EPA Reference Method 23

Determination of Dioxins/Furan Emissions From Stationary Sources

Client NRG Date 40232

Facility Vienna Job Number 902637

Unit 8 Operator NT

Location Stack Version ST629-01

Train Blank

Detection

Element Status ng TEF

2378-TCDD BDL 0.0016 1.00

12378-PeCDD BDL 0.0017 1.00

123478-HxCDD BDL 0.0017 0.100

123678-HxCDD BDL 0.0017 0.100

123789-HxCDD BDL 0.0016 0.100

1234678-HpCDD ADL 0.0089 0.010

OCDD ADL 0.0209 0.000300

2378-TCDF ADL 0.0043 0.100

12378-PeCDF BDL 0.0018 0.0300

23478-PeCDF BDL 0.0035 0.300

123478-HxCDF ADL 0.0016 0.100

123678-HxCDF BDL 0.0015 0.100

234678-HxCDF ADL 0.0036 0.100

123789-HxCDF BDL 0.0019 0.100

1234678-HpCDF BDL 0.0074 0.0100

1234789-HpCDF BDL 0.0020 0.0100

OCDF BDL 0.0043 0.000300

Total TCDD BDL 0.0016

Total PeCDD BDL 0.0017

Total HxCDD ADL 0.0024

Total HpCDD ADL 0.0174

Total TCDF ADL 0.0124

Total PeCDF ADL 0.0057

Total HxCDF ADL 0.0104

Total HpCDF BDL 0.0086

Total PCDD/PCDF ADL 0.0854

Total TEQ BDL 0.0017

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit

EMSI
EPA REFERENCE METHOD 23

 Determination of Polyaromatic Hydrocarbon Emissions From Stationary Sources

Client NRG Date 2-24-10

Facility Job Number 902637

Unit 1 Operator

Location Stack

Reagent Blank

Detection Fraction 1 Detection Fraction 2

Element Status ug Status ug

1,2,4-Trichlorobenzene BDL 6.00 BDL 6.00

1,2-Dichlorobenzene BDL 6.00 BDL 6.00

1,3-Dichlorobenzene BDL 6.00 BDL 6.00

1,4-Dichlorobenzene BDL 6.00 BDL 6.00

1-Methylnaphthalene BDL 0.150 BDL 0.150

2,4,5-Trichlorophenol BDL 6.00 BDL 6.00

2,4,6-Trichlorophenol BDL 5.00 BDL 5.00

2,4-Dichlorophenol BDL 4.00 BDL 4.00

2,4-Dimethylphenol BDL 6.00 BDL 6.00

2,4-Dinitrophenol BDL 10.00 BDL 10.00

2,4-Dinitrotoluene BDL 2.00 BDL 2.00

2,6-Dinitrotoluene BDL 3.00 BDL 3.00

2-Chloronaphthalene BDL 3.00 BDL 3.00

2-Chlorophenol BDL 6.00 BDL 6.00

2-Methylanthracene BDL 0.15 BDL 0.15

2-Methylnaphthalene BDL 0.15 BDL 0.15

2-Methylphenol BDL 9.00 BDL 9.00

2-Nitroaniline BDL 20.00 BDL 20.00

2-Nitrophenol BDL 5.000 BDL 5.000

3 & 4-methylphenol BDL 10.00 BDL 10.00

3,3'-Dichlorobenzidine BDL 8.00 BDL 8.00

3-Nitroaniline BDL 20.00 BDL 20.00

4,6-Dinitro-2-methylphenol BDL 10.00 BDL 10.00

4-Bromophenyl phenyl ether BDL 2.00 BDL 2.00

4-Chloro-3-Methylphenol BDL 5.00 BDL 5.00

4-Chloroaniline BDL 20.00 BDL 20.00

4-Chlorophenyl phenyl ether BDL 3.00 BDL 3.00

4-Nitroaniline BDL 20.00 BDL 20.00

4-Nitrophenol BDL 10.00 BDL 10.00

Acenaphthene BDL 0.075 BDL 0.075

Acenaphthylene BDL 0.075 BDL 0.075

Aniline BDL 20.00 BDL 20.00

Anthracene BDL 0.075 BDL 0.075

Benzidine BDL 60.00 BDL 60.00

Benzo(a)anthracene BDL 0.075 BDL 0.075

Benzo(a)pyrene BDL 0.075 BDL 0.075

Benzo(b)fluoranthene BDL 0.075 BDL 0.075

Benzo(e)pyrene BDL 0.15 BDL 0.15

Benzo(g,h,i)perylene BDL 0.075 BDL 0.075

Benzo(k)fluoranthene BDL 0.075 BDL 0.075

Benzoic Acid BDL 10.00 BDL 10.00

Benzyl Alcohol BDL 6.00 BDL 6.00

Benzyl butyl phthalate BDL 2.00 BDL 2.00

Bis(2-chloroethoxy)methane BDL 4.00 BDL 4.00

Bis(2-chloroethyl)ether BDL 5.00 BDL 5.00

Bis(2-chloroisopropyl)ether BDL 5.00 BDL 5.00

Bis(2-ethylhexyl)phthalate ADL 12.00 BDL 8.00

Carbazole BDL 20.00 BDL 20.00

Chrysene BDL 0.075 BDL 0.075

Coronene BDL 0.15 BDL 0.15

Dibenz(a,h)anthracene BDL 0.075 BDL 0.075

Dibenzofuran BDL 20.00 BDL 20.00

Diethyl phthalate BDL 3.00 BDL 3.00

Dimethyl phthalate BDL 3.00 BDL 3.00

Di-N-butyl phthalate BDL 3.00 BDL 3.00

Di-N-octyl phthalate BDL 3.00 BDL 3.00

Fluoranthene BDL 0.075 BDL 0.075

Fluorene BDL 0.075 BDL 0.075

Hexachlorobenzene BDL 6.00 BDL 6.00

Hexachlorobutadiene BDL 6.00 BDL 6.00

Hexachlorocyclopentadiene BDL 6.00 BDL 6.00

Hexachloroethane BDL 6.00 BDL 6.00

Indeno(1,2,3-cd)pyrene BDL 0.075 BDL 0.075

Isophorone BDL 10.00 BDL 10.00

Naphthalene BDL 0.11 ADL 0.14

Nitrobenzene BDL 6.00 BDL 6.00

N-Nitrosodimethylamine BDL 30.00 BDL 30.00

N-Nitroso-di-n-propylamine BDL 6.00 BDL 6.00

N-Nitrosodiphenylamine BDL 6.00 BDL 6.00

Pentachlorophenol BDL 9.00 BDL 9.00

Perylene BDL 0.15 BDL 0.15

Phenanthrene BDL 0.075 BDL 0.075

Phenol BDL 5.00 BDL 5.00

Pyrene BDL 0.075 BDL 0.075

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit

EMSI
SW0011

Determination of Formaldehyde

Client NRG Date 2-24-10

Facility Vienna Job Number 902637

Unit 8 Operator

Location Stack Version ST631-01

Blank

Element Status ug

Formaldehyde ADL 2.00

 

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit
EPA METHOD 26

Determination of Hydrochloric Acid and Hydrofluoric Acid

Client NRG Date 2/24/2010

Facility Vienna Job Number 902637

Unit 8 Operator

Location Stack Version ST631-01

Reagent Blank

Element Status ug

Hydrochloric Acid (HCl) BDL 200.00

Hydrofluoric Acid (HF) BDL 200.00

 

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit
CTM 033

Determination of Hydrogen Cyanide

Client NRG Date 2/24/2010

Facility Vienna Job Number 902637

Unit 8 Operator

Location Stack Version ST631-01

Blank

Element Status ug

Hydrogen Cyanide (HCN) BDL 10.00

 

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit
ASTM D-6784-02

Determination of Speciated Mercury (Ontario Hydro Method)

Client NRG Date 2/23/2010

Facility Vienna Job Number 902637

Unit 8 Operator

Location Stack Version ST631-01

Train Blank

Element Status ug

Front Half Antimony (Sb) BDL 0.200

Back Half Antimony (Sb) BDL 0.400

Total Antimony (Sb) BDL 0.600

Front Half Arsenic (As) BDL 0.200

Back Half Arsenic (As) BDL 0.400

Total Arsenic (As) BDL 0.600

Front Half Beryllium (Be) BDL 0.050

Back Half Beryllium (Be) BDL 0.100

Total Beryllium (Be) BDL 0.150

Front Half Cadmium (Cd) BDL 0.050

Back Half Cadmium (Cd) BDL 0.100

Total Cadmium (Cd) BDL 0.150

Front Half Chromium (Cr) ADL 0.210

Back Half Chromium (Cr) ADL 1.220

Total Chromium (Cr) ADL 1.430

Front Half Cobalt (Co) BDL 0.050

Back Half Cobalt (Co) BDL 0.100

Total Cobalt (Co) BDL 0.150

Front Half Lead (Pb) ADL 0.210

Back Half Lead (Pb) ADL 0.220

Total Lead (Pb) ADL 0.430

Front Half Manganese (Mn) BDL 0.250

Back Half Manganese (Mn) ADL 0.860

Total Manganese (Mn) DLL 1.110

Front Half Nickel (Ni) BDL 0.250

Back Half Nickel (Ni) ADL 0.740

Total Nickel (Ni) DLL 0.990

Front Half Selenium (Se) BDL 0.500

Back Half Selenium (Se) BDL 1.000

Total Selenium (Se) BDL 1.500

 

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit
EPA REFERENCE METHOD 23

Determination of Polychlorinated Biphenyl Emissions From Stationary Sources

Client NRG Date 2/23/2010

Facility Vienna Job Number 902637

Unit 8 Operator NT

Location Stack

Train Blank

Detection

Element Status ng

3,4',4,5'-TetraCB (#81) BDL 0.0036

3,3',4,4'-TetraCB (#77) BDL 0.0066

2',3,4,4',5-PentaCB (#123) BDL 0.0038

2,3',4,4',5-PentaCB (#118) BDL 0.0390

2,3,4,4',5-PentaCB (#114) BDL 0.0038

2,3,3',4,4'-PentaCB (#105) ADL 0.0100

3,3',4,4',5-PentaCB (#126) BDL 0.0038

2,3',4,4',5,5'-HexaCB (#167) BDL 0.0039

2,3,3,4,4,5-HexaCB (#156/#157) BDL 0.0070

3,3',4,4',5,5'-HexaCB (#169) BDL 0.0041

2,3,3',4,4',5,5'-HeptaCB (#189) BDL 0.0036

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit

EMSI
 EPA REFERENCE METHOD 0030

Volatile Organic Sampling Train (VOST)

Client NRG Energy Inc. Date 2/24/2010

Facility Vienna Job Number 902637

Unit 8 Operator JW-BD

Location Stack

Glassware Time NA Date NA

Pre-Screening

Detection Air Detection Rinse

Element Status ug Status ug

Dichlorodifluoromethane (Freon 12) BDL 0.020

Chloromethane BDL 0.020

Vinyl chloride BDL 0.010

Bromomethane BDL 0.020

Chloroethane BDL 0.009

Trichlorofluoromethane (Freon 11) BDL 0.010

Acetone (2-Propanone) BDL 0.050

1,1-Dichloroethylene BDL 0.010

Iodomethane BDL 0.020

Carbon disulfide BDL 0.030

Methylene Chloride (Dichloromethane) ADL 0.030

1,1-Dichloroethane BDL 0.010

trans-1,2-Dichloroethylene BDL 0.010

cis-1,2-Dichloroethylene BDL 0.010

Chloroform BDL 0.010

1,2-Dichloroethane BDL 0.007

Methyl Ethyl Ketone (2-Butanone) BDL 0.040

1,1,1-Trichloroethane BDL 0.010

Carbon Tetrachloride BDL 0.020

Benzene BDL 0.009

1,1,2-Trichloroethane BDL 0.020

1,2-Dichloropropane BDL 0.010

Trichloroethylene BDL 0.010

Dibromomethane BDL 0.010

Bromodichloromethane BDL 0.010

cis-1,3-Dichloropropene BDL 0.010

trans-1,3-Dichloropropene BDL 0.007

Dibromochloromethane BDL 0.009

Methyl Isobutyl Ketone BDL 0.020

Methyl Butyl Ketone (2-Hexanone) BDL 0.030

Toluene ADL 0.030

Ethylene Dibromide BDL 0.010

Tetrachloroethylene BDL 0.020

Chlorobenzene BDL 0.010

1,1,1,2-Tetrachloroethane BDL 0.010

Ethylbenzene BDL 0.010

m / p-Xylene BDL 0.020

Styrene BDL 0.010

o-Xylene BDL 0.020

Bromoform BDL 0.010

1,1,2,2-Tetrachloroethane BDL 0.010

1,2,3-Trichloropropane BDL 0.020

1,3-Dichlorobenzene BDL 0.020

1,4-Dichlorobenzene BDL 0.020

1,2-Dichlorobenzene BDL 0.020

BDL = Below Detection Limit - All fractions below detection limit

DLL = Detection Limit Limited - Some fractions below detection limit

ADL = Above Detection Limit - All fractions above detection limit

EMSI