Statistical evaluation of the June 1 - August 31, 2002 BaseB CMAQ simulation across the OTR

(including all of VA; summer months only because of PAMS sampling) Daily average ethene (19 sites), isoprene (19 sites), and formaldehyde (18 sites) Daily averages of eth/isop computed from hourly data, require at least 12 valid hours per day Only those hours where the observed and predicted eth/isop concentrations agreed to within a factor of 25 are considered in this analysis Observed formaldehyde data consist of every 6th day 24-hour averages (only those main sampling days are displayed here) July 6-9 data were excluded because of the influence of the Quebec forest fires Only those predictions from hours with valid observed concentrations were included here The sites are SLAMS/NAMS/PAMS

Site names: first 9 characters = AQS code or descriptive name for special sites, last character = parameter occurrence code

Statistics: observed average predicted average coefficient of determination, R2

normalized mean error root mean square error fractional gross error

mean absolute gross error

mean normalized gross error

mean bias

mean normalized bias

mean fractionalized bias normalized mean bias

Statistics are organized two ways - "by date" (consider all valid observed/predicted data pairs at all sites on a given day) and "by site" (consider all valid days at a given site)obs avg, ppbCMAQ avg, ppbR^2 NME, % RMSE, ppbFE, % MAGE, ppbMNGE, % MB, ppbMNB, %MFB, % NMB, %N

20020601 0.5 0.98 0.488 100.21 0.55 83.27 0.51 255.83 0.48 253.73 81 94.8815 20020602 0.44 0.86 0.561 99.71 0.48 86.05 0.43 369.96 0.43 369.04 85.09 97.7115 20020603 0.39 1.12 0.627 185.76 0.83 105.37 0.72 335.41 0.72 335.41 105.37 185.7614 20020604 0.41 1.2 0.486 196.71 0.88 101.06 0.8 286.68 0.8 286.68 101.06 196.7116 20020605 0.48 1.26 0.822 164.4 0.88 101.82 0.78 345.86 0.78 345.86 101.82 164.417 20020606 0.65 1.56 0.662 139.38 0.97 95.18 0.91 286.82 0.91 286.82 95.18 139.3817 20020607 0.43 0.94 0.316 120.32 0.6 73.1 0.51 201.99 0.51 201.78 72.89 120.1415 20020608 0.55 0.91 0.371 70.93 0.54 54.2 0.39 111.18 0.37 107.78 50.56 66.6314 20020609 0.59 1.14 0.346 105.44 0.74 84.57 0.63 236.35 0.55 231.57 79.19 92.2815 20020610 0.56 1.450.419 157.04 0.96 95.44 0.88 263.3 0.88 263.3 95.44 157.0415 20020611 0.7 1.72 0.63 144.73 1.13 92.93 1.02 264.36 1.02 264.36 92.93 144.7315 20020612 0.78 1.83 0.842 134.29 1.18 93.45 1.05 214.21 1.05 214.21 93.45 134.2912 20020613 0.48 1.250.492 162.03 0.88 97.25 0.77 326.79 0.77 326.79 97.25 162.0315 20020614 0.48 1.150.263 140.13 0.77 92.38 0.67 399.87 0.67 399.87 92.38 140.1318 20020615 0.55 0.98 0.594 77.74 0.61 77.95 0.43 217.1 0.43 217.1 77.95 77.7413 20020616 0.61 1.03 0.709 68.83 0.52 74.21 0.42 281.89 0.41 281.22 73.53 67.415 20020617 0.74 1.37 0.269 88.18 0.91 72.66 0.66 204.89 0.62 202.71 70.38 83.6916 20020618 0.78 1.36 0.621 75.98 0.7 72.31 0.59 245.48 0.57 244.35 71.12 73.317 20020619 0.93 1.44 0.8 56.76 0.63 62.05 0.53 243.46 0.51 239.92 57.97 54.7415 20020620 0.8 1.28 0.739 67.19 0.61 65.69 0.54 222.22 0.47 218.77 61.68 59.2716 20020621 0.93 1.45 0.74 62.2 0.69 64.39 0.58 140.54 0.52 136.61 59.8 55.6419 20020622 0.76 1.49 0.643 98.29 0.83 79.1 0.75 203.9 0.72 202.59 77.71 94.919 20020623 0.65 1.32 0.654 107.5 0.74 86.18 0.7 323.89 0.67 322.01 84.11 101.6919 20020624 0.71 1.54 0.771 117.1 0.88 97.51 0.83 346.88 0.82 346.53 97.16 11619 20020625 0.89 2.06 0.653 130.36 1.23 86.62 1.16 190.06 1.16 190.06 86.62 130.3617 20020626 0.92 1.91 0.612 115.57 1.17 90.08 1.06 251.66 0.99 248.67 86.76 108.4918 20020627 0.6 1.350.668 125.68 0.83 92.6 0.75 330.34 0.75 330.34 92.6 125.6818 20020628 0.61 1.3 0.667 111.86 0.77 83.89 0.69 232.59 0.69 232.59 83.89 111.8617 20020629 0.75 1.28 0.56 80.44 0.7 76.78 0.6 278.86 0.53 275.6 73 71.2517 20020630 1.05 1.38 0.883 48.72 0.55 59.19 0.51 142.97 0.33 135.94 51.53 31.5817 20020701 0.62 1.86 0.475 202.05 1.34 111.66 1.25 373.48 1.25 373.48 111.66 202.0518 20020702 0.93 2.2 0.287 135.54 1.46 87.31 1.26 268.7 1.26 268.7 87.31 135.5417 20020703 0.82 1.99 0.175 143.2 1.29 91.52 1.17 267.41 1.17 267.41 91.52 143.217 20020704 0.6 1.64 0.205 170.68 1.1 101.65 1.03 379.74 1.03 379.74 101.65 170.6814 20020705 0.3 1.22 0.215 303.13 0.97 122.02 0.92 379.62 0.92 379.62 122.02 303.1316 2002070620020707

20020708 20020709 20020710 0.42 1.1 0.496 159.96 0.73 95.93 0.68 227.4 0.68 227.4 95.93 159.9617 20020711 0.45 0.98 0.701 119.77 0.57 91.12 0.53 276.32 0.53 276.32 91.12 119.7718 20020712 0.75 1.41 0.845 87.13 0.69 75.68 0.65 185.69 0.65 185.69 75.68 87.1318 20020713 0.66 1.31 0.637 106.03 0.74 84.7 0.7 275.29 0.66 272.97 82.11 100.5118 20020714 0.76 1.32 0.557 81.3 0.69 68.35 0.62 161.3 0.56 157.91 64.38 73.8617 20020715 0.89 1.7 0.532 94.34 0.94 77.39 0.84 197.5 0.81 196.2 76.01 90.5217 20020716 0.6 1.39 0.651 133.37 0.84 95.82 0.8 303.8 0.8 303.8 95.82 133.3717 20020717 0.96 2.01 0.908 109.24 1.08 90.06 1.05 314.1 1.05 314.1 90.06 109.2416 20020718 0.78 1.950.607 149.33 1.23 97.4 1.17 293.19 1.17 293.19 97.4 149.3318 20020719 0.67 1.51 0.677 125.94 0.94 90.81 0.84 322.46 0.84 322.46 90.81 125.9417 20020720 0.5 1.04 0.524 106.88 0.61 80.6 0.54 223.85 0.54 223.85 80.6 106.8817 20020721 0.42 0.88 0.645 114.29 0.52 81.08 0.48 228.08 0.47 226.22 79.06 112.0417 20020722 0.47 1.44 0.827 209.64 1.04 114.18 0.98 397.24 0.98 397.24 114.18 209.6418 20020723 0.56 1.650.811 196.33 1.13 111.98 1.09 371.25 1.09 371.25 111.98 196.3317 20020724 0.42 1.150.562 173.78 0.8 99.93 0.73 428.75 0.73 428.75 99.93 173.7817 20020725 0.4 0.98 0.318 145.76 0.68 85.98 0.58 217.57 0.58 217.57 85.98 145.7616 20020726 0.45 1.08 0.61 143.63 0.78 86.27 0.64 205.61 0.63 200.64 80.07 141.6116 20020727 0.85 1.37 0.904 61.06 0.57 60.35 0.52 108.96 0.52 108.96 60.35 61.0615 20020728 0.93 1.41 0.86 53.48 0.56 61.27 0.5 202.73 0.48 200.86 59.24 51.3917 20020729 0.81 1.9 0.479 135.88 1.21 97.5 1.1 394.64 1.1 394.64 97.5 135.8817 20020730 0.68 1.89 0.021 178.68 1.3 101.03 1.21 309.22 1.21 309.22 101.03 178.6817 20020731 0.73 1.82 0.529 147.22 1.14 94.21 1.08 314.03 1.08 314.03 94.21 147.2216 20020801 1.02 2.04 0.563 106.63 1.18 86.7 1.09 275.79 1.02 273.32 84.05 100.415 20020802 1.01 1.850.731 98.87 1.11 93.97 1 355.27 0.84 352.01 90.4 83.4718 20020803 0.96 1.48 0.66 58.55 0.67 63.94 0.56 180.26 0.52 178.17 61.78 54.8119 20020804 1.88 1.58 0.87 68.97 3.1 63.81 1.3 137.8 -0.3 122.49 41.94 -15.9317 20020805 0.62 1.89 0.594 203.46 1.33 113.4 1.27 422.85 1.27 422.85 113.4 203.4619 20020806 0.25 0.96 0.554 287.45 0.74 131.2 0.71 666.56 0.71 666.56 131.2 287.4515 20020807 0.46 1.150.601 148.31 0.74 104.52 0.69 404.2 0.69 404.2 104.52 148.3116 20020808 0.67 1.46 0.618 116.07 0.84 89.14 0.78 312.8 0.78 312.8 89.14 116.0716 20020809 0.76 1.58 0.358 114.71 0.97 86.33 0.87 261.76 0.82 259.79 84.2 108.7716 20020810 0.77 1.46 0.42 95.95 0.81 74.34 0.73 172.72 0.7 170.24 71.59 90.7916 20020811 0.61 1.44 0.399 139.59 0.94 93.57 0.85 258.17 0.83 256.27 91.51 135.0617 20020812 0.88 1.93 0.699 118.27 1.15 85.21 1.05 212.47 1.05 212.47 85.21 118.271720020813 1.06 2.32 0.612 117.8 1.35 86.21 1.25 238.81 1.25 238.81 86.21 117.816

20020814 0.77 2.050.752 167.38 1.32 98.97 1.28 252.25 1.28 252.25 98.97 167.3817 20020815 0.47 1.64 0.576 252.94 1.26 119 1.18 428.49 1.18 428.49 119 252.9419 20020816 0.84 1.87 0.634 126.46 1.16 97.21 1.07 313.51 1.02 311.16 94.58 121.5218 20020817 0.82 1.8 0.418 125.2 1.1 88.67 1.03 259.74 0.97 256.64 85.14 117.9816 20020818 0.95 1.94 0.572 108.71 1.12 82.95 1.03 217.84 1 215.9 80.84 105.416 20020819 0.67 2 0.42 196.07 1.45 103.68 1.32 326.81 1.32 326.81 103.68 196.0717 20020820 0.69 1.88 0.369 176.78 1.29 104.48 1.21 353.44 1.2 352.16 103.12 174.0918 20020821 0.56 1.47 0.488 163.99 0.98 100.3 0.92 349.93 0.92 349.93 100.3 163.9917 20020822 0.68 1.88 0.431 175.79 1.34 98.6 1.2 284.46 1.2 284.46 98.6 175.7918 20020823 0.57 1.67 0.49 191.83 1.17 104.46 1.1 317.79 1.1 317.79 104.46 191.8316 20020824 0.65 1.450.676 123.7 0.88 86.32 0.8 212.81 0.8 212.81 86.32 123.715 20020825 0.7 1.4 0.392 99.53 0.79 75.22 0.7 170.84 0.7 170.84 75.22 99.5314 20020826 1.17 2.04 0.516 83.62 1.05 71.3 0.98 187.85 0.87 183.99 66.68 74.4217 20020827 0.99 2.050.597 109.87 1.16 83.63 1.09 274.61 1.05 273.23 82.16 106.3118 20020828 0.42 1.28 0.33 206.75 0.93 108.88 0.86 412.94 0.86 412.94 108.88 206.7517 20020829 0.52 1.46 0.454 178.52 1.09 101.27 0.93 328.74 0.93 328.74 101.27 178.5218 20020830 0.89 1.52 0.553 75.7 0.86 70.6 0.67 199.64 0.63 196.07 66.36 71.0718 20020831 0.83 1.21 0.475 67.61 0.66 69.84 0.56 223.56 0.38 212.46 56.92 45.8418obs avg, ppbCMAQ avg, ppbR^2 NME, % RMSE, ppbFE, % MAGE, ppbMNGE, % MB, ppbMNB, %MFB, % NMB, %N

0900190031 1.03 1.31 0.356 39.09 0.49 37.19 0.4 53.69 0.28 45.9 28.5 27.5288 0900310035 0.77 1.50.262 95.43 0.82 67.08 0.73 121.7 0.73 121.57 66.96 95.2566 0900990051 0.6 1.4 0.281 132.86 0.88 87.44 0.8 237.14 0.8 236.92 87.21 132.4285 1000310071 0.39 1.19 0.382 208.42 0.86 106.75 0.8 308.3 0.8 308.3 106.75 208.4288 1100100431 0.85 1.97 0.049 135.93 1.26 86.31 1.16 200.24 1.12 198.5 84.31 131.2388 2300520031 0.12 1.42 0.285 1060.77 1.37 168.08 1.3 1264.51 1.3 1264.51 168.08 1060.7776 2300901021 0.06 0.50.277 681.8 0.49 159.6 0.44 1076.47 0.44 1076.47 159.6 681.834 2303130021 0.44 1.38 0.491 216.54 1 107.67 0.94 319.13 0.94 319.13 107.67 216.5483 2400530011 1.05 1.89 0.282 81.21 0.97 62.5 0.85 111.56 0.83 110.76 61.67 79.3183 2500920061 0.6 1.28 0.31 116.47 0.79 74.26 0.7 136.63 0.68 135.08 72.38 113.9287 2500940041 0.32 1.050.226 233.04 0.89 107.1 0.74 352 0.73 349.66 104.37 229.9578 2501300081 0.54 1.31 0.328 143.63 0.85 86.57 0.77 191.92 0.77 191.63 86.26 142.8377 3301500131 0.29 1.18 0.241 304.71 0.96 121.09 0.89 384.8 0.89 384.8 121.09 304.7174 3400700031 1.09 1.73 0.344 59.2 0.76 47.16 0.65 70.88 0.64 70.29 46.55 58.285 3402100051 0.34 1.37 0.163 306.67 1.08 121.03 1.03 350.05 1.03 350.05 121.03 306.6788 3402300111 1.06 1.56 0.161 55.97 0.71 47.12 0.59 70.92 0.5 66.78 42.45 47.3785 3600500831 2.2 3.26 0.165 64.09 1.97 54.75 1.41 89.87 1.06 86.58 50.16 48.2186 4200100011 0.26 0.99 0.135 275.04 0.77 113.91 0.73 293.83 0.73 293.83 113.91 275.0475 5108700143 0.69 1.56 0.076 126.17 0.98 79.1 0.87 156.93 0.87 156.48 78.63 125.0338obs avg, ppbCMAQ avg, ppbR^2 NME, % RMSE, ppbFE, % MAGE, ppbMNGE, % MB, ppbMNB, %MFB, % NMB, %N

20020601 0.33 1.17 0.088 259.49 1.19 98.16 0.85 318.12 0.84 316.26 96.22 256.5415 20020602 0.19 0.7 0.137 279.59 0.83 92.48 0.52 328.35 0.52 325.2 88.91 276.9115 20020603 0.12 0.58 0.081 372.12 0.68 107.9 0.46 456.19 0.46 456.19 107.9 372.1216 20020604 0.12 0.49 0.011 313.25 0.58 98.26 0.38 475.54 0.37 469.56 90.39 302.6916 20020605 0.27 1.01 0.078 278.06 1 106.97 0.75 463.27 0.74 457.79 100.79 271.8716 20020606 0.16 0.81 0.39 406.34 0.94 125.11 0.65 575.08 0.65 573.81 123.78 404.4817 20020607 0.08 0.250.081 205.19 0.26 84.34 0.17 270.65 0.17 267.48 80.71 200.5716 20020608 0.12 0.33 0.109 200.42 0.35 85.64 0.25 322.06 0.21 304.71 62.69 169.515 20020609 0.25 0.83 0.158 232.23 0.73 100.42 0.58 370.59 0.58 369.47 99.26 230.7415 20020610 0.26 0.78 0.065 206.63 0.77 89.09 0.53 313.85 0.52 310.91 85.78 201.0915 20020611 0.37 1.36 0.228 269.19 1.56 95.25 1.01 375.01 0.99 371.75 91.58 264.114 20020612 0.29 1.18 0.475 309.47 1.1 122.73 0.89 482.86 0.89 482.86 122.73 309.4711 20020613 0.13 0.46 0.051 260.71 0.48 95.34 0.34 333.66 0.33 329.92 90.95 256.4316 20020614 0.11 0.4 0.011 271.23 0.44 95.57 0.3 447.34 0.3 447.34 95.57 271.2318 20020615 0.1 0.37 0.029 263.04 0.37 109.51 0.27 464.61 0.27 464.61 109.51 263.0414 20020616 0.19 0.59 0.151 219.93 0.63 91.51 0.41 299.88 0.4 292.9 82.27 212.2914 20020617 0.22 0.7 0.001 230.42 0.67 100.2 0.51 299.48 0.47 286.66 78.43 214.3716 20020618 0.26 0.650.041 164.24 0.64 85.63 0.42 250.11 0.4 237.06 64.97 153.9717 20020619 0.27 0.550.007 126.74 0.5 70.34 0.34 237.79 0.28 224.29 54.33 103.9915 20020620 0.35 0.62 0.041 114.68 0.56 79.9 0.4 286.28 0.27 258.53 42.9 78.5416 20020621 0.44 1.01 0.029 156.15 0.99 83.45 0.68 278.56 0.57 261.47 58.15 129.9119 20020622 0.4 1.05 0 179.21 1.03 86.47 0.71 405.32 0.66 396.8 75.12 166.419 20020623 0.48 1.1 0.124 154.96 1.04 89.81 0.74 365.46 0.62 354.17 72.97 130.2818 20020624 0.63 1.62 0.033 167.58 1.6 78.93 1.06 240.41 0.98 233.52 70.78 155.6919 20020625 0.7 1.87 0.035 189.9 1.83 93.67 1.33 307.75 1.17 289.86 70.51 166.8319 20020626 0.87 1.77 0.06 135.07 1.66 74.76 1.17 189.57 0.9 169.04 45.39 103.5119 20020627 0.59 1.46 0.244 163.64 1.41 81.28 0.97 242.95 0.87 233.5 68.49 146.2518 20020628 0.57 1.08 0.007 124.69 1 71.15 0.71 140.67 0.51 123.15 45.1 90.1318 20020629 0.83 1.12 0.034 101.96 1.12 74.81 0.84 198.31 0.29 159.01 16.44 35.5818 20020630 0.71 1.39 0.009 139.01 1.4 80.11 0.99 201.12 0.68 176.97 43.4 95.9418 20020701 0.8 2.02 0.151 162.39 1.72 84.39 1.3 268.83 1.22 263.95 78.82 152.5518 20020702 1.19 2.45 0.1 124.74 2.14 74.28 1.49 238.9 1.26 225.95 58.73 105.818 20020703 1.4 2.64 0 124.14 2.72 73.8 1.74 196.81 1.24 169.32 38.99 88.4218 20020704 1.57 2.44 0.095 93.33 2.4 62.57 1.47 121.9 0.86 99.22 32.45 54.8515 20020705 0.48 1.050.014 143.84 1.1 76.78 0.7 326.25 0.56 307.74 53.85 115.8716 2002070620020707

20020708 20020709 20020710 0.35 0.83 0.197 149.48 0.9 67.12 0.53 325.16 0.48 315.96 56.24 135.0917 20020711 0.28 0.68 0.022 152.2 0.62 74.05 0.43 202.15 0.39 194.1 65.18 140.118 20020712 0.39 0.89 0.22 156.44 0.89 73.99 0.62 230.62 0.49 210.41 47.91 125.3818 20020713 0.43 1.04 0.019 171.67 1.08 84.66 0.74 355.31 0.61 338.11 60 140.3917 20020714 0.41 0.91 0.001 158.21 0.93 88.45 0.65 263.22 0.5 244.67 62.26 121.5418 20020715 0.6 1.42 0.063 162.7 1.4 85.4 0.98 200.21 0.82 185.97 66.26 13618 20020716 0.56 1.38 0.297 164.25 1.61 71.85 0.92 212.22 0.83 194.71 50.64 148.2918 20020717 0.64 1.61 0.081 182.94 1.9 75.63 1.17 205.2 0.97 182.8 44.55 151.5917 20020718 0.82 1.99 0.007 172.85 2.07 79.3 1.41 315 1.17 295.99 55.14 14318 20020719 0.42 1 0.012 159.1 1.17 68.68 0.67 211.7 0.58 195.39 49.5 136.8118 20020720 0.43 0.950.019 169.37 1.15 82.72 0.73 292.05 0.52 252.35 28.31 121.8518 20020721 0.49 0.81 0.029 130.03 0.87 82.79 0.63 219.09 0.33 178.36 24.22 66.8817 20020722 0.63 1.7 0.011 193.5 1.71 87.73 1.21 362.79 1.08 350.25 71.25 171.9718 20020723 0.55 1.550.147 187.49 1.39 90.29 1.02 333.43 1.01 331.91 88.66 184.7217 20020724 0.35 0.51 0.065 104.35 0.47 74.72 0.36 151.45 0.16 115.75 26.8 46.717 20020725 0.29 0.50.397 128.71 0.51 82.03 0.37 260.47 0.21 222.87 29.81 72.0117 20020726 0.21 0.450.119 162.03 0.51 82.9 0.34 226.46 0.24 185.92 28.15 114.2917 20020727 0.27 0.69 0.027 158.83 0.68 68.85 0.43 200.05 0.42 197.36 65.8 154.8517 20020728 0.53 1.41 0.352 175.52 1.6 62.03 0.92 194.17 0.89 186.53 52.87 168.917 20020729 1.05 2.450.005 139.5 2.41 67.19 1.47 177.57 1.39 168.46 55.41 132.1717 20020730 1.02 2.150.133 111.47 1.72 65.93 1.14 164.08 1.13 163.77 65.62 110.818 20020731 1.11 2.33 0.003 128.58 2.58 65.5 1.42 210.76 1.23 198.36 51.01 110.9917 20020801 0.88 1.47 0.049 121.47 1.51 77.02 1.06 204.13 0.6 171.59 34.6 67.9216 20020802 0.64 1.72 0.132 191.08 1.9 75.98 1.22 237.61 1.08 217.81 50.4 168.319 20020803 0.79 1.64 0.029 151.82 1.76 78.75 1.19 198.31 0.85 159.11 24.37 108.3519 20020804 0.93 1.79 0 143.44 1.79 87.9 1.34 233.08 0.85 187.65 27.17 91.3318 20020805 0.75 2.07 0.126 175.28 1.75 87.57 1.32 258.87 1.32 257.45 86.04 174.8319 20020806 0.34 0.74 0.369 131.49 0.67 71.97 0.45 204.6 0.4 193.79 58.31 117.0417 20020807 0.38 0.88 0.006 136.11 0.71 77.48 0.52 242.56 0.49 239.28 73.63 128.2918 20020808 0.43 1.04 0.015 147.55 0.83 77.15 0.63 227.86 0.61 223.04 71.75 141.1416 20020809 0.48 1.1 0.068 162.78 1.07 81.77 0.78 261.88 0.62 239.46 51.3 129.1517 20020810 0.56 1.11 0 125.29 0.99 78.2 0.71 284.57 0.54 266.04 53.01 96.1216 20020811 0.58 1.44 0.025 193.88 1.72 85.78 1.12 360.1 0.87 333.66 48.72 150.7116 20020812 0.76 1.86 0.037 196.12 2.08 89.63 1.49 337.47 1.1 300.72 40.44 144.041720020813 0.99 2.09 0.01 160.18 2.26 84.65 1.59 275.03 1.09 237.6 34.95 110.316

20020814 0.95 1.76 0.018 145.99 2 83.45 1.39 239.48 0.8 199.66 28.33 84.0916 20020815 0.61 1.77 0 215.46 1.91 89.47 1.32 315.91 1.16 298.85 65.78 188.2319 20020816 0.62 1.58 0 189.39 1.85 84.54 1.17 294.29 0.96 273.07 56.94 154.7518 20020817 0.72 1.89 0.061 192.03 1.99 87.85 1.38 309.16 1.18 291.83 64.78 164.1916 20020818 0.92 1.99 0.03 147.77 2.09 75.47 1.36 252.65 1.07 227.33 38.73 116.5117 20020819 0.66 1.83 0.063 198.8 1.76 87.79 1.31 353.13 1.18 342.32 75.03 178.7117 20020820 0.42 0.9 0.506 134.54 0.82 81.69 0.57 308.44 0.48 293.15 62.28 114.8318 20020821 0.39 0.88 0.045 149.67 0.89 75.84 0.59 324.89 0.49 303.5 48.35 123.9117 20020822 0.41 1.39 0.234 240.95 1.45 88.85 0.98 336.91 0.98 334.86 86.6 240.5118 20020823 0.36 0.72 0.681 105.88 0.66 52.12 0.39 102.67 0.36 91.42 38.43 98.516 20020824 0.32 0.72 0.741 136.69 0.81 60.08 0.43 129.78 0.4 116.92 42.95 127.4516 20020825 0.49 0.99 0.192 125.49 1.03 67.26 0.62 145.62 0.5 123.18 39.14 100.9816 20020826 0.58 1.06 0.037 101.22 0.98 53.73 0.59 129.15 0.48 115.59 35.22 81.9917 20020827 0.52 1.31 0.149 166.01 1.24 77.86 0.87 294.63 0.79 283.26 63.66 150.2619 20020828 0.19 0.550.217 199.78 0.51 94.52 0.39 375.28 0.36 363.42 79.47 183.419 20020829 0.15 0.68 0.001 350.67 0.73 109.48 0.54 454.4 0.53 445.99 98.08 342.9419 20020830 0.3 0.51 0 103.54 0.41 69.74 0.31 170.92 0.2 148.72 40.95 67.6819 20020831 0.22 0.4 0 129.38 0.39 85.37 0.28 216.16 0.18 176.7 30.43 8219obs avg, ppbCMAQ avg, ppbR^2 NME, % RMSE, ppbFE, % MAGE, ppbMNGE, % MB, ppbMNB, %MFB, % NMB, %N

0900190031 0.57 0.46 0.541 38.6 0.3 45.37 0.22 42.97 -0.11 -8.41 -22.39 -18.9588 0900310035 0.41 0.53 0.588 52.42 0.29 46.5 0.21 72.76 0.12 56.85 25.86 29.8366 0900990051 0.56 0.98 0.454 83.63 0.69 60.71 0.47 120.63 0.41 113.69 52.69 73.0585 1000310071 0.34 3 0.561 788.81 3.18 159 2.66 999.36 2.66 999.36 159 788.8180 1100100431 0.42 1.43 0.342 236.75 1.14 108.55 1.01 279.83 1.01 279.83 108.55 236.7588 2300520031 0.28 0.41 0.28 80.79 0.32 73.28 0.23 196 0.13 173.11 43.42 45.1684 2300901021 0.27 0.29 0.55 40.06 0.14 48.83 0.11 103.97 0.01 83.12 22.84 4.9285 2303130021 0.48 0.62 0.665 47.36 0.32 49.65 0.23 107.89 0.13 94.04 33.21 27.0183 2400530011 0.53 0.73 0.272 52.2 0.36 43.8 0.27 62.74 0.2 53.06 30.75 38.4483 2500920061 0.83 0.63 0.635 38.15 0.49 44.89 0.32 55.84 -0.2 13.5 -10.02 -24.487 2500940041 0.53 2.36 0.722 341.66 2.29 136.84 1.82 594.33 1.82 594.33 136.84 341.6675 2501300081 0.85 0.42 0.286 59.15 0.66 76.79 0.5 67.08 -0.43 -20.19 -54.24 -50.6577 3301500131 0.88 1.23 0.762 47.2 0.56 43.88 0.41 79.22 0.36 75.57 39.82 40.5976 3400700031 0.18 1.99 0.411 1011.19 2 165.63 1.81 1140.69 1.81 1140.69 165.63 1011.1974 3402100051 0.25 0.750.349 203.5 0.56 102.53 0.5 283.85 0.5 283.85 102.53 203.588 3402300111 0.59 2.19 0.812 267.82 1.79 117.21 1.59 317.18 1.59 317.18 117.21 267.8285 3600500831 0.64 0.67 0.543 32.68 0.27 34.04 0.21 40.66 0.02 18.82 7.01 3.5686 4200100011 0.47 2.78 0.632 486.87 2.72 141.98 2.31 611.43 2.31 611.43 141.98 486.8773 5108700143 1 2.58 0.424 157.17 1.87 85.39 1.58 179.44 1.58 179.44 85.39 157.1738obs avg, ppbCMAQ avg, ppbR^2 NME, % RMSE, ppbFE, %MAGE, ppbMNGE, % MB, ppbMNB, %MFB, % NMB, %N

20020601 3.67 3.27 0.074 41.3 2.21 44.22 1.52 80.15 -0.4 49.34 4.65 -10.9216 20020607 1.8 1.1 0.048 42.77 1.12 46.54 0.77 36.22 -0.7 -26.57 -38.63 -38.7216 20020613 2.83 2.07 0.649 32.99 1.21 49.22 0.93 41.49 -0.76 -20.24 -35.59 -26.7417 20020619 2.51 2.89 0.28 34.1 1.24 41.65 0.86 132.47 0.38 116.59 23.13 15.0617 20020625 4.75 5.11 0.161 38.96 2.54 42.04 1.85 149.66 0.36 128.07 17.58 7.615 20020701 5.28 4.75 0.09 23.49 2.04 26.37 1.24 35.82 -0.53 8.11 -8.11 -10.0216 20020707 20020713 3.33 3.1 0.027 28.09 1.3 34.87 0.94 54.07 -0.23 24.25 -1.15 -6.8814 20020719 4.29 3.84 0.19 34.13 1.83 40.07 1.47 46.23 -0.45 4.24 -12.26 -10.5413 20020725 2.05 1.7 0.219 33.03 0.86 35.76 0.68 40.07 -0.35 1.24 -10.56 -16.9313 20020731 4.25 5.25 0.04 31.24 2 34.68 1.33 93.72 1 87.71 28.22 23.5313 20020806 2.3 2.32 0.693 18.47 0.47 19.43 0.42 19.96 0.03 3.73 1.28 1.1213 20020812 8.15 5.74 0.006 38.93 7.22 33.11 3.17 35.89 -2.41 0.14 -15.79 -29.5912 20020818 7.26 5.06 0.003 42.47 7.82 32.75 3.08 29.61 -2.19 -2.93 -13.94 -30.2312 20020824 5.11 2.58 0.431 59.87 8.17 53.25 3.06 77.54 -2.53 22.4 -21.47 -49.4814 20020830 1.79 1.56 0.116 28.7 0.63 33.33 0.51 31.51 -0.23 -6.43 -14.47 -12.9213obs avg, ppbCMAQ avg, ppbR^2 NME, % RMSE, ppbFE, % MAGE, ppbMNGE, % MB, ppbMNB, %MFB, % NMB, %N

2303130022 3.09 2.48 0.875 26.62 1.29 27.02 0.82 25.96 -0.62 -5.98 -10.91 -19.916 2500920063 2.57 2.350.385 40.07 1.32 54.74 1.03 93.84 -0.22 44.77 -11.1 -8.5915 2501300083 3.96 2.67 0.731 32.51 1.48 46.16 1.29 35.14 -1.29 -35.14 -46.16 -32.5114 3400700036 1.36 3.81 0.015 187.7 3.22 103.42 2.56 489.96 2.45 483.75 96.06 179.3210 3402300066 4.08 2.8 0.467 35.65 2.39 38.29 1.45 30.81 -1.28 -23.53 -31.62 -31.28 9 3402730016 5.27 2.84 0.859 46.17 2.83 65.94 2.43 47.99 -2.43 -47.99 -65.94 -46.17 8 3403900046 3.32 3.79 0.803 18.66 1.03 17.86 0.62 20.35 0.47 10.61 6.82 14.2214 3600500832 4.58 3.8 0.696 23.4 1.35 32.55 1.07 25.78 -0.78 -20.34 -27.77 -16.9915 3608101242 3.93 3.48 0.927 15.07 0.67 24.89 0.59 20.49 -0.45 -15.75 -20.46 -11.3913 4200300311 3.26 2.81 0.853 15.7 0.64 20.42 0.51 17.43 -0.45 -16.04 -19.07 -13.9415 4207100071 1.45 3.19 0.624 119.69 2.14 69.03 1.74 119.63 1.74 119.63 69.03 119.6914 4210100042 3.73 3.64 0.339 30.32 1.36 37.81 1.13 38.85 -0.09 4.91 -7.63 -2.4113 5105900302 3.97 4.02 0.951 7.7 0.4 9.44 0.31 9.85 0.05 2.27 1.48 1.3514 5105900304 4.28 4.26 0.913 10.83 0.68 11.4 0.46 11.74 -0.01 2.52 1.41 -0.2915 5108700142 4.98 4.28 0.82 17.78 1.18 18.21 0.89 16.25 -0.7 -13.18 -15.43 -14.0715 5108700144 1.86 3.82 0 140.59 3.16 85.85 2.61 211.38 1.97 199.89 71.96 105.9 6 5171000242 10.02 3.2 0.603 69.06 13.1 57.52 6.92 39.73 -6.82 -35.44 -53.69 -68.113 5171000244 3.17 2.57 0.847 20.87 0.77 27.98 0.66 23.61 -0.6 -21.18 -25.64 -18.8 9