# Patent

## Title
Leader tape and magnetic tape cartridge using the same

## Abstract

A leader tape where an non-magnetic under layer that contains a powder and a binder and a magnetic upper layer are sequentially laminated on at least one face of a support, in which F5 values of the support in a machine direction (MD) and in a transverse direction (TD) are from 80 to 120 MPa respectively, the F5 value in MD is larger than that in TD, and a difference between the F5 value in MD and that in TD is 15 MPa or less.

## Background
This application is based on Japanese Patent application JP 2004-091718, filed Mar. 26, 2004, the entire content of which is hereby incorporated by reference. This claim for priority benefit is being filed concurrently with the filing of this application.
BACKGROUND OF THE INVENTION
1. Technical Field of the Invention
The present invention relates to a leader tape, to a magnetic tape cartridge in which the cartridge case rotatably houses a reel with a magnetic tape wound up therearound along with the leader tape bonded thereto.
2. Description of the Related Art
As magnetic tape cartridges used as recording media for external memory devices for computers and others, heretofore known are those of a type where a magnetic tape is wound up around one or more reels rotatably housed in the cartridge case. Since the magnetic tapes are used for data storage for computers and others and since important information is recorded therein, the cartridges are specifically so designed that they are free from a trouble of tape jamming and that a magnetic tape is not carelessly led out of them.
In a single reel-type cartridge, a leader member such as a leader pin or a leader block is fitted to the top end of the magnetic tape, via which the magnetic tape is led out of the cartridge; or a leader tape is bonded thereto, which is formed of a relatively hard plastic material and which has engage holes formed at the top end of the tape. For the cartridge of the type, a drive device is so constructed that the magnetic tape therein could be loaded/unloaded (draw out/wind up) while the leader member or the leader tape top end is held by the holder member on the side of a recording and reproduction device.
In the loading/unloading process as above where the magnetic tape is drawn out toward the side of the magnetic recording and reproduction device and its top end is wound up around the drive reel in the device, the top end of the magnetic tape is contacted with the tape guide and the magnetic head disposed along the tape-running route, while not accurately positioned relative to them, and in that condition, it is pulled and is therefore readily damaged. Accordingly, it is desirable that the top end of the magnetic tape is reinforced.
In addition, the reinforcement is also desirable in order to prevent the leader block level difference occurring in the drive reel from being transferred on to a data-recording magnetic tape to increase the dropouts in the tape. For this, a leader tape having a higher strength than that of a magnetic tape is bonded to the top end of the magnetic tape (e.g., see JP-A-2001-110164).
As a leader tape there is normally used a magnetic tape having a single magnetic layer.
Therefore, when the magnetic tape cartridge loaded in LTO drive is subjected to load/unload cycles, the surface of the leader tape which rubs against LTO drive running system is scratched to give scrapings that are then attached to the running system. The scrapings that have been attached to the running system are then transferred to the surface of the magnetic tape, causing a rise of dropout. It is also disadvantageous in that deformation of the leader tape is transferred to the magnetic tape, raising the error rate.
With the recent tendency for enhancement of capacity of magnetic tape cartridge, the recording density of the magnetic tape cartridge has been raised. Thus, the problem of spacing loss due to transfer of tape deformation of leader tape to data recording magnetic tape has become more remarkable. It has thus been desired to improve the related art leader tape and data tape.
The leader block mentioned above is so designed that it may be housed in the recess formed in the core of a take-up reel, and when housed therein, a part of the leader block forms a part of the arc face of the core.
This is graphically illustrated. As in FIG. 4A, a leader block 40 is fitted into the recess 42 formed along the radial direction of the core 41, and, for example, in this condition, the end face 40a of the leader block 40 forms a part of the take-up face of the core 41. As illustrated, the end face 40a of the leader block 40 is curved like an arc in correspondence to the outer peripheral face of the core 41, in order to smoothly wind up the magnetic tape MT around it.
However, in such a conventional tape drive, the end face 40a may protrude above the core 41, as in FIG. 4B, depending on the dimensional accuracy of the leader block 40 that constitutes a part of the take-up face, and it may form an unacceptable level difference in the take-up face of the core 41.
The level difference may cause folding or deformation of the leader tape LT, and, as in FIG. 4C, the folding and the deformation occur similarly also in the part of the magnetic tape MT which is wound up as the subsequent layers and which is to be a substantial recording region (this may be referred to as “tape deformation transfer”). The tape deformation transfer may cause a problem in that a suitable distance between the tape and the recording/reproducing head could not be ensured in the process of information recording/reproduction, and it may therefore cause recording failure and information loss.
If the time for which the tape is kept wound up around a take-up reel is short, then the tape deformation transfer would not cause the problems as above, but when the magnetic tape MT is kept wound up around the take-up reel and left as such for long, then the magnetic tape MT may often have a regular tape deformation transfer on the surface thereof, at a pitch of nearly the circumference length of the core 41.
SUMMARY OF THE INVENTION
An object of the invention is to provide a leader tape which can suppress the increase in dropouts to be caused by transference of a drive reel or a leader block onto it during long-term storage or high-temperature running; and to provide a magnetic tape cartridge using the leader tape.
The object of the invention can be attained by the following means:
1) A leader tape where an non-magnetic under layer that contains a powder and a binder and a magnetic upper layer are sequentially laminated on at least one face of a support, in which F5 values of the support in a machine direction (MD) and in a transverse direction (TD) are from 80 to 120 MPa respectively, the F5 value in MD is larger than that in TD, and a difference between the F5 value in MD and that in TD is 15 MPa or less.
2) The leader tape of above 1), wherein a thickness of the upper layer is 0.1 to 2.0 μm.
3) The leader tape of above 1) or 2), wherein the leader tape has a back layer on the opposite face of the support, and surface electrical resistances of the upper layer and the back layer are at most 1010 Ω/sq respectively.
4) A magnetic tape cartridge where a magnetic tape is wound up around one or more reels rotatably housed in the cartridge case, in which a leader tape that is bonded to the top end of the magnetic tape and is let out toward a magnetic recording and reproduction device while leading the magnetic tape is the leader tape of any of 1) to 3).
In accordance with the leader tape according to the invention, F5 values of the support in the machine direction (MD) and the transverse direction (TD) and the difference in F5 values between in MD and in TD are defined. In this arrangement, the rise of dropout due to tape deformation transfer of drive reel or leader block during prolonged storage or running at high temperature can be suppressed, though the reason being unknown.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a constitutional view conceptually showing a magnetic recording and reproduction device used for the invention.
FIG. 2 is a perspective exploded view showing the magnetic tape cartridge used in the magnetic recording and reproduction device.
FIG. 3A is a perspective view of the drive reel used in the magnetic recording and reproduction device; FIG. 3B is a partly-enlarged cross-sectional view of FIG. 3A cut along the IIIB-IIIB line.
FIG. 4A to 4C are explanatory views of a related art.



DETAILED DESCRIPTION OF THE INVENTION
The leader tape according to the invention is preferably used in a magnetic recording/reproducing device having a linear recording density of not smaller than 100 kfci and a difference of from 0 to 16 μm between recording track width and reproducing track width. In other words, since a system having a difference of more than 16 μm between recording track width and reproducing track width has a sufficiently great recording track width as compared with reproducing track width, no rise of dropout occurs even tape deformation causes the occurrence of tape deviation of several micrometers because the head runs over the recording track. However, a magnetic recording/reproducing device having a difference of not greater than 16 μm between recording track width and reproducing track width and a great linear recording density is subject to remarkable track dislocation due to tape deformation and thus is more subject to tape deformation transfer. Accordingly, the advantage of the leader tape according to the invention becomes remarkable when a magnetic recording/reproducing device having a great linear magnetic density is used.
In addition, not specifically defined, the magnetic recording and reproduction device may be any one that comprises a magnetic tape cartridge and a magnetic tape drive.
Not also specifically defined, the magnetic tape cartridge may be any one in which a magnetic tape with the leader tape of the invention bonded thereto is wound up around one or more reels rotatably housed in the cartridge case. The invention produces better results when applied to single reel devices.
The leader tape of the invention may be bonded to the top end of a magnetic tape on and from which signals are recorded and reproduced, by attaching a known splicing tape thereto in such a manner that one end of the leader tape is butt-jointed with the top end of the magnetic tape. The other end of the leader tape is provided with an engaging member such as leader pin, and this is used for fixing the leader tape to the drive reel of a magnetic recording and reproduction device.
In the magnetic recording and reproduction of the invention, the magnetic tape cartridge provided with the leader tape of the invention may be used in a magnetic recording and reproduction device, and it enables recording and reproduction under the condition where the line recording density of the magnetic tape to which the leader tape is bonded is at least 100 kfci (preferably at least 200 kfci, more preferably at least 300 kfci) and the difference between the recording track width (preferably at most 20 μm, more preferably at most 15 μm) and the reproduction track width (preferably at most 10 μm, more preferably at most 7 μm) is from 0 to 16 μm (preferably from 0 to 10 μm, more preferably from 2 to 8 μm).
The magnetic recording and reproduction using the leader tape and the magnetic tape cartridge of the invention prevents track shifting and enables stable recording and reproduction even when the recording track width is narrow and the difference between the recording track width and the reproduction track width is small like this.
The recording and reproduction device in which recording and reproduction is attained at the above-mentioned track width is not specifically defined, for which are usable any known magnetic recording and reproduction devices equipped with recording/reproduction heads.
The magnetic head for use in the invention is preferably an inductive head for recording, and an MR head for reproduction.
The invention is described in more detail hereinunder.
[Leader Tape]
The magnetic upper layer and the non-magnetic lower layer to be provided on the support are mainly composed of a dispersion of an inorganic particulate material in a binder. The upper layer and the lower layer are formed on the surface of the support which is to come in contact with the magnetic head. The average particle size of the inorganic powder to be used in the upper layer and the lower layer is from 0.02 to 1 μm, preferably from 0.05 to 0.6 μm. The form of the particles may be grain, needle, tablet, cube or the like.
The purpose of providing the upper layer and the lower layer is to provide functions which are not possessed by the support, e.g., to incorporate abrasive particles in the surface of the support which is to come in contact with the magnetic head and hence render the support capable of cleaning, to incorporate electrically-conductive particles in the support and hence provide the support with antistat effect, to incorporate a magnetic material in the support and hence allow recording of magnetic signal.
Preferably, a two-layer structure obtained by spreading the same non-magnetic layer (lower layer) and magnetic layer (upper layer) as used in the data tape is provided on the surface of the support which is to come in contact with the magnetic head while a back coat (back layer) mainly composed of carbon black is provided on the other surface of the support.
The leader tape according to the invention is arranged to have F5 values of the support in the machine direction (MD) and the transverse direction (TD) from 80 to 120 MPa, preferably from 85 to 115 MPa, more preferably from 90 to 105 MPa in the machine direction (MD) and the transverse direction of the support (TD), wherein F5 value in MD direction is greater than F5 value in TD direction and the difference in F5 value between in MD direction and TD direction is 15 MPa or less, preferably 10 MPa or less.
F5 value can be easily controlled by, e.g., properly predetermining the stretching conditions of the support material. The predetermination of F5 to 15 MPa or less can be easily carried out by, e.g., individually predetermining the factor of stretching in MD direction and TD direction during the stretching of the support material. Referring further to F5 value, F5 value can be defined to a desired range by predetermining the factor of stretching in MD direction and TD direction to a range of from 3 to 5 and from 3 to 5, respectively, when as the support material there is used a polyethylene terephthalate (PET) or by predetermining the factor of stretching in MD direction and TD direction to a range of from 2 to 4 and from 2 to 4, respectively, when as the support material there is used a polyethylene naphthalate (PEN).
The central line average roughness (Ra) of the leader tape according to the invention is preferably from 30 to 50 nm.
The term “Ra” as used herein is meant to indicate a value measured by a Type HD-2000 optical interference surface roughness meter (produced by WYKO) under the following conditions.
Objective lens: 50×; intermediate lens: 0.5×; measurement range: cylindrical correction by 242 μm×184 μm; Ra is calculated after inclination correction.
In this arrangement, a cushioning effect can be exerted when the leader tape is wound on a reel, making it possible to further prevent the tape deformation transfer.
The thickness of the upper layer is preferably from 0.1 to 2.0 μm. By predetermining the thickness of the upper layer to the above defined range, an effect can be exerted to make it difficult for the shape of drive reel or leader block to be transferred to the magnetic layer.
The central line average surface roughness (Ra) of the upper layer is preferably from 15 to 40 nm.
The sum of the thickness of the upper layer and the lower layer is preferably from 1.0 to 3.0 μm, more preferably from 1.5 to 2.5 μm. The thickness of the support is preferably from 3 to 17 μm, more preferably from 6 to 15 μm.
Preferably, the overall thickness of the leader tape is from 5 to 20 μm, more preferably from 8 to 18 μm.
Preferably, the surface electrical resistance of the leader tape and that of the back layer provided as need arises are at most 1010 Ω/sq, more preferably at most 109 Ω/sq. Thus controlled, the leader tape is prevented from being statistically charged and is prevented from being damaged by static charges of magnetic heads, whereby its reliability is increased. In addition, the strength of the leader tape is basically higher than that of the magnetic tape which is bonded to the leader tape, and when the magnetic tape cartridge having therein the two tapes bonded to each other is driven in a magnetic recording and reproduction device in which the tapes are repeatedly loaded/unloaded, then the durability of the leader tape is kept high.
For controlling the surface electrical resistance of the leader tape to fall within the predetermined range, for example, a conductive powder such as carbon black may be added to at least one layer of the lower layer, the upper layer and the back layer of the tape. For example, from 1 to 20 parts by weight of carbon black may be added to 100 parts by weight of the binder in each layer.
Preferably, the leader tape is a magnetic tape that comprises a non-magnetic layer containing an inorganic powder and a binder as the lower layer and a magnetic layer containing a ferromagnetic powder and a binder as the upper layer, and has a back layer formed on the opposite side thereto.
The leader tape that is the magnetic tape as above is described in detail hereinunder.
(Magnetic Layer)
<Binder in Magnetic Layer and Non-Magnetic Layer>
The binder to be used in the magnetic layer and the non-magnetic layer may be any of known thermoplastic resins, thermosetting resins, reactive resins and their mixtures. The thermoplastic resin may have a glass transition point falling between −100 and 150° C., a number-average molecular weight falling between 1000 and 200000, preferably between 10000 and 100000, and a degree of polymerization falling between about 50 and 1000 or so.
Examples of the resin of the type are polymers or copolymers comprising constitutive units of vinyl chloride, vinyl acetate, vinyl alcohol, maleic acid, acrylic acid, acrylate, vinylidene chloride, acrylonitrile, methacrylic acid, methacrylate, styrene, butadiene, ethylene, vinyl butyral, vinyl acetal, vinyl ether and the like; and polyurethane resins, and various rubber-type resins. The thermosetting resin and the reactive resin include, for example, phenolic resins, epoxy resins, polyurethane-curable resins, urea resins, melamine resins, alkyd resins, acrylic reactive resins, formaldehyde resins, silicone resins, epoxy-polyamide resins, mixtures of polyester resins and isocyanate prepolymers, mixtures of polyester-polyols and polyisocyanates, and mixtures of polyurethanes and polyisocyanates. These resins are described in detail in Plastic Handbook (published by Asakura Shoten). In addition, any known electron ray-curable resin may be used in each layer. Its examples and its production methods are described in JP-A 62-256219.
The above-mentioned resins may be used herein either singly or as combined. Preferably, at least one selected from polyvinyl chloride resins, vinyl chloride-vinyl acetate copolymers, vinyl chloride-vinyl acetate-vinyl alcohol copolymers and vinyl chloride-vinyl acetate-maleic anhydride copolymers is combined with a polyurethane resin and a polyisocyanate for use in the invention.
The polyurethane resin may have any known structure of polyester-polyurethane, polyether-polyurethane, polyether-polyester-polyurethane, polycarbonate-polyurethane, polyester-polycarbonate-polyurethane, and polycaprolactone-polyurethane. Optionally but preferably, all these binders have at least one polar group selected from COOM, SO3M, OSO3M, P═O(OM)2, O—P═O (OM)2 (in these, M represents a hydrogen atom or an alkali metal base), OH, N(R)2, N+(R)3 (where R represents a hydrocarbon group), epoxy group, SN and CN, introduced thereinto through copolymerization or addition reaction, in order that the binders may realize further better dispersibility and durability. The amount of the polar group in the binders may be from 10−1 to 10−8 mol/g, preferably from 10−2 to 10−6 mol/g.
Preferably, the number of the hydroxyl groups to be in the polyurethane resin is from 3 to 20 in one molecule, more preferably from 4 or 5 in one molecule. If the number is smaller than 3 in one molecule, then the reactivity of the resin with a polyisocyanate curing agent may lower and therefore the film strength and the durability may lower. If, however, the number is larger than 20, then the solubility and the dispersibility in solvent of the resin may lower. For controlling the content of the hydroxyl groups in the polyurethane resin, a compound having at least three functional hydroxyl groups may be used in producing the polyurethane resin. Concretely, there are mentioned trimethylolethane, trimethylolpropane, trimellitic anhydride, glycerin, pentaerythritol, hexanetriol; as well as branched polyesters and polyether-esters having 3 or more functional hydroxyl groups that are obtained from a dibasic starting from a polyester-polyol described in JP-B 6-64726 and the compound serving as a glycol component. Preferred for use herein are tri-functional compounds. Tetra- or more multi-functional compounds may readily gel in the reaction step.
The polyisocyanates usable herein are, for example, isocyanates such as tolylene diisocyanate, 4,4′-diphenylmethane diisocyanate (MDI), hexamethylene diisocyanate, xylylene diisocyanate, naphthylene-1,5-diisocyanate, o-toluidine diisocyanate, isophorone diisocyanate, triphenylmethane triisocyanate; products of these isocyanates with polyalcohols; and polyisocyanates produced through condensation of these isocyanates.
The amount of the binder to be in the magnetic layer and the non-magnetic layer may be generally from 5 to 50% by weight, preferably from 10 to 30% by weight of the ferromagnetic powder in the magnetic layer or of the non-magnetic inorganic powder in the non-magnetic layer. When a vinyl chloride-based rein is used, its amount may be from 5 to 30% by weight and when a polyurethane resin is used, its amount may be from 2 to 20% by weight; and the amount of the polyisocyanate to be combined with these is preferably from 2 to 20% by weight. For example, however, when head corrosion may occur owing to minor dechlorination, a combination of only polyurethane and isocyanate may be used.
In the magnetic tape of the type, the amount of the binder, the proportion of the vinyl chloride-based resin in the binder, the amount of the polyurethane resin, the polyisocyanate resin and other resins, the molecular weight and the polar group content of the resins constituting the magnetic layer, as well as various physical properties of the resins mentioned above may be optionally varied between the non-magnetic layer and the magnetic layer, and they are rather optimized in the respective layers. For this, employable are any known techniques relating to multi-layered magnetic layers. For example, when the binder amount is varied in each layer, it is effective to increase the binder amount in the magnetic layer so as to reduce the surface abrasion of the magnetic layer. In order to improve the head touch of the tape to heads, the binder amount in the non-magnetic layer may be increased so as to soften the tape.
<Ferromagnetic Powder>
The ferromagnetic powder to be used in the magnetic layer is preferably a ferromagnetic alloy powder comprising a principal component of α-Fe. The ferromagnetic powder may contain any other atoms such as Al, Si, S, Sc, Ca, Ti, V, Cr, Cu, Y, Mo, Rh, Pd, Ag, Sn, Sb, Te, Ba, Ta, W, Re, Au, Hg, Pb, Bi, La, Ce, Pr, Nd, P, Co, Mn, Zn, Ni, Sr and B, in addition to the predetermined atom. In particular, the powder preferably contains at least one of Al, Si, Ca, Y, Ba, La, Nd, Co, Ni and B, in addition to α-Fe, more preferably at least one of Co, Y and Al.
The ferromagnetic alloy powder may contain a small amount of a hydroxide or an oxide. The ferromagnetic alloy powder for use herein may be any one produced according to any known method. For producing it, for example, the following methods may be mentioned: A method of reducing a composite organic acid salt (principally oxalate) with a reducing vapor such as hydrogen; a method of reducing iron oxide with a reducing vapor such as hydrogen to obtain Fe or Fe—Co particles; a method of pyrolyzing a metal carbonyl compound; a method of adding a reducing agent such as sodium borohydride, hypophosphite or hydrazine to an aqueous solution of a ferromagnetic metal so as to reduce the metal; a method of vaporizing a metal in a low-pressure inert gas to obtain a fine powder of the metal. Thus obtained, the ferromagnetic alloy powder may be subjected to known slow oxidation, for example, according to a method of dipping it in an organic solvent and then drying it; or a method of dipping it in an organic solvent, then introducing oxygen-containing gas into it so as to form an oxide film on the surface of the particles and thereafter drying the particles; or a method of forming an oxide film on the surface of the particles by controlling the partial pressure of the oxygen gas and the inert gas applied thereto, not using an organic solvent. The ferromagnetic alloy powder thus processed in any of these methods may be used herein.
A hexagonal-system ferrite powder may also be used for the ferromagnetic powder to be in the magnetic layer. The hexagonal-system ferrite includes, for example, barium ferrite, strontium ferrite, lead ferrite, calcium ferrite, and their substituted derivatives such as Co-substituted derivatives. Concretely, there are mentioned magnetoplumbite-type barium ferrite and strontium ferrite, spinel-coated magnetoplumbite-type ferrite, partially spinel phase-containing magnetoplumbite-type barium ferrite and strontium ferrite. They may contain any other atoms such as Al, Si, S, Sc, Ti, V, Cr, Cu, Y, Mo, Rh, Pd, Ag, Sn, Sb, Te, Ba, Ta, W, Re, Au, Hg, Pb, Bi, La, Ce, Pr, Nd, P, Co, Mn, Zn, Ni, Sr, B, Ge and Nb, in addition to the predetermined atoms. In general, substances with elements such as Co—Ti, Co—Ti—Zr, Co—Ti—Zn, Ni—Ti—Zn, Nb—Zn—Co, Sb—Zn—Co or Nb—Zn added thereto may be used.
(Non-Magnetic Layer)
The inorganic powder to be sued in the non-magnetic layer is a non-magnetic powder and may be selected, for example, from inorganic compounds such as metal oxides, metal carbonates, metal sulfates, metal nitrides, metal carbides, metal sulfides. Carbon black may be added to the non-magnetic layer so as to attain known effects of reducing the surface electrical resistance Rs, reducing the light transmittance and obtaining a desired micro-Vickers hardness. When carbon black is added to the lower layer, then the layer may be effective for storing lubricant. Regarding its type, carbon black usable herein may be any of furnace black for rubber, thermal black for rubber, black for color, and acetylene black. Depending on the desired effect thereof, carbon black to be in the lower layer must optimize the characteristics mentioned below. When combined in the layer, carbon black may exhibit its effect. In addition, the non-magnetic layer may contain an organic powder depending on its object. Known techniques relating to the magnetic layer may apply to the lubricant, the dispersant, the additive, the solvent and the dispersion method in the non-magnetic layer.
[Additive]
The additives that may be in the magnetic layer and the non-magnetic layer may be those having a head-cleaning effect, a lubricating effect, an antistatic effect, a dispersing effect and a plasticizing effect. Concretely, those described in WO98/35345 may be used herein.
For the lubricant, for example, herein usable are monobasic fatty acids having from 10 to 24 carbon atoms, and their metal salts (e.g., with Li, Na, K, Cu); monofatty acid esters, difatty acid esters or trifatty acid esters of monobasic fatty acids having from 10 to 24 carbon atoms and at least any one of mono, di, tri, tetra, penta or hexa-alcohols having from 2 to 12 carbon atoms; fatty acid esters of monoalkyl ethers of alkylene oxide polymers; and fatty acid amides having from 8 to 22 carbon atoms. The fatty acids and alcohols may contain unsaturated bond and may be branched.
Specific examples of the fatty acids are capric acid, caprylic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, elaidic acid, linolic acid, linolenic acid, isostearic acid. The esters include butyl stearate, octyl stearate, amyl stearate, isooctyl stearate, butyl myristate, octyl myristate, butoxyethyl stearate, butoxydiethyl stearate, 2-ethylhexyl stearate, 2-octyldodecyl palmitate, 2-hexyldodecyl palmitate, isohexadecyl stearate, oleyl oleate, dodecyl stearate, tridecyl stearate, oleyl erucate, neopentylglycol didecanoate, ethylene glycol dioleate.
(Back Layer)
Preferably, the back layer contains carbon black and an inorganic powder. Regarding the binder and various additives to the back layer, referred to are those mentioned hereinabove for the magnetic layer and the non-magnetic layer. The thickness of the back layer is preferably from 0.1 to 1.0 μm, more preferably from 0.4 to 0.6 μm.
(Support)
The support for the magnetic tape is preferably a non-magnetic flexible support. For this, usable are any known films of polyesters such as polyethylene terephthalate, polyethylene naphthalate; as well as polyolefins, cellulose triacetate, polycarbonates, aromatic or aliphatic polyamides, polyimides, polyamidimides, polysulfones, polyaramids, and polybenzoxazole. Of those, preferred are polyethylene terephthalate films and polyimide films. The support may be previously processed for corona discharge treatment, plasma treatment, adhesiveness improvement treatment, thermal treatment or dust removal treatment.
Preferably, the support has an elastic modulus in the machine direction of from 3.5 to 20 GPa, and an elastic modulus in the cross direction of from 3.5 to 20 GPa. More preferably, the elastic modulus of the support is from 4 to 15 in both the machine direction and the cross direction.
(Production Method)
The magnetic layer and the non-magnetic layer may be formed by dissolving or dispersing the above-mentioned components in a solvent to prepare coating compositions for these, and applying the compositions in order on a support (web). The method may be either a wet-on-wet system where the magnetic layer is formed while the underlying non-magnetic layer is still wet, or a wet-on-dry system where the magnetic layer is formed after the underlying non-magnetic layer is dried. Thus coated and dried, the web is suitably oriented, calendered and slit.
[Data-Recording Magnetic Tape]
The data-recording magnetic tape for use herein comprises a magnetic layer formed on a non-magnetic support, and optionally has a back layer. One preferred embodiment of the tape comprises a non-magnetic lower layer and a magnetic upper layer formed on a support having a thickness of from 2 to 9 μm, and has aback layer formed on the opposite side thereto. The constitutive elements of the magnetic tape are suitable to high-density recording, and the magnetic tapes described in JP-A 2001-250219 and 2002-251710 are preferred examples for use herein.
[Magnetic Tape Cartridge]
The magnetic tape cartridge of the invention is so designed that a magnetic tape is wound up around one or more reels rotatably housed in the cartridge case, and this is characterized in that the leader tape that is bonded to the top end of the magnetic tape and is let out toward a magnetic recording and reproduction device while leading the magnetic tape is the leader tape of the invention.
[Magnetic Recording and Reproduction Device]
The leader tape of the invention exhibits its effect when used in a magnetic recording and reproduction device where the line recording density is at least 100 kfci and the difference between the recording track width and the reproduction track width is from 0 to 16 μm, and its effect is more remarkable when it is used in a magnetic recording and reproduction device where the difference between the recording track width and the reproduction track width is at most 10 μm.
Preferably, the thickness of the leader tape is at most 5 times that of the magnetic tape, more preferably at most 3 times, even more preferably at most 2 times.
Also preferably, the length of the leader tape is not shorter than the length corresponding to at least 3 windings of the drive reel in the magnetic recording and reproduction device, plus the tape running route length from the mouth of the cartridge case to the drive reel.
One embodiment of the magnetic recording and reproduction device used for the invention is described in detail with reference to the drawings attached hereto. Of the drawings that are referred to herein, FIG. 1 is a constitutional view conceptually showing one embodiment of the recording and reproduction device of the invention; FIG. 2 is a perspective exploded view showing the magnetic tape cartridge used in the magnetic recording and reproduction device; FIG. 3A is a perspective view of the drive reel (take-up reel) used in the magnetic recording and reproduction device; FIG. 3B is a partly-enlarged cross-sectional view of FIG. 3A cut along the IIIB-IIIB line. The magnetic recording and reproduction device of this embodiment comprises a magnetic tape cartridge with a magnetic tape wound up around one cartridge reel (let-off reel) and a magnetic tape drive (tape drive) loaded with the magnetic tape cartridge, and this is used in the magnetic recording and reproduction method described hereinunder.
As in FIG. 1, the magnetic recording and reproduction device 1 comprises a magnetic tape cartridge 10 and a magnetic tape drive 20. In the magnetic recording and reproduction device 1 of the type, the magnetic tape MT wound up in the magnetic tape cartridge 10 is let off and taken by the drive reel of the magnetic tape drive 20 that serves as a tape receiver, or the magnetic tape MT thus wound up around the drive reel 20 is unwound toward the cartridge reel (let-off reel) 11, whereby information is recorded on the magnetic tape MT or the information thus recorded on the magnetic tape MT is reproduced.
As in FIG. 2, the magnetic tape cartridge 10 satisfies the LTO Standard, and this has a cartridge case 2 divided into a lower half 2B and an upper half 2A. Inside it, the cartridge case 2 houses a single cartridge reel 11 around which a magnetic tape MT is wound up; a reel lock and a compression coil spring 5 for keeping the rotation of the cartridge reel 11 locked; a release pad 6 for releasing the locked condition of the cartridge reel 11; a slide door 2D for opening and closing the magnetic tape let-off mouth 2C formed on one face of the cartridge case 2 to extend to both the lower half 2B and the upper half 2A; a twisted coil spring 7 for forcedly pushing the slide door 2D toward the closing position of the magnetic tape let-off mouth 2C; a miserasure preventing claw 8; and a leader pin rack 9 formed near the magnetic tape let-off mouth 2C. A leader tape LT is bonded to the top end of the magnetic tape MT. The magnetic tape MT in FIG. 2 is the leader tape LT.
The magnetic tape cartridge 10 is loaded in the magnetic tape drive 20, as in FIG. 1, and the leader tape LT is let out by the leader block 31 which will be described hereinunder, and the leader block 31 is fitted into the recess 23 formed in the core 22 of the drive reel 21 in the magnetic tape drive 20. Accordingly, the leader tape TL from the magnetic tape cartridge 10 may be thereby wound up around the core 22 of the drive reel 21.
The leader tape LT and the magnetic tape MT used in the magnetic tape cartridge 10 of this embodiment are described in detail.
The leader tape LT is formed long, and in this embodiment, its length is enough to correspond to at least 3 windings around the core 22 of the drive reel 21 in the magnetic tape drive 20. The leader tape LT preferably has a length of from 0.5 to 5.0 m, more preferably 0.9 m.
Next described is the magnetic tape drive 20.
The magnetic tape drive 20 comprises a spindle 24, a spindle drive unit 25 for driving the spindle 24, a magnetic head H, a drive reel 21, a take-up reel drive unit 26 for driving the drive reel 21, and a control unit 27, as in FIG. 1.
In addition, the magnetic tape drive 20 is provided with a leader block 31 capable of engaging with the leader pin (see FIG. 2) disposed at the top end of the leader tape LT from the magnetic tape cartridge 10, and the leader block 31 is moved toward the magnetic tape cartridge 10 by a lead-off mechanism (not shown) including a lead-off guide 32 or the like.
When data are recorded/reproduced on/from the magnetic tape MT, the spindle drive unit 25 and the take-up reel drive unit 26 act to rotate and drive the spindle 24 and the drive reel 21, whereby the magnetic tape MT is moved.
The drive reel 21 is so designed that the upper face of the lower flange 21a has radial grooves 21b formed at regular intervals, as in FIGS. 3A and 3B. The grooves 21b function as discharge paths for discharging the air that may enter the drive reel 21 while the magnetic tape MT is wound up around it.
The action of the magnetic tape drive 20 is described.
When the magnetic tape cartridge 10 is set in the magnetic tape drive 20 as in FIG. 1, then the lead-off guide 32 (see FIG. 2) acts to lead out the leader pin 30 and move it to the drive reel 21 via the magnetic head H, and the leader block 31 is thereby fitted into the recess 23 of the core 22 of the drive reel 21. The recess 23 is provided with an anchor part (not shown) that engages with the leader block 31 to thereby prevent the leader block 31 from jumping out of the recess 23.
With that, the spindle drive unit 25 and the take-up reel drive unit 26 are driven while controlled by the control unit 27, and the spindle 24 and the drive reel 21 are rotated in the same direction so that the leader tape LT and the magnetic tape MT are moved toward the drive reel 21 from the cartridge reel 11. Accordingly, the leader tape LT is wound up around the drive reel 21, and then the magnetic tape MT is wound up around the drive reel 21, whereupon information is recorded on the magnetic tape MT or the information recorded on the magnetic tape MT is reproduced by the action of the magnetic head H.
When the magnetic tape MT is rewound around the cartridge reel 11, the spindle 24 and the drive reel 21 are rotated and driven in the direction opposite to the above, whereby the magnetic tape MT is moved toward the cartridge reel 11. Also in the rewinding operation, information recording on the magnetic tape MT or information reproduction from the magnetic tape MT may be attained by the magnetic head H.
In the magnetic recording and reproduction device 1 of the type, the magnetic tape MT is generally kept wound in the magnetic cartridge 10 in many cases, but in some use embodiment, it may be kept wound up around the drive reel 21 in the magnetic tape drive 20 for a long period of time. In some such use embodiment, the usefulness of preventing tape deformation transfer is extremely great, and the magnetic recording and reproduction device 1 of this embodiment are favorable for the case. Specifically, when the magnetic tape MT is wound up around the drive reel 21 of the magnetic tape drive 20 from the magnetic tape cartridge 10, the leader block 31 that acts to lead the magnetic tape MT out of the magnetic tape cartridge 10 is fitted into the core 22 of the drive reel 21, but depending on the dimensional accuracy of the leader block 31, the leader block 31 may protrude (as level difference) from the edge face of the core 22. In such a case, when a conventional leader tape is wound up around the drive reel 21, then the level difference may be transferred to the magnetic tape MT and the distance between the magnetic head and the magnetic layer may be enlarged, therefore causing some problems of recording failure and information loss in the magnetic tape MT.
Contrary to this, in the magnetic recording and reproduction of the invention, the level difference can be well absorbed by the leader tape LT, and even when the magnetic recording and reproduction device 1 is used, in which the line recording density is at least 100 kfci and the difference between the recording track width and the reproduction track width is from 0 to 16 μm, the method of the invention enjoys the advantage in that it can evade the problems of recording failure and information loss in the magnetic tape MT.
EXAMPLES
The invention is described in detail with reference to the following Examples, to which, however, the invention should not be limited.
Example 1
In the Examples, “part” is by weight.
Formation of Leader Tape:
<Preparation of Coating Compositions>










Coating Composition for upper layer:
















Ferromagnetic metal powder
 100 parts


coercive force Hc: 128 kA/m (1600 Oe)


specific surface area by BET method: 53 m2/g


crystallite size: 160 angstroms


saturation magnetization σs: 130 A · m2/kg


mean major axis length: 130 nm


mean acicular ratio: 6.5


pH: 9.3


Co/Fe: 5 atm. %


Al/Fe: 7 atm. %


Y/Fe: 2 atm. %


soluble Na: 5 ppm


soluble Ca: 1 ppm


soluble Fe: 1 ppm


Vinyl chloride-based copolymer (Nippon Zeon's MR-100)
  10 parts


(—SO3Na content: 5 × 10−6 eq/g, degree of polymerization:


350), epoxy content: 3.5 weight % as monomer unit)


Polyester-polyurethane resin
 2.5 parts


(neopentylglycol/caprolactone polyol/MDI = 0.9/2.6/1 by


weight, —SO3Na content: 1 × 10−4 eq/g)


α-alumina (mean particle size: 0.3 μm)
  10 parts


Carbon black (mean particle size: 0.10 μm)
  1 part


Butyl stearate
 1.5 parts


Stearic acid
 0.5 parts


Methyl ethyl ketone
 150 parts


Cyclohexanone
  50 parts


Toluene
  40 parts



















Coating Composition for under layer:
















Non-magnetic powder, TiO2
  90 parts


specific surface area by BET method: 45 m2/g


mean grain diameter: 0.1 μm


pH: 6.5


soluble Na: 5 ppm


soluble Ca: 1 ppm


Carbon black
  10 parts


mean primary particle size: 16 nm


DBP oil absorption: 80 ml/100 g


pH: 8.0


specific surface area by BET method: 250 m2/g


Vinyl chloride-based polymer
  12 parts


Nippon Zeon's MR-100


Polyester-polyurethane resin
  5 parts


(neopentylglycol/caprolactone polyol/MDI = 0.9/2.6/1 by


weight, —SO3Na content: 1 × 10−4 eq/g)


Butyl stearate
1.06 parts


Stearic acid
1.18 parts


Methyl ethyl ketone
 150 parts


Cyclohexanone
  50 parts


Toluene
  40 parts









The constitutive components of the upper layer coating composition and those of the lower layer coating composition were separately kneaded in a continuous kneader and then dispersed by the use of a sand mill. 5 parts of polyisocyanate (Nippon Polyurethane's Coronate L) was added to each of the resulting dispersions, and 40 parts of methyl ethyl ketone was added to each of them. The dispersions were filtered through a filter membrane having a mean pore size of 1 μm, and the upper layer coating composition and the lower layer coating composition were thus obtained.










Coating Composition for back layer formation:
















Particulate carbon black
 100 parts


(Cabot's BP-800, mean particle size: 17 nm)


Coarse carbon black
 10 parts


(Carncalp's thermal black, mean particle size: 270 nm)


α-alumina (hard inorganic powder)
  5 parts


(mean particle size: 200 nm, Mohs' hardness: 9)


Nitrocellulose resin
 140 parts


Polyurethane resin
 15 parts


Polyester resin
  5 parts


Dispersant: copper oleate
  5 parts


Copper phthalocyanine
  5 parts


Barium sulfate (precipitating)
  5 parts


(BF-1, mean particle size: 50 nm, Mohs' hardness: 3, by


Sakai Kagaku Kogyo)


Methyl ethyl ketone
1200 parts


Butyl acetate
 300 parts


Toluene
 600 parts









The constitutive components of the back layer coating composition were kneaded in a continuous kneader and then dispersed by the use of a sand mill. 40 parts of polyisocyanate (Nippon Polyurethane's Coronate L) and 1000 parts of methyl ethyl ketone were added to the resulting dispersion, and this was filtered through a filter membrane having a mean pore size of 1 μm to prepare a back layer coating composition.
<Preparation of Leader Tape>
The upper layer coating compound and lower layer coating compound thus obtained were simultaneously spread over a polyethylene terephthalate (PET) support of continuous length (thickness: 14.0 μm; F5 value in machine (MD) direction: 105 MPa; F5 value in transverse (TD) direction: 96 MPa; Ra (cutoff value: 0.25 mm): 40 nm) to a dry thickness of 0.8 μm and 1.8 μm, respectively. Subsequently, while the upper layer was wet, the coated support was stretched using a cobalt magnet having a magnetic force of 300 mT and a solenoid having a magnetic force of 150 mT. Thereafter, the coated support was dried to form an upper layer.
F5 value of the PET support was adjusted by adjusting the factor of stretching.
F5 value was determined by the following measurement method.
The sample was cut into a size of 1⁄2 inch wide (MD direction) and about 200 mm long (TD direction). Using a tensile testing machine “Strograph”, the sample was then pulled at a pulling rate of 25 mm/min over a distance of 100 mm between chucks. The load value and thickness of the various samples at 5% elongation were used to determine strength at 5% elongation as F5 value.
Thereafter, the aforementioned back layer coating compound was spread over the other surface of the support (surface opposite the upper layer) to a dry thickness of 0.5 μm, and then dried to form a back layer. Thus, a leader tape having an upper layer provided on one surface thereof and a back layer provided on the other surface thereof was obtained in the form of roll.
The web was allowed to run through a 110° C. heat treatment zone for 5 seconds under a tension of 1.5 Kg/m (14.7 N/m) so that it was subjected to heat treatment.
The roll of leader tape thus heat-treated was passed through a 7-stage calendering machine comprising a hot metal roll and an elastic roll having a core metal covered by a thermosetting resin (temperature: 90° C.; linear pressure: 300 Kg/cm (294 kN/m); speed: 300 m/min) so that it was calendered, and then wound under a tension of 5 Kg/m (49 N/m). The hot metal roll was made of chrome-molybdenum steel plated with hard chromium. The surface roughness Ra of the hot metal roll was 0.005 μm (cutoff value: 0.25 mm). The thermosetting resin constituting the elastic roll was obtained by reacting a work of bis(2-oxoline) with an aromatic diamine and an epoxy compound.
The roll thus obtained was then subjected to heat treatment at 50° C. for 48 hours. Subsequently, the roll was slit into a size of 1⁄2 inch wide, and then passed through a solenoid having a magnetic flux density of 300 mT to undergo demagnetization.
[Preparation of Magnetic Tape Cartridge]
The 1⁄2 inch wide magnetic tape thus obtained was connected as a leader tape to a commercially available LTO tape to prepare a magnetic tape cartridge. The magnetic tape was wound over a length of 580 m.
Example 2
A magnetic tape cartridge according to the invention was prepared in the same manner as in Example 1 except that as the support to be used in the preparation of leader tape there was used a PET support having an F5 value of 118 MPa and 108 MPa in MD direction and TD direction, respectively.
Example 3
A magnetic tape cartridge according to the invention was prepared in the same manner as in Example 1 except that as the support to be used in the preparation of leader tape there was used a PET support having an F5 value of 90 MPa and 85 MPa in MD direction and TD direction, respectively.
Comparative Example 1
A magnetic tape cartridge was prepared in the same manner as in Example 1 except that as the support to be used in the preparation of leader tape there was used a PET support having an F5 value of 130 MPa and 118 MPa in MD direction and TD direction, respectively.
Comparative Example 2
A magnetic tape cartridge was prepared in the same manner as in Example 1 except that as the support to be used in the preparation of leader tape there was used a PET support having an F5 value of 85 MPa and 75 MPa in MD direction and TD direction, respectively.
Comparative Example 3
A magnetic tape cartridge was prepared in the same manner as in Example 1 except that as the support to be used in the preparation of leader tape there was used a PET support having an F5 value of 117 MPa and 100 MPa in MD direction and TD direction, respectively.
Comparative Example 4
A magnetic tape cartridge was prepared in the same manner as in Example 1 except that as the support to be used in the preparation of leader tape there was used a PET support having an F5 value of 100 MPa and 110 MPa in MD direction and TD direction, respectively.
Comparative Example 5
A magnetic tape cartridge was prepared in the same manner as in Example 1 except that only the upper layer coating compound was spread over the support to a thickness of 2.6 μm.
[Evaluation of Magnetic Tape Cartridge]
(1) Deformation of Magnetic Tape
The magnetic tape cartridge thus obtained was subjected to 10,000 cycles of load/unload using LTO remodeled drive at a temperature of 23±2° C. and a relative humidity of from 40 to 60%. Thereafter, the meter length over which the shape of the leader tape and the drive reel is caught by the magnetic tape was determined by a three-score method.

    
    
        3 points: Less than 5 m
        2 points: From not smaller than 5 m to less than 20 m
        1 point: 20 m or more
    
    


The results are set forth in Table 1 below.











TABLE 1









Surface
Surface




strength of
electrical



support
resistance
Deformation



F5 value (MPa)
Rs Ω/sq
of magnetic













MD
TD
Upper layer
Back layer
tape
















Example 1
105
96
5 × 108
8 × 107
3


Example 2
118
108
5 × 108
8 × 107
3


Example 3
90
85
5 × 108
8 × 107
2


Comparative
130
118
5 × 108
8 × 107
1


Example 1


Comparative
85
75
5 × 108
8 × 107
1


Example 2


Comparative
117
100
5 × 108
8 × 107
1


Example 3


Comparative
100
110
5 × 108
8 × 107
1


Example 4


Comparative
105
96
5 × 108
8 × 107
1


Example 5









As can be seen in the aforementioned results, the inventive examples show a less deformation of magnetic tape than the comparative examples.

## Claims

1. A leader tape comprising: a support; a non-magnetic under layer that contains a powder and a binder; and a magnetic upper layer in this order on at least one face of the support,
wherein the support has a first F5 value in a machine direction and a second F5 value in a transverse direction,
the first F5 value and the second F5 value are from 80 to 120 MPa,
the first F5 value is larger than the second F5 value, and
a difference between the first F5 value and the second F5 value is in a range of 2 MPa to 15 MPa.

2. The leader tape according to claim 1, which further comprises a back layer on an opposite face of the support, and the magnetic upper layer and the back layer each has a surface electrical resistance in a range of 1×105 to 1×1010 Ω/sq.

3. The leader tape according to claim 1, wherein the first F5 value and the second F5 value are 85 to 115 MPa.

4. The leader tape according to claim 1, wherein the first F5 value and the second F5 value are 90 to 105 MPa.

5. The leader tape according to claim 1, wherein the difference is 10 MPa or less.

6. The leader tape according to claim 1, wherein the support has a center line average roughness of 30 to 50 nm.

7. The leader tape according to claim 1, which has a thickness of 5 to 20 μm.

8. The leader tape according to claim 1, which has a thickness of 8 to 18 μm.

9. A magnetic tape cartridge where a magnetic tape is wound up around one or more reels rotatably housed in the cartridge case, in which a leader tape that is bonded to the top end of the magnetic tape and is let out toward a magnetic recording and reproduction device while leading the magnetic tape is the leader tape of claim 1.