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Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT C: FLASHING EMISSIONS CALCULATIONS 

• E&P Tanks Emission Summary

• E&P Tanks Linear Relationship (Emission Factor)
Mandaree Field 1000 BOPD wt%

******************************************************************************************

* Project Setup Information *

******************************************************************************************

Project File : Y:\Projects\Williams Exploration & Production WEP\WEP211324 Ft. Berthold

IR Well Work\E&P Tanks\Mandaree Field 1000 BOPD.ept

Flowsheet Selection : Oil Tank with Separator

Calculation Method : RVP Distillation

Control Efficiency : 100.0%

Known Separator Stream : Low Pressure Oil

Entering Air Composition : No

Filed Name : Mandaree

Well Name : Cross 2-13H and Patricia Charging 4-15H Averages

Permit Number : Dakota-3 E&P Company, LLC

Date : 9/24/2010

******************************************************************************************

* Data Input *

******************************************************************************************

Separator Pressure : 51.00[psig]

Separator Temperature : 82.50[F]

Ambient Pressure : 14.70[psia]

Ambient Temperature : 70.00[F]

C10+ SG : 0.8000

C10+ MW : 235.14

-- Low Pressure Oil ----------------------------------------------------------------------

 No. Component wt %

 1 H2S 0.0014

 2 O2 0.0000

 3 CO2 0.0042

 4 N2 0.0015

 5 C1 0.0320

 6 C2 0.3654

 7 C3 1.2089

 8 i-C4 0.3443

 9 n-C4 1.5191

 10 i-C5 0.6508

 11 n-C5 1.2185

 12 C6 1.3933

 13 C7 6.7524

 14 C8 15.9338

 15 C9 14.3170

 16 C10+ 53.7971

 17 Benzene 0.0479

 18 Toluene 0.0997

 19 E-Benzene 0.0600

 20 Xylenes 0.3998

 21 n-C6 1.4864

 22 224Trimethylp 0.3663

-- Sales Oil -----------------------------------------------------------------------------

Production Rate : 1000[bbl/day]

Days of Annual Operation : 365 [days/year]

API Gravity : 41.85

Reid Vapor Pressure : 5.90[psia]

******************************************************************************************

* Calculation Results *

******************************************************************************************

-- Emission Summary ----------------------------------------------------------------------

Item Uncontrolled Uncontrolled 

 [ton/yr] [lb/hr] 

Page 1---------------------------------------------------------------- E&P TANK 

Total HAPs 8.550 1.952 

Total HC 812.744 185.558 

VOCs, C2+ 796.480 181.845 

VOCs, C3+ 612.595 139.862 

Page 1
Mandaree Field 1000 BOPD wt%

 

Uncontrolled Recovery Info. 

 Vapor 40.2300 [MSCFD] 

 HC Vapor 40.0300 [MSCFD] 

 GOR 40.23 [SCF/bbl] 

-- Emission Composition ------------------------------------------------------------------

No Component Uncontrolled Uncontrolled 

 [ton/yr] [lb/hr] 

1 H2S 0.689 0.157 

2 O2 0.000 0.000 

3 CO2 2.160 0.493 

4 N2 0.786 0.179 

5 C1 16.264 3.713 

6 C2 183.886 41.983 

7 C3 375.375 85.702 

8 i-C4 37.149 8.482 

9 n-C4 112.787 25.750 

10 i-C5 17.863 4.078 

11 n-C5 24.862 5.676 

12 C6 8.648 1.974 

13 C7 13.803 3.151 

14 C8 10.281 2.347 

15 C9 3.270 0.747 

16 C10+ 0.004 0.001 

17 Benzene 0.234 0.053 

18 Toluene 0.136 0.031 

19 E-Benzene 0.027 0.006 

20 Xylenes 0.156 0.036 

21 n-C6 7.394 1.688 

22 224Trimethylp 0.604 0.138 

 Total 816.378 186.388 

-- Stream Data ---------------------------------------------------------------------------

No. Component MW LP Oil Flash Oil Sale Oil Flash Gas W&S Gas Total Emissions

 wt % wt % wt % wt % wt % wt % 

1 H2S 34.80 0.0014 0.0010 0.0000 0.0873 0.0856 0.0861 

2 O2 32.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

3 CO2 44.01 0.0042 0.0020 0.0000 0.4818 0.1765 0.2642 

4 N2 28.01 0.0015 0.0001 0.0000 0.3044 0.0123 0.0962 

5 C1 16.04 0.0320 0.0079 0.0000 5.2226 0.6866 1.9891 

6 C2 30.07 0.3654 0.2356 0.0039 28.3624 20.1288 22.4930 

7 C3 44.10 1.2089 1.0468 0.4786 36.1613 49.8497 45.9192 

8 i-C4 58.12 0.3443 0.3257 0.2757 4.3503 4.6218 4.5438 

9 n-C4 58.12 1.5191 1.4623 1.3185 13.7647 13.8076 13.7953 

10 i-C5 72.15 0.6508 0.6432 0.6257 2.2771 2.1480 2.1850 

11 n-C5 72.15 1.2185 1.2094 1.1888 3.1795 2.9854 3.0410 

12 C6 86.16 1.3933 1.3945 1.3984 1.1369 1.0640 1.0850 

13 C7 100.20 6.7524 6.7753 6.8342 1.8207 1.7133 1.7442 

14 C8 114.23 15.9338 16.0015 16.1730 1.3430 1.2744 1.2941 

15 C9 128.28 14.3170 14.3815 14.5440 0.4133 0.4189 0.4174 

16 C10+ 235.14 53.7971 54.0465 54.6758 0.0006 0.0005 0.0006 

17 Benzene 78.11 0.0479 0.0480 0.0483 0.0298 0.0281 0.0285 

18 Toluene 92.13 0.0997 0.1001 0.1011 0.0174 0.0165 0.0166 

19 E-Benzene 106.17 0.0600 0.0603 0.0610 0.0035 0.0032 0.0033 

20 Xylenes 106.17 0.3998 0.4016 0.4059 0.0196 0.0187 0.0191 

21 n-C6 86.18 1.4864 1.4889 1.4959 0.9466 0.8874 0.9045 

22 224Trimethylp 114.24 0.3663 0.3677 0.3711 0.0772 0.0726 0.0739 

 

 MW 143.08 144.90 148.98 39.02 43.55 42.14 

 Stream Mole Ratio 1.0000 0.9829 0.9448 0.0171 0.0381 0.0552 

 Heating Value [BTU/SCF] 2225.52 2481.29 2401.97 

 Gas Gravity [Gas/Air] 1.35 1.50 1.45 

 Bubble Pt. @ 100F [psia] 32.28 20.39 7.37 

Page 2---------------------------------------------------------------- E&P TANK 

 RVP @ 100F [psia] 15.35 12.04 6.01 

 Spec. Gravity @ 100F 0.677 0.678 0.680 

Page 2
Emission estimates are based on using the E&P TANK V2.0 Model, RVP Distillation Column

As shown below, the E&P Tanks summary output has a linear relationship with the production rate

of the oil with the given inputs listed below.

Inputs:

Low pressure oil from average of 2 representative Mandaree Field Dakota-3 Wells

Separator: 51 psig, 83 degF

Flash Valve: 13.7 psia, 50 degF

Sales Oil: API Gravity 41.9, Reid Vapor Pressure 5.90 psia, 365 days/year

Outputs:

Oil Production Rates (bbl/day) (P) 0 50 100 300 1000

Emission (tons/yr)

Total HC 0 40.6372 81.2744 243.8232 812.744

VOCs, C3+ 0 30.62975 61.2595 183.7785 612.595

Total HAPs 0 0.4275 0.855 2.565 8.55

VOC (C3+) Emission Factor: 0.6126 tpy/BOPD

HAP Emission Factor: 0.00855 tpy/BOPD

Oil Storage Tank Flashing Emissions Calculation Methodology

E&P Tanks Linear Relation between Production (bbls/day) and Emissions (tons/yr)

y = 0.00855x

R2 = 1.00000

y = 0.6126x

R2 = 1

0

100

200

300

400

500

600

700

0 500 1000 1500

tons/year

bbl/day

Tank Emissions by Production Rate

Total HAPs

VOCs, C3+

Linear (Total HAPs)

Linear (VOCs, C3+)
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT D: REPRESENTATIVE LOW PRESSURE OIL 

ANALYTICAL DATA 
Company .................... ZENERGY

Lab Number ................ CRͲ10330 Study Number.......... CRͲ2

Date Sampled .............. 7Ͳ15Ͳ2010 Date Tested............. 7Ͳ23Ͳ2010

S l Id tifi ti CROSS 2 13 H CRUDE OIL

 EXTENDED HYDROCARBON (GLYCALC) LIQUID STUDY

Sample Identification .................... CROSS 2-13 H CRUDE OIL

Sample Location .......... MONTANA.

Sample Pressure ......... 22 PSIG Sample Temperature.... 95 F

Type Sample ............... SPOT County...................... DUNN

Test method ................ GPAͲ2286 Sampling Method........ YZ PISTON

 Components Mole % Weight % Liq. Vol. %

Hydrogen Sulfide .......... 0.003 0.001 0.001

Oxygen ...................... 0.000 0.000 0.000

Carbon Dioxide ............ 0.013 0.004 0.004

Nitrogen ..................... 0.007 0.001 0.001

Methane ..................... 0 180 . 0 021 . 0 050 .

Ethane ....................... 1.602 0.342 0.709

Propane ..................... 4.036 1.264 1.839

isoͲButane .................. 0.855 0.353 0.463

nͲButane .................... 3.974 1.640 2.072

isoͲPentane ................ 1.378 0.706 0.833

nͲPentane ................... 2.569 1.316 1.540

Hexanes ..................... 2 510. 1 536. 1 707.

Heptanes .................... 10.694 7.610 8.159

Octanes ..................... 19.351 15.699 16.394

Nonanes ..................... 17.072 15.551 15.886

Decanes+ ................... 31.435 51.099 47.376

Benzene...................... 0.093 0.052 0.043

Toluene....................... 0.166 0.109 0.092

Ethylbenzene............... 0.104 0.078 0.066

Xylenes....................... 0.618 0.466 0.397

nͲHexane .................... 2.798 1.712 1.903

2,2,4ͲTrimethylpentane... 0.542 0.440 0.466

TOTALS ..................... 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

2-Methylpentane 1.486 0.910 1.011

3-Methylpentane 3-Methylpentane 1 024 . 0 627 . 0 696 .

n-Hexane 2.798 1.712 1.903

2,2,4-Trimethylpentane 0.542 0.440 0.466

Benzene 0.093 0.052 0.043

Toluene 0.166 0.109 0.092

Ethylbenzene 0.104 0.078 0.066

m-Xylene 0.066 0.050 0.042

p-Xylene 0.436 0.329 0.280

o-Xylene 0.116 0.087 0.074

API GRAVITY AT 60/60 F, calculated........................................................................ 60.3

SPECIFIC GRAVITY AT 60/60 F, calculated.............................................................. 0.7378

RELATIVE SPECIFIC GRAVITY OF DECANES+ (C10+) FRACTION ............................... 0.7958

AVERAGE MOLECULAR WEIGHT .......................................................................... 140.803

AVERAGE MOLECULAR WEIGHT OF DECANES+ (C10+) FRACTION .......................... 228.881

TRUE VAPOR PRESSURE AT 100 F PSIA calculated TRUE VAPOR PRESSURE AT 100 F, PSIA, calculated................................................ 33 400 .

AVERAGE BOILING POINT, F, ................................................................................ 299.063

CUBIC FEET OF GAS / GALLON OF LIQUID, as Ideal Gas .......................................... 19.106

BTU / GALLON OF LIQUID AT 14.73 PSIA, calculated ................................................. 122456.887

LBS / GALLON OF LIQUID, calculated ...................................................................... 6.152

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
 EXTENDED HYDROCARBON LIQUID STUDIES

 CERTIFICATE OF ANALYSIS

Company................ PRECISION ANALYSIS

L bN ba umer............. CR-10330 CR 10330 Study Number............ St d N b CR-2B 

Date Sampled............. 7-15-2010 Date Tested.............. 7-22-2010

Sample Identification................ ZENERGY - CROSS 2-13 H CRUDE OIL

Sample Location......... MONTANA.

Sample Pressure.......... N/A Sample Temperature.... N/A

Flowrate................... N/A County..................... DUNN

Test Method.............. VARIOUS Sample Container........

1-QUART 

BOTTLE

TEST PERFORMED RESULTS

API GRAVITY AT 60/60 F (ASTM D-287), observed...................... / ( ), 42.5

SPECIFIC GRAVITY AT 60/60 F (ASTM D-1657), calculated.......... 0.8132

REID VAPOR PRESSURE (ASTM D-323), PSIG AT 100 F.............. 5.2 PSIG

TOTAL SULFUR CONTENT (ASTM D-5453), PPMW.................. PPMW 658.98

TRUE VAPOR PRESSURE (ASTM D-2889), PSIA AT 100 F ........... N/A

BASIC SEDIMENT AND WATER CONTENT, % BY VOLUME.... N/A

COPPER STRIP CORROSION (ASTM D-130), 1 HOUR AT 100 F........... N/A

FREE WATER, observed......................................................... N/A

NOTATION : ALL TESTING PROVIDED ABOVE WAS PERFORMED IN ACCORDANCE TO METHODOLOGY

 OUTLINED BY THE AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM).
5HSRUW5HSRUW(GLWRU

Chromatogram Cross 2-13H C:\GCsolution\DRO\DRO Data\08-2010\08-01-2010\Cross 2-13H.gcd - Channel 1

min

Intensity 0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0

0 50000 100000 150000 200000 250000

 1.055 / 1.137 / 1.306 / 1.405 / 1.552 / 1.668 / 

 1.729 / 1.901 / 1.979 / 2.039 / 2.109 / 2.280 / 2.417 / 2.565 / 2.667 / 2.854 / 2.949 / 3.034 / 3.092 / 3.213 / 3.342 / 3.420 / 3.539 / 3.632 / 3.773 / 3.862 / 3.965 / 4.069 / 4.148 / 4.335 / 4.448 / 4.508 / 4.583 / 4.692 / 4.751 / 4.901 / 5.021 / 5.164 / 5.365 / 5.508 / 5.608 / Decane (C10) 5.816 / 5.947 / 6.069 / 6.188 / 6.286 / 6.393 / 6.509 / 6.569 / 6.657 / 6.714 / 6.777 / 6.896 / 7.083 / 7.220 / 7.323 / 7.381 / 7.455 / 7.559 / 7.632 / 7.703 / 7.769 / 7.836 / 7.907 / 7.967 / 8.056 / 8.184 / 8.268 / 8.329 / 8.452 / 8.540 / 8.633 / 8.744 / 8.808 / 8.998 / 9.128 / 9.270 / 9.380 / 9.467 / 9.526 / 9.596 / 9.724 / 9.862 / 9.939 / 10.055 / 10.150 / 10.257 / 10.332 / 10.427 / 10.487 / 10.568 / 10.638 / 10.766 / 10.828 / 10.911 / 11.051 / 11.216 / 11.469 / 11.613 / 11.706 / 11.785 / 12.031 / 12.128 / 12.182 / 12.302 / 12.409 / 12.463 / 12.536 / 12.607 / 12.700 / 12.822 / 13.004 / 13.088 / 13.203 / 13.305 / 13.372 / 13.447 / 13.582 / 13.674 / 13.803 / 13.929 / 14.089 / 14.146 / 14.316 / 14.427 / 14.515 / 14.592 / 14.691 / 14.773 / 14.896 / 15.041 / 15.129 / 15.249 / 15.300 / 15.369 / 15.430 / 15.566 / 15.620 / 15.691 / 15.787 / 15.947 / o-terphenyl 16.113 / 16.187 / 16.339 / 16.456 / 16.570 / 16.661 / 16.813 / 16.894 / 16.979 / 17.143 / 17.306 / 17.449 / 17.519 / 17.642 / 17.787 / 17.954 / 18.052 / 18.153 / 18.222 / 18.292 / 18.434 / 18.549 / 18.723 / 18.887 / 18.991 / 19.197 / 19.331 / 19.474 / 19.663 / 19.724 / 19.785 / 19.850 / 19.927 / 19.995 / 20.077 / 20.222 / 20.182 / 20.345 / 20.443 / 20.634 / 20.789 / 20.871 / 20.945 / 21.059 / 21.134 / 21.205 / 21.310 / 21.542 / 21.695 / 21.795 / 21.855 / 21.905 / 21.966 / 22.073 / 22.181 / 22.367 / 22.425 / 22.599 / Octacosane (C28) 22.737 / 22.808 / 22.879 / 23.003 / 23.058 / 23.117 / 23.217 / 23.351 / 23.418 / 

 23.678 / 23.816 / 23.905 / 24.027 / 24.086 / 24.202 / 24.264 / 24.400 / 24.521 / 24.587 / 24.651 / 24.765 / 24.809 / 24.874 / 24.981 / 25.069 / 25.142 / 25.201 / 25.273 / 25.334 / 25.401 / 25.462 / 25.568 / 25.705 / 25.765 / 25.966 / 26.056 / 26.229 / 26.397 / 26.487 / 26.575 / 26.665 / 26.758 / 26.958 / 27.073 / 27.191 / 27.327 / 27.441 / 27.561 / 27.668 / 27.798 / 27.952 / 28.073 / 28.297 / 28.467 / 28.689 / 28.833 / 28.995 / 29.193 / 29.393 / 29.601 / 
Company .................... ZENERGY

Lab Number ................ CRͲ10330 Study Number.......... CRͲ3

Date Sampled .............. 7Ͳ15Ͳ2010 Date Tested............. 7Ͳ23Ͳ2010

S l Id tifi ti PATRICIA CHARGING 4 15 H CRUDE OIL

 EXTENDED HYDROCARBON (GLYCALC) LIQUID STUDY

Sample Identification .................... PATRICIA CHARGING 4-15 H CRUDE OIL

Sample Location .......... MONTANA.

Sample Pressure ......... 80 PSIG Sample Temperature.... 70 F

Type Sample ............... SPOT County...................... DUNN

Test method ................ GPAͲ2286 Sampling Method........ YZ PISTON

 Components Mole % Weight % Liq. Vol. %

Hydrogen Sulfide .......... 0.008 0.002 0.002

Oxygen ...................... 0.000 0.000 0.000

Carbon Dioxide ............ 0.014 0.004 0.004

Nitrogen ..................... 0.008 0.001 0.001

Methane ..................... 0 398 . 0 043 . 0 107 .

Ethane ....................... 1.921 0.387 0.811

Propane ..................... 3.914 1.155 1.702

isoͲButane .................. 0.862 0.335 0.445

nͲButane .................... 3.606 1.403 1.795

isoͲPentane ................ 1.238 0.598 0.715

nͲPentane ................... 2.329 1.125 1.333

Hexanes ..................... 2 180. 1 257. 1 415.

Heptanes .................... 8.849 5.934 6.445

Octanes ..................... 21.103 16.133 17.068

Nonanes ..................... 15.296 13.130 13.589

Decanes+ ................... 34.917 56.412 52.378

Benzene...................... 0.085 0.044 0.038

Toluene....................... 0.148 0.091 0.078

Ethylbenzene............... 0.060 0.043 0.037

Xylenes....................... 0.473 0.336 0.290

nͲHexane .................... 2.204 1.271 1.431

2,2,4ͲTrimethylpentane... 0.387 0.296 0.317

TOTALS ..................... 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

2-Methylpentane 1.272 0.734 0.826

3-Methylpentane 3-Methylpentane 0 908 . 0 524 . 0 590 .

n-Hexane 2.204 1.271 1.431

2,2,4-Trimethylpentane 0.387 0.296 0.317

Benzene 0.085 0.044 0.038

Toluene 0.148 0.091 0.078

Ethylbenzene 0.060 0.043 0.037

m-Xylene 0.058 0.041 0.036

p-Xylene 0.298 0.212 0.183

o-Xylene 0.117 0.083 0.072

API GRAVITY AT 60/60 F, calculated........................................................................ 57.8

SPECIFIC GRAVITY AT 60/60 F, calculated.............................................................. 0.7475

RELATIVE SPECIFIC GRAVITY OF DECANES+ (C10+) FRACTION ............................... 0.8050

AVERAGE MOLECULAR WEIGHT .......................................................................... 149.417

AVERAGE MOLECULAR WEIGHT OF DECANES+ (C10+) FRACTION .......................... 241.399

TRUE VAPOR PRESSURE AT 100 F PSIA calculated TRUE VAPOR PRESSURE AT 100 F, PSIA, calculated................................................ 46 319 .

AVERAGE BOILING POINT, F, ................................................................................ 314.836

CUBIC FEET OF GAS / GALLON OF LIQUID, as Ideal Gas .......................................... 18.857

BTU / GALLON OF LIQUID AT 14.73 PSIA, calculated ................................................. 122700.693

LBS / GALLON OF LIQUID, calculated ...................................................................... 6.232

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
 EXTENDED HYDROCARBON LIQUID STUDIES

 CERTIFICATE OF ANALYSIS

Company................ ZENERGY

L bN ba umer............. CR-10330 CR 10330 Study Number............ St d N b CR-3B 

Date Sampled............. 7-15-2010 Date Tested.............. 7-22-2010

Sample Identification................ PATRICIA CHARGING 4-15 H CRUDE OIL

Sample Location......... MONTANA.

Sample Pressure.......... N/A Sample Temperature.... N/A

Flowrate................... N/A County..................... DUNN

Test Method.............. VARIOUS Sample Container........

1-QUART 

BOTTLE

TEST PERFORMED RESULTS

API GRAVITY AT 60/60 F (ASTM D-287), observed...................... / ( ), 41.2

SPECIFIC GRAVITY AT 60/60 F (ASTM D-1657), calculated.......... 0.8193

REID VAPOR PRESSURE (ASTM D-323), PSIG AT 100 F.............. 6.6 PSIG

TOTAL SULFUR CONTENT (ASTM D-5453), PPMW.................. PPMW 940.25

TRUE VAPOR PRESSURE (ASTM D-2889), PSIA AT 100 F ........... N/A

BASIC SEDIMENT AND WATER CONTENT, % BY VOLUME.... N/A

COPPER STRIP CORROSION (ASTM D-130), 1 HOUR AT 100 F........... N/A

FREE WATER, observed......................................................... N/A

NOTATION : ALL TESTING PROVIDED ABOVE WAS PERFORMED IN ACCORDANCE TO METHODOLOGY

 OUTLINED BY THE AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM).
5HSRUW5HSRUW(GLWRU

Chromatogram PC 4-15 1-100 C:\GCsolution\DRO\DRO Data\08-2010\08-01-2010\PC 4-15 1-100.gcd - Channel 1

min

Intensity 0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0

0 50000 100000 150000 200000 250000

 1.054 / 1.137 / 1.407 / 1.593 / 1.670 / 

 1.730 / 1.902 / 2.040 / 2.109 / 2.280 / 2.363 / 2.418 / 2.566 / 2.667 / 2.855 / 2.950 / 3.035 / 3.136 / 3.214 / 3.343 / 3.421 / 3.540 / 3.635 / 3.773 / 3.863 / 3.967 / 4.070 / 4.149 / 4.335 / 4.509 / 4.584 / 4.694 / 4.750 / 4.901 / 5.022 / 5.166 / 5.366 / 5.510 / 5.610 / Decane (C10) 5.818 / 5.949 / 6.070 / 6.190 / 6.288 / 6.397 / 6.512 / 6.564 / 6.660 / 6.714 / 6.780 / 6.901 / 7.016 / 7.084 / 7.156 / 7.221 / 7.326 / 7.384 / 7.457 / 7.561 / 7.634 / 7.747 / 7.836 / 7.908 / 7.969 / 8.059 / 8.184 / 8.270 / 8.331 / 8.453 / 8.542 / 8.634 / 8.745 / 8.812 / 9.000 / 9.129 / 9.271 / 9.381 / 9.469 / 9.529 / 9.597 / 9.725 / 9.863 / 9.942 / 10.057 / 10.149 / 10.260 / 10.334 / 10.429 / 10.488 / 10.570 / 10.640 / 10.768 / 10.830 / 10.913 / 11.059 / 11.220 / 11.472 / 11.615 / 11.787 / 12.031 / 12.130 / 12.184 / 12.318 / 12.414 / 12.470 / 12.541 / 12.606 / 12.706 / 12.826 / 13.005 / 13.088 / 13.306 / 13.376 / 13.450 / 13.583 / 13.673 / 13.728 / 13.934 / 14.091 / 14.148 / 14.319 / 14.445 / 14.516 / 14.595 / 14.692 / 14.779 / 14.896 / 15.042 / 15.130 / 15.246 / 15.373 / 15.431 / 15.568 / 15.658 / 15.621 / 15.775 / 15.883 / 15.950 / o-terphenyl 16.056 / 16.118 / 16.191 / 16.341 / 16.460 / 16.573 / 16.667 / 16.814 / 16.894 / 16.987 / 17.144 / 17.313 / 17.452 / 17.528 / 17.644 / 17.796 / 17.963 / 18.087 / 18.144 / 18.226 / 18.292 / 18.436 / 18.558 / 18.723 / 18.924 / 18.986 / 19.083 / 19.198 / 19.272 / 19.329 / 19.473 / 19.627 / 19.786 / 19.849 / 19.928 / 20.077 / 20.180 / 20.244 / 20.372 / 20.431 / 20.488 / 20.634 / 20.798 / 20.870 / 20.952 / 21.027 / 21.131 / 21.218 / 21.313 / 21.422 / 21.538 / 21.594 / 21.705 / 21.795 / 21.845 / 21.966 / 22.068 / 22.188 / 22.368 / 22.426 / 22.604 / Octacosane (C28) 22.717 / 22.799 / 22.997 / 23.054 / 23.217 / 23.347 / 23.408 / 23.605 / 23.663 / 23.817 / 24.040 / 24.163 / 24.292 / 24.402 / 24.498 / 24.572 / 24.634 / 24.695 / 24.758 / 24.836 / 24.977 / 25.088 / 25.178 / 

 25.438 / 25.504 / 25.571 / 25.721 / 25.797 / 26.044 / 26.117 / 26.208 / 26.366 / 26.438 / 26.526 / 26.626 / 26.733 / 26.830 / 26.947 / 27.166 / 

 27.448 / 27.552 / 27.669 / 27.776 / 27.974 / 

 28.293 / 28.432 / 28.616 / 28.720 / 28.944 / 29.074 / 

 29.336 / 

 29.688 / 29 920 /
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT E: REPRESENTATIVE GAS ANALYSIS 
	

	





	






























































 




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	Client: BISON ENGINEERING Analysis Date: 10/11/2011

Sample ID: ALISIA FOX 16Ͳ9 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 62 DEG F Sample Pressure: 20 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.677 1.161 0.551

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 3.323 3.626 1.742

Methane...................... 58.464 36.543 47.240

Ethane........................ 21.074 24.689 26.862

Propane....................... 10.662 18.317 13.999

isoͲButane................... 0.861 1.949 1.342

nͲButane...................... 2.523 5.713 3.791

isoͲPentane.................. 0.389 1.092 0.677

nͲPentane.................... 0.599 1.684 1.035

Cyclopentane............... 0.028 0.075 0.039

nͲHexane..................... 0.196 0.657 0.384

Cyclohexane................ 0.196 0.642 0.317

Other Hexanes ............. 0.147 0.492 0.287

Heptanes..................... 0.338 1.321 0.744

Methylcyclohexane........ 0.129 0.493 0.247

2,2,4ͲTrimethylpentane... 0.001 0.004 0.002

Benzene...................... 0.085 0.257 0.113

Toluene....................... 0.073 0.264 0.117

Ethylbenzene............... 0.003 0.014 0.006

Xylenes....................... 0.112 0.462 0.206

C8+ Heavies................ 0.122 0.545 0.299

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.028 0.075 0.039

Cyclohexane 0.196 0.642 0.317

2-Methylpentane 0.092 0.310 0.181

3-Methylpentane 0.054 0.182 0.106

n-Hexane 0.196 0.657 0.384

Methylcyclohexane 0.129 0.493 0.247

2,2,4-Trimethylpentane 0.001 0.004 0.002

Benzene 0.085 0.257 0.113

Toluene 0.073 0.264 0.117

Ethylbenzene 0.003 0.014 0.006

m-Xylene 0 018. 0 073. 0 033.

p-Xylene 0.076 0.313 0.139

o-Xylene 0.018 0.076 0.034

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 0 8862.

TOTAL GPM (Ethane Inclusive)................................................................. 10.561

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1462.236

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1437.527

AVERAGE MOLECULAR WEIGHT............................................................ 25.666

MOLAR MASS RATIO.............................................................................. 0.8862

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 0.8911

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1450 907 1450.907

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99453

PROPANE GPM ..................................................................................... 2.9297

BUTANE GPM ....................................................................................... 1.0743

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 0.9357

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

Sample ID: HIGH HAWK 4Ͳ9 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 59 DEG F Sample Pressure: 25 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.517 0.681 0.356

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 0.562 0.471 0.249

Methane...................... 28.060 13.456 19.176

Ethane........................ 34.433 30.949 37.122

Propane....................... 25.191 33.204 27.977

isoͲButane................... 2.180 3.787 2.875

nͲButane...................... 6.332 11.001 8.047

isoͲPentane.................. 0.795 1.714 1.172

nͲPentane.................... 1.017 2.194 1.487

Cyclopentane............... 0.037 0.079 0.045

nͲHexane..................... 0.146 0.375 0.242

Cyclohexane................ 0.047 0.119 0.065

Other Hexanes ............. 0.291 0.749 0.482

Heptanes..................... 0.084 0.252 0.157

Methylcyclohexane........ 0.025 0.073 0.040

2,2,4ͲTrimethylpentane... 0.000 0.000 0.000

Benzene...................... 0.018 0.043 0.021

Toluene....................... 0.069 0.190 0.093

Ethylbenzene............... 0.004 0.011 0.005

Xylenes....................... 0.015 0.049 0.024

C8+ Heavies................ 0.177 0.605 0.366

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.037 0.079 0.045

Cyclohexane 0.047 0.119 0.065

2-Methylpentane 0.183 0.471 0.303

3-Methylpentane 0.108 0.278 0.179

n-Hexane 0.146 0.375 0.242

Methylcyclohexane 0.025 0.073 0.040

2,2,4-Trimethylpentane 0.000 0.000 0.000

Benzene 0.018 0.043 0.021

Toluene 0.069 0.190 0.093

Ethylbenzene 0.004 0.011 0.005

m-Xylene 0 002. 0 008. 0 004.

p-Xylene 0.010 0.033 0.016

o-Xylene 0.003 0.008 0.004

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 1 1551.

TOTAL GPM (Ethane Inclusive)................................................................. 19.847

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1945.085

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1911.926

AVERAGE MOLECULAR WEIGHT............................................................ 33.454

MOLAR MASS RATIO.............................................................................. 1.1551

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 1.1668

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1921 067 1921.067

COMPRESSIBILITY FACTOR (Z).............................................................. 0.98992

PROPANE GPM ..................................................................................... 6.9222

BUTANE GPM ....................................................................................... 2.7025

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.0377

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: NATHAN HALE 3Ͳ18 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 59 DEG F Sample Pressure: 15 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.561 0.873 0.443

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 3.504 3.471 1.784

Methane...................... 56.578 32.094 44.375

Ethane........................ 15.797 16.795 19.545

Propane....................... 11.394 17.765 14.522

isoͲButane................... 1.536 3.156 2.325

nͲButane...................... 5.735 11.786 8.364

isoͲPentane.................. 1.045 2.666 1.768

nͲPentane.................... 1.419 3.619 2.379

Cyclopentane............... 0.102 0.252 0.139

nͲHexane..................... 0.461 1.405 0.877

Cyclohexane................ 0.304 0.903 0.478

Other Hexanes ............. 0.333 1.015 0.634

Heptanes..................... 0.692 2.453 1.478

Methylcyclohexane........ 0.242 0.842 0.451

2,2,4ͲTrimethylpentane... 0.001 0.002 0.001

Benzene...................... 0.192 0.530 0.248

Toluene....................... 0.066 0.215 0.102

Ethylbenzene............... 0.003 0.010 0.005

Xylenes....................... 0.010 0.038 0.018

C8+ Heavies................ 0.027 0.109 0.064

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.102 0.252 0.139

Cyclohexane 0.304 0.903 0.478

2-Methylpentane 0.210 0.639 0.399

3-Methylpentane 0.123 0.376 0.235

n-Hexane 0.461 1.405 0.877

Methylcyclohexane 0.242 0.842 0.451

2,2,4-Trimethylpentane 0.001 0.002 0.001

Benzene 0.192 0.530 0.248

Toluene 0.066 0.215 0.102

Ethylbenzene 0.003 0.010 0.005

m-Xylene 0 002. 0 006. 0 003.

p-Xylene 0.007 0.026 0.012

o-Xylene 0.002 0.006 0.003

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 0 9765.

TOTAL GPM (Ethane Inclusive)................................................................. 11.511

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1602.761

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1575.593

AVERAGE MOLECULAR WEIGHT............................................................ 28.281

MOLAR MASS RATIO.............................................................................. 0.9765

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 0.9832

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1588 143 1588.143

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99316

PROPANE GPM ..................................................................................... 3.1309

BUTANE GPM ....................................................................................... 2.3045

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.8621

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: SKUNK CREEK 1Ͳ12 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 78 DEG F Sample Pressure: 30 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.596 0.893 0.454

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 3.717 3.545 1.828

Methane...................... 46.514 25.407 35.242

Ethane........................ 22.053 22.578 26.359

Propane....................... 16.952 25.451 20.872

isoͲButane................... 1.718 3.399 2.512

nͲButane...................... 5.657 11.195 7.971

isoͲPentane.................. 0.829 2.037 1.355

nͲPentane.................... 1.021 2.507 1.654

Cyclopentane............... 0.070 0.167 0.092

nͲHexane..................... 0.263 0.771 0.483

Cyclohexane................ 0.077 0.222 0.118

Other Hexanes ............. 0.061 0.178 0.112

Heptanes..................... 0.231 0.789 0.477

Methylcyclohexane........ 0.034 0.115 0.062

2,2,4ͲTrimethylpentane... 0.000 0.000 0.000

Benzene...................... 0.015 0.040 0.019

Toluene....................... 0.044 0.137 0.065

Ethylbenzene............... 0.004 0.016 0.008

Xylenes....................... 0.018 0.066 0.032

C8+ Heavies................ 0.125 0.487 0.287

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.070 0.167 0.092

Cyclohexane 0.077 0.222 0.118

2-Methylpentane 0.038 0.112 0.070

3-Methylpentane 0.023 0.066 0.041

n-Hexane 0.263 0.771 0.483

Methylcyclohexane 0.034 0.115 0.062

2,2,4-Trimethylpentane 0.000 0.000 0.000

Benzene 0.015 0.040 0.019

Toluene 0.044 0.137 0.065

Ethylbenzene 0.004 0.016 0.008

m-Xylene 0 003. 0 011. 0 005.

p-Xylene 0.012 0.045 0.021

o-Xylene 0.003 0.011 0.005

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 1 0141.

TOTAL GPM (Ethane Inclusive)................................................................. 13.943

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1663.548

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1635.316

AVERAGE MOLECULAR WEIGHT............................................................ 29.370

MOLAR MASS RATIO.............................................................................. 1.0141

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 1.0215

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1647 712 1647.712

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99276

PROPANE GPM ..................................................................................... 4.6583

BUTANE GPM ....................................................................................... 2.3395

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.0627

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: TAT 2Ͳ1 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 117 DEG F Sample Pressure: 17 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.644 0.870 0.462

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 1.573 1.352 0.727

Methane...................... 39.023 19.208 27.788

Ethane........................ 23.624 21.796 26.538

Propane....................... 20.193 27.321 23.368

isoͲButane................... 2.557 4.559 3.514

nͲButane...................... 7.945 14.169 10.521

isoͲPentane.................. 1.185 2.623 1.820

nͲPentane.................... 1.596 3.532 2.430

Cyclopentane............... 0.101 0.217 0.125

nͲHexane..................... 0.369 0.975 0.637

Cyclohexane................ 0.172 0.445 0.246

Other Hexanes ............. 0.417 1.101 0.720

Heptanes..................... 0.393 1.209 0.762

Methylcyclohexane........ 0.099 0.299 0.168

2,2,4ͲTrimethylpentane... 0.001 0.002 0.001

Benzene...................... 0.031 0.075 0.037

Toluene....................... 0.034 0.097 0.048

Ethylbenzene............... 0.002 0.007 0.004

Xylenes....................... 0.007 0.021 0.011

C8+ Heavies................ 0.035 0.121 0.074

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.101 0.217 0.125

Cyclohexane 0.172 0.445 0.246

2-Methylpentane 0.262 0.693 0.453

3-Methylpentane 0.154 0.408 0.267

n-Hexane 0.369 0.975 0.637

Methylcyclohexane 0.099 0.299 0.168

2,2,4-Trimethylpentane 0.001 0.002 0.001

Benzene 0.031 0.075 0.037

Toluene 0.034 0.097 0.048

Ethylbenzene 0.002 0.007 0.004

m-Xylene 0 001. 0 003. 0 002.

p-Xylene 0.004 0.014 0.007

o-Xylene 0.001 0.003 0.002

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 1 1253.

TOTAL GPM (Ethane Inclusive)................................................................. 16.864

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1874.169

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1842.251

AVERAGE MOLECULAR WEIGHT............................................................ 32.591

MOLAR MASS RATIO.............................................................................. 1.1253

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 1.1360

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1852 257 1852.257

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99058

PROPANE GPM ..................................................................................... 5.5490

BUTANE GPM ....................................................................................... 3.3329

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.6803

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: WELL 32Ͳ29 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 66 DEG F Sample Pressure: 20 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.512 0.724 0.372

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 1.570 1.414 0.735

Methane...................... 39.457 20.353 28.475

Ethane........................ 27.369 26.461 31.158

Propane....................... 20.271 28.740 23.773

isoͲButane................... 2.013 3.763 2.805

nͲButane...................... 5.884 10.995 7.896

isoͲPentane.................. 0.765 1.776 1.192

nͲPentane.................... 1.021 2.368 1.575

Cyclopentane............... 0.054 0.123 0.069

nͲHexane..................... 0.193 0.536 0.339

Cyclohexane................ 0.066 0.180 0.096

Other Hexanes ............. 0.261 0.724 0.457

Heptanes..................... 0.240 0.773 0.471

Methylcyclohexane........ 0.081 0.254 0.138

2,2,4ͲTrimethylpentane... 0.000 0.000 0.000

Benzene...................... 0.015 0.038 0.018

Toluene....................... 0.073 0.216 0.104

Ethylbenzene............... 0.004 0.014 0.007

Xylenes....................... 0.015 0.050 0.024

C8+ Heavies................ 0.136 0.498 0.296

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.054 0.123 0.069

Cyclohexane 0.066 0.180 0.096

2-Methylpentane 0.164 0.455 0.288

3-Methylpentane 0.097 0.268 0.169

n-Hexane 0.193 0.536 0.339

Methylcyclohexane 0.081 0.254 0.138

2,2,4-Trimethylpentane 0.000 0.000 0.000

Benzene 0.015 0.038 0.018

Toluene 0.073 0.216 0.104

Ethylbenzene 0.004 0.014 0.007

m-Xylene 0 002. 0 008. 0 004.

p-Xylene 0.010 0.034 0.016

o-Xylene 0.002 0.008 0.004

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 1 0738.

TOTAL GPM (Ethane Inclusive)................................................................. 16.499

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1796.792

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1766.229

AVERAGE MOLECULAR WEIGHT............................................................ 31.101

MOLAR MASS RATIO.............................................................................. 1.0738

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 1.0830

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1777 412 1777.412

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99149

PROPANE GPM ..................................................................................... 5.5702

BUTANE GPM ....................................................................................... 2.5073

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.1204

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Client: BISON ENGINEERING Analysis Date: 10/11/2011

WILLIAMS

Sample ID: WOLF 27Ͳ34 Date Sampled: 10/11/2011

Unique #: Purpose:

Sample Temperature: 60 DEG F Sample Pressure: 30 PSI

Sampled By: TC Type Sample: ONLINE

County: DUNN

 Components Mole % Weight % Liq. Vol. %

Carbon Dioxide............. 0.514 0.836 0.406

Hydrogen Sulfide........... 0.000 0.000 0.000

Nitrogen...................... 2.455 2.541 1.250

Methane...................... 55.961 33.170 43.916

Ethane........................ 21.138 23.484 26.169

Propane....................... 11.397 18.569 14.535

isoͲButane................... 1.184 2.543 1.794

nͲButane...................... 3.503 7.523 5.113

isoͲPentane.................. 0.833 2.219 1.409

nͲPentane.................... 1.363 3.634 2.287

Cyclopentane............... 0.097 0.250 0.132

nͲHexane..................... 0.357 1.138 0.680

Cyclohexane................ 0.150 0.467 0.236

Other Hexanes ............. 0.456 1.453 0.868

Heptanes..................... 0.400 1.481 0.854

Methylcyclohexane........ 0.082 0.299 0.153

2,2,4ͲTrimethylpentane... 0.000 0.000 0.000

Benzene...................... 0.030 0.085 0.038

Toluene....................... 0.032 0.110 0.050

Ethylbenzene............... 0.002 0.006 0.003

Xylenes....................... 0.007 0.026 0.012

C8+ Heavies................ 0.039 0.166 0.093

Totals ........................ 100.000 100.000 100.000
ADDITIONAL BETX DATA

 Components Mole % Weight % Liq. Vol. %

Cyclopentane 0.097 0.250 0.132

Cyclohexane 0.150 0.467 0.236

2-Methylpentane 0.287 0.914 0.547

3-Methylpentane 0.169 0.538 0.322

n-Hexane 0.357 1.138 0.680

Methylcyclohexane 0.082 0.299 0.153

2,2,4-Trimethylpentane 0.000 0.000 0.000

Benzene 0.030 0.085 0.038

Toluene 0.032 0.110 0.050

Ethylbenzene 0.002 0.006 0.003

m-Xylene 0 001. 0 004. 0 002.

p-Xylene 0.005 0.018 0.008

o-Xylene 0.001 0.004 0.002

SPECIFIC GRAVITY @ 60/60 F l l t d SPECIFIC GRAVITY @ 60/60 F, calculated................................................... 0 9345.

TOTAL GPM (Ethane Inclusive)................................................................. 11.726

CALCULATED BTU / REAL CF @ 14.73 PSIA, dry basis.................................. 1558.098

CALCULATED BTU / REAL CF @ 14.73 PSIA, wet basis.................................. 1531.712

AVERAGE MOLECULAR WEIGHT............................................................ 27.065

MOLAR MASS RATIO.............................................................................. 0.9345

RELATIVE DENSITY ( G x Z (Air) / Z ), calculated........................................ 0.9403

IDEAL GROSS HEATING VALUE BTU / IDEAL CF @ 14 696 PSIA IDEAL GROSS HEATING VALUE, BTU / IDEAL CF @ 14.696 PSIA.................. 1544 831 1544.831

COMPRESSIBILITY FACTOR (Z).............................................................. 0.99377

PROPANE GPM ..................................................................................... 3.1318

BUTANE GPM ....................................................................................... 1.4882

GASOLINE GPM (PENTANE AND HEAVIER) ........................................... 1.4675

NOTATION: ALL CALCULATIONS PERFORMED USING PHYSICAL CONSTANTS FROM GPA 2145-09, THE TABLES

 OF PHYSICAL CONSTANTS FOR HYDROCARBONS AND OTHER COMPOUNDS OF INTEREST

 TO THE NATURAL GAS INDUSTRY.
Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT F: ENGINE MANUFACTURER’S SPECS 
This section of the document has been redacted because it 

contains copyrighted information. The redacted information 

can be viewed from the hard copy of the docket, which is 

available at the EPA Region 8 Office upon request. 






Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT G: EMISSION CONTROL DEVICE 

MANUFACTURER’S SPECS 


	



	











 



TYPICAL MANDAREE AREA 

FOUR WELL PAD FACILITY PLOT PLAN 

Dakota-3 E&P Company, LLC 

FBIR, North Dakota 

NOT TO SCALE 

12’d x 20’h 12’d x 20’h 12’d x 20’h 

Recycle Pump 

Chemicals 

(4)Wellheads 

Tank Vent line 

Utility 

Flare

 

LACT 

Gas to sales

Gas Meter

12’d x 20’h 12’d x 20’h 12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl 

Prod. H2O 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl oil 

Enclosed 

Combustor

Recycle 

Pump 

Recycle 

Pump 

Recycle 

Pump 

LACT 

Unit 

LACT 

Unit 

LACT 

Unit 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl 

H2O 

12’d x 20’h 

12’d x 20’h 

12’d x 20’h 

400 bbl oil 

12’d x 20’h 

400 bbl oil 

Valve

Valve

Valve

Valve

Recycle Line 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 

Gas Meter 

(4) Gensets 

Genset

Oil Pipeline 

Water 

Pipeline 

24 bbl 

Diesel 

Legend 

Berms 

Water Line 

Crude Line 

Flowline 

Buried Recycle Lines 

Gas Sales Line 

Tank Vapor Line 

Flared Gas Line 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 

Gas Meter 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 

6’d x 20’h 

vertical treater 

Separator 30” d 

by 10’ h 
	



	










 




Dakota-3 E&P Company, LLC. 

NSR Synthetic Minor Application 

WEP211324 

ATTACHMENT J: DIESEL TANK EPA TANKS 4.09D 

EMISSIONS SUMMARY 
TANKS 4.0.9d

Emissions Report - Detail Format 

Tank Indentification and Physical Characteristics

Identification

 User Identification: 1000 gallon diesel tank

 City: Williston

 State: North Dakota

 Company: Williams E&P, LLC

 Type of Tank: Horizontal Tank

 Description: 1,000 gallon diesel tank to fuel onsite diesel generators. Tank throughput is based on engine fuel consumption.

Tank Dimensions

 Shell Length (ft): 10.00

 Diameter (ft): 4.16

 Volume (gallons): 1,000.00

 Turnovers: 2,244.31

 Net Throughput(gal/yr): 2,244,312.00

 Is Tank Heated (y/n): N

 Is Tank Underground (y/n): N

Paint Characteristics

 Shell Color/Shade: Gray/Medium

 Shell Condition Good

Breather Vent Settings

 Vacuum Settings (psig): -0.03

 Pressure Settings (psig) 0.03

Meterological Data used in Emissions Calculations: Bismarck, North Dakota (Avg Atmospheric Pressure = 13.86 psia)

TANKS 4.0 Report Page 1 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
1000 gallon diesel tank - Horizontal Tank

Williston, North Dakota 

TANKS 4.0.9d

Emissions Report - Detail Format 

Liquid Contents of Storage Tank

Daily Liquid Surf. 

Temperature (deg F)

Liquid

Bulk

Temp Vapor Pressure (psia)

Vapor

Mol. 

Liquid

Mass 

Vapor

Mass Mol. Basis for Vapor Pressure

Mixture/Component Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract. Fract. Weight Calculations

Distillate fuel oil no. 2 All 50.18 39.72 60.64 44.68 0.0045 0.0031 0.0067 130.0000 188.00 Option 1: VP50 = .0045 VP60 = .0065

TANKS 4.0 Report Page 2 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
1000 gallon diesel tank - Horizontal Tank

Williston, North Dakota 

TANKS 4.0.9d

Emissions Report - Detail Format 

Detail Calculations (AP-42)

Annual Emission Calcaulations

Standing Losses (lb): 0.2654

 Vapor Space Volume (cu ft): 86.5719

 Vapor Density (lb/cu ft): 0.0001

 Vapor Space Expansion Factor: 0.0780

 Vented Vapor Saturation Factor: 0.9995

Tank Vapor Space Volume:

 Vapor Space Volume (cu ft): 86.5719

 Tank Diameter (ft): 4.1600

 Effective Diameter (ft): 7.2797

 Vapor Space Outage (ft): 2.0800

 Tank Shell Length (ft): 10.0000

Vapor Density

 Vapor Density (lb/cu ft): 0.0001

 Vapor Molecular Weight (lb/lb-mole): 130.0000

 Vapor Pressure at Daily Average Liquid

 Surface Temperature (psia): 0.0045

 Daily Avg. Liquid Surface Temp. (deg. R): 509.8466

 Daily Average Ambient Temp. (deg. F): 41.5958

 Ideal Gas Constant R

 (psia cuft / (lb-mol-deg R)): 10.731

 Liquid Bulk Temperature (deg. R): 504.3458

 Tank Paint Solar Absorptance (Shell): 0.6800

 Daily Total Solar Insulation

 Factor (Btu/sqft day): 1,276.2450

Vapor Space Expansion Factor

 Vapor Space Expansion Factor: 0.0780

 Daily Vapor Temperature Range (deg. R): 41.8377

 Daily Vapor Pressure Range (psia): 0.0036

 Breather Vent Press. Setting Range(psia): 0.0600

 Vapor Pressure at Daily Average Liquid

 Surface Temperature (psia): 0.0045

 Vapor Pressure at Daily Minimum Liquid

 Surface Temperature (psia): 0.0031

 Vapor Pressure at Daily Maximum Liquid

 Surface Temperature (psia): 0.0067

 Daily Avg. Liquid Surface Temp. (deg R): 509.8466

 Daily Min. Liquid Surface Temp. (deg R): 499.3872

 Daily Max. Liquid Surface Temp. (deg R): 520.3060

 Daily Ambient Temp. Range (deg. R): 24.3583

Vented Vapor Saturation Factor

 Vented Vapor Saturation Factor: 0.9995

 Vapor Pressure at Daily Average Liquid:

 Surface Temperature (psia): 0.0045

 Vapor Space Outage (ft): 2.0800

Working Losses (lb): 5.6720

 Vapor Molecular Weight (lb/lb-mole): 130.0000

 Vapor Pressure at Daily Average Liquid

 Surface Temperature (psia): 0.0045

 Annual Net Throughput (gal/yr.): 2,244,312.0000

TANKS 4.0 Report Page 3 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
 Annual Turnovers: 2,244.3120

 Turnover Factor: 0.1800

 Tank Diameter (ft): 4.1600

 Working Loss Product Factor: 1.0000

Total Losses (lb): 5.9375

TANKS 4.0 Report Page 4 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
Emissions Report for: Annual 

1000 gallon diesel tank - Horizontal Tank

Williston, North Dakota 

TANKS 4.0.9d

Emissions Report - Detail Format 

Individual Tank Emission Totals

Losses(lbs)

Components Working Loss Breathing Loss Total Emissions

Distillate fuel oil no. 2 5.67 0.27 5.94

TANKS 4.0 Report Page 5 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011
TANKS 4.0 Report Page 6 of 6

file://C:\Program Files\Tanks409d\summarydisplay.htm 9/29/2011