AP-42 SectionIf•-7 

Referenoe 

 R rt Sect /~ 

Envisage Environmental Incorporated 

P.O. Box 152, Richfield, Ohio 44286 

Phone (216) 526-0990 

~ epo . 

REPORT NO. 9471 • Reference 

COMPANY M-E-'t] 

TITLE CoIhF.------- 

DATE 3-30 & 4-14- 94 

A-99-30 

7I- { -00'7 

METROPOLITAN CERAMICS INC. 

CANTON, OHIO 

TK1, TK2, TK3 EXHAUSTS 

PARTICULATE, SULFUR DIOXIDES, & FLUORIDES 

EMISSION EVALUATION 

CONDUCTED - MARCH 30 & APRIL 14, 1994 
SOURCE 

EVALUATION 

RESULTS 

PREPARED BY 

Envisage 

Environmental 

1 ncorporated 

P.O. Box 152 Richfield, Ohio 44286 

Phone (216) 526-0990 

IN 
Envisage Environmental Incorporated P one (216)2526-0990 Ohio 44286 

May 9, 1994 

Mr.Phillip McGuiness 

Metropolitan Ceramics Inc. 

1201 Millerton Road 

Canton, Ohio 44707 

Dear Mr. McGuiness: 

The following report is the result of the fluorides, sulphur dioxide, and 

particulate emission evaluation conducted March 30, and April 14, 1994 at the 

above facility. Three test runs each of the above was conducted at the TK1, 

TK2, and TK3 common exhaust for regulatory purposes. 

The results are true and accurate to the degree specified in the pertinent 

sections of the Code of Federal Regulations , in force at the time of the tests. 

I look forward to answering any questions you may have and assisting you in 

the future. 

Respectfully submitted, 

, 4' ~' 

Robert C. Hovan 

Air Quality Supervisor 

ENVISAGE ENVIRONMENTAL INC. 

P.O. Box 152 Richfield, Ohio 44286 Phone (216) 526-0990 Fax (216) 526-8555 

~ 


INTRODUCTION 

On March 30, 1994, Envisage Environmental Inc. conducted a particulate and 

fluoride emission evaluation and on April 14, 1994, continued the testing for 

Ifur dioxide emissions at the Metropolitan Ceramic Inc. facility, Canton, Ohio. 

Three (3) test runs for particulate, fluorides and sulfur ioxi e emissions were 

performed at the common exhaust serving the TK1, TK2, and TK3. Test 

parameters were in accordance with USEPA Reference Methods 1- 5, 6, and 

13.The kiln operations were monitored by Metropolitan Ceramic Inc. 

personnel throughout the duration of the testing program(s). 

The purpose of this evaluation was to determine the particulate, fluoride and 

sulfur dioxide emission rates from the above exhaust to determine compliance 

with OEPA regulations. The Envisage test teams consisted of Messrs. Greg 

Sinkovich, Terry Campbell, David Donelson and Jeff Belino on March 30, 1994 

and Messrs. Robert Hovan, Terry Campbell, and Clint Holley on April 14, 1994. 

The Canton Department of Air Pollution Control was represented by Mr. Rick 

Miller on both dates. Mr. Phillip McGuiness, Metropolitan Ceramic Inc., 

coordinated the tests. 

Results are presented in this report for particulate, fluorides and sulfur dioxide 

emissions as pounds/hour and the various velocity, volumetric, and 

temperature measurements associated with these tests. 

3 

_ Envisage 

- 

Environmental 

Incorporated 

-

P.O. 8ox 152 Hlohlield, OhiO 44266 

Phone (216) 526-0990 

5 

DESCRIPTION OF PROGRAM 

~

jhe emission test consisted of three (3) test runs at the common exhaust 

serving the TK1, TK2, TK3 for particulate, fluoride, and sulfur dioxide. Two 

5~p1" I sampling ports with twelve (12) sample points in each of the ports were utilized 

OCCLY for testing on March 30, and four (4) ports with six sample points were utilized 

for testing on April 14,1994. Sample time per point was two and one-half (2.5) 

~

minutes for the isokinetic sample . The total time per test run was sixty (60) 

minutes. 

._-- 

The particulate and fluoride samples were taken from the gas stream 

isokinetically through a five (5) foot pyrex lined probe and a guarter .25) inch 

nozzle. The entire length of the probe was heated and attached to a standard 

EPA Method 5 sample train. The hot box temperature was maintained 

between i225 and 273 degrees Fahrenhei Exit gas temperature of the 

r— 

1 impingers was maintained below 68 degrees Fahrenheit.with an ice bat The 

nozzle, probe and connecting glassware was cleaned before testing and at the 

conclusion of each test run with acetone. After the particulate analysis was 

completed, the filters and impinger solutions were sent to a laboratory for the 

fluoride evaluation. Leak checks of the pitot tube lines and the sample trains 

were all acceptable by EPA regulations. 

.~.._— 

The method 6 evaluation was conducted on the second date, due to a 

problem with accuracy on the audit evaluation on the first test date. The 

method 6 sample train utilized the following reagents; 100m1 of 80% IPA, 

100m1 of 3%H O~ , 100m1 of 3% H2 O„ and 200 grams of Silica Gel. Sampling 

was conducted at one sample point, with volumetric determinations 

~.. 

conducted before and after each test run. The average of these readings was 

utilized for the emission calculations. The analysis of the impinger solution was 

conducted by Barium-Thorin titration. An OEPA audit sample was analyzed 

prior to the test samples to assure quality control. 

~ Envisage 

Environmental 

— Incorporated 

-

P.O. Box 152 Rithtieltl, OhlO 44266 

PhOne (216) 526-0990 
Description cont. 

Flue gas analysis was conducted by drawing an integrated air_bag sample and 

analyzing it on a Hays Republic Model 621A "Orsat" Portabfe Gas Anayzer. 

The average of these readings for each run were used in calculating the 

emission rates. 

Calibration of the equipment used, including the dry gas meters, temperature 

measuring devices, orifice meters, and the "S" type p~ito,t tubes were conducted 

within 60 days of the test date. Copies of the data are included in this report. 

AII analytical procedures were performed in accordance with the methods 

specified in the Code of Federal Regulations, Title 40, Part 60, Volume 43. 

Blanks were collected and analyzed in the evaluation. The acetone blank was 

recorded and incorporated into the results. 

The example equations included in this report use the figures from Run # 1 on 

both dates. 

R 

® Envisage 

Envlronmental 

- Incorporated 

-

P.O. Box 152 Richfielo. Ohio 44286 

Phone (216) 526-0990 
TEST RESULTS 

SUMMARY 

_ Envisage - Envlronmental 

Incorporated 

-

P.O. Boz 152 Richiield, Ohio 44286 

Phone (216) 526-0990 

/v 
TEST RESULTS SUMMARY : 

Metropolitan Ceramics Inc. 

Canton, Ohio 

Particulate & Fluorides Emission Evaluation 

TK1, TK2, & TK3 Exhaust 

Conducted - March 30, 1994 

PARAMETER 

articulate Emissions 

Pounds/hour 

Grains/dscf 

Fluorides Emissions 

~ Pounds/hour 

Grains/dscf 

System Flow Rates 

~ ACFM 

~ DSCFM 

Degrees Fahrenheit 

Moisture Content rU' ~ ` . ' ( `x 

t _ 0 5 °ld 

RUN#1 RUN#2 RUN#3 

9.12 12.32 8.19 9-$ E 

0.0298 0.0316 0.0249 •t, ? 7. 

2.63 2.34 2.78 ~ 5 

8.60E-03 7.12E-03 8.43E-03 

53,215 56,750 56,701 

35,697 38,284 38,412 

273 274 271 

3.79 3.20 3.0 

- Envisage 

Environmental 

- Incorporated 

-

P.O. BOa 152 fiiohflelC. Ohio 44266 

Phone (216) 526-0990 
%~ 

11 TEST RESULTS 

Metropolitan Ceramics Inc. 

TK1, TK2, & TK3 Exhaust 

Particulate & Fluorides Emission Evaluation 

DATE: March 30, 1994 Symbol Units RUN # 1 RUN # 2 

Time of Day 1135 1322 

1240 1425 

1 Gas Volume-dry,std. Vmstd cu. ft. 39.64 41.63 

2 Condensate Vapor Vol. Vwstd cu. ft. 1.56 1.37 

3 Gas Stream Moisture Bws vol.dec 0.0379 0.0320 

4 Mo1.Wt-flue gas (dry) Msd lb/lb mo. 28.96 28.96 

5 Mol.Wt-flue gas (wet) Ms lb/lb mo. 28.54 28.61 

6 Flue Gas Velocity Vs ft/sec 45.17 48.17 

7 Flue Gas Volume-Actual ACFM cu. ft. 53,215 56,750 

8 Flue Gas Volume-Std. DSCFM cu. ft.. 35,697 38,284 

RUN # 3 

1506 

1612 

41.73 

1.33 

0.0309 

28.82 

28.49 

48.13 

56,701 

38,412 

9 Particulate Conc. Cs 

- Probe 

- Filter 

- Total 

- Fluorides 

10 Emission Rate E 

- Probe 

- Filter 

- Total 

- Fluorides 

~ 11 Isokinetic Rate I 

gr/dscf 0.0081 0.0186 0.0059 

gr/dscf 0.0217 0.0189 0.0190 

gr/dscf 0.0298 0.0376 0.0249 

gr/dscf 0.0086 0.0071 0.0084 

lb/hr 2.48 6.12 1:94 

lb/hr 6.65 6.20 6.26 

lb/hr 9.12 12.32 8.19 

lb/hr 2.63 2.34 2.78 

% 106.6 104.4 104.3 

S Envisage 

Environmental 

- Incorporated 

-

P.O. 9ox 152 Riahfieltl. OhiO 44266 

Phone (216) 526-0990 
TEST RESULTS 

Metropolitan Ceramics Inc. 

TK1, TK2, & TK3 Exhaust 

Sulfur Dioxide Emission Evaluation 

DATE: April 14, 1994 Symbol Units RUN # 1 

Time of Day 0955 

1055 

1 Gas Volume-dry,std. Vmstd cu. ft. 43.47 

2 Condensate Vapor Vol. Vwstd cu. ft. 1.69 

° ~~ 3 Gas Stream Moisture Bws vol.dec 0.0375 

4 Mol.Wt-flue gas (dry) Msd lb/lb mo. 28.91 

5 Mol.Wt-flue gas (wet) Ms lb/lb mo. 28.50 

~ 6 Flue Gas Velocity Vs ft/sec 48.71 

~ 7 Flue Gas Volume-Actual ACFM cu. ft. 57,385 

~ 8 Flue Gas Volume-Std. DSCFM cu. ft. '38,370 

9 Normality of Ba(C104)2 N meq/ml 0.0110 

10 Volume of solution Vsln ml 240.0 

11 Volume aliquot titrant Va ml 1.00 

12 Volume Ba(C104)2 Blank Vtb ml 0.0 

13 Volume Ba(C104)2 Sampl Vt ml 3.97 

14 Concentration S02 Cso2 lb/scf 1.70E-05 1 

15 Concentration S02 PPM ppmV 102.4 

L 16 Emission Rate S02 Eso2 lb/hr 39.20 

12 

RUN # 2 RUN # 3 

1122 1244 

1222 1344 

43.17 43.31 

1.56 1.63 

0.0349 0.0363 

28.90 28.91 

28.52 28.51 

49.53 49.87 

58,347 58,754 

38,659 38,827 

0.0110 0.0110 

240.0 231.0 

1.00 1.00 

0.0 0.0 

4.00 4.08 

.73E-05 1.69E-05 

103.9 101.8 

40.06 39.41 

_ Envisage 

Environmental 

- Incorporated 

-

P.O. Box 152 Rtohlielo, Ohio 44286 

Phone (216) 526-0990 
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OPERATIONAL PARANlETERS 

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Envisage 

Environmental 

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P.O. Box 152 RlchllelC, Ohio 44268 

Phone (216) 526-0990 
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~ SAMPLE POINT LOCATIONS 17 

Metropolitan Ceramics Incorporated 

Canton, Ohio 

TK1, TK2, and TK3 Common Exhaust 

Inside Diameter: 

* 60 inches 

* 

* 

* 

* 

1 * 2 * 1 1* 

2 4 6 8 10 12 

* 

* 

* 

* 

* * 

Point # ------- 

D lnsiaeeWaTQm ------------- 

Point # ------- D insaeeeWa ~ Qm ------------- 

1 58.1 inches 7 21.4 inches 

2 56.0 inches 8 15.0 inches 

3 52.9 inches 9 10.6 inches 

4 49.4 inches 10 7.1 inches 

5 45.0 inches 11 4.0 inches 

6 38.6 inches 12 1.3 inches 

_ Envisage 

- 

Environmental Incorporated 

-

P.O. Box 152 RIOh11elA, Ohio 44266 

Phone (216) 526-0990 

~~ 

EPA h1ETHOD 5 PARTICIJLATE 

SAMPLE TRAIN 

TEMPERATUAE SEiVSOA 

THEAMOMETER 

~ PITOT TUB THEAMOMETEA E '- ' HEATED AAEA I C-~ ECK FILTER HOLOEA 1 

STACK r ----- ----- -, ll VALVE 

TEMPERATURE wALL 

SE N50 R 

PA08E ~ •~ v -S1 L1CA GF L 

AEvERsF TYPE 

P1TOT TUBE ~ 

L-- -- , -J VACUUM LtNE 

PiTOT MANOMETEA THERMOMETEAS IMPINGFAS lCE BATH 

- 8Y•PASS VALVE 

OEi1FiCE 

MAIN 

VALVE 

ORY GAS METEA AIA•TTGHT 

PUMP 

19 

Me 
20 

J 

EPA METHOD 6 

SAMPLE-TRAIN 

TH ERMOMETER 

STACK WALL MIDGET tMPINGERS ~ PR08E (ENO PACXED Stl1CA GEL WITH QUARTZ OR MIDG'cT BUBBLER 

P1fREx WOOL) GLA55 WOOL DRYING TuBE 

~ \ ~ 

•..,: , , .,~, 

a ; ; °a. , ; e ~ . a i i' '• 

'? ; ~ ° ,~~~• 

ICE BATH " 

THERMOMETER / 

DRY 

GAS METER 

RATE METER NEEDLE VALVE 

~ 

~ PUMP 

~ 

SURGETANK 

M 

22 LABORATORY SUMMARY SHEET 

Metropolitan Ceramics Inc. 

TK1, TK2, & TK3 Exhaust 

Particulate & Fluorides Emission Evaluation 

DATE: March 30, 1994 Symbol Units RUN # 1 RUN # 2 

1 Sampling Time t minutes 60.0 60.0 

2 Barometric Pressure Pb in. Hg 29.02 29.02 

3 Static Pressure Pg in. H20 -0.71 -0.71 

Stack Pressure Ps in. Hg 28.97 28.97 

4 Gas Meter Volume Vm cu. ft. 43.73 45.15 

5 Stack Area A sq. ft. 19.63 19.63 

6 Nozzle Diameter Dn dec. in. 0.25 0.25 

7 "Y" Factor 1.00 1.00 

8 Meter Temperature degrees F 107.1 97.8 

Tm degrees R 567.1 557.8 

9 Stack Temperature degrees F 273.2 273.5 

10 Velocity Head 

11 Orifice Pressure 

~ 12 Carbon dioxide 

~ 13 Oxygen . 

14 Carbon monoxide 

15 Nitrogen 

16 Pitot Coefficien 

17 Water Collected 

18 Sample Weight: 

- Probe 

- Filter 

- Fluorides 

Ts degrees R 733.2 733.5 

^P in. H20 0.668 0.713 

^H' in. H20 1.50 1.67 

CO2 % 1.0 1.0 

02 % 20.0 20.0 

CO % 0.0 0.0 

N2 % 79.0 79.0 

t Cp 0.84 0.84 

Vlc ml 33.2 29.2 

Mn 

RUN#3 

60.0 

29.02 

-0.71 

28.97 

45.12 

19.63 

0.25 

1.00 

96.0 

556.0 

271.3 

731.3 

0.712 

1.67 

0.4 

19.0 

0.0 

80.6 

0.84 

28.3 

g 0.0208 0.0503 0.0159 

g 0.0558 0.0510 0.0514 

mg 22.1 19.2 22.8 

~ Envisage 

Environmental 

- Incorporated 

-

P.O. Box 152 RlGhlield, OhiO 44286 

PhOnB (216) 526-0990 
LABORATORY SUMMARY SHEET 23 

Metropolitan Ceramics Inc. 

TK1, TK2, & TK3 Exhaust 

Sulfur Dioxide Emission Evaluation 

DATE: April 14, 1994 Symbol Units RUN # 1 RUN # 2 RUN # 3 

1 Sampling Time t minutes 60.0 60.0 60.0 

2 Barometric Pressure Pb in. Hg 29.02 29.02 29.02 

3 Static Pressure Pg in. H20 -0.55 -0.55 -0.55 

Stack Pressure Ps in. Hg 28.98 28.98 28.98 

4 Gas Meter Volume Vm cu. ft.. 46.25 46.46 46.75 

5 Stack Area A sq. ft. 19.63 19.63 19.63 

6 Meter Temperature degrees F 87.4 93.5 95.3 

Tm degrees R 547.4 553.5 555.3 

7 Stack Temperature degrees F 276.1 284.9 285.7 

Ts degrees R 736.1 744.9 745.7 

8 Velocity Head ^P in. H20 0.719 0.727 0.731 

9 Orifice Pressure ^H in. H20 1.80 1.80 1.80 

'-,.,10 Carbon dioxide CO2 % 1.0 1.0 1.0 

~ 11 Oxygen 02 % 18.8 18.7 18.7 

12 Carbon monoxide CO % 0.0 0.0 0.0 

13 Nitrogen N2 % 80.2 80.3 80.3 

14 Pitot Coefficient Cp 0.84 0.84 0.84 

15 Water Collected Vlc ml 36.0 33.2 34.7 

_ Envisage 

Environmental 

- Incorporated 

-

P.O. f3ox 152 Rlchflel0. Ohlo 44266 

Phone (216) 526-0990 
PLANT Metropolitan Ceramic 

DATE March 30, 1994 

RUN N0. 1 

CASE N0. 16 

24 

CONTAINER 

NUMBER 

248 

N/A 

611 

WEIGHT OF PARTICULATE COLLECTED 

FINAL WEIGHT TARE WEIGHT WEIGHT GAIN 

0.6649 0.6091 0.0558 FILTER 

N/A N/A N/A IMPINGERS 

~ 

105.6688 105.6480 0.0208 PROBE 

Corrected for Acetone Blank 

VOLUME OF LIQUID WATER COLLECTED 

IMPINGER SILICA GEL 

VOLUME WEIGHT 

(ml) (9) 

FINAL 225 238.5 

INITIAL 200 230.3 

NET LIQUID COLLECTED 25 8.2 

TOTAL NET VOLUME 33.2 g ml 

* 

Convert weight of water to volume by dividing 

weight increase by density of water: 

_ Incr_ease g_ = Vol ume Water, ml _ Envisage 

- 

Environmental 

Incorporated 

-

P.O. BO: 152 Rlthlleltl. Ohio 44266 

Phone (216) 526-0990 
PLANT Metropolitan Ceramic 

DATE March 30, 1994 

RUN N0. 2 

CASE N0. 38 

25 

CONTAINER 

NUMBER 

254 

N/A 

99 

WEIGHT OF PARTICULATE COLLECTED 

FINAL WEIGHT TARE WEIGHT WEIGHT GAIN 

0.6590 0.6080 0.0510 FILTER 

N/A N/A N/A IMPINGERS 

A 

94.2642 94.2139 0.0503 PROBE 

Corrected for Acetone Blank 

VOLUME OF LIQUID WATER COLLECTED 

IMPINGER SILICA GEL 

VOLUME WEIGHT 

(ml) (g) 

FINAL 220 239.5 

INITIAL 200 230.3 

NET LIQUID COLLECTED 20 9.2 

TOTAL NET VOLUME 29.2 g ml 

* 

Convert weight of water to volume by dividing 

weight increase by density of water: 

_Incr_ease g_ _ Uolume Water, ml - Envisa e 

(1 g%ml ) 

~ 

Environmental 

_

Inoorporated 

P.O. Box 152 RlchlielG, Ohlo 44286 

 Phone(218)526-0990 
PLANT Metropolitan Ceramic 

901 

DATE March 30, 1994 

RUN N0. 3 

CASE N0. 29 

CONTAINER 

NUMBER 

246 

N/A 

71 

WEIGHT OF PARTICULAT 

FINAL WEIGHT TARE WEIGHT 

0.6628 0.6114 

N/A N/A 

101.9547 101.9388 

: COLLECTED 

WEIGHT GAIN 

0.0514 FILTER 

~ N/A IMPINGERS 

~ 

0.0159 PROBE 

* 

Corrected for Acetone Blank 

VOLUME OF LIQUID WATER COLLECTED 

IMPINGER SILICA GEL 

VOLUME WEIGHT 

(ml) (9) 

FINAL 220 238.6 

INITIAL 200 230.3 

NET LIQUID COLLECTED 20 8.3 

TOTAL NET VOLUME 28.3 g ml 

* 

Convert weight of water to volume by diViding 

weight increase by density of water: 

_ Incr_ease g = Vol ume Water, ml ~ Envlsage 

(1 g%ml j 

- 

Environmental 

Incorporated 

-

P.O. f3ox 152 Rlohfield. OhiO 44286 

PhOne(216)526-0990 

GkVI 
ORSAT A..NAI.YSIS WORS SHE.., ~T 27 

DATE: 

, . 

LOC.A.TiON; 

OP~A TOR ~ • 

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Envtr~ onrrmental 

lncorpora#ed 

` - ac. s. ,a ,..•ra a..as. 

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ORSA? A.NALYSIS WORS Si~,~~ I' 28 

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F.%--&n Environmental 

- Incorporated 

~

PG IM,Q 1irwNL d..AIn. 

~..~.~ 
Work Order # 94-04-102 Ross Analytical services, Inc Reported: 04/25/94 

29 

Sample Descsiptions Filter 0246 Lab No.: 01 

Analvte Descrintion Result Units E~L 

Fluoride anal. by EPA 13B <EQL Total mg 1.5 

samvle Descrivtion: Filter 1248 Lab No.: 02 

Analvte Description Result IInits EQ_L 

Fluoride anal. by EPA 13B <EQL Total mg 1.5 

samvle Descriotion: Filter #254 Lab No.: 03 

Analvte Descrintion Result IInits ZOL 

Fluoride anal. by EPA 13B <EQL Total mg 1.5 

samnle Descrivtion: Impinger Run# 1 Lab No.: 04 

Analvte Description Result IInits ROL 

Sample volume 225 Total mL 5 

Fluoride anal. by EPA 13B 22.1 Total mg 1.5 

samale Descrintion: Impinger Run# 2 Lab No.: 05 

Analvte Description Result IInits EL 

Sample volume 220 Total mL 5 

Fluoride anal. by EPA 13B 19.2 Total mq 1.5 

Samvle Descriotion: Impinger Run# 3 Lab No.: 06 

Analvte Descrivtion Result IIaits ZOL 

Sample volume 220 Total mL 5 

Fluoride anal. by EPA 13B 22.8 Total mg 1.5 

~~ 

CANTON CITY HEALTH DEPARTMENT 

DYVISION OF AIR POLLUTION CONTROL 

420 MARKET AVENUE NORTH ~ 

31 

CANTON, OHIO 44702 

FAX: (216) 489-3335 

1TELEFAX TRAIVSMII?'AL 

~/ - z ~_ q~ 

DATE; 

FOR THE ATTEZN3TION OF: r /R .4 ,AIK .9 6r Z o C / ` 

FIRM: e /yj11SO4 lf ` 

FAX NUMBER: /"- ~ ~ ~ — 1 ~ 

RE: ~ER",C 411z)ll, s"~s ~SD2~ 

This transmission consists of pages including this page. 

Please notify us if you do not receive all the pa;es at (216} 489-3385. 

I~/?~'!~ 

~~ c C oN~ E•vr~r~ rro~s REpoRrEa F ~ 

AND 

Tf1E ~cc-E0TA ~!'LE n'RNGE . 

3Y, 
AUDIT SAMPLE # 8823 

- --------------- ------- 32 Sulfur dioxide Concentration 

------------------------------ 

c ( Vt - Vtb ) N I_ -Vs a n- 

--------- 

 _I S02 = K2 ---------------------- -- - 

Vm(given) 

Nomenclature: (EPA Equation 6-2) 

CS02 = Concentration of sulfur dioxide in Audit sample, mg/dscm. 

K2 = Constant, 32.03 mg/meq. 

Vt = Volume of barium perchlorate titrant used for the sample, 

ml (average of replicate titrations). 

Vtb = Volume of barium perchlorate titrant used for the blank, ml. 

N = Normality of barium perchlorate titrant, milliequivalents/ml. 

Vsln = Volume of solution containing sulfur dioxide sample, ml. 

Va = Volume of aliquot titrated, ml. 

V m(given) = Volume of gas sample (given with.each audit.sample), dscm. 

Where: 

Vt = 2.03 ml V

sln = 

100.0 ml 

Vtb = 0.00 ml V a = 5.0 ml 

N = 0.0111 meq/ml V - m(given) 0.0210 M3 

_ - ( --?- 03 ----------O-oo--)-----

0 ~ 0111

-----I--_

100 . 0

C SO 32.03 --I- 5.0 

2 0.0210 

= 688.5 mg/dscm 

- Envisage 

Environmental 

- Incorporated 

_P.O. 8ox 152 Riohlieltl. Ohio 44286 

Phone (216) 526-0990 

/ 
AUDIT SAMPLE # 8947 

- --------------- ------- 33 

Sulfur dioxide Concentration 

------------------------------ 

C ( V t - Vtb) N — -Vsln- ~ a-- _I S02 = K2 ----- 

- 

- ---------------=-------- - --- 

Vm(given) 

Nomenclature: (EPA Equation 6-2) 

C S02 = Concentration of sulfur dioxide in Audit sample, mg/dscm. 

K2 = Constant, 32.03 mg/meq. 

Vt = Volume of barium perchlorate titrant used for the sample, 

ml (average of replicate titrations). 

V tb = Volume of barium perchlorate titrant used for the blank, ml. 

N = Normality of barium perchlorate titrant, milliequivalents/ml. 

V sln = 

Volume of solution containing sulfur dioxide sample, ml. 

Va = Volume of aliquot titrated, ml. 

V m(given) = Volume of gas sample (given with each audit.sample), dscm. 

Where: 

Vt = 4.93 ml V

sln = 

100.0 ml 

Vtb = 0.00 ml V a = 5.0 ml 

N = 0.0111 meq/ml Vm(given) 0.0210 M3 

( 4.93 - 0.00 ) 0.0111 

---5 . 0 _I CS0 = 32.03 -----------------------

0.0210

2 ------------ -_----------- 

= 1667.6 mg/dscm 

— Envisage 

Environmental 

— Inoorporated 

-

P.O. Box 152 filohfleld. Ohio 44266 

Phone (216) 526-0990 

Equ pment and Specifications 

Test Reference Methods 

Control Unit (meter box) 

Envisage Environmental Inc. 

XAndersen Samplers 

_ Remanufactured RAC 

_DuPont Constant Flow Pumps 

Sample Box 

XEEI 

_ Remanufactured RAC 

_EEISpecial Design 

Impingers - per sample train (each set changed for each test run) 

XEEI 

X EEI 

35 

Equipment Designation 

Control Unit #'s MB 08 & 09 

Control Unit #'s MB 01 - 02 

Control Unit #'s MB 03 - 07 

Control Unit #'s MB Ol - 05 

SB Ol, 02 & 05 - 07 

SB 03 & 04 

SBO8-11 

3 Modified Smith Greenburg type 

1 Smith Greenburo type 

Probes length lining type 

_EEI 2 foot SS, PYREX, QUARTZ 

_EEI 3 foot SS, PYREX, QUARTZ 

XEEI 5 foot SS, PYREX, QUARTZ 

_fiEI 7 foot SS, PYREX, QUARTZ 

_EEI 10 foot SS, PYREX, QUARTZ 

_EEI 12 foot SS, PYREX, QUARTZ 

_EEI 15 foot SS, PYREX, QUARTZ 

_EEI 24 foot SS, PYREX, QUARTZ 

Temperature Sensors Equipment Designation 

_Omega Engineering PY 01 & 02 

_Thermo Electric PY 03 - 08 

XFluke 51 PY Ol - 05 

_Fisher Scientific Mercury in Glass 

Fisher Scientific Bimetallic 

Pressure Gauges Type 

Oil, 0- 10 in. water 

Magnetic/Mechnical 0- 1 in. water 

Magnetic/Mechnical 0- 10 in. water 

Mercury, 36 inches 

Water, 72 inches 

Water, 0- 10 inches of water 

Electric, .001 - .100 in. water 

Deionized/Distilled 

Reagent Grade (<0.001% residual) 

6 - 16 Mesh 

Acetone insoluble & heat resistant 

Reagent Grade 

Reagent Grade 

Reagent Grade 

Reagent Grade 

Reagent Giade 

~ Envisage 

Environmental 

- Incorporated 

-

P.O. Box 152 Richlield, Ohio 44286 

Phone (216) 526-0990 

X Dwyer Incline Manometer 

_ Dwyer Magnehelic 

_ Dwyer MagneheHc 

_Dwyer "U"Tube Manometer 

_ Dwyer "U"Tube Manometer 

_ Dwyer Microtector (micro-tnanometer) 

Davis Electromanometer 

Chemicals and Reagents 

X Water 

X Acetone • Silica Gel 

• Stopcock Grease 

_ Nitric Acid 

_.1 N Sulfuric Acid 

_ Methylene Chloride 

_5% HNO3/ 10% H2O2 

_Sodium Hydroxide 

_IQ1iIN04/Sodium Hydroxide 
FIELD DATA SNEETS 

36 

_ Envisage - Environmental 

Incorporated 

-

PA. BOx 152 R1cMleltl, Ohio 44286 

Phone (216) 526-0990 
t ~ 

..Y .. 

FIELD DATA COVER SHEET 

PLANT ~C oR 4MrC S PROBE LENGTH ,~ / 37 

DATE yv,,.,t. °1 y NOZZLE I.D. J,' 

SAMPLING LOCATION ASSUMED MOISTURE z "?d 

M ETER BOX I. D. I(1 ~ 

SAMPLING METHOD j ~~ METER OH I-3 0 

OPERATOR J: e-* . METER "Y" FACTOR 

AMBIENT TEMPERATUR E ~'(~ NOMOGRAPH "C" FACTOR f, ~ 

~ BAROMETRIC PRESSURE 1'5t- 0 -2--- PROBE I.D. kL 

STATIC PRESSURE 71 THERMOCOUPLE I.D.'s -- 

HEATER BOX SETTING ' Zltq± ZS PITOT COR. FACTOR 

PROBE TEMP SETTING ZO±2.5 SAMPLE TRAIN I.D. I 

TRAVERSE POINT LOCATIONS CYCLONIC FLOW CHECK ~ ~C 

1. 7. 4 6 3 UPSTREAM DISTANCE 

2. 8. 5~ DOWNSTREAM DISTANCE 

3.q.5 9. S'ti,Z 

4.! ?-,l 10. b3-i 

5.15 11. (o?- ~- 

i 

6. 12. TO•S 

NOZZLE CALIBRATION 

Diameter 1 , zso 

Diameter 2 , z.5b 

Diameter 3. z5o 

Average . zS0 

Test Team Members-T- c -T b ~J t) C~ S 

EPA Representative/s a,ck *.,11vFacility Contact 1N%11~D 

EEI Team Leader G .S . 

FH394 

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PLANT tir-v ~.~r~cs 

- 

DATE q' I Y-4 `I 

SAMPLING LOCATION - 

SAMPLING METHOD ~ 

OPERATOR 4' 

AMBIENT TEMPERATURE 

BAROMETRIC PRESSURE 

STATIC PRESSURE -- SS 

HEATER BOX SETTING NIA' 

PROBE TEMP SETTING V/* 

TRAVERSE POINT LOCATIONS 

1. ~5 7. *0 3% •~ 

2. q•0 8. of 45:0 

3.1W 9. ift. L 

4. (04 10.** 5~ 1 

5.15. 0 11.*or Sv 

6. ?$ 4 12. frtgr M? 

PROBE LENGTH 41 

NOZZLE I.D. N14- 

ASSUMED MOISTURE 

METER BOX I.D. N~ 

METER AH / 9 Z 

METER "Y" FACTOR ~ 

li 

NOMOGRAPH "C" FACTOR zv/4- 

_ PROBE i.D. .. ~ 0 I 

THERMOCOUPLE I.D.'s s 

PITOT COR. FACTOR • $`f 

SAMPLE TRAIN I.D.A/ 

CYCLONIC FLOW CHECK 

UPSTREAM DISTANCE 

DOWNSTREAM DISTANCE 

NOZZLE CALIBRATION 

Diameter 1 ADiameter 2 

Diameter 3 

Average 

Test Team Members G~' f" rC 

fl .. . _ 11 _ " I 

EPA Representative/ 

Facility Contact , 

EEI Team Leader94- 

FH394 

~ 

~ 

~ 
c Ots6:0-S 

P.L.N* 1 CASEO LOCAMON 

.S-am'D' ow,-R as*..l M' el.er'. rinpinzeV. 

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post-Test 0-o -CF'Lvf @ _"Ha 

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:::.::::::.;::::..:;°.:,.::::: :::: :: ::;: ::;:: °::::: : : ' :Tn :: :; :'•>.Out:::: : 

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System Leak Checla: Pre CF12 @ "Hog 

Post-Test 0 CF'IvI @ _._8__"H? 
/ 

er 

' 

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~ 
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CALIBRATION SECTION 

49 

i Envisage 

~ 

Environmental 

Incorporated 

-

P.O. Boz 152 Rithfield. OhiO 44286 

PhOne(216)526-0990 

5:9-- 
DRY GAS METER CALIBRATION sa 

Using Wet Test Meter 

Meter Box Number MB 1A 65 deg F, Ambient Temp. 

Ca(ibration Date 3/18/94 28.28 "Hg, Baro. Press. 

Technician Krisak 

Dry Gas Meter 

Orifice Differential "H20 1.0 2.0 3.0 4.0 

Meter Temperature deg F 102.0 105.0 105.5 105.5 

Volume cu ft 7.300 14.175 26.500 28.195 

Wet Test Meter 

Orifice Differential "H20 -1.4 -2.1 -3.0 -4.0 

Volume cu ft 6.790 13.375 25.005 26.715 

Temperature deg F 66.0 65.5 65.0 65.0 

Time of Test minutes 11.75 17.00 26.25 24.50 

Totals 

Delta H@ .75 cfm 1.69 1.82 1.86 1.89 

Y Factor 0.991 1.009 1.009 1.010 

Dry Gas Meter MB 1A 

Average Delta H@ 1.82 

Average Y Factor 1.005 

CALCULATIONS 

Y = Vt " Pbar ' (Tm) 

Vm ' ( Pbar + (°H / 13.6) ] ' (Tmw) 

"H@ =.0317 " "H * Tmo ' min 

Pbar " (Tm) " Vw 

NOMENCLATURE 

Orifice Differentiat ="H Dry Gas Meter = sub m 

Temperature = T Wet Test Meter = sub w 

Votume = cu ft Barometric Pressure = Pbar 

Time of Test = min 

~ Envisage 

Environmental 

- Incorporated 

-

P.O. Box 152 Richfield, Ohio 44286 

Phone (276) 526-0990 
DRY GAS METER CALIBRATION 

Using Wet Test Meter 

51 

Meter Box Number MB 01 62 deg F, Ambient Temp. 

Calibration Date 4/1 /94 28.96 "Hg, Baro. Press. 

Technician Krisak 

Dry Gas Meter 

Orifice Differential °H20 

Meter Temperature deg F 

Volume cu ft 

Wet Test Meter 

1.0 2.0 3.0 4.0 

74.3 76.3 78.0 79.8 

6.430 9.050 17.555 14.830 

Orifice Differential -'H20 -1.5 -2.5 -3.5 -4.3 

Volume cu ff 6.274 8.765 16.850 14.105 

Temperature deg F 61.0 61.0 61.0 61.0 

Time of Test mfnutes 11.00 11.00 17.50 13.00 

Totals 

Delta H@ .75 cfm 1.73 1.77 1.81 1.90 

Y Factor 0.998 0.992 0.984 0.975 

Dry Gas Meter MB 01 

Average Delta H@ 1.80 

Average Y Factor 0.987 

CALCULATIONS 

Y = Vw ' Pbar ' (Tm) 

Vm ' [ Pbar + ("H / 13.6) ] ' (Tw) 

"H@ = .0317 ' "H * Tmo * min 

Pbar * (Tm) ' Vw 

NOMENCLATURE 

Orifice Differential ="H Dry Gas Meter = sub m 

Temperature = T Wet Test Meter = sub w 

Volume = cu ft Barometric Pressure = Pbar 

Time of Test = min 

_ Envlsage - Environmental • _Incorporated 

P.O. Boz 152 Richlleld, Ohio 44286 

Phone (216) 526-0990 
"S" TYPE PITOT TUBE CALIBRATION 

52 

"S" Type Pitot Tube (Probe) # 501 - 5 ft Probe 

Calibration Date: March 4, 1994 

/ 

^P 

/ std 

C C ------- 

p std / 

^P 

v p (EPA Equation 2-2) 

where: 

C = Coefficient of Type S pitot tube, dimensionless 

P 

C = Coefficient of Standard Pitot Tube (0.99), dimensionless 

std 

"P 

std 2 

= Velocity head measured by standard pitot tube, inches H 0 

^P = Velocity head measured by Type S pitot tube, inches H 0 

P 2 

^P ^P C 

std 

------------- 

p 

------------------- 

p 

--------------- 

Side A 0.23 0.32 0.839 

Side B 0.23 0.32 0.839 

Side A 0.41 0.56 0.847 

Side B 0.41 0.56 0.847 

Side A 0.82 1.14 0.840 

Side B 0.82 1.14 0.840 

Average - 0.84 

_ Envisage 

Environmental 

- Incorporated 

~ 

-

P.O. Box 152 Rithfieltl, Ohio 44266 

Phone (216) 526-0990 

.~ 
"S" TYPE PITOT TUBE CALIBRATION 53 

"S" Type Pitot Tube (Probe) # 303 - 3 ft Probe 

Calibration Date: March 4, 1994 

/ 

Ap 

/ std 

C = C ------- 

p std / 

^P 

v p ( EPA Equation 2-2) 

where: 

C = Coefficient of Type S pitot tube, dimensionless 

P 

C = Coefficient of Standard Pitot Tube (0.99), dimensionless 

std 

^P = Velocity head measured by standard pitot tube, inches H 0 

std 2 

^P = Velocity head measured by Type S pitot tube, inches H 0 

P 2 

^P ^P C 

std 

------------- 

p 

------------------- 

p 

--------------- 

Side A 0.27 0.38 0.834 

Side B 0.27 0.38 0.834 

Side A 0.44 0.61 0.841 

Side B 0.44 0.61 0.841 

Side A 0.78 1.06 0.849 

Side B 0.78 1.06 0.849 

Average - 0.84 

- Enrisage 

Environmental 

- Incorporated 

-

P.O. Box 152 Rlohfleld. Ohio 44286 

Phone (216) 526-0990 
ThermocouplelThermometer Calibration 

54 

Calibration Date: April 11, 1994 

Technician: Krisak 

Identification Low Reference Medium Reference High Reference Average 

Number Reading Reading Reading Deviation 

1 44 45 86 86 206 208 1.00 

2 42 42 89 89 209 209 0.00 

3 46 45 90 90 209 210 0.67 

4 44 44 91 91 208 209 0.33 

5 45 46 82 80 204 204 1.00 

6 46 45 92 92 205 205 0.33 

7 41 40 91 91 204 204 0.33 

8 40 41 89 89 204 204 0.33 

9 42 42 88 87 203 206 1.33 

10 44 44 87 87 202 202 0.00 

11 46 46 92 91 200 200 0.33 

12 48 47 91 91 200 200 0.33 

13 44 45 94 94 198 199 0.67 

14 42 42 96 96 198 200 0.67 

15 41 41 96 96 196 198 0.67 

16 40 40 96 96 196 195 0.33 

17 44 44 94 94 195 195 0.00 

18 44 44 95 95 195 195 0.00 

19 45 45 94 94 200 201 0.33 

20 42 42 94 94 201 202 0.33 

21 41 41 95 96 202 203 0.67 

~ Envlsage 

Environmental 

- Incorporated 

-

P.O. Box 152 RiChIiBIC. OhiO 44286 

Phone (216) 526-0990 

SAMPLING NOMENCLATURE 56 

A = Cross sectional area of stack or duct, ft?. 

A, = Cross sectional area of nozzle entry plane, ft?. 

k

g = Water vapor in gas stream, proportion by volume. 

C = Nomograph correction factor, dimensionless. 

CS = Concentration of particulate matter in gas stream, dry basis-corrected to 

standard conditions, gr/dscf. 

Dn = Nominal diameter of probe nozzle entry plane, in. 

E = Particulate Emission Rate, Ib./hr. 

"H = Average pressure differential across orifice, in. of H2 O. 

"H@= Orifice meter calibration factor, in. of H 2 O. 

I = Percent of isokinetic sampling, %. 

K, = Pitot tube constant, 85.49 ft./sec. 

Md = Molecular weight of gas, dry basis, Ib./Ib.-mole. 

N~ , = Total amount of particulate matter collected, g. 

Molecular weight of gas, wet basis, Ib./Ib.-mole. 

N~, = Molecular weight of water, 18 Ib./Ib.-mole. 

Pbar = Barometric pressure, in. of H9 . 

P9 = Pressure differential from gas stream to atmosphere, 

(static pressure) in. of H2 O. - Envisage 

Environmental 

_

- Incorporated 

P.O. Boz 152 Richfleltl, Ohio 44286 

Phone (216) 526-0990 
SAMPLING NOMENCLATURE - continued 57 

Ps = Absolute gas stream pressure, (Pbar + P9 /13.6) in. of H9 . 

Pstd = Absolute pressure at standard conditions, 29.92 in. of Hg . 

PPM = Parts per million 

P,, = Density of water, 0.0022 Ib./ml. 

"Pa„9= Average of the square roots of the velocity head readings, in. of H 2 0. 

Q = Volumetric flow rate at gas stream conditions, A.C. F. M. 

qtd= Dry volumetric gas flow rate corrected to standard conditions, D.S.C.F.M. 

R = Ideal gas constant, 21.85 in. of H9 -f~ /° R-Ib.-mole. 

t = Total sampling time, minutes. 

Tm = Average dry gas meter temperature, ° R. 

Tg = Average absolute gas stream temperature, ° R. 

Tstd = Standard absolute temperature, 528°rankine. 

VC = Volume of water collected in impingers and silica gel, ml. 

VOC = Volatile organic compounds 

Vm = Volume of gas sample measured at meter box (meter conditions), ft 3. 

Vm(Std) = Volume of gas sample measured at meter box (corrected to standard 

conditions), ft 3. 

Vs = Average gas stream velocity, ft./sec. 

Envisage 

Environmental 

Incorporated 

P.O. Box 152 Richlleld. Ohio 44266 

Phone (216) 526-0990 
SAMPLING NOMENCLATURE - continued 58 

V,(std) = Volume of water vapor in gas sample (standard conditions), ft 3. 

13.6 = Specific gravity of inercury (H9). 

%CO2 = Percent by volume of CO2 in gas stream (dry basis). 

%02 = Percent by volume of 02 in gas stream (dry basis). 

%CO = . Percent by volume of CO in gas stream (dry basis). 

%N2 = Percent by volume of N2 in gas stream (dry basis). 

_ Envisage 

- 

Environmental 

Incorporated 

-

P.O. Box 152 Richflelo. Ohio 44286 

Phone (216) 526-0990 
EMISSION SAMPLING 

CALCULATIONS 

W 

_ Envisage - Envlronmental 

Incorporated 

—

P.O. Boz 152 Riohfield, Ohio 44266 

Phone(216)526-0990 
1) Volume - of - dry - gas - sampled - through - meter - box - at - standard - conditions, 

^H 

- Tstd - V __ V -Pb ----- 13_6_ - 

m(std) m 

Tm P std 

(EPA Equation 5-1) 

Where• 

Um(std) Volume of gas sample meaiured at meter box (corrected to 

standard conditions), ft . 

Vm = Volume of gas simple measured at meter box (meter 

conditions), ft . 

Tstd = 

Standard absolute temperature, 528 0 Rankine. 

Tm = Average dry gas meter temperature, °R. 

P bar = 

garometric Pressure, in. Hg. 

^H = Average pressure differential across orifice, in. H 2 O. 

13.6 = Specific gravity of inercury (Hg). 

P std = 

Absolute pressure at standard conditions, 29.92 in. Hg. 

Example: Run 1 

V = 43.73 ft3 

m 

T = 567.1 ° R 

m 

^H = 1.50 in. H 2 0 

Pbar - 

29•02 in. Hg 

528.0 29.02 + 

-1.50- 

V = 43.73 ------- ----------------13= 6 - m(std) 567.1 29.92 

= 43.73 ( 0.9310 ) ( 0.9736 ) 

= 39.64 ft 3 

- Envlsage 

Environmental 

- Incorporated 

-

P.O. BOx 152 RiChfielA. OhiO 44286 

Phane (216) 526-0990 

Z1 
2) Volume 

-

of 

-

water 

-

vapor 

-

collected 

-

at 

-

standard 

-

conditions, 

----------------------------------------------- 

Vw(std) V lc 

P w ( R) ( T s t d ) 

Mw P std 

(EPA Equation 5-2) 

61 

Where: 

Vw(std) 

V lc 

Pw = 

Mw = 

R = 

Tstd 

P std 

Example: Run 1 

Vlc 

Vw(std) 

Volume of water vapor in gas sample (standard conditions) ft 3 . 

Volume of water collected in impingers & silica gel, ml. 

Density of water, 0.0022 lb/ml. 

Molecular weight of-water, 18 lb/lb-mole. 

Ideal gas constant, 21.85 in. Hg-ft 3/ o R-lb-mole. 

Standard absolute temperature, 528 o Rankine. 

Absolute pressure at standard conditions, 29.92 in. Hg. 

33.2 ml 

33.2 1-

0_0022- I I( - 21_85 - ) - ( -- 528 : 0 - ) 

18.0 29.92 

1.56 ft3 

_ Envisage - Environmental 

Incorp.orated 

-

P.O. Boz 152 Rlchlield. Ohio 44286 

Phane(216)526-0990 

4) Dry 

-

Molecular 

-

Weight 

-

of 

-

gas 

-

in 

-

gas 

-

stream, 

---------------------------------- 

63 

Md = 0.440 (%CO 2 ) + 0.320 (%0 2 ) + 0.280 (%N 2+ %CO) 

(EPA Equation 3-2) 

Where: 

Md = Molecular weight of gas, dry basis, lb/lb-mole. 

0.440 = Molecular weight of CO2 divided by 100. 

0.320 = Molecular weight of 02divided by 100. 

0.280 = Molecular weight of N 2or CO (same for both compounds) 

divided by 100. 

% CO2 = Percent by volume of CO2 in gas stream (dry basis). 

% 02 = Percent by volume of 02 in gas stream (dry basis). 

% CO = Percent by volume of CO in gas stream (dry basis). 

% N 2 = Percent by volume of N 2 in gas stream (dry basis). 

Example: Run 1 

% CO 2= 1.0 

% 02 = 20.0 

% CO = 0.0 

% N2 = 79.0 

Md = 0.440 ( 1.0 ) + 0.320 ( 20.0 ) + 0.280 ( 79.0 ) 

= 0.440 + 6.400 + 22.120 

= 28.96 lb/lb-mole 

- Envisage 

Environmental 

_- Incorporated 

P.O. Boa 152 Richfield, Ohio 44286 

Phone (216) 526-0990 

6) Average 

-

Gas 

-

Stream 

-

Velocity, ------------------------ 

65 

V= 

s 

T 

K C ^P - - s -- 

P p av9 P sMS 

\ (EPA Equation 2-9) 

Average gas stream velocity, ft/sec. 

)H__) /Z 1 Pitot tube constant, 85.49 - ft 

(1_b_/lb-mole(in.g 

sec I ( ° R}(in.H 0) I 

- 2 - 

Pitot tube coefficient, dimensionless. 

Average of th square roots of the velocity head 

readings, ( \~ ^p ) ( in.H2 O ). 

Average absolute gas stream temperature, ° R. 

Absolute gas stream pressure,(P bar + Pg/13.6) in.Hg. 

Barometric Pressure, in. Hg. 

Pressure differential from gas stream to atmosphere, 

(static pressure) in.H 2 O. 

Molecular weight of gas, wet basis, lb/lb-mole. 

Where: 

V s = 

Kp = 

C p = 

APavg 

Ts = 

P s 

P bar 

Pg = 

Ms = 

Example: Run 1 

C = 

P 

APavg 

T = 

s 

P s 

Ms = 

0.84 

0.668 in.H2 O

1/2 

733.2 ° R 

Pbar + Pg/13.6 = 29.02 

28.54 lb/lb-mole 

+ -0.71 /13.6 = 28.97 in.Hg 

V s = ( 85.49 )( 0.84 ) ( 0.668 ) 

I--=--=--=_733_2__--=--_-- 

\ ( 28.97 ) ( 28.54 ) 

= 45.17 ft/sec 

~ Envisage 

Environmental 

- Incorporated 

-

P.O. Box 152 RichlielE, Ohio 44266 

Phone (216) 526-0990 

8) Volumetric 

-

Flow 

-

Rate 

-

at 

-

Standard 

-

Conditions, 

------------------------------------_-- 

Q = 60 ( 1- B ) V A - Tstd - - --- 

P 

 Ps--- 67 sd ws s Ts std 

Where: (EPA Equation 2-10) 

Qsd = Dry volumetric gas flow rate corrected to standard 

conditions, S.C.F.M. 

60 = Conversion factor from seconds to minutes. 

Bws = Water vapor in gas stream, proportion by volume. 

V s = Average gas stream velocity, ft/sec. 

A = Cross sectional area of stack or duct, ft 2 . 

Tstd = 

Standard absolute temperature, 528 o Rankine. 

Ts = Average absolute gas s.tream temperature, o R. 

P s = Absolute gas stream pressure,(Pbar + Pg/13.6) in.Hg. 

P bar = 

Barometric Pressure, in. Hg. 

Pg = Pressure differential from gas stream to atmosphere, 

(static pressure) in.H 2 O. 

P std = 

Absolute pressure at standard conditions, 29.92 in. Hg. 

Example: Run 1 

B = 0.0379 

ws 

V s = 45.17 ft/sec 

A = 19.63 ft 2 

T = 733.2 o R 

s 

P s Pbar + Pg /13.6 = 29.02 + -0.71 /13.6 = 28.97 in.Hg 

Q = 60 ( 1 - 0.0379 ) ( 45.17 ) ( 19.63 )( _528_0 28_97 - 

sd 733.2 29.92 

= 35,697 SCFM 

- Envlsage 

Environmental 

- Incorporated 

-

P.O. Boz 152 Richfieltl. Ohio 44286 

Phone (216) 526-0990 


11) Percent 

------------------- -

of -Isokinetic - Sampling, 

------- _ 

~ 

100 T 

s 

K V+ 3 1 c 

--Vm-- — P 

+ 

 --- H - bar 70 I _ Tm 13 ..6 

---------------------60---An--- ~ S---PS---t-------

~

EPA Equation 5-7 Where: . 

I = Percent of Isokinetic sampling, %. 

T s = Average absolute gas stream temperature, o R. 

K3 = Constant, 0.002669 in.Hg-ft 3/ml- o R. 

V lc = Volume of water collected in impingers & silica gel, ml. 

Vm = Gas sample volume measured at meter box (meter conditions), ft3 . 

Tm = Average dry gas meter temperature, o R. 

Pbar = 

Barometric Pressure, in. Hg. 

^H = Average pressure differential across orifice, in. H 2 O. 

t = Total sampling time, minutes. 

V s = Average gas stream velocity, ft/sec. 

P s = Absolute gas stream pressure, in.Hg. 

D n = Nominal diameter of probe nozzle tip, inches. 

A = Cross sectional area of nozzle, ft 2 . n 

Example: Run 

-------- 

1 

Ts = 733.2 o R ^H = 1.50 in.H 2O 

V lc = 33.2 ml t = 60.0 min. 

Vm = 43.73 ft3 V s = 45.17 ft/sec 

Tm = 567.1 o R P s = 28.97 in.Hg 

An = 0.0003408 ft2 P

bar = 

29•02 in.Hg 

"Y" = 1.000 

I = 733.2 ( 100 ) 0.002669 ( 33.2 ) + I_I 7 — I_ 

29.02 + i356- 

------- 60 (0.0003408 - ) ---- ( -- 45.17 -- ) --- ( ---- 28.97 ) --- ( --- 60.0 -- ) --------- ~ -- 

= 106.6 % 

— Envisage 

Environmental 

— Incorporated 

-

P.O. Box 152 Riohlleld, Ohio 44286 

Phone(218)526-0990 


1) Volume 

-

of 

-

dry 

-

gas 

-

sampled 

-

through 

-

meter 

-

box 

-

at 

-

standard 

-

conditions, 

-------------------------------------------------------- 

^H 

V __ V - Tstd - - P b - + --- 13_6 -- 

m(std) m 

Tm Pstd 

Where: 

Vm(std) Volume of gas sample meaiured at meter box (corrected to 

standard conditions), ft . 

Vm = Volume of gas simple measured at meter box (meter 

conditions), ft . 

Tstd - 

Standard absolute temperature, 528 0 Rankine. 

Tm' = Average dry gas meter temperature, o R. 

Pbar = 

Barometric Pressure, in. Hg. 

^H = Average pr.essure differential across orifice, in. H 2 O. 

13.6 = Specific gravity of inercury (Hg). 

P std = 

Absolute pressure at standard conditions, 29.92 in. Hg. 

Example: Run 1 

73 

V = 46.25 ft3 

m 

T = 547.4 o R 

m 

^H = 1.80 in. H 2 0 

P bar = 

29•02 in. Hg 

528.0 

Vm(std) 46.25 

547.4 

= 43.47 ft 3 

29.02 + 

-1.80-- 

13.6 

29.92 

- Envisage 

Environmental 

- _

Inoorporated 

P.O. Box 152 Rlchfieltl. Ohio 44286 

Phone (216) 526-0990 


76 

4) Dry 

-

Molecular 

-

Weight 

-

of 

-

gas 

-

in 

-

gas 

-

stream, 

---------------------------------- 

Md = 0.440 (%CO2 ) + 0.320 (%0 2 ) + 0.280 (%N 2+ %CO) 

(EPA Equation 3-2) 

Where: 

Md = Molecular weight of gas, dry basis, lb/lb-mole. 

0.440 = Molecular weight of CO2 divided by 100. 

0.320 = Molecular weight of 02divided by 100. 

0.280 = Molecular weight of N 2or CO (same for both compounds) 

divided by 100. 

% CO2 = Percent by volume of CO2 in gas stream (dry basis). 

% 02 = Percent by volume of 02 in gas stream (dry basis). 

% CO = Percent by volume of CO in gas stream (dry basis). 

% N 2 = Percent by volume of N 2 in gas stream (dry basis). 

Example: Run 1 

% CO2= 1.0 

% 02 = 18.8 

% CO = 0.0 

% N 2 = 80.2 

Md = 0.440 ( 1.0 ) + 0.320 ( 18.8 ) + 0.280 ( 80.2 ) 

= 28.91 lb/lb-mole 

~ Envisage 

Environmentai 

- Incorporated 

_ P.O. f3ox 152 Richfield. Ohio 44286 

Phone (216) 526-0990 

6) Average 

-

Gas 

-

Stream 

-

Velocity, 

------------------------ 

: 

T 

V = K C ^P - -- s -- 

s p p avg P s Ms 

\ (EPA Equation 2-9) 

Where: 

V s = Average gas stream velocity, ft/sec. 

) _ ._g_) H 

p 

_ JZ 1 K = Pitot tube constant, 85.49 -

ft (1_b_/lb-mole(in_ 

sec I ( ° R)(in.H 0) I 

- 2 - 

C p = Pitot tube coefficient, dimensionless. 

^P = Average of th square roots of the velocity head 

avg reading-s, ( \~ ^p ) ( in.H 2O ). 

TS = Average absolute gas stream temperature, ° R. 

P s = Absolute gas stream pressure,(P bar + Pg/13.6) in.Hg. 

P bar = 

Barometric Pressure, in. Hg. 

Pg = Pressure differential from gas stream to atmosphere, 

(static pressure) in.H 2 O. 

Ms = Molecular weight of gas, wet basis, lb/lb-mole. 

Example: Run 1 

C = 0.84 

P 

^P avg = 0.719 in.H2 O

1/2 

T = 736.1 ° R 

s 

P s Pbar + Pg/13.6 = 29.02 + -0.55 /13.6 =. 28.98 in.Hg 

M = 

s 

28.50 lb/lb-mole 

------------------------- 

V = ( 85.49 )( 0.84 ) ( 0.719) _ _736.1 _ 

s )--- 

= 48.71 ft/sec 

_ Envisage 

Environmental 

_ Incorporated 

-

P.O. Box 152 Richfieltl, Ohio 44286 

Phone (216) 526-0990 

8) Volumetric 

-

Flow 

-

Rate 

-

at 

-

Standard 

-

Conditions, 

-------------------------------------- 

-- 

_ 

80 

Q = 60 ( 1- B ) V A _ T std - -- P s - _ 

sd ws s Ts Pstd 

Where: ' _ 

(EPA Equation 2-10) 

Qsd = Dry volumetric gas flow rate corrected to standard 

conditions, S.C.F.M. 

60 = Conversion factor from seconds to minutes. 

Bws = Water vapor in gas stream, proportion by volume. 

V s = Average gas stream velocity, ft/sec. 

A = Cross sectional area of stack or duct, ft. 2 

Tstd ° Standard absolute temperature, 528 o Rankine. 

T s = Average absolute gas stream temperature, o R. 

P s = Absolute gas stream pressure,(Pbar+ Pg/13.6) in.Hg. 

Pbar = 

Barometric Pressure, in. Hg. 

P g = Pressure differential from gas stream to atmosphere, 

(static pressure) in.H 2O. 

Pstd = 

Absolute pressure at standard conditions, 29.92 in. Hg. 

Example: Run 1 

B = 0.0375 

ws 

V s = 48.71 ft/sec 

A = 19.63 ft 2 

T = 736.1 oR 

s 

P s Pbar + Pg/13.6 = 29.02 + -0.55 /13.6 = 28.98 in.Hg 

Q = 60 ( 1- 0.0375 ) ( 48.710 ) ( 19.63 _528_0 28_98_ 

sd I 736.1 29.92 

= 38,369 SCFM 

Envisage 

Environmental 

Incorporated 

P.O. Box 152 RiOhlleld, OhiO 44286 

Phone (216) 526-0990 
9) Gas 

-

Stream 

-

Sulfur 

-

dioxide 

-

Concentration

= -

(lb/dscf), 

------------------------------------------- 

 — Vsln 

_ -- ( -Ut---V tb

- ) ---N-- ---- V C S02 K2 V --- a---=l -- 

m(std) (EPA Equation 6-2) Where: 

C SO = Concentration of sulfur dioxide, dry basis corrected to 

2 standard conditions, lb/dscf. 

K2 = Constant, 7.061 x 10 -5lb/meq. 

V t = Volume of barium perchlorate titrant used for the sample, 

ml (average of replicate titrations). 

Vtb = Volume of barium perchlorate titrant used for the blank, ml. 

N = Normality of barium perchlorate titrant, milliequivalents/ml. 

V sln = Total volume of solution in which the sulfur dioxide sample 

is contained, ml. 

V a = Volume of aliquot titrated, ml. 

Vm(std) Volume of gas sampl- e meaiured at meter box (corrected to 

standard conditions), ft . 

Example: Run 1 

V t = 4.0 ml 

V tb = 0.0 ml 

N = 0.0110 meq/ml 

240.0 ml Vsln = 

` V = 1.0 ml 

a 

43.47 ft3 Vm(std) 

-5 ( 4.0 - 0.0 ) 0.0110 240: 0

- 

= 7.061 x 10 ------------------------------------------------- 

CS02 43.47 

= 0.1703 x 10 -4lb/dscf 

--------------- 

_ Envisag• 

Environmental 

— Incorporated 

-

P.O. Boz 152 Rlchfield, Ohio 44266 

Phone (216) 526-0990 

. ~I 

r~ 

: 

11) Sulfur 

-

dioxide 

-

Emission 

-

Rate, 

------------------------- 

_ 60 

--

minutes 

- ---------- E S0 2 CS0 2 4 - sd - 1 hour 

Where: 

E SO = Sulfur Dioxide Emission Rate, lb/hr. 

2 

R sd = Dry volumetric gas flow rate corrected to standard 

conditions, S.C.F.M. 

C = Concentration of sulfur dioxide, dry basis corrected S02 to standard conditions, lb/dscf. 

Example: Run 1 

Q sd = 

38,369 SCFM 

C SO = 1.703E-05 lb/dscf 

2 

ESO = (1.703E-05 )( 38,369 ) ( 60 ) 

2 

= 39.19 lb/hr 

_ Envisage - Environmental 

Inoorporated 

-

P.O. Box 152 RlohlielG.Ohio 44286 

Phone (216) 526-0990 
1 ~l 

~ 

VISIBL.E EMISSION OBSERVATION FORNi 

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STACK TEST 

OBSERVATION REPORT 

METROPOLITAN INDUSTRIES 

15 76 05 1149 

P004, P005 & P006 

MARCH 30 & APRIL 14, 1994 

On March 30, 1994, George Long and I observed the stack testing of the present three tunnel kilns, all 

in operation and ducted to a common stack (150 foot stainless). The testing firm was Envisage 

Environmental. The representative from Envisage was Greg Sinkovich. I did the VE readings during 

the stack test, the final leak checks on the unit located on the stack platform about 75 feet above the 

ground and observed the sampling trains used. George observed the testing technique and the final leak 

checks on the SOZunit stationed on the ground at the base of the stack. 

Tunnel Kiln #1 (P004) and Tunnel Kiln #2 (P005) use a common dryer and therefore, process the same 

tile composite materials. They were being operated at a rate of 34 cars per day (each) and processing 

product 507, which is a 100% clay product. This calculates to 62.832 dry tons of product / kiln / day, 

concerning these two kilns. Tunnel Kiln #3 (P006) was being operated at a rate of 40 cars per day, and 

was processing product 310, which is a 30 % clay, 70 % shale composite. TK #3 was calculated as 

processing 73.92 dry tons of product / day. The total capacity during the stack test was at a rate 

equivalent to 199.584 tons / day, which is 90% rated capacity for the operation. Attached is 

confirmation from Metropolitan. It was explained previously at a meeting that the manufacturers rating 

for the kilns is 36 cars / day, which makes 108 cars / day the 100% capacity rating for the operation 

of all three kilns. However, 40 cars / day is the potential Metropolitan can push. Therefore, 108 cars 

/ day could be viewed as 90% potential capacity. q, ~~~ ~~~,~ : A G>~-J 

A Particulate Sampling - Observation Checkiist was completed. The stack test was for particulates, SO Z 

and fluorides (Method 1-5, Method 6 and Method 13A, respectively). Audit samples for SO Zwere 

given for analysis, C8613 & C8853. No problems were seen in the test methods. All leak checks were 

ok. The peak temperature in TK # 1 & #2 was 1190 °.K, and in TK #3 it was 1 150 °k+'. Copies of all raw 

data were collected at the time of the testing. ? 

Audit sample results from Envisage indicated that their results could not be accepted for the SO Zportion 

of the stack test. Therefore, the S0 2portion of the stack test (Method 6) had to be repeated on April 

14, 1994. All operation parameters for the April 14th test were the same as that of the March 30th test. 

Audit samples for SOZwere again given (C8947 & C8823). This time, the results came back within 

an acceptable range. The Envisage rep. during the April 14th test was Bob Hovan. The tile samples 

collected by Metropolitan during the last stack test were to be sent out for sulfur analysis. 

The April 14th testing was observed by myself. I did the VE readings on emissions from the 

lvletropolitan stack and final leak checks on the Envisage equipment. The weather conditions were 

better than that of March, and a steady flow of low emissions was very evident. Once again, raw data 

was collected at the time of testing. This data was collected by Philip McGuinness of Metropolitan and 

copies made available the following day. Dan Aleman of our office received them. 

Rick L. Miller 

Staff Field Inspector 

ii am 
Envisage Environmental Incorporated 

I► ~ II!{ 

FEB 2 41994 

.s~~ T} ~ ! 

EALTH LE. 

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February 23, 1994 

Mr. Andy Pasko 

Canton City Health Department 

Air Pollution Control 

420 Market Avenue N. 

Canton, Ohio 44702 

Dear Mr. Pasko: 

I am enclosing your copy of the Intent to Test Notification for testing of the 

TKi, TK2, and TK3 Common Exhaust at th~ tr ~ = ar ~n ~facility, 

Canton, Ohio. Please review for accuracy of information. 

One copy has been sent to Mr. Phillip McGuiness, Metropolitan Ceramics; 

and one copy has been retained for our files. If there are any changes 

please notify us as soon as possible. 

Questions may be directed to Mr. Frank Hezoucky or myself. 

Sincerely, 

Robert S'

H ovan 

Air Quality Supervisor 

ENVISAGE ENVIRONMENTAL INC. 

Enclosure 

P.O. Box 152 Richiield, Ohio 44286 Phone (216) 526-0990 Fax (216) 526-8555 ~ 

~ 
1 

07:09:51 0104 01 MALONE COL 04/14/94 

01 02 03 04 05 06 

CHAN S02 WD WS TEMP 1 TEMP 2 03 SD1 

UNITS PPM DEGR MPH DEG C DEG C PPM DEG 

FSCL .473 540 50.0 50.0 50.0 .471 99.9 

ZERO -.024 0 0.0 0.0 -30.0 -.024 00.0 

------------------------------------------------***** ----------------------------------------------- 

01:00 0.001 248 11.7 23.4 7.1 0.033 10.7 

02:00 0.001 251 10.6 23.6 6.5 0.032 9.8 

03:00 0.001 245 9.4 23.6 5.9 0.031 9.2 

04:00 0.001 254 13.4 23.4 6.8 0.037 10.6 

05:00 0.001 241 10.1 23.4 6.9 0.036 11.8 

06:00 0.004 229 7.9 23.6 7.0 0.028 14.3 

07:00 0.005< 225< 8.0< 23.7< 7.3< 0.021< 14.7 

08:00 0.005 226 8.6 23.9 8.9 0.027 15.8 

09:00 0.003 216 9.3 24.1 10.2 0.036 15.7 

10:00 0.003 200 7.3 24.4 11.9 0.037 18.6 

11:00 0.003 185 7.3 25.2 13.4 0.041 19.9 

12:00 0.010 184 8.3 26.1 14.5 0.042 16.9 

13:00 0.022 201 9.2 27.1 16.2 0.042 22.1 

14:00 0.016 212 10.4 27.4 18.6 0.050 18.6 

15:00 0.013 241 10.3 27.3 20.5 0.056 19.4 

16:00 0.007 253 14.7 27.3 21.0 0.061 15.7 

17:00 0.005 262 12.3 27.2 21.2 0.062 13.9 

18:00 0.003 269 10.0 27.2 21.1 0.065A 13.1 

19:00 0.003 254 7.1 27.2 20.3 0.056 10.7 

20:00 0.005 272 2.6 27.2 19.0 0.018 30.9 

21:00 0.003 109 1.2 27.2 18.3 0.031 26.2 

22:00 0.006 116 4.2 27.4 17.1 0.004 7.1 

23:00 0.008 183 5.7 27.0 17.1 0.024 8.7 

24:00 0.012 198 6.8 27.2 17.0 0.021 8.8 

DLYAV 0.006 ------ 8.6 25.6 13.9 0.037 

CALIBRATION RESULTS 

NONE CONDUCTED 

~~1 
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F1ELD DATA COVER SHEET 

PLANT ~&v 

DATE q- N--~ `I 

SAMPLING LOCATION 

SAMPLING METHOD ~ 

OPERATOR 

AMBIENT TEMPERATURE 

BAROMETRIC PRESSURE 

STATIC PRESSURE = 9S 

HEATER BOX SETTING NIA' 

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Test Team Members G 1~ 'f C 

PROBE LEN'GTH , ~ 77 

NOZZtE I.D. 4114- 

ASSUMED MOISTURE .4111t' 

METEA BOX I.D. /✓c--' 

M ETER A H /$ Z 

METER "Y" FACTOR ~ 

NOMOGRAPH "C" FACTOR ,,'/4- 

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Average 

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Date: 

Observ 

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Source: 

Test Fi ri 

sampling locations meet 

ati-on (s) modified to 

y 

. 

Sampling - Observation Checklist 

Sampling Method(s): 

RM 5 13; 53; 5B E3; 5D E3; 5E E3; 5F C3; 8 t3; 12 E3; 17 C3; 

or other ( I f other, , p 1 ease descri be. ) /GJt` 

Are there anY r+odi f i cati ons to the speci f i ed ref erence methoti ( s)? 

Yes CJ; No Cy~ (If yes, please describe modification.) 

Do the inlet (if applicable) and outlet 

the requirement s specified in RM 1? 

Yes E3; No E3 (If n.o}ow was (were th 

allow sampling?) /~✓~ ~~l o~~~~`1'4 

If inlet/outlet sampling is being performed, are the samples 

befng taken simultaneously? 

Yes 13; No E3 (If no, be sure that the source operating 

parameters are the same vjhen they switch trom one to the other.) 

If cycionic flow is present and other sampling.locations do not 

exist, how will the samples be withdrawn? ~ 

Di recti onal probe techni q ~~ e C 7; Ai i gnment techni que G7 ; other C 3 

(If other, please describe.) 

Is the sampling trafn set up properly, in accordance with the 

reference method or as agreed upon in the pre-test meeting? 

Yes C3; No E3 (If no, correct problems and continue, if 

possible.) . 

ChecE: to ensure.that the sampling equipment has been recently 

cal ibr3ted ( i. e. ,/theter bo:: , therm met rs/therm coupl es, pitot / 

tubes, etc. ) Of ~: 4Yj , not DK C 3 3~~/`~'~ iir 

Type of filter: / 

Is the fflter assembly positioned properly? 

Yes C3; No E3 (If no, adjust and continue, if possible. Please 

note that the filter may be ch.anged during the test run; however, 

it is recommended that the entire filter assembly be changed.) 

m 
„_•; 

Nozzle Diameter: 

(Please note that the nozzle may not be changed during the test 

run.) 

Number of sampling points on a traverse: 

Sampling time per point: 

Type of probe: (quart" ainless stee] ; water jact:eted, etc. ) 

Type of probe liner (if applicabie) : 

Impinger contents: 

First - 

Second - 

Third - 

Fourth 

Modifications 

Will the stacF: moisture content be determined as part of •P.M 5? 

Yes C 7; No C] ( I f no, pl ease descri bei~ he procedure for the 

separate moisture determination.) ~ 

Gas analysis: 

Orsat C7a Fyrit 1 7; Grab C7; other C] (If other, please 

describe. ) 

--, 

Indicate probe and filter iqq> temperature settings: 

Probe (if applic-able) - /U~ 

Filter box - 

(If on, have probe checked to'ensure it is heating properiy.) 

Reminder: When conduct3ng tests on boilers, the probe and filter 

box temperatures may not exceed 320 degrees Fahrenheit 

Ensure that the sampiing por is fare) sealed around the 

probe(s) when sampling. OK E(•; not Ofk C7 

Chect: and note color and conditfon of sflica gel: 

'

0! ?, -&( 

Leak-checf:s: 

Pre-test (optional) - cfm Cd "Hg 

s'v,, Post-test (mandatory) - O 0 cfm @ "Hg 

(The post-test leak-checi; must be conducted at 'or above the 

highest vacuum reading encountered during the test run. The leak 

checE: should be conducted by plugging the inlet to the probe 

noZ..le. The maximum acceptable leakage rate for a leak-check is 

.02 Cfm (.0057 cmm) or 4% of the average sampling rate, whichever 

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Particulate Sampling - Observation Checklist 

Date: 

Observ , 

Facili - Source 

Test F 

Samp 1 i n~ hlethod ( s): 

FM 5 CYJ; 5A 13; 5B C3; 

or other 13 (If other, 

SD 13; 5E 13; 5F C3; 8 C3; 12 C3; 17 C3; 

please describe. )/-, c} /g ~ 

hreth~ re any modifications to the specified reference method(s)? 

Yes CV~J /; No L. (?f yes, please describe modi` f' i/cation.) 

—~ /GtG ~a . l /~f~ /Y t✓~ ~/ ~~ G'4hs?6 ~h ~.,i' le CL 

Do the inlet (if applicable) 

the requirements specified in 

Yes :.; No C 7 ( I f ow wa s 

allow sampling?) — - 

If inlet/outlet sampling is being performed, are the samples 

beinq taken simultaneously? 

Yes C 3; No 11 ( If nb. besure that the =_ource operating 

parameters are the same vwhen they switch r'rom one to the oti -her. ) 

4i 

If cyclonic flow is present and other sampling locations do not 

exast, how will the =_amples be withdrawn? 

Directional probe tDchnique 13; rlliqnment technique CZ .-other C3 

(If other, please describe.) 

Is the sampling train set up properly, in accordance with tt-+e ' 

~ refer5ece method or as aqreed upon in the pre-test meetinq? 

Yes C J; No C3 (If no, correct problems and continue, if 

p o s s i b 1 e . > ~ Pi~ !M~ /.[ er- ~ ~, ~ ,!"'f ~w ~+~ /~ Ja~f.~ e~ 6 ~~ ~ 

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\ '~ ~> 

Checi; to ensure that the sampling equipment has been recently 

cal ibrated ( i. e. , ~ter bo;; , thermometers/th ~ ermocoupl es, ~p tot 

tubes, etc. ) OK L J; not OK 13 ~/iir C, cj Wa-y~ - ~e~t 

Type of f i 1 ter : 

Is the/+ ilter assembly positioned properly? 

~ Yes CP1; No 13 (Ir" no, adjust and continue, if possible. Flease 

note that the filter ma v be chanqed during the test run; . . however, 

it is recommended that the entire filter assembly be changed.) 

/a0'q_ 
~ Nozzle Diameter: 

(Please note that 

run.) 

the nozzle may not be changed during the test 

Number of sampl i ng poi nts on atraverse: 

Sampling time per point: ..S 

~ Type of probe: %quartz. stainless steel water jac(;eted, etc. ) 

Type of probe li

2wC

e

? 

r(if applicable): 

Impinger contents: S f 

First - Odn~ 

Second - 

Third - e:~ 

Fourth - v C 

Modifications - 

~ 

/ o cd 

iv / 7 h' 

Wi11 tpr e stacfs moisture content be determined as part of 

~ Yes C✓J: No 17 (If no, please describe the procedure for 

separate moisture determination,) 

RM 5? 

the 

Gas anal is: 

4 Orsat C ~J; Fyrite 17; Grab C7; other CJ (If other, please 

describe.) 

Indicate probe and filter oo:; tempe_rature settings: 

~ Frobe (if applic-able) 

Filter bo:: - ,'~ c/AC 

(If on, have probe checl:ed to ensure it is heating properly.) 

Reminder: When conductinq tests on boilers, the probe and filter 

box temperatures may not e::ceed 3,20 degrees Fahrent-heit 

ol Ensure that the sampling port^) is (are) sealed around the 

probe(s) when sampling. Ok: 114, not OK C] 

Che ; and note color and condition of silica gel: F ~/r~• ~ 

1 

'(,. 

Leak-checks: 

/ P~ p~=test .( .S~y, > - ~d/ ~ .~~ cfm id l.~ ~~ //'s_ "Hg 

~N~~Post-test (mandatory) cfm Hg 

(The post-test leaF:-checl; must be conducted at or above the 

highest vacuum reading encountered during the test run. The leak 

checE; should be conducted by plugging the inlet to the probe 

nozzle. The maximum acceptable lea{:age rate for a leak-checF: is 

.02 cfm (.0057 cmm) or 4% of the average sampling rate, ,whichever 

/ Q~~ 
is less. If the sampling was stopped during the test run to 

change a sampling train component, be sure the sampling train is 

leaEc-checEced again. ) 

F'eriodically record readings from the test firm's raw data 

sheet(s) (i.e., delta H, delta F, initiai Cas volume, filter 

numbers, filter box temperatures, etc.). Or photocopies of the 

raw data sheets may be requested from the test firm. (Attach the 

readings and/or photocopies to this chectclist.) 

Check to ensure that the sample train recovery procedures are 

conducted properly ( i. e. , f i i ter handl ing, probe wast -h, 1 iqui d 

transfers, appropriate sample recovery solution(s), recovery of 

nozzel catch, etc.). 

(+lill there be additional sampling and/or analyses performed 

(i.e., particle size distributions, bacl:-half analysis. HC1 

analys , metals anaiysis, etc.)? 

Yes CO; t+10 ] (ir' yes please describe. ) ..Gf~ifo~ ~ ctbi• ~~. d' 

w /3 A- ~ /tcAlp r i.4'f 

Optional checEcs/verifications: 

The test firm may be asked to do a ten (iv) minute run on their 

dry gas meter for calibration verification. Operate the meter at 

the delta H setting obtained from the test firm's calibration 

sheet. Record the volume collected, the dry gas meter 

temperatt_tre and the barometric pressure. Calcuiate a dry gas 

meter calibration check value, Yc, as follows: 

'Yc = 10 C0.0319 * Tm31/2 

tlm Fb ar 

Where: 

Yc = dry gas meter calibration check value (dimensionless) 

10 = ten minute verification run 

Compare the Yc value with the dry gas meter calibration factor Y 

to determine that: 0.97 Y<; Yc <; 1.03 Y. If the Yc value is not 

within this range the meter should be recalibrated and if 

compieted the run and/or test should be voided. 

The test r'irm may be required to perform at least one actual 

moisture determination. (This chect; shouid be performed ar'ter 

the first run. ) 

Measure or have the test firm remeasure the nozzle diameter to 

verify it's calibration. (This should be performed for each 

nozzle utilized.) 

ia~ 
Source operating conditions - Compliance demonstation checklist 

Source operating rate(s) (i.e., total heat input. feed rate(s), 

steam loaoi s ~+ charpp e rates, etc. ): s~~- c~~,~s„~'~ 

~FYJ1 e~-O ,A3 J / fl 

F'eriodically chec}: and record the operating rate(s) during the 

test period. 

Tot31 heat input determined by: F Factor C J: coal scales E] 

Date of coal scale calibration: 

F'rocess weight rate: 

For incinerators, indicate the operating temperature(s) and 

retention time(s) (if E:nown) : 

Did the source perform sootblowing, ash pulling, ESF' plate 

rapping or fabric filter cleaning during any of the test runs? 

Yes CJ; No 17 (If yes, please indicate activity and time 

interval(s).) 

Indicate the type(s) - of continuous monitor(s) utilized by the 

source being_ tested: 

Opaci ty C]; S02 C]; NO-c C]; CO C].; 02 C 7; other C] ( I f other 

please describe.) 

F'eriodically check and record the readings from the monitors 

during the test period. 

Are visible emissioy readings being taken in accordance with RM 9 

procedures? Yes CJJ; No L7 If yes, are the RM 9 readings 

comparable to the continuous opacity monitor readings? Yes 17; 

No C] (If no, indicate the discrepancies.) ! ~i4 

Are the coal and/or auxiliary fuel(s) and scrubber water and/or 

ash samples (if applicable) t~ eing collected at the proper 

location and frequency? Yes tJ; No CJ (If no, correct and 

continue, if possible.) 

Additional source or process information: 

/2v~ 
03/2911994 11:15 L104040400 

Facsimile Cover __, ~_ . et--,, 

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Phone: 

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Company: Metropolitan Gerami 

F rom . a ~ V`+ ~ 1 ~ W , =t~~e7 

Phone: 216-484-8453 

Fax: 216-484-8455 

Date: 3121 ~a.? 

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/3D 
ADDITIONAL TERMS & CONDITIONS 

~ 

1. Performance Test Requirements 

METROPOLITAIV INDUSTRIES 

1576051149 

P004 

The permittee shall conduct, or have conducted, performance testing on the air contami.nant source(s) in accordance 

with procedures approved by the Agency. Two copies of the written report shall be submitted and signed by the 

person responsible for the test, describing the test procedures followed and the results of such tests. The Director, 

or an Ohio EPA representative, shall be allowed to witness the tests, examine testing equipment and require the 

acquisition or submission of data and information necessary to assure that the source data and information necessary 

to assure that the source operation and testing procedures provide a valid characterization of the emissions from the 

source and/or the performance of the control equipment. 

A completed Intent to Test notification form shall be submitted to the Canton City Health Deparmient, Division of 

Air Pollution Control, 420 Market Avenue North, Canton, Ohio 44702. This notice shall be made thirty (30) days 

in advance and shall specify the source operating parameters, the proposed test procedures and the time, data, place 

and person(s) conducting such tests. 

Two copies of the test results shall be submitted within thirty (30) days after the completion of the performance test. 

Tests shall be performed for the following sources and pollutants: 

ource Pollutant(s) 

P004, P005, P006 S02, Fluorides 

Test'Method 13A should be employed to measure fluoride emissions. 

Test Method 6 should be employed to measure SO Zemissions. This test shall be run with all three kilns (#1, #2, #3) 

operating. This test shall be run at or near the maximum production capacity of all three kilns. 

This stack test shall include an analysis of the sulfur content of the raw materials (clay and shale). 

This test shall be conducted before Ivlay 1, 1994. 

2. A sulfur content limit will be established for the raw materials (clay and shale) used in Kiln #1 (P004), Kiln #2 

(P005) and Kiln #3 (P006). This limit shall be based on the results of the stack test done with all three kilns 

operating and shall be on a quarterly weighted average. Sulfur analysis method L E co will be used. 

At any one time, only two of the three kilns can be using a 1009'o clay mix with no shale. The third kiln must 

be using a mix with a shale content of at least 40%. J 

No more than 79 tons of raw materials shall be used in each kiln in any one day. 

The facility shall maintain monthly records which: 

A. List the weekly average sulfur content (percent) of daily sampled clay and shale and analyzed as weekly 

composite samples; 

B. List the clay and shale content of mixes used in each kiln each day; and 

/.~ 
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