### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information**

Parent Company

Name:

Address:

City:
Country: USA

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 145 115 Perimeter Place, Suite 460 Axiall Corporation

662-369-3590

jason.darnell@axiall.com Aberdeen

PO Box 91

Aberdeen

Jason Darnell Atlanta

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: GA Zip Code: 30346

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 5848

State: MS Zip Code: 39730

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER**

Process Unit ID: 1

Process Equipment ID: U-60/61 Wastewater Feed Rate (lb/hr): 10500 Feed Temperature (°F): 80 Feed Inlet Pressure (psia): 20 Liquid Loading Rate (liters/m2): SteamFeed Rate (lb/hr): 3000 Steamto Feed Ratio (kg steam/liter of wastewater): Operating Temperature (°F): 200 Operating Pressure (psig): 0 Total Number of Stages: 1 Overall Calculated Tray Efficiency: 100 Stripping Factor: Flow configuration (countercurrent, cocurrent): Batch Number of Actual Trays: 0 Colum n Height (meters):

Year Equipm ent Installed: 2004 Equipm ent Currently

Regulated Under (cite regulations): 40 CFR 61 Subparts A and F, 40 CFR 63 Subpart J 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions**

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

40 CFR 61 Subparts A and F, 40 CFR 63 Subpart J 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessaryPlease also provide the stripper feed rate in liters per hour, or liters for batch strippers: liters/hour 15000 liters

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

**PVC Process Wastewater**  **Stream ID PVC Process**  **Unit ID Name of PVC Process Wastewater Stream**  **2 Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System**  **1 2**  **3 4**  **5 6** 

**Min** 1 U-60/61 SteamStripping Batch 16000

**Table 3. PVC Process Wastewater Destination Codes Table**

Wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3**

**Min Ma** **x Is this**  **process wastewater**  **treatment system batch**  **or continuous operation?** 

**Process Wastewater Stream Flow Rate (gallons per day)**  **Ty pe of Process**  **Wastewater Treatment System** 

**Source of Process Wastewater Stream**

**1 PVC Process Wastewater Stream Flow Rate** 

**Destination Description PVC Process**  **Wastewater Treatment**  **System ID PVC Process**  **Unit ID PVC Process**  **Wastewater Stream ID** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Operating Days Per**  **Year Flow Rate**  **Determination Me** **thod 7**  **8 9**  **10 11** 

**Ma x**  **Av erage**  24000 20000 Estimated 350 WWT

**Code** WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 4**  **5 6**  **7**

**Av erage**  **Flow Rate Determination**  **Me thod**  **Operating Days**

**Per Year**

**Process Wastewater Stream Flow Rate**

**(gallons per day) PVC Process**  **Wastewater Stream Destination Code** 

(Refer to Table 3 below) **PVC Process Wastewater Stream Flow Rate**

**(gallons per day)**

**Flow Rate**

**Determination Me** **thod PVC Process**  **Wastewater Treatment**  **System ID Operating Days**  **Per Year Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

**Originating PVC Process Equipment ID**  **Originating PVC Process Equipment Description** **12 13** 

City of Aberdeen POTW Yes

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recycled **As sociated Destination**  **Information**

(Refer to Table 3 below)

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Is this PVC process wastewater**  **stream exposed to the atmosphere at any point between the outlet of**  **the PVC process wastewater treatment system and its**  **destination? 11**  **12**

**As sociated Destination Information**  **PVC Process Wastewater Stream Destination Code** 

(Refer to Table 3 below)**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system**  **14**

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 13** 

**Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? If your response in Column 3 is "Other" then please provide a description of the process wastewaetr** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P** 

107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethylpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethylene) 1330207 Xylenes (isomers and mixtures)

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

Axiall Corporation Aberdeen

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?** 

SW-846-8015C 0.6 Non-detect SW-846-8015C 0.2 Non-detect SW-846-8315A 6.53 SW-846-8315A 0.975 SW-846-8270D 0.0876 Non-detect SW-846-8270D 15.8 SW-846-8270D 0.143 Non-detect SW-846-8270D 0.370 Non-detect SW-846-8270D 0.485 Non-detect SW-846-8260B 0.00465 Non-detect SW-846-8260B 0.012 Non-detect SW-846-8260B 0.0225 Non-detect SW-846-8260B 0.00239 Non-detect SW-846-8260B 0.00232 Non-detect SW-846-8260B 0.00545 Non-detect SW-846-8260B 0.0165 Non-detect SW-846-8260B 0.00287 Non-detect SW-846-8260B 0.0271 SW-846-8260B 0.00291 Non-detect SW-846-8260B 0.0140 Non-detect SW-846-8260B 0.00580 Non-detect SW-846-8260B 0.049 SW-846-8260B 0.0209 Non-detect SW-846-8260B 0.0835 Non-detect **Stream Temperature (degrees F) -->**

**Sample Date -->**

**Stream Flow Rate (gallons per minute) --> Resin Type (suspension, dispersion, bulk, etc.) -->**  Suspension 200 01/14/13

Stripper Bottoms W astewater 13-015-0215 01/16/13 41

**Lab Report ID --> Flow Rate Determination Method -->** 

**An alysis Date -->** 

**Lab Sample ID -->** EstimatedSW-846-8260B 0.00250 Non-detect

SW-846-8260B 0.00690 Non-detect SW-846-8260B 0.00223 Non-detect SW-846-8260B 0.00337 Non-detect SW-846-8260B NOT FOUND Non-detect EPA Method 107 0.869 SW-846-8260B 0.00287 Non-detect SW-846-8260B 0.0036 Non-detect1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 0.2 Non-detect 11.600 Detected in blank 1.21 0.0928 Non-detect 14.800 0.152 Non-detect 0.400 Non-detect 0.513 Non-detect 0.00465 Non-detect 0.012 Non-detect 0.0225 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.00287 Non-detect Estimated Value 0.0533 0.00291 Non-detect 0.0140 Non-detect 0.00580 Non-detect Estimated Value 0.128 0.0209 Non-detect 0.0835 Non-detect **1**

Suspension

Estimated

Stripper Bottoms W astewater Estimated

01/18/13 37.4

13-017-0225 01/15/13

200 **2**0.00250 Non-detect 0.00690 Non-detect 0.00223 Non-detect 0.00337 Non-detect NOT FOUND Non-detect

1.780 0.00358 Non-detect 0.0036 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 0.2 Non-detect 0.2 Non-detect 7.32 7.97 1.32 1.66 0.0770 Non-detect 0.0686 Non-detect 18.5 17.9 0.126 Non-detect 0.112 Non-detect 0.435 Non-detect 0.429 Non-detect 0.426 Non-detect 0.0379 Non-detect 0.00465 Non-detect 0.00186 Non-detect 0.0120 Non-detect 0.00480 Non-detect 0.0225 Non-detect 0.00900 Non-detect 0.00239 Non-detect 0.00095 Non-detect 0.00232 Non-detect 0.00092 Non-detect 0.00545 Non-detect 0.00218 Non-detect 0.0165 Non-detect 0.0066 Non-detect 0.00287 Non-detect 0.00115 Non-detect 0.00625 Non-detect 0.0242 0.00291 Non-detect 0.00116 Non-detect 0.0140 Non-detect 0.00560 Non-detect 0.00580 Non-detect 0.00232 Non-detect 0.0651 0.0826 0.0209 Non-detect 0.00836 Non-detect 0.0835 Non-detect 0.0334 Non-detect 200

41 Estimated

Stripper Bottoms W astewater 01/18/13 39.2 Estimated

13-017-0226 13-021-0234 01/21/13

Stripper Bottoms W astewater 200 **3** 01/17/13 01/16/13 Suspension Suspension0.00250 Non-detect 0.00099 Non-detect

0.00690 Non-detect 0.00276 Non-detect 0.00223 Non-detect 0.00089 Non-detect 0.00337 Non-detect 0.00135 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

1.17 1.86 0.00358 Non-detect 0.00143 Non-detect 0.0036 Non-detect 0.0014 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 0.2 Non-detect 5.55 1.40 0.0853 Non-detect 16.8 0.139 Non-detect 0.316 Non-detect 0.0472 Non-detect 0.00186 Non-detect 0.00480 Non-detect 0.00900 Non-detect 0.00095 Non-detect 0.00092 Non-detect 0.00218 Non-detect 0.00660 Non-detect 0.00115 Non-detect 0.0740 0.00116 Non-detect 0.00560 Non-detect 0.00232 Non-detect 0.211 0.00836 Non-detect 0.0334 Non-detect 35.6 Estimated Estimated

13-021-0235 01/21/13

Stripper Bottoms W astewater Suspension 200 **4 5**  01/18/130.00099 Non-detect 0.00276 Non-detect 0.00089 Non-detect 0.00135 Non-detect NOT FOUND Non-detect

2.700 0.00143 Non-detect 0.0014 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

65.9 Non-detect 6.5 Non-detect 1650 790 4.77 5.99 1.61 1.2 0.0789 Non-detect 0.0631 Non-detect 15.400 14.7 0.129 Non-detect 0.103 Non-detect 0.380 Non-detect 0.0316 Non-detect 0.0436 Non-detect 0.0349 Non-detect 0.00465 Non-detect 0.00465 Non-detect 0.0120 Non-detect 0.0120 Non-detect 0.0225 Non-detect 0.0225 Non-detect 0.00239 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.0165 Non-detect 0.00287 Non-detect 0.00287 Non-detect 0.127 0.00625 Non-detect 0.00291 Non-detect 0.00291 Non-detect 0.0682 0.386 0.00580 Non-detect 0.00580 Non-detect 0.197 0.0362 0.0209 Non-detect 0.0209 Non-detect 0.0835 Non-detect 0.0835 Non-detect 01/19/13 01/20/13

01/22/13 13-021-0263 Estimated

Stripper Bottoms W astewater Stripper Bottoms W astewater 39.2

13-021-0264 01/22/13 Estimated 39.2 **6**

200 200 Suspension Suspension0.00250 Non-detect 0.00250 Non-detect

0.00690 Non-detect 0.00690 Non-detect 0.00223 Non-detect 0.00223 Non-detect 0.00337 Non-detect 0.00337 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

5.350 0.766 0.00358 Non-detect 0.00358 Non-detect 0.0036 Non-detect 0.0036 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

6.5 Non-detect 673 4.70 1.08 0.0657 Non-detect 24.0 0.107 Non-detect 0.0316 Non-detect 0.0364 Non-detect 0.00186 Non-detect 0.00480 Non-detect 0.00900 Non-detect 0.00095 Non-detect 0.00092 Non-detect 0.00218 Non-detect 0.00660 Non-detect 0.00115 Non-detect 0.0322 0.00116 Non-detect Estimated value 0.0380 0.00232 Non-detect Estimated value 0.107 0.00836 Non-detect 0.0334 Non-detect Suspension

Estimated 200 01/21/13 **7 8** 

Estimated 41

Stripper Bottoms W astewater 13-021-0265 01/22/130.00099 Non-detect 0.00276 Non-detect 0.00089 Non-detect 0.00135 Non-detect NOT FOUND Non-detect

1.250 0.00143 Non-detect 0.0014 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.8 Estimated value/detected in blank 1.0 1250 910 32.4 2.42 4.37 0.381 0.0678 Non-detect 0.0678 Non-detect 21.5 19.7 0.111 Non-detect 0.111 Non-detect 0.319 Non-detect 0.306 Non-detect 0.0375 Non-detect 0.0375 Non-detect 0.00186 Non-detect 0.00092 Non-detect 0.00480 Non-detect 0.00240 Non-detect 0.00900 Non-detect 0.00450 Non-detect 0.00095 Non-detect 0.00047 Non-detect 0.00092 Non-detect 0.00046 Non-detect 0.00218 Non-detect 0.00109 Non-detect 0.00660 Non-detect 0.00330 Non-detect 0.00115 Non-detect 0.00335 0.0643 0.112 0.00116 Non-detect 0.00058 Non-detect 0.00560 Non-detect 0.406 0.00232 Non-detect 0.00116 Non-detect 0.144 0.259 0.00836 Non-detect 0.00418 Non-detect 0.0334 Non-detect 0.0167 Non-detect Suspension 200 200 **9** 01/23/13 01/22/13 Suspension

01/25/13 37.4 Estimated Estimated 39.2

Stripper Bottoms W astewater Stripper Bottoms W astewater 13-024-0209 13-024-0210 01/25/130.00099 Non-detect 0.00049 Non-detect

0.00276 Non-detect 0.00044 Non-detect 0.00089 Non-detect 0.00138 Non-detect 0.00135 Non-detect 0.00067 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

1.82 3.37 0.00143 Non-detect 0.00071 Non-detect 0.00115 Non-detect 0.0007 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

Detected in blank 10.4 Detected in blank 901 2.16 Estimated Value 0.223 0.0760 Non-detect 30.8 0.124 Non-detect 0.300 Non-detect 0.0420 Non-detect 0.00186 Non-detect 0.00240 Non-detect 0.00450 Non-detect 0.00095 Non-detect 0.00092 Non-detect 0.00218 Non-detect 0.00660 Non-detect Estimated Value 0.00115 Non-detect 0.0358 0.00116 Non-detect 0.0382 0.00232 Non-detect 0.0859 0.0265 Estimated value 0.0334 Non-detect 01/24/13 Suspension **10 11** 

200

33.8 01/28/13 Estimated Estimated

Stripper Bottoms W astewater 13-028-02050.00099 Non-detect 0.00276 Non-detect 0.00089 Non-detect 0.00135 Non-detect NOT FOUND Non-detect

0.934 0.00143 Non-detect 0.0014 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

19.7 Detected in blank 3.9 2210 2300 4.63 5.79 0.419 0.987 0.0686 Non-detect 0.0751 Non-detect 38.1 38.2 0.112 Non-detect 0.123 Non-detect 0.357 Non-detect 0.361 Non-detect 0.0379 Non-detect 0.0415 Non-detect 0.00186 Non-detect 0.00009 Non-detect 0.00480 Non-detect 0.00024 Non-detect 0.00900 Non-detect 0.00045 Non-detect 0.00095 Non-detect 0.00004 Non-detect 0.00092 Non-detect 0.00004 Non-detect 0.00412 Estimated value 0.00010 Non-detect 0.00660 Non-detect 0.00033 Non-detect 0.00115 Non-detect 0.00081 0.0694 0.0359 0.00116 Non-detect 0.00005 Non-detect 0.107 0.0369 0.00232 Non-detect 0.00011 Non-detect 0.218 0.123 0.0303 Estimated value 0.00041 Non-detect 0.0334 Non-detect 0.00167 Non-detect 01/25/13 01/26/13 Suspension Suspension **12**

200

39.2 37.4 200 Estimated Estimated

13-028-0206 13-028-0301 01/28/13 01/29/13

Stripper Bottoms W astewater Stripper Bottoms W astewater0.00099 Non-detect 0.00004 Non-detect

0.00276 Non-detect 0.00013 Non-detect 0.00089 Non-detect 0.00075 0.00135 Non-detect 0.0006 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

1.59 1.01 0.00143 Non-detect 0.00007 Non-detect 0.0014 Non-detect 0.00007 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

Detected in blank 3.6 Detected in blank 1710 5.59 0.918 0.0631 Non-detect 39.9 0.103 Non-detect 0.345 Non-detect 0.0349 Non-detect 0.00009 Non-detect 0.00024 Non-detect 0.00045 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.00010 Non-detect 0.00033 Non-detect Estimated value 0.00129 0.0755 0.00005 Non-detect 0.0521 0.00011 Non-detect 0.245 0.00041 Non-detect 0.00167 Non-detect Suspension **13 14**  01/27/13

200

33.8 Estimated Estimated

01/29/13 13-028-0302 Stripper Bottoms W astewater0.00004 Non-detect 0.00013 Non-detect Estimated value 0.00128 0.00006 Non-detect NOT FOUND Non-detect

1.54 0.00007 Non-detect 0.00007 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

3.2 Detected in blank 0.6 Non-detect 1580 201 4.25 4.26 0.978 0.496 0.0742 Non-detect 0.0631 Non-detect 16.8 10.7 0.121 Non-detect 0.103 Non-detect 0.385 Non-detect 0.300 Non-detect 0.0411 Non-detect 0.0349 Non-detect 0.00009 Non-detect 0.00929 Non-detect 0.00024 Non-detect 0.0240 Non-detect 0.00045 Non-detect 0.0450 Non-detect 0.00004 Non-detect 0.00478 Non-detect 0.00004 Non-detect 0.00463 Non-detect 0.00010 Non-detect 0.0109 Non-detect 0.00033 Non-detect 0.0330 Non-detect 0.00157 0.00573 Non-detect 0.0609 0.0125 Non-detect 0.00005 Non-detect 0.00581 Non-detect 0.0448 0.0280 Non-detect 0.00011 Non-detect 0.0116 Non-detect 0.170 0.0538 0.00041 Non-detect 0.179 0.00167 Non-detect 0.167 Non-detect Suspension Suspension 01/29/13 01/28/13 **15**

39.2 Estimated 200 200

41 Estimated

13-028-0303 Stripper Bottoms W astewater Stripper Bottoms W astewater 13-031-0227 01/29/13 02/01/130.00004 Non-detect 0.00499 Non-detect

0.00013 Non-detect 0.0138 Non-detect 0.00106 0.00445 Non-detect 0.00006 Non-detect 0.00674 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

1.32 0.718 0.00007 Non-detect 0.00716 Non-detect 0.00007 Non-detect 0.0072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 71.5 4.39 0.653 0.0701 Non-detect 14.4 0.115 Non-detect 0.333 Non-detect 0.0388 Non-detect 0.00186 Non-detect 0.00480 Non-detect 0.00900 Non-detect 0.00095 Non-detect 0.00092 Non-detect 0.00218 Non-detect 0.00660 Non-detect 0.00115 Non-detect 0.101 0.00116 Non-detect 0.0786 0.00232 Non-detect Estimated value 0.250 Estimated value 0.0329 Estimated value 0.0334 Non-detect Suspension **16 17**  01/30/13

Estimated Estimated 200

02/01/13

Stripper Bottoms W astewater 13-031-0228 37.40.00099 Non-detect 0.00276 Non-detect 0.00089 Non-detect 0.00135 Non-detect NOT FOUND Non-detect

2.92 0.00143 Non-detect 0.0014 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 97.0 175 3.28 6.59 1.29 1.15 0.0709 Non-detect 0.0678 Non-detect 22.4 28.0 0.116 Non-detect 0.111 Non-detect 0.361 Non-detect 0.357 Non-detect 0.0392 Non-detect 0.0375 Non-detect 0.00465 Non-detect 0.00465 Non-detect 0.0120 Non-detect 0.0120 Non-detect 0.0225 Non-detect 0.0225 Non-detect 0.00239 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.0165 Non-detect 0.00287 Non-detect 0.00287 Non-detect 0.0466 Estimated value 0.224 0.00291 Non-detect 0.00291 Non-detect 0.0798 0.235 0.00580 Non-detect 0.00580 Non-detect 0.141 0.396 0.0209 Non-detect 0.0209 Non-detect 0.0835 Non-detect 0.0835 Non-detect Suspension Suspension 01/31/13 02/01/13 **18**

Estimated Estimated 200 200

02/04/13 02/04/13

Stripper Bottoms W astewater Stripper Bottoms W astewater 39.2

13-035-0213 37.4

13-035-02140.00250 Non-detect 0.00250 Non-detect

0.00690 Non-detect 0.00690 Non-detect 0.00223 Non-detect 0.00223 Non-detect 0.00337 Non-detect 0.00337 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

1.26 3.00 0.00358 Non-detect 0.00358 Non-detect 0.0036 Non-detect 0.0036 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 116 3.50 0.912 0.0760 Non-detect 20.8 0.0124 Non-detect 0.349 Non-detect 0.0420 Non-detect 0.00465 Non-detect 0.0518 0.0225 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.00287 Non-detect 0.117 0.00291 Non-detect 0.0140 Non-detect 0.00580 Non-detect 0.305 0.0209 Non-detect 0.0835 Non-detect 02/02/13 Suspension **19 20** 

Estimated Estimated 200

39.2 02/06/13 13-035-0304 Stripper Bottoms W astewater0.00250 Non-detect 0.00690 Non-detect 0.00223 Non-detect 0.00337 Non-detect NOT FOUND Non-detect

2.79 0.00358 Non-detect 0.00358 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 216 120 3.63 4.02 1.16 1.22 0.0734 Non-detect 0.0779 Non-detect 20.4 26.6 0.120 Non-detect 0.127 Non-detect 0.357 Non-detect 0.437 0.0406 Non-detect 0.0431 Non-detect 0.00465 Non-detect 0.00465 Non-detect 0.0470 Estimated Value 0.0120 Non-detect 0.0225 Non-detect 0.0225 Non-detect 0.00239 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.0165 Non-detect 0.00287 Non-detect 0.00287 Non-detect 0.0957 0.0447 0.00291 Non-detect 0.00291 Non-detect 0.109 0.0705 0.00580 Non-detect 0.00580 Non-detect 0.211 0.111 0.0209 Non-detect 0.0209 Non-detect 0.0835 Non-detect 0.0835 Non-detect 02/03/13 02/04/13 Suspension **21**

35.6 200 Estimated

02/06/13

Stripper Bottoms W astewater 200 Suspension

Estimated

13-035-0305 13-035-0306 02/06/13

Stripper Bottoms W astewater 37.40.00250 Non-detect 0.00250 Non-detect

0.00690 Non-detect 0.00690 Non-detect 0.00223 Non-detect 0.00223 Non-detect 0.00337 Non-detect 0.00337 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

1.54 1.15 0.00358 Non-detect 0.00358 Non-detect 0.0036 Non-detect 0.0036 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 111 3.66 1.97 0.0657 Non-detect 18.3 0.107 Non-detect Estimated value 0.333 Non-detect 0.0364 Non-detect 0.00092 Non-detect 0.00240 Non-detect 0.00450 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.0141 0.00330 Non-detect 0.00057 Non-detect Estimated value 0.101 0.00058 Non-detect 0.00280 Non-detect 0.00116 Non-detect 0.385 0.00418 Non-detect 0.0167 Non-detect **22** 02/05/13 Suspension

Estimated

13-038-0264 41 200 Estimated

02/08/13

Stripper Bottoms W astewater **23**0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect NOT FOUND Non-detect

1.68 0.00071 Non-detect 0.0007 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

2.0 3.3 242 273 3.65 2.92 1.11 0.960 0.0725 Non-detect 0.0742 Non-detect 17.8 21.8 0.119 Non-detect 0.121 Non-detect 0.341 Non-detect 0.323 Non-detect 0.0401 Non-detect 0.0411 Non-detect 0.00465 Non-detect 0.00092 Non-detect 0.0120 Non-detect 0.00240 Non-detect 0.0225 Non-detect 0.00450 Non-detect 0.00239 Non-detect 0.00047 Non-detect 0.00232 Non-detect 0.00046 Non-detect 0.00545 Non-detect 0.00109 Non-detect 0.0165 Non-detect 0.00330 Non-detect 0.00287 Non-detect 0.00057 Non-detect 0.191 0.0453 0.00291 Non-detect 0.00394 0.132 0.0467 0.00580 Non-detect 0.00116 Non-detect 0.449 0.124 0.0209 Non-detect 0.00418 Non-detect 0.0835 Non-detect 0.0167 Non-detect 02/06/13 02/07/13 Suspension Suspension 200 200 Estimated

13-042-0203 39.2. 39.2 02/08/13 Estimated

02/12/13

Stripper Bottoms W astewater 13-038-0265 Stripper Bottoms W astewater **24**0.00250 Non-detect 0.00049 Non-detect

0.00690 Non-detect 0.00138 Non-detect 0.0223 Non-detect 0.00044 Non-detect 0.00337 Non-detect 0.00067 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

3.11 0.976 0.00358 Non-detect 0.00071 Non-detect 0.0036 Non-detect 0.0007 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

Detected in blank 0.6 Non-detect 149 3.47 1.25 0.077 Non-detect 23.4 0.126 Non-detect 0.390 Non-detect 0.0426 Non-detect 0.00092 Non-detect 0.00240 Non-detect 0.00450 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00330 Non-detect 0.00057 Non-detect 0.11 Estimated value; detected in blank 0.00269 Estimated value; detected in blank 0.0684 0.00116 Non-detect 0.230 0.00418 Non-detect 0.0167 Non-detect Estimated

Stripper Bottoms W astewater **26 25** 

37.4 02/12/13 Suspension 200 02/08/13

13-042-0204 Estimated0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect NOT FOUND Non-detect

2.95 0.00071 Non-detect 0.0007 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 153 162 4.34 4.82 0.775 0.798 0.0760 Non-detect 0.0631 Non-detect 21.8 37 0.124 Non-detect 0.103 Non-detect 0.323 Non-detect 0.323 Non-detect 0.0420 Non-detect 0.0349 Non-detect 0.00092 Non-detect 0.00465 Non-detect 0.00240 Non-detect 0.0120 Non-detect 0.00450 Non-detect 0.02250 Non-detect 0.00047 Non-detect 0.00239 Non-detect 0.00046 Non-detect 0.00232 Non-detect 0.00109 Non-detect 0.00545 Non-detect 0.00330 Non-detect 0.01650 Non-detect 0.00057 Non-detect 0.00287 Non-detect 0.0182 0.0516 0.00058 Non-detect 0.00291 Non-detect 0.0155 0.124 0.00116 Non-detect 0.00580 0.0299 0.112 0.00418 Non-detect 0.0938 0.0167 Non-detect 0.0835 Non-detect Stripper Bottoms W astewater Stripper Bottoms W astewater **27**

02/13/13 Estimated 200 02/09/13 Suspension Suspension

02/13/13 41 39.2

13-042-0292 13-042-0293 Estimated 200 02/10/130.00049 Non-detect 0.00250 Non-detect

0.00138 Non-detect 0.00690 Non-detect 0.00044 Non-detect 0.00223 Non-detect 0.00067 Non-detect 0.00337 Non-detect NOT FOUND Non-detect NOT FOUND Non-detect

0.406 1.12 0.00071 Non-detect 0.00906 0.0007 Non-detect 0.0007 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 169 4.11 1.69 0.0686 Non-detect 29.5 0.112 Non-detect 0.333 Non-detect 0.0379 Non-detect 0.00465 Non-detect 0.0120 Non-detect 0.0225 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.00287 Non-detect 0.0654 0.00291 Non-detect 0.0900 Estimated value 0.00580 Non-detect 0.139 Estimated value 0.0822 Estimated value 0.0835 Non-detect Stripper Bottoms W astewater 02/13/13 Suspension

Estimated **28**

13-042-0294 39.2 Estimated 200 02/11/13 **29**0.00250 Non-detect 0.00690 Non-detect 0.00223 Non-detect 0.00337 Non-detect NOT FOUND Non-detect

1.08 Estimated value 0.00358 Non-detect 0.0036 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 117 3.75 0.973 0.0686 Non-detect 27.3 0.112 Non-detect 0.337 Non-detect 0.0379 Non-detect 0.00465 Non-detect 0.0120 Non-detect 0.0225 Non-detect 0.00239 Non-detect 0.00232 Non-detect 0.00545 Non-detect 0.0165 Non-detect 0.00287 Non-detect 0.00625 Non-detect 0.00291 Non-detect 0.0535 0.00580 Non-detect 0.0604 0.0209 Non-detect 0.0835 Non-detect Stripper Bottoms W astewater Suspension 02/12/13

37.4 02/18/13 Estimated

13-044-0236 200 **30**0.00250 Non-detect

0.00690 Non-detect 0.00223 Non-detect 0.00337 Non-detect NOT FOUND Non-detect

0.391 0.00358 Non-detect 0.0036 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 31**  **32 Concentration** 

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **33 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **35 34** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **36 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **37 38** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **39 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **41 40** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **42 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **43 44** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **45 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **47 46** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **48 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **49 50** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **51 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **53 52** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **54 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **55 56** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **57 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **58 59** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) 60**