### 13339 Hagers Ferry Road Hu n tersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report 

# Analytical Laboratory

Order Number: J13020159 Project Name: Wastewater Nietering

Lab C ont act: Jason C Perkins 

### Date: 2/26/2013 Cus t omer Address: 253 Plant Allen Road Customer Name(s): Bill K., Ron L., Don S., Ray L.

Belmont, NC 28012

Phone: 980- 875-5348 Report Authorized By: (Signature)


### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, An a lytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Jason C Perkins

## Sample ID's & Descriptions:

Sample ID Plant/Station Co l lection Date and Time Collected By Sample Description 2013003195 ALLE N 06-Feb-13 9:40 AM P. N, FGD Purge Eff 2013003196 ALLEN 06-Feb-13 9:12 AM P. N, EQ Tank Eff 2013003197 ALLEN 06-Feb-13 9:05 AM P. N, BioReactor 1 Inf 2013003198 ALLEN 06-Feb-13 9:50 AM P. N, BioReactor 1 Inf BLANK 2013003199 ALLEN 06-Feb-13 9:18 AM P. N, BioReactor 2 Inf 2013003200 ALLEN 06-Feb-13 10:00 AM P. N, BioReactor 2 Inf BLANK 2013003201 ALLEN 06-Feb-13 9:09 AM P. N, BioReactor 2 Eff 2013003202 ALLEN 06-Feb-13 9:55 AM P. N, BioReactor 2 Eff BLANK 2013003203 ALLEN 06-Feb-13 10:30 AM P. N, Filter Blk 9 Total Samples

### COC and .pdf report are in agreement with sample totals

a n d analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No



# Te c hnical Validation Review Checklist:

Yes No

Yes No



## R e port Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

Rev i ewed By: 

### DBA Account Date: 

### 2/26/2013 Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13020159

2013003195 Collection Date: 06-Feb-13 9:40 AM 

### Site: FGD Purge Eff M at rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F A L KALINITY - (Analysis Performed by Prism Labs) Vendor Parameter C o m plete Vendor Method V_PRISM
I N O RGANIC IONS BY IC Bromide 47 mg/ L E PA 300.0 02/15/2013 16:34 JAHERMA 10 100 Chl or ide 2700 mg/L EPA 300.0 02/15/2013 16:34 JAHERMA 100 1000 Sul f ate 2100 mg/L EPA 300.0 02/15/2013 16:34 JAHERMA 100 1000 ME R CURY (COLD VAPOR) IN WATER Mercury (Hg) 64.7 u g/ L EPA 245.1 02/14/2013 14:09 AGIBBS 2. 5 50 DI S SOLVED METALS BY ICP Manganese (Mn) < 0. 05 mg/L EPA 200.7 02/18/2013 11:13 MHH7131 0.05 10 TO TAL RECOVERABLE METALS BY ICP Boron (B) 281 mg/ L E PA 200.7 02/15/2013 13:51 DJSULL1 0. 5 10 Cal c ium (Ca) 2070 mg/L EPA 200.7 02/15/2013 13:51 DJSULL1 0. 1 10 Iron (Fe) 134 mg/L EPA 200.7 02/15/2013 13:51 DJSULL1 0. 1 10 Magnes i um (Mg) 1000 mg/L EPA 200.7 02/15/2013 13:51 DJSULL1 0.05 10 Manganes e (Mn) 7.60 mg/L EPA 200.7 02/15/2013 13:51 DJSULL1 0.05 10 DI S SOLVED METALS BY ICP-MS Selenium (Se) 314 ug/ L E PA 200.8 02/13/2013 11:06 KRICHAR 10 10 TO TAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 231 ug/ L E PA 200.8 02/13/2013 15:16 KRICHAR 10 10 Cadm i um (Cd) < 10 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 Chrom ium (Cr) 228 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 Copper (Cu) 180 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 Ni c kel (Ni) 263 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 Sel eni um (Se) 1390 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 Si l ver (Ag) < 10 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 Zi nc(Zn) 377 ug/L EPA 200.8 02/13/2013 15:16 KRICHAR 10 10 SE L ENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Co m plete Vendor Method V_AS&C TO TAL DISSOLVED SOLIDS TDS 100 00 m g/L SM2540C 02/13/2013 16:40 SWILLI3 200 1 TO TAL SUSPENDED SOLIDS TSS 2800 mg/ L S M2540D 02/14/2013 13:49 SWILLI3 250 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13020159

2013003196 Collection Date: 06-Feb-13 9:12 AM 

### Site: EQ Tank Eff M at rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F M E RCURY (COLD VAPOR) IN WATER Mercury (Hg) 47. 7 u g/ L EPA 245.1 02/14/2013 14:12 AGIBBS 2

. 5 50 D I S SOLVED METALS BY ICP Manganese (Mn) < 0. 05 mg/L EPA 200.7 02/18/2013 11:17 MHH7131 0.05 10 TO TAL RECOVERABLE METALS BY ICP Boron (B) 268 mg/ L E PA 200.7 02/15/2013 13:55 DJSULL1 0. 5 10 Cal c ium (Ca) 1850 mg/L EPA 200.7 02/15/2013 13:55 DJSULL1 0. 1 10 Iron (Fe) 106 mg/L EPA 200.7 02/15/2013 13:55 DJSULL1 0. 1 10 Magnes i um (Mg) 944 mg/L EPA 200.7 02/15/2013 13:55 DJSULL1 0.05 10 Manganes e (Mn) 5.73 mg/L EPA 200.7 02/15/2013 13:55 DJSULL1 0.05 10 DI S SOLVED METALS BY ICP-MS Selenium (Se) 277 ug/ L E PA 200.8 02/13/2013 11:09 KRICHAR 10 10 TO TAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 183 ug/ L E PA 200.8 02/13/2013 15:20 KRICHAR 10 10 Cadm i um (Cd) < 10 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10 Chrom ium (Cr) 190 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10 Copper (Cu) 154 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10 Ni c kel (Ni) 232 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10 Sel eni um (Se) 1220 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10 Si l ver (Ag) < 10 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10 Zi nc(Zn) 329 ug/L EPA 200.8 02/13/2013 15:20 KRICHAR 10 10


### 2013003197 Collection Date: 06-Feb-13 9:05 AM 

### Site: BioReactor 1 Inf Mat rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF A L KALINITY - (Analysis Performed by Prism Labs) Vendor Parameter Co m plete Vendor Method V_PRISM
ME R CURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND
ME R CURY 1631 - DISSOLVED - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND
DI S SOLVED METALS BY ICP Manganese (Mn) < 0. 05 mg/L EPA 200.7 02/18/2013 11:21 MHH7131 0.05 10

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13020159

2013003197 Collection Date: 06-Feb-13 9:05 AM 

### Site: BioReactor 1 Inf M at rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F T O TAL RECOVERABLE METALS BY ICP Boron (B) 235 m g/ L E PA 200.7 02/15/2013 13:59 DJSULL1 0

. 5 10 C al c ium (Ca) 1470 mg/L EPA 200.7 02/15/2013 13:59 DJSULL1 0

. 1 10 I ron (Fe) < 0.1 mg/L EPA 200.7 02/15/2013 13:59 DJSULL1 0

. 1 10 M agnes i um (Mg) 773 mg/L EPA 200.7 02/15/2013 13:59 DJSULL1 0.05 10 Manganes e (Mn) < 0.05 mg/L EPA 200.7 02/15/2013 13:59 DJSULL1 0.05 10 DI S SOLVED METALS BY ICP-MS Selenium (Se) 245 ug/ L E PA 200.8 02/13/2013 11:12 KRICHAR 10 10 TO TAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 u g/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Cadm i um (Cd) < 10 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Chrom ium (Cr) < 10 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Copper (Cu) < 10 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Ni c kel (Ni) < 10 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Sel eni um (Se) 303 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Si l ver (Ag) < 10 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 Zi nc(Zn) < 10 ug/L EPA 200.8 02/13/2013 15:23 KRICHAR 10 10 SE L ENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Co m plete Vendor Method V_AS&C


### 2013003198 Collection Date: 06-Feb-13 9:50 AM 

### Site: BioReactor 1 Inf BLANK Mat rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF M E RCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND
ME R CURY 1631 - DISSOLVED - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND


### 2013003199 Collection Date: 06-Feb-13 9:18 AM 

### Site: BioReactor 2 Inf Mat rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF A L KALINITY - (Analysis Performed by Prism Labs) Vendor Parameter Com plete Vendor Method V_PRISM

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13020159

2013003199 Collection Date: 06-Feb-13 9:18 AM 

### Site: BioReactor 2 Inf M at rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F M E RCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter C o m plete Vendor Method V_BRAND M E R CURY 1631 - DISSOLVED - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND
DI S SOLVED METALS BY ICP Manganese (Mn) < 0. 05 mg/L EPA 200.7 02/18/2013 11:25 MHH7131 0.05 10 TO TAL RECOVERABLE METALS BY ICP Boron (B) 251 mg/ L E PA 200.7 02/15/2013 14:03 DJSULL1 0. 5 10 Cal c ium (Ca) 1500 mg/L EPA 200.7 02/15/2013 14:03 DJSULL1 0. 1 10 Iron (Fe) < 0.1 mg/L EPA 200.7 02/15/2013 14:03 DJSULL1 0. 1 10 Magnes i um (Mg) 785 mg/L EPA 200.7 02/15/2013 14:03 DJSULL1 0.05 10 Manganes e (Mn) 0.050 mg/L EPA 200.7 02/15/2013 14:03 DJSULL1 0.05 10 DI S SOLVED METALS BY ICP-MS Selenium (Se) 218 ug/ L E PA 200.8 02/13/2013 11:16 KRICHAR 10 10 TO TAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 u g/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Cadm i um (Cd) < 10 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Chrom ium (Cr) < 10 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Copper (Cu) < 10 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Ni c kel (Ni) < 10 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Sel eni um (Se) 219 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Si l ver (Ag) < 10 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 Zi nc(Zn) < 10 ug/L EPA 200.8 02/13/2013 15:27 KRICHAR 10 10 SE L ENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Co m plete Vendor Method V_AS&C


### 2013003200 Collection Date: 06-Feb-13 10:00 AM 

### Site: BioReactor 2 Inf BLANK Mat rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF M E RCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND
ME R CURY 1631 - DISSOLVED - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Com plete Vendor Method V_BRAND

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13020159

2013003201 Collection Date: 06-Feb-13 9:09 AM 

### Site: BioReactor 2 Eff M at rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F A L KALINITY - (Analysis Performed by Prism Labs) Vendor Parameter C o m plete Vendor Method V_PRISM
I N O RGANIC IONS BY IC Bromide 96 mg/ L E PA 300.0 02/15/2013 16:53 JAHERMA 10 100 Chl or ide 3300 mg/L EPA 300.0 02/15/2013 16:53 JAHERMA 100 1000 Sul f ate 2100 mg/L EPA 300.0 02/15/2013 16:53 JAHERMA 100 1000 ME R CURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND ME R CURY 1631 - DISSOLVED - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND
DI S SOLVED METALS BY ICP Manganese (Mn) < 0. 05 mg/L EPA 200.7 02/18/2013 11:29 MHH7131 0.05 10 TO TAL RECOVERABLE METALS BY ICP Boron (B) 241 mg/ L E PA 200.7 02/15/2013 14:07 DJSULL1 0. 5 10 Cal c ium (Ca) 1590 mg/L EPA 200.7 02/15/2013 14:07 DJSULL1 0. 1 10 Iron (Fe) 0.131 mg/L EPA 200.7 02/15/2013 14:07 DJSULL1 0. 1 10 Magnes i um (Mg) 803 mg/L EPA 200.7 02/15/2013 14:07 DJSULL1 0.05 10 Manganes e (Mn) < 0.05 mg/L EPA 200.7 02/15/2013 14:07 DJSULL1 0.05 10 DI S SOLVED METALS BY ICP-MS Selenium (Se) 6.98 u g/ L EPA 200.8 02/13/2013 11:19 KRICHAR 5 5 TO TAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 5.47 u g/ L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Cadm i um (Cd) < 5 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Chrom ium (Cr) < 5 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Copper (Cu) < 5 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Ni c kel (Ni) < 5 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Sel eni um (Se) 11.1 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Si l ver (Ag) < 5 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 Zi nc(Zn) < 5 ug/L EPA 200.8 02/13/2013 15:30 KRICHAR 5 5 SE L ENIUM SPECIATION - (Analysis Performed by Applied Speciation and Consulting, LLC) Vendor Parameter Co m plete Vendor Method V_AS&C

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13020159

2013003202 Collection Date: 06-Feb-13 9:55 AM 

### Site: BioReactor 2 Eff BLANK M at rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F M E RCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter C o m plete Vendor Method V_BRAND M E R CURY 1631 - DISSOLVED - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Co m plete Vendor Method V_BRAND


### 2013003203 Collection Date: 06-Feb-13 10:30 AM 

### Site: Filter Blk Mat rix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF D I SSOLVED METALS BY ICP Manganese (Mn) < 0. 005 mg/L EPA 200.7 02/18/2013 11:02 MHH7131 0.005 1 DI S SOLVED METALS BY ICP-MS Selenium (Se) < 1 u g/L EPA 200.8 02/13/2013 10:50 KRICHAR 1 1

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 02/13/2013

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen WW - Nietering (January 2013-Test Burn) Project No.: J13020159 Lab Submittal Date: 02/08/2013 Prism Work Order: 3020187 VA Certification No. 1287 DoD ELAP Certification No. L2307



### Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference: 

### HT Sample received and analyzed outside of the hold time.

Method Detection Limit MDL Below Reporting Limit BRL
Relative Percent Difference RPD


## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 1 of 9

# Sample Receipt Summary 02/13/2013 

### Prism Work Order: 3020187 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 3020187-01 02/06/13 2013003195/FGD Purge Eff 02/08/13 Water 3020187-02 02/06/13 2013003197/BioReactor 1 Inf 02/08/13 Water 3020187-03 02/06/13 2013003199/BioReactor 2 Inf 02/08/13 Water 3020187-04 02/06/13 2013003201/BioReactor 2 Eff 02/08/13 Water Samples received in good condition at 1.1 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 2 of 9

# Laboratory Report 02/13/2013

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen WW - Nietering (January 2013-Test Burn) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 3020187-01 Prism Work Order: 3020187 Time Collected: 02/06/13 09:40 Time Submitted: 02/08/13 08:55 2013003195/FGD Purge Eff


### J13020159

General Chemistry Parameters 6.6 *SM4500-H B P3B0186 1 2/11/13 11:45 JAB HT pH Units pH 34 *SM2320 B P3B0188 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Total Alkalinity BRL *SM2320 B P3B0189 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Carbonate Alkalinity 34 *SM2320 B P3B0190 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 3 of 9

# Laboratory Report 02/13/2013

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen WW - Nietering (January 2013-Test Burn) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 3020187-02 Prism Work Order: 3020187 Time Collected: 02/06/13 09:05 Time Submitted: 02/08/13 08:55 2013003197/BioReactor 1 Inf


### J13020159

General Chemistry Parameters 7.4 *SM4500-H B P3B0186 1 2/11/13 11:45 JAB HT pH Units pH 69 *SM2320 B P3B0188 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Total Alkalinity BRL *SM2320 B P3B0189 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Carbonate Alkalinity 69 *SM2320 B P3B0190 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 4 of 9

# Laboratory Report 02/13/2013

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen WW - Nietering (January 2013-Test Burn) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 3020187-03 Prism Work Order: 3020187 Time Collected: 02/06/13 09:18 Time Submitted: 02/08/13 08:55 2013003199/BioReactor 2 Inf


### J13020159

General Chemistry Parameters 7.5 *SM4500-H B P3B0186 1 2/11/13 11:45 JAB HT pH Units pH 300 *SM2320 B P3B0188 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Total Alkalinity BRL *SM2320 B P3B0189 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Carbonate Alkalinity 300 *SM2320 B P3B0190 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 5 of 9

# Laboratory Report 02/13/2013

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen WW - Nietering (January 2013-Test Burn) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 3020187-04 Prism Work Order: 3020187 Time Collected: 02/06/13 09:09 Time Submitted: 02/08/13 08:55 2013003201/BioReactor 2 Eff


### J13020159

General Chemistry Parameters 7.5 *SM4500-H B P3B0186 1 2/11/13 11:45 JAB HT pH Units pH 220 *SM2320 B P3B0188 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Total Alkalinity BRL *SM2320 B P3B0189 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Carbonate Alkalinity 220 *SM2320 B P3B0190 1 5.0 2/11/13 12:45 JAB mg/L 0.59 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 6 of 92/13/13 

### Level II QC Report

13339 Hagers Ferry Road Project No: J13020159 Project: Allen WW - Nietering (January 2013-Test Burn) Duke Energy Corporation
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 3020187 Time Submitted: 2/8/2013 8:55:00AM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control

Batch P3B0186 - NO PREP LCS (P3B0186-BS1) Prepared & Analyzed: 02/11/13 pH pH Units 6.93 6.880 99-101 101 Batch P3B0188 - NO PREP Blank (P3B0188-BLK1) Prepared & Analyzed: 02/11/13 Total Alkalinity mg/L BRL 5.0 LCS (P3B0188-BS1) Prepared & Analyzed: 02/11/13 Total Alkalinity mg/L 251 5.0 250.0 90-110 100 LCS Dup (P3B0188-BSD1) Prepared & Analyzed: 02/11/13 Total Alkalinity mg/L 260 5.0 250.0 200 90-110 104 4 Batch P3B0189 - NO PREP Blank (P3B0189-BLK1) Prepared & Analyzed: 02/11/13 Carbonate Alkalinity mg/L BRL 5.0 Batch P3B0190 - NO PREP Blank (P3B0190-BLK1) Prepared & Analyzed: 02/11/13 Bicarbonate Alkalinity mg/L BRL 5.0 LCS (P3B0190-BS1) Prepared & Analyzed: 02/11/13 Bicarbonate Alkalinity mg/L 251 5.0 250.0 90-110 100

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 7 of 92/13/13 

### Level II QC Report

13339 Hagers Ferry Road Project No: J13020159 Project: Allen WW - Nietering (January 2013-Test Burn) Duke Energy Corporation
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 3020187 Time Submitted: 2/8/2013 8:55:00AM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control

Batch P3B0190 - NO PREP LCS Dup (P3B0190-BSD1) Prepared & Analyzed: 02/11/13 Bicarbonate Alkalinity mg/L 260 5.0 250.0 200 90-110 104 4

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 8 of 9

### Page 9 of 9

## February 21, 2013

Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5245 Project: Allen Wastewater - Nietering (January 2013 - Test Burn) (LIMS #J13020159)

Dear Mr. Perkins, Attached is the report associated with four (4 ) aqueous samples submitted for selenium speciationon February 7, 2013. The samples were received in a sealed cooler at- 0. 3 ° C on February 8, 2013. Selenium speciation analysis was performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS). Any issues associated with the analysis are addressed in the following report. If you have any questions, please feel free to contact me at your convenience.
Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

## Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 Project: Allen Wastewater - Nietering (January 2013 - Test Burn) (LIMS #J13020159)

February 21 , 2013

1. Sample Reception Four (4 ) aqueous samples in125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for selenium speciation analysis on February 7, 2013. The sampl es were received on February 8, 2013 in a sealed container at -0.3°C. The samples were received in a laminar flow clean hood, void of trace metals contamination and ultra-violet radiation, and were designated discrete sample identifiers. An aliquot of each sample was filtered (0.45μm) and each filtrate w as stored in a secure, monitored cryofreezer (maintained at a temperature of -80 o 

## C) until selenium speciation analysis could be performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All applied water for dilutions and sample preservatives are monitored for contamination to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-CRC-MS Prior to analysis, an aliquot of each sample was filtered with a syringe filter (0.45μm) and injected directly into an autosampler vial. No further sample preparation was performed as any chemical alteration of a sample may shift the equilibrium of the system, resulting in changes in speciation ratios.

3. Sample Analysis All sample analysis is preceded by a minimum of a five-point calibration curve spanning the entire concentration range of interest. Calibration curves are performed at the beginning of

## each analytical day. All calibration curves, associated with each species of interest, are

standardized by linear regression resulting in a response factor. All sample results are instrument blank correctedto account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are verified using second source standard s which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is identified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimum interval of every ten analytical runs. Selenium Speciation Analysis by IC-ICP-CRC-MS Eachsample for selenium speciation analysis w asanalyzed by ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS) on February 12, 2013. Analiquot of each sample isinjected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy-transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber ( CRC ) containing a reaction gas which preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.

4. Analytical Issues The overall analyses went well and no significant analytical issues were encountered. All quality control parameters associated with the samples were within acceptance limits. The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium species are present in preparation blanks; therefore, eMDL calculations based on preparation blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species.

## If you have any questions or concerns regarding this report, please feel free to contact me.

Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

### Sample Results Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe Unknown Se Species (n) FGD Purge Eff 30.8 249 ND (<1.8) ND (<1.5) ND (<1.5) 0 (0) BioReactor 1 Inf 31.7 208 ND (<0.45) 2.03 ND (<0.39) 0 (0) BioReactor 2 Inf 167 16.5 ND (<0.45) 2.73 ND (<0.39) 0.71 (1) BioReactor 2 Eff 1.79 ND (<0.46) ND (<0.45) ND (<0.39) ND (<0.39) 0 (0) All results reflect the applied dilution and are reported in μg/L ND = Not detected at the applied dilution SeCN = Selenocyanate MeSe(IV) = Methylseleninic acid SeMe = Selenomethionine Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS Report Generated by: Russell Gerads Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen Wastewater - Nietering (January 2013 - Test Burn) Contact: Jay Perkins
Date: February 21, 2013 LIMS #J13020159

### Quality Control Summary - Preparation Blank Summary

Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 250x eMDL 1000x Se(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.25 0.98 Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.46 1.9 SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.45 1.8 MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.39 1.5 SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.39 1.5 eMDL = Estimated Method Detection Limit *Please see narrative regarding eMDL calculations
Quality Control Summary - Certified Reference Materials Analyte (μg/L) CRM True Value Result Recovery Se(IV) LCS 9.57 9.87 103.1 Se(VI) LCS 9.48 9.57 100.9 SeCN LCS 8.92 9.13 102.4 MeSe(IV) LCS 6.47 6.49 100.3 SeMe LCS 9.32 9.12 97.8 Selenium Speciation Results for Duke Energy Project Name: Allen Wastewater - Nietering (January 2013 - Test Burn) Contact: Jay Perkins LIMS #J13020159 Date: February 21, 2013 Report Generated by: Russell Gerads Applied Speciation and Consulting, LLC

### Quality Control Summary - Matrix Duplicates Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD Se(IV) Batch QC 20.36 21.41 20.89 5.0 Se(VI) Batch QC 344.5 322.9 333.7 6.5 SeCN Batch QC ND (<1.8) ND (<1.8) NC NC MeSe(IV) Batch QC ND (<1.5) ND (<1.5) NC NC SeMe Batch QC ND (<1.5) ND (<1.5) NC NC ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL

Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD Se(IV) Batch QC 5560 5770 103.4 5560 5724 102.6 0.8 Se(VI) Batch QC 5045 5447 101.4 5045 5462 101.6 0.3 SeCN Batch QC 4575 4605 100.7 4575 4592 100.4 0.3 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen Wastewater - Nietering (January 2013 - Test Burn) Contact: Jay Perkins LIMS #J13020159 Date: February 21, 2013 Report Generated by: Russell Gerads

### 3958 6 th 

### Ave NW • Seattle, WA 98107 • T: 206

- 632

- 6206 • F: 206

- 632

- 6017 • www.brooksrand.com • brl@brooksrand.com 

## February 22, 2013 Duke Energy ATTN : Jay Perkins Scientific Support

- Laboratory 13339 Hagers Ferry Road Huntersville NC 28078 jcperkins@duke

- energy.com labcustomer@duke

- energy.com
RE: Project DUK
- HV1 201 Client P roject : J13020159 Dear Mr. Perkins, O n February 8, 2013 , Brooks Rand Labs ( BRL ) received three(3 ) wastewater sample and three (3 ) corresponding field blank s. An aliquot was removed from each sample bottle and filtered into a separate container designed for dissolved mercury (Hg) analysis. The sample volume from the original container was logged
- in for total Hg analysis . All samples were received, prepared, analyzed, and stored according to BRL SOPs and EPA methodology. Data used for regulatory purposes has a 24 hour filtration holding time requirement. Non
regulatory purposed data has a 48 hour filtration holding time. The samples were received within the non
- regulatory holding time limit and results were not qualified. The results were blank
- corrected as described in the calculations section of the relevant SOP and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample
- specific MDLs, MRLs, and other details. All data was reported without additional qualification, aside from concentration qualifiers, and a ll associated q uality control sample results met the acceptance criteria. BRL, an accredited laboratory, certifies the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details , see the Report Information page of the report. Please feel free to contact me if you have any questions. Sincerely,

Tiffany Stilwater Project Manager tiffany@brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



### Definition of Data Qualifiers

(Effective 9/23/09) 

### Laboratory Accreditation BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is also certified by many other states to perform environmental analyses. For a current list of our accreditations /certifications, please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results reported relate only to the samples listed in the report. 

# Report Information

BLK BRL BS CAL CCV CRM D DUP ICV MSD ND NR PS REC RPD RSD SCV SOP 

### method blank Brooks Rand Labs laboratory fortified blank calibration standard continuing calibration verification certified reference material dissolved fraction duplicate initial calibration verification matrix spike duplicate non-detect non-reportable post preparation spike percent recovery relative percent difference relative standard deviation secondary calibration verification standard operating procedure MDL MRL MS



### method detection limit method reporting limit matrix spike

SRM T COC



### standard reference material total recoverable fraction chain of custody record 

### Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand Labs, those found in the EPA SOW ILM03.0, Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review; USEPA; January 2010. These supersede all previous qualifiers ever employed by BRL. Detected by the instrument, the result is > the MDL but ≤the MRL. Result is reported and considered an estimate. B E 

### An estimated value due to the presence of interferences. A full explanation is presented in the narrative. H 

### Holding time and/or preservation requirements not met. Result is estimated. J 

### Estimated value. A full explanation is presented in the narrative. J-M 

### Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated. J-N 

### Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated. M 

### Duplicate precision (RPD) was not within acceptance criteria. Result is estimated. N 

### Spike recovery was not within acceptance criteria. Result is estimated. R 

### Rejected, unusable value. A full explanation is presented in the narrative. U 

### Result is ≤the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL. X 

### Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. Result is estimated. 

### Field Quality Control Samples Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field quality control samples.

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Information

Report Matrix Type Received Sampled Sample Lab ID 

### 1306033-01 BioReactor 1 Inf 02/06/2013 02/08/2013 Sample Influent 1306033-02 BioReactor 1 Inf 02/06/2013 02/08/2013 Sample Influent 1306033-03 BioReactor 1 Inf Hg Blk 02/06/2013 02/08/2013 Field Blank DIW 1306033-04 BioReactor 1 Inf Hg Blk 02/06/2013 02/08/2013 Field Blank DIW 1306033-05 BioReactor 2 Inf 02/06/2013 02/08/2013 Sample Influent 1306033-06 BioReactor 2 Inf 02/06/2013 02/08/2013 Sample Influent 1306033-07 BioReactor 2 Inf Hg Blk 02/06/2013 02/08/2013 Field Blank DIW 1306033-08 BioReactor 2 Inf Hg Blk 02/06/2013 02/08/2013 Field Blank DIW 1306033-09 BioReactor 2 Eff 02/06/2013 02/08/2013 Sample Effluent 1306033-10 BioReactor 2 Eff 02/06/2013 02/08/2013 Sample Effluent 1306033-11 BioReactor 2 Eff Hg Blk 02/06/2013 02/08/2013 Field Blank DIW 1306033-12 BioReactor 2 Eff Hg Blk 02/06/2013 02/08/2013 Field Blank DIW 

# Batch Summary

Analyte Prepared Analyzed Sequence Batch Lab Matrix Method 

### B130230 02/11/2013 02/14/2013 1300104 Water EPA 1631 Hg

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

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### Tiffany Stilwater Client PM: 

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# Sample Results

Sample Sequence Result MDL MRL Unit Batch

Qualifier Analyte Basis

Report Matrix BioReactor 1 Inf 

### 739 T 1300104 B130230 Influent 50.5 18.9 1306033-01 Hg ng/L 134 D 1300104 B130230 Influent 10.1 3.79 1306033-02 Hg ng/L
BioReactor 1 Inf Hg Blk 

### 0.15 T U 1300104 B130230 DIW 0.40 0.15 1306033-03 Hg ng/L 0.15 D U 1300104 B130230 DIW 0.40 0.15 1306033-04 Hg ng/L

BioReactor 2 Eff 

### 135 T 1300104 B130230 Effluent 0.42 0.16 1306033-09 Hg ng/L 23.0 D 1300104 B130230 Effluent 0.39 0.15 1306033-10 Hg ng/L
BioReactor 2 Eff Hg Blk 

### 0.16 T U 1300104 B130230 DIW 0.42 0.16 1306033-11 Hg ng/L 0.15 D U 1300104 B130230 DIW 0.41 0.15 1306033-12 Hg ng/L

BioReactor 2 Inf 

### 356 T 1300104 B130230 Influent 1.02 0.38 1306033-05 Hg ng/L 21.5 D 1300104 B130230 Influent 0.42 0.16 1306033-06 Hg ng/L
BioReactor 2 Inf Hg Blk 

### 0.15 T U 1300104 B130230 DIW 0.41 0.15 1306033-07 Hg ng/L 0.15 D U 1300104 B130230 DIW 0.40 0.15 1306033-08 Hg ng/L

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Accuracy & Precision Summary

Batch: 

### B130230

Analyte Result Units Native Spike REC & Limits RPD & Limits Method: 

### EPA 1631 Lab Matrix: 

### Water

Sample Certified Reference Material (1307035, NIST 1641d 1000x dilution) B130230-SRM1 

### 15.68 102% ng/L 0-200 Hg 16.03
Matrix Spike (1306022-02) B130230-MS3 

### 20.70 86% ng/L 71-125 Hg 18.50

0.61
Matrix Spike Duplicate (1306022-02) B130230-MSD3 

### 20.96 87% ng/L 71-125 24 2% Hg 18.87

0.61
Matrix Spike (1306033-01) B130230-MS4 

### 4545 107% ng/L 71-125 Hg 5583

739.3
Matrix Spike Duplicate (1306033-01) B130230-MSD4 

### 4545 106% ng/L 71-125 240.2% Hg 5570

739.3
Matrix Spike (1306035-01) B130230-MS1 

### 7.879 106% ng/L 71-125 Hg 10.10

1.74
Matrix Spike Duplicate (1306035-01) B130230-MSD1 

### 7.776 105% ng/L 71-125 242% Hg 9.93

1.74

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Method Blanks & Reporting Limits

Batch: 

### B130230
Method: 

### EPA 1631 Matrix: 

### Water Analyte: 

### Hg Result Units Sample 

### B130230-BLK1 ng/L 0.15 B130230-BLK2 ng/L 0.16 B130230-BLK3 ng/L 0.16 B130230-BLK4 ng/L 0.16 MDL: 

### 0.15 Average: 

### 0.16 Standard Deviation: 

### 0.01 Limit: 

### 0.10 Limit: 

### 0.50 MRL: 

### 0.41

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Instrument Calibration

Sequence: 

### 1300104 Method: 

### EPA 1631 Instrument: 

### THG-05 Date: 

### 02/14/2013 Total Mercury and Mercury Speciation by CV AFS
Analyte: 

### Hg REC & Limits Result True Value Lab ID Units 

### 1300104-IBL1 0.99 pg of Hg 1300104-IBL2 2.53 pg of Hg 1300104-IBL3 2.41 pg of Hg 1300104-IBL4 2.58 pg of Hg 1300104-CAL1 10.00 9.98 pg of Hg 100% 1300104-CAL2 25.00 24.60 pg of Hg 98% 1300104-CAL3 100.0 99.33 pg of Hg 99% 1300104-CAL4 500.0 500.9 pg of Hg 100% 1300104-CAL5 2500 2515 pg of Hg 101% 1300104-CAL6 10000 10180 pg of Hg 102% 1300104-ICV1 1568 1603 pg of Hg 102% 85-115 1300104-CCB1 7.14 pg of Hg 1300104-CCV1 500.0 510.2 pg of Hg 102% 77-123 1300104-CCB2 4.56 pg of Hg 1300104-CCB3 3.69 pg of Hg 1300104-CCB4 3.60 pg of Hg 1300104-CCV2 500.0 532.6 pg of Hg 107% 77-123 1300104-CCB5 3.59 pg of Hg 1300104-CCV3 500.0 534.4 pg of Hg 107% 77-123 1300104-CCB6 4.82 pg of Hg 1300104-CCV4 500.0 538.8 pg of Hg 108% 77-123 1300104-CCB7 7.27 pg of Hg 1300104-CCV5 500.0 535.9 pg of Hg 107% 77-123 1300104-CCB8 4.68 pg of Hg 1300104-CCV6 500.0 528.8 pg of Hg 106% 77-123 1300104-CCB9 5.03 pg of Hg 1300104-CCV7 500.0 523.6 pg of Hg 105% 77-123 1300104-CCBA 4.72 pg of Hg 1300104-CCV8 500.0 524.5 pg of Hg 105% 77-123 1300104-CCBB 5.83 pg of Hg 1300104-CCBC 5.63 pg of Hg 1300104-CCVA 500.0 517.8 pg of Hg 104% 77-123 1300104-CCBD 3.89 pg of Hg 1300104-CCVB 500.0 512.6 pg of Hg 103% 77-123 1300104-CCBE 3.33 pg of Hg 1300104-ICV2 1568 1596 pg of Hg 102% 85-115 1300104-CCVC 500.0 519.9 pg of Hg 104% 77-123 1300104-CCBF 3.04 pg of Hg 1300104-CCVD 500.0 529.6 pg of Hg 106% 77-123 1300104-CCBG 3.46 pg of Hg

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Instrument Calibration

Sequence: 

### 1300104 Method: 

### EPA 1631 Instrument: 

### THG-05 Date: 

### 02/14/2013 Total Mercury and Mercury Speciation by CV AFS
Analyte: 

### Hg REC & Limits Result True Value Lab ID Units 

### 1300104-CCVE 500.0 528.8 pg of Hg 106% 77-123 1300104-CCBH 2.82 pg of Hg

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1306033-01 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 02/08/2013 Sample: 

### BioReactor 1 Inf Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71666330 10 Cooler

none n/a 500mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-02 Report Matrix: 

### Influent Sample Type : 

### Sample Received: 

### 02/08/2013 Sample: 

### BioReactor 1 Inf Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 13-0001 Cooler none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-03 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 02/08/2013 Sample: 

### BioReactor 1 Inf Hg Blk Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71666330 10 Cooler

none n/a 500mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-04 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 02/08/2013 Sample: 

### BioReactor 1 Inf Hg Blk Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 13-0001 Cooler none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-05 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Inf Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71666330 10 Cooler

none n/a 500mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-06 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Inf Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 13-0001 Cooler none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-07 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Inf Hg Blk Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71666330 10 Cooler

none n/a 500mL Bottle FLPE Hg-T

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.comProject ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1306033-08 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Inf Hg Blk Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 13-0001 Cooler none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-09 Report Matrix: 

### Effluent Sample T

ype: 

### Sample Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Eff Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71666330 10 Cooler

none n/a 500mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-10 Report Matrix: 

### Effluent Sample Type: 

### Sample Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Eff Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 13-0001 Cooler none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-11 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Eff Hg Blk Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71666330 10 Cooler

none n/a 500mL Bottle FLPE Hg-T

Lab ID: 

### 1306033-12 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 02/08/2013 Sample: 

### BioReactor 2 Eff Hg Blk Collected: 

### 02/06/2013 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 13-0001 Cooler none n/a 250mL Bottle FLPE Hg-T



# Shipping Containers

Cooler Tracking No: 

### 535305198375 via FedEx Temperature: 

### 0.1 °C Coolant Type: 

### Ice Description: 

### Cooler Damaged in transit? 

### No Returned to client? 

### No Custody seals present? 

### No Custody seals intact? 

### No COC present? 

### Yes Received: 

### February 8, 2013 9:00

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com