file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542 Focus Ready Draft 8/27/2009 ENGINEER: Jon \ AH PV (kg/yr):
SUBMITTER: USE: Fragrance for scented paper, detergents, candles etc. (10%); food flavors and frangrance material in cosmetics (90%; FFDCA use). STN file CA 7 references found; mostly as a flavor component in melons. OTHER USES: None found. MSDS: Yes Label: No Gen Eqpt: chemical resistant gloves, splash -proof safety glasses or goggles, safety shower, eye wash Respirator: usually not required, avoid inhalation concentrated vapors Health Effects: may be irritating to skin and eyes TLV/PEL: not established

CRSS : Chemical Name: 3-Nonen-1-ol, 1-acetate, (3Z)- S-H20: 0.0286 g/L @ VP: 6.0E-2 torr @ MW: 184.00 %<500 %<1000 Physical State and Misc CRSS Info: Neat: Liquid Mfg: Liquid Proc/Form: Solution, 0.01-0.2% in formulation End Use: Solid / Solution. Submitted data: odor of the flesh of a pear, ws = insoluble, soluble in alcohol, flash point = 91°C, d = 0.882-0.888 g/cc. A printout from EPI suite is provided. Estimated data (EPI with mp entered as 20°C): bp = 235°C at 760 torr, vp = 0.0602 torr, ws = 28.6 mg/L, log P = 4. 09. ACDLabs (Prop database): bp = 237°C, vp = 0.0458 torr, ws = 0.31 g/L, log P = 4.01. Consumer Use: Yes SAT (concerns) (08/14/2009): Migration to groundwater: Negligible PBT rating: P1B1T1 Health: 1-2 Dermal, Inhalation Eco: 3 Water (All releases to water with a CC = 9ppb) OCCUPATIONAL EXPOSURE RATING: 1-2Cfile:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] NOTES & KEY ASSUMPTIONS: Generated by the 06/07/2005 version of ChemSTEER. This PMN is a fragrance ingredient for candles, scented paper, detergents (10%; TSCA use) as well as food flavors and cosmetics (90%; FFDCA use). This IRER assesses 100% of the PV for MFG and only considers the TSCA uses (10% PV) for PROC and USE. The submitter was contacted but was unable to provide all information on end uses, see contact report. This IRER assesses the three TSCA uses (candle, scented paper, detergent) separately. No assessments are made after the PMN is incorporated into "articles" such as candles and scented papers. However, CEB considers the commercial use of detergents containing PMN. The 1991 Scenario on the Mfg of Granular Detergents, the 2008 ESD on the Blending of Fragrance Oil into Commercial and Consumer Products, and the 2006 ESD on Institutaion and Industrial Laundries were referenced to fill data gaps. Same submitter similar use past cases were also referenced for consistency: P05-0667, P05-0736, and P02-0974. P05-0667 assessed incineration release during MFG (consistent with this IRER), P02-0974 assessed water release and P05-0736 was imported. All past cases were non-volatile liquids (this PMN is a volatile liquid). P05-0667 assessed separate PROC and USE operations for the uses of PMN in candles and detergents but did not address the use in scented paper; other past cases only provide a single, general assessment for all uses (this IRER provide separate assessments for each of the three uses). POLLUTION PREVENTION CONSIDERATIONS: None.
EXPOSURE-BASED REVIEW: No INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542 Manufacturing Number of Sites/ Location: Days/yr: Basis: Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium. Submitter does not provide release estimates from MFG;file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Air Output 2: 3.2E-2 kg/site-day over 5 days/yr from to: from: basis: Air Typical: 1.3E-6 kg/site-day over 5 days/yr from Worst Case: 2.7E-6 kg/site-day over 5 days/yr from to: from: basis Incineration Conservative: 1.8E-1 kg/site-day over 5 days/yr from or 9.0E-1 kg/yr to: from: basis:

RELEASE TOTAL 1.1E+0 kg/yr - all sites
OCCUPATIONAL EXPOSURES ESTIMATE SUMMARYfile:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542 Processing 1: Number of Sites/ Location: Days/yr: Basis:
Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium.

Water or Incineration or Landfill Conservative: 7.2E-5 kg/site-day over 250 days/yr from or 9.0E-2 kg/yr to: from: basis:
Air Typical: 1.1E-9 kg/site-day over 250 days/yr from Worst Case: 2.1E-9 kg/site-day over 250 days/yr from to: from: basis: Air Output 2: 6.7E-10 kg/site-day over 250 days/yr from to: from: basis:file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Air Output 2: 3.2E-4 kg/site-day over 250 days/yr from to: from: basis: Air Typical: 1.1E-9 kg/site-day over 250 days/yr from Worst Case: 2.1E-9 kg/site-day over 250 days/yr from to: from: basis RELEASE TOTAL 4.9E-1 kg/yr - all sites
OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Processing 2-1: Number of Sites/ Location: Days/yr: Basis:
Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium.

Water or Incineration or Landfill High End: 6.2E-2 kg/site-day over 1 day/yr from or 6.2E-2 kg/yr to: from: basis: Water or Incineration or Landfill Conservative: 1.2E-4 kg/site-day over 250 days/yr from or 3.0E-2 kg/yr to: from: basis:
Air Typical: 1.8E-9 kg/site-day over 250 days/yr from Worst Case: 3.6E-9 kg/site-day over 250 days/yr from to: from: basis: Air Output 2: 6.1E-11 kg/site-day over 250 days/yr from to: from: basis:file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Air Output 2: 1.6E-5 kg/site-day over 250 days/yr from to: from: basis: RELEASE TOTAL 9.6E-2 kg/yr - all sites
OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542 Processing 2-2: Number of Sites/ Location: Days/yr: Basis:file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium. Water or Air or Incineration or Landfill Output 2: 7.0E-4 kg/site-day over 7 days/yr from or 9.8E-3 kg/yr to: from: basis:

Water or Incineration or Landfill Conservative: 6.0E-5 kg/site-day over 250 days/yr from or 3.0E-2 kg/yr to: from: basis:
Air Typical: 8.9E-10 kg/site-day over 250 days/yr from Worst Case: 1.8E-9 kg/site-day over 250 days/yr from to: from: basis: Air Output 2: 3.0E-11 kg/site-day over 250 days/yr from to: from: basis: Air Output 2: 1.6E-5 kg/site-day over 250 days/yr from to: from: basis: RELEASE TOTAL 4.8E-2 kg/yr - all sitesfile:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] OCCUPATIONAL EXPOSURES ESTIMATE SUMMARYfile:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542 Processing 2-3: Number of Sites/ Location: Days/yr: Basis:
Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium.

Water or Incineration or Landfill High End: 6.2E-2 kg/site-day over 1 day/yr from or 6.2E-2 kg/yr to: from: basis: Water or Incineration or Landfill Conservative: 1.2E-4 kg/site-day over 250 days/yr from or 3.0E-2 kg/yr to: from: basis:
Air Typical: 1.8E-9 kg/site-day over 250 days/yr from Worst Case: 3.6E-9 kg/site-day over 250 days/yr from to: from: basis:file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Air Output 2: 6.1E-11 kg/site-day over 250 days/yr from to: from: basis: Air Output 2: 1.6E-5 kg/site-day over 250 days/yr from to: from: basis: RELEASE TOTAL 9.6E-2 kg/yr - all sites
OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

INITIAL REVIEW ENGINEERING REPORT CBI: PMN: 09-0542 Use 2-2:file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] Number of Sites/ Location: Days/yr: Basis:

Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources to the same medium. Water Output 2: 5.8E-3 kg/site-day over 250 days/yr from to: POTW (GS) from: basis:

Water or Air or Incineration or Landfill Output 2: 5.2E-4 kg/site-day over 14 days/yr from or 7.3E-3 kg/yr to: ) from: basis:

Incineration or Landfill Output 2: 1.0E-3 kg/site-day over 14 days/yr from or 1.5E-2 kg/yr to: from: basis:

RELEASE TOTAL 1.5E+0 kg/yr - all sites
OCCUPATIONAL EXPOSURES ESTIMATE SUMMARYfile:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM] MEMORANDUM of TELEPHONE CONVERSATION CALL BY: Ariel Hou Organization: ERG CALL TO: Organization Date: 08/17/2009 Time: 11AM Phone: Concerning ? PMN: 09-0542file:///J|/SNURS/SNUR%20Batch%20FY10-3/reports%20for%20sanitization/CBI%20engineering%20reports/p090542.eng.txt[4/23/2010 12:28:23 PM]