### SPA 

### RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of HazardousWaste (cont'd) RCRA REVISION CHECKLIST 140 Carbamate Production Identification and Listing of Hazardous Waste 60 FR 7824-7859 February 9, 1995 as amended at 60 FR 19165, April 17, 1995 and at 60 FR 25619, May 12, 1995 (RCRA ClusterV, HSWA provisions) Note: 1) On August 8,1995, EPA published an interpretive rule in the Federal Register (see**60~** 

### 41817­ 41818) regarding a change in the Agency's interpretation of the February 9, 1995 rule that lists wastes from carbamate production as hazardous wastes under RCRA. Underthis new interpretation, wastes from the production of non-carbamate intermediates that are used exclusively in the production of carbamates but are not produced at the ultimate site of manufacture of the carbamates will not be subject to the February 9, 1995 rule. These wastes are among those given in the RCRA waste code designations K156 and K157 in that rule. 2) On November 1, 1996, the U.S. Court of Appeals for the District of Columbia Circuit (Dithiocarbamate Task Force v. EPA, CA DC 95-1249, 11/1/96) vacated the following carbamate wastes listed by the February 9, 1995 (60 FR 7824) listing rule: U277, U365, U366, U375, U376, U377, U378, U379, U381, U382, U383, U384, U385,U386,U390,U391,U392,U393, U396, U400, U401,U402, U403,U407,andK160. In addWon, the

ourt vacated K156, K157 and K158 in so far as they encompass 3-iodo-2-propynyl n-butylcarbarnate (IPBC), hich was listed as product waste U375. These vacated wastes are not included on this checklist, because • they are no longer required for authorization for this rule. States may choose to list these wastes as a matter of State law. In this case, the State-listed wastes will be broader in scope or more stringentthan the Federal requirements, depending on whether or not the listed wastes also exhibit a 40 CFR 261, SUbpart C hazardous waste characteristic. 3) States that incorporate the CFR by reference should be careful in their incorporation, particularly those States that have a statutory or regulatory restriction against being more stringent or broader in scopethan the Federal requirements, because the U.S. Court of Appeals' vacatur may not be transferable to State law. See the special guidance for States that incorporate by reference on the Summary for this checklist. FEDERAL REQUIREMENTS FEDERAL RCRA CITATION ANALOGOUS STATE CITATION WAC 173-303· STATE ANALOG IS: EQUIV· LESS MORE BROADER ALENT STRIN- STRIN- IN SCOPE GENT GENT 

### PART 261 -IDENTIFICATION AND LISTING OF HAZARDOUS WASTE SUBPARTA.:.GENERAL DEFINITION OF HAZARDOUS WASTE

CL140.16 - Revised: 2114/97 Printed: 10121198 

### February 9, 1995 - Page 1 of 11 

# •t remove period at 'end of paragraph; add "; or" 261.3(a)(2)(iv)(E) No analog 

# x

# c SPA 

## • RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd)

Error! okma 

## rk not fined.

Error! okma 

## rk not fined. FEDERAL REQUIREMENTS FEDERAL RCRA CITATION ANALOGOUS STATE CITATION STATE ANALOG IS: WAC 173-303· EQUIV­ . LESS MORE BROADER ALENT STRIN- STRIN· IN SCOPE GENT GENT 

## add new paragraph 261.3(a)(2)(iv)(F) No analog X 

## which excludes as \ 

## hazardous waste certain wastewaters from the production of carbamates and carbamoyl oximes (EPA Hazardous Waste No. K157); specific provisions which must be met add new paragraph**261.~(a)(2)(iv)(G)** 

## No analog X 

## which excludes as hazardous waste certain wastewaters derived from the treatment of one or more of the wastes listed in 261.32-­ organic waste from the production of carbamates and carbamoyl oximes (EPA Hazardous Waste No. K156); specific provisions which must be met add new paragraph 261.3(c)(2)(ii)(D) 071(3)(dd) X 

## which excludes as hazardous waste biological treatment sludge from the treatment of one of the wastes listed in 261.32--organic waste from the production of carbamates and carbamoyl oximes


# .C)
CL 140.16 - Revised: 2114/97 Printed: 10/21198 

## February 9, 1995 - Page 2 of 11 

# c

# .. 

# • RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd) SPA

FEDERAL REQUIREMENTS FEDERAL RCRA CITATION ANALOGOUS STATE CITATION STATE ANALOG IS: WAC 173-303· EQUIV- LESS MORE BROADER ALENT STRIN- STRIN- IN SCOPE GENT GENT 

### (EPA Hazardous Waste No. K156), and wastewaters from the production of carbamates and carbamoyl oximes (EPA Hazardous Waste No. K157) SUBPART D--L1STS OF HAZARDOUSWASTES HAZARDOUS WASTE FROM SPECIFIC SOURCES Error! okma rk not 

### fined. 

# • add the following "K" 261.32 9904 

## X wastes in alphanumeric order (by the first column) to the subgroup "Organic chemicals": Industry and EPA hazardous Hazard waste No. Organic Chemicals:
K156 Organicwaste (including heavy ends, still bottoms, lightends, spentsolvents, filtrates, and decantates)from the production ofcarbamates and carbamoyl oximes. K157 Wastewaters (including scrubberwaters, condenserwaters, washwaters, and separation waters) from the production ofcarbamates and carbamoyl oximes. K158 Bag house dusts and filter/separation solids from the production ofcarbamates and carbamoyl oximes. K159 Organics from the treatmentofthiocarbamate wastes. K161 Purification solids (including filtration, evaporation, and centrifugation solids), bag house dust and floorsweepings from the production ofdithiocarbamate acids and theirsalts. (This listing does not include K125 orK126.)· 

# • CL140.16 - Revised: 2/14/97 Printed: 10/21198 

### February 9, 1995 - Page 3 of 11

# c SPA 

# . RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd)

DISCARDED COMMERCIAL CHEMICAL PRODUCTS, OFF-SPECIFICATION SPECIES, CONTAINER RESIDUES AND SPILL RESIDUES THEREOF 

### , 2 3 

### add the following 

## lip" 261.33(e) 9903 

### X wastes in alphabetic order (by the third column) Chemical Hazardous abstracts waste No. No. Substance P203 1646-88-4 Aldicarb sulfone.
P127 P188**156~6-2** 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate. 57-64-7 Benzoic acid, 2-hydroxy-, compd. with (3aS-cis}-l,2,3,3a,8,8a-hexahydro-l,3a,8-lrimethylpyrrolo[2,3-b]indol-5-yl methylcarbamate ester (1:1). P189 P191 P192 P190 P127 55285-14-8 644.Q4-4 119-38-0 1129-41-5 1563.Q6-2 Carbamicacid, [(dibutylamino)-thio)methyl-, 2,3-dihydro-2,2-<limethyl- 7 -benzofuranyl ester. Carbamicacid, dimethyl-, l-[(dimethyl-amino)carbonyl]- 5-methyl-lH-pyrazol-3-yl ester. Carbamicacid, dimethyl-, 3-methyl-l- (l-methylethyl)-lH- pyrazol-5-yl ester. Carbamicacid, methyl-, 3-methylphenyl ester. Carbofuran. 

# o

P189 5285-14-8 Carbosulfan. P202 64-00.Q m-Cumenyl methylcarbamate.
P191 644.Q4-4 Dimetilan.
P185 26419-73-8 l,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, 

### 0- [(methylamino)- carbonyl)oxime. P194 23135-22-0 Ethanimidothioc acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl)oxy]-2-oxo-, methyl ester. P198 23422-53-9 Forrnetanate hydrochloride. P197 17702-57-7 Forrnparanate.

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### February 9, 1995 - Page 4 of 11

### SPA 

# • RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd)

P192 P202 119-38-0 64-00-6 Isolan. 3-lsopropylphenyl N-methylcarbamate.
P196 P196 15339-36-3 15339-36-3 Manganese, bis(dimethylcarbamodithioato-S,S')-, Manganese dimethyldithiocarbamate. P198 P197 P199 23422-53-9 17702-57-7 2032-65-7 Methanimidamide, N.N-dimethyl-N'-[3-[((methylamino)-carbonyl]oxy]phenyl]-, monohydrochloride. Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-([(methylamino)carbonyl]oxy]phenyl]- Methiocarb.
P190 1129-41-5 Metolcarb. P128 315-18-4 Mexacarbate. 

# • P194 P128 P199 P202 23135-22-0 315-18-4 2032-65-7

64-00-6 Oxamyl. Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester).**Ph~nol,** (3,5-dimethyl-4-(methylthio)-, methylcarbamate Phenol, 3-(1-methylethyl)-, methyl carbamate.
P201 2631-37-0 Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate.
P204 P188 57-47-6 57-64-7 Physostigmine. Physostigminesalicylate.
P201 P203 2631-37-0**164~8-4** Promecarb Propanal, 2-methyl-2-(methyl-sulfonyl)-, Q-[(methylamino)carbonyl] oxime.
P204 57-47-6**Pyrrolo[2,3-b]indol-~I,** 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, methylcarbamate (ester), (3aS-cis)-. 

# • P185 26419-73-8 Tirpate
.


### February 9, 1995- Page 5 of 11 CL140.16- Revised: 2114/97 Printed: 10121/98 

# (

### RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste 

## (cont'd) SPA 

## • 

# c

P205 137-30-4 Zinc. bis(dimethylcarbamodithioato-S.S·)-,
P205 137-30-4 Ziram. 

### Error! okma rk not fined. add the following 261.33(f) 9903 

## X "U" wastes in alphabetic order (by the third column) Hazardous Chemical waste No. abstracts No. Substance U394 30558-43-1

U280 101-27-9 U278 22781-23-3 U364**22961-82~** U271 17804-35-2 U278 22781-23-3 U364**22961-82~** U367 1563-38-8 U372 10605-21-7 • U271 17804-35-2

U280 101-27-9 U373 122-42-9 U409 23564-05-8
U389 2303-17-5 U387 52888-80-9 U279 63-25-2 U372 10605-21-7 U367 1563-38-8 U395 5952-26-1 A2213.

Barban. Bendiocarb. Bendiocarb phenol. Benomyl. 

# o 1.3-Benzodioxol-4-oI. 2.2-dimethyl-. methyl carbamate. 1.3-Benzodioxol-4-oI. 2.2-dimethyl-. 7 -Benzofuranol. 2,3-dihydro-2,2-dimethyl- Carbamicacid. 1H-benzimidazol-2-yl. methyl ester. Carbamicacid. [1-[(butylamino)carbonyl)-1H-benzimidazol-2-yl)-,

methyl ester Carbamicacid. (3-chlorophenyl)-. 4-chloro-2-butynyl ester. Carbamicacid. phenyl-. 1-methylethyl ester. Carbamicacid. [1.2-phenylenebis (iminocarbonothioyl)]bis-. dimethyl ester. Carbamothioic acid, bis(l-methylethyl)-.

S-(2.3.3-trichloro-2-propenyl) ester. Carbamothioicacid, dipropyl-, S-(phenylmethyl) ester. Carbaryl. Carbendazim. Carbofuran phenol. Diethylene glycol. dicarbamate. 

# o CL140.16 • Revised:2114/97 Printed: 10121198 

### February 9, 1995- Page 6 of 11

### SPA 

# • RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd)

U404 121-44-8
U410 59669-26-0 U394 30558-43-1
U395 5952-26-1 Ethanamine, N,N-diethylEthanimidothioicacid, N,N'- [thiobis[(methylimino)carbonyloxyJ]bis-, dimethyl ester Ethanimidothioicacid, 2-{dimethylamino)-N-hydroxy-2-oxo-, methyl ester. Ethanol, 2,2'-oxybis-, dicarbamate.

U279 63-25-2 1-Naphthalenol, methylcarbamate.

U411 114-26-1 Phenol, 2-{1-methylethoxy}-, methylcarbamate. 

# • U373 U411 U410 122-42-9 114-26-1 59669-26-0 Propham
. Propoxur. Thiodicarb.

U409 23564-05-8 Thiophanate-methyl.
U389 2303-17-5 Triallate.
U404 121-44-8 Triethylamine.



## APPENDIX VII TO PART 261 Error!
.

## Add in alphanumeric 261, Appendix VII 082(4) X okma 

## order (by first rk not 

## column) BASIS FOR LISTING HAZARDOUS WASTE 

# • CL140.16 - Revised: 2114/97 Printed: 10/21/98 

## February 9, 1995 - Page 7 of 11

### RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd) SPA 

## , 

# o fined.

_________........ r--r----l .....;.

....;L-l--JL...­
_ EPA hazardous Waste No. Hazardous constituents forwhich listed K156 Benomyl, carbaryl, carbendazim, carbofuran, carbosulfan, formaldehyde, methylene chloride, triethylamine. K157 Carbon tetrachloride, formaldehyde, methyl chloride, methylene chloride, pyridine, triethylamine. K158 Benomyl, carbendazim, carbofuran, carbosulfan, chloroform, methylene chloride. K159 Benzene, butylate, eptc, molinate, pebulate, vemolate. K161 Antimony, arsenic, metam-sodium, ziram. 

### APPENDIXVIII TO PART 261 HAZARDOUS CONSTITUENTS 

## Error! okma rk not fined. Add in alphabetical order: 261, Appendix VIII 9905 X

Common Name Chemical abstracts name Chemical Hazardous abstracts No. waste No. A2213 Ethanimidothioicacid, 2-(dimethylamino) -N-hydroxy-2-oxo-, methyl ester 30558-43-1 U394 

# 0
Aldicarb sulfone Propanal, 2-methyl-2- (methylsulfonyl) -,Q-[(methylamino) carbonyl) oxime 1646-88-4 P203
Barban Carbamicacid, (3-chlorophenyl) -,4-chloro-2-butynyl ester 101-27-9 U280
Bendiocarb Bendiocarb phenol Benomyl 1,3-Benzodioxol-4-0l, 2,2-dimethyl-, methyl carbamate 22781-23-3 1,3-Benzodioxol-4-0l, 2,2-dimethyl-, 22961-82-6 Carbamicacid, [1- [(butylamino) carbonyl)­ 17804-35-2U271

1H-benzimidazol-2-yl]-, methyl ester U278 U364

Carbaryl Carbendazim Carbofuran Carbofuran phenol 1-Naphthalenol, methylcarbamate Carbamicacid, 1H-benzimidazol-2-yl, methyl ester 10605-21-7 7 -Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate 7-Benzofuranol,2,3-dihydro-2,2-dimethyl­ 1563-38-8 U367 63-25-2 U372 1563-66-2 U279 P127

Carbosulfan Carbamic acid, [(dibutylamino) thio] methyl-, 55285-14-8P189 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester


### February 9, 1995 - Page 8 of 11 CL 140.16 - Revised: 2/14/97 Printed: 10/21198

# ... SPA 

# • RCRA REVISION CHECKLIST 140: Carbamate Production Identification and Listing of Hazardous Waste (cont'd)

m-Cumenyl Phenol, 3-(methylethyl)-. methyl carbamate**64~0-6** P202

methylcarbamate
Diethyleneglycol, Ethanol, 2,2'-{)xybis-, dicarbamate 5952-26-1 U395 Dicarbamate DimeUlan Carbamicacid, dimethyl-, 1-[(dimethylamino) 644-64-4 P191 carbonyl)-5-methyl-1H-pyrazol-3-yl ester
Formetanate hydrochloride Methanimidamide, N,N-dimethyl-N'-[3-[[(methylamino) 23422-53-9 P198 carbonylloxyjphenyl)-, monohydrochloride 

# • Formparanate Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino) 17702-57-7 P197 carbonyljoxyjphenyl)-.
Isolan Carbamic acid, dimethyl-, 3-methyl-1-(1-methylethyl)-1**H-119-38~** P192 pyrazol-5-yl ester Manganese Manganese, bis(dimethylcarbamodithioato-S,S')-. 15339-36-3 P196 Dimethyldithiocarbamate
Methiocarb Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate 2032-65-7 P199
Metolcarb Carbamicacid, methyl-, 3-methylphenyl ester1129-41-5 P190
Mexacarbate Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester) 315-18-4 P128 Oxamyl Ethanimidothiocacid, 2-(dimethylamino)-N-[[(methylamino)**23135-22~** P194 carbonyljoxyj-2-{)xo-, methyl ester 

# • CL 140.16 - Revised: 2/14/97 Printed: 10/21198 

### February 9, 1995 - Page 9 of 11; 

### SPA 

## , RCRA REVISION CHECKLIST 140: Carbamate Production Identification and
Physostigmine Physostigmine salicylate 

### Listing of Hazardous Waste (cont'd) Pyrrolo[2,3-b)indol-5-o1, 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-,

methylcarbamate (ester), (3aS-cis)- Benzoicacid, 2-hydroxy-, compd. with (3aS-cis) 57-64-7 -1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo [2,3-b)indol-5-yl methytcarbamate ester (1:1). 57-47-8 P188 P204 

# c

Promecarb Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate 2631-37-0 P201 Propham Propoxur Carbamicacid, phenyl-, 1-methylethyl ester 122-42-9 Phenol, 2-(1-methylethoxy)-, methylcarbamate U373 114-26-1 U411
Prosulfocarb Carbamothioicacid, dipropyl-, S-(phenylmethyl) ester 52888-80-9 U387 Thiodicarb Thiophanate-methyl Ethanimidothioicacid, N,N'-[thiobis [(methylimino) 59669-26-0 carbonyloxy)J bis-, dimethyl ester. Carbamicacid, [1,2-phyenylenebis (iminocarbonothioyl)) bis-, dimethyl ester U410 23564-05-8 U409 Tirpate Triallate 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, Q..[(methylamino) carbonyl) oxime. Carbamothioic acid, bis(1-methylethyl)-,

S-(2,3,3-trichloro-2-propenyl) ester 2303-17-5 U389 26419-73-8 P185 

# o

Triethylamine Ethanamine, N,N-diethyl­ 121-44-8 U404
Ziram Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)­ 137-30-4 P205



# o CL140.16- Revised:2/14/97 Printed: 10/21198 

### February 9, 1995 - Page 10 of 11