Material Safety Data Sheet 

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Version 2.0 

Revision Date 10/11/2013 Ref[ J 

This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory 

requirements in other countries. 

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION 

Product name 

Tradename/Synonym 

MSDS Number 

Manufacturer 

Product Information 

Medical Emergency 

Transport Emergency 

:[ 

. Cyclooctadiene metal derivatives 

r- -

: '- CHEMTREC: +1-800-424-9300 (outside the u.S. ;1::703-527-3887) 

SECTION 2. HAZARDS IDENTIFICATION 

Emergency Overview 

WARNING! 

May cause cancer. Causes eye, skin, and respiratory tract irritation. Flammable solid. This product is for 

experimental uses only. The product has not been completely analysed and all of the hazards may not be 

known. Please use caution while handling this product. 

Potential Health Effects 

Skin 

Eyes 

Inhalation 

Ingestion 

Carcinogenicity 

Material 

Causes: Mild skin irritation, Prolonged or repeated contact may dry skin 

and cause irritation .. 

Causes: Mild eye irritation 

Causes respiratory tract irritation. Irritation of mucous membranes 

Effects due to ingestion may include: Diarrhea, Weakness, Convulsions. 

IARC NTP OSHA 

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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 

3 

SECTION 4. FIRST AID MEASURES 

Skin contact 

Eye contact 

Inhalation 

Ingestion 

Wash off with soap and water. Get medical attention if irritation develops and 

persists. Wash contaminated clothing before re-use. 

Immediately flush eyes for at least 15 minutes. Get medical attention. 

If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not 

breathing, give artificial respiration. Get medical attention. 

If swallowed DO NOT induce vomiting unless directed to do so by a physician 

or poison control center. Drink plenty of water. Call a physician or poison 

control centre immediately. 

SECTION 5. FIREFIGHTING MEASURES 

Flammable Properties 

Flash point 

Fire and Explosion Hazard 

: not determined 

Flammable. Burning produces irritant fumes. Hazardous decomposition 

products formed under fire conditions. 

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Suitable extinguishing media 

Firefighting Instructions 

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Use extinguishing measures that are appropriate to local circumstances and 

the surrounding environment. 

Foam, Carbon dioxide (C02), Dry chemical 

Exposure to decomposition products may be a hazard to health. Wear full 

protective clothing and self-contained breathing apparatus. 

Evacuate personnel to safe areas. 

SECTION 6. ACCIDENTAL RELEASE MEASURES 

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NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. 

Safeguards (Personnel) 

Spill Cleanup 

Accidental Release Measures 

Avoid contact with skin, eyes and clothing. Avoid dust formation. Ensure 

adequate ventilation. Wear personal protective equipment. Use the indicated 

respiratory protection if the occupational exposure limit is exceeded and/or in 

case of product release (dust). 

Avoid dust formation. Clean-up methods- large spillage Ventilate the area. 

Use approved industrial vacuum cleaner for removal. Do not create a powder 

cloud by using a brush or compressed air. 

Clean-up methods -small spillage For small spills, use cloth or paper towels 

and place collected material and towels in appropriate container for disposal. 

Moisten and remove. Clean contaminated floors and objects thoroughly while 

observing environmental regulations. 

Prevent further leakage or spillage. Prevent product from entering drains. 

Clean contaminated floors and objects thoroughly while observing 

environmental regulations. 

Dispose of in accordance with local regulations. 

SECTION 7. HANDLING AND STORAGE 

Handling (Personnel) Avoid breathing dust. Keep container closed when not in use. Do not use in 

areas without adequate ventilation. 

Handle under nitrogen, protect from moisture. 

Handle in accordance with good industrial hygiene and safety practice. Avoid 

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Material Safety Data Sheet · 

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Handling (Physical Aspects) 

Storage 

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contact with skin, eyes and clothing. Contaminated work clothing should not 

be allowed out of the workplace. Remove contaminated clothing and 

protective equipment before entering eating areas. Remove and wash 

contaminated clothing before re-use. 

Keep away from heat and sources of ignition. 

Handle and store in a DRY closed system, preferably under DRY nitrogen. 

Keep away from sources of ignition- No smoking. Do not store or consume 

food, drink or tobacco in areas where they may become contaminated with 

this material. Keep container closed when not in use. Do not reuse empty 

container. 

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Engineering controls 

Personal protective equipment 

Respiratory protection 

Hand protection 

Any process that has the potential to generate dust should be performed 

using engineering controls, such as isolation, enclosures, local exhaust 

ventilation, wetting with coolant, or dust collection systems, to control airborne 

fibers and dusts below applicable limits. Provide appropriate exhaust 

ventilation at places where dust is formed. 

Provide adequate ventilation. No personal respiratory protective equipment 

normally required. Where there is potential for airborne exposures in excess 

of applicable limits, wear approved respiratory protection with dust/mist 

cartridge. When workers are facing concentrations above the exposure limit 

they must use appropriate certified respirators. Consult the respirator 

manufacturer to determine the appropriate type of equipment for a given 

application. Observe respirator use limitations specified by the manufacturer. 

Additional protection: Gloves must be inspected prior to use., Gloves should 

be discarded and replaced if there is any indication of degradation or 

chemical breakthrough., The choice of an appropriate glove does not only 

depend on its material but also on other quality features and is different from 

one producer to the other., The exact break through time can be obtained 

from the protective glove producer and this has to be observed., Please 

observe the instructions regarding permeability and breakthrough time which 

are provided by the supplier of the gloves. Also take into consideration the 

specific local conditions under which the product is used, such as the danger 

of cuts, abrasion, and the contact time. 

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Material Safety Data Sheet 

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Eye protection 

Skin and body protection 

Exposure Guidelines 

Exposure Limit Values 

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Wear safety glasses with side shields. 

Choose body protection in relation to its type, to the concentration and 

amount of dangerous substances, and to the specific work-place. 

Lightweight protective clothing 

Safety shoes 

[ =r 

PEL: (OSHA) 1 mg/m3 8 hr. TWA as[ J 

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 

Form 

Color 

Odor 

Melling point 

Water solubility [ J 

SECTION 10. STABILITY AND REACTIVITY 

Stability 

Conditions to avoid 

Incompatibility 

Hazardous decomposition 

products 

Hazardous reactions 

Air and moisture-sensitive material. 

Heat, flames and sparks. Exposure to air. Exposure to moisture. 

Strong oxidizing agents 

Hazardous decomposition products formed under fire conditions.: Carbon 

monoxide, Carbon dioxide (C02).[ ]oxides 

Hazardous polymerisation does not occur. 

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SECTION 11. TOXICOLOGICAL INFORMATION 

[ Oral Jno data available 

SECTION 12. ECOLOGICAL INFORMATION 

Cuatic Toxicity 

~o data available 

SECTION 13. DISPOSAL CONSIDERATIONS 

Waste Disposal 

Container Disposal 

If recycling is not practicable, dispose of in compliance with local regulations. 

Never place unused product down any indoor or out door drain. 

Do not reuse empty container. 

Contaminated/not cleaned containers should be treated/handled like product 

waste. 

Dispose of container properly. 

Refer to applicable Local, State/Provincial, and Federal Regulations, as well 

as industry Standards. 

SECTION 14. TRANSPORT INFORMATION 

DOT UN number 

Proper shipping name 

Class 

Packing group 

Labelling No. 

1325 

Flammable solids, organic, n.o.s.[ 

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Material Safety Data Sheet 

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IATA_C 

Reportable Quantity 

UN number 

:[ 

: T325 

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Proper shipping name Flammable solid, organ~n.o.s.[ 

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IMDG 

Class 

Packing group 

Labelling No. 

UN number 

II 

4.1 

1325 

Proper shipping name FLAMMABLE SOLID, ORGANIC, N.O.S [ 

Class 4.1 ~ Packing group 

Labelling No. 

II 

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SECTION 15. REGULATORY INFORMATION 

TSCA 

SARA 313 Regulated 

Chemical(s) 

CERCLA Reportable 

Quantity 

California Prop. 65 

NJ Right to Know 

Regulated Chemical(s) 

One or more constituents are not listed in the TSCA Chemical Substances 

Inventory. Restricted to research and development activities as defined in 40 

CFR 720.36. 

These experimental samples are to be used by a technically qualified 

individual. 

:[ 

: 11bs 

cased on the percentage cojosition of this chemical in the product.: 

WARNING! This product contains a chemical or chemicals known to the State 

of California to cause cancer[ J 

Substances on the New Jersey Workplace Hazardous Substance List 

present at a concentration of 1% or more (0.1% for substances 

identified as carcinogens, mutagens or teratogens):[ 

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SECTION 16. OTHER INFORMATION 

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Restrictions for use : For research use only. 

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The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at 

the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, 

storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The 

information relates only to the specific material designated and may not be valid for such material used in combination 

with any other materials or in any process, unless specified in the text. 

Significant change from previous version is denoted with a double bar. 

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