# OAR Box 

# 1394 Prepped by Ollie Stewart



### Document

Number: 

# 12 ) ll-B- 7 Docket Number: 

# A-94-5 2

Printed 7/3/2008 7:22:10 AM

Sheet 12 of 57P. 2


## 1 7 £7i /=Z7G~7GZ 7 O PACIFI C ENVIRONMENTA L SERVICES , INC . 

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. N C 27709-207 7 (919)941-033 3 FAX (919 ) 941-023 4



### SIT E VISI T REPOR T TO :

FROM : DATE : SUBJECT : Madelein e Stru m (MD-13 ) ESD/CP B U. S Environmenta l Protectio nAgenc y Researc hTriangl e Park , NC 2771 1 Greg^raFlam

an dDeanCarrol l Pacifi c Environmenta l Services , Inc . Octobe r 6 , 199 3 L:\N02 7 (N204 ) (PES ) .;' ; i'l f. " | , !!•

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### Sit e Visit--Picken' s Plastics , Inc . Ashtabula , Ohi o EPA Contrac t 68D10116 ; ES DProjec t 93/5 8 PE S Project s N027 , N20 4
I . Purpos e Th e purpos e o f thi s visi t wa s t o observe han dlayup , sprayup , an

d compressio nmoldin g fabricatio nprocesse s an dt o obtai ninformatio nonth e processes , hazardou s ai r pollutan t (HAP ) emissions , an dapplicabl e contro l measures . Thi s informatio nwil l be use di nth e developmen t o f a maximu m achievabl e contro l technology (MACT ) standar dfo r th e reinforce dplasti c composite s productio nsourc e category . Thi s sit e visi t wa s par t o f a 3-day tri pt o observ e operation s a t si x composit e facilitie s b y the U.S . Environmenta l Protectio nAgenc y (EPA) , it s contractor , Pacifi c Environmenta l Services , Inc . (PES) , an drepresentative s o f tw o industr y

trad e associations : Th e Societ y o f th e Plastic s Industry Composite s Institut e (CI) , an dth e Composite s Fabricator s Associatio n(CFA) . II . Plac e an

dDat e Picken' s Plastics , Inc . 421 2 An nAvenue , P.O . Bo x127 9 Ashtabula , Ohi o 4400 4 Augus t 12 , 1993 , 8:3 0 a.m . - 11:0 0 a.m .

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### Sit e Visi t Repor t - Picken' s Plastic s Pag e 2 III . Participant s Picken' s Mr . To m Picken , Presiden t Mr . Te d Hebert , Consultan t t o Picken' s Plastic s U.S . EP A 

### Ms . Madelein e Strum , Projec t Manage r PE S Mr . Gre g LaFlam , Environmenta l Enginee r Mr . Dea nCarroll , Environmenta l Enginee r SP I Composite s Institut e Mr . JohnSchweitzer , Technica l Directo r Composite s Fabricator s Associatio n Mr . Stev e McNally , Directo r o f Governmen t Affair s IV . Discussio n Picken' s Plastic s i s locate dinAshtabul a County , Ohio , a nattainmen t are a fo r ozone . Stat e regulation s limi t emission s o f photochemicall y reactiv e VOC' s fro

m eac hpermitte demissio nsourc e t o n o mor e tha n4 0 pound s (lb ) pe r day , o r 8 lb/hr . (The Stat e o f Ohi o consider s some compound s define da s VOC's b y EPA t o be photochemicall y reactive , an

dother s t o be nonphotochemicall y reactive. ) (Please

confirm, is

styrene

considered

photochemically

reactive?) 

### Th e facilit y

i s require dt o kee pdail y record s o f resi nan

dge l coa t us e a t eac hspray

boot han

dt o fil e a quarterl y

repor t wit hth e State . Th e visi t bega ninMr . Picken' s offic e wit hMr . Picke nan dMr . Heber t describin g th e products , processes , emissions , an dcontro l measure s a t th e facility . Mr . Heber t agree dt o provid e additiona l writte ninformatio nt o PE S a t a late r dat e (thi s informatio nwa s receive dAugus t 16 , 199 3 an di s discusse dinSectio nV) . A t 9:3 0 a.m. , a tou r o f th e proces s operation s a t th e facilit y

wa s taken . Th e tou r conclude da t 11:0 0 a.m . A . Processe s an

dProduct s Picken' s Plastic s wa s starte db y Tom Picke ni n1974 , an

dtoda y ha s approximatel y

10 0 employee s workin g two shift s pe r day , 5 day s pe r week . Th e company' s produc t lin e consist s primaril y o f truc kpart s (tracto r hood s an d sid e fairings ) fo r sal e t o majo r truc kmanufacturers . Fou r truc khood s pe r da y ar e produce da t th e facility . Th e company ha s als o produce dcover s fo r larg e machiner y

an dha s performe don-sit e repair s t o composit e pipin g a t a nuclea r powe r plan t an da t chemica l productio nfacilities .P. 4

Sit e Visi t Repor t - Picken' s Plastic s Pag e 3 Th e facility' s primar y productio nproces s i s ope nmolding , consistin g o f abou t 9 0 percen t han dlayupan

d1 0 percen t sprayup . Some close dmoldin g i s als o carrie dout , using shee t moldin g compound(SMC ) an dbul k moldin g compoun d (BMC ) i ncompressio nmolds . Thre e type s o f resin s ar e usedi nth e ope nmol dprocesses : 1 ) orthophthali c genera l purpos e polyester , 2 ) a nisophthalic-orthophthali c blen d (withstand s 225-250° F fo r 1 hour) , an d3 ) a corrosion-resistan t resi n(use d fo r on-sit e repair s a t chemica l facilities) . (Please match these resin types to the attached

MSDS sheets.) A methy l ethy l keton e peroxid e (MEKP)-typ e catalys t (Luperso l DDM- 9 b y Atochem ) i s adde dt o th e resin s a t 1 t o 1. 5 percen t b

y weight . On e o f th e resi nmixe s use dwithi nth e facilit y incorporate s a styren e suppressan t additiv e fo r reducin g styren e emissions , whic hi s adde db

y th e resi nvendo r a t 1. 5 percen t b y weight . A

vapo r suppresse dge l coa t i s als o useda t Picken's . (Please specify if any other resins or gel coats have vapor suppressant

components. Also, what products cannot be produced

with styrene

suppressed

resins?) Resi nshipment s ar e receive dint o a non-vente d8,500-gallo nhighwa y tanke r approximatel y onc e pe r month . I t i s transferre dt o custo m tote s (abou t 2 0 i nth e plant ) fo r us e i nth e spray booths . (Hhat

size are the custom totes?) Fo r han

dlayup , th e resi ni s transferre dt o plasti c buckets . Th e facilit y

operate s fiv e spray booth s permitte dwit hth e Ohi o EPA , consistin g o f on e ge l coa t boot han dfou r resin/choppe dfibe r fabricatio n booths . Mold s ar e treate dwit ha produc t calle d"Monocoat " ( a mol dreleas e agent) , afte r eac hfift hpar t i s produced . (Is there an MSDS available for the Monocoat?)

Ge l coa t i s firs t spraye dont o th e mol dsurface , a t a thicknes s o f 1 5 t o 2 0 mils . Thi s laye r cure s i napproximatel y 2 0 minutes . A laye r o f resi ncombine dwit hchoppe dfiberglas s roving i s the napplie dusing a nairles s spra y

gunwit ha glas s choppe r unit . Th e resultin g laye r i s approximatel y

6 9 percen t b

y weigh t resin , 3 0 percen t glass , an d1 percen t catalyst . Eac hspra y

boot hi s ventilate dthroug ha bank o f wall-mounte ddr y Andre a filter s situate da t th e botto m o f on e wal l o f th e booth , througha blowe r an d the nt o th e atmospher e througha roundstack . Th e adjacen t "walls " ar e actuall y full y ope nt o th e res t o f th e shop . Th e followin g informatio no nth e booth s wa s provided :
Boot h#/Tvp e B5-A/Resi n B5-B/Resi n B5-C/Resi n B-6/Ge l Coa t # o f 20"x20"x2 " Filter s 8 4 1 4 1 2 Flo

w (acfm/fonO 4,704/17 5 3,093/11 5 4,093/15 2 6,750/25 0 Stac k Di a 3 4 2 7 2 4 36 Inche s n n H
Th e filter s ma y

las t fro

m 1 t o severa l day s befor e they needt o b e change d out . Spra y

booth s ar e cleane dweekly . Eac hboot hutilize s a 3-gallo nP. 5

Sit e Visi t Repor t - Picken' s Plastic s Pag e 4 pressurize dcanniste r o f aceton e pipe dt o th e spray gun , whic hi s use dfo r gun flushin g betwee nsprayin g operations . Smalle r part s ar e lai du pb y handinope narea s o f th e sho pfloor . Wove nglas s reinforcin g clot hi s sprea dou t onsheet s o f brow npape r ona wor k bench , an

dth e clot hi s saturate dusin g brushe s dippe dint o ope nplasti c bucket s o f resin . Piece s o f saturate dclot har e the npresse dont o th e mol d an dsmoothe dou t usin g brushe s an drollers . Finishin g operations , includin g trimming , assembling , grinding , an d sanding , ar e performedi ntri m booth s B8 , B9 , an

dBIO . Boot hB 8 contain s si x wor k stations , terme dSl , S2 , S3 , S4 , S5 , an dS6 . Two separate dus t collectio nsystem s ( 2 Mode l DC6000' s b y Dustcontrol ) ar e use dfo r spo t collectio no f dus t fro m th e finishin g tools . Exhaus t ai r fro m thes e system s i s recirculate dbac k int o th e buildin g t o conserv e hea t energy . Thes e system s ar e emptie ddail y

an dth e dus t i s discardedt o a landfill . Th e company report s tha t th e system collect s dus t wit h99.5 7 percen t efficiency , an dabou t 0. 6 poundo f dus t i s collecte dpe r 10 0 pound s o f produc t processed . Boot hB 9 i s a sandin g boot hwhic hi s exhauste dusin g two fan s throug h1 4 filter s (24"x24"x2" ) int o separat e stacks . Ai r flow throug heac hfani s 2,75 6 acf m (17 5 fpm) . Collecteddus t i s discarde dt o a landfill . Boot hBI O i s use dfo r trimmin g an

dassembl y

o f truc k hoods . Thi s boot hutilize s a ban k o f Andre a filter s t o clea nth e dust y wor k air , whic hi s exhauste da t 6,33 9 acf m (10 5 fpm ) throug ha fa nt o a singl e 36-inc hroundstack .

Th e facilit y

use s approximatel y

two drum s pe r yea r o f bondin g agent s t o assembl e th e truc k components . Th e primar y adhesiv e i s Pliogri p6600 , supplie db

y Ashlan dChemical . Thi s produc t i s classifie da s a polyurethan e prepolymer , an

dcontain s 1 9 t o 2 6 percen t b y weigh t o f th e HA P methylen e phenylen e diisocyanat e (MDI) . Paint s ar e spraye dina separat e boot hont o th e externa l surface s o f th e truc k hood s i norde r t o produc e a Clas s A (automotiv e quality ) surface . (The paintin g operation , whic hfollow s th e trimmin g an

dassembl y

o f truc k hood s describedfo r boot hB1 0 above , wa s no t observe ddurin g th e visit. ) Th e facilit y

als o operate s seve nBMC/SM C closed-mol dpresses . Bot hBM C an dSMC ar e purchasedfro m outsid e source s fo r thes e processes . (What kinds of products

are made from BMC and SMC at Picken's?)

Th e styren

e conten t o f thes e moldin g compound s i s 1 1 t o 1 3 percent . Th e compan y estimate s tha t abou t 0. 5 percen t o f th e styren e conten t i s los t a s emission s durin g thes e moldin g operations . Measurement s a t thes e mold s hav e indicate dconcentration s o f styren e n o highe r tha n1 5 pp m i nth e breathin g space . B . Wast e Handlin g an dClean-u p Th e company

previousl y

relie dexclusivel y

onaceton e fo r cleaning , bu t replace dmuc ho f it s aceton e usag e onJul y 1 , 1993 , wit ha produc t calle d Envirosol v

2000 . Aceton e i s stil l use dfo r guncleanin g an dflushin g betwee n sprayupoperations . A non-sit e distillatio nuni t i s usedt o recycl e th e aceton e fo r furthe r use . Th e compan y ha s reduce dit s projecte dannua l usag eP. 6

/ ^ 

### Sit e Visi t Repor t - Picken' s Plastic s Pag e 5 o f aceton e fro

m 70,00 0 pound s t o 50,00 0 pounds . No methylen e chlorid e an dno ozone-depletin g chemical s ar e use da t th e facility . Th e facilit y

dispose s o f no unpolymerize dresi nwaste . Smal l amount s o f SMC occasionall y

polymeriz e i nstorage , whic har e the ndispose do f a s non hazardou s material . Th e facilit y i s categorize da s a smal l quantit y hazardou s wast e generato r (les s tha n1,00 0 kilogram s pe r month) , an dit s hazardou s wast e consist s primaril y

o f spen t aceton e an

dpain t wast e an

dsolvents . Th e facilit y

ha s no hazardou s wastewate r issues ; plan t wate r i s dispose d o f throug hth e municipa l sewe r t o th e publicl y owne dwate r treatmen t facility . C . VOC/HA P Contro l Measure s Th e facility' s principa l VOC/HA P contro l measure s consis t o f th e us e o f a wax-typ e styren e suppressan t i nit s AR0P0 L resi nmi xan dth e replacemen t o f par t o f it s aceton e wit hEnvirosol v 200 0 ( a non-HA P product) . I nth e cas e o f th e styren e suppressant , san dblastin g o f th e molde dpar t i s necessar y t o remov e th e residua l wa xfro m th e par t surfac e prio r t o secondar y bondin g operations . (Methylen e chlorid e i s th e onl y chemica l mean s o f accomplishin g this. ) Th e company

estimate s tha t 6 percen t o f th e styren e conten t i s emitte d fro m th e vapo r suppresse dresin , versu s 1 1 t o 1 2 percen t fro m a nequivalen t nonsuppresse dresin . The y als o state dtha t approximatel y 98. 5 percen t o f th e vapor s emitte di nth e sprayupoperatio ni s styrene , whil e th e remainde r i s othe r volatil e compounds . (What types of volatile

compounds

are these?) 

### Finally , Mr . Picke npointe dou t tha t Envirosol v 200 0 i s no t a s effectiv e a cleane r a s acetone . V . Attachment s Picken' s Plastic s supplie dwritte nmaterial s t o provid e a bette r understandin g o f it s ra w materials , proces s operations , an demissions . Thes e material s fal l int o thre e categories : 1 ) Materia l Safet y Dat a Sheet s (MSDS's) , 2 ) Ohi o permi t application s fo r emittin g sources , an d3 ) VOC/HA P emission s calculation s a s submitte dt o th e Ohi o EPA . Attachmen t 1 consist s o f MSDS' s an dtw o letter s a s follows : a ) Alte k75-373 0 0L-LV S polyeste r resi n(Alpha Corp. ) b ) AR0P0 L Q-6022- S suppresse dpolyeste r resi n(Ashland ) c ) DION (R ) 33-597-0 0 halogenate dpolyeste r resi n(Reichhold ) d ) Luperso l DDM- 9 MEK P catalys t (Atochem ) e ) Letter : Ashlandt o Picken's , 1-21-93 . Confirmatio ntha t AR0P0 L Q-6022- S i s a styren e suppresse dpolyester . f ) Letter : Specialt y

Product s t o Hebert , 1-29-93 . VO C conten t o f "Styrid " vapo r suppressant . g ) "Styrid " vapo r suppressan t (Specialt y Product s Co. ) h ) Gra y ge l coa t (Coo kPain t & Varnish ) i ) Blac kge l coa t (Coo kComposite s an dPolymers ) j ) Pliogri p660 0 (Ashland )P. 7

/ / / 0 g

Sit e Visi t Report - Picken' s Plastic s Pag e 6 

### Attachmen t 2 consist s o f th e followin g permi t application s fo r spray an d tri m booths , a s submitte dt o the Ohi o EPA : a ) Resi nboot hB5- A b ) Resi nboot hB5- B c ) Resi nboot hB5- C d ) Ge l coatin g boot hB 6 e ) Trimmin g boot hB 8 (Station s S1-S6 ) f ) Finishin g boot hB 9 ( 2 fans , 2 stacks ) g ) Trimmin g an

dassembl y

boot hBI O Attachmen t 3 consist s o f Picken' s calculation s o f VO C conten t an d emission s fo r th e thre e representativ e resi nmixe s an dtwo ge l coats ./Colli e IVl ] li O T R-.1.1.1 n ^..'J-J/J O C7.~*.V=
. P. 8
iViierui l ijatt.c y L»at a S«X.* L l h e Alph aCorporatio n P . 0 . Bo

x 37 0 Collierville , T

n 3801 7 (901)853-261 5 Product : ALTE K75-373 0 QL-LV

S Interna l ID s ALTE

K75-373 0 CL-L V KSDf i Jto : ALPH

A / 24 2 Revision : Marc

h 20 , 198 9 Date : Novembe r5 , 199 1 SECTIO N IV . F1R

£ AN D EXPLOSIO

N DAT A ?~t~ r1 I ! ! I

* \ \ '. ! 1 ! 1 ! . ! 1 1 * ! ! * ! * ! ' t' \ \ •! * ! •* - t"i : M : i n- : :-H < :- u fr



## * 4 Flas h Poin t(nethod) : 88-92| F (CC ) Umits : HZ. % : 1. 1 OET.

. % : 6. 1 KFP A FlflnmabWOonbustibl e TAo-iu d Classification : I C KFP A Ftt e Hazar d Synto l Oxles : Flarmability : 3 Hsalth : 2 Reactivity : 2 Special * non e Extinguishin g Madia : \rate rfog , dr y chatiical , foam o r00 ^ Autoignitio n Temp : 9W| F Unusua l fix e ox* explosio n hazards : A televate d tecperatues , suc h a s i n afir e condition , polymerizatio n ma y tak e plac e resultin g i n violen t.ruptur e o f close d containers . Vfea rpositiv e pressur e apparatus , ey e protection , an d kee p vapor s awa y fro m possibl e ignitio n sources . .Special:fixe^idhtlngnrcoedittes : i f electrica l equipmai ti s involved , th e us e o f Handlin g equipmen tshool d b e coole d b y wate rstrea m i f expose d t o fire . ;;;;; ; • « !*!!!!!!!!!!?*!!*!!!!!!!?!!?!*.! ! H-: ; ; i ;;;;*, ! 

### 4 - SBCTIO N V . REACTIVIT Y DAI A ; : 1. 1 * . i i - •i •: •> i i 

# * 4 Materia l i s stabl e . Ibzarduu s polymerizatio n na y occu r. Oiamica l Anaocipatibilities : Acids , oxidizin g agents , fre e radica l initJLator s suc h a s peroxides , an d metalli chalide s an d soaps . Condition s t o avoid : sunlight , ope n flanes , contamination , an d prolonge d sLurag e abov e 75] . Hazardou s deoOnpositio n Products : carbo n n-onoxide . carto n dioxide , an d lo wrolecular •weigh thydrocarbons . •s tis .:::: : i: n :::'. : '.'.'.'.'.'.'.'.'.'.'.'.'.'.

........ . SECTlCt- VT . HEALT

H HAZAR

D INFORMATIO N iiiii i Thi s produc ti s considere d a-possibl e carcinoge n b y IARC. * Suooar y o f

risks : Cause s irritatio n t o throat , eyes , 6ki n an d nose . Harmfu l i f

inhaled . Madiaa l condition s vhic h may b e aggravate d b y contact : Ka y aggravat e pre-e > respirator y an aski n targe torgans : CNS , respirator y system , lungs , eye s an d skin . Prinsii y entr y route(s) : inhalation , ingestion , contact . iers .

Pag e 2 — HEALT H HAZAR D INFORMATIO

N continue s o n pago . 3 Pag e 2

U0V - 5-9 1 TU E 15:4 7 ? e l p ' HCV - 5-9 1 TU E mZ'.Al 'v . ? • ZI 1 ?• ' • ' P . M ' 

## 7P. 9



### ATTACHMEN T 1 Th e Alph aCorporatio n P . 0 . Box*37 0 Collierville , Tn 3801 7 (901)853-261 5 Pnxluct : ALTE K75-373 0 CL-LV

5 Interna l ID i ALTE

K75-373 0 CL-L V *ED S NJ : AIJ'H

A / 24 2 Pevisinn : Parch 20 . 198 9 Date : Novarbe r5 , 199 1 Nationa l Pain t an d Coating s Associatio n Hazardou s Materia l Identi f icatio n Syste m 1 1 1 

### 4-*-*- 4-H HEALT H HAZARD j FLAMXABTT.TTY HAZARD j RFACT1VTT Y HAZARD j PERSONA L PROTECTIO N | 2 3 2 I i i 1 

## 4 - S.ECTIO N I . KATERIA

L IDENTIFICATIO

N Tcade/fcateria l Name : ALTE K75-373 0 OL-LV

S Description : Diacid/Glyco l condensat e CAS : mixtur e Trad e Secre tRegister : N/ A Chemica l N&ae* Pr>1*YF>st*»* rP<=>fi-i n Manufacturer* : Alph aResin s Corporatio n Phone : (901)85 3 2615 ) SECTIO N II . IN3*ED1EN1 S AN D HAZARD

S ! Ingredien tName : Styr*eu e Alpt o Msthy l Styren e SAR A 31 3 INFDRMAT

l V: th e reportin g reo an d Reauthorizat I CA S Number : 100-42- 5 98-83- 9 I-taroent :

42-50% * 0-3% * Ejrrjoeuxe Limits :

5 0 pp m TWA : 10 0 Pit t

- 0 pp m TWA : 10 0 pp m

. s produc tcontain s th e abov e substanc e whic h i s subjec tt o j o l sectio n 31 3 o f

Titl e II I o f

th e Superfun d Amendment s j f 198 6 an d 4 0 CF

RPar t372 . * weigh tPercent . 

## 4 - SBCTIO N III . PHYSICA

L UAT A Appearanc e & Odor ; Visoou s Liqui d wit h aSwee tPungen tOdor . .Boilin g point : 293l F Specifi cgravit y (ao=ll : 1. 0 - 1. 1 Vapo rpressure : <4. 5 vrtOq *-=_I*--*_\*IL_.,_I.

_.... Vfete rs^ubiHt y (%) : ver y sligh t Vapo rdensit y (air^l) : 3. 6 ^ cavit y (ItO=l) : 1. 0 •Haltin g Joint : N/

A
Pag e 1 Post-It " bran d fa xtransmitta l mem o 7ip 1 |t» « pag-* * » ££ 

### Te 

# f H 

# ,\K<^>-ur
C*pt . *»1 * 

## TZfjLLidmS C o P.'IOO f » tm- - NOV - 5-5 1 TU E 15:4 6 HOV - 5 -•'-• ] T..- F IT:** ? 91 ? 1 S 5 * 1 Pag e 1



## <hP.1 0

Materia l Safet y Dat aShee t Th e Alph aCorporatio n .Product : ALTE K 75-373 0 OL-LV

S n .J' ° : -if° xIZ 0 TMTM.
. Interna l ID: ALTE K 75-373 0 .KSD S NO : ALPH

A / 24 2 Itevisicn : Marc h20 , 198 9 cate : Jtoveribe r

5 , 199 1

i • « i i . . J . i i HEALT H HAZAR

D DtTCRMATlC

N continue dfro mpag e 2 ••••• • : : ••-'- :::! : • •••:::: : iv-H-:::;:::::::::*.: { :*;•*•;: : H-H-H:;;:; : ;::::!*•-> * Acut e effects : Ma

y irritat e eyes , nose , tliroat , an dskin
. Chroni c effect(e) t

*fa y caus e victi mt o fee l drugged , sleep y o r becom e unconscious
. Repeate dski n contac t na y caus e rash
. Ka

y affec t th e brai no r

nervou s system , causiji g dizziness , headach e o r nausea . Report s hav e associate drepeate dan d prolonge doccupationa l overexposur e t o solvent s wit hpernanen t brai nan dnervou s syste mdairage
. Intentiona l misus e b y deliberatel y concentratin g an dinhalin g th e content s ma

y b e harmfu l o r

fatal
. Sign s & synptas s o f

overexposure : Ey e contact : Cause s irritatio nt o th e eyes . Ski ncontact : Ma

y caus e irritatio nt o th e skin
. Inhalation : Ma

y irritat e eyes , nos e aivdthroat
. Ma y fee l drugged , sleepy , o r

unconcious
. Ingestion : Ma

y caus e victi mt o become vvea k an dunsteady
. Firs t aid :
iftaterial. ) S u n contact ! Was

hexpose dski n-wit

hsoa p an dvater . Ge t medica l attentio ni f

irritatio ndevelopes
. Remov e contaminate d clothing , shoes , an dthoroughl y clea nbefor e reuse . Inhalation : Mov

e expose dperson(s ) t o fres hair
. Ge t medica l attention
. Ingestion : D

O N3 T induc e vomiting
. Cal l Physicia ninnediately
. *Fo r hazar dcomnunicatio n purpose s unde r OSH A Standar d2

9 CTR Par t

1910.1200 , styren e i s liste da s apossibl e carcinoge nt y IARC
. Neithe r th e dat afro mvariou s long-ter m anima l studie s no r

fro mepidemiolog y o f

worker s expose dt o styren e provid e a n adequat e basi s t o conclud e tha t styren e i s carcinogenic
.

Pag p 3 —MSD 6 24 2 continue s o npag e 4 —Pag e 3

NOV - 5-9 1 TU E 15:4 ? ?C< ! S5 ? 152 5Materia l Safet yDat a Shee t p.1 1

Th e Alph aCorporatio n P . 0 . .BoxNr/

Q Collierville , Tn 3801 7 (901)853-261 5 .ProductJ .ALTE K7S- 3 Interna l ID : AL

T 

### O M MSD S tto : ALPH

A / 24 2 Revision : March- 3«7 2 ia& a Date : Noveibe r5f°^|i B 9 

# m

+-H - 

### ! SECnCNvii ! spiii ' 'LEAK'AN D DISJ-CSA

L

### 'wsixiiixJKis ' ""•••••••*•**"• } tpiuiiii,;, 1 , I.I,.,. 1 ••—• • . i i i i . . . i . I ' . : ; ! : . . ! 1 t... . . ! } . i ... » t««....> . 1 Spil l / I^aa kprocedures : Remove al l source s o f ignition , ventilat e area . Epgyen t •materia l fro m enterin g drains . Absorben tshoul d B e vermicalite , dr y sara' & garfh * Stal l Spil l - Soa ku p vit h absorben tan d scoo p int o drums . Larg e Spil l - Dik e an d pum p int o drums . •test e sanaganen t/

Disposal : Dispos e o f accordin g t o local , stat e an d federa l regulations . -eaera r 

## 3 1 SECTIO N VIII . SPECIA L l^OTBCriO N INFCJRMATIO N

. . . I . . I Persona l protectiv e equipment : Goggles : Us e chemica l goggles . Gloves : Us e glove s o f rubbe ro rothe rresistan tmaterial . Reepiratar j Chemica l cartridg e respiraLo rwit h NIOSH/OSH A approve d organi cXBDor cartridg e t o 40 0 ppm . A texposure s abov e 40 0 pp m us e a n '§§gj p ^P 0 * Other : Us e chemica l resistan tapron s o rcoat s t o avoi d ski n contact . Workplac e considerations : VentUation : loca l exliaus ti s preferred . Mechanica l ventilatio n I s a

U.s e explosio n proo f

eqoipmenL . •Safet y stations :

Safet y shower s en d ey e was h station s ajre recommended . Contaminate d equipment :

Clea n contaminate d equipmen twit h a n appropriat e solven t 

### storage . - 

# •pis ? fe I SECTIO N IX . SPECIA

L PRECAUTION

S Storag e segregation : Stor e i n acoo l dr y plac e away frc m incctnpatabl e figfcgf j-flj g • Specia l handlin g /

storage : Stor e i n a n are abelo w75I F an d ou to f direc tSunJiflbt . Kee p frc m heat , spark , an A srokin g areasT^fr^ 1 1 ^ • container s ma

y b e hazardous . uifrc y tt-a-iiraaering controls : fcjuipmentshoul d b e grounde d durin g transfe ran d non-s , ^ ^ CArr|> s shoul d b e used . " lu
- ni ~~l Pag-e 4 SP.BCIA L pRECAuna ccontinue s o n pag e 5



### ( 0P.1 2

11/05--3 1 13:4 2 HLFH H RESIN S CCf-P . 00 5

Materia l Safet y Dat aShee t Tb e Alph aCorporatio n P
. 0
. Box*37 0 Collierville , Tn 3801 7 (901)853-261 5 Product : ALTE R75-373 0 OL-LV

5 Interna l ID : ALTE

K 75-373 0 Or-L V MSD S Ifo : ALPHA

. / 24 2 Revision : Marc h2 0 Date : Novembe

r 5

# fisl i 8 9

+-s - .•- TJ.I. I •T- H i! : SPECIA LPPECfiim.OLjS oori^ue df

re mpage 4 4 -.i. i ::i::i:::: 

### l Othe r precautions : D

o no t transfe r

t o unlabele dbottle s o r containers
. DO T Class : Flammabl e Liqui dU N Register : UN-186 6 Prepared/revise dby : ROBER T RAUAR D Marc h20 , 198 9

The informatio ncontaine dherei ni s base donth e dat aavailabl e t o u s an di s believe d t b b e oorrect . Uo warranty , exoresse do r implied , i s mad

e requardin g th e accurac y o f thi s dat ao r

th e result s t o b e obtaine dfro mth e us e thereof
. Alph aResin s Corporatio nassure s n o responsibilit y fo r .injur y fro mth e us e o f th e product
. Pag e 5 Erxio f MSD S 242 Pi- a llP.1 3

JiWJ Lit-z -,..U/ "ATTENTIO N DIRECTO R O F PURCHASING : Al l shlpmerv.s

—— ^ shal l be Governe d b y th e Term s an d Condition s o n th < ..•a**---**^ £sq H | ^ K m rwPMTro i revVjBe- side . Acceptanc e o fdelivery shal l b e deeme d hav e ACU I AM n PHPMTrA i reversa-side. Acceptanc e o fdelivery shal l b e de < WS, SZ TM- *"i , **,•*$•*¥* •Pl,fc uc h Provisions . N o othe rterm s shal l 3IDIAR YO F ASHLAN^^p3nie S ^K^Itln o signe d b y Seller . hlan d Chernical . Inc . SUB S
_ iDsidiar y o

fAshlan d Oil . Inc . p.o . BO X2219 , COLUMBUS/'OHYO " 4321 6 

### (614 ) 889-333 3 AROFO L Q 602 2 S 

### ENTERE D JA U 1 0 19S^ ABE | A 

### HI S MSD S COMPLIE S WIT H 2 9 CF R 1910.120 0 (TH E HAZAR D COMMUNICATIO NSTANDARD )

24-HOU R EMERGENC Y TELEPHONE : 1-800-ASHLAN D O R 1-800-274-526 3 :0DUC T NAME : AROPO L G l 602 2 S DAT ASHEE T NO : 0260149-00 1 PREPARED : 10/04/9 1 SUPERSEDES : ( N/ A)

SECTIO NI-PRODUC T IDENTIFICATIO N ENERA L O R GENERI C ID : UNSATURATE D POLYESTE R RESI N O T HAZAR D CLASSIFICATION : FLAMMABL E LIOUI D (173.115 )
SECTIO NII-COMPONENT S
; F PRESENT , IARC , NT P AN D OSH ACARCINOGEN S AN D CHEMICAL S SUBJEC T T O TH E REPORT
IN G REQUIREMENT S O F SAR ATITL E II I SECTIO N31 3 AR E IDENTIFIE D I NTHI S SECTION . SE E DEFINITIO NPAG E FO R CLARIFICATIO N INGREDIEN T */. (B Y WT ) NOT E POLYESTE R RESI N* 50-5 5 ( 1 ) 3TYRENE -4 6 (2 ) CA S # : 100-42- 5 PEL : 5 0 PP M TLV : 5 0 PP M ( 1) : PEL/TL

V NO T ESTABLISHE D FO R THI S MATERIA L
* 2) : ACGI H /OSH

ASHOR T TERM EXPOSUR E LIMI T (STEL ) FOR STYREN E MONOME R I S 10 0 PPM . NIOS H RECOMMEND S ALIMI T O F 5 0 PPM , 8-HOU R TWA , 10 0 PP M 1 5 MINUT E CEILLINE . THI S CHEMICAL I S SUBJEC T T O TH E REPORTING REOUIREMENT S O F SECTIO N31 3 O F SAR ATITL E III . K TH E SPECIFI C CHEMICAL NAM E O F THI S COMPONENT I S BEIN G WITHHEL D A S ATRAD E SECRET .


## |2 >yiZStt i -Um Z f jm,.'<Lmm. l ..shlah d Chemical . Inc . Subsidiar

y o l Ashlan d Oil . Inc . P.1 4
LUimriUc D O N -ATTENTIO N DIRECTO R OF PURCHASING : Al l shipment s shal l b e Governe

d b y the Terms an

d Condition s o n th e revers e side . Acceptanc

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e deemed Anno m n *«-,*->-

> acceptanc

e o f auc h provisions . No otne r teirorahal l hav

e ARUPU L G 60-.^ e | fectun | ess , nwrtt , nfl8lgne< , bySe „ e fFACE S Z
SECTIO N111-PHYSICA L DAT A
PROPERT Y REFINEMEN T MEASUREMEN T FOILIN G POIN T FO R COMPONENT ( 46V. )
,'APO R PRESSUR E .
SPECIFI C VAPO R DENSIT YAI R = 1 SPECIFI C GRAVIT Y

-'ERCEN TVO L ATI LE S " IVAPORATIO N RAT E APPEARANC E 3TAT E -OR M 293.4 0 DE G F ( 145.2 2 DE G C )

- 3 760.0 0 MMH G FO R COMFONENT (

AI R = 1

i

• 467. ) 4.5 0 MMH G 6 6B.0 0 DE G F ( 20.0 0 DE G C ) 3. 6 1.05 2 - 1.08 8 €77.0 0 DE G F ( 25.0 0 DE G C )

45-507 . SLOWE R THA NETHE R

HAZ Y BLU E

. LIQUI D HOMOG SOL N

SECTIO N IV-FIR E AN D EXPLOSIO N INFORMATIO N •LAS H POIN T ( .73. 0 - 22. 8 -' • 100. 0 DE G F

37. 8 DE G C ) IXPLOSIV E LIMI T (LOWES TVALU E O F COMPONENT ) LOWE R 1.17 . UPPE R . - 6*17 . IXTINGUISHIN G MEDIA : REGULA R FOA M O R WATE R FO G O R CARBO NDIOXID E O R DR Y CHEMICA L HAZARDOU S DECOMPOSITIO NPRODUCTS : MA Y FOR M TOXI C MATERIALS: , CARBO NDIOXID E AN D CARBO NMONOXIDE , VARIOU S HYDROCARBONS , ETC . r IREFIGHTIN 6 PROCEDURES : WEA R SELF-CONTAINE D BREATHIN G APPARATU S WIT H AFUL L FACEPIEC E OPERATE D I NTH E POSITIV E PRESSUR E DEMAN D MOD E WHE NFIGHTIN G FIRES . SPECIA L FIR E & EXPLOSIO NHAZARDS : VAPOR S AR E HEAVIE R THA NAI R AN D MA Y TRAVE L ALON G TH E GROUN D O R MA Y B E MOVE D B Y VENTILATIO NAN D IGNITE D B Y PILO T LIGHTS , OTHE R FLAMES , SPARKS , HEATERS , SMOKINS , ELECTRI C MOTORS , STATI C DISCHARGE , O R OTHE R IGNITIO NSOURCE S AT LOCATION S DISTAN T FRO M MATERIA L HANDLIN G POINT . AL L FIV E GALLO NPAIL S AN D LARGE R META L CONTAINER S INCLUDIN G TAN K CAR S AN D TAN K TRUC.£? } SHOUL D B E GROUNDE D AND/O R BONDE D WHE NMATERIA L I S TRANSFERRED . -''•.T" ' VZZ

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CONTINUE D ON"ATTENTIO N DIRECTO R O F PURCHASING : Al l shipment s E'^l_ ! ahal l b e governe

d b y th e Term s an

d Conditions o n th e JffZk&P 1 revers e side . Acceptanc

e o f dellvw y shal l b

e deeme d -^___

_acceptanc e o f auc h provisions . No othe r terms . JbaJI hav

e •^j^ndChenriiCal.lnc . AROPO L Q 6022 e ffec t unles s I n writin g signe

d b y Seller. FA&t . - i jubsidiaryo t Ashlan d Oil . Inc . , '
_ __ _

SECTIO NIV-FIR E AN D EXPLOSIO NINFORMATIO N(CONTINUED )
POLYMERIZATIO NWIL L TAK E PLAC E UNDE R FIR E CONDITIONS . I F POLYMERIZATIO N OCCUR S I NACLOSE D CONTAINER , THER E I S APOSSIBILIT Y I T WIL L RUPTUR E VIOLENTLY . COO L STORAG E CONTAINE R WIT H WATER , I F EXPOSE D T O FIRE . -FP ACODES : HEALTH
- 2 FLAMMABILITY
- 3 REACTIVITY
- 2

SECTIO NV-HEALT H HAZAR D DAT A. I PERMISSIBL E EXPOSUR E LIMIT : NO T ESTABLISHE D FO R PRODUCT . SE E SECTIO NII .

E EFFECT S O F ACUT E OVEREXPOSURE : -VFQ"~CAN~CAUS E SEVER E IRRITATION , REDNESS , TEARING , BLURRE D VISION . 3KI N- PROLONGE D O R REPEATE D CONTAC T CAN.CAUS E MODERAT E IRRITATION , DEFATTING , i f WATHIN G - EXCESSIV E INHALATIO NO F VAPOR S CA NCAUS E NASA L AN D RESPIRATOR Y

IRRITATION , CENTRA L NERVOU S SYSTE M EFFECT S INCLUDIN G DIZZINESS , WEAKNESS , FATIGUE . NAUSEA , HEADACH E AN D POSSIBL E UNCONSCIOUSNESS , AN D EVE NDEATH . SWALLOWIN G - CA NCAUS E GASTROINTESTINA L IRRITATION , NAUSEA, . VOMITING , AN D .j , DIARRHEA . '.". . y\ -IRS T AID : .. , . . ' Tp'rnTsKIN
- THOROUGHL Y WAS H EXPOSE D ARE AWIT H SOA P AN D WATER . REMOVE . CONTAMINATE D CLOTHING.
- LAUNDE R CONTAMINATE D CLOTHIN G BEFOR E RE-USE .

~ ~ I F I NEYES : FLUS H WIT H LARG E AMOUNT S O F WATER,.LIFTIN G UPPE R AN D LOWE R LID S

nr-CASIONALLY , GE T MEDICA L ATTENTION :

~ r r FALLOWED : D O NO T INDUC E VOMITING , KEE P PERSO NWARM , QUIET , AN D GE T MEDICA L

- F ATTENTION . ASPIRATIO NOF.MATERIA L INT O TH E LUNG S DU E T O VOMITIN G CA N CAUS E CHEMICA L PNEUMONITI S WHIC H CA NB E FATAL . T F BREATHED : I F AFFECTED , REMOV E INDIVIDUA L T O FRES H AIR . I F BREATHIN G I S DIFFICULT.ADMINISTE R OXYGEN. " I F BREATHIN G HA S STOPPED , GIV E ARTIFICIA L n o RESPIRATION . KEE P PERSO NWARM , QUIET , AN D GE T MEDICA L ATTENTION . J.L 5 • I d PRIMAR Y ROUTE(S ) O F ENTRY : . . ° " INHALATION , SKI NCONTAC T

^ EFFECT S O F CHRONI C OVEREXPOSURE : • ' ' 'rf, ^INTERNATIONA L AGENC Y FO R RESEARC H O NCANCE R (IARC ) HA S CLASSIFIE D STYREN E 111 I NGROU P 2 B (POSSIBL Y CARCINOGENI C T O HUMANS) . THI S CLASSIFICATIO NI S NO T ." . F.ASE D O NAN Y SIGNIFICAN T NE W EVIDENC E THA T STYREN E MA Y B E CARCINOGENIC , ' ^ WI T FATHE R O NAREVISE D DEFINITIO NFO R GROU P 2 B AN D CONSIDERATIO NO F NE W ?- ° DAT AO NSTYREN E OXIDE . ANUMBE R O F LIFETIM E ANIMA L STUDIE S WIT H STYREN E n* ? INCLUDIN G THOS E CONDUCTE D I NTH E NC I BIOASSA Y PROGRA M HAV E NOT . SHOW N i l 3 ' STYREN E T O B E CARCINOGENIC . . rf ] OVEREXPOSUR E T O STYREN E HA S APPARENTL Y BEE NFOUN D T O CAUS E TH E FOLLOWIN G -r!" . EFFECT S I NLABORATOR Y ANIMALS : LIVE R ABNORMALITIES , KIDNE Y DAMAG E AN D /r'" 1 L'J'.T

- PAMA ^ 

# / sP.1 6 

## irssnl LifQffiicsi
Ashlan d Chemical . Inc : SuDsidian y o'

Ashlan d Oil . In c * *r+C- i \*s ••& ij CONTINUE D ON-^TTENTio A DIRECTO R O F PURCHASING : Al l ahlpment s shal l b e governed b

y the Term

s snd Condition s o n th e revers e aide . Acceptanc

e o fdeliver y ahal l b

e deemed Acnon i n /.^oo 8 *cP e P tar,C € o f* u c h provisions . N

o other temw.ahaJ I hay

e AROPO L Q 6022 e ^ unles8lnwr|tln , g s ^ r>e< , bvSeI|er #•PfiBE" : T f

SECTIO NVI-REACTIVIT Y DAT A
HAZARDOU S POLYMERIZATION : CA NOCCUR —AVOI D EXPOSUR E T O EXCESSIVE HEAT , PEROXIDE S AN D POLYMERIZATIO NCATALYSTS . STABILITY : STABL E INCOMPATIBILITY : AVOI D CONTAC T WITH: , STRON G ALKALIES. , STRONG MINERAL ACIDS .
SECTIONVII-SPIL L O R LEAK PROCEDURE S
STEP S T O B E TAKE NI NCAS E MATERIA L I S RELEASE D O R SPILLED : SMAL L SPILL : ABSOR B LIQUI D ONPAPER , VERMICULITE , FLOO R ABSORBENT , O R OTHE R ABSORBEN T MATERIA L AND TRANSFE R T O HOOD . LARG E SPILL : ELIMINAT E AL L IGNITIO NSOURCE S (FLARES , FLAME S INCLUDIN G PILO T LIGHTS , ELECTRICA L SPARKS) , PERSON S NO T WEARIN G PROTECTIV E EQUIPMENT . • SHOUL D B E EXCLUDE D FRO M ARE AO F SPIL L UNTI L CLEAN-U P HA S BEE NCOMPLETED . STO P SPIL L A T SOURCE , DIK E ARE AO F SPIL L T O PREVEN T SPREADING , PUM P LIQUI D T O SALVAG E TANK . REMAININ G LIQUI D MAY B E TAKE NU P O NSAND , CLAY , EARTH , FLOO R ABSORBENT , O R OTHE R ABSORBEN T MATERIA L AN D SHOVELE D INT O CONTAINERS . WAST E DISPOSA L METHOD : SMAL L SPILL : ALLO W VOLATIL E PORTIO NT O EVAPORAT E I NHOOD . ALLO W SUFFICIENT TIM E FO R VAPOR S T O COMPLETEL Y CLEA R HOO D DUC T WORK . DISPOS E O F REMAININ G MATERIA L I NACCORDANC E WIT H APPLICABL E REGULATIONS . LARG E SPILL : DESTRO Y B Y LIQUI D INCINERATIO NI NACCORDANC E WIT H APPLICABL E REGULATIONS . , . . CONTAMINATE D ABSORBENT MA Y B E DEPOSITE D I NALANDFIL L I NACCORDANC E WIT H LOCAL , STAT E AND FEDERA L REGULATIONS .

SECTIO NVIII-FROTECTIV E EQUIPMEN T T O B E USE D RESPIRATOR Y PROTECTION : I F WORKPLAC E EXPOSUR E LIMIT(S ) O F PRODUC T OR ANY COMPONENT I S EXCEEDE D (SE E SECTIO NII) , ANIOSH/MSH AAPPROVE D AI R SUPPLIE D RESPIRATO R I S ADVISE D I NABSENC E O F PROPE R ENVIRONMENTA L CONTROL . OSH AREGULATION S ALS O PERMI T OTHE R NIOSH/MSHARESPIRATOR S (NEGATIVE PRESSUR E TYPE ) UNDE R SPECIFIE D CONDITION S (SE E YOU R SAFET Y EQUIPMENT SUPPLIER) . ENGINEERIN G O R ADMINISTRATIV E CONTROL S SHOUL D B E IMPLEMENTE D T O REDUC E EXPOSURE . VENTILATION : PROVID E SUFFICIEN T MECHANICA L (GENERA L AND/O R LOCAL EXHAUST ) VENTILATIO NT O MAINTAI NEXPOSUR E BELO W TLV(S) . .-ROTECTIV

E GLOVES : WEA

R RESISTAN T GLOVE S SUC H AS: , POLYVINY L ALCOHO L EY E PROTECTION : CHEMICA L SPLAS H GOGGLE S I NCOMPLIANC E WIT H OSH AREGULATION S AR E ADVISED ; HOWEVER , OSHAREGULATION S ALS O PERMI T OTHE R TYP E SAFET Y GLASSES . (CONSUL T YOU R SAFET Y EQUIPMEN T SUPPLIER ) .TTHE R PROTEC T 1 ^ EQUIPMENT : NORMA L WORK CLOTHING COVERIN G ARM S AN D LEGS .P.1 7

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fAshlan d Oil . Inc . 6t> —effec t unles s I n wrhln g signe

d b y Seller . PtffeiE : 5 SECTIO N IX-SPECIA

L PRECAUTION S O

ROTHERCOMMENT S
CONTAINER S O F THI S MATERIA L MA YB E HAZARDOU S WHEN EMPTIED . SINC E EMPTIE D CONTAINER S RETAI N

PRODUC T RESIDUE S (VAPOR , LIQUID , AND/ORSOLID ) AL L HAZAR D PRECAUTION S GIVEN I N THI S DATASHEE T MUS T B E OBSERVE D ZXPOSUR E T O AEROSOL S AN D MIST S WHE

N MATERIA

L I S SPRAYE D MA

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YFRO M COMPONENT S BECAUS E HIGHE RCONCENTRATION S AR E I N TH E ATMOSPHER E THA

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N ACCUMULATE D HEREI N I S BELIEVE D T O B E ACCURAT E BU T I S NO T WARRANTE D T O B E WHETHE RORIGINATIN GWIT H TH E COMPAN

YO RNO T RECIPIENT S AR E ADVISE D T O CONFIR M I N ADVANCE OF NEE D THA T TH E INFORMATIO

N I S CURRENT , APPLICABLE , AN D SUITABL E T O THEI RCIRCUMSTANCES .



# e i 7P.1 8 

# MATERIA L SAFET

YDAT A SHEE T Informatio n Telephon e No. . (BOO ) 874-180 7 I n Non h Carolin a Coll . (800 ) 342-720 1 REICHHOL D CHEMICALS . INC . PO.Box1358 2 Researc h Triangl e Park Durham . N C 2770 9 AL L CHEMICA L EMERGENCIE S 

### 1-800-424-930 0 Issue Date : 05/13/9 1 Pag e i 5SsxxxxBsseBsxssssxxxxssssesxsssassessBsxsxsBBSSBEEBSB«B» « SECTIO N I - PRODUC T IDENTIFICATIO N Produc t Code : Trad e Name : Formerly : Produc t Class : C.A.S . Numbe r HMI S Rating : 33-597-0 0

D10N(R ) 33-597-0 0 Kopper s DIO

N F R6604 T Unsaturate dhalogenate dpolyeste r Mixtur e Healt h« 3 Fir e * 2 Reactivit y !s:::c:e::EStc£c:E::e:c:££;ictss:s=:=a::x:c>c:t:=issc:Escscec:etisiecacste 3 SECTIO N I I - INGREDIENT S Ingredient s CA S « Ueigh t Exposur e ma x. X Limit s Polyeste r resi n Styren e Monome r Epichlorohydri n Methylen e Chlorid e Proprietary 100-4E- S 106-89- 8 75-09- E 80. 0 Non e assigne d

40. 0 50. 0 pp

m 0.5 0 S. O pp

m 1. 5 50. 0 pp

a ee xssssssss i :sssxxsssssssxsssESSssssESXSXKBBBSSBSSSSBBBBSSBBCBBBBSBSBsssB C SECTIO N II I - PHYSICA

L DATA Boiling Poin t Volatil e '/.• Evap . Rate : Appearance : £9 5 Deg . F .

4 0 b y weigh t . Slowe rtha n n-Buty l Acetat e Liqui d wit h pungen todor . Vapo r Density : Heavie r tha n Air . Specifi c Grav : 1.1 5 - 1.2 0

BBBSSSSXSSSSSSSSSBESSSSSSSSSSSSSSSSSSBBSSSSSSSSSSSSSSSSSSBBESEBBSBBEBBSSSBBB I SECTIO N I V - FIR E AN

D EXPLOSIO

N HAZARD DAT

A Flas hPoint : 8 5 Deg . F , Flammabilit y

Class : I C -EXTINGUISHIN

GMEDIA : Wate r spray , foam , dry chemical , carbondioxid e o r an y Clas s 6 extinguishing agent . -SPECIA L FIREFIGHTIN

GPROCEDURES : Firefighter s an

dother s exposedt o vapor s o r product s o f combustio nshoul dwea r self-containe dbreathing apparatus . Equipmen t shoul dbe thoroughl y decontaminate dafte r use . -UNUSUA L FIR E ft EXPLOSIO

N HAZARDS : A t elevate dtemperatures , suc ha s ina fire , polymerizatio n ma y tak e place . I f polymerizatio ntake s plac e ina close d container , ther e i s th e possibilit y o f violent rupture.o f the container . Produc t vapor s ma y for m a nexplosive mixtur e inair . LE L : 1. 1

Th' n informatio n i t lurnithe d withou t warranty , representation , inducemen t o r licens e o l an y kind , ctcep t tha t i t i l accurate t o th e bea t o l Reichhol d Chemicals . Inc.' t knowledge , or obtaine d Iro m source ! believe d b > Reichhol d Chemical! . Inc . t o b e accurate , an d Reichhol d ChemicaH . Inc . doe s not assum e an y lege ' reiponiib'lit y lo r us t orrelianc

e upo n tam e Customer s ar e encour»se d t o conduc t thei r ow n test s fie lor

e usin g an

yproduct , rea d its label .P.1 9

« •U LI U O 0 o 

## MATERIA L SAFETYDAT A SHEE T Informatio n Telephon e No. : (600 ) 874-180 7 I n Non h Carolin a Call : (800 ) 342-720 1 REICHHOL D CHEMICALS . INC . P O Bo x1358 2 Researc h Triangl e Par k Durham . N C 2770 9 AL L CHEMICA L EMERGENCIE S 

### 1-800-424-930 0 Produc t Code : 33-597-0 0 Issue Date : 05/13/9 1 Page c B S B*:SBSKSESBSCB S = ESESBEBSSSEBESESECSES=KSSXESSSEeBBBSBBEKBBSBBSBBBBBBEEBBBBBBB B SECTIO N V - HEALT H HAZAR

D DATA -PERMISSIBL E EXPOSUR E LEVEL : OSH A PE L en

dACGI H TL

V fo r styren e are both5 0 pp m fo r a n8-hou r Tim e Weighte dAverag e (TUA) . The OSH A an dACGI H Shor t Ter

m Exposur e Leve l (STEL ) ar e 10 0 pp m fo r a 15-minut e period . Exposur e t o styrene ma y excee dth e STE L durin

g a 15-minut e period(n

o ceiling fo

r brie f exposures) , howeve r th e averag e fo r a singl e STE L periodmus t no t excee d10 0 ppm . The OSH A PE L an

dACGI H TL

V fo r epichlorhydri nar e Epp m fo r an 8-hou r TWA . Ski nhazardnoted . Th e ACGI H TL

V fo r methylene chlorid e i s 5 0 pp m for a n8-hour TUA . The OSH

A PE L fo

r methylene chlorid e i s 50 0 pp m fo r an 8-hour TUA . OSH

A ha s establisheda 1.00 0 pp m acceptabl e ceilin g concentratio nan

da 8,00 0 pp

m acceptabl e maximu m pea k for a duratio no f 5 minute s inan y 2 hours . Th

e OSH A limit s for methylen e chlorid e ar e currentl y being revisedunde r OSH A 6(b ) rulemaking . -EFFECT S OF OVEREXPOSURE : SKIN : Prolonge do r frequent contac t ma y caus e defattin g an d drynes s o f the ski nwit hresultan t irritatio nan dpossibl e dermatitis . Styren e ma y b e absorbe dthroug

hth e ski ni ntoxi c amounts . EYES : Ka

y caus e irritation . Liqui dsplashe s may resul t inmor e seriou s injuries . Ha y caus e lachrymatio n(tears) . INHALATION : Vapor s ma y caus e mucou s membrane irritatio nan d uppe r respiratory

trac t discomfort . Highconcentration s ma y resul t i nheadache , nausea , insensibilit y an dothe r centra l nervou s syste

m effects . Repeatedexposur e t o hig hconcentration s ma y caus e liver an

dkidne y damage . INGESTION : Ma

y caus e gastrointestina l disturbances , pai nan d discomfort . Epichlorohydri nma y be absorbe

dthroughth

e ski ni

nharmfu l amounts . Repeate doverexposur e t o epichlorhydri nma y caus e allergi c ski nreactions . Overexposur e t o epichlorohydri nma y caus e harmfu l effect s t o live r and/o r kidneys . Th e effect s o f epichlorhydri noverexposur e ma y b e delayed . Overexposur e t o methylen e chlorid e canrais e th e leve l o f carbo n monoxid e inthe bloodcausin g cardiovascula r stress . -FIRS T AID : SKIN : Uas hwit hsoa pan dwater . EYES : Flus hwit hcopiou s amount s of wate r fo r 1 5 minutes . See k immediat e medica l aid . INHALATION : Renove victim fro m exposure . I

f victi m

i s un conscious , administe r artificia l respirationand/o r oxyge na s (cont. )

Thi s inlormalio n i s lumishe d withou t warranty , representation , tnducemen t o r licens e o l an y kind , cicept lhat h i t accurat e t o th e best ot Reichhol d Chemicals . Inc.' t ' knowledg e or obtaine d Iro m source s believe d b

y Reichhol d Chemicals . Inc . t o b e accurate , an d Reichhol d Chemicals . In c does no t assum e an y lega l responsibilit y lo i us e o r tel.anc e upo n sem e Customer s ar e encourage d t o conduc t the! ' ow n tests . Eelo' c usin g an y product, rea d h s label .



### / aP.2 0 

# MATERIA L SAFET

YDAT A SHEET Inlormalio n Telephon e No. : (800 ) 874-180 7 I n Non h Carolin a Call : (800 ) 342-720 1 REICHHOL D CHEMICALS . INC . P O 8ox1358 2 Researc h Triangl e Par k Durham . N C 2770 9 AL L CHEMICA L EMERGENCIE S 

### 1-800-424-930 0

Issu e Date : 05/13/9 1 Produc t Code : 33-597-0 0
:S B CSSS S S S S BB S B SE E B' S SSBEe E CES S BSEBBCBEEECSSBS ! SECTIO N V - HEALT H HAZAR D DAT A (cont. ) Pag e 2 iccccacccc i
-FIRS T AID : (cont. ) needed . Seek medica l aid . INGESTION : D

O NO T INDUC E VOMITIN G(aspiratio

nhaierd) . Seek immediat e medica l aid . -PRIMAR YROUTE(S ) O

F ENTRY : Inhalatio nan

dSki nAbsorption . -CARCINOGENICITY : Th e Internationa l Agency fo r Researc ho

nCance r (IARC ) ha s classifie dstyrene a s possibl y carcinogeni c t o human s (clas s 2B> . The IAR

C 2 B classificationi s not base do nsignifican t ne w evidenc e tha t styren e might be a carcinogen , bu t o na revise d IAR C classificationschem e an dnew dat a o

nstyren e oxide . Epichlorhydri ni s liste da s a carcinoge nb y th e Nationa l Toxicology

Progra m (NTP ) an

dthe Internationa l Agency fo r Researc ho

nCance r (IARC) . Methylen e chloride i s listeda s a potentia l carcinoge nb y IAR C (clas s EB ) an

dNTP . ESS E SSS S EC S SSSS S BS E SS I rscssss s rSESSSSSSCBEBEBEEBBBBC : SECTIO N VI - REACTIVITYDATA tx D Stabl e Cx i Ha y occu r [ ] Wil l no t occu r STABILITY : t 3 Unstabl e HAZARDOU S POLYMERIZATION : -INCOMPATIBILITY : Strong acid s an

doxidizing agents . -CONDITION S T O AVOID : Hea t an ddirec t sunlight . -HAZARDOU S DECOMPOSITIO N PRODUCTS : Heating o f thi s materia l t o decompositionma y caus e the emissio no

f irritating , acri dfumes . SECTIO N VI I - SPIL L O

RLEA KPROCEDURE S -STEP S TO B E TAKEN I N CAS E MATERIA

L I S RELEASED O

RSPILLED : Remov e al l source s of ignition . Ventilat e area . Absorbspil l wit ha nabsorben t materia l sucha s sawdust , vermiculit e o r san dan dplac e ina close dcontainer . I f larg e spill , dik e th e are a t o preven t thi s materia l fro m enterin

g wate r system s or sewers . Thi s materia l contain s th e followin g ingredient s which , i f spille d o r release d i n quantitie s equa l t o o r greate r tha n th e Reportabl e Ouentit y (RQ) , ar e subjec t t o th e reportin g require - ment s o fCERCL

A and/o r SAR

A (4 0 CF

R Part s 30 2 i

355) : Styren e Monome r R Q Valu e * 100 0 lbs . (cont. ) thi ! intormatio n i s furnishe d withou t warranty , representation , inducemen t o r licens e o l an y kind , excep t that h i s accurat

e t o Ih e bes t o l Reichhol d Chemical! . Inc e knowledge , or obtaine d Iro m source s believe d b

y Reichhol d Chemicals . Inc . t o b e accurate , an d Reichhol d Chemicals . In c doe s no l assum e any leoa ! respo-uibilit y lo r us e o r relianc e upo n tame Customer s ar e encourage d t

o conduc

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# MATERIA L SAFET

YDAT A SHEET Inlormalio n Telephon e No . (800 ) 874-180 7 I n Noa h Carolin a Call : (800 ) 342-720 1 REICHHOL D CHEMICALS . INC . P O Bo x1358 2 Researc h Triangl e Par k Dpjrham . N C 2770 9 AL L CHEMICA L EMERGENCIE S 

### 1-800-424-930 0 Produc t Code : 33-597-0 0 Issu e Date : 05/13/9 1 Pag * 4 aESEBSEESSSS S ESS E SEBE E ESSE S SS E BB S ES S B E SSS S EBB S SS B BB S BBEEBBBSBSSSB E EB B SEBBBEBBBE B 

### SECTIO N VI I - SPIL L O

RLEA KPROCEDURE S (cont. ) -STEP S T O B E TAKE N

I N CAS E MATERIAL I S RELEASE D O RSPILLED : (cont. ) Epichlorohydri nR Q Valu e = 10 0 lbs . Methylen e Chlorid e R Q Valu e * 100 0 lbs . -UAST E DISPOSA L METHOD : Thi s materia l ha s bee nteste dan dfoundt o hav e a flas hpoin t below 14 0 F . I f discarded , thi s materia l an dcontainer s shoul d b e treate da s hazardou s waste s base do nth e characteristi c o f ignitabilit y

a s define dunde r th e federa l RCR A regulation s (4 0 CF R£61) . Disposa l o f thi s materia l an dit s container , require s complianc e wit happlicabl e labeling , packaging , and recor dkeepin g standards . Extrem e car e shoul db e take nt o ensur e tha t i

t i s dispose do f onl y i na facilit y

permitte dfo r disposa l o f hazardou s wastes . Fo r furthe r information , contac t you r stat e o r loca l soli dwast e agenc y o r th e Unite dState s Environmenta l Protectio nAgency' s RCR A hotlin e (1-800-424-934 6 o r 202-3S2-3000) . aESBSBSSSEBSSSSSS&SBSSSSSSSSSSSSSSSB&SBeSSSBSSSSSSBSSSKSBSBSSSSBSSSSBSBSKBSSBBS X



### SECTIO N VII I - SPECIA L PROTECTIO N INFORMATION -RESPIRATOR YPROTECTION : A canister-typ e respirato r ous t b e wor nt o preven t th e inhala tio no f vapor s o r spra y mist s whe nth e TLV o r PE L l s exceeded . -VENTILATION : Genera l ventilatio ni s require ddurin g norma l use . Loca l ventilatio nma y b e require ddurin g certai noperation s t o keepexposur e level s belo w th e TL V liste di nSectio nI I o f thi s dat a sheet . -PROTECTIV E GLOVES : Uea r appropriat e imperviou s glove s t o preven t ski ncontact . -EY E PROTECTION : Uea r fac e shiel do r chemica l goggles . -OTHE RPROTECTIV E EQUIPMENT : Uea r protectiv e clothin g t o preven t ski ncontact . Eye was hstatio nan dsafet y showe r shoul db e available . KSSSS&SSSSSSSSSS&BBSSSSSSSSSBSSSSSSSSSSSSSSSSSSSSSSSSSSBBSSS&SSSSSBBSBSBSSSSSS S 

### SECTIO N I X- SPECIA L PRECAUTION S -PRECAUTION S T O B E TAKE N IN HANDLIN GAN D STORING: Avoi dstorag e abov e 10 0 Deg . F . Avoi dprolonge do r repeate d ski ncontact . Avoi dinhalatio no f heate dvapor s o r spra y mists .

Thi s inlormalio n i t lumishe d withou l warranty , representation , inducemen t o r licens e o l an y kind , excep t that h i s aceurat

a t o th e best o l Reichhol d Chemicals . Inc' a knowledoe . orobtaine d hor n source s believe d b

y Reichhol d Chemicali.In c t o b e accurate , an d Reichhol d Chemicals . Inc . doe s no t assum e an y leoa ! responsibilit y lo r us e o r relianc e upo n sam i Cust : -r.c. ar e encourape d t

o conduc t thti r ow n lest ! 6tlc" t usin p any produc i rea d its label .



### n.\P.2 2


### fc 0 2 10 5 5 e 

# MATERIA L SAFET

YDATA SHEET Inlormalio n Telephon e No : (800 ) 874-180 7 I n Nort h Carolin a Call : (800 ) 342-720 1 REICHHOL D CHEMICALS . IN C PO.Bo x 1358 2 Researc h Triangl e Park Durham . N C 2770 9 AL L CHEMICA L EMERGENCIE S 

### 1-800-424-930

0 Produc t Code : 33-S9T-0 0 Issue Date : 05/13/9 1 SECTIO N I X- SPECIA

L PRECAUTION S (cont Pag e ) -OTHE R PRECAUTIONS : Avoi d imprope r additio n o f promote r and/o r catalyst . A promote r an d catalys t use d wit h thi s produc t shoul d alway s b e mixe d separatel y wit h th e produc t an d mus t neve r b e mixe d together . :sssss t :sssssssssss i SECTIO N X - SUPPLEMENTA L INFORMATIO N -REGULATOR YINFORMATION :

SCAQM D Rul e 116 2 establishe s specifi c process , control , housekeeping , an d recordkeepin g requirement s fo r fabricatio n operation s usin g polyeste r resi n materials . I t l s th e responsibilit y o f th e fabricato r t o ensur e complianc e wit h thes e requirements . Styren e i s NOTcurrentl y liste d a s a carcinoge n b y California' s Saf e Drinkin g Wate r an d Toxi c Enforcemen t Ac t o f 198 6 (Propositio n 65) . Epichlorhydri n i s liste d b y th e stat e o f Californi a a s a substanc e know n t o caus e cancer . Th e Californi a Saf e Drinkin g Uate r an d Toxi c Enforcemen t Ac t o f 198 6 (Propositio n £5 ) require s tha t clea r an d reasonabl e warnin g b e give n befor e exposin g an y Individua l t o epichlorohydrin . Methylen e Chlorid e (als o kno wa s dichloromethane ) i s liste d b y b y th e stat e o f Californi a a s a substanc e know n t o caus e cancer . Th e Californi a Saf e Drinkin g Uate r an d Toxi c Enforcemen t Ac t o f 198 6 (Propostio n 65 ) require s tha t clea r an d reasonabl e warnin g b e give n befor e exposin g an y individua l t o methylen e chloride . -SAR A HAZAR D CLASSIFICATION :

Thi s materia l ha s bee n categorize d a s havin g th e followin g hazard(s ) a s define d b y SARA Titl e II I regulation s (4 0 CF R 370 ) acute , chronic , fire , reactive . -SAR A SECTIO N 31 3 LISTE D INGREDIENTS '

Th e followin g ingredient s i n thi s reportin g requirement s o f sectio n [se e Sectio n I I fo r percentag e o f Styren e monome r (100-42-5 ) Epichlorohydri n (106-89-8 ) Methylen e chlorid e (75-09-2 ) -DO TPROPE R SHIPPIN G NAME :

Resi n Solutio n -U N NUMBER :

UN186 6 materia l ar e subjec t t o th e 31 3 o r SAR

A an d 4 0 CF R 37 2 ingredient(s) 3 :

Thi i informatio n i t lumishe d withou t warranty , represenution . inducemen t o r licens e ofan y kin d excep t that h i s accurate t o th e bes i o l Reichhol d Chemi:a! < Inc t knowledoe . or obtaine d Iro m source s believe d b

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### Ashland Chemical ^^^i3V L ^,^^J*^* ^ Composh e Polymer s DNlskx i AshUn d Chem'icsl , Inc . SubsW.ar

y o f Ashlan d Oil , inc . Aijdres s Rect y RO . 60x221 8 Columbus , Ohi o 4321 6



### Jsmuai y 21,199 3 Mr
. To mPicken Picken s Plastic s P
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saving s b y mean s o f reduce dresi nrequirements
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Ala nR
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Headquarter * MO O Blaze r Parkwa y OuWin.Ohto<30l T (eid)e55-333 2 Cabl e Address : Aropla z O H Telex : 24538 5 Answerback : ASHCHE M Fax : (6U ) 62 3 373 5 

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### )&taltty tUl$ana {Jhemunfs l 75 MONTGOMER Y STREE T A H C A COO S tO I C«kA»iA * «l">tltM<.''ivt » I TSU»»-<OM | 414-4TC C SPECIALTYPRODUCT S Co.LTD . v — ' P . O . BO X 30 6 rA " "•<"*~w

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### Faxed : Januar y 29 , 199 3

(3>1f i OQ**>-140fl )


### Mr . Te d Heber t T.J . Heber t Associate s 181 0 Meado

w Roa d Madison , Ohi o 4405 7 Dea r Ted : Thi e i e i n answe r t o your question s concernin g our product , Styrid . Styri dcontain s 53-55 % VO C (volatil e organi c compounds) . The VO C i s composed o f minera l spirit s i n it s entirety , whil e th e remainin g component s i n the formulationar e no t classifieda s VOC . A s I mentioned , th e Specifi c Gravit y

i s .7 9 gram s pe r cc . Thi s equal B t o a density o f 6.5 9 pound s pe r gallon . I als o mentionedt o yo u the stud y tha t had beendon e wit h Styri dan

d variou s polyeste r resins . The tes t tha t wa s conductedfull y

complie s wit hth

e styrene emission s regulations . Thi s informationwil l be sen t t o your offic e fo r you r revie

w an d files . I f yo u requir e an

y furthe r assistance , pleas e fee l fre e t o contac t us . Very trul y yours , 8FECIALTYPRODUCT S COMPAK Y 

# HSL Rau l D . Hernande z Technica l Departmen t 

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SECTIO N I V FIR E AN D EXPLOSIO N HAZAR D DAT A

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SECTIO N VII I SPECIA L PROTECTION INFORMATIO N

RESPIRATORY PROTECTION : D o no tbreath e o ringes tvapors , spra y mis to rdus tvhil e applying . sanding , grinding , o rsawin g cure d product . Wea ra n appropriat e properl y fitte d respirato r(NIOSH/MSHA approved ) durin g applicatio n an d othe rus e o f

thi s produc tunti l vapors , mist s an d dust s ar e exhausted , unles s ai rmonitorin g demonstrate s vapor , mis tan d dus tlevel s ar e belo w applicabl e limits . Follo vrespirato rmanufacturer' s direction s fo r respirato ruse . Observ e OSH A Standar d 29CF R1910.134 . VENTILATION : Provid e genera l clea n ai rdilutio n o rloca l exhaus tventilatio n i n volum e an d patter n t o kee p th e ai rcontaminan tconcentratio n belo wth e lowe rexplosio n limi tan d belov ; curren tapplicabl e exposur e limit s i n t h e mixing , applicatio n an d curin g areas ; an d t o remov e decompositio n produc tdurin g weldin g an d flam e cuttin g o n surface s coate d wit h thi s product . I n confine d areas , us e onl y wit h force d ventilatio n adequat e t o kee p vapo rconcentratio n belo w20 % o f lowe rexplosio n limits . Refer t o OSH A Standard s 29CF R1910.94 . 1910.107 , 1910.108 . MOTE : Heav y solven tvapor s shoul d b e remove d fro m lowe rlevel s o f th e wor k are aan d al l ignitio n source s (nonexplosion-proo f motors , etc. ) shoul d b e eliminated . PROTECTIVE GLOVES : Us e solven timpermeabl e glove s t o avoi d contac tvit h product . EY E PROTECTION : D o no tge ti n eyes . Us e safet y eyewea rvit h splas h guard s o rsid e shields , chemica l goggles , fac e shields . OTHE RPROTECTIVE EQUIPMENT : Avoi d contac tvit h skin . Us e protectiv e clothing . Preven tcontac twit h contaminate d clothing . Was h contaminate d clothing , includin g shoes . befor e reuse .
SECTIO N I X SPECIA L PRECAUTIONS

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# + l•MATERIA L SAFET Y DATASHEET 

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. BO X 221 9 COLUMBUS , OHI

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Produc t Name : PLIOGRI P 66C C

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"^SECTIO N 4-*-A0DUCT~4OE«TIF.<CAT*O N ESZ2E25Z 3 Genera l o r Generi c ID : POLYURETHAN E PREPOLYME R DOTHazar d Classification : NO TAPPLICABL E

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## 42 .P.4 3 MATERIA L SAFET Y DAT ASHEE T AmhMdllU r.v. bU A uiv COLUMBUS , OHI

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sRDOU S DECOMPOSITIO N PRODUCTS : Mt vFORM. TOXI C MATERIALS: , CARBON DIOXID E AN D CARBO N MONOXIDE , VARIOU S HYDROCARBONS , NITROGE N COMPOUNDS . HYDROGE N CYANIDE . E"d . IfSFIGHTlN G PROCEDURES : WEA R SELF-COI.TAINE D BREATHIN G AI-FARATU S WIT H A FUL L FACEPIEC E OPERATE D I N TH E POSITIV E PRESSUR E DEMAN D MODE AN D FUL L BOD YPROTECTIO N WHE N FIGHTIN G FIRES . WATE R O

R FOA M MA Y CAUS E FROTHIN G WHIC H CA N B E VIOLEN TAN D POSSIBL YENDANGE R TH E LIF E O F TH E FIREFIGHTER . ESPECIALL YI F SPRAYE D INT O CONTAINER S O F HOT , BURNIN G LIQUID . iPKIA L FIR E I EXPLOSIO N HAZARDS : NEVE R US E WELDIN G O R CUTTIN G TORC H O N O R NEA R DRU M (EVE N EMPTY ) BECAUS E PROOUC

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Y CAUS E MIL D SKI N IRRITATION , SYMPTOM S MA Y INCLUD E REDNES S AN D BURNING . .:• * - REPEATE D CONTAC TMA Y CAUS E SENSITIZATION . 3REATHIN G - CAN CAUS E NASA L AN D RESPIRATORYIRRITATION , TIGHTNES S O F CHEST , COUGHING , HEADACHE , AN D SHORTNESS O F BREATH . CA

N CAUS E ALLERGI C SENSITIZATION . SWAMLOWIN G - CAN CAUS E GASTROINTESTINA L IRRITATION , NAUSEA , VOMITING , AN D DIARRHEA . ASPIRATIO N O F MATERIA L INT O TH E LUNG S CA

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O NOT INDUC E VOMITING , KEE P PERSO N WARM , QUIET , AN D GE T MEDICA L ATTENTION . ASPIRATIO N O F MATERIA L INT O TH E LUNG S DU E T 0 VOMITIN G CA N CAUS E CHEMICA L PNEUMONITI S WHIC H CA N B E FATAL . I F BREATHED : I F AFFECTED , REMOV E INDIVIDUA L T O FRES H AIR . I F TIGHTNES S O R CONGESTIO N I N CHES TDEVELOPS , GE T MEDICA L ATTENTION . I F AFFECTED , REMOV E INDIVIDUA L T

O FRES H AIR . I F BREATHIN G I S DIFFICULT , ADMINISTE R OXYGEN . I F BREATHIN G HA S STOPPED . GIV E ARTIFICIA L RESP I RAT I ON . KEE P PERSO N WARM . QUIET , AN D GET MEDICA L ATTENTION . FROAAR YROUTE(S ) O F ENTRY : INHALATION . SKI N CONTAC T EFFECT S O F CHRONI C OVEREXPOSURE : PROLONGED INHALATIO N O F TAL C DUSTI KHIG H CONCENTRATION S CA N CAUS E PULMONAR YFIBROSIS . A STUDYBY TH E INTERNATIONA L ISOCVANAT E INSTITUT E SUGGEST S THA TPROLONGE D EXPOSUR E T O HIG H CONCENTRATION S O F POLYMERI C METHYLEN E B1SPHENYLISOCYANAT E (MDl ) MA Y INCREAS E TH E INCIDENC E O F TUMOR S I N TH E LUNGS . THI S STUD YENTAILE D A LIFETIM E EXPOSUR E O F MAL E AN D FEMAL E RAT S T O A N AEROSO L O F POLYMERI C MD l A T LEVEL S U P T O 6 MG/M3 . AEROSO L EXPOSURE S WER E USE D BECAUS E O F TH E DIFFICULT YO F GENERATIN G A VAPO R ATMOSPHER E O F HO I HIG H ENOUG H T O CARR V OU T A MEANINGFU L STUDY . A T TH E HIOiES TEXPOSUR E LEVEL S THER E WA S A N INCREAS E I N A BENIG N TUMO

R O F TH E LUN G WHIC H WA S STATISTICALL YSIGNIFICAN TI N TH E MAL E RATS , BU T NO T TH E FEMALE . ON E MAL E RA

T ALS O HA D A MALIGNAN TTUMO R O F TH E LUNG . TUMO R FORMATIO N WA

S ACCOMPANIE D B

Y TH E ACCUMUUTIO N O F A YELLOW MATERIA L I N TH E LUNG S DURIN G TH E COURS E O F TH E STUD YAN D PRELIMINAR YEVALUATIO N O F TH E REPOR T SUGGESTS THA

TTHES E EFFECT S WER E RELATE D T O PROLONGE D IRRITATION . TH E TUMOR EFFECT S NOTE D I N TH E STUD Y OCCURRE D A

T LEVEL S THA TWOUL D NO T B E TOLERATE D I N A WORKPLAC E DU E T O TH E IRRITAN TAN D SENSITIZIN G PROPERTIE S O F MD l AN D I N TH E ABSENCE O F PROLONGE D HIG H EXPOSURE S LEADIN G T O IRRITATIO N AN D SENSITIZATION . I TI S UNLIKEL YTHA TTUMO R FORMATIO N WOUL D OCCUR . HOWEVER . THI S REPOR TEMPHASIZE S TH E NEE D T O MAINTAI N EXPOSURE S BELO

W TH E RECOMMENDE D OCCUPATIONA L EXPOSUR E LIMITS . OIHIEXPOSUR E T O THI S MATERIA L (O R IT S COMPONENTS ) HAS BEE N SUGGESTE D A S A CAUS E O F TH E FOLLOWIN G EFFECT S I N HUMANST . RESPIRATOR YSENSITIZATION , SKI N SENSITIZATIO N 

### m 2 i*i>w«nCECI I O N -W l T*tAC n tl H ¥•-«• > AT A ^"'**tow»'»^'»w''^St(.^?»--«fcf>»,Kc,-*.=r'* » •««« • UIZARDOU S POLYMERIZATION : CA N OCCUR —AVOI D CONTAC TWIT H STRON G ALKALIES , STRONG MINERA L ACIDS . AN D WATER . STABILITY : STABL E ^COMPATIBILITY : AVOI D CONTACTWITH: , STRON G ALKALIES , STRONG MINERA L ACIDS. . WATER . EXCESSIV E HEA T » p \

.<WW*M^-«W>W« S E C 1 1 O N «I 4 -%£P 4 4.-t«40 R AEAK-tfAOCEOURE S W^M H -WSRSUSe**? . • * Jfi* ST S ^y.;_ TEP S T O B E TAKE N I N CAS E MATERIA L I S RELEASE D O R SPILLED : SHAL L SPILL : ABSOR B LIQUI D Ot. ' VERM'.CULITE , FLOO R ABSORBENT . O R OTHE R ABSORBENTMMTERIA L AN D TRANSFE R T O HOOD . W-.G E SPILL : PERSON S N0 TWEARIN G PROTECTIV E EOUIPMEN TSKX'L C B E EXCLUDE D FRO M ARE A O F S r lL L UNTIL CLEAN-U P HA S BEE N COMPLETED . S T 0 SF1L L A T SOJRCE . DIK E ARE A O F SHI L T O PREVEN TSPREADING . PUM " LIOUI D T O SALVAG E TALK . NEUTRALIZ E SPIL L WIT H A N AOJEOU S SOLUTIO N O F AHON1A . REMAININ G LIQUI D Mi YBE TAKE N VI P ON SAND . CLAV , EARTH . FLOO " ABSORBENT . O R OTHE R AESORBENTMI'ERiA L AN D SHOVELE D INT O CONTAINERS . HAST E DISPOSA L METHOD : WAL L SPILL : DISPOS E O F I N ACCORDANC E WIT H AL L LOCAL . STAT E AN D FEDERA L REGULATIONS .

COKTIKUE D O) : F7.Gr : 3



# to• MATERIA L SAFET Y

DAT ASHEE T 

## Ashland P.4 4 ^?.0. BO

X 221 9 COLUMBUS , OHI O 4321 6 (614 ) 889-333 3 Telephon e 1(800 ) 274-526 3 or 1(800 ) ASHLAN

D
00025 1 E rnfl.Ja a PLIOGRI P 660 0 ECT*O N «UII-i£P 4 4.1<*D R AtAK^ilOCeDURE S Page : 3 nncuiii y LARG E SPILL : DESTRO YB YLIQUI DINCINERATIO N I N ACCORDANC E WIT H APPLICABL E REGULATIONS . E C M O N «l«l<-J>«OT£Cn«E«OUI>PMEMr*i*0«E«UBE O RESPIRATOR YPROTECTION : I F WORKPLAC E EXPOSUR E LIMIT(S ) O F PRODUC T O RAN YCOMPONEN T I S EXCEEDE D(SEE SECTION II) , A NIOSH/MSHA

APPROVE DAI RSUPPLIE DRESPIRATORI S ADVISE DIN ABSENC E O F PROPE RENVIRONMENTAL CONTROL . OSH i REGULATION S ALS O PERMI T OTHERNIOSH/MSH A RESPIRATOR S (NEGATIVE PRESSUR E TYPE ) UNDERSPECIFIE D CONDITION S (SE E YOU

RSAFET YEQUIPMENT SUPPLIER) . ENGINEERIN GO RADMINISTRATIV E CONTROL S SHOUL DB E IMPLEMENTE DT O REDUC E EXPOSURE . VENTILATION : PROVID E SUFFICIEN T MECHANICA L (GENERA

L AND/ORLOCAL EXHAUST ) VENTILATIO N T O MAINTAI N

EXPOSUR E BELOW TLV(S) . PROTECTIV E GLOVES : WEARRESISTAN T GLOVE S SUC H AS: , NATURAL RUBBER , POLYVINY L ALCOHO L EY E PROTECTION : CHEMICA L SPLAS H GOGGLE S I N COMPLIANC E WIT H OSHA

REGULATION S AR E ADVISED : HOWEVER , OSH A REGULATION S ALS O PERMI T OTHE RTYP E SAFET YGLASSES . (CONSUL T YOU RSAFET YEQUIPMEN T SUPPLIER ) OTHE RPROTECTIV E EQUIPMENT : T O PREVEN T REPEATE DO RPROLONGE DSKI N CONTACT , WEARIMPERVIOU S CLOTHINGAN DBOOTS . -SECTIO N 4X-SPECIA L PRECAUTION S O R OTHE R -COMMENT S CONTAINER S O F THI S MATERIA L MA YB E HAZARDOU S WHEN EMPTIED . SINC E EMPTIE D CONTAINER S RETAI N PRODUC TRESIDUE S (VAPOR . LIQUID , AND/O R SOLID) . AL L HAZAR D PRECAUTION S GIVE N I N THI S DATASHEE TMUSTB E OBSERVED . EXPOSUR E T O AEROSOLS AN D MIST S WHEN MATERIA L I S SPRAYE D MA YPRESEN TA GREATE R RIS KO F INJUR YFRO M COMPONENT S BECAUS E HIGHE R CONCENTRATION S AR E I N TH E ATMOSPHER E THA N RESULTFROM VAPO R ALONE . PROVID E ADEQUAT E VENTILATIO N AN D I F NECESSARY , US E RESPIRATOR YPROTECTION . TH E INFORMATIO N ACCUMULATE D HEREI N I S BELIEVE D T O B E ACCURAT E BUTI S NO TWARRANTE D T O B E WHETHER ORIGINATIN G WIT H TH E COMPAN

YO R NOT . RECIPIENT S AR E ADVISE D T O CONFIR M I N ADVANC E O F NEE D THA TTH E INFORMATIO N I S CURRENT , APPLICABLE , AN D SUITABL E T O THEI R CIRCUMSTANCES .

A>4-P.4 5 AMPLICATIO

NcX,R Ai-Z.Sl.1 xO Cr-L^ I A N AI ROOOTAHINAM T SDURC E 

### ATTACHMEN T 2 Picken' s Plastics , Inc . Facilit y

Nam e 421 2 An n Ave . Pau l Nichola s
Facilit yAddres s Ashtabula , Ashtabula , Cit yCount y (216 ) 992-400 0 4400 4 

### Zi p Telephon e Are a 0204030269R00 1 Perso n t o Contac t P.O . Bo x 127 9 Mailin g Addres s Ashtabula , O H Cit ySut e (216 ) 992-400 0 4400 4 

### Zi p Numbe r Telephon e 308 9 

### (Applicatio nNo. , i f

thi s i s arenewal application ) Std
. Ind
. Class
. Cod e 1
. Conplet e an dattac hany o f th e followin g appendice s nos t appropriat e t o th e ai r -contaminant

source . I naddition , acomplianc e tim e schedul e for mi s t o b e attache dwhe

napplicable
. Chec

k a s appropriat e th e following : _Appendi x A, Proces s "Appendix B , Fuel-Burnin g Equipment " [Appendi x C , Incinerato r "Appendix D , Surfac e Coatin g o r

Printin g Operatio n _Appendix E , Storag e Tan k _Appendix H , Gasolin e Dispensin g

Facilit y _Appendi x J , Loadin g Rac k a t Bulk Gasolin e Plan t

o r Termina l _Appendi x K

, Surfao e Coatin g Lin e o r Printin g Lin e " Appendix L , Solven t Metal Cleanin g _Appendi x M , Fugitiv e Dus t Emissio nSource s Specif y Appendi x No
. _Appendi x N , Rubbe

r Tir e Manufacturin g Appendix 0 , Dr

y Cleanin g Facilit y _Appendi x P , Landfill s _Other Append i x _ ^Complianc e Tim

e Schedul e 2
. Descriptio no f

Sourc e (san e a s use donappendix) : Fiberglas s Spray-u p Boot h 3
. You r identificatio nfo r

Sourc e (sam

e a s use do

nappendix) :

— 5 > Spra y Boot hB5- A 

### I , .bein g th e individua l specifie di nRul e 3745-35-02(B ) of th e Ohi o Administrativ e Code , hereb y appl y fo r aPermi t

t o Operat e th e ai r contaminan t

source(s ) describe dherein
. A s required , th e followin g additiona l document s ar e submitte da s par t o f thi s applicatio n(describ e al l attachments) : Thoma s J
. Picke n 

### Authorize dSignature * President , Picken' s Plasties , In c Titl e Jan
. 29 , 199 3
_____ _ 

### Dat e •Pursuan t t o OA C Rul e 3745-35-02(B ) (Permi t t o Operate)
. Operatio no f

a nai r contaminan t

sourc e withou t

aneffectiv e permi t

t o operat e i s prohibite dt o 3704.0 5 Ohi o Revise dCo>3
. Peo e 1 EPA-316 1 A,£>P.4 6 'ccar.s e No
. Sourc e No
. Applicatio n /

/ No
. _ /

/ / •** •APPENDIXD

SURFAC E COATIN

GO RPRINTIN

GOPERATION 1 . Thi s appendi xi s submittedfo r a : D Surfac e coatin g operation(check on e below) :

Pain t spra

y boot hFlo w coating Di ptank Rolle r coatin g XSpra y

Coatin g (Othe r thanpain t spra y booth ) Othe r surfac e coatin g operation , describ e
DPrintin g o r lithographi c operation . 2 . Name o f operatio nFiberglas s Spray-u p; You r identificatio n?~ 5 3 Yea r Installe d 3 . I s thi s operatio nsucceededby a heate ddrying o r bakin g operation ? E J Ye s Q N o I f yes , indicat e operating temperatur e o f ove n11 0 F . A . Norma l operatin g schedule : 1 6 hours/day , 5 days/wk. , 5 2 wks./year . PAIN T SPRA

YBOOT H " . : • - 5 . Typ e o f spra y

booth : E f Enclose d•Conveyo r rjDowndraf t .

• Other , describ e 6 . Boot hmanufacture r Devilbis s Ma k e o r M 0( j e l No . XP O 7 . Typ e o f spraying : • Ai r gunE O Airles s • Electrostati c D Other , describ e '__ 8 . Spraying operatio nis : 0Manua l D Automati c 9 . Fa nmanufacture r Dayto n'_Mak e o r Mode l No . 3N333 A 10 . BootV s exhaus t i s equippe dwith : • Wate r was h(Complet e ite m 11 ) E D Exhaus t filter s (Complet e item 12 ) D Baffle s • Other , describ e • Non e 11 . Wate r wash : (a ) I s wate r recirculated ? DYe s D N o

(b ) I s a chemica l addedt o the water ? DYe s O.N o (c ) I s materia l reclaime dfro nwas hwater . DYe s D N o (d ) Describ e metho dfor disposa l o f wast e materials : N A

* Doe s no t includ e meta l platin g



## A 

## fcP.4 7

L3 .
14 .
15 .
16 .

L7 . (a ) Typ e o f material : B Fibergla s D Aluminu m
• Other , describ e (b ) Filte r siz e (inches) : Lengt h 20 " Widt h 20 " Thicknes s 2 " No . o f filters : 8 No . o f filte r changes : 5 1 time s pe r yea r Describ e materia l painte d Mixtur e 30 % Fiberglass , 69 % Polyeste r Resin , 1 % ME K P . AL L OPERATION S (Except pain t spra y booth ) Describe typ

e o f operatio

nFiberglass/Resin/Catalys t i s spraye d o n the surfac e o f a fiberglas s par t mold . Describe metho do f coatin g spra yequipment . or printin g Choppe d

Identif y

an ddescribe type(s ) of materia l coate d reinforce d plasti c par t i s coate d wit h par t raw Fiberglas s

o r printe

d materials . i s applie d

Bas e mol d wit h

fo r i airles s
Fiberglas s

ALL OPERATION S Complet e th

e followin

g informatio

nfo r eac hgenera l typ

e o f surfac e coatin g o f printin

g material . Repor t o nthe materia l a s i t i s employe dafter the additio no f an y pigments , solvents , etc . I f ther e ar e aor e tha nthre e type s o

f materials , furnis hth e sam e dat a fo r th e additiona l maieris-l s o na separat e shee t or anothe r appendi xform . (a ) Materia l -employe d Polyeste r Resin/Mi x 6604 T Densit y 9.8 7 Solid s conten t 48.36 % b y volum e o r %b

y weight . Solvent content 5 1 »6 4 % b y volume ; Solven t densit y 7.6 1 lbs./gallo n Norma l applicationschedul e 5 hrs./day , * days/wk. , 7.6 1 wk s ./year . Quantity

use d(gallons/hour) : Norma l 4. 0 Maximu m Unknow n. (gallons/year) : 49 6 , } Complet e the solvent compositio nby identifyin

g eac hsolven t componen t an dit s respective X b y volum e o f th e tota l solvent . (Th e % b y volum e shoul dtoza i to 100%) . _lbs./gallo n

Solven t Compositio

n Solven t Styren e Dimethy l Phthalat e Hexylen e Glyco l X b y Volum e 98.8 3 .84 4 .20 3 *

Y
• J
• J Solvent

ME K Solvent Compositio n X b y Volum e .11 6 *

. N

* I f solven t i s photochemically reactive enter "Y" , i f no t photochemicall y reactiv e ente r "N" , i f unknow nente r "U" . I s th e materia l photochemically reactive ? 

### 0Ye s • N o • D

o not kno

w



## AlP.4 8

•(b ) Materia l employe d polyeste r ResinMi xQ6022 5 Densit y 9 - ° 2 Solid s conten t 45.25 % b y volum e o r 2 b

y weight lbs./gallc n Solven t content54.7 5 2 b y volum e Solven t density

7.5 9 lbs./gallo n Norma l applicatio

nschedule : 12. 5 hrs./day . 5 days/wk. , 5 2 wks./year . Quantit y

used(gallons/hour ) : Norma l 4 Maximu m Unknow

n (gallons/year) : 12,910 . Complet e the solven t compositio

nb y identifyin

g eac hsolvent componen t an dit s respective % b

y volum e of th e tota l solvent . (Th e 2 b y volum e shoul dtota l t

o 100%) . Solven

t Compositio

n Solven t Styren e Dimethy l Phthalat e Hexylene Glyco l % b y Volum e 97. 4 .7 9 • 1 9 *

Y N N Solven t Composition Solven t ME K Minera l Spirit s 2 b y Volum e .10 9 l.b O *

N 

### N

* I f solven t l s photochemicall y reactiv

e ente r "Y" , i f no t photochemicall y Teactive enter "N" , i f unknow nente r "U" . I s th e materia l photochemicall y reactive ? EfYe s

i- 2 "Tbyweigh

t • N

o (c ) Materia l employe dPolyeste r ResinMi x75-3730Density 9 - 0 1 Solid s conten t 42 - ab 2 b y volum e o r • Do no t kno w lbs./gallo

n Solvent conten t 57.0 4 2 b y volum e Solven t density

7.5 9 lbs./gallo n Norma l applicationschedule:j____hrs . /day , 5 days/wk . ,_52_wks./year . Quantity

use d(gallons/hour) : Norma l 4 Maximu m Unknow

n (gallons/year) : 260 8 Complet e the solvent compositio nb y identifyin

g eac hsolvent componen t an dit s respectiv

e % b y volum e o f th e tota l solvent . (Th e 2 b y volum e shoul dtota l t

o 1002) . 1 Solven t Com i I Solven t | Styren e Monome r | Dimethy l Phthalat e \ Hexylene Glyco l positio n 2 b y Volum e 97.5 4 .7 6 .1 8 *

Y N N Solven t Composition Solven t ME K Minera l Spirit s 2 b y Volum e .10 5 • 1.4 0 *

N N

* I f sclveur i s photochemicall y reactiv

e ente r "Y" , i f no t photochemicall y reactiv e enter. . "N" , i f unknow nente r "U" . I s th e materia l photochemicall y reactive ? ©Ye s • N o • Do no t kno

w 18 . Identif y

al l liqui dorgani c cleanu pmaterial s fo r thi s proces s an dIndicat e th

e amoun t use dpe r averag e operatin g da y an dper year . Cleanu pMateria l Aceton e Gallon s Used Dail y 6.93 7 Yearl y

180 3 Se/one • R-i-yfm'le

* I f materia l i s photochemicall y reactiv

e enter "Y" , i f no t photochemicall y reactiv

e enter "N" , i f unknow nenter "U" .

* " * * t » • f , 

## 4- aP.4 9 point s o f

al l material s an dfinishe dproducts
. Labe l al l material s includin g aiTborn e contaminant s an dothe r vast e materials
. Labe l th e proces s equipmen t an d• contro l equipment
. CONTRO LEQUIPMEN

T 20
. Typ e o f

contro l equipment : QNon e • Incinerator , Temp
. °F , Thermal/Catalyti c (Circl e one ) D Adsorption , 'describ e • Condensation , describ e EOther , describ e Filtere dSpra y Booth 21
. Manufacture r

Devilbis s Mode l Ko
. XD O Yea r

lnstalled
_ 22
. Percen t

collectio no r

remova l efficiency : Desig nN/ A 2 Operatin g N/ A 23
. Fo r non-incineratio nmetho dIdentif y specifi c pollutan t controlle dPolyeste r Resi n STAC K DAT A 2A
. You r

stac k identificatio n 34 " Diamete r Roun dStac k 25
. Ar e othe r

source s vente dt o thi s stack ? ^EfVe s EjN o I f yes , identif y source s j^asa_=-B*-JDjB£Bg5 c 26
. Type : " E

Q Round , to p insid e diamete r dimensio n34 " • Rectangular , top . insid e dimension s (L ) N/ A p

c (W ) N/ A 27
. Height : Abov e roo f 0 ' ft. , abov e groun d8 ' ft
. 28
. Exi t

gas : Temp
. AM B °F

_Volum e 470 4 " - ' ACFM , Velocit y 17 5 ft./min
. 29
. Continuou s monitorin g equipment : DYe s ©N o .. .

I f yes , indicat e Typ e -• ' - • » Manufacturer_
. Mak e o r Mode l » Pollutan t (s ) monitore d• 30
. Emissio ndata : Emission s fro mthi s sourc e hav e bee ndetermine dan dsuc hdat ai s include dwit hl±±s appendix : " Dye s O^ o I f yes , chec k

method : • Stac k

Tes t • Emissio nfacto r • Materia l balanc e Complete db y j/Kg-zf&teTYvo&vf .Dat e 1-24-9 3 Theodor e Heber t

•-2103 . 

# * 1.APPLICATION KX. A PERKTT T O OPERAT E A NAI RCOOTAMINAN

T SOURC E P.5 0



### Picken' s Plastics , Inc
. Facilit y Nam

e 421 2 An nAve
. Pau l Nichola s Perso nt o Contac t P.O
. Bo x 127 9 Facilit y Addres s Ashtabula , .Ashtabul a44004 Mailin g Addres s Ashtabula , O

H 44004 Cit y County (216)992-400 0 Zi p Cit y Stat e (216)992-400 0 Zi p Telephon e Are a 020403026 9 R00

4 Numbe r Telephon e 308 9 (Applicatio nNo. , i f

thi s i s arenewa l application ) Std
. Ind
. Class
. Code 1
. Complet e an dattac han y o f th e followin g appendice s aos t appropriat e t o th e a i rcontaminan t

source . I naddition , acomplianc e tim e schedul e formi s t o . b e attache dwhe

napplicable
. Check

a s appropriat e th e following : _Appendi x L , Solven t

Meta l Cleanin g _Appendi x K

f 

### Fugitiv e Dus t Emissio nSource s

2 . 3 . 

### Appendi x A , Proces s Appendi x B , Fuel-Burnin g Equipment " Appendi x C , Incinerato r X Appendi x D , Surfac e Coatin g o r

Printin g Operatio n Appendi x E , Storag e Tan k Appendi x H , Gasolin e Dispensin g

Facilit y Appendi x J , Loadin g Rack a t Bul k Gasolin e Plan t

o r Termina l Appendi x K

, Surfac e Coatin g " •".
. Lin e o r

Printin g Lin e Cc-mplianc e Tim e Schedul e Descriptio no f

Sourc e (.sam

e a s use do nappendix) ; Fiberglas s Spray-u p Boot h Your identificatio nfo r

Sourc e (same a s use do nappendix) : » Spray Boot

hB5 B Specif y Appendi x No
. _Appendi x N , Rubber

Tir e Manufacturin g Appendi x 0 , Dr

y Cleanin g Facilit y ^Appendi x P , Landfill s "Othe r Appendi x

I , bein g th e individua l specifie di nRul e 3745-35-02(B ) o f th e Ohi o Administrativ e Code , hereb y appl y fo r aPermi t

t o Operat e th e ai r contaminan t

source(s ) describe dherein
. A s required , th e followin g additiona l document s ar e submitte da s par t o f thi s applicatio n(describ e al l attachments) : Thoma s J
. Picke n Authorize dSignatufte*- / President , Picken' s Plastics , Inc
. Titl e Marc h30 , 199 3 Dat e •Pursuan t

t o OA C Rul e 3745-35-02{B ) (Permi t t o Operate)
. Operatio n o f

a nai r contaminan t

sourc e withou t

a neffectiv e permi t

t o operat e i s

. _ • ••..*..- • . . --—• r.r r.-'r. r-..-:,.-- - ToS- . p £ or - ? EPP.-21C)

r " r.P.5 1 j\s e No
. -c e No . .^catio n /

/ No . _ /

/ / .*

# APPENDI X D * SURFAC E COATIN

G O RPRINTIN

G OPERATIO

N Thi s appendi x i s submitte d fo ra : D Surfac e coatin g operatio n (chec kon e below) :

Pain tspra y boot h Flo wcoatin g Di p tan kRolle rcoatin g X Spra y Coatin g (Othe rtha n pain tspra y booth ) Othe rsurfac e coatin g operation , describ e , •

• Printin g o rlithographi coperation . Nam e o f operatio n Fiberglas s Spray-u p ; Youridentificatio n B5 B Yea rInstalle d I s thi s operatio n succeede d b y aheate d dryin g o rbakin g operation ? Q Ye s • N o I f yes , indicat e operatin g temperatur e o f ove n 11 0 F . Norma l operatin g schedule : 8 hours/day , 5 days/wk. , 5 2 wks./year . PAIN T SPRA Y BOOT H " - - - Typ e o f spra y booth : 1 0 Enclose d •Conveyo rDDowndraft • Other , describ e Boot h manufacture rDevilbis s Mak e o rMode l No . JJ42T 2 Typ e o f spraying : • Ai rgu n ©Airles s D Electrostati c

D Other , describ e - ' Sprayin g operatio n is : 13Manua l D Automati c Fa n manufacture rDayto n Mak e o rMode l No . 3N553

A

» . Booth' s exhaus ti s equippe d with : D Wate rwas h (Complet e ite m 11 ) 0 Exhaus tfilter s (Complet e ite m 12 ) D Baffle s D Other , describ e D Non e Wate rwash : (a ) I s wate rrecirculated ? DYe s D N o (b ) I s achemica l adde d t o th e water ? DYe s D.N o N/ A l ' = ^ I s Eateria l reclaime d fro m was h water . DYe s D N o (d ) Describ e metho d fo rdisposa l o f vast e materials : Die s ho tinclud e meta l platin g


## X 5 \P.5 2

13 .
14 .
15 .
16 .

17 . _. : filters :

(a ) typ e o f

material : ( 3 Fibergla s • Aluminu m D Other , describ e (b ) Filte rsiz e (inches) : Length 20 " Widt h 20 " Thicknes s Zl No . o f filters : 4 No . o f filte r changes : 5 1 time s pe r yea r Describe materia l painte dMixtur e 30 % Fiberglass , 69 % Polyeste r Resin . 1 % MEKP . AL L OPERATION S (Except pain t spra y booth ) Describe type o f operationFiberglass/Resin/Catalys t i s spraye do nth e surfac e o f
a fiberglas s par t mold . Describe metho do f coatin g o r printin

g Choppedfiberglas s i s applie dwit hairles s spra y equipment . Identif y

an ddescrib e type(s ) o f materia l coate do r printe dBas e mol dfor fiberglas s reinforcedplasti c par t i s coate dwit hpar t raw

materials . ALL OPERATION S Complet e th

e followin

g informationfo

r eac hgenera l typ e o f surfac e coatin g o r printin

g material . Repor t o nth e materia l a s I t i s employe dafte r the additiono f an y pigments , solvents , etc . I f ther e ar e mor e tha nthre e type s o f materials , furnis hth e sam e dat a for th e additiona l material s o na separat e shee t o r anothe r appendi xform . (a ) Materia l employedPolyeste r Resi nMi xO6022 S Densit y q.Q 2 lbs./gallo n Solid s content45.2 5 I b y volum e o r Z b

y weigh t Solven t content"?>4.7 5 Z b y volume ; Solven t densit y 7.5 9 lbs./gallon Norma l applicationschedul e 4.5hrs./day , 5 days/wk. , 5 2 wks./year . Quantit y

used(gallons/hour) : Normal" " 6 Maximu m Unknow

n (gallons/year) : 633 6 Complet e the solven t compositio nb y Identifyin

g eac hsolven t componen t an dit s respective Z b y volum e o f th e tota l solvent . (Th e Z b y volum e shoul dtota l t o 100Z) .

Solven t Composition Solven t Styrene Dimethy l Phthalat e Hexylene Glyco l Z b y Volum e 

### 97. 4 .79 .1 9 * 

### Y N N Solvent Compositio n Solven t 

### ME K Minera l Spirit s Z b y Volum e 

## -JQ L J_- i

* I f solven t l s photochemicall y reactiv

e ente r "Y" , i f no t photochemicall y reactive ente r "N" , I f unknow nente r "U" . 

### J S

I s th e materia l photochemicall y reactive ? 

### files • N o • Do no t kno w

EPA-310 3 3/11/P 1 

### D- 2 

## q - 

## zP.5 3 lbB./gallon (b ) Materia l employedPolyeste r Resi nMi x75-3730pen8ity 9.0 1 Solid s content42.9 6 Z b y volum e o r Z b

y weight Solvent content57.0 4 Z b y volum e Solven t density

7.5 9 lbs./gallon Norma l applicationschedule : 3 hrs./day . 5 days/wk. , 5 2 vks./year . Quantity

used(gallons/hour) : Norma l 6 Max.iaru m Unknow

n (gallons/year) : 474 0 Complet e the solven t compositio

nb y identifyin

g eac hsolven t component an dIt s respectiv

e Z b y volum e of th e tota l solvent . (Th e Z b y volum e shoul dtota l to 100Z) . Solvent Compositio n Solven t Styren e Monome r Dimethy l Phthalat e Hexylen e Glyco l Z b y Volum e 

### 31M 

### .76 .1 8 * Solven t Compositio n Solven t 

### TffiT " Minera l Spiri t Tl.4 0

Z b y Volum e Z b y 

### •nu T

* I f solven t 1 6 photochemicall y reactiv

e ente r 'V , i f no t photochemicall y reactiv e ente r "N" , I f -unknow nente r "U" . I s th e materia l photochemicall y reactive ? EXYe s • N o (c ) Materia l employe d Polyeste r Resi nMi x6604 T Density 9.8 7 Solid s conten t b y volum e o r • D o no t kno

w lbs./gallo

n Z b y weight Solven t content"51.6 4 Z b y volum e Solvent density

7.6 1 lbs./gallo n Norma l applicationschedule : 1 hr6./day , 1 days/wk. , 4 T wks./year . Quantity

use d(gallons/hour) : Norma l 6 Maximu m Unknow

n (gallons/year) : 25 4 Complet e th e solvent compositio nb y identifyin

g eac hsolven t component an dit s respectiv

e Z b y volum e of th e tota l solvent . (Th e Z b y volum e shoul dtota l t o 100%) . Solvent Co m Solven t Styrene Dimethy l Phthalat e Hexylene Glyco l positio n Z b y Volum e 98.8 3 .84 4 .20 3 * 

### Y N N Solven t Compositio n Solven t 

### ME K Z b

y Volum e .11 6 *



### N

* I f solven t i s photochemicall y reactiv

e enter "Y" , i f no t photochemicall y reactiv e enter . "N" , I f unknow nente r "U" . I s th e materia l photochemicall y reactive ? E Ye s • N o • D

o no t kno

w IS . Identif y

al l liqui dorgani c cleanu pmaterial s fo

r thi s proces s an

dIndicat e th

e amount usedper averag e operatin g da y an dper year . Note : 50 % o f th e daily/yearl y

us e reporte dher e i s recoveredfor recycle .

* I f materia l i s photochemicall y reactiv

e enter "Y" , i f no t photochemicall y reactiv

e enter "N" , I f unknow nenter H U" . Cleanu pMateria l Aceton e * 

### N Gallon s Use d Dail y 3.4 6 Yearl y



### 90 0

EPA-310 3 

### D- 3 

# C bP.5 4 19 . A PROCES

S FLO W DUGRA

M MUS T B E INCLUDE

D WIT H THI S .APPENDIX

. Sho wentr y an d exi t point s o f

al l material s and finishe d products . Labe l al l material s Includin g airborn e contaminant s and othe rvast e materials . Labe l th e proces s equipmen tan d contro l equipment . CONTRO L EQUIPMEN

T 20 . Typ e o f

contro l equipment : DNon e • Incinerator , Temp . °F , Thermal/Catalyti c(Circl e one ) D Adsorption , describ e D Condensation , describ e B Other , describ e Filtere d Spra vBoot h 21 . Manufacture rMode l No . Yea rInstalled ^ 22 . Percen tcollectio n o rremova l efficiency : Desig n 99. 0 Z Operatin g 23 . Fo rnon-lnclneratlo n metho d identif y specifi cpollutan tcontrolle d Polyeste rResi n Solid s STAC KDAT A 24 . You rstac kidentificatio n B5 B 25 . Ar e othe rsource s vente d t o thi s 6tack ? • Ye s 13N o

I f yes , identif y source s 26 . Type : -0Round , to p Insid e diamete rdimensio n 27 "

• Rectangular , to p insid e dimension s (L ) x (W)
_ 27 . Height : Above roo f 7 ft. , abov e groun d 3 2 ft . 28 . Exi tgas : Temp . -Am b 0 F , Volum

e 309 3 ACFM

. Velocit y 11 5 ft./min . 29 . Continuou s monitorin g equipment : QYe s QN o

I f yes , indicat e Typ e , Manufacture r Mak e o rMode l , Pollutan t(s ) monitore d 30 . Bnissio n data : Emission s from thi s sourc e hav e bee n determine d an d suc h dat aI E Include d vit h thi s appendix : - Dye s jQN o I f yes , chec kmethod : • Stac kTe6 t• Emissio n facto r• Materia l balanc e Complete d b y *ffi „ JL j fliWiJ

.Date^-3 /

te Theodo rHeber t

EPA-310 3 ?/*l/B l D- 4 

## £ 

## 4-/vrri_xv-AlXU i r*w- KafLM'U l A*- 1 uuvu u A NAI RCONTAMINAN

T SOURC E P.5 5


### Picken' s Plastics , Inc
. Facilit y Nam

e Pau l Nichola s 421 2 An nAve
. Perso n t o Contac t P
. 0
. Bo x 127 9 Facilit y Addres s Ashtabula , Ashtabul a 4400 4 

### Mailin g Addres s Ashtabula , O

H 44004 Cit y Count

y (216 ) 992-400 0 Zi p Cit y Stat e (216 ) 992-400 0 Zi p Telephon e Area 020403026 9 R00

5 Numbe rTelephon e 308 9 (Applicatio n No. , i f

thi s i s arenewal application ) Std . Ind . Class . Cod e 1 . Complete an d attac h an y o f th e followin g appendice s nos tappropriat e t o th e ai rcontaminan tsource . I n addition , acomplianc e tim e schedul e for m i s t o b e attache d whe

n applicable . Chec

ka s appropriat e th e following :

_Appendi x L , Solven tMeta

l Cleanin g ^Appendi x M , Fugitiv e Dus t Emissio n Source s

2 . 3 . Appendi xA , Proces s Appendi xB , Fuel-Burning Equipment " Appendi xC , Incinerato r XAppendi xD , Surfac e Coating o r

Printin g Operation Appendi xE , Storag e Tan k Appendi xH , Gasolin e Dispensing

Facilit y Appendi xJ , Loadin g Rac k a t Bul k

Gasolin e Plan t o r Termina l 

### Appendi x K

, Surfac e Coatin g \ *'. . Lin e o rPrintin g Lin e Conplianc e Tim e Schedul e Descriptio n o f

Sourc e (sam e a s use d o n appendix) ; Fiberglas s Spray-u p Boot h You ridentificatio n fo rSourc e (sam e a s use d o n appendix) : > Spra v Boot

hB5 C , Specif y Appendi

x No . _Appendi x N , Rubbe

rTir e Manufacturing Appendi x 0 , Dr

y Cleanin g Facilit y ^Appendi x P #

### Landfill s "OtherAppendi x

I , bein g th e individua l specifie d i n Rul e 3745-35-02(B ) o f th e Ohio Administrativ e Code , hereb y appl y fo raPermi tt o Operat e th e ai r contaminan tsource(s ) describe d herein . A s required , th e followin g additiona l document

s ar e submitte d a s par to f thi s applicatio n (describ e al l attachments) : Thoma s J
. Picke n Authorize d Signat u President , Picken ' £

Plastics , Inc
. Titl e Marc h30 , 199 3 Dat e •Pursuan tt o OA

C Rul e 3745-35-02(B ) (Penni tt o Operate) . Operatio no f

a n ai rcontaminan t

sourc e withou t

a neffectiv e permi tt o operat e i s

—•'*•••'.- * 1'

- 3704
. OS • Cr.:-

- F-vise dCooe
. Pep- ' ? E*?.-31£ l 

## 5- 5P.5 6 \ s e No . .rc e No . plicatio n /

/ No . _ /

/ /
+. •APPENDI X D * SURFACE COATIN

G O RPRINTIN G OPERATIO N Thi s appendi x i s submitte d fo ra : D Surfac e coatin g operatio n (chec kon e below) :

Pain tspra y boot h Flo wcoatin g Di p tan kRolle rcoatin g X Spra y Coatin g (Othe rtha n pain tspra y booth ) Othe rsurfac e coatin g operation , describ e

\s

> . S . 7 , 8» 9 . ; You ridentificatio n B5 C D Printin g o rlithographi coperation . Nam e o f operatio n Fiberglas s Spray-u p Tea rInstalle d I s thi s operatio n succeede d b y aheate d dryin g o rbakin g operation ? • Ye s I f yes , indicat e operatin g temperatur e o f ove n 11 0 °F . Norma l operatin g schedule : 1 6 hours/day , 5 days/wk. , 5 2 wks . /year . PAIN T SPRA Y BOOT H

• Downdraf t 

### • N o

Typ e o f spra y booth : Boot h manufacture rBink s 0 Enclose d • Conveyo r D Other , describ e Mak e o rMode l No . 30-230 5 Typ e o f spraying : D Ai rgu n 0 Airles s

D Other , describ e D Electrostati c Sprayin g operatio n is : Fa n manufacture rDavto n ©Manua l • Automati c Mak e or Mode l No . 3N558 A 0 „ Booth' s exhaus t i s equippe dwith : • Wate r was h(Complete ite m 11 ) 0 Exhaus t filters (Complete ite m 12 ) O Baffle s D Other , describ

e D Non e Wate r wash : (a ) I s vate r recirculated ? DYe s Q N o (b ) I s a chemica l adde dt o th e vater ? DYe s O.N o N/ A (c ) I s materia l reclaime dfro m washvater . DYe s • N o (d ) Describ

e metho dfo r disposa l of vaste xaaterials :
Doe s no t includ

e meta l platin

g


### tjG ,P.5 7

13 .

14 .

15 .

16 .

17 . (a ) Type o f material : Q Fibergla s • Aluminu m D Other , describ e (b ) Filte r sire (inches) : Length20 " Widt h20 " Thicknes s 2 " No . o f filters : 1 4 No . o f filte r changes : 5 1 t.lme s pe r year Describe materia l paintedMixtur e 30 % Fiberglass , 69 % Polyeste r Resin , 1 % ME KP . •AL L OPERATION S (Except pain t spra y booth ) Describe type o f operationFiberglass/Resin/Catalys t i s spraye do nth e surfac e o f a fiberglas s par t mold . Describe methodo f coatin g o r printin

g ChoppedFiberglas s i s applie dwit hairles s spra y equipment . Identif y

an d describ e type(s ) o f materia l coatedo r printe d Bas e m °l d fo r fiberglas s reinforcedplasti c par t i s coate dwit hpar t ra

w materials . •AL L OPERATION S Complet e th

e following informationfo r eac hgenera l typ e o f surfac e coatin g o r printin

g material . Repor t o nthe materia l a

a i t i s employe

dafte r the additiono f an y pigments , solvents , etc . I f ther e ar e mor e tha nthre e type s o f materials , furnis hth e sam e dat a for th e additiona l material s o na separat e shee t o r anothe r appendi xform . (a ) Materia l employedPolyeste r Resi nMi xQ6022 S Densit y 9.0 2 Solid s content45.2 5 Z b y volum e o r Z b

y weigh t lbs./gallo n Solven t content54.7 5 Z b y volume ; Solven t density 7.5 9 Norma l applicationschedul e 1 2 hrs./day , 5 days/wk. , 5 2 Quantit y

use d(gallons/hour) : Norma l 5 (gallons/year) : 15.60 0 Maximu m _lbs./gallo n wks./year . Complet e th e solven tcompositio n b y identifyin g eac h solven tcomponen t an d it s respectiv e Z b y volum e o f th e tota l solvent . (Th e Z b y volum e shoul d tota l t o 100Z) .

Solven t Composition Solven t Styrene Dimethy l Phthalat e Hexylene Glyco l Z b y Volum e y/. 4 

### .7 9 .i y * 

## ¥ N M Solven t Compositio n Solven t 

### Mk R Minera l Spirit s Z b y Volum e .10 9 

### 1. 5 *



### N N

* I f solven tl s photochemicall y reactiv e ente r"Y" , i f no tphotochemicall y reactiv e ente r"N" , i f unknow

n ente r M

U" . I s th e materia l photochemicall y reactive ? 

### 0 

### Ye s 

### • N o • D

o no tkno

w

EPA-3103 3/11/8 1 D- 2 

## SlP.5 8 (b ) Materia l -employe d Polyeste rResi n Mi x 75-3730Densit y 9.Q 1 Solid 6 content42.9 6 Z b y volum e o r lbs./gallo n Z b y veigh t Solven tconten t57.0 4 Z b y volum e Solven tdensit y 7.5 9 lbs./gallo n Norma l applicatio n schedule : 4 hrs./day , 5 days/wk. . 5 2 vks./year . Quantit y use d (gallons/hour) : Norma l 4 Maximu m UAW-ftnvi'v

t (gallons/year) : 410 0 Complet e th e solven tcompositio n b y identifyin g eac h solven tcomponen tand it s respectiv e Z b y volum e o f th e tota l solvent . (Th e Z b y volum e shoul d tota l t o 100Z) . Solven tCompositio n Solven t Styren e Monome

r Dimethy l Phthalat e Hexylen e Glyco l Z b y Volum e 97.5 4 .7 6 .1 6 * Y Solven tCompositio n

Solven t ME K Minera l Spirit s Z b y Volum e .10 5 1.4 0 *

* I f solven ti s photochemicall y reactiv e ente r"Y" , i f no tphotochemicall y reactiv e ente r"N" , i f unknow n ente r"U" . I s th e materia l photochemicall y reactive ? (c ) Materia l employe d Solid s conten t\ Z b y volum e o r Solven tconten tNS b y volum e Solven tdensit y E D Ye s • N

o Densit y / Norma l applicatio n schedule : hrs./day . Quantit y use d (galIons/hour) : Norma l (gallons/yea r Z b y veigh t days/wk/ , /Max ' HJD

o no tkno

w lbs./gallo n lbs./gallon vks./year . 

# z -Iimiff

l Complet e th e solven tcompositlonNb y identifyin g eac h solven tcomponen tan d it 6 respectiv e X

b y volum e o f

th e totai\solven£ < (The Z b y volum e shoul d tota l t o 100Z) . | Solven tCo m Solven t

: positio n /

X b y Volum

e
/ * Solven t Solven tCompositio n \ ~ Z b y Volum e *

/ * I f solven ti s photochemicall y reactiv e ente r"Y" , i f reactiv e enter . "N" , i f unknow n ente r"U" . tphotochemicall y / I s the materia l photochemicall y reactive ? D Ye s D o no tkno

w 18 . Identif y al l liqui d organi ccleanu p material s fo rthi s proces s an d indicat e th e amoun t use d pe raverag e operatin g day and pe ryear . Note : 50 % o f th e daily/yearl y us e reporte d i s recovere d fo rrecycle .
* I f materia l i s photochemicall y reactiv e ente r"Y" , i f no tphotochemicall y reactiv e ente r"N" , i f

unknow

n ente r"U" . Cleanu p Materia l Aceton e * N Gallon s Use d Dail y 6.93 7 Yearl y

18 m

rl> 

### ;-3)o ? 

# 9iP.5 9 19 . A PROCES

S FLO W DIAGRA

M MUS T B E INCLUDE

D WIT H THI S APPENDIX

. Sho wentr y an d exi t point s o f

al l material s and finishe d products . Labe l al l material s Includin g airborn e contaminant s and othe rvast e materials . Labe l th e proces s equipmen tan d contro l equipment . CONTROL EQUIPMEN T 20 . Typ e o f

contro l equipment : •Non e • Incinerator , Temp . °F , Thermal/Catalyti c(Circl e one ) D Adsorption , describe ^ • Condensation , describ e E J Other , describ e Filtere d Spray BootK " 21 . Manufacture rModel No . Yea rInstalled ^ 22 . Percen tcollectio n o rremova l efficiency : Desig n 99. 0 Z Operatin g

. 3 . Fo rnon-incineratio n metho d identif y specifi cpollutan tcontrolle d Polyeste rResi n STAC KDAT A 24 . You rstac kidentificatio n B5 C 25 . Ar e othe rsource s vente d t o thi s 6tack ? D Ye s Q N o I f yes , identif y source s 26 . Type : E Round , to p insid e diamete rdimensio n 2 V

• Rectangular , to p insid e dimension s (L ) x (W ) 27 . Eelght : Above roo f 7 ft. , abov e groun d 3 2 ft . 18 . Exi tgas : Temp . Am b °F , Volum

e 409 3 ACFM

, Velocit y 15 2 ft./min , 29 . Continuou s monitorin g equipment : DYe s C9No

I f yes , indicat e Typ e , Manufacture r Mak e o rMode l , Pollutan t(6 ) monitore d 30 . Gnissio n data : Emission s fro m thi s sourc e hav e bee n determine d and.suc h dat ai s include d vit h thi s appendix : - DYe s (3N o I f yes , chec kmethod : D Stac kTes t• Emissio n facto r• Materia l balanc e Complete d b y /7uiufio> -&6Z&L/ ,Date_________
_ Theodo rHeber t

SPA-310 3 

### ?/:i/e i r 

### .- / 

# 5 1Ar-PLICATIU- 1 cZR A FZ?.1I T TO LrZPJaz A NAI RCONTAMINAN

T .SOURC E P.6 0

Picken' s Plastics , Inc
. Facilit y Nam

e 421 2 An nAve
. Facility

Addres s Ashtabula , Ashtabula , Pau l Nichola s Perso nt o Contac t P.O . Bo x127 9
4400 4 Mailin

g Addres s Ashtabula , OH 4400 4 City Count

y (216 ) 992-400 0 

### Zi p City

Stat e (216 ) 992-400 0 

### Zi p Telephone 020403026 9 Are

a R00 2 Numbe r Telephon

e 308 9 (Applicatio n No. , i f

thi s i s arenewa l application ) Std . Ind . Class . Cod e 1 . Complet e an d attac h any o f th e followin g appendice s mos tappropriat e t o th e ai rcontaminan tsource . I n addition , acomplianc e tim e schedul e for m i s t o b e attache d whe

n applicable . Chec

ka s appropriat e th e following : _Appendix A , Proces s [[Appendi x B , Fuel-Burnin g Equipment " [[Appendi x C , Incinerato r [[[Appendi x D , Surfac e Coatin g o r

~ Printin g Operatio n _Appendi x E , Storag e Tan k "Appendix H

, Gasolin e Dispensin g " ~ Facilit y _Appendi x3, Loadin g Rac k a t Bul k Gasolin e Plant o r Termina l _Appendi xK , Surfac e Coatin g [ Line o r Printin

g Lin e " _Appendi

xL , Solvent Meta l Cleanin g _Appendi

xM , Fugitiv

e Dus t Emissio nSource s Specify Appendi xNo . _Appendi xN , Rubbe r Tir e Manufacturin

g Appendix0 , Dr

y Cleanin

g Facilit y _Appendi

xP , Landfill s "Othe r Appendi x _Conpliance Tim

e Schedul e 2 ] Descriptio

no f Sourc e (sam

e a s usedo nappendix): Polyeste r Gelcoatl " g B °°» > 3 . You r identificatio

nfor Sourc e (sam

e a s usedo

nappendix): Gelcoatin g -t> Boot h#B- 6 „, I , bein g th e individua l specifie d i n Rul e 3745-35-02(B ) o f th e Ohi o Administrativ e Code , hereb y appl y fo raPermi tt o Operat e th e ai r contaminan tsource(s ) describe d herein . A s required , th e followin g additiona l documents ar e submitte d a s par to f thi s applicatio n (describ e al l attachments) : d^ —•=» Thomas J
. Picke n Authorize d Signature * President , Picken' s Pl'astics , Inc
. Titl e Jan
. 29 , 199 3 Dat e •Pursuan tt o Ok

C Rul e 3745-35-02 (B ) (Permi t t o Operate)
. Operatio no f

a nai rcontaminan t

sourc e vithou ta n effectiv e permi tt o operat e i s prohibite 3 t o 3704.0 5 Ohi o Revise dCode
. Pso e 1 EPA-316 1 

### G OP.6 1
rca5.s e No
. j.iurc e No
. applicatio n /

/ No
. /

/ /

• * • APPENDI X D SURFAC ECOATIN GO RPRINTIN

GOPERATIO

N 1
. Thi s appendi x i s submitte dfo r a : D Surfac e coatin g operatio n(chec k on e below) : Pain t spra y boot hFlo w coatin g Di p tan k

Rolle r coatin g X Spra y Coatin g (Othe r tha npain t

spra y booth ) Othe r surfac e coatin g operation , describ e
D Printin g o r

lithographi c operation
. 2
. Nam

e o f operatio nPolyeste r Gelcoatin g . You r identificatio n B- 6 Yea r Installe d 3
. I s thi s operatio nsucceede db y aheate ddryin g o r bakin g operation ? • Ye s 0 N o I f yes , indicat e operatin g temperatur e o f ove nN

A F
. 4
. Norma l operatin g schedule : 1 6 hours/day , 5 days/vk. , 5 2 vks./year
. PAIN T SPRA Y BOOT H " - *

• "*• » — — — "—-——"——-—"—- — % 5
. Typ e o f

spra y booth : • Enclose d•Conveyo r •Downdraf t

. • Other , describ e 6
. Boot hmanufacture r Devilbis s Mak e o r Mode l No
. XDO-40

9 7
. Typ e o f

spraying : • Ai r gu n0 Airles s D Electrostati c D Other , describ e '__ 8
. Sprayin g operatio nis : 0Manua l D Automati c .9.

_ Fa nmanufacture r

Hov e 1 1 Mak e o r Mode l Ko
. JJ421 2 & 10
. Booth' s exhaus t i s equippe dvith : D Wate r vas h(Complet e ite m11 ) E 3 Exhaus t

filter s (Complet e ite m12 ) D Baffle s D Other , describ e 

### • Non e 1 1
. Wate r

vash : (a ) I s wate r recirculated ? DYe s D N o N A(b ) I s achemica l adde dt o th e water ? DYe s Qu o

(c ) I s materia l reclaime dfro mwas hvater . DYe s D N o (d ) Describ e metho dfo r dispose l o f

wast e materials :

* Doe s no t

includ e meta l platin g


## <o\P.6 2

14 . (a ) Typ e o f material : D Fibergla s D Aluainu a
• Other , describ e (b ) Filte r siz e (inches) : Lengt h 2 0 " Widt h 20 " Thicknes s 2 " No . o f filters : 1 2 No . o f filte r changes : 5 1 time s pe r yea r _3 . Describ e materia l painte d Fiberglas s Mold s AL L OPERATION S (Excep t pain t spray booth ) Describ e typ e o f operatio n Pol Y este r Gelcoa t i s applie d t o th e surfac e o f th e mold s
use d t o produc e fiberglas s products . 15 . Describ e metho do f coatin g o r printin g Gelcoa t i s applie d vit hairles s spray.equipment .

16 . Identif y

an ddescrib e type(s ) o f materia l coate do r prlnted
_ (Coatin g i s transfere d t o th e surfac e o f th e molde d part) . Variou s Fiberlas s mold s

AL L OPERATION S 17 . Complet e th e followin g informatio nfo r eac hgenera l typ e o f surface coatin g o f printin g material . Repor t o nth e materia l a s i t i s employe dafte r th e additio no f any pigments , solvents , etc . I f there .ar e mor e tha nthre e type s o f materials , furnis hth e sam e dat a fo r th e additiona l ma-eri^l s on . a separat e shee t o r anothe r appendi xform . (a ) Materia l -employe d Mi x Resi n No . 944A08 3 Gra y Solid s conten t 4 9 Densit y 10.79 5 _lbs./gallo n X b y weigh t Solven tconten t51 X b y volum e o r % b y volume ; Solven t densit y 7.5 9 lbs./gallo n Norma l applicatio nschedule 1 5 hrs./day , 5 days/wk. , 5 2 vks./year . Quantit y

use d(gallons/hour) : Nonna i 2^ 0 Maximum Unknow n (gallon s /year) : 769 5 , Complet e th e solven t compositio nb y identifyin g eac hsolven t componen t an dit s respectiv e X b y volum e o f th e tota l solvent . (The X b y volum e shoul dtora i t o 100%) .

Solven tCompositio n Solven t Styren e Monome

r Hexylene Glyco l ME K X b y Volum e 48. 6 .2 0 .11 8 *

Y N N Solven t Solven tCompositio n

Dimethy l Phthalat e X

b y Volum

e 

# 3

* I f solven ti s photochemicall y reactiv e ente r"Y" , i f no tphotochemicall y reactiv e ente r"N" , i f unknow n ente r"U" . I s th e materia l photochemicall y reactive ? 0 Ye s 

### • N o • D

o no tkno

w



## 6 1P.63
_ •(b ) Materia l eoployedResi n Mi x No
. 944B02

5 Blac k Solid s conten t

47.3 7 %by volum e o r Densit y 10_14 6 lbs./gallc n % b y weigh t Solven t conten t 52.63 7, b y volum e Solven t densit

y 7 - 6 4 lbs./gallon Norma l applicatio

nschedule : l

hrs./day . 5 days/wk. , 5 2 vks./year . Quantit y

used(gallons/hour) : Norma l ' 2.73 Maximu m Unknow n (gallons/year) : 709. 8 Complet e the solven t compositio

nb y identifyin

g eac hsolven t componen t an d it s respective 7. b

y volum e of th

e tota l solvent . (Th e X b y volum e shoul dtota l t

o 100%) . Solven tCompositio n Solven t Styren e Monome

r Methyl Methacrylat e Dimethyl Rithalat e 7. b y Volum e 87.2 5 11.6 1 .82 8 *

Y U N Solven t Compositio n Solven t Hexylen e Glyco l ME K X

b y Volum e .10 5 .0 6 *

N N

* I f solven t i s photochemicall y reactiv

e ente r "Y" , i f no t photochemicall y reactive enter "N" , i f unknow nente r "U" . I s th e materia l photochemicall y reactive ? (c ) Materia l employed
_ Solid s conten t X b y volum e o r 

### E Ye

s • N

o Densit y X b y veigh t • D o no t kno w lbs./gallo n Solven t conten t

X

b y volum e Solven t densit y Norma l applicatio n schedule : hrs./day , days/vk.,
_ Quantit y use d(gallons/hour) : Norma l

(gallons/year) : _lbs./gallo n wks./year
. Maximu m Complet e th e solven t compositio

nb y identifyin

g eac hsolven t componen t an d it s respectiv

e % b y volum e o f th

e tota l solvent . (Th e X b y volum e shoul dtota l t

o 100%) . Solven tCoa i Solven t positio n X b y Volum e * Solven tCompositio n Solven t X b y Volum e • • *

18
. * I f

sclven r

i s photochemicall y reactiv e ente r "Y" , i f

no t photochemicall y reactiv e eater. . *'N" , i f unknow n ente r

"U"
. I s th e materia l photochemicall y reactive ? • Ye s D N o • D

o no t kno w Identif y al l liqui dorgani c cleanu p material s fo r thi s proces s an dindicat e th e amoun t use dpe r

averag e operatin g da y an dpe r year . Cleanu p Materia l Acetone * N Gallon s Use d
. Dail y 6. 8 Yearl y

1769

* I f materia l i s photochemicall y reactiv e ente r "Y" , i f

no t photochemicall y reactiv e er.te r "S", i f

unknow

n ente r "U"
.

^P.6 4

point s o f

al l material s an dfinishe dproducts
. Labe l al l material s includin g aiTborn e contaminant s an dothe r vast e materials
. Labe l th e proces s equipmen t an d contro l equipment
. CONTRO LEQUIPMEN

T !0
. Typ e o f

contro l equipnent : QNon e • Incinerator , Temp
. °F , Thermal/Catalyti c (Circl e one ) D Adsorption , 'describ e . • '
. • Condensation , describ e B Other , describ e Filtere dSpra y Boot h 21
. Manufacture r

DevilMs s Mode l No
. *D Q Yea r

Installe d198 5 22
. Percen t

collectio no r

remova l efficiency : Desig n. ^ X Operatin g ^
_ 23
. Fo r

non-incineratio nmetho didentif y specifi c pollutan t controlle dPolyester Gelcoa t
STACK DATA 24
. You r

stac k identificatio n 36 " Dianete r Roun d**** 25
. Ar e othe r

source s vente dt o thi s stack ? DYe s 0N o I f yes , identif y source s [
_ ^ 26
. Type : ERound , to p insid e diamete r dimensio n36 "
• Rectangular , top . insid e dimension s (L ) x (W ) 27
. Height : Abov e roo f ° ft.,-abov e groun d8 ft
. 28
. Exi t

gas : . Temp
. -BM

B °F , Volume 675 0 • ACPM , Velocit y 250 ft./min
. 29
. Continuou s monitorin g equipment : DYe s : • - f_fN o I f yes , indicat e Typ e - . . .'

- . . . . . , Manufacture r . --• • Mak e o r

Mode l • , Pollutan t (s ) monitore d 30
. Emissio ndata : Emission s fro mthi s sourc e hav e bee ndetermine dan dsuc hdat ai s include dvit htil s appendix : Dye s B N o I f yes , chec k

method : • Stac k

Tes t •Emissio nfacto r • Materia l balanc e Complete db y - //pJmffi.yvS/fof ,Date________ ^

rr;.*- . r ,~ . 

## 04 -P.6 5

=o r Offic e Us e Onl y Chec k Appropriat e box(es ) \ | Ai r Discharg e { | Wate r Discharg e t o New Sourc e Treatmen t Work s 1 I Soli d Wast e Disposa l Facility | | Hazardou s Wast e Disposa l Facility Fo r Offic e Us e Onl y PT I Applicatio n No . Dat e Receive d — Premis e No .

OHI O ENVIRONMENTA L PROTECTIO N AGENCY Applicatio n fo r Permi t t o Instal l NiCV cfeV\* AW V it. "Tu c Applicant' s Nam

e Mailin g Addres

s 

# XuT a 

# .,L H-U-.U-U

dito tM. m-it-nL-fr* City 

### k u Count y Stat

e Zi p Cod

e Telephone Number Perso n t o contac

t (Name and Titl e and Telephone Number ) Locatio n o

fPropose d Facilit y (Stat e th e locatio n a

s completely an d precisely as possible)* 

## fii>hf<k(-uJlL As/sldJA Woo? City o rTownshi p 

## 3021 Count y Zi p Cod e Standar d Industria l Classificatio n Cod e Directions : A Permi t t o Instal l i s require d fo r newo r modifie d sourc e o fpollutio n unde r th e provision s ofOA C Rul e 3745-31 . A n applicatio n cannot b e considere d complete unles s al l applicabl e question s are answere d an d th e require d informatio n ha s bee n submitted . Thi s applicatio n mus t b e signe d i n accordanc e wit h OA C Rul e 3745-31-04(B ) o r i t cannot be accepted . Applicants fo r permit s involvin g ai r emission s o r wastewate r treatmen t facilitie s wil l be require d t o pay a permi t t o instal l fe e a s show n i n Sectio n 3745.11(B ) an d (C ) o fth e Ohi o Revise d Code . Thi s fee i s payabl e fiftee n day s afte r th e date o

f fina l issuanc e o

fth e permit . Nam e o fne wo r modifie d sourc e o r facility : //tt'mmiitt. Produc t o

fne wo r modifie d source/facility : FlkeYt-sjas s -xag- k £o«."^*riaocA . Wil l th e proposed source/facility involve an y o fth e following : Chec k al l that apply . A . •Ai r Discharg e fte^Uw.U'a^ ? B . •Wastewate r Treatmen t Work s C . •Soli d Waste Disposa l Facility D . •Hazardou s Wast e Disposa l Facility

•Example

: "Th e sourc e wil l b e constructe

d o n a 2 0 acr e pb t t c b e loca'.s- d o n Franklin Townshi

p Roa d No. 17 . Esprcxin-.Etei

y 1 1/ 4 nvle s nsr.h o f th e ir.iersecv.cr

. c'. H't'.e

F.cr. e 9 ^ E-. i FrEnKli

n Townsfv p 

## 6 £P.6 6 

## X

OHI O ENVIRONMENTA L PROTECTIO N AGENC Y INSTALLATIO N SCHEDUL E T O ACCOMPAN

YAPPLICATIO N FO R PERMITTO INSTAL L

Thi s for m constitute s par t of th e applicatio n of : FACILIT YNAME f -WeWwc , 'TAQL. A

### i cTUe , ; ADDRESS : . Fo ra Permi t t o Instal l th e followin g ai rcontaminan t source : IDENTIFICATION : "b C LCsbG J^tis f QoKgcVo-o.
. , DESCRIPTION : /Wi V QcUfrftott , ,?frxA - Sg^t'rv a 3 iitettYg
. ^Wkft-AS
. e<A. 

# 7Zs*m LrtL J3 X

\kvkl \ IvAe^c

J gaefci ^ Ri«

. Th e installatio n o f th e above ai rcontaminan t sourc e i s planne d t o follo wth e tim e schedul e describe d below : DATE 1
. Equipmen t ordere d 2
. Commenc e Constructio n 3
. Startu p f W j y \*f\\ 4
. Performanc e Testin g 

# ftoW.: Tltte. uv.;k exUu*! - T o ivAuadL••Tac.t ,

# ( t 

# , A;*.- , \W
_ f\\<\ S»UJC\C S OVV - "W C 

### \i > ? Tntm irootL Afvre, 6ee„ CAptd ct*%d eu. i



# & £ >P.6 7 OHI O ENVIRONMENTA L PROTECTIO N AGENC Y APPLICATIO N FO R A PERMI TT O OPERAT E A N AI R CONTAMINAN TSOURC E 

### •ReV-fe* * ^Wfrk c\ » \v.c- 

## •^jg^ t riickotct Facilit y Nam e ¥X/0 fir>n five. Facilit y Addres s . Cit y County Zi p 

## n/c 99Z - Voce Perso n t o Contact Vl/* /?nrt. Ave Mailin g Addres s 

### Cit y 2/C Telephon e Are a Numbe r Count y 

### Zi

p Telephon e (Applicatio n No. , I fthi s i s a renewa l

application ) Are a Numbe r Standar d Industria l Classificatio n Cod e 1 . Complet e an d attac h an y ofth e followin g appendice s most appropriat e t o th e ai r contaminan t source . I n addition , a compliance tim e schedul e for m i s t o be attache d whe n applicable . Chec k a s appropriate th e following : Appendi xA , Appendi xB , Appendi xC , Appendi xD , Appendi xE , Appendi xH , Appendi xJ , Appendix K

, Proces s Fuel-Burning Equipmen

t Incinerato r Surfac e Coatin g o r Printin g Operatio n Storag e Tan k Gasolin e Dispensin g Facility Loadin g Rac k

at Bul k Gasolin e Plan

to rTermina

l Surfac e Coatin g Lin e o r Printin g Lin e Appendi xL , Appendi xM , Solven t Meta l

Cleanin g Fugitive Dus t Emissio n Source s (Specif y Appendi xNo. ) Appendi xN , Rubbe r Tir e

Manufacturin g Dr y Cleanin g Facility Landfill s

2 . Descriptio n o

fSourc e (sam e a s use d o n appendix) : 

# (jfaAhw i \-C) Appendi xO , Appendi xP , Othe r Appendi x' Complianc e Tim e Schedul e

3 . You r identificatio n fo r Sourc e (sam e a s used o n appendix) : I , bein g th e individua l specifie d i n Rul e 3745-35-02(B ) o fth e Ohi o Administrative Code , hereb y appl y fo r a Permi t t o Operat e th e ai r contaminan t source(s ) describe d herein . As required , th e followin g additiona l document s are submitte d a s par t ofthi s applicatio n (describ e al l attachments) : W7\")' AuthdSze d Signature * Titl e Date •Pursuan t t o OA C Rul e 3745-35-02(B ) (Permi t t o Operate) . Operatio n o

fa n ai r contaminan t source withou t a n effective permi t t o operate i s prohibite d t

o 3704.0 5 Ohi o Revise d Code . Pc?c - 1 EPA-31G 1 

# QIP.6 8

r Officia l Us

e Onl y "remis e No . aurc e No . Applicatio n No . Appendix A, Proces s Proces s Dat a 1 . • » 2 . 3 .

4 . 5 . 6 .

7 . 6 . 9 . 10 .
11 . 12 . 13 .

14 . Nam e o

f proces s ^i(r£?r».-aWt« > (pft-.w-ltv ^ SWAW h CUHIKO ^ En d produc

t o f thi s proces

s ^*tW,rtAWfr S ""^m. V »^ft> trwr l Primar y process equipmen

t 1W-A y\wAe.<_ s . Scad- k ^frill s ( ^tt«uv*a*ic Wvx A "Tftfel c 

# JB£
. Yea r installed 

# m i You r indentificatio n _ J-^S**- —Mak e or mode l Manufacture r Capacit y o f equipmen

t (lbs./hr.) : Rate

d Method o

t exhau ^ ventilation : •Stac k [_ ] Windo

wFa n •Roo

f Ven t Max . /fefrXfrg Q tttV A

Ar e ther e multipl e exhausts?

Norma l operatin g schedule : 

### J 3 Other , describ e "/* fti hah*/fiitl, D Ye s E l No OW

£ €J.VjUJ*b

V*» ' U/A ^ Operatin g Dat

a hrs./day , —£L!—days/wk. , . wks./yea r Percent annua l productio n (finished units ) b y season : Winte r +&/•

Sprin g — 2 C

A Summer &£~/( Fal l 

## &Tk /3Q 

# £4- Hourl y productio n rate

s (lbs.) : Average /JO Maximu m — **'?.. . "J?***.- sfrud^ o n -mx. tt p+mfm* ieaei v sV-aJUe- A \>« n . «/

© vr\.!v \ C S-Vc* ( ©w & Annua l productio n (indicat

e units ) 2-Zj «To o Projecte d percen tannua l increas e in productio n Type o f operation : P_ ( Con t If batch , indicate : Minute s per cycl e Material s used i n process : 

# ^L tinuou s

# flfl. •Batc

h Minute s betwee n cycles 

# n

a
Lis t o f Ra wMaterial s 

## •Af t Principa l Us e Amount (Ibs./hr. )

• »

A PROCES

S FLOV / DIAGRA M MUS TBE INCLUDE D V/IT H THI S APPENDIX. Sho w entr y and exi t point

s o f al l rav / material , intermediat

e products , by-products an d finishe d products . Labe l al l material s includin g airborn e contaminant s an d othe r wast e materials . Label the proces s equipmen

t and contro l equipment . (Continue

d on revers

e side ) 

## 6< &P.6 9
Contro l Equipmen t Code : A T ) Settlin g chambe r B\) Cyclon e C ) Multipl e cyclon e D ) Electrostati c precipitato r ;E) Fabri c filte r (F) Spraychambe r (G ) (H ) 

### 0 ) (J ) (K ) (L ) Cycloni c scrubbe r Impingemen t scrubbe r Orific e scrubbe r Ventur i scrubbe r Plate o r tra

y towe r Packe d towe r (M ) (N ) (0 ) (P ) (Q ) Adsorbe r Condense r Afterburner-catalys t Afterburner-therma l Other , describ e \

i . Contro l Equipmen t data :

ITE M (a ) Typ e (See abov e code ) (b ) Manufacture r (c ) Mode l No . (d ) Yea r installe d PRIMAR YCOLLECTO R 

## * + & "WskhNX-V-ftp& l T^« L "^ C CmtCXS (e ) You r identificatio n (f ) PollutantControlle d (g ) Controlle d pollutan t emissio n rat e (i fknown ) (h ) Pressure dro p 

# m i TbS >Cloo a SECONDAR YCOLLECTO R 

### O

99,9 7 % ^T - K4wrt_ \ 

# nm*/ ecf Wr 

# . (i ) Desig n efficienc y (j ) Operatin g efficienc y 

### JW___
_ Wl 

# w.sn STAC KDAT

A 16 . You r stac k

identificatio n 17 . Are othe r source s vente d t o thi s stack ? 18 . Type : L J Round , to p insid e diamete r dimensio n

\ \ Rectangular , to p insid e dimensio n (L )



### £UcU . Vi cl.»»yfi , U&feA . ^\-Call<_tW& . V\^W '
•ves g| N o •7 Tin-few* ! Rlf c

### J1Q

## nn~

# x(w) 19. Height : Abov

e roof 20 . Exi t gas : Temp . 

# M. ft. , abovegroun d ft .



# m=.

F , Volum e 21 . Continuou s monitorin g equipment :

I f yes , indicate : Typ e Mak e o r Mode l £/_2__ . ___ _ 

# D Ye s ACFM , Velocit y 

## • N O

. , Manufacture r f t ./min .

. , Pollutant(s ) monitore d 2 2 Emisssio n data : Emission s fro m thi s source hav e bee n determine d an d suc h dat a i s 

## /ifr DYe s DN O included wit h thi s appendix : Ifyes , chec k

method : Complete d [_JStackTes t J~ ] Emissio n facto r | | Materia l balanc e 

# b yrfZLJUU^

/-/*/-93
(o <\FICKEN' 3 PLASTIC S INC
.

247.5 ' 

## t\c*t t 

# ff S S 

### T

T s x 

## TT =

s t 

### §

V * 

## H 

## L Gelcoa t Boot h

£xWx.u<w \ "T . ^«*>v n H**K
CMe.Gowv^l«i« - £*cl\. . ^ii c /^'*» J ^<»y / 58 "P.7 1

: o r Offic e Us e Onl y Chec kAppropriat

e box(es ) [ | Ai r Discharg e j \ Wate r Discharg e t o Ne w Sourc e Treatmen t Work s Q Soli d Wast e Disposa l Facility r~ j Hazardou s Waste Disposa l Facility Fo r Offic e Us e Onl y PT I Applicatio n No . Dat e Receive d Premis e No .

OHI O ENVIRONMENTA L PROTECTIO N AGENCY Applicatio n fo r Permi t t o Instal l P.<-.kew rP-la W ic y J/ic . Applicant' s Nam

e 

### P. o. BtmX

fan* Mailin g Addres s /tfk4m.t)mm.U /UkhUU Off WOOY (a/6>)

tla-Veoo City Count y Stat

e Zi p Cod e Telephon e Numbe r (3/6) <ZHmm-vooc Perso n t o contac

t (Nam e an d Titl e an d Telephon e Number ) Vs/mi /!*,» Ayr

fiU

*t 

## hffiLocatio n o

f Propose d Facilit y (State th e locatio n e s completel y an d precisel y a s possible) * 

### /Isk + o-bJ* Axk-fc.hu lo. YVooY Cit y o rTownshi p

308<\ Count y Zi p Cod e Standar d Industria l Classificatio n Cod e Directions : A Permi t t o Instal l i s require d fo r ne wo r modifie d sourc e o f pollutio n unde r th e provision s of OA C Rul e 3745-31 . A n applicatio n cannot b e considere d complet e unless al l applicabl e question s ar e answere d an d th e require d informatio n ha s bee n submitted . Thi s applicatio n mus t b e signe d i n accordanc e wit h OA C Rul e 3745-31-04(B ) o r i t canno t be accepted . Applicants fo r permit s involvin g ai r emission s o r wastewate r treatmen t facilitie s wil l b e require d t o pa

y a permi t t o instal l fee a s show n i n Sectio n 3745.11(B ) an d (C ) o fth e Ohi o Revise d Code . Thi s fee i s payabl e fiftee n days afte r th e dat e q f fina l issuanc e of th e permit . Nam e o f ne wo r modifie d sourc e o r facility Produc t o

f ne wo r modifie d source/facility : 'fc-A^Yi afeotfUv 

# KH-hx
Wil l th e proposed source/facilit y involve an y o fth e following : Chec k al l tha t apply . A . D 8 Ai r Discharg e & H teeotWv*i\V k Xft*.A S 2.€fcWvi» \

ow e ?Mfc<t&avA< Oh

C fcoolVx Wastewate r Treatmen t Work s Soli d Wast e Disposa l Facilit y Hazardou s Waste Disposa l Facility Example : Th e source wil l b e constructe d o n a 20 acr e plo t t cbe locate d o n Frankli n Townshi p Roa d No
. 17 , e-orcxirr.e'.e' y1 MAmile s nort h ofth e ir.terser'.icr , c ! State Rout e 9 9 an d Fra'".'•'Ji n Townshi p *S..\>' "7 " B . C . D . 

# D D 

# •

" 7P.7 2



### OHI O ENVIRONMENTAL PROTECTION AGENC Y INSTALLATIO N

SCHEDUL E T O ACCOMPAN

YAPPLICATIO N

FO RPERMI T T O INSTAL L THI S FOR M CONSTITUTE S PART O

F TH E APPLICATIO N

OF : FACILIT YNAME : fie hex* f/dtt'cS

£/'

C:.. ADD R ESS : H2I2 flhh A- e Js6fe/?i</c> : 

### #A/b

yYOOV FO R APERMI TT O INSTAL LTH E FOLLOWIN G AI R CONTAMINAN TSOURCE : 

### IDENTIFICATION : 0*i/i/£iSS /-fadv/. JfflO

f/'*//'s/lju*

Av # J3J~/ DESCRIPTION: Tr'*?'X/2

/ /*/' Fi/fcr*c/

f/hisAftt*

&o/?* 

## n/fzf* /?;«. fen

$'£*A**tst/Ad-el

£r/-jo?'$~?/)

&'**«*?

Ms S-W U « * B-V l «-vv- i WWe l ?W(.fVol«-/j2 - "fced'owc e S*Vack . 8?-a . TH E INSTALLATION OF TH E ABOV E AI R CONTAMINAN TSOURC E I S PLANNE D T

O FOLLO WTH E TIM E SCHEDUL E DESCRIBE D BELOW: DATE l . EQUIPMEN TORDERE

D /7TJ 2 . COMMENC

E CONSTRUCTIO N - - - / ?<T ^ 

### 3
. STARTU P / jZ~7 4
. PERFORMANC E TESTIN G



## 1%E.73
_ OHI O ENVIRONMENTA L PROTECTIO N AGENCY APPLICATIO N FO R A PERMI TTO OPERAT E A N AI R CONTAMINAN TSOURC E 

### ^j'cVe-A * yio^kc y Tw « 

## r?ftvJl WtcViJ& s Facilit y Nam e V2/ 3 fin*. J- W Facilit y Address . . 

# peloid A fokkU* W#></ Cit y Count

y Zi

p 

## •2/ £ 9frl - Vcco Perso n t o Contac t Mailin g Addres s 

### Cit y Count

y Zi

p IIL 992. - 4/6O0 Telephon e Are a 

### Numbe r (Applicatio

n No. , I f thi s i s arenewa

l application

) Telephon e Are a 

### 3oS 9 Numbe

r Standar d Industria

l Classification Code 1 . Complet

e an d attach an

y o f th e followin

g appendices mos

tappropriate ' t o th e ai rcontaminan

tsource . I

n addition , acomplianc

e tim e schedul e for

m i s t o b e attache d whe n applicable . Chec

ka s appropriat

e th e following : 

# X Appendi

x A , Appendi x B , Appendi x C, Appendi x D, Appendi x E, Appendi x H , Appendi xJ , 

### Appendi x K , Proces s 

### Fuel-Burnin

g Equipmen

t Incinerato r 

### Surfac e Coatin g o r Printin g Operatio

n Storag e Tan k Gasolin e Dispensing Facilit y Loadin g Rac k

a t Bul k 

### Gasolin e Plan torTermina

l Surfac e Coatin g Lin e o r Printin g Lin e Appendi x L , Appendi x M , Solven

tMeta l Cleanin g Fugitiv e Dust Emission Source s (Specif y Appendi x No.) Appendi x N, Rubbe

rTir e Manufacturin g Dr y Cleanin g Facility .Landfill s


### 2 . Descriptio

n o f Source (same a s use d on appendix) : Appendi x O , Appendi x P , Othe rAppendi x Complianc

e Tim e Schedule
You ridentificatio

n fo rSourc e (same a s used o

n appendix) : 

# __& 3 I , bein g the individua

l specified i

n Rul e 3745-35-02(B) o

f th e Ohi o Administrativ

e Code , hereb

y appl y fo raPermi tto Operat

e the ai r contaminan

tsource(s ) described herein . A s required , the followin

g additiona l document

s ar e submitted a s par

to f this applicationjgescrib e al l attachments) : ^ , , _ mm-m-Cm-^*-m~m 

### Authorize d Signature * •^\rWi<i-* V ^>\c\(fe ^ \WWc s TK . 

### Titl e Dat e •Pursuan t t o OA C Rul e 3745-35-02(B ) (Permi t t o Operate) . 

### Operatio n o f a n ai rcontaminan

tsourc e withou

ta n effectiv e permi tto operat

e i s prohibite d t o 3704.05 Ohi

o Revised Code.

Paot 1 EPA-31C 1 

## 7 3P.7 4
o r Officia l Use Onl y remis e No . urc e No . ^plicatio n No . Appendi xA, Proces s Proces s Dat a 1 . Name o

fprocess ^TlfcviaWc g StuwAi* ^ c< f ^ftr-jVs ,

4 . 5 . 6 .

7 . 8 .
9 . 10 .
11 . 12 . 13 .

14 . nUwcAc.-i. c ^•*<?6'o.ce l ^WW^-Vi . 3 . Primar

y process equipmen

t 2 . En d produc

t o fthi s proces

s _ _— 

# i l You r indentificatio n _ Manufacture r PfcvUkte & Yea r installed Mak e or mode l 

# m\ 

# ^a . Capacit y o fequipmen

t (IbsVhr.) : Rate

d M faX-tiA Max . W TftftkdMethod o fexhau ^ ventilation : [_ 3 Stac k C l Windo

wFa n O Roo

fVen t D Other , describ

e Ar e ther e multipl e exhausts? E Ye s D No 7*» f-W , 1** Skclt * of>«.a*U* ^ Operatin g Dat

a Norma l operatin g schedule : J5 " hrs./day , - 5 , days/wk. , •••S O wks./yea r
•A T ft Percent annua l production (finished units ) b y season : Winte r Z^'A Sprin g — ^ /• Summer — ^ £

6 Fal l Hourl y productio n rate

s (lbs.) : Averag e _Maximu m TF^i e *^*&u ° * lots pan* > ImXt-eAd. Y m% SW-V** * &«**$*. / fy p«*U . pe* . *utf« aiW U 

## /3ooo Annua l productio n (indicat e units ) Projected percent annual increase i n productio n Type o foperation : E [ Continuou s Ifbatch , indicate : Minute s pe r cycl e Material s used i n process : . 

# JUL

•Batc h Minute s betwee n cycles
Lis t o fRa wMaterial s Principa l Us e Amount (Ibs./hr. ) 

# ja__
_

A PROCES

S FLOV / DIAGRA M MUS TB E INCLUDE D WITH THI S APPENDIX . Sho w entr y and exi t point

s o fal l ra wmaterial , intermediat

e products , by-products an d finishe d products . Label al l material s includin g airborne contaminant s an d othe r wast e materials . Label the process equipmen t and contro l equipment . (Continued on revers

e side ) 

# IkContro l Equipmen t Code : A ) B ) C ) .D ) .E ) IF ) Settlin g chambe r Cyclon e Multipl e cyclon e Electrostati c precipitato r Fabri c fille r Spra y chambe r P.7 5
(G ) Cycloni c scrubbe r (M ) (H ) Impingemen t scrubbe r (N ) (I ) Orifice scrubbe r (O ) (J ) Ventur i scrubbe r (P ) (K ) Plat e o r tray towe r (Q ) (L ) Packed towe r Adsorbe r Condense r Afterburner-catalys t Afterburner-therma l Other , describ e

i . Contro l Equipmen t data :

ITE M (a ) Typ e (See abov e code ) (b ) Manufacture r (d ) Mode l No . PRIMAR YCOLLECTO R

Yea r installe d [jW^fyf t ftik«.runsvtoos . (e ) You r identificatio n Pollutan t Controlle d (g ) Controlle d pollutan t emissio n rat e (i fknown ) (h ) Pressur

e dro p (i ) Desig n efficienc y 

### Wi^ 

## M t)u,s, V SECONDAR YCOLLECTO R



# X i 4 £ 

# y

(j ) Operatin g efficienc y U.V-.V-A O VOV UvvUvvovOvs . 

## SUU ^ W/m ^ ^ 

# s _Q_L L

STAC KDAT A 16 . You r stac k

identificatio n 17 . Ar e othe r source s vente d t o thi s stack ? L J Ye s [££) N o 18 . Type : [X l Round , to p insid e diamete r dimensio n

\ \ Rectangular , to p insid e dimensio n (L ) x(W) 19 . Height : Abov

e roo f— 20 . Exi t gas : Temp . r* w 9 i ft. , abov e groun d — , ~ ' €Actt_&Uk . tt. ( F , Volum e 2J£LfZTMm, Velocit y 

## J3 £ 21 . Continuou s monitorin g equipment :

If yes , indicate : Typ e Mak e o r Mode l 

## •ve s [^]N O

, Manufacture r

. , Pollutant(s ) monitore d . ft./mln .

22 . Emisssio n data : Emission s fro m thi s source hav e bee n determine d an d suc h dat a i s •include d wit h thi s appendix : 

## DYes K)N O If yes . chec k

method : QstackTes t Q Emissio n facto r [~ | Materia l balance Completed by " 7 .Dat e 

# i-w-n

7 SP.7 6

• > i : U i » •i a m o O , LU

$ o 

# 1

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### I •mt. c n r j »- i t •



## .1 U-, tr. Ki r» i r* i H

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### 3



## §

•^(f lP.7 7 OHI O ENVIRONMENTA L PROTECTIO N AGENC Y APPLICATIO N FO R A PERMI TT O OPERAT E A N AI R CONTAMINAN TSOURC E 

### -"UcU-gy ^ MoAie i Yv-x . 

# ^ n>cL \ &hFacilit y Nam e 

### VlLll. Jinn-

/!„. Perso n t o Contac t 

## %/hjJLAdkUtLm. ¥6f/ Cit y County Zi p Mailin g Addres s ^ . , , . Cit y County Zip 

### 2U - 992. Vcce Telephon e Are a Numbe r (Applicatio n No. , I fthi s i s a renewa l

application ) Telephon e Are a 

### 3oV9 Numbe r Standar d Industria l Classificatio n Cod e 1 . Complet e an d attac h an y ofth e followin g appendice s most appropriat e t o th e ai r contaminan t source . I n addition , a complianc e tim e schedul e for m i s t o be attache d whe n applicable . Chec k a s appropriate th e following : Appendi xA , Appendi xB , Appendi xC , Appendi xD , Appendi xE , Appendi xH , Appendi xJ , Appendi xK, Proces s

Fuel-Burnin g Equipmen t Incinerato r Surfac e Coatin g o r Printin g Operatio n Storag e Tan k Gasolin e Dispensin g Facility Loadin g Rac k

a t Bul k Gasolin e Planto rTermina l Surfac e Coatin g Un e o r Printin g Lin e Appendi xL , Appendi xM , Solven t Meta l

Cleanin g Fugitive Dus t Emissio n Source s (Specify Appendi xNo. ) Appendi xN , Rubbe r Tir e

Manufacturin g Dry Cleanin g Facility . Landfill s
Descriptio n ofSourc e (sam e a s use d o n appendix) :



### flssemLly

fiooth B lo Appendi xO , Appendi xP , Olhe r Appendi x Complianc e Tim e Schedul e

tmn.it. <i

o< 

## V 3 . You r identificatio n fo r Sourc e (sam e a s used o n appendix) : I , bein g th e individua l specifie d i n Rul e 3745-35-02(B ) o fth e Ohi o Administrative Code , hereby appl y fo r a Permi t t o Operat e th e ai r contaminan t source(s ) describe d herein . As required , th e followin g additiona l document s ar e submitte d a s par

t o fthi s applicatio n ^describ e al l attachments) : Autnf c signature* 

### nne*iA^V^vcW- v tAuAt o A Titl e Dat e •Pursuan t t o OA C Rul e 3745-35-02(B ) (Permi t t o Operate) . Operatio n o

fa n ai r contaminan t sourc e v/ithou t a n effective permi t t o operate i s prohibite d t o 3704.0 5 Ohi o Revise d Code . Pcce- 1 EPA-31C-1 

## T 7P.7 8 

## X
o r Officia l Us e Onl y •remis e No . 

### Sourc e No . applicatio n No . Appendi x A , Proces s Proces s Data 1 . 2 . 3 .


### 4 . 5 . 6 .

7 . 8 .
9 . 10 .
11 . 12 . 13 .

14 . Nam e ot proces s •VTUfta.q^s ^ Mwdt . Uo-L7«7r>\*M-.W Q ••* - Asae-Aii-U ^ En d product o f thi s proces s 

### •Ui-t.tt* U Primar y proces s equipmen

ty^* * ( S&UJ > 

### , Rou.W_ > Pneu.-M.eLAn ' c You r indentificatio n 

# _£Ac

_ Yea r installe d 

# J3 & Manufacture r Sfcy-A. ; ft^fr «-v*.4- ft-Vfr Mak e o r mode l f W Speciei c Capacity o

f equipmen t (IbsJhr.) : Rate d M ftfrWl Max . Uo V ftaW Metho d o

f exhaus t ventilation : J ^ Stac k D Windo wFa n O Roo f Ven t C 3 Other , describ e Are there multipl e exhausts ? •Ye s ( 3 N o Operatin g Dat a Norma l operatin g schedule : hrs./day , __s_—days/wk. , - wks./yea r Percen t annua l productio n (finishe d units) by season : Winte r . -*••

* /• Sprin g —- ^ A Summe r — •r-K/ a Fal l 

### __4___ . Hourl y productio n rate s (lbs.) : Averag e Maximu m >o u „ . 77i« c Sf-udi* * InA^c^t* . - V U*ih> A. V OL (o pouful- veucX . c*.u . U t T-Vv.v'tli-t.cL t n S>wim v Annua l productio n (indicate units ) V&cx s ; 

### yw-g, . Projecte d percen t annua l increas e i n productio n Typ e o f operation : [_ 3 Continuou s ! Q Batc h I f batch , indicate : Minute s pe r cycl e if** Minute s betwee n cycle s ''rr Material s use d i n process : Lis t o f Ra wMaterial s Principa l Us e Amoun t (ibs./hr. ) 

### Plusctti p CioC

&nJmo^ftgf.w-t - /6 . PoUyytis .

A PROCES S FLOW DIAGRA M MUSTB E INCLUDE D WIT H THI S APPENDIX . Sho w entr y an d exi t points o

f al l ra wmaterial , intermediate products , by-product s an d finishe d products . Labe l al l material s includin g airborn e contaminant s an d othe r v/aste materials . Labe l th e proces s equipmen t an d contro l equipment . (Continue d o n revers e side) 

# i lP.7 9 Contro l Equipmen t Code : A ) Settlin g chambe r B ) Cyclon e C ) Multipl e cyclon e D) Electrostati c precipitato r ;E ) Fabri c filte r ;F ) Spray chambe r (G ) (H ) 

### 0 ) (J ) (K ) (L ) Cycloni c scrubbe r Impingemen t scrubbe r Orific e scrubbe r Ventur i scrubbe r Plat e o r tray towe r Packed towe r (M ) (N ) (0 ) (P ) (Q ) Adsorbe r Condense r Afterburner-catalys t Afterburner-therma l Other , describ e

i . Contro l Equipmen t data :

ITE M (a ) Typ e (See abov e code ) (b ) Manufacture r (c ) Mode l No . (d ) Yea r installe d (e ) You r identificatio n (f ) Pollutan t Controlle d (g ) Controlle d pollutan t emissio n rate (i fknown ) (h ) Pressur

e dro p (i ) Desig n efficienc y 1 (j ) Operatin g efficienc y PRIMAR YCOLLECTO R 

# E mai » A w>!W. t r\t*\t , 

# m B/o Jfcus f JDu^ V Cov\Uve V Unk-AeVgw

Uv-vk-nouJv

v /lA<keaMea. <ft% SECONDAR YCOLLECTO R

> . / 

## s# sf 

# .< r

# * + < ? C V

16 . You r stac k

identificatio n 17 . 18 . STAC KPAT A 

## B\ 6 Ar e othe r source s vente d t o thi s stack ? L J Yes [)£ j N o Type : fc__J Round , to p insid e diamete r dimensio n

\ \ Rectangular , to p insid e dimensio n (L ) x(W )

/ ft., abov

e groun d Iv

ft . 19. Height : Abov

e roof 20 . 21 . Exi t gas : Temp . lk*S. ° F , Volum e 4S- 2 ACFM , Velocit y ^£ l Continuou s monitorin g equipment : | ] Ye s i2_ J N o I fyes , indicate : Typ e \ , Manufacture r Mak e o r Mode l , Pollutant(s ) monitored ft./mln .

22 . Emisssio n data : Emission s fro m thi s source hav e bee n determine d and suc h dat a i s Included wit h thi s appendix : [_ J Ye s yQ N o Ifyes , chec k

method : j_]stac k Tes t Q Emissio n facto r J_ J Materia l balance Complete d b

y _,Dat e 

# it

### F::K=rc* 3 FUSTIC S IKC
.

209.9 '

Open Ai r Concret e .Doc k Tri mBoot h
Tri mBoot h



# 3te 

# - r H 1 - 

# **i ^ 

# «.

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= : Loadin g Dock s 36 ! 37.4 '

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.

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v OP.8 1



### ATTACHMEN T 3 P icken' s p] g s t ic s , Inc . Use d i n Spray/lay-u p Booth s ROOl , R004 , R005 , R00 6 D C %••. Phot o R

X Releas e Calculation s pe r CT B Ga l of : Mi x Resi n No . 75-373 0 Componen t -S

l i

i Resi n No : 75-373 0 ! Volum e Mi x Ration : 97V i | Specifi c gravity : 1. 1 j Weigh t V. VOC : 46'/ . i Organi c Chemica l V. b ywt . Styrene : 46V , j Alph a Methy l I Styrene : 1.5 % j
i Componen t Catalys t ] 1 . 5*/ . 1 .08 4 4 1 '/ . Dimethy l Phthalat e Hexylen e Glycol : MEK : # 2

DDM 9

: 32V , 6 % 3 % Componen t # 3 Styrid : P5505001 P 1.5 % .7 9 5 3 - 55V . Minera 1 Spirits : 54.5V . b yvolum e Therefor e V. volum e componen t # 1 equals : NOTE : Combin e Styren e an d Alph a Methy l Styren e (S q75-373 0 x 8.33 ) (wt % VO C Styrene ) Densit yStyrene/gal . (1. 1 x 8.33 ) (47.5'/. )

7.58 7 */ . Volum e Styren e

57.3 7 V. Volum e Styren e */ • Vo l Styren e x V, mi x rati o = V. Vol . Styren e Pe r CT G Gal . 57.3 7 x 9 7 = 55.6 4 •/ . Vo l Styren e Pe r CT G ga l Therefor e */

. Vo l Componen t # 2 equal s (1.084 0 x 8.33)(.32 )
= 29*/ , byvol . Dimethy l Phthalat e (DP )

9.9 3 29V . x 1.5 % = .43 6 •/ . byvol/CT G Gal . (DP ) (1.084 0 x 8.33)(.06 ) 7.7 1 7.027 . x 1.5*/ , = 7.02V . Vol . Hexylen e Glyco l (HG ) .105 % Volatil e b

yvolume/CT G Ga l Hexylen e Glyco l (1.084 0 x 8.33)(.03 ) 6.7 5 4. 0 V, V: • I-. ' /
. = 4.0V . Vol . ME K .0 6 V< byVc l /CT G Gel . ME K 

## 9 [P.82
_

MI X RESI NNO . 75-373 0 SOLVEN T COMPOSITIO N Therefore ; '/

. b yvolume : Componen t # • 3 equals : 54.5'/.' x 1. 5 = .82'/ . minera l spirit s pe r CT G gal . '/ . Compositio n CT G Gal . Compostio n % Volum e pe r Gal , o f Solven t Styren e 55.6 4 '/ . = 97.5 4 '/ . Dimethy l Phthalat e .436*/ . = .7 6 % Hexylen e Glyco l .105 % = .1 8 % ME K .0 6 % = .105 % Minera l Spirit s . 8 % 1.4 0 % Tota l % Vol . 57.0 4 % 99.985 % Solven t Densit y 0 C % Comp . x Density = Pounds/ga l Solven t Densit y Styren e 97.54 % x 7.58 7 = 7.4 0 > Dimethy l Phthalat e .7 6 % x 9.9 3 = .075 * Hexylen e Glyco l .1 8 % x 7.7 1 = .014 * 7.58 8 ME K .105 % x 6.7 5 = .007 * Minera l Spirit s 1.4 0 % x 6.5 9 = .0923

- Note : Thi s resi n mi x contain s styren e suppressent . Therefore ; fo r eac h CT G gal . used , assum e 6 % styren e los s t o th e atmosphere . Therefore : 1 CT G Gal . ha s a ne t los s of : 55.64 % x 7.58 7 x .06 % = .25 4 pounds/ga l styrene .



# <\WP.8 3

Picken' s Plastics , Inc . Use d i n Spray/lay-u p Booth s ROOl , ROO4 bR005 , ROO 6 O C %>. Phot o R

X Releas e Calculation s pe r CT G Ga ] of : Mi x Resi n Mo . Aropo l Q6022 S Componen t -S

l Componen t *i2 Componen t #3 Resi n No : Aropo l Q6022 S Catalys t DDM 9 Styrid : P5505001 P Volum e Mi x Ration : 97 % 1.5 % 1.5 % Specifi c gravity : 1.08 8 1.08 4 .7 9 Weigh t % VOC : 46 % 4 1 % 5 3 - 55 % Organi c Chemica l % bywt . Styren e 46 % Dimethy l Phthalate : 32 % Minera l Hexylen e Spirits : 54.5 % Glycol : 6 % byvolum e MEK : 3 % Therefor e % volum e componen t tti equal s : (S q6022 S x e.33)(w t % VO C Styrene )

. = y . Volum e Styren e Densit yStyrene/gal . (1.08 8 x 8.33)(.46 ) = 54.9 5 % Volum e Styren e 7.58 7 V. Vo l Styren e x % mi x rati o = % Vol . Styren e Pe r CT G Gal .

54.9 8 x 9 7 = 53.3 3 % Vo l Styren e Pe r CT G ga l Therefor e % Vo l Componen t # 2 equal s (1.084 0 x B.33)(.32 )
= 29 % byvol . Dimethy l Phthalat e (DP ) 9.9 3 29*/ . x 1.5 % = .43 6 % byvo l /CT G Gal . (DP ) (1.084 0 x 8.33)(.06 )
= 7.02 % Vol . Hexylen e Glyco l (H G 7.7 1 7.02 % x 1.5 % = .105 % Volatil e b yvolume/CT G Ga l Hexylen e Glyco l (1.084 0 x 8.33)(.03 ) = 4.0 % Vol . ME K 6.7 5 

# nhP.8 4

MI X RESI NAROPO L Q6022 S SOLVEN T COMPOSITIO N Therefor ; % byvolume : Componen t tt 3 equals : 54.5 % x 1. 5 = .82 % minera l spirit s pe r CT G gal . % Compositio n CT G Gal . Compostio n % Volum e pe r Gal , o f Solven t Styren e 53.3 3 % = 97. 4 % Dimethy l Phthalat e .436 % = .7 9 V. Hexylen e Glyco l .105 % = .1 9 % ME K .0 6 % = .109 % Minera l Spirit s .8 2 % = 1.5 0 % Tota l % Vol . 54.7 5 % 99.989 % Solven t Densit y O C % Comp . x Density = Pounds/ga l Solven t Densit y Styren e . 97. 4 % x 7.58 7 = 7.3 9 3 Dimethy l Phthalat e .7 9 % x 9.9 3 = .0783

- Hexylen e Glyco l .1 9 % x 7.7 1 = .015 } 7.58 9 ME K .109 % x 6.7 5 = .0073

- Minera l Spirit s 1.5 0 % x 6.5 9 = .0993

- Note : Thi s resi n mi x contain s styren e suppressent . Therefore ; fo r eac h CT G gal . used , assum e 6 % styren e los s t o th e atmosphere . Therefore : 1 CT G Gal . has^e—-Re t los s of : 53.33 % x 7.58 7 x .06 % -( .243ypounds/ga1 styren e



# oi ^



# ? *P.8 5

Picken' s Plastics , Int . Use d jr . Spra y/lay-u p .booths ROOl , F;004 , F\005 , F;00 6 O C & Phot o R X Releas e Calculation s per^CT G Ga l of :

Mi x Resi n No . Kopper s Dio n F R 6,004 T Componen t -K

l Componen t tt2 Resi n No : 6604 1 Catalys t DDM 9 Volum e Mi x Ration : 98.5 % • 1.5 % Specific , gravity : 1.1 8 "1.08 4 Weigh t % VOC : 40 % 4 1 % Organi c Chemica l % bywt . Styren e 40 % Dimethy l Phthalat e 32 % Hexylen e 61yco l 6 % ME K 3 % Therefor e % volum e componen t tti equal s : (S q6604 T x e.33)(w t V. VO C Styrene ) s y, Volum e Styren e Bensi.t yStyrene/gal . (1.1 B x e.33)(.40 )

_= 51. 8 %

7.58 7 •/ « Vo l Styren e x mi x rati o = V. Vol . Styren e Pe rCT G Gal . 51. 8 x 98. 5 = 51.0 4 % Vo l Styren e Pe rCT G ga l Therefor e V. Vo l Componen ttt2 equal s (1.084 0 x 6.33)(.32 ) = 29'/. b y vol . Dimethy l Phthalat e (DP )

9.9 3 29 % x 1.5 % = .43 6 % b y vol/CT G Gal . D P (1.084 0 xB.33)(.06 ) 7.02 % Vol . Hexylen e Glyco l (H G 7.7 1 7.02 % x 1.5 % = .105 % Volatil e b y volume/CT G Gal . Hexylen e Glyco l (1.0E4 0 x 8.33)(.03 ) ij.o % Vo ) . ME K 6.7 5 4 . 0 V . x 1. 5 V

. « = .0 6 V

. b y Vol/CT G Bai . ME K 

# •B SP.8 6

MI X RESI NKOPPER S DIO NF R 6604 T SOLVEN T COMPOSITIO N
* / Compositio n CT G Gal . CofT.postio n % Volum e pe r Gal , o f Solven t Styren e 51.0 4 V, = 9B.e 3 V. Dimethy l Phthalat e .436 % = - .844 % Hexylen e Glyco l .105 % = -.203 % ME K .0 6 % .116 % Tota l % Vol . 51.6 4 V. 99.9 9 V, Solid s fro m

resi n 47.4 8 Solid s fro mcatalys t . 6 Solven t Densit y O C V- Comp . x Den£ity = Pounds/ga l Solven t _;

_Dens i t v Styren e 98. 8 % x 7.58 7 = 7.5 0 > Dimethy l Phthalat e .e44 % x 9.9 3 = .0 8 J Hexylen e Glyco l .203 % x 7.7 1 = .0 2 > 7.6 1 ME K .116 % x 6.7 5 - .008 3 Note : Thi s resi n mi x doe s no t contai n styren e suppressent . Therefore ? fo r eac h CT G gal . used , assum e 11V J styren e los s t o atmosphere . Eac h CT G gallo n o f resi n mi x contain s 51.0 4 V. b yvolum e styren e an d 11 % o f thi s i s los t t o th e atmosphere . Therefore : 1 CT G Eal . ha s a ne t los s of : 51i04 % x 7.58 7 x 11 % ='.42 5 pound s styren e



# I tP.8 7

Picken' s Plastics , Inc . Use d i n Ge l Cos t Boot h R00 2 O C + Phot o RX Releas e Calculation s pe r CT G Ga l of :

Mi x Resi n No . 944A0B 3 Gray . Componen t tti Componen t tt2 Resi n Ha: 944A08 3 • Catalys t DDM 9 Volum e Mi x Ration : 98.5 % 1.5 % Specifi c gravity : 1.3 0 1.08 4 Weigh t % VOC : 35.847 % 4 1 % Organi c Chemica l % bywt . Styren e 35.847 % Dimethy l Phthalat e 32 % Hexylen e Glyco l 6 % ME K 3 % Therefor e % volum e componen t -11 1 equal s : (S q944A08 3 x 8.33)(w t % VO C Styrene ) = % Volum e Styren e Densit yStyren e (1.3 0 x 8.33)(35.85 ) = 51.1 7 %

7.58 7 % Vo l Styren e x mi x rati o = % Vol . Styren e Pe r CT G Gal .

51.1 7 x 98. 5 = 50.4 0 % Vo l Styren e Pe r CT G ga l Therefor e % Vo l Componen t tt2 equal s (1.084 0 x 8.33)(.32 )
= 29 % b yvol . Dimethy l Phthalat e (DP ) 9.9 3 2 9 % x 1.5 % = .45 6 % byvol/CT G Gal . D P (1.084 0 x 8.33)(.06 )
= 7.02 % Vol . Hexylen e Glyco l 7.7 1 7.02'/ . x 1.5 % = .105 % Volatil e byvolume/CT G Gal . Hexylen e Glyco l ( 1.084 0 x 8.33 ) (.03 )

= 4 y , vol . ME K 6.7 5 4 % x 1. 5 % = .0 6 V. byVol/CT G Gal . ME K 

# ? 7P.8 8

MI X RESI NGE L COA T .944A08 3 GRAY SOLVEN T COMPOSITIO N
CT G Gal . Compos t io n % Volum e % Compositio n pe r Gal , o f Solven t Styren e 50. 4 % Dimethy l Phthalat e .436 % Hexylen e Glyco l .105 % ME K .0 6 % 98. 8 % .8 5 % .2 0 % .118 % Tota l 51.0 0 % 99.968 % Solven t Densit y O C % Comp . x Density = Pounds/ga l Solven t Dens i t y Styren e 98. 8 % x 7.5 8 = 7.4 9 3

- Dimethy l Phthalat e .85 % x 9.9 3 = .0 8 > Hexylen e Glyco l .20 % x 7.7 1 = .015 } 7.5 9 ME K .118 % x 6.7 5 = .008 J Thi s resi n mi x doe s no t contai n styren e suppressent . Therefore ; fo r eac h CT G gal . used , assum e a 30.5 % emissio n facto r fo r Styren e Monomer . Eac h CT G gallo n o f resi n mi x contain s 50. 4 % b yvolum e styren e an d 30.5 % o f thi s i s los t t o th e atmosphere . Therefore : 1 CT G Gal . ha s a ne t los s of : 50.4 % x 7.58 7 x 30.5 % = 1.1 7 pound s styren e



# < HP.8 9

PICKEN' S PLASTICS , INC . USE D INGE L COA T BOOT H R00 2 O C + PHOT O R

X RELEAS E CALCULATION S FE R CT G GA L OF : MI X RESI NNO . 944B02 5 BLAC K Componen t # 1 Componen t V.2 Resi n No : 944B02 5 Catalys t DD M 9 Volum e Mi x Ratio : 98.5 % 1.5 % Specifi c Gravity : 1.2 2 1.0B4 0 Wt . % VOC : 39.7 9 4 1 % Organi c Chemica l % b ywt . Styren e 34.8 1 Dimethy l Phthalat e 32 % Methy l Methacrylat e 4.8 3 Hexylen e Glyco l 6 % ME K 3 % Therefor e % Volum e Componen t tti equals : (S q944B02 5 x 8.33)(W t % VO C Styrene )
= y . Volum e Styren e Densit yStyrene/ga l (1.2 2 x 8.33)(34.81 )

- 46.62 % Volum e Styren e 7.58 7 % Vol
. Styren e x mi x ratio = % Vol
. Styren e pe r CT GGal
. 46.6 2 x 98. 5 = 45.92 % Vol
. Styren e pe r CT GGal
. (1.2 2 x e.33)(4.e3 )
= 6.20 % Volum e Methy l Methacrylat e (MM ) 7.9 1 6.20 % x 98. 5 = 6.11 % Vo l M M pe r CT G Gal . Therefor e % Volum e Componen t tt2 equal s (1.084 0 x 8.33)(.32 ) = 29 % b y volum e Dimethy l Phthalat e (DP ) 9.9 3 29 % x 1.5 % = .436 % byvolume/CT G gal . D P (1.084 0 x 8.33 ) (.06 )
= 7.0 2 % Volum e Hexylen e Glyco l 7.7 1 7.02 % x 1.5 % = .10 5 b yvolume/CT G gal . Hexylen e Glyco l (1.0S4 0 x 8.33 ) (.03 )

= 4./ , Volum e ME K 6.7 5 4 % x 1.5 % = .06 % b vvolume/CTG

- oal . ME K 

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MI X RESI NGE L COA T 944B02 5 BLAC K SOLVEN T COMPOSITIO N CT G Gal . Compositio n % Vo l Compositio n pe r Ga l o f Solven t 87.2 5 1 1 .6 1 .82 8 .2 0 .11 4 10 0 % Styren e Methy l Methacrylat e Dimethy l Phthalat e Hexylen e Glyco l ME K Tota l 45.92 % 6.1 1 %

. 436 %

. 10 5 .0 6 52.63 %

7.5 8

7.9 1 9.9 3 7.7 1 6.7 5 =

= = = = 6 .6 1 > .9 2 3

- .0 8 > .0 2 > .0083

- 7.6 4

lbs./ga l O C % Comp . x Density = Pounds/ga l Solven t Dens i t y Styren e 87.2 5 Methy l Methacrylat e 11.6 1 Dimethy l Phthalat e .82 8 Hexylen e Glyco l .2 0 ME K .11 4 Thi s resi n mi x doe s no t contai n suppressen t fo r styren e Therefore ; fo r eac h CT G gal. , used , assum e a 30.5 % emissio n facto r fo r styren e monomer . Eac h CT G gallo n o f resi n mi x contain s 45.92 % b yvolum e styren e and 30.5 % o f thi s i s los t t o th e atmosphere . Therefore , on e CT G gallo n ha s a ne t los s of : 45.92 % x 7.58 7 x 30.5 % = 1.06 3 pound s styrene .

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### SIT E VISI T QUESTIONNAIR E COMPOSITE S FACILITIE S - OH , P A

Augus t 199 3



# aI . 

# k:fb Facilit yInformatio n

- Compan yname/lega l owne r

- Addres s

- Contacts , phon e nos .

- No . o f employee s ~ loo T,d f-h-mer-t

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### I I . Productio n Processe s

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### \ «_ f *'*- - productio n schedul e 0<£rA

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### - 199 2 productio n (units , tons , etc. ) *br*-c. /_ : /_v-y-g&

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### - 199 2 emission s total s (VOC , styrene , othe r HAPs ) T^" r 

### ' '"y o j) S 

## 'cU ',«III . Resins/Ge l Coat s I °Y- $f>*^- cy

,, j^- Identit yo f resin s & ge l coat s used/functio n o f eac h- >fr t e ~ * -•-*fS~J- c^. y*- *+*Jte j ^ 

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### - An yothe r HAP s involved ? (refe r t o HA P list ) 26-_;s

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- Fillers/additives/mol d releas e agent s /

- MSDS' s fo r principa l material s gp m

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### IV . Spra yBooth s

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- filte r type , size , changeou t schedul e p .

- spra yeguipmen t (typ e used , lifetime , advent . & disadv. , consideratio n o f upgrade d equipment )

V . Ai r Management/Contro l System s

- What ai r managemen t practice s ar e i n plac e a t facility ?

- T o wha t proces s operation s d o thes e practice s apply ?

- Technica l descriptio n o f ai r managemen t syste m

- Proces s parameter s (ai r flo wrates , ai r velocities , concentration s a t collectio n points )

- Ar e anycontro l device s installed ? (inlet/outle t concentrations , contro l efficiency , installe d cost , cost s o f operation ) 

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### VI . Contro l Measure s

- Wha t measure s hav e bee n take n o r contemplate d t o reduc e VOC/HAPs ?

- Wha t i s feasibilit yof : a ) lowering styren e conten t . b ) increasing fille r conten t -As**-*- ; •«-££_ £ 

# T ej ) usin g othe r monomer s

./pt f us e o f vapo r suppressant s e ) add-o n control s

- Doe s th e facilit yhav e a specifi c environmenta l program ?

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### VIII . Regulation s

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- Wha t ar e th e applicabl e OSH Alimits ? Ho w me a sured/frequency ?
Ha s th e facilit yuse d o r ar e yo u familia r wit h th e SP I Stati c Tes t Method ?



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