Page 1 of 10 Revision date 09/05/2007 

# Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

ADCOTETM 76R36B

Revision date: 09/05/2007

Supplier ROHM AND HAAS CHEMICALS LLC A Subsidiary of The Dow Chemical Company

100 INDEPENDENCE MALL WEST

PHILADELPHIA

, PA 19106-2399 United States

For non-emergency information contact: 215-592-3000

For non-emergency information contact: 215-592-3000 Emergency telephone number

1 800 424 9300
Local emergency telephone number
989-636-4400



### 2. COMPOSITION/INFORMAT ION ON INGREDIENTS

Component CAS-No. Concentration

Polyester resin(s) Not Hazardous 38.0
- 40.0%

Methyl ethyl ketone 78-93-3 28.0
- 30.0%

Toluene 108-88-3 24.0
- 26.0%

Propylene glycol methyl ether acetate 108-65-6 2.0
- 4.0%



### 3. HAZARDS IDENTIFICATION

Emergency Overview 

### Appearance

Form liquid

Colour Light colored

Odour Solvent odorADCOTETM 76R36B

Page 2 of 10 Revision date 09/05/2007



### Hazard Summary CAUTION!
FLAMMABLE LIQUID AND VAPOR.

MAY CAUSE SENSITIZATION BY SKIN CONTACT. THE SOLVENT(S) IN THIS MATERIAL CAN BE ABSORBED

THROUGH INTACT SKIN. INHALATION MAY CAUSE DIZZINESS, HEADACHE AND

INCOORDINATION. CENTRAL NERVOUS SYSTEM (CNS) EFFECTS

COMA

DEATH

PROLONGED OR REPEATED OVEREXPOSURE TO THE SOLVENT(S) IN THIS MATERI AL CAN CAUSE THE FOLLOWING:

LIVER DAMAGE

KIDNEY DAMAGE

BLOOD DISORDERS

CAUSES SEVERE EYE IRRITATION.

MODERATE SKIN IRRITATION

ASPIRATION MAY CAUSE PULMONARY OEDEMA AND

PNEUMONITIS.

Potential Health Effects Primary Routes of Entry: Inhalation Eye contact

Skin contact Dermal Absorption

Eyes: The solvent(s) in this material can cause the following:

Severe irritation temporary corneal injury tearing

Pain

Skin: The solvent(s) in this material can be absorbed through intact skin. The solvent(s) in this material can cause the following: slight to moderate irritation

skin sensitization Prolonged or repeated skin contact can cause the following: defatting and drying of the skin which can lead to irritation and dermatitis Ingestion: Material is possibly harmful if swallowed. Material can cause the following:

headache

nausea diarrhea

dizziness

Lack of coordination Vomiting

drowsiness

coma Aspiration may cause pulmonary oedema and pneumonitis.

death

Inhalation: Inhalation of solvent vapor or mist can cause the following: irritation of nose, throat, and lungs

headache Vomiting

drowsinessADCOTETM 76R36B

Page 3 of 10 Revision date 09/05/2007 nausea dizziness

Lack of coordination central nervous system (CNS) effects

unconsciousness Inhalation of high solvent vapor or mist concentrations can cause the following: damage to the upper respiratory tract

coma death

Chronic Exposure: Methyl ethyl ketone (MEK) can cause ce ntral nervous system (CNS) effects. Prolonged or repeated overexposure to propylene glycol monomethyl ether acetate can cause the following: - liver damage - kidney damage - blood disorders Prolonged or repeated overexposure to toluene can c ause the following: - irritation of the respiratory tract - enlarged liver - kidney effects - cardiac sensitization Methyl ethyl ketone IRIS Not classifiable.

Toluene ACGIH Not classifiable as a human carcinogen.

Toluene US CA65CRT Developmental toxin.

Toluene IARC Classification not possible

from current data.

Toluene IRIS Not classified.



### 4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Immediate medical attention is required.

Skin contact: Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. Eye contact: Immediately flush eye(s) with plenty of water. Immediate medical attention is required. Ingestion: Never give anything by mouth to an unconscious person. If a person vomits when lying on his back, place him in the recovery position. Drink 1 or 2 glasses of water. Call a physician immediately. Notes to physician Massive ingestion of methyl ethyl ketone may cause gastric irritation with absorption leading to metabolic acidosis with an anion gap. CNS narcosi s and cardiac arrhythmias effects may be similar to other organic solvents. Acute massive exposure to toluene can cause transient hematuria and albuminuria. Cardiac arrhythmias can occur after massive inhalation.



### 5. FIRE-FIGHTING MEASURES

Flash point -4 °C ( 24.80 °F ) estimated

Ignition temperature 480.0 °C ( 896.00 °F ) Toluene

Lower explosion limit 1.40 %(V)Methyl ethyl ketone

Upper explosion limit 11.40 %(V)Methyl ethyl ketone
Thermal decomposition Heating or fire conditions liberates toxic gas., Carbon oxides

Suitable extinguishing

media: Foam Carbon dioxide (CO2) Dry powder Water sprayADCOTETM 76R36B

Page 4 of 10 Revision date 09/05/2007 Specific hazards during fire fighting: Vapors can travel to a source of ignition and flash back. Heated material can form flammable or explosive vapors with air. Closed containers may rupture via pressure build-up when exposed to fire or extreme heat. Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suit.

Further information: For safety reasons in case of fire, co ntainers should be stored separately in

closed containments. Cool closed containers exposed to fire with water spray.



### 6. ACCIDENTAL RELEASE MEASURES

Environmental precautions Do not flush into surface water or sanitary sewer system. 

### Methods for cleaning up Evacuate personnel to safe areas. Remove all sources of ignition. Ensure adequate ventilation. Contain spillage, and then collect with non-comb ustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in cont ainer for disposal according to local / national regulations (see section 13). No sparking tools should be used.



### 7. HANDLING AND STORAGE

Handling Provide sufficient air exchange and/or exhaust in work rooms. In case of insufficient ventilation, wear suitable respiratory equipment. Do not breathe vapours or spray mist. Wear personal protective equipment. For personal protection see section 8. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product residue follow all MSDS and label warnings even after container is emptied. 

### Storage Storage conditions: Material can burn; limit indoor storage to approved areas equipped with automatic sprinklers. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Electrical installations / working materials must comply with the technological safety standards.



### 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limit(s) Exposure limits are listed below, if they exist.

Component Regulation Type of listing Value Methyl ethyl ketone Rohm and Haas TWA 50 ppm

Rohm and Haas STEL 100 ppm

ACGIH TWA 200 ppm

ACGIH STEL 300 ppm

NIOSH/GUIDE REL 590 mg/m3 200 ppm

NIOSH/GUIDE STEL 885 mg/m3 300 ppm OSHA_TRANS PEL 590 mg/m3 200 ppm

Z1A TWA 590 mg/m3 200 ppm

Z1A STEL 885 mg/m3 300 ppm

Component Regulation Type of listing Value
Toluene Rohm and Haas TWA 10 ppm

Rohm and Haas STEL 20 ppm

Rohm and Haas Absorbed via skinADCOTETM 76R36B

Page 5 of 10 Revision date 09/05/2007 ACGIH TWA 20 ppm

NIOSH/GUIDE REL 375 mg/m3 100 ppm

NIOSH/GUIDE STEL 560 mg/m3 150 ppm

OSHA/Z2 TWA 200 ppm OSHA/Z2 Ceiling 300 ppm

OSHA/Z2 MAX. CONC 500 ppm

Z1A TWA 375 mg/m3 100 ppm

Z1A STEL 560 mg/m3 150 ppm

Component Regulation Type of listing Value Propylene glycol methyl

ether acetate Rohm and Haas TWA 30 ppm

Rohm and Haas STEL 90 ppm

Rohm and Haas Absorbed via skin

WEEL TWA 50 ppm

Eye protection: Tightly fitting safety goggles Eye protection worn must be compatible with respiratory protection system employed. Hand protection: Chemical-resistant gloves should be worn whenever this material is handled. The glove(s) listed below may provide protection against permeation. (Gloves of other chemically resistant materials may not provide adequate protection): SilverShield Gloves butyl-rubber 4H Glove (Trademark of Safety 4 A/S of Denmark) Gloves should be removed and replaced immediately if there is any indication of degradation or chemical breakthrough. Before removing gloves clean them with soap and water. Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2 requirements or equivalent must be followed whenev er workplace conditions warrant a respirator’s

use. None required if airborne concentrations are ma intained below the exposure limit listed in Exposure Limit Information. Where vapors and/or mists may oc cur, wear a properly fitted NIOSH approved (or equivalent) half-ma sk, air-purifying respirator. Air-purifying respirators should be equipped with NIOSH approved (or equivalent) organic vapor cartridges and N95 filters. If oil mist is present, use R95 or P95 filters. Hygiene measures: Wash hands before breaks and immediately after handling the product. 

### Engineering measures: Use only in area provided with appropriate exhaust ventilation. Use explosion-proof local exhaust ventilation with a minimum captur e velocity of 100 ft/min (0.5 m/sec) at the point of vapor evolution. Refer to the current edition of Industrial Ventilation: A Manual of Recommended Practice published by the American C onference of Governmental Industrial Hygienists for information on the design, installation , use, and maintenance of exhaust systems.



### 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form liquid

Colour Light colored

Odour Solvent odor

pH Not Applicable

Boiling point/range 80 °C ( 176.00 °F ) Methyl ethyl ketone

Flash point -4 °C ( 24.80 °F ) estimated

Ignition temperature 480 °C ( 896.00 °F ) Toluene

Lower explosion limit 1.40 %(V)Methyl ethyl ketone

Upper explosion limit 11.40 %(V)Methyl ethyl ketone

Vapour pressure 100.0 mmHg Methyl ethyl ketone

Relative vapour density 3.1TolueneADCOTETM 76R36B

Page 6 of 10 Revision date 09/05/2007 Water solubility negligible

Relative density 0.96

Viscosity, dynamic 1,700.000 mPa.s

Evaporation rate 5.70 Methyl ethyl ketone

Percent volatility 58 - 60 %

VOC’s 575 g/l

NOTE: The physical data presented above are ty pical values and should not be construed as a specification.



### 10. STABILITY AND REACTIVITY

Hazardous reactions No dangerous reaction known under conditions of normal use. Stable under recommended storage conditions.

Conditions to avoid Heat, flames and sparks.

Materials to avoid Strong oxidizing agents

Hazardous decomposition products Formaldehyde

Phenol



### 11. TOXICOLOGICAL INFORMATION

No toxicity data are available for this material. Component: Methyl ethyl ketone Acute oral toxicity LD50 rat 2,737 mg/kg

Component: Toluene Acute oral toxicity LD50 rat > 2,000 mg/kg

Component: Propylene glycol methyl ether acetate Acute oral toxicity LD50 rat 8,532 mg/kg

Component: Methyl ethyl ketone

Acute inhalation toxicity LC50 rat 8 h 23,500 mg/l

Component: Toluene

Acute inhalation toxicity LC50 rat 4 h 15.07 mg/l

Component: Propylene glycol methyl ether acetate

Acute inhalation toxicity LC50 rat 6 h 23.49 mg/l

Component: Methyl ethyl ketone Acute dermal toxicity LD50 rabbit male > 5,000 mg/kg

Component: Toluene Acute dermal toxicity LD50 rabbit > 3,000 mg/kg

Component: TolueneADCOTETM 76R36B

Page 7 of 10 Revision date 09/05/2007

Acute dermal toxicity LD50 rabbit 14,000 mg/kg

Component: Propylene glycol methyl ether acetate Acute dermal toxicity LD50 rabbit >5,000 mg/kg

Component: Toluene Subchronic toxicity IARC assessment: this product is not classifiable as to its carcinogenicity to humans (Group 3).

Component: Toluene Toxicity to reproduction In laboratory studies, birth defects, increased fe tal lethality and delayed fetal development have been observed in offspring of female animals exposed during pregnancy. Component: Toluene Teratogenicity Toluene has been demonstrated to be embryofetotoxic and teratogenic in laboratory animals. Component: Propylene glycol methyl ether acetate Toxicity to reproduction Dermal teratology testing of this solvent (with less than 3% beta isomer) revealed no maternally toxic, teratogenic or fetotoxic responses in rats or rabbits exposed to concentrations of 1,000 and 2,000 mg/kg per day. Component: Propylene glycol methyl ether acetate Mutagenicity No significant mutagenic response was observed and the carcinogenic potential of the material is

therefore considered to be low.



### 12. ECOLOGICAL INFORMATION

There is no data available for this product. Methyl ethyl ketone Ecotoxicity effects Toxicity to fish LC50 Bluegill sunfish (Lepomis macrochirus) 96 h 3,220 mg/l

Toxicity to aquatic

invertebrates LC50 Daphnia magna 48 h 5,091 mg/l

Toluene Ecotoxicity effects Toxicity to fish LC50 Oncorhynchus mykiss (rainbow trout) 96 h 24 ppm

Toxicity to fish LC50 Fathead minnow (Pimephales promelas) 96 h 26 ppm

Toxicity to fish LC50 Bluegill sunfish 96 h 13 ppm

Toxicity to algae EC50 Algae 96 h >433 ppm

Toxicity to aquatic

invertebrates EC50 Daphnia magna 48 h 11.5 ppm

Propylene glycol methyl ether acetateADCOTETM 76R36B

Page 8 of 10 Revision date 09/05/2007 Ecotoxicity effects Toxicity to fish LC50 Fathead minnow (Pimephales promelas) 96 h 161 mg/l

Toxicity to aquatic

invertebrates EC50 Daphnia magna 48 h >500 mg/l



### 13. DISPOSAL CONSIDERATIONS

Environmental precautions: Do not flush into surface water or sanitary sewer system. 

### Disposal

Waste Classification: 40 CFR 261.30 - .38 - Listed Waste D035 D001, 100 lbs.

When a decision is made to discard this material as supplied, it is classi fied as a RCRA hazardous waste with the characteristic of ignitability and toxicity. For disposal, incinerate this material at a facility t hat complies with local, st ate, and federal regulations. (See 40 CFR 268)



### 14. TRANSPORT INFORMATION



## DOT

Proper shipping name Resin solution

UN-No. UN 1866

Class 3 Packing group II Reportable Quantity Methyl ethyl ketone

, Toluene



## IMO/IMDG

Proper shipping name RESIN SOLUTION

UN-No. UN 1866

Class 3 Packing group II

Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations



### 15. REGULATORY INFORMATION

Workplace Classification This product is considered hazardous under t he OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is a ‘controlled product’ under the Canadian Workplace Hazardous Materials Information System (WHMIS).


### SARA TITLE III: Section 311/312 Categorizations (40CFR370): Acute Health Hazard

Fire Hazard

Chronic Health Hazard



### SARA TITLE III: Section 313 Information (40CFR372) This product contains a chemical which is list edin Section 313 at or above de minimis concentrations. The following listed chemicals are present: (Quantity present is found elsewhere on this MSDS.)

SARA Title III Components: Toluene 108-88-3



### CERCLA Information (40CFR302.4)ADCOTETM 76R36B

Page 9 of 10 Revision date 09/05/2007 This material is regulated under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA)and the Superfund Amendm ents and Reauthorization Act (SARA) Title III

Section 304. This material is or contains chem ical(s) listed in 40 CFR Table 302.4 or nondesignated RCRA ICR substance(s). (N ondesignated ICR subs tances apply to materials that will not be reused.) The Reportable Quantity(s) (RQ) are listed below. Releases in exce ss of its reportable quantity must be reported to the National Response Center (1- 800-424-8802) and to the appropriate state and local emergency response organizations. See Section 13, Disposal Considerations, Subs ection Disposal, for CERCLA classification.

CERCLA Components: Methyl ethyl ketone 78-93-3 5,000 lbs RQ

Toluene 108-88-3 1,000 lbs RQ



### US. Toxic Substances Control Act ( TSCA ) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Contro l Act (TSCA) Chemical Substance Inventory. 

### Pennsylvania Any material listed as “Not Hazardous” in the CAS REG NO. column of SECTION 2, Composition/Information On Ingredients, of this MSDS is a trade secret unde r the provisions of the Pennsylvania Worker and Community Right-to-Know Act. 

### California (Proposition 65) This product contains a component or components known to the state of Ca lifornia to cause birth defects or other reproductive harm: Components: Toluene 108-88-3



### 16. OTHER INFORMATION

Hazard Rating



### Health Fire Reactivity

HMIS 3* 3 0

HMIS: * = Chronic Effects (See Hazards Identification)



### Legend

ACGIH American Conference of Governmental Industrial Hygienists

BAc Butyl acetate

OSHA Occupational Safety and Health Administration

PEL Permissible Exposure Limit

STEL Short Term Exposure Limit (STEL):

TLV Threshold Limit Value

TWA Time Weighted Average (TWA):

| Bar denotes a revision from prior MSDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The informat ion given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information re lates only to the specific material designated and may not be valid for such material used in combinat ion with any other materials or in any process, unless specified in the text.

Version: 1.3

Print Date: 09/21/2012

Layout 000101108802ADCOTETM 76R36B

Page 10 of 10 Revision date 09/05/2007