REICHHOLD Material Safety DataSheet Revision Date: 20/Jul/2012 1.PRODUCT AND COMPANY IDENTIFICATION Product Description: SAP ID(s): Chemical Family: Intended Use: Manufacturer/Supplier: Reichhold, Inc

. Corporate Headquarters P.O.Box13582 Research Triangle Park,NC 27709 USA Tel +1-919-990-7500 Fax +1-919-767-8602 arance:Water \Nhite Primary Routesof Entry Acute Effects Eyes: Skin: Inhalation: Ingestion: Chronic Effects: Target Organ(s): Polyurethane Resin Wood Coating Emergency Telephone: Email: 2.HAZARDS IDENTIFICATION Emergency Overview: WARNING

I Maycauseskinirritation and/or dermatitis Irritatingto eyes Harmful byinhalation Harmfulincontactwithskin Maycausesensitization
byskincontact (Chemtrec) 1-800-424-9300 prodsafety@reichhold.com PhsicalState:
Liuid Odor: Mild,Amine Skin contact, Ingestion, Inhalation, Eye contact,Skin absorption. Moderately irritatingtothe eyes. Mildskinirritant. Repeated exposure maycauseskin drynessor cracking. Harmful byskin absorption. Maycausesensitization
byskincontact. Inhalation
of vapours
in high concentration maycauseirritationof respiratory system. Inhalation
of high vaporconcentrations cancause CNS-depression and narcosis. Ingestion {swallowing) mayirritatethe mouth, throatandstomach

.Ingestion

isnotan anticipated routeof exposureforthismaterial
inindustrial use. Thismaterial doesnotcontain 0.1%ormoreof anychemical listed bythe International Agencyfor ResearchonCancer {IARC), theNational Toxicology Program (NTP),or regulated bythe Occupational Safety andHealth Administration {OSHA) asa carcinogen

. Eyes, Central Vascular System {CVS), Kidney, Liver, Adrenal Gland, Central nervous system (CNS). HMIS: Health:

2 Flammability:

1 Reactivity:

0 3. COMPOSITION/INFORMATION

ON INGREDIENTS Component CAS-No Weighto/o Status Water 7732-18-5 60.5-64.5

Not Hazardous Polyurethane Resin Proprietary 34-38
Not Hazardous Triethylamine 121-44-8

1-2 Hazardous Page1/7

### Skin Contact: Eye Contact: Inhalation: Ingestion: Flammability: Suitable Extinguishing Media: Hazardous Combustion Products: Fire/Explosion Hazard: Protective Equipment and Precautions for Firefighters:

Revision Date: 20/Jul/2012 

# 4. FIRST AID MEASURES Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use

. Get medical attention

if irritation develops or persists. Move individual away from exposure. Immediately flush eyes with large quantities
of clean water for at least 15 minutes. Get immediate medical attention. Remove victim to fresh air. Keep warm and quiet. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen by trained personnel. GET IMMEDIATE MEDICAL ATTENTION. Do not induce vomiting. Never give anything by mouth to an unconscious person

. Seek immediate medical attention/advice

. 

# 5. FIRE-FIGHTING MEASURES Not applicable

. Carbon dioxide {C02), Alcohol-resistant foam, Dry chemical

, Water spray

. Carbon monoxide, Carbon dioxide {C02), Nitrogen oxides {NOx)

. This material will not bum unless
it is evaporated
to dryness. Closed containers may rupture when exposed to extreme heat. Wear self-contained breathing apparatus {SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate

all protective equipment after use

. Evacuate all persons from the fire area to a safe location. Move non-burning material

, as feasible,
to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazard while extinguishing the blaze

. Use water spray to cool fire-exposed containers

. NFPA Rating: Health

2 Flammability

1 Instability

0 Personal Precautions: Environmental Precautions: Methods for Containment: Methods for Clean-up

: Handling: Storage:



# 6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Prevent further leakage or spillage



## if safe to do so. Prevent product from entering drains. Do not flush Into surface water or sanitary sewer system. Prevent spilled material from 1) contaminating soil

, 2) entering sanitary sewers, storm sewers, and drainage systems, and 3) entering bodies of water or ditches that lead to waterways. Prevent spreading over a wide area {e

. g . by containment
or oil barriers). Soak up with inert absorbent material {e

. g. sand, silica gel, acid binder, universal binder, sawdust)

. 

# 7. HANDLING AND STORAGE Avoid breathing vapors or mists

. Avoid contact with skin

, eyes and clothing

. Remove and wash contaminated clothing before re-use

. Wash hands before breaks and immediately after handling the product. Ensure adequate ventilation

. Keep from freezing

. Keep container tightly closed

. Keep in a dry place. 

# 8. EXPOSURE CONTROLS



# I PERSONAL PROTECTION Page 2/7Revision Date: 20/Jul/2012 Exposure limits Components with workplace control parameters. Triethylamine (CAS #: 121-44-8) ACGIH- TLV OSHA PEL Canada

-Alberta OELs Canada

-Ontario OELs Canada

-British Columbia OELs NIOSH IDLH MexicoOEL legend

1 ppmTWA 3ppm STEL (skin) 25ppmTWA 100 mg/m

3 TWA 3ppm STEL 12 mg/m

3 STEL 1 ppmTWA 4.1 mg/m

3 TWA 1 ppmTWA 3 ppm STEL (skin) 1 ppmTWA 3 ppm STEL 200 ppm Immediately dangerous
to life or health (IDLH) 40ppmSTEL 160 mg/m

3 STEL 25ppmTWA 100 mgfml TWA (skin) ACGIH

-American Conference
of Industrial Hygienists TLV

-Threshold Limit Value TWA

-Time weighted average STEL

-Short Term Exposure Limit OSHA

- Occupational Safety and Health Administration PEL

-Permissible Exposure Limit OEL

- Occupational Exposure Limit NIOSH- National Institute for Occupational Safety and Health IDLH

- Immediately Dangerous
to Life or Health SKIN: Skin Absorption Engineering Controls: Personal Protective Equipment Eye/face Protection: Skin Protection: Respiratory Protection: Appearance: Odor:

Good general ventilation should be sufficient to control airborne levels of irritating vapors. Local ventilation may be required during certain operations. Safety glasses with side-shields.

If splashes are likely to occur, wear:. Tightly fitting safety goggles. Ensure that eyewash stations and safety showers are close to the workstation location. Gloves made of nitrile rubber. Gloves made of Viton®. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product
is used, such as the danger of cuts, abrasion. Chemical resistant apron. Boots

. None required

if hazards have been assessed and airborne concentrations are maintained below the exposure limits listed in Section 8. Wear an approved air-purifying respirator with organic vapor/amine cartridges where airborne concentrations may exceed exposure limits in Section
8. Use an approved positive-pressure air-supplied respirator with emergency escape provisions

if there is any potential for an uncontrolled release, airborne concentrations are not known, or any other circumstances where air-purifying respirators may not provide adequate protection

. 9. PHYSICAL AND CHEMICAL PROPERTIES Water White Mild Amine Page 3/7Odor Threshold: Physical State

: pH: Flash Point: Autoignition Temperature: Boiling Point/Range: Freezing point: Flammability Limits in Air Lower: Upper: Specific Gravity: Solubility: Evaporation Rate: Vapor Pressure: Vapor Density: Percent volatile: VOC Content: Viscosity: Chemical Stability: Conditions
to Avoid: Incompatible Materials: Hazardous Decomposition Products: Hazardous Polymerization: Acute Toxicity Triethylamine LD50 Oral LD50 Dermal LC50 Inhalation Chronic Toxicity Triethylamine ACGIH Legend: Target Organ(s): Ecotoxicity Ecotoxicity effects: Bioaccumulation:

Not available Liquid 7-9 Not applicable Not available 212°F- 347oF /100°C -175°C 0 oc
I 32 oF (Water) Not applicable Not applicable 1 . 011-

1 . 035@ 25°C Dispersible

in water < 1 (BuAc
= 1) Not available > 1 (Air= 1) 63
- 65 % by weight Revision Date: 20/Jul/2012 43 g/1 (calculated) product as supplied 0.5

- 5.0 Stokes @ 25°C 

### 10. STABILITY AND REACTIVITY Stable under normal conditions. Freezing temperatures. Contamination

by those materials referred to under Incompatible materials. Strong acids

. Strong bases. Strong oxidizing agents. Carbon monoxide

. Carbon dioxide (C02)

. Hydrocarbons

. Nitrogen oxides (NOx). Methanol. Hazardous polymerisation does not occur

. 

### 11. TOXICOLOGICAL INFORMATION 460 mg/kg

- rat 416 mg/kg

- rabbit > 1000 ppm (4 hours)

- rat Group A4
- Not classifiable as a human carcinogen

. ACGJH

- American Conference
of Industrial Hygienists Eyes, Central Vascular System (CVS), Kidney, Liver, Adrenal Gland, Central nervous system (CNS). 

### 12. ECOLOGICAL INFORMATION No information available

. No information available. Page 4/7Triethylamine Log Kow Aquatic Invertebrates Freshwater Fish Waste Disposal Method: Contaminated Packaging: US EPA Waste Number: DOT Proper Shipping Name: TOG Proper Shipping Name lATA Proper Shipping Name IMDGnMO Proper Shipping Name International Inventories TSCA Inventory Status: Canadian Inventory Status: Australian Inventory Status: Korean Inventory Status: Philippine Inventory: Japan ENCS: Chinese IECS:

Revision Date: 20/Jul/2012 1.45 EC50 = 200 mg/L (Daphnia magna) (48h) LC50 = 43

.7 mg/L (Pimephales promelas) (96 h) static 13. DISPOSAL CONSIDERATIONS NOT A RCRA HAZARDOUS WASTE: When discarded

in its purchased fonn, this material would not be regulated as a RCRA Hazardous waste under 40 CFR 261

. Empty containers should be taken for local recycling, recovery or waste disposal. Not applicable. 14. TRANSPORT INFORMATION NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED 15. REGULA TORY INFORMATION This material
is supplied under the Research and Development Exemption (Section (5)(h)(3)), of the US Toxic Substances Control Act (TSCA). This material contains

a component that is NOT listed on the TSCA inventory.

It may be used ONLY for research and development purposes. This material contains components that are NOT listed on the Canadian Domestic Substances List (DSL). This product contains one or more chemicals currently not on the Australian Inventory of Chemical Substances. This product contains one or more chemicals currently not on the Korean Chemical Substances List. This product contains one or more chemicals currently not on the Philippine Inventory of Chemicals and Chemical Substances. This product contains one or more chemicals currently not on the Japanese Inventory of Existing and New Chemical Substances. This product contains one or more chemicals currently not on the Chinese Inventory of Existing Chemical Substances. Page 5/7Revision Date: 20/Jul/2012 New Zealand Inventory: This product contains one or more chemicals currently not on the New Zealand Inventory of Chemicals. U.S. Federal Regulations SARA313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains

a chemical or chemicals which are subject to the reporting requirements

of the Act and and Title 40 of the Code of Federal Regulations, Part 372: SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
CAS-No 121-44-8 Yes No No No No

SARA 313 Status Listed. TSCA 12(b)

- Export Notification: This material does not contain any components that are subject to the US Toxic Substances Control Act (TSCA) Section 12(b) Export Notification requirements. CERCLA This product contains the followina reoortable auantities

: Component Triethylamine Chemical Weapons Convention (CWC) This product does not contain any listed substances. State Regulations California Proposition
65 CAS-No

HAPS data 121-44-8

Listed

. 40 CFR 302.4 RQ

40 CFR 355 EHS TPQs 50001b

Not Listed 2270 kg W A R N

I N G: This material contains

a chemical known to the State of California to cause cancer

. The California Safe Drinking Water and Toxic Enforcement Act of 1986 requires that clear and reasonable warning be given prior to exposing any person to this chemical. Canada This product has been classified

in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class: Prepared By: Revision Date:

D1 B Toxic materials CAS-No 121-44-8 

## 16. OTHER INFORMATION Reichhold Product Regulatory Department Phone Number

: 919-990-7500 20/Jul/2012 Page 6/7
redient Disclosure List 

### 1%Revision Date: 20/Jul/2012 Revision Number: Revision Summary:
None Former date:

New This information

is provided
in good faith and is correct to the best of Reichhold's knowledge asof the date hereof and is designed to assist our customers; however, Reichhold makes no representation
asto its completeness

or accuracy.Our products are intended for sale to industrial and commercial customers. We require customers
to inspect and test our products before useand to satisfy themselves
asto suitability for their specific applications. Any usewhich Reichhold customers orthird parties make of this information,

or anyreliance on,ordecisions made based upon it, arethe responsibility

of such customer orthird party. Reichhold disclaims responsibility for damages, or liability, of anykind resulting from the useof this information. THERE ARE NO WARRANTIES OR REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY

OR FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT
IT DESCRIBES.

IN NO EVENT SHALL REICHHOLD BE LIABLE FOR SPECIAL, INCIDENTAL, OR CONSEQUENTIAL DAMAGES. En d ofM S D S Page 7/7