SPA
 

RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

RCRA REVISION CHECKLIST 140
 

Carbamate Production Identification and Listing of Hazardous Waste
 

60 FR 7824-7859
 

February 9, 1995
 

as amended at 60 FR 19165, April 17, 1995
 

and at 60 FR 25619, May 12, 1995
 

(RCRA Cluster V, HSWA provisions)
 

Note: 1) On August 8,1995, EPA published an interpretive rule in the Federal Register (see 60~ 41817­

41818) regarding a change in the Agency's interpretation of the February 9, 1995 rule that lists wastes from 

carbamate production as hazardous wastes under RCRA. Under this new interpretation, wastes from the 

production of non-carbamate intermediates that are used exclusively in the production of carbamates but are 

not produced at the ultimate site of manufacture of the carbamates will not be subject to the February 9, 1995 

rule. These wastes are among those given in the RCRA waste code designations K156 and K157 in that rule. 

2) On November 1, 1996, the U.S. Court of Appeals for the District of Columbia Circuit (Dithiocarbamate Task 

Force v. EPA, CA DC 95-1249, 11/1/96) vacated the following carbamate wastes listed by the February 9, 

1995 (60 FR 7824) listing rule: U277, U365, U366, U375, U376, U377, U378, U379, U381, U382, U383, U384, 

U385,U386,U390,U391,U392,U393, U396, U400, U401,U402, U403,U407,andK160. In addWon, the 

ourt vacated K156, K157 and K158 in so far as they encompass 3-iodo-2-propynyl n-butylcarbarnate (IPBC), 

hich was listed as product waste U375. These vacated wastes are not included on this checklist, because • 

they are no longer required for authorization for this rule. States may choose to list these wastes as a matter 

of State law. In this case, the State-listed wastes will be broader in scope or more stringent than the Federal 

requirements, depending on whether or not the listed wastes also exhibit a 40 CFR 261, SUbpart C hazardous 

waste characteristic. 

3) States that incorporate the CFR by reference should be careful in their incorporation, particularly those 

States that have a statutory or regulatory restriction against being more stringent or broader in scope than the 

Federal requirements, because the U.S. Court of Appeals' vacatur may not be transferable to State law. See 

the special guidance for States that incorporate by reference on the Summary for this checklist. 

FEDERAL REQUIREMENTS FEDERAL RCRA CITATION ANALOGOUS STATE CITATION 

WAC 173-303· 

STATE ANALOG IS: 

EQUIV· LESS MORE BROADER 

ALENT STRIN- STRIN- IN SCOPE 

GENT GENT 

PART 261 -IDENTIFICATION AND LISTING OF HAZARDOUS WASTE
 

SUBPART A.:. GENERAL
 

DEFINITION OF HAZARDOUS WASTE 

CL140.16 - Revised: 2114/97 

Printed: 10121198 • February 9, 1995 - Page 1 of 11 

t remove period at 

'end of paragraph; 

add "; or" 

261.3(a)(2)(iv)(E) No analog x 
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SPA• RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

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FEDERAL REQUIREMENTS FEDERAL RCRA CITATION ANALOGOUS STATE CITATION STATE ANALOG IS: 

WAC 173-303· EQUIV­ . LESS MORE BROADER 

ALENT STRIN- STRIN· IN SCOPE 

GENT GENT 

add new paragraph 261.3(a)(2)(iv)(F) No analog X 

which excludes as \ 

hazardous waste 

certain wastewaters 

from the production 

of carbamates and 

carbamoyl oximes 

(EPA Hazardous 

Waste No. K157); 

specific provisions 

which must be met 

add new paragraph 261.~(a)(2)(iv)(G) No analog X 

which excludes as 

hazardous waste 

certain wastewaters 

derived from the 

treatment of one or 

more of the wastes 

listed in 261.32-­

organic waste from 

the production of 

carbamates and 

carbamoyl oximes 

(EPA Hazardous 

Waste No. K156); 

specific provisions 

which must be met 

add new paragraph 261.3(c)(2)(ii)(D) 071(3)(dd) X 

which excludes as 

hazardous waste 

biological treatment 

sludge from the 

treatment of one of 

the wastes listed in 

261.32--organic 

waste from the 

production of 

carbamates and 

carbamoyl oximes 

.C)
 

CL 140.16 - Revised: 2114/97 

Printed: 10/21198 February 9, 1995 - Page 2 of 11 

c 
..
 

• 

RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

SPA
 

FEDERAL REQUIREMENTS FEDERAL RCRA CITATION ANALOGOUS STATE CITATION STATE ANALOG IS: 

WAC 173-303· EQUIV- LESS MORE BROADER 

ALENT STRIN- STRIN- IN SCOPE 

GENT GENT 

(EPA Hazardous 

Waste No. K156), 

and wastewaters 

from the production 

of carbamates and 

carbamoyl oximes 

(EPA Hazardous 

Waste No. K157) 

SUBPART D--L1STS OF HAZARDOUS WASTES
 

HAZARDOUS WASTE FROM SPECIFIC SOURCES
 

Error! 

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fined. 

•
 

add the following "K" 261.32 9904 X 

wastes in 

alphanumeric order 

(by the first column) 

to the subgroup 

"Organic 

chemicals": 

Industry and 

EPA hazardous Hazard 

waste No. 

Organic
 

Chemicals:
 

K156 Organic waste (including heavy ends, still bottoms, light ends, spent solvents, filtrates, and 

decantates) from the production ofcarbamates and carbamoyl oximes. 

K157 Wastewaters (including scrubber waters, condenser waters, washwaters, and separation waters) 

from the production ofcarbamates and carbamoyl oximes. 

K158 Bag house dusts and filter/separation solids from the production ofcarbamates and carbamoyl oximes. 

K159 Organics from the treatment ofthiocarbamate wastes. 

K161 Purification solids (including filtration, evaporation, and centrifugation solids), bag house dust 

and floor sweepings from the production ofdithiocarbamate acids and their salts. 

(This listing does not include K125 orK126.)· 

• CL140.16 - Revised: 2/14/97 

Printed: 10/21198 February 9, 1995 - Page 3 of 11 
c 

SPA. RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

DISCARDED COMMERCIAL CHEMICAL PRODUCTS, OFF-SPECIFICATION SPECIES, 

CONTAINER RESIDUES , AND SPILL RESIDUES THEREOF

2 

3 

add the following lip" 261.33(e) 9903 X 

wastes in alphabetic 

order (by the third 

column) 

Chemical 

Hazardous abstracts 

waste No. No. Substance 

P203 1646-88-4 Aldicarb sulfone. 

P127 

P188 

156~6-2 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate. 

57-64-7 Benzoic acid, 2-hydroxy-, compd. with (3aS-cis}-l,2,3,3a,8,8a-hexahydro-l ,3a,8-lrimethylpyrrolo[2,3-b]indol-5-yl 

methylcarbamate ester (1:1). 

P189 

P191 

P192 

P190 

P127 

55285-14-8 

644.Q4-4 

119-38-0 

1129-41-5 

1563.Q6-2 

Carbamic acid, [(dibutylamino)- thio)methyl-, 2,3-dihydro-2,2-<limethyl- 7-benzofuranyl ester. 

Carbamic acid, dimethyl-, l-[(dimethyl-amino)carbonyl]- 5-methyl-l H-pyrazol-3-yl ester. 

Carbamic acid, dimethyl-, 3-methyl-l- (l-methylethyl)-lH- pyrazol-5-yl ester. 

Carbamic acid, methyl-, 3-methylphenyl ester. 

Carbofuran. 

o 

P189 5285-14-8 Carbosulfan. 

P202 64-00.Q m-Cumenyl methylcarbamate. 

P191 644.Q4-4 Dimetilan. 

P185 26419-73-8 l,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, 0- [(methylamino)- carbonyl)oxime. 

P194 23135-22-0 Ethanimidothioc acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl)oxy]-2-oxo-, methyl ester. 

P198 23422-53-9 Forrnetanate hydrochloride. 

P197 17702-57-7 Forrnparanate. 

C1140.16 - Revised: 2114/97 

Printed:10121198 February 9, 1995 - Page 4 of 11 
SPA
 

• 

RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

P192 

P202 

119-38-0 

64-00-6 

Isolan. 

3-lsopropylphenyl N-methylcarbamate. 

P196 

P196 

15339-36-3 

15339-36-3 

Manganese, bis(dimethylcarbamodithioato-S,S')-, 

Manganese dimethyldithiocarbamate. 

P198 

P197 

P199 

23422-53-9 

17702-57-7 

2032-65-7 

Methanimidamide, N.N-dimethyl-N'-[3-[((methylamino)-carbonyl]oxy]phenyl]-, monohydrochloride. 

Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-([(methylamino)carbonyl]oxy]phenyl]-

Methiocarb. 

P190 1129-41-5 Metolcarb. 

P128 315-18-4 Mexacarbate. 

• 

P194 

P128 

P199 

P202 

23135-22-0 

315-18-4 

2032-65-7 

64-00-6 

Oxamyl. 

Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester). 

Ph~nol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate 

Phenol, 3-(1-methylethyl)-, methyl carbamate. 

P201 2631-37-0 Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate. 

P204 

P188 

57-47-6 

57-64-7 

Physostigmine. 

Physostigmine salicylate. 

P201 

P203 

2631-37-0 

164~8-4

Promecarb 

Propanal, 2-methyl-2-(methyl-sulfonyl)-, Q-[(methylamino)carbonyl] oxime. 

P204 57-47-6 Pyrrolo[2,3-b]indol-~I, 1,2,3,3a,8,8a-hexahydro-1 ,3a,8-trimethyl-, methylcarbamate (ester), (3aS-cis)-. 

• 

P185 26419-73-8 Tirpate. 

February 9, 1995 - Page 5 of 11 

CL140.16 - Revised: 2114/97 

Printed: 10121/98 

(
 
RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

SPA

• 

c 

P205 137-30-4 Zinc. bis(dimethylcarbamodithioato-S.S·)-, 

P205 137-30-4 Ziram. 

Error! 

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fined. 

add the following 261.33(f) 9903 X 

"U" wastes in 

alphabetic order (by 

the third column) 

Hazardous Chemical 

waste No. abstracts No. Substance 

U394 30558-43-1 

U280 101-27-9 

U278 22781-23-3 

U364 22961-82~

U271 17804-35-2 

U278 22781-23-3 

U364 22961-82~

U367 1563-38-8 

U372 10605-21-7 

• U271 17804-35-2 

U280 101-27-9 

U373 122-42-9 

U409 23564-05-8 

U389 2303-17-5 

U387 52888-80-9 

U279 63-25-2 

U372 10605-21-7 

U367 1563-38-8 

U395 5952-26-1 

A2213. 

Barban. 

Bendiocarb. 

Bendiocarb phenol. 

Benomyl. o 

1.3-Benzodioxol-4-oI. 2.2-dimethyl-. methyl carbamate.
 

1.3-Benzodioxol-4-oI. 2.2-dimethyl-.
 

7-Benzofuranol. 2,3-dihydro-2,2-dimethyl-


Carbamic acid. 1H-benzimidazol-2-yl. methyl ester. 

Carbamic acid. [1-[(butylamino)carbonyl)-1 H-benzimidazol-2-yl)-, 

methyl ester 

Carbamic acid. (3-chlorophenyl)-. 4-chloro-2-butynyl ester.
 

Carbamic acid. phenyl-. 1-methylethyl ester.
 

Carbamic acid. [1.2-phenylenebis (iminocarbonothioyl)]bis-. dimethyl
 

ester.
 

Carbamothioic acid, bis(l-methylethyl)-. 

S-(2.3.3-trichloro-2-propenyl) ester. 

Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester.
 

Carbaryl.
 

Carbendazim.
 

Carbofuran phenol.
 

Diethylene glycol. dicarbamate.
 

o
 

CL140.16 • Revised: 2114/97 

Printed: 10121198 February 9, 1995 - Page 6 of 11 
SPA
 

• 

RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

U404 121-44-8 

U410 59669-26-0 

U394 30558-43-1 

U395 5952-26-1 

Ethanamine, N,N-diethylEthanimidothioic acid, N,N'- [thiobis[(methylimino)carbonyloxyJ]bis-, 

dimethyl ester 

Ethanimidothioic acid, 2-{dimethylamino)-N-hydroxy-2-oxo-, methyl 

ester. 

Ethanol, 2,2'-oxybis-, dicarbamate. 

U279 63-25-2 1-Naphthalenol, methylcarbamate. 

U411 114-26-1 Phenol, 2-{1-methylethoxy}-, methylcarbamate. 

• 

U373 

U411 

U410 

122-42-9 

114-26-1 

59669-26-0 

Propham. 

Propoxur. 

Thiodicarb. 

U409 23564-05-8 Thiophanate-methyl. 

U389 2303-17-5 Triallate. 

U404 121-44-8 Triethylamine. 

APPENDIX VII TO PART 261
 

Error! .Add in alphanumeric 261, Appendix VII 082(4) X 

okma order (by first 

rk not column) 

BASIS FOR LISTING HAZARDOUS WASTE 

• CL140.16 - Revised: 2114/97 

Printed: 10/21/98 February 9, 1995 - Page 7 of 11 
RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

SPA, 

o 

fined. _________........ .....;.....;L-l--JL...­ r--r----l _ 

EPA hazardous 

Waste No. Hazardous constituents forwhich listed 

K156 Benomyl, carbaryl, carbendazim, carbofuran, carbosulfan, formaldehyde, methylene chloride, triethylamine. 

K157 Carbon tetrachloride, formaldehyde, methyl chloride, methylene chloride, pyridine, triethylamine. 

K158 Benomyl, carbendazim, carbofuran, carbosulfan, chloroform, methylene chloride. 

K159 Benzene, butylate, eptc, molinate, pebulate, vemolate. 

K161 Antimony, arsenic, metam-sodium, ziram. 

APPENDIX VIII TO PART 261
 

HAZARDOUS CONSTITUENTS
 

Error! 

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fined. 

Add in alphabetical 

order: 

261, Appendix VIII 9905 X 

Common Name Chemical abstracts name 

Chemical Hazardous 

abstracts No. waste No. 

A2213 Ethanimidothioic acid, 2-(dimethylamino) -N-hydroxy-2-oxo-, 

methyl ester 

30558-43-1 U394 

0 

Aldicarb sulfone Propanal, 2-methyl-2- (methylsulfonyl) -,Q-[(methylamino) 

carbonyl) oxime 

1646-88-4 P203 

Barban Carbamic acid, (3-chlorophenyl) -,4-chloro-2-butynyl ester 101-27-9 U280 

Bendiocarb 

Bendiocarb phenol 

Benomyl 

1,3-Benzodioxol-4-0l, 2,2-dimethyl-, methyl carbamate 22781-23-3 

1,3-Benzodioxol-4-0l, 2,2-dimethyl-, 22961-82-6 

Carbamic acid, [1- [(butylamino) carbonyl)­ 17804-35-2U271 

1H-benzimidazol-2-yl]-, methyl ester 

U278 

U364 

Carbaryl 

Carbendazim 

Carbofuran 

Carbofuran phenol 

1-Naphthalenol, methylcarbamate 

Carbamic acid, 1H-benzimidazol-2-yl, methyl ester 10605-21-7 

7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate 

7-Benzofuranol,2,3-dihydro-2,2-dimethyl­ 1563-38-8 U367 

63-25-2 

U372 

1563-66-2 

U279 

P127 

Carbosulfan Carbamic acid, [(dibutylamino) thio] methyl-, 55285-14-8P189 

2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester 

February 9, 1995 - Page 8 of 11 

CL 140.16 - Revised: 2/14/97 

Printed: 10/21198 
...
 SPA
 

• 

RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Listing of Hazardous Waste (cont'd) 

m-Cumenyl Phenol, 3-(methylethyl)-. methyl carbamate 64~0-6 P202
 

methylcarbamate
 

Diethylene glycol, Ethanol, 2,2'-{)xybis-, dicarbamate 5952-26-1 U395 

Dicarbamate 

DimeUlan Carbamic acid, dimethyl-, 1-[(dimethylamino) 644-64-4 P191 

carbonyl)-5-methyl-1 H-pyrazol-3-yl ester 

Formetanate hydrochloride Methanimidamide, N,N-dimethyl-N'-[3-[[(methylamino) 23422-53-9 P198 

carbonylloxyjphenyl)-, monohydrochloride 

• 

Formparanate Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino) 17702-57-7 P197 

carbonyljoxyjphenyl)-. 

Isolan Carbamic acid, dimethyl-, 3-methyl-1-(1-methylethyl)-1 H-119-38~ P192 

pyrazol-5-yl ester 

Manganese Manganese, bis(dimethylcarbamodithioato-S,S')-. 15339-36-3 P196 

Dimethyldithiocarbamate 

Methiocarb Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate 2032-65-7 P199 

Metolcarb Carbamic acid, methyl-, 3-methylphenyl ester1129-41-5 P190 

Mexacarbate Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester) 315-18-4 P128 

Oxamyl Ethanimidothioc acid, 2-(dimethylamino)-N-[[(methylamino) 23135-22~ P194 

carbonyljoxyj-2-{)xo-, methyl ester 

• CL 140.16 - Revised: 2/14/97 

Printed: 10/21198 February 9, 1995 - Page 9 of 11 
; 

SPA, RCRA REVISION CHECKLIST 140: Carbamate Production Identification and 

Physostigmine 

Physostigmine 

salicylate 

Listing of Hazardous Waste (cont'd) 

Pyrrolo[2,3-b)indol-5-o1, 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, 

methylcarbamate (ester), (3aS-cis)-

Benzoic acid, 2-hydroxy-, compd. with (3aS-cis) 57-64-7 

-1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo 

[2,3-b)indol-5-yl methytcarbamate ester (1:1). 

57-47-8 

P188 

P204 

c 

Promecarb Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate 2631-37-0 P201 

Propham 

Propoxur 

Carbamic acid, phenyl-, 1-methylethyl ester 122-42-9 

Phenol, 2-(1-methylethoxy)-, methylcarbamate 

U373 

114-26-1 U411 

Prosulfocarb Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester 52888-80-9 U387 

Thiodicarb 

Thiophanate-methyl 

Ethanimidothioic acid, N,N'-[thiobis [(methylimino) 59669-26-0 

carbonyloxy)J bis-, dimethyl ester. 

Carbamic acid, [1,2-phyenylenebis (iminocarbonothioyl)) bis-, 

dimethyl ester 

U410 

23564-05-8 U409 

Tirpate 

Triallate 

1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, Q..[(methylamino) 

carbonyl) oxime. 

Carbamothioic acid, bis(1-methylethyl)-, 

S-(2,3,3-trichloro-2-propenyl) ester 

2303-17-5 U389 

26419-73-8 P185 

o 

Triethylamine Ethanamine, N,N-diethyl­ 121-44-8 U404 

Ziram Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)­ 137-30-4 P205 

o 

CL140.16- Revised:2/14/97 

Printed: 10/21198 February 9, 1995 - Page 10 of 11