:47 BP_SPK5_000103.LAB 

### 33.7465 1.4555 03/05/10 14:17:02 BP_SPK5_000104.LAB 

### 34.6247 1.4640

RAW AVERAGE 34.3653 1.4748

POST-SPIKE (NATIVE) #7 Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 14:26:09 BP_SPK5_000139.LAB 

### 35.9273 0.0000 03/05/10 14:26:24 BP_SPK5_000140.LAB 

### 35.7135 0.0000 03/05/10 14:26:39 BP_SPK5_000141.LAB 

### 35.1987 0.0000 03/05/10 14:26:53 BP_SPK5_000142.LAB 

### 35.4474 0.0000 03/05/10 14:27:08 BP_SPK5_000143.LAB 

### 35.5930 0.0000 03/05/10 14:27:23 BP_SPK5_000144.LAB 

### 35.8892 0.0000 03/05/10 14:27:37 BP_SPK5_000145.LAB 

### 35.3678 0.0000 03/05/10 14:27:52 BP_SPK5_000146.LAB 

### 35.9093 0.0000 03/05/10 14:28:07 BP_SPK5_000147.LAB 

### 35.9948 0.0000 03/05/10 14:28:21 BP_SPK5_000148.LAB 

### 35.8653 0.0000 03/05/10 14:28:36 BP_SPK5_000149.LAB 

### 35.7906 0.0000 03/05/10 14:28:51 BP_SPK5_000150.LAB 

### 36.0136 0.0000

RAW AVERAGE 35.7259 0.0000

POST-SPIKE (SF 6 Cylinder Conc.) Date Time Spectrum HCHO SF 6 (mm/dd/yy) hh:mm:ss File Name (ppm) (ppm)

03/05/10 14:23:09 BP_SPK5_000129.LAB 

### 12.8649 11.0932 03/05/10 14:23:23 BP_SPK5_000130.LAB 

### 18.3992 11.0737 03/05/10 14:23:38 BP_SPK5_000131.LAB 

### 21.7196 11.1074 03/05/10 14:23:53 BP_SPK5_000132.LAB 

### 22.6310 11.1044 03/05/10 14:24:08 BP_SPK5_000133.LAB 

### 23.7967 11.1416 03/05/10 14:24:22 BP_SPK5_000134.LAB 

### 24.0553 11.0981 03/05/10 14:24:37 BP_SPK5_000135.LAB 

### 24.3226 11.1109 03/05/10 14:24:52 BP_SPK5_000136.LAB 

### 24.6235 11.1459 03/05/10 14:25:06 BP_SPK5_000137.LAB 

### 23.7308 11.0881

RAW AVERAGE 21.7937 11.1070

bp-10-hinton.ok-ftir#1-rpt App. D

### BP America Production Company and Ch esapeake Energ y March 5, 2010 380 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Engine Tulsa County, Oklahoma


## Spiking Results Analyzer Make: MKS Analyzer Model: 2030 36.58 ppm 11.11 ppm 25.00 ppm

Spike Run No. Dilution Factor Ideal Spike Yield (ppm) Percent Recovery Pass/Fail (70-130%) Spike 5 0.8792 34.978 88.6% PASS Spike 6 0.9161 35.963 76.8% PASS Spike 7 0.8672 34.875 84.7% PASS

QA Notes: Certified Analyte (HCHO) cylinder concentration

1. Section 8.6.2 of EPA Method 320 requires the aver age spiked percent recovery must be between 70% to 130%. 2. Calibration and run spectral data are not included in this report. Electronic copies of this data are available upon request. Average Analyte ( HCHO) stack concentration Average Diluent (SF 6 ) concentration

bp-10-hinton.ok-ftir#1-rpt App. D

## CALIBRATION TRANSFER SPECTRA (CTS SCAN) - PRE TEST Date Time C 2 H 6 (mm/dd/yy) hh:mm:ss (ppm)

03/05/10 8:13:37 BP_PRE_000011.LAB 

## 100.0453 03/05/10 8:14:04 BP_PRE_000012.LAB 

## 100.8151 03/05/10 8:14:31 BP_PRE_000013.LAB 

## 101.2215 03/05/10 8:14:59 BP_PRE_000014.LAB 

## 101.8710 03/05/10 8:15:26 BP_PRE_000015.LAB 

## 102.2718

PRE TEST AVERAGE 101.2450

CALIBRATION TRANSFER SPECTRA (CTS SCAN) - POST TEST Date Time C 2 H 6 (mm/dd/yy) hh:mm:ss (ppm)

03/05/10 17:02:05 BP_PST_000001.LAB 

## 102.0044 03/05/10 17:02:19 BP_PST_000002.LAB 

## 102.8170 03/05/10 17:02:34 BP_PST_000003.LAB 

## 103.8380 03/05/10 17:02:49 BP_PST_000004.LAB 

## 103.5275 03/05/10 17:03:03 BP_PST_000005.LAB 

## 103.3340

POST TEST AVERAGE 103.1042

Analyzer Make: MKS A nalyzer Model: 2030 99.80

Pre Test 101. 24 1. 45 PASS Post Test 103.10 3. 31 PASS BP America Production Company and Ch esapeake Energy March 5, 2010 0 Cubic Inch (6.2 Liter), 80 Horsepower Gas-Fired 4-Stroke Rich Burn Eng Tulsa County, Oklahoma

Filename

Filename

Run ID Instrument Response (%) Error (%) Pass / Fail ±5% C 2 H 6 Cylinder Conc. (ppm) =

bp-10-hinton.ok-ftir#1-rpt App. D

# APPENDIX E

FUEL ANALYSIS RECORDS

## Client: BP America Production Company and Chesapeake Energy Location: Tulsa County, Oklahoma Date: Project #: bp-10-hinton.ok-ftir#1

Natural Gas - Fuel Analysis

Mole (%) Molecular 1 

### Weight (lb/lb-mole) Lbs Component per Lb-Mole

of Gas Wt. % of Component Ideal Gross 1,3 

### Heating Value (Btu/ft 3 

### ) Fuel Heat Value [HHV]

(Btu/SCF) Ideal Net 1,3 

### Heating Value (Btu/ft 3 

### ) Fuel Heat Value [LHV]

(Btu/SCF)

Methane CH 4 

### 95.232 16.0430 15.28 90.84 994.85 947.41 895.75 853.04 Ethane C 2 

### H 6 

### 2.604 30.0700 0.78 4.66 1,743.15 45.40 1,594.41 41.52 Propane C 3 

### H 8 

### 0.263 44.0970 0.12 0.69 2,478.35 6.51 2,280.17 5.99 iso-Butane iC 4 

### H 10 

### 0.026 58.1230 0.02 0.09 3,203.11 0.83 2,955.38 0.77 n-Butane nC 4 

### H 10 

### 0.016 58.1230 0.01 0.06 3,213.35 0.52 2,965.62 0.48 Iso-Pentane iC 5 

### H 12 

### 0.005 72.1500 0.00 0.02 3,940.87 0.18 3,643.50 0.17 n-Pentane nC 5 

### H 12 

### 0.006 72.1500 0.00 0.02 3,948.75 0.22 3,648.32 0.20 Hexanes C 6 

### H 14 

### 0.010 86.1770 0.01 0.05 4,684.54 0.47 4,337.82 0.44 Heptanes C 7 

### H 16 

### 0.000 100.2040 0.00 0.00 5,419.94 0.00 5,023.77 0.00 Octanes C 8 

### H 18 

### 0.000 114.2310 0.00 0.00 6,155.14 0.00 5,709.23 0.00 Carbon Dioxide CO 2 

### 0.536 44.0100 0.24 1.40 0.00 0.00 0.00 0.00 Nitrogen N 2 

### 1.303 28.0134 0.36 2.17 0.00 0.00 0.00 0.00 Hydrogen Sulfide H 2 

### S 0.000 34.0800 0.00 0.00 627.54 0.00 578.00 0.00 Oxygen O 2 

### 0.000 31.9988 0.00 0.00 0.00 0.00 0.00 0.00 Helium He 0.000 4.0026 0.00 0.00 0.00 0.00 0.00 0.00 Hydrogen H 2 

### 0.000 2.0159 0.00 0.00 319.34 0.00 269.82 0.00 100.000 16.82 100.00 dry 1,001.54 dry 902.61
wet 2,5 

### 978.44 wet 2,5 

### 881.80

Component Wt% Molecular Weight of gas = 16.818 lb/lb-mole carbon 72.88 Btu per lb. of gas 4 

### = 22,940.580 gross (HHV) oxygen 1.02 Btu per lb. of gas 4 

### = 20,674.568 net (LHV) hydrogen 23.93 Density of fuel gas 2 

### = 0.0437 lb/cu. ft nitrogen 2.17 Wt % VOC in fuel gas = 0.93 % helium 0.00 Specific Gravity 1 

### = 0.5807 sulfur 0.00 Total 100.00 8,650.83

F-Factor Calculation: F-Factor = 1,000,000*((3.64*%H)+(1.53*%C)+(0.57*%S)+(0.14*%N)-(0.46*%O))/GCV GCV = Gross Btu per lb. of gas (HHV) %H, %C, %S, %N, & %O are percent weight values calculated from fuel analysis and have units of (scf/lb)/% Density of natural gas based on specific gravity multiplied by density of air at 68 deg F and 14.696 psia.

References:

1 

### ASTM D 3588
2 

### Civil Engineering Reference Manual, 7th ed. - Michael R. Lindeburg
3 

### Mark's Standard Handbook for Mechanical Engineers, 10th ed. - Eugene A. Avallone, Theodore Baumeister III
4 

### Introduction to Fluid Mechanics, 3rd ed. - William S. Janna
5 

### GPA Reference Bulletin 181-86, revised 1986, reprinted 1995 

## March 5, 2010

Standardized to 68 deg F and 14.696 psia - EPA St andards



### F-Factor (SCF dry exhaust per MMBtu [HHV]) = (Based on EPA RM-19) at 68 deg F and 14. 696 psia Characteristics of Fuel Gas Gas Component

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