### Cover Letter

August 2012
Dear PMN Reviewer, Please find attached PMN for Fragrance component TS11FH01. Respectfully Bonita Reynolds TSCA Consultant

Page 1 SANITIZED SUBMISSION74332497418 FIRM120919066451553
11FH01

X X X X X X

X

X

Page 2 SANITIZED SUBMISSIONX

Page 3 SANITIZED SUBMISSIONKerry Blissett Director, Product Safety & Regulatory Affairs Firmenich Inc. 250 Plainsboro Road Plainsboro NJ 08536 Kerry.Blissett@firmenich.com

Bonita Reynolds Consultant Intertek Health, Environmental & Regulatory Services 801 Travis Street, Suite 1500 Houston TX 77002 bonita.reynolds@intertek.com 336-848-6549

Kerry Blissett Director, Product Safety & Regulatory Affairs Firmenich Incorporated 250 Plainsboro Road Plainsboro NJ 08536 Kerry.Blissett@firmenich.com 609-452-1000



### X X

X

X

Page 4 SANITIZED SUBMISSION

### X

2-Propen-1-ol, 2-methyl-3-4(-methylphenyl)-, (2E)-

56138-10-4


### X ID Method - TS11FH01.pdf C11H14O

See Attachment 002 (Structure - TS11FH01.pdf)

Structure - TS11FH01.pdf

Page 5 SANITIZED SUBMISSIONNot applicable.

Not applicable.

Not applicable.

Page 6 SANITIZED SUBMISSIONPage 7 SANITIZED SUBMISSIONPage 8 SANITIZED SUBMISSION(2E)-2-methyl-3-(4-methylphenyl)-2-propen-1-ol

ST 15 C 10 (for testing only)

XXX

Not applicable. Impurity structures - CAS.pdf



### X XXX XXX XXX X

XXX XXX XXX X

XXX XXX XXX X

Page 9 SANITIZED SUBMISSIONXXX XXX 

### X

X Not aqpplicable. Aroma for use in fragrance mixtures, which in turn are used in perfumes 100 1 0 0 100 0

Page 10 SANITIZED SUBMISSION

### X

XXX XXX XXX 

### X

X 1

1. A master formula for a fragrance mixture containing notified chemical will be used by the compounder. The compounder will follow the instructions in the master formula to determine the weight of notified chemical to be used. It will be weighed into an open vat, with stirring, to blend it with the other materials in the formula. The average duration of mixing in the vat is 1-2 hours. 2. The master formula is identified by a compound number, e.g., 049247. Each component of the master formula is identified by an unique six digit code. The production batch sheet will indicate the percentage, by weight, of notified chemical to be used as part of the total fragrance composition. 3. After addition of all master formula ingredients, the mix vessel is covered for continuous blending. Based on the vapor pressure of the new chemical substance, it is estimated that the worker exposure to this material will be less than 1 ppm. The material is blended into fragrance compounds at 1% or less. See page 11 for pollution prevention information.. Firmenich Inc
250 Plainsboro Road Plainsboro Middlesex NJ 08536

Page 11 SANITIZED SUBMISSIONPage 12 SANITIZED SUBMISSIONWA1: Blending See MSDS - Attachment 004 Liquid, 100 2 2 100

WA2: Packaging See MSDS - Attachment 004 Liquid, 100 1 2 100

Page 13 SANITIZED SUBMISSION

### X NJPDES NJ 0031445

XXX XXX XXX XXX XXX X X

XXX XXX XXX XXX XXX X X

Page 14 SANITIZED SUBMISSION50

The subject chemical of this PMN will leave our controlled site as an ingredient in a fragrance compound (perfume oil). The concentration of the material will average 1%, or less, in the fragrance compound. At controlled customer sites, the fragrance compound will be blended into consumer products, generally, at concentrations of 1% or less, resulting in an average final concentration, of this chemical in the consumer product, of 0.1% or less. The number of possible uncontrolled sites where exposure may take place may be as many as 50. The number of workers possibly exposed may be more than 500. The duration of the exposure will vary. The level of exposure, to the component, will be vanishingly small (well below 1 ppm).

Page 15 SANITIZED SUBMISSIONP10SB1(a)(4)1 Part II, Section B, 1(a)(4). Operation Site Locations

ALL US Customers

Page 16 SANITIZED SUBMISSIONNone

WA1: Load 500 0.25 100 XXX XXX XXX

1 0 0.0069kg/batch Empty containers are removed by private contractor to off-site incinerator X

WA2: Clean 500 0.16 100 XXX XXX XXX

2 0 <0.0069kg/batch Aqueous waste stream from equipment cleaning is sent to on-site waste treatment plant. X

Page 17 SANITIZED SUBMISSIONMixtures containing this chemical, which do not pass specifications, are blended together with other like off-specification materials, and these

blends of waste are sold for one-time use as fragrance oils for specific low-value applications. Thus, waste recapture eliminates material from the manufacturing plant. When the containers are empty, the covers are replaced, without washing, and the containers are removed by a private contractor for incineration of any residue in the container. The vessel in which the new chemical has been mixed/blended is cleaned with hot water and soap solution after processing, and the waste treated on site. Transfer of the mixture containing the new chemical to drums for shipping is accomplished by pumping in a closed system.

Page 18 SANITIZED SUBMISSION001 ID Method - TS11FH01 ID Method - TS11FH01.pdf Pt.I, Sec.B, 1c. 2

002 Structure TS11FH01 Structure - TS11FH01.pdf Pt.I, Sec.B, 1e. 1

003 Impurities - TS11FH01 Impurity structures - CAS.pdf Pt.I, Sec.B, 3. 1

004 MSDS - TS11FH01 US SDS Josenol.pdf See continuation page. id: <P12004> 9

005 Report TS11FH01 Attachment 005 - USE - TS11FH01 - sanitized 1 1

006 Tests - phys/chem -TS11FH01 General phys-chem properties - Firmenich - E096-12 2010.pdf 29

007 Report TS11FH01 Attachment 007 - SPECTRA sanitized 10 pages.docx Worksheet: Spectra 10

008 Vapor Pressure - TS11FH01 01 - 203371_497284_Firmenich, Intertek_phys.chem.pdf 20

009 TOX Oral Rat - TS11FH01 02 - 203371_497285_Firmenich_Inter 14

010 TOX Acute Dermal -TS11FH01 03 - 203371_497286_Firmenich_Inter 13

011 TOX Skin Irritation - TS11FH01 05 - 203371_497288_Firmenich_Inter 13

012 TOX - Eye Irritation TS11FH01 06 - 13
013 TOX LLNA - TS11FH01 07 - 203371_497290_Firmenich_Inter 25

014 TOX - 28 day Oral rat - TS11FH01 09 - 203371_498106_Firmenich, Intertek_28-Day Oral Rat.pdf 156

015 TOX - E Coli -TS11FH01 10 - 203371_497293_Firmenich 27

016 TOX METI - TS11FH01 11a - 203371-497294 Firmenich Chrom hum lymph METI 16

017 TOX Chromosome Aberr - TS11FH01 11b - 203371_497294_Firmenich, 33

018 TOX Daphnia Acute - TS11FH01 12 - 203371_497295_Firmenich, Intertek_Daphnia Acute OEC 24

019 TOX - Algae - TS11FH01 13 - 203371_497296_Firmenich, 36

020 TOX - Respiratory - TS11FH01 14 - 203371_497297_Firmenich, Intertek_Inh, of Resp. OECD 24

021 TOX - Validation - TS11FH01 15 - 203371_497284_Firmenich, 20 

### X

Page 19 SANITIZED SUBMISSION

### (1)

022 Biodeg - TS11FH01 16 - Readily biodegradation - Firmenich - FIR19.pdf 29

023 Episuite - Henry Law Constant Josenol - EPISUITE.pdf Worksheet: Henrys Law Const 2

024 Ready Biodeg - TS11FH01 19a - 2011ESG0300 T2011138 Ready Biodegr.pdf 17

025 Ready Biodeg 2 - TS11FH01 19c - Ready_Biodegradability_ST_15_ 17

026 Waste -TS11FH01 Waste Calculation Josenol - DHA.pdf 2

Page 20 SANITIZED SUBMISSIONP12004 List of Attachments, Associated PMN Section No., ID: 004

Worksheet: Physical State | Worksheet: Vapor Pressure | Worksheet: Density | Worksheet: Solubility In Water | Worksheet: Melting temp | Worksheet: Boiling / sublimation temp | Worksheet: Octanol / water partition coefficient | Worksheet: Other Property (Flash Point)

Page 21 SANITIZED SUBMISSION004 

### X X Measured

004 

### X 4.05 x 10-4 Measured 20

004 

### X 1.01 Measured

004 

### X 0.581 Measured 20

004 

### X 22.6 Measured

004 

### X 275.5 Measured 

### X 007 See annexes Measured



### X 004 2.39 Measured 

### X 023 2.248E-007 atm -m3/mole Estimate



### X 004 137 - 141 degrees C Measured Flash Point

Page 22 SANITIZED SUBMISSION

### ATTACHMENT HEADER SHEET

Attachment Number 001
Attachment Name ID Method - TS11FH01


### Associated PMN Section Number

Pt.I, Sec.B, 1c.

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 002
Attachment Name Structure TS11FH01


### Associated PMN Section Number

Pt.I, Sec.B, 1e.

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 003
Attachment Name Impurities - TS11FH01


### Associated PMN Section Number

Pt.I, Sec.B, 3.

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 004
Attachment Name MSDS - TS11FH01


### Associated PMN Section Number Worksheet: Physical State | Worksheet: Vapor Pressure | Worksheet: Density | Worksheet: Solubility In Water | Worksheet: Melting temp | Worksheet: Boiling / sublimation temp | Worksheet: Octanol / water partition coefficient | Worksheet: Other Property (Flash Point)

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 005
Attachment Name Report TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 006
Attachment Name Tests - phys/chem -TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 007
Attachment Name Report TS11FH01


### Associated PMN Section Number

Worksheet: Spectra

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 008
Attachment Name Vapor Pressure - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 009
Attachment Name TOX Oral Rat - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 010
Attachment Name TOX Acute Dermal -TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 011
Attachment Name TOX Skin Irritation - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 012
Attachment Name TOX - Eye Irritation TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 013
Attachment Name TOX LLNA - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 014
Attachment Name TOX - 28 day Oral rat - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 015
Attachment Name TOX - E Coli -TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 016
Attachment Name TOX METI - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 017
Attachment Name TOX Chromosome Aberr - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 018
Attachment Name TOX Daphnia Acute - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 019
Attachment Name TOX - Algae - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 020
Attachment Name TOX - Respiratory - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 021
Attachment Name TOX - Validation - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 022
Attachment Name Biodeg - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 023
Attachment Name Episuite - Henry Law Constant


### Associated PMN Section Number Worksheet: Henrys Law Const

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 024
Attachment Name Ready Biodeg - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 025
Attachment Name Ready Biodeg 2 - TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553

### ATTACHMENT HEADER SHEET

Attachment Number 026
Attachment Name Waste -TS11FH01


### Associated PMN Section Number

N/A

Does not contain CBI 

### Report Number FIRM120919066451553