# METALS

# Data Validation Package for METALS

TABLE OF CONTENTS

LABORATORY NAME: 

# APPL Inc.

Case Narrative

Chain ofCustody and ARF

QC Summary
Sample Data

Calibration Data

Raw Data 

# \t)

# METALS

Case Narrative

## 908 North Temperance Ave. V Clovis, CA93611 V Phone 559-275-2175 V Fax 559-275-4422

Certification Number: CA1312 NELAP Certification number: 05233CA DoD-ELAP Certificate number: ADE-1410 

# DataValidatable Report

10102/12



# CSC 6101 Stevenson Ave. Alexandria, Va

Attn: ChipMcCarty
Title: Report ofData: Case 68603 Project: FGD MDLSTUDY

Results in this report apply to the samples analyzed in accordance with the chain ofcustody document. This analytical report mustbe reproducedin its entirety.

Dear Mr. 

# McCarty:
TheFGD matrix was receivedon August 30,2012at room temperature. Writtenresults for the requested analyses are provided on this 10/02112. All holding times were met.

. Standards Prep:
Calibration standards (Absolute Standards),ICV (CPIInc), MDL spiking standards (CPIInc and 02SI)preparedusing 2% nitric acidand0.5% hydrochloric. MDL spike levels are summarizedin the QC section ofthis narrative. SamplePrep and Digestion: Samples were prepared and digested according to EPA method 1638. A 50mLsample aliquot

was used for digestion. 0.5mLnitric acid and0.25 mL hydrochloric acid were addedto the samples priorto digestion. The samples were heated using a digestion blockfor 2 hrs at 85°C.
InstrumentParameters:
The samples were analyzed using an Agilent7500cx ICP-MS using the High Matrix Introduction (HMJ) 

# system. The 10ppbtuning solution (lot# 

# 1036822) was purchasedfrom 02SIas recommendedby Agilent. Argon gas was used as the makeup (0.3 Umin) and carrier (0.7 Umin). The spraychambertemperature was maintained at 2°C. TheRFPowerwas set at 1600W with RFmatching at 1.66 V. 

# The internal standards associated with the analytes of interest are as follows: As (I.S. 115 In

- Helium mode), Cd(I.S. 115 In

- No-gas mode), Se (I.S. 115 In

- Hydrogen mode), Cr (I.S. 45 Sc

- Helium mode), Pb, Tl (I.S. 159Tb

- No gas mode), All otherinstrumentcriteria are pertainingto the MDL study are summarized on the Tunereport.

68603 CSCCASE.doc

# Sample QC:
Thereagent waterMDLstudy was spiked at O.4ug/Lfor the target amilytes. As perCFRpart 136 Appendix B, aMDLin water shouldbe spiked at one to five times the estimated detection limit. Ourin houseMDLs for similaranalyses are all around 0.1ug/L. Forthe synthetic FOD matrix MDLstudy we spiked at 0.5ug/Land 1.0ug/L, as we anticipated needing a slightly higherconcentration than the waterMDL. Both ofthese proved to be discernable in the syntheticFOD matrix.
The methodblanks met acceptance criteria. TheLaboratory Control Samples (LCS) were spiked incorrectly. The 120920A-LCS was spiked at a concentration of 1.0ug/Linstead of 40ug/Lfor all target analytes. Recoveries met acceptancecriteria. The 120921A-LCS was spiked at a concentration of250ug/Lfor chromium, arsenic, selenium, thallium and lead, and 50ug/Lfor cadmium.

In the 120921Areagent water samples, and all methodblanks andLCS samplesran this day, the internal standards indium and terbium exceededthe 125% upper control limits.


# Calibration:

A three-pointcalibration curve was preparedfor quantitation and summarizedin the "standard prep" section ofthis report. The correlation coeficients for all analytes were greaterthan 0.995 and are summarizedon the highest calibration pointin the "calibration" section ofthis report.
In the calibration for analysis performed on 9/26/12, the percent oxides were measured at 1.566% insteadof 1 % as suggestedin the method. According to the instrumentmanufacturer,

an oxide level below three is acceptable, howeverwhen it is greaterthan 2% the rare earth metals maybecome unstable. The rare earth metals onlyinclude ourinternal standards. All othertuning criteria weremet.
Weusedthe calibration blank at Mass 75-interference check. Thecounts per second (CPS) for arsenic were well below 25% ofthe CPS for arsenic at the reporting limit.

In the ICV at 05:21, seleniumrecovered below the 90% lowercontrol limit at 89.6%. The ICB, LUCV, andthe unspikedFOD matrix interferencecheck met acceptancecriteria. The spikedFOD matrix checkrecovered above the 130% uppercontrol limitfor arsenic at 130.1% and selenium at 134.6%. The CCVs were spikedincorrectly at 100ug/Lfor As, Cd, Cr, Pb, TI and Seinstead of50ug/L.

In the individual FOD interference check, chloride was analyzed at 5000mg/Linstead of 10,000mg/Lbecause the laboratory does nothave a standard at this concentration. All other interference check solutions were made according to the concentrations statedin the method. In the Calcium interferencecheck the indium andterbium internal standardsrecovered below the 60% lowercontrol limit at 57.9% and 55.7%,respectively.
The individual interferencecheck solutions exceededthe reporting limits of 1.0ug/Las follows: in the calcium solution, chromiumexceededat 3.44ug/L, arsenic at 4.04ug/L, cadmium at 3.32ugIL, and lead at 1.08ug/L. In the sulfate solution, seleniumexceeded at 3.45ug/L. In the magnesium solution, chromiumexceededat 3.09ug/L, arsenic at l.llug/L and lead at 1.69ugIL. In the iron solution, chromiumexceeded at 1.1lugIL. In the vanadium

68603 CSC CASE.doc

# solution, selenium exceededat 9.64ugIL. In the zinc solution, selenium exceeded at 3.43ugIL. In the chromium solution, selenium exceeded at 1.86ugIL. In the copper solution, selenium exceeded at 1.41ugIL.

In the 120921A 1.0FGDmatrix MDL samples, the internal standardindium (#1) associated with selenium recovered below the 60% lower control limits.

In the calibration for analysis performedon 9/27112 the percent oxides were measured at 1.997% instead of 1 % as suggestedin the method. All othertuning criteria were met.

In the ICV on 9/27112 at 06:50, silverrecovered below the 90% lowercontrol limit at 89.8%. TheICB, LUCV, and the unspikedFGDmatrix interferencecheck met acceptance criteria. In the spikedFGDmatrix, arsenic and seleniumrecovered above the 130% uppercontrol limits at 138.6% and 134.6%,respectively.

In the CCVs at 09:11,10:44 and 12:18 andthe CCBs at 09:24 and 10:58 the internal standards indium#3 (associated with cadmium) andterbium (associated with lead) recovered above the 125% uppercontrol limits. Additionally, the CCVat 09: 11 exceededthe 110% uppercontrol limit for selenium at 113.4%.

Ifyou have any questions orrequirefurther information, please contact yourAPPLProject ManagerStephaneMaupas at yourconvenience. Thankyou for choosingAPPL, Inc.
Release ofthe hard copy has been authorizedby the LaboratoryManagerorherdesignee, as verifiedby the following signature.

Sharon Dehmlow, LaboratoryDirector APPL, Inc.
SD/rp Enclosure

cc: File

68603 CSCCASE.doc

# METALS



# Chain ofCustodyand ARF

# APPL
- 

# Analysis Request Form 68603

Client: CSC Received by: CM 11111111111111111111111111111111111 

## Address: 6101 Steveson Ave. Date Received: 

# 08/30/12 Time: 15:30 Alexandria, VA 22304 Delivered by: -=---F=E=O--=E=-X=------

________ _ Attn:**Chi~Q_'_'M=c~C=a=_=__rt~y** 

## ________ _ Shuttle Custody Seals 

# (YIN): 

# l Time Zone: -4 Phone: 703-461-2392 Fax: 703-461-8056 Chest Temp(s):**-'-R=O~O::...:M_=..:........:.T-=E=M=P** 

## _______ _ Job: FGO MOL Study Color:**A-frig~**

## _________**~** 

## PO 

# #: 685553SS0 Samples Chilled until Placed in Refrig/Freezer: 

# Y Chain of Custody 

# (Y/N):--'L 

# #

______ _ Project Manager: SteQhane MauQ'--'-a-'-s

____ _ RAD Screen 

# (YIN): Y pH 

# (YIN): N QC Report Type: OVP4/EXCELN A
r1 

## Turn Around Type:

Comments: 

# STO Due Date: 

# 09/20/12

Send PDFon CD andemailreporttohmccarty@csc.com Documenteverythingyou do. Report

# 3 sig figs. Do not waste the simulatedFGD fluid. Follow SOWand QAPP: do notdeviate with notifying PM Need Results by9-15-2012

Sample Distribution: Charges: Invoice To: Metals:**14-$2008~Cr,Se,Cd,Pb,I!t----=1'--'-4_-** 

## ____________ _ $20082(As,Cr,Se,-=C.=d,'-'-P-=bL:,T-'1 I)

______________----- Send Invoice to PM for approval

Client ID

1. RW-1

2. RW-2

3. RW-3 APPL ID Sampled Analyses Requested
AY67404W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67405W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67406W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI), 111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

Note: All times, excluding sample collection times. are Pacific Time Zone unless noted otherwise. Collection times are in: -4 UTC 

## Page 1 Client Code: GENERIC 

### Printed 10102112 12:53:33 

### PM Computer: RENEECOMPUT 

# # 68603

# APPL
- Analysis Request Form 68603
4. RW-4 AY67407W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

5. RW-5 AY67408W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

6. RW-6

7. RW-7

8. FGD-1

9. FGD-2

10. FGD-3

11. FGD-4

12. FGD-5

13. FGD-6

14. FGD-7 AY67409W 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY6741OW 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67411M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67412M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67413M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67414M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67415M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67416M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

AY67417M 08/30/12 00:01 $2008(As,Cr,Se,Cd,Pb,TI),
111111111111111111111111111111111111111111111 

## $20082(As,Cr,Se,Cd,Pb,TI)

-- Dilute; digest by EPA 1638

Note: All times, excluding sample collection times, are Pacific Time Zone unless noted otherwise. Collection times are in: -4 UTC 

## Page 2 Client Code: GENERIC 

### Printed 10/02112 

## 12:53:33 PM Computer: RENEECOMPUT 

# # 68603

# METALS

QC Summary

# METALS BLANK

APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

Method Analyte Result PQL Units Prep Date Analysis Date QC Group
200.8 ARSENIC (AS) Not detected 0.5 ug/L 

## 09/20/12 09/26/12 #2008-120920A-AY67404 200.8 CADMIUM (CD) Not detected 0.2 ug/L 

## 09/20/12 09/26/12 #2008-120920A-AY67404 200.8 CHROMIUM (CR) Not detected 0.5 ug/L 

## 09/20/12 09/26/12 #2008-120920A-AY67404 200.8 LEAD (PB) Not detected 0.2 ug/L 

## 09/20/12 09/26/12 #2008-120920A-A Y67404 200.8 SELENIUM (SE) Not detected 1.0 ug/L 

## 09/20/12 09/26/12 #2008-120920A-AY67404 200.8 THALLIUM (TL) Not detected 0.2 ug/L 

## 09/20/12 09/26/12 #2008-120920A-AY67404

200.8 ARSENIC (AS) Not detected 0.2 ug/L 

## 09/20/12 09/27/12 #2008-120920A-AY67411 200.8 CADMIUM (CD) Not detected 0.20 ug/L 

## 09/20/12 09/27/12 #2008-120920A-AY67411 200.8 CHROMIUM (CR) Notdetected 0.2 ug/L 

## 09/20/12 09/27/12 #2008-120920A-AY67411 200.8 LEAD (PB) Not detected 0.2 ug/L 

## 09/20/12 09/27/12 #2008-120920A-AY67411 200.8 SELENIUM (SE) Not detected 0.2 ug/L 

## 09/20/12 09/27/12 #2008-120920A-AY67411 200.8 THALLIUM (TL) Not detected 0.2 ug/L 

## 09/20/12 09/27/12 #2008-120920A-AY67411

Printed: 101011125:01:13

### PM

# Laboratory Control Spike Recovery METALS

APPL Inc. 908 

## North Temperance Avenue Clovis, CA 93611

Method Compound Name Spike Level SPK Result SPK% Recovery Extract Analysis 

## ug/L ug/L Recovery Limits Date Date

200.8 ARSENIC (AS) 250 257 103 85-115 09/20/12 09/26/12
200.8 CADMIUM (CD) 50.0 47.6 95.2 85-115 09/20/12 09/26/12
200.8 CHROMIUM (CR) 250 285 114 85-115 09/20/12 09/26/12
200.8 LEAD (PB) 250 229 91.6 85-115 09/20/12 09/26/12
200.8 SELENIUM (SE) 250 269 108 85-115 09/20/12 09/26/12 200.8 THALLIUM (TL) 250 226 

## 9004 85-115 09/20/12 09/26/12



## Comments:



# ---------------------------------------------------------------------- QC Group

#2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404

Printed: 101011125:04:41 

### PM APPL StandardLCS

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

Method Compound Name

200.8 ARSENIC (AS)
200.8 CADMIUM (CD)
200.8 CHROMIUM (CR)
200.8 LEAD (PB)
200.8 SELENIUM (SE)
200.8 THALLIUM (TL) 

# Laboratory Control Spike Recovery METALS

Spike Level SPK Result SPK% Recovery Extract ug/L ug/L Recovery Limits Date

1.00 1.1 110 85-115 

## 09/20/12
1.00 1.1 110 85-115 

## 09/20/12
1.00 0.99 99.0 85-115 

## 09/20/12
1.00 0.98 98.0 85-115 

## 09/20/12
1.00 1.1 110 85-115 

## 09/20/12
1.00 0.91 91.0 85-115 

## 09/20/12 

## Analysis Date

09/27/12 09/27/12 09/27/12 09/27/12 09/27/12 09/27/12



## Comments:

____________________________________________________________________ __ QC Group

#2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411

Printed: 101011125:04:41 PM APPL StandardLCS

# METALS
Sample Data

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: 

# RW-1 Sampie Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.46 0.36 0.37 0.33 0.88 POL Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67404

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12**_~~9_·~**

# ______________**T_Ij_~~~~~~_Q~~)**

# _______________________________________**9_·~~** 

# _______________________**~:?**

# ________________**~9!~**

# ________**9_9!~~L~?** 

# ___________**~~~?X!~_ ?** 

# _____

Form 

### 1 - APPL Standard Metals

- No 

# Me
Printed: 101011125:01:18

### PMC,\ICPCIlEM\1\OATA\12I26qOO.B\OBOSMPL.O\OBOSMPL .0#



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\080SMPL.D\080SMPL.D# Sep 27 2012 01:20 am Operator: NBS Sample Name: BLK MDL 0.4-1 

### Mise Info: 120921A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3304 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep oil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element (Li) Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 MIl 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Conc. ug/l 0.30 ug/l 11.67 ug/l 383.10 ug/l 237.30 ug/l

1.30 ug/l 59.06 ug/l 326.00 ug/l

0.22 ug/l 0.47 ug/l 0.37 ug/l -1.06 ug/l 3.58 ug/l 0.40 ug/l 0.32 ug/l 0.44 ug/l 0.45 ug/l -2.43 ug/l 0.46 ug/l 0.88 ug/l 2.71 ug/l -0.06 ug/l -0.03 ug/l 0.33 ug/l ug/l 0.17 ug/l ug/l 0.36 ug/l -3.14 ug/l -3.30 ug/l -2.92 ug/l 0.39 ug/l 0.30 ug/l 0.33 ug/l ug/l ug/l 0.33 ug/l Carr. Conc. #VALUEI 0.30 11.67 383.10 237.30

1.30 59.06 326.00

0.22 0.47 0.37 -1.06 3.58 0.40 0.32 0.44 0.45 -2.43 0.46 0.88 2.71 -0.06 -0.03 0.33 #VALUEI 0.17 #VALUEI 0.36 -3.14 -3.30 -2.92 0.39 0.30 0.33 #VALUEI #VALUE I 0.33

Element CPS Mean RSD(%) Ref Value Li -103602.70 5.24 -131996.50 45 Sc 3305273.30 0.78 3646344.80 45 Sc 438338.66 0.47 537987.94 45 Sc 15578020.00 0.39 17012292.00 72 Ge 823952.19 0.11 949396.31 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 277281.06 3276284.80 5969842.00 2882175.30 21738374.00 27067192.00 26065410.00 2.07 338792.91 0.81 3456710.80 0.96 6610579.00 0.68 3651775.30 0.71 22769202.00 1.06 28649686.00 0.84 27453282.00 RSD(%) High Limit 

## o 2.81 1000 2.04 1000 4.74 25000 2.62 50000 32.20 20000

8.04 20000 6.14 50000 22.40 1000

1.61 1000 3.55 1000 1.48 1000 1.93 20000 0.59 8.86 6.57 7.45 0.75 3.22 2.25 6.82 37.80 16.72 4.08

2.79

0.86 1.02 1.84 0.19 1.42 5.10 0.83

1.36 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### #U####U 500 

### #UU##U# 1000 

### U#UUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU U##UUUU 1000

QC Range(%) Rec(%)

78.5 90.6 81.5 91.6 86.8 81.8 94.8 90.3 78.9 95.5 94.5 94.9 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 70

- 70

- 70 70

- 70

- 70

- 120 120 120 120 120 120 120 Flag

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU

:Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 1:24 AM 

### Pass Fail

## o :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study 

## Sample 10: 

## RW-1 Sample Collection Date: 08/30/12

Method
200.8 200.8 200.8 

## Analyte
ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) 

# Metals Analysis

Result
0.50 0.40 0.36 

# pal

0.2 0.2 

## 0.2 

## Units ug/L ug/L ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67404

Prep Date Analysis Date
09/21/12 09/21/12 09/21/12 09/27/12 09/27/12 09/27/12 200.8 LEAD (PB) 0.38 0.2 ug/L 

## 09/21/12 09/27/12 200.8 SELENIUM (SE) 0.45 0.2 

## ug/L 09/21/12 09/27/12



# __**~~9_·~**

# ______________**T_Ij_;:'_~~~~~_Q~~)**

# _______________________________________**9:~?** 

# _______________________**~:~**

# _ _______________**~g!~**

# ________**9_~!?~L~?** 

# ___________**9~~?X{~ _?** 

# _____

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:03:26 PMC,\ICPCHEM\l\OATA\12127s00.B\037SMPL.D\037SMPL.Dj



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27s00.B\037SMPL.D\037SMPL.D# Sep 27 2012 10:04 pm Operator: NBS Sample Name: BLK MDL 0.4-1 Mise Info: 120921A-1638 Vial Number: CUrrent Method: Calibration File: Last Cal Update: 3304 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep oil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l 0.42 ug/l 0.29 ug/l 145.50 ug/l 106.90 ug/l

4.00 ug/l 47.81 ug/l 184.80 ug/l

0.37 ug/l 0.57 ug/l 0.36 ug/l 0.49 ug/l 8.36 ug/l 0.42 ug/l 0.51 ug/l 0.41 ug/l 0.43 ug/l 4.03 ug/l 0.50 ug/l 0.45 ug/l 2.87ug/l 0.48 ug/l 0.40 ug/l 0.26 ug/l ug/l 0.20ug/l ug/l 0.40 ug/l 0.32 ug/l 0.38 ug/l 0.30 ug/l 0.42 ug/l 0.45 ug/l 0.36 ug/l ug/l ug/l 0.38 ug/l

Element CPS Mean RSD(%) Carr. Cone. #VALUE! 0.42 0.29 145.50 106.90

4.00 47.81 184.80

0.37 0.57 0.36 0.49 8.36 0.42 0.51 0.41 0.43 4.03 0.50 0.45 2.87 0.48 0.40 0.26 #VALUE! 0.20 #VALUE! 0.40 0.32 0.38 0.30 0.42 0.45 0.36 #VALUE! #VALUE! 0.38 RSD(%) High Limit 

## o 1.01 1000 13.21 1000

1.01 25000 1.17 50000 14.14 20000 2.61 20000 3.26 50000 5.49 1000 3.92 1000 0.73 1000 2.37 1000 0.96 20000 2.38 1000 4.79 1000 1.37 1000 4.30 1000 0.85 1000 3.03 1000 14.17 1000 3.24 1000 2.39 1000 1.14 1000 1.84 1000 ####### 3.36 500 ####### 1.98 1000 24.98 #######

2.87 ####### 3.63 1000 3.14 1000 1.87 1000 1.12 1000 ####### ####### 0.84 1000

QC Range(%) 6 Li -173541.61 4.37 Ref Value -88139.43 5590061.50

732360.19 Rec(%) 196.9 98.5 101.5 128.3 99.7 101.4 126.0

97.9 70 120 45 Sc 5508884.00 13.18 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 743064.00 23117014.00

1404062.80 482285.81 4587767.50 9846775.00 4771820.00 27685338.00 31468000.00 29482754.00 0.78 0.46 18013604.00 8.38 1407958.90 0.55 475526.09 0.95 3640663.30 13.13 10055673.00 0.55 4993515.00 0.54 20883300.00 0.55 23533162.00 0.84 22278996.00 95.6 132.6 133.7 132.3 70

- 120 70 120 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70 70 120 120 120 120 120 120 120 120 120 Flag

Flag IS fai

IS fai

IS fai

IS fai IS fai IS fai

ISTD Ref File , C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

:Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 10:08 PM 

### Pass Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: RW-2 Sampie Collection Date: 08/30/12

Method Analyte

200.8 ARSENIC (AS) 200.8 CADMIUM (CD) 200.8 CHROMIUM (CR) 200.8 LEAD (PB) 200.8 SELENIUM (SE) 

# Metals Analysis

Result

0.46 0.37 0.40 0.34 0.62 

## PQl Units

0.2 

## ug/L 0.2 

## ug/L 0.2 

## ug/L 0.2 

## ug/L 0.2 

## ug/L APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67405

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12



# __**~~9_·~**

# ______________**~_~~_~!:~~~_C~~~**

# _______________________________________**9_·~~** 

# _______________________**~:~**

# ________________**~g!!:**

# ________**9_~!?~!_1_?**

# __________**9~~?X~~?**

# ____

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:01:18 

### PMC:\ICPCHEM\l\DATA\12I26qOO.B\OB1SMPL.D\OB1SMPL.

# D'

Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\081SMPL.D\081SMPL.D# Sep 27 2012 01:27 am Operator: NBS Sample Name: BLK MDL 0.4-2 Misc Info: 120921A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3305 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l 0.31 ug/l 12.80 ug/l 169.10 ug/l 61.55 ug/l

1.59 ug/l 54.60 ug/l -37.99 ug/l

0.32 ug/l 0.58 ug/l 0.40 ug/l -0.98 ug/l 8.16 ug/l 0.41 ug/l 0.31 ug/l 0.49 ug/l 0.49 ug/l -2.37 ug/l 0.46 ug/l 0.62 ug/l 2.42 ug/l -0.05 ug/l -0.02 ug/l 0.35 ug/l ug/l 0.17 ug/l ug/1 0.37 ug/l -3.13 ug/l -3.27 ug/l -2.91 ug/l 0.36 ug/l 0.30 ug/l 0.34 ug/l ug/l ug/l 0.34 ug/l

Element CPS Mean RSD(%) 

### Corr. Cone. #VALUEI 0.31 12.80 169.10 61.55

1.59 54.60 -37.99

0.32 0.58 0.40 -0.98 8.16 0.41 0.31 0.49 0.49 -2.37 0.46 0.62 2.42 -0.05 -0.02 0.35 #VALUE! 0.17 #VALUEI 0.37 -3.13 -3.27 -2.91 0.36 0.30 0.34 #VALUE! #VALUE! 0.34 RSD(%) High Limit 

## o 3.31 1000 2.25 1000 2.77 25000 3.00 50000 18.97 20000 11.10 20000 24.25 50000 23.29 1000 7.54 1000 4.60 1000 1.23 1000 44.41 20000

1.98 8.27 3.20 5.03 0.65 3.20 6.23 12.46 187.39 171 .70

7.05

1.15

3.84 0.77 0.22 0.34 2.74 4.71 1.08

1.46 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 6 Li -106963.16 0.87 45 Sc 3072831.00 0.87 Ref Value -131996.50 3646344.80 Rec(%) 81.0 84.3 75.2 86.3 80.1 76.2 89.1 84 .0 74.9 92 .3 91.0 91.8 70 120 70

- 120 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 404812.03 14678355.00

760577.31 258010.20 3079824.50 5554741.00 2735935.30 21012024.00 26077882.00 25191176.00 0.43 537987.94 0.40 17012292.00 1.33 949396.31 2.44 338792.91 0.53 3456710.80 0.86 6610579.00 0.30 3651775.30 0.62 22769202.00 0.59 28649686.00 1.29 27453282.00 70 70 70 70 70 70 70 70 70

- 70 120 120 120 120 120 120 120 120 120 120 Flag

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.0#

o :Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 1:30 AM 

### Pass Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study 

## Sample 10: RW-2 Sample Collection Date: 08/30/12

Method Analyte
200.8 ARSENIC (AS) 200.8 CADMIUM (CD) 200.8 CHROMIUM (CR) 

# Metals Analysis

Result PQL Units
0.50 0.2 ug/L 0.40 0.2 ug/L 0.38 0.2 ug/L APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67405

Prep Date Analysis Date
09/21/12 09/21/12 09/27/12 09/27/12 09/21/12 09/27/12 200.8 LEAD (PB) 0.39 0.2 ug/L 09/21/12 09/27/12 200.8 SELENIUM (SE) 0.49 0.2 ug/L 09/21/12 09/27/12**.~~~:~**

# ______________**T_Ij_~_~~~~~_C~~~**

# _______________________________________**Q:~!**

# ______________________**~:?**

# ________________**~9!~**

# ________**~_~!~~!_~?** 

# ___________**Q~{?X!~_?**

# _____

Form 

## 1 - APPL Standard Metals

- No 

# Me
Printed: 101011125:03:26 PMC:\ICPCHEK\l\DATA\12127.00.8\038SMPL.D\038SMPL.D#



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27s00.B\038SMPL.D\038SMPL.D# Sep 27 2012 10:11 pm Operator: NBS Sample Name: BLK MDL 0.4-2 Mise Info: 120921A-1638 Vial Number: CUrrent Method: Calibration File: Last Cal Update: 3305 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Blements Element Conc. Carr. Conc. #VALUEl 0.42 0.29 93.11 54.85 4.48 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.42 ug/l 0.29 ug/l 93.11 ug/l 54.85 ug/l 4.48 ug/l 45.40 ug/1 66.38 ug/l 0.43 ug/l 0.54 ug/l 0.38 ug/l 0.54 ug/l 10.54 ug/l 0.42 ug/l 0.45 ug/l 0.41 ug/l 0.38 ug/l 1.16 ug/l 0.50 ug/l 0.49 ug/l .2.66 ug/l 0.47 ug/l 0.39 ug/l 0.27 ug/l ug/l 0.20 ug/l ug/l 0.40 ug/l 0.37 ug/l 0.43 ug/l 0.31 ug/l 0.40 ug/l 0.44 ug/l 0.37 ug/l ug/l ug/l 0.39 ug/l 45.40 66.38 0.43 0.54 0.38 0.54 10.54 0.42 0.45 0.41 0.38 1.16 0.50 0.49 2.66 0.47 0.39 0.27 #VALUEl 0.20 #VALUEl 0.40 0.37 0.43 0.31 0.40 0.44 0.37 #VALUEl #VALUEl 0.39

ISTD Elements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50

732360.19 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -177837.72 5411389.00

744891. 38 23060816.00

1379568.50 476809.56 4585969.50 9483376.00 4788741.00 27870798.00 31247978.00 29465290.00 1.26 1.27 1.07 0.87 18013604.00 0.18 1407958.90 1.30 475526.09 1.71 3640663.30 0.48 10055673.00 0.78 4993515.00 0.95 20883300.00 0.37 23533162.00 0.45 22278996.00 RSD(%)

3.34 35.26

2.34 3.12 32.37

1.96 6.16 17.58 1.83 2.81 1.15 1.17 1.03 2.13 0.47 3.59 10.42 2.36 3.33 6.19 6.28 2.54 7.24

0.52

2.06 5.71 1.85 4.14 0.79 6.23 2.24

1.42

Rec(%)

201.8

96.8 101.7 128.0 98.0 100.3 126.0 94.3 95.9 133.5 132.8 132.3 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

QC Range (%) Flag 70 120 IS Fai 70 120 70

- 120 70

- 120 IS Fai 70

- 120 70

- 120 70 120 IS Fai 70 120 70 70

- 70

- 70

- 120 120 IS Fai 120 IS Fai 120 IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#

:Blement Failures 6 :ISTD Failures



### Data Results: Analytes: ISTD:

912711210:15 PM 

### Pass Fail :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: RW-3 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.43 0.35 0.35 0.34 0.54 POL Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67406

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12



# ..**~~9_·~**

# ______________**"!"_Ij~_~~~~~_C~~)**

# _______________________________________**9}~** 

# _______________________**~:?**

# ________________**~9!_~**

# ________**9_~!?~!_~?** 

# ___________**9~~?X!~ _~** 

# _____

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:01:18

### PMC,\ICPCIIEM\l\DATA\12126qOO.B\082SMPL.D\082SMPL.D#



### Sample QC Report

Data File: Date Acquired, Operator: C:\ICPCHEM\1\DATA\12I26qOO.B\082SMPL.D\082SMPL.D# Sep 27 2012 01:33 am
Sample Name, Mise Info: NBS BLK MDL 0.4-3 120921A-1638 Vial Number, Current Method, Calibration File: Last Cal Update, Sample Type, Prep Dil Factor: 3306 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample 1.00 Total Dil Factor, 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Conc. ug/l 0.32 ug/l 12.89 ug/l 139.40 ug/l 44.64 ug/l

1.55 ug/l 46.60 ug/l -57.04 ug/l

0.29 ug/l 0.52 ug/l 0.35 ug/l -1.02 ug/l 3.21 ug/l 0.39 ug/l 0.30 ug/l 0.47 ug/l 0.47ug/l -2.44 ug/l 0.43 ug/l 0.54 ug/l 2.22 ug/l -0.06 ug/l -0.05 ug/l 0.31 ug/l ug/l 0.17 ug/l ug/l 0.35 ug/l -3.18 ug/l -3.36 ug/l -2.93 ug/l 0.36ug/l 0.43 ug/l 0.33 ug/l ug/l ug/l 0.34 ug/l

Element CPS Mean RSD(%) 

### Cerro Conc. #VALUE! 0.32 12.89 139.40 44.64

1.55 46.60 -57.04

0.29 0.52 0.35 -1.02 3.21 0.39 0.30 0.47 0.47 -2.44 0.43 0.54 2.22 -0.06 -0.05 0.31 #VALUE! 0.17 #VALUE! 0.35 -3.18 -3.36 -2.93 0.36 0.43 0.33 #VALUE! #VALUE! 0.34 RSD(%) High Limit 

## o 5.92 1000 2.06 1000 2.93 25000 5.66 50000 23.69 20000

9.22 20000 16.12 50000 33.53 1000 4.93 1000 4.44 1000 3.92 1000 6.29 20000 2.31 1000 2.55 1000 1.00 11.20 0.73 4.19 4.05 4.77 58.44 6.31 7.64

2.13

6.18 1.34 0.49 0.24 3.76 5.64 1.67

1.07 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 6 Li -104798.59 1.86 Ref Value -131996.50 3646344.80 Rec(%) 79.4 82.0 74.6 84.4 78.4 74.7 87.7 82.5 74.4 89.9 90.6 91.7 70 120 45 Sc 2990962.50 0.47 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 401310.91 14360043.00

744779.69 253142.72 3032086.30 5451065.50 2718455.50 20458602.00 25961598.00 25171444.00 1.75 537987.94 0.25 17012292.00 1.01 949396.31 0.18 338792.91 0.45 3456710.80 0.09 6610579.00 0.11 3651775.30 0.41 22769202.00 0.28 28649686.00 0.46 27453282.00 70 120 70 70

- 70

- 70

- 70 70

- 70 70

- 70 70

- 120 120 120 120 120 120 120 120 120 120 Flag

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures :ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 1:37 AM 

### Pass Fail :Max. Number of Failures Allowed

o :Max. Number of ISTD Failures Allowed

C,\ICPCHBM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: 

## RW-3 Sample Collection Date: 08/30/12

Method
200.8 200.8 Analyte
ARSENIC (AS) CADMIUM (CD) 

# Metals Analysis

Result
0.47 0.41 

## PQL
0.2 0.2 Units ug/L ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: 

## AY67406

Prep Date Analysis Date
09/21/12 09/21/12 09/27/12 09/27/12 200.8 CHROMIUM (CR) 0.34 0.2 ug/L 09/21/12 09/27/12 200.8 LEAD (PB) 0.38 0.2 ug/L 09/21/12 09/27/12 200.8 SELENIUM (SE) 0.44 0.2 ug/L 09/21/12 09/27/12



# ..**~Q9:~**

# ........__**._._T.~~_~~~~~_C~~1**

# __._.._ ...._._._.._._._..___._...__..**_.9:~?._._._**

# ................**Q:~**

# ............._ ..**~g!~_**

# .......**9.~!?~!.~?**

# ...__. ____**9~~?X{~_~**

# _____

Form 

## 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:03:26

### PMC,\ICPCHEM\l\DATA\12127.00 .B\OJ9SMPL.D\039SMPL.

### D'

Sample QC Report

Data File, Date Acquired, Operator, Sample Name, 

### Mise Info: C:\ICPCHEM\1\DATA\12I27S00.B\039SMPL.D\039SMPL.DU Sep 27 2012 10,18 pm NBS BLK MDL 0.4-3 120921A-1638 Vial Number, Current Method, 

### Calibration File: Last Cal Update, Sample Type, Prep Dil Factor: 3306 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample 1.00 Total Dil Factor, 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Cone. ug/l 0.43 ug/l 0.18 ug/l 91.42 ug/l 33.53 ug/l 3.79 ug/l 42.26 ug/l 23.65 ug/l 0.37 ug/l 0.49 ug/l 0.34 ug/l 0.46 ug/l 7.77 ug/l 0.41 ug/l 0.41 ug/l 0.38 ug/l 0.38 ug/l 1.05 ug/l 0.47 ug/l 0.44 ug/l 2.55 ug/l 0.46 ug/l 0.38 ug/l 0.24 ug/l ug/l 0.19 ug/l ug/l 0.41 ug/l 0.30 ug/l 0.36 ug/l 0.27 ug/l 0.39 ug/l 0.57 ug/l 0.36 ug/l ug/l ug/l 0.38 ug/l 

### Carr. Cone. UVALUE! 0.43 0.18 91.42 33.53

3.79 42.26 23.65

0.37 0.49 0.34 0.46 7.77 0.41 0.41 0.38 0.38 1.05 0.47 0.44 2.55 0.46 0.38 0.24 UVALUE! 0.19 UVALUE! 0.41 0.30 0.36 0.27 0.39 0.57 0.36 UVALUE! UVALUE! 0.38 RSD(%) High Limit 

## o 4.59 1000 62.53 1000

2.86 25000 1.49 50000 5.75 20000 6.82 20000 13 .00 50000 30.42 1000

1.37 1000 0.79 1000 2.63 1000 0.42 20000 0.97 6.76 4.74 10.98 2.27 5.32 6.95 5.70 3.24 1.24 6.31

2.24

3.73 9.61 7.36 5.02 1.86 2.01 1.66

2.29 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000 Flag

Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 Rec (%) 196.3 96.7 101.6 126.8 97.1 98.5 124.6 QC Range (%) Flag 6 Li -173009.55 5.75 70 120 IS Fai 45 Sc 5406428.50 0.63 70

- 120 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 744385.31 22844010.00

1367568.50 468234.97 4537357.50 9585306.00 4835281.50 27915818.00 31504894.00 29729574.00

ISTD Ref File :



## o :Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD:

9/27/1210:22 PM 0.72 732360.19 0.77 18013604.00 0.32 1407958.90 1.57 475526.09 1.17 3640663.30 0.74 10055673.00 0.16 4993515.00 0.53 20883300.00 1.37 23533162.00 0.54 22278996.00 95.3 96.8 133.7 133.9 133.4 70 70 70 70 70 70 70 70 70 70 120 120 IS Fai 120 120 120 IS Fai 120 120 120 IS Fai 120 IS Fai 120 IS Fai

C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.DU



### Pass Fail

## o ,Max. Number of Failures Allowed

o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: RW-4 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.45 0.36 0.38 0.35 0.56 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67407

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12



# ..**~~9:~**

# .....____...**_.T.I-:lt-.~!:~~~.{!~)**

# ..._ .._

.._._.__________________________

# 9}?

_______________________**~:~**

# ________________**~g!_~**

# ________**9_~t~~!_~~**

# __________**Q~~?!.t~_?**

# _____

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:01:18

### PMC:\ICPCHEM\l\DATA\12I26qOO .8\083SMPL.D\083SMPL.D#



### Sample QC Report.

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\083SMPL.D\083SMPL.DU Sep 27 2012 01:40 am Operator: NBS Sample Name: BLK MDL 0.4-4 

### Mise Info: 120921A-1638 Vial Number: CUrrent Method: 

### Calibration File: Last Cal Update: 3307 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) III Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Cone. ug/l 0.33 ug/l 12.57 ug/l 84.68 ug/l 30.14 ug/l

1.53ug/l 45.41 ug/l -91.93 ug/l

0.34 ug/l 0.50 ug/l 0.38 ug/l -1.03 ug/l 4.86 ug/l 0.39 ug/l 0.29 ug/l 0.50 ug/l 0.51 ug/l -2.38 ug/l 0.45 ug/l 0.56 ug/l 2.11 ug/l -0.08 ug/l -0.04 ug/l 0.35 ug/l ug/l 0.17 ug/l ug/l 0.36 ug/1 -3.15 ug/l -3.32 ug/l -2.92 ug/l 0.36 ug/l 0.30 ug/l 0.36 ug/l ug/l ug/l 0.35 ug/l

Element CPS Mean Carr. Cone. #VALUE! 0.33 12.57 84.68 30.14

1. 53 45.41 -91.93

0.34 0.50 0.38 -1.03 4.86 0.39 0.29 0.50 0.51 -2.38 0.45 0.56 2.11 -0.08 -0.04 0.35 #VALUE! 0.17 UVALUE! 0.36 -3.15 -3.32 -2.92 0.36 0.30 0.36 #VALUE! #VALUE! 0.35 RSD(%) High Limit 

## o 2.75 1000 3.37 1000 1.34 25000 4.09 50000 9.21 20000 6.21 20000 4.78 50000 45.70 1000

1.35 1000 5.45 1000 0.96 1000 7.19 20000 1.54 1000 1.85 6.95 0.87 0.77 5.94 6.54 1.66 9.34 14.13 19.52

2.61

4.74 0.83 1.23 0.47 1.58 4.08 1.63

1.49 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 U##U#UU 500 #U##U## 1000 U#UU##U U#U#UU# 1000 1000 1000 1000 #U#U### U##U##U 1000

QC Range(%) Li -104533.84 45 Sc 2888578.00 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 394083.78 14073723.00

723777.88 248784.34 2993818.80 5281723.00 2697630.00 RSD(%) 7.03 0.45 0.83 Ref Value -131996.50 3646344.80

537987.94 Rec(%) 79.2 79.2 73.3 82.7 76.2 73.4 86.6 79.9 73.9 90.1 90.8 92.1 70 120 70

- 120 70 120

20513066.00 26002262.00 25280290.00 1.12 17012292.00 0.78 949396.31 1.65 338792.91 1.42 3456710.80 0.44 6610579.00 0.41 3651775.30 0.77 22769202.00 0.15 28649686.00 0.44 27453282.00 70 70

- 70

- 70 70

- 70

- 70

- 70 70

- 120 120 120 120 120 120 120 120 120 Flag

Flag IS fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU

:Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/271121:44 AM 

### Pass Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MOL Study 

## Sample 10: RW-4 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.49 0.41 0.35 0.39 0.48 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67407

Prep Date Analysis Date

09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12



# __**~~9:~**

# ______________**T_Ij_~~~~~~_{~~~**

# _______________________________________**9:~~** 

# _______________________**~:~**

# ________________**~g!~**

# ________**9_~!~~!_~?** 

# ___________**~~~?X!~_~**

# _____

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:03:26

### PMC,\ICPCHEM\l\DATA\12I27.00.B\040SIIPL.D\040SIIPL.Df



### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, Mise Info: C,\ICPCHEM\1\DATA\12I27s00.B\040SMPL.D\040SMPL.D# Sep 27 2012 10,24 pm NBS BLK MDL 0.4-4 120921A-1638 Vial Number, CUrrent Method, Calibration File, Last Cal Update, Sample Type, 3307 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element Cone. Carr. Cone. #VALUEI 0.44 0.07 64.42 30.92 4.99 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 

### V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.44 ug/l 0.07 ug/l 64.42 ug/l 30.92 ug/l 4.99 ug/l 40.69 ug/l 23.13 ug/l 0.38 ug/l 0.51 ug/l 0.35 ug/l 0.54 ug/l 9.15 ug/l 0.42 ug/l 0.43 ug/l 0.39 ug/l 0.39 ug/l 1.06 ug/l 0.49 ug/l 0.48 ug/l 2.54 ug/l 0.47 ug/l 0.39 ug/l 0.26 ug/l ug/l 0.20 ug/l ug/l 0.41 ug/l 0.32 ug/l 0.36 ug/l 0.29ug/l 0.40 ug/l 0.43 ug/l 0.38 ug/l ug/l ug/l 0.39 ug/l 40.69 23.13 0.38 0.51 0.35 0.54 9.15 0.42 0.43 0.39 0.39 1.06 0.49 0.48 2.54 0.47 0.39 0.26 #VALUEI 0.20 #VALUEI 0.41 0.32 0.36 0.29 0.40 0.43 0.38 #VALUEI #VALUEI 0.39

ISTD Elements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -167382.92 5318581.00

742171.38 22777006.00

1359469.50 465309.97 4441313.50 9494831. 00 4811176.50 27997222.00 31543754.00 30051966.00 3.61 0.46 0.59 732360.19 0.39 18013604.00 0.78 1407958.90 1.72 475526.09 1.38 3640663.30 0.51 10055673.00 0.47 4993515.00 0.39 20883300.00 0.79 23533162.00 0.73 22278996.00 RSD (%)

1.95 54.42 2.49 1.59 12.31 9.17 17.38 7.43 2.95 4.31 3.44 2.06 1.19 9.24 6.51 1.44 5.60 4.27 3.28 2.07 2.03 1.04 4.88

3.70

4.40 3.79 5.68 2.96 1.90 5.17 1.94

1.35

Rec(%)

189.9 95.1 101.3 126.4 96.6 97.9 122.0 94.4 96.3 134.1 134.0 134.9 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

QC Range (%) Flag 70

- 120 IS fai 70

- 120 70

- 120 70

- 120 IS fai 70

- 120 70 70 70 70 70 70

- 70

- 120 120 IS fai 120 120 120 IS fai 120 IS fai 120 IS fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#

:Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD:

9/2711210:28 PM 

### Pass Fail :Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA22304

Attn: Chip McCarty Project: FGD MDL Study 

# Sample 10: RW-5 Sample Collection Date: 

## 08/30/12

Method Analyte
200.8 ARSENIC (AS) 200.8 CADMIUM (CD) 200.8 CHROMIUM (CR) 200.8 lEAD (PB) 

# Metals Analysis

Result PQl Units
0.39 0.2 ug/l 

## 0.35 0.2 ug/l 

## 0.36 0.2 ug/l 

## 0.35 0.2 ug/l 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

# APPL 10: AY67408

Prep Date Analysis Date
09/21/12 09/21/12 09/21/12 09/27/12 09/27/12 09/27/12 09/21/12 09/27/12 

## 200.8 SELENIUM (SE) 0.50 0.2 ug/l 09/21/12 09/27/12



# __**~~9_·~**

# ______________**~_Ij_~_~!:~~~_Q~~)**

# _______________________________________**9:~?** 

# _______________________**~:~**

# ________________**~g!_~**

# ________**9_~!~1!_~2** 

# ___________**~~~?X!~_~**

# _____

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:01:18PMC,\ ICPCHEM\1\DATA\12I26qOO.B\08aSMPL.D\088SMPL.**D~**


### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, Mise Info: C,\ICPCHEM\1\DATA\12I26qOO.B\088SMPL.D\088SMPL.D# Sep 27 2012 02,13 am NBS BLK MDL 0.4-5 120921A-1638 Vial Number, CUrrent Method, Calibration File: Last Cal Update, Sample Type, 3308 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l 0.34 ug/l 11.92 ug/l 33.13 ug/l 25.81 ug/l 2.06 ug/l 44.55 ug/l -94.87 ug/l

0.36 ug/l 0.36ug/l 0.36 ug/l -1.02 ug/l 3.38 ug/l 0.40 ug/l 0.30ug/l 0.49 ug/l 0.47 ug/l -2.39 ug/l 0.39ug/l 0.50 ug/l 1.78 ug/l 0.01 ug/l -0.05 ug/l 0.33 ug/l ug/l 0.17 ug/l ug/l 0.35 ug/l -3.09 ug/l -3.21 ug/l -2.84 ug/l 0.38 ug/l 0.30 ug/l 0.35 ug/l ug/l ug/l 0.35 ug/l Carr. Cone. #VALUE! 0.34 11.92 33.13 25.81 2.06 44.55 -94.87

0.36 0.36 0.36 -1.02 3.38 0.40 0.30 0.49 0.47 -2.39 0.39 0.50 1.78 0.01 -0.05 0.33 #VALUE! 0.17 #VALUE! 0.35 -3.09 -3.21 -2.84 0.38 0.30 0.35 #VALUE! #VALUE! 0.35 RSD(%) High Limit 

## o 2.18 1000 2.46 1000 5.87 25000 5.55 50000 9.93 20000 4.18 20000 3.09 50000 25.59 1000

1.09 1000 2.36 1000 0.58 1000 3.03 20000 1.88 19.86 2.45 8.09 2.73 6.39 6.08 5.81 1292.30

16.22 3.24

3.32

9.87 0.36 1.58 0.38 3.86 5.91 3.56

3.23 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 537987.94 Rec(%) 79.2 75.5 70.6 80.3 72 .9 72 .5 84.8 78.8 72.9 87.3 89.1 90.4 QC Range (%) Flag Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -104491.62 2754044.50

379776.13 13653336.00

691758.75 245508.00 2930961.80 5208871.00 2663554.30 19886866.00 25516102.00 24830408.00

ISTD Ref File ,

:Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD: 2.48 0.31 0.46 1.24 17012292.00 0.33 949396.31 0.82 338792.91 1.59 3456710.80 0.45 6610579.00 0.27 3651775.30 1.17 22769202.00 1.81 28649686.00 1.58 27453282.00 70 120 IS Fai 70 120 70

- 120 70 120 70 120 70 70 70

- 70

- 70 70 70

- 120 120 120 120 120 120 120
C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### Pass Fail :Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed 

# ,..r'l

9/27/122:17 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: RW-5 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.46 0.40 0.34 0.39 0.44 POL Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67408

Prep Date
09/21/12 09/21/12 09/21/12 09/21/12 09/21/12 Analysis Date
09/27/12 09/27/12 09/27/12 09/27/12 09/27/12



# __**~~9_·~**

# ______________**T_Ij!-_~~~~~_C~~)**

# ______________________________________g}?

_______________________**Q:~**

# ________________**~g!~**

# ________**9_~!~~L~~**

# __________**q~~?X!~_~**

# _____

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:03:27PMC,\ICPCHEM\l\DATA\l2I27s00.B\04lSMPL.D\04lSKPL.D#



### Sample QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I27S00.B\041SMPL.D\041SMPL.D# Sep 27 2012 10,31 pm Sample Name, 

### Mise Info: NBS BLK MDL 0.4-5 120921A-1638 Vial Number, Current Method, Calibration File, Last Cal Update, Sample Type, 3308 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Blements 

### Element Conc. Carr. Cone. #VALUE! 0.43 0.04 59.30 28.64

2.82 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.43 ug/l 0.04 ug/l 59.30 ug/l 28.64 ug/l

2.82 ug/l 45.84 ug/l 10.85 ug/l 0.36ug/l 0.48 ug/l 0.34 ug/l 0.45 ug/l 7.75 ug/l 0.41 ug/l 0.43 ug/l 0.38 ug/l 0.37 ug/l 1.03 ug/l 0.46 ug/l 0.44 ug/l 2.35 ug/l 0.44 ug/l 0.37 ug/l 0.25 ug/l ug/l 0.18 ug/l ug/l 0.40ug/l 0.27 ug/l 0.33 ug/l 0.25 ug/l 0.38 ug/l 0.42 ug/l 0.37 ug/l ug/l ug/l 0.39 ug/l 45.84 10.85 0.36 0.48 0.34 0.45 7.75 0.41 

## o.43 0.38 0.37 1.03 0.46 0.44 2.35 0.44 0.37 0.25 #VALUE! 0.18 #VALUE! 0.40 0.27 0.33 0.25 0.38 0.42 0.37 #VALUE! #VALUE! 0.39

ISTD B1ements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 732360.19 Li -172695.88 1.89 45 Sc 5487221.00 3.62 45 Sc 728612.38 0.71 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 22262300.00 1384213.10 462509.19 4454759.50 9855620.00 4800969.50 27879698.00 31392670.00 30001668.00 0.31 18013604.00 3.87 1407958.90 0.82 475526.09 0.99 3640663.30 4.29 10055673.00 0.43 4993515.00 0.69 20883300.00 1.40 23533162.00 0.78 22278996.00 RSD(%) High Limit 

## o 2.62 1000 66.93 1000

1.55 25000 3.00 50000 19.13 20000 1.26 20000 35.16 50000 25.82 1000 7.26 1000 1.49 1000 5.15 1000 1.28 20000 5.22 5.51 2.51 7.12 0.19 5.65 6.62 1.88 6.15 1.75 6.50

3.28

2.47 3.96 4.05 4.10 2.81 3.56 1.15

0.21 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

Rec(%)

195.9 98.2 99.5 123.6 98.3 97.3 122.4 QC Range (%) Flag

98.0 96 .1 133.5 133.4 134.7 70

- 120 IS Fai 70 120 70 120 70 120 IS fai 70

- 120 70

- 120 70

- 120 IS Fai 70 120 70

- 120 70 120 IS Fai 70 120 IS fai 70 120 IS fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#



### o :Element 

### Failures

:ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 10:35 PM 

### Pass Fail

## o ,Max. Number of Failures Allowed 

## o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: RW-6 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.39 0.37 0.38 0.36 0.51 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67409

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12

Form 1 - APPL Standard Metals

- No

# Me
Printed: 10/011125:01:18 PMC, \ICPCHEM\l\OATA\12I26qOO.B\OB9SMPL.O\OB9SMPL.O#



### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, Mise Info: vial Number: C,\ICPCHEM\1\DATA\12I26qOO.B\089SMPL.D\089SMPL.D# Sep 27 2012 02,20 am NBS BLK MDL 0.4-6 120921A-1638

CUrrent Method, Calibration File: Last Cal Update, Sample Type, 3309 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep·26 2012 05,18 pm Sample Prep Oil Factor; Total Oil Factor, 1.00 1.00

QC Elements Element Cone. Carr. Cone. #VALUE! 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.34 ug/l 12.26 ug/l 27.19 ug/l 24.50 ug/l 2.56 ug/l 52.40 ug/l -96.83 ug/l

0.43 ug/l 0.38 ug/l 0.38 ug/l -1.05 ug/l 3.43 ug/l 0.41 ug/l 0.31 ug/l 0.51 ug/l 0.47 ug/l -1.52 ug/l 0.39 ug/l 0.51 ug/l 1.60 ug/l -0.08 ug/l -0.03 ug/l 0.34 ug/l ug/l 0.17 ug/l ug/l 0.37 ug/l -3.11 ug/l -3.27 ug/l -2.85 ug/l 0.38 ug/l 0.32 ug/l 0.37 ug/l ug/l ug/l 0.36 ug/l 0.34 12.26 27.19 24.50

2.56 52.40

- 96

.83

0.43 0.38 0.38 -1.05 3.43 0.41 0.31 0.51 0.47 -1.52 0.39 0.51 1.60 -0.08 -0.03 0.34 #VALUE! 0.17 #VALUE! 0.37 -3.11 -3.27 -2.85 0.38 0.32 0.37 #VALUE! #VALUE! 0.36

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 Li -99843.95 1.49 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 2758808.50 380028.69 13325853.00

689633.63 246202.89 2886170.00 5191213.00 2646496.30 19773904.00 25146660.00 24375834.00 0.36 3646344.80 1.82 537987.94 3.88 17012292.00 0.67 949396.31 0.78 338792.91 2.97 3456710.80 0.89 6610579.00 0.40 3651775.30 4.74 22769202.00 3.40 28649686.00 3.60 27453282.00 RSD(%) High Limit 

## o 8.41 1000 2.64 1000 4.81 25000 1.75 50000 25.22 20000

3.84 20000 1.50 50000 21.57 1000 8.12 1000 1.88 1000 1.16 1000 4.00 20000 2.14 12.11

1.76 6.23 6.08 10.91 5.15 15.01 42.20 45.74 4.84

6.47

9.54 0.26 0.74 0.72 4.07 12.57 3.30

6.39

Rec(%)

75.6 75.7 70.6 78.3 72 .6 72.7 83.5 78.5 72.5 86.8 87.8 88.8 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range (%) 70 120 70 120 70 120 70

- 120 70

- 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70 120 70 120 Flag

Flag IS Fai 

## tJ

# T

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures

: ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 2:24 AM 

### Pass Fail :Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: RW-6 

## Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.46 0.40 0.37 0.39 0.47 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67409

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12



# __**~~~:~**

# __.___________**T_Ij_~_~~~~~_Q~~)**

# _______________________________________**~:~?** 

# _________......______**._~:~**

# _______. ________**~9!~**

# ________**~_~!?~!_~?** 

# __________**.Q~{?X{~_~**

# ____.

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:03:27PMC,\ICPCHEII\l\DATA\12127.00.B\046SMPL.D\046SMPL.D#



### Sample QC Report

Data File, Date Acquired, Operator: C:\ICPCHEM\1\DATA\12I27s00.B\046SMPL.D\046SMPL.D# Sep 27 2012 11:04 pm NBS Sample Name: BLK MDL 0.4- 6 

### Mise Info: 120921A-1638 Vial Number: CUrrent Method, Calibration File: Last Cal Update: 3309 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor, 1.00

QC Elements Element 

### Cone. Corr. Cone. #VALUEI 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) III Cd 118 Sn 118 Sn ll8 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.42 ug/l -0.18 ug/l 27.73 ug/l 27.69 ug/l 4.59ug/l 37.02 ug/l 2.88 ug/l 0.39 ug/l 0.47 ug/l 0.37 ug/l 0.48 ug/l 8.46 ug/l 0.44 ug/l 0.45 ug/l 0.40 ug/l 0.40 ug/l 2.17 ug/l 0.46 ug/l 0.47 ug/l 2.15 ug/l 0.47 ug/l 0.37 ug/l 0.26 ug/l ug/l 0.19ug/l ug/l 0.40 ug/l 0.37 ug/l 0.42 ug/l 0.29 ug/l 0.39 ug/l 0.43 ug/l 0.37 ug/l ug/l ug/l 0.39 ug/l 0.42 -0.18 27.73 27.69 4.59 37.02

2.88 0.39 0.47 0.37 0.48 8.46 0.44 0.45 0.40 0.40 2.17 0.46 0.47 2.15 0.47 0.37 0.26 #VALUEI 0.19 #VALUEI 0.40 0.37 0.42 0.29 0.39 0.43 0.37 #VALUEI #VALUEI 0.39

ISTD Elements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 Li 45 Sc 45 SC 45 Sc 72 Ge 72 Ge 72 Ge ll5 In ll5 In ll5 In 159 Tb 165 Ho -181708.94 5032921.00 708218.94 22776726.00

1288200.40 451280.44 4525150.50 9055589.00 4705553.50 28881048.00 33012752.00 31604992.00 3.30 0.46 1.10 732360.19 3.88 18013604.00 0.72 1.18 3.87 1407958.90 475526.09 3640663.30 0.58 10055673.00 0.25 4993515.00 4.08 20883300.00 3.85 23533162.00 4.90 22278996.00 RSD(%)

5.44 105.32

2.69 1.24 13.77 3.51 189.68

8.98 4.15 3.63 3.31 6.96 2.17 0.42 2.54 2.59 5.05 2.46 6.22 3.95 5.00 4.66 6.86

4.90

7.93 6.13 6.60 8.06 5.64 6.53 2.80

4.23

Rec (%) 206.2

90.0 96.7 126.4 91.5 94.9 124.3 90.1 94.2 138.3 140.3 141.9 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

QC Range (%) Flag 70

- 120 IS Fai 70 120 70 120 70 120 IS Fai 70 120 70 120 70 120 IS Fai 70 70 70

- 70 70 120 120 120 IS Fai 120 IS Fai 120 IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#



### :Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 11:08 PM 

### Pass Fail :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study 

## Sample 10: RW-7 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 0.44 0.40 0.34 0.39 0.46 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67410

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12



# ..**~~~:~**

# ......._._...**_T_Ij_~.~~!~~.Q~!-)._._._._**

# ..._._.... _ .._._._.._ ..._ ..__**._~:~?** 

# _______________._...**_._~:~**

# _______________**.~9!~_**

# ..___..**~.~t~~!.~?_**

# ....._____**q~~?X~~. ?.** 

# ___

Form 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:03:27PMC.\ICPCIIEM\l\DATA\12126qOO .B\090SMPL.D\090SMPL.D#



### Sample QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I26qOO.B\090SMPL.D\090SMPL.Dn Sep 27 2012 02,27 am NBS Sample Name: BLK MDL O. 4 - 7 Mise Info: 120921A-1638 Vial Number, CUrrent Method, Calibration File: Last Cal Update, Sample Type, 3310 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Blements Element Cone. 

### Carr. Cone. nVALUE! 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.33 ug/l 12.13 ug/l 24.74 ug/l 23.68 ug/l

1.06 ug/l 41.07 ug/l -101.50 ug/l 0.31 ug/l 0.36 ug/l 0.38 ug/l -1.01 ug/l 3.44 ug/l 0.37 ug/l 0.27ug/l 0.47 ug/l 0.48 ug/l -2.43 ug/l 0.41 ug/l 0.50 ug/l 2.05 ug/l -0.09 ug/l -0.04 ug/l 0.33 ug/l ug/l 0.17 ug/l ug/l 0.37 ug/l -3.13 ug/l -3.28 ug/l -2.89 ug/l 0.35 ug/l 0.30 ug/l 0.35 ug/l ug/l ug/l 0.34 ug/l 0.33 12.13 24.74 23.68

1.06 41.07 -101.50 0.31 0.36 0.38 -1. 01 3.44 0.37 0.27 0.47 0.48 -2.43 0.41 0.50 2.05 -0.09 -0.04 0.33 nVALUE! 0.17 nVALUE! 0.37 -3.13 -3.28 -2.89 0.35 0.30 0.35 nVALUEI nVALUE! 0.34

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996 .50 3646344.80 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -104710.40 2768963.30 382155.50 13295464.00

693991.00 242890.73 2856965.00 5179731.00 2617901.80 19577700.00 24970244.00 24356580.00 2.82 1.09 0.96 537987.94 

## o .08 17012292.00 1.47 0.79 0.06 949396.31 338792.91 3456710.80 0.45 6610579.00 1.15 3651775.30 1.49 22769202.00 1.32 28649686.00 0.96 27453282.00 RSD (%)

1.12 3.61 2.72 3.26 16.50 11.69 2.96 21.62

1.95 16.78 6.97 10.73 4.50 11.47 0.86 6.22 2.49 12.47 4.64 19.84 13 .30 11.44 1.93

5.48

2.51 0.73 0.62 0.20 2.33 3.59 2.65

1.92

Rec(%)

79.3 75.9 71.0 78.2 73.1 71.7 82.6 78.4 71.7 86.0 87.2 88.7 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

# nnnnnnn 500 

# nnnnnnn 1000 

# nnnnnnn nnnnnnn 1000 1000 1000 1000 

# nnnnnnn nnnnnnn 1000

QC Range(%) 70

- 120 70

- 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70

- 70

- 70 70 70

- 120 120 120 120 120 Flag

Flag IS Fai 

# ",-r

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn

o :Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/271122:31 AM 

### Pass Failo ,Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHBM\1\rpttmp\Samp1e.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MOL Study Sample 10: RW-7 Sample Collection Date: 08/30/12

Method


## 200.8 200.8 200.8 200.8 Analyte


## ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) LEAD (PB) 

# Metals Analysis

Result


## 0.41 0.37 0.38 0.34 PQl Units


## 0.2 

## ug/L 0.2 

## ug/L 0.2 

## ug/L 0.2 ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67410

Prep Date Analysis Date


## 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 09/21/12 09/27/12 200.8 SELENIUM (SE) 0.50 0.2 ug/L 09/21/12 09/27/12



# __**~Q9:~**

# ______________**T_Ij_~_~~~~~_r~~1**

# _______________________________________**9:~?** 

# ___________. __.

__.

____**.Q:~_.**

# __________. ___**~9!~**

# ________**9.~!?~!.~?**

# ____. __.

__**9~~?X~~_ ?** 

# _____

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:01:18 PMC,\ICPCHEM\1\OATA\12I27.00.0\0475MPL.0\0475MPL.0#



### Sample QC Report

Data File: Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I27s00.B\047SMPL.D\047SMPL.D# Sep 27 2012 11,11 pm NBS BLK MDL 0.4-7 120921A-1638 Sample Name, 

### Mise Info: vial Number: Current Method:' 

### Calibration File: Last Cal Update, Sample Type, Prep oil Factor: 3310 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample 1.00 Total Dil Factor, 1.00

QC Elements 

### Element 7 (Li) 9 Be 

### 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Conc. ug/l 0.44 ug/l -0.18 ug/l 28.83 ug/l 29.62 ug/l 3.53 ug/l 36.50 ug/l 10.10 ug/l 0.40 ug/l 0.45 ug/l 0.34 ug/l 0.45 ug/l 7.76 ug/l 0.40 ug/l 0.39 ug/l 0.38 ug/l 0.37 ug/l 0.94 ug/l 0.44 ug/l 0.46 ug/l 2.05 ug/l 0.48 ug/l 0.37 ug/l 0.25 ug/l ug/l 0.19 ug/l ug/l 0.40 ug/l 0.34 ug/l 0.40 ug/l 0.28ug/1 0.39 ug/l 0.41 ug/l 0.37 ug/l ug/l ug/l 0.39 ug/l Carr. Conc. #VALUE! 0.44 -0.18 28.83 29.62 3.53 36.50 10.10 0.40 0.45 0.34 0.45 7.76 0.40 0.39 0.38 0.37 0.94 0.44 0.46 2.05 0.48 0.37 0.25 #VALUE! 0.19 #VALUE! 0.40 0.34 0.40 0.28 0.39 0.41 0.37 #VALUE! #VALUE! 0.39

Element CPS Mean RSD(%) Ref Value Li -170084.17 45 Sc 4968832.50 45 Sc 709009.69 45 Sc 21708042.00 1273538.40 453147.94 4370091.00 9076215.00 4720906.00 5.13 -88139.43 RSD(%) High Limit 

## o 4.84 1000 25.76 1000 4.22 25000 4.11 50000 16.88 20000 8.25 20000 24.72 50000 24.13 1000

1.98 1000 2.58 1000 3.98 1000 2.08 20000 1.29 1000 3.13 5.25 6.63 2.39 3.63 8.29 4.20 2.01 1.04 2.93

4.06

4.51 1.66 8.62 0.82 0.83 2.46 0.57

1.23

Rec(%)

193.0 88.9 96.8 120.5 90.5 95.3 120.0 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 70

- 120 70 120 70 120 70

- 120 70 120 70 120 70 120 70 120 70 120 70 120 Flag

Flag IS fai

IS Fai

IS Fai

IS Fai 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 27684634.00 31795818.00 30462428.00 0.79 5590061.50 0.79 732360.19 0.75 18013604.00 1.38 1407958.90 1.95 475526.09 0.46 3640663.30 0.88 10055673.00 1.33 4993515.00 0.50 20883300.00 0.33 23533162.00 1.24 22278996.00 90.3 94.5 132.6 135.1 136.7 70 70 120 IS Fai 120 IS Fai

ISTD Ref File ,


### :Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD:

912711211:15 PM C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#



### Pass Fail o :Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-1 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 1.5 0.46

1.1 2.0 

# 7.9 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67411

Prep Date Analysis Date
09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:01:18 PMC,\ICPCHEM\l\OATA\12I26QOO.s\069SMPL.O\069SMPL.oN



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12126qOO.B\069SMPL.D\069SMPL.D# Sep 27 2012 12:07 am Operator: NBS Sample Name: 1638 MDL-0.25-1 Mise Info: 120920A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3209 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element Cone. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.33 ug/l 31.71 ug/l 943100.00 ug/l 961700.00 ug/l 14.04 ug/l 54.12 ug/l 1987000.00 ug/l 0.49 ug/l 0.67 ug/l 1.15 ug/l -0.57 ug/l 14.64 ug/l O.71ug/l 4.18 ug/l 0.69 ug/l 1.09ug/l 0.09 ug/l 1.46 ug/l 7.91 ug/l 11.37 ug/l 125.00 ug/l 115.60 ug/l

0.60 ug/l ug/l 0.28 ug/l ug/l 0.46 ug/l -2.00 ug/l -2.18 ug/l -2.22 ug/l 2.42 ug/l 2.75 ug/l 0.40 ug/l ug/l ug/l 2.01 ug/l

ISTD Elements Carr. Cone. #VALUE! 0.33 31.71 943100.00 961700.00 14 .04 54.12 1987000.00 0.49 0.67 1.15 -0.57 14.64 0.71 4.18 0.69 1.09 0.09 1.46 7.91 11.37 125.00 115.60

0.60 #VALUE! 0.28 #VALUE! 0.46 -2.00 -2.18 -2.22 2.42 2.75 0.40 #VALUE! #VALUE! 2.01 RSD(%)

3.25 1.83 0.81 0.25 2.52 7.61 0.41 24.01 2.95 1.14 7.70 0.84 1.60 1.54 0.88 0.67 15.48 0.75 0.60 4.04 0.63 1.73 2.16

1.79

10.65 2.19 2.17 0.42 1.54 1.70 0.88

0.89 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

>Cal 

### :>Cal

,Cal

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Rec(%) 68.5 99.0 96.4 89.7 84.9 82.6 80.6 86.5 76.1 73.1 72 .4 72.5 QC Range (%) Flag 70 120 IS Fai

## ~ 6 Li -90381.13 3.39 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3608444.30 518700.31 15264073.00

806354.31 279748.41 2787681.80 5719383.00 2779431.80 16647595.00 20738282.00 19912326.00

ISTD Ref File :

:Element Failures

:ISTD Failures



### Data Results: Analytes: 

### ISTD:

9/2711212:11 AM 1.34 0.40 537987.94 0.27 17012292.00 1.06 949396.31 2.32 338792.91 0.25 3456710.80 0.92 6610579.00 1.03 3651775.30 0.64 22769202.00 0.82 28649686.00 0.47 27453282.00 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70 70

- 70 70 120 120 120 120 120 120 120 120 120 120 120
C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: 

## FGO-1 Sample Collection Date: 08/30/12

Method


## 200.8 200.8 200.8 Analyte


## ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) 

# Metals Analysis

Result


## 1.6 0.52

1.1 PQL


## 0.2 0.2 0.2 Units 

## ug/L ug/L ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603
APPL 10: AY67411

Prep Date Analysis Date


## 09/20/12 09/20/12 09/20/12 09/27/12 09/27/12 09/27/12 200.8 LEAD (PB) 2.4 0.2 ug/L 09/20/12 09/27/12 200.8 SELENIUM (SE) 1.1 0.2 ug/L 09/20/12 09/27/12**._~~9_·~**

# ____. _________**T_fj~_~~~~~_Q~~)**

# _______________________________________**9:~?** 

# _______________________**~:?**

# ________________**!-!9!~**

# ________**9_~!~9!_~?** 

# __________**g~~?X!~_ ?** 

# _____

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:03:27PMC,\ICPCHEM\l\DATA\12I27.00.B\025SMPL.D\025SMPL.D#



### Sample OC Report

Data File, Date Acquired, Operator, Sample Name: C,\ICPCHEM\1\DATA\12I27S00.B\025SMPL.D\025SMPL.Dn Sep 27 2012 08,44 pm NBS 1638 MDL-0.25-1 Mise Info: 120920A-1638 Vial Number: Current Method, Calibration File, Last Cal Update, Sample Type, 3209 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample Prep Dil Factor, 1.00 Total Dil Factor, 1.00

QC Blements Element 

### Cone. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.45 ug/l 3.62 ug/l 1013000.00 ug/l 1041000.00 ug/l 19.00 ug/l 52.61 ug/l 2257000.00 ug/l 0.62 ug/l 0.73 ug/l 1.13 ug/l 0.79 ug/l 22.16 ug/l 0.70 ug/l 4.41 ug/l 0.60 ug/l 0.91 ug/l 4.40 ug/l 1.55 ug/l 1.07 ug/l 3.28 ug/l 144.00 ug/l 131.40 ug/l

0.63 ug/l ug/l 0.32 ug/l ug/l 0.52 ug/l 1.53 ug/l 1.45 ug/l 0.98 ug/l 4.13 ug/l 3.03 ug/l 0.46 ug/l ug/l ug/l 2.35ug/l

ISTD Blements Element CPS Mean RSD(%) 

### Carr. Cone. nVALUE! 0.45 3.62 1013000.00 1041000.00 19.00 52.61 2257000.00 0.62 0.73 1.13 0.79 22.16

0.70 4.41 0.60 0.91 4.40 1.55 1.07 3.28 144.00 131.40

0.63 nVALUE! 0.32 nVALUE! 0.52 1.53 1.45 0.98 4.13 3.03 0.46 nVALUE! nVALUE! 2.35 RSD(%)

1.76 4.52 1.27 0.59 3.11 4.84 0.50 6.03 1.96 2.72 4.35 0.65 0.58 0.83 2.14 1.46 2.03 1.15 2.75 6.87 0.27 1.12 3.48

1.56

5.38 1.80 3.24 2.62 3.02 0.40 2.04

1.06 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

# nnnnnnn 500 

# nnnnnnn 1000 

# nnnnnnn nnnnnnn 1000 1000 1000 1000 

# nnnnnnn nnnnnnn 1000

QC Range (%) 6 Li -134885.36 4.47 45· Sc 5604948.50 0.40 Ref Value -88139.43 5590061.50 Rec(%) 153.0 100.3 119.7 114.1 70 120 70

- 120 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 876485.56 20558242.00

1212428.40 470575.81 3495994.30 8120078.00 4307361.50 18058296.00 18906474.00 17688424.00 1.74 732360.19 0.40 18013604.00 1.09 l407958.90 1.71 475526.09 0.61 3640663.30 0.08 10055673.00 1.004993515.00 0.67 20883300.00 0.35 23533162.00 0.58 22278996.00 86.1 99.0 96.0 80.8 86.3 86.5 80.3 79.4 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70 70 120 120 120 120 120 120 120 120 120 120 Flag

>Cal >Cal

>Cal

Flag IS Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12127S00.B\004CALB.D\004CALB.Dn

:Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD:

9/27/128:47 PM 

### Fail Fail :Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHBM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-2 Sample Collection Date: 

## 08/30/12

Method


## 200.8 200.8 200.8 Analyte


## ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) 

# Metals Analysis

Result


## 1.4 0.44

1.1 POL


## 0.2 0.2 0.2 Units 

## ug/L ug/L ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67412

Prep Date Analysis Date


## 09/20/12 09/20/12 09/20/12 09/27/12 09/27/12 09/27/12 200.8 LEAD (PB) 2.0 0.2 ug/L 09/20/12 09/27/12 200.8 SELENIUM (SE) 5.6 0.2 ug/L 09/20/12 09/27/12



# ..**~~9:~**

# ......._ ......**"!".~.~.~~~~~J~~)._._._**

# ..._ .._.__._._......_ ...._ .._

....**9:~~.**

# __. ___.........._ .....**~:?**

# ...............**~9!~**

# ........**9.~!?9!.~?**

# ..........**9~~?X(~. ~** 

# __._.

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:01:18 

### PMC,\ICPCHEM\l\DATA\12I26qOO.B\OHSMPL.D\OHSHPL.**D~**


### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, 

### Mise Info: C,\ICPCHEM\1\DATA\12I26qOO.B\074SMPL.D\074SMPL.D# Sep 27 2012 12,40 am NBS 1638 MDL-0.25-2 120920A-1638 Vial Number, CUrrent Method, 

### Calibration File: Last Cal Update, Sample Type, 3210 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element 

### Cone. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.34 ug/l 25.72 ug/l 890600.00 ug/l 910300.00 ug/l 13.64 ug/l 54.37 ug/l 1886000.00 ug/l 0.49 ug/l 0.56 ug/l 1.09 ug/l -0.72 ug/l 27.26 ug/l 0.68 ug/l 2.34 ug/l 0.67 ug/l 1.03 ug/l -0.95 ug/l 1.37 ug/l 5.64 ug/l 9.46 ug/l 119.30 ug/l 118.10 ug/l

0.59 ug/l ug/l 0.29 ug/l ug/l 0.44 ug/l -2.31 ug/l -2.49 ug/l -2.38 ug/l 2.01 ug/l 2.81 ug/l 0.39 ug/l ug/l ug/l 2.01 ug/l

ISTD Elements Element CPS Mean RSD(%) 

### Carr. Cone. #VALUE! 0.34 25.72 890600.00 910300.00 13 .64 54.37 1886000.00 0.49 0.56 1.09 -0.72 27.26 0.68 2.34 0.67 1.03 -0.95 1.37 5.64 9.46 119.30 118.10

0.59 #VALUE! 0.29 #VALUE! 0.44 -2.31 -2.49 -2.38 2.01 2.81 0.39 #VALUE! #VALUEl 2.01 RSD(%) High Limit 

## o 21.99 1000 16.42 1000 0.38 25000 0.32 50000 2.14 20000 6.76 20000 0.40 50000 8.25 1000 0.22 1000 2.48 1000 4.13 1000 0.54 20000 2.42
1.96 5.28 2.44 2.45 3.02 2.04 1.68 0.46 19.26 18.99

18.29

15.63

1.19 2.70 5.28 19.01 21.17 18.25

19.97 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range (%) 6 Li -89182.19 15.79 45 Sc 3628762.00 0.21 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 511291.09 14300611.00

807285.25 278891.25 2708812.50 5715730.00 2736030.00 0.40 Ref Value -131996.50 3646344.80 537987.94 Rec (%) 67.6 99.5 95.0 84.1 85.0 82.3 78.4 86.5 74.9 69.6 68.7 68.8 70

- 120 70

- 120 70

- 120

15838820.00 19674946.00 18891008.00 16.25 17012292.00 0.26 949396.31 0.41 12.20 0.56 0.34 338792.91 3456710.80 6610579.00 3651775.30 16.56 22769202.00 17.00 28649686.00 16.78 27453282.00 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70 120 120 120 120 120 120 120 120 120 Flag

>Cal >Cal

>Cal

Flag IS Fai

IS Fai 

# '7Oil...
IS Fai IS Fai 

## rJ\'

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures 4 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 12:44 AM 

### Fail Failo :Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C,\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study 

## Sample 10: FGO-2 Sample Collection Date: 08/30/12

Method Analyte

200.8 

## ARSENIC (AS) 200.8 

## CADMIUM (CD) 200.8 

## CHROMIUM (CR) 200.8 

## LEAD (PB) 200.8 

## SELENIUM (SE) 

# Metals Analysis

Result
1.5 0.51

1.1 2.2 

## PQL

0.2 0.2 0.2 0.2 0.94 0.2 

## Units ug/L ug/L ug/L ug/L ug/L APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 

## 10: AY67412

Prep Date Analysis Date
09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12



# ..**~~9:~**

# ..............**T.Ij.~.~!:~~~.{~~)**

# .......................................**9:~?** 

# .....................**~:?**

# ................**~9!!:**

# ........**9.~!?:9!.~?**

# ..........**9~~?X~~ .?** 

# ....

Form 

## 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:03:27PMC,\ICPCHEK\l\OATA\12I27.00.**B\026SIlP~. O\026SIIP~.**  0#



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27s00.B\026SMPL.D\026SMPL.DU Sep 27 2012 08:50 pm Operator: NBS Sample Name: 1638 MDL-0.25-2 Mise Info: 120920A-1638 Vial Number: CUrrent Method: Calibration File: Last Cal Update: 3210 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element Cone. 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.41 ug/l 3.10 ug/l 960700.00 ug/l 978300.00 ug/l 16.86 ug/l 52.17 ug/l 2161000.00 ug/l 0.55 ug/l 0.70 ug/l 1.12 ug/l 0.77 ug/l 34.45 ug/l 

## o .70 ug/l 2.70 ug/l 0.56 ug/l 0.88 ug/l 2.73 ug/l 1.47 ug/l 0.94 ug/l 3.45 ug/l 137.60 ug/l 123.90 ug/l

0.55 ug/l ug/l 0.30 ug/l ug/l 0.51 ug/l 1.00 ug/l 1.09 ug/l 0.69 ug/l 3.55ug/l 2.93 ug/l 0.42 ug/l ug/l ug/l 2.15 ug/l

ISTD Blements Carr. Cone. UVALUE! 0.41 3.10 960700.00 978300.00 16.86 52.17 2161000.00 0.55 0.70 1.12 0.77 34.45 0.70 2.70 0.56 0.88 2.73 1.47 0.94 3.45 137.60 123.90

0.55 UVALUE! 0.30 UVALUE! 0.51 1.00 1.09 0.69 3.55 2.93 0.42 UVALUE! UVALUE! 2.15 RSD(%) High Limit 

## o 1.50 1000 3.47 1000 1.33 25000 1.57 50000 5.29 20000 3.31 20000 2.21 50000 3.51 1000 3.72 1000 2.72 1000 4.20 1000 1.95 20000 1.95 1000 2.06 3.21 4.75 1.70 1.10 0.94 7.87 0.44 1.16 5.69

1.19

7.91 1.50 3.17 3.12 0.51 0.24 1.66

0.72 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000 Flag

,Cal ,Cal

,Cal

Element CPS Mean RSD(%) Ref Value -88139.43 Rec(%) 146.2 102.6 113.9 113.7 QC Range(%) Flag Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -128835.28 5736286.00

834298.63 20490146.00

1247538.10 449871.63 3498658.50 8426690.00 4174665.50 18333754.00 19561808.00 18245612.00 1.25 1.30 5590061.50 1.78 732360.19 0.73 18013604.00 1.681407958.90 1.26 475526.09 0.57 3640663.30 0.82 10055673.00 1.06 4993515.00 0.54 20883300.00 0.72 23533162.00 0.98 22278996.00 88.6 94.6 96 .1 83.8 83.6 87.8 83.1 81. 9 70 120 IS fai 70

- 120 70 120 70 120 70 120 70 70 70 70 70 70 70 120 120 120 120 120 120 120

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.DU

:Element Failures 0 :Max. Number of Failures Allowed :ISTD Failures 0 :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9127112 8:54 PM C'\ICPCHEM\l\rptbmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-3 Sample Collection Date: 08/30/12

Method
200.8 200.8 200.8 

## Analyte
ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) 

# Metals Analysis

Result


## 1.3 0.42



## 1.1 POL
0.2 0.2 0.2 

## Units ug/L ug/L ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67413

Prep Date Analysis Date
09/20/12 09/20/12 09/20/12 09/27/12 09/27/12 09/27/12 200.8 LEAD (PB) 1.9 0.2 ug/L 09/20/12 09/27/12 200.8 SELENIUM (SE) 5.7 0.2 ug/L 09/20/12 09/27/12**_~~9_·~**

# ______________**~_1:l_~_~!:~~~_C'~~)**

# _______________________________________**9:~?** 

# _______________________**~:?**

# ________________**~9!_~**

# ________**9_~!?9L~?** 

# ___________**Q~~?X!~ _?** 

# _____

Form 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:01:18

### PMC,\ICPCHEM\l\DATA\12I26qOO.S\075SHPL.D\075SHPL.DO



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\075SMPL.D\075SMPL.D# Sep 27 2012 12:47 am Operator: NBS Sample Name: 1638 MDL-0.25-3 Mise Info: 120920A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3211 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element Cone. Carr. Cone. #VALUE! 0.32 19.60 910500.00 924600.00 13.54 64.79 (Li) Be 11 B 23 Na 24 Mg 27 Ai 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.32 ug/l 19.60 ug/l 910500.00 ug/l 924600.00 ug/l 13.54 ug/l 64.79 ug/l 1926000.00 ug/l 0.45 ug/l 0.59 ug/l 1.14 ug/l -0.70 ug/l 13.71 ug/l 0.69 ug/l 7.59 ug/l 0.69 ug/l 1.08 ug/l 0.93 ug/l 1.31 ug/l 5.71 ug/l 11.01 ug/l 121.70 ug/l 111.80 ug/l

0.53 ug/l ug/l 0.28 ug/l ug/l 0.42 ug/l -2.72 ug/l -2.65 ug/l -2.55 ug/l 1.74 ug/l 2.71 ug/l 0.36 ug/l ug/l ug/l 1.90 ug/l 1926000.00 0.45 0.59 1.14 -0.70 13.71 0.69 7.59 0.69 1.08 0.93 1.31 5.71 11.01 121.70 111.80

0.53 #VALUE! 0.28 #VALUEI 0.42 -2.72 -2.65 -2.55 1.74 2.71 0.36 #VALUE I #VALUEI 1.90

ISTD Elements Element CPS Mean RSD(%) Ref Value 6 Li -89139.98 8.74 -131996.50 45 Sc 4423724.00 17.42 3646344.80 45 Sc 497981.81 1.37 537987.94 45 Sc 15238093.00 0.55 17012292.00 72 Ge 931605.75 13.14 949396.31 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 273502.31 2800274.30 6909247.50 2661074.00 16803858.00 21087884.00 20193890.00 2.70 338792.91 0.53 3456710.80 17.80 6610579.00

1.80 3651775.30 1.12 22769202.00 0.89 28649686.00 0.62 27453282.00 RSD(%)

0.68 0.58 0.58 0.43 12.08 4.18 0.70 16.48

1.00 2.40 5.06 0.92 2.81 1.89 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 4.73 1000 1.62 1000 4.05 1000 1.59 1000 13.83 1000 6.38 1000 0.78 1000 1.51 1000 4.18 1000 ####### 1.59 500 ####### 7.00 1000 5.66 ####### 1.33 ####### 0.57 1000 1.41 1000 0.90 1000 1.37 1000 ####### ####### 1.43 1000

Rec(%)

67.5 121.3 92.6 89.6 98.1 80.7 81.0 104.5 72 .9 73.8 73.6 73.6 QC Range(%) 70

- 120 70

- 120 70 120 70

- 120 70

- 120 70

- 120 70 120 70 120 70

- 120 70 120 70 120 70 120 Flag

>Cal >Cal

>Cal

Flag IS Fai IS Fai

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures :Max. Number of Failures Allowed :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/27112 12:50 AM C:\ICPCHEM\l\rpttrnp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-3 

## Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 200.8 CADMIUM (CD) 200.8 CHROMIUM (CR) 

# Metals Analysis

Result PQl Units


## 1.5 0.2 ug/L 0.53 0.2 ug/L

1.1 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67413

Prep Date Analysis Date


## 09/20/12 09/20/12 09/27/12 09/27/12 09/20/12 09/27/12 200.8 LEAD (PB) 2.2 0.2 ug/L 

## 09/20/12 09/27/12 200.8 SELENIUM (SE) 0.99 0.2 ug/L 

## 09/20/12 09/27/12**_~~9_·~**

# ______________**T_Ij~_~~~~~_Q~~)**

# _______________________________________**9:~~** 

# _______________________**~·?**

# _______________**~g!~**

# ________**9_~!~9!_~?** 

# ___________**q~~?X!~_?**

# _____

Form 

### 1 - APPL Standard Metals

- No 

# Me
Printed: 101011125:03:27PMc:\ICPCIlEM\l\OATA\12I27s00 .B\027SMPL.O\027SMPL.of



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27S00.B\027SMPL.D\027SMPL.D# Sep 27 2012 08:57 pm Operator: NBS Sample Name: 1638 MDL-0.25-3 Mise Info: 120920A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3211 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element Conc. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.42 ug/l 2.43 ug/1 963800.00 ug/l 984800.00 ug/l 17.86 ug/l 63.19 ug/l 2205000.00 ug/l O.71ug/l 0.75 ug/l 1.14 ug/l 0.77 ug/l 20.98 ug/l 0.70 ug/l 7.71ug/l 0.60 ug/l 0.97 ug/l 4.97 ug/l 1.52 ug/l 0.99 ug/l 3.83 ug/l 141.50 ug/l 126.40 ug/l

0.52 ug/l ug/l 0.31 ug/l ug/l 0.53 ug/l 0.91 ug/l 0.95 ug/l 0.62 ug/l 3.23 ug/l 3.01 ug/l 0.43 ug/l ug/l ug/l 2.20 ug/l

ISTD Elements Carr. Cone. #VALUEI 0.42 2.43 963800.00 984800.00 17.86 63.19 2205000.00 0.71 0.75 1.14 0.77 20.98 0.70 7.71 0.60 0.97 4.97 1.52 0.99 3.83 141.50 126.40

0.52 #VALUEI 0.31 #VALUEI 0.53 0.91 0.95 0.62 3.23 3.01 0.43 #VALUEI #VALUEI 2.20 RSD(%) High Limit 

## a 1.47 1000 1.14 1000 0.55 25000 0.84 50000 2.37 20000 3.00 20000 0.25 50000 3.67 1000 3.65 1000 1.13 1000 0.78 1000 0.36 20000 2.59 0.74 0.95 2.13 1.10 2.16 4.07 5.25 0.58 1.91 1.67

3.14

4.77 3.87 3.01 0.94 1.38 1.65 2.27

0.84 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

>Cal >Cal

>cal

Element CPS Mean RSD(%) Ref Value -88139.43 Rec(%) 140.2 100.4 112.1 112.6 QC Range (%) Flag Li -123561.20 2.59 45 Sc 45 Sc 45 sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 5614797.00 820963.94 20275090.00

1223584.40 440852.72 3472048.80 8208808.50 4068804.80 18436316.00 19359424.00 18018564.00 1.34 5590061.50 1.26 732360.19 1.13 18013604.00 0.75 1407958.90 0.92 475526.09 0.34 3640663.30 0.53 10055673.00 1.01 4993515.00 1.24 20883300.00 0.36 23533162.00 0.19 22278996.00 86.9 92.7 95.4 81. 6 81.5 88.3 82.3 80.9 70 120 IS Fai 70

- 120 70

- 120 70

- 120 70

- 120 70 120 70 70 70 70 70 70 120 120 120 120 120 120

ISTD Ref File: C:\ICPCHEM\1\DATA\12127s00.B\004CALB.D\004CALB.D#

3 :Element Failures :Max. Number of Failures Allowed 1 :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/271129:01 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-4 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 1.3 0.45

1.2 1.9 6.8 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67414

Prep Date Analysis Date

09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12



# __**~Q9_·~**

# ______________**T_fj_~_~~~l!~_cr~~)**

# _______________________________________**9:~?** 

# _______________________**Q:~**

# ________________**~9!~**

# ________**9_~t?:9!_~?** 

# ___________**9~~?X( ~_?** 

# _____

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:01:18 

### PM

### c:\ICPCIIEM\l\DATA\12I26qOO.B\076SMPL.D\076SMPL.DI



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\076SMPL.D\076SMPL.D# Sep 27 2012 12:53 am Operator: NBS Sample Name: 1638 MDL-0.25-4 Mise Info: 120920A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3212 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Element. Element (Li) Cone. ug/l 0.29 ug/l 18.48 ug/l 897400.00 ug/l 908600.00 ug/l 12.90 ug/l 68.26 ug/l Corr. Cone. #VALUE! 0.29 18.48 897400.00 908600.00 12.90 68.26 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb 1902000.00 ug/l 0.55 ug/l 0.63 ug/l 1.15 ug/l -0.74 ug/l 13.97 ug/l 0.70 ug/l 4.07 ug/l 0.65 ug/l 1.04 ug/l 0.40 ug/l 1.34 ug/l 6.82 ug/l 10.40 ug/l 120.80 ug/l 110.40 ug/l

0.51 ug/l ug/l 0.28 ug/l ug/l 0.45ug/1 -2.70 ug/l -2.83 ug/l -2.61 ug/l 1.68 ug/l 2.71 ug/l 0.37 ug/l ug/l ug/l 1.92 ug/l 1902000.00 0.55 0.63 1.15

- 0.74 13.97 0.70 4.07 0.65 1.04 0.40 1.34 6.82 10.40 120.80 110.40

0.51 #VALUE! 0.28 #VALUE! 0.45 -2.70 -2.83 -2.61 1.68 2.71 0.37 #VALUE! #VALUE! 1.92

ISTD Element. Element CPS Mean RSD (%) Ref Value -131996.50 Li 45 Sc 45 Sc 45 SC 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -80795.81 3731903.00

501592.44 14162061.00

831037.63 275335.19 2626549.30 5791835.00 2694596.30 15886792.00 20053700.00 19337210.00 6.67 1.24 3646344.80 0.56 537987.94 2.19 17012292.00 1.02 0.41 949396.31 338792.91 1.60 3456710.80 0.18 6610579.00 

## o.59 3651775.30 1.51 22769202.00 1.40 28649686.00 1.61 27453282.00 RSD(%)

3.66 7.82 0.16 0.87 6.04 7.28 0.62 11.26 2.20 0.77 0.61 2.23 3.65 1.98 1.94 2.30 26.53 2.32 2.17 3.71 1.00 0.58 2.57

3.12

6.63 1.23 1.53 0.45 2.58 0.42 0.68

0.77

Rec(%)

61.2 102.3 93.2 83.2 87.5 81.3 76.0 87.6 73.8 69.8 70.0 70.4 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range (%) 70

- 120 70

- 120 70

- 120 70

- 120 70

- 70

- 70 70

- 70

- 70

- 70 70 120 120 120 120 120 120 120 120 Flag

,Cal >Cal

,Cal

Flag IS Fai

IS Fai IS fai

ISTD Ref File: C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D#

:Element Failures 0 :Max. Number of Failures Allowed

:ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail 

## ,J\

9127/12 12:57 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-4 

## Sample Collection Date: 08/30/12

Method
200.8 200.8 200.8 Analyte
ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) 

# Metals Analysis

Result
1.5 0.51

1.1 PQl Units
0.2 ug/L 0.2 ug/L 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: 

## AY67414

Prep Date
09/20/12 09/20/12 09/20/12 Analysis Date
09/27/12 09/27/12 09/27/12 2.1 0.2 ug/L 09/20/12 200.8 LEAD (PB) 09/27/12 200.8 SELENIUM (SE) 0.98 0.2 ug/L 09/20/12 09/27/12



# ..**~~9:~**

# ..............**T.I:I~.~~~~~.Q~~)**

# ......................................**g:~~**

# .......................**~~?**

# ...............**~9!~**

# ........**9.~!~9!.~?**

# ..........**q~~?X!~_~**

# .....

Form 1 - APPL Standard Metals

- No 

## Me Printed: 10/011125:03:27

### PMC.\ICPCHEK\l\DATA\12127000.B\Ol2SMPL.D\Ol2SMPL.D#



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27S00.B\032SMPL.D\032SMPL.D# Sep 27 2012 09:30 pm Operator: NBS Sample Name: 1638 MDL-0.25-4 Mise Info: 120920A-1638 Vial Number: Current Method: Calibration File: Last Cal Update: 3212 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep Oil Factor: 1.00 Total Oil Factor: 1.00

QC Elements 

### Element Cone. 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 MIl 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) III Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb ug/l 0.44 ug/l 2.84 ug/l 930000.00 ug/l 958400.00 ug/l 16.82 ug/l 68.45 ug/l 2180000.00 ug/l 0.58 ug/l 0.74 ug/l 1.12 ug/l 0.76 ug/l 20.34 ug/l

0.70 ug/l 4.26 ug/l 0.54 ug/l 0.86 ug/l 4.25 ug/l 1.48 ug/l 0.98 ug/l 4.08 ug/l 138.40 ug/l 122.10 ug/l

0.50 ug/l ug/l 0.30 ug/l ug/l 0.51 ug/l 0.97 ug/l 1.04 ug/l 0.62 ug/l 2.62 ug/l 2.92 ug/l 0.41 ug/l ug/l ug/l 2.12 ug/l

ISTD Elements Carr. Cone. #VALUEI 0.44 2.84 930000.00 958400.00 16.82 68.45 2180000.00 0.58 0.74 1.12 0.76 20.34 0.70 4.26 0.54 0.86 4.25 1.48 0.98 4.08 138.40 122.10

0.50 #VALUEI 0.30 #VALUEI 0.51 0.97 1.04 0.62 2.62 2.92 0.41 #VALUEI #VALUEI 2.12 RSD(i)

1.21 5.26 1.30 1.21 5.86 2.73 1.35 17.80 2.32 0.83 4.73 1.10 1.91 1.30 2.18 1.68 3.28 2.70 12.95 0.43 0.89 1.42 3.00

4.15

3.12 20.53 4.73 2.10 2.71 1.57 1.24

1.24 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

>Cal >Cal

>Cal

Element CPS Mean RSD(i) Ref Value -88139.43 5590061.50 Rec (i) 146.4 93.2 105.7 111.6 83.2 88.6 94.7 76.8 78.4 88.8 84.4 83.2 QC Range (i) Flag Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -129059.02 2.45 5208575.50 13.65 70 120 IS Fai 70 120 773885.31 20102064.00

1171146.40 421478.94 3447134.50 7718151.50 3917239.80 18534298.00 19872700.00 18526108.00

ISTD Ref File :

3 :Element Failures

: ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 9:34 PM 2.96 732360.19 1.06 18013604.00 6.10 1407958.90 1.95 475526.09 0.903640663.30 12.57 10055673.00 2.14 4993515.00 0.81 20883300.00 0.96 23533162.00 0.45 22278996.00 70

- 70

- 70 70

- 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120 120

C:\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#



### Fail Fail o :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MOL Study Sample 10: FGO-5 

## Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 1.3 0.47

1.1 2.0 6.3 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 APPL 10: AY67415

Prep Date Analysis Date


## 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12



# ..**~Q9:~**

# ..............**TtI.~~~~~~.Q~~)**

# .......................................**9:~9** 

# .......................**Q:~**

# ................**~9!~**

# ........**9.~!~9!.~?** 

# .........**Q~~?X!~.?**

# .....

Form 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:01:18

### PMC,\ICPCHEM\l\DATA\12126qOO.B\077SKPL.D\077SKPL.**D~**


### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\077SMPL.D\077SMPL.D# Sep 27 2012 01:00 am Operator: NBS Sample Name: 1638 MDL-0.25-5 

### Mise Info: 120920A-1638 

### Vial Number: CUrrent Method: Calibration File: Last Cal Update: 3301 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: prep Dil Factor: Sample 1.00 Total Dil Factor: 1.00

QC Elements 

### Element Cone. (Li) Be 11 B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 cu 65 CU 66 

## zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.33 ug/l 17.13 ug/l 891800.00 ug/l 908300.00 ug/l 14.48ug/l 67.26 ug/l 1930000.00 ug/l 0.58 ug/l 0.62 ug/l 1.13 ug/l -0.78 ug/l 17.43 ug/l 0.72 ug/l 1.91 ug/l 0.64 ug/l 1.02 ug/l -1.08 ug/l 1.34 ug/l 6.32 ug/l 9.93 ug/l 123.10 ug/l 116.40 ug/l

0.53 ug/l ug/l 0.29ug/l ug/l 0.47 ug/l -2.69 ug/l -2.86 ug/l -2.57 ug/l 1.72 ug/l 2.85 ug/l 0.40 ug/l ug/l ug/l 2.05 ug/l

ISTD Elements Element CPS Mean RSD(%) Li -68437.67 9.55 45 Sc 3418180.80 1.82 1.58 Cerr. Cone. #VALUEI 0.33 17.13 891800.00 908300.00 14 .48 67.26 1930000.00 0.58 0.62 1.13 -0.78 17.43 0.72 1.91 0.64 1.02 -1.08

1.34 6.32 9.93 123.10 116.40

0.53 #VALUE! 0.29 #VALUE! 0.47 -2.69 -2.86 -2.57 1.72 2.85 0.40 #VALUE! #VALUEI 2.05

Ref Value -131996.50 3646344.80 537987.94 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 489458.69 12373311.00

769181.13 269453.91 2360199.80 5336500.00 2624859.50 5.10 17012292.00

14227306.00 18279216.00 17522862.00 0.93 949396.31 0.76 338792.91 3.23 3456710.80 0.89 6610579.00 0.70 3651775.30 5.04 22769202.00 4.52 28649686.00 4.49 27453282.00 RSD(%)

2.11 3.84 1.62 1.87 5.61 8.17 1.59 6.64 9.78 2.95 2.67 3.11 2.26 1.95 3.73 6.46 12.23 2.61 0.89 3.37 0.24 4.13 2.92

6.11

4.11 1.60 2.68 2.66 4.14 2.69 0.94

4.12

Rec(%)

51. 8 93.7 91.0 72.7 81.0 79.5 68.3 80.7 71.9 62.5 63.8 63.8 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 70

- 120 70

- 120 70 120 70 70 70 70 70 70 70

- 70 70 120 120 120 120 120 120 120 120 120 Flag

,Cal ,Cal

,Cal

Flag IS Fai

IS Fai

IS Fai IS Fai IS Fai

ISTD Ref File, C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures 5 :ISTD Failures



### Data Results: Analytes: 

### ISTD: Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed 

### (pc)

# -11

...\ 

# i. '/' OV--

# ~.-rs ,.1-'1

9127112 1'04 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

# Metals Analysis

CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 

## 10: FGO-5 Sample Collection Date: 08/30/12

Method Analyte Result


## 200.8 ARSENIC (AS) 1.5 

## 200.8 CADMIUM (CD) 

## 0.49 200.8 CHROMIUM (CR) 1.1 

## 200.8 LEAD (PB) 

## 2.0 200.8 SELENIUM (SE) 

## 0.96 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67415

Prep Date Analysis Date

09/20/12 09/20/12 09/20/12 09/20/12 09/27/12 09/27/12 09/27/12 09/27/12 09/20/12 09/27/12



# __**~Q9:~**

# ______________**T_~_~_~~~~f>J1_Q~~)**

# _______________________________________**9:~9** 

# _______________________**Q:~**

# ________________**~g!~**

# ________**9_~!?9!_~?** 

# ___________**Q~~?X!~_~**

# _____

Form 

### 1 - APPL Standard Metals

- No 

# Me
Printed: 101011125:03:27

### PMC,\ICPCHEM\l\DATA\12I27s00.S\OJJSMPL.D\OJJSMPL**.D~**


### Sample QC Report

Data File: Date Acquired, Operator, Sample Name, Mise Info: C,\ICPCHEM\1\DATA\12I27S00.B\033SMPL.D\033SMPL.D# Sep 27 2012 09,37 pm NBS 1638 MDL-0.25-5 120920A-1638 Vial Number: CUrrent Method, Calibration File: Last Cal Update, Sample Type, 3301 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Blements Element (Li) 

### done. ug/l 0.41 ug/l 2.60 ug/l 942100.00 ug/l 967000.00 ug/l 17.80 ug/l Be II B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) III Cd ll8 Sn ll8 Sn ll8 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 64.03 ug/l 2193000.00 ug/l 0.65 ug/l 0.76 ug/l loll ug/l 0.74 ug/l 23.53 ug/l 0.70 ug/l 2.12 ug/l 0.54 ug/l 0.89 ug/l 2.61 ug/l 1.47 ug/l 0.96 ug/l 4.11 ug/l 140.50 ug/l 116.20 ug/l

0.46 ug/l ug/l 0.28 ug/l ug/l 0.49 ug/l 0.89 ug/l 0.89 ug/l 0.53 ug/l 2.51 ug/l 2.83 ug/l 0.40 ug/l ug/l ug/l 2.04 ug/l

ISTD Elements Element CPS Mean RSD(%) Li -128832.59 1.74 45 Sc 5199ll9.00 0.51 Carr. Cone. #VALUE! 0.41 2.60 942100.00 967000.00 17.80 64.03 2193000.00 0.65 0.76 1.11 0.74 23.53 0.70 2.12 0.54 0.89 2.61 1.47 0.96 4.ll l40.50 ll6.20

0.46 #VALUE! 0.28 #VALUE! 0.49 0.89 0.89 0.53 2.51 2.83 0.40 #VALUE! #VALUE! 2.04

Ref Value -88139.43 5590061.50 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 772689.38 20202606.00

ll34833.50 1.59 732360.19 5.53 18013604.00

413190.78 3420337.80 7713857.50 3885233.30 19070764.00 20546552.00 19237108.00 0.87 1407958.90 1.86 475526.09 0.81 3640663.30 0.70 10055673.00 1.28 4993515.00 3.08 20883300.00 3.87 23533162.00 4.03 22278996.00 RSD(%) High Limit 

## o 3.30 1000 18.26 1000 0.84 25000 0.78 50000 4.69 20000 5.20 20000 0.77 50000 16.63 1000

1.48 1000 1.79 1000 1.59 1000 1.06 20000 0.76 1.48 2.96 5.39 4.91 0.22 2.37 3.41 0.04 2.41 6.12

3.14

8.36 3.36 4.96 10.78 3.08 4.39 2.89

3.07 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) Rec (%)

146.2 93.0 105.5 112.2

80.6 86.9 93.9 76.7 77.8 91.3 87.3 86.3 70 120 70

- 120 70 120 70 120 70 120 70

- 70 70

- 70

- 70 70

- 70 120 120 120 120 120 120 120 Flag

>Cal >Cal

>Cal

Flag IS Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

:Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/271129:41 PM 

### Fail Fail ,Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C,\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MOL Study Sample 10: FGO-6 

## Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 lEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 1.4 0.53

1.2 2.0 6.0 PQl Units


## 0.2 ug/l 

## 0.2 ug/l 

## 0.2 ug/l 

## 0.2 ug/l 

## 0.2 ug/l 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: 

## AY67416

Prep Date Analysis Date
09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12



# ..**~~9:~**

# ......________**T_I:I~_~~~~~_C~~)**

# _______________________________________**9:~?** 

# ________. __.

___. _______**~:~._.**

# _________. ___**~9!~**

# __. _____**9_~!?_.9!.~?** 

# ___________**Q~~?X!~_?**

# _____

Form 

### 1 - APPL Standard Metals

- No 

## Me Printed: 101011125:01:18PMC.\ICPCHEM\1\DATA\ 12I26qOO.B\07BSMPL. D\07BSMPL.01



### Sample QC Report

Data File: Date Acquired: C,\ICPCHEM\1\DATA\12I26qOO.B\078SMPL.D\078SMPL D# Sep 27 2012 01:06 am Operator: Sample Name. Mise Info: NBS 1638 MDL-0.25-6 120nOA-1638 Vial Number: CUrrent Method, Calibration File: Last Cal Update, Sample Type, 3302 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element Cone. 

### Cerro Cone. #VALUEI 0.34 14.08 894700.00 906400.00 14 .75 83.17 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag lOB (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.34 ug/l 14.08 ug/l 894700.00 ug/l 906400.00 ug/l 14.75 ug/l 83.17 ug/l 1927000.00 ug/l 0.57 ug/l 0.70 ug/l 1.18 ug/l -0.77 ug/l 16.28 ug/l 0.86 ug/l 2.08 ug/l 0.67 ug/l 1.07 ug/l -1.19 ug/l

1.40 ug/l 5.98 ug/l 10.15 ug/l 123.30 ug/l 113.70 ug/l

0.55 ug/l ug/l 0.30 ug/l ug/l 0.53 ug/l -2.69 ug/l -2.84 ug/l -2.59 ug/l 1.57 ug/l 2.84 ug/l 0.42 ug/l ug/l ug/l 2.02 ug/l 1927000.00 0.57 0.70 1.18 -0.77 16.28 0.86 2.08 0.67 1.07 -1.19 1.40 5.98 10.15 123.30 113.70

0.55 #VALUEI 0.30 #VALUEI 0.53 -2.69 -2.84 -2.59 1.57 2.84 0.42 #VALUEI #VALUEI 2.02

ISTD Elements Element CPS Mean RSD (%) Ref Value -131996.50 3646344.80 6 Li -78978.44 33.21 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3411907.00 467452.09 14293704.00

752096.63 259763.64 2571415.80 5370700.50 2536029.30 0.90 1.37 537987.94 36.57 17012292.00 0.83 949396.31 0.50 338792.91 27.15 3456710.80 0.46 6610579.00 1.12 3651775.30 16308394.00 37.2B 22769202.00 21095204.00 38.57 28649686.00 20412764.00 39.12 27453282.00 RSD(%)

36.34 35.72 2.01 2.04 8.93 5.87 1.37 17.68 0.78 2.30 5.40 3.60 24.28

2.06 5.06 5.11 10.73

1.69 2.56 1.84 0.73 37.36 38.27

38.15

42.20

1.20 1.85 9.29 37.16 37.60 38.79

37.87

Rec(%)

59.8 93.6 86.9 84.0 79.2 76.7 74.4 81.2 69.4 71.6 73.6 74.4 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 70

- 120 70

- 120 70

- 120 70

- 120 70 120 70 120 70

- 120 70

- 120 70 120 70 120 70

- 120 70

- 120 Flag



### >Cal >Cal

>Cal

Flag IS Fai

IS Fai

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures :Max. Number of Failures Allowed :ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/27/121:10 AM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-6 

## Sample Collection Date: 08/30/12

Method
200.8 200.8 200.8 

## Analyte
ARSENIC (AS) CADMIUM (CD) CHROMIUM (CR) 

# Metals Analysis

Result


## 1.7 0.55

1.2 PQL


## 0.5 0.2 

## 0.5 Units ug/L ug/L ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: 

## AY67416

Prep Date Analysis Date
09/20/12 09/20/12 09/20/12 09/27/12 09/27/12 09/27/12 200.8 LEAD (PB) 2.2 0.2 ug/L 09/20/12 09/27/12 200.8 SELENIUM (SE) 1.1 1.0 ug/L 09/20/12 09/27/12

# .~~9:~

# ..............**T.Ij.~.~~~~~.C~~)**

# .......................................**9:~?** 

# .....................**~:?**

# ................**~9!~**

# ........**9.9!?9!.~?**

# ..........**~~~?X!~. ?**  

# ....

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:03:27

### PMC,\ ICPCHEM\1\OATA\12Il7.00.B\034SMPL.O\034SMPL.OH



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27S00.8\034SMPL.D\034SMPL.DU sep 27 2012 09:44 pm Operator: N8S Sample Name: 1638 MDL-0.25-6 Mise Info: 120920A-1638 Vial Number: current Method: 

### Calibration File: Last Cal Update: 3302 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALI8\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: Sample Prep Oil Factor: 1.00 Total oil Factor: 1.00

QC Elements 

### Element Cone. Carr. Conc. 7 (Li) 9 8e 11 8 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 1378a 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.46 ug/l 2.46 ug/l 954000.00 ug/l 972100.00 ug/l 18.31 ug/l 68.54 ug/l 2235000.00 ug/l 0.61 ug/l 0.85 ug/l 1.17 ug/l 0.75ug/l 22.68 ug/l 0.75 ug/l 2.35ug/l 0.58 ug/l 0.93 ug/l 2.45 ug/l 1.67 ug/l 1.06 ug/l 4.75 ug/l 144.00 ug/l 126.30 ug/l

0.54 ug/l ug/l 0.33 ug/l ug/l 0.55 ug/l 0.95 ug/l 0.89 ug/l 0.57 ug/l 2.43 ug/l 3.06 ug/l 0.46 ug/l ug/l ug/l 2.24 ug/l UVALUE! 0.46 2.46 954000.00 972100.00 18.31 68.54 2235000.00 0.61 0.85 l.17 0.75 22.68

0.75 2.35 0.58 0.93 2.45 1.67 1.06 4.75 144.00 126.30

0.54 UVALUE! 0.33 UVALUE! 0.55 0.95 0.89 0.57 2.43 3.06 0.46 UVALUE! UVALUE! 2.24

ISTD Elements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 732360.19 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -124807.09 5205648.00 768943.50 20064602.00

1143915.10 413330.66 3473263.50 7762750.00 3868647.30 18836104.00 19873688.00 18683172.00 2.92 0.97 0.65 0.21 18013604.00 0.40 1407958.90 0.68 475526.09 0.59 3640663.30 0.18 10055673.00 0.75 4993515.00 0.80 20883300.00 0.29 23533162.00 0.32 22278996.00 RSD(%)

1.13 5.15 0.27 0.51 3.33 2.92 0.33 14.28 0.65 4.04 2.49 0.24 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000 0.44 1000 1.13 1000 1.40 1000 3.48 .1000 2.63 1000 0.41 1000 4.08 1000 1.53 1000 0.61 1000 

## o.72 1000 1.17 1000 

### UUUUUUU 1.84 500 

### UUUUUUU 5.58 1000 

### 3.42 UUUUUUU 4.07 UUUUUUU 1.38 1000 1.67 1000 1.36 1000 0.73 1000 

### UUUUUUU UUUUUUU 0.73 1000

Rec(%)

141.6 93.1 105.0 111.4 81.2 86.9 95.4 77.2 77.5 90.2 84.4 83.9 QC Range(%) 70 120 70 120 70 120 70 120 70

- 120 70 120 70

- 120 70

- 120 70 120 70

- 120 70

- 120 70

- 120 Flag

>Cal 

### >Cal

>Cal

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I27s00.8\004CAL8.D\004CAL8.DU

:Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 9:48 PM 

### Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA 22304

Attn: Chip McCarty Project: FGD MDL Study 

## Sample 10: FGO-7 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 1.3 0.44

1.2 2.0 5.3 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67417

Prep Date Analysis Date


## 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12



# ..**~~9_·~**

# ______________**~_~_~_~!:~~~_Q~~)**

# _______________________________________**9:~~** 

# _______________________**~:~**

# ________________**~9!!:**

# ________**9_~!~9!_~?** 

# ___________**Q~~?X!~_?**

# _____

Form 

## 1 - APPL Standard Metals

- No 

# Me
Printed: 101011125:01:18 PMC,\ICPCHEM\l\OATA\12126qOO.B\079SMPL.0\079SKPL.0#



### Sample QC Report

Data File, Date Acquired: C,\ICPCHEM\1\DATA\12I26qOO.B\079SMPL.D\079SMPL.D# Sep 27 2012 01,13 am Operator: NBS Sample Name: 1638 MDL-0.25-7 Mise Info: 120920A-1638 Vial Number, CUrrent Method, 

### Calibration File: Last Cal Update, Sample Type, 3303 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Oil Factor, Total Oil Factor, 1.00 1.00

QC Blements Element 

### Cone. Cerro Conc. #VALUEI 0.30 12.52 889100.00 898700.00 20.87 74.21 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.30 ug/l 12.52 ug/l 889100.00 ug/l 898700.00 ug/l 20.87 ug/l 74.21 ug/l 1924000.00 ug/l 0.67 ug/l 0.63 ug/l 1.15 ug/l -0.79 ug/l 17.93 ug/l 0.70ug/l 1.82 ug/l 0.72 ug/l 1.12 ug/l -1.25 ug/l 1.31 ug/l 5.35 ug/l 9.48 ug/l 123.10 ug/l 110.30 ug/l

0.59 ug/l ug/l 0.27 ug/l ug/l 0.44 ug/l -2.74 ug/l -2.90 ug/l -2.68 ug/l

1.35 ug/l 2.74 ug/l 0.39 ug/l ug/l ug/l 2.02 ug/l 1924000.00 0.67 0.63 1.15 -0.79 17.93 0.70 1.82 0.72 1.12 -1.25

1.31 5.35 9.48 123.10 110.30

0.59 #VALUEI 0.27 #VALUEI 0.44 -2.74 -2.90 -2.68

1.35 2.74 0.39 #VALUEI #VALUEI 2.02

ISTD B1ements Element CPS Mean RSD(%) Ref Value 6 Li -75405.17 5.22 -131996.50 45 Sc 3306792.00 0.70 3646344.80 45 Sc 449292.06 3.73 537987.94 45 Sc 12766245.00 0.52 17012292.00 72 Ge 734343.13 1.20 949396.31 72 Ge 245269.66 2.71 338792.91 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 2400689.80 5224508.00 2428834.30 15097894.00 19379362.00 18647806.00 0.31 3456710.80 1.62 6610579.00 1.91 3651775.30 0.49 22769202.00 0.13 28649686.00 0.20 27453282.00 RSD(%) High Limit 

## o 2.71 1000 0.90 1000 0.86 25000 0.96 50000 28.97 20000 4.88 20000 1.15 50000 43.97 1000

0.47 1000 1.55 1000 2.74 1000 25.74 20000

2.74 1000 3.20 1000 2.89 1000 3.38 1000 7.54 1000 0.66 1000 1.08 1000 3.64 1000 0.52 1000 1.26 1000 26.60 1000 ####### 3.98 500 ####### 6.99 1000 0.19 ####### 1.34 ####### 0.48 1000 0.75 1000 0.06 1000 1.71 1000 ####### ####### 0.36 1000

Ree(%)

57.1 90.7 83.5 75.0 77.3 72 .4 69.5 79.0 66.5 66.3 67.6 67.9 QC Range (%) 70

- 120 70

- 120 70 120 70 120 70

- 120 70

- 120 70 120 70

- 120 70 120 70 120 70

- 120 70

- 120 Flag

>Cal >Cal

>Cal

Flag IS Fai

IS Fai

IS Fai IS Fai IS Fai IS Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### 3 :Element Failures 6 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/27/121:17 AM 

### Fail Fail :Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHBM\l\rpttmp\Sample_qct Page 1of 1

## CSC 6101 Steveson Ave. Alexandria, VA22304

Attn: Chip McCarty Project: FGD MDL Study Sample 10: FGO-7 Sample Collection Date: 08/30/12

Method Analyte


## 200.8 ARSENIC (AS) 

## 200.8 CADMIUM (CD) 

## 200.8 CHROMIUM (CR) 

## 200.8 LEAD (PB) 

## 200.8 SELENIUM (SE) 

# Metals Analysis

Result


## 1.6 0.51

1.1 2.2 1.00 PQl Units


## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## 0.2 ug/L 

## APPL Inc. 908 North TemperanceAvenue Clovis, CA 93611

ARF: 68603 

## APPL 10: AY67417

Prep Date Analysis Date
09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12 09/20/12 09/27/12**_~~9:~**

# ______________**T_Ij_~_~~~~~_C~~)**

# _______________________________________**9:~?** 

# _________._.___________**~·_?**

# ________________**~9!~**

# ________**9_~!~9!_~?** 

# ___________**Q~~?X~~_?**

# _____

Form 

### 1 - APPL Standard Metals

- No

# Me
Printed: 101011125:03:27

### PMC,\ICPCHEM\l\DATA\12127.00.B\035SMPL.D\035SMPL.D#



### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, 

### Mise Info: C,\ICPCHEM\1\DATA\12I27S00.B\035SMPL.D\035SMPL.DU Sep 27 2012 09,51 pm NBS 1638 MDL-0.25-7 120920A-1638 Vial Number, Current Method: Calibration File: Last Cal Update, Sample Type, prep Dil Factor: 3303 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample 1.00 Total Dil Factor, 1.00

QC Elements Element Cone. 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb ug/l 0.41 ug/l 2.25 ug/l 957600.00 ug/l 978000.00 ug/l 18.25 ug/l 65.91 ug/l 2265000.00 ug/l 0.70 ug/l 0.80 ug/l 1.13 ug/l 0.74 ug/l 22.65 ug/l 0.72 ug/l 2.06 ug/l 0.61 ug/l 0.98 ug/l 2.38 ug/l 1.59 ug/l 1.00 ug/l 4.47 ug/l 146.50 ug/l 127.20 ug/l

0.50 ug/l ug/l 0.31 ug/l ug/l 0.51 ug/l 0.80 ug/l 0.83 ug/l 0.55 ug/l 2.18ug/1 3.17 ug/l 0.42 ug/l ug/l ug/l 2.23 ug/l

ISTD Elements 

### Cerro Cone. UVALUE! 0.41 2.25 957600.00 978000.00 18.25 65.91 2265000.00 0.70 0.80 1.13 0.74 22.65

0.72 2.06 0.61 0.98 2.38 1.59 1.00 4.47 146.50 127.20

0.50 UVALUE! 0.31 UVALUE! 0.51 0.80 0.83 0.55 2.18 3.17 0.42 UVALUEI UVALUE! 2.23 RSD(%)

2.47 4.47 0.80 0.66 4.80 6.68 0.44 6.65 3.38 1.27 4.66 1.43 1.17 2.20 2.36 1.63 4.51 3.61 3.79 7.91 0.74 0.77 4.88

0.54

9.57 2.35 0.33 3.84 2.64 1.72 2.87

1.01 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000 Flag

>Cal >Cal

>Cal

Element CPS Mean RSD(%) Ref Value Rec(%) QC Range(%) Flag 6 Li -120470.04 4.83 -88139.43 45 Sc 5289535.00 0.74 5590061.50 45 Sc 800425.56 2.58 732360.19 45 Sc 18963600.00 0.82 18013604.00 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 1166711.90 426553.41 3277794.50 7891399.00 4000139.30 18184142.00 19559186.00 18464470.00 0.56 1407958.90 1.62 475526.09 1.40 3640663.30 0.20 10055673.00 2.27 4993515.00 0.89 20883300.00 1.58 23533162.00 1.28 22278996.00 136.7 70 120 IS Fai 94.6 70 120 109.3 70 120 105.3 70

- 120 82.9 89.7 90.0 78.5 80.1 87.1 83.1 82.9 70

- 70 70 70 70

- 70 70 70

- 120 120 120 120 120 120 120 120

ISTD Ref File, C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.DU

:Element Failures 0 :Max. Number of Failures Allowed ,ISTD Failures 0 ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/271129'55 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

# METALS



# Calibration Data

## A.P.P.L. INC. 2A INITIALAND CONTINUING CALIBRATIONVERIFICATION

LabName: A.P.P.L. INC. Contract: CSC



# ---------------------------- ARFNo: 68603 SDG: 68603
InitialCalibration Source: CPI ContinuingCalibration Source: Environmental Express AnalysisDate: 09/26112 

## ConcentrationUnits: ug/L

----------------------



## Analyte Initial Calibration Continuing Calibration M

True Found %R(1) True Found %R(1) True Found %R(1)
17:21 CCVI 18:08 CCVI 19:41
Arsenic (As) 

### 40 36.79 92.0 100 100.1 100 100 98.93 98.9 P Cadmium(Cd) 40 36.94 92.3 100 96.71 96.7 100 99.08 99.1 P Chromium (Cr) 40 40.67 102 100 99.9 99.9 100 101.2 101 P Lead (Pb) 40 37.63 94.1 100 95.21 95.2 100 100.8 101 P Selenium(Se) 40 35.84 89.6 100 98.18 98.2 100 101.4 101 P Thallium(TI) 40 37.44 93.6 100 95.78 95.8 100 100 100 P



## (1) ControlLimits: Metals 90-110 ILM02.0

67404_2008_Opti_120926Arev 

## FORMII (PART 1)

- IN

## A.P.P.L. INC. 2A INITIALAND CONTINUING CALIBRATIONVERIFICATION

LabName: A.P.P.L. INC. Contract: CSC



## ARFNo: 

## 68603 SDG: 

## 68603 Initial Calibration Source: CPI Continuing Calibration Source: Environmental Express AnalysisDate: 

# 09/26112 ConcentrationUnits: ugiL

----------------------



## Analyte Initial Calibration Continuing Calibration

True Found %R(1) True Found %R(1) True
17:21 CCVI 21:14 CCVI Arsenic (As) 40 36.79 92.0 100 100.6 101 100 Cadmium (Cd) 40 36.94 92.3 100 93.17 93.2 100 Chromium(Cr) 40 40.67 102 100 104.3 104 100 Lead (Pb) 40 37.63 94.1 100 93.82 93.8 100 Selenium (Se) 40 35.84 89.6 100 102.9 103 100 Thallium(TI) 40 37.44 93.6 100 92.17 92.2 100



## (1) ControlLimits: Metals 90-110
67404_2008_0pti_120926Arev 

## FORMII (PART 1)

- IN 

## M

Found %R(1)
22:47

. 100.1 100 P

94.51 94.5 P 105.2 lOS P 92.46 92.5 P 102.8 103 P 91.96 92.0 P



## ILM02.0

## AP.P.L. INC. 2A INITIALANDCONTINUING CALIBRATIONVERIFICATION

LabName: AP.P.L. INC. Contract: CSC



# ---------------------------- ARFNo: 68603 SDG: 68603 Initial CalibrationSource: CPI Continuing CalibrationSource: Environmental Express Analysis Date: 09/26112 

## ConcentrationUnits: ug/L



# ----------------------

Analyte Initial Calibration Continuing Calibration M

True Found %R(1) True Found %R(1) True Found %R(1)
17:21 CCVI 0:20 CCVI 1:53 Arsenic (As) 

### 40 36.79 92.0 100 100.1 100 100 93.77 93.8 P Cadmium(Cd) 40 36.94 92.3 100 92.53 92.5 100 91 91.0 P Chromium (Cr) 40 40.67 102 100 101.7 102 100 98.87 98.9 P Lead (Pb) 40 37.63 94.1 100 91.53 91.5 100 96.11 96.1 P Selenium(Se) 40 35.84 89.6 100 102.3 102 100 97.26 97.3 P Thallium (TI) 40 37.44 93.6 100 90.94 90.9 100 95.85 95.8 P



## (1) ControlLimits: Metals 90-110 ILM02.0
67404_2008_0pti_120926Arev 

## FORM II (PART 

## 1)

- IN

## A.P.P.L. INC. 2A INITIALAND CONTINUING CALIBRATIONVERIFICATION

LabName: A.P.P.L. INC. Contract: CSC



# ---------------------------- ARFNo: 68603 SDG: 68603
Initial Calibration Source: CPI Continuing Calibration Source: Environmental Express Analysis Date: 09/26/12 ConcentrationUnits: ugiL



# ----------------------

Analyte Initial Calibration Continuing Calibration 

# M

True Found %R(1) True Found %R(1) True Found %R(1)
17:21 CCVI 3:27 Arsenic (As) 40 36.79 92.0 100 90.07 90.1 P Cadmium(Cd) 40 36.94 92.3 100 87.87 87.9 

## Y
Chromium (Cr) 40 40.67 102 100 98.91 98.9 P Lead (Pb) 40 37.63 94.1 100 93.81 93.8 P Selenium(Se) 40 35.84 89.6 100 93.15 93.2 P Thallium (TI) 40 37.44 93.6 100 97.33 97.3 P



## (1) Control Limits: Metals 90-110 ILM02.0
67404_2008_Opti_120926Arev 

## FORMII (PART 1)

- IN

## LabName: A.P.P.L. INC. A.P.P.L. INC. 

# 3 BLANKS

Contract: CSC



# ---------------------------- ARFNo.: 68603 SDG: 68603 PreparationBlankMatrix (soil/water): water

------------- 

## PreparationBlankConcentrationUnits (ug/L ormg/kg): ug/L

-------------



## Analysis Date: 09/26112 

## Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation 

# M Blank (ug/L) Blank 

## C 1 C 2 C 3 C C 17:34 18:21 19:54 21:27 23:47
Arsenic (As) .50 U .50 U .50 U .50 U .50 U P Cadmium (Cd) .20 U .20 U .20 U .20 U .20 U P Chromium(Cr) .50 U .50 U .50 U .50 U .50 U P Lead (Pb) .20 U .20 U .20 U .20 U .20 U P Selenium(Se) 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U P Thallium(TI) .20 U .20 U .20 U .20 U .20 U P

67405_2008_OpttI20926Arev 

## FORM III

- 

## IN ILM02.0

## LabName: A.P.P.L. INC. A.P.P.L. INC. 3 BLANKS

Contract: CSC



# ---------------------------- ARFNo.: 68603 SDG: 68603 PreparationBlank:Matrix (soil/water): water

----------- 

## PreparationBlank: ConcentrationUnits (ug/L ormg/kg): ug/L

---------



## AnalysisDate: 09/26/12 Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M Blank (ug/L) Blank 

## C 1 C 2 C 3 C C 17:34 23:00 00:33 02:07 23:47
Arsenic (As) 

### .50 U 

### .50 U 

### .50 U 

### .50 U 

### .50 U 

### P Cadmium(Cd) .20 U 

### .20 U 

### .20 U 

### .20 U 

### .20 U 

### P Chromium(Cr) .50 U 

### .50 U 

### .50 U 

### .50 U 

### .50 U 

### P Lead (Pb) .20 U 

### .20 U 

### .20 U 

### .20 U 

### .20 U 

### P Selenium (Se) 1.00 U 

### 1.00 U 

### 1.00 U 

### 1.00 U 

### 1.00 U 

### P Thallium(11) .20 U 

### .20 U 

### .20 U 

### .20 U 

### .20 

### U P

67405_2008_0pti_120926Arev 

## FORM III

- 

## IN ILM02.0

## LabName: A.P.P.L. INC. A.P.P.L. INC. 3 BLANKS

Contract: CSC



# ---------------------------- ARFNo.: 68603 SDG: 68603 PreparationBlankMatrix (soil/water): water

------------- 

## PreparationBlankConcentrationUnits (ugIL ormg/kg): ug/L

-------------



## Analysis Date: 09/26112 

## Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M Blank (ug/L) Blank 

## C 1 C 2 C 3 C C 17:34 03:40 23:47
Arsenic (As) .50 U 

### .50 U 

### .50 U 

### P Cadmium (Cd) .20 U 

### .20 U 

### .20 U 

### P Chromium(Cr) .50 U 

### .50 U 

### .50 U 

### P Lead (Pb) .20 U 

### .20 U 

### .20 U 

### P Selenium (Se) 1.00 U 

### 1.00 U 

### 1.00 U 

### P Thallium (Tl) .20 U 

### .20 U 

### .20 U 

### P

67405_2008_Opti_120926Arev 

## FORMIII

- 

## IN ILM02.0

## A.P.P.L. INC. 2A INITIALAND CONTINUING CALIBRATIONVERIFICATION

LabName: A.P.P.L. INC. Contract: CSC



# ---------------------------- ARFNo: 68603 SDG: 68603 Initial Calibration Source: CPI Continuing Calibration Source: Environmental Express AnalysisDate: 09/27/12 ConcentrationUnits: ug/L

----------------------



## Analyte Initial Calibration Continuing Calibration M

True Found %R(1) True Found %R(1) True Found %R(1)
18:50 CCVI 19:37 CCVI 21:11 Arsenic (As) 40 37.43 93.6 50 53.3 107 50 53.88 108 P Cadmium (Cd) 40 38.37 95.9 50 50.43 101 50 49.57 99.1 P Chromium(Cr) 40 40.21 101 50 48.95 97.9 50 50.17 100 P Lead (Pb) 40 36.78 92.0 50 48.8 97.6 50 48.44 96.9 P Selenium(Se) 40 39.26 98.2 50 53.83 108 50 56.73 113 

# 1/
Thallium (TI) 40 38.32 95.8 50 49.83 99.7 50 49.23 98.5 P



## (1) ControlLimits: Metals90-110 ILM02.0

67405_2008

_Opti_120927Arev 

## FORMII (PART 1)

- IN

## A.P.P.L. INC. 2A INITIALAND CONTINUING CALIBRATIONVERIFICATION

LabName: A.P.P.L. INC. Contract: CSC



# ---------------------------- ARF

## No: 68603 SDG: 68603 Initial Calibration Source: CPI Continuing Calibration Source: Environmental Express AnalysisDate: 09/27112 ConcentrationUnits: ugIL

----------------------



## Analyte Initial Calibration Continuing Calibration M

True Found %R(1) True Found %R(1) True Found %R(1)
18:50 CCVI 22:44 CCVI 0:18 Arsenic (As) 40 37.43 93.6 50 51.63 103 50 50.33 101 P Cadmium(Cd) 40 38.37 95.9 50 48.92 97.8 50 47.31 94.6 P Chromium (Cr) 40 40.21 101 50 49.43 98.9 50 48.24 96.5 P Lead (Pb) 40 36.78 92.0 50 50.07 100 50 49.63 99.3 P Selenium (Se) 40 39.26 98.2 50 54.07 108 50 54.22 108 P Thallium(TI) 40 38.32 95.8 50 50.49 101 50 50.19 100 P



## (1) Control Limits: Metals 90-110 ILM02.0
67404_2008_0pti_120926Arev 

## FORMII (PART 1)

- IN

## LabName: A.P.P.L. INC. A.P.P.L. INC. 

# 3 BLANKS

Contract: CSC



# ---------------------------- ARFNo.: 68603 SDG: 68603 PreparationBlankMatrix (soil/water): water

------------- 

## PreparationBlankConcentrationUnits (ug/L ormg/kg): ug/L
---'-----------



## AnalysisDate: 09/27112 Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M Blank (ug/L) Blank 

## C 1 C 2 C 3 C C 19:04 19:50 21:24 22:58 20:11
Silver(Ag) .20 

### U .20 

### U .20 

### U .20 

### U .20 

### U P Cadmium(Cd) .20 

### U .20 

### U .20 

### U .20 

### U .20 

### U P Chromium(Cr) .50 

### U .50 

### U .50 

### U .50 

### U .50 

### U P Lead (Pb) .20 

### U .20 

### U .20 

### U .20 

### U .20 

### U P Selenium (Se) 1.00 

### U 1.00 

### U 1.00 

### U 1.00 

### U 1.00 

### U P Thallium(TI) .20 

### U .20 

### U .20 

### U .20 

### U .20 

### U P

67404_2008_Opti_120927Arev 

## FORM III

- 

## IN ILM02.0

## LabName: A.P.P.L. INC. A.P.P.L. INC. 3 BLANKS

Contract: CSC



# ---------------------------- ARFNo.: 68603 SDG: 68603 PreparationBlankMatrix (soil/water): water

----------- 

## PreparationBlankConcentrationUnits (ugiL ormglkg): ug/L

-----------



## AnalysisDate: 09/27/12 Analyte Initial Calibration Continuing Calibration Blank (ug/L) Preparation M Blank (ug/L) Blank C 1 C 2 C 3 C C 19:04 00:32 20:11
Silver(Ag) .20 

### U .20 

### U .20 

### U P Cadmium (Cd) .20 

### U .20 

### U .20 

### U P Chromium(Cr) .50 

### U .50 

### U .50 

### U P Lead (Pb) .20 

# u .20 

### U .20 

### U P Selenium(Se) 1.00 

### U 1.00 

### U 1.00 

### U P Thallium (TI) .20 

### U .20 

### U .20 

### U P

67404_2008

_Opti_120927Arev 

## FORMIII

- IN ILM02.0C.\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D#



## Calibration Blank QC Report

Data File: Date Acquired: Operator: Sample Name: Mise Info: Vial Number: C:\ICPCHEM\1\DATA\12I26qOO.B\004CAL Sep 26 2012 04:54 pm NBS Calibration Blank

Current Method: 1102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 04:51 pm Calibration File: Last Cal Update: Sample Type: CalBlk Total Dil Factor: l.00

QC&ISTD 

### Elements Element 6 7 9 

### 11 23 24 27 39 44 45 45 45 47 51 52 55 56 59 60 63 65 66 

### 72 72 72 75 78 78 88 88 95 106 107 108 111 115 115 115 118 118 118 121 137 159 165 205 206 207 208 Li (Li) Be B 

### Na 

## Mg Al K 

### Ca Sc Sc Sc Ti V 

### Cr Mn Fe Co Ni Cu Cu 

### Zn Ge Ge Ge As Se Se Sr Sr Mo (Cd) 

## Ag (Cd) Cd In In In Sn Sn Sn Sb Ba Tb Ho TI (Pb) (Pb) Pb

9/26/124:58 PM 

### CPS Mean -131996.50 A 9364744.00 A 265.57 P 10658.16 P 38625.20 P

1465.68 P 1132.33 P 55876.13 P

3152.87P 3646345.00 A

537987.88 A 17012290.00 A 20.44 P 600.02 P 390.23P 4003.71 P 23753.24P 184.45 P 23l.73 P 394.23P 215.56 P 3000.36 P 949396 .31 A 338792.91 A 3456711.00 A 74.67 P 12.78 P 197.45P 2728.15P 29199.07P

325.57 P

77.78 P 30l.13 P

34.45 P 206.20 P 6610579.00 A 3651775.00 A 22769200.00 A 2071l.03 P 12091.18 P 71947.77 P

804.50 P 1065.64P 28649680.00 A 27453280.00 A 142l.24 P

743.38P 620.04P 2831.34 P SO 4085.00 101000.00 13.47 533.70 271 .10

27.96 61.89 946.60

93.55 104600.00

5966.00 243000.00 3.36 8.33 16.56 77.60 198.50

14.26 138.20

30.99 15.34 72.91 13980.00

3278.00 29270.00 3.18 4.81 12.83 116.60 383.90

44.39 12.62 15.03 15.03 40.64 142000.00

23990.00 500600.00 467.80 122.40 426.90

43.51 10.18 627100.00 578000.00 115.00

20.82 18.57 64.32 RSD(%) 3.09 l.08 5.07 5.01 0.70 l.91 5.47 l.69 2.97 2.87 l.11 l.43 16.42

l.39 4.24 l.94 0.84 7.73 59.64

7.86 7.12 2.43 l.47 0.97 0.85 4.26 37.65

6.50 4.27 l.31 13.64 16.23

4.99 43.63 19.71

2.15 0.66 2.20 2.26 l.01 0.59 5.41 0.96 2.19 2.11 8.09 2.80 3.00 2.27

C:\ICPCHEM\l\rpttmp\CalBlk.qct Page 1of 19126112 5:05 PM c:\ICPCHKH\l\DATA\HI2IiqOQ .B\005CALS.D\005CALS.D'



### Calibration Standard QC Report

Data File: Date Acquired: C.\ICPCHEM\l\ DATA\12I 26qOO.B\005CALS.D\005CALS

.D# Sep 26 2012 05.01 pm Operator: Sample Name: Misc Info I Vial Number: Current Method: Calibration File: Last Cal Update: Sample Type. Total Oil Factor:

Elements NBS 120926 Standard 1

1103 C.\ICPCHEM\l\METHODS\CSC-MDL.M C.\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 04.58 pm CalStd 1.00

QC&ISTD Element 6 Li CPS Mean -128456.10A 9374662.00A SD 14870.00 11470.00 61.99 339.10 612.50 3324.00 RSD(\) 11.58 0.12 0.67 2.13 1.21 4.35 4.02 2.44 4.02 0.26 0.84 1.74 3.40 1.34 2.36 1.20 0.46 3.90 2.63 2.33 5.87 0.94

. 0.46 1.07 0.82 1.78 5.55 5.68 1.17 0.70 0.63 3.17 1.23 3.32 3.47 0.14 0.53 1.65 1.69 0.69 8.77 0.59 2.62 1.44 1.86 1.01 0.62 0.57 0.25 Cal Coef 0.0000 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 45 Sc 45 Sc 45 Sc 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 

### Cu 65 CU 66 Zn 72 Ge 72 Ge 72 Ge 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 115 In 115 In 115 In 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 159 Tb 165 Ho 205 Tl 206 (Pb) 207 (Pb) 208 Pb 9215.35P 15891.85 P 50818.34 P 76363.15P 14064.36P 66014.35 P 6679.48P 3864788.00A 542454.88 A 17162160.00A 274.67 P 4073.95 P 4338.48P 3616.54P 364264.50 P

5822.57P 1639.67 P 5722.53P 2818.54P 2764.30P 970636.38 A 335102.59A 3498259.00A 674.35P 264.78 P 265.00 P 6080.42 P 69383.48P 23553.46 P

640.04 P 29520.78 P

464.47P 6220.04 P 6941834.00A 3633142.00A 22559980.00A 25271.30 P 14575.83 P 91354.67 P 48745.79P

9586.97 P 29082390.00 A 27937120.00A 47197.45P 16295.04 P 13757.63 P 63812.34P 565.70 1613.00 268.80 9866.00 4576.00 298200.00 9.33 54.62 102.40 43.30 1685.00 227.20 43.09 133.60 165.50 25.96 4494.00 3588.00 28760.00 12.00 14.70 15.06 71.36 487.90 147.70 20.28 363.70 15.40 215.70 9968.00 19120.00 372400.00

427.50 100.20 8012.00 286.10 251.60 419400.00 520600.00 476.40 100.40 78.52 159.20

ISTD Elements Element CPS Mean RSO (%:) Ref Value -131996.50 3646344.80 Li -128456.14 11.58 45 Sc 3864787.50 0.26 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 542454.94 17162164.00

970636.44 335102.56 3498259.00 6941833.50 3633142.30 0.84 537987.94 1.74 17012292.00 0.46 949396.31 1.07 338792.91 0.82 3456710.80 0.14 6610579.00 0.53 3651775.30 22559976.00 1.65 22769202.00 29082388.00 1.44 28649686.00 27937124.00 1.86 27453282.00 Rec (\) QC Range (\) 97.3 70- 106.0 70- 100.8 100.9 102.2 98.9 101.2 105.0 99.5 99.1 101.5 101.8 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 

### o.0000 

### o.0000 0.0000 0.0000 0.0000 0.0000 

## o.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

## o .0000 

## o .0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 

## o.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

120 120 120 120 120 120 120 120 120 120 120 120

ISTD Ref File. C.\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures :Max. Number of Failures Allowed :ISTD Failures :Max. Number of ISTO Failures Allowed



### Data Results: Analytes: ISTD: Pass Fail

C.\ICPCHEM\l\RPTTMP\CalStdx.qct Flag IS Fail

Page 1of 19/261125:12 PM c:\ICPCHEM\l\DATA\12I26CJOO. B\006CALS.D\OO6CALS.D'



### Calibration Standard QC Report

Data File: Date Acquired: c,\ ICPCHEM\l\ DATA\12I26qOO.B\006CALS.D\006CALS.Dff Sep 26 2012 05,08 pm Operator: NBS Sample Name: 120926 Standard 2 Misc InEo: Vial Number: 1104 Current Method: Calibration File: Last Cal Update: 

### c,\ ICPCHEM\l\METIlODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,05 pm Sample Type, Total Dil Factor: CalStd 1.00

OC&ISTD Blements Element CPS Mean 6 Li -124052.80A 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 45 Sc 45 Sc 45 Sc 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 72 Ge 72 Ge 72 Ge 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 115 In 115 In 115 In 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 159 Tb 165 Ho 205 Tl

. 206 (Pb) 207 (Pb) 208 Pb 9388073.00A 87670.49 P 67109.20 P 173675.80 P 702927.38P 129542.10 P 138457.30P 51318.47P 3831536.00A 547501.50A 17162970.00A 2602.49P 33628.83 P 37931.25 P 28513.23 P 3549105.00A

53880.38 P 13775.06P 36971.40 P 17914.33 P 10200.58 P 970464.13 A 340663.81A 3481775.00A 5912.55 P 2397.65P 799.36 P 51626.11 P 605982.88 P 222339.20P

5337.86 P 281855.81 P

4228.56 P 58614.76 P 6879776.00A 3681573.00A 22643760.00 A

122217.90 P 71977 .47 P 438536.69 P 464702.41 P

87739.07P 28843040.00A 27834820.00 A

434437.09 P 149330.00 P 125279.60 P 586482.50P

ISTD Elements SD 4981.00 50090.00

1032.00 1683.00 1025.00 5082.00 408.60 2727.00 249.50 19360.00 1637.00 233900.00 16.46 141.20 275.00 320.30 12120.00

332.70 135.70 437.30 180.30 129.90 11430.00 5247.00 19370.00 7.37 15.74 7.64 58.37 486.10 1875.00

94.08 2377.00 184.60 640.40 38680.00 22140.00 311600.00

1176.00 1319.00 429.10 4739.00 1433.00 590600.00 502000.00

4798.00 602.10 362.10 2413.00 RSD(%) 4.02 0.53 1.18 2.51 0.59 0.72 0.32 1. 97 0.49 0.51 0.30 1.36 0.63 0.42 0.73 1.12 0.34 0.62 0.99 1.18 1.01 1.27 1.18 1.54 0.56 0.12 0.66 0.96 0.11 0.08 0.84 1.76 0.84 4.37 1.09 0.56 0.60 1.38 0.96 1.83 0.10 1. 02 1.63 2.05 1.80 1.10 0.40 0.29 0.41 Cal Coef 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 

## o.0000 0.0000 1.0000 1.0000 1.0000 -1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 -1.0000 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000

Element CPS Mean RSD (%) 6 Li -124052.85 4.02 Ref Value -131996.50 3646344.80 Flag 120 IS Fail 

# ,vT Rec (%) QC Range (% )

94.0 70- 45 Sc 3831535.80 0.51 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 547501.56 17162970.00 0.30 537987.94 1.36 17012292.00 970464.13 1.18 949396.31 340663.81 1.54 338792.91 3481774.50 0.56 3456710.80 6879776.00 0.56 6610579.00 3681573.00 0.60 3651775.30 22643762.00 1.38 22769202.00 28843046.00 2.05 28649686.00 27834816.00 1.80 27453282.00 105.1 70

- 101.8 70

- 100.9 70- 102.2 100.6 100.7 104.1 100.8 99.4 100.7 101.4 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 120 120 120 120 120 120 120 120 120 120 120

ISTD Ref File : c,\ ICPCHEM\l\ DATA\12I26qOO.B\004CALB.D\004CALB.Dff

:Element Failures
:ISTD Failures



### Data Results: Analytes: ISTD: Pass 

### Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C I \ICPCHEM\l\RPTTMP\CalStdx.qct Page 1of 19/261125:16 PM c:\ICPt'HEJ1\l\DATA\llI:ill5qOO.B\007CALS.D\007CALS.DO



### Calibration Standard QC Report

Data File: Date Acquired: C, \ICPCHEM\l\ DATA\12126qOO.B\007CALS

.D\007CALS .DD Sep 26 2012 05,14 pm Operator; Sample Name: Misc Infol vial Number: NBS 120926 Standard 3

1105 Current Method: Calibration File: Last Cal Update: C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,12 pm Sample Type, Total Oil Factor I CalStd 1.00

QC&ISTD Elements Element CPS Mean 6 Li -119622.80A 7 (Li) 8883137.00A 9 Be 921109.69A 11 B 558770.63P 23 Na 1545638.00A 24 Mg 7149967.00A 27 Al 1397824.00A 39 K 949240.50A 44 Ca 45 Sc 45 Sc 45 Sc 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 72 Ge 72 Ge 72 Ge 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 115 In 115 In 115 In 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 159 Tb 165 Ho 205 Tl 206 (Pb) 207 (Pb) 208 Pb 492536.41 P 3771472.00A 545941.38 A 15972640.00A

25286.86 P 328196.91 P 368763.00 P 273514.00 P 33976660.00A

519900.50P 128886.30 P 343775.81 P 167424.30 P 81050.26P 958901. 88 A 338705.59A 3377177.00A

58660.87 P 25092.68 P 6399.32 P 502820.41 P 6075893.00 A 227B739.00A

51378.79 P 2793105.00 A

40564.85 P 565222.38 P 6690475.00A 3596723.00A 20753860.00 A 1164467.00 A 629511.69P 4011512.00A 4796117.00 A

829636.13 P 26839880.00A 25972040.00A 4520327.00 A 1584920.00A 1333277.00A 6152221.00 A

ISTD Elements SO 1118.00 109900.00

4498.00 2836.00 7041.00 65720.00 10740.00 10870.00 5380.00 33200.00 2053.00 263100.00 348.60 1634.00 3426.00 2094.00 134500.00

1849.00 943.60 2227.00 1532.00 591.70 9627.00 3370.00 46780.00

346.10 87.23 60.43 2241. 00 49300.00 17670.00

306.00 13880.00

174.50 3386.00 117700.00 14060.00 235300.00 15530.00 6945.00 16700.00 40750.00 2515.00 198200.00 187600.00 31470.00 13340.00 3933.00 26170.00 RSD(%) 0.93 1.24 0.49 0.51 0.46 0.92 0.77 1.15 1.09 0.88 0.38 1.65 1.38 0.50 0.93 0.77 0.40 0.36 0.73 0.65 0.92 0.73 1.00 0.99 1.39 0.59 0.35 0.94 0.45 0.81 0.78 0.60 0.50 0.43 0.60 1.76 0.39 1.13 1.33 1.10 0.42 0.85 0.30 0.74 0.72 0.70 0.84 0.29 0.43 Cal Coef 0.0000 0.9406 1.0000 1.0000 0.9999 1.0000 1.0000 0.9998 0.9997 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 0.9944 1.0000 1.0000 1.0000 0.9990 0.9989 0.9931 0.0000 0.0000 0.0000 1.0000 1.0000 0.9999 0.9996 0.9996 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 0.9982 0.9986 0.9991 1.0000 1.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000

Element CPS Mean RSD(\) Ref Value -131996.50 Rec (%) QC Range (\) Li -119622.90 0.93 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3771471.80 0.88 3646344.80 545941.44 0.38 537987.94 15972640.00

958901.94 338705.66 1.65 17012292.00 1.00 949396.31 0.99 338792.91 3377176.50 1.39 3456710.80 6690474.50 1.766610579.00 3596723.50 0.39 3651775.30 20753860.00 1.13 22769202.00 26839886.00 0.74 28649686.00 25972036.00 0.72 27453282.00 90.6 70

- 103.4 101.5 93.9 101.0 100.0 97.7 101.2 98.5 91.1 93.7 94.6 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 120 120 120 120 120 120 120 120 120 120 120 120

ISTD Ref File : C,\ICPCHEM\l\DATA\12I 26qOO

.B\004CALB.D\004CALB.DD

;Element Failures 1 ;ISTD Failures



### Data Results: Analytes: ISTD: Pass Fail ;Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C.\ ICPCHEM\1\RPTTMP\CalStdx.qct Flag IS Fail

Page 1of 1C,\ICPCHEM\l\DATA\12126qOO .S\OOB_QCS.D\OOB_QCS.of



### QCS QC Report

Data File, Date Acquired, Operator: 

### C,\ICPCHEM\1\DATA\12126qOO.8\008_QCS.D\008_QCS.D# Sep 26 2012 05,21 

### pm

Sample Name: 

### Mise Info: Vial Number: Current Method: Calibration File: 

### Last Cal Update, Sample Type, Total Dil Factor, NBS 

### ICV 120926

1107 

### C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 

### pm QCS 1.

### 00

QC Elements Element 

### Cone. RSD(%) Expected QC Range(%) 7 (Li) 9 

### Be 11 B 

### 23 Na 24 Mg 27 Al 39 K 

### 44 Ca 47 Ti 51 

### v 52 Cr 55 Mn 

### 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 

### (Cd) 107 

### Ag 108 

### (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 

### Sb 137 Ba 205 

### Tl 206 

### (Pb) 207 

### (pb) 208 

### Pb ug/l 35.25 ug/l 38.88 ug/l 3686.00 

### ug/l 4070.00 

### ug/l 3530.00 

### ug/l 3732.00 

### ug/l 3778.00 

### ug/l

26.98 ug/l 40.08 

### ug/l 40.67 

### ug/l 39.29 ug/l 3954.00 

### ug/l

39.83 ug/l 40.94 

### ug/l 40.06 

### ug/l 39.97 ug/l 33.20 

### ug/l 36.79 ug/l 35.84 ug/l 36.44 ug/l 37.73 ug/l 37.43 ug/l 34.52 ug/l ug/l 35.49 ug/l ug/l 36.94 ug/l

2.43 ug/l 2.74 ug/l 1.83 ug/l 34.80 

### ug/l 37.13 ug/l 37.44 ug/l ug/l ug/l 37.63 ug/l 0.82 

### 1.44 1.14 0.57 0.59 0.67 

### 1.38 2.23 0.85 0.78 0.77 

### 1.38 1.07 0.15 0.62 0.37 

### 1.38 0.86 0.68 0.90 0.35 

### 1.06 0.76

1.13

0.32 8.02 

### 22.16 12.37 0.74 0.44 0.61



### 1.87

ISTD Elements 

### Element CPS Mean RSD(%) Ref Value Li -134362.28 1.83 -131996.50 

### 45 Sc 3846838.80 

### 1.27 3646344.80 

### 45 Sc 541400.81 0.69 537987.94 

### 45 Sc 16911978.00 0.09 17012292.00 72 

### Ge 958731. 75 1.

### 26 949396.31 72 

### Ge 339681.38 2.08 338792.91 72 

### Ge 3461235.80 0.95 3456710.80 

### 115 In 6836313.50 0.53 6610579.00 

### 115 In 115 In 159 Tb 165 Ho 3636110.30 22338996.00 28408302.00 27378630.00 0.59 3651775.30 

### 0.61 22769202.00 1.02 28649686.00 0.72 27453282.00 100.00 

### 90 110 40.00 40.00 4000.00 4000.00 4000.00

40.00 4000.00

40.00 40.00 40.00 40.00 4000.00

40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 20.00 20.00 20.00 20.00 20.00 40.00 40.00 40.00 40.00 

### 90

- 110 90 110 90

- 110 90 110 90 110 90 110 

### 90

- 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90

- 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 110 90 110

Rec(%) QC Range(%)

101.8 105.5 100.6



### 99.4 101.0 100.3 100.1 103.4 

### 99.6 98.1 99.2 99.7 70 70 70 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120 

### 70

- 120 

### 70

- 120 70 120 

### Flag

Fail

Fail Fail

Fail

Fail

Fail

Fail

Fail

Fail Fail Fail Fail Fail

Flag IS Fail

ISTD Ref File, C,\ICPCHEM\1\DATA\12126qOO.8\004CALB.D\004CALB.D#

13 :Element Failures 0 :Max. Number of Failures Allowed



### 1 ,ISTD Failures 0 ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes : Fail ISTD: Fail

9/26/125:25 PM 

### C:\ICPCHEM\l\rpttmp\QCS.qct Page 1 of 1

### CCB QC Report

Data File, Date Acquired: Operator: Sample Name: Mise Info: 

### Vial Number: CUrrent Method: 

### Calibration File: Last Cal Update, Sample Type: Total Dil Factor:

QC Blement. 

### Element 

### Conc. 7 (Li) 9 Be 0.00 11 B 0.49 23 Na 0.72 24 Mg -0.19 27 Al 1.48 39 K 1. 54 44 Ca -2.41 47 Ti 0.04 51 V -0.02 52 Cr 0.01 55 Mn -0.02 56 Fe 0.24 59 Co 0.00 60 Ni -0.07 63 Cu 0.00 65 CU -0.01 66 Zn 0.02 75 As 0.01 78 Se 0.01 78 Se 0.20 88 Sr -0.02 88 Sr 0.00 95 Mo 0.03 106 (Cd) 107 Ag 0.00 108 (Cd) 111 Cd 0.01 118 Sn 0.19 118 Sn 0.00 118 Sn 0.12 121 Sb 0.03 137 Ba -0.01 205 TI 0.01 206 (Pb) 207 (Pb) 208 Pb 0.00

ISTD Element. 

### Element CPS 

### Mean 6 Li -122884.55 45 Sc 3477002.80 45 Sc 528808.06 45 Sc 16805466.00 72 Ge 914926.44 72 Ge 338749.25 72 Ge 3416004.80 115 In 6345123.50 115 In 3602017.00 115 In 22248522.00 159 Tb 27758682.00 165 Ho 26702446.00

ISTD Ref File :

:Element Failures :ISTD Failures



### Data Results: Analytes: ISTD:

9126112 5:38 PM C, \ ICPCHEM\1\OATA\12I26qOO.B\OlO_CCB.O\OlO_CCB.of

C,\ICPCHEM\1\DATA\12I26qOO.B\010_CCB.D\010_CCB.D# Sep 26 2012 05,34 pm NBS ICB 120926

1102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm CCB 1.00

RSD(%) High Limit ug/l ####### ug/l 91.54 0.12 ug/l 10.59 15.00 ug/l 95.39 77.10 ug/l 110.05 7.50 ug/l 100.34 3.96 ug/l 174.71 19.20 ug/l 63.12 90.00 ug/l 160.32 0.78 ug/l 33.46 0.21 ug/l 39.14 0.12 ug/l 121.97 0.18 ug/l 31.62 40.80 ug/l 242.04 0.09 ug/l 6.31 0.48 ug/l 206.18 0.39 ug/l 71.58 0.39 ug/l 245.26 6.90 ug/l 15.42 0.27 ug/l 185.45 0.30 ug/l 50.12 0.30 ug/l 53.22 0.03 ug/l 565.80 0.03 ug/l 13.51 0.21 ug/l ####### ug/l 3791.20 0.09 ug/l ####### ug/l 111.74 0.06 ug/l 90.51 ####### ug/l 2695.20 ####### Flag

ug/l 30.72 0.30 ug/l 9.56 0.03 Fail 

# rJ'1 ug/1 89.88 0.12 ug/l 15.53 0.03 ug/l ####### ug/l ####### ug/l 95.16 0.33

RSD (%)

. Ref Value Rec(%) QC Range(%) Flag

5.56 -131996.50 93.1 70

- 120 

### IS FaL 

### 1'1""'( 4.24 3646344.80 95.4 70 120 1.32 537987.94 98.3 70

- 120 0.54 17012292.00 98.8 70

- 120 4.24 949396.31 96.4 70 120 1.08 338792

.91 100.0 70 120 0.30 3456710.80 98.8 70

- 120 3.69 6610579.00 96.0 70 120 1.14 3651775.30 98.6 70 120 1.71 22769202.00 97.7 70 120 1.17 28649686.00 96.9 70

- 120 1.31 27453282.00 97.3 70

- 120
C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D#



### Fail Fail0 0 

### :Max. Number



### :Max. Number of Failures Allowed of ISTD Failures Allowed

C:\ICPCHEM\I\rpttmp\CCB.qct Page 1of 1C:\ICPCIIEM\l\OATA\11I26qOO.B\OllSMPL.O\OllSMPL.O'



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\011SMPL.D\011SMPL.D# Sep 26 2012 05:41 pm Operator: NBS Sample Name: LLICV 120926 Mise Info: Vial Number: Current Method: 

### Calibration File: Last Cal Update: 1103 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements 

### Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se .78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Conc. ug/l 0.89 ug/l 1.21 ug/l 21.79 ug/l 253.50 ug/l

90.86 ug/l 22.57 ug/l 191.90 ug/l

1.96 ug/l 0.99 ug/l 1.09 ug/l -0.18 ug/l 101.10 ug/l

1.08 ug/l 1.10 ug/l 1.23 ug/l 1.21 ug/l -0.19 ug/l 1.03 ug/l 0.92 ug/l 1.16 ug/l 0.61 ug/l 0.60 ug/l 1.87ug/1 ug/l 0.95 ug/l ug/l 0.97 ug/l 0.45 ug/l 0.95 ug/l 0.72 ug/l 1.85 ug/l 0.94 ug/l 0.92 ug/l ug/l ug/l 0.91 ug/l

Element CPS Mean RSD(%) Li -126401.63 7.40 45 Sc 3813611.50 0.79 45 Sc 525005.56 2.09 

### Cerro Conc. #VALUE! 0.89 1.21 21.79 253.50

90.86 22.57 191.90

1.96 0.99 1.09 -0.18 101.10

1.08 1.10 1.23 1.21 -0.19

1.03 0.92 1.16 0.61 0.60 1.87 #VALUEI 0.95 #VALUE! 0.97 0.45 0.95 0.72 1.85 0.94 0.92 #VALUE! #VALUE! 0.91

Ref Value -131996.50 3646344.80 537987.94 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 16691403.00 966428.06 328401.03 3403630.30 6889807.50 3514611.30 1.16 17012292.00

22120702.00 28237270.00 27165836.00 0.21 949396.31 1.03 338792.91 1.04 3456710.80 0.71 6610579.00 2.19 3651775.30 1.30 22769202.00 0.24 28649686.00 0.69 27453282.00 RSD(%)

2.07 2.41 9.44 2.67 2.52 16.17 9.60 4.49 3.16 1.48 23.95

1.93 1.62 3.90 2.31 0.72 17.91 6.47 9.12 22.38

1.25 2.36 2.64

3.37

0.54 20.86 17.92 5.32 2.39 3.55 1.51

0.21

Rec(%)

95.8 104.6 97.6 98.1 101.8 96.9 98.5 104.2 96.2 97.2 98.6 99.0 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 

### I 0 ., 

### 'I.
1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 107,'/' 

## 0\1. ",

"11. ",



# '11 'I.

QC Range(%) 70 120 70 120 70 120 70 70 70

- 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120 Flag

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### o :Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/26/12 5:45 PM 

### Pass Fail

## o :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\1\rpttmp\Samp1e,qct Page 1of 1CI\IC'PCH!l(\l\DATA\13IlliqOO ,1'\013lC'SA .0\013leBA**.P~**



### ICS-A QC Report

Data File: Date Acquired: Acq. Method, Operator: Sample Name: MIse Info: VIal Number: Current Method: Callbration FIle: Last cal. Update, Sample Type, DilutIon Factor:

OC Elements Element IS Ref Tune 7 (Ll) 9 Be 45 11 B 45 23 Na 45 24 Mg 45 27 Al 45 39 K 45 44 Ca 45 47 Tl 45 51 V 45 52 Cr 45 55 Mn 45 56 Fe 45 59 Co 45 60 Ni 45 63 cu 45 65 cu 45 66 Zn 115 75 As 115 78 Se 115 78 Se 115 88 Sr 115 88 Sr 115 95 Mo 115 106 (Cd) 107 Ag 115 108 (Cd) 111 cd 115 118 Sn 115 118 Sn 115 118 Sn 115 121 Sb 115 137 Ba 115 205 Tl 159 206 (Pb) 207 (Pb) 208 Pb 159

ISTD Elements 

### Element
6 Ll 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 2

2 2 2

2

3 3

3 3

Tune C,\ICPCHEM\1\DATA\12I26qOO.B\012ICSA.D\012ICSA.D# Sep 26 2012 05,48 pm CSC-MDL.M NBS FGD MATRIX

2101 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm ICSA 1.00

Cone. ug/l 0.00 ug/l 0.59 ug/l 887800.00 ug/l 925800.00 ug/l 5.60 ug/l 9.92 ug/l 1929000.00 ug/l 0.19 ug/l 0.15 ug/l 0.70 ug/l -0.56ug/l 7.65 ug/l 0.25 ug/l 1.43 ug/l 0.16 ug/l 0.48 ug/l -2.39ug/l 0.76 ug/l 0.21 ug/l 1.33 ug/l 122.60 1Jg/l 122.20 ug/l

0.10 ug/l ug/l 0.18 ug/l ug/l 0.03 ug/l -1.39 ug/l 0.19 ug/l -1.37 ug/l 2.16 ug/l 2.23 ug/l 0.03 ug/l ug/l ug/l 1.63 ug/l RSD(%)

55.33 9.26 0.77 0.44 10.09 47.91 0.49 67.42 28.29 2.88 38.20

1.50 1.72 1.40 7.62 6.79 2.13 2.60 13.19 19.29 3.79 12.12 42.54

2.92

20.78 0.13 1396.60 2.63 2.65 2.86 16.42

2.77 Data Results: Analytes: Fail ISTD: Fail

High Limit ppb

38.55 3.75

45.00

CPS Mean RSD(%) Ref value Rec(%) QC Range (%) 70 120 70

- 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 -110792 5.59 3656943 0.76 560921 1.02 14763353

828390 300758 2781498 5776089 3007656 16366449 20493616 19437084 1.35 1.52 0.52 0.61 0.80 0.58 1.22 1.89 1.55 -131997 83.9 3646345 100.3 537988 104.3 17012292

949396 338793 3456711 6610579 3651775 22769202 28649686 27453282 86.8 87.3 88.8 80.5 87.4 82.4 71.9 71.5 70.8

Tune File# c'\lcpchem\1\7500\h2_hml.u Tune Flle# c,\icpchem\1\7500\he_hml.u Tune File# c,\icpchem\1\7500\ng_hmi.u Flag

Fail Fail

Fail

Flag IS Fail

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

3 :Element Failures :Max. Number of Failures Allowed 1 :ISTD FaIlures :Max. Nnumber of ISTD Failures Allowed

9/26/125:51 PM C:\ICPCHEM\1\RPTTMP\6020ICSA.qct Page 1of 1C;\ICPCHEM\l\DnA\1

..:n5qOO .B\Ol'3ICSB.D\OUICSB.DII



### ICS-AB QC Report

Data FIle: Date Acquired: C,\ICPCHEM\1\DATA\12I26qOO.B\013ICSB.D\013ICSB.DD Sep 26 2012 05,54 pm Acq. Method, Operator: sample Name: Mise Info: 

### Vial Number: Current Method: CalIbration FIle: Last Cal. Update: Sample Type, DIlutIon Factor:

QC Elements CSC-MDL.M NBS FGD MATRIX SPIKED

2102 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C sep 26 2012 05,19 pm ICSAB 1.00

Element IS Ref Tune Conc. ppb RSD(%) Expected 100 40 40 5000 5000 4000 7 (Ll) --------.------. 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Nl 63 Cu 65 Cu 66 Zn 75 As 78 5e 79 Se 88 5r 88 Sr 95 Mo 106 (Cd) 107 Ag 109 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 209 Pb 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 115 115 115 115 115 115 115

115

115 115 115 115 115 115 159

159

ISTD Elements Element Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 2 2

2 3

1 2

Tune

2

3 3 3 31.36 2.52 34.13 1.42 775200.00 1.43 902700.00 1.98

3712.00 1.79 3866.00 1.58 1671000.00 1.30 31.08 12.75 41.67 1.76 40.28 1.86 38.01 2.01 3695.00 2.21

36.56 36.64 33.83 33.99 33.47 52.03 53.84 59.91 149.30 144.40 40.94 1. 89 2.51 1.74 1.66 1.02 0.95 0.40 1.02 0.99 2.17 1.90

34.151.98

37.96 2.02

1.2320.45 1.14 25.27 1.25 29.52 40.03 2.06 42.38 2.60 33.16 1.63

31.29 1.14

CPS Mean RSD (%) -104032 3.51 3858832 0.06 560798 2.59 15475736

856279 304597 2969213 5987052 3029399 17056412 21157712 20205690 2.13 0.56 0.12 0.91 0.95 0.83 2.26 1.60 1.71 40 6000

40 40 40 40 4000

40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 20 20 20 20 20 40 40 40 40

Ref Value -131997 3646345 537988 17012292

949396 338793 3456711 6610579 3651775 22769202 28649686 27453292

Tune FileD c'\lcpchem\1\7500\h2_hmi.u Tune FileD 2 c'\lcpchem\1\7500\he_hmi.u Tune FileD 3 c'\lcpchem\1\7500\ng_hml.u %Recovery #VALUEI



### 78.4 85.3 15504.0 16054.0

92.8 9665.0 27850.0

77.7 104.2 100.7 95.0 92.4 91.4 91.6 84.6 85.0 83.7 130.1 134.6 149.8 373.3 361.0 102.4 #VALUEI



### 85.4 #VALUEI



### 94.9 62 5.7 6.2 200.2 211.9 82.9 #VALUEI #VALUEI



### 78.2

Rec(%)

78.8 105.8 104.2 91. 0 90.2 89.9 85.9 90.6 83.0 74.9 73.8 73.6

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DD Data Results: Analytes: Fail ISTD: Fail

QC Range (%) 70 130 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 130 .130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130

QC Range (%) 70 120 70 120 70 120 70 70 70 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120

:Elernent Failures 1 :ISTD FaIlures :Max. Number of FaIlures Allowed :Max. Number of ISTD Failures Allowed Flag

Fall Fall Fail

Fall Fail

Fall Fail

Flag I S Fall

9126/12 5:58 PM C:\ICPCHEM\1\RPTTMP\6020ICSB.qct Page 1of1C,\ICPCHEM\l\DATA\12126qOO .B\OlS_CCV.D\OlS_CCV.01



### CCV QC Report

Data File, Date Acquired, Operator, Sample Name: C,\ICPCHEM\1\DATA\12I26qOO.B\015_CCV.D\015_CCV.D# Sep 26 2012 06,08 pm

Mise Info: Vial Number, CUrrent Method, 

### Calibration File: Last Cal Update, Sample Type, Total Oil Factor, NBS CCV 120926

1106 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm CCV 1.00

QC Blements 

### Element Cone. RSD (%) Expected QC Range (%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/1 94.77 ug/l 94.19 ug/l 2529.00 ug/l 24840.00 ug/l

9751.00 ug/l 1992.00 ug/l 24450.00 ug/l

197.40 ug/l 99.95 ug/l 99.90 ug/l 99.19 ug/l 9857.00 ug/l

100.20 ug/l 99.93 ug/l 99.71 ug/l 99.12 ug/l 98.97 ug/l 100.10 ug/l 98.18 ug/l 98.64 ug/l 98.85 ug/l 99.05 ug/l 196.50 ug/l ug/l 97.22 ug/l ug/l 96.71 ug/l 195.30 ug/l 196.90 ug/l 196.30 ug/l 195.60 ug/l 97.85 ug/l 95.78 ug/l ug/l ug/l 95.21 ug/l 50.00 90

- 110 0.55 0.61 50.00 50.00 0.44 1250.00 0.62 12500.00 0.28 5000,00 0.82 1000,00 0.32 12500.00 0.66 .100.00 0.82 0.96 0.70 0.26 0.83 0.92 0.16 0.29 1.15 0.15 0.53 0,71 0.60 0.31 0.65

0.97 50.00 50.00 50.00 500.00

50,00 50,00 50.00 50.00 50.00 50,00 50,00 50.00 50,00 50.00 100,00 50.00 50.00 50.00 90

- 110 90

- 110 90 90

- 90

- 90

- 110 110 110 110 90

- 110 90 110 90

- 110 90 110 90 110 90

- 110 90

- 110 90 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90 110 90 110 90

- 110 90

- 110 90

- 110 0.45 0.52 0.12 0.54 0.73 0.92 1.10 50.00 90

- 110

1.34 100.00 100,00 50.00 50.00 50.00 50.00 50.00 #####

- ##### #####

- ##### 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 537987.94 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -115650.49 3684740.30 512384.28 16709469.00

925152.69 324210.50 3528030.30 6520419.50 3350236.30 21373888.00 27624948.00 26691872.00 7.51 0.36 0.20 0.37 17012292.00 0.72 949396.31 1.36 338792.91 0.47 0.49 0.34 3456710.80 6610579.00 3651775.30 0.12 22769202.00 1.35 28649686.00 1.40 27453282.00 Rec(%) QC Range(%) 87.6 101.1 95.2 98.2 97,4 95,7 102.1 98.6 91.7 93.9 96.4 97.2 70 120 70 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120 Flag

I'

. Fa'l Fa'l Fa 1 Fa Fa Fa Fa Fa Fa Fa Fa' F '1 F '1
F il Fil F il Fil F i 1 F il 

### F il 

### F il Fil

F il

F il

F il 

### F il
F il F il

'1

Flag IS Fail

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB D\004CALB.D#

30 :Element Failures

1 ,ISTD Failures



### Data Results: Analytes: ISTD: Fail Fail o :Max. 

### Number of 

### Failures Allowed

o ,Max, Number of ISTD Failures Allowed 

## "t 

# S -g'/,



# '\-:;.2 'I·

9/26/126:11 PM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1

### CCB QC Report

Data File: Date Acquired: Operator: Sample Name: Mise Info: Vial Number: Current Method: Calibration File: Last Cal Update: Sample Type: Total Dil Factor:

QC Elements Element Cone. 7 (Li) 9 Be 0.01 11 B 0.79 23 Na 12.81 24 Mg 12.50 27 Al -0.27 39 K 7.65 44 Ca 3.76 47 Ti 0.17 51 V -0.01 52 Cr 0.00 55 Mn -0.06 56 Fe 0.38 59 Co 0.00 60 Ni -0.07 63 Cu 0.00 65 CU 0.00 66 Zn -0.05 75 As 0.02 78 Se 0.02 78 Se 0.68 88 Sr -0.03 88 Sr 0.02 95 Mo 0.05 106 (Cd) 107 Ag 0.00 108 (Cd) 111 Cd 0.00 118 Sn 0.39 118 Sn 0.15 118 Sn 0.26 121 Sb 0.07 137 Ba 0.01 205 TI 0.01 206 (Pb) 207 (Pb) 208 Pb 0.00

ISTD Blements Element CPS Mean Li -129076.62 45 Sc 3443597.30 45 Sc 515338.28 45 Sc 16949942.00 72 Ge 884837.38 72 Ge 319274.75 72 Ge 3499408.30 115 In 6140074 .00 115 In 3416706.80 115 In 22334394.00 159 Tb 27860248.00 165 Ho 26780708.00

ISTD Ref File :



### :Elemenc Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/26/126:25 PM C,\ICPCIIEM\1\OATA\12I26qOO.B\017_CCB .0\017_CCB .0#

C:\ICPCHEM\1\DATA\12I26qOO.B\017_CCB.D\017_CCB.D# Sep 26 2012 06:21 pm NBS CCB 120926

1102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm CCB 1.00

RSD (%) High Limit ug/l ####### ug/l 175.35 0.12 ug/l 20.15 15.00 ug/l 7.79 77.10 ug/l 152.96 7.50 ug/l 74.80 3.96 ug/l 31.96 19.20 ug/l 267.22 90.00 ug/l 134.86 0.78 ug/l 123.08 0.21 ug/l 191.20 0.12 ug/l 35.73 0.18 ug/l 27.96 40.80 ug/l 335.05 0.09 ug/l 20.53 0.48 ug/l 47494.00 0.39 ug/l 61.08 0.39 ug/l 85.34 6.90 ug/l 7.57 0.27 ug/l 43.78 0.30 ug/l 8.28 0.30 ug/l 116.39 0.03 ug/l 16.72 0.03 ug/l 9.86 0.21 ug/l ####### ug/l 47.19 0.09 ug/l ####### ug/l 310.18 0.06 ug/l 33.80 ####### ug/l 80.69 ####### ug/l 49.64 0.30 ug/l 5.97 0.03 ug/l 54.85 0.12 ug/l 8.23 0.03 ug/l ####### ug/l ####### ug/l 41. 39 0.33

RSD(%) Ref Value Rec(%) QC Range(%)

8.06 -131996.50 97.8 70

- 3.19 3646344.80 94.4 70

- 2.12 537987.94 95.8 70

- 0.60 17012292.00 99.6 70

- 3.54 949396.31 93.2 70

- 1.60 338792.91 94.2 70

- 0.24 3456710.80 101.2 70

- 3.91 6610579.00 92.9 70

- 0.44 3651775.30 93.6 70

- 0.65 22769202.00 98.1 70

- 0.72 28649686.00 97.2 70 1.14 27453282.00 97.6 70 Flag

Fail 

### ,J-("

Fail 

## tJ-(

Fail 

### t'"\

Flag 120 

### IS FaL 

# t1
120 120 120 120 120 120 120 120 120 120 120
C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### Fail Fail :Max. :Max. Number Number of Failures Allowed of ISTD Failures Allowed 

# -- 1

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1C: \ICPCHEM\1\DATA\12126qOO.B\019SMPL.D\019SMPL.DN



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\019SMPL.D\019SMPL.D# Sep 26 2012 06:34 pm Operator: NBS Sample Name: FGD ICS

- Chloride Mise Info: Vial Number: CUrrent Method: Calibration File: Last Cal Update: 3101 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element Cone. Carr. Cone. #VALUE!

-0.02 0.32 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l -0.02 ug/l 0.32 ug/l 2926000.00 ug/l 11.54 ug/l -5.77 ug/l 99.82 ug/l -37.33 ug/l

-0.09 ug/l 0.04 ug/l 0.01 ug/l -0.63 ug/l -4.44 ug/l 0.69 ug/l -0.10 ug/l 0.02 ug/l -0.03 ug/l -3.36 ug/l 0.17 ug/l 0.14 ug/l 1.78 ug/l 4.62 ug/l 4.26 ug/l 0.06 ug/l ug/l 0.16 ug/l ug/l 0.00 ug/l -3.44 ug/l -3.71 ug/l -3.25 ug/l 0.00 ug/l 0.19 ug/l -0.02 ug/l ug/l ug/l -0.02 ug/l 2926000.00 11.54 -5.77 99.82 -37.33 -0.09 0.04 0.01 -0.63 -4.44 0.69 -0.10 0.02 -0.03 -3.36 0.17 0.14 1.78 4.62 4.26 0.06 #VALUE! 0.16 #VALUE! 0.00 -3.44 -3.71 -3.25 0.00 0.19 -0.02 #VALUE! #VALUE!

-0.02

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 537987.94 Li -97970.58 5.63 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 2923316.80 432408.34 12321775.00

725016.50 253589.20 2414153.80 5133755.00 2604404.30 14781928.00 18922060.00 18154954.00 2.52 1.99 3.34 17012292.00 2.15 949396.31 2.74 338792.91 3.28 3456710.80 1.34 6610579.00 2.96 3651775.30 3.47 22769202.00 3.33 28649686.00 3.46 27453282.00 RSD(%)

13 .06 18.17 1.03 16.01 29.80 3.13 22.45 23.95 23.54 102.78

5.50 42.06

1.95 14 .43 35.58 78.93

1.16 3.00 3.36 26.10 0.94 1.38 5.52

2.07

616.04

0.70 0.22 0.11 29.08 10.22 6.15

11.08

Rec(%)

74.2 80.2 80.4 72 .4 76.4 74.9 69.8 77.7 71. 3 64.9 66.0 66.1 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range (%) Flag

>Cal

70 120 Flag IS Fai 70 120 70 120 70 70

- 70

- 70

- 70

- 70 70 70 70 120 120 120 120 IS Fai 120 120 120 IS Fai 

### 01( 120 IS Fai 

### 01<- 120 IS Fai 

## ,..s\

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Elernent Failures 5 :ISTD Failures



### Data Results: Analytes: ISTD:

9/26/12 6:38 PM 

### Fail Failo :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHBM\l\rpttmp\Sample.qct Page 1of 1C,\ ICPCHEM\1\DATA\12126qoO.B\020SMPL.D\020SMPL.Df



### Sample QC Report

Data File: Date Acquired: C,\ICPCHEM\1\DATA\12126qOO.B\020SMPL.D\020SMPL.D# Sep 26 2012 06:41 pm Operator: NBS Sample Name: FGD ICS

- Calcium 

### Mise Info: vial Number: Current Method: Calibration File: Last Cal Update: 3102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type, Prep Oil Factor: Sample 1.00 Total oil Factor: 1.00

QC Elements Element 

### Cone. 7 (Li) Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.03 ug/l 1.10 ug/l 589.90 ug/l 272.90 ug/l

37.44 ug/l 53.83 ug/l 4769000.00 ug/l 7.07 ug/l 1.13 ug/l 3.44 ug/l -0.13 ug/l 106.50 ug/l

0.98 ug/1 7.69 ug/l 9.30 ug/l 9.91 ug/l 29.16 ug/l 4.04 ug/l 0.42 ug/l 3.17 ug/l 43.22 ug/l 42.60 ug/l

0.22 ug/l ug/l 0.07 ug/l ug/l 3.32 ug/l -2.07 ug/l -2.24 ug/l -2.28 ug/l 0.33 ug/l 8.83 ug/l 0.11 ug/l ug/l ug/l 1.08 ug/l

ISTD Elements Element CPS Mean RSD (%) 3.07 0.69 

### Cerro 

### Cone. #VALUEI 0.03 1.10 589.90 272.90

37.44 53.83 4769000.00 7.07 1.13 3.44


# -

-0.13 106.50

0.98 7.69 9.30 9.91 29.16 4.04**~** 0.42 3.17 43.22 42.60

0.22 #VALUEI 0.07 #VALUEI 3.32 -2.07 -2.24 -2.28 0.33 8.83 0.11 #VALUEI #VALUEI 1.08

Ref Value -131996.50 3646344.80 0.44 537987.94 1.72 17012292.00 0.46 949396.31 1.21 338792.91 RSD(%)

22.42 4.69 17 .39

1.66 109.56

6.99 0.46 5.07 0.53 0.66 21.90

2.15 2.40 2.53 0.38 1.31 0.68 3.40 14.19 4.84 0.97 1.69 3.01

2.98

2.00 3.81 2.05 0.71 3.12 1. 81 3.08

1. 88 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70 120 70 120 Flag

,Cal

Flag IS Fai

IS Fai IS Fai IS Fai IS Fai 

# "rr Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -83282.44 3097643.00

425698.88 11544175.00

660715.13 227209.55 2161734.00 4817941.50 2300628.80 1.21 3456710.80 0.44 6610579.00 0.40 3651775.30 1.26 22769202.00 1.48 28649686.00 1.73 27453282.00 Rec(%) 63.1 85.0 79.1 67.9 69.6 67.1 62.5 72.9 63.0 57.9 55.7 55.0 70 70 70

- 70

- 70

- 120 120 120 120 120 

# -t vD- ,1.,.;;1. IS Fai 0 

### k. l-\.'vV' ' 13191882.00 15965009.00 15107971. 00

ISTD Ref File :



### 1 :Element Failures 9 :ISTD Failures



### Data Results: Analytes: ISTD:

9/26/12 6:45 PM IS Fai IS Fai IS Fai 

# tJI

C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D#



### Fail Fail :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1of 1C,\ ICPCHEM\1\DATA\12126qOO.B\021SMPL.D\021SMPL.Dt



### Sample QC Report

Data File, Date Acquired: C,\ICPCHEM\1\DATA\12I26qOO.B\021SMPL.D\021SMPL.DU Sep 26 2012 06,48 pm Operator, Sample Name, 

### Mise Info: NBS FGD ICS

- Sulfate

Vial Number, CUrrent Method, Calibration File, Last Cal Update, Sample Type, 3103 C,\ICPCHEM\l\METHODS\CSC-MDL M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element Conc. Carr. Conc. #VALUE!

-0.01 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l -0.01 ug/l -0.14 ug/l 404.00 ug/l

2.09 ug/l -3.51 ug/l 2894000.00 ug/l 531.00 ug/l

0.03 ug/l 0.06 ug/l 0.12 ug/l -0.80 ug/l -0.13 ug/l 0.02 ug/l -0.01 ug/l 0.75ug/l 0.78 ug/l 0.78 ug/l 0.14 ug/l 3.45 ug/l 3.00 ug/l 0.81 ug/l 0.73 ug/l 1.10 ug/l ug/l 0.00 ug/l ug/l 0.00 ug/l -3.13 ug/l -3.34 ug/l -2.92 ug/l 0.14 ug/l 0.89 ug/l 0.05 ug/l ug/l ug/l 0.01 ug/l -0.14 404.00

2.09 -3.51 2894000.00 531.00

0.03 0.06 0.12 -0.80 -0.13 0.02 -0.01 0.75 0.78 0.78 0.14 3.45

- 3.00

0.81 0.73 1.10 UVALUE! 0.00 UVALUE! 0.00 -3.13 -3.34 -2.92 0.14 0.89 0.05 UVALUE! UVALUE! 0.01

ISTD Elements Element CPS Mean RSD(%) Ref Value 6 Li -103139.68 3.34 -131996.50 45 Sc 2787913.50 1.57 3646344.80 45 Sc 430391.03 1.66 537987.94 45 Sc 11817731.00 1.03 17012292.00 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 660532.75 243915.70 2305505.50 4706154.50 2457743.80 14441559.00 18234338.00 17415250.00 1.62 949396.31 2.08 338792.91 0.72 3456710.80 2.71 6610579.00 0.58 3651775.30 1.56 22769202.00 1.24 28649686.00 0.82 27453282.00 RSD(%) High Limit 

## o 26.45 1000 48.85 1000

2.24 25000 271.02 50000

15.28 20000 0.65 20000 2.99 50000 311.36 1000

4.31 1000 25.09 1000 22.60 1000 1003.80 20000

18.60 90.57 2.11 4.55 11.37 8.09 10.98 8.16 4.29 4.62 2.61

44.94

294.99

0.35 0.56 0.44 3.12 4.26 16.15

8.53

Rec(%)

78.1 76.5 80.0 69.5 69.6 72 .0 66.7 71.2 67.3 63.4 63.6 63.4 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### #UUU#U# 500 

### #UU##U# 1000 

### UUUU#UU UUUUU#U 1000 1000 1000 1000 

### UU#UU#U UUUU#U# 1000

QC Range(%) 70

- 120 70

- 120 70 120 70

- 120 70

- 120 70 120 70 120 70

- 120 70 120 70

- 120 70 120 70 120 Flag

,Cal

Flag IS Fai

IS Fai IS Fai

IS Fai

IS Fai IS Fai IS Fai IS Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU



### :Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD:

9/26/126:51 PM 

### Fail Fail :Max. Number of Failures Allowed 'Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

### c,\ICPCHEM\l\DATA\12126qOO.B\022SMPL.D\022SMPL.Df



### Sample QC Report

Data File, Date Acquired, 

### Operator: C,\ICPCHEM\1\DATA\12I26qOO.B\022SMPL.D\022SMPL.Dn Sep 26 2012 06,54 pm NBS FGD ICS

- Magnesium Sample Name, 

### Mise Info: vial Number: CUrrent Method, 

### Calibration File: Last Cal Update, Sample Type, 3104 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total oil Factor: 1.00 1.00

QC Blements Element 

### Cone. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 

### v 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.04 ug/l 2.10 ug/l 337.70 ug/l 2880000.00 ug/l 150.80 ug/l 441.20 ug/l 330.10 ug/l

33.76 ug/l 2.14 ug/l 3.09 ug/l 102.00 ug/l 68.45 ug/l 0.10 ug/l 4.20 ug/l 9.38 ug/l 9.27 ug/l 8.95 ug/l 1.11 ug/l 0.14 ug/l 2.57 ug/l -0.24 ug/l -0.05 ug/l 0.08 ug/l ug/l 0.06 ug/l ug/l 0.05 ug/l -1.75 ug/l -1.88 ug/l -2.06 ug/l 0.41ug/l 0.58 ug/l 0.08 ug/l ug/l ug/l 1.69 ug/l

ISTD Elements Cerro Cone. nVALUE! 0.04 2.10 337.70 2880000.00 150.80 441.20 330.10 33.76

2.14 3.09 102.00 68.45 0.10 4.20 9.38 9.27 8.95 

# 2.2-L 0.14 2.57 -0.24 -0.05 0.08 nVALUE! 0.06 nVALUE! 0.05 -1.75 -1.88 -2.06 0.41 0.58 0.08 nVALUE! nVALUE! 1.69 RSD(%)

97.32

7.97 19.52 0.95 124.60 20.79 7.64 1.02 3.60 4.18 0.62 1.16 6.95 1.09 0.90 2.44 2.02 2.98 4.65 2.99 6.77 89.20 16.44

6.40

50.30 3.32 2.46 1.78 4.25 8.06 2.97

2.71 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

# nnnnnnn 500 

# nnnnnnn 1000 

# nnnnnnn nnnnnnn 1000 1000 1000 1000 

# nnnnnnn nnnnnnn 1000 Flag

>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Rec(%) QC Range(%) Flag 6 Li -109873.66 8.12 45 Sc 3335598.50 1.49 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 470870.91 13922356.00

822159.63 280261.97 2701303.00 5375041.50 2589054.50 16211134.00 21408504.00 20714622.00 1.22 537987.94 2.31 17012292.00 0.92 949396.31 1.66 338792.91 1.42 3456710.80 0.49 6610579.00 0.13 3651775.30 1.94 22769202.00 2.97 28649686.00 3.09 27453282.00 83.2 70 120 IS Fai 91.5 70 120 87.5 81.8 86.6 82.7 78.1 81.3 70.9 71.2 74.7 75.5 70 120 70

- 120 70

- 120 70

- 120 70 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn



### :Element Failures :Max. Number of Failures Allowed 1 ,ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/26/126.58 PM C,\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

### c:\ICPCHEM\1\DATA\12126qOO.B\02JSMPL.0\02JSMPL.D#



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\023SMPL.D\023SMPL.DU Sep 26 2012 07:01 pm Operator: NBS Sample Name: FGD ICS

- Sodium Mise Info: Vial Number: current Method: 

### Calibration File: Last Cal Update: 3105 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Oil Factor: 1.00 Total Oil Factor: 1.00

QC Elements 

### Element Cone. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.08 ug/l -0.17 ug/l 1773000.00 ug/l 249.00 ug/l

-1.01 ug/l 296.40 ug/l 303.40ug/l

0.33 ug/l 1.58ug/l 0.37 ug/l -0.85 ug/l 17.00 ug/l 0.04 ug/l 0.28 ug/l 0.42 ug/l 0.40 ug/l 8.15 ug/l 0.86 ug/l 0.16 ug/l 2.58 ug/l 1.03 ug/l 1.10 ug/l 0.10ug/l ug/l 0.05 ug/l ug/l 0.10 ug/l -1.51 ug/l -1.60 ug/l -1.61 ug/l 0.49 ug/l 0.40 ug/l 0.02 ug/l ug/l ug/l 0.17 ug/l

ISTD Elements Carr. Cone. UVALUE! 0.08 -0.17 1773000.00 249.00

-1.01 296.40 303.40

0.33 1.58 0.37 -0.85 17.00 0.04 0.28 0.42 0.40 8.15 0.86 0.16 2.58 1.03 1.10 0.10 UVALUE! 0.05 UVALUE! 0.10 -1.51 -1. 60 -1.61 0.49 0.40 0.02 UVALUE! UVALUE! 0.17 RSD (%)

2.49 31.36 0.88 1.54 40.82

2.83 4.27 31.09 0.74 3.95 4.28 26.14

3.43 6.99 13 .51 26.22

1.62 0.80 7.41 15.28 7.32 7.09 12.16

7.76

24.03

6.27 7.38 5.93 5.45 10.89 21.61

9.40 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000 Flag

:>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 Rec(%) 73.7 85.4 81.0 78.8 85.5 84.1 78.4 79.0 70.5 70.1 70.5 70.9 QC Range (%) Flag Li -97277.94 7.98 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3114489.00 436024.88 13410355.00

811870.75 284784.84 2710904.00 5222633.00 2574462.80 15969458.00 20204874.00 19470320.00 1.09 3646344.80 1.51 537987.94 6.38 17012292.00 2.82 949396.31 1.63 338792.91 3.90 3456710.80 1.016610579.00 1.16 3651775.30 7.04 22769202.00 8.32 28649686.00 8.09 27453282.00 70

- 120 IS Fai 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70 70

- 70 70

- 120 120 120 120 120 120 120 120 120 120 120

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU



### :Element Failures :Max. Number of Failures Allowed :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9126112 7:05 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1C,\ICPCIIEM\l\DATA\12126qOO.B\0245MPL.D\0245MPL.D'



### Sample QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I26qOO.B\024SMPL.D\024SMPL.D# Sep 26 2012 07,08 pm NBS Sample Name: FGD ICS

- Boron Mise Info: Vial Number, Current Method, Calibration File: Last Cal Update, Sample Type, 3106 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 

### V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 7B Se 7B Se BB Sr BB Sr 95 Mo 106 (Cd) 107 Ag lOB (Cd) 111 Cd 11B Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb Cone. ug/l 0.00 ug/l 474200.00 ug/l 347.40 ug/l

53.09 ug/l 3.96 ug/l 74.70 ug/l 344.60 ug/l

0.04 ug/l 0.53 ug/l 0.04 ug/l -1.17 ug/l -4.14 ug/l -0.01 ug/l -0.03 ug/l 2.45 ug/l 2.39 ug/l 3.80 ug/l 0.21 ug/l 0.03 ug/l 1.17 ug/l -0.20 ug/l -0.15 ug/l 0.07 ug/l ug/l 0.01 ug/l ug/l -0.01 ug/l -2.65 ug/l -2.83 ug/l -2.65 ug/l 0.18 ug/l 0.00 ug/l 0.01 ug/l ug/l ug/l -0.01 ug/l

ISTD Elements Carr. Conc. #VALUE! 0.00 474200.00 347.40

53.09 3.96 74.70 344.60

0.04 0.53 0.04 -1.17 -4.14 -0.01 -0.03 2.45 2.39 3.80 0.21 0.03 1.17 -0.20 -0.15 0.07 #VALUEJ 0.01 #VALUE!

-0.01 -2.65 -2. B3 -2.65 0.18 0.00 0.01 #VALUE! #VALUEJ

-0.01 RSD(%)

193.78

0.60 1.55 4.81 14.76 2.15 73.97 102.30

7.45 13 .38 0.61 1.28 21.11 32.76

1.31 2.71 4.95 9.04 34.68 4.31 5.48 3.36 8.62

25.58

27.42

0.50 0.79 0.45 3.24 637.20

27.14

17.99 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Rec (%) 91.4 101.3 92.2 QC Range (%) Flag Li -120613.04 3.31 70 120 IS Fai 45 Sc 3693170.50 0.72 70 120 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 495B89.19 17132572.00

878855.44 303641.69 3229729.50 6438535.50 3274603.00 23372748.00 28895424.00 27893406.00

ISTD Ref File ,

:Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD:

9/26/127:12 PM 1.53 537987.94 0.66 17012292.00 1.43 949396.31 0.30 338792.91 1.09 3456710.80 0.80 6610579.00 0.58 3651775.30 0.73 22769202.00 0.30 28649686.00 0.25 27453282.00 100.7 92 .6 89.6 93.4 97.4 89.7 102.7 100.9 101.6 70 120 70 120 70

- 120 70

- 120 70 70 70

- 70

- 70 70 120 120 120 120 120 120
C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### Fail Fail o :Max. Number of Failures Allowed 

## o ,Max. Number of ISTD Failures Allowed

C,\ICPCHEM\l\rpttmp\Sampla.qct Page 1of 1C,\ICPCIIEM\l\DATA\12I26qOO .•\02SSMPL.D\02SSMPL.Df



### Sample QC Report

Dat.a File: Date Acquired: C:\lCPCHEM\1\DATA\12I26qOO.B\025SMPL.D\025SMPL.Dn Sep 26 2012 07:+5 pm Operat.or: NBS Sample Name: FGD lCS - Iron Mise Info: Vial Number: Current Method: Calibration File: Last Cal Update: 3107 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALlB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep oil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element Cone. Cerro Cone. nVALUEI 0.01 1938.00

176.90

8.03 1.50 60.21 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.01 ug/l 1938.00 ug/l 176.90 ug/l

8.03 ug/l 1.50 ug/l 60.21 ug/l 331.60 ug/l

0.21 ug/l 0.68 ug/l 1.11ug/l 6.76 ug/l 458500.00 ug/l 6.65 ug/l 4.55 ug/l 2.64 ug/l 2.61 ug/l 11.18 ug/l 0.71 ug/l 0.04 ug/l 1.39 ug/l 4.81ug/l -0.19 ug/l 0.34 ug/l ug/l 0.03 ug/l ug/l 0.00 ug/l -1.60 ug/l -1.75 ug/l -1.94 ug/l 0.84 ug/l 0.08 ug/l 0.00 ug/l ug/l ug/l 0.01 ug/l 331.60 0.21 0.68 1.11 6.76 458500.00 6.65 4.55 2.64 2 .61 11.18 0.71 0.04 1. 39 4.81 -0.19 0.34 nVALUE I 0.03 nVALUEI 0.00 -1.60 -1. 75 -1.94 0.84 0.08 0.00 nVALUEI nVALUEI 0.01

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Li -98050.09 3.92 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3512328.50 477275.06 14471162.00 1409565.60 553576.31 7064350.50 6209121.00 3045038.50 19537344.00 24922826.00 24244648.00 0.91 3.14 537987.94 0.32 17012292.00 0.50 949396.31 0.58 338792.91 1.24 3456710.80 0.76 6610579.00 0.74 3651775.30 0.39 22769202.00 1.21 28649686.00 0.32 27453282.00 RSD(%)

79.71

1.37 18.97 18.58 40.55

7.80 14.94 37.72 4.40 28.43 3.02 1.91 2.80 4.17 6.10 6.72 1.79 5.66 22.77 13.94 182.68

4.27 5.00

5.86

127.00

3.66 2.73 0.30 2.35 16.34 4.26

6.78

Rec(%)

74.3 96.3 88.7 85.1 148.5 163.4 204.4

93.9 83.4 85.8 87.0 88.3 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

# nnnnnnn 500 

# nnnnnnn 1000 

# nnnnnnn nnnnnnn 1000 1000 1000 1000 

# nnnnnnn nnnnnnn 1000 Flag

>Cal

>Cal

QC Range (%) Flag 70 120 IS Fai 70

- 120 70 70

- 70 70 70 70 120 120 120 120 120 120 70

- 120 70 120 70 120 70

- 120 IS Fai IS Fai IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn

:Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD:

9/26/12 7: 18 PM 

### Fail Failo :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1C,\ICPCHEM\l\DATA\12I26qOO. 8\026SMPL.D\026SMPL.**D~**


### Sample QC Report

Data File: Date Acquired: C,\ICPCHEM\1\DATA\12126qOO.B\026SMPL.D\026SMPL.DU Sep 26 2012 07,21 pm Operator: NBS Sample Name: FGD ICS

- Nitrate 

### Mise Info: vial Number: Current Method: 

### Calibration File: Last Cal Update: 3108 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element 

### Cone. Corr. Cone. 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 

## v 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu .66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.01 ug/l 1689.00 ug/l 365000.00 ug/l 2.44 ug/l -2.72 ug/l 161.60 ug/l 297.10 ug/l

0.22 ug/l 0.50 ug/l 0.18 ug/l -0.90 ug/l 49.33 ug/l

0.15 ug/l 0.29 ug/l 0.75ug/l 0.74 ug/l 10.68 ug/l 0.34 ug/l 0.06 ug/l 1.27 ug/l 0.09 ug/l 0.13 ug/l 0.13 ug/l ug/l 0.02 ug/l ug/l 0.05 ug/l -2.12 ug/l -2.18 ug/l -2.22 ug/l 0.51 ug/l 0.61 ug/l 0.00 ug/l ug/l ug/l 0.07 ug/l UVALUE! 0.01 1689.00 365000.00 2.44 -2.72 161.60 297.10

0.22 0.50 0.18 -0.90

### ~ 0.15 0.29 0.75 0.74 10.68 0.34 0.06 1.27 0.09 0.13 0.13 UVALUE! 0.02 UVALUE! 0.05 -2.12 -2.18 -2.22 0.51 0.61 0.00 UVALUE! UVALUE! 0.07

ISTD Elements Element Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho CPS Mean RSD (%) -89100.86 0.41 3305611.00 1.92 Ref Value -131996.50 3646344.80 446707.13 14388429.00

857193.38 295294.19 2875063.00 5955676.00 2976431.80 18980878.00 24611324.00 23737788.00 0.51 537987.94 1.67 17012292.00 1.79 949396.31 1.08 338792.91 1.29 3456710.80 1.21 6610579.00 0.75 3651775.30 1.95 22769202.00 1.89 28649686.00 1.27 27453282.00 RSD(%)

55.06

0.61 1.03 13.53 12.41 0.74 3.03 110.60

2.79 7.27 1.87 9.10 4.39 0.31 4.45 2.52 3.33 5.72 4.90 11.39 30.50

9.56 7.65

1.69

15.25

1.36 2.14 0.93 1.46 2.32 39.21

5.90

Rec(%)

67.5 90.7 83.0 84.6 90.3 87.2 83.2 90.1 81.5 83.4 85.9 86.5 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000 

# rJ1

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000

QC Range (%) 70 120 70

- 120 70 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 70 70 120 120 120 Flag

>Cal >Cal

Flag IS Fai

ISTD Ref File: C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.DU

:Element Failures 0 :Max. Number of Failures Allowed :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/26112 7:25 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1C,\ICPCHEM\l\DATA\12I26qOO .B\027SMPL.D\027SMPL.D#



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\027SMPL.D\027SMPL.D# Sep 26 2012 07:28 pm Operator: NBS Sample Name: FGD ICS

- Manganese Mise Info: Vial Number: Current Method: Calibration File: Last Cal Update: 3109 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 se 78 se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb Conc. ug/l -0.02 ug/l 1536.00 ug/l

90.59 ug/l

5.48 ug/l 44.41 ug/l 114.40 ug/l -23.69 ug/l

0.21 ug/l 0.40 ug/l 0.25 ug/l 192900.00 ug/l 6.95 ug/l 0.73 ug/l 0.36 ug/l 0.45 ug/l 0.39ug/l -0.22 ug/l 0.24 ug/l 0.07 ug/l 0.93 ug/l -0.39 ug/l -0.29 ug/l

1.71ug/l ug/l 0.03 ug/l ug/l -0.01 ug/l -1.74 ug/l -1.82 ug/l -2.05 ug/l 0.43 ug/l 0.02 ug/l -0.02 ug/l ug/l ug/l 

## o.05 ug/l

ISTD Elements Carr. Conc. #VALUE!

-0.02 1536.00

90.59

5.48 44.41 114.40 -23.69

0.21 0.40 0.25 192900.00 6.95 0.73 0.36 0.45 0.39 -0.22 0.24 0.07 0.93 -0.39 -0.29

1.71 #VALUE! 0.03 #VALUE!

-0.01 -1.74 -1.82 -2.05 0.43 0.02 -0.02 #VALUE! nVALUE! 0.05

Element CPS Mean RSD(%) Ref ValUe 6 Li -96080.56 2.74 -131996.50 45 Sc 3330538.00 0.23 3646344.80 45 Sc 442001.22 0.88 537987.94 45 Sc 14493612.00 2.21 17012292.00 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 1009336.00 312663.88 2967031.00 6114611.00 3008750.50 19826062.00 25590550.00 24755814.00 0.29 0.86 949396.31 338792.91 2.19 3456710.80 0.82 6610579.00 0.18 3651775.30 2.36 22769202.00 1.90 28649686.00 2.85 27453282.00 RSD (%)

10.58 2.55 7.85 5.19 2.92 9.68 17.47 50.19

1.03 4.36 0.86 11.20 1.43 15.59 4.21 3.47 4.64 4.57 22.06 10.91

1.33 1.78 0.64

4.40

41.73

2.12 6.13 7.67 4.81 116.90

8.08

2.12

Rec (%)

72.8 91. 3 82.2 85.2 106.3 92 .3 85.8 92.5 82.4 87.1 89.3 90.2 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

# nnnnnnn 500 

# nnnnnnn 1000 

# nnnnnnn nnnnnnn 1000 1000 1000 1000 

# #nnn#nn nnnnnnn 1000

QC Range(%) 70 120 70 120 70

- 120 70 120 70 120 70 120 70 120 70 120 70 120 70 120 70 120 70 120 Flag

,Cal

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn

2 :Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/26/12 7:32 PM 

### Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C,\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1C,\ICPCHEM\l\CATA\12I26qOO .B\029_CCV.C\029_CCV.CI



### CCV QC Report

Data File, Date Acquired, Operator, Sample Name, 

### Mise Info: C,\ICPCHEM\1\DATA\12I26qOO.B\029_CCV.D\029_CCV.D# Sep 26 2012 07,41 pm NBS CCV 120926

Vial Number, current Method, 

### Calibration File: 1106 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Last Cal update, Sample Type, Total Dil Factor, CCV 1.00

QC B1ements 

### Element (Li) Cone. ug/l 97.00 ug/l 1248.00 ug/l 2587.00 ug/l 24970.00 ug/l

9738.00 ug/l 2102.00 ug/l RSD (%) Expected QC Range (%) 50.00 90

- 110 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 cr 55 Mn 56 Fe 59 Co 60 Ni 63 cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 24880.00 ug/l 197.70 ug/l 101.50 ug/l 101.20 ug/l 103.60 ug/l 10000.00 ug/l

101.30 ug/l 101.20 ug/l 101.70 ug/l 101.80 ug/l 100.30 ug/l 98.93 ug/l 101.40 ug/l 97.31 ug/l 101.00 ug/l 101.80 ug/l 197.90 ug/l ug/l 98.45 ug/l ug/l 99.08 ug/l 206.70 ug/l 201.10 ug/l 200.90 ug/l 199.30 ug/l 102.40 ug/l 100.00 ug/l ug/l ug/l 100.80 ug/l 3.12 50.00 90

- 110 90

- 110 90 110 90

- 110 3.47 50.00

90 110 0.32 1250.00 1.37 12500.00 0.255000.00 

## o .72 1000.00 1.04 12500.00 2.29 100.00 1.09 0.59 1.29 0.46 l.20 1.19 0.72 0.75 0.93 1.06 1.96 0.91 0.90 2.57 2.01 50.00 50.00 50.00 500.00 90

- 110 90

- 110 90 110 90

- 110 90 110 90

- 110 90

- 110

2.20

2.31 2.14 0.64 2.39 2.90 2.70 l.82

2.36 50.00 90 50.00 90 50.00 90- 50.00 90 50.00 90- 50.00 90 50.00 90 50.00 90 50.00 90 50.00 90 100.00 90- 50.00 90 50.00 90 50.00 90- 50.00 90 ##### ##### 100.00 90

- 100.00 90- 50.00 90 50.00 90 50.00 90 50.00 90 50.00 90 110 110 110 110 110 110 110 110 110 110 110 110 110 110 110 ##### #####

110 110 110 110 110 110 110

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 537987.94 6 Li 45 SC 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -107346.35 3565577.30 496672 .25 16040120.00

913231.31 321271.00 3443301.00 6503246.00 3332759.50 21510152.00 27763568.00 26929486.00 0.63 1.59 1.03 2.44 17012292.00 0.68 949396.31 1.12 338792.91 1.69 3456710.80 1.62 6610579.00 0.70 3651775.30 2.61 22769202.00 2.39 28649686.00 2.59 27453282.00 Rec(%) QC Range(%) 81.3 70

- 120 97.8 70 120 92.3 70

- 120 94.3 96.2 94.8 99.6 98.4 91.3 94.5 96.9 98.1 70 120 70 120 70 120 70 120 70 120 70 120 70

- 120 70 120 70 120 Flag

Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail

Fail

Fail

Fail Fail Fail Fail

Fail

Flag IS Fail

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### 30 :Element Failures

1 ,ISTD Failures



### Data Results: Analytes: 

### ISTD: Fail Failo :Max. 

### Number of Failures Allowed 

## o ,Max. Number of ISTD Failures Allowed 

### 101 '/'



# or**~,q** 

# '/,
101.4 '/'



### IUV .,.

9/26/12 7:45 PM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1of 1

### c: \ICPCHEM\1\DATA\12126qOO.B\Oll_CCB,D\031_CCB.D'



### CCB QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12126qOO.B\031_CCB.D\031_CCB.DU Sep 26 2012 07,54 pm
Sample Name, Mise Info: NBS CCB 120926

Vial Number, CUrrent Method, Calibration File: Last Cal Update, Sample Type, Total Dil Factor: 1102 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm CCB 1.00

QC Elements Element Cone. RSD(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.00 ug!l 836.50 ug/l

16.37 ug/l 0.83 ug/l -0.09 ug/l 37.24 ug/l -12.51 ug/l

0.04 ug/l -0.02 ug/l 0.00 ug/l 0.71 ug/l O.78ug/l 0.00 ug/l -0.07 ug/l 0.06 ug/l 0.03 ug/l -0.04 ug/l 0.03 ug/l 0.03 ug/l 0.83 ug/l -0.02 ug/l -0.01 ug/l 0.05 ug/l ug/l 0.00 ug/l ug/l 0.00 ug/l 0.48 ug/l 0.38 ug/l 0.18 ug/l 0.07 ug/l 0.00 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l 665.60 0.51 13 .48 7.51 205.54

22.89 22.85 67.72 36.33 98.91 12.57 15.39 170.93 28.37 28.11 11.58 192.69 32.39 59.60 11.03 17.32 42.55 11.96

838.79

53.54 90.90 14.15 40.79

5.75 142.06 38.75

93.82

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -118087.91 12.60 3640759.00 0.58

501826.38 17409780.00

937541.81 319426.91 3611899.00 6779286.50 3409012.30 23946008.00 29768486.00 28770254.00 0.87 537987.94 0.69 17012292.00 0.69 949396.31 0.48 338792.91 1.16 3456710.80 0.60 6610579.00 1.34 3651775.30 0.72 22769202.00 1.04 28649686.00 1.26 27453282.00 High Limit 

# uuuuuuu 0.12 15.00 77.10 7.50 3.96 19.20 90.00 0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 

# uuuuuuu 0.09 

# uuuuuuu 0.06 

# uuuuuuu uuuuuuu 0.30 0.03 0.12 0.03 

### UUUUUUU UUUUUUU 0.33

Rec(%) QC Range(%)

89.5 70

- 120 120 99.8 70 93.3 102.3 98.8 94.3 104.5 102.6 93.4 105.2 103.9 104.8 70

- 120 70 120 70

- 120 70 120 70 120 70 120 70

- 120 70 120 70

- 120 70 120 Flag

Fail 

# ,;<

Fail

Fail

Fail

Fail 

# tJ"\

Flag IS FaL

ISTD Ref File, C,\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.DU

5 ,Element Failures 0 ,Max. Number of Failures Allowed 1 ,ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/26/127:58 PM C,\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1C,\ICPCHEM\l\OATA\12I26qOO.B\032SKPL.O\OJ2SKPL.

# 0,

Sample QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I26qOO.B\032SMPL.D\032SMPL.D# Sep 26 2012 08,01 pm
Sample Name, 

### Mise Info: NBS FGD ICS

- Bromide

Vial Number, CUrrent Method: Calibration File, Last Cal Update, Sample Type, 3110 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor: 1.00 Total Dil Factor, 1.00

QC Blements Element 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Cone. ug/l -0.02 ug/l 872.70 ug/l 66.72 ug/l -2.11 ug/l -4.92 ug/l 44240.00 ug/l

-22.27 ug/l

0.01 ug/l 0.67 ug/l 0.12 ug/l -0.18 ug/l 0.70 ug/l -0.03 ug/l 0.01 ug/l 0.13 ug/l 0.09 ug/l -0.16 ug/l 0.35 ug/l 0.25 ug/l 0.89 ug/l -0.43 ug/l -0.34 ug/l

1.68 ug/l ug/l 0.01 ug/l ug/l -0.01 ug/l -0.57 ug/l -0.80 ug/l -1.63 ug/l 1.76 ug/l 0.03 ug/l -0.01 ug/l ug/l ug/l 0.00 ug/l 

### Carr. Cone. #VALUEI

-0.02 872.70 66.72 -2.11 -4.92 44240.00

-22.27

0.01 0.67 0.12 -0.18 0.70 -0.03 0.01 0.13 0.09 -0.16 0.35 0.25 0.89 -0.43 -0.34 1.68 #VALUEI 0.01 #VALUEI

-0.01 -0.57 -0.80 -1.63 1.76 0.03 -0.01 #VALUE I #VALUEI 0.00 RSD(%) High Limit 

## o 6.67 1000 0.85 1000 14.14 25000 18.89 50000 10.97 20000

1.53 20000 35.21 50000 627.06 1000

1.43 1000 8.58 1000 5.95 1000 20.77 20000 6.22 1000 495.02

4.37 7.93 25.57

3.39 7.17 17.10 2.66 0.87 1.69

12.26

12.22 15.31 16.52 2.56 0.19 43.76

7.29

199.10 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Rec(%) 72 .1 94.9 87.4 94.9 97.5 96.1 89.3 99.3 90.3 98.9 QC Range (%) Flag 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -95216.25 3460578.50 470243.56 16152620.00

925292

.56 325558.84 3086042.00 6562977.50 3297406.50 22512394.00 28717122.00 27692346.00

ISTD Ref File,



### 1 :Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/26/12 8:05 PM 3.60 0.69 1.34 537987.94 1.40 17012292.00 1.44 949396.31 1.00 338792.91 1.24 3456710.80 1.30 6610579.00 1.47 3651775.30 0.58 22769202.00 0.53 26649666.00 0.34 27453262.00 100.2 100.9 70

- 120 IS Fai 70 120 70

- 120 70 120 70 120 70 120 70

- 120 70 120 70 120 70 120 70 120 70

- 120
C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### Fail Fail

## o ,Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1C,\ICPCIIEM\l\OATA\12Il6QOO.8\0335MPL.0\0335MPL.011



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12126qOO.B\033SMPL.D\033SMPL.D# Sep 26 2012 08:08 pm Operator: NBS Sample Name: FGD ICS

- Fluoride Mise Info: Vial Number: current Method: Calibration File: Last Cal Update: 3111 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Elements 

### Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb Cone. ug/l -0.01 ug/l 896.00 ug/l 113500.00 ug/l -0.12 ug/l 7.72 ug/l 153.10 ug/l -28.01 ug/l

1.32 ug/l 0.64 ug/l 0.19 ug/l -0.07 ug/l -1.11 ug/l 0.07 ug/l 0.09 ug/l 0.18 ug/l 0.15 ug/l 0.03 ug/l 0.57 ug/l 0.27 ug/l 0.93 ug/l -0.38 ug/l -0.29 ug/l 0.09 ug/l ug/l 0.02 ug/l ug/l 0.16 ug/l -1.08 ug/l -1.03 ug/l -1.50 ug/l 0.79 ug/l 0.26 ug/l -0.01 ug/l ug/l ug/l 0.24 ug/l

lSTD Elements Carr. Conc. #VALUE!

-0.01 896.00 113500.00 -0.12 7.72 153.10 -28.01

1.32 0.64 0.19 -0.07 -1.11 0.07 0.09 0.18 0.15 0.03 0.57 0.27 0.93 -0.38 -0.29 0.09 #VALUE! 0.02 #VALUE! 0.16 -1.08 -1. 03 -1.50 0.79 0.26 -0.01 #VALUE! #VALUE! 0.24 RSD(%) High Limit 

## o 12.71 1000 5.72 1000 0.75 25000 189.13 50000

3.82 20000 3.92 20000 34.35 50000 12.77 1000 2.16 1000 2.39 1000 37.47 1000 10.51 20000 11.09 27.35 1000 1000 5.15 1000 14 .12 1000 164.17 1000

4.79 1000 8.95 1000 12.52 1000 2.63 1000 2.38 1000 10.99 1000 ####### 5.33 500 ####### 9.13 1000 3.31 ####### 6.25 ####### 8.11 1000 3.01 1000 15.23 1000 10.49 1000 ####### ####### 6.20 1000 Flag

>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80

537987.94 Rec(%) 63.4 99.2 88.0 91. 8 QC Range(%) Flag Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -83713.09 3615403.50 473218.03 15619648.00 1052588.40 355182.38 3259586.80 6749887.00 3311883.00 21659004.00 27423886.00 26467844 .00

ISTD Ref File :



### :Element Failures

:ISTD Failures



### Data Results: Analytes: 

### ISTD:

9/26/128:12 PM 5.76 1.52 1.26 4.95 17012292.00 1.30 949396.31 0.74 338792.91 3.65 3456710.80 0.59 6610579.00 0.35 3651775.30 4.54 22769202.00 6.01 28649686.00 5.94 27453282.00 110.9 104.8 94.3 102.1 90.7 95.1 95.7 96.4 70

- 120 IS Fai 70 120 70

- 120 70

- 120 70 120 70 120 70

- 120 70 70 70 70 70 120 120 120 120 120
C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D#



### Fail Failo :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\lCPCHEM\l\rpttmp\Sample.qct Page 1 of 1C,\ICPCHEM\l\OATA\12I26qOO.B\OHSMPL.O\OHSMPL.

# 0,

Sample QC Report

Data File, Date Acquired: C,\ICPCHEM\1\DATA\12126qOO.B\034SMPL.D\034SMPL.D# Sep 26 2012 08,15 pm Operator: NBS Sample Name: FGD ICS

- Selenium Mise Info: Vial Number: Current Method: Calibration File: Last Cal Update, Sample Type, Prep Dil Factor: 3112 C,\ICPCHEM\l\METHQDS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample 1.00 Total Dil Factor: 1.00

QC Elements Element Cone. carr. Cone. #VALUE:!

-0.02 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb ug/l -0.02 ug/l 706.70 ug/l

83.22 ug/l -1.75 ug/l -5.06 ug/l 141.40 ug/l -24.59 ug/l

0.01 ug/l 0.71 ug/l 0.15 ug/l -0.09 ug/l -1.79 ug/l -0.02 ug/l -0.01 ug/l 0.09 ug/l 0.07 ug/l 0.17 ug/l 0.38 ug/l 21980.00 ug/l 20210.00 ug/l -0.41 ug/l -0.33 ug/l 0.06 ug/l ug/l 0.01 ug/l ug/l -0.03 ug/l -0.38 ug/l -1.02 ug/l -1.76 ug/l 0.47 ug/l 0.05 ug/l -0.02 ug/l ug/l ug/l 0.00 ug/l 706.70 83.22 -1.75 -5.06 141.40 -24.59

0.01 0.71 0.15 -0.09 -1.79 -0.02 -0.01 0.09 0.07 0.17 0.38 21980.00 20210.00 -0.41 -0.33 0.06 #VALUE! 0.01 #VALUE!

-0.03 -0.38 -1.02 -1.76 0.47 0.05 -0.02 #VALUE! #VALUE! 0.00

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996 .50 3646344.80 537987.94 Li -91518.63 15.22 45 Sc 3260116.00 7.82 45 Sc 463591.81 0.91 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 16695750.00 1114728.00 389775.25 3626899.00 6288215.50 3356181.50 23250030.00 28815582.00 28013624.00 3.38 17012292.00 4.00 949396.31 1.02 338792.91 0.62 3456710.80 6.29 6610579.00 0.42 3651775.30 2.51 22769202.00 2.49 28649686.00 1.40 27453282.00 RSD(%)

10.64 2.77 2.32 6.86 3.29 3.22 13.97 542.12

1.38 10.44 10.28 4.25 11.13 88.90 18.31 17.55 11.16 4.62 6.68 0.42 3.52 1.40 18.37

18.32

22.06 65.63 2.38 0.55 2.27 26.69

3.94

81.37

Rec(%)

69.3 89.4 86.2 98.1 117.4 115.0 104.9 95.1 91.9 102.1 100.6 102.0 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 Flag

>Cal >Cal

QC Range(%) Flag 70 120 IS Fai 70

- 120 70

- 120 70

- 120 70

- 120 70 120 70 120 70 120 70

- 120 70 70 70

- 120 120 120

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures 0 :Max. Number of Failures Allowed ,ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/26/128:18 PM C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1C,\ICPCHEM\l\DATA\12I36qOO.B\035SMPL.D\035SMPL.D#



### Sample QC Report

Data File, Date Acquired, Operator: C:\ICPCHEM\1\DATA\12I26qOO.B\035SMPL.D\035SMPL.DU Sep 26 2012 08:21 pm
Sample Name, 

### Mise Info: NBS FGD ICS

- Vanadium

Vial Number, Current Method, 

### Calibration File: Last Cal Update, Sample Type, Prep Dil Factor: 3201 C,\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample l.00 Total Dil Factor: 1.00

QC Elements Element 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Cone. ug/l 0.02 ug/l 573.20 ug/l

19.88 ug/l 2.60 ug/l -0.05 ug/l 49.15 ug/l 96 .45 ug/l 0.25 ug/l 10320.00 ug/l 0.29 ug/l 2.10 ug/l 1.18 ug/l 0.05 ug/l 0.08 ug/l 0.12 ug/l 0.11 ug/l 4.31 ug/l 0.13 ug/l 9.64 ug/l 8.12 ug/l -0.15 ug/l -0.10 ug/l 0.05 ug/l ug/l 0.26 ug/l ug/l 0.04 ug/l -0.41 ug/l -0.42 ug/l -0.50 ug/l 0.32 ug/l 0.07 ug/l 0.05ug/1 ug/l ug/l 0.05 ug/l 

### Carr. cone. #VALUEi 0.02 573.20

19.88 2.60 -0.05 49.15 96.45 0.25 10320.00 0.29 2.10 1.18 0.05 0.08 0.12 0.11 4.31 0.13 9.64 

# --a:rr -0.15 -0.10 0.05 UVALUE! 0.26 UVALUE! 0.04 -0.41 -0.42 -0.50 0.32 0.07 0.05 UVALUE! UVALUE! 0.05 RSD(%) High Limit 

## o 26.29 1000

1.10 1000 18.06 25000 23.16 50000 977.78 20000 22.32 20000 1l.37 50000 140.94 1000

1.99 1000 10.53 1000 3.44 1000 84.04 20000

8.31 1000 3l.70

8.83 8.30 l.35 15.54 2.92 8.60 13.94 5.00 6.67

l. 99

25.84 11.88 11.74 2.29 2.03 11.34 6.09

4.29 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### .UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000 Flag

>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 Rec (%) 79.6 100.9 93.6 103.0 98.6 94.6 105.0 105.7 QC Range(%) Flag 6 Li -105046.50 6.86 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3678947.00 503759.44 17528172.00

935870.19 320547.00 3630231.30 6987954.50 3525189.80 24514934.00 30530728.00 29432308.00 0.67 3646344.80 2.17 537987.94 0.27 17012292.00 0.74 949396.31 0.82 338792.91 0.47 3456710.80 0.51 6610579.00 0.51 3651775.30 0.74 22769202.00 0.28 28649686.00 0.35 27453282.00 96.5 107.7 106.6 107.2 70 120 IS Fai 70 120 70 120 70 120 70 120 70

- 120 70 120 70 120 70 120 70

- 70

- 70 120 120 120

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU



### :Element Failures :Max. Number of Failures Allowed :ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/26/128:25 PM C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1 of 1C:\ICPCIIEM\l\DATA\12Il6qOO. 8\0369""L.D\0369MPL.DH



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\036SMPL.D\036SMPL.DU Sep 26 2012 08:28 pm Operator: NBS Sample Name: FGD ICS

- zinc Mise Info: Vial Number: Current Method: Calibration File: Last Cal Update: 3202 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep oil Factor: 1.00 Total Dil Factor: 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Conc. ug/l -0.01 ug/l 597.90 ug/l

6.37 ug/l 0.23 ug/l 2.22 ug/l 36.70 ug/l -12.39 ug/l

0.08 ug/l 1.18 ug/l -0.02 ug/l 2.45 ug/l 0.30 ug/l -0.01 ug/l -0.06 ug/l 0.09 ug/l 0.09 ug/l 1872.00 ug/l 0.02 ug/l 3.43 ug/l 3.48 ug/l -0.05 ug/l 0.04 ug/l 0.01 ug/l ug/l 0.01 ug/l ug/l -0.01 ug/l -0.14 ug/l -0.08 ug/l 0.42 ug/l 0.03 ug/l 0.06 ug/l 0.00 ug/l ug/l ug/l 0.00 ug/l Corr. Conc. UVALUEI

-0.01 597.90

6.37 0.23 2.22 36.70 -12.39

0.08 1.18 -0.02 2.45 0.30 -0.01 -0.06 0.09 0.09 1872.00 0.02 3.43 

## """'3:"48 -0.05 0.04 0.01 UVALUEI 0.01 UVALUEI

-0.01 -0.14 -0.08 0.42 0.03 0.06 0.00 UVALUEI UVALUEI 0.00 RSD(%) High Limit 

## o 21.50 1000

9.06 1000 13.07 25000 119.81 50000 26.73 20000 10.57 20000 75.51 50000 106.37 1000

4.97 1000 11.85 1000 2.76 1000 13

.06 20000 38.95 40.32 18.89 14.89

1.06 42.39

3.44 10.58 57.53 117.68 37.70

44 .06

158.59 29.06 301.63 129.95

14.53 14 .97 39.78

200.83 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 

### UUUUUUU 500 

### UUUUUUU 1000 

### UUUUUUU UUUUUUU 1000 1000 1000 1000 

### UUUUUUU UUUUUUU 1000 Flag

>Cal

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Rec(%) 80.7 101.6 94.8 93.3 100.6 95.6 99.9 QC Range (%) Flag 6 Li -106505.75 2.24 70

- 120 IS Fai 45 Sc 3704809.00 0.39 70 120 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 509750.44 15876257.00

955397.25 323899.44 3453841.50 6883933.00 3498517.30 21942132.00 27459006.00 26417262.00

ISTD Ref File :

1 :Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/26/128:31 PM 0.49 537987.94 8.55 17012292.00 0.04 0.90 949396.31 338792.91 6.71 3456710.80 0.46 6610579.00 0.49 3651775.30 9.01 22769202.00 9.87 28649686.00 10.85 27453282.00 104.1 95.8 96.4 95.8 96.2 70 70

- 70 70

- 70 70

- 70

- 70 70 70 120 120 120 120 120 120 120 120 120 120
C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.DU



### Fail Fail :Max. Number of Failures Allowed

o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1C,\ICPCHEM\l\DATA\12I26qOO.B\037SMPL.D\037SMPL.D#



### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, Mise Info: C,\ICPCHEM\1\DATA\12126qOO.B\037SMPL.D\037SMPL D# Sep 26 2012 08,34 pm NBS FGD ICS

- Chromium

Vial Number: CUrrent Method, Calibration File, Last Cal Update, Sample Type, 3203 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Sample Prep Dil Factor: 1.00 Total Dil Factor, 1.00

QC Elements Element Cone. Carr. Cone. #VALUEJ

-0.02 498.40

3.48 -0.51 0.01 32.49 -39.66

0.07 0.15 1066.00 1.57 0.42 -0.02 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug!l -0.02 ug/l 498.40 ug/l

3.48 ug/l -0.51 ug/l 0.01 ug/l 32.49 ug/l -39.66 ug/l

0.07 ug/l 0.15 ug/l 1066.00 ug/l 1.57 ug/l 0.42 ug/l -0.02 ug/l -0.10 ug/l 0.04 ug/l 0.02 ug/l -0.51 ug/l 0.06 ug/l 1.86 ug/l 2.26 ug/l -0.10 ug/l -0.04 ug/l 0.01 ug/l ug/l -0.01 ug/l ug/l -0.02 ug/l -0.28 ug/l -0.19 ug/l -0.28 ug/l 0.01 ug/l -0.01 ug/l -0.02 ug/l ug/l ug/l -0.01 ug/l -0.10 0.04 0.02 -0.51 0.06 

## L!L 2.26 -0.10 -0.04 0.01 #VALUEI

-0.01 #VALUEI

-0.02 -0.28 -0.19 -0.28 0.01 -0.01 -0.02 #VALUE! #VALUE!

-0.01

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -120827.75 3708234.00 497315.22 17330376.00

946894.25 321435.47 3628007.80 6943829.50 3505867.30 24331450.00 30187410.00 29144966.00 8.79 1.32 0.94 537987.94 1.22 17012292.00 0.94 949396.31 0.98 338792.91 0.86 3456710.80 0.47 6610579.00 0.90 3651775.30 0.48 22769202.00 0.40 28649686.00 1.12 27453282.00 RSD(%) High Limit 

## o 9.36 1000 2.23 1000 13.09 25000 51.28 50000 1584.50 20000

10.37 20000 12.61 50000 12.03 1000 12.87 1000 0.41 1000 1.52 1000 10.32 20000 8.51 1000 16.15 11.74 36.05 13.14 150.20

4.21 1.40 21.00 13.02 40.47

8.59

8.71 7.83 50.95 11.50

1.09 142.82

6.28

12.63 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) Rec(%)

91.5 101.7 92.4 101.9 99.7 94.9 105.0 105.0 70 120

96.0 106.9 105.4 106.2 70 120 70 120 70 120 70

- 120 70

- 120 70 120 70

- 70 70

- 70 70

- 120 120 120 120 120 Flag

,Cal

Flag IS fai

ISTD Ref File, C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures :Max. Number of Failures Allowed ,ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9126112 8:38 PM C:\ICPCHEM\1\rpttmp\Samp1e.qct Page 1of 1C:\ ICPClIEM\1\DATA\12I26qOO.B\03BSMPL.D\03BSMPL.DH



### Sample QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\038SMPL.D\038SMPL.D# Sep 26 2012 08:41 pm Operator: NBS Sample Name: FGD ICS

- Copper Mise Info: Vial Number: current Method: Calibration File: Last Cal Update: 3204 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: Sample Prep Dil Factor: 1.00 Total Dil Factor: 1.00

QC Blement. Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) III Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l -0.02 ug/l 446.20 ug/l

-2.19 ug/l -0.27 ug/l -1.04 ug/l 23.63 ug/l -59.99 ug/l -0.01 ug/l -0.01 ug/l 0.79 ug/l 1.06 ug/l 0.12 ug/l -0.01 ug/l -0.10 ug/l 1085.00 ug/l 1093.00 ug/l

-2.36 ug/l -0.01 ug/l 1.41 ug/l 1.87 ug/l -0.10 ug/l -0.05 ug/l 0.00 ug/l ug/l -0.01 ug/l ug/l -0.01 ug/l -0.43 ug/l -0.14 ug/l -0.37 ug/l 0.00 ug/l -0.04 ug/l -0.01 ug/l ug/l ug/l -0.01 ug/l

Element CPS Mean RSD(%) 6 Li -117488.69 4.07 45 Sc 3718146.30 0.99 45 Sc 509565.50 1.21 Cerr. Cone. #VALUE!

-0.02 446.20

-2.19 -0.27 -1.04 23.63 -59.99 -0.01 -0.01 0.79 1.06 0.12 -0.01 -0.10 1085.00 1093.00

-2.36 -0.01 1.41 

## -r:B"1 -0.10 -0.05 0.00 #VALUE!

-0.01 #VALUE!

-0.01 -0.43 -0.14 -0.37 0.00 -0.04 -0.01 #VALUE! #VALUE!

-0.01

Ref Value -131996.50 3646344.80

537987.94 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 17720008.00 956646.06 328000.44 3676394.80 7016368.00 3546346.50 1.04 17012292.00

24716714.00 30987344.00 29784232.00 0.12 949396.31 0.41 338792.91 1.08 3456710.80 0.66 6610579.00 0.22 3651775.30 0.45 22769202.00 0.32 28649686.00 0.53 27453282.00 RSD(%)

9.70 0.10 23.23 54.59 5.92 12.25 3.26 253.09

20.92

1.11 3.65 50.85 6.44 20.03

1.60 1.08 2.24 150.70

3.02 1.82 19.09 7.23 1156.60

8.70

5.86 8.95 260.62

8.82 88.90 30.31

3.75

14.20

Rec(%)

89.0 102.0 94.7 104.2 100.8 96.8 106.4 106.1 97.1 108.6 108.2 108.5 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000

1000 1000 1000 1000 20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) 70 120 70

- 120 70 120 70

- 120 70 120 70 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70 120 Flag

>Cal >Cal

Flag IS Fai

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

2 :Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

9126112 B:45 PM 

### Fail Fail

## o :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1C,\ICPCIIE>!\1\CATA\12126qOO.B\04l_CCV.C\04l_CCV.

# 0_

CCV QC Report

Data File: Date Acquired, Operator: C:\ICPCHEM\1\DATA\12I26qOO.B\043_CCV.D\043_ccv.Dn Sep 26 2012 09:14 pm NBS Sample Name: CCV 120926 Mise Info: Vial Number: CUrrent Method: Calibration File: Last Cal Update: 1106 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: CCV Total Oil Factor: 1.00

QC Elements Element 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 

### Cone.

91.23 411.90 2627.00 25830.00

9893.00 2097.00 25620.00

202.80 103.50 104.30 102.80 10210.00

103.70 ug/1 ug/l ug/1 ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l 103.90 ug/l 104.30 ug/l 104.10 ug/l 101.90 ug/l 100.60 ug/l 102.90 ug/l 101.20 ug/l 103.20 ug/l 95.44 ug/l 186.30 ug/l ug/l 92 .45 ug/l ug/l 93.17 ug/l 208.40 ug/l 206.40 ug/l 189.00 ug/l 184.90 ug/l 101.30 ug/l 92 .17 ug/l ug/l ug/l 93.82 ug/l RSD(%) Expected QC Range(%) 50.00 0.76 50.00 1.52 50.00 1.44 1250.00 1.99 12500.00 1.37 5000.00 0.94 1000.00 1.09 12500.00 1.39 1.09 0.92 0.85 1.02 1.16 0.90 1.12 1.21 0.64 0.19 0.53 1.04 0.63 3.49 3.26

2.77 100.00 50.00 50.00 50.00 500.00

50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 100.00 50.00 50.00 90

- 110 90 110 90 110 90 110 90

- 110 90 110 90

- 110 90

- 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90

- 110 90 110 90 110 90

- 110 90 110 90

- 110 90 110 50.00 90 110 110 

# nnnnn 1.33 0.80 0.40 1. 68 2.06 7.34 1.69

1.66 50.00 90

100.00 100.00 50.00 50.00 50.00 50.00 50.00 

# nnnnn nnnnn 90 90 90 90 90 90 90 

# - nnnnn 110 110 110 110 110 110 110 Flag


### 'Fiili F il F il F il Fil F i 1 F il 

### F il
F il F il 

### F il 

### F il F il F il 

### F il F il F '1 Fa'l Fa 1 Fa Fa Fa Fa

Fa'

Fa'l

Fa Fa Fa Fa \£11}. (p'{' 

## lo1.."

# I

Element CPS Mean RSD(%) 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -117534.54 13.21 Ref Value -131996 .50 Rec(%) QC Range(%) 89.0 106.5 98.4 108.9 103.5 99.6 110.8 106.6 70 70 70 120 120 120 Flag 

### <" IS Fail 

## rJ\ 3881736.00 529203.44 18518892.00

983097.25 337297.94 3828636.50 7043901.50 3542548.50 24714964.00 31189180.00 30200216.00

ISTD Ref File :

30 :Element Failures

1 :ISTD Failures



### Data Results: Analytes: ISTD:

9/26/129:18 PM 0.47 3646344.80 1.38 537987.94 1.46 17012292.00 0.08 949396.31 1.65 338792.91 1.43 3456710.80 0.55 6610579.00 0.66 3651775.30 2.4622769202.00 1.78 28649686.00 1.20 27453282.00 97.0 108.5 108.9 110.0 70

- 120 70 120 70 120 70

- 120 70 120 70 120 70 120 70

- 120 70

- 120
C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn



### Fail Failo :Max. Number of 

### Failures Allowed

o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1C,\ICPCIIEM\l\OATA\12126qOO.B\045_CCB.0\045_CCB.011



### CCB QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\045_CCB.D\045_CCB.D# Sep 26 2012 09:27 pm Operator: NBS Sample Name: CCB 120926 

### Mise Info: Vial Number: CUrrent Method: 

### Calibration File: Last Cal Update: 1102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: CCB Total Dil Factor: 1.00

QC Elements 

### Element (Li) 

### Cone. ug/l 0.00 ug/l RSD(%)

Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 273.50 ug/l 6.88 ug/l 1.02 ug/l 0.13 ug/l 34.08 ug/l -4.81 ug/l 0.05 ug/l -0.03 ug/l 0.00 ug/l 0.21 ug/l 0.97 ug/l 0.00 ug/l -0.05 ug/l 0.03 ug/l 0.02 ug/l -0.07 ug/l 0.02 ug/l 0.56 ug/l 1.35Ug/l -0.03 ug/l 0.01 ug/l 0.06 ug/l ug/l 0.00 ug/l ug/l 0.01 ug/l 0.83 ug/l 0.37 ug/l 0.23 ug/l 0.08 ug/l O.Olug/l 0.01 ug/l ug/l ug/l 0.00 ug/l 88.44 0.64 16.71 11.82 277.89

5.96 94.04 207.34 49.09 256.67

14.26 16.84 138.85 40.65 22.62 59.28 91.85 23.70

6.23 8.17 55.21 74.58

3.08

71.81

55.53 160.24

15.65 25.32

3.97 70.96 25.21

33.56

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.SO 3646344.80

537987.94 6 Li -113701.58 4.53 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3965454.SO 523514.81 18366760.00

1034474.60 334192.81 3769784.00 7415833.50 3600374.SO 24837508.00 30861174.00 29640796.00 0.74 1.82 1.25 17012292.00 5.36 949396.31 0.75 338792.91 0.95 3456710.80 2.74 6610579.00 0.25 3651775.30 0.82 22769202.00 LOS 28649686.00 1.42 27453282.00 High Limit ####### 0.12 15.00 77.10 7.50 3.96 19.20 90.00

0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%)

86.1 70

- 120 108.8 70

- 120 97.3 70

- 120 108.0 109.0 98.6 109.1 112.2 98.6 109.1 107.7 108.0 70 120 70 120 70 120 70 120 70 120 70 120 70 120 70

- 120 70

- 120 Flag

Fail 

## tl'"

Fail 

## ,.1-<:

Fail

Fail Fail

Fail 

# r'1"

Flag IS Fai.

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### 6 :Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD: 

### Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed 

## L.. \

.

# oJ'1.8

# 1 L..

9/26/129:31 PM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1C,\ICPCIIEM\l\OATA\12126qOO.B\057_CCV.0\057_CCV.Oi



### CCV QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I26qOO.B\057_CCV.D\057_CCV.D# Sep 26 2012 10,47 pm NBS Sample Name: CCV 120926 Mise Info: Vial Number, CUrrent Method, 

### Calibration File: Last Cal Update, Sample Type, Total Dil Factor: 1106 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm CCV 1.00

QC Elements 

### Element Cone. RSD(%) Expected QC Range(%) 7 (Li) ug/l 91.72 ug/l 199.20 ug/l 2662.00 ug/l 26120.00 ug/l

9918.00 ug/l 2116.00 ug/l 50.00 90 110
9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 25680.00 ug/l 205.10 ug/l 104.60 ug/l 105.20 ug/l 103.80 ug/l 10380.00 ug/l

105.20 ug/l 105.40 ug/l 105.20 ug/l 105.30 ug/l 101.10 ug/l 100.10 ug/l 102.80 ug/l 99.72 ug/l 102.50 ug/l 97.55 ug/l 189.00 ug/l ug/l 94.02 ug/l ug/l 94.51 ug/l 209.20 ug/l 206.80 ug/l 190.10 ug/l 186.10 ug/l 106.80 ug/l 91.96 ug/l ug/l ug/l 92.46 ug/l

ISTD Element. 1.07 50.00 1.76 50.00 1.62 1250.00 1.11 12500.00 0.96 5000.00 1.10 1000.00 0.75 12500.00 1.80 100.00 1.29 50.00 1.53 50.00 1.76 50.00 1.06 500.00 1.35 1.42 1.49 1.58 1.45 1.11 1.21 0.62 1.35 0.66 0.67

0.87

0.09 0.70 0.80 0.74 0.56 1.73 0.46

0.45 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 100.00 50.00 50.00 50.00 50.00

100.00 100.00 50.00 50.00 50.00 50.00 50.00 90 110 90

- 110 90

- 110 90

- 110 90

- 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 90 90 90 90 90 90 90 90 90 90 90 90 90 90 ##### 110 110 110 110 110 110 110 110 110 110 110 110 110 110 110 ##### #####

- ##### 90 110 90 110 90 110 90 110 90 110 90 110 90 110

Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80

537987.94 17012292.00

949396.31 Rec(%) QC Range(%) 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -102336.02 3994279.80 535870.88 18766360.00

1018578.60 344028.53 3878756.30 7257053.50 3639922.80 24605280.00 31141070.00 29932426.00 5.73 0.65 1.40 0.17 0.92 0.43 338792.91 0.93 3456710.80 0.41 6610579.00 1.12 3651775.30 0.97 22769202.00 0.79 28649686.00 1.23 27453282.00 77.5 109.5 99.6 110.3 107.3 101.5 112.2 109.8 99.7 108.1 108.7 109.0 70 70 70 70 70 70 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail

Fail

Fail

Fail Fail Fail Fail

Fail

Flag IS Fail

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

30 :Element Failures ,ISTD Failures



### Data Results: Analytes: ISTD:

912611210:51 PM 

### Fail Fail o :Max. Number of 

### Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\CCV.qct Page 1of 1C,\ICPCIIEI<\l\DATA\12I26qOO .9\OS9_CCB.D\OS9_CCB.DI



### CCB QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\059_CCB.D\059_CCB.Dn Sep 26 2012 11:00 pm Operator: NBS Sample Name, CCB 120926 Misc Info, Vial Number, Current Method, Calibration File: Last Cal Update, Sample Type, Total Di1 Factor, 1102 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,16 pm CCB 1.00

QC Elements Element 

### Cone. RSD(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 A1 39 K 44 ca 47 Ti 51 V 52 cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 76 se 76 Se 66 Sr 66 sr 95 Mo 106 (Cd) 107 Ag 106 (Cd) 111 Cd 116 Sn 116 Sn 116 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 206 Pb ug/l 0.00 ug/l 72.73 ug/l

3.23 ug/l 1.23 ug/1 0.53 ug/1 24.16 ug/1 -5.02 ug/l 0.04 ug/l -0.04 ug/l 0.00 ug/l 0.06 ug/l 0.96 ug/1 0.00 ug/l -0.07 ug/l 0.02 ug/l 0.00 ug/1 0.01 ug/1 0.01 ug/l 0.36 ug/l 0.70 ug/l -0.02 ug/l 0.01ug/1 0.07 ug/l ug/l 0.00 ug/l ug/1 0.00 ug/l 0.36 ug/l 0.49 ug/l 0.35 ug/l 0.09 ug/l 0.01 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l 43.77 0.61 14.66 23.26 101.46

14.00 76.07 13.76 6.56 50.42 24.13 14.32 37.60 16.13 31.77 7713.60 736.09

62.06 4.36 20.26

6.60 109.14

7.15

43.03

66.14

6.63 20.31 22.02

6.13 67.17 9.36

51.52

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.60 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -105393.61 3972629.50

542640.00 16651006.00 1016659.50 346291.13 3906303.30 7422523.00 3755156.00 25235746.00 30922952.00 29636662.00 4.09 0.92 0.56 537967.94 1.31 17012292.00 0.53 949396.31 1.61 336792.91 0.72 3456710.60 1.09 6610579.00 0.77 3651775.30 1.34 22769202.00 1.24 26649666.00 0.66 27453262.00 High Limit 

# nnnnnnn 0.12 15.00 77.10

7.50 3.96 19.20 90.00 0.7B 0.21 0.12 0.16 40.60

0.09 0.46 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 

# nnnnnnn 0.09 

# nnnnnnn 0.06 

# nnnnnnn nnnnnnn 0.30 0.03 0.12 0.03 

# nnnnnnn nnnnnnn 0.33

Rec(%) QC Range(%)

79.6 70 120 106.9 100.9 109.6 107.3 102.2 113.1 112.3 102.6 110.6 107.9 106.0 70 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120 70 120 70

- 120 Flag

Fail

Fail

Fail Fail

Fail Fail

Flag IS FaL

ISTD Ref File: C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn

6 :Element Failures :Max. Number of Failures Allowed 1 ,ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9i26/12 11:04 PM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1C:\ICPCHEK\l\DATA\12I26qOO .B\071_CCV.0\07l_CCV.0#



### CCV QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\071_CCV.D\071_CCV.D# Sep 27 2012 12:20 am Operator: NBS Sample Name: CCV 120926 Mise Info: vial Number: CUrrent Method: Calibration File: Last Cal Update: 1106 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: CCV Total 

### Dil Factor: 1.00

QC Elements Element Cone. RSD(%) Expected QC Range(%) 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 

### v 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 cu 65 cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 93.23 136.10 2670.00 26170.00 10020.00 2105.00 25440.00

200.60 102.20 101.70 101.60 10080.00 ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l 101.70 ug/l 101.40 ug/l 102.00 ug/l 101.70 ug/l 100.40 ug/l 100.10 ug/l 102.30 ug/l 102.10 ug/l 103.20 ug/l 95.70 ug/l 185.00 ug/l ug/l 91.05 ug/l ug/l 92.53 ug/l 207.60 ug/l 203.00 ug/l 189.40 ug/l 186.90 ug/l 102.50 ug/l 90.94 ug/l ug/l ug/l 91.53 ug/l 50.00 90 110 0.72 50.00 0.76 50.00 2.03 1250.00 1.68 12500.00 0.585000.00 2.311000.00 1.38 12500.00 1.47 1.64 0.98 1.83 2.50 2.40 1.41 1.57 1.57 0.40 0.77 0.60 0.26 0.93 1.04 1.49

2.03

1.36 0.61 0.57 0.98 1.27 6.61 0.79

0.67 100.00 50.00 50.00 50.00 500.00

50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 100.00 50.00 50.00 50.00 50.00

100.00 100.00 50.00 50.00 50.00 50.00 50.00 90 110 90 110 90

- 110 90 110 90

- 110 90 110 90 110 90

- 110 90 110 90

- 110 90

- 110 90

- 110 90 90 90 90

- 90

- 90

- 90

- 90 90 90

- 90 90 90 90 90 ##### ##### 90

- 90

- 90 90 90 90 90 110 110 110 110 110 110 110 110 110 110 110 110 110 110 110 ##### #####

110 110 110 110 110 110 110

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -116018.45 3765953.50

517915.38 17945498.00

954073.50 324142.25 3688293.30 6818772.00 3413148.30 23549862.00 30084936.00 28980032.00 8.09 0.48 1.42 537987.94 0.89 17012292.00 0.63 949396.31 0.29 338792.91 1.05 3456710.80 1.15 6610579.00 0.33 3651775.30 1.10 22769202.00 1.3228649686.00 0.95 27453282.00 Rec(%) QC Range(%) 87.9 103.3 96.3 105.5 100.5 95.7 106.7 103.1 93.5 103.4 105.0 105.6 70

- 120 70 120 70 120 70 120 70 120 70 120 70 120 70 120 70 120 70 70 70 120 120 120 Flag

Fa Fa Fa Fa Fa Fa

F F F F F F il F il F il F il

F il

F il

F il F il F il
F il

Flag IS Fail

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

30 :Element Failures

: ISTD Failures



### Data Results: Analytes: ISTD: Fail Fail :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed 

## (01.1-/

lao. l "(. ID1,.**~(.**

9/27112 12:24 AM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1 of 1C I \ICPCHEM\1\DATA\12126QOO.B\073_CCB.D\073_CCB.DfI:



### CCB QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\073_CCB.D\073_CCB.D# Sep 27 2012 12:33 am Operator: NBS Sample Name: CCB 120926 Mise Info: Vial Number: CUrrent Method: Calibration File: Last Cal Update: 1102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: CCB Total Dil Factor: 1.00

QC Elements Element 

### Cone. RSD(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.00 ug/l 28.44 ug/l 6.00 ug/l 2.88 ug/l 0.86 ug/l 19.74 ug/l -8.59 ug/l 0.04 ug/l -0.03 ug/l 0.00 ug/l 0.11 ug/l 1.10 ug/l 0.00 ug/l -0.08 ug/l 0.02 ug/l 0.01 ug/l -0.02 ug/l 0.03 ug/l 0.27 ug/l 0.93 ug/l -0.05 ug/l 0.00 ug/l 0.07 ug/l ug/l 0.00 ug/l ug/l 0.00 ug/l 0.41 ug/l 0.53 ug/l 0.33 ug/l 0.11 ug/l 0.01 ug/l 0.02 ug/l ug/l ug/l 0.00 ug/l 170.77 14 .10 13.77 5.89 53.50 22.34 74.87 118.78 33.46 694.21

22.80

9.83 84.30

8.63 22.22 129.24 419.81

50.85 11.24 5.59 51.99 1342.20

20.81

355.08

55.65 33.85

8.83 153.50 14.73 137.71 37.94

291.49

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80

537987.94 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -116657.41 3744551. 80

517859.63 17840296.00

956514 .00 325372.00 3688012.30 6878506.50 12.10 1.41 0.60 12.02 17012292.00 0.33 949396.31 0.22 8.46 1.30 338792.91 3456710.80 6610579.00 3447856.30 0.15 3651775.30 24145908.00 12.98 22769202.00 29998472.0012.5528649686.00 29103804.00 12.60 27453282.00 High Limit ####### 0.12 15.00 77.10

7.50 3.96 19.20 90.00 0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%)

88.4 70 102.7 70

-

96.3 70 104.9 70 100.7 70 96.0 70 106.7 70 104.1 70 94.4 70

- 106.0 70 104.7 70 106.0 70 120 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail

Fail

Fail ,.J""i

Fail 

## tJ-rFai1 

### rJ-('

Flag IS Fai.**~\**

ISTD Ref File : C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

5 :Element Failures 1 :ISTD Failures



### Data Results: Analytes: ISTD:

912711212:37 AM 

### Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1of 1C,\ICPCHEM\1\DATA\lZI26qOO .B\085_CCV.D\085_CCV.DII



### CCV 

### QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\085_CCV.D\085_CCV.D# Sep 27 2012 01:53 am Operator: NBS Sample Name: CCV 120926 Misc Info: Vial Number: CUrrent Method: Calibration File: Last Cal Update: 1106 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: CCV Total Dil Factor: 1.00

QC Elements Element (Li) Cone. RSD(%) Expected QC Range(%)

Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 

### V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 82.34 94.23 2651.00 25450.00 10010.00

1906.00 25390.00

198.50 99.93 98.87 100.40 9858.00

99.26 ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l 98.92 ug/l 99.45 ug/l 99.01 ug/l 93.71 ug/l 93.77 ug/l 97.26 ug/l 97.44 ug/l 102.00 ug/l 94.84 ug/l 181.20 ug/l ug/l 90.25 ug/l ug/l 91.00 ug/l 190.50 ug/l 200.70 ug/l 190.70 ug/l 186.20 ug/l 99.61 ug/l 95.85 ug/l ug/l ug/l 96.11 ug/l 50.00 90

- 110 4.87 50.00 0.35 50.00 1.67 1250.00 1.47 12500.00 1.77 5000.00 2.06 1000.00 0.64 12500.00 1. 86 1.08 1.69 1.51 1.52 1.26 2.09 2.01 1.87 0.45 0.74 0.52 0.98 1.01 0.79 1.09

0.57 100.00 50.00 50.00 50.00 500.00

50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 100.00 50.00 50.00 50.00 90

- 110 90 110 90

- 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 110 90

- 110 90

- 110 90 110 90 110 90

- 110 90

- 110 90 110 90 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90 110 90

- 110 0.59 0.40 0.25 0.04 0.38 0.74 0.30 50.0090 110

0.80 - - - ##### ##### #####

- ##### 100.00 100.00 50.00 50.00 50.00 50.00 50.00 90

- 110 90 110 90 110 90 110 90

- 110 90 110 90 110

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 6 Li -100876.27 4.50 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 2791081.00 383152.88 13567006.00

700089.38 244911.61 2927789.50 5149708.50 2608314.50 19387486.00 26095872.00 25362694.00 0.50 3646344.80 1.66 537987.94 0.46 17012292.00 1.01 949396.31 1.60 338792.91 1.30 3456710.80 0.74 6610579.00 0.74 3651775.30 0.75 22769202.00 0.26 28649686.00 0.36 27453282.00 Rec(%) QC Range(%) 76.4 70 120 76.5 70 120 71.2 70

- 120 79.7 70

- 120 73.7 70 120 72.3 70 120 84.770 120 77.9 70 120 71.4 70

- 120 85.1 70 120 91.1 70 120 92.4 70 120 Flag

11 F il F il F il F il F il F il F il F il F il F il F il Fil 

### F il
F il

il il 

### ail ail ail 

### ail ail ail

ail

ail 

## q('/.

Flag IS Fail ,.. -(

ISTD Ref File: C:\ICPCHEM\1\DATA\12126qOO.B\004CALB.D\004CALB.D#

30 :Blement Failures :Max. Number of Failures Allowed
: ISTD Failures 0 :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/27112 1:57 AM C:\ICPCHEM\l\rpttmP\CCV.qct Page 1of 1C,\ICPCHEM\l\DATA\12I26qOO .9\087_CCB .D\087_CCB**.D~**



### CCB QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I26qOO.B\087_CCB.D\087_CCB.D# Sep 27 2012 02:07 am Operator: NBS Sample Name: CCB 120926 Mise Info: Vial Number: CUrrent Method: Calibration File: Last Cal Update: 1102 C:\ICPCHEM\l\METHODS\CSC-MDL.M C:\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05:18 pm Sample Type: CCB Total Dil Factor: 1.00

QC Blements Element (Li) Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 Cu 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Blements 

### Cone. ug/l 0.00 ug/l 12.90 ug/l 31.66 ug/l 6.60 ug/l 0.63 ug/l 41.57 ug/l -9.23 ug/l 0.04 ug/l 0.01 ug/l -0.02 ug/l 0.09 ug/l 1.18 ug/l 0.00 ug/l -0.07 ug/l 0.08 ug/l 0.07 ug/l -0.22 ug/l 0.04 ug/l 0.14 ug/l 1.43 ug/l -0.04 ug/l 0.00 ug/l 0.06 ug/l ug/l 

## o .00 ug/l ug/l -0.01 ug/l 0.29 ug/l 0.36 ug/l 0.25 ug/l 0.08 ug/l 0.01 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l

Element CPS Mean RSD(%) Li -100982.52 4.41 45 Sc 2775014.30 1.15 45 Sc 0.41 RSD(%)

23.20

2.62 3.48 5.90 41.4 3

7.44 57.00 45.54 167.60 26.89 29.14

5.79 217.64

36.54 14.06 10.31 33.36 6.01 10.01 5.09 59.80 136.82

8.88

131.43

13.27 5.43 29.24 25.95

5.58 85.91 4.75

100.66

Ref Value -131996.50 3646344.80

537987.94 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 376871.16 13653593.00 0.40 17012292.00

699303.81 243273.42 2904337.50 5171818.50 2637361.00 20064644.00 26151482.00 25236008.00 1.18 949396.31 0.63 338792.91 0.29 3456710.80 0.56 6610579.00 0.13 3651775.30 0.91 22769202.00 0.37 28649686.00 0.77 27453282.00 High Limit ####### 0.12 15.00 77.10 7.50 3.96 19.20 90.00 0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%)

76.5 70 76.1 70 70.1 70

- 80.3 70

- 73.7 70 71. 8 70 84.0 70

- 78.2 70

- 72.2 70

- 88.1 70

- 91.3 70 91.9 70 120 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail 

### rJ-:"

Fail 

## rJ'

Fail

### ~,

Flag IS FaL 

### N'

ISTD Ref File: C:\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

:Element Failures 0 :Max. Number of Failures Allowed
: ISTD Failures 0 :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/271122:10AM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1C,\ICPCHEM\l\DATA\12126qOO .B\099_CCV.D\099_CCV.D#



### CCV QC Report

Data File, Date Acquired: C,\ICPCHEM\1\DATA\12I26qOO.B\099_CCV.D\099_ccv.Dn Sep 27 2012 03,27 am Operator: NBS Sample Name, 

### Mise Info: CCV 120926

Vial Number, Current Method, 

### Calibration File: 1106 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm Last Cal Update, Sample Type, Total Dil Factor: CCV 1.00

QC Elements Element Conc. RSD(%) Expected QC Range(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 70.16 ug/l 77.44 ug/l 2755.00 ug/l 24850.00 ug/l

8841.00 ug/l 1935.00 ug/l 25320.00 ug/l

197.50 ug/l 101.00 ug/l 98.91 ug/l 100.10 ug/l 9822.00 ug/l

100.30 ug/l 99.57 ug/l 100.60 ug/l 99.53 ug/l 87.82 ug/l 90.07 ug/l 93.15 ug/l 92.68 ug/l 100.40 ug/l 93.53 ug/l 175.50 ug/l ug/l 88.04 ug/l ug/l 87.87 ug/l 190.20 ug/l 200.70 ug/l 191.50 ug/l 183.40 ug/l 101.70 ug/l 97.33 ug/l ug/l ug/l 93.81 ug/l 50.00 90

- 110 0.85 50.00 90

- 110 1.13 50.00 1.27 1250.00 1.11 12500.00 1.43 5000.00 1.65 1000.00 1.38 12500.00 3.45 100.00 1.60 0.69 1. 69 1.66 1.68 1.75 1.39 1.35 0.95 0.31 1.90 1.45 0.50 0.26 0.66

0.74

0.45 0.55 0.82 0.60 0.93 0.32 0.27

2.54 50.00 50.00 50.00 500.00

50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 100.00 50.00 50.00 50.00 50.00

100.00 100.00 50.00 50.00 50.00 50.00 50.00 90 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90 110 90

- 110 90'

- 110 90

- 110 90 110 90

- 110 90

- 110 90

- 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 110 90

- 110 90

- 110 90 110 90

- 110 

# nnnnn nnnnn nn#n#

- nnnnn 90

- 110 90

- 110 90

- 110 90 110 90

- 110 90

- 110 90

- 110

ISTD Elements Element 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho CPS Mean RSD (%) -64965.80 3.16 Ref Value -131996.50 2288065.50 296688.63 9010487.00

567642.88 195897.47 2047839.80 4264824.00 2120616.30 14245596.00 19298392.00 18735534.00 0.95 3646344.80 1.22 537987.94 0.74 17012292.00 0.13 949396.31 1.23 338792.91 0.67 3456710.80 0.45 6610579.00 0.33 3651775.30 0.22 22769202.00 0.67 28649686.00 0.11 27453282.00 Rec(%) QC Range(%) 49.2 70 120 62.7 70 120 55.1 70

- 120 53.0 70

- 120 59.8 70 120 57.8 59.2 64.5 58.1 62.6 67.4 68.2 70 120 70 120 70 120 70

- 120 70 120 70

- 120 70 120 Flag

Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail Fail

Fail

Fail

Fail Fail Fail Fail

Fail

Flag IS Fail IS Fail IS Fail IS Fai1 IS Fail IS Fail IS Fail IS Fail IS Fail IS Fail IS Fail IS Fail

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.Dn



### 30 :Element Failures 12 ,ISTD Failures



### Data Results: Analytes: 

### ISTD:

91271123:31 AM 

### Fail Fail

## o ,Max. Number of Failures Allowed 

## o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmP\CCV.qct Page 1of 1C,\ICPCHEM\l\DATA\12I26qOO.B\lOl_CCB.D\lOl_CCB.D#



### CCB QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12126qOO.B\101_CCB.D\101_CCB.D# Sep 27 2012 03,40 am Sample Name, Mise Info: NBS CCB 120926

Vial Number, Current Method, Calibration File, Last Cal Update, Sample Type, Total Dil Factor, 1102 C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Sep 26 2012 05,18 pm CCB 1.00

QC Elements 

### Element Cone. RSD(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l -0.01 ug/l 7.99ug/l 136.10 ug/l 23.12 ug/l 0.07 ug/l 67.58 ug/l 7.81 ug/l 0.09 ug/l 0.13 ug/l 0.00 ug/l 0.07 ug/l 2.51ug/l 0.00 ug/l -0.07 ug/l 0.27 ug/l 0.27 ug/l -0.48 ug/l 0.04 ug/l O.l1ug/l 1.41 ug/l 0.00 ug/l -0.01 ug/l 0.05 ug/l ug/l 0.00 ug/l ug/l 0.00 ug/l 0.30 ug/l 0.25ug/l 0.25 ug/l 0.08 ug/l 0.02 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l 35.06 2.07 2.57 3.88 1743.40 3.92 32.34 126.54

2.53 775.16 23.27 31.44 450.90

28.63

1.53 7.10 24.24 16.24 4.18 2.91 2698.80

15.62 12.38

75.53

689.81

15.85 39.55 23.85

2.76 11.85 22.19

48.24

ISTD Elements Element CPS Mean RSD(%) Ref Value -131996.50 3646344.80 6 Li -70076.81 6.78 45 Sc 2280102.50 0.39 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 297527.41 9199227.00

570441.38 196082.13 2053901. 50 4331588.50 2179950.00 14933505.00 19575280.00 18972254.00 0.40 537987.94 0.68 17012292.00 0.51 949396.31 0.54 338792.91 0.65 3456710.80 0.47 6610579.00 0.25 3651775.30 0.50 22769202.00 0.20 28649686.00 0.89 27453282.00 High Limit 

# """"""" 0.12 15.00 77.10

7.50 3.96 19.20 90.00 0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 

# """"""" 0.09 

# """"""" 0.06 

# """"""" """"""" 0.30 0.03 0.12 0.03 

# """"""" """"""" 0.33 Flag

Fail Fail

Fail

Fail

Fail

Rec (%) QC Range (%) Flag

53.1 70

- 120 IS Fai. 62.5 70 120 IS FaL 55.3 54.1 60.1 57.9 59.4 65.5 59.7 65.6 68.3 69.1 70

- 70 70 70

- 70

- 70 70

- 70

- 70 70 120 IS FaL 120 IS Fai: 120 IS Fai. 120 IS FaL 120 IS Fai. 120 IS FaL 120 IS FaL 120 IS FaL 120 IS FaL 120 IS Fai.

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D"



### :Element Failures 12 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 3:44 AM 

### Fail Fail ,Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1of 1C.\ICPCHEH\1\DATA\12127s00.B\004CALB.D\004CALB.D#



## Calibration Blank QC Report

Data File: Date Acquired: Operator: Sample Name: Misc Info: Vial Number: C:\ICPCHEM\1\DATA\12I27s00.B\004CAL Sep 27 2012 06:24 pm NBS Calibration Blank

Current Method: 1102 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:21 pm Calibration File: Last Cal Update: Sample Type: CalBlk Total Dil Factor: 1.00

QC&ISTD Elements Element 6 7 

### 9 

### 11 23 24 27 39 44 45 45 45 47 51 52 55 56 59 60 63 65 66 72 72 72 

### 75 78 78 88 88 95 106 107 108 111 115 115 115 118 118 118 121 137 159 165 205 206 207 208 Li (Li) Be B 

### Na 

## Mg Al K 

### Ca Sc Sc Sc Ti V 

### Cr Mn Fe Co Ni Cu Cu 

### Zn Ge Ge Ge As Se Se Sr Sr Mo (Cd) 

## Ag (Cd) Cd In In In Sn Sn Sn Sb Ba Tb Ho Tl (Pb) (Pb) Pb

9/271126:28 PM 

### CPS Mean -88139.43 A 7903326.00 A 45.56 P 30017.70 P 62647.53P

241.12 P 1245.65 P 41165.74 P

1666.77 P 5590061.00 A

732360.19 A 18013600.00 A 23.56 P 519.13 P 665.36 P 134.22P 10611.09 P 56.89 P 82.67 P 691. 58 P 340.90 P 689.80P 1407959.00 A

475526.09 A 3640663.00 A 59.44 P 16.22 P 156.22 P 300.01P 2594.76 P 1357.89 P

24.45 P 50.00 P 13.33 P 71.99 P 10055670.00 A 4993515.00 A 20883300.00 A 1871.30 P

940.07P 3706.22 P

758.94 P 243.34 P 23533160.00 A 22279000.00 A 173.34 P 185.56 P 174.45 P 706.70 P SD 4741.00 205200.00 18.36 557.30 517.60

15.03 129.80 736.70

23.37 77690.00

7292.00 146800.00 4.29 47.41 34.74 18.15 182.60

4.68 24.33 42.21 14.87 20.93 32860.00

5892.00 21880.00 4.17 0.51 10.46 15.28 121.00

76.19

7.70 5.77 6.67 13.83 213100.00

40850.00 82490.00 77.50 43.34 205.30

55.21 15.28 228000.00 264000.00 32.83 26.94 11.71 32.83 RSD(%) 5.38 2.60 40.30

1.86 0.83 6.23 10.42

1.79 1.40 1.39 1.00 0.81 18.20

9.13 5.22 13.52

1.72 

### 8.23 29.43

6.10 4.36 3.03 2.33 1.24 0.60 7.01 3.14 6.70 5.09 4.66 5.61 31.49 11.55 50.00 19.21

2.12 0.82 0.40 4.14 4.61 5.54 7.27 6.28 0.97 1.19 18.94 14.52

6.71 4.65

C:\ICPCHEM\1\rpttmp\Ca1Blk.qct Page 1 of 19/27/126:34 PM C:\ ICPCHEM\1\DATA\12r271100.B\OOSCALS.D\OOSCALS.D'



### Calibration Standard QC Report

Data File: Date Acquired: 

## c,\ ICPCHEM\1\oATA\12 127s00.B\005CALS.o\005CALS.on Sep 27 2012 06,31 pm Operator: NBS Sample Name: 120927 Standard 1 Misc Info: Vial Number: 1103 Current Method: Calibration File: Last cal Update: C,\ICPCHEM\l\METHOoS\CSC-MoL2.M C, \ICPCHEM\l\CALIB\CSC-MoL2.C Sep 27 2012 06,28 pm Sample Type, Total Dil Factor: CalStd 1.00

QC&ISTD Elements Element CPS Mean Li -79461.60A (Li) 7917991.00A Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 45 Sc 45 Se 45 Se 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 72 Ge 72 Ge 72 Ge 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 115 In 115 In 115 In 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 159 Tb 165 Ho 205 Tl 206 (Pb) 207 (Pb) 208 Pb 7970.17 P 38071.99P 80964.98 P 86783.83 P 15028.11P 50302.97 P 7811.61 P 5655816.00A 725914.00A 18390580.00A 348.45P 4826.63 P 6010.64 P 3725.86P 472681.50 P

7766.16P 2113.07 P 6019.10P 2887.44 P 2462.91 P 1446652.00A 486976.50A 3706852.00A 848.03 P 397.67 P 251.78P 6495.05 P 56656.70 P 20691.20 P

526.70 P 25541.62 P

430.02 P 5435.98 P 10203640.00A 5045017.00A 20863360.00A 13751. 63 P 7726.86 P 31247.88 P 38870.35 P 6946.42 P 23940950.00A 22745950.00A 29920.09 P 10595.71 P 8881.08 P 41176.38 P

ISTD Elements so 2580.00 145200.00 175.20 676.50 477.80 402.60 310.50 1255.00

89.84 22800.00 4685.00 22150.00 14.63 54.44 118.30 58.50 3106.00

97.06 22.48 148.80 28.49 55.45 8970.00 2930.00 29900.00 18.82 16.71 9.98 29.63 727.40 458.40 28.48 640.80 43.34 4.16 97010.00 30340.00 161600.00 129.00 113.50 344.50 247.70 299.00 357200.00 219600.00 203.10 70.72 93.92 396.90 RSo(%) 3.25 1.83 2.20 1.78 0.59 0.46 2.07 2.49 1.15 0.40 0.65 0.12 4.20 1.13 1.97 1.57 0.66 1.25 1.06 2.47 0.99 2.25 0.62 0.60 0.81 2.22 4.20 3.96 0.46 1.28 2.22 5.41 2.51 10.08 0.08 0.95 0.60 0.77 0.94 1.47 1.10 0.64 4.30 1.49 0.97 0.68 0.67 1.06 0.96

Element CPS Mean RSD(%:) Ref Value -88139.43 Ree (%) QC Range (%) Li -79461.60 3.25 45 Se 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 5655816.500.405590061.50 725914 .00 0.65 732360.19 18390584.00 0.12 18013604.00 1446651.60 0.62 1407958.90 486976.50 0.60 475526.09 3706851.80 0.81 3640663.30 10203645.00 0.95 10055673.00 5045017.00 0.60 4993515.00 20863356.00 0.77 20883300.00 23940950.00 1.4923533162.00 22745950.00 0.97 22278996.00 90.2 70- 101.2 99.1 102.1 102.7 102.4 101.8 101.5 101.0 99.9 101.7 102.1 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- Cal Coef 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

Flag 120 IS Fail 120 120 120 120 120 120 120 120 120 120 120

ISTD Ref File : c,\ lCPCHEM\l\oATA\12 127s00.B\004CALB.o\004CALB.on

:Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD: Pass 

### Fail :Max. Number of Failures Allowed ;Max. Number of ISTD Fa'ilures Allowed

C.\ ICPCHEM\l\RPTTMP\CalStdx.qct Page 1of19/27{12 6:41 PM C: \ICPCHKK\l\DATA\12127.00 .B\OD6CA[..B.D\DD6CALB .DI



### Calibration Standard QC Report

Data File: Date Acquired: c,\ ICPCHEM\l\OATA\12I27s00.B\006CALS.0\006CALS.0# Sep 27 2012 06,37 pm Operator: NBS Sample Name: 120927 Standard 2 Misc Info: Vial Number: 1104 Current Method: Calibration File: Last Cal Update: 

### c,\ ICPCHEM\l\METIiOOS\CSC-MOL2

.M C, \ ICPCHEM\l\CALIB\CSC-MOL2.C Sep 27 2012 06,34 pm Sample Type: CalStd Total Oil Factor 1 1.00

QC&ISTD Blements Element CPS Mean 6 Li -74083.47 A (Li) 7913410.00A Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 45 Se 45 Se 45 Se 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 72 Ge 72 Ge 72 Ge 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) III Cd 115 In 115 In 115 In 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 159 Tb 165 Ho 205 TI 206 (Pb) 207 (Pb) 208 Pb 81222.73 P 87464.79P 234750.70 P 949219.81A 139950.59 P 134157.09 P 59557.17 P 5740691.00A 742203.63 A 18341010.00A 3050.58P 44537.78 P 53512.48 P 34925.81P 4801609.00 A

76642.34 P 19623.14 P 53709.16 P 26038.59 P 11630.56 P 1458780.00A 484064.91 A 3698306.00A 8034.24 P 3848.08 P 994.37P 60448.72 P 533160.13P 198190.41P

4991.06 P 251216.20 P

3921.78 P 53158.30 P 10266880.00A 5091337.00A 20604500.00A

120525.40 P 67725.74 P 276397.41P 384442.50 P 67506.51 P 23944500.00 A 22713590.00A

297932.00 P 101841.80 P 85295.77 P 398321.00 P

ISTD Elements SO 7907.00 91270.00

652.90 327.50 661.30 10050.00

279.10 961.80 301.00 42720.00 2871.00 251300.00 46.58 283.80 194.00 253.20 19380.00

184.80 83.34 828.10 179.50 101.4 0 19640.00 4098.00 34850.00

135.60 74.35 21. 61 318.20 1797.00 813.00 55.11 2057.00 111.30 235.10 104900.00 31490.00 118900.00

1746.00 283.70 714.90 2318.00 455.50 117700.00 38770.00 2700.00 1444.00 403.20 1278.00 RSO(') 10.67 1.15 0.80 0.37 0.28 1.06 0.20 0.72 0.51 0.74 0.39 1.37 1.53 0.64 0.36 0.72 0.40 0.24 0.42 1.54 0.69 0.87 1.35 0.85 0.94 1.69 1.93 2.17 0.53 0.34 0.41 1.10 0.82 2.84 0.44 1.02 0.62 0.58 1.45 0.42 0.26 0.60 0.67 0.49 0.17 0.91 1.42 0.47 0.32 Cal Coef 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 

## o.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000

Element CPS Mean RSO (') 6 Li -74083.48 10.67 Ref Value -88139.43 5590061.50 732360.19 Ree(') QC Range(%) 84.170- 120 120 120 120 120 120 120 120 120 120 120 120 45 Se 5740691.50 0.74 45 Se 742203.63 0.39 45 Se 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 18341012.00 1.37 18013604.00 1458780.30 1.35 1407958.90 484064.94 0.85 475526.09 3698305.80 0.94 3640663.30 10266882.00 1.02 10055673.00 5091337.50 0.624993515.00 20604496.00 0.58 20883300.00 23944504.00 0.4923533162.00 22713588.00 0.17 22278996.00 102.7 70- 101.3 70

- 101.8 103.6 101.8 101.6 102.1 102.0 98.7 101.7 102.0 70

- 70

- 70

- 70

- 70

- 70

- 70

. 70

- 70

-

ISTD Ref File : c,\ ICPCHEM\l\ DATA\12127800.B\004CALB.0\004CALB .0#

:Element Failures

:ISTD Failures



### Data Results: Analytes: ISTD: Pass Fail :Max. Number of Failures Allowed

:Max. Number of ISTD Failures Allowed

C. \ICPCHEM\l\RPTTMP\Calstdx.qct Flag IS Fail

Page 1of 1127/126;48 PM c:\ICPC'HID4\l\DATA\12127.00.B\007CALS.D\007CALS.D'



### Calibration Standard QC Report

Data File: Date Acquired: c,\ ICPCHEM\l\ DATA\12127s00.B\007CALS .D\007CALS.0# Sep 27 2012 06,44 pm Operator: NBS Sample Name: 120927 Standard 3 Misc Info: Vial Number: 1105 Current Method: Calibration File: C, \ ICPCHEM\ 1\METHODS\CSC-MDL2.M C,\ ICPCHEM\l\CALIB\CSC-MDL2.C Last Cal lJpdate: sep 27 2012 06;41 pm Sample Type, Total Dil Factor: CalStd 1.00

QC&ISTD Elements Element CPS Mean 6 Li -79024.59A (Li) 7966219.00A Be II B 23 Na 24 Mg 27 Al 39 K 44 Ca 45 Sc 45 Sc 45 Sc 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 72 Ge 72 Ge 72 Ge 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 115 In 115 In 115 In 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 159 Tb 165 Ho 205 Tl 206 (Pb) 207 (Pb) 208 Pb 872271.00A 613779.31M 1950815.00A 8859926.00A 1531080.00A 1046506.00A 561527.38P 5718452.00A 736497.38A 18361220.00A 30192.44 P 428244.00 P 509199.31 P 337043.31P 46317472.00A

731149.63 P 187009.09P 504469.50 P 245330.00 P 98290.86P 1438381.OOA 483861.31 A 3729901.00A

76900.68P 36547.99P 8096.61 P 582633.00 P 5624660.00A 2120572.00A

47918.89P 2626533.00A

37867.33 P 519130.69 P 10120670.00A 4917685.00 A 20177140.00A 1295272.00A 652734.38 P 2960587.00A 4142146.00 A 660981.69 P 23522870.00 A 22364340.00A 3204610.00A 1000439.00M 800689.50 P 4062204.00 A

ISTD Elements Element CPS Mean RSD (\) 6 Li -79024.59 7.40 45 Sc 5718452.50 0.07 so 5848.00 71360.00 7312.00 44090.00 15320.00 98930.00 23660.00 2598.00 3857.00 3854.00 5865.00 75080.00

307.40 549.90 2544.00 566.30 495900.00

1897.00 1713.00 4586.00 1438.00 852.70 17480.00 2149.00 12090.00

245.70 470.60

18.53 2861.00 49530.00 25750.00

261.50 25480.00

366.80 2242.00 152600.00

7485.00 108100.00 12340.00 3736.00 13350.00 33260.00 3160.00 156100.00 200200.00 24170.00 72930.00 4088.00 50350.00

Ref value -88139.43 5590061.50 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 736497.38 0.80 732360.19 18361224.00 0.4118013604.00 1438381.50 1.22 1407958.90 483861.34 0.44 475526.09 3729900.80 0.32 3640663.30 10120667.00 1.51 10055673.00 4917685.50 0.15 4993515.00 20177142.00 0.54 20883300.00 23522868.00 0.6623533162.00 22364342.00 0.9022278996.00 RSD(%) 7.40 0.90 0.84 7.18 0.79 1.12 1.55 0.25 0.69 0.07 0.80 0.41 1.02 0.13 0.50 0.17 1.07 0.26 0.92 0.91 0.59 0.87 1.22 0.44 0.32 0.32 1.29 0.23 0.49 0.88 1.21 0.55 0.97 0.97 0.43 1.51 0.15 0.54 0.95 0.57 0.45 0.80 0.48 0.66 0.90 0.75 7.29 0.51 1.24

Rec(%) QC Range(%)

89.7 70- 102.3 70- 100.6 70- 101.9 70- 102.2 101.8 102.5 100.6 98.5 96.6 100.0 100.4 70

- 70

- 70

- 70

- 70

- 70

- 70

- 70

- Cal Coef 0.0000 0.2996 1.0000 0.9996 0.9999 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.9981 0.0000 0.0000 0.0000 1.0000 1.0000 0.9999 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.0000 0.0000 1.0000 1.0000 1.0000 1.0000

Flag 120 IS Fail 120 120 120 120 120 120 120 120 120 120 120

ISTD Ref File , c,\ ICPCHEM\l\ DATA\12127500.B\004CALB.D\004CALB.0#

:Element Failures 1 : ISTD Failures



### Data Results: Analytes: ISTD: Pass 

### Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C.\ICPCHEM\l\RPTTMP\CalStdx.qct Page 1of 1C:\ICPCHEM\l\DATA\12I27.00.B\OOB_OCS.D\OOB_OCS.D#



### QCS QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12127S00.B\008_QCS.D\008_QCS.D# Sep 27 2012 06:50 pm Operator: Sample Name: Mise Info: 

### Vial Number: Current Method: 

### Calibration File: Last Cal Update: Sample Type: Total 

### Dil Factor: NBS ICV 120927

1107 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm QCS 1.00

QC Elements Element Cone. RSD(%) Expected QC Range(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 37.18 ug/l 38.97 ug/l 3855.00 ug/l 4156.00 ug/l 3592.00 ug/l 3861.00 ug/l 4049.00 ug/l

27.29 ug/l 40.04 ug/l 40.21 ug/l 40.60 ug/l 3997.00 ug/l

39.88 ug/l 40.53 ug/l 39.86 ug/l 39.71 ug/l 40.19 ug/l 37.43 ug/l 39.26 ug/l 39.03 ug/l 37.96 ug/l 38.34 ug/l 34.83 ug/l ug/l 192.80 ug/l ug/l 38.37 ug/l 3.58 ug/l 3.40 ug/l 3.07 ug/l 35.59 ug/l 37.63 ug/l 38.32 ug/l ug/l ug/l 36.78 ug/l 1. 94 1.46 2.29 1.18 1.11 0.77 0.72 0.65 1.58 1.55 1.08 1.43 0.48 0.47 1.02 1.36 0.71 0.68 1.65 2.04 0.67 1.33 0.92

2.11

1.30 2.07 3.36 6.25 0.67 1.71 2.03

1.41

ISTD Elements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50

732360.19 Li -88795.66 10.54 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 5927146.50 753954.75 18857634.00

1478545.50 493392.72 3761570.30 10422317.00 5103784.00 20926948.00 23880362.00 22720544.00 1.44 1.31 1.13 18013604.00 0.34 1407958.90 0.42 475526.09 0.79 3640663.30 0.43 10055673.00 0.65 4993515.00 0.60 20883300.00 1.68 23533162.00 0.75 22278996.00 100.00 90 110 40.00 40.00 4000.00 4000.00 4000.00 4000.00 4000.00

40.00 40.00 40.00 40.00 4000.00

40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 40.00 20.00 20.00 20.00 40.00 40.00 40.00 40.00 40.00 40.00 90

- 110 90

- 110 90 110 90

- 110 90 110 90

- 110 90 110 90

- 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90 110 90 110 90 110 90 110 90

- 110 90 110 90

- 110 90

- 110 90 110 90 110 90 110 90

- 110 90 110 90 110 90 110

Rec(%) QC Range(%)

100.7 106.0 102.9 104.7 105.0 103.8 103.3 103.6 102.2 100.2 101.5 102.0 70 70 120 120 70

- 120 70 120 70

- 120 70

- 120 70 120 70 120 70 120 70 120 70 120 70 120 Flag

Fail

Fail

Fail 

# lIlT

Fail

Fail; Fail 

# ,JI
Fail Fail

Flag IS Fail 

# fJl!..

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#



### :Element Failures 0 :Max. Number of Failures Allowed :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: 

### Fail ISTD: 

### Fail

9/27112 6:54 PM C:\ICPCHEM\l\rpttmp\QCS.qct Page 1of 1

### c, \ICPCHEII\1\DATA\l2127.00 .B\OlO_CCB.D\OlO_CCB.D#



### CCB QC Report

Data File: Date Acquired: C,\ICPCHEM\1\DATA\12127s00.B\010_CCB.D\010_CCB.D# Sep 27 2012 07:04 pm Operator: NBS Sample Name: ICB 120927 

### Mise Info: Vial Number: CUrrent Method: 

### Calibration File: Last Cal Update: 1102 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: CCB Total Dil Factor: l.00

QC Elements Element Cone. RSD(%) 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Sa 205 TI 206 (Pb) 207 (Pb) 208 Pb ug/l 0.00 ug/l 0.90 ug/l 0.23 ug/l 0.10 ug/l -0.05 ug/l 3.36 ug/l -l.44 ug/l -0.09 ug/l -0.02 ug/l 0.00 ug/l 0.01 ug/l -0.15 ug/l 0.00 ug/l 0.01 ug/l 0.01 ug/l -0.01 ug/l 0.09 ug/l 0.02 ug/l 0.01 ug/l 0.14 ug/l 0.00 ug/l 0.00 ug/l -0.05 ug/l ug/l 0.09 ug/l ug/l 0.00 ug/l 0.09 ug/l 0.14 ug/l 0.09 ug/l 0.05 ug/l 0.00 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l 81.81 21.58 437.74

78.33 157.16 39.23 211.78 28.27 49.03 208.69

4.74 14.60 142.63 124.30 69.47 114.24 26.79 17.73 87.64 44 .66 164.77 131.57

0.57

7.90

244.22

4.02 9.99 21.33 10.62 86.58 16.25

59.11

ISTD Elements Element CPS Mean RSD(%) Ref Value Li -88949.12 4.47 -88139.43 45 Sc 5875857.00 l.06 559006l.50 45 Sc 748267.06 0.51 732360.19 45 Sc 18769994.00 0.85 18013604.00 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 1480136.50 49304l. 34 3731785.50 10478834.00 5105096.50 21188870.00 23826704.00 22633512.00 l.04 1407958.90 0.24 475526.09 1.31 3640663.30 0.61 10055673.00 1.05 4993515.00 0.63 20883300.00 0.91 23533162.00 0.46 22278996.00 High Limit ####### 0.12 15.00 77.10

7.50 3.96 19.20 90.00 0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%)

100.9 70 105.1 70 102.2 70

- 104.2 70 105.1 70 103.7 102.5 104.2 102.2 101.5 10l.2 101.6 70 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail

Fail

Flag IS Fai.

ISTD Ref File: C:\ICPCHEM\1\DATA\12127s00.B\004CALB.D\004CALB.D#



### :Element Failures :Max. Number of Failures Allowed 1 :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/271127:08 PM C:\ICPCHEM\l\rpttmp\CCB.qct Page 1 of 1C,\ICPCIIEM\l\DATA\12I27.00.B\OllSMPL.D\OllSMPL.D#



### Sample QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I27S00.B\011SMPL.D\011SMPL.D# Sep 27 2012 07,10 pm
Sample Name, Mise Info: NBS LLICV 120927

Vial Number, Current Method: Calibration File: Last Cal Update, Sample Type, Prep Dil Factor: 1103 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample 1.00 Total Dil Factor, 1.00

QC Elements Element (Li) Cone. ug/l 0.94 ug/l 1.61 ug/l 21.86 ug/l 241.90 ug/l

89.74 ug/l 18.44 ug/l Carr. Cone. #VALUEI 0.94 1.61 21.86 241.90

89.74 18.44 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 cu 65 CU 66 

### Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb 267.80 ug/l 1.90 ug/l 1.00 ug/l 1.03 ug/l 1.02 ug/l 98.99 ug/l

1.04 ug/l 1.06 ug/l 1.04 ug/l 1.05 ug/l 1.71 ug/l 0.99 ug/l 0.99 ug/l 1.12 ug/l 1.01 ug/l 0.91 ug/l 1.72 ug/l ug/l 0.96 ug/l ug/l 0.99 ug/l 1.87 ug/l 2.00 ug/l 1.82 ug/l 1.79 ug/l 0.97 ug/l 0.91 ug/l ug/l ug/l 0.95 ug/l 267.80 1.90 1.00 1.03 1.02 98.99

1.04 1.06 1.04 1.05 1.71 0.99 0.99 1.12 1.01 0.91 1.72 #VALUEI 0.96 #VALUEI 0.99 1.87 2.00 1.82 1.79 0.97 0.91 #VALUEI #VALUEI 0.95

ISTD Elements Element 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho CPS Mean RSD (%) -82968.41 3.72 5940541.00 0.98 Ref Value -88139.43 5590061.50 760440.06 18896988.00

1483715.10 492921.63 3742942.00 10470458.00 5203708.00 21196740.00 23949770.00 22659082.00 0.95 732360.19 1.33 18013604.00 0.58 1407958.90 0.97 475526.09 0.30 3640663.30 1.40 10055673.00 0.81 4993515.00 0.72 20883300.00 1.07 23533162.00 0.31 22278996.00 RSD(%) High Limit Flag 

## o 5.62 1000 4.89 1000 1.53 25000 0.67 50000 2.02 20000 1.34 20000 0.42 50000 4.71 1000 1.00 1000 1.21 1000,01, 

### 'J. 1.98 1000 0.60 20000 1.49 1.80 2.63 2.35 4.40 0.84 0.83 14.43 2.75 2.08 1.58

1.24

1.17 1.11 3.69 0.29 1.59 0.93 2.17

1.14

Rec(%)

94.1 106.3 103.8 104.9 105.4 103.7 102.8 104.1 104.2 101.5 101.8 101.7 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 

### "1"1./. 

### 0,,, 'I.

" I '/.



### <If**~** 

### 'I.

QC Range (%) Flag 70 120 IS Fai 70 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 120 70

- 70 120 120

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#

o :Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/271127:14 PM 

### Pass Fail o :Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C,\ICPCHBM\l\rpttmp\Sample.qct Page 1of 1CI\ICPCHEM\l\Dl1'A\1:1: UhOO.B\012IC6'1.D\012ICS1.pM



### ICS-A QC Report

Data Flle: Date Acquired: C,\ICPCHEM\1\DATA\12I27S00.B\012ICSA.D\012ICSA.D# Sep 27 2012 07,17 pm Acq. Method, Operator: Sample Name: Mise Info: Via1 Number: Current Method: Calibration File: Last Cal. Update, Sample Type, Di1ution Factor:

OC Elements Element IS Ref 7 (Ll) 9 Be 45 11 B 45 23 Na 45 24 Mg 45 27 Al 45 39 K 45 44 Ca 45 47 Ti 45 51 V 45 52 Cr 45 55 Mn 45 56 Fe 45 59 Co 45 60 Ni 45 63 Cu 45 65 Cu 45 66 Zn 115 75 As 115 78 Se 115 78 Se 115 88 Sr 115 88 Sr 115 95 Mo 115 106 (cd) 107 Ag 115 108 (Cd) 111 Cd 115 118 Sn 115 118 Sn 115 118 Sn 115 121 Sb 115 137 Ba 115 205 Tl 159 206 (pb) 207 (Pb) 208 Pb 159

ISTD Elements Element 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho Tune

3

1 2

3

3 3

3

3 3 3 3

Tune

3

3 CSC-MDL2.M NBS FGD MATRIX

2101 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm ICSA 1.00

Cone. ug/l 0.03 ug/l 0.29 ug/l 899900.00 ug/l 911300.00 ug/l 6.68 ug/l 19.78 ug/l 1954000.00 ug/l 0.13 ug/l 0.17 ug/l 0.62 ug/l 0.83 ug/l 14.05 ug/l 0.22 ug/l 1.67 ug/l 0.08 ug/l 0.31 ug/l 1.02 ug/l 0.62 ug/l 0.32 ug/l 1.33 ug/l 122.00 ug/l 120.50 ug/l

0.02 ug/l ug/l 0.19ug/1 ug/l 0.06 ug/l 1.96 ug/l 2.24 ug/l 2.00 ug/l 3.67 ug/l 2.31 ug/l 0.05 ug/l ug/l ug/l 1.84 ug/l

CPS Mean -89208 5404673 809597 RSD(%) 3.74 0.37 1.07 17657602 0.71 1149240 0.48 433848 0.87 3080454 7954718 4127340 15664644 16644687 15533937 0.91 0.35 0.40 0.61 0.36 0.90 RSD(%)

19.15 14.65 0.42 0.21 2.59 6.75 0.77 25.09 5.68 0.94 1.51 0.79 5.64 1.64 17.60 3.21 6.50 4.29 7.76 10.75 0.19 0.90 27.19

3.86

13.80 1.65 2.99 1.98 0.95 3.04 4.90

0.64

Ref Value -88139 5590062 732360 18013604 1407959 475526 3640663 10055673 4993515 20883300 23533162 22278996

Tune Flle# c'\lcpchem\1\7500\h2_hITQ.u Tune File# c'\lcpchem\1\7500\he_hmi.u Tune Flle# c'\lcpchem\1\7500\ng_hml.u Data Results: Analytes: Fail ISTD: Fail

Hlgh LiITQ t ppb

Rec (%) 101.2 96.7 110.5 98.0 81. 6 91.2 84.6 79.1 82.7 75.0 70.7 69.7 ..:68.55 3 75

QC Range (%)

70 120 70 120 70

- 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70 120 70

- 120 70

- 120 70 120 Flag



### Pail Fall

Flag IS Fail

IS Fall 

# tJr

ISTD Ref File, C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

:Element Failures :Max. Number of Fallures Allowed :ISTD Failures :Max. Nnumber of ISTD FaIlures Allowed

9/27/127:21 PM C:\ICPCHEM\1\RPTTMP\6020ICSA.qct Page 1of 1CI\ICPCHD(\l\DATA\12%27

..00.»\013ICSB.D\013ICSB

### .n"

ICS-AB QC Report

Data File: Date Acquired: Acq. Method: Operator: Sample Name: MIse Info: Vial Number: Current Method: Calibration File: Last Cal. Update: Sample Type: DIlutIon Factor:

OC Elements C:\ICPCHEM\1\DATA\12I27s00.B\013ICSB.D\013ICSB.D# Sep 27 2012 07:24 pm CSC-MDL2.M NBS FGD MATRIX SPIKED

2102 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm ICSAB 1.00 Data Results: Analytes: Fail ISTD: Fail

Element IS Ref Tune Conc. ppb RSD(%) Expected 100 40 40 5000 5000 4000 %Recovery #VALUEI

82.2 85.4 16002.0 16314.0 106.2 OC Range(%) 7 (Li) --------.------. 70 130 Be 11 B 23 

### Na 24 Mg 27 Al 39 K 44 Ca 47 Tl 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 115 115 115 115 115 115 115

115

115 115 115 115 115 115 159

159

ISTD Elements Element 6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho

Tune Flle# Tune FlIeD Tune File# 3 2

2 2

2 2 2 2 2 2 2 2

1 2

3 3

2 3

3 3

Tune

3 1 2 3 1 32.87 34.16 800100.00 815700.00

4249.00 4303.00 1773000.00 31.00 42.83 40.01 41. 63 3655.00

35.80 35.19 32.21 0.30 0.73 0.92 0.70 6.31 0.75 0.36 1. 11 0.12 0.40 0.37 0.19 0.59 0.64 0.92 32.48 0.22 43.41 1.46 55.45 0.91 53.82 3.84 65.47 0.97 166.70 4.80 156.70 1.54 45.24 1.68

35.73 0.89

41.32 0.94 5.40 3.36 5.94 0.62 5.40 0.84 43.62 1.51 45.24 1.52 31.95 0.96

36.15 0.45

CPS Mean -102651 5930639

861957 19232968 1267534 472114 3412355 8534682 4348852 17382268 17918272 RSD(%) 5.40 1.42 0.40 0.94 0.68 1.27 1. 86 1.38 0.29 1.37 0.77 16728765 0.72 40 6000

40 40 40 40 4000

40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 20 20 20 20 20 40 40 40 40

Ref Value -88139 5590062

732360 18013604 1407959 475526 3640663 10055673 4993515 20883300 23533162 22278996
c:\lcpchem\1\7500\h2_hmi.u c:\lcpchem\1\7500\he_hml.u c:\lcpchem\1\7500\ng_hmi.u 10757.5 29550.0



### 77.5 107.1 100.0 104.1 91.4 89.5 88.0 80.5 81.2 108.5 138.6 134.6 163.7 416.8 391.8 113.1 #VALUEI

89.3 #VALUEI

103.3 27.0 29.7 27.0 218.1 226.2 79.9 #VALUEI #VALUE!

90.4

Rec (%) 116.5 106.1 117.7 106.8 90.0 99.3 93.7 84.9 87.1 83.2 76.1 75.1 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 10 10 10 10 70 10 10 10 70 10 10 10 10 10 10 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130

OC Range(%) 70 120 10 120 10 120 10 120 10 120 70 120 10 120 10 120 70 120 10 120 70 120 10 120

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

:Element FaIlures

: ISTD FaIlures :Max. Number of FaIlures Allowed :Max. Number of ISTD Failures Allowed Flag

Fall Fall Fall**~""\**

Fall 

### ..,T Fail pJ 

### T

Flag IS Fail 

# tvl

9127112 7:28 PM C:\ICPCHEM\I\RPTTMP\6020ICSB.qct Page 1011C:\ICPCHEM\l\OATA\12I27s00.B\OlS_CC:V.0\OlS_CC:V.0#



### CCV QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27s00.B\015_CCV.D\015_CCV.D# Sep 27 2012 07:37 pm Operator: NBS Sample Name: CCV 120927 Mise Info: Vial Number: CUrrent Method: Calibration File: Last Cal Update: 1106 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: CCV Total Dil Factor: 1.00

QC Elements Element (Li) Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l 51.59 ug/l 53.71 ug/l 1353.00 ug/l 13310.00 ug/l 5651.00 ug/l 987.10 ug/l 13350.00 ug/l

103.00 ug/l 50.77 ug/l 48.95 ug/l 50.71 ug/l 4898.00 ug/l

48.96 ug/l 48.03 ug/l 47.69 ug/l 47.47 ug/l 52.39 ug/l 53.30 ug/l 53.83 ug/l 57.06 ug/l 54.14 ug/l 51.77 ug/l 101.90 ug/l ug/l 51.06 ug/l ug/l 50.43 ug/l 94.28 ug/l 101.80 ug/l 102.50 ug/l 101.00 ug/l 50.52 ug/l 49.83 ug/l ug/l ug/l 48.80 ug/l

Element CPS Mean RSD(%) Li -146158.83 7.35 45 Sc 6267881.50 0.66 RSD(%) Expected QC Range(%) 50.00 90

- 110 1.68 50.00 90 110 0.94 50.00 0.27 1250.00 0.57 12500.00 1.29 5000.00 0.78 1000.00 0.42 12500.00 90 110 90 110 90 110 90 110 90

- 110 90

- 110 0.40 100.00 90 110 0.78 50.00 90 110 1.01 50.00 90 110 0.32 50.00 90 110 0.825000.00 90

- 110 90

- 110 0.21 0.89 1.10 0.70 1.13 0.94 1.21 1.47 0.47 3.18 2.63

1.88

2.54 2.21 0.54 2.70 1.66 2.83 1.35

1.17

Ref Value -88139.43 5590061.50 50.00 50.00 90

- 110 50.00 90 110 50.00 90

- 110 50.00 90

- 110 50.00 90 110 50.00 90 110 50.00 90

- 110 50.00 90 110 50.00 90 110 100.00 90

- 110 50.00 90

- 110 50.00 90 110 50.00 90 110 50.00 90

- 110 #####

- ##### ##### ##### 100.00 90

- 110 100.00 90

- 110 50.00 90

- 110 50.00 90 110 50.00 90 110 50.00 90

- 110 50.00 90

- 110

Rec(%) QC Range(%) 70 70 120 120 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 846493.06 23068482.00

1560514.30 536636.25 4480422.50 10577996.00 0.24 732360.19 1.71 18013604.00 165.8 112.1 115.6 128.1 110.8 112.9 123.1 105.2 105.1 118.0 118.7 118.0 70

- 120 70 120

5248140.00 24646030.00 27943412.00 26300172.00 0.75 0.16 1407958.90 475526.09 2.14 3640663.30 0.77 10055673.00 0.54 4993515.00 2.51 20883300.00 1.16 23533162.00 1.97 22278996.00 70 70

- 120 120 70

- 120 70

- 120 70

- 120 70 120 70 120 70

- 120 Flag

Fail 

### (IfI

Fail ""

Flag IS Fail 

## fJ'I

IS Fail**~r**

IS Fail 

## N7

ISTD Ref File: C:\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

2 :Element Failures :Max. Number of Failures Allowed 3 :ISTD Failures :Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/27112 7:41 PM C:\ICPCHEM\l\rpttmp\CCV.qct Page 1of 1C,\ ICPCHEM\1\DATA\12I27.00 .8\017_CC8.D\017_CCB.D#



### CCB QC Report

Data File, Date Acquired, Operator, Sample Name, Mise Info: C,\ICPCHEM\1\DATA\12I27s00.B\017_CCB.D\017_CCB.D# Sep 27 2012 07,50 pm NBS CCB 120927

Vial Number, CUrrent Method, Calibration File: Last Cal Update, Sample Type, Total Dil Factor: 1102 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm CCB 1.00

QC Elements Element Cone. RSD(%) 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 TI 206 (Pb) 207 (Pb) 208 Pb ug/l 0.00 ug/l 0.63 ug/l -1.62 ug/l 5.65 ug/l 0.90 ug/l 9.32 ug/l 10.27 ug/l -0.08 ug/l 0.03 ug/l -0.04 ug/l 0.01 ug/l -0.13 ug/l 0.00 ug/l 0.00 ug/l 0.04 ug/l 0.04 ug/l 0.03 ug/l 0.04 ug/l 0.01 ug/l 0.81 ug/l 0.01 ug/l 0.01 ug/l -0.06 ug/l ug/l 0.01 ug/l ug/l 0.00 ug/l 0.14 ug/l 0.17 ug/l 0.08 ug/l 0.06 ug/l 0.00 ug/l 0.00 ug/l ug/l ug/l 0.00 ug/l 25.72 159.78 43.51

5.79 76.56

9.93 3.67 9.45 16.89 5.99 23.51 70.12 11.85 228.39 41.76 41.95 17.22 12.70 145.05

0.44 76.88

3.68 7.21

10.82

462.37

14.86 11.79 6.81 8.47 356.02

29.10

3.88

ISTD Elements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -162468.08 6371934.00

863803.63 24647802.00

1602456.50 553437.50 4742773.50 10869377.00 5512092.00 27402228.00 30665950.00 29010666.00 3.51 1.06 0.21 732360.19 3.08 18013604.00 1.37 1407958.90 0.19 475526.09 2.88 3640663.30 0.94 10055673.00 0.61 4993515.00 2.40 20883300.00 3.60 23533162.00 3.75 22278996.00 High Limit ####### 0.12 15.00 77.10 7.50 3.96 19.20 90.00

0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%)

184.3 70 114.0 70 117.9 70 136.8 70 113.8 70 116.4 130.3 108.1 110.4 131.2 130.3 130.2 70 70 70 70 70 70 70 120 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail

Fail

Flag IS fai.

IS fai.

# ,.J"

IS fai: 

### ,.1"1'

IS fai: IS fai.**~** IS fai.

# tlr

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB D#

2 :Element Failures 6 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/271127:54 PM 

### Fail Fail :Max. Number of Failures Allowed :Max. Number of ISTD Failures Allowed

C,\ICPCHBM\l\rpttmp\CCB.qct Page 1of 1C,\ ICPClIEK\1\DATA\lZI27.00 .B\OZ9_CCV,D\OZ9_CCV.D#



### CCV QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I27S00.B\029_CCV.D\029_CCV.D# Sep 27 2012 09,11 pm NBS Sample Name: CCV 120927 Mise Info: Vial Number: Current Method, Calibration File: Last Cal Update, Sample Type, Total Dil Factor: 1106 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm

QC Elements Element 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 

### K 44 Ca 47 Ti 51 

### V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 

### Zn 75 As '78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd)' 111 Cd 

## 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements CCV l.00

Cone. ug/l 56.34 ug/l 56.33 ug/l 1404.00 ug/l 13820.00 ug/l 6025.00 ug/l 1064.00 ug/l 14170.00 ug/l

107.50 ug/l 52.82 ug/l 50.17 ug/l 52.78 ug/l 5038.00 ug/l

50.16 ug/l 49.06 ug/l 48.71 ug/l 48.73 ug/l 52.25 ug/l 53.88 ug/l 56.73 ug/l 58.24 ug/l 57.11 ug/l 51.49 ug/l 100.60 ug/l ug/l 50.61 ug/l ug/l 49.57 ug/l 100.20 ug/l 105.40 ug/l 103.10 ug/l 100.20 ug/l 5l.04 ug/l 49.23 ug/l ug/l ug/l 48.44 ug/l

Element CPS Mean RSD(%) Li -172280.63 1.60 45 Sc 6272232.00 0.49 45 Sc 848366.50 1.99 RSD(%) Expected QC Range(%)

3.88 0.71 50.00 90 110 50.00 50.00 2.67 1250.00 1.9212500.00 1.84 5000.00 l.82 1000.00 1.2812500.00 0.50100.00 90 110 90

- 110 90

- 110 90 110 90 110 90 110 90 110 90 110 2.15 50.00 90

- 110 90 110 90

- 110 90

- 110 l.92 50.00 2.44 50.00 2.31 5000.00 2.17 2.65 2.43 1.73 0.87 0.94 1.32 1. 56 0.48 0.52 0.93

0.91

0.71 0.87 0.66 l.34 l.27 l.72 0.30

0.98

Ref Value -88139.43 5590061.50

732360.19 50.00 90 50.00 90 50.00 90 50.00 90 50.00 90 50.00 90 50.00 90 50.00 90 50.0090 50.00 90 100.00 90 50.00 90 50.00 90- 50.00 90 50.00 90 ##### ##### 100.00 90 100.00 90 50.00 90

- 50.00 90- 50.00 90 50.00 90 50.00 90 110 110 110 110 110 110 110 110 110 110 110 110 110 110 110 ##### #####

110 110 110 110 110 110 110

Rec(%) QC Range(%) 70

- 120 70 120 70 120 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 24084944.00 1579056.60 535948.06 4741855.50 10599475.00 0.37 18013604.00 195.5 112.2 115.8 133.7 112.2 112.7 130.2 105.4 107.0 130.0 128.1 128.2 70 120

5340990.50 27140082.00 30135526.00 28552696.00 0.54 l.36 0.33 1407958.90 475526.09 3640663.30 1.24 10055673.00 0.59 4993515.00 0.63 20883300.00 0.81 23533162.00 0.23 22278996.00 70

- 120 70

- 120 70

- 120 70 70 120 120 70 120 70 120 70

- 120 Flag

Fail Fail Fail Fail Fail

Fail

Fail Fail 

## r-rt Fail ,J-(

Flag IS Fail

IS Fail 

# tl T \"t.**~** ,.... .,,1:('

IS Fail

# '1' W"(

IS Fail IS Fail IS Fail 

### ,,.rI

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#

9 :Element Failures 6 :ISTD Failures



### Data Results: Analytes: ISTD:

9/271129:14 PM 

### Fail Fail o :Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C,\ICPCHEM\l\rpttmp\CCV.qct Page 1 01 1C,\ICPCHEM\l\OATA\12127s00.B\031_CCB.0\031_CCB.0#



### CCB QC Report

Data File, Date Acquired: C,\ICPCHEM\1\DATA\12I27s00.B\031_CCB.D\031_CCB.D# Sep 27 2012 09,24 pm Operator: NBS Sample Name: CCB 120927 Mise Info: Vial Number: CUrrent Method: 

### Calibration**File~** Last Cal Update, Sample Type, Total 

### oil Factor, 1102 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm

QC Elements 

### Element 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements CCB 1.00



### Cone. ug/l 0.00 ug/l 1.56 ug/l 10.50 ug/l 4.37 ug/l 1.89 ug/l 18.69 ug/l -3.04 ug/l -0.10 ug/l 0.05 ug/l -0.05 ug/l 0.01 ug/l -0.12 ug/l 0.00 ug/l 0.00 ug/l -0.05 ug/l -0.05 ug/l 0.04 ug/l 0.04 ug/l 0.02 ug/l 1.09 ug/l 0.00 ug/l 0.00 ug/l -0.06 ug/l ug/l 0.01 ug/l ug/l 0.00 ug/l 0.23 ug/l 0.25 ug/l 0.14 ug/l 0.07 ug/l 0.00 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l

Element CPS Mean RSD(%) RSD(%)

59.73 13.88 14.11 8.27 7.81 8.34 89.04 22.86

5.06 3.89 58.53 32.32 53.22 202.63

1.13 18.31 48.80 12.18 37.29 15.73 206.16

99.85 11.72

4.73

84.95 6.76 8.21 0.36 4.71 158.60

9.85

90.19 High Limit ####### 0.12 15.00 77 .10 7.50 3.96 19.20 90.00 0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%) Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -173881.47 6067105.50

827457.19 23537194.00

1521434.40 526629.31 4657299.00 10656626.00 6.82 0.78 Ref Value -88139.43 5590061.50 197.3 70 120

5351477.50 27788430.00 31549506.00 29754092.00 1.18 732360.19 2.31 18013604.00 0.26 1407958.90 1.55 475526.09 0.98 3640663.30 0.38 10055673.00 1.06 4993515.00 0.98 20883300.00 0.51 23533162.00 0.37 22278996.00 108.5 113.0 130.7 108.1 110.7 127.9 106.0 107.2 133.1 134.1 133.6 70 70

- 70 70 70 70

- 70 70 70 70 70 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail

Fail

Flag IS Fai.

IS FaL

IS FaL

IS Fai. IS Fai. IS Fai. 

### ,.I

....
ISTD Ref File, C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

2 :Element Failures :Max. Number of Failures Allowed 6 ,ISTD Failures ,Max. Number of ISTD Failures Allowed



### Data Results: Analytes: Fail ISTD: Fail

9/271129:28 PM C,\ICPCHEM\l\rpttmp\CCB.qct Page 1of 1CI \ICPCHEM\l\DATA\12127aOO.B\043_CCV.D\043_CCV.ell



### CCV QC Report

Data File, Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I27S00.B\043_CCV.D\043_CCV.D# Sep 27 2012 10,44 pm NBS Sample Name: CCV 120927 Mise Info: Vial Number, Current Method, Calibration File: Last Cal Update, Sample Type, Total Dil Factor, 1106 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm CCV 1.00

QC Elements 

### Element Cone. RSD(%) Expected QC Range(%) 7 (Li) ug/l 51.83 ug/l 52.45ug/l 1381.00 ug/l 13700.00 ug/l 6093.00 ug/l 1090.00 ug/l 14410.00 ug/l 50.00 90 110
9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 

### V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements 107.20 ug/l 51.99 ug/l 49.43 ug/l 53.23 ug/l 5059.00 ug/l

49.81 ug/l 48.22 ug/l 47.77 ug/l 47.71 ug/l 49.64 ug/l 51.63 ug/l 54.07 ug/l 57.61 ug/l 57.37 ug/l 50.80 ug/l 96.77 ug/l ug/l 49.38 ug/l ug/l 48.92 ug/l 100.30 ug/l 105.30 ug/l 103.10 ug/l 98.56 ug/l 53.47 ug/l 50.49 ug/l ug/l ug/l 50.07 ug/l 0.69 50.00 0.76 50.00 0.67 1250.00 0.20 12500.00 0.29 5000.00 0.73 1000.00 0.81 12500.00 0.28 100.00 0.97 50.00 1.20 50.00 0.43 50.00 0.82 5000.00 0.68 50.00 1.00 0.43 1.08 0.58 0.42 0.46 0.66 0.41 1.42 1.78

0.71

1.40 0.41 0.61 1.31 0.90 1. 80 0.78

0.53 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 50.00 100.00 50.00 50.00 50.00 50.00

100.00 100.00 50.00 50.00 50.00 50.00 50.00 90 110 90

- 110 90

- 110 90

- 110 90

- 110 90 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90

- 110 90 110 90

- 110 90

- 90 90 90

- 90 90 90

- 90 90 90 90

- 90 90 ##### 110 110 110 110 110 110 110 110 110 110 110 110 110 ##### #####

- ##### 90 110 90

- 110 90

- 110 90

- 110 90 110 90

- 110 90

- 110

Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50

732360.19 Rec(%) QC Range(%)
6 Li 45 Sc 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho -155881.72 5090510.50

694128.56 21533240.00

1281427.10 444393.19 4358286.00 8980917.00 4570515.50 26421628.00 31529898.00 30090092.00 3.56 1.16 0.63 0.63 18013604.00 0.53 1407958.90 1.49 475526.09 0.55 3640663.30 0.62 10055673.00 0.62 4993515.00 0.70 20883300.00 0.95 23533162.00 1.11 22278996.00 176.9 91.1 94.8 119.5 91.0 93.5 119.7 89.3 91.5 126.5 134.0 135.1 70 120 70 120 70

- 120 70 120 70

- 120 70

- 120 70

- 120 70

- 120 70 120 70 120 70 120 70 120 Flag

Fail

Fail

Fail

Fail

# ti'

Fail 

## tJ 1"

Flag 

### <" IS Fail 

## t'\

IS Fail IS Fail IS Fail 

## sJ\

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#

5 :Element Failures 4 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 10:48 PM 

### Fail Fail

## o ,Max. Number of Failures Allowed 

## o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\CCV.qct Page 1of 1C:\ICPCHE>!\l\OATA\12I27.00.B\04S_CCB.O\04S_CCB.01



### CCB QC Report

Data File: Date Acquired: C:\ICPCHEM\1\DATA\12I27s00.B\045_CCB.D\045_CCB.D# Sep 27 2012 10:58 pm Operator: NBS Sample Name: CCB 120927 Mise Info: Vial Number: Current Method: Calibration File: Last Cal Update: 1102 C:\ICPCHEM\1\METHODS\CSC-MDL2.M C:\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06:48 pm Sample Type: CCB Total Dil Factor: 1.00

QC Illements Element Cone. RSD(%) 7 (Li) 9 Be 11 

### B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb ug/l 0.00 ug/l 0.06 ug/l 9.16 ug/l 1.71 ug/l 2.77 ug/l 29.43 ug/l -15.65 ug/l

-0.09 ug/l 0.03 ug/l -0.07 ug/l 0.01 ug/l 0.00 ug/l 0.00 ug/l -0.01 ug/l -0.07 ug/l -0.07 ug/l 0.00 ug/l 0.03 ug/l 0.01 ug/l 1.55 ug/l 0.00 ug/l 0.00 ug/l -0.07 ug/l ug/l 0.01 ug/l ug/l 0.00 ug/l 0.19 ug/l 0.23 ug/l 0.11 ug/l 0.05 ug/l 0.00 ug/l 0.01 ug/l ug/l ug/l 0.00 ug/l 29.75 176.45

5.93 17.63 5.23 6.52 11.43 34.50 16.32 4.58 70.90 1289.00

17.56 101.00 10.91 12.01 1695.90 9.35 78.05 9.50 217.07

52.01 6.39

6.47

400.43

14 .18 8.15 8.65 8.35 280.02

10.25

150.75

ISTD Illements Element CPS Mean RSD(%) Ref Value -88139.43 5590061.50 6 Li -165741.77 2.45 45 Sc 5106580.00 1.08 45 Sc 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 697391.88 22109682.00

1269388.10 449594.13 4386039.50 9082652.00 4681851.50 27747928.00 31902092.00 30507590.00 0.67 732360.19 0.31 18013604.00 0.97 1407958.90 1.82 475526.09 0.83 3640663.30 1.47 10055673.00 0.37 4993515.00 0.23 20883300.00 0.60 23533162.00 1.05 22278996.00 High Limit ####### 0.12 15.00 77.10

7.50 3.96 19.20 90.00

0.78 0.21 0.12 0.18 40.80

0.09 0.48 0.39 0.39 6.90 0.27 0.30 0.30 0.03 0.03 0.21 ####### 0.09 ####### 0.06 ####### ####### 0.30 0.03 0.12 0.03 ####### ####### 0.33

Rec(%) QC Range(%)

188.0 70 91.4 70 95.2 70 122.7 70 90.2 70 94.5 70 120.5 70

- 90.3 93.8 132.9 135.6 136.9 70

- 70 70 70 70 120 120 120 120 120 120 120 120 120 120 120 120 Flag

Fail "'"

Fai 1

## ~-(

Fail 

# rJ-(

Flag 

# -r
IS FaL

# r

IS FaL ",-(

IS FaL 

## N\

IS FaL IS Fai IS FaL

ISTD Ref File : C:\ICPCHEM\1\DATA\12127S00.B\004CALB.D\004CALB.D#

3 :Element Failures 6 :ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 11:02 PM 

### Fail Fail :Max. Number of Failures Allowed 

## o :Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\CCB.qct Page 1of 1

# METALS

Raw Data

# METALS BLANK

APPL Inc. 908 North Temperance Avenue Clovis, CA 93611

Method Analyte Result 

## PQL Units Prep Date Analysis Date QC Group
200.8 ARSENIC (AS) Notdetected 0.5 ug/L 09/20/12 09/26/12 #2008-120920A-AY67404 200.8 CADMIUM (CD) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-AY67404 200.8 CHROMIUM (CR) Not detected 0.5 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 200.8 LEAD (PB) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 200.8 SELENIUM (SE) Not detected 1.0 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404 200.8 THALLIUM (TL) Not detected 0.2 ug/L 09/20/12 09/26/12 #2008-120920A-A Y67404

200.8 ARSENIC (AS) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-AY67411 200.8 CADMIUM (CD) Not detected 0.20 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 200.8 CHROMIUM (CR) Notdetected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 200.8 LEAD (PB) Notdetected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 200.8 SELENIUM (SE) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411 200.8 THALLIUM (TL) Not detected 0.2 ug/L 09/20/12 09/27/12 #2008-120920A-A Y67411

------------------------------------------------------.-----------------.-------------------_.-------------------------------._------.---------------._--------------------------------



### Printed: 101011125:23:48 PMC, \ICPCHEM\l\ DATA\12I26qOO.B\066SMPL.D\066SMPL.DI



### Sample QC Report

Data File: Date Acquired, Operator, Sample Name, 

### Mise Info: C,\ICPCHEM\1\DATA\12I26qOO.B\066SMPL.D\066SMPL.D# Sep 26 2012 11,47 pm NBS 120921A-1638-BLK 120921A-1638 Vial Number: 3207 Current Method: 

### Calibration File: C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Last Cal Update, Sample Type, Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 cr 55 Mn 56 Fe 59 Co 60 Ni 63 CU 65 CU 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l -0.02 ug/l 38.44 ug/l -4.10 ug/l -2.03 ug/l -5.59 ug/l 16.77 ug/l -128.40 ug/l

-0.11 ug/l -0.07 ug/l -0.03 ug/l -1.40 ug/l -5.00 ug/l -0.03 ug/l -0.01 ug/l 0.04 ug/l 0.03 ug/l -2.44 ug/l -0.01 ug/l 0.29 ug/l 0.78 ug/l -0.49 ug/l -0.41 ug/l 0.00 ug/l ug/l -0.01 ug/l ug/l -0.03 ug/l -3.46 ug/l -3.62 ug/l -3.18 ug/l 0.02 ug/l -0.06 ug/l -0.02 ug/l ug/l ug/l -0.02 ug/l

Element CPS Mean RSD(%) 6 Li -101898.27 3.96 45 Sc 3980021.80 0.22 45 Sc 526890.69 1.25 18955604.00 1020355.50 1.14 0.97 0.46 Carr. Cone. #VALUE!

-0.02 38.44 -4.10 -2.03 -5.59 16.77 -128.40

-0.11 -0.07 -0.03 -1.40 -5.00 -0.03 -0.01 0.04 0.03 -2.44 -0.01 0.29 0.78 -0.49 -0.41 0.00 #VALUE!

-0.01 #VALUE!

-0.03 -3.46 -3.62 -3.18 0.02 -0.06 -0.02 #VALUE! #VALUE!

-0.02

Ref Value -131996.50 3646344.80

537987.94 17012292.00

949396.31 338792.91 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 337668.31 3918444.50 7427485.50 3674193.80 25471844.00 30928492.00 29656830.00 0.99 3456710.80 0.35 6610579.00 0.88 3651775.30 0.49 22769202.00 0.72 28649686.00 0.58 27453282.00 RSD(%) High Limit 

## o 5.21 1000 1.62 1000 14.44 25000 2.21 50000 7.66 20000 33.23 20000 2.46 50000 19.51 1000 4.39 1000 13.96 1000 0.40 1000 0.56 20000 2.61 1000 100.82 1000 23.95

7.89 0.93 103.72

7.55 39.08

1.91 0.35 145.60

5.57

5.50 0.38 0.37 0.03 12.62 1.43 10.54

2.45 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000

QC Range(%) Rec(%)

77 .2 109.2 97.9 111.4 107.5 70

- 120 70

- 120 70 120 70

- 120 70

- 120 99.7 113.4 112.4 100.6 111.9 108.0 108.0 70

- 70 70 70 70

- 70 70 120 120 120 120 120 120 120 Flag

Flag IS ·Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#

o :Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/26112 11 :51 PM 

### Pass Failo :Max. 

### Number of 

### Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1C.\ICPCHEM\l\OATA\12127800.B\020SMPL.O\020SMPL. oj



### Sample QC Report

Data File, Date Acquired: C,\ICPCHEM\1\DATA\12I27s00.B\020SMPL.D\020SMPL.D# Sep 27 2012 OB,ll pm Operator: Sample Name, Mise Info: Vial Number: NBS 120920A-163B-BLK 120920A-163B 3205 Current Method: Calibration File: C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Last Cal Update, Sample Type, Sep 27 2012 06,4B pm Sample Prep oil Factor, Total Oil Factor, 1.00 1.00

QC Elements Element Conc. Carr. Conc. #VALUE! 0.00 0.66 -3.96 7 (Li) 9 Be 11 B 23 

# Na
24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 CU 66 Zn 75 As 7B Se 7B Se BB Sr BB Sr 95 Mo 106 (Cd) 107 Ag lOB (Cd) 111 Cd 11B Sn llB Sn llB Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 20B Pb ug/l 0.00 ug/l 0.66 ug/l -3.96 ug/l 3.B4 ug/l -3.09 ug/l 11.36 ug/l -9.79 ug/l -0.07 ug/l 0.02 ug/l -0.04 ug/l 0.03 ug/l 0.23 ug/l 0.00 ug/l 0.16 ug/l 0.02 ug/l 0.03 ug/l 0.00 ug/l 0.02 ug/l 0.00 ug/l 0.60 ug/l 0.00 ug/l 0.01 ug/l -O.OB ug/l ug/l 0.00 ug/l ug/l 0.00 ug/l -0.09 ug/l -0.06 ug/l -0.09 ug/l 0.05 ug/l 0.00 ug/l 0.00 ug/l ug/l ug/l 0.00 ug/l 3.B4 -3.09 11.36 -9.79 -0.07 0.02 -0.04 0.03 0.23 0.00 0.16 0.02 0.03 0.00 0.02 0.00 0.60 0.00 0.01 -O.OB #VALUE! 0.00 #VALUE! 0.00 -0.09 -0.06 -0.09 0.05 0.00 0.00 #VALUE! #VALUE! 0.00

ISTD Elements Element CPS Mean RSD(%) Ref Value

- 88139.43 5590061.50

732360.19 6 Li -152224.53 4.32 45 Sc 6221422.50 0.3B 45 Sc B61960.69 0.B4 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 229B9646.00 1565471

. 50 546797.56 4560489.00 108755B8.00 5554323.00 2683122B.00 29800406.00 28234376.00 0.49 18013604.00 0.69 1407958.90 1.47 475526.09 1.50 3640663.30 1.05 10055673.00 0.18 4993515.00 1.40 20B83300.00 0.79 23533162.00 0.43 22278996.00 RSD(%) High Limit 

## o 2068.70 1000

18.79 1000 11.36 25000

1.64 50000 11.20 20000 8.79 20000 24.03 50000 59.41 1000 19.99 1000 4.58 1000 3.10 1000 32.78 20000 21.33 1000

1.87 1000 43.81 1000 46.53 1000 200.61 1000

17.74 1000 238.63 1000

10.56 1000 153.12 1000 28.74 1000

2.74 1000 ####### 6.88 500 ####### 178.50 1000

16.43 ####### 33.70 ####### 4.25 1000 16.70 1000 60.96 1000 18.05 1000 ####### ####### 48.50 1000

QC Range(%) 70 120 70 120 70 120 70 120 70 120 70 120 Flag

Flag IS fai

IS fai Rec(%)

172.7 111.3 117.7 127.6 111.2 115.0 125.3 108.2 111.2 128.5 126.6 126.7 70 120 IS Fai 70

- 120 70

- 120 70

- 120 IS Fai 70

- 120 IS Fai 70

- 120 IS Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27s00.B\004CALB.D\004CALB.D#

o :Element Failures 6 ,ISTD Failures



### Data Results: Analytes: ISTD:

9/27112 8: 14 PM 

### Pass Fail :Max. Number of Failures Allowed ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1 of 1

## APPL 

## Inc. 908 North Temperance Avenue Clovis, CA93611

Method Compound Name

200.8 ARSENIC (AS)
200.8 CADMIUM (CD)
200.8 CHROMIUM (CR)
200.8 LEAD (PB) 200.8 SELENIUM (SE) 200.8 THALLIUM (TL)



## Comments: 

# Laboratory Control Spike Recovery METALS

Spike Level SPK Result SPK% Recovery Extract ug/L ug/L Recovery Limits Date

1.00 1.1 110 85-115 

## 09/20/12
1.00 1.1 110 85-115 

## 09/20/12
1.00 0.99 99.0 85-115 

## 09/20/12
1.00 0.98 98.0 85-115 

## 09/20/12
1.00 1.1 110 85-115 

## 09/20/12
1.00 0.91 91.0 85-115 

## 09/20/12 Analysis Date



## 09/27/12 09/27/12 09/27/12 09/27/12 09/27/12 09/27/12



# ---------------------------------------------------------------------- QC Group

#2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-AY67411 #2008-120920A-A Y67411

Printed: 101011125:07:31 PM APPL StandardLCSC,\ICPCHEM\l\DATA\12127s00.B\021SKPL.**D\021SKPL.D~**



### Sample QC Report

Data File: Date Acquired, Operator: C,\ICPCHEM\1\DATA\12I27s00.B\021SMPL.D\021SMPL.D# Sep 27 2012 08,17 pm
Sample Name, 

### Mise Info: NBS 12092OA-1638-LCS 120920A-1638 Vial Number: CUrrent Method, Calibration File: Last Cal Update, Sample Type, 3206 C,\ICPCHEM\1\METHODS\CSC-MDL2.M C,\ICPCHEM\1\CALIB\CSC-MDL2.C Sep 27 2012 06,48 pm Sample Prep Dil Factor, Total Dil Factor: 1. 00 1.00

QC Elements Element (Li) Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 Cu 65 Cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb

ISTD Elements Cone. ug/l 1.10 ug/l 1.57 ug/l 23.41 ug/l 56.71 ug/l 17.04 ug/l 3l.71 ug/l 48.63 ug/l

0.97 ug/l 1.06 ug/l 0.99 ug/l 1.09 ug/l 20.76 ug/l

1.02 ug/l 1.20 ug/l 1.05 ug/l 1.06 ug/l 1.33 ug/l 1.09 ug/l 1.14 ug/l 1.92 ug/l 1.10 ug/l 0.94 ug/l 0.77 ug/l ug/l 0.47 ug/l ug/l 1.05 ug/l 0.82 ug/l 0.91 ug/l 0.78 ug/l 0.93 ug/l 1.04 ug/l 0.91 ug/l ug/l ug/l 0.98 ug/l

Element CPS Mean RSD(%) 6 Li -180040.25 5.15 45 Sc 6265600.50 1.13 45 Sc 869270.13 0.86 

### Cerro 

### Cone. #VALUEI 1.10 1.57 23.41 56.71 17.04 31.71 48.63

0.97 1.06 0.99 1.09 20.76

1.02 1.20 1.05 1.06 1.33 1.09 1.14 1.92 1.10 0.94 0.77 #VALUEI 0.47 #VALUEI 1.05 0.82 0.91 0.78 0.93 1.04 0.91 #VALUEI #VALUEI 0.98

Ref Value -88139.43 5590061.50

732360.19 45 Sc 72 Ge 72 Ge 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 23586592.00 1577643.30 546680.13 4628849.50 10957130.00 0.43 18013604.00

5603903.00 27068172

.00 30816206.00 29108454.00 0.88 1.10 0.35 1407958.90 475526.09 3640663.30 0.86 10055673.00 0.65 4993515.00 0.30 20883300.00 0.64 23533162.00 1.24 22278996.00 RSD(%)

1.81 7.32 7.50 0.75 5.46 9.32 7.31 3.49 1.49 1.31 1.12 1.47 1.26 3.31 0.86 3.89 4.61 0.57 3.45 3.71 1.37 0.73 1.34

2.10

0.82 3.64 2.96 2.12 2.20 1.43 1.52

0.44

Rec(%)

204.3 112.1 118.7 130.9 112.1 115.0 127.1 109.0 112.2 129.6 130.9 130.7 High Limit 

## o 1000 1000 25000 50000 20000 20000 50000 Flag

1000 1000 1000 1000 

# qq 'j.

20000

1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 ####### 500 ####### 1000 ####### ####### 1000 1000 1000 1000 ####### ####### 1000 

# ql!**q~·I.**

QC Range(%) Flag 70

- 120 IS Fai 70 120 70

- 120 70 120 IS Fai 70 120 70 120 70

- 120 IS Fai 70

- 120 70

- 120 70

- 70

- 70 120 IS Fai 120 IS Fai 120 IS Fai

ISTD Ref File , C,\ICPCHEM\1\DATA\12I27S00.B\004CALB.D\004CALB.D#



### :Element Failures :ISTD 

### Failures



### Data Results: Analytes: ISTD:

9/271128:21 PM 

### Pass Failo :Max. 

### Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed

C:\ICPCHEM\l\rpttmp\Sample.qct Page 1of 1

# Laboratory Control Spike Recovery METALS

APPL 

## Inc. 908 

## North Temperance Avenue Clovis, CA 93611



## Method Compound Name Spike Level SPK Result SPK% Recovery Extract Analysis ug/L ug/L Recovery Limits Date Date

200.8 ARSENIC (AS) 250 257 103 85-115 09/20/12 09/26/12
200.8 CADMIUM (CD) 50.0 47.6 95.2 85-115 09/20/12 09/26/12
200.8 CHROMIUM (CR) 250 285 114 85-115 09/20/12 09/26/12
200.8 LEAD (PB) 250 229 91.6 85-115 09/20/12 09/26/12
200.8 SELENIUM (SE) 250 269 108 85-115 09/20/12 09/26/12 200.8 THALLIUM (TL) 250 226 

## 9004 85-115 09/20/12 09/26/12



## Comments:

____________________________________________________________________ __ QC Group

#2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404 #2008-120920A-AY67404

Printed: 101011125:07:31 PM APPL StandardLCSCI \ICPCHEM\l\DATA\12126qOO.B\067SMPL.D\067SMPL.cll



### Sample QC Report

Data File, Date Acquired, Operator, Sample Name, 

### Mise Info: C,\ICPCHEM\1\DATA\12I26qOO.B\067SMPL.D\067SMPL.D# Sep 26 2012 11,54 pm NBS 120921A-1638-LCS 120921A-1638 3208 Vial Number: current Method, 

### Calibration File: C,\ICPCHEM\l\METHODS\CSC-MDL.M C,\ICPCHEM\l\CALIB\CSC-MDL.C Last Cal Update, Sample Type, Sep 26 2012 05,18 pm Sample Prep Dil Factor, Total Dil Factor, 1.00 1.00

QC Elements 

### Element 7 (Li) 9 Be 11 B 23 Na 24 Mg 27 Al 39 K 44 Ca 47 Ti 51 V 52 Cr 55 Mn 56 Fe 59 Co 60 Ni 63 cu 65 cu 66 Zn 75 As 78 Se 78 Se 88 Sr 88 Sr 95 Mo 106 (Cd) 107 Ag 108 (Cd) 111 Cd 118 Sn 118 Sn 118 Sn 121 Sb 137 Ba 205 Tl 206 (Pb) 207 (Pb) 208 Pb Conc. ug/l 44.26 ug/1 289.40 ug/l 24820.00 ug/l 25720.00 ug/l

1763.00 ug/l 4851.00 ug/l 25010.00 ug/l

251.90 ug/l 282.50 ug/l 285.00 ug/l 255.70 ug/l 1032.00 ug/l 282.30 ug/l 264.80 ug/l 263.30 ug/l 261.90 ug/l 453.30 ug/l 256.70 ug/l 268.50 ug/l 259.10 ug/l 270.20 ug/l 241.50 ug/l 225.80 ug/l ug/l 92.59 ug/l ug/l 47.61 ug/l 218.90 ug/l 216.50 ug/l 200.60 ug/l 221.20 ug/l 256.90 ug/l 225.80 ug/l ug/l ug/l 229.10 ug/l

ISTD B1ements 

### Carr. Conc. #VALUE!

44.26 289.40 24820.00 25720.00

1763.00 4851.00 25010.00

251.90 282.50 285.00 255.70 1032.00 282.30 264.80 263.30 261.90 453.30 256.70 268.50 259.10 270.20 241.50 225.80 #VALUE!

92.59 #VALUE!

47.61 218.90 216.50 200.60 221.20 256.90 225.80 #VALUE! #VALUEI

229.10 RSD(%) High Limit 

## o 0.70 1000 0.45 1000 2.13 25000 1.76 50000 2.39 20000 1.77 20000 1.97 50000 2.68 1000 2.81 1000 2.38 1000 2.75 1000 2.43 20000 2.71 1000 2.51 1000 2.22 1000 2.19 1000 0.78 1000 0.47 1000 0.55 1000 0.39 1000 0.55 1000 0.53 1000 0.81 1000 ####### 0.32 500 ####### 1.18 1000 0.79 ####### 0.38 ####### 0.20 1000 0.98 1000 1.21 1000 0.44 1000 ####### ####### 0.56 1000 Flag

Element CPS Mean RSD(%) Ref Value Rec(%) 75.6 107.5 96.9 107.6 103.6 97.8 107.7 108.0 QC Range (%) Flag 6 Li -99735.90 5.93 -131996.50 45 Sc 3919895.80 0.99 3646344.80 45 Sc 521538.72 2.17 537987.94 45 Sc 18298404.00 0.79 17012292.00 72 Ge 983780.88 0.17 949396.31 72 Ge 331282.41 0.80 338792.91 72 Ge 115 In 115 In 115 In 159 Tb 165 Ho 3722552.80 7137157.50 3509093.00 24109940.00 30015476.00 29011228.00 1.65 3456710.80 0.48 6610579.00 0.46 3651775.30 0.03 22769202.00 1.01 28649686.00 1.08 27453282.00 96 .1 105.9 104.8 105.7 70 120 IS fai 70

- 120 70 120 70

- 120 70 120 70 120 70

- 120 70 120 70

- 120 70

- 120 70 120 70

- 120

ISTD Ref File , C,\ICPCHEM\1\DATA\12I26qOO.B\004CALB.D\004CALB.D#



### o :Element Failures 1 ,ISTD Failures



### Data Results: Analytes: ISTD: 

### Pass Failo ,Max. Number of Failures Allowed

o ,Max. Number of ISTD Failures Allowed 

# ,)'\

9/26/1211:57 PM C,\ICPCHEM\1\rpttmp\Samp1e.qct Page 1of 1

# 004**t~etals** 

# Standards log Book 

# #

4- 

# Hg WORKING STANDARD 

# 7470Al7471/24S.1 1ml X 10ug/ml Hg STOCK STD. (09/14/12RJS)/200ml 1% 

## HN03 Lot#L12065 1ml X 10ug/ml Hg STOCK 

# ICV**(09/14/12RJ~)~00rpl** 

## 1% 

## HN03 Lot#L12065 Final concentration is 50 ug/L. Expires

......

# "?M~b.~

# ............

## , ,

-, ',:

"



### c.., )i I

# e~alsSt?tndard~ 

# Log Book

# #**',~** 

# Page # -

......<1



### STD**~** 

### w

## ~

# ~ !!i
w

# ~ i2 <i:

### ~ 

# '" 

# g

Vl

# ~

5 VARIOUS VARIOUS VARIOUS

# ~ 

# Hg WORKING STANDARD 

# 7470Al7471/24S.1 1ml X 10ug/ml Hg STOCK STD. (09/14/12RJS)/200mI1% HN03 Lot#L12065 1ml X 10ug/ml Hg STOCK ICV**(09/14/12RJS)/~~1**

# % HN03 Lot#L12065 Final concentration is 50 ug/L. Expires

.........

# ~.~?:**.~~**

# ..........

# ~s 

# Standards Log Book**t~**



# 5 CALA 0.05 

# B

Vl

## ~ 

## '" N 

## '"

# ~ N 

### <3 

### CONe Final 

# 005

# Metals Standards Log Book =# 006

STD**~** "-l

## ~

## ~ "-l

## ~

# ~ 0:;

### ~ 

# '" 0.1



## ..., -I

## ~ "-l -I 

# 8

# ~ o:l

'- 

# B

STD LOT EXPDATE



# c.---------, ICYB 0.8 (PI 12084-30612 09/20/13



# ----------------1

ICYA 02 (PI 12084-30611 09/20/13


# . l:....'--------------,



# ,-----------------,

# Met !s Standards 

# Log BOiok 

# # 3<;., 

# Page # 007

# .rtj~Gt fS 

# Standards Lo ' Book #**3~** 

# 009

Hg WORKING STANDARD 

# 7470Al7471/24S.1 1ml X 10ug/ml Hg STOCK STD. (09/14/12RJS)/200ml 

## 1% 

## HN03 Lot#L12065 1ml X 10ug/ml Hg STOCK ICV (09/14/12RJS)1290rlll)% 

## HN03 Lot#L12065 Final concentration is 50 ug/L. Expires

........**9./~k~**

# .........

STD

ICVB

ICVA

### ~----------~-------I 0.08

0.02 LOT

CPI 12084-30612

CPI 12084-30611 09/20/1310001-

_______ _

F2-MEB43 5088MCA na

# ~s 

# Standards Lo Book

# # 011

STD

><:: UJ

## ~ 

# -**~** UJ

## ~ 

# § f- 

### .;.;

### ~ a... 0.1



## ..., ....l 

# g;**~** 

# 5

# ~ §

# ,etafs Standards Lo 

# Book

# #

LOT EXPDATE



### '--
lCVB 0,08 

### Q>l 12084-30612 09/20/13



# --

--



# --

--

--

-- lCVA 0.02 

### Q>l 12084-30611 09/20/13



# ;-------------r----I**~**

# -- ,- ----------t----I



# --,-"-----+----------------4**--'------+-----------------=-~**



# f:**'~-:-----~------------------:-~**

# -:~"**----------+~------------------------------------------~a** -!

- -,j

# ~r-:----------I----------------------------------------_:~

# ~!.**----~---------------------~~** -i--

! 

# --'**"----------+-----------------------------------------~~ ~,--**  

# _I**~T-"----__t---------------------~ ---,'-'-~------+-------------------~~** 

# -'-.-----I------------------~

# .;::-----l----------------~

### Tune File Comment

m/z 7 89 205 156/140

70/140 140 

# r

e

# n - 

### r

### Page: 1 Range 50,000 100,000

50,000 2 2 100,000 

# (

- NG HMI.u 120926

Count 29153.0 65890.0 38361.0

1.554% 1.105% 67092.0 Tune Report

Mean 28824.2 66508.4 38281.0

1.574% 1.088% 66192.5



# /

r-

- 

### Integration Time: Sampling Period:

n: 

### 0.1000 sec 0.6200 sec 200 Oxide: 156/140 1.566% Doubly Charged: 70/140 1.119%

RSD% Background 2.00 2.70 2.10 3.20 2.31 14.70 4.97 4.82 2.08 8.40

m/z: 7 89 Height: 28,624 67,845

Axis: 6.95 88.95 W-50%: 0.65 0.65 W-l0%: 0.800 0.800
Integration Time: 0.1000 sec Acquisition Time: 22.7600 sec

Y axis Linear

Generated Printed Sep 26, 2012 13:51:19 Sep 26, 2012 13:51:22 205 39,192 204.95 0.60 0.7500

## Tune File Comment

Tuning Parameters 

## NG HMI.u 120926



## ===Plasma Condition=== RF Power 1600 W 

## RF Matching 1.7 V

Smpl Depth 8 mm Torch-H 0.2 mm Torch-V -0.2 mm Carrier Gas 0.7 L/min

Makeup Gas 0.3 L/min Optional Gas % 

## Nebulizer Pump 0.1 rps Sample Pump rps 

# sic Temp 2 degC

===Reaction Cell===

Reaction Mode OFF H2 Gas 0 

## mL/min

Page: 2 Tune Report

===Ion Lenses=== Extract 1 0 Extract 2 -140 Omega Bias-ce -24 Omega Lens-ce -0.4 Cell Entrance -30 QP Focus 5 Cell Exit -30
===Octopole Parameters=== OctP RF 180 OctP Bias -6

He Gas

Generated Printed 0 

## ===Q-Po1e Parameters=== V AMU Gain 128 V AMU Offset 126 V Axis Gain 0.9999 V Axis Offset -0.05 V QP Bias -3 V V ===Detector Parameters=== Discriminator Analog HV V Pulse HV V

mL/min Optional Gas

S

## ep 26, 2012 13: 51 : 19 

## Sep 26, 2012 13:51:24 

## 8 1720 1350



# --- V

mV V V

%

### C:\ICPCHEM\1\DATA\12126qOO.B\OOlTUNE.D



# 200.8 QC Tune Report

Data File: Date Acquired: Acq. Method: Operator: Sample Name: Misc Info: Vial Number: Current Method:

RSD (%) Element CPS Mean 9 Be 

# 1828908 24 Mg 

# 5674046 59 Co 

# 9252430 115 In 

# 39905972 208 Pb 

# 6904355

9/26/124:37 PM 

## C:\ICPCHEM\1\DATA\12I26qOO.B\001TUNE.D Sep 26 2012 04:35 pm TN200 8.M NBS 100ppb Tune sol

1303 C:\ICPCHEM\1\METHODS\TN200 8.M

Rep1 Rep2 Rep3 Rep4 1820953 1819237 1832929 1836726 5555187 5541242 5608233 5814412 9317050 9222301 9272642 9242114 Rep5 1834695 5851157 9208043 4017530839857856400056243958969639901376 6901831 6913951 6911489 6897688



## 9 Be Mass Calib. Actual: 8.95 Required:8.90 Flag: 

## Peak Width

24 Mg Actual: 0.65 Required:0.90 Flag:



## Mass Calib. Actual: 23.95 Required:23.90 Flag: 

## Peak Width Actual: 0.65 Required:0.80 Flag: 6896818



## C:\ICPCHEM\1\RPTTMP\2008tnrt.qct %RSD Required Flag 

## 0.47 5.00 

## 2.95 5.00 

## 0.49 5.00 

## 0.36 5.00 

## 0.73 5.00

9.10

24.10

Page 1 of2

## Tune Result: 

## Pass

9/26/124:37 PM C:\ICPCHEM\1\DATA\12126qOO.B\OOlTUNE.D



## 59 Co Mass Calib. Actual: 58.95 Required: 58.90 Flag: 

## Peak Width Actual: 0.60 Required: 0.90 Flag:



## 115 In Mass Calib. Actual: 114.95 Required: 114.90 Flag: 

## Peak Width Actual: 0.60 Required: 0.90 Flag:



## 208 Pb Mass Ca1ib. Actual: 207.95 Required: 207.90 Flag: 

## Peak Width Actual: 0.55 Required: 0.80 Flag:



## C:\ICPCHEM\1\RPTTMP\2008tnrt.qct 59.10

ll5.10

208.10

Page2of2

### Tune File Comment

m/z 7 89 205 156/140

70/140 140 

# /

-



### Page: 1 Range 50,000 100,000

50,000 5 2 100,000



# f

-

f-- 

### NG HMI.u 

## 120927

Count 31160.0 55876.0 28478.0

1.930% 1.427% 51157.0 Tune Report

Mean 31280.2 55563.2 28362.6

2.000% 1.

### 477% 52242.1 

# /

- 

### Integration Time: 0.1000 sec Sampling Period: 0.6200 sec
n: 200 Oxide: 156/140 Doubly Charged: 70/140

RSD% Background 1.

### 41 2.90 1.

### 98 3.30 2.14 8.30 4.11 5.08 2.09 6.00

m/z: 7 89 Height: 31,171 56,406

Axis: 6.95 88.95 W-50%: 0.65 0.65 W-10%: 0.7500 0.800
Integration Time: 0.1000 sec Acquisition Time: 22.7600 sec



## Y axis Linear

Generated Printed 

## Sep 

## 27, 2012 1 7 : 51 :44 Sep 

## 27, 2012 17:51:46 1.997% 1.

### 464%

205 28,435 204.95 0.60 0.800

## Tune File Comment

Tuning Parameters NG HMI.u 120927

===P1asma Condition=== RF Power 1600 W 

## RF Matching 1.7 V

Smpl Depth B mm Torch-H 0.2 mm Torch-V -0.2 mm Carrier Gas 0.7 L/min

Makeup Gas 0.3 L/min Optional Gas % 

## Nebulizer Pump 0.1 rps Sample Pump rps SIC Temp 2 degC

===Reaction Cell===

Reaction Mode OFF H2 Gas 0 mL/min

Page: 2 Tune Report

===Ion Lenses=== Extract 1 0 Extract 2 -140 Omega Bias-ce -24 Omega Lens-ce -0.4 Cell Entrance -30 QP Focus 5 Cell Exit -30
===Octopole Parameters=== OctP RF IBO OctP Bias -6

He Gas

Generated Printed 0 ===Q-Po1e Parameters=== V AMU Gain 12B V AMU Offset 126 V Axis Gain 0.9999 V Axis Offset -0.05 V QP Bias -3 V V ===Detector Parameters=== Discriminator Analog HV V Pulse HV V

mL/min Optional Gas

Sep 27, 2012 17:51:44 Sep 27, 2012 17:51:49 B 1720 1350



## - -- V

mV V V

%

### C:\ICPCHEM\1\DATA\12I27s00.B\OOlTUNE.D



# 200.8 QC Tune Report

Data File: Date Acquired: Acq. Method: Operator: Sample Name: Misc Info: Vial Number: Current Method:

RSD (%) 

## Element CPS Mean 9 Be 

# 3059314 24 Mg 

# 9872001 59 Co 

# 14536614 115 In 

# 50490691 208 Pb 

# 7076922

9/27/12 6:07 PM 

## C:\ICPCHEM\1\DATA\12I27s00.B\001TUNE.D Sep 27 2012 06:06 pm TN200 8.M NBS 100ppb Tune sol

1303 C:\ICPCHEM\1\METHODS\TN200 8.M



## Repl Rep2 Rep3 Rep4 2974824 3071305 3075572 3092106 9638955 9922088 9943710 9902779 Rep5 3082762 9952473 1411063314497120147084311469940914667477 4947086850433084510898805085078050608840 6791028 7154809 7111241 7206525

9 Be Mass Calib. 

## Actual: 8.95 Required:8.90 Flag: Peak Width

24 Mg 

## Actual: 0.65 Required:0.90 Flag:

Mass Calib. 

## Actual: 23.95 Required:23.90 Flag: Peak Width 

## Actual: 0.65 Required:0.80 Flag: 7121005

C:\ICPCHEM\1\RPTTMP\2008tnrt.qct %RSD 

## Required Flag 1. 83 

## 5.00 1.28 

## 5.00 1. 83 

## 5.00 1.27 

## 5.00 2.24 

## 5.00

9.10

24.10

Page 1of2

## Tune Result: 

## Pass

9/27/126:07 PM 

### C:\ICPCHEM\1\DATA\12127s00.B\OOlTUNE.D



## 59 Co Mass Calib. Actual: 58.95 

## Required: 58.90 Flag: 

## Peak Width Actual: 0.60 

## Required: 0.90 Flag:



## 115 In Mass Calib. Actual: 115.00 

## Required: 114.90 Flag: 

## Peak Width Actual: 0.60 

## Required: 0.90 Flag:



## 208 Pb Mass Calib. Actual: 207.95 

## Required: 207.90 Flag: 

## Peak Width Actual: 0.55 

## Required: 0.80 Flag:



## C:\ICPCHEM\1\RPTTMP\2008tnrt.qct 59.10

115.10

208.10

Page2of2

# MetalsDigestionWorksheet

MethodName 200.8 11.2 Digestion PrepMethod M2008 Set 120920A Units mL

Spiked ID2 LCSWLOT# 1037546-31168 Spiked ID 3 6020 HDLPREP: 9-20-12 SpikedID4 

# Spiked

# ByEA Date: 

## 09/20112 

# 1:40:00PM Witnessed

# By NM Date: 

## 09120112 

# 1:40:00PM
Sample

# I~ample Spike Spike

# I~igested Final StartDatelTime Comments Container lAmount ID Amount Volume 1120920ABlk

## IIIIIIIIII[I~II111111111111111111111111111111111111111111111111 

# I 50 50 09120/12 13:40 equip: Modblock2 1638 FGDMATRIX

2120920ALCS 

# I 0.5 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

111111111111111111111111111111111111111111111111111111111111111 

### 3MDL-0.25-1 

# I 0.25 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

4MDL-0.25-2 

# I 0.25 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

5MDL-O.25-3 

# I 0.25 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

6MDL-0.25-4 

# I 0.25 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

7MDL-0.25-5 

# I 0.25 

# I 3 

# I 50 50 09/20/12 13

### :40 equip: Modblock2

8MDL-0.25-6 

# I 0.25 

# I 3 

# I 50 50 09/20112 13:40 equip: Modblock2

9MDL-0.25-7 

# I 0.25 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

IOMDL-0.5-1 

# I 0.50 

# I 3 

# I 50 50 09/20/12 13

### :40 equip: Modblock2

IIMDL-0.5-2 

# I 0.50 

# I 3 

# I 50 50 09/20/12 13

### :40 equip: Modblock2

12MDL-0.5-3 

# I 0.50 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

13MDL-0.5-4 

# I 0.50 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

14MDL-0.5-5 

# I 0.50 

# I 3 

# I 50 50 09/20/12 13:40 equip: Modblock2

i 

### 15MDL-0.5-6 

# I 0.50 

# I 3 

# I 50 50 09/20112 13:40 equip: Modblock2

16MDL-0.5-7 

# I 0.50 

# I 3 

# I 50 50 09/20/1213:40 equip: Modblock2

# ~s{jf&'fifi\t~fiaTifffJWtlitl~~~~ri!m1:~fl.~ 1:1 HN03 8-28-12 

# Sampleprep employee Initials run 

### 1:1 HCL08-28-12 

# Analvst'sinitials EA 

# SamplePreparation run 

# Date Digestion run 

# Time Brin!! uptovolume run 

# Moved to METALS 

# Modified 101011123:08:34 PM



# ReviewedBy: EA 

# Date:.10/01112

101011123:08:39PM Page I ofI

# ,c;.""3,'6 MethodName 

# 200:-8 11.2 Digestion

Spiked ID 2 LCSWLOT# 1037546-31168 Spiked ID 3 6020 HDLPREP: 9-21-12 SpikedID 4 

# MetalsDigestionWorksheet /"3«; PrepMethod 

# Ml-008 Set 120921A

EndingTemp: 86 c TemperatureType: Mod Block Sufficient Vol forMatrix QC: Yes 

# Spiked By

# EA Date: 

# 09/211122:00:00 PM EndDatelTime 09/2111216:00 

# Witnessed By

# NM Date: 

# 09/211122:16:55 PM
Sample

# I~ample Spike Spike

# I~igested Final StartDatelTime Comments Container Amount ID Amount Volume 1120921ABik 

# I 50

1111111111111111111111111111111111111111111111111111111111111II 

### 50 09/21112 14:00 

### equip: Modblock2

212092IALCS

1 

### fllill

# lillll~illlllll~li11111111111III111111111111IIIIIUIIIII 

# I 0.5 

# I 1+2 1 

### 50 50 09/21112 14:00 

### equip: Modblock2

3BLKMDL0.4-1 

# ,I

iiifillillil11111II1IIIm11111111111111111111111111111/1111111111111111 ' 

### 0.2 1 

### 3 

# I 50 50 09/21112 14:00 

### equip: Modblock2

4BLKMDL0.4-2 

# ,I 0.2 

# I 3

11111111111111111111111111111111111111111111111111111111IllImllllllllll 1 

### 50 50 09/21/12 14:00 

### equip: Modblock2

5BLKMDL0.4-3 

# ,I

lIilllil!II'WI

# ITIlillllllJ/UlJIII

## 1IJ1111LIIIIJIIU~11I1I1I1I1I1I111 0.2 

# I 3 1 

### 50 50 09/21112 14:00 

### equip: Modblock2

6BLKMDL0.4-4 

# I 0.2 

# I 3

111111111111111111111111111111111111111111111111111111/1111111111111111 

# I 50 50 09/21112 14:00 

### equip: Modblock2

7BLKMDL0.4-5 

# I

IlIilll111111iii/lIIIlililll1111111111111111111111111111111111111111111111 

### 0.2 

# I 3 1 

### 50 50 09/21112 14:00 

### equip: Modblock2

8BLKMDL0.4-6 0.2 

# I 3

111111111111111111111111111111111111111111111111111111111111111111111111II 

# I 50 50 09/21112 14:00 equip: Modblock2

9BLKMDLO.4-7 

# ,I

I 1IIIIIIIilill

# iiill11111111111111111111111111111111111111111111111111111111 

### 0.2 

# I 3 1 

### 50 50 09/21112 14:00 equip: Modblock2 

# Units mL

.'**;"S~"o'Vl·~'·''"''.','e'!1%n~~l.a''''''n'''i?''h_;:t.'M.J.;lo,4!P,f#·?~.:.'l"1,~'.~** 

## ..**".:,·.'f.'_'::.ifI\i.:,;;.;,!.~.~_~·"".'.~~."t~.· ,:i1'.~,>;f;;**  

### ••**!.~z.L.1~.~ ~S'~1'ia':'m';~Wllke·";Q~ZJm1.??!a':::-n",W;s""e"~;:'¥.~~.\W("i$~;r,\l\1~~t~j,,\,,,,J:~~~i>1i:'** **~e' ~~c;~aw"""n'** **:l""tif.W:'r.'a'ifI'!1s";J~f~~~\IK4i'~~~li\)::t%.1i~~~l\\<ll~-S\!!?;rl** ,'t'o lA, UY..J.:J**-.tg:*"~-,,~.wt;_,~,]j~.-",,!,,&....",,,~** " •.:it.. !!

- .VJ**h~!~:~PJ::.I.~.I.~** 11**r~~~*i,§j:Mltj,~;,;;~~~~~~mrJ.;1****~",** 

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### HN03 IT 

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# Modified 09/21112 2:14:58 PM



# Reviewed By: 

# 'LA10/011123:13:11 PM Page 1of 1

# 6020/200.8 

# Injection Log Directory: K:\lCP-MS Optimus\raw data output csv\

RunlD Injected Sample Name Misc Info FileName Multiplier

26 Sep 2012 16:54 Calibration Blank 120926Arev 1. 2 26 Sep 2012 17:01 120926 Standard 1 120926Arev 1. 3 26 Sep 2012 17:08 120926 Standard 2 120926Arev 1. 4 26 Sep 2012 17:14 120926 Standard 3 120926Arev 1. 5 26 Sep 2012 17:21 ICV 120926 120926Arev 1. 6 26 Sep 2012 17:34 ICB 120926 120926Arev 1. 7 26 Sep 2012 17:41 LLlCV 120926 120926Arev 1. 8 26 Sep 2012 17:48 FGD MATRIX 120926Arev 1. 9 26 Sep 2012 17:54 FGD MATRIX SPIKED 120926Arev 1. 10 26 Sep 2012 18:08 CCV 120926 120926Arev 1. 11 26 Sep 2012 18:21 CCB 120926 120926Arev 1. 12 26 Sep 2012 18:34 FGD ICS

- Chloride 120926Arev 1. 13 26 Sep 2012 18:41 FGD ICS

- Calcium 120926Arev 1. 14 26 Sep 2012 18:48 FGD ICS

- Sulfate 120926Arev 1. 15 26 Sep 2012 18:54 FGD ICS

- Magnesium 120926Arev 1. 16 26 Sep 2012 19:01 FGD ICS

- Sodium 120926Arev 1. 17 26 Sep 2012 19:08 FGD ICS

- Boron 120926Arev 1. 18 26 Sep 2012 19:15 FGD ICS

- Iron 120926Arev 1. 19 26 Sep 2012 19:21 FGD ICS

- Nitrate 120926Arev 1. 20 26 Sep 2012 19:28 FGD ICS

- Manganese 120926Arev 1. 22 26 Sep 2012 19:41 CCV 120926 120926Arev 1. 23 26 Sep 2012 19:54 CCB 120926 120926Arev 1. 24 26 Sep 2012 20:01 FGD ICS

- Bromide 120926Arev 1. 25 26 Sep 2012 20:08 FGD ICS

- Fluoride 120926Arev 1. 26 26 Sep 2012 20:15 FGD ICS

- Selenium 120926Arev 1. 27 26 Sep 2012 20:21 FGD ICS

- Vanadium 120926Arev 1. 28 26 Sep 2012 20:28 FGD ICS

- Zinc 120926Arev 1. 29 26 Sep 2012 20:34 FGD ICS

- Chromium 120926Arev 1. 30 26 Sep 2012 20:41 FGD ICS

- Copper 120926Arev 1. 32 26 Sep 2012 21:14 CCV 120926 120926Arev 1. 33 26 Sep 2012 21:27 CCB 120926 120926Arev 1. 35 26 Sep 2012 22:47 CCV 120926 120926Arev 1. 36 26 Sep 2012 23:00 CCB 120926 120926Arev 1. 39 26 Sep 2012 23:47 120921A-1638-BLK 120926Arev 1. 40 26 Sep 2012 23:54 120921A-1638-LCS 120926Arev 1. 41 27 Sep 2012 00:07 1638 MDL-0.25-1 120926Arev 1. 43 27 Sep 2012 00:20 CCV 120926 120926Arev 1. 44 27 Sep 2012 00:33 CCB 120926 120926Arev 1. 45 27 Sep 2012 00:40 1638 MDL-0.25-2 120926Arev 1. 46 27 Sep 2012 00:47 1638 MDL-0.25-3 120926Arev 1. 47 27 Sep 2012 00:53 1638 MDL-0.25-4 120926Arev 1. 48 27 Sep 2012 01:00 1638 MDL-0.25-5 120926Arev 1. 49 27 Sep 2012 01:06 1638 MDL-0.25-6 120926Arev 1.

Page 1 01 Oct2012 16:59

## 50 27 Sep 2012 01:13 1638 MOL-0.25-7 120926Arev 1. 51 27 Sep 2012 01:20 BLK MOL 0.4-1 120926Arev 1. 52 27 Sep2012 01:27 BLK MOL 0.4-2 120926Arev 1. 53 27 Sep 2012 01:33 BLK MOL 0.4-3 120926Arev 1. 54 27 Sep 2012 01:40 BLK MOL 0.4-4 120926Arev 1. 56 27 Sep 2012 01:53 CCV 120926 120926Arev 1. 57 27 Sep 2012 02:07 CCB 120926 120926Arev 1. 58 27 Sep 2012 02:13 BLK MOL 0.4-5 120926Arev 1. 59 27 Sep 2012 02:20 BLK MOL 0.4-6 120926Arev 1. 60 27 Sep 2012 02:27 BLK MOL 0.4-7 120926Arev 1. 69 27 Sep 2012 03:27 CCV 120926 120926Arev 1. 70 27 Sep 2012 03:40 CCB 120926 120926Arev 1.

Page 2 01 

# Oct2012 16:59

# 6020/200.8 

# Injection Log Directory: K:\ICP-MS Optimus\raw data output csv\

RunlD Injected Sample Name Misc Info FileName Multiplier

74 27 Sep 2012 18:24 Calibration Blank 120927Arev 1. 75 27 Sep 2012 18:31 120927 Standard 1 120927Arev 1. 76 27 Sep 2012 18:37 120927 Standard 2 120927Arev 1. 

# 77 27 Sep 2012 18:44 120927 Standard 3 120927Arev 1. 78 27 Sep 2012 18:50 ICV 120927 120927Arev 1. 79 27 Sep 2012 19:04 ICB 120927 120927Arev 1. 80 27 Sep 2012 19:10 LLlCV 120927 120927Arev 1. 81 27 Sep 2012 19:17 FGD MATRIX 120927Arev 1. 82 27 Sep 2012 19:24 FGD MATRIX SPIKED 120927Arev 1. 83 27 Sep 2012 19:37 CCV 120927 120927Arev 1. 84 27 Sep 2012 19:50 CCB 120927 120927Arev 1. 85 27 Sep 2012 20:11 120920A-1638-BLK 120927Arev 1. 86 27 Sep 2012 20:17 120920A-1638-LCS 120927Arev 1. 89 27 Sep 2012 20:44 1638 MDL-0.25-1 120927Arev 1. 90 27 Sep 2012 20:50 1638 MDL-0.25-2 120927Arev 1. 91 27 Sep 2012 20:57 1638 MDL-0.25-3 120927Arev 1. 93 27 Sep 2012 21:11 CCV 120927 120927Arev 1. 94 27 Sep 2012 21:24 CCB 120927 120927Arev 1. 95 27 Sep2012 21:30 1638 MDL-0.25-4 120927Arev 1. 96 27 Sep 2012 21:37 1638 MDL-0.25-5 120927Arev 1. 97 27 Sep 2012 21:44 1638 MDL-0.25-6 120927Arev 1. 98 27 Sep 2012 21:51 1638 MDL-0.25-7 120927Arev 1. 99 27 Sep 2012 22:04 BLK MDL 0.4-1 120927Arev 1. 100 27 Sep 2012 22:11 BLK MDL 0.4-2 120927Arev 1. 101 27 Sep 2012 22:18 BLK MDL 0.4-3 120927Arev 1. 102 27 Sep 2012 22:24 BLK MDL 0.4-4 120927Arev 1. 103 27 Sep 2012 22:31 BLK MDL 0.4-5 120927Arev 1. 105 27 Sep 2012 22:44 CCV 120927 120927Arev 1. 106 27 Sep 2012 22:58 CCB 120927 120927Arev 1. 107 27 Sep 2012 23:04 BLK MDL 0.4-6 120927Arev 1. 108 27 Sep 2012 23:11 BLK MDL 0.4-7 120927Arev 1. 117 28 Sep 2012 00:18 CCV 120927 120927Arev 1. 118 28 Sep 2012 00:32 CCB 120927 120927Arev 1.

Page 1 01 Oct2012 16:56