Page 1 of 8 Revision date 02/15/2008 

# Material Safety Data Sheet

1. PRODUCT AND COMPA NY IDENTIFICATION

ROBOND TM CR

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Revision date: 02/15/2008

Supplier ROHM AND HAAS CHEMICALS LLC

A Subsidiary of The Dow Chemical Company

100 INDEPENDENCE MALL WEST

PHILADELPHIA

, PA 19106

- 2399 United States

For non

- emergency information contact: 215

- 592

- 3000

For non

- emergency information contact: 215

- 592

- 3000

Emergency telephone number

1 800 424 9300

Local emergency telephone number

989

- 636

- 4400



### 2. COMPOSITION/INFOR MATION ON INGREDIENT S

Component CAS

- No. Concentration

Polymeric isocyanate Not Hazardous 99.0

- 100.0%

Hexamethylene diisocyanate 822

- 06

- 0 < 1.0%



### 3. HAZARDS IDENTIFIC ATION

Emergency Overview



### Appearance

Form liquid

Colour colorless to pale yellow

Odour Faint odorROBOND TM CR

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Page 2 of 8 Revision date 02/15/2008 

### Hazard Summary WARNING !

INHALATION OF VAPOR OR MIST CAN CAUSE TH E

FOLLOWING:

SHORTNESS OF BREATH

TIGHTNESS IN THE CHE ST

IRRITATING TO EYES A ND SKIN.

MAY CAUSE SENSITIZAT ION BY INHALATION AN D SKIN

CONTACT.

LONG TERM EXPOSURE T O DIISOCYANATES MAY CAUSE

LUNG DAMAGE, INCLUDI NG REDUCED LUNG FUNC TION,

WHICH MAY BE PERMANE NT.

CLOSED CONTAINERS MA Y EXPLODE WHEN HEATE D OR

CONTENTS CONTAMINATE D WITH WATER.

Potential Health Effects

Primary Routes of Entry: Inhalation

Eye contact

Skin contact

Eyes: Material can cause the following:

Moderate irritation.

burning sensation

tearing

reddening

Skin: May cause sensitization by skin contact.

Material can cause the following:

Moderate irritation.

burning sensation

reddening

Itching

Ingestion: Material can cause the following:

severe irritation of the mouth, throat, and digestive tract

diarrhea

nausea

Vomiting

Abdominal pain

Inhalation: Inhalation of vapor or mist can cause the following:

coughing

irritation of nose, throat, and lungs

tightness in the chest

Shortness of breath

May cause severe allergic respiratory reaction.

Sensitisation

Chronic Exposure: Long term exposure to diisocyanates may cause lung damage, including reduced

lung function, w hich may be permanent.



### 4. FIRST AID MEASURE S

Inhalation: Move to fresh air. Give artificial respiration if breathing has stopped. Get prompt medical

attention. In case of shortness of breath, give oxygen.ROBOND TM CR

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Page 3 of 8 Revision date 02/15/2008 Skin contact: Remove contaminated clothing. Wash off with soap and plenty of water. Wash

contaminated clothing before re

- use. Do not take clothing home to be laundered. Consult a

physician.

Eye contact: Flush eyes with water as a precaution. If eye irritation persists, consult a specialist.

In gestion: Drink 1 or 2 glasses of water. Consult a physician. If vomiting occurs spontaneously, keep

airway clear. Never give anything by mouth to an unconscious person.



### 5. FIRE

- FIGHTING MEASURES

Flash point no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Suitable extinguishing

media: Use the following extinguishing media when fighting fires involving this

material:

Carbon dioxide (CO2)

Dry powder

Foam

Water in very large quantities.

Specific hazards during fire fighting: Closed containers may rupture via pressure build

- up when

exposed to fire or extreme heat. During a fire, irritating and highly toxic gases and/or fumes may be

generated during combustion or decomposition. DO NOT permit water to enter containers. Closed

containers may explode when heated or contents contaminated with water.

Special protective equipment for fire

- fighters: In the event of fire, wear self

- contained breathing

apparatus.

Further information: Cool closed containers exposed to fire with water spray.

DO NOT permit water to enter containers.

Remain upwind.

Avoid breathing smoke.

Contain run

- off.



### 6. ACCIDENTAL RELEAS E MEASURES

Personal precautions

Appropriate protective equipment must be worn when handling a spill of this material. See SECTION

8, Exposure Controls/Personal Protection, for recommendations.

MATERIAL IS A POTENTIAL SENSITIZER.

If exposed to material during clean

- up operations, IMMEDIA TELY remove all contaminated clothing

and wash exposed skin areas with soap and water. See SECTION 4, First Aid Measures, for further

information.

Wash contaminated clothing before re

- use.

Do not take clothing home to be laundered.



### Environmental precautio ns

WARNING: KEEP SPILLS AND CLEANING RUNOFFS OUT OF MUNICIPAL SEWERS AND OPEN

BODIES OF WATER.



### Methods for cleaning up

Evacuate personnel to safe areas.

Ventilate the area.

Floor may be slippery; use care to avoid falling.

Soak up with inert absorbent mat erial (e.g. sand, silica gel, acid binder, universal binder, sawdust).ROBOND TM CR

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Page 4 of 8 Revision date 02/15/2008 Sweep up or vacuum up spillage and collect in suitable container for disposal.

Avoid all contact.

Avoid breathing vapor.

NOTE: Spills on porous surfaces can contaminate groundwater.



### 7. HANDLING AND STOR AGE

Handling

Vapors can be evolved when material is heated during processing operations. See SECTION 8,

Exposure Controls/Personal Protection, for types of ventilation required.



### Storage

Storage conditions: Avoid temperature extremes during storage; ambient temperature preferred.

Store away from excessive heat (e.g. steampipes, radiators), from sources of ignition and from

reactive materials. Material can burn; limit indoor storage to approved areas equippe d with automatic

sprinklers. Store out of direct sunlight in a cool place. Keep containers tightly closed in a cool, well

ventilated place. Keep material dry. Moisture may affect product quality.

Storage temperature: 10

- 37.8 °C ( 50

- 100.0 °F )

Furthe r information:

This material is a potential sensitizer.

See SECTION 8, Exposure Controls/Personal Protection, prior to handling.

Wash after handling and shower at end of work period.

CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product

residue follow all MSDS and label warnings even after container is emptied.

Improper disposal or re

- use of this container may be dangerous and illegal. Refer to applicable local,

state and federal regulations.

Persons susceptible to skin sensitisa tion problems or asthma, allergies, chronic or recurrent

respiratory disease should not be employed in any process in which this preparation is being used.



### 8. EXPOSURE CONTROLS / PERSONAL PROTECTIO N

Exposure limit(s)

Exposure limit s are listed below, if they exist.

Component Regulation Type of listing Value

Hexamethylene diisocyanate Rohm and Haas TWA 0.005 ppm

Rohm and Haas STEL 0.02 ppm

ACGIH TWA 0.005 ppm

NIOSH/GUIDE REL 0.035 mg/m3 0.005

ppm

NIOSH/GUIDE Ceil _Time 0.140 mg/m3 0.020

ppm

Eye protection: Use chemical splash goggles (ANSI Z87.1 or approved equivalent). Eye protection

worn must be compatible with respiratory protection system employed.

Hand protection: Chemical

- resistant gloves should be wor n whenever this material is handled. The

glove(s) listed below may provide protection against permeation. (Gloves of other chemically resistant

materials may not provide adequate protection): butyl

- rubber Gloves should be removed and

replaced immediatel y if there is any indication of degradation or chemical breakthrough. Rinse and

remove gloves immediately after use. Wash hands with soap and water.

Skin and body protection: Use chemically resistant apron or other impervious clothing to avoid

prolonged or repeated skin contact. Where splashing is possible, full chemically resistant protective

clothing (e.g. acid suit) and boots are required.

Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2

requirements or e quivalent must be followed whenever workplace conditions warrant a respirator ‟ sROBOND TM CR

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Page 5 of 8 Revision date 02/15/2008 use. None required if airborne concentrations are maintained below the exposure limit listed in

Exposure Limit Information. Above the exposure limit: Wear a properly fitted NIOSH approved (or

equivalent) self

- contained breathing apparatus in the pressure demand mode, OR full

- facepiece,

airline respirator in the pressure demand mode with emergency escape provision.

Protective measures: Facilities storing or utilizing this mat erial should be equipped with an eyewash

facility and a safety shower.



### Engineering measures: Use local exhaust ventilation with a minimum capture velocity of 100

ft/min. (0.5 m/sec.) at the point of vapor evolution. Refer to the current edition of Industr ial Ventilation:

A Manual of Recommended Practice published by the American Conference of Governmental

Industrial Hygienists for information on the design, installation, use, and maintenance of exhaust

systems.



### 9. PHYSICAL AND CHEM ICAL PROPERTIES

Appearan ce

Form liquid

Colour colorless to pale yellow

Odour Faint odor

pH not applicable

Boiling point/boilingrange no data available

Melting point/range not applicable

Flash point no data available

Lower explosion limit not applicable

Uppe r explosion limit not applicable

Vapour pressure no data available

Relative vapour density no data available

Water solubility Reacts

Relative density 1.17 at 20 °C ( 68 °F )

Viscosity, dynamic 2,000

- 6,000 mPa.s

Evaporation rate no data availa ble

Percent volatility negligible

NOTE: The physical data presented above are typical values and should not be construed as a

specification.



### 10. STABILITY AND RE ACTIVITY

Hazardous reactions This material is considered stable.

However, keep away from moisture, heat or flame.

However, this material can undergo hazardous polymerization. See

Hazardous Polymerization for conditions to avoid.

Materials to avoid Avoid contact with the following: Strong Oxidizers Acids Water Bases

Amines

Hazardou s

decomposition

products Thermal decomposition may yield the following:

, isocyanate monomers

,ROBOND TM CR

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Page 6 of 8 Revision date 02/15/2008 polymerization Hazardous polymerization will also occur if contaminated with the

following:

- water (moisture)



### 11. TOXICOLOGICAL IN FORMATION

Sensitisation Can cause allergic skin reactions and respiratory sensitization, even at

low levels of exposure. Sensitizied individuals should not be exposed to

any concentration of this material.



### 12. ECOLOGICAL INFOR MATION

This product has no known eco

- toxicological effects.



### 13. DISPOSAL CONSIDE RATIONS

Environmental precautions: WARNING: KEEP SPILLS AND CLEANING RUNOFFS OUT OF

MUNICIPAL SEWERS AND OPEN BODIES OF WATER.



### Disposal

Waste Classification: When a decision is made to discard this material as supplied, it d oes not meet

RCRA ‟ s characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40 CFR

261.33. The toxicity characteristic (TC), however, has not been evaluated by the Toxicity

Characteristic Leaching Procedure (TCLP).

For d isposal, incinerate this material at a facility that complies with local, state, and federal regulations.

(See 40 CFR 268)

Contaminated packaging: Empty containers should be taken for local recycling or waste disposal.



### 14. TRANSPORT INFORM ATION



## DOT

Not regulated for transport



## IMO/IMDG

Not regulated (Not dangerous for transport)

Transportation classifications may vary by container volume and may be influenced by regional or

country variations in regulations



### 15. REGULATORY INFOR MATION

Workplace Clas sification

This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR

1910.1200).

This product is a „ controlled product ‟ under the Canadian Workplace Hazardous Materials Information

System (WHMIS).



### SARA TITLE III : Section 3 11/312 Categorizations (40CFR370): Acute Health Hazard

Chronic Health HazardROBOND TM CR

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### SARA TITLE III : Section 313 Information (40CFR372)

This product does not contain a chemical which is listed in Section 313 at or above de minimis

concentrations.



### CERCLA Informat ion ( 40CFR302.4 )

This material is regulated under the Comprehensive Environmental Response, Compensation and

Liability Act (CERCLA)and the Superfund Amendments and Reauthorization Act (SARA) Title III

Section 304. This material is or contains chemical(s) l isted in 40 CFR Table 302.4 or nondesignated

RCRA ICR substance(s). (Nondesignated ICR substances apply to materials that will not be reused.)

The Reportable Quantity(s) (RQ) are listed below. Releases in excess of its reportable quantity must

be reported to the National Response Center (1

- 800

- 424

- 8802) and to the appropriate state and local

emergency response organizations.

CERCLA Components: Hexamethylene diisocyanate 822

- 06

- 0 100 lbs RQ



### US. Toxic Substances Control Act ( TSCA ) All components of thi s product are in compliance

with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical

Substance Inventory.



### Pennsylvania

Any material listed as “ Not Hazardous ” in the CAS REG NO. column of SECTION 2,

Composition/Infor mation On Ingredients, of this MSDS is a trade secret under the provisions of the

Pennsylvania Worker and Community Right

- to

- Know Act.



### California (Proposition 65)

This product contains trace levels of a component or components known to the state of Califo rnia to

cause cancer and birthdefects or other reproductive harm:

Components: Ethylene Oxide 75

- 21

- 8



### 16. OTHER INFORMATIO N

Hazard Rating



### Health Fire Reactivity

HMIS 2 1 0



### Legend

ACGIH American Conference of Governmental Industrial Hygienists

BAc Butyl acetate

OSHA Occupational Safety and Health Administration

PEL Permissible Exposure Limit

STEL Short Term Exposure Limit (STEL):

TLV Threshold Limit Value

TWA Time Weighted Average (TWA):

| Bar denotes a revision from prior MSDS.

The inform ation provided in this Safety Data Sheet is correct to the best of our knowledge, information

and belief at the date of its publication. The information given is designed only as a guidance for safe

handling, use, processing, storage, transportation, dispo sal and release and is not to be considered a

warranty or quality specification. The information relates only to the specific material designated and

may not be valid for such material used in combination with any other materials or in any process,

unless specified in the text.

Version: 2

. 2ROBOND TM CR

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Page 8 of 8 Revision date 02/15/2008 Print Date: 11/08/2012

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