Instructions for using the Emission Test Reporting Template for the Primary Aluminum Test Program

This Information Collection Request (ICR) spreadsheet is intended to be used to report emissions data from primary aluminum 

reduction facilities as an alternative to the Electronic Reporting Tool (ERT), as well as in cases where the test methods are not 

currently supported by the ERT. Data for multiple process units should be reported by using separate copies of the 

appropriate tabs of this spreadsheet. Please Do Not delete rows or columns, addition of rows and columns is appropriate 

as necessary. 

Emission Data Worksheets 

The emission data worksheets are provided for each test required for this testing program, although all facilities are not 

required to conduct all of the tests. On each worksheet, please enter process unit operating information during sampling 

and emission test results. The emission test results to be entered depends on the constituent. 

Source Operating Information

1. Please provide the Exhaust Flow Rate (acfm and dscfm) and the Exhaust Temperature (deg F). 

2. Please provide the values of all requested parameters for each of the sample testing periods in the appropriate cells.

3. Please provide any other supporting information or comments in the Other Supporting Information field.
Page 1 of 8 

Primary Aluminum Testing: Dioxins and Furans

Parent company name: Alcoa Facility address: Alcoa Massena Operations

East Plant

Description of source tested: Line 3 Downcomer Massena, New York 13662

lb/hr lb/ton 

Throughputa

1 4/30/2013 1002 4/30/2013 1418 2.93E-08 5.74E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 7.81E-08 1.53E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 2.41E-08 4.72E-09 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 1.54E-07 3.01E-08 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 3.98E-07 7.80E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 1.02E-07 2.00E-08 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 1.21E-08 2.37E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 8.31E-08 1.63E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 6.08E-09 1.19E-09 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 [<8.58E-09] [<1.68E-09] 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.64E-08 3.22E-09 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 [<8.08E-09] [<1.57E-09] 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 4.63E-08 9.06E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 3.98E-08 7.80E-09 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 2.84E-08 5.56E-09 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 [8.78E-09] [<1.72E-09] 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.64E-08 3.22E-09 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 [<7.45E-09 [<1.46E-09] 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 4.56E-08 8.93E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 7.93E-08 1.55E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 2.35E-08 4.60E-09 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 9.63E-09 1.89E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.62E-08 3.17E-09 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 [<8.93E-09] [<1.75E-09] 5.11 Aluminum

Calculated Emission Rate

Throughput 

Material

1,2,3,7,8,9-

HxCDD

1,2,3,6,7,8-

HxCDD

1,2,3,6,7,8-

HxCDF

1,2,3,4,7,8-

HxCDD

1,2,3,4,7,8-

HxCDF

1,2,3,4,6,7,8-

HpCDF

1,2,3,4,7,8,9-

HpCDF

1,2,3,4,6,7,8-

HpCDD

Throughput 

(ton/hr) Compound Run Number

Test Start 

Date

Test Start 

Time

Test End 

Date

Test End 

Time
Page 2 of 8 

lb/hr lb/ton 

Throughputa

Calculated Emission Rate

Throughput 

Material

Throughput 

(ton/hr) Compound Run Number

Test Start 

Date

Test Start 

Time

Test End 

Date

Test End 

Time

1 4/30/2013 1002 4/30/2013 1418 [<5.74E-09] [<1.12E-09] 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 [<6.4E-09] [<1.25E-09] 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 [<6.12E-09] [<1.20E-09] 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 1.24E-08 2.43E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.47E-08 2.87E-09 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 [<8.78E-09] [<1.72E-09] 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 4.36E-08 8.53E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 6.90E-08 1.35E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 2.08E-08 4.08E-09 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 4.42E-08 8.67E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 6.68E-08 1.31E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 2.17E-08 4.24E-09 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 8.75E-08 1.71E-08 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.30E-07 2.54E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 5.11E-08 1.00E-08 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 7.50E-09 1.47E-09 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 5.93E-09 1.16E-09 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 [<6.30E-09] [<1.23E-09] 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 7.70E-08 1.51E-08 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 9.78E-08 1.92E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 5.11E-08 1.00E-08 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 8.07E-08 1.58E-08 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.50E-07 2.94E-08 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 6.98E-08 1.37E-08 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 1.60E-07 3.13E-08 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 1.37E-06 2.69E-07 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 1.07E-07 2.10E-08 5.11 Aluminum

a

 Note that lb/ton results based on total Line 3 potroom flow rate

b

 EMPC = Estimated Maximum Possible Concentration. EMPC occurs when there is possible co-eluting interference or signal to noise ratio

is not sufficient for peak identification

OCDF

OCDD

2,3,7,8-

TCDD

2,3,7,8-TCDF

2,3,4,6,7,8-

HxCDF

2,3,4,7,8-

PeCDF

1,2,3,7,8-

PeCDD

1,2,3,7,8-

PeCDF

1,2,3,7,8,9-

HxCDF
Page 3 of 8 

Primary Aluminum Testing: Dioxins and Furans

Parent company name: Alcoa Facility address: Alcoa Massena Operat

East Plant

Description of source tested: Line 3 Downcomer Massena, New York 13

Measured 

Value (ng)

Wet or Dry 

Basis

Test Method 

(e.g.,CARB 429)

Data Flag 

(ADL, BDL, DLL)

Front Half 

Mass* (ng)

Back Half 

Mass** (ng)

Impinger Soln 

Mass*** (ng)

ADL 1 ADL

ADL 2 ADL

EMPCb

3 ADL/EMPC

ADL 1 ADL

ADL 2 ADL

ADL 3 ADL

ADL/EMPC 1 ADL/EMPC

ADL 2 ADL

ADL 3 ADL

BDL 1 BDL

ADL 2 ADL

BDL 3 BDL

ADL 1 ADL

ADL 2 ADL

ADL 3 ADL

BDL 1 BDL

ADL 2 ADL

BDL 3 BDL

ADL 1 ADL

ADL 2 ADL

ADL/EMPC 3 ADL/EMPC

ADL 1 ADL

ADL/EMPC 2 ADL/EMPC

BDL 3 BDL

Separate Analysis

1,2,3,7,8,9-

HxCDD

1,2,3,6,7,8-

HxCDD

1,2,3,6,7,8-

HxCDF

1,2,3,4,7,8-

HxCDD

1,2,3,4,7,8-

HxCDF

1,2,3,4,6,7,8-

HpCDF

1,2,3,4,7,8,9-

HpCDF

1,2,3,4,6,7,8-

HpCDD

Test Method Comments Compound Run 

Number

Dioxins and Furans Emission Test Results
Page 4 of 8 

Measured 

Value (ng)

Wet or Dry 

Basis

Test Method 

(e.g.,CARB 429)

Data Flag 

(ADL, BDL, DLL)

Front Half 

Mass* (ng)

Back Half 

Mass** (ng)

Impinger Soln 

Mass*** (ng)

Separate Analysis Test Method Comments Compound Run 

Number

Dioxins and Furans Emission Test Results

BDL 1 BDL

BDL 2 BDL

BDL 3 BDL

ADL 1 ADL

ADL 2 ADL

BDL 3 BDL

ADL 1 ADL

ADL 2 ADL

ADL/EMPC 3 ADL/EMPC

ADL 1 ADL

ADL 2 ADL

ADL 3 ADL

ADL 1 ADL

ADL 2 ADL

ADL 3 ADL

ADL/EMPC 1 ADL/EMPC

ADL/EMPC 2 ADL/EMPC

BDL 3 BDL

ADL 1 ADL

ADL 2 ADL

ADL 3 ADL

ADL/EMPC 1 ADL/EMPC

ADL 2 ADL

ADL 3 ADL

ADL 1 ADL

ADL 2 ADL

ADL 3 ADL

* Front Half Composite contains particulate filter, front half of the filter holder, and probe solvent rinses

** Back Half Composite contains XAD-2 resin tube, back half of the filter holder, and coil condenser solvent rinses

OCDF

OCDD

2,3,7,8-

TCDD

2,3,7,8-TCDF

2,3,4,6,7,8-

HxCDF

2,3,4,7,8-

PeCDF

1,2,3,7,8-

PeCDD

1,2,3,7,8-

PeCDF

1,2,3,7,8,9-

HxCDF
Page 5 of 8 

Primary Aluminum Testing: Dioxins and Furans

na Operations Parent company name: Alcoa Facility address:

w York 13662 Description of source tested: Line 3 Downcomer

Composite Analysis

Total (ng) Total (ng) Moisture 

(%) CO2

 (%) O2 (%) Flow 

(acfm)

Flow 

(dscfm)

Temperature 

(°F)

0.0087 1 8.6 0.0 20.9 NA 3837511 77

0.0249 2 7.1 0.0 20.9 NA 3648875 91

0.0067 3 6.7 0.0 20.9 NA 4143142 94

0.0455 1 8.6 0.0 20.9 NA 3837511 77

0.1270 2 7.1 0.0 20.9 NA 3648875 91

0.0283 3 6.7 0.0 20.9 NA 4143142 94

0.0036 1 8.6 0.0 20.9 NA 3837511 77

0.0265 2 7.1 0.0 20.9 NA 3648875 91

0.0017 3 6.7 0.0 20.9 NA 4143142 94

0.0025 1 8.6 0.0 20.9 NA 3837511 77

0.0038 2 7.1 0.0 20.9 NA 3648875 91

0.0022 3 6.7 0.0 20.9 NA 4143142 94

0.0137 1 8.6 0.0 20.9 NA 3837511 77

0.0320 2 7.1 0.0 20.9 NA 3648875 91

0.0079 3 6.7 0.0 20.9 NA 4143142 94

0.0026 1 8.6 0.0 20.9 NA 3837511 77

0.0052 2 7.1 0.0 20.9 NA 3648875 91

0.0021 3 6.7 0.0 20.9 NA 4143142 94

0.0135 1 8.6 0.0 20.9 NA 3837511 77

0.0253 2 7.1 0.0 20.9 NA 3648875 91

0.0065 3 6.7 0.0 20.9 NA 4143142 94

0.0029 1 8.6 0.0 20.9 NA 3837511 77

0.0052 2 7.1 0.0 20.9 NA 3648875 91

0.0025 3 6.7 0.0 20.9 NA 4143142 94

1,2,3,7,8,9-

HxCDD

1,2,3,6,7,8-

HxCDD

1,2,3,6,7,8-

HxCDF

1,2,3,4,7,8-

HxCDD

1,2,3,4,7,8-

HxCDF

1,2,3,4,6,7,8-

HpCDF

1,2,3,4,7,8,9-

HpCDF

Compound Run 

Number

Exhaust Gas

1,2,3,4,6,7,8-

HpCDD
Page 6 of 8 

Composite Analysis

Total (ng) Total (ng) Moisture 

(%) CO2

 (%) O2 (%) Flow 

(acfm)

Flow 

(dscfm)

Temperature 

(°F)

Compound Run 

Number

Exhaust Gas

0.0017 1 8.6 0.0 20.9 NA 3837511 77

0.0020 2 7.1 0.0 20.9 NA 3648875 91

0.0017 3 6.7 0.0 20.9 NA 4143142 94

0.0037 1 8.6 0.0 20.9 NA 3837511 77

0.0047 2 7.1 0.0 20.9 NA 3648875 91

0.0024 3 6.7 0.0 20.9 NA 4143142 94

0.0129 1 8.6 0.0 20.9 NA 3837511 77

0.0220 2 7.1 0.0 20.9 NA 3648875 91

0.0058 3 6.7 0.0 20.9 NA 4143142 94

0.0131 1 8.6 0.0 20.9 NA 3837511 77

0.0213 2 7.1 0.0 20.9 NA 3648875 91

0.0060 3 6.7 0.0 20.9 NA 4143142 94

0.0259 1 8.6 0.0 20.9 NA 3837511 77

0.0414 2 7.1 0.0 20.9 NA 3648875 91

0.0142 3 6.7 0.0 20.9 NA 4143142 94

0.0022 1 8.6 0.0 20.9 NA 3837511 77

0.0019 2 7.1 0.0 20.9 NA 3648875 91

0.0018 3 6.7 0.0 20.9 NA 4143142 94

0.0228 1 8.6 0.0 20.9 NA 3837511 77

0.0312 2 7.1 0.0 20.9 NA 3648875 91

0.0142 3 6.7 0.0 20.9 NA 4143142 94

0.0239 1 8.6 0.0 20.9 NA 3837511 77

0.0479 2 7.1 0.0 20.9 NA 3648875 91

0.0194 3 6.7 0.0 20.9 NA 4143142 94

0.0473 1 8.6 0.0 20.9 NA 3837511 77

0.4380 2 7.1 0.0 20.9 NA 3648875 91

0.0298 3 6.7 0.0 20.9 NA 4143142 94

OCDF

OCDD

2,3,7,8-TCDD

2,3,7,8-TCDF

2,3,4,6,7,8-

HxCDF

2,3,4,7,8-PeCDF

1,2,3,7,8-PeCDD

1,2,3,7,8-PeCDF

1,2,3,7,8,9-

HxCDF
Page 7 of 8 

Alcoa Massena Operations

East Plant

Massena, New York 13662

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Other Supporting Information
Page 8 of 8 

Other Supporting Information

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom

Flow data is for total Line 3 Potroom
Page 1 of 8

Primary Aluminum Testing: Polycyclic Aromatic Hydrocarbons

Parent company name: Alcoa Facility address: Alcoa Massena Operations

East Plant

Description of source tested: Line 3 Downcomer Massena, New York 13662

lb/hr lb/ton 

Throughput

1 4/30/2013 1002 4/30/2013 1418 0.13376 0.02619 5.11

2 4/30/2013 1455 4/30/2013 1911 0.14830 0.02904 5.11

3 5/1/2013 825 5/1/2013 1230 0.15085 0.02954 5.11

1 4/30/2013 1002 4/30/2013 1418 0.01246 0.00244 5.11

2 4/30/2013 1455 4/30/2013 1911 0.01304 0.00255 5.11

3 5/1/2013 825 5/1/2013 1230 0.00900 0.00176 5.11

1 4/30/2013 1002 4/30/2013 1418 0.02131 0.00417 5.11

2 4/30/2013 1455 4/30/2013 1911 0.02527 0.00495 5.11

3 5/1/2013 825 5/1/2013 1230 0.02200 0.00431 5.11

1 4/30/2013 1002 4/30/2013 1418 0.03547 0.00695 5.11

2 4/30/2013 1455 4/30/2013 1911 0.05361 0.01050 5.11

3 5/1/2013 825 5/1/2013 1230 0.02031 0.00398 5.11

1 4/30/2013 1002 4/30/2013 1418 0.02388 0.00468 5.11

2 4/30/2013 1455 4/30/2013 1911 0.02289 0.00448 5.11

3 5/1/2013 825 5/1/2013 1230 0.00806 0.00158 5.11

1 4/30/2013 1002 4/30/2013 1418 0.08613 0.01687 5.11

2 4/30/2013 1455 4/30/2013 1911 0.07807 0.01529 5.11

3 5/1/2013 825 5/1/2013 1230 0.04968 0.00973 5.11

1 4/30/2013 1002 4/30/2013 1418 0.14794 0.02897 5.11

2 4/30/2013 1455 4/30/2013 1911 0.14861 0.02910 5.11

3 5/1/2013 825 5/1/2013 1230 0.10081 0.01974 5.11

1 4/30/2013 1002 4/30/2013 1418 0.03138 0.00615 5.11

2 4/30/2013 1455 4/30/2013 1911 0.03126 0.00612 5.11

3 5/1/2013 825 5/1/2013 1230 0.01991 0.00390 5.11

Compound Run 

Number

Test Start 

Date

Test Start 

Time

Test End 

Date

Test End 

Time

Acenaphthene (83-32-9)

Calculated Emission Rate

Throughput 

(ton/hr)

Acenaphthylene (208-96-8)

Anthracene (120-12-7)

Benz[a]anthracene (56-55-3)

Benzo[a]pyrene (50-32-8)

Benzo(e)pyrene (192-97-2)

Benzo[b]fluoranthene (205-99-2)

Benzo[g,h,i]perylene (191-24-2)
Page 2 of 8

lb/hr lb/ton 

Throughput

Compound Run 

Number

Test Start 

Date

Test Start 

Time

Test End 

Date

Test End 

Time

Calculated Emission Rate

Throughput 

(ton/hr)

1 4/30/2013 1002 4/30/2013 1418 0.06451 0.01263 5.11

2 4/30/2013 1455 4/30/2013 1911 0.05173 0.01013 5.11

3 5/1/2013 825 5/1/2013 1230 0.03550 0.00695 5.11

1 4/30/2013 1002 4/30/2013 1418 0.11619 0.02275 5.11

2 4/30/2013 1455 4/30/2013 1911 0.11883 0.02327 5.11

3 5/1/2013 825 5/1/2013 1230 0.08857 0.01734 5.11

1 4/30/2013 1002 4/30/2013 1418 0.00730 0.00143 5.11

2 4/30/2013 1455 4/30/2013 1911 0.00875 0.00171 5.11

3 5/1/2013 825 5/1/2013 1230 0.00432 0.00085 5.11

1 4/30/2013 1002 4/30/2013 1418 0.29893 0.05854 5.11

2 4/30/2013 1455 4/30/2013 1911 0.29033 0.05686 5.11

3 5/1/2013 825 5/1/2013 1230 0.30207 0.05916 5.11

1 4/30/2013 1002 4/30/2013 1418 0.02567 0.00503 5.11

2 4/30/2013 1455 4/30/2013 1911 0.02712 0.00531 5.11

3 5/1/2013 825 5/1/2013 1230 0.02668 0.00522 5.11

1 4/30/2013 1002 4/30/2013 1418 0.02621 0.00513 5.11

2 4/30/2013 1455 4/30/2013 1911 0.02499 0.00489 5.11

3 5/1/2013 825 5/1/2013 1230 0.01588 0.00311 5.11

1 4/30/2013 1002 4/30/2013 1418 0.10167 0.01991 5.11

2 4/30/2013 1455 4/30/2013 1911 0.10284 0.02014 5.11

3 5/1/2013 825 5/1/2013 1230 0.09577 0.01875 5.11

1 4/30/2013 1002 4/30/2013 1418 0.06316 0.01237 5.11

2 4/30/2013 1455 4/30/2013 1911 0.07619 0.01492 5.11

3 5/1/2013 825 5/1/2013 1230 0.06625 0.01297 5.11

1 4/30/2013 1002 4/30/2013 1418 0.19186 0.03757 5.11

2 4/30/2013 1455 4/30/2013 1911 0.21728 0.04255 5.11

3 5/1/2013 825 5/1/2013 1230 0.20342 0.03984 5.11

1 4/30/2013 1002 4/30/2013 1418 0.00513 0.00101 5.11

2 4/30/2013 1455 4/30/2013 1911 0.00593 0.00116 5.11

3 5/1/2013 825 5/1/2013 1230 0.00188 0.00037 5.11

1 4/30/2013 1002 4/30/2013 1418 0.07093 0.01389 5.11

2 4/30/2013 1455 4/30/2013 1911 0.06929 0.01357 5.11

3 5/1/2013 825 5/1/2013 1230 0.07237 0.01417 5.11

Benzo[k]fluoranthene (207-08-9)

Chrysene (218-01-9)

Dibenz[a,h]anthracene (53-70-3)

Fluoranthene (206-44-0)

Fluorene (86-73-7)

Indeno (1,2,3-cd) pyrene (193-39-5)

Naphthalene (91-20-3)

2-Methylnaphthalene (91-57-6)

Phenanthrene (85-01-8)

Perylene (198-55-0)

Pyrene (129-00-0)
Page 3 of 8

Primary Aluminum Testing: Polycyclic Aromatic Hydrocarbons

ena Operations Parent company name: Alcoa Facility address: Alcoa Massena Op

East Plant

ew York 13662 Description of source tested: Line 3 Downcomer Massena, New Yor

Measured 

Value (ng)

Wet or Dry 

Basis

Test Method 

(e.g.,CARB 429)

Data Flag 

(ADL, BDL, DLL)

Front Half 

Mass* (ng)

Back Half 

Mass** (ng)

Condensate 

Mass*** (ng) Total (ng)

Aluminum 1 CARB 429 ADL 39600

Aluminum 2 CARB 429 ADL 47300

Aluminum 3 CARB 429 ADL 41900

Aluminum 1 CARB 429 ADL 3690

Aluminum 2 CARB 429 ADL 4160

Aluminum 3 CARB 429 ADL 2500

Aluminum 1 CARB 429 ADL 6310

Aluminum 2 CARB 429 ADL 8060

Aluminum 3 CARB 429 ADL 6110

Aluminum 1 CARB 429 ADL 10500

Aluminum 2 CARB 429 ADL 17100

Aluminum 3 CARB 429 ADL 5640

Aluminum 1 CARB 429 ADL 7070

Aluminum 2 CARB 429 ADL 7300

Aluminum 3 CARB 429 ADL 2240

Aluminum 1 CARB 429 ADL 25500

Aluminum 2 CARB 429 ADL 24900

Aluminum 3 CARB 429 ADL 13800

Aluminum 1 CARB 429 ADL 43800

Aluminum 2 CARB 429 ADL 47400

Aluminum 3 CARB 429 ADL 28000

Aluminum 1 CARB 429 ADL 9290

Aluminum 2 CARB 429 ADL 9970

Aluminum 3 CARB 429 ADL 5530

Compound Run 

Number

Polycyclic Aromatic Hydrocarbons Emission Test Results

Ace naphthene

Throughput 

Material

Ace 

naphthylene

Anthracene

Benz[a] 

anthracene

Benzo[a] 

pyrene

Benzo(e) 

pyrene

Benzo[b] 

fluoranthene

Benzo[g,h,i]per

ylene
Page 4 of 8

Measured 

Value (ng)

Wet or Dry 

Basis

Test Method 

(e.g.,CARB 429)

Data Flag 

(ADL, BDL, DLL)

Front Half 

Mass* (ng)

Back Half 

Mass** (ng)

Condensate 

Mass*** (ng) Total (ng)

Compound Run 

Number

Polycyclic Aromatic Hydrocarbons Emission Test Results

Throughput 

Material

Aluminum 1 CARB 429 ADL 19100

Aluminum 2 CARB 429 ADL 16500

Aluminum 3 CARB 429 ADL 9860

Aluminum 1 CARB 429 ADL 34400

Aluminum 2 CARB 429 ADL 37900

Aluminum 3 CARB 429 ADL 24600

Aluminum 1 CARB 429 ADL 2160

Aluminum 2 CARB 429 ADL 2790

Aluminum 3 CARB 429 ADL 1200

Aluminum 1 CARB 429 ADL 88500

Aluminum 2 CARB 429 ADL 92600

Aluminum 3 CARB 429 ADL 83900

Aluminum 1 CARB 429 ADL 7600

Aluminum 2 CARB 429 ADL 8650

Aluminum 3 CARB 429 ADL 7410

Aluminum 1 CARB 429 ADL 7760

Aluminum 2 CARB 429 ADL 7970

Aluminum 3 CARB 429 ADL 4410

Aluminum 1 CARB 429 ADL 30100

Aluminum 2 CARB 429 ADL 32800

Aluminum 3 CARB 429 ADL 26600

Aluminum 1 CARB 429 ADL 18700

Aluminum 2 CARB 429 ADL 24300

Aluminum 3 CARB 429 ADL 18400

Aluminum 1 CARB 429 ADL 56800

Aluminum 2 CARB 429 ADL 69300

Aluminum 3 CARB 429 ADL 56500

Aluminum 1 CARB 429 ADL 1520

Aluminum 2 CARB 429 ADL 1890

Aluminum 3 CARB 429 ADL 521

Aluminum 1 CARB 429 ADL 21000

Aluminum 2 CARB 429 ADL 22100

Aluminum 3 CARB 429 ADL 20100

* Contains particulate filter, front half of filter holder and probe solvent rinses *** Contains condensate, impinger contents and glassware solvent r

** Contains XAD-2 resin tube, back half of filter holder and coil condenser solvent rinses E-The reported concentration exceeds The calibration range (upper point of c

Benzo[k] 

fluoranthene

Chrysene

Dibenz[a,h] 

anthracene

Fluoranthene

Fluorene

Indeno (1,2,3-

cd) pyrene

Naphthalene

2-Methyl 

naphthalene

Phenan threne

Perylene

Pyrene
Page 5 of 8

Primary Aluminum Testing: Polycyclic Aromatic Hydrocarbons

Massena Operations Parent company name: Alcoa Facility address:

na, New York 13662 Description of source tested: Line 3 Downcomer

Test Method 

Comments

Moisture 

(%) CO2

 (%) O2 (%) Flow 

(acfm)

Flow 

(dscfm)

Temperature 

(°F)

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

Compound Run 

Number

Exhaust Gas

Acenaphthene

Acenaphthylene

Anthracene

Benz[a] 

anthracene

Benzo[a]pyrene

Benzo(e)pyrene

Benzo[b] 

fluoranthene

Benzo[g,h,i] 

perylene
Page 6 of 8

Test Method 

Comments

Moisture 

(%) CO2

 (%) O2 (%) Flow 

(acfm)

Flow 

(dscfm)

Temperature 

(°F)

Compound Run 

Number

Exhaust Gas

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

E 1 8.6 0 20.9 NA 3837511 77

E 2 7.1 0 20.9 NA 3648875 91

E 3 6.7 0 20.9 NA 4143142 94

are solvent rinses

upper point of calibration curve)

Benzo[k] 

fluoranthene

Chrysene

Dibenz[a,h] 

anthracene

Fluoranthene

Fluorene

Indeno (1,2,3-cd) 

pyrene

Naphthalene

2-Methyl 

naphthalene

Phenanthrene

Perylene

Pyrene
Page 7 of 8

Alcoa Massena Operations

East Plant

Massena, New York 13662

Other Supporting Information
Page 8 of 8

Other Supporting Information
Page 1 of 6 

Primary Aluminum Testing: Polychlorinate Biphenyls (PCB)

Parent company name: Alcoa Facility address: Alcoa Massena Operations

East Plant

Description of source tested: Downcomer Line 3 Exhaust Massena, New York 13662

lb/hr lb/ton 

Throughput

1 4/30/2013 1002 4/30/2013 1418 0.000041208 0.000008070 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 0.000036056 0.000007061 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 0.000030279 0.000005930 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 0.000078701 0.000015412 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 0.000065842 0.000012894 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 0.000084968 0.000016640 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 0.000162807 0.000031883 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 0.000121337 0.000023762 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 0.000167056 0.000032715 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 0.000093563 0.000018323 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 0.000071172 0.000013938 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 0.000096129 0.000018825 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 0.000049315 0.000009658 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 0.000041700 0.000008166 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 0.000048605 0.000009518 5.11 Aluminum

1 4/30/2013 1002 4/30/2013 1418 0.000016247 0.000003182 5.11 Aluminum

2 4/30/2013 1455 4/30/2013 1911 0.000014830 0.000002904 5.11 Aluminum

3 5/1/2013 825 5/1/2013 1230 0.000016202 0.000003173 5.11 Aluminum

Compound Run 

Number

Test Start 

Date

Test Start 

Time

Test End 

Date

Test End 

Time

Calculated Emission Rate

Throughput 

(ton/hr)

Throughput 

Material Test Method Comments

Monochlorinated 

biphenyls

Dichlorinated 

biphenyls

Trichlorinated 

biphenyls

Tetrachlorinated 

biphenyls

Pentachlorinated 

biphenyls

Hexachlorinated 

biphenyls
Page 2 of 6 

lb/hr lb/ton 

Throughput

Compound Run 

Number

Test Start 

Date

Test Start 

Time

Test End 

Date

Test End 

Time

Calculated Emission Rate

Throughput 

(ton/hr)

Throughput 

Material Test Method Comments

1 4/30/2013 1002 4/30/2013 1418 0.000003614 0.000000708 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000003700 0.000000725 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000003514 0.000000688 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000000591 0.000000116 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000000793 0.000000155 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000000698 0.000000137 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.000000147 0.000000029 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.000000201 0.000000039 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.000000127 0.000000025 5.11 Aluminum 1 4/30/2013 1002 4/30/2013 1418 0.00000013 0.00000003 5.11 Aluminum 2 4/30/2013 1455 4/30/2013 1911 0.00000092 0.00000018 5.11 Aluminum 3 5/1/2013 825 5/1/2013 1230 0.00000008 0.00000002 5.11 Aluminum

Heptachlorinated 

biphenyls

Octachlorinated 

biphenyls

Nonachlorinated 

biphenyls

Decachlorinated 

biphenyls

a
Page 3 of 6 

Composite 

Analysis

Total (ng) Total (ng) Moisture 

(%)

CO2 (%) O2 (%)

Flow 

(acfm)

Flow 

(dscfm)

Temperature 

(°F)

12.2 8.6 0 20.9 NA 3837511 77

11.5 7.1 0 20.9 NA 3648875 91

8.41 6.7 0 20.9 NA 4143142 94

23.3 8.6 0 20.9 NA 3837511 77

21 7.1 0 20.9 NA 3648875 91

23.6 6.7 0 20.9 NA 4143142 94

48.2 8.6 0 20.9 NA 3837511 77

38.7 7.1 0 20.9 NA 3648875 91

46.4 6.7 0 20.9 NA 4143142 94

27.7 8.6 0 20.9 NA 3837511 77

22.7 7.1 0 20.9 NA 3648875 91

26.7 6.7 0 20.9 NA 4143142 94

14.6 8.6 0 20.9 NA 3837511 77

13.3 7.1 0 20.9 NA 3648875 91

13.5 6.7 0 20.9 NA 4143142 94

4.81 8.6 0 20.9 NA 3837511 77

4.73 7.1 0 20.9 NA 3648875 91

4.5 6.7 0 20.9 NA 4143142 94

Polychlorinated Biphenyls Emission Test Results

Compound

Exhaust Gas

Separate Analysis

Monochlorinated 

biphenyls

Monochlorinated 

biphenyls

Dichlorinated 

biphenyls

Dichlorinated 

biphenyls

Trichlorinated 

biphenyls

Trichlorinated 

biphenyls

Tetrachlorinated 

biphenyls

Tetrachlorinated 

biphenyls

Pentachlorinated 

biphenyls

Pentachlorinated 

biphenyls

Hexachlorinated 

biphenyls

Hexachlorinated 

biphenyls
Page 4 of 6 

Composite 

Analysis

Total (ng) Total (ng) Moisture 

(%)

CO2 (%) O2 (%)

Flow 

(acfm)

Flow 

(dscfm)

Temperature 

(°F)

Polychlorinated Biphenyls Emission Test Results

Compound

Exhaust Gas

Separate Analysis

1.07 8.6 0 20.9 NA 3837511 77

1.18 7.1 0 20.9 NA 3648875 91

0.976 6.7 0 20.9 NA 4143142 94

0.175 8.6 0 20.9 NA 3837511 77

0.253 7.1 0 20.9 NA 3648875 91

0.194 6.7 0 20.9 NA 4143142 94

0.0434 8.6 0 20.9 NA 3837511 77

0.0641 7.1 0 20.9 NA 3648875 91

0.0353 6.7 0 20.9 NA 4143142 94

0.039 8.6 0 20.9 NA 3837511 77

0.292 7.1 0 20.9 NA 3648875 91

0.0227 6.7 0 20.9 NA 4143142 94

Heptachlorinated 

biphenyls

Heptachlorinated 

biphenyls

Octachlorinated 

biphenyls

Octachlorinated 

biphenyls

Nonachlorinated 

biphenyls

Nonachlorinated 

biphenyls

Decachlorinated 

biphenylsa

Decachlorinated 

biphenyls
Page 5 of 6 

Other Supporting Information
Page 6 of 6 

Other Supporting Information