# Patent

## Title
Optical device structure using GaN substrates and growth structure for laser applications

## Abstract

An optical device having a structured active region configured for one or more selected wavelengths of light emissions.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of U.S. application Ser. No. 12/762,278, filed Apr. 16, 2010; which claims priority to U.S. Application No. 61/170,550, filed Apr. 17, 2009; U.S. Application No. 61/170,553, filed Apr. 17, 2009; U.S. Application No. 61/177,217, filed May 11, 2009; U.S. application Ser. No. 12/534,829, filed Aug. 3, 2009; which claims priority to U.S. Application No. 61/243,502, filed Sep. 17, 2009; and U.S. application Ser. No. 12/759,273, filed Apr. 13, 2010, each of which is commonly assigned and hereby incorporated by reference.


BACKGROUND OF THE INVENTION
This invention is directed to optical devices and related methods. More particularly, the invention provides a method of manufacture and a device for emitting electromagnetic radiation using semipolar or non-polar gallium containing substrates such as GaN, MN, InN, InGaN, AlGaN, and AlInGaN, and others. Merely by way of example, the invention can be applied to optical devices, lasers, light emitting diodes, solar cells, photoelectrochemical water splitting and hydrogen generation, photodetectors, integrated circuits, and transistors, among other devices.
In 1960, the laser was first demonstrated by Theodore H. Maiman at Hughes Research Laboratories in Malibu. This laser utilized a solid-state flash lamp-pumped synthetic ruby crystal to produce red laser light at 694 nm. By 1964, blue and green laser output was demonstrated by William Bridges at Hughes Aircraft utilizing a gas Argon ion laser. The Ar-ion laser utilized a noble gas as the active medium and produced laser light output in the UV, blue, and green wavelengths including 351 nm, 454.6 nm, 457.9 nm, 465.8 nm, 476.5 nm, 488.0 nm, 496.5 nm, 501.7 nm, 514.5 nm, and 528.7 nm. The Ar-ion laser had the benefit of producing highly directional and focusable light with a narrow spectral output, but the wall plug efficiency was less than 0.1%. The size, weight, and cost of the laser was undesirable as well.
As laser technology evolved, more efficient lamp pumped solid state laser designs were developed for the red and infrared wavelengths, but these technologies remained a challenge for blue and green lasers. As a result, lamp pumped solid state lasers were developed in the infrared, and the output wavelength was converted to the visible using specialty crystals with nonlinear optical properties. A green lamp pumped solid state laser had 3 stages: electricity powers lamp, lamp excites gain crystal which lases at 1064 nm, 1064 nm goes into frequency conversion crystal which converts to visible 532 nm. The resulting green and blue lasers were called “lamped pumped solid state lasers with second harmonic generation” (LPSS with SHG). These had wall plug efficiency of  ̃1%, and were more efficient than Ar-ion gas lasers, but were still too inefficient, large, expensive, and fragile for broad deployment outside of specialty scientific and medical applications. Additionally, the gain crystal used in the solid state lasers typically had energy storage properties which made the lasers difficult to modulate at high speeds, limiting broader deployment.
To improve the efficiency of these visible lasers, high power diode (or semiconductor) lasers were utilized. These “diode pumped solid state lasers with SHG” (DPSS with SHG) had 3 stages: electricity powers 808 nm diode laser, 808 nm excites gain crystal which lases at 1064 nm, 1064 nm goes into frequency conversion crystal which converts to visible 532 nm. The DPSS laser technology extended the life and improved the wall plug efficiency of the LPSS lasers to 5-10%. This sparked further commercialization into specialty industrial, medical, and scientific applications. The change to diode pumping, however, increased the system cost and required precise temperature controls, leaving the laser with substantial size and power consumption. The result did not address the energy storage properties which made the lasers difficult to modulate at high speeds.
As high power laser diodes evolved and new specialty SHG crystals were developed, it became possible to directly convert the output of the infrared diode laser to produce blue and green laser light output. These “directly doubled diode lasers” or SHG diode lasers had 2 stages: electricity powers 1064 nm semiconductor laser, 1064 nm goes into frequency conversion crystal which converts to visible 532 nm green light. These lasers designs are intended to provide improved efficiency, cost and size compared to DPSS-SHG lasers, but the specialty diodes and crystals required make this challenging today. Additionally, while the diode-SHG lasers have the benefit of being directly modulated, they suffer from sensitivity to temperature which limits their application.
BRIEF SUMMARY OF THE INVENTION
The present invention provides a method and device for emitting electromagnetic radiation using semipolar gallium or non-polar containing substrates such as GaN, MN, InN, InGaN, AlGaN, and AlInGaN, and others. The invention can be applied to optical devices, lasers, light emitting diodes, solar cells, photoelectrochemical water splitting and hydrogen generation, photodetectors, integrated circuits, and transistors, among other devices.
In a specific embodiment, the present invention provides an optical device configured to emit electromagnetic radiation. The device includes a gallium nitride substrate member having a nonpolar crystalline surface region. The device includes an n-type GaN cladding layer overlying the surface region. The n-type GaN cladding layer has a thickness from 100 nm to 3000 nm and a Si doping level of 1E17 to 5E19 cm-3. The device also has an n-side SCH layer overlying the n-type GaN cladding layer. The n-side SCH layer is comprised of InGaN and having a molar fraction of indium of between 3% and 7% and a thickness from 20 to 150 nm. The device has a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 3.5-7.5 nm InGaN quantum wells separated by 1.5-7.5 nm GaN or InGaN barriers. The device has a p-type cladding layer overlying the multiple quantum well active region. The p-type cladding layer has a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 5E19 cm-3. The device has a p++-type contact layer overlying the p-type cladding layer. The p++-type contact layer has a thickness from 10 nm to 50 nm with Mg doping level of 5E19 cm-3 to 1E21 cm-3.
In an alternative embodiment, the present invention provides an optical device configured on a semipolar oriented substrate. The device has a gallium nitride substrate member having a semipolar crystalline surface region. The device has an n-GaN cladding layer overlying the surface region. The n-GaN cladding layer has a thickness from 100 nm to 3000 nm and a Si doping level of 1E17 to 5E19 cm-3. The device has an n-side SCH layer overlying the n-GaN cladding layer. The n-side SCH layer is comprised of InGaN and having a molar fraction of indium of between 3% and 8% and a thickness from 20 to 150 nm. The device has a multiple quantum well active region overlying the n-side SCH layer. The multiple quantum well active region comprises a plurality of 2.5-6.5 nm InGaN quantum wells separated by 2.5-8.0 nm GaN or InGaN barriers and a p-type cladding layer overlying the electron blocking layer. The p-type cladding layer has a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 5E19 cm-3. The device has a p++-type contact layer overlying the p-type cladding layer. The p++-type contact layer has a thickness from 10 nm to 50 nm with Mg doping level of 5E19 cm-3 to 1E21 cm-3.
The present invention enables a cost-effective optical device for laser applications. In a specific embodiment, the present optical device can be manufactured in a relatively simple and cost effective manner. The present laser device uses a semipolar or non-polar gallium nitride material to provide a green laser device capable of emitting wavelengths ranging from about 470 nm to greater than about 530 nm.
A further understanding of the nature and advantages of the present invention may be realized by reference to the latter portions of the specification and attached drawings.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1A is a perspective view of a laser device fabricated on a semipolar substrate.
FIG. 1B is a perspective view of a laser device fabricated on a non-polar substrate.
FIG. 2 is a cross-sectional view of a laser device fabricated on a non-polar substrate.
FIG. 3 is a diagram illustrating an epitaxial laser structure.
FIGS. 4 through 6 are diagrams illustrating a laser device.
FIGS. 7 through 8 are diagrams illustrating a laser device.
FIGS. 9 through 10 are diagrams illustrating a laser device.
FIGS. 11 through 13 are diagrams illustrating a laser device.



DETAILED DESCRIPTION OF THE INVENTION
The present invention provides a method and device for emitting electromagnetic radiation using semipolar or non-polar gallium containing substrates such as GaN, MN, InN, InGaN, AlGaN, and AlInGaN, and others. The invention can be applied to optical devices, lasers, light emitting diodes, solar cells, photoelectrochemical water splitting and hydrogen generation, photodetectors, integrated circuits, and transistors, among other devices. The present laser device can be employed in either a semipolar or non-polar gallium containing substrate, as described below.
In a specific embodiment, the invention provides an optical device. The optical device includes a gallium nitride substrate member having a nonpolar or semipolar crystalline surface region. The device also has an n-GaN cladding layer overlying the surface region. Preferably, the n-GaN cladding layer has a thickness from 100 nm to 3000 nm and a Si doping level of 5E17 to 3E18 cm-3. The device has an n-side SCH layer overlying the n-GaN cladding layer. Preferably, the n-side SCH layer is comprised of InGaN and has a molar fraction of indium of between 3% and 7% and a thickness from 40 to 60 nm. The device also has a multiple quantum well active region overlying the n-side SCH layer. The multiple quantum well active region is comprising seven 3.5-4.5 nm InGaN quantum wells separated by eight 9.5-10.5 nm GaN barriers. In a specific embodiment, the device has a p-side SCH layer overlying the multiple quantum well active region. The p-side SCH layer is comprised of InGaN with molar a fraction of indium of between 2% and 5% and a thickness from 15 nm to 25 nm according to a preferred embodiment. The device also has an electron blocking layer overlying the p-side SCH layer. Preferably, the electron blocking layer is comprised of AlGaN with molar fraction of aluminum of between 15% and 22% and a thickness from 10 nm to 15 nm and doped with Mg. The optical device has a p-GaN cladding layer overlying the electron blocking layer. Preferably, the p-GaN cladding layer has a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 1E19 cm-3. In a specific embodiment, the device has a p++-GaN contact layer overlying the p-GaN cladding layer. Preferably, the p++-GaN contact layer having a thickness from 20 nm to 40 nm with Mg doping level of 1E20 cm-3 to 1E21 cm-3.
FIG. 1A is a simplified perspective view of a laser device 100 fabricated on a semipolar substrate according to an embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. One of ordinary skill in the art would recognize other variations, modifications, and alternatives. As shown, the optical device includes a gallium nitride substrate member 101 having a semipolar or non-polar crystalline surface region. The gallium nitride substrate member is a bulk GaN substrate characterized by having a semipolar or non-polar crystalline surface region, but can be others. In a specific embodiment, the bulk nitride GaN substrate comprises nitrogen and has a surface dislocation density below 105 cm−2. The nitride crystal or wafer may comprise AlxInyGa1-x-yN, where 0≦x, y, x+y≦1. The nitride crystal preferably comprises GaN. Typically the GaN substrate has threading dislocations, at a concentration between about 105 cm−2 and about 108 cm−2, in a direction that is substantially orthogonal or oblique with respect to the surface. As a consequence of the orthogonal or oblique orientation of the dislocations, the surface dislocation density is below about 105 cm−2. In a specific embodiment, the device can be fabricated on a slightly off-cut semipolar substrate as described in U.S. Provisional No. 61/164,409 filed Mar. 28, 2009, commonly assigned, and hereby incorporated by reference herein.
On semipolar GaN, the device has a laser stripe region formed overlying a portion of the semi polar crystalline orientation surface region. In a specific semipolar GaN embodiment, the laser stripe region is characterized by a cavity orientation is substantially parallel to the m-direction. In a specific embodiment, the laser strip region has a first end 107 and a second end 109.
On nonpolar GaN, the device has a laser stripe region formed overlying a portion of the semi or non-polar crystalline orientation surface region, as illustrated by FIG. 1B, for example. In a specific embodiment, the laser stripe region is characterized by a cavity orientation is substantially parallel to the c-direction. The laser strip region has a first end and a second end. The non-polar crystalline orientation is configured on an m-plane, which leads to polarization ratios parallel to the a-direction. The more embodiments, the m-plane is the (10-10) family. Of course, there cavity orientation can also be substantially parallel to the a-direction as well. In the specific nonpolar GaN embodiment having the cavity orientation substantially parallel to the c-direction is further described in “Laser Device and Method Using Slightly Miscut Non-Polar GaN Substrates,” in the names of Raring, James W. and Pfister, Nick listed as U.S. Provisional Ser. No. 61/168,926 filed Apr. 13, 2009, commonly assigned, and hereby incorporated by reference for all purposes.
In a preferred semipolar embodiment, the device has a first cleaved m-face facet provided on the first end of the laser stripe region and a second cleaved m-face facet provided on the second end of the laser stripe region. In one or more embodiments, the first cleaved m-facet is substantially parallel with the second cleaved m-facet. In a specific embodiment, the semipolar substrate is configured on (11-22) series of planes, which enables the formation of m-facets for laser cavities oriented in the m-direction. Mirror surfaces are formed on each of the cleaved surfaces. The first cleaved m-facet comprises a first mirror surface. In a preferred embodiment, the first mirror surface is provided by a scribing and breaking process. The scribing process can use any suitable techniques, such as a diamond scribe or laser scribe or combinations. In a specific embodiment, the first mirror surface comprises a reflective coating. The reflective coating is selected from silicon dioxide, hafnia, and titaniatantalum pentoxidezirconia, including combinations, and the like. Depending upon the embodiment, the first mirror surface can also comprise an anti-reflective coating.
In a preferred nonpolar embodiment, the device has a first cleaved c-face facet provided on the first end of the laser stripe region and a second cleaved c-face facet provided on the second end of the laser stripe region. In one or more embodiments, the first cleaved c-facet is substantially parallel with the second cleaved c-facet. In a specific embodiment, the nonpolar substrate is configured on (10-10) series of planes, which enables the formation of c-facets for laser cavities oriented in the c-direction. Mirror surfaces are formed on each of the cleaved surfaces. The first cleaved c-facet comprises a first mirror surface. In a preferred embodiment, the first mirror surface is provided by a scribing and breaking process. The scribing process can use any suitable techniques, such as a diamond scribe or laser scribe or combinations. In a specific embodiment, the first mirror surface comprises a reflective coating. The reflective coating is selected from silicon dioxide, hafnia, and titaniatantalum pentoxidezirconia, including combinations, and the like. Depending upon the embodiment, the first mirror surface can also comprise an anti-reflective coating.
Also in a preferred semipolar embodiment, the second cleaved m-facet comprises a second mirror surface. The second mirror surface is provided by a scribing and breaking process according to a specific embodiment. Preferably, the scribing is diamond scribed or laser scribed or the like. In a specific embodiment, the second mirror surface comprises a reflective coating, such as silicon dioxide, hafnia, and titaniatantalum pentoxidezirconia, combinations, and the like. In a specific embodiment, the second mirror surface comprises an anti-reflective coating.
Also in a preferred nonpolar embodiment, the second cleaved c-facet comprises a second mirror surface. The second mirror surface is provided by a scribing and breaking process according to a specific embodiment. Preferably, the scribing is diamond scribed or laser scribed or the like. In a specific embodiment, the second mirror surface comprises a reflective coating, such as silicon dioxide, hafnia, and titaniatantalum pentoxidezirconia, combinations, and the like. In a specific embodiment, the second mirror surface comprises an anti-reflective coating.
The laser stripe has a length and width. The length ranges from about 50 microns to about 3000 microns. The strip also has a width ranging from about 0.5 microns to about 50 microns, but can be other dimensions. Preferably, the width is substantially constant in dimension, although there may be slight variations. The width and length are often formed using a masking and etching process, which are commonly used in the art.
In a semipolar embodiment, the device is also characterized by a spontaneously emitted light that is polarized in substantially parallel to the projection of the c-direction. That is, the device performs as a laser or the like. In a preferred embodiment, the spontaneously emitted light is characterized by a polarization ratio of greater than about 0.2 and less than about 1 parallel to the projection of the c-direction. In a preferred embodiment, the spontaneously emitted light characterized by a wavelength ranging from about 500 to about 580 nanometers to yield a green laser and others and the spontaneously emitted light is highly polarized and is characterized by a polarization ratio parallel to the projection of the c-direction of greater than 0.4.
In a nonpolar embodiment, the device is also characterized by a spontaneously emitted light that is polarized parallel to the a-direction. That is, the device performs as a laser or the like. In a preferred embodiment, the spontaneously emitted light is characterized by a polarization ratio of greater than about 0.1 and less than about 1 parallel to the projection of the c-direction. In a preferred embodiment, the spontaneously emitted light characterized by a wavelength ranging from about 475 to about 530 nanometers to yield a blue-green or green laser and others and the spontaneously emitted light is highly polarized and is characterized by a polarization ratio parallel to the a-direction of greater than 0.5.
FIG. 2 is a detailed cross-sectional view of a laser device 200 fabricated on a non-polar substrate according to an embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. One of ordinary skill in the art would recognize other variations, modifications, and alternatives. As shown, the laser device includes gallium nitride substrate 203, which has an underlying n-type metal back contact region 201. In a specific embodiment, the metal back contact region is made of a suitable material such as those noted below and others.
The device also has an overlying n-type gallium nitride layer 205, an active region 207, and an overlying p-type gallium nitride layer structured as a laser stripe region 209. In a specific embodiment, each of these regions is formed using at least an epitaxial deposition technique of metal organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), or other epitaxial growth techniques suitable for GaN growth. In a specific embodiment, the epitaxial layer is a high quality epitaxial layer overlying the n-type gallium nitride layer. In some embodiments the high quality layer is doped, for example, with Si or O to form n-type material, with a dopant concentration between about 1016 cm−3 and 1020 cm−3.
An n-type AluInvGa1-u-vN layer, where 0≦u, v, u+v≦1, is deposited on the substrate. In a specific embodiment, the carrier concentration may lie in the range between about 1016 cm−3 and 1020 cm−3. The deposition may be performed using metalorganic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE).
As an example, the bulk GaN substrate is placed on a susceptor in an MOCVD reactor. After closing, evacuating, and back-filling the reactor (or using a load lock configuration) to atmospheric pressure, the susceptor is heated to a temperature between about 1000 and about 1200 degrees Celsius in the presence of a nitrogen-containing gas. In one specific embodiment, the susceptor is heated to approximately 1100 degrees Celsius under flowing ammonia. A flow of a gallium-containing metalorganic precursor, such as trimethylgallium (TMG) or triethylgallium (TEG) is initiated, in a carrier gas, at a total rate between approximately 1 and 50 standard cubic centimeters per minute (sccm). The carrier gas may comprise hydrogen, helium, nitrogen, or argon. The ratio of the flow rate of the group V precursor (ammonia) to that of the group III precursor (trimethylgallium, triethylgallium, trimethylindium, trimethylaluminum) during growth is between about 2000 and about 12000. A flow of disilane in a carrier gas, with a total flow rate of between about 0.1 and 10 sccm, is initiated.
The laser stripe region is made of the p-type gallium nitride layer 209. In a specific embodiment, the laser stripe is preferably provided by dry etching, but wet etching can be used. As an example, the dry etching process is an inductively coupled process using chlorine bearing species or a reactive ion etching process using similar chemistries. The chlorine bearing species are commonly derived from chlorine gas or the like. The device also has an overlying dielectric region, which exposes 213 contact region. In a specific embodiment, the dielectric region is an oxide such as silicon dioxide or silicon nitride, but can be others. The contact region is coupled to an overlying metal layer 215. The overlying metal layer is a multilayered structure containing gold and platinum (Pt/Au), but can be others.
The laser device has active region 207 which can include one to twenty quantum well regions. Following deposition of the n-type AluInvGa1-u-vN layer for a predetermined period of time, so as to achieve a predetermined thickness, an active layer is deposited. The active layer may comprise a single quantum well or a multiple quantum well, with 1-20 quantum wells. The quantum wells may comprise InGaN wells and GaN barrier layers. In other embodiments, the well layers and barrier layers comprise AlwInxGa1-w-xN and AlyInzGa1-y-zN, respectively, where 0≦w, x, y, z, w+x, y+z≦1, where w<u, y and/or x>v, z so that the bandgap of the well layer(s) is less than that of the barrier layer(s) and the n-type layer. The well layers and barrier layers may each have a thickness between about 1 nm and about 40 nm. In another embodiment, the active layer comprises a double heterostructure, with an InGaN or AlwInxGa1-w-xN layer about 10 nm to 100 nm thick surrounded by GaN or AlyInzGa1-y-zN layers, where w<u, y and/or x>v, z. The composition and structure of the active layer are chosen to provide light emission at a preselected wavelength. The active layer may be left undoped (or unintentionally doped) or may be doped n-type or p-type.
The active region can also include an electron blocking region, and a separate confinement heterostructure. In some embodiments, an electron blocking layer is deposited. The electron-blocking layer may comprise AlsIntGa1-s-tN, where 0≦s, t, s+t≦1, with a higher bandgap than the active layer, and may be doped p-type. In one embodiment, the electron blocking layer comprises AlGaN. In another embodiment, the electron blocking layer comprises an AlGaN/GaN super-lattice structure, with alternating layers of AlGaN and GaN, each with a thickness between about 0.2 nm and about 5 nm.
As noted, the p-type gallium nitride structure, which can be a p-type doped AlqInrGa1-q-rN, where 0≦q, r, q+r≦1, layer is deposited above the active layer. The p-type layer may be doped with Mg, to a level between about 1016 cm−3 and 1022 cm−3, and may have a thickness between about 5 nm and about 1000 nm. The outermost 1-50 nm of the p-type layer may be doped more heavily than the rest of the layer, so as to enable an improved electrical contact. In a specific embodiment, the laser stripe is provided by an etching process selected from dry etching or wet etching. In a preferred embodiment, the etching process is dry, but can be others. The device also has an overlying dielectric region, which exposes 213 contact region. In a specific embodiment, the dielectric region is an oxide such as silicon dioxide.
In a specific embodiment, the metal contact is made of suitable material. The reflective electrical contact may comprise at least one of silver, gold, aluminum, nickel, platinum, rhodium, palladium, chromium, or the like. The electrical contact may be deposited by thermal evaporation, electron beam evaporation, electroplating, sputtering, or another suitable technique. In a preferred embodiment, the electrical contact serves as a p-type electrode for the optical device. In another embodiment, the electrical contact serves as an n-type electrode for the optical device.
FIG. 3 is a simplified diagram illustrating a laser structure according to a preferred embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. One of ordinary skill in the art would recognize other variations, modifications, and alternatives. In a specific embodiment, the device includes a starting material such as a bulk nonpolar or semipolar GaN substrate, but can be others. In a specific embodiment, the device is configured to achieve emission wavelength ranges of 390 nm to 530 nm.
In a preferred embodiment, the growth structure is configured using between 3 and 5 or 5 and 7 quantum wells positioned between n-type GaN and p-type GaN cladding layers. In a specific embodiment, the n-type GaN cladding layer ranges in thickness from 500 nm to 2000 nm and has an n-type dopant such as Si with a doping level of between 1E18 cm-3 and 3E18 cm-3. In a specific embodiment, the p-type GaN cladding layer ranges in thickness from 500 nm to 1000 nm and has a p-type dopant such as Mg with a doping level of between 1E17 cm-3 and 5E19 cm-3. In a specific embodiment, the Mg doping level is graded such that the concentration would be lower in the region closer to the quantum wells.
In a preferred embodiment, the quantum wells have a thickness of between 3 nm and 5.5 nm or 5.5 nm and 8 nm, but can be others. In a specific embodiment, the quantum wells would be separated by barrier layers with thicknesses between 4 nm and 8 nm or 8 nm and 12 nm. The quantum wells and the barriers together comprise a multiple quantum well (MQW) region.
Also in a preferred embodiment, the device has barrier layers formed from GaN or InGaN. In a specific embodiment using InGaN, the indium contents range from 1% to 5% (mole percent), but can be others. Of course, there can be other variations, modifications, and alternatives. Also, it should be noted that % of indium or aluminum is in a molar fraction, not weight percent.
An InGaN separate confinement hetereostructure layer (SCH) could be positioned between the n-type GaN cladding and the MQW region according to one or more embodiments. Typically, such separate confinement layer is commonly called the n-side SCH. The n-side SCH layer ranges in thickness from 10 nm to 50 nm or 50 nm to 100 nm and ranges in indium composition from 1% to 7% (mole percent), but can be others. In a specific embodiment, the n-side SCH layer may or may not be doped with an n-type dopant such as Si.
In yet another preferred embodiment, an InGaN separate confinement hetereostructure layer (SCH) is positioned between the p-type GaN cladding and the MQW region, which is called the p-side SCH. In a specific embodiment, the p-side SCH layer ranges in thickness from 10 nm to 50 nm or 50 nm to 100 nm and ranges in indium composition from 1% to 7% (mole percent), but can be others. The p-side SCH layer may or may not be doped with a p-type dopant such as Mg. In another embodiment, the structure would contain both an n-side SCH and a p-side SCH.
In another embodiment, an AlGaN electron blocking layer, with an aluminum content of between 14% and 22% (mole percent), is positioned between the MQW and the p-type GaN cladding layer either within the p-side SCH or between the p-side SCH and the p-type GaN cladding. The AlGaN electron blocking layer ranges in thickness from 10 nm to 20 nm and is doped with a p-type dopant such as Mg from 1E18 cm-3 and 1E20 cm-3 according to a specific embodiment. Preferably, a p-contact layer positioned on top of and is formed overlying the p-type cladding layer. The p-contact layer would be comprised of GaN doped with a p-dopant such as Mg at a level ranging from 1E20 cm-3 to 1E22 cm-3.
Embodiment A
In this embodiment, the laser device is capable of emitting 474 nm and also 485 nm or 470 nm to 490 nm wavelength light, among others. The device is provided with the following elements, as also referenced in FIGS. 4 through 6.
n-GaN cladding layer with a thickness from 100 nm to 3000 nm with Si doping level of 5E17 to 3E18 cm-3
n-side SCH layer comprised of InGaN with molar fraction of indium of between 3% and 5% and thickness from 45 to 65 nm.
Multiple quantum well active region layers comprised of five 4.5-5.5 nm InGaN quantum wells separated by six 4.5-5.5 nm GaN barriers
p-side SCH layer comprised of InGaN with molar fraction of indium of between 3% and 5% and thickness from 45 nm to 65 nm
Electron blocking layer comprised of AlGaN with molar fraction of aluminum of between 15% and 22% and thickness from 10 nm to 15 nm and doped with Mg
p-GaN cladding layer with a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 1E19 cm-3
p++-GaN contact layer with a thickness from 20 nm to 40 nm with Mg doping level of 1E20 cm-3 to 1E21 cm-3
The laser device is fabricated on a nonpolar oriented surface region. Preferably, the 474 nm configured laser device uses a nonpolar (10-10) substrate with a miscut or off cut of −0.3 to 0.3 degrees towards (0001) and −0.3 to 0.3 degrees towards (11-20). The n-GaN/p-GaN is grown using an N2 subflow and N2 carrier gas.
Embodiment B
In this embodiment, the invention provides a laser device capable of emitting 486 nm wavelength light, among others, in a ridge laser embodiment. The device is provided with the following elements, as also referenced in FIGS. 8 through 9.
n-GaN cladding layer with a thickness from 100 nm to 3000 nm with Si doping level of 5E17 to 3E18 cm-3
n-side SCH layer comprised of InGaN with molar fraction of indium of between 3% and 5% and thickness from 40 to 60 nm.
Multiple quantum well active region layers comprised of seven 4.5-5.5 nm InGaN quantum wells separated by eight 4.5-5.5 nm GaN barriers
p-side guide layer comprised of GaN with a thickness from 40 nm to 50 nm.
Electron blocking layer comprised of AlGaN with molar fraction of aluminum of between 15% and 22% and thickness from 10 nm to 15 nm and doped with Mg.
p-GaN cladding layer with a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 1E19 cm-3
p++-GaN contact layer with a thickness from 20 nm to 40 nm with Mg doping level of 1E20 cm-3 to 1E21 cm-3
The laser device is fabricated on a non-polar (10-10) oriented surface region (m-plane).
In a preferred embodiment, the non-polar substrate has a miscut or off cut of −0.8 to −1.2 degrees towards (0001) and −0.3 to 0.3 degrees towards (11-20). The non-polar oriented surface region has an overlying n-GaN/p-GaN grown with H2/N2 subflow and H2 carrier gas.
Embodiment C
In this embodiment, the invention provides an alternative device structure capable of emitting 481 nm light, among others, in a ridge laser embodiment. The device is provided with the following elements, as also referenced in FIGS. 9 through 10.
n-GaN cladding layer with a thickness from 100 nm to 3000 nm with Si doping level of 5E17 to 3E18 cm-3
n-side SCH layer comprised of InGaN with molar fraction of indium of between 4% and 6% and thickness from 45 to 60 nm
Multiple quantum well active region layers comprised of five 4.5-5.5 nm InGaN quantum wells separated by four 9.5-10.5 nm InGaN barriers with an indium molar fraction of between 1.5% and 3%
p-side guide layer comprised of GaN with molar a thickness from 10 nm to 20 nm.
Electron blocking layer comprised of AlGaN with molar fraction of aluminum of between 15% and 22% and thickness from 10 nm to 15 nm and doped with Mg.
p-GaN cladding layer with a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 1E19 cm-3
p++-GaN contact layer with a thickness from 20 nm to 40 nm with Mg doping level of 1E20 cm-3 to 1E21 cm-3
The laser device is fabricated on a non-polar oriented surface region (m-plane). In a preferred embodiment, the non-polar substrate has a miscut or off cut of −0.8 to −1.2 degrees towards (0001) and −0.3 to 0.3 degrees towards (11-20). The non-polar oriented surface region has an overlying n-GaN/p-GaN grown with H2/N2 subflow and H2 carrier gas.
Embodiment D
In this embodiment, the invention provides an alternative device structure capable of emitting 501 nm light in a ridge laser embodiment. The device is provided with the following elements, as also referenced in FIGS. 11 through 12.
n-GaN cladding layer with a thickness from 100 nm to 3000 nm with Si doping level of 5E17 to 3E18 cm-3
n-side SCH layer comprised of InGaN with molar fraction of indium of between 3% and 7% and thickness from 40 to 60 nm
Multiple quantum well active region layers comprised of seven 3.5-4.5 nm InGaN quantum wells separated by eight 9.5-10.5 nm GaN barriers p-side SCH layer comprised of InGaN with molar a fraction of indium of between 2% and 5% and a thickness from 15 nm to 25 nm.
Electron blocking layer comprised of AlGaN with molar fraction of aluminum of between 15% and 22% and thickness from 10 nm to 15 nm and doped with Mg.
p-GaN cladding layer with a thickness from 400 nm to 1000 nm with Mg doping level of 5E17 cm-3 to 1E19 cm-3
p++-GaN contact layer with a thickness from 20 nm to 40 nm with Mg doping level of 1E20 cm-3 to 1E21 cm-3
In a specific embodiment, the laser device is fabricated on a non-polar (10-10) oriented surface region (m-plane). In a preferred embodiment, the non-polar substrate has a miscut or off cut of −0.8 to −1.2 degrees towards (0001) and −0.3 to 0.3 degrees towards (11-20). The non-polar oriented surface region has an overlying n-GaN/p-GaN grown with H2/N2 subflow and H2 carrier gas. The laser device configured for a 500 nm laser uses well regions and barriers fabricated using slow growth rates of between 0.3 and 0.6 angstroms per second, but can be others. In a specific embodiment, the slow growth rate is believed to maintain the quality of the InGaN at longer wavelengths.
In a specific embodiment, the present structure and method may have variations. That is, the gallium nitride substrate material is characterized by the nonpolar crystalline surface region is characterized by an m-plane or others. The gallium nitrogen substrate material characterized by the nonpolar crystalline surface region is characterized by an m-plane having an offcut surface orientation. In other examples, the non-polar crystalline surface region is characterized by an off cut of −0.8 to −1.2 degrees towards (0001) and −0.3 to 0.3 degrees towards (11-20). In a specific embodiment, the device has a p-side SCH region overlying the multiple quantum well region, where p-side SCH region is comprised of InGaN with 0 to 7% molar fraction of InN and ranging in thickness from 5 to 70 nm. The device also has an electron blocking layer region overlying the multiple quantum well active region, where the electron blocking layer is comprised of AlGaN or AlInGaN with 5 to 30% molar fraction of AlN and ranging in thickness from 5 to 30 nm. A p-type cladding layer is comprised of p-type GaN or other suitable materials. The multiple quantum well region comprises 3-5 quantum wells. Each of the barriers is comprised of GaN and range in thickness ranges from 2.5 nm to 4.0 nm. Each of the barriers is comprised of InGaN with an InN molar fraction of 1 to 5% and each of the barriers is characterized by a thickness ranging from 2 nm to 4.5 nm.
In an alternative specific embodiment, the present device is configured on the semipolar crystalline surface region oriented in a {20-21} plane or {30-31} plane. The plane is offcut within +/−5 degree towards a c-plane. In other embodiments, the semipolar crystalline surface region is oriented in a {20-2-1} plane or {30-3-1} plane. The plane is offcut within +/−5 degree towards a c-plane.
While the above is a full description of the specific embodiments, various modifications, alternative constructions and equivalents may be used. Therefore, the above description and illustrations should not be taken as limiting the scope of the present invention which is defined by the appended claims.

## Claims

1. An optical device configured to emit electromagnetic radiation of more than about 500 nm wavelength comprising:
a gallium nitride substrate having a nonpolar crystalline surface region;
an n-GaN cladding layer overlying the surface region, the n-GaN cladding layer having a thickness between 100 nm and 3000 nm and a Si doping level between 1E17 to 5E19 cm-3;
an n-side SCH layer overlying the n-GaN cladding layer, the n-side SCH layer comprised of InGaN and having a molar fraction of indium between 3% and 7%, and a thickness between 20 and 150 nm;
a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 3.5-7.5 nm InGaN quantum wells separated by 1.5-7.5 nm GaN or InGaN barriers;
a p-type cladding layer overlying the multiple quantum well active region, the p-type cladding layer having a thickness between 400 nm and 1000 nm with a Mg doping level between 5E17 cm-3 to 5E19 cm-3;
a p++-type contact layer overlying the p-type cladding layer, the p++-type contact layer having a thickness between 10 nm and 50 nm with a Mg doping level between 5E19 cm-3 and 1E21 cm-3; and
a p-side SCH region overlying the multiple quantum well region, where the p-side SCH region is comprised of InGaN with 0 to 7% molar fraction of InN and has a thickness between 5 nm and 70 nm.

2. The device of claim 1, wherein the nonpolar crystalline surface region is characterized by an m-plane.

3. The device of claim 2, wherein the nonpolar crystalline surface region has an offcut surface orientation.

4. The device of claim 3, wherein the non-polar crystalline surface region is characterized by an off cut of −0.8 to −1.2 degrees towards (0001) plane and −0.3 to 0.3 degrees towards (11-20) plane.

5. An optical device configured to emit electromagnetic radiation of more than about 500 nm wavelength comprising:
a gallium nitride substrate having a nonpolar crystalline surface region;
an n-GaN cladding layer overlying the surface region, the n-GaN cladding layer having a thickness between 100 nm and 3000 nm and a Si doping level between 1E17 to 5E19 cm-3;
an n-side SCH layer overlying the n-GaN cladding layer, the n-side SCH layer comprised of InGaN and having a molar fraction of indium between 3% and 7%, and a thickness between 20 and 150 nm;
a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 3.5-7.5 nm InGaN quantum wells separated by 1.5-7.5 nm GaN or InGaN barriers;
a p-type cladding layer overlying the multiple quantum well active region, the p-type cladding layer having a thickness between 400 nm and 1000 nm with a Mg doping level between 5E17 cm-3 to 5E19 cm-3;
a p++-type contact layer overlying the p-type cladding layer, the p++-type contact layer having a thickness between 10 nm and 50 nm with a Mg doping level between 5E19 cm-3 and 1E21 cm-3; and
an electron blocking layer region overlying the multiple quantum well active region, where the electron blocking layer is comprised of AlGaN or AlInGaN with between 5 and 30% molar fraction of AlN, and having a thickness between 5 nm and 30 nm.

6. The device of claim 5, wherein the nonpolar crystalline surface region is characterized by an m-plane.

7. The device of claim 6, wherein the nonpolar crystalline surface region has an offcut surface orientation.

8. The device of claim 7, wherein the non-polar crystalline surface region is characterized by an off cut of −0.8 to −1.2 degrees towards (0001) plane and −0.3 to 0.3 degrees towards (11-20) plane.

9. An optical device configured to emit electromagnetic radiation of more than about 500 nm wavelength comprising:
a gallium nitride substrate having a nonpolar crystalline surface region;
an n-GaN cladding layer overlying the surface region, the n-GaN cladding layer having a thickness between 100 nm and 3000 nm and a Si doping level between 1E17 to 5E19 cm-3;
an n-side SCH layer overlying the n-GaN cladding layer, the n-side SCH layer comprised of InGaN and having a molar fraction of indium between 3% and 7%, and a thickness between 20 and 150 nm;
a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 3.5-7.5 nm InGaN quantum wells separated by 1.5-7.5 nm GaN or InGaN barriers;
a p-type cladding layer overlying the multiple quantum well active region, the p-type cladding layer having a thickness between 400 nm and 1000 nm with a Mg doping level between 5E17 cm-3 to 5E19 cm-3; and
a p++-type contact layer overlying the p-type cladding layer, the p++-type contact layer having a thickness between 10 nm and 50 nm with a Mg doping level between 5E19 cm-3 and 1E21 cm-3.
wherein each of the barriers is comprised of InGaN with an InN molar fraction of 1 to 5% and each of the barriers is characterized by a thickness between 2 nm and 4.5 nm.

10. The device of claim 9, wherein the nonpolar crystalline surface region is characterized by an m-plane.

11. The device of claim 10, wherein the nonpolar crystalline surface region has an offcut surface orientation.

12. The device of claim 11, wherein the non-polar crystalline surface region is characterized by an off cut of −0.8 to −1.2 degrees towards (0001) plane and −0.3 to 0.3 degrees towards (11-20) plane.

13. An optical device comprising:
a gallium nitride substrate having a semipolar crystalline surface region;
an n-GaN cladding layer overlying the surface region, the n-GaN cladding layer having a thickness from 100 nm to 3000 nm and a Si doping level of 1E17 to 5E19 cm-3;
an n-side SCH layer overlying the n-GaN cladding layer, the n-side SCH layer comprised of InGaN and having a molar fraction of indium between 3% and 8%, and a thickness between 20 and 150 nm;
a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 2.5-6.5 nm InGaN quantum wells separated by 2.5-8.0 nm GaN or InGaN barriers;
a p-type cladding layer overlying the electron blocking layer, the p-type cladding layer having a thickness between 400 nm and 1000 nm with a Mg doping level between 5E17 cm-3 and 5E19 cm-3;
a p++-type contact layer overlying the p-type cladding layer, the p++-type contact layer having a thickness from 10 nm to 50 nm with Mg doping level of 5E19 cm-3 to 1E21 cm-3; and
a p-side SCH region overlying the multiple quantum well region, wherein the p-side SCH region is comprised of InGaN with 0 to 7% molar fraction of InN and ranging in thickness from 5 to 70 nm.

14. The optical device of claim 13, wherein the semipolar crystalline surface region is oriented in a {20-21} plane or {30-31} plane.

15. The optical device of claim 14, wherein the plane is offcut within +/−5 degree towards a c-plane.

16. The optical device of claim 13, wherein the semipolar crystalline surface region is oriented in a {20-2-1} plane or {30-3-1} plane.

17. An optical device comprising:
a gallium nitride substrate having a semipolar crystalline surface region;
an n-GaN cladding layer overlying the surface region, the n-GaN cladding layer having a thickness from 100 nm to 3000 nm and a Si doping level of 1E17 to 5E19 cm-3;
an n-side SCH layer overlying the n-GaN cladding layer, the n-side SCH layer comprised of InGaN and having a molar fraction of indium between 3% and 8%, and a thickness between 20 and 150 nm;
a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 2.5-6.5 nm InGaN quantum wells separated by 2.5-8.0 nm GaN or InGaN barriers;
a p-type cladding layer overlying the electron blocking layer, the p-type cladding layer having a thickness between 400 nm and 1000 nm with a Mg doping level between 5E17 cm-3 and 5E19 cm-3;
a p++-type contact layer overlying the p-type cladding layer, the p++-type contact layer having a thickness from 10 nm to 50 nm with Mg doping level of 5E19 cm-3 to 1E21 cm-3; and
an electron blocking region overlying the multiple quantum well region, wherein the electron blocking layer is comprised of AlGaN or AlInGaN with 5 to 30% molar fraction of AlN and ranging in thickness between 5 nm and 30 nm.

18. The optical device of claim 17, wherein the semipolar crystalline surface region is oriented in a {20-21} plane or {30-31} plane.

19. The optical device of claim 18, wherein the plane is offcut within +/−5 degree towards a c-plane.

20. The optical device of claim 17, wherein the semipolar crystalline surface region is oriented in a {20-2-1} plane or {30-3-1} plane.

21. An optical device comprising:
a gallium nitride substrate having a semipolar crystalline surface region;
an n-GaN cladding layer overlying the surface region, the n-GaN cladding layer having a thickness from 100 nm to 3000 nm and a Si doping level of 1E17 to 5E19 cm-3;
an n-side SCH layer overlying the n-GaN cladding layer, the n-side SCH layer comprised of InGaN and having a molar fraction of indium between 3% and 8%, and a thickness between 20 and 150 nm;
a multiple quantum well active region overlying the n-side SCH layer, the multiple quantum well active region comprising a plurality of 2.5-6.5 nm InGaN quantum wells separated by 2.5-8.0 nm GaN or InGaN barriers;
a p-type cladding layer overlying the electron blocking layer, the p-type cladding layer having a thickness between 400 nm and 1000 nm with a Mg doping level between 5E17 cm-3 and 5E19 cm-3; and
a p++-type contact layer overlying the p-type cladding layer, the p++-type contact layer having a thickness from 10 nm to 50 nm with Mg doping level of 5E19 cm-3 to 1E21 cm-3;
wherein each of the barriers is comprised of InGaN with an InN molar fraction of 1 to 5% and range in thickness ranges from 2 nm to 4.5 nm.

22. The optical device of claim 21, wherein the semipolar crystalline surface region is oriented in a {20-21} plane or {30-31} plane.

23. The optical device of claim 22, wherein the plane is offcut within +/−5 degree towards a c-plane.

24. The optical device of claim 21, wherein the semipolar crystalline surface region is oriented in a {20-2-1} plane or {30-3-1} plane.