p. 1



# RCRA Box 1883 Prepped by Ollie Stewart



### Document

Number: 

# 92 ) ll-B-25 4

Docket Number: 

# A-90-1 9

Printed 12/3/200810:42:16

AM Sheet 92 of 171P. 2

» • i r 

# A-90-1 9 M-B2B 4 

# RADIA N
CORPORATIO N MEMORANDU

M

TO : Le s Evans . EPA/CP B <^0
FROM : Thoma s Olsen , Radia nCorporatio

n
DATE : Septembe r 17 , 199 1 , ,.«

_AI « DQC K 

### SUBJECT : Developmen t o f Mode l Emissio nSourc e Characteristics " fo r SOCM I Proces s Vent s

1. 0 INTRODUCTIO

N T o asses s th

e nationa l impact s o f th e Hazardou s Organi c NESHA P (HON ) regulator

y option s fo

r proces s ven t ai r emission s fro m Syntheti c Organi c Chemica l Manufacturin g Industr

y (SOCMI ) facilities , th

e impact s o f th

e option s o

nal l SOCM I facilitie s woul d ideall y

be examined . However , becaus e th e detailed informatio

nfo r suc ha nassessmen t wa s no t availabl e fo r eac h facilit y inth e country , baseline emission s an d nationa l impact s wer e estimated usin g mode l proces s ven t stream s t o approximat e th e proces s ven t stream s fro m differen t productio nprocesse s foun d a t SOCM I facilities . Mode l proces s ven t stream s wer e develope

d t o represent th

e broa d range o f productio nprocesse s a s wel l a s th e range o f emission s commo

ni nth e industry . Existin g dat a fro

m previou s Ne w Sourc e Performanc e Standard s (NSPS ) fo r th e SOCM I wer e reviewe d t o develo

p th e characteristic s fo r mode l proces s vent streams . The procedur e use

d t o develo

p thes e ven t strea

m characteristic s i s describe d inth e followin

g sections . Sectio n2. 0 discusse s ho

w th e dat a wer e gathered , an d th e developmen t o f th

e model s i s discusse d inSectio

n3.0 . Example s o f th e mode l developmen t procedur e ar e presente d inAppendice s A , B , an d C .

MESC(HTN03)(LS )

Progres s Center/320 0 E

. Chape l Hil l Rd./Nelso n Hwy./P.O

. Bo x 13000/Researc h Triangl e Park , N.C

. 27709/(919)541-910 0P. 3



### 2. 0 DAT

A GATHERIN

G Durin g the mi d 1980s , NSP S wer e develope d fo r proces s ven t emission s fro

m SOCM I distillatio

noperations , reacto r processes , an d ai r oxidatio

nprocesses . For eac hstandard , a Backgroun d Informatio

nDocumen t (BID ) wa s develope d tha t characterized th e ven t stream

s associate

d wit heac

hproces s ven t type , interm s o f flo w rate , hea t content , an d VOC concentratio

no f eac

hstream . Thes e ven t strea

m characteristic s wer e developed fro m informatio

n gathered unde r th

e authority

o f Sectio

n11 4 o f th

e Clea nAi r Ac t
an d focuse

d o nemission s o f VOCs . For mode l development , th e dat a presented inthe NSP S BID' S
wer e use

d t o develo

p thre e dat a base s — one for eac

hrespectiv

e ven t type . The informatio nstore d inthes e dat a base s i s described inTabl e 2-1 . For mos t streams , th e distillatio

nan d reactor BID' S contai ndat a fo r proces s capacity , volumetri c flo w rate , hea t content , strea m temperature , oxyge ncontent , an

d VO C
mas s flo

w rate . The Idea l Ga s La w wa s use

d t o calculat e th

e tota l strea

m mas s flo

w rate . Th

e tota l strea

m mas s flo

w rat e wa s use d t o calculat e VOC weigh t percen t a s follows :
VO C weigh t Percent = VO C Mas s Flo w Rat e (lb/yr ) Tota l Strea

m Mas s Flo

w Rat e (lb/yr )

The ai r oxidatio

nNSP S BI D onl y

provided informatio no n strea m flo w rate , VOC mas s flo w rate , an

d hea t content . A separat e summar

y o f th e origina l Sectio

n11 4 questionnair e dat a an d the actua l response s ' wer e use d t o identify

proces s capacity , strea

m temperature , an

d oxyge ncontent . The Idea l Ga s La w wa s als o use

d t o calculat e th

e tota l strea

m mas s flo

w rat e fo r ai r oxidatio

nstreams . Informatio

no nHA P conten t wa s no t provided inth e NSP S BID's , s o th

e Sectio

n11 4 questionnaire s use d t o develo

p th e BID' S wer e examined . For reactor an d distillatio

nvents , speciated ven t strea m compositio

nwa s provided ina summar y o f th e Sectio

n11 4 responses. 1 6 

### The overal l HA P emissio

nrat e fo

r

MESC(HTM03)(LS ) 2P. 4

TABL E 2-1 . PROCES S VENT S MODE L STREA M CHARACTERISTIC S

1 ) Mode l strea

m name 2 ) Reactio ntyp e (i f applicable )
3 ) Proces s capacit y correspondin g t o th e mode l strea m (1,000,00 0 kg )
4 ) Numbe r o f distillatio ncolumn s (i f applicable )
5 ) Colum

noperatin g condition s (i f applicable )
6 ) Mode l strea

m flo w rat e (scfm )
7 ) Mode l strea

m hea t conten t (Btu/scf ) 8 ) Mode l strea

m temperatur e (°F ) 9 ) Mode l strea

m oxyge nconten t (volum e percent )
10 ) Mode l strea

m VO C compositio n(weigh t percent )
11 ) Mode l strea

m HA P compositio n(weigh t percent )
12 ) Annua l VO C emissio nrat e (kg/yr ) 13 ) Annua l HA P emissio nrat e (kg/yr )

MESC(HTM03)(LS )P. 5



### eac hstrea m wa s estimate

d b y summin g th e emissio

nrate s o f eac

h HA P compoun

d reporte

d fo r th e ven t stream . Strea m compositio

ninformatio

ninth e ai r oxidatio

n Sectio n11 4 questionnair e summar y wa s presente

d interm

s o f fee

d stock , product , an

d othe r VOCs . For example , a strea m migh t b

e 2 percen t unreacted fee d stock , 5 percen t product , an d 2 percen t othe r VOC s wit hth e balanc e bein

g oxygen , nitrogen , water , carbo nmonoxide (CO) , an d carbo ndioxide (CO2) . The idea l chemica l reactio

nequatio

nwa s use

d t o provide som

e indicatio

no f wha t percen t o f "other VOC " wa s als o HAP . The mas s flo w rat e o f HAP' s wa s estimate

d b y addin g th e flo w rat e o f "othe r VOCs " t o th e flo w rate s fo

r th e fee d stock (i f i t wa s a HAP ) an d produc t (i f i t wa s a HAP) . Fo r reactor , distillation , an d ai r oxidatio

nven t streams , strea m HA P weigh t percentag e wa s calculate d a s follows : HA P Mas s Flo

w Rat e
_HA

P Weight Percent VOC Mas s Flo

w Rat e VO C Weight Percent

or

HA P Weigh t Percent = ("* * i_ as s 

### ^ o w 

### j^ 6 

### ) * vo c 

### Weight Percent \VO C Mas s Flo

w Rate /

For som e streams , HA

P weigh t percentag e coul d no t be derive d fro m th e availabl e data . For thes e streams , th e followin

g equatio

n wa s used :

weight = WeTgh t * (Average HA P Weight Percent j Percen t Percent \Average VOC Weight Percent /

wher e the averag e HA P an d VOC weigh t percentage s wer e calculate d
a s th e meano f th

e value s fo

r al l stream

s fo r whichHA

P dat a wer e available . The HA

P mas s flo

w rat e wa s calculate d a s follows: 1 0

MESC(HTM03)(LS )

### HA P VOC Hassno w

= Mas s Flo

w * ( "g Wei 

### ? h t 

### Percent \ Rat e Rat e \VO C Weight Percent /

Som e stream

s i nth e NSP S BID' S lacke

d dat a for strea

m temperatur e or strea m oxyge ncontent . Whe

nsuc hdat a wer e no t availabl e fro

m th e Sectio

n11 4 responses , averag e value s wer e used . Thes e averag e value s wer e calculate d a s th e meano f th

e value s fo

r al l stream

s fo r whichth

e dat a wer e available . 3. 0 MODE L DEVELOPMEN T Th e proces s ven t dat a base s develope d fo r the HO

N wer e use

d t o generat e mode l stream s t o characteriz e uncontrolled emissio n stream s or emissio

nstream

s locate

d upstrea

m o f combustio

n devices . The model s represen t ven t stream s fro m reacto r processes , distillatio noperations , or ai r oxidatio nprocesses . Mode l strea

m characteristic s wer e develope d fo r eac hven t type fo r specifi c productio nprocesse s an

d fo r genera l proces s types . The productio

nprocess-specifi c streams , or Type A models , represen t a

nactua l productio

nprocess , a s described i nth e SOCM I NSP S BID'S . The generi c mode l streams , o r Type B models , represen t a genera l classificatio no f th e productio

nprocesse s fo r whichspecifi c informatio nwa s no t presented inth e SOCM I NSP S BID'S , suc

ha s a mode l fo

r a proces s usin

g a halogenatio

n reaction . 3. 1 Type A

Uncontrolled Model s The complete

d dat a base s wer e use d t o generat e th

e Type A mode l stream

s for th

e specifi c productio nprocesse s identifie d i n eac hNSP S BID . I f onl y a singl e strea

m wa s identifie

d fo r a particula r productio nprocess , it s characteristic s wer e designated a s th

e model . I f multipl e stream s wer e identifie

d fo r a particula r productio nprocess , thena singl e se t o f ven t strea m characteristic s wer e developed base d o nmediancharacteristics , weightin

g b y capacity , or weightin g b y flo w rate . Example s o f

MESC(HTM03)(LS )P. 7



### th e mode l developmen t procedur e ar e presente d i nAppendice s A , B , an d C . Th e ven t strea

m characteristic s fo r eac hType A

productio

n proces s wer e derive d fro m dat a o nal l existin

g productio

nproces s stream s presented i

nth e NSP S BID'S . The percen t oxygen represent s th

e medianoxyge

nvalue . The strea m temperatur e represent s th

e mediantemperatur e value . The mode l capacity

represent s th

e mediano f al l th

e capacitie s associate d wit hven t stream s fo r tha t productio

n process . Fo r example , dat a wer e availabl e for fiv e reacto r ven t stream s fro m th e productio

no f cumen

e b y alkylation . Afte r sortin g th e stream

s fro m lowes t t o highes t capacity , th e capacity o f the thir

d strea m woul d b

e th e mediancapacity

and , therefore , th e capacity

fo r th e mode l fo

r tha t productio

nprocess . Mode l flo

w rat e wa s calculate d a s presented inth e followin

g equation :

Mode l Flo

w Rat e = MedianCapacit y m 

### g plo w

Rat e 

## S i= l 2 Capacit

y i= l
wher e mediancapacity i s fo r strea m i= l throug

hN . The numbe r o f columns , VO C emissions , an d HA P emission s wer e calculate d wit h th e sam e approach , b

y replacin

g th e su m o f th e flo w rate s wit h th e su m o f th e respectiv

e characteristics . Mode l hea t conten t an d VOC weigh t percen t wer e calculate d a s weighted average s base d o nflo w rate . The mode l hea t conten t wa s calculated a s show

ninth e followin

g equation :
Mode l Hea t Conten t = S ( < Hea t 

### Content) ! * (Flo w Rate)i ^ i= l N

E Flo w Rat e i- l

MESC(HTM03)(LS )P. 8



### A simila r calculatio nwa s use

d t o calculat e th

e weigh t percen t VO C an d the weigh t percen t HAP . The weigh t percen t VO C wa s calculate

d a s shown : Weigh t Percent VO C = E I & ei 

### 3 ht 

### Percent VOC ) i * (Flo w Rate)i ^ i= l N

E Flo w Rat e i= l

Mode l ven t strea

m characteristic s fo r ai r oxidatio

n processe s ar e presented inTabl e 2- 2 an d distillatio

noperatio

n mode l ven t strea

m characteristic s ar e presented i nTabl e 2-3 . Becaus e occasionall y a chemica l i s manufactured usin g bot ha

n atmospheri c distillatio ncolum nan d a vacuu

m distillatio

ncolumn , dat a for the characteristic s o f bot htype s o f stream s wer e combine d t o represen t a singl e distillatio noperation . I n addition , the numbe r o f operatin g column s fo

r eachmode l wa s developed t o estimat e impact s pe r operatin g column . The developed mode l ven t strea m represent s on

e combine

d ven t strea

m fo r al l distillatio

ncolumn s use

d inth e process . The specifi c mode l ven t strea m characteristic s fo r reactor processe s ar e show

ninTabl e 2-4 . For reactor processes , th e productio

nproces s fo

r th e mode l i s specifi c t o th e actua l reactio ntype fo

r eac hproduct . For example , tw o set s o f mode l
ven t strea

m characteristic s wer e develope d fo r linear alkylbenzene . The firs t mode l ven t strea m represent s th

e neutralizatio

nreaction , an

d th e secon d mode l ven t strea

m represent s th

e alkylatio

nreaction . 3. 2 Type B Uncontrolled Model s Type B models , or generi c models , wer e developed t o represen t productio nprocesse s wit hn o specifie

d strea m informatio

ninthe SOCM I NSP S BID'S . The Type B mode l stream s wer e developed usin g th e sam e approachpresented inSectio n3. 1 fo r developmen t o f Type A models . However , th e strea m

NESC(HTM03)(LS )TABL E 2-2 . Categor y A Ai r Oxidatio nEmissio nMode l Ven t Stream s

HA P Produc t Proces s Productio n Capacit y (Cg/yr )

Acetaldehyd e Acrylonitril e Ethylen e Oxid e Formaldehyd e Malei c Anhydrid e Phthali c Anhydrid e Terephthali c Aci d Acetaldehyd e vi a ethano l Acrylonitril e fro

m aaaoni a t propylen e Ethylen e Oxid e vi a direc t oxidatio n Formaldehyd e Malei c Anhydrid e vi a oxidatio no f benzen e Phthali c Anhydrid e Terephthali c Aci d 54.2 0 99.7 9 63.5 0 16.7 8 18.1 4 40.8 2 209.1 0 Strea m Characteristic s

Hea t Tem

pOxyge nTota l VO C VO C HAP MA P Flowrat e Conten t Conten t EM . Rat e Compositio nEm . Rat e Cofrpo«iti < (scfm ) (Btu/scf ) (F ) (vo l X ) (Mg/yr ) (wtX ) (Mg/yr ) (MtX )

9923.3 7 56968.1 4 27243.8 0 5023.0 0 35974.8 7 61046.0 6 46279.6 5 16.2 6

25.9 2 5.9 1 1.3 7 10.1 0 2.9 8 7.5 9 52.0 0 111.5 0 270.0 0 95.0 0 100.0 0 113.0 0 92.0 0 0.9 5

4.4 9 4.3 0 6.0 7 13.2 9 12.4 0 5.3 2 60.9 6 12389.0 6 1775.7 4 239.4 4 1719.5 5 2467.4 4 1168.1 4 0.0 3

0.6 5 0.0 7 0.0 8 0.2 7 2.7 7 0.1 8 60.0 1

2569.7 0 1772.3 4 215.0 9 1681.2 3 1811.5 5 114.9 0 0.0 3

0.1 2 0.0 7 0.0 7 0.2 6 2.5 8 0.0 3

ts:s-::sc : SS£E::::SS :
0 9

T J C OTABL E 2-3 . Categor y A Distillatio nEmissio nMode l Ven t Stream s

\o Produc t

-._-----_-..--_-=_...--_
_
Aceti c Aci d Adiponitril e Allyl Alcoho l Ally l Chloride Anilin e Butadiene Caprolactu

m CarbonDisulfide CarbonTetrachlorid e Chlorobenzene Chlorodifluoromethan e Cumen e Cyclohexane CycIohexanone/cyc I ohexan e Dichlorodifluoromethane Dimethy l Terephthalat e Ethanolamine s Ethyl Acrylat e Ethylacetat e Ethylbenzene Ethylene Glyco l Formaldehyd

e Mesity l Oxid e Methano l Methy l Ethy

l Keton e Methy l Methacrylat e Nitrobenzen

e Number

o f Column s

========= =

7 9 3 2 2 3 7 2 3 1 6 4 1 8 2 2 3 4 5 2 3 1 1 1 2 3 1 Distillatio n Typ e

:-----__-----_ :

N V V N V NV/V V N V V/N V N V N V N V N V N V N V V N V NV/ V V/N V V N V V/N V V/N V V/N V N V N V N V V/NV . V Productio n Capacity (Gg/yr )
:_______.=_-

258.5 5 168.2 8 168.2 8 24.9 5 168.2 8 168.2 8 163.5 2 27.2 2 40.8 2 4.0 8 168.2 8 204.1 2 16.3 3 140.6 1 168.2 8 124.6 7 '6.8 0 40.8 2 20.4 1 158.9 8 115.6 7 83.9 1 168.2 8 29.4 8 41.9 6 119.2 9 168.2 8 Flowrat e

(scfm )

========== =

358.1 8 75.0 0 0.0 0 0.0 0 0.0 3 6.2 2 0.0 0 0.0 0 0.0 0 8.1 9 0.0 0 0.0 0 0.0 0 38.5 5 0.0 0 61.7 4 11.9 0 246.2 0 1.5 0 2.9 4 25.8 1 1.1 9 0.0 0 74.2 1 3.5 5 155.8 2 1.5 0 Strea

m Characteristic s

Heat Conten t (Btu/scf )

=========== =

344.0 1 0.0 0 0.0 0 0.0 0 3229.7 8 1453.0 0 0.0 0 0.0 0 0.0 0 395.8 1 0.0 0 0.0 0 0.0 0 58.5 9 0.0 0 2181.3 7 0.0 0 47.6 5 934.5 3 321.9 7 0.0 0 9.0 0 0.0 0 1175.7 2 1748.9 2 220.6 6 352.0 0 Tem

p (F )

======= =

110.8 0 89.1 7 110.8 0 99.9 8 89.1 7 110.8 0 99.9 8 110.8 0 110.8 0 89.1 7 110.8 0 110.8 0 110.8 0 89.1 7 110.8 0 99.9 8 99.9 8 89.1 7 110.8 0 110.8 0 100.0 0 99.9 8 110.8 0 110.8 0 110.8 0 110.8 0 89.1 7 Oxygen Content (vo l X )

======= =

2.5 0 0.0 0 0.0 0 0.0 0 0.7 4 0.0 0 0.0 0 0.0 0 0.0 0 12.5 4 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 7.8 2 10.5 0 4.9 7 4.4 9 0.0 0 0.0 0 0.0 0 0.0 0 6.2 5 3.0 2 14.9 4 1.1 0 Tota l VO

C Em . Rat e (Mg/yr ) :-__-=_=== =

1411.6 9 0.0 0 0.0 0 0.0 0 1.5 9 110.4 0 0.0 0 0.0 0 0.0 0 49.6 0 0.0 0 0.0 0 0.0 0 69.2 1 0.0 0 900.0 5 0.0 0 1826.2 0 13.5 1 1.3 3 0.0 0 0.3 0 0.0 0 1923.9 5 84.7 9 1847.0 4 7.1 5 VO

C Compositio

n (w t X )

=========== =

10.9 3 0.0 0 0.0 0 0.0 0 87.0 4 50.4 0 0.0 0 0.0 0 0.0 0 10.8 9 0.0 0 0.0 0 0.0 0 2.0 0 0.0 0 66.2 4 0.0 0 1.6 2 25.6 6 0.9 3 0.0 0 1.3 0 0.0 0 96.3 9 59.3 0 35.5 1 .9.6 0 HA

P Em . Rat e (Mg/yr )

========= =

180.3 3 0.0 0 0.0 0 0.0 0 1.5 9 110.4 0 0.0 0 0.0 0 0.0 0 49.6 0 0.0 0 0.0 0 0.0 0 45.5 3 0.0 0 290.1 0 0.0 0 20.5 4 13.5 1 1.3 3 0.0 0 0.3 0 0.0 0 116.4 6 19.8 7 1523.3 7 7.1 5 HA

P Compo s i t i o n (wt X )
==:.::sxss r

1.4 0 0.0 0 0.0 0 0.0 0 87.0 4 50.4 0 0.0 0 0.0 0 0.0 0 10.8 9 0.0 0 0.0 0 0.0 0 1.7 4 0.0 0 22.2 0 0.0 0 0.8 3 25.6 6 0.9 3 0.0 0 1.3 0 0.0 0 22.7 3 12.3 0 34.7 2 9.6 0TABL E 2-3 . Categor y A Distillatio nEmissio nMode l Ven t Stream s

Produc t

-...-_-.-_._-__--______ -
Perchloroethylene Pheno l Styrene Terephthali c Aci d Trichloroethane Trichloroethylene Trichlorofluoromethane Viny l Acetat e Vinylchloride H O Number o f Column s

... .
2 1 2 2 6 3 1 4 3 ====== = Distillation

Type

============= =

NV/ V NV/ V NV/ V N V N V N V N V NV/ V N V Productio n Capacity (Gg/yr )

=========== =

45.3 6 56.2 5 220.2 2 168.2 8 158.7 6 92.9 9 168.2 8 161.2 5 181.4 4 Flowrat e

(scfm )

========== =

2.2 7 0.0 0 0.0 0 1.2 6 0.0 0 0.0 0 0.0 0 10.9 4 0.0 0 Strea

m Characteristic s

Heat Content (Btu/scf )

=========== =

17.9 5 0.0 0 0.0 0 114.4 4 0.0 0 0.0 0 0.0 0 450.5 5 0.0 0 Tem

p (F )
:_.__=_. =

110.8 0 110.8 0 110.8 0 110.8 0 110.8 0 110.8 0 110.8 0 110.8 0 110.8 0 Oxygen Content (vo l X ) Tota l VO

C Em . Rat e (Mg/yr )

========== =

0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 ====== =

3.3 4 0.0 0 0.0 0 3.8 1 0.0 0 0.0 0 0.0 0 72.9 9 0.0 0 VO

C Compositio

n (w t X )
:=I&3C1BSSS :

2.0 0 0.0 0 0.0 0 6.5 9 0.0 0 0.0 0 0.0 0 30.9 3 0.0 0 HA

P Em . Rat e (Mg/yr ) :3xsisssss :

3.3 4 0.0 0 0.0 0 3.8 1 0.0 0 0.0 0 0.0 0 72.9 9 0.0 0 HA

P Compositio

n (w t X )

2.0 0 0.0 0 0.0 0 6.5 9 0.0 0 0.0 0 0.0 0 30.9 3 0.0 0

B3SCSSSSSSSS STABL E 2-4
. Categor y A Reacto r Ven t Mode l Emissio n Stream s

Produc t

_c__.-s--r--s-_--.-___ : Adiponitril e Ally l Chlorid

e Anilin e Benzene Bispheno l - A Caprolacta

m CarbonDisulfide Chlorobenzene Cumen e Cyclohexan e Dimethy l Terephthalat e Dinitrotoluene Dinitrotoluene Ethanolamine s Ethy l Chlorid

e Ethy l Chloride Ethylbenzene Ethylene Dichlorid

e Ethylene Glyco l Ethylene Glyco l Mono Freon Freo n Freo n11.12.113,11 4 Freo n- 1 2 Linea r Alkylbenzen

e Methy l Chlorid

e Methy l Ethy

l Keton e MTB E Reaction Type

-_=.___----.---__-_- : Hydrodimerizatio

n Chlorinatio

n Hydrogenatio

n Catalyti c Reformin

g Condensatio

n Aaninatio

n Sulfurizatio

n Chlorinatio

n Alkylatio

n Hydrogenatio

n Esterificatio

n Nitratio

n Nitratio

n AiMony t isi s HydrochIo

r i nat i o

n Hydrochtorinatio

n Alkylatio

n Chlorinatio

n Hydratio

n Esterificatio

n Fluorinatio

n Fluorinatio

n Fluorinatio

n Fluorinatio

n Alkylatio

n HydrochIo

r i nat i o

n Dehydrogenatio

n Ether ificat io

n Productio

n Capacit y (Gg/yr ) :--..-_-_..
_ 81.6 5 113.4 0 68.0 4 29.4 8 68.0 4 127.0 1 131.9 1 33.1 1 204.1 2 0.7 3 131.9 1 39.9 2 39.9 2 37.4 2 45.3 6 45.3 6 440.4 4 136.0 8 ' 83.0 1 131.9 1 131.9 1 131.9 1 131.9 1 131.9 1 131.9 1 36.2 9 66.2 2 131.9 1 Flowrat e

(scfm )

========== = 1080.0 0 0.0 0 0.0 0 1289.0 0 0.0 0 0.0 0 0.0 0 55.0 0 0.0 0 0.0 0 0.0 0 822.0 0 822.0 0 0.0 0 2.5 9 2.5 9 12.8 5 113.7 6 0.0 0 8.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 20.0 0 0.0 0 0.0 0 Strea

m Characteristc s

Heat Content (Btu/scf )
=...__..-- - 70.0 0 0.0 0 0.0 0 205.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 1286.0 0 1286.0 0 121.0 8 752.5 3 0.0 0 102.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 500.0 0 0.0 0 0.0 0 Tem

p (F )

--__-. - 74.7 6 68.0 0 68.0 0 74.7 6 68.0 0 68.0 0 68.0 0 74.7 6 68.0 0 68.0 0 68.0 0 74.7 6 74.7 6 74.0 0 68.0 0 68.0 0 87.3 8 74.7 6 68.0 0 74.7 6 68.0 0 68.0 0 68.0 0 68.0 0 68.0 0 74.7 6 68.0 0 68.0 0 Oxyge

n Conten t (vo l X )
--.._-- ; 0.1 8 0.0 0 0.0 0 0.1 8 0.0 0 O.O O 0.0 0 0.1 8 0.0 0 0.0 0 0.0 0 0.1 8 0.1 8 0.0 0 0.0 0 0.0 0 0.1 8 0.1 8 0.0 0 0.1 8 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.1 8 0.0 0 0.0 0 Tota l VO

C Em . Rat e (Mg/yr ) :-._.._--- - 107.2 8 0.0 0 0.0 0 32.9 8 0.0 0 0.0 0 0.0 0 15.8 9 0.0 0 0.0 0 0.0 0 0.4 0 0.4 0 0.0 0 86.4 0 86.4 0 31.9 9 181.7 6 0.0 0 372.3 1 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 8.3 4 0.0 0 0.0 0 VO

C HA

P Compositio

nEm . Rat e (wtX )
-_--_--_--. : 13.5 4 0.0 0 0.0 0 13.5 4 0.0 0 0.0 0 0.0 0 13.5 4 0.0 0 0.0 0 0.0 0 13.5 4 13.5 4 10.6 0 13.5 4 13.5 4 17.8 1 13.5 4 0.0 0 13.5 4 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 13.5 4 0.0 0 0.0 0 (Mg/yr ) HA P Compositio

n (wtX )

13.2 1 0.0 0 0.0 0 13.2 1 0.0 0 0.0 0 0.0 0 13.2 1 0.0 0 0.0 0 0.0 0 0.4 0 0.4 0 0.0 0 1.7 1 1.7 1 38.3 9 9.5 1 0.0 0 13.2 1 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 8.3 4 0.0 0 0.0 0 7.8 1

0.0 0 0.0 0 7.8 1 0.0 0 0.0 0 0.0 0 7.8 1 0.0 0 0.0 0 0.0 0 13.5 4 13.5 4 10.0 0 7.8 1 7.8 1 15.8 7 7.8 1 0.0 0 7.8 1 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 7.8 1 0.0 0 0.0 0 13.5 4 0.0 0 13.5 4 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 13.5 4 0.0 0 0.0 0 9.5 1

0.0 0 13.2 1 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 8.3 4 0.0 0 0.0 0 7.8 1

0.0 0 7.8 1 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 7.8 1 0.0 0 0.0 0TABL E 2-4 . Categor y A Reacto r Ven t Mode l Emissio nS t ream s

E:sss:esc===-r::ss::5= : issssssssrss :

Produc t

Nitrobenzene Nonylpheno l Phenol/Aceton

e Styrene Vinyl Acetat e Vinyliden

e Chloride Reaction Typ e

Nitration Alkylation Cleavag e Dehydrogena t io

n Oxyacetylatlo

n Dehydrochlorinatio

n Productio

n Capacity (Gg/yr )

55.7 9 27.2 2 226.7 9 149.6 8 180.5 3 34.0 2 Flowrat e

(scfm )

13.0 0 0.0 0 0.0 0 2891.0 0 7.0 0 10.0 0 Strea

m Characteristc s

Heat Content (Btu/scf )

434.0 0 0.0 0 0.0 0 281.9 9 407.0 0 600.0 0 Tem

p (F )

74.7 6 68.0 0 0.0 0 97.3 8 68.0 0 90.0 0 Oxyge

n Conten t (vo l X )

0.1 8 0.0 0 0.0 0 0.1 8 0.1 8 0.1 8 Tota l VOC Em . Rat e (Mg/yr )

75.5 0 0.0 0 0.0 0 1732.4 2 0.4 0 162.9 1 VO

C HA

P Compositio

nEm . Rat e (wtX )

23.1 9 0.0 0 0.0 0 18.4 2 12.5 0 0.0 0 (Mg/yr ) HA P Compositio

n (wtX )

75.5 0 0.0 0 0.0 0 326.4 7 0.2 0 162.9 1 23.1 9

0.0 0 0.0 0 13.2 6 6.2 5 0.0 0

Mtittscss:s:scexssss:s:s :

K JP.1 4

characteristic s wer e no t base d o nspecifi c productio nprocesses , bu t o na rang e o f processe s wit hsimila r reactio ntype s o r distillatio ncolum noperatin g characteristics . Tabl e 2- 5 list s th e 2 2 Typ e B mode l ven t streams . A singl e Typ e B mode l strea m wa s develope d fo r ai r oxidatio nprocesses . Al l ai r oxidatio nven t stream s wer e considere d i ndevelopin g thi s mode l stream . Fo r ven t stream s fro m distillatio noperations , two Typ e B mode l ven t stream s wer e develope d — on e t o represen t atmospheri c operation s and on e t o represen t vacuu m operations . Fo r reacto r processes , Typ e B mode l stream s wer e develope d base d o nreactio ntype . Th e update d HON dat a bas e wa s reviewe d
and th e followin g reactio ntype s wer e selecte d fo r generatin g Typ e B mode l streams : (1 ) Alkylation(10 ) Hydroformylatio n (2 ) Carbonylatio n(11 ) Hydrogenation (3 ) Catalyti c Reformatio n(12 ) Hydrohalogenation (4 ) Condensatio n(13 ) Hydrolysi s (5 ) Dehydrogenatio n(14 ) Nitration (6 ) Dehydrohalogenatio n(15 ) Oxidation (7 ) Esterificatio n(16 ) Oxyacetylatio n (8 ) Halogenatio n(17 ) Oxyhalogenatio n (9 ) Hydrodimerizatio n(18 ) Sulfonatio n Th e dat a bas e entrie s wer e sorte d b y reactio ntype , and th e mode l developmen t approac houtline d i nSectio n3. 1 wa s use d t o generat e th e mode l ven t stream s fo r thes e 1 8 reactio nprocesses . A separat e generi c mode l strea m wa s develope d t o represen t reactio n type s tha t wer e no t include d i nth e 1 8 specifie d reactio ntype s liste d above . Th e mode l ven t strea m characteristic s fo r thi s "unspecifie d reaction " typ e wer e develope d usin g dat a fro m al l reacto r ven t stream s and th e approac houtline d i nSectio n3.1 .

cc : Projec t Fil e 6. 1 (M . Haley )

MESC(HTM03)US ) 1 3TABL E 2-5 . Categor

y B (Generic ) Proces s Mode l Ven t Stream

s

333333=38333333—83 3

Vent Typ e Proces s

Typ e Nuafce

r Distillatio

nProduction
of Type Capacity Colurn s (Gg/yr )
5383333383333=33333====== 3

A

D D Ai r Oxidation

DistillationN

V Distillatio

nV
Alkylation Carbonylation Catalyti c Reformin

g Condensation Dehydrogena t i o

n DehydrohaIogena t i on Esterification Generi c Reactio

n Halogenatio

n Hydrodimerizatio

n HydroformyI a

t i o n Hydrogenatio

n Hydrohalogenatio

n Hydrolysi s Nitratio

n Oxidatio

n Oxyacetylatlo

n Oxyhalogenatio

n Sulfonatio

n N

A

2 2

N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N

A

N V V

N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A N A 56.7 0

115.6 9 84.1 4

192.7 8 673.1 3 29.4 8 131.9 9 54.4 3 33.5 7 65.7 7 48.9 9 131.9 1 81.6 5 79.3 8 90.7 2 45.3 6 158.7 6 47.8 5 211.3 7 180.5 3 413.6 7 13.6 1 Strea m Characteristic s

Flowrat e (scfm )

17369.4 7

11.8 3 52.6 6

1.7 9 18950.0 0 1289.0 0 57.7 4 557.2 3 5.0 0 14.8 6 260.0 3 847.1 0 1080.0 0 729.0 0 849.5 2 4.2 0 99.0 0 417.5 0 5512.3 6 7.0 0 304.0 0 1863.0 0 Heat

Conten t (Btu/scf )

16.9 3

559.6 5 134.9 4

121.0 8 295.0 0 205.0 0 1069.0 0 282.7 7 600.0 0 102.0 0 208.6 3 36.6 8 70.0 0 1233.0 0 714.2 4 893.0 0 0.0 0 6.7 6 2.3 8 407.0 0 713.0 0 0.0 0 Oxygen

Tem p Content (F ) (vo l X ) Tota l VOC VO C Em . Rat e Compositio n (Mg/yr ) (w

t X ) HA

P HA

P Em . Rat e Compositio n (Mg/yr ) (w

t X )
:sssssssses8SsssEEsss:s i

90.0 0

89.1 7 99.9 9

68.0 0 74.7 6 74.7 6 68.0 0 68.0 0 79.0 0 74.7 6 68.0 0 68.0 0 74.7 6 74.7 6 71.5 0 68.0 0 60.0 0 75.0 0 90.0 0 68.0 0 74.7 6 74.7 6 6.0 7

0.0 0 0.0 0

0.0 0 0.1 8 0.1 8 0.0 0 0.0 0 0.0 9 0.1 8 0.0 0 0.0 0 0.1 8 0.1 8 0.0 0 0.0 0 0.1 8 0.1 8 0.0 0 0.1 8 0.1 8 0.1 8 1562.8 4

197.6 7 681.9 7

4.4 5 298.0 1 32.9 8 476.0 5 322.3 0 81.4 6 61.1 7 138.2 7 69.8 5 107.2 8 9512.4 4 1977.9 7 70.9 5 0.4 0 37.9 5 138.9 8 0.4 0 2972.1 4 0.4 0 1.3 4 826.3 2 0.8 0

52.2 4 9.5 3

17.8 1 0.5 0 13.5 4 13.5 4 17.7 5 0.0 0 16.0 9 8.3 8 13.5 4 13.5 4 13.5 4 10.6 4 13.5 4 13.5 4 13.6 9 8.0 5 12.5 0 13.5 4 13.5 4 60.9 1

134.0 4

4.4 5 0.0 0 13.2 1 5.1 9 60.6 0 81.4 6 5.8 1 4.6 0 5.7 5 13.2 1 13.2 1 4.8 4 2.2 6 0.4 0 37.9 5 3.5 5 0.2 0 13.2 1 0.4 0 24.6 0

5.0 0

17.8 1 0.0 0 7.8 1 7.8 1 12.7 7 0.0 0 14.3 8 5.2 1 7.8 1 7.8 1 7.8 1 6.1 4 10.6 7 7.8 1 13.6 9 4.6 5 6.2 5 7.8 1 13.5 4

Note : A = Ai r Oxidatio

nVen t Strea m D = Distillatio

nVen t Strea m R= Reacto

r Ven t Strea mP.1 6



### 4. 0 REFERENCE S

1

. Reacto r Processe s i n Syntheti c Organi c Chemica l Manufacturin g Industry- Backgroun d Informatio n fo r Propose d Standard

. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No
. EPA-450/3-90-016a

. Jun e 1990

. p . 3-1

. 2

. Ai r Oxidatio n Proces s i n Syntheti c Organi c Chemica l manufacturin g Industry- Background Informatio n fo r Propose d Standard

. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No
. EPA-450/3-82-001a

. Octobe r 1983

. 3

. Distillatio n Operation s i n Syntheti c Organi c Chemica l Manufacturin g Industry- Backgroun d Informatio n fo r Propose d Standard

. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No
. EPA-450/3-82-001a

. 4

. Draf t Memorandu m fro mOlsen , T. , Radia n Corporation , t o Evans , L. , CPB/EPA

. Septembe r 1 , 1991

. Dat a Use d i n HON Proces s Vent s Databas e Development

. 5

. Engineerin g an

d Cos t Stud

yo f Ai r Pollutio n Contro l fo r th e Petrochemica l Industry , Volum e 2 : Acrylonitril e Manufacture

. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No
. EPA-450/3-73/006-b

. February1975

. 6

. Engineerin g an

d Cos t Stud

yo f Ai r Pollutio n Contro l fo r th e Petrochemica l Industry , Volum e 3 : Ethylen e Dichlorid e Manufactur e b

yOxychlorination

. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No
. EPA-450/3-73/006-C

. Novembe r 1974

. 7

. Engineerin g an

d Cos t Stud

yo f Ai r Pollutio n Contro l fo r th e Petrochemica l Industry , Volum e 4 : Formaldehyd e Manufactur e wit h th e Silve r Catalys t Process
. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No
. EPA-450/3-73-006-d

. Marc h 1975

. 8

. Engineerin g an

d Cos t Stud

yo f Ai r Pollutio n Contro l fo r th e Petrochemica l Industry , Volum e 5 : Formaldehyd e Manufactur e wit h th e Mixe d Oxid e Catalys t Process
. U
. S
. Environmenta l Protectio n Agency
. Researc h Triangl e Park , NC
. Publicatio n No . EPA-450/3-73-006-e . Marc h1975 . 

### 9

. Engineerin g an

d Cos t Stud

yo f Ai r Pollutio n Contro l fo r th e Petrochemica l Industry , Volum e 6 : Ethylen e Oxid e Manufactur e b

yDirec t Oxidatio n o f Ethylene

. U
. S
.
MESC(HTM03)(LS ) 1 5P
. 1 7



### Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio

nNo . EPA-450/3-73-006-f . Jun e 1975 . 10 . Engineerin

g an d Cos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 7 : Phthali c Anhydride Manufactur e fro

m Ortho-Xylene . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-006-g . Jul y 1975 . 11 . Engineerin

g an d Cos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 8 : Viny l Chloride Manufactur e b

y th e Balance

d Process . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-006-h . Jul y 1975 . 12 . Surve

y Report s o

nAtmospheri c Emission s fro m the Petroleu

m Industry , Volum

e I . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio nNo . EPA 450/3-73-005-a . Januar y 1974 . 13 . Surve

y Report s o

nAtmospheri c Emission s fro m th e Petroleu

m Industry , Volum

e II . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-005-b . Apri l 1974 . 14 . Surve

y Report s o

nAtmospheri c Emission s fro m th e Petroleu

m Industry , Volum

e III . U . S . Environmenta l Protectio n Agency . ResearchTriangl e Park , NC . Publicatio nNo . EPA-450/3-73-005-C . Apri l 1974 . 15 . Surve

y Report s o

nAtmospheri c Emission s fro m th e Petroleu

m Industry , Volum

e IV . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-005-d . Apri l 1974 . 16 . I T Enviroscience . Emission s Contro l Option s fo r th e Syntheti c Organi c Chemical s Manufacturin g Industry . Prepare d fo r U . S . Environmenta l Protectio nAgency , OAQPS . Jul y 1980 , EP

A Contrac t Numbe r 68-02-2577 .

MESC(HTM03)(LS ) 1 6P.1 8



### APPENDI XA
EXAMPL E MODE L DEVELOPMEN T FO RDISTILLATIO

N PROCESS : ACETI C ACI D

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