p. 1 

# OAR Box 

# 1384 Prepped by Charmelle Mathews



## Document

Number: 

# 93 ) ll-E-5 3 Docket Number: 

# A-94-5 2

Printed 7/2/2008 8:42:06

AM Sheet 93 of 264P. 2

SEC-03-199 6 09:2 9 BRISTOLIT E SKYLIGHT S P . 0 2 

## m -A-94-5 2

From : Date : Contact : Company : Contac tRepor t Meianie Proctor , Pacific Environmenta l Services , Inc . (PES ) Octobe r 31,199 6 Mr . Charle s Va

n Liew , Directo

r o f Operation s Bristo l Fiberlit

e Industrie s Telephon e Number : (714 ) 540-895 0 Fax Number : (714 ) 540-541 5 ContactSummary : Mr . Va n Liew wa s contactedt

o verif y to the conten

t o f hazardou s air

pollutant s i n th e resin s use db y BristolFJgrHte . Mr . Va n Lie w explainedtha

t Bristo l Fiberlite use s only tw o differen t resins , whiMrar

e bot hvapo r suppressed . I

n 1995 , the compan

y use d34,00 0 pound s o f i/fif**- $A? resi n

### * a t conta 

### " l s 2 

### * Percen

t styrene b y weigh t an dcontain s no methyl methacrylate (MMA) . «^>^~w.Bristo I Fiberlite used^O.OO O pound s of anothe r resin tha t contain s 2 3 percent

styren e an d5 percent MMA b y weight . A tota

l o f 1,49 8 pound s of

styrene pe r yea r were adde dt o th e resin s a

t Bristo l befor

e the resin s wer

e applied . Mr . Va

n Liew offere

dt o sen dmateria l safet y dat asheet s o f th e tw o resin s use dt o PES . INFORMATION I S ACCURAT Et? &L. ^£

_IP. 3

5EC-03-199 6 09:2 9 BRISTOLIT E SKYLIGHT S P . 0 3

MATERIA L SAFET

Y OAT A SHEET 

### Ashlan dChemica l Co . L B 1043-1 1 

### Pag e 00 1 Dat e Prepared : 01/05/9 6 Dat e Printed : 01/20/9 6 MSD S No : 0301846-002.00 1 1 . CHEMICA L PRODUC TAN D COMPAN

YIDENTIFICATIO N 

### Materia l Identit y produc t Name : L

B 1043-1 1 Genera l o r

Generi c ID : UNSATURATE D POLYESTE

RRESI N Compan y Ashlan dChemica l Co . P.O . Bo x 221 9 Columbus , O

H 4321 6 614-790-333 3 

### Emergenc y Telephon e Number ; 1-800-ASHLAN

D (1-800-274-5263 ) 

### 2 4 hour s everyda y Regulator y Informatio n Number : 1-800-325-375 1 2 . COMPOSITION/INFORMATIO N O N INGREDIENT S 

### Ingredient(s ) CA S Numbe r POLYESTE R RESI N STYREN E FLAK E RETARDANT ESTE R Trad e Secre t 100-42- 5 Trad e Secre t Trad e Secre t % (b yveight ) 55.0
- 60. 0 28. 0 5.0
- 10. 0 1.0
- 5. 0 .ISL

# r 3 . HAZARD S IDENTIFICATION Potentia l Healt hEffect s Ey e Exposur e cause s ey e irritation , redness , an

d swelling . Symptom s mayinclud e stinging , tearing , 

### Ski n Exposur e cause s slci n irritation . Prolonge d o r repeate d exposur e ma ydr yth e skin . Symptom s mayinclud e redness , burning , dryin g am d cracking , ski n burn s an d ski n damage . Ski n absorptio n i s possible , bu t harmfu l effect s ar e no t expecte d fromthi s rout e o f exposur e unde r norma l condition s o f handlin g and use . Swallowin g Singl e dos e ora l toxicit yi s low . swallowing smal l amount s durin g norma l handlin g i s no t likel yt o caus e harmfu l effects ; swallowin g larg e amount s nay b e harmful . Thi s materia l ca n ente r th e lung s durin g swallowin g o r vomitin g and caus e lun g inflammatio n and/o r damage . Inhalatio n Exposur e t o vapo r o r mis t i s possible . Exposur e t o aeroso l and/o r mis t i s possibl e whe n materia l i s sprayed . Aeroso l and mis t ma ypresen t a greate r ris k o f injurybecaus e mor e materia l ma ybe presen t i n th e ai r tha n fro mvapo r alone . Short-ter

minhalatio n toxicit yi s low . Breathin g smal l amount s durin g norma l handlin g i s no t likel yt o caus e harmfu l effects ; breathin g larg e amount s ma yb e harmful . Symptom s ar e mor e typicall ysee n a t ai r concentration s exceedin g th e recommende d exposur e limits .

Continue d o n next pag e 

# 2__P. 4

ITjEC-03-199 6 09-2 9 MATERIA L SAFET

Y ' DATASHEE T BRISTOLIT E SKYLIGHT S 

# Ashland u i visio n e t ASnlan dinc . 

### P.O . BO X 221 9 COLUMBUS

, OHI O 4321 6 (614 ) 790-333 3 P . 0 4 

### Emergenc y Telephon e (800 ) 274-526 3 o r (800 ) ASHLAN

D 00070 S 

### L B 1043-0 2 THI S MSO

S COMPLIE

S WIT H 2 9 CP

R 1910.120 0 (TH E HAZAR D CC*J*WICATIC*

) STANDARD

) 

## Page :

Produc t Nana : L S 1043-0 2 BRISTO L FIBERLIT E INDUSTRIE S 40 1 EAS T GOET Z STREE T SANT A AN A C A 9270 7

ATTN : PLAN T MGR./SAPETV OIR . 0 3 5 6 04 1 1326100 -

PRODUCT : 50511 9 INVOICE : 41019 7 INVOIC E DATE : 05/11/9 5 TQ 3 SAM E Oat a Shee t No : 0301790-001.00 0 Prepared t

04/14/9 5 Supersedes : ( N/ A

] Prin t Date : OS/20/9 5

O NI -PRODUC T I Dfc N T I F I C A T I O N Genera l e r Generi c 10 : UNSATURATE D POLYESTERRESI N DO T Hazar dClassification ; 3 (FUMWIABL E LIQUIO ) SECTIO NI I - COMPONENT S I P PRESENT . IARC . NT P AN O 091 * CARCINOGEN S AN D CHEMICAL S SUBJEC T T O TH E REPORT IN GREQUIREMENT S O F SAR A TITL E II I SECTIO

N 31 3 AR E IDENTIFIED I N THI S SECTION . SE E DEFINITIO

N PAG E FO RCLARIFICATIO

N INGREDIENT POLYESTERRESI N

• Percen t 58-6 2 PE

L TL

V Not e



### ( O STYRENE CA S *. 100-42- 5 METHYL METHACRYUT E CA S *: 80-62- 6 2 3 5 5 0 PP

M 10 0 PPM 5 0 PP M 10 0 PP M ( 2 ] ( 3 ) FLAM E RETARDAN T • ESTE R• OIMETHYL METHYLPHOSPHONAT E O S *x 756-79- 6 1- S 1- 5 1- 5 (4 ) { 5 ) ( 6 ) Notes : ( 1 ) PEL/TLV

NO T ESTA8LI»E DFORTHI S MATERIA L ( 2 ) ACGI H /OS * SHOR T TER M EXPOSUR E LIMI T (STEL ) FO RSTYRENE MONOME

RI S 10 0 PPM . NIOS H RECOKMEND S A LIMI T O P S O PPM . 8-HOU

RTHA . 10 0 PP M

1 5 MINUT E CEILING . THI S CHEMICAL I S SUBJEC T T O TH E REPORTIN GREQUIREMENT S O F SECTIO N 31 3 O P SAR

A TITL E III . ( 3 ) THI S CHEMICA

L I S SUBJEC T T O TH E REPORTIN GREQUIREMENT S O P SECTIO N 31 3 OF SAR

A TIU E III . ( 4 ) PEL/TL

V NO T ESTA6U9C D FO

RTHI S MATBHA L ( 5 ) PEL/TL

V NO T ESTABLISU D FO

RTHI S MATERIA

L ( 6 ) PEL/TL

V NO T ESTABLISHE D FO

RTHI S MATERIA

L • TH E SPECIFI C CHEMICAL NAM E O P THI S COMPONENT I S BEIN GWWEL O A S A

TRAO E SECRET . SECTIO N 111-PHYSiCA L DAT A Boiling Point Vaoo r Pressur e Specifi c vapo r Densit y Specifi c Gravit y Percen t volatile s EvaporationRat e Stat e For m fo r C0MP0NENT ( S» ) 207.0 0 Oe g F 97.2 2 De g C ) 760.0 0 BI B H g fo r COMPONENT f AI R= 1 S% ) \ 9 ( 35.0 0 n

m H o 68.0 0 Oe g F 20.0 0 Oe g C ) 3.6 0 1.10 0 77.0 0 De g F 25.0 0 De g C ) 28-32 % SLOWE RTHA N ETHER LIOUI D K K KSOL

N 

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