# URS Corporation

1600 Perimeter Park Dr. Morrisville, NC 27560



# AES ICR Test Guayama, PR Project # 39682175 PO # 226013.US



# Analytical Report (0310-96)

EPA CTM-033
Hydrogen Cyanide


# EPA OTM-028

Condensible Particulate Matter


# EPA Method 26A
Hydrogen Chloride Hydrogen Fluoride



# Enthalpy Analytical, Inc.

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 2202 Ellis Road Durham, NC 27703 - 5518

### I certify that to the best of my knowledge a ll analytical data presented in this report:

 Have been checked for completeness

 Are accurate, error-free, and legible

 Have been conducted in accordance with approved prot ocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s)

This analytical report was prepared in Portable Document Format (.PDF) and contains  pages.

# Summary of Results

### Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Hydrogen Cyanide 2,261 1,887 2,253

Unit 2 Run 1 Unit 2 Run 2 Unit 2 Run 3 Hydrogen Cyanide 2,751 2,497 2,475

NaOH FS Pb Ace FB 3/8/10 NaOH FB 3/8/10 Hydrogen Cyanide 594 12.4 ND 16.3 ND

NaOH RB 3/11/10 Pb Ace RB 3/6/10 Pb Ace RB2 3/14/10 Hydrogen Cyanide 13.3 ND 6.59 ND 9.36 ND

H2O RB 3/6/10 Hydrogen Cyanide 10.2 ND Company

Analyst Parameters # Samples URS Corp. - RTP KHB EPA CTM-033 6 Runs, 6 Blanks Client # Job # PO # Report Date 39682175 0310-96 226013.US 4/8/2010

0310-96 res ctm033 4/9/2010

### Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Hydrogen Fluoride 384 ND 320 ND 315 ND Hydrogen Chloride 375 ND 313 ND 307 ND

Unit 2 Run 1 Unit 2 Run 2 Unit 2 Run 3 Hydrogen Fluoride 305 ND 331 ND 354 ND Hydrogen Chloride 297 ND 323 ND 345 ND

Field Blank RB H2SO4 Hydrogen Fluoride 210 ND 63.0 ND 0 N D Hydrogen Chloride 205 ND 61.5 ND 0 N D Company

Analyst Parameters # Samples URS Corp. - RTP EO EPA Method 26A 6 Runs, 2 Blanks Client # Job # PO # Report Date 39682175 0310-96 226013.US 3/31/2010

0310-96 res m26a 4/9/2010

### Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Net Organic Catch 20.3 15.0 13.0 Corrected Inorganic 330.8 220.4 336.4 FB Corrected CPM 349.1 233.5 347.4

Unit 2 Run 1 Unit 2 Run 2 Unit 2 Run 3 Net Organic Catch 13.9 12.7 10.9 Corrected Inorganic 159.2 176.6 234.3 FB Corrected CPM 171.1 187.3 243.2

Filter Blank Run 8 Run 9 Net Organic Catch 2.9 0.0 0.0 Corrected Inorganic 10.3 0.0 0.0 FB Corrected CPM 11.2 -2.0 -2.0

Field Blank Organic Catch 8.3 If Train Blank Corrected CPM is >2.0 mg, Inorganic Catch 6.3 then sample correction is 2.0 mg. CPM 14.6 Company

Analyst Parameters # Samples URS Corp. - RTP ARM EPA OTM-028 6 Runs, Blanks Client # Job # PO # Report Date 39682175 0310-96 226013.US 3/31/2010

0310-96 res OTM-028 4/9/2010

# ResultsMDL 0.0143 (ug/mL)Lower Curve Limit 0.104 (ug/mL)LOQ 0.104 (ug/mL)Upper Curve Limit 2.08 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualU1-Pb-R1 036-4901.D 036-4902.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 364 26.0 NDU1-NaOH-R1 037-5001.D 037-5002.D 0310-96C.M 8.22 8.25 0.4 1.33 1.31 0.6 1.32 5 342 2,2612,261U1-Pb-R2 038-5101.D 038-5102.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 313 22.4 NDU1-NaOH-R2 039-5201.D 039-5202.D 0310-96C.M 8.26 8.30 0.5 0.887 0.908 1.1 0.897 5 421 1,8871,887U1-Pb-R3 040-5301.D 040-5302.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 279 19.9 NDU1-NaOH-R3 041-5601.D 041-5602.D 0310-96C.M 8.31 8.31 0.0 0.972 0.981 0.5 0.977 5 461 2,2532,253U2-Pb-R1 042-5701.D 042-5702.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 291 20.8 NDU2-NaOH-R1 043-5801.D 043-5802.D 0310-96C.M 8.23 8.20 0.3 1.35 1.39 1.3 1.37 5 402 2,7512,751U2-Pb-R2 044-5901.D 044-5902.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 283 20.2 NDU2-NaOH-R2 045-6001.D 045-6002.D 0310-96C.M 8.16 8.14 0.2 1.15 1.16 0.6 1.15 5 434 2,4972,497U2-Pb-R3 046-6301.D 046-6302.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 328 23.5 NDU2-NaOH-R3 047-6401.D 047-6402.D 0310-96C.M 8.02 8.03 0.2 1.16 1.19 1.2 1.17 5 422 2,4752,475Hydrogen CyanideCompanyAnalystParameters# SamplesURS Corp. - RTPKHBEPA CTM-0336 Runs, 6 BlanksClient #Job #PO #Report Date396821750310-96226013.US4/8/20100310-96 res ctm0334/9/2010MDL 0.0143 (ug/mL)Lower Curve Limit 0.104 (ug/mL)LOQ 0.104 (ug/mL)Upper Curve Limit 2.08 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualHydrogen CyanideCompanyAnalystParameters# SamplesURS Corp. - RTPKHBEPA CTM-0336 Runs, 6 BlanksClient #Job #PO #Report Date396821750310-96226013.US4/8/2010LD / U2-NaOH-R1 062-2301.D 062-2302.D 0310-96D.M 8.19 8.22 0.5 1.48 1.50 0.6 1.49 5 402 3,000% Difference 9.0%NaOH FS 050-6701.D 050-6702.D 0310-96C.M 8.01 8.02 0.2 0.843 0.829 0.9 0.836 5 142 594NaOH FB 3/8/10 048-6501.D 048-6502.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 228 16.3 NDNaOH RB 3/11/10 049-6601.D 049-6602.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 186 13.3 NDPb Ace FB 3/8/10 051-0801.D 051-0802.D 0310-96D.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 174 12.4 NDPb Ace RB 3/6/10 052-0901.D 052-0902.D 0310-96D.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 92.2 6.59 NDPb Ace RB2 3/14/10 053-1001.D 053-1002.D 0310-96D.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 131 9.36 NDH2O RB 3/6/10 054-1101.D 054-1102.D 0310-96D.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 143 10.2 ND0.1N NaOH - RB 007-0801.D 007-0802.D 0310-96C.M NA NA NA 0.0143 0.0143 0.0 0.0143 1 1.00 0.0143 ND0.1N NaOH - RB 007-0701.D 007-0702.D 0310-96D.M NA NA NA 0.0143 0.0143 0.0 0.0143 1 1.00 0.0143 ND0.1N NaOH - RB 007-0801.D 007-0802.D 0310-96G.M NA NA NA 0.0143 0.0143 0.0 0.0143 1 1.00 0.0143 ND0310-96 res ctm0334/9/2010MDL 0.0143 (ug/mL)Lower Curve Limit 0.104 (ug/mL)LOQ 0.104 (ug/mL)Upper Curve Limit 2.08 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualHydrogen CyanideCompanyAnalystParameters# SamplesURS Corp. - RTPKHBEPA CTM-0336 Runs, 6 BlanksClient #Job #PO #Report Date396821750310-96226013.US4/8/2010MS / U2-NaOH-R1 015-1101.D 015-1102.D 0310-96G.M 8.39 8.39 0.0 1.19 1.18 0.3 1.18 2 0.525 1.24Spike Amount (ug) 0.520Native Amount (ug) 0.685Spike Recovery (%) 107%MSD / U2-NaOH-R1 016-1201.D 016-1202.D 0310-96G.M 8.38 8.39 0.0 1.17 1.18 0.3 1.18 2 0.525 1.24Spike Amount (ug) 0.520Native Amount (ug) 0.685Spike Recovery (%) 106%LCS #1 055-1201.D 055-1202.D 0310-96D.M 8.00 8.02 0.2 1.16 1.17 0.4 1.16 100 10.0 1,163Spike Amount (ug) 1,088Spike Recovery (%) 107%LCS #2 056-1501.D 056-1502.D 0310-96D.M 7.97 7.98 0.1 1.15 1.19 1.8 1.17 100 10.0 1,168Spike Amount (ug) 1,088Spike Recovery (%) 107%0310-96 res ctm0334/9/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidCorrectionFactorDFVol(mL)CatchWeight(ug)QualUnit 1 Run 1 025-2801.D 025-2802.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 911 384 NDUnit 1 Run 2 028-3501.D 028-3502.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 760 320 NDUnit 1 Run 3 029-3601.D 029-3602.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 747 315 NDUnit 2 Run 1 030-3701.D 030-3702.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 723 305 NDUnit 2 Run 2 031-3801.D 031-3802.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 785 331 NDUnit 2 Run 3 032-3901.D 032-3902.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 840 354 NDField Blank033-4001.D 033-4002.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 499 210 NDRB H2SO4034-4301.D 034-4302.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 150 63.0 ND0.01N H2SO4/NaOH Blank 007-0801.D 007-0802.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 1 1.00 0.0211 ND0.01N H2SO4/NaOH Blank 093-3201.D 093-3202.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 1 1.00 0.0211 NDHydrogen Fluoride as FluorideCompanyAnalystParameters# SamplesURS Corp. - RTPEOEPA Method 26A6 Runs, 2 BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/20100310-96 res m26a4/9/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidCorrectionFactorDFVol(mL)CatchWeight(ug)QualHydrogen Fluoride as FluorideCompanyAnalystParameters# SamplesURS Corp. - RTPEOEPA Method 26A6 Runs, 2 BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/2010MS U1 R1026-3301.D 026-3302.D HPLC51PG56.M 2.79 2.79 0.0 3.31 3.32 0.2 3.31 1.053 1 10.0 34.9Spike Amount (ug) 31.6Native Amount (ug) 0.00Spike Recovery (%) 110%MSD U1 R1 027-3401.D 027-3402.D HPLC51PG56.M 2.80 2.79 0.0 3.32 3.31 0.1 3.31 1.053 1 10.0 34.9Spike Amount (ug) 31.6Native Amount (ug) 0.00Spike Recovery (%) 110%HPLC51pg56 #LCS 006-0701.D 006-0702.D HPLC51PG56.M 2.79 2.79 0.0 4.20 4.21 0.1 4.21 1.053 1 1.00 4.43Spike Amount (ug) 4.21Spike Recovery (%) 105%HPLC51pg56 #LCS 092-3101.D 092-3102.D HPLC51PG56.M 2.80 2.80 0.0 4.23 4.23 0.1 4.23 1.053 1 1.00 4.45Spike Amount (ug) 4.21Spike Recovery (%) 106%0310-96 res m26a4/9/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidCorrectionFactorDFVol(mL)CatchWeight(ug)QualUnit 1 Run 1 025-2801.D 025-2802.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 911 375 NDUnit 1 Run 2 028-3501.D 028-3502.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 760 313 NDUnit 1 Run 3 029-3601.D 029-3602.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 747 307 NDUnit 2 Run 1 030-3701.D 030-3702.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 723 297 NDUnit 2 Run 2 031-3801.D 031-3802.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 785 323 NDUnit 2 Run 3 032-3901.D 032-3902.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 840 345 NDField Blank033-4001.D 033-4002.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 499 205 NDRB H2SO4034-4301.D 034-4302.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 150 61.5 ND0.01N H2SO4/NaOH Blank 007-0801.D 007-0802.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 1 1.00 0.0206 ND0.01N H2SO4/NaOH Blank 093-3201.D 093-3202.D HPLC51PG56.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 1 1.00 0.0206 NDHydrogen Chloride as ChlorideCompanyAnalystParameters# SamplesURS Corp. - RTPEOEPA Method 26A6 Runs, 2 BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/20100310-96 res m26a4/9/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidCorrectionFactorDFVol(mL)CatchWeight(ug)QualHydrogen Chloride as ChlorideCompanyAnalystParameters# SamplesURS Corp. - RTPEOEPA Method 26A6 Runs, 2 BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/2010MS U1 R1026-3301.D 026-3302.D HPLC51PG56.M 3.74 3.74 0.0 2.85 2.85 0.0 2.85 1.028 1 10.0 29.3Spike Amount (ug) 30.8Native Amount (ug) 0.00Spike Recovery (%) 94.9%MSD U1 R1 027-3401.D 027-3402.D HPLC51PG56.M 3.74 3.74 0.0 2.85 2.85 0.1 2.85 1.028 1 10.0 29.3Spike Amount (ug) 30.8Native Amount (ug) 0.00Spike Recovery (%) 95.1%HPLC51pg56 #LCS 006-0701.D 006-0702.D HPLC51PG56.M 3.77 3.77 0.0 3.78 3.78 0.0 3.78 1.028 1 1.00 3.89Spike Amount (ug) 4.11Spike Recovery (%) 94.5%HPLC51pg56 #LCS 092-3101.D 092-3102.D HPLC51PG56.M 3.74 3.74 0.0 3.80 3.80 0.0 3.80 1.028 1 1.00 3.91Spike Amount (ug) 4.11Spike Recovery (%) 95.0%0310-96 res m26a4/9/2010Analysis of Condensible Particulate RecoverySample ID Number Field BlankUnit 1 Run 1Unit 1 Run 2Unit 1 Run 3OrganicBeaker Number3526352035213522Initial Acetone Volume, mL 21837338Initial MeCl2 Volume, mL 17165167142Lab MeCl2 Volume, mL165 Dates165Dates165Dates 165 DatesFinal Weight, g2.6551 3/30/10 2.6819 3/30/10 2.6597 3/30/10 2.6583 3/30/10Reweigh, Final, g2.6550 3/31/10 2.6817 3/31/10 2.6596 3/31/10 2.6582 3/31/10Beaker Tare, g2.6468 3/24/10 2.6615 3/24/10 2.6446 3/24/10 2.6452 3/24/10Net Organic Catch, mg8.320.315.013.0InorganicBeaker Number3565Dates3559Dates3560Dates3561DatesFinal Weight, g2.6707 3/30/10 2.9634 3/30/10 2.8499 3/30/10 2.9662 3/30/10Reweigh, Final, g2.6706 3/31/10 2.9630 3/31/10 2.8498 3/31/10 2.9660 3/31/10Beaker Tare, g2.6642 3/26/10 2.6318 3/26/10 2.6288 3/26/10 2.6288 3/26/10H2O FV, mL86534498503Resuspended Volume, mL 100100100100Removed Pre-aliquot, mL 0.50.50.50.5Pre-aliquot CF1.011.0011.0011.001Removed Post-aliquot, mL 0.50.50.50.5Post-aliquot CF1.011.011.011.01Net Inorganic, mg6.5333.2222.3339.3Ammonium Correction, mg 0.12.41.92.9Corrected Inorganic, mg6.3330.8220.4336.4Condensible Particulate Matter, mg 14.6351.1235.5349.4TB Corrected CPM, mg349.1233.5347.4-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3528Beaker Number3567Beaker Number3530Tare weight, g2.6319Tare weight, g2.6558Tare weight, g2.6660Dry Residue Weight, g 2.6393Dry Residue Weight, g 2.6569Dry Residue Weight, g 2.6658Reweigh, Final, g2.6393Reweigh, Final, g2.6568Reweigh, Final, g 2.6658MeCl2 Residue, g0.0074Water Residue, g0.0010Acetone Residue, g -0.0002MeCl2 Volume, mL110Water Volume, mL106Acetone Volume, mL 77Max. MeCl2 Residue, g 0.0022Max. Water Residue, g 0.0011Max. Acetone Residue, g 0.0006---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3529Beaker Number3568Beaker Number3531Tare weight, g2.6235Tare weight, g2.6607Tare weight, g2.6675Dry Residue Weight, g 2.6264Dry Residue Weight, g 2.6612Dry Residue Weight, g 2.6674Reweigh, Final, g2.6264Reweigh, Final, g2.6611Reweigh, Final, g 2.6674MeCl2 Residue, g0.0029Water Residue, g0.0005Acetone Residue, g -0.0001MeCl2 Volume, mL225Water Volume, mL250Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045Max. Water Residue, g 0.0025Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesURS Corp. - RTPARMEPA OTM-286 Runs, BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/2010Analysis of Condensible Particulate RecoverySample ID Number Field BlankUnit 2 Run 1Unit 2 Run 2Unit 2 Run 3OrganicBeaker Number3526352335243525Initial Acetone Volume, mL 21546616Initial MeCl2 Volume, mL 1712712480Lab MeCl2 Volume, mL165 Dates165Dates165Dates 165 DatesFinal Weight, g2.6551 3/30/10 2.6698 3/30/10 2.6620 3/30/10 2.6564 3/30/10Reweigh, Final, g2.6550 3/31/10 2.6697 3/31/10 2.6618 3/31/10 2.6564 3/31/10Beaker Tare, g2.6468 3/24/10 2.6559 3/24/10 2.6492 3/24/10 2.6455 3/26/10Net Organic Catch, mg8.313.912.710.9InorganicBeaker Number3565Dates3562Dates3563Dates3564DatesFinal Weight, g2.6707 3/30/10 2.8206 3/30/10 2.8386 3/30/10 2.8928 3/30/10Reweigh, Final, g2.6706 3/31/10 2.8206 3/31/10 2.8385 3/31/10 2.8927 3/31/10Beaker Tare, g2.6642 3/26/10 2.6614 3/26/10 2.6603 3/26/10 2.6570 3/26/10H2O FV, mL86559487525Resuspended Volume, mL 100100100100Removed Pre-aliquot, mL 0.50.50.50.5Pre-aliquot CF1.011.0011.0011.001Removed Post-aliquot, mL 0.50.50.50.5Post-aliquot CF1.011.011.011.01Net Inorganic, mg6.5160.2179.2237.1Ammonium Correction, mg 0.11.02.62.8Corrected Inorganic, mg6.3159.2176.6234.3Condensible Particulate Matter, mg 14.6173.1189.3245.2TB Corrected CPM, mg171.1187.3243.2-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3528Beaker Number3567Beaker Number3530Tare weight, g2.6319Tare weight, g2.6558Tare weight, g2.6660Dry Residue Weight, g 2.6393Dry Residue Weight, g 2.6569Dry Residue Weight, g 2.6658Reweigh, Final, g2.6393Reweigh, Final, g2.6568Reweigh, Final, g 2.6658MeCl2 Residue, g0.0074Water Residue, g0.0010Acetone Residue, g -0.0002MeCl2 Volume, mL110Water Volume, mL106Acetone Volume, mL 77Max. MeCl2 Residue, g 0.0022Max. Water Residue, g 0.0011Max. Acetone Residue, g 0.0006---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3529Beaker Number3568Beaker Number3531Tare weight, g2.6235Tare weight, g2.6607Tare weight, g2.6675Dry Residue Weight, g 2.6264Dry Residue Weight, g 2.6612Dry Residue Weight, g 2.6674Reweigh, Final, g2.6264Reweigh, Final, g2.6611Reweigh, Final, g 2.6674MeCl2 Residue, g0.0029Water Residue, g0.0005Acetone Residue, g -0.0001MeCl2 Volume, mL225Water Volume, mL250Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045Max. Water Residue, g 0.0025Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesURS Corp. - RTPARMEPA OTM-286 Runs, BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/2010Analysis of Condensible Particulate RecoverySample ID Number Field BlankFilter BlankRun 8Run 9OrganicBeaker Number35263527Initial Acetone Volume, mL 2100 0Initial MeCl2 Volume, mL 1700 0Lab MeCl2 Volume, mL165 Dates165Dates165Dates 165 DatesFinal Weight, g2.6551 3/30/10 2.6520 3/30/10Reweigh, Final, g2.6550 3/31/10 2.6520 3/31/10Beaker Tare, g2.6468 3/24/10 2.6492 3/24/10Net Organic Catch, mg8.32.90.00.0InorganicBeaker Number3565Dates3566DatesDatesDatesFinal Weight, g2.6707 3/30/10 2.6776 3/30/10Reweigh, Final, g2.6706 3/31/10 2.6775 3/31/10Beaker Tare, g2.6642 3/26/10 2.6673 3/26/10H2O FV, mL86750 0Resuspended Volume, mL 100100100.0100.0Removed Pre-aliquot, mL 0.50.50.50.5Pre-aliquot CF1.011.010.000.00Removed Post-aliquot, mL 0.50.50.50.5Post-aliquot CF1.011.011.011.01Net Inorganic, mg6.510.30.00.0Ammonium Correction, mg 0.10.00.00.0Corrected Inorganic, mg6.310.30.00.0Condensible Particulate Matter, mg 14.613.20.00.0TB Corrected CPM, mg11.2-2.0-2.0-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3528Beaker Number3567Beaker Number3530Tare weight, g2.6319Tare weight, g2.6558Tare weight, g2.6660Dry Residue Weight, g 2.6393Dry Residue Weight, g 2.6569Dry Residue Weight, g 2.6658Reweigh, Final, g2.6393Reweigh, Final, g2.6568Reweigh, Final, g 2.6658MeCl2 Residue, g0.0074Water Residue, g0.0010Acetone Residue, g -0.0002MeCl2 Volume, mL110Water Volume, mL106Acetone Volume, mL 77Max. MeCl2 Residue, g 0.0022Max. Water Residue, g 0.0011Max. Acetone Residue, g 0.0006---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3529Beaker Number3568Beaker Number3531Tare weight, g2.6235Tare weight, g2.6607Tare weight, g2.6675Dry Residue Weight, g 2.6264Dry Residue Weight, g 2.6612Dry Residue Weight, g 2.6674Reweigh, Final, g2.6264Reweigh, Final, g2.6611Reweigh, Final, g 2.6674MeCl2 Residue, g0.0029Water Residue, g0.0005Acetone Residue, g -0.0001MeCl2 Volume, mL225Water Volume, mL250Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045Max. Water Residue, g 0.0025Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesURS Corp. - RTPARMEPA OTM-286 Runs, BlanksClient #Job #PO #Report Date396821750310-96226013.US3/31/2010MDL 0.09 (mg Ammonium) MDL 0.26 (mg Sulfate)
Blank titrant amount (Vtb) 0.03 [Set this equal to the In-House Blank Titration Volume and then white out this note] NH4OH normality 0.1 Lot # Sigma Aldrich 318620

Sample ID. Volume Resuspended (mL) Titration Aliquot Vol (mL) Aliquot Factor (mL rec'd/aliq mL)

Field Blank 100 99.5 0.10 1.01 0.34 0.12
Unit 1 Run 1 100 99.5 1.44 1.01 6.81 2.41
Unit 1 Run 2 100 99.5 1.14 1.01 5.36 1.90
Unit 1 Run 3 100 99.5 1.71 1.01 8.11 2.88
Unit 2 Run 1 100 99.5 0.62 1.01 2.85 1.01
Unit 2 Run 2 100 99.5 1.55 1.01 7.34 2.60
Unit 2 Run 3 100 99.5 1.69 1.01 8.01 2.84
Filter Blank 100 99.5 0.08 ND 1.01 0.26 ND 0.09 ND Reagent Blank 100 99.5 0.08 ND 1.01 0.26 ND 0.09 ND SO4 Catch (mg) NH 4 OH
Titration Vol (mL) Ammonium equivalent (mg) Company

Analyst Parameters # Samples URS Corp. - RTP ARM EPA OTM-28 6 Runs, Blanks Client # Job # PO # Report Date 39682175 0310-96 226013.US 3/31/2010

# Narrative Summary

# Enthalpy Analytical Narrative Summary

Company 

### URS Corp. - RTP Client # 

### 39682175

Analyst 

### KHB Job # 

### 0310-96
Parameters 

### EPA CTM-033 PO # 

### 226013.US

# Samples 

### 6 Runs, 6 Blanks Report Date 

### April 8, 2010

Custody Heather Tarjeft received the samples on 3/18/10 after being relinquished by URS Corporation of Research Tria ngle Park, NC. The samples were received at 5.2  C and in good condition. The NaOH fractions were received at a pH of 12 or greater. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for hydrogen cyanide using the analytical procedures in EPA Conditional Test Method 033, Sampling and Analysis for Hydrogen Cyanide Emissions from Stationary Sources.
The samples were analyzed followi ng the procedures in Section 11.0, Analytical Procedures.
The DIONEX Model 500, High Perfor mance Liquid Chromatograph ("Grandmama") was equipped with a DIONEX ED40 Electrochemical Detector and a Dionex Ion Pac AS7, 4 x 250 mm column (S/N 012759).

Calibration The calibration curves are located in the back of this report and referenced in the Analysis Method column on the Detailed Results page.
For each calibration curve used, the firs t page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound.

Chromatographic Conditions The acquisition method 1000.M is included in the Calibration Curve Chromatograms section of this report.
QC Notes As required in Section 9.0, Quality C ontrol, client-provided field blank, reagent blank and field spike were analyzed. In the laboratory the following QC samples were analyzed: method blank, Matrix Spike/Matrix Spike Duplicate, and a replicate analysis. All method required acceptance criteria were met.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes (continued) A matrix spike and matrix spike duplicate (MS and MSD) were performed on the sample U2-NaOH-R1 and exhibited recovery values of 106% and 107%.
A Laboratory Duplicate (LD) analys is was performed on the sample U2-NaOH-R1. The result differed from the initial result by 9%.
Prior to sample collection the labor atory prepared aqueous spikes, each of which contained 1,088 μg of hydroge n cyanide. Five aqueous spikes were sent to the client and two were retained by the laboratory for use as Laboratory Control Samples (LCSs).
The LCSs were then analyzed in the same manner as the samples and both exhibited recovery values of 107%.
The volumes as measured by the la boratory were used for reporting

purposes. All sample preparation and analytical holding times specified in the method were met. In Section 11.1.2 the specified analytical holding time is 30 days from collection.
Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.
Enthalpy Analytical, Inc. is accredited to perform this method for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company 

### URS Corp. - RTP Client # 

### 39682175

Analyst 

### EO Job # 

### 0310-96
Parameters 

### EPA Method 26A PO # 

### 226013.US

# Samples 

### 6 Runs, 2 Blanks Report Date 

### March 31, 2010

Custody Heather Tarjeft received the samples on 3/19/10 after being relinquished by URS Corporation of Research Tr iangle Park, NC. The samples were received at 17.2  C and in good condition. Pr ior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for hydrogen chloride (HCl) and hydrogen fluoride (HF) using the analytical procedures in EPA Method 26A, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Me thod (40 CFR Part 60, Appendix A).
The samples were analyzed followi ng the procedures in Section 11.0, Analytical Procedures. All samples and standards are prepared, stored, and analyzed using high-density polyethylene containers.
Samples for Unit 1 were received in two containers per run. Proportional aliquots were taken and combined for a single analysis.
The Metrohm 861 Compact IC ("Smithers" S/N 1861002007189) was equipped with a Metrohm 861 Conductiv ity Detector and a Metrosep A Supp 5 - 110/4.0mm column (S/N # 905298).

Calibration The calibration curve is located in the back of this report and referenced in the Analysis Method column on the Detailed Results page.
The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) us ed to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (c orresponding units), Area, Response Factor (Amt/Area) and the analyte Na me. The calibration table is used to identify (by retention time) and quantify each target compound.

Chromatographic Conditions The acquisition method Metrohm.M is included in the Calibration Curve Chromatograms section of this report.
QC Notes As required in Section 7.2.2, Absorbing Solution Blanks, clientprovided field and reagent blanks were analyzed. Additionally, a quality control check sample was an alyzed at the same time as the blanks and samples. All method required acceptance criteria were met.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes (continued) A matrix spike and a matrix spike duplicate sample were performed on the sample Unit 1 Run 1 . The matrix spike samples exhibited recovery values of 94.9% and 95.1% for HCl and 110% and 110% for HF.
The Laboratory Control Samples (L CS) prepared and analyzed along with the samples exhibited recovery values of 105% and 106% for HF and 94.5% and 95.0% for HCL.
All sample preparation and analytical holding times specified in the method were met. Section 13.2, Sample Stability, specifies an analytical holding time of four weeks.
Reporting Notes The H 2 

### SO 4 

### matrix samples were analyzed for Cl - 

### and F - 

### but are reported as HCl and HF, respectively. The resu lts were converted using an acid conversion factor of 1.028 for HCl and 1.053 for HF.
The results presented in this report are representative of the samples as provided to the laboratory.
Enthalpy Analytical, Inc. is accredited to perform this method for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company 

### URS Corp. - RTP Client # 

### 39682175

Analyst 

### ARM Job # 

### 0310-96
Parameters 

### EPA OTM-028 PO # 

### 226013.US

# Samples 

### 6 Runs, Blanks Report Date 

### March 31, 2010

Custody Heather Tarjeft received the samples on 3/19/10 after being relinquished by URS Corporation of of Research Triangle Park, NC. The samples were received at 19.1  C and in good condition. Prior to, during, and after analysis, the samples were ke pt under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for Par ticulate Matter using the analytical procedures in EPA Other Test Method (OTM) 28, Dry Inpinger Method for Determining Condensable Partic ulate Emissions from Stationary Sources.
All samples were weighed on a Sartorius Model ME 5-F (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010, (NIST Test Weight # 1481174).
QC Notes A field blank, filter blank, acetone blank, water blank, and methylene chloride blank were received and analyzed with these samples.
The method specifies blank correcti ons are accomplished by subtracting the particulate mass determined in the ‘Field Train Blank’ or 2 mg (whichever is less) from the sample weight.
The inorganic results for the sample s were corrected for the ammonium ions used to precipitate the sulf ate, per the formula in the Method (Section 12.2.1).
When the pH of the samples was meas ured to be 7.0 or greater with the pH meter, no titrant was added.
All sample preparation and analytical holding times specified in the method were met.
Reporting Notes Enthalpy Analytical, Inc. considers gravimetric analyses for OTM-028 ±0.5 mg. Therefore, negative catch weights between 0 and –0.5 mg are set to zero and no investigation is undertaken. Negative catch weights < -0.5 mg are investigated. None of the catch results for this data set were < -0.5 mg.
The results presented in this report are representative of the samples as provided to the laboratory.

# General Reporting Notes

The following are general reporting notes that are a pplicable to all Enthalpy Analytical, Inc. data reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.

 The acronym ND following a value indicates a non-detect or analytical result below the MDL.

 The letter J following a value indicates an analytical r esult between the MDL and the LOQ. A J flag indicates that the laboratory can positively identify th e analyte of interest as present, but the value should be considered an estimate.

 The letter E following a value indicates an analytical r esult exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analyti cal result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results.

 The addition of MS to the Sample ID represents a Matrix Sp ike. An aliquot of an actual sample is spiked with a known amount of analyte so that a per cent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s).

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.

 The addition of LD to the Sample ID represents a Laborat ory Duplicate. The analyst prepares an additional aliquot of sample for testing and the resu lts of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).

 The addition of AD to the Sample ID represents an Alte rnate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usu ally double the initial factor). This analysis helps confirm that no additional compound is present and coel uting or sharing absorbance with the analyte of interest, as they would have a different res ponse/absorbance than the analyte of interest.

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laborator y using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. The extras (randomly chosen) are labeled with the asso ciated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection and/or sample transport.

# General Reporting Notes

(continued)

 Significant Figures : Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. Ther e are five significant digits displayed, but no confidence should be placed on more than two significant digits.

 Manual Integration : The data systems used for processing w ill flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations. The peak was not integrated by the software “NI” , the peak

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP” . These codes will accompany the analyst’s ma nual integration stamp placed next to the compound name.

# Sample Custody--------------------------- 

## Chain of Custody Record

Project 

## AES ICR Test .... 

## .8 E Site 

## Guayama, PR :::I ex) Z N


### .... I <D Project

## ~ c:
Number 

# 39682175 0

## ~

.... 0 by Jerry Workman <D (.,) Q. C 0'1 CI) c:

# ~ "a Sample 10 Code DatelTime "0 Q. Sample Matrix 0 :.2 

### :::c :E CI) Comments

AGY -U1-27/28-IMR-1 Methylene Chloride 3/5/2010 

## X Unit 1 Run 1

AGY-U1-27/28-IMR-2 Methylene Chloride 3/5/2010 

## X Unit 1 Run 2

-27128-IMR-3 Methylene Chloride 3/6/2010 

## X Unit 1 Run 3

Methylene Chloride 3/1312010 

## X Unit 2 Run 1

Methylene Chloride 3113/2010 

## X Unit 2 Run 2

MR-3 Methylene Chloride 3/14/2010 

## X Unit 2 Run 3

Methylene Chloride 3/812010 

## X Field Blank

Methylene Chloride 3/8/2010 

## X**t~;** Reagent Blank

Water 3/8/2010 

## X**P6~** 

# ..**~**

### ~ 

# 3tcnho

Remarks: Technical Contact is Jerry Workman (919) 461-1289

Relinquished by:

Received by:

Relinquished by:

Received by:

## Chain of Custody Record

Page 1 of

Project 

## AES ICRTest

r-- co N N 

### ,

I 

### ::?! Site 

## Guayama, PR

....

## ~ t- Q) O 0 

# i c



# ... 

# ... Q) Q) 

## 39682175 a.. a..
0 (.) ';:: Q) 

### c Cl C 

### E 'Q.. 'S; '0 0.. 

### f! Sample Matrix '0 :2 ::I: CJ) Comments G

Unit 1 Run 1 Acetone

Unit 1 Run 2 Acetone

Unit 1 Run 3 Acetone

Unit 1 Run 1 Acetone

Unit 1 Run 2 Acetone

Unit 1 Run 3 Acetone

Acetone

Acetone

Acetone



### 10

# Sample Chromatogramsmin 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\036-4901.D)

A

r ea

: 47 .

5 631.4741.7578.358 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.358 MM 47.56303 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\036-4901.D Sample Name: U1-Pb-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 49 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 2:47:50 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:00:33 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\036-4902.D)

A

r ea

: 48

. 8 26

61.4731.7538.312 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.312 MM 48.82658 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\036-4902.D Sample Name: U1-Pb-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 49 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 3:03:06 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:00:52 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\037-5001.D)1.4801.6191.7312.1828.220 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.220 BB 1370.48254 9.70414e-4 1.32993 Hydrogen Cyanide

Totals : 1.32993

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\037-5001.D Sample Name: U1-NaOH-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 3:18:23 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:01:00 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\037-5002.D)1.4791.7342.1888.253 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.253 BB 1355.80103 9.69881e-4 1.31497 Hydrogen Cyanide

Totals : 1.31497

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\037-5002.D Sample Name: U1-NaOH-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 3:33:39 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:01:11 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\038-5101.D)

A

r ea

: 63

. 1 59

51.4771.6881.7658.371 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.371 MM 63.15947 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\038-5101.D Sample Name: U1-Pb-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 51 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 3:48:56 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:01:26 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\038-5102.D)

A

r ea

: 50

. 9 54

51.4761.6911.7648.388 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.388 MM 50.95449 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\038-5102.D Sample Name: U1-Pb-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 51 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 4:04:12 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:01:40 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\039-5201.D)1.4781.6221.7392.1788.256 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.256 BB 936.07892 9.47596e-4 8.87025e-1 Hydrogen Cyanide

Totals : 8.87025e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\039-5201.D Sample Name: U1-NaOH-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 52 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 4:19:30 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:01:48 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\039-5202.D)1.7452.1858.300 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.300 BB 956.22791 9.49113e-4 9.07568e-1 Hydrogen Cyanide

Totals : 9.07568e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\039-5202.D Sample Name: U1-NaOH-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 52 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 4:34:46 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:02:01 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\040-5301.D)

A

r ea

: 60

. 0 79

31.4741.7658.367 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.367 MM 60.07925 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\040-5301.D Sample Name: U1-Pb-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 53 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 4:50:02 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:02:20 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\040-5302.D)

A

r ea

: 58

. 2 78

11.4761.7718.383 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.383 MM 58.27813 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\040-5302.D Sample Name: U1-Pb-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 53 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 5:05:18 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:02:33 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\041-5601.D)1.7532.1838.312 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.312 BB 1019.54974 9.53490e-4 9.72130e-1 Hydrogen Cyanide

Totals : 9.72130e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\041-5601.D Sample Name: U1-NaOH-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 56 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 6:21:41 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:02:42 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\041-5602.D)1.7542.1868.310 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.310 BB 1028.17786 9.54044e-4 9.80927e-1 Hydrogen Cyanide

Totals : 9.80927e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\041-5602.D Sample Name: U1-NaOH-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 56 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 6:36:57 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:02:50 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\042-5701.D)

A

r ea

: 70

. 7 30

91.4811.7678.374 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.374 MM 70.73090 6.68875e-5 4.73102e-3 Hydrogen Cyanide

Totals : 4.73102e-3

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\042-5701.D Sample Name: U2-Pb-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 6:52:15 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:03:06 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\042-5702.D)

A

r ea

: 70

. 0 30

31.4761.7678.341 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.341 MM 70.03030 5.73567e-5 4.01670e-3 Hydrogen Cyanide

Totals : 4.01670e-3

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\042-5702.D Sample Name: U2-Pb-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 7:07:30 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:03:18 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\043-5801.D)1.7312.1578.229 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.229 BB 1391.50391 9.71156e-4 1.35137 Hydrogen Cyanide

Totals : 1.35137

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\043-5801.D Sample Name: U2-NaOH-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 58 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 7:22:47 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:03:29 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\043-5802.D)1.7342.1558.203 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.203 BB 1427.31409 9.72371e-4 1.38788 Hydrogen Cyanide

Totals : 1.38788

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\043-5802.D Sample Name: U2-NaOH-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 58 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 7:38:04 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:03:36 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\044-5901.D)

A

r ea

: 47 .

6 00

21.4811.6071.7648.289 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.289 MM 47.60016 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\044-5901.D Sample Name: U2-Pb-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 59 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 7:53:21 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:03:58 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\044-5902.D)

A

r ea

: 47 .

9 00

21.4781.7678.262 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.262 MM 47.90025 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\044-5902.D Sample Name: U2-Pb-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 59 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 8:08:36 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:04:11 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\045-6001.D)1.7312.1698.155 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.155 BB 1189.37158 9.62926e-4 1.14528 Hydrogen Cyanide

Totals : 1.14528

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\045-6001.D Sample Name: U2-NaOH-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 60 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 8:23:53 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:04:19 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\045-6002.D)1.7342.1708.136 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.136 BB 1201.94104 9.63519e-4 1.15809 Hydrogen Cyanide

Totals : 1.15809

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\045-6002.D Sample Name: U2-NaOH-2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 60 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 8:39:09 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:04:25 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\046-6301.D)

A

r ea

: 11 .

1 26

51.4721.7648.173 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.173 MM 11.12650 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\046-6301.D Sample Name: U2-Pb-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 63 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 9:55:32 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:04:47 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\046-6302.D)

A

r ea

: 12 .

0 70

51.4761.7678.181 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.181 MM 12.07053 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\046-6302.D Sample Name: U2-Pb-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 63 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 10:10:49 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:05:02 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\047-6401.D)1.7272.1538.019 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.019 BB 1203.38965 9.63586e-4 1.15957 Hydrogen Cyanide

Totals : 1.15957

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\047-6401.D Sample Name: U2-NaOH-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 64 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 10:26:05 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:05:11 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\047-6402.D)1.7342.1568.034 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.034 BB 1230.87097 9.64837e-4 1.18759 Hydrogen Cyanide

Totals : 1.18759

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\047-6402.D Sample Name: U2-NaOH-3*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 64 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 10:41:21 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:05:18 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\062-2301.D)1.7312.1328.186 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.186 BB 862.47913 1.72158e-3 1.48483 Hydrogen Cyanide

Totals : 1.48483

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\062-2301.D Sample Name: LD/U2-NaOH-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 23 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 12:58:59 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Lab Duplicate

=====================================================================

Instrument 3 4/6/2010 8:41:27 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\062-2302.D)1.7342.1278.224 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.224 BB 872.12213 1.72236e-3 1.50211 Hydrogen Cyanide

Totals : 1.50211

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\062-2302.D Sample Name: LD/U2-NaOH-1*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 23 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 1:14:15 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Lab Duplicate

=====================================================================

Instrument 3 4/6/2010 8:41:32 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\050-6701.D)1.4761.7478.005 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.005 BB 893.33582 9.44152e-4 8.43445e-1 Hydrogen Cyanide

Totals : 8.43445e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\050-6701.D Sample Name: NaOH FS*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 67 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 11:57:45 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:05:54 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\050-6702.D)1.4811.7508.021 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.021 BB 878.99542 9.42921e-4 8.28823e-1 Hydrogen Cyanide

Totals : 8.28823e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\050-6702.D Sample Name: NaOH FS*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 67 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 12:13:01 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 10:06:00 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\048-6501.D)1.4711.6451.7452.243

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.255 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\048-6501.D Sample Name: NaOH FB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 65 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 10:56:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/3/2010 10:05:28 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\048-6502.D)1.4791.7532.252

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.255 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\048-6502.D Sample Name: NaOH FB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 65 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 11:11:54 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/3/2010 10:05:34 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\049-6601.D)1.4771.756

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.255 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\049-6601.D Sample Name: NaOH RB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 66 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 11:27:12 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/3/2010 10:05:40 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\049-6602.D)1.4801.7572.256

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.255 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\049-6602.D Sample Name: NaOH RB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 66 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 11:42:28 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/3/2010 10:05:47 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\051-0801.D)1.6081.780

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\051-0801.D Sample Name: NaOH FB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 8:15:44 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:39:12 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\051-0802.D)1.4581.6041.779

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\051-0802.D Sample Name: NaOH FB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 8:30:59 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:39:21 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\052-0901.D)1.6131.790

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\052-0901.D Sample Name: NaOH RB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 9 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 8:46:17 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:39:34 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\052-0902.D)1.4681.6171.789

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\052-0902.D Sample Name: NaOH RB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 9 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 9:01:33 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:39:40 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\053-1001.D)1.6121.6601.794

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\053-1001.D Sample Name: NaOH RB2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 10 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 9:16:50 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:39:57 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\053-1002.D)1.6041.6551.795

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\053-1002.D Sample Name: NaOH RB2*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 10 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 9:32:06 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:40:06 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\054-1101.D)1.4601.6531.732

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\054-1101.D Sample Name: H2O RB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 9:47:23 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:40:18 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\054-1102.D)1.4651.6651.735

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\054-1102.D Sample Name: H2O RB*5 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 10:02:39 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Sample Blank

=====================================================================

Instrument 3 4/6/2010 8:40:29 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\007-0801.D)

A

r ea

: 33

. 8 08

71.4721.6701.7418.357 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.357 MM 33.80872 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\007-0801.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 5:54:58 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/6/2010 9:14:09 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\007-0802.D)

A

r ea

: 31 .

4 20

71.4751.6681.7388.358 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.358 MM 31.42074 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\007-0802.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 6:10:14 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/6/2010 9:14:23 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\007-0701.D)1.6491.724

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\007-0701.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 7:45:11 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:27:27 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\007-0702.D)1.6681.737

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\007-0702.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 8:00:27 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:27:35 AM KHB Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\007-0801.D)1.6961.7692.2708.472 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.472 BB 148.58122 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\007-0801.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 1:25:35 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:36:34 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\007-0802.D)1.6871.7662.2668.456 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.456 BB 150.31404 0.00000 0.00000 Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Negative results set to zero (cal. curve intercept), (Hydrogen Cyanide)

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\007-0802.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 1:40:51 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:36:41 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\015-1101.D)

A

r ea

: 15

1 6 .0

71.7582.1878.388 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.388 MM 1516.06641 7.82306e-4 1.18603 Hydrogen Cyanide

Totals : 1.18603

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\015-1101.D Sample Name: MS*2/U2-NaOH-1 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 2:57:14 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB Sample Info : Matrix Spike

=====================================================================

Instrument 3 4/8/2010 4:56:12 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\015-1102.D)

A

r ea

: 15

0 6 .8

41.7582.1918.387 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.387 MM 1506.84326 7.81755e-4 1.17798 Hydrogen Cyanide

Totals : 1.17798

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\015-1102.D Sample Name: MS*2/U2-NaOH-1 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 3:12:29 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB Sample Info : Matrix Spike

=====================================================================

Instrument 3 4/8/2010 4:57:57 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\016-1201.D)

A

r ea

: 15

0 2 .7

91.7592.1878.382 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.382 MM 1502.78699 7.81510e-4 1.17444 Hydrogen Cyanide

Totals : 1.17444

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\016-1201.D Sample Name: MSD*2/U2-NaOH-1 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 12 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 3:27:47 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB Sample Info : Matrix Spike Duplicate

=====================================================================

Instrument 3 4/8/2010 4:43:04 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\016-1202.D)

A

r ea

: 15

1 1 .1

21.7602.1918.386 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.386 MM 1511.12451 7.82011e-4 1.18172 Hydrogen Cyanide

Totals : 1.18172

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\016-1202.D Sample Name: MSD*2/U2-NaOH-1 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 12 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 3:43:09 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB Sample Info : Matrix Spike Duplicate

=====================================================================

Instrument 3 4/8/2010 4:43:24 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\055-1201.D)1.7348.002 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.002 BB 680.45349 1.70276e-3 1.15865 Hydrogen Cyanide

Totals : 1.15865

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\055-1201.D Sample Name: LCS #1*100 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 12 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 10:17:56 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Lab Control Sample

=====================================================================

Instrument 3 4/6/2010 8:40:37 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\055-1202.D)1.4661.6671.7408.021 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.021 BB 685.77051 1.70345e-3 1.16817 Hydrogen Cyanide

Totals : 1.16817

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\055-1202.D Sample Name: LCS #1*100 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 12 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 10:33:12 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Lab Control Sample

=====================================================================

Instrument 3 4/6/2010 8:40:43 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\056-1501.D)1.4331.6631.7337.970 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.970 BB 673.66669 1.70186e-3 1.14649 Hydrogen Cyanide

Totals : 1.14649

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\056-1501.D Sample Name: LCS #2*100 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 11:49:41 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Lab Control Sample

=====================================================================

Instrument 3 4/6/2010 8:40:53 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\056-1502.D)1.4651.6671.7427.980 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.980 BB 697.71216 1.70496e-3 1.18957 Hydrogen Cyanide

Totals : 1.18957

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\056-1502.D Sample Name: LCS #2*100 0310-96

===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 12:04:57 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB Sample Info : Lab Control Sample

=====================================================================

Instrument 3 4/6/2010 8:41:01 AM KHB Page 1 of 1

# Calibration Curve Chromatograms===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.300 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.300 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Ignored Weight : Linear (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 8.255 1 1 1.03500e-1 158.68324 6.52243e-4 Hydrogen Cyanide
2 5.07300e-1 599.87674 8.45674e-4
3 9.90500e-1 1096.56512 9.03275e-4
4 1.54100 1557.83539 9.89193e-4
5 2.08000 2039.49207 1.01986e-3

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M

Instrument 3 4/3/2010 9:40:41 AM KHB Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 1 2 Area

0 250 500 750 1000 1250 1500 1750 2000

1 2 3 4 5 Hydrogen Cyanide at exp. RT: 8.255 ADC1 A, ADC1 CHANNEL A Correlation: 0.99859 Residual Std. Dev.: 56.86690 Formula: y = mx + b
m: 980.79368 b: 66.09075

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.204021 Level 3 : 0.104493 Level 4 : 0.067164 Level 5 : 0.04976

===================================================================== Method H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M

Instrument 3 4/3/2010 9:40:41 AM KHB Page 2 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\001-0201.D)1.4681.6691.7398.325 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.325 BB 158.31195 5.93936e-4 9.40271e-2 Hydrogen Cyanide

Totals : 9.40271e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\001-0201.D Sample Name: hplcprep4pg7 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 2:51:33 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:09 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\001-0202.D)1.4661.7348.310 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.310 BB 159.05453 5.95923e-4 9.47842e-2 Hydrogen Cyanide

Totals : 9.47842e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\001-0202.D Sample Name: hplcprep4pg7 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 3:06:49 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:16 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\002-0301.D)1.4661.6651.7358.302 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.302 BB 594.40326 9.06217e-4 5.38658e-1 Hydrogen Cyanide

Totals : 5.38658e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\002-0301.D Sample Name: hplcprep4pg7 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 3:22:06 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:20 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\002-0302.D)1.4691.6711.7418.301 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.301 BB 605.35022 9.08267e-4 5.49819e-1 Hydrogen Cyanide

Totals : 5.49819e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\002-0302.D Sample Name: hplcprep4pg7 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 3:37:22 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:25 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-0401.D)1.4631.6601.7288.240 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.240 BB 1096.14856 9.58108e-4 1.05023 Hydrogen Cyanide

Totals : 1.05023

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-0401.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 3:52:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:31 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-0402.D)1.4701.7328.272 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.272 BB 1096.98169 9.58155e-4 1.05108 Hydrogen Cyanide

Totals : 1.05108

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-0402.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 4:07:55 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:36 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-0501.D)1.4731.7398.278 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.278 BB 1515.66589 9.75123e-4 1.47796 Hydrogen Cyanide

Totals : 1.47796

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-0501.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 4:23:12 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:43 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-0502.D)1.4681.7358.251 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 BB 1600.00488 9.77467e-4 1.56395 Hydrogen Cyanide

Totals : 1.56395

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-0502.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 4:38:28 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:50 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\005-0601.D)1.4611.6611.7298.233 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.233 BB 2090.05225 9.87342e-4 2.06360 Hydrogen Cyanide

Totals : 2.06360

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\005-0601.D Sample Name: hplcprep4pg7 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 4:53:45 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:41:57 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\005-0602.D)1.4691.7318.263 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.263 BB 1988.93188 9.85702e-4 1.96050 Hydrogen Cyanide

Totals : 1.96050

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\005-0602.D Sample Name: hplcprep4pg7 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 5:09:07 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:42:04 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\006-0701.D)1.4701.6691.7378.288 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.288 BB 959.67920 9.49366e-4 9.11087e-1 Hydrogen Cyanide

Totals : 9.11087e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\006-0701.D Sample Name: hplcprep4pg7 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 5:24:24 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:42:11 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\006-0702.D)1.4641.6661.7378.276 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.276 BB 961.50732 9.49500e-4 9.12951e-1 Hydrogen Cyanide

Totals : 9.12951e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\006-0702.D Sample Name: hplcprep4pg7 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 5:39:40 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:42:18 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-1301.D)1.4681.6641.7338.134 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.134 BB 1585.77869 9.77089e-4 1.54945 Hydrogen Cyanide

Totals : 1.54945

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-1301.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 8:27:47 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:42:35 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-1302.D)1.4721.7368.122 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.122 BB 1596.32336 9.77370e-4 1.56020 Hydrogen Cyanide

Totals : 1.56020

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-1302.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 3/31/2010 8:43:03 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:42:41 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2001.D)1.4801.6651.7418.020 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.020 BB 1608.29333 9.77684e-4 1.57240 Hydrogen Cyanide

Totals : 1.57240

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2001.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 12:01:39 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:42:49 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2002.D)1.4721.6691.7408.019 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.019 BB 1712.51831 9.80234e-4 1.67867 Hydrogen Cyanide

Totals : 1.67867

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2002.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 12:16:55 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:43:12 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2701.D)1.4721.6721.7438.022 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.022 BB 1647.42615 9.78679e-4 1.61230 Hydrogen Cyanide

Totals : 1.61230

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2701.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 27 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 3:35:31 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:43:21 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2702.D)1.4681.7327.982 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.982 BB 1625.98572 9.78140e-4 1.59044 Hydrogen Cyanide

Totals : 1.59044

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-2702.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 27 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 3:50:47 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:43:28 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-3401.D)1.4831.6731.7458.261 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.261 BB 1528.44287 9.75495e-4 1.49099 Hydrogen Cyanide

Totals : 1.49099

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-3401.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 34 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 7:09:28 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:43:42 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-3402.D)1.4821.6751.7488.281 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.281 BB 1560.73547 9.76407e-4 1.52391 Hydrogen Cyanide

Totals : 1.52391

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-3402.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 34 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 7:24:44 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:43:49 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4101.D)1.4791.6681.7388.264 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.264 BB 1502.43188 9.74732e-4 1.46447 Hydrogen Cyanide

Totals : 1.46447

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4101.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 41 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 10:43:25 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:43:58 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4102.D)1.4671.6601.7298.228 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.228 BB 1501.56042 9.74706e-4 1.46358 Hydrogen Cyanide

Totals : 1.46358

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4102.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 41 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 10:58:42 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:44:04 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4801.D)1.4701.6721.7468.275 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.275 BB 1633.78418 9.78338e-4 1.59839 Hydrogen Cyanide

Totals : 1.59839

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4801.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 48 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 2:17:17 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:44:14 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4802.D)1.4711.6661.7368.250 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.250 BB 1599.92737 9.77465e-4 1.56387 Hydrogen Cyanide

Totals : 1.56387

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-4802.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 48 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 2:32:33 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:44:24 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-5501.D)1.4791.6761.7468.313 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.313 BB 1443.40576 9.72898e-4 1.40429 Hydrogen Cyanide

Totals : 1.40429

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-5501.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 55 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 5:51:08 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:44:44 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-5502.D)1.4741.6721.7438.289 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.289 BB 1431.87061 9.72522e-4 1.39253 Hydrogen Cyanide

Totals : 1.39253

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-5502.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 55 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 6:06:24 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:44:56 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-6201.D)1.4721.6661.7388.074 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.074 BB 1414.13306 9.71931e-4 1.37444 Hydrogen Cyanide

Totals : 1.37444

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-6201.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 62 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 9:24:59 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:45:05 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-6202.D)1.4731.6691.7388.066 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.066 BB 1450.10461 9.73113e-4 1.41112 Hydrogen Cyanide

Totals : 1.41112

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\004-6202.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 62 Acq. Instrument : Grandmama Location : - Injection Date : 4/1/2010 9:40:16 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:45:11 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-6801.D)1.4721.6721.7408.017 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.017 BB 946.83807 9.48414e-4 8.97994e-1 Hydrogen Cyanide

Totals : 8.97994e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-6801.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 68 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 12:28:18 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:45:46 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-6802.D)

A

r ea

: 95

7 .

64

41.4801.6701.7418.023 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 01, 2010 8:37:28 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.023 MM 957.64447 9.49217e-4 9.09013e-1 Hydrogen Cyanide

Totals : 9.09013e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96C\003-6802.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 68 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 12:43:33 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96C.M Last changed : 4/2/2010 5:02:15 PM by KHB

=====================================================================

Instrument 3 4/3/2010 9:46:00 AM KHB Page 1 of 1===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.300 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.300 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Ignored Weight : Linear (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 8.267 1 1 1.03500e-1 91.28078 1.13386e-3 Hydrogen Cyanide
2 5.07300e-1 315.68977 1.60696e-3
3 9.90500e-1 596.65891 1.66008e-3
4 1.54100 892.60303 1.72641e-3
5 2.08000 1187.42535 1.75169e-3

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M

Instrument 3 4/6/2010 8:25:06 AM KHB Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 1 2 Area

0 200 400 600 800 1000

1 2 3 4 5 Hydrogen Cyanide at exp. RT: 8.267 ADC1 A, ADC1 CHANNEL A Correlation: 0.99994 Residual Std. Dev.: 7.20496 Formula: y = mx + b
m: 558.04992 b: 33.87075

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.204021 Level 3 : 0.104493 Level 4 : 0.067164 Level 5 : 0.04976

===================================================================== Method H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M

Instrument 3 4/6/2010 8:25:06 AM KHB Page 2 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\001-0101.D)

A

r ea

: 92 .

9 141.4711.6701.7428.308 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.308 MM 92.91398 1.13872e-3 1.05803e-1 Hydrogen Cyanide

Totals : 1.05803e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\001-0101.D Sample Name: hplcprep4pg7 #1

===================================================================== Acq. Operator : KHB Seq. Line : 1 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 4:41:48 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:25:50 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\001-0102.D)

A

r ea

: 89 .

7 03

51.4551.6521.7238.253 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.253 MM 89.70345 1.11534e-3 1.00050e-1 Hydrogen Cyanide

Totals : 1.00050e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\001-0102.D Sample Name: hplcprep4pg7 #1

===================================================================== Acq. Operator : KHB Seq. Line : 1 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 4:57:08 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:25:21 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\002-0201.D)1.4551.6511.7268.221 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.221 BB 322.97928 1.60403e-3 5.18069e-1 Hydrogen Cyanide

Totals : 5.18069e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\002-0201.D Sample Name: hplcprep4pg7 #2

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 5:12:25 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:25:56 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\002-0202.D)1.4681.6651.7368.273 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.273 BB 308.40027 1.59515e-3 4.91944e-1 Hydrogen Cyanide

Totals : 4.91944e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\002-0202.D Sample Name: hplcprep4pg7 #2

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 5:27:41 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:03 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-0301.D)1.4641.6661.7378.232 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.232 BB 605.01593 1.69163e-3 1.02347 Hydrogen Cyanide

Totals : 1.02347

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-0301.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 5:42:58 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:08 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-0302.D)1.4661.6601.7328.245 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.245 BB 588.30188 1.68878e-3 9.93515e-1 Hydrogen Cyanide

Totals : 9.93515e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-0302.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 5:58:15 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:16 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\004-0401.D)1.6661.7418.248 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.248 BB 875.26874 1.72261e-3 1.50775 Hydrogen Cyanide

Totals : 1.50775

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\004-0401.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 6:13:32 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:25 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\004-0402.D)1.4691.6671.7398.255 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.255 BB 909.93732 1.72525e-3 1.56987 Hydrogen Cyanide

Totals : 1.56987

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\004-0402.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 6:28:48 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:39 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\005-0501.D)1.4671.6651.7408.224 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.224 BB 1180.62842 1.74055e-3 2.05494 Hydrogen Cyanide

Totals : 2.05494

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\005-0501.D Sample Name: hplcprep4pg7 #5

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 6:44:05 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:46 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\005-0502.D)1.4581.6581.7308.206 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.206 BB 1194.22229 1.74113e-3 2.07930 Hydrogen Cyanide

Totals : 2.07930

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\005-0502.D Sample Name: hplcprep4pg7 #5

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 6:59:21 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:26:53 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\006-0601.D)1.7358.208 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.208 BB 517.62390 1.67470e-3 8.66864e-1 Hydrogen Cyanide

Totals : 8.66864e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\006-0601.D Sample Name: hplcprep4pg7 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 7:14:38 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:27:06 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\006-0602.D)1.6641.7358.192 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.192 BB 498.90042 1.67030e-3 8.33312e-1 Hydrogen Cyanide

Totals : 8.33312e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\006-0602.D Sample Name: hplcprep4pg7 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 7:29:54 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:27:13 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-1301.D)1.6571.7307.972 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.972 BB 635.89722 1.69651e-3 1.07880 Hydrogen Cyanide

Totals : 1.07880

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-1301.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 10:48:29 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:27:44 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-1302.D)1.4651.6671.7418.006 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.006 BB 637.61737 1.69676e-3 1.08189 Hydrogen Cyanide

Totals : 1.08189

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-1302.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 4/2/2010 11:03:51 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:27:51 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2001.D)1.6631.7358.208 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.208 BB 616.81616 1.69355e-3 1.04461 Hydrogen Cyanide

Totals : 1.04461

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2001.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 11:27:14 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:28:04 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2002.D)1.4641.6661.7418.221 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.221 BB 629.77905 1.69558e-3 1.06784 Hydrogen Cyanide

Totals : 1.06784

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2002.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 11:42:30 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:28:10 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2701.D)1.4681.6671.7438.271 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.271 BB 624.37903 1.69475e-3 1.05816 Hydrogen Cyanide

Totals : 1.05816

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2701.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 27 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 3:01:11 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:28:19 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2702.D)1.4691.6701.7418.251 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 BB 630.06641 1.69562e-3 1.06836 Hydrogen Cyanide

Totals : 1.06836

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-2702.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 27 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 3:16:27 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:28:27 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-3401.D)1.6751.7468.291 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.291 BB 604.33838 1.69152e-3 1.02225 Hydrogen Cyanide

Totals : 1.02225

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-3401.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 34 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 6:35:07 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:28:35 AM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-3402.D)

A

r ea

: 59

4
.

34

11.6581.7318.273 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 06, 2010 8:24:10 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.273 MM 594.34137 1.68983e-3 1.00434 Hydrogen Cyanide

Totals : 1.00434

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96D\003-3402.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 34 Acq. Instrument : Grandmama Location : - Injection Date : 4/3/2010 6:50:24 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 3/17/2010 9:48:43 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96D.M Last changed : 4/6/2010 8:24:11 AM by KHB

=====================================================================

Instrument 3 4/6/2010 8:28:55 AM KHB Page 1 of 1===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.300 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.300 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Ignored Weight : Linear (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 8.520 1 1 1.03500e-1 255.03889 4.05820e-4 Hydrogen Cyanide
2 5.07300e-1 827.54083 6.13021e-4
3 9.90500e-1 1407.16968 7.03895e-4
4 1.54100 1860.77960 8.28148e-4
5 2.08000 2418.35120 8.60090e-4

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M

Instrument 3 4/8/2010 4:22:05 PM KHB Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 1 2 Area

0 500 1000 1500 2000 2500

1 2 3 4 5 Hydrogen Cyanide at exp. RT: 8.520 ADC1 A, ADC1 CHANNEL A Correlation: 0.99525 Residual Std. Dev.: 116.32524 Formula: y = mx + b
m: 1146.38235 b: 156.42553

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.204021 Level 3 : 0.104493 Level 4 : 0.067164 Level 5 : 0.04976

===================================================================== Method H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M

Instrument 3 4/8/2010 4:22:05 PM KHB Page 2 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\001-0201.D)

A

r ea

: 25

3

. 13

51.6861.7652.2728.505 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.505 FM 253.13521 3.33264e-4 8.43608e-2 Hydrogen Cyanide

Totals : 8.43608e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\001-0201.D Sample Name: hplcprep4pg7 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 10:22:16 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:29:35 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\001-0202.D)

A

r ea

: 25

6

. 95

81.6981.7732.2868.525 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.525 MM 256.95786 3.41283e-4 8.76953e-2 Hydrogen Cyanide

Totals : 8.76953e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\001-0202.D Sample Name: hplcprep4pg7 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 10:37:33 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:22:22 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\002-0301.D)1.6821.7602.2688.467 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.467 BB 839.83075 7.09834e-4 5.96141e-1 Hydrogen Cyanide

Totals : 5.96141e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\002-0301.D Sample Name: hplcprep4pg7 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 10:52:49 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:29:45 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\002-0302.D)1.6861.7672.2738.491 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.491 BB 815.25092 7.04936e-4 5.74700e-1 Hydrogen Cyanide

Totals : 5.74700e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\002-0302.D Sample Name: hplcprep4pg7 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 11:08:06 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:29:50 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-0401.D)1.6951.7752.2838.460 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.460 BB 1401.60974 7.74956e-4 1.08619 Hydrogen Cyanide

Totals : 1.08619

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-0401.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 11:23:23 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:29:55 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-0402.D)1.6991.7772.2868.475 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.475 BB 1412.72961 7.75722e-4 1.09589 Hydrogen Cyanide

Totals : 1.09589

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-0402.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 11:38:38 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:30:00 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\004-0501.D)1.6961.7772.2838.458 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.458 BB 1902.18762 8.00575e-4 1.52284 Hydrogen Cyanide

Totals : 1.52284

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\004-0501.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 11:53:55 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:30:09 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\004-0502.D)1.6881.7682.2718.453 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.453 BB 1819.37158 7.97310e-4 1.45060 Hydrogen Cyanide

Totals : 1.45060

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\004-0502.D Sample Name: hplcprep4pg7 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 12:09:12 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:30:15 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\005-0601.D)1.6901.7692.2728.433 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.433 BB 2389.64868 8.15208e-4 1.94806 Hydrogen Cyanide

Totals : 1.94806

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\005-0601.D Sample Name: hplcprep4pg7 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 12:24:29 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:30:21 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\005-0602.D)1.6981.7752.2848.435 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.435 BB 2447.05371 8.16548e-4 1.99814 Hydrogen Cyanide

Totals : 1.99814

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\005-0602.D Sample Name: hplcprep4pg7 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 12:39:45 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:30:29 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\006-0701.D)

A

r ea

: 11

7 0 .1

81.6891.7692.2758.430 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.430 MM 1170.18103 7.55702e-4 8.84308e-1 Hydrogen Cyanide

Totals : 8.84308e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\006-0701.D Sample Name: hplcprep4pg7 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 12:55:01 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:31:04 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\006-0702.D)

A

r ea

: 11

2 0 .7

61.6871.7642.2688.425 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.425 MM 1120.75830 7.50560e-4 8.41196e-1 Hydrogen Cyanide

Totals : 8.41196e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\006-0702.D Sample Name: hplcprep4pg7 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 1:10:18 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:31:20 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-1301.D)

A

r ea

: 13

4 3 .4

91.6891.7692.2758.383 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.383 MM 1343.49377 7.70745e-4 1.03549 Hydrogen Cyanide

Totals : 1.03549

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-1301.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 3:58:32 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:32:25 PM KHB Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-1302.D)1.6891.7692.2748.388 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 08, 2010 4:21:55 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.388 BB 1379.40637 7.73389e-4 1.06682 Hydrogen Cyanide

Totals : 1.06682

===================================================================== *** End of Report *** Data File H:\HPLC2010Q1\GRANDMAM\DATA\MAR\0310-96G\003-1302.D Sample Name: hplcprep4pg7 #3

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 4/8/2010 4:13:48 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q1\GRANDMAM\METHODS\0310-96G.M Last changed : 4/8/2010 4:21:58 PM by KHB

=====================================================================

Instrument 3 4/8/2010 4:32:42 PM KHB Page 1 of 1Method Information

Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified: 3/17/2010 at 9:48:43 AM

Column: Dionex Ionpac AS7 4 X 250mm Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine Flow rate: 1.0 mL/min

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: nC Units/Volt: 1000.000 Peakwidth (Data Rate): 0.133 Min (2.00 Hz) Stop Time: 14.01 Min Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

<no events> method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 7 0.1N NaOH - RB 1000 2 Sample

2 Vial 1 hplcprep4pg7 #1 1000 2 Sample

3 Vial 2 hplcprep4pg7 #2 1000 2 Sample

4 Vial 3 hplcprep4pg7 #3 1000 2 Sample

5 Vial 4 hplcprep4pg7 #4 1000 2 Sample

6 Vial 5 hplcprep4pg7 #5 1000 2 Sample

7 Vial 6 hplcprep4pg7 #LCS 1000 2 Sample

8 Vial 7 0.1N NaOH - RB 1000 2 Sample

9 Vial 8 T5 Run 1*5 0310-127 1000 2 Sample

10 Vial 9 T5 Run 2*5 0310-127 1000 2 Sample

11 Vial 10 T5 Run 3*5 0310-127 1000 2 Sample

12 Vial 3 hplcprep4pg7 #3 1000 2 Sample

13 Vial 4 hplcprep4pg7 #4 1000 2 Sample

14 Vial 11 Blank*5 0310-127 1000 2 Sample

15 Vial 12 Unit 1 R3*5 0310-126 1000 2 Sample

16 Vial 13 Unit 1 R4*5 0310-126 1000 2 Sample

17 Vial 14 Unit 1 R5*5 0310-126 1000 2 Sample

18 Vial 15 Unit 2 R4*5 0310-126 1000 2 Sample

19 Vial 3 hplcprep4pg7 #3 1000 2 Sample

20 Vial 4 hplcprep4pg7 #4 1000 2 Sample

21 Vial 16 Unit 2 R5*5 0310-126 1000 2 Sample

22 Vial 17 Unit 2 R6*5 0310-126 1000 2 Sample

23 Vial 18 Blank*5 0310-126 1000 2 Sample

24 Vial 19 U9-R1-C3*5 0210-93 1000 2 Sample

25 Vial 20 U9-R1-C4*5 0210-93 1000 2 Sample

26 Vial 3 hplcprep4pg7 #3 1000 2 Sample

27 Vial 4 hplcprep4pg7 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96C.S

Instrument 3 4/6/2010 9:16:38 AM KHB Page 1 of 4Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

28 Vial 21 U9-R2-C3*5 0210-93 1000 2 Sample

29 Vial 22 U9-R2-C4*5 0210-93 1000 2 Sample

30 Vial 23 U9-R3-C3*5 0210-93 1000 2 Sample

31 Vial 24 U9-R3-C4*5 0210-93 1000 2 Sample

32 Vial 25 U10-R1-C3*5 0210-93 1000 2 Sample

33 Vial 3 hplcprep4pg7 #3 1000 2 Sample

34 Vial 4 hplcprep4pg7 #4 1000 2 Sample

35 Vial 26 U10-R1-C4*5 0210-93 1000 2 Sample

36 Vial 27 U10-R2-C3*5 0210-93 1000 2 Sample

37 Vial 28 U10-R2-C4*5 0210-93 1000 2 Sample

38 Vial 29 U10-R3-C3*5 0210-93 1000 2 Sample

39 Vial 30 U10-R3-C4*5 0210-93 1000 2 Sample

40 Vial 3 hplcprep4pg7 #3 1000 2 Sample

41 Vial 4 hplcprep4pg7 #4 1000 2 Sample

42 Vial 31 FB Spk*5 0210-93 1000 2 Sample

43 Vial 32 U10-FB-C3*5 0210-93 1000 2 Sample

44 Vial 33 U10-FB-C4*5 0210-93 1000 2 Sample

45 Vial 34 U10-RB-4N NaOH*5 0210-93 1000 2 Sample

46 Vial 35 U10-RB-Pb Ace*5 0210-93 1000 2 Sample

47 Vial 3 hplcprep4pg7 #3 1000 2 Sample

48 Vial 4 hplcprep4pg7 #4 1000 2 Sample

49 Vial 36 U1-Pb-1*5 0310-96 1000 2 Sample

50 Vial 37 U1-NaOH-1*5 0310-96 1000 2 Sample

51 Vial 38 U1-Pb-2*5 0310-96 1000 2 Sample

52 Vial 39 U1-NaOH-2*5 0310-96 1000 2 Sample

53 Vial 40 U1-Pb-3*5 0310-96 1000 2 Sample

54 Vial 3 hplcprep4pg7 #3 1000 2 Sample

55 Vial 4 hplcprep4pg7 #4 1000 2 Sample

56 Vial 41 U1-NaOH-3*5 0310-96 1000 2 Sample

57 Vial 42 U2-Pb-1*5 0310-96 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96C.S

Instrument 3 4/6/2010 9:16:38 AM KHB Page 2 of 4Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

58 Vial 43 U2-NaOH-1*5 0310-96 1000 2 Sample

59 Vial 44 U2-Pb-2*5 0310-96 1000 2 Sample

60 Vial 45 U2-NaOH-2*5 0310-96 1000 2 Sample

61 Vial 3 hplcprep4pg7 #3 1000 2 Sample

62 Vial 4 hplcprep4pg7 #4 1000 2 Sample

63 Vial 46 U2-Pb-3*5 0310-96 1000 2 Sample

64 Vial 47 U2-NaOH-3*5 0310-96 1000 2 Sample

65 Vial 48 NaOH FB*5 0310-96 1000 2 Sample

66 Vial 49 NaOH RB*5 0310-96 1000 2 Sample

67 Vial 50 NaOH FS*5 0310-96 1000 2 Sample

68 Vial 3 hplcprep4pg7 #3 1000 2 Sample

69 Vial 4 hplcprep4pg7 #4 1000 2 Sample

70 Vial 51 NaOH FB*5 0310-96 1000 2 Sample

71 Vial 52 NaOH RB*5 0310-96 1000 2 Sample

72 Vial 53 NaOH RB2*5 0310-96 1000 2 Sample

73 Vial 54 H2O RB*5 0310-96 1000 2 Sample

74 Vial 55 LCS #1*100 0310-96 1000 2 Sample

75 Vial 3 hplcprep4pg7 #3 1000 2 Sample

76 Vial 4 hplcprep4pg7 #4 1000 2 Sample

77 Vial 56 LCS #2*100 0310-96 1000 2 Sample

78 Vial 57 LCS #1*100 0210-93 1000 2 Sample

79 Vial 58 LCS #2*100 0210-93 1000 2 Sample

80 Vial 59 LD/U9-R1-C4*5 0210-93 1000 2 Sample

81 Vial 60 MS/U9-R1-C4 0210-93 1000 2 Sample

82 Vial 3 hplcprep4pg7 #3 1000 2 Sample

83 Vial 4 hplcprep4pg7 #4 1000 2 Sample

84 Vial 61 MSD/U9-R1-C4 0210-93 1000 2 Sample

85 Vial 62 LD/U2-NaOH-1*5 0310-96 1000 2 Sample

86 Vial 63 MS/U2-NaOH-1 0310-96 1000 2 Sample

87 Vial 64 MSD/U2-NaOH-1 0310-96 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96C.S

Instrument 3 4/6/2010 9:16:38 AM KHB Page 3 of 4Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

88 Vial 65 LD/Unit 1 R4*5 0310-126 1000 2 Sample

89 Vial 3 hplcprep4pg7 #3 1000 2 Sample

90 Vial 4 hplcprep4pg7 #4 1000 2 Sample

91 Vial 66 MS/Unit 1 R4 0310-126 1000 2 Sample

92 Vial 67 MSD/Unit 1 R4 0310-126 1000 2 Sample

93 Vial 68 LD/T5 Run 1*5 0310-127 1000 2 Sample

94 Vial 69 MS/T5 Run 1 0310-127 1000 2 Sample

95 Vial 70 MSD/T5 Run 1 0310-127 1000 2 Sample

96 Vial 3 hplcprep4pg7 #3 1000 2 Sample

97 Vial 4 hplcprep4pg7 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96C.S

Instrument 3 4/6/2010 9:16:38 AM KHB Page 4 of 4Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 1 hplcprep4pg7 #1 1000 2 Sample

2 Vial 2 hplcprep4pg7 #2 1000 2 Sample

3 Vial 3 hplcprep4pg7 #3 1000 2 Sample

4 Vial 4 hplcprep4pg7 #4 1000 2 Sample

5 Vial 5 hplcprep4pg7 #5 1000 2 Sample

6 Vial 6 hplcprep4pg7 #LCS 1000 2 Sample

7 Vial 7 0.1N NaOH - RB 1000 2 Sample

8 Vial 51 NaOH FB*5 0310-96 1000 2 Sample

9 Vial 52 NaOH RB*5 0310-96 1000 2 Sample

10 Vial 53 NaOH RB2*5 0310-96 1000 2 Sample

11 Vial 54 H2O RB*5 0310-96 1000 2 Sample

12 Vial 55 LCS #1*100 0310-96 1000 2 Sample

13 Vial 3 hplcprep4pg7 #3 1000 2 Sample

14 Vial 4 hplcprep4pg7 #4 1000 2 Sample

15 Vial 56 LCS #2*100 0310-96 1000 2 Sample

16 Vial 57 LCS #1*100 0210-93 1000 2 Sample

17 Vial 58 LCS #2*100 0210-93 1000 2 Sample

18 Vial 59 LD/U9-R1-C4*5 0210-93 1000 2 Sample

19 Vial 60 MS/U9-R1-C4 0210-93 1000 2 Sample

20 Vial 3 hplcprep4pg7 #3 1000 2 Sample

21 Vial 4 hplcprep4pg7 #4 1000 2 Sample

22 Vial 61 MSD/U9-R1-C4 0210-93 1000 2 Sample

23 Vial 62 LD/U2-NaOH-1*5 0310-96 1000 2 Sample

24 Vial 63 MS/U2-NaOH-1 0310-96 1000 2 Sample

25 Vial 64 MSD/U2-NaOH-1 0310-96 1000 2 Sample

26 Vial 65 LD/Unit 1 R4*5 0310-126 1000 2 Sample

27 Vial 3 hplcprep4pg7 #3 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96D.S

Instrument 3 4/6/2010 9:16:45 AM KHB Page 1 of 2Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

28 Vial 4 hplcprep4pg7 #4 1000 2 Sample

29 Vial 66 MS/Unit 1 R4 0310-126 1000 2 Sample

30 Vial 67 MSD/Unit 1 R4 0310-126 1000 2 Sample

31 Vial 68 LD/T5 Run 1*5 0310-127 1000 2 Sample

32 Vial 69 MS/T5 Run 1 0310-127 1000 2 Sample

33 Vial 70 MSD/T5 Run 1 0310-127 1000 2 Sample

34 Vial 3 hplcprep4pg7 #3 1000 2 Sample

35 Vial 4 hplcprep4pg7 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96D.S

Instrument 3 4/6/2010 9:16:45 AM KHB Page 2 of 2Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 7 0.1N NaOH - RB 1000 2 Sample

2 Vial 1 hplcprep4pg7 #1 1000 2 Sample

3 Vial 2 hplcprep4pg7 #2 1000 2 Sample

4 Vial 3 hplcprep4pg7 #3 1000 2 Sample

5 Vial 4 hplcprep4pg7 #4 1000 2 Sample

6 Vial 5 hplcprep4pg7 #5 1000 2 Sample

7 Vial 6 hplcprep4pg7 #LCS 1000 2 Sample

8 Vial 7 0.1N NaOH - RB 1000 2 Sample

9 Vial 11 MS/U2-NaOH-1 0310-96 1000 2 Sample

10 Vial 12 MSD/U2-NaOH-1 0310-96 1000 2 Sample

11 Vial 15 MS*2/U2-NaOH-1 0310-96 1000 2 Sample

12 Vial 16 MSD*2/U2-NaOH-1 0310-96 1000 2 Sample

13 Vial 3 hplcprep4pg7 #3 1000 2 Sample

14 Vial 4 hplcprep4pg7 #4 1000 2 Sample

15 Vial 13 MS*10/T5 Run 1 0310-127 1000 2 Sample

16 Vial 14 MSD*10/T5 Run 1 0310-127 1000 2 Sample

17 Vial 3 hplcprep4pg7 #3 1000 2 Sample

18 Vial 4 hplcprep4pg7 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\0210-96G.S

Instrument 3 4/8/2010 5:01:55 PM KHB Page 1 of 1

# Sample Chromatograms===================================================================== Acq. Operator : EO Seq. Line : 28 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 12:32:07 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\025-2801.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\025-2801.D Sample Name: U1 R1 *20 0310-96

Instrument 1 3/24/2010 1:51:32 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 28 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 12:42:56 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\025-2802.D)5.802

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\025-2802.D Sample Name: U1 R1 *20 0310-96

Instrument 1 3/24/2010 1:51:43 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 35 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 3:03:17 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\028-3501.D)3.449

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\028-3501.D Sample Name: U1 R2 *20 0310-96

Instrument 1 3/24/2010 1:54:30 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 35 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 3:14:05 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\028-3502.D)3.450

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\028-3502.D Sample Name: U1 R2 *20 0310-96

Instrument 1 3/24/2010 1:54:39 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 36 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 3:24:53 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\029-3601.D)3.4514.5065.804

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\029-3601.D Sample Name: U1 R3 *20 0310-96

Instrument 1 3/24/2010 1:55:23 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 36 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 3:35:41 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\029-3602.D)3.451

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\029-3602.D Sample Name: U1 R3 *20 0310-96

Instrument 1 3/24/2010 1:55:35 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 37 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 3:46:28 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\030-3701.D)3.4514.5055.788

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\030-3701.D Sample Name: U2 R1 *20 0310-96

Instrument 1 3/24/2010 1:56:01 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 37 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 3:57:16 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\030-3702.D)3.5124.5605.850

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\030-3702.D Sample Name: U2 R1 *20 0310-96

Instrument 1 3/24/2010 1:56:13 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 38 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 4:08:04 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\031-3801.D)3.4514.499

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\031-3801.D Sample Name: U2 R2 *20 0310-96

Instrument 1 3/24/2010 1:56:29 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 38 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 4:18:51 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\031-3802.D)3.4504.503

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\031-3802.D Sample Name: U2 R2 *20 0310-96

Instrument 1 3/24/2010 1:57:22 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 39 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 4:29:40 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\032-3901.D)3.4494.501

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\032-3901.D Sample Name: U2 R3 *20 0310-96

Instrument 1 3/24/2010 1:57:33 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 39 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 4:40:27 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\032-3902.D)3.4474.503

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\032-3902.D Sample Name: U2 R3 *20 0310-96

Instrument 1 3/24/2010 1:57:44 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 40 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 4:51:16 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\033-4001.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\033-4001.D Sample Name: FB *20 0310-96

Instrument 1 3/24/2010 1:58:06 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 40 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 5:02:04 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\033-4002.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\033-4002.D Sample Name: FB *20 0310-96

Instrument 1 3/24/2010 1:58:19 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 43 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 5:56:02 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\034-4301.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\034-4301.D Sample Name: RB H2SO4 *20 0310-96

Instrument 1 3/24/2010 1:59:07 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 43 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 6:06:50 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\034-4302.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\034-4302.D Sample Name: RB H2SO4 *20 0310-96

Instrument 1 3/24/2010 1:59:16 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 5:20:15 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\007-0801.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\007-0801.D Sample Name: 0.01N H2SO4/NaOH Blank

Instrument 1 3/24/2010 1:50:34 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 5:31:02 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\007-0802.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\007-0802.D Sample Name: 0.01N H2SO4/NaOH Blank

Instrument 1 3/24/2010 1:50:45 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 32 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 1:58:30 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\093-3201.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\093-3201.D Sample Name: 0.01N H2SO4/NaOH Blank

Instrument 1 3/24/2010 1:53:11 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 32 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 2:09:18 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\093-3202.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 - - - Fluoride 3.775 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\093-3202.D Sample Name: 0.01N H2SO4/NaOH Blank

Instrument 1 3/24/2010 1:53:21 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO Seq. Line : 33 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 2:20:06 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\026-3301.D)2.794 - Fluoride3.743 - Chloride5.0865.7636.233

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.794 BB 213.10400 1.55139e-2 3.30608 Fluoride 3.743 BB 110.73000 2.57113e-2 2.84702 Chloride

Totals : 6.15310

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\026-3301.D Sample Name: MS U1 R1 *20 0310-96

Instrument 1 3/24/2010 1:53:38 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 33 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 2:30:54 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\026-3302.D)2.793 - Fluoride3.742 - Chloride5.0855.7626.232

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.793 BB 213.78407 1.55141e-2 3.31667 Fluoride 3.742 BB 110.83074 2.57110e-2 2.84957 Chloride

Totals : 6.16624

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\026-3302.D Sample Name: MS U1 R1 *20 0310-96

Instrument 1 3/24/2010 1:53:48 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 34 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 2:41:42 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\027-3401.D)2.795 - Fluoride3.743 - Chloride5.0875.7636.233

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.795 BB 213.85445 1.55141e-2 3.31776 Fluoride 3.743 BB 110.87465 2.57109e-2 2.85069 Chloride

Totals : 6.16845

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\027-3401.D Sample Name: MSD U1 R1 *20 0310-96

Instrument 1 3/24/2010 1:54:09 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 34 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 2:52:29 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\027-3402.D)2.794 - Fluoride3.744 - Chloride5.0875.7656.233

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.794 BB 213.30302 1.55140e-2 3.30918 Fluoride 3.744 BB 110.98945 2.57105e-2 2.85360 Chloride

Totals : 6.16278

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\027-3402.D Sample Name: MSD U1 R1 *20 0310-96

Instrument 1 3/24/2010 1:54:18 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 4:58:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\006-0701.D)2.794 - Fluoride3.769 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.794 BB 270.79840 1.55243e-2 4.20394 Fluoride 3.769 BB 147.50558 2.56262e-2 3.78001 Chloride

Totals : 7.98396

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\006-0701.D Sample Name: HPLC51pg56 #LCS

Instrument 1 3/24/2010 1:50:16 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 5:09:27 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\006-0702.D)2.794 - Fluoride3.768 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.794 BB 271.25171 1.55243e-2 4.21100 Fluoride 3.768 BB 147.51759 2.56262e-2 3.78032 Chloride

Totals : 7.99132

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\006-0702.D Sample Name: HPLC51pg56 #LCS

Instrument 1 3/24/2010 1:50:24 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 31 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 1:36:54 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\092-3101.D)2.797 - Fluoride3.744 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 BB 272.30817 1.55245e-2 4.22744 Fluoride 3.744 BB 148.21523 2.56250e-2 3.79802 Chloride

Totals : 8.02546

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\092-3101.D Sample Name: HPLC51pg56 #LCS

Instrument 1 3/24/2010 1:52:52 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 31 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 1:47:43 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\092-3102.D)2.797 - Fluoride3.743 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 BB 272.62543 1.55245e-2 4.23238 Fluoride 3.743 BB 148.30034 2.56249e-2 3.80017 Chloride

Totals : 8.03255

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\092-3102.D Sample Name: HPLC51pg56 #LCS

Instrument 1 3/24/2010 1:53:02 PM ARM Page 1 of 1

# Calibration Curve Chromatograms===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Linear (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC1 B, Metrohm Signal 2: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|---------------
2.806 2 1 1.00000e-1 6.11878 1.63431e-2 Fluoride
2 9.99000e-1 70.82605 1.41050e-2
3 5.07600 354.18941 1.43313e-2
4 9.10000 597.66461 1.52259e-2
5 14.80000 907.06418 1.63164e-2 3.775 2 1 1.00000e-1 2.87020 3.48408e-2 Chloride
2 9.99000e-1 33.95667 2.94198e-2
3 5.07600 194.73593 2.60661e-2
4 9.10000 357.45839 2.54575e-2
5 14.80000 588.98598 2.51279e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M

Instrument 1 3/24/2010 1:26:45 PM ARM Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 200 400 600 800

1 2 3 4 5 Fluoride at exp. RT: 2.806 ADC1 A, ADC1 CHANNEL A Correlation: 0.99851 Residual Std. Dev.: 31.22675 Formula: y = mx + b
m: 64.25766 b: 6.62762e-1

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.1001 Level 3 : 0.019701 Level 4 : 0.010989 Level 5 : 0.006757

Amount[ug/mL] 0 10 Area

0 100 200 300 400 500

1 2 3 4 5 Chloride at exp. RT: 3.775 ADC1 A, ADC1 CHANNEL A Correlation: 0.99973 Residual Std. Dev.: 5.19853 Formula: y = mx + b
m: 39.41669 b: -1.48998

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.1001 Level 3 : 0.019701 Level 4 : 0.010989 Level 5 : 0.006757

===================================================================== Method U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M

Instrument 1 3/24/2010 1:26:45 PM ARM Page 2 of 2===================================================================== Acq. Operator : EO Seq. Line : 2 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 3:10:41 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-0201.D)2.791 - Fluoride3.771 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.791 BB 6.09814 1.41073e-2 8.60283e-2 Fluoride 3.771 BB 2.84644 3.86500e-2 1.10015e-1 Chloride

Totals : 1.96043e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-0201.D Sample Name: HPLC51pg56 #1

Instrument 1 3/24/2010 1:47:13 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 2 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 3:21:29 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-0202.D)2.793 - Fluoride3.773 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.793 BB 6.15458 1.41073e-2 8.68244e-2 Fluoride 3.773 BB 2.84985 3.86341e-2 1.10101e-1 Chloride

Totals : 1.96926e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-0202.D Sample Name: HPLC51pg56 #1

Instrument 1 3/24/2010 1:47:21 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 44 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 6:17:38 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-4401.D)2.791 - Fluoride3.761 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.791 BB 6.08988 1.41073e-2 8.59117e-2 Fluoride 3.761 BB 2.91406 3.83418e-2 1.11731e-1 Chloride

Totals : 1.97642e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-4401.D Sample Name: HPLC51pg56 #1

Instrument 1 3/24/2010 1:47:29 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 44 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 6:28:26 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-4402.D)2.793 - Fluoride3.766 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.793 BB 6.13252 1.41073e-2 8.65133e-2 Fluoride 3.766 BB 2.87045 3.85389e-2 1.10624e-1 Chloride

Totals : 1.97137e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\001-4402.D Sample Name: HPLC51pg56 #1

Instrument 1 3/24/2010 1:47:37 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 3 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 3:32:16 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-0301.D)2.789 - Fluoride3.771 - Chloride5.1665.9136.181

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.789 BB 70.84959 1.54168e-2 1.09227 Fluoride 3.771 BB 33.76752 2.64894e-2 8.94481e-1 Chloride

Totals : 1.98675

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-0301.D Sample Name: HPLC51pg56 #2

Instrument 1 3/24/2010 1:47:50 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 3 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 3:43:05 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-0302.D)2.788 - Fluoride3.768 - Chloride5.1625.9096.183

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.788 BB 71.08764 1.54173e-2 1.09598 Fluoride 3.768 BB 33.87715 2.64858e-2 8.97263e-1 Chloride

Totals : 1.99324

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-0302.D Sample Name: HPLC51pg56 #2

Instrument 1 3/24/2010 1:47:58 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 45 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 6:39:13 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-4501.D)2.790 - Fluoride3.767 - Chloride5.1655.8916.185

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.790 BB 70.53569 1.54161e-2 1.08739 Fluoride 3.767 BB 34.09715 2.64786e-2 9.02844e-1 Chloride

Totals : 1.99023

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-4501.D Sample Name: HPLC51pg56 #2

Instrument 1 3/24/2010 1:48:06 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 45 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 6:50:01 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-4502.D)2.789 - Fluoride3.768 - Chloride5.1725.9046.172

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.789 BB 70.83129 1.54167e-2 1.09199 Fluoride 3.768 BB 34.08488 2.64790e-2 9.02533e-1 Chloride

Totals : 1.99452

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\002-4502.D Sample Name: HPLC51pg56 #2

Instrument 1 3/24/2010 1:48:15 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 3:53:53 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-0401.D)2.795 - Fluoride3.767 - Chloride5.1375.8796.189

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.795 BB 351.93832 1.55330e-2 5.46667 Fluoride 3.767 BB 192.98418 2.55658e-2 4.93380 Chloride

Totals : 10.40047

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-0401.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:48:24 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 4:04:41 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-0402.D)2.841 - Fluoride3.822 - Chloride5.1975.9446.249

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.841 BB 357.80850 1.55335e-2 5.55803 Fluoride 3.822 BB 195.88971 2.55629e-2 5.00752 Chloride

Totals : 10.56554

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-0402.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:48:32 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 46 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 7:00:50 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-4601.D)2.795 - Fluoride3.770 - Chloride5.1585.8956.171

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.795 BB 353.74982 1.55332e-2 5.49486 Fluoride 3.770 BB 195.05389 2.55638e-2 4.98631 Chloride

Totals : 10.48117

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-4601.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:48:41 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 46 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 7:11:37 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-4602.D)2.794 - Fluoride3.771 - Chloride5.1665.9066.160

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.794 BB 353.26099 1.55331e-2 5.48726 Fluoride 3.771 BB 195.01593 2.55638e-2 4.98535 Chloride

Totals : 10.47260

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\003-4602.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:48:49 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 4:15:29 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-0501.D)2.800 - Fluoride3.766 - Chloride5.1255.8686.189

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.800 BB 597.61945 1.55451e-2 9.29005 Fluoride 3.766 BB 356.49597 2.54760e-2 9.08209 Chloride

Totals : 18.37214

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-0501.D Sample Name: HPLC51pg56 #4

Instrument 1 3/24/2010 1:48:57 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 4:26:16 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-0502.D)2.800 - Fluoride3.768 - Chloride5.1315.8746.190

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.800 BB 596.18506 1.55450e-2 9.26772 Fluoride 3.768 BB 356.59222 2.54760e-2 9.08453 Chloride

Totals : 18.35226

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-0502.D Sample Name: HPLC51pg56 #4

Instrument 1 3/24/2010 1:49:06 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 47 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 7:22:24 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-4701.D)2.799 - Fluoride3.771 - Chloride5.1605.9046.157

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.799 BB 598.91089 1.55451e-2 9.31014 Fluoride 3.771 BB 358.35028 2.54754e-2 9.12913 Chloride

Totals : 18.43928

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-4701.D Sample Name: HPLC51pg56 #4

Instrument 1 3/24/2010 1:49:17 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 47 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 7:33:13 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-4702.D)2.800 - Fluoride3.774 - Chloride5.1695.9156.147

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.800 BB 597.94305 1.55451e-2 9.29508 Fluoride 3.774 BB 358.39508 2.54754e-2 9.13027 Chloride

Totals : 18.42535

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\004-4702.D Sample Name: HPLC51pg56 #4

Instrument 1 3/24/2010 1:49:26 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 4:37:04 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-0601.D)2.808 - Fluoride3.768 - Chloride5.8656.191

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.808 BB 904.42017 1.55509e-2 14.06459 Fluoride 3.768 BB 587.19165 2.54343e-2 14.93483 Chloride

Totals : 28.99942

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-0601.D Sample Name: HPLC51pg56 #5

Instrument 1 3/24/2010 1:49:35 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 4:47:52 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-0602.D)2.807 - Fluoride3.766 - Chloride5.1185.8616.194

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.807 BB 905.61633 1.55510e-2 14.08320 Fluoride 3.766 BB 588.26648 2.54342e-2 14.96210 Chloride

Totals : 29.04530

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-0602.D Sample Name: HPLC51pg56 #5

Instrument 1 3/24/2010 1:49:46 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 48 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 7:44:01 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-4801.D)2.807 - Fluoride3.775 - Chloride5.1625.9126.148

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.807 BB 908.30072 1.55510e-2 14.12498 Fluoride 3.775 BB 590.09827 2.54340e-2 15.00857 Chloride

Totals : 29.13355

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-4801.D Sample Name: HPLC51pg56 #5

Instrument 1 3/24/2010 1:49:54 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 48 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 7:54:49 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-4802.D)2.806 - Fluoride3.775 - Chloride5.1675.9196.139

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.806 BB 909.91949 1.55510e-2 14.15017 Fluoride 3.775 BB 590.38751 2.54340e-2 15.01591 Chloride

Totals : 29.16608

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\005-4802.D Sample Name: HPLC51pg56 #5

Instrument 1 3/24/2010 1:50:06 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 17 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 8:34:36 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-1701.D)2.795 - Fluoride3.755 - Chloride5.0895.8186.204

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.795 BB 353.08353 1.55331e-2 5.48449 Fluoride 3.755 BB 193.78250 2.55650e-2 4.95406 Chloride

Totals : 10.43855

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-1701.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:51:05 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 17 Acq. Instrument : Smithers Location : - Injection Date : 3/23/2010 8:45:23 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-1702.D)2.796 - Fluoride3.754 - Chloride5.8086.209

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.796 BB 352.39661 1.55331e-2 5.47380 Fluoride 3.754 BB 193.77600 2.55650e-2 4.95389 Chloride

Totals : 10.42769

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-1702.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:51:17 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 29 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 12:53:43 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-2901.D)2.796 - Fluoride3.741 - Chloride5.0365.7426.225

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.796 BB 353.42969 1.55332e-2 5.48988 Fluoride 3.741 BB 194.13525 2.55647e-2 4.96300 Chloride

Totals : 10.45289

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-2901.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:52:06 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 29 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 1:04:31 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-2902.D)2.797 - Fluoride3.742 - Chloride5.0375.7446.227

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 BB 352.92029 1.55331e-2 5.48195 Fluoride 3.742 BB 194.20056 2.55646e-2 4.96466 Chloride

Totals : 10.44662

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\090-2902.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:52:16 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 41 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 5:12:51 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\100-4101.D)2.795 - Fluoride3.740 - Chloride5.0445.7466.220

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.795 BB 352.20810 1.55331e-2 5.47087 Fluoride 3.740 BB 194.22064 2.55646e-2 4.96517 Chloride

Totals : 10.43604

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\100-4101.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:58:31 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO Seq. Line : 41 Acq. Instrument : Smithers Location : - Injection Date : 3/24/2010 5:23:39 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q1\SMITHERS\METHODS\HPLC51PG56.M Last changed : 3/24/2010 11:55:00 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\100-4102.D)2.796 - Fluoride3.742 - Chloride5.0475.7496.223

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Wednesday, March 24, 2010 11:54:54 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.796 BB 351.85950 1.55330e-2 5.46545 Fluoride 3.742 BB 194.21121 2.55646e-2 4.96493 Chloride

Totals : 10.43038

===================================================================== *** End of Report *** Data File U:\HPLC2010Q1\SMITHERS\DATA\MAR\HPLC51PG56\100-4102.D Sample Name: HPLC51pg56 #3

Instrument 1 3/24/2010 1:58:39 PM ARM Page 1 of 1Method Information

Method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified: 2/23/2010 at 8:12:27 AM

========================================================================= ANALOG DIGITAL CONVERTER

=========================================================================  Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: μS/cm Units/Volt: 100.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:
<no events> method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified on: 2/23/2010 at 8:12:27 AM

Smithers 3/16/2010 1:54:21 PM KHB/EO Page 1 of 1Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 127 DI Rinse METROHM 4 Sample

2 Vial 1 HPLC51pg56 #1 METROHM 2 Sample

3 Vial 2 HPLC51pg56 #2 METROHM 2 Sample

4 Vial 3 HPLC51pg56 #3 METROHM 2 Sample

5 Vial 4 HPLC51pg56 #4 METROHM 2 Sample

6 Vial 5 HPLC51pg56 #5 METROHM 2 Sample

7 Vial 6 HPLC51pg56 #LCS METROHM 2 Sample

8 Vial 7 0.01N H2SO4/NaOH Blank METROHM 2 Sample

9 Vial 8 KR-031810-11 *20 0310-117 METROHM 2 Sample

10 Vial 9 MS KR-031810-11 *20 0310-117 METROHM 2 Sample

11 Vial 10 MSD KR-031810-11 *20 0310-117 METROHM 2 Sample

12 Vial 11 KR-031810-12 *20 0310-117 METROHM 2 Sample

13 Vial 12 KR-031810-13 *20 0310-117 METROHM 2 Sample

14 Vial 13 KR-031810-14 *20 0310-117 METROHM 2 Sample

15 Vial 14 U9 R1 *20 0210-93 METROHM 2 Sample

16 Vial 15 MS U9 R1 *20 0210-93 METROHM 2 Sample

17 Vial 90 HPLC51pg56 #3 METROHM 2 Sample

18 Vial 91 HPLC51pg56 #4 METROHM 2 Sample

19 Vial 16 MSD U9 R1 *20 0210-93 METROHM 2 Sample

20 Vial 17 U9 R2 *20 0210-93 METROHM 2 Sample

21 Vial 18 U9 R3 *20 0210-93 METROHM 2 Sample

22 Vial 19 U10 R1 *20 0210-93 METROHM 2 Sample

23 Vial 20 U10 R2 *20 0210-93 METROHM 2 Sample

24 Vial 21 U10 R3 *20 0210-93 METROHM 2 Sample

25 Vial 22 RB DI H2O 0210-93 METROHM 2 Sample

26 Vial 23 RB H2SO4 *20 0210-93 METROHM 2 Sample

27 Vial 24 FB *20 0210-93 METROHM 2 Sample Sequence: U:\HPLC2010Q1\SMITHERS\SEQUENCE\HPLC51PG56.S

Instrument 1 3/24/2010 2:03:12 PM ARM Page 1 of 2Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

28 Vial 25 U1 R1 *20 0310-96 METROHM 2 Sample

29 Vial 90 HPLC51pg56 #3 METROHM 2 Sample

30 Vial 91 HPLC51pg56 #4 METROHM 2 Sample

31 Vial 92 HPLC51pg56 #LCS METROHM 2 Sample

32 Vial 93 0.01N H2SO4/NaOH Blank METROHM 2 Sample

33 Vial 26 MS U1 R1 *20 0310-96 METROHM 2 Sample

34 Vial 27 MSD U1 R1 *20 0310-96 METROHM 2 Sample

35 Vial 28 U1 R2 *20 0310-96 METROHM 2 Sample

36 Vial 29 U1 R3 *20 0310-96 METROHM 2 Sample

37 Vial 30 U2 R1 *20 0310-96 METROHM 2 Sample

38 Vial 31 U2 R2 *20 0310-96 METROHM 2 Sample

39 Vial 32 U2 R3 *20 0310-96 METROHM 2 Sample

40 Vial 33 FB *20 0310-96 METROHM 2 Sample

41 Vial 100 HPLC51pg56 #3 METROHM 2 Sample

42 Vial 101 HPLC51pg56 #4 METROHM 2 Sample

43 Vial 34 RB H2SO4 *20 0310-96 METROHM 2 Sample

44 Vial 1 HPLC51pg56 #1 METROHM 2 Sample

45 Vial 2 HPLC51pg56 #2 METROHM 2 Sample

46 Vial 3 HPLC51pg56 #3 METROHM 2 Sample

47 Vial 4 HPLC51pg56 #4 METROHM 2 Sample

48 Vial 5 HPLC51pg56 #5 METROHM 2 Sample Sequence: U:\HPLC2010Q1\SMITHERS\SEQUENCE\HPLC51PG56.S

Instrument 1 3/24/2010 2:03:12 PM ARM Page 2 of 2

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