**Pulp and Paper Data Supporting the 2013 A nnual Review Report** 

**Data Compiled: November 2013 - March 2014**

**Tab Name**

Summary

Rankings

Top DMR Pollutants

Top DMR Pollutant Data

DMR Dioxin Data Pulp - SC0000876

Top TRI Pollutants

Top TRI Pollutant Data TRI Dioxin Data TRI Manganese Data**Pulp and Paper Data Supporting the 2013 A nnual Review Report**  **Data Compiled: November 2013 - March 2014**

**Tab Description** 2013 Final Rankings for the DMR and TRI databases. Also shows what percent DMR and TRI make up for the category being reviewed. Top pollutants in the 2011 DMR Database for the Pulp and Paper Category. Includes facility count, pounds, and TWPE for each pollutant. Highlights the pollutants that were reviewed as part of the 2013 Annual Review. Also includes corrections to the top pollutant data after the 2013 Annual Review was completed. Top facilities for each top pollutant in the 2011 DMR Database for the Pulp and Paper Category reviewed as part of the 2013 Annual Review. Includes facility pounds and TWPE. Also includes corrections to the top facility data after the 2013 Annual Review was completed. Facility-specific 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) data and notes for Rayonier Performance Fibers Jesup Mill, in Jesup, GA. Also includes data for Upper Potomac River Comm STP. Facility-specific data and notes on Smurfit-Stone Container in Florence, SC. Top pollutants in the 2011 TRI Database for the Pulp and Paper Category. Includes facility count, pounds, and TWPE for each pollutant. Highlights the pollutants that were reviewed as part of the 2013 Annual Review. Top facilities for each top pollutant in the 2011 TRI Database for the Pulp and Paper Category reviewed as part of the 2013 Annual Review. Includes facility pounds and TWPE. Dioxin data and notes for the top four pulp mills with 2011 TRI dioxin discharges. All pulp and paper facilities in the 2011 TRI Database discharging manganese; ranked by percent total TWPE.**2013 - Final Combined Rankings Excluding Categories Recently Reviewed**

**2/7/2014 Revised to incorporate PSC code changes for facilities missed as part of the change to the DMR Loading Tool**  Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

**PSC Point Source Category**  **Total Count of**  **Facilities Direct** 

**Only Indirect** 

**Only Both**  **Direct and Indirect**  **TRI LBY TRI TWPE**  414 Organic chemicals, plastics and synthetic fibers 631 194 380 57 25991167.15 147675.2182 430 Pulp, paper and paperboard 221 145 63 13 17750608.67 651376.5506 419 Petroleum refining 267 192 52 23 23589915.03 680608.0883 501 Drinking Water Treatment 2 0 0 2 12810 1643 440 Ore mining and dressing 33 29 3 1 1826546.128 1229923.39 420 Iron and steel manufacturing 222 118 50 54 33509051.72 82937.27287 418 Fertilizer manufacturing 41 32 4 5 4377973.034 6667.914961 415 Inorganic chemicals manufacturing 153 56 71 26 8732577.95 326863.4381 421 Nonferrous metals manufacturing 119 52 49 18 4669549.932 42948.34437 455 Pesticide chemicals 56 30 24 2 2115074.33 373899.7328 409 Sugar processing 14 12 2 0 487306.72 429.8574031 433 Metal Finishing 1785 263 1256 266 4300840.877 51738.65198 451 Concentrated Aquatic Animal Production 0 0 0 0 0 0 434 Coal mining 17 17 0 0 292406.0871 563.9618167 432 Meat and Poultry Products 156 82 61 13 51722815.47 39117.80918 429 Timber products processing 102 67 21 14 39325.3567 32332.84936 435 Oil & Gas Extraction 0 0 0 0 0 0 463 Plastics molding and forming 114 24 71 19 2926175.403 69161.81513 503 Miscellaneous Foods and Beverages 131 19 109 3 3983961.506 4901.790156 445 Landfills 1 1 0 0 19942.9 42850.60386 417 Soap and detergent manufacturing 70 4 62 4 94322.31682 2368.142999 424 Ferroalloy

manufacturing 5 5 0 0 135757.55 8990.980096 436 Mineral Mining and Processing 83 49 32 2 2103016.382 2946.423878 458 Carbon black manufacturing 4 4 0 0 559.579 27865.49368 464 Metal molding and casting (foundries) 199 89 72 38 212440.0484 9671.857609 410 Textile mills 44 4 33 7 592379.4161 1074.029372 471 Nonferrous metals forming and metal powders 119 28 56 35 1340579.676 17883.4982 428 Rubber Manufacturing 157 26 85 46 962717.5478 10197.31036 438 Metal Products and Machinery 74 18 45 11 316649.16 7951.962317 422 Phosphate manufacturing 10 9 1 0 18457.5674 193.4171027 406 Grain mills 23 7 10 6 2851270.356 10517.45364 **TRI Facility Counts**457 Explosives manufacturing 9 5 2 2 18485.4034 17.39397107

469 Electrical and electronic components 70 5 62 3 2889479.15 3575.853324 437 Centralized Waste Treatment 2 1 1 0 265785.1 2353.763007 460 Hospital 0 0 0 0 0 0 468 Copper forming 109 24 41 44 41872.93951 6178.329298 467 Aluminumforming 114 18 60 36 175623.3605 1303.472471 439 Pharmaceutical manufacturing 84 9 71 4 1046704.288 2347.025621 411 Cement manufacturing 53 43 8 2 1148.100086 651.7279191

407 Canned and preserved fruits and vegetables processing 26 8 18 0 5894286.82 4420.079944 405 Dairy

products processing 291 36 247 8 4992508.337 3766.50093 413 Electroplating 306 15 264 27 1105818.527 4097.304214 466 Porcelain Enameling 4 0 3 1 300.216 27.83928 444 Waste combustors 2 1 0 1 45.5586 88.22424233 508 Printing & Publishing 57 2 54 1 19936 388 425 Leather tanning and finishing 13 1 11 1 218884.82 1898.084539 426 Glass manufacturing 53 9 35 9 40981.34463 246.0956356 442 Transportation Equipment Cleaning 1 1 0 0 11.7 0.012987 443 Paving and roofing materials (tars and asphalt) 29 16 6 7 136.35443 1062.519238 461 Battery

manufacturing 54 3 35 16 16899.04192 869.8050999 507 Independent and Stand Alone Labs 1 0 1 0 1.482 4.46838 408 Canned and preserved seafood processing 6 6 0 0 99330 74.1664 427 Asbestos manufacturing 0 0 0 0 0 0 454 Gum and wood chemicals manufacturing 10 8 1 1 2733.19054 33.58020866 465 Coil coating 37 1 36 0 19825.1946 74.98402799 446 Paint formulating 53 10 41 2 70441.63756 86.45111028 505 Food Service Establishments 0 0 0 0 0 0 506 Industrial Laundries 0 0 0 0 0 0 502 Tobacco Products 17 1 15 1 88022.7562 12.5288154 447 Ink formulating 10 1 9 0 1304.0257 3.612719447 509 Photo Processing 0 0 0 0 0 0 459 Photographic 0 0 0 0 0 0

3918883.447Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

**Total Count of**  **Facilities Ma** 

**jors Minors**  **DMR LBY DMR TWPE**  **Total LBY Total TWPE**  **% of Total TWPE**  **Combined %**

**of Total TWPE**  470 189 281 2738253625 1540387.114 2,764,244,793 1,688,062 0.13 0.13 234 194 40 2239681616 1034369.59 2,257,432,225 1,685,746 0.13 0.26 479 96 383 516230325.2 751580.6938 539,820,240 1,432,189 0.11 0.37 1335 20 1315 4216219611 1384298.003 4,216,232,421 1,385,941 0.11 0.48 93 53 40 698538772.3 109758.1093 700,365,318 1,339,681 0.10 0.59 146 83 63 1279823916 1170699.952 1,313,332,968 1,253,637 0.10 0.68 39 19 20 122486680.9 599100.4356 126,864,654 605,768 0.05 0.73 217 70 147 1532389542 142060.7974 1,541,122,119 468,924 0.04 0.77 57 28 29 157405728.4 382840.4371 162,075,278 425,789 0.03 0.80 33 20 13 29998642.94 19317.89791 32,113,717 393,218 0.03 0.83 26 19 7 65490570.71 373178.6753 65,977,877 373,609 0.03 0.86 626 86 540 216670888.6 264963.1311 220,971,729 316,702 0.02 0.88 266 20 246 105515454.3 291885.136 105,515,454 291,885 0.02 0.91 218 13 205 8405721295 188756.1494 8,406,013,701 189,320 0.01 0.92 158 34 124 464043654 119028.2383 515,766,469 158,146 0.01 0.93 139 4 135 1136810374 98629.5955 1,136,849,700 130,962 0.01 0.94 150 14 136 5024628205 106089.5093 5,024,628,205 106,090 0.01 0.95 78 5 73 724327795.5 26693.83158 727,253,971 95,856 0.01 0.96 119 7 112 4247927288 57364.7284 4,251,911,250 62,267 0.00 0.97 234 5 229 81481172.75 19311.53355 81,501,116 62,162 0.00 0.97 18 3 15 2781234.308 47123.66268 2,875,557 49,492 0.00 0.97 13 2 11 13220221.92 27260.26418 13,355,979 36,251 0.00 0.98 992 27 965 3093991064 31156.47101 3,096,094,081 34,103 0.00 0.98 2 0 2 4375209.577 0.2009075 4,375,769 27,866 0.00 0.98 53 8 45 27454867.86 16283.18749 27,667,308 25,955 0.00 0.98 67 31 36 33130533.05 22342.79249 33,722,912 23,417 0.00 0.99 34 11 23 6011501.362 3438.610671 7,352,081 21,322 0.00 0.99 77 15 62 19197556.73 7322.237141 20,160,274 17,520 0.00 0.99 491 76 415 230974159.8 7672.994297 231,290,809 15,625 0.00 0.99 12 8 4 23096767.64 13597.30481 23,115,225 13,791 0.00 0.99 34 7 27 55857054.6 2808.320562 58,708,325 13,326 0.00 0.99 **DMR Facility Counts**11 4 7 104873877.7 11829.26076 104,892,363 11,847 0.00 0.99

12 5 7 80960904.97 8179.21937 83,850,384 11,755 0.00 0.99 19 9 10 211936878.3 7864.421151 212,202,663 10,218 0.00 0.99 155 2 153 16801424.87 9419.724086 16,801,425 9,420 0.00 1.00 28 8 20 4005009.424 2613.052703 4,046,882 8,791 0.00 1.00 27 9 18 4106427.55 6962.480421 4,282,051 8,266 0.00 1.00 58 20 38 37208518.52 4519.197551 38,255,223 6,866 0.00 1.00 323 6 317 99524423.29 5964.807959 99,525,571 6,617 0.00 1.00

51 7 44 856519832.8 1063.841802 862,414,120 5,484 0.00 1.00 54 3 51 36114818.66 593.1695576 41,107,327 4,360 0.00 1.00 0 0 0 0 0 1,105,819 4,097 0.00 1.00 3 0 3 579081.6817 2733.890934 579,382 2,762 0.00 1.00 9 5 4 484441.2705 2652.262618 484,487 2,740 0.00 1.00 12 2 10 1397612.326 1891.085596 1,417,548 2,280 0.00 1.00 3 1 2 52662.71522 8.195757828 271,548 1,906 0.00 1.00 43 1 42 10436822.26 1555.930967 10,477,804 1,802 0.00 1.00 49 1 48 20451295.3 1697.742516 20,451,307 1,698 0.00 1.00 48 3 45 11673576.8 581.4361552 11,673,713 1,644 0.00 1.00 2 0 2 10969.23373 298.0498167 27,868 1,168 0.00 1.00 33 5 28 69404043.95 756.2223126 69,404,045 760.7 0.00 1.00 53 8 45 68783703.06 686.4242635 68,883,033 760.6 0.00 1.00 2 0 2 7018812.068 517.9002151 7,018,812 518 0.00 1.00 12 3 9 3863729.745 360.0025889 3,866,463 394 0.00 1.00 5 1 4 24097.81521 249.914905 43,923 325 0.00 1.00 8 0 8 50775.60004 3.051504149 121,217 90 0.00 1.00 87 0 87 10346303.53 45.63688716 10,346,304 46 0.00 1.00 5 0 5 380387.7176 12.62378436 380,388 13 0.00 1.00 1 0 1 5.17447E-07 0 88,023 13 0.00 1.00 3 0 3 26080.35784 2.222387256 27,384 6 0.00 1.00 1 0 1 21973.57197 0.06279474 21,974 0 0.00 1.00 1 0 1 21973.57197 0.06279474 21,974 0 0.00 1.00

8932381.498 12,851,265**TRI % of**

**Total DMR % of** 

**Total** 9% 91% 39% 61% 48% 52% 0.1% 99.9% 92% 8% 7% 93% 1% 99% 70% 30% 10% 90% 95% 5% 0% 100% 16% 84% 0% 100% 0% 100% 25% 75% 25% 75% 0% 100% 72% 28% 8% 92% 69% 31% 5% 95% 25% 75% 9% 91% 100% 0% 37% 63% 5% 95% 84% 16% 58% 42% 51% 49% 1% 99% 79% 21%0% 100%

30% 70% 23% 77% 0% 100% 70% 30% 16% 84% 34% 66% 10% 90%

81% 19% 86% 14% 100% 0% 1% 99% 3% 97% 17% 83% 100% 0% 14% 86% 0% 100% 65% 35% 74% 26% 1% 99% 10% 90% 0% 100% 9% 91% 23% 77% 97% 3% 0% 100% 0% 100% 100% 0% 62% 38% 0% 100% 0% 100%**Top Pollutants in Pulp and Paper (40 CFR Part 430) from DMR2011**

11/21/2013 Table from DMR Database: TSD 01 - Top Pollutants by PSC

Pollutants Reviewed as part of the 2013 ARR

**PSC Code PSC Description**  **Fac Count**  **Pollutant** 430 Pulp, paper and paperboard 62,3,7,8-Tetrachlorodibenzo-p-dioxin 430 Pulp, paper and paperboard 2Sulfide 430 Pulp, paper and paperboard 52,3,7,8-Tetrachlorodibenzofuran 430 Pulp, paper and paperboard 30Aluminum 430 Pulp, paper and paperboard 25 Mercury 430 Pulp, paper and paperboard 31 Total Residual Chlorine 430 Pulp, paper and paperboard 71 Ammonia as N 430 Pulp, paper and paperboard 40Copper 430 Pulp, paper and paperboard 26Zinc 430 Pulp, paper and paperboard 10Sulfate 430 Pulp, paper and paperboard 15 Iron 430 Pulp, paper and paperboard 5Arsenic 430 Pulp, paper and paperboard 17 Lead 430 Pulp, paper and paperboard 9Ammonia as NH3 430 Pulp, paper and paperboard 5 Manganese 430 Pulp, paper and paperboard 3Silver 430 Pulp, paper and paperboard 4Selenium 430 Pulp, paper and paperboard 6Cyanide 430 Pulp, paper and paperboard 33,4,6-Trichloroguaiacol 430 Pulp, paper and paperboard 9 Nickel 430 Pulp, paper and paperboard 5Cadmium 430 Pulp, paper and paperboard 6Chloride 430 Pulp, paper and paperboard 11 Nitrogen, nitrate dissolved 430 Pulp, paper and paperboard 22,4,6-Trichlorophenol 430 Pulp, paper and paperboard 4 Barium 430 Pulp, paper and paperboard 1 Boron 430 Pulp, paper and paperboard 2 Magnesium 430 Pulp, paper and paperboard 3Tetrachloroguaiacol 430 Pulp, paper and paperboard 28Chloroform 430 Pulp, paper and paperboard 2 Di(2-ethylhexyl) phthalate 430 Pulp, paper and paperboard 4Chromium 430 Pulp, paper and paperboard 34,5,6-Trichloroguaiacol 430 Pulp, paper and paperboard 2Tetrachlorocatechol 430 Pulp, paper and paperboard 2 Formaldehyde 430 Pulp, paper and paperboard 23,4,5-Trichloroguaiacol 430 Pulp, paper and paperboard 23,4,5-Trichlorocatechol 430 Pulp, paper and paperboard 1 Pentachlorophenol 430 Pulp, paper and paperboard 6 Nitrite nitrogen, dissolved (as N) 430 Pulp, paper and paperboard 1 Chromium, Hexavalent 430 Pulp, paper and paperboard 22,3,4,6-Tetrachlorophenol 430 Pulp, paper and paperboard 1 Epichlorohydrin 430 Pulp, paper and paperboard 22,4,5-Trichlorophenol 430 Pulp, paper and paperboard 2Trichlorosyringol 430 Pulp, paper and paperboard 1 3,4,6-Trichlorocatechol 430 Pulp, paper and paperboard 1 Sodium**LBY TWPE**  **% of Total TWPE**  **Pollutant TWPE DMR TWPE**  0.000889 625541.8 61% 182637.86 575582.16 86131.51 241168.2 24% 0.001544 67639.78 7% 448416.9 26905.02 3% 173.7635 20349.45 2% 34299.6 17149.8 2% 6555865 7277.01 1% 5146.632 3242.378 0% 48802.56 1952.102 0% 2.1E+08 1174.669 0% 187542.3 1050.237 0% 259.1111 1046.809 0% 410.3792 919.2494 0% 659176.2 731.6855 0% 7451.252 521.5876 0% 20.65557 340.1972 0% 302.8499 339.1918 0% 184.5391 204.8384 0% 18636.3 186.363 0% 1828.781 182.8781 0% 6.512657 150.5075 0% 3970395 96.67048 0% 70601.92 52.7161 0% 85.77289 42.02872 0% 20778.83 41.36561 0% 4733.213 39.48288 0% 43889.89 37.98816 0% 115.2235 19.588 0% 9199.96 19.12109 0% 49.4251 12.35628 0% 171.8521 12.02965 0% 50.96718 9.174092 0% 113.7333 7.961333 0% 2421.075 5.642683 0% 71.64505 5.015154 0% 144.5887 4.33766 0% 3.416822 1.879252 0% 569.8249 1.82344 0% 3.410416 1.739312 0% 14.56558 0.728279 0% 31.93416 0.221822 0% 19.914 0.19914 0% 19.914 0.19914 0% 3.416822 0.034168 0% 4710.176 0.02586 0%

1018486.0 8038929 **Corrected Data after 2013 A nnual**  **Review was Completed 40 CFR Part 430 - Pulp and Paper** 

From DMR Database: TSD 02 - Facility Discharges query

Facilities Reviewed as part of the 2013 ARR

**2,3,7,8-Tetrachlorodibenzo-p-dioxin PSC**  **Code NPDES ID**  **FA CILITY_NA** **ME** 430 GA0003620 RAYONIER PERFORMANCE FIBERS JESUP MILL 430 MD0021687 UPPER POTOMAC RIVER COMM STP 430 ID0001163 CLEARWATER PAPER CORP 430 LA0007927 BOISE PACKAGING & NEWSPRINT LLC 430 ME0002020 RED SHIELD ENVIRONMENTAL BIOREFINERY 430 NC0000078 RFS ECUSTA, INCORPORATED

**Sulfide PSC**  **Code NPDES ID**  **FA CILITY_NA** **ME** 430 SC0000876 SMURFIT-STONE CONTAINER 430 PA0002143 DOMTAR - JOHNSONBURG MILL**CITY State**  **Ma jor/Minor**  **Group**

**Code Group Desc**  JESUP GA M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin WESTERNPORT MD M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin LEWISTON ID M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin DERIDDER LA M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin OLD TOWN ME M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin PISGAH FOREST NC M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin

**CITY State**  **Ma jor/Minor**  **Group**

**Code Group Desc**  FLORENCE SC M S Sulfide JOHNSONBURG PA M S Sulfide**LBY TWPE**  **% of Total TWPE Corrected**  **Facility TWPE New Pollutant**  **TWPE** 0.000629497 442903.92 71% 0 182637.86 0.000157289 110666.30 18% 9.1033E-05 64049.35 10% 6.83364E-06 4808.04 1% 3.02869E-06 2130.94 0% 1.39746E-06 983.23 0% 0.00089 625541.78 0.000259582 182637.86

**LBY TWPE**  **% of Total TWPE** 83543.66069 233922.25 97% 2587.85 7245.98 3% 86131.51069 241168.23 **Corrected Data after 2013 A nnual**  **Review was Completed 40 CFR Part 430 - Pulp and Paper** 

**DMR 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) Discharges**

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more exceedances of permit effluent limits for this pollutant sometime during the y ear.
**Top two dischargers of 2,3,7,8-TCDD in 2011 DMR database**

PSC Code NPDES ID FACILITY_NAME 430 GA0003620 RAYONIER PERFORMANCE FIBERS JESUP MILL 430 MD0021687 UPPER POTOMAC RIVER COMM STP

**RECOMMENDA**

**TION:** Rayonier facility

contact confirmed that all discharges are BDL and that the values reported are 1/2 the detection limit. Since all TCDD discharges are BDL for outfall 0A0 the TCDD discharge can be zeroed. New Facility

TWPE for Rayonier Performance Fibers = 0

**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TWPE.

**Pollutant Total Pounds**  **(lbs/yr) Ma** **x A llowable Load (lbs/yr)** 

2,3,7,8-Tetrachlorodibenzo-pdioxin 0.00062 0.025

Solids, total suspended 8,183,550 15,333,650 BOD, 5-day, 20 deg. C 5,185,095 9,604,200

2,3,7,8-TCDD, Outfall 0A0

**Monitoring Period Discharge**  **Information Below Detection Limit?** 

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No **Rayonier Performance Fibers**

3/31/2011 No **2,3,7,8-TCDD: View Details**

2011 Monitoring Period-Level Loads for 2,3,7,8-Tetrachlorodibenzo-p-dioxin (34675) for Outfall 0A0

Number of Months Requiring Estimation

12/31/2011 No 9/30/2011 No

Annual Load from Monitoring Data (lb/yr)

6/30/2011 NoAnnual Load (lb/yr)Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more exceedances of permit effluent limits for this pollutant sometime during the y ear.

CITY State Major/Min

or Group

Code Group Desc JESUP GA M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin WESTERNPORT MD M TCDD 2,3,7,8-Tetrachlorodibenzo-p-dioxin

Rayonier facility

contact confirmed that all discharges are BDL and that the values reported are 1/2 the detection limit.

**Previous Years Data from DMR LT**

**Total TWPE (lbs eq/yr)**  **Ma x A** **llowable**

**Load (lbs eq/yr)**  **Year**

442,904 17,848,382 2010 2009 2008 2007

**Me asurement**  **Ty pe**  **Av g** 

**Daily Value Limit**  **Wastewat er Flow**  **(MGD) Number of Days** 

0.000109 1.53E-07 Concentration (mg/L) 4.50E-09 1.53E-07 52 31

Concentration (mg/L) 8.50E-10 1.53E-07 54.1 31 30

Concentration (mg/L) 1.95E-09 1.53E-07 57.1 30 54 Concentration (mg/L) 8.10E-090.00032LBY TWPE **% of Total TWPE**  0.000629497 442903.92 71% 0.000157289 110666.30 18% 553570.22

**Pounds TWPE** 

0.0086 0 0.000608 428,362 0.000705 496,095 0 0

**Monitoring Per iod Load**  **(lb/period) Equation** 

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 6.054E-005

8 2.78E-005 Concentration (mg/L) × Flow

(MGD) × 3.785 (L/gal) × Number of Days × 2.205 1.18E-005 Concentration (mg/L) × Flow

(MGD) × 3.785 (L/gal) × Number of Days × 2.205 Sumof Monitoring Period Loads 0.000109Concentration (mg/L) × Flow

(MGD) × 3.785 (L/gal) × Number of Days × 2.205Annual Load from Monitoring Data (lb/yr) × 12 /**40 CFR Part 430 - Pulp and Paper**

**Smurfit-Stone Container Florence, SC**  SC0000876 (TRI ID: 29502STNCNOLDGE)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more exceedances of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:** The mill’s kraft pulping process uses sodium-based alkaline pulping solution (liquor) which consists of sodium sulfide and sodium hy droxide in 10 percent solution. This is the primary source of sulfides in the wastewater. The mill contact confirmed the 2011 discharges and stated that Jan and Feb 2011 concentrations appear to be anomalies. Contact provided DMR sulfide data from 2009-2013 and 2011 is an anomalie.

**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TWPE.

**Pollutant Total Pounds**  **(lbs/yr) Ma** **x Al** **lowable Load (lbs/yr)**  **Total TWPE**

**(lbs-eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)**

Sulfide 83,544 0 233,922 0 Ammonia as N 31,606 97,103 35.08 108 Solids, total suspended 1,111,448 7,993,500 BOD, 5-day, 20 deg. C 946,198 3,730,300

Sulfide, Outfall 001

**Monitoring Period Discharge**  **Information Below** 

**Detection Limit?**  **Me asurement** 

**Ty pe**  **Av g Daily Value** 

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes **Sulfide: View Details**

2011 Monitoring Period-Level Loads for Sulfide (00745) for Outfall 001

1/31/2011 No Concentration (mg/L) 7.7

2/28/2011

3/31/2011 No Concentration (mg/L) 1.2 No Concentration

(mg/L) 8.6Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

**Facility Multi-Year Loading Report**

**2007 2007**  **2008 2008**  **lbs/yr lbs-eq/yr**  **lbs/yr lbs-eq/yr** 

Sulfide 21,599 60,476 35,762 100,135 No TRI sulfide discharges. Discharges to DMR Pollutants by Pounds (lbs) and Toxic-Weighted Pounds (TWPE) 4/30/2011 No Concentration (mg/L) 0.38

6/30/2011 No Concentration (mg/L) 2.7 5/31/2011 No Concentration (mg/L) 0.42

7/31/2011 No Concentration (mg/L) 0.61

10/31/2011 No Concentration (mg/L) 0.19 9/30/2011 No Concentration (mg/L) 0.65 8/31/2011 No Concentration (mg/L) 0.93

11/30/2011 No Concentration (mg/L) 0.56

**Pollutant** Number of Months Requiring Estimation Annual Load (lb/yr) 12/31/2011 No Concentration (mg/L) 1.1

Annual Load from Monitoring Data (lb/yr)Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more exceedances of permit effluent limits for this pollutant sometime during the year.

The mill’s kraft pulping process uses sodium-based alkaline pulping solution (liquor) which consists of sodium sulfide and sodium hydroxide in 10 percent solution. This is the primary source of sulfides in the wastewater. The mill contact confirmed the 2011 discharges and stated that Jan and Feb 2011 concentrations appear to be anomalies. Contact provided DMR sulfide data from 2009-2013 and 2011 is an anomalie.

**Previous Years Data from DMR LT**

**Year Pollutant** 

Sulfide Ammonia as N Solids, total suspended BOD, 5-day, 20 deg. C Sulfide Ammonia as N Solids, total suspended BOD, 5-day, 20 deg. C Sulfide Ammonia as N Solids, total suspended BOD, 5-day, 20 deg. C Sulfide Ammonia as N Mercury Solids, total suspended BOD, 5-day, 20 deg. C

**Limit Wastewat** 

**er Flow (MGD)**  **Number**

**of Days Monitoring Period Load (lb/period)** 

15.3 31 30,480

28 24,116

15.1 31 4,688 12 2010

2009

2008

200782,742

82,742

**2009 2009**  **2010 2010**  **lbs/yr lbs** 

**eq/yr lbs/yr**  **lbs-eq/yr**

48,368 135,430 58,346 163,368

17.4 30 1,655

11.1 30 7,504 13.8 31 1,500

14.8 31 2,336

14.1 31 3,393

14.8 30 2,409

9.5 30 1,332

Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation) 11.7 31 3,330

Sumof Monitoring Period Loads 16.3 31 801The mill’s kraft pulping process uses sodium-based alkaline pulping solution (liquor) which consists of sodium sulfide and sodium hydroxide in 10 percent solution. This is the primary source of sulfides in the wastewater. The mill contact confirmed the 2011 discharges and stated that Jan and Feb 2011 concentrations appear to be anomalies. Contact provided DMR sulfide data from 2009-2013 and 2011 is an anomalie.

**Total Pounds (lbs/yr) Ma** **x Al** **lowable Load (lbs/yr)**  **Total TWPE**

**(lbs-eq/yr) Ma** **x**

**Al lowable** **Load (lbs eq/yr)**  58,346 0 163,368 0 20,709 107,916 22.9 120 2,324,812 7,993,500 1,187,770 3,730,300 48,368 0 135,430 0 13,951 92,201 15.4 102 1,115,920 7,993,500 524,904 3,730,300 35,762 0 100,135 0 25,739 115,399 28.5 128 1,848,530 7,993,500 665,281 3,730,300 21,599 0 60,476 0 15,575 77,380 17.2 85.8 0.012 0 1.408 0 1,251,584 7,993,500 629,483 3,730,300

**Equation**

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205**2011 2011** 

**lbs/yr lbs-eq/yr** 

83,544 233,922 Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205**Top Pollutants in Pulp and Paper (40 CFR Part 430) from TRI2011**

11/21/2013 Table from TRI Database: TSD 02 - Top Pollutants by PSC

Pollutants Reviewed as part of the 2013 ARR

**PSC Code PSC Description**  **Fac Count**  **CHEMICA L_NA** **ME LBY**  **TWPE** 430 Pulp, paper and paperboard 104 MANGANESE AND MANGANESE COMPOUNDS 3804966 266347.6 430 Pulp, paper and paperboard 38 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.095911 237694.8 430 Pulp, paper and paperboard 81 MERCURY AND MERCURY COMPOUNDS 450.0562 52706.08 430 Pulp, paper and paperboard 157 LEAD AND LEAD COMPOUNDS 21421.71 47984.63 430 Pulp, paper and paperboard 21 POLYCYCLIC AROMATIC COMPOUNDS 408.1928 13964.28 430 Pulp, paper and paperboard 88ZINC AND ZINC COMPOUNDS 311486.5 12459.46 430 Pulp, paper and paperboard 61 NITRATE COMPOUNDS 6655196 4969.213 430 Pulp, paper and paperboard 1 ARSENIC AND ARSENIC COMPOUNDS 1036 4185.44 430 Pulp, paper and paperboard 9COPPER AND COPPER COMPOUNDS 5429 3420.27 430 Pulp, paper and paperboard 116AMMONIA 1577327 1750.833 430 Pulp, paper and paperboard 33VANADIUM AND VANADIUM COMPOUNDS 43630.9 1308.927 430 Pulp, paper and paperboard 3 POLYCHLORINATED BIPHENYLS 0.0374 1272.857 430 Pulp, paper and paperboard 1 ACROLEIN 706.1 691.978 430 Pulp, paper and paperboard 87ACETALDEHYDE 290277.2 639.9398 430 Pulp, paper and paperboard 6 NICKEL AND NICKEL COMPOUNDS 5119.8 511.98 430 Pulp, paper and paperboard 36 BARIUM AND BARIUM COMPOUNDS 205614.6 409.3287 430 Pulp, paper and paperboard 82 FORMALDEHYDE 129119 300.9313 430 Pulp, paper and paperboard 33 PHENOL 10746.23 214.9246 430 Pulp, paper and paperboard 7CHROMIUM AND CHROMIUM COMPOUNDS 2536.2 177.534 430 Pulp, paper and paperboard 49 FORMIC ACID 309397.1 114.6348 430 Pulp, paper and paperboard 78CATECHOL 11426.32 114.2632 430 Pulp, paper and paperboard 96 METHANOL 4316835 62.93874 430 Pulp, paper and paperboard 4 ETHYLENE GLYCOL 16319.96 21.87419 430 Pulp, paper and paperboard 2 COBALT AND COBALT COMPOUNDS 149 16.39 430 Pulp, paper and paperboard 2 DIETHANOLAMINE 8451.68 14.79044 430 Pulp, paper and paperboard 10 NAPHTHALENE 667.984 6.67984 430 Pulp, paper and paperboard 1 1,2,4-TRIMETHYLBENZENE 182 3.64 430 Pulp, paper and paperboard 22 CRESOL (MIXED ISOMERS) 603.89 2.954834 430 Pulp, paper and paperboard 1 4,4'-ISOPROPYLIDENEDIPHENOL 1095.9 2.57983 430 Pulp, paper and paperboard 2 DAZOMET 146.7 1.392407 430 Pulp, paper and paperboard 12 CERTAIN GLYCOL ETHERS 10298.8 1.098586 430 Pulp, paper and paperboard 3CHLOROFORM 466 0.968529 430 Pulp, paper and paperboard 2STYRENE 50.6 0.506 430 Pulp, paper and paperboard 1 N-BUTYL ALCOHOL 2765 0.282961430 Pulp, paper and paperboard 4CHLOROMETHANE 45.51 0.243895

430 Pulp, paper and paperboard 1 METHYL METHACRYLATE 410 0.122915 430 Pulp, paper and paperboard 1 ANTIMONY AND ANTIMONY COMPOUNDS 5 0.05 430 Pulp, paper and paperboard 1 DIMETHYL PHTHALATE 8.97 0.029548 430 Pulp, paper and paperboard 2VINYL ACETATE 6.016 0.024081 430 Pulp, paper and paperboard 1 O-CRESOL 5 0.014959 430 Pulp, paper and paperboard 1 BUTYL ACRYLATE 0.7 0.007 430 Pulp, paper and paperboard 4TOLUENE 0.8464 0.004763 430 Pulp, paper and paperboard 2 N-HEXANE 0.1 0.003 430 Pulp, paper and paperboard 1 XYLENE (MIXED ISOMERS) 0.2 0.000865 651376.55 0576987**% of Total**

**TWPE** 41% 36% 8% 7% 2% 2% 1% 1% 1% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0% 0%0%

0% 0% 0% 0% 0% 0% 0% 0% 0%**40 CFR Part 430 - Pulp and Paper**

From TRI Database: TSD 04 - Facility Discharges

Facilities Reviewed as part of the 2013 ARR

**Ma nganese and Manganese Compounds** 

**PSC Code**  **TRI ID Facility Name**  **City** 430 71822NKSPPHIGHW DOMTAR AWLLC ASHDOWN MILL ASHDOWN 430 35618CHMPNPOBOX INTERNATIONAL PAPER COURTLAND MILL COURTLAND

430 36916JMSRVROUTE GEORGIA-PACIFIC CONSUMER PRODUCTS LP PENNINGTON

430 31545TTRYNSAVAN RAYONIER PERFORMANCE FIBERS JESUP MILL JESUP 430 36470LBMRVOFFHI ALABAMA RIVER CELLULOSE LLC PERDUE HILL 430 29704BWTRC5300C ABIBOWUS INC CATAWBA OPERATIONS CATAWBA 430 04976SDWRRRFD3U SD WARREN CO SKOWHEGAN 430 31521BRNSW14W9T BRUNSWICK CELLULOSE INC BRUNSWICK

430 70791GRGPCZACHA GEORGIA-PACIFIC CONSUMER PRODUCTS LLC ZACHARY 430 77656PLPPPPOBOX MEADWESTVACO TEXAS LP EVADALE 430 37309BWTRSROUTE ABIBOWUS INC - CALHOUN OPERATIONS CALHOUN 430 30913FDRLPHIGHW INTERNATIONAL PAPER - AUGUSTA MILL AUGUSTA 430 04239NTRNTRILEY VERSO PAPER HOLDINGS LLC JAY 430 36426CNTNRHIGHW GEORGIA-PACIFIC BREWTON LLC BREWTON 430 04276BSCSCROUTE RUMFORD PAPER CO RUMFORD 430 39703CLMBSCARSO COLUMBUS CELLULOSE FIBERS COLUMBUS 430 36701HMMRMRIVER INTERNATIONAL PAPER - RIVERDALE MILL SELMA

430 39654GRGPCSANDI GEORGIA-PACIFIC MONTICELLO LL C MONTICELLO

430 04694GRGPCMILLA WOODLAND PULP LLC BAILEYVILLE

430 38326TNNSSHIGHW PACKAGING CORP OF AMERICA COUNCE MILL COUNCE

430 28716CHMPNMAINS BLUE RIDGE PAPER PRODUCTS INC (DBA EVERGREEN PACKAGING) CANTON 430 71654PTLTCHIGHW CLEARWATER PAPER CORP ARKANSAS CITY 430 74764WYRHSHIGHW INTERNATIONAL PAPER CO VALLIANT

430 39180NTRNTPOBOX INTERNATIONAL PAPER - VICKSBUR G MILL REDWOOD 430 29044NNCMPROUTE INTERNATIONAL PAPER CO EASTOVER MILL EASTOVER 430 31732GRTSTHIGHW GEORGIA PACIFIC CEDAR SPRINGS LLC CEDAR SPRINGS

430 28456FDRLPRIEGE INTERNATIONAL PAPER RIEGELWOOD MILL RIEGELWOOD 430 04468JMSRVPORTL RED SHIELD ACQUISITION LLC OLD TOWN

430 36067NNCMP100JE INTERNATIONAL PAPER PRATTVILLE 430 36545BSCSC307WE BOISE WHITE PAPER LLC JACKSON 430 12801FNCHP1GLEN FINCH PAPER LLC GLENS FALLS 430 36868MDCTDALABA MEADWESTVACO COATED BOARD INC COTTONTON 430 32533CHMPN375MU INTERNATIONAL PAPER PENSACOLA MILL CANTONMENT 430 27962WYRHSTROWB DOMTAR PAPER CO LLC PLYMOUTH MILL PLYMOUTH 430 36732GLFSTHIGHW ROCK-TENN MILL CO LLC DEMOPOLIS 430 75504NTRNTPOBOX INTERNATIONAL PAPER TEXARKANA MILL QUEEN CITY430 71611NTRNTFAIRF EVERGREEN PACKAGING PINE BLUFF

430 70634BSSTHUSHIG BOISE PACKAGING & NEWSPRINT LLC DERIDDER

430 32347BCKYCROUTE BUCKEYE FLORIDA LP PERRY 430 54457NKSMLMARKE DOMTAR AWLLC NEKOOSA MILL NEKOOSA 430 30162NLNDR238MA TEMPLE-INLAND ROME LINERBOARD MILL ROME

430 27870CHMPNNORTH KAPSTONE KRAFT PAPER CORP ROANOKE RAPIDS 430 98632WYRHS3401I WEYERHAEUSER NR CO - LONGVIEW LONGVIEW

430 38901NWSPRPAPER BOWATER NEWSPRINT SOUTH OPERATIONS LLC GRENADA 430 12883NTRNTSHORE INTERNATIONAL PAPER TICONDEROGA

430 23181CHSPK19THM SMURFIT-STONE CONTAINER ENTERPRISES INC WEST POINT 430 71411WLLMTHIGHW INTERNATIONAL PAPER / RED RIVER MILL CAMPTI 430 42087WSTVCHIGHW WICKLIFFE PAPER CO WICKLIFFE

430 31402NNCMPWESTL INTERNATIONAL PAPER CO - SAVANNAH COMPLEX SAVANNAH 430 15845PNNTC100CE DOMTAR - JOHNSONBURG MILL JOHNSONBURG

430 98368PRTTW100PA PORT TOWNSEND PAPER CORP PORT TOWNSEND 430 97132SMRFTWYNOO SP NEWSPRINT CO LLC NEWBERG 430 29512WLLMTHWY91 DOMTAR PAPER CO BENNETTSVILLE

430 56649BSCSCSECON BOISE WHITE PAPER LLC INTERNATIONAL FALLS 430 35044SPLPNALABA ABIBOWUS INC COOSA PINES FACILITY COOSA PINES

430 31407STNCN1BONN WEYERHAEUSER NR PORT WENTWORTH PORT WENTWORTH 430 97348PPTLB30480 CASCADE PACIFIC PULP HALSEY PULP MILL HALSEY 430 32401STNCN1EVER SMURFIT-STONE CONTAINER CORP PANAMA CITY 430 29442NTRNTKAMIN INTERNATIONAL PAPER GEORGETOWN MILL GEORGETOWN 430 49829MDPBLCOUNT ESCANABA PAPER CO ESCANABA 430 98632LNGVWSOUTH LONGVIEWFIBRE PAPER & PACKAGING INC LONGVIEW

430 70775JMSRVENDOF KPAQ INDUSTRIES LLC ST FRANCISVILLE OPERATIONS SAINT FRANCISVILLE 430 3676WNTRNT76HIG INTERNATIONAL PAPER PINE HILL MILL PINE HILL

430 71247STNHDMILLS SMURFIT-STONE CONTAINER ENTERPRISES INC HODGE

430 16673PPLTN100PA APPLETON PAPERS INC ROARING SPRING 430 45601MDCRP401SP PH GLATFELTER CO - CHILLICOTHE FACILITY CHILLICOTHE 430 23860STNHP910IN ROCKTENN CP LLC HOPEWELL 430 49876CHMPNUSHIG VERSO QUINNESEC LLC QUINNESEC 430 98201SCTTP2600F KIMBERLY-CLARK WORLDWIDE EVERETT

430 97016JMSRVWAUNA GEORGIA PACIFIC CONSUMER PRODUCTS LP WAUNA MILL CLATSKANIE 430 31040STHSTSHADD SP NEWSPRINT CO LLC DUBLIN 430 37662MDPPRPOBOX DOMTAR PAPER CO LLC KINGSPORT MILL KINGSPORT 430 31068BCKYCOLDST WEYERHAEUSER NR CO OGLETHORPE

430 98607JMSRVNE4TH GEORGIA-PACIFIC CONSUMER PRODUCTS (CAMAS) LLC CAMAS

430 72110RKNSSHIGHW GREEN BAY PACKAGING INC ARKANSAS KRAFT DIV MORRILTON 430 97391GRGPCBUTLE GEORGIA-PACIFIC TOLEDO LLC TOLEDO430 54487NKSPCN9090 PACKAGING CORP OF AMERI CA TOMAHAWK

430 29502STNCNOLDGE SMURFIT-STONE CONTAINER CORP FLORENCE 430 24526NKSPCHIGHW GEORGIA-PACIFIC BIG ISLAND MILL BIG ISLAND 430 31206MCNKR4891M GRAPHIC PACKAGING INTERNATIONAL INC MACON 430 04457LNCLNKATAH LINCOLN PAPER & TISSUE LLC LINCOLN 430 97478WYRHS785N4 INTERNATIONAL PAPER SPRINGFIELD 430 28560WYRHSSTREE WEYERHAEUSER NR CO VANCEBORO 430 42348WLLMTPOBOX DOMTAR PAPER CO LLC HAWESVILLE MILL HAWESVILLE

430 04430GRTNRMAINS KATAHDIN PAPER CO LLC EAST MILLINOCKET 430 98421SMPSN801PO SIMPSON TACOMA KRAFT CO LLC TACOMA 430 54130THLMNTHILM THILMANY KAUKAUNA 430 35772MDCNTHIGHW SMURFIT-STONE CONT STEVENSON MILL STEVENSON 430 17362PHGLT228SO P H GLATFELTER CO - SPRING GROVE MILL SPRING GROVE 430 49634PCKGN2245U PACKAGING CORP OF AMERICA FILER CITY 430 54474WYRHS200GR DOMTAR PAPER CO LLC ROTHSCHILD 430 37134NLNDCCONAL TEMPLE-INLAND WA VERLY

430 71052NTRNTHWY50 INTERNATIONAL PAPER CO - MANSFIELD MILL MANSFIELD 430 55720PTLTCNORTH SAPPI CLOQUET LLC CLOQUET

430 32034TTRYNFOOTO RAYONIER PERFORMANCE FIBERS LLC FERNANDINA BEACH 430 31604NKSPCHIGHW PACKAGING CORP OF AMERICA CLYATTVILLE 430 54455MSNPP100MA WAUSAU PAPER MILLS LLC MOSINEE 430 54552FLMBP200NO FLAMBEAU RIVER PAPERS PARK FALLS

430 43812STNCN500N4 SMURFIT-STONE CONTAINER ENTERPRISES INC COSHOCTON 430 04416CHMPNMAINS VERSO PAPER BUCKSPORT MILL BUCKSPORT 430 04092SDWRR89CUM S D WARREN CO WESTBROOK 430 21540WSTVC300PR LUKE PAPER CO LUKE

430 54494CNSLDNASHR WATER QUALITY CENTER WISCONSIN RAPIDS

430 32034CNTNRNORTH SMURFIT-STONE CONTAINER ENTERP RISES INC FERNANDINA BEACH**Dioxin and Dioxin Compounds**

**State Chem ID**  **LBY TWPE**  **% of Total TWPE**  **PSC Code**  **TRI ID** AR N450 217349 15214.43 6% 430 98201SCTTP2600F AL N450 128600 9002 3% 430 04976SDWRRRFD3U

AL N450 110000 7700 3% 430 32034TTRYNFOOTO

GA N450 110000 7700 3% 430 98421SMPSN801PO AL N450 109000 7630 3% 430 12883NTRNTSHORE SC N450 101697 7118.79 3% 430 36916JMSRVROUTE ME N450 95000 6650 2% 430 98362DSHWMMARIN GA N450 94660 6626.2 2% 430 36545BSCSC307WE

LA N450 92000 6440 2% 430 36732GLFSTHIGHW TX N450 87657 6135.99 2% 430 71611NTRNTFAIRF TN N450 82820 5797.4 2% 430 71654PTLTCHIGHW GA N450 81950 5736.5 2% 430 28560WYRHSSTREE ME N450 80974 5668.18 2% 430 28456FDRLPRIEGE AL N450 70838 4958.66 2% 430 27962WYRHSTROWB ME N450 62714 4389.98 2% 430 37662MDPPRPOBOX MS N450 61000 4270 2% 430 32533CHMPN375MU AL N450 61000 4270 2% 430 32347BCKYCROUTE

MS N450 60572 4240.04 2% 430 23181CHSPK19THM

ME N450 59043 4133.01 2% 430 18629PRCTRROUTE

TN N450 59000 4130 2% 430 3676WNTRNT76HIG

NC N450 57798 4045.86 2% 430 31521BRNSW14W9T AR N450 56115 3928.05 1% 430 29442NTRNTKAMIN OK N450 53514 3745.98 1% 430 70634BSSTHUSHIG

MS N450 53225 3725.75 1% 430 31545TTRYNSAVAN SC N450 52343 3664.01 1% 430 35044SPLPNALABA GA N450 48823 3417.61 1% 430 42087WSTVCHIGHW

NC N450 47777 3344.39 1% 430 54308THPRC501EA ME N450 46600 3262 1% 430 49829MDPBLCOUNT

AL N450 46000 3220 1% 430 63702PRCTRPOBOX AL N450 45500 3185 1% 430 75504NTRNTPOBOX NY N450 44700 3129 1% 430 36426CNTNRHIGHW AL N450 43000 3010 1% 430 29704BWTRC5300C FL N450 42658 2986.06 1% 430 31407STNCN1BONN NC N450 42189 2953.23 1% 430 29044NNCMPROUTE AL N450 42000 2940 1% 430 54457NKSMLMARKE TX N450 38223 2675.61 1% 430 54474WYRHS200GRAR N450 38000 2660 1% 430 98607JMSRVNE4TH

LA N450 37400 2618 1% 430 31068BCKYCOLDST

FL N450 37237.64 2606.635 1% WI N450 36584 2560.88 1% GA N450 36000 2520 1%

NC N450 35674 2497.18 1% WA N450 35000 2450 1%

MS N450 34727 2430.89 1% NY N450 32498 2274.86 1%

VA N450 31164 2181.48 1% LA N450 30828 2157.96 1% KY N450 30493 2134.51 1%

GA N450 30150 2110.5 1% PA N450 30039 2102.73 1%

WA N450 30000 2100 1% OR N450 28259 1978.13 1% SC N450 28223 1975.61 1%

MN N450 28000 1960 1% AL N450 27786 1945.02 1%

GA N450 26852 1879.64 1% OR N450 26176 1832.32 1% FL N450 25231.8 1766.226 1% SC N450 24677 1727.39 1% MI N450 24529 1717.03 1% WA N450 24291 1700.37 1%

LA N450 23003 1610.21 1% AL N450 21749 1522.43 1%

LA N450 20800 1456 1%

PA N450 20449.52 1431.466 1% OH N450 19000 1330 0% VA N450 18333 1283.31 0% MI N450 18121.6 1268.512 0% WA N450 17645.8 1235.206 0%

OR N450 17000 1190 0% GA N450 16827 1177.89 0% TN N450 16532 1157.24 0% GA N450 16467 1152.69 0%

WA N450 15000 1050 0%

AR N450 15000 1050 0% OR N450 14810 1036.7 0%WI N450 12976 908.32 0%

SC N450 12640 884.8 0% VA N450 12200 854 0% GA N450 12171.6 852.012 0% ME N450 12043 843.01 0% OR N450 12000 840 0% NC N450 11095 776.65 0% KY N450 9520 666.4 0%

ME N450 8957 626.99 0% WA N450 8943 626.01 0% WI N450 8146 570.22 0% AL N450 7839 548.73 0% PA N450 7658 536.06 0% MI N450 7000 490 0% WI N450 6040.18 422.8126 0% TN N450 5100 357 0%

LA N450 4880 341.6 0% MN N450 4320 302.4 0%

FL N450 4300 301 0% GA N450 3300 231 0% WI N450 2300 161 0% WI N450 2012.15 140.8505 0%

OH N450 1568 109.76 0% ME N450 374 26.18 0% ME N450 342.8 23.996 0% MD N450 322.8 22.596 0%

WI N450 15 1.05 0%

FL N450 6.3 0.441 0% 266347.63 33**Facility Name City**  **State Chem ID** 

KIMBERLY-CLARK WORLDWIDE EVERETT WA N150 SD WARREN CO SKOWHEGAN ME N150

RAYONIER PERFORMANCE FIBERS LLC FERNANDINA BEACH FL N150

SIMPSON TACOMA KRAFT CO LLC TACOMA WA N150 INTERNATIONAL PAPER TICONDEROGA NY N150 GEORGIA-PACIFIC CONSUMER PRODUCTS LP PENNINGTON AL N150 NIPPON PAPER INDUSTRIES USA CO LTD PORT ANGELES WA N150 BOISE WHITE PAPER LLC JACKSON AL N150

ROCK-TENN MILL CO LLC DEMOPOLIS AL N150 EVERGREEN PACKAGING PINE BLUFF AR N150 CLEARWATER PAPER CORP ARKANSAS CITY AR N150 WEYERHAEUSER NR CO VANCEBORO NC N150 INTERNATIONAL PAPER RIEGELWOOD MILL RIEGELWOOD NC N150 DOMTAR PAPER CO LLC PLYMOUTH MILL PLYMOUTH NC N150 DOMTAR PAPER CO LLC KINGSPORT MILL KINGSPORT TN N150 INTERNATIONAL PAPER PENSACOLA MILL CANTONMENT FL N150 BUCKEYE FLORIDA LP PERRY FL N150

SMURFIT-STONE CONTAINER ENTERPRISES INC WEST POINT VA N150

THE PROCTER & GAMBLE PAPER PRODUCTS CO MEHOOPANY PA N150

INTERNATIONAL PAPER PINE HILL MILL PINE HILL AL N150

BRUNSWICK CELLULOSE INC BRUNSWICK GA N150 INTERNATIONAL PAPER GEORGETOWN MILL GEORGETOWN SC N150 BOISE PACKAGING & NEWSPRINT LLC DERIDDER LA N150

RAYONIER PERFORMANCE FIBERS JESUP MILL JESUP GA N150 ABIBOWUS INC COOSA PINES FACILITY COOSA PINES AL N150 WICKLIFFE PAPER CO WICKLIFFE KY N150

THE PROCTER & GAMBLE PAPER PRODUCTS CO GREEN BAY WI N150 ESCANABA PAPER CO ESCANABA MI N150

THE PROCTER & GAMBLE PAPER PRODUCTS CO JACKSON MO N150 INTERNATIONAL PAPER TEXARKANA MILL QUEEN CITY TX N150 GEORGIA-PACIFIC BREWTON LLC BREWTON AL N150 ABIBOWUS INC CATAWBA OPERATIONS CATAWBA SC N150 WEYERHAEUSER NR PORT WENTWORTH PORT WENTWORTH GA N150 INTERNATIONAL PAPER CO EASTOVER MILL EASTOVER SC N150 DOMTAR AWLLC NEKOOSA MILL NEKOOSA WI N150 DOMTAR PAPER CO LLC ROTHSCHILD WI N150GEORGIA-PACIFIC CONSUMER PRODUCTS

(CAMAS) LLC CAMAS WA N150 WEYERHAEUSER NR CO OGLETHORPE GA N150**LBY TWPE**  **% of Total TWPE**  0.001014126 67740.91 28% 0.000365747 42205.12 18%

0.016159443 38873.85 16%

0.001740109 27054.15 11% 0.001168891 12001.38 5% 0.007752996 10191.98 4% 8.75972E-05 9507.701 4% 0.005389861 4323.882 2%

0.002611596 4043.656 2% 0.004485746 3593.797 2% 0.000948839 3039.974 1% 0.003250571 2952.504 1% 0.008622103 2666.08 1% 0.007179354 2222.101 1% 0.00195528 1563.904 1% 0.00289467 1525.786 1% 0.000278061 1171.617 0%

0.000434289 670.5555 0%

5.03776E-05 655.7293 0%

0.006396272 404.5276 0%

0.000368392 227.9702 0% 0.001447114 209.6502 0% 0.000220021 174.0191 0%

2.9101E-07 112.3874 0% 0.000660946 94.77717 0% 9.76163E-05 78.25287 0%

3.79585E-06 74.97112 0% 0.001675548 72.39441 0%

7.49572E-06 67.55206 0% 0.002462563 66.16279 0% 0.006625552 43.63324 0% 0.005789339 38.12627 0% 0.003108738 20.47291 0% 0.000277342 2.542114 0% 0.00031426 2.069589 0% 5.8299E-05 0.383934 0%5.73202E-06 0.232574 0%

1.7637E-06 0.011615 0%

0.095910737 237694.81

7101617 0.09489661 169953.9**40 CFR Part 430 - Pulp and Paper**

**TRI Dioxin Discharges**

**Dioxin and Dioxin Compounds**

**TRI ID Facility Name**  **City State**  **Chem ID TWPE**  **% of TRI Dioxin TWPE** 

98201SCTTP2600F KIMBERLY-CLARK WORLDWIDE EVERETT WA N150 67,740.91 28%

04976SDWRRRFD3U SD WARREN CO SKOWHEGAN ME N150 42,205.12 18%

32034TTRYNFOOTO RAYONIER PERFORMANCE FIBERS LLC FERNANDINA BEACH FL N150 38,873.85 16%

98421SMPSN801PO SIMPSON TACOMA KRAFT CO LLC TACOMA WA N150 27,054.15 11%**Notes from Screening Level Review**

Facility was shut down in April 2012 and mass balances based on historical congener data were used to estimate their TRI dioxin discharges. No further action necessary

. The calculation process for 2011 was the same as previous years. The concentration data obtained in 2002 was applied to the annual flow rate and then we made corrections for the naturally occurring congers ( i.e. OCDD, HpCDD and OCDF ) contained in the mill’s receiving water, pulp wood and kaolin clay. Facility confirmed discharges in the 2011 ARR. No further action necessary

. 2011 data was confirmed, discharges have decreased since 2009. The data is based on quarterly measurements, using 0 for BDL results. No further action necessary

. Facility provided 2012 data and confirmed 2011 data. TWPE has decreased since 2009, no significant facility changes. No further action necessary

.**Pulp and Paper TRI Manganese Data**

From TRI Database: TSD 04 - Facility Discharges

**Ma nganese and Manganese Compounds** 

**PSC Code TRI ID**  **Facility Name City**  **State Chem ID**  430 71822NKSPPHIGHW DOMTAR AWLLC ASHDOWN MILL ASHDOWN AR N450 430 35618CHMPNPOBOX INTERNATIONAL PAPER COURTLAND MILL COURTLAND AL N450

430 36916JMSRVROUTE GEORGIA-PACIFIC CONSUMER PRODUCTS LP PENNINGTON AL N450

430 31545TTRYNSAVAN RAYONIER PERFORMANCE FIBERS JESUP MILL JESUP GA N450 430 36470LBMRVOFFHI ALABAMA RIVER CELLULOSE LLC PERDUE HILL AL N450 430 29704BWTRC5300C ABIBOWUS INC CATAWBA OPERATIONS CATAWBA SC N450 430 04976SDWRRRFD3U SD WARREN CO SKOWHEGAN ME N450 430 31521BRNSW14W9T BRUNSWICK CELLULOSE INC BRUNSWICK GA N450

430 70791GRGPCZACHA GEORGIA-PACIFIC CONSUMER PRODUCTS LLC ZACHARY LA N450 430 77656PLPPPPOBOX MEADWESTVACO TEXAS LP EVADALE TX N450 430 37309BWTRSROUTE ABIBOWUS INC - CALHOUN OPERATIONS CALHOUN TN N450 430 30913FDRLPHIGHW INTERNATIONAL PAPER - AUGUSTA MILL AUGUSTA GA N450 430 04239NTRNTRILEY VERSO PAPER HOLDINGS LLC JAY ME N450 430 36426CNTNRHIGHW GEORGIA-PACIFIC BREWTON LLC BREWTON AL N450 430 04276BSCSCROUTE RUMFORD PAPER CO RUMFORD ME N450 430 39703CLMBSCARSO COLUMBUS CELLULOSE FIBERS COLUMBUS MS N450 430 36701HMMRMRIVER INTERNATIONAL PAPER - RIVERDALE MILL SELMA AL N450 430 39654GRGPCSANDI GEORGIA-PACIFIC MONTICELLO LL C MONTICELLO MS N450 430 04694GRGPCMILLA WOODLAND PULP LLC BAILEYVILLE ME N450

430 38326TNNSSHIGHW PACKAGING CORP OF AMERICA COUNCE MILL COUNCE TN N450

430 28716CHMPNMAINS BLUE RIDGE PAPER PRODUCTS INC (DBA EVERGREEN PACKAGING) CANTON NC N450

430 71654PTLTCHIGHW CLEARWATER PAPER CORP ARKANSAS CITY AR N450 430 74764WYRHSHIGHW INTERNATIONAL PAPER CO VALLIANT OK N450 430 39180NTRNTPOBOX INTERNATIONAL PAPER - VICKSBUR G MILL REDWOOD MS N450 430 29044NNCMPROUTE INTERNATIONAL PAPER CO EASTOVER MILL EASTOVER SC N450

430 31732GRTSTHIGHW GEORGIA PACIFIC CEDAR SPRINGS LLC CEDAR SPRINGS GA N450 430 28456FDRLPRIEGE INTERNATIONAL PAPER RIEGELWOOD MILL RIEGELWOOD NC N450430 04468JMSRVPORTL RED SHIELD ACQUISITION LLC OLD TOWN ME N450

430 36067NNCMP100JE INTERNATIONAL PAPER PRATTVILLE AL N450 430 36545BSCSC307WE BOISE WHITE PAPER LLC JACKSON AL N450 430 12801FNCHP1GLEN FINCH PAPER LLC GLENS FALLS NY N450 430 36868MDCTDALABA MEADWESTVACO COATED BOARD INC COTTONTON AL N450 430 32533CHMPN375MU INTERNATIONAL PAPER PENSACOLA MILL CANTONMENT FL N450 430 27962WYRHSTROWB DOMTAR PAPER CO LLC PLYMOUTH MILL PLYMOUTH NC N450 430 36732GLFSTHIGHW ROCK-TENN MILL CO LLC DEMOPOLIS AL N450 430 75504NTRNTPOBOX INTERNATIONAL PAPER TEXARKANA MILL QUEEN CITY TX N450 430 71611NTRNTFAIRF EVERGREEN PACKAGING PINE BLUFF AR N450 430 70634BSSTHUSHIG BOISE PACKAGING & NEWSPRINT LLC DERIDDER LA N450 430 32347BCKYCROUTE BUCKEYE FLORIDA LP PERRY FL N450 430 54457NKSMLMARKE DOMTAR AWLLC NEKOOSA MILL NEKOOSA WI N450 430 30162NLNDR238MA TEMPLE-INLAND ROME LINERBOARD MILL ROME GA N450

430 27870CHMPNNORTH KAPSTONE KRAFT PAPER CORP ROANOKE RAPIDS NC N450 430 98632WYRHS3401I WEYERHAEUSER NR CO - LONGVIEW LONGVIEW WA N450

430 38901NWSPRPAPER BOWATER NEWSPRINT SOUTH OPERATIONS LLC GRENADA MS N450 430 12883NTRNTSHORE INTERNATIONAL PAPER TICONDEROGA NY N450

430 23181CHSPK19THM SMURFIT-STONE CONTAINER ENTERPRISES INC WEST POINT VA N450 430 71411WLLMTHIGHW INTERNATIONAL PAPER / RED RIVER MILL CAMPTI LA N450 430 42087WSTVCHIGHW WICKLIFFE PAPER CO WICKLIFFE KY N450

430 31402NNCMPWESTL INTERNATIONAL PAPER CO - SAVANNAH COMPLEX SAVANNAH GA N450 430 15845PNNTC100CE DOMTAR - JOHNSONBURG MILL JOHNSONBURG PA N450

430 98368PRTTW100PA PORT TOWNSEND PAPER CORP PORT TOWNSEND WA N450 430 97132SMRFTWYNOO SP NEWSPRINT CO LLC NEWBERG OR N450

430 29512WLLMTHWY91 DOMTAR PAPER CO BENNETTSVILLE SC N450

430 56649BSCSCSECON BOISE WHITE PAPER LLC INTERNATIONAL FALLS MN N450 430 35044SPLPNALABA ABIBOWUS INC COOSA PINES FACILITY COOSA PINES AL N450

430 31407STNCN1BONN WEYERHAEUSER NR PORT WENTWORTH PORT WENTWORTH GA N450

430 97348PPTLB30480 CASCADE PACIFIC PULP HALSEY PULP MILL HALSEY OR N450 430 32401STNCN1EVER SMURFIT-STONE CONTAINER CORP PANAMA CITY FL N450 430 29442NTRNTKAMIN INTERNATIONAL PAPER GEORGETOWN MILL GEORGETOWN SC N450430 49829MDPBLCOUNT ESCANABA PAPER CO ESCANABA MI N450

430 98632LNGVWSOUTH LONGVIEWFIBRE PAPER & PACKAGING INC LONGVIEW WA N450

430 70775JMSRVENDOF KPAQ INDUSTRIES LLC ST FRANCISVILLE OPERATIONS SAINT FRANCISVILLE LA N450 430 3676WNTRNT76HIG INTERNATIONAL PAPER PINE HILL MILL PINE HILL AL N450

430 71247STNHDMILLS SMURFIT-STONE CONTAINER ENTERPRISES INC HODGE LA N450

430 16673PPLTN100PA APPLETON PAPERS INC ROARING SPRING PA N450 430 45601MDCRP401SP PH GLATFELTER CO - CHILLICOTHE FACILITY CHILLICOTHE OH N450 430 23860STNHP910IN ROCKTENN CP LLC HOPEWELL VA N450 430 49876CHMPNUSHIG VERSO QUINNESEC LLC QUINNESEC MI N450 430 98201SCTTP2600F KIMBERLY-CLARK WORLDWIDE EVERETT WA N450

430 97016JMSRVWAUNA GEORGIA PACIFIC CONSUMER PRODUCTS LP WAUNA MILL CLATSKANIE OR N450 430 31040STHSTSHADD SP NEWSPRINT CO LLC DUBLIN GA N450 430 37662MDPPRPOBOX DOMTAR PAPER CO LLC KINGSPORT MILL KINGSPORT TN N450 430 31068BCKYCOLDST WEYERHAEUSER NR CO OGLETHORPE GA N450

430 98607JMSRVNE4TH GEORGIA-PACIFIC CONSUMER PRODUCTS (CAMAS) LLC CAMAS WA N450

430 72110RKNSSHIGHW GREEN BAY PACKAGING INC ARKANSAS KRAFT DIV MORRILTON AR N450 430 97391GRGPCBUTLE GEORGIA-PACIFIC TOLEDO LLC TOLEDO OR N450 430 54487NKSPCN9090 PACKAGING CORP OF AMERI CA TOMAHAWK WI N450 430 29502STNCNOLDGE SMURFIT-STONE CONTAINER CORP FLORENCE SC N450 430 24526NKSPCHIGHW GEORGIA-PACIFIC BIG ISLAND MILL BIG ISLAND VA N450 430 31206MCNKR4891M GRAPHIC PACKAGING INTERNATIONAL INC MACON GA N450 430 04457LNCLNKATAH LINCOLN PAPER & TISSUE LLC LINCOLN ME N450 430 97478WYRHS785N4 INTERNATIONAL PAPER SPRINGFIELD OR N450 430 28560WYRHSSTREE WEYERHAEUSER NR CO VANCEBORO NC N450 430 42348WLLMTPOBOX DOMTAR PAPER CO LLC HAWESVILLE MILL HAWESVILLE KY N450

430 04430GRTNRMAINS KATAHDIN PAPER CO LLC EAST MILLINOCKET ME N450 430 98421SMPSN801PO SIMPSON TACOMA KRAFT CO LLC TACOMA WA N450 430 54130THLMNTHILM THILMANY KAUKAUNA WI N450 430 35772MDCNTHIGHW SMURFIT-STONE CONT STEVENSON MILL STEVENSON AL N450 430 17362PHGLT228SO P H GLATFELTER CO - SPRING GROVE MILL SPRING GROVE PA N450 430 49634PCKGN2245U PACKAGING CORP OF AMERICA FILER CITY MI N450 430 54474WYRHS200GR DOMTAR PAPER CO LLC ROTHSCHILD WI N450 430 37134NLNDCCONAL TEMPLE-INLAND WA VERLY TN N450430 71052NTRNTHWY50 INTERNATIONAL PAPER CO - MANSFIELD MILL MANSFIELD LA N450

430 55720PTLTCNORTH SAPPI CLOQUET LLC CLOQUET MN N450

430 32034TTRYNFOOTO RAYONIER PERFORMANCE FIBERS LLC FERNANDINA BEACH FL N450 430 31604NKSPCHIGHW PACKAGING CORP OF AMERICA CLYATTVILLE GA N450 430 54455MSNPP100MA WAUSAU PAPER MILLS LLC MOSINEE WI N450 430 54552FLMBP200NO FLAMBEAU RIVER PAPERS PARK FALLS WI N450

430 43812STNCN500N4 SMURFIT-STONE CONTAINER ENTERPRISES INC COSHOCTON OH N450 430 04416CHMPNMAINS VERSO PAPER BUCKSPORT MILL BUCKSPORT ME N450 430 04092SDWRR89CUM S D WARREN CO WESTBROOK ME N450 430 21540WSTVC300PR LUKE PAPER CO LUKE MD N450

430 54494CNSLDNASHR WATER QUALITY CENTER WISCONSIN RAPIDS WI N450

430 32034CNTNRNORTH SMURFIT-STONE CONTAINER ENTERP RISES INC FERNANDINA BEACH FL N450**Chemical LBY**  **TWPE % of Total**  **TWPE** MANGANESE AND MANGANESE COMPOUNDS 217349 15214.43 6% MANGANESE AND MANGANESE COMPOUNDS 128600 9002 3%

MANGANESE AND MANGANESE COMPOUNDS 110000 7700 3%

MANGANESE AND MANGANESE COMPOUNDS 110000 7700 3% MANGANESE AND MANGANESE COMPOUNDS 109000 7630 3% MANGANESE AND MANGANESE COMPOUNDS 101697 7118.79 3% MANGANESE AND MANGANESE COMPOUNDS 95000 6650 2% MANGANESE AND MANGANESE COMPOUNDS 94660 6626.2 2%

MANGANESE AND MANGANESE COMPOUNDS 92000 6440 2% MANGANESE AND MANGANESE COMPOUNDS 87657 6135.99 2% MANGANESE AND MANGANESE COMPOUNDS 82820 5797.4 2% MANGANESE AND MANGANESE COMPOUNDS 81950 5736.5 2% MANGANESE AND MANGANESE COMPOUNDS 80974 5668.18 2% MANGANESE AND MANGANESE COMPOUNDS 70838 4958.66 2% MANGANESE AND MANGANESE COMPOUNDS 62714 4389.98 2% MANGANESE AND MANGANESE COMPOUNDS 61000 4270 2% MANGANESE AND MANGANESE COMPOUNDS 61000 4270 2% MANGANESE AND MANGANESE COMPOUNDS 60572 4240.04 2% MANGANESE AND MANGANESE COMPOUNDS 59043 4133.01 2%

MANGANESE AND MANGANESE COMPOUNDS 59000 4130 2%

MANGANESE AND MANGANESE COMPOUNDS 57798 4045.86 2%

MANGANESE AND MANGANESE COMPOUNDS 56115 3928.05 1% MANGANESE AND MANGANESE COMPOUNDS 53514 3745.98 1% MANGANESE AND MANGANESE COMPOUNDS 53225 3725.75 1% MANGANESE AND MANGANESE COMPOUNDS 52343 3664.01 1%

MANGANESE AND MANGANESE COMPOUNDS 48823 3417.61 1% MANGANESE AND MANGANESE COMPOUNDS 47777 3344.39 1%MANGANESE AND MANGANESE COMPOUNDS 46600 3262 1%

MANGANESE AND MANGANESE COMPOUNDS 46000 3220 1% MANGANESE AND MANGANESE COMPOUNDS 45500 3185 1% MANGANESE AND MANGANESE COMPOUNDS 44700 3129 1% MANGANESE AND MANGANESE COMPOUNDS 43000 3010 1% MANGANESE AND MANGANESE COMPOUNDS 42658 2986.06 1% MANGANESE AND MANGANESE COMPOUNDS 42189 2953.23 1% MANGANESE AND MANGANESE COMPOUNDS 42000 2940 1% MANGANESE AND MANGANESE COMPOUNDS 38223 2675.61 1% MANGANESE AND MANGANESE COMPOUNDS 38000 2660 1% MANGANESE AND MANGANESE COMPOUNDS 37400 2618 1% MANGANESE AND MANGANESE COMPOUNDS 37237.64 2606.635 1% MANGANESE AND MANGANESE COMPOUNDS 36584 2560.88 1% MANGANESE AND MANGANESE COMPOUNDS 36000 2520 1%

MANGANESE AND MANGANESE COMPOUNDS 35674 2497.18 1% MANGANESE AND MANGANESE COMPOUNDS 35000 2450 1%

MANGANESE AND MANGANESE COMPOUNDS 34727 2430.89 1% MANGANESE AND MANGANESE COMPOUNDS 32498 2274.86 1%

MANGANESE AND MANGANESE COMPOUNDS 31164 2181.48 1% MANGANESE AND MANGANESE COMPOUNDS 30828 2157.96 1% MANGANESE AND MANGANESE COMPOUNDS 30493 2134.51 1%

MANGANESE AND MANGANESE COMPOUNDS 30150 2110.5 1% MANGANESE AND MANGANESE COMPOUNDS 30039 2102.73 1%

MANGANESE AND MANGANESE COMPOUNDS 30000 2100 1% MANGANESE AND MANGANESE COMPOUNDS 28259 1978.13 1%

MANGANESE AND MANGANESE COMPOUNDS 28223 1975.61 1%

MANGANESE AND MANGANESE COMPOUNDS 28000 1960 1% MANGANESE AND MANGANESE COMPOUNDS 27786 1945.02 1%

MANGANESE AND MANGANESE COMPOUNDS 26852 1879.64 1%

MANGANESE AND MANGANESE COMPOUNDS 26176 1832.32 1% MANGANESE AND MANGANESE COMPOUNDS 25231.8 1766.226 1% MANGANESE AND MANGANESE COMPOUNDS 24677 1727.39 1%MANGANESE AND MANGANESE COMPOUNDS 24529 1717.03 1%

MANGANESE AND MANGANESE COMPOUNDS 24291 1700.37 1%

MANGANESE AND MANGANESE COMPOUNDS 23003 1610.21 1% MANGANESE AND MANGANESE COMPOUNDS 21749 1522.43 1%

MANGANESE AND MANGANESE COMPOUNDS 20800 1456 1%

MANGANESE AND MANGANESE COMPOUNDS 20449.52 1431.466 1% MANGANESE AND MANGANESE COMPOUNDS 19000 1330 0% MANGANESE AND MANGANESE COMPOUNDS 18333 1283.31 0% MANGANESE AND MANGANESE COMPOUNDS 18121.6 1268.512 0% MANGANESE AND MANGANESE COMPOUNDS 17645.8 1235.206 0%

MANGANESE AND MANGANESE COMPOUNDS 17000 1190 0% MANGANESE AND MANGANESE COMPOUNDS 16827 1177.89 0% MANGANESE AND MANGANESE COMPOUNDS 16532 1157.24 0% MANGANESE AND MANGANESE COMPOUNDS 16467 1152.69 0%

MANGANESE AND MANGANESE COMPOUNDS 15000 1050 0%

MANGANESE AND MANGANESE COMPOUNDS 15000 1050 0% MANGANESE AND MANGANESE COMPOUNDS 14810 1036.7 0% MANGANESE AND MANGANESE COMPOUNDS 12976 908.32 0% MANGANESE AND MANGANESE COMPOUNDS 12640 884.8 0% MANGANESE AND MANGANESE COMPOUNDS 12200 854 0% MANGANESE AND MANGANESE COMPOUNDS 12171.6 852.012 0% MANGANESE AND MANGANESE COMPOUNDS 12043 843.01 0% MANGANESE AND MANGANESE COMPOUNDS 12000 840 0% MANGANESE AND MANGANESE COMPOUNDS 11095 776.65 0% MANGANESE AND MANGANESE COMPOUNDS 9520 666.4 0%

MANGANESE AND MANGANESE COMPOUNDS 8957 626.99 0% MANGANESE AND MANGANESE COMPOUNDS 8943 626.01 0% MANGANESE AND MANGANESE COMPOUNDS 8146 570.22 0% MANGANESE AND MANGANESE COMPOUNDS 7839 548.73 0% MANGANESE AND MANGANESE COMPOUNDS 7658 536.06 0% MANGANESE AND MANGANESE COMPOUNDS 7000 490 0% MANGANESE AND MANGANESE COMPOUNDS 6040.18 422.8126 0% MANGANESE AND MANGANESE COMPOUNDS 5100 357 0%MANGANESE AND MANGANESE COMPOUNDS 4880 341.6 0%

MANGANESE AND MANGANESE COMPOUNDS 4320 302.4 0%

MANGANESE AND MANGANESE COMPOUNDS 4300 301 0% MANGANESE AND MANGANESE COMPOUNDS 3300 231 0% MANGANESE AND MANGANESE COMPOUNDS 2300 161 0% MANGANESE AND MANGANESE COMPOUNDS 2012.15 140.8505 0%

MANGANESE AND MANGANESE COMPOUNDS 1568 109.76 0% MANGANESE AND MANGANESE COMPOUNDS 374 26.18 0% MANGANESE AND MANGANESE COMPOUNDS 342.8 23.996 0% MANGANESE AND MANGANESE COMPOUNDS 322.8 22.596 0%

MANGANESE AND MANGANESE COMPOUNDS 15 1.05 0%

MANGANESE AND MANGANESE COMPOUNDS 6.3 0.441 0% 266347.6