prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

c. Physical Appearance 

2128/11 

(EPA Method 9095} 

Solid (EPA Method 9095} 

Gas (ambient temperature & pressure} 

Color Orange, cloudy Odor 

Number of Solid or Liquid Phases of Separation 

2 

No 

Describe each phase of selpar·ati,on .. l!!J'.8._ _ __________ _____ -J 

a. 

d. 

e. 

procedures employed the laboratory(ies) is 

attached. The EPA approved method to test each analyte is listed on the attached laboratory 

results. Fairway Laboratories is accredited by the Pennsylvania Department of Environmental 

Protection. 

generator knowledge in 

- 1 -

No 

N/A 
c. 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

Name 

Title 

Phone 412-977-5959 Email Address MBowser@advancedwasteservices.com 

d. Volume of 

75,200 

or 

[81 gal 

un•rvr<.ru"' year. D lb D ton (check one) 

a. Solid waste permit number(s) for processing or disposal facility being utilized. 

c. 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

Facility 

Title 

Phone 

County 

Email Address 

d. Volume of waste shipped to processing or disposal facility in the previous year. D cu yd D gal D lb D ton (check one) 

b. Volume of waste beneficially used in the previous year. 

N/A D cu yd D gal D ib D ton (check one) 

-2-
_._ ___ ~not~ocl. 

-

F()t& SUbmttted: F8J FQilll 26R 

[j otb8r(speelfy) -------------- P.a~ 'ubmttt~: 

t ce'*'fv the lrifolmatlon requlr'tid-ln Sectloli &-2, Ch~mt¢~· Al,laJv•ls ~~a ~upplied tq ltte Dapart~J~ent for the y~ar J2j:Jl ~n~ ~otchanged -- -

PO.!m S~ct. I8J FfJPtl2fiR 

0 ou.- {specify) 

-----------------------------

P.te :S-Ilted: ~ ~ iJl.!J lnf9rmatlon req!i~~Jn S~otlon B-3, Process p~~UQn arnfSchematlc,. vnrs supplied to the DepaFtment 

(or lh4t y~ar 2010 and has n&t changed. 

Fonn Submitted: 1!81 Fom:I26R 

0 Ql_h$-(speclfy) -------------

0.W S

_1,1bmftted: ~m• ~~poflatble Official 

-3-

Tl

_

be 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Joe Kunst 

Project: KEYSTONE CLEARWATER~ 

ProjectNumber: 10241-3 

Collector: JK 

Number of Containers: 17 

Reported: 

08/23/10 10:55 

ANALYTICAL REPORT FOR SAMPLES 

lsampleiD 

SLAVEK 1H 

Test Uncert. 

Gross Alpha +/- 299.0 

Gross Beta 

Radium226 

Radium228 

+/- 80.19 

+/- 8.97 

+/- 25.95 

Fairway Laboratories, Inc. 

y_ and Submitted by: 

Michael P. Tyler 

Laboratory Director 

Laboratory ID 

OG20037-01 

Matrix Date Sampled Date Received 

Water 07/20/10 10:30 07/20/10 12:40 

11re results ill this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced in its entirety. 

Page 1 of9 
ARM Group 

2013 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte 

Metals by EPA 200 Series Methods 

Silver 

Aluminum 

Arsenic 

Boron 

Barium 

Beryllium 

Calcium 

Cadmium 

Cobalt 

Chromium 

Copper 

Iron 

Mercury 

Lithium 

Magnesium 

Manganese 

Molybdenum 

Sodium 

Nickel 

Lead 

Fairway Laboratories, Inc. 

Result 

<0.0200 

<0.250 

0.0968 

4.87 

420 

<0.00500 

1160 

<0.0100 

0.157 

0.00782 

<0.0500 

26.7 

<0.000200 

11.6 

141 

1.72 

<0.0500 

5320 

0.137 

<0.0100 

Project: KEYSTONE CLEARWATER 1 

Project Number: 10241-3 

Collector: JK 

Number of Containers: 17 

Reported: 

08/23/10 10:55 

Date/fime Sampled: 07/20/10 10:30 

OG20037-01 (Water) 

Laboratory 

Reporting 

Limit Units 

Date /Time 

Analyzed Method Analyst Note 

0.0200 mg/1 07/28/10 04:34 EPA200.7 rb 

0.250 mg/1 07/28/10 04:33 EPA200.7 rb 

0.0200 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

1.00 mg/1 07/28/10 04:34 EPA200.7 rb Ll 

0.00500 mg/1 07/28/10 04:34 EPA200.7 rb 

10.0 mg/1 07/28/10 04:38 EPA 200.7 rb 

0.0100 mgll 07/28/10 04:34 EPA200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA200.7 rb 

0.00500 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA200.7 rb 

2.00 mg/1 07/28/10 04:39 EPA200.7 rb Ll2 

0.000200 mg/1 08/12/10 08:10 EPA 245.1 cb 

5.00 mg/1 08/02110 23 :19 EPA200.7 sub SCI 

10.0 mg/1 07/28110 04:38 EPA200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

20.0 mg/1 07/28/10 04:34 EPA200.7 rb Ll 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.0100 mg/1 07/28/10 04:34 EPA 200.7 rb 

The results in this r~port apply to the samples analyzed in accordance with the clrai11 of 

custody document. This a11alytical report must be reproduced ill its entirety. 

Page 2 of 9 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte Result 

Metals by EPA 200 Series Methods 

Selenium <0.0500 

Strontium 206 

Zinc 0.0773 

Metals (Dissolved) by EPA 200 Series Methods 

Iron, Dissolved 25.8 

Volatile Organic Compounds b~ EPA Method 8260B 

Benzene <5.00 

Toluene <5.00 

SurroJ!ate: 4-Bromofluorobenzene 99.3% 

SurroJ!ate: 1 ,2-Dichloroethane-d4 94.0% 

SurroJ!ate: F/uorobenzene 96.8% 

Conventional Chemistry Parameters by SMIEPA Methods 

Acidity -240 

Total Alkalinity 368 

Biochemical Oxygen Demand 44.8 

Chemical Oxygen Demand 925 

Specific Conductance (EC) 30600 

Total Hardness 4200 

Methylene Blue Active Substances 2.96 

Nitrate as N <25.0 

Fairway Laboratories, Inc. 

Project: KEYSTONE CLEARWATER~ 

Project Number: 

Collector: 

10241-3 

JK 

Number of Containers: 17 

Date!fime Sampled: 

OG20037-0l (Water) 

Laboratory 

Reporting Date /Time 

Limit Units Analyzed 

0.0500 mg/1 07/28/10 04:34 

0.200 mg/1 07/28/10 04:35 

0.0500 mg/1 07/28/10 04:34 

0.400 mg/1 08/04/10 12:29 

5.00 ug/1 07/28/10 02:08 

5.00 ug/1 07/28/10 02:08 

70-130 07/28/10 02:08 

70-130 07/28110 02:08 

70-130 07128/10 02:08 

-10000 mg/1 07/27/10 13:45 

10.0 mg/1 07/27110 12:00 

20.0 mg/1 07/22/10 07:51 

75.0 mg/1 07/23/10 12:29 

2.00 umhos/cm 07/23/10 12:07 

100 mg/1 07127/lO 22:34 

Reported: 

08/23/10 10:55 

07/20/10 10:30 

Method Analyst 

EPA200.7 rb 

EPA200.7 rb 

EPA200.7 rb 

EPA200.7 rb 

EPA8260B wm 

EPA8260B wm 

EPA 8260B WID 

EPA 8260B wm 

EPA 8260B wm 

SM2310B EB 

SM2320B EB 

SM5210B SP 

EPA410.4 bw 

SM 2510B bw 

SM2340C JG 

Note 

Ll 

1.00 mg/1 07/21/10 13:00 SM5540C EB L6,MS 

25.0 mg/1 07/21/10 15:26 EPA 300.0 BW 

17te results in this report apply to the samples analyzed in accordance with the chain of 

custody document. 17tis analytical report must be reproduced in its entirety. 

Page 3 of 9 
ARM Group 

2013 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte Result 

Conventional Chemistry Parameters by SMIEP A Methods 

Nitrite as N 

Total Nitrogen 

Nitrate/Nitrite as N 

Oil & Grease 

pH 

Phenolics 

Total Dissolved Solids 

Total Suspended Solids 

Total Kjeldahl Nitrogen 

Anions by EPA Method 300.0 

Bromide 

Chloride 

Sulfate as S04 

<5.00 

112 

<30.0 

24.2 

6.70 

0.0230 

20500 

80.0 

81.7 

80.1 

10500 

<25.0 

Physical Parameters by APHA/ASTMIEPA Methods 

Ammonia asN 

Gross Alpha- Radiological Suite 

Gross Beta - Radiological Suite 

Fairway Laboratories, Inc. 

50.1 

2200 

463 

Project: KEYSTONE CLEARWATER 1 

Project Number: 10241-3 

Collector: JK 

Number of Containers: 17 

Reported: 

08123/10 10:55 

Date!fime Sampled: 07/20/10 10:30 

OG20037-0l (Water) 

Laboratory 

Reporting 

Limit Units 

Date/Time 

Analyzed Method Analyst Note 

5.00 mg/1 07/21110 15:26 EPA 300.0 BW 

31.0 mg/l 08/03/10 10:26 SM4500Norg AD 

c 

30.0 mg/l 07/28/10 16:46 EPA 3.00.0 bw 

12.5 mg/l 07/21110 22:40 EPA 1664A IG Dl 

pH Units 07/20/10 17:45 SM4500H+B MC 

0.0100 mg/l 08/05/10 11:00 EPA420.1 JH Ll2 

20.0 mg/l 07/26/10 18:51 SM2540C RH 

8.00 mg/1 07/26/10 17:27 SM2540D RH 

1.00 mg/l 08/03/10 16:14 SM4500Norg JG 

c 

5.00 mg/l 07/21110 15:26 EPA300.0 BW 

1250 mg/1 07/23/10 22:03 EPA 300.0 BW 

25.0 mg/1 07/21110 15:26 EPA 300.0 BW 

5.00 mg/l 07/30110 01:26 ASTM JG 

06919-03 

318 pCi/L 08/02/10 00:00 EPA 900.0 sub SC2 

196 pCi!L 08/02/10 00:00 EPA 900.0 sub SC2 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This a11alytical report must be reproduced in its e11tirety. 

Page 4 of 9 
ARM Group 

20 13 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte Result 

Subcontracted Analyses 

Ethylene glycol <10.0 

Radium 226 205 

Radium228 <54.0 

Thorium <10.6 

Uranium <7.23 

Fairway Laboratories, Inc. 

Project: KEYSTONE CLEARWATER~ 

Project Number: 10241-3 

Collector: JK 

Number of Containers: 17 

Reported: 

08/23/10 10:55 

Dateffime Sampled: 07/20/10 10:30 

OG20037-0l (Water) 

Laboratory 

Reporting Date/Time 

Limit Units Analyzed Method Analyst 

10.0 mg/1 08/03/10 04:30 EPA8015M sub 

34.5 pCi/L 08/10/10 00:00 EPA903.0 sub 

54.0 pCi/L 08/04/10 00:00 EPA904.0 sub 

10.6 mg/1 08/11110 00:00 EPA200.8 sub 

7.23 pCi/L 08/11/10 00:00 SM 7500-U sub 

A-B 

The results in this report apply to the samples analyzed in accm·dance with the cl1ain of 

custody document. This analytical report must be reproduced in its emirety. 

Note 

SCI 

SC2 

SC2 

MS,SC2 

MS, SC2 

Page 5 of 9 
ARM Group Project: KEYSTONE CLEARWATER~ 

2013 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: Joe Kunst 

Notes 

Project Number: 10241-3 

Collector: JK 

Number of Containers: 17 

SC2 This analysis was subcontracted to BenchMark Analytical, ID# 09-00944. 

SCI This analysis was subconttacted to Analytical Laboratory Services, Inc, ID# 22-00293. 

MS The spike recovery was outside acceptance limits for the MS and/or MSD due to sample matrix interferences. The batch 

was accepted based on acceptable CCV recovery. 

L6 MBAS, calculated as LAS, mol wt 320 

Ll2 The prep method LCS spike recovery was outside acceptance limits. The batch results were accepted based on the 

acceptable recovery of the other associated QC. 

Ll This result was above the calibration range; therefore it is an estimated value. 

Dl The RPD result exceeded the QC control limits for the duplicate sample analyzed. 

Reported: 

08/23/10 10:55 

Fairway Laboratories, Inc. The res11lts in this report apply to the samples analyzed in accordance with the clrailr of 

c11stody doc11ment. This analytical report must be reproduced in its elllirety. 

Page 6 of9 
3} 

eact

e Su

de 

4} Reactive Cyanide 

5} Toxicity Characteristic Leaching Procedure (TCLP} - include all parameters found in 40 CFR 

261.24, as incorporated by reference at 25 Pa. Code 261a.1, as well as pH of extract. 

Report all results in mg/L or as otherwise specified in method. 

d. Wastewater Produced from the Drilling, Completion and Production of a Marcellus 

Shale or Other Shale Gas Well. In lieu of the Trace Analysis described in subsection b., the 

chemical analysis of wastewater produced from the drilling, completion and production of a 

Marcellus Shale or other shale gas well must include the following: 

Acidity Calcium Lead Selenium Alkalinity (Total as Chemical Oxygen Lithium Silver 

CaC03} Demand Magnesium Sodium 

Aluminum Chlorides Manganese Specific Conductance 

Ammonia Nitrogen Chromium MBAS (Surfactants} Strontium 

Arsenic Cobalt Mercury Sulfates 

Barium Copper Molybdenum Thorium 

Benzene Ethylene Glycol Nickel Toluene 

Beryllium Gross Alpha Nitrite-Nitrate Nitrogen Total Dissolved Solids Biochemical Oxygen Gross Beta Oil & Grease Total Kjeldahl Nitrogen 

Demand Hardness (Total as pH Total Suspended Solids 

Boron CaC03} Phenolics (Total} Uranium 

Bromide Iron- Dissolved Radium 226 Zinc 

Cadmium Iron- Total Radium 228 

Additional constituents that are expected or known to be present in the wastewater. 

*Note - All metals reported as total. 

For impoundments and tanks, the chemical analysis must represent the volume of wastewater 

stored in the impoundment or tank. A representative analysis is based upon the frequency, 

location and number of samples. Samples of an impoundment should be composite samples 

taken from various locations and wastewater depths as identified on a grid. If multiple loads of 

wastewater are removed from the same impoundment or tanks for transfer, processing, 

treatment or disposal, the same chemical analysis of the wastewater may be used repeatedly 

without further analysis, provided the analysis remains representative of the impoundment. If 

large volumes of water, wastewater or other fluids are added to the impoundment, a new 

chemical analysis must be performed that is representative of the impoundment. 

Page 3 of6 
the Slavek IH well pad. The sampling of flow back water at the site consisted of collecting grab 

samples of the material and placing the samples into laboratory provided glassware. A total of 

seventeen (17) representative samples were collected. Samples were collected by personnel 

wearing a clean pair of nitrile gloves for each sampling area to minimize sample cross 

contamination. 

The samples of the flow back water were submitted to Fairway Laboratories of Altoona, 

Pennsylvania for analysis of the appropriate Form 26R constituents. A complete list of analyses 

is attached. The analytical results for the samples are representative the quality of the fluids 

generated during well drilling activities at this well site. 
Flow Back 

Tanks 

Clearwater Treated Water 

Nanofiltration 1 Tanks 

Concentrate 

, 

Concentrate 

Tank 

, 

To Offsite Treatment Facility 

Process Description: A mobile filtration unit was utilized to filter flow back water from 

fracturing of natural gas wells. Filtered water was reused and "concentrate" from the filtering 

process was hauled off-site to a permitted brine water treatment facility. 
prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

2/28/11 

EPA Generator ID# 

c. Physical Appearance 

e. 

First Name Ned 

Ml 

E. 

ng use of generator knowledge in 

- 1 -

Phone Ext 

717-508-0550 

Suffix 

P.G. 

No 

N/A 
Solid waste perm 

301353 

b. Facility Name 

Address Line 1 Address Line 1 

Address City State ZIP 

Municipality 

c. Facility Contact 

Title 

Phone 412-977-5959 Address MBowser@advancedwasteservices.com 

waste shipped to processing or disposal facility in the previous year. 

28,200 0 cu yd 181 gal 0 lb 0 ton (check one) 

a. Solid waste 

b. Facility Name 

Address Line 1 Address Line 1 Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title 

d. 

a. 

b. 

Phone 

Volume of waste 

N/A 

r processing or disposal facility being utilized. 

County 

or disposal facility in the previous year. D gal 0 lb 0 ton (check one) 

0 ton (check one) 

-2-
G I· f;e{Uty frl~l.lon ~q~~d In SeQtlon S

t, General Pt'OP~~e was supplied to the Dapa

Q y

a

_

mrhaa ~ ~nged. -

form 6ubmltl8ct. ~ Form~ 

Q Other(SJ$0tM ------------

Date 8u

_

bmltt.d: ~ I ceri.t~J the mformatlpn required -In Section B·~. Chomfclll Analyal$ WiJS ayPP,tled to the Departmfritt for the year U 

aild~ .. ,~-

Form 8u~hllt ... 4: ~ Form~ 

0 OOI~rf~) 

Ba1e Sub~Jtt,ct. 

I ctirtiJy tl\c:t tnf~lion ~fred fn S~n 84, Process DescripOon and Schematic, was eupplfed· bfthe Department 

for the year B1! ~dt.aa not charigeCt. 

Form SUbm~ l8J ftoqA 26A 

0 0t~ (sP'-Ctfy) -------------

Date ~mtttect: 

N.a!lle of Responsl~e efficla.l 110e 
ARM Group 

2013 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: · Joe Kunst 

Project: KEYSTONE CLEARWATER! 

Project Number: l 0241-3 

Collector: JK 

Number of Containers: 17 

Reported: 

08/23/10 10:55 

ANALYTICAL REPORT FOR SAMPLES 

lsampleiD 

SLAVEK lH 

Test Uncert. 

Gross Alpha +/- 299.0 

Gross Beta 

Radium226 

Radium228 

+/- 80.19 

+/- 8.97 

+/- 25.95 

Fairway Laboratories, Inc. y_and Submitted by: 

Michael P. Tyler 

Laboratory Director 

Laboratory ID 

OG20037-01 

Matrix Date Sampled Date Received 

Water 07/20/10 10:30 07/20/10 12:40 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced in its entirety. 

Page 1 of9 
ARM Group 

20 13 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte Result 

Metals by EPA 200 Series Methods 

Silver <0.0200 

Aluminum <0.250 

Arsenic 0.0968 

Boron 4.87 

Barium 420 

Beryllium <0.00500 

Calcium 1160 

Cadmium <0.0100 

Cobalt 0.157 

Chromium 0.00782 

Copper <0.0500 

Iron 26.7 

Mercury <0.000200 

Lithium 11.6 

Magnesium 141 

Manganese 1.72 

Molybdenum <0.0500 

Sodium 5320 

Nickel 0.137 

Lead <0.0100 

Fairway Laboratories, Inc. 

Project: KEYSTONE CLEARWATER~ 

Project Number: 10241-3 Reported: 

Collector: JK 08/23/10 10:55 

Number of Containers: 17 

Dateffime Sampled: 07/20/10 10:30 

OG20037-0l (Water) 

Laboratory 

Reporting Date/Time 

Limit Units Analyzed Method Analyst Note 

0.0200 mg/1 07/28/10 04:34 EPA200.7 rb 

0.250 mg/1 07/28/10 04:33 EPA200.7 rb 

0.0200 mg/1 07/28/10 04:34 EPA200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA200.7 rb 

1.00 mg/1 07/28/10 04:34 EPA200.7 rb Ll 

0.00500 mg/1 07/28/10 04:34 EPA200.7 rb 

10.0 mg/1 07/28/10 04:38 EPA200.7 rb 

0.0100 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA200.7 rb 

0.00500 mg/1 07/28/10 04:34 EPA200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

2.00 mg/1 07/28/10 04:39 EPA200.7 rb Ll2 

0.000200 mg/1 08/12/10 08:10 EPA 245.1 cb 

5.00 mg/1 08/02/10 23:19 EPA200.7 sub SCI 

10.0 mg/1 07/28/10 04:38 EPA 200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

20.0 mg/1 07/28/10 04:34 EPA 200.7 rb Ll 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.0100 mg/1 07/28/10 04:34 EPA200.7 rb 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This analytical report must be reproduced in its entirety. 

Page 2 of9 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte Result 

Metals by EPA 200 Series Methods 

Selenium <0.0500 

Strontium 206 

Zinc 0.0773 

Metals (Dissolved) by EPA 200 Series Methods 

Iron, Dissolved 25.8 

Volatile Organic Coml!ounds b;r EPA Method 8260B 

Benzene <5.00 

Toluene <5.00 

Surrof!ate: 4-Bromofluorobenzene 99.3% 

Surrof!ate: 1,2-Dichloroethane-d4 94.0% 

Surrof!ate: Fluorobenzene 96.8% 

Conventional Chemist!:I Parameters b;y SMIEP A Methods 

Acidity -240 

Total Alkalinity 368 

Biochemical Oxygen Demand 44.8 

Chemical Oxygen Demand 925 

Specific Conductance (EC) 30600 

Total Hardness 4200 

Methylene Blue Active Substances 2.96 

Nitrate as N <25.0 

Fairway Laboratories, Inc. 

Project: KEYSTONE CLEARWATER~ 

Project Number: 10241-3 Reported: 

Collector: JK 08/23/10 10:55 

Number of Containers: 17 

Date/Time Sampled: 07/20/10 10:30 

OG20037-0l (Water) 

Laboratory 

Reporting Date /Time 

Limit Units Analyzed Method Analyst Note 

0.0500 mg/1 07/28/10 04:34 EPA200.7 rb 

0.200 mg/1 07/28/10 04:35 EPA200.7 rb Ll 

0.0500 mg/1 07/28/10 04:34 EPA 200.7 rb 

0.400 mg/1 08/04/10 12:29 EPA200.7 rb 

5.00 ug/1 07/28/10 02:08 EPA8260B wm 

5.00 ug/1 07/28/10 02:08 EPA8260B wm 

70-130 07/28110 02:08 EPA 8260B wm 

70-130 07128/10 02:08 EPA 8260B wm 

70-130 07128/10 02:08 EPA 8260B wm 

-10000 mg/1 07/27/10 13:45 SM2310B EB 

10.0 mg/1 07/27/10 12:00 SM2320B EB 

20.0 mg/1 07/22/10 07:51 SM5210B SP 

75.0 mg/1 07/23/10 12:29 EPA 410.4 bw 

2.00 umbos/em 07/23/10 12:07 SM2510B bw 

100 mg/1 07/27/10 22:34 SM2340C JG 

1.00 mg/1 07/21/10 13:00 SM5540C EB L6,MS 

25.0 mg/1 07/21/10 15:26 EPA 300.0 BW 

The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This al!alytical report must be reproduced in its entirety. 

Page 3 of9 
ARM Group 

2013 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte Result 

Conventional Chemistry Parameters by SMIEP A Methods 

Nitrite as N 

Total Nitrogen 

Nitrate/Nitrite as N 

OU & Grease 

pH 

Phenolics 

Total Dissolved Solids 

Total Suspended Solids 

Total Kjeldahl Nitrogen 

Anions by EPA Method 300.0 

Bromide 

Chloride 

Sulfate as S04 

<5.00 

112 

<30.0 

24.2 

6.70 

0.0230 

20500 

80.0 

81.7 

80.1 

10500 

<25.0 

Physical Parameters by APHA/ASTM/EPA Methods 

Ammonia asN 

Gross Alpha- Radiological Suite 

Gross Beta - Radiological Suite 

Fairway Laboratories, Inc. 

50.1 

2200 

463 

Project: KEYSTONE CLEARWATER 

Project Number: 10241-3 

Collector: JK 

Reported: 

08/23110 10:55 

Number of Containers: 17 

OG20037-01 (Water) 

Laboratory 

Reporting 

Limit 

5.00 

31.0 

30.0 

12.5 

0.0100 

20.0 

8.00 

1.00 

5.00 

1250 

25.0 

5.00 

318 

196 

Units 

mg/1 

mg/1 

mg/1 

mg/1 

pH Units 

mg/1 

mg/1 

mg/1 

mg/l 

mg/1 

mg/1 

mg/1 

mg/1 

pCiiL 

pCi/L 

Date/Time Sampled: 

Date /Time 

Analyzed 

07/21110 15:26 

08/03/10 10:26 

07/28/10 16:46 

07/21/10 22:40 

07/20/10 17:45 

08/05/ I 0 11 :00 

07/26/10 18:51 

07/26/10 17:27 

08/03/10 16:14 

07/21!10 15:26 

07/23/10 22:03 

07/21/10 15:26 

07/30/10 01:26 

08/02/10 00:00 

08/02/10 00:00 

07/20/10 10:30 

Method Analyst Note 

EPA 300.0 BW 

SM4500Norg AD 

c 

EPA300.0 bw 

EPA 1664A JG Dl 

SM4500H+B MC 

EPA420.1 m L12 

SM2540C RH 

SM2540D RH 

SM4500Norg JG 

c 

EPA300.0 BW 

EPA 300.0 BW 

EPA 300.0 BW 

ASTM JG 

D6919-03 

EPA 900.0 sub SC2 

EPA 900.0 sub SC2 

The results ill this report apply to the samples analyzed in accordance with the chain of 

custody document. This a11alytical report must be reproduced in its entirety. 

Page 4 of9 
ARM Group 

2013 Sandy Drive, Suite 205 

State College PA, 16803 

Project Manager: Joe Kunst 

Client Sample ID: SLAVEKlH 

Laboratory Sample ID: 

Analyte 

Subcontracted Analyses 

Ethylene glycol 

Radium226 

Radium 228 

Thorium 

Uranium 

Fairway Laboratories, Inc. 

Result 

<10.0 

205 

<54.0 

<10.6 

<7.23 

Project: KEYSTONE CLEARWATER~ 

ProjectNumber: 10241-3 

Collector: JK 

Number of Containers: 17 

Reported: 

08/23/10 10:55 

OG20037-01 (Water) 

Laboratory 

Reporting 

Limit 

10.0 

34.5 

54.p 

10.6 

7.23 

Units 

rng/1 

pCi/L 

pCi/L 

rng/1 

pCi/L 

Dateffime Sampled: 

Date/Time 

Analyzed 

08/03/10 04:30 

08/10/10 00:00 

08/04/10 00:00 

08/11/10 00:00 

08/11/10 00:00 

07/20/1 0 1 0:30 

Method Analyst Note 

EPA8015M sub SCl 

EPA 903.0 sub SC2 

EPA 904.0 sub SC2 

EPA 200.8 sub MS,SC2 

SM 7500-U sub MS,SC2 

A-B 

The results in chis report apply Co the samples analyzed in accordance with rhe chain of 

custody document. This ana lyrical report muse be reproduced in its elllirety. 

Page 5 of9 
ARM Group Project: KEYSTONE CLEARWATER 

2013 Sandy Drive, Suite 205 

State College P A, 16803 

Project Manager: Joe Kunst 

Notes 

Project Number: 10241-3 

Collector: JK 

Number of Containers: 17 

SC2 This analysis was subcontracted to BenchMark Analytical, ID# 09-00944. 

SCI This analysis was subcontracted to Analytical Laboratory Services, Inc, ID# 22-00293. 

MS The spike recovery was outside acceptance limits for the MS and/or MSD due to sample matrix interferences. The batch 

was accepted based on acceptable CCV recovery. 

L6 MBAS, calculated as LAS, mol wt 320 

L 12 The prep method LCS spike recovery was outside acceptance limits. The batch results were accepted based on the 

acceptable recovery of the other associated QC. 

Ll This result was above the calibration range; therefore it is an estimated value. 

Dl The RPD result exceeded the QC control limits for the duplicate sample analyzed. 

Reported: 

08/23/10 10:55 

Fairway Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of 

custody document. This aJJalytica/ report must be reproduced ill its entirety. 

Page 6 of9 
3} Reactive Sulfide 

4} Reactive Cyanide 

5} Toxicity Characteristic Leaching Procedure (TCLP) - include all parameters found in 40 CFR 

261.24, as incorporated by reference at 25 Pa. Code 261 a.1, as well as pH of extract. 

Report all results in mg/L or as otherwise specified in method. 

d. Wastewater Produced from the Drilling, Completion and Production of a Marcellus 

Shale or Other Shale Gas Well. In lieu of the Trace Analysis described in subsection b., the 

chemical analysis of wastewater produced from the drilling, completion and production of a 

Marcellus Shale or other shale gas well must include the following: 

Acidity Calcium Lead Selenium 

Alkalinity (Total as Chemical Oxygen Lithium Silver 

CaC03) Demand Magnesium Sodium 

Aluminum Chlorides Manganese Specific Conductance 

Ammonia Nitrogen Chromium MBAS (Surfactants) Strontium 

Arsenic Cobalt Mercury Sulfates 

Barium Copper Molybdenum Thorium 

Benzene Ethylene Glycol Nickel Toluene 

Beryllium Gross Alpha Nitrite-Nitrate Nitrogen Total Dissolved Solids 

Biochemical Oxygen Gross Beta Oil & Grease Total Kjeldahl Nitrogen Demand Hardness (Total as pH Total Suspended Solids Boron CaC03) Phenolics (Total) Uranium 

Bromide Iron - Dissolved Radium 226 Zinc 

Cadmium Iron- Total Radium 228 

Additional constituents that are expected or known to be present in the wastewater. 

*Note - All metals reported as total. 

For impoundments and tanks, the chemical analysis must represent the volume of wastewater 

stored in the impoundment or tank. A representative analysis is based upon the frequency, 

location and number of samples. Samples of an impoundment should be composite samples 

taken from various locations and wastewater depths as identified on a grid. If multiple loads of 

wastewater are removed from the same impoundment or tanks for transfer, processing, 

treatment or disposal, the same chemical analysis of the wastewater may be used repeatedly 

without further analysis, provided the analysis remains representative of the impoundment. If 

large volumes of water, wastewater or other fluids are added to the impoundment, a new 

chemical analysis must be performed that is representative of the impoundment. 

Page 3 of6 
the Slavek 2H well pad. The sampling of flow back water at the site consisted of collecting grab 

samples of the material and placing the samples into laboratory provided glassware. A total of 

seventeen (17) representative samples were collected. Samples were collected by personnel 

wearing a clean pair of nitrile gloves for each sampling area to minimize sample cross 

contamination. 

The samples of the flow back water were submitted to Fairway Laboratories of Altoona, 

Pennsylvania for analysis of the appropriate Form 26R constituents. A complete list of analyses 

is attached. The analytical results for the samples are representative the quality of the fluids 

generated during well drilling activities at this well site. 
Flow Back 

Tanks 

Clearwater Treated Water 

N anofiltration Tanks 

Concentrate 

Concentrate 

Tank 

To Offsite Treatment .Facility 

Process Description: A mobile filtration unit was utilized to filter flow back water from 

fracturing of natural gas wells. Filtered water was reused and "concentrate" from the filtering 

process was hauled off-site to a permitted brine water treatment facility.