**Instructions for using the Emission Test Reporting Template for the Primary Aluminum Test Program**

This Information Collection Request (ICR) spreadsheet is intended to be used to report emissions data from primary aluminum reduction facilities as an alternative to the Electronic Reporting Tool (ERT), as well as in cases where the test methods arenot currently supported by the ERT.**Data for multiple process units should be reported by using separate copies of the appropriate tabs of this spreadsheet.**  **Please Do Not delete rows or columns , addition of rows and columns is appropriate**  **as necessary.**
**Emission Data Worksheets** The emission data worksheets are provided for each test required for this testing program, although all facilities are not required to conduct all of the tests. On each worksheet,please enter process unit operating informationduring sampling and emission test results. The emission test results to be entered depends on the constituent. **Source Operating Information** 1. Please provide the Exhaust Flow Rate (acfm and dscfm) and the Exhaust Temperature (deg F). 2. Please provide the values of all requested parametersfor each of the sample testing periods in the appropriate cells. 3. Please provide any other supporting informationor commentsin the Other Supporting Informationfield.

### Page 1 of 8 

# Primary Aluminum Testing: Dioxins and Furans

**Parent company**

**name:** Alcoa 

### Facility **address:** Alcoa Massena Operations

East Plant 

### Description of source tested: Line 3 Downcomer Massena, New York 13662

**lb/hr lb/ton** 

**Throughput a**  1 4/30/2013 1002 4/30/2013 1418 2.93E-08 5.74E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 7.81E-08 1.53E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 2.41E-08 4.72E-09 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 1.54E-07 3.01E-08 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 3.98E-07 7.80E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 1.02E-07 2.00E-08 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 1.21E-08 2.37E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 8.31E-08 1.63E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 6.08E-09 1.19E-09 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 [<8.58E-09] [<1.68E-09] 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.64E-08 3.22E-09 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 [<8.08E-09] [<1.57E-09] 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 4.63E-08 9.06E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 3.98E-08 7.80E-09 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 2.84E-08 5.56E-09 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 [8.78E-09] [<1.72E-09] 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.64E-08 3.22E-09 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 [<7.45E-09 [<1.46E-09] 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 4.56E-08 8.93E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 7.93E-08 1.55E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 2.35E-08 4.60E-09 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 9.63E-09 1.89E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.62E-08 3.17E-09 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 [<8.93E-09] [<1.75E-09] 5.11 Aluminum **Calculated Emission Rate Throughput**  **Ma terial** 

1,2,3,7,8,9- HxCDD 1,2,3,6,7,8- HxCDD
1,2,3,6,7,8- HxCDF 1,2,3,4,7,8- HxCDD
1,2,3,4,7,8- HxCDF 1,2,3,4,6,7,8- HpCDF
1,2,3,4,7,8,9- HpCDF 1,2,3,4,6,7,8- HpCDD **Throughput (ton/hr)**  **Compound Run** 

**Number Test Start** 

**Date Test Start** 

**Time Test End** 

**Date Test End** 

**Time**

### Page 2 of 8

**lb/hr lb/ton** 

**Throughput a**  **Calculated Emission Rate Throughput**  **Ma terial**  **Throughput (ton/hr)**  **Compound Run** 

**Number Test Start** 

**Date Test Start** 

**Time Test End** 

**Date Test End** 

**Time**

1 4/30/2013 1002 4/30/2013 1418 [<5.74E-09] [<1.12E-09] 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 [<6.4E-09] [<1.25E-09] 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 [<6.12E-09] [<1.20E-09] 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 1.24E-08 2.43E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.47E-08 2.87E-09 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 [<8.78E-09] [<1.72E-09] 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 4.36E-08 8.53E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 6.90E-08 1.35E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 2.08E-08 4.08E-09 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 4.42E-08 8.67E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 6.68E-08 1.31E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 2.17E-08 4.24E-09 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 8.75E-08 1.71E-08 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.30E-07 2.54E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 5.11E-08 1.00E-08 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 7.50E-09 1.47E-09 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 5.93E-09 1.16E-09 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 [<6.30E-09] [<1.23E-09] 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 7.70E-08 1.51E-08 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 9.78E-08 1.92E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 5.11E-08 1.00E-08 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 8.07E-08 1.58E-08 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.50E-07 2.94E-08 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 6.98E-08 1.37E-08 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 1.60E-07 3.13E-08 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 1.37E-06 2.69E-07 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 1.07E-07 2.10E-08 5.11 Aluminum

aNote that lb/ton results based on total Line 3 potroom flow rate bEMPC = Estimated Maximum Possible Concentration. EMPC occurs when there is possible co-eluting interference or signal to noise ratio is not sufficient for peak identification OCDF OCDD 2,3,7,8- TCDD

2,3,7,8-TCDF 2,3,4,6,7,8- HxCDF
2,3,4,7,8- PeCDF 1,2,3,7,8- PeCDD
1,2,3,7,8- PeCDF 1,2,3,7,8,9- HxCDF

### Page 3 of 8 

# Primary Aluminum Testing: Dioxins and Furans

**Parent company**

**name:** Alcoa 

### Facility **address:** Alcoa Massena Operations

East Plant 

### Description of source tested: Line 3 Downcomer Massena, New York 13662

**Me asured**  **Value (n g)**  **Wet or Dry**

**Basis Test Method** 

**(e.g.,CA RB 429)**  **Data Flag**

**(A DL, BDL, DLL)**  **Front Half**

**Ma****ss* (ng)** **Back Half**

**Ma ss**  (ng)** **Impinger Soln**

**Ma ss** * (ng)** ADL 1 ADL ADL 2 ADL EMPCb 3 ADL/EMPC ADL 1 ADL ADL 2 ADL ADL 3 ADL ADL/EMPC 1 ADL/EMPC ADL 2 ADL ADL 3 ADL BDL 1 BDL ADL 2 ADL BDL 3 BDL ADL 1 ADL ADL 2 ADL ADL 3 ADL BDL 1 BDL ADL 2 ADL BDL 3 BDL ADL 1 ADL ADL 2 ADL ADL/EMPC 3 ADL/EMPC ADL 1 ADL ADL/EMPC 2 ADL/EMPC BDL 3 BDL**Separate A nalysis** 

1,2,3,7,8,9- HxCDD 1,2,3,6,7,8- HxCDD
1,2,3,6,7,8- HxCDF 1,2,3,4,7,8- HxCDD
1,2,3,4,7,8- HxCDF 1,2,3,4,6,7,8- HpCDF
1,2,3,4,7,8,9- HpCDF 1,2,3,4,6,7,8- HpCDD **Test Method Comments Compound**  **Run Number**  **Dioxins and Furans Emission Test Results**

### Page 4 of 8

**Me asured**  **Value (n g)**  **Wet or Dry**

**Basis Test Method** 

**(e.g.,CA RB 429)**  **Data Flag**

**(A DL, BDL, DLL)**  **Front Half**

**Ma****ss* (ng)** **Back Half**

**Ma ss**  (ng)** **Impinger Soln**

**Ma ss** * (ng)** **Separate A nalysis**  **Test Method Comments Compound**  **Run Number**  **Dioxins and Furans Emission Test Results**

BDL 1 BDL BDL 2 BDL BDL 3 BDL ADL 1 ADL ADL 2 ADL BDL 3 BDL ADL 1 ADL ADL 2 ADL ADL/EMPC 3 ADL/EMPC ADL 1 ADL ADL 2 ADL ADL 3 ADL ADL 1 ADL ADL 2 ADL ADL 3 ADL ADL/EMPC 1 ADL/EMPC ADL/EMPC 2 ADL/EMPC BDL 3 BDL ADL 1 ADL ADL 2 ADL ADL 3 ADL ADL/EMPC 1 ADL/EMPC ADL 2 ADL ADL 3 ADL ADL 1 ADL ADL 2 ADL ADL 3 ADL * Front Half Composite contains particulate filter, front half of the filter holder, and probe solvent rinses ** Back Half Composite contains XAD-2 resin tube, back half of the filter holder, and coil condenser solvent rinses OCDF OCDD 2,3,7,8- TCDD

2,3,7,8-TCDF 2,3,4,6,7,8- HxCDF
2,3,4,7,8- PeCDF 1,2,3,7,8- PeCDD
1,2,3,7,8- PeCDF 1,2,3,7,8,9- HxCDF

### Page 5 of 8 

# Primary Aluminum Testing: Dioxins and Furans

Alcoa Massena Operations 

### Parent company **name:** Alcoa 

### Facility **address:**

Massena, New York 13662 

### Description of source tested: Line 3 Downcomer

**Composite A nalysis** 
**Total (ng) Total (ng)**  **Moisture (%)**  **CO 2** **(%) O** **2 (%)**  **Flow (acfm)**  **Flow**

**(dscfm) Temperature** 

**( °F)**  0.0087 1 8.6 0.0 20.9 NA 3837511 77 0.0249 2 7.1 0.0 20.9 NA 3648875 91 0.0067 3 6.7 0.0 20.9 NA 4143142 94 0.0455 1 8.6 0.0 20.9 NA 3837511 77 0.1270 2 7.1 0.0 20.9 NA 3648875 91 0.0283 3 6.7 0.0 20.9 NA 4143142 94 0.0036 1 8.6 0.0 20.9 NA 3837511 77 0.0265 2 7.1 0.0 20.9 NA 3648875 91 0.0017 3 6.7 0.0 20.9 NA 4143142 94 0.0025 1 8.6 0.0 20.9 NA 3837511 77 0.0038 2 7.1 0.0 20.9 NA 3648875 91 0.0022 3 6.7 0.0 20.9 NA 4143142 94 0.0137 1 8.6 0.0 20.9 NA 3837511 77 0.0320 2 7.1 0.0 20.9 NA 3648875 91 0.0079 3 6.7 0.0 20.9 NA 4143142 94 0.0026 1 8.6 0.0 20.9 NA 3837511 77 0.0052 2 7.1 0.0 20.9 NA 3648875 91 0.0021 3 6.7 0.0 20.9 NA 4143142 94 0.0135 1 8.6 0.0 20.9 NA 3837511 77 0.0253 2 7.1 0.0 20.9 NA 3648875 91 0.0065 3 6.7 0.0 20.9 NA 4143142 94 0.0029 1 8.6 0.0 20.9 NA 3837511 77 0.0052 2 7.1 0.0 20.9 NA 3648875 91 0.0025 3 6.7 0.0 20.9 NA 4143142 94 1,2,3,7,8,9- HxCDD 1,2,3,6,7,8- HxCDD
1,2,3,6,7,8- HxCDF 1,2,3,4,7,8- HxCDD
1,2,3,4,7,8- HxCDF 1,2,3,4,6,7,8- HpCDF
1,2,3,4,7,8,9- HpCDF **Compound Run** 

**Number Exhaust Gas** 

1,2,3,4,6,7,8- HpCDD

### Page 6 of 8

**Composite A nalysis** 
**Total (ng) Total (ng)**  **Moisture (%)**  **CO 2** **(%) O** **2 (%)**  **Flow (acfm)**  **Flow**

**(dscfm) Temperature** 

**( °F)**  **Compound Run** 

**Number Exhaust Gas** 

0.0017 1 8.6 0.0 20.9 NA 3837511 77 0.0020 2 7.1 0.0 20.9 NA 3648875 91 0.0017 3 6.7 0.0 20.9 NA 4143142 94 0.0037 1 8.6 0.0 20.9 NA 3837511 77 0.0047 2 7.1 0.0 20.9 NA 3648875 91 0.0024 3 6.7 0.0 20.9 NA 4143142 94 0.0129 1 8.6 0.0 20.9 NA 3837511 77 0.0220 2 7.1 0.0 20.9 NA 3648875 91 0.0058 3 6.7 0.0 20.9 NA 4143142 94 0.0131 1 8.6 0.0 20.9 NA 3837511 77 0.0213 2 7.1 0.0 20.9 NA 3648875 91 0.0060 3 6.7 0.0 20.9 NA 4143142 94 0.0259 1 8.6 0.0 20.9 NA 3837511 77 0.0414 2 7.1 0.0 20.9 NA 3648875 91 0.0142 3 6.7 0.0 20.9 NA 4143142 94 0.0022 1 8.6 0.0 20.9 NA 3837511 77 0.0019 2 7.1 0.0 20.9 NA 3648875 91 0.0018 3 6.7 0.0 20.9 NA 4143142 94 0.0228 1 8.6 0.0 20.9 NA 3837511 77 0.0312 2 7.1 0.0 20.9 NA 3648875 91 0.0142 3 6.7 0.0 20.9 NA 4143142 94 0.0239 1 8.6 0.0 20.9 NA 3837511 77 0.0479 2 7.1 0.0 20.9 NA 3648875 91 0.0194 3 6.7 0.0 20.9 NA 4143142 94 0.0473 1 8.6 0.0 20.9 NA 3837511 77 0.4380 2 7.1 0.0 20.9 NA 3648875 91 0.0298 3 6.7 0.0 20.9 NA 4143142 94 OCDF OCDD 2,3,7,8-TCDD

2,3,7,8-TCDF 2,3,4,6,7,8- HxCDF

2,3,4,7,8-PeCDF 1,2,3,7,8-PeCDD

1,2,3,7,8-PeCDF 1,2,3,7,8,9- HxCDF

### Page 7 of 8

Alcoa Massena Operations East Plant Massena, New York 13662

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom **Other Supporting Information**

### Page 8 of 8

**Other Supporting Information**

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

### Page 1 of 8 

# Primary Aluminum Testing: Polycyclic Aromatic Hydrocarbons

**Parent company**

**name:** Alcoa 

### Facility **address:** Alcoa Massena Operations

East Plant 

### Description of source tested: Line 3 Downcomer Massena, New York 13662

**lb/hr lb/ton** 

**Throughput** 1 4/30/2013 1002 4/30/2013 1418 0.13376 0.02619 5.11 2 4/30/2013 1455 4/30/2013 1911 0.14830 0.02904 5.11 3 5/1/2013 825 5/1/2013 1230 0.15085 0.02954 5.11 1 4/30/2013 1002 4/30/2013 1418 0.01246 0.00244 5.11 2 4/30/2013 1455 4/30/2013 1911 0.01304 0.00255 5.11 3 5/1/2013 825 5/1/2013 1230 0.00900 0.00176 5.11 1 4/30/2013 1002 4/30/2013 1418 0.02131 0.00417 5.11 2 4/30/2013 1455 4/30/2013 1911 0.02527 0.00495 5.11 3 5/1/2013 825 5/1/2013 1230 0.02200 0.00431 5.11 1 4/30/2013 1002 4/30/2013 1418 0.03547 0.00695 5.11 2 4/30/2013 1455 4/30/2013 1911 0.05361 0.01050 5.11 3 5/1/2013 825 5/1/2013 1230 0.02031 0.00398 5.11 1 4/30/2013 1002 4/30/2013 1418 0.02388 0.00468 5.11 2 4/30/2013 1455 4/30/2013 1911 0.02289 0.00448 5.11 3 5/1/2013 825 5/1/2013 1230 0.00806 0.00158 5.11 1 4/30/2013 1002 4/30/2013 1418 0.08613 0.01687 5.11 2 4/30/2013 1455 4/30/2013 1911 0.07807 0.01529 5.11 3 5/1/2013 825 5/1/2013 1230 0.04968 0.00973 5.11 1 4/30/2013 1002 4/30/2013 1418 0.14794 0.02897 5.11 2 4/30/2013 1455 4/30/2013 1911 0.14861 0.02910 5.11 3 5/1/2013 825 5/1/2013 1230 0.10081 0.01974 5.11 1 4/30/2013 1002 4/30/2013 1418 0.03138 0.00615 5.11 2 4/30/2013 1455 4/30/2013 1911 0.03126 0.00612 5.11 3 5/1/2013 825 5/1/2013 1230 0.01991 0.00390 5.11 **Compound Run**  **Number Test Start** 

**Date Test Start** 

**Time Test End** 

**Date Test End** 

**Time**

Acenaphthene (83-32-9) **Calculated Emission Rate Throughput**  **(ton/hr)**

Acenaphthylene (208-96-8)

Anthracene (120-12-7)

Benz[a]anthracene (56-55-3)

Benzo[a]pyrene (50-32-8)

Benzo(e)pyrene (192-97-2)

Benzo[b]fluoranthene (205-99-2)

Benzo[g,h,i]perylene (191-24-2)

### Page 2 of 8

**lb/hr lb/ton** 

**Throughput Compound**  **Run Number**  **Test Start**

**Date Test Start** 

**Time Test End** 

**Date Test End** 

**Time Calculated Emission Rate**  **Throughput (ton/hr)** 

1 4/30/2013 1002 4/30/2013 1418 0.06451 0.01263 5.11 2 4/30/2013 1455 4/30/2013 1911 0.05173 0.01013 5.11 3 5/1/2013 825 5/1/2013 1230 0.03550 0.00695 5.11 1 4/30/2013 1002 4/30/2013 1418 0.11619 0.02275 5.11 2 4/30/2013 1455 4/30/2013 1911 0.11883 0.02327 5.11 3 5/1/2013 825 5/1/2013 1230 0.08857 0.01734 5.11 1 4/30/2013 1002 4/30/2013 1418 0.00730 0.00143 5.11 2 4/30/2013 1455 4/30/2013 1911 0.00875 0.00171 5.11 3 5/1/2013 825 5/1/2013 1230 0.00432 0.00085 5.11 1 4/30/2013 1002 4/30/2013 1418 0.29893 0.05854 5.11 2 4/30/2013 1455 4/30/2013 1911 0.29033 0.05686 5.11 3 5/1/2013 825 5/1/2013 1230 0.30207 0.05916 5.11 1 4/30/2013 1002 4/30/2013 1418 0.02567 0.00503 5.11 2 4/30/2013 1455 4/30/2013 1911 0.02712 0.00531 5.11 3 5/1/2013 825 5/1/2013 1230 0.02668 0.00522 5.11 1 4/30/2013 1002 4/30/2013 1418 0.02621 0.00513 5.11 2 4/30/2013 1455 4/30/2013 1911 0.02499 0.00489 5.11 3 5/1/2013 825 5/1/2013 1230 0.01588 0.00311 5.11 1 4/30/2013 1002 4/30/2013 1418 0.10167 0.01991 5.11 2 4/30/2013 1455 4/30/2013 1911 0.10284 0.02014 5.11 3 5/1/2013 825 5/1/2013 1230 0.09577 0.01875 5.11 1 4/30/2013 1002 4/30/2013 1418 0.06316 0.01237 5.11 2 4/30/2013 1455 4/30/2013 1911 0.07619 0.01492 5.11 3 5/1/2013 825 5/1/2013 1230 0.06625 0.01297 5.11 1 4/30/2013 1002 4/30/2013 1418 0.19186 0.03757 5.11 2 4/30/2013 1455 4/30/2013 1911 0.21728 0.04255 5.11 3 5/1/2013 825 5/1/2013 1230 0.20342 0.03984 5.11 1 4/30/2013 1002 4/30/2013 1418 0.00513 0.00101 5.11 2 4/30/2013 1455 4/30/2013 1911 0.00593 0.00116 5.11 3 5/1/2013 825 5/1/2013 1230 0.00188 0.00037 5.11 1 4/30/2013 1002 4/30/2013 1418 0.07093 0.01389 5.11 2 4/30/2013 1455 4/30/2013 1911 0.06929 0.01357 5.11 3 5/1/2013 825 5/1/2013 1230 0.07237 0.01417 5.11 Benzo[k]fluoranthene (207-08-9)

Chrysene (218-01-9)

Dibenz[a,h]anthracene (53-70-3)

Fluoranthene (206-44-0)

Fluorene (86-73-7)

Indeno (1,2,3-cd) pyrene (193-39-5)

Naphthalene (91-20-3)

2-Methylnaphthalene (91-57-6)

Phenanthrene (85-01-8)

Perylene (198-55-0)

Pyrene (129-00-0)

### Page 3 of 8



# Primary Aluminum Testing: Polycyclic Aromatic Hydrocarbons

Alcoa Massena Operations 

### Parent company **name:** Alcoa 

### Facility **address:** Alcoa Massena Operations

East Plant Massena, New York 13662 

### Description of source tested: Line 3 Downcomer Massena, New York 13662

**Me asured**  **Value (n g)**  **Wet or Dry**

**Basis Test Method** 

**(e.g.,CA RB 429)**  **Data Flag**

**(A DL, BDL, DLL)**  **Front Half**

**Ma****ss* (ng)** **Back Half**

**Ma ss**  (ng)** **Condensate**

**Ma ss** * (ng)** **Total (ng)**
Aluminum 1 CARB 429 ADL 39600 Aluminum 2 CARB 429 ADL 47300 Aluminum 3 CARB 429 ADL 41900 Aluminum 1 CARB 429 ADL 3690 Aluminum 2 CARB 429 ADL 4160 Aluminum 3 CARB 429 ADL 2500 Aluminum 1 CARB 429 ADL 6310 Aluminum 2 CARB 429 ADL 8060 Aluminum 3 CARB 429 ADL 6110 Aluminum 1 CARB 429 ADL 10500 Aluminum 2 CARB 429 ADL 17100 Aluminum 3 CARB 429 ADL 5640 Aluminum 1 CARB 429 ADL 7070 Aluminum 2 CARB 429 ADL 7300 Aluminum 3 CARB 429 ADL 2240 Aluminum 1 CARB 429 ADL 25500 Aluminum 2 CARB 429 ADL 24900 Aluminum 3 CARB 429 ADL 13800 Aluminum 1 CARB 429 ADL 43800 Aluminum 2 CARB 429 ADL 47400 Aluminum 3 CARB 429 ADL 28000 Aluminum 1 CARB 429 ADL 9290 Aluminum 2 CARB 429 ADL 9970 Aluminum 3 CARB 429 ADL 5530 **Compound Run** 

**Number Polycyclic A** **romatic Hydrocarbons Emission Test Results**

Ace naphthene **Throughput Ma** **terial**

Ace

naphthylene

Anthracene

Benz[a] anthracene
Benzo[a] pyrene Benzo(e) pyrene Benzo[b] fluoranthene
Benzo[g,h,i]per ylene

### Page 4 of 8

**Me asured**  **Value (n g)**  **Wet or Dry**

**Basis Test Method** 

**(e.g.,CA RB 429)**  **Data Flag**

**(A DL, BDL, DLL)**  **Front Half**

**Ma****ss* (ng)** **Back Half**

**Ma ss**  (ng)** **Condensate**

**Ma ss** * (ng)** **Total (ng) Compound**  **Run**

**Number Polycyclic A** **romatic Hydrocarbons Emission Test Results Throughput**  **Ma terial** 

Aluminum 1 CARB 429 ADL 19100 Aluminum 2 CARB 429 ADL 16500 Aluminum 3 CARB 429 ADL 9860 Aluminum 1 CARB 429 ADL 34400 Aluminum 2 CARB 429 ADL 37900 Aluminum 3 CARB 429 ADL 24600 Aluminum 1 CARB 429 ADL 2160 Aluminum 2 CARB 429 ADL 2790 Aluminum 3 CARB 429 ADL 1200 Aluminum 1 CARB 429 ADL 88500 Aluminum 2 CARB 429 ADL 92600 Aluminum 3 CARB 429 ADL 83900 Aluminum 1 CARB 429 ADL 7600 Aluminum 2 CARB 429 ADL 8650 Aluminum 3 CARB 429 ADL 7410 Aluminum 1 CARB 429 ADL 7760 Aluminum 2 CARB 429 ADL 7970 Aluminum 3 CARB 429 ADL 4410 Aluminum 1 CARB 429 ADL 30100 Aluminum 2 CARB 429 ADL 32800 Aluminum 3 CARB 429 ADL 26600 Aluminum 1 CARB 429 ADL 18700 Aluminum 2 CARB 429 ADL 24300 Aluminum 3 CARB 429 ADL 18400 Aluminum 1 CARB 429 ADL 56800 Aluminum 2 CARB 429 ADL 69300 Aluminum 3 CARB 429 ADL 56500 Aluminum 1 CARB 429 ADL 1520 Aluminum 2 CARB 429 ADL 1890 Aluminum 3 CARB 429 ADL 521 Aluminum 1 CARB 429 ADL 21000 Aluminum 2 CARB 429 ADL 22100 Aluminum 3 CARB 429 ADL 20100 * Contains particulate filter, front half of filter holder and probe solvent rinses *** Contains condensate, impinger contents and glassware solvent rinses ** Contains XAD-2 resin tube, back half of filter holder and coil condenser solvent rinses E-The reported concentration exceeds The calibration range (upper point of calibration curve) Benzo[k] fluoranthene

Chrysene
Dibenz[a,h] anthracene

Fluoranthene

Fluorene

Indeno (1,2,3- cd) pyrene

Naphthalene

2-Methyl naphthalene

Phenan threne

Perylene

Pyrene

### Page 5 of 8



# Primary Aluminum Testing: Polycyclic Aromatic Hydrocarbons

Alcoa Massena Operations 

### Parent company **name:** Alcoa 

### Facility **address:**

Massena, New York 13662 

### Description of source tested: Line 3 Downcomer

**Test Method Comments**  **Moisture (%)**  **CO 2** **(%) O** **2 (%)**  **Flow (acfm)**  **Flow**

**(dscfm) Temperature** 

**( °F)**  E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 **Compound Run** 

**Number Exhaust Gas** 

Acenaphthene

Acenaphthylene

Anthracene

Benz[a] anthracene

Benzo[a]pyrene

Benzo(e)pyrene
Benzo[b] fluoranthene
Benzo[g,h,i] perylene

### Page 6 of 8

**Test Method Comments**  **Moisture (%)**  **CO 2** **(%) O** **2 (%)**  **Flow (acfm)**  **Flow**

**(dscfm) Temperature** 

**( °F)**  **Compound Run** 

**Number Exhaust Gas** 

E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 E 1 8.6 0 20.9NA 3837511 77 E 2 7.1 0 20.9NA 3648875 91 E 3 6.7 0 20.9NA 4143142 94 *** Contains condensate, impinger contents and glassware solvent rinses E-The reported concentration exceeds The calibration range (upper point of calibration curve) Benzo[k] fluoranthene

Chrysene
Dibenz[a,h] anthracene

Fluoranthene

Fluorene

Indeno (1,2,3-cd) pyrene

Naphthalene

2-Methyl naphthalene

Phenanthrene

Perylene

Pyrene

### Page 7 of 8

Alcoa Massena Operations East Plant Massena, New York 13662

**Other Supporting Information**

### Page 8 of 8

**Other Supporting Information**Page 1 of 6 

## Primary Aluminum Testing: Polychlorinate Biphenyls (PCB)
**Parent company**

**name:** Alcoa 

### Facility **address:** Alcoa Massena Operations

East Plant 

### Description of source tested: Downcomer Line 3 Exhaust Massena, New York 13662

**lb/hr lb/ton** 

**Throughput** 1 4/30/2013 1002 4/30/2013 1418 0.000041208 0.000008070 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000036056 0.000007061 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000030279 0.000005930 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000078701 0.000015412 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000065842 0.000012894 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000084968 0.000016640 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000162807 0.000031883 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000121337 0.000023762 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000167056 0.000032715 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000093563 0.000018323 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000071172 0.000013938 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000096129 0.000018825 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000049315 0.000009658 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000041700 0.000008166 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000048605 0.000009518 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000016247 0.000003182 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000014830 0.000002904 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000016202 0.000003173 5.11 Aluminum **Compound Run** 

**Number Test Start** 

**Date Test Start** 

**Time Test End** 

**Date Test End** 

**Time Calculated Emission Rate**  **Throughput (ton/hr)**  **Throughput**

**Material Test Method Comments** 

Monochlorinated biphenyls

Dichlorinated biphenyls

Trichlorinated biphenyls

Tetrachlorinated biphenyls

Pentachlorinated biphenyls

Hexachlorinated biphenylsPage 2 of 6

**lb/hr lb/ton** 

**Throughput Compound**  **Run**

**Number Test Start** 

**Date Test Start** 

**Time Test End** 

**Date Test End** 

**Time Calculated Emission Rate**  **Throughput (ton/hr)**  **Throughput**

**Material Test Method Comments** 

1 4/30/2013 1002 4/30/2013 1418 0.000003614 0.000000708 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000003700 0.000000725 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000003514 0.000000688 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000000591 0.000000116 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000000793 0.000000155 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000000698 0.000000137 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000000147 0.000000029 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000000201 0.000000039 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000000127 0.000000025 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.00000013 0.00000003 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.00000092 0.00000018 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.00000008 0.00000002 5.11 Aluminum Heptachlorinated biphenyls

Octachlorinated biphenyls

Nonachlorinated biphenyls

Decachlorinated biphenylsaPage 3 of 6

**Composite Analy**  **sis Total (ng)**  **Total (ng) Moisture**  **(% )**  **CO 2** **(% )**  **O 2** **(% )**  **Flow (acfm)**  **Flow**

**(dscfm) Temperature** 

**( °F)**  12.2 8.6 0 20.9 NA 3837511 77 11.5 7.1 0 20.9 NA 3648875 91 8.41 6.7 0 20.9 NA 4143142 94 23.3 8.6 0 20.9 NA 3837511 77 21 7.1 0 20.9 NA 3648875 91 23.6 6.7 0 20.9 NA 4143142 94 48.2 8.6 0 20.9 NA 3837511 77 38.7 7.1 0 20.9 NA 3648875 91 46.4 6.7 0 20.9 NA 4143142 94 27.7 8.6 0 20.9 NA 3837511 77 22.7 7.1 0 20.9 NA 3648875 91 26.7 6.7 0 20.9 NA 4143142 94 14.6 8.6 0 20.9 NA 3837511 77 13.3 7.1 0 20.9 NA 3648875 91 13.5 6.7 0 20.9 NA 4143142 94 4.81 8.6 0 20.9 NA 3837511 77 4.73 7.1 0 20.9 NA 3648875 91 4.5 6.7 0 20.9 NA 4143142 94 **Poly chlorinated Bipheny** **ls Emission Test Results**
**Compound Exhaust Gas**  **Separate Analy**

**sis**

Monochlorinated biphenyls Monochlorinated biphenyls

Dichlorinated biphenyls Dichlorinated biphenyls

Trichlorinated biphenyls Trichlorinated biphenyls

Tetrachlorinated biphenyls Tetrachlorinated biphenyls

Pentachlorinated biphenyls Pentachlorinated biphenyls

Hexachlorinated biphenyls Hexachlorinated biphenylsPage 4 of 6

**Composite Analy**  **sis Total (ng)**  **Total (ng) Moisture**  **(% )**  **CO 2** **(% )**  **O 2** **(% )**  **Flow (acfm)**  **Flow**

**(dscfm) Temperature** 

**( °F)**  **Poly chlorinated Bipheny** **ls Emission Test Results**
**Compound Exhaust Gas**  **Separate Analy**

**sis**

1.07 8.6 0 20.9 NA 3837511 77 1.18 7.1 0 20.9 NA 3648875 91 0.976 6.7 0 20.9 NA 4143142 94 0.175 8.6 0 20.9 NA 3837511 77 0.253 7.1 0 20.9 NA 3648875 91 0.194 6.7 0 20.9 NA 4143142 94 0.0434 8.6 0 20.9 NA 3837511 77 0.0641 7.1 0 20.9 NA 3648875 91 0.0353 6.7 0 20.9 NA 4143142 94 0.039 8.6 0 20.9 NA 3837511 77 0.292 7.1 0 20.9 NA 3648875 91 0.0227 6.7 0 20.9 NA 4143142 94 Heptachlorinated biphenyls Heptachlorinated biphenyls

Octachlorinated biphenyls Octachlorinated biphenyls

Nonachlorinated biphenyls Nonachlorinated biphenyls

Decachlorinated biphenylsa Decachlorinated biphenylsPage 5 of 6

**Other Supporting Information**Page 6 of 6

**Other Supporting Information**