2540-PM-BWM0347Rev.1/2011COMMONWEALTHOFPENNSYLVANIADEPARTMENTOFENVIRONMENTALPROTECTIONBUREAUOFWASTEMANAGEMENTFORM26RCHEMICALANALYSISOFRESIDUALWASTEANNUALREPORTBYTHEGENERATORThisformmustbeandcompleted.Allrequiredinformationmustbetypedorlegiblyprintedinthespacesprovided.Ifadditionalspaceisnecessary,identifyeachattachedsheetasForm26R,referencetheitemnumberandidentifythedateprepared.Thedateonattachedsheetsneedstomatchthedatenotedbelow.GeneralReference287.54c.PhysicalAppearance2128/11(EPAMethod9095}Solid(EPAMethod9095}Gas(ambienttemperature&pressure}ColorOrange,cloudyOdorNumberofSolidorLiquidPhasesofSeparation2NoDescribeeachphaseofselpar·ati,on..l!!J'.8._________________-Ja.d.e.proceduresemployedthelaboratory(ies)isattached.TheEPAapprovedmethodtotesteachanalyteislistedontheattachedlaboratoryresults.FairwayLaboratoriesisaccreditedbythePennsylvaniaDepartmentofEnvironmentalProtection.generatorknowledgein- 1 -NoN/A2540-PM-BWM0347 Rev.1/2011 a.
A detailed description
and/or pollution control processes producing the waste, as specified

In the Instructions,

is attached. b. c. c.
A schematic
of the manufacturing
control processes producing the waste, as specified

in the instructions,

is attached. If portions of the information subm are
the substantiation
for a confidentiality claim, as described

in the instructions,

is attached. Address Line
1 Address Line
1 Address City State ZIP Municipality Name

No N/A Title Phone 412-977-5959
Email Address MBowser@advancedwasteservices.com d. Volume of 75,200

or [81 gal un•rvr<.ru"' year. D lb D ton (check one) a. Solid waste permit number(s) for processing
or disposal facility being utilized. c. Address Line
1 Address Line
1 Address City State ZIP Municipality Facility Title Phone

County Email Address d . Volume of waste shipped to processing
or disposal facility in the previous year. D cu yd D gal D lb D ton (check one) b. Volume of waste beneficially used in the previous year. N/A

D cu yd D gal D ib D ton (check one) -2-

# <;IMb1(tf'i8

_ foftQ'Wfng,

If a_pplloabf4t: 

# ' 

# ~
1 

# :1J1ify **th~ ln.for~tlon**  rE!qr;dr,¢11n 

# Seotlon B-1, 

# <.;'n~t **Pl'Ope~s** was supplied 

# to the 

# Department
for the 

# year 

# gig, _ ._ _ _ _ **~not~ocl.**



# - F()t& SUbmttted:



# F8J FQilll 26R 

# [j otb8r(speelfy)

-------------- **P.a~ 'ubmttt~:**  

## t 

# ce'*'fv the 

## lrifolmatlon 

# requlr'tid-ln Sectloli 

# &-2, **Ch~mt¢~·** 

## Al,laJv•ls **~~a ~upplied** 


## tq ltte **Dapart~J~ent** 

## for the **y~ar** 

# J2j:Jl **~n~ ~otchanged** 



# --

- PO.!m 

# S~ct.



# I8J FfJPtl2fiR 

# 0 

# ou.- {specify) 

# ----------------------------- P.te :S-Ilted: **~ ~**  

# iJl.!J lnf9rmatlon **req!i~~Jn S~otlon**  

## B-3, Process **p~~UQn** 

# arnfSchematlc,

. vnrs supplied


# to the 

## DepaFtment (or 

# lh4t **y~a r**  

# 2010 and has n&t 

# changed. Fonn Submitted:



# 1!81 Fom:I26R 

# 0 Ql_h$-(speclfy)

------------- 

## 0.W
S _ 1,1bmftted: **~m• ~~poflatble**  

## Official



# -3-
Tl _ beFAIRWAY lABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Joe Kunst

••• e
•. FAIRWAY LABORATORIES •• •• •• Project

: KEYSTONE **CLEARWATER~** ProjectNumber: 10241-3 Collector: JK Number of Containers:

17 Reported: 08/23/10 10:55 ANALYTICAL REPORT FOR SAMPLES lsampleiD SLAVEK 1H Test Uncert. Gross Alpha

+/- 299.0 Gross Beta Radium226 Radium228

+/- 80.19 +/- 8
. 97 +/- 25.95 Fairway Laboratories, Inc. y_ and Submitted by: Michael
P. Tyler Laboratory Director Laboratory
ID OG20037-01 Matrix

Date Sampled Date Received Water 07/20/10 10:30 07/20/10 12:40 11re results
ill this report apply to the samples analyzed

in accordance with the chain of custody document. This analytical report must be reproduced

in its entirety. Page

1 of9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791

- Fax ARM Group 2013 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte Metals by EPA 200 Series Methods Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Mercury Lithium Magnesium Manganese Molybdenum Sodium Nickel Lead Fairway Laboratories, Inc.
Result <0.0200 <0.250 0.0968 4.87 420 <0

. 00500 1160 <0.0100 0.157 0.00782 <0.0500 26

. 7 <0.000200 11.6 141 1.72 <0

. 0500 5320 0.137 <0.0100
••• •
•• FAIRWAY LABORATORIES •• •• •• Project: KEYSTONE CLEARWATER

1 Project Number: 10241-3 Collector:
JK Number of Containers:

17 Reported: 08/23/10 10:55 Date/fime Sampled: 07/20/10 10:30 OG20037-01 (Water) Laboratory Reporting Limit Units Date /Time Analyzed Method Analyst Note 0.0200 mg/1 07/28/10 04:34 EPA200.7

rb 0.250 mg/1 07/28/10 04:33 EPA200.7

rb 0.0200 mg/1 07/28/10 04:34 EPA 200.7

rb 0.0500 mg/1 07/28/10 04:34 EPA 200.7

rb 1.00 mg/1 07/28/10 04:34 EPA200.7

rb Ll 0.00500 mg/1 07/28/10 04:34 EPA200.7

rb 10.0 mg/1 07/28/10 04:38 EPA 200.7

rb 0.0100 mgll 07/28/10 04:34 EPA200

. 7 rb 0.0500 mg/1 07/28/10 04:34 EPA200.7

rb 0.00500 mg/1 07/28/10 04:34 EPA 200.7

rb 0.0500 mg/1 07/28/10 04:34 EPA200.7

rb 2
. 00 mg/1 07/28/10 04:39 EPA200.7

rb Ll2 0.000200 mg/1 08/12/10 08:10 EPA 245

. 1 cb 5.00 mg/1 08/02110
23

: 19 EPA200

. 7 sub SCI 10.0 mg/1 07/28110 04:38 EPA200.7

rb 0
. 0500 mg/1 07/28/10 04:34 EPA200

. 7 rb 0.0500 mg/1 07/28/10 04:34 EPA 200.7

rb 20.0 mg/1 07/28/10 04:34 EPA200.7

rb Ll 0.0500 mg/1 07/28/10 04:34 EPA 200.7

rb 0.0100 mg/1 07/28/10 04

: 34 EPA 200

. 7 rb The results in this **r~port** apply to the samples analyzed

in accordance with the clrai11 of custody document

. This a11alytical report must be reproduced

ill its entirety

. Page
2 of 9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814)946-4306 (814)946-8791-
Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte

Result Metals by EPA 200 Series Methods Selenium

<0.0500 Strontium

206 Zinc

0.0773 Metals (Dissolved) by EPA 200 Series Methods Iron, Dissolved

25

. 8 Volatile Organic Compounds
**b~** EPA Method 8260B Benzene

<5.00 Toluene

<5.00 SurroJ!ate: 4-Bromofluorobenzene

99

. 3% SurroJ!ate:

1 ,2-Dichloroethane-d4

94

. 0% SurroJ!ate: F/uorobenzene

96

. 8% Conventional Chemistry Parameters
by SMIEPA Methods Acidity

-240 Total Alkalinity

368 Biochemical Oxygen Demand

44

. 8 Chemical Oxygen Demand

925 Specific Conductance (EC)

30600 Total Hardness

4200 Methylene Blue Active Substances

2
. 96 Nitrate as N

<25

. 0 Fairway Laboratories,
Inc

.

••• •
•• FAIRWAY LABORATORIES •• •• •• Project: KEYSTONE **CLEARWATER~** Project Number: Collector: 10241-3 JK Number of Containers:

17 Date!fime Sampled: OG20037-0l (Water) Laboratory Reporting

Date /Time Limit Units Analyzed 0.0500 mg/1 07/28/10 04:34 0.200 mg/1 07/28/10 04:35 0.0500 mg/1 07/28/10 04:34 0.400 mg/1 08/04/10 12:29 5
. 00 ug/1 07/28/10 02:08 5.00 ug/1 07/28/10 02:08 70-130 07/28/10 02:08 70-130 07/28110 02:08 70-130 07128/10 02:08 -10000 mg/1 07/27/10 13:45 10.0 mg/1 07/27110 12:00 20

. 0 mg/1 07/22/10 07

: 51 75.0 mg/1 07/23/10 12:29 2
. 00 umhos/cm 07/23/10 12:07 100 mg/1 07127/lO 22

: 34 Reported: 08/23/10 10:55 07/20/10 10:30 Method Analyst EPA200.7

rb EPA200.7

rb EPA200.7

rb EPA200.7

rb EPA8260B
wm EPA8260B
wm EPA 8260B WID EPA 8260B wm EPA 8260B wm SM2310B

EB SM2320B
EB SM5210B

SP EPA410.4
bw SM 2510B bw SM2340C

JG Note Ll 1.00 mg/1 07/21/10 13:00 SM5540C
EB L6,MS 25.0 mg/1 07/21/10 15:26 EPA 300.0 BW 17te results in this report apply to the samples analyzed
in accordance with the chain of custody document. 17tis analytical report must be reproduced

in its entirety. Page
3 of 9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax ARM Group 2013 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte

Result Conventional Chemistry Parameters
by SMIEP A Methods Nitrite as N Total Nitrogen Nitrate/Nitrite

as N Oil & Grease pH Phenolics Total Dissolved Solids Total Suspended Solids Total Kjeldahl Nitrogen Anions by EPA Method 300.0 Bromide Chloride Sulfate as S04

<5

. 00 112 <30.0 24.2 6
. 70 0.0230 20500 80.0 81.7 80.1 10500 <25

. 0 Physical Parameters
by APHA/ASTMIEPA Methods Ammonia asN Gross Alpha- Radiological Suite Gross Beta

- Radiological Suite Fairway Laboratories,
Inc

.

50.1 2200 463 ••• •
•• FAIRWAY LABORATORIES •• •• •• Project: KEYSTONE CLEARWATER

1 Project Number: 10241-3 Collector:
JK Number of Containers:

17 Reported: 08123/10 10:55 Date!fime Sampled: 07/20/10 10:30 OG20037-0l (Water) Laboratory Reporting Limit Units Date/Time Analyzed Method Analyst Note 5.00 mg/1 07/21110 15:26 EPA 300.0 BW 31.0 mg/l 08/03/10 10:26 SM4500Norg
AD c 30.0 mg/l 07/28/10 16:46 EPA

3 . 00.0 bw 12.5 mg/l 07/21110 22:40 EPA 1664A
IG Dl pH Units 07/20/10 17:45 SM4500H+B
MC 0.0100 mg/l 08/05/10 11:00 EPA420.1

JH Ll2 20.0 mg/l 07/26/10 18:51 SM2540C
RH 8.00 mg/1 07/26/10 17:27 SM2540D
RH 1.00 mg/l 08/03/10
16

: 14 SM4500Norg

JG c 5.00 mg/l 07/21110 15:26 EPA300

. 0 BW 1250 mg/1 07/23/10 22

: 03 EPA 300

. 0 BW 25.0 mg/1 07/21110 15:26 EPA 300

. 0 BW 5
. 00 mg/l 07/30110 01:26 ASTM

JG 06919-03 318 pCi/L 08/02/10 00:00 EPA 900

. 0 sub SC2 196 pCi!L 08/02/10 00:00 EPA 900.0 sub SC2 The results in this report apply to the samples analyzed
in accordance with the chain of custody document

. This a11alytical report must be reproduced

in its e11tirety

. Page
4 of 9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791

- Fax ARM Group 20 13 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte

Result Subcontracted Analyses Ethylene glycol

<10

. 0 Radium 226

205 Radium228

<54.0 Thorium

<10.6 Uranium

<7.23 Fairway Laboratories, Inc.

••• •
•• FAIRWAY LABORATORIES •• •• •• Project: KEYSTONE **CLEARWATER~** Project Number

: 10241-3 Collector

: JK Number of Containers:

17 Reported: 08/23/10 10:55 Dateffime Sampled: 07/20/10 10:30 OG20037-0l (Water) Laboratory Reporting Date/Time Limit Units Analyzed Method Analyst 10

. 0 mg/1 08/03/10 04

: 30 EPA8015M
sub 34

. 5 pCi/L 08/10/10 00

: 00 EPA903.0
sub 54.0 pCi/L 08/04/10 00

: 00 EPA904.0
sub 10.6 mg/1 08/11110 00

: 00 EPA200.8
sub 7
. 23 pCi/L 08/11/10 00:00 SM 7500-U sub A-B The results
in this report apply to the samples analyzed

in accm·dance with the cl1ain of custody document. This analytical report must be reproduced

in its emirety. Note SCI SC2 SC2 MS,SC2 MS, SC2 Page
5 of 9•• • e

· . FAIRWAY LABORATORIES 2019 Ninth Avenue FAIRWAY LABORATORIES PO Box 1925 Altoona, Pennsylvania 16603 (814} 946-4306 (814} 946-8791- Fax

·. .- •• ARM Group

Project: KEYSTONE **CLEARWATER~** 2013 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:
Joe Kunst Notes

Project Number: 10241-3 Collector:
JK Number of Containers:

17 SC2 This analysis was subcontracted

to BenchMark Analytical, ID# 09 - 00944

. SCI This analysis was subconttacted

to Analytical Laboratory Services

, Inc, ID# 22-00293

. MS The spike recovery was outside acceptance limits for the MS and/or MSD due to sample matrix interferences

. The batch was accepted based on acceptable CCV recovery. L6 MBAS, calculated
as LAS

, mol wt 320 Ll2 The prep method LCS spike recovery was outside acceptance limits

. The batch results were accepted based on the acceptable recovery of the other associated QC. Ll This result was above the cal
i bration range; therefore

it is an estimated value. Dl The RPD result exceeded the QC control limits for the duplicate sample analyzed. Reported: 08/23/10 10:55 Fairway Laboratories, Inc.

The res11lts in this report apply to the samples analyzed
in accordance with the clrailr of c11stody doc11ment. This analytical report must be reproduced

in its elllirety

. Page
6 of9J540-PM-BWM0347Rev.7/2009Instructionsc.HazardousWasteDetermination.Asrequiredunder40CFR262.11,andasincorporatedbyreferenceat25Pa.Code262a.1.1}pH2}lgnitability3}ReactiveSulfide4}ReactiveCyanide5}ToxicityCharacteristicLeachingProcedure(TCLP}-includeallparametersfoundin40CFR261.24,asincorporatedbyreferenceat25Pa.Code261a.1,aswellaspHofextract.Reportallresultsinmg/Lorasotherwisespecifiedinmethod.d.WastewaterProducedfromtheDrilling,CompletionandProductionofaMarcellusShaleorOtherShaleGasWell.InlieuoftheTraceAnalysisdescribedinsubsectionb.,thechemicalanalysisofwastewaterproducedfromthedrilling,completionandproductionofaMarcellusShaleorothershalegaswellmustincludethefollowing:AcidityCalciumLeadSeleniumAlkalinity(TotalasChemicalOxygenLithiumSilverCaC03}DemandMagnesiumSodiumAluminumChloridesManganeseSpecificConductanceAmmoniaNitrogenChromiumMBAS(Surfactants}StrontiumArsenicCobaltMercurySulfatesBariumCopperMolybdenumThoriumBenzeneEthyleneGlycolNickelTolueneBerylliumGrossAlphaNitrite-NitrateNitrogenTotalDissolvedSolidsBiochemicalOxygenGrossBetaOil&GreaseTotalKjeldahlNitrogenDemandHardness(TotalaspHTotalSuspendedSolidsBoronCaC03}Phenolics(Total}UraniumBromideIron-DissolvedRadium226ZincCadmiumIron-TotalRadium228Additionalconstituentsthatareexpectedorknowntobepresentinthewastewater.*Note-Allmetalsreportedastotal.Forimpoundmentsandtanks,thechemicalanalysismustrepresentthevolumeofwastewaterstoredintheimpoundmentortank.Arepresentativeanalysisisbaseduponthefrequency,locationandnumberofsamples.Samplesofanimpoundmentshouldbecompositesamplestakenfromvariouslocationsandwastewaterdepthsasidentifiedonagrid.Ifmultipleloadsofwastewaterareremovedfromthesameimpoundmentortanksfortransfer,processing,treatmentordisposal,thesamechemicalanalysisofthewastewatermaybeusedrepeatedlywithoutfurtheranalysis,providedtheanalysisremainsrepresentativeoftheimpoundment.Iflargevolumesofwater,wastewaterorotherfluidsareaddedtotheimpoundment,anewchemicalanalysismustbeperformedthatisrepresentativeoftheimpoundment.Page3of6Form26R:ChemicalAnalysisofResidualWasteAnnualReportbytheGeneratorFlowBackWaterSamplingMethodsNarrativeFlowbackwatersampleswerecollectedonJuly20,2010fromtheconcentratetanklocatedattheSlavekIHwellpad.Thesamplingofflowbackwateratthesiteconsistedofcollectinggrabsamplesofthematerialandplacingthesamplesintolaboratoryprovidedglassware.Atotalofseventeen(17)representativesampleswerecollected.Sampleswerecollectedbypersonnelwearingacleanpairofnitrile glovesforeachsamplingareatominimizesamplecrosscontamination.ThesamplesoftheflowbackwaterweresubmittedtoFairwayLaboratoriesofAltoona,PennsylvaniaforanalysisoftheappropriateForm26Rconstituents.Acompletelistofanalysesisattached.Theanalyticalresultsforthesamplesarerepresentativethequalityofthefluidsgeneratedduringwelldrillingactivitiesatthiswellsite.WaterTreatmentSchematicandProcessDescriptionforMarcellusShaleFlowbackFluidIWellsIFlowBackTanksClearwaterTreatedWaterNanofiltration1TanksConcentrate,ConcentrateTank,ToOffsiteTreatmentFacilityProcessDescription:Amobilefiltrationunitwasutilizedtofilterflowbackwaterfromfracturingofnaturalgaswells.Filteredwaterwasreusedand"concentrate"fromthefilteringprocesswashauledoff-sitetoapermittedbrinewatertreatmentfacility.2640-PM-BWM0347Rev.1/2011cCOMMONWEALTHOFPENNSYLVANIADEPARTMENTOFENVIRONMENTALPROTECTIONBUREAUOFWASTEMANAGEMENTFORM26RCHEMICALANALYSISOFRESIDUALWASTEANNUALREPORTBYTHEGENERATORmustbefullyandaccuratelycompleted.Allrequiredinformationmustbetypedorlegiblyprintedinthespacesprovided.Ifadditionalspaceisnecessary,identifyeachattachedsheetasForm26R,referencetheitemnumberandidentifythedateprepared.Thedateonattachedsheetsneedstomatchthedatenotedbelow.GeneralReference287.542/28/11EPAGeneratorID#c.PhysicalAppearancee.FirstNameNedMlE.nguseofgeneratorknowledgein- 1 -PhoneExt717-508-0550SuffixP.G.NoN/A2540-PM-BWM0347Rev.1/2011b.c.thewaste,asspecifiedintheinstructions,Isattached.Aand/orpollutioncontrolprocessesproducingthewaste,asspecifiedintheinstructions,isattached.submittedareconfidential,thesubstantiationforaconfidentialityclaim,asdescribedintheinstructions,isattached.Solidwasteperm301353b.FacilityNameAddressLine1AddressLine1AddressCityStateZIPMunicipalityc.FacilityContactTitleNoNoN/APhone412-977-5959AddressMBowser@advancedwasteservices.comwasteshippedtoprocessingordisposalfacilityinthepreviousyear.28,2000cuyd181gal0lb0ton(checkone)a.Solidwasteb.FacilityNameAddressLine1AddressLine1AddressCityStateZIPMunicipalityc.FacilityContactNameTitled.a.b.PhoneVolumeofwasteN/Arprocessingordisposalfacilitybeingutilized.Countyordisposalfacilityinthepreviousyear.Dgal0lb0ton(checkone)0ton(checkone)-2-

# to~,~!'~



# J1f **Ia~,**



# -

I · 

# h~ **~~** exarnlned 

# anctam 

# fa!ll~r **Wltf'l ~**  **lnfc»mati<J**

**Ifl** **&*•~** 

# Report

. aitd 811: attaC1Mcl doJMnC!.m. 

# .ail4



# : U.@t **-~ ~pon**  

# my lf'!ql.ilry **~**



# . IJJ'JG
_ **~tvtduals**



# . t'f&lponelblle obtatn'lng thQ 

# lnff.tm@{lon,



# I verlfv 

# ta-.t **~ ~ed**  

# Information

It 

# we, accurate and 

# ooA'•P18.le knowledge.



# I **~-i'stand** 

# tha. tM **,ubltlt~**



# o t false **lnfo~tlor!**



# . MtOfn _, **m.~e a~ject** 


# to **Ill~** 

# .,..,_,. §4804. rtlaUng tO. _ unfiWC)n, fa"'lfication



# tQ a\dborttl", which 

# fnokfde 

# nn. · l(tld _ 1mPrfsonmant. Oh.•ct< the **fo11~**



# If •pQcable: 

# G

I · 

# f;e{Uty **frl~l.lon ~q~~d** 


# In SeQtlon 

# S·t, General **Pt'OP~ ~e**  

# was supplied 

# to the 

# DapartmenUor


# thQ year 

# a!!! a _ mrhaa **~ ~nged.** 



# - form 

# 6ubmltl8ct.

**~ Form~**  

# Q Other(SJ$0tM

------------ Date 

# 8u _ bmltt.d: **~**



# I **ceri.t~J** the 

# mformatlpn required -In 

# Section 

# B·~. Chomfclll 

# Analyal$ WiJS 

# ayPP,tled
to 

# the Departmfritt


# for the 

# year 

# U **aild~** 

# .. **,~-** 

# Form **8u~hllt** 

# ... 

# 4: **~ Form~**  

# 0 **OOI~rf~)** 

# Ba1e **Sub~ Jtt,ct.**  

# I ctirtiJy 

# tl\c:t **tnf~lion ~fred** 


# fn **S~n** 

# 84, 

# Process DescripOon and Schematic, was 

# eupplfed

· 

# b f the Department for the year 

# B1! **~dt.aa** 

# not charigeCt. Form **SUbm~**



# l8J ftoqA 26A 

# 0 **0t~ (sP'-Ctfy)**  ------------- 

# Date **~mtttect:** 

# N

. a!lle of **Responsl~e** 

# efficla.l



# 110eFAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814} 946-4306 (814) 946-8791

- Fax ARM Group 2013 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:

· Joe Kunst

••• e
•. FAIRWAY LABORATORIES ·. .- •• Project: KEYSTONE CLEARWATER! Project Number:

l 0241-3 Collector:
JK Number of Containers:

17 Reported: 08/23/10 10:55 ANALYTICAL REPORT FOR SAMPLES lsampleiD SLAVEK lH Test Uncert

. Gross Alpha

+/- 299.0 Gross Beta Radium226 Radium228

+/- 80.19 +/- 8
. 97 +/- 25.95 Fairway Laboratories,
Inc

. y_and Submitted

b y : Mic h ael P. T yler Laborat

o ry Direct

o r Laboratory
ID OG20037-01 Matrix

Date Sampled Date Received Water 07/20/10
10

: 30 07/20/10 12:40 The results
in this report apply to the samples analyzed

in accordance with the chain of custody document. This analytical report must be reproduced

in its entirety

. Page

1 of9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax ARM Group 20 13 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte

Result Metals by EPA 200 Series Methods Silver

<0.0200 Aluminum

<0

. 250 Arsenic

0.0968 Boron

4.87 Barium

420 Beryllium

<0.00500 Calcium

1160 Cadmium

<0.0100 Cobalt

0.157 Chromium

0.00782 Copper

<0.0500 Iron

26.7 Mercury
<0.000200 Lithium

11.6 Magnesium

141 Manganese

1.72 Molybdenum

<0.0500 Sodium

5320 Nickel

0
. 137 Lead

<0.0100 Fairway Laboratories, Inc.

••• e
•. FAIRWAY LABORATORIES ·. .- •• Project: KEYSTONE **CLEARWATER~** Project Number: 10241-3 Reported: Collector:
JK 08/23/10 10:55 Number of Containers:

17 Dateffime Sampled: 07/20/10
10

: 30 OG20037-0l (Water) Laboratory Reporting Date/Time Limit Units Analyzed Method Analyst Note 0.0200 mg/1 07/28/10 04:34 EPA200.7

rb 0
. 250 mg/1 07/28/10 04:33 EPA200.7

rb 0.0200 mg/1 07/28/10 04

: 34 EPA200.7

rb 0.0500 mg/1 07/28/10 04:34 EPA200.7

rb 1.00 mg/1 07/28/10 04:34 EPA200.7

rb Ll 0.00500 mg/1 07/28/10 04:34 EPA200.7

rb 10

. 0 mg/1 07/28/10 04:38 EPA200

. 7 rb 0.0100 mg/1 07/28/10 04:34 EPA 200.7

rb 0.0500 mg/1 07/28/10 04:34 EPA200.7

rb 0.00500 mg/1 07/28/10 04:34 EPA200.7

rb 0.0500 mg/1 07/28/10 04

: 34 EPA 200.7

rb 2.00 mg/1 07/28/10 04:39 EPA200.7

rb Ll2 0.000200 mg/1 08/12/10 08:10 EPA 245.1
cb 5.00 mg/1 08/02/10 23:19 EPA200.7
sub SCI 10.0 mg/1 07/28/10 04:38 EPA 200

. 7 rb 0.0500 mg/1 07/28/10 04:34 EPA 200.7

rb 0.0500 mg/1 07/28/10 04:34 EPA 200.7

rb 20.0 mg/1 07/28/10 04:34 EPA 200.7

rb Ll 0
. 0500 mg/1 07/28/10 04

: 34 EPA 200.7

rb 0.0100 mg/1 07/28/10 04

: 34 EPA200.7

rb The results
in this report apply to the samples analyzed

i n accordance with the chain of custody document. This analytical report must be reproduced

in its entirety

. Page
2 of9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte

Result Metals by EPA 200 Series Methods Selenium

<0.0500 Strontium

206 Zinc

0.0773 Metals (Dissolved) by EPA 200 Series Methods Iron, Dissolved

25.8 Volatile Organic Coml!ounds
b;r EPA Method 8260B Benzene

<5.00 Toluene

<5.00 Surrof!ate: 4-Bromofluorobenzene

99

. 3% Surrof!ate: 1,2-Dichloroethane-d4

94.0% Surrof!ate: Fluorobenzene

96

. 8% Conventional Chemist!:I Parameters
b;y SMIEP
A Methods Acidity

-240 Total Alkalinity

368 Biochemical Oxygen Demand

44.8 Chemical Oxygen Demand

925 Specific Conductance (EC)

30600 Total Hardness

4200 Methylene Blue Active Substances

2.96 Nitrate as N

<25.0 Fairway Laboratories, Inc.

••• e
•. FAIRWAY LABORATORIES ·. .- •• Project: KEYSTONE **CLEARWATER~** Project Number: 10241-3 Reported: Collector:
JK 08/23/10 10:55 Number of Containers:

17 Date/Time Sampled: 07/20/10 10:30 OG20037-0l (Water) Laboratory Reporting

Date /Time Limit Units Analyzed Method Analyst Note 0.0500 mg/1 07/28/10 04:34 EPA200.7

rb 0.200 mg/1 07/28/10 04:35 EPA200.7

rb Ll 0.0500 mg/1 07/28/10 04:34 EPA 200

. 7 rb 0.400 mg/1 08/04/10 12:29 EPA200.7

rb 5.00 ug/1 07/28/10 02:08 EPA8260B
wm 5.00 ug/1 07/28/10 02:08 EPA8260B
wm 70-130 07/28110 02:08 EPA 8260B wm 70-130 07128/10 02
: 08 EPA 8260B wm 70-130 07128/10 02
: 08 EPA 8260B wm -10000 mg/1 07/27/10 13:45 SM2310B
EB 10.0 mg/1 07/27/10 12:00 SM2320B
EB 20

. 0 mg/1 07/22/10 07:51 SM5210B

SP 75.0 mg/1 07/23/10 12:29 EPA 410.4 bw 2.00 umbos/em 07/23/10 12:07 SM2510B
bw 100 mg/1 07/27/10 22:34 SM2340C

JG 1.00 mg/1 07/21/10 13:00 SM5540C
EB L6,MS 25.0 mg/1 07/21/10 15:26 EPA 300.0 BW The results in this report apply to the samples analyzed
in accordance with the chain of custody document

. This al!alytical report must be reproduced

in its entirety

. Page
3 of9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax ARM Group 2013 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte

Result Conventional Chemistry Parameters
by SMIEP A Methods Nitrite as N Total Nitrogen Nitrate/Nitrite

as N OU & Grease pH Phenolics Total Dissolved Solids Total Suspended Solids Total Kjeldahl Nitrogen Anions by EPA Method 300.0 Bromide Chloride Sulfate as S04

<5.00 112 <30.0 24.2 6
. 70 0.0230 20500 80.0 81.7 80.1 10500 <25.0 Physical Parameters
by APHA/ASTM/EPA Methods Ammonia asN Gross Alpha- Radiological Suite Gross Beta

- Radiological Suite Fairway Laboratories, Inc.

50

. 1 2200 463 ••• •
•• FAIRWAY LABORATORIES •• •• •• Project: KEYSTONE CLEARWATER Project Number: 10241-3 Collector

: JK Reported: 08/23110
10

: 55 Number of Containers:

17 OG20037-01 (Water) Laboratory Reporting Limit 5.00 31.0 30.0 12.5 0.0100 20.0 8.00 1.00 5.00 1250 25

. 0 5.00 318 196 Units mg/1 mg/1 mg/1 mg/1 pH Units mg/1 mg/1 mg/1 mg/l mg/1 mg/1 mg/1 mg/1 pCiiL pCi/L Date/Time Sampled: Date /Time Analyzed 07/21110 15:26 08/03/10 10:26 07/28/10 16:46 07/21/10 22:40 07/20/10 17:45 08/05/

I 0 11 :00 07/26/10 18:51 07/26/10 17:27 08/03/10 16:14 07/21!10 15:26 07/23/10 22:03 07/21/10
15

: 26 07/30/10 01:26 08/02/10 00:00 08/02/10 00

: 00 07/20/10 10:30 Method Analyst Note EPA 300.0 BW SM4500Norg
AD c EPA300.0
bw EPA 1664A
JG Dl SM4500H+B
MC EPA420.1

m L12 SM2540C
RH SM2540D
RH SM4500Norg

JG c EPA300.0 BW EPA 300.0 BW EPA 300.0 BW ASTM

JG D6919-03 EPA 900.0 sub SC2 EPA 900

. 0 sub SC2 The results
ill this report apply to the samples analyzed

in accordance with the chain of custody document. This a11alytical report must be reproduced

in its entirety. Page
4 of9FAIRWAY LABORATORIES 2019 Ninth Avenue PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax ARM Group 2013 Sandy Drive, Suite 205 State College PA, 16803 Project Manager:
Joe Kunst Client Sample ID: SLAVEKlH Laboratory Sample ID: Analyte Subcontracted Analyses Ethylene glycol Radium226 Radium 228 Thorium Uranium Fairway Laboratories, Inc.
Result <10.0 205 <54.0 <10

. 6 <7

. 23 ••• . e

·. FAIRWAY LABORATORIES •• •• •• Project: KEYSTONE **CLEARWATER~** ProjectNumber: 10241-3 Collector: JK Number of Containers:

17 Reported: 08/23/10
10

: 55 OG20037-01 (Water) Laboratory Reporting Limit 10.0 34

. 5 54

. p 10.6 7

. 23 Units rng/1 pCi/L pCi/L rng/1 pCi/L Dateffime Sampled: Date/Time Analyzed 08/03/10 04:30 08/10/10 00

: 00 08/04/10 00:00 08/11/10 00:00 08/11/10 00:00 07/20/1

0 1 0
: 30 Method Analyst Note EPA8015M
sub SCl EPA 903.0 sub SC2 EPA 904.0 sub SC2 EPA 200.8 sub MS,SC2 SM 7500-U sub MS,SC2 A - B The results in chis report apply Co the samples analyzed

in accordance with rhe chain of custody document. This ana lyrical report muse be reproduced

in its elllirety. Page
5 of9••• e
•. FAIRWAY LABORATORIES 2019 Ninth Avenue FAIRWAY LABORATORIES PO Box 1925 Altoona, Pennsylvania 16603 (814) 946-4306 (814) 946-8791- Fax

·. .- •• ARM Group

Project: KEYSTONE CLEARWATER 2013 Sandy Drive, Suite 205 State College

P A, 16803 Project Manager:
Joe Kunst Notes

Project Number

: 10241-3 Collector

: JK Number of Containers:

17 SC 2 This anal y sis w as subco
n tracted to BenchMark Analytical

, ID# 09 - 00944

. SCI This analy

s is was subcontracted

to Analytical Laboratory Services

, Inc

, ID# 22-00293. MS The spike reco v ery was outs

i de acceptance limits for the MS an d/o r MSD due to sample matrix interferences

. The batch was accepted based on acceptable CCV recovery. L6 MBAS, calculated

as LAS

, mo
l wt 320 L 12 The prep method LCS sp i ke recovery was outside acceptance lim

i ts . The batch results were accepted based on the acceptable recovery of the other associated QC. Ll This result was above the calibration range; therefore

it is an estimated value. Dl The RPD result exceeded the QC control limits for the duplica

t e sample analyzed

. Reported: 08/23/10
10

: 55 Fairway Laboratories, Inc.

The results in this report apply to the samples analyzed
in accordance with the chain of custody document. This aJJalytica/ report must be reproduced

ill its entirety. Page
6 of9.l540-PM-BWM0347
Rev. 7/2009 Instructions c. Hazardous Waste Determination.

As required under 40 CFR262.11, and as incorporated

by reference
at 25 Pa. Code 262a.1. 1} pH 2} lgnitability 3} Reactive Sulfide 4} Reactive Cyanide 5} Toxicity Characteristic Leaching Procedure (TCLP)

- include all parameters found
in 40 CFR 261.24, as incorporated

by reference

at 25 Pa. Code 261 a.1, as well as pH of extract. Report all results
in mg/L or as otherwise specified

in method. d. Wastewater Produced from the Drilling, Completion and Production

of a Marcellus Shale or Other Shale Gas Well.
In lieu of the Trace Analysis described

in subsection
b., the chemical analysis of wastewater produced from the drilling, completion and production
of a Marcellus Shale or other shale gas well must include the following: Acidity Calcium

Lead Selenium Alkalinity (Total as Chemical Oxygen Lithium
Silver CaC03) Demand Magnesium Sodium Aluminum Chlorides Manganese Specific Conductance Ammonia Nitrogen Chromium
MBAS (Surfactants) Strontium Arsenic
Cobalt Mercury Sulfates Barium Copper Molybdenum Thorium Benzene Ethylene Glycol Nickel Toluene Beryllium
Gross Alpha Nitrite-Nitrate Nitrogen Total Dissolved Solids Biochemical Oxygen Gross Beta

Oil & Grease
Total Kjeldahl Nitrogen Demand Hardness (Total as
pH

Total Suspended Solids Boron CaC03) Phenolics (Total) Uranium Bromide

Iron

- Dissolved Radium 226
Zinc Cadmium
Iron- Total Radium 228 Additional constituents that are expected
or known to be present

in the wastewater

. *Note

- All metals reported as total. For impoundments
and tanks, the chemical analysis must represent the volume of wastewater stored
in the impoundment

or tank. A representative analysis

is based upon the frequency, location and number of samples. Samples
of an impoundment should be composite samples taken from various locations and wastewater depths as identified on a grid.
If multiple loads of wastewater are removed from the same impoundment

or tanks for transfer, processing, treatment
or disposal, the same chemical analysis
of the wastewater may be used repeatedly without further analysis, provided the analysis remains representative

of the impoundment.

If large volumes
of water, wastewater

or other fluids are added to the impoundment,

a new chemical analysis must be performed that is representative

of the impoundment. Page
3 of6Form 26R: Chemical Analysis of Residual Waste Annual Report by the Generator Flow Back Water Sampling Methods Narrative Flow back water samples were collected on July 20, 2010 from the concentrate tank located
at the Slavek 2H well pad. The sampling of flow back water at the site consisted of collecting grab samples of the material and placing the samples into laboratory provided glassware.

A total of seventeen (17) representative samples were collected. Samples were collected by personnel wearing

a clean pair of nitrile gloves for each sampling area to minimize sample cross contamination. The samples of the flow back water were submitted

to Fairway Laboratories
of Altoona, Pennsylvania
for analysis of the appropriate Form 26R constituents.

A complete list of analyses is attached. The analytical results for the samples are representative
the quality of the fluids generated during well drilling activities
at this well site.WaterTreatmentSchematicandProcessDescriptionforMarcellusShaleFlowbackFluidIWellsIFlowBackTanksClearwaterTreatedWaterNanofiltrationTanksConcentrateConcentrateTankToOffsiteTreatment.FacilityProcessDescription:Amobilefiltrationunitwasutilizedtofilterflowbackwaterfromfracturingofnaturalgaswells.Filteredwaterwasreusedand"concentrate"fromthefilteringprocesswashauledoff-sitetoapermittedbrinewatertreatmentfacility.