# Patent

## Title
Single mask adder phase change memory element

## Abstract

A method of fabricating a phase change memory element within a semiconductor structure includes etching an opening to an upper surface of a bottom electrode, the opening being formed of a height equal to a height of a metal region at a same layer within the semiconductor structure, depositing phase change material within the opening, recessing the phase change material within the opening, and forming a top electrode on the recessed phase change material.

## Background
CROSS-REFERENCE TO RELATED APPLICATION
This application is a divisional of U.S. patent application Ser. No. 12/549,997, filed Aug. 28, 2009, the disclosure of which is incorporated by reference herein in its entirety.


BACKGROUND
The present invention relates generally to semiconductor structures, and more specifically, to a semiconductor structure having an embedded single mask adder phase change memory element.
Typically, programming currents required by phase change memories require some aspect of the structure to have a feature size which is sub-lithographically defined in order to maintain a small cell size for the phase change memory element and access circuitry. Some applications, such as fuse devices, have less stringent area requirements. In these applications, it is important to minimize the additional processing costs required to fabricate an embedded memory element into an existing complementary metal oxide semiconductor (CMOS) technology, for example.
FIG. 1 illustrates a typical semiconductor structure. As shown in FIG. 1, a CMOS structure 10 includes a substrate 11 having a borophosphosilicate glass (BPSG) dielectric layer 12 formed thereon. A plurality of conductive contacts 14 (e.g., tungsten) are formed in the BPSG dielectric layer 12 and surrounded by a liner 15 of titanium nitride, for example, used prior to the deposition of the tungsten fill, to form the conductive contacts 14. An access transistor having a gate 16 and spacers 17 adjacent to the sidewalls of the gate 16, and source/drain regions 18 is also provided. Shallow trench isolation (STI) regions 19 are formed within the substrate 11 to provide electrical isolation between the access transistor and other devices. The conductive contacts 14 connect to the source/drain regions 18. A first metal region 19 (M1) is formed on top of each conductive contact 14 within a first dielectric layer 20 and capped with a first cap layer 21. A second dielectric layer 23 is then formed to contain vias 24 and capped with a second cap layer 25. A second metal region 26 (M2) is formed within a third dielectric layer 28, over each via 24 with the vias 24 connecting the first metal regions 19 to the second metal regions 26.
SUMMARY
In one embodiment, a phase change memory element of a semiconductor structure includes a bottom electrode formed at a contact surface of a conductive contact within a substrate having access circuitry, and an opening formed at an upper surface of the bottom electrode, the opening being formed of a height equal to a height of a metal region formed at a same layer within the semiconductor structure, and filled with phase change material and top electrode material to form the top electrode within the opening.
In another embodiment, a semiconductor structure having a single mask adder phase change memory element embedded therein includes a plurality of conductive contacts recessed to form a plurality of vias at an upper surface of each conductive contact within a substrate including access circuitry to be connected with the conductive contacts and having a first dielectric layer formed thereon, a bottom electrode formed in each via, and a first metal region formed within a second dielectric layer above the first dielectric layer at a respective bottom electrode. The semiconductor structure further includes an opening formed within the second dielectric layer to an upper surface of a respective bottom electrode and having recessed phase change memory formed therein, a top electrode formed on the recessed phase change material within the opening, a via formed in a third dielectric layer formed above the second dielectric layer, and a second metal region formed in a fourth dielectric layer above the third dielectric layer, the via is formed in between the first and the second metal regions to connect the first metal region to the second metal region.
Additional features and advantages are realized through the techniques of the present invention. Other embodiments and aspects of the invention are described in detail herein and are considered a part of the claimed invention. For a better understanding of the invention with the advantages and the features, refer to the description and to the drawings.



BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The forgoing and other features, and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:
FIG. 1 is a diagram illustrating a conventional semiconductor structure.
FIG. 2 is a diagram illustrating a fabrication operation of a semiconductor structure having an embedded phase change memory element that can be implemented within embodiments of the present invention.
FIG. 3 is a diagram illustrating a recess operation of conductive contacts within the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 4 is a diagram illustrating a deposition operation for forming a bottom electrode within the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 5 is a diagram illustrating planarizing operation of the bottom electrode within the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 6 is a diagram illustrating forming of a first metal region of the semiconductor structure that can be implemented within embodiments of the present invention.
FIG. 7 is a diagram illustrating the deposition of a cap layer on the first metal region that can be implemented within embodiments of the present invention.
FIG. 8 is a diagram illustrating the formation of an opening to define a bit line within the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 9 is a diagram illustrating deposition of phase change material within the opening of the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 10 is a diagram illustrating a planarization operation of the phase change material of the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 11 is a diagram illustrating a recess operation of the phase change material that can be implemented within embodiments of the present invention.
FIG. 12 is a diagram illustrating a formation operation of a top electrode of the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 13 is a diagram illustrating a planarizing operation of the top electrode of the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 14 is a diagram illustrating a deposition a cap layer above the phase change memory element that can be implemented within embodiments of the present invention.
FIG. 15 is a diagram illustrating a final fabrication operation of the semiconductor structure that can be implemented within embodiments of the present invention.



DETAILED DESCRIPTION
The present invention provides a single mask adder phase change memory element to be included in advanced CMOS technologies, bi-CMOS technologies and SiGe-based technologies. The fabrication of the semiconductor structure 200 (depicted in FIG. 15) including an embedded phase change memory element 150 will now be described below with reference to FIGS. 2 through 15.
With reference now to FIG. 2, a diagram illustrating a fabrication operation of a phase change memory element that can be implemented within embodiments of the present invention is provided. As shown in FIG. 2, a substrate 50 having a first dielectric layer 100 (e.g., a borophosphosilicate glass (BPSG) dielectric layer) formed thereon is provided. The present invention is not limited to a BPSG type wafer and any suitable type of wafer may be utilized for the purpose set forth herein. A plurality of conductive contacts 101 are formed in the BPSG dielectric layer 100 and surrounded by a liner 102 of titanium nitride, for example, used prior to the deposition of the contact fill, to form the conductive contacts 101. According to an embodiment of the present invention, the conductive contacts 101 may include tungsten (W), or titanium nitride (TiN), or copper (Cu), for example. The conductive contacts are connected to access circuitry (e.g., an access transistor) within the substrate 50. The access transistor includes a gate 103 and spacers 104 adjacent to the sidewalls of the gate 103, and source/drain regions 105. Shallow trench isolation (STI) regions 106 are formed within the substrate 50 to provide electrical isolation between the access transistor and other devices. The conductive contacts 101 connect to the source/drain regions 105. A first cap layer 107 is formed over the BPSG dielectric layer 100 of a predetermined thickness ranging from approximately 20 nanometers (nm) to approximately 50 nanometers (nm). The first cap layer 107 may include silicon nitride (SiN) or silicon dioxide (SiO2), for example, however the present invention is not limited hereto. The first cap layer 107 is incorporated as a top layer of the BPSG dielectric layer 100 or alternatively the first cap layer 107 may be formed on top of the BPSG dielectric layer 100 and polished via a conventional polishing procedure. Fabrication processes of a bottom electrode will now be described below with reference to FIGS. 3 through 6 below. The bottom electrode may be formed in accordance with a Patent Application entitled “FLAT LOWER BOTTOM ELECTRODE OF PHASE CHANGE MEMORY” written by Breitwisch, et al. and filed on Aug. 28, 2009, which is incorporated herein by reference.
FIG. 3 is a diagram illustrating a recess operation of conductive contacts within the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 3, the conductive contacts 101 are recessed with respect to the first cap layer 107 using a reactive ion etching (RIE) process, for example, to form vias 101a. According to an embodiment of the present invention, the conductive contacts 101 are etched a depth of the first cap layer 107 plus an additional 10-15 (nm) nanometers to form the vias 101a. 
FIG. 4 is a diagram illustrating a deposition of electrode material within the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 4, a selectable electrode material 108 is deposited on the first cap layer 107 and within the vias 101a. According to an embodiment of the present invention, the selectable electrode material 108 may include titanium nitride (TiN), tungsten (W), or any suitable conductive material. According to one embodiment, approximately 10 nanometers (nm) of ion metal plasma (IMP) titanium may be deposited followed by a layer of titanium nitride, which is deposited via a chemical vapor deposition (CVD) process. According to an embodiment of the present invention, the electrode material 108 is compatible with the selected phase change material 118 as discussed later with reference to FIG. 9.
FIG. 5 is a diagram illustrating a planarization operation of the electrode material within the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 5, the electrode material 108 is planarized using a chemical mechanical polishing (CMP) process, to form a lower bottom electrode 109 over each conductive contact 101. In one embodiment of the present invention, the first cap layer 107 acts as a CMP stop layer.
FIG. 6 is a diagram illustrating formation of a first metal region within the semiconductor structure that can be implemented within embodiments of the present invention. As shown in FIG. 6, a second dielectric layer 111 is formed on the first cap layer 107 and a first metal region 112 (M1) is formed within the second dielectric layer 111. The second dielectric layer 111 may be formed of silicon dioxide (SiO2), for example. The first metal region 112 may be formed of copper (Cu), for example however the present invention is not limited hereto, other types of metals including aluminum (Al), titanium nitride (TiN), and tungsten (W) based materials may be used.
FIG. 7 is a diagram illustrating the formation of a second cap layer within the semiconductor structure that can be implemented within embodiments of the present invention. As shown in FIG. 7, a second cap layer 114 is formed on the second dielectric layer 111 and used to cap the metal contained in the first metal region 112. According to an embodiment of the present invention, the second cap layer 114 may be formed of the same material as the first cap layer 107. For example, both the first and second cap layers 107 and 114 may be formed of silicon nitride (SiN), for example. The fabrication of the embedded phase change memory cell will now be discussed below with reference to FIGS. 8 through 13.
FIG. 8 is a diagram illustrating the formation of an opening for the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 8, an opening 116 is etched through the second cap layer 114 and the second dielectric layer 111 to contact an upper surface of the respective bottom electrode 109. According to an embodiment of the present invention, the opening 116 may be a trench or a via. As shown in FIG. 8, the opening 116 is adjacent to the first metal region 112 and is formed at a height of a same height as that of the first metal region 112. The opening 116 is formed within the same layer (e.g., second dielectric layer 111) of the semiconductor structure. The opening 116 is etched to define a bitline of the phase change memory.
FIG. 9 is a diagram illustrating a deposition of phase change material within the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 9, phase change material 118 is deposited within the opening 116, thereby filling the opening 116 and along the second cap layer 114. According to an embodiment of the present invention, the phase change material 118 may be made of germanium-antimony-telluride (GeSbTe) or one of alloys of gallium (Ga)/Sb, indium (In)/Sb, In/selenium (Se), Sb/Te, Ge/Te, In/Sb/Te, Ga/Se/Te, Sn/Sb/Te, In/Sb/Ge, silver (Ag)/In/Sb/Te, Ge/Sb/Se/Te, Te/Ge/Sb/sulfur (S). A wide range of alloy compositions may be used. The phase change material 118 may be deposited using a physical vapor deposition (PVD) process, a chemical vapor deposition (CVD) process, a spin-on process, or an electro-chemical plating process, for example, or any other suitable deposition operation.
FIG. 10 is a diagram illustrating a planarizing operation of the phase change material of the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 10, the phase change material 118 is polished using a chemical mechanical polishing (CMP) process. As further shown, the phase change material 118 is stopped at the second cap layer 114. Thus, the second cap layer 114 acts as a CMP stop layer.
FIG. 11 is a diagram illustrating a recess operation of the phase change material within the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 11, the phase change material 118 is recessed using a RIE process, a sputtering process, or a wet chemistry process, for example to form a via 120. According to an embodiment of the present invention, the phase change material 118 is recessed such that the recessed phase change material 118 is greater than approximately 5 nanometers (nm), and preferably greater than approximately 20 nanometers (nm). The preferred thickness of the phase change material 118 ranges from approximately 20 nanometers (nm) to 100 nanometers (nm). According to an embodiment of the present invention, the via 120 may be of a height equal to one-half a height of the first metal region 112. According to another embodiment of the present invention, the via 120 is of a predetermined height ranging from approximately 20 nanometers (nm) to 100 nanometers (nm). FIG. 12 is a diagram illustrating the formation of a top electrode of the phase change memory element that can be implemented within embodiments of the present invention. As shown in FIG. 12, a top electrode 122 (as depicted in FIG. 13) is formed by first depositing electrode material 121 (e.g., a phase change material capping layer) such as titanium nitride (TiN) for example, on the second cap layer 114 and within the via 120.
FIG. 13 is a diagram illustrating a planarization operation of the top electrode 122 of the phase change memory. As shown in FIG. 13, the material 121 is removed from the upper surface of the second cap layer 114 such that the material 121 (e.g., the CMP titanium nitride (TiN)) stops at the second cap layer 114 to form the top electrode 122. According to an embodiment of the present invention, the bottom electrode 109 and the top electrode 122 are made of the same material. As shown in FIG. 13, a resulting phase change memory element 150 is formed. The phase change material 118 and the top electrode 122 together are of a same height as the first metal region 112 within the semiconductor structure.
FIG. 14 is a diagram illustrating deposition of a third cap layer within the semiconductor structure that can be implemented within embodiments of the present invention. As shown in FIG. 14, a third cap layer 124 is formed on an upper surface of the second cap layer 114 and the top electrode 122 to cap the top electrode 122. The third cap layer 124 may be formed of the same material as that of the first and second cap layers 107 and 114. For example, all three cap layers 107, 114 and 124 may be formed of silicon nitride (SiN), for example. Next, in FIG. 15, the remaining back-of-the-line process (e.g., the final fabrication process) is performed to form a semiconductor structure 200.
It should be noted that although the processing order described here is the first metallization process first followed by the formation of the phase change element, it is also herein disclosed that the reverse order of these two processes may occur.
FIG. 15 is a diagram illustrating the final fabrication process of a semiconductor structure that can be implemented within embodiments of the present invention. As shown in FIG. 15, the semiconductor structure 200 further includes a third dielectric layer 126 on the third cap layer 124 and having a via 128 formed therein, a fourth cap layer 130 is formed on an upper surface of the third dielectric layer 126 to cap the material contained in the via 128, and a second metal region 132 is formed in a fourth dielectric layer 134 on an upper surface of the via 128. The via 128 connects the first metal region 112 to the second metal region 132. According to an embodiment of the present invention, the via 128 and the second metal region 134 may be formed using a conventional single or dual damascene process such that the via 128 and the second metal region 134 are formed separately or simultaneously.
Embodiments of the present invention provide a method of fabricating an embedded phase change memory element into a semiconductor structure using only a single lithographic masking operation. Therefore, the present invention provides the advantages of minimizing the number of additional masking levels and in turn minimizing associated processing costs. The present invention also provide additional advantages such as the metallization layers occurring in the same physical location as the structure without the phase change element so that the electrical models associated with the wiring capacitance and resistance are identical or very similar with or without the additional phase change element.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, element components, and/or groups thereof.
The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The embodiment was chosen and described in order to best explain the principles of the invention and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated
The flow diagrams depicted herein are just one example. There may be many variations to this diagram or the steps (or operations) described therein without departing from the spirit of the invention. For instance, the steps may be performed in a differing order or steps may be added, deleted or modified. All of these variations are considered a part of the claimed invention.
While the preferred embodiment to the invention had been described, it will be understood that those skilled in the art, both now and in the future, may make various improvements and enhancements which fall within the scope of the claims which follow. These claims should be construed to maintain the proper protection for the invention first described.

## Claims

1. A phase change memory element of a semiconductor structure, the phase change memory element comprising:
a bottom electrode formed at a contact surface of a conductive contact within a substrate having access circuitry; and
an opening formed at an upper surface of the bottom electrode, the opening being formed of a height equal to a height of a metal region formed at a same layer within the semiconductor structure, and filled with phase change material and top electrode material to form the top electrode within the opening.

2. The phase change memory element of claim 1, wherein a via is formed at an upper surface of the phase change material.

3. The phase change memory element of claim 2, wherein the via formed at an upper surface of the phase change material is of a predetermined height equal to one-half the height of the metal region, to form the top electrode.

4. The phase change memory element of claim 1, wherein a via is formed at an upper surface of the phase change material of a height ranging from approximately 20 nanometers (nm) to approximately 100 nanometers (nm), to form the top electrode.

5. The phase change memory element of claim 1, wherein the opening is a trench or a via.

6. A semiconductor structure having a single mask adder phase change memory element embedded therein, the semiconductor structure comprising:
a plurality of conductive contacts recessed to form a plurality of vias at an upper surface of each conductive contact within a substrate including access circuitry to be connected with the conductive contacts and having a first dielectric layer formed thereon;
a bottom electrode formed in each via;
a first metal region formed within a second dielectric layer above the first dielectric layer at a respective bottom electrode;
an opening formed within the second dielectric layer to an upper surface of a respective bottom electrode and having recessed phase change memory formed therein;
a top electrode formed on the recessed phase change material within the opening;
a via formed in a third dielectric layer formed above the second dielectric layer; and
a second metal region formed in a fourth dielectric layer above the third dielectric layer, the via formed in the third dielectric layer is formed in between the first and the second metal regions to connect the first metal region to the second metal region.

7. The semiconductor structure of claim 6, wherein the plurality of conductive contacts are recessed a depth equal to approximately 10 nanometers (nm) to 15 nanometers (nm) in addition to a depth of the first dielectric layer to form the plurality of vias.

8. The semiconductor structure of claim 6, wherein each bottom electrode is formed of a material comprises at least one of titanium nitride (TiN) or tungsten (W).

9. The semiconductor structure of claim 6, wherein the opening is formed is of height equal to a height of the first metal region.

10. The semiconductor structure of claim 6, wherein the phase change material is recessed to form a via at an upper surface of the phase change material for depositing top electrode material to form the top electrode.

11. The semiconductor structure of claim 10, wherein the via is formed at the upper surface of the recessed phase change material is of a predetermined height equal to one-half the height of the metal region.

12. The semiconductor structure of claim 6, wherein the via is formed at the upper surface of the recessed phase change material of a height ranging from approximately 20 nanometers (nm) to approximately 100 nanometers (nm).