**SW-846 Update V FIVE - 1 Revision 6 October 2012**  **CHAPTER FIVE**

**MISCELLANEOUS TEST METHODS**

**Prior to employing the methods in this chapter, ana lysts are advised to consult the**  **disclaimer statement at the front of this manual an d the information in Chapter Two for guidance**  **on the allowed flexibility in the choice of apparat us, reagents, and supplies. In addition, unless**  **specified in a regulation, the use of SW-846 method s is not mandatory in response to Federal**  **testing requirements. The information contained in each procedure is provided by EPA as**  **guidance to be used by the analyst and the regulate d community in making judgments**  **necessary to meet the data quality objectives or ne eds for the intended use of the data.** 

**The following methods are found in Chapter Five:**

Method 5050: **Bomb Preparation Method for Solid Waste** Method 9000 **: Determination of Water in Waste Materials by Karl Fischer** 

**Titration** Method 9001 **: Determination of Water in Waste Materials by Quan titative** 

**Calcium Hydride Reaction** Method 9010C: **Total and Amenable Cyanide: Distillation** Method 9012B: **Total and Amenable Cyanide (Automated Colorimetric , with** 

**Off-line Distillation)** Method 9013A: **Cyanide Extraction Procedure for Solids and Oils** Method 9014: **Titrimetric and Manual Spectrophotometric Determin ative** 

**Methods for Cyanide** Method 9015: **Metal Cyanide Complexes by Anion Exchange**

**Chromatography and UV Detection** Method 9016: **Free Cyanide in Water, Soils and Solid Wastes by**

**Microdiffusion** Method 9020B: **Total Organic Halides (TOX)** Method 9021: **Purgeable Organic Halides (POX)** Method 9022: **Total Organic Halides (TOX) by Neutron Activation Analysis**  Method 9023: **Extractable Organic Halides (EOX) in Solids** Method 9030B: **Acid-Soluble and Acid-Insoluble Sulfides: Distilla tion**  Method 9031: **Extractable Sulfides** Method 9034: **Titrimetric Procedure for Acid-Soluble and Acid-In soluble** 

**Sulfides** Method 9035: **Sulfate (Colorimetric, Automated, Chloranilate)** Method 9036: **Sulfate (Colorimetric, Automated, Methylthymol Blu e, AA II)**  Method 9038: **Sulfate (Turbidimetric)** Method 9056A: **Determination of Inorganic Anions by Ion Chromatog raphy**  Method 9057: **Determination of Chloride from HCl/Cl 2**  **Emission Sampling**

**Train (Methods 0050 and 0051) by Anion Chromatograp hy**  Method 9060A: **Total Organic Carbon** Method 9065: **Phenolics (Spectrophotometric, Manual 4-AAP with D istillation)**  Method 9066: **Phenolics (Colorimetric, Automated 4-AAP with Dist illation)**  Method 9067: **Phenolics (Spectrophotometric, MBTH with Distillat ion)** **SW-846 Update V FIVE - 2 Revision 6 October 2012**  Method 9070A: n **-Hexane Extractable Material (HEM) for Aqueous Samp les**  Method 9071B: n **-Hexane Extractable Material (HEM) for Sludge, Sedi ment,** 

**and Solid Samples** Method 9075: **Test Method for Total Chlorine in New and Used Pet roleum** 

**Products by X-Ray Fluorescence Spectrometry (XRF)** Method 9076: **Test Method for Total Chlorine in New and Used Pet roleum** 

**Products by Oxidative Combustion and Microcoulometr y**  Method 9077: **Test Methods for Total Chlorine in New and Used Pe troleum** 

**Products (Field Test Kit Methods)** Method A: **Fixed End Point Test Kit Method** Method B: **Reverse Titration Quantitative End Point Test Kit**

**Method** Method C: **Direct Titration Quantitative End Point Test Kit**

**Method** Method 9131: **Total Coliform: Multiple Tube Fermentation Techni que**  Method 9132: **Total Coliform: Membrane-Filter Technique** Method 9210A: **Potentiometric Determination of Nitrate in Aqueous Samples** 

**with an Ion-Selective Electrode** Method 9211: **Potentiometric Determination of Bromide in Aqueous Samples** 

**with Ion-Selective Electrode** Method 9212: **Potentiometric Determination of Chloride in Aqueou s Samples** 

**with Ion-Selective Electrode** Method 9213: **Potentiometric Determination of Cyanide in Aqueous Samples** 

**and Distillates with Ion-Selective Electrode** Method 9214: **Potentiometric Determination of Fluoride in Aqueou s Samples** 

**with Ion-Selective Electrode** Method 9215: **Potentiometric Determination of Sulfide in Aqueous Samples** 

**and Distillates with Ion-Selective Electrode** Method 9216: **Potentiometric Determination of Nitrate in Aqueous Samples** 

**with Ion-Selective Electrode** Method 9250: **Chloride (Colorimetric, Automated Ferricyanide AAI)** Method 9251: **Chloride (Colorimetric, Automated Ferricyanide AAI I)**  Method 9253: **Chloride (Titrimetric, Silver Nitrate)** Method 9320: **Radium-228 SW-846 Update V FIVE - 3 Revision 6**  **October 2012 Appendix A: Changes in this version** 

**1. The format was updated to Microsoft Word 2007 .d ocx.**  **2. Methods 9015 and 9016 were added. Method letter for 9014 was updated to A.**  **3. Revision number was changed to 6. The date publ ished was updated to October**  **2012.**