SDS: 0055510 Date Prepared: 09/16/2013 

## SAFETY DATA SHEET

 

## 1. IDENTIFICATION

Product Name: 

### IRR 781
Synonyms: None Chemical Family: Acrylated oligomer Molecular Weight: Mixture

Intended/Recommended Use: Coatings & Inks.

Allnex USA Inc., 1950 Lake Park Driv e, Smyrna, Georgia 30080, USA For Product and all Non-Emergency Information call your local Allnex contact point or contact us at http://www.allnex.com/contact

EMERGENCY PHONE (24 hours/day) - For emergency only invo lving spill, leak, fire, exposure or accident call:

Asia Pacific: Australia: +61 2801 44558 (Carechem 24) China (PRC): +86(0)532-8388-9090 (NRCC) Japan: +81 345 789 341 (Carechem 24) New Zealand: +64 9929 1483 (Carechem 24) All Others: +65 3158 1074 (Carechem 24) Europe/Africa/Middle East (Carechem 24): Europe, Middle East, Africa, Israel: +44 (0) 1235 239 670 Middle East, Africa (Arabic speaking countries): +44 (0) 1235 239 671 Latin America (Carechem 24):

Brazil: +55 113 711 9144

Mexico and all others: +52-555-004-8763 Canada and USA (Carechem 24 - Allnex29003-NCEC): +1-866-928-0789 (toll free) or +1-215-207-0061

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## 2. HAZARDS IDENTIFICATION

GHS Classification Serious Eye Damage / Eye Irritation Hazard Category 2A Skin Corrosion / Irritation Hazard Category 2

LABEL ELEMENTS

Signal Word Warning

Hazard Statements

Causes skin irritation Causes serious eye irritation

Precautionary StatementsIRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 2 of 8

Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. Specific treatment (see supplemental first aid instructions on this label).

If skin irritation occurs: Get medical advice/attention. Take off all contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously wi th water for several minutes. Re move contact lenses , if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Hazards Not Otherwise Classified (HNOC), Other Hazards Polymerization may occur from excessive heat, contamination or exposure to direct sunlight. This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous. It may only be used for R&D purposes under the supervision of technically qualified individuals.

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## 3. COMPOSITION/INFORMATION ON INGREDIENTS

HAZARDOUS INGREDIENTS

Component / CAS No. % GHS Classification Carcinogen Acrylated oligomer

- 99.5 Skin Irrit. 2 (H315) Eye Irrit. 2A (H319) -

The specific chemical identity and/or exact percentage of co mposition for one or more ingredients has been withheld as a

trade secret.

Additional GHS classification or other information may be in cluded in this section but has not been adopted by OSHA. See Section 16 for full text of H phrases.





## 4. FIRST AID MEASURES

DESCRIPTION OF FIRST AID MEASURES

Eye Contact: Rinse immediately with plenty of water for at least 15 minut es. Obtain medical advice if there are persistent symptoms.

Skin Contact: Remove contaminated clothing and shoes without delay. Wa sh immediately with plenty of water. Do not reuse contaminated clothing without laundering. Get medical attention if pain or irritation persists after washing or if signs and symptoms of overexposure appear.

Ingestion: If swallowed, call a physician immediately. Only induce vomi ting at the instruction of a physician. Never give anything by mouth to an unconscious person.

Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if t here are persistent symptoms.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED

None known

INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED

Not applicable

IRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 3 of 8



## 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media: Use water spray, alcohol foam, carbon dioxide or dry chemic al to extinguish fires. Water stream may be ineffective.

Protective Equipment: Firefighters, and others exposed, wear se lf-contained breathing apparatus. Wear fu ll firefighting protective clothing. See MSDS Section 8 (Exposure C ontrols/Personal Protection).

Special Hazards: Keep containers cool by spraying with water if exposed to fire.





## 6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Where exposure level is not known, wear approved, positiv e pressure, self-contained respirator. Where exposure level is known, wear approved respirator suitable for level of exposure. In addition to the pr otective clothing/equipment in Section 8 (Exposure Controls/Personal Prot ection), wear impermeable boots.

Methods For Cleaning Up: Remove sources of ignition. Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water.

References to other sections:

See Sections 8 and 13 for additional information.

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## 7. HANDLING AND STORAGE

HANDLING

Precautions: Wash hands thoroughly after handling. Wear pr otective gloves and eye/face protection.

Special Handling Statements: Contact with this material may not be apparent until 24-48 hour s after the exposure. Therefore, good personal hygiene, such as washing imm ediately with soap and water after handling is highly recommended. This is a research and development (R &D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigat ed. Its handling or use may be hazardous. It may only be used for R&D purposes under the supervision of technically qualified individuals.

STORAGE Containers which are opened must be carefully resealed and k ept upright to prevent leakage. Prevent unauthorised access. Storage in stainless steel, amber glass, amber polyethylene or baked phenolic lined container. Keep containers tightly closed. Keep away from heat.

Storage Temperature: Store at 4 - 40 °C 39.2 - 104 °F

Reason: Quality.

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## 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures: Utilize a closed system process where feasible. Where this ma terial is not used in a closed system, good enclosure and local exhaust ventilation should be pr ovided to control exposure.

Respiratory Protection: For operations where inhalation exposure can occur use an approved respirator. Recommendations are listed below. Othe r protective respiratory equipment may be used based on user 's own risk assessment. Recommended respirators include those certified by NIOS H (U.S.) or CEN (EU).IRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 4 of 8

Recommended: Full Face Mask with organic v apor cartridge, Type A filter (BP >65°C)

Eye Protection: Prevent eye and skin contact. Provide eye wash fountain and safety shower in close proximity to points of potential exposure. Wear eye/face protec tion such as chemical splash proof goggles or face shield.

Skin Protection: Prevent contamination of skin or clothing when removing protective equipment. Wear impermeable gloves and impervious protective clothing.

Hand Protection: Wear protective gloves. Recommendations are listed below. Ot her protective materials may be used based on user's own risk assessment. Barrier creams may help to protect the expo sed areas of the skin, they sh ould however not be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension, color, flexibility etc.) is noticed.

Gloves for short term exposure: Laminated multilayer gloves, break through time: > 60 min Nitrile rubber (NBR), thickness: > 0.56 mm, break through time: < 60 min

The chemical resistance depends on the type of product and am ount of product on the glove. Therefore gloves need to be changed when in contact with chemicals.

Not suitable gloves: Latex gloves

Due to many conditions (e.g. temperature, abrasion) the practi cal usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing.

Additional Advice: Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water.





### Exposure Limit(s)

No values have been established.

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## 9. PHYSICAL AND CH EMICAL PROPERTIES

Color: colorless to yellow Appearance: liquid resin

Odor: ester-like Boiling Point: >100 °C 212 °F Melting Point: ~50 °C 122 °F Vapor Pressure: 1.33hPa @ 20 °C Specific Gravity/Density: 1.0 - 1.2 g/cm3 Vapor Density: Not available Percent Volatile (% by wt.): <0.1 - 0.3- pH: Not applicable Saturation In Air (% By Vol.): Not applicable Evaporation Rate: Not applicable Solubility In Water: negligible Volatile Organic Content: Not available

Flash Point: >100 °C 212 °F Cleveland Open Cup Flammable Limits (% By Vol): Not available Autoignition Temperature: Not available Decomposition Temperature: Not available

Partition coefficient (n-octanol/water): Not available

Odor Threshold: Not availableIRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 5 of 8



## 9. PHYSICAL AND CH EMICAL PROPERTIES

Viscosity (Kinematic): Not available

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## 10. STABILITY AND REACTIVITY

Stability: Stable

Conditions To Avoid: Avoid direct exposure to sunlight. Avoi d temperatures above 60°C (140°F). Avoid friction with temperature increase as resu lt. Avoid exposure to strong UV sources. Loss of dissolved air. Loss of polymerization inhibitor. Avoid direct contact with heat

sources.

Polymerization: May occur

Conditions To Avoid: Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupt ure of sealed storage vessels or containers

A void contact with bases or amines. Avoid c ontact with strong oxidizing agents. Avoid

contact with free radical initiators.

Materials To Avoid: Avoid free radical producing initiators. Av oid contact with peroxides. Avoid contact

with reactive metals. Avoid contact with strong alkalis. They give an exothermic reaction with the product. Unintentional contact with them should be avoided.

Avoid contact with active metals.

Hazardous Decomposition

Products: Hazardous polymerization can occur when exposed to direct sunlight. Hazardous exothermic polymeriz ation can occur when heated.

oxides of carbon

smoke hydrocarbons

soot

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## 11. TOXICOLOGICAL INFORMATION

PRODUCT TOXICITY INFORMATION

Likely Routes of Exposure: Skin, Eyes, Oral.

ACUTE TOXICITY DATA

oral rat Acute LD50

. No data

dermal rabbit Acute LD50

. No data

inhalation rat Acute LC50 4 hr

. No data

LOCAL EFFECTS ON SKIN AND EYE

Acute Irritation skin Irritating

Acute Irritation eye Irritating

ALLERGIC SENSITIZATION

Sensitization skin No data

Sensitization respiratory No data

GENOTOXICITY

Assays for Gene MutationsIRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 6 of 8

Ames Salmonella Assay No data

OTHER INFORMATION This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous. It may only be used for R&D purposes under the supervision of technically qualified individuals.

HAZARDOUS INGREDIENT TOXICITY DATA

The toxicological properties of acrylated oligomer have not been fully investigated. Direct contact may cause moderate eye and skin irritation. Prolonged or repeated contact may cause alle rgic skin reaction in individuals previously sensitized to acrylates.

California Proposition 65 Warning (applicable in California only) - This product contains (a) chemical(s) known to the State o f California to cause birth defects or other reproductive harm.





## 12. ECOLOGICAL INFORMATION

TOXICITY, PERSISTENCE AND DEGRADABILITY, BIOACCU MULATIVE POTENTIAL, MOBI LITY IN SOIL, OTHER

ADVERSE EFFECTS

This is a research and development (R&D) sample. The ecological properties of this material have not been fully investigated. Avoid release to the environment.

RESULTS OF PBT AND vPvB ASSESSMENT This product does not meet the criteria for PBT (Persisten t, Bioaccumulative and Toxic su bstance) or for vPvB (Very Persistent and Very Bioaccumulative).

HAZARDOUS INGREDIENT TOXICITY DATA

Component / CAS No. Toxicity to Algae Toxicity to Fish Toxicity to Water Flea

A crylated oligomer

- Not available Not available Not available

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## 13. DISPOSAL CONSIDERATIONSIRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 7 of 8



## 13. DISPOSAL CONSIDERATIONS

The information on RCRA waste classification and disposal methodology provided below applies only to the product, as supplied. If the material has been altered or contaminated, or it has exceeded its recommended shelf life, the guidance may be inapplicable. Hazardous waste classi fication under federal regulations (40 CFR Part 261 et seq) is dependent upon

whether a material is a RCRA "listed ha zardous waste" or has any of the four RCRA "hazardous waste characteristics." Refer to 40 CFR Part 261.33 to determine if a given material to be disposed of is a RCRA "listed haz ardous waste";

information contained in Section 15 of this MSDS is not int ended to indicate if the product is a "listed hazardous waste."

RCRA Hazardous Waste Characteristics: There are four characteristics defi ned in 40 CFR Section 261.21-61.24: Ignitability, Corrosivity, Reactivity, and To xicity. To determine Ignitability, see Sect ion 9 of this MSDS (flash point). For Corrosivity, see Sections 9 and 14 (pH and DOT corrosivity). Fo r Reactivity, see Section 10 (incompatible materials). For Toxicity, see Section 3 (composition). Federal regulations ar e subject to change. State and local requirements, which may differ from or be more stringent than the federal regulations, may also apply to the classification of the material if it is to be disposed. The Company encourages the re cycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste. The Company recommends that organi c materials classified as RCRA hazardous wastes be disposed of by thermal treatment or incineration at EPA approved facilit ies. The Company has provided the foregoing for information only; the person generating the waste is responsible for determining the wa ste classification and disposal method.





## 14. TRANSPORT INFORMATION

This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements.

US DOT

Dangerous Goods? Not applicable/Not regulated

TRANSPORT CANADA

Dangerous Goods? Not applicable/Not regulated

ICAO / IATA

Dangerous Goods? Not applicable/Not regulated

IMO

Dangerous Goods? Not applicable/Not regulated



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__________________________ __________________ __________________ ______________



## 15. REGULATORY INFORMATION

Inventory Information

This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous, and it must be used under the supervision of technically qualified individuals. The chemical inv entory status has not been determined and may contain components NOT included on the pertinent national chemical inventories. Materials not in cluded on the pertinent national chemical inventories may only be used for research and development (R&D) purposes or in ot her exempt activities. Exemptions for R&D uses or other activities vary for each country. These requirements are spec ifically defined and may include notification and/or record keeping.

OTHER ENVIRONMENTAL INFORMATION The following components of this product may be subject to r eporting requirements pursuant to Section 313 of CERCLA (40 CFR 372), Section 12(b) of TSCA, or may be subject to releas e reporting requirements (40 CF R 307, 40 CFR 311, etc.) See

Section 13 for information on waste classifi cation and waste disposal of this product.

This product does not contain any components regulated under these sections of the EPA

PRODUCT HAZARD CLASSIFICATION UNDER SECTION 311 OF SARAIRR 781 SDS: 0055510 Date Prepared: 09/16/2013 Page 8 of 8

• Acute • Reactivity



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________________________ ____________________ __________________ ______________



## 16. OTHER INFORMATION

NFPA Hazard Rating (National Fire Protection Association) Health: 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.

Fire: 1 - Materials that must be preheated before ignition can occur.

Instability: 1 - Materials that in themselves are no rmally stable, but that can become unstabl e at elevated
temperatures and pressures.

Reasons For Issue: New Company Identification

Date Prepared: 09/16/2013 Date of last significant revision: NOT AUTHORIZED

Component Hazard Phrases Acrylated oligomer

H315 - Causes skin irritation. H319 - Causes serious eye irritation.

 Prepared By: Product Stewardship & Regulatory Affairs Department, http://www.allnex.com/contact

 This information is given without any warr anty or representation. We do not assume any legal responsibility for same, nor do w e give permission, inducement, or recommendation to practice an y patented invention without a license. It is offered solely for your consideratio n, investigation, and verification. Before using any product, read its label.

