AP-42 Section If•

- 7 Referenoe R rt Sect /~ 

## Envisage Environmental Incorporated P.O. Box 152, Richfield, Ohio 44286 Phone (216) 526-0990 ~ epo . REPORT NO. 9471 • Reference COMPANY M-E-

't] TITLE CoIhF.------- DATE 3-30 & 4-14- 94 

# A-99-30 7I- { -00'7

METROPOLITAN CERAMICS INC. CANTON, OHIO TK1, TK2, TK3 EXHAUSTS PARTICULATE, SULFUR DIOXIDES, & FLUORIDES

EMISSION EVALUATION CONDUCTED - MARCH 30 & APRIL 14, 1994

# SOURCE

EVALUATION RESULTS

PREPARED BY 

# Envisage Environmental 1 ncorporated P.O. Box 152 Richfield, Ohio 44286 Phone (216) 526-0990



# IN

## Envisage Environmental Incorporated P one (216)2526-0990 Ohio 44286



### May 9, 1994 Mr.Phillip McGuiness Metropolitan Ceramics Inc. 1201 Millerton Road Canton, Ohio 44707
Dear Mr. McGuiness: The following report is the result of the fluorides, sulphur dioxide, and 

### particulate emission evaluation conducted March 30, and April 14, 1994 at the above facility. Three test runs each of the above was conducted at the TK1, TK2, and TK3 common exhaust for regulatory purposes. The results are true and accurate to the degree specified in the pertinent sections of the Code of Federal Regulations 

### , in force at the time of the tests. 

### I look forward to answering any questions you may have and assisting you in the future. Respectfully submitted,

, 

# 4'

~ 

# ' Robert C. Hovan Air Quality Supervisor ENVISAGE ENVIRONMENTAL INC.

P.O. Box 152 Richfield, Ohio 44286 Phone (216) 526-0990 Fax (216) 526-8555 

# ~

### INTRODUCTION



## On March 30, 1994, Envisage Environmental Inc. conducted a particulate and fluoride emission evaluation and on April 14, 1994, continued the testing for Ifur dioxide emissions at the Metropolitan Ceramic Inc. facility, Canton, Ohio. Three (3) test runs for particulate, fluorides and sulfur ioxi e emissions were performed at the common exhaust serving the TK1, TK2, and TK3. Test parameters were in accordance with USEPA Reference Methods 1- 5, 6, and 13. 

## The kiln operations were monitored by Metropolitan Ceramic Inc. personnel throughout the duration of the testing program(s). The purpose of this evaluation was to determine the particulate, fluoride and sulfur dioxide emission rates from the above exhaust to determine compliance with OEPA regulations 

## . The Envisage test teams consisted of Messrs. Greg Sinkovich, Terry Campbell, David Donelson and Jeff Belino on March 30, 1994 and Messrs. Robert Hovan, Terry Campbell, and Clint Holley on April 14, 1994. The Canton Department of Air Pollution Control was represented by Mr. Rick Miller on both dates. Mr. Phillip McGuiness, Metropolitan Ceramic Inc., coordinated the tests. Results are presented in this report for particulate, fluorides and sulfur dioxide emissions as pounds/hour and the various velocity, volumetric, and temperature measurements associated with these tests. 3

_ Envisage

Environmental


## - Incorporated

- P.O. 8ox 152 Hlohlield, OhiO 44266 Phone (216) 526-0990

### 5 DESCRIPTION OF PROGRAM



# ~ jhe emission test consisted of three (3) test runs at the common exhaust 

### serving the TK1, TK2, TK3 for particulate, fluoride, and sulfur dioxide. Two 5~ 

### p1" I sampling ports with twelve (12) sample points in each of the ports were utilized OCCLY for testing on March 30, and four (4) ports with six sample points were utilized



### for testing on April 14,1994. Sample time per point was two and one-half (2.5)



# ~ minutes for the isokinetic sample . The total time per test run was sixty (60) 

## minutes. ._-- The particulate and fluoride samples were taken from the gas stream isokinetically through a five (5) foot pyrex lined probe and a guarter .25) inch nozzle. The entire length of the probe was heated and attached to a standard EPA Method 5 sample train. The hot box temperature was maintained between i225 and 273 degrees Fahrenhei Exit gas te mperature of the r— 

### 1 impingers was maintained below 68 degrees Fahrenheit.with an ice bat The nozzle, probe and connecting glassware was cleaned before testing and at the conclusion of each test run with acetone. After the particulate analysis was completed, the filters and impinger solutions were sent to a laboratory for the fluoride evaluation. Leak checks of the pitot tube lines and the sample trains were all acceptable by EPA regulations. .~ 

### .._— 

### The method 6 evaluation was conducted on the second date, due to a problem with accuracy on the audit evaluation on the first test date. The method 6 sample train utilized the following reagents; 100m1 of 80% IPA, 

### 100m1 of 3%H O

~ 

### , 100m1 of 3% H 2 O„ and 200 grams of Silica Gel. Sampling was conducted at one sample point, with volumetric determinations

~ 

### .. 

### conducted before and after each test run. The average of these readings was utilized for the emission calculations. The analysis of the impinger solution was conducted by Barium-Thorin titration. An OEPA audit sample was analyzed prior to the test samples to assure quality control.

~ 

### Envisage Environmental — Incorporated

- P.O. Box 152 Rithtieltl, OhlO 44266 PhOne (216) 526-0990

### Description cont.



### Flue gas analysis was conducted by drawing an integrated air_bag sample and analyzing it on a Hays Republic Model 621A "Orsat" Portabfe Gas Anayzer. The average of these readings for each run were used in calculating the emission rates. Calibration of the equipment used, including the dry gas meters, temperature measuring devices, orifice meters, and the "S" type p

~ 

### ito,t tubes were conducted within 60 days of the test date. Copies of the data are included in this report. AII analytical procedures were performed in accordance with the methods specified in the Code of Federal Regulations, Title 40, Part 60, Volume 43. 

### Blanks were collected and analyzed in the evaluation. The acetone blank was recorded and incorporated into the results. The example equations included in this report use the figures from Run # 1 on both dates. 

### R

® Envisage

Envlronmental - Incorporated

- P.O. Box 152 Richfielo. Ohio 44286 Phone (216) 526-0990

# TEST RESULTS SUMMARY



# _ Envisage Envlronmental 

# -

Incorporated

- P.O. Boz 152 Richiield, Ohio 44286 Phone (216) 526-0990 

### /vTEST RESULTS SUMMARY : Metropolitan Ceramics Inc. Canton, Ohio Particulate & Fluorides Emission Evaluation

TK1, TK2, & TK3 Exhaust Conducted - March 30, 1994
PARAMETER articulate Emissions Pounds/hour Grains/dscf Fluorides Emissions

~ Pounds/hour Grains/dscf System Flow Rates

~ ACFM

~ DSCFM Degrees Fahrenheit Moisture Content 

# rU' ~ 

# `

. 

# ' ( `x t _ 0 5 °

ld RUN#1 RUN#2 RUN#3

9.12 12.32 8.19 9-$ E 0.0298 0.0316 0.0249 •t , ? 7.
2.63 2.34 2.78 ~ 5 8.60E-03 7.12E-03 8.43E-03
53,215 56,750 56,701 35,697 38,284 38,412 273 274 271 3.79 3.20 3.0

- Envisage

Environmental - Incorporated

- P.O. BOa 152 fiiohflelC. Ohio 44266 Phone (216) 526-0990

## %~11 TEST RESULTS Metropolitan Ceramics Inc. TK1, TK2, & TK3 Exhaust Particulate & Fluorides Emission Evaluation DATE: March 30, 1994 Symbol Units RUN # 1 RUN # 2 Time of Day 1135 1322 1240 1425 1 Gas Volume-dry,std. Vmstd cu. ft. 39.64 41.63 2 Condensate Vapor Vol. Vwstd cu. ft. 1.56 1.37 3 Gas Stream Moisture Bws vol.dec 0.0379 0.0320 4 Mo1.Wt-flue gas (dry) Msd lb/lb mo. 28.96 28.96 5 Mol.Wt-flue gas (wet) Ms lb/lb mo. 28.54 28.61 6 Flue Gas Velocity Vs ft/sec 45.17 48.17 7 Flue Gas Volume-Actual ACFM cu. ft. 53,215 56,750 8 Flue Gas Volume-Std. DSCFM cu. ft.. 35,697 38,284 RUN # 3 1506 1612 41.73 1.33 0.0309 28.82 28.49 48.13 56,701 38,412 9 Particulate Conc. Cs - Probe - Filter - Total - Fluorides 10 Emission Rate E - Probe - Filter - Total - Fluorides 

# ~ 11 Isokinetic Rate I gr/dscf 0.0081 0.0186 0.0059 gr/dscf 0.0217 0.0189 0.0190 gr/dscf 0.0298 0.0376 0.0249 gr/dscf 0.0086 0.0071 0.0084
lb/hr 2.48 6.12 1:94 lb/hr 6.65 6.20 6.26 lb/hr 9.12 12.32 8.19 lb/hr 2.63 2.34 2.78 % 106.6 104.4 104.3

S Envisage

Environmental - Incorporated

- P.O. 9ox 152 Riahfieltl. OhiO 44266

Phone (216) 526-0990TEST RESULTS Metropolitan Ceramics Inc. TK1, TK2, & TK3 Exhaust Sulfur Dioxide Emission Evaluation DATE: April 14, 1994 Symbol Units RUN # 1 Time of Day 0955 1055 1 Gas Volume-dry,std. Vmstd cu. ft. 43.47 2 Condensate Vapor Vol. Vwstd cu. ft. 1.69

° ~~ 3 Gas Stream Moisture Bws vol.dec 0.0375 4 Mol.Wt-flue gas (dry) Msd lb/lb mo. 28.91 5 Mol.Wt-flue gas (wet) Ms lb/lb mo. 28.50



### ~ 6 Flue Gas Velocity Vs ft/sec 48.71



### ~ 7 Flue Gas Volume-Actual ACFM cu. ft. 57,385



### ~ 8 Flue Gas Volume-Std. DSCFM cu. ft. '38,370 9 Normality of Ba(C104)2 N meq/ml 0.0110 10 Volume of solution Vsln ml 240.0 11 Volume aliquot titrant Va ml 1.00 12 Volume Ba(C104)2 Blank Vtb ml 0.0 13 Volume Ba(C104)2 Sampl Vt ml 3.97 14 Concentration S02 Cso2 lb/scf 1.70E-05 1 15 Concentration S02 PPM ppmV 102.4 L 16 Emission Rate S02 Eso2 lb/hr 39.20 12

RUN # 2 RUN # 3 1122 1244 1222 1344 43.17 43.31 1.56 1.63 0.0349 0.0363 28.90 28.91 28.52 28.51 49.53 49.87 58,347 58,754 38,659 38,827 0.0110 0.0110 240.0 231.0 1.00 1.00 0.0 0.0 4.00 4.08 .73E-05 1.69E-05 103.9 101.8 40.06 39.41

_ Envisage

Environmental - Incorporated

- P.O. Box 152 Rtohlielo, Ohio 44286 Phone (216) 526-0990'

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# OPERATIONAL PARANlETERS 13

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# ~ SAMPLE POINT LOCATIONS 

### 17 

## Metropolitan Ceramics Incorporated

Canton, Ohio TK1, TK2, and TK3 Common Exhaust 

## Inside Diameter: * 60 inches 

# * * * *
1 * 2 * 1 1* 2 4 6 8 10 12
* * * * * * 

## Point # ------- 

## D 

## lnsiae e WaTQ m

------------- 

## Point # ------- 

## D 

## insaee e Wa ~ 

## Q m

------------- 1 58.1 inches 7 21.4 inches 2 56.0 inches 8 15.0 inches 3 52.9 inches 9 10.6 inches 4 49.4 inches 10 7.1 inches 5 45.0 inches 11 4.0 inches 6 38.6 inches 12 1.3 inches



# _ Envisage Environmental - Incorporated

- P.O. Box 152 RIOh11elA, Ohio 44266 Phone (216) 526-0990



### ~~

# EPA h1ETHOD 5 PARTICIJLATE SAMPLE TRAIN

TEMPERATUAE SEiVSOA
THEAMOMETER



# ~ PITOT TUB 

### THEAMOMETEA

E '- ' HEATED AAEA I C-

~ ECK FILTER HOLOEA 1 STACK r ----- ----- -, 

### ll VALVE TEMPERATURE wALL SE N50 R PA08E ~ •~ v -S1 L1CA GF L AEvERsF TYPE P1TOT TUBE ~ L-- -- , -J VACUUM LtNE PiTOT MANOMETEA THERMOMETEAS IMPINGFAS lCE BATH

- 8Y•PASS VALVE OEi1FiCE MAIN 

### VALVE

ORY GAS METEA AIA•TTGHT PUMP 

### 19



# Me

### 20



## J


# EPA METHOD 6

SAMPLE - TRAIN

TH ERMOMETER STACK WALL MIDGET tMPINGERS ~ PR08E (ENO PACXED Stl1CA GEL WITH QUARTZ OR MIDG' cT BUBBLER P1fREx WOOL) GLA55 WOOL DRYING TuBE

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## ~ PUMP

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## SURGETANK

M22 LABORATORY SUMMARY SHEET Metropolitan Ceramics Inc. TK1, TK2, & TK3 Exhaust Particulate & Fluorides Emission Evaluation DATE: March 30, 1994 Symbol Units RUN # 1 RUN # 2 1 Sampling Time t minutes 60.0 60.0 2 Barometric Pressure Pb in. Hg 29.02 29.02 3 Static Pressure Pg in. H20 -0.71 -0.71 Stack Pressure Ps in. Hg 28.97 28.97 4 Gas Meter Volume Vm cu. ft. 43.73 45.15 5 Stack Area A sq. ft. 19.63 19.63 6 Nozzle Diameter Dn dec. in. 0.25 0.25 7 "Y" Factor 1.00 1.00 8 Meter Temperature degrees F 107.1 97.8 Tm degrees R 567.1 557.8 9 Stack Temperature degrees F 273.2 273.5 10 Velocity Head 11 Orifice Pressure



### ~ 12 Carbon dioxide



### ~ 13 Oxygen . 14 Carbon monoxide 15 Nitrogen 16 Pitot Coefficien 17 Water Collected 18 Sample Weight: - Probe - Filter - Fluorides Ts degrees R 733.2 733.5 ^P in. H20 0.668 0.713 ^H' in. H20 1.50 1.67 CO2 % 1.0 1.0 02 % 20.0 20.0 CO % 0.0 0.0 N2 % 79.0 79.0 t Cp 0.84 0.84

Vlc ml 33.2 29.2 Mn RUN#3 60.0 29.02 -0.71 28.97 45.12 19.63 0.25 1.00 96.0 556.0 271.3 731.3 0.712 1.67 0.4 19.0 0.0 80.6 0.84 28.3
g 0.0208 0.0503 0.0159 g 0.0558 0.0510 0.0514 mg 22.1 19.2 22.8



## ~ Envisage

Environmental - Incorporated

- P.O. Box 152 RlGhlield, OhiO 44286 PhOnB (216) 526-0990LABORATORY SUMMARY SHEET 23 Metropolitan Ceramics Inc. TK1, TK2, & TK3 Exhaust Sulfur Dioxide Emission Evaluation DATE: April 14, 1994 Symbol Units RUN # 1 RUN # 2 RUN # 3 1 Sampling Time t minutes 60.0 60.0 60.0 2 Barometric Pressure Pb in. Hg 29.02 29.02 29.02 3 Static Pressure Pg in. H20 -0.55 -0.55 -0.55 Stack Pressure Ps in. Hg 28.98 28.98 28.98 4 Gas Meter Volume Vm cu. ft.. 46.25 46.46 46.75 5 Stack Area A sq. ft. 19.63 19.63 19.63 6 Meter Temperature degrees F 87.4 93.5 95.3 Tm degrees R 547.4 553.5 555.3 7 Stack Temperature degrees F 276.1 284.9 285.7 Ts degrees R 736.1 744.9 745.7 8 Velocity Head ^P in. H20 0.719 0.727 0.731 9 Orifice Pressure ^H in. H20 1.80 1.80 1.80 '- , .,10 Carbon dioxide CO2 % 1.0 1.0 1.0

~ 11 Oxygen 02 % 18.8 18.7 18.7 12 Carbon monoxide CO % 0.0 0.0 0.0 13 Nitrogen N2 % 80.2 80.3 80.3 14 Pitot Coefficient Cp 0.84 0.84 0.84 15 Water Collected Vlc ml 36.0 33.2 34.7

_ Envisage

Environmental - Incorporated

- P.O. f3ox 152 Rlchflel0. Ohlo 44266

Phone (216) 526-0990

### PLANT Metropolitan Ceramic DATE March 30, 1994 

### RUN N0. 1 CASE N0. 16 24

CONTAINER NUMBER
248
N/A


### 611 WEIGHT OF PARTICULATE COLLECTED

FINAL WEIGHT TARE WEIGHT WEIGHT GAIN 

### 0.6649 0.6091 0.0558 FILTER
N/A N/A N/A IMPINGERS

~ 

### 105.6688 105.6480 0.0208 PROBE

Corrected for Acetone Blank



### VOLUME OF LIQUID WATER COLLECTED IMPINGER SILICA GEL 

### VOLUME WEIGHT (ml) (9) FINAL 225 238.5 INITIAL 200 230.3 

### NET LIQUID COLLECTED 25 8.2 TOTAL NET VOLUME 33.2 g ml * Convert weight of water to volume by dividing weight increase by density of water: 

### _ Incr _ease g_ = Vol ume Water, ml _ Envisage Environmental
- Incorporated

- P.O. BO: 152 Rlthlleltl. Ohio 44266 Phone (216) 526-0990

### PLANT Metropolitan Ceramic DATE March 30, 1994 RUN N0. 2 CASE N0. 38 

### 25

CONTAINER NUMBER
254
N/A
99 WEIGHT OF PARTICULATE COLLECTED



### FINAL WEIGHT TARE WEIGHT WEIGHT GAIN 0.6590 0.6080 0.0510 FILTER
N/A N/A N/A IMPINGERS

A 

### 94.2642 94.2139 0.0503 PROBE



### Corrected for Acetone Blank



## VOLUME OF LIQUID WATER COLLECTED

IMPINGER SILICA GEL VOLUME WEIGHT (ml) (g) FINAL 220 239.5 

### INITIAL 200 230.3 NET LIQUID COLLECTED 20 9.2 TOTAL NET VOLUME 29.2 g ml * Convert weight of water to volume by dividing 

### weight increase by density of water: _Incr _ease g_
_ Uolume Water, ml - Envisa e Enviro 

### n mental 

### (1 g%ml ) 

## ~ Inoorporated 

# _ P.O. Box 152 RlchlielG, Ohlo 44286

Phone(218)526-0990

### PLANT Metropolitan Ceramic 

### 901 DATE March 30, 1994 

### RUN N0. 3 CASE N0. 29
CONTAINER NUMBER
246
N/A
71 WEIGHT OF PARTICULAT

FINAL WEIGHT TARE WEIGHT 

### 0.6628 0.6114
N/A N/A


### 101.9547 101.9388 : COLLECTED WEIGHT GAIN 

### 0.0514 FILTER

~ 

### N/A IMPINGERS

~ 

### 0.0159 PROBE
* Corrected for Acetone Blank



### VOLUME OF LIQUID WATER COLLECTED IMPINGER SILICA GEL 

### VOLUME WEIGHT 

### (ml) (9) FINAL 220 238.6 INITIAL 200 230.3 

### NET LIQUID COLLECTED 20 8.3 TOTAL NET VOLUME 28.3 g ml * Convert weight of water to volume by diViding weight increase by density of water: 

### _ Incr _ease g = Vol ume Water, ml 

## ~ Envlsage (1 g%ml j Environmental
- Incorporated

- P.O. f3ox 152 Rlohfield. OhiO 44286

PhOne(216)526-0990 

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## ~ PG IM,Q 1irwNL d..AIn.

~..~.~Work Order # 94-04-102 Ross Analytical services, Inc Reported: 04/25/94 

### 29 Sample Descsiptions Filter 0246 Lab No.: 01
Analvte Descrintion Result Units E ~ L Fluoride anal. by EPA 13B <EQL Total mg 1.5
samvle Descrivtion: Filter 1248 Lab No.: 02 Analvte Description Result IInits EQ_L Fluoride anal. by EPA 13B <EQL Total mg 1.5
samvle Descriotion: Filter #254 Lab No.: 03
Analvte Descrintion Result IInits ZOL Fluoride anal. by EPA 13B <EQL Total mg 1.5
samnle Descrivtion: Impinger Run# 1 Lab No.: 04 Analvte Description Result IInits ROL Sample volume 225 Total mL 5 Fluoride anal. by EPA 13B 22.1 Total mg 1.5
samale Descrintion: Impinger Run# 2 Lab No.: 05 Analvte Description Result IInits EL Sample volume 220 Total mL 5 Fluoride anal. by EPA 13B 19.2 Total mq 1.5
Samvle Descriotion: Impinger Run# 3 Lab No.: 06
Analvte Descrivtion Result IIaits ZOL Sample volume 220 Total mL 5 Fluoride anal. by EPA 13B 22.8 Total mg 1.5



## ~~

# CANTON CITY HEALTH DEPARTMENT

DYVISION OF AIR POLLUTION CONTROL 420 MARKET AVENUE NORTH
~ 

### 31 

# CANTON, OHIO 44702 FAX: (216) 489-3335 

# 1TELEFAX TRAIVSMII?'AL

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FOR THE ATTEZN3TION OF: r /R .4 ,AIK 

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This transmission consists of pages including this page. Please notify us if you do not receive all the pa;es at (216} 489-3385. 

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### AUDIT SAMPLE # 8823 - --------------- ------- 32 Sulfur dioxide Concentration ------------------------------ 

# c ( V t - V tb ) N I_ -Vs a n-
--------- 

# _I S0 2 = K 2 ---------------------- - -- 

## V m(given) Nomenclature: (EPA Equation 6-2) 

### C S0 2 = Concentration of sulfur dioxide in Audit sample, mg/dscm. 

### K 2 = Constant, 32.03 mg/meq. V t = Volume of barium perchlorate titrant used for the sample,

ml (average of replicate titrations). V tb = Volume of barium perchlorate titrant used for the blank, ml. N = Normality of barium perchlorate titrant, milliequivalents/ml. 

## V sln = Volume of solution containing sulfur dioxide sample, ml. V a = Volume of aliquot titrated, ml. V m(given) = Volume of gas sample (given with.each audit.sample), dscm. Where: 

### V t = 2.03 ml V sln = 100.0 ml V tb = 0.00 ml V a = 5.0 ml N = 0.0111 meq/ml V - m(given) 0.0210 M 3

_ - ( --?- 03 ----------O-oo--)----- 0 

## ~ 0111 -----I--_ 100 . 0 --I- C SO 32.03 5.0 2 0.0210
= 688.5 mg/dscm

- Envisage Environmental - Incorporated 

# _ P.O. 8ox 152 Riohlieltl. Ohio 44286 Phone (216) 526-0990

/AUDIT SAMPLE # 8947 

### - --------------- ------- 33 Sulfur dioxide Concentration ------------------------------ C 

### ( V t - V tb ) N — -Vsln

- ~ 

### a-- _I S0 2 = K 2 ----- - - ---------------=-------- --- - 

### V m(given) Nomenclature: (EPA Equation 6-2) 

## C S0 2 = Concentration of sulfur dioxide in Audit sample, mg/dscm. 

### K 2 = Constant, 32.03 mg/meq. V t = Volume of barium perchlorate titrant used for the sample,

ml (average of replicate titrations). V tb = Volume of barium perchlorate titrant used for the blank, ml. N = Normality of barium perchlorate titrant, milliequivalents/ml. 

### V sln = Volume of solution containing sulfur dioxide sample, ml. V a = Volume of aliquot titrated, ml. V m(given) = Volume of gas sample (given with each audit.sample), dscm. Where: 

### V t = 4.93 ml V sln = 100.0 ml V tb = 0.00 ml V a = 5.0 ml N = 0.0111 meq/ml Vm(given) 0.0210 M 3 ( 4.93 - 0.00 ) 0.0111 ---5 . 0 _I C S0 = 32.03
----------------------- 0.0210 ------------ 2 

### -_-----------

= 1667.6 mg/dscm

— Envisage Environmental — Inoorporated

- P.O. Box 152 filohfleld. Ohio 44266 Phone (216) 526-0990Equ pment and Specifications

Test Reference Methods Control Unit (meter box) Envisage Environmental Inc. XAndersen Samplers _ Remanufactured RAC _DuPont Constant Flow Pumps Sample Box X EEI _ Remanufactured RAC _EEISpecial Design Impingers - per sample train (each set changed for each test run) X EEI X EEI 

### 35 Equipment Designation Control Unit #'s MB 08 & 09 Control Unit #'s MB 01 - 02 Control Unit #'s MB 03 - 07 Control Unit #'s MB Ol - 05

SB Ol, 02 & 05 - 07 SB 03 & 04 SBO8-11
3 Modified Smith Greenburg type 1 Smith Greenburo type Probes length lining type _EEI 2 foot SS, PYREX, QUARTZ _EEI 3 foot SS, PYREX, QUARTZ XEEI 5 foot SS, PYREX , QUARTZ _fiEI 7 foot SS, PYREX, QUARTZ _EEI 10 foot SS, PYREX, QUARTZ _EEI 12 foot SS, PYREX, QUARTZ _EEI 15 foot SS, PYREX, QUARTZ _EEI 24 foot SS, PYREX, QUARTZ Temperature Sensors Equipment Designation _Omega Engineering PY 01 & 02 _Thermo Electric PY 03 - 08 X Fluke 51 PY Ol - 05 _Fisher Scientific Mercury in Glass Fisher Scientific Bimetallic Pressure Gauges Type Oil, 0- 10 in. water Magnetic/Mechnical 0- 1 in. water Magnetic/Mechnical 0- 10 in. water Mercury, 36 inches Water, 72 inches Water, 0- 10 inches of water Electric, .001 - .100 in. water

Deionized/Distilled Reagent Grade (<0.001% residual) 6 - 16 Mesh Acetone insoluble & heat resistant Reagent Grade Reagent Grade Reagent Grade Reagent Grade Reagent Giade



## ~ Envisage

Environmental - Incorporated

- P.O. Box 152 Richlield, Ohio 44286 Phone (216) 526-0990 X Dwyer Incline Manometer _ Dwyer Magnehelic _ Dwyer MagneheHc _Dwyer "U"Tube Manometer _ Dwyer "U"Tube Manometer _ Dwyer Microtector (micro-tnanometer) Davis Electromanometer Chemicals and Reagents X Water X Acetone 

# • Silica Gel • Stopcock Grease _ Nitric Acid _.1 N Sulfuric Acid _ Methylene Chloride _5% HNO3/ 10% H2O2 _Sodium Hydroxide _IQ1iIN04/Sodium Hydroxide

# FIELD DATA SNEETS 

# 36

_ Envisage

Environmental 

# - Incorporated

- PA. BOx 152 R1cMleltl, Ohio 44286 Phone (216) 526-0990t ~ ..Y
.. 

### FIELD DATA COVER SHEET 

### PLANT ~ C oR 4MrC S PROBE LENGTH , 

### ~ / 37 DATE yv,,.,t. ° 1 y NOZZLE I.D. J ,' SAMPLING LOCATION ASSUMED MOISTURE z "? d M ETER BOX I. D. I(1 

### ~ SAMPLING METHOD j 

### ~~ METER OH I-3 0 OPERATOR J: e-

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### ~'(~ NOMOGRAPH "C" FACTOR f, 

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### BAROMETRIC PRESSURE 1 ' 5t - 0 -2--- PROBE I.D. kL

STATIC PRESSURE 71 THERMOCOUPLE I.D.'s -- HEATER BOX SETTING ' Zltq± ZS PITOT COR. FACTOR PROBE TEMP SETTING ZO±2.5 SAMPLE TRAIN I.D. I TRAVERSE POINT LOCATIONS CYCLONIC FLOW CHECK 

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### DOWNSTREAM DISTANCE 3.q.5 9. S'ti,Z 4.! ?- , l 10. b3-i 5.15 11. (o?-
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### -

i 6. 12. TO•S NOZZLE CALIBRATION 

### Diameter 1 

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## PLANT t 

# ir

- v ~.~r~cs

- 

### DATE 

# q' I Y-4 `I SAMPLING LOCATION -

SAMPLING METHOD 

### ~ OPERATOR 4' AMBIENT TEMPERATURE BAROMETRIC PRESSURE STATIC PRESSURE -- SS HEATER BOX SETTING NIA' PROBE TEMP SETTING V/* 

### TRAVERSE POINT LOCATIONS 1. ~5 7. *0 3% •~ 2. q• 0 8. of 45:0 3. 1W 9. ift. L 4. (04 10.** 5~ 1 5.15. 0 11.*or Sv 6. ?$ 4 12. frtgr M? PROBE LENGTH 41 NOZZLE I.D. 

# N14- ASSUMED MOISTURE METER BOX I.D. N 

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### ~

li NOMOGRAPH "C" FACTOR zv/4 - PROBE i.D. ..



### ~ 

### 0 I

_ THERMOCOUPLE I.D.'s s PITOT COR. FACTOR • $`f SAMPLE TRAIN I.D.A/ CYCLONIC FLOW CHECK 

### UPSTREAM DISTANCE DOWNSTREAM DISTANCE

NOZZLE CALIBRATION Diameter 1 A Diameter 2 Diameter 3 

## Average Test Team Members 

# G

~ 

# '

f" rC fl

.. . _ 11 _ " I EPA Representative/ 

## Facility Contact , EEI Team Leader 

# 94-

FH394 

# ~ ~
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# 1 CASEO LOCAMON



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. .:::; ::..:. .:: : : :::.::::::.;::::..:;°.:,.::::: :::: :: ::;: ::;:: °::::: : : ' :Tn :: :; :'•>.Out:::: :



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## CF'IvI @ _._8__"H?

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# CALIBRATION SECTION 49

i Envisage

Environmental 

## ~ Incorporated

- P.O. Boz 152 Rithfield. OhiO 44286

PhOne(216)526-0990 

# 5:9--

# DRY GAS METER CALIBRATION sa

Using Wet Test Meter 

## Meter Box Number MB 1A 65 deg F, Ambient Temp. 

## Ca(ibration Date 3/18/94 28.28 "Hg, Baro. Press. Technician 

## Krisak Dry Gas Meter

Orifice Differential "H20 1.0 2.0 3.0 4.0 Meter Temperature deg F 102.0 105.0 105.5 105.5

Volume cu ft 7.300 14.175 26.500 28.195 Wet Test Meter

Orifice Differential "H20 -1.4 -2.1 -3.0 -4.0

Volume cu ft 6.790 13.375 25.005 26.715 Temperature deg F 66.0 65.5 65.0 65.0 Time of Test minutes 11.75 17.00 26.25 24.50 

### Totals Delta H@ .75 cfm 1.69 1.82 1.86 1.89

Y Factor 0.991 1.009 1.009 1.010 Dry Gas Meter MB 1A

Average Delta H@ 1.82 Average Y Factor 1.005
CALCULATIONS Y = Vt " Pbar ' (Tm) Vm ' ( Pbar + (°H / 13.6) ] ' (Tmw)
"H@ = .0317 " "H * Tmo ' min Pbar " (Tm) " Vw NOMENCLATURE Orifice Differentiat ="H Dry Gas Meter = sub m Temperature = T Wet Test Meter = sub w Votume = cu ft Barometric Pressure = Pbar Time of Test = min 

## ~ Envisage Environmental - Incorporated

- P.O. Box 152 Richfield, Ohio 44286 Phone (276) 526-0990

# DRY GAS METER CALIBRATION

Using Wet Test Meter 51 

## Meter Box Number MB 01 62 deg F, Ambient Temp. Calibration Date 4/1 /94 28.96 "Hg, Baro. Press. Technician Krisak Dry Gas Meter

Orifice Differential °H20 Meter Temperature deg F

Volume cu ft Wet Test Meter 1.0 2.0 3.0 4.0 74.3 76.3 78.0 79.8 6.430 9.050 17.555 14.830

Orifice Differential - 'H20 -1.5 -2.5 -3.5 -4.3

Volume cu ff 6.274 8.765 16.850 14.105 Temperature deg F 61.0 61.0 61.0 61.0 Time of Test mfnutes 11.00 11.00 17.50 13.00 Totals Delta H@ .75 cfm 1.73 1.77 1.81 1.90

Y Factor 0.998 0.992 0.984 0.975 Dry Gas Meter MB 01

Average Delta H@ 1.80 Average Y Factor 0.987
CALCULATIONS Y = Vw ' Pbar ' (Tm) Vm ' [ Pbar + ("H / 13.6) ] ' (Tw)
"H@ = .0317 ' "H * Tmo * min

Pbar * (Tm) ' Vw NOMENCLATURE Orifice Differential ="H Dry Gas Meter = sub m Temperature = T Wet Test Meter = sub w Volume = cu ft Barometric Pressure = Pbar Time of Test = min 

# _ Envlsage Environmental 

# -

Incorporated 

# • _

P.O. Boz 152 Richlleld, Ohio 44286 Phone (216) 526-0990

### "S" TYPE PITOT TUBE CALIBRATION 52 "S" Type Pitot Tube (Probe) # 501 - 5 ft Probe



### Calibration Date: March 4, 1994

/ ^P / std 

### C C ------- p std / ^P

v p (EPA Equation 2-2) where: C = Coefficient of Type S pitot tube, dimensionless P C = Coefficient of Standard Pitot Tube (0.99), dimensionless std 

### "P std 2 

### = Velocity head measured by standard pitot tube, inches H 0 ^P = Velocity head measured by Type S pitot tube, inches H 0 P 2

^P ^P C 

### std

------------- 

### p

------------------- 

### p

--------------- Side A 0.23 0.32 0.839 Side B 0.23 0.32 0.839 Side A 0.41 0.56 0.847 Side B 0.41 0.56 0.847 Side A 0.82 1.14 0.840 Side B 0.82 1.14 0.840 Average - 0.84

_ Envisage

Environmental - Incorporated

~

- P.O. Box 152 Rithfieltl, Ohio 44266 Phone (216) 526-0990
.~"S" TYPE PITOT TUBE CALIBRATION 53 "S" Type Pitot Tube (Probe) # 303 - 3 ft Probe

Calibration Date: March 4, 1994

/ Ap / std C = C ------- p std / ^P



## v p ( EPA Equation 2-2) where: C = Coefficient of Type S pitot tube, dimensionless P C = Coefficient of Standard Pitot Tube (0.99), dimensionless std ^P = Velocity head measured by standard pitot tube, inches H 0 std 2 ^P = Velocity head measured by Type S pitot tube, inches H 0 P 2

^P ^P C std

------------- p

------------------- p

--------------- Side A 0.27 0.38 0.834 Side B 0.27 0.38 0.834 Side A 0.44 0.61 0.841 Side B 0.44 0.61 0.841 Side A 0.78 1.06 0.849 Side B 0.78 1.06 0.849 Average - 0.84

- Enrisage

Environmental

- Incorporated

- P.O. Box 152 Rlohfleld. Ohio 44286 Phone (216) 526-0990

## ThermocouplelThermometer Calibration 54 

## Calibration Date: April 11, 1994 Technician: Krisak

Identification Low Reference Medium Reference High Reference Average 

### Number Reading Reading Reading Deviation 1 44 45 86 86 206 208 1.00 2 42 42 89 89 209 209 0.00 3 46 45 90 90 209 210 0.67 4 44 44 91 91 208 209 0.33 5 45 46 82 80 204 204 1.00 6 46 45 92 92 205 205 0.33 7 41 40 91 91 204 204 0.33 8 40 41 89 89 204 204 0.33 9 42 42 88 87 203 206 1.33 10 44 44 87 87 202 202 0.00 11 46 46 92 91 200 200 0.33 12 48 47 91 91 200 200 0.33 13 44 45 94 94 198 199 0.67 14 42 42 96 96 198 200 0.67 15 41 41 96 96 196 198 0.67 16 40 40 96 96 196 195 0.33 17 44 44 94 94 195 195 0.00 18 44 44 95 95 195 195 0.00 19 45 45 94 94 200 201 0.33 20 42 42 94 94 201 202 0.33 21 41 41 95 96 202 203 0.67



## ~ Envlsage

Environmental - Incorporated

- P.O. Box 152 RiChIiBIC. OhiO 44286 Phone (216) 526-0990

### SAMPLING NOMENCLATURE 

### 56

A = Cross sectional area of stack or duct, ft?. A, = Cross sectional area of nozzle entry plane, ft?. 

## k g = Water vapor in gas stream, proportion by volume. C = Nomograph correction factor, dimensionless. 

## C S = Concentration of particulate matter in gas stream, dry basis-corrected to

standard conditions, gr/dscf. D n = Nominal diameter of probe nozzle entry plane, in. E = Particulate Emission Rate, Ib./hr. "H = Average pressure differential across orifice, in. of H 2 O. 

## "H @ = Orifice meter calibration factor, in. of H 2 O. I = Percent of isokinetic sampling, %. K, = Pitot tube constant, 85.49 ft./sec. M d = Molecular weight of gas, dry basis, Ib./Ib.-mole. N~ 

## , = Total amount of particulate matter collected, g.

Molecular weight of gas, wet basis, Ib./Ib.-mole. N 

### ~ , = Molecular weight of water, 18 Ib./Ib.-mole. P bar = Barometric pressure, in. of H 9
. 

## P 9 = Pressure differential from gas stream to atmosphere,

(static pressure) in. of H 2 O. - Envisage Environmental - Incorporated 

# _ P.O. Boz 152 Richfleltl, Ohio 44286 Phone (216) 526-0990

### SAMPLING NOMENCLATURE - continued 

### 57

P s = Absolute gas stream pressure, (P bar + P 9 /13.6) in. of H 9
. Pstd = Absolute pressure at standard conditions, 29.92 in. of H g . PPM = Parts per million P,, = Density of water, 0.0022 Ib./ml. 

### "P a „ 9 = Average of the square roots of the velocity head readings, in. of H 2 0. Q = Volumetric flow rate at gas stream conditions, A.C. F. M. q td = Dry volumetric gas flow rate corrected to standard conditions, D.S.C.F.M. R = Ideal gas constant, 21.85 in. of H 9 -f~ /° R-Ib.-mole. t = Total sampling time, minutes. 

### T m = Average dry gas meter temperature, ° R. 

## T g = Average absolute gas stream temperature, ° R. T std = Standard absolute temperature, 528 ° rankine. V C = Volume of water collected in impingers and silica gel, ml. VOC = Volatile organic compounds V m = Volume of gas sample measured at meter box (meter conditions), ft 3. Vm(Std) = Volume of gas sample measured at meter box (corrected to standard

conditions), ft 3. V s = Average gas stream velocity, ft./sec. 

## Envisage Environmental Incorporated P.O. Box 152 Richlleld. Ohio 44266 Phone (216) 526-0990

### SAMPLING NOMENCLATURE 

## - continued 58

V,(std) 

### = Volume of water vapor in gas sample (standard conditions), 

### ft 

## 3. 13.6 = Specific gravity of inercury (H 9 ). %CO 2 = Percent by volume of CO 2 in gas stream (dry basis). %0 2 = Percent by volume of 0 2 in gas stream (dry basis). 

## %CO = . Percent by volume of CO in gas stream (dry basis). %N 2 = Percent by volume of N 2 in gas stream (dry basis).



## _ Envisage

Environmental 

## - Incorporated

- P.O. Box 152 Richflelo. Ohio 44286 Phone (216) 526-0990

# EMISSION SAMPLING CALCULATIONS 

# W

_ Envisage

Envlronmental 

# - Incorporated

— P.O. Boz 152 Riohfield, Ohio 44266 Phone(216)526-09901) Volume

- of

- dry

- gas - sampled

- through

- meter

- box

- at
- standard

- conditions, ^H

- T std - -Pb ----- V __ V 13_6_ - m(std) m 

## T m 

## P std (EPA Equation 5-1) Where• Um(std) Volume of gas sample meaiured at meter box (corrected to

standard conditions), ft
. V m = Volume of gas simple measured at meter box (meter

conditions), ft
. 

## T std = Standard absolute temperature, 528 0 Rankine. T m = Average dry gas meter temperature, ° R. 

## P bar = garometric Pressure, in. Hg. ^H = Average pressure differential across orifice, in. H 2 O. 13.6 = Specific gravity of inercury (Hg). 

## P std = Absolute pressure at standard conditions, 29.92 in. Hg. Example: Run 1 V = 43.73 ft 3 m T = 567.1 

## ° R m ^H = 1.50 in. H 2 0 

## P bar - 29•02 in. Hg
528.0 29.02 + -1.50-

------- ---------------- 13 

# = 6 - V = 43.73 m(std) 567.1 29.92

= 43.73 ( 0.9310 ) ( 0.9736 )

= 39.64 ft 3

- Envlsage Environmental

- Incorporated

- P.O. BOx 152 RiChfielA. OhiO 44286 Phane (216) 526-0990 Z12) Volume

- of

- water

- vapor

- collected

- at

- standard

- conditions,

-----------------------------------------------



### V w(std) V lc P w ( R) ( T s t d )



### M w P std (EPA Equation 5-2) 61

Where:


### V w(std) 

### V lc P w = M w = R = 

### T std 

### P std Example: Run 1



### V lc



### V w(std) Volume of water vapor in gas sample (standard conditions) ft 3
.

Volume of water collected in impingers & silica gel, ml. Density of water, 0.0022 lb/ml. Molecular weight of-water, 18 lb/lb-mole. Ideal gas constant, 21.85 in. Hg-ft 3 / o R-lb-mole. Standard absolute temperature, 528 o Rankine. Absolute pressure at standard conditions, 29.92 in. Hg.

33.2 ml

33.2 1- 0_0022- 

# I I(

- 21_85

- )

- (

-- 528 : 0

- )

18.0 29.92

1.56 ft 3


# _ Envisage Environmental 

# -

Incorp.orated

- P.O. Boz 152 Rlchlield. Ohio 44286

Phane(216)526-09904) Dry

- Molecular

- Weight

- of

- gas

- in

- gas

- stream,

---------------------------------- 63 M d = 0.440 (%CO 2 ) + 0.320 (%0 2 ) + 0.280 (%N 2 + %CO) (EPA Equation 3-2) Where: M d = Molecular weight of gas, dry basis, lb/lb-mole. 0.440 = Molecular weight of CO 2 divided by 100. 0.320 = Molecular weight of 0 2 divided by 100. 0.280 = Molecular weight of N 2 or CO (same for both compounds)

divided by 100. % CO 2 = Percent by volume of CO 2 in gas stream (dry basis). % 0 2 = Percent by volume of 0 2 in gas stream (dry basis). % CO = Percent by volume of CO in gas stream (dry basis). % N 2 = Percent by volume of N 2 in gas stream (dry basis). Example: Run 1
% CO 2 = 1.0 % 0 2 = 20.0 % CO = 0.0 % N 2 = 79.0
M d = 0.440 ( 1.0 ) + 0.320 ( 20.0 ) + 0.280 ( 79.0 )

= 0.440 + 6.400 + 22.120

= 28.96 lb/lb-mole

- Envisage Environmental

- Incorporated 

# _ P.O. Boa 152 Richfield, Ohio 44286 Phone (216) 526-09906) Average

- Gas

- Stream

- Velocity,



## ------------------------ 65 

## V= s T

K C ^P - - s -- P p av9 P s MS

\ (EPA Equation 2-9) Average gas stream velocity, ft/sec. 

### )H

__ ) 1 /Z Pitot tube constant, 85.49 - ft (1_b _/lb-mole(in.g sec I ( ° R}(in.H 0) I - 2 - Pitot tube coefficient, dimensionless. Average of th square roots of the velocity head 

### readings, ( \ 

# ~ ^p ) ( in.H 2 O ). Average absolute gas stream temperature, ° R. Absolute gas stream pressure,(P bar + P g /13.6) in.Hg. Barometric Pressure, in. Hg. Pressure differential from gas stream to atmosphere, (static pressure) in.H 2 O. 

### Molecular weight of gas, wet basis, lb/lb-mole. Where: 

### V s = K p = C p = 

### AP avg 

### T s = P s 

### P bar 

### P g = M s = Example: Run 1 

## C = P 

### AP avg 

### T = s P s M s = 0.84

0.668 in.H 2 O 1/2 733.2 ° R Pbar + P g /13.6 = 29.02 28.54 lb/lb-mole + -0.71 /13.6 = 28.97 in.Hg

V s = ( 85.49 )( 0.84 ) ( 0.668 ) I--=--=--=_733_2__--=--_-- \ ( 28.97 ) ( 28.54 )

= 45.17 ft/sec



## ~ Envisage Environmental - Incorporated

- P.O. Box 152 RichlielE, Ohio 44266 Phone (216) 526-09908) Volumetric

- Flow

- Rate

- at

- Standard

- Conditions, ------------------------------------_-- Q = 60 ( 1- B ) V A - T std

- - --- P Ps--- 67 sd ws s Ts std Where: (EPA Equation 2-10) Qsd = Dry volumetric gas flow rate corrected to standard

conditions, S.C.F.M. 60 = Conversion factor from seconds to minutes. B ws = Water vapor in gas stream, proportion by volume. V s = Average gas stream velocity, ft/sec. A = Cross sectional area of stack or duct, ft 2
. Tstd = Standard absolute temperature, 528 o Rankine. T s = Average absolute gas s.tream temperature, o R. P s = Absolute gas stream pressure,(Pbar + P g /13.6) in.Hg. 

### P bar = Barometric Pressure, in. Hg. P g = Pressure differential from gas stream to atmosphere,

(static pressure) in.H 2 O. 

### P std = Absolute pressure at standard conditions, 29.92 in. Hg. Example: Run 1 B = 0.0379 ws V s = 45.17 ft/sec A = 19.63 ft 2 T = 733.2 o R s 

### P s P bar + P g /13.6 = 29.02 + -0.71 /13.6 = 28.97 in.Hg
Q = 60 ( 1 - 0.0379 ) ( 45.17 ) ( 19.63 )( _528_0 28_97 - sd 733.2 29.92

= 35,697 SCFM

- Envlsage Environmental

- Incorporated

- P.O. Boz 152 Richfieltl. Ohio 44286 Phone (216) 526-0990

### 11) Percent

------------------- 

## - of -Isokinetic - Sampling,

------- _
~ 

### 100 T 

### s K V+



### 1 3 c - -Vm-

- — P + - -- H -



### bar 70 

### I


### _ T m 13 ..6

---------------------60---An---
~ 

### S---PS---t-------

~ 

### EPA Equation 5-7 Where:
. I = Percent of Isokinetic sampling, %. T s = Average absolute gas stream temperature, o R. 

### K 3 = Constant, 0.002669 in.Hg-ft 3 /ml- o R. V lc = Volume of water collected in impingers & silica gel, ml. (meter conditions), ft 3
. V m = Gas sample volume measured at meter box T m = o R.

Average dry gas meter temperature, P bar = Barometric Pressure, in. Hg. ^H = Average pressure differential across orifice, in. H 2 O. 

### t = Total sampling time, minutes. V s = Average gas stream velocity, ft/sec. P s = Absolute gas stream pressure, in.Hg. 

### D n = Nominal diameter of probe nozzle tip, inches.

Cross sectional area of nozzle, ft 2
. A = 

### n Example: Run

-------- 1 T s = 733.2 o R ^H = 1.50 in.H 2 O V lc = 33.2 ml t = 60.0 min. V m = 43.73 ft 3 V s = 45.17 ft/sec T m = 

### o R

567.1 P s = 28.97 in.Hg A n = 0.0003408 ft2 P bar = 29•02 in.Hg "Y" = 1.000 

## I = 733.2 100

( ) 0.002669 33.2

( ) + 7

I_I —

I_ 29.02 + i356-



### ------- 60 (0.0003408

- )

---- (

-- 45.17 28.97



### -- )

--- (

---- )

--- (

--- 60.0

-- )

--------- ~ --


### = 106.6 %
— Envisage Environmental — Incorporated

- P.O. Box 152 Riohlleld, Ohio 44286

Phone(218)526-09901) Volume

- of

- dry

- gas

- sampled

- through

- meter

- box

- at

- standard

- conditions,

-------------------------------------------------------- ^H V __ V - T std - - P b

- + --- 13_6 -- m(std) m 

### T m P std Where: Vm(std) Volume of gas sample meaiured at meter box (corrected to

standard conditions), ft . V m = Volume of gas simple measured at meter box (meter

conditions), ft . 

### T std - Standard absolute temperature, 528 0 Rankine. T m ' = Average dry gas meter temperature, o R. 

### P bar = Barometric Pressure, in. Hg. ^H = Average pr.essure differential across orifice, in. H 2 O. 13.6 = Specific gravity of inercury (Hg). 

### P std = Absolute pressure at standard conditions, 29.92 in. Hg. Example: Run 1 73

V = 46.25 ft 3 m T = 547.4 

### o R m ^H = 1.80 in. H 2 0 

### P bar = 29•02 in. Hg
528.0 Vm(std) 46.25 547.4

= 43.47 ft 3 29.02 + -1.80-- 13.6 29.92

- Envisage

Environmental

- Inoorporated 

# _ P.O. Box 152 Rlchfieltl. Ohio 44286 Phone (216) 526-0990

### 76

4) Dry

- Molecular

- Weight

- of

- gas

- in

- gas

- stream, ----------------------------------

M d = 0.440 (%CO 2 ) + 0.320 (%0 2 ) + 0.280 (%N 2 + %CO) (EPA Equation 3-2) Where: M d = Molecular weight of gas, dry basis, lb/lb-mole. 0.440 = Molecular weight of CO 2 divided by 100. 0.320 = Molecular weight of 0 2 divided by 100. 0.280 = Molecular weight of N 2 or CO (same for both compounds)

divided by 100. % CO 2 = Percent by volume of CO 2 in gas stream (dry basis). % 0 2 = Percent by volume of 0 2 in gas stream (dry basis). % CO = Percent by volume of CO in gas stream (dry basis). % N 2 = Percent by volume of N 2 in gas stream (dry basis). Example: Run 1
% CO 2 = 1.0 % 0 2 = 18.8 % CO = 0.0 % N 2 = 80.2
M d = 0.440 ( 1.0 ) + 0.320 ( 18.8 ) + 0.280 ( 80.2 )

= 28.91 lb/lb-mole



## ~ Envisage Environmentai - Incorporated 

# _ P.O. f3ox 152 Richfield. Ohio 44286 Phone (216) 526-09906) Average

- Gas

- Stream

- Velocity,

------------------------ : T V = K C ^P - -- s -- s p p avg P s M s \ (EPA Equation 2-9) Where: V s = Average gas stream velocity, ft/sec. ) H

_ ._g_) p _ 1 JZ K = Pitot tube constant, 85.49

- ft (1_b _/lb-mole(in_ sec I ( ° R)(in.H 0) I - 2 - C p = Pitot tube coefficient, dimensionless. ^P = Average of th square roots of the velocity head avg reading-s, ( \ 

# ~ ^p ) ( in.H 2 O ). TS = Average absolute gas stream temperature, ° R. P s = Absolute gas stream pressure,(P bar + P g /13.6) in.Hg. 

# P bar = Barometric Pressure, in. Hg. P g = Pressure differential from gas stream to atmosphere,

(static pressure) in.H 2 O. M s = Molecular weight of gas, wet basis, lb/lb-mole. Example: Run 1 C = 0.84 P ^P avg = 0.719 in.H 2 O 1/2 T = 736.1 ° R 

## s 

## P s Pbar + P g /13.6 = 29.02 + -0.55 /13.6 =. 28.98 in.Hg M = s 28.50 lb/lb-mole

------------------------- V = ( 85.49 )( 0.84 ) ( 0.719) _ _736.1

_ )--- s

= 48.71 ft/sec
_ Envisage Environmental _ Incorporated

- P.O. Box 152 Richfieltl, Ohio 44286 Phone (216) 526-09908) Volumetric

- Flow

- Rate

- at

- Standard

- Conditions, -------------------------------------- _ -- 80 Q = 60 ( 1- B ) V A
_ T std - -- P s - _ sd ws s Ts Pstd Where: '

_ (EPA Equation 2-10) Qsd = Dry volumetric gas flow rate corrected to standard

conditions, S.C.F.M. 60 = Conversion factor from seconds to minutes. B ws = Water vapor in gas stream, proportion by volume. V = Average gas stream velocity, ft/sec. s 

### 2 A = Cross sectional area of stack or duct, ft. Tstd ° Standard absolute temperature, 528 o Rankine. T s = Average absolute gas stream temperature, o R. P s = Absolute gas stream pressure,(Pbar + P g /13.6) in.Hg. Pbar = Barometric Pressure, in. Hg. P = Pressure differential from gas stream to atmosphere, g (static pressure) in.H 2 O. Pstd = Absolute pressure at standard conditions, 29.92 in. Hg. Example: Run 1
B = 0.0375 ws V s = 48.71 ft/sec A = 19.63 ft 2 T = 736.1 o R s 

### P s Pbar + P g /13.6 = 29.02 + -0.55 /13.6 = 28.98 in.Hg Q = 60 ( 1- 0.0375 ) ( 48.710 ) ( 19.63 _528_0 28_98_ sd 

# I 736.1 29.92

= 38,369 SCFM

Envisage Environmental Incorporated P.O. Box 152 RiOhlleld, OhiO 44286 Phone (216) 526-09909) Gas

- Stream

- Sulfur

- dioxide

- Concentration = - (lb/dscf), 

### ------------------------------------------- — Vsln

_ -- ( -Ut---V tb

- ) ---N-- ---- V a---=l -- C S02 K 2 V --- m(std) (EPA Equation 6-2) Where: C SO = Concentration of sulfur dioxide, dry basis corrected to 

### 2 standard conditions, lb/dscf. K 2 = Constant, 7.061 x 10 -5 lb/meq. V t = Volume of barium perchlorate titrant used for the sample,



### ml (average of replicate titrations). V tb = Volume of barium perchlorate titrant used for the blank, ml. N = Normality of barium perchlorate titrant, milliequivalents/ml. 

### V sln = Total volume of solution in which the sulfur dioxide sample

is contained, ml. 

### V a = Volume of aliquot titrated, ml. Vm(std) Volume of gas sampl

- e meaiured at meter box (corrected to



### standard conditions), ft . Example: Run 1 V t = 4.0 ml V tb = 0.0 ml N = 0.0110 meq/ml

240.0 ml 

### V sln = ` V = 1.0 ml a 

### 43.47 ft 3 Vm(std) 

### -5 ( 4.0 - 0.0 ) 0.0110 24 0: 0 - = 7.061 x 10 ------------------------------------------------- 

### CS0 2 43.47

= 0.1703 x 10 -4 lb/dscf --------------- _ Envisag• Environmental — Incorporated

- P.O. Boz 152 Rlchfield, Ohio 44266 Phone (216) 526-0990

. ~ I

r~:

11) Sulfur

- dioxide

- Emission

- Rate, -------------------------

_ 60

-- minutes - ---------- 

## E S0 2 C S0 2 4 - sd - 1 hour

Where: E SO = Sulfur Dioxide Emission Rate, lb/hr. 2 R sd = Dry volumetric gas flow rate corrected to standard

conditions, S.C.F.M. C = Concentration of sulfur dioxide, dry basis corrected S02 to standard conditions, lb/dscf. Example: Run 1 

## Q sd = 38,369 SCFM C SO = 1.703E-05 lb/dscf 2 E SO = (1.703E-05 )( 38,369 ) ( 60 ) 2

= 39.19 lb/hr



# _ Envisage Environmental 

# -

Inoorporated

- P.O. Box 152 RlohlielG.Ohio 44286 Phone (216) 526-09901 ~l

~ 

### VISIBL.E EMISSION OBSERVA TION FORNi

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### STACK TEST OBSERVATION REPORT METROPOLITAN INDUSTRIES

15 76 05 1149 P004, P005 & P006 

### MARCH 30 & APRIL 14, 1994 On March 30, 1994, George Long and I observed the stack testing of the present three tunnel kilns, all in operation and ducted to a common stack (150 foot stainless). The testing firm was Envisage Environmental. The representative from Envisage was Greg Sinkovich. I did the VE readings during the stack test, the final leak checks on the unit located on the stack platform about 75 feet above the ground and observed the sampling trains used. George observed the testing technique and the final leak checks on the SO Z unit stationed on the ground at the base of the stack. Tunnel Kiln #1 (P004) and Tunnel Kiln #2 (P005) use a common dryer and therefore, process the same tile composite materials. They were being operated at a rate of 34 cars per day (each) and processing product 507, which is a 100% clay product. This calculates to 62.832 dry tons of product / kiln / day, concerning these two kilns. Tunnel Kiln #3 (P006) was being operated at a rate of 40 cars per day, and was processing product 310, which is a 30 % clay, 70 % shale composite. TK #3 was calculated as processing 73.92 dry tons of product / day. The total capacity during the stack test was at a rate equivalent to 199.584 tons / day, which is 90% rated capacity for the operation. Attached is confirmation from Metropolitan. It was explained previously at a meeting that the manufacturers rating for the kilns is 36 cars / day, which makes 108 cars / day the 100% capacity rating for the operation of all three kilns. However, 40 cars / day is the potential Metropolitan can push. Therefore, 108 cars / day could be viewed as 90% potential capacity. q, ~~ ~ ~~~,~ : 

### A G>

~ - 

### J A Particulate Sampling - Observation Checkiist was completed. The stack test was for particulates, SO Z and fluorides (Method 1-5, Method 6 and Method 13A, respectively). Audit samples for SO Z were given for analysis, C8613 & C8853. No problems were seen in the test methods. All leak checks were ok. The peak temperature in TK # 1 & #2 was 1190 °.K, and in TK #3 it was 1 150 °k+'. Copies of all raw data were collected at the time of the testing. ? Audit sample results from Envisage indicated that their results could not be accepted for the SO Z portion of the stack test. Therefore, the S0 2 portion of the stack test (Method 6) had to be repeated on April 14, 1994. All operation parameters for the April 14th test were the same as that of the March 30th test. Audit samples for SO Z were again given (C8947 & C8823). This time, the results came back within an acceptable range. The Envisage rep. during the April 14th test was Bob Hovan. The tile samples collected by Metropolitan during the last stack test were to be sent out for sulfur analysis. The April 14th testing was observed by myself. I did the VE readings on emissions from the lvletropolitan stack and final leak checks on the Envisage equipment. The weather conditions were better than that of March, and a steady flow of low emissions was very evident. Once again, raw data was collected at the time of testing. This data was collected by Philip McGuinness of Metropolitan and copies made available the following day. Dan Aleman of our office received them.

Rick L. Miller Staff Field Inspector 

## ii 

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## Envisage Environmental Incorporated

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# ~ II!{ 

## FEB 2 41994

T} .s~~ ~ ! EALTH LE. ~~ i. •

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### February 23, 1994
Mr. Andy Pasko Canton City Health Department Air Pollution Control 420 Market Avenue N. Canton, Ohio 44702
Dear Mr. Pasko: I am enclosing your copy of the Intent to Test Notification for testing of the 

### TKi, TK2, and TK3 Common Exhaust at th ~ 

## tr

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### facility, Canton, Ohio. Please review for accuracy of information. One copy has been sent to Mr. Phillip McGuiness, Metropolitan Ceramics; 

### and one copy has been retained for our files. If there are any changes please notify us as soon as possible. Questions may be directed to Mr. Frank Hezoucky or myself. Sincerely, 

# S ' H Robert ovan Air Quality Supervisor ENVISAGE ENVIRONMENTAL INC. Enclosure

P.O. Box 152 Richiield, Ohio 44286 Phone (216) 526-0990 Fax (216) 526-8555 

# ~ ~1 

### 07:09:51 0104 01 MALONE COL 04/14/94

01 02 03 04 05 06 

### CHAN S02 WD WS TEMP 1 TEMP 2 03 SD1 UNITS PPM DEGR MPH DEG C DEG C PPM DEG FSCL .473 540 50.0 50.0 50.0 .471 99.9 ZERO -.024 0 0.0 0.0 -30.0 -.024 00.0 ------------------------------------------------***** ----------------------------------------------- 01:00 0.001 248 11.7 23.4 7.1 0.033 10.7 02:00 0.001 251 10.6 23.6 6.5 0.032 9.8 03:00 0.001 245 9.4 23.6 5.9 0.031 9.2 04:00 0.001 254 13.4 23.4 6.8 0.037 10.6 05:00 0.001 241 10.1 23.4 6.9 0.036 11.8 06:00 0.004 229 7.9 23.6 7.0 0.028 14.3 07:00 0.005< 225< 8.0< 23.7< 7.3< 0.021< 14.7 08:00 0.005 226 8.6 23.9 8.9 0.027 15.8 09:00 0.003 216 9.3 24.1 10.2 0.036 15.7 10:00 0.003 200 7.3 24.4 11.9 0.037 18.6 11:00 0.003 185 7.3 25.2 13.4 0.041 19.9 12:00 0.010 184 8.3 26.1 14.5 0.042 16.9 13:00 0.022 201 9.2 27.1 16.2 0.042 22.1 14:00 0.016 212 10.4 27.4 18.6 0.050 18.6 15:00 0.013 241 10.3 27.3 20.5 0.056 19.4 16:00 0.007 253 14.7 27.3 21.0 0.061 15.7 17:00 0.005 262 12.3 27.2 21.2 0.062 13.9 18:00 0.003 269 10.0 27.2 21.1 0.065A 13.1 19:00 0.003 254 7.1 27.2 20.3 0.056 10.7 20:00 0.005 272 2.6 27.2 19.0 0.018 30.9 21:00 0.003 109 1.2 27.2 18.3 0.031 26.2 22:00 0.006 116 4.2 27.4 17.1 0.004 7.1 23:00 0.008 183 5.7 27.0 17.1 0.024 8.7 24:00 0.012 198 6.8 27.2 17.0 0.021 8.8 DLYAV 0.006 ------ 8.6 25.6 13.9 0.037 

### CALIBRATION RESULTS NONE CONDUCTED



## ~~1r' 

### F1ELD DATA COVER SHEET 

## PLANT 

# ~ &v DATE q - N-- 

## ~ `I SAMPLING LOCATION

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sampling locations meet ati-on (s) modified to y

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Sampling - Observation Checklist

Sampling Method(s): RM 5 13; 53; 5B E3; 5D E3; 5E E3; 5F C3; 8 t3; 12 E3; 17 C3; or other ( I f other, , p 1 ease descri be. ) /GJt`
Are there anY r+odi f i cati ons to the speci f i ed ref erence methoti ( s)? Yes CJ; No Cy

~ (If yes, please describe modification.)
Do the inlet (if applicable) and outlet the requirement s specified in RM 1? Yes E3; No E3 (If n . o } ow was (were th allow sampling?) /~ ✓ ~ ~~l o~~~~ `1'4
If inlet/outlet sampling is being performed, are the samples befng taken simultaneously? Yes 13; No E3 (If no, be sure that the source operating parameters are the same vjhen they switch trom one to the other.) If cycionic flow is present and other sampling.locations do not exist, how will the samples be withdrawn? 

## ~ Di recti onal probe techni q

~~ e C 7; Ai i gnment techni que G7 ; other C 3 (If other, please describe.)
Is the sampling trafn set up properly, in accordance with the reference method or as agreed upon in the pre-test meeting? Yes C3; No E3 (If no, correct problems and continue, if possible.)

. ChecE: to ensure.that the sampling equipment has been recently cal ibr3ted ( i. e. ,/theter bo:: , therm met rs/therm coupl es, pitot / tubes, etc. ) Of

~ : 4Yj , not DK C 3 3~~/ `~'~ iir Type of filter: / Is the fflter assembly positioned properly? Yes C3; No E3 (If no, adjust and continue, if possible. Please note that the filter may be ch.anged during the test run; however, it is recommended that the entire filter assembly be changed.)
m„_•;

Nozzle Diameter: (Please note that the nozzle may not be changed during the test run.) Number of sampling points on a traverse: Sampling time per point: Type of probe: (quart" ainless stee] ; water jact:eted, etc. ) Type of probe liner (if applicabie) : Impinger contents: First - Second - Third - Fourth Modifications Will the stacF: moisture content be determined as part of •P.M 5? Yes C 7; No C] ( I f no, pl ease descri bei 

# ~ he procedure for the separate moisture determination.) ~
Gas analysis: Orsat C7a Fyrit 1 7; Grab C7; other C] (If other, please describe. )

--, Indicate probe and filter iqq> temperature settings: Probe (if applic-able) - /U 

### ~ Filter box - (If on, have probe checked to'ensure it is heating properiy.) Reminder: When conduct3ng tests on boilers, the probe and filter

box temperatures may not exceed 320 degrees Fahrenheit Ensure that the sampiing por is fare) sealed around the probe(s) when sampling. OK E(•; not Ofk C7 Chect: and note color and conditfon of sflica gel:

' 0 ! ?, -&( Leak-checf:s: Pre-test (optional) - cfm Cd "Hg s'v,, Post-test (mandatory) - O 0 cfm @ "Hg (The post-test leak-checi; must be conducted at 'or above the highest vacuum reading encountered during the test run. The leak checE: should be conducted by plugging the inlet to the probe noZ..le. The maximum acceptable leakage rate for a leak-check is .02 Cfm (.0057 cmm) or 4% of the average sampling rate, whichever 

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Particulate Sampling - Observation Checklist
Date: Observ , Facili - Source Test F Samp 1 i n

~ hlethod ( s): FM 5 CYJ; 5A 13; 5B C3; or other 13 (If other, SD 13; 5E 13; 5F C3; 8 C3; 12 C3; 17 C3; please describe. ) /-, c} /g ~

hreth ~ re any modifications to the specified reference method(s)? Yes CV

~ J / ; No L. (?f yes, please describe modi ` f ' i / cation.)

—~ /GtG ~ a . l / ~f~ /Y t ✓ ~ ~/ ~~ G'4hs ?6 ~ h ~ .,i' le CL Do the inlet (if applicable) the requirements specified in Yes :.; No C 7 ( I f ow wa s allow sampling?) — -
If inlet/outlet sampling is being performed, are the samples beinq taken simultaneously? Yes C 3; No 11 ( If nb. be sure that the =_ource operating parameters are the same vwhen they switch r'rom one to the oti

- her. )

4i If cyclonic flow is present and other sampling locations do not exast, how will the =_amples be withdrawn? Directional probe tDchnique 13; rlliqnment technique CZ .-other C3 (If other, please describe.)
Is the sampling train set up properly, in accordance with tt

- +e ' ~ refer 

### 5

ece method or as aqreed upon in the pre-test meetinq? Yes C J; No C3 (If no, correct problems and continue, if

~ p o s s i b 1 e . > ~ Pi~ !M ~ /.[ er- ~ ~, ~ ,!"'f ~w ~+~ /~ Ja~f.~ e~ 6 ~~ -.% /~ ~, ~~/,~ ~ f~ CtJS3J" Lf1'C ~ C %d eA ,Cti 64_ '' ~~~.~~ pIP . ~~:~G ^' 4 -Y ~ '~ ~> \ Checi; to ensure that the sampling equipment has been recently cal ibrated ( i. e. , ~ ter bo;; , thermometers/th

~ ermocoupl es,

~ p tot ~e~t tubes, etc. ) OK L J; not OK 13
~ /iir C, cj 

## W a-y ~ - Type of f i 1 ter : Is the 

### /+ ilter assembly positioned properly?
~ Yes CP1; No 13 (Ir" no, adjust and continue, if possible. Flease note that the filter ma
. v be chanqed during the test run;
. however, it is recommended that the entire filter assembly be changed.) 

## /a0 'q_~ Nozzle Diameter:

(Please note that run.) the nozzle may not be changed during the test Number of sampl i ng poi nts on atraverse: Sampling time per point: 

### ..S

~ Type of probe: %quartz. stainless steel water jac(;eted, etc. ) Type of probe li 2wC e ? r(if applicable): 

### S Impinger contents: f First - Odn ~ Second - Third - e: ~ Fourth - v C Modifications - ~ / o cd iv / 7 h'

Wi11 t 

### pr e stacfs moisture content be determined as part of

~ Yes C ✓

J: No 17 (If no, please describe the procedure for separate moisture determination,) RM 5? the

Gas anal is: 

### 4 Orsat C

~

J; Fyrite 17; Grab C7; other CJ (If other, please describe.) Indicate probe and filter oo:; tempe_rature settings: 

### ~ Frobe (if applic-able) Filter bo:: - ,' ~ c/AC (If on, have probe checl:ed to ensure it is heating properly.) Reminder: When conductinq tests on boilers, the probe and filter

box temperatures may not e::ceed 3 , 20 degrees Fahrent

- heit ol Ensure that the sampling port^) is (are) sealed around the probe(s) when sampling. Ok: 114, not OK C] Che ; and note color and condition of silica gel: F ~/r~• ~ 1 '(,. Leak-checks:

/ P

~ p~ =test .( .S ~ y, > - ~d/ ~ .~~ cfm id l.~ ~~ 

# //'s_ "Hg 

### ~N~~ Post-test (mandatory) cfm Hg (The post-test leaF:-checl; must be conducted at or above the highest vacuum reading encountered during the test run. The leak checE; should be conducted by plugging the inlet to the probe nozzle. The maximum acceptable lea{:age rate for a leak-checF: is .02 cfm (.0057 cmm) or 4% of the average sampling rate, ,whichever

/ Q~~is less. If the sampling was stopped during the test run to

change a sampling train component, be sure the sampling train is leaEc-checEced again. ) F'eriodically record readings from the test firm's raw data sheet(s) (i.e., delta H, delta F, initiai Cas volume, filter numbers, filter box temperatures, etc.). Or photocopies of the raw data sheets may be requested from the test firm. (Attach the readings and/or photocopies to this chectclist.) Check to ensure that the sample train recovery procedures are conducted properly ( i. e. , f i i ter handl ing, probe wast

- h, 1 iqui d transfers, appropriate sample recovery solution(s), recovery of nozzel catch, etc.). (+lill there be additional sampling and/or analyses performed (i.e., particle size distributions, bacl:-half analysis. HC1 analys , metals anaiysis, etc.)? Yes CO; t+10 ] (ir' yes please describe. ) ..Gf ~ifo~ ~ ctbi• ~~ . d' w /3 A- ~ /tc A lp r i.4'f

Optional checEcs/verifications: The test firm may be asked to do a ten (iv) minute run on their dry gas meter for calibration verification. Operate the meter at the delta H setting obtained from the test firm's calibration sheet. Record the volume collected, the dry gas meter temperatt_tre and the barometric pressure. Calcuiate a dry gas meter calibration check value, Yc, as follows: 'Yc = 10 C0.0319 * Tm31/2

tlm Fb ar Where: Yc = dry gas meter calibration check value (dimensionless) 10 = ten minute verification run Compare the Yc value with the dry gas meter calibration factor Y to determine that: 0.97 Y<; Yc <; 1.03 Y. If the Yc value is not within this range the meter should be recalibrated and if compieted the run and/or test should be voided. The test r'irm may be required to perform at least one actual moisture determination. (This chect; shouid be performed ar'ter the first run. ) Measure or have the test firm remeasure the nozzle diameter to verify it's calibration. (This should be performed for each nozzle utilized.) 

# ia~Source operating conditions - Compliance demonstation checklist

Source operating rate(s) (i.e., total heat input. feed rate(s), steam loaoi s

~ + char p p e rates, etc. ): s~~- c~~,~s„~'~



### ~ FYJ1 e ~ -O , A3 J / fl F'eriodically chec}: and record the operating rate(s) during the test period. Tot31 heat input determined by: F Factor C J: coal scales E] Date of coal scale calibration: F'rocess weight rate: For incinerators, indicate the operating temperature(s) and retention time(s) (if E:nown) : Did the source perform sootblowing, ash pulling, ESF' plate rapping or fabric filter cleaning during any of the test runs? Yes CJ; No 17 (If yes, please indicate activity and time interval(s).)

Indicate the type(s)

- of continuous monitor(s) utilized by the source being_ tested: Opaci ty C]; S02 C]; NO-c C]; CO C].; 02 C 7; other C] ( I f other please describe.) F'eriodically check and record the readings from the monitors during the test period. Are visible emissio 

## y readings being taken in accordance with RM 9 procedures? Yes CJJ; No L7 If yes, are the RM 9 readings comparable to the continuous opacity monitor readings? Yes 17; No C] (If no, indicate the discrepancies.) ! ~ i4

Are the coal and/or auxiliary fuel(s) and scrubber water and/or ash samples (if applicable) t ~ eing collected at the proper location and frequency? Yes tJ; No CJ (If no, correct and continue, if possible.) Additional source or process information:


# /2v ~03/2911994 11:15 L104040400 

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### ADDITIONAL TERMS & CONDITIONS


# ~ 1. Performance Test Requirements METROPOLITAIV INDUSTRIES 1576051149 

### P004

The permittee shall conduct, or have conducted, performance testing on the air contami.nant source(s) in accordance with procedures approved by the Agency. Two copies of the written report shall be submitted and signed by the person responsible for the test, describing the test procedures followed and the results of such tests. The Director, or an Ohio EPA representative, shall be allowed to witness the tests, examine testing equipment and require the acquisition or submission of data and information necessary to assure that the source data and information necessary to assure that the source operation and testing procedures provide a valid characterization of the emissions from the source and/or the performance of the control equipment. A completed Intent to Test notification form shall be submitted to the Canton City Health Deparmient, Division of Air Pollution Control, 420 Market Avenue North, Canton, Ohio 44702. This notice shall be made thirty (30) days in advance and shall specify the source operating parameters, the proposed test procedures and the time, data, place and person(s) conducting such tests. Two copies of the test results shall be submitted within thirty (30) days after the completion of the performance test. Tests shall be performed for the following sources and pollutants:

ource Pollutant(s) P004, P005, P006 S0 2 , Fluorides Test'Method 13A should be employed to measure fluoride emissions. Test Method 6 should be employed to measure SO Z emissions. This test shall be run with all three kilns (#1, #2, #3) operating. This test shall be run at or near the maximum production capacity of all three kilns. This stack test shall include an analysis of the sulfur content of the raw materials (clay and shale). This test shall be conducted before Ivlay 1, 1994. 2. A sulfur content limit will be established for the raw materials (clay and shale) used in Kiln #1 (P004), Kiln #2 (P005) and Kiln #3 (P006). This limit shall be based on the results of the stack test done with all three kilns operating and shall be on a quarterly weighted average. Sulfur analysis method L E co will be used. At any one time, only two of the three kilns can be using a 1009'o clay mix with no shale. The third kiln must be using a mix with a shale content of at least 40%. J No more than 79 tons of raw materials shall be used in each kiln in any one day. The facility shall maintain monthly records which: A. List the weekly average sulfur content (percent) of daily sampled clay and shale and analyzed as weekly composite samples; B. List the clay and shale content of mixes used in each kiln each day; and


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