# Summary of Results

## Compound Sample ID / Catch Weight (ug)

CTM-033-R2-C3-NaOH CTM-033-R3-C3-NaOH CTM-033-R4-C3-NaOH Hydrogen cyanide 64.8 ND 61.2 ND 71.0 ND

CTM-033-BT-C3-NaOH Hydrogen cyanide 44.7 ND Company

Analyst Parameters # Samples C & E Consultants, Inc. KHB EPA CTM-033 3 Runs & 1 blank Client # Job # PO # Report Date 100-208 0410-10 100-208-0001 5/14/2010

0410-10-hcn-res 5/17/2010

## Compound Sample ID / Catch Weight (ug)

M26A-R1-C3-H2SO4 M26A-R2-C3-H2SO4 M26A-R3-C3-H2SO4 Hydrogen fluoride 311 ND 337 ND 288 ND Hydrogen chloride 304 ND 329 ND 281 ND

M26A-BT-C3-H2SO4 Hydrogen fluoride 113 ND Hydrogen chloride 150 J Company

Analyst Parameters # Samples C & E Consultants, Inc. A RM EPA Method 26A 3 Runs & 1 blank Client # Job # PO # Report Date 100-208 0410-10 100-208-0001 5/14/2010

0410-10-m26a-res 5/17/2010

## Compound Sample ID / Catch Weight (ug)

M8A-R1-C1-SO3 M8A-R2-C1-SO3 M8A-R3-C1-SO3 Sulfuric Acid 117 J 81.3 J 87.6 J

M8A-BT-C1-SO3 Sulfuric Acid 18.1 ND Company

Analyst Parameters # Samples C & E Consultants, Inc. KHB NCASI Method 8A 3 Runs & 1 blank Client # Job # PO # Report Date 100-208 0410-10 100-208-0001 5/14/2010

0410-10-m8a-res 5/17/2010

## Compound Sample ID / Catch Weight (ug)

Run 1 Run 2 Run 3 Sulfate 7,137 7,482 6,634

Train Blk Sulfate 4.76 ND Company

Analyst Parameters # Samples C & E Consultants, Inc. KHB HPLC/IC Sulfate Analysis 3 Runs & 1 blank Client # Job # PO # Report Date 100-208 0410-10 100-208-0001 5/14/2010

0410-10-sulfate-res 5/17/2010

## Compound Sample ID / Catch Weight (mg)

Run 1 Run 2 Run 3 47 mm Filter 2.0 0.7 2.5 >2.5 PM 0.8 2.7 0.9 < 2.5 PM 0.2 0.7 0.1

TOTAL 3.0 4.1 3.4

Blank Train 47 mm Filter 0.3 >2.5 PM 0.1 < 2.5 PM 0.1

TOTAL 0.4 Company

Analyst Parameters # Samples C & E Consultants, Inc. KTH EPA OTM-027 4 Runs & 1 blank Client # Job # PO # Report Date 100-208 100-208-0001 0410-10 5/17/2010

0410-10-ctm027-res 5/17/2010

## Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Run 1 Run 2 Run 3 Net Organic Catch 6.1 4.8 7.4 Corrected Inorganic 19.2 17.1 11.0 TB Corrected CPM 23.3 19.9 16.4

Train Blank Organic Catch 2.9 If Train Blank Corrected CPM is >2.0 mg, Inorganic Catch 1.9 then sample correction is 2.0 mg. CPM 4.7

Company

Analyst Parameters # Samples C & E Consultants, Inc. KTH EPA OTM-028 3 Runs & 1 blank Client # Job # PO # Report Date 100-208 0410-10 100-208-0001 5/14/2010

0410-10-OTM028-res 5/17/2010

# ResultsMDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL)LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)pHCatchWeight(ug)QualCTM-033-R2-C3-NaOH 028-3701.D 028-3702.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 906 14.0 64.8 NDCTM-033-R3-C3-NaOH 029-3801.D 029-3802.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 856 12.0 61.2 NDCTM-033-R4-C3-NaOH 030-3901.D 030-3902.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 993 12.5 71.0 NDCTM-033-BT-C3-NaOH 031-4001.D 031-4002.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 625 14.0 44.7 ND0.1N NaOH - RB 007-0801.D 007-0802.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 1 1.00 0.0143 NDLD/CTM-033-R2-C3-NaOH 050-7601.D 050-7602.D HPLC50PG78.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 906 64.8 NDdifference 0.0%MS/CTM-033-R2-C3-NaOH 051-9301.D 051-9302.D HPLC50PG78.M 8.01 8.03 0.3 1.15 1.16 0.4 1.15 1 0.525 0.606Spike Amount (ug) 0.520Native Amount (ug) 0.000Spike Recovery (%) 117%MSD/CTM-033-R2-C3-NaOH 052-9401.D 052-9402.D HPLC50PG78.M 8.05 8.06 0.1 1.12 1.13 0.2 1.13 1 0.525 0.591Spike Amount (ug) 0.520Native Amount (ug) 0.000Spike Recovery (%) 114%hplc50pg78 #LCS 006-0701.D 006-0702.D HPLC50PG78.M 8.29 8.26 0.3 0.916 0.900 0.9 0.908 1 1.00 0.908Spike Amount (ug) 0.840Spike Recovery (%) 108%Hydrogen cyanideCompanyAnalystParameters# SamplesC & E Consultants, Inc.KHBEPA CTM-0333 Runs & 1 blankClient #Job #PO #Report Date100-2080410-10100-208-00015/14/20100410-10-hcn-res5/17/2010MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)CFF -->HFDFVol(mL)CatchWeight(ug)QualM26A-R1-C3-H2SO4 011-0901.D 011-0902.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 739 311 NDM26A-R2-C3-H2SO4 014-1201.D 014-1202.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 799 337 NDM26A-R3-C3-H2SO4 015-1301.D 015-1302.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 684 288 NDM26A-BT-C3-H2SO4 016-1401.D 016-1402.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 267 113 NDReagent Blank 007-0801.D 007-0802.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 1 1.00 0.0211 NDHPLC51p92 #LCS 006-0701.D 006-0702.D HPLC51PG92.M 2.78 2.78 0.0 4.07 4.07 0.0 4.07 1.000 1 1.00 4.07Spike Amount (ug) 4.00Spike Recovery (%) 102%MS M26A-R1-C3-H2SO4 012-1001.D 012-1002.D HPLC51PG92.M 2.78 2.78 0.0 3.57 3.55 0.2 3.56 1.000 1 10.0 35.6Spike Amount (ug) 30.0Native Amount (ug) 0.00Spike Recovery (%) 119%MSD M26A-R1-C3-H2SO4 013-1101.D 013-1102.D HPLC51PG92.M 2.78 2.78 0.0 3.53 3.53 0.1 3.53 1.000 1 10.0 35.3Spike Amount (ug) 30.0Native Amount (ug) 0.00Spike Recovery (%) 118%HF as FluorideCompanyAnalystParameters# SamplesC & E Consultants, Inc.ARMEPA Method 26A3 Runs & 1 blankClient #Job #PO #Report Date100-2080410-10100-208-00015/14/20100410-10-m26a-res5/17/2010MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)CFCl -->HClDFVol(mL)CatchWeight(ug)QualM26A-R1-C3-H2SO4 011-0901.D 011-0902.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 739 304 NDM26A-R2-C3-H2SO4 014-1201.D 014-1202.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 799 329 NDM26A-R3-C3-H2SO4 015-1301.D 015-1302.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 684 281 NDM26A-BT-C3-H2SO4 016-1401.D 016-1402.D HPLC51PG92.M 3.72 3.72 0.1 0.0279 0.0267 2.2 0.0273 1.028 20 267 150 JReagent Blank 007-0801.D 007-0802.D HPLC51PG92.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 1 1.00 0.0206 NDHPLC51p92 #LCS 006-0701.D 006-0702.D HPLC51PG92.M 3.73 3.73 0.0 3.76 3.76 0.1 3.76 1.000 1 1.00 3.76Spike Amount (ug) 4.00Spike Recovery (%) 94.0%MS M26A-R1-C3-H2SO4 012-1001.D 012-1002.D HPLC51PG92.M 3.73 3.73 0.0 2.91 2.91 0.0 2.91 1.000 1 10.0 29.1Spike Amount (ug) 30.0Native Amount (ug) 0.00Spike Recovery (%) 97.1%MSD M26A-R1-C3-H2SO4 013-1101.D 013-1102.D HPLC51PG92.M 3.73 3.73 0.0 2.90 2.90 0.0 2.90 1.000 1 10.0 29.0Spike Amount (ug) 30.0Native Amount (ug) 0.00Spike Recovery (%) 96.7%HCl as ChlorideCompanyAnalystParameters# SamplesC & E Consultants, Inc.ARMEPA Method 26A3 Runs & 1 blankClient #Job #PO #Report Date100-2080410-10100-208-00015/14/20100410-10-m26a-res5/17/2010MDL 0.0118 (ug/mL) Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL) Upper Curve Limit 15.0 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)CF SO4----->H2SO4DFVol(mL)CatchWeight(ug)QualM8A-R1-C1-SO3 013-1401.D 013-1402.D HPLC53PG44.M 9.56 9.57 0.1 0.0945 0.0919 1.4 0.0932 1.021 20 61.7 117 JM8A-R2-C1-SO3 014-1501.D 014-1502.D HPLC53PG44.M 9.59 9.59 0.1 0.0526 0.0536 1.0 0.0531 1.021 20 75.0 81.3 JM8A-R3-C1-SO3 015-1601.D 015-1602.D HPLC53PG44.M 9.60 9.60 0.0 0.0645 0.0635 0.8 0.0640 1.021 20 67.0 87.6 JM8A-BT-C1-SO3 016-1701.D 016-1702.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 1.021 20 75.0 18.1 NDRB/DI H2O 007-0801.D 007-0802.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 1.021 1 1.00 0.0120 NDhplc53pg44 #LCS 006-0701.D 006-0702.D HPLC53PG44.M 9.49 9.49 0.0 6.26 6.08 1.5 6.17 1.000 1 1.00 6.17Spike Amount (ug) 6.25Spike Recovery (%) 98.7%MS/M8A-R1-C1-SO3 024-3302.D 025-3401.D HPLC53PG44.M 9.51 9.51 0.0 2.81 2.88 1.3 2.85 1.000 1 10.0 28.5Spike Amount (ug) 30.0Native Amount (ug) 0.932Spike Recovery (%) 91.8%MSD/M8A-R1-C1-SO3 025-3402.D 026-3501.D HPLC53PG44.M 9.51 9.51 0.0 3.08 2.93 2.5 3.00 1.000 1 10.0 30.0Spike Amount (ug) 30.0Native Amount (ug) 0.932Spike Recovery (%) 97.0%H2SO4as SulfateCompanyAnalystParameters# SamplesC & E Consultants, Inc.KHBNCASI Method 8A3 Runs & 1 blankClient #Job #PO #Report Date100-2080410-10100-208-00015/14/20100410-10-m8a-res5/17/2010MDL 0.0118 (ug/mL) Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL) Upper Curve Limit 15.0 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualRun 1 031-5701.D 031-5702.D HPLC53PG44.M 9.67 9.67 0.0 6.79 7.39 4.3 7.09 50.33 20.0 7,137Run 2 032-4301.D 032-4302.D HPLC53PG44.M 9.65 9.65 0.0 7.60 7.27 2.2 7.43 50.33 20.0 7,482Run 3 033-4401.D 033-4402.D HPLC53PG44.M 9.66 9.67 0.1 6.82 6.36 3.5 6.59 50.33 20.0 6,634Train Blk 034-4501.D 034-4502.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 20.17 20.0 4.76 NDIHB 035-4601.D 035-4602.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 20.14 20.0 4.75 NDRB/DI H2O 007-0801.D 007-0802.D HPLC53PG44.M NA NA NA 0.0118 0.0118 0.0 0.0118 1 20.0 0.236 NDhplc53pg44 #LCS 006-0701.D 006-0702.D HPLC53PG44.M 9.49 9.49 0.0 6.26 6.08 1.5 6.17 1 1.00 6.17Spike Amount (ug) 6.25Spike Recovery (%) 98.7%MS/Run 1 036-5801.D 036-5802.D HPLC53PG44.M 9.66 9.66 0.0 12.0 10.8 5.1 11.4 1 10.0 114Spike Amount (ug) 30.0Native Amount (ug) 71.4Spike Recovery (%) 141%MSD/Run 1 037-5901.D 037-5902.D HPLC53PG44.M 9.66 9.66 0.0 11.8 10.8 4.4 11.3 1 10.0 113Spike Amount (ug) 30.0Native Amount (ug) 71.4Spike Recovery (%) 138%SulfateCompanyAnalystParameters# SamplesC & E Consultants, Inc.KHBHPLC/IC Sulfate Analysis3 Runs & 1 blankClient #Job #PO #Report Date100-2080410-10100-208-00015/14/20100410-10-sulfate-res5/17/2010

## Other Test Method 027 - Particulate Determination - Data Analysis

Analysis of Particulate Recovery

Sample ID Run 1 Run 2 Run 3 Blank Train

47 mm Filter ID 2420 Dates 2421 Dates 2422 Dates 2423 Dates Final wt. (g) 1st 0.115233 5/11/10 9A 0.112507 5/11/10 9A 0.115278 5/11/10 9A 0.112585 5/11/10 9A Final wt. (g) 2nd 0.115144 5/11/10 4P 0.112464 5/11/10 4P 0.115274 5/11/10 4P 0.112599 5/11/10 4P Final Tare Weight (g) 0.113114 4/14/10 0.111768 4/14/10 0.112817 4/14/10 0.112308 4/14/10

Net filter catch (mg) 2.0 0.7 2.5 0.3

>2.5 PM Acetone Rinses Beaker number 11422 Dates 11423 Dates 11424 Dates 11425 Dates Final wt (g) 1st 1.904289 5/11/10 9A 1.910792 5/11/10 9A 1.909630 5/11/10 9A 1.908709 5/11/10 9A Final wt (g) 2nd 1.904353 5/11/10 4P 1.910808 5/11/10 4P 1.909641 5/11/10 4P 1.908728 5/11/10 4P Beaker tare (g) 1.903529 5/5/10 1.908136 5/5/10 1.908790 5/5/10 1.908673 5/5/10 Acetone vol (mL) 34.0 35.0 20.0 20.0 >2.5 PM Catch (mg) 0.8 2.7 0.9 0.1

<2.5 PM Acetone Rinses Beaker number 11426 Dates 11429 Dates 11430 Dates 11431 Dates Final wt (g) 1st 1.913072 5/11/10 9A 1.910419 5/11/10 9A 1.897631 5/11/10 9A 1.895270 5/11/10 9A Final wt (g) 2nd 1.913073 5/11/10 4P 1.910422 5/11/10 4P 1.897642 5/11/10 4P 1.895260 5/11/10 4P Beaker tare (g) 1.912878 5/5/10 1.909704 5/6/10 1.897503 5/6/10 1.895163 5/6/10 Acetone vol (mL) 32.0 25.0 22.0 31.0 <2.5 PM Catch (mg) 0.19 0.72 0.14 0.10
Total particulate (mg) 3.0 4.1 3.4 0.4



## In-House Blank Acetone Analysis Blank beaker number 11414 Dates

Blank volume (mL) 200 Dates Final wt (g) 1st 1.921755 5/11/10 9A Beaker tare (g) 1.922098 5/4/10 Final wt (g) 2nd 1.921783 5/11/10 4P Max acetone residue (g) 0.0016 Acetone residue (g) -0.0003 Company

Analyst Parameters # Samples C & E Consultants, Inc. KTH EPA OTM-027 4 Runs & 1 blank Client # Job # PO # Report Date 100-208 100-208-0001 0410-10 5/17/2010

0410-10-ctm027-res 5/17/2010Analysis of Condensible Particulate RecoverySample ID NumberTrain Blank Run 1 Run 2 Run 3OrganicBeaker Number11412 11409 11410 11411Initial MeCl2/Acetone Volume, mL 80.0 104 126 102Lab MeCl2 Volume, mL 165 Dates 165 Dates 165 Dates 165 DatesFinal Weight, g 1.916835 5/11/10 9A 1.917380 5/11/10 9A 1.909652 5/11/10 9A 1.917204 5/11/10 9AReweigh, Final, g 1.916878 5/11/10 4P 1.917444 5/11/10 4P 1.909696 5/11/10 4P 1.917286 5/11/10 4PBeaker Tare, g 1.914028 5/4/10 1.911348 5/4/10 1.904885 5/4/10 1.909837 5/4/10Net Organic Catch, mg 2.9 6.1 4.8 7.4InorganicBeaker Number11444Dates11441Dates11442Dates11443DatesFinal Weight, g 1.906756 5/11/10 9A 1.919771 5/11/10 9A 1.920327 5/11/10 9A 1.918502 5/11/10 9AReweigh, Final, g 1.906968 5/11/10 4P 1.919840 5/11/10 4P 1.920389 5/11/10 4P 1.918560 5/11/10 4PBeaker Tare, g 1.905090 5/6/10 1.897897 5/6/10 1.900583 5/6/10 1.905295 5/6/10H2O FV, mL 140 340 335 305Resuspended Volume, mL 100 100 100 100Removed Pre-aliquot, mL 0.500 0.500 0.500 0.500Pre-aliquot CF 1.004 1.001 1.001 1.002Removed Post-aliquot, mL 0.500 0.500 0.500 0.500Post-aliquot CF 1.005 1.005 1.005 1.005Net Inorganic, mg 1.9 22.1 19.9 13.4Ammonium Correction, mg 0.0 2.9 2.8 2.4Corrected Inorganic, mg 1.9 19.2 17.1 11.0Condensible Particulate Matter, mg 4.7 25.3 21.9 18.4TB Corrected CPM, mg 23.3 19.9 16.4----------------------------------------------------------In-House Blank Analyses-----------------------------------------------------------------Type Blank MeCl Blank Type Blank H2O Blank Type Blank AcetoneBeaker Number11413Dates Beaker Number11445Dates Beaker Number11414DatesTare weight, g 1.919109 5/4/10 Tare weight, g 1.902906 5/6/10 Tare weight, g 1.922098 5/4/10Dry Residue Weight, g 1.921238 5/11/10 9A Dry Residue Weight, g 1.903331 5/11/10 9A Dry Residue Weight, g 1.921755 5/11/10 9AReweigh, Final, g 1.921308 5/11/10 4P Reweigh, Final, g 1.903358 5/11/10 4P Reweigh, Final, g 1.921783 5/11/10 4PMeCl2 Residue, g 0.0022 Water Residue, g 0.0005 Acetone Residue, g -0.0003MeCl2 Volume, mL 225 Water Volume, mL 250 Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045 Max. Water Residue, g 0.0025 Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesC & E Consultants, Inc.KTHEPA OTM-0283 Runs & 1 blankClient #Job #PO #Report Date100-2080410-10100-208-00015/14/20100410-10-OTM028-res5/17/2010MDL 0.09 (mg Ammonium) MDL 0.26 (mg Sulfate) Blank titrant amount (Vtb) 0.02 [Set this equal to the In-House Blank Titration Volume and then white out this note] NH4OH normality 0.100 Lot # Sigma Aldrich 318620

Sample ID. Volume Resuspended (mL) Titration Aliquot Vol (mL) Aliquot Factor (mL rec'd/aliq mL)

Train Blank 100 99.5 0.01 ND 1.01 0.26 ND 0.09 ND Run 1 100 99.5 1.72 1.01 8.21 2.91 Run 2 100 99.5 1.66 1.01 7.92 2.81 Run 3 100 99.5 1.41 1.01 6.71 2.38 In House 100 99.5 0.02 ND 1.01 0.26 ND 0.09 ND SO4 Catch (mg) NH 4 OH Titration Vol (mL) Ammonium equivalent (mg) Company

Analyst Parameters # Samples C & E Consultants, Inc. KTH EPA OTM-028 3 Runs & 1 blank Client # Job # PO # Report Date 100-208 0410-10 100-208-0001 5/14/2010

# Narrative Summary

# Enthalpy Analytical Narrative Summary

Company C & E Consultants, Inc. Client # 100-208 Analyst KHB Job # 0410-10 Parameters EPA CTM-033 PO # 100-208-0001

# Samples 3 Runs & 1 blank Report Date May 14, 2010
Custody Heather Tarjeft of Enthalpy Analy tical, Inc. received the samples on 4/29/10 at 0.9 °C after being relinqui shed by Civil and Environmental Consultants, Inc. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for hydrogen cyanide using the analytical procedures in EPA Conditional Test Method 033, Sampling and Analysis for Hydrogen Cyanide Emissions from Stationary Sources.
The samples were analyzed followi ng the procedures in Section 11.0, Analytical Procedures.
The Dionex Model 500, High Perfor mance Liquid Chromatograph ("Grandmama") was equipped with a Dionex ED40 Electrochemical Detector and a Dionex Ion Pac AS7, 4 x 250 mm (S/N 012759) column.
The pH of the samples was determined using test strips and is included in the results.

Calibration The calibration curve is locat ed in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page.
For each calibration curve used, the firs t page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound.
Chromatographic Conditions A copy of the acquisition method 1000.M is included in the Calibration Curve Chromatograms section of this report.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes As required in Section 9.0, Quality C ontrol, client-provided field blank, reagent blank and field spike were analyzed. In the laboratory the following QC samples were analyzed: method blank, Matrix Spike/Matrix Spike Duplicate, and a replicate analysis. All method required acceptance criteria were met.
All sample preparation and analytical holding times specified in the method were met. In Section 11.1.2 the specified analytical holding time is 30 days from collection.
Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.
Enthalpy Analytical, Inc. is accredited to perform this method for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company C & E Consultants, Inc. Client # 100-208 Analyst ARM Job # 0410-10 Parameters EPA Method 26A PO # 100-208-0001

# Samples 3 Runs & 1 blank Report Date May 14, 2010
Custody Heather Tarjeft of Enthalpy Analy tical, Inc. received the samples on 4/29/10 at 0.9 °C after being relinqui shed by Civil and Environmental Consultants, Inc. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for fluoride and chloride using the analytical procedures in EPA Me thod 26A, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Method (40 CFR Part 60, Appendix A).
The samples were analyzed followi ng the procedures in Section 11.0, Analytical Procedures. All samples and standards are prepared, stored, and analyzed using high-density polyethylene containers.
The Metrohm 861 Compact IC ("Smithers" S/N 1861002007189) was equipped with a Metrohm 861 Conductiv ity Detector and a Metrosep A Supp 5 - 110/4.0mm (S/N # 905298) column.

Calibration The calibration curve is locat ed in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page.
For each calibration curve used, the firs t page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound.
Chromatographic Conditions The acquisition method METROHM.M is included in the Calibration Curve Chromatograms section of this report.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes As required in Section 7.2.2, Absorbing Solution Blanks, clientprovided reagent blanks were analyzed. Additionally, a quality control check sample was analyzed at the sa me time as the blanks and samples. All method required acceptance criteria were met.
All sample preparation and analytical holding times specified in the method were met. Section 13.2, Sample Stability, specifies an analytical holding time of four weeks.
Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.

The H 2 

## SO 4 

## matrix samples were analyzed for Cl- and F- but are reported as HCl and HF. The resu lts were converted using acid conversion factors (CF) of 1.028 fo r HCl and 1.053 for HF to account for the hydrogen mass.
Enthalpy Analytical, Inc. is accredited to perform this method for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company C & E Consultants, Inc. Client # 100-208 Analyst KHB Job # 0410-10 Parameters NCASI Method 8A PO # 100-208-0001

# Samples 3 Runs & 1 blank Report Date May 14, 2010
Custody Heather Tarjeft of Enthalpy Analy tical, Inc. received the samples on 4/29/10 at 0.9 °C after being relinqui shed by Civil and Environmental Consultants, Inc. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. Analysis The samples were analyzed for sulfate using the analytical procedures in NCASI Method 8A - Determination of Sulfuric Acid Vapor or Mist and Sulfur Dioxide Emissions From Kraft Recovery Furnaces. The Metrohm 861, High Performance Liquid Chromatograph ("Mr Burns" S/N 1861004003180) was equipped with a Metrohm 861 Conductivity Detector and a Metrosep A Supp 5 - 110/4.0mm (S/N # 905298) column.

Calibration The calibration curve is locat ed in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page.
For each calibration curve used, the firs t page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. Chromatographic Conditions The acquisition method METROHM.M is included in the Calibration Curve Chromatograms section of this report. QC Notes All sample preparation and analytical holding times specified in the method were met. Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory.

The sulfate results were converted to sulfuric acid values using a conversion factor of 1.021 to account for the additional hydrogen mass.

# Enthalpy Analytical Narrative Summary

Company C & E Consultants, Inc. Client # 100-208 Analyst KHB Job # 0410-10 Parameters HPLC/IC Analysis PO # 100-208-0001

# Samples 3 Runs & 1 blank Report Date May 14, 2010
Custody Heather Tarjeft of Enthalpy Analy tical, Inc. received the samples on 4/29/10 at 0.9 °C after being relinqui shed by Civil and Environmental Consultants, Inc. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. Analysis Per the client’s request, the residues of the inorganic fractions of the OTM-028 analyses were each suspe nded using 20 mL of deionized water. These suspensions were analyzed for sulfate using a Metrohm 861, High Performance Liquid Chro matograph ("Mr Burns" S/N 1861004003180) the analyzer was equipped with a Metrohm 861 Conductivity Detectorand a Metros ep A Supp 5 - 110/4.0mm (S/N # 905298) column.
Calibration The calibration curve is locat ed in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page. For each calibration curve used, the firs t page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. Chromatographic Conditions The acquisition method METROHM.M is included in the Calibration Curve Chromatograms section of this report. QC Notes None Reporting Notes The analytical dilution factors (DFs) for these samples were 50 and 20 as shown on the chromatograms. The DF values in the results spreadsheet table are actually slightly higher, each including aliquot factors for the 0.5 mL aliquots remove d from the sample as received and the sample prior to titration. The results presented in this report are representative of the samples as provided to the laboratory.

# Enthalpy Analytical Narrative Summary

Company C & E Consultants, Inc. Client # 100-208 Analyst KTH Job # 0410-10 Parameters EPA OTM 027 PO # 100-208-0001

# Samples 3 runs & 1 blank Report Date May 17, 2010
Custody Heather Tarjeft of Enthalpy Analy tical, Inc. received the samples on 4/29/10 at 0.9 °C after being relinqui shed by Civil and Environmental Consultants, Inc. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc. Analysis The samples were analyzed for Par ticulate Matter using the analytical procedures in EPA Other Test Method-027. Determination of PM 10 

## and PM 2.5 

## Emissions From Stationary Sources. The samples were analyzed following the procedures in Section 11.0 Analytical Procedures. All samples were weighed on a Sartorius Model ME 5-F (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010, (NIST Test Weight # 1481174). After evaporating the acetone rinses at room temperature to dryness, the residue was baked in a forced flow oven at 160oC for 6 hours. The remaining residue was desiccated and weighed at 24 hour (or longer) intervals until a constant weight was achieved. QC Notes Acetone was used as a field rinse a nd was received for use as a reagent blank. Blank corrections were perfor med on the sample results using a volume-proportioned correction value.
An in-house acetone blank was drie d down with the samples and the residue mass was well below the method-specified limit. Reporting Notes Gravimetric analyses are typically accurate to ±0.5 mg. Therefore, negative catch weights between 0 and –0.5 mg are set to zero and no investigation is undertaken. Nega tive catch weights < -0.5 mg are investigated. Only the lab’s In House acetone blank had a negative catch weight, but it was less than 0.5 mg. The results presented in this report are representative of the samples as provided to the laboratory.

# Enthalpy Analytical Narrative Summary

Company C & E Consultants, Inc. Client # 100-208 Analyst KTH Job # 0410-10 Parameters EPA OTM 028 PO # 100-208-0001

# Samples 3 Runs & 1 blank Report Date May 17, 2010
Custody Heather Tarjeft of Enthalpy Analy tical, Inc. received the samples on 4/29/10 at 0.9 °C after being relinqui shed by Civil and Environmental Consultants, Inc. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for Par ticulate Matter using the analytical procedures in EPA Other Test Method-028. Determination of Condensible Particulate Emissions From Stationary Sources.
The samples were analyzed following the procedures in Section 11.0 Analytical Procedures.
All samples were weighed on a Sartorius Model ME 5-F (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010, (NIST Test Weight # 1481174).
After evaporating the acetone rinses at room temperature to dryness, the residue was baked in a forced flow oven at 160oC for 6 hours.
The remaining residue was desiccated and weighed at 24 hour (or longer) intervals until a constant weight was achieved.
QC Notes Acetone, methylene chloride, and water reagent blanks were received with these samples. All blanks ha d residue results allowable by the method.
All sample preparation and analytical holding times specified in the method were met.
Reporting Notes Gravimetric analyses are typically accurate to ±0.5 mg. Therefore, negative catch weights between 0 and –0.5 mg are set to zero and no investigation is undertaken. Nega tive catch weights < -0.5 mg are investigated. None of the sample fractions had a negative catch, though the laboratory In-House Acetone Bl anks did. Its value was low enough to note require an investigation.

# Enthalpy Analytical Narrative Summary (continued)

Reporting Notes (continued) The Train Blank had a catch weight greater than 2 mg. Per the method 2.0 mg has been used as the Train Blank Correction for all the samples rather than the measured value (or 4.7 mg).
The results presented in this report are representative of the samples as provided to the laboratory.

# General Reporting Notes

The following are general reporting notes that are a pplicable to all Enthalpy Analytical, Inc. data reports, unless specifically noted otherwise.

 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.

 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.

 The acronym ND following a value indicates a non-detect or analytical result below the MDL.

 The letter J following a value indicates an analytical r esult between the MDL and the LOQ. A J flag indicates that the laboratory can positively identify th e analyte of interest as present, but the value should be considered an estimate.

 The letter E following a value indicates an analytical r esult exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.

 The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analyti cal result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results.

 The addition of MS to the Sample ID represents a Matrix Sp ike. An aliquot of an actual sample is spiked with a known amount of analyte so that a per cent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s).

 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.

 The addition of LD to the Sample ID represents a Laborat ory Duplicate. The analyst prepares an additional aliquot of sample for testing and the resu lts of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).

 The addition of AD to the Sample ID represents an Alte rnate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usu ally double the initial factor). This analysis helps confirm that no additional compound is present and coel uting or sharing absorbance with the analyte of interest, as they would have a different res ponse/absorbance than the analyte of interest.

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laborator y using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. The extras (randomly chosen) are labeled with the asso ciated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection and/or sample transport.

# General Reporting Notes (continued)

 Significant Figures : Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. Ther e are five significant digits displayed, but no confidence should be placed on more than two significant digits.

 Manual Integration : The data systems used for processing w ill flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations. The peak was not integrated by the software “NI” , the peak

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP” . These codes will accompany the analyst’s ma nual integration stamp placed next to the compound name.

# Sample Custody

# Sample Chromatogramsmin 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3701.D)1.7452.0882.687



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3701.D Sample Name: CTM-033-R2-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 37 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 5:43:19 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:42:52 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3702.D)1.6151.7482.0902.1412.688



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\028-3702.D Sample Name: CTM-033-R2-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 37 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 5:58:35 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:01 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3801.D)1.6491.7442.065



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3801.D Sample Name: CTM-033-R3-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 38 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 6:13:51 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:08 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3802.D)1.4651.6501.7432.0692.670



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\029-3802.D Sample Name: CTM-033-R3-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 38 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 6:29:13 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:14 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3901.D)1.7502.0872.675



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3901.D Sample Name: CTM-033-R4-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 39 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 6:44:30 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:22 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3902.D)1.7412.0742.673



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\030-3902.D Sample Name: CTM-033-R4-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 39 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 6:59:47 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:29 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4001.D)1.4761.5411.7781.8531.917



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4001.D Sample Name: CTM-033-BT-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 40 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 7:15:04 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:35 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4002.D)1.4751.5501.7831.8571.916



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\031-4002.D Sample Name: CTM-033-BT-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 40 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 7:30:20 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 4:43:41 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0801.D)1.6521.738



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0801.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 2:56:46 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 4:02:13 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0802.D)1.6521.737



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\007-0802.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 3:12:00 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 4:02:21 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7601.D)1.7442.087



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7601.D Sample Name: LD/CTM-033-R2-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 76 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 2:28:58 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM Sample Info : Lab Duplicate

=====================================================================

Instrument 3 5/11/2010 4:43:54 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7602.D)1.7452.0842.653



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\050-7602.D Sample Name: LD/CTM-033-R2-C3-NaOH*5 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 76 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 2:44:14 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM Sample Info : Lab Duplicate

=====================================================================

Instrument 3 5/11/2010 4:44:00 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9301.D)

A

r ea

: 22

7 3 .5

61.7392.1002.6898.005 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.005 MM 2273.56030 5.05590e-4 1.14949 Hydrogen Cyanide

Totals : 1.14949

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9301.D Sample Name: MS/CTM-033-R2-C3-NaOH 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 93 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 11:16:26 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM Sample Info : Matrix Spike

=====================================================================

Instrument 3 5/11/2010 4:49:05 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9302.D)

A

r ea

: 22

9 1 .4

81.7442.1068.026 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.026 MM 2291.47754 5.05716e-4 1.15884 Hydrogen Cyanide

Totals : 1.15884

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\051-9302.D Sample Name: MS/CTM-033-R2-C3-NaOH 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 93 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 11:31:42 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM Sample Info : Matrix Spike

=====================================================================

Instrument 3 5/11/2010 4:44:37 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9401.D)

A

r ea

: 22

2 4 .2

81.7492.1032.7048.048 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.048 MM 2224.28442 5.05233e-4 1.12378 Hydrogen Cyanide

Totals : 1.12378

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9401.D Sample Name: MSD/CTM-033-R2-C3-NaOH 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 94 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 11:46:59 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM Sample Info : Matrix Spike Duplicate

=====================================================================

Instrument 3 5/11/2010 4:45:03 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9402.D)

A

r ea

: 22

3 5 .0

11.7442.1068.060 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.060 MM 2235.01416 5.05312e-4 1.12938 Hydrogen Cyanide

Totals : 1.12938

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\052-9402.D Sample Name: MSD/CTM-033-R2-C3-NaOH 0410-10

===================================================================== Acq. Operator : KHB Seq. Line : 94 Acq. Instrument : Grandmama Location : - Injection Date : 5/8/2010 12:02:16 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM Sample Info : Matrix Spike Duplicate

=====================================================================

Instrument 3 5/11/2010 4:45:23 PM ARM Page 1 of 1

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.300 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.300 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 8.251 1 1 1.03500e-1 237.96333 4.34941e-4 Hydrogen Cyanide 2 5.07300e-1 1162.53619 4.36374e-4 3 9.90500e-1 2156.07153 4.59400e-4 4 1.54100 3051.88635 5.04934e-4 5 2.08000 3752.79333 5.54254e-4

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

Instrument 3 5/6/2010 3:20:44 PM ARM Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 1 2 Area

0 500 1000 1500 2000 2500 3000 3500 4000

1 2 3 4 5 

### Hydrogen Cyanide at exp. RT: 8.251 ADC1 A, ADC1 CHANNEL A Correlation: 0.99532 Residual Std. Dev.: 218.88566 Formula: y = mx + b m: 1916.69420 b: 70.33972 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.204021 Level 3 : 0.104493 Level 4 : 0.067164 Level 5 : 0.04976

===================================================================== Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M

Instrument 3 5/6/2010 3:20:44 PM ARM Page 2 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0201.D)1.6461.7321.8418.404 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.404 BB 237.55678 3.85163e-4 9.14980e-2 Hydrogen Cyanide

Totals : 9.14980e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0201.D Sample Name: hplc50pg78 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 11:54:41 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:21:04 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0202.D)

A

r ea

: 23

8

. 40

21.6491.7368.389 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.389 MF 238.40192 3.85163e-4 9.18235e-2 Hydrogen Cyanide

Totals : 9.18235e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\001-0202.D Sample Name: hplc50pg78 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 12:09:30 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:24:21 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0301.D)

A

r ea

: 11

7 1 .3

11.6481.7361.8438.337 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.337 FM 1171.31274 4.90401e-4 5.74412e-1 Hydrogen Cyanide

Totals : 5.74412e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0301.D Sample Name: hplc50pg78 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 12:24:30 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:25:33 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0302.D)1.6511.7388.341 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.341 BB 1153.77625 4.89924e-4 5.65263e-1 Hydrogen Cyanide

Totals : 5.65263e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\002-0302.D Sample Name: hplc50pg78 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 12:39:38 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:25:40 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0401.D)

A

r ea

: 21

9 5 .51.6511.7391.8518.315 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.315 FM 2195.49976 5.05016e-4 1.10876 Hydrogen Cyanide

Totals : 1.10876

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0401.D Sample Name: hplc50pg78 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 12:54:52 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:35:39 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0402.D)1.6531.7408.320 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.320 BB 2116.71265 5.04394e-4 1.06766 Hydrogen Cyanide

Totals : 1.06766

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\003-0402.D Sample Name: hplc50pg78 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 1:10:06 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:36:15 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0501.D)1.6451.7328.264 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.264 BB 3041.79395 5.09667e-4 1.55030 Hydrogen Cyanide

Totals : 1.55030

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0501.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 1:25:20 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:36:23 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0502.D)

A

r ea

: 30

6 2 .0

11.6511.7371.8468.274 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.274 FM 3062.01001 5.09747e-4 1.56085 Hydrogen Cyanide

Totals : 1.56085

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-0502.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 1:40:34 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:38:34 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0601.D)1.6471.7358.248 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.248 BB 3786.44922 5.12040e-4 1.93881 Hydrogen Cyanide

Totals : 1.93881

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0601.D Sample Name: hplc50pg78 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 1:55:49 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:58:59 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0602.D)1.6501.7368.252 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.252 BB 3719.13745 5.11864e-4 1.90369 Hydrogen Cyanide

Totals : 1.90369

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\005-0602.D Sample Name: hplc50pg78 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 2:11:03 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 3:59:13 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0701.D)

A

r ea

: 18

2 5 .0

81.6491.7368.289 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.289 MM 1825.08093 5.01624e-4 9.15504e-1 Hydrogen Cyanide

Totals : 9.15504e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0701.D Sample Name: hplc50pg78 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 2:26:18 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 4:01:49 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0702.D)1.6471.7328.263 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.263 BB 1794.44543 5.01280e-4 8.99520e-1 Hydrogen Cyanide

Totals : 8.99520e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\006-0702.D Sample Name: hplc50pg78 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 2:41:32 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 4:01:58 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1501.D)

A

r ea

: 31

7 6 .6

11.6601.7468.359 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.359 MM 3176.61182 5.10179e-4 1.62064 Hydrogen Cyanide

Totals : 1.62064

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1501.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 6:31:17 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 4:03:56 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1502.D)1.6591.7458.376 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.376 BB 3132.86230 5.10018e-4 1.59781 Hydrogen Cyanide

Totals : 1.59781

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-1502.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 6:46:35 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/6/2010 4:04:04 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2201.D)

A

r ea

: 33

0 0 .5

91.6491.7351.8537.972 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.972 MM 3300.58984 5.10613e-4 1.68532 Hydrogen Cyanide

Totals : 1.68532

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2201.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 22 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 10:04:58 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:00:31 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2202.D)1.6491.7367.957 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.957 BB 3250.91577 5.10443e-4 1.65941 Hydrogen Cyanide

Totals : 1.65941

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2202.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 22 Acq. Instrument : Grandmama Location : - Injection Date : 5/5/2010 10:20:14 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:00:50 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2901.D)

A

r ea

: 32

3 1 .9

21.6611.7481.8667.998 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.998 MM 3231.92456 5.10377e-4 1.64950 Hydrogen Cyanide

Totals : 1.64950

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2901.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 29 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 1:38:49 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:01:04 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2902.D)

A

r ea

: 32

6 7 .7

11.6521.7407.998 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.998 MM 3267.71216 5.10501e-4 1.66817 Hydrogen Cyanide

Totals : 1.66817

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-2902.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 29 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 1:54:06 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:01:22 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3601.D)1.6581.7458.165 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.165 BB 3229.64795 5.10369e-4 1.64831 Hydrogen Cyanide

Totals : 1.64831

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3601.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 36 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 5:12:46 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:01:34 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3602.D)

A

r ea

: 32

5 6 .4

21.4361.6581.7478.207 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.207 MM 3256.42480 5.10462e-4 1.66228 Hydrogen Cyanide

Totals : 1.66228

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-3602.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 36 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 5:28:02 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:15:41 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4201.D)1.6551.7428.328 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.328 BB 3157.99609 5.10111e-4 1.61093 Hydrogen Cyanide

Totals : 1.61093

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4201.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 42 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 8:16:10 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:01:53 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4202.D)

A

r ea

: 33

0 0 .1

11.6511.7368.309 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.309 MM 3300.10522 5.10611e-4 1.68507 Hydrogen Cyanide

Totals : 1.68507

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-4202.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 42 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 8:31:26 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:02:06 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5001.D)

A

r ea

: 33

1 1 .2

61.6781.7508.324 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.324 MM 3311.25879 5.10649e-4 1.69089 Hydrogen Cyanide

Totals : 1.69089

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5001.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 12:20:36 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:09:21 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5002.D)

A

r ea

: 32

4 6 .2

71.6751.7448.267 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.267 MM 3246.26709 5.10427e-4 1.65698 Hydrogen Cyanide

Totals : 1.65698

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5002.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 12:35:52 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:09:40 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5501.D)

A

r ea

: 32

5 5 .2

81.6741.7451.8608.147 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.147 MM 3255.27905 5.10458e-4 1.66168 Hydrogen Cyanide

Totals : 1.66168

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5501.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 55 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 2:53:23 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:10:00 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5502.D)

A

r ea

: 33

1 8 .91.6751.7478.164 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.164 MM 3318.90112 5.10674e-4 1.69488 Hydrogen Cyanide

Totals : 1.69488

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5502.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 55 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 3:08:45 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:10:13 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5701.D)

A

r ea

: 32

8 6 .2

21.6731.7448.239 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.239 MM 3286.22314 5.10564e-4 1.67783 Hydrogen Cyanide

Totals : 1.67783

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5701.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 5:43:41 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:10:41 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5702.D)

A

r ea

: 31

9 9 .3

91.6751.7418.248 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.248 MM 3199.38721 5.10261e-4 1.63252 Hydrogen Cyanide

Totals : 1.63252

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-5702.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Grandmama Location : - Injection Date : 5/6/2010 5:58:54 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:10:57 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7101.D)

A

r ea

: 31

5 4 .21.6661.7418.283 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.283 MM 3154.19629 5.10097e-4 1.60895 Hydrogen Cyanide

Totals : 1.60895

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7101.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 71 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 11:56:07 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:11:48 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7102.D)1.6751.7468.327 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.327 BB 3104.43188 5.09910e-4 1.58298 Hydrogen Cyanide

Totals : 1.58298

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7102.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 71 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 12:11:23 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/7/2010 2:12:18 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7801.D)

A

r ea

: 31

7 7 .5

41.6711.7458.310 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.310 MM 3177.54395 5.10182e-4 1.62113 Hydrogen Cyanide

Totals : 1.62113

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7801.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 78 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 3:30:04 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/10/2010 8:57:13 AM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7802.D)

A

r ea

: 32

5 1 .71.6661.7408.289 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.289 MM 3251.69995 5.10446e-4 1.65982 Hydrogen Cyanide

Totals : 1.65982

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-7802.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 78 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 3:53:25 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/10/2010 8:56:52 AM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8501.D)

A

r ea

: 32

2 1 .2

91.6711.7428.288 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.288 MM 3221.28784 5.10339e-4 1.64395 Hydrogen Cyanide

Totals : 1.64395

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8501.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 85 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 7:12:02 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/10/2010 8:57:46 AM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8502.D)

A

r ea

: 32

5 0 .81.6701.7448.251 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.251 MM 3250.79932 5.10443e-4 1.65935 Hydrogen Cyanide

Totals : 1.65935

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-8502.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 85 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 7:27:18 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/10/2010 8:58:04 AM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9201.D)

A

r ea

: 33

0 7 .0

51.6641.7397.970 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.970 MM 3307.05029 5.10635e-4 1.68869 Hydrogen Cyanide

Totals : 1.68869

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9201.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 92 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 10:45:54 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/10/2010 4:27:45 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9202.D)

A

r ea

: 32

8 1 .3

21.6711.7457.989 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.989 MM 3281.32031 5.10548e-4 1.67527 Hydrogen Cyanide

Totals : 1.67527

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9202.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 92 Acq. Instrument : Grandmama Location : - Injection Date : 5/7/2010 11:01:09 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/10/2010 4:28:03 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9701.D)

A

r ea

: 32

1 8 .41.6631.7397.983 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.983 MM 3218.40381 5.10329e-4 1.64244 Hydrogen Cyanide

Totals : 1.64244

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9701.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 97 Acq. Instrument : Grandmama Location : - Injection Date : 5/8/2010 1:18:39 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 8:20:48 AM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9702.D)

A

r ea

: 32

5 3 .9

71.6611.7407.977 - Hydrogen Cyanide



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Thursday, May 06, 2010 2:56:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.977 MM 3253.96826 5.10454e-4 1.66100 Hydrogen Cyanide

Totals : 1.66100

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\MAY\HPLC50PG78\004-9702.D Sample Name: hplc50pg78 #4

===================================================================== Acq. Operator : KHB Seq. Line : 97 Acq. Instrument : Grandmama Location : - Injection Date : 5/8/2010 1:33:54 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 5/7/2010 3:44:49 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG78.M Last changed : 5/6/2010 3:19:41 PM by ARM

=====================================================================

Instrument 3 5/11/2010 8:21:05 AM ARM Page 1 of 1

### Method Information
Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified: 3/17/2010 at 9:48:43 AM
Column: Dionex Ionpac AS7 4 X 250mm Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine Flow rate: 1.0 mL/min

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: nC Units/Volt: 1000.000 Peakwidth (Data Rate): 0.133 Min (2.00 Hz) Stop Time: 14.01 Min Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1

### Sequence Table:
Method and Injection Info Part:
Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========
1 Vial 7 0.1N NaOH - RB 1000 4 Sample
2 Vial 1 hplc50pg78 #1 1000 2 Sample
3 Vial 2 hplc50pg78 #2 1000 2 Sample
4 Vial 3 hplc50pg78 #3 1000 2 Sample
5 Vial 4 hplc50pg78 #4 1000 2 Sample
6 Vial 5 hplc50pg78 #5 1000 2 Sample
7 Vial 6 hplc50pg78 #LCS 1000 2 Sample
8 Vial 7 0.1N NaOH - RB 1000 2 Sample
9 Vial 8 HCN-H2O-RB*5 0410-22 1000 2 Sample
10 Vial 9 H8-M26-1*5 0410-131 1000 2 Sample
11 Vial 10 H8-M26-2*5 0410-131 1000 2 Sample
12 Vial 11 H8-M26-3*5 0410-131 1000 2 Sample
13 Vial 12 H8-M26-FB*5 0410-131 1000 2 Sample
14 Vial 3 hplc50pg78 #3 1000 2 Sample
15 Vial 4 hplc50pg78 #4 1000 2 Sample
16 Vial 13 H8-M26-FS*5 0410-131 1000 2 Sample
17 Vial 14 H8-M26-RB*5 0410-131 1000 2 Sample
18 Vial 15 Run 2 Unit 1/2*5 0410-144 1000 2 Sample
19 Vial 16 Run 3 Unit 1/2*5 0410-144 1000 2 Sample
20 Vial 17 Run 4 Unit 1/2*5 0410-144 1000 2 Sample
21 Vial 3 hplc50pg78 #3 1000 2 Sample
22 Vial 4 hplc50pg78 #4 1000 2 Sample
23 Vial 18 Blank Unit 1/2*5 0410-144 1000 2 Sample
24 Vial 19 M26A/033-Hope-U1/2-1*5 0410-148 1000 2 Sample
25 Vial 20 M26A/033-Hope-U1/2-2*5 0410-148 1000 2 Sample
26 Vial 21 M26A/033-Hope-U1/2-3*5 0410-148 1000 2 Sample
27 Vial 22 M26A/033-Hope-U1/2-FB1*5 0410-148 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 1 of 4

### Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========
28 Vial 3 hplc50pg78 #3 1000 2 Sample
29 Vial 4 hplc50pg78 #4 1000 2 Sample
30 Vial 23 M26A/033-Hope-U1/2-RB*5 0410-148 1000 2 Sample
31 Vial 24 M26A/033-Hope-U1/2-FS*5 0410-148 1000 2 Sample
32 Vial 25 M26A/033 R1 HCl/HF/HCN*5 0410-102 1000 2 Sample
33 Vial 26 M26A/033 R2 HCl/HF/HCN*5 0410-102 1000 2 Sample
34 Vial 27 M26A/033 R3 HCl/HF/HCN*5 0410-102 1000 2 Sample
35 Vial 3 hplc50pg78 #3 1000 2 Sample
36 Vial 4 hplc50pg78 #4 1000 2 Sample
37 Vial 28 CTM-033-R2-C3-NaOH*5 0410-10 1000 2 Sample
38 Vial 29 CTM-033-R3-C3-NaOH*5 0410-10 1000 2 Sample
39 Vial 30 CTM-033-R4-C3-NaOH*5 0410-10 1000 2 Sample
40 Vial 31 CTM-033-BT-C3-NaOH*5 0410-10 1000 2 Sample
41 Vial 3 hplc50pg78 #3 1000 2 Sample
42 Vial 4 hplc50pg78 #4 1000 2 Sample
43 Vial 32 LCS 1*100 0410-131 1000 2 Sample
44 Vial 33 LCS 2*100 0410-131 1000 2 Sample
45 Vial 34 LCS 1*100 0410-102 1000 2 Sample
46 Vial 35 LCS 2*100 0410-102 1000 2 Sample
47 Vial 3 hplc50pg78 #3 1000 2 Sample
48 Vial 4 hplc50pg78 #4 1000 2 Sample
49 Vial 3 hplc50pg78 #3 1000 2 Sample
50 Vial 4 hplc50pg78 #4 1000 2 Sample
51 Vial 33 LCS 2*100 0410-131 1000 2 Sample
52 Vial 34 LCS 1*100 0410-102 1000 2 Sample
53 Vial 35 LCS 2*100 0410-102 1000 2 Sample
54 Vial 3 hplc50pg78 #3 1000 2 Sample
55 Vial 4 hplc50pg78 #4 1000 2 Sample
56 Vial 3 hplc50pg78 #3 1000 2 Sample
57 Vial 4 hplc50pg78 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 2 of 4

### Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========
58 Vial 36 LCS 1*100 0410-102 1000 2 Sample
59 Vial 37 LCS 2*100 0410-102 1000 2 Sample
60 Vial 38 LD/H8-M26-2*5 0410-131 1000 2 Sample
61 Vial 39 MS/H8-M26-2 0410-131 1000 2 Sample
62 Vial 40 MSD/H8-M26-2 0410-131 1000 2 Sample
63 Vial 3 hplc50pg78 #3 1000 2 Sample
64 Vial 4 hplc50pg78 #4 1000 2 Sample
65 Vial 41 LD/Run 2 Unit 1/2*5 0410-144 1000 2 Sample
66 Vial 42 MS/Run 2 Unit 1/2 0410-144 1000 2 Sample
67 Vial 43 MSD/Run 2 Unit 1/2 0410-144 1000 2 Sample
68 Vial 44 LD/M26A/033-Hope-U1/2-2*5 0410-148 1000 2 Sample
69 Vial 45 MS*2/M26A/033-Hope-U1/2-2 0410-148 1000 2 Sample
70 Vial 3 hplc50pg78 #3 1000 2 Sample
71 Vial 4 hplc50pg78 #4 1000 2 Sample
72 Vial 46 MSD*2/M26A/033-Hope-U1/2-2 0410-148 1000 2 Sample
73 Vial 47 LD/M26A/033 R2 HCl/HF/HCN*5 0410-102 1000 2 Sample
74 Vial 48 MS/M26A/033 R2 HCl/HF/HCN 0410-102 1000 2 Sample
75 Vial 49 MSD/M26A/033 R2 HCl/HF/HCN 0410-102 1000 2 Sample
76 Vial 50 LD/CTM-033-R2-C3-NaOH*5 0410-10 1000 2 Sample
77 Vial 3 hplc50pg78 #3 1000 2 Sample
78 Vial 4 hplc50pg78 #4 1000 2 Sample
79 Vial 36 LCS 1*100 0410-102 1000 2 Sample
80 Vial 37 LCS 2*100 0410-102 1000 2 Sample
81 Vial 38 LD/H8-M26-2*5 0410-131 1000 2 Sample
82 Vial 39 MS/H8-M26-2 0410-131 1000 2 Sample
83 Vial 40 MSD/H8-M26-2 0410-131 1000 2 Sample
84 Vial 3 hplc50pg78 #3 1000 2 Sample
85 Vial 4 hplc50pg78 #4 1000 2 Sample
86 Vial 41 LD/Run 2 Unit 1/2*5 0410-144 1000 2 Sample
87 Vial 42 MS/Run 2 Unit 1/2 0410-144 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 3 of 4

### Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========
88 Vial 43 MSD/Run 2 Unit 1/2 0410-144 1000 2 Sample
89 Vial 44 LD/M26A/033-Hope-U1/2-2*5 0410-148 1000 2 Sample
90 Vial 45 MS*2/M26A/033-Hope-U1/2-2 0410-148 1000 2 Sample
91 Vial 3 hplc50pg78 #3 1000 2 Sample
92 Vial 4 hplc50pg78 #4 1000 2 Sample
93 Vial 51 MS/CTM-033-R2-C3-NaOH 0410-10 1000 2 Sample
94 Vial 52 MSD/CTM-033-R2-C3-NaOH 0410-10 1000 2 Sample
95 Vial 53 M26A/033-Hope-U1/2-FS*50 0410-148 1000 2 Sample
96 Vial 3 hplc50pg78 #3 1000 2 Sample
97 Vial 4 hplc50pg78 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG78.S

Instrument 3 5/10/2010 9:15:58 AM ARM Page 4 of 4

# Sample Chromatograms

### ===================================================================== Acq. Operator : ARM Seq. Line : 9 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 2:54:39 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\011-0901.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\011-0901.D Sample Name: M26A-R1-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:49:17 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 9 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 3:05:26 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\011-0902.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\011-0902.D Sample Name: M26A-R1-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:49:28 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 12 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 3:59:25 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\014-1201.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\014-1201.D Sample Name: M26A-R2-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:21 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 12 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 4:10:14 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\014-1202.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\014-1202.D Sample Name: M26A-R2-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:32 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 13 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 4:21:01 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\015-1301.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\015-1301.D Sample Name: M26A-R3-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:43 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 13 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 4:31:49 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\015-1302.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\015-1302.D Sample Name: M26A-R3-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:50:54 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 14 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 4:42:37 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\016-1401.D)3.722 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.722 BB 7.51000e-1 3.72010e-2 2.79380e-2 Chloride

Totals : 2.79380e-2

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\016-1401.D Sample Name: M26A-BT-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:51:05 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 14 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 4:53:25 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\016-1402.D)3.720 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.720 BB 7.18118e-1 3.72010e-2 2.67147e-2 Chloride

Totals : 2.67147e-2

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\016-1402.D Sample Name: M26A-BT-C3-H2SO4 *20 0410-10

Instrument 1 5/5/2010 8:51:15 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 2:33:03 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\007-0801.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\007-0801.D Sample Name: Reagent Blank

Instrument 1 5/5/2010 8:48:55 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 2:43:51 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\007-0802.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 - - - Fluoride 3.705 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\007-0802.D Sample Name: Reagent Blank

Instrument 1 5/5/2010 8:49:06 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 2:11:27 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\006-0701.D)2.779 - Fluoride3.730 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.779 BB 251.20392 1.62063e-2 4.07108 Fluoride Both Tag Value= 4.0 μg/mL 3.730 BB 148.30563 2.53543e-2 3.76018 Chloride

Totals : 7.83126

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\006-0701.D Sample Name: HPLC51p92 #LCS

Instrument 1 5/5/2010 8:48:34 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 2:22:15 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\006-0702.D)2.779 - Fluoride3.730 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.779 BB 251.05655 1.62063e-2 4.06869 Fluoride Both Tag Value= 4.0 μg/mL 3.730 BB 148.15286 2.53545e-2 3.75634 Chloride

Totals : 7.82504

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\006-0702.D Sample Name: HPLC51p92 #LCS

Instrument 1 5/5/2010 8:48:44 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 10 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 3:16:15 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\012-1001.D)2.781 - Fluoride3.730 - Chloride5.1045.7936.085



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 BB 219.94760 1.62129e-2 3.56600 Fluoride 3.730 BB 114.65800 2.54184e-2 2.91443 Chloride

Totals : 6.48043

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\012-1001.D Sample Name: MS M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:49:38 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 10 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 3:27:02 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\012-1002.D)2.781 - Fluoride3.730 - Chloride5.1045.7946.085



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 BB 218.93048 1.62132e-2 3.54956 Fluoride 3.730 BB 114.60918 2.54186e-2 2.91320 Chloride

Totals : 6.46276

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\012-1002.D Sample Name: MS M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:49:49 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 11 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 3:37:49 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\013-1101.D)2.780 - Fluoride3.729 - Chloride5.1055.7926.084



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.780 BB 217.89267 1.62135e-2 3.53279 Fluoride 3.729 BB 114.13017 2.54198e-2 2.90116 Chloride

Totals : 6.43395

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\013-1101.D Sample Name: MSD M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:50:00 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 11 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 3:48:38 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\013-1102.D)2.781 - Fluoride3.730 - Chloride5.1055.7946.086



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 BB 217.54382 1.62135e-2 3.52716 Fluoride 3.730 BB 114.07535 2.54199e-2 2.89978 Chloride

Totals : 6.42694

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\013-1102.D Sample Name: MSD M26A-R1-C3-H2SO4 0410-10

Instrument 1 5/5/2010 8:50:10 AM ARM Page 1 of 1

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: ADC1 B, ADC1 B, Metrohm Signal 2: ADC1 A, ADC1 CHANNEL A
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 2.781 2 1 1.00000e-1 5.08084 1.96818e-2 Fluoride 2 9.99000e-1 62.57442 1.59650e-2 3 4.97500 320.71269 1.55123e-2 4 8.92000 563.32326 1.58346e-2 5 14.80000 888.43126 1.66586e-2 3.705 2 1 1.00000e-1 3.07677 3.25017e-2 Chloride 2 9.99000e-1 34.87551 2.86447e-2 3 4.97500 192.28088 2.58736e-2 4 8.92000 354.95784 2.51297e-2 5 14.80000 593.68901 2.49289e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Instrument 1 5/5/2010 8:45:48 AM ARM Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 200 400 600 800

1 2 3 4 5 

### Fluoride at exp. RT: 2.781 ADC1 A, ADC1 CHANNEL A Correlation: 0.99950 Residual Std. Dev.: 18.67116 Formula: y = mx + b m: 61.88432 b: -7.31816e-1 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.1001 Level 3 : 0.020101 Level 4 : 0.011211 Level 5 : 0.006757

Amount[ug/mL] 0 10 Area

0 100 200 300 400 500

1 2 3 4 5 

### Chloride at exp. RT: 3.705 ADC1 A, ADC1 CHANNEL A Correlation: 0.99976 Residual Std. Dev.: 4.89599 Formula: y = mx + b m: 39.78424 b: -1.29033 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.1001 Level 3 : 0.020101 Level 4 : 0.011211 Level 5 : 0.006757

===================================================================== Method Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M

Instrument 1 5/5/2010 8:45:48 AM ARM Page 2 of 2

### ===================================================================== Acq. Operator : ARM Seq. Line : 2 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 12:23:29 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-0201.D)2.772 - Fluoride3.737 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.772 BB 5.03732 1.83264e-2 9.23158e-2 Fluoride 3.737 BB 3.00709 3.59211e-2 1.08018e-1 Chloride

Totals : 2.00334e-1

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-0201.D Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:46:46 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 2 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 12:34:17 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-0202.D)2.774 - Fluoride3.738 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.774 BB 5.09628 1.83264e-2 9.33964e-2 Fluoride 3.738 BB 2.97792 3.60268e-2 1.07285e-1 Chloride

Totals : 2.00681e-1

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-0202.D Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:46:57 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 30 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 10:28:12 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-3001.D)2.780 - Fluoride3.706 - Chloride



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.780 BB 5.13956 1.83264e-2 9.41896e-2 Fluoride 3.706 BB 3.14353 3.54530e-2 1.11448e-1 Chloride

Totals : 2.05637e-1

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-3001.D Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:56:53 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 30 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 10:39:00 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\001-3002.D)2.779 - Fluoride3.703 - Chloride5.638



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.779 BB 5.05021 1.83264e-2 9.25520e-2 Fluoride 3.703 BB 3.17853 3.53394e-2 1.12327e-1 Chloride

Totals : 2.04879e-1

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\001-3002.D Sample Name: HPLC51p92 #1

Instrument 1 5/5/2010 8:57:04 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 3 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 12:45:06 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-0301.D)2.775 - Fluoride3.737 - Chloride5.8246.055



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.775 BB 62.29956 1.63490e-2 1.01854 Fluoride 3.737 BB 34.63943 2.60719e-2 9.03115e-1 Chloride

Totals : 1.92165

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-0301.D Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:47:07 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 3 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 12:55:54 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-0302.D)2.774 - Fluoride3.734 - Chloride5.0935.8146.057



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.774 BB 62.50897 1.63484e-2 1.02192 Fluoride 3.734 BB 34.88967 2.60652e-2 9.09405e-1 Chloride

Totals : 1.93132

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-0302.D Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:47:18 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 31 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 10:49:47 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-3101.D)2.782 - Fluoride3.703 - Chloride5.0025.6296.153



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.782 BB 62.83863 1.63474e-2 1.02725 Fluoride 3.703 BB 35.03148 2.60614e-2 9.12970e-1 Chloride

Totals : 1.94022

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-3101.D Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:57:14 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 31 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 11:00:36 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\002-3102.D)2.782 - Fluoride3.703 - Chloride4.9995.6246.154



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.782 BB 62.65052 1.63479e-2 1.02421 Fluoride 3.703 BB 34.94147 2.60638e-2 9.10707e-1 Chloride

Totals : 1.93491

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\002-3102.D Sample Name: HPLC51p92 #2

Instrument 1 5/5/2010 8:57:25 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 1:06:40 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-0401.D)2.779 - Fluoride3.732 - Chloride5.0495.7826.064



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.779 BB 319.55215 1.61962e-2 5.17553 Fluoride 3.732 BB 191.97200 2.53045e-2 4.85776 Chloride

Totals : 10.03329

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-0401.D Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:47:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 1:17:29 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-0402.D)2.779 - Fluoride3.731 - Chloride5.0465.7786.067



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.779 BB 319.27460 1.61962e-2 5.17104 Fluoride 3.731 BB 191.94141 2.53046e-2 4.85699 Chloride

Totals : 10.02803

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-0402.D Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:47:39 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 32 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 11:11:23 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-3201.D)2.786 - Fluoride3.699 - Chloride5.6066.146



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.786 BB 322.12744 1.61959e-2 5.21714 Fluoride 3.699 BB 192.54091 2.53040e-2 4.87206 Chloride

Totals : 10.08920

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-3201.D Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:57:36 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 32 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 11:22:10 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-3202.D)2.787 - Fluoride3.699 - Chloride5.6036.148



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.787 BB 321.89658 1.61959e-2 5.21341 Fluoride 3.699 BB 192.66919 2.53039e-2 4.87529 Chloride

Totals : 10.08870

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-3202.D Sample Name: HPLC51p92 #3

Instrument 1 5/5/2010 8:57:46 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 1:28:16 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-0501.D)2.785 - Fluoride3.728 - Chloride5.0405.7646.078



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.785 BB 561.44849 1.61802e-2 9.08437 Fluoride 3.728 BB 354.50882 2.52271e-2 8.94322 Chloride

Totals : 18.02759

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-0501.D Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:47:50 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 1:39:05 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-0502.D)2.786 - Fluoride3.729 - Chloride5.0405.7636.082



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.786 BB 560.80377 1.61803e-2 9.07396 Fluoride 3.729 BB 354.60712 2.52270e-2 8.94569 Chloride

Totals : 18.01964

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-0502.D Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:48:00 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 33 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 11:32:57 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-3301.D)2.792 - Fluoride3.699 - Chloride4.9825.5976.148



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.792 BB 564.49432 1.61801e-2 9.13359 Fluoride 3.699 BB 355.35175 2.52269e-2 8.96441 Chloride

Totals : 18.09800

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-3301.D Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:57:57 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 33 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 11:43:44 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\004-3302.D)2.791 - Fluoride3.696 - Chloride4.9805.5926.148



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.791 BB 566.54645 1.61801e-2 9.16675 Fluoride 3.696 BB 355.36368 2.52268e-2 8.96471 Chloride

Totals : 18.13146

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\004-3302.D Sample Name: HPLC51p92 #4

Instrument 1 5/5/2010 8:58:08 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 1:49:52 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-0601.D)2.794 - Fluoride3.728 - Chloride5.0245.7516.087



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.794 BB 883.68909 1.61726e-2 14.29152 Fluoride 3.728 BB 592.64661 2.51903e-2 14.92895 Chloride

Totals : 29.22047

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-0601.D Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:48:12 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 2:00:40 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-0602.D)2.793 - Fluoride3.726 - Chloride5.0215.7486.086



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.793 BB 885.45966 1.61725e-2 14.32013 Fluoride 3.726 BB 592.68384 2.51903e-2 14.92989 Chloride

Totals : 29.25001

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-0602.D Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:48:23 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 34 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 11:54:33 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-3401.D)2.801 - Fluoride3.698 - Chloride4.9755.5886.148



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.801 BB 892.53955 1.61724e-2 14.43453 Fluoride 3.698 BB 594.80170 2.51901e-2 14.98312 Chloride

Totals : 29.41765

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-3401.D Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:58:19 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 34 Acq. Instrument : Smithers Location : - Injection Date : 5/5/2010 12:05:20 AM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\005-3402.D)2.800 - Fluoride3.697 - Chloride4.9755.5856.148



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.800 BB 892.03674 1.61724e-2 14.42641 Fluoride 3.697 BB 594.62390 2.51901e-2 14.97865 Chloride

Totals : 29.40506

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\005-3402.D Sample Name: HPLC51p92 #5

Instrument 1 5/5/2010 8:58:31 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 19 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 6:30:38 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-1901.D)2.781 - Fluoride3.731 - Chloride5.0465.7746.072



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 BB 320.84857 1.61960e-2 5.19648 Fluoride 3.731 BB 192.44281 2.53041e-2 4.86960 Chloride

Totals : 10.06607

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-1901.D Sample Name: HPLC51pg92 #3

Instrument 1 5/5/2010 8:52:54 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : ARM Seq. Line : 19 Acq. Instrument : Smithers Location : - Injection Date : 5/4/2010 6:41:25 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG92.S Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : Y:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG92.M Last changed : 5/5/2010 8:45:19 AM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (HPLC51PG92\003-1902.D)2.781 - Fluoride3.731 - Chloride5.0475.7766.070



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : Wednesday, May 05, 2010 8:45:15 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 A, ADC1 CHANNEL A
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 2.781 BB 319.23227 1.61962e-2 5.17036 Fluoride 3.731 BB 192.04607 2.53045e-2 4.85962 Chloride

Totals : 10.02998

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG92\003-1902.D Sample Name: HPLC51pg92 #3

Instrument 1 5/5/2010 8:53:05 AM ARM Page 1 of 1

### Method Information
Method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified: 1/13/2010 at 7:06:26 AM

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 A, Metrohm Source: Signal Unit: mAU Units/Volt: 100.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified on: 1/13/2010 at 7:06:26 AM

Smithers 1/18/2010 7:20:57 AM mgb Page 1 of 1

### Sequence: C:\HPCHEM\1\SEQUENCE\hplc51pg92.txt
Line Vial Sample Name Method Inj 1 Vial 127 DI H2O M ETROHM 4 2 Vial 1 HPLC51p92 #1 M ETROHM 2 3 Vial 2 HPLC51p92 #2 M ETROHM 2 4 Vial 3 HPLC51p92 #3 M ETROHM 2 5 Vial 4 HPLC51p92 #4 M ETROHM 2 6 Vial 5 HPLC51p92 #5 M ETROHM 2 7 Vial 6 HPLC51p92 #LCS M ETROHM 2 8 Vial 7 Reagent Blank M ETROHM 2 9 Vial 11 M26A-R1-C3-H2SO4 *20 0410-10 M ETROHM 2 10 Vial 12 MS M26A-R1-C3-H2SO4 0410-10 M ETROHM 2 11 Vial 13 MSD M26A-R1-C3-H2SO4 0410-10 M ETROHM 2 12 Vial 14 M26A-R2-C3-H2SO4 *20 0410-10 M ETROHM 2 13 Vial 15 M26A-R3-C3-H2SO4 *20 0410-10 M ETROHM 2 14 Vial 16 M26A-BT-C3-H2SO4 *20 0410-10 M ETROHM 2 15 Vial 21 Run 2 Unit 1/2 *20 0410-144 M ETROHM 2 16 Vial 22 MS Run 2 Unit 1/2 0410-144 M ETROHM 2 17 Vial 23 MSD Run 2 Unit 1/2 0410-144 M ETROHM 2 18 Vial 24 Run 3 Unit 1/2 *20 0410-144 M ETROHM 2 19 Vial 3 HPLC51pg92 #3 M ETROHM 2 20 Vial 4 HPLC51pg92 #4 M ETROHM 2 21 Vial 25 Run 4 Unit 1/2 *20 0410-144 M ETROHM 2 22 Vial 26 Blank Unit 1/2 *20 0410-144 M ETROHM 2 23 Vial 31 H8-M26-1 *20 0410-131 M ETROHM 2 24 Vial 32 MS H8-M26-1 0410-131 M ETROHM 2 25 Vial 33 MSD H8-M26-1 0410-131 M ETROHM 2 26 Vial 34 H8-M26-2 *20 0410-131 M ETROHM 2 27 Vial 35 H8-M26-3 *20 0410-131 M ETROHM 2 28 Vial 36 H8-M26-FB *20 0410-131 M ETROHM 2 29 Vial 37 H8-M26-RB *20 0410-131 M ETROHM 2 30 Vial 1 HPLC51p92 #1 M ETROHM 2 31 Vial 2 HPLC51p92 #2 M ETROHM 2 32 Vial 3 HPLC51p92 #3 M ETROHM 2 33 Vial 4 HPLC51p92 #4 M ETROHM 2 34 Vial 5 HPLC51p92 #5 M ETROHM 2

# Sample Chromatograms

### ===================================================================== Acq. Operator : KHB Seq. Line : 14 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 8:09:50 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1401.D)

A

r ea

: 1.

5 0 51

39.558 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.558 MM 1.50513 6.27688e-2 9.44753e-2 Sulfate

Totals : 9.44753e-2

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1401.D Sample Name: M8A-R1-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:29:25 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 14 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 8:26:38 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1402.D)

A

r ea

: 1.

4 6 47

69.566 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.566 MM 1.46476 6.27688e-2 9.19411e-2 Sulfate

Totals : 9.19411e-2

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\013-1402.D Sample Name: M8A-R1-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:30:09 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 8:43:27 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1501.D)

A

r ea

: 0.

8 3 73

4 19.587 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.587 MM 8.37341e-1 6.27688e-2 5.25589e-2 Sulfate

Totals : 5.25589e-2

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1501.D Sample Name: M8A-R2-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:30:33 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 9:00:14 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1502.D)

A

r ea

: 0.

8 5 41

8 29.593 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.593 MM 8.54182e-1 6.27688e-2 5.36160e-2 Sulfate

Totals : 5.36160e-2

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\014-1502.D Sample Name: M8A-R2-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:31:03 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 16 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 9:17:02 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1601.D)

A

r ea

: 1.

0 2 839.595 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.595 MM 1.02830 6.27688e-2 6.45453e-2 Sulfate

Totals : 6.45453e-2

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1601.D Sample Name: M8A-R3-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:34:55 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 16 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 9:33:50 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1602.D)

A

r ea

: 1.

0 1 21

99.598 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.598 MM 1.01219 6.27688e-2 6.35342e-2 Sulfate

Totals : 6.35342e-2

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\015-1602.D Sample Name: M8A-R3-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:35:42 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 17 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 9:50:38 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Sample Blank

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\016-1701.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\016-1701.D Sample Name: M8A-BT-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:20:24 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 17 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 10:07:26 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Sample Blank

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\016-1702.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\016-1702.D Sample Name: M8A-BT-C1-SO3*20 0410-10

Instrument 1 5/12/2010 9:20:32 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 4:48:14 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0801.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0801.D Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:10 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 5:05:03 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0802.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0802.D Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:21 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 4:14:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D)3.1074.2125.8826.5828.3509.491 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.491 BB 141.38943 4.42883e-2 6.26190 Sulfate Tag Value = 6.250 μg/mL

Totals : 6.26190

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:04 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 4:31:27 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D)3.1074.2135.8846.5858.3519.491 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.491 BB 137.15407 4.42948e-2 6.07521 Sulfate Tag Value = 6.250 μg/mL

Totals : 6.07521

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:10 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 33 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 12:29:46 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Matrix Spike

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\024-3302.D)9.509 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.509 BB 63.05366 4.45500e-2 2.80904 Sulfate

Totals : 2.80904

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\024-3302.D Sample Name: MS/M8A-R1-C1-SO3 0410-10

Instrument 3 5/13/2010 10:14:13 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 34 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 12:46:34 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Matrix Spike Duplicate

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\025-3401.D)9.510 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.510 BB 64.73146 4.45377e-2 2.88299 Sulfate

Totals : 2.88299

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\025-3401.D Sample Name: MSD/M8A-R1-C1-SO3 0410-10

Instrument 3 5/13/2010 10:14:20 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 34 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 1:03:21 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Matrix Spike Duplicate

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\025-3402.D)9.511 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.511 BB 69.13836 4.45084e-2 3.07724 Sulfate

Totals : 3.07724

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\025-3402.D Sample Name: MSD/M8A-R1-C1-SO3 0410-10

Instrument 3 5/13/2010 10:14:26 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 35 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 1:20:09 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Matrix Spike

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\026-3501.D)9.514 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.514 BB 65.78504 4.45303e-2 2.92943 Sulfate

Totals : 2.92943

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\026-3501.D Sample Name: MS/MeadWestVaco M8R1 0510-45

Instrument 3 5/13/2010 10:14:32 AM ARM Page 1 of 1

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : 5/11/2010 5:55:38 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 9.489 1 1 1.00000e-1 1.94891 5.13107e-2 Sulfate 2 5.00000e-1 9.20960 5.42912e-2 3 5.00000 107.53530 4.64964e-2 4 10.00000 225.66882 4.43127e-2 5 15.00000 346.48825 4.32915e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 50 100 150 200 250 300

1 2 3 4 5 

### Sulfate at exp. RT: 9.489 ADC1 B, ADC2 CHANNEL B Correlation: 0.99952 Residual Std. Dev.: 5.06077 Formula: y = mx + b m: 22.68721 b: -6.75574e-1 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.2 Level 3 : 0.02 Level 4 : 0.01 Level 5 : 0.006667

===================================================================== Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 2 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 1:26:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D)

A

r ea

: 1.

8 8 94

73.1044.2179.506 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.506 MM 1.88947 5.98375e-2 1.13061e-1 Sulfate

Totals : 1.13061e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:07 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 1:43:28 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D)

A

r ea

: 2.

0 0 83

53.1044.2179.503 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.503 MM 2.00835 5.89047e-2 1.18301e-1 Sulfate

Totals : 1.18301e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:00:15 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D)3.1034.2155.9066.6238.3749.498 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.498 BB 9.16793 4.73257e-2 4.33879e-1 Sulfate

Totals : 4.33879e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:01 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:17:03 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D)3.1044.2165.9066.6228.3769.499 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.499 BB 9.25128 4.72965e-2 4.37553e-1 Sulfate

Totals : 4.37553e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:08 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:33:51 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D)3.1124.2135.8866.5878.3539.492 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.492 BB 109.14275 4.43505e-2 4.84054 Sulfate

Totals : 4.84054

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:14 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:50:39 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D)3.1124.2135.8866.5878.3539.492 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.492 BB 105.92785 4.43588e-2 4.69883 Sulfate

Totals : 4.69883

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:26 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:07:27 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D)3.1244.2155.8816.5778.3509.490 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.490 BB 228.02539 4.42083e-2 10.08061 Sulfate

Totals : 10.08061

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:39 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:24:15 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D)3.1224.2145.8846.5818.3489.488 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.488 BB 223.31224 4.42110e-2 9.87287 Sulfate

Totals : 9.87287

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:46 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:41:03 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D)3.1334.2165.8786.5718.3469.488 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.488 BB 352.66254 4.41621e-2 15.57433 Sulfate

Totals : 15.57433

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:51 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:57:51 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D)3.1324.2155.8766.5688.3479.489 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 BB 340.31396 4.41652e-2 15.03003 Sulfate

Totals : 15.03003

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:58 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 19 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 10:57:49 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1901.D)3.1274.1775.7366.3878.4179.583 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.583 BB 231.36612 4.42064e-2 10.22786 Sulfate

Totals : 10.22786

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1901.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:20:54 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 19 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 11:14:38 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1902.D)3.1274.1775.7356.3868.4219.584 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.584 BB 223.56235 4.42109e-2 9.88389 Sulfate

Totals : 9.88389

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1902.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:21:01 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 28 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 4:00:14 AM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2801.D)3.1294.1755.7246.3738.4239.596 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.596 BB 231.33727 4.42064e-2 10.22659 Sulfate

Totals : 10.22659

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2801.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:05 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 28 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 4:17:01 AM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2802.D)3.1294.1775.7286.3798.4309.595 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.595 BB 221.99748 4.42118e-2 9.81491 Sulfate

Totals : 9.81491

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2802.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:12 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 30 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 10:48:57 AM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3001.D)3.1244.2155.8836.5818.3339.495 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.495 BB 242.00009 4.42007e-2 10.69658 Sulfate

Totals : 10.69658

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3001.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:34 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 30 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 11:05:45 AM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3002.D)3.1204.2125.8776.5748.3359.496 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.496 BB 219.04594 4.42136e-2 9.68482 Sulfate

Totals : 9.68482

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3002.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:41 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 41 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 4:58:32 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-4102.D)3.1344.2185.8566.5438.4889.649 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.649 BB 241.92140 4.42008e-2 10.69311 Sulfate

Totals : 10.69311

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-4102.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:16:08 AM ARM Page 1 of 1

### Method Information
Method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified: 1/13/2010 at 7:06:26 AM

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 A, Metrohm Source: Signal Unit: mAU Units/Volt: 100.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified on: 1/13/2010 at 7:06:26 AM

Smithers 1/18/2010 7:20:57 AM mgb Page 1 of 1Sequence: C:\HPCHEM\3\SEQUENCE\hplc53pg44.txt
Line Vial Sample Name Method Inj 1 Vial 7 RB/DI H2O METROHM 3 2 Vial 1 hplc53pg44 #1 METROHM 2 3 Vial 2 hplc53pg44 #2 METROHM 2 4 Vial 3 hplc53pg44 #3 METROHM 2 5 Vial 4 hplc53pg44 #4 METROHM 2 6 Vial 5 hplc53pg44 #5 METROHM 2 7 Vial 6 hplc53pg44 #LCS METROHM 2 8 Vial 7 RB/DI H2O METROHM 2 9 Vial 8 Run 1 post*50 0410-10 METROHM 2 10 Vial 9 Run 2 post*50 0410-10 METROHM 2 11 Vial 10 Run 3 post*50 0410-10 METROHM 2 12 Vial 11 Train Blk post*50 0410-10 METROHM 2 13 Vial 12 IHB post*50 0410-10 METROHM 2 14 Vial 13 M8A-R1-C1-SO3*20 0410-10 METROHM 2 15 Vial 14 M8A-R2-C1-SO3*20 0410-10 METROHM 2 16 Vial 15 M8A-R3-C1-SO3*20 0410-10 METROHM 2 17 Vial 16 M8A-BT-C1-SO3*20 0410-10 METROHM 2 18 Vial 3 hplc53pg44 #3 METROHM 2 19 Vial 4 hplc53pg44 #4 METROHM 2 20 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2 21 Vial 18 MeadWestVaco M8R2*20 0510-45 METROHM 2 22 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2 23 Vial 20 M13A-1*20 0510-135 METROHM 2 24 Vial 21 M13A-2*20 0510-135 METROHM 2 25 Vial 22 M13A-3*20 0510-135 METROHM 2 26 Vial 23 IPA Blank*20 0510-135 METROHM 2 27 Vial 3 hplc53pg44 #3 METROHM 2 28 Vial 4 hplc53pg44 #4 METROHM 2 29 Vial 3 hplc53pg44 #3 METROHM 2 30 Vial 4 hplc53pg44 #4 METROHM 2 31 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2 32 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2 33 Vial 24 MS/M8A-R1-C1-SO3 0410-10 METROHM 2 34 Vial 25 MSD/M8A-R1-C1-SO3 0410-10 METROHM 2 35 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2 36 Vial 27 MSD/MeadWestVaco M8R1 0510-45 METROHM 2 37 Vial 28 MS/M13A-1 0510-135 METROHM 2 38 Vial 29 MSD/M13A-1 0510-135 METROHM 2 39 Vial 30 M13A-3*20 0510-135 METROHM 2 40 Vial 3 hplc53pg44 #3 METROHM 2 41 Vial 4 hplc53pg44 #4 METROHM 2 42 Vial 31 Run 1*50 0410-10 METROHM 2 43 Vial 32 Run 2*50 0410-10 METROHM 2 44 Vial 33 Run 3*50 0410-10 METROHM 2 45 Vial 34 Train Blk*20 0410-10 METROHM 2 46 Vial 35 IHB*20 0410-10 METROHM 2 47 Vial 36 MS/Run 1 0410-10 METROHM 2 48 Vial 37 MSD/Run 1 0410-10 METROHM 2 49 Vial 3 hplc53pg44 #3 METROHM 2 50 Vial 4 hplc53pg44 #4 METROHM 2 51 Vial 3 hplc53pg44 #3 METROHM 2 52 Vial 4 hplc53pg44 #4 METROHM 2 53 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2 54 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2 55 Vial 3 hplc53pg44 #3 METROHM 2 56 Vial 4 hplc53pg44 #4 METROHM 2

# Sample Chromatograms

### ===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 5:26:32 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\031-5701.D)9.670 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.670 BB 153.27998 4.42720e-2 6.78601 Sulfate

Totals : 6.78601

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\031-5701.D Sample Name: Run 1*50 0410-10

Instrument 1 5/14/2010 8:15:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 5:43:19 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\031-5702.D)9.667 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.667 BB 167.09430 4.42559e-2 7.39491 Sulfate

Totals : 7.39491

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\031-5702.D Sample Name: Run 1*50 0410-10

Instrument 1 5/14/2010 8:15:37 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 43 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 6:33:15 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\032-4301.D)4.1799.654 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.654 BB 171.69333 4.42511e-2 7.59762 Sulfate

Totals : 7.59762

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\032-4301.D Sample Name: Run 2*50 0410-10

Instrument 3 5/13/2010 10:16:28 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 43 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 6:50:03 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\032-4302.D)9.654 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.654 BB 164.26805 4.42590e-2 7.27033 Sulfate

Totals : 7.27033

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\032-4302.D Sample Name: Run 2*50 0410-10

Instrument 3 5/13/2010 10:16:34 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 44 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 7:06:51 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\033-4401.D)9.658 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.658 BB 154.12886 4.42709e-2 6.82342 Sulfate

Totals : 6.82342

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\033-4401.D Sample Name: Run 3*50 0410-10

Instrument 3 5/13/2010 10:16:41 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 44 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 7:23:40 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\033-4402.D)9.668 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.668 BB 143.55124 4.42851e-2 6.35718 Sulfate

Totals : 6.35718

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\033-4402.D Sample Name: Run 3*50 0410-10

Instrument 3 5/13/2010 10:16:47 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 45 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 7:40:27 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Sample Blank

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\034-4501.D)3.3544.2106.540



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\034-4501.D Sample Name: Train Blk*20 0410-10

Instrument 3 5/13/2010 10:16:53 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 45 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 7:57:15 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : Sample Blank

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\034-4502.D)3.3524.2056.519



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\034-4502.D Sample Name: Train Blk*20 0410-10

Instrument 3 5/13/2010 10:17:00 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 46 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 8:14:03 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : In-House Blank

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\035-4601.D)4.203



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\035-4601.D Sample Name: IHB*20 0410-10

Instrument 3 5/13/2010 10:17:07 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 46 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 8:30:50 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM Sample Info : In-House Blank

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\035-4602.D)4.201



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\035-4602.D Sample Name: IHB*20 0410-10

Instrument 3 5/13/2010 10:17:14 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 4:48:14 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0801.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0801.D Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:10 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 5:05:03 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\007-0802.D)



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 - - - Sulfate

Totals : 0.00000

1 Warnings or Errors :
Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\007-0802.D Sample Name: RB/DI H2O

Instrument 1 5/12/2010 9:19:21 AM ARM Page 1 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 4:14:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D)3.1074.2125.8826.5828.3509.491 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.491 BB 141.38943 4.42883e-2 6.26190 Sulfate Tag Value = 6.250 μg/mL

Totals : 6.26190

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0701.D Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:04 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 4:31:27 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D)3.1074.2135.8846.5858.3519.491 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.491 BB 137.15407 4.42948e-2 6.07521 Sulfate Tag Value = 6.250 μg/mL

Totals : 6.07521

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\006-0702.D Sample Name: hplc53pg44 #LCS

Instrument 3 5/12/2010 8:19:10 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 58 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 6:00:06 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM Sample Info : Matrix Spike

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\036-5801.D)9.662 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.662 BB 270.48413 4.41878e-2 11.95209 Sulfate

Totals : 11.95209

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\036-5801.D Sample Name: MS/Run 1 0410-10

Instrument 1 5/14/2010 8:15:44 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 58 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 6:16:54 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM Sample Info : Matrix Spike

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\036-5802.D)9.661 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.661 BB 244.02638 4.41997e-2 10.78590 Sulfate

Totals : 10.78590

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\036-5802.D Sample Name: MS/Run 1 0410-10

Instrument 1 5/14/2010 8:15:52 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 59 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 6:33:42 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM Sample Info : Matrix Spike

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\037-5901.D)9.658 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.658 BB 266.11325 4.41896e-2 11.75944 Sulfate

Totals : 11.75944

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\037-5901.D Sample Name: MSD/Run 1 0410-10

Instrument 1 5/14/2010 8:16:01 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 59 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 6:50:29 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM Sample Info : Matrix Spike

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\037-5902.D)9.655 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.655 BB 243.85738 4.41998e-2 10.77845 Sulfate

Totals : 10.77845

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\037-5902.D Sample Name: MSD/Run 1 0410-10

Instrument 1 5/14/2010 8:16:10 AM ARM Page 1 of 1

# Calibration Curve Chromatograms

### ===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : 5/11/2010 5:55:38 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks
Curve Type : Linear Origin : Connected Weight : Linear (Amnt)
Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 9.489 1 1 1.00000e-1 1.94891 5.13107e-2 Sulfate 2 5.00000e-1 9.20960 5.42912e-2 3 5.00000 107.53530 4.64964e-2 4 10.00000 225.66882 4.43127e-2 5 15.00000 346.48825 4.32915e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 1 of 2

### ===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 50 100 150 200 250 300

1 2 3 4 5 

### Sulfate at exp. RT: 9.489 ADC1 B, ADC2 CHANNEL B Correlation: 0.99952 Residual Std. Dev.: 5.06077 Formula: y = mx + b m: 22.68721 b: -6.75574e-1 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.2 Level 3 : 0.02 Level 4 : 0.01 Level 5 : 0.006667

===================================================================== Method H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M

Instrument 3 5/12/2010 8:15:42 AM ARM Page 2 of 2

### ===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 1:26:39 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D)

A

r ea

: 1.

8 8 94

73.1044.2179.506 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.506 MM 1.88947 5.98375e-2 1.13061e-1 Sulfate

Totals : 1.13061e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0201.D Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:07 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 1:43:28 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D)

A

r ea

: 2.

0 0 83

53.1044.2179.503 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.503 MM 2.00835 5.89047e-2 1.18301e-1 Sulfate

Totals : 1.18301e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\001-0202.D Sample Name: hplc53pg44 #1

Instrument 3 5/12/2010 8:17:29 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:00:15 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D)3.1034.2155.9066.6238.3749.498 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.498 BB 9.16793 4.73257e-2 4.33879e-1 Sulfate

Totals : 4.33879e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0301.D Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:01 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:17:03 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D)3.1044.2165.9066.6228.3769.499 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.499 BB 9.25128 4.72965e-2 4.37553e-1 Sulfate

Totals : 4.37553e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\002-0302.D Sample Name: hplc53pg44 #2

Instrument 3 5/12/2010 8:18:08 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:33:51 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D)3.1124.2135.8866.5878.3539.492 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.492 BB 109.14275 4.43505e-2 4.84054 Sulfate

Totals : 4.84054

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0401.D Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:14 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 2:50:39 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D)3.1124.2135.8866.5878.3539.492 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.492 BB 105.92785 4.43588e-2 4.69883 Sulfate

Totals : 4.69883

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\003-0402.D Sample Name: hplc53pg44 #3

Instrument 3 5/12/2010 8:18:26 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:07:27 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D)3.1244.2155.8816.5778.3509.490 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.490 BB 228.02539 4.42083e-2 10.08061 Sulfate

Totals : 10.08061

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0501.D Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:39 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:24:15 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D)3.1224.2145.8846.5818.3489.488 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.488 BB 223.31224 4.42110e-2 9.87287 Sulfate

Totals : 9.87287

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-0502.D Sample Name: hplc53pg44 #4

Instrument 3 5/12/2010 8:18:46 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:41:03 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D)3.1334.2165.8786.5718.3469.488 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.488 BB 352.66254 4.41621e-2 15.57433 Sulfate

Totals : 15.57433

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0601.D Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:51 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 3:57:51 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D)3.1324.2155.8766.5688.3479.489 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.489 BB 340.31396 4.41652e-2 15.03003 Sulfate

Totals : 15.03003

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\005-0602.D Sample Name: hplc53pg44 #5

Instrument 3 5/12/2010 8:18:58 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 19 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 10:57:49 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1901.D)3.1274.1775.7366.3878.4179.583 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.583 BB 231.36612 4.42064e-2 10.22786 Sulfate

Totals : 10.22786

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1901.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:20:54 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 19 Acq. Instrument : Mr Burns Location : - Injection Date : 5/11/2010 11:14:38 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-1902.D)3.1274.1775.7356.3868.4219.584 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.584 BB 223.56235 4.42109e-2 9.88389 Sulfate

Totals : 9.88389

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-1902.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:21:01 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 28 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 4:00:14 AM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2801.D)3.1294.1755.7246.3738.4239.596 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.596 BB 231.33727 4.42064e-2 10.22659 Sulfate

Totals : 10.22659

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2801.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:05 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 28 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 4:17:01 AM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-2802.D)3.1294.1775.7286.3798.4309.595 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.595 BB 221.99748 4.42118e-2 9.81491 Sulfate

Totals : 9.81491

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-2802.D Sample Name: hplc53pg44 #4

Instrument 1 5/12/2010 9:23:12 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 30 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 10:48:57 AM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3001.D)3.1244.2155.8836.5818.3339.495 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.495 BB 242.00009 4.42007e-2 10.69658 Sulfate

Totals : 10.69658

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3001.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:34 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 30 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 11:05:45 AM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-3002.D)3.1204.2125.8776.5748.3359.496 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.496 BB 219.04594 4.42136e-2 9.68482 Sulfate

Totals : 9.68482

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-3002.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:13:41 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 41 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 4:58:32 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-4102.D)3.1344.2185.8566.5438.4889.649 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.649 BB 241.92140 4.42008e-2 10.69311 Sulfate

Totals : 10.69311

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-4102.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:16:08 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 10:28:28 PM Inj : 1 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5001.D)3.1374.1945.7586.4158.5429.722 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.722 BB 227.11307 4.42088e-2 10.04040 Sulfate

Totals : 10.04040

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5001.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:17:56 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Mr Burns Location : - Injection Date : 5/12/2010 10:45:15 PM Inj : 2 Sequence File : H:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : H:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/11/2010 5:55:50 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5002.D)3.1374.1945.7606.4168.5479.724 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.724 BB 201.75278 4.42253e-2 8.92257 Sulfate

Totals : 8.92257

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5002.D Sample Name: hplc53pg44 #4

Instrument 3 5/13/2010 10:18:03 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 52 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 11:38:20 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/14/2010 8:20:53 AM by ARM (modified after loading)

min 182 184 186 188 190 192 194 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5201.D)183.329184.418186.068186.759188.672189.845 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/14/2010 8:19:04 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 189.845 BB 231.77820 4.42062e-2 10.24603 Sulfate

Totals : 10.24603

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5201.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 8:20:57 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 56 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 4:52:56 PM Inj : 1 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5601.D)3.1384.2165.8416.5228.4959.676 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.676 BB 242.22186 4.42006e-2 10.70636 Sulfate

Totals : 10.70636

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5601.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 8:15:14 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 56 Acq. Instrument : Mr Burns Location : - Injection Date : 5/13/2010 5:09:44 PM Inj : 2 Sequence File : Y:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC53PG44.S Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (HPLC53PG44\004-5602.D)3.1334.2165.8476.5318.4919.672 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.672 BB 210.46223 4.42192e-2 9.30647 Sulfate

Totals : 9.30647

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-5602.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 8:15:22 AM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 63 Acq. Instrument : Mr Burns Location : - Injection Date : 5/14/2010 9:57:05 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6301.D)3.1524.2625.9576.6668.5739.828 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.828 BB 250.22568 4.41967e-2 11.05915 Sulfate

Totals : 11.05915

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6301.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:19:41 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 63 Acq. Instrument : Mr Burns Location : - Injection Date : 5/14/2010 10:13:53 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6302.D)3.1514.2625.9566.6668.5769.830 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.830 BB 235.69072 4.42040e-2 10.41848 Sulfate

Totals : 10.41848

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6302.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:19:55 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 66 Acq. Instrument : Mr Burns Location : - Injection Date : 5/14/2010 11:37:52 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6601.D)3.1524.2515.9156.6118.5909.850 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.850 BB 252.76761 4.41955e-2 11.17119 Sulfate

Totals : 11.17119

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6601.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:21:27 PM ARM Page 1 of 1

### ===================================================================== Acq. Operator : KHB Seq. Line : 66 Acq. Instrument : Mr Burns Location : - Injection Date : 5/14/2010 11:54:39 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\MR BURNS\METHODS\METROHM.M Last changed : 3/23/2010 5:17:01 PM by ARM Analysis Method : Y:\HPLC2010Q2\MR BURNS\METHODS\HPLC53PG44.M Last changed : 5/13/2010 12:47:32 PM by ARM

min 0 2 4 6 8 10 12 14 μS/cm

10 20 30 40 50 60 70 80 90 ADC1 B, ADC2 CHANNEL B (Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6602.D)3.1524.2485.9056.5998.5949.855 - Sulfate



### ===================================================================== External Standard Report

=====================================================================
Sorted By : Signal Calib. Data Modified : 5/11/2010 5:55:38 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs
Signal 1: ADC1 B, ADC2 CHANNEL B
RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 9.855 BB 234.02809 4.42049e-2 10.34520 Sulfate

Totals : 10.34520

===================================================================== *** End of Report *** Data File Y:\HPLC2010Q2\MR BURNS\DATA\APR\HPLC53PG44\004-6602.D Sample Name: hplc53pg44 #4

Instrument 1 5/14/2010 12:21:35 PM ARM Page 1 of 1

### Method Information
Method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified: 1/13/2010 at 7:06:26 AM

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 A, Metrohm Source: Signal Unit: mAU Units/Volt: 100.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All
Start Signal Source: External Device Will Start 35900

Timed Event Table: <no events> method: U:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified on: 1/13/2010 at 7:06:26 AM

Smithers 1/18/2010 7:20:57 AM mgb Page 1 of 1Sequence: C:\HPCHEM\1\SEQUENCE\hplc53pg44.txt
Line Vial Sample Name Method Inj 1 Vial 7 RB/DI H2O METROHM 3 2 Vial 1 hplc53pg44 #1 METROHM 2 3 Vial 2 hplc53pg44 #2 METROHM 2 4 Vial 3 hplc53pg44 #3 METROHM 2 5 Vial 4 hplc53pg44 #4 METROHM 2 6 Vial 5 hplc53pg44 #5 METROHM 2 7 Vial 6 hplc53pg44 #LCS METROHM 2 8 Vial 7 RB/DI H2O METROHM 2 9 Vial 8 Run 1 post*50 0410-10 METROHM 2 10 Vial 9 Run 2 post*50 0410-10 METROHM 2 11 Vial 10 Run 3 post*50 0410-10 METROHM 2 12 Vial 11 Train Blk post*50 0410-10 METROHM 2 13 Vial 12 IHB post*50 0410-10 METROHM 2 14 Vial 13 M8A-R1-C1-SO3*20 0410-10 METROHM 2 15 Vial 14 M8A-R2-C1-SO3*20 0410-10 METROHM 2 16 Vial 15 M8A-R3-C1-SO3*20 0410-10 METROHM 2 17 Vial 16 M8A-BT-C1-SO3*20 0410-10 METROHM 2 18 Vial 3 hplc53pg44 #3 METROHM 2 19 Vial 4 hplc53pg44 #4 METROHM 2 20 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2 21 Vial 18 MeadWestVaco M8R2*20 0510-45 METROHM 2 22 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2 23 Vial 20 M13A-1*20 0510-135 METROHM 2 24 Vial 21 M13A-2*20 0510-135 METROHM 2 25 Vial 22 M13A-3*20 0510-135 METROHM 2 26 Vial 23 IPA Blank*20 0510-135 METROHM 2 27 Vial 3 hplc53pg44 #3 METROHM 2 28 Vial 4 hplc53pg44 #4 METROHM 2 29 Vial 3 hplc53pg44 #3 METROHM 2 30 Vial 4 hplc53pg44 #4 METROHM 2 31 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2 32 Vial 19 MeadWestVaco M8R3*20 0510-45 METROHM 2 33 Vial 24 MS/M8A-R1-C1-SO3 0410-10 METROHM 2 34 Vial 25 MSD/M8A-R1-C1-SO3 0410-10 METROHM 2 35 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2 36 Vial 27 MSD/MeadWestVaco M8R1 0510-45 METROHM 2 37 Vial 28 MS/M13A-1 0510-135 METROHM 2 38 Vial 29 MSD/M13A-1 0510-135 METROHM 2 39 Vial 30 M13A-3*20 0510-135 METROHM 2 40 Vial 3 hplc53pg44 #3 METROHM 2 41 Vial 4 hplc53pg44 #4 METROHM 2 42 Vial 31 Run 1*50 0410-10 METROHM 2 43 Vial 32 Run 2*50 0410-10 METROHM 2 44 Vial 33 Run 3*50 0410-10 METROHM 2 45 Vial 34 Train Blk*20 0410-10 METROHM 2 46 Vial 35 IHB*20 0410-10 METROHM 2 47 Vial 36 MS/Run 1 0410-10 METROHM 2 48 Vial 37 MSD/Run 1 0410-10 METROHM 2 49 Vial 3 hplc53pg44 #3 METROHM 2 50 Vial 4 hplc53pg44 #4 METROHM 2 51 Vial 3 hplc53pg44 #3 METROHM 2 52 Vial 4 hplc53pg44 #4 METROHM 2 53 Vial 17 MeadWestVaco M8R1*20 0510-45 METROHM 2 54 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2 55 Vial 3 hplc53pg44 #3 METROHM 2 56 Vial 4 hplc53pg44 #4 METROHM 2 57 Vial 31 Run 1*50 0410-10 METROHM 2 58 Vial 36 MS/Run 1 0410-10 METROHM 2 59 Vial 37 MSD/Run 1 0410-10 METROHM 2 60 Vial 3 hplc53pg44 #3 METROHM 2 61 Vial 4 hplc53pg44 #4 METROHM 2 62 Vial 3 hplc53pg44 #3 METROHM 2 63 Vial 4 hplc53pg44 #4 METROHM 2 64 Vial 26 MS/MeadWestVaco M8R1 0510-45 METROHM 2 65 Vial 3 hplc53pg44 #3 METROHM 2 66 Vial 4 hplc53pg44 #4 METROHM 2

# This Is The Last Page Of This Report.

### 5/7/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood MO 63042

Project Name: KCP&L ICR Testing Project #:

Dear Mr. Frank Stevens
The following report includes the data for the above referenced project for sample(s) received on 4/24/2010 at Air Toxics Ltd. The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding the data in this report.

Regards,

Ausha Scott Project Manager Workorder #: 1004525A

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020 Hours 6:30 A.M to 5:30 PST

Page 1 of 63

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1004525A

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 04/24/2010 DATE COMPLETED: 

### 05/06/2010 P.O. # 

### 100-208-0001
PROJECT # 

### KCP&L ICR Testing 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Ausha Scott

NAME FRACTION # TEST 

### 01AB M0031-R1-TS1-C1-Tenax/M0031-R1-TS1- Modified VOST 5041A/8260 01C M0031-R1-TS1-C4-Anasorb Modified VOST 5041A/8260 02A M0031-R1-TS1-C3-Condensate Modified VOST 5041A/8260 03AB M0031-R1-TS2-C1-Tenax/M0031-R1-TS2- Modified VOST 5041A/8260 03C M0031-R1-TS2-C4-Anasorb Modified VOST 5041A/8260 04AB M0031-R1-TS3-C1-Tenax/M0031-R1-TS3- Modified VOST 5041A/8260 04C M0031-R1-TS3-C4-Anasorb Modified VOST 5041A/8260 05AB M0031-R1-TS4-C1-Tenax/M0031-R1-TS4- Modified VOST 5041A/8260 05C M0031-R1-TS4-C4-Anasorb Modified VOST 5041A/8260 06AB M0031-R2-TS1-C1-Tenax/M0031-R2-TS1- Modified VOST 5041A/8260 06C M0031-R2-TS1-C4-Anasorb Modified VOST 5041A/8260 07AB M0031-R2-TS2-C1-Tenax/M0031-R2-TS2- Modified VOST 5041A/8260 07C M0031-R2-TS2-C4-Anasorb Modified VOST 5041A/8260 08AB M0031-R2-TS3-C1-Tenax/M0031-R2-TS3- Modified VOST 5041A/8260 09A Lab Blank Modified VOST 5041A/8260 09B Lab Blank Modified VOST 5041A/8260 10A LCS Modified VOST 5041A/8260

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 2 of 63 

### Continued on next page

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1004525A

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 04/24/2010 DATE COMPLETED: 

### 05/06/2010 P.O. # 

### 100-208-0001
PROJECT # 

### KCP&L ICR Testing 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Ausha Scott

NAME FRACTION # TEST 

### 10B LCS Modified VOST 5041A/8260

CERTIFIED BY: Laboratory Director DATE:



### Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act,

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020 

### 05/07/10

Page 3 of 63 This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd. 

### Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719

## LABORATORY NARRATIVE VOST 5041A Civil & Environmental Consultants, Inc. Workorder# 1004525A Laboratory Services Since 1989



## Nineteen VOST 0031 Tube and one VOA Vial-40 mL samples were received on April 24, 2010. The laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components into the GC/MS system for further separation. See the data sheets for the reporting limits for each compound.
Requirement ATL Modifications VOST 5041A 

### Batch Certification Blanks from the same media as samples Analysis of set of cartridges prior to onset of any project; Sampling media provided by the client is batch certified ahead of time, only if client provides blank cartridges.
Method blank Cartridges from the same media batches as the samples Media batch is certified prior to use in the field. Method Blank is used to certify instrument is contaminant free

Connection between cartridge thermal desorption apparatus & sample purge vessel PTFE 1/16" Teflon tubing Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for non-CCCs RSD +- 15 % for all non-CCCs RSD </= 30 % for some compounds: Acetone, Bromoform, Vinyl Acetate, Bromomethane, Chloromethane, 1,1,2,2-Tetracholoroethane, & 1,2,3-Trichloropropane



## Receiving Notes The Chain of Custody (COC) information for samples M0031-R1-TS3-C4-Anasorb and M0031-R1-TS4-C4-Anasorb did not match the entries on the sample tags with regard to sample identification. Therefore the information on the COC was used to process and report the samples.

Per client request, compounds that are not validated under Method 0031 collection protocols were reported in this work order. These compounds may not be suitable for collection by Method 0031 due to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory analytical method 5041A/8260B is validated for all target analytes.
Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the Anasorb. In addition the laboratory method has not been validated for recovery of these additional compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Each tube was spiked with Dibromofluoromethane, 1,2-Dichloroethane-d4, Toluene-d8 and 4-Bromofluorobenzene prior to shipment to the field as an additional QC step.

The recoveries of surrogates Dibromofluoromethane and 1,2-Dichloroethane-d4 in samples Analytical Notes

Page 4 of 63Laboratory Services Since 1989



## M0031-R1-TS4-C4-Anasorb, M0031-R2-TS1-C4-Anasorb, and M0031-R2-TS2-C4-Anasorb was outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as qualified.

The recovery of surrogate Toluene-d8 in samples M0031-R1-TS1-C4-Anasorb, M0031-R1-TS2-C4-Anasorb, M0031-R1-TS3-C4-Anasorb, M0031-R1-TS4-C4-Anasorb, M0031-R2-TS1-C4-Anasorb, and M0031-R2-TS2-C4-Anasorb was outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target compound non-detects in the samples that are associated with high bias in QC analyses have not been flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows: B

- Compound present in laboratory blank or tube certification greater than reporting limit (background subtraction not performed). J

- Estimated value. E

- Exceeds instrument calibration range. S

- Saturated peak. Q

- Exceeds quality control limits. U

- Compound analyzed for but not detected above the detection limit. N

- The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags

Page 5 of 63

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax
Lab ID#: 1004525A-01AB
(ng) (ng) Compound Amount Rpt. Limit

50 160 Acetone 10 340 Methylene Chloride 10 31 Hexane 10 19 Benzene 10 160 Toluene 10 27 Ethyl Benzene 10 98 m,p-Xylene 10 21 o-Xylene



### Client Sample ID: M0031-R1-TS1-C4-Anasorb
Lab ID#: 1004525A-01C
(ng) (ng) Compound Amount Rpt. Limit

50 2100 E Chloromethane 10 44 Bromomethane 50 56 Acetone 10 820 Methylene Chloride 10 39 Freon 12



### Client Sample ID: M0031-R1-TS1-C3-Condensate
Lab ID#: 1004525A-02A
(ng) (ng) Compound Amount Rpt. Limit

400 640 Acetone 80 24000 E Methylene Chloride 80 110 Chloroform



### Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax
Lab ID#: 1004525A-03AB
(ng) (ng) Compound Amount Rpt. Limit

50 98 Acetone 10 30 Methylene Chloride 10 14 Benzene 10 87 Toluene
Page 6 of 63

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax
Lab ID#: 1004525A-03AB 10 13 Ethyl Benzene 10 48 m,p-Xylene 10 11 o-Xylene



### Client Sample ID: M0031-R1-TS2-C4-Anasorb
Lab ID#: 1004525A-03C
(ng) (ng) Compound Amount Rpt. Limit

50 1800 Chloromethane 10 56 Bromomethane 10 13 Freon 11 10 160 Methylene Chloride 10 55 Freon 12



### Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax
Lab ID#: 1004525A-04AB
(ng) (ng) Compound Amount Rpt. Limit

10 44 Methylene Chloride 10 44 Toluene 10 28 m,p-Xylene



### Client Sample ID: M0031-R1-TS3-C4-Anasorb
Lab ID#: 1004525A-04C
(ng) (ng) Compound Amount Rpt. Limit

50 2200 E Chloromethane 10 67 Bromomethane 10 39 Freon 11 10 2400 E Methylene Chloride 10 10 Hexane 10 26 Freon 12



### Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax
Lab ID#: 1004525A-05AB

Page 7 of 63

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax
Lab ID#: 1004525A-05AB
(ng) (ng) Compound Amount Rpt. Limit

10 45 Methylene Chloride 10 28 Toluene 10 15 m,p-Xylene



### Client Sample ID: M0031-R1-TS4-C4-Anasorb
Lab ID#: 1004525A-05C
(ng) (ng) Compound Amount Rpt. Limit

50 1200 Chloromethane 10 54 Bromomethane 10 190 Methylene Chloride 10 25 Freon 12



### Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax
Lab ID#: 1004525A-06AB
(ng) (ng) Compound Amount Rpt. Limit

50 61 Acetone 10 230 Methylene Chloride 10 11 Benzene 10 36 Toluene 10 26 m,p-Xylene



### Client Sample ID: M0031-R2-TS1-C4-Anasorb
Lab ID#: 1004525A-06C
(ng) (ng) Compound Amount Rpt. Limit

50 1400 Chloromethane 10 99 Bromomethane 10 30 Methylene Chloride 10 23 Freon 12



### Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax
Lab ID#: 1004525A-07AB
Page 8 of 63

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax
Lab ID#: 1004525A-07AB
(ng) (ng) Compound Amount Rpt. Limit

10 63 Methylene Chloride 10 27 Toluene 10 13 m,p-Xylene



### Client Sample ID: M0031-R2-TS2-C4-Anasorb
Lab ID#: 1004525A-07C
(ng) (ng) Compound Amount Rpt. Limit

50 1200 Chloromethane 10 30 Bromomethane 10 130 Methylene Chloride 10 26 Freon 12



### Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax
Lab ID#: 1004525A-08AB
(ng) (ng) Compound Amount Rpt. Limit

10 26 Methylene Chloride 10 21 Toluene 10 11 m,p-Xylene

Page 9 of 63

### Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax Lab ID#: 1004525A-01AB MODIFIED VOST 5041A/8260B

4042918 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 05:41 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 160 Acetone 50 Not Detected 3-Chloropropene 10 340 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 31 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 19 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 160 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 10 of 63

### Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax Lab ID#: 1004525A-01AB MODIFIED VOST 5041A/8260B

4042918 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 05:41 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 27 Ethyl Benzene 10 98 m,p-Xylene 10 21 o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

107 70-130 Dibromofluoromethane

Page 11 of 63

### Client Sample ID: M0031-R1-TS1-C1-Tenax/M0031-R1-TS1-C2-Tenax Lab ID#: 1004525A-01AB MODIFIED VOST 5041A/8260B

4042918 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 05:41 PM

Limits %Recovery Surrogates Method

108 70-130 1,2-Dichloroethane-d4 119 70-130 Toluene-d8 109 70-130 4-Bromofluorobenzene

Page 12 of 63

### Client Sample ID: M0031-R1-TS1-C4-Anasorb Lab ID#: 1004525A-01C MODIFIED VOST 5041A/8260B

4042911 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 02:04 PM

(ng) (ng) Compound Amount Rpt. Limit

50 2100 E Chloromethane 10 Not Detected Vinyl Chloride 10 44 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 56 Acetone 50 Not Detected 3-Chloropropene 10 820 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 13 of 63

### Client Sample ID: M0031-R1-TS1-C4-Anasorb Lab ID#: 1004525A-01C MODIFIED VOST 5041A/8260B

4042911 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 02:04 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 39 Freon 12
E = Exceeds instrument calibration range. Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 14 of 63

### Client Sample ID: M0031-R1-TS1-C4-Anasorb Lab ID#: 1004525A-01C MODIFIED VOST 5041A/8260B

4042911 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 02:04 PM

Limits %Recovery Surrogates Method

62 50-150 Dibromofluoromethane 53 50-150 1,2-Dichloroethane-d4 15 Q 50-150 Toluene-d8

Page 15 of 63

### Client Sample ID: M0031-R1-TS1-C3-Condensate Lab ID#: 1004525A-02A MODIFIED VOST 5041A/8260B

4042909 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 12:50 PM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 640 Acetone 400 Not Detected 3-Chloropropene 80 24000 E Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 Not Detected 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 110 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 16 of 63

### Client Sample ID: M0031-R1-TS1-C3-Condensate Lab ID#: 1004525A-02A MODIFIED VOST 5041A/8260B

4042909 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 12:50 PM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
E = Exceeds instrument calibration range. Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

Page 17 of 63

### Client Sample ID: M0031-R1-TS1-C3-Condensate Lab ID#: 1004525A-02A MODIFIED VOST 5041A/8260B

4042909 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 12:50 PM

Limits %Recovery Surrogates Method

96 70-130 Dibromofluoromethane 93 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 100 70-130 4-Bromofluorobenzene

Page 18 of 63

### Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax Lab ID#: 1004525A-03AB MODIFIED VOST 5041A/8260B

4042917 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 05:16 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 98 Acetone 50 Not Detected 3-Chloropropene 10 30 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 14 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 87 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 19 of 63

### Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax Lab ID#: 1004525A-03AB MODIFIED VOST 5041A/8260B

4042917 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 05:16 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 13 Ethyl Benzene 10 48 m,p-Xylene 10 11 o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

102 70-130 Dibromofluoromethane

Page 20 of 63

### Client Sample ID: M0031-R1-TS2-C1-Tenax/M0031-R1-TS2-C2-Tenax Lab ID#: 1004525A-03AB MODIFIED VOST 5041A/8260B

4042917 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 05:16 PM

Limits %Recovery Surrogates Method

112 70-130 1,2-Dichloroethane-d4 119 70-130 Toluene-d8 107 70-130 4-Bromofluorobenzene

Page 21 of 63

### Client Sample ID: M0031-R1-TS2-C4-Anasorb Lab ID#: 1004525A-03C MODIFIED VOST 5041A/8260B

4042912 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 02:28 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1800 Chloromethane 10 Not Detected Vinyl Chloride 10 56 Bromomethane 50 Not Detected Chloroethane 10 13 Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 160 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 22 of 63

### Client Sample ID: M0031-R1-TS2-C4-Anasorb Lab ID#: 1004525A-03C MODIFIED VOST 5041A/8260B

4042912 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 02:28 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 55 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 23 of 63

### Client Sample ID: M0031-R1-TS2-C4-Anasorb Lab ID#: 1004525A-03C MODIFIED VOST 5041A/8260B

4042912 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 02:28 PM

Limits %Recovery Surrogates Method

101 50-150 Dibromofluoromethane 91 50-150 1,2-Dichloroethane-d4 35 Q 50-150 Toluene-d8

Page 24 of 63

### Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax Lab ID#: 1004525A-04AB MODIFIED VOST 5041A/8260B

4042920 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 06:42 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 44 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 44 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 25 of 63

### Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax Lab ID#: 1004525A-04AB MODIFIED VOST 5041A/8260B

4042920 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 06:42 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 28 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

96 70-130 Dibromofluoromethane

Page 26 of 63

### Client Sample ID: M0031-R1-TS3-C1-Tenax/M0031-R1-TS3-C2-Tenax Lab ID#: 1004525A-04AB MODIFIED VOST 5041A/8260B

4042920 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 06:42 PM

Limits %Recovery Surrogates Method

98 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 100 70-130 4-Bromofluorobenzene

Page 27 of 63

### Client Sample ID: M0031-R1-TS3-C4-Anasorb Lab ID#: 1004525A-04C MODIFIED VOST 5041A/8260B

4042914 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 03:32 PM

(ng) (ng) Compound Amount Rpt. Limit

50 2200 E Chloromethane 10 Not Detected Vinyl Chloride 10 67 Bromomethane 50 Not Detected Chloroethane 10 39 Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 2400 E Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 10 Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 28 of 63

### Client Sample ID: M0031-R1-TS3-C4-Anasorb Lab ID#: 1004525A-04C MODIFIED VOST 5041A/8260B

4042914 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 03:32 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 26 Freon 12
E = Exceeds instrument calibration range. Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 29 of 63

### Client Sample ID: M0031-R1-TS3-C4-Anasorb Lab ID#: 1004525A-04C MODIFIED VOST 5041A/8260B

4042914 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 03:32 PM

Limits %Recovery Surrogates Method

61 50-150 Dibromofluoromethane 50 50-150 1,2-Dichloroethane-d4 15 Q 50-150 Toluene-d8

Page 30 of 63

### Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax Lab ID#: 1004525A-05AB MODIFIED VOST 5041A/8260B

4042921 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 07:08 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 45 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 28 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 31 of 63

### Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax Lab ID#: 1004525A-05AB MODIFIED VOST 5041A/8260B

4042921 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 07:08 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 15 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

95 70-130 Dibromofluoromethane

Page 32 of 63

### Client Sample ID: M0031-R1-TS4-C1-Tenax/M0031-R1-TS4-C2-Tenax Lab ID#: 1004525A-05AB MODIFIED VOST 5041A/8260B

4042921 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/29/10 07:08 PM

Limits %Recovery Surrogates Method

97 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 101 70-130 4-Bromofluorobenzene

Page 33 of 63

### Client Sample ID: M0031-R1-TS4-C4-Anasorb Lab ID#: 1004525A-05C MODIFIED VOST 5041A/8260B

4043007 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/30/10 11:32 AM

(ng) (ng) Compound Amount Rpt. Limit

50 1200 Chloromethane 10 Not Detected Vinyl Chloride 10 54 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 190 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 34 of 63

### Client Sample ID: M0031-R1-TS4-C4-Anasorb Lab ID#: 1004525A-05C MODIFIED VOST 5041A/8260B

4043007 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/30/10 11:32 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 25 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 35 of 63

### Client Sample ID: M0031-R1-TS4-C4-Anasorb Lab ID#: 1004525A-05C MODIFIED VOST 5041A/8260B

4043007 File Name: Dil. Factor: 1.00 Date of Collection: 4/21/10 Date of Analysis: 4/30/10 11:32 AM

Limits %Recovery Surrogates Method

18 Q 50-150 Dibromofluoromethane 12 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 36 of 63

### Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax Lab ID#: 1004525A-06AB MODIFIED VOST 5041A/8260B

4042922 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/29/10 08:42 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 61 Acetone 50 Not Detected 3-Chloropropene 10 230 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 11 Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 36 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 37 of 63

### Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax Lab ID#: 1004525A-06AB MODIFIED VOST 5041A/8260B

4042922 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/29/10 08:42 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 26 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

82 70-130 Dibromofluoromethane

Page 38 of 63

### Client Sample ID: M0031-R2-TS1-C1-Tenax/M0031-R2-TS1-C2-Tenax Lab ID#: 1004525A-06AB MODIFIED VOST 5041A/8260B

4042922 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/29/10 08:42 PM

Limits %Recovery Surrogates Method

78 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 81 70-130 4-Bromofluorobenzene

Page 39 of 63

### Client Sample ID: M0031-R2-TS1-C4-Anasorb Lab ID#: 1004525A-06C MODIFIED VOST 5041A/8260B

4043008 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 12:10 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1400 Chloromethane 10 Not Detected Vinyl Chloride 10 99 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 30 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 40 of 63

### Client Sample ID: M0031-R2-TS1-C4-Anasorb Lab ID#: 1004525A-06C MODIFIED VOST 5041A/8260B

4043008 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 12:10 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 23 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 41 of 63

### Client Sample ID: M0031-R2-TS1-C4-Anasorb Lab ID#: 1004525A-06C MODIFIED VOST 5041A/8260B

4043008 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 12:10 PM

Limits %Recovery Surrogates Method

23 Q 50-150 Dibromofluoromethane 14 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 42 of 63

### Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax Lab ID#: 1004525A-07AB MODIFIED VOST 5041A/8260B

4043015 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 03:44 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 63 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 27 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 43 of 63

### Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax Lab ID#: 1004525A-07AB MODIFIED VOST 5041A/8260B

4043015 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 03:44 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 13 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

88 70-130 Dibromofluoromethane

Page 44 of 63

### Client Sample ID: M0031-R2-TS2-C1-Tenax/M0031-R2-TS2-C2-Tenax Lab ID#: 1004525A-07AB MODIFIED VOST 5041A/8260B

4043015 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 03:44 PM

Limits %Recovery Surrogates Method

82 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 95 70-130 4-Bromofluorobenzene

Page 45 of 63

### Client Sample ID: M0031-R2-TS2-C4-Anasorb Lab ID#: 1004525A-07C MODIFIED VOST 5041A/8260B

4043017 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 04:44 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1200 Chloromethane 10 Not Detected Vinyl Chloride 10 30 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 130 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 46 of 63

### Client Sample ID: M0031-R2-TS2-C4-Anasorb Lab ID#: 1004525A-07C MODIFIED VOST 5041A/8260B

4043017 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 04:44 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 26 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 47 of 63

### Client Sample ID: M0031-R2-TS2-C4-Anasorb Lab ID#: 1004525A-07C MODIFIED VOST 5041A/8260B

4043017 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 04:44 PM

Limits %Recovery Surrogates Method

12 Q 50-150 Dibromofluoromethane 8.7 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 48 of 63

### Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax Lab ID#: 1004525A-08AB MODIFIED VOST 5041A/8260B

4042923 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/29/10 09:38 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 26 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 21 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 49 of 63

### Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax Lab ID#: 1004525A-08AB MODIFIED VOST 5041A/8260B

4042923 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/29/10 09:38 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 11 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

78 70-130 Dibromofluoromethane

Page 50 of 63

### Client Sample ID: M0031-R2-TS3-C1-Tenax/M0031-R2-TS3-C2-Tenax Lab ID#: 1004525A-08AB MODIFIED VOST 5041A/8260B

4042923 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/29/10 09:38 PM

Limits %Recovery Surrogates Method

76 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 87 70-130 4-Bromofluorobenzene

Page 51 of 63

### Client Sample ID: Lab Blank Lab ID#: 1004525A-09A MODIFIED VOST 5041A/8260B

4042907 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/29/10 11:37 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 52 of 63

### Client Sample ID: Lab Blank Lab ID#: 1004525A-09A MODIFIED VOST 5041A/8260B

4042907 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/29/10 11:37 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

94 70-130 Dibromofluoromethane

Page 53 of 63

### Client Sample ID: Lab Blank Lab ID#: 1004525A-09A MODIFIED VOST 5041A/8260B

4042907 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/29/10 11:37 AM

Limits %Recovery Surrogates Method

98 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 98 70-130 4-Bromofluorobenzene

Page 54 of 63

### Client Sample ID: Lab Blank Lab ID#: 1004525A-09B MODIFIED VOST 5041A/8260B

4043006 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:53 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 55 of 63

### Client Sample ID: Lab Blank Lab ID#: 1004525A-09B MODIFIED VOST 5041A/8260B

4043006 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:53 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

92 70-130 Dibromofluoromethane

Page 56 of 63

### Client Sample ID: Lab Blank Lab ID#: 1004525A-09B MODIFIED VOST 5041A/8260B

4043006 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:53 AM

Limits %Recovery Surrogates Method

93 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 97 70-130 4-Bromofluorobenzene

Page 57 of 63

### Client Sample ID: LCS Lab ID#: 1004525A-10A MODIFIED VOST 5041A/8260B

4042906 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/29/10 11:12 AM

%Recovery Compound
129 Chloromethane 108 Vinyl Chloride 95 Bromomethane 101 Chloroethane 136 Q Freon 11 151 Q 2-Chloropropane 118 1,1-Dichloroethene 136 Q Freon 113 130 Carbon Disulfide 98 Acetone 136 Q 3-Chloropropene 101 Methylene Chloride 102 trans-1,2-Dichloroethene 95 Acrylonitrile 131 Q Hexane 111 1,1-Dichloroethane Not Spiked Vinyl Acetate 101 2,2-Dichloropropane 96 cis-1,2-Dichloroethene 90 2-Butanone (Methyl Ethyl Ketone) 99 Bromochloromethane 105 Chloroform 104 1,1,1-Trichloroethane 99 Carbon Tetrachloride 110 1,1-Dichloropropene 106 Benzene 99 1,2-Dichloroethane 103 Trichloroethene 107 1,2-Dichloropropane 99 Dibromomethane 92 Bromodichloromethane 97 cis-1,3-Dichloropropene 100 trans-1,3-Dichloropropene 94 4-Methyl-2-pentanone 110 Toluene 93 1,1,2-Trichloroethane 106 Tetrachloroethene 96 1,3-Dichloropropane 96 2-Hexanone

Page 58 of 63

### Client Sample ID: LCS Lab ID#: 1004525A-10A MODIFIED VOST 5041A/8260B

4042906 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/29/10 11:12 AM

%Recovery Compound
86 Dibromochloromethane 108 Chlorobenzene 90 1,2-Dibromoethane (EDB) 110 Ethyl Benzene 113 m,p-Xylene 108 o-Xylene 107 Styrene 75 Bromoform 92 1,1,2,2-Tetrachloroethane 110 1,3-Dichlorobenzene 110 1,4-Dichlorobenzene 106 1,2-Dichlorobenzene 121 Cumene 88 cis-1,4-Dichloro-2-butene 105 Bromobenzene 86 1,2,3-Trichloropropane 95 trans-1,4-Dichloro-2-butene 105 Propylbenzene 107 2-Chlorotoluene 110 4-Chlorotoluene 109 1,3,5-Trimethylbenzene 106 tert-Butylbenzene 106 1,2,4-Trimethylbenzene 110 sec-Butylbenzene 112 p-Cymene 63 Q 1,2-Dibromo-3-chloropropane 97 1,2,4-Trichlorobenzene 85 Naphthalene 101 Hexachlorobutadiene 91 1,2,3-Trichlorobenzene 101 1,1,1,2-Tetrachloroethane 112 Butylbenzene 90 Iodomethane 104 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 59 of 63

### Client Sample ID: LCS Lab ID#: 1004525A-10A MODIFIED VOST 5041A/8260B

4042906 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/29/10 11:12 AM

Limits %Recovery Surrogates Method

98 70-130 Dibromofluoromethane 99 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 97 70-130 4-Bromofluorobenzene

Page 60 of 63

### Client Sample ID: LCS Lab ID#: 1004525A-10B MODIFIED VOST 5041A/8260B

4043005 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:28 AM

%Recovery Compound
126 Chloromethane 105 Vinyl Chloride 96 Bromomethane 82 Chloroethane 133 Q Freon 11 144 Q 2-Chloropropane 118 1,1-Dichloroethene 135 Q Freon 113 134 Q Carbon Disulfide 88 Acetone 133 Q 3-Chloropropene 100 Methylene Chloride 102 trans-1,2-Dichloroethene 90 Acrylonitrile 127 Hexane 109 1,1-Dichloroethane Not Spiked Vinyl Acetate 100 2,2-Dichloropropane 99 cis-1,2-Dichloroethene 87 2-Butanone (Methyl Ethyl Ketone) 97 Bromochloromethane 107 Chloroform 105 1,1,1-Trichloroethane 100 Carbon Tetrachloride 112 1,1-Dichloropropene 107 Benzene 98 1,2-Dichloroethane 101 Trichloroethene 104 1,2-Dichloropropane 96 Dibromomethane 91 Bromodichloromethane 96 cis-1,3-Dichloropropene 99 trans-1,3-Dichloropropene 88 4-Methyl-2-pentanone 111 Toluene 93 1,1,2-Trichloroethane 108 Tetrachloroethene 95 1,3-Dichloropropane 93 2-Hexanone

Page 61 of 63

### Client Sample ID: LCS Lab ID#: 1004525A-10B MODIFIED VOST 5041A/8260B

4043005 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:28 AM

%Recovery Compound
84 Dibromochloromethane 109 Chlorobenzene 88 1,2-Dibromoethane (EDB) 111 Ethyl Benzene 114 m,p-Xylene 109 o-Xylene 108 Styrene 72 Bromoform 90 1,1,2,2-Tetrachloroethane 112 1,3-Dichlorobenzene 110 1,4-Dichlorobenzene 106 1,2-Dichlorobenzene 122 Cumene 78 cis-1,4-Dichloro-2-butene 108 Bromobenzene 90 1,2,3-Trichloropropane 88 trans-1,4-Dichloro-2-butene 108 Propylbenzene 110 2-Chlorotoluene 114 4-Chlorotoluene 112 1,3,5-Trimethylbenzene 108 tert-Butylbenzene 109 1,2,4-Trimethylbenzene 113 sec-Butylbenzene 114 p-Cymene 62 Q 1,2-Dibromo-3-chloropropane 97 1,2,4-Trichlorobenzene 78 Naphthalene 102 Hexachlorobutadiene 87 1,2,3-Trichlorobenzene 100 1,1,1,2-Tetrachloroethane 113 Butylbenzene 86 Iodomethane 98 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 62 of 63

### Client Sample ID: LCS Lab ID#: 1004525A-10B MODIFIED VOST 5041A/8260B

4043005 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:28 AM

Limits %Recovery Surrogates Method

96 70-130 Dibromofluoromethane 95 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 100 70-130 4-Bromofluorobenzene

Page 63 of 63

### 5/7/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood MO 63042

Project Name: KCP&L ICR Testing Project #:

Dear Mr. Frank Stevens
The following report includes the data for the above referenced project for sample(s) received on 4/24/2010 at Air Toxics Ltd. The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding the data in this report.

Regards,

Ausha Scott Project Manager Workorder #: 1004525B

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020 Hours 6:30 A.M to 5:30 PST

Page 1 of 58

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1004525B

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 04/24/2010 DATE COMPLETED: 

### 05/06/2010 P.O. # 

### 100-208-0001
PROJECT # 

### KCP&L ICR Testing 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Ausha Scott

NAME FRACTION # TEST 

### 08C M0031-R2-TS3-C4-Anasorb Modified VOST 5041A/8260 09AB M0031-R2-TS4-C1-Tenax/M0031-R2-TS4- Modified VOST 5041A/8260 09C M0031-R2-TS4-C4-Anasorb Modified VOST 5041A/8260 10A M0031-R2-TS4-C3-Condensate Modified VOST 5041A/8260 11AB M0031-R3-TS1-C1-Tenax/M0031-R3-TS1- Modified VOST 5041A/8260 11C M0031-R3-TS1-C3-Anasorb Modified VOST 5041A/8260 12AB M0031-R3-TS2-C1-Tenax/M0031-R3-TS2- Modified VOST 5041A/8260 12C M0031-R3-TS2-C4-Anasorb Modified VOST 5041A/8260 13AB M0031-R3-TS3-C1-Tenax/M0031-R3-TS3- Modified VOST 5041A/8260 13C M0031-R3-TS3-C4-Anasorb Modified VOST 5041A/8260 14AB M0031-R3-TS4-C1-Tenax/M0031-R3-TS4- Modified VOST 5041A/8260 14C M0031-R3-TS4-C4-Anasorb Modified VOST 5041A/8260 15A M0031-R3-TS4-C3-Condensate Modified VOST 5041A/8260 16A Lab Blank Modified VOST 5041A/8260 16B Lab Blank Modified VOST 5041A/8260 17A LCS Modified VOST 5041A/8260 17B LCS Modified VOST 5041A/8260

CERTIFIED BY: Laboratory Director DATE:



### Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act,

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020 

### 05/07/10

Page 2 of 58 This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd. 

### Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719

## LABORATORY NARRATIVE VOST 5041A Civil & Environmental Consultants, Inc. Workorder# 1004525B Laboratory Services Since 1989



## Seventeen VOST 0031 Tube and two VOA Vial-40 mL samples were received on April 24, 2010. The laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components into the GC/MS system for further separation. See the data sheets for the reporting limits for each compound.
Requirement ATL Modifications VOST 5041A 

### Batch Certification Blanks from the same media as samples Analysis of set of cartridges prior to onset of any project; Sampling media provided by the client is batch certified ahead of time, only if client provides blank cartridges.
Method blank Cartridges from the same media batches as the samples Media batch is certified prior to use in the field. Method Blank is used to certify instrument is contaminant free

Connection between cartridge thermal desorption apparatus & sample purge vessel PTFE 1/16" Teflon tubing Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for non-CCCs RSD +- 15 % for all non-CCCs RSD </= 30 % for some compounds: Acetone, Bromoform, Vinyl Acetate, Bromomethane, Chloromethane, 1,1,2,2-Tetracholoroethane, & 1,2,3-Trichloropropane



## Receiving Notes There were no receiving discrepancies.

Per client request, compounds that are not validated under Method 0031 collection protocols were reported in this work order. These compounds may not be suitable for collection by Method 0031 due to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory analytical method 5041A/8260B is validated for all target analytes.
Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the Anasorb. In addition the laboratory method has not been validated for recovery of these additional compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Each tube was spiked with Dibromofluoromethane, 1,2-Dichloroethane-d4, Toluene-d8 and 4-Bromofluorobenzene prior to shipment to the field as an additional QC step.

The recoveries of surrogates Dibromofluoromethane, 1,2-Dichloroethane-d4, and Toluene-d8 in samples M0031-R2-TS3-C4-Anasorb, M0031-R2-TS4-C4-Anasorb, M0031-R3-TS1-C3-Anasorb, M0031-R3-TS2-C4-Anasorb, M0031-R3-TS3-C4-Anasorb and M0031-R3-TS4-C4-Anasorb was Analytical Notes

Page 3 of 58Laboratory Services Since 1989



## outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target compound non-detects in the samples that are associated with high bias in QC analyses have not been flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows: B

- Compound present in laboratory blank or tube certification greater than reporting limit (background subtraction not performed). J

- Estimated value. E

- Exceeds instrument calibration range. S

- Saturated peak. Q

- Exceeds quality control limits. U

- Compound analyzed for but not detected above the detection limit. N

- The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags

Page 4 of 58

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R2-TS3-C4-Anasorb
Lab ID#: 1004525B-08C
(ng) (ng) Compound Amount Rpt. Limit

50 1300 Chloromethane 10 77 Bromomethane 10 28 Methylene Chloride 10 26 Freon 12



### Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax
Lab ID#: 1004525B-09AB
(ng) (ng) Compound Amount Rpt. Limit

10 42 Methylene Chloride 10 31 Toluene 10 13 m,p-Xylene



### Client Sample ID: M0031-R2-TS4-C4-Anasorb
Lab ID#: 1004525B-09C
(ng) (ng) Compound Amount Rpt. Limit

50 1500 Chloromethane 10 67 Bromomethane 10 70 Methylene Chloride 10 23 Freon 12



### Client Sample ID: M0031-R2-TS4-C3-Condensate
Lab ID#: 1004525B-10A
(ng) (ng) Compound Amount Rpt. Limit

400 710 Acetone 80 24000 E Methylene Chloride 80 110 Chloroform



### Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax
Lab ID#: 1004525B-11AB
(ng) (ng) Compound Amount Rpt. Limit

Page 5 of 58

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax
Lab ID#: 1004525B-11AB
(ng) (ng) Compound Amount Rpt. Limit

10 27 Methylene Chloride 10 17 Toluene



### Client Sample ID: M0031-R3-TS1-C3-Anasorb
Lab ID#: 1004525B-11C
(ng) (ng) Compound Amount Rpt. Limit

50 1500 Chloromethane 10 64 Bromomethane 10 20 Methylene Chloride 10 27 Freon 12



### Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax
Lab ID#: 1004525B-12AB
(ng) (ng) Compound Amount Rpt. Limit

10 31 Methylene Chloride 10 13 Toluene



### Client Sample ID: M0031-R3-TS2-C4-Anasorb
Lab ID#: 1004525B-12C
(ng) (ng) Compound Amount Rpt. Limit

50 2800 E Chloromethane 10 100 Bromomethane 10 68 Methylene Chloride 10 27 Freon 12



### Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax
Lab ID#: 1004525B-13AB
(ng) (ng) Compound Amount Rpt. Limit

10 68 Methylene Chloride 10 15 Toluene
Page 6 of 58

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-R3-TS3-C4-Anasorb
Lab ID#: 1004525B-13C
(ng) (ng) Compound Amount Rpt. Limit

50 5400 E Chloromethane 10 99 Bromomethane 10 36 Methylene Chloride 10 29 Freon 12



### Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax
Lab ID#: 1004525B-14AB
(ng) (ng) Compound Amount Rpt. Limit

10 54 Methylene Chloride 10 18 Toluene



### Client Sample ID: M0031-R3-TS4-C4-Anasorb
Lab ID#: 1004525B-14C
(ng) (ng) Compound Amount Rpt. Limit

50 1800 Chloromethane 10 60 Bromomethane 10 44 Methylene Chloride 10 31 Freon 12



### Client Sample ID: M0031-R3-TS4-C3-Condensate
Lab ID#: 1004525B-15A
(ng) (ng) Compound Amount Rpt. Limit

400 650 Acetone 80 23000 E Methylene Chloride 80 85 Chloroform

Page 7 of 58

### Client Sample ID: M0031-R2-TS3-C4-Anasorb Lab ID#: 1004525B-08C MODIFIED VOST 5041A/8260B

4043009 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 12:43 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1300 Chloromethane 10 Not Detected Vinyl Chloride 10 77 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 28 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 8 of 58

### Client Sample ID: M0031-R2-TS3-C4-Anasorb Lab ID#: 1004525B-08C MODIFIED VOST 5041A/8260B

4043009 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 12:43 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 26 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 9 of 58

### Client Sample ID: M0031-R2-TS3-C4-Anasorb Lab ID#: 1004525B-08C MODIFIED VOST 5041A/8260B

4043009 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 12:43 PM

Limits %Recovery Surrogates Method

23 Q 50-150 Dibromofluoromethane 15 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 10 of 58

### Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax Lab ID#: 1004525B-09AB MODIFIED VOST 5041A/8260B

4043014 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 03:16 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 42 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 31 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 11 of 58

### Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax Lab ID#: 1004525B-09AB MODIFIED VOST 5041A/8260B

4043014 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 03:16 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 13 m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

87 70-130 Dibromofluoromethane

Page 12 of 58

### Client Sample ID: M0031-R2-TS4-C1-Tenax/M0031-R2-TS4-C2-Tenax Lab ID#: 1004525B-09AB MODIFIED VOST 5041A/8260B

4043014 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 03:16 PM

Limits %Recovery Surrogates Method

78 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 85 70-130 4-Bromofluorobenzene

Page 13 of 58

### Client Sample ID: M0031-R2-TS4-C4-Anasorb Lab ID#: 1004525B-09C MODIFIED VOST 5041A/8260B

4043018 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 05:20 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1500 Chloromethane 10 Not Detected Vinyl Chloride 10 67 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 70 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 14 of 58

### Client Sample ID: M0031-R2-TS4-C4-Anasorb Lab ID#: 1004525B-09C MODIFIED VOST 5041A/8260B

4043018 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 05:20 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 23 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 15 of 58

### Client Sample ID: M0031-R2-TS4-C4-Anasorb Lab ID#: 1004525B-09C MODIFIED VOST 5041A/8260B

4043018 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 05:20 PM

Limits %Recovery Surrogates Method

8.8 Q 50-150 Dibromofluoromethane 6.4 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 16 of 58

### Client Sample ID: M0031-R2-TS4-C3-Condensate Lab ID#: 1004525B-10A MODIFIED VOST 5041A/8260B

4043011 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 01:48 PM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 710 Acetone 400 Not Detected 3-Chloropropene 80 24000 E Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 Not Detected 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 110 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 17 of 58

### Client Sample ID: M0031-R2-TS4-C3-Condensate Lab ID#: 1004525B-10A MODIFIED VOST 5041A/8260B

4043011 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 01:48 PM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
E = Exceeds instrument calibration range. Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

Page 18 of 58

### Client Sample ID: M0031-R2-TS4-C3-Condensate Lab ID#: 1004525B-10A MODIFIED VOST 5041A/8260B

4043011 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 01:48 PM

Limits %Recovery Surrogates Method

95 70-130 Dibromofluoromethane 98 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 98 70-130 4-Bromofluorobenzene

Page 19 of 58

### Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax Lab ID#: 1004525B-11AB MODIFIED VOST 5041A/8260B

4043016 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 04:11 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 27 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 17 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 20 of 58

### Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax Lab ID#: 1004525B-11AB MODIFIED VOST 5041A/8260B

4043016 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 04:11 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

86 70-130 Dibromofluoromethane

Page 21 of 58

### Client Sample ID: M0031-R3-TS1-C1-Tenax/M0031-R3-TS1-C2-Tenax Lab ID#: 1004525B-11AB MODIFIED VOST 5041A/8260B

4043016 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 04:11 PM

Limits %Recovery Surrogates Method

83 70-130 1,2-Dichloroethane-d4 118 70-130 Toluene-d8 93 70-130 4-Bromofluorobenzene

Page 22 of 58

### Client Sample ID: M0031-R3-TS1-C3-Anasorb Lab ID#: 1004525B-11C MODIFIED VOST 5041A/8260B

4043019 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 06:05 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1500 Chloromethane 10 Not Detected Vinyl Chloride 10 64 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 20 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 23 of 58

### Client Sample ID: M0031-R3-TS1-C3-Anasorb Lab ID#: 1004525B-11C MODIFIED VOST 5041A/8260B

4043019 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 06:05 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 27 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 24 of 58

### Client Sample ID: M0031-R3-TS1-C3-Anasorb Lab ID#: 1004525B-11C MODIFIED VOST 5041A/8260B

4043019 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 06:05 PM

Limits %Recovery Surrogates Method

28 Q 50-150 Dibromofluoromethane 18 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 25 of 58

### Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax Lab ID#: 1004525B-12AB MODIFIED VOST 5041A/8260B

4050310 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 02:56 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 31 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 13 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 26 of 58

### Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax Lab ID#: 1004525B-12AB MODIFIED VOST 5041A/8260B

4050310 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 02:56 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

92 70-130 Dibromofluoromethane

Page 27 of 58

### Client Sample ID: M0031-R3-TS2-C1-Tenax/M0031-R3-TS2-C2-Tenax Lab ID#: 1004525B-12AB MODIFIED VOST 5041A/8260B

4050310 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 02:56 PM

Limits %Recovery Surrogates Method

90 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 96 70-130 4-Bromofluorobenzene

Page 28 of 58

### Client Sample ID: M0031-R3-TS2-C4-Anasorb Lab ID#: 1004525B-12C MODIFIED VOST 5041A/8260B

4050315 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:32 PM

(ng) (ng) Compound Amount Rpt. Limit

50 2800 E Chloromethane 10 Not Detected Vinyl Chloride 10 100 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 68 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 29 of 58

### Client Sample ID: M0031-R3-TS2-C4-Anasorb Lab ID#: 1004525B-12C MODIFIED VOST 5041A/8260B

4050315 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:32 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 27 Freon 12
E = Exceeds instrument calibration range. Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 30 of 58

### Client Sample ID: M0031-R3-TS2-C4-Anasorb Lab ID#: 1004525B-12C MODIFIED VOST 5041A/8260B

4050315 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:32 PM

Limits %Recovery Surrogates Method

17 Q 50-150 Dibromofluoromethane 11 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 31 of 58

### Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax Lab ID#: 1004525B-13AB MODIFIED VOST 5041A/8260B

4050311 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 03:39 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 68 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 15 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 32 of 58

### Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax Lab ID#: 1004525B-13AB MODIFIED VOST 5041A/8260B

4050311 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 03:39 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

90 70-130 Dibromofluoromethane

Page 33 of 58

### Client Sample ID: M0031-R3-TS3-C1-Tenax/M0031-R3-TS3-C2-Tenax Lab ID#: 1004525B-13AB MODIFIED VOST 5041A/8260B

4050311 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 03:39 PM

Limits %Recovery Surrogates Method

87 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 91 70-130 4-Bromofluorobenzene

Page 34 of 58

### Client Sample ID: M0031-R3-TS3-C4-Anasorb Lab ID#: 1004525B-13C MODIFIED VOST 5041A/8260B

4050316 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:59 PM

(ng) (ng) Compound Amount Rpt. Limit

50 5400 E Chloromethane 10 Not Detected Vinyl Chloride 10 99 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 36 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 35 of 58

### Client Sample ID: M0031-R3-TS3-C4-Anasorb Lab ID#: 1004525B-13C MODIFIED VOST 5041A/8260B

4050316 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:59 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 29 Freon 12
E = Exceeds instrument calibration range. Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 36 of 58

### Client Sample ID: M0031-R3-TS3-C4-Anasorb Lab ID#: 1004525B-13C MODIFIED VOST 5041A/8260B

4050316 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:59 PM

Limits %Recovery Surrogates Method

28 Q 50-150 Dibromofluoromethane 16 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 37 of 58

### Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax Lab ID#: 1004525B-14AB MODIFIED VOST 5041A/8260B

4050312 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 04:12 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 54 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 18 Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 38 of 58

### Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax Lab ID#: 1004525B-14AB MODIFIED VOST 5041A/8260B

4050312 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 04:12 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

93 70-130 Dibromofluoromethane

Page 39 of 58

### Client Sample ID: M0031-R3-TS4-C1-Tenax/M0031-R3-TS4-C2-Tenax Lab ID#: 1004525B-14AB MODIFIED VOST 5041A/8260B

4050312 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 04:12 PM

Limits %Recovery Surrogates Method

93 70-130 1,2-Dichloroethane-d4 119 70-130 Toluene-d8 96 70-130 4-Bromofluorobenzene

Page 40 of 58

### Client Sample ID: M0031-R3-TS4-C4-Anasorb Lab ID#: 1004525B-14C MODIFIED VOST 5041A/8260B

4050317 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 06:27 PM

(ng) (ng) Compound Amount Rpt. Limit

50 1800 Chloromethane 10 Not Detected Vinyl Chloride 10 60 Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 44 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 41 of 58

### Client Sample ID: M0031-R3-TS4-C4-Anasorb Lab ID#: 1004525B-14C MODIFIED VOST 5041A/8260B

4050317 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 06:27 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 31 Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 42 of 58

### Client Sample ID: M0031-R3-TS4-C4-Anasorb Lab ID#: 1004525B-14C MODIFIED VOST 5041A/8260B

4050317 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 06:27 PM

Limits %Recovery Surrogates Method

26 Q 50-150 Dibromofluoromethane 18 Q 50-150 1,2-Dichloroethane-d4 5.2 Q 50-150 Toluene-d8

Page 43 of 58

### Client Sample ID: M0031-R3-TS4-C3-Condensate Lab ID#: 1004525B-15A MODIFIED VOST 5041A/8260B

4043012 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 02:14 PM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 650 Acetone 400 Not Detected 3-Chloropropene 80 23000 E Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 Not Detected 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 85 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 44 of 58

### Client Sample ID: M0031-R3-TS4-C3-Condensate Lab ID#: 1004525B-15A MODIFIED VOST 5041A/8260B

4043012 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 02:14 PM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
E = Exceeds instrument calibration range. Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

Page 45 of 58

### Client Sample ID: M0031-R3-TS4-C3-Condensate Lab ID#: 1004525B-15A MODIFIED VOST 5041A/8260B

4043012 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 4/30/10 02:14 PM

Limits %Recovery Surrogates Method

94 70-130 Dibromofluoromethane 93 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 96 70-130 4-Bromofluorobenzene

Page 46 of 58

### Client Sample ID: Lab Blank Lab ID#: 1004525B-16A MODIFIED VOST 5041A/8260B

4043006 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:53 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 47 of 58

### Client Sample ID: Lab Blank Lab ID#: 1004525B-16A MODIFIED VOST 5041A/8260B

4043006 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:53 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

92 70-130 Dibromofluoromethane

Page 48 of 58

### Client Sample ID: Lab Blank Lab ID#: 1004525B-16A MODIFIED VOST 5041A/8260B

4043006 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:53 AM

Limits %Recovery Surrogates Method

93 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 97 70-130 4-Bromofluorobenzene

Page 49 of 58

### Client Sample ID: Lab Blank Lab ID#: 1004525B-16B MODIFIED VOST 5041A/8260B

4050305 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:48 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 50 of 58

### Client Sample ID: Lab Blank Lab ID#: 1004525B-16B MODIFIED VOST 5041A/8260B

4050305 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:48 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

95 70-130 Dibromofluoromethane

Page 51 of 58

### Client Sample ID: Lab Blank Lab ID#: 1004525B-16B MODIFIED VOST 5041A/8260B

4050305 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:48 AM

Limits %Recovery Surrogates Method

95 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 99 70-130 4-Bromofluorobenzene

Page 52 of 58

### Client Sample ID: LCS Lab ID#: 1004525B-17A MODIFIED VOST 5041A/8260B

4043005 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:28 AM

%Recovery Compound
126 Chloromethane 105 Vinyl Chloride 96 Bromomethane 82 Chloroethane 133 Q Freon 11 144 Q 2-Chloropropane 118 1,1-Dichloroethene 135 Q Freon 113 134 Q Carbon Disulfide 88 Acetone 133 Q 3-Chloropropene 100 Methylene Chloride 102 trans-1,2-Dichloroethene 90 Acrylonitrile 127 Hexane 109 1,1-Dichloroethane Not Spiked Vinyl Acetate 100 2,2-Dichloropropane 99 cis-1,2-Dichloroethene 87 2-Butanone (Methyl Ethyl Ketone) 97 Bromochloromethane 107 Chloroform 105 1,1,1-Trichloroethane 100 Carbon Tetrachloride 112 1,1-Dichloropropene 107 Benzene 98 1,2-Dichloroethane 101 Trichloroethene 104 1,2-Dichloropropane 96 Dibromomethane 91 Bromodichloromethane 96 cis-1,3-Dichloropropene 99 trans-1,3-Dichloropropene 88 4-Methyl-2-pentanone 111 Toluene 93 1,1,2-Trichloroethane 108 Tetrachloroethene 95 1,3-Dichloropropane 93 2-Hexanone

Page 53 of 58

### Client Sample ID: LCS Lab ID#: 1004525B-17A MODIFIED VOST 5041A/8260B

4043005 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:28 AM

%Recovery Compound
84 Dibromochloromethane 109 Chlorobenzene 88 1,2-Dibromoethane (EDB) 111 Ethyl Benzene 114 m,p-Xylene 109 o-Xylene 108 Styrene 72 Bromoform 90 1,1,2,2-Tetrachloroethane 112 1,3-Dichlorobenzene 110 1,4-Dichlorobenzene 106 1,2-Dichlorobenzene 122 Cumene 78 cis-1,4-Dichloro-2-butene 108 Bromobenzene 90 1,2,3-Trichloropropane 88 trans-1,4-Dichloro-2-butene 108 Propylbenzene 110 2-Chlorotoluene 114 4-Chlorotoluene 112 1,3,5-Trimethylbenzene 108 tert-Butylbenzene 109 1,2,4-Trimethylbenzene 113 sec-Butylbenzene 114 p-Cymene 62 Q 1,2-Dibromo-3-chloropropane 97 1,2,4-Trichlorobenzene 78 Naphthalene 102 Hexachlorobutadiene 87 1,2,3-Trichlorobenzene 100 1,1,1,2-Tetrachloroethane 113 Butylbenzene 86 Iodomethane 98 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 54 of 58

### Client Sample ID: LCS Lab ID#: 1004525B-17A MODIFIED VOST 5041A/8260B

4043005 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 4/30/10 10:28 AM

Limits %Recovery Surrogates Method

96 70-130 Dibromofluoromethane 95 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 100 70-130 4-Bromofluorobenzene

Page 55 of 58

### Client Sample ID: LCS Lab ID#: 1004525B-17B MODIFIED VOST 5041A/8260B

4050304 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:04 AM

%Recovery Compound
138 Chloromethane 108 Vinyl Chloride 105 Bromomethane 88 Chloroethane 143 Q Freon 11 149 Q 2-Chloropropane 119 1,1-Dichloroethene 146 Q Freon 113 138 Q Carbon Disulfide 98 Acetone 138 Q 3-Chloropropene 99 Methylene Chloride 104 trans-1,2-Dichloroethene 95 Acrylonitrile 138 Q Hexane 112 1,1-Dichloroethane Not Spiked Vinyl Acetate 100 2,2-Dichloropropane 100 cis-1,2-Dichloroethene 75 2-Butanone (Methyl Ethyl Ketone) 98 Bromochloromethane 109 Chloroform 106 1,1,1-Trichloroethane 103 Carbon Tetrachloride 111 1,1-Dichloropropene 111 Benzene 101 1,2-Dichloroethane 104 Trichloroethene 110 1,2-Dichloropropane 96 Dibromomethane 95 Bromodichloromethane 96 cis-1,3-Dichloropropene 98 trans-1,3-Dichloropropene 85 4-Methyl-2-pentanone 111 Toluene 94 1,1,2-Trichloroethane 110 Tetrachloroethene 96 1,3-Dichloropropane 87 2-Hexanone

Page 56 of 58

### Client Sample ID: LCS Lab ID#: 1004525B-17B MODIFIED VOST 5041A/8260B

4050304 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:04 AM

%Recovery Compound
85 Dibromochloromethane 108 Chlorobenzene 90 1,2-Dibromoethane (EDB) 111 Ethyl Benzene 114 m,p-Xylene 107 o-Xylene 107 Styrene 76 Bromoform 91 1,1,2,2-Tetrachloroethane 111 1,3-Dichlorobenzene 109 1,4-Dichlorobenzene 103 1,2-Dichlorobenzene 125 Cumene 84 cis-1,4-Dichloro-2-butene 105 Bromobenzene 89 1,2,3-Trichloropropane 88 trans-1,4-Dichloro-2-butene 106 Propylbenzene 106 2-Chlorotoluene 111 4-Chlorotoluene 108 1,3,5-Trimethylbenzene 107 tert-Butylbenzene 105 1,2,4-Trimethylbenzene 111 sec-Butylbenzene 114 p-Cymene 65 Q 1,2-Dibromo-3-chloropropane 98 1,2,4-Trichlorobenzene 77 Naphthalene 103 Hexachlorobutadiene 90 1,2,3-Trichlorobenzene 102 1,1,1,2-Tetrachloroethane 115 Butylbenzene 73 Iodomethane 110 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 57 of 58

### Client Sample ID: LCS Lab ID#: 1004525B-17B MODIFIED VOST 5041A/8260B

4050304 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:04 AM

Limits %Recovery Surrogates Method

100 70-130 Dibromofluoromethane 98 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 95 70-130 4-Bromofluorobenzene

Page 58 of 58

### 5/7/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood MO 63042

Project Name: KCP&L ICR Testing Project #:

Dear Mr. Frank Stevens
The following report includes the data for the above referenced project for sample(s) received on 4/24/2010 at Air Toxics Ltd. The data and associated QC analyzed by Modified VOST 5041A/8260B are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding the data in this report.

Regards,

Ausha Scott Project Manager Workorder #: 1004525C

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020 Hours 6:30 A.M to 5:30 PST

Page 1 of 26

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 

## WORK ORDER #: 1004525C

CLIENT: BILL TO:

PHONE: 

### Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042
314-686-4565 314-656-4595 04/24/2010 DATE COMPLETED: 

### 05/06/2010 P.O. # 

### 100-208-0001
PROJECT # 

### KCP&L ICR Testing 

### Work Order Summary

FAX: DATE RECEIVED: CONTACT: 

### Ausha Scott

NAME FRACTION # TEST 

### 16AB M0031-BT-TS1-C1-Tenax/M0031-BT-TS1 Modified VOST 5041A/8260 16C M0031-BT-TS1-C4-Anasorb Modified VOST 5041A/8260 17A M0031-BT-TS1-C3-Condensate Modified VOST 5041A/8260 18AB M0031-Trip Blank-TS1-C1-Tenax/M0031-T Modified VOST 5041A/8260 18C M0031-Trip Blank-TS1-C4-Anasorb Modified VOST 5041A/8260 19A Lab Blank Modified VOST 5041A/8260 20A LCS Modified VOST 5041A/8260

CERTIFIED BY: Laboratory Director DATE:



### Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act,

Accreditation number: E87680, Effective date: 07/01/09, Expiration date: 06/30/10

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020 

### 05/07/10

Page 2 of 26 This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd. 

### Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure AZ0719

## LABORATORY NARRATIVE VOST 5041A Civil & Environmental Consultants, Inc. Workorder# 1004525C Laboratory Services Since 1989



## Six VOST 0031 Tube and one VOA Vial-40 mL samples were received on April 24, 2010. The laboratory performed the analysis via EPA SW-846 Method 5041A using GC/MS in the full scan mode. VOST sorbent tubes are thermally desorbed at 180 degrees centrigrade for ten minutes by UHP helium carrier gas. The gas stream is then bubbled through 5 mL of organic free water and trapped on the sorbent trap of the purge and trap system. The trap is thermally desorbed to elute the components into the GC/MS system for further separation. See the data sheets for the reporting limits for each compound.
Requirement ATL Modifications VOST 5041A 

### Batch Certification Blanks from the same media as samples Analysis of set of cartridges prior to onset of any project; Sampling media provided by the client is batch certified ahead of time, only if client provides blank cartridges.
Method blank Cartridges from the same media batches as the samples Media batch is certified prior to use in the field. Method Blank is used to certify instrument is contaminant free

Connection between cartridge thermal desorption apparatus & sample purge vessel PTFE 1/16" Teflon tubing Heated, 1/16" silica lined stainless steel tubing

Calibration Criteria for non-CCCs RSD +- 15 % for all non-CCCs RSD </= 30 % for some compounds: Acetone, Bromoform, Vinyl Acetate, Bromomethane, Chloromethane, 1,1,2,2-Tetracholoroethane, & 1,2,3-Trichloropropane



## Receiving Notes There were no receiving discrepancies.

Per client request, compounds that are not validated under Method 0031 collection protocols were reported in this work order. These compounds may not be suitable for collection by Method 0031 due to elevated boiling point (> 121 degrees C.), polar water solubility or reactivity. The laboratory analytical method 5041A/8260B is validated for all target analytes.
Compounds other than those listed in method 0031 section 1.1, may exhibit poor recovery from the Anasorb. In addition the laboratory method has not been validated for recovery of these additional compounds from Anasorb and the values are semi-quantitative in nature and reported as estimated.

Each tube was spiked with Dibromofluoromethane, 1,2-Dichloroethane-d4, Toluene-d8 and 4-Bromofluorobenzene prior to shipment to the field as an additional QC step.

The recoveries of surrogates Dibromofluoromethane, 1,2-Dichloroethane-d4, and Toluene-d8 in samples M0031-BT-TS1-C4-Anasorb and M0031-Trip Blank-TS1-C4-Anasorb was outside control limits. It is not possible to re-run to confirm matrix or dilute for matrix using sorbent tube media. Data Analytical Notes

Page 3 of 26Laboratory Services Since 1989



## is reported as qualified.

All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target compound non-detects in the samples that are associated with high bias in QC analyses have not been flagged.

Seven qualifiers may have been used on the data analysis sheets and indicate as follows: B

- Compound present in laboratory blank or tube certification greater than reporting limit (background subtraction not performed). J

- Estimated value. E

- Exceeds instrument calibration range. S

- Saturated peak. Q

- Exceeds quality control limits. U

- Compound analyzed for but not detected above the detection limit. N

- The identification is based on presumptive evidence.

File extensions may have been used on the data analysis sheets and indicates

as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags

Page 4 of 26

# MODIFIED VOST 5041A/8260B Summary of Detected Compounds

Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax
Lab ID#: 1004525C-16AB
(ng) (ng) Compound Amount Rpt. Limit

10 170 Methylene Chloride



### Client Sample ID: M0031-BT-TS1-C4-Anasorb
Lab ID#: 1004525C-16C
(ng) (ng) Compound Amount Rpt. Limit

50 320 Chloromethane 10 48 Methylene Chloride



### Client Sample ID: M0031-BT-TS1-C3-Condensate
Lab ID#: 1004525C-17A
(ng) (ng) Compound Amount Rpt. Limit

400 620 Acetone 80 26000 E Methylene Chloride 80 98 Chloroform



### Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax
Lab ID#: 1004525C-18AB
(ng) (ng) Compound Amount Rpt. Limit

10 14 Methylene Chloride



### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb
Lab ID#: 1004525C-18C
(ng) (ng) Compound Amount Rpt. Limit

50 670 Chloromethane

Page 5 of 26

### Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax Lab ID#: 1004525C-16AB MODIFIED VOST 5041A/8260B

4050309 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 02:01 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 170 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 6 of 26

### Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax Lab ID#: 1004525C-16AB MODIFIED VOST 5041A/8260B

4050309 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 02:01 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

98 70-130 Dibromofluoromethane

Page 7 of 26

### Client Sample ID: M0031-BT-TS1-C1-Tenax/M0031-BT-TS1-C2-Tenax Lab ID#: 1004525C-16AB MODIFIED VOST 5041A/8260B

4050309 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 02:01 PM

Limits %Recovery Surrogates Method

89 70-130 1,2-Dichloroethane-d4 118 70-130 Toluene-d8 85 70-130 4-Bromofluorobenzene

Page 8 of 26

### Client Sample ID: M0031-BT-TS1-C4-Anasorb Lab ID#: 1004525C-16C MODIFIED VOST 5041A/8260B

4050314 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:04 PM

(ng) (ng) Compound Amount Rpt. Limit

50 320 Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 48 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 9 of 26

### Client Sample ID: M0031-BT-TS1-C4-Anasorb Lab ID#: 1004525C-16C MODIFIED VOST 5041A/8260B

4050314 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:04 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 10 of 26

### Client Sample ID: M0031-BT-TS1-C4-Anasorb Lab ID#: 1004525C-16C MODIFIED VOST 5041A/8260B

4050314 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 05:04 PM

Limits %Recovery Surrogates Method

12 Q 50-150 Dibromofluoromethane 24 Q 50-150 1,2-Dichloroethane-d4 7.6 Q 50-150 Toluene-d8

Page 11 of 26

### Client Sample ID: M0031-BT-TS1-C3-Condensate Lab ID#: 1004525C-17A MODIFIED VOST 5041A/8260B

4050306 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 12:13 PM

(ng) (ng) Compound Amount Rpt. Limit

400 Not Detected Chloromethane 80 Not Detected Vinyl Chloride 80 Not Detected Bromomethane 400 Not Detected Chloroethane 80 Not Detected Freon 11 400 Not Detected 2-Chloropropane 80 Not Detected 1,1-Dichloroethene 80 Not Detected Freon 113 80 Not Detected Carbon Disulfide 400 620 Acetone 400 Not Detected 3-Chloropropene 80 26000 E Methylene Chloride 80 Not Detected trans-1,2-Dichloroethene 400 Not Detected Acrylonitrile 80 Not Detected Hexane 80 Not Detected 1,1-Dichloroethane 400 Not Detected Vinyl Acetate 400 Not Detected 2,2-Dichloropropane 80 Not Detected cis-1,2-Dichloroethene 400 Not Detected 2-Butanone (Methyl Ethyl Ketone) 80 Not Detected Bromochloromethane 80 98 Chloroform 80 Not Detected 1,1,1-Trichloroethane 80 Not Detected Carbon Tetrachloride 80 Not Detected 1,1-Dichloropropene 80 Not Detected Benzene 80 Not Detected 1,2-Dichloroethane 80 Not Detected Trichloroethene 80 Not Detected 1,2-Dichloropropane 80 Not Detected Dibromomethane 80 Not Detected Bromodichloromethane 80 Not Detected cis-1,3-Dichloropropene 80 Not Detected trans-1,3-Dichloropropene 400 Not Detected 4-Methyl-2-pentanone 80 Not Detected Toluene 80 Not Detected 1,1,2-Trichloroethane 80 Not Detected Tetrachloroethene 80 Not Detected 1,3-Dichloropropane 400 Not Detected 2-Hexanone

Page 12 of 26

### Client Sample ID: M0031-BT-TS1-C3-Condensate Lab ID#: 1004525C-17A MODIFIED VOST 5041A/8260B

4050306 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 12:13 PM

(ng) (ng) Compound Amount Rpt. Limit

80 Not Detected Dibromochloromethane 80 Not Detected Chlorobenzene 80 Not Detected 1,2-Dibromoethane (EDB) 80 Not Detected Ethyl Benzene 80 Not Detected m,p-Xylene 80 Not Detected o-Xylene 80 Not Detected Styrene 80 Not Detected Bromoform 80 Not Detected 1,1,2,2-Tetrachloroethane 80 Not Detected 1,3-Dichlorobenzene 80 Not Detected 1,4-Dichlorobenzene 80 Not Detected 1,2-Dichlorobenzene 80 Not Detected Cumene 400 Not Detected cis-1,4-Dichloro-2-butene 80 Not Detected Bromobenzene 80 Not Detected 1,2,3-Trichloropropane 400 Not Detected trans-1,4-Dichloro-2-butene 80 Not Detected Propylbenzene 80 Not Detected 2-Chlorotoluene 80 Not Detected 4-Chlorotoluene 80 Not Detected 1,3,5-Trimethylbenzene 80 Not Detected tert-Butylbenzene 80 Not Detected 1,2,4-Trimethylbenzene 80 Not Detected sec-Butylbenzene 80 Not Detected p-Cymene 400 Not Detected 1,2-Dibromo-3-chloropropane 400 Not Detected 1,2,4-Trichlorobenzene 400 Not Detected Naphthalene 400 Not Detected Hexachlorobutadiene 400 Not Detected 1,2,3-Trichlorobenzene 80 Not Detected 1,1,1,2-Tetrachloroethane 80 Not Detected Butylbenzene 400 Not Detected Iodomethane 80 Not Detected Freon 12
E = Exceeds instrument calibration range. Container Type: VOA Vial-40 mL

Limits %Recovery Surrogates Method

Page 13 of 26

### Client Sample ID: M0031-BT-TS1-C3-Condensate Lab ID#: 1004525C-17A MODIFIED VOST 5041A/8260B

4050306 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 12:13 PM

Limits %Recovery Surrogates Method

93 70-130 Dibromofluoromethane 91 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 98 70-130 4-Bromofluorobenzene

Page 14 of 26

### Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax Lab ID#: 1004525C-18AB MODIFIED VOST 5041A/8260B

4050308 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 01:36 PM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 14 Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 15 of 26

### Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax Lab ID#: 1004525C-18AB MODIFIED VOST 5041A/8260B

4050308 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 01:36 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

94 70-130 Dibromofluoromethane

Page 16 of 26

### Client Sample ID: M0031-Trip Blank-TS1-C1-Tenax/M0031-Trip Blank-TS1-C2-Tenax Lab ID#: 1004525C-18AB MODIFIED VOST 5041A/8260B

4050308 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 01:36 PM

Limits %Recovery Surrogates Method

87 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 75 70-130 4-Bromofluorobenzene

Page 17 of 26

### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb Lab ID#: 1004525C-18C MODIFIED VOST 5041A/8260B

4050313 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 04:37 PM

(ng) (ng) Compound Amount Rpt. Limit

50 670 Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 18 of 26

### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb Lab ID#: 1004525C-18C MODIFIED VOST 5041A/8260B

4050313 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 04:37 PM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Q = Exceeds Quality Control limits. Container Type: VOST 0031 Tube

Limits %Recovery Surrogates Method

Page 19 of 26

### Client Sample ID: M0031-Trip Blank-TS1-C4-Anasorb Lab ID#: 1004525C-18C MODIFIED VOST 5041A/8260B

4050313 File Name: Dil. Factor: 1.00 Date of Collection: 4/22/10 Date of Analysis: 5/3/10 04:37 PM

Limits %Recovery Surrogates Method

10 Q 50-150 Dibromofluoromethane 9.8 Q 50-150 1,2-Dichloroethane-d4 0 U Q 50-150 Toluene-d8

Page 20 of 26

### Client Sample ID: Lab Blank Lab ID#: 1004525C-19A MODIFIED VOST 5041A/8260B

4050305 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:48 AM

(ng) (ng) Compound Amount Rpt. Limit

50 Not Detected Chloromethane 10 Not Detected Vinyl Chloride 10 Not Detected Bromomethane 50 Not Detected Chloroethane 10 Not Detected Freon 11 50 Not Detected 2-Chloropropane 10 Not Detected 1,1-Dichloroethene 10 Not Detected Freon 113 10 Not Detected Carbon Disulfide 50 Not Detected Acetone 50 Not Detected 3-Chloropropene 10 Not Detected Methylene Chloride 10 Not Detected trans-1,2-Dichloroethene 50 Not Detected Acrylonitrile 10 Not Detected Hexane 10 Not Detected 1,1-Dichloroethane 50 Not Detected Vinyl Acetate 50 Not Detected 2,2-Dichloropropane 10 Not Detected cis-1,2-Dichloroethene 50 Not Detected 2-Butanone (Methyl Ethyl Ketone) 10 Not Detected Bromochloromethane 10 Not Detected Chloroform 10 Not Detected 1,1,1-Trichloroethane 10 Not Detected Carbon Tetrachloride 10 Not Detected 1,1-Dichloropropene 10 Not Detected Benzene 10 Not Detected 1,2-Dichloroethane 10 Not Detected Trichloroethene 10 Not Detected 1,2-Dichloropropane 10 Not Detected Dibromomethane 10 Not Detected Bromodichloromethane 10 Not Detected cis-1,3-Dichloropropene 10 Not Detected trans-1,3-Dichloropropene 50 Not Detected 4-Methyl-2-pentanone 10 Not Detected Toluene 10 Not Detected 1,1,2-Trichloroethane 10 Not Detected Tetrachloroethene 10 Not Detected 1,3-Dichloropropane 50 Not Detected 2-Hexanone

Page 21 of 26

### Client Sample ID: Lab Blank Lab ID#: 1004525C-19A MODIFIED VOST 5041A/8260B

4050305 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:48 AM

(ng) (ng) Compound Amount Rpt. Limit

10 Not Detected Dibromochloromethane 10 Not Detected Chlorobenzene 10 Not Detected 1,2-Dibromoethane (EDB) 10 Not Detected Ethyl Benzene 10 Not Detected m,p-Xylene 10 Not Detected o-Xylene 10 Not Detected Styrene 10 Not Detected Bromoform 10 Not Detected 1,1,2,2-Tetrachloroethane 10 Not Detected 1,3-Dichlorobenzene 10 Not Detected 1,4-Dichlorobenzene 10 Not Detected 1,2-Dichlorobenzene 10 Not Detected Cumene 50 Not Detected cis-1,4-Dichloro-2-butene 10 Not Detected Bromobenzene 10 Not Detected 1,2,3-Trichloropropane 50 Not Detected trans-1,4-Dichloro-2-butene 10 Not Detected Propylbenzene 10 Not Detected 2-Chlorotoluene 10 Not Detected 4-Chlorotoluene 10 Not Detected 1,3,5-Trimethylbenzene 10 Not Detected tert-Butylbenzene 10 Not Detected 1,2,4-Trimethylbenzene 10 Not Detected sec-Butylbenzene 10 Not Detected p-Cymene 50 Not Detected 1,2-Dibromo-3-chloropropane 50 Not Detected 1,2,4-Trichlorobenzene 50 Not Detected Naphthalene 50 Not Detected Hexachlorobutadiene 50 Not Detected 1,2,3-Trichlorobenzene 10 Not Detected 1,1,1,2-Tetrachloroethane 10 Not Detected Butylbenzene 50 Not Detected Iodomethane 10 Not Detected Freon 12
Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

95 70-130 Dibromofluoromethane

Page 22 of 26

### Client Sample ID: Lab Blank Lab ID#: 1004525C-19A MODIFIED VOST 5041A/8260B

4050305 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:48 AM

Limits %Recovery Surrogates Method

95 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 99 70-130 4-Bromofluorobenzene

Page 23 of 26

### Client Sample ID: LCS Lab ID#: 1004525C-20A MODIFIED VOST 5041A/8260B

4050304 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:04 AM

%Recovery Compound
138 Chloromethane 108 Vinyl Chloride 105 Bromomethane 88 Chloroethane 143 Q Freon 11 149 Q 2-Chloropropane 119 1,1-Dichloroethene 146 Q Freon 113 138 Q Carbon Disulfide 98 Acetone 138 Q 3-Chloropropene 99 Methylene Chloride 104 trans-1,2-Dichloroethene 95 Acrylonitrile 138 Q Hexane 112 1,1-Dichloroethane Not Spiked Vinyl Acetate 100 2,2-Dichloropropane 100 cis-1,2-Dichloroethene 75 2-Butanone (Methyl Ethyl Ketone) 98 Bromochloromethane 109 Chloroform 106 1,1,1-Trichloroethane 103 Carbon Tetrachloride 111 1,1-Dichloropropene 111 Benzene 101 1,2-Dichloroethane 104 Trichloroethene 110 1,2-Dichloropropane 96 Dibromomethane 95 Bromodichloromethane 96 cis-1,3-Dichloropropene 98 trans-1,3-Dichloropropene 85 4-Methyl-2-pentanone 111 Toluene 94 1,1,2-Trichloroethane 110 Tetrachloroethene 96 1,3-Dichloropropane 87 2-Hexanone

Page 24 of 26

### Client Sample ID: LCS Lab ID#: 1004525C-20A MODIFIED VOST 5041A/8260B

4050304 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:04 AM

%Recovery Compound
85 Dibromochloromethane 108 Chlorobenzene 90 1,2-Dibromoethane (EDB) 111 Ethyl Benzene 114 m,p-Xylene 107 o-Xylene 107 Styrene 76 Bromoform 91 1,1,2,2-Tetrachloroethane 111 1,3-Dichlorobenzene 109 1,4-Dichlorobenzene 103 1,2-Dichlorobenzene 125 Cumene 84 cis-1,4-Dichloro-2-butene 105 Bromobenzene 89 1,2,3-Trichloropropane 88 trans-1,4-Dichloro-2-butene 106 Propylbenzene 106 2-Chlorotoluene 111 4-Chlorotoluene 108 1,3,5-Trimethylbenzene 107 tert-Butylbenzene 105 1,2,4-Trimethylbenzene 111 sec-Butylbenzene 114 p-Cymene 65 Q 1,2-Dibromo-3-chloropropane 98 1,2,4-Trichlorobenzene 77 Naphthalene 103 Hexachlorobutadiene 90 1,2,3-Trichlorobenzene 102 1,1,1,2-Tetrachloroethane 115 Butylbenzene 73 Iodomethane 110 Freon 12
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable

Limits %Recovery Surrogates Method

Page 25 of 26

### Client Sample ID: LCS Lab ID#: 1004525C-20A MODIFIED VOST 5041A/8260B

4050304 File Name: Dil. Factor: 1.00 Date of Collection: NA Date of Analysis: 5/3/10 11:04 AM

Limits %Recovery Surrogates Method

100 70-130 Dibromofluoromethane 98 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 95 70-130 4-Bromofluorobenzene

Page 26 of 26

# Air Toxics Ltd. Sample Receipt Confirmation Cover Page

Thank you for choosing Air Toxics Ltd. We have received your samples and have listed any Sample Receipt Descrepancies below. In order to expedite analysis and reporting, please review the attached information for accuracy. For corrections call: ATL will proceed with the analysis as specified on the Chain of Custody and Sample Receipt Summary page. Ausha Scott at 916-985-1000

The following discrepancy has been observed:
We have found a discrepancy between the Chain of Custody (COC) and the sample tags. The samples labeled M0031-R1-TS3-C4-Anasorb and M0031-R1-TS4-C4-Anasorb on the COC are labeled as M0031-R1-TS3-C3-Condensate and M0031-R1-TS4-C3-Condensate on the sample tags. ATL will report the sample identifications on the COC unless otherwise notified. Please note : The Sample Receipt Confirmation, including the total workorder charge, is subject to change upon secondary review. Our aim is to provide a confirmation to you in a timely manner. Sample Receipt Discrepancies, if any, may not include discrepancies regarding sample receipt pressure(s). Additionally, the Chain of Custody (COC) will be provided with the final report.

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020 Hours 6:30 A.M to 5:30 P.M. PST

# SAMPLE RECEIPT SUMMARY
WORKORDER 1004525A

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 Client Phone
314-686-4565
Fax
314-656-4595 Date Completed:
Date Received: 

### 4/24/10

PO#: Project#:

Total $: Logged By: 

### 100-208-0001

$ 5,000.00 KCP&L ICR Testing

MW Sales Rep: TL Date Promised: 

### 05/10/10

Analysis Fraction Sample # Collected Amount$
01A M0031-R1-TS1-C1-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 02A M0031-R1-TS1-C2-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 03A M0031-R1-TS1-C3-Condensate Modified VOST 5041A/8260B $250.00 4/21/2010 04A M0031-R1-TS1-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/21/2010 05A M0031-R1-TS2-C1-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 06A M0031-R1-TS2-C2-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 07A M0031-R1-TS2-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/21/2010 08A M0031-R1-TS3-C1-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 09A M0031-R1-TS3-C2-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 10A M0031-R1-TS3-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/21/2010 11A M0031-R1-TS4-C1-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 12A M0031-R1-TS4-C2-Tenax Modified VOST 5041A/8260B $250.00 4/21/2010 13A M0031-R1-TS4-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/21/2010 14A M0031-R2-TS1-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 15A M0031-R2-TS1-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 16A M0031-R2-TS1-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 17A M0031-R2-TS2-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 18A M0031-R2-TS2-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 19A M0031-R2-TS2-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 BILL TO:

Reporting Method: Modified VOST 5041A/8260B (Full list) Analysis Code: Other MS Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1

# Continued

SAMPLE RECEIPT SUMMARY

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 Client Phone
314-686-4565
Fax
314-656-4595 Date Completed:
Date Received: 

### 4/24/10

PO#: Project#:

Total $: Logged By: 

### 100-208-0001

$ 5,000.00 KCP&L ICR Testing

MW Sales Rep: TL Date Promised: 

### 05/10/10

Analysis Fraction Sample # Collected Amount$
20A M0031-R2-TS3-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 BILL TO:

Reporting Method: Modified VOST 5041A/8260B (Full list) Analysis Code: Other MS Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 2

# SAMPLE RECEIPT SUMMARY
WORKORDER 1004525B

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 Client Phone
314-686-4565
Fax
314-656-4595 Date Completed:
Date Received: 

### 4/24/10

PO#: Project#:

Total $: Logged By: 

### 100-208-0001

$ 4,750.00 KCP&L ICR Testing

MW Sales Rep: TL Date Promised: 

### 05/10/10

Analysis Fraction Sample # Collected Amount$
21A M0031-R2-TS3-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 22A M0031-R2-TS3-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 23A M0031-R2-TS4-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 24A M0031-R2-TS4-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 25A M0031-R2-TS4-C3-Condensate Modified VOST 5041A/8260B $250.00 4/22/2010 26A M0031-R2-TS4-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 27A M0031-R3-TS1-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 28A M0031-R3-TS1-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 29A M0031-R3-TS1-C3-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 30A M0031-R3-TS2-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 31A M0031-R3-TS2-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 32A M0031-R3-TS2-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 33A M0031-R3-TS3-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 34A M0031-R3-TS3-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 35A M0031-R3-TS3-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 36A M0031-R3-TS4-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 37A M0031-R3-TS4-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 38A M0031-R3-TS4-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 39A M0031-R3-TS4-C3-Condensate Modified VOST 5041A/8260B $250.00 4/22/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 BILL TO:

Reporting Method: Modified VOST 5041A/8260B (Full list) Analysis Code: Other MS Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1

# SAMPLE RECEIPT SUMMARY
WORKORDER 1004525C

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 Client Phone
314-686-4565
Fax
314-656-4595 Date Completed:
Date Received: 

### 4/24/10

PO#: Project#:

Total $: Logged By: 

### 100-208-0001

$ 1,750.00 KCP&L ICR Testing

MW Sales Rep: TL Date Promised: 

### 05/10/10

Analysis Fraction Sample # Collected Amount$
40A M0031-BT-TS1-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 41A M0031-BT-TS1-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 42A M0031-BT-TS1-C3-Condensate Modified VOST 5041A/8260B $250.00 4/22/2010 43A M0031-BT-TS1-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010 44A M0031-Trip Blank-TS1-C1-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 45A M0031-Trip Blank-TS1-C2-Tenax Modified VOST 5041A/8260B $250.00 4/22/2010 46A M0031-Trip Blank-TS1-C4-Anasorb Modified VOST 5041A/8260B $250.00 4/22/2010

Mr. Frank Stevens Civil & Environmental Consultants, Inc. 4848 Park 370 Blvd., Suite F Hazelwood, MO 63042 BILL TO:

Reporting Method: Modified VOST 5041A/8260B (Full list) Analysis Code: Other MS Note: Samples received after 3 P.M. PST are considered to be received on the following work day.

Atlas Project Name/Profile#: ICR Testing/14203

TERMS: NET 60

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1

### Method : Modified VOST 5041A/8260B (Full list)

Compound Rpt. Limit (ng) CAS Number

Compound CAS Number
10 74-87-3 Chloromethane 10 75-01-4 Vinyl Chloride 10 74-83-9 Bromomethane 10 75-00-3 Chloroethane 10 Freon 11 75-69-4 50 75-29-6 2-Chloropropane 10 75-35-4 1,1-Dichloroethene 10 76-13-1 Freon 113 10 75-15-0 Carbon Disulfide 50 Acetone 67-64-1 50 107-05-1 3-Chloropropene 10 75-09-2 Methylene Chloride 10 156-60-5 trans-1,2-Dichloroethene 50 107-13-1 Acrylonitrile 10 Hexane 110-54-3 10 75-34-3 1,1-Dichloroethane 50 108-05-4 Vinyl Acetate 50 594-20-7 2,2-Dichloropropane 10 156-59-2 cis-1,2-Dichloroethene 50 2-Butanone (Methyl Ethyl Ketone) 78-93-3 10 74-97-5 Bromochloromethane 10 67-66-3 Chloroform 10 71-55-6 1,1,1-Trichloroethane 10 56-23-5 Carbon Tetrachloride 10 1,1-Dichloropropene 563-58-6 10 71-43-2 Benzene 10 107-06-2 1,2-Dichloroethane 10 79-01-6 Trichloroethene 10 78-87-5 1,2-Dichloropropane 10 Dibromomethane 74-95-3 10 75-27-4 Bromodichloromethane 10 10061-01-5 cis-1,3-Dichloropropene 10 10061-02-6 trans-1,3-Dichloropropene 50 108-10-1 4-Methyl-2-pentanone 10 Toluene 108-88-3 10 79-00-5 1,1,2-Trichloroethane 10 127-18-4 Tetrachloroethene 10 142-28-9 1,3-Dichloropropane

Page 1

### Method : Modified VOST 5041A/8260B (Full list)

Compound Rpt. Limit (ng) CAS Number 50 591-78-6 2-Hexanone 10 124-48-1 Dibromochloromethane 10 108-90-7 Chlorobenzene 10 106-93-4 1,2-Dibromoethane (EDB) 10 Ethyl Benzene 100-41-4 10 108-38-3 m,p-Xylene 10 95-47-6 o-Xylene 10 100-42-5 Styrene 10 75-25-2 Bromoform 10 1,1,2,2-Tetrachloroethane 79-34-5 10 541-73-1 1,3-Dichlorobenzene 10 106-46-7 1,4-Dichlorobenzene 10 95-50-1 1,2-Dichlorobenzene 10 98-82-8 Cumene 50 cis-1,4-Dichloro-2-butene 1476-11-5 10 108-86-1 Bromobenzene 10 96-18-4 1,2,3-Trichloropropane 50 110-57-6 trans-1,4-Dichloro-2-butene 10 103-65-1 Propylbenzene 10 2-Chlorotoluene 95-49-8 10 106-43-4 4-Chlorotoluene 10 108-67-8 1,3,5-Trimethylbenzene 10 98-06-6 tert-Butylbenzene 10 95-63-6 1,2,4-Trimethylbenzene 10 sec-Butylbenzene 135-98-8 10 99-87-6 p-Cymene 50 96-12-8 1,2-Dibromo-3-chloropropane 50 120-82-1 1,2,4-Trichlorobenzene 50 91-20-3 Naphthalene 50 Hexachlorobutadiene 87-68-3 50 87-61-6 1,2,3-Trichlorobenzene 10 630-20-6 1,1,1,2-Tetrachloroethane 10 104-51-8 Butylbenzene 50 74-88-4 Iodomethane 10 Freon 12 75-71-8

Surrogate Method Limits CAS Number 70-130 1868-53-7 Dibromofluoromethane 70-130 17060-07-0 1,2-Dichloroethane-d4

Page 2

### Method : Modified VOST 5041A/8260B (Full list)

Surrogate Method Limits CAS Number 70-130 2037-26-5 Toluene-d8 70-130 460-00-4 4-Bromofluorobenzene

Page 3

# APPENDIX F

ANALYTICAL DATA - FUELS

# APPENDIX G
CALIBRATIONS SHEETS, CERTIFICATIONS

# ( Intentionally Left Blank )

# ( Intentionally Left Blank )

# ( Intentionally Left Blank )

# APPENDIX H

PROCESS DATA