Summary of Results
Compound Sample ID / Catch Weight (ug)

CTM-033-R2-C3-NaOH CTM-033-R3-C3-NaOH CTM-033-R4-C3-NaOH

Hydrogen cyanide 64.8 ND 61.2 ND 71.0 ND

CTM-033-BT-C3-NaOH

Hydrogen cyanide 44.7 ND

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KHB

EPA CTM-033

3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

0410-10

100-208-0001

5/14/2010

0410-10-hcn-res 5/17/2010
Compound Sample ID / Catch Weight (ug)

M26A-R1-C3-H2SO4 M26A-R2-C3-H2SO4 M26A-R3-C3-H2SO4

Hydrogen fluoride 311 ND 337 ND 288 ND

Hydrogen chloride 304 ND 329 ND 281 ND

M26A-BT-C3-H2SO4

Hydrogen fluoride 113 ND

Hydrogen chloride 150 J

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

ARM

EPA Method 26A

3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

0410-10

100-208-0001

5/14/2010

0410-10-m26a-res 5/17/2010
Compound Sample ID / Catch Weight (ug)

M8A-R1-C1-SO3 M8A-R2-C1-SO3 M8A-R3-C1-SO3

Sulfuric Acid 117 J 81.3 J 87.6 J

M8A-BT-C1-SO3

Sulfuric Acid 18.1 ND

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KHB

NCASI Method 8A

3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

0410-10

100-208-0001

5/14/2010

0410-10-m8a-res 5/17/2010
Compound Sample ID / Catch Weight (ug)

Run 1 Run 2 Run 3

Sulfate 7,137 7,482 6,634 

Train Blk

Sulfate 4.76 ND

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KHB

HPLC/IC Sulfate Analysis

3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

0410-10

100-208-0001

5/14/2010

0410-10-sulfate-res 5/17/2010
Compound Sample ID / Catch Weight (mg)

Run 1 Run 2 Run 3

47 mm Filter 2.0 0.7 2.5

>2.5 PM 0.8 2.7 0.9

< 2.5 PM 0.2 0.7 0.1

TOTAL 3.0 4.1 3.4

Blank Train

47 mm Filter 0.3

>2.5 PM 0.1

< 2.5 PM 0.1

TOTAL 0.4

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KTH

EPA OTM-027

4 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

100-208-0001

0410-10

5/17/2010

0410-10-ctm027-res 5/17/2010
Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Run 1 Run 2 Run 3

Net Organic Catch 6.1 4.8 7.4

Corrected Inorganic 19.2 17.1 11.0

TB Corrected CPM 23.3 19.9 16.4

Train Blank

Organic Catch 2.9 If Train Blank Corrected CPM is >2.0 mg,

Inorganic Catch 1.9 then sample correction is 2.0 mg.

CPM 4.7

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KTH

EPA OTM-028

3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

0410-10

100-208-0001

5/14/2010

0410-10-OTM028-res 5/17/2010
Results
MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL)

LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

DF 

CTM-033-R2-C3-NaOH 028-3701.D 028-3702.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 CTM-033-R3-C3-NaOH 029-3801.D 029-3802.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 CTM-033-R4-C3-NaOH 030-3901.D 030-3902.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 CTM-033-BT-C3-NaOH 031-4001.D 031-4002.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 

0.1N NaOH - RB 007-0801.D 007-0802.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 1 

LD/CTM-033-R2-C3-NaOH 050-7601.D 050-7602.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 

d

MS/CTM-033-R2-C3-NaOH 051-9301.D 051-9302.D HPLC50PG78.M 8.01 8.03 0.3 1.15 1.16 0.4 1.15 1 

Spike Am

Native Am

Spike Rec

MSD/CTM-033-R2-C3-NaOH 052-9401.D 052-9402.D HPLC50PG78.M 8.05 8.06 0.1 1.12 1.13 0.2 1.13 1 

Spike Am

Native Am

Spike Rec

hplc50pg78 #LCS 006-0701.D 006-0702.D HPLC50PG78.M 8.29 8.26 0.3 0.916 0.900 0.9 0.908 1 

Spike Am

Spike Rec

Hydrogen cyanide

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.KHBEPA CTM-0333 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-2080410-10100-208-00015/14/2010

0410-10-hcn-res 
MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

CF

F --

HF

M26A-R1-C3-H2SO4 011-0901.D 011-0902.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.05M26A-R2-C3-H2SO4 014-1201.D 014-1202.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.05M26A-R3-C3-H2SO4 015-1301.D 015-1302.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.05M26A-BT-C3-H2SO4 016-1401.D 016-1402.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.05

Reagent Blank 007-0801.D 007-0802.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.05

HPLC51p92 #LCS 006-0701.D 006-0702.D HPLC51PG92.M 2.78 2.78 0.0 4.07 4.07 0.0 4.07 1.00

S

Sp

MS M26A-R1-C3-H2SO4 012-1001.D 012-1002.D HPLC51PG92.M 2.78 2.78 0.0 3.57 3.55 0.2 3.56 1.00

S

N

Sp

MSD M26A-R1-C3-H2SO4 013-1101.D 013-1102.D HPLC51PG92.M 2.78 2.78 0.0 3.53 3.53 0.1 3.53 1.00

S

N

Sp

HF as Fluoride

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.ARM

EPA Method 26A3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-2080410-10100-208-00015/14/2010

0410-10-m26a-res 
MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

CF

Cl --

HC

M26A-R1-C3-H2SO4 011-0901.D 011-0902.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.02M26A-R2-C3-H2SO4 014-1201.D 014-1202.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.02M26A-R3-C3-H2SO4 015-1301.D 015-1302.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.02M26A-BT-C3-H2SO4 016-1401.D 016-1402.D HPLC51PG92.M 3.72 3.72 0.1 0.0279 0.0267 2.2 0.0273 1.02

Reagent Blank 007-0801.D 007-0802.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.02

HPLC51p92 #LCS 006-0701.D 006-0702.D HPLC51PG92.M 3.73 3.73 0.0 3.76 3.76 0.1 3.76 1.00

S

Sp

MS M26A-R1-C3-H2SO4 012-1001.D 012-1002.D HPLC51PG92.M 3.73 3.73 0.0 2.91 2.91 0.0 2.91 1.00

S

N

Sp

MSD M26A-R1-C3-H2SO4 013-1101.D 013-1102.D HPLC51PG92.M 3.73 3.73 0.0 2.90 2.90 0.0 2.90 1.00

S

N

Sp

HCl as Chloride

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.ARM

EPA Method 26A3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-2080410-10100-208-00015/14/2010

0410-10-m26a-res 
MDL 0.0118 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

CF S

----->

H2SO

M8A-R1-C1-SO3 013-1401.D 013-1402.D HPLC53PG44.M 9.56 9.57 0.1 0.0945 0.0919 1.4 0.0932 1.021 M8A-R2-C1-SO3 014-1501.D 014-1502.D HPLC53PG44.M 9.59 9.59 0.1 0.0526 0.0536 1.0 0.0531 1.021 M8A-R3-C1-SO3 015-1601.D 015-1602.D HPLC53PG44.M 9.60 9.60 0.0 0.0645 0.0635 0.8 0.0640 1.021 M8A-BT-C1-SO3 016-1701.D 016-1702.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 1.021 

RB/DI H2O 007-0801.D 007-0802.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 1.021 

hplc53pg44 #LCS 006-0701.D 006-0702.D HPLC53PG44.M 9.49 9.49 0.0 6.26 6.08 1.5 6.17 1.000 

S

MS/M8A-R1-C1-SO3 024-3302.D 025-3401.D HPLC53PG44.M 9.51 9.51 0.0 2.81 2.88 1.3 2.85 1.000 

S

MSD/M8A-R1-C1-SO3 025-3402.D 026-3501.D HPLC53PG44.M 9.51 9.51 0.0 3.08 2.93 2.5 3.00 1.000 

S

H2SO4 as Sulfate

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.KHBNCASI Method 8A3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-2080410-10100-208-00015/14/2010

0410-10-m8a-res 
MDL 0.0118 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Run 1 031-5701.D 031-5702.D HPLC53PG44.M 9.67 9.67 0.0 6.79 7.39 4.3 7.09 Run 2 032-4301.D 032-4302.D HPLC53PG44.M 9.65 9.65 0.0 7.60 7.27 2.2 7.43 Run 3 033-4401.D 033-4402.D HPLC53PG44.M 9.66 9.67 0.1 6.82 6.36 3.5 6.59 

Train Blk 034-4501.D 034-4502.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 

IHB 035-4601.D 035-4602.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 

RB/DI H2O 007-0801.D 007-0802.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 

hplc53pg44 #LCS 006-0701.D 006-0702.D HPLC53PG44.M 9.49 9.49 0.0 6.26 6.08 1.5 6.17 

Sp

Spik

MS/Run 1 036-5801.D 036-5802.D HPLC53PG44.M 9.66 9.66 0.0 12.0 10.8 5.1 11.4 

Sp

Nat

Spik

MSD/Run 1 037-5901.D 037-5902.D HPLC53PG44.M 9.66 9.66 0.0 11.8 10.8 4.4 11.3 

Sp

Nat

Spik

Sulfate

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.KHBHPLC/IC Sulfate Analysis3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-2080410-10100-208-00015/14/2010

0410-10-sulfate-res 
Other Test Method 027 - Particulate Determination - Data Analysis

Analysis of Particulate Recovery

Sample ID Run 1 Run 2 Run 3 Blank Train

47 mm Filter ID 2420 Dates 2421 Dates 2422 Dates 2423 Dates

Final wt. (g) 1st 0.115233 5/11/10 9A 0.112507 5/11/10 9A 0.115278 5/11/10 9A 0.112585 5/11/10 9A

Final wt. (g) 2nd 0.115144 5/11/10 4P 0.112464 5/11/10 4P 0.115274 5/11/10 4P 0.112599 5/11/10 4P

Final Tare Weight (g) 0.113114 4/14/10 0.111768 4/14/10 0.112817 4/14/10 0.112308 4/14/10

Net filter catch (mg) 2.0 0.7 2.5 0.3

>2.5 PM Acetone Rinses

Beaker number 11422 Dates 11423 Dates 11424 Dates 11425 Dates

Final wt (g) 1st 1.904289 5/11/10 9A 1.910792 5/11/10 9A 1.909630 5/11/10 9A 1.908709 5/11/10 9A

Final wt (g) 2nd 1.904353 5/11/10 4P 1.910808 5/11/10 4P 1.909641 5/11/10 4P 1.908728 5/11/10 4P

 Beaker tare (g) 1.903529 5/5/10 1.908136 5/5/10 1.908790 5/5/10 1.908673 5/5/10

Acetone vol (mL) 34.0 35.0 20.0 20.0

>2.5 PM Catch (mg) 0.8 2.7 0.9 0.1

<2.5 PM Acetone Rinses

Beaker number 11426 Dates 11429 Dates 11430 Dates 11431 Dates

Final wt (g) 1st 1.913072 5/11/10 9A 1.910419 5/11/10 9A 1.897631 5/11/10 9A 1.895270 5/11/10 9A

Final wt (g) 2nd 1.913073 5/11/10 4P 1.910422 5/11/10 4P 1.897642 5/11/10 4P 1.895260 5/11/10 4P

 Beaker tare (g) 1.912878 5/5/10 1.909704 5/6/10 1.897503 5/6/10 1.895163 5/6/10

Acetone vol (mL) 32.0 25.0 22.0 31.0

<2.5 PM Catch (mg) 0.19 0.72 0.14 0.10

Total particulate (mg) 3.0 4.1 3.4 0.4

 In-House Blank Acetone Analysis

Blank beaker number 11414 Dates

Blank volume (mL) 200 Dates Final wt (g) 1st 1.921755 5/11/10 9A

Beaker tare (g) 1.922098 5/4/10 Final wt (g) 2nd 1.921783 5/11/10 4P

Max acetone residue (g) 0.0016 Acetone residue (g) -0.0003

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KTH

EPA OTM-027

4 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

100-208-0001

0410-10

5/17/2010

0410-10-ctm027-res 5/17/2010
Analysis of Condensible Particulate Recovery

Sample ID Number Train Blank Run 1 Run 2 Run 3

Organic

Beaker Number 11412 11409 11410 11411

Initial MeCl2/Acetone Volume, mL 80.0 104 126 102

Lab MeCl2 Volume, mL 165 Dates 165 Dates 165 Dates 165 Dat

Final Weight, g 1.916835 5/11/10 9A 1.917380 5/11/10 9A 1.909652 5/11/10 9A 1.917204 5/11/1

Reweigh, Final, g 1.916878 5/11/10 4P 1.917444 5/11/10 4P 1.909696 5/11/10 4P 1.917286 5/11/1

Beaker Tare, g 1.914028 5/4/10 1.911348 5/4/10 1.904885 5/4/10 1.909837 5/4/

Net Organic Catch, mg 2.9 6.1 4.8 7.4

Inorganic

Beaker Number 11444 Dates 11441 Dates 11442 Dates 11443 Dat

Final Weight, g 1.906756 5/11/10 9A 1.919771 5/11/10 9A 1.920327 5/11/10 9A 1.918502 5/11/1

Reweigh, Final, g 1.906968 5/11/10 4P 1.919840 5/11/10 4P 1.920389 5/11/10 4P 1.918560 5/11/1

Beaker Tare, g 1.905090 5/6/10 1.897897 5/6/10 1.900583 5/6/10 1.905295 5/6/

H2O FV, mL 140 340 335 305

Resuspended Volume, mL 100 100 100 100

Removed Pre-aliquot, mL 0.500 0.500 0.500 0.500

Pre-aliquot CF 1.004 1.001 1.001 1.002

Removed Post-aliquot, mL 0.500 0.500 0.500 0.500

Post-aliquot CF 1.005 1.005 1.005 1.005

Net Inorganic, mg 1.9 22.1 19.9 13.4

Ammonium Correction, mg 0.0 2.9 2.8 2.4

Corrected Inorganic, mg 1.9 19.2 17.1 11.0

Condensible Particulate Matter, mg 4.7 25.3 21.9 18.4

TB Corrected CPM, mg 23.3 19.9 16.4

----------------------------------------------------------In-House Blank Analyses----------------------------------------------------------

Type Blank MeCl Blank Type Blank H2O Blank Type Blank 

Beaker Number 11413 Dates Beaker Number 11445 Dates Beaker Number 

Tare weight, g 1.919109 5/4/10 Tare weight, g 1.902906 5/6/10 Tare weight, g 

Dry Residue Weight, g 1.921238 5/11/10 9A Dry Residue Weight, g 1.903331 5/11/10 9A Dry Residue Weigh

Reweigh, Final, g 1.921308 5/11/10 4P Reweigh, Final, g 1.903358 5/11/10 4P Reweigh, Final, 

MeCl2 Residue, g 0.0022 Water Residue, g 0.0005 Acetone Residue

MeCl2 Volume, mL 225 Water Volume, mL 250 Acetone Volume, 

Max. MeCl2 Residue, g 0.0045 Max. Water Residue, g 0.0025 Max. Acetone Resid

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.KTHEPA OTM-0283 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-2080410-10100-208-00015/14/2010

0410-10-OTM028-res 
MDL 0.09 (mg Ammonium)

MDL 0.26 (mg Sulfate)

Blank titrant amount (Vtb) 0.02 [Set this equal to the In-House Blank Titration Volume and then white out this note]

NH4OH normality 0.100 Lot # Sigma Aldrich 318620

Sample ID.

Volume

Resuspended

(mL)

Titration

Aliquot

Vol (mL)

Aliquot Factor 

(mL rec'd/aliq mL)

Train Blank 100 99.5 0.01 ND 1.01 0.26 ND 0.09 ND

Run 1 100 99.5 1.72 1.01 8.21 2.91

Run 2 100 99.5 1.66 1.01 7.92 2.81

Run 3 100 99.5 1.41 1.01 6.71 2.38

In House 100 99.5 0.02 ND 1.01 0.26 ND 0.09 ND

SO4 Catch

(mg)

NH4OH

Titration

Vol (mL)

Ammonium

equivalent

(mg)

Company

Analyst

Parameters

# Samples

C & E Consultants, Inc.

KTH

EPA OTM-028

3 Runs & 1 blank

Client #

Job #

PO #

Report Date

100-208

0410-10

100-208-0001

5/14/2010
Narrative Summary
Enthalpy Analytical Narrative Summary 

Company C & E Consultants, Inc. Client # 100-208 

Analyst KHB Job # 0410-10 

Parameters EPA CTM-033 PO # 100-208-0001 

# Samples 3 Runs & 1 blank Report Date May 14, 2010 

Custody Heather Tarjeft of Enthalpy Analytical, Inc. received the samples on 

4/29/10 at 0.9 °C after being relinquished by Civil and Environmental 

Consultants, Inc. The samples were received in good condition. Prior to, 

during, and after analysis, the samples were kept under lock with access 

only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for hydrogen cyanide using the analytical 

procedures in EPA Conditional Test Method 033, Sampling and 

Analysis for Hydrogen Cyanide Emissions from Stationary Sources. 

The samples were analyzed following the procedures in Section 11.0, 

Analytical Procedures. 

The Dionex Model 500, High Performance Liquid Chromatograph 

("Grandmama") was equipped with a Dionex ED40 Electrochemical 

Detector and a Dionex Ion Pac AS7, 4 x 250 mm (S/N 012759) column. 

The pH of the samples was determined using test strips and is included 

in the results. 

Calibration The calibration curve is located in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

For each calibration curve used, the first page of the curve contains all 

method specific parameters (i.e., curve type, origin, weight, etc.) used to 

quantify the samples. The calibration curve section also includes a table 

with the Retention Time (RetTime), Level (Lvl), Amount 

(corresponding units), Area, Response Factor (Amt/Area) and the 

analyte Name. The calibration table is used to identify (by retention 

time) and quantify each target compound. 

Chromatographic 

Conditions 

A copy of the acquisition method 1000.M is included in the Calibration 

Curve Chromatograms section of this report. 
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes As required in Section 9.0, Quality Control, client-provided field blank, 

reagent blank and field spike were analyzed. In the laboratory the 

following QC samples were analyzed: method blank, Matrix 

Spike/Matrix Spike Duplicate, and a replicate analysis. All method 

required acceptance criteria were met. 

All sample preparation and analytical holding times specified in the 

method were met. In Section 11.1.2 the specified analytical holding time 

is 30 days from collection. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

Enthalpy Analytical, Inc. is accredited to perform this method for 

compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 
Enthalpy Analytical Narrative Summary 

Company C & E Consultants, Inc. Client # 100-208 

Analyst ARM Job # 0410-10 

Parameters EPA Method 26A PO # 100-208-0001 

# Samples 3 Runs & 1 blank Report Date May 14, 2010 

Custody Heather Tarjeft of Enthalpy Analytical, Inc. received the samples on 

4/29/10 at 0.9 °C after being relinquished by Civil and Environmental 

Consultants, Inc. The samples were received in good condition. Prior to, 

during, and after analysis, the samples were kept under lock with access 

only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for fluoride and chloride using the 

analytical procedures in EPA Method 26A, Determination of Hydrogen 

Halide and Halogen Emissions from Stationary Sources Isokinetic 

Method (40 CFR Part 60, Appendix A). 

The samples were analyzed following the procedures in Section 11.0, 

Analytical Procedures. All samples and standards are prepared, stored, 

and analyzed using high-density polyethylene containers. 

The Metrohm 861 Compact IC ("Smithers" S/N 1861002007189) was 

equipped with a Metrohm 861 Conductivity Detector and a Metrosep A 

Supp 5 - 110/4.0mm (S/N # 905298) column. 

Calibration The calibration curve is located in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

For each calibration curve used, the first page of the curve contains all 

method specific parameters (i.e., curve type, origin, weight, etc.) used to 

quantify the samples. The calibration curve section also includes a table 

with the Retention Time (RetTime), Level (Lvl), Amount 

(corresponding units), Area, Response Factor (Amt/Area) and the 

analyte Name. The calibration table is used to identify (by retention 

time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition method METROHM.M is included in the Calibration 

Curve Chromatograms section of this report. 
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes As required in Section 7.2.2, Absorbing Solution Blanks, clientprovided reagent blanks were analyzed. Additionally, a quality control 

check sample was analyzed at the same time as the blanks and samples. 

All method required acceptance criteria were met. 

All sample preparation and analytical holding times specified in the 

method were met. Section 13.2, Sample Stability, specifies an analytical 

holding time of four weeks. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

The H2SO4 matrix samples were analyzed for Cl- and F- but are 

reported as HCl and HF. The results were converted using acid 

conversion factors (CF) of 1.028 for HCl and 1.053 for HF to account 

for the hydrogen mass. 

Enthalpy Analytical, Inc. is accredited to perform this method for 

compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 
Enthalpy Analytical Narrative Summary 

Company C & E Consultants, Inc. Client # 100-208 

Analyst KHB Job # 0410-10 

Parameters NCASI Method 8A PO # 100-208-0001 

# Samples 3 Runs & 1 blank Report Date May 14, 2010 

Custody Heather Tarjeft of Enthalpy Analytical, Inc. received the samples on 

4/29/10 at 0.9 °C after being relinquished by Civil and Environmental 

Consultants, Inc. The samples were received in good condition. Prior to, 

during, and after analysis, the samples were kept under lock with access 

only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for sulfate using the analytical procedures in 

NCASI Method 8A - Determination of Sulfuric Acid Vapor or Mist and 

Sulfur Dioxide Emissions From Kraft Recovery Furnaces. 

The Metrohm 861, High Performance Liquid Chromatograph 

("Mr Burns" S/N 1861004003180) was equipped with a Metrohm 861 

Conductivity Detector and a Metrosep A Supp 5 - 110/4.0mm (S/N # 

905298) column. 

Calibration The calibration curve is located in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

For each calibration curve used, the first page of the curve contains all 

method specific parameters (i.e., curve type, origin, weight, etc.) used to 

quantify the samples. The calibration curve section also includes a table 

with the Retention Time (RetTime), Level (Lvl), Amount 

(corresponding units), Area, Response Factor (Amt/Area) and the 

analyte Name. The calibration table is used to identify (by retention 

time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition method METROHM.M is included in the Calibration 

Curve Chromatograms section of this report. 

QC Notes All sample preparation and analytical holding times specified in the 

method were met. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

The sulfate results were converted to sulfuric acid values using a 

conversion factor of 1.021 to account for the additional hydrogen mass. 
Enthalpy Analytical Narrative Summary 

Company C & E Consultants, Inc. Client # 100-208 

Analyst KHB Job # 0410-10 

Parameters HPLC/IC Analysis PO # 100-208-0001 

# Samples 3 Runs & 1 blank Report Date May 14, 2010 

Custody Heather Tarjeft of Enthalpy Analytical, Inc. received the samples on 

4/29/10 at 0.9 °C after being relinquished by Civil and Environmental 

Consultants, Inc. The samples were received in good condition. Prior to, 

during, and after analysis, the samples were kept under lock with access 

only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis Per the client’s request, the residues of the inorganic fractions of the 

OTM-028 analyses were each suspended using 20 mL of deionized 

water. These suspensions were analyzed for sulfate using a Metrohm 

861, High Performance Liquid Chromatograph ("Mr Burns" S/N 

1861004003180) the analyzer was equipped with a Metrohm 861 

Conductivity Detectorand a Metrosep A Supp 5 - 110/4.0mm (S/N # 

905298) column. 

Calibration The calibration curve is located in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

For each calibration curve used, the first page of the curve contains all 

method specific parameters (i.e., curve type, origin, weight, etc.) used to 

quantify the samples. The calibration curve section also includes a table 

with the Retention Time (RetTime), Level (Lvl), Amount 

(corresponding units), Area, Response Factor (Amt/Area) and the 

analyte Name. The calibration table is used to identify (by retention 

time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition method METROHM.M is included in the Calibration 

Curve Chromatograms section of this report. 

QC Notes None 

Reporting Notes The analytical dilution factors (DFs) for these samples were 50 and 20 

as shown on the chromatograms. The DF values in the results 

spreadsheet table are actually slightly higher, each including aliquot 

factors for the 0.5 mL aliquots removed from the sample as received and 

the sample prior to titration. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 
Enthalpy Analytical Narrative Summary 

Company C & E Consultants, Inc. Client # 100-208 

Analyst KTH Job # 0410-10 

Parameters EPA OTM 027 PO # 100-208-0001 

# Samples 3 runs & 1 blank Report Date May 17, 2010 

Custody Heather Tarjeft of Enthalpy Analytical, Inc. received the samples on 

4/29/10 at 0.9 °C after being relinquished by Civil and Environmental 

Consultants, Inc. The samples were received in good condition. Prior to, 

during, and after analysis, the samples were kept under lock with access 

only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for Particulate Matter using the analytical 

procedures in EPA Other Test Method-027. Determination of PM10 and 

PM2.5 Emissions From Stationary Sources. 

The samples were analyzed following the procedures in Section 11.0 

Analytical Procedures. 

All samples were weighed on a Sartorius Model ME 5-F (SN 23104965) 

certified by Precision Weighing, Inc. through the end of October 2010, 

(NIST Test Weight # 1481174). 

After evaporating the acetone rinses at room temperature to dryness, the 

residue was baked in a forced flow oven at 160oC for 6 hours. 

The remaining residue was desiccated and weighed at 24 hour (or 

longer) intervals until a constant weight was achieved. 

QC Notes Acetone was used as a field rinse and was received for use as a reagent 

blank. Blank corrections were performed on the sample results using a 

volume-proportioned correction value. 

An in-house acetone blank was dried down with the samples and the 

residue mass was well below the method-specified limit. 

Reporting Notes Gravimetric analyses are typically accurate to ±0.5 mg. Therefore, 

negative catch weights between 0 and –0.5 mg are set to zero and no 

investigation is undertaken. Negative catch weights < -0.5 mg are 

investigated. Only the lab’s In House acetone blank had a negative catch 

weight, but it was less than 0.5 mg. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 
Enthalpy Analytical Narrative Summary 

Company C & E Consultants, Inc. Client # 100-208 

Analyst KTH Job # 0410-10 

Parameters EPA OTM 028 PO # 100-208-0001 

# Samples 3 Runs & 1 blank Report Date May 17, 2010 

Custody Heather Tarjeft of Enthalpy Analytical, Inc. received the samples on 

4/29/10 at 0.9 °C after being relinquished by Civil and Environmental 

Consultants, Inc. The samples were received in good condition. Prior to, 

during, and after analysis, the samples were kept under lock with access 

only to authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for Particulate Matter using the analytical 

procedures in EPA Other Test Method-028. Determination of 

Condensible Particulate Emissions From Stationary Sources. 

The samples were analyzed following the procedures in Section 11.0 

Analytical Procedures. 

All samples were weighed on a Sartorius Model ME 5-F (SN 23104965) 

certified by Precision Weighing, Inc. through the end of October 2010, 

(NIST Test Weight # 1481174). 

After evaporating the acetone rinses at room temperature to dryness, the 

residue was baked in a forced flow oven at 160oC for 6 hours. 

The remaining residue was desiccated and weighed at 24 hour (or 

longer) intervals until a constant weight was achieved. 

QC Notes Acetone, methylene chloride, and water reagent blanks were received 

with these samples. All blanks had residue results allowable by the 

method. 

All sample preparation and analytical holding times specified in the 

method were met. 

Reporting Notes Gravimetric analyses are typically accurate to ±0.5 mg. Therefore, 

negative catch weights between 0 and –0.5 mg are set to zero and no 

investigation is undertaken. Negative catch weights < -0.5 mg are 

investigated. None of the sample fractions had a negative catch, though 

the laboratory In-House Acetone Blanks did. Its value was low enough 

to note require an investigation. 
Enthalpy Analytical Narrative Summary 

(continued) 

Reporting Notes 

(continued) 

The Train Blank had a catch weight greater than 2 mg. Per the method 

2.0 mg has been used as the Train Blank Correction for all the samples 

rather than the measured value (or 4.7 mg). 

The results presented in this report are representative of the samples as 

provided to the laboratory. 
General Reporting Notes 

The following are general reporting notes that are applicable to all Enthalpy Analytical, Inc. data 

reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot 

determine the presence of the analyte of interest reliably. 

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot 

quantitate the analyte of interest within the criteria of the method. 

 The acronym ND following a value indicates a non-detect or analytical result below the MDL. 

 The letter J following a value indicates an analytical result between the MDL and the LOQ. A J flag 

indicates that the laboratory can positively identify the analyte of interest as present, but the value 

should be considered an estimate. 

 The letter E following a value indicates an analytical result exceeding 100% of the highest calibration 

point. The associated value should be considered as an estimate. 

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the 

preparation and/or analysis process. The analytical result taken from a laboratory instrument is 

multiplied by the DF to determine the final undiluted sample results. 

 The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is 

spiked with a known amount of analyte so that a percent recovery value can be determined. This shows 

what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample 

matrix interferes with the analysis of the analyte(s). 

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same 

manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality 

by showing the consistency of results gained by performing the same steps multiple times. 

 The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an 

additional aliquot of sample for testing and the results of the duplicate analysis are compared to the 

initial result. The result should have a difference value of within 10% of the initial result (if the results 

of the original analysis are greater than the LOQ). 

 The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an 

additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps 

confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of 

interest, as they would have a different response/absorbance than the analyte of interest. 

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample 

matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and 

procedures used for the client samples. The LCS is used to assess the control of the laboratory’s 

analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. 

The extras (randomly chosen) are labeled with the associated project number and kept in-house at the 

appropriate temperature conditions. When the project samples are received for analysis, the LCSs are 

analyzed to confirm that the analyte could be recovered from the media, separate from the samples 

which were used on the project and which may have been affected by source matrix, sample collection 

and/or sample transport. 
General Reporting Notes 

(continued) 

 Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, 

the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a 

value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no 

confidence should be placed on more than two significant digits. 

 Manual Integration: The data systems used for processing will flag manually integrated peaks with 

an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified 

by the following two letter designations. The peak was not integrated by the software “NI”, the peak 

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software 

“WP”. These codes will accompany the analyst’s manual integration stamp placed next to the 

compound name. 
Sample Custody


Sample 

Chromatograms
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3701.D) 1.745 2.088 2.687

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3701.D

Sample Name: CTM-033-R2-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 37

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 5:43:19 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:42:52 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3702.D) 1.615 1.748 2.090 2.141 2.688

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3702.D

Sample Name: CTM-033-R2-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 37

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 5:58:35 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:01 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3801.D) 1.649 1.744 2.065

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3801.D

Sample Name: CTM-033-R3-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 38

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 6:13:51 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:08 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3802.D) 1.465 1.650 1.743 2.069 2.670

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3802.D

Sample Name: CTM-033-R3-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 38

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 6:29:13 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:14 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3901.D) 1.750 2.087 2.675

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3901.D

Sample Name: CTM-033-R4-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 39

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 6:44:30 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:22 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3902.D) 1.741 2.074 2.673

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3902.D

Sample Name: CTM-033-R4-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 39

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 6:59:47 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:29 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4001.D) 1.476 1.541 1.778 1.853 1.917

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4001.D

Sample Name: CTM-033-BT-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 40

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 7:15:04 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:35 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4002.D) 1.475 1.550 1.783 1.857 1.916

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4002.D

Sample Name: CTM-033-BT-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 40

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 7:30:20 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 4:43:41 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0801.D) 1.652 1.738

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0801.D

Sample Name: 0.1N NaOH - RB

 =====================================================================

 Acq. Operator : KHB Seq. Line : 8

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 2:56:46 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 4:02:13 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0802.D) 1.652 1.737

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0802.D

Sample Name: 0.1N NaOH - RB

 =====================================================================

 Acq. Operator : KHB Seq. Line : 8

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 3:12:00 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 4:02:21 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7601.D) 1.744 2.087

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7601.D

Sample Name: LD/CTM-033-R2-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 76

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 2:28:58 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 Sample Info : Lab Duplicate

 

 =====================================================================

Instrument 3 5/11/2010 4:43:54 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7602.D) 1.745 2.084 2.653

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7602.D

Sample Name: LD/CTM-033-R2-C3-NaOH*5 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 76

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 2:44:14 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 Sample Info : Lab Duplicate

 

 =====================================================================

Instrument 3 5/11/2010 4:44:00 PM ARM Page 1 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9301.D)

 Area: 2273.56

 1.739

 2.100

 2.689

 8.005 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.005 MM 2273.56030 5.05590e-4 1.14949 Hydrogen Cyanide 

Totals : 1.14949

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9301.D

Sample Name: MS/CTM-033-R2-C3-NaOH 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 93

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 11:16:26 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 Sample Info : Matrix Spike

 

 =====================================================================

Instrument 3 5/11/2010 4:49:05 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9302.D)

 Area: 2291.48

 1.744

 2.106

 8.026 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.026 MM 2291.47754 5.05716e-4 1.15884 Hydrogen Cyanide 

Totals : 1.15884

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9302.D

Sample Name: MS/CTM-033-R2-C3-NaOH 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 93

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 11:31:42 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 Sample Info : Matrix Spike

 

 =====================================================================

Instrument 3 5/11/2010 4:44:37 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9401.D)

 Area: 2224.28

 1.749

 2.103

 2.704

 8.048 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.048 MM 2224.28442 5.05233e-4 1.12378 Hydrogen Cyanide 

Totals : 1.12378

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9401.D

Sample Name: MSD/CTM-033-R2-C3-NaOH 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 94

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 11:46:59 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 Sample Info : Matrix Spike Duplicate

 

 =====================================================================

Instrument 3 5/11/2010 4:45:03 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9402.D)

 Area: 2235.01

 1.744

 2.106

 8.060 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.060 MM 2235.01416 5.05312e-4 1.12938 Hydrogen Cyanide 

Totals : 1.12938

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9402.D

Sample Name: MSD/CTM-033-R2-C3-NaOH 0410-10

 =====================================================================

 Acq. Operator : KHB Seq. Line : 94

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/8/2010 12:02:16 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 Sample Info : Matrix Spike Duplicate

 

 =====================================================================

Instrument 3 5/11/2010 4:45:23 PM ARM Page 1 of 1
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.300 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.300 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 8.251 1 1 1.03500e-1 237.96333 4.34941e-4 Hydrogen Cyanide 

 2 5.07300e-1 1162.53619 4.36374e-4 

 3 9.90500e-1 2156.07153 4.59400e-4 

 4 1.54100 3051.88635 5.04934e-4 

 5 2.08000 3752.79333 5.54254e-4 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

Instrument 3 5/6/2010 3:20:44 PM ARM Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 1 2

Area

0

500

1000

1500

2000

2500

3000

3500

4000

1

2

3

4

5

Hydrogen Cyanide at exp. RT: 8.251

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99532

Residual Std. Dev.: 218.88566

Formula: y = mx + b

 m: 1916.69420

 b: 70.33972

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.204021

 Level 3 : 0.104493

 Level 4 : 0.067164

 Level 5 : 0.04976

=====================================================================

Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

Instrument 3 5/6/2010 3:20:44 PM ARM Page 2 of 2
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0201.D) 1.646 1.732 1.841 8.404 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.404 BB 237.55678 3.85163e-4 9.14980e-2 Hydrogen Cyanide 

Totals : 9.14980e-2

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0201.D

Sample Name: hplc50pg78 #1

 =====================================================================

 Acq. Operator : KHB Seq. Line : 2

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 11:54:41 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:21:04 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0202.D)

 Area: 238.402

 1.649 1.736

 8.389 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.389 MF 238.40192 3.85163e-4 9.18235e-2 Hydrogen Cyanide 

Totals : 9.18235e-2

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0202.D

Sample Name: hplc50pg78 #1

 =====================================================================

 Acq. Operator : KHB Seq. Line : 2

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 12:09:30 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:24:21 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0301.D)

 Area: 1171.31

 1.648 1.736 1.843

 8.337 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.337 FM 1171.31274 4.90401e-4 5.74412e-1 Hydrogen Cyanide 

Totals : 5.74412e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0301.D

Sample Name: hplc50pg78 #2

 =====================================================================

 Acq. Operator : KHB Seq. Line : 3

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 12:24:30 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:25:33 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0302.D) 1.651 1.738 8.341 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.341 BB 1153.77625 4.89924e-4 5.65263e-1 Hydrogen Cyanide 

Totals : 5.65263e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0302.D

Sample Name: hplc50pg78 #2

 =====================================================================

 Acq. Operator : KHB Seq. Line : 3

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 12:39:38 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:25:40 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0401.D)

 Area: 2195.5

 1.651 1.739 1.851

 8.315 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.315 FM 2195.49976 5.05016e-4 1.10876 Hydrogen Cyanide 

Totals : 1.10876

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0401.D

Sample Name: hplc50pg78 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 4

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 12:54:52 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:35:39 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0402.D) 1.653 1.740 8.320 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.320 BB 2116.71265 5.04394e-4 1.06766 Hydrogen Cyanide 

Totals : 1.06766

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0402.D

Sample Name: hplc50pg78 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 4

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 1:10:06 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:36:15 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0501.D) 1.645 1.732 8.264 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.264 BB 3041.79395 5.09667e-4 1.55030 Hydrogen Cyanide 

Totals : 1.55030

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0501.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 5

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 1:25:20 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:36:23 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0502.D)

 Area: 3062.01

 1.651 1.737 1.846

 8.274 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.274 FM 3062.01001 5.09747e-4 1.56085 Hydrogen Cyanide 

Totals : 1.56085

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0502.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 5

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 1:40:34 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:38:34 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0601.D) 1.647 1.735 8.248 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.248 BB 3786.44922 5.12040e-4 1.93881 Hydrogen Cyanide 

Totals : 1.93881

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0601.D

Sample Name: hplc50pg78 #5

 =====================================================================

 Acq. Operator : KHB Seq. Line : 6

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 1:55:49 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:58:59 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0602.D) 1.650 1.736 8.252 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.252 BB 3719.13745 5.11864e-4 1.90369 Hydrogen Cyanide 

Totals : 1.90369

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0602.D

Sample Name: hplc50pg78 #5

 =====================================================================

 Acq. Operator : KHB Seq. Line : 6

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 2:11:03 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 3:59:13 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0701.D)

 Area: 1825.08

 1.649 1.736

 8.289 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.289 MM 1825.08093 5.01624e-4 9.15504e-1 Hydrogen Cyanide 

Totals : 9.15504e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0701.D

Sample Name: hplc50pg78 #LCS

 =====================================================================

 Acq. Operator : KHB Seq. Line : 7

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 2:26:18 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 4:01:49 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0702.D) 1.647 1.732 8.263 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.263 BB 1794.44543 5.01280e-4 8.99520e-1 Hydrogen Cyanide 

Totals : 8.99520e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0702.D

Sample Name: hplc50pg78 #LCS

 =====================================================================

 Acq. Operator : KHB Seq. Line : 7

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 2:41:32 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 4:01:58 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1501.D)

 Area: 3176.61

 1.660 1.746

 8.359 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.359 MM 3176.61182 5.10179e-4 1.62064 Hydrogen Cyanide 

Totals : 1.62064

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1501.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 15

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 6:31:17 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 4:03:56 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1502.D) 1.659 1.745 8.376 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.376 BB 3132.86230 5.10018e-4 1.59781 Hydrogen Cyanide 

Totals : 1.59781

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1502.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 15

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 6:46:35 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/6/2010 4:04:04 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2201.D)

 Area: 3300.59

 1.649 1.735 1.853

 7.972 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.972 MM 3300.58984 5.10613e-4 1.68532 Hydrogen Cyanide 

Totals : 1.68532

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2201.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 22

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 10:04:58 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:00:31 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2202.D) 1.649 1.736 7.957 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.957 BB 3250.91577 5.10443e-4 1.65941 Hydrogen Cyanide 

Totals : 1.65941

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2202.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 22

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/5/2010 10:20:14 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:00:50 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2901.D)

 Area: 3231.92

 1.661 1.748 1.866

 7.998 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.998 MM 3231.92456 5.10377e-4 1.64950 Hydrogen Cyanide 

Totals : 1.64950

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2901.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 29

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 1:38:49 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:01:04 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2902.D)

 Area: 3267.71

 1.652 1.740

 7.998 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.998 MM 3267.71216 5.10501e-4 1.66817 Hydrogen Cyanide 

Totals : 1.66817

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2902.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 29

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 1:54:06 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:01:22 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3601.D) 1.658 1.745 8.165 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.165 BB 3229.64795 5.10369e-4 1.64831 Hydrogen Cyanide 

Totals : 1.64831

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3601.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 36

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 5:12:46 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:01:34 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3602.D)

 Area: 3256.42

 1.436

 1.658 1.747

 8.207 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.207 MM 3256.42480 5.10462e-4 1.66228 Hydrogen Cyanide 

Totals : 1.66228

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3602.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 36

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 5:28:02 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:15:41 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4201.D) 1.655 1.742 8.328 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.328 BB 3157.99609 5.10111e-4 1.61093 Hydrogen Cyanide 

Totals : 1.61093

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4201.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 42

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 8:16:10 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:01:53 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4202.D)

 Area: 3300.11

 1.651 1.736

 8.309 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.309 MM 3300.10522 5.10611e-4 1.68507 Hydrogen Cyanide 

Totals : 1.68507

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4202.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 42

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 8:31:26 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:02:06 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5001.D)

 Area: 3311.26

 1.678 1.750

 8.324 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.324 MM 3311.25879 5.10649e-4 1.69089 Hydrogen Cyanide 

Totals : 1.69089

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5001.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 50

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 12:20:36 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:09:21 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5002.D)

 Area: 3246.27

 1.675 1.744

 8.267 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.267 MM 3246.26709 5.10427e-4 1.65698 Hydrogen Cyanide 

Totals : 1.65698

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5002.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 50

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 12:35:52 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:09:40 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5501.D)

 Area: 3255.28

 1.674 1.745 1.860

 8.147 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.147 MM 3255.27905 5.10458e-4 1.66168 Hydrogen Cyanide 

Totals : 1.66168

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5501.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 55

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 2:53:23 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:10:00 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5502.D)

 Area: 3318.9

 1.675 1.747

 8.164 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.164 MM 3318.90112 5.10674e-4 1.69488 Hydrogen Cyanide 

Totals : 1.69488

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5502.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 55

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 3:08:45 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:10:13 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5701.D)

 Area: 3286.22

 1.673 1.744

 8.239 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.239 MM 3286.22314 5.10564e-4 1.67783 Hydrogen Cyanide 

Totals : 1.67783

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5701.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 57

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 5:43:41 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:10:41 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5702.D)

 Area: 3199.39

 1.675 1.741

 8.248 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.248 MM 3199.38721 5.10261e-4 1.63252 Hydrogen Cyanide 

Totals : 1.63252

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5702.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 57

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/6/2010 5:58:54 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:10:57 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7101.D)

 Area: 3154.2

 1.666 1.741

 8.283 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.283 MM 3154.19629 5.10097e-4 1.60895 Hydrogen Cyanide 

Totals : 1.60895

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7101.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 71

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 11:56:07 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:11:48 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7102.D) 1.675 1.746 8.327 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.327 BB 3104.43188 5.09910e-4 1.58298 Hydrogen Cyanide 

Totals : 1.58298

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7102.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 71

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 12:11:23 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/7/2010 2:12:18 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7801.D)

 Area: 3177.54

 1.671 1.745

 8.310 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.310 MM 3177.54395 5.10182e-4 1.62113 Hydrogen Cyanide 

Totals : 1.62113

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7801.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 78

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 3:30:04 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/10/2010 8:57:13 AM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7802.D)

 Area: 3251.7

 1.666 1.740

 8.289 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.289 MM 3251.69995 5.10446e-4 1.65982 Hydrogen Cyanide 

Totals : 1.65982

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7802.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 78

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 3:53:25 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/10/2010 8:56:52 AM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8501.D)

 Area: 3221.29

 1.671 1.742

 8.288 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.288 MM 3221.28784 5.10339e-4 1.64395 Hydrogen Cyanide 

Totals : 1.64395

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8501.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 85

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 7:12:02 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/10/2010 8:57:46 AM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8502.D)

 Area: 3250.8

 1.670 1.744

 8.251 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.251 MM 3250.79932 5.10443e-4 1.65935 Hydrogen Cyanide 

Totals : 1.65935

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8502.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 85

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 7:27:18 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/10/2010 8:58:04 AM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9201.D)

 Area: 3307.05

 1.664 1.739

 7.970 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.970 MM 3307.05029 5.10635e-4 1.68869 Hydrogen Cyanide 

Totals : 1.68869

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9201.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 92

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 10:45:54 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/10/2010 4:27:45 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9202.D)

 Area: 3281.32

 1.671 1.745

 7.989 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.989 MM 3281.32031 5.10548e-4 1.67527 Hydrogen Cyanide 

Totals : 1.67527

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9202.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 92

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/7/2010 11:01:09 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/10/2010 4:28:03 PM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9701.D)

 Area: 3218.4

 1.663 1.739

 7.983 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.983 MM 3218.40381 5.10329e-4 1.64244 Hydrogen Cyanide 

Totals : 1.64244

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9701.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 97

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/8/2010 1:18:39 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 8:20:48 AM ARM Page 1 of 1
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9702.D)

 Area: 3253.97

 1.661 1.740

 7.977 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.977 MM 3253.96826 5.10454e-4 1.66100 Hydrogen Cyanide 

Totals : 1.66100

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9702.D

Sample Name: hplc50pg78 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 97

 Acq. Instrument : Grandmama Location : -

 Injection Date : 5/8/2010 1:33:54 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 5/7/2010 3:44:49 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

 Last changed : 5/6/2010 3:19:41 PM by ARM

 =====================================================================

Instrument 3 5/11/2010 8:21:05 AM ARM Page 1 of 1
 Method Information

 Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Modified: 3/17/2010 at 9:48:43 AM

 Column: Dionex Ionpac AS7 4 X 250mm

 Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine

 Flow rate: 1.0 mL/min

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 CHANNEL A

Source: Signal

Unit: nC

Units/Volt: 1000.000

Peakwidth (Data Rate): 0.133 Min (2.00 Hz)

Stop Time: 14.01 Min

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1
Sequence Table:

 Method and Injection Info Part:

 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 1 Vial 7 0.1N NaOH - RB 1000 4 Sample 

 

 2 Vial 1 hplc50pg78 #1 1000 2 Sample 

 3 Vial 2 hplc50pg78 #2 1000 2 Sample 

 4 Vial 3 hplc50pg78 #3 1000 2 Sample 

 5 Vial 4 hplc50pg78 #4 1000 2 Sample 

 6 Vial 5 hplc50pg78 #5 1000 2 Sample 

 7 Vial 6 hplc50pg78 #LCS 1000 2 Sample 

 8 Vial 7 0.1N NaOH - RB 1000 2 Sample 

 9 Vial 8 HCN-H2O-RB*5 0410-22 1000 2 Sample 

 10 Vial 9 H8-M26-1*5 0410-131 1000 2 Sample 

 11 Vial 10 H8-M26-2*5 0410-131 1000 2 Sample 

 12 Vial 11 H8-M26-3*5 0410-131 1000 2 Sample 

 13 Vial 12 H8-M26-FB*5 0410-131 1000 2 Sample 

 14 Vial 3 hplc50pg78 #3 1000 2 Sample 

 15 Vial 4 hplc50pg78 #4 1000 2 Sample 

 16 Vial 13 H8-M26-FS*5 0410-131 1000 2 Sample 

 17 Vial 14 H8-M26-RB*5 0410-131 1000 2 Sample 

 18 Vial 15 Run 2 Unit 1/2*5 0410-144 1000 2 Sample 

 19 Vial 16 Run 3 Unit 1/2*5 0410-144 1000 2 Sample 

 20 Vial 17 Run 4 Unit 1/2*5 0410-144 1000 2 Sample 

 21 Vial 3 hplc50pg78 #3 1000 2 Sample 

 22 Vial 4 hplc50pg78 #4 1000 2 Sample 

 23 Vial 18 Blank Unit 1/2*5 0410-144 1000 2 Sample 

 24 Vial 19 M26A/033-Hope-U1/2-1*5 0410-148 1000 2 Sample 

 25 Vial 20 M26A/033-Hope-U1/2-2*5 0410-148 1000 2 Sample 

 26 Vial 21 M26A/033-Hope-U1/2-3*5 0410-148 1000 2 Sample 

 27 Vial 22 M26A/033-Hope-U1/2-FB1*5 0410-148 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 1 of 4
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 28 Vial 3 hplc50pg78 #3 1000 2 Sample 

 

 29 Vial 4 hplc50pg78 #4 1000 2 Sample 

 30 Vial 23 M26A/033-Hope-U1/2-RB*5 0410-148 1000 2 Sample 

 31 Vial 24 M26A/033-Hope-U1/2-FS*5 0410-148 1000 2 Sample 

 32 Vial 25 M26A/033 R1 HCl/HF/HCN*5 0410-102 1000 2 Sample 

 33 Vial 26 M26A/033 R2 HCl/HF/HCN*5 0410-102 1000 2 Sample 

 34 Vial 27 M26A/033 R3 HCl/HF/HCN*5 0410-102 1000 2 Sample 

 35 Vial 3 hplc50pg78 #3 1000 2 Sample 

 36 Vial 4 hplc50pg78 #4 1000 2 Sample 

 37 Vial 28 CTM-033-R2-C3-NaOH*5 0410-10 1000 2 Sample 

 38 Vial 29 CTM-033-R3-C3-NaOH*5 0410-10 1000 2 Sample 

 39 Vial 30 CTM-033-R4-C3-NaOH*5 0410-10 1000 2 Sample 

 40 Vial 31 CTM-033-BT-C3-NaOH*5 0410-10 1000 2 Sample 

 41 Vial 3 hplc50pg78 #3 1000 2 Sample 

 42 Vial 4 hplc50pg78 #4 1000 2 Sample 

 43 Vial 32 LCS 1*100 0410-131 1000 2 Sample 

 44 Vial 33 LCS 2*100 0410-131 1000 2 Sample 

 45 Vial 34 LCS 1*100 0410-102 1000 2 Sample 

 46 Vial 35 LCS 2*100 0410-102 1000 2 Sample 

 47 Vial 3 hplc50pg78 #3 1000 2 Sample 

 48 Vial 4 hplc50pg78 #4 1000 2 Sample 

 49 Vial 3 hplc50pg78 #3 1000 2 Sample 

 50 Vial 4 hplc50pg78 #4 1000 2 Sample 

 51 Vial 33 LCS 2*100 0410-131 1000 2 Sample 

 52 Vial 34 LCS 1*100 0410-102 1000 2 Sample 

 53 Vial 35 LCS 2*100 0410-102 1000 2 Sample 

 54 Vial 3 hplc50pg78 #3 1000 2 Sample 

 55 Vial 4 hplc50pg78 #4 1000 2 Sample 

 56 Vial 3 hplc50pg78 #3 1000 2 Sample 

 57 Vial 4 hplc50pg78 #4 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 2 of 4
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 58 Vial 36 LCS 1*100 0410-102 1000 2 Sample 

 

 59 Vial 37 LCS 2*100 0410-102 1000 2 Sample 

 60 Vial 38 LD/H8-M26-2*5 0410-131 1000 2 Sample 

 61 Vial 39 MS/H8-M26-2 0410-131 1000 2 Sample 

 62 Vial 40 MSD/H8-M26-2 0410-131 1000 2 Sample 

 63 Vial 3 hplc50pg78 #3 1000 2 Sample 

 64 Vial 4 hplc50pg78 #4 1000 2 Sample 

 65 Vial 41 LD/Run 2 Unit 1/2*5 0410-144 1000 2 Sample 

 66 Vial 42 MS/Run 2 Unit 1/2 0410-144 1000 2 Sample 

 67 Vial 43 MSD/Run 2 Unit 1/2 0410-144 1000 2 Sample 

 68 Vial 44 LD/M26A/033-Hope-U1/2-2*5 0410-148 1000 2 Sample 

 69 Vial 45 MS*2/M26A/033-Hope-U1/2-2 0410-148 1000 2 Sample 

 70 Vial 3 hplc50pg78 #3 1000 2 Sample 

 71 Vial 4 hplc50pg78 #4 1000 2 Sample 

 72 Vial 46 MSD*2/M26A/033-Hope-U1/2-2 0410-148 1000 2 Sample 

 73 Vial 47 LD/M26A/033 R2 HCl/HF/HCN*5 0410-102 1000 2 Sample 

 74 Vial 48 MS/M26A/033 R2 HCl/HF/HCN 0410-102 1000 2 Sample 

 75 Vial 49 MSD/M26A/033 R2 HCl/HF/HCN 0410-102 1000 2 Sample 

 76 Vial 50 LD/CTM-033-R2-C3-NaOH*5 0410-10 1000 2 Sample 

 77 Vial 3 hplc50pg78 #3 1000 2 Sample 

 78 Vial 4 hplc50pg78 #4 1000 2 Sample 

 79 Vial 36 LCS 1*100 0410-102 1000 2 Sample 

 80 Vial 37 LCS 2*100 0410-102 1000 2 Sample 

 81 Vial 38 LD/H8-M26-2*5 0410-131 1000 2 Sample 

 82 Vial 39 MS/H8-M26-2 0410-131 1000 2 Sample 

 83 Vial 40 MSD/H8-M26-2 0410-131 1000 2 Sample 

 84 Vial 3 hplc50pg78 #3 1000 2 Sample 

 85 Vial 4 hplc50pg78 #4 1000 2 Sample 

 86 Vial 41 LD/Run 2 Unit 1/2*5 0410-144 1000 2 Sample 

 87 Vial 42 MS/Run 2 Unit 1/2 0410-144 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 3 of 4
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 88 Vial 43 MSD/Run 2 Unit 1/2 0410-144 1000 2 Sample 

 

 89 Vial 44 LD/M26A/033-Hope-U1/2-2*5 0410-148 1000 2 Sample 

 90 Vial 45 MS*2/M26A/033-Hope-U1/2-2 0410-148 1000 2 Sample 

 91 Vial 3 hplc50pg78 #3 1000 2 Sample 

 92 Vial 4 hplc50pg78 #4 1000 2 Sample 

 93 Vial 51 MS/CTM-033-R2-C3-NaOH 0410-10 1000 2 Sample 

 94 Vial 52 MSD/CTM-033-R2-C3-NaOH 0410-10 1000 2 Sample 

 95 Vial 53 M26A/033-Hope-U1/2-FS*50 0410-148 1000 2 Sample 

 96 Vial 3 hplc50pg78 #3 1000 2 Sample 

 97 Vial 4 hplc50pg78 #4 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 4 of 4
Sample 

Chromatograms
=====================================================================

Acq. Operator : ARM Seq. Line : 9

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 2:54:39 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\011-0901.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\011-0901.D

Sample Name: M26A-R1-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:49:17 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 9

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 3:05:26 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\011-0902.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\011-0902.D

Sample Name: M26A-R1-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:49:28 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 12

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 3:59:25 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\014-1201.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\014-1201.D

Sample Name: M26A-R2-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:21 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 12

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 4:10:14 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\014-1202.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\014-1202.D

Sample Name: M26A-R2-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:32 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 13

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 4:21:01 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\015-1301.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\015-1301.D

Sample Name: M26A-R3-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:43 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 13

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 4:31:49 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\015-1302.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\015-1302.D

Sample Name: M26A-R3-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:54 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 14

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 4:42:37 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\016-1401.D) 3.722 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.722 BB 7.51000e-1 3.72010e-2 2.79380e-2 Chloride 

Totals : 2.79380e-2

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\016-1401.D

Sample Name: M26A-BT-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:51:05 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 14

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 4:53:25 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\016-1402.D) 3.720 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.720 BB 7.18118e-1 3.72010e-2 2.67147e-2 Chloride 

Totals : 2.67147e-2

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\016-1402.D

Sample Name: M26A-BT-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:51:15 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 8

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 2:33:03 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\007-0801.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\007-0801.D

Sample Name: Reagent Blank

Instrument 1 5/5/2010 8:48:55 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 8

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 2:43:51 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\007-0802.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 - - - Fluoride 

 3.705 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\007-0802.D

Sample Name: Reagent Blank

Instrument 1 5/5/2010 8:49:06 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 7

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 2:11:27 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\006-0701.D) 2.779 - Fluoride 3.730 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.779 BB 251.20392 1.62063e-2 4.07108 Fluoride Both Tag Value= 4.0 μg/mL 

 3.730 BB 148.30563 2.53543e-2 3.76018 Chloride 

Totals : 7.83126

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\006-0701.D

Sample Name: HPLC51p92 #LCS

Instrument 1 5/5/2010 8:48:34 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 7

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 2:22:15 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\006-0702.D) 2.779 - Fluoride 3.730 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.779 BB 251.05655 1.62063e-2 4.06869 Fluoride Both Tag Value= 4.0 μg/mL 

 3.730 BB 148.15286 2.53545e-2 3.75634 Chloride 

Totals : 7.82504

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\006-0702.D

Sample Name: HPLC51p92 #LCS

Instrument 1 5/5/2010 8:48:44 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 10

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 3:16:15 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\012-1001.D) 2.781 - Fluoride 3.730 - Chloride 5.104

 5.793

 6.085

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 219.94760 1.62129e-2 3.56600 Fluoride 

 3.730 BB 114.65800 2.54184e-2 2.91443 Chloride 

Totals : 6.48043

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\012-1001.D

Sample Name: MS M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:49:38 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 10

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 3:27:02 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\012-1002.D) 2.781 - Fluoride 3.730 - Chloride 5.104

 5.794

 6.085

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 218.93048 1.62132e-2 3.54956 Fluoride 

 3.730 BB 114.60918 2.54186e-2 2.91320 Chloride 

Totals : 6.46276

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\012-1002.D

Sample Name: MS M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:49:49 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 11

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 3:37:49 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\013-1101.D) 2.780 - Fluoride 3.729 - Chloride 5.105

 5.792

 6.084

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.780 BB 217.89267 1.62135e-2 3.53279 Fluoride 

 3.729 BB 114.13017 2.54198e-2 2.90116 Chloride 

Totals : 6.43395

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\013-1101.D

Sample Name: MSD M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:50:00 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 11

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 3:48:38 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\013-1102.D) 2.781 - Fluoride 3.730 - Chloride 5.105

 5.794

 6.086

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 217.54382 1.62135e-2 3.52716 Fluoride 

 3.730 BB 114.07535 2.54199e-2 2.89978 Chloride 

Totals : 6.42694

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\013-1102.D

Sample Name: MSD M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:50:10 AM ARM Page 1 of 1
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC1 B, Metrohm

Signal 2: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 2.781 2 1 1.00000e-1 5.08084 1.96818e-2 Fluoride 

 2 9.99000e-1 62.57442 1.59650e-2 

 3 4.97500 320.71269 1.55123e-2 

 4 8.92000 563.32326 1.58346e-2 

 5 14.80000 888.43126 1.66586e-2 

 3.705 2 1 1.00000e-1 3.07677 3.25017e-2 Chloride 

 2 9.99000e-1 34.87551 2.86447e-2 

 3 4.97500 192.28088 2.58736e-2 

 4 8.92000 354.95784 2.51297e-2 

 5 14.80000 593.68901 2.49289e-2 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Instrument 1 5/5/2010 8:45:48 AM ARM Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

200

400

600

800

1

2

3

4

5

Fluoride at exp. RT: 2.781

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99950

Residual Std. Dev.: 18.67116

Formula: y = mx + b

 m: 61.88432

 b: -7.31816e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.1001

 Level 3 : 0.020101

 Level 4 : 0.011211

 Level 5 : 0.006757

Amount[ug/mL]

0 10

Area

0

100

200

300

400

500

1

2

3

4

5

Chloride at exp. RT: 3.705

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99976

Residual Std. Dev.: 4.89599

Formula: y = mx + b

 m: 39.78424

 b: -1.29033

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.1001

 Level 3 : 0.020101

 Level 4 : 0.011211

 Level 5 : 0.006757

=====================================================================

Method Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Instrument 1 5/5/2010 8:45:48 AM ARM Page 2 of 2
=====================================================================

Acq. Operator : ARM Seq. Line : 2

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 12:23:29 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-0201.D) 2.772 - Fluoride 3.737 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.772 BB 5.03732 1.83264e-2 9.23158e-2 Fluoride 

 3.737 BB 3.00709 3.59211e-2 1.08018e-1 Chloride 

Totals : 2.00334e-1

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-0201.D

Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:46:46 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 2

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 12:34:17 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-0202.D) 2.774 - Fluoride 3.738 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.774 BB 5.09628 1.83264e-2 9.33964e-2 Fluoride 

 3.738 BB 2.97792 3.60268e-2 1.07285e-1 Chloride 

Totals : 2.00681e-1

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-0202.D

Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:46:57 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 30

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 10:28:12 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-3001.D) 2.780 - Fluoride 3.706 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.780 BB 5.13956 1.83264e-2 9.41896e-2 Fluoride 

 3.706 BB 3.14353 3.54530e-2 1.11448e-1 Chloride 

Totals : 2.05637e-1

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-3001.D

Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:56:53 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 30

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 10:39:00 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-3002.D) 2.779 - Fluoride 3.703 - Chloride

 5.638

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.779 BB 5.05021 1.83264e-2 9.25520e-2 Fluoride 

 3.703 BB 3.17853 3.53394e-2 1.12327e-1 Chloride 

Totals : 2.04879e-1

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-3002.D

Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:57:04 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 3

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 12:45:06 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-0301.D) 2.775 - Fluoride 3.737 - Chloride

 5.824

 6.055

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.775 BB 62.29956 1.63490e-2 1.01854 Fluoride 

 3.737 BB 34.63943 2.60719e-2 9.03115e-1 Chloride 

Totals : 1.92165

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-0301.D

Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:47:07 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 3

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 12:55:54 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-0302.D) 2.774 - Fluoride 3.734 - Chloride 5.093

 5.814

 6.057

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.774 BB 62.50897 1.63484e-2 1.02192 Fluoride 

 3.734 BB 34.88967 2.60652e-2 9.09405e-1 Chloride 

Totals : 1.93132

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-0302.D

Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:47:18 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 31

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 10:49:47 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-3101.D) 2.782 - Fluoride 3.703 - Chloride 5.002

 5.629

 6.153

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.782 BB 62.83863 1.63474e-2 1.02725 Fluoride 

 3.703 BB 35.03148 2.60614e-2 9.12970e-1 Chloride 

Totals : 1.94022

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-3101.D

Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:57:14 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 31

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 11:00:36 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-3102.D) 2.782 - Fluoride 3.703 - Chloride 4.999

 5.624

 6.154

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.782 BB 62.65052 1.63479e-2 1.02421 Fluoride 

 3.703 BB 34.94147 2.60638e-2 9.10707e-1 Chloride 

Totals : 1.93491

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-3102.D

Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:57:25 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 4

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 1:06:40 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-0401.D) 2.779 - Fluoride 3.732 - Chloride 5.049

 5.782

 6.064

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.779 BB 319.55215 1.61962e-2 5.17553 Fluoride 

 3.732 BB 191.97200 2.53045e-2 4.85776 Chloride 

Totals : 10.03329

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-0401.D

Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:47:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 4

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 1:17:29 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-0402.D) 2.779 - Fluoride 3.731 - Chloride 5.046

 5.778

 6.067

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.779 BB 319.27460 1.61962e-2 5.17104 Fluoride 

 3.731 BB 191.94141 2.53046e-2 4.85699 Chloride 

Totals : 10.02803

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-0402.D

Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:47:39 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 32

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 11:11:23 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-3201.D) 2.786 - Fluoride 3.699 - Chloride

 5.606

 6.146

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.786 BB 322.12744 1.61959e-2 5.21714 Fluoride 

 3.699 BB 192.54091 2.53040e-2 4.87206 Chloride 

Totals : 10.08920

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-3201.D

Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:57:36 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 32

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 11:22:10 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-3202.D) 2.787 - Fluoride 3.699 - Chloride

 5.603

 6.148

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.787 BB 321.89658 1.61959e-2 5.21341 Fluoride 

 3.699 BB 192.66919 2.53039e-2 4.87529 Chloride 

Totals : 10.08870

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-3202.D

Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:57:46 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 5

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 1:28:16 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-0501.D) 2.785 - Fluoride 3.728 - Chloride 5.040

 5.764

 6.078

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.785 BB 561.44849 1.61802e-2 9.08437 Fluoride 

 3.728 BB 354.50882 2.52271e-2 8.94322 Chloride 

Totals : 18.02759

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-0501.D

Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:47:50 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 5

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 1:39:05 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-0502.D) 2.786 - Fluoride 3.729 - Chloride 5.040

 5.763

 6.082

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.786 BB 560.80377 1.61803e-2 9.07396 Fluoride 

 3.729 BB 354.60712 2.52270e-2 8.94569 Chloride 

Totals : 18.01964

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-0502.D

Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:48:00 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 33

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 11:32:57 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-3301.D) 2.792 - Fluoride 3.699 - Chloride 4.982

 5.597

 6.148

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.792 BB 564.49432 1.61801e-2 9.13359 Fluoride 

 3.699 BB 355.35175 2.52269e-2 8.96441 Chloride 

Totals : 18.09800

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-3301.D

Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:57:57 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 33

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 11:43:44 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-3302.D) 2.791 - Fluoride 3.696 - Chloride 4.980

 5.592

 6.148

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.791 BB 566.54645 1.61801e-2 9.16675 Fluoride 

 3.696 BB 355.36368 2.52268e-2 8.96471 Chloride 

Totals : 18.13146

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-3302.D

Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:58:08 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 6

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 1:49:52 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-0601.D) 2.794 - Fluoride 3.728 - Chloride 5.024

 5.751

 6.087

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.794 BB 883.68909 1.61726e-2 14.29152 Fluoride 

 3.728 BB 592.64661 2.51903e-2 14.92895 Chloride 

Totals : 29.22047

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-0601.D

Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:48:12 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 6

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 2:00:40 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-0602.D) 2.793 - Fluoride 3.726 - Chloride 5.021

 5.748

 6.086

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.793 BB 885.45966 1.61725e-2 14.32013 Fluoride 

 3.726 BB 592.68384 2.51903e-2 14.92989 Chloride 

Totals : 29.25001

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-0602.D

Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:48:23 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 34

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 11:54:33 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-3401.D) 2.801 - Fluoride 3.698 - Chloride 4.975

 5.588

 6.148

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.801 BB 892.53955 1.61724e-2 14.43453 Fluoride 

 3.698 BB 594.80170 2.51901e-2 14.98312 Chloride 

Totals : 29.41765

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-3401.D

Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:58:19 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 34

Acq. Instrument : Smithers Location : -

Injection Date : 5/5/2010 12:05:20 AM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-3402.D) 2.800 - Fluoride 3.697 - Chloride 4.975

 5.585

 6.148

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.800 BB 892.03674 1.61724e-2 14.42641 Fluoride 

 3.697 BB 594.62390 2.51901e-2 14.97865 Chloride 

Totals : 29.40506

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-3402.D

Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:58:31 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 19

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 6:30:38 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-1901.D) 2.781 - Fluoride 3.731 - Chloride 5.046

 5.774

 6.072

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 320.84857 1.61960e-2 5.19648 Fluoride 

 3.731 BB 192.44281 2.53041e-2 4.86960 Chloride 

Totals : 10.06607

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-1901.D

Sample Name: HPLC51pg92 #3

Instrument 1 5/5/2010 8:52:54 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : ARM Seq. Line : 19

Acq. Instrument : Smithers Location : -

Injection Date : 5/4/2010 6:41:25 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Last changed : 5/5/2010 8:45:19 AM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-1902.D) 2.781 - Fluoride 3.731 - Chloride 5.047

 5.776

 6.070

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 319.23227 1.61962e-2 5.17036 Fluoride 

 3.731 BB 192.04607 2.53045e-2 4.85962 Chloride 

Totals : 10.02998

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-1902.D

Sample Name: HPLC51pg92 #3

Instrument 1 5/5/2010 8:53:05 AM ARM Page 1 of 1
 Method Information

 Method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

 Modified: 1/13/2010 at 7:06:26 AM

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 A, Metrohm

Source: Signal

Unit: mAU

Units/Volt: 100.000

Peakwidth (Data Rate): 0.027 Min (10.00 Hz)

Stop Time: No Limit

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Modified on: 1/13/2010 at 7:06:26 AM

Smithers 1/18/2010 7:20:57 AM mgb Page 1 of 1
Sequence: C:\HPCHEM\1\SEQUENCE\hplc51pg92.txt

Line Vial Sample Name Method Inj

1 Vial 127 DI H2O METROHM 4

2 Vial 1 HPLC51p92 #1 METROHM 2

3 Vial 2 HPLC51p92 #2 METROHM 2

4 Vial 3 HPLC51p92 #3 METROHM 2

5 Vial 4 HPLC51p92 #4 METROHM 2

6 Vial 5 HPLC51p92 #5 METROHM 2

7 Vial 6 HPLC51p92 #LCS METROHM 2

8 Vial 7 Reagent Blank METROHM 2

9 Vial 11 M26A-R1-C3-H2SO4 *20 0410-10 METROHM 2

10 Vial 12 MS M26A-R1-C3-H2SO4 0410-10 METROHM 2

11 Vial 13 MSD M26A-R1-C3-H2SO4 0410-10 METROHM 2

12 Vial 14 M26A-R2-C3-H2SO4 *20 0410-10 METROHM 2

13 Vial 15 M26A-R3-C3-H2SO4 *20 0410-10 METROHM 2

14 Vial 16 M26A-BT-C3-H2SO4 *20 0410-10 METROHM 2

15 Vial 21 Run 2 Unit 1/2 *20 0410-144 METROHM 2

16 Vial 22 MS Run 2 Unit 1/2 0410-144 METROHM 2

17 Vial 23 MSD Run 2 Unit 1/2 0410-144 METROHM 2

18 Vial 24 Run 3 Unit 1/2 *20 0410-144 METROHM 2

19 Vial 3 HPLC51pg92 #3 METROHM 2

20 Vial 4 HPLC51pg92 #4 METROHM 2

21 Vial 25 Run 4 Unit 1/2 *20 0410-144 METROHM 2

22 Vial 26 Blank Unit 1/2 *20 0410-144 METROHM 2

23 Vial 31 H8-M26-1 *20 0410-131 METROHM 2

24 Vial 32 MS H8-M26-1 0410-131 METROHM 2

25 Vial 33 MSD H8-M26-1 0410-131 METROHM 2

26 Vial 34 H8-M26-2 *20 0410-131 METROHM 2

27 Vial 35 H8-M26-3 *20 0410-131 METROHM 2

28 Vial 36 H8-M26-FB *20 0410-131 METROHM 2

29 Vial 37 H8-M26-RB *20 0410-131 METROHM 2

30 Vial 1 HPLC51p92 #1 METROHM 2

31 Vial 2 HPLC51p92 #2 METROHM 2

32 Vial 3 HPLC51p92 #3 METROHM 2

33 Vial 4 HPLC51p92 #4 METROHM 2

34 Vial 5 HPLC51p92 #5 METROHM 2
Sample 

Chromatograms
=====================================================================

Acq. Operator : KHB Seq. Line : 14

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 8:09:50 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1401.D)

 Area: 1.50513 9.558 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.558 MM 1.50513 6.27688e-2 9.44753e-2 Sulfate 

Totals : 9.44753e-2

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1401.D

Sample Name: M8A-R1-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:29:25 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 14

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 8:26:38 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1402.D)

 Area: 1.46476 9.566 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.566 MM 1.46476 6.27688e-2 9.19411e-2 Sulfate 

Totals : 9.19411e-2

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1402.D

Sample Name: M8A-R1-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:30:09 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 15

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 8:43:27 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1501.D)

 Area: 0.837341 9.587 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.587 MM 8.37341e-1 6.27688e-2 5.25589e-2 Sulfate 

Totals : 5.25589e-2

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1501.D

Sample Name: M8A-R2-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:30:33 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 15

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 9:00:14 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1502.D)

 Area: 0.854182 9.593 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.593 MM 8.54182e-1 6.27688e-2 5.36160e-2 Sulfate 

Totals : 5.36160e-2

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1502.D

Sample Name: M8A-R2-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:31:03 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 16

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 9:17:02 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1601.D)

 Area: 1.0283 9.595 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.595 MM 1.02830 6.27688e-2 6.45453e-2 Sulfate 

Totals : 6.45453e-2

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1601.D

Sample Name: M8A-R3-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:34:55 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 16

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 9:33:50 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1602.D)

 Area: 1.01219 9.598 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.598 MM 1.01219 6.27688e-2 6.35342e-2 Sulfate 

Totals : 6.35342e-2

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1602.D

Sample Name: M8A-R3-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:35:42 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 17

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 9:50:38 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Sample Blank

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\016-1701.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\016-1701.D

Sample Name: M8A-BT-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:20:24 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 17

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 10:07:26 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Sample Blank

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\016-1702.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\016-1702.D

Sample Name: M8A-BT-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:20:32 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 4:48:14 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0801.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0801.D

Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:10 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 5:05:03 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0802.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0802.D

Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:21 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 4:14:39 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D) 3.107 4.212 5.882 6.582 8.350 9.491 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.491 BB 141.38943 4.42883e-2 6.26190 Sulfate Tag Value = 6.250 μg/mL 

Totals : 6.26190

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D

Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:04 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 4:31:27 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D) 3.107 4.213 5.884 6.585 8.351 9.491 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.491 BB 137.15407 4.42948e-2 6.07521 Sulfate Tag Value = 6.250 μg/mL 

Totals : 6.07521

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D

Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:10 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 33

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 12:29:46 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Matrix Spike

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\024-3302.D)

 9.509 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.509 BB 63.05366 4.45500e-2 2.80904 Sulfate 

Totals : 2.80904

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\024-3302.D

Sample Name: MS/M8A-R1-C1-SO3 0410-10

Instrument 3 5/13/2010 10:14:13 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 34

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 12:46:34 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Matrix Spike Duplicate

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\025-3401.D)

 9.510 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.510 BB 64.73146 4.45377e-2 2.88299 Sulfate 

Totals : 2.88299

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\025-3401.D

Sample Name: MSD/M8A-R1-C1-SO3 0410-10

Instrument 3 5/13/2010 10:14:20 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 34

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 1:03:21 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Matrix Spike Duplicate

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\025-3402.D)

 9.511 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.511 BB 69.13836 4.45084e-2 3.07724 Sulfate 

Totals : 3.07724

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\025-3402.D

Sample Name: MSD/M8A-R1-C1-SO3 0410-10

Instrument 3 5/13/2010 10:14:26 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 35

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 1:20:09 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Matrix Spike

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\026-3501.D)

 9.514 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.514 BB 65.78504 4.45303e-2 2.92943 Sulfate 

Totals : 2.92943

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\026-3501.D

Sample Name: MS/MeadWestVaco M8R1 0510-45

Instrument 3 5/13/2010 10:14:32 AM ARM Page 1 of 1
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : 5/11/2010 5:55:38 PM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 9.489 1 1 1.00000e-1 1.94891 5.13107e-2 Sulfate 

 2 5.00000e-1 9.20960 5.42912e-2 

 3 5.00000 107.53530 4.64964e-2 

 4 10.00000 225.66882 4.43127e-2 

 5 15.00000 346.48825 4.32915e-2 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

50

100

150

200

250

300

12

3

4

5

Sulfate at exp. RT: 9.489

ADC1 B, ADC2 CHANNEL B

Correlation: 0.99952

Residual Std. Dev.: 5.06077

Formula: y = mx + b

 m: 22.68721

 b: -6.75574e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.2

 Level 3 : 0.02

 Level 4 : 0.01

 Level 5 : 0.006667

=====================================================================

Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 2 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 1:26:39 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D)

 Area: 1.88947

 3.104

 4.217

 9.506 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.506 MM 1.88947 5.98375e-2 1.13061e-1 Sulfate 

Totals : 1.13061e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D

Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:07 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 1:43:28 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D)

 Area: 2.00835

 3.104

 4.217

 9.503 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.503 MM 2.00835 5.89047e-2 1.18301e-1 Sulfate 

Totals : 1.18301e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D

Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:00:15 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D) 3.103 4.215 5.906 6.623 8.374 9.498 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.498 BB 9.16793 4.73257e-2 4.33879e-1 Sulfate 

Totals : 4.33879e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D

Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:01 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:17:03 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D) 3.104 4.216 5.906 6.622 8.376 9.499 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.499 BB 9.25128 4.72965e-2 4.37553e-1 Sulfate 

Totals : 4.37553e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D

Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:08 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:33:51 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D) 3.112 4.213 5.886 6.587 8.353 9.492 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.492 BB 109.14275 4.43505e-2 4.84054 Sulfate 

Totals : 4.84054

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D

Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:14 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:50:39 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D) 3.112 4.213 5.886 6.587 8.353 9.492 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.492 BB 105.92785 4.43588e-2 4.69883 Sulfate 

Totals : 4.69883

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D

Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:26 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:07:27 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D) 3.124 4.215 5.881 6.577 8.350 9.490 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.490 BB 228.02539 4.42083e-2 10.08061 Sulfate 

Totals : 10.08061

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D

Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:39 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:24:15 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D) 3.122 4.214 5.884 6.581 8.348 9.488 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.488 BB 223.31224 4.42110e-2 9.87287 Sulfate 

Totals : 9.87287

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D

Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:46 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:41:03 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D) 3.133 4.216 5.878 6.571 8.346 9.488 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.488 BB 352.66254 4.41621e-2 15.57433 Sulfate 

Totals : 15.57433

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D

Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:51 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:57:51 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D) 3.132 4.215 5.876 6.568 8.347 9.489 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 BB 340.31396 4.41652e-2 15.03003 Sulfate 

Totals : 15.03003

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D

Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:58 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 19

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 10:57:49 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1901.D) 3.127 4.177 5.736 6.387

 8.417

 9.583 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.583 BB 231.36612 4.42064e-2 10.22786 Sulfate 

Totals : 10.22786

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1901.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:20:54 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 19

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 11:14:38 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1902.D) 3.127 4.177 5.735 6.386

 8.421

 9.584 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.584 BB 223.56235 4.42109e-2 9.88389 Sulfate 

Totals : 9.88389

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1902.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:21:01 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 28

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 4:00:14 AM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2801.D) 3.129 4.175 5.724 6.373

 8.423

 9.596 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.596 BB 231.33727 4.42064e-2 10.22659 Sulfate 

Totals : 10.22659

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2801.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:05 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 28

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 4:17:01 AM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2802.D) 3.129 4.177 5.728 6.379

 8.430

 9.595 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.595 BB 221.99748 4.42118e-2 9.81491 Sulfate 

Totals : 9.81491

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2802.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:12 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 30

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 10:48:57 AM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3001.D) 3.124 4.215 5.883 6.581

 8.333

 9.495 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.495 BB 242.00009 4.42007e-2 10.69658 Sulfate 

Totals : 10.69658

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3001.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:34 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 30

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 11:05:45 AM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3002.D) 3.120 4.212 5.877 6.574

 8.335

 9.496 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.496 BB 219.04594 4.42136e-2 9.68482 Sulfate 

Totals : 9.68482

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3002.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:41 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 41

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 4:58:32 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-4102.D) 3.134 4.218 5.856 6.543

 8.488

 9.649 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.649 BB 241.92140 4.42008e-2 10.69311 Sulfate 

Totals : 10.69311

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-4102.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:16:08 AM ARM Page 1 of 1
 Method Information

 Method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

 Modified: 1/13/2010 at 7:06:26 AM

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 A, Metrohm

Source: Signal

Unit: mAU

Units/Volt: 100.000

Peakwidth (Data Rate): 0.027 Min (10.00 Hz)

Stop Time: No Limit

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Modified on: 1/13/2010 at 7:06:26 AM

Smithers 1/18/2010 7:20:57 AM mgb Page 1 of 1
Sequence: C:\HPCHEM\3\SEQUENCE\hplc53pg44.txt

Line Vial Sample Name Method Inj

1 Vial 7 RB/DI H2O METROHM 3

2 Vial 1 hplc53pg44 #1 METROHM 2

3 Vial 2 hplc53pg44 #2 METROHM 2

4 Vial 3 hplc53pg44 #3 METROHM 2

5 Vial 4 hplc53pg44 #4 METROHM 2

6 Vial 5 hplc53pg44 #5 METROHM 2

7 Vial 6 hplc53pg44 #LCS METROHM 2

8 Vial 7 RB/DI H2O METROHM 2

9 Vial 8 Run 1 post*50 0410-10 METROHM 2

10 Vial 9 Run 2 post*50 0410-10 METROHM 2

11 Vial 10 Run 3 post*50 0410-10 METROHM 2

12 Vial 11 Train Blk post*50 0410-10 METROHM 2

13 Vial 12 IHB post*50 0410-10 METROHM 2

14 Vial 13 M8A-R1-C1-SO3*20 0410-10 METROHM 2

15 Vial 14 M8A-R2-C1-SO3*20 0410-10 METROHM 2

16 Vial 15 M8A-R3-C1-SO3*20 0410-10 METROHM 2

17 Vial 16 M8A-BT-C1-SO3*20 0410-10 METROHM 2

18 Vial 3 hplc53pg44 #3 METROHM 2

19 Vial 4 hplc53pg44 #4 METROHM 2

20 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2

21 Vial 18 MeadWestVaco M8R2*20 0510-45 METROHM 2

22 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2

23 Vial 20 M13A-1*20 0510-135 METROHM 2

24 Vial 21 M13A-2*20 0510-135 METROHM 2

25 Vial 22 M13A-3*20 0510-135 METROHM 2

26 Vial 23 IPA Blank*20 0510-135 METROHM 2

27 Vial 3 hplc53pg44 #3 METROHM 2

28 Vial 4 hplc53pg44 #4 METROHM 2

29 Vial 3 hplc53pg44 #3 METROHM 2

30 Vial 4 hplc53pg44 #4 METROHM 2

31 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2

32 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2

33 Vial 24 MS/M8A-R1-C1-SO3 0410-10 METROHM 2

34 Vial 25 MSD/M8A-R1-C1-SO3 0410-10 METROHM 2

35 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2

36 Vial 27 MSD/MeadWestVaco M8R1 0510-45 METROHM 2

37 Vial 28 MS/M13A-1 0510-135 METROHM 2

38 Vial 29 MSD/M13A-1 0510-135 METROHM 2

39 Vial 30 M13A-3*20 0510-135 METROHM 2

40 Vial 3 hplc53pg44 #3 METROHM 2

41 Vial 4 hplc53pg44 #4 METROHM 2

42 Vial 31 Run 1*50 0410-10 METROHM 2

43 Vial 32 Run 2*50 0410-10 METROHM 2

44 Vial 33 Run 3*50 0410-10 METROHM 2

45 Vial 34 Train Blk*20 0410-10 METROHM 2

46 Vial 35 IHB*20 0410-10 METROHM 2

47 Vial 36 MS/Run 1 0410-10 METROHM 2

48 Vial 37 MSD/Run 1 0410-10 METROHM 2

49 Vial 3 hplc53pg44 #3 METROHM 2

50 Vial 4 hplc53pg44 #4 METROHM 2

51 Vial 3 hplc53pg44 #3 METROHM 2

52 Vial 4 hplc53pg44 #4 METROHM 2

53 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2

54 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2

55 Vial 3 hplc53pg44 #3 METROHM 2

56 Vial 4 hplc53pg44 #4 METROHM 2
Sample 

Chromatograms
=====================================================================

Acq. Operator : KHB Seq. Line : 57

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 5:26:32 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\031-5701.D)

 9.670 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.670 BB 153.27998 4.42720e-2 6.78601 Sulfate 

Totals : 6.78601

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\031-5701.D

Sample Name: Run 1*50 0410-10

Instrument 1 5/14/2010 8:15:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 57

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 5:43:19 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\031-5702.D)

 9.667 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.667 BB 167.09430 4.42559e-2 7.39491 Sulfate 

Totals : 7.39491

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\031-5702.D

Sample Name: Run 1*50 0410-10

Instrument 1 5/14/2010 8:15:37 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 43

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 6:33:15 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\032-4301.D) 4.179

 9.654 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.654 BB 171.69333 4.42511e-2 7.59762 Sulfate 

Totals : 7.59762

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\032-4301.D

Sample Name: Run 2*50 0410-10

Instrument 3 5/13/2010 10:16:28 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 43

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 6:50:03 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\032-4302.D)

 9.654 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.654 BB 164.26805 4.42590e-2 7.27033 Sulfate 

Totals : 7.27033

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\032-4302.D

Sample Name: Run 2*50 0410-10

Instrument 3 5/13/2010 10:16:34 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 44

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 7:06:51 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\033-4401.D)

 9.658 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.658 BB 154.12886 4.42709e-2 6.82342 Sulfate 

Totals : 6.82342

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\033-4401.D

Sample Name: Run 3*50 0410-10

Instrument 3 5/13/2010 10:16:41 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 44

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 7:23:40 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\033-4402.D)

 9.668 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.668 BB 143.55124 4.42851e-2 6.35718 Sulfate 

Totals : 6.35718

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\033-4402.D

Sample Name: Run 3*50 0410-10

Instrument 3 5/13/2010 10:16:47 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 45

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 7:40:27 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Sample Blank

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\034-4501.D) 3.354 4.210 6.540

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\034-4501.D

Sample Name: Train Blk*20 0410-10

Instrument 3 5/13/2010 10:16:53 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 45

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 7:57:15 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : Sample Blank

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\034-4502.D) 3.352 4.205 6.519

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\034-4502.D

Sample Name: Train Blk*20 0410-10

Instrument 3 5/13/2010 10:17:00 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 46

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 8:14:03 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : In-House Blank

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\035-4601.D) 4.203

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\035-4601.D

Sample Name: IHB*20 0410-10

Instrument 3 5/13/2010 10:17:07 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 46

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 8:30:50 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

Sample Info : In-House Blank

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\035-4602.D) 4.201

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\035-4602.D

Sample Name: IHB*20 0410-10

Instrument 3 5/13/2010 10:17:14 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 4:48:14 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0801.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0801.D

Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:10 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 5:05:03 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0802.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 - - - Sulfate 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0802.D

Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:21 AM ARM Page 1 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 4:14:39 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D) 3.107 4.212 5.882 6.582 8.350 9.491 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.491 BB 141.38943 4.42883e-2 6.26190 Sulfate Tag Value = 6.250 μg/mL 

Totals : 6.26190

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D

Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:04 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 4:31:27 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D) 3.107 4.213 5.884 6.585 8.351 9.491 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.491 BB 137.15407 4.42948e-2 6.07521 Sulfate Tag Value = 6.250 μg/mL 

Totals : 6.07521

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D

Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:10 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 58

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 6:00:06 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

Sample Info : Matrix Spike

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\036-5801.D)

 9.662 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.662 BB 270.48413 4.41878e-2 11.95209 Sulfate 

Totals : 11.95209

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\036-5801.D

Sample Name: MS/Run 1 0410-10

Instrument 1 5/14/2010 8:15:44 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 58

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 6:16:54 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

Sample Info : Matrix Spike

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\036-5802.D)

 9.661 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.661 BB 244.02638 4.41997e-2 10.78590 Sulfate 

Totals : 10.78590

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\036-5802.D

Sample Name: MS/Run 1 0410-10

Instrument 1 5/14/2010 8:15:52 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 59

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 6:33:42 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

Sample Info : Matrix Spike

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\037-5901.D)

 9.658 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.658 BB 266.11325 4.41896e-2 11.75944 Sulfate 

Totals : 11.75944

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\037-5901.D

Sample Name: MSD/Run 1 0410-10

Instrument 1 5/14/2010 8:16:01 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 59

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 6:50:29 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

Sample Info : Matrix Spike

 

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\037-5902.D)

 9.655 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.655 BB 243.85738 4.41998e-2 10.77845 Sulfate 

Totals : 10.77845

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\037-5902.D

Sample Name: MSD/Run 1 0410-10

Instrument 1 5/14/2010 8:16:10 AM ARM Page 1 of 1
Calibration 

Curve Chromatograms
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : 5/11/2010 5:55:38 PM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 9.489 1 1 1.00000e-1 1.94891 5.13107e-2 Sulfate 

 2 5.00000e-1 9.20960 5.42912e-2 

 3 5.00000 107.53530 4.64964e-2 

 4 10.00000 225.66882 4.43127e-2 

 5 15.00000 346.48825 4.32915e-2 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 1 of 2
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

50

100

150

200

250

300

12

3

4

5

Sulfate at exp. RT: 9.489

ADC1 B, ADC2 CHANNEL B

Correlation: 0.99952

Residual Std. Dev.: 5.06077

Formula: y = mx + b

 m: 22.68721

 b: -6.75574e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.2

 Level 3 : 0.02

 Level 4 : 0.01

 Level 5 : 0.006667

=====================================================================

Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 2 of 2
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 1:26:39 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D)

 Area: 1.88947

 3.104

 4.217

 9.506 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.506 MM 1.88947 5.98375e-2 1.13061e-1 Sulfate 

Totals : 1.13061e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D

Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:07 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 1:43:28 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D)

 Area: 2.00835

 3.104

 4.217

 9.503 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.503 MM 2.00835 5.89047e-2 1.18301e-1 Sulfate 

Totals : 1.18301e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D

Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:29 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:00:15 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D) 3.103 4.215 5.906 6.623 8.374 9.498 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.498 BB 9.16793 4.73257e-2 4.33879e-1 Sulfate 

Totals : 4.33879e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D

Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:01 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:17:03 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D) 3.104 4.216 5.906 6.622 8.376 9.499 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.499 BB 9.25128 4.72965e-2 4.37553e-1 Sulfate 

Totals : 4.37553e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D

Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:08 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:33:51 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D) 3.112 4.213 5.886 6.587 8.353 9.492 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.492 BB 109.14275 4.43505e-2 4.84054 Sulfate 

Totals : 4.84054

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D

Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:14 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 2:50:39 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D) 3.112 4.213 5.886 6.587 8.353 9.492 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.492 BB 105.92785 4.43588e-2 4.69883 Sulfate 

Totals : 4.69883

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D

Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:26 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:07:27 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D) 3.124 4.215 5.881 6.577 8.350 9.490 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.490 BB 228.02539 4.42083e-2 10.08061 Sulfate 

Totals : 10.08061

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D

Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:39 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:24:15 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D) 3.122 4.214 5.884 6.581 8.348 9.488 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.488 BB 223.31224 4.42110e-2 9.87287 Sulfate 

Totals : 9.87287

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D

Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:46 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:41:03 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D) 3.133 4.216 5.878 6.571 8.346 9.488 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.488 BB 352.66254 4.41621e-2 15.57433 Sulfate 

Totals : 15.57433

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D

Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:51 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 3:57:51 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D) 3.132 4.215 5.876 6.568 8.347 9.489 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.489 BB 340.31396 4.41652e-2 15.03003 Sulfate 

Totals : 15.03003

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D

Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:58 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 19

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 10:57:49 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1901.D) 3.127 4.177 5.736 6.387

 8.417

 9.583 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.583 BB 231.36612 4.42064e-2 10.22786 Sulfate 

Totals : 10.22786

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1901.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:20:54 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 19

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/11/2010 11:14:38 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1902.D) 3.127 4.177 5.735 6.386

 8.421

 9.584 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.584 BB 223.56235 4.42109e-2 9.88389 Sulfate 

Totals : 9.88389

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1902.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:21:01 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 28

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 4:00:14 AM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2801.D) 3.129 4.175 5.724 6.373

 8.423

 9.596 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.596 BB 231.33727 4.42064e-2 10.22659 Sulfate 

Totals : 10.22659

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2801.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:05 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 28

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 4:17:01 AM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2802.D) 3.129 4.177 5.728 6.379

 8.430

 9.595 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.595 BB 221.99748 4.42118e-2 9.81491 Sulfate 

Totals : 9.81491

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2802.D

Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:12 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 30

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 10:48:57 AM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3001.D) 3.124 4.215 5.883 6.581

 8.333

 9.495 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.495 BB 242.00009 4.42007e-2 10.69658 Sulfate 

Totals : 10.69658

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3001.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:34 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 30

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 11:05:45 AM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3002.D) 3.120 4.212 5.877 6.574

 8.335

 9.496 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.496 BB 219.04594 4.42136e-2 9.68482 Sulfate 

Totals : 9.68482

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3002.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:41 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 41

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 4:58:32 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-4102.D) 3.134 4.218 5.856 6.543

 8.488

 9.649 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.649 BB 241.92140 4.42008e-2 10.69311 Sulfate 

Totals : 10.69311

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-4102.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:16:08 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 50

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 10:28:28 PM Inj : 1

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5001.D) 3.137 4.194 5.758 6.415

 8.542

 9.722 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.722 BB 227.11307 4.42088e-2 10.04040 Sulfate 

Totals : 10.04040

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5001.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:17:56 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 50

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/12/2010 10:45:15 PM Inj : 2

Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/11/2010 5:55:50 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5002.D) 3.137 4.194 5.760 6.416

 8.547

 9.724 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.724 BB 201.75278 4.42253e-2 8.92257 Sulfate 

Totals : 8.92257

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5002.D

Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:18:03 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 52

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 11:38:20 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/14/2010 8:20:53 AM by ARM

 (modified after loading)

182 184 186 188 190 192 194 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5201.D) 183.329 184.418 186.068 186.759 188.672 189.845 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/14/2010 8:19:04 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

189.845 BB 231.77820 4.42062e-2 10.24603 Sulfate 

Totals : 10.24603

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5201.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 8:20:57 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 56

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 4:52:56 PM Inj : 1

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5601.D) 3.138 4.216 5.841 6.522

 8.495

 9.676 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.676 BB 242.22186 4.42006e-2 10.70636 Sulfate 

Totals : 10.70636

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5601.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 8:15:14 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 56

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/13/2010 5:09:44 PM Inj : 2

Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5602.D) 3.133 4.216 5.847 6.531

 8.491

 9.672 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.672 BB 210.46223 4.42192e-2 9.30647 Sulfate 

Totals : 9.30647

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5602.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 8:15:22 AM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 63

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/14/2010 9:57:05 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6301.D) 3.152 4.262 5.957 6.666 8.573 9.828 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.828 BB 250.22568 4.41967e-2 11.05915 Sulfate 

Totals : 11.05915

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6301.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:19:41 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 63

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/14/2010 10:13:53 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6302.D) 3.151 4.262 5.956 6.666 8.576 9.830 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.830 BB 235.69072 4.42040e-2 10.41848 Sulfate 

Totals : 10.41848

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6302.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:19:55 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 66

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/14/2010 11:37:52 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6601.D) 3.152 4.251 5.915 6.611 8.590 9.850 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.850 BB 252.76761 4.41955e-2 11.17119 Sulfate 

Totals : 11.17119

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6601.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:21:27 PM ARM Page 1 of 1
=====================================================================

Acq. Operator : KHB Seq. Line : 66

Acq. Instrument : Mr Burns Location : -

Injection Date : 5/14/2010 11:54:39 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M

Last changed : 3/23/2010 5:17:01 PM by ARM

Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Last changed : 5/13/2010 12:47:32 PM by ARM

0 2 4 6 8 10 12 14 min

μS/cm

10

20

30

40

50

60

70

80

90

 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6602.D) 3.152 4.248 5.905 6.599 8.594 9.855 - Sulfate

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 5/11/2010 5:55:38 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 B, ADC2 CHANNEL B

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 9.855 BB 234.02809 4.42049e-2 10.34520 Sulfate 

Totals : 10.34520

=====================================================================

 *** End of Report ***

Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6602.D

Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:21:35 PM ARM Page 1 of 1
 Method Information

 Method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

 Modified: 1/13/2010 at 7:06:26 AM

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 A, Metrohm

Source: Signal

Unit: mAU

Units/Volt: 100.000

Peakwidth (Data Rate): 0.027 Min (10.00 Hz)

Stop Time: No Limit

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Modified on: 1/13/2010 at 7:06:26 AM

Smithers 1/18/2010 7:20:57 AM mgb Page 1 of 1
Sequence: C:\HPCHEM\1\SEQUENCE\hplc53pg44.txt

Line Vial Sample Name Method Inj

1 Vial 7 RB/DI H2O METROHM 3

2 Vial 1 hplc53pg44 #1 METROHM 2

3 Vial 2 hplc53pg44 #2 METROHM 2

4 Vial 3 hplc53pg44 #3 METROHM 2

5 Vial 4 hplc53pg44 #4 METROHM 2

6 Vial 5 hplc53pg44 #5 METROHM 2

7 Vial 6 hplc53pg44 #LCS METROHM 2

8 Vial 7 RB/DI H2O METROHM 2

9 Vial 8 Run 1 post*50 0410-10 METROHM 2

10 Vial 9 Run 2 post*50 0410-10 METROHM 2

11 Vial 10 Run 3 post*50 0410-10 METROHM 2

12 Vial 11 Train Blk post*50 0410-10 METROHM 2

13 Vial 12 IHB post*50 0410-10 METROHM 2

14 Vial 13 M8A-R1-C1-SO3*20 0410-10 METROHM 2

15 Vial 14 M8A-R2-C1-SO3*20 0410-10 METROHM 2

16 Vial 15 M8A-R3-C1-SO3*20 0410-10 METROHM 2

17 Vial 16 M8A-BT-C1-SO3*20 0410-10 METROHM 2

18 Vial 3 hplc53pg44 #3 METROHM 2

19 Vial 4 hplc53pg44 #4 METROHM 2

20 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2

21 Vial 18 MeadWestVaco M8R2*20 0510-45 METROHM 2

22 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2

23 Vial 20 M13A-1*20 0510-135 METROHM 2

24 Vial 21 M13A-2*20 0510-135 METROHM 2

25 Vial 22 M13A-3*20 0510-135 METROHM 2

26 Vial 23 IPA Blank*20 0510-135 METROHM 2

27 Vial 3 hplc53pg44 #3 METROHM 2

28 Vial 4 hplc53pg44 #4 METROHM 2

29 Vial 3 hplc53pg44 #3 METROHM 2

30 Vial 4 hplc53pg44 #4 METROHM 2

31 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2

32 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2

33 Vial 24 MS/M8A-R1-C1-SO3 0410-10 METROHM 2

34 Vial 25 MSD/M8A-R1-C1-SO3 0410-10 METROHM 2

35 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2

36 Vial 27 MSD/MeadWestVaco M8R1 0510-45 METROHM 2

37 Vial 28 MS/M13A-1 0510-135 METROHM 2

38 Vial 29 MSD/M13A-1 0510-135 METROHM 2

39 Vial 30 M13A-3*20 0510-135 METROHM 2

40 Vial 3 hplc53pg44 #3 METROHM 2

41 Vial 4 hplc53pg44 #4 METROHM 2

42 Vial 31 Run 1*50 0410-10 METROHM 2

43 Vial 32 Run 2*50 0410-10 METROHM 2

44 Vial 33 Run 3*50 0410-10 METROHM 2

45 Vial 34 Train Blk*20 0410-10 METROHM 2

46 Vial 35 IHB*20 0410-10 METROHM 2

47 Vial 36 MS/Run 1 0410-10 METROHM 2

48 Vial 37 MSD/Run 1 0410-10 METROHM 2

49 Vial 3 hplc53pg44 #3 METROHM 2

50 Vial 4 hplc53pg44 #4 METROHM 2

51 Vial 3 hplc53pg44 #3 METROHM 2

52 Vial 4 hplc53pg44 #4 METROHM 2

53 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2

54 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2

55 Vial 3 hplc53pg44 #3 METROHM 2

56 Vial 4 hplc53pg44 #4 METROHM 2

57 Vial 31 Run 1*50 0410-10 METROHM 2

58 Vial 36 MS/Run 1 0410-10 METROHM 2

59 Vial 37 MSD/Run 1 0410-10 METROHM 2

60 Vial 3 hplc53pg44 #3 METROHM 2

61 Vial 4 hplc53pg44 #4 METROHM 2

62 Vial 3 hplc53pg44 #3 METROHM 2

63 Vial 4 hplc53pg44 #4 METROHM 2

64 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2

65 Vial 3 hplc53pg44 #3 METROHM 2

66 Vial 4 hplc53pg44 #4 METROHM 2
This Is The Last Page

Of This Report.
5/7/2010

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood MO 63042

Project Name: KCP&L ICR Testing

Project #: 

Dear Mr. Frank Stevens

The following report includes the data for the above referenced project for sample(s) 

received on 4/24/2010 at Air Toxics Ltd.

The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant 

with the project requirements or laboratory criteria with the exception of the deviations 

noted in the attached case narrative.

Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is 

committed to providing accurate data of the highest quality. Please feel free to contact

the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding 

the data in this report.

Regards,

Ausha Scott

Project Manager

Workorder #: 1004525A

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020

Hours 6:30 A.M to 5:30 PST

Page 1 of 63
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1004525A

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

04/24/2010

DATE COMPLETED: 05/06/2010

P.O. # 100-208-0001

PROJECT # KCP&L ICR Testing

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Ausha Scott

FRACTION # NAME TEST

01AB M0031-R1-TS1-C1-Tenax/M0031-R1-TS1- Modified VOST 5041A/8260

01C M0031-R1-TS1-C4-Anasorb Modified VOST 5041A/8260

02A M0031-R1-TS1-C3-Condensate Modified VOST 5041A/8260

03AB M0031-R1-TS2-C1-Tenax/M0031-R1-TS2- Modified VOST 5041A/8260

03C M0031-R1-TS2-C4-Anasorb Modified VOST 5041A/8260

04AB M0031-R1-TS3-C1-Tenax/M0031-R1-TS3- Modified VOST 5041A/8260

04C M0031-R1-TS3-C4-Anasorb Modified VOST 5041A/8260

05AB M0031-R1-TS4-C1-Tenax/M0031-R1-TS4- Modified VOST 5041A/8260

05C M0031-R1-TS4-C4-Anasorb Modified VOST 5041A/8260

06AB M0031-R2-TS1-C1-Tenax/M0031-R2-TS1- Modified VOST 5041A/8260

06C M0031-R2-TS1-C4-Anasorb Modified VOST 5041A/8260

07AB M0031-R2-TS2-C1-Tenax/M0031-R2-TS2- Modified VOST 5041A/8260

07C M0031-R2-TS2-C4-Anasorb Modified VOST 5041A/8260

08AB M0031-R2-TS3-C1-Tenax/M0031-R2-TS3- Modified VOST 5041A/8260

09A Lab Blank Modified VOST 5041A/8260

09B Lab Blank Modified VOST 5041A/8260

10A LCS Modified VOST 5041A/8260

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 2 of 63

Continued on next page
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1004525A

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

04/24/2010

DATE COMPLETED: 05/06/2010

P.O. # 100-208-0001

PROJECT # KCP&L ICR Testing

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Ausha Scott

FRACTION # NAME TEST

10B LCS Modified VOST 5041A/8260

CERTIFIED BY:

Laboratory Director

DATE:

Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, 

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

 

 

05/07/10

Page 3 of 63

This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, 

NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719
LABORATORY NARRATIVE

VOST 5041A

Civil & Environmental Consultants, Inc.

Workorder# 1004525A

Laboratory Services Since 1989

Nineteen VOST 0031 Tube and one VOA Vial-40 mL samples were received on April 24, 2010. The

laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan

mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP

helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on

the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components

into the GC/MS system for further separation. See the data sheets for the reporting limits for each

compound.

Requirement VOST 5041A ATL Modifications

Batch Certification Blanks from the same 

media as samples

Analysis of set of cartridges prior to onset of any project; 

Sampling media provided by the client is batch certified 

ahead of time, only if client provides blank cartridges.

Method blank Cartridges from the 

same media batches as 

the samples

Media batch is certified prior to use in the field. Method 

Blank is used to certify instrument is contaminant free

Connection between cartridge 

thermal desorption apparatus & 

sample purge vessel

PTFE 1/16" Teflon 

tubing

Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for 

non-CCCs

RSD +- 15 % for all 

non-CCCs

RSD </= 30 % for some compounds: Acetone, 

Bromoform, Vinyl Acetate, Bromomethane, 

Chloromethane, 1,1,2,2-Tetracholoroethane, & 

1,2,3-Trichloropropane

Receiving Notes

The Chain of Custody (COC) information for samples M0031-R1-TS3-C4-Anasorb and 

M0031-R1-TS4-C4-Anasorb did not match the entries on the sample tags with regard to sample 

identification. Therefore the information on the COC was used to process and report the samples.

Per client request, compounds that are not validated under Method 0031 collection protocols were

reported in this work order. These compounds may not be suitable for collection by Method 0031 due

to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory

analytical method 5041A/8260B is validated for all target analytes.

Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the

Anasorb. In addition the laboratory method has not been validated for recovery of these additional

compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Each tube was spiked with Dibromofluoromethane, 1,2-Dichloroethane-d4, Toluene-d8 and

4-Bromofluorobenzene prior to shipment to the field as an additional QC step. 

The recoveries of surrogates Dibromofluoromethane and 1,2-Dichloroethane-d4 in samples

Analytical Notes

Page 4 of 63
Laboratory Services Since 1989

M0031-R1-TS4-C4-Anasorb, M0031-R2-TS1-C4-Anasorb, and M0031-R2-TS2-C4-Anasorb was

outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent

tube media. Data is reported as qualified.

The recovery of surrogate Toluene-d8 in samples M0031-R1-TS1-C4-Anasorb,

M0031-R1-TS2-C4-Anasorb, M0031-R1-TS3-C4-Anasorb, M0031-R1-TS4-C4-Anasorb,

M0031-R2-TS1-C4-Anasorb, and M0031-R2-TS2-C4-Anasorb was outside control limits. It is not

possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as

qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is

defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target

compound non-detects in the samples that are associated with high bias in QC analyses have not been

flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows:

B - Compound present in laboratory blank or tube certification greater than reporting limit

(background subtraction not performed).

J - Estimated value.

E - Exceeds instrument calibration range.

S - Saturated peak.

Q - Exceeds quality control limits.

U - Compound analyzed for but not detected above the detection limit.

N - The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows:

a-File was requantified

b-File was quantified by a second column and detector

r1-File was requantified for the purpose of reissue

Definition of Data Qualifying Flags

Page 5 of 63
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax

Lab ID#: 1004525A-01AB

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 50 160

Methylene Chloride 10 340

Hexane 10 31

Benzene 10 19

Toluene 10 160

Ethyl Benzene 10 27

m,p-Xylene 10 98

o-Xylene 10 21

Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1004525A-01C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 2100 E

Bromomethane 10 44

Acetone 50 56

Methylene Chloride 10 820

Freon 12 10 39

Client Sample ID: M0031-R1-TS1-C3-Condensate

Lab ID#: 1004525A-02A

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 400 640

Methylene Chloride 80 24000 E

Chloroform 80 110

Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax

Lab ID#: 1004525A-03AB

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 50 98

Methylene Chloride 10 30

Benzene 10 14

Toluene 10 87

Page 6 of 63
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax

Lab ID#: 1004525A-03AB

Ethyl Benzene 10 13

m,p-Xylene 10 48

o-Xylene 10 11

Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1004525A-03C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1800

Bromomethane 10 56

Freon 11 10 13

Methylene Chloride 10 160

Freon 12 10 55

Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax

Lab ID#: 1004525A-04AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 44

Toluene 10 44

m,p-Xylene 10 28

Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1004525A-04C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 2200 E

Bromomethane 10 67

Freon 11 10 39

Methylene Chloride 10 2400 E

Hexane 10 10

Freon 12 10 26

Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax

Lab ID#: 1004525A-05AB

Page 7 of 63
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax

Lab ID#: 1004525A-05AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 45

Toluene 10 28

m,p-Xylene 10 15

Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1004525A-05C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1200

Bromomethane 10 54

Methylene Chloride 10 190

Freon 12 10 25

Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax

Lab ID#: 1004525A-06AB

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 50 61

Methylene Chloride 10 230

Benzene 10 11

Toluene 10 36

m,p-Xylene 10 26

Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1004525A-06C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1400

Bromomethane 10 99

Methylene Chloride 10 30

Freon 12 10 23

Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax

Lab ID#: 1004525A-07AB

Page 8 of 63
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax

Lab ID#: 1004525A-07AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 63

Toluene 10 27

m,p-Xylene 10 13

Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1004525A-07C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1200

Bromomethane 10 30

Methylene Chloride 10 130

Freon 12 10 26

Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax

Lab ID#: 1004525A-08AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 26

Toluene 10 21

m,p-Xylene 10 11

Page 9 of 63
Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax

Lab ID#: 1004525A-01AB

MODIFIED VOST 5041A/8260B

File Name: 4042918

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 05:41 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 160

3-Chloropropene 50 Not Detected

Methylene Chloride 10 340

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 31

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 19

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 160

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 10 of 63
Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax

Lab ID#: 1004525A-01AB

MODIFIED VOST 5041A/8260B

File Name: 4042918

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 05:41 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 27

m,p-Xylene 10 98

o-Xylene 10 21

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 107 70-130

Page 11 of 63
Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax

Lab ID#: 1004525A-01AB

MODIFIED VOST 5041A/8260B

File Name: 4042918

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 05:41 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 108 70-130

Toluene-d8 119 70-130

4-Bromofluorobenzene 109 70-130

Page 12 of 63
Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1004525A-01C

MODIFIED VOST 5041A/8260B

File Name: 4042911

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 02:04 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 2100 E

Vinyl Chloride 10 Not Detected

Bromomethane 10 44

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 56

3-Chloropropene 50 Not Detected

Methylene Chloride 10 820

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 13 of 63
Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1004525A-01C

MODIFIED VOST 5041A/8260B

File Name: 4042911

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 02:04 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 39

E = Exceeds instrument calibration range.

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 14 of 63
Client Sample ID: M0031-R1-TS1-C4-Anasorb

Lab ID#: 1004525A-01C

MODIFIED VOST 5041A/8260B

File Name: 4042911

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 02:04 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 62 50-150

1,2-Dichloroethane-d4 53 50-150

Toluene-d8 15 Q 50-150

Page 15 of 63
Client Sample ID: M0031-R1-TS1-C3-Condensate

Lab ID#: 1004525A-02A

MODIFIED VOST 5041A/8260B

File Name: 4042909

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 12:50 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 640

3-Chloropropene 400 Not Detected

Methylene Chloride 80 24000 E

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 Not Detected

Bromochloromethane 80 Not Detected

Chloroform 80 110

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 16 of 63
Client Sample ID: M0031-R1-TS1-C3-Condensate

Lab ID#: 1004525A-02A

MODIFIED VOST 5041A/8260B

File Name: 4042909

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 12:50 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

E = Exceeds instrument calibration range.

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Page 17 of 63
Client Sample ID: M0031-R1-TS1-C3-Condensate

Lab ID#: 1004525A-02A

MODIFIED VOST 5041A/8260B

File Name: 4042909

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 12:50 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 96 70-130

1,2-Dichloroethane-d4 93 70-130

Toluene-d8 108 70-130

4-Bromofluorobenzene 100 70-130

Page 18 of 63
Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax

Lab ID#: 1004525A-03AB

MODIFIED VOST 5041A/8260B

File Name: 4042917

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 05:16 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 98

3-Chloropropene 50 Not Detected

Methylene Chloride 10 30

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 14

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 87

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 19 of 63
Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax

Lab ID#: 1004525A-03AB

MODIFIED VOST 5041A/8260B

File Name: 4042917

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 05:16 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 13

m,p-Xylene 10 48

o-Xylene 10 11

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 102 70-130

Page 20 of 63
Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax

Lab ID#: 1004525A-03AB

MODIFIED VOST 5041A/8260B

File Name: 4042917

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 05:16 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 112 70-130

Toluene-d8 119 70-130

4-Bromofluorobenzene 107 70-130

Page 21 of 63
Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1004525A-03C

MODIFIED VOST 5041A/8260B

File Name: 4042912

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 02:28 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1800

Vinyl Chloride 10 Not Detected

Bromomethane 10 56

Chloroethane 50 Not Detected

Freon 11 10 13

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 160

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 22 of 63
Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1004525A-03C

MODIFIED VOST 5041A/8260B

File Name: 4042912

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 02:28 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 55

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 23 of 63
Client Sample ID: M0031-R1-TS2-C4-Anasorb

Lab ID#: 1004525A-03C

MODIFIED VOST 5041A/8260B

File Name: 4042912

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 02:28 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 101 50-150

1,2-Dichloroethane-d4 91 50-150

Toluene-d8 35 Q 50-150

Page 24 of 63
Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax

Lab ID#: 1004525A-04AB

MODIFIED VOST 5041A/8260B

File Name: 4042920

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 06:42 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 44

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 44

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 25 of 63
Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax

Lab ID#: 1004525A-04AB

MODIFIED VOST 5041A/8260B

File Name: 4042920

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 06:42 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 28

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 96 70-130

Page 26 of 63
Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax

Lab ID#: 1004525A-04AB

MODIFIED VOST 5041A/8260B

File Name: 4042920

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 06:42 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 98 70-130

Toluene-d8 114 70-130

4-Bromofluorobenzene 100 70-130

Page 27 of 63
Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1004525A-04C

MODIFIED VOST 5041A/8260B

File Name: 4042914

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 03:32 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 2200 E

Vinyl Chloride 10 Not Detected

Bromomethane 10 67

Chloroethane 50 Not Detected

Freon 11 10 39

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 2400 E

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 10

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 28 of 63
Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1004525A-04C

MODIFIED VOST 5041A/8260B

File Name: 4042914

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 03:32 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 26

E = Exceeds instrument calibration range.

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 29 of 63
Client Sample ID: M0031-R1-TS3-C4-Anasorb

Lab ID#: 1004525A-04C

MODIFIED VOST 5041A/8260B

File Name: 4042914

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 03:32 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 61 50-150

1,2-Dichloroethane-d4 50 50-150

Toluene-d8 15 Q 50-150

Page 30 of 63
Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax

Lab ID#: 1004525A-05AB

MODIFIED VOST 5041A/8260B

File Name: 4042921

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 07:08 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 45

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 28

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 31 of 63
Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax

Lab ID#: 1004525A-05AB

MODIFIED VOST 5041A/8260B

File Name: 4042921

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 07:08 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 15

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 95 70-130

Page 32 of 63
Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax

Lab ID#: 1004525A-05AB

MODIFIED VOST 5041A/8260B

File Name: 4042921

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/29/10 07:08 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 97 70-130

Toluene-d8 114 70-130

4-Bromofluorobenzene 101 70-130

Page 33 of 63
Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1004525A-05C

MODIFIED VOST 5041A/8260B

File Name: 4043007

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/30/10 11:32 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1200

Vinyl Chloride 10 Not Detected

Bromomethane 10 54

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 190

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 34 of 63
Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1004525A-05C

MODIFIED VOST 5041A/8260B

File Name: 4043007

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/30/10 11:32 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 25

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 35 of 63
Client Sample ID: M0031-R1-TS4-C4-Anasorb

Lab ID#: 1004525A-05C

MODIFIED VOST 5041A/8260B

File Name: 4043007

Dil. Factor: 1.00

Date of Collection: 4/21/10 

Date of Analysis: 4/30/10 11:32 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 18 Q 50-150

1,2-Dichloroethane-d4 12 Q 50-150

Toluene-d8 0 U Q 50-150

Page 36 of 63
Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax

Lab ID#: 1004525A-06AB

MODIFIED VOST 5041A/8260B

File Name: 4042922

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/29/10 08:42 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 61

3-Chloropropene 50 Not Detected

Methylene Chloride 10 230

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 11

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 36

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 37 of 63
Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax

Lab ID#: 1004525A-06AB

MODIFIED VOST 5041A/8260B

File Name: 4042922

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/29/10 08:42 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 26

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 82 70-130

Page 38 of 63
Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax

Lab ID#: 1004525A-06AB

MODIFIED VOST 5041A/8260B

File Name: 4042922

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/29/10 08:42 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 78 70-130

Toluene-d8 106 70-130

4-Bromofluorobenzene 81 70-130

Page 39 of 63
Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1004525A-06C

MODIFIED VOST 5041A/8260B

File Name: 4043008

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 12:10 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1400

Vinyl Chloride 10 Not Detected

Bromomethane 10 99

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 30

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 40 of 63
Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1004525A-06C

MODIFIED VOST 5041A/8260B

File Name: 4043008

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 12:10 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 23

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 41 of 63
Client Sample ID: M0031-R2-TS1-C4-Anasorb

Lab ID#: 1004525A-06C

MODIFIED VOST 5041A/8260B

File Name: 4043008

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 12:10 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 23 Q 50-150

1,2-Dichloroethane-d4 14 Q 50-150

Toluene-d8 0 U Q 50-150

Page 42 of 63
Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax

Lab ID#: 1004525A-07AB

MODIFIED VOST 5041A/8260B

File Name: 4043015

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 03:44 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 63

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 27

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 43 of 63
Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax

Lab ID#: 1004525A-07AB

MODIFIED VOST 5041A/8260B

File Name: 4043015

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 03:44 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 13

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 88 70-130

Page 44 of 63
Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax

Lab ID#: 1004525A-07AB

MODIFIED VOST 5041A/8260B

File Name: 4043015

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 03:44 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 82 70-130

Toluene-d8 114 70-130

4-Bromofluorobenzene 95 70-130

Page 45 of 63
Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1004525A-07C

MODIFIED VOST 5041A/8260B

File Name: 4043017

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 04:44 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1200

Vinyl Chloride 10 Not Detected

Bromomethane 10 30

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 130

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 46 of 63
Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1004525A-07C

MODIFIED VOST 5041A/8260B

File Name: 4043017

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 04:44 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 26

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 47 of 63
Client Sample ID: M0031-R2-TS2-C4-Anasorb

Lab ID#: 1004525A-07C

MODIFIED VOST 5041A/8260B

File Name: 4043017

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 04:44 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 12 Q 50-150

1,2-Dichloroethane-d4 8.7 Q 50-150

Toluene-d8 0 U Q 50-150

Page 48 of 63
Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax

Lab ID#: 1004525A-08AB

MODIFIED VOST 5041A/8260B

File Name: 4042923

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/29/10 09:38 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 26

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 21

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 49 of 63
Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax

Lab ID#: 1004525A-08AB

MODIFIED VOST 5041A/8260B

File Name: 4042923

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/29/10 09:38 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 11

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 78 70-130

Page 50 of 63
Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax

Lab ID#: 1004525A-08AB

MODIFIED VOST 5041A/8260B

File Name: 4042923

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/29/10 09:38 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 76 70-130

Toluene-d8 105 70-130

4-Bromofluorobenzene 87 70-130

Page 51 of 63
Client Sample ID: Lab Blank

Lab ID#: 1004525A-09A

MODIFIED VOST 5041A/8260B

File Name: 4042907

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/29/10 11:37 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 52 of 63
Client Sample ID: Lab Blank

Lab ID#: 1004525A-09A

MODIFIED VOST 5041A/8260B

File Name: 4042907

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/29/10 11:37 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 94 70-130

Page 53 of 63
Client Sample ID: Lab Blank

Lab ID#: 1004525A-09A

MODIFIED VOST 5041A/8260B

File Name: 4042907

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/29/10 11:37 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 98 70-130

Toluene-d8 102 70-130

4-Bromofluorobenzene 98 70-130

Page 54 of 63
Client Sample ID: Lab Blank

Lab ID#: 1004525A-09B

MODIFIED VOST 5041A/8260B

File Name: 4043006

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:53 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 55 of 63
Client Sample ID: Lab Blank

Lab ID#: 1004525A-09B

MODIFIED VOST 5041A/8260B

File Name: 4043006

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:53 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 92 70-130

Page 56 of 63
Client Sample ID: Lab Blank

Lab ID#: 1004525A-09B

MODIFIED VOST 5041A/8260B

File Name: 4043006

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:53 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 93 70-130

Toluene-d8 100 70-130

4-Bromofluorobenzene 97 70-130

Page 57 of 63
Client Sample ID: LCS

Lab ID#: 1004525A-10A

MODIFIED VOST 5041A/8260B

File Name: 4042906

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/29/10 11:12 AM

Compound %Recovery

Chloromethane 129

Vinyl Chloride 108

Bromomethane 95

Chloroethane 101

Freon 11 136 Q

2-Chloropropane 151 Q

1,1-Dichloroethene 118

Freon 113 136 Q

Carbon Disulfide 130

Acetone 98

3-Chloropropene 136 Q

Methylene Chloride 101

trans-1,2-Dichloroethene 102

Acrylonitrile 95

Hexane 131 Q

1,1-Dichloroethane 111

Vinyl Acetate Not Spiked

2,2-Dichloropropane 101

cis-1,2-Dichloroethene 96

2-Butanone (Methyl Ethyl Ketone) 90

Bromochloromethane 99

Chloroform 105

1,1,1-Trichloroethane 104

Carbon Tetrachloride 99

1,1-Dichloropropene 110

Benzene 106

1,2-Dichloroethane 99

Trichloroethene 103

1,2-Dichloropropane 107

Dibromomethane 99

Bromodichloromethane 92

cis-1,3-Dichloropropene 97

trans-1,3-Dichloropropene 100

4-Methyl-2-pentanone 94

Toluene 110

1,1,2-Trichloroethane 93

Tetrachloroethene 106

1,3-Dichloropropane 96

2-Hexanone 96

Page 58 of 63
Client Sample ID: LCS

Lab ID#: 1004525A-10A

MODIFIED VOST 5041A/8260B

File Name: 4042906

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/29/10 11:12 AM

Compound %Recovery

Dibromochloromethane 86

Chlorobenzene 108

1,2-Dibromoethane (EDB) 90

Ethyl Benzene 110

m,p-Xylene 113

o-Xylene 108

Styrene 107

Bromoform 75

1,1,2,2-Tetrachloroethane 92

1,3-Dichlorobenzene 110

1,4-Dichlorobenzene 110

1,2-Dichlorobenzene 106

Cumene 121

cis-1,4-Dichloro-2-butene 88

Bromobenzene 105

1,2,3-Trichloropropane 86

trans-1,4-Dichloro-2-butene 95

Propylbenzene 105

2-Chlorotoluene 107

4-Chlorotoluene 110

1,3,5-Trimethylbenzene 109

tert-Butylbenzene 106

1,2,4-Trimethylbenzene 106

sec-Butylbenzene 110

p-Cymene 112

1,2-Dibromo-3-chloropropane 63 Q

1,2,4-Trichlorobenzene 97

Naphthalene 85

Hexachlorobutadiene 101

1,2,3-Trichlorobenzene 91

1,1,1,2-Tetrachloroethane 101

Butylbenzene 112

Iodomethane 90

Freon 12 104

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 59 of 63
Client Sample ID: LCS

Lab ID#: 1004525A-10A

MODIFIED VOST 5041A/8260B

File Name: 4042906

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/29/10 11:12 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 98 70-130

1,2-Dichloroethane-d4 99 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 97 70-130

Page 60 of 63
Client Sample ID: LCS

Lab ID#: 1004525A-10B

MODIFIED VOST 5041A/8260B

File Name: 4043005

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:28 AM

Compound %Recovery

Chloromethane 126

Vinyl Chloride 105

Bromomethane 96

Chloroethane 82

Freon 11 133 Q

2-Chloropropane 144 Q

1,1-Dichloroethene 118

Freon 113 135 Q

Carbon Disulfide 134 Q

Acetone 88

3-Chloropropene 133 Q

Methylene Chloride 100

trans-1,2-Dichloroethene 102

Acrylonitrile 90

Hexane 127

1,1-Dichloroethane 109

Vinyl Acetate Not Spiked

2,2-Dichloropropane 100

cis-1,2-Dichloroethene 99

2-Butanone (Methyl Ethyl Ketone) 87

Bromochloromethane 97

Chloroform 107

1,1,1-Trichloroethane 105

Carbon Tetrachloride 100

1,1-Dichloropropene 112

Benzene 107

1,2-Dichloroethane 98

Trichloroethene 101

1,2-Dichloropropane 104

Dibromomethane 96

Bromodichloromethane 91

cis-1,3-Dichloropropene 96

trans-1,3-Dichloropropene 99

4-Methyl-2-pentanone 88

Toluene 111

1,1,2-Trichloroethane 93

Tetrachloroethene 108

1,3-Dichloropropane 95

2-Hexanone 93

Page 61 of 63
Client Sample ID: LCS

Lab ID#: 1004525A-10B

MODIFIED VOST 5041A/8260B

File Name: 4043005

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:28 AM

Compound %Recovery

Dibromochloromethane 84

Chlorobenzene 109

1,2-Dibromoethane (EDB) 88

Ethyl Benzene 111

m,p-Xylene 114

o-Xylene 109

Styrene 108

Bromoform 72

1,1,2,2-Tetrachloroethane 90

1,3-Dichlorobenzene 112

1,4-Dichlorobenzene 110

1,2-Dichlorobenzene 106

Cumene 122

cis-1,4-Dichloro-2-butene 78

Bromobenzene 108

1,2,3-Trichloropropane 90

trans-1,4-Dichloro-2-butene 88

Propylbenzene 108

2-Chlorotoluene 110

4-Chlorotoluene 114

1,3,5-Trimethylbenzene 112

tert-Butylbenzene 108

1,2,4-Trimethylbenzene 109

sec-Butylbenzene 113

p-Cymene 114

1,2-Dibromo-3-chloropropane 62 Q

1,2,4-Trichlorobenzene 97

Naphthalene 78

Hexachlorobutadiene 102

1,2,3-Trichlorobenzene 87

1,1,1,2-Tetrachloroethane 100

Butylbenzene 113

Iodomethane 86

Freon 12 98

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 62 of 63
Client Sample ID: LCS

Lab ID#: 1004525A-10B

MODIFIED VOST 5041A/8260B

File Name: 4043005

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:28 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 96 70-130

1,2-Dichloroethane-d4 95 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 100 70-130

Page 63 of 63
5/7/2010

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood MO 63042

Project Name: KCP&L ICR Testing

Project #: 

Dear Mr. Frank Stevens

The following report includes the data for the above referenced project for sample(s) 

received on 4/24/2010 at Air Toxics Ltd.

The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant 

with the project requirements or laboratory criteria with the exception of the deviations 

noted in the attached case narrative.

Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is 

committed to providing accurate data of the highest quality. Please feel free to contact

the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding 

the data in this report.

Regards,

Ausha Scott

Project Manager

Workorder #: 1004525B

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020

Hours 6:30 A.M to 5:30 PST

Page 1 of 58
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1004525B

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

04/24/2010

DATE COMPLETED: 05/06/2010

P.O. # 100-208-0001

PROJECT # KCP&L ICR Testing

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Ausha Scott

FRACTION # NAME TEST

08C M0031-R2-TS3-C4-Anasorb Modified VOST 5041A/8260

09AB M0031-R2-TS4-C1-Tenax/M0031-R2-TS4- Modified VOST 5041A/8260

09C M0031-R2-TS4-C4-Anasorb Modified VOST 5041A/8260

10A M0031-R2-TS4-C3-Condensate Modified VOST 5041A/8260

11AB M0031-R3-TS1-C1-Tenax/M0031-R3-TS1- Modified VOST 5041A/8260

11C M0031-R3-TS1-C3-Anasorb Modified VOST 5041A/8260

12AB M0031-R3-TS2-C1-Tenax/M0031-R3-TS2- Modified VOST 5041A/8260

12C M0031-R3-TS2-C4-Anasorb Modified VOST 5041A/8260

13AB M0031-R3-TS3-C1-Tenax/M0031-R3-TS3- Modified VOST 5041A/8260

13C M0031-R3-TS3-C4-Anasorb Modified VOST 5041A/8260

14AB M0031-R3-TS4-C1-Tenax/M0031-R3-TS4- Modified VOST 5041A/8260

14C M0031-R3-TS4-C4-Anasorb Modified VOST 5041A/8260

15A M0031-R3-TS4-C3-Condensate Modified VOST 5041A/8260

16A Lab Blank Modified VOST 5041A/8260

16B Lab Blank Modified VOST 5041A/8260

17A LCS Modified VOST 5041A/8260

17B LCS Modified VOST 5041A/8260

CERTIFIED BY:

Laboratory Director

DATE:

Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, 

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

 

 

05/07/10

Page 2 of 58

This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, 

NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719
LABORATORY NARRATIVE

VOST 5041A

Civil & Environmental Consultants, Inc.

Workorder# 1004525B

Laboratory Services Since 1989

Seventeen VOST 0031 Tube and two VOA Vial-40 mL samples were received on April 24, 2010. The

laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan

mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP

helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on

the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components

into the GC/MS system for further separation. See the data sheets for the reporting limits for each

compound.

Requirement VOST 5041A ATL Modifications

Batch Certification Blanks from the same 

media as samples

Analysis of set of cartridges prior to onset of any project; 

Sampling media provided by the client is batch certified 

ahead of time, only if client provides blank cartridges.

Method blank Cartridges from the 

same media batches as 

the samples

Media batch is certified prior to use in the field. Method 

Blank is used to certify instrument is contaminant free

Connection between cartridge 

thermal desorption apparatus & 

sample purge vessel

PTFE 1/16" Teflon 

tubing

Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for 

non-CCCs

RSD +- 15 % for all 

non-CCCs

RSD </= 30 % for some compounds: Acetone, 

Bromoform, Vinyl Acetate, Bromomethane, 

Chloromethane, 1,1,2,2-Tetracholoroethane, & 

1,2,3-Trichloropropane

Receiving Notes

There were no receiving discrepancies.

Per client request, compounds that are not validated under Method 0031 collection protocols were

reported in this work order. These compounds may not be suitable for collection by Method 0031 due

to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory

analytical method 5041A/8260B is validated for all target analytes.

Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the

Anasorb. In addition the laboratory method has not been validated for recovery of these additional

compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Each tube was spiked with Dibromofluoromethane, 1,2-Dichloroethane-d4, Toluene-d8 and

4-Bromofluorobenzene prior to shipment to the field as an additional QC step. 

The recoveries of surrogates Dibromofluoromethane, 1,2-Dichloroethane-d4, and Toluene-d8 in

samples M0031-R2-TS3-C4-Anasorb, M0031-R2-TS4-C4-Anasorb, M0031-R3-TS1-C3-Anasorb,

M0031-R3-TS2-C4-Anasorb, M0031-R3-TS3-C4-Anasorb and M0031-R3-TS4-C4-Anasorb was

Analytical Notes

Page 3 of 58
Laboratory Services Since 1989

outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent

tube media. Data is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is

defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target

compound non-detects in the samples that are associated with high bias in QC analyses have not been

flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows:

B - Compound present in laboratory blank or tube certification greater than reporting limit

(background subtraction not performed).

J - Estimated value.

E - Exceeds instrument calibration range.

S - Saturated peak.

Q - Exceeds quality control limits.

U - Compound analyzed for but not detected above the detection limit.

N - The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows:

a-File was requantified

b-File was quantified by a second column and detector

r1-File was requantified for the purpose of reissue

Definition of Data Qualifying Flags

Page 4 of 58
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1004525B-08C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1300

Bromomethane 10 77

Methylene Chloride 10 28

Freon 12 10 26

Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax

Lab ID#: 1004525B-09AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 42

Toluene 10 31

m,p-Xylene 10 13

Client Sample ID: M0031-R2-TS4-C4-Anasorb

Lab ID#: 1004525B-09C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1500

Bromomethane 10 67

Methylene Chloride 10 70

Freon 12 10 23

Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1004525B-10A

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 400 710

Methylene Chloride 80 24000 E

Chloroform 80 110

Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax

Lab ID#: 1004525B-11AB

Compound (ng) (ng)

Rpt. Limit Amount

Page 5 of 58
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax

Lab ID#: 1004525B-11AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 27

Toluene 10 17

Client Sample ID: M0031-R3-TS1-C3-Anasorb

Lab ID#: 1004525B-11C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1500

Bromomethane 10 64

Methylene Chloride 10 20

Freon 12 10 27

Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax

Lab ID#: 1004525B-12AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 31

Toluene 10 13

Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1004525B-12C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 2800 E

Bromomethane 10 100

Methylene Chloride 10 68

Freon 12 10 27

Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax

Lab ID#: 1004525B-13AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 68

Toluene 10 15

Page 6 of 58
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1004525B-13C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 5400 E

Bromomethane 10 99

Methylene Chloride 10 36

Freon 12 10 29

Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax

Lab ID#: 1004525B-14AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 54

Toluene 10 18

Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1004525B-14C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1800

Bromomethane 10 60

Methylene Chloride 10 44

Freon 12 10 31

Client Sample ID: M0031-R3-TS4-C3-Condensate

Lab ID#: 1004525B-15A

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 400 650

Methylene Chloride 80 23000 E

Chloroform 80 85

Page 7 of 58
Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1004525B-08C

MODIFIED VOST 5041A/8260B

File Name: 4043009

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 12:43 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1300

Vinyl Chloride 10 Not Detected

Bromomethane 10 77

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 28

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 8 of 58
Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1004525B-08C

MODIFIED VOST 5041A/8260B

File Name: 4043009

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 12:43 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 26

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 9 of 58
Client Sample ID: M0031-R2-TS3-C4-Anasorb

Lab ID#: 1004525B-08C

MODIFIED VOST 5041A/8260B

File Name: 4043009

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 12:43 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 23 Q 50-150

1,2-Dichloroethane-d4 15 Q 50-150

Toluene-d8 0 U Q 50-150

Page 10 of 58
Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax

Lab ID#: 1004525B-09AB

MODIFIED VOST 5041A/8260B

File Name: 4043014

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 03:16 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 42

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 31

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 11 of 58
Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax

Lab ID#: 1004525B-09AB

MODIFIED VOST 5041A/8260B

File Name: 4043014

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 03:16 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 13

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 87 70-130

Page 12 of 58
Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax

Lab ID#: 1004525B-09AB

MODIFIED VOST 5041A/8260B

File Name: 4043014

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 03:16 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 78 70-130

Toluene-d8 113 70-130

4-Bromofluorobenzene 85 70-130

Page 13 of 58
Client Sample ID: M0031-R2-TS4-C4-Anasorb

Lab ID#: 1004525B-09C

MODIFIED VOST 5041A/8260B

File Name: 4043018

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 05:20 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1500

Vinyl Chloride 10 Not Detected

Bromomethane 10 67

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 70

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 14 of 58
Client Sample ID: M0031-R2-TS4-C4-Anasorb

Lab ID#: 1004525B-09C

MODIFIED VOST 5041A/8260B

File Name: 4043018

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 05:20 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 23

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 15 of 58
Client Sample ID: M0031-R2-TS4-C4-Anasorb

Lab ID#: 1004525B-09C

MODIFIED VOST 5041A/8260B

File Name: 4043018

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 05:20 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 8.8 Q 50-150

1,2-Dichloroethane-d4 6.4 Q 50-150

Toluene-d8 0 U Q 50-150

Page 16 of 58
Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1004525B-10A

MODIFIED VOST 5041A/8260B

File Name: 4043011

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 01:48 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 710

3-Chloropropene 400 Not Detected

Methylene Chloride 80 24000 E

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 Not Detected

Bromochloromethane 80 Not Detected

Chloroform 80 110

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 17 of 58
Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1004525B-10A

MODIFIED VOST 5041A/8260B

File Name: 4043011

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 01:48 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

E = Exceeds instrument calibration range.

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Page 18 of 58
Client Sample ID: M0031-R2-TS4-C3-Condensate

Lab ID#: 1004525B-10A

MODIFIED VOST 5041A/8260B

File Name: 4043011

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 01:48 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 95 70-130

1,2-Dichloroethane-d4 98 70-130

Toluene-d8 107 70-130

4-Bromofluorobenzene 98 70-130

Page 19 of 58
Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax

Lab ID#: 1004525B-11AB

MODIFIED VOST 5041A/8260B

File Name: 4043016

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 04:11 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 27

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 17

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 20 of 58
Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax

Lab ID#: 1004525B-11AB

MODIFIED VOST 5041A/8260B

File Name: 4043016

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 04:11 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 86 70-130

Page 21 of 58
Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax

Lab ID#: 1004525B-11AB

MODIFIED VOST 5041A/8260B

File Name: 4043016

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 04:11 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 83 70-130

Toluene-d8 118 70-130

4-Bromofluorobenzene 93 70-130

Page 22 of 58
Client Sample ID: M0031-R3-TS1-C3-Anasorb

Lab ID#: 1004525B-11C

MODIFIED VOST 5041A/8260B

File Name: 4043019

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 06:05 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1500

Vinyl Chloride 10 Not Detected

Bromomethane 10 64

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 20

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 23 of 58
Client Sample ID: M0031-R3-TS1-C3-Anasorb

Lab ID#: 1004525B-11C

MODIFIED VOST 5041A/8260B

File Name: 4043019

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 06:05 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 27

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 24 of 58
Client Sample ID: M0031-R3-TS1-C3-Anasorb

Lab ID#: 1004525B-11C

MODIFIED VOST 5041A/8260B

File Name: 4043019

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 06:05 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 28 Q 50-150

1,2-Dichloroethane-d4 18 Q 50-150

Toluene-d8 0 U Q 50-150

Page 25 of 58
Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax

Lab ID#: 1004525B-12AB

MODIFIED VOST 5041A/8260B

File Name: 4050310

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 02:56 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 31

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 13

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 26 of 58
Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax

Lab ID#: 1004525B-12AB

MODIFIED VOST 5041A/8260B

File Name: 4050310

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 02:56 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 92 70-130

Page 27 of 58
Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax

Lab ID#: 1004525B-12AB

MODIFIED VOST 5041A/8260B

File Name: 4050310

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 02:56 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 90 70-130

Toluene-d8 114 70-130

4-Bromofluorobenzene 96 70-130

Page 28 of 58
Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1004525B-12C

MODIFIED VOST 5041A/8260B

File Name: 4050315

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:32 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 2800 E

Vinyl Chloride 10 Not Detected

Bromomethane 10 100

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 68

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 29 of 58
Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1004525B-12C

MODIFIED VOST 5041A/8260B

File Name: 4050315

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:32 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 27

E = Exceeds instrument calibration range.

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 30 of 58
Client Sample ID: M0031-R3-TS2-C4-Anasorb

Lab ID#: 1004525B-12C

MODIFIED VOST 5041A/8260B

File Name: 4050315

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:32 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 17 Q 50-150

1,2-Dichloroethane-d4 11 Q 50-150

Toluene-d8 0 U Q 50-150

Page 31 of 58
Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax

Lab ID#: 1004525B-13AB

MODIFIED VOST 5041A/8260B

File Name: 4050311

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 03:39 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 68

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 15

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 32 of 58
Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax

Lab ID#: 1004525B-13AB

MODIFIED VOST 5041A/8260B

File Name: 4050311

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 03:39 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 90 70-130

Page 33 of 58
Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax

Lab ID#: 1004525B-13AB

MODIFIED VOST 5041A/8260B

File Name: 4050311

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 03:39 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 87 70-130

Toluene-d8 113 70-130

4-Bromofluorobenzene 91 70-130

Page 34 of 58
Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1004525B-13C

MODIFIED VOST 5041A/8260B

File Name: 4050316

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:59 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 5400 E

Vinyl Chloride 10 Not Detected

Bromomethane 10 99

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 36

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 35 of 58
Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1004525B-13C

MODIFIED VOST 5041A/8260B

File Name: 4050316

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:59 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 29

E = Exceeds instrument calibration range.

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 36 of 58
Client Sample ID: M0031-R3-TS3-C4-Anasorb

Lab ID#: 1004525B-13C

MODIFIED VOST 5041A/8260B

File Name: 4050316

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:59 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 28 Q 50-150

1,2-Dichloroethane-d4 16 Q 50-150

Toluene-d8 0 U Q 50-150

Page 37 of 58
Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax

Lab ID#: 1004525B-14AB

MODIFIED VOST 5041A/8260B

File Name: 4050312

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 04:12 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 54

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 18

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 38 of 58
Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax

Lab ID#: 1004525B-14AB

MODIFIED VOST 5041A/8260B

File Name: 4050312

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 04:12 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 93 70-130

Page 39 of 58
Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax

Lab ID#: 1004525B-14AB

MODIFIED VOST 5041A/8260B

File Name: 4050312

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 04:12 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 93 70-130

Toluene-d8 119 70-130

4-Bromofluorobenzene 96 70-130

Page 40 of 58
Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1004525B-14C

MODIFIED VOST 5041A/8260B

File Name: 4050317

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 06:27 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 1800

Vinyl Chloride 10 Not Detected

Bromomethane 10 60

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 44

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 41 of 58
Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1004525B-14C

MODIFIED VOST 5041A/8260B

File Name: 4050317

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 06:27 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 31

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 42 of 58
Client Sample ID: M0031-R3-TS4-C4-Anasorb

Lab ID#: 1004525B-14C

MODIFIED VOST 5041A/8260B

File Name: 4050317

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 06:27 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 26 Q 50-150

1,2-Dichloroethane-d4 18 Q 50-150

Toluene-d8 5.2 Q 50-150

Page 43 of 58
Client Sample ID: M0031-R3-TS4-C3-Condensate

Lab ID#: 1004525B-15A

MODIFIED VOST 5041A/8260B

File Name: 4043012

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 02:14 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 650

3-Chloropropene 400 Not Detected

Methylene Chloride 80 23000 E

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 Not Detected

Bromochloromethane 80 Not Detected

Chloroform 80 85

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 44 of 58
Client Sample ID: M0031-R3-TS4-C3-Condensate

Lab ID#: 1004525B-15A

MODIFIED VOST 5041A/8260B

File Name: 4043012

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 02:14 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

E = Exceeds instrument calibration range.

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Page 45 of 58
Client Sample ID: M0031-R3-TS4-C3-Condensate

Lab ID#: 1004525B-15A

MODIFIED VOST 5041A/8260B

File Name: 4043012

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 4/30/10 02:14 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 94 70-130

1,2-Dichloroethane-d4 93 70-130

Toluene-d8 106 70-130

4-Bromofluorobenzene 96 70-130

Page 46 of 58
Client Sample ID: Lab Blank

Lab ID#: 1004525B-16A

MODIFIED VOST 5041A/8260B

File Name: 4043006

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:53 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 47 of 58
Client Sample ID: Lab Blank

Lab ID#: 1004525B-16A

MODIFIED VOST 5041A/8260B

File Name: 4043006

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:53 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 92 70-130

Page 48 of 58
Client Sample ID: Lab Blank

Lab ID#: 1004525B-16A

MODIFIED VOST 5041A/8260B

File Name: 4043006

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:53 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 93 70-130

Toluene-d8 100 70-130

4-Bromofluorobenzene 97 70-130

Page 49 of 58
Client Sample ID: Lab Blank

Lab ID#: 1004525B-16B

MODIFIED VOST 5041A/8260B

File Name: 4050305

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:48 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 50 of 58
Client Sample ID: Lab Blank

Lab ID#: 1004525B-16B

MODIFIED VOST 5041A/8260B

File Name: 4050305

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:48 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 95 70-130

Page 51 of 58
Client Sample ID: Lab Blank

Lab ID#: 1004525B-16B

MODIFIED VOST 5041A/8260B

File Name: 4050305

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:48 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 95 70-130

Toluene-d8 105 70-130

4-Bromofluorobenzene 99 70-130

Page 52 of 58
Client Sample ID: LCS

Lab ID#: 1004525B-17A

MODIFIED VOST 5041A/8260B

File Name: 4043005

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:28 AM

Compound %Recovery

Chloromethane 126

Vinyl Chloride 105

Bromomethane 96

Chloroethane 82

Freon 11 133 Q

2-Chloropropane 144 Q

1,1-Dichloroethene 118

Freon 113 135 Q

Carbon Disulfide 134 Q

Acetone 88

3-Chloropropene 133 Q

Methylene Chloride 100

trans-1,2-Dichloroethene 102

Acrylonitrile 90

Hexane 127

1,1-Dichloroethane 109

Vinyl Acetate Not Spiked

2,2-Dichloropropane 100

cis-1,2-Dichloroethene 99

2-Butanone (Methyl Ethyl Ketone) 87

Bromochloromethane 97

Chloroform 107

1,1,1-Trichloroethane 105

Carbon Tetrachloride 100

1,1-Dichloropropene 112

Benzene 107

1,2-Dichloroethane 98

Trichloroethene 101

1,2-Dichloropropane 104

Dibromomethane 96

Bromodichloromethane 91

cis-1,3-Dichloropropene 96

trans-1,3-Dichloropropene 99

4-Methyl-2-pentanone 88

Toluene 111

1,1,2-Trichloroethane 93

Tetrachloroethene 108

1,3-Dichloropropane 95

2-Hexanone 93

Page 53 of 58
Client Sample ID: LCS

Lab ID#: 1004525B-17A

MODIFIED VOST 5041A/8260B

File Name: 4043005

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:28 AM

Compound %Recovery

Dibromochloromethane 84

Chlorobenzene 109

1,2-Dibromoethane (EDB) 88

Ethyl Benzene 111

m,p-Xylene 114

o-Xylene 109

Styrene 108

Bromoform 72

1,1,2,2-Tetrachloroethane 90

1,3-Dichlorobenzene 112

1,4-Dichlorobenzene 110

1,2-Dichlorobenzene 106

Cumene 122

cis-1,4-Dichloro-2-butene 78

Bromobenzene 108

1,2,3-Trichloropropane 90

trans-1,4-Dichloro-2-butene 88

Propylbenzene 108

2-Chlorotoluene 110

4-Chlorotoluene 114

1,3,5-Trimethylbenzene 112

tert-Butylbenzene 108

1,2,4-Trimethylbenzene 109

sec-Butylbenzene 113

p-Cymene 114

1,2-Dibromo-3-chloropropane 62 Q

1,2,4-Trichlorobenzene 97

Naphthalene 78

Hexachlorobutadiene 102

1,2,3-Trichlorobenzene 87

1,1,1,2-Tetrachloroethane 100

Butylbenzene 113

Iodomethane 86

Freon 12 98

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 54 of 58
Client Sample ID: LCS

Lab ID#: 1004525B-17A

MODIFIED VOST 5041A/8260B

File Name: 4043005

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 4/30/10 10:28 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 96 70-130

1,2-Dichloroethane-d4 95 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 100 70-130

Page 55 of 58
Client Sample ID: LCS

Lab ID#: 1004525B-17B

MODIFIED VOST 5041A/8260B

File Name: 4050304

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:04 AM

Compound %Recovery

Chloromethane 138

Vinyl Chloride 108

Bromomethane 105

Chloroethane 88

Freon 11 143 Q

2-Chloropropane 149 Q

1,1-Dichloroethene 119

Freon 113 146 Q

Carbon Disulfide 138 Q

Acetone 98

3-Chloropropene 138 Q

Methylene Chloride 99

trans-1,2-Dichloroethene 104

Acrylonitrile 95

Hexane 138 Q

1,1-Dichloroethane 112

Vinyl Acetate Not Spiked

2,2-Dichloropropane 100

cis-1,2-Dichloroethene 100

2-Butanone (Methyl Ethyl Ketone) 75

Bromochloromethane 98

Chloroform 109

1,1,1-Trichloroethane 106

Carbon Tetrachloride 103

1,1-Dichloropropene 111

Benzene 111

1,2-Dichloroethane 101

Trichloroethene 104

1,2-Dichloropropane 110

Dibromomethane 96

Bromodichloromethane 95

cis-1,3-Dichloropropene 96

trans-1,3-Dichloropropene 98

4-Methyl-2-pentanone 85

Toluene 111

1,1,2-Trichloroethane 94

Tetrachloroethene 110

1,3-Dichloropropane 96

2-Hexanone 87

Page 56 of 58
Client Sample ID: LCS

Lab ID#: 1004525B-17B

MODIFIED VOST 5041A/8260B

File Name: 4050304

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:04 AM

Compound %Recovery

Dibromochloromethane 85

Chlorobenzene 108

1,2-Dibromoethane (EDB) 90

Ethyl Benzene 111

m,p-Xylene 114

o-Xylene 107

Styrene 107

Bromoform 76

1,1,2,2-Tetrachloroethane 91

1,3-Dichlorobenzene 111

1,4-Dichlorobenzene 109

1,2-Dichlorobenzene 103

Cumene 125

cis-1,4-Dichloro-2-butene 84

Bromobenzene 105

1,2,3-Trichloropropane 89

trans-1,4-Dichloro-2-butene 88

Propylbenzene 106

2-Chlorotoluene 106

4-Chlorotoluene 111

1,3,5-Trimethylbenzene 108

tert-Butylbenzene 107

1,2,4-Trimethylbenzene 105

sec-Butylbenzene 111

p-Cymene 114

1,2-Dibromo-3-chloropropane 65 Q

1,2,4-Trichlorobenzene 98

Naphthalene 77

Hexachlorobutadiene 103

1,2,3-Trichlorobenzene 90

1,1,1,2-Tetrachloroethane 102

Butylbenzene 115

Iodomethane 73

Freon 12 110

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 57 of 58
Client Sample ID: LCS

Lab ID#: 1004525B-17B

MODIFIED VOST 5041A/8260B

File Name: 4050304

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:04 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 100 70-130

1,2-Dichloroethane-d4 98 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 95 70-130

Page 58 of 58


5/7/2010

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood MO 63042

Project Name: KCP&L ICR Testing

Project #: 

Dear Mr. Frank Stevens

The following report includes the data for the above referenced project for sample(s) 

received on 4/24/2010 at Air Toxics Ltd.

The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant 

with the project requirements or laboratory criteria with the exception of the deviations 

noted in the attached case narrative.

Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is 

committed to providing accurate data of the highest quality. Please feel free to contact

the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding 

the data in this report.

Regards,

Ausha Scott

Project Manager

Workorder #: 1004525C

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020

Hours 6:30 A.M to 5:30 PST

Page 1 of 26
Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

WORK ORDER #: 1004525C

CLIENT: BILL TO: 

PHONE:

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

314-686-4565

314-656-4595

04/24/2010

DATE COMPLETED: 05/06/2010

P.O. # 100-208-0001

PROJECT # KCP&L ICR Testing

Work Order Summary

FAX:

DATE RECEIVED: CONTACT: Ausha Scott

FRACTION # NAME TEST

16AB M0031-BT-TS1-C1-Tenax/M0031-BT-TS1 Modified VOST 5041A/8260

16C M0031-BT-TS1-C4-Anasorb Modified VOST 5041A/8260

17A M0031-BT-TS1-C3-Condensate Modified VOST 5041A/8260

18AB M0031-Trip Blank-TS1-C1-Tenax/M0031-T Modified VOST 5041A/8260

18C M0031-Trip Blank-TS1-C4-Anasorb Modified VOST 5041A/8260

19A Lab Blank Modified VOST 5041A/8260

20A LCS Modified VOST 5041A/8260

CERTIFIED BY:

Laboratory Director

DATE:

Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, 

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

 

 

05/07/10

Page 2 of 26

This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, 

NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719
LABORATORY NARRATIVE

VOST 5041A

Civil & Environmental Consultants, Inc.

Workorder# 1004525C

Laboratory Services Since 1989

Six VOST 0031 Tube and one VOA Vial-40 mL samples were received on April 24, 2010. The

laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan

mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP

helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on

the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components

into the GC/MS system for further separation. See the data sheets for the reporting limits for each

compound.

Requirement VOST 5041A ATL Modifications

Batch Certification Blanks from the same 

media as samples

Analysis of set of cartridges prior to onset of any project; 

Sampling media provided by the client is batch certified 

ahead of time, only if client provides blank cartridges.

Method blank Cartridges from the 

same media batches as 

the samples

Media batch is certified prior to use in the field. Method 

Blank is used to certify instrument is contaminant free

Connection between cartridge 

thermal desorption apparatus & 

sample purge vessel

PTFE 1/16" Teflon 

tubing

Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for 

non-CCCs

RSD +- 15 % for all 

non-CCCs

RSD </= 30 % for some compounds: Acetone, 

Bromoform, Vinyl Acetate, Bromomethane, 

Chloromethane, 1,1,2,2-Tetracholoroethane, & 

1,2,3-Trichloropropane

Receiving Notes

There were no receiving discrepancies.

Per client request, compounds that are not validated under Method 0031 collection protocols were

reported in this work order. These compounds may not be suitable for collection by Method 0031 due

to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory

analytical method 5041A/8260B is validated for all target analytes.

Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the

Anasorb. In addition the laboratory method has not been validated for recovery of these additional

compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Each tube was spiked with Dibromofluoromethane, 1,2-Dichloroethane-d4, Toluene-d8 and

4-Bromofluorobenzene prior to shipment to the field as an additional QC step. 

The recoveries of surrogates Dibromofluoromethane, 1,2-Dichloroethane-d4, and Toluene-d8 in

samples M0031-BT-TS1-C4-Anasorb and M0031-Trip Blank-TS1-C4-Anasorb was outside control

limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data

Analytical Notes

Page 3 of 26
Laboratory Services Since 1989

is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is

defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target

compound non-detects in the samples that are associated with high bias in QC analyses have not been

flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows:

B - Compound present in laboratory blank or tube certification greater than reporting limit

(background subtraction not performed).

J - Estimated value.

E - Exceeds instrument calibration range.

S - Saturated peak.

Q - Exceeds quality control limits.

U - Compound analyzed for but not detected above the detection limit.

N - The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows:

a-File was requantified

b-File was quantified by a second column and detector

r1-File was requantified for the purpose of reissue

Definition of Data Qualifying Flags

Page 4 of 26
MODIFIED VOST 5041A/8260B

Summary of Detected Compounds

Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax

Lab ID#: 1004525C-16AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 170

Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1004525C-16C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 320

Methylene Chloride 10 48

Client Sample ID: M0031-BT-TS1-C3-Condensate

Lab ID#: 1004525C-17A

Compound (ng) (ng)

Rpt. Limit Amount

Acetone 400 620

Methylene Chloride 80 26000 E

Chloroform 80 98

Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax

Lab ID#: 1004525C-18AB

Compound (ng) (ng)

Rpt. Limit Amount

Methylene Chloride 10 14

Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1004525C-18C

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 670

Page 5 of 26
Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax

Lab ID#: 1004525C-16AB

MODIFIED VOST 5041A/8260B

File Name: 4050309

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 02:01 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 170

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 6 of 26
Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax

Lab ID#: 1004525C-16AB

MODIFIED VOST 5041A/8260B

File Name: 4050309

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 02:01 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 98 70-130

Page 7 of 26
Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax

Lab ID#: 1004525C-16AB

MODIFIED VOST 5041A/8260B

File Name: 4050309

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 02:01 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 89 70-130

Toluene-d8 118 70-130

4-Bromofluorobenzene 85 70-130

Page 8 of 26
Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1004525C-16C

MODIFIED VOST 5041A/8260B

File Name: 4050314

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:04 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 320

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 48

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 9 of 26
Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1004525C-16C

MODIFIED VOST 5041A/8260B

File Name: 4050314

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:04 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 10 of 26
Client Sample ID: M0031-BT-TS1-C4-Anasorb

Lab ID#: 1004525C-16C

MODIFIED VOST 5041A/8260B

File Name: 4050314

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 05:04 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 12 Q 50-150

1,2-Dichloroethane-d4 24 Q 50-150

Toluene-d8 7.6 Q 50-150

Page 11 of 26
Client Sample ID: M0031-BT-TS1-C3-Condensate

Lab ID#: 1004525C-17A

MODIFIED VOST 5041A/8260B

File Name: 4050306

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 12:13 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 400 Not Detected

Vinyl Chloride 80 Not Detected

Bromomethane 80 Not Detected

Chloroethane 400 Not Detected

Freon 11 80 Not Detected

2-Chloropropane 400 Not Detected

1,1-Dichloroethene 80 Not Detected

Freon 113 80 Not Detected

Carbon Disulfide 80 Not Detected

Acetone 400 620

3-Chloropropene 400 Not Detected

Methylene Chloride 80 26000 E

trans-1,2-Dichloroethene 80 Not Detected

Acrylonitrile 400 Not Detected

Hexane 80 Not Detected

1,1-Dichloroethane 80 Not Detected

Vinyl Acetate 400 Not Detected

2,2-Dichloropropane 400 Not Detected

cis-1,2-Dichloroethene 80 Not Detected

2-Butanone (Methyl Ethyl Ketone) 400 Not Detected

Bromochloromethane 80 Not Detected

Chloroform 80 98

1,1,1-Trichloroethane 80 Not Detected

Carbon Tetrachloride 80 Not Detected

1,1-Dichloropropene 80 Not Detected

Benzene 80 Not Detected

1,2-Dichloroethane 80 Not Detected

Trichloroethene 80 Not Detected

1,2-Dichloropropane 80 Not Detected

Dibromomethane 80 Not Detected

Bromodichloromethane 80 Not Detected

cis-1,3-Dichloropropene 80 Not Detected

trans-1,3-Dichloropropene 80 Not Detected

4-Methyl-2-pentanone 400 Not Detected

Toluene 80 Not Detected

1,1,2-Trichloroethane 80 Not Detected

Tetrachloroethene 80 Not Detected

1,3-Dichloropropane 80 Not Detected

2-Hexanone 400 Not Detected

Page 12 of 26
Client Sample ID: M0031-BT-TS1-C3-Condensate

Lab ID#: 1004525C-17A

MODIFIED VOST 5041A/8260B

File Name: 4050306

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 12:13 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 80 Not Detected

Chlorobenzene 80 Not Detected

1,2-Dibromoethane (EDB) 80 Not Detected

Ethyl Benzene 80 Not Detected

m,p-Xylene 80 Not Detected

o-Xylene 80 Not Detected

Styrene 80 Not Detected

Bromoform 80 Not Detected

1,1,2,2-Tetrachloroethane 80 Not Detected

1,3-Dichlorobenzene 80 Not Detected

1,4-Dichlorobenzene 80 Not Detected

1,2-Dichlorobenzene 80 Not Detected

Cumene 80 Not Detected

cis-1,4-Dichloro-2-butene 400 Not Detected

Bromobenzene 80 Not Detected

1,2,3-Trichloropropane 80 Not Detected

trans-1,4-Dichloro-2-butene 400 Not Detected

Propylbenzene 80 Not Detected

2-Chlorotoluene 80 Not Detected

4-Chlorotoluene 80 Not Detected

1,3,5-Trimethylbenzene 80 Not Detected

tert-Butylbenzene 80 Not Detected

1,2,4-Trimethylbenzene 80 Not Detected

sec-Butylbenzene 80 Not Detected

p-Cymene 80 Not Detected

1,2-Dibromo-3-chloropropane 400 Not Detected

1,2,4-Trichlorobenzene 400 Not Detected

Naphthalene 400 Not Detected

Hexachlorobutadiene 400 Not Detected

1,2,3-Trichlorobenzene 400 Not Detected

1,1,1,2-Tetrachloroethane 80 Not Detected

Butylbenzene 80 Not Detected

Iodomethane 400 Not Detected

Freon 12 80 Not Detected

E = Exceeds instrument calibration range.

Container Type: VOA Vial-40 mL

Surrogates %Recovery Limits

Method

Page 13 of 26
Client Sample ID: M0031-BT-TS1-C3-Condensate

Lab ID#: 1004525C-17A

MODIFIED VOST 5041A/8260B

File Name: 4050306

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 12:13 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 93 70-130

1,2-Dichloroethane-d4 91 70-130

Toluene-d8 105 70-130

4-Bromofluorobenzene 98 70-130

Page 14 of 26
Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax

Lab ID#: 1004525C-18AB

MODIFIED VOST 5041A/8260B

File Name: 4050308

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 01:36 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 14

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 15 of 26
Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax

Lab ID#: 1004525C-18AB

MODIFIED VOST 5041A/8260B

File Name: 4050308

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 01:36 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Dibromofluoromethane 94 70-130

Page 16 of 26
Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax

Lab ID#: 1004525C-18AB

MODIFIED VOST 5041A/8260B

File Name: 4050308

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 01:36 PM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 87 70-130

Toluene-d8 114 70-130

4-Bromofluorobenzene 75 70-130

Page 17 of 26
Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1004525C-18C

MODIFIED VOST 5041A/8260B

File Name: 4050313

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 04:37 PM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 670

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 18 of 26
Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1004525C-18C

MODIFIED VOST 5041A/8260B

File Name: 4050313

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 04:37 PM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Q = Exceeds Quality Control limits.

Container Type: VOST 0031 Tube

Surrogates %Recovery Limits

Method

Page 19 of 26
Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb

Lab ID#: 1004525C-18C

MODIFIED VOST 5041A/8260B

File Name: 4050313

Dil. Factor: 1.00

Date of Collection: 4/22/10 

Date of Analysis: 5/3/10 04:37 PM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 10 Q 50-150

1,2-Dichloroethane-d4 9.8 Q 50-150

Toluene-d8 0 U Q 50-150

Page 20 of 26
Client Sample ID: Lab Blank

Lab ID#: 1004525C-19A

MODIFIED VOST 5041A/8260B

File Name: 4050305

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:48 AM

Compound (ng) (ng)

Rpt. Limit Amount

Chloromethane 50 Not Detected

Vinyl Chloride 10 Not Detected

Bromomethane 10 Not Detected

Chloroethane 50 Not Detected

Freon 11 10 Not Detected

2-Chloropropane 50 Not Detected

1,1-Dichloroethene 10 Not Detected

Freon 113 10 Not Detected

Carbon Disulfide 10 Not Detected

Acetone 50 Not Detected

3-Chloropropene 50 Not Detected

Methylene Chloride 10 Not Detected

trans-1,2-Dichloroethene 10 Not Detected

Acrylonitrile 50 Not Detected

Hexane 10 Not Detected

1,1-Dichloroethane 10 Not Detected

Vinyl Acetate 50 Not Detected

2,2-Dichloropropane 50 Not Detected

cis-1,2-Dichloroethene 10 Not Detected

2-Butanone (Methyl Ethyl Ketone) 50 Not Detected

Bromochloromethane 10 Not Detected

Chloroform 10 Not Detected

1,1,1-Trichloroethane 10 Not Detected

Carbon Tetrachloride 10 Not Detected

1,1-Dichloropropene 10 Not Detected

Benzene 10 Not Detected

1,2-Dichloroethane 10 Not Detected

Trichloroethene 10 Not Detected

1,2-Dichloropropane 10 Not Detected

Dibromomethane 10 Not Detected

Bromodichloromethane 10 Not Detected

cis-1,3-Dichloropropene 10 Not Detected

trans-1,3-Dichloropropene 10 Not Detected

4-Methyl-2-pentanone 50 Not Detected

Toluene 10 Not Detected

1,1,2-Trichloroethane 10 Not Detected

Tetrachloroethene 10 Not Detected

1,3-Dichloropropane 10 Not Detected

2-Hexanone 50 Not Detected

Page 21 of 26
Client Sample ID: Lab Blank

Lab ID#: 1004525C-19A

MODIFIED VOST 5041A/8260B

File Name: 4050305

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:48 AM

Compound (ng) (ng)

Rpt. Limit Amount

Dibromochloromethane 10 Not Detected

Chlorobenzene 10 Not Detected

1,2-Dibromoethane (EDB) 10 Not Detected

Ethyl Benzene 10 Not Detected

m,p-Xylene 10 Not Detected

o-Xylene 10 Not Detected

Styrene 10 Not Detected

Bromoform 10 Not Detected

1,1,2,2-Tetrachloroethane 10 Not Detected

1,3-Dichlorobenzene 10 Not Detected

1,4-Dichlorobenzene 10 Not Detected

1,2-Dichlorobenzene 10 Not Detected

Cumene 10 Not Detected

cis-1,4-Dichloro-2-butene 50 Not Detected

Bromobenzene 10 Not Detected

1,2,3-Trichloropropane 10 Not Detected

trans-1,4-Dichloro-2-butene 50 Not Detected

Propylbenzene 10 Not Detected

2-Chlorotoluene 10 Not Detected

4-Chlorotoluene 10 Not Detected

1,3,5-Trimethylbenzene 10 Not Detected

tert-Butylbenzene 10 Not Detected

1,2,4-Trimethylbenzene 10 Not Detected

sec-Butylbenzene 10 Not Detected

p-Cymene 10 Not Detected

1,2-Dibromo-3-chloropropane 50 Not Detected

1,2,4-Trichlorobenzene 50 Not Detected

Naphthalene 50 Not Detected

Hexachlorobutadiene 50 Not Detected

1,2,3-Trichlorobenzene 50 Not Detected

1,1,1,2-Tetrachloroethane 10 Not Detected

Butylbenzene 10 Not Detected

Iodomethane 50 Not Detected

Freon 12 10 Not Detected

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Dibromofluoromethane 95 70-130

Page 22 of 26
Client Sample ID: Lab Blank

Lab ID#: 1004525C-19A

MODIFIED VOST 5041A/8260B

File Name: 4050305

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:48 AM

Surrogates %Recovery Limits

Method

1,2-Dichloroethane-d4 95 70-130

Toluene-d8 105 70-130

4-Bromofluorobenzene 99 70-130

Page 23 of 26
Client Sample ID: LCS

Lab ID#: 1004525C-20A

MODIFIED VOST 5041A/8260B

File Name: 4050304

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:04 AM

Compound %Recovery

Chloromethane 138

Vinyl Chloride 108

Bromomethane 105

Chloroethane 88

Freon 11 143 Q

2-Chloropropane 149 Q

1,1-Dichloroethene 119

Freon 113 146 Q

Carbon Disulfide 138 Q

Acetone 98

3-Chloropropene 138 Q

Methylene Chloride 99

trans-1,2-Dichloroethene 104

Acrylonitrile 95

Hexane 138 Q

1,1-Dichloroethane 112

Vinyl Acetate Not Spiked

2,2-Dichloropropane 100

cis-1,2-Dichloroethene 100

2-Butanone (Methyl Ethyl Ketone) 75

Bromochloromethane 98

Chloroform 109

1,1,1-Trichloroethane 106

Carbon Tetrachloride 103

1,1-Dichloropropene 111

Benzene 111

1,2-Dichloroethane 101

Trichloroethene 104

1,2-Dichloropropane 110

Dibromomethane 96

Bromodichloromethane 95

cis-1,3-Dichloropropene 96

trans-1,3-Dichloropropene 98

4-Methyl-2-pentanone 85

Toluene 111

1,1,2-Trichloroethane 94

Tetrachloroethene 110

1,3-Dichloropropane 96

2-Hexanone 87

Page 24 of 26
Client Sample ID: LCS

Lab ID#: 1004525C-20A

MODIFIED VOST 5041A/8260B

File Name: 4050304

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:04 AM

Compound %Recovery

Dibromochloromethane 85

Chlorobenzene 108

1,2-Dibromoethane (EDB) 90

Ethyl Benzene 111

m,p-Xylene 114

o-Xylene 107

Styrene 107

Bromoform 76

1,1,2,2-Tetrachloroethane 91

1,3-Dichlorobenzene 111

1,4-Dichlorobenzene 109

1,2-Dichlorobenzene 103

Cumene 125

cis-1,4-Dichloro-2-butene 84

Bromobenzene 105

1,2,3-Trichloropropane 89

trans-1,4-Dichloro-2-butene 88

Propylbenzene 106

2-Chlorotoluene 106

4-Chlorotoluene 111

1,3,5-Trimethylbenzene 108

tert-Butylbenzene 107

1,2,4-Trimethylbenzene 105

sec-Butylbenzene 111

p-Cymene 114

1,2-Dibromo-3-chloropropane 65 Q

1,2,4-Trichlorobenzene 98

Naphthalene 77

Hexachlorobutadiene 103

1,2,3-Trichlorobenzene 90

1,1,1,2-Tetrachloroethane 102

Butylbenzene 115

Iodomethane 73

Freon 12 110

Q = Exceeds Quality Control limits.

Container Type: NA - Not Applicable

Surrogates %Recovery Limits

Method

Page 25 of 26
Client Sample ID: LCS

Lab ID#: 1004525C-20A

MODIFIED VOST 5041A/8260B

File Name: 4050304

Dil. Factor: 1.00

Date of Collection: NA 

Date of Analysis: 5/3/10 11:04 AM

Surrogates %Recovery Limits

Method

Dibromofluoromethane 100 70-130

1,2-Dichloroethane-d4 98 70-130

Toluene-d8 104 70-130

4-Bromofluorobenzene 95 70-130

Page 26 of 26
Air Toxics Ltd. Sample Receipt Confirmation Cover Page

Thank you for choosing Air Toxics Ltd. We have received your samples and have listed any 

Sample Receipt Descrepancies below.

In order to expedite analysis and reporting, please review the attached information for accuracy.

For corrections call:

ATL will proceed with the analysis as specified on the Chain of Custody and Sample Receipt 

Summary page.

Ausha Scott at 916-985-1000

The following discrepancy has been observed:

We have found a discrepancy between the Chain of Custody (COC) and the sample tags. The 

samples labeled M0031-R1-TS3-C4-Anasorb and M0031-R1-TS4-C4-Anasorb on the COC 

are labeled as M0031-R1-TS3-C3-Condensate and M0031-R1-TS4-C3-Condensate on the 

sample tags. ATL will report the sample identifications on the COC unless otherwise notified.

Please note : The Sample Receipt Confirmation, including the total workorder charge, is 

subject to change upon secondary review. Our aim is to provide a confirmation to you in a 

timely manner. Sample Receipt Discrepancies, if any, may not include discrepancies 

regarding sample receipt pressure(s). Additionally, the Chain of Custody (COC) will be 

provided with the final report.

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020

Hours 6:30 A.M to 5:30 P.M. PST
SAMPLE RECEIPT SUMMARY

WORKORDER 1004525A

Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

Client Phone

314-686-4565

Fax

314-656-4595

Date Completed:

Date Received: 4/24/10

PO#:

Project#:

Total $:

Logged By:

100-208-0001

$ 5,000.00

KCP&L ICR Testing

MW

Sales Rep: TL

Date Promised: 05/10/10

Fraction Sample # Analysis Collected Amount$

01A M0031-R1-TS1-C1-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

02A M0031-R1-TS1-C2-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

03A M0031-R1-TS1-C3-Condensate Modified VOST 5041A/8260B 4/21/2010 $250.00

04A M0031-R1-TS1-C4-Anasorb Modified VOST 5041A/8260B 4/21/2010 $250.00

05A M0031-R1-TS2-C1-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

06A M0031-R1-TS2-C2-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

07A M0031-R1-TS2-C4-Anasorb Modified VOST 5041A/8260B 4/21/2010 $250.00

08A M0031-R1-TS3-C1-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

09A M0031-R1-TS3-C2-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

10A M0031-R1-TS3-C4-Anasorb Modified VOST 5041A/8260B 4/21/2010 $250.00

11A M0031-R1-TS4-C1-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

12A M0031-R1-TS4-C2-Tenax Modified VOST 5041A/8260B 4/21/2010 $250.00

13A M0031-R1-TS4-C4-Anasorb Modified VOST 5041A/8260B 4/21/2010 $250.00

14A M0031-R2-TS1-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

15A M0031-R2-TS1-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

16A M0031-R2-TS1-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

17A M0031-R2-TS2-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

18A M0031-R2-TS2-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

19A M0031-R2-TS2-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

BILL TO:

Reporting Method:Modified VOST 5041A/8260B (Full list)

Analysis Code: Other MS

Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1
SAMPLE RECEIPT SUMMARY Continued

Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

Client Phone

314-686-4565

Fax

314-656-4595

Date Completed:

Date Received: 4/24/10

PO#:

Project#:

Total $:

Logged By:

100-208-0001

$ 5,000.00

KCP&L ICR Testing

MW

Sales Rep: TL

Date Promised: 05/10/10

Fraction Sample # Analysis Collected Amount$

20A M0031-R2-TS3-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

BILL TO:

Reporting Method:Modified VOST 5041A/8260B (Full list)

Analysis Code: Other MS

Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 2
SAMPLE RECEIPT SUMMARY

WORKORDER 1004525B

Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

Client Phone

314-686-4565

Fax

314-656-4595

Date Completed:

Date Received: 4/24/10

PO#:

Project#:

Total $:

Logged By:

100-208-0001

$ 4,750.00

KCP&L ICR Testing

MW

Sales Rep: TL

Date Promised: 05/10/10

Fraction Sample # Analysis Collected Amount$

21A M0031-R2-TS3-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

22A M0031-R2-TS3-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

23A M0031-R2-TS4-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

24A M0031-R2-TS4-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

25A M0031-R2-TS4-C3-Condensate Modified VOST 5041A/8260B 4/22/2010 $250.00

26A M0031-R2-TS4-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

27A M0031-R3-TS1-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

28A M0031-R3-TS1-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

29A M0031-R3-TS1-C3-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

30A M0031-R3-TS2-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

31A M0031-R3-TS2-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

32A M0031-R3-TS2-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

33A M0031-R3-TS3-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

34A M0031-R3-TS3-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

35A M0031-R3-TS3-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

36A M0031-R3-TS4-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

37A M0031-R3-TS4-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

38A M0031-R3-TS4-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

39A M0031-R3-TS4-C3-Condensate Modified VOST 5041A/8260B 4/22/2010 $250.00

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

BILL TO:

Reporting Method:Modified VOST 5041A/8260B (Full list)

Analysis Code: Other MS

Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1
SAMPLE RECEIPT SUMMARY

WORKORDER 1004525C

Mr. Frank Stevens

Civil & Environmental Consultants, 

Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

Client Phone

314-686-4565

Fax

314-656-4595

Date Completed:

Date Received: 4/24/10

PO#:

Project#:

Total $:

Logged By:

100-208-0001

$ 1,750.00

KCP&L ICR Testing

MW

Sales Rep: TL

Date Promised: 05/10/10

Fraction Sample # Analysis Collected Amount$

40A M0031-BT-TS1-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

41A M0031-BT-TS1-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

42A M0031-BT-TS1-C3-Condensate Modified VOST 5041A/8260B 4/22/2010 $250.00

43A M0031-BT-TS1-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

44A M0031-Trip Blank-TS1-C1-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

45A M0031-Trip Blank-TS1-C2-Tenax Modified VOST 5041A/8260B 4/22/2010 $250.00

46A M0031-Trip Blank-TS1-C4-Anasorb Modified VOST 5041A/8260B 4/22/2010 $250.00

Mr. Frank Stevens

Civil & Environmental Consultants, Inc.

4848 Park 370 Blvd.,

Suite F

Hazelwood, MO 63042

BILL TO:

Reporting Method:Modified VOST 5041A/8260B (Full list)

Analysis Code: Other MS

Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1





Method : Modified VOST 5041A/8260B (Full list)

CAS Number Compound Rpt. Limit (ng)

CAS Number Compound

74-87-3 Chloromethane 10

75-01-4 Vinyl Chloride 10

74-83-9 Bromomethane 10

75-00-3 Chloroethane 10

75-69-4 Freon 11 10

75-29-6 2-Chloropropane 50

75-35-4 1,1-Dichloroethene 10

76-13-1 Freon 113 10

75-15-0 Carbon Disulfide 10

67-64-1 Acetone 50

107-05-1 3-Chloropropene 50

75-09-2 Methylene Chloride 10

156-60-5 trans-1,2-Dichloroethene 10

107-13-1 Acrylonitrile 50

110-54-3 Hexane 10

75-34-3 1,1-Dichloroethane 10

108-05-4 Vinyl Acetate 50

594-20-7 2,2-Dichloropropane 50

156-59-2 cis-1,2-Dichloroethene 10

78-93-3 2-Butanone (Methyl Ethyl Ketone) 50

74-97-5 Bromochloromethane 10

67-66-3 Chloroform 10

71-55-6 1,1,1-Trichloroethane 10

56-23-5 Carbon Tetrachloride 10

563-58-6 1,1-Dichloropropene 10

71-43-2 Benzene 10

107-06-2 1,2-Dichloroethane 10

79-01-6 Trichloroethene 10

78-87-5 1,2-Dichloropropane 10

74-95-3 Dibromomethane 10

75-27-4 Bromodichloromethane 10

10061-01-5 cis-1,3-Dichloropropene 10

10061-02-6 trans-1,3-Dichloropropene 10

108-10-1 4-Methyl-2-pentanone 50

108-88-3 Toluene 10

79-00-5 1,1,2-Trichloroethane 10

127-18-4 Tetrachloroethene 10

142-28-9 1,3-Dichloropropane 10

Page 1
Method : Modified VOST 5041A/8260B (Full list)

CAS Number Compound Rpt. Limit (ng)

591-78-6 2-Hexanone 50

124-48-1 Dibromochloromethane 10

108-90-7 Chlorobenzene 10

106-93-4 1,2-Dibromoethane (EDB) 10

100-41-4 Ethyl Benzene 10

108-38-3 m,p-Xylene 10

95-47-6 o-Xylene 10

100-42-5 Styrene 10

75-25-2 Bromoform 10

79-34-5 1,1,2,2-Tetrachloroethane 10

541-73-1 1,3-Dichlorobenzene 10

106-46-7 1,4-Dichlorobenzene 10

95-50-1 1,2-Dichlorobenzene 10

98-82-8 Cumene 10

1476-11-5 cis-1,4-Dichloro-2-butene 50

108-86-1 Bromobenzene 10

96-18-4 1,2,3-Trichloropropane 10

110-57-6 trans-1,4-Dichloro-2-butene 50

103-65-1 Propylbenzene 10

95-49-8 2-Chlorotoluene 10

106-43-4 4-Chlorotoluene 10

108-67-8 1,3,5-Trimethylbenzene 10

98-06-6 tert-Butylbenzene 10

95-63-6 1,2,4-Trimethylbenzene 10

135-98-8 sec-Butylbenzene 10

99-87-6 p-Cymene 10

96-12-8 1,2-Dibromo-3-chloropropane 50

120-82-1 1,2,4-Trichlorobenzene 50

91-20-3 Naphthalene 50

87-68-3 Hexachlorobutadiene 50

87-61-6 1,2,3-Trichlorobenzene 50

630-20-6 1,1,1,2-Tetrachloroethane 10

104-51-8 Butylbenzene 10

74-88-4 Iodomethane 50

75-71-8 Freon 12 10

CAS Number Surrogate Method Limits

1868-53-7 Dibromofluoromethane 70-130

17060-07-0 1,2-Dichloroethane-d4 70-130

Page 2
Method : Modified VOST 5041A/8260B (Full list)

CAS Number Surrogate Method Limits

2037-26-5 Toluene-d8 70-130

460-00-4 4-Bromofluorobenzene 70-130

Page 3

APPENDIX F 

ANALYTICAL DATA - FUELS 

 


















APPENDIX G 

CALIBRATIONS SHEETS, CERTIFICATIONS 

 







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APPENDIX H 

PROCESS DATA