1

METALS 
2

Data Validation Package 

for 

METALS 

TABLE OF CONTENTS 

LABORATORY NAME: APPL Inc. 

Case Narrative 

Chain of Custody and ARF 

QC Summary 

Sample Data 

Calibration Data 

Raw Data 

\t) 
3

METALS 

Case Narrative 
4

908 North Temperance Ave. V Clovis, CA 93611 V Phone 559-275-2175 V Fax 559-275-4422 

Certification Number: CA1312 

NELAP Certification number: 05233CA 

DoD-ELAP Certificate number: ADE-1410 

Data Validatable Report 

10102/12 

CSC 

6101 Stevenson Ave. 

Alexandria, Va 

Attn: Chip McCarty 

Title: Report of Data: Case 68603 

Project: FGD MDL STUDY 

Results in this report apply to the samples analyzed in accordance with the chain of custody 

document. This analytical report must be reproduced in its entirety. 

Dear Mr. McCarty: 

The FGD matrix was received on August 30,2012 at room temperature. Written results for 

the requested analyses are provided on this 10/02112. All holding times were met. . 

Standards Prep: 

Calibration standards (Absolute Standards), ICV (CPI Inc), MDL spiking standards (CPI Inc 

and 02SI) prepared using 2% nitric acid and 0.5% hydrochloric. MDL spike levels are 

summarized in the QC section of this narrative. 

Sample Prep and Digestion: 

Samples were prepared and digested according to EPA method 1638. A 50mL sample aliquot 

was used for digestion. 0.5mL nitric acid and 0.25 mL hydrochloric acid were added to the 

samples prior to digestion. The samples were heated using a digestion block for 2 hrs at 85°C. 

Instrument Parameters: 

The samples were analyzed using an Agilent 7500cx ICP-MS using the High Matrix 

Introduction (HMJ) system. The 10ppb tuning solution (lot # 1036822) was purchased from 

02SI as recommended by Agilent. Argon gas was used as the makeup (0.3 Umin) and carrier 

(0.7 Umin). The spray chamber temperature was maintained at 2°C. The RF Power was set 

at 1600W with RF matching at 1.66 V. The internal standards associated with the analytes of 

interest are as follows: As (I.S. 115 In - Helium mode), Cd (I.S. 115 In - No-gas mode), Se 

(I.S. 115 In - Hydrogen mode), Cr (I.S. 45 Sc - Helium mode), Pb, Tl (I.S. 159 Tb - No gas 

mode), All other instrument criteria are pertaining to the MDL study are summarized on the 

Tune report. 

68603 CSC CASE.doc 
5

Sample QC: 

The reagent water MDL study was spiked at O.4ug/L for the target amilytes. As per CFR part 

136 Appendix B, a MDL in water should be spiked at one to five times the estimated 

detection limit. Our in house MDLs for similar analyses are all around 0.1 ug/L. For the 

synthetic FOD matrix MDL study we spiked at 0.5ug/L and 1.0ug/L, as we anticipated 

needing a slightly higher concentration than the water MDL. Both of these proved to be 

discernable in the synthetic FOD matrix. 

The method blanks met acceptance criteria. The Laboratory Control Samples (LCS) were 

spiked incorrectly. The 120920A-LCS was spiked at a concentration of 1.0ug/L instead of 

40ug/L for all target analytes. Recoveries met acceptance criteria. The 120921A-LCS was 

spiked at a concentration of 250ug/L for chromium, arsenic, selenium, thallium and lead, and 

50ug/L for cadmium. 

In the 120921A reagent water samples, and all method blanks and LCS samples ran this day, 

the internal standards indium and terbium exceeded the 125% upper control limits. 

Calibration: 

A three-point calibration curve was prepared for quantitation and summarized in the "standard 

prep" section of this report. The correlation coeficients for all analytes were greater than 

0.995 and are summarized on the highest calibration point in the "calibration" section of this 

report. 

In the calibration for analysis performed on 9/26/12, the percent oxides were measured at 

1.566% instead of 1 % as suggested in the method. According to the instrument manufacturer, 

an oxide level below three is acceptable, however when it is greater than 2% the rare earth 

metals may become unstable. The rare earth metals only include our internal standards. All 

other tuning criteria were met. 

We used the calibration blank at Mass 75-interference check. The counts per second (CPS) for 

arsenic were well below 25% of the CPS for arsenic at the reporting limit. 

In the ICV at 05:21, selenium recovered below the 90% lower control limit at 89.6%. The 

ICB, LUCV, and the unspiked FOD matrix interference check met acceptance criteria. The 

spiked FOD matrix check recovered above the 130% upper control limit for arsenic at 130.1 % 

and selenium at 134.6%. The CCVs were spiked incorrectly at 100ug/L for As, Cd, Cr, Pb, TI 

and Se instead of 50ug/L. 

In the individual FOD interference check, chloride was analyzed at 5000 mg/L instead of 

10,000 mg/L because the laboratory does not have a standard at this concentration. All other 

interference check solutions were made according to the concentrations stated in the method. 

In the Calcium interference check the indium and terbium internal standards recovered below 

the 60% lower control limit at 57.9% and 55.7%, respectively. 

The individual interference check solutions exceeded the reporting limits of 1.0ug/L as 

follows: in the calcium solution, chromium exceeded at 3.44ug/L, arsenic at 4.04ug/L, 

cadmium at 3.32ugIL, and lead at 1.08ug/L. In the sulfate solution, selenium exceeded at 

3.45ug/L. In the magnesium solution, chromium exceeded at 3.09ug/L, arsenic at l.llug/L 

and lead at 1.69ugIL. In the iron solution, chromium exceeded at 1.1lugIL. In the vanadium 

68603 CSC CASE.doc 
6

solution, selenium exceeded at 9.64ugIL. In the zinc solution, selenium exceeded at 3.43ugIL. 

In the chromium solution, selenium exceeded at 1.86ugIL. In the copper solution, selenium 

exceeded at 1.41 ugIL. 

In the 120921A 1.0 FGD matrix MDL samples, the internal standard indium (#1) associated 

with selenium recovered below the 60% lower control limits. 

In the calibration for analysis performed on 9/27112 the percent oxides were measured at 

1.997% instead of 1 % as suggested in the method. All other tuning criteria were met. 

In the ICV on 9/27112 at 06:50, silver recovered below the 90% lower control limit at 89.8%. 

The ICB, LUCV, and the unspiked FGD matrix interference check met acceptance criteria. In 

the spiked FGD matrix, arsenic and selenium recovered above the 130% upper control limits 

at 138.6% and 134.6%, respectively. 

In the CCVs at 09:11,10:44 and 12:18 and the CCBs at 09:24 and 10:58 the internal standards 

indium #3 (associated with cadmium) and terbium (associated with lead) recovered above the 

125% upper control limits. Additionally, the CCV at 09: 11 exceeded the 110% upper control 

limit for selenium at 113.4%. 

If you have any questions or require further information, please contact your APPL Project 

Manager Stephane Maupas at your convenience. Thank you for choosing APPL, Inc. 

Release of the hard copy has been authorized by the Laboratory Manager or her designee, as 

verified by the following signature. 

Sharon Dehmlow, Laboratory Director 

APPL, Inc. 

SD/rp 

Enclosure 

cc: File 

68603 CSC CASE.doc 
7

METALS 

Chain of Custody and ARF 
8

APPL - Analysis Request Form 68603 

Client: CSC Received by: CM 11111111111111111111111111111111111 

Address: 6101 Steveson Ave. Date Received: 08/30/12 Time: 15:30 

Alexandria, VA 22304 Delivered by: -=---F=E=O--=E=-X=------________ _ 

Attn: Chi~Q_'_'M=c~C=a=_=__rt~y ________ _ Shuttle Custody Seals (YIN): l Time Zone: -4 

Phone: 703-461-2392 Fax: 703-461-8056 Chest Temp(s): -'-R=O~O::...:M_=..:........:.T-=E=M=P _______ _ 

Job: FGO MOL Study Color: A-frig~ _________ ~ 

PO #: 685553SS0 Samples Chilled until Placed in Refrig/Freezer: Y 

Chain of Custody (Y/N):--'L # ______ _ Project Manager: SteQhane MauQ'--'-a-'-s ____ _ 

RAD Screen (YIN): Y pH (YIN): N QC Report Type: OVP4/EXCELN A 

r1 

Turn Around Type: 

Comments: 

STO Due Date: 09/20/12 

Send PDF on CD and email reporttohmccarty@csc.com 

Document everything you do. Report 3 sig figs. Do not waste the simulated FGD fluid. 

Follow SOW and QAPP: do not deviate with notifying PM 

Need Results by 9-15-2012 

Sample Distribution: Charges: Invoice To: 

Metals: 14-$2008~Cr,Se,Cd,Pb,I!t----=1'--'-4_-____________ _ 

$20082(As,Cr,Se,-=C.=d,'-'-P-=bL:,T-'1I

) ______________ ----- Send Invoice to PM for approval 

Client ID 

1. RW-1 

2. RW-2 

3. RW-3 

APPL ID Sampled Analyses Requested 

AY67404W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr,Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

AY67405W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr,Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

AY67406W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr,Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

Note: All times, excluding sample collection times. are Pacific Time Zone unless noted otherwise. Collection times are in: -4 UTC 

Page 1 Client Code: GENERIC Printed 10102112 12:53:33 PM Computer: RENEECOMPUT # 68603 
9

APPL - Analysis Request Form 68603 

4. RW-4 AY67407W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As,Cr,Se,Cd,Pb,TI) -- Dilute; digest by 

EPA 1638 

5. RW-5 AY67408W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr, Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

6. RW-6 

7. RW-7 

8. FGD-1 

9. FGD-2 

10. FGD-3 

11. FGD-4 

12. FGD-5 

13. FGD-6 

14. FGD-7 

AY67409W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr,Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

AY6741OW 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr,Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

AY67411M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As,Cr,Se,Cd,Pb,TI) -- Dilute; digest by 

EPA 1638 

AY67412M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As,Cr,Se,Cd,Pb,TI) -- Dilute; digest by 

EPA 1638 

AY67413M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr,Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

AY67414M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As,Cr,Se,Cd,Pb,TI) -- Dilute; digest by 

EPA 1638 

AY67415M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As,Cr,Se,Cd,Pb,TI) -- Dilute; digest by 

EPA 1638 

AY67416M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr, Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

AY67417M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 

111111111111111111111111111111111111111111111 $20082(As, Cr, Se, Cd, Pb, TI) -- Dilute; digest by 

EPA 1638 

Note: All times, excluding sample collection times, are Pacific Time Zone unless noted otherwise. Collection times are in: -4 UTC 

Page 2 Client Code: GENERIC Printed 10/02112 12:53:33 PM Computer: RENEECOMPUT # 68603 
10

METALS 

QC Summary 
11

METALS BLANK 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

Method Analyte Result PQL Units Prep Date Analysis Date QC Group 

200.8 ARSENIC (AS) Not detected 0.5 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67 404 

200.8 CADMIUM (CD) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67 404 

200.8 CHROMIUM (CR) Not detected 0.5 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67 404 

200.8 LEAD (PB) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 

200.8 SELENIUM (SE) Not detected 1.0 ug/L 09/20/12 09/26/12 #2008-120920A-AY67404 

200.8 THALLIUM (TL) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67 404 

200.8 ARSENIC (AS) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67 411 

200.8 CADMIUM (CD) Not detected 0.20 ug/L 09/20/12 09/27/12 #2008-120920A-AY67411 

200.8 CHROMIUM (CR) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-AY67411 

200.8 LEAD (PB) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-AY67411 

200.8 SELENIUM (SE) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-AY67411 

200.8 THALLIUM (TL) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67 411 

Printed: 101011125:01:13 PM 
12

Laboratory Control Spike Recovery 

METALS 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

Method Compound Name Spike Level SPK Result SPK% Recovery Extract Analysis 

ug/L ug/L Recovery Limits Date Date 

200.8 ARSENIC (AS) 250 257 103 85-115 09/20/12 09/26/12 

200.8 CADMIUM (CD) 50.0 47.6 95.2 85-115 09/20/12 09/26/12 

200.8 CHROMIUM (CR) 250 285 114 85-115 09/20/12 09/26/12 

200.8 LEAD (PB) 250 229 91.6 85-115 09/20/12 09/26/12 

200.8 SELENIUM (SE) 250 269 108 85-115 09/20/12 09/26/12 

200.8 THALLIUM (TL) 250 226 9004 85-115 09/20/12 09/26/12 

Comments: ----------------------------------------------------------------------

QC Group 

#2008-120920A-A Y67 404 

#2008-120920A-AY67404 

#2008-120920A-AY67404 

#2008-120920A-A Y67 404 

#2008-120920A-AY67404 

#2008-120920A-AY67404 

Printed: 101011125:04:41 PM 

APPL Standard LCS 
13

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

Method Compound Name 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

200.8 THALLIUM (TL) 

Laboratory Control Spike Recovery 

METALS 

Spike Level SPK Result SPK% Recovery Extract 

ug/L ug/L Recovery Limits Date 

1.00 1.1 110 85-115 09/20/12 

1.00 1.1 110 85-115 09/20/12 

1.00 0.99 99.0 85-115 09/20/12 

1.00 0.98 98.0 85-115 09/20/12 

1.00 1.1 110 85-115 09/20/12 

1.00 0.91 91.0 85-115 09/20/12 

Analysis 

Date 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

Comments: ____________________________________________________________________ __ 

QC Group 

#2008-120920A-AY67411 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67 411 

Printed: 101011125:04:41 PM 

APPL Standard LCS 
14

METALS 

Sample Data 
15

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-1 

Sam pie Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.46 

0.36 

0.37 

0.33 

0.88 

POL Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67404 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

_~~9_·~ ______________ T_Ij_~~~~~~_Q~~) __________________ _____________________ 9_·~~ _______________________ ~:? __ ______________ ~9!~ ________ 9_9!~~L~? ___________ ~~~?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
16

C, \ICPCIlEM\1\OATA\12I26qOO. B\OBOSMPL. O\OBOSMPL .0# 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\080SMPL.D\080SMPL.D# 

Sep 27 2012 01:20 am 

Operator: NBS 

Sample Name: BLK MDL 0.4-1 

Mise Info: 120921A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3304 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep oil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

(Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 MIl 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Conc. 

ug/l 

0.30 ug/l 

11.67 ug/l 

383.10 ug/l 

237.30 ug/l 

1.30 ug/l 

59.06 ug/l 

326.00 ug/l 

0.22 ug/l 

0.47 ug/l 

0.37 ug/l 

-1. 06 ug/l 

3.58 ug/l 

0.40 ug/l 

0.32 ug/l 

0.44 ug/l 

0.45 ug/l 

-2.43 ug/l 

0.46 ug/l 

0.88 ug/l 

2.71 ug/l 

-0.06 ug/l 

-0.03 ug/l 

0.33 ug/l 

ug/l 

0.17 ug/l 

ug/l 

0.36 ug/l 

-3.14 ug/l 

-3.30 ug/l 

-2.92 ug/l 

0.39 ug/l 

0.30 ug/l 

0.33 ug/l 

ug/l 

ug/l 

0.33 ug/l 

Carr. Conc. 

#VALUEI 

0.30 

11.67 

383.10 

237.30 

1. 30 

59.06 

326.00 

0.22 

0.47 

0.37 

-1.06 

3.58 

0.40 

0.32 

0.44 

0.45 

-2.43 

0.46 

0.88 

2.71 

-0.06 

-0.03 

0.33 

#VALUEI 

0.17 

#VALUEI 

0.36 

-3.14 

-3.30 

-2.92 

0.39 

0.30 

0.33 

#VALUEI 

# VALUE I 

0.33 

Element CPS Mean RSD(%) Ref Value 

Li -103602.70 5.24 -131996.50 

45 Sc 3305273.30 0.78 3646344.80 

45 Sc 438338.66 0.47 537987.94 

45 Sc 15578020.00 0.39 17012292.00 

72 Ge 823952.19 0.11 949396.31 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

277281.06 

3276284.80 

5969842.00 

2882175.30 

21738374.00 

27067192.00 

26065410.00 

2.07 338792.91 

0.81 3456710.80 

0.96 6610579.00 

0.68 3651775.30 

0.71 22769202.00 

1.06 28649686.00 

0.84 27453282.00 

RSD(%) High Limit 

o 

2.81 1000 

2.04 1000 

4.74 25000 

2.62 50000 

32.20 20000 

8.04 20000 

6.14 50000 

22.40 1000 

1.61 1000 

3.55 1000 

1. 48 1000 

1. 93 20000 

0.59 

8.86 

6.57 

7.45 

0.75 

3.22 

2.25 

6.82 

37.80 

16.72 

4.08 

2.79 

0.86 

1.02 

1.84 

0.19 

1. 42 

5.10 

0.83 

1.36 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

#U####U 

500 

#UU##U# 

1000 

U#UUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

U##UUUU 

1000 

Rec(%) QC Range(%) 

78.5 

90.6 

81. 5 

91.6 

86.8 

81.8 

94.8 

90.3 

78.9 

95.5 

94.5 

94.9 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 -

70 -

70 -

70 

70 -

70 -

70 -

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU 

:Element Failures 

1 : ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 1 :24 AM 

Pass 

Fail 

o :Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
17

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-1 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

Metals Analysis 

Result 

0.50 

0.40 

0.36 

pal 

0.2 

0.2 

0.2 

Units 

ug/L 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67404 

Prep Date Analysis Date 

09/21/12 

09/21/12 

09/21/12 

09/27/12 

09/27/12 

09/27/12 

200.8 LEAD (PB) 0.38 0.2 ug/L 09/21/12 09/27/12 

200.8 SELENIUM (SE) 0.45 0.2 ug/L 09/21/12 09/27/12 

__ ~~9_·~ ______________ T_Ij_;:'_~~~~~_Q~~) ________________ _______________________ 9:~? _______________________ ~:~ ________________ ~g!~ ________ 9_~!?~L~? ___________ 9~~?X{~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:26 PM 
18

C, \ICPCHEM\l \OATA\12127s00. B\037SMPL. D\037SMPL. Dj 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27s00.B\037SMPL.D\037SMPL.D# 

Sep 27 2012 10:04 pm 

Operator: NBS 

Sample Name: BLK MDL 0.4-1 

Mise Info: 120921A-1638 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

3304 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep oil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

0.42 ug/l 

0.29 ug/l 

145.50 ug/l 

106.90 ug/l 

4.00 ug/l 

47.81 ug/l 

184.80 ug/l 

0.37 ug/l 

0.57 ug/l 

0.36 ug/l 

0.49 ug/l 

8.36 ug/l 

0.42 ug/l 

0.51 ug/l 

0.41 ug/l 

0.43 ug/l 

4.03 ug/l 

0.50 ug/l 

0.45 ug/l 

2.87ug/l 

0.48 ug/l 

0.40 ug/l 

0.26 ug/l 

ug/l 

0.20ug/l 

ug/l 

0.40 ug/l 

0.32 ug/l 

0.38 ug/l 

0.30 ug/l 

0.42 ug/l 

0.45 ug/l 

0.36 ug/l 

ug/l 

ug/l 

0.38 ug/l 

Element CPS Mean RSD(%) 

Carr. Cone. 

#VALUE! 

0.42 

0.29 

145.50 

106.90 

4.00 

47.81 

184.80 

0.37 

0.57 

0.36 

0.49 

8.36 

0.42 

0.51 

0.41 

0.43 

4.03 

0.50 

0.45 

2.87 

0.48 

0.40 

0.26 

#VALUE! 

0.20 

#VALUE! 

0.40 

0.32 

0.38 

0.30 

0.42 

0.45 

0.36 

#VALUE! 

#VALUE! 

0.38 

RSD(%) High Limit 

o 1.01 1000 

13.21 1000 

1. 01 25000 

1.17 50000 

14.14 20000 

2.61 20000 

3.26 50000 

5.49 1000 

3.92 1000 

0.73 1000 

2.37 1000 

0.96 20000 

2.38 1000 

4.79 1000 

1.37 1000 

4.30 1000 

0.85 1000 

3.03 1000 

14.17 1000 

3.24 1000 

2.39 1000 

1.14 1000 

1.84 1000 

####### 

3.36 500 

####### 

1.98 1000 

24.98 ####### 

2.87 ####### 

3.63 1000 

3.14 1000 

1.87 1000 

1.12 1000 

####### 

####### 

0.84 1000 

QC Range(%) 

6 Li -173541.61 4.37 

Ref Value 

-88139.43 

5590061.50 

732360.19 

Rec(%) 

196.9 

98.5 

101.5 

128.3 

99.7 

101.4 

126.0 

97.9 

70 120 

45 Sc 5508884.00 13.18 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

743064.00 

23117014.00 

1404062.80 

482285.81 

4587767.50 

9846775.00 

4771820.00 

27685338.00 

31468000.00 

29482754.00 

0.78 

0.46 18013604.00 

8.38 1407958.90 

0.55 475526.09 

0.95 3640663.30 

13.13 10055673.00 

0.55 4993515.00 

0.54 20883300.00 

0.55 23533162.00 

0.84 22278996.00 

95.6 

132.6 

133.7 

132.3 

70 - 120 

70 120 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS fai 

IS fai 

IS fai 

IS fai 

IS fai 

IS fai 

ISTD Ref File , C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 10:08 PM 

Pass 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
19

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-2 

Sam pie Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.46 

0.37 

0.40 

0.34 

0.62 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67405 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

__ ~~9_·~ ______________ ~_~~_~!:~~~_C~~~ _______________________________________ 9_·~~ _______________________ ~:~ ________________ ~g!!: ________ 9_~!?~!_1_? __________ 9~~?X~~? ___ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
20

C: \ICPCHEM\l \DATA\12I26qOO. B\OB1SMPL. D\OB1SMPL. D' 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\081SMPL.D\081SMPL.D# 

Sep 27 2012 01:27 am 

Operator: NBS 

Sample Name: BLK MDL 0.4-2 

Misc Info: 120921A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3305 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1.00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

0.31 ug/l 

12.80 ug/l 

169.10 ug/l 

61. 55 ug/l 

1.59 ug/l 

54.60 ug/l 

-37.99 ug/l 

0.32 ug/l 

0.58 ug/l 

0.40 ug/l 

-0.98 ug/l 

8.16 ug/l 

0.41 ug/l 

0.31 ug/l 

0.49 ug/l 

0.49 ug/l 

-2.37 ug/l 

0.46 ug/l 

0.62 ug/l 

2.42 ug/l 

-0.05 ug/l 

-0.02 ug/l 

0.35 ug/l 

ug/l 

0.17 ug/l 

ug/1 

0.37 ug/l 

-3.13 ug/l 

-3.27 ug/l 

-2.91 ug/l 

0.36 ug/l 

0.30 ug/l 

0.34 ug/l 

ug/l 

ug/l 

0.34 ug/l 

Element CPS Mean RSD(%) 

Corr. Cone. 

#VALUEI 

0.31 

12.80 

169.10 

61.55 

1.59 

54.60 

-37.99 

0.32 

0.58 

0.40 

-0.98 

8.16 

0.41 

0.31 

0.49 

0.49 

-2.37 

0.46 

0.62 

2.42 

-0.05 

-0.02 

0.35 

#VALUE! 

0.17 

#VALUEI 

0.37 

-3.13 

-3.27 

-2.91 

0.36 

0.30 

0.34 

#VALUE! 

#VALUE! 

0.34 

RSD(%) High Limit 

o 3.31 1000 

2.25 1000 

2.77 25000 

3.00 50000 

18.97 20000 

11.10 20000 

24.25 50000 

23.29 1000 

7.54 1000 

4.60 1000 

1. 23 1000 

44.41 20000 

1.98 

8.27 

3.20 

5.03 

0.65 

3.20 

6.23 

12.46 

187.39 

171 .70 

7.05 

1.15 

3.84 

0.77 

0.22 

0.34 

2.74 

4.71 

1. 08 

1. 46 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

6 Li -106963.16 0.87 

45 Sc 3072831.00 0.87 

Ref Value 

-131996.50 

3646344.80 

Rec(%) 

81.0 

84.3 

75.2 

86.3 

80.1 

76.2 

89.1 

84 .0 

74.9 

92 .3 

91.0 

91.8 

70 120 

70 - 120 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

404812.03 

14678355.00 

760577.31 

258010.20 

3079824.50 

5554741. 00 

2735935.30 

21012024.00 

26077882.00 

25191176.00 

0.43 537987.94 

0.40 17012292.00 

1.33 949396.31 

2.44 338792.91 

0.53 3456710.80 

0.86 6610579.00 

0.30 3651775.30 

0.62 22769202.00 

0.59 28649686.00 

1.29 27453282.00 

70 

70 

70 

70 

70 

70 

70 

70 

70 -

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.0# 

o :Element Failures 

1 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 1 :30 AM 

Pass 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
21

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-2 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

Metals Analysis 

Result PQL Units 

0.50 0.2 ug/L 

0.40 0.2 ug/L 

0.38 0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67405 

Prep Date Analysis Date 

09/21/12 

09/21/12 

09/27/12 

09/27/12 

09/21/12 09/27/12 

200.8 LEAD (PB) 0.39 0.2 ug/L 09/21/12 09/27/12 

200.8 SELENIUM (SE) 0.49 0.2 ug/L 09/21/12 09/27/12 

.~~~:~ ______________ T_Ij_~_~~~~~_C~~~ _______________________________________ Q:~! ______________________ ~:? ________________ ~9!~ ________ ~_~!~~!_~? ___________ Q~{?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:26 PM 
22

C: \ICPCHEK\l \DATA \12127.00.8\0 38SMPL. D\038SMPL. D# 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27s00.B\038SMPL.D\038SMPL.D# 

Sep 27 2012 10:11 pm 

Operator: NBS 

Sample Name: BLK MDL 0.4-2 

Mise Info: 120921A-1638 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

3305 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Blements 

Element Conc. Carr. Conc. 

#VALUEl 

0.42 

0.29 

93.11 

54.85 

4.48 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.42 ug/l 

0.29 ug/l 

93.11 ug/l 

54.85 ug/l 

4.48 ug/l 

45.40 ug/1 

66.38 ug/l 

0.43 ug/l 

0.54 ug/l 

0.38 ug/l 

0.54 ug/l 

10.54 ug/l 

0.42 ug/l 

0.45 ug/l 

0.41 ug/l 

0.38 ug/l 

1.16 ug/l 

0.50 ug/l 

0.49 ug/l 

.2.66 ug/l 

0.47 ug/l 

0.39 ug/l 

0.27 ug/l 

ug/l 

0.20 ug/l 

ug/l 

0.40 ug/l 

0.37 ug/l 

0.43 ug/l 

0.31 ug/l 

0.40 ug/l 

0.44 ug/l 

0.37 ug/l 

ug/l 

ug/l 

0.39 ug/l 

45.40 

66.38 

0.43 

0.54 

0.38 

0.54 

10.54 

0.42 

0.45 

0.41 

0.38 

1.16 

0.50 

0.49 

2.66 

0.47 

0.39 

0.27 

#VALUEl 

0.20 

#VALUEl 

0.40 

0.37 

0.43 

0.31 

0.40 

0.44 

0.37 

#VALUEl 

#VALUEl 

0.39 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

732360.19 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-177837.72 

5411389.00 

744891. 38 

23060816.00 

1379568.50 

476809.56 

4585969.50 

9483376.00 

4788741.00 

27870798.00 

31247978.00 

29465290.00 

1. 26 

1. 27 

1. 07 

0.87 18013604.00 

0.18 1407958.90 

1.30 475526.09 

1.71 3640663.30 

0.48 10055673.00 

0.78 4993515.00 

0.95 20883300.00 

0.37 23533162.00 

0.45 22278996.00 

RSD(%) 

3.34 

35.26 

2.34 

3.12 

32.37 

1. 96 

6.16 

17.58 

1. 83 

2.81 

1.15 

1.17 

1. 03 

2.13 

0.47 

3.59 

10.42 

2.36 

3.33 

6.19 

6.28 

2.54 

7.24 

0.52 

2.06 

5.71 

1. 85 

4.14 

0.79 

6.23 

2.24 

1.42 

Rec(%) 

201.8 

96.8 

101.7 

128.0 

98.0 

100.3 

126.0 

94.3 

95.9 

133.5 

132.8 

132.3 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

QC Range (%) Flag 

70 120 IS Fai 

70 120 

70 - 120 

70 - 120 IS Fai 

70 - 120 

70 - 120 

70 120 IS Fai 

70 120 

70 

70 -

70 -

70 -

120 

120 IS Fai 

120 IS Fai 

120 IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

:Blement Failures 

6 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

912711210:15 PM 

Pass 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
23

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-3 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.43 

0.35 

0.35 

0.34 

0.54 

POL Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67406 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

.. ~~9_·~ ______________ "!"_Ij~_~~~~~_C~~) _______________________________________ 9}~ _______________________ ~:? ___ _____________ ~9!_~ ________ 9_~!?~!_~? ___________ 9~~?X!~_~ ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
24

C, \ICPCIIEM\l \DATA\12126qOO. B\082SMPL. D\082SMPL. D# 

Sample QC Report 

Data File: 

Date Acquired, 

Operator: 

C:\ICPCHEM\1\DATA\12I26qOO.B\082SMPL.D\082SMPL.D# 

Sep 27 2012 01:33 am 

Sample Name, 

Mise Info: 

NBS 

BLK MDL 0.4-3 

120921A-1638 

Vial Number, 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Prep Dil Factor: 

3306 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

1. 00 

Total Dil Factor, 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Conc. 

ug/l 

0.32 ug/l 

12.89 ug/l 

139.40 ug/l 

44.64 ug/l 

1.55 ug/l 

46.60 ug/l 

-57.04 ug/l 

0.29 ug/l 

0.52 ug/l 

0.35 ug/l 

-1.02 ug/l 

3.21 ug/l 

0.39 ug/l 

0.30 ug/l 

0.47 ug/l 

0.47ug/l 

-2.44 ug/l 

0.43 ug/l 

0.54 ug/l 

2.22 ug/l 

-0.06 ug/l 

-0.05 ug/l 

0.31 ug/l 

ug/l 

0.17 ug/l 

ug/l 

0.35 ug/l 

-3.18 ug/l 

-3.36 ug/l 

-2.93 ug/l 

0.36ug/l 

0.43 ug/l 

0.33 ug/l 

ug/l 

ug/l 

0.34 ug/l 

Element CPS Mean RSD(%) 

Cerro Conc. 

#VALUE! 

0.32 

12.89 

139.40 

44.64 

1.55 

46.60 

-57.04 

0.29 

0.52 

0.35 

-1.02 

3.21 

0.39 

0.30 

0.47 

0.47 

-2.44 

0.43 

0.54 

2.22 

-0.06 

-0.05 

0.31 

#VALUE! 

0.17 

#VALUE! 

0.35 

-3.18 

-3.36 

-2.93 

0.36 

0.43 

0.33 

#VALUE! 

#VALUE! 

0.34 

RSD(%) High Limit 

o 

5.92 1000 

2.06 1000 

2.93 25000 

5.66 50000 

23.69 20000 

9.22 20000 

16.12 50000 

33.53 1000 

4.93 1000 

4.44 1000 

3.92 1000 

6.29 20000 

2.31 1000 

2.55 1000 

1.00 

11.20 

0.73 

4.19 

4.05 

4.77 

58.44 

6.31 

7.64 

2.13 

6.18 

1. 34 

0.49 

0.24 

3.76 

5.64 

1.67 

1. 07 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

6 Li -104798.59 1. 86 

Ref Value 

-131996.50 

3646344.80 

Rec(%) 

79.4 

82.0 

74.6 

84.4 

78.4 

74.7 

87.7 

82.5 

74.4 

89.9 

90.6 

91. 7 

70 120 

45 Sc 2990962.50 0.47 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

401310.91 

14360043.00 

744779.69 

253142.72 

3032086.30 

5451065.50 

2718455.50 

20458602.00 

25961598.00 

25171444.00 

1.75 537987.94 

0.25 17012292.00 

1.01 949396.31 

0.18 338792.91 

0.45 3456710.80 

0.09 6610579.00 

0.11 3651775.30 

0.41 22769202.00 

0.28 28649686.00 

0.46 27453282.00 

70 120 

70 

70 -

70 -

70 -

70 

70 -

70 

70 -

70 

70 -

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures 

:ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 1 :37 AM 

Pass 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C,\ICPCHBM\l\rpttmp\Sample.qct Page 1 of 1 
25

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-3 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

Metals Analysis 

Result 

0.47 

0.41 

PQL 

0.2 

0.2 

Units 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67406 

Prep Date Analysis Date 

09/21/12 

09/21/12 

09/27/12 

09/27/12 

200.8 CHROMIUM (CR) 0.34 0.2 ug/L 09/21/12 09/27/12 

200.8 LEAD (PB) 0.38 0.2 ug/L 09/21/12 09/27/12 

200.8 SELENIUM (SE) 0.44 0.2 ug/L 09/21/12 09/27/12 

.. ~Q9:~ ........ __ ._._T.~~_~~~~~_C~~1 __ ._ .. _ .... _._._ .. _._._ .. ___ ._ ... __ .. _.9:~?._._._ ................ Q:~ ............. _ ..~g!~_ ....... 9.~!?~!.~? ... __ . ____ 9~~?X{~_~ ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:26 PM 
26

C, \ICPCHEM\l \DATA\12127.00 .B\OJ9SMPL. D\039SMPL. D' 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C:\ICPCHEM\1\DATA\12I27S00.B\039SMPL.D\039SMPL.DU 

Sep 27 2012 10,18 pm 

NBS 

BLK MDL 0.4-3 

120921A-1638 

Vial Number, 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Prep Dil Factor: 

3306 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample 

1. 00 

Total Dil Factor, 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

0.43 ug/l 

0.18 ug/l 

91.42 ug/l 

33.53 ug/l 

3.79 ug/l 

42.26 ug/l 

23.65 ug/l 

0.37 ug/l 

0.49 ug/l 

0.34 ug/l 

0.46 ug/l 

7.77 ug/l 

0.41 ug/l 

0.41 ug/l 

0.38 ug/l 

0.38 ug/l 

1.05 ug/l 

0.47 ug/l 

0.44 ug/l 

2.55 ug/l 

0.46 ug/l 

0.38 ug/l 

0.24 ug/l 

ug/l 

0.19 ug/l 

ug/l 

0.41 ug/l 

0.30 ug/l 

0.36 ug/l 

0.27 ug/l 

0.39 ug/l 

0.57 ug/l 

0.36 ug/l 

ug/l 

ug/l 

0.38 ug/l 

Carr. Cone. 

UVALUE! 

0.43 

0.18 

91.42 

33.53 

3.79 

42.26 

23.65 

0.37 

0.49 

0.34 

0.46 

7.77 

0.41 

0.41 

0.38 

0.38 

1.05 

0.47 

0.44 

2.55 

0.46 

0.38 

0.24 

UVALUE! 

0.19 

UVALUE! 

0.41 

0.30 

0.36 

0.27 

0.39 

0.57 

0.36 

UVALUE! 

UVALUE! 

0.38 

RSD(%) High Limit 

o 4.59 1000 

62.53 1000 

2.86 25000 

1.49 50000 

5.75 20000 

6.82 20000 

13 .00 50000 

30.42 1000 

1.37 1000 

0.79 1000 

2.63 1000 

0.42 20000 

0.97 

6.76 

4.74 

10.98 

2.27 

5.32 

6.95 

5.70 

3.24 

1. 24 

6.31 

2.24 

3.73 

9.61 

7.36 

5.02 

1. 86 

2.01 

1.66 

2.29 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

Flag 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

Rec (%) 

196.3 

96.7 

101. 6 

126.8 

97.1 

98.5 

124.6 

QC Range (%) Flag 

6 Li -173009.55 5.75 70 120 IS Fai 

45 Sc 5406428.50 0.63 70 - 120 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

744385.31 

22844010.00 

1367568.50 

468234.97 

4537357.50 

9585306.00 

4835281.50 

27915818.00 

31504894.00 

29729574.00 

ISTD Ref File : 

o :Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27/1210:22 PM 

0.72 732360.19 

0.77 18013604.00 

0.32 1407958.90 

1. 57 475526.09 

1.17 3640663.30 

0.74 10055673.00 

0.16 4993515.00 

0.53 20883300.00 

1.37 23533162.00 

0.54 22278996.00 

95.3 

96.8 

133.7 

133.9 

133.4 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

120 

120 IS Fai 

120 

120 

120 IS Fai 

120 

120 

120 IS Fai 

120 IS Fai 

120 IS Fai 

C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.DU 

Pass 

Fail 

o ,Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
27

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-4 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.45 

0.36 

0.38 

0.35 

0.56 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67407 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

.. ~~9:~ ..... ____ ... _.T.I-:lt-.~!:~~~.{!~) ... _ .._ .._._. __________________________ 9}? _______________________ ~:~ ________________ ~g!_~ ________ 9_~t~~!_~~ __________ Q~~?!.t~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
28

C: \ICPCHEM\l \DATA \12I26qOO .8\083SMPL .D\083SMPL .D# 

Sample QC Report. 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\083SMPL.D\083SMPL.DU 

Sep 27 2012 01:40 am 

Operator: NBS 

Sample Name: BLK MDL 0.4-4 

Mise Info: 120921A-1638 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

3307 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1.00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

III Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

0.33 ug/l 

12.57 ug/l 

84.68 ug/l 

30.14 ug/l 

1.53ug/l 

45.41 ug/l 

-91.93 ug/l 

0.34 ug/l 

0.50 ug/l 

0.38 ug/l 

-1.03 ug/l 

4.86 ug/l 

0.39 ug/l 

0.29 ug/l 

0.50 ug/l 

0.51 ug/l 

-2.38 ug/l 

0.45 ug/l 

0.56 ug/l 

2.11 ug/l 

-0.08 ug/l 

-0.04 ug/l 

0.35 ug/l 

ug/l 

0.17 ug/l 

ug/l 

0.36 ug/1 

-3.15 ug/l 

-3.32 ug/l 

-2.92 ug/l 

0.36 ug/l 

0.30 ug/l 

0.36 ug/l 

ug/l 

ug/l 

0.35 ug/l 

Element CPS Mean 

Carr. Cone. 

#VALUE! 

0.33 

12.57 

84.68 

30.14 

1. 53 

45.41 

-91. 93 

0.34 

0.50 

0.38 

-1.03 

4.86 

0.39 

0.29 

0.50 

0.51 

-2.38 

0.45 

0.56 

2.11 

-0.08 

-0.04 

0.35 

#VALUE! 

0.17 

UVALUE! 

0.36 

-3.15 

-3.32 

-2.92 

0.36 

0.30 

0.36 

#VALUE! 

#VALUE! 

0.35 

RSD(%) High Limit 

o 2.75 1000 

3.37 1000 

1. 34 25000 

4.09 50000 

9.21 20000 

6.21 20000 

4.78 50000 

45.70 1000 

1. 35 1000 

5.45 1000 

0.96 1000 

7.19 20000 

1. 54 1000 

1. 85 

6.95 

0.87 

0.77 

5.94 

6.54 

1. 66 

9.34 

14.13 

19.52 

2.61 

4.74 

0.83 

1. 23 

0.47 

1. 58 

4.08 

1. 63 

1. 49 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

U##U#UU 

500 

#U##U## 

1000 

U#UU##U 

U#U#UU# 

1000 

1000 

1000 

1000 

#U#U### 

U##U##U 

1000 

QC Range(%) 

Li -104533.84 

45 Sc 2888578.00 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

394083.78 

14073723.00 

723777.88 

248784.34 

2993818.80 

5281723.00 

2697630.00 

RSD(%) 

7.03 

0.45 

0.83 

Ref Value 

-131996.50 

3646344.80 

537987.94 

Rec(%) 

79.2 

79.2 

73.3 

82.7 

76.2 

73.4 

86.6 

79.9 

73.9 

90.1 

90.8 

92.1 

70 120 

70 - 120 

70 120 

20513066.00 

26002262.00 

25280290.00 

1.12 17012292.00 

0.78 949396.31 

1.65 338792.91 

1.42 3456710.80 

0.44 6610579.00 

0.41 3651775.30 

0.77 22769202.00 

0.15 28649686.00 

0.44 27453282.00 

70 

70 -

70 -

70 

70 -

70 -

70 -

70 

70 -

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU 

:Element Failures 

1 : ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271121:44 AM 

Pass 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
29

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MOL Study 

Sample 10: RW-4 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.49 

0.41 

0.35 

0.39 

0.48 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67407 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

__ ~~9:~ ______________ T_Ij_~~~~~~_{~~~ __________________ _____________________ 9:~~ _______________________ ~:~ ________________ ~g!~ ________ 9_~!~~!_~? ___________ ~~~?X!~_~ ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:26 PM 
30

C, \ICPCHEM\l \DATA\12I27.00. B\040SIIPL. D\040SIIPL.Df 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I27s00.B\040SMPL.D\040SMPL.D# 

Sep 27 2012 10,24 pm 

NBS 

BLK MDL 0.4-4 

120921A-1638 

Vial Number, 

CUrrent Method, 

Calibration File, 

Last Cal Update, 

Sample Type, 

3307 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1. 00 

1.00 

QC Elements 

Element Cone. Carr. Cone. 

#VALUEI 

0.44 

0.07 

64.42 

30.92 

4.99 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.44 ug/l 

0.07 ug/l 

64.42 ug/l 

30.92 ug/l 

4.99 ug/l 

40.69 ug/l 

23.13 ug/l 

0.38 ug/l 

0.51 ug/l 

0.35 ug/l 

0.54 ug/l 

9.15 ug/l 

0.42 ug/l 

0.43 ug/l 

0.39 ug/l 

0.39 ug/l 

1.06 ug/l 

0.49 ug/l 

0.48 ug/l 

2.54 ug/l 

0.47 ug/l 

0.39 ug/l 

0.26 ug/l 

ug/l 

0.20 ug/l 

ug/l 

0.41 ug/l 

0.32 ug/l 

0.36 ug/l 

0.29ug/l 

0.40 ug/l 

0.43 ug/l 

0.38 ug/l 

ug/l 

ug/l 

0.39 ug/l 

40.69 

23.13 

0.38 

0.51 

0.35 

0.54 

9.15 

0.42 

0.43 

0.39 

0.39 

1. 06 

0.49 

0.48 

2.54 

0.47 

0.39 

0.26 

#VALUEI 

0.20 

#VALUEI 

0.41 

0.32 

0.36 

0.29 

0.40 

0.43 

0.38 

#VALUEI 

#VALUEI 

0.39 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-167382.92 

5318581.00 

742171.38 

22777006.00 

1359469.50 

465309.97 

4441313.50 

9494831. 00 

4811176.50 

27997222.00 

31543754.00 

30051966.00 

3.61 

0.46 

0.59 732360.19 

0.39 18013604.00 

0.78 1407958.90 

1.72 475526.09 

1.38 3640663.30 

0.51 10055673.00 

0.47 4993515.00 

0.39 20883300.00 

0.79 23533162.00 

0.73 22278996.00 

RSD (%) 

1. 95 

54.42 

2.49 

1. 59 

12.31 

9.17 

17.38 

7.43 

2.95 

4.31 

3.44 

2.06 

1.19 

9.24 

6.51 

1.44 

5.60 

4.27 

3.28 

2.07 

2.03 

1. 04 

4.88 

3.70 

4.40 

3.79 

5.68 

2.96 

1. 90 

5.17 

1. 94 

1.35 

Rec(%) 

189.9 

95.1 

101. 3 

126.4 

96.6 

97.9 

122.0 

94.4 

96.3 

134.1 

134.0 

134.9 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

QC Range (%) Flag 

70 - 120 IS fai 

70 - 120 

70 - 120 

70 - 120 IS fai 

70 - 120 

70 

70 

70 

70 

70 

70 -

70 -

120 

120 IS fai 

120 

120 

120 IS fai 

120 IS fai 

120 IS fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

:Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/2711210:28 PM 

Pass 

Fail 

:Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
31

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-5 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 lEAD (PB) 

Metals Analysis 

Result PQl Units 

0.39 0.2 ug/l 

0.35 0.2 ug/l 

0.36 0.2 ug/l 

0.35 0.2 ug/l 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67408 

Prep Date Analysis Date 

09/21/12 

09/21/12 

09/21/12 

09/27/12 

09/27/12 

09/27/12 

09/21/12 09/27/12 

200.8 SELENIUM (SE) 0.50 0.2 ug/l 09/21/12 09/27/12 

__ ~~9_·~ ______________ ~_Ij_~_~!:~~~_Q~~) ________________ _______________________ 9:~? _______________________ ~:~ ________________ ~g!_~ ________ 9_~!~1!_~2 ___________ ~~~?X!~_~ ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
32

C, \ ICPCHEM\ 1 \DATA\12I26qOO. B\08aSMPL. D\088SMPL. D~ 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I26qOO.B\088SMPL.D\088SMPL.D# 

Sep 27 2012 02,13 am 

NBS 

BLK MDL 0.4-5 

120921A-1638 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3308 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

prep Dil Factor, 

Total Dil Factor, 

1. 00 

1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

0.34 ug/l 

11.92 ug/l 

33.13 ug/l 

25.81 ug/l 

2.06 ug/l 

44.55 ug/l 

-94.87 ug/l 

0.36 ug/l 

0.36ug/l 

0.36 ug/l 

-1.02 ug/l 

3.38 ug/l 

0.40 ug/l 

0.30ug/l 

0.49 ug/l 

0.47 ug/l 

-2.39 ug/l 

0.39ug/l 

0.50 ug/l 

1.78 ug/l 

0.01 ug/l 

-0.05 ug/l 

0.33 ug/l 

ug/l 

0.17 ug/l 

ug/l 

0.35 ug/l 

-3.09 ug/l 

-3.21 ug/l 

-2.84 ug/l 

0.38 ug/l 

0.30 ug/l 

0.35 ug/l 

ug/l 

ug/l 

0.35 ug/l 

Carr. Cone. 

#VALUE! 

0.34 

11.92 

33.13 

25.81 

2.06 

44.55 

-94.87 

0.36 

0.36 

0.36 

-1. 02 

3.38 

0.40 

0.30 

0.49 

0.47 

-2.39 

0.39 

0.50 

1.78 

0.01 

-0.05 

0.33 

#VALUE! 

0.17 

#VALUE! 

0.35 

-3.09 

-3.21 

-2.84 

0.38 

0.30 

0.35 

#VALUE! 

#VALUE! 

0.35 

RSD(%) High Limit 

o 

2.18 1000 

2.46 1000 

5.87 25000 

5.55 50000 

9.93 20000 

4.18 20000 

3.09 50000 

25.59 1000 

1.09 1000 

2.36 1000 

0.58 1000 

3.03 20000 

1. 88 

19.86 

2.45 

8.09 

2.73 

6.39 

6.08 

5.81 

1292.30 

16.22 

3.24 

3.32 

9.87 

0.36 

1. 58 

0.38 

3.86 

5.91 

3.56 

3.23 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

Rec(%) 

79.2 

75.5 

70.6 

80.3 

72 .9 

72 .5 

84.8 

78.8 

72.9 

87.3 

89.1 

90.4 

QC Range (%) Flag 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-104491.62 

2754044.50 

379776.13 

13653336.00 

691758.75 

245508.00 

2930961.80 

5208871.00 

2663554.30 

19886866.00 

25516102.00 

24830408.00 

ISTD Ref File , 

:Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

2.48 

0.31 

0.46 

1.24 17012292.00 

0.33 949396.31 

0.82 338792.91 

1.59 3456710.80 

0.45 6610579.00 

0.27 3651775.30 

1.17 22769202.00 

1.81 28649686.00 

1.58 27453282.00 

70 120 IS Fai 

70 120 

70 - 120 

70 120 

70 120 

70 

70 

70 -

70 -

70 

70 

70 -

120 

120 

120 

120 

120 

120 

120 

C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

Pass 

Fail 

:Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

,..r'l 

9/27/122:17 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
33

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-5 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.46 

0.40 

0.34 

0.39 

0.44 

POL Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67408 

Prep Date 

09/21/12 

09/21/12 

09/21/12 

09/21/12 

09/21/12 

Analysis Date 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

__ ~~9_·~ ______________ T_Ij!-_~~~~~_C~~) _________________ _____________________ g}? _______________________ Q:~ ________________ ~g!~ ________ 9_~!~~L~~ __________ q~~?X!~_~ __ __ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
34

C, \ICPCHEM\l \DATA\l2I27s00. B\04lSMPL. D\04lSKPL.D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I27S00.B\041SMPL.D\041SMPL.D# 

Sep 27 2012 10,31 pm 

Sample Name, 

Mise Info: 

NBS 

BLK MDL 0.4-5 

120921A-1638 

Vial Number, 

Current Method, 

Calibration File, 

Last Cal Update, 

Sample Type, 

3308 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1. 00 

1. 00 

QC Blements 

Element Conc. Carr. Cone. 

#VALUE! 

0.43 

0.04 

59.30 

28.64 

2.82 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.43 ug/l 

0.04 ug/l 

59.30 ug/l 

28.64 ug/l 

2.82 ug/l 

45.84 ug/l 

10.85 ug/l 

0.36ug/l 

0.48 ug/l 

0.34 ug/l 

0.45 ug/l 

7.75 ug/l 

0.41 ug/l 

0.43 ug/l 

0.38 ug/l 

0.37 ug/l 

1. 03 ug/l 

0.46 ug/l 

0.44 ug/l 

2.35 ug/l 

0.44 ug/l 

0.37 ug/l 

0.25 ug/l 

ug/l 

0.18 ug/l 

ug/l 

0.40ug/l 

0.27 ug/l 

0.33 ug/l 

0.25 ug/l 

0.38 ug/l 

0.42 ug/l 

0.37 ug/l 

ug/l 

ug/l 

0.39 ug/l 

45.84 

10.85 

0.36 

0.48 

0.34 

0.45 

7.75 

0.41 

o .43 

0.38 

0.37 

1.03 

0.46 

0.44 

2.35 

0.44 

0.37 

0.25 

#VALUE! 

0.18 

#VALUE! 

0.40 

0.27 

0.33 

0.25 

0.38 

0.42 

0.37 

#VALUE! 

#VALUE! 

0.39 

ISTD B1ements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

732360.19 

Li -172695.88 1.89 

45 Sc 5487221.00 3.62 

45 Sc 728612.38 0.71 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

22262300.00 

1384213.10 

462509.19 

4454759.50 

9855620.00 

4800969.50 

27879698.00 

31392670.00 

30001668.00 

0.31 18013604.00 

3.87 1407958.90 

0.82 475526.09 

0.99 3640663.30 

4.29 10055673.00 

0.43 4993515.00 

0.69 20883300.00 

1.40 23533162.00 

0.78 22278996.00 

RSD(%) High Limit 

o 2.62 1000 

66.93 1000 

1.55 25000 

3.00 50000 

19.13 20000 

1.26 20000 

35.16 50000 

25.82 1000 

7.26 1000 

1.49 1000 

5.15 1000 

1.28 20000 

5.22 

5.51 

2.51 

7.12 

0.19 

5.65 

6.62 

1. 88 

6.15 

1.75 

6.50 

3.28 

2.47 

3.96 

4.05 

4.10 

2.81 

3.56 

1.15 

0.21 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

Rec(%) 

195.9 

98.2 

99.5 

123.6 

98.3 

97.3 

122.4 

QC Range (%) Flag 

98.0 

96 .1 

133.5 

133.4 

134.7 

70 - 120 IS Fai 

70 120 

70 120 

70 120 IS fai 

70 - 120 

70 - 120 

70 - 120 IS Fai 

70 120 

70 - 120 

70 120 IS Fai 

70 120 IS fai 

70 120 IS fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

o :Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 10:35 PM 

Pass 

Fail 

o ,Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
35

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-6 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.39 

0.37 

0.38 

0.36 

0.51 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67409 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 10/011125:01:18 PM 
36

C, \ICPCHEM\l \OATA\12I26qOO. B\OB9SMPL. O\OB9SMPL.O# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

vial Number: 

C,\ICPCHEM\1\DATA\12I26qOO.B\089SMPL.D\089SMPL.D# 

Sep 27 2012 02,20 am 

NBS 

BLK MDL 0.4-6 

120921A-1638 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3309 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep·26 2012 05,18 pm 

Sample 

Prep Oil Factor; 

Total Oil Factor, 

1.00 

1.00 

QC Elements 

Element Cone. Carr. Cone. 

7 (Li) #VALUE! 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.34 ug/l 

12.26 ug/l 

27.19 ug/l 

24.50 ug/l 

2.56 ug/l 

52.40 ug/l 

-96.83 ug/l 

0.43 ug/l 

0.38 ug/l 

0.38 ug/l 

-1. 05 ug/l 

3.43 ug/l 

0.41 ug/l 

0.31 ug/l 

0.51 ug/l 

0.47 ug/l 

-1. 52 ug/l 

0.39 ug/l 

0.51 ug/l 

1.60 ug/l 

-0.08 ug/l 

-0.03 ug/l 

0.34 ug/l 

ug/l 

0.17 ug/l 

ug/l 

0.37 ug/l 

-3.11 ug/l 

-3.27 ug/l 

-2.85 ug/l 

0.38 ug/l 

0.32 ug/l 

0.37 ug/l 

ug/l 

ug/l 

0.36 ug/l 

0.34 

12.26 

27.19 

24.50 

2.56 

52.40 

- 96 . 83 

0.43 

0.38 

0.38 

-1. 05 

3.43 

0.41 

0.31 

0.51 

0.47 

-1.52 

0.39 

0.51 

1.60 

-0.08 

-0.03 

0.34 

#VALUE! 

0.17 

#VALUE! 

0.37 

-3.11 

-3.27 

-2.85 

0.38 

0.32 

0.37 

#VALUE! 

#VALUE! 

0.36 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

Li -99843.95 1.49 -131996.50 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

2758808.50 

380028.69 

13325853.00 

689633.63 

246202.89 

2886170.00 

5191213.00 

2646496.30 

19773904.00 

25146660.00 

24375834.00 

0.36 3646344.80 

1.82 537987.94 

3.88 17012292.00 

0.67 949396.31 

0.78 338792.91 

2.97 3456710.80 

0.89 6610579.00 

0.40 3651775.30 

4.74 22769202.00 

3.40 28649686.00 

3.60 27453282.00 

RSD(%) High Limit 

o 8.41 1000 

2.64 1000 

4.81 25000 

1.75 50000 

25.22 20000 

3.84 20000 

1.50 50000 

21. 57 1000 

8.12 1000 

1.88 1000 

1.16 1000 

4.00 20000 

2.14 

12.11 

1. 76 

6.23 

6.08 

10.91 

5.15 

15.01 

42.20 

45.74 

4.84 

6.47 

9.54 

0.26 

0.74 

0.72 

4.07 

12.57 

3.30 

6.39 

Rec( %) 

75.6 

75.7 

70.6 

78.3 

72 .6 

72.7 

83.5 

78.5 

72.5 

86.8 

87.8 

88.8 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range (%) 

70 120 

70 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 120 

Flag 

Flag 

IS Fai tJ T 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 2:24 AM 

Pass 

Fail 

:Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
37

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-6 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.46 

0.40 

0.37 

0.39 

0.47 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67409 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

__ ~~~:~ __ . ___________ T_Ij_~_~~~~~_Q~~) _________________ ______________________ ~:~? _________ ...... ______ ._~:~ _______ . ________ ~9!~ ________ ~_~!?~!_~? __________ .Q~{?X{~_~ ____ . 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
38

C, \ICPCHEII\l \DATA\12127.00. B\046SMPL. D\046SMPL. D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C:\ICPCHEM\1\DATA\12I27s00.B\046SMPL.D\046SMPL.D# 

Sep 27 2012 11:04 pm 

NBS 

Sample Name: BLK MDL 0.4 - 6 

Mise Info: 120921A-1638 

Vial Number: 

CUrrent Method, 

Calibration File: 

Last Cal Update: 

3309 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep Dil Factor: 1.00 

Total Dil Factor, 1.00 

QC Elements 

Element Cone. Corr. Cone. 

7 (Li) #VALUEI 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

III Cd 

118 Sn 

118 Sn 

ll8 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.42 ug/l 

-0.18 ug/l 

27.73 ug/l 

27.69 ug/l 

4.59ug/l 

37.02 ug/l 

2.88 ug/l 

0.39 ug/l 

0.47 ug/l 

0.37 ug/l 

0.48 ug/l 

8.46 ug/l 

0.44 ug/l 

0.45 ug/l 

0.40 ug/l 

0.40 ug/l 

2.17 ug/l 

0.46 ug/l 

0.47 ug/l 

2.15 ug/l 

0.47 ug/l 

0.37 ug/l 

0.26 ug/l 

ug/l 

0.19ug/l 

ug/l 

0.40 ug/l 

0.37 ug/l 

0.42 ug/l 

0.29 ug/l 

0.39 ug/l 

0.43 ug/l 

0.37 ug/l 

ug/l 

ug/l 

0.39 ug/l 

0.42 

-0.18 

27.73 

27.69 

4.59 

37.02 

2.88 

0.39 

0.47 

0.37 

0.48 

8.46 

0.44 

0.45 

0.40 

0.40 

2.17 

0.46 

0.47 

2.15 

0.47 

0.37 

0.26 

#VALUEI 

0.19 

#VALUEI 

0.40 

0.37 

0.42 

0.29 

0.39 

0.43 

0.37 

#VALUEI 

#VALUEI 

0.39 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

Li 

45 Sc 

45 SC 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

ll5 In 

ll5 In 

ll5 In 

159 Tb 

165 Ho 

-181708.94 

5032921.00 

708218.94 

22776726.00 

1288200.40 

451280.44 

4525150.50 

9055589.00 

4705553.50 

28881048.00 

33012752.00 

31604992.00 

3.30 

0.46 

1.10 732360.19 

3.88 18013604.00 

0.72 

1.18 

3.87 

1407958.90 

475526.09 

3640663.30 

0.58 10055673.00 

0.25 4993515.00 

4.08 20883300.00 

3.85 23533162.00 

4.90 22278996.00 

RSD(%) 

5.44 

105.32 

2.69 

1. 24 

13.77 

3.51 

189.68 

8.98 

4.15 

3.63 

3.31 

6.96 

2.17 

0.42 

2.54 

2.59 

5.05 

2.46 

6.22 

3.95 

5.00 

4.66 

6.86 

4.90 

7.93 

6.13 

6.60 

8.06 

5.64 

6.53 

2.80 

4.23 

Rec (%) 

206.2 

90.0 

96.7 

126.4 

91. 5 

94.9 

124.3 

90.1 

94.2 

138.3 

140.3 

141.9 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

QC Range (%) Flag 

70 - 120 IS Fai 

70 120 

70 120 

70 120 IS Fai 

70 120 

70 120 

70 120 IS Fai 

70 

70 

70 -

70 

70 

120 

120 

120 IS Fai 

120 IS Fai 

120 IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 11 :08 PM 

Pass 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
39

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: RW-7 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

0.44 

0.40 

0.34 

0.39 

0.46 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67410 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

.. ~~~:~ ....... _._ ... _T_Ij_~.~~!~~.Q~!-)._._._._ ... _._ .... _ .. _._._ .. _ ... _ ..__ ._~:~? _______________ ._ ... _._~:~ __ _____________ .~9!~_ .. ___ .. ~.~t~~!.~?_ ..... _____ q~~?X~~.?. __ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
40

C. \ICPCIIEM\l \DATA\12126qOO .B\090SMPL. D\090SMPL .D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I26qOO.B\090SMPL.D\090SMPL.Dn 

Sep 27 2012 02,27 am 

NBS 

Sample Name: BLK MDL O. 4 - 7 

Mise Info: 120921A-1638 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3310 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1.00 

1. 00 

QC Blements 

Element Cone. Carr. Cone. 

7 (Li) nVALUE! 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.33 ug/l 

12.13 ug/l 

24.74 ug/l 

23.68 ug/l 

1. 06 ug/l 

41.07 ug/l 

-101.50 ug/l 

0.31 ug/l 

0.36 ug/l 

0.38 ug/l 

-1. 01 ug/l 

3.44 ug/l 

0.37 ug/l 

0.27ug/l 

0.47 ug/l 

0.48 ug/l 

-2.43 ug/l 

0.41 ug/l 

0.50 ug/l 

2.05 ug/l 

-0.09 ug/l 

-0.04 ug/l 

0.33 ug/l 

ug/l 

0.17 ug/l 

ug/l 

0.37 ug/l 

-3.13 ug/l 

-3.28 ug/l 

-2.89 ug/l 

0.35 ug/l 

0.30 ug/l 

0.35 ug/l 

ug/l 

ug/l 

0.34 ug/l 

0.33 

12.13 

24.74 

23.68 

1. 06 

41.07 

-101.50 

0.31 

0.36 

0.38 

-1. 01 

3.44 

0.37 

0.27 

0.47 

0.48 

-2.43 

0.41 

0.50 

2.05 

-0.09 

-0.04 

0.33 

nVALUE! 

0.17 

nVALUE! 

0.37 

-3.13 

-3.28 

-2.89 

0.35 

0.30 

0.35 

nVALUEI 

nVALUE! 

0.34 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996 .50 

3646344.80 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-104710.40 

2768963.30 

382155.50 

13295464.00 

693991.00 

242890.73 

2856965.00 

5179731.00 

2617901.80 

19577700.00 

24970244.00 

24356580.00 

2.82 

1. 09 

0.96 537987.94 

o . 08 17012292.00 

1. 47 

0.79 

0.06 

949396.31 

338792.91 

3456710.80 

0.45 6610579.00 

1.15 3651775.30 

1.49 22769202.00 

1.32 28649686.00 

0.96 27453282.00 

RSD (%) 

1.12 

3.61 

2.72 

3.26 

16.50 

11.69 

2.96 

21. 62 

1. 95 

16.78 

6.97 

10.73 

4.50 

11.47 

0.86 

6.22 

2.49 

12.47 

4.64 

19.84 

13 .30 

11.44 

1. 93 

5.48 

2.51 

0.73 

0.62 

0.20 

2.33 

3.59 

2.65 

1.92 

Rec(%) 

79.3 

75.9 

71. 0 

78.2 

73.1 

71.7 

82.6 

78.4 

71.7 

86.0 

87.2 

88.7 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

nnnnnnn 500 

nnnnnnn 1000 

nnnnnnn 

nnnnnnn 1000 

1000 

1000 

1000 

nnnnnnn 

nnnnnnn 1000 

QC Range(%) 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 -

70 -

70 

70 

70 -

120 

120 

120 

120 

120 

Flag 

Flag 

IS Fai ",-r 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

o :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271122:31 AM 

Pass 

Fail 

o ,Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHBM\1\rpttmp\Samp1e.qct Page 1 of 1 
41

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MOL Study 

Sample 10: RW-7 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

LEAD (PB) 

Metals Analysis 

Result 

0.41 

0.37 

0.38 

0.34 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67410 

Prep Date Analysis Date 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

09/21/12 09/27/12 

200.8 SELENIUM (SE) 0.50 0.2 ug/L 09/21/12 09/27/12 

__ ~Q9:~ ______________ T_Ij_~_~~~~~_r~~1 _______________________________________ 9:~? ___________ . __ . __ . ____ .Q:~_. __________ . ___ ~9!~ ________ 9.~!?~!.~? ____ . __ . __ 9~~?X~~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
42

C, \ICPCHEM\1\OATA\12I27.00. 0\0475MPL. 0\0475MPL .0# 

Sample QC Report 

Data File: 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I27s00.B\047SMPL.D\047SMPL.D# 

Sep 27 2012 11,11 pm 

NBS 

BLK MDL 0.4-7 

120921A-1638 

Sample Name, 

Mise Info: 

vial Number: 

Current Method:' 

Calibration File: 

Last Cal Update, 

Sample Type, 

Prep oil Factor: 

3310 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

1. 00 

Total Dil Factor, 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Conc. 

ug/l 

0.44 ug/l 

-0.18 ug/l 

28.83 ug/l 

29.62 ug/l 

3.53 ug/l 

36.50 ug/l 

10.10 ug/l 

0.40 ug/l 

0.45 ug/l 

0.34 ug/l 

0.45 ug/l 

7.76 ug/l 

0.40 ug/l 

0.39 ug/l 

0.38 ug/l 

0.37 ug/l 

0.94 ug/l 

0.44 ug/l 

0.46 ug/l 

2.05 ug/l 

0.48 ug/l 

0.37 ug/l 

0.25 ug/l 

ug/l 

0.19 ug/l 

ug/l 

0.40 ug/l 

0.34 ug/l 

0.40 ug/l 

0.28ug/1 

0.39 ug/l 

0.41 ug/l 

0.37 ug/l 

ug/l 

ug/l 

0.39 ug/l 

Carr. Conc. 

#VALUE! 

0.44 

-0.18 

28.83 

29.62 

3.53 

36.50 

10.10 

0.40 

0.45 

0.34 

0.45 

7.76 

0.40 

0.39 

0.38 

0.37 

0.94 

0.44 

0.46 

2.05 

0.48 

0.37 

0.25 

#VALUE! 

0.19 

#VALUE! 

0.40 

0.34 

0.40 

0.28 

0.39 

0.41 

0.37 

#VALUE! 

#VALUE! 

0.39 

Element CPS Mean RSD(%) Ref Value 

Li -170084.17 

45 Sc 4968832.50 

45 Sc 709009.69 

45 Sc 21708042.00 

1273538.40 

453147.94 

4370091.00 

9076215.00 

4720906.00 

5.13 -88139.43 

RSD(%) High Limit 

o 

4.84 1000 

25.76 1000 

4.22 25000 

4.11 50000 

16.88 20000 

8.25 20000 

24.72 50000 

24.13 1000 

1.98 1000 

2.58 1000 

3.98 1000 

2.08 20000 

1.29 1000 

3.13 

5.25 

6.63 

2.39 

3.63 

8.29 

4.20 

2.01 

1. 04 

2.93 

4.06 

4.51 

1. 66 

8.62 

0.82 

0.83 

2.46 

0.57 

1. 23 

Rec(%) 

193.0 

88.9 

96.8 

120.5 

90.5 

95.3 

120.0 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

70 - 120 

70 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

Flag 

Flag 

IS fai 

IS Fai 

IS Fai 

IS Fai 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

27684634.00 

31795818.00 

30462428.00 

0.79 5590061.50 

0.79 732360.19 

0.75 18013604.00 

1.38 1407958.90 

1.95 475526.09 

0.46 3640663.30 

0.88 10055673.00 

1.33 4993515.00 

0.50 20883300.00 

0.33 23533162.00 

1.24 22278996.00 

90.3 

94.5 

132.6 

135.1 

136.7 

70 

70 

120 IS Fai 

120 IS Fai 

ISTD Ref File , 

:Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

912711211:15 PM 

C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

Pass 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
43

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-1 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.5 

0.46 

1.1 

2.0 

7.9 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67411 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
44

C, \ICPCHEM\l \OATA\12I26QOO. s\069SMPL. O\069SMPL. oN 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12126qOO.B\069SMPL.D\069SMPL.D# 

Sep 27 2012 12:07 am 

Operator: NBS 

Sample Name: 1638 MDL-0.25-1 

Mise Info: 120920A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3209 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.33 ug/l 

31.71 ug/l 

943100.00 ug/l 

961700.00 ug/l 

14.04 ug/l 

54.12 ug/l 

1987000.00 ug/l 

0.49 ug/l 

0.67 ug/l 

1.15 ug/l 

-0.57 ug/l 

14.64 ug/l 

O.71ug/l 

4.18 ug/l 

0.69 ug/l 

1.09ug/l 

0.09 ug/l 

1. 46 ug/l 

7.91 ug/l 

11.37 ug/l 

125.00 ug/l 

115.60 ug/l 

0.60 ug/l 

ug/l 

0.28 ug/l 

ug/l 

0.46 ug/l 

-2.00 ug/l 

-2.18 ug/l 

-2.22 ug/l 

2.42 ug/l 

2.75 ug/l 

0.40 ug/l 

ug/l 

ug/l 

2.01 ug/l 

ISTD Elements 

Carr. Cone. 

#VALUE! 

0.33 

31.71 

943100.00 

961700.00 

14 .04 

54.12 

1987000.00 

0.49 

0.67 

1.15 

-0.57 

14.64 

0.71 

4.18 

0.69 

1. 09 

0.09 

1. 46 

7.91 

11.37 

125.00 

115.60 

0.60 

#VALUE! 

0.28 

#VALUE! 

0.46 

-2.00 

-2.18 

-2.22 

2.42 

2.75 

0.40 

#VALUE! 

#VALUE! 

2.01 

RSD(%) 

3.25 

1. 83 

0.81 

0.25 

2.52 

7.61 

0.41 

24.01 

2.95 

1.14 

7.70 

0.84 

1. 60 

1. 54 

0.88 

0.67 

15.48 

0.75 

0.60 

4.04 

0.63 

1. 73 

2.16 

1. 79 

10.65 

2.19 

2.17 

0.42 

1.54 

1. 70 

0.88 

0.89 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

>Cal 

:>Cal 

,Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Rec(%) 

68.5 

99.0 

96.4 

89.7 

84.9 

82.6 

80.6 

86.5 

76.1 

73.1 

72 .4 

72.5 

QC Range (%) Flag 

6 Li -90381.13 3.39 70 120 IS Fai ~ 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3608444.30 

518700.31 

15264073.00 

806354.31 

279748.41 

2787681.80 

5719383.00 

2779431.80 

16647595.00 

20738282.00 

19912326.00 

ISTD Ref File : 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/2711212:11 AM 

1. 34 

0.40 537987.94 

0.27 17012292.00 

1.06 949396.31 

2.32 338792.91 

0.25 3456710.80 

0.92 6610579.00 

1.03 3651775.30 

0.64 22769202.00 

0.82 28649686.00 

0.47 27453282.00 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 

70 -

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
45

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-1 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

Metals Analysis 

Result 

1.6 

0.52 

1.1 

PQL 

0.2 

0.2 

0.2 

Units 

ug/L 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67411 

Prep Date Analysis Date 

09/20/12 

09/20/12 

09/20/12 

09/27/12 

09/27/12 

09/27/12 

200.8 LEAD (PB) 2.4 0.2 ug/L 09/20/12 09/27/12 

200.8 SELENIUM (SE) 1.1 0.2 ug/L 09/20/12 09/27/12 

._~~9_·~ ____ . _________ T_fj~_~~~~~_Q~~) _________________ ______________________ 9:~? _______________________ ~:? __ ______________ !-!9!~ ________ 9_~!~9!_~? __________ g~~?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
46

C, \ICPCHEM\l \DATA\12I27.00. B\025SMPL. D\025SMPL.D# 

Sample OC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name: 

C,\ICPCHEM\1\DATA\12I27S00.B\025SMPL.D\025SMPL.Dn 

Sep 27 2012 08,44 pm 

NBS 

1638 MDL-0.25-1 

Mise Info: 120920A-1638 

Vial Number: 

Current Method, 

Calibration File, 

Last Cal Update, 

Sample Type, 

3209 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

Prep Dil Factor, 1. 00 

Total Dil Factor, 1.00 

QC Blements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.45 ug/l 

3.62 ug/l 

1013000.00 ug/l 

1041000.00 ug/l 

19.00 ug/l 

52.61 ug/l 

2257000.00 ug/l 

0.62 ug/l 

0.73 ug/l 

1.13 ug/l 

0.79 ug/l 

22.16 ug/l 

0.70 ug/l 

4.41 ug/l 

0.60 ug/l 

0.91 ug/l 

4.40 ug/l 

1.55 ug/l 

1.07 ug/l 

3.28 ug/l 

144.00 ug/l 

131.40 ug/l 

0.63 ug/l 

ug/l 

0.32 ug/l 

ug/l 

0.52 ug/l 

1.53 ug/l 

1. 45 ug/l 

0.98 ug/l 

4.13 ug/l 

3.03 ug/l 

0.46 ug/l 

ug/l 

ug/l 

2.35ug/l 

ISTD Blements 

Element CPS Mean RSD(%) 

Carr. Cone. 

nVALUE! 

0.45 

3.62 

1013000.00 

1041000.00 

19.00 

52.61 

2257000.00 

0.62 

0.73 

1.13 

0.79 

22.16 

0.70 

4.41 

0.60 

0.91 

4.40 

1.55 

1. 07 

3.28 

144.00 

131.40 

0.63 

nVALUE! 

0.32 

nVALUE! 

0.52 

1. 53 

1.45 

0.98 

4.13 

3.03 

0.46 

nVALUE! 

nVALUE! 

2.35 

RSD(%) 

1. 76 

4.52 

1. 27 

0.59 

3.11 

4.84 

0.50 

6.03 

1. 96 

2.72 

4.35 

0.65 

0.58 

0.83 

2.14 

1. 46 

2.03 

1.15 

2.75 

6.87 

0.27 

1.12 

3.48 

1.56 

5.38 

1. 80 

3.24 

2.62 

3.02 

0.40 

2.04 

1. 06 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

nnnnnnn 500 

nnnnnnn 1000 

nnnnnnn 

nnnnnnn 1000 

1000 

1000 

1000 

nnnnnnn 

nnnnnnn 1000 

QC Range (%) 

6 Li -134885.36 4.47 

45· Sc 5604948.50 0.40 

Ref Value 

-88139.43 

5590061.50 

Rec(%) 

153.0 

100.3 

119.7 

114.1 

70 120 

70 - 120 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

876485.56 

20558242.00 

1212428.40 

470575.81 

3495994.30 

8120078.00 

4307361.50 

18058296.00 

18906474.00 

17688424.00 

1.74 732360.19 

0.40 18013604.00 

1.09 l407958.90 

1.71 475526.09 

0.61 3640663.30 

0.08 10055673.00 

1.004993515.00 

0.67 20883300.00 

0.35 23533162.00 

0.58 22278996.00 

86.1 

99.0 

96.0 

80.8 

86.3 

86.5 

80.3 

79.4 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12127S00.B\004CALB.D\004CALB.Dn 

:Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27/128:47 PM 

Fail 

Fail 

:Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHBM\l\rpttmp\Sample.qct Page 1 of 1 
47

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-2 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

Metals Analysis 

Result 

1.4 

0.44 

1.1 

POL 

0.2 

0.2 

0.2 

Units 

ug/L 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67412 

Prep Date Analysis Date 

09/20/12 

09/20/12 

09/20/12 

09/27/12 

09/27/12 

09/27/12 

200.8 LEAD (PB) 2.0 0.2 ug/L 09/20/12 09/27/12 

200.8 SELENIUM (SE) 5.6 0.2 ug/L 09/20/12 09/27/12 

.. ~~9:~ ....... _ ...... "!".~.~.~~~~~J~~)._._._ ... _ .. _. __ ._._ ...... _ .... _ .. _ .... 9:~~. __ . ___ .......... _ ..... ~:? ............... ~9!~ ........ 9.~!?9!.~? .......... 9~~?X(~.~ __ ._. 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
48

C, \ICPCHEM\l \DATA\12I26qOO. B\OHSMPL. D\OHSHPL. D~ 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I26qOO.B\074SMPL.D\074SMPL.D# 

Sep 27 2012 12,40 am 

NBS 

1638 MDL-0.25-2 

120920A-1638 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3210 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1. 00 

1. 00 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.34 ug/l 

25.72 ug/l 

890600.00 ug/l 

910300.00 ug/l 

13.64 ug/l 

54.37 ug/l 

1886000.00 ug/l 

0.49 ug/l 

0.56 ug/l 

1.09 ug/l 

-0.72 ug/l 

27.26 ug/l 

0.68 ug/l 

2.34 ug/l 

0.67 ug/l 

1.03 ug/l 

-0.95 ug/l 

1.37 ug/l 

5.64 ug/l 

9.46 ug/l 

119.30 ug/l 

118.10 ug/l 

0.59 ug/l 

ug/l 

0.29 ug/l 

ug/l 

0.44 ug/l 

-2.31 ug/l 

-2.49 ug/l 

-2.38 ug/l 

2.01 ug/l 

2.81 ug/l 

0.39 ug/l 

ug/l 

ug/l 

2.01 ug/l 

ISTD Elements 

Element CPS Mean RSD(%) 

Carr. Cone. 

#VALUE! 

0.34 

25.72 

890600.00 

910300.00 

13 .64 

54.37 

1886000.00 

0.49 

0.56 

1.09 

-0.72 

27.26 

0.68 

2.34 

0.67 

1. 03 

-0.95 

1.37 

5.64 

9.46 

119.30 

118.10 

0.59 

#VALUE! 

0.29 

#VALUE! 

0.44 

-2.31 

-2.49 

-2.38 

2.01 

2.81 

0.39 

#VALUE! 

#VALUEl 

2.01 

RSD(%) High Limit 

o 21.99 1000 

16.42 1000 

0.38 25000 

0.32 50000 

2.14 20000 

6.76 20000 

0.40 50000 

8.25 1000 

0.22 1000 

2.48 1000 

4.13 1000 

0.54 20000 

2.42 

1. 96 

5.28 

2.44 

2.45 

3.02 

2.04 

1. 68 

0.46 

19.26 

18.99 

18.29 

15.63 

1.19 

2.70 

5.28 

19.01 

21.17 

18.25 

19.97 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range (%) 

6 Li -89182.19 15.79 

45 Sc 3628762.00 0.21 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

511291.09 

14300611.00 

807285.25 

278891.25 

2708812.50 

5715730.00 

2736030.00 

0.40 

Ref Value 

-131996.50 

3646344.80 

537987.94 

Rec (%) 

67.6 

99.5 

95.0 

84.1 

85.0 

82.3 

78.4 

86.5 

74.9 

69.6 

68.7 

68.8 

70 - 120 

70 - 120 

70 - 120 

15838820.00 

19674946.00 

18891008.00 

16.25 17012292.00 

0.26 949396.31 

0.41 

12.20 

0.56 

0.34 

338792.91 

3456710.80 

6610579.00 

3651775.30 

16.56 22769202.00 

17.00 28649686.00 

16.78 27453282.00 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

IS Fai '7 Oil... IS Fai 

IS Fai rJ\' 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures 

4 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 12:44 AM 

Fail 

Fail 

o :Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C,\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
49

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-2 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.5 

0.51 

1.1 

2.2 

PQL 

0.2 

0.2 

0.2 

0.2 

0.94 0.2 

Units 

ug/L 

ug/L 

ug/L 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67412 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

.. ~~9:~ .............. T.Ij.~.~!:~~~.{~~) ....................................... 9:~? ..................... ~:? ................ ~9!!: ........ 9.~!?:9!.~? .......... 9~~?X~~.? ... . 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
50

C, \ICPCHEK\l \OATA\12I27.00. B\026SIlP~. O\026SIIP~. 0# 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27s00.B\026SMPL.D\026SMPL.DU 

Sep 27 2012 08:50 pm 

Operator: NBS 

Sample Name: 1638 MDL-0.25-2 

Mise Info: 120920A-1638 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

3210 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.41 ug/l 

3.10 ug/l 

960700.00 ug/l 

978300.00 ug/l 

16.86 ug/l 

52.17 ug/l 

2161000.00 ug/l 

0.55 ug/l 

0.70 ug/l 

1.12 ug/l 

0.77 ug/l 

34.45 ug/l 

o . 70 ug/l 

2.70 ug/l 

0.56 ug/l 

0.88 ug/l 

2.73 ug/l 

1.47 ug/l 

0.94 ug/l 

3.45 ug/l 

137.60 ug/l 

123.90 ug/l 

0.55 ug/l 

ug/l 

0.30 ug/l 

ug/l 

0.51 ug/l 

1.00 ug/l 

1.09 ug/l 

0.69 ug/l 

3.55ug/l 

2.93 ug/l 

0.42 ug/l 

ug/l 

ug/l 

2.15 ug/l 

ISTD Blements 

Carr. Cone. 

UVALUE! 

0.41 

3.10 

960700.00 

978300.00 

16.86 

52.17 

2161000.00 

0.55 

0.70 

1.12 

0.77 

34.45 

0.70 

2.70 

0.56 

0.88 

2.73 

1.47 

0.94 

3.45 

137.60 

123.90 

0.55 

UVALUE! 

0.30 

UVALUE! 

0.51 

1. 00 

1. 09 

0.69 

3.55 

2.93 

0.42 

UVALUE! 

UVALUE! 

2.15 

RSD(%) High Limit 

o 

1.50 1000 

3.47 1000 

1. 33 25000 

1.57 50000 

5.29 20000 

3.31 20000 

2.21 50000 

3.51 1000 

3.72 1000 

2.72 1000 

4.20 1000 

1.95 20000 

1.95 1000 

2.06 

3.21 

4.75 

1. 70 

1.10 

0.94 

7.87 

0.44 

1.16 

5.69 

1.19 

7.91 

1. 50 

3.17 

3.12 

0.51 

0.24 

1. 66 

0.72 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

Flag 

,Cal 

,Cal 

,Cal 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

Rec(%) 

146.2 

102.6 

113.9 

113.7 

QC Range(%) Flag 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-128835.28 

5736286.00 

834298.63 

20490146.00 

1247538.10 

449871.63 

3498658.50 

8426690.00 

4174665.50 

18333754.00 

19561808.00 

18245612.00 

1. 25 

1.30 5590061.50 

1.78 732360.19 

0.73 18013604.00 

1.681407958.90 

1.26 475526.09 

0.57 3640663.30 

0.82 10055673.00 

1.06 4993515.00 

0.54 20883300.00 

0.72 23533162.00 

0.98 22278996.00 

88.6 

94.6 

96 .1 

83.8 

83.6 

87.8 

83.1 

81. 9 

70 120 IS fai 

70 - 120 

70 120 

70 120 

70 120 

70 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.DU 

:Element Failures 0 :Max. Number of Failures Allowed 

:ISTD Failures 0 :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9127112 8:54 PM C'\ICPCHEM\l\rptbmp\Sample.qct Page 1 of 1 
51

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-3 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

Metals Analysis 

Result 

1.3 

0.42 

1.1 

POL 

0.2 

0.2 

0.2 

Units 

ug/L 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67413 

Prep Date Analysis Date 

09/20/12 

09/20/12 

09/20/12 

09/27/12 

09/27/12 

09/27/12 

200.8 LEAD (PB) 1.9 0.2 ug/L 09/20/12 09/27/12 

200.8 SELENIUM (SE) 5.7 0.2 ug/L 09/20/12 09/27/12 

_~~9_·~ ______________ ~_1:l_~_~!:~~~_C'~~) _______________________________________ 9:~? _______________________ ~:? __ ______________ ~9!_~ ________ 9_~!?9L~? ___________ Q~~?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
52

C, \ICPCHEM\l \DATA\ 12I26qOO. S\075SHPL. D\075SHPL. DO 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\075SMPL.D\075SMPL.D# 

Sep 27 2012 12:47 am 

Operator: NBS 

Sample Name: 1638 MDL-0.25-3 

Mise Info: 120920A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3211 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1.00 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. Carr. Cone. 

#VALUE! 

0.32 

19.60 

910500.00 

924600.00 

13.54 

64.79 

(Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Ai 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.32 ug/l 

19.60 ug/l 

910500.00 ug/l 

924600.00 ug/l 

13.54 ug/l 

64.79 ug/l 

1926000.00 ug/l 

0.45 ug/l 

0.59 ug/l 

1.14 ug/l 

-0.70 ug/l 

13.71 ug/l 

0.69 ug/l 

7.59 ug/l 

0.69 ug/l 

1.08 ug/l 

0.93 ug/l 

1.31 ug/l 

5.71 ug/l 

11. 01 ug/l 

121.70 ug/l 

111.80 ug/l 

0.53 ug/l 

ug/l 

0.28 ug/l 

ug/l 

0.42 ug/l 

-2.72 ug/l 

-2.65 ug/l 

-2.55 ug/l 

1.74 ug/l 

2.71 ug/l 

0.36 ug/l 

ug/l 

ug/l 

1.90 ug/l 

1926000.00 

0.45 

0.59 

1.14 

-0.70 

13.71 

0.69 

7.59 

0.69 

1. 08 

0.93 

1. 31 

5.71 

11.01 

121.70 

111.80 

0.53 

#VALUE! 

0.28 

#VALUEI 

0.42 

-2.72 

-2.65 

-2.55 

1. 74 

2.71 

0.36 

# VALUE I 

#VALUEI 

1. 90 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

6 Li -89139.98 8.74 -131996.50 

45 Sc 4423724.00 17.42 3646344.80 

45 Sc 497981.81 1.37 537987.94 

45 Sc 15238093.00 0.55 17012292.00 

72 Ge 931605.75 13.14 949396.31 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

273502.31 

2800274.30 

6909247.50 

2661074.00 

16803858.00 

21087884.00 

20193890.00 

2.70 338792.91 

0.53 3456710.80 

17.80 6610579.00 

1.80 3651775.30 

1.12 22769202.00 

0.89 28649686.00 

0.62 27453282.00 

RSD(%) 

0.68 

0.58 

0.58 

0.43 

12.08 

4.18 

0.70 

16.48 

1. 00 

2.40 

5.06 

0.92 

2.81 

1.89 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

4.73 1000 

1.62 1000 

4.05 1000 

1.59 1000 

13.83 1000 

6.38 1000 

0.78 1000 

1.51 1000 

4.18 1000 

####### 

1.59 500 

####### 

7.00 1000 

5.66 ####### 

1. 33 ####### 

0.57 1000 

1.41 1000 

0.90 1000 

1.37 1000 

####### 

####### 

1. 43 1000 

Rec(%) 

67.5 

121. 3 

92.6 

89.6 

98.1 

80.7 

81. 0 

104.5 

72 .9 

73.8 

73.6 

73.6 

QC Range(%) 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

IS Fai 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures :Max. Number of Failures Allowed 

:ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/27112 12:50 AM C:\ICPCHEM\l\rpttrnp\Sample.qct Page 1 of 1 
53

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-3 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

Metals Analysis 

Result PQl Units 

1.5 0.2 ug/L 

0.53 0.2 ug/L 

1.1 0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67413 

Prep Date Analysis Date 

09/20/12 

09/20/12 

09/27/12 

09/27/12 

09/20/12 09/27/12 

200.8 LEAD (PB) 2.2 0.2 ug/L 09/20/12 09/27/12 

200.8 SELENIUM (SE) 0.99 0.2 ug/L 09/20/12 09/27/12 

_~~9_·~ ______________ T_Ij~_~~~~~_Q~~) __________________ _____________________ 9:~~ _______________________ ~·? ___ ____________ ~g!~ ________ 9_~!~9!_~? ___________ q~~?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
54

c: \ICPCIlEM\l \OATA\12I27s00 .B\027SMPL. O\027SMPL. of 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27S00.B\027SMPL.D\027SMPL.D# 

Sep 27 2012 08:57 pm 

Operator: NBS 

Sample Name: 1638 MDL-0.25-3 

Mise Info: 120920A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3211 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element Conc. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.42 ug/l 

2.43 ug/1 

963800.00 ug/l 

984800.00 ug/l 

17.86 ug/l 

63.19 ug/l 

2205000.00 ug/l 

O.71ug/l 

0.75 ug/l 

1.14 ug/l 

0.77 ug/l 

20.98 ug/l 

0.70 ug/l 

7.71ug/l 

0.60 ug/l 

0.97 ug/l 

4.97 ug/l 

1. 52 ug/l 

0.99 ug/l 

3.83 ug/l 

141.50 ug/l 

126.40 ug/l 

0.52 ug/l 

ug/l 

0.31 ug/l 

ug/l 

0.53 ug/l 

0.91 ug/l 

0.95 ug/l 

0.62 ug/l 

3.23 ug/l 

3.01 ug/l 

0.43 ug/l 

ug/l 

ug/l 

2.20 ug/l 

ISTD Elements 

Carr. Cone. 

#VALUEI 

0.42 

2.43 

963800.00 

984800.00 

17.86 

63.19 

2205000.00 

0.71 

0.75 

1.14 

0.77 

20.98 

0.70 

7.71 

0.60 

0.97 

4.97 

1. 52 

0.99 

3.83 

141.50 

126.40 

0.52 

#VALUEI 

0.31 

#VALUEI 

0.53 

0.91 

0.95 

0.62 

3.23 

3.01 

0.43 

#VALUEI 

#VALUEI 

2.20 

RSD(%) High Limit 

a 1.47 1000 

1.14 1000 

0.55 25000 

0.84 50000 

2.37 20000 

3.00 20000 

0.25 50000 

3.67 1000 

3.65 1000 

1.13 1000 

0.78 1000 

0.36 20000 

2.59 

0.74 

0.95 

2.13 

1.10 

2.16 

4.07 

5.25 

0.58 

1.91 

1. 67 

3.14 

4.77 

3.87 

3.01 

0.94 

1. 38 

1. 65 

2.27 

0.84 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

>Cal 

>Cal 

>cal 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

Rec(%) 

140.2 

100.4 

112.1 

112.6 

QC Range (%) Flag 

Li -123561.20 2.59 

45 Sc 

45 Sc 

45 sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

5614797.00 

820963.94 

20275090.00 

1223584.40 

440852.72 

3472048.80 

8208808.50 

4068804.80 

18436316.00 

19359424.00 

18018564.00 

1.34 5590061.50 

1.26 732360.19 

1.13 18013604.00 

0.75 1407958.90 

0.92 475526.09 

0.34 3640663.30 

0.53 10055673.00 

1.01 4993515.00 

1.24 20883300.00 

0.36 23533162.00 

0.19 22278996.00 

86.9 

92.7 

95.4 

81. 6 

81. 5 

88.3 

82.3 

80.9 

70 120 IS Fai 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

ISTD Ref File: C:\ICPCHEM\1\DATA\12127s00.B\004CALB.D\004CALB.D# 

3 :Element Failures :Max. Number of Failures Allowed 

1 :ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/271129:01 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
55

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-4 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.3 

0.45 

1.2 

1.9 

6.8 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67414 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

__ ~Q9_·~ ______________ T_fj_~_~~~l!~_cr~~) ________________ _______________________ 9:~? _______________________ Q:~ ________________ ~9!~ ________ 9_~t?:9!_~? ___________ 9~~?X( ~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
56

c: \ICPCIIEM\l \DATA\12I26qOO. B\076SMPL. D\076SMPL.DI 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\076SMPL.D\076SMPL.D# 

Sep 27 2012 12:53 am 

Operator: NBS 

Sample Name: 1638 MDL-0.25-4 

Mise Info: 120920A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3212 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1.00 

QC Element. 

Element 

(Li) 

Cone. 

ug/l 

0.29 ug/l 

18.48 ug/l 

897400.00 ug/l 

908600.00 ug/l 

12.90 ug/l 

68.26 ug/l 

Corr. Cone. 

#VALUE! 

0.29 

18.48 

897400.00 

908600.00 

12.90 

68.26 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

1902000.00 ug/l 

0.55 ug/l 

0.63 ug/l 

1.15 ug/l 

-0.74 ug/l 

13.97 ug/l 

0.70 ug/l 

4.07 ug/l 

0.65 ug/l 

1.04 ug/l 

0.40 ug/l 

1.34 ug/l 

6.82 ug/l 

10.40 ug/l 

120.80 ug/l 

110.40 ug/l 

0.51 ug/l 

ug/l 

0.28 ug/l 

ug/l 

0.45ug/1 

-2.70 ug/l 

-2.83 ug/l 

-2.61 ug/l 

1.68 ug/l 

2.71 ug/l 

0.37 ug/l 

ug/l 

ug/l 

1. 92 ug/l 

1902000.00 

0.55 

0.63 

1.15 

- 0.74 

13.97 

0.70 

4.07 

0.65 

1. 04 

0.40 

1. 34 

6.82 

10.40 

120.80 

110.40 

0.51 

#VALUE! 

0.28 

#VALUE! 

0.45 

-2.70 

-2.83 

-2.61 

1. 68 

2.71 

0.37 

#VALUE! 

#VALUE! 

1. 92 

ISTD Element. 

Element CPS Mean RSD (%) Ref Value 

Li -131996.50 

45 Sc 

45 Sc 

45 SC 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-80795.81 

3731903.00 

501592.44 

14162061.00 

831037.63 

275335.19 

2626549.30 

5791835.00 

2694596.30 

15886792.00 

20053700.00 

19337210.00 

6.67 

1.24 3646344.80 

0.56 537987.94 

2.19 17012292.00 

1. 02 

0.41 

949396.31 

338792.91 

1.60 3456710.80 

0.18 6610579.00 

o .59 3651775.30 

1.51 22769202.00 

1.40 28649686.00 

1.61 27453282.00 

RSD(%) 

3.66 

7.82 

0.16 

0.87 

6.04 

7.28 

0.62 

11.26 

2.20 

0.77 

0.61 

2.23 

3.65 

1. 98 

1. 94 

2.30 

26.53 

2.32 

2.17 

3.71 

1. 00 

0.58 

2.57 

3.12 

6.63 

1. 23 

1.53 

0.45 

2.58 

0.42 

0.68 

0.77 

Rec(%) 

61. 2 

102.3 

93.2 

83.2 

87.5 

81.3 

76.0 

87.6 

73.8 

69.8 

70.0 

70.4 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range (%) 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 -

70 -

70 

70 -

70 -

70 -

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

,Cal 

>Cal 

,Cal 

Flag 

IS Fai 

IS Fai 

IS fai 

ISTD Ref File: C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D# 

:Element Failures 0 :Max. Number of Failures Allowed 

: ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

,J\ 

9127/12 12:57 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
57

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-4 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

Metals Analysis 

Result 

1.5 

0.51 

1.1 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67414 

Prep Date 

09/20/12 

09/20/12 

09/20/12 

Analysis Date 

09/27/12 

09/27/12 

09/27/12 

200.8 LEAD (PB) 2.1 0.2 ug/L 09/20/12 09/27/12 

200.8 SELENIUM (SE) 0.98 0.2 ug/L 09/20/12 09/27/12 

.. ~~9:~ .............. T.I:I~.~~~~~.Q~~) ...................................... g:~~ ....................... ~~? ............... ~9!~ ........ 9.~!~9!.~? .......... q~~?X!~_~ .... . 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 10/011125:03:27 PM 
58

C. \ICPCHEK\l \DATA \12127000. B\Ol2SMPL. D\Ol2SMPL. D# 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27S00.B\032SMPL.D\032SMPL.D# 

Sep 27 2012 09:30 pm 

Operator: NBS 

Sample Name: 1638 MDL-0.25-4 

Mise Info: 120920A-1638 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3212 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep Oil Factor: 1. 00 

Total Oil Factor: 1. 00 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 MIl 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

III Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.44 ug/l 

2.84 ug/l 

930000.00 ug/l 

958400.00 ug/l 

16.82 ug/l 

68.45 ug/l 

2180000.00 ug/l 

0.58 ug/l 

0.74 ug/l 

1.12 ug/l 

0.76 ug/l 

20.34 ug/l 

0.70 ug/l 

4.26 ug/l 

0.54 ug/l 

0.86 ug/l 

4.25 ug/l 

1.48 ug/l 

0.98 ug/l 

4.08 ug/l 

138.40 ug/l 

122.10 ug/l 

0.50 ug/l 

ug/l 

0.30 ug/l 

ug/l 

0.51 ug/l 

0.97 ug/l 

1. 04 ug/l 

0.62 ug/l 

2.62 ug/l 

2.92 ug/l 

0.41 ug/l 

ug/l 

ug/l 

2.12 ug/l 

ISTD Elements 

Carr. Cone. 

#VALUEI 

0.44 

2.84 

930000.00 

958400.00 

16.82 

68.45 

2180000.00 

0.58 

0.74 

1.12 

0.76 

20.34 

0.70 

4.26 

0.54 

0.86 

4.25 

1.48 

0.98 

4.08 

138.40 

122.10 

0.50 

#VALUEI 

0.30 

#VALUEI 

0.51 

0.97 

1. 04 

0.62 

2.62 

2.92 

0.41 

#VALUEI 

#VALUEI 

2.12 

RSD(i) 

1. 21 

5.26 

1.30 

1. 21 

5.86 

2.73 

1. 35 

17.80 

2.32 

0.83 

4.73 

1.10 

1.91 

1. 30 

2.18 

1. 68 

3.28 

2.70 

12.95 

0.43 

0.89 

1. 42 

3.00 

4.15 

3.12 

20.53 

4.73 

2.10 

2.71 

1.57 

1. 24 

1.24 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

>Cal 

>Cal 

>Cal 

Element CPS Mean RSD(i) Ref Value 

-88139.43 

5590061.50 

Rec (i) 

146.4 

93.2 

105.7 

111.6 

83.2 

88.6 

94.7 

76.8 

78.4 

88.8 

84.4 

83.2 

QC Range (i) Flag 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-129059.02 2.45 

5208575.50 13.65 

70 120 IS Fai 

70 120 

773885.31 

20102064.00 

1171146.40 

421478.94 

3447134.50 

7718151. 50 

3917239.80 

18534298.00 

19872700.00 

18526108.00 

ISTD Ref File : 

3 :Element Failures 

: I STD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 9:34 PM 

2.96 732360.19 

1.06 18013604.00 

6.10 1407958.90 

1. 95 475526.09 

0.903640663.30 

12.57 10055673.00 

2.14 4993515.00 

0.81 20883300.00 

0.96 23533162.00 

0.45 22278996.00 

70 -

70 -

70 

70 -

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
59

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MOL Study 

Sample 10: FGO-5 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.3 

0.47 

1.1 

2.0 

6.3 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67415 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

.. ~Q9:~ .............. TtI.~~~~~~.Q~~) ....................................... 9:~9 ....................... Q:~ ................ ~9!~ ........ 9.~!~9!.~? ......... Q~~?X!~.? .... . 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
60

C, \ICPCHEM\l \DATA\12126qOO. B\077SKPL.D\077SKPL. D~ 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\077SMPL.D\077SMPL.D# 

Sep 27 2012 01:00 am 

Operator: NBS 

Sample Name: 1638 MDL-0.25-5 

Mise Info: 120920A-1638 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

3301 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: 

prep Dil Factor: 

Sample 

1. 00 

Total Dil Factor: 1.00 

QC Elements 

Element Cone. 

(Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 cu 

65 CU 

66 zn 75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.33 ug/l 

17.13 ug/l 

891800.00 ug/l 

908300.00 ug/l 

14.48ug/l 

67.26 ug/l 

1930000.00 ug/l 

0.58 ug/l 

0.62 ug/l 

1.13 ug/l 

-0.78 ug/l 

17.43 ug/l 

0.72 ug/l 

1.91 ug/l 

0.64 ug/l 

1.02 ug/l 

-1.08 ug/l 

1.34 ug/l 

6.32 ug/l 

9.93 ug/l 

123.10 ug/l 

116.40 ug/l 

0.53 ug/l 

ug/l 

0.29ug/l 

ug/l 

0.47 ug/l 

-2.69 ug/l 

-2.86 ug/l 

-2.57 ug/l 

1.72 ug/l 

2.85 ug/l 

0.40 ug/l 

ug/l 

ug/l 

2.05 ug/l 

ISTD Elements 

Element CPS Mean RSD(%) 

Li -68437.67 9.55 

45 Sc 3418180.80 1.82 

1.58 

Cerr. Cone. 

#VALUEI 

0.33 

17.13 

891800.00 

908300.00 

14 .48 

67.26 

1930000.00 

0.58 

0.62 

1.13 

-0.78 

17.43 

0.72 

1.91 

0.64 

1. 02 

-1.08 

1. 34 

6.32 

9.93 

123.10 

116.40 

0.53 

#VALUE! 

0.29 

#VALUE! 

0.47 

-2.69 

-2.86 

-2.57 

1. 72 

2.85 

0.40 

#VALUE! 

#VALUEI 

2.05 

Ref Value 

-131996.50 

3646344.80 

45 Sc 537987.94 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

489458.69 

12373311.00 

769181.13 

269453.91 

2360199.80 

5336500.00 

2624859.50 

5.10 17012292.00 

14227306.00 

18279216.00 

17522862.00 

0.93 949396.31 

0.76 338792.91 

3.23 3456710.80 

0.89 6610579.00 

0.70 3651775.30 

5.04 22769202.00 

4.52 28649686.00 

4.49 27453282.00 

RSD(%) 

2.11 

3.84 

1. 62 

1. 87 

5.61 

8.17 

1. 59 

6.64 

9.78 

2.95 

2.67 

3.11 

2.26 

1. 95 

3.73 

6.46 

12.23 

2.61 

0.89 

3.37 

0.24 

4.13 

2.92 

6.11 

4.11 

1.60 

2.68 

2.66 

4.14 

2.69 

0.94 

4.12 

Rec(%) 

51. 8 

93.7 

91. 0 

72.7 

81. 0 

79.5 

68.3 

80.7 

71. 9 

62.5 

63.8 

63.8 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

70 - 120 

70 - 120 

70 120 

70 

70 

70 

70 

70 

70 

70 -

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

,Cal 

,Cal 

,Cal 

Flag 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

ISTD Ref File, C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures 

5 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

(pc) -11 ... \ i. 

'/' OV-- ~.-rs 

,.1-'1 

9127112 1'04 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
61

Metals Analysis 

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-5 

Sample Collection Date: 08/30/12 

Method Analyte Result 

200.8 ARSENIC (AS) 1.5 

200.8 CADMIUM (CD) 0.49 

200.8 CHROMIUM (CR) 1.1 

200.8 LEAD (PB) 2.0 

200.8 SELENIUM (SE) 0.96 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North T em perance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67415 

Prep Date Analysis Date 

09/20/12 

09/20/12 

09/20/12 

09/20/12 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

09/20/12 09/27/12 

__ ~Q9:~ ______________ T_~_~_~~~~f>J1_Q~~) _________________ ______________________ 9:~9 _______________________ Q:~ __ ______________ ~g!~ ________ 9_~!?9!_~? ___________ Q~~?X!~_~ ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
62

C, \ICPCHEM\l \DATA\12I27s00. S\OJJSMPL.D\OJJSMPL .D~ 

Sample QC Report 

Data File: 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I27S00.B\033SMPL.D\033SMPL.D# 

Sep 27 2012 09,37 pm 

NBS 

1638 MDL-0.25-5 

120920A-1638 

Vial Number: 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3301 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1.00 

1.00 

QC Blements 

Element 

(Li) 

done. 

ug/l 

0.41 ug/l 

2.60 ug/l 

942100.00 ug/l 

967000.00 ug/l 

17.80 ug/l 

Be 

II B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

III Cd 

ll8 Sn 

ll8 Sn 

ll8 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

64.03 ug/l 

2193000.00 ug/l 

0.65 ug/l 

0.76 ug/l 

loll ug/l 

0.74 ug/l 

23.53 ug/l 

0.70 ug/l 

2.12 ug/l 

0.54 ug/l 

0.89 ug/l 

2.61 ug/l 

1.47 ug/l 

0.96 ug/l 

4.11 ug/l 

140.50 ug/l 

116.20 ug/l 

0.46 ug/l 

ug/l 

0.28 ug/l 

ug/l 

0.49 ug/l 

0.89 ug/l 

0.89 ug/l 

0.53 ug/l 

2.51 ug/l 

2.83 ug/l 

0.40 ug/l 

ug/l 

ug/l 

2.04 ug/l 

ISTD Elements 

Element CPS Mean RSD(%) 

Li -128832.59 1.74 

45 Sc 5199ll9.00 0.51 

Carr. Cone. 

#VALUE! 

0.41 

2.60 

942100.00 

967000.00 

17.80 

64.03 

2193000.00 

0.65 

0.76 

1.11 

0.74 

23.53 

0.70 

2.12 

0.54 

0.89 

2.61 

1. 47 

0.96 

4.ll 

l40.50 

ll6.20 

0.46 

#VALUE! 

0.28 

#VALUE! 

0.49 

0.89 

0.89 

0.53 

2.51 

2.83 

0.40 

#VALUE! 

#VALUE! 

2.04 

Ref Value 

-88139.43 

5590061.50 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

772689.38 

20202606.00 

ll34 833.50 

1.59 732360.19 

5.53 18013604.00 

413190.78 

3420337.80 

7713857.50 

3885233.30 

19070764.00 

20546552.00 

19237108.00 

0.87 1407958.90 

1.86 475526.09 

0.81 3640663.30 

0.70 10055673.00 

1.28 4993515.00 

3.08 20883300.00 

3.87 23533162.00 

4.03 22278996.00 

RSD(%) High Limit 

o 

3.30 1000 

18.26 1000 

0.84 25000 

0.78 50000 

4.69 20000 

5.20 20000 

0.77 50000 

16.63 1000 

1.48 1000 

1.79 1000 

1. 59 1000 

1.06 20000 

0.76 

1.48 

2.96 

5.39 

4.91 

0.22 

2.37 

3.41 

0.04 

2.41 

6.12 

3.14 

8.36 

3.36 

4.96 

10.78 

3.08 

4.39 

2.89 

3.07 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Rec (%) QC Range(%) 

146.2 

93.0 

105.5 

112.2 

80.6 

86.9 

93.9 

76.7 

77.8 

91. 3 

87.3 

86.3 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 -

70 

70 -

70 -

70 

70 -

70 

120 

120 

120 

120 

120 

120 

120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

:Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271129:41 PM 

Fail 

Fail 

,Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C,\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
63

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MOL Study 

Sample 10: FGO-6 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 lEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.4 

0.53 

1.2 

2.0 

6.0 

PQl Units 

0.2 ug/l 

0.2 ug/l 

0.2 ug/l 

0.2 ug/l 

0.2 ug/l 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67416 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

.. ~~9:~ ...... ________ T_I:I~_~~~~~_C~~) _______________________________________ 9:~? ________ . __ . ___ . _______ ~:~._. _________ . ___ ~9!~ __ . _____ 9_~!?_.9!.~? ___________ Q~~?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
64

C. \ICPCHEM\ 1 \DATA \ 12I26qOO. B\07 BSMPL. D\07BSMPL. 01 

Sample QC Report 

Data File: 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I26qOO.B\078SMPL.D\078SMPL D# 

Sep 27 2012 01:06 am 

Operator: 

Sample Name. 

Mise Info: 

NBS 

1638 MDL-0.25-6 

120nOA-1638 

Vial Number: 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3302 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1. 00 

1. 00 

QC Elements 

Element Cone. Cerro Cone. 

#VALUEI 

0.34 

14.08 

894700.00 

906400.00 

14 .75 

83.17 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

lOB (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.34 ug/l 

14.08 ug/l 

894700.00 ug/l 

906400.00 ug/l 

14.75 ug/l 

83.17 ug/l 

1927000.00 ug/l 

0.57 ug/l 

0.70 ug/l 

1.18 ug/l 

-0.77 ug/l 

16.28 ug/l 

0.86 ug/l 

2.08 ug/l 

0.67 ug/l 

1.07 ug/l 

-1.19 ug/l 

1.40 ug/l 

5.98 ug/l 

10.15 ug/l 

123.30 ug/l 

113.70 ug/l 

0.55 ug/l 

ug/l 

0.30 ug/l 

ug/l 

0.53 ug/l 

-2.69 ug/l 

-2.84 ug/l 

-2.59 ug/l 

1.57 ug/l 

2.84 ug/l 

0.42 ug/l 

ug/l 

ug/l 

2.02 ug/l 

1927000.00 

0.57 

0.70 

1.18 

-0.77 

16.28 

0.86 

2.08 

0.67 

1. 07 

-1.19 

1.40 

5.98 

10.15 

123.30 

113.70 

0.55 

#VALUEI 

0.30 

#VALUEI 

0.53 

-2.69 

-2.84 

-2.59 

1. 57 

2.84 

0.42 

#VALUEI 

#VALUEI 

2.02 

ISTD Elements 

Elemen t CPS Mean RSD (%) Ref Value 

-131996.50 

3646344.80 

6 Li -78978.44 33.21 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3411907.00 

467452.09 

14293704.00 

752096.63 

259763.64 

2571415.80 

5370700.50 

2536029.30 

0.90 

1.37 537987.94 

36.57 17012292.00 

0.83 949396.31 

0.50 338792.91 

27.15 3456710.80 

0.46 6610579.00 

1.12 3651775.30 

16308394.00 37.2B 22769202.00 

21095204.00 38.57 28649686.00 

20412764.00 39.12 27453282.00 

RSD(%) 

36.34 

35.72 

2.01 

2.04 

8.93 

5.87 

1. 37 

17.68 

0.78 

2.30 

5.40 

3.60 

24.28 

2.06 

5.06 

5.11 

10.73 

1. 69 

2.56 

1. 84 

0.73 

37.36 

38.27 

38.15 

42.20 

1. 20 

1. 85 

9.29 

37.16 

37.60 

38.79 

37.87 

Rec(%) 

59.8 

93.6 

86.9 

84.0 

79.2 

76.7 

74.4 

81.2 

69.4 

71. 6 

73.6 

74.4 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 - 120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

IS Fai 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures :Max. Number of Failures Allowed 

:ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/27/121:10 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
65

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-6 

Sample Collection Date: 08/30/12 

Method 

200.8 

200.8 

200.8 

Analyte 

ARSENIC (AS) 

CADMIUM (CD) 

CHROMIUM (CR) 

Metals Analysis 

Result 

1.7 

0.55 

1.2 

PQL 

0.5 

0.2 

0.5 

Units 

ug/L 

ug/L 

ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67416 

Prep Date Analysis Date 

09/20/12 

09/20/12 

09/20/12 

09/27/12 

09/27/12 

09/27/12 

200.8 LEAD (PB) 2.2 0.2 ug/L 09/20/12 09/27/12 

200.8 SELENIUM (SE) 1.1 1.0 ug/L 09/20/12 09/27/12 

.~~9:~ .............. T.Ij.~.~~~~~.C~~) ....................................... 9:~? ..................... ~:? ................ ~9!~ ........ 9.9!?9!.~? .......... ~~~?X!~.? ... . 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
66

C, \ ICPCHEM\ 1 \OATA\12Il7.00. B\034SMPL.O\034SMPL. OH 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27S00.8\034SMPL.D\034SMPL.DU 

sep 27 2012 09:44 pm 

Operator: N8S 

Sample Name: 1638 MDL-0.25-6 

Mise Info: 120920A-1638 

Vial Number: 

current Method: 

Calibration File: 

Last Cal Update: 

3302 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALI8\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: Sample 

Prep Oil Factor: 1. 00 

Total oil Factor: 1. 00 

QC Elements 

Element Cone. Carr. Conc. 

7 (Li) 

9 8e 

11 8 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

1378a 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.46 ug/l 

2.46 ug/l 

954000.00 ug/l 

972100.00 ug/l 

18.31 ug/l 

68.54 ug/l 

2235000.00 ug/l 

0.61 ug/l 

0.85 ug/l 

1.17 ug/l 

0.75ug/l 

22.68 ug/l 

0.75 ug/l 

2.35ug/l 

0.58 ug/l 

0.93 ug/l 

2.45 ug/l 

1.67 ug/l 

1.06 ug/l 

4.75 ug/l 

144.00 ug/l 

126.30 ug/l 

0.54 ug/l 

ug/l 

0.33 ug/l 

ug/l 

0.55 ug/l 

0.95 ug/l 

0.89 ug/l 

0.57 ug/l 

2.43 ug/l 

3.06 ug/l 

0.46 ug/l 

ug/l 

ug/l 

2.24 ug/l 

UVALUE! 

0.46 

2.46 

954000.00 

972100.00 

18.31 

68.54 

2235000.00 

0.61 

0.85 

l.17 

0.75 

22.68 

0.75 

2.35 

0.58 

0.93 

2.45 

1.67 

1. 06 

4.75 

144.00 

126.30 

0.54 

UVALUE! 

0.33 

UVALUE! 

0.55 

0.95 

0.89 

0.57 

2.43 

3.06 

0.46 

UVALUE! 

UVALUE! 

2.24 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

732360.19 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-124807.09 

5205648.00 

768943.50 

20064602.00 

1143915.10 

413330.66 

3473263.50 

7762750.00 

3868647.30 

18836104.00 

19873688.00 

18683172.00 

2.92 

0.97 

0.65 

0.21 18013604.00 

0.40 1407958.90 

0.68 475526.09 

0.59 3640663.30 

0.18 10055673.00 

0.75 4993515.00 

0.80 20883300.00 

0.29 23533162.00 

0.32 22278996.00 

RSD(%) 

1.13 

5.15 

0.27 

0.51 

3.33 

2.92 

0.33 

14.28 

0.65 

4.04 

2.49 

0.24 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

0.44 1000 

1.13 1000 

1.40 1000 

3.48 .1000 

2.63 1000 

0.41 1000 

4.08 1000 

1.53 1000 

0.61 1000 

o .72 1000 

1.17 1000 

UUUUUUU 

1. 84 500 

UUUUUUU 

5.58 1000 

3.42 UUUUUUU 

4.07 UUUUUUU 

1. 38 1000 

1.67 1000 

1.36 1000 

0.73 1000 

UUUUUUU 

UUUUUUU 

0.73 1000 

Rec(%) 

141.6 

93.1 

105.0 

111.4 

81. 2 

86.9 

95.4 

77.2 

77.5 

90.2 

84.4 

83.9 

QC Range(%) 

70 120 

70 120 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I27s00.8\004CAL8.D\004CAL8.DU 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 9:48 PM 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
67

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-7 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.3 

0.44 

1.2 

2.0 

5.3 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67417 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

.. ~~9_·~ ______________ ~_~_~_~!:~~~_Q~~) ________________ _______________________ 9:~~ _______________________ ~:~ ________________ ~9!!: ________ 9_~!~9!_~? ___________ Q~~?X!~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:01:18 PM 
68

C, \ICPCHEM\l \OATA\12126qOO. B\079SMPL.0\079SKPL. 0# 

Sample QC Report 

Data File, 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I26qOO.B\079SMPL.D\079SMPL.D# 

Sep 27 2012 01,13 am 

Operator: NBS 

Sample Name: 1638 MDL-0.25-7 

Mise Info: 120920A-1638 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3303 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Oil Factor, 

Total Oil Factor, 

1. 00 

1. 00 

QC Blements 

Element Cone. Cerro Conc. 

#VALUEI 

0.30 

12.52 

889100.00 

898700.00 

20.87 

74.21 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.30 ug/l 

12.52 ug/l 

889100.00 ug/l 

898700.00 ug/l 

20.87 ug/l 

74.21 ug/l 

1924000.00 ug/l 

0.67 ug/l 

0.63 ug/l 

1.15 ug/l 

-0.79 ug/l 

17.93 ug/l 

0.70ug/l 

1.82 ug/l 

0.72 ug/l 

1.12 ug/l 

-1.25 ug/l 

1.31 ug/l 

5.35 ug/l 

9.48 ug/l 

123.10 ug/l 

110.30 ug/l 

0.59 ug/l 

ug/l 

0.27 ug/l 

ug/l 

0.44 ug/l 

-2.74 ug/l 

-2.90 ug/l 

-2.68 ug/l 

1. 35 ug/l 

2.74 ug/l 

0.39 ug/l 

ug/l 

ug/l 

2.02 ug/l 

1924000.00 

0.67 

0.63 

1.15 

-0.79 

17.93 

0.70 

1.82 

0.72 

1.12 

-1. 25 

1. 31 

5.35 

9.48 

123.10 

110.30 

0.59 

#VALUEI 

0.27 

#VALUEI 

0.44 

-2.74 

-2.90 

-2.68 

1. 35 

2.74 

0.39 

#VALUEI 

#VALUEI 

2.02 

ISTD B1ements 

Element CPS Mean RSD(%) Ref Value 

6 Li -75405.17 5.22 -131996.50 

45 Sc 3306792.00 0.70 3646344.80 

45 Sc 449292.06 3.73 537987.94 

45 Sc 12766245.00 0.52 17012292.00 

72 Ge 734343.13 1.20 949396.31 

72 Ge 245269.66 2.71 338792.91 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

2400689.80 

5224508.00 

2428834.30 

15097894.00 

19379362.00 

18647806.00 

0.31 3456710.80 

1.62 6610579.00 

1.91 3651775.30 

0.49 22769202.00 

0.13 28649686.00 

0.20 27453282.00 

RSD(%) High Limit 

o 2.71 1000 

0.90 1000 

0.86 25000 

0.96 50000 

28.97 20000 

4.88 20000 

1.15 50000 

43.97 1000 

0.47 1000 

1.55 1000 

2.74 1000 

25.74 20000 

2.74 1000 

3.20 1000 

2.89 1000 

3.38 1000 

7.54 1000 

0.66 1000 

1.08 1000 

3.64 1000 

0.52 1000 

1.26 1000 

26.60 1000 

####### 

3.98 500 

####### 

6.99 1000 

0.19 ####### 

1.34 ####### 

0.48 1000 

0.75 1000 

0.06 1000 

1.71 1000 

####### 

####### 

0.36 1000 

Ree( %) 

57.1 

90.7 

83.5 

75.0 

77.3 

72 .4 

69.5 

79.0 

66.5 

66.3 

67.6 

67.9 

QC Range (%) 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 - 120 

Flag 

>Cal 

>Cal 

>Cal 

Flag 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

3 :Element Failures 

6 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27/121:17 AM 

Fail 

Fail 

:Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHBM\l\rpttmp\Sample_qct Page 1 of 1 
69

CSC 

6101 Steveson Ave. 

Alexandria, VA 22304 

Attn: Chip McCarty 

Project: FGD MDL Study 

Sample 10: FGO-7 

Sample Collection Date: 08/30/12 

Method Analyte 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

Metals Analysis 

Result 

1.6 

0.51 

1.1 

2.2 

1.00 

PQl Units 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

0.2 ug/L 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

ARF: 68603 

APPL 10: AY67417 

Prep Date Analysis Date 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

09/20/12 09/27/12 

_~~9:~ ______________ T_Ij_~_~~~~~_C~~) __________________ _____________________ 9:~? _________ ._. ___________ ~·_? ________________ ~9!~ ________ 9_~!~9!_~? ___________ Q~~?X~~_? ____ _ 

Form 1 - APPL Standard 

Metals - No Me 

Printed: 101011125:03:27 PM 
70

C, \ICPCHEM\l \DATA\12127.00. B\035SMPL. D\035SMPL. D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I27S00.B\035SMPL.D\035SMPL.DU 

Sep 27 2012 09,51 pm 

NBS 

1638 MDL-0.25-7 

120920A-1638 

Vial Number, 

Current Method: 

Calibration File: 

Last Cal Update, 

Sample Type, 

prep Dil Factor: 

3303 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

1.00 

Total Dil Factor, 1. 00 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.41 ug/l 

2.25 ug/l 

957600.00 ug/l 

978000.00 ug/l 

18.25 ug/l 

65.91 ug/l 

2265000.00 ug/l 

0.70 ug/l 

0.80 ug/l 

1.13 ug/l 

0.74 ug/l 

22.65 ug/l 

0.72 ug/l 

2.06 ug/l 

0.61 ug/l 

0.98 ug/l 

2.38 ug/l 

1.59 ug/l 

1. 00 ug/l 

4.47 ug/l 

146.50 ug/l 

127.20 ug/l 

0.50 ug/l 

ug/l 

0.31 ug/l 

ug/l 

0.51 ug/l 

0.80 ug/l 

0.83 ug/l 

0.55 ug/l 

2.18ug/1 

3.17 ug/l 

0.42 ug/l 

ug/l 

ug/l 

2.23 ug/l 

ISTD Elements 

Cerro Cone. 

UVALUE! 

0.41 

2.25 

957600.00 

978000.00 

18.25 

65.91 

2265000.00 

0.70 

0.80 

1.13 

0.74 

22.65 

0.72 

2.06 

0.61 

0.98 

2.38 

1. 59 

1.00 

4.47 

146.50 

127.20 

0.50 

UVALUE! 

0.31 

UVALUE! 

0.51 

0.80 

0.83 

0.55 

2.18 

3.17 

0.42 

UVALUEI 

UVALUE! 

2.23 

RSD(%) 

2.47 

4.47 

0.80 

0.66 

4.80 

6.68 

0.44 

6.65 

3.38 

1. 27 

4.66 

1.43 

1.17 

2.20 

2.36 

1. 63 

4.51 

3.61 

3.79 

7.91 

0.74 

0.77 

4.88 

0.54 

9.57 

2.35 

0.33 

3.84 

2.64 

1. 72 

2.87 

1. 01 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

Flag 

>Cal 

>Cal 

>Cal 

Element CPS Mean RSD(%) Ref Value Rec(%) QC Range(%) Flag 

6 Li -120470.04 4.83 -88139.43 

45 Sc 5289535.00 0.74 5590061.50 

45 Sc 800425.56 2.58 732360.19 

45 Sc 18963600.00 0.82 18013604.00 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

1166711. 90 

426553.41 

3277794.50 

7891399.00 

4000139.30 

18184142.00 

19559186.00 

18464470.00 

0.56 1407958.90 

1. 62 475526.09 

1.40 3640663.30 

0.20 10055673.00 

2.27 4993515.00 

0.89 20883300.00 

1.58 23533162.00 

1.28 22278996.00 

136.7 70 120 IS Fai 

94.6 70 120 

109.3 70 120 

105.3 70 - 120 

82.9 

89.7 

90.0 

78.5 

80.1 

87.1 

83.1 

82.9 

70 -

70 

70 

70 

70 -

70 

70 

70 -

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.DU 

:Element Failures 0 :Max. Number of Failures Allowed 

,ISTD Failures 0 ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/271129'55 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
71

METALS 

Calibration Data 
72

A.P.P.L. INC. 

2A 

INITIAL AND CONTINUING CALIBRATION VERIFICATION 

Lab Name: A.P.P.L. INC. Contract: CSC ---------------------------- ARF No: 68603 SDG: 68603 

Initial Calibration Source: CPI 

Continuing Calibration Source: Environmental Express 

Analysis Date: 09/26112 Concentration Units: ug/L ----------------------

Analyte Initial Calibration Continuing Calibration M 

True Found %R(1) True Found %R(1) True Found %R(1) 

17:21 CCVI 18:08 CCVI 19:41 

Arsenic (As) 40 36.79 92.0 100 100.1 100 100 98.93 98.9 P 

Cadmium (Cd) 40 36.94 92.3 100 96.71 96.7 100 99.08 99.1 P 

Chromium (Cr) 40 40.67 102 100 99.9 99.9 100 101.2 101 P 

Lead (Pb) 40 37.63 94.1 100 95.21 95.2 100 100.8 101 P 

Selenium (Se) 40 35.84 89.6 100 98.18 98.2 100 101.4 101 P 

Thallium (TI) 40 37.44 93.6 100 95.78 95.8 100 100 100 P 

(1) Control Limits: Metals 90-110 ILM02.0 

67404_2008_ Opti _120926Arev FORM II (PART 1) - IN 
73

A.P.P.L. INC. 

2A 

INITIAL AND CONTINUING CALIBRATION VERIFICATION 

Lab Name: A.P.P.L. INC. Contract: CSC 

ARF No: 68603 SDG: 68603 

Initial Calibration Source: CPI 

Continuing Calibration Source: Environmental Express 

Analysis Date: 09/26112 Concentration Units: ugiL ----------------------

Analyte Initial Calibration Continuing Calibration 

True Found %R(1) True Found %R(1) True 

17:21 CCVI 21:14 CCVI 

Arsenic (As) 40 36.79 92.0 100 100.6 101 100 

Cadmium (Cd) 40 36.94 92.3 100 93.17 93.2 100 

Chromium (Cr) 40 40.67 102 100 104.3 104 100 

Lead (Pb) 40 37.63 94.1 100 93.82 93.8 100 

Selenium (Se) 40 35.84 89.6 100 102.9 103 100 

Thallium (TI) 40 37.44 93.6 100 92.17 92.2 100 

(1) Control Limits: Metals 90-110 

67404_2008_0pti_120926Arev FORM II (PART 1) - IN 

M 

Found %R(1) 

22:47 

. 100.1 100 P 

94.51 94.5 P 

105.2 lOS P 

92.46 92.5 P 

102.8 103 P 

91.96 92.0 P 

ILM02.0 
74

AP.P.L. INC. 

2A 

INITIAL AND CONTINUING CALIBRATION VERIFICATION 

Lab Name: AP.P.L. INC. Contract: CSC ---------------------------- ARF No: 68603 SDG: 68603 

Initial Calibration Source: CPI 

Continuing Calibration Source: Environmental Express 

Analysis Date: 09/26112 Concentration Units: ug/L ----------------------

Analyte Initial Calibration Continuing Calibration M 

True Found %R(1) True Found %R(1) True Found %R(1) 

17:21 CCVI 0:20 CCVI 1:53 

Arsenic (As) 40 36.79 92.0 100 100.1 100 100 93.77 93.8 P 

Cadmium (Cd) 40 36.94 92.3 100 92.53 92.5 100 91 91.0 P 

Chromium (Cr) 40 40.67 102 100 101.7 102 100 98.87 98.9 P 

Lead (Pb) 40 37.63 94.1 100 91.53 91.5 100 96.11 96.1 P 

Selenium (Se) 40 35.84 89.6 100 102.3 102 100 97.26 97.3 P 

Thallium (TI) 40 37.44 93.6 100 90.94 90.9 100 95.85 95.8 P 

(1) Control Limits: Metals 90-110 ILM02.0 

67404_2008_0pti_120926Arev FORM II (PART 1) - IN 
75

A.P.P.L. INC. 

2A 

INITIAL AND CONTINUING CALIBRATION VERIFICATION 

Lab Name: A.P.P.L. INC. Contract: CSC ---------------------------- ARF No: 68603 SDG: 68603 

Initial Calibration Source: CPI 

Continuing Calibration Source: Environmental Express 

Analysis Date: 09/26/12 Concentration Units: ugiL ----------------------

Analyte Initial Calibration Continuing Calibration M 

True Found %R(1) True Found %R(1) True Found %R(1) 

17:21 CCVI 3:27 

Arsenic (As) 40 36.79 92.0 100 90.07 90.1 P 

Cadmium (Cd) 40 36.94 92.3 100 87.87 87.9 Y 

Chromium (Cr) 40 40.67 102 100 98.91 98.9 P 

Lead (Pb) 40 37.63 94.1 100 93.81 93.8 P 

Selenium (Se) 40 35.84 89.6 100 93.15 93.2 P 

Thallium (TI) 40 37.44 93.6 100 97.33 97.3 P 

(1) Control Limits: Metals 90-110 ILM02.0 

67404_2008_Opti_120926Arev FORM II (PART 1) - IN 
76

Lab Name: A.P.P.L. INC. 

A.P.P.L. INC. 

3 

BLANKS 

Contract: CSC ---------------------------- ARF No.: 68603 SDG: 68603 

Preparation Blank Matrix (soil/water): water -------------

Preparation Blank Concentration Units (ug/L or mg/kg): ug/L 

-------------

Analysis Date: 09/26112 

Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M 

Blank (ug/L) Blank 

C 1 C 2 C 3 C C 

17:34 18:21 19:54 21:27 23:47 

Arsenic (As) .50 U .50 U .50 U .50 U .50 U P 

Cadmium (Cd) .20 U .20 U .20 U .20 U .20 U P 

Chromium (Cr) .50 U .50 U .50 U .50 U .50 U P 

Lead (Pb) .20 U .20 U .20 U .20 U .20 U P 

Selenium (Se) 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U P 

Thallium (TI) .20 U .20 U .20 U .20 U .20 U P 

67405_2008_ Optt I 20926Arev FORM III - IN ILM02.0 
77

Lab Name: A.P.P.L. INC. 

A.P.P.L. INC. 

3 

BLANKS 

Contract: CSC ---------------------------- ARF No.: 68603 SDG: 68603 

Preparation Blank: Matrix (soil/water): water -----------

Preparation Blank: Concentration Units (ug/L or mg/kg): ug/L ---------

Analysis Date: 09/26/12 

Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M 

Blank (ug/L) Blank 

C 1 C 2 C 3 C C 

17:34 23:00 00:33 02:07 23:47 

Arsenic (As) .50 U .50 U .50 U .50 U .50 U P 

Cadmium (Cd) .20 U .20 U .20 U .20 U .20 U P 

Chromium (Cr) .50 U .50 U .50 U .50 U .50 U P 

Lead (Pb) .20 U .20 U .20 U .20 U .20 U P 

Selenium (Se) 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U P 

Thallium (11) .20 U .20 U .20 U .20 U .20 U P 

67405_2008_0pti_120926Arev FORM III - IN ILM02.0 
78

Lab Name: A.P.P.L. INC. 

A.P.P.L. INC. 

3 

BLANKS 

Contract: CSC ---------------------------- ARF No.: 68603 SDG: 68603 

Preparation Blank Matrix (soil/water): water -------------

Preparation Blank Concentration Units (ugIL or mg/kg): ug/L -------------

Analysis Date: 09/26112 

Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M 

Blank (ug/L) Blank 

C 1 C 2 C 3 C C 

17:34 03:40 23:47 

Arsenic (As) .50 U .50 U .50 U P 

Cadmium (Cd) .20 U .20 U .20 U P 

Chromium (Cr) .50 U .50 U .50 U P 

Lead (Pb) .20 U .20 U .20 U P 

Selenium (Se) 1.00 U 1.00 U 1.00 U P 

Thallium (Tl) .20 U .20 U .20 U P 

67405_2008_ Opti_120926Arev FORM III - IN ILM02.0 
79

A.P.P.L. INC. 

2A 

INITIAL AND CONTINUING CALIBRATION VERIFICATION 

Lab Name: A.P.P.L. INC. Contract: CSC ---------------------------- ARF No: 68603 SDG: 68603 

Initial Calibration Source: CPI 

Continuing Calibration Source: Environmental Express 

Analysis Date: 09/27/12 Concentration Units: ug/L ----------------------

Analyte Initial Calibration Continuing Calibration M 

True Found %R(1) True Found %R(1) True Found %R(1) 

18:50 CCVI 19:37 CCVI 21:11 

Arsenic (As) 40 37.43 93.6 50 53.3 107 50 53.88 108 P 

Cadmium (Cd) 40 38.37 95.9 50 50.43 101 50 49.57 99.1 P 

Chromium (Cr) 40 40.21 101 50 48.95 97.9 50 50.17 100 P 

Lead (Pb) 40 36.78 92.0 50 48.8 97.6 50 48.44 96.9 P 

Selenium (Se) 40 39.26 98.2 50 53.83 108 50 56.73 113 1/ 

Thallium (TI) 40 38.32 95.8 50 49.83 99.7 50 49.23 98.5 P 

(1) Control Limits: Metals 90-110 ILM02.0 

67405_2008 _ Opti_120927 Arev FORM II (PART 1) - IN 
80

A.P.P.L. INC. 

2A 

INITIAL AND CONTINUING CALIBRATION VERIFICATION 

Lab Name: A.P.P.L. INC. Contract: CSC ---------------------------- ARF No: 68603 SDG: 68603 

Initial Calibration Source: CPI 

Continuing Calibration Source: Environmental Express 

Analysis Date: 09/27112 Concentration Units: ugIL ----------------------

Analyte Initial Calibration Continuing Calibration M 

True Found %R(1) True Found %R(1) True Found %R(1) 

18:50 CCVI 22:44 CCVI 0:18 

Arsenic (As) 40 37.43 93.6 50 51.63 103 50 50.33 101 P 

Cadmium (Cd) 40 38.37 95.9 50 48.92 97.8 50 47.31 94.6 P 

Chromium (Cr) 40 40.21 101 50 49.43 98.9 50 48.24 96.5 P 

Lead (Pb) 40 36.78 92.0 50 50.07 100 50 49.63 99.3 P 

Selenium (Se) 40 39.26 98.2 50 54.07 108 50 54.22 108 P 

Thallium (TI) 40 38.32 95.8 50 50.49 101 50 50.19 100 P 

(1) Control Limits: Metals 90-110 ILM02.0 

67404_2008_0pti_120926Arev FORM II (PART 1) - IN 
81

Lab Name: A.P.P.L. INC. 

A.P.P.L. INC. 

3 

BLANKS 

Contract: CSC ---------------------------- ARF No.: 68603 SDG: 68603 

Preparation Blank Matrix (soil/water): water -------------

Preparation Blank Concentration Units (ug/L or mg/kg): ug/L ---'-----------

Analysis Date: 09/27112 

Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M 

Blank (ug/L) Blank 

C 1 C 2 C 3 C C 

19:04 19:50 21:24 22:58 20:11 

Silver (Ag) .20 U .20 U .20 U .20 U .20 U P 

Cadmium (Cd) .20 U .20 U .20 U .20 U .20 U P 

Chromium (Cr) .50 U .50 U .50 U .50 U .50 U P 

Lead (Pb) .20 U .20 U .20 U .20 U .20 U P 

Selenium (Se) 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U P 

Thallium (TI) .20 U .20 U .20 U .20 U .20 U P 

67404_2008_ Opti_120927 Arev FORM III - IN ILM02.0 
82

Lab Name: A.P.P.L. INC. 

A.P.P.L. INC. 

3 

BLANKS 

Contract: CSC ---------------------------- ARF No.: 68603 SDG: 68603 

Preparation Blank Matrix (soil/water): water -----------

Preparation Blank Concentration Units (ugiL or mglkg): ug/L -----------

Analysis Date: 09/27/12 

Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M 

Blank (ug/L) Blank 

C 1 C 2 C 3 C C 

19:04 00:32 20:11 

Silver (Ag) .20 U .20 U .20 U P 

Cadmium (Cd) .20 U .20 U .20 U P 

Chromium (Cr) .50 U .50 U .50 U P 

Lead (Pb) .20 u .20 U .20 U P 

Selenium (Se) 1.00 U 1.00 U 1.00 U P 

Thallium (TI) .20 U .20 U .20 U P 

67404_2008 _ Opti_120927 Arev FORM III - IN ILM02.0 
83

C.\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D# 

Calibration Blank QC Report 

Data File: 

Date Acquired: 

Operator: 

Sample Name: 

Mise Info: 

Vial Number: 

C:\ICPCHEM\1\DATA\12I26qOO.B\004CAL 

Sep 26 2012 04:54 pm 

NBS 

Calibration Blank 

Current Method: 

1102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 04:51 pm 

Calibration File: 

Last Cal Update: 

Sample Type: CalBlk 

Total Dil Factor: l. 00 

QC&ISTD Elements 

Element 

6 

7 

9 

11 

23 

24 

27 

39 

44 

45 

45 

45 

47 

51 

52 

55 

56 

59 

60 

63 

65 

66 

72 

72 

72 

75 

78 

78 

88 

88 

95 

106 

107 

108 

111 

115 

115 

115 

118 

118 

118 

121 

137 

159 

165 

205 

206 

207 

208 

Li 

(Li) 

Be 

B 

Na 

Mg 

Al 

K 

Ca 

Sc 

Sc 

Sc 

Ti 

V 

Cr 

Mn 

Fe 

Co 

Ni 

Cu 

Cu 

Zn 

Ge 

Ge 

Ge 

As 

Se 

Se 

Sr 

Sr 

Mo 

(Cd) 

Ag 

(Cd) 

Cd 

In 

In 

In 

Sn 

Sn 

Sn 

Sb 

Ba 

Tb 

Ho 

TI 

(Pb) 

(Pb) 

Pb 

9/26/124:58 PM 

CPS Mean 

-131996.50 A 

9364744.00 A 

265.57 P 

10658.16 P 

38625.20 P 

1465.68 P 

1132.33 P 

55876.13 P 

3152.87P 

3646345.00 A 

537987.88 A 

17012290.00 A 

20.44 P 

600.02 P 

390.23P 

4003.71 P 

23753.24P 

184.45 P 

23l. 73 P 

394.23P 

215.56 P 

3000.36 P 

949396 .31 A 

338792.91 A 

3456711.00 A 

74.67 P 

12.78 P 

197.45P 

2728.15P 

29199.07P 

325.57 P 

77.78 P 

30l.13 P 

34.45 P 

206.20 P 

6610579.00 A 

3651775.00 A 

22769200.00 A 

2 071l. 03 P 

12091.18 P 

71947.77 P 

804.50 P 

1065.64P 

28649680.00 A 

27453280.00 A 

142l.24 P 

743.38P 

620.04P 

2831.34 P 

SO 

4085.00 

101000.00 

13.47 

533.70 

271 .10 

27.96 

61.89 

946.60 

93.55 

104600.00 

5966.00 

243000.00 

3.36 

8.33 

16.56 

77.60 

198.50 

14.26 

138.20 

30.99 

15.34 

72.91 

13980.00 

3278.00 

29270.00 

3.18 

4.81 

12.83 

116.60 

383.90 

44.39 

12.62 

15.03 

15.03 

40.64 

142000.00 

23990.00 

500600.00 

467.80 

122.40 

426.90 

43.51 

10.18 

627100.00 

578000.00 

115.00 

20.82 

18.57 

64.32 

RSD(%) 

3.09 

l. 08 

5.07 

5.01 

0.70 

l.91 

5.47 

l. 69 

2.97 

2.87 

l.11 

l. 43 

16.42 

l. 39 

4.24 

l. 94 

0.84 

7.73 

59.64 

7.86 

7.12 

2.43 

l. 47 

0.97 

0.85 

4.26 

37.65 

6.50 

4.27 

l. 31 

13.64 

16.23 

4.99 

43.63 

19.71 

2.15 

0.66 

2.20 

2.26 

l. 01 

0.59 

5.41 

0.96 

2.19 

2.11 

8.09 

2.80 

3.00 

2.27 

C:\ICPCHEM\l\rpttmp\CalBlk.qct Page 1 of 1 
9126112 5:05 PM 84

c: \ICPCHKH\l \DATA\HI2IiqOQ .B\005CALS .D\005CALS. D' 

Calibration Standard QC Report 

Data File: 

Date Acquired: 

C. \ICPCHEM\l \ DATA \12 I 26qOO. B\005CALS. D\005CALS . D# 

Sep 26 2012 05.01 pm 

Operator: 

Sample Name: 

Misc Info I 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

Sample Type. 

Total Oil Factor: 

Elements 

NBS 

120926 Standard 1 

1103 

C.\ICPCHEM\l\METHODS\CSC-MDL.M 

C.\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 04.58 pm 

CalStd 

1. 00 

QC&ISTD 

Element 

6 Li 

CPS Mean 

-128456.10 A 

9374662.00A 

SD 

14870.00 

11470.00 

61.99 

339.10 

612.50 

3324.00 

RSD(\) 

11.58 

0.12 

0.67 

2.13 

1. 21 

4.35 

4.02 

2.44 

4.02 

0.26 

0.84 

1. 74 

3.40 

1.34 

2.36 

1. 20 

0.46 

3.90 

2.63 

2.33 

5.87 

0.94 . 

0.46 

1. 07 

0.82 

1. 78 

5.55 

5.68 

1.17 

0.70 

0.63 

3.17 

1. 23 

3.32 

3.47 

0.14 

0.53 

1. 65 

1. 69 

0.69 

8.77 

0.59 

2.62 

1.44 

1. 86 

1. 01 

0.62 

0.57 

0.25 

Cal Coef 

0.0000 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

45 Sc 

45 Sc 

45 Sc 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

72 Ge 

72 Ge 

72 Ge 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

115 In 

115 In 

115 In 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

159 Tb 

165 Ho 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

9215.35P 

15891.85 P 

50818.34 P 

76363.15P 

14064.36P 

66014.35 P 

6679.48P 

3864788.00 A 

542454.88 A 

17162160.00 A 

274.67 P 

4073.95 P 

4338.48P 

3616.54P 

364264.50 P 

5822.57P 

1639.67 P 

5722.53P 

2818.54P 

2764.30P 

970636.38 A 

335102.59 A 

3498259.00A 

674.35P 

264.78 P 

265.00 P 

6080.42 P 

69383.48P 

23553.46 P 

640.04 P 

29520.78 P 

464.47P 

6220.04 P 

6941834.00A 

3633142.00 A 

22559980.00A 

25271.30 P 

14575.83 P 

91354.67 P 

48745.79P 

9586.97 P 

29082390.00 A 

27937120.00A 

47197.45P 

16295.04 P 

13757.63 P 

63812.34P 

565.70 

1613.00 

268.80 

9866.00 

4576.00 

298200.00 

9.33 

54.62 

102.40 

43.30 

1685.00 

227.20 

43.09 

133.60 

165.50 

25.96 

4494.00 

3588.00 

28760.00 

12.00 

14.70 

15.06 

71.36 

487.90 

147.70 

20.28 

363.70 

15.40 

215.70 

9968.00 

19120.00 

372400.00 

427.50 

100.20 

8012.00 

286.10 

251. 60 

419400.00 

520600.00 

476.40 

100.40 

78.52 

159.20 

ISTD Elements 

Element CPS Mean RSO (%:) Ref Value 

-131996.50 

3646344.80 

Li -128456.14 11.58 

45 Sc 3864787.50 0.26 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

542454.94 

17162164.00 

970636.44 

335102.56 

3498259.00 

6941833.50 

3633142.30 

0.84 537987.94 

1.74 17012292.00 

0.46 949396.31 

1.07 338792.91 

0.82 3456710.80 

0.14 6610579.00 

0.53 3651775.30 

22559976.00 1. 65 22769202.00 

29082388.00 1. 44 28649686.00 

27937124.00 1. 86 27453282.00 

Rec (\) QC Range (\) 

97.3 70-

106.0 70-

100.8 

100.9 

102.2 

98.9 

101. 2 

105.0 

99.5 

99.1 

101. 5 

101.8 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

o .0000 

o .0000 

0.0000 

0.0000 

0.0000 

0.0000 

o .0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

o . 0000 

o . 0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

o .0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File. C.\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures :Max. Number of Failures Allowed 

:ISTD Failures :Max. Number of ISTO Failures Allowed 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

C. \ICPCHEM\l \RPTTMP\CalStdx.qct 

Flag 

IS Fail 

Page 1 of 1 
9/261125:12 PM 85

c: \ICPCHEM\l \DATA \12 I 26CJO O. B \0 06CALS. D\OO 6CALS. D' 

Calibration Standard QC Report 

Data File: 

Date Acquired: 

c, \ ICPCHEM\l \ DATA \12 I26qOO. B\006CALS. D\006CALS. Dff 

Sep 26 2012 05,08 pm 

Operator: NBS 

Sample Name: 120926 Standard 2 

Misc InEo: 

Vial Number: 1104 

Current Method: 

Calibration File: 

Last Cal Update: 

c, \ ICPCHEM\l \METIlODS\CSC-MDL.M 

C, \ICPCHEM\l \CALIB\CSC-MDL.C 

Sep 26 2012 05,05 pm 

Sample Type, 

Total Dil Factor: 

CalStd 

1. 00 

OC&ISTD Blements 

Element CPS Mean 

6 Li -124052.80A 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

45 Sc 

45 Sc 

45 Sc 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

72 Ge 

72 Ge 

72 Ge 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

115 In 

115 In 

115 In 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

159 Tb 

165 Ho 

205 Tl . 

206 (Pb) 

207 (Pb) 

208 Pb 

9388073.00A 

87670.49 P 

67109.20 P 

173675.80 P 

702927.38P 

129542.10 P 

138457.30P 

51318.47P 

3831536.00 A 

547501. 50 A 

17162970.00A 

2602.49P 

33628.83 P 

37931.25 P 

28513.23 P 

3549105.00 A 

53880.38 P 

13775.06P 

36971.40 P 

17914.33 P 

10200.58 P 

970464.13 A 

340663.81A 

3481775.00A 

5912.55 P 

2397.65P 

799.36 P 

51626.11 P 

605982.88 P 

222339.20P 

5337.86 P 

281855.81 P 

4228.56 P 

58614.76 P 

6879776.00A 

3681573.00 A 

22643760.00 A 

122217.90 P 

71977 .47 P 

438536.69 P 

464702.41 P 

87739.07P 

28843040.00A 

27834820.00 A 

434437.09 P 

149330.00 P 

125279.60 P 

586482.50P 

ISTD Elements 

SD 

4981. 00 

50090.00 

1032.00 

1683.00 

1025.00 

5082.00 

408.60 

2727.00 

249.50 

19360.00 

1637.00 

233900.00 

16.46 

141.20 

275.00 

320.30 

12120.00 

332.70 

135.70 

437.30 

180.30 

129.90 

11430.00 

5247.00 

19370.00 

7.37 

15.74 

7.64 

58.37 

486.10 

1875.00 

94.08 

2377.00 

184.60 

640.40 

38680.00 

22140.00 

311600.00 

1176.00 

1319.00 

429.10 

4739.00 

1433.00 

590600.00 

502000.00 

4798.00 

602.10 

362.10 

2413.00 

RSD(%) 

4.02 

0.53 

1.18 

2.51 

0.59 

0.72 

0.32 

1. 97 

0.49 

0.51 

0.30 

1. 36 

0.63 

0.42 

0.73 

1.12 

0.34 

0.62 

0.99 

1.18 

1. 01 

1.27 

1.18 

1. 54 

0.56 

0.12 

0.66 

0.96 

0.11 

0.08 

0.84 

1. 76 

0.84 

4.37 

1. 09 

0.56 

0.60 

1. 38 

0.96 

1. 83 

0.10 

1. 02 

1. 63 

2.05 

1. 80 

1.10 

0.40 

0.29 

0.41 

Cal Coef 

0.0000 

1.0000 

1.0000 

1. 0000 

1. 0000 

1.0000 

1. 0000 

1.0000 

1.0000 

0.0000 

o .0000 

0.0000 

1.0000 

1. 0000 

1. 0000 

-1.0000 

1. 0000 

1. 0000 

1.0000 

1. 0000 

1.0000 

-1.0000 

0.0000 

0.0000 

0.0000 

1.0000 

1.0000 

1. 0000 

1. 0000 

1. 0000 

1. 0000 

1.0000 

1.0000 

1.0000 

1. 0000 

0.0000 

0.0000 

0.0000 

1.0000 

1. 0000 

1. 0000 

1. 0000 

1. 0000 

0.0000 

0.0000 

1.0000 

1.0000 

1. 0000 

1. 0000 

Element CPS Mean RSD (%) 

6 Li -124052.85 4.02 

Ref Value 

-131996.50 

3646344.80 

Flag 

120 IS Fail ,vT Rec ( %) QC Range (% ) 

94.0 70-

45 Sc 3831535.80 0.51 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

547501. 56 

17162970.00 

0.30 537987.94 

1.36 17012292.00 

970464.13 1.18 949396.31 

340663.81 1.54 338792.91 

3481774.50 0.56 3456710.80 

6879776.00 0.56 6610579.00 

3681573.00 0.60 3651775.30 

22643762.00 1.38 22769202.00 

28843046.00 2.05 28649686.00 

27834816.00 1.80 27453282.00 

105.1 70 -

101.8 70 -

100.9 70-

102.2 

100.6 

100.7 

104.1 

100.8 

99.4 

100.7 

101.4 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File : c, \ ICPCHEM\l \ DATA \12 I 26qOO. B\004CALB. D\004CALB. Dff 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C I \ICPCHEM\l \RPTTMP\CalStdx. qct Page 1 of 1 
9/261125:16 PM 86

c: \ICPt'HEJ1\l \DATA \llI:ill5qOO. B\007CALS .D\007CALS. DO 

Calibration Standard QC Report 

Data File: 

Date Acquired: 

C, \ICPCHEM\l \ DATA \1212 6qOO. B\007CALS . D\007CALS .DD 

Sep 26 2012 05,14 pm 

Operator; 

Sample Name: 

Misc Infol 

vial Number: 

NBS 

120926 Standard 3 

1105 

Current Method: 

Calibration File: 

Last Cal Update: 

C, \ICPCHEM\l \METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,12 pm 

Sample Type, 

Total Oil Factor I 

CalStd 

1. 00 

QC&ISTD Elements 

Element CPS Mean 

6 Li -119622.80A 

7 (Li) 8883137.00A 

9 Be 921109.69A 

11 B 558770.63P 

23 Na 1545638.00 A 

24 Mg 7149967.00A 

27 Al 1397824.00A 

39 K 949240.50A 

44 Ca 

45 Sc 

45 Sc 

45 Sc 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

72 Ge 

72 Ge 

72 Ge 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

115 In 

115 In 

115 In 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

159 Tb 

165 Ho 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

492536.41 P 

3771472.00 A 

545941.38 A 

15972640.00A 

25286.86 P 

328196.91 P 

368763.00 P 

273514.00 P 

33976660.00 A 

519900.50P 

128886.30 P 

343775.81 P 

167424.30 P 

81050.26P 

958901. 88 A 

338705.59 A 

3377177.00A 

58660.87 P 

25092.68 P 

6399.32 P 

502820.41 P 

6075893.00 A 

227B739.00A 

51378.79 P 

2793105.00 A 

40564.85 P 

565222.38 P 

6690475.00A 

3596723.00 A 

20753860.00 A 

1164467.00 A 

629511.69P 

4011512.00A 

4796117.00 A 

829636.13 P 

26839880.00 A 

25972040.00A 

4520327.00 A 

1584920.00 A 

1333277.00 A 

6152221.00 A 

ISTD Elements 

SO 

1118.00 

109900.00 

4498.00 

2836.00 

7041. 00 

65720.00 

10740.00 

10870.00 

5380.00 

33200.00 

2053.00 

263100.00 

348.60 

1634.00 

3426.00 

2094.00 

134500.00 

1849.00 

943.60 

2227.00 

1532.00 

591. 70 

9627.00 

3370.00 

46780.00 

346.10 

87.23 

60.43 

2241. 00 

49300.00 

17670.00 

306.00 

13880.00 

174.50 

3386.00 

117700.00 

14060.00 

235300.00 

15530.00 

6945.00 

16700.00 

40750.00 

2515.00 

198200.00 

187600.00 

31470.00 

13340.00 

3933.00 

26170.00 

RSD(%) 

0.93 

1.24 

0.49 

0.51 

0.46 

0.92 

0.77 

1.15 

1. 09 

0.88 

0.38 

1.65 

1. 38 

0.50 

0.93 

0.77 

0.40 

0.36 

0.73 

0.65 

0.92 

0.73 

1. 00 

0.99 

1. 39 

0.59 

0.35 

0.94 

0.45 

0.81 

0.78 

0.60 

0.50 

0.43 

0.60 

1. 76 

0.39 

1.13 

1.33 

1.10 

0.42 

0.85 

0.30 

0.74 

0.72 

0.70 

0.84 

0.29 

0.43 

Cal Coef 

0.0000 

0.9406 

1. 0000 

1. 0000 

0.9999 

1.0000 

1. 0000 

0.9998 

0.9997 

0.0000 

0.0000 

0.0000 

1.0000 

1. 0000 

1.0000 

0.9944 

1. 0000 

1. 0000 

1. 0000 

0.9990 

0.9989 

0.9931 

0.0000 

0.0000 

0.0000 

1.0000 

1. 0000 

0.9999 

0.9996 

0.9996 

1.0000 

1. 0000 

1. 0000 

1. 0000 

1.0000 

0.0000 

0.0000 

0.0000 

0.9982 

0.9986 

0.9991 

1. 0000 

1. 0000 

0.0000 

0.0000 

1.0000 

1.0000 

1.0000 

1.0000 

Element CPS Mean RSD(\) Ref Value 

-131996.50 

Rec (%) QC Range (\) 

Li -119622.90 0.93 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3771471.80 0.88 3646344.80 

545941.44 0.38 537987.94 

15972640.00 

958901.94 

338705.66 

1.65 17012292.00 

1.00 949396.31 

0.99 338792.91 

3377176.50 1.39 3456710.80 

6690474.50 1.766610579.00 

3596723.50 0.39 3651775.30 

20753860.00 1.13 22769202.00 

26839886.00 0.74 28649686.00 

25972036.00 0.72 27453282.00 

90.6 70 -

103.4 

101. 5 

93.9 

101.0 

100.0 

97.7 

101. 2 

98.5 

91.1 

93.7 

94.6 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File : C, \ICPCHEM\l \DATA \12 I 26qOO . B\004CALB. D\004CALB. DD 

; Element Failures 

1 ; ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

;Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C. \ ICPCHEM\1 \RPTTMP\CalStdx.qct 

Flag 

IS Fail 

Page 1 of 1 
87

C, \ICPCHEM\l \DATA \12126qOO .S\OOB_QCS. D\OOB_QCS. of 

QCS QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12126qOO.8\008_QCS.D\008_QCS.D# 

Sep 26 2012 05,21 pm 

Sample Name: 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Dil Factor, 

NBS 

ICV 120926 

1107 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

QCS 

1. 00 

QC Elements 

Element Cone. RSD(%) Expected QC Range(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 v 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (pb) 

208 Pb 

ug/l 

35.25 ug/l 

38.88 ug/l 

3686.00 ug/l 

4070.00 ug/l 

3530.00 ug/l 

3732.00 ug/l 

3778.00 ug/l 

26.98 ug/l 

40.08 ug/l 

40.67 ug/l 

39.29 ug/l 

3954.00 ug/l 

39.83 ug/l 

40.94 ug/l 

40.06 ug/l 

39.97 ug/l 

33.20 ug/l 

36.79 ug/l 

35.84 ug/l 

36.44 ug/l 

37.73 ug/l 

37.43 ug/l 

34.52 ug/l 

ug/l 

35.49 ug/l 

ug/l 

36.94 ug/l 

2.43 ug/l 

2.74 ug/l 

1.83 ug/l 

34.80 ug/l 

37.13 ug/l 

37.44 ug/l 

ug/l 

ug/l 

37.63 ug/l 

0.82 

1. 44 

1.14 

0.57 

0.59 

0.67 

1. 38 

2.23 

0.85 

0.78 

0.77 

1. 38 

1.07 

0.15 

0.62 

0.37 

1. 38 

0.86 

0.68 

0.90 

0.35 

1. 06 

0.76 

1.13 

0.32 

8.02 

22.16 

12.37 

0.74 

0.44 

0.61 

1. 87 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

Li -134362.28 1.83 -131996.50 

45 Sc 3846838.80 1.27 3646344.80 

45 Sc 541400.81 0.69 537987.94 

45 Sc 16911978.00 0.09 17012292.00 

72 Ge 958731. 75 1. 26 949396.31 

72 Ge 339681.38 2.08 338792.91 

72 Ge 3461235.80 0.95 3456710.80 

115 In 6836313.50 0.53 6610579.00 

115 In 

115 In 

159 Tb 

165 Ho 

3636110.30 

22338996.00 

28408302.00 

27378630.00 

0.59 3651775.30 

0.61 22769202.00 

1.02 28649686.00 

0.72 27453282.00 

100.00 90 110 

40.00 

40.00 

4000.00 

4000.00 

4000.00 

40.00 

4000.00 

40.00 

40.00 

40.00 

40.00 

4000.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

20.00 

20.00 

20.00 

20.00 

20.00 

40.00 

40.00 

40.00 

40.00 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 110 

Rec(%) QC Range(%) 

101.8 

105.5 

100.6 

99.4 

101.0 

100.3 

100.1 

103.4 

99.6 

98.1 

99.2 

99.7 

70 

70 

70 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

70 - 120 

70 - 120 

70 120 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Flag 

IS Fail 

ISTD Ref File, C,\ICPCHEM\1\DATA\12126qOO.8\004CALB.D\004CALB.D# 

13 :Element Failures 0 :Max. Number of Failures Allowed 

1 ,ISTD Failures 0 ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes : Fail 

ISTD: Fail 

9/26/125:25 PM C:\ICPCHEM\l\rpttmp\QCS.qct Page 1 of 1 
88

CCB QC Report 

Data File, 

Date Acquired: 

Operator: 

Sample Name: 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update, 

Sample Type: 

Total Dil Factor: 

QC Blement. 

Element Conc. 

7 (Li) 

9 Be 0.00 

11 B 0.49 

23 Na 0.72 

24 Mg -0.19 

27 Al 1. 48 

39 K 1. 54 

44 Ca -2.41 

47 Ti 0.04 

51 V -0.02 

52 Cr 0.01 

55 Mn -0.02 

56 Fe 0.24 

59 Co 0.00 

60 Ni -0.07 

63 Cu 0.00 

65 CU -0.01 

66 Zn 0.02 

75 As 0.01 

78 Se 0.01 

78 Se 0.20 

88 Sr -0.02 

88 Sr 0.00 

95 Mo 0.03 

106 (Cd) 

107 Ag 0.00 

108 (Cd) 

111 Cd 0.01 

118 Sn 0.19 

118 Sn 0.00 

118 Sn 0.12 

121 Sb 0.03 

137 Ba -0.01 

205 TI 0.01 

206 (Pb) 

207 (Pb) 

208 Pb 0.00 

ISTD Element. 

Element CPS Mean 

6 Li -122884.55 

45 Sc 3477002.80 

45 Sc 528808.06 

45 Sc 16805466.00 

72 Ge 914926.44 

72 Ge 338749.25 

72 Ge 3416004.80 

115 In 6345123.50 

115 In 3602017.00 

115 In 22248522.00 

159 Tb 27758682.00 

165 Ho 26702446.00 

ISTD Ref File : 

: Element Failures 

:ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9126112 5:38 PM 

C, \ ICPCHEM\1 \OATA\12I26qOO. B\OlO_CCB. O\OlO_CCB .of 

C,\ICPCHEM\1\DATA\12I26qOO.B\010_CCB.D\010_CCB.D# 

Sep 26 2012 05,34 pm 

NBS 

ICB 120926 

1102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

CCB 

1. 00 

RSD(%) High Limit 

ug/l ####### 

ug/l 91.54 0.12 

ug/l 10.59 15.00 

ug/l 95.39 77.10 

ug/l 110.05 7.50 

ug/l 100.34 3.96 

ug/l 174.71 19.20 

ug/l 63.12 90.00 

ug/l 160.32 0.78 

ug/l 33.46 0.21 

ug/l 39.14 0.12 

ug/l 121.97 0.18 

ug/l 31.62 40.80 

ug/l 242.04 0.09 

ug/l 6.31 0.48 

ug/l 206.18 0.39 

ug/l 71.58 0.39 

ug/l 245.26 6.90 

ug/l 15.42 0.27 

ug/l 185.45 0.30 

ug/l 50.12 0.30 

ug/l 53.22 0.03 

ug/l 565.80 0.03 

ug/l 13.51 0.21 

ug/l ####### 

ug/l 3791.20 0.09 

ug/l ####### 

ug/l 111.74 0.06 

ug/l 90.51 ####### 

ug/l 2695.20 ####### 

Flag 

ug/l 30.72 0.30 

ug/l 9.56 0.03 Fail rJ'1 

ug/1 89.88 0.12 

ug/l 15.53 0.03 

ug/l ####### 

ug/l ####### 

ug/l 95.16 0.33 

RSD (%) . Ref Value Rec(%) QC Range(%) Flag 

5.56 -131996.50 93.1 70 - 120 IS FaL 1'1""'( 

4.24 3646344.80 95.4 70 120 

1.32 537987.94 98.3 70 - 120 

0.54 17012292.00 98.8 70 - 120 

4.24 949396.31 96.4 70 120 

1. 08 338792 . 91 100.0 70 120 

0.30 3456710.80 98.8 70 - 120 

3.69 6610579.00 96.0 70 120 

1.14 3651775.30 98.6 70 120 

1.71 22769202.00 97.7 70 120 

1.17 28649686.00 96.9 70 - 120 

1. 31 27453282.00 97.3 70 - 120 

C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

0 

0 

:Max. Number 

:Max. Number 

of Failures Allowed 

of ISTD Failures Allowed 

C:\ICPCHEM\I\rpttmp\CCB.qct Page 1 of 1 
89

C: \ICPCIIEM\l \OATA\11I26qOO. B\OllSMPL. O\OllSMPL. O' 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\011SMPL.D\011SMPL.D# 

Sep 26 2012 05:41 pm 

Operator: NBS 

Sample Name: LLICV 120926 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

1103 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

.78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Conc. 

ug/l 

0.89 ug/l 

1. 21 ug/l 

21.79 ug/l 

253.50 ug/l 

90.86 ug/l 

22.57 ug/l 

191. 90 ug/l 

1. 96 ug/l 

0.99 ug/l 

1.09 ug/l 

-0.18 ug/l 

101.10 ug/l 

1. 08 ug/l 

1.10 ug/l 

1.23 ug/l 

1. 21 ug/l 

-0.19 ug/l 

1.03 ug/l 

0.92 ug/l 

1.16 ug/l 

0.61 ug/l 

0.60 ug/l 

1.87ug/1 

ug/l 

0.95 ug/l 

ug/l 

0.97 ug/l 

0.45 ug/l 

0.95 ug/l 

0.72 ug/l 

1. 85 ug/l 

0.94 ug/l 

0.92 ug/l 

ug/l 

ug/l 

0.91 ug/l 

Element CPS Mean RSD(%) 

Li -126401.63 7.40 

45 Sc 3813611.50 0.79 

45 Sc 525005.56 2.09 

Cerro Conc. 

#VALUE! 

0.89 

1. 21 

21.79 

253.50 

90.86 

22.57 

191.90 

1.96 

0.99 

1. 09 

-0.18 

101.10 

1.08 

1.10 

1. 23 

1. 21 

-0.19 

1. 03 

0.92 

1.16 

0.61 

0.60 

1. 87 

#VALUEI 

0.95 

#VALUE! 

0.97 

0.45 

0.95 

0.72 

1. 85 

0.94 

0.92 

#VALUE! 

#VALUE! 

0.91 

Ref Value 

-131996.50 

3646344.80 

537987.94 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

16691403.00 

966428.06 

328401.03 

3403630.30 

6889807.50 

3514611.30 

1.16 17012292.00 

22120702.00 

28237270.00 

27165836.00 

0.21 949396.31 

1.03 338792.91 

1.04 3456710.80 

0.71 6610579.00 

2.19 3651775.30 

1.30 22769202.00 

0.24 28649686.00 

0.69 27453282.00 

RSD(%) 

2.07 

2.41 

9.44 

2.67 

2.52 

16.17 

9.60 

4.49 

3.16 

1.48 

23.95 

1. 93 

1. 62 

3.90 

2.31 

0.72 

17.91 

6.47 

9.12 

22.38 

1. 25 

2.36 

2.64 

3.37 

0.54 

20.86 

17.92 

5.32 

2.39 

3.55 

1. 51 

0.21 

Rec(%) 

95.8 

104.6 

97.6 

98.1 

101.8 

96.9 

98.5 

104.2 

96.2 

97.2 

98.6 

99.0 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 I 0 ., 'I. 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

107,'/' 

0\1. ", 

"11. ", 

'11 'I. 

QC Range(%) 

70 120 

70 120 

70 120 

70 

70 

70 -

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

o :Element Failures 

1 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/12 5:45 PM 

Pass 

Fail 

o :Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\1\rpttmp\Samp1e,qct Page 1 of 1 
90

C I \IC'PCH!l(\l \DATA \13 IlliqOO ,1'\013 lC'SA .0\013 leBA .P~ 

ICS-A QC Report 

Data File: 

Date Acquired: 

Acq. Method, 

Operator: 

Sample Name: 

MIse Info: 

VIal Number: 

Current Method: 

Callbration FIle: 

Last cal. Update, 

Sample Type, 

DilutIon Factor: 

OC Elements 

Element IS Ref Tune 

7 (Ll) 

9 Be 45 

11 B 45 

23 Na 45 

24 Mg 45 

27 Al 45 

39 K 45 

44 Ca 45 

47 Tl 45 

51 V 45 

52 Cr 45 

55 Mn 45 

56 Fe 45 

59 Co 45 

60 Ni 45 

63 cu 45 

65 cu 45 

66 Zn 115 

75 As 115 

78 Se 115 

78 Se 115 

88 Sr 115 

88 Sr 115 

95 Mo 115 

106 (Cd) 

107 Ag 115 

108 (Cd) 

111 cd 115 

118 Sn 115 

118 Sn 115 

118 Sn 115 

121 Sb 115 

137 Ba 115 

205 Tl 159 

206 (Pb) 

207 (Pb) 

208 Pb 159 

ISTD Elements 

Element 

6 Ll 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

2 

2 

2 

2 

2 

3 

3 

3 

3 

Tune 

C,\ICPCHEM\1\DATA\12I26qOO.B\012ICSA.D\012ICSA.D# 

Sep 26 2012 05,48 pm 

CSC-MDL.M 

NBS 

FGD MATRIX 

2101 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

ICSA 

1. 00 

Cone. 

ug/l 

0.00 ug/l 

0.59 ug/l 

887800.00 ug/l 

925800.00 ug/l 

5.60 ug/l 

9.92 ug/l 

1929000.00 ug/l 

0.19 ug/l 

0.15 ug/l 

0.70 ug/l 

-0.56ug/l 

7.65 ug/l 

0.25 ug/l 

1. 43 ug/l 

0.16 ug/l 

0.48 ug/l 

-2.39ug/l 

0.76 ug/l 

0.21 ug/l 

1. 33 ug/l 

122.60 1Jg/l 

122.20 ug/l 

0.10 ug/l 

ug/l 

0.18 ug/l 

ug/l 

0.03 ug/l 

-1.39 ug/l 

0.19 ug/l 

-1.37 ug/l 

2.16 ug/l 

2.23 ug/l 

0.03 ug/l 

ug/l 

ug/l 

1. 63 ug/l 

RSD(%) 

55.33 

9.26 

0.77 

0.44 

10.09 

47.91 

0.49 

67.42 

28.29 

2.88 

38.20 

1. 50 

1.72 

1. 40 

7.62 

6.79 

2.13 

2.60 

13.19 

19.29 

3.79 

12.12 

42.54 

2.92 

20.78 

0.13 

1396.60 

2.63 

2.65 

2.86 

16.42 

2.77 

Data Results: 

Analytes: Fail 

ISTD: Fail 

High Limit ppb 

38.55 

3.75 

45.00 

CPS Mean RSD(%) Ref value Rec(%) QC Range (%) 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

-110792 5.59 

3656943 0.76 

560921 1. 02 

14763353 

828390 

300758 

2781498 

5776089 

3007656 

16366449 

20493616 

19437084 

1.35 

1.52 

0.52 

0.61 

0.80 

0.58 

1. 22 

1. 89 

1. 55 

-131997 83.9 

3646345 100.3 

537988 104.3 

17012292 

949396 

338793 

3456711 

6610579 

3651775 

22769202 

28649686 

27453282 

86.8 

87.3 

88.8 

80.5 

87.4 

82.4 

71.9 

71.5 

70.8 

Tune File# c'\lcpchem\1\7500\h2_hml.u 

Tune Flle# c,\icpchem\1\7500\he_hml.u 

Tune File# c,\icpchem\1\7500\ng_hmi.u 

Flag 

Fail 

Fail 

Fail 

Flag 

IS Fail 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

3 :Element Failures :Max. Number of Failures Allowed 

1 :ISTD FaIlures :Max. Nnumber of ISTD Failures Allowed 

9/26/125:51 PM C:\ICPCHEM\1\RPTTMP\6020ICSA.qct Page 1 of 1 
91

C; \ICPCHEM\l \DnA \1 .. :n 5qOO .B\Ol'3ICSB .D\OUICSB .DII 

ICS-AB QC Report 

Data FIle: 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I26qOO.B\013ICSB.D\013ICSB.DD 

Sep 26 2012 05,54 pm 

Acq. Method, 

Operator: 

sample Name: 

Mise Info: 

Vial Number: 

Current Method: 

CalIbration FIle: 

Last Cal. Update: 

Sample Type, 

DIlutIon Factor: 

QC Elements 

CSC-MDL.M 

NBS 

FGD MATRIX SPIKED 

2102 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

sep 26 2012 05,19 pm 

ICSAB 

1. 00 

Element IS Ref Tune Conc. ppb RSD(%) Expected 

100 

40 

40 

5000 

5000 

4000 

7 (Ll) --------.------. 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Nl 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 5e 

79 Se 

88 5r 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

109 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

209 Pb 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

159 

159 

ISTD Elements 

Element 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

2 

2 

2 

3 

1 

2 

Tune 

2 

3 

3 

3 

31.36 2.52 

34.13 1.42 

775200.00 1.43 

902700.00 1.98 

3712.00 1.79 

3866.00 1.58 

1671000.00 1.30 

31.08 12.75 

41.67 1.76 

40.28 1.86 

38.01 2.01 

3695.00 2.21 

36.56 

36.64 

33.83 

33.99 

33.47 

52.03 

53.84 

59.91 

149.30 

144.40 

40.94 

1. 89 

2.51 

1. 74 

1.66 

1. 02 

0.95 

0.40 

1.02 

0.99 

2.17 

1. 90 

34.151.98 

37.96 2.02 

1.2320.45 

1.14 25.27 

1.25 29.52 

40.03 2.06 

42.38 2.60 

33.16 1.63 

31.29 1.14 

CPS Mean RSD (%) 

-104032 3.51 

3858832 0.06 

560798 2.59 

15475736 

856279 

304597 

2969213 

5987052 

3029399 

17056412 

21157712 

20205690 

2.13 

0.56 

0.12 

0.91 

0.95 

0.83 

2.26 

1. 60 

1. 71 

40 

6000 

40 

40 

40 

40 

4000 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

20 

20 

20 

20 

20 

40 

40 

40 

40 

Ref Value 

-131997 

3646345 

537988 

17012292 

949396 

338793 

3456711 

6610579 

3651775 

22769202 

28649686 

27453292 

Tune FileD c'\lcpchem\1\7500\h2_hmi.u 

Tune FileD 2 c'\lcpchem\1\7500\he_hmi.u 

Tune FileD 3 c'\lcpchem\1\7500\ng_hml.u 

%Recovery 

#VALUEI 

78.4 

85.3 

15504.0 

16054.0 

92.8 

9665.0 

27850.0 

77.7 

104.2 

100.7 

95.0 

92.4 

91.4 

91.6 

84.6 

85.0 

83.7 

130.1 

134.6 

149.8 

373.3 

361.0 

102.4 

#VALUEI 

85.4 

#VALUEI 

94.9 

62 

5.7 

6.2 

200.2 

211.9 

82.9 

#VALUEI 

#VALUEI 

78.2 

Rec(%) 

78.8 

105.8 

104.2 

91. 0 

90.2 

89.9 

85.9 

90.6 

83.0 

74.9 

73.8 

73.6 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DD 

Data Results: 

Analytes: Fail 

ISTD: Fail 

QC Range (%) 

70 130 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

130 

.130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

QC Range (%) 

70 120 

70 120 

70 120 

70 

70 

70 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

:Elernent Failures 

1 :ISTD FaIlures 

:Max. Number of FaIlures Allowed 

:Max. Number of ISTD Failures Allowed 

Flag 

Fall 

Fall 

Fail 

Fall 

Fail 

Fall 

Fail 

Flag 

I S Fall 

9126/12 5:58 PM C:\ICPCHEM\1\RPTTMP\6020ICSB.qct Page 1 of1 
92

C, \ICPCHEM\l \DATA\12126qOO .B\OlS_CCV .D\OlS_CCV. 01 

CCV QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name: 

C,\ICPCHEM\1\DATA\12I26qOO.B\015_CCV.D\015_CCV.D# 

Sep 26 2012 06,08 pm 

Mise Info: 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Oil Factor, 

NBS 

CCV 120926 

1106 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

CCV 

1. 00 

QC Blements 

Element Cone. RSD (%) Expected QC Range (%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/1 

94.77 ug/l 

94.19 ug/l 

2529.00 ug/l 

24840.00 ug/l 

9751.00 ug/l 

1992.00 ug/l 

24450.00 ug/l 

197.40 ug/l 

99.95 ug/l 

99.90 ug/l 

99.19 ug/l 

9857.00 ug/l 

100.20 ug/l 

99.93 ug/l 

99.71 ug/l 

99.12 ug/l 

98.97 ug/l 

100.10 ug/l 

98.18 ug/l 

98.64 ug/l 

98.85 ug/l 

99.05 ug/l 

196.50 ug/l 

ug/l 

97.22 ug/l 

ug/l 

96.71 ug/l 

195.30 ug/l 

196.90 ug/l 

196.30 ug/l 

195.60 ug/l 

97.85 ug/l 

95.78 ug/l 

ug/l 

ug/l 

95.21 ug/l 

50.00 90 - 110 

0.55 

0.61 

50.00 

50.00 

0.44 1250.00 

0.62 12500.00 

0.28 5000,00 

0.82 1000,00 

0.32 12500.00 

0.66 .100.00 

0.82 

0.96 

0.70 

0.26 

0.83 

0.92 

0.16 

0.29 

1.15 

0.15 

0.53 

0,71 

0.60 

0.31 

0.65 

0.97 

50.00 

50.00 

50.00 

500.00 

50,00 

50,00 

50.00 

50.00 

50.00 

50,00 

50,00 

50.00 

50,00 

50.00 

100,00 

50.00 

50.00 

50.00 

90 - 110 

90 - 110 

90 

90 -

90 -

90 -

110 

110 

110 

110 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

0.45 

0.52 

0.12 

0.54 

0.73 

0.92 

1.10 

50.00 90 - 110 

1. 34 

100.00 

100,00 

50.00 

50.00 

50.00 

50.00 

50.00 

##### - ##### 

##### - ##### 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-115650.49 

3684740.30 

512384.28 

16709469.00 

925152.69 

324210.50 

3528030.30 

6520419.50 

3350236.30 

21373888.00 

27624948.00 

26691872.00 

7.51 

0.36 

0.20 

0.37 17012292.00 

0.72 949396.31 

1.36 338792.91 

0.47 

0.49 

0.34 

3456710.80 

6610579.00 

3651775.30 

0.12 22769202.00 

1.35 28649686.00 

1.40 27453282.00 

Rec(%) QC Range(%) 

87.6 

101.1 

95.2 

98.2 

97,4 

95,7 

102.1 

98.6 

91.7 

93.9 

96.4 

97.2 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

Flag 

I' . 

Fa'l 

Fa'l 

Fa 1 

Fa 

Fa 

Fa 

Fa 

Fa 

Fa 

Fa 

Fa' 

F '1 

F '1 

F il 

Fil 

F il 

Fil 

F i 1 

F il 

F il 

F il 

Fil 

F il 

F il 

F il 

F il 

F il 

F il 

'1 

Flag 

IS Fail 

I STD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB D\004CALB.D# 

30 :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o ,Max, Number of ISTD Failures Allowed 

"t S -g'/, 

'\-:;.2 'I· 

9/26/126:11 PM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
93

CCB QC Report 

Data File: 

Date Acquired: 

Operator: 

Sample Name: 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

Sample Type: 

Total Dil Factor: 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 0.01 

11 B 0.79 

23 Na 12.81 

24 Mg 12.50 

27 Al -0.27 

39 K 7.65 

44 Ca 3.76 

47 Ti 0.17 

51 V -0.01 

52 Cr 0.00 

55 Mn -0.06 

56 Fe 0.38 

59 Co 0.00 

60 Ni -0.07 

63 Cu 0.00 

65 CU 0.00 

66 Zn -0.05 

75 As 0.02 

78 Se 0.02 

78 Se 0.68 

88 Sr -0.03 

88 Sr 0.02 

95 Mo 0.05 

106 (Cd) 

107 Ag 0.00 

108 (Cd) 

111 Cd 0.00 

118 Sn 0.39 

118 Sn 0.15 

118 Sn 0.26 

121 Sb 0.07 

137 Ba 0.01 

205 TI 0.01 

206 (Pb) 

207 (Pb) 

208 Pb 0.00 

ISTD Blements 

Element CPS Mean 

Li -129076.62 

45 Sc 3443597.30 

45 Sc 515338.28 

45 Sc 16949942.00 

72 Ge 884837.38 

72 Ge 319274.75 

72 Ge 3499408.30 

115 In 6140074 .00 

115 In 3416706.80 

115 In 22334394.00 

159 Tb 27860248.00 

165 Ho 26780708.00 

ISTD Ref File : 

: Elemenc Failures 

1 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/126:25 PM 

C, \ICPCIIEM\1 \OATA\12I26qOO. B\017 _CCB .0\017 _CCB .0# 

C:\ICPCHEM\1\DATA\12I26qOO.B\017_CCB.D\017_CCB.D# 

Sep 26 2012 06:21 pm 

NBS 

CCB 120926 

1102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

CCB 

1.00 

RSD (%) High Limit 

ug/l ####### 

ug/l 175.35 0.12 

ug/l 20.15 15.00 

ug/l 7.79 77.10 

ug/l 152.96 7.50 

ug/l 74.80 3.96 

ug/l 31.96 19.20 

ug/l 267.22 90.00 

ug/l 134.86 0.78 

ug/l 123.08 0.21 

ug/l 191.20 0.12 

ug/l 35.73 0.18 

ug/l 27.96 40.80 

ug/l 335.05 0.09 

ug/l 20.53 0.48 

ug/l 47494.00 0.39 

ug/l 61.08 0.39 

ug/l 85.34 6.90 

ug/l 7.57 0.27 

ug/l 43.78 0.30 

ug/l 8.28 0.30 

ug/l 116.39 0.03 

ug/l 16.72 0.03 

ug/l 9.86 0.21 

ug/l ####### 

ug/l 47.19 0.09 

ug/l ####### 

ug/l 310.18 0.06 

ug/l 33.80 ####### 

ug/l 80.69 ####### 

ug/l 49.64 0.30 

ug/l 5.97 0.03 

ug/l 54.85 0.12 

ug/l 8.23 0.03 

ug/l ####### 

ug/l ####### 

ug/l 41. 39 0.33 

RSD(%) Ref Value Rec(%) QC Range(%) 

8.06 -131996.50 97.8 70 -

3.19 3646344.80 94.4 70 -

2.12 537987.94 95.8 70 -

0.60 17012292.00 99.6 70 -

3.54 949396.31 93.2 70 -

1. 60 338792.91 94.2 70 -

0.24 3456710.80 101. 2 70 -

3.91 6610579.00 92.9 70 -

0.44 3651775.30 93.6 70 -

0.65 22769202.00 98.1 70 -

0.72 28649686.00 97.2 70 

1.14 27453282.00 97.6 70 

Flag 

Fail ,J-(" 

Fail tJ-( 

Fail t' "\ 

Flag 

120 IS FaL t1 120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

:Max. 

:Max. 

Number 

Number 

of Failures Allowed 

of ISTD Failures Allowed 

1 --

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
94

C: \ICPCHEM\1\DATA\12126qOO. B\019SMPL. D\019SMPL. DN 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\019SMPL.D\019SMPL.D# 

Sep 26 2012 06:34 pm 

Operator: NBS 

Sample Name: FGD ICS - Chloride 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

3101 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1.00 

QC Elements 

Element Cone. Carr. Cone. 

#VALUE! 

-0.02 

0.32 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

-0.02 ug/l 

0.32 ug/l 

2926000.00 ug/l 

11.54 ug/l 

-5.77 ug/l 

99.82 ug/l 

-37.33 ug/l 

-0.09 ug/l 

0.04 ug/l 

0.01 ug/l 

-0.63 ug/l 

-4.44 ug/l 

0.69 ug/l 

-0.10 ug/l 

0.02 ug/l 

-0.03 ug/l 

-3.36 ug/l 

0.17 ug/l 

0.14 ug/l 

1.78 ug/l 

4.62 ug/l 

4.26 ug/l 

0.06 ug/l 

ug/l 

0.16 ug/l 

ug/l 

0.00 ug/l 

-3.44 ug/l 

-3.71 ug/l 

-3.25 ug/l 

0.00 ug/l 

0.19 ug/l 

-0.02 ug/l 

ug/l 

ug/l 

-0.02 ug/l 

2926000.00 

11.54 

-5.77 

99.82 

-37.33 

-0.09 

0.04 

0.01 

-0.63 

-4.44 

0.69 

-0.10 

0.02 

-0.03 

-3.36 

0.17 

0.14 

1. 78 

4.62 

4.26 

0.06 

#VALUE! 

0.16 

#VALUE! 

0.00 

-3.44 

-3.71 

-3.25 

0.00 

0.19 

-0.02 

#VALUE! 

#VALUE! 

-0.02 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

Li -97970.58 5.63 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

2923316.80 

432408.34 

12321775.00 

725016.50 

253589.20 

2414153.80 

5133755.00 

2604404.30 

14781928.00 

18922060.00 

18154954.00 

2.52 

1.99 

3.34 17012292.00 

2.15 949396.31 

2.74 338792.91 

3.28 3456710.80 

1.34 6610579.00 

2.96 3651775.30 

3.47 22769202.00 

3.33 28649686.00 

3.46 27453282.00 

RSD(%) 

13 .06 

18.17 

1. 03 

16.01 

29.80 

3.13 

22.45 

23.95 

23.54 

102.78 

5.50 

42.06 

1.95 

14 .43 

35.58 

78.93 

1.16 

3.00 

3.36 

26.10 

0.94 

1.38 

5.52 

2.07 

616.04 

0.70 

0.22 

0.11 

29.08 

10.22 

6.15 

11.08 

Rec(%) 

74.2 

80.2 

80.4 

72 .4 

76.4 

74.9 

69.8 

77.7 

71. 3 

64.9 

66.0 

66.1 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range (%) 

Flag 

>Cal 

70 120 

Flag 

IS Fai 

70 120 

70 120 

70 

70 -

70 -

70 -

70 -

70 

70 

70 

70 

120 

120 

120 

120 IS Fai 

120 

120 

120 IS Fai 01( 

120 IS Fai 01<-

120 IS Fai ,..s\ 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Elernent Failures 

5 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/12 6:38 PM 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHBM\l\rpttmp\Sample.qct Page 1 of 1 
95

C, \ ICPCHEM\ 1 \DATA\12126qoO. B\020SMPL. D\020SMPL. Df 

Sample QC Report 

Data File: 

Date Acquired: 

C,\ICPCHEM\1\DATA\12126qOO.B\020SMPL.D\020SMPL.D# 

Sep 26 2012 06:41 pm 

Operator: NBS 

Sample Name: FGD ICS - Calcium 

Mise Info: 

vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type, 

Prep Oil Factor: 

Sample 

1. 00 

Total oil Factor: 1. 00 

QC Elements 

Element Cone. 

7 (Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.03 ug/l 

1.10 ug/l 

589.90 ug/l 

272.90 ug/l 

37.44 ug/l 

53.83 ug/l 

4769000.00 ug/l 

7.07 ug/l 

1.13 ug/l 

3.44 ug/l 

-0.13 ug/l 

106.50 ug/l 

0.98 ug/1 

7.69 ug/l 

9.30 ug/l 

9.91 ug/l 

29.16 ug/l 

4.04 ug/l 

0.42 ug/l 

3.17 ug/l 

43.22 ug/l 

42.60 ug/l 

0.22 ug/l 

ug/l 

0.07 ug/l 

ug/l 

3.32 ug/l 

-2.07 ug/l 

-2.24 ug/l 

-2.28 ug/l 

0.33 ug/l 

8.83 ug/l 

0.11 ug/l 

ug/l 

ug/l 

1.08 ug/l 

ISTD Elements 

Element CPS Mean RSD (%) 

3.07 

0.69 

Cerro Cone. 

#VALUEI 

0.03 

1.10 

589.90 

272.90 

37.44 

53.83 

4769000.00 

7.07 

1.13 

3.44 

--0.13 

106.50 

0.98 

7.69 

9.30 

9.91 

29.16 

~ 

4.04 

0.42 

3.17 

43.22 

42.60 

0.22 

#VALUEI 

0.07 

#VALUEI 

3.32 

-2.07 

-2.24 

-2.28 

0.33 

8.83 

0.11 

#VALUEI 

#VALUEI 

1. 08 

Ref Value 

-131996.50 

3646344.80 

0.44 537987.94 

1.72 17012292.00 

0.46 949396.31 

1.21 338792.91 

RSD(%) 

22.42 

4.69 

17 .39 

1. 66 

109.56 

6.99 

0.46 

5.07 

0.53 

0.66 

21. 90 

2.15 

2.40 

2.53 

0.38 

1. 31 

0.68 

3.40 

14.19 

4.84 

0.97 

1. 69 

3.01 

2.98 

2.00 

3.81 

2.05 

0.71 

3.12 

1. 81 

3.08 

1. 88 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

Flag 

,Cal 

Flag 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

"rr Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-83282.44 

3097643.00 

425698.88 

11544175.00 

660715.13 

227209.55 

2161734.00 

4817941.50 

2300628.80 

1.21 3456710.80 

0.44 6610579.00 

0.40 3651775.30 

1.26 22769202.00 

1. 48 28649686.00 

1.73 27453282.00 

Rec(%) 

63.1 

85.0 

79.1 

67.9 

69.6 

67.1 

62.5 

72.9 

63.0 

57.9 

55.7 

55.0 

70 

70 

70 -

70 -

70 -

120 

120 

120 

120 

120 

-t vD- ,1.,.;;1. IS Fai 0 k. l-\.'vV' ' 

13191882.00 

15965009.00 

15107971. 00 

ISTD Ref File : 

1 :Element Failures 

9 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/12 6:45 PM 

IS Fai 

IS Fai 

IS Fai tJI 

C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
96

C, \ ICPCHEM\1 \DATA\12126qOO. B\021SMPL. D\021SMPL. Dt 

Sample QC Report 

Data File, 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I26qOO.B\021SMPL.D\021SMPL.DU 

Sep 26 2012 06,48 pm 

Operator, 

Sample Name, 

Mise Info: 

NBS 

FGD ICS - Sulfate 

Vial Number, 

CUrrent Method, 

Calibration File, 

Last Cal Update, 

Sample Type, 

3103 

C,\ICPCHEM\l\METHODS\CSC-MDL M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1. 00 

1. 00 

QC Elements 

Element Conc. Carr. Conc. 

#VALUE! 

-0.01 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

-0.01 ug/l 

-0.14 ug/l 

404.00 ug/l 

2.09 ug/l 

-3.51 ug/l 

2894000.00 ug/l 

531.00 ug/l 

0.03 ug/l 

0.06 ug/l 

0.12 ug/l 

-0.80 ug/l 

-0.13 ug/l 

0.02 ug/l 

-0.01 ug/l 

0.75ug/l 

0.78 ug/l 

0.78 ug/l 

0.14 ug/l 

3.45 ug/l 

3.00 ug/l 

0.81 ug/l 

0.73 ug/l 

1.10 ug/l 

ug/l 

0.00 ug/l 

ug/l 

0.00 ug/l 

-3.13 ug/l 

-3.34 ug/l 

-2.92 ug/l 

0.14 ug/l 

0.89 ug/l 

0.05 ug/l 

ug/l 

ug/l 

0.01 ug/l 

-0.14 

404.00 

2.09 

-3.51 

2894000.00 

531.00 

0.03 

0.06 

0.12 

-0.80 

-0.13 

0.02 

-0.01 

0.75 

0.78 

0.78 

0.14 

3.45 

- 3.00 

0.81 

0.73 

1.10 

UVALUE! 

0.00 

UVALUE! 

0.00 

-3.13 

-3.34 

-2.92 

0.14 

0.89 

0.05 

UVALUE! 

UVALUE! 

0.01 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

6 Li -103139.68 3.34 -131996.50 

45 Sc 2787913.50 1.57 3646344.80 

45 Sc 430391.03 1.66 537987.94 

45 Sc 11817731.00 1.03 17012292.00 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

660532.75 

243915.70 

2305505.50 

4706154.50 

2457743.80 

14441559.00 

18234338.00 

17415250.00 

1.62 949396.31 

2.08 338792.91 

0.72 3456710.80 

2.71 6610579.00 

0.58 3651775.30 

1.56 22769202.00 

1.24 28649686.00 

0.82 27453282.00 

RSD(%) High Limit 

o 26.45 1000 

48.85 1000 

2.24 25000 

271.02 50000 

15.28 20000 

0.65 20000 

2.99 50000 

311.36 1000 

4.31 1000 

25.09 1000 

22.60 1000 

1003.80 20000 

18.60 

90.57 

2.11 

4.55 

11.37 

8.09 

10.98 

8.16 

4.29 

4.62 

2.61 

44.94 

294.99 

0.35 

0.56 

0.44 

3.12 

4.26 

16.15 

8.53 

Rec(%) 

78.1 

76.5 

80.0 

69.5 

69.6 

72 .0 

66.7 

71.2 

67.3 

63.4 

63.6 

63.4 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

#UUU#U# 

500 

#UU##U# 

1000 

UUUU#UU 

UUUUU#U 

1000 

1000 

1000 

1000 

UU#UU#U 

UUUU#U# 

1000 

QC Range(%) 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 120 

Flag 

,Cal 

Flag 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

IS Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU 

:Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/126:51 PM 

Fail 

Fail 

:Max. Number of Failures Allowed 

'Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
97

c, \ ICPCHEM\l \DATA\12126qOO. B\022SMPL.D\022SMPL. Df 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I26qOO.B\022SMPL.D\022SMPL.Dn 

Sep 26 2012 06,54 pm 

NBS 

Sample Name, FGD ICS - Magnesium 

Mise Info: 

vial Number: 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3104 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total oil Factor: 

1.00 

1.00 

QC Blements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 v 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.04 ug/l 

2.10 ug/l 

337.70 ug/l 

2880000.00 ug/l 

150.80 ug/l 

441.20 ug/l 

330.10 ug/l 

33.76 ug/l 

2.14 ug/l 

3.09 ug/l 

102.00 ug/l 

68.45 ug/l 

0.10 ug/l 

4.20 ug/l 

9.38 ug/l 

9.27 ug/l 

8.95 ug/l 

1.11 ug/l 

0.14 ug/l 

2.57 ug/l 

-0.24 ug/l 

-0.05 ug/l 

0.08 ug/l 

ug/l 

0.06 ug/l 

ug/l 

0.05 ug/l 

-1.75 ug/l 

-1.88 ug/l 

-2.06 ug/l 

0.41ug/l 

0.58 ug/l 

0.08 ug/l 

ug/l 

ug/l 

1.69 ug/l 

ISTD Elements 

Cerro Cone. 

nVALUE! 

0.04 

2.10 

337.70 

2880000.00 

150.80 

441.20 

330.10 

33.76 

2.14 

3.09 

102.00 

68.45 

0.10 

4.20 

9.38 

9.27 

8.95 

2.2-L 

0.14 

2.57 

-0.24 

-0.05 

0.08 

nVALUE! 

0.06 

nVALUE! 

0.05 

-1.75 

-1.88 

-2.06 

0.41 

0.58 

0.08 

nVALUE! 

nVALUE! 

1. 69 

RSD(%) 

97.32 

7.97 

19.52 

0.95 

124.60 

20.79 

7.64 

1. 02 

3.60 

4.18 

0.62 

1.16 

6.95 

1. 09 

0.90 

2.44 

2.02 

2.98 

4.65 

2.99 

6.77 

89.20 

16.44 

6.40 

50.30 

3.32 

2.46 

1. 78 

4.25 

8.06 

2.97 

2.71 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

nnnnnnn 500 

nnnnnnn 1000 

nnnnnnn 

nnnnnnn 1000 

1000 

1000 

1000 

nnnnnnn 

nnnnnnn 1000 

Flag 

>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Rec(%) QC Range(%) Flag 

6 Li -109873.66 8.12 

45 Sc 3335598.50 1.49 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

470870.91 

13922356.00 

822159.63 

280261. 97 

2701303.00 

5375041.50 

2589054.50 

16211134.00 

21408504.00 

20714622.00 

1.22 537987.94 

2.31 17012292.00 

0.92 949396.31 

1.66 338792.91 

1.42 3456710.80 

0.49 6610579.00 

0.13 3651775.30 

1.94 22769202.00 

2.97 28649686.00 

3.09 27453282.00 

83.2 70 120 IS Fai 

91.5 70 120 

87.5 

81.8 

86.6 

82.7 

78.1 

81. 3 

70.9 

71. 2 

74.7 

75.5 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

:Element Failures :Max. Number of Failures Allowed 

1 ,ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/26/126.58 PM C,\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
98

c: \ICPCHEM\ 1 \DATA \1212 6qOO. B\02 JSMPL. 0\0 2JSMPL. D# 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\023SMPL.D\023SMPL.DU 

Sep 26 2012 07:01 pm 

Operator: NBS 

Sample Name: FGD ICS - Sodium 

Mise Info: 

Vial Number: 

current Method: 

Calibration File: 

Last Cal Update: 

3105 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Oil Factor: 1. 00 

Total Oil Factor: 1. 00 

QC Elements 

Element Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.08 ug/l 

-0.17 ug/l 

1773000.00 ug/l 

249.00 ug/l 

-1.01 ug/l 

296.40 ug/l 

303.40ug/l 

0.33 ug/l 

1.58ug/l 

0.37 ug/l 

-0.85 ug/l 

17.00 ug/l 

0.04 ug/l 

0.28 ug/l 

0.42 ug/l 

0.40 ug/l 

8.15 ug/l 

0.86 ug/l 

0.16 ug/l 

2.58 ug/l 

1.03 ug/l 

1.10 ug/l 

0.10ug/l 

ug/l 

0.05 ug/l 

ug/l 

0.10 ug/l 

-1.51 ug/l 

-1.60 ug/l 

-1. 61 ug/l 

0.49 ug/l 

0.40 ug/l 

0.02 ug/l 

ug/l 

ug/l 

0.17 ug/l 

ISTD Elements 

Carr. Cone. 

UVALUE! 

0.08 

-0.17 

1773000.00 

249.00 

-1.01 

296.40 

303.40 

0.33 

1.58 

0.37 

-0.85 

17.00 

0.04 

0.28 

0.42 

0.40 

8.15 

0.86 

0.16 

2.58 

1. 03 

1.10 

0.10 

UVALUE! 

0.05 

UVALUE! 

0.10 

-1.51 

-1. 60 

-1.61 

0.49 

0.40 

0.02 

UVALUE! 

UVALUE! 

0.17 

RSD (%) 

2.49 

31. 36 

0.88 

1. 54 

40.82 

2.83 

4.27 

31.09 

0.74 

3.95 

4.28 

26.14 

3.43 

6.99 

13 .51 

26.22 

1.62 

0.80 

7.41 

15.28 

7.32 

7.09 

12.16 

7.76 

24.03 

6.27 

7.38 

5.93 

5.45 

10.89 

21.61 

9.40 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

Flag 

:>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

Rec(%) 

73.7 

85.4 

81. 0 

78.8 

85.5 

84.1 

78.4 

79.0 

70.5 

70.1 

70.5 

70.9 

QC Range (%) Flag 

Li -97277.94 7.98 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3114489.00 

436024.88 

13410355.00 

811870.75 

284784.84 

2710904.00 

5222633.00 

2574462.80 

15969458.00 

20204874.00 

19470320.00 

1.09 3646344.80 

1.51 537987.94 

6.38 17012292.00 

2.82 949396.31 

1.63 338792.91 

3.90 3456710.80 

1.016610579.00 

1.16 3651775.30 

7.04 22769202.00 

8.32 28649686.00 

8.09 27453282.00 

70 - 120 IS Fai 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 

70 -

70 

70 -

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU 

:Element Failures :Max. Number of Failures Allowed 

:ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9126112 7:05 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
99

C, \ICPCIIEM\l \DATA\12126qOO. B\0245MPL. D\0245MPL. D' 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I26qOO.B\024SMPL.D\024SMPL.D# 

Sep 26 2012 07,08 pm 

NBS 

Sample Name: FGD ICS - Boron 

Mise Info: 

Vial Number, 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3106 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1.00 

1.00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

7B Se 

7B Se 

BB Sr 

BB Sr 

95 Mo 

106 (Cd) 

107 Ag 

lOB (Cd) 

111 Cd 

11B Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

Cone. 

ug/l 

0.00 ug/l 

474200.00 ug/l 

347.40 ug/l 

53.09 ug/l 

3.96 ug/l 

74.70 ug/l 

344.60 ug/l 

0.04 ug/l 

0.53 ug/l 

0.04 ug/l 

-1.17 ug/l 

-4.14 ug/l 

-0.01 ug/l 

-0.03 ug/l 

2.45 ug/l 

2.39 ug/l 

3.80 ug/l 

0.21 ug/l 

0.03 ug/l 

1.17 ug/l 

-0.20 ug/l 

-0.15 ug/l 

0.07 ug/l 

ug/l 

0.01 ug/l 

ug/l 

-0.01 ug/l 

-2.65 ug/l 

-2.83 ug/l 

-2.65 ug/l 

0.18 ug/l 

0.00 ug/l 

0.01 ug/l 

ug/l 

ug/l 

-0.01 ug/l 

ISTD Elements 

Carr. Conc. 

#VALUE! 

0.00 

474200.00 

347.40 

53.09 

3.96 

74.70 

344.60 

0.04 

0.53 

0.04 

-1.17 

-4.14 

-0.01 

-0.03 

2.45 

2.39 

3.80 

0.21 

0.03 

1.17 

-0.20 

-0.15 

0.07 

#VALUEJ 

0.01 

#VALUE! 

-0.01 

-2.65 

-2. B3 

-2.65 

0.18 

0.00 

0.01 

#VALUE! 

#VALUEJ 

-0.01 

RSD(%) 

193.78 

0.60 

1. 55 

4.81 

14.76 

2.15 

73.97 

102.30 

7.45 

13 .38 

0.61 

1. 28 

21.11 

32.76 

1. 31 

2.71 

4.95 

9.04 

34.68 

4.31 

5.48 

3.36 

8.62 

25.58 

27.42 

0.50 

0.79 

0.45 

3.24 

637.20 

27.14 

17.99 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Rec (%) 

91.4 

101.3 

92.2 

QC Range (%) Flag 

Li -120613.04 3.31 70 120 IS Fai 

45 Sc 3693170.50 0.72 70 120 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

495B89.19 

17132572.00 

878855.44 

303641.69 

3229729.50 

6438535.50 

3274603.00 

23372748.00 

28895424.00 

27893406.00 

ISTD Ref File , 

:Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/127:12 PM 

1.53 537987.94 

0.66 17012292.00 

1.43 949396.31 

0.30 338792.91 

1.09 3456710.80 

0.80 6610579.00 

0.58 3651775.30 

0.73 22769202.00 

0.30 28649686.00 

0.25 27453282.00 

100.7 

92 .6 

89.6 

93.4 

97.4 

89.7 

102.7 

100.9 

101. 6 

70 120 

70 120 

70 - 120 

70 - 120 

70 

70 

70 -

70 -

70 

70 

120 

120 

120 

120 

120 

120 

C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C,\ICPCHEM\l\rpttmp\Sampla.qct Page 1 of 1 
100

C, \ICPCIIEM\l \DATA\12I26qOO .• \02SSMPL.D\02SSMPL. Df 

Sample QC Report 

Dat.a File: 

Date Acquired: 

C:\lCPCHEM\1\DATA\12I26qOO.B\025SMPL.D\025SMPL.Dn 

Sep 26 2012 07:+5 pm 

Operat.or: NBS 

Sample Name: FGD lCS - I ron 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3107 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALlB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep oil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. Cerro Cone. 

nVALUEI 

0.01 

1938.00 

176.90 

8.03 

1. 50 

60.21 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.01 ug/l 

1938.00 ug/l 

176.90 ug/l 

8.03 ug/l 

1.50 ug/l 

60.21 ug/l 

331.60 ug/l 

0.21 ug/l 

0.68 ug/l 

1.11ug/l 

6.76 ug/l 

458500.00 ug/l 

6.65 ug/l 

4.55 ug/l 

2.64 ug/l 

2.61 ug/l 

11.18 ug/l 

0.71 ug/l 

0.04 ug/l 

1. 39 ug/l 

4.81ug/l 

-0.19 ug/l 

0.34 ug/l 

ug/l 

0.03 ug/l 

ug/l 

0.00 ug/l 

-1.60 ug/l 

-1. 75 ug/l 

-1.94 ug/l 

0.84 ug/l 

0.08 ug/l 

0.00 ug/l 

ug/l 

ug/l 

0.01 ug/l 

331.60 

0.21 

0.68 

1.11 

6.76 

458500.00 

6.65 

4.55 

2.64 

2 .61 

11.18 

0.71 

0.04 

1. 39 

4.81 

-0.19 

0.34 

nVALUE I 

0.03 

nVALUEI 

0.00 

-1.60 

-1. 75 

-1.94 

0.84 

0.08 

0.00 

nVALUEI 

nVALUEI 

0.01 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Li -98050.09 3.92 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3512328.50 

477275.06 

14471162.00 

1409565.60 

553576.31 

7064350.50 

6209121.00 

3045038.50 

19537344.00 

24922826.00 

24244648.00 

0.91 

3.14 537987.94 

0.32 17012292.00 

0.50 949396.31 

0.58 338792.91 

1.24 3456710.80 

0.76 6610579.00 

0.74 3651775.30 

0.39 22769202.00 

1.21 28649686.00 

0.32 27453282.00 

RSD(%) 

79.71 

1. 37 

18.97 

18.58 

40.55 

7.80 

14.94 

37.72 

4.40 

28.43 

3.02 

1.91 

2.80 

4.17 

6.10 

6.72 

1. 79 

5.66 

22.77 

13.94 

182.68 

4.27 

5.00 

5.86 

127.00 

3.66 

2.73 

0.30 

2.35 

16.34 

4.26 

6.78 

Rec(%) 

74.3 

96.3 

88.7 

85.1 

148.5 

163.4 

204.4 

93.9 

83.4 

85.8 

87.0 

88.3 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

nnnnnnn 500 

nnnnnnn 1000 

nnnnnnn 

nnnnnnn 1000 

1000 

1000 

1000 

nnnnnnn 

nnnnnnn 1000 

Flag 

>Cal 

>Cal 

QC Range (%) Flag 

70 120 IS Fai 

70 - 120 

70 

70 -

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

70 - 120 

70 120 

70 120 

70 - 120 

IS Fai 

IS Fai 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

:Element Failures 

: ISTD Fai lures 

Data Results: 

Analytes: 

ISTD: 

9/26/12 7: 18 PM 

Fail 

Fail 

o :Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
101

C, \ICPCHEM\l \DATA\12I26qOO. 8\02 6SMPL. D\026SMPL. D~ 

Sample QC Report 

Data File: 

Date Acquired: 

C,\ICPCHEM\1\DATA\12126qOO.B\026SMPL.D\026SMPL.DU 

Sep 26 2012 07,21 pm 

Operator: NBS 

Sample Name: FGD ICS - Nitrate 

Mise Info: 

vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3108 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. Corr. Cone. 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 v 52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

.66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.01 ug/l 

1689.00 ug/l 

365000.00 ug/l 

2.44 ug/l 

-2.72 ug/l 

161.60 ug/l 

297.10 ug/l 

0.22 ug/l 

0.50 ug/l 

0.18 ug/l 

-0.90 ug/l 

49.33 ug/l 

0.15 ug/l 

0.29 ug/l 

0.75ug/l 

0.74 ug/l 

10.68 ug/l 

0.34 ug/l 

0.06 ug/l 

1. 27 ug/l 

0.09 ug/l 

0.13 ug/l 

0.13 ug/l 

ug/l 

0.02 ug/l 

ug/l 

0.05 ug/l 

-2.12 ug/l 

-2.18 ug/l 

-2.22 ug/l 

0.51 ug/l 

0.61 ug/l 

0.00 ug/l 

ug/l 

ug/l 

0.07 ug/l 

UVALUE! 

0.01 

1689.00 

365000.00 

2.44 

-2.72 

161.60 

297.10 

0.22 

0.50 

0.18 

-0.90 

~ 

0.15 

0.29 

0.75 

0.74 

10.68 

0.34 

0.06 

1. 27 

0.09 

0.13 

0.13 

UVALUE! 

0.02 

UVALUE! 

0.05 

-2.12 

-2.18 

-2.22 

0.51 

0.61 

0.00 

UVALUE! 

UVALUE! 

0.07 

ISTD Elements 

Element 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

CPS Mean RSD (%) 

-89100.86 0.41 

3305611.00 1.92 

Ref Value 

-131996.50 

3646344.80 

446707.13 

14388429.00 

857193.38 

295294.19 

2875063.00 

5955676.00 

2976431.80 

18980878.00 

24611324.00 

23737788.00 

0.51 537987.94 

1.67 17012292.00 

1.79 949396.31 

1.08 338792.91 

1.29 3456710.80 

1.21 6610579.00 

0.75 3651775.30 

1. 95 22769202.00 

1.89 28649686.00 

1.27 27453282.00 

RSD(%) 

55.06 

0.61 

1. 03 

13.53 

12.41 

0.74 

3.03 

110.60 

2.79 

7.27 

1.87 

9.10 

4.39 

0.31 

4.45 

2.52 

3.33 

5.72 

4.90 

11. 39 

30.50 

9.56 

7.65 

1.69 

15.25 

1. 36 

2.14 

0.93 

1. 46 

2.32 

39.21 

5.90 

Rec(%) 

67.5 

90.7 

83.0 

84.6 

90.3 

87.2 

83.2 

90.1 

81.5 

83.4 

85.9 

86.5 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 rJ1 1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

QC Range (%) 

70 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 -

70 

70 

120 

120 

120 

Flag 

>Cal 

>Cal 

Flag 

IS Fai 

ISTD Ref File: C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.DU 

:Element Failures 0 :Max. Number of Failures Allowed 

:ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/26112 7:25 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
102

C, \ICPCHEM\l \DATA\12I26qOO .B\027SMPL. D\027SMPL. D# 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\027SMPL.D\027SMPL.D# 

Sep 26 2012 07:28 pm 

Operator: NBS 

Sample Name: FGD ICS - Manganese 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3109 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1.00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

(Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 se 

78 se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

Conc. 

ug/l 

-0.02 ug/l 

1536.00 ug/l 

90.59 ug/l 

5.48 ug/l 

44.41 ug/l 

114.40 ug/l 

-23.69 ug/l 

0.21 ug/l 

0.40 ug/l 

0.25 ug/l 

192900.00 ug/l 

6.95 ug/l 

0.73 ug/l 

0.36 ug/l 

0.45 ug/l 

0.39ug/l 

-0.22 ug/l 

0.24 ug/l 

0.07 ug/l 

0.93 ug/l 

-0.39 ug/l 

-0.29 ug/l 

1.71ug/l 

ug/l 

0.03 ug/l 

ug/l 

-0.01 ug/l 

-1. 74 ug/l 

-1.82 ug/l 

-2.05 ug/l 

0.43 ug/l 

0.02 ug/l 

-0.02 ug/l 

ug/l 

ug/l 

o .05 ug/l 

ISTD Elements 

Carr. Conc. 

#VALUE! 

-0.02 

1536.00 

90.59 

5.48 

44.41 

114.40 

-23.69 

0.21 

0.40 

0.25 

192900.00 

6.95 

0.73 

0.36 

0.45 

0.39 

-0.22 

0.24 

0.07 

0.93 

-0.39 

-0.29 

1. 71 

#VALUE! 

0.03 

#VALUE! 

-0.01 

-1.74 

-1.82 

-2.05 

0.43 

0.02 

-0.02 

#VALUE! 

nVALUE! 

0.05 

Element CPS Mean RSD(%) Ref ValUe 

6 Li -96080.56 2.74 -131996.50 

45 Sc 3330538.00 0.23 3646344.80 

45 Sc 442001.22 0.88 537987.94 

45 Sc 14493612.00 2.21 17012292.00 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

1009336.00 

312663.88 

2967031.00 

6114611.00 

3008750.50 

19826062.00 

25590550.00 

24755814.00 

0.29 

0.86 

949396.31 

338792.91 

2.19 3456710.80 

0.82 6610579.00 

0.18 3651775.30 

2.36 22769202.00 

1.90 28649686.00 

2.85 27453282.00 

RSD (%) 

10.58 

2.55 

7.85 

5.19 

2.92 

9.68 

17.47 

50.19 

1. 03 

4.36 

0.86 

11.20 

1. 43 

15.59 

4.21 

3.47 

4.64 

4.57 

22.06 

10.91 

1. 33 

1. 78 

0.64 

4.40 

41. 73 

2.12 

6.13 

7.67 

4.81 

116.90 

8.08 

2.12 

Rec (%) 

72.8 

91. 3 

82.2 

85.2 

106.3 

92 .3 

85.8 

92.5 

82.4 

87.1 

89.3 

90.2 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

nnnnnnn 500 

nnnnnnn 1000 

nnnnnnn 

nnnnnnn 1000 

1000 

1000 

1000 

#nnn#nn 

nnnnnnn 1000 

QC Range(%) 

70 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

Flag 

,Cal 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

2 :Element Failures 

1 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/12 7:32 PM 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C,\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
103

C, \ICPCHEM\l \CATA\12I26qOO .B\029_CCV. C\029_CCV .CI 

CCV QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I26qOO.B\029_CCV.D\029_CCV.D# 

Sep 26 2012 07,41 pm 

NBS 

CCV 120926 

Vial Number, 

current Method, 

Calibration File: 

1106 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Last Cal update, Sep 26 2012 05,18 pm 

Sample Type, 

Total Dil Factor, 

CCV 

1. 00 

QC B1ements 

Element 

(Li) 

Cone. 

ug/l 

97.00 ug/l 

1248.00 ug/l 

2587.00 ug/l 

24970.00 ug/l 

9738.00 ug/l 

2102.00 ug/l 

RSD (%) Expected QC Range (%) 

50.00 90 - 110 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

24880.00 ug/l 

197.70 ug/l 

101.50 ug/l 

101.20 ug/l 

103.60 ug/l 

10000.00 ug/l 

101.30 ug/l 

101.20 ug/l 

101.70 ug/l 

101.80 ug/l 

100.30 ug/l 

98.93 ug/l 

101.40 ug/l 

97.31 ug/l 

101.00 ug/l 

101.80 ug/l 

197.90 ug/l 

ug/l 

98.45 ug/l 

ug/l 

99.08 ug/l 

206.70 ug/l 

201.10 ug/l 

200.90 ug/l 

199.30 ug/l 

102.40 ug/l 

100.00 ug/l 

ug/l 

ug/l 

100.80 ug/l 

3.12 50.00 90 - 110 

90 - 110 

90 110 

90 - 110 

3.47 50.00 

90 110 

0.32 1250.00 

1.37 12500.00 

0.255000.00 

o . 72 1000.00 

1. 04 12500.00 

2.29 100.00 

1.09 

0.59 

1.29 

0.46 

l.20 

1.19 

0.72 

0.75 

0.93 

1.06 

1.96 

0.91 

0.90 

2.57 

2.01 

50.00 

50.00 

50.00 

500.00 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

2.20 

2.31 

2.14 

0.64 

2.39 

2.90 

2.70 

l. 82 

2.36 

50.00 90 

50.00 90 

50.00 90-

50.00 90 

50.00 90-

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

100.00 90-

50.00 90 

50.00 90 

50.00 90-

50.00 90 

##### 

##### 

100.00 90 -

100.00 90-

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

##### 

##### 

110 

110 

110 

110 

110 

110 

110 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

6 Li 

45 SC 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-107346.35 

3565577.30 

496672 .25 

16040120.00 

913231.31 

321271.00 

3443301.00 

6503246.00 

3332759.50 

21510152.00 

27763568.00 

26929486.00 

0.63 

1.59 

1.03 

2.44 17012292.00 

0.68 949396.31 

1.12 338792.91 

1.69 3456710.80 

1.62 6610579.00 

0.70 3651775.30 

2.61 22769202.00 

2.39 28649686.00 

2.59 27453282.00 

Rec(%) QC Range(%) 

81.3 70 - 120 

97.8 70 120 

92.3 70 - 120 

94.3 

96.2 

94.8 

99.6 

98.4 

91.3 

94.5 

96.9 

98.1 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 - 120 

70 120 

70 120 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Flag 

IS Fail 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

30 :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

101 '/' 

or ~,q '/, 

101.4 '/' 

IUV .,. 

9/26/12 7:45 PM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
104

c: \ICPCHEM\1\DATA\12126qOO. B\Oll_CCB ,D\031_CCB .D' 

CCB QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12126qOO.B\031_CCB.D\031_CCB.DU 

Sep 26 2012 07,54 pm 

Sample Name, 

Mise Info: 

NBS 

CCB 120926 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Dil Factor: 

1102 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

CCB 

1.00 

QC Elements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.00 ug!l 

836.50 ug/l 

16.37 ug/l 

0.83 ug/l 

-0.09 ug/l 

37.24 ug/l 

-12.51 ug/l 

0.04 ug/l 

-0.02 ug/l 

0.00 ug/l 

0.71 ug/l 

O.78ug/l 

0.00 ug/l 

-0.07 ug/l 

0.06 ug/l 

0.03 ug/l 

-0.04 ug/l 

0.03 ug/l 

0.03 ug/l 

0.83 ug/l 

-0.02 ug/l 

-0.01 ug/l 

0.05 ug/l 

ug/l 

0.00 ug/l 

ug/l 

0.00 ug/l 

0.48 ug/l 

0.38 ug/l 

0.18 ug/l 

0.07 ug/l 

0.00 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

665.60 

0.51 

13 .48 

7.51 

205.54 

22.89 

22.85 

67.72 

36.33 

98.91 

12.57 

15.39 

170.93 

28.37 

28.11 

11.58 

192.69 

32.39 

59.60 

11.03 

17.32 

42.55 

11.96 

838.79 

53.54 

90.90 

14.15 

40.79 

5.75 

142.06 

38.75 

93.82 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-118087.91 12.60 

3640759.00 0.58 

501826.38 

17409780.00 

937541.81 

319426.91 

3611899.00 

6779286.50 

3409012.30 

23946008.00 

29768486.00 

28770254.00 

0.87 537987.94 

0.69 17012292.00 

0.69 949396.31 

0.48 338792.91 

1.16 3456710.80 

0.60 6610579.00 

1.34 3651775.30 

0.72 22769202.00 

1.04 28649686.00 

1.26 27453282.00 

High Limit 

uuuuuuu 0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

uuuuuuu 0.09 

uuuuuuu 0.06 

uuuuuuu 

uuuuuuu 0.30 

0.03 

0.12 

0.03 

UUUUUUU 

UUUUUUU 

0.33 

Rec(%) QC Range(%) 

89.5 70 - 120 

99.8 70 120 

93.3 

102.3 

98.8 

94.3 

104.5 

102.6 

93.4 

105.2 

103.9 

104.8 

70 - 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

Flag 

Fail ,;< 

Fail 

Fail 

Fail 

Fail tJ"\ 

Flag 

IS FaL 

ISTD Ref File, C,\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.DU 

5 ,Element Failures 0 ,Max. Number of Failures Allowed 

1 ,ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/26/127:58 PM C,\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
105

C, \ICPCHEM\l \OATA\12I26qOO. B\032SKPL. O\OJ2SKPL. 0, 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I26qOO.B\032SMPL.D\032SMPL.D# 

Sep 26 2012 08,01 pm 

Sample Name, 

Mise Info: 

NBS 

FGD ICS - Bromide 

Vial Number, 

CUrrent Method: 

Calibration File, 

Last Cal Update, 

Sample Type, 

3110 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor: 1.00 

Total Dil Factor, 1. 00 

QC Blements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

-0.02 ug/l 

872.70 ug/l 

66.72 ug/l 

-2.11 ug/l 

-4.92 ug/l 

44240.00 ug/l 

-22.27 ug/l 

0.01 ug/l 

0.67 ug/l 

0.12 ug/l 

-0.18 ug/l 

0.70 ug/l 

-0.03 ug/l 

0.01 ug/l 

0.13 ug/l 

0.09 ug/l 

-0.16 ug/l 

0.35 ug/l 

0.25 ug/l 

0.89 ug/l 

-0.43 ug/l 

-0.34 ug/l 

1. 68 ug/l 

ug/l 

0.01 ug/l 

ug/l 

-0.01 ug/l 

-0.57 ug/l 

-0.80 ug/l 

-1. 63 ug/l 

1. 76 ug/l 

0.03 ug/l 

-0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

Carr. Cone. 

#VALUEI 

-0.02 

872.70 

66.72 

-2.11 

-4.92 

44240.00 

-22.27 

0.01 

0.67 

0.12 

-0.18 

0.70 

-0.03 

0.01 

0.13 

0.09 

-0.16 

0.35 

0.25 

0.89 

-0.43 

-0.34 

1. 68 

#VALUEI 

0.01 

#VALUEI 

-0.01 

-0.57 

-0.80 

-1. 63 

1. 76 

0.03 

-0.01 

# VALUE I 

#VALUEI 

0.00 

RSD(%) High Limit 

o 6.67 1000 

0.85 1000 

14.14 25000 

18.89 50000 

10.97 20000 

1. 53 20000 

35.21 50000 

627.06 1000 

1.43 1000 

8.58 1000 

5.95 1000 

20.77 20000 

6.22 1000 

495.02 

4.37 

7.93 

25.57 

3.39 

7.17 

17.10 

2.66 

0.87 

1.69 

12.26 

12.22 

15.31 

16.52 

2.56 

0.19 

43.76 

7.29 

199.10 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Rec(%) 

72 .1 

94.9 

87.4 

94.9 

97.5 

96.1 

89.3 

99.3 

90.3 

98.9 

QC Range (%) Flag 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-95216.25 

3460578.50 

470243.56 

16152620.00 

92 5292 . 56 

325558.84 

3086042.00 

6562977.50 

3297406.50 

22512394.00 

28717122.00 

27692346.00 

ISTD Ref File, 

1 :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/12 8:05 PM 

3.60 

0.69 

1.34 537987.94 

1.40 17012292.00 

1.44 949396.31 

1.00 338792.91 

1.24 3456710.80 

1.30 6610579.00 

1.47 3651775.30 

0.58 22769202.00 

0.53 26649666.00 

0.34 27453262.00 

100.2 

100.9 

70 - 120 IS Fai 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 120 

70 - 120 

C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

o ,Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
106

C, \ICPCIIEM\l \OATA\12Il6QOO. 8\0335MPL. 0\0335MPL. 011 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12126qOO.B\033SMPL.D\033SMPL.D# 

Sep 26 2012 08:08 pm 

Operator: NBS 

Sample Name: FGD ICS - Fluoride 

Mise Info: 

Vial Number: 

current Method: 

Calibration File: 

Last Cal Update: 

3111 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

Cone. 

ug/l 

-0.01 ug/l 

896.00 ug/l 

113500.00 ug/l 

-0.12 ug/l 

7.72 ug/l 

153.10 ug/l 

-28.01 ug/l 

1. 32 ug/l 

0.64 ug/l 

0.19 ug/l 

-0.07 ug/l 

-1.11 ug/l 

0.07 ug/l 

0.09 ug/l 

0.18 ug/l 

0.15 ug/l 

0.03 ug/l 

0.57 ug/l 

0.27 ug/l 

0.93 ug/l 

-0.38 ug/l 

-0.29 ug/l 

0.09 ug/l 

ug/l 

0.02 ug/l 

ug/l 

0.16 ug/l 

-1.08 ug/l 

-1.03 ug/l 

-1. 50 ug/l 

0.79 ug/l 

0.26 ug/l 

-0.01 ug/l 

ug/l 

ug/l 

0.24 ug/l 

lSTD Elements 

Carr. Conc. 

#VALUE! 

-0.01 

896.00 

113500.00 

-0.12 

7.72 

153.10 

-28.01 

1. 32 

0.64 

0.19 

-0.07 

-1.11 

0.07 

0.09 

0.18 

0.15 

0.03 

0.57 

0.27 

0.93 

-0.38 

-0.29 

0.09 

#VALUE! 

0.02 

#VALUE! 

0.16 

-1.08 

-1. 03 

-1.50 

0.79 

0.26 

-0.01 

#VALUE! 

#VALUE! 

0.24 

RSD(%) High Limit 

o 12.71 1000 

5.72 1000 

0.75 25000 

189.13 50000 

3.82 20000 

3.92 20000 

34.35 50000 

12.77 1000 

2.16 1000 

2.39 1000 

37.47 1000 

10.51 20000 

11.09 

27.35 

1000 

1000 

5.15 1000 

14 .12 1000 

164.17 1000 

4.79 1000 

8.95 1000 

12.52 1000 

2.63 1000 

2.38 1000 

10.99 1000 

####### 

5.33 500 

####### 

9.13 1000 

3.31 ####### 

6.25 ####### 

8.11 1000 

3.01 1000 

15.23 1000 

10.49 1000 

####### 

####### 

6.20 1000 

Flag 

>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

Rec(%) 

63.4 

99.2 

88.0 

91. 8 

QC Range(%) Flag 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-83713.09 

3615403.50 

473218.03 

15619648.00 

1052588.40 

355182.38 

3259586.80 

6749887.00 

3311883.00 

21659004.00 

27423886.00 

26467844 .00 

ISTD Ref File : 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/128:12 PM 

5.76 

1. 52 

1.26 

4.95 17012292.00 

1.30 949396.31 

0.74 338792.91 

3.65 3456710.80 

0.59 6610579.00 

0.35 3651775.30 

4.54 22769202.00 

6.01 28649686.00 

5.94 27453282.00 

110.9 

104.8 

94.3 

102.1 

90.7 

95.1 

95.7 

96.4 

70 - 120 IS Fai 

70 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D# 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\lCPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
107

C, \ICPCHEM\l \OATA\12I26qOO. B\OHSMPL. O\OHSMPL. 0, 

Sample QC Report 

Data File, 

Date Acquired: 

C,\ICPCHEM\1\DATA\12126qOO.B\034SMPL.D\034SMPL.D# 

Sep 26 2012 08,15 pm 

Operator: NBS 

Sample Name: FGD ICS - Selenium 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update, 

Sample Type, 

Prep Dil Factor: 

3112 

C,\ICPCHEM\l\METHQDS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

1.00 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. carr. Cone. 

#VALUE:! 

-0.02 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

-0.02 ug/l 

706.70 ug/l 

83.22 ug/l 

-1.75 ug/l 

-5.06 ug/l 

141.40 ug/l 

-24.59 ug/l 

0.01 ug/l 

0.71 ug/l 

0.15 ug/l 

-0.09 ug/l 

-1.79 ug/l 

-0.02 ug/l 

-0.01 ug/l 

0.09 ug/l 

0.07 ug/l 

0.17 ug/l 

0.38 ug/l 

21980.00 ug/l 

20210.00 ug/l 

-0.41 ug/l 

-0.33 ug/l 

0.06 ug/l 

ug/l 

0.01 ug/l 

ug/l 

-0.03 ug/l 

-0.38 ug/l 

-1.02 ug/l 

-1.76 ug/l 

0.47 ug/l 

0.05 ug/l 

-0.02 ug/l 

ug/l 

ug/l 

0.00 ug/l 

706.70 

83.22 

-1.75 

-5.06 

141.40 

-24.59 

0.01 

0.71 

0.15 

-0.09 

-1.79 

-0.02 

-0.01 

0.09 

0.07 

0.17 

0.38 

21980.00 

20210.00 

-0.41 

-0.33 

0.06 

#VALUE! 

0.01 

#VALUE! 

-0.03 

-0.38 

-1.02 

-1. 76 

0.47 

0.05 

-0.02 

#VALUE! 

#VALUE! 

0.00 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996 .50 

3646344.80 

537987.94 

Li -91518.63 15.22 

45 Sc 3260116.00 7.82 

45 Sc 463591.81 0.91 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

16695750.00 

1114728.00 

389775.25 

3626899.00 

6288215.50 

3356181.50 

23250030.00 

28815582.00 

28013624.00 

3.38 17012292.00 

4.00 949396.31 

1.02 338792.91 

0.62 3456710.80 

6.29 6610579.00 

0.42 3651775.30 

2.51 22769202.00 

2.49 28649686.00 

1.40 27453282.00 

RSD(%) 

10.64 

2.77 

2.32 

6.86 

3.29 

3.22 

13.97 

542.12 

1.38 

10.44 

10.28 

4.25 

11.13 

88.90 

18.31 

17.55 

11.16 

4.62 

6.68 

0.42 

3.52 

1. 40 

18.37 

18.32 

22.06 

65.63 

2.38 

0.55 

2.27 

26.69 

3.94 

81.37 

Rec(%) 

69.3 

89.4 

86.2 

98.1 

117.4 

115.0 

104.9 

95.1 

91.9 

102.1 

100.6 

102.0 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Flag 

>Cal 

>Cal 

QC Range(%) Flag 

70 120 IS Fai 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 120 

70 - 120 

70 

70 

70 -

120 

120 

120 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures 0 :Max. Number of Failures Allowed 

,ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/26/128:18 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
108

C, \ICPCHEM\l \DATA \12I36qOO. B\035SMPL. D\035SMPL. D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C:\ICPCHEM\1\DATA\12I26qOO.B\035SMPL.D\035SMPL.DU 

Sep 26 2012 08:21 pm 

Sample Name, 

Mise Info: 

NBS 

FGD ICS - Vanadium 

Vial Number, 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Prep Dil Factor: 

3201 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

l. 00 

Total Dil Factor: 1.00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

0.02 ug/l 

573.20 ug/l 

19.88 ug/l 

2.60 ug/l 

-0.05 ug/l 

49.15 ug/l 

96 .45 ug/l 

0.25 ug/l 

10320.00 ug/l 

0.29 ug/l 

2.10 ug/l 

1.18 ug/l 

0.05 ug/l 

0.08 ug/l 

0.12 ug/l 

0.11 ug/l 

4.31 ug/l 

0.13 ug/l 

9.64 ug/l 

8.12 ug/l 

-0.15 ug/l 

-0.10 ug/l 

0.05 ug/l 

ug/l 

0.26 ug/l 

ug/l 

0.04 ug/l 

-0.41 ug/l 

-0.42 ug/l 

-0.50 ug/l 

0.32 ug/l 

0.07 ug/l 

0.05ug/1 

ug/l 

ug/l 

0.05 ug/l 

Carr. cone. 

#VALUEi 

0.02 

573.20 

19.88 

2.60 

-0.05 

49.15 

96.45 

0.25 

10320.00 

0.29 

2.10 

1.18 

0.05 

0.08 

0.12 

0.11 

4.31 

0.13 

9.64 

--a:rr 

-0.15 

-0.10 

0.05 

UVALUE! 

0.26 

UVALUE! 

0.04 

-0.41 

-0.42 

-0.50 

0.32 

0.07 

0.05 

UVALUE! 

UVALUE! 

0.05 

RSD(%) High Limit 

o 

26.29 1000 

1.10 1000 

18.06 25000 

23.16 50000 

977.78 20000 

22.32 20000 

1l. 37 50000 

140.94 1000 

1.99 1000 

10.53 1000 

3.44 1000 

84.04 20000 

8.31 1000 

3l. 70 

8.83 

8.30 

l. 35 

15.54 

2.92 

8.60 

13.94 

5.00 

6.67 

l. 99 

25.84 

11.88 

11.74 

2.29 

2.03 

11.34 

6.09 

4.29 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

.UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

Flag 

>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

Rec (%) 

79.6 

100.9 

93.6 

103.0 

98.6 

94.6 

105.0 

105.7 

QC Range(%) Flag 

6 Li -105046.50 6.86 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3678947.00 

503759.44 

17528172.00 

935870.19 

320547.00 

3630231.30 

6987954.50 

3525189.80 

24514 934.00 

30530728.00 

29432308.00 

0.67 3646344.80 

2.17 537987.94 

0.27 17012292.00 

0.74 949396.31 

0.82 338792.91 

0.47 3456710.80 

0.51 6610579.00 

0.51 3651775.30 

0.74 22769202.00 

0.28 28649686.00 

0.35 27453282.00 

96.5 

107.7 

106.6 

107.2 

70 120 IS Fai 

70 120 

70 120 

70 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 -

70 -

70 

120 

120 

120 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU 

:Element Failures :Max. Number of Failures Allowed 

:ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/26/128:25 PM C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
109

C: \ICPCIIEM\l \DATA\12Il6qOO. 8\0369""L. D\0369MPL. DH 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\036SMPL.D\036SMPL.DU 

Sep 26 2012 08:28 pm 

Operator: NBS 

Sample Name: FGD ICS - zinc 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

3202 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep oil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Conc. 

ug/l 

-0.01 ug/l 

597.90 ug/l 

6.37 ug/l 

0.23 ug/l 

2.22 ug/l 

36.70 ug/l 

-12.39 ug/l 

0.08 ug/l 

1.18 ug/l 

-0.02 ug/l 

2.45 ug/l 

0.30 ug/l 

-0.01 ug/l 

-0.06 ug/l 

0.09 ug/l 

0.09 ug/l 

1872.00 ug/l 

0.02 ug/l 

3.43 ug/l 

3.48 ug/l 

-0.05 ug/l 

0.04 ug/l 

0.01 ug/l 

ug/l 

0.01 ug/l 

ug/l 

-0.01 ug/l 

-0.14 ug/l 

-0.08 ug/l 

0.42 ug/l 

0.03 ug/l 

0.06 ug/l 

0.00 ug/l 

ug/l 

ug/l 

0.00 ug/l 

Corr. Conc. 

UVALUEI 

-0.01 

597.90 

6.37 

0.23 

2.22 

36.70 

-12.39 

0.08 

1.18 

-0.02 

2.45 

0.30 

-0.01 

-0.06 

0.09 

0.09 

1872.00 

0.02 

3.43 

"""'3:"48 

-0.05 

0.04 

0.01 

UVALUEI 

0.01 

UVALUEI 

-0.01 

-0.14 

-0.08 

0.42 

0.03 

0.06 

0.00 

UVALUEI 

UVALUEI 

0.00 

RSD(%) High Limit 

o 21. 50 1000 

9.06 1000 

13.07 25000 

119.81 50000 

26.73 20000 

10.57 20000 

75.51 50000 

106.37 1000 

4.97 1000 

11.85 1000 

2.76 1000 

13 . 06 20000 

38.95 

40.32 

18.89 

14.89 

1. 06 

42.39 

3.44 

10.58 

57.53 

11 7.68 

37.70 

44 .06 

158.59 

29.06 

301. 63 

129.95 

14.53 

14 .97 

39.78 

200.83 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

UUUUUUU 

500 

UUUUUUU 

1000 

UUUUUUU 

UUUUUUU 

1000 

1000 

1000 

1000 

UUUUUUU 

UUUUUUU 

1000 

Flag 

>Cal 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Rec(%) 

80.7 

101. 6 

94.8 

93.3 

100.6 

95.6 

99.9 

QC Range (%) Flag 

6 Li -106505.75 2.24 70 - 120 IS Fai 

45 Sc 3704809.00 0.39 70 120 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

509750.44 

15876257.00 

955397.25 

323899.44 

3453841. 50 

6883933.00 

3498517.30 

21942132.00 

27459006.00 

26417262.00 

ISTD Ref File : 

1 :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/128:31 PM 

0.49 537987.94 

8.55 17012292.00 

0.04 

0.90 

949396.31 

338792.91 

6.71 3456710.80 

0.46 6610579.00 

0.49 3651775.30 

9.01 22769202.00 

9.87 28649686.00 

10.85 27453282.00 

104.1 

95.8 

96.4 

95.8 

96.2 

70 

70 -

70 

70 -

70 

70 -

70 -

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU 

Fail 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
110

C, \ICPCHEM\l \DATA\12I26qOO. B\037SMPL.D\037SMPL. D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12126qOO.B\037SMPL.D\037SMPL D# 

Sep 26 2012 08,34 pm 

NBS 

FGD ICS - Chromium 

Vial Number: 

CUrrent Method, 

Calibration File, 

Last Cal Update, 

Sample Type, 

3203 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor, 1. 00 

QC Elements 

Element Cone. Carr. Cone. 

#VALUEJ 

-0.02 

498.40 

3.48 

-0.51 

0.01 

32.49 

-39.66 

0.07 

0.15 

1066.00 

1. 57 

0.42 

-0.02 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug!l 

-0.02 ug/l 

498.40 ug/l 

3.48 ug/l 

-0.51 ug/l 

0.01 ug/l 

32.49 ug/l 

-39.66 ug/l 

0.07 ug/l 

0.15 ug/l 

1066.00 ug/l 

1. 57 ug/l 

0.42 ug/l 

-0.02 ug/l 

-0.10 ug/l 

0.04 ug/l 

0.02 ug/l 

-0.51 ug/l 

0.06 ug/l 

1. 86 ug/l 

2.26 ug/l 

-0.10 ug/l 

-0.04 ug/l 

0.01 ug/l 

ug/l 

-0.01 ug/l 

ug/l 

-0.02 ug/l 

-0.28 ug/l 

-0.19 ug/l 

-0.28 ug/l 

0.01 ug/l 

-0.01 ug/l 

-0.02 ug/l 

ug/l 

ug/l 

-0.01 ug/l 

-0.10 

0.04 

0.02 

-0.51 

0.06 

L!L 

2.26 

-0.10 

-0.04 

0.01 

#VALUEI 

-0.01 

#VALUEI 

-0.02 

-0.28 

-0.19 

-0.28 

0.01 

-0.01 

-0.02 

#VALUE! 

#VALUE! 

-0.01 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-120827.75 

3708234.00 

497315.22 

17330376.00 

946894.25 

321435.47 

3628007.80 

6943829.50 

3505867.30 

24331450.00 

30187410.00 

29144966.00 

8.79 

1. 32 

0.94 537987.94 

1.22 17012292.00 

0.94 949396.31 

0.98 338792.91 

0.86 3456710.80 

0.47 6610579.00 

0.90 3651775.30 

0.48 22769202.00 

0.40 28649686.00 

1.12 27453282.00 

RSD(%) High Limit 

o 9.36 1000 

2.23 1000 

13.09 25000 

51.28 50000 

1584.50 20000 

10.37 20000 

12.61 50000 

12.03 1000 

12.87 1000 

0.41 1000 

1.52 1000 

10.32 20000 

8.51 1000 

16.15 

11.74 

36.05 

13.14 

150.20 

4.21 

1.40 

21.00 

13.02 

40.47 

8.59 

8.71 

7.83 

50.95 

11.50 

1.09 

142.82 

6.28 

12.63 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Rec(%) QC Range(%) 

91. 5 

101.7 

92.4 

101. 9 

99.7 

94.9 

105.0 

105.0 

70 120 

96.0 

106.9 

105.4 

106.2 

70 120 

70 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 -

70 

70 -

70 

70 -

120 

120 

120 

120 

120 

Flag 

,Cal 

Flag 

IS fai 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures :Max. Number of Failures Allowed 

,ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9126112 8:38 PM C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
111

C: \ ICPClIEM\ 1 \DATA \12I2 6qOO. B\ 03 BSMPL. D\03 BSMPL. DH 

Sample QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\038SMPL.D\038SMPL.D# 

Sep 26 2012 08:41 pm 

Operator: NBS 

Sample Name: FGD ICS - Copper 

Mise Info: 

Vial Number: 

current Method: 

Calibration File: 

Last Cal Update: 

3204 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: Sample 

Prep Dil Factor: 1. 00 

Total Dil Factor: 1. 00 

QC Blement. 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

III Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

-0.02 ug/l 

446.20 ug/l 

-2.19 ug/l 

-0.27 ug/l 

-1.04 ug/l 

23.63 ug/l 

-59.99 ug/l 

-0.01 ug/l 

-0.01 ug/l 

0.79 ug/l 

1.06 ug/l 

0.12 ug/l 

-0.01 ug/l 

-0.10 ug/l 

1085.00 ug/l 

1093.00 ug/l 

-2.36 ug/l 

-0.01 ug/l 

1. 41 ug/l 

1.87 ug/l 

-0.10 ug/l 

-0.05 ug/l 

0.00 ug/l 

ug/l 

-0.01 ug/l 

ug/l 

-0.01 ug/l 

-0.43 ug/l 

-0.14 ug/l 

-0.37 ug/l 

0.00 ug/l 

-0.04 ug/l 

-0.01 ug/l 

ug/l 

ug/l 

-0.01 ug/l 

Element CPS Mean RSD(%) 

6 Li -117488.69 4.07 

45 Sc 3718146.30 0.99 

45 Sc 509565.50 1.21 

Cerr. Cone. 

#VALUE! 

-0.02 

446.20 

-2.19 

-0.27 

-1. 04 

23.63 

-59.99 

-0.01 

-0.01 

0.79 

1.06 

0.12 

-0.01 

-0.10 

1085.00 

1093.00 

-2.36 

-0.01 

1.41 

-r:B"1 

-0.10 

-0.05 

0.00 

#VALUE! 

-0.01 

#VALUE! 

-0.01 

-0.43 

-0.14 

-0.37 

0.00 

-0.04 

-0.01 

#VALUE! 

#VALUE! 

-0.01 

Ref Value 

-131996.50 

3646344.80 

537987.94 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

17720008.00 

956646.06 

328000.44 

3676394.80 

7016368.00 

3546346.50 

1.04 17012292.00 

24716714.00 

30987344.00 

29784232.00 

0.12 949396.31 

0.41 338792.91 

1.08 3456710.80 

0.66 6610579.00 

0.22 3651775.30 

0.45 22769202.00 

0.32 28649686.00 

0.53 27453282.00 

RSD(%) 

9.70 

0.10 

23.23 

54.59 

5.92 

12.25 

3.26 

253.09 

20.92 

1.11 

3.65 

50.85 

6.44 

20.03 

1. 60 

1. 08 

2.24 

150.70 

3.02 

1. 82 

19.09 

7.23 

1156.60 

8.70 

5.86 

8.95 

260.62 

8.82 

88.90 

30.31 

3.75 

14.20 

Rec(%) 

89.0 

102.0 

94.7 

104.2 

100.8 

96.8 

106.4 

106.1 

97.1 

108.6 

108.2 

108.5 

High Limit 

o 1000 

1000 

25000 

50000 

20000 

20000 

50000 

1000 

1000 

1000 

1000 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

QC Range(%) 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

Flag 

>Cal 

>Cal 

Flag 

IS Fai 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

2 :Element Failures 

1 : ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9126112 B:45 PM 

Fail 

Fail 

o :Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
112

C, \ICPCIIE>!\1\CATA\12126qOO. B\04l_CCV. C\04l_CCV. 0_ 

CCV QC Report 

Data File: 

Date Acquired, 

Operator: 

C:\ICPCHEM\1\DATA\12I26qOO.B\043_CCV.D\043_ccv.Dn 

Sep 26 2012 09:14 pm 

NBS 

Sample Name: CCV 120926 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1106 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: CCV 

Total Oil Factor: 1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

91.23 

411.90 

2627.00 

25830.00 

9893.00 

2097.00 

25620.00 

202.80 

103.50 

104.30 

102.80 

10210.00 

103.70 

ug/1 

ug/l 

ug/1 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

103.90 ug/l 

104.30 ug/l 

104.10 ug/l 

101.90 ug/l 

100.60 ug/l 

102.90 ug/l 

101.20 ug/l 

103.20 ug/l 

95.44 ug/l 

186.30 ug/l 

ug/l 

92 .45 ug/l 

ug/l 

93.17 ug/l 

208.40 ug/l 

206.40 ug/l 

189.00 ug/l 

184.90 ug/l 

101.30 ug/l 

92 .17 ug/l 

ug/l 

ug/l 

93.82 ug/l 

RSD(%) Expected QC Range(%) 

50.00 

0.76 50.00 

1.52 50.00 

1.44 1250.00 

1.99 12500.00 

1.37 5000.00 

0.94 1000.00 

1.09 12500.00 

1. 39 

1. 09 

0.92 

0.85 

1. 02 

1.16 

0.90 

1.12 

1. 21 

0.64 

0.19 

0.53 

1. 04 

0.63 

3.49 

3.26 

2.77 

100.00 

50.00 

50.00 

50.00 

500.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

100.00 

50.00 

50.00 

90 - 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

50.00 90 110 

110 

nnnnn 1. 33 

0.80 

0.40 

1. 68 

2.06 

7.34 

1.69 

1.66 

50.00 90 

100.00 

100.00 

50.00 

50.00 

50.00 

50.00 

50.00 

nnnnn 

nnnnn 

90 

90 

90 

90 

90 

90 

90 

- nnnnn 110 

110 

110 

110 

110 

110 

110 

Flag 

'Fiili 

F il 

F il 

F il 

Fil 

F i 1 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F '1 

Fa'l 

Fa 1 

Fa 

Fa 

Fa 

Fa 

Fa' 

Fa'l 

Fa 

Fa 

Fa 

Fa 

\£11}. (p'{' 

lo1.." I 

Element CPS Mean RSD(%) 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-117534.54 13.21 

Ref Value 

-131996 .50 

Rec(%) QC Range(%) 

89.0 

106.5 

98.4 

108.9 

103.5 

99.6 

110.8 

106.6 

70 

70 

70 

120 

120 

120 

Flag <" IS Fail rJ \ 3881736.00 

529203.44 

18518892.00 

983097.25 

337297.94 

3828636.50 

7043901.50 

3542548.50 

24714964.00 

31189180.00 

30200216.00 

ISTD Ref File : 

30 :Element Failures 

1 : ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26/129:18 PM 

0.47 3646344.80 

1.38 537987.94 

1.46 17012292.00 

0.08 949396.31 

1.65 338792.91 

1.43 3456710.80 

0.55 6610579.00 

0.66 3651775.30 

2.4622769202.00 

1.78 28649686.00 

1.20 27453282.00 

97.0 

108.5 

108.9 

110.0 

70 - 120 

70 120 

70 120 

70 - 120 

70 120 

70 120 

70 120 

70 - 120 

70 - 120 

C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
113

C, \ICPCIIEM\l \OATA \12126qOO. B\045_CCB. 0\045_CCB. 011 

CCB QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\045_CCB.D\045_CCB.D# 

Sep 26 2012 09:27 pm 

Operator: NBS 

Sample Name: CCB 120926 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: CCB 

Total Dil Factor: 1. 00 

QC Elements 

Element 

(Li) 

Cone. 

ug/l 

0.00 ug/l 

RSD(%) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

273.50 ug/l 

6.88 ug/l 

1.02 ug/l 

0.13 ug/l 

34.08 ug/l 

-4.81 ug/l 

0.05 ug/l 

-0.03 ug/l 

0.00 ug/l 

0.21 ug/l 

0.97 ug/l 

0.00 ug/l 

-0.05 ug/l 

0.03 ug/l 

0.02 ug/l 

-0.07 ug/l 

0.02 ug/l 

0.56 ug/l 

1.35Ug/l 

-0.03 ug/l 

0.01 ug/l 

0.06 ug/l 

ug/l 

0.00 ug/l 

ug/l 

0.01 ug/l 

0.83 ug/l 

0.37 ug/l 

0.23 ug/l 

0.08 ug/l 

O.Olug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

88.44 

0.64 

16.71 

11.82 

277.89 

5.96 

94.04 

207.34 

49.09 

256.67 

14.26 

16.84 

138.85 

40.65 

22.62 

59.28 

91.85 

23.70 

6.23 

8.17 

55.21 

74.58 

3.08 

71.81 

55.53 

160.24 

15.65 

25.32 

3.97 

70.96 

25.21 

33.56 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996. SO 

3646344.80 

537987.94 

6 Li -113701.58 4.53 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3965454. SO 

523514.81 

18366760.00 

1034474.60 

334192.81 

3769784.00 

7415833.50 

3600374. SO 

24837508.00 

30861174.00 

29640796.00 

0.74 

1. 82 

1.25 17012292.00 

5.36 949396.31 

0.75 338792.91 

0.95 3456710.80 

2.74 6610579.00 

0.25 3651775.30 

0.82 22769202.00 

LOS 28649686.00 

1.42 27453282.00 

High Limit 

####### 

0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

86.1 70 - 120 

108.8 70 - 120 

97.3 70 - 120 

108.0 

109.0 

98.6 

109.1 

112.2 

98.6 

109.1 

107.7 

108.0 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 - 120 

70 - 120 

Flag 

Fail tl'" 

Fail ,.1-<: 

Fail 

Fail 

Fail 

Fail r'1" 

Flag 

IS Fai. 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

6 :Element Failures 

1 : ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

L.. \ . oJ'1.8 1 L.. 

9/26/129:31 PM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
114

C, \ICPCIIEM\l \OATA\12126qOO .B\057 _CCV. 0\057 _CCV. Oi 

CCV QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I26qOO.B\057_CCV.D\057_CCV.D# 

Sep 26 2012 10,47 pm 

NBS 

Sample Name: CCV 120926 

Mise Info: 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Dil Factor: 

1106 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

CCV 

1. 00 

QC Elements 

Element Cone. RSD(%) Expected QC Range(%) 

7 (Li) ug/l 

91.72 ug/l 

199.20 ug/l 

2662.00 ug/l 

26120.00 ug/l 

9918.00 ug/l 

2116.00 ug/l 

50.00 90 110 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

25680.00 ug/l 

205.10 ug/l 

104.60 ug/l 

105.20 ug/l 

103.80 ug/l 

10380.00 ug/l 

105.20 ug/l 

105.40 ug/l 

105.20 ug/l 

105.30 ug/l 

101.10 ug/l 

100.10 ug/l 

102.80 ug/l 

99.72 ug/l 

102.50 ug/l 

97.55 ug/l 

189.00 ug/l 

ug/l 

94.02 ug/l 

ug/l 

94.51 ug/l 

209.20 ug/l 

206.80 ug/l 

190.10 ug/l 

186.10 ug/l 

106.80 ug/l 

91.96 ug/l 

ug/l 

ug/l 

92.46 ug/l 

ISTD Element. 

1.07 50.00 

1.76 50.00 

1.62 1250.00 

1.11 12500.00 

0.96 5000.00 

1.10 1000.00 

0.75 12500.00 

1.80 100.00 

1.29 50.00 

1.53 50.00 

1.76 50.00 

1.06 500.00 

1. 35 

1. 42 

1. 49 

1. 58 

1.45 

1.11 

1.21 

0.62 

1. 35 

0.66 

0.67 

0.87 

0.09 

0.70 

0.80 

0.74 

0.56 

1.73 

0.46 

0.45 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

100.00 

50.00 

50.00 

50.00 

50.00 

100.00 

100.00 

50.00 

50.00 

50.00 

50.00 

50.00 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 

90 

90 

90 

90 

90 

90 

90 

90 

90 

90 

90 

90 

90 

90 

##### 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

##### 

##### - ##### 

90 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 110 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

17012292.00 

949396.31 

Rec(%) QC Range(%) 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-102336.02 

3994279.80 

535870.88 

18766360.00 

1018578.60 

344028.53 

3878756.30 

7257053.50 

3639922.80 

24605280.00 

31141070.00 

29932426.00 

5.73 

0.65 

1. 40 

0.17 

0.92 

0.43 338792.91 

0.93 3456710.80 

0.41 6610579.00 

1.12 3651775.30 

0.97 22769202.00 

0.79 28649686.00 

1.23 27453282.00 

77.5 

109.5 

99.6 

110.3 

107.3 

101.5 

112.2 

109.8 

99.7 

108.1 

108.7 

109.0 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Flag 

IS Fail 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

30 :Element Failures 

,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

912611210:51 PM 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
115

C, \ICPCIIEI<\l\DATA \12I26qOO .9\OS9 _CCB. D\OS9_CCB. DI 

CCB QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\059_CCB.D\059_CCB.Dn 

Sep 26 2012 11:00 pm 

Operator: NBS 

Sample Name, CCB 120926 

Misc Info, 

Vial Number, 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Di1 Factor, 

1102 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,16 pm 

CCB 

1. 00 

QC Elements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 A1 

39 K 

44 ca 

47 Ti 

51 V 

52 cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

76 se 

76 Se 

66 Sr 

66 sr 

95 Mo 

106 (Cd) 

107 Ag 

106 (Cd) 

111 Cd 

116 Sn 

116 Sn 

116 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

206 Pb 

ug/l 

0.00 ug/l 

72.73 ug/l 

3.23 ug/l 

1. 23 ug/1 

0.53 ug/1 

24.16 ug/1 

-5.02 ug/l 

0.04 ug/l 

-0.04 ug/l 

0.00 ug/l 

0.06 ug/l 

0.96 ug/1 

0.00 ug/l 

-0.07 ug/l 

0.02 ug/l 

0.00 ug/1 

0.01 ug/1 

0.01 ug/l 

0.36 ug/l 

0.70 ug/l 

-0.02 ug/l 

0.01ug/1 

0.07 ug/l 

ug/l 

0.00 ug/l 

ug/1 

0.00 ug/l 

0.36 ug/l 

0.49 ug/l 

0.35 ug/l 

0.09 ug/l 

0.01 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

43.77 

0.61 

14.66 

23.26 

101. 46 

14.00 

76.07 

13.76 

6.56 

50.42 

24.13 

14.32 

37.60 

16.13 

31.77 

7713.60 

736.09 

62.06 

4.36 

20.26 

6.60 

109.14 

7.15 

43.03 

66.14 

6.63 

20.31 

22.02 

6.13 

67.17 

9.36 

51.52 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.60 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-105393.61 

3972629.50 

542640.00 

16651006.00 

1016659.50 

346291.13 

3906303.30 

7422523.00 

3755156.00 

25235746.00 

30922952.00 

29636662.00 

4.09 

0.92 

0.56 537967.94 

1.31 17012292.00 

0.53 949396.31 

1.61 336792.91 

0.72 3456710.60 

1.09 6610579.00 

0.77 3651775.30 

1. 34 22769202.00 

1.24 26649666.00 

0.66 27453262.00 

High Limit 

nnnnnnn 0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.7B 

0.21 

0.12 

0.16 

40.60 

0.09 

0.46 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

nnnnnnn 0.09 

nnnnnnn 0.06 

nnnnnnn 

nnnnnnn 0.30 

0.03 

0.12 

0.03 

nnnnnnn 

nnnnnnn 0.33 

Rec(%) QC Range(%) 

79.6 70 120 

106.9 

100.9 

109.6 

107.3 

102.2 

113.1 

112.3 

102.6 

110.6 

107.9 

106.0 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Flag 

IS FaL 

ISTD Ref File: C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

6 :Element Failures :Max. Number of Failures Allowed 

1 ,ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9i26/12 11 :04 PM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
116

C: \ICPCHEK\l \DATA\12I26qOO .B\071_CCV. 0\ 0 7l_CCV .0# 

CCV QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\071_CCV.D\071_CCV.D# 

Sep 27 2012 12:20 am 

Operator: NBS 

Sample Name: CCV 120926 

Mise Info: 

vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1106 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: CCV 

Total Dil Factor: 1. 00 

QC Elements 

Element Cone. RSD(%) Expected QC Range(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 v 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 cu 

65 cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

93.23 

136.10 

2670.00 

26170.00 

10020.00 

2105.00 

25440.00 

200.60 

102.20 

101.70 

101.60 

10080.00 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

101.70 ug/l 

101. 40 ug/l 

102.00 ug/l 

101.70 ug/l 

100.40 ug/l 

100.10 ug/l 

102.30 ug/l 

102.10 ug/l 

103.20 ug/l 

95.70 ug/l 

185.00 ug/l 

ug/l 

91.05 ug/l 

ug/l 

92.53 ug/l 

207.60 ug/l 

203.00 ug/l 

189.40 ug/l 

186.90 ug/l 

102.50 ug/l 

90.94 ug/l 

ug/l 

ug/l 

91.53 ug/l 

50.00 90 110 

0.72 50.00 

0.76 50.00 

2.03 1250.00 

1.68 12500.00 

0.585000.00 

2.311000.00 

1.38 12500.00 

1. 47 

1. 64 

0.98 

1. 83 

2.50 

2.40 

1. 41 

1. 57 

1. 57 

0.40 

0.77 

0.60 

0.26 

0.93 

1. 04 

1.49 

2.03 

1. 36 

0.61 

0.57 

0.98 

1. 27 

6.61 

0.79 

0.67 

100.00 

50.00 

50.00 

50.00 

500.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

100.00 

50.00 

50.00 

50.00 

50.00 

100.00 

100.00 

50.00 

50.00 

50.00 

50.00 

50.00 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 

90 

90 

90 -

90 -

90 -

90 -

90 

90 

90 -

90 

90 

90 

90 

90 

##### 

##### 

90 -

90 -

90 

90 

90 

90 

90 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

##### 

##### 

110 

110 

110 

110 

110 

110 

110 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-116018.45 

3765953.50 

517915.38 

17945498.00 

954073.50 

324142.25 

3688293.30 

6818772.00 

3413148.30 

23549862.00 

30084936.00 

28980032.00 

8.09 

0.48 

1.42 537987.94 

0.89 17012292.00 

0.63 949396.31 

0.29 338792.91 

1.05 3456710.80 

1.15 6610579.00 

0.33 3651775.30 

1.10 22769202.00 

1.3228649686.00 

0.95 27453282.00 

Rec(%) QC Range(%) 

87.9 

103.3 

96.3 

105.5 

100.5 

95.7 

106.7 

103.1 

93.5 

103.4 

105.0 

105.6 

70 - 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 

70 

70 

120 

120 

120 

Flag 

Fa 

Fa 

Fa 

Fa 

Fa 

Fa 

F 

F 

F 

F 

F 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

Flag 

IS Fail 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

30 :Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Fail 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

(01.1-/ 

lao. l "(. 

ID1,. ~(. 

9/27112 12:24 AM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
117

C I \ICPCHEM\1\DATA\12126QOO. B\073_CCB .D\073_CCB. DfI: 

CCB QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\073_CCB.D\073_CCB.D# 

Sep 27 2012 12:33 am 

Operator: NBS 

Sample Name: CCB 120926 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: CCB 

Total Dil Factor: 1.00 

QC Elements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.00 ug/l 

28.44 ug/l 

6.00 ug/l 

2.88 ug/l 

0.86 ug/l 

19.74 ug/l 

-8.59 ug/l 

0.04 ug/l 

-0.03 ug/l 

0.00 ug/l 

0.11 ug/l 

1.10 ug/l 

0.00 ug/l 

-0.08 ug/l 

0.02 ug/l 

0.01 ug/l 

-0.02 ug/l 

0.03 ug/l 

0.27 ug/l 

0.93 ug/l 

-0.05 ug/l 

0.00 ug/l 

0.07 ug/l 

ug/l 

0.00 ug/l 

ug/l 

0.00 ug/l 

0.41 ug/l 

0.53 ug/l 

0.33 ug/l 

0.11 ug/l 

0.01 ug/l 

0.02 ug/l 

ug/l 

ug/l 

0.00 ug/l 

170.77 

14 .10 

13.77 

5.89 

53.50 

22.34 

74.87 

118.78 

33.46 

694.21 

22.80 

9.83 

84.30 

8.63 

22.22 

129.24 

419.81 

50.85 

11.24 

5.59 

51.99 

1342.20 

20.81 

355.08 

55.65 

33.85 

8.83 

153.50 

14.73 

137.71 

37.94 

291. 49 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

537987.94 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-116657.41 

3744551. 80 

517859.63 

17840296.00 

956514 .00 

325372.00 

3688012.30 

6878506.50 

12.10 

1.41 

0.60 

12.02 17012292.00 

0.33 949396.31 

0.22 

8.46 

1. 30 

338792.91 

3456710.80 

6610579.00 

3447856.30 0.15 3651775.30 

24145908.00 12.98 22769202.00 

29998472.0012.5528649686.00 

29103804.00 12.60 27453282.00 

High Limit 

####### 

0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

88.4 70 

102.7 70 -

96.3 70 

104.9 70 

100.7 70 

96.0 70 

106.7 70 

104.1 70 

94.4 70 -

106.0 70 

104.7 70 

106.0 70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail 

Fail 

Fail ,.J""i 

Fail tJ-rFai 1 rJ-(' 

Flag 

IS Fai. ~\ 

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

5 :Element Failures 

1 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

912711212:37 AM 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
118

C, \ICPCHEM\1\DATA\lZI26qOO .B\085_CCV .D\085_CCV. DII 

CCV QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\085_CCV.D\085_CCV.D# 

Sep 27 2012 01:53 am 

Operator: NBS 

Sample Name: CCV 120926 

Misc Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1106 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: CCV 

Total Dil Factor: 1. 00 

QC Elements 

Element 

(Li) 

Cone. RSD(%) Expected QC Range(%) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

82.34 

94.23 

2651.00 

25450.00 

10010.00 

1906.00 

25390.00 

198.50 

99.93 

98.87 

100.40 

9858.00 

99.26 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

ug/l 

98.92 ug/l 

99.45 ug/l 

99.01 ug/l 

93.71 ug/l 

93.77 ug/l 

97.26 ug/l 

97.44 ug/l 

102.00 ug/l 

94.84 ug/l 

181. 20 ug/l 

ug/l 

90.25 ug/l 

ug/l 

91.00 ug/l 

190.50 ug/l 

200.70 ug/l 

190.70 ug/l 

186.20 ug/l 

99.61 ug/l 

95.85 ug/l 

ug/l 

ug/l 

96.11 ug/l 

50.00 90 - 110 

4.87 50.00 

0.35 50.00 

1.67 1250.00 

1.47 12500.00 

1.77 5000.00 

2.06 1000.00 

0.64 12500.00 

1. 86 

1. 08 

1. 69 

1. 51 

1. 52 

1.26 

2.09 

2.01 

1. 87 

0.45 

0.74 

0.52 

0.98 

1.01 

0.79 

1.09 

0.57 

100.00 

50.00 

50.00 

50.00 

500.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

100.00 

50.00 

50.00 

50.00 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

0.59 

0.40 

0.25 

0.04 

0.38 

0.74 

0.30 

50.0090 110 

0.80 

- - - ##### ##### 

##### - ##### 

100.00 

100.00 

50.00 

50.00 

50.00 

50.00 

50.00 

90 - 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

6 Li -100876.27 4.50 -131996.50 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

2791081.00 

383152.88 

13567006.00 

700089.38 

244911.61 

2927789.50 

5149708.50 

2608314.50 

19387486.00 

26095872.00 

25362694.00 

0.50 3646344.80 

1.66 537987.94 

0.46 17012292.00 

1.01 949396.31 

1.60 338792.91 

1.30 3456710.80 

0.74 6610579.00 

0.74 3651775.30 

0.75 22769202.00 

0.26 28649686.00 

0.36 27453282.00 

Rec(%) QC Range(%) 

76.4 70 120 

76.5 70 120 

71.2 70 - 120 

79.7 70 - 120 

73.7 70 120 

72.3 70 120 

84.770 120 

77.9 70 120 

71.4 70 - 120 

85.1 70 120 

91.1 70 120 

92.4 70 120 

Flag 

11 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

F il 

Fil 

F il 

F il 

il 

il 

ail 

ail 

ail 

ail 

ail 

ail 

ail 

ail q('/. 

Flag 

IS Fail ,.. -( 

ISTD Ref File: C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D# 

30 :Blement Failures :Max. Number of Failures Allowed 

: ISTD Failures 0 :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/27112 1 :57 AM C:\ICPCHEM\l\rpttmP\CCV.qct Page 1 of 1 
119

C, \ICPCHEM\l \DATA\12I26qOO .9\087 _CCB .D\087 _CCB .D~ 

CCB QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I26qOO.B\087_CCB.D\087_CCB.D# 

Sep 27 2012 02:07 am 

Operator: NBS 

Sample Name: CCB 120926 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1102 

C:\ICPCHEM\l\METHODS\CSC-MDL.M 

C:\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05:18 pm 

Sample Type: CCB 

Total Dil Factor: 1.00 

QC Blements 

Element 

(Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Blements 

Cone. 

ug/l 

0.00 ug/l 

12.90 ug/l 

31.66 ug/l 

6.60 ug/l 

0.63 ug/l 

41.57 ug/l 

-9.23 ug/l 

0.04 ug/l 

0.01 ug/l 

-0.02 ug/l 

0.09 ug/l 

1.18 ug/l 

0.00 ug/l 

-0.07 ug/l 

0.08 ug/l 

0.07 ug/l 

-0.22 ug/l 

0.04 ug/l 

0.14 ug/l 

1.43 ug/l 

-0.04 ug/l 

0.00 ug/l 

0.06 ug/l 

ug/l 

o . 00 ug/l 

ug/l 

-0.01 ug/l 

0.29 ug/l 

0.36 ug/l 

0.25 ug/l 

0.08 ug/l 

0.01 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

Element CPS Mean RSD(%) 

Li -100982.52 4.41 

45 Sc 2775014.30 1.15 

45 Sc 0.41 

RSD(%) 

23.20 

2.62 

3.48 

5.90 

41. 4 3 

7.44 

57.00 

45.54 

167.60 

26.89 

29.14 

5.79 

217.64 

36.54 

14.06 

10.31 

33.36 

6.01 

10.01 

5.09 

59.80 

136.82 

8.88 

131.43 

13.27 

5.43 

29.24 

25.95 

5.58 

85.91 

4.75 

100.66 

Ref Value 

-131996.50 

3646344.80 

537987.94 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

376871.16 

13653593.00 0.40 17012292.00 

699303.81 

243273.42 

2904337.50 

5171818.50 

2637361.00 

20064644.00 

26151482.00 

25236008.00 

1.18 949396.31 

0.63 338792.91 

0.29 3456710.80 

0.56 6610579.00 

0.13 3651775.30 

0.91 22769202.00 

0.37 28649686.00 

0.77 27453282.00 

High Limit 

####### 

0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

76.5 70 

76.1 70 

70.1 70 -

80.3 70 -

73.7 70 

71. 8 70 

84.0 70 -

78.2 70 -

72.2 70 -

88.1 70 -

91. 3 70 

91. 9 70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail rJ-:" 

Fail rJ' 

Fail ~, 

Flag 

IS FaL N' 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

:Element Failures 0 :Max. Number of Failures Allowed 

: ISTD Failures 0 :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/271122:10 AM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
120

C, \ICPCHEM\l \DATA\12126qOO .B\099_CCV .D\099_CCV. D# 

CCV QC Report 

Data File, 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I26qOO.B\099_CCV.D\099_ccv.Dn 

Sep 27 2012 03,27 am 

Operator: NBS 

Sample Name, 

Mise Info: 

CCV 120926 

Vial Number, 

Current Method, 

Calibration File: 

1106 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Last Cal Update, Sep 26 2012 05,18 pm 

Sample Type, 

Total Dil Factor: 

CCV 

1. 00 

QC Elements 

Element Conc. RSD(%) Expected QC Range(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

70.16 ug/l 

77.44 ug/l 

2755.00 ug/l 

24850.00 ug/l 

8841.00 ug/l 

1935.00 ug/l 

25320.00 ug/l 

197.50 ug/l 

101.00 ug/l 

98.91 ug/l 

100.10 ug/l 

9822.00 ug/l 

100.30 ug/l 

99.57 ug/l 

100.60 ug/l 

99.53 ug/l 

87.82 ug/l 

90.07 ug/l 

93.15 ug/l 

92.68 ug/l 

100.40 ug/l 

93.53 ug/l 

175.50 ug/l 

ug/l 

88.04 ug/l 

ug/l 

87.87 ug/l 

190.20 ug/l 

200.70 ug/l 

191.50 ug/l 

183.40 ug/l 

101.70 ug/l 

97.33 ug/l 

ug/l 

ug/l 

93.81 ug/l 

50.00 90 - 110 

0.85 50.00 90 - 110 

1.13 50.00 

1.27 1250.00 

1.11 12500.00 

1. 43 5000.00 

1.65 1000.00 

1.38 12500.00 

3.45 100.00 

1.60 

0.69 

1. 69 

1.66 

1.68 

1. 75 

1.39 

1. 35 

0.95 

0.31 

1. 90 

1.45 

0.50 

0.26 

0.66 

0.74 

0.45 

0.55 

0.82 

0.60 

0.93 

0.32 

0.27 

2.54 

50.00 

50.00 

50.00 

500.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

100.00 

50.00 

50.00 

50.00 

50.00 

100.00 

100.00 

50.00 

50.00 

50.00 

50.00 

50.00 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90' - 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

nnnnn nnnnn 

nn#n# - nnnnn 90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

ISTD Elements 

Element 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

CPS Mean RSD (%) 

-64965.80 3.16 

Ref Value 

-131996.50 

2288065.50 

296688.63 

9010487.00 

567642.88 

195897.47 

2047839.80 

4264824.00 

2120616.30 

14245596.00 

19298392.00 

18735534.00 

0.95 3646344.80 

1.22 537987.94 

0.74 17012292.00 

0.13 949396.31 

1.23 338792.91 

0.67 3456710.80 

0.45 6610579.00 

0.33 3651775.30 

0.22 22769202.00 

0.67 28649686.00 

0.11 27453282.00 

Rec(%) QC Range(%) 

49.2 70 120 

62.7 70 120 

55.1 70 - 120 

53.0 70 - 120 

59.8 70 120 

57.8 

59.2 

64.5 

58.1 

62.6 

67.4 

68.2 

70 120 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Flag 

IS Fail 

IS Fail 

IS Fail 

IS Fai 1 

IS Fail 

IS Fail 

IS Fail 

IS Fail 

IS Fail 

IS Fail 

IS Fail 

IS Fail 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn 

30 :Element Failures 

12 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

91271123:31 AM 

Fail 

Fail 

o ,Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmP\CCV.qct Page 1 of 1 
121

C, \ICPCHEM\l \DATA\12I26qOO. B\lOl_CCB .D\lOl_CCB. D# 

CCB QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12126qOO.B\101_CCB.D\101_CCB.D# 

Sep 27 2012 03,40 am 

Sample Name, 

Mise Info: 

NBS 

CCB 120926 

Vial Number, 

Current Method, 

Calibration File, 

Last Cal Update, 

Sample Type, 

Total Dil Factor, 

1102 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Sep 26 2012 05,18 pm 

CCB 

1.00 

QC Elements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

-0.01 ug/l 

7.99ug/l 

136.10 ug/l 

23.12 ug/l 

0.07 ug/l 

67.58 ug/l 

7.81 ug/l 

0.09 ug/l 

0.13 ug/l 

0.00 ug/l 

0.07 ug/l 

2.51ug/l 

0.00 ug/l 

-0.07 ug/l 

0.27 ug/l 

0.27 ug/l 

-0.48 ug/l 

0.04 ug/l 

O.l1ug/l 

1.41 ug/l 

0.00 ug/l 

-0.01 ug/l 

0.05 ug/l 

ug/l 

0.00 ug/l 

ug/l 

0.00 ug/l 

0.30 ug/l 

0.25ug/l 

0.25 ug/l 

0.08 ug/l 

0.02 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

35.06 

2.07 

2.57 

3.88 

1743.40 

3.92 

32.34 

126.54 

2.53 

775.16 

23.27 

31. 44 

450.90 

28.63 

1.53 

7.10 

24.24 

16.24 

4.18 

2.91 

2698.80 

15.62 

12.38 

75.53 

689.81 

15.85 

39.55 

23.85 

2.76 

11.85 

22.19 

48.24 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-131996.50 

3646344.80 

6 Li -70076.81 6.78 

45 Sc 2280102.50 0.39 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

297527.41 

9199227.00 

570441.38 

196082.13 

2053901. 50 

4331588.50 

2179950.00 

14933505.00 

19575280.00 

18972254.00 

0.40 537987.94 

0.68 17012292.00 

0.51 949396.31 

0.54 338792.91 

0.65 3456710.80 

0.47 6610579.00 

0.25 3651775.30 

0.50 22769202.00 

0.20 28649686.00 

0.89 27453282.00 

High Limi t 

""""""" 0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

""""""" 0.09 

""""""" 0.06 

""""""" """"""" 0.30 

0.03 

0.12 

0.03 

""""""" """"""" 0.33 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Rec (%) QC Range (%) Flag 

53.1 70 - 120 IS Fai. 

62.5 70 120 IS FaL 

55.3 

54.1 

60.1 

57.9 

59.4 

65.5 

59.7 

65.6 

68.3 

69.1 

70 -

70 

70 

70 -

70 -

70 

70 -

70 -

70 

70 

120 IS FaL 

120 IS Fai: 

120 IS Fai. 

120 IS FaL 

120 IS Fai. 

120 IS FaL 

120 IS FaL 

120 IS FaL 

120 IS FaL 

120 IS Fai. 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D" 

:Element Failures 

12 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 3:44 AM 

Fail 

Fail 

,Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
122

C.\ICPCHEH\1\DATA\12127s00.B\004CALB.D\004CALB.D# 

Calibration Blank QC Report 

Data File: 

Date Acquired: 

Operator: 

Sample Name: 

Misc Info: 

Vial Number: 

C:\ICPCHEM\1\DATA\12I27s00.B\004CAL 

Sep 27 2012 06:24 pm 

NBS 

Calibration Blank 

Current Method: 

1102 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:21 pm 

Calibration File: 

Last Cal Update: 

Sample Type: CalBlk 

Total Dil Factor: 1. 00 

QC&ISTD Elements 

Element 

6 

7 

9 

11 

23 

24 

27 

39 

44 

45 

45 

45 

47 

51 

52 

55 

56 

59 

60 

63 

65 

66 

72 

72 

72 

75 

78 

78 

88 

88 

95 

106 

107 

108 

111 

115 

115 

115 

118 

118 

118 

121 

137 

159 

165 

205 

206 

207 

208 

Li 

(Li) 

Be 

B 

Na 

Mg 

Al 

K 

Ca 

Sc 

Sc 

Sc 

Ti 

V 

Cr 

Mn 

Fe 

Co 

Ni 

Cu 

Cu 

Zn 

Ge 

Ge 

Ge 

As 

Se 

Se 

Sr 

Sr 

Mo 

(Cd) 

Ag 

(Cd) 

Cd 

In 

In 

In 

Sn 

Sn 

Sn 

Sb 

Ba 

Tb 

Ho 

Tl 

(Pb) 

(Pb) 

Pb 

9/271126:28 PM 

CPS Mean 

-88139.43 A 

7903326.00 A 

45.56 P 

30017.70 P 

62647.53P 

241.12 P 

1245.65 P 

41165.74 P 

1666.77 P 

5590061.00 A 

732360.19 A 

18013600.00 A 

23.56 P 

519.13 P 

665.36 P 

134.22P 

10611.09 P 

56.89 P 

82.67 P 

691. 58 P 

340.90 P 

689.80P 

1407959.00 A 

475526.09 A 

3640663.00 A 

59.44 P 

16.22 P 

156.22 P 

300.01P 

2594.76 P 

1357.89 P 

24.45 P 

50.00 P 

13.33 P 

71.99 P 

10055670.00 A 

4993515.00 A 

20883300.00 A 

1871.30 P 

940.07P 

3706.22 P 

758.94 P 

243.34 P 

23533160.00 A 

22279000.00 A 

173.34 P 

185.56 P 

174.45 P 

706.70 P 

SD 

4741.00 

205200.00 

18.36 

557.30 

517.60 

15.03 

129.80 

736.70 

23.37 

77690.00 

7292.00 

146800.00 

4.29 

47.41 

34.74 

18.15 

182.60 

4.68 

24.33 

42.21 

14.87 

20.93 

32860.00 

5892.00 

21880.00 

4.17 

0.51 

10.46 

15.28 

121.00 

76.19 

7.70 

5.77 

6.67 

13.83 

213100.00 

40850.00 

82490.00 

77.50 

43.34 

205.30 

55.21 

15.28 

228000.00 

264000.00 

32.83 

26.94 

11.71 

32.83 

RSD(%) 

5.38 

2.60 

40.30 

1. 86 

0.83 

6.23 

10.42 

1. 79 

1. 40 

1.39 

1. 00 

0.81 

18.20 

9.13 

5.22 

13.52 

1.72 

8.23 

29.43 

6.10 

4.36 

3.03 

2.33 

1. 24 

0.60 

7.01 

3.14 

6.70 

5.09 

4.66 

5.61 

31. 49 

11.55 

50.00 

19.21 

2.12 

0.82 

0.40 

4.14 

4.61 

5.54 

7.27 

6.28 

0.97 

1.19 

18.94 

14.52 

6.71 

4.65 

C:\ICPCHEM\1\rpttmp\Ca1Blk.qct Page 1 of 1 
123

9/27/126:34 PM 

C: \ ICPCHEM\ 1 \DATA \12 r271100. B\OOSCALS. D\OOSCALS .D' 

Calibration Standard QC Report 

Data File: 

Date Acquired: 

c, \ ICPCHEM\ 1 \oATA \12 127s00. B\005CALS. o\005CALS. on 

Sep 27 2012 06,31 pm 

Operator: NBS 

Sample Name: 120927 Standard 1 

Misc Info: 

Vial Number: 1103 

Current Method: 

Calibration File: 

Last cal Update: 

C, \ICPCHEM\l \METHOoS\CSC-MoL2.M 

C, \ICPCHEM\l \CALIB\CSC-MoL2.C 

Sep 27 2012 06,28 pm 

Sampl e Type, 

Total Dil Factor: 

CalStd 

1. 00 

QC&ISTD Elements 

Element CPS Mean 

Li -79461.60A 

(Li) 7917991.00 A 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

45 Sc 

45 Se 

45 Se 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

72 Ge 

72 Ge 

72 Ge 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

115 In 

115 In 

115 In 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

159 Tb 

165 Ho 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

7970.17 P 

38071.99P 

80964.98 P 

86783.83 P 

15028.11P 

50302.97 P 

7811.61 P 

5655816.00 A 

725914.00A 

18390580.00A 

348.45P 

4826.63 P 

6010.64 P 

3725.86P 

472681.50 P 

7766.16P 

2113.07 P 

6019.10P 

2887.44 P 

2462.91 P 

1446652.00 A 

486976.50A 

3706852.00A 

848.03 P 

397.67 P 

251.78P 

6495.05 P 

56656.70 P 

20691.20 P 

526.70 P 

25541.62 P 

430.02 P 

5435.98 P 

10203640.00A 

5045017.00 A 

20863360.00 A 

13 751. 63 P 

7726.86 P 

31247.88 P 

38870.35 P 

6946.42 P 

23940950.00A 

22745950.00 A 

29920.09 P 

10595.71 P 

8881.08 P 

41176.38 P 

ISTD Elements 

so 

2580.00 

145200.00 

175.20 

676.50 

477.80 

402.60 

310.50 

1255.00 

89.84 

22800.00 

4685.00 

22150.00 

14.63 

54.44 

118.30 

58.50 

3106.00 

97.06 

22.48 

148.80 

28.49 

55.45 

8970.00 

2930.00 

29900.00 

18.82 

16.71 

9.98 

29.63 

727.40 

458.40 

28.48 

640.80 

43.34 

4.16 

97010.00 

30340.00 

161600.00 

129.00 

113.50 

344.50 

247.70 

299.00 

357200.00 

219600.00 

203.10 

70.72 

93.92 

396.90 

RSo(%) 

3.25 

1. 83 

2.20 

1. 78 

0.59 

0.46 

2.07 

2.49 

1.15 

0.40 

0.65 

0.12 

4.20 

1.13 

1. 97 

1. 57 

0.66 

1.25 

1. 06 

2.47 

0.99 

2.25 

0.62 

0.60 

0.81 

2.22 

4.20 

3.96 

0.46 

1. 28 

2.22 

5.41 

2.51 

10.08 

0.08 

0.95 

0.60 

0.77 

0.94 

1. 47 

1.10 

0.64 

4.30 

1. 49 

0.97 

0.68 

0.67 

1. 06 

0.96 

Element CPS Mean RSD(%:) Ref Value 

-88139.43 

Ree (%) QC Range (%) 

Li -79461.60 3.25 

45 Se 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

5655816.500.405590061.50 

725914 .00 0.65 732360.19 

18390584.00 0.12 18013604.00 

1446651.60 0.62 1407958.90 

486976.50 0.60 475526.09 

3706851.80 0.81 3640663.30 

10203645.00 0.95 10055673.00 

5045017.00 0.60 4993515.00 

20863356.00 0.77 20883300.00 

23940950.00 1.4923533162.00 

22745950.00 0.97 22278996.00 

90.2 70-

101.2 

99.1 

102.1 

102.7 

102.4 

101. 8 

101.5 

101. 0 

99.9 

101. 7 

102.1 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

Cal Coef 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

0.0000 

Flag 

120 IS Fail 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File : c, \ lCPCHEM\l \oATA \12 127s00. B \004CALB. o\004CALB. on 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

:Max. Number of Failures Allowed 

;Max. Number of ISTD Fa'ilures Allowed 

C. \ ICPCHEM\l \RPTTMP\CalStdx.qct Page 1 of1 
124

9/27{12 6:41 PM 

C: \ICPCHKK\l \DATA \12127.00 .B\OD6CA[..B .D\DD6CALB .DI 

Calibration Standard QC Report 

Data File: 

Date Acquired: 

c, \ ICPCHEM\l \OATA \12I27s00. B\006CALS. 0\00 6CALS. 0# 

Sep 27 2012 06,37 pm 

Operator: NBS 

Sample Name: 120927 Standard 2 

Misc Info: 

Vial Number: 1104 

Current Method: 

Calibration File: 

Last Cal Update: 

c, \ ICPCHEM\l \METIiOOS\CSC-MOL2 . M 

C, \ ICPCHEM\l \CALIB\CSC-MOL2.C 

Sep 27 2012 06,34 pm 

Sample Type: CalStd 

Total Oil Factor 1 1. 00 

QC&ISTD Blements 

Element CPS Mean 

6 Li -74083.47 A 

(Li) 7913410.00A 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

45 Se 

45 Se 

45 Se 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

72 Ge 

72 Ge 

72 Ge 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

III Cd 

115 In 

115 In 

115 In 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

159 Tb 

165 Ho 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

81222.73 P 

87464.79P 

234750.70 P 

949219.81A 

139950.59 P 

134157.09 P 

59557.17 P 

5740691.00A 

742203.63 A 

18341010.00 A 

3050.58P 

44537.78 P 

53512.48 P 

34925.81P 

4801609.00 A 

76642.34 P 

19623.14 P 

53709.16 P 

26038.59 P 

11630.56 P 

1458780.00 A 

484064.91 A 

3698306.00 A 

8034.24 P 

3848.08 P 

994.37P 

60448.72 P 

533160.13P 

198190.41P 

4991.06 P 

251216.20 P 

3921. 78 P 

53158.30 P 

10266880.00 A 

5091337.00 A 

20604500.00 A 

120525.40 P 

67725.74 P 

276397.41P 

384442.50 P 

67506.51 P 

23944500.00 A 

22713590.00A 

297932.00 P 

101841. 80 P 

85295.77 P 

398321. 00 P 

ISTD Elements 

SO 

7907.00 

91270.00 

652.90 

327.50 

661.30 

10050.00 

279.10 

961. 80 

301.00 

42720.00 

2871. 00 

251300.00 

46.58 

283.80 

194.00 

253.20 

19380.00 

184.80 

83.34 

828.10 

179.50 

101. 4 0 

19640.00 

4098.00 

34850.00 

135.60 

74.35 

21. 61 

318.20 

1797.00 

813.00 

55.11 

2057.00 

111.30 

235.10 

104900.00 

31490.00 

118900.00 

1746.00 

283.70 

714.90 

2318.00 

455.50 

117700.00 

38770.00 

2700.00 

1444.00 

403.20 

1278.00 

RSO(') 

10.67 

1.15 

0.80 

0.37 

0.28 

1. 06 

0.20 

0.72 

0.51 

0.74 

0.39 

1. 37 

1. 53 

0.64 

0.36 

0.72 

0.40 

0.24 

0.42 

1. 54 

0.69 

0.87 

1. 35 

0.85 

0.94 

1.69 

1. 93 

2.17 

0.53 

0.34 

0.41 

1.10 

0.82 

2.84 

0.44 

1. 02 

0.62 

0.58 

1. 45 

0.42 

0.26 

0.60 

0.67 

0.49 

0.17 

0.91 

1. 42 

0.47 

0.32 

Cal Coef 

0.0000 

1.0000 

1. 0000 

1. 0000 

1. 0000 

1. 0000 

1. 0000 

1. 0000 

1. 0000 

0.0000 

0.0000 

o .0000 

1.0000 

1. 0000 

1.0000 

1. 0000 

1. 0000 

1. 0000 

1.0000 

1.0000 

1. 0000 

1.0000 

0.0000 

0.0000 

0.0000 

1. 0000 

1.0000 

1.0000 

1.0000 

1.0000 

1.0000 

1.0000 

1. 0000 

1. 0000 

1.0000 

0.0000 

0.0000 

0.0000 

1.0000 

1. 0000 

1.0000 

1. 0000 

1. 0000 

0.0000 

0.0000 

1.0000 

1.0000 

1.0000 

1.0000 

Element CPS Mean RSO (') 

6 Li -74083.48 10.67 

Ref Value 

-88139.43 

5590061.50 

732360.19 

Ree(') QC Range(%) 

84.170- 120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

45 Se 5740691. 50 0.74 

45 Se 742203.63 0.39 

45 Se 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

18341012.00 1. 37 18013604.00 

1458780.30 1.35 1407958.90 

484064.94 0.85 475526.09 

3698305.80 0.94 3640663.30 

10266882.00 1.02 10055673.00 

5091337.50 0.624993515.00 

20604496.00 0.58 20883300.00 

23944504.00 0.4923533162.00 

22713588.00 0.17 22278996.00 

102.7 70-

101.3 70 -

101.8 

103.6 

101. 8 

101.6 

102.1 

102.0 

98.7 

101. 7 

102.0 

70 -

70 -

70 -

70 -

70 -

70 -

70 . 

70 -

70 -

ISTD Ref File : c, \ ICPCHEM\l \ DATA \12127800. B\004CALB. 0\004CALB .0# 

:Element Failures 

: ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

:Max. Number of Failures Allowed 

: Max. Number of ISTD Fai lures Allowed 

C. \ICPCHEM\l \RPTTMP\Calstdx.qct 

Flag 

IS Fail 

Page 1 of 1 
125 127/126;48 PM 

c: \ICPC'HID4\l \DATA \12127.00. B\007CALS. D\007CALS. D' 

Calibration Standard QC Report 

Data File: 

Date Acquired: 

c, \ ICPCHEM\l \ DATA \1212 7s00. B\007CALS .D\007CALS. 0# 

Sep 27 2012 06,44 pm 

Operator: NBS 

Sample Name: 120927 Standard 3 

Misc Info: 

Vial Number: 1105 

Current Method: 

Calibration File: 

C, \ ICPCHEM\ 1 \METHODS\CSC-MDL2.M 

C, \ ICPCHEM\l \CALIB\CSC-MDL2.C 

Last Cal lJpdate: sep 27 2012 06;41 pm 

Sample Type, 

Total Dil Factor: 

CalStd 

1. 00 

QC&ISTD Elements 

Element CPS Mean 

6 Li -79024.59A 

(Li) 7966219.00A 

Be 

II B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

45 Sc 

45 Sc 

45 Sc 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

72 Ge 

72 Ge 

72 Ge 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

115 In 

115 In 

115 In 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

159 Tb 

165 Ho 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

872271.00A 

613779.31 M 

1950815.00A 

8859926.00A 

1531080.00 A 

1046506.00A 

561527.38P 

5718452.00 A 

736497.38A 

18361220.00 A 

30192.44 P 

428244.00 P 

509199.31 P 

337043.31P 

46317472.00A 

731149.63 P 

187009.09P 

504469.50 P 

245330.00 P 

98290.86P 

1438381. OOA 

483861.31 A 

3729901.00A 

76900.68P 

36547.99P 

8096.61 P 

582633.00 P 

5624660.00A 

2120572.00 A 

47918.89P 

2626533.00 A 

37867.33 P 

519130.69 P 

10120670.00A 

4917685.00 A 

20177140.00A 

1295272.00A 

652734.38 P 

2960587.00A 

4142146.00 A 

660981.69 P 

23522870.00 A 

22364340.00A 

3204610.00 A 

1000439.00 M 

800689.50 P 

4062204.00 A 

ISTD Elements 

Element CPS Mean RSD (\) 

6 Li -79024.59 7.40 

45 Sc 5718452.50 0.07 

so 

5848.00 

71360.00 

7312.00 

44090.00 

15320.00 

98930.00 

23660.00 

2598.00 

3857.00 

3854.00 

5865.00 

75080.00 

307.40 

549.90 

2544.00 

566.30 

495900.00 

1897.00 

1713.00 

4586.00 

1438.00 

852.70 

17480.00 

2149.00 

12090.00 

245.70 

470.60 

18.53 

2861.00 

49530.00 

25750.00 

261. 50 

25480.00 

366.80 

2242.00 

152600.00 

7485.00 

108100.00 

12340.00 

3736.00 

13350.00 

33260.00 

3160.00 

156100.00 

200200.00 

24170.00 

72930.00 

4088.00 

50350.00 

Ref value 

-88139.43 

5590061.50 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

736497.38 0.80 732360.19 

18361224.00 0.4118013604.00 

1438381.50 1.22 1407958.90 

483861.34 0.44 475526.09 

3729900.80 0.32 3640663.30 

10120667.00 1. 51 10055673.00 

4917685.50 0.15 4993515.00 

20177142.00 0.54 20883300.00 

23522868.00 0.6623533162.00 

22364342.00 0.9022278996.00 

RSD(%) 

7.40 

0.90 

0.84 

7.18 

0.79 

1.12 

1.55 

0.25 

0.69 

0.07 

0.80 

0.41 

1. 02 

0.13 

0.50 

0.17 

1. 07 

0.26 

0.92 

0.91 

0.59 

0.87 

1.22 

0.44 

0.32 

0.32 

1.29 

0.23 

0.49 

0.88 

1.21 

0.55 

0.97 

0.97 

0.43 

1. 51 

0.15 

0.54 

0.95 

0.57 

0.45 

0.80 

0.48 

0.66 

0.90 

0.75 

7.29 

0.51 

1. 24 

Rec(%) QC Range(%) 

89.7 70-

102.3 70-

100.6 70-

101.9 70-

102.2 

101.8 

102.5 

100.6 

98.5 

96.6 

100.0 

100.4 

70 -

70 -

70 -

70 -

70 -

70 -

70 -

70 -

Cal Coef 

0.0000 

0.2996 

1. 0000 

0.9996 

0.9999 

1. 0000 

1. 0000 

1.0000 

1. 0000 

0.0000 

0.0000 

0.0000 

1. 0000 

1. 0000 

1.0000 

1.0000 

1.0000 

1.0000 

1.0000 

1.0000 

1.0000 

0.9981 

0.0000 

0.0000 

0.0000 

1. 0000 

1. 0000 

0.9999 

1. 0000 

1.0000 

1.0000 

1.0000 

1.0000 

1.0000 

1. 0000 

0.0000 

0.0000 

0.0000 

1. 0000 

1. 0000 

1.0000 

1. 0000 

1.0000 

0.0000 

0.0000 

1.0000 

1.0000 

1.0000 

1.0000 

Flag 

120 IS Fail 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

ISTD Ref File , c, \ ICPCHEM\l \ DATA \12127500. B\ 004CALB. D\004CALB. 0# 

:Element Failures 

1 : I STD Fai lures 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C.\ICPCHEM\l\RPTTMP\CalStdx.qct Page 1 of 1 
126

C: \ICPCHEM\l \DATA\12I27.00. B\OOB_OCS. D\OOB_OCS. D# 

QCS QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12127S00.B\008_QCS.D\008_QCS.D# 

Sep 27 2012 06:50 pm 

Operator: 

Sample Name: 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

Sample Type: 

Total Dil Factor: 

NBS 

ICV 120927 

1107 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

QCS 

1. 00 

QC Elements 

Element Cone. RSD(%) Expected QC Range(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

37.18 ug/l 

38.97 ug/l 

3855.00 ug/l 

4156.00 ug/l 

3592.00 ug/l 

3861. 00 ug/l 

4049.00 ug/l 

27.29 ug/l 

40.04 ug/l 

40.21 ug/l 

40.60 ug/l 

3997.00 ug/l 

39.88 ug/l 

40.53 ug/l 

39.86 ug/l 

39.71 ug/l 

40.19 ug/l 

37.43 ug/l 

39.26 ug/l 

39.03 ug/l 

37.96 ug/l 

38.34 ug/l 

34.83 ug/l 

ug/l 

192.80 ug/l 

ug/l 

38.37 ug/l 

3.58 ug/l 

3.40 ug/l 

3.07 ug/l 

35.59 ug/l 

37.63 ug/l 

38.32 ug/l 

ug/l 

ug/l 

36.78 ug/l 

1. 94 

1. 46 

2.29 

1.18 

1.11 

0.77 

0.72 

0.65 

1. 58 

1. 55 

1. 08 

1. 43 

0.48 

0.47 

1. 02 

1.36 

0.71 

0.68 

1. 65 

2.04 

0.67 

1. 33 

0.92 

2.11 

1.30 

2.07 

3.36 

6.25 

0.67 

1. 71 

2.03 

1.41 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061. 50 

732360.19 

Li -88795.66 10.54 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

5927146.50 

753954.75 

18857634.00 

1478545.50 

493392.72 

3761570.30 

10422317.00 

5103784.00 

20926948.00 

23880362.00 

22720544.00 

1. 44 

1. 31 

1.13 18013604.00 

0.34 1407958.90 

0.42 475526.09 

0.79 3640663.30 

0.43 10055673.00 

0.65 4993515.00 

0.60 20883300.00 

1.68 23533162.00 

0.75 22278996.00 

100.00 90 110 

40.00 

40.00 

4000.00 

4000.00 

4000.00 

4000.00 

4000.00 

40.00 

40.00 

40.00 

40.00 

4000.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

20.00 

20.00 

20.00 

40.00 

40.00 

40.00 

40.00 

40.00 

40.00 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 110 

90 - 110 

90 110 

90 110 

90 110 

Rec(%) QC Range(%) 

100.7 

106.0 

102.9 

104.7 

105.0 

103.8 

103.3 

103.6 

102.2 

100.2 

101. 5 

102.0 

70 

70 

120 

120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

Flag 

Fail 

Fail 

Fail lIlT 

Fail 

Fail; Fail ,JI Fail 

Fail 

Flag 

IS Fail fJl!.. 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

:Element Failures 0 :Max. Number of Failures Allowed 

:ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/27112 6:54 PM C:\ICPCHEM\l\rpttmp\QCS.qct Page 1 of 1 
127

c, \ICPCHEII\ 1 \DATA\ l2127.00 .B\OlO_CCB .D\OlO_CCB .D# 

CCB QC Report 

Data File: 

Date Acquired: 

C,\ICPCHEM\1\DATA\12127s00.B\010_CCB.D\010_CCB.D# 

Sep 27 2012 07:04 pm 

Operator: NBS 

Sample Name: ICB 120927 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1102 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: CCB 

Total Dil Factor: l. 00 

QC Elements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Sa 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.00 ug/l 

0.90 ug/l 

0.23 ug/l 

0.10 ug/l 

-0.05 ug/l 

3.36 ug/l 

-l. 44 ug/l 

-0.09 ug/l 

-0.02 ug/l 

0.00 ug/l 

0.01 ug/l 

-0.15 ug/l 

0.00 ug/l 

0.01 ug/l 

0.01 ug/l 

-0.01 ug/l 

0.09 ug/l 

0.02 ug/l 

0.01 ug/l 

0.14 ug/l 

0.00 ug/l 

0.00 ug/l 

-0.05 ug/l 

ug/l 

0.09 ug/l 

ug/l 

0.00 ug/l 

0.09 ug/l 

0.14 ug/l 

0.09 ug/l 

0.05 ug/l 

0.00 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

81.81 

21. 58 

437.74 

78.33 

157.16 

39.23 

211.78 

28.27 

49.03 

208.69 

4.74 

14.60 

142.63 

124.30 

69.47 

114.24 

26.79 

17.73 

87.64 

44 .66 

164.77 

131.57 

0.57 

7.90 

244.22 

4.02 

9.99 

21.33 

10.62 

86.58 

16.25 

59.11 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

Li -88949.12 4.47 -88139.43 

45 Sc 5875857.00 l. 06 559006l. 50 

45 Sc 748267.06 0.51 732360.19 

45 Sc 18769994.00 0.85 18013604.00 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

1480136.50 

49304l. 34 

3731785.50 

10478834.00 

5105096.50 

21188870.00 

23826704.00 

22633512.00 

l. 04 1407958.90 

0.24 475526.09 

1.31 3640663.30 

0.61 10055673.00 

1.05 4993515.00 

0.63 20883300.00 

0.91 23533162.00 

0.46 22278996.00 

High Limit 

####### 

0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

100.9 70 

105.1 70 

102.2 70 -

104.2 70 

105.1 70 

103.7 

102.5 

104.2 

102.2 

101.5 

10l. 2 

101.6 

70 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail 

Fail 

Flag 

IS Fai. 

ISTD Ref File: C:\ICPCHEM\1\DATA\12127s00.B\004CALB.D\004CALB.D# 

:Element Failures :Max. Number of Failures Allowed 

1 :ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes : Fail 

ISTD: Fail 

9/271127:08 PM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
128

C, \ICPCIIEM\l \DATA\12I27.00. B\OllSMPL .D\OllSMPL.D# 

Sample QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I27S00.B\011SMPL.D\011SMPL.D# 

Sep 27 2012 07,10 pm 

Sample Name, 

Mise Info: 

NBS 

LLICV 120927 

Vial Number, 

Current Method: 

Calibration File: 

Last Cal Update, 

Sample Type, 

Prep Dil Factor: 

1103 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

1.00 

Total Dil Factor, 1. 00 

QC Elements 

Element 

(Li) 

Cone. 

ug/l 

0.94 ug/l 

1.61 ug/l 

21.86 ug/l 

241.90 ug/l 

89.74 ug/l 

18.44 ug/l 

Carr. Cone. 

#VALUEI 

0.94 

1.61 

21.86 

241.90 

89.74 

18.44 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

267.80 ug/l 

1.90 ug/l 

1.00 ug/l 

1.03 ug/l 

1.02 ug/l 

98.99 ug/l 

1.04 ug/l 

1.06 ug/l 

1.04 ug/l 

1.05 ug/l 

1.71 ug/l 

0.99 ug/l 

0.99 ug/l 

1.12 ug/l 

1.01 ug/l 

0.91 ug/l 

1.72 ug/l 

ug/l 

0.96 ug/l 

ug/l 

0.99 ug/l 

1.87 ug/l 

2.00 ug/l 

1.82 ug/l 

1.79 ug/l 

0.97 ug/l 

0.91 ug/l 

ug/l 

ug/l 

0.95 ug/l 

267.80 

1. 90 

1. 00 

1. 03 

1.02 

98.99 

1.04 

1. 06 

1. 04 

1.05 

1. 71 

0.99 

0.99 

1.12 

1. 01 

0.91 

1. 72 

#VALUEI 

0.96 

#VALUEI 

0.99 

1. 87 

2.00 

1.82 

1. 79 

0.97 

0.91 

#VALUEI 

#VALUEI 

0.95 

ISTD Elements 

Element 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

CPS Mean RSD (%) 

-82968.41 3.72 

5940541.00 0.98 

Ref Value 

-88139.43 

5590061.50 

760440.06 

18896988.00 

1483715.10 

492921.63 

3742942.00 

10470458.00 

5203708.00 

21196740.00 

23949770.00 

22659082.00 

0.95 732360.19 

1.33 18013604.00 

0.58 1407958.90 

0.97 475526.09 

0.30 3640663.30 

1.40 10055673.00 

0.81 4993515.00 

0.72 20883300.00 

1.07 23533162.00 

0.31 22278996.00 

RSD(%) High Limit Flag 

o 5.62 1000 

4.89 1000 

1.53 25000 

0.67 50000 

2.02 20000 

1. 34 20000 

0.42 50000 

4.71 1000 

1.00 1000 

1. 21 1000,01, 'J. 

1.98 1000 

0.60 20000 

1. 49 

1. 80 

2.63 

2.35 

4.40 

0.84 

0.83 

14.43 

2.75 

2.08 

1.58 

1. 24 

1.17 

1.11 

3.69 

0.29 

1.59 

0.93 

2.17 

1.14 

Rec(%) 

94.1 

106.3 

103.8 

104.9 

105.4 

103.7 

102.8 

104.1 

104.2 

101.5 

101. 8 

101.7 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

"1"1./. 

0,,, 'I. 

" I '/. 

<If ~ 'I. 

QC Range (%) Flag 

70 120 IS Fai 

70 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 -

70 

120 

120 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

o :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271127:14 PM 

Pass 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C,\ICPCHBM\l\rpttmp\Sample.qct Page 1 of 1 
129

C I \ICPCHEM\l \Dl1'A \1:1: UhOO .B\012 IC6'1.D\012 ICS1.pM 

ICS-A QC Report 

Data Flle: 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I27S00.B\012ICSA.D\012ICSA.D# 

Sep 27 2012 07,17 pm 

Acq. Method, 

Operator: 

Sample Name: 

Mise Info: 

Vi a1 Number: 

Current Method: 

Calibration File: 

Last Cal. Update, 

Sample Type, 

Di 1 ut ion Factor: 

OC Elements 

Element IS Ref 

7 (Ll) 

9 Be 45 

11 B 45 

23 Na 45 

24 Mg 45 

27 Al 45 

39 K 45 

44 Ca 45 

47 Ti 45 

51 V 45 

52 Cr 45 

55 Mn 45 

56 Fe 45 

59 Co 45 

60 Ni 45 

63 Cu 45 

65 Cu 45 

66 Zn 115 

75 As 115 

78 Se 115 

78 Se 115 

88 Sr 115 

88 Sr 115 

95 Mo 115 

106 (cd) 

107 Ag 115 

108 (Cd) 

111 Cd 115 

118 Sn 115 

118 Sn 115 

118 Sn 115 

121 Sb 115 

137 Ba 115 

205 Tl 159 

206 (pb) 

207 (Pb) 

208 Pb 159 

ISTD Elements 

Element 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

Tune 

3 

1 

2 

3 

3 

3 

3 

3 

3 

3 

3 

Tune 

3 

3 

CSC-MDL2.M 

NBS 

FGD MATRIX 

2101 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

ICSA 

1. 00 

Cone. 

ug/l 

0.03 ug/l 

0.29 ug/l 

899900.00 ug/l 

911300.00 ug/l 

6.68 ug/l 

19.78 ug/l 

1954000.00 ug/l 

0.13 ug/l 

0.17 ug/l 

0.62 ug/l 

0.83 ug/l 

14.05 ug/l 

0.22 ug/l 

1. 67 ug/l 

0.08 ug/l 

0.31 ug/l 

1. 02 ug/l 

0.62 ug/l 

0.32 ug/l 

1. 33 ug/l 

122.00 ug/l 

120.50 ug/l 

0.02 ug/l 

ug/l 

0.19ug/1 

ug/l 

0.06 ug/l 

1. 96 ug/l 

2.24 ug/l 

2.00 ug/l 

3.67 ug/l 

2.31 ug/l 

0.05 ug/l 

ug/l 

ug/l 

1. 84 ug/l 

CPS Mean 

-89208 

5404673 

809597 

RSD(%) 

3.74 

0.37 

1. 07 

17657602 0.71 

1149240 0.48 

433848 0.87 

3080454 

7954718 

4127340 

15664644 

16644687 

15533937 

0.91 

0.35 

0.40 

0.61 

0.36 

0.90 

RSD(%) 

19.15 

14.65 

0.42 

0.21 

2.59 

6.75 

0.77 

25.09 

5.68 

0.94 

1. 51 

0.79 

5.64 

1. 64 

17.60 

3.21 

6.50 

4.29 

7.76 

10.75 

0.19 

0.90 

27.19 

3.86 

13.80 

1. 65 

2.99 

1. 98 

0.95 

3.04 

4.90 

0.64 

Ref Value 

-88139 

5590062 

732360 

18013604 

1407959 

475526 

3640663 

10055673 

4993515 

20883300 

23533162 

22278996 

Tune Flle# c'\lcpchem\1\7500\h2_hITQ.u 

Tune File# c'\lcpchem\1\7500\he_hmi.u 

Tune Flle# c'\lcpchem\1\7500\ng_hml.u 

Data Results: 

Analytes: Fail 

ISTD: Fail 

Hlgh LiITQ t ppb 

Rec (%) 

101. 2 

96.7 

110.5 

98.0 

81. 6 

91.2 

84.6 

79.1 

82.7 

75.0 

70.7 

69.7 

..:68.55 

3 75 

QC Range (%) 

70 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 120 

Flag 

Pail 

Fall 

Flag 

IS Fail 

IS Fall tJr 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

:Element Failures :Max. Number of Fallures Allowed 

:ISTD Failures :Max. Nnumber of ISTD FaIlures Allowed 

9/27/127:21 PM C:\ICPCHEM\1\RPTTMP\6020ICSA.qct Page 1 of 1 
130

C I \ICPCHD(\l \DATA \12 %27 .. 00 .»\013ICSB.D\013ICSB .n" 

ICS-AB QC Report 

Data File: 

Date Acquired: 

Acq. Method: 

Operator: 

Sample Name: 

MIse Info: 

Vi al Number: 

Current Method: 

Calibration File: 

Last Cal. Update: 

Sample Type: 

DIlutIon Factor: 

OC Elements 

C:\ICPCHEM\1\DATA\12I27s00.B\013ICSB.D\013ICSB.D# 

Sep 27 2012 07:24 pm 

CSC-MDL2.M 

NBS 

FGD MATRIX SPIKED 

2102 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

ICSAB 

1. 00 

Data Results: 

Analytes: Fail 

ISTD: Fail 

Element IS Ref Tune Conc. ppb RSD(%) Expected 

100 

40 

40 

5000 

5000 

4000 

%Recovery 

#VALUEI 

82.2 

85.4 

16002.0 

16314.0 

106.2 

OC Range(%) 

7 (Li) --------.------. 70 130 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Tl 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

45 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

115 

159 

159 

ISTD Elements 

Element 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

Tune Flle# 

Tune FlIeD 

Tune File# 

3 

2 

2 

2 

2 

2 

2 

2 

2 

2 

2 

2 

1 

2 

3 

3 

2 

3 

3 

3 

Tune 

3 

1 

2 

3 

1 

32.87 

34.16 

800100.00 

815700.00 

4249.00 

4303.00 

1773000.00 

31. 00 

42.83 

40.01 

41. 63 

3655.00 

35.80 

35.19 

32.21 

0.30 

0.73 

0.92 

0.70 

6.31 

0.75 

0.36 

1. 11 

0.12 

0.40 

0.37 

0.19 

0.59 

0.64 

0.92 

32.48 0.22 

43.41 1.46 

55.45 0.91 

53.82 3.84 

65.47 0.97 

166.70 4.80 

156.70 1.54 

45.24 1.68 

35.73 0.89 

41.32 0.94 

5.40 3.36 

5.94 0.62 

5.40 0.84 

43.62 1. 51 

45.24 1.52 

31.95 0.96 

36.15 0.45 

CPS Mean 

-102651 

5930639 

861957 

19232968 

1267534 

472114 

3412355 

8534682 

4348852 

17382268 

17918272 

RSD(%) 

5.40 

1. 42 

0.40 

0.94 

0.68 

1. 27 

1. 86 

1. 38 

0.29 

1. 37 

0.77 

16728765 0.72 

40 

6000 

40 

40 

40 

40 

4000 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

40 

20 

20 

20 

20 

20 

40 

40 

40 

40 

Ref Value 

-88139 

5590062 

732360 

18013604 

1407959 

475526 

3640663 

10055673 

4993515 

20883300 

23533162 

22278996 

c:\lcpchem\1\7500\h2_hmi.u 

c:\lcpchem\1\7500\he_hml.u 

c:\lcpchem\1\7500\ng_hmi.u 

10757.5 

29550.0 

77.5 

107.1 

100.0 

104.1 

91.4 

89.5 

88.0 

80.5 

81.2 

108.5 

138.6 

134.6 

163.7 

416.8 

391.8 

113.1 

#VALUEI 

89.3 

#VALUEI 

103.3 

27.0 

29.7 

27.0 

218.1 

226.2 

79.9 

#VALUEI 

#VALUE! 

90.4 

Rec (%) 

116.5 

106.1 

117.7 

106.8 

90.0 

99.3 

93.7 

84.9 

87.1 

83.2 

76.1 

75.1 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

70 

10 

10 

10 

10 

70 

10 

10 

10 

70 

10 

10 

10 

10 

10 

10 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

130 

OC Range(%) 

70 120 

10 120 

10 120 

10 120 

10 120 

70 120 

10 120 

10 120 

70 120 

10 120 

70 120 

10 120 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

:Element FaIlures 

: I STD FaIlures 

:Max. Number of FaIlures Allowed 

:Max. Number of ISTD Failures Allowed 

Flag 

Fall 

Fall 

Fall ~""\ 

Fall ..,T 

Fail pJ T 

Flag 

IS Fail tvl 

9127112 7:28 PM C:\ICPCHEM\I\RPTTMP\6020ICSB.qct Page 1 011 
131

C: \ICPCHEM\l \OATA\12I27s00. B\OlS_CC:V .0\OlS_CC:V .0# 

CCV QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27s00.B\015_CCV.D\015_CCV.D# 

Sep 27 2012 07:37 pm 

Operator: NBS 

Sample Name: CCV 120927 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File: 

Last Cal Update: 

1106 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: CCV 

Total Dil Factor: 1.00 

QC Elements 

Element 

(Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

51. 59 ug/l 

53.71 ug/l 

1353.00 ug/l 

13310.00 ug/l 

5651.00 ug/l 

987.10 ug/l 

13350.00 ug/l 

103.00 ug/l 

50.77 ug/l 

48.95 ug/l 

50.71 ug/l 

4898.00 ug/l 

48.96 ug/l 

48.03 ug/l 

47.69 ug/l 

47.47 ug/l 

52.39 ug/l 

53.30 ug/l 

53.83 ug/l 

57.06 ug/l 

54.14 ug/l 

51.77 ug/l 

101.90 ug/l 

ug/l 

51.06 ug/l 

ug/l 

50.43 ug/l 

94.28 ug/l 

101.80 ug/l 

102.50 ug/l 

101.00 ug/l 

50.52 ug/l 

49.83 ug/l 

ug/l 

ug/l 

48.80 ug/l 

Element CPS Mean RSD(%) 

Li -146158.83 7.35 

45 Sc 6267881.50 0.66 

RSD(%) Expected QC Range(%) 

50.00 90 - 110 

1. 68 50.00 90 110 

0.94 50.00 

0.27 1250.00 

0.57 12500.00 

1.29 5000.00 

0.78 1000.00 

0.42 12500.00 

90 110 

90 110 

90 110 

90 110 

90 - 110 

90 - 110 

0.40 100.00 90 110 

0.78 50.00 90 110 

1.01 50.00 90 110 

0.32 50.00 90 110 

0.825000.00 90 - 110 

0.21 90 - 110 

0.89 

1.10 

0.70 

1.13 

0.94 

1. 21 

1.47 

0.47 

3.18 

2.63 

1. 88 

2.54 

2.21 

0.54 

2.70 

1.66 

2.83 

1. 35 

1.17 

Ref Value 

-88139.43 

5590061.50 

50.00 

50.00 90 - 110 

50.00 90 110 

50.00 90 - 110 

50.00 90 - 110 

50.00 90 110 

50.00 90 110 

50.00 90 - 110 

50.00 90 110 

50.00 90 110 

100.00 90 - 110 

50.00 90 - 110 

50.00 90 110 

50.00 90 110 

50.00 90 - 110 

##### - ##### 

##### ##### 

100.00 90 - 110 

100.00 90 - 110 

50.00 90 - 110 

50.00 90 110 

50.00 90 110 

50.00 90 - 110 

50.00 90 - 110 

Rec(%) QC Range(%) 

70 

70 

120 

120 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

846493.06 

23068482.00 

1560514.30 

536636.25 

4480422.50 

10577996.00 

0.24 732360.19 

1.71 18013604.00 

165.8 

112.1 

115.6 

128.1 

110.8 

112.9 

123.1 

105.2 

105.1 

118.0 

118.7 

118.0 

70 - 120 

70 120 

5248140.00 

24646030.00 

27943412.00 

26300172.00 

0.75 

0.16 

1407958.90 

475526.09 

2.14 3640663.30 

0.77 10055673.00 

0.54 4993515.00 

2.51 20883300.00 

1.16 23533162.00 

1.97 22278996.00 

70 

70 -

120 

120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 - 120 

Flag 

Fail (IfI 

Fail "" 

Flag 

IS Fail fJ'I 

IS Fail ~r 

IS Fail N7 

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

2 :Element Failures :Max. Number of Failures Allowed 

3 :ISTD Failures :Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/27112 7:41 PM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
132

C, \ ICPCHEM\1 \DATA\12I27.00 .8\017 _CC8. D\017 _CCB. D# 

CCB QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I27s00.B\017_CCB.D\017_CCB.D# 

Sep 27 2012 07,50 pm 

NBS 

CCB 120927 

Vial Number, 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Dil Factor: 

1102 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

CCB 

1.00 

QC Elements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 TI 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.00 ug/l 

0.63 ug/l 

-1. 62 ug/l 

5.65 ug/l 

0.90 ug/l 

9.32 ug/l 

10.27 ug/l 

-0.08 ug/l 

0.03 ug/l 

-0.04 ug/l 

0.01 ug/l 

-0.13 ug/l 

0.00 ug/l 

0.00 ug/l 

0.04 ug/l 

0.04 ug/l 

0.03 ug/l 

0.04 ug/l 

0.01 ug/l 

0.81 ug/l 

0.01 ug/l 

0.01 ug/l 

-0.06 ug/l 

ug/l 

0.01 ug/l 

ug/l 

0.00 ug/l 

0.14 ug/l 

0.17 ug/l 

0.08 ug/l 

0.06 ug/l 

0.00 ug/l 

0.00 ug/l 

ug/l 

ug/l 

0.00 ug/l 

25.72 

159.78 

43.51 

5.79 

76.56 

9.93 

3.67 

9.45 

16.89 

5.99 

23.51 

70.12 

11.85 

228.39 

41.76 

41.95 

17.22 

12.70 

145.05 

0.44 

76.88 

3.68 

7.21 

10.82 

462.37 

14.86 

11.79 

6.81 

8.47 

356.02 

29.10 

3.88 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-162468.08 

6371934.00 

863803.63 

24647802.00 

1602456.50 

553437.50 

4742773.50 

10869377.00 

5512092.00 

27402228.00 

30665950.00 

29010666.00 

3.51 

1. 06 

0.21 732360.19 

3.08 18013604.00 

1. 37 1407958.90 

0.19 475526.09 

2.88 3640663.30 

0.94 10055673.00 

0.61 4993515.00 

2.40 20883300.00 

3.60 23533162.00 

3.75 22278996.00 

High Limit 

####### 

0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

184.3 70 

114.0 70 

117.9 70 

136.8 70 

113.8 70 

116.4 

130.3 

108.1 

110.4 

131.2 

130.3 

130.2 

70 

70 

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail 

Fail 

Flag 

IS fai. 

IS fai. 

,.J" 

IS fai: ,.1"1' 

IS fai: 

IS fai. ~ 

IS fai. tlr 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB D# 

2 :Element Failures 

6 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271127:54 PM 

Fail 

Fail 

:Max. Number of Failures Allowed 

:Max. Number of ISTD Failures Allowed 

C,\ICPCHBM\l\rpttmp\CCB.qct Page 1 of 1 
133

C, \ ICPClIEK\ 1 \DATA \lZI27.00 .B\OZ9_CCV, D\OZ9_CCV .D# 

CCV QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I27S00.B\029_CCV.D\029_CCV.D# 

Sep 27 2012 09,11 pm 

NBS 

Sample Name: CCV 120927 

Mise Info: 

Vial Number: 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Dil Factor: 

1106 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

'78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd)' 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

CCV 

l. 00 

Cone. 

ug/l 

56.34 ug/l 

56.33 ug/l 

1404.00 ug/l 

13820.00 ug/l 

6025.00 ug/l 

1064.00 ug/l 

14170.00 ug/l 

107.50 ug/l 

52.82 ug/l 

50.17 ug/l 

52.78 ug/l 

5038.00 ug/l 

50.16 ug/l 

49.06 ug/l 

48.71 ug/l 

48.73 ug/l 

52.25 ug/l 

53.88 ug/l 

56.73 ug/l 

58.24 ug/l 

57.11 ug/l 

51.49 ug/l 

100.60 ug/l 

ug/l 

50.61 ug/l 

ug/l 

49.57 ug/l 

100.20 ug/l 

105.40 ug/l 

103.10 ug/l 

100.20 ug/l 

5l.04 ug/l 

49.23 ug/l 

ug/l 

ug/l 

48.44 ug/l 

Element CPS Mean RSD(%) 

Li -172280.63 1.60 

45 Sc 6272232.00 0.49 

45 Sc 848366.50 1.99 

RSD(%) Expected QC Range(%) 

3.88 

0.71 

50.00 90 110 

50.00 

50.00 

2.67 1250.00 

1.9212500.00 

1.84 5000.00 

l.82 1000.00 

1.2812500.00 

0.50100.00 

90 110 

90 - 110 

90 - 110 

90 110 

90 110 

90 110 

90 110 

90 110 

2.15 50.00 90 - 110 

90 110 

90 - 110 

90 - 110 

l.92 50.00 

2.44 50.00 

2.31 5000.00 

2.17 

2.65 

2.43 

1. 73 

0.87 

0.94 

1. 32 

1. 56 

0.48 

0.52 

0.93 

0.91 

0.71 

0.87 

0.66 

l. 34 

l. 27 

l. 72 

0.30 

0.98 

Ref Value 

-88139.43 

5590061.50 

732360.19 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.00 90 

50.0090 

50.00 90 

100.00 90 

50.00 90 

50.00 90-

50.00 90 

50.00 90 

##### 

##### 

100.00 90 

100.00 90 

50.00 90 -

50.00 90-

50.00 90 

50.00 90 

50.00 90 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

##### 

##### 

110 

110 

110 

110 

110 

110 

110 

Rec(%) QC Range(%) 

70 - 120 

70 120 

70 120 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

24084944.00 

1579056.60 

535948.06 

4741855.50 

10599475.00 

0.37 18013604.00 

195.5 

112.2 

115.8 

133.7 

112.2 

112.7 

130.2 

105.4 

107.0 

130.0 

128.1 

128.2 

70 120 

5340990.50 

27140082.00 

30135526.00 

28552696.00 

0.54 

l. 36 

0.33 

1407958.90 

475526.09 

3640663.30 

1.24 10055673.00 

0.59 4993515.00 

0.63 20883300.00 

0.81 23533162.00 

0.23 22278996.00 

70 - 120 

70 - 120 

70 - 120 

70 

70 

120 

120 

70 120 

70 120 

70 - 120 

Flag 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail 

Fail r-rt Fail ,J-( 

Flag 

IS Fail 

IS Fail tl T \"t. ~ ,.... .,,1:(' 

IS Fail '1' W"( 

IS Fail 

IS Fail 

IS Fail ,,.rI 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

9 :Element Failures 

6 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271129:14 PM 

Fail 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C,\ICPCHEM\l\rpttmp\CCV.qct Page 1 01 1 
134

C, \ICPCHEM\l \OATA\12127s00. B\031_CCB. 0\031_CCB .0# 

CCB QC Report 

Data File, 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I27s00.B\031_CCB.D\031_CCB.D# 

Sep 27 2012 09,24 pm 

Operator: NBS 

Sample Name: CCB 120927 

Mise Info: 

Vial Number: 

CUrrent Method: 

Calibration File~ 

Last Cal Update, 

Sample Type, 

Total oil Factor, 

1102 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

CCB 

1. 00 

Cone. 

ug/l 

0.00 ug/l 

1.56 ug/l 

10.50 ug/l 

4.37 ug/l 

1. 89 ug/l 

18.69 ug/l 

-3.04 ug/l 

-0.10 ug/l 

0.05 ug/l 

-0.05 ug/l 

0.01 ug/l 

-0.12 ug/l 

0.00 ug/l 

0.00 ug/l 

-0.05 ug/l 

-0.05 ug/l 

0.04 ug/l 

0.04 ug/l 

0.02 ug/l 

1.09 ug/l 

0.00 ug/l 

0.00 ug/l 

-0.06 ug/l 

ug/l 

0.01 ug/l 

ug/l 

0.00 ug/l 

0.23 ug/l 

0.25 ug/l 

0.14 ug/l 

0.07 ug/l 

0.00 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

Element CPS Mean RSD(%) 

RSD(%) 

59.73 

13.88 

14.11 

8.27 

7.81 

8.34 

89.04 

22.86 

5.06 

3.89 

58.53 

32.32 

53.22 

202.63 

1.13 

18.31 

48.80 

12.18 

37.29 

15.73 

206.16 

99.85 

11.72 

4.73 

84.95 

6.76 

8.21 

0.36 

4.71 

158.60 

9.85 

90.19 

High Limit 

####### 

0.12 

15.00 

77 .10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-173881. 47 

6067105.50 

827457.19 

23537194.00 

1521434.40 

526629.31 

4657299.00 

10656626.00 

6.82 

0.78 

Ref Value 

-88139.43 

5590061.50 

197.3 70 120 

5351477.50 

27788430.00 

31549506.00 

29754092.00 

1.18 732360.19 

2.31 18013604.00 

0.26 1407958.90 

1.55 475526.09 

0.98 3640663.30 

0.38 10055673.00 

1.06 4993515.00 

0.98 20883300.00 

0.51 23533162.00 

0.37 22278996.00 

108.5 

113.0 

130.7 

108.1 

110.7 

127.9 

106.0 

107.2 

133.1 

134.1 

133.6 

70 

70 -

70 

70 

70 

70 -

70 

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail 

Fail 

Flag 

IS Fai. 

IS FaL 

IS FaL 

IS Fai. 

IS Fai. 

IS Fai. ,.I .... 

ISTD Ref File, C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

2 :Element Failures :Max. Number of Failures Allowed 

6 ,ISTD Failures ,Max. Number of ISTD Failures Allowed 

Data Results: 

Analytes: Fail 

ISTD: Fail 

9/271129:28 PM C,\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
135

CI \ICPCHEM\l \DATA\ 12127aOO. B\043_CCV. D\043_CCV. ell 

CCV QC Report 

Data File, 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I27S00.B\043_CCV.D\043_CCV.D# 

Sep 27 2012 10,44 pm 

NBS 

Sample Name: CCV 120927 

Mise Info: 

Vial Number, 

Current Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

Total Dil Factor, 

1106 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

CCV 

1.00 

QC Elements 

Element Cone. RSD(%) Expected QC Range(%) 

7 (Li) ug/l 

51. 83 ug/l 

52.45ug/l 

1381.00 ug/l 

13700.00 ug/l 

6093.00 ug/l 

1090.00 ug/l 

14410.00 ug/l 

50.00 90 110 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

107.20 ug/l 

51.99 ug/l 

49.43 ug/l 

53.23 ug/l 

5059.00 ug/l 

49.81 ug/l 

48.22 ug/l 

47.77 ug/l 

47.71 ug/l 

49.64 ug/l 

51.63 ug/l 

54.07 ug/l 

57.61 ug/l 

57.37 ug/l 

50.80 ug/l 

96.77 ug/l 

ug/l 

49.38 ug/l 

ug/l 

48.92 ug/l 

100.30 ug/l 

105.30 ug/l 

103.10 ug/l 

98.56 ug/l 

53.47 ug/l 

50.49 ug/l 

ug/l 

ug/l 

50.07 ug/l 

0.69 50.00 

0.76 50.00 

0.67 1250.00 

0.20 12500.00 

0.29 5000.00 

0.73 1000.00 

0.81 12500.00 

0.28 100.00 

0.97 50.00 

1.20 50.00 

0.43 50.00 

0.82 5000.00 

0.68 50.00 

1. 00 

0.43 

1. 08 

0.58 

0.42 

0.46 

0.66 

0.41 

1.42 

1. 78 

0.71 

1. 40 

0.41 

0.61 

1. 31 

0.90 

1. 80 

0.78 

0.53 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

50.00 

100.00 

50.00 

50.00 

50.00 

50.00 

100.00 

100.00 

50.00 

50.00 

50.00 

50.00 

50.00 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 -

90 

90 

90 -

90 

90 

90 

-

90 

90 

90 

90 

-

90 

90 

##### 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

110 

##### 

##### 

- ##### 

90 110 

90 - 110 

90 - 110 

90 - 110 

90 110 

90 - 110 

90 - 110 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

732360.19 

Rec(%) QC Range(%) 

6 Li 

45 Sc 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

-155881.72 

5090510.50 

694128.56 

21533240.00 

1281427.10 

444393.19 

4358286.00 

8980917.00 

4570515.50 

26421628.00 

31529898.00 

30090092.00 

3.56 

1.16 

0.63 

0.63 18013604.00 

0.53 1407958.90 

1.49 475526.09 

0.55 3640663.30 

0.62 10055673.00 

0.62 4993515.00 

0.70 20883300.00 

0.95 23533162.00 

1.11 22278996.00 

176.9 

91.1 

94.8 

119.5 

91. 0 

93.5 

119.7 

89.3 

91.5 

126.5 

134.0 

135.1 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 - 120 

70 - 120 

70 120 

70 120 

70 120 

70 120 

Flag 

Fail 

Fail 

Fail 

Fail ti' Fail tJ 1" 

Flag <" 

IS Fail t' \ 

IS Fail 

IS Fail 

IS Fail sJ\ 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

5 :Element Failures 

4 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 10:48 PM 

Fail 

Fail 

o ,Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1 
136

C: \ICPCHE>!\l \OATA\12I27.00. B\04S_CCB .O\04S_CCB. 01 

CCB QC Report 

Data File: 

Date Acquired: 

C:\ICPCHEM\1\DATA\12I27s00.B\045_CCB.D\045_CCB.D# 

Sep 27 2012 10:58 pm 

Operator: NBS 

Sample Name: CCB 120927 

Mise Info: 

Vial Number: 

Current Method: 

Calibration File: 

Last Cal Update: 

1102 

C:\ICPCHEM\1\METHODS\CSC-MDL2.M 

C:\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06:48 pm 

Sample Type: CCB 

Total Dil Factor: 1. 00 

QC Illements 

Element Cone. RSD(%) 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ug/l 

0.00 ug/l 

0.06 ug/l 

9.16 ug/l 

1.71 ug/l 

2.77 ug/l 

29.43 ug/l 

-15.65 ug/l 

-0.09 ug/l 

0.03 ug/l 

-0.07 ug/l 

0.01 ug/l 

0.00 ug/l 

0.00 ug/l 

-0.01 ug/l 

-0.07 ug/l 

-0.07 ug/l 

0.00 ug/l 

0.03 ug/l 

0.01 ug/l 

1. 55 ug/l 

0.00 ug/l 

0.00 ug/l 

-0.07 ug/l 

ug/l 

0.01 ug/l 

ug/l 

0.00 ug/l 

0.19 ug/l 

0.23 ug/l 

0.11 ug/l 

0.05 ug/l 

0.00 ug/l 

0.01 ug/l 

ug/l 

ug/l 

0.00 ug/l 

29.75 

176.45 

5.93 

17.63 

5.23 

6.52 

11.43 

34.50 

16.32 

4.58 

70.90 

1289.00 

17.56 

101.00 

10.91 

12.01 

1695.90 

9.35 

78.05 

9.50 

217.07 

52.01 

6.39 

6.47 

400.43 

14 .18 

8.15 

8.65 

8.35 

280.02 

10.25 

150.75 

ISTD Illements 

Element CPS Mean RSD(%) Ref Value 

-88139.43 

5590061.50 

6 Li -165741.77 2.45 

45 Sc 5106580.00 1.08 

45 Sc 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

697391.88 

22109682.00 

1269388.10 

449594.13 

4386039.50 

9082652.00 

4681851. 50 

27747928.00 

31902092.00 

30507590.00 

0.67 732360.19 

0.31 18013604.00 

0.97 1407958.90 

1.82 475526.09 

0.83 3640663.30 

1.47 10055673.00 

0.37 4993515.00 

0.23 20883300.00 

0.60 23533162.00 

1. 05 22278996.00 

High Limit 

####### 

0.12 

15.00 

77.10 

7.50 

3.96 

19.20 

90.00 

0.78 

0.21 

0.12 

0.18 

40.80 

0.09 

0.48 

0.39 

0.39 

6.90 

0.27 

0.30 

0.30 

0.03 

0.03 

0.21 

####### 

0.09 

####### 

0.06 

####### 

####### 

0.30 

0.03 

0.12 

0.03 

####### 

####### 

0.33 

Rec(%) QC Range(%) 

188.0 70 

91. 4 70 

95.2 70 

122.7 70 

90.2 70 

94.5 70 

120.5 70 -

90.3 

93.8 

132.9 

135.6 

136.9 

70 -

70 

70 

70 

70 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

120 

Flag 

Fail "'" 

Fai 1 ~-( 

Fail rJ-( 

Flag -r IS FaL r 

IS FaL ",-( 

IS FaL N\ 

IS FaL 

IS Fai 

IS FaL 

ISTD Ref File : C:\ICPCHEM\1\DATA\12127S00.B\004CALB.D\004CALB.D# 

3 :Element Failures 

6 :ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 11 :02 PM 

Fail 

Fail 

:Max. Number of Failures Allowed 

o :Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1 
137

METALS 

Raw Data 
138

METALS BLANK 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

Method Analyte Result PQL Units Prep Date Analysis Date QC Group 

200.8 ARSENIC (AS) Not detected 0.5 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67 404 

200.8 CADMIUM (CD) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67 404 

200.8 CHROMIUM (CR) Not detected 0.5 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 

200.8 LEAD (PB) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 

200.8 SELENIUM (SE) Not detected 1.0 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 

200.8 THALLIUM (TL) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 

200.8 ARSENIC (AS) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-AY67411 

200.8 CADMIUM (CD) Not detected 0.20 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67 411 

200.8 CHROMIUM (CR) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 

200.8 LEAD (PB) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 

200.8 SELENIUM (SE) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 

200.8 THALLIUM (TL) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 

------------------------------------------------------.-----------------.-------------------_.-------------------------------._------.---------------._--------------------------------

Printed: 101011125:23:48 PM 
139

C, \ICPCHEM\l \ DATA \12I26qOO. B\066SMPL .D\066SMPL. DI 

Sample QC Report 

Data File: 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I26qOO.B\066SMPL.D\066SMPL.D# 

Sep 26 2012 11,47 pm 

NBS 

120921A-1638-BLK 

120921A-1638 

Vial Number: 3207 

Current Method: 

Calibration File: 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Last Cal Update, 

Sample Type, 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1. 00 

1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 CU 

65 CU 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

-0.02 ug/l 

38.44 ug/l 

-4.10 ug/l 

-2.03 ug/l 

-5.59 ug/l 

16.77 ug/l 

-128.40 ug/l 

-0.11 ug/l 

-0.07 ug/l 

-0.03 ug/l 

-1.40 ug/l 

-5.00 ug/l 

-0.03 ug/l 

-0.01 ug/l 

0.04 ug/l 

0.03 ug/l 

-2.44 ug/l 

-0.01 ug/l 

0.29 ug/l 

0.78 ug/l 

-0.49 ug/l 

-0.41 ug/l 

0.00 ug/l 

ug/l 

-0.01 ug/l 

ug/l 

-0.03 ug/l 

-3.46 ug/l 

-3.62 ug/l 

-3.18 ug/l 

0.02 ug/l 

-0.06 ug/l 

-0.02 ug/l 

ug/l 

ug/l 

-0.02 ug/l 

Element CPS Mean RSD(%) 

6 Li -101898.27 3.96 

45 Sc 3980021.80 0.22 

45 Sc 526890.69 1.25 

18955604.00 

1020355.50 

1.14 

0.97 

0.46 

Carr. Cone. 

#VALUE! 

-0.02 

38.44 

-4.10 

-2.03 

-5.59 

16.77 

-128.40 

-0.11 

-0.07 

-0.03 

-1.40 

-5.00 

-0.03 

-0.01 

0.04 

0.03 

-2.44 

-0.01 

0.29 

0.78 

-0.49 

-0.41 

0.00 

#VALUE! 

-0.01 

#VALUE! 

-0.03 

-3.46 

-3.62 

-3.18 

0.02 

-0.06 

-0.02 

#VALUE! 

#VALUE! 

-0.02 

Ref Value 

-131996.50 

3646344.80 

537987.94 

17012292.00 

949396.31 

338792.91 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

337668.31 

3918444.50 

7427485.50 

3674193.80 

25471844.00 

30928492.00 

29656830.00 

0.99 3456710.80 

0.35 6610579.00 

0.88 3651775.30 

0.49 22769202.00 

0.72 28649686.00 

0.58 27453282.00 

RSD(%) High Limit 

o 5.21 1000 

1.62 1000 

14.44 25000 

2.21 50000 

7.66 20000 

33.23 20000 

2.46 50000 

19.51 1000 

4.39 1000 

13.96 1000 

0.40 1000 

0.56 20000 

2.61 1000 

100.82 1000 

23.95 

7.89 

0.93 

103.72 

7.55 

39.08 

1.91 

0.35 

14 5.60 

5.57 

5.50 

0.38 

0.37 

0.03 

12.62 

1.43 

10.54 

2.45 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

Rec(%) QC Range(%) 

77 .2 

109.2 

97.9 

111.4 

107.5 

70 - 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

99.7 

113.4 

112.4 

100.6 

111.9 

108.0 

108.0 

70 -

70 

70 

70 

70 -

70 

70 

120 

120 

120 

120 

120 

120 

120 

Flag 

Flag 

IS ·Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

o :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/26112 11 :51 PM 

Pass 

Fail 

o :Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
140

C. \ICPCHEM\l \OATA\12127800. B\020SMPL. O\020SMPL. oj 

Sample QC Report 

Data File, 

Date Acquired: 

C,\ICPCHEM\1\DATA\12I27s00.B\020SMPL.D\020SMPL.D# 

Sep 27 2012 OB,ll pm 

Operator: 

Sample Name, 

Mise Info: 

Vial Number: 

NBS 

120920A-163B-BLK 

120920A-163B 

3205 

Current Method: 

Calibration File: 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Last Cal Update, 

Sample Type, 

Sep 27 2012 06,4B pm 

Sample 

Prep oil Factor, 

Total Oil Factor, 

1. 00 

1.00 

QC Elements 

Element Conc. Carr. Conc. 

#VALUE! 

0.00 

0.66 

-3.96 

7 (Li) 

9 Be 

11 B 

23 Na 24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 CU 

66 Zn 

75 As 

7B Se 

7B Se 

BB Sr 

BB Sr 

95 Mo 

106 (Cd) 

107 Ag 

lOB (Cd) 

111 Cd 

11B Sn 

llB Sn 

llB Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

20B Pb 

ug/l 

0.00 ug/l 

0.66 ug/l 

-3.96 ug/l 

3.B4 ug/l 

-3.09 ug/l 

11.36 ug/l 

-9.79 ug/l 

-0.07 ug/l 

0.02 ug/l 

-0.04 ug/l 

0.03 ug/l 

0.23 ug/l 

0.00 ug/l 

0.16 ug/l 

0.02 ug/l 

0.03 ug/l 

0.00 ug/l 

0.02 ug/l 

0.00 ug/l 

0.60 ug/l 

0.00 ug/l 

0.01 ug/l 

-O.OB ug/l 

ug/l 

0.00 ug/l 

ug/l 

0.00 ug/l 

-0.09 ug/l 

-0.06 ug/l 

-0.09 ug/l 

0.05 ug/l 

0.00 ug/l 

0.00 ug/l 

ug/l 

ug/l 

0.00 ug/l 

3.B4 

-3.09 

11.36 

-9.79 

-0.07 

0.02 

-0.04 

0.03 

0.23 

0.00 

0.16 

0.02 

0.03 

0.00 

0.02 

0.00 

0.60 

0.00 

0.01 

-O.OB 

#VALUE! 

0.00 

#VALUE! 

0.00 

-0.09 

-0.06 

-0.09 

0.05 

0.00 

0.00 

#VALUE! 

#VALUE! 

0.00 

ISTD Elements 

Element CPS Mean RSD(%) Ref Value 

- 88139.43 

5590061.50 

732360.19 

6 Li -152224.53 4.32 

45 Sc 6221422.50 0.3B 

45 Sc B61960.69 0.B4 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

229B9646.00 

1565471 . 50 

546797.56 

4560489.00 

108755B8.00 

5554323.00 

2683122B.00 

29800406.00 

28234376.00 

0.49 18013604.00 

0.69 1407958.90 

1.47 475526.09 

1.50 3640663.30 

1.05 10055673.00 

0.18 4993515.00 

1.40 20B83300. 00 

0.79 23533162.00 

0.43 22278996.00 

RSD(%) High Limit 

o 

2068.70 1000 

18.79 1000 

11.36 25000 

1.64 50000 

11.20 20000 

8.79 20000 

24.03 50000 

59.41 1000 

19.99 1000 

4.58 1000 

3.10 1000 

32.78 20000 

21.33 1000 

1.87 1000 

43.81 1000 

46.53 1000 

200.61 1000 

17.74 1000 

238.63 1000 

10.56 1000 

153.12 1000 

28.74 1000 

2.74 1000 

####### 

6.88 500 

####### 

178.50 1000 

16.43 ####### 

33.70 ####### 

4.25 1000 

16.70 1000 

60.96 1000 

18.05 1000 

####### 

####### 

48.50 1000 

QC Range(%) 

70 120 

70 120 

70 120 

70 120 

70 120 

70 120 

Flag 

Flag 

IS fai 

IS fai 

Rec(%) 

172.7 

111.3 

117.7 

127.6 

111.2 

115.0 

125.3 

108.2 

111.2 

128.5 

126.6 

126.7 

70 120 IS Fai 

70 - 120 

70 - 120 

70 - 120 IS Fai 

70 - 120 IS Fai 

70 - 120 IS Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D# 

o :Element Failures 

6 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/27112 8: 14 PM 

Pass 

Fail 

:Max. Number of Failures Allowed 

,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
141

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

Method Compound Name 

200.8 ARSENIC (AS) 

200.8 CADMIUM (CD) 

200.8 CHROMIUM (CR) 

200.8 LEAD (PB) 

200.8 SELENIUM (SE) 

200.8 THALLIUM (TL) 

Comments: 

Laboratory Control Spike Recovery 

METALS 

Spike Level SPK Result SPK% Recovery Extract 

ug/L ug/L Recovery Limits Date 

1.00 1.1 110 85-115 09/20/12 

1.00 1.1 110 85-115 09/20/12 

1.00 0.99 99.0 85-115 09/20/12 

1.00 0.98 98.0 85-115 09/20/12 

1.00 1.1 110 85-115 09/20/12 

1.00 0.91 91.0 85-115 09/20/12 

Analysis 

Date 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

09/27/12 

----------------------------------------------------------------------

QC Group 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67 411 

#2008-120920A-AY67411 

#2008-120920A-A Y67 411 

#2008-120920A-A Y67411 

Printed: 101011125:07:31 PM 

APPL Standard LCS 
142

C, \ICPCHEM\l \DATA\12127s00. B\021SKPL. D\021SKPL.D~ 

Sample QC Report 

Data File: 

Date Acquired, 

Operator: 

C,\ICPCHEM\1\DATA\12I27s00.B\021SMPL.D\021SMPL.D# 

Sep 27 2012 08,17 pm 

Sample Name, 

Mise Info: 

NBS 

12092 OA-163 8 -LCS 

120920A-1638 

Vial Number: 

CUrrent Method, 

Calibration File: 

Last Cal Update, 

Sample Type, 

3206 

C,\ICPCHEM\1\METHODS\CSC-MDL2.M 

C,\ICPCHEM\1\CALIB\CSC-MDL2.C 

Sep 27 2012 06,48 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor: 

1. 00 

1. 00 

QC Elements 

Element 

(Li) 

Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 Cu 

65 Cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

ISTD Elements 

Cone. 

ug/l 

1.10 ug/l 

1. 57 ug/l 

23.41 ug/l 

56.71 ug/l 

17.04 ug/l 

3l.71 ug/l 

48.63 ug/l 

0.97 ug/l 

1.06 ug/l 

0.99 ug/l 

1.09 ug/l 

20.76 ug/l 

1.02 ug/l 

1. 20 ug/l 

1.05 ug/l 

1.06 ug/l 

1. 33 ug/l 

1.09 ug/l 

1.14 ug/l 

1.92 ug/l 

1.10 ug/l 

0.94 ug/l 

0.77 ug/l 

ug/l 

0.47 ug/l 

ug/l 

1.05 ug/l 

0.82 ug/l 

0.91 ug/l 

0.78 ug/l 

0.93 ug/l 

1.04 ug/l 

0.91 ug/l 

ug/l 

ug/l 

0.98 ug/l 

Element CPS Mean RSD(%) 

6 Li -180040.25 5.15 

45 Sc 6265600.50 1.13 

45 Sc 869270.13 0.86 

Cerro Cone. 

#VALUEI 

1.10 

1. 57 

23.41 

56.71 

17.04 

31.71 

48.63 

0.97 

1. 06 

0.99 

1. 09 

20.76 

1. 02 

1. 20 

1. 05 

1. 06 

1. 33 

1. 09 

1.14 

1. 92 

1.10 

0.94 

0.77 

#VALUEI 

0.47 

#VALUEI 

1. 05 

0.82 

0.91 

0.78 

0.93 

1. 04 

0.91 

#VALUEI 

#VALUEI 

0.98 

Ref Value 

-88139.43 

5590061.50 

732360.19 

45 Sc 

72 Ge 

72 Ge 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

23586592.00 

1577643.30 

546680.13 

4628849.50 

10957130.00 

0.43 18013604.00 

5603903.00 

27068172 . 00 

30816206.00 

29108454.00 

0.88 

1.10 

0.35 

1407958.90 

475526.09 

3640663.30 

0.86 10055673.00 

0.65 4993515.00 

0.30 20883300.00 

0.64 23533162.00 

1.24 22278996.00 

RSD(%) 

1. 81 

7.32 

7.50 

0.75 

5.46 

9.32 

7.31 

3.49 

1.49 

1. 31 

1.12 

1.47 

1. 26 

3.31 

0.86 

3.89 

4.61 

0.57 

3.45 

3.71 

1. 37 

0.73 

1. 34 

2.10 

0.82 

3.64 

2.96 

2.12 

2.20 

1. 43 

1.52 

0.44 

Rec(%) 

204.3 

112.1 

118.7 

130.9 

112.1 

115.0 

127.1 

109.0 

112.2 

129.6 

130.9 

130.7 

High Limit 

o 

1000 

1000 

25000 

50000 

20000 

20000 

50000 

Flag 

1000 

1000 

1000 

1000 

qq 'j. 

20000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

1000 

####### 

500 

####### 

1000 

####### 

####### 

1000 

1000 

1000 

1000 

####### 

####### 

1000 

ql! 

q~·I. 

QC Range(%) Flag 

70 - 120 IS Fai 

70 120 

70 - 120 

70 120 IS Fai 

70 120 

70 120 

70 - 120 IS Fai 

70 - 120 

70 - 120 

70 -

70 -

70 

120 IS Fai 

120 IS Fai 

120 IS Fai 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D# 

:Element Failures 

:ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

9/271128:21 PM 

Pass 

Fail 

o :Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1 
143

Laboratory Control Spike Recovery 

METALS 

APPL Inc. 

908 North Temperance Avenue 

Clovis, CA 93611 

Method Compound Name Spike Level SPK Result SPK% Recovery Extract Analysis 

ug/L ug/L Recovery Limits Date Date 

200.8 ARSENIC (AS) 250 257 103 85-115 09/20/12 09/26/12 

200.8 CADMIUM (CD) 50.0 47.6 95.2 85-115 09/20/12 09/26/12 

200.8 CHROMIUM (CR) 250 285 114 85-115 09/20/12 09/26/12 

200.8 LEAD (PB) 250 229 91.6 85-115 09/20/12 09/26/12 

200.8 SELENIUM (SE) 250 269 108 85-115 09/20/12 09/26/12 

200.8 THALLIUM (TL) 250 226 9004 85-115 09/20/12 09/26/12 

Comments: ____________________________________________________________________ __ 

QC Group 

#2008-120920A-A Y67 404 

#2008-120920A-A Y67 404 

#2008-120920A-A Y67 404 

#2008-120920A-A Y67 404 

#2008-120920A-A Y67 404 

#2008-120920A-A Y67 404 

Printed: 101011125:07:31 PM 

APPL Standard LCS 
144

CI \ICPCHEM\l \DATA\12126qOO. B\067SMPL. D\067SMPL. cll 

Sample QC Report 

Data File, 

Date Acquired, 

Operator, 

Sample Name, 

Mise Info: 

C,\ICPCHEM\1\DATA\12I26qOO.B\067SMPL.D\067SMPL.D# 

Sep 26 2012 11,54 pm 

NBS 

120921A-1638-LCS 

120921A-1638 

Vial Number: 3208 

current Method, 

Calibration File: 

C,\ICPCHEM\l\METHODS\CSC-MDL.M 

C,\ICPCHEM\l\CALIB\CSC-MDL.C 

Last Cal Update, 

Sample Type, 

Sep 26 2012 05,18 pm 

Sample 

Prep Dil Factor, 

Total Dil Factor, 

1.00 

1. 00 

QC Elements 

Element 

7 (Li) 

9 Be 

11 B 

23 Na 

24 Mg 

27 Al 

39 K 

44 Ca 

47 Ti 

51 V 

52 Cr 

55 Mn 

56 Fe 

59 Co 

60 Ni 

63 cu 

65 cu 

66 Zn 

75 As 

78 Se 

78 Se 

88 Sr 

88 Sr 

95 Mo 

106 (Cd) 

107 Ag 

108 (Cd) 

111 Cd 

118 Sn 

118 Sn 

118 Sn 

121 Sb 

137 Ba 

205 Tl 

206 (Pb) 

207 (Pb) 

208 Pb 

Conc. 

ug/l 

44.26 ug/1 

289.40 ug/l 

24820.00 ug/l 

25720.00 ug/l 

1763.00 ug/l 

4851. 00 ug/l 

25010.00 ug/l 

251.90 ug/l 

282.50 ug/l 

285.00 ug/l 

255.70 ug/l 

1032.00 ug/l 

282.30 ug/l 

264.80 ug/l 

263.30 ug/l 

261. 90 ug/l 

453.30 ug/l 

256.70 ug/l 

268.50 ug/l 

259.10 ug/l 

270.20 ug/l 

241.50 ug/l 

225.80 ug/l 

ug/l 

92.59 ug/l 

ug/l 

47.61 ug/l 

218.90 ug/l 

216.50 ug/l 

200.60 ug/l 

221. 20 ug/l 

256.90 ug/l 

225.80 ug/l 

ug/l 

ug/l 

229.10 ug/l 

ISTD B1ements 

Carr. Conc. 

#VALUE! 

44.26 

289.40 

24820.00 

25720.00 

1763.00 

4851.00 

25010.00 

251.90 

282.50 

285.00 

255.70 

1032.00 

282.30 

264.80 

263.30 

261. 90 

453.30 

256.70 

268.50 

259.10 

270.20 

241.50 

225.80 

#VALUE! 

92.59 

#VALUE! 

47.61 

218.90 

216.50 

200.60 

221.20 

256.90 

225.80 

#VALUE! 

#VALUEI 

229.10 

RSD(%) High Limit 

o 0.70 1000 

0.45 1000 

2.13 25000 

1.76 50000 

2.39 20000 

1.77 20000 

1.97 50000 

2.68 1000 

2.81 1000 

2.38 1000 

2.75 1000 

2.43 20000 

2.71 1000 

2.51 1000 

2.22 1000 

2.19 1000 

0.78 1000 

0.47 1000 

0.55 1000 

0.39 1000 

0.55 1000 

0.53 1000 

0.81 1000 

####### 

0.32 500 

####### 

1.18 1000 

0.79 ####### 

0.38 ####### 

0.20 1000 

0.98 1000 

1.21 1000 

0.44 1000 

####### 

####### 

0.56 1000 

Flag 

Element CPS Mean RSD(%) Ref Value Rec(%) 

75.6 

107.5 

96.9 

107.6 

103.6 

97.8 

107.7 

108.0 

QC Range (%) Flag 

6 Li -99735.90 5.93 -131996.50 

45 Sc 3919895.80 0.99 3646344.80 

45 Sc 521538.72 2.17 537987.94 

45 Sc 18298404.00 0.79 17012292.00 

72 Ge 983780.88 0.17 949396.31 

72 Ge 331282.41 0.80 338792.91 

72 Ge 

115 In 

115 In 

115 In 

159 Tb 

165 Ho 

3722552.80 

7137157.50 

3509093.00 

24109940.00 

30015476.00 

29011228.00 

1.65 3456710.80 

0.48 6610579.00 

0.46 3651775.30 

0.03 22769202.00 

1.01 28649686.00 

1.08 27453282.00 

96 .1 

105.9 

104.8 

105.7 

70 120 IS fai 

70 - 120 

70 120 

70 - 120 

70 120 

70 120 

70 - 120 

70 120 

70 - 120 

70 - 120 

70 120 

70 - 120 

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D# 

o :Element Failures 

1 ,ISTD Failures 

Data Results: 

Analytes: 

ISTD: 

Pass 

Fail 

o ,Max. Number of Failures Allowed 

o ,Max. Number of ISTD Failures Allowed 

,)'\ 

9/26/1211:57 PM C,\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1 
145

004 t~etals Standards log Book # 

4-

Hg WORKING STANDARD 7470Al7471/24S.1 

1 ml X 10ug/ml Hg STOCK STD. (09/14/12RJS)/200ml 1 % HN03 Lot#L 12065 

1 ml X 10ug/ml Hg STOCK ICV (09/14/12RJ~)~00rpl 1 % HN03 Lot#L 12065 

Final concentration is 50 ug/L. Expires ...... "?M~b.~ ........... . 
146

, , 

-, 

',: 

" 

c.., 

)i 

I 

e~alsSt?tndard~ Log Book # ',~ Page # - ...... <1 

STD 

~ 

w 

~ 

~ 

!!i 

w 

~ i2 

<i: 

~ 

'" 

g 

Vl 

~ 

5 VARIOUS VARIOUS VARIOUS 

~ 

Hg WORKING STANDARD 7470Al7471/24S.1 

1ml X 10ug/ml Hg STOCK STD. (09/14/12RJS)/200mI1% HN03 Lot#L 12065 

1 ml X 10ug/ml Hg STOCK ICV (09/14/12RJS)/~~1 % HN03 Lot#L 12065 

Final concentration is 50 ug/L. Expires ......... ~.~?: .~~ ......... . 
147

~s Standards Log Book t~ 

5 CAL A 0.05 B 

Vl 

~ 

'" N 

'" 

N 

~ <3 

CONe 

Final 

005 
148

Metals Standards Log Book =# 

006 

STD 

~ 

"-l 

~ 

~ "-l 

~ 

~ 0:; 

~ 

'" 0.1 

..., 

-I 

~ "-l 

-I 

8 

~ o:l 

'- B 

STD LOT EXPDATE 

c.---------, ICYB 0.8 (PI 12084-30612 09/20/13 

----------------1 

ICY A 02 (PI 12084-30611 09/20/13 . l:....' --------------, 

,-----------------, 
149

Met !s Standards Log BOiok # 3<;., Page # 007 
150

.rtj~Gt fS Standards Lo ' Book # 3~ 009 

Hg WORKING STANDARD 7470Al7471/24S.1 

1 ml X 10ug/ml Hg STOCK STD. (09/14/12RJS)/200ml 1 % HN03 Lot#L 12065 

1 ml X 10ug/ml Hg STOCK ICV (09/14/12RJS)1290rlll)% HN03 Lot#L 12065 

Final concentration is 50 ug/L. Expires ........ 9./~k~ ........ . 

STD 

ICVB 

ICVA ~----------~-------I 

0.08 

0.02 

LOT 

CPI 12084-30612 

CPI 12084-30611 09/20/1310001-_______ _ 

F2-MEB43 

5088MCA na 
151
152

~s Standards Lo Book # 011 

STD 

><:: 

UJ 

~ 

-

~ UJ 

~ 

§ 

f-

.;.; 

~ a... 

0.1 

..., 

....l 

g; 

~ 

5 

~ § 
153

, etafs Standards Lo Book # 

LOT EXPDATE 

'--

lCVB 0,08 Q>l 12084-30612 09/20/13 

--

--

--

--

--

-- lCVA 0.02 Q>l 12084-30611 09/20/13 

;-------------r----I 

~ -- ,- ----------t----I 

--,-"-----+----------------4 

f: --'------+-----------------=-~ 

'~-:-----~------------------:-~ 

-,j 

-:~" -! - ----------+~------------------------------------------~a ~r-:----------I----------------------------------------_:~ 

~!. -i--

! ----~---------------------~~ 

--' ~,--"----------+-----------------------------------------~~ _I 

~T-"----__t---------------------~ 

---,'-'-~------+-------------------~~ 

-'-.-----I------------------~ 

.;::-----l----------------~ 
154

Tune File 

Comment 

m/z 

7 

89 

205 

156/140 

70/140 

140 

r 

en - rPage: 1 

Range 

50,000 

100,000 

50,000 

2 

2 

100,000 

( 

-

NG HMI.u 

120926 

Count 

29153.0 

65890.0 

38361.0 

1.554% 

1.105% 

67092.0 

Tune Report 

Mean 

28824.2 

66508.4 

38281.0 

1.574% 

1.088% 

66192.5 

/ 

r-

-

Integration Time: 

Sampling Period: 

n: 

0.1000 sec 

0.6200 sec 

200 

Oxide: 156/140 1.566% 

Doubly Charged: 70/140 1.119% 

RSD% Background 

2.00 2.70 

2.10 3.20 

2.31 14.70 

4.97 

4.82 

2.08 8.40 

m/z: 7 89 

Height: 28,624 67,845 

Axis: 6.95 88.95 

W-50%: 0.65 0.65 

W-l0%: 0.800 0.800 

Integration Time: 0.1000 sec 

Acquisition Time: 22.7600 sec 

Y axis Linear 

Generated 

Printed 

Sep 26, 2012 13:51:19 

Sep 26, 2012 13:51:22 

205 

39,192 

204.95 

0.60 

0.7500 
155

Tune File 

Comment 

Tuning Parameters 

NG HMI.u 

120926 

===Plasma Condition=== 

RF Power 1600 W 

RF Matching 1.7 V 

Smpl Depth 8 mm 

Torch-H 0.2 mm 

Torch-V -0.2 mm 

Carrier Gas 0.7 L/min 

Makeup Gas 0.3 L/min 

Optional Gas % 

Nebulizer Pump 0.1 rps 

Sample Pump rps 

sic Temp 2 degC 

===Reaction Cell=== 

Reaction Mode OFF 

H2 Gas 0 mL/min 

Page: 2 

Tune Report 

===Ion Lenses=== 

Extract 1 0 

Extract 2 -140 

Omega Bias-ce -24 

Omega Lens-ce -0.4 

Cell Entrance -30 

QP Focus 5 

Cell Exit -30 

===Octopole Parameters=== 

OctP RF 180 

OctP Bias -6 

He Gas 

Generated 

Printed 

0 

===Q-Po1e Parameters=== 

V AMU Gain 128 

V AMU Offset 126 

V Axis Gain 0.9999 

V Axis Offset -0.05 

V QP Bias -3 

V 

V ===Detector Parameters=== 

Discriminator 

Analog HV 

V Pulse HV 

V 

mL/min Optional Gas 

S ep 26, 2012 13: 51 : 19 

Sep 26, 2012 13:51:24 

8 

1720 

1350 

---

V 

mV 

V 

V 

% 
156

C:\ICPCHEM\1\DATA\12126qOO.B\OOlTUNE.D 

200.8 QC Tune Report 

Data File: 

Date Acquired: 

Acq. Method: 

Operator: 

Sample Name: 

Misc Info: 

Vial Number: 

Current Method: 

RSD (%) 

Element CPS Mean 

9 Be 1828908 

24 Mg 5674046 

59 Co 9252430 

115 In 39905972 

208 Pb 6904355 

9/26/124:37 PM 

C:\ICPCHEM\1\DATA\12I26qOO.B\001TUNE.D 

Sep 26 2012 04:35 pm 

TN200 8.M 

NBS 

100ppb Tune sol 

1303 

C:\ICPCHEM\1\METHODS\TN200 8.M 

Rep1 Rep2 Rep3 Rep4 

1820953 1819237 1832929 1836726 

5555187 5541242 5608233 5814412 

9317050 9222301 9272642 9242114 

Rep5 

1834695 

5851157 

9208043 

4017530839857856400056243958969639901376 

6901831 6913951 6911489 6897688 

9 Be 

Mass Calib. 

Actual: 8.95 

Required:8.90 

Flag: 

Peak Width 

24 Mg 

Actual: 0.65 

Required:0.90 

Flag: 

Mass Calib. 

Actual: 23.95 

Required:23.90 

Flag: 

Peak Width 

Actual: 0.65 

Required:0.80 

Flag: 

6896818 

C:\ICPCHEM\1\RPTTMP\2008tnrt.qct 

%RSD Required Flag 

0.47 5.00 

2.95 5.00 

0.49 5.00 

0.36 5.00 

0.73 5.00 

9.10 

24.10 

Page 1 of2 
157

Tune Result: Pass 

9/26/124:37 PM 

C:\ICPCHEM\1\DATA\12126qOO.B\OOlTUNE.D 

59 Co 

Mass Calib. 

Actual: 58.95 

Required: 58.90 

Flag: 

Peak Width 

Actual: 0.60 

Required: 0.90 

Flag: 

115 In 

Mass Calib. 

Actual: 114.95 

Required: 114.90 

Flag: 

Peak Width 

Actual: 0.60 

Required: 0.90 

Flag: 

208 Pb 

Mass Ca1ib. 

Actual: 207.95 

Required: 207.90 

Flag: 

Peak Width 

Actual: 0.55 

Required: 0.80 

Flag: 

C:\ICPCHEM\1\RPTTMP\2008tnrt.qct 

59.10 

ll5.10 

208.10 

Page2of2 
158

Tune File 

Comment 

m/z 

7 

89 

205 

156/140 

70/140 

140 

/ 

-

Page: 1 

Range 

50,000 

100,000 

50,000 

5 

2 

100,000 

f 

-

f--

NG HMI.u 

120927 

Count 

31160.0 

55876.0 

28478.0 

1.930% 

1.427% 

51157.0 

Tune Report 

Mean 

31280.2 

55563.2 

28362.6 

2.000% 

1. 477% 

52242.1 

/ 

-

Integration Time: 0.1000 sec 

Sampling Period: 0.6200 sec 

n: 200 

Oxide: 156/140 

Doubly Charged: 70/140 

RSD% Background 

1. 41 2.90 

1. 98 3.30 

2.14 8.30 

4.11 

5.08 

2.09 6.00 

m/z: 7 89 

Height: 31,171 56,406 

Axis: 6.95 88.95 

W-50%: 0.65 0.65 

W-10%: 0.7500 0.800 

Integration Time: 0.1000 sec 

Acquisition Time: 22.7600 sec 

Y axis Linear 

Generated 

Printed 

S ep 27, 2012 1 7 : 51 : 44 

Sep 27, 2012 17:51:46 

1.997% 

1. 464% 

205 

28,435 

204.95 

0.60 

0.800 
159

Tune File 

Comment 

Tuning Parameters 

NG HMI.u 

120927 

===P1asma Condition=== 

RF Power 1600 W 

RF Matching 1.7 V 

Smpl Depth B mm 

Torch-H 0.2 mm 

Torch-V -0.2 mm 

Carrier Gas 0.7 L/min 

Makeup Gas 0.3 L/min 

Optional Gas % 

Nebulizer Pump 0.1 rps 

Sample Pump rps 

SIC Temp 2 degC 

===Reaction Cell=== 

Reaction Mode OFF 

H2 Gas 0 mL/min 

Page: 2 

Tune Report 

===Ion Lenses=== 

Extract 1 0 

Extract 2 -140 

Omega Bias-ce -24 

Omega Lens-ce -0.4 

Cell Entrance -30 

QP Focus 5 

Cell Exit -30 

===Octopole Parameters=== 

OctP RF IBO 

OctP Bias -6 

He Gas 

Generated 

Printed 

0 

===Q-Po1e Parameters=== 

V AMU Gain 12B 

V AMU Offset 126 

V Axis Gain 0.9999 

V Axis Offset -0.05 

V QP Bias -3 

V 

V ===Detector Parameters=== 

Discriminator 

Analog HV 

V Pulse HV 

V 

mL/min Optional Gas 

Sep 27, 2012 17:51:44 

Sep 27, 2012 17:51:49 

B 

1720 

1350 

- --

V 

mV 

V 

V 

% 
160

C:\ICPCHEM\1\DATA\12I27s00.B\OOlTUNE.D 

200.8 QC Tune Report 

Data File: 

Date Acquired: 

Acq. Method: 

Operator: 

Sample Name: 

Misc Info: 

Vial Number: 

Current Method: 

RSD (%) 

Element CPS Mean 

9 Be 3059314 

24 Mg 9872001 

59 Co 14536614 

115 In 50490691 

208 Pb 7076922 

9/27/12 6:07 PM 

C:\ICPCHEM\1\DATA\12I27s00.B\001TUNE.D 

Sep 27 2012 06:06 pm 

TN200 8.M 

NBS 

100ppb Tune sol 

1303 

C:\ICPCHEM\1\METHODS\TN200 8.M 

Repl Rep2 Rep3 Rep4 

2974824 3071305 3075572 3092106 

9638955 9922088 9943710 9902779 

Rep5 

3082762 

9952473 

1411063314497120147084311469940914667477 

4947086850433084510898805085078050608840 

6791028 7154809 7111241 7206525 

9 Be 

Mass Calib. 

Actual: 8.95 

Required:8.90 

Flag: 

Peak Width 

24 Mg 

Actual: 0.65 

Required:0.90 

Flag: 

Mass Calib. 

Actual: 23.95 

Required:23.90 

Flag: 

Peak Width 

Actual: 0.65 

Required:0.80 

Flag: 

7121005 

C:\ICPCHEM\1\RPTTMP\2008tnrt.qct 

%RSD Required Flag 

1. 83 5.00 

1. 28 5.00 

1. 83 5.00 

1.27 5.00 

2.24 5.00 

9.10 

24.10 

Page 1 of 2 
161

Tune Result: Pass 

9/27/126:07 PM 

C:\ICPCHEM\1\DATA\12127s00.B\OOlTUNE.D 

59 Co 

Mass Calib. 

Actual: 58.95 

Required: 58.90 

Flag: 

Peak Width 

Actual: 0.60 

Required: 0.90 

Flag: 

115 In 

Mass Calib. 

Actual: 115.00 

Required: 114.90 

Flag: 

Peak Width 

Actual: 0.60 

Required: 0.90 

Flag: 

208 Pb 

Mass Calib. 

Actual: 207.95 

Required: 207.90 

Flag: 

Peak Width 

Actual: 0.55 

Required: 0.80 

Flag: 

C:\ICPCHEM\1\RPTTMP\2008tnrt.qct 

59.10 

115.10 

208.10 

Page2of2 
162

Metals Digestion Worksheet 

Method Name 200.8 11.2 Digestion Prep Method M2008 Set 120920A Units mL 

Spiked ID2 LCSWLOT# 1037546-31168 

Spiked ID 3 6020 HDLPREP: 9-20-12 

Spiked ID4 

Spiked By EA Date: 09/20112 1:40:00 PM 

Witnessed By NM Date: 09120112 1:40:00 PM 

Sample I~ample Spike Spike I~igested Final Start DatelTime Comments 

Container lAmount ID Amount Volume 

1120920A Blk 

IIIIIIIIII[I~II 111111111111111 1111111111111111111111 11111111111 

I 50 50 09120/12 13:40 equip: Modblock2 1638 FGD MATRIX 

2120920A LCS I 0.5 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

111111111111111111111111111111111111111111111111111111111111111 

3MDL-0.25-1 I 0.25 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

4 MDL-0.25-2 I 0.25 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

5 MDL-O .25-3 I 0.25 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

6MDL-0.25-4 I 0.25 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

7MDL-0.25-5 I 0.25 I 3 I 50 50 09/20/12 13 :40 equip: Modblock2 

8 MDL-0.25-6 I 0.25 I 3 I 50 50 09/20112 13 :40 equip: Modblock2 

9 MDL-0.25-7 I 0.25 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

IOMDL-0.5-1 I 0.50 I 3 I 50 50 09/20/12 13 :40 equip: Modblock2 

II MDL-0.5-2 I 0.50 I 3 I 50 50 09/20/12 13 :40 equip: Modblock2 

12 MDL-0.5-3 I 0.50 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

13 MDL-0.5-4 I 0.50 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

14 MDL-0.5-5 I 0.50 I 3 I 50 50 09/20/12 13:40 equip: Modblock2 

i 15 MDL-0.5-6 I 0.50 I 3 I 50 50 09/20112 13:40 equip: Modblock2 

16 MDL-0.5-7 I 0.50 I 3 I 50 50 09/20/1213:40 equip: Modblock2 

~s{jf&'fifi\t~fiaTifffJWtlitl~~~~ri!m1:~fl.~ 

1:1 HN03 8-28-12 Sample prep employee Initials run 

1:1 HCL08-28-12 Analvst's initials EA Sample Preparation run 

Date Digestion run 

Time Brin!! up to volume run 

Moved to METALS Modified 101011123:08:34 PM 

Reviewed By: EA Date: .10/01112 

101011123:08:39 PM Page I of I 
163

,c;.""3,'6 

Method Name 200:-8 11.2 Digestion 

Spiked ID 2 LCSW LOT# 1037546-31168 

Spiked ID 3 6020 HDLPREP: 9-21-12 

Spiked ID 4 

Metals Digestion Worksheet 

/" 3«; Prep Method Ml-008 Set 120921A 

Ending Temp: 86 c 

Temperature Type: Mod Block 

Sufficient Vol for Matrix QC: Yes 

Spiked By EA Date: 09/211122:00:00 PM End DatelTime 09/2111216:00 

Witnessed By NM Date: 09/211122:16:55 PM 

Sample I~ample Spike Spike I~igested Final Start DatelTime Comments 

Container Amount ID Amount Volume 

1120921A Bik I 50 

1111111111111111111111111111111111111111111111111111111111111II 

50 09/21112 14:00 equip: Modblock2 

212092IA LCS 

1 fllill lillll~illlllll~li 11111 111111 III 111111111111 IIIIIUIIIII 

I 0.5 I 1+2 1 50 50 09/21112 14:00 equip: Modblock2 

3BLKMDL0.4-1 ,I iii fillillil 11111 II 1IIIm 1111111111111111111111111111 1/1111111111111111 ' 

0.2 1 3 I 50 50 09/21112 14:00 equip: Modblock2 

4 BLK MDL 0.4-2 ,I 0.2 I 3 

11111111111111111111111111111111 11111111111111 1111 111111 IllImllllllllll 1 50 50 09/21/12 14:00 equip: Modblock2 

5 BLK MDL 0.4-3 ,I lIilllil!II 'WI IT IlillllllJ/UlJIII 1IJ1111LIIIIJIIU~11I1I1I1I1I1I111 0.2 I 3 1 50 50 09/21112 14:00 equip: Modblock2 

6 BLK MDL 0.4-4 I 0.2 I 3 

11111111111111111111111111111111111111111111111111111 1/1111111111111111 

I 50 50 09/21112 14:00 equip: Modblock2 

7BLKMDL0.4-5 I 

IlIilll 111111 iii/l IIIlililll 1111 111111 111111111111 1111111111 11111111111111 

0.2 I 3 1 50 50 09/21112 14:00 equip: Modblock2 

8 BLK MDL 0.4-6 0.2 I 3 

111111111111111111111111111111111111111111111111111111111111111111111111II 

I 50 50 09/21112 14:00 equip: Modblock2 

9BLKMDLO.4-7 ,I I 1IIIIIIIilill iiill 1111111111 1111 11111111 111111 1111 111111111111111111111111 

0.2 I 3 1 50 50 09/21112 14:00 equip: Modblock2 

Units mL 

.' ;"S~"o'Vl·~'·''"''.','e'!1%n~~l.a''''''n'''i?''h_;:t.'M.J.;lo,4!P,f#·?~.:.'l"1,~'.~ .. ".:,·.'f.'_'::.ifI\i.:,;;.;,!.~.~_~·"".'.~~."t~.· ,:i1'.~,>;f;; •• !.~z.L.1~.~ ~S'~1'ia':'m';~Wllke·";Q~ZJm1.??!a':::-n",W;s""e"~;:'¥.~~.\W("i$~;r,\l\1~~t~j,,\,,,,J:~~~i>1i:' ~e' ~~c;~aw"""n' :l""tif.W:'r.'a'ifI'!1s";J~f~~~\IK4i'~~~li\)::t%.1i~~~l\\<ll~-S\!!?;rl ,'t'o lA, UY..J.:J -.tg:*"~-,,~.wt;_,~,]j~.-",,!,,&....",,,~ " • .:it.. !! - .VJ h~!~:~PJ::.I.~.I.~ 11 r~~~*i,§j:Mltj,~;,;;~~~~~~mrJ.;1 ~", .CJllll·I :t.S~.J.:.llln !iF?~!;'~li€.';,-.~~S]~~~J'~;~~~~Z~~t-t*~~~~s 

HN03 IT Sample prep employee Initials nm Scanned Bv 10 

HCL EMD Analyst's initials ~ ;t q... ,.... Sample Preparation nm 

Date (!)"J) (,)1+1.. "ZI-t'L Dh!estion nm 

Time J (p : cfD Bring up to volume nm 

Moved to N-t~l5 Modified 09/21112 2:14:58 PM 

Reviewed By: 'LA10/011123:13:11 PM Page 1 of 1 
164

6020/200.8 Injection Log 

Directory: K:\lCP-MS Optimus\raw data output csv\ 

RunlD Injected Sample Name Misc Info FileName Multiplier 

26 Sep 2012 16:54 Calibration Blank 120926Arev 1. 

2 26 Sep 2012 17:01 120926 Standard 1 120926Arev 1. 

3 26 Sep 2012 17:08 120926 Standard 2 120926Arev 1. 

4 26 Sep 2012 17:14 120926 Standard 3 120926Arev 1. 

5 26 Sep 2012 17:21 ICV 120926 120926Arev 1. 

6 26 Sep 2012 17:34 ICB 120926 120926Arev 1. 

7 26 Sep 2012 17:41 LLlCV 120926 120926Arev 1. 

8 26 Sep 2012 17:48 FGD MATRIX 120926Arev 1. 

9 26 Sep 2012 17:54 FGD MATRIX SPIKED 120926Arev 1. 

10 26 Sep 2012 18:08 CCV 120926 120926Arev 1. 

11 26 Sep 2012 18:21 CCB 120926 120926Arev 1. 

12 26 Sep 2012 18:34 FGD ICS - Chloride 120926Arev 1. 

13 26 Sep 2012 18:41 FGD ICS - Calcium 120926Arev 1. 

14 26 Sep 2012 18:48 FGD ICS - Sulfate 120926Arev 1. 

15 26 Sep 2012 18:54 FGD ICS - Magnesium 120926Arev 1. 

16 26 Sep 2012 19:01 FGD ICS - Sodium 120926Arev 1. 

17 26 Sep 2012 19:08 FGD ICS - Boron 120926Arev 1. 

18 26 Sep 2012 19:15 FGD ICS - Iron 120926Arev 1. 

19 26 Sep 2012 19:21 FGD ICS - Nitrate 120926Arev 1. 

20 26 Sep 2012 19:28 FGD ICS - Manganese 120926Arev 1. 

22 26 Sep 2012 19:41 CCV 120926 120926Arev 1. 

23 26 Sep 2012 19:54 CCB 120926 120926Arev 1. 

24 26 Sep 2012 20:01 FGD ICS - Bromide 120926Arev 1. 

25 26 Sep 2012 20:08 FGD ICS - Fluoride 120926Arev 1. 

26 26 Sep 2012 20:15 FGD ICS - Selenium 120926Arev 1. 

27 26 Sep 2012 20:21 FGD ICS - Vanadium 120926Arev 1. 

28 26 Sep 2012 20:28 FGD ICS - Zinc 120926Arev 1. 

29 26 Sep 2012 20:34 FGD ICS - Chromium 120926Arev 1. 

30 26 Sep 2012 20:41 FGD ICS - Copper 120926Arev 1. 

32 26 Sep 2012 21:14 CCV 120926 120926Arev 1. 

33 26 Sep 2012 21:27 CCB 120926 120926Arev 1. 

35 26 Sep 2012 22:47 CCV 120926 120926Arev 1. 

36 26 Sep 2012 23:00 CCB 120926 120926Arev 1. 

39 26 Sep 2012 23:47 120921A-1638-BLK 120926Arev 1. 

40 26 Sep 2012 23:54 120921 A-1638-LCS 120926Arev 1. 

41 27 Sep 2012 00:07 1638 MDL-0.25-1 120926Arev 1. 

43 27 Sep 2012 00:20 CCV 120926 120926Arev 1. 

44 27 Sep 2012 00:33 CCB 120926 120926Arev 1. 

45 27 Sep 2012 00:40 1638 MDL-0.25-2 120926Arev 1. 

46 27 Sep 2012 00:47 1638 MDL-0.25-3 120926Arev 1. 

47 27 Sep 2012 00:53 1638 MDL-0.25-4 120926Arev 1. 

48 27 Sep 2012 01:00 1638 MDL-0.25-5 120926Arev 1. 

49 27 Sep 2012 01:06 1638 MDL-0.25-6 120926Arev 1. 

Page 1 01 Oct 2012 16:59 
165

50 27 Sep 2012 01:13 1638 MOL-0.25-7 120926Arev 1. 

51 27 Sep 2012 01:20 BLK MOL 0.4-1 120926Arev 1. 

52 27 Sep 2012 01:27 BLK MOL 0.4-2 120926Arev 1. 

53 27 Sep 2012 01:33 BLK MOL 0.4-3 120926Arev 1. 

54 27 Sep 2012 01:40 BLK MOL 0.4-4 120926Arev 1. 

56 27 Sep 2012 01:53 CCV 120926 120926Arev 1. 

57 27 Sep 2012 02:07 CCB 120926 120926Arev 1. 

58 27 Sep 2012 02:13 BLK MOL 0.4-5 120926Arev 1. 

59 27 Sep 2012 02:20 BLK MOL 0.4-6 120926Arev 1. 

60 27 Sep 2012 02:27 BLK MOL 0.4-7 120926Arev 1. 

69 27 Sep 2012 03:27 CCV 120926 120926Arev 1. 

70 27 Sep 2012 03:40 CCB 120926 120926Arev 1. 

Page 2 01 Oct 2012 16:59 
166

6020/200.8 Injection Log 

Directory: K:\ICP-MS Optimus\raw data output csv\ 

RunlD Injected Sample Name Misc Info FileName Multiplier 

74 27 Sep 2012 18:24 Calibration Blank 120927Arev 1. 

75 27 Sep 2012 18:31 120927 Standard 1 120927Arev 1. 

76 27 Sep 2012 18:37 120927 Standard 2 120927Arev 1. 

77 27 Sep 2012 18:44 120927 Standard 3 120927Arev 1. 

78 27 Sep 2012 18:50 ICV 120927 120927Arev 1. 

79 27 Sep 2012 19:04 ICB 120927 120927Arev 1. 

80 27 Sep 2012 19:10 LLlCV 120927 120927Arev 1. 

81 27 Sep 2012 19:17 FGD MATRIX 120927Arev 1. 

82 27 Sep 2012 19:24 FGD MATRIX SPIKED 120927Arev 1. 

83 27 Sep 2012 19:37 CCV 120927 120927Arev 1. 

84 27 Sep 2012 19:50 CCB 120927 120927Arev 1. 

85 27 Sep 2012 20:11 120920A-1638-BLK 120927Arev 1. 

86 27 Sep 2012 20:17 120920A-1638-LCS 120927Arev 1. 

89 27 Sep 2012 20:44 1638 MDL-0.25-1 120927Arev 1. 

90 27 Sep 2012 20:50 1638 MDL-0.25-2 120927Arev 1. 

91 27 Sep 2012 20:57 1638 MDL-0.25-3 120927Arev 1. 

93 27 Sep 2012 21: 11 CCV 120927 120927Arev 1. 

94 27 Sep 2012 21:24 CCB 120927 120927Arev 1. 

95 27 Sep 2012 21:30 1638 MDL-0.25-4 120927Arev 1. 

96 27 Sep 2012 21:37 1638 MDL-0.25-5 120927Arev 1. 

97 27 Sep 2012 21:44 1638 MDL-0.25-6 120927Arev 1. 

98 27 Sep 2012 21:51 1638 MDL-0.25-7 120927Arev 1. 

99 27 Sep 2012 22:04 BLK MDL 0.4-1 120927Arev 1. 

100 27 Sep 2012 22:11 BLK MDL 0.4-2 120927Arev 1. 

101 27 Sep 2012 22:18 BLK MDL 0.4-3 120927Arev 1. 

102 27 Sep 2012 22:24 BLK MDL 0.4-4 120927Arev 1. 

103 27 Sep 2012 22:31 BLK MDL 0.4-5 120927Arev 1. 

105 27 Sep 2012 22:44 CCV 120927 120927Arev 1. 

106 27 Sep 2012 22:58 CCB 120927 120927Arev 1. 

107 27 Sep 2012 23:04 BLK MDL 0.4-6 120927Arev 1. 

108 27 Sep 2012 23:11 BLK MDL 0.4-7 120927Arev 1. 

117 28 Sep 2012 00:18 CCV 120927 120927Arev 1. 

118 28 Sep 2012 00:32 CCB 120927 120927Arev 1. 

Page 1 01 Oct 2012 16:56