# west virginia department of environmental protection

Division of Water and Waste Management

60 I 57th Street SE

Charleston, West Virginia 25304-2345

Phone: 304-926-0495

Fax: 304-926-0496



# PATRICK SMITH

MOUNTAIN STATE CARBON, LLC

1851 MAIN ST

FOLLANSBEE, WV 26037

And

STEVEN W. SORVOLD, DIRECTOR August 29, 2013

WHEELING PITTSBURGH STEEL CORP (Operator)

ENVIRONMENTAL CONTROL DEPT

1134 MARKET STREET

WHEELING, WV 26003-2971 Earl Ray Tomblin, Governor

Randy C. Huffman, Cabinet Secretary



# www.dep.wv.gov

CERTIFIED RETURN RECEIPT REQUESTED

Dear Permittee:

Enclosed please find WV/NPDES Permit Number WV0004499 dated August 29, 2013.

Mountain State Carbon's (MSC) comments were received by letter dated March 22, 2013. The following is

the agency's response to these comments regarding the draft permit that went to public notice on February 8,

2013.

Comment No. I : Production Rate and TBELs

The agency believes that use of the maximum 12 month rolling average production value is appropriate and

therefore no revision to the permit has been made.

Comment No.2: Section 301(g) variance limits

The agency has revised the WQBEL for ammonia at Outlet 006 since a water supply intake is not located

downstream of the discharge. Due to this change the 30i(g) variance has been adjusted based on the revised

WQBEL for ammonia. Section A.006 of the permit has been revised accordingly.

Comment No. 3 : Outlet 006 truncated mixing zone and use of Outlet 005 monitoring data



# Promoting a healthy environment

# PATRICK SMITH

Page2

August 29, 2013

The agency believes that limiting the size of mixing zones is critical in minimizing the potential for adverse

impacts within the mixing zone. As such, the agency limits the size of the mixing zones granted based on

what the discharge actually needs in order to be compliant. In limiting the size of the mixing zone being

granted to what is needed, the agency is limiting the potential for adverse impacts to aquatic life and human

health within the receiving stream. The agency further believes that this is consistent with antidegradation

requirements prescribed in 60 CSR 5 of the WV Legislative Rules which were prescribed to limit degradation

to receiving streams in the state. No revision to the mixing zone has been made.

The agency believes that use of Outlet 005 monitoring data is appropriate in assessing effluent quality at

Outlet 006. No data was submitted with the permit application for Outlet 006. As such, the permit writer used

all available data to determine whether reasonable potential to exceed water quality was present. Many of the

parameters listed at former Outlet 005 were imposed due to the presence ofthe process wastewater from

Internal Outlet 205 since cooling water and sanitary sewage would only serve to dilute the concentrations of

pollutants introduced by Internal Outlet 205. Therefore, it is reasonable to assume reasonable potential exists

at Outlet 006 if reasonable potential existed at former Outlet 005. No revision to the reasonable potential

evaluation or Section A.006 of the permit has been made.

Comment No.4 :Outlet 006 ammonia, WAD cyanide, total residual chlorine, mercury, PAHs

As stated above, the ammonia WQBEL has been revised.

As stated above, the agency believes limiting mixing zones to what is necessary prevents greater impacts to

aquatic life and human health in the environment within the mixing zone and that the use of Outlet 005 DMR

data for Outlet 006 reasonable potential evaluations is appropriate for cyanide, total residual chlorine,

mercury, and PAHs. No revisions have been made.

Comment No.5 :Outlet 006 Schedule of Compliance (Nitrite-N, Total Cyanide, WAD Cyanide, Phenolics,

Mercury, Selenium)

Outlet 006 was constructed as the permittee's selected compliance solution for past violations and/or

compliance issues in the permit for multiple parameters as required by Administrative Consent Order No.

7160. The permittee believed that separating the process wastewater from Outlet 005 and obtaining a site

specific mixing zone was the resolution needed to achieve full compliance with WV/NPDES Permit No.

WV0004499. The agency therefore fully expects the permittee to comply with all final effluent limitations at

Outlet 006.

# PATRICK SMITH

Page3

August 29, 2013

ORSANCO contains a prohibition on mixing zones for bioaccumulative chemicals of concern (BCCs) which

includes mercury. All mixing zones for existing discharges ofBCCs are required to be eliminated as soon as

possible, but no later than October 16, 2013. Effluent data from former Outlet 005 reveals that mercury

exhibits the reasonable potential to exceed water quality criteria at the end of pipe and water quality based

effluent limitations are imposed at Outlet 006. Effluent data indicates that the permittee cannot currently

achieve these limitations and a compliance schedule has been granted consistent with ORSANCO's deadline

for the elimination of mixing zones. The agency does not have the authority to grant a variance or extend

time to meet the ORSANCO requirements. If a pollutant is in the discharge at levels that reflect reasonable

potential to exceed water quality criteria, then water quality based limitations are required by law. At the

time of this permit issuance, the permittee has not obtained a variance from ORSANCO and the BCC

prohibition must be imposed accordingly. The agency envisions addressing any future compliance issues

with the

final mercury limits through an enforcement action.

Comment No. 6 : Outlet 006 Monitoring Requirements

The agency believes the monitoring frequencies imposed at Outlet 006 are appropriate. As stated above, it is

reasonable to assume the concentrations at Outlet 006 will be the same or greater in magnitude than

concentrations observed at former Outlet 005 due to separation of the outlets. Therefore, no revisions have

been made. After collection of a minimum number of data points, the permittee may request via the permit

modification process that the monitoring frequency be reduced if the resultant data supports the rationale for

such a reduction.

Comment No. 7 : References to 205, 305, and 005 and Section C.33

At the time of public notice of the draft permit, the permittee had not made the agency aware that the

reconfiguration of the process wastewater discharge from Outlet 205 to Outlet 006 was complete and

discharge had been initiated. As such, the draft permit included Outlets 205, 305, and 005. Section A.205,

A.305, and A.005 have been deleted from the final permit and references to these outlets have been removed,

where appropriate, in Sections B and C of the permit.

Comment No. 8 : Outlet 004 TSS, fecal coliform, and temperature

The TSS limit is a net limit and therefore the intake portion ofTSS in the Outlet 004 discharge should not

affect compliance with the imposed limitation. No revision has been made.

For the reasons stated above, the agency believes the fecal coliform limitations are appropriate. No data has

been submitted indicating the sanitary sewage plant was the sole source of fecal coliform at former Outlet

005 and that there will cease to be a discharge of fecal coliform at Outlet 006. As such, no revision has been

made. After collection of a minimum number of data points the permittee may request via the permit

modification process that frequency be reduced if the resultant data supports the rationale for such a

reduction.

# PATRICK SMITH

Page4

August 29, 2013

The temperature limitations imposed at Outlet 004 are protective of both WV (47 CSR 2 Appendix E 8.29.4)

and ORSANCO water quality criteria. A default mixing zone was granted for temperature at this outlet since

background temperature data was available for the Ohio River. Contrary to the comment letter the agency

cannot grant any higher dilutions in the Ohio River without submittal of a site specific mixing zone study for

this outlet. Also contrary to the comment letter, the permittee has not performed a biological habitat study in

the vicinity of Outlet 004 and therefore the agency cannot make a determination on what if any thermal

impacts are present in the Ohio River directly attributable to the Outlet 004 discharge. The agency believes

the limitations are appropriate and no revision to the draft permit was made. The permittee may pursue a site

specific mixing zone and/or 316(a) thermal variance if it so desires and submit a permit modification request

in the future with the appropriate supporting rationale. If the permittee elects to pursue a 316(a) thermal

variance, the agency strongly recommends that the permittee first discuss this with the agency to

ensure that all of the proper information is collected and provided.

Comment No. 9 : 

# Outlet 004 Monitoring Requirements

The agency believes the monitoring frequencies imposed at Outlet 004 are appropriate. No revisions have

been made. After collection of a minimum number of data points, the permittee may request via the permit

modification process that frequency be reduced if the resultant data supports the rationale for such a

reduction.

Comment No. 10: Sections C.30 and C.31

Sections C.30 and C.31 have been revised to reflect that the permittee will perform a dye tracer study to

verify the granted site specific mixing zone at Outlet 006. However, this still requires some sampling for

other pollutants for verification purposes.

Comment No. II : Section D- Intake Requirements

The agency believes the intake requirements are consistent with 316(b) of the Clean Water Act and therefore

no revision was made.

Comment No. 12 : Section B. 

# Schedule of Compliance

The agency believes the revised schedule of compliance in Section B of the permit is appropriate and no

revisions have been made.

Comment No. 13 : Section C.l7

Section C.l7 has been revised to indicate that Method OIA 1677 is an allowable method for analysis of free

cyanide. The permittee may not however omit a free cyanide analysis when a total cyanide result is less than

0.005 mg/1.

Comment No. 14 : Section C.29

# PATRICK SMITH

PageS

August 29, 2013

The agency agrees that the current sampling point satisfies Section C.29; however, to ensure that any changes

to the intake configuration do not affect the collection of representative samples, no revision has been made

to the permit.

Comment No. 15 :Section C.32

Based on the request in the comment letter, Section C.32 has been revised to allow up to 60 minutes between

intake and effluent samples.

Comment No. 17 : Outlet 097 Monitoring Requirements

The agency believes the monitoring frequencies imposed at Outlet 097 are appropriate. After collection of a

minimum number of data points the permittee may request via the permit modification process that frequency

be reduced if the resultant data supports the rationale for such a reduction.

Please note that a Discharge Monitoring Report (DMR) is to be completed and submitted to this Division

each month.

Finally note that copies of all future correspondence regarding the permit must be forwarded to the Field

Inspector and Field Supervisor at the following address:

Department of Environmental Protection

Environmental Enforcement

601 57th St.

Charleston, WV 25304

Also, please note the attachment to this permit which describes the annual permit fee requirement.

Reissuance of your permit does not change the annual fee billing cycle.

If you have any questions, please contact John Lockhart, P.E. of this Division at (304) 926-0499 at

extension 1028.

# ,a~

Director

SGM:jl

Enclosures

# STATE OF WEST VIRGINIA

DEPARTMENT OF ENVIRONMENTAL PROTECTION

DIVISION OF WATER AND WASTE MANAGEMENT

601 57TH STREET SE

CHARLESTON, WV 25304-2345

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

WATER POLLUTION CONTROL PERMIT

NPDES PERMIT NO.: WV0004499

SUBJECT: Industrial Waste

LOCATION: FOLLANSBEE

(City)

See the next page for a list of Outlets.

TO WHOM IT MAY CONCERN: Brooke

(County)

This is to certify that: MOUNTAIN STATE CARBON, LLC

1851 MAIN ST

FOLLANSBEE, WV 26037

And ISSUE DATE: August 

# 29, 2013

EFFECTIVE DATE : October 

# 01. 2013

EXPIRATION DATE: June 

# 30, 2017

SUPERSEDES: Permit No. 

# WV0004499

daled January 

# 15. 2008

Upper Ohio River 1

(Drainage Basin)

WHEELING PITTSBURGH STEEL CORP (OPERATOR)

ENVIRONMENTAL CONTROL DEPT

1134 MARKET STREET

WHEELING, WV 26003-2971

are hereby granted a West Virginia NPDES Water Pollution Control Permit to:



# Operate and maintain treatment and disposal systems and best management practices for the direct dischatge of

treated process wastes, groundwater, and storm water through Outlet 006 into the Ohio River at approximate

milepoint 68.7.

Operate and maintain treatment and disposal systems and best management practices for the direct dischatge of

treated sanitary waste, untreated storm water, untreated non-contact cooling water, and untreated boiler

blowdown through Outlet 004 into the Ohio River at approximately milepoint 68.85.

Also to operate and maintain disposal systems and best management practices for the direct dischatge of

untreated drains from freeze protection lines for the river water through Outlets 008 and 009 into the Ohio River

at approximately Milepoint 68.9.

Also to operate and maintain an intake system (Outlet 097) for the withdrawal of water from the Ohio River.

This permit is subject to the following terms and conditions :



# The information submitted on and with Permit Application No. WV0004499 dated the 28th day of March 2012

and subsequent information submitted the 7th day of September 2012 are hereby made terms and conditions of

this Permit with like effect as if all such permit application information were set forth herein and with other

conditions set forth in Sections A, B, C, and Appendix A.

# Page No.: 2 of 46

Permit No. : VIN0004499



# The validity of this permit is contingent upon the payment of the applicable annual permit fee, as

required by Chapter 22, Article 11, Section 10 ofthe Code of West Virginia.PageNo.: 3of46PermitNo.:WV0004499llnspectableUnTtli--H-ULatitudeIILongitude!!ReceivingStreamI,------·,...DisttoStreamIIMilepostMnnthtinMile)00440°20'47"80°36'33"OHIORVN/A68.8500640°20'47"80°36'33"OHIORVN/A68.700840°20'44"80°36'33"OHIORV--NoMonitoringRequiredN/A68.900940°20'44"80°36'33"OHIORV-NoMonitoringRequiredN/A68.909740°20'40"80°36'24"OHIORVN/AN/A10540°21'10"80°36'30"OHIORVN/AN/AIA.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 9/30/2015 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units **Freguen~** Im!!

Flow, in Conduit or thru plant NIA NIA N/A N/A Rpt Only Rpt Only mgd 1/week measured

(Year Round) (ML-1) Avg. Monthly Max. Daily

Total Suspended Solids NIA N/A N/A N/A Rpt Only 60 mg/1 1/month 24 hr Composite

(Year Round) (ML-2) Avg. Monthly Max. Daily

Coliform, Fecal NIA N/A NIA NIA 200 400 Cnts/100ml 1/month Grab

(Year Round) (ML-1) Mon. Geo. Mean Max. Daily

pH N/A N/A NIA 6 N/A 9 s.u. 1/month Grab

(Year Round) (ML-1) lost. Min. lnsl Max.

Ammonia Nitrogen N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Nitrogen, Total (as N) Rpt Only Rpt Only Lbs/Day NIA RptOnly Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Phosphorus, Total Rpt Only RptOnly Lbs/Day N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Chlorine, Total Residual NIA N/A N/A NIA Rptonly Rpt Only ugA 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location{s):

Outlet 004 (Previously Internal Outlet (1 05 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3. Page No.: 4 of 46

Permit No.: WV0004499A.OD4 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 9130/2015 the permittee is authorized to discharge from Outlet Number(s) 004 (Santtary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring R!!Quirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantitv Units other Units Units **F~uen~**

**~**

Copper, Total Recoverable NIA N/A NIA NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Zinc, Total Recoverable N/A NIA N/A N/A Rpt Only RptOnly mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Weak Acid Dissociable N/A N/A NIA N/A Rpt Only Rpt Only ug/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Mercury, Total (as Hg) N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Aluminum, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Iron, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Manganese, Total (as Mn) N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Chloride (as Cl) N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (105 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3 .

. Page No.: 5 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/112013 and lasting through midnight 9/30/2015 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the penmittee as specified below: Monitoring Reguirements

Effluent Discha!:Qe Limitations Measurement Sample

Characteristic Ouantitv Units Other Units Units **Freguen~** 1m!

Fluoride, Total NIA NIA N/A NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Dally

Pyrene NIA NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Dally

Benzo (A) Anthracene N/A N/A N/A N/A Rpl Only Rp!Only NG!L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Chrysene N/A N/A N/A N/A Rpt Only Rp!Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluoranthene N/A N/A NIA NIA Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluorene N/A N/A N/A NIA Rpt Only Rpt Only ugn 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Phenanthrene N/A NIA N/A N/A Rpt Only Rp!Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acenaphthylene N/A N/A NIA N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location{s):

Outlet 004 (Previously Internal Outlet (1 05 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 6 of 46

Permit No.: WV0004499A.OD4 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 9/30/2015 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantitv Units Other Units Units Fregueng: **~**

Acenaphthene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Anthracene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (B) Fluoranthene N/A N/A NIA N/A Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (K) Fluoranthene N/A NIA N/A N/A Rpt Only Rpt Only NGIL 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (A) Pyrene N/A N/A N/A N/A Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Selenium, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Arsenic, Total Recoverable NIA N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Dibenzo (A, H) Anthracene N/A N/A N/A N/A Rpt Only RptOnly NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (105 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 7 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 9/30/2015 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the pennittee as specified below: Monitoring **R~uirements**

Effluent Discharge Limitations Measurement Sample

Characteristic quantity Units Other Units Units Fmguency: Im!

lndeno (1 ,2,3-cd) Pyrene N/A N/A NIA NIA Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Total NIA NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Phenolics, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Naphthalene N/A N/A NIA N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Temperature, F NIA N/A NIA N/A Rpt Only Rpt Only DEG.F 2/month lnsitu

(Year Round) (ML-2) Avg. Monthly Max. Daily

Temperature difference between intake upstream and discharge.

Temperature, F NIA NIA N/A N/A Rpt Only RptOnly DEG.F 2/month lnsitu

(Year Round) (ML-7) Avg. Monthly Max. Daily

Temperature in intake/upstream representative of the Ohio River upstream of outlet.

Temperature, F N/A N/A N/A NIA Rpt Only Rpt Only DEG.F 2/month lnsitu

(Summer May 1-Jan 31) (ML-1) Avg. Monthly Max. Daily

(May 1- January 31) Temperature of the discharge.

Temperature, F NIA N/A N/A NIA Rpt Only Rpt Only DEG.F 2/month lnsitu

(Winter Feb 1-28/29) (ML-1) Avg. Monthly Max. Daily

(February 1 - 28/29) Temperature of the discharge.

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (105 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 8 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 9/30/2015 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary.

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Requirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units frequency **~**

Temperature, F N/A N/A NIA N/A Rpt Only Rpt Only DEG.F 2/month lnsitu

(Winter Mar 1-31) (ML-1) Avg. Monthly Max. Daily

(March 1 - 31) Temperature of the discharge.

Temperature, F N/A N/A N/A NIA Rpt Only 90.4 DEG.F 2/month lnsitu

(Winter Apr 1-30) (ML-1) Avg. Monthly Max. Daily

(April 1 - 30) Temperature ofthe discharge.

Sulfate NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Oil and Grease, Hexane EXTR. NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (105 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 9 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2015 and lasting through midnight 6/30/2017 the permittee is au1horized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring **R~uirements**

Effluent Discharge Limitations Measurement Sample

Characteristic Ouantitv Units Other Units Units Freguen9! rFlow, in Conduit or thru plant N/A N/A N/A N/A Rpt Only Rpt Only mgd 1/week measured

(Year Round) (ML-1) Avg. Monthly Max. Daily

Total Suspended Solids N/A NIA N/A N/A Rpt Only 60 mg/1 1/month 24 hr Composite

(Year Round) (ML-2) Avg. Monthly Max. Dally

Coliform, Fecal NIA NIA N/A N/A 200 400 Cnts/100ml 1/month Grab

(Year Round) (ML-1) Mon. Geo. Mean Max. Dally

pH N/A NIA N/A 6 NIA 9 s.u. 1/month Grab

(Year Round) (ML-1) lnst Min. lnst. Max.

Ammonia Nitrogen N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Nitrogen, Total (as N) Rpt Only Rpt Only Lbs!Day N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Phosphorus, Total Rpt Only Rpt Only Lbs!Day N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. MOnthly Max. Daily Avg. Monthly Max. Daily

Chlorine, Total Residual N/A N/A NIA N/A Rpt Only Rpt Only ug/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (1 05 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 10 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2015 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring R!:!Quirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantitv Units Other Units Units **F~uen~**

**~**

Copper, Total Recoverable N/A N/A NIA N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Zinc, Total Recoverable NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Weak Acid Dissociable NIA NIA N/A NIA Rpt Only Rpt Only ug/ 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Mercury, Total (as Hg) N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Aluminum, Total Recoverable N/A N/A NIA N/A Rpt Only Rpt Only mgt 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily

Iron, Total Recoverable N/A N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Manganese, Total (as Mn) N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Chloride (as Cl) N/A N/A NIA N/A Rpt Only Rpt Only mgt 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (105 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 11 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2015 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring **R~uirements**

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units **Freguen~**

**~**

Fluoride, Total N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily

Pyrene N/A N/A NIA N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (A) Anthracene NIA N/A N/A NIA Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Chrysene N/A NIA N/A N/A Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluoranthene N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluorene N/A N/A NIA N/A RptOnly Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Phenanthrene N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acenaphthylene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location{s):

Outlet 004 (Previously Internal Outlet (1 05 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 12 of 46

Permtt No.: WV0004499A-004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2015 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary

Cooling Water, Storm Water Runoff, Other) '

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Requirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantitv Units Other Units Units Frequency **~**

Acenaphthene NIA N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Anthracene N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (B) Fluoranthene N/A N/A N/A N/A Rpt Only RptOnly NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (K) Fluoranthene N/A N/A NIA NIA Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (A) Pyrene NIA NIA N/A NIA Rpt Only Rpt Only NGIL 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Selenium, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Arsenic, Total Recoverable N/A N/A NIA N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Dibenzo (A, H) Anthracene N/A NIA N/A N/A Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 004 (Previously Internal Outlet (1 05 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 13 of 46

Permit No.: WV0004499A.004 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2015 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 004 (Sanitary,

Cooling Water, Storm Water Runoff, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units **Fr!Quen~**

**~**

lndeno (1 ,2,3-cd) Pyrene N/A N/A NIA N/A Rpt Only Rpt Only NG/L 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Total N/A N/A N/A N/A Rpt Only Rpt Only mg!l 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Phenolics, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Naphthalene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Temperature, F NIA N/A NIA N/A Rpt Only 15 DEG.F 2/month lnsitu

(Year Round) (ML-2) Avg. Monthly Max. Daily

Temperature difference between intake upstream and discharge.

Temperature, F N/A N/A NIA NIA RptOnly Rpt Only DEG.F 2/month lnsitu

(Year Round) (ML-7) Avg. Monthly Max. Daily

Temperature in intake/upstream representative of the Ohio River upstream of outlet.

Temperature, F NIA N/A NIA NIA Rpt Only Rpt Only DEG.F 2/month lnsitu

(Summer May 1-Jan 31) (ML-1) Avg. Monthly Max. Daily

(May 1- January 31) Temperature of the discharge.

Temperature, F N/A NIA N/A NIA 58.1 67.3 DEG.F 2/month lnsitu

(Winter Feb 1-28/29) (ML-1) Avg. Monthly Max. Daily

(February 1 - 28/29) Temperature of the discharge.

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location{s):

Outlet 004 (Previously Internal Outlet (1 05 + 305)/005) From manhole near end of discharge pipe prior to mixing with the Ohio River.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3. Page No.: 14 of 46

Permit No.: WV0004499A.004DISCHARGELIMITATIONSANDMONITORINGREQUIREMENTS:FinalLimitationsDuringtheperiodbeginning10/1/2015andlastingthroughmidnight6/30/2017thepermitteeisauthorizedtodischargefromOutletNumber(s)004(Sanitary,CoolingWater,StormWaterRunoff,Other)Suchdischargesshallbelimitedandmonitoredbythepermitteeasspecifiedbelow:EffluentDischargeLimitationsCharacteristicQuantityUnitsOtherUnitsTemperature,FN/ANIAN/AN/A67.177.6(WinterMar1-31)(ML-1)Avg.MonthlyMax.Daily(March1 -31)Temperatureofthedischarge.Temperature,FNIANIAN/ANIA78.190.4(WinterApr1-30)(ML-1)Avg.MonthlyMax.Daily(April1 -30)Temperatureofthedischarge.SulfateNIA NIAN/ANIARptOnlyRptOnly(YearRound)(ML-1)Avg.MonthlyMax.DailyOilandGrease,HexaneEXTR.NIAN/AN/AN/ARptOnlyRptOnly(YearRound)(ML-1)Avg.MonthlyMax.DailySamplestakenincompliancewiththemonitoringrequirementsspecifiedaboveshallbetakenatthefollowinglocation(s):Outlet004(PreviouslyInternalOutlet(105+305)/005)FrommanholenearendofdischargepipepriortomixingwiththeOhioRiver.UnitsDEG.FDEG.Fmg/1mg/1MonitoringReauirementsMeasurementFrequency2/month2/month1/quarter1/monthSampleIm!llnsitulnsitu24hrCompositeGrabThisdischargeshallnotcauseviolationofTitle47,Series2,Section3,oftheWestVirginiaLegislativeRulesissuedpursuanttoChapter22B,Article3.PageNo.:15of46PermitNo.:WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 10/15/2013 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantitv Units Other Units Units **Freguen~**

**~**

Flow, in Conduit or thru plant N/A NIA N/A N/A Rpt Only 1.2 mgd 1/daily measured

(Year Round) (ML-1) Avg. Monthly Max. Daily

Total Suspended Solids 1227 2371 Lbs/Day N/A Rpt Only Rpt Only mg/1 1/week 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Coliform, Fecal N/A N/A N/A N/A 200 400 Cnts/100ml 2/month Grab

(Year Round) (ML-1) Mon. Geo. Mean Max. Daily

pH N/A N/A N/A 6 NIA 9 s.u. 1/week Grab

(Year Round) (ML-1) lnst. Min. lnst. Max.

Ammonia Nitrogen 791 1591 Lbs/Day N/A Rpt Only Rpt Only mg/1 1/week 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Nitrogen, Kjeldahl Total Rpt Only RptOnly Lbs/Day N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Nitrogen Nitrate Rpt Only RptOnly Lbs/Day NIA Rpt Only Rpt Only mg/1 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Nitrogen Nitrite Rpt Only Rpt Only Lbs/Day N/A 4 15.5 mg/1 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max.. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously lntemal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 16 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 10/15/2013 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units **F~uenc~**

**~**

Nitrogen, Total (as N) RptOnly Rpt Only Lbs/Day N/A Rpt Only RptOnly mg/1 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Phosphorus, Total Rpt Only Rpt Only Lbs/Day N/A Rpt Only Rpt Only mgn 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Chlorine, Total Residual N/A NIA N/A N/A 150 300 ug/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Copper, Total Recoverable N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Zinc, Total Recoverable N/A NIA N/A N/A Rpt Only RptOnly mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Weak Acid Dissociable N/A NIA N/A N/A 67 120 ug/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Mercury, Total (as Hg) N/A N/A N/A N/A 0.234 0.417 ug/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Aluminum, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only mgn 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 17 of46

Permit No.: WVOOD4499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 10/15/2013 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units other Units Units **Freguen~** !m!

Iron, Total Recoverable NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Manganese, Total (as Mn) NIA NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Chloride (as Cl) N/A NIA N/A N/A Rpt Only RptOnly mg/1 1/year 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluoride, Total N/A N/A N/A N/A Rpt Only Rpt Only mgt 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acute Tox- Ceriodaphnia Dubia N/A N/A NIA N/A RptOnly Rpt Only TUa 1/year 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acute Toxicity- Pimephales N/A NIA N/A N/A Rpt Only Rpt Only TUa 1/year 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Pyrene N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Compostte

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (A) Anthracene N/A N/A NIA NIA 6.9 19.7 ugn 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 18 of 46

Permtt No.: WV0004499A.006DISCHARGELIMITATIONSANDMONITORINGREQUIREMENTS:InterimLimitationsDuringtheperiodbeginning10/1/2013andlastingthroughmidnight10/15/2013thepermitteeisauthorizedtodischargefromOutletNumber(s)006(StormWaterRunoff,ProcessWater,Other)Suchdischargesshallbelimitedandmonitoredbythepermitteeasspecifiedbelow:MonitoringReguirementsEffluentDischargeLimitationsMeasurementSampleCharacteristicQuantitvUnitsOtherUnitsUnitsIm!tChryseneNIA N/AN/ANIA6.917.3ug/12/month24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyFluorantheneN/AN/AN/A N/ARptOnlyRptOnlyug/11/quarter24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyFluoreneN/AN/A N/AN/ARptOnlyRptOnlyug/11/quarter24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyPhenanthreneNIA NIAN/ANIARptOnlyRptOnlyug/11/quarter24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyAcenaphthyleneN/A N/A NIA NIARptOnlyRptOnlyug/1/quarter24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyAcenaphtheneNIA N/ANIA NIARptOnlyRptOnlyug/1/quarter24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyAnthraceneN/AN/AN/A N/ARptOnlyRptOnlyug/11/quarter24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailyBenzo(B)FluorantheneN/AN/AN/AN/A6.917.8ug/12/month24hrComposite(YearRound)(ML-1)Avg.MonthlyMax.DailySamplestakenincompliancewiththemonitoringrequirementsspecifiedaboveshallbetakenatthefollowinglocation(s):Outlet006(PreviouslyInternalOutlet205)-SamplesshallbetakenatthedischargefromtheprocesswastewatertreatmentsystempriortodischargingtotheOhioRiverthroughthesubmergedOutlet006dischargepipe.ThisdischargeshallnotcauseviolationofTitle47,Series2,Section3,oftheWestVirginiaLegislativeRulesissuedpursuanttoChapter228,Article3.PageNo.:19of46PermitNo.:WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 10/1512013 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the penmittee as specified below: Monitoring Requirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units Frequency **~**

Benzo (K) Fluoranthene N/A NIA N/A N/A 6.9 17.4 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (A) Pyrene 0.0754 0.136 Lbs!Day N/A 6.9 19 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Selenium, Total Recoverable N/A N/A N/A N/A 0.106 0.243 mg/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Arsenic, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Dibenzo (A, H) Anthracene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

lndeno (1 ,2,3-cd) Pyrene NIA N/A N/A N/A 6.9 18.2 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Total 25.6 36.6 Lbs!Day N/A 4.39 9.31 mg/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Phenolics, Total Recoverable 0.29 0.47 Lbs!Day N/A 82 145 ug/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring nequirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205) -Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 20 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Interim Limitations During the period beginning 10/1/2013 and lasting through midnight 10/15/2013 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units **Freguen~**

**~**

Naphthalene 0.0759 0.137 Lbs/Day N/A Rpt Only Rpt Only ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Temperature, F N/A N/A NIA NIA Rpt Only Rpt Only DEG.F 1/month lnsitu

(Year Round) (ML-1) Avg. Monthly Max. Daily

Temperature of the discharge.

Temperature, F N/A N/A N/A N/A Rpt Only Rpt Only DEG.F 1/month lnsitu

(Year Round) (ML-2) Avg. Monthly Max. Daily

Temperature difference between upstreamflntake and discharge.

Temperature, F NIA N/A NIA NIA Rpt Only Rpt Only DEG.F 1/month In situ

(Year Round) (ML-7) Avg. Monthly Max. Daily

Temperature in intake/upstream representative of the Ohio River upstream of outlet

Sulfate N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Oil and Grease, Hexane EXTR. 102 306 Lbs/Day NIA Rpt Only Rpt Only mg/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 21 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/16/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharne Limitations Measurement Sample

Characteristic QuantitY Units Other Units Units **Freguen~** illl!t

Flow, in Conduit or thru plant NIA N/A NIA NIA Rpt Only 1.2 mgd 1/daily measured

(Year Round) (ML-1) Avg. Monthly Max. Daily

Total Suspended Solids 1227 2371 Lbs/Day NIA RptOnly Rpt Only mg/1 1/week 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Coliform, Fecal N/A N/A N/A N/A 200 400 Cnts/100ml 2/month Grab

(Year Round) (ML-1) Mon. Gee. Mean Max. Daily

pH N/A NIA N/A 6 N/A 9 s.u. 1/week Grab

(Year Round) (ML-1) lnst. Min. lnst. Max.

Ammonia Nitrogen 791 1591 LbsiDay N/A Rpt Only Rpt Only mg/1 1/week 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Nitrogen, Kjeldahl Total Rpt Only Rpt Only LbsiDay N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (Ml-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Nitrogen Nitrate Rpt Only Rpt Only Lbs/Day NIA Rpt Only Rpt Only mg/1 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Nitrogen Nitrite Rpt Only Rpt Only Lbs/Day N/A 4 15.5 mg/1 1/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 22 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/16/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantitv Units Other Units Units Fregueng:: Tvpe

Nitrogen, Total (as N) Rpt Only Rpt Only Lbs!Day NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Phosphorus, Total Rpt Only RptOnly Lbs!Day N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Chlorine, Total Residual N/A N/A NIA N/A 150 300 ug/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Copper, Total Recoverable N/A N!A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Zinc, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Weak Acid Dissociable N/A N/A N/A N/A 67 120 ug/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Mercury, Total (as Hg) N/A N/A NIA NIA 0.0098 0.018 ug/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily

Effective Date of Final Limitations is 10/16/2013

Aluminum, Total Recoverable N/A N/A NIA NIA Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location{s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 23 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/16/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units Freauency **~**

Iron, Total Recoverable NIA N/A NIA N/A RptOnly Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Manganese, Total (as Mn) N/A N/A NIA N/A RptOnly Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Chloride (as Cl) N/A N/A NIA N/A Rpt Only Rpt Only mg/1 1/year 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluoride, Total N/A N/A NIA N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acute Tox- Ceriodaphnia Dubia N/A N/A N/A N/A Rpt Only Rpt Only TUa 1/year 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acute Toxicity- Pimephales N/A N/A NIA NIA Rpt Only Rpt Only TUa 1/year 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Pyrene NIA N/A NIA NIA Rpt Only Rpt Only ugn 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (A) Anthracene NIA N/A N/A NIA 6.9 19.9 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205) - Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 24 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/16/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units Freguenc:v: £ll1!

Chrysene NIA NIA N/A NIA 6.9 17.3 ug/ 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluoranthene NIA NIA N/A NIA Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Fluorene N/A NIA N/A N/A Rpt Only RptOnly ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Phenanthrene N/A N/A N/A N/A Rpt Only RptOnly ug/1 1/quarter 24 hr Composfte

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acenaphthylene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Acenaphthene NIA N/A N/A NIA Rpt Only Rpt Only ug/ 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Anthracene N/A NIA N/A N/A Rpt Only RptOnly ug/1 1/quarter 24 hr Composfte

(Year Round) (ML-1) Avg. Monthly Max. Daily

Benzo (B) Fluoranthene N/A N/A NIA N/A 6.9 17.8 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205) -Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 25 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/16/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff. Process Water. Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units **Freguen~** nm

Benzo (K) Fluoranthene N/A N/A NIA N/A 6.9 17.4 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Dally

Benzo (A) Pyrene 0.0754 0.136 Lbs/Day N/A 6.9 19 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Selenium. Total Recoverable N/A N/A NIA N/A 0.106 0.243 mg/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Arsenic. Total Recoverable N/A N/A NIA N/A Rpt Only Rpt Only mg/1 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Dibenzo (A, H) Anthracene N/A N/A NIA N/A Rpt Only Rpt Only ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

lndeno (1 ,2,3-cd) Pyrene N/A N/A N/A NIA 6.9 18.2 ug/1 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Cyanide, Total 25.6 36.6 Lbs/Day N/A 4.39 9.31 mg/1 2/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Phenolics, Total Recoverable 0.29 0.47 Lbs/Day N/A 82 145 ug/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 26 of 46

Permit No.: WV0004499A.006 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/16/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 006 (Storm Water

Runoff, Process Water, Other)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Requirements

Effluent Dischame Limitations Measurement Sample

Characteristic Quantity Units Other Units Units Freauency **~**

Naphthalene 0.0759 0.137 Lbs/Day NIA Rpt Only Rpt Only ugll 2/month 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Temperature, F N/A N/A N/A N/A RptOnly Rpt Only DEG.F 1/month lnsitu

(Year Round) (ML-1) Avg. Monthly Max. Daily

Temperature of the discharge.

Temperature, F N/A N/A N/A N/A Rpt Only Rpt Only DEG.F 1/month lnsitu

(Year Round) (ML-2) Avg. Monthly Max. Daily

Temperature difference between upstreamflntake and discharge.

Temperature, F N/A N/A N/A N/A Rpt Only Rpt Only DEG.F 1/month lnsitu

(Year Round) (ML-7) Avg. Monthly Max. Daily

Temperature in intake/upstream representative of the Ohio River upstream of outlet.

Sulfate N/A N/A N/A N/A Rpt Only Rpt Only mgll 1/quarter 24 hr Composite

(Year Round) (ML-1) Avg. Monthly Max. Daily

Oil and Grease, Hexane EXTR. 102 306 Lbs/Day NIA Rpt Only Rpt Only mg/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Outlet 006 (Previously Internal Outlet 205)- Samples shall be taken at the discharge from the process wastewater treatment system prior to discharging to the Ohio River through the submerged

Outlet 006 discharge pipe.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 27 of 46

Permit No.: WV0004499A.097 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 097 (Intake)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring **R~uirements**

Effluent Discharge Limitations Measurement

Characteristic Quantitv Units Other Units Units Frequency

Total Suspended Solids N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/week

(Year Round) (ML-5) Avg. Monthly Max. Daily

Coliform, Fecal N/A N/A N/A N/A Rpt Only Rpt Only Cnts/100ml 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

pH NIA N/A NIA Rpt Only N/A Rpt Only s.u. 1/month

(Year Round) (ML-5) Jnst Min. lnst Max.

Ammonia Nitrogen NIA N/A N/A N/A Rpt Only Rpl Only mg/1 ·1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Nitrogen, Kjeldahl Total N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Nitrogen Nitrate N/A N/A NIA NIA Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Nitrogen Nitrite N/A NIA N/A N/A Rpt Only Rpl Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Nitrogen, Total (as N) N/A N/A N/A N/A Rpl Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Sampling shall be taken upstream of the influence of Outlet 005 in the Ohio River on the West Virginia side of the river. Refer to Section C.37 for solids sampling.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 28 of 46

Permit No.: WV0004499 Sample **~** Grab Grab Grab Grab Grab Grab Grab GrabA.097 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 097 (Intake)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Reguirements

Effluent Discharge Limitations Measurement

Characteristic Quantitv Units Other Units Units Frequency

Chlorine, Total Residual NIA N/A N/A NIA Rpt Only Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Copper, Total Recoverable NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Zinc, Total Recoverable NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Cyanide, Weak Acid Dissociable NIA N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Mercury, Total (as Hg) NIA NIA N/A NIA Rpt Only Rpt Only ug/1 1/year

(Year Round) (ML-5) Avg. Monthly Max. Daily

Hardness, Total (as CaC03) N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Aluminum, Total Recoverable N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Iron, Total Recoverable NIA N/A N/A NIA Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Sampling shall be taken upstream of the influence of Outlet 005 in the Ohio River on the West Virginia side of the river. Refer to Section C.37 for solids sampling.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 29 of 46

Permit No.: WV0004499 Sample £t.pg Grab Grab Grab Grab Grab Grab Grab GrabA.097 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 097 (Intake)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Requirements

Effluent Discharne Limitations Measurement

Characteristic Quantitv Units Other Units Units Frequency

Chloride (as Cl) N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/year

(Year Round) (ML-5) Avg. Monthly Max. Daily

Fluoride, Total N/A NIA N/A N/A Rpt Only RptOnly mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Pyrene N/A N/A N/A N/A Rpt Only RptOnly ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Benzo (A) Anthracene N/A N/A NIA N/A Rpt Only Rpt Only NG/L 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Chrysene NIA NIA N/A NIA Rpt Only Rpt Only NG/L 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Fluoranthene N/A NIA N/A N/A Rpt Only RptOnly ug/1 1/year

(Year Round) (ML-5) Avg. Monthly Max. Daily

Fluorene N/A N/A NIA N/A RptOnly Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Phenanthrene N/A NIA N/A N/A Rpt Only RptOnly ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Sampling shall be taken upstream of the influence of Outlet 005 in the Ohio River on the West Virginia side of the river. Refer to Section C.37 for solids sampling.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 30 of 46

Permit No.: WV0004499 Sample Jmg Grab Grab Grab Grab Grab Grab Grab GrabA.097 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 097 (Intake)

Such discharges shall be limited and monitored by the permittee as specified below: Monitoring Requirements

Effluent Discharne Limitations Measurement

Characteristic Quantitv Units Other Units Units Frequency

Acenaphthylene N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Acenaphthene N/A NIA N/A N/A Rpt Only Rpt Only ug/1 1/year

(Year Round) (ML-5) Avg. Monthly Max. Daily

Anthracene N/A N/A N/A N/A Rpt Only Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Benzo (B) Fluoranthene N/A N/A N/A N/A Rpt Only Rpt Only NG/L 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Benzo (K) Fluoranthene N/A N/A N/A N/A Rpt Only Rp!Only NG/L 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Benzo (A) Pyrene N/A N/A NIA NIA Rp!Only Rpt Only NGIL 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Selenium, Total Recoverable NIA N/A N/A NIA Rpt Only Rpt Only ug/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Arsenic, Total Recoverable N/A NIA N/A N/A Rpt Only Rpt Only mg/1 1/quarter

(Year Round) (ML-5) Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Sampling shall be taken upstream of the influence of Outlet 005 in the Ohio River on the West Virginia side of the river. Refer to Section C.37 for solids sampling.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 31 of 46

Permit No.: WV0004499 Sample **~** Grab Grab Grab Grab Grab Grab Grab GrabA.097DISCHARGELIMITATIONSANDMONITORINGREQUIREMENTS:FinalLimitationsDuringtheperiodbeginning10/1/2013andlastingthroughmidnight6/30/2017thepermitteeisauthorizedtodischargefromOutletNumber(s)097(Intake)Suchdischargesshallbelimitedandmonitoredbytlhepermitteeasspecifiedbelow:MonitoringReguirementsEffluentDischargeLimitationsMeasurementCharacteristicQuantitvUnitsOtherUnitsUnitsFreauencyDibenzo(A,H)AnthraceneN/AN/AN/A N/ARptOnlyRptOnlyNG/L1/quarter(YearRound)(ML-5)Avg.MonthlyMax.Dailylndeno(1,2,3-cd)PyreneNJANJAN/AN/ARptOnlyRptOnlyNGIL1/quarter(YearRound)(ML-5)Avg.MonthlyMax.DailyBenzo(GHI)PeryleneNJAN/AN/ANJARptOnlyRptOnlyug/11/quarter(YearRound)(ML-5)Avg.MonthlyMax.DailyCyanide,TotalN/AN/AN/A N/ARptOnlyRptOnlymg/11/quarter(YearRound)(ML-5)Avg.MonthlyMax.DailyPhenolics,TotalRecoverableN/ANJAN/A N/ARptOnlyRptOnlyug/11/quarter(YearRound)(ML-5)Avg.MonthlyMax.DailyNaphthaleneN/ANJAN/A N/ARptOnlyRptOnlyug/11/quarter(YearRound)(ML-5)Avg.MonthlyMax.DailyTotalRecov.ManganeseNJANJAN/ANJARptOnlyRptOnlymg/11/quarter(YearRound)(ML-5)Avg.MonthlyMax.DailyTemperature,FN/AN/ANJANJARptOnlyRptOnlyDEG.F1/month(YearRound)(ML-5)Avg.MonthlyMax.DailySamplestakenincompliancewiththemonitoringrequirementsspecifiedaboveshallbetakenatthefollowinglocation(s):SamplingshallbetakenupstreamoftheinfluenceofOutlet005intheOhioRiverontheWestVirginiasideoftheriver.RefertoSectionC.37forsolidssampling.ThisdischargeshallnotcauseviolationofTitle47,Series2,Section3,oftheWestVirginiaLegislativeRulesissuedpursuanttoChapter228,Article3.PageNo.:32of46PermitNo.:WV0004499SampleI:lP!tGrabGrabGrabGrabGrabGrabGrablmrstbA.097 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 097 (Intake)

Such discharges shall be limited and monitored by the permittee as specified below:

Effluent

Characteristic Sulfate (Year Round) (ML-5) N/A Quantitv N/A Discharge Limitations

Units other Units

N/A NIA Rpt Only

Avg. Monthly Rpt Only

Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following Jocation(s): Monitoring Requirements

Measurement Sample

Units Frequency **~**

mg/1 1/quarter Grab

Sampling shall be taken upstream of the influence of Outlet 005 in the Ohio River on the West Virginia side of the river. Refer to Section C.37 for solids sampling.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3.

Page No.: 33 of 46

Penmtt No.: WV0004499A.105 DISCHARGE LIMITATIONS AND MONITORING REQUIREMENTS:

Final Limitations During the period beginning 10/1/2013 and lasting through midnight 6/30/2017 the permittee is authorized to discharge from Outlet Number(s) 105 (Sanital)l)

Such discharges shall be limited and monitored by the pennittee as specified below: Monitoring **~uirements**

Effluent Discharge Limitations Measurement Sample

Characteristic Quantity Units Other Units Units Freauency **~**

Flow, in Conduit or thru plant N/A N/A NIA N/A 0.044 Rpt Only mgd 2/month measured

(Year Round) (ML-1) Avg. Monthly Max. Daily

BOD, 5-Day 20 Deg.C 10 20 Lbs/Day N/A 30 60 mgn 1/month Grab

(Year Round) (ML-B) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Total Suspended Solids 10 20 Lbs/Day N/A 30 60 mg/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Coliform, Fecal NIA N/A N/A NIA 200 400 Cnts/100ml 1/monlh Grab

(Year Round) (ML-1) Mon. Geo. Mean Max. Daily

Ammonia Nitrogen 5 10 Lbs/Day NIA 15 30 mg/1 1/month Grab

(Year Round) (ML-1) Avg. Monthly Max. Daily Avg. Monthly Max. Daily

Samples taken in compliance with the monitoring requirements specified above shall be taken at the following location(s):

Internal Outlet 105 (Sanitary)- Effluent BOD samples shall be collected ala point immediately preceding disinfection. All other samples shall be collected after disinfection at the Internal Outlet 105

final discharge point.

This discharge shall not cause violation of Title 47, Series 2, Section 3, of the West Virginia Legislative Rules issued pursuant to Chapter 228, Article 3. Page No.: 34 of 46

Permtt No.: WV0004499

# Page No.: 35 of 46

Permit No.: WV0004499



# B. SCHEDULE OF COMPLIANCE

1. The permitee shall achieve compliance with the provisions for waste treatment and the monitoring

requirements specified in the permit in accordance with the following schedule :

Oct 16, 2013: The permittee shall complete the construction of necessary treatment upgrades and

comply with the final effluent limitations for mercury at Outlet 006.

Jan 01, 2014:

Apr 01, 2014:

Apr 01, 2014:

Jul 01, 2014:

Oct 01, 2014:

Oct 01, 2014:

Dec 31, 2014:

Jan 01, 2015:

Mar 01,2015: The permittee shall submit a Plan of Action on obtaining compliance with the average and

maximum temperature limitations (February and March), average monthly temperature

limitation {April), and temperature rise limitation at Outlet 004.

The permittee shall submit a Quarterly Progress Report which summarizes the actions

taken and any additional actions to be taken in the future to achieve the Final

Requirements for the average and maximum temperature limitations (February and

March), average monthly temperature limitation (April), and temperature rise limitation at

Outlet 004.

The pemittee shall submit a progress report pursuant to finalizing a study of its existing

cooling water intake structures and the effects of fish and other aquatic organisms in

accordance with the requirements of Section D.03. The permitttee shall submit a progress

report pursuant to finalizing its Compliance Demonstration Work Plan in accordance with

Section D.04 of the permit.

The permittee shall submit a Quarterly Progress Report which summarizes the actions

taken and any additional actions to be taken in the future to achieve the Final

Requirements for the average and maximum temperature limitations (February and

March), average monthly temperature limitation (April), and temperature rise limitation at

Outlet 004.

The permittee shall submit a Quarterly Progress Report which summarizes the actions

taken and any additional actions to be taken in the future to achieve the Final

Requirements for the average and maximum temperature limitations (February and

. March), average monthly temperature limitation (April), and temperature rise limitation at

Outlet 004.

The pemittee shall submit a progress report pursuant to finalizing a study of its existing

cooling water intake structures and the effects of fish and other aquatic life in accordance

with the requirements of Section D.03. The permitttee shall submit a progress report

pursuant to finalizing its Compliance Demonstration Work Plan in accordance with Section

D.04 of the permit.

The permittee shall submit the results of the mixing zone verification studies required by

Sections C.30 and C.31 of the permit.

The permittee shall submit a Quarterly Progress Report which summarizes the actions

taken and any additional actions to be taken in the future to achieve the Final

Requirements for the average and maximum temperature limitations (February and

March), average monthly temperature limitation (April), and temperature rise limitation at

Outlet 004.

The permittee shall complete a study and submit a report on its existing cooling water

intake structures and the effects of fish and other aquatic organisms in accordance with

Section D.03 of this permit.

# Page No.: 36 of 46

Permit No.: WV0004499



# B. SCHEDULE OF COMPLIANCE

1. The permitee shall achieve compliance with the provisions for waste treatment and the monitoring

requirements specified in the permit in accordance with the following schedule :

Apr 01, 2015: The permittee shall submit a Quarterly Progress Report which summarizes the actions

taken and any additional actions to be taken in the future to achieve the Final

Requirements for the average and maximum temperature limitations (February and

March), average monthly temperature limitation (April), and temperature rise limitation at

Outlet 004.

Apr 01, 2015:

Jul 01, 2015:

Oct 01, 2015:

Oct 01, 2015:

Apr 01, 2016: The permitttee shall submit a progress report pursuant to finalizing its Compliance

Demonstration Work Plan in accordance with Section D.04 of the permit.

The permittee shall submit a Quarterly Progress Report which summarizes the actions

taken and any additional actions to be taken in the future to achieve the Final

Requirements for the average and maximum temperature limitations (February and

March), average monthly temperature limitation (April), and temperature rise limitation at

Outlet 004.

The permittee shall complete the construction of necessary treatment upgrades and

comply with the final requirements for the average and maximum temperature limitations

(February and March), average monthly temperature limitation (April), and the temperature

rise limitation at Outlet 004.

The permitttee shall submit a progress report pursuant to finalizing its Compliance

Demonstration Work Plan in accordance with Section D.04 of the permit.

The permittee shall submit a Compliance Demonstration Work Plan and permit

modification application in accordance with the requirements of Section D.04 of this permit.

2. Reports of compliance or non-compliance with, and progress reports on Interim and final requirements contained in

the above compliance schedule, if any, shall be postmarked no later than 

# 14 days following each schedule date.

# Section C -Other Requirements Page No.: 37 of 

# 46

Permit No.: 

# WV0004499

0 I. The permittee shall practice good housekeeping including maintaining the facility grounds. There shall be no

scattered parts, equipment, debris, etc. Any and all drums shall be either stored in a covered area or kept upon

pallets and properly sealed.

02. The issuance of this permit shall not relieve the permittee of the obligation to comply with any other federal, state

or local laws. Compliance with this permit does not relieve the permittee from the obligation of Section 311 of the

Clean Water Act. This permit does not authorize spills of hazardous substances/wastes from any permitted outlet

into waters ofthe State. Such incidents are to be reported in accordance with Sections IV.! and IV.2 of Appendix

A of this permit.

03. Upon review of information submitted under terms and conditions of this permit, the permit may be modified to

require additional effluent limitations/monitoring requirements and/or improved best management practices.

04. The permittee shall notify the Division of Water and Waste Management immediately when it becomes aware of

any migration of any pollutant from any unpermitted source (such as contaminated groundwater and/or storm water)

into surface waters of the State.

05. If there is evidence indicating potential or realized impacts on water quality due to any storm water discharge

associated with industrial activity covered by this permit, the permit may be promptly modified and/or reissued to

include effluent limitations and/or other requirements to control such storm water discharges.

06. The permittee shall submit each month according to the enclosed format, a Discharge Monitoring Report (DMR)

indicating in terms of concentration and/or quantities the values of the constituents listed in Section A analytically

determined to be in the plant effluent(s). Additional information pertaining to effluent monitoring and reporting can

be found in Section III of Appendix A.

07. The required DMRs shall be received by the agency no later than 20 days following the end of the reporting period

in accordance with the following requirements. The agency is now requiring the permittee to utilize our electronic

discharge monitoring report ( eDMR) system which is now mandatory. The permittee is not required to submit hard

copies ofthe DMRs to the addresses listed below when using eDMR. Special circumstances may result in the

agency granting an exemption to eDMR and are considered on case by case basis. If the permittee was exempted

by the agency from using the eDMR system, then the permittee is required to send hard copies to the addresses

below. The permittee may contact the agency for more information about the eDMR system and potential

exemptions from using it. Regardless, in accordance with Appendix A, Section III.6 of this permit, the permittee

shall maintain copies ofDMRs (either hard copies or electronic copies) at the plant site and the DMRs shall be

made readily available upon request for DEP personnel.

a. Director

Division of Water and Waste Management

601 57th Street, SE



# Charleston, West Virginia 25304

Attn: Permitting Branch

Department of Environmental Protection

Environmental Enforcement

Wheeling Satellite Office (NW)



# 1060 Chapline Street, Lower Lobby

Wheeling, WV 26033-2955 u. s. Environmental Protection Agency

Region III, Water Protection Division

NPDES Enforcement Branch (3WP42)

1650 Arch Street



# Philadelphia, PA 19103



# 08. For any noncompliance reports to be submitted in writing by this permit, a copy shall also be forwarded to the EPA

at the location specified under Condition C.7 of this permit.

09. Any "not detected (ND)" results by the permittee must be "ND" at the method detection limit (MDL) for the test

method used for that parameter and must be reported as less than the MDL used. The permittee may not report the

result as zero, "ND", or report the result as less than a minimum level (ML), reporting limit (RL), or practical

quantitation limit (PQL). When averaging values of analytical results for DMR reporting purposes for monthly

averages, the permittee should use actual analytical results when these results are greater than or equal to the MDL

and should use zero (0) when these results are less than the MDL. If all analytical results are non-detect at the

MDL (<MDL), then the permittee should use the actual MDL in the calculation for averaging and report the result

as less than the average calculation.

# Section 

# C

- Other Requirements Page No.: 38 of 

# 46

Permit No.: 

# WV0004499

I 0. In incidences where a specific test method is not deemed, the permittee shall utilize an EPA approved method with

a method detection limit (MDL) sensitive enough to confirm compliance with the permit effluent limit for that

parameter. If a MDL is not sensitive enough to confirm compliance, the most sensitive approved method must be

used. If a more sensitive EPA approved method becomes available, that method shall be used. Should the current

and/or new method not be sensitive enough to confirm compliance with the permitted effluent limit, analytical

results reported as "not detected" at the MDL of the most sensitive method available will be deemed compliant for

purposes of permit compliance. Results shall be reported on the Discharge Monitoring Reports as a numeric value

less than the MDL.

11. The permittee shall not use alternate DMRs without prior approval from this Agency.

12. The Groundwater Protection Plan (GPP) shall be maintained at the plant site and shall be available for inspection

by DEP personnel.

13. The permittee shall maintain and continue to implement its storm water pollution prevention plan (SWPPP) for the

site. The SWPPP shall be prepared in accordance with good engineering practices. The SWPPP shall identifY

potential sources of pollution which may reasonably be expected to affect the quality of storm water discharges

associated with the industrial activity. In addition, the plan shall describe and ensure the implementation of

practices which are to be used to reduce the pollutants in storm water discharges associated with the industrial

activity at the facility and to assure compliance with the terms and conditions of this permit A copy of this

document shall be retained at the site for review upon request.

14. If any portion of the Permittee's discharge that is identified as being subject to Federal Effluent Guideline(s) and the

new or revised requirements of the Federal Effluent Guideline(s) are not currently in this permit, the Director may

reopen or reissue this permit to incorporate additional, more stringent requirements or limitations.

15. The permittee shall perform acute effluent toxicity testing in accordance with the following.

a. The acute effluent toxicity testing prescribed, herein, shall be 48-hour static acute toxicity tests utilizing

Pimephales Promelas fathead minnow and Ceriodaphnia Dubia as the test species.

b. The acute toxicity testing shall be performed on an annual (!/year) basis. The first acute toxicity testing shall

be carried out within 6 months from the effective date of the permit for Outlet 006. There shall be a minimum

of three (3) months between sampling events.

c. 24-hour flow weighted composite samples of the effluent, as prescribed in Section A, shall be collected for

testing.

d. The dilution water should be a representative sample ofthe receiving water and should be obtained from a

point as close as possible to but upstream or outside of the zone influenced by the effluent. If dilution water

from the receiving stream is not suitable, some other uncontaminated, well-aerated surface or groundwater or

commercially available media or reconstituted laboratory water can be used.

e. Testing and reporting of the result shall be performed in accordance with 40 CFR 136 and must be submitted

with the Discharge Monitoring Report (DMR) for the month following the completion of each test. LC50 shall

be converted into Acute Toxic Units (TUa) using the following formula:

TUa**~** 

# l 00/LCSO

For example, ifLC50 is 100%, then TUa**~** 

# 100/100**~I.**



# f. If acute effluent toxicity testing demonstrates toxicity above l TUa, the permittee shall immediately resample

and test the effluent. This shall be performed within 30 days. Copies of the retesting results shall be provided

to the Director immediately upon completion of the test.

g. The Director may impose further requirements should the acute effluent toxicity testing results show toxicity.

16. The permittee shall utilize EPA Method No. 1664 A (gravimetric analysis using the hexane extractable method

[HEM]) for the analysis of oil and grease.

17. For the measurement of Free Cyanide, the permittee shall use the standard method (including approved general

method OIA 1677) for weak acid dissociable cyanide, as specified in the latest edition of Standard Methods.

# Section 

# C

- Other Requirements Page No.: 39 of 46

Permit No.: WV0004499



# 18. The Division has started to analyze the impacts of nutrients upon water quality and whether there is a need to

establish nutrient water quality standards. Therefore, the Division shall impose effluent sampling for Total

Nitrogen and Total Phosphorus in order to assist in this analysis. The Division recognizes there is not an EPA

approved method to directly test for Total Nitrogen. The Total Nitrogen value to be reported on the permittee's

Discharge Monitoring Reports (DMRs) shall be the sum of the following parameters; Total Kjeldahl Nitrogen,

Nitrate and Nitrite.

19. The Permittee shall submit the enclosed Annual Production Report summarizing the actual production from Outlet

006 for each month. This report shall include the actual production from each unit for each month and not the

potential production from the unit. For example, if a unit was in operation for only 2 shifts every day during a

month, then the production reported from the unit should reflect only 2 shifts of operation for each day of the month

and shall not include the potential third shift that was not worked. Please find the attached Annual Production

Report that is to be used by the Permittee. An alternate report may not be used by the permittee without prior

approval from this Agency. This report is due on or before the 20th of January each calendar year and may be

attached to the Permittee's December DMR.

20. The following conditions apply only to the package sewage treatment plant:

a. The herein described treatment works, structures, electrical, and mechanical equipment shall be adequately

protected from physical damage by the maximum expected twenty-five (25) year flood level, and operability

shall be maintained during the ten (10) year flood level.

b. Maintenance and operation of the listed sewage treatment facility shall be performed by, or supervised by, a

certified operator possessing at least a Class 1-S certificate, for Waste Water Treatment Plant Operators, issued

by the State of West Virginia.

c. The permittee shall connect to a municipal or public service district sewage collection system, iffeasible, when

one becomes available; however, prior to this connection, the permittee shall obtain written permission from

the municipal or public service district sewage system authority which will receive the waste and submit a

request along with one (I) copy of the written permission to the Division of Water and Waste Management for

approval.

d. Without prior approval from the agency, use of intermediates, by-products, spent solvents or any other

materials (except commercial grade materials), containing pollutant(s) that cannot be removed by the

wastewater treatment plant is prohibited.

21. Should two (2) consecutive discharge monitoring reports illustrate non-compliance with any pollutant's permit

limitations, the pe1mittee shall submit a Plan of Action outlining milestones to achieve compliance.

22. Prior to disposing of any solids generated by the package sewage treatment plant, the permittee shall submit a letter

of acceptance from the disposal facility to this Division. This does not apply to any normal solid wastes

(trash/refuse) generated by the standard operation of the facility. However, those normal solid wastes shall be

disposed of in a manner consistent with any, and all, appropriate laws and regulations. Any intentional

discharge/disposal of any non-wastewater waste materials through any permitted discharge for the purpose of

circumventing other regulations solely by dilution is prohibited.

23. The permittee shall operate and maintain barge loading and unloading facilities in such a manner so as, to the

maximum extent practicable, preclude spillage of coal, chemicals, etc. used at the facility, and shall take all actions

necessary to clean up and control any such spill which may occur.

24. In conformance with the requirements of Appendix A, Part II, Section 5, Removed Substances, the permittee shall

obtain approval for the disposal of any solids generated by the wastewater treatment plant. This approval shall be

afforded in accordance with the provisions of Title 33, Series 2, of the Legislative Rules, accordingly, and 40 CFR

Part 503, as applicable.

25. In accordance with Appendix A.III.6 of this permit, the permittee shall keep hard or electronic copies oflaboratory

records on site and have readily available for review by DEP personnel.

# Section 

# C - Other Requirements Page No.: 40 of46

Permit No.: WV0004499



# 26. Any bilge water that is pumped out of the barges shall be pumped to the on-site collection system and properly

treated prior to discharge, unless extreme emergency situations, such as, the imminent sinking of a barge into the

Ohio River requires the immediate pumping of bilge water to the river to prevent a potentially worse environmental

situation. In the case of these extreme emergency situations, the permittee shall follow the bypass provisions

contained in Appendix A, Part II, Section 3 and the reporting requirements of Appendix A, PartlY, Section 2.

Discharged bilge water shall not cause a violation of Title 47, Series 2, Section 3.a of the West Virginia Code of

State Regulations.

27. Net TSS calculations at Outlet 004 shall be calculated by subtracting the Gross TSS value at Outlet 097 from the

Gross TSS value taken at Outlet 004. Outfall and upstream sampling (Outlet 097) for TSS shall be concurrent in

order to calculate a representative net value. The permittee may collect a composite sample for TSS at Outlet 097

in lieu of the required grab sample. The permittee should indicate this on the DMR accordingly.

28. Effluent monitoring for the following pollutants shall be conducted using the most sensitive methods and detection

levels commercially available and economically feasible. The following methods are to be used unless the

permittee desires to use an EPA Approved Test Method with a listed lower method detection level. Regardless, it is

recognized that detection levels can vary from analysis to analysis and that non-detect results at a different MDL for

the specified test method would not constitute a permit violation.

Parameter

Copper, Total Recoverable

Zinc, Total Recoverable

Aluminum, Total Recoverable

Selenium, Total Recoverable



# Benzene

Phenolics, Total Recoverable

Mercury, Total*

Mercury, Total*

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(b)fluoranthene

Benzo(k)fluoranthene

Benzo(a)pyrene

Chrysene

Fluoranthane

Fluorene



# Naphthalene

Phenanthrene

Pyrena

Benzo(ghi)perylene

Dibenzo(a,h)anthracene

Indeno(l,2,3-cd)pyrene EPA Method No.



# 200.8

200.8



# 200.8

200.9



# 602

420.1

1631



# 245.7

610

610

610

610

610

610

610

610

610

610

610

610

610

610

610

610 Method Detection Level (ug/1)



# 0.5

1.8

1



# 0.6

0.2



# 5

0.0002

0.0018

1.8



# 2.3

0.66

0.01

0.018

0.017

0.02



# 0.15

0.21

0.21



# 1.8



# 0.64

0.27

0.076



# 0.03

0.04

*The permittee may use either EPA Test Method 1631 or 245.7 for mercury.



# 29. Sampling for total suspended solids at Outlet 097 shall be flow-proportional to reflect the quality of water from two

water intakes (pump house at the Steubenville North Plant and the pump station on WV side of the river).

30. The ZID granted for Outlet 006 extends approximately 6.0 meters downstream of Outlet 006. The CMZ for chronic

aquatic life criteria granted for Outlet 006 extends approximately 49.2 meters downstream of Outlet 006. The CMZ

for noncarcinogen human health criteria granted for Outlet 006 extends approximately 49.2 meters downstream of

Outlet 006. The permittee shall conduct a mixing zone verification study per Section B of this permit. Monitoring

for this study shall be conducted between the months of August and October. Monitoring for this study shall be

conducted during normal operations, production, and discharge at the facility. The permittee shall attempt to

conduct this study during low flow conditions in the Ohio River. For the purposes of this study, low flow

conditions shall be defined as less than 7,500 cubic feet per second in the Ohio River. The Agency recognizes that

this condition may not occur prior to the time specified in Section B ofthis permit. If this low flow condition is not

met by the deadline in Section B of this permit, the permittee shall conduct this study between the months of August

and October in 2014.

# Section C -Other Requirements Page No.: 41 

# of 46

Permit No.: WV0004499

30. a. The permittee shall monitor Outlet 006, immediately upstream and outside the influence ofthe discharge from

Outlet 006, and the following downstream verification locations concurrently (the same day) for flow rate,

temperature, pH, hardness, total suspended solids, total aluminum, ammonia nitrogen, total arsenic, chloride,

total copper, free cyanide, fluoride, iron, mercury, nitrate nitrogen, nitrite nitrogen, total selenium, total

residual chlorine, zinc, total phenolics, and total cyanide, and any other pollutant for which a mixing zone may

be requested in the future. All monitoring shall be representative of normal operations and discharge levels at

the facility. Monitoring for Outlet 006 shall be in accordance with its respective requirements defined in

Sections A and C ofthis permit. Monitoring at the following verification locations shall consist of three

depths: a surface, an approximate mid depth, and an approximate bottom sample. The depth of each sample

shall be recorded and each sample analyzed separately. Test Methods used at the verification points shall be in

accordance with Section C of the permit.

b. I meter downstream of Outlet 006 and 95 meters from the stream bank.

I meter downstream of Outlet 006 and 115 meters from the stream bank.

I meter downstream of Outlet 006 and 125 meters from the stream bank.

I meter downstream of Outlet 006 and 13 5 meters from the stream bank.

I meter downstream of Outlet 006 and 145 meters from the stream bank.

6.2 meters downstream of Outlet 006 and 95 meters from the stream bank.

6.2 meters downstream of Outlet 006 and 115 meters from the stream bank.

6.2 meters downstream of Outlet 006 and 125 meters from the stream bank.

6.2 meters downstream of Outlet 006 and 135 meters from the stream bank.

6.2 meters downstream of Outlet 006 and 145 meters from the stream bank.

I 0 meters downstream of Outlet 006 and 95 meters from the stream bank.

I 0 meters downstream of Outlet 006 and 115 meters from the stream bank.

10 meters downstream of Outlet 006 and 125 meters from the stream bank.

I 0 meters downstream of Outlet 006 and 13 

# 5 meters from the stream bank.

10 meters downstream of Outlet 006 and 145 meters from the stream bank.

35 meters downstream of Outlet 006 and 70 meters from the stream bank.

35 meters downstream of Outlet 006 and 90 meters from the stream bank.

35 meters downstream of Outlet 006 and 110 meters from the stream bank.

35 meters downstream of Outlet 006 and 130 meters from the stream bank.

35 meters downstream of Outlet 006 and 150 meters from the stream bank.

35 meters downstream of Outlet 006 and 170 meters from the stream bank.

50 meters downstream of Outlet 006 and 70 meters from the stream bank.

50 meters downstream of Outlet 006 and 90 meters from the stream bank.

50 meters downstream of Outlet 006 and II 0 meters from the stream bank.

50 meters downstream of Outlet 006 and 130 meters from the stream bank.

50 meters downstream of Outlet 006 and 150 meters from the stream bank.

50 meters downstream of Outlet 006 and 170 meters from the stream bank.

72 meters downstream of Outlet 006 and 70 meters from the stream bank.

72 meters downstream of Outlet 006 and 90 meters from the stream bank.

72 meters downstream of Outlet 006 and II 0 meters from the stream bank.

72 meters downstream of Outlet 006 and 130 meters from the stream bank.

72 meters downstream of Outlet 006 and !50 meters from the stream bank.

72 meters downstream of Outlet 006 and 170 meters from the stream bank.

c. Upon completion, the permittee shall submit the study results including all sampling results along with

corresponding lab sheets as specified in Section B 

# of this permit.

d. The permittee may elect use a dye tracer/indicator parameter in lieu of sampling for the above mentioned

pollutants 

# in Section C.30.a at the verification locations noted 

# In Section C.30.a- C.30.b based on the

following conditions.

# Section 

# C

- Other Requirements Page No.: 42 of 46

Permit No.: WV0004499

30. d. I) The permittee must select a dye tracer/indicator with a concentration in the discharge that is high enough

to be recognized by the downstream plume study sampling locations prescribed in Section C.30.b.

2) The dye tracer/indicator shall have been introduced into Outlet 006 at a constant concentration and

allowed to continuously discharge for a minimum of 12 hours prior to sampling at the verification

locations.

3) The permittee shall still follow all other requirements identified in Section C.30 and subparts C.30.aC.30.c.

4) The permittee shall still be required to sample the discharge from Outlet 006, immediately upstream and

outside the influence of the discharge from Outlet 006, and at the locations listed below for all of the

pollutants listed in Section C.30.a in order to verity that water quality criteria for these pollutants are

being achieved at the edge of the zone of initial dilution and chronic mixing zone. All protocols identified

in Section C.30 and Section C.30.a- C.30.c shall be followed including surface, mid-depth, and bottom

sampling at each location.

6.2 meters downstream of Outlet 006 and 95 meters from the stream banlc

6.2 meters downstream of Outlet 006 and 125 meters from the stream bank.

6.2 meters downstream of Outlet 006 and 145 meters from the stream bank.

50 meters downstream of Outlet 006 and 70 meters from the stream bank.

50 meters downstream of Outlet 006 and 120 meters from the stream bank.

50 meters downstream of Outlet 006 and 170 meters from the stream bank.

31. The CMZ for carcinogen human health criteria granted for Outlet 006 extends approximately 1126.5 meters

downstream of Outlet 006. The permittee shall conduct a mixing zone verification study per Section B of this

permit. Monitoring for this study shall be conducted during normal operations, production, and discharge at the

facility. The permittee shall attempt to conduct this study during the harmonic mean flow condition of the Ohio

River (20,500 cfs). For the purposes of this study, acceptable flow conditions shall be defmed as between 20,500

cfs and 23,000 cfs in the Ohio River. The Agency recognizes that this condition may not occur prior to the time

specified in Section B of this permit. Ifthis flow range is not met by the deadline in Section B of this permit, the

permittee shall conduct this study in 2014 at a stream flow as close as possible to the range prescribed above;

however, the flow in the stream must be at least 20,500 cfs.

a. The permittee shall monitor Outlet 006, immediately upstream and outside the influence of the discharge from

Outlet 006, and the following downstream verification locations concurrently (the same day) for flow rate,

temperature, pH, total suspended solids, benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,

benzo(k)fluoranthene, chrysene, dibenzo(a,h)anthracene, and indeno(1,2,3-cd)pyrene, and any other

carcinogen pollutant for which a mixing zone may be requested in the future. All monitoring shall be

representative of normal operations and discharge levels at the facility. Monitoring for Outlet 006 shall be in

accordance with its respective requirements defined in Sections A and C of this permit. Monitoring at the

following verification locations shall consist of three depths: a surface, an approximate mid depth, and an

approximate bottom sample. The depth of each sample shall be recorded and each sample analyzed separately.

Test Methods used at the verification points shall be in accordance with Section C of the permit.

b. 1120 meters downstream of Outlet 006 and I 0 meters from the stream bank.

1120 meters downstream of Outlet 006 and 20 meters from the stream bank.

1120 meters downstream of Outlet 006 and 40 meters from the stream bank.

1120 meters downstream of Outlet 006 and 80 meters from the stream bank.

1120 meters downstream of Outlet 006 and 95 meters from the stream bank.

1120 meters downstream of Outlet 006 and II 0 meters from the stream bank.

1120 meters downstream of Outlet 006 and 125 meters from the stream bank.

1120 meters downstream of Outlet 006 and 140 meters from the stream bank.

1120 meters downstream of Outlet 006 and !55 meters from the stream bank.

1120 meters downstream of Outlet 006 and 160 meters from the stream bank.

1120 meters downstream of Outlet 006 and 175 meters from the stream bank.

1120 meters downstream of Outlet 006 and 190 meters from the stream bank.

# Section 

# C - Other Requirements Page No.: 43 of 46

Permit No.: 

# WV0004499

31. c. Upon completion, the permittee shall submit the study results including all sampling results along with

corresponding lab sheets as specified in Section B of this permit.

d. The permittee may elect use a dye tracer/indicator parameter in lieu of sampling for the above mentioned

pollutants in Section C.3l.a at the verification locations noted In Section C.3l.a- C.30.b based on the

following conditions.

l) The permittee must select a dye tracer/indicator with a concentration in the discharge that is high enough

to be recognized by the downstream plume study sampling locations prescribed in Section C.3l.b.

2) The dye tracer/indicator shall have been introduced into Outlet 006 at a constant concentration and

allowed to continuously discharge for a minimum of 12 hours prior to sampling at the verification

locations.

3) The permittee shall still follow all other requirements identified in Section C.31 and subparts C.31.aC.3l.c.

4) The permittee shall still be required to sample the discharge from Outlet 006, immediately upstream and

outside the influence of the discharge from Outlet 006, and at the locations listed below for all of the

pollutants listed in Section C.3l.a in order to verify that water quality criteria for these pollutants are

being achieved at the edge of the zone of initial dilution and chronic mixing zone. All protocols identified

in Section C.3l and Section C.3l.a- C.3l.c shall be followed including surface, mid-depth, and bottom

sampling at each location.

1120 meters downstream of Outlet 006 and 20 meters from the stream bank.

1120 meters downstream of Outlet 006 and l 00 meters from the stream bank.

1120 meters downstream of Outlet 006 and 190 meters from the stream bank.

32. The temperature difference between the upstream/intake location and the discharge shall be calculated by

subtracting the discharge temperature from the upstream/intake temperature measured in the Ohio River. The

upstream/intake temperatures and discharge temperatures required by Section A of this permit shall be collected

concurrently. Concurrently shall be defined as no more than 60 minutes between monitoring collected at the

upstream/intake location in the Ohio River and the respective discharges.

33. For purposes of identity, in this permit, Outlet No.004 refers to discharges from the combination of existing Internal

Outlet Nos. 105 and former 305 into a new dedicated outlet at the same location as former Outlet No. 005. Outlet

No.006 refers to discharges from the separation of former Internal Outlet No. 205 from former Outlet No. 005 to

the new dedicated Outlet No. 006.

Former Internal Outlet Nos. 205 and 305 and former Outlet No. 005 have been removed from the permit.

# Section D- 316 (b) Intake Requirements Page No.: 44 of 46

Permit No.: WV0004499



# I. In accordance with 316(b) of the Clean Water Act, the location, design, construction, and capacity of the cooling

water intake structures (CWIS) for the permittee's facility shall reflect the best technology available (BTA) for

minimizing adverse environmental impact.

2. On the basis of currently available information, the agency has determined that the BTA alternatives for this facility

shall be one, or a combination, ofthe following:

a. Behavioral barriers, which alter or take advantage of natural behavioral patterns to attract or repel fish and

physical barriers, which physically block fish passage.

b. Collection systems which actively collect fish for their return to a safe release location.

c. Diversion systems which divert fish to bypasses for their return to safe release location.

d. Flow reduction systems which reduce intake flow commensurate with closed cycle cooling systems.

e. A reduction in the intake velocity such that the flow inake velocity is equal to, or less than, 0.5 feet per second.

f. Some facilities may have existing technologies in place for their intake system and may be able to demonstrate

that existing technologies may meet the BTA requirements of316(b) of the CW A. Similarly, some facilities

may determine that alternate technologies than those identified in this permit may meet the BTA requirements

of316(b) of the CWA. The agency will consider these on a case-by-case basis.

3. The permittee shall complete a study of its existing cooling water intake structures and the effects offish and other

aquatic organisms within 15 months after the issuance if this permit. This study shall include, but not be limited to,

an analysis of the existing influent plume and current levels of impingement and entrainment and associated

mortality. The permittee shall submit a comprehensive report no later than 45 days after completing its study. The

report shall set forth the research methodologies used and the results and shall also identify and describe all

existing intake structures at the facility including the location, stream source, design flow, average intake flow,

percent of intake flow used for cooling water and the average intake flow velocity.

4. The permittee shall submit a Compliance Demonstration Work Plan (CDWP) no later than 30 months after the

issuance of this permit along with a permit modification application that identifies its selected BTA alternative(s) to

reduce the impingement and entrainment impacts of the CWIS as required by 316(b) of the Clean Water Act. The

CDWP shall identify the impingement and entrainment reductions which will be attained through implementation of

the selected BTA alternatives. This CDWP shall also include, but not be limited to, the following information:

a. A description of the proposed technologies and operational measures to be implemented at the facility.

b. A summary of any past or ongoing consultations with appropriate Federal, State, and wildlife agencies that are

relevant to 316(b) and a copy of written comments received as a result of such consultations

c. A sampling plan for any new field studies proposed to be conducted in order to ensure that sufficient data

exists to develop a scientifically valid estimate of impingement mortality and entrainment at the facility. In

general, the sampling plan shall include methodologies of measuring impingement and entrainment reductions

to be attained after implementation of selected BTA alternatives to verify targeted reductions are achieved.

The sampling plan must document all methods and quality assurance/quality control procedures for sampling

and data analysis. The sampling and data analysis methods proposed must be appropriate for a quantitative

survey and include consideration of the methods used in other studies performed in the source waterbody. The

sampling plan must include a description of the cooling water intake structure(s), and provide a taxonomic

identification of the sampled or evaluated biological assemblages (including all life stages offish and shellfish).

If the permittee decides to pursue, or already has implemented, technologies that meet the requirements fouud

in Sections D.2.d and/or D.2.e above; then, a measurement of the flow reduction and/or intake velocity shall

suffice as meeting impingement and entrainment reductions and the above described sampling plan is not

necessary.

d. A plan and schedule to implement the CDWP.

5. The permittee shall implement the CDWP upon written approval by the Agency. The permittee shall submit

semi-annual progress reports to the Agency, outlining progress on the obligations contained in the CDWP. The

reports shall be submitted on or before February I and August I of each year. The reports shall include information

relating to any delays or problems complying with the obligations in the approved CDWP.

# Section D- 316 (b) Intake Requirements Page No.: 45 of 46

Permit No.: WV0004499



# 6. The Agency, in consultation with EPA, will evaluate the results of the permittee's 316(b) CDWP and determine, on

the basis of best professional judgement, whether the currently implemented and proposed technologies and other

measures reflect BTA, as required by 316(b ). Pursuant to 40 

# CFR 122.62, if the Agency and/or EPA determines

that the currently implemented technologies and other measures do not reflect BTA, the permit may be reopened

and modified to include a 316(b) compliance schedule, which may include but not necessarily be limited to

proposed design and construction technologies and/or operational measures identified by the permittee. Pursuant to

40 

# CFR 122.62, the permit may also be reopened and modified with requirements of new regulations, standards, or

judicial decisions relating to 316(b ).

7. Continued and future compliance with Section 316(b) of the Clean Water Act will be determined from a successful

implementation of the CDWP which reflects that the design and construction technologies and/or operational

measures that the permittee has selected and installed, or will install, at the facility meet the applicable requirements

of316(b) of the Clean Water Act including BTA.

# Page No.: 46 of 46

Permit No.: WV0004499

The herein-described activity is to be extended, modified, added to, made, enlarged, acquired, constructed or

installed, and operated, used and maintained strictly in accordance with the terms and conditions of this permit, with

the plans and specifications submitted with Permit Application No. WV0004499; with the plan of maintenance and

method of operation thereof submitted with such application(s); and with any applicable rules and regulations

promulgated by the Enviromnental Quality Board and the Secretary of the Department of Environmental Protection.

Failure to comply with the terms and conditions of this permit, with the plans and specifications submitted with

Permit Application No. WV0004499; and with the plan of maintenance and method of operation thereof submitted

with such application( s) shall constitute grounds for the revocation or suspension of this permit and the invocation of

all the enforcement procedures set forth in Chapter 22, Article 11, or 15 of the Code of West Virginia.

This permit is issued in accordance with the provisions of Chapter 22, Article II and 12 and/or 15 of the Code of

West Virginia and is transferable under the terms of Section 11 of Article II.

# ~U/£1 Scott G. Mandirola, Director

# Appendix A

I. MANAGEMENT CONDITIONS:

1. Duty to Comply

a)

b) 

# The permittee must comply with all conditions of this permit. Permit noncompliance constitutes a violation of the CWA and State Act and is

grounds for enforcement action; for pennit modification, revocation and rcissuance, suspension or revocation; or for denial of a permit renewal



# application.

The permittee shall comply with all effluent standards or prohibitions established under Section 307(a) of the CWA for toxic pollutants within

the time provided in the regulations that establish these standards or prohibitions, even if 

# the penn it 

# has not yet been modified to incorporate

the requirement.

2. Duty to Reapply

If the permittee wishes to continue an activity regulated by this permit after the expiration date of this permit, the pennittee must apply for a new permit at

least 180 days prior to expiration of the permit.

3. 

# Duty to Mitigate

The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this permit, which has a reasonable likelihood of

adversely affecting human health or the environment.

4. Permit Actions

This permit may be modified, revoked and reissued, suspended, or revoked for cause. The filing of a request by the permittee for permit modification,

revocation and reissuance, or revocation, or a notification of planned changes or anticipated noncompliance, does not stay any permit condition.



# 5. Property Rights

This permit does not convey any property rights of any sort or any exclusive privilege.



# 6. Signatory Requirements

All applications, reports, or information submitted to the Director shall be signed and certified as required in Title 47, Series 10, Section4.6 of the West

Virginia Legislative Rules.

7. Transfers

This permit is not transferrable to any person except after notice to the Director. The Director may require modification or revocation and reissuance of the

permit to change the name of the permittee and incorporate such other requirements as may be necessary.

8. Duty to Provide Information

The permittee shall furnish to the Director, within a reasonable specified time, any information which the Director may request to determine whether cause

exists for modifying, revoking and reissuing, suspending, or revoking this permit, or to determine compliance with this permit. The permittee shall also

furnish to the Director, upon request, copies of records required to be kept by this permit.

9. 

# Other Information

Where the pennittee becomes aware that it failed to submit any relevant facts in a permit application, or submitted incorrect information in a permit

application or in any report to the Director, it shall promptly submit such facts or information.

10. Inspection and Entry

The permittee shall allow the Director, or an authorized representative, upon the presentation of credentials and other documents as may be required by law,

to:

a)

b)

c)



# d) Enter upon the permittee's premises in which an effluent source or activity is located, or where records must be kept under the conditions of this

pennit;

HaVe access to and copy at reasonable times, any records that must be kept under the conditions of this permit;

Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices, or operations regulated or required under this permit; and

Sample or monitor at reasonable times, for the purposes of assuring permit compliance or as othenvise authorized by the State Act, any

substances or parameters at any location.

11. Permit Modification

This permit may be modified, suspended, or revoked in whole or in part during its term in accordance with the provisions of Chapter 22-11-12 of the

Code of West Virginia.

12. Water Quality

Subject to 47 WV CSR 10.3.4.a, the effluent or effluents covered by this permit are to be of such quality so as not to cause violation of applicable water quality

standards.

13. Outlet Markers

A penn anent marker at the establishment shall be posted in accordance with Title 47, Series ll, Section 9 of the West Virginia Legislative Rules.

14. Liabilities

a)



# b)

c)



# d) Any person who violates a permit condition implementing sections 301, 302, 306, 307, 308, 318, or 405 of the Clean Water Act is subject to a

civil penalty not to exceed $25,000 per day of such violation. Any person who willfully or negligently violates permit conditions

implementing sections 301, 302,306,307,308 or 405 of the Clean Water Act is subject to a fine of not less than $2,500 nor more than $25,000 per day of violation, or by imprisonment for not more than 1 year, or both.

Any person who falsifies, tampers with, or knowingly renders inaccurate any monitoring device or method required to be maintained under

this permit shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than 2

years, or by both.

Any person who knowingly makes any false statement, representation, or certification in any record or other document submitted or required to

be maintained under this permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction, be punished

by a fine of not more than $10,000 per violation, or by imprisonment for not more than 2 years, or by both.

Nothing in 1.14 a), b), and c) shall be construed to limit or prohibit any other authority the Director may have under the State Water Pollution

Control Act, Chapter 22, Article 11.

# II. OPERATION AND MAINTENANCE:

l. 

# Proper Operation and Maintenance

The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are

installed or used 

# by the permittee to achieve compliance with the conditions of this permit. Proper operation and maintenance also includes adequate

laboratory controls, and appropriate quality assurance procedures. Unless otherwise required 

# by Federal or State law, this provision requires the operation

of back-up auxiliary facilities or similar systems which are installed 

# by the permittee only when the operation is necessary to achieve compliance with the

conditions of the pennit. For domestic waste treatment facilities, waste treatment operators as classified by the WV Bureau of Public Health Laws, W.Va.

Code Chapter 

# 16-1, will be required except that in circumstances where the domestic waste treatment facility is receiving any type of industrial waste, the

Director may require a more highly skilled operator.



# 2. Need to Halt 

# or Reduce Activity Not a Defense



# 3. Bypass

4. Upset 

# It shall not be a defense for 

# a pennittee in an enforcement action that 

# it would have been necessary to halt or reduce the permitted activity in order to

maintain compliance with the conditions of the permit.

a) Definitions

(l) "Bypass" means the intentional diversion of waste streams from any portion of a treatment facility; and

(2) "Severe property damage" means substantial physical damage to property, damage to the treatment facilities which causes them to

become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence

of a bypass. Severe property damage does not mean economic loss caused by delays in production.

b) Bypass not exceeding limitations. The permittee may allow any bypass to occur which does not cause effluent limitations to be exceeded, but

only if it also is for essential maintenance to assure efficient operation. These bypasses are not subject to the provision ofll.3.c) and II.3.d) of

this permit.

c) 

# (I) If the permittee knows in advance of the need for a byp'ass, it shall submit prior notice, if possible at least ten (10) days before the

date of the bypass;

(2) If the permittee does not know in advance of the need for bypass, notice shall be submitted as required in IV.2.b) of this pennit.

d) Prohibition of bypass

(l) Bypass is permitted only under the following conditions, and the Director may take enforcement action against a pennittee for a

bypass, unless;

(A) Bypass was unavoidable to prevent loss of life, personal injury, or severe property damage;

(B) There were no feasible alternatives to the bypass, such as the use of auxiliary treatment facilities, retention of untreated

wastes, or maintenance during nonnal periods of equipment downtime. This condition is not satisfied if adequate backup

equipment should have been installed in the exercise of reasonable engineering judgement to prevent a bypass which

occurred during normal periods of equipment downtime or preventative maintenance; and

(C) The pennittee submitted notices as required under IIJ.c) of this pennit.

(2) The Director may approve an anticipated bypass. after considering its adverse effects. if the Director determines that it will meet the

three conditions listed in II.3.d.(l) of this permit.

a) Definition. "Upset" means an exceptional incident in which there is unintentional and temporary noncompliance with technology-based permit

effluent limitations because of factors beyond the reasonable control of the pennittee. An 

# upset does not include noncompliance to the extent

caused by operational error, improperly designed treatment facilities, inadequate treatment facilities, lack of preventative maintenance, or

careless or improper operation.

b) Effect of an upset. An upset constih1tes an affinnative defense to an action brought for noncompliance with such technology-based permit

effluent limitation if the requirements ofll.4.c) are met. No determination made during administrative review of claims that noncompliance

was caused by upset, and before an action for noncompliance, is final administrative action subject to judicial review.

c) Conditions necessary for a demonstration of upset. A pennittee who wishes to establish the affirmative defense of upset shall demonstrate,

through properly signed, contemporaneous operating logs, or other relevant evidence that

(1) An upset occurred and that the permittee can identify the cause(s) of the upset;

(2) The pennitted facility was at the time being properly operated;

(3) The pennittee submitted notice of the upset as required in IV.2.b) of this permit.

(4) The permittee complied with any remedial measures required under 1.3. of this pennit.

d) Burden of proof. In any enforcement proceeding the permittee seeking to establish the occurrence of an upset has the burden of proof.

5. Removed Substances

Where removed substances arc not otherwise covered by the terms and conditions of this permit or other existing permit by the Director, any solids, sludges,

filter backwash or other pollutants (removed in the course of treatment or control of wastewaters) and which are intended for disposal within the State,

shall be disposed of only in a manner and at a site subject to the approval by the Director. If such substances are intended for disposal outside the State or for

reuse, i.e., as a material used for making another product, which in turn has another use, the permittee shall notify the Director in writing of the proposed

disposal or use of such substances, the identity of the prospective disposer or users, and the intended place of disposal or use, as appropriate.

# III. MONITORING AND REPORTING

I. 

# Representative Sampling

Samples and measurements taken for the purpose of monitoring shall be representative of the monitored activity.



# 2. Reporting

a) Permittee shall submit, according to the enclosed format, a Discharge Monitoring Report (DMR) indicating in terms of concentration, and/or

quantities, the values of the constituents listed in Part A analytically detennined to be in the plant effiuent(s). DMR submissions shall be made

in accordance with the terms contained in Section C of this permit.

b)

c)



# d) Enter reported average and maximum values under "Quantity" and "Concentration" in the units specified for each parameter, as appropriate.

SpecifY the number of analyzed samples that exceed the allowable pennit conditions in the columns labeled "N.E." (i.e., number exceeding).

SpecifY frequency of analysis for each parameter as number of analyses/specified period (e.g.,3/month is equivalent to 

# 3 analyses performed

every calendar month). If continuous, enter "Cont.". The frequency listed on format is the minimum required.

3, Test Procedures

Samples shall be taken, preserved and analyzed in accordance with the latest edition of 40 CFR Part 136, unless other test procedures have been specified

elsewhere in this permit.

4. Recording of Results

For each measurement or sample taken pursuant to the permit, the permittee shall record the following information.

a) The date, exact place, and time of sampling or measurement;

b) The date(s) analyses were performed;

c) The individual(s) who performed the sampling or measurement;

d) The individual(s) who performed the analyses; if a commercial laboratory is used, the name and address of the laboratory;

e) The analytical techniques or methods used, and



# f) The results of such analyses. Information not required by the DMR form is not to be submitted to this agency, but is to be retained as required

in III.6.



# 5. 

# Additional Monitoring by Permittee

If the permittee monitors any pollutant at any monitoring point specified in this permit more frequently than required by this permit, using approved test

procedures or others as specified in this permit, the results of this monitoring shall be included in the calculation and reporting of the data submitted in the

Discharge Monitoring Report Form. Such increased frequency shall also be indicated. Calculations for all limitations which require averaging of

measurements shall utilize an arithmetic mean unless otherwise specified in the pennit.

6. 

# Records Retention

7. 

# The permittee shall retain records of all monitoring information, including all calibration and maintenance records and all original chart recordings for

continuous monitoring instrumentation, copies of all reports required by this permit, and records of all data used to complete the application for the permit,

for a period of at least three (3) years from the date of the sample, measurement, report or application. This period may be extended by request of the

Director at any time.

Definitions

a)

b)

c)



# d)

e)

f)

g)



# h)



# i)

j)

k)

I) 

# "Daily discharge" means the discharge of a pollutant measured during a calendar day or within any specified period that reasonably represents

the calendar day for purposes of sampling. For pollutants with limitations expressed in units of mass, the daily discharge is calculated as the

total mass of the pollutant discharged over the day. For pollutants with limitations expressed in other units of measurement, the daily discharge

is calculated as the average measurement of the pollutant over the day.

"Average monthly discharge limitation" means the highest allowable average of daily discharges over a calendar month, calculated as the sum

of all daily discharges measured during a calendar month divided by the number of daily discharges measured during that month.

11 

# Maximum daily discharge limitation" means the highest allowable daily discharge.

"Composite Sample" is a combination of individual samples obtained at regular intervals over a time period. Either the volume of each

individual sample is proportional to discharge flow rates or the sampling interval (for constant volume samples) is proportional to the flow rates

over the time period used to produce the composite. The maximum time period between individual samples shall be two hours.

"Grab Sample" is an individual sample collected in less than 15 minutes.

"is" "" immersion stabilization - a calibrated device is immersed in the effluent stream until the reading is stabilized.

The "daily average temperature" means the arithmetic average of temperature measurements made on an hourly basis, or the mean value plot of

the record of a continuous automated temperature recording instrument, either during a calendar month, or during the operating month if flows

are of shorter duration.

The "daily maximum temperature" means the highest arithmetic average of the temperatures observed for any two (2) consecutive hours during

a 24 hour day, or during the operating day if flows are of shorter duration.

The "monthly average fecal coliform 11 

# bacteria is the geometric average of all samples collected during the month.

"Measured Flow" means any method of liquid volume measurement, the accuracy of which has been previously demonstrated in engineering

practice, or which a relationship to absolute volume has been obtained.

"Estimate" means to be based on a technical evaluation of the sources contributing to the discharge including, but not limited to pump

capabilities, water meters and batch discharge volumes.

"Non-contact cooling water" means the water that is contained in a leak-free system, i.e., no contact with any gas, liquid, or solid other than the

container for transport; the water shall have no net poundage addition of any pollutant over intake water levels, exclusive of approved antifouling agents.

# IV. OTHER REPORTING

1. Reporting Spills and Accidental Discharges



# Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the permittee from any responsibilities, liabilities or

penalties established pursuant to Title 47, Series 11, Section 2 of the West Virginia Legislative Rules promulgated pursuant to Chapter 22, Article 11.

Attached is a copy of the West Virginia Spill Alert System for use in complying with Title 47, Series 11, Section 2 of the Legislative rules as they pertain

to the reporting of spills and accidental discharges.



# 2. Immediate Reporting

a) The permittee shall report any noncompliance which may endanger health or the environment immediately after becoming aware of the



# circumstances by 

# using the Agency's designated spill alert telephone number. A written submission shall be provided within five (5) days of

the time the pennittee becomes aware of the circumstances. The written submission shall contain a description of the noncompliance and its**cause~** 

# the period of noncompliance, including exact dates and times, and if the noncompliance has not been corrected, the anticipated time it is

expected to continue; and steps taken or planned to reduce, eliminate, and prevent recurrence of the noncompliance.

b) 

# The following shall also be reported immediately:

(I) 

# Any unanticipated bypass which exceeds any effluent limitation in the penn it;

(2) Any upset which exceeds any effluent limitation in the permit; and

(3) 

# Violation of a maximum daily discharge limitation for any of the pollutants listed by the Director in the permit shall be reported

immediately. This list shall include any toxic pollutant or hazardous substance, or any pollutant specifically identified as the

method to control a toxic pollutant or hazardous substance.

c) The Director may waive the written report on a case-by-case basis if the oral report has been received in accordance with the above.

d) Compliance with the requirements oflV.2 of this section, shall not relieve a person of compliance with Title 47, Series ll, 

# Section 2.

3. Reporting Requirements



# a) Planned changes. The permittee shall give notice to the Director of any planned physical alterations or additions to the permitted facility which

may affect the nature or quantity of the discharge. Notice is required when:

(l) 

# The alteration or addition to a permitted facility may meet one of the criteria for detennining whether a facility is a new source in

Section l3.7.b of Series 10, Title 47; or

(2) The alteration or addition could significantly change the nature or increase the quantity of pollutants discharged. This notification

applies to pollutants which are subject neither to effluent limitations in the permit, nor to notification requirements under IV.2 of this

section.

b) Anticipated noncompliance. The permittee shall give advance notice to the Director of any planned changes in the permitted facility or activity

which may result in noncompliance with pennit requirements.

c) In addition to the above reporting requirements, all existing manufacturing, commercial, and silvicultural discharges must notify the Director in

writing as soon as they know or have reason to believe:

(l) 

# That any activity has occurred or will occur which would result in the discharge, on a routine or frequent basis, or any toxic

pollutant which is not limited in the permit, if that discharge will exceed the highest of the following "notification levels":

(A) One hundred micrograms per liter (100 ug/1);

(B) 

# Two hundred micrograms per liter (200 ug/1) for acrolein and acrylonitrile; five hundred micrograms per liter (500 

# ugll)

for 2,4-dinitro phenot and for 2-methyl4,6-dinitrophenol; and one milligram per liter (1 

# mg/1) for antimony;

(C) 

# Five (5) times the maximum concentration value reported for that pollutant in the permit application in accordance with

Section 4.4.b.9 ofSerieslO, Title 47.

(D) The level established by the Director in accordance with Section 6.3.g of Series 10, Title 47;

(2) That any activity has occurred or will occur which would result in any discharge (on a non-routine or infrequent basis) of 

# a toxic

which is not limited in the permit, if that discharge will exceed the highest of the following "notification levels":

(A) 

# Five hundred micrograms per liter (500 ugll);

(B) 

# One milligram per liter (1 

# mg/1) for antimony;

(C) Ten (10) 

# times the maximum concentration value reported for that pollutant in the permit application in accordance with

Section 4.4.b.7 of Series 10, 

# Title 47;

(D) 

# The level established by the Director in accordance with Section 6.3.g of Series 10, 

# Title 47.

(3) 

# That they have begun or expect to begin to use or manufacture as an intennediate or final product or by-product of any toxic

pollutant which was not reported in the pennit application under Section 4.4.b.9 of Series 10, Title 47 and which will result in the

discharge on a routine or frequent basis of that toxic pollutant at levels which exceed five times the detection limit for that pollutant

under approved analytical procedure.

( 4) That they have begun or expect to begin to use or manufacture as an intennediate or final product or by-product of any toxic

pollutant which was not reported in the permit application under Section4.4.b.9 of Series 10, Title 47 and which will result in the

discharge on a non-routine or infrequent basis of that toxic pollutant at levels which exceed ten times the detection limit for that

pollutant under approved analytical procedure.

4. 

# Other Noncompliance

The permittee shall report all instances of noncompliance not reported under the above paragraphs at the time monitoring reports are submitted. The

reports shall contain the information listed in IV.2.a). Should other applicable noncompliance reporting be required, these terms and conditions will be

found in Section C of this permit.WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLC\MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyCERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:PERMITNO.:WV0004499OUTLErNO.:,004=.._____WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·'.·.·..·.·...·.·.•...·.."'t··.,..-·.·.··I-..-<Quantity·otherUnitsInterimLimitationsIUnitsN.E·CEL*Measurement.,.SampleUnitsIN£.1,.FrequencyType50050(ML-1)RF-AFlow,inConduitorthruplantYearRound00530(ML-2)RF-ATotalSuspendedSolidsYearRound74055(ML-1)RF-AColiform,FecalYearRound00400(ML-1)RF-ApHYearRound00610(ML-1)RF-BAmmoniaNitrogenYearRound00600(ML-1)RF-BNitrogen,Total(asN)YearRound00665(ML-1)RF-BPhosphorus,TotalYearRound50060(ML-1)RF-BChlorine,TotalResidualYearRoundReportedPermitLimitsReportedPermitLimitsReported'PermitLimitsReportedPermitLimitsReportedPermitLimitsReportedPermitLimitsReportedPermitLimitsReportedPermitLimits*CEL=Co'TI.I2!lanceEvaluationLevelN/ANIAN/ANIAN/ARptOnlyAvg.MonthlyRptOnlyAvg.MonthlyN/AN/AN/AN/AN/AN/ARptOnlyMax.DailyRptOnlyMax.DailyN/ANIAIN/ANIAlnstMin.NIALbs!DayN/ALbs!DayIN/AN/ARptOnlyAvg.MonthlyRptOnlyAvg.Monthly200Mon.Geo.MeanN/ARptOnlyAvg.MonthlyRptOnlyAvg.MonthlyRptOnlyAvg.MonthlyRptOnlyAvg.MonthlyRptOnlyMax.Daily60Max.Daily400Max.Daily9lnslMax.RptOnlyMax.DailyRptOnlyMax.DailyRptOnlyMax.DailyRptOnlyMax.DailyN/AlmgdNIAlmg/1N/AICnls/1DOnNIAIS.U.NIAlmg/1N/Amg/1N/Amg/1NIAlug/!1/week1/month1/month1/month1/quarter1/quarter1/quarter1/quartermeasured24hrCompositeGrabGrab24hrComposite24hrComposite24hrCompositeGrabNameofPiiriCipaLEi<eeuthiedfficer...,.__..,ce.ltify__·....u...n·P...na_lty...o.·f.Ia.w_th.._at·_.th__.is.docu...._me__.f!t.anda__natta.ch...m..e.n_.we_re.pre_P_.ared..·..·0tCo1ted11:-'nd:rmyorsuperv1s1on1naccordanceWithasystemdes1gnedtoassurethatae.mpeJ1and.evaluatetheinfotrmilionsubrilittedBasedon. . .....·..•._•.•..·..1j!====c=c=======c==WillY.mgu1ry.ofthepers6gorper5ons.wh6managetheSystem,·orthosepersollsdirectlyS1gnature.ofPnnCipalEi<ecuti.veOfficerorT"rtleof.Officer.•.. . ..·..•.<;Spoi1Sibleforgalhertngtheinfonnation,theinformationsubmittedis;to.thebestofmyAuthonzedAgent. .··.·.·..1_:._d.ge·an·d.b.··.till.·e,a:cu_..._rate;Iam...·.awarethat!.herear.esignificantJf'<'nalties•forsubmittingfalsemfonmationmcludmgthepossibilityofafineand··..•imprisonmenfforknowing. .. .WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: (Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: **=004~-----** CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

I . ' · .. ··. . ._ .... -- . Quantity. _,. . Other Units

:Parameter ,· .. ·.

. . . . . ·. . Units N:E. .· . . . CEL*

01119 (ML-1) RF-B Reported

Copper, Total Recoverable NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01094 (ML-1) RF-B Reported

Zinc, Total Recoverable NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00718 (ML-1) RF-B Reported

Cyanide, Weak Acid Dissociable N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Perm tt Lim tts Avg. Monthly Max. Daily

71900 (ML-1) RF-B Reported

Mercury, Total (as Hg) N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01104 (ML-1) RF-B Reported

Aluminum, Total Recoverable N/A N/A NIA Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00980 (ML-1) RF-B Reported

Iron, Total Recoverable N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01055 (ML-1) RF-B Reported

Manganese, Total (as Mn) NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00940 (ML-1) RF-B Reported

Chloride (as Cl) NIA N/A N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

"" CEL = Compliance Evaluation Level Interim Limitations

. . Measurement Sample

·Units N.E. Frequency. Type·

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr Composite

ug/1 1/quarter Grab

ug/1 1/quarter Grab

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr

Composite

**~arne** <it Principal ExecutiVe Officer l. ce __ · **-~fy** ... **_u_n~** .. e_r.pe __ naJty__ o.f.Ia_w th.. _at_ **~.-** .. is __ .d.·ocu

__ ·. m_·

.. e.··. ·n·t .. an· ? aU att·a· _ch_ m_ e_n __ **~** were_· __ Pr_ ep. ared Date Completed 1

nd.er my **.d~eecl1on** orsuperv1s1on m accordance with a system des1gnedto assure that · II

**~pa!ifJe~ ~e~onoel**  prOperty gatherand evaluate the information submitted. Based on . . . . . . . . . 1

i!================:dl'my 1nquuy ofthe peTSOn orper.;ons who manage the system; or those persons directly S1gnature of PnnCipai.Executtve Officer or

Trtle of'Otlider .·· · · .. · . · · · esp6riSiple **foqjat~ering_** theinformation, the informationsubmitted is, to the best of my **.rA~uth_o..cnz** ___ **ed~_ c...A..:gc.;e~nt_~~~~~--~----,** 

l .. · · ··· · ···· no ____ wle ___ dg. e_·an_

.·. a

__ ._be. lief, .. tru····.· e, accura_

· .. ·. t. e., and, complete: I a_ m. **aware_th.~atth.ere** are significant

**~Penalties** .for submitting false. information including the posSibility of a fine and

-,-,,...,-...,.-,....,-,.,-.,.-...,.----,--,--" r,rnprisonmernfor Knowing violations. .. L._-,----,----,-WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:(MountainStateCarbonLLC\MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:,;004=------CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·,......··..··.....·..·.·..Quantitv".·I·...·.·OtherUnitsP..rarneter.·.Units·N.E.GEL*....·.·....00951(ML-1)RF-8ReportedFluoride,TotalN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPennitLimitsAvg.MonthlyMax.Daily34469(ML-1)RF-8ReportedPyreneN/AN/ANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34526(ML-1)RF-AReportedBenzo(A)AnthraceneNIANIAN/ARptOnlyRptOnlyN/AYearRoundPermrtLimitsAvg.MonthlyMax.Daily34320(ML-1)RF-AReportedChryseneN/AN/ANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34376(ML-1)RF-BReportedFluorantheneN/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34381(ML-1)RF-8ReportedFluoreneNIANIAN/ARptOnlyRptOnlyN/AYearRoundAvg.MonthlyMax.Daily34461(ML-1)RF-8Reported.PhenanthreneNIAN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax..Daily34200(ML-1)RF-8ReportedAcenaphthyleneN/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=Coi!!Q!_ianceEvaluationLevelInterimLimitations.Measurement.sampleUnits.N.EFrequency··.Typemg/11/quarter24hrCompositeug/11/quarter24hrCompositeNG/L1/month24hrCompositeNGJL1/month24hrCompositeugn1/quarter24hrCompositeug/11/quarter24hrCompositeug/11/quarter24hrCompositeugn1/quarter24hrCompositefN;ili,eofofficer.lofi<!W.thiSdocumentallwereprepared...Date.Completedrllundermyd1rectionormaccordanceWithasystemdes1gnedtoassurethat..·,·.II,u;;llifiedp.Orsonnetproperlygatherandevaluatetheinformationsubmitted.Base<l,on·.,·.·.•.•..:·....I•.y!inquiry.ofthe_personpi"personswhomanage_theS}'Stern,citthose.personsdirectly.Slgnatllre.ofPiinCJpalExecutiveOfficerortitleofo=ifi=ce=.r='.===========r..esponsibleforgatheringtheinformation,the.informationsubmittedis,tothe.bestofmy.Authonze<lAgent.···.·····nowle<lgean.d.l>elie_f,true;ae<:lirate,andcomplete.Iamawarethatthere.aresignificantenaltiesforsubmittingfalseipfonnationincludingthepossibilityofafineandknowingviolations:··WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:_,00""4'-------CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:InterimLimitationsWASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·..·.......·.··..·...·.···•Quantitv.·..·····.·OtherUnffsMeasurementParameter.I.·•.......·...I.·.. .·.UnitsN.E.CEL*.··Unffs.·N.E.·Frequency•..•.··I.I.34205(ML-1)RF-BReportedAcenaphtheneNIANIAN/ARptOnlyRptOnlyNIAug/11/quarterYearRoundPermitlimitsAvg.MonthlyMax.Daily34220(ML-1)RF-BReportedAnthraceneN/AN/AN/ARptOnlyRptOnlyNIAug/11/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily34230(ML-1)RF-AReportedBenzo{B)FluorantheneN/ANIANIARptOnlyRptOnlyN/ANG/L1/monthYearRoundPermitLimitsAvg.MonthlyMax.Daily34242(ML-1)RF-AReportedBenzo(K)FluorantheneNIAN/AN/ARptOnlyRptOnlyNIANG/L1/monthYearRoundPermitlimitsAvg.MonthlyMax.Daily34247(ML-1)RF-AReportedBenzo(A)PyreneNIAN/AN/ARptOnlyRptOnlyNIANG/L1/monthYearRoundPermttLimitsAvg.MonthlyMax.Daily00981(ML-1)RF-BReportedSelenium,TotalRecoverableN/AN/AN/ARptOnlyRptOnlyN/Au9/l1/quarterYearRoundPermitlimitsAvg.MonthlyMax.Daily00978(ML-1)RF-BReportedArsenic,TotalRecoverableN/A N/ANIARptOnlyRptOnlyN/Amg/11/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily34556(ML-1)RF-AReportedDibenzo{A,H)AnthraceneN/ANIANIARptOnlyRptOnlyN/ANG/L1/monthYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=EvaluationLevel·.SampleType24hrComposite24hrComposite24hrComposite24hrComposite24hrComposite24hrComposite24hrComposite24hrCompositeNameofPiincii>CIIExecOiiVeofficer.·r(;ertifyunderP¥lnal_tyallwereprepared·DateCompletedIodermyd1recbonorsuperv•s•on.maccordancewitt!asyS!errrdes1gnedioassurethat·,...·_·"""."'·.··..c:...•""'-.J-.,....---.,....-----4qu."Jilie<!personnelpropertygath-:ran<Je\r.iiluatethe1nfunmatioJ1submitte<(Bas':<!on:..·.......·.·_. .···.····.•·.·•c.!!================!!'mymqUJryofthepersonorpersonswho.managethesystem,orthosepersonsdlfectlyofExecutiveOfficerorTrtleofOfficer.···.infonmalion,theinformationsubmittejlis,tothe.bestofmy1········kn6wlt>dgeand:belief,.1i"ue;accurate;andcomplete:Iamawarethattherearesignificantpenafiiesfor.submittingfalseincludingthepossibilffyofafineandknowingyiolatiops...·..··.··......·...WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTCERTIFIEDLABORATORYNAME:FACILITYNAME:!MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyCERTIFIEDLABORATORYADDRESS:PERMITNO.:WV0004499OUTLETNO.:-"'004=------WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·.'·.··.··_..·........·.•,,·._...·'•.....···....·.·....·..Quan!it\t..·····.·...·OtherUnits-.Parameter...I.·'..·...·...••••F··.·..·.·.··UnitsN.E..L_CEL*.-34403(ML-1)RF-AReportedlndeno(1,2,3-cd)PyreneN/AN/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00720(ML-1)RF-BReportedCyanide,TotalNIAN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily32730(ML-1)RF-BReportedPhenolics,TotalRecoverableN/AN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34696(ML-1)RF-BReportedNaphthaleneN/ANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00011(ML-2)RF-AReportedTemperature,FNIAN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00011(ML-7)RF-AReportedTemperature,FN/ANIAN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily00011(ML-1)RF-AReportedTemperature,FN/AN/AN/ARptOnlyRptOnlyNIASummerMay1-Jan31PermitLimitsAvg.MonthlyMax.Daily00011(ML-1)RF-AReportedTemperature,FN/A N/ANIARptOnlyRptOnlyNIAWinterFeb1-28129PermitLimitsAvg.MonthlyMax.Daily•CEL=Coll]QiianoeEvaluationLevelInterimLimitations.-.·..SampleMeasurementUnitsN.E:·Frequency··Type..NG/L1/month24hrCompositemg/11/quarterGrabug/11/quarterGrabug/11/quarter24hrCompositeDEG.F2/monthlnsituDEG.F2/monthlnsituDEG.F2/monthlnsituDEG.F2/monthlnsituName.MPiiildpai..ElcecUtlve·Offider...•.·•rdocumentan?allwerepreparedDateCompleted/lr=========-===4•1'undermy_dlfecfionor_s!Jperw;Jon1naccordanceWith<tsystemdeSJgnedtoassure!hatpersonnelproperlygalherandevaluatethesubmitted.BaSedon...._·.·....··lk===:=:========::!f'·nYin9uiiyofthepersonorpersons.whomah,.gethe.system,ortlioseperSonsdirectly.S•gnatureofPnnCipalExecutive.Officer.orofOfficer.·..•......tqrtheinforrilation,theinformationsubrllittedis,JothemylrA-uth'-.······.o\Niedge:;mdbehef,_(rue;accurate,<3ndcompletaIamaware:thatthere:ores_1gruficant.,for.submittirigfalseinformation.inCluding.!lieposSibilityofafineand..forknoWingViolations:·.·.'iWRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLC\MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:_,004=.______CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·''..........···.Quantity·__c_.OtlierUnits--'-.P.ar:ameter···'..·...·..'.·..·•...UnitsN.E.GEL*...•..'·'.·..00011(ML-1)RF-AReportedTemperature,FN/AN/AN/ARptOnlyRptOnlyNJAWinterMar1-31PermitLimitsAvg.MonthlyMax.Daily00011(ML-1)RF-AReportedTemperature,FNIANJAN/ARptOnly90.4NIAWinterApr1-30PermitLimitsAvg.MonthlyMax.Daily81020(ML-1)RF-BReportedSulfateNIANIANJARptOnlyRptOnlyN/AYearRoundPermitlimitsAvg.MonthlyMax.Daily00552(ML-1)RF-AReportedOilandGrease,HexaneEXTR.NJANIANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.DailyNIAN/ANIANJA*CEL=ComplianceEvaluationLevelInterimLimitations--.Measure!Tleot·.'sampleUnitsNE.Frequency'TypeDEG.F2/monthlnsituDEG.F2/monthlnsitumg/11/quarter24hrCompositemg/11/monthGrablrN.=a::lll:::"e"',o"'f"'P'"'n"''O:::ci:t:l'o::al:c:··a=·=.e<:ufiv:::····."'·,-c::•::·O::.:ifi:::oe,.<..DateCompleted..f11andevaluatethilinfunila!ion.subrrutted.Basedon·•..... . .... . .1myihqufryofthe.persorior.personsw!Jorilanagethesysteril,orthosepersonsdirectly..otPnnapalExecutiveOffioerorrrtlaofOffieer·.···espom;ibleforgatheringtheinformation,theinformationsubmitte!'lis,tothebestofmy··"ndbelief,We,accur;ate,c:ompl..te.lamawarethattherearesignificantpenaltiesforsubm.itting,flilseinfoJ"Il)ationincludil"!g·thepossit>ilitybfafineand·...·.··•.··knowingviol3tions;.··..,...·WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT CERTIFIED LABORATORY NAME:

FACILITY NAME: !Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County CERTIFIED LABORATORY ADDRESS:

PERMIT NO.: WV0004499 OUTLET NO.: "'004""-------

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

·' Quar\titv• · .. ... . ... Other Units . ..

**Param~ter** · Units N.E. ·. GEL*

. .· ...... ·. . . . . . I . .

50050 (ML-1) RF-A Reported

Flow, in Conduit or thru plant N/A N/A N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00530 (ML-2) RF-A Reported

Total Suspended Solids N/A N/A N/A Rpt Only 60 N/A

Year Round Permit Limits Avg. Monthly Max. Daily

74055 (ML-1) RF-A Reported

Coliform, Fecal N/A N/A N/A 200 400 NIA

Year Round Permit Limits Mon. Geo. Mean Max. Da1ly

00400 (ML-1) RF-A Reported

pH N/A N/A 6 N/A 9 NIA

Year Round Permit Limits lost. Min. lnst Max.

00610 (ML-1) RF-B Reported

Ammonia Nitrogen NIA N/A N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00600 (ML-1) RF-B Reported

Nitrogen, Total (as N) Rpt Only Rpt Only Lbs/Day N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00665 (ML-1) RF-B Reported

Phosphorus, Total Rpt Only Rpt Only Lbs/Day NIA Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

50060 (ML-1) RF-B Reported

Chlorine, Total Residual N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

* CEL = Compliance Evaluation Level Final Limitations

. · . Me'lsurement· Sample

Units N.E. Frequency Type

mgd 1/week measured

mg/1 1/month 24 hr Composite

Cnts/100n 1/month Grab

S.U. 1/month Grab

mg/1 1/quarter 24 hr

Composite

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr Composite

ug/1 1/quarter Grab

Nan\e of Prtricipal EfectiliVJ Qffi6er . I **ee_~fy un~r**  **p~alty** oflav,r **t~~~ ~is**  docume11t anp all attach **men~** were.prepared Date Completea

I f'nder **myd~reoc!•()n** or sapervosoon m accordance with a system desogned to assurethat · · II

f!:ua!ifiro.per5ooinel properly gather and evaluate the information **submitted~** B'l$ed on s' . . , . ·. . . . Offi

. . . "'Y onquny o_f the·peorson or.persons who manage. the system. or thOse persons directly . . **og_na~re** of Pnncopal Executive cer or

Tolle Of Ofliber ..• ·. ·• _ . . .• . · · ... · ...,Sponsible for gathering .the information. the information **s~!lmitie<l** is, to the best of my **rA_uth_.~o_nz~ed~A-=g_en_t_'--'---'---'--------,**

I . · · · · ·· · · · · . **~~~~tg~~~~~~':~!~o'!".iu6~di:~a~:ti.~a~!':J~~~~~~e** !d significant

irilprisonmentfor knowing violations. . . . . . . .WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTCERTIFIEDLABORATORYNAME:FACILITYNAME:!MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyCERTIFIEDLABORATORYADDRESS:PERMITNO.:WV0004499OUTLETNO.:"'004=------WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·...-,:_.,.....·.·.·.Quantitv·..Othefunits--c:.:Parameter.Units·.·.....N.E...CEL*..01119(ML-1)RF-BReportedCopper,TotalRecoverableN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily01094(ML-1)RF-BReportedZinc,TotalRecoverableNIA N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00718(ML-1)RF-BReportedCyanide,WeakAcidDissociableNIANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily71900(ML-1)RF-BReportedMercury,Total(asHg)N/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily01104(ML-1)RF-BReportedAluminum,TotalRecoverableN/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00980(ML-1)RF-BReportedIron,TotalRecoverableN/A N/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily01055(ML-1)RF-BReportedManganese,Total(asMn)NIANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Dally00940(ML-1)RF-BReportedIChloride(asCl)NIAN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationlevelFinalLimitations.:·Measurement·SampleUnits.N£··FrequencyTypemgn1/quarter24hrCompositemg/11/quarter24hrCompositeug/11/quarterGrabug/11/quarterGrabmg/11/quarter24hrCompositemg/11/quarter24hrCompositemg/11/quarter24hrCompositemg/11/quarter24hrCompositeEXeciJiiveOffieer.·;I.ce_rtifyoflaw!b_atdOC(JI"I"Ieritan?allwerepr-epared.·CompletedrlsupeMslon'"·aCC()rdancewithasystem.desJgneatoassurethat_··ualifiedpersonnelproperlygainerand.evaluatetbeinforrilationsubmitte<LBasedon.·.. .•.. .••·-..•. .'yinquiiyoflhe;personorpersonswhomanagethesystem,e>rthesepersonscfrrectiySignali:"eofPnnclpalExecutiveOfficerorTitleofOffleer·,,fesponsibleforgatheringthetheinformationsubmittedis.•tothebestofmy..::·I.·······'····.significant-,-,.,..,--,-..,---.,------,---'limp(isonmeritforRnowingviolations.··..,___________WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLC)MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:-"'004=.._____CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·'QuantitYOtherUnits.....•···.··..IUnits.CEl*.·N.E..00951(ML-1)RF-BReportedFluoride,TotalN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34469(ML-1)RF-BReportedPyreneN/ANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34526(ML-1)RF-AReportedBenzo(A)AnthraceneNIAN/AN/ARptOnlyRptOnlyNIAYearRoundPermitlimitsAvg.MonthlyMax.Daily34320(ML-1)RF-AReportedChryseneN/AN/ANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34376(ML-1)RF-BReportedFluorantheneN/ANIANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34381(ML-1)RF-BReportedFluoreneNIAN/AN/ARp!OnlyRptOnlyN/AYearRoundPermttLimitsAvg.MonthlyMax.Daily34461(ML-1)RF-BReportedPhenanthreneNIAN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34200(ML-1)RF-BReportedAcenaphthyleneN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevelFinalLimitations..'SampleUnitsN.E.··FrequencyTypemgn1/quarter24hrCompositeugn1/quarter24hrCompositeNGIL1/month24hrCompositeNG/L1/month24hrCompositeug/11/quarter24hrCompositeug/11/quarter24hrCompositeug/11/quarter24hrCompositeug/11/quarter24hrCompositeName0f]>iihcipaj&ec..rtlVeOffii:erIce!lifyoflaw.f\lisallwerepreparedDateCompleted.·.·r¥eriTIYdJrect1onor.superviSion-macconlanceWithasystemdes•gn!!dI()assurethat.·..··...IIInualifiedpersoimelandevaluatetheinformationsubmitted:Basedon·..•·.·.··...•.•..,..c..•.·ofthE>pers6norpersonswhomanagetheSystem,orthosepersonsdirectlySignatureofPnnctpaiExecutive.OfficerorTrtleoofOffifur.,··.•··•.·.•.·espprisibleforgatherirygtheinformation,theinformationsUbmittedis;to.thebestofmy·······nowledgeand.JJelief;true,accurate,and.eomplete.Iamaware·thatthereare.significantpenaltieSforsubmittingfalseinfofmationJncludihgthepossibility.ofa:linearid·mprisonmeiltforknowingviolations.·WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:!MountainStateCarbonLLC)MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:,.,004=-._____CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·.....·.·...·.........·•auan!itv•.OtherUnitsParameterUnits.N.E.CEL*......-···34205(ML-1)RF-BReportedAcenaphtheneN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34220(ML-1)RF-BReportedAnthraceneN/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34230(ML-1)RF-AReportedBenzo(B)FluorantheneNIANIAN/ARptOnlyRptOnlyN/AYearRoundPermrtLimitsAvg.MonthlyMax.Daily34242(ML-1)RF-AReportedBenzo(K)FluorantheneN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34247(ML-1)RF-AReportedBenzo(A)PyreneN/AN/ANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily00981(ML-1)RF-BReportedSelenium,TotalRecoverableN/AN/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00978(ML-1)RF-BReportedArsenic,TotalRecoverableN/AN/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34556(ML-1)RF-AReportedDibenzo(A,H)AnthraceneN/ANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=CormWanceEvaluationLevelFinalLimitations---:MeasurementSample.UnitsNeE.Frequency.ITypeug/11/quarter24hrCompositeug/11/quarter24hrCompositeNG/L1/month24hrCompositeNGIL1/month24hrCompositeNG/L1/month24hrCompositeug/11/quarter24hrCompositemg/11/quarter24hrCompositeNG/L1/month24hrCompositeNanietit.PiirlclpalExetuiiveOfficiltIoflaliitallwereprepared...DateCompleted.r····nder,myd•rectionorsuperviSI()nUJaccordancewitha.systemdeslgnedtoassurethat·.·.·,·.J1.1personnelproperlygatherandevaluatetheinfunnationsubmi)lecL8asedon·.....··...Il!=============::!!fffiYinquiryoUhepersbnorpersonswhomanagethesystem;orthosepersonsdirectlyofPnnCipalExecutiVeOfficerorTilleofOfficer..esponSibleJortheinfunnation•.theinfonnationsubmittedis,tothe<?fmyAuthonzedAgent·,··owledgeandbelief,true,accurate,andcomplete.Iamawarethatther(ilares•gnfficantpenalties.forsubmittingfalseincluding·tbepossibilityofafine.and·••·.,-,.,...,--,---,-.,-,-----,---,-Jj'inptiso'1inenjforViolations.····..J.'--,--,----,------,---,----,.-,J·WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:(MountainStateCarbonLLC)MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:"'004""------CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·.<·.·•..·.•..·.·.....··•·•.•..............·...Quantitv-···.·.·.·.OtherUnits....·l.......•.....··...·.···......UnitsN.E..CEL*........·..34403(ML-1)RF-AReportedlndeno(1,2,3-cd)PyreneNIAN/AN/ARptOnlyRptOnlyN/AYearRoundPermitlimitsAvg.MonthlyMax.Daily00720(ML-1)RF-BReportedCyanide,TotalN/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily32730(ML-1)RF-BReportedPhenolics,TotalRecoverableN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34696(ML-1)RF-BReportedNaphthaleneNIAN/AN/ARptOnlyRptOnlyN/AYearRoundPermitlimitsAvg.MonthlyMax.Daily00011(ML-2)RF-AReportedTemperature,FN/AN/AN/ARptOnly15NIAYearRoundPermitlimitsAvg.MonthlyMax.Daily00011(ML-7)RF-AReportedTemperature,FN/AN/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00011(ML-1)RF-AReportedTemperature,FNIAN/AN/ARptOnlyRptOnlyN/ASummerMay1-Jan31PermiTLimitsAvg.MonthlyMax.Daily00011(ML-1)RF-AReportedTemperature,FN/ANIAN/A58.167.3N/AWinterFeb1-28/29PermitLimitsAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevelFinalLimitationsMeasurementSample..UnitsN.E.·FrequencyType.NG/L1/month24hrCompositemg/11/quarterGrabug/11/quarterGrabug/11/quarter24hrCompositeDEG.F2/monthlnsituDEG.F2/monthInsituDEG.F2/monthlnsituDEG.F2/monthlnsituNameof.a$Ctit;11eOffieerIce..·rtify····...u_n.•P....na.lty.·-_..of.Jawfh_d.oc..um_._en_t.and_al.latta.··chm··.....en_..___ere.prepa.red.·DateCompletedfndermydired1onormaccordance.withasystemdesignedtoassurethat•.·..LIIpersonnelpf()peliygatheraridevaluatetheinformationsubmitted.Basedon.........·.·........Il!==============:!.f'.l.yinquiryofthepersonorpersonswhomanagethesystem,orthosepersonsdkectlySignatureofPnnapalExecuti1te()fficerorITttleof.OffiCer.•.espons_•.•..I.b.·.'"•.·e..lin!l_th.·e···im.·onm_..·at..·.·.ici·n;·.th.e.iin..o.rm_..atio·.."..s.ub_lll_.itted··.JS·..to_...th.e..·best..·..yAuthOIJZedAgent·.......·······n()wledgeand_belief,true,accutate,andcomplete,I.am..ware,th?l•!hereare.s1gilmcant·slibi"tlittill9.f8l¥Iilf()l)'nationincludingtheofafineand··1....,---,..,..,.___,,.-.,....,---,-..,-,......,--,-,..,--,--.---,-JIIinprisonn:Jentforknowingviolations,•..···.··•·.·.·..·t'---,------,--,----,---,---,.,.----,-,-,...,-,--,.,---,----'WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:!MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:,0-"'04"---------CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·.·.·....··•··•······.·.Quantity....OtherUnitsParameter·........UnitsN.E.1···.·.CEL*:..·..··..:.:·..00011(ML-1)RF-AReportedTemperature,FNIANIANIA67.177.6NIAWinterMar1-31PermitlimitsAvg.MonthlyMax.Daily00011(ML-1)RF-AReportedTemperature,FNIANIANIA78.190.4NIAWinterApr1-30PermitLimitsAvg.MonthlyMax.Daily81020(ML-1)RF-BReportedSulfateNIANIANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily00552(ML-1)RF-AReportedOilandGrease,HexaneEXTR.NIANIANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.DailyNIANIANIANIA*CEL=EvaluationLevelFinalLimitationsMeasurement.sampleUntlsN.EFrequencyTypeDEG.F2/monthlnsituDEG.F2/monthlnsitumg/11/quarter24hrCompositemg/11/monthGrabNarneofPrinclharEXeCutiveOffieer..:_:Ice.·rt_ify·.·.<;l_nalty.,_o.flaw_·..fh_.·_.._a..._t.th··.isdocu_·..m_E!nt_·..a_n_d.·.a_r_ratta.·..chm.·.e.nts_•.·.·w_!lre_•.pr..epa.red..DateCompletedrunder.mydJrectionor.supervJsJonmaccordancewllb.asystem.des•gnedto.assurethat·.:··.·.Irquiilifiedproperlygatherinformation'submitted.Basedon·..··....··..·....1l:,:==;===;============fl'."myjnquiry<ifthepersonorpersonswhc:>managethesYstem,orthosepersonsdirectly.PnnCJpalExecutiveOfficer-orTJtleofbttici;r••.••··•.•....·....•e5f:>Onsible.forgatheringtheinformation,theinforrnati(!nsubmittedis,tothebestofmy.Agent..·I.··········.kn·ow··..__._eCl[l___d.be_..___ne__f,tnu.e____;_a__C:CU__··.·.·_ra___·_.l·e·_·d,co_mp._le.•te._I.a.m_a_-ya_•.th•·a_J.th_·.._erea.re_.signifiCantpenalties•for.submtltingialsaniformationmcludJng•thepossli:5Jiltyof:afin<;!.and..==========...,.,.__.·,,mpriS()nmentforknoWingviolations.•.. ..·..WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: <Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

PERMIT NO.: WV0004499 OUTLET NO.: ,O.e:06"--------

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

.. ·.·.··.···._.······ ... · .. ···. · ... · .. ··_ .. ·.·.·.··•. - ·c·. . . . Quai:tfity .. . ·. Other Units

.•·. . . . . . · .. · ... · .

Parameter .. . · .. Units

. · N.E . ·. . ... I GEL* · . ·Units

50050 (ML-1) RF-A Reported

Flow,in Conduit or thru plant NIA N/A IN/A Rpt Only 1.2 NIA mgd

Year Round Permrt Limits Avg. Monthly Max. Daily

00530 (ML-1) RF-A Reported

Total Suspended Solids 1227 2371 Lbs/Day N/A Rpt Only Rpt Only NIA mg/1

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

74055 (ML-1) RF-A Reported

Coliform, Fecal N/A N/A N/A 200 400 NIA Cnts/100n

Year Round Permit Limits Mon. Geo. Mean Max. Daily

00400 (ML-1) RF-A Reported

pH N/A N/A 6 N/A 9 NIA S.U.

Year Round Permit Limits lnst. Min. lnst Max.

00610 (ML-1) RF-A Reported

Ammonia Nitrogen 791 1591 Lbs/Day N/A Rpt Only RptOnly NIA mg/

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00625 (ML-1) RF-B Reported

Nitrogen, Kjeldahl Total RptOnly Rpt Only Lbs/Day N/A Rpt Only Rpt Only NIA mg/1

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00620 (ML-1) RF-A Reported

Nitrogen Nitrate Rpt Only RptOnly Lbs/Day N/A Rpt Only RptOnly N/A mg/1

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00615 (ML-1) RF-A Reported

Nitrogen Nitrite Rpt Only Rpt Only Lbs/Day N/A 4 15.5 N/A mg/1

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

* CEL = Compliance Evaluation Level

Name i:>tJ>rinciP'ltEXecuiiveOtticer l **certify)Jn~er~nalty oflaw~h_at**  **t~is** document **an~ all.attachtll~nts**  were prepared . Interim Limitations

,,,,- .Measurement ·•• .salllple

**NJ~:.** · F.requency •. Type .

.·.

1/daily measured

1/week 24 hr Composite

2/month Grab

1/week Grab

1/week 24 hr

Composite

1/quarter 24 hr

Composite

1/month 24 hr

Composite

1/month 24 hr

Compostte

ndercmy direction or superviSIOn m accordance with a system des1gnedto assure.that ·

j<!ualified personnel p.ropeny ga(her ai:td evaluate the information submitted Based **on·}~.'-** •. **~."". ~_.:._**  .-:--. 1--.- .. -- .. --------.J..J

**i==============;.==-.!!~muyinci)Jiry** ofthe.person or peis<Jnswho manage the system, or **tho~** ;;ersons directly . **S1gnat~re** of Principal Executive Officer or

Trtle of Officer • · · · ·•· . . • ej;p<msibleXor gatpefing tlleiofoiJTlatiof1;lhe information submitted is, to the best ofmy .I **rA~uth-'-'-o_n_z_ed_** . ...;A..:g:.:e:.:nt::.._ ___ **~-~~---~**

· · .· nowledgeand belief, !rue, accurate, and compiE>te • .I am aware thatthe.re are significant

!penaltiesfor subnfrtting false information including the possibility of a fine and

**.,--,.,..,-~_,-,-...,..,...,.....,..-...,..--1fmpriSonmentfor** knowingviolati6ns: · · .WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: !Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: ,.0,.,06,_ ____ _ CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

.... ·· .. ·. .·. · Quantitv . .. other Units .

.

· Pammeter .• • untts ·NE CEL*

.··. ·. .· -

00600 (ML-1) RF-B Reported

Nitrogen, Total (as N) Rpt Only RptOnly Lbs/Day N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00665 (ML-1) RF-B Reported

Phosphorus, Total Rpt Only Rpt Only Lbs/Day N/A Rpt Only RptOnly N/A

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

50060 (ML-1) RF-A Reported

Chlorine, Total Residual N/A N/A N/A 150 300 NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01119 (ML-1) RF-B Reported

Copper, Total Recoverable NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01094 (ML-1) RF-B Reported

Zinc, T ota1 Recoverable N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00718 (ML-1) RF-A Reported

Cyanide, Weak Acid Dissociable NIA N/A N/A 67 120 N/A

Year Round Permit Limits Avg. Monthly Max. Daily

71900 (ML-1) RF-A Reported

Mercury, Total (as Hg) NIA N/A N/A 0.234 0.417 NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01104 (ML-1) RF-B Reported

Aluminum, Total Recoverable NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Permit limits Avg. Monthly Max. Daily

* CEL = Cor:!1QJ_iance Evaluation Level Interim Limitations Measurement Sample

Uhtls N.E. . Frequency .. · .. Type

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr Composite

ug/1 2/month Gmb

mg/1 1/quarter 24 hr Composite

mg/1 1/quarter 24 hr Composite

ug/1 2/month Gmb

ug/1 2/month Grab

mg/1 1/quarter 24 hr Composite

I.Nallle **'otPrinCipilloBc~ve** 6tiieer- ·•.·•· .• I ce .... **rti.·zy···.··un.~er** •... P. **·.~·.·.** ally ·o.fla .• w .. **·.~** .. at .... **~** ... d ...... o. cu. me. nt ....•. an. **~.** ·.·.II a.tta. chill **en~** w.·e .. 'e .. ·. p. **·.'~.pa** .. red.

. . . . . Date Completed r

11 **und~rmyd1rection** or l;upeMSJonm accordanc::ewllh.a sysfe'!l des•gn<:ctto assure that · · · .. • · .. · I II

gu;3lified personnel properly **g~her** and evaluate the 1nformat1on subll).itted. Based on . . · . . .. · , .... ·· .· .. ·· ·.· • .· . . 1

. .. . . .. . ·•[(IY **i~9u\ly** of the pers?n or P<:rSon.sw.ho **man~ge** the **~yst** .. m, or•ttiose persons directly ·.· Signa1ureof PnnCipal Executive Officer or

.'rjui;, C)f.Oifii:er ••. ·· resp()nsible fot.gathenng the mformation, the Information submitjed.1s;to **~he b~**  '?f llJY , . Authonzed Agent • ··

! 1 · · · · · · ·· · ·· ···· **krlo\VIeageandbel\i~f,true, ac:c~mfe,**  :"nd. **com~lete.** I **am;3w~~e** tJiat there are s1gmficant

l penaltiasf()r submitting f<jlsemformation mcfudmg •the .poss1blltty Of anne and··

niprJs<mmentfor knoWing .viola:tions. · .. · . . · .WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:(MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:-"'00,;6,_______CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS···.····<·.··..·...Quantity..·."•·OtherUnitsParamf!ter·...·.·.·.CEL*UnitsN.E.•....00980(ML-1)RF-BReportedIron,TotalRecoverableNIAN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily01055(ML-1)RF-BReportedManganese,Total(asMn)N/AN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00940(ML-1)RF-DReportedChloride(asCl)NIANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00951(ML-1)RF-BReportedFluoride,TotalN/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily61425(ML-1)RF-DReportedAcuteTox-CeriodaphniaDubiaN/ANIAN/ARptOnlyRptOnlyN/AYearRoundPermitlimitsAvg.MonthlyMax.Daily61427(ML-1)RF-DReportedAcuteToxicity-PimephalesN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34469(ML-1)RF-BReportedPyreneN/A N/ANIARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34526(ML-1)RF-AReportedBenzo(A)AnthraceneNIANIANIA6.919.7N/AYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevelInterimLimitations.-.Measi.JreinentSampleUnitsN.E:FrequencyTypemg/1!/quarter24hrCompositemg/11/quarter24hrCompositemgt/1/year24hrCompositemg/11/quarter24hrCompositeTUa1/year24hrCompositeTUa1/year24hrCompositeug/11/quarter24hrCompositeug/12/month24hrComposite1-,.,N,a"'m"'e"'.o"'f"-•P"'.ii""nC.,'pa.,····,tc:Ex:o.,ce,.·fc_·---,·.·.•··1tuice,rfifyoflaw!natailprf!pared..DaleComletdrdermydlr¢clionorsuPf!f1l1SIOnmaccordancewil/lasystemassure.that·..:.p"'-e-C1..----------.....LJevaluatetheinfonmiltiorisubJ"llitted>Basedon•....·.·•.·.·. . . .·.....,·.-"·l!=============::dl'my.inquiryofthePf!i"Sonorpe..Si:msWhOmanageor.those.persons.dirE!CIIy·.0fPnnctpalEXecutiveOfficerorfrtleof.oilicer···.·:·responsibleforgatheringtheinformation,theinf0nmationis,totheliestofrnYAuthonzedAgent. .······.owledgeandbelief,.true,ratE!,.andcomplete-,1ama.ware.thaUherE!aresigl)ificant·penaltiesfoMubmi!tingfalseinformationincludingthepossibilityofa:filleand·iiriprisonmentforknowingviolations......WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: <Mountain State Carbon LLC) MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: :::00,6'-------- CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

. . .. · ... · ·.• · .. · ... Quanllty Other UnitS ..

.. I.'·.

F'aia!lleter 'UnitS N . .E ... .. .·· .. CEL*

. .·· .. . . . .· .. ·• . . .. . . c . .·

34320 (ML-1) RF-A Reported

Chrysene N/A N/A N/A 6.9 17.3 NIA

Year Round Penn it Limits Avg. Monthly Max. Daily

34376 (ML-1) RF-B Reported

Fluoranthene N!A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

34381 (ML-1) RF-B Reported

Fluorene NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Penn it Limits Avg. Monthly Max. Daily

34461 (ML-1) RF-B Reported

Phenanthrene NIA N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

34200 (ML-1) RF-B Reported

Acenaphthylene NIA N/A N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34205 (ML-1) RF-B Reported

Acenaphthene NIA N/A N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34220 (ML-1) RF-B Reported

Anthracene N/A NIA NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34230 (ML-1) RF-A Reported

Benzo (B) Fluoranthene N/A N/A N!A 6.9 17.8 N/A

Year Round Permit Limits Avg. Monthly Max. Daily

* CEL = Coflliillance Evaluation Level Interim Limitations ·Measurement Sample

Units N:E Frequency

. . .·· .. Type

ug/1 2/month 24 hr Composite

ug/1 1/quarter 24 hr Composite

ug/1 1/quarter 24 hr Composite

ug/1 1/quarter 24 hr Composite

ug/1 1/quarter 24 hr Composite

ug/1 1/quarter 24 hr Composite

ug/1 1/quarter 24hr Compostte

ugll 2/month 24 hr Composite

-- ·-

**,~N_,a::;m:.::e::.:' ~f_,_Pri"'-"'i:;"'ci"'p"'iii'-'Ex=ecut:::':.::··**  **.:e:iv:::e~0ffi~·** :.::ce:::·· :=:.''-'-'·_I ce_. rt.ify **un~er_p~_na_lty_**

. o_:_

.. f ... _!_a_ w **-~h_att~is.** d. octim_ e_ nt __ a

__ **n~-** a_ll_ajta_ chm_

·_ **en~w** ___ ere P_repa ... **~-eel_** ·_. . bate Compfet d r

1r under my.: direction or supeMs1on m accordance With_ a systemdestgned to assure that . -.·. · . e ' 11

**aualifi~** personnel properly gather and: evaluate the infoniiatior\ submttted. Based on , · . · _ . . . . . ·•

i!===============""·yn· Y iJ1qufry **ofthepe~on** or peisoris who manage the system, or those persons. directly Slgnan.rre of Pnnclpa!Executive Officer or

Trtle> otoffic:er .... · . . . .. . . . . .• **esponsibleforg~ering** the information, the informationsubmttted is, to the **b~t~fmy lr,A~·**  **_uth_o~nz_e_d_Ag_;;_e_n_t~-~-~~-~---'~-,**

. ... ... . . . . . . . DOW! edge and belief, true, accurate, and COmpletecl 3f11 aware that there **~re** Significant

**pe~tJ~ for~ubmit!in~faj~**  **in~OITJlljtiOri iJ1ciUdin~**  the possibilily of a iine and ·. . ..

**lll)PTJ~onrnentfor** knowmg VIOI1ilions. · • . · · . . · . · · · · . . • •WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:-"'00,6'--------WASTELOADFORTHEMONTHOF..•······•QuantitY.·....·.·..CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:INDIVIDUALPERFORMINGANALYSIS..·...·..•.OtherUnits.._... ...·.•··..•.....·.·.·.Parameter·'··.-...UnitsN.E.ICEL*.·..:........·34242(ML-1)RF-AReportedBenzo(K)FluorantheneNIAN/AN/A6.917.4NIAYearRoundPermitLimitsAvg.MonthlyMax..Daily34247(ML-1)RF-AReportedBenzo(A)Pyrene0.07640.136Lbs!DayNIA6.919N/AYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily00981(ML-1)RF-AReportedSelenium,TotalRecoverableNIAN/AN/A0.1060.243NIAYearRoundPermitLimitsAvg.MonthlyMax.Daily00978(ML-1)RF-BReportedArsenic,TotalRecoverableN/A N/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily34566(ML-1)RF-AReportedDibenzo(A,H)AnthraceneN/ANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34403(ML-1)RF-AReportedJndeno(1,2,3-cd)PyreneNIAN/AN/A6.918.2NIAYearRoundPermitLimitsAvg.MonthlyMax.Daily00720(ML-1)RF-AReportedCyanide,Total25.636.6Lbs!DayNIA4.399.31N/AYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily32730(ML-1)RF-AReportedPhenolics,TotalRecoverable0.290.47Lbs!DayNIA82145N/AYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevelInterimLimitations-.._MeasllremeritSampleFrequency-UnitsN.E.TY!>eug/12/month24hrCompositeug/12/month24hrCompositemg/12/month24hrCompositemg/11/quarter24hrCompositeug/12/month24hrCompositeug/12/month24hrCompositemg/12/monthGrabug/11/monthGrabExeCutiveOfficer...lcertifydocur:nentwereprepared·_..DateCompletedJde[imy'drrectionor.supervrsronmaccordancewithasystemdesrgned.toassurethat··:IIqualifiedpersonnelproperlygather.theinfonnationsubmitted:Basedon•.. .··.··..··..··of.'thepe..SOnor.PersonswhomanagetliesyStem,orthosepe""'ns.<lirectlySrgnatureofPnncrpalExecutiveOfficerorTitle-ofOffieer.··.gatheiingthe.information,theinformationsubmittedis,tothebestofmyAuthonzedAgent.•·--··········._owledgeandbelief,true;complete:Iamawarethatthereate.,ignificantp-enaltiesfors.ufimittingincludingtheposSibUiiyofanneand··.,_.......,.,.,.,.......,.,,...,_,....,------,-..,._Jrlrri•i>riSDnnientforknowingviolations:·...·..WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: <Mountain State Carbon LLC\ MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: _,00,6"---------

WASTELOAD FOR THE MONTH OF·

' .....•. .. · .... · · Quantitv· ·. · . CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

INDIVIDUAL PERFORMING ANALYSIS·

··.· . •. Other Units

Pararrieier · ..

. ·_·. Units N.E . I . . • GEL*

.. · ... · . ··. . .. ·

34696 (ML-1) RF-A Reported

Naphthalene 0.0759 0.137 Lbs/Day N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00011 (ML-1) RF-A Reported

Temperature, F N/A NIA N/A RptOnly Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00011 (ML-2) RF-A Reported

Temperature, F N/A NIA N/A RptOnly Rpt Only N/A

Year Round Permit Limits Avg. Malthly Max. Daily

00011 (ML-7) RF-A Reported

Temperature, F N/A NIA N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

81020 (ML-1) RF-B Reported

Sulfate N/A N/A NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00552 (ML-1) RF-A Reported

Oil and Grease, Hexane EXTR. 102 306 Lbs/Day N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily N/A N/A

---

• CEL = Comcliance Evaluation Level Interim Limitations

·.. . Measurement .S?ffiple .

units N.E. . Frequency Type · .

ug/1 2/month 24 hr Composite

DEG.F 1/month lnsitu

DEG.F 1/month lnsitu

DEG.F 1/month lnsitu

mg/1 1/quarter 24 hr

Composite

mg/1 1/month Grab

Name of .f'rinqpal **Ex~ive~** . • I certify **UO~E!Lp~malty** oflaw **~-atl!tis** document **an~** all attachments were prepared . ·.· Date Completed

**um~ermy** direction or supervJSI()n m accordance Wltll a system designed to assure that · II

**~~a!ijie~ p_erSonneiJ)roper~y**  gather and evaluate tile information **~-ub.mitted.** Based on • . · · • . - ·. . . . . .. . . · . .

**i!=="'C'==o==~========o==!f"Y** IO(juny **of~** per5on or **person~who** manage the system; or !J1ose personscdirectly... **Slgna~re** of PnnCipal Executive Officer or

'Title 6foincer · . . rrisP.onsible for gath8ring:theinformatii>n, tt1e information sub!"itted Is, toth!" best of my Aulhonzed Agerrt • . .

· ·· ·· · ···· ···· · · · ·· · · **I£_~.** o:

__ Y!l<ld·g· e_ ·_and·· .. b·e· he

.. f.t. nue;. ace_._

.. u_ra_ .• t. e.; an. d.. com_ pl·e.te .. am aw_ an:. that there. ar_e s•gnificant

F.oaltiestor submitting ·false information inCluding the possibility of a fine and . .

irripiisomilentfor knowing violations. . · · · . · . . ·WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:_,0,06.,________CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·t·. .'.........•1:•...Quantity...OtherUnitS.Parameter.··.·•.·.·........··units,N.E.GEL*50050(ML-1)RF-AReportedFlow,inConduitorthruplantN/AN/AN/ARptOnly1.2N/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00530(ML-1)RF-AReportedTotalSuspendedSolids12272371Lbs/DayNIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily74055(ML-1)RF-AReportedColiform,FecalNIAN/AN/A200400NIAYearRoundPermitLimitsMon.Gee.MeanMax.Daily00400(ML-1)RF-AReportedpHN/A N/A6N/A9N/AYearRoundPermitLimitslnst.Min.lnst.Max.00610(ML-1)RF-AReportedAmmoniaNitrogen7911591Lbs/DayNIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily00625(ML-1)RF-BReportedNitrogen,KjeldahlTotalRptOnlyRptOnlyLbs/DayN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily00620(ML-1)RF-AReportedNitrogenNitrateRptOnlyRptOnlyLbs/DayN/ARptOnlyRptOnlyN/AYearRoundPermitlimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily00615(ML-1)RF-AReportedNitrogenNitriteRptOnlyRptOnlyLbs/DayN/A415.5NIAYearRoundPermttLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevelFinalLimitations...·.•·...·MeasurementSampleUnitsN.E.FrequencyTypemgd1/dailymeasuredmg/11/week24hrCompositeCnts/100r2/monthGrabS.U.1/weekGrabmg/11/week24hrCompositemg/11/quarter24hrCompositeimg/11/month24hrCompositemg/11/month24hrCompositeNameofPnrici;:furEXecUtrvif6ffiter•...Ic;ertify..(Jjltlait}'oflawallprepared.Date.Completedundermydirectionorsuperv1s1on1naccordancewithasystemdesignedtoassurethat····Jlnualifiedpersonryelproperly,gaJberandevaluatetheinformationsubmitted.Basedoir·.·.•.··..··.·.. .-··....··.Iil"lquiryoftheorpersonswf1omanagethesystem,.ortho.sepersonsdirectlyofPnnclpalExecutiveOfficerorTrtle&tofficer····.·..··-respoJ1SibleforgatlieriJ1gthetheinformationsubmittedIs,tothe<?fmyAU!honzedAgent.··.····.knowledge<mdbelief,true,accura1e,""dcomplete.lama1Nl>fethattllereares1gnfficant·forsubmitliri9.inf?f!llalioninCludingthepossi.bilityofafineand···.lrnPf1SOnmentforlo\OwmgVlolat•ons._.._.·.._.WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:(MountainStateCarbonLLC\MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:_,0"'06,______CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·. .···.•·.......··Quantity...··.Other·Units·.......ParameterUnits.N.E.'GEL*u.... ........nits00600(ML-1)RF-BReportedNitrogen,Total(asN)RptOnlyRptOnlyLbs/DayN/ARptOnlyRptOnlyNIAmgnYearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily00665(ML-1)RF-BReportedPhosphorus,TotalRptOnlyRptOnlyLbs/DayNIARptOnlyRptOnlyN/Amg/1YearRoundPermitLimitsAvg.MonthlyMax.DailyAvg.MonthlyMax.Daily50060(ML-1)RF-AReportedChlorine,TotalResidualN/AN/AN/A150300NIAug/1YearRoundPermitlimitsAvg.MonthlyMax.Daily01119(ML-1)RF-BReportedCopper,TotalRecoverableN/AN/ANIARptOnlyRptOnlyN/Amg/1YearRoundPermitLimitsAvg.MonthlyMax.Daily01094(ML-1)RF-BReportedZinc,TotalRecoverableNIANIAN/ARptOnlyRp!OnlyN/Amg/1YearRoundPermitLimitsAvg.MonthlyMax.Daily00718(ML-1)RF-AReportedCyanide,WeakAcidDissociableNIAN/AN/A67120NIAug/1YearRoundPermitLimitsAvg.MonthlyMax.Daily71900(ML-1)RF-AReportedMercury,Total(asHg)N/AN/ANIA0.00980.018N/Aug/1YearRoundPermitLimitsAvg.MonthlyMax.Daily01104(ML-1)RF-BReportedAluminum,TotalRecoverableN/ANIANIARptOnlyRptOnlyN/Amg/1YearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevelFinalLimitationsMeasurementSampleN.E.FrequencyType1/quarter24hrComposite1/quarter24hrComposite2/monthGrab1/quarter24hrComposite1/quarter24hrComposite2/monthGrab2/monthGrab1/quarter24hrCompositeNarrleofficer..l.c:eFfifyof!fl_iltfi.Jisdocumentan,danprepared·.·DateCompleted.rr'·ndermyl?Upe(VJS•on•naccordanpe\Nitha'?Ystemdes•gned_toassurethat··..·I11lnumified,personnelj)rbpertygalh!'randevaluatetheinroimationsu001ittedc.Basedon·..•;_._,. . . . .Ilk==================:!JiitiyinquiiyofthepersOnorpersonswliomanagethesystem,orthoSepersonsdi(eC!Iy.ofPnr1c•palExecutiveOfficeror·•·_.·.··res·p·o._ns.ib.le.fo·.·r_•g.a.._lh_e_n·ng.th.·e.in··..ati_o_n··.•__!fiei.nfo.ima..ti·.·on...·..sub___m·itt...ed·..·..·.is.•.t_.·6..th.ebes.....t.ofm.yAuthoi)ZedAgent'..I···········noWiedge.aodbelief;true,accl.lrate;.andcomplete.Lamawat:e.thattherearesignificantIJjpenalties.fol"-sl!bmittfn_g:falseinfoi"riJatiC>nincludingthe,possil>ilitycifaifineand.··.•·•knoWingviolations...·.·•·...···.·JWRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: (Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: ,oo,s'------- CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

•.·.·

. · .. · ouarititv . .•. Other UnitS . · .

**Pa~E!r.** ·•· ... . .. Units. N.E. · . GEL*

·····' . .·. . · · ... . ·.

00980 (ML-1) RF-B Reported

Iron, Total Recoverable N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

01055 (ML-1) RF-B Reported

Manganese, Total (as Mn) N/A N/A N/A Rpt Only Rp!Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00940 (ML-1) RF-D Reported

Chloride (as Cl) NIA N/A N/A Rpt Only Rp!Only NIA

Year Round Perm it Lim its Avg. Monthly Max. Daily

00951 (ML-1) RF-B Reported

Fluoride, Total NIA NIA N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Dally

61425 (ML-1) RF-D Reported

Acute Tox- Ceriodaphnia Dubia N/A NIA NIA RptOnly Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

61427 (ML-1) RF-D Reported

Acute Toxicity- Pimephales N/A N/A NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34469 (ML-1) RF-B Reported

Pyrene N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

34526 (ML-1) RF-A Reported

Benzo (A) Anthracene N/A NIA N/A 6.9 19.9 NIA

Year Round Permit Limits Avg. Monthly Max. Daily

* CEL = Comoliance_Evaluation Level Final Limitations .Measurement Sample

Units .· N.E. Frequency . Type

·.·. ·.

mgn 1/quarter 24 hr

Composite

mgn 1/quarter 24 hr

Composite

mg/1 1/year 24 hr

Composite

mg/1 1/quarter 24 hr Composite

TUa 1/year 24hr

Composite

TUa 1/year 24 hr

Composite

ug/1 1/quarter 24 hr

Composite

ug/1 2/month 24 hr

Composite

·- ·--

Name dtPrtnciPai &eciifute ()ffic..r . . I eertify **~n~er p~nalty**  of law !h.atthisdocument **an~** all **attaC:hmen~ ~ere**  prepared · . Date Completed I

I 1 ... nder my dJ£eclion oLsupervJl!•on m accordance With a system des1gned to .assure that . . ·. . . I . II

**~walified** personnel proi>erly satller and evaluate the information Sllbmitted. Based on . · · •. · · . . ·. • _ .

· · y inquiry ?fthe.per5onorpersonswho manage !lie system, or those persons.directly **S•gnat~re** ofPnnapal Executive Ofliceror

· ··· · ·• · • "bl·to·· .·.th ·· ·th "fo ·ti ·th. ·n11· · ·ti· .. **·.b."'~~·** •t·th· .. bes· f · AIJthonzedAgent ·.·

Trtfeofbfficer . .. respons• .e rsa,enng e•n **rm~** on, e1 ()rma onsumu,cuJS, o e. .t'? my **j·,r··~·-"'"··~·.c·~·.::c.·-~·~--'---~-'-'-~'-~~-'-'-1**

1 ... · ·· · · ·· ·· no.wled·.··.g .. e.· an.db.·E!·I.•.ef •. tru_ ... e; .. accu·. ra_te ..•. and .. complet. e.la_m_• _a_w._are.th

.. a .. tther ___ **e~_re.s•** .. g. m_ficallt

pe 0 aHies for submitting ·false.infon:i)ation including the possibllity.ofafirie and. ··.· · . · ·

· **iinprisonin~ntfor** J<nowing)liolatlcins. · · · · L-.,---,---,-.,---.,..,--.,..,.,-.,---,,-,-,.WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: <Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: ,00,6'-------

WASTELOAD FOR THE MONTH OF· CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

INDIVIDUAL PERFORMING ANALYSIS· Final Limitations

**Pa~~ter** 1·· .·· . · Quantity ..... · · · · I . OtlrerUnits . • ·· .. · . · ·. ·1 M . . · . t

·.· . I . I Units I N.E. I I I. GEL* I Units INE **;:;'~~;'**

34320 (ML-1) RF-A

Chrysene

Year Round 34376 (ML-1) RF-B Fluoranthene

Year Round 34381 (ML-1) RF-B

Fluorene Year Round 34461 (ML-1) RF-B Phenanthrene

Year Round 34200 (ML-1) RF-B Acenaphthylene

Year Round 34205 (ML-1) RF-B Acenaphthene

Year Round 34220 (ML-1) RF-B Anthracene

Year Round 34230 (ML-1) RF-A

Benzo (B) Fluoranthene

Year Round Reported IPennit Limits Reported Permit Limits Reported Permit Limits Reported Perm it Lim its Reported Permit Limits Reported Permit Limits Reported Permit Limits Reported Permit Limits

.. CEL = Compliance Evaluation Level N/A N/A

N/A N/A

N/A NIA

NIA N/A

NIA N/A

N/A N/A

N/A N/A

N/A N/A N/A 6.9 17.3 NIA lug/1 2/month

Avg. Monthly Max. Dally

NIA Rpt Only Rpt Only NIA lug/1 1/quarter

Avg. Monthly Max. Daily

N/A Rpt Only Rpt Only N/A lug/1 1/quarter

Avg. Monthly Max. Daily

N/A Rpt Only Rpt Only N/A lug/1 1/quarter

Avg. Monthly Max. Daily

IN/A Rpt Only Rpt Only N/A lug/1 1/quarter

Avg. Monthly Max. Daily

IN/A Rpt Only Rpt Only N/A lug/1 1/quarter

Avg. Monthly Max. Daily

N/A Rpt Only Rpt Only NIA lug/1 1/quarter

Avg. Monthly Max. Daily

N/A 6.9 17.8 NIA lug/1 2/month

Avg. Monthly Max. Daily Sample Type.

24 hr

Composite

24 hr

Composite

24 hr

Composite

24 hr

Composite

24 hr

Composite

24 hr

Composite

24 hr

Composite

24 hr

Composite

Name ()f **Pnnci~** Executive officer . .. I **certif}run~er** pt;!nalty of lao/ 1h.at :t\Jis document an? **allattachment~** were prepared . . · Date Completed ·

undermy d1rection ar supervtsron m.accordance with a system des•gned toassure that **f-~..,-·,-~-~· _j,---~--~---...,..LJ** 

**~IJalified** peisonnelpropeily gather and ewluate the infurrl)ation submittedc Based on **~.** • ··. · . . . . . . _ ·· · . · ... ·

i!==============4•rny inqu.iry of the. person or persons who manage the. system, or those persons directly ··. **S•gnat~re** of **Pnne~paf** .Executive Officer or

·Title ()f Oflii:er .· ·. · · · esponsible for gathering theitifol11)"tion, the information submitte<Hs, to the best ofmy . · Authonzed Agent · .· ·.· · . • ...

· nowledge and ])<ilief, true, aceurate; and complete. I am aware.that.there are significant

penalti6$fot $.ubmittil)g.talseiirformati<>n .including the possibirrty ()fa fine an9 ·

...,__,..,....,,...,=,._,...-,--,-_,_-,-.,.-,,...,..,J 1 1rnpiisohment for knoWing violations. · · · · · · ... · .,..,..,.-,-, ...-.,.--,._,_-,--,;,-...,.,.,-,--,-==-:c-:==c:-WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: (Mountain State Carbon LLC) MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: .::;00.,6'-------- CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

. ·.·.. . .:•·.· .. ·.··· . . ·:·.·· .·· · ... Quantity · •··· · · . ·.·• btherUnits · .

**P;~ra(lleter.** ·. Units N . .E. GEL*

·. · .. ·.

34242 (ML-1) RF-A Reported

Benzo (K) Fluoranthene NIA N/A N/A 6.9 17.4 N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34247 (ML-1) RF-A Reported

Benzo (A) Pyrene 0.0754 0.136 Lbs/Day N/A 6.9 19 NIA

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

00981 (ML-1) RF-A Reported

Selenium, Total Recoverable N/A N/A N/A 0.106 0.243 NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00978 (ML-1) RF-B Reported

Arsenic, Total Recoverable N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Dairy

34556 (ML-1) RF-A Reported

Dibenzo (A,H)Anthracene N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

34403 (ML-1) RF-A Reported

lndeno (1 ,2,3-cd) Pyrene N/A N/A N/A 6.9 18.2 NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00720 (ML-1) RF-A Reported

Cyanide, Total 25.6 36.6 Lbs/Day N/A 4.39 9.31 NIA

Year Round Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

32730 (ML-1) RF-A Reported

Phenolics, Total Recoverable 0.29 0.47 Lbs/Day N/A 82 145 N/A

Year Round

L__ Permit Limits Avg. Monthly Max. Daily Avg. Monthly Max. Daily

* CEL = Compliance Evaluation level Final Limitations Measurement I .SampleUnits N.E • . ·Frequency Type

·.

ugn 2/month 24 hr

Composite

ug/1 2/month 24 hr Composite

mg/1 2/month 24hr Composite

mg/1 1/quarter 24 hr Composite

ug/1 2/month 24 hr Composite

ug/1 2/month 24 hr Composite

mg/1 2/month Grab

ug/1 1/month Grab

**Na(ll~flc:;ipa(Elie2UliV~ffiC:er** .. . ..•.. I **~rti1}' ifn~er**  **p~nalty** of **law~.at !~is**  doctiment an? an **atlljchment~wete** prepared . . Date Completed .

Ul)dermy dtreclion or superviSIOn m **acco~di!nce** VJith a systemdes1gnedto assur-e tliat **1"----..,..---~'--------...,.---""-1**

**~uaEifiE>~** personn€)1 propeily **g~the[a~d** ewluate the information submitted. Based on . . .. . . · . . . . . .

**i!=====~=~=====:dJ·** my Jnqujry:ofthe person **orper>;()p~** who manage the_ system; or. tho.se persons directly Signature of PnnCJpal Executive Officer or

Title Of Officer ·.. .. · .. • · . · e$POQSibleJor gatpering th<;> iriforrnatton, the Information submitted is,to th_e **b~** '?f my **lrA_uth~_ ~o_n_;z·**  **ed_Ag-..:.e_nt~·...;·-~·~-~-~--------,**

· · · · · · · · ·· ·· · kiloWjedgeandbehef, true, accurate, and completE). I am awarethatthere are Significant

pemalti.eS.ior submitti[1g false infOrmation ihduding the possibility of a fine and

1 ..,_,_...__,...-,.-,..----..--,-,-.,---...-'Jimprlsonmenttqrknov.tingviolaiions. ·

# I WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: (Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: 

### WV0004499 OUTLET NO.: 

### -"'00..,6'------- CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·



# ' ·· .. ·.·• . . . 

### · Quantity .. 

### · · Other Uiii!S · .



# ?8rameier

... ·.

. 

### : 

# . . . .... . .. 

## ... .• . .·· 

### .Units N.E. CEL*

34696 (ML-1) RF-A Reported

Naphthalene 

### 0.0759 0.137 Lbs/Day N/A Rpt Only RptOnly N/A

Year Round Permit limits

Avg. Monthly Max. Daily Avg. Monthly Max. Daily



### 00011 (ML-1) RF-A Reported

Temperature, F 

### N/A NIA N/A RptOnly Rpt Only N/A

Year Round Permit Limits Avg.

Monthly Max. Daily



### 00011 (ML-2) RF-A Reported

Temperature, F 

### N/A NIA NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg.

Monthly Max. Daily



### 00011 (ML-7) RF-A Reported

Temperature, F 

### N/A N/A NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg.

Monthly Max. Daily



### 81020 (Ml-1) RF-B Reported

Sulfate 

### N/A N/A N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg.

Monthly Max. Daily



### 00552 (ML-1) RF-A Reported

Oil and Grease, Hexane EXTR. 

### 102 306 Lbs/Day N/A Rpt Only Rpt Only NIA

Year Round Permit Limits

Avg. Monthly Max. Daily Avg. Monthly Max. Daily 

### N/A N/A

* GEL = Cor:D.Q!_iance Evaluation Level 

### Final Limitations ·--- 

### Measurement ... ·



### . Frequency **s~ple.**



### Units

N.E

. Type

ug/1 

### 2/month 24 hr Composite

DEG.F 1/month 

### lnsitu

DEG.F 1/month lnsttu

DEG.F 1/month lnsitu

mgA 

### 1/quarter 24 hr Composite

mg/1 

### 1/month Grab

Nail"le. of Principal 

# Exe®tive.Offieer

· 11 

# tertify

**~nder pe~alty"**  **ofJa~ !~at.l!lisdocu":lentan~**  all



### attaCilmen~ \'lere 

# !>'"Pared

.. Date Co -leted



### un<lerm~.crli"eCfjon

or supent1"'on m accordance 

# with

.a system des•gl1ed·to a.ssurethat • ·•• · mp .•. •. .· 

## 11

\l_uallfiectpersonnel

properly gather 

# and evaluate the infonriation submitted, Based on ·. , · . .· . · .. · . .. · .· ·. · . . , . · ·.. .. . ... . 

### 1



## ~================!f":·

yiiiquiry 

## of the i>ElrsOn or p¢JSons Who



## m~nagethe syStem; or\h9se persons direCtly ·. SJgn"h.'re of



## Pn~CIJl'll EJ<ecutive Officer or

Trtle

ofOfflter ·• · .. ,... 

## esponsi~Ieforga!herjng \h• infom1ation, thE! infom1ation SIJb!""ittedis, to 

# "!fie **~** 

# '?f

my . Au!honzed Agent • .. •

·

· · ··· · · nowfedge andJ)ehef,true,. accurate, and complete. I am .. aware that. there.aresJgnifi.cali!

peoalties.ft>r siJbthttting f<llseinfolll)atlon-·including-thepossibiiity·ofa1ine_and

'

ilripriSonmen!Jor knowing violations; • · · ·. · ·· . , • IIWRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: (Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: _,09,_,7 _____ _ CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

· .. ·· ... · ... •. ' · .. · ... ·.· ' ' Ouantitv. .·· Oth<kUnifs

Parameter ·.···.· .. ··' . ·.· Units N.E. CEL*

00530 (ML-5) RF-A Reported

Total Suspended Solids N/A N/A NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

74055 (ML-5) RF-B Reported

Coliform, Fecal N/A N/A NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00400 (ML-5) RF-A Reported

pH N/A N/A Rpt Only N/A Rpt Only NIA

Year Round Permit Limits lnst. Min. lnst Max.

00610 (ML-5) RF-B Reported

Ammonia Nitrogen N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

00625 (ML-5) RF-B Reported

Nitrogen, Kjeldahl Total N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Penm tt Lim tts Avg. Monthly Max. Daily

OQ620 (ML-5) RF-B Reported

Nitrogen Nitrate NIA NIA N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00615 (ML-5) RF-B Reported

Nitrogen Nitrite N/A N/A NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

00600 (ML-5) RF-B Reported

Nitrogen, Total (as N) N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

* CEL = Comoliance Evaluation Level Final Limitations .. •

Measurement Sam pie

unas Freq\Jency • ..

NeE. Type

mg/1 1/week Grab

Cn!s/100n 1/quarter Grab

S.U. 1/month Grab

mg/ 1/quarter Grab

mg/1 1/quarter Grab

mg/1 1/quarter Grab

mg/1 1/quarter Grab

mg/ 1/quarter Grab

I'Name **ofPnociP~** Elieeun,;e **offi~f** · · · **~:;d~%,~~~J~~aJ~~~J!\~n~sli~l~~a~1tta~;y~~~~~;=~~~r!!'!~that** •. **D~te** Comple(ed •··.I 11

**~u~i~"'!i>ersonm•l** propeilygatherarid evaluate ih<! information subrilitte<Ulasildor\ • . - ... · . _ ·. -. , ·

**l!=c=~=====~======"J·** my IOq!li!Y ofthe pef50n or persons. who manage the sys!em.--or those persons directly **S•gnaj~re ofPnne~paJ**  EXecutiVe Officer or

··. · ·· • .. ··· · ·. •. ··· ·. . . •· ._.·. •• · responsible fur **galhe~ng** the information, the informalibf:l sub in **it!~** is; to !llebE>stof rny Authonzild Agent .·

Title of Officer · nowledgeandbeli.,f, true; accurate, and eomplete. lam aware that there are significant

· penalliesfpr.submitting false **infot~:naji6n** ini:ltraing_the pils5ioility. ofa fine and ·•

I U:nt>iisoilmE>nt tQrknoWirig **viol;;~liof:ls.** . · · ·. ·.. . · ·. · .WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:_,09"'7'--------CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·......·......•···Quantitv.·.··.·._...·otherUnitsl"araffieter··[..·.··.....·....·UnitsN.E..GEL*50060(ML-5)RF-BReportedChlorine,TotalResidualN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily01119(ML-5)RF-BReportedCopper,TotalRecoverableN/ANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily01094(ML-5)RF-BReportedZinc,TotalRecoverableN/A N/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.Daily00718(ML-5)RF-BReportedCyanide,WeakAcidDissociableNIAN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily71900(ML-5)RF-DReportedMercury,Total(asHg}N/AN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00900(ML-5)RF-BReportedHardness,Total(asCaC03}N/A N/ANIARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily01104(ML-5)RF-BReportedAluminum,TotalRecoverableNIANIAN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00980(ML-5)RF-BReportedIron,TotalRecoverableN/AN/AN/ARptOnlyRptOnlyNIAYearRoundPermitLimitsAvg.MonthlyMax.DailyV!;;.L..-VVIIIIICUI\,;1;0L..VCUUC:UIVIIL."<;;YII;i'lFinalLimitations..Measurement·UnitsN.E.Frequencyug/11/quartermg/11/quartermg/11/quarterug/11/quarterug/11/yearmg/11/quarterug/11/quartermg/11/quarterName_ofci:ioodp:;ili:XeciiiiveOfficer'..Ice.rtifyUlid_erpenaltyoflawthatthisdocumentandallattachmentswereprepared·ndermydirectionorsupervisioninaccordancewithasysteindesignedtoasSurethat,.DateCompleted.jSampleTypeGrabGrabGrabGrabGrabGrabGrabGrabgatherandevaluatetheinfoJlT)atkmsubmitted,Base_don·.SignatureofPrincipalExecutiveor.Y:whomanagethesystem,_orthOse-personS:directly_T)lle()f····espoiisibleforgathellngtheInformation,theinformationsubmittedis,tothebestofmyAuthorizedAgent··nowledgeandbeflef,true,_accurate;andcomplete.Iamawarethattherearesignificantpenidtiesforsubmittingfalseinforinationincluding!hepossibilityofafineand•·•mprisonmentforknowing.violations.WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: !Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: "'09,_,7 _____ _ CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

·· ....... . ... ··.·. Ouantitv. .. Other Units . .

•Parameter . · .. .

. • .. · ·. • Units N:E. . CEL*

00940 (ML-5) RF-D Reported

Chloride {as Cl) NIA NIA N/A Rpt Only Rpt Only N/A

Year Round Permit limits Avg. Monthly Max. Daily

00951 (ML-5) RF-B Reported

Fluoride, Total NIA NIA N/A Rpt Only Rpt Only N/A

Year Round Permit limits Avg. Monthly Max. Daily

34469 (ML-5) RF-B Reported

Pyrene NIA NIA N/A Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34526 (ML-5) RF-B Reported

Benzo (A) Anthracene NIA N/A N/A Rpt Only Rpt Only N/A

Year Round Penmit Limits Avg. Monthly Max. Daily

34320 (ML-5) RF-B Reported

Chrysene NIA NIA N/A RptOnly Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34376 (ML-5) RF-D Reported

Fluoranthene N/A NIA NIA Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

34381 (ML-5) RF-B Reported

Fluorene N/A NIA NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily

34461 (ML-5) RF-B Reported

Phenanthrene N/A N/A N/A Rpt Only Rpt Only NIA

Year Round Permit Limits Avg. Monthly Max. Daily

L__

* CEL = Compliance Evaluation Level Final Limitations Measurement Sample

. Units.· N.E. Frequency I· Type

mg/1 1/year Grab

mg/1 1/quarter Grab

ug/1 1/quarter Grab

NG/L 1/quarter Grab

NG/L 1/quarter Grab

ug/1 1/year Grab

ug/1 1/quarter Grab

ug/1 1/quarter Grab

Narrie·of Prlnc:il'al· E:xeclltive Ollicer I certify under penalty ()f _law **thatthi~** document and all. attachments were preJ)ated D I . Cotnplet_. ed

· · under my direction or supervision in. accordance With a system ·designed to assure. that **1--a_e_._-'-"·-'-~....L.......,.----.,...----....1**

**~ualffied** perSonnel properly gather and evaluate the information submitted, Based on . · . · f . . · ..

I!=============:=!Jirri}iinquil)'of the pers()ii or persons \VhO manage the system, or tho5e persons directly . Srgn<rt\'re. 0 • Pnnc1pal Executive Officer or

1itleof0fficer .·· . . . · **re$ponsil)leforg!!l~ering** the infon;nation, the infonmation submitted **i~,** to **the~** of my **.rA~ut;_h_o_n_z~e_d_A..:g_e~nt-'-. -'-'--~~-~-----'-i** 

· · · · owledge and bebef, tr1Je, accurate, ?"d complete. I am aware thattl;lere **~** srgnificant

· peiialliesfof Sl.lbinitting false inforrnatiorlinCiudihg the POSsibility of a fine <!rid · . . . **'==.,.,.,.---,,..,-,--,---.,-,-,-,--,--__JJiffiPii~onmerifforkrio'o\ling** violations:WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:<MountainStateCarbonLLC\MOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:_,0"'97,_______CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:WASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·•.·....... .>·.......·.·.OtherUnits····•Parameter·....··.....·IU.,..··mtsN.ECEL*..·.·34200(ML-5)RF-8ReportedAcenaphthyleneN/AN!AN!ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34205(ML-5)RF-DReportedAcenaphtheneN/AN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34220(ML-5)RF-8ReportedAnthraceneN/AN/AN!ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily34230(ML-5)RF-8ReportedBenzo(B)FluorantheneN!AN/AN/ARptOnlyRptOnlyN/AYearRoundPermttLimitsAvg.MonthlyMax.Dally34242(ML-5)RF-8ReportedBenzo(K)FluorantheneN/AN/AN/ARptOnlyRptOnlyN!AYearRoundPermitLimitsAvg.MonthlyMax.Daily34247(ML-5)RF-BReportedBenzo(A)PyreneN/AN!AN!ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00981(ML-5)RF-8ReportedSelenium,TotalRecoverableN!AN!AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily00978(ML-5)RF-8ReportedArsenic,TotalRecoverableN!AN/AN/ARptOnlyRptOnlyN/AYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=ComolianceEvaluationlevelFinalLimitations...·MeasurementSample·UnnsN£.··FrequencyTY!>eug/11/quarterGrabug/11/yearGrabug/11/quarterGrabNG/L1/quarterGrabNG/L1/quarterGrabNG/L1/quarterGrabug/11/quarterGrabmg/11/quarterGrab_.·.atrattachment;;preparedDateC·.mleted.unqermydJrectionaccordance'YithasystemdeSI!:JOedto<!sSUre1halgatherandevaluatetheinformationsubmittedcBasedon.•.·..··_...,...···of!hepersonOrpersonswhomanageJhesystem,orthosepersonsdirectly.ofPnnCipalExecutiveOfficerorTrtle.ofC>ffi&er.•·.•····.•.·•..gal':'eringtheinformation,theinforii)ationis,totheofmy.......... ....n()Vi'ledgeandbelief;true,aCC1Jrale;andcompletecIamaware!hatthere"reSignificantpenalti"l'submittingfalseinformation.inCludingthepossibilityofafineand·lfnpiisC>nmentforknowingviolations.·.··.···.WRD2A-82STATEOFWESTVIRGINIANATIONALPOLLUTANTDISCHARGEELIMINATIONSYSTEMDISCHARGEMONITORINGREPORTFACILITYNAME:!MountainStateCarbonLLClMOUNTAINSTATECARBONLLCLOCATIONOFFACILITY:FOLLANSBEE;BrookeCountyPERMITNO.:WV0004499OUTLETNO.:-"'09"-'7______CERTIFIEDLABORATORYNAME:CERTIFIEDLABORATORYADDRESS:FinalLimitationsWASTELOADFORTHEMONTHOF·INDIVIDUALPERFORMINGANALYSIS·I.<'.•··.·....·..<:•.<•...:QuantitY·_..·-...·_·.Otherunits.·...-:·.·.Measuremel\t... ."p""'inetet_·.._..-·····•.·._.·...CEL* .UnitsN.E,Frequency.····-.-.._.·..•..·._.·...UnitsN.E... .:...._·__.·..••.-.34556(ML-5)RF-BReportedDibenzo(A,H)AnthraceneN/AN/AN/ARptOnlyRptOnlyN/ANGIL1/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily34403(ML-5)RF-BReportedlndeno(1,2,3-cd)PyreneN/AN/AN/ARptOnlyRptOnlyN/ANG/L1/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily34521(ML-5)RF-BReportedBenzo{GHI)PeryleneN/A N/AN/ARptOnlyRptOnlyN/Aug/11/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily00720(ML-5)RF-BReportedCyanide,TotalN/AN/AN/ARptOnlyRptOnlyN/Amg/11/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily32730(ML-5)RF-BReportedPhenolics,TotalRecoverableN/AN/AN/ARptOnlyRptOnlyN/Aug/11/quarterYearRoundPermttLimitsAvg.MonthlyMax.Daily.34696(ML-5)RF-BReportedNaphthaleneN/AN/AN/ARptOnlyRptOnlyN/Aug/11/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily11123(ML-5)RF-BReportedTotalRecov.ManganeseN/A N/AN/ARptOnlyRptOnlyN/Amg/11/quarterYearRoundPermitLimitsAvg.MonthlyMax.Daily00011(ML-5)RF-AReportedTemperature,FN/AN/AN/ARptOnlyRptOnlyN/ADEG.F1/monthYearRoundPermitLimitsAvg.MonthlyMax.Daily*CEL=ComplianceEvaluationLevel..Sample··1.Type··GrabGrabGrabGrabGrabGrabGrablmrstb'Namecirf>rilli:ipa!ExecutiJteOfficer_Icertify.underdocumentallwereprepared.DateCompletedIIundermydirectionorsuperv•s•onmaccordancew11hasystemdes1gnecltoassurethat.•. .···-.II!Lualifiedproperlygatherandevaluatetheinformationsubmitted.Basedori_·._._.·...:...··II!================!CJ'llYlnqui,YofthepersonorPersonswl)ollianagethe.system,"Drthosepersonsdirectly.ofPnnCJpalExecutiveOfficerormii;,·of.Offieer.·.·:.esponsiblefurtheinforinatjc;)n.theinfonnatton.submittedis,t"OtheAuthonzedAgent_---..·······-··_andbEihef,true,accw-ate.lamcawarethatthereareSignificant•penaltiesfi)rslilim_ittingfalseinfolirlatt6ninCJudin_g.thepOsSlo_·_ility:_:ota:finea__·n_d .•mpriso11menffof"RnoWirigviolations.····•·-··-····-·.·-·,--..,..,---.---,----,--.--,----,-,.,---,-JI'..'-,,...'"-.--------'---.1L,--,--,----,--.______-.,-__..-___--------···___J· WRD2A-82 STATE OF WEST VIRGINIA

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

DISCHARGE MONITORING REPORT

FACILITY NAME: !Mountain State Carbon LLCl MOUNTAIN STATE CARBON LLC

LOCATION OF FACILITY: FOLLANSBEE; Brooke County

PERMIT NO.: WV0004499 OUTLET NO.: "'09,_,7'-------- CERTIFIED LABORATORY NAME:

CERTIFIED LABORATORY ADDRESS:

WASTELOAD FOR THE MONTH OF· INDIVIDUAL PERFORMING ANALYSIS·

**~~·-·** . . - . ·· ·. ·ouahtity· .. .· .. OtnerUnits

..... · .

Parameter .· Units .· N.E . .. .· GEL*

. · .· ... · ·:-. . I

81020 (ML-5) RF-B Reported

Sulfale N/A NIA NIA Rpt Only Rpt Only N/A

Year Round Permit Limits Avg. Monthly Max. Daily N/A N/A N/A N/A NIA N/A N/A

-

* CEL = Comoliance Evaluation Level Final Limitations ------

.·· · .. ·

**MeaSun:~IJl~nt** sample

Units· N.E. Frequency ·Type

mg/1 1/quarter Grab

Name ofi:>rlncii>aJ.Biecutive Officer.· . •.··· l•eeffify **Ulld_er,p~alty** of **la\1\'~.af** !\tis dOCIJmEmtand all **<i!tafllmen~** W!lre prepmed ·.Date Completed r

I nd<>J: 111Y" direction or superviSIOn _In_ accordance-With a. system designed to assure that **1-~-.:.·~·~-** =·-· --·-'----.....,--,-..,...-,..-...,.-'-1

k:iualifiec( persi>nnetproPElrlygatherana evaluate !he. information submitted. :Based on : . · ·. • · _· · . . .·. . : . . • < · .· ·

·.. .• . . .. ·. . .·· **~Y** inq.Jiry of the person or per,s0ns wlio manage the sy8tem; or those Persons **cfir~y** Signan.u-e of·PnnCipal Executive Officer or

lltle Ot-Oflicei . ··.. · _ · **~esponsiolefor ga~eiinl;!**  the information, itieinformation submitted i$,tothe be:;t ?fmy Authonzed A!i!ent ·. ·.. . • . : . . . .. · ·.·.. .. · ..

1 · ····· · · · · · **l<nowl~~ge a~d**  **be~~f,** trtie, ac:curate, **~nd_ com~lete..J**  am av:-a.r.ll th;;rt tflere are significant

· PElnatties for.submittingtalse.mformalion Indudmgthe_ possibility ofa fine and

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# WV/NPDES Permit No.: WV0004499



# NOTICE TO PERMITTEES

The 1999 regular session of the West Virginia legislature revised the Water Pollution Control Act,

Chapter 22, Article II, Section 10 of the Code of West Virginia relating to fees associated with permits.

This section of the Code requires all holders of a State water pollution control permit or a national

pollutant discharge elimination system permit to be assessed an annual permit fee, based upon rules

promulgated by the Secretary of the Department of Environmental Protection. The Secretary has

promulgated a final rule in accordance with the code revision to this effect and these rules were effective

May 4, 2000. The rules establish an annual permit fee based upon the relative potential to degrade the

waters of the State which, in most instances, relate to volume of discharge. However, for sewage facilities,

the annual permit fee is based upon the number of customers served by the facility. You may contact the

Secretary of State's Office, State Capitol Building, Charleston, WV 25305, to obtain a copy of the rules.

The reference is Title 47, Legislative Rules, Department of Environmental Protection, Division of Water

Resources, Series 26 Water Pollution Control Permit Fee Schedules.

Based upon the volume of discharge for which your facility is currently permitted, the number of

customers served by your facility or for the category you fall within, pursuant to Section 7 of Title 4 7,

Series 26, your annual permit fee is $5000.00. This fee is due no later than the anniversary date of permit

issuance in each year of the term of the permit or in the case of coverage under a general permit, the fee is

due no later than the anniversary date of your coverage under the general permit. You will be invoiced by

this agency at the appropriate time for the fee. Failure to submit the annual fee within ninety(90) days

of the due date will render your permit void upon the date you are mailed a certified written notice to that

effect.

# EMERGENCY RESPONSE SPILL ALERT SYSTEM

WEST VIRGINIA DEPARTMENT OF ENVIRONMENTAL PROTECTION

REQUIREMENTS:



# Title 47, Series II, Section 2 of the West Virginia Legislative Rules, Environmental Protection, Water

Resources- Waste Management, Effective July I, 1994.

RESPONSIBILITY FOR REPORTING:



# Each and every person who may cause or be responsible for any spill or accidental discharge of pollutants

into the waters of the State shall give immediate notification to the Division of Water and Waste Management's

Emergency Notification Number, 1-800-642-3074. Such notification shall set forth insofar as possible and as soon

thereafter as practical the time and place of such spill or discharge, type or types and quantity or quantities of the

material or materials therein, action or actions taken to stop such spill or discharge and to minimize the polluting

effect thereof, the measure or measures taken or to be taken in order to prevent a recurrence of any such spill or

discharge and such additional information as may be requested by the Division of Water and Waste Management.

This also applies to spills to the waters of the State resulting from accidents to common carriers by highway, rail and



# water.

It shall be the responsibility of each industrial establishment or other entity discharging directly to a stream

to have available the following information pertaining to those substances that are employed or handled in its

operation in sufficiently large amounts as to constitute a hazard in case of an accidental spill or discharge into a

public stream:

(I) Potential toxicity in water to man, animals and aquatic life;

(2) Details on analytical procedures for the quantitative estimation of such substances in water and

(3) Suggestions on safeguards or other precautionary measures to nullify the toxic effects of a substance once it has

gotten into a stream.

Failure to furnish such information as required by Section 14, Article II, Chapter 22, Code of West

Virginia may be punishable under Section 24, Article II, Chapter 22, and/or Section 22, Article II, Chapter 22,

Code of West Virginia.

It 

# shall be the responsibility of any person who causes or contributes in any way to the spill or accidental

discharge of any pollutant or pollutants into State waters to immediately take any and all measures necessary to

contain such spill or discharge. It 

# shall further be the responsibility of such person to take any and all measures

necessary to clean-up, remove and otherwise render such spill or discharge harmless to the waters of the State.

When the Director determines it necessary for the effective containment and abatement of spills and

accidental discharges, the Director may require the person or persons responsible for such spill or discharge to

monitor affected waters in a manner prescribed by the Director until the possibility of any adverse effect on the

waters of the State no longer exists.

VOLUNTARY REPORTING BY LAW OFFICERS, U. S. COAST GUARD, LOCK MASTERS AND

OTHERS:



# In cases involving river and highway accidents where the responsible party may or may not be available to

report the incident, law officers, U. S. Coast Guard, Lock Masters and other interested person(s) should make the

report.

WHO TO CONTACT:

Notify the following number: 1-800-642-3074



# INFORMATION NEEDED·

- Source of spill or discharge

- Location of incident

- Time of incident

- Material spilled or discharged

- Amount spilled or discharged

- Toxicity of material spilled or discharged - Personnel at the scene

-Actions initiated

- Shipper/Manufacturer identification

- Railcar/Truck identification number

- Container type

# RIGHT OF APPEAL

Notice is hereby given of your right to appeal the terms and conditions

of this permit which you are aggrieved by to the Environmental Quality Board

by filing a NOTICE OF APPEAL on the form prescribed by such Board for

this purpose, with the Board, in accordance with the provisions of Section 21,

Article 11, Chapter 22 of the Code of West Virginia within thirty (30) days

after the date of receipt of the above permit.