OAR Box 1394 

Prepped by Ollie Stewart 

Document Number: 

12) ll-B-7 

Docket Number: 

A-94-52 

Printed 7/3/2008 7:22:10 AM Sheet 12 of 57 
P.2 

17 £7i 

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O PACIFIC ENVIRONMENTAL SERVICES, INC. 

f 1 ^cj hs^^ 

p*. /^»w ^ 

1 1 _ T, -2 -«r r> 

A»@*4-§2 

&~&-7 

Central Park West 

5001 South Miami Boulevard 

PO Box 12077 

Research Triangle Park. NC 27709-2077 

(919)941-0333 FAX (919) 941-0234 

SITE VISIT REPORT 

TO: 

FROM: 

DATE: 

SUBJECT: 

Madeleine Strum (MD-13) 

ESD/CPB 

U.S Environmental Protection Agency 

Research Triangle Park, NC 27711 

Greg^raFlam and Dean Carroll 

Pacific Environmental Services, Inc. 

October 6, 1993 

L:\N027 (N204) 

(PES) .;'; i'l f." |, !!•/ f 

Site Visit--Picken's Plastics, Inc. 

Ashtabula, Ohio 

EPA Contract 68D10116; ESD Project 93/58 

PES Projects N027, N204 

I. Purpose 

The purpose of this visit was to observe hand layup, sprayup, and 

compression molding fabrication processes and to obtain information on the 

processes, hazardous air pollutant (HAP) emissions, and applicable control 

measures. This information will be used in the development of a maximum 

achievable control technology (MACT) standard for the reinforced plastic 

composites production source category. 

This site visit was part of a 3-day trip to observe operations at six 

composite facilities by the U.S. Environmental Protection Agency (EPA), its 

contractor, Pacific Environmental Services, Inc. (PES), and representatives of 

two industry trade associations: The Society of the Plastics Industry 

Composites Institute (CI), and the Composites Fabricators Association (CFA). 

II. Place and Date 

Picken's Plastics, Inc. 

4212 Ann Avenue, P.O. Box 1279 

Ashtabula, Ohio 44004 

August 12, 1993, 8:30 a.m. - 11:00 a.m. 

II^TA M r. r> . OCCCADA U TDIAMA I c Dtni / nr» . t r\r* . rrt,. r>ii>ir>ikii>iA'rt r\% i 
P.3 

Site Visit Report - Picken's Plastics 

Page 2 

III. Participants 

Picken's 

Mr. Tom Picken, President 

Mr. Ted Hebert, Consultant to Picken's Plastics 

U.S. EPA 

Ms. Madeleine Strum, Project Manager 

PES 

Mr. Greg LaFlam, Environmental Engineer 

Mr. Dean Carroll, Environmental Engineer 

SPI Composites Institute 

Mr. John Schweitzer, Technical Director 

Composites Fabricators Association 

Mr. Steve McNally, Director of Government Affairs 

IV. Discussion 

Picken's Plastics is located in Ashtabula County, Ohio, an attainment 

area for ozone. State regulations limit emissions of photochemically reactive 

VOC's from each permitted emission source to no more than 40 pounds (lb) per 

day, or 8 lb/hr. (The State of Ohio considers some compounds defined as VOC's 

by EPA to be photochemically reactive, and others to be nonphotochemically 

reactive.) (Please confirm, is styrene considered photochemically reactive?) 

The facility is required to keep daily records of resin and gel coat use at 

each spray booth and to file a quarterly report with the State. 

The visit began in Mr. Picken's office with Mr. Picken and Mr. Hebert 

describing the products, processes, emissions, and control measures at the 

facility. Mr. Hebert agreed to provide additional written information to PES 

at a later date (this information was received August 16, 1993 and is 

discussed in Section V). At 9:30 a.m., a tour of the process operations at 

the facility was taken. The tour concluded at 11:00 a.m. 

A. Processes and Products 

Picken's Plastics was started by Tom Picken in 1974, and today has 

approximately 100 employees working two shifts per day, 5 days per week. The 

company's product line consists primarily of truck parts (tractor hoods and 

side fairings) for sale to major truck manufacturers. Four truck hoods per 

day are produced at the facility. The company has also produced covers for 

large machinery and has performed on-site repairs to composite piping at a 

nuclear power plant and at chemical production facilities. 
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Site Visit Report - Picken's Plastics 

Page 3 

The facility's primary production process is open molding, consisting of 

about 90 percent hand layup and 10 percent sprayup. Some closed molding is 

also carried out, using sheet molding compound (SMC) and bulk molding compound 

(BMC) in compression molds. 

Three types of resins are used in the open mold processes: 1) 

orthophthalic general purpose polyester, 2) an isophthalic-orthophthalic blend 

(withstands 225-250°F for 1 hour), and 3) a corrosion-resistant resin (used 

for on-site repairs at chemical facilities). (Please match these resin types 

to the attached MSDS sheets.) A methyl ethyl ketone peroxide (MEKP)-type 

catalyst (Lupersol DDM-9 by Atochem) is added to the resins at 1 to 1.5 

percent by weight. One of the resin mixes used within the facility 

incorporates a styrene suppressant additive for reducing styrene emissions, 

which is added by the resin vendor at 1.5 percent by weight. A vapor 

suppressed gel coat is also used at Picken's. (Please specify if any other 

resins or gel coats have vapor suppressant components. Also, what products 

cannot be produced with styrene suppressed resins?) 

Resin shipments are received into a non-vented 8,500-gallon highway 

tanker approximately once per month. It is transferred to custom totes (about 

20 in the plant) for use in the spray booths. (Hhat size are the custom 

totes?) For hand layup, the resin is transferred to plastic buckets. 

The facility operates five spray booths permitted with the Ohio EPA, 

consisting of one gel coat booth and four resin/chopped fiber fabrication 

booths. Molds are treated with a product called "Monocoat" (a mold release 

agent), after each fifth part is produced. (Is there an MSDS available for 

the Monocoat?) Gel coat is first sprayed onto the mold surface, at a 

thickness of 15 to 20 mils. This layer cures in approximately 20 minutes. A 

layer of resin combined with chopped fiberglass roving is then applied using 

an airless spray gun with a glass chopper unit. The resulting layer is 

approximately 69 percent by weight resin, 30 percent glass, and 1 percent 

catalyst. 

Each spray booth is ventilated through a bank of wall-mounted dry Andrea 

filters situated at the bottom of one wall of the booth, through a blower and 

then to the atmosphere through a round stack. The adjacent "walls" are 

actually fully open to the rest of the shop. The following information on the 

booths was provided: 

Booth #/Tvpe 

B5-A/Resin 

B5-B/Resin 

B5-C/Resin 

B-6/Gel Coat 

# of 20"x20"x2" 

Filters 

8 

4 

14 

12 

Flow (acfm/fonO 

4,704/175 

3,093/115 

4,093/152 

6,750/250 

Stack Dia 

34 

27 

24 

36 

Inches 

n 

n 

H 

The filters may last from 1 to several days before they need to be changed 

out. Spray booths are cleaned weekly. Each booth utilizes a 3-gallon 
P.5 

Site Visit Report - Picken's Plastics 

Page 4 

pressurized cannister of acetone piped to the spray gun, which is used for gun 

flushing between spraying operations. 

Smaller parts are laid up by hand in open areas of the shop floor. 

Woven glass reinforcing cloth is spread out on sheets of brown paper on a work 

bench, and the cloth is saturated using brushes dipped into open plastic 

buckets of resin. Pieces of saturated cloth are then pressed onto the mold 

and smoothed out using brushes and rollers. 

Finishing operations, including trimming, assembling, grinding, and 

sanding, are performed in trim booths B8, B9, and BIO. Booth B8 contains six 

work stations, termed Sl, S2, S3, S4, S5, and S6. Two separate dust 

collection systems (2 Model DC6000's by Dustcontrol) are used for spot 

collection of dust from the finishing tools. Exhaust air from these systems 

is recirculated back into the building to conserve heat energy. These systems 

are emptied daily and the dust is discarded to a landfill. The company 

reports that the system collects dust with 99.57 percent efficiency, and about 

0.6 pound of dust is collected per 100 pounds of product processed. Booth B9 

is a sanding booth which is exhausted using two fans through 14 filters 

(24"x24"x2") into separate stacks. Air flow through each fan is 2,756 acfm 

(175 fpm). Collected dust is discarded to a landfill. Booth BIO is used for 

trimming and assembly of truck hoods. This booth utilizes a bank of Andrea 

filters to clean the dusty work air, which is exhausted at 6,339 acfm (105 

fpm) through a fan to a single 36-inch round stack. 

The facility uses approximately two drums per year of bonding agents 

to assemble the truck components. The primary adhesive is Pliogrip 6600, 

supplied by Ashland Chemical. This product is classified as a polyurethane 

prepolymer, and contains 19 to 26 percent by weight of the HAP methylene 

phenylene diisocyanate (MDI). Paints are sprayed in a separate booth onto 

the external surfaces of the truck hoods in order to produce a Class A 

(automotive quality) surface. (The painting operation, which follows the 

trimming and assembly of truck hoods described for booth B10 above, was not 

observed during the visit.) 

The facility also operates seven BMC/SMC closed-mold presses. Both BMC 

and SMC are purchased from outside sources for these processes. (What kinds 

of products are made from BMC and SMC at Picken's?) The styrene content of 

these molding compounds is 11 to 13 percent. The company estimates that about 

0.5 percent of the styrene content is lost as emissions during these molding 

operations. Measurements at these molds have indicated concentrations of 

styrene no higher than 15 ppm in the breathing space. 

B. Waste Handling and Clean-up 

The company previously relied exclusively on acetone for cleaning, but 

replaced much of its acetone usage on July 1, 1993, with a product called 

Envirosolv 2000. Acetone is still used for gun cleaning and flushing between 

sprayup operations. An on-site distillation unit is used to recycle the 

acetone for further use. The company has reduced its projected annual usage 
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/ ^ 

Site Visit Report - Picken's Plastics 

Page 5 

of acetone from 70,000 pounds to 50,000 pounds. No methylene chloride and no 

ozone-depleting chemicals are used at the facility. 

The facility disposes of no unpolymerized resin waste. Small amounts of 

SMC occasionally polymerize in storage, which are then disposed of as nonhazardous material. The facility is categorized as a small quantity hazardous 

waste generator (less than 1,000 kilograms per month), and its hazardous waste 

consists primarily of spent acetone and paint waste and solvents. 

The facility has no hazardous wastewater issues; plant water is disposed 

of through the municipal sewer to the publicly owned water treatment facility. 

C. VOC/HAP Control Measures 

The facility's principal VOC/HAP control measures consist of the use of 

a wax-type styrene suppressant in its AR0P0L resin mix and the replacement of 

part of its acetone with Envirosolv 2000 (a non-HAP product). In the case of 

the styrene suppressant, sand blasting of the molded part is necessary to 

remove the residual wax from the part surface prior to secondary bonding 

operations. (Methylene chloride is the only chemical means of accomplishing 

this.) The company estimates that 6 percent of the styrene content is emitted 

from the vapor suppressed resin, versus 11 to 12 percent from an equivalent 

nonsuppressed resin. They also stated that approximately 98.5 percent of the 

vapors emitted in the sprayup operation is styrene, while the remainder is 

other volatile compounds. (What types of volatile compounds are these?) 

Finally, Mr. Picken pointed out that Envirosolv 2000 is not as effective a 

cleaner as acetone. 

V. Attachments 

Picken's Plastics supplied written materials to provide a better 

understanding of its raw materials, process operations, and emissions. These 

materials fall into three categories: 1) Material Safety Data Sheets 

(MSDS's), 2) Ohio permit applications for emitting sources, and 3) VOC/HAP 

emissions calculations as submitted to the Ohio EPA. 

Attachment 1 consists of MSDS's and two letters as follows: 

a) Altek 75-3730 0L-LVS polyester resin (Alpha Corp.) 

b) AR0P0L Q-6022-S suppressed polyester resin (Ashland) 

c) DION (R) 33-597-00 halogenated polyester resin (Reichhold) 

d) Lupersol DDM-9 MEKP catalyst (Atochem) 

e) Letter: Ashland to Picken's, 1-21-93. Confirmation that 

AR0P0L Q-6022-S is a styrene suppressed polyester. 

f) Letter: Specialty Products to Hebert, 1-29-93. VOC content of 

"Styrid" vapor suppressant. 

g) "Styrid" vapor suppressant (Specialty Products Co.) 

h) Gray gel coat (Cook Paint & Varnish) 

i) Black gel coat (Cook Composites and Polymers) 

j) Pliogrip 6600 (Ashland) 
P.7 

/ 

/ 

/

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Site Visit Report - Picken's Plastics 

Page 6 

Attachment 2 consists of the following permit applications for spray and 

trim booths, as submitted to the Ohio EPA: 

a) Resin booth B5-A 

b) Resin booth B5-B 

c) Resin booth B5-C 

d) Gel coating booth B6 

e) Trimming booth B8 (Stations S1-S6) 

f) Finishing booth B9 (2 fans, 2 stacks) 

g) Trimming and assembly booth BIO 

Attachment 3 consists of Picken's calculations of VOC content and 

emissions for the three representative resin mixes and two gel coats. 
/Collie IVl ] liO T R -.1.1.1 n ^..'J-J/J O C7.~*.V=. 

P.8 

iViieruil ijatt.cy L»ata S«X.*L 

l h e Alpha Corporation 

P. 0. Box 370 

Collierville , Tn 38017 

(901)853-2615 

Product: ALTEK 75-3730 QL-LVS 

Internal IDs ALTEK 75-3730 

CL-LV 

KSDfi Jto: ALPHA / 242 

Revision: March 20, 1989 

Date: November 5, 1991 

SECTION IV. F1R£ AND EXPLOSION DATA 

?~t~r 1 I ! ! I * \ \ '. ! 1 ! 1 ! . ! 1 1 * ! ! * ! * ! ' t ' \ \ •! * ! •*- t"i: M : i n-: :-H< :-u fr *4 

Flash Point (nethod): 88-92|F (CC) Umits: HZ. %: 1.1 OET.. %: 6.1 

KFPA FlflnmabWOonbustible TAo-iud Classification: IC 

KFPA Ftt e Hazard Syntol Oxles: Flarmability: 3 Hsalth: 2 Reactivity: 2 Special* none 

Extinguishing Madia: \rater fog, dry chatiical, foam or 00^ Autoignition Temp: 

9W|F 

Unusual fix e ox* explosion hazards: At elevated tecperatues, such as in a fir e 

condition, polymerization may take place resulting i n violent .rupture of closed 

containers. Vfear positive pressure apparatus, eye protection, and keep vapors away 

from possibl e ignition sources. 

.Special:fixe^idhtlngnrcoedittes: if electrica l equipmait i s involved, the us e of 

Handling equipment shoold be cooled by water stream if exposed t o fire . 

;;;;; ; • « !*!!!!!!!!!!?*!!*!!!!!!!?!!?!*.! ! H-:; ; i ;;;;*,! 

4-

SBCTION V. REACTIVITY DAIA 

; : 1.1 * .i i-

• i •:• > i i *4 

Material is stable . Ibzarduus polymerization nay occur . 

Oiamical Anaocipatibilities: Acids, oxidizing agents, free radical initJLators such as 

peroxides, and metalli c halides and soaps. 

Conditions t o avoid: sunlight, open flanes, contamination, and prolonged sLurage 

above 75]. 

Hazardous deoOnposition Products: carbon n-onoxide. carton dioxide , and low rolecular 

•weight hydrocarbons. 

•s t is.::::: i: n :::'.: '.'.'.'.'.'.'.'.'.'.'.'.'.'. ........ . 

SECTlCt- VT. HEALTH HAZARD INFORMATION 

iiiii i 

This product is considered a -possible carcinogen by IARC.* 

Suooary of risks: Causes irritation t o throat, eyes, 6kin and nose. Harmful i f 

inhaled. 

Madiaal conditions vhich may be aggravated by contact: Kay aggravate pre-e> 

respiratory ana skin 

target organs: CNS, respiratory system, lungs, eyes and skin. 

Prinsiiy entry route(s): inhalation, ingestion, contact. 

iers. 

Page 2 — HEALTH HAZARD INFORMATION continues on pago. 3 Page 2 

U0V- 5-9 1 TUE 15:4 7 ? e l p' 

HCV- 5-9 1 TUE mZ'.Al ' v . ?• ZI 1 ?• '• ' P . M ' 

7 
P.9 

ATTACHMENT 1 

The Alpha Corporation 

P. 0. Box*370 

Collierville , Tn 38017 

(901)853-2615 

Pnxluct: ALTEK 75-3730 CL-LV5 

Internal IDi ALTEK 75-3730 

CL-LV 

*EDS NJ : AIJ'HA / 242 

Pevisinn: Parch 20. 1989 

Date: Novarber 5, 1991 

National Paint 

and Coatings 

Association 

Hazardous Material 

Identif ication 

System 

1 

1 

1 

4-*-*-

4-HHEALTH HAZARD j 

FLAMXABTT.TTY HAZARD j 

RFACT1VTTY HAZARD j 

PERSONAL PROTECTION | 

2 

3 

2 

I 

i 

i 

1 

4-

S.ECTION I. KATERIAL IDENTIFICATION 

Tcade/fcaterial Name: ALTEK 75-3730 OL-LVS 

Description: Diacid/Glycol condensate 

CAS: mixture Trade Secret Register: N/A 

Chemical N&ae* Pr>1*YF>st*»*r P<=>fi-in 

Manufacturer*: Alpha Resins Corporation Phone: (901)853 2615) 

SECTION II. IN3*ED1EN1S AND HAZARDS ! 

Ingredient Name: 

Styr*eue 

Alpto Msthyl Styrene 

SARA 313 INFDRMATl V: 

the reporting reoand ReauthorizatI 

CAS Number: 

100-42-5 

98-83-9 

I-taroent: 

42-50%* 

0-3%* 

Ejrrjoeuxe Limits: 

50 ppm TWA: 100 Pitt 

-0 ppm TWA: 100 ppm 

.s product contains the above substance which is subject t o 

j ol section 313 of Titl e III of the Superfund Amendments 

jf 1986 and 40 CFR Part 372. 

* weight Percent. 

4-

SBCTION III. PHYSICAL UATA 

Appearance & Odor; Visoous Liquid with a Sweet Pungent Odor. 

.Boiling point: 293lF Specific gravit y (ao=ll: 1.0 - 1.1 

Vapor pressure: <4.5 vrtOq *-=_I*--*_\*IL_.,_I._ .... 

Vfeter s^ubiHt y (%): very sligh t 

Vapor density (air^l): 3.6 ^ 

cavit y (ItO=l): 1.0 

•Halting Joint: N/A 

Page 1 Post-It" brand fax transmittal memo 7ip1 |t»« pag-** » ££ 

TefH,\K<^>-ur 

C*pt. 

*»1 * 

TZfjLLidmS 

Co 

P.'IOOf » 

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NOV- 5-5 1 TUE 15:4 6 

HOV- 5 -•'-•] T..-F IT:**? 

91? 1 S 5 * 1 

Page 1 

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P.10 

Material Safety Data Sheet 

The Alpha Corporation .Product: ALTEK 75-3730 OL-LVS 

n .J' °:-if° x IZ0TMTM.. Internal ID: ALTEK 75-3730 

.KSDS NO: ALPHA / 242 

Itevisicn: March 20, 1989 

cate: Jtoveriber 5, 1991 

i •« i i . . J . i i 

HEALTH HAZARD DtTCRMATlCN continue d from pag e 2 •••••• 

: : ••-'- :::! :

 • •••:::: : iv-H-:::;:::::::::*.: { :*;•*•;: : H-H-H:;;:; : ;::::!*•-> * 

Acute effects: May irritat e eyes, nose, tliroat, and skin. 

Chronic effect(e)t *fay cause victim to feel drugged, sleepy o r become unconscious. 

Repeated skin contact nay cause rash. Kay affect the brain o r nervous system, 

causijig dizziness, headache or nausea. Reports have associated repeated and 

prolonged occupational overexposure to solvents with pernanent brain and nervous 

system dairage. Intentional misuse by deliberately concentrating and inhaling the 

contents may be harmful or fatal. 

Signs & synptass of overexposure: 

Eye contact: Causes irritatio n to the eyes. 

Skin contact: May cause irritation t o the skin. 

Inhalation: May irritat e eyes, nose aivd throat. May fee l drugged, sleepy, or unconcious. 

Ingestion: May cause victim t o become vveak and unsteady. 

First aid: 

iftaterial.) 

S u n contact! Wash exposed skin -with soap and vater. Get medical 

attention if irritatio n developes. Remove contaminated 

clothing, shoes, and thoroughly clean before reuse. 

Inhalation: Move exposed person(s) t o fresh air. Get medical 

attention. 

Ingestion: DO N3T induce vomiting. Call Physician innediately. 

*For hazard comnunication purposes under OSHA Standard 29 CTR Part 1910.1200, styrene 

is listed as a possible carcinogen ty IARC. Neither the data from various long-term 

animal studies nor from epidemiology of workers exposed to styrene provide an 

adequate basis t o conclude that styrene is carcinogenic. 

Pagp 3 — MSD6 242 continues on page 4 — Page 3 

NOV- 5-9 1 TUE 15:4 ? ?C<! S5? 152 5 
Material Safety Data Sheet 

p.11 

The Alpha Corporation 

P. 0. .BoxNr/Q 

Collierville , Tn 38017 

(901)853-2615 

.ProductJ .ALTEK 7S-3 

Internal ID: ALT OM 

MSDS tto: ALPHA / 242 

Revision: March- 3«72ia&a 

Date: Noveiber 5f°^|i B 9 

m 

+-H-

! SECnCNvii! spiii' 'LEAK'AND DISJ-CSAL 'wsixiiixJKis' ""•••••••*•**"•} 

tpiuiiii,;, 1, I.I,.,. 1 ••—•• . i i i i . . . i . I '. : ; ! : . . ! 1 t ... . . ! } . i ... » t ««....> . 1 

Spill / I^aak procedures: Remove al l sources of ignition, ventilat e area. Epgyent 

•material from entering drains. Absorbent should Be vermicalite , dry sara'& garfh* 

Stall Spil l - Soak up vit h absorbent and scoop into drums. 

Large Spil l - Dike and pump int o drums. 

•teste sanaganent / Disposal: Dispose of according t o local, stat e and federal 

regulations. -eaerar 

3 

1 SECTION VIII . SPECIAL l^OTBCriON INFCJRMATION 

. . . I . . I 

Personal protective equipment: 

Goggles: Use chemical goggles. 

Gloves: Use gloves of rubber or other resistant material. 

Reepiratarj Chemical cartridge respiraLor with NIOSH/OSHA approved organic XBDor 

cartridge t o 400 ppm. At exposures above 400 ppm use an '§§gjp ^P 0* 

Other: Use chemical resistant aprons or coats t o avoid skin contact. 

Workplace considerations: 

VentUation: loca l exliaust i s preferred. Mechanical ventilation Is a 

U.se explosion proof eqoipmenL. 

•Safety stations: 

Safety showers end eye wash stations ajre recommended. 

Contaminated equipment: 

Clean contaminated equipment with an appropriate solvent 

storage. - •pis? fe 

I SECTION IX. SPECIAL PRECAUTIONS 

Storage segregation: Store in a cool dry place away frcm incctnpatable figfcgf j-fljg • 

Special handling / storage: Store in an area below 75IF and out of direc t SunJiflbt. 

Keep frcm heat, spark, anA sroking areasT^fr^ 1 1 ^ • 

containers may be hazardous. uifrcy 

tt-a-iiraaering controls: fcjuipment should be grounded during transfer and non-s, 

^ ^ CArr|>s should be used. " lu-

ni~~l 

Pag-e 4 SP.BCIAL pRECAunac continues on page 5 

(0 
P.12 

11/05--31 13:42 HLFHH RESINS CCf-P. 005 

Material Safety Data Sheet 

Tbe Alpha Corporation 

P. 0. Box*370 

Collierville, Tn 38017 

(901)853-2615 

Product: ALTER 75-3730 OL-LV5 

Interna l ID: ALTEK 75-3730 

Or-LV 

MSDS Ifo: ALPHA. / 242 

Revision: March 20 

Date: November 5 fisli 89 

+-s- .•-T J.I. I •T-H i! : 

SPECIAL PPECfiim.OLjS oori^ued f rem page4 4 

-.i. i ::i::i:::: l 

Other precautions: Do not transfer to unlabeled bottles or containers. 

DOT Class: Flammable Liquid UN Register: UN-1866 

Prepared/revised by: ROBERT RAUARD 

March 20, 1989 

The information contained herein is based onthe data available t o us and is believed 

tb be oorrect. Uo warranty, exoressed or implied, is made requarding the accuracy of 

this data or the results t o be obtained from the use thereof. Alpha Resins 

Corporation assures no responsibility for .injury from the use of the product. 

Page 5 Erxi of MSDS 242 Pi-a 

ll 
P.13 

JiWJ Lit-z-,..U/ "ATTENTION DIRECTOR OF PURCHASING: All shlpmerv.s 

——^ shall be Governed by the Terms and Conditions on th< 

..•a**---**^ £sqH| ^ K m rwPMTroi revVjBe- side. Acceptance of delivery shall be deemed 

have 

ACU I AMn PHPMTrAi reversa-side. Acceptance of delivery shall be de< 

WS, SZ TM- *"i , **,•*$•*¥*• Pl,fcuch Provisions. No other terms shall hland 3IDIARY OF ASHLAN^^p3nieS^K^Itlno signed by Seller. 

 Chernical. Inc. SUBS _ 

iDsidiary of Ashland Oil. Inc. p.o . BOX 2219 , COLUMBUS/'OHYO " 4321 6 

(614) 889-3333 

AROFOL Q 6022 S ENTERED JAU 10 19S^ABE| A 

HIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) 

24-HOUR EMERGENCY TELEPHONE: 1-800-ASHLAND OR 1-800-274-5263 

:0DUCT NAME: AROPOL Gl 6022 S 

DATA SHEET NO: 0260149-001 

PREPARED: 10/04/91 

SUPERSEDES: ( N/A ) 

SECTION I-PRODUCT IDENTIFICATION 

ENERAL OR GENERIC ID: UNSATURATED POLYESTER RESIN 

OT HAZARD CLASSIFICATION: FLAMMABLE LIOUID (173.115) 

SECTION II-COMPONENTS 

;F PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. 

SEE DEFINITION PAGE FOR CLARIFICATION 

INGREDIENT */. (BY WT) NOTE 

POLYESTER RESIN * 50-55 ( 1) 

3TYRENE -46 (2) 

CAS #: 100-42-5 PEL: 50 PPM TLV: 50 PPM 

( 1): PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL 

* 2): ACGIH /OSHA SHORT TERM EXPOSURE LIMIT (STEL) FOR STYRENE MONOMER IS 100 

PPM. NIOSH RECOMMENDS A LIMIT OF 50 PPM, 8-HOUR TWA, 100 PPM 15 MINUTE 

CEILLINE. 

THIS CHEMICAL IS SUBJECT TO THE REPORTING REOUIREMENTS OF SECTION 313 OF 

SARA TITLE III. 

K THE SPECIFIC CHEMICAL NAME OF THIS COMPONENT IS BEING WITHHELD AS A TRADE 

SECRET. 

|2> 
yiZStt i -Um Z f jm,.'<Lmm. l 

..shlahd Chemical. Inc. 

Subsidiary ol Ashland Oil. Inc. 

P.14 

LUimriUcD ON -ATTENTION DIRECTOR OF PURCHASING: All shipments 

shall be Governed by the Terms and Conditions on the 

reverse side. Acceptance of delivery shall be deemed 

Annom n *«-,*->-> acceptance of auch provisions. No otner teirorahall have ARUPUL G 60-.^e | fectun | ess , nwrtt , nfl8lgne< , bySe „ e f FACES Z 

SECTION 111-PHYSICAL DATA 

PROPERTY REFINEMENT MEASUREMENT 

FOILING POINT FOR COMPONENT( 46V.) 

,'APOR PRESSURE . 

SPECIFIC VAPOR DENSITY AIR = 1 

SPECIFIC GRAVITY 

-'ERCENT VOL AT I LES " 

IVAPORATION RATE 

APPEARANCE 

3TATE 

-ORM 

293.40 DEG F 

( 145.22 DEG C) 

-3 760.00 MMHG 

FOR COMFONENT( 

AIR = 1 

i 

• 

467.) 4.50 MMHG 

6 6B.00 DEG F 

( 20.00 DEG C) 

3.6 

1.052 - 1.088 

€ 77.00 DEG F 

( 25.00 DEG C) 

45-507. 

SLOWER THAN ETHER 

HAZY BLUE 

. LIQUID 

HOMOG SOLN 

SECTION IV-FIR E AND EXPLOSION INFORMATION 

•LASH POINT 

( 

.73.0 -

22. 8 -'• 

100. 0 DEG F 

37. 8 DEG C) 

IXPLOSIVE LIMIT (LOWEST VALUE OF COMPONENT) LOWER 1.17. UPPER .- 6*17. 

IXTINGUISHING MEDIA: REGULAR FOAM OR WATER FOG OR CARBON DIOXIDE OR DRY 

CHEMICAL 

HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:, CARBON DIOXIDE 

AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC. 

rIREFIGHTIN6 PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL 

FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING 

FIRES. 

SPECIAL FIRE & EXPLOSION HAZARDS: VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL 

ALONG THE GROUND OR MAY BE MOVED BY VENTILATION AND IGNITED BY PILOT 

LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKINS, ELECTRIC MOTORS, STATIC 

DISCHARGE, OR OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL 

HANDLING POINT. 

ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND 

TANK TRUC.£?} SHOULD BE GROUNDED AND/OR BONDED WHEN MATERIAL IS TRANSFERRED. 

-''•.T"' VZZ f'ZLV-.-::- CR CUTTjf.'C TCF.C.H D'.-i OT: t.'E-.R DPl'M (E7E*J EMPTV' FETC A'JSE 
P.15 

• - --iri E^'UiiliCBi CONTINUED ON"ATTENTION DIRECTOR OF PURCHASING: All shipments 

E'^l_ ! ahall be governed by the Terms and Conditions on the 

JffZk&P1 reverse side. Acceptance of dellvwy shall be deemed 

-^____ acceptance of auch provisions. No other terms. JbaJI have 

•^j^ndChenriiCal.lnc. AROPOL Q 6022effect unless In writing signed by Seller. FA&t. -i 

jubsidiaryot Ashland Oil. Inc. , ' __ __ 

SECTION IV-FIRE AND EXPLOSION INFORMATION (CONTINUED) 

POLYMERIZATION WILL TAKE PLACE UNDER FIRE CONDITIONS. IF POLYMERIZATION 

OCCURS IN A CLOSED CONTAINER, THERE IS A POSSIBILITY IT WILL RUPTURE 

VIOLENTLY. COOL STORAGE CONTAINER WITH WATER, IF EXPOSED TO FIRE. 

-FPA CODES: HEALTH- 2 FLAMMABILITY- 3 REACTIVITY- 2 

SECTION V-HEALTH HAZARD DATA . 

I PERMISSIBLE EXPOSURE LIMIT: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. 

E EFFECTS OF ACUTE OVEREXPOSURE: 

-VFQ"~CAN~CAUS E SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. 

3KIN - PROLONGED OR REPEATED CONTACT CAN.CAUSE MODERATE IRRITATION, DEFATTING, 

if 

WATHIN G - EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY 

IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING DIZZINESS, WEAKNESS, 

FATIGUE. NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS, AND EVEN DEATH. 

SWALLOWING - CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA,. VOMITING, AND 

.j, DIARRHEA. '.".. 

y\ -IRST AID: .., . . ' 

Tp'rnTsKIN- THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE. 

CONTAMINATED CLOTHING.- LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. 

~~ IF IN EYES: FLUSH WITH LARGE AMOUNTS OF WATER,.LIFTING UPPER AND LOWER LIDS 

nr-CASIONALLY, GET MEDICAL ATTENTION: 

~ rr FALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET, AND GET MEDICAL 

-

F ATTENTION. ASPIRATION OF.MATERIAL INTO THE LUNGS DUE TO VOMITING CAN 

CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. 

TF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS 

DIFFICULT.ADMINISTER OXYGEN." IF BREATHING HAS STOPPED, GIVE ARTIFICIAL 

no RESPIRATION. KEEP PERSON WARM, QUIET, AND GET MEDICAL ATTENTION. 

J.L5 • 

Id PRIMARY ROUTE(S) OF ENTRY: . . 

°" INHALATION, SKIN CONTACT 

^ EFFECTS OF CHRONIC OVEREXPOSURE: • ' ' 

'rf, ^INTERNATIONA L AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED STYRENE 

111 IN GROUP 2B (POSSIBLY CARCINOGENIC TO HUMANS). THIS CLASSIFICATION IS NOT 

.". F.ASED ON ANY SIGNIFICANT NEW EVIDENCE THAT STYRENE MAY BE CARCINOGENIC, 

'^ WIT FATHER ON A REVISED DEFINITION FOR GROUP 2B AND CONSIDERATION OF NEW 

?-° DATA ON STYRENE OXIDE. A NUMBER OF LIFETIME ANIMAL STUDIES WITH STYRENE 

n*? INCLUDING THOSE CONDUCTED IN THE NCI BIOASSAY PROGRAM HAVE NOT. SHOWN 

i l3' STYRENE TO BE CARCINOGENIC. . 

rf] OVEREXPOSURE TO STYRENE HAS APPARENTLY BEEN FOUND TO CAUSE THE FOLLOWING 

-r!". EFFECTS IN LABORATORY ANIMALS: LIVER ABNORMALITIES, KIDNEY DAMAGE AND 

/r'"1 L'J'.T- PAMA ^ 

/s 
P.16 

irssnl LifQffiicsi 

Ashland Chemical. Inc: 

SuDsidiany o' Ashland Oil. Inc 

* *r+C- i \*s ••& ij 

CONTINUED ON-^TTENTioA DIRECTOR OF PURCHASING: All ahlpments 

shall be governed by the Terms snd Conditions on the 

reverse aide. Acceptance of delivery ahall be deemed 

Acnoni n /.^oo8*cPeP

tar,C€ o f

 * u c h provisions. No other temw.ahaJI haye AROPOL Q 6022e ^ unles8lnwr|tln

,

g s ^ r>e< , bvSeI|er # • PfiBE": Tf 

SECTION VI-REACTIVITY DATA 

HAZARDOUS POLYMERIZATION: CAN OCCUR — AVOID EXPOSURE TO EXCESSIVE HEAT, 

PEROXIDES AND POLYMERIZATION CATALYSTS. 

STABILITY: STABLE 

INCOMPATIBILITY: AVOID CONTACT WITH:, STRONG ALKALIES., STRONG MINERAL ACIDS. 

SECTION VII-SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: 

SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR OTHER 

ABSORBENT MATERIAL AND TRANSFER TO HOOD. 

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING PILOT 

LIGHTS, ELECTRICAL SPARKS), PERSONS NOT WEARING PROTECTIVE EQUIPMENT. • 

SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. 

STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP 

LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, 

EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO 

CONTAINERS. 

WASTE DISPOSAL METHOD: 

SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT 

TIME FOR VAPORS TO COMPLETELY CLEAR HOOD DUCT WORK. DISPOSE OF REMAINING 

MATERIAL IN ACCORDANCE WITH APPLICABLE REGULATIONS. 

LARGE SPILL: DESTROY BY LIQUID INCINERATION IN ACCORDANCE WITH APPLICABLE 

REGULATIONS. , . . 

CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH 

LOCAL, STATE AND FEDERAL REGULATIONS. 

SECTION VIII-FROTECTIVE EQUIPMENT TO BE USED 

RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY 

COMPONENT IS EXCEEDED (SEE SECTION II), A NIOSH/MSHA APPROVED AIR 

SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL 

CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS 

(NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY 

EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE 

IMPLEMENTED TO REDUCE EXPOSURE. 

VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) 

VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). 

.-ROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, POLYVINYL ALCOHOL 

EYE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS 

ARE ADVISED; HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY 

GLASSES. (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) 

.TTHER PROTECT 1 ^ EQUIPMENT: NORMAL WORK CLOTHING COVERING ARMS AND LEGS. 
P.17 

' £*#g ImlXUiiliCUl CONTINUED 0K-£nE£n0ff DIRECTOR OF PURCHASING: Al^pZ u 

&'*-&**" L^iLS6 9°TM*TM*

 bX •*• Terms and Conditions on the 

^ — — ?,^BrTM*-. A «*P"nce of deliver ahall be deemed 

Ashlano Chemical, Inc. AROPOL Q 60 ,''»!^l!SP e °.f 8UCu

h

, PwWont. No other terms ahajl have 

Subsidiary of Ashland Oil. Inc.

 6t>—effect unless In wrhlng signed by Seller. PtffeiE: 5 

SECTION IX-SPECIAL PRECAUTIONS OR OTHER COMMENTS 

CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED 

CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID) ALL 

HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED 

ZXPOSURE TO AEROSOLS AND MISTS WHEN MATERIAL IS SPRAYED MAY PRESENT A GREATERRISK OF INJURY FROM COMPONENTS BECAUSE HIGHER CONCENTRATIONS ARE IN THE 

ATMOSPHERE THAN RESULT FROM VAPOR ALONE. PROVIDE ADEQUATE VENTILATION AND 

IF NECESSARY, USE RESPIRATORY PROTECTION.

 RN D 

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT 

WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT RECIPIENTS 

ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS 

CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. 

e 

i7 
P.18 

MATERIAL SAFETY DATA SHEET 

Information Telephone No.. (BOO) 874-1807 In Nonh Carolina Coll. (800) 342-7201 

REICHHOLD CHEMICALS. INC. 

PO.Box 13582 

Research Triangle Park 

Durham. NC 27709 

ALL CHEMICAL EMERGENCIES 

1-800-424-9300 

Issue Date: 05/13/91 Page i 

5SsxxxxBsseBsxssssxxxxssssesxsssassessBsxsxsBBSSBEEBSB«B» « 

SECTION I - PRODUCT IDENTIFICATION 

Product Code: 

Trade Name: 

Formerly: 

Product Class: 

C.A.S. Number 

HMIS Rating: 

33-597-00 

D10N(R) 33-597-00 

Koppers DION FR 6604T 

Unsaturated halogenated polyester 

Mixture 

Health « 3 Fire * 2 Reactivity 

!s:::c:e::EStc£c:E::e:c:££;ictss:s=:=a::x:c>c:t:=issc:Escscec:etisiecacste 3 

SECTION II - INGREDIENTS 

Ingredients CAS « 

Ueight Exposure 

max . X Limits 

Polyester resin 

Styrene Monomer 

Epichlorohydrin 

Methylene Chloride 

Proprietary 

100-4E-S 

106-89-8 

75-09-E 

80.0 None assigned 

40.0 50.0 ppm 

0.50 S.O ppm 

1.5 50.0 ppa 

ee xssssssssi :sssxxsssssssxsssESSssssESXSXKBBBSSBSSSSBBBBSSBBCBBBBSBSBsssB C 

SECTION III - PHYSICAL DATA 

Boiling Point 

Volatile '/.• 

Evap. Rate: 

Appearance: 

£95 Deg. F. 

40 by weight . 

Slower than n-Butyl Acetat e 

Liquid with pungent odor . 

Vapor Density: Heavier than Air. 

Specific Grav: 1.15 - 1.20 

BBBSSSSXSSSSSSSSSBESSSSSSSSSSSSSSSSSSBBSSSSSSSSSSSSSSSSSSBBESEBBSBBEBBSSSBBB I 

SECTION IV - FIRE AND EXPLOSION HAZARD DATA 

Flammability Class: IC Flash Point: 85 Deg. F, 

-EXTINGUISHING MEDIA: 

Water spray, foam, dry chemical, carbon dioxide or any 

Class 6 extinguishing agent. 

-SPECIAL FIREFIGHTING PROCEDURES: 

Firefighters and others exposed to vapors or products of 

combustion should wear self-contained breathing apparatus. 

Equipment should be thoroughly decontaminated after use. 

-UNUSUAL FIRE ft EXPLOSION HAZARDS: 

At elevated temperatures, such as in a fire, polymerization 

may take place. If polymerization takes place in a closed 

container, there is the possibility of violent rupture.of 

the container. Product vapors may form an explosive mixture 

in air. 

LEL : 1.1 

Th'n information it lurnithed without warranty, representation, inducement or license ol any kind, ctcept that it il accurate to the beat ol Reichhold Chemicals. Inc.'t 

knowledge, or obtained Irom source! believed b> Reichhold Chemical!. Inc. to be accurate, and Reichhold ChemicaH. Inc. does not assume any lege' reiponiib'lity lor 

ust or reliance upon tame Customers are encour»sed to conduct their own tests fie lore using any product, read its label. 
P.19 

«• U L I U O 0 o 

MATERIAL SAFETY DATA SHEET 

Information Telephone No.: (600) 874-1807 In Nonh Carolina Call: (800) 342-720 1 

REICHHOLD CHEMICALS. INC. 

PO Box 13582 

Research Triangle Park 

Durham. NC 27709 

ALL CHEMICAL EMERGENCIES 

1-800-424-9300 

Product Code: 33-597-00 

Issue Date: 05/13/91 Page c 

B S B*:SBSKSESBSCB S = ESESBEBSSSEBESESECSES=KSSXESSSEeBBBSBBEKBBSBBSBBBBBBEEBBBBBBB B 

SECTION V - HEALTH HAZARD DATA 

-PERMISSIBLE EXPOSURE LEVEL: 

OSHA PEL end ACGIH TLV for styrene are both 50 ppm for an 8-hour 

Time Weighted Average (TUA). The OSHA and ACGIH Short Term 

Exposure Level (STEL) are 100 ppm for a 15-minute period. 

Exposure to styrene may exceed the STEL during a 15-minute 

period (no ceiling for brief exposures), however the average for 

a single STEL period must not exceed 100 ppm. 

The OSHA PEL and ACGIH TLV for epichlorhydrin are Eppm for an 

8-hour TWA. Skin hazard noted. 

The ACGIH TLV for methylene chloride is 50 ppm for an 8-hour 

TUA. The OSHA PEL for methylene chloride is 500 ppm for an 

8-hour TUA. OSHA has established a 1.000 ppm acceptable ceiling 

concentration and a 8,000 ppm acceptable maximum peak for a 

duration of 5 minutes in any 2 hours. The OSHA limits for 

methylene chloride are currently being revised under OSHA 6(b) 

rulemaking. 

-EFFECTS OF OVEREXPOSURE: 

SKIN: Prolonged or frequent contact may cause defatting and 

dryness of the skin with resultant irritation and possible 

dermatitis. Styrene may be absorbed through the skin in toxic 

amounts. 

EYES: Kay cause irritation. Liquid splashes may result in more 

serious injuries. Hay cause lachrymation (tears). 

INHALATION: Vapors may cause mucous membrane irritation and 

upper respiratory tract discomfort. High concentrations may 

result in headache, nausea, insensibility and other central 

nervous system effects. Repeated exposure to high concentrations 

may cause liver and kidney damage. 

INGESTION: May cause gastrointestinal disturbances, pain and 

discomfort. 

Epichlorohydrin may be absorbed through the skin in harmful 

amounts. Repeated overexposure to epichlorhydrin may cause 

allergic skin reactions. Overexposure to epichlorohydrin may 

cause harmful effects to liver and/or kidneys. The effects of 

epichlorhydrin overexposure may be delayed. 

Overexposure to methylene chloride can raise the level of carbon 

monoxide in the blood causing cardiovascular stress. 

-FIRST AID: 

SKIN: Uash with soap and water. 

EYES: Flush with copious amounts of water for 15 minutes. 

Seek immediate medical aid. 

INHALATION: Renove victim from exposure. If victim is unconscious, administer artificial respiration and/or oxygen as 

(cont.) 

This inlormalion is lumished without warranty, representation, tnducement or license ol any kind, cicept lhat h it accurate to the best ot Reichhold Chemicals. Inc.'t 

' knowledge or obtained Irom sources believed by Reichhold Chemicals. Inc. to be accurate, and Reichhold Chemicals. Inc does not assume any legal responsibility loi 

use or tel.ance upon seme Customers are encouraged to conduct the!' own tests. Eelo'c using any product, read hs label. 

/ a 
P.20 

MATERIAL SAFETY DATA SHEET 

Inlormalion Telephone No.: (800) 874-1807 In Nonh Carolina Call: (800) 342-720 1 

REICHHOLD CHEMICALS. INC. 

PO 8ox1358 2 

Research Triangle Park 

Durham. NC 27709 

ALL CHEMICAL EMERGENCIES 

1-800-424-9300 

Issue Date: 05/13/91 

Product Code: 33-597-00 

:SB CSSS S S S S BB S B SE E B'S SSBEe E CES S BSEBBCBEEECSSBS ! 

SECTION V - HEALTH HAZARD DATA (cont. ) 

Page 2 

iccccacccc i 

-FIRST AID: (cont.) 

needed. Seek medical aid. 

INGESTION: DO NOT INDUCE VOMITING (aspiration haierd). Seek 

immediate medical aid. 

-PRIMARY ROUTE(S) OF ENTRY: 

Inhalation and Skin Absorption. 

-CARCINOGENICITY: 

The International Agency for Research on Cancer (IARC) has 

classified styrene as possibly carcinogenic to humans (class 

2B>. The IARC 2B classification is not based on significant new 

evidence that styrene might be a carcinogen, but on a revised 

IARC classification scheme and new data on styrene oxide. 

Epichlorhydrin is listed as a carcinogen by the National 

Toxicology Program (NTP) and the International Agency for 

Research on Cancer (IARC). 

Methylene chloride is listed as a potential carcinogen by IARC 

(class EB) and NTP. 

ESSE SSS S EC S SSSS S BS E SSI rscssss s rSESSSSSSCBEBEBEEBBBBC : 

SECTION VI - REACTIVITY DATA 

txD Stable 

Cxi Hay occur [ ] Will not occur 

STABILITY: t 3 Unstable 

HAZARDOUS POLYMERIZATION: 

-INCOMPATIBILITY: 

Strong acids and oxidizing agents. 

-CONDITIONS TO AVOID: 

Heat and direct sunlight. 

-HAZARDOUS DECOMPOSITION PRODUCTS: 

Heating of this material to decomposition may cause 

the emission of irritating, acrid fumes. 

SECTION VII - SPILL OR LEAK PROCEDURES 

-STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: 

Remove all sources of ignition. Ventilate area. Absorb spill 

with an absorbent material such as sawdust, vermiculite or 

sand and place in a closed container. If large spill, dike 

the area to prevent this material from entering water systems or 

sewers. 

This materia l contains the following ingredients which, i f 

spille d or released in quantitie s equal to or greater than the 

Reportable Ouentity (RQ), are subject to the reporting require -

ments of CERCLA and/or SARA (40 CFR Parts 302 i 355): 

Styrene Monomer RQ Value * 1000 lbs . 

(cont.) 

thi! intormation is furnished without warranty, representation, inducement or license ol any kind, except that h is accurate to Ihe best ol Reichhold Chemical!. Ince 

knowledge, or obtained Irom sources believed by Reichhold Chemicals. Inc. to be accurate, and Reichhold Chemicals. Inc does nol assume any leoa! respo-uibility lor 

use or reliance upon tame Customers are encouraged to conduct their own tests Belo't using any product, read hi labe' 

1.& 
P.21 

v. V L i U 0 O O 

MATERIAL SAFETY DATA SHEET 

Inlormalion Telephone No. (800) 874-1807 In Noah Carolina Call: (800) 342-720 1 

REICHHOLD CHEMICALS. INC. 

PO Box 13582 

Research Triangle Park 

Dpjrham. NC 27709 

ALL CHEMICAL EMERGENCIES 

1-800-424-9300 

Product Code: 33-597-00 

Issue Date: 05/13/91 Pag* 4 

aESEBSEESSSS S ESS E SEBE E ESSE S SS E BB S ES S B E SSS S EBB S SS B BB S BBEEBBBSBSSSB E EB B SEBBBEBBBE B 

SECTION VII - SPILL OR LEAK PROCEDURES (cont.) 

-STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: (cont.) 

Epichlorohydrin RQ Value = 100 lbs. 

Methylene Chloride RQ Value * 1000 lbs. 

-UASTE DISPOSAL METHOD: 

This material has been tested and found to have a flash point 

below 140 F. If discarded, this material and containers should 

be treated as hazardous wastes based on the characteristic of 

ignitability as defined under the federal RCRA regulations 

(40 CFR £61). Disposal of this material and its container, 

requires compliance with applicable labeling, packaging, and 

record keeping standards. Extreme care should be taken to 

ensure that it is disposed of only in a facility permitted for 

disposal of hazardous wastes. 

For further information, contact your state or local solid waste 

agency or the United States Environmental Protection Agency's 

RCRA hotline (1-800-424-9346 or 202-3S2-3000). 

aESBSBSSSEBSSSSSS&SBSSSSSSSSSSSSSSSB&SBeSSSBSSSSSSBSSSKSBSBSSSSBSSSSBSBSKBSSBBS X 

SECTION VIII - SPECIAL PROTECTION INFORMATION 

-RESPIRATORY PROTECTION: 

A canister-type respirator oust be worn to prevent the inhalation of vapors or spray mists when the TLV or PEL ls exceeded. 

-VENTILATION: 

General ventilation is required during normal use. 

Local ventilation may be required during certain operations 

to keep exposure levels below the TLV listed in Section II 

of this data sheet. 

-PROTECTIVE GLOVES: 

Uear appropriate impervious gloves to prevent skin contact. 

-EYE PROTECTION: 

Uear face shield or chemical goggles. 

-OTHER PROTECTIVE EQUIPMENT: 

Uear protective clothing to prevent skin contact. 

Eye wash station and safety shower should be available. 

KSSSS&SSSSSSSSSS&BBSSSSSSSSSBSSSSSSSSSSSSSSSSSSSSSSSSSSBBSSS&SSSSSBBSBSBSSSSSS S 

SECTION IX - SPECIAL PRECAUTIONS 

-PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: 

Avoid storage above 100 Deg. F. Avoid prolonged or repeated 

skin contact. Avoid inhalation of heated vapors or spray mists. 

This inlormalion it lumished withoul warranty, representation, inducement or license ol any kind, except that h is aceurata to the best ol Reichhold Chemicals. Inc'a 

knowledoe. or obtained horn sources believed by Reichhold Chemicali.Inc to be accurate, and Reichhold Chemicals. Inc. does not assume any leoa! responsibility lor 

use or reliance upon sami Cust: -r.c. are encouraped to conduct thtir own lest! 6tlc"t usinp any produci read its label. 

n.\ 
P.22 

fc 0 2 10 5 5 e 

MATERIAL SAFETY DATA SHEET 

Inlormalion Telephone No: (800) 874-1807 In North Carolina Call: (800) 342-7201 

REICHHOLD CHEMICALS. INC 

PO.Box 13582 

Research Triangle Park 

Durham. NC 27709 

ALL CHEMICAL EMERGENCIES 

1-800-424-9300 

Product Code: 33-S9T-00 

Issue Date: 05/13/91 

SECTION IX - SPECIAL PRECAUTIONS (cont 

Page 

) 

-OTHER PRECAUTIONS: 

Avoid improper additio n of promoter and/or catalyst . A promoter 

and catalys t used wit h thi s product should always be mixed 

separatel y wit h th e product and must never be mixe d together. 

:sssss t :sssssssssss i 

SECTION X - SUPPLEMENTAL INFORMATION 

-REGULATORY INFORMATION: 

SCAQMD Rul e 1162 establishes specifi c process, control , 

housekeeping , and recordkeeping requirement s fo r fabricatio n 

operation s using polyester resi n materials. I t l s th e 

responsibilit y of the fabricato r t o ensure compliance wit h 

these requirements. 

Styren e i s NOT currentl y liste d as a carcinogen by California' s 

Saf e Drinkin g Water and Toxi c Enforcement Act o f 1986 

(Propositio n 65) . 

Epichlorhydri n i s liste d by th e stat e of Californi a as a 

substance known t o cause cancer. The Californi a Safe Drinkin g 

Uater and Toxi c Enforcement Act of 1986 (Propositio n £5) 

requires that clea r and reasonabl e warning be give n befor e 

exposin g any Individual t o epichlorohydrin . 

Methylen e Chlorid e (als o know as dichloromethane) i s liste d by 

by th e stat e of Californi a as a substance known t o cause cancer. 

The Californi a Saf e Drinkin g Uater and Toxic Enforcement Act of 

1986 (Propostio n 65) requires tha t clear and reasonabl e warning 

be give n befor e exposing any individua l t o methylen e chloride . 

-SARA HAZARD CLASSIFICATION: 

Thi s materia l has been categorize d as having th e followin g 

hazard(s) as define d by SARA Titl e II I regulation s (40 CFR 370) 

acute, chronic, fire , reactive . 

-SARA SECTION 313 LISTED INGREDIENTS' 

The followin g ingredient s i n thi s 

reportin g requirement s of sectio n 

[see Sectio n I I fo r percentage o f 

Styren e monomer (100-42-5) 

Epichlorohydri n (106-89-8) 

Methylene chlorid e (75-09-2) 

-DOT PROPER SHIPPING NAME: 

Resin Solutio n 

-UN NUMBER: 

UN1866 

material ar e subject t o the 

313 or SARA and 40 CFR 372 

ingredient(s)3 : 

Thii information it lumished without warranty, represenution. inducement or license of any kind except that h is accurate to the besi ol Reichhold Chemi:a!< Inct 

knowledoe. or obtained Irom sources believed by Reichhold Chemicals Inc to be accurate, end Reichhold Chemicals. Inc does not assume any leoa! respns'-. "lity lo* 

uif o-retienc* u^on s?~i« Customers e'f encojrjpei ic coidjr; t*.ei* own t€ it! 6; !r-r» uS'if an» •{-••oiuct mi r.; lat-r! 

<\/L 
P.23 

*w.... 

Atoehen Cedet 1 » 

TRADENAME 

CHDUCAL NAME ... . 

•MOLECULAR FORMULA 

.lUPERSOL POK-S 

..Methyl EthgT Ketone Peroxide filature e f C.H..O. 

and €»H»0» 

Wf)m-?mWv 

KTOCHEV NORTH AuSc?l 3 

OHWKC rtJOXlDD KVISIJKV—IT , -v^-^r - . 

pit) I77-17« • (*X) &5M57J • fc pll) l^-lHIft^E^ . 

. . . . • m > fral a. •!»' jVi U I'^J" l-CRT . 

.-.^iiiti-^#I»iSi 

^.• :,ii^'^^^ . 

<*VW.i-?^.la,'W?3/$rii 

Superaedea Fora Catedi ©1/25/91 

CHEMICAL PAKIIY .Organic Peroxide 

SYHOSTHS T-fcitenone Peroxide 

C.A.S. RECISTRY KUMBER(S) . . Peroxidei 1J»-I3- t 

CKP« 1S1-11-J 

HOCt 1B-9J-1 

Hexyltnt Glycol i 107-41-5 

K.0jt 77M-S*-1 

HAZARDOUS INCREMENTS 

" M.ttrials or Components 

Methyl tthy l X.tone Peroxide •truetura . 

«cX t for ••• * 0.1Wct1v. oxygen 

BlMthyl PhtMlrtt** «•* 

tie xylene *S1Jfe?\f.** «* 

Kethyl Ethyl Ketone** «*• 

Hydrogen Peroxide 

KO.Ibt 

10 

5000 

$000 

\mfm 

U.O 

S2.0 

CO 

1.0 

0.7 

Haierd 0«ti 

PEL ISM • O.T ppm (Call!no) 

TLV 19E1 • 5 wqfm? CWA) 

TLV 1*77 • JS ppe (TKA) 

TLV 1976 - WO ppm (TVA) 

TLV 18B6 - 1 pprr. (TVA) 

y**^.^^^^ 

SHIFT INC INrORHATIOH 

S ei i SHIPPING NAKE.Oraenlc Peroxide type 0,iLiquid 

••••I i 5TIc. tiriTion Organic Peroxide 

HAIARD CLASSIF ICATIW » 1*0105 

1.0 . WJKBER 

FREIGHT CLASSIFICATION Chanlcala H3IBK 

HOC COOE PACE JUS 

PHTCICAL PROPERTIES 

ICLTINC/FREEIINC POINT, *C .«e1o« -SO 

•MOLECULAR mo n N/A 

SPECIFIC CRAVITY (H.O - 1) , «/2J* C 1.0MO ain 

•S.A.C.T i 70*C, 

Ail Cube 

•Salt Accelerating Decomposition Tanperatura 

SOLUBILITY I n H.0 alight 

VAPOR PRESSURE M/E 

VAPOR DENSITY (Ai r - 1 ) M/E 

% VOLATILES BY VOLUKE M/E 

APPEARANCE 4 ODOR Clear oil y Tiqutd, 

ketone odor 

PIRE MO EXPLOSION OATA 

n a m POINT. "C/'F • ''"' V.... .*r.w Matar Poo. ©ry Chemical, Teea 

KSil c KOI*......."-. " 1M.r « UounO. «Sil»ed. •»*"« * •"» • * "J *

 ,,r t ,rC B 

PttlM. PIK "«» * ^OCBmO ..f.T.ttnt. . Cool surrounding yUf W •*»«*" ; „ „ n . 

. n o . MIB N HAIARDS Center.! nation. Tanperatura - Can ejeccapeie -Ith force If con 

UKUSUAL FIRE » EXPLOSION HAZARDS fJ|>e d -ur|B g t|ipewir i to fl,, . 

INACTIVITY OATA 

Unstable. 

SSo»AT»IUT» (.void contact .1th) ....... . "^ft'^Ju . P' - ^1^ - l-tolgnit. 

^ ^ DEC«P0S,T.0N PRODUCTS %£$« £ Spfrrsr/pnuUr.^r.^ffi^ r 

CONDITIONS TO*wio ....••^y.iiiuillllllll l . ••• 

Oil K*$iV- i^)LSPH10R LEAX 

STEPS TO K TAKEN IF MATERIAL Use absorbent Mterlal , aweep or eceop ap using nonIS RELEASED OR SPILLED aparklng tools and dispose of temedletcly. 

VASTE OISPOSAL METHOD Consult arith an Atochaa representative for the talcphoni 

number of your state's tiaierdous artste agency. 

Z3 
HATERI-A l SAFET Y DATASHEE T 

umsoiDDH-s 

TOXICITY 

CF.AL (arate*)(rati) It, . • ASV aig/kg 

INTRAPERITONEAL (acute)(rats) IK : • CS »g/kg 

INHALATION (acute)(ratt) UjjJ - SODppm (A hours) 

SUKHP.ONlCt Thrice weekly closings (rats) a t one-fifth e f IS. , for 7 weeks caused tx o out of five teith t 

IP and five out e f fiv e deaths orally. Liver elfcege arts noted. 

fKES TESTt HuUgenlc In eene a t rains e f Salaenella. 

—•••••>a)e»>»»*JW»aeooai»oo»a«a>a»—eaaoae—» i .a n ai m+m*m+m • »•• • — •• • aaa i 

. ;*.. '. S HEALTH HAZARD INFDFW.T ION 

IFTECTS Or EXPOSUREt 

IRRITATION SKIN-Severe CORROSIVITY SKIK-K' 

EYE • Severe EYE » Key Cause Bllndne: 

SENSITIZATION M/E IMC ETFtnS Irrlti 

INHALATION EFFECTS ....Irritating to almiyt I Ismgs CTHER lx * 

fXERGENCY FIRST AID: 

INCEST I OK Do MST Induce vorr.lt1ng. Cet •ecrgency aedlcal attention for lavage. 

KRHAL ttuiheilth aost and alter . Cet Medical attention. 

EYE CONTACT MWED1ATELY flush arith planty ef water fo r a t least IS minutes. 

Cet emergency etdlcal attention, 

INHALATION <«anevc t o fresh air . If awt fcreathlng, fjlve artificia l respiration. Cet t 

-" attention. 

* " SPECIAL PSOTtnION IMPORTATION 

VENTIIATIOK REQUIREMENTS .. . tlse arith adequate ventilation, -local exhaust. 

EYE Safety classes. frStlet, face ahleld 

HAND (Clove type) fJeoprant, tiltrlle rubber 

•RESPIRATOR TYPE Can e r cartridge, fi t er vapor 

«TMER PROTECTIVE EQUIPHEKT.. Eyewash station 

••Use only WIOSH/KESA approved equipment 

........... . . EABEL PRECAUTIONS 

PRECAUTIONARY IABEL1NC Mash thoroughly efte r handling - • 

Do not *e t In eyes, e*m «H n er clothing 

Do not tter t Mar ceobuttlble t 

Empty container awy contain ttaxardout residue s 

Keep container closed 

Keep amy f m beat, eparkt, and flames 

tto not reuse container 

OTHER HORACE AKC 

HUiDLINC C0KOITI0KS Store fctle* lOQ'F'(H C) t o raelntaln activ e oxygen content. 

PREPARED *Y: •»«•»• ' ***:'-; 

tUrketlng Strvleet t*epirt»ent 17*0 Mlllti-y Moid, t.Halo, MY SA7AD 0«> -

ICTESi M/E « Mot Established 

»i/A«.|iot Applicable 

-•lhe above Inferv.itlcn It accurate t e the keit et e*jr knevledge. ttcvever, since €eti, atfely ataneirdt, i 

•etvletlent era autject tc ehmgr and the conditions ef hendllnc en* «itt, er elsv.it art t-eyonf eur cci -

K'Hl K". »W».VTY. EITHD. EJW.ESS D-" ff i IB, MI1H MLSnCT TC TH" eC^LClEKCS! V. CD-niK'JIK'. ft.CtKrt.w.n |l> C0'".MKrii HTl.tll. AV. CISCUI^ ALI lU'llITt FO' P.UIA-.:C TKrf.lO>.'. tier eVsjld eitllt} M1 

,•• . ?••, r.i.p f tr I'I tr-r'rilr* i-re .* 

-1 tv 
P.25 

Ashland Chemical 

^^^i3VL^,^^J*^*^ 

Composhe Polymers DNlskxi AshUnd Chem'icsl, Inc. 

SubsW.ary of 

Ashland Oil, inc. 

Aijdress Recty 

RO. 60x2218 

Columbus, Ohio 43216 

Jsmuaiy 21,1993 

Mr. Tom Picken 

Pickens Plastics 

P. O. Box 1279 

•Ashtabula, OH 44004 

Fax # 216/992-1408 

Dear .Mr. Picken: 

Per your request this is to confirm that AROPOL^Q-tSOZZ-S polyester resin is a styrene 

suppressed polyester. By suppressing the release of styrene monomer from the laminate 

while it is curing, the amount of styrene released into the environment is reduced. The 

retained styrene becomes part of the finished laminate resulting in a cost savings by means 

of reduced resin requirements. 

A MSDS on AROPOL Q-6022--S resin has been sent to you separately. 

Thank you for allowing Ashland Chemical the opportunity to supply your polyester resin 

requirements. If you have any questions on the above, please call me. 

Sincerely yours, 

Alan R. Robers 

Distribution Manager 

ARR/jls 

cc: R Moor 

JJ Anclien 

TR Evans 

Headquarter* 

MOO Blazer Parkway 

OuWin.Ohto<30lT 

(eid)e55-3332 

Cable Address: Aroplaz OH 

Telex: 245385 

Answerback: ASHCHEM 

Fax: (6U) 623 3735 

n, ^ 
)&taltty tUl$ ana {Jhemunfs 

l 75 MONTGOMERY STREET 

AH CA COOS tOI 

C«kA»iA* «l">tltM<.''ivt» I TSU»»-<OM| 414-4TCC 

SPECIALTY PRODUCTS Co.LTD.

 v—' P. O. BO X 30 6 rA " "•<"*~w TORONTO. CANA>» 

AREA COOE 4iB 

TCLf»MON( IJ» i6*l 

TAX 4ie-»J"»i» * 

JERSE Y CITY, N. J. 07303-0306 

Faxed: January 29, 1993 

(3>1fi OQ**>-140fl) 

Mr. Ted Hebert 

T.J. Hebert Associates 

1810 Meadow Road 

Madison, Ohio 44057 

Dear Ted: 

Thie ie in answer to your questions concerning our product, 

Styrid. 

Styrid contains 53-55% VOC (volatile organic compounds). 

The VOC is composed of mineral spirits in its entirety, 

while the remaining components in the formulation are not 

classified as VOC. As I mentioned, the Specific Gravity is 

.79 grams per cc. This equalB to a density of 6.59 pounds 

per gallon. 

I also mentioned to you the study that had been done with 

Styrid and various polyester resins. The test that was 

conducted fully complies with the styrene emissions 

regulations. This information will be sent to your office 

for your review and files. 

If you require any further assistance, please feel free to 

contact us. 

Very truly yours, 

8FECIALTY PRODUCTS COMPAKY 

HSL 

Raul D. Hernandez 

Technical Department 

/msp 

TO< 3 sxonao^- ^ AATV I ^s.tss•* 

9 0> 
P.27 

SEP-26-1991 12:20 FR31 . FRP SUPPLY 16C 

-?-*-

T 0

 19921403 

£15 3SS KZi r.ci 

P. 02 

Preparation Date " vAN 18. '90 

SPECULTY PSCCCCTS CCKPANY 

75 KONTSCnSRY STREET 

P.O. BOX 306 

JERSEY CITY. HEX.JERSEY 

07303 

Emergency Phone Number . • * 

201-434-4700 BETWEEN $:C0 ASD 4:30 P.SI 

20l-43S-*031$ AFTSE <:30 P.M. 

Inforaation Phone Nuabar J 

201-434-4700 FCR INFORHATXCN 

OOO 

f-Jf-V 

HAZARD RATING 

Health .... * 2 

Reactivity s 1 

Flammability ... : 2 

E qui pa-ant ...... : A 

Special Hazard .. K 

SECTION 1 - GENERAL INFORMATION 

A4-- -Zlyfiatn*. %ijA&f«h± roduc t Code t P5S0$00iP 

bealca l Haae h Syn. x STYRENE SUPPRESSANT ASD ADDITIVE .. , / _ , ' T-. 

fceaical **»Uy

 : THlSS ^ HYDROCARBON ftcU4- ol fc,Vi« fy-4*voraul e

 f KJXTuRr , . t ">/,-» «y / 

OT Shipping Ha»e ... « STYRID ^ideid- cAr /•£> 4 «*•/ 

OT Haaard Class ....'• COMBUSTIBLE LIQ ©•a*. 

SECTION II - INGREDIENTS 

Of 

SECTION III - PHYSICAL DATA 

i ne Point (*F> : 3C5*395 

-Hi*. Gravity (RJ0»1> i cx.0 

•or P • - : turt —a tg.) : <!0ES 6 25*C. 

jieeirt »ti* y Vol (X>.... : 50 

* ••»er t". 'V =1) J APPROX. 4.6 

. . .ta.. " Re * (S-BUTYL ACETATE el ) O. I OF THE SOLVENT PAET. 

5C ' ;il t vt. •*-, ar *'. NEGLIGIBLE 

,B « HONE 

Appearance * Odor i .VHITE VISCCCS LlSUID/PSTROLEUfci ODOR 

' IzCTION IV - PIRB A EXPLOSION HAZARD LATA " 

Slash Poitvt .... : 10CF. 

Flash Pftlnt 3est r.*-fcod : TOC 

Tlaaaable its : * »Sff V^loae. — LEL .: O.P* . 

Pare « *• 1 

7,1 
P.28 

J91 12:20 FROM FRP SUPPLY 16C TO 19921403 P. 03 

• • V A. 

C$</3k</0 

•OKSGSTICS. 

'SECTION V - JiEALTR HAZARD DATA 

-vJ-#£hc'* d Llait Value ' JJSS5 

Tixesac-a_«*n-a ._4(R<t Talue : SOOPFS ***- ... . „...- •-""•"KDAY 

Page • ^ 

1*. 
P.29 

/...T.?.4...}.2.:.e.?. 216 <35 ee n . P . e 3 

^.6-1991 12:21 FROM • FRP SUPPLY 16B '""lO i^MM '"p.ii 

©s/ei. isw :M : « ^ ^? S^?LY KTJUW.M* •siESsres.t; r.as 

.........iv i -•'<". T-"* */*»} • "*•* **J.**m * >! M \ * •• 'J.vv *•" •vii" ••""^K.'C.r.f *** Sf/tT.-tJ! ) * M^ "^ " a"'*; t V 

-•>;*£ _ w-r.v* . _.«\.*i£ - ••'f • «••- ••*•»•. iJ 1* v'. i »•.„*.»?<« , CvPlVl. : ....S-v.fti ' .i.i.-^.AitL : . ISHALATICN: VAPOR PSEESvRE IS V2&Y LOW. VAPOR INHALATION CN5ES AHBIENT. 

CONDITIONS IS NCr.y.AlLY SOT A PROELEJI. IF OVEP.COftE SY VAPOR FBOX KCT PEGDOCT. 

IMMEDIATELY REMOVE F>C!i EXPOSURE AND CALL A PHYSICIAN'. . I? BREATHING IS 

I»5£S'vLAR CR HAS STOPPED. START RSSTSCITATICS. ADMINISTER OXYGEN IF AVAILABLE. 

I* OVEREXPOSED TO O'S MIST; F.EH0VE J50K FCKTXE5 EXPOSURE UNTIL EXCESSIVE OIL 

»SST COALITION JBC2SIDES. 

SECTION VI - EEACTIVITY DATA 

Stabilit y - Cnstable J SO 

- Stabl e • .* YES 

Conditions to Avoid : OPEN FL.A2ES 

Incoapatibllit y : ETRCNfi OXIDIZING AGENTS 

Baterials t o Avoid : CHLORINE. LIQOID CXYGZS 

Hecard Polyafertration - Hey Occur: NO 

- Vil l Not Occur .. t YES 

Conditions t o Avoid : CPEN FLAXES 

Hazardous Decoaposition Products : CARBCN iJONCXlDE, ALDEKYDES, FOKES, SMOKE 

SECTION VII - ENVIRONMENTAL PROTECTION PROCEDURES 

Spil l Response : SECT OFF AND ELIMINATE ALL IGNITICK SOURCES. KES? 

-ECPLS A«AY J -'ILATE AREA. KEEP PRODUCT OUT OF SEWERS ASD WATER COURSES 3Y 

six:*"* CR ':.:. :;-*L:NG. ABSOEB VITH SAND OR INERT MATERIAL: -SHEEP OR SCOOP W - •• 

AND REhC'-E. rREVEJsT SPREAD CR SPILL. ADVISE AUTHORITIES IF PRODUCT HAS ENTERED 

OR RAY ESTER SEVERS, KATE?. COURSES. OE EXTENSIVE LAND AREAS. ASSURE CDNFORKITY 

WITH LOCAL ESC-CLATIONS. CONTINUE TO OSSERVS PRECAUTIONS FOE VOLATILES, 

CCMSVSTIBLS VAPCRS FROM ABSORBENT HATER!AL. 

%Caste Disposal Hethod .. : CCNSULT FEDERAL, STATS OR LOCAL AUTHORITIES FOR 

?°C?SR DISPOSAL PROCEDURES. ASSURE CONFORMITY VITK APPLICABLE DISPOSAL 

e.EC-vLATlCNS. DISPOSE CF ABSORBED MATERIAL AT AN APPROVES KATSR SITE OB FACILITY. 

SECTICN VIII - SPECIAL PROTECTION INFORMATION 

Ere Protection » SPLASH GOGGLES. CR FACE SHIELD WHEN SYS CONTACT MX 

CCC'JB. 

Respiratory Protection .: USE AIR SUPPLIED RESPIRATORY PROTECTION IN CONFINED 

CR ENCLOSED SPACES. OSS ONLY NIOSK .APPROVED EOUTPMSNT. USE CAN OR CARTRIDGE. 

GAS CE V.APCR RESPIRATOR TYPE DNDER CONDITIONS EXCEEDING TLV STANDARDS. 

Ven-ailatien Reeomoended •- ALWAYS MAINTAIN BELOW PERMISSIBLE EXPOSURE LIMITS. 

?R-:viCE GREATER THAS SIXTY TEET PER MINUTE KOCD, FACE VELOCITY FOR CONFINED 

SFi.'Ii. PROVIDE VENTILATION SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED 

IST .VES LIMITS OP. BUILDUP OF IXPLCSIVS CONCENTRATIONS OF VAPOR IN AIR. DSE 

s..:..,,;s;cn-PROOF EQUIPMENT. 

Otoe? Protection : USE CEEMMAL RESISTANT APRON OR CTEER IMPERVIOUS 

PP.CLCS5ED Or. EErS.VTED SKIN CCSTACT. 

~"~ ' SECTION II - SPECIAL PRECAUTIONS 

Ptffc t : 3 
P.30 

-26-9 1 THU l'2:e9__ ^ ?A*-?.??--?-8-!-7-. 

SEP-26-1991 12:22 FR31 FRP SUPPLY 160 

P.64 

•"TM: / -/A/1 :~y T" -VttpiRED-SY^AUL-S.-KSSHAJOEZ 

-V 0 
P.31 

I 

^ m- « ~ PAGE 01 

MATERIAL SAFETY OATA SHEET /"» /?,/} /O J_ 

SECTION I - MANUFACTURERS INFORMATION^ 

PRODUCT CODE IDENTITY: 944A083 COMPANY NAME :COOK PAINT & VARNISH CO. 

PRODUCT NAME: MEDIUM GRAY SANDABLE ADDRESS: 919 E. 14TH STREET 

NPCA HMIS RATING: NORTH KANSAS CITY MO 64116 

DATE OF MSDS: 03/01/89 PREPARED BY: HAZARD COMMUNICATION DEPT 

EMERGENCY TELEPHONE: 816-391-6000 INFORMATION TELEPHONE: 816-391-6003 

ATTN: SAFETY AND HEALTH OFFICER 

PICKENS PLASTICS CUSTOMER NUMBER: S6027EI 

4212 ANN AVENUE DATE PRINTED: 03/14/90 

COMPLEX: 380 

ORDER NO: 054874 

ASHTABULA OH 44004 PACK LIST NO: 000564 

SECTION II - HAZARDOUS INGREDIENTS 

STYRENE MONOMER <ZL,'%°I° 

CAS « : 000100-42-5 UT. 'Ax 35.000 VAPOR PRESSURE: 4.5 

(MMHG/DEG F> 

EXPOSURE LIMIT: 

ACGIH TLV/TUA: 50 PPM (SKIN) (215 MG/CU.M.) 

ACGIH TLV/STEL: 100 PPM (SKIN) (425 MG/CU.M.) 

OSHA PEL/TUA: 50 PPM (215 MG/CU.M.) 

OSHA PEL/CEILING: 100 PPM (425 MG/CU.M.) 

TITANIUM DIOXIDE 

CAS 4: 013463-67-7 WT. M'. LESS THAN 5 VAPOR PRESSURE: N/A 

(MMHG/DEG F) 

EXPOSURE LIMIT i 

ACGIH TLV/TUA: 

OSHA PEL/TUA: 

10 MG/CU.M. (TOTAL. DUST) 

lOMG/CU.M.(TOT DUST)j5MG/CU.M.(RSPIRABLE FRACTH 

TALC (HYDROUS MAGNESIUM SILICATE) 

CAS «: 014807-96-6 UT. Kl 15.000 VAPOR PRESSURE: 

(MMHG/DEG F) 

N/A 

EXPOSURE LIMIT : 

ACGIH TLV/TUA! 

OSHA PEL/TUA: 

2 MG/CU.M. (RESPIRABLE DUST) 

2 MG/CU.M. (RESPIRABLE DUST) 

ALUMINUM SILICATE (KAOLIN) 

CAS 4 : 001332-58- 7 UT. Xi 15.000 VAPOR PRESSURE: 

(MMHG/DEG F) 

N/A 

EXPOSURE LIMIT 

"3 I 
P.32 

\ . 

MATERIAL SAFETY DATA SHEEI 

PRODUCT CODE IDENTITY: 944A083 PRODUCT NAME: MEDIUM Gl-;.. 

OSHA PEL/1 UA : 10MG/CU . M . (TO f DUST > j 5MB/L.U . M . ( RE:.., 

THIS MATERIAL CONTAINS INGREDIENTS COVERED BY THE CALIFORNIA "SAFE ORINIUNo 

UATER AND TOXIC ENFORCEMENT ACT OF 1986" (PROPOSITION 65). 

SECTION III - HEALTH HAZARD DATA 

ILFFECTS OF OVEREXPOSURE TO PRODUCT. PRIMARY ROUTES OF ENTRY ARE: 

EYE CONTACT: IRRITATION. SYMPTOMS ARE TEARING, REDNESS AND DISCOMFORT. 

SKIN CONTACT: IRRITATION. CAN CAUSE DEFATTING OF SKIN UHICH MAY LEAD TO 

DERMATITIS. 

INHALATION: IRRITATION TO NOSE AND THROAT. EXTENDED OR REPEATED EXPOSURE 

TO CONCENTRATIONS ABOVE THE RECOMMENDED EXPOSURE LIMITS MAY 

CAUSE BRAIN OR NERVOUS SYSTEM DEPRESSION, CAUSING DIZZINESS, 

HEADACHE OR NAUSEA AND IF CONTINUED INDEFINITELY, LOSS Or 

CONSCIOUSNESS, LIVER AND KIDNEY DAMAGE. 

REPORTS HAVE ASSOCIATED REPEATED OR PROLONGED OCCUPATIONAL 

OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS 

SYSTEM DAMAGE. 

INGESTION: ' MAY CAUSE MOUTH, THROAT, ESOPHAGUS AND STOMACH IRRITATION, 

NAUSEA, VOMITING AND DIARRHEA. 

MEDICAL CONDITIONS THAT MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT: 

PREEXISTINO EYE, SKIN, LIVER, KIDNEY AND RESPIRATORY DISORDERS. 

EMERGENCY AND FIRST AID PROCEDURES: 

IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY UITH PLENTY OF UATER FOR AT LEAST 

15 MINUTES AND GET MEDICAL ATTENTION; FOR SKIN, UASH THOROUGHLY UITH SOAP AND 

WATER. IF AFFECTED BY INHALATION OF VAPORS OR SPRAY MIST, REMOVE TO FRESH 

AIR. „ IF SUALLOUEO, GET MEDICAL ATTENTION IMMEDIATELY. 

OTHER HEALTH HAZARDS: 

THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS RECLASSIFIED 

STYRENE AS GROUP*2B "POSSIBLY CARCINOGENIC TO HUMANS". THIS NEU CLASSIFICATION IS NOT BASED ON NEU HEALTH OATA RELATING TO EITHER HUMANS OR ANIMALS, 

BUT ON A CHANGE IN THE IARC CLASSIFICATION SYSTEM. THE STYRENE INFORMATION 

AND RESEARCH CENTER DOES NOT AGREE UITH THE RECLASSIFICATION AND HAS 

PUBLISHED THE FOLLOUING STATEMENT. "RECENTLY PUBLISHED STUDIES TRACING 

50,000 UORKERS EXPOSED TO HIGH OCCUPATIONAL LEVELS OF STYRENE OVER A PERIOD 

OF 45 YEARS SHOUED NO ASSOCIATION BETUEEN STYRENE AND CANCERt NO INCREASE IN 

CANCER AMONG STYRENE UORKERS (AS OF'POSED TO THE AVERAGE AMONG AIL UORKERS), 

AilO NO INCREASE IN MORTALITY RELATED TO STYRENE." 

SECTION IV - PHYSICAL DATA 

^ 
P.33 

PAGE 03 

MATERIAL SAFETY DATA SHEET 

PRODUCT CODE IDENTITY: 944A083 PRODUCT NAME: MEDIUM GRAY SANDADL.E 

PERCENT VOLATILE BY VOLUME: 52.015 PHYSICAL STATE: LIQUID 

ODOR: AROMATIC APPEARANCE: 

ODOR THRESHOLD: (NOT AVAILABLE) SPECIFIC GRAVITY: 1.30 

VAPOR PRESSURE: (NOT AVAILABLE) FREEZING POINT: (NOT AVAILABLE) 

PH: (NOT AVAILABLE) COEFFICIENT OF UATER/OIL 

DISTRIBUTION: (NOT AVAILABLE) 

SECTION V - FIRE AND EXPLOSION HAZARD DATA 

OSHA FLAMMABILITY CLASSIFICATION: FLAMMABLE LIQUID CLASS IC 

FLASH POINT SETA CLOSED CUP. OEG F i 88 

DOT HAZARD CLASS: RED-LABEL, FLAMMABLE LIQUID LEL (JO : 1.10 

EXTINGUISHING MEDIA: FOAM, CARBON DIOXIDE, DRY CHEMICAL., UATER FOG. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: 

IF POLYMERIZATION TAKES PLACE IN A CONTAINER, THERE IS POSSIBILITY OF VIOLENT 

RUPTURE OF THE CONTAINER. STYRENE VAPORS ARE UNINHIBITED AND MAY FORM 

POLYMERS IN VENTS OR FLAME ARRESTORS OF STORAGE TANKS RESULTING IN STOPPAGE 

OF VENTS. VAPORS MAY CAUSE FLASH FIRE. KEEP CONTAINERS TIGHTLY CLOSED AND 

ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. NEVER USE UELDING 

OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST 

RESIDUE) CAN IGNITE EXPLOSIVELY. 

SPECIAL FIRE FIGHTING PROCEDURES: 

FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD 

BE USED. UATER SPRAY MAY BE INEFFECTIVE. IF UATER IS USED, FOG NOZZLES ARE 

PREFERABLE. WATER MAY BE USED TO COOL. CLOSED CONTAINERS TO PREVENT PRESSURE 

BUILD-UP AND POSSIBLE AUTO-IGNITION OR EXPLOSION UHEN EXPOSED TO EXTREME HEAT 

SECTION VI - REACTIVITY DATA 

STABILITY: STABLE • HAZARDOUS POLYMERIZATION: MAY OCCUR. 

CONDITIONS TO AVOID: 

ELEVATED TEMPERATURES. IMPROPER ADDITION OF PROMOTER AND/OR CATALYST. AVOID 

DIRECT CONTACT OF MEKP CATALYST UITH ACCELERATOR. IF AN ACCELERATOR SUCH AS 

COBALT DRIER IS TO BE ADDED. MIX THIS ACCELERATOR UITH BASE MATERIAL BEFORE 

ADDING CATALYST. 

INCOMPATIBILITY (MATERIALS TO AVOID): 

OXIDIZERS, PEROXIDES, STRONG ACIDS. ALUMINUM CHLORIDE AND VINYL POLYMERS. 

HAZARDOUS DECOMPOSITION PRODUCTS: 

THERMAL DECOMPOSITION OR COMEiUSTlON CAN' PRODUCE FUMES CONTAINING OKGAHJC 

f..:JU.' , CARfcC-N DIOXIDE AND CARBON MONOXIDr.. 

"2> 2, 
P.34 

\ 

PAGE 04 . 

MATERIAL SAFETY DATA SHEET \ 

"?!!--I_-?!?!_"!!!"I!i.!!!^??..__ PRODUCT NAME: MEDIUM GRAY SANDAKLE 

SECTION VII - SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: 

REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, AND ELECTRICAL , STATIC 

OR FRICTIONAL SPARKS). AVOID BREATHING VAPORS. VENTILATE AREA. C0N1A1N AND 

REMOVE UITH INERT ABSORBENT AND NON-SPARKING TOOLS. 

WASTE DISPOSAL. METHOD: 

DISPOSE OF IN ACCORDANCE UITH LOCAL, STATE AND FEDERAL. REGULATIONS. DO NOT 

INCINERATE CLOSED CONTAINERS. INCINERATE IN APPROVED FACILITY. 

SECTION VIII - SPECIAL PROTECTION INFORMATION 

RESPIRATORY PROTECTION: 

DO NOT BREATHE OR INGEST VAPORS, SPRAY MIST OR DUST WHILE APPLYING, SANDING, 

GRINDING, OR SAUING CURED PRODUCT. UEAR AN APPROPRIATE, PROPERLY FITTED 

RESPIRATOR (NIOSH/MSHA APPROVEO) DURING APPLICATION AND OTHER USE OF THIS 

PRODUCT UNTIL ALL VAPORS, MISTS, AND DUSTS ARE EXHAUSTED, UNLESS AIR MONITORING DEMONSTRATES VAPOR AND MIST AND DUST LEVELS ARE BELOW APPLICABLE LIMITS. 

FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE. OBSERVE OSHA 

STANDARD 29CFR 1910.134. 

VENTILATION: 

PROVIDE GENERAL. CLEAN AIR DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND 

PATTERN TO KEEP THE AIR CONTAMINANT CONCENTRATION BELOW THE LOWER EXPLOSION 

LIMIT AND BELOW CURRENT APPLICABLE EXPOSURE LIMITS IN THE MIXING, APPLICATION 

AND CURING AREAS; AND TO REMOVE DECOMPOSITION PRODUCT OURING WELDING AND 

FLAME CUTTING ON SURFACES COATED UITH THIS PRODUCT. IN CONFINED AREAS. USE 

ONLY WITH FORCED VENTILATION ADEQUATE TO KEEP VAPOR CONCENTRATION BELOW 20* 

OF LOUER EXPLOSION LIMITS. REFER TO OSHA STANDARDS 29CFR 1910.94, 1910.107, 

1910.108. 

INOTEs HEAVY SOLVENT VAPORS SHOULD BE REMOVED FROM LOUER LEVELS OF THE UORK AREA 

AND ALL IGNITION SOURCES (NONEXPLOSION-PROOF MOTORS, ETC.) SHOULD BE ELIMINATED. 

PROTECTIVE GLOVES: USE SOLVENT IMPERMEABLE GLOVES TO AVOID CONTACT WITH PRODUCT 

ft 

EYE PROTECTION: 

DO NOT GET IN EYES, USE SAFETY EYEUEAR WITH SPLASH GUARDS OR SIDE SHIELDS, 

CHEMICAL GOGGLES, FACE SHIELDS. 

ETHER PROTECTIVE EQUIPMENT: 

AVOID CONTACT UITH SKIN. USE PROTECTIVE CLOTHING. PREVENT CONTACT UITH 

CONTAMINATED CLOTHING. UASH CONTAMINATED CLOTHING, INCLUDING SHOES, BEFORE 

REUSE. 

SECTION IX - SPECIAL PRECAUTIONS 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: 

DO NuT STORE ADOVC 120 OEG. F. STORE LARGE QUANTITIES IN UUILD1NGS DESIGNED 

TO COMPLY WITH OSHA 1910.106. KEEP AWAY FROM HEAT, SPARKS AND FLAME. KEF 1 

CONTAlNf RS n fir.ri. MHEN NOT IN USf AND IIPPIRHT TO PREVENT f | ,-,*..r: 

I'l t 
P.35 

PAOL 05 

MATERIAL SAFETY DATA SHEET 

CAS 

NUMBER 

000100-42-5 

X BY 

WEIGHT 

35.8470 

PRODUCT CODE IDENTITY: 944A003 PRODUCT NAME: MEDIUM GRAY SANDAM.E 

HANDS AFTER USING AND BEFORE SMOKING OR EATING. EMPTIED CONTAINERS MAY RETAIN HAZARDOUS RESIDUE AND EXPLOSIVE VAPORS. KEEP AWAY FROM HEAT, SPARKS AND 

FLAMES. DO NOT CUT, PUNCTURE OR WELD ON OR NEAR EMPTIED CONTAINERS. FOLLOW 

ALL HAZARD PRECAUTIONS GIVEN IN THIS DATA SHEET UNTIL CONTAINER IS THOROUGHLY 

CLEANED OR DESTROYED. IF THIS PRODUCT IS BLENDED WITH OTHER COMPONENTS SUCH 

AS THINNERS, CONVERTER, COLORANTS AND CATALYSTS PRIOR TO USE, READ ALL WARNING LABELS. ANY MIXTURE OF COMPONENTS WILL HAVE HAZARDS OF ALL COMPONENTS. 

"FOLLOW ALL PRECAUTIONS. IF SPRAYING THIS MATERIAL, KEEP SPRAY BOOTHS CLEAN. 

AVOID BUILDUP OF SPRAY DUST OR OVERSPRAY IN BOOTHS OR DUCTS. 

KEEP OUT OF REACH OF CHILDREN FOR INDUSTRIAL USE ONLY 

SECTION X - SARA TITLE III INFORMATION 

THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING 

REQUIREMENTS OF SECTION 313 OF SARA TITLE III EMERGENCY PLANNING AND COMMUNITY 

RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR PART 372. 

CHEMICAL 

NAME 

STYRENE MONOMER • 

THIS LAW REQUIRES CERTAIN MANUFACTURERS TO REPORT ON ANNUAL EMISSIONS OF 

SPECIFIED TOXIC CHEMICALS AND CHEMICAL CATEGORIES. IF YOU ARE UNSURE IF YOU 

MUST REPORT OR REQUIRE MORE INFORMATION, CALL THE EPA EMERGENCY PLANNING AND 

COMMUNITY RIGHT-TO-KNOU HOT LINE: 800-535-0202 OR 202-479-2449. 

DISCLAIMER AND LIMITATION OF LIABILITY 

TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE. 

THE WARRANTY DESCRIBED HEREIN SHALL BE IN LIEU OF ANY 'OTHER WARRANTY, EXPRESS 

OR IMPllEO. INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF 

MERCHANTABLITIY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES 

THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. THE BUYERS SOLE AND 

EXCLUSIVE REMEDY AGAINST SELLER SHALL BE FOR THE REPLACEMENT OF THE PRODUCTS Ok 

REFUND OF THE PURCHASE PRICE IN THE EVENT THAT A DEFECTIVE CONDITION OF THE 

PRODUCTS SHOULD BE FOUND TO EXIST. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED 

TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES"FOR LOST PROFITS, LOST SALES, INJURY TC 

PERSON OR PROPERTY, OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE 

AVAILABLE TO THE BUYER. THE SOLE PURPOSE OF THIS EXCLUSIVE REMEDY SHALL BE TO 

PROVIDE BUYER WITH REPLACEMENT OF THE PRODUCTS OR REFUND OF THE PURCHASE PRICE. 

OF THE PRODUCTS IF ANY DEFECT IN MATERIALS OR UORKMANSHIP IS FOUND TO EXIST. 

THIS EXCLUSIVE REMEDY SHALL NOT BE DEEMED TO HAVE FAILED ITS ESSENTIAL PURPOSE 

SO LONG AS SELLER IS WILLING AND ABLE TO REPLACE THE DEFECTIVE PRODUCTS OR 

REFUND THE PURCHASE PRICE. BUYER MUST CIVE SELLER NOTICE IN URITING OF ANY 

AllEGED DEFECT COVERED BY THIS UARRANTY (TOGETHER WITH ALL IDENTIFYING BCTAII E 

INCLUrilMU THE PRODUCT CODE <S) , DESCR J PTION AND DATE OE PUPC-HASr ) WITHIN 111] I-IV 

,.. .. .,•*•' r-r TI T i -i •: r r,.i:-1 v r.r c\\ry> 1'irrjrT. n>*' * j.r T r * v "< •/ *, -j , "•<• t-r ".:••• 

%<> 
P.36 

^ 

Lx?> 

MATERIAL SAFETY DATA SHEET 

37166 

37165 

4 Otol 

Pag e 1 

SECTION I - IDENTIFICATION Qj j /If) /? JL~~*~ 

.REVISION: DZ 

DATE OF MSDS: DATE PRINTED: 

PRODUCT CODE IDENTITY: 944B025 

PRODUCT NAME: BLACK 

NPCA HMIS RATING: H F R 

COHPANY NAME: COOK COMPOSITES AND POLYMERS CO. pREpAR£ D fiy 

ADDRESS: SoRIH'rlSsA S CITY . MO 6411 6 HAZARD COM 

INFORMATION TELEPHONE: B16-391-600 3 

r-iicTniATTR NAME- GREAT LAKE TERMINALS CUSTOMER NAttt. u* ^ EXECUT1V E BLVD 

DAYTON OH 4S4 24 

11-26-9 0 

01-30-9 1 

COMMUNICATION DEPT. 

EMERGENCY TELEPHONE: 616-391-600 0 

SECTION II HAZARDOUS INGREDIENTS 

CAS* 000100-42-5 

•iSFR TM 34*61 VAPOR PRESSURE: 4.50 KHHG € 6BF 

EXPOSURE LIMIT: B 0 ppK (SK1N ) (215 KG/CU.K.) 

%.A pil/CEItlNG: i-- PPK «« " "B/CU^ ) 

-ii-iii" SiS5»5«"«M« 5 " S« O14B07-8S.6 

X BI VI: 10.0 

EXPOSURE IIBII: 2 HC/CU.M. . 11|PI|»BI.| JUST 

.JM I"' •f»H/?lli5t4»S,8«Bl»«Dll!Iicmi 

-iriirSiSoiiii-LiiHi5 — « " •<•»«-*-' 

% BY WT: 10. 0 

EXPOSUREcUMlT^ i8 H ^c5V(TO T DUST) :*HG/CU.K . (RESPIRABL FRACTION 

-ii-iS"i55i5ii-«iSi= 

X BY WT: <S.O 

EXPOSURE c LIMIT Lv/m : 10 KG/CU K. TOTAL DUST 

CifflBM'MK:' Imcr.-SKORPHOU^SILICACEL 

CAS* O000B0-62- 6 

24BKETHYL KETHACRYLATE • yApo R ms8URK . 29 . 0 0 MKHG 6 6BF 

EXPOSURE LIMIT: a ppM (41 0 KG/CU.K.) 

OBBA PEL/TWAV l??.?p.Lill?.^---:-:-

SECTION 111 PHYSICAL DATA 

. . . v/7 !r v 7';? . f* T 

~2, G 
/.* * 

s^ 

P.37 

jftHt.fti.itt K •.**** tur n it * « • >. »(«••. •xn-x*»(*>i*»i»'. K»t»i»<**i*k*f:*»(*ti*«»*»(»»*»<*»<»>«*:*>-

COOK COMPOSITES AND POLYMERS CO. 

MATERIAL SAFETY DATA SHEET 

Pag e 2 

^^«tNKti**«t(«hl(llti»l*»(«(»l«*»(«»(*!<«**»ltlt(K*»(«»(»(l(***»(»t«»(l(ll»(tt**»l«t(*«»l»(»(»l*»t*«« « 

Vapor Pressure: See Section II 

Vapor Density: Heavier Than Air 

Evaporation Rate: Slower than Ether 

Veight per Gallon: 10.16 

Specific Gravity: 1.22 

\ Volatile by Volume: 3.40 

% Volatile by Weight: 39.79 

VOC: 4.044 

Physical State: LIQUID 

Appearance: BLACK 

Odor: MODERATE AROMATIC f/C'^° 

Odor Threshold: N/A 

pH: N/A 

Freezing Point: .N/A 

Water Solubiltiy: N/A 

Coefficient o£ Vater/Oil Distribution: N/A 

Mechanical Impact Explosion: N/A 

Static Electricity Explosion: N/A 

SECTION IV FIRE AND EXPLOSION HAZARD DATA 

OSHA Flammability Classification: Class IC 

j 

DOT Hazard Class: Flammable Liquid 

Actual Flashpoint Seta Closed Cup: B2.0 

Explosion Level: Lower- 1.1 

I EXTINGUISHING MEDIA:. . . 

Foam, carbon dioxide, dry chemical, water fog. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: 

If polymerization takes place in a container, there is possibility of 

violent rupture of the container. Styrene vapors are uninhibited and 

may form polymers in vents or flame arrestors of etorage tanks resultins in stoppage of vents. Vapors may cause flash fire. Keep containers 

tightly closed and isolate from heat, electrical equipment, sparks and 

flame. Never use velding or cutting torch on or near drum (even empty) 

because product (even just residue) can ignite explosively. 

SPECIAL FIRE FIGHTING PROCEDURES: 

Full protective equipment including seif-contiincd breathing apparatus 

should be used. Water spray may be ineffective. If vater is used. log 

nozzles are preferable. Water ray be used to cool closed containers to 

prevent pressure build-up and possible auto-ignition or explosion vhen 

exposed lo extreme heat. 

"hi 
r ::Va«.«v««.t«.««"««^ 

^^•••oaaaO^i^ill^^Bn.vMrR S CO. 

P.38 

, »"....» » « " l 

SECTION V HEALTH HAZARD DATA 

„".'oF EXCESSIVE OVEHEXPOSUBE. »»* « KOUIES CE EKTKI «« . 

'f.fflli . i,»t.» •« t.«i... »•«•• ">' «»«««»*• 

"•B.SSK5 ' C.n »« « «.t.«t. . o£ sli . which » x I--- t . i.».tit.. . 

or nausea ann *» *•*" 

and kidney damage. or . o n „ ( 1 occupational over -

vomiting and diarrhea. rVpnMJRE TO THIS PRODUCT. 

reB °V e

 J v •>>«. Californi a "Safe Drinking 

,T«EE KM. " HMM.DS: _ 

SECTION VI mCTIVlTI M M 

„„,„„ , ,i.« . KUUDOUS POUKEEIzmom K.I .ccr . 

7,* 
P.39 

3 "716 6 

COOK COMPOSITES AND POLYMERS CO. \ 

MATERIAL SAFETY DATA SHEET \ 

««««f«*M*M«*Kai««««t(lfK<t««(«KM««t-MM«IM«tM«K«IM-MKItW«l(MK « V . 

materia l befor e adding catalyst . 

INCOMPATIBILITY (MATERIALS TO AVOID): 

Oxidizers , peroxides, stron g acids , aluminum chlorid e and viny l polymer s 

HAZARDOUS DECOMPOSITION PRODUCTS: 

Thermal decompositio n or combustion can produc e fuiae s containin g organi c 

acids , carbon dioxid e -and carbon monoxide . 

SECTION VII SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL 15 RELEASED OR SPILLED: 

Remove il l source s of ignitio n (flames, ho t surfaces , and electrical , 

static , or frictiona l sparks) . Avoid breathin g vapors . Ventilat e area 

Contain and remove vit h iner t absorbent and non-sparkin g tools . 

VASTE DISPOSAL METHOD: 

Dispos e of i n accordance vit h local , stat e and federa l regulations . Do 

n o t incinerat e close d containers. Incinerat e i n approved facility . 

SECTION VIII SPECIAL PROTECTION INFORMATION 

RESPIRATORY PROTECTION: 

Do no t breath e or ingest vapors, spray mist or dust vhil e applying . 

sanding , grinding , o r sawing cured product. Wear an appropriat e 

properl y fitte d respirato r (NIOSH/MSHA approved) durin g applicatio n and 

othe r us e of thi s produc t unti l vapors, mists and dust s are exhausted , 

unless ai r monitoring demonstrate s vapor , mist and dust level s ar e below 

applicabl e limits . Follo v respirato r manufacturer's direction s fo r 

respirato r use . Observe OSHA Standard 29CFR 1910.134 . 

VENTILATION: 

Provide genera l clean ai r dilutio n or loca l exhaust ventilatio n i n 

volume and patter n t o keep th e ai r contaminant concentratio n below the 

lowe r explosio n limi t and belov; curren t applicabl e exposur e limit s i n 

t he mixing , applicatio n and curing areas; and t o remov e decompositio n 

produc t during welding and flame cuttin g on surface s coated with thi s 

product. In confined areas, us e only with forced ventilatio n adequat e 

t o keep vapor concentratio n below 20% of lower explosio n limits . Refert o OSHA Standards 29CFR 1910.94 . 1910.107 , 1910.108 . 

MOTE: Heavy solven t vapor s shoul d be removed from lowe r level s of th e work 

are a and al l ignitio n source s (nonexplosion-proo f motors, etc. ) 

should be eliminated . 

PROTECTIVE GLOVES: 

Use solven t impermeable glove s t o avoid contac t vit h product. 

EYE PROTECTION: 

Do no t ge t i n eyes. Use safet y eyewear vit h splas h guards or sid e 

shields , chemica l goggles, fac e shields . 

OTHER PROTECTIVE EQUIPMENT: 

Avoid contac t vit h skin . Use protectiv e clothing . Preven t contac t with 

contaminated clothing . Wash contaminated clothing , includin g shoes . 

befor e reuse . 

SECTION IX SPECIAL PRECAUTIONS 

"h o. 
P.40 

« « ~« n „ « «««««««««««„«« f; «««««, „ « „ ¥¥¥ti „ «-,,-«"«Vii K « * ««•.•*•,«««•.•,•,« «/i jy?* 1 

C00 L£iTM? 0SITE S

 AND POLYMERS CO. MATERIAL SAFETY DATA SHEET 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: 

Do no t stor e above 120 deg F. Stor e larg e quantitie s in building s 

designe d t o comply vit h OSHA 1910.106 . Keep away from hea t spark ! and 

flame . Keep container s close d when no t in use and uprigh t t o preven t 

1 E BK O g C • 

OTHER PRECAUTIONS: 

Container s shoul d be grounded when pouring . Do no t take internall y 

Wash hands afte r using and befor e smoking or eating . Emptied container s 

may retai n hazardous residu e and explosiv e vapors. Keep away from heat 

spark s and flame s Do not cut . punctur e or weld on or nea r emptied containers . Follo w al l hazard precaution s give n in thi s data shee t unti l C 0 "Mi2 e

.

r

. ii v «*v" u5!?i?.5l?f n e d ° f destroyed . If thi s produc t i s 

and 

KEEP OUT OF REACH OF CHILDREN POR INDUSTRIAL USE ONLY 

SECTION X Sara Titl e II I Informatio n 

This produc t contain s th e followin g toxi c chemicals subjec t t o the 

reportin g requirements of Sectio n 313 of th e Emergency Plannin g and 

Community Right-To -Knovr Act of 1986 and o f 40 CFR 372 . This law require s 

certai n manufacturer s t o repor t on annual emission s of specifie d tSxi c 

chemicals and chemica l categories. If you are unsure i f you must repor t 

or requir e more-informatio n cal l the EPA Emergency Plannin g and Community 

Right-To-Know Hot Line : B00-S3S-0202 o r 202-479-244 9 ' 

{The FULL Chemical Name can be found i n Sectio n II.'vithi n th e listin g of Exposur e Limit } 

Chemical CAS Number Weight % 

STTRENE MONOMER D00100-42-S 34 oi 

METHYL METHACRYLATE O000BO-62-6 4!8 3 

DISCLAIMER AND LIMITATION OF LIABILITY 

TO THE BEST OF OUR KNOWLEDGE. THE INFORMATION CONTAINEDHEREINISACCURATE " 

THE WARRANTY DESCRIBED HEREIN SHALL BE IN LIEU OF ANY OTHER WARRANTY 

EXPRESS OR IMPLIED. INCLUDING BUT HOT LIMITED TO, ANY IMPLIED WARRANTY OF 

MERCHANTABILITY OF FITNESS FOR A PARTICULAR PURPOSE THERE ARE KO 

WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF THE 

BUYERS SOLE AND EXCLUSIVE REMEDY AGAINST SELLER SHALL BE FOR THE'REPLACEMENT OP THE PRODUCTS OR REFUND OF IHE PURCHASE PRICE IN THE EVENT THAT A 

BUYERS SOLE AND EXCLUSIVE REMEDY AGAINST SELLER SHALL BE FOR THE REPLACEDEFECTIVE CONDITION OF THE PRODUCTS SHOULD BE FOUND TO EXIST NO OTHER 

REMEDY {INCLUDING. BUT NOT LIMITED TOJ INCIDENTAL OR CONSEQUENTIAL DAMAGES 

FOR LOST PROFITS, LOST SALE, INJURY T6 PERSON OR PROPERTY OR ANY OTHER 

INCIDENTAL OR CONSEQUENTIAL LOSS} SHALL BE AVAILABLE TO THE BUYER THE 

SOLE PURPOSE OF THIS EXCLUSIVE REKEDY SHALL BE 30 PROVIDE BUYER WITH 

f•F^.9.Elll«Le^?,HLFS9?y9I^e^.•5lr.^P..OF_THE PURCHASE PRICE OF THE PRODUCTS 

4*o 
P.41 

I i'« -i"i''-'«US-2-2S'»M»-!«p!'. S H.»t.«-M J. ., -. m. a. a. a. -• -. . . .. _ _ 

.«i(l(lllll(lllllllllllllllllllllillllllllil«l(«lll«IKIII(iillKII|li(lllltlll«illill«lll(«llliKIIII«ill(lliltl «4T> 

COOK COMPOSITES AND POLYMERS CO. 

MATERIAL SAFETY DATA SHEET 

,{> Pag e 6 

^«K«'K'M«*W««(*(*M*Mtl«l«««K«*HK«« 1 M*KM»(HHKK««MWK9tK*M-M«tt-M«4 K 

ALLEGED DEFECT COVERED BY THIS WARRANTY {TOGETHER WITH ALL IDENTIFYING 

•US. INCLUDING THE PRODUCT CODE{S}. DESCRIPTION AND DATE OF PURCHASE) 

vm THIRTY {30} DAYS OF THE DISCOVERY OF SUCH DEFECT. FINAL DETERKIH-

>l OF THE SUITABILITY OF THE MATERIAL FOR THE USE CONTEMPLATED. THE 

vtR OF USE AND VHETHER THE SUGGESTED USE INFRINGES ANY PATENTS IS THE 

r RESPONSIBILITY OF THE BUYER. 

+ l 
•MATERIAL SAFETY 

DATA SHEET 

Ashland P.O. BOX 2219 

COLUMBUS, OHIO 43216 

(614) 889-3333 

Telephone 

1(800) 274-5263 

1(800) ASHLAND 

or 

000251 PLIOGRIP 660 0 

THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COKWJN1 CATION STANDARD) 

Page: 3 

Product Name: PLIOGRIP 66CC 

PICKEN PLASTICS INCORPORATED 

4212 ANN AVENUE 

ASHTABULA OH 44004 

ATTN: PLANT MGR./SAFETY DIR. 

03 54 561 7056000-

PRODUCT: 583042 

INVOICE: 837502 

INVOICE DATE: 07/29/9 2 

TO: SAME 

Data Sheet No: 0171547-006.001 

Prepared: 07/31/92 

Supersedes: 05/31/B9 

"^SECTIO N 4-*-A0DUCT~4OE«TIF.<CAT*O N ESZ2E25Z3 

General or Generic ID : POLYURETHANE PREPOLYMER 

DOT Hazard Classification : NOT APPLICABLE 

"SECTIO N 4 4-COMPONENT S 

I F PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SARA TITLE 111 SECTION 313 ARE IDENTIFIED IN THIS SECTION. 

SEE DEFINITION PAGE FOR CLARIFICATION 

mwwtvm SBk. 

INGREDIENT 

POLYURETHANE POLYMER 

MODIFIED METHYLENEDIPHENYL 1SOCYANATE 

CAS # : 39310-05-9 

TALC 

CAS # : 14807-96-6 

POLY(METHYLENEPHENYLENE) P0LY1SOCYANATE 

CAS # : 9016-87-9 

* (by WT) 

43-47 

20-25 

20-25 

5-10 

PEL TLV 

3 MG/M3 2 MS/M3 

Note 

( D 

( 2) 

( 3) 

( A) 

Notes : 

{ 1) PEL/TLV NOT ESTABLISHED. THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 29 CFR 1910.1200 (OSHA HAZARD 

COMMUNICATION STANDARD). 

THIS COMPONENT DOES NOT MEET THE CRITERIA OF A "CONTROLLED PROOUCT" AS DEFINED BY CANADA'S HAZARDOUS 

PRODUCTS ACT. CONTROLLED PRODUCTS REGULATIONS. AND I S LISTED FOR COMPOSITIONAL PURPOSES ONLV. 

( 2) THIS MATERIAL CONTAINS 80 * METHYLENE PHENYLENE 1SOCYANATE (ICI ) (CAS * 101-68-8) WHICH IS SUBJECT TO THE 

REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III . UOl HAS AN OSHA PEL OF 0.02 PPM-CEILING AND AN 

ACGIH TLV OF 0.005 PPM. 8-HOUR TWA. 

PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL 

( 3) AS RESPIRABLE DUST. 

( 4) THIS MATERIAL CONTAINS 55% METHYLENE PHENYLENE 1SOCYANATE (MDl) (CAS # 101-6B-8) WHICH IS SUBJECT TO THE 

REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE 111 . MDl HAS AN OSHA PEL OF 0.02 PPM-CEILING AND AN 

ACGIH TLV OF 0.00 5 PPM, 8-HOUR TWA. 

PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL 

^-•4SECr 4 0 N 4 H -«M4YSI£AL*I>AT A - •U*f*.H* *X-r--&9r.uS*K.t&— 4-«fc».W»-*h' 

Boiling Point 

Vapor Pressure 

Specific Vapor Density 

Specific Gravity 

Percent Volatiles 

Evaporation Rate 

Appearance 

State 

fT-r.-fcp.jur-J-v. -JTIf.-J-J 

for COMPONENT( 20-25%) 392.00 Deg F 

200.00 Deg C) 

5.00 rm Hg 

for COMPONENT( 

NOT APPLICABLE 

5-10%) < 0.01 im. Hg 

€ 68.0 0 Deg? 

( 20.00 Deg C) 

HEAVIER THAN AIR 

1.265 

€ 68.0 0 Deg F 

( 20.00 Deg C) 

SLOWER THAN ETrtR 

HEAVY BROWN SYR'JF 

LIQUID 

«CECflO N 4V-*4«EMN O «tCP-LOS-ION *t «F4)RMAT40 N «***u 

FLAS-t P01NT(U('K ) 

EXPLOSIVE LIMIT 

> 250.0 Deg F 

UNAVAILABLE 

( 121.1 Deg C) 

EXTINGUISHING MEDIA: REGJLAR FOAV. OR ALCOHOL FOAM OR WATER FOG OR CARBON DIOXIDE OF DRY CHEV.rCM. 

CONTINUED 0): PAGE: 2 

42. 
P.43 

MATERIAL SAFETY 

DATA SHEET 

AmhMdllU r.v. bUA uiv 

COLUMBUS, OHIO 43216 

(614) 889-3333 

leiephone 

1(800) 274-5263 o 

1(800) ASHLAND 

•51 PLIOGRIP 660 0 Page: 2\ 

sRDOUS DECOMPOSITION PRODUCTS: Mtv FORM. TOXIC MATERIALS:, CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS 

HYDROCARBONS, NITROGEN COMPOUNDS. HYDROGEN CYANIDE. E"d. 

IfSFIGHTlNG PROCEDURES: WEAR SELF-COI.TAINED BREATHING AI-FARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE 

PRESSURE DEMAND MODE AND FULL BODY PROTECTION WHEN FIGHTING FIRES. 

WATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER. 

ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. 

iPKIAL FIRE I EXPLOSION HAZARDS: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE 

PROOUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. 

.^w^t.*.*-.^^!—TMw»tcno N •mi-MHAim <*IAZARD^>AT A «««»HWM « 

;.RRlSSlBi_E EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT; SEE SECTION 11 AND SECTION IX. 

iFFICTS OF ACUTE OVEREXPOSURE: 

rYES - EXPOSURE TO LIQUID OR VAPOR MAY CAUSE MILD EYE IRRITATION. SYMPTOMS MAY INCLUDE BURNING. TEARING AND 

REDNESS. 

"•KM - EXPOSURE MAY CAUSE MILD SKIN IRRITATION, SYMPTOMS MAY INCLUDE REDNESS AND BURNING. 

.:•* - REPEATED CONTACT MAY CAUSE SENSITIZATION. 

3REATHING - CAN CAUSE NASAL AND RESPIRATORY IRRITATION, TIGHTNESS OF CHEST, COUGHING, HEADACHE, AND SHORTNESS 

OF BREATH. CAN CAUSE ALLERGIC SENSITIZATION. 

SWAMLOWING - CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA. ASPIRATION OF MATERIAL INTO 

THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WIC H CAN BE FATAL. 

F1FST AID : 

1F®>' SKIN: REMOVE CONTAM1NATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. LAUNDER CONTAMINATED 

CLOTHING BEFORE REUSE. I F SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. 

REMOVE CONTAMINATED SHOES PROMPTLY. DISCARD SHOES SATURATED WITH THIS PRODUCT. 

IF IN EYES: IF SYMPTOMS DEVELOP. MOVE INDIVIDUAL AWAY FROM. EXPOSURE AND INTO FRESH AIR. FLUSH EYES WITH CLEAN 

WATER WHILE HOLDING EYELIDS APART. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. 

IF SWALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET, AND GET MEDICAL ATTENTION. ASPIRATION OF 

MATERIAL INTO THE LUNGS DUE

 T 0 VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. 

IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF TIGHTNESS OR CONGESTION IN CHEST DEVELOPS, GET 

MEDICAL ATTENTION. 

I F AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING 

HAS STOPPED. GIVE ARTIFICIAL RESPI RATI ON. KEEP PERSON WARM. QUIET, AND GET MEDICAL ATTENTION. 

FROAARY ROUTE(S) OF ENTRY: 

INHALATION. SKIN CONTACT 

EFFECTS OF CHRONIC OVEREXPOSURE: 

PROLONGED INHALATION OF TALC DUST IK HIGH CONCENTRATIONS CAN CAUSE PULMONARY FIBROSIS. 

A STUDY BY THE INTERNATIONAL ISOCVANATE INSTITUTE SUGGESTS THAT PROLONGED EXPOSURE TO HIGH CONCENTRATIONS 

OF POLYMERIC METHYLENE B1SPHENYLISOCYANATE (MDl) MAY INCREASE THE INCIDENCE OF TUMORS IN THE LUNGS. THIS 

STUDY ENTAILED A LIFETIME EXPOSURE OF MALE AND FEMALE RATS TO AN AEROSOL OF POLYMERIC MDl AT LEVELS UP TO 

6 MG/M3. AEROSOL EXPOSURES WERE USED BECAUSE OF THE DIFFICULTY OF GENERATING A VAPOR ATMOSPHERE OF HOI 

HIGH ENOUGH TO CARRV OUT A MEANINGFUL STUDY. AT THE HIOiEST EXPOSURE LEVELS THERE WAS AN INCREASE IN A 

BENIGN TUMOR OF THE LUNG WHICH WAS STATISTICALLY SIGNIFICANT IN THE MALE RATS, BUT NOT THE FEMALE. ONE 

MALE RAT ALSO HAD A MALIGNANT TUMOR OF THE LUNG. TUMOR FORMATION WAS ACCOMPANIED BY THE ACCUMUUTION OF A 

YELLOW MATERIAL IN THE LUNGS DURING THE COURSE OF THE STUDY AND PRELIMINARY EVALUATION OF THE REPORT 

SUGGESTS THAT THESE EFFECTS WERE RELATED TO PROLONGED IRRITATION. THE TUMOR EFFECTS NOTED IN THE STUDY 

OCCURRED AT LEVELS THAT WOULD NOT BE TOLERATED IN A WORKPLACE DUE TO THE IRRITANT AND SENSITIZING 

PROPERTIES OF MDl AND I N THE ABSENCE OF PROLONGED HIGH EXPOSURES LEADING TO IRRITATION AND SENSITIZATION. 

IT IS UNLIKELY THAT TUMOR FORMATION WOULD OCCUR. HOWEVER. THIS REPORT EMPHASIZES THE NEED TO MAINTAIN 

EXPOSURES BELOW THE RECOMMENDED OCCUPATIONAL EXPOSURE LIMITS. 

OIHIEXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A CAUSE OF THE FOLLOWING EFFECTS IN 

HUMANST. RESPIRATORY SENSITIZATION, SKIN SENSITIZATION 

m2 i*i>w«nCECI I O N -W l T*tAC n tl H ¥•-«•> AT A ^"'**tow»'»^'»w''^St(.^?»--«fcf>»,Kc,-*.=r'*» •«««• 

UIZARDOUS POLYMERIZATION: CAN OCCUR — AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS. AND WATER. 

STABILITY: STABLE 

^COMPATIBILITY: AVOID CONTACT WITH:, STRONG ALKALIES, STRONG MINERAL ACIDS.. WATER. EXCESSIVE HEAT 

»p 

\ 

.<WW*M^-«W>W« S EC 11 ON «I 4 -%£P4 4.-t«40R AEAK-tfAOCEOURE S W^M H -WSRSUSe**?. • * Jfi*STS ^y.;_ 

TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: 

SHALL SPILL: ABSORB LIQUID Ot.' VERM'.CULITE, FLOOR ABSORBENT. OR OTHER ABSORBENT MMTERIAL AND TRANSFER TO HOOD. 

W-.GE SPILL: PERSONS N0T WEARING PROTECTIVE EOUIPMENT SKX'LC BE EXCLUDED FROM AREA OF SrlLL UNTIL CLEAN-UP HAS 

BEEN COMPLETED. ST0 SF1LL AT SOJRCE. DIKE AREA OF SHIL TO PREVENT SPREADING. PUM" LIOUID TO SALVAGE 

TALK. NEUTRALIZE SPILL WITH AN AOJEOUS SOLUTION OF AHON1A. REMAINING LIQUID MiY BE TAKEN VIP ON SAND. 

CLAV, EARTH. FLOO" ABSORBENT. OR OTHER AESORBENT MI'ERiAL AND SHOVELED INTO CONTAINERS. 

HASTE DISPOSAL METHOD: 

WALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL REGULATIONS. 

COKTIKUED O): F7.Gr: 3 

to 
• MATERIAL SAFETY 

DATA SHEET 

Ashland 

P.44 

^?.0. BOX 2219 

COLUMBUS, OHIO 43216 

(614) 889-3333 

Telephone 

1(800) 274-5263 or 

1(800) ASHLAND 

000251 

E rnfl.Jaa 

PLIOGRIP 6600 

ECT*ON «UII-i£P4 4.1<*DR AtAK^ilOCeDURE S 

Page: 3 

nncuiii y 

LARGE SPILL: DESTROY BY LIQUID INCINERATION IN ACCORDANCE WITH APPLICABLE REGULATIONS. 

E CM ON «l«l<-J>«OT£Cn«E«OUI>PMEMr*i*0«E«UBEO 

RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION 

II), A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. 

OSHi REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED 

CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE 

IMPLEMENTED TO REDUCE EXPOSURE. 

VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE 

BELOW TLV(S). 

PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NATURAL RUBBER, POLYVINYL ALCOHOL 

EYE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED: HOWEVER, OSHA 

REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) 

OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. 

-SECTIO N 4X-SPECIA L PRECAUTION S OR OTHE R -COMMENTS 

CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES 

(VAPOR. LIQUID, AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. 

EXPOSURE TO AEROSOLS AND MISTS WHEN MATERIAL IS SPRAYED MAY PRESENT A GREATER RISK OF INJURY FROM COMPONENTS 

BECAUSE HIGHER CONCENTRATIONS ARE IN THE ATMOSPHERE THAN RESULT FROM VAPOR ALONE. PROVIDE ADEQUATE 

VENTILATION AND IF NECESSARY, USE RESPIRATORY PROTECTION. 

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING 

WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS 

CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. 

A>4-
P.45 

AMPLICATION cX,R A i-Z.Sl.1 xO Cr-L^I 

AN AIR OOOTAHINAMT SDURCE 

ATTACHMENT 2 

Picken's Plastics, Inc. 

Facility Name 

4212 Ann Ave. 

Paul Nicholas 

Facility Address 

Ashtabula, Ashtabula, 

City County 

(216) 992-4000 

44004 

Zip 

Telephone Area 

0204030269R001 

Person to Contact 

P.O. Box 1279 

Mailing Address 

Ashtabula, OH 

City Sute 

(216) 992-4000 

44004 

Zip 

Number Telephone 

3089 

(Application No., if this is a renewal application) Std. Ind. Class. Code 

1. Conplete and attach any of the following appendices nost appropriate to the 

air -contaminant source. In addition, a compliance time schedule form is to 

be attached when applicable. Check as appropriate the following: 

_Appendix A, Process 

"Appendix B, Fuel-Burning Equipment" 

[Appendix C, Incinerator 

"Appendix D, Surface Coating or 

Printing Operation 

_Appendix E, Storage Tank 

_Appendix H, Gasoline Dispensing 

Facility 

_Appendix J, Loading Rack at Bulk 

Gasoline Plant or 

Terminal 

_Appendix K, Surfaoe Coating 

Line or Printing Line " 

Appendix L, Solvent Metal 

Cleaning 

_Appendix M, Fugitive Dust 

Emission Sources 

Specify Appendix No. 

_Appendix N, Rubber Tire 

Manufacturing 

Appendix 0, Dry Cleaning 

Facility 

_Appendix P, Landfills 

_Other Appendi x_ 

^Compliance Time Schedule 

2. Description of Source (sane as used on appendix): Fiberglass Spray-up Booth 

3. Your identification for Source (same as used on appendix): 

—5> Spray Booth B5-A 

I, .being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents are submitted as part of this application (describe all 

attachments): 

Thomas J. Picken 

Authorized Signature* 

President, Picken's Plasties, Inc 

Titl e 

Jan. 29, 1993 ______ 

Date 

•Pursuant to OAC Rule 3745-35-02(B) (Permit to Operate). 

Operation of an air contaminant source without an effective permit to operate is 

prohibited to 3704.05 Ohio Revised Co>3. Peoe 1 EPA-3161 

A,£> 
P.46 

'ccar.se No. 

Source No. 

Applicatio n 

/ 

/ 

No. _ 

/ 

/ 

/ 

•** 

•APPENDIX D 

SURFACE COATING OR PRINTING OPERATION 

1. This appendix is submitted for a: 

D Surface coating operation (check one below): 

Paint spray booth Flow coating 

Dip tank Roller coating 

X Spray Coating (Other than paint spray booth) 

Other surface coating operation, describe 

DPrinting or lithographic operation. 

2. Name of operation Fiberglass Spray-up ; Your identification ?~53 

Year Installed 

3. Is this operation succeeded by a heated drying or baking operation? EJ Yes Q No 

If yes, indicate operating temperature of oven 110 F. 

A. Normal operating schedule: 16 hours/day, 5 days/wk., 52 wks./year. 

PAINT SPRAY BOOTH " . : • -

5. Type of spray booth: Ef Enclosed •Conveyor rjDowndraft . 

• Other, describe 

6. Booth manufacturer Devilbiss Make o r M0(jel No. XPO 

7. Type of spraying: • Air gun EO Airless • Electrostatic 

D Other, describe '__ 

8. Spraying operation is: 0Manual D Automatic 

9. Fan manufacturer Dayton '_ Make or Model No. 3N333A 

10. BootVs exhaust is equipped with: • Water wash (Complete item 11) 

ED Exhaust filters (Complete item 12) 

D Baffles 

• Other, describe 

• None 

11. Water wash: (a) Is water recirculated? DYes D No 

(b) Is a chemical added to the water? DYes O.No 

(c) Is material reclaimed fron wash water. DYes D No 

(d) Describe method for disposal of waste materials:

 NA 

* Does not include metal plating 

A fc 
P.47 

L3. 

14. 

15. 

16. 

L7. 

(a) Type of material: B Fiberglas D Aluminum 

• Other, describe 

(b) Filter size (inches): Length 20" Width 20" Thickness 2" 

No. of filters: 8 No. of filter changes: 51 times per year 

Describe material painted Mixture 30% Fiberglass, 69% Polyester Resin, 1% MEK P. 

ALL OPERATIONS (Except paint spray booth) 

Describe type of operation Fiberglass/Resin/Catalyst is sprayed on the surface of a 

fiberglass part mold. 

Describe method of coating 

spray equipment. 

or printing Chopped 

Identify and describe type(s) of material coated 

reinforced plastic part is coated with part raw 

Fiberglass 

or printed 

materials. 

is applied 

Base mold 

with 

for 

i airless 

Fiberglass 

ALL OPERATIONS 

Complete the following information for each general type of surface coating of printing 

material. Report on the material as it is employed after the addition of any pigments, 

solvents, etc. If there are aore than three types of materials, furnish the same data 

for the additional maieris-ls on a separate sheet or another appendix form. 

(a) Material -employed Polyester Resin/Mix 6604T Density 9.87 

Solids content 48.36% by volume or % by weight . 

Solvent content51 »64 % by volume; Solvent density 7.61 lbs./gallon 

Normal application schedule

 5 hrs./day, * days/wk., 7.61 wks ./year. 

Quantity used (gallons/hour): Normal 4.0 Maximum Unknown . 

(gallons/year): 496 , } 

Complete the solvent composition by identifying each solvent component 

and its respective X by volume of the total solvent. (The % by volume 

should tozai to 100%). 

_lbs./gallon 

Solvent Composition 

Solvent 

Styrene 

Dimethyl Phthalate 

Hexylene Glycol 

X by Volume 

98.83 

.844 

.203 

* 

Y 

•J 

•J 

Solvent 

MEK 

Solvent Composition 

X by Volume 

.116 

*. 

N 

* If solvent is photochemically reactive enter "Y", if not photochemically 

reactive enter "N", if unknown enter "U". 

Is the material photochemically reactive? 0Yes • No • Do not know 

Al 
P.48 

•(b) Material employed polyester Resin Mix Q60225 Density

 9 - ° 2 

Solids content 45.25% by volume or 2 by weight 

lbs./gallcn 

Solvent content54.75 2 by volume Solvent density 7.59 lbs./gallon 

Normal application schedule: 12.5 hrs./day. 5 days/wk., 52 wks./year. 

Quantity used (gallons/hour) : Normal 4 Maximum Unknown 

(gallons/year): 12,910. 

Complete the solvent composition by identifying each solvent component and its 

respective % by volume of the total solvent. (The 2 by volume should total to 

100%). 

Solvent Composition 

Solvent 

Styrene 

Dimethyl Phthalate 

Hexylene Glycol 

% by Volume 

97.4 

.79 

• 19 

* 

Y 

N 

N 

Solvent Composition 

Solvent 

MEK 

Mineral Spirits 

2 by Volume 

.109 

l.bO 

* 

N 

N 

* If solvent ls photochemically reactive enter "Y", if not photochemically 

Teactive enter "N", if unknown enter "U". 

Is the material photochemically reactive? EfYes 

i-2 

"Tby weight 

• No 

(c) Material employed Polyester Resin Mix 75-3730Density

 9-01 

Solids content

 42- ab 2 by volume or 

• Do not know 

lbs./gallon 

Solvent content 57.04 2 by volume Solvent density 7.59 lbs./gallon 

Normal application schedule:j____hrs. /day, 5 days/wk. ,_52_wks./year. 

Quantity used (gallons/hour): Normal 4 Maximum Unknown 

(gallons/year): 2608 

Complete the solvent composition by identifying each solvent component and its 

respective % by volume of the total solvent. (The 2 by volume should total to 

1002). 

1 Solvent Comi 

I Solvent 

| Styrene Monomer 

| Dimethyl Phthalate 

\Hexylene Glycol 

position 

2 by Volume 

97.54 

.76 

.18 

* 

Y 

N 

N 

Solvent Composition 

Solvent 

MEK 

Mineral Spirits 

2 by Volume 

.105 • 

1.40 

* 

N 

N 

* If sclveur is photochemically reactive enter "Y", if not photochemically 

reactive enter.. "N", if unknown enter "U". 

Is the material photochemically reactive? ©Yes • No • Do not know 

18. Identify all liquid organic cleanup materials for this process and Indicate the amount 

used per average operating day and per year. 

Cleanup Material 

Acetone 

Gallons Used 

Daily 

6.937 

Yearly 

1803 

Se/one • R-i-yfm'le 

* If material is photochemically reactive enter "Y", if not photochemically reactive 

enter "N", if unknown enter "U". 

*" ** t » • f, 

4-a 
P.49 

points of al l materials and finished products. Label al l materials including 

aiTborne contaminants and other vast e materials. Label th e process equipment and • 

contro l equipment. 

CONTROL EQUIPMENT 

20. Type of contro l equipment: QNone 

• Incinerator, Temp. °F, Thermal/Catalytic (Circl e one) 

D Adsorption, 'describe 

• Condensation, describe 

E Other, describe Filtered Spray Booth 

21. Manufacturer Devilbiss Model Ko. XDO Year lnstalled_ 

22. Percent collectio n or removal efficiency: Design N/A 2 Operating N/A 

23. For non-incineration method Identify specific pollutant controlled Polyester Resin 

STACK DATA 

2A. Your stac k identificatio n

 34 " Diameter Round Stack 

25. Are othe r sources vented to this stack? ^EfVes EjNo 

If yes, identify sources j^asa_=-B*-JDjB£Bg5c 

26. Type: " EQ Round, top inside diameter dimension 34" 

• Rectangular, top. inside dimensions (L) N/A pc (W) N/A 

27. Height: Above roof 0' ft. , above ground 8' ft . 

28. Exit gas: Temp.

 AMB

 °F_ Volume 4704 " -' ACFM, Velocity 175 ft./min. 

29. Continuous monitoring equipment: DYes ©No .. . 

If yes, indicat e Type -• ' - •» Manufacturer_. 

Make or Model » Pollutant (s) monitored • 

30. Emission data : Emissions from this source have been determined and such data is 

included with l±±s appendix: " Dye s O^ o 

If yes, check method: • Stack Test • Emission factor • Material balance 

Completed by j/Kg-zf&teTYvo&vf .Date 1-24-93 

Theodore Hebert 

•-2103. 

*1 
.APPLICATION KX. A PERKTT TO OPERATE 

AN AIR COOTAMINANT SOURCE 

P.50 

Picken's Plastics, Inc. 

Facility Name 

4212 Ann Ave. 

Paul Nicholas 

Person to Contact 

P.O. Box 1279 

Facility Address 

Ashtabula, .Ashtabula 44004 

Mailing Address 

Ashtabula, OH 44004 

City County 

(216)992-4000 

Zip City Stat e 

(216)992-4000 

Zip 

Telephone Area 

0204030269 R004 

Number Telephone 

3089 

(Application No., if this is a renewal application) Std. Ind. Class. Code 

1. Complete and attach any of the following appendices aost appropriate to the 

a i r contaminant source. In addition, a compliance time schedule form is to . 

be attached when applicable. Check as appropriate the following: 

_Appendix L, Solvent Metal 

Cleaning 

_Appendix Kf Fugitive Dust 

Emission Sources 

2. 

3. 

Appendix A, Process 

Appendix B, Fuel-Burning Equipment" 

Appendix C, Incinerator 

X Appendix D, Surface Coating or 

Printing Operation 

Appendix E, Storage Tank 

Appendix H, Gasoline Dispensing 

Facility 

Appendix J, Loading Rack at Bulk 

Gasoline Plant or 

Terminal 

Appendix K, Surface Coating " 

•".. Line or Printing Line Cc-mpliance Time Schedule 

Description of Source (.same as used on appendix); Fiberglass Spray-up Booth 

Your identification for Source (same as used on appendix): 

» Spray Booth B5B 

Specify Appendix No. 

_Appendix N, Rubber Tire 

Manufacturing 

Appendix 0, Dry Cleaning 

Facility 

^Appendix P, Landfills 

"Other Appendix 

I, being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents ar e submitted as part of this application (describe al l 

attachments): 

Thomas J. Picken 

Authorized Signatufte*-/ 

President, Picken's Plastics, Inc. 

Titl e 

March 30, 1993 

Date 

•Pursuant t o OAC Rule 3745-35-02{B) (Permit to Operate). 

Operation of an air contaminant source without an effective permit to operate is 

. _ • ••..*..-• . . --—• r.r r.-'r. r-..-:,.--- ToS-. p£ or- ? EPP.-21C) 

r" r. 
P.51 

j\s e No. 

-ce No. 

.^cation 

/ 

/ 

No. _ 

/ 

/ 

/ 

.*# 

APPENDIX D 

* 

SURFACE COATING OR PRINTING OPERATION 

This appendix is submitted for a: 

D Surface coating operation (check one below): 

Paint spray booth Flow coating 

Dip tank Roller coating 

X Spray Coating (Other than paint spray booth) 

Other surface coating operation, describe , • 

• Printing or lithographic operation. 

Name of operation Fiberglass Spray-up ; Your identification B5B 

Year Installed 

Is this operation succeeded by a heated drying or baking operation? Q Yes • No 

If yes, indicat e operating temperature of oven 110 F. 

Normal operating schedule: 8 hours/day, 5 days/wk., 52 wks./year. 

PAINT SPRAY BOOTH " - - -

Type of spray booth: 10 Enclosed •Conveyor DDowndraft 

• Other, describe 

Booth manufacturer Devilbiss Make or Model No. JJ42T2 

Type of spraying: • Air gun ©Airless D Electrostati c 

D Other, describe - ' 

Spraying operation is: 13Manual D Automatic 

Fan manufacturer Dayton Make or Model No. 3N553A 

». Booth's exhaust is equipped with: D Water wash (Complete item 11) 

0 Exhaust filter s (Complete item 12) 

D Baffles 

D Other, describe 

D None 

Water wash: (a) Is water recirculated? DYes D No 

(b) Is a chemical added to the water? DYes D.No 

N/A

 l'=

^

 I s Eateria l

 reclaimed from wash water. DYes D No 

(d) Describe method for disposal of vaste materials: 

Dies hot include metal plating 

X 5 \ 
P.52 

13. 

14. 

15. 

16. 

17. 

_.: filters: 

(a) type of material: (3 Fiberglas • Aluminum 

D Other, describe 

(b) Filte r size (inches): Length 20" Width 20" Thickness Zl 

No. of filters: 4 No. of filter changes: 51 times per year 

Describe material painted Mixture 30% Fiberglass, 69% Polyester Resin. 1% MEK P. 

ALL OPERATIONS (Except paint spray booth) 

Describe type of operation Fiberglass/Resin/Catalyst is sprayed on the surface of 

a fiberglass part mold. 

Describe method of coating or printing Chopped fiberglass is applied with airless 

spray equipment. 

Identify and describe type(s) of material coated or printed Base mold for 

fiberglass reinforced plastic part is coated with part raw materials. 

ALL OPERATIONS 

Complete the following information for each general type of surface coating or printing 

material. Report on the material as It is employed after the addition of any pigments, 

solvents, etc. If there are more than three types of materials, furnish the same data 

for the additional materials on a separate sheet or another appendix form. 

(a) Material employed Polyester Resin Mix O6022S Density q.Q2 lbs./gallon 

Solids content45.25 I by volume or Z by weight 

Solvent content"?>4.75 Z by volume; Solvent density 7.59 lbs./gallon 

Normal application schedule 4.5hrs./day, 5 days/wk., 52 wks./year. 

Quantity used (gallons/hour): Normal"" 6 Maximum Unknown 

(gallons/year): 6336 

Complete the solvent composition by Identifying each solvent component 

and its respective Z by volume of the total solvent. (The Z by volume 

should total to 100Z). 

Solvent Composition 

Solvent 

Styrene 

Dimethyl Phthalate 

Hexylene Glycol 

Z by Volume 

97.4 

.79 

.19 

* 

Y 

N 

N 

Solvent Composition 

Solvent 

MEK 

Mineral Spirits 

Z by Volume 

-JQL 

J_-i 

* If solvent ls photochemically reactive enter "Y", if not photochemically 

reactive enter "N", If unknown enter "U". 

JS 

Is the material photochemically reactive? files • No • Do not know 

EPA-3103 

3/11/P1 D-2 

q- z 
P.53 

(b) Material employed Polyester Resin Mix 75-3730pen8ity 9.01 lbB./gallon 

Solids content42.96 Z by volume or Z by weight 

Solvent content57.04 Z by volume Solvent density 7.59 lbs./gallon 

Normal application schedule: 3 hrs./day. 5 days/wk., 52 vks./year. 

Quantity used (gallons/hour): Normal 6 Max.iarum Unknown 

(gallons/year): 4740 

Complete the solvent composition by identifying each solvent component and Its 

respective Z by volume of the total solvent. (The Z by volume should total to 

100Z). 

Solvent Composition 

Solvent 

Styrene Monomer 

Dimethyl Phthalate 

Hexylene Glycol 

Z by Volume 

31M 

.76 

.18 

* 

Solvent Composition 

Solvent 

TffiT" 

Mineral Spirit Tl.40 

ZZ b by y Volume 

•nuT 

* If solvent 16 photochemically reactive enter 'V, if not photochemically 

reactive enter "N", If -unknown enter "U". 

Is the material photochemically reactive? EXYes • No 

(c) Material employed Polyester Resin Mix 6604T Density 9.87 

Solids content by volume or 

• Do not know 

lbs./gallon 

Z by weight 

Solvent content"51.64 Z by volume Solvent density 7.61 lbs./gallon 

Normal application schedule: 1 hr6./day, 1 days/wk., 4T wks./year. 

Quantity used (gallons/hour): Normal 6 Maximum Unknown 

(gallons/year): 254 

Complete the solvent composition by identifying each solvent component and its 

respective Z by volume of the total solvent. (The Z by volume should total to 

100%). 

Solvent Com 

Solvent 

Styrene 

Dimethyl Phthalate 

Hexylene Glycol 

position 

Z by Volume 

98.83 

.844 

.203 

* 

Y 

N 

N 

Solvent Composition 

Solvent 

MEK 

Z by Volume 

.116 

* 

N 

* If solvent is photochemically reactive enter "Y", if not photochemically 

reactive enter. "N", If unknown enter "U". 

Is the material photochemically reactive? E Yes • No • Do not know 

IS. Identify all liquid organic cleanup materials for this process and Indicate the amount 

used per average operating day and per year. 

Note: 50% of the 

daily/yearly use 

reported here is 

recovered for recycle. 

* If material is photochemically reactive enter "Y", if not photochemically reactive 

enter "N", If unknown enter

 HU". 

Cleanup Material 

Acetone 

* 

N 

Gallons Used 

Daily 

3.46 

Yearly 

900 

EPA-3103 D-3 

Cb 
P.54 

19. A PROCESS FLOW DUGRAM MUST BE INCLUDED WITH THIS .APPENDIX. Show entry and exit 

points of al l materials and finished products. Label al l materials Including 

airborne contaminants and other vaste materials. Label the process equipment and 

control equipment. 

CONTROL EQUIPMENT 

20. Type of control equipment: DNone 

• Incinerator, Temp. °F, Thermal/Catalytic (Circle one) 

D Adsorption, describe 

D Condensation, describe 

B Other, describe Filtered Sprav Booth 

21. Manufacturer Model No. Year Installed^ 

22. Percent collection or removal efficiency: Design 99.0 Z Operating 

23. For non-lnclneratlon method identify specifi c pollutant controlled Polyester Resin Solids 

STACK DATA 

24. Your stack identification B5B 

25. Are other sources vented to this 6tack? • Yes 13No 

If yes, identify sources 

26. Type: -0Round, top Inside diameter dimension 27" 

• Rectangular, top inside dimensions (L) x (W)_ 

27. Height: Above roof 7 ft. , above ground 32 ft . 

28. Exit gas: Temp. -Amb

 0F, Volume 3093 ACFM. Velocity 115 ft./min. 

29. Continuous monitoring equipment: QYes QNo 

If yes, indicate Type , Manufacturer 

Make or Model , Pollutant (s) monitored 

30. Bnission data: Emissions from this source have been determined and such data IE 

Included vith this appendix: - Dye s jQNo 

If yes, check method: • Stack Te6t • Emission factor • Material balance 

Completed by *ffi„ JL j fliWiJ .Date^-3/ te 

Theodor Hebert 

EPA-3103 

?/*l/Bl D-4 

£ 4-
/vrri_xv-AlXUi r*w-K a fLM'Ul A*-1

 uuvu u 

AN AIR CONTAMINANT SOURCE 

P.55 

Picken's Plastics, Inc. 

Facility Name 

Paul Nicholas 

4212 Ann Ave. 

Person to Contact 

P. 0. Box 1279 

Facility Address 

Ashtabula, Ashtabula 44004 

Mailing Address 

Ashtabula, OH 44004 

City County 

(216) 992-4000 

Zip City State 

(216) 992-4000 

Zip 

Telephone Area 

0204030269 R005 

Number Telephone 

3089 

(Application No., if this is a renewal application) Std. Ind. Class. Code 

1. Complete and attach any of the following appendices nost appropriate to the 

air contaminant source. In addition, a compliance time schedule form is to 

be attached when applicable. Check as appropriate the following: 

_Appendix L, Solvent Metal 

Cleaning 

^Appendix M, Fugitive Dust 

Emission Sources 

2. 

3. 

Appendix A, Process 

Appendix B, Fuel-Burning Equipment" 

Appendix C, Incinerator 

X Appendix D, Surface Coating or 

Printing Operation 

Appendix E, Storage Tank 

Appendix H, Gasoline Dispensing 

Facility 

Appendix J, Loading Rack at Bulk 

Gasoline Plant or 

Terminal 

Appendix K, Surface Coating \ 

*'.. Line or Printing Line Conpliance Time Schedule 

Description of Source (same as used on appendix); Fiberglass Spray-up Booth 

Your identification for Source (same as used on appendix): 

> Sprav Booth B5C , 

Specify Appendix No. 

_Appendix N, Rubber Tire 

Manufacturing 

Appendix 0, Dry Cleaning 

Facility 

^Appendix P# Landfills 

"Other Appendix 

I, being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents are submitted as part of this application (describe all 

attachments): 

Thomas J. Picken 

Authorized Signatu 

President, Picken' £ Plastics, Inc. 

Title 

March 30, 1993 

Date 

•Pursuant to OAC Rule 3745-35-02(B) (Pennit to Operate). 

Operation of an air contaminant source without an effective permit to operate is 

— •'*•••'.-* 1'- 3704. OS• Cr.:-- F-vised Cooe. Pep-' ? E*?.-31£l 

5-5 
P.56 

\ s e No. 

.rce No. 

plication 

/ 

/ 

No. _ 

/ 

/ 

/ 

+. 

•APPENDIX D 

* 

SURFACE COATING OR PRINTING OPERATION 

This appendix is submitted for a: 

D Surface coating operation (check one below): 

Paint spray booth Flow coating 

Dip tank Roller coating 

X Spray Coating (Other than paint spray booth) 

Other surface coating operation, describe 

\s 

> . 

S. 

7, 

8» 

9. 

; Your identification B5C 

D Printing or lithographic operation. 

Name of operation Fiberglass Spray-up 

Tear Installed 

Is this operation succeeded by a heated drying or baking operation? • Yes 

If yes, indicat e operating temperature of oven 110 °F. 

Normal operating schedule: 16 hours/day, 5 days/wk., 52 wks. /year. 

PAINT SPRAY BOOTH 

• Downdraft 

• No 

Type of spray booth: 

Booth manufacturer Binks 

0 Enclosed • Conveyor 

D Other, describe 

Make or Model No. 30-2305 

Type of spraying: D Air gun 0 Airless 

D Other, describe 

D Electrostati c 

Spraying operation is: 

Fan manufacturer Davton 

©Manual • Automatic 

Make or Model No. 3N558A 

0„ Booth's exhaust is equipped with: • Water wash (Complete item 11) 

0 Exhaust filters (Complete item 12) 

O Baffles 

D Other, describe 

D None 

Water wash: (a) Is vater recirculated? DYes Q No 

(b) Is a chemical added to the vater? DYes O.No 

N/A (c) Is material reclaimed from wash vater. DYes • No 

(d) Describe method for disposal of vaste xaaterials: 

Does not include metal plating 

tjG, 
P.57 

13. 

14. 

15. 

16. 

17. 

(a) Type of material: Q Fiberglas • Aluminum 

D Other, describe 

(b) Filter sire (inches): Length 20" Width 20" Thickness 2" 

No. of filters: 14 No. of filter changes: 51 t.lmes per year 

Describe material painted Mixture 30% Fiberglass, 69% Polyester Resin, 1% MEK P. 

•ALL OPERATIONS (Except paint spray booth) 

Describe type of operation Fiberglass/Resin/Catalyst is sprayed on the surface of 

a fiberglass part mold. 

Describe method of coating or printing Chopped Fiberglass is applied with airless 

spray equipment. 

Identify and describe type(s) of material coated or printed

 Bas e m°ld for fiberglass 

reinforced plastic part is coated with part raw materials. 

•ALL OPERATIONS 

Complete the following information for each general type of surface coating or printing 

material. Report on the material aa it is employed after the addition of any pigments, 

solvents, etc. If there are more than three types of materials, furnish the same data 

for the additional materials on a separate sheet or another appendix form. 

(a) Material employed Polyester Resin Mix Q6022S Density 9.02 

Solids content45.25 Z by volume or Z by weight 

lbs./gallon 

Solvent content54.75 Z by volume; Solvent density 7.59 

Normal application schedule 12 hrs./day, 5 days/wk., 52 

Quantity used (gallons/hour): Normal 5 

(gallons/year): 15.600 

Maximum 

_ lbs./gallon 

wks./year. 

Complete the solvent composition by identifying each solvent component 

and its respective Z by volume of the total solvent. (The Z by volume 

should tota l to 100Z). 

Solvent Composition 

Solvent 

Styrene 

Dimethyl Phthalate 

Hexylene Glycol 

Z by Volume 

y/.4 

.79 

.iy 

* 

¥ 

N 

M 

Solvent Composition 

Solvent 

MkR 

Mineral Spirits 

Z by Volume 

.109 

1.5 

* 

N 

N 

* If solvent ls photochemically reactive enter "Y", if not photochemically 

reactive enter "N", if unknown enter

 MU". 

Is the material photochemically reactive? 0 Yes • No • Do not know 

EPA-3103 

3/11/81 D-2 

Sl 
P.58 

(b) Material -employed Polyester Resin Mix 75-3730Density 9.Q1 

Solid6 content42.96 Z by volume or 

lbs./gallon 

Z by veight 

Solvent content 57.04 Z by volume Solvent density 7.59 lbs./gallon 

Normal application schedule: 4 hrs./day, 5 days/wk.. 52 vks./year. 

Quantity used (gallons/hour): Normal 4 Maximum UAW-ftnvi'vt 

(gallons/year): 4100 

Complete the solvent composition by identifying each solvent component and its 

respective Z by volume of the total solvent. (The Z by volume should total to 

100Z). 

Solvent Composition 

Solvent 

Styrene Monomer 

Dimethyl Phthalate 

Hexylene Glycol 

Z by Volume 

97.54 

.76 

.16 

* 

Y 

Solvent Composition 

Solvent 

MEK 

Mineral Spirits 

Z by Volume 

.105 

1.40 

* 

* If solvent is photochemically reactive enter "Y", if not photochemically 

reactive enter "N", if unknown enter "U". 

Is the material photochemically reactive? 

(c) Material employed 

Solids content \ Z by volume or 

Solvent content NS by volume Solvent density 

ED Yes • No 

Density / 

Normal application schedule: hrs./day. 

Quantity used (galIons/hour): Normal 

(gallons/year 

Z by veight 

days/wk/, 

/Max' 

HJDo not know 

lbs./gallon 

lbs./gallon 

vks./year. 

z 

-Iimiffl 

Complete the solvent compositlonNby identifying each solvent component and it6 

respective X by volume of the totai\solven£< (The Z by volume should total to 

100Z). 

| Solvent Com 

Solvent 

: 

position / 

X by Volume 

/ 

* Solvent 

Solvent Composition 

\ ~ 

Z by Volume * 

/ 

* If solvent is photochemically reactive enter "Y", if 

reactive enter. "N", if unknown enter "U". 

t photochemically 

/ 

Is the material photochemically reactive? D Yes Do not know 

18. Identify al l liquid organic cleanup materials for this process and indicate the amount 

used per average operating day and per year. 

Note: 50% of the 

daily/yearly use 

reported is recovered 

for recycle. 

* If material is photochemically reactive enter "Y", if not photochemically reactive 

enter "N", i f unknown enter "U". 

Cleanup Material 

Acetone 

* 

N 

Gallons Used 

Daily 

6.937 

Yearly 

18m 

rl>;-3)o? 

9i 
P.59 

19. A PROCESS FLOW DIAGRAM MUST BE INCLUDED WITH THIS APPENDIX. Show entry and exit 

points of al l materials and finished products. Label al l materials Including 

airborne contaminants and other vaste materials. Label the process equipment and 

control equipment. 

CONTROL EQUIPMENT 

20. Type of control equipment: •None 

• Incinerator, Temp. °F, Thermal/Catalytic (Circle one) 

D Adsorption, describe^ 

• Condensation, describe 

EJ Other, describe Filtered Spray BootK" 

21. Manufacturer Model No. Year Installed^ 

22. Percent collection or removal efficiency: Design 99.0 Z Operating 

. 3. For non-incineration method identify specific pollutant controlled Polyester Resin 

STACK DATA 

24. Your stack identification

 B5 C 

25. Are other sources vented to this 6tack? D Yes Q No 

If yes, identify sources 

26. Type: E Round, top inside diameter dimension 2V 

• Rectangular, top inside dimensions (L) x (W) 

27. Eelght: Above roof 7 ft. , above ground 32 ft . 

18. Exit gas: Temp. Amb °F, Volume 4093 ACFM, Velocity 152 ft./min, 

29. Continuous monitoring equipment: DYes C9No 

If yes, indicate Type , Manufacturer 

Make or Model , Pollutant (6) monitored 

30. Gnission data: Emissions from this source have been determined and.such data is 

included vith this appendix: - DYes (3No 

If yes, check method: D Stack Test • Emission factor • Material balance 

Completed by /7uiufio> -&6Z&L/ ,Date__________ 

Theodor Hebert 

SPA-3103 

?/:i/ei r.-/ 

51 
Ar-PLICATIU-1 cZR A FZ?.1IT TO LrZPJaz 

AN AIR CONTAMINANT .SOURCE 

P.60 

Picken's Plastics , Inc . 

Facility Name 

4212 Ann Ave. 

Facility Address 

Ashtabula, Ashtabula, 

Paul Nicholas 

Person to Contact 

P.O. Box 1279 

44004 

Mailing Address 

Ashtabula, OH 44004 

City County 

(216) 992-4000 

Zip City State 

(216) 992-4000 

Zip 

Telephone 

0204030269 

Area 

R002 

Number Telephone 

3089 

(Application No., if this is a renewal application) Std. Ind. Class. Code 

1. Complete and attach any of the following appendices most appropriate to the 

air contaminant source. In addition, a compliance time schedule form is to 

be attached when applicable. Check as appropriate the following: 

_Appendix A, Process 

[[Appendix B, Fuel-Burning Equipment" 

[[Appendix C, Incinerator 

[[[Appendix D, Surface Coating or 

~ Printing Operation 

_Appendix E, Storage Tank 

"Appendix H, Gasoline Dispensing 

"~ Facility 

_Appendix 3, Loading Rack at Bulk 

Gasoline Plant or 

Terminal 

_Appendix K, Surface Coating [ 

Line or Printing Line " 

_Appendix L, Solvent Metal 

Cleaning 

_Appendix M, Fugitive Dust 

Emission Sources 

Specify Appendix No. 

_Appendix N, Rubber Tire 

Manufacturing 

Appendix 0, Dry Cleaning 

Facility 

_Appendix P, Landfills 

"Other Appendix 

_Conpliance Time Schedule 

2] Description of Source (same as used on appendix):Polyester Gelcoatl "g

 B°°»> 

3. Your identification for Source (same as used on appendix):Gelcoating 

-t> Booth # B-6 „, 

I, being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents are submitted as part of this application (describe all 

attachments): 

d^—•=» Thomas J. Picken 

Authorized Signature* 

President, Picken's Pl'astics, Inc. 

Title 

Jan. 29, 1993 

Date 

•Pursuant t o OkC Rule 3745-35-02(B) (Permit to Operate). 

Operation of an air contaminant source vithout an effective permit to operate is 

prohibite3 t o 3704.05 Ohio Revised Code. Psoe 1 EPA-3161 

G O 
P.61 

rca5.se No. 

j.iurce No. 

application 

/ 

/ 

No. 

/ 

/ 

/ 

• * • 

APPENDIX D 

SURFACE COATING OR PRINTING OPERATION 

1. This appendix is submitted for a: 

D Surface coating operation (check one below): 

Paint spray booth Flow coating 

Dip tank Roller coating 

X Spray Coating (Other than paint spray booth) 

Other surface coating operation, describe 

D Printin g or lithographic operation. 

2. Name of operation Polyester Gelcoating . Your identification B-6 

Year Installe d 

3 . Is this operation succeeded by a heated drying or baking operation? • Yes 0 No 

If yes, indicat e operating temperature of oven NA F. 

4. Normal operating schedule:

 1 6

 hours/day,

 5 days/vk., 5 2

 vks./year. 

PAINT SPRAY BOOTH " - * 

• "*•» — — — % "—-——"——-—"—- — 

5. Type of spray booth: • Enclosed •Conveyor •Downdraft . 

• Other, describe 

6. Booth manufacturer Devilbiss Make or Model No. XDO-409 

7. Type of spraying: • Air gun 0 Airless D Electrostati c 

D Other, describe '__ 

8. Spraying operation is: 0Manual D Automatic 

.9._ Fan manufacturer Hove 11 Make or Model Ko. JJ4212 

& 

10. Booth's exhaust is equipped vith : D Water vash (Complete item 11) 

E3 Exhaust filters (Complete item 12) 

D Baffles 

D Other, describe 

• None 

1 1 . Water vash: (a) Is water recirculated? DYes D No 

NA (b) Is a chemical added t o the water? DYes Qu o 

(c) Is material reclaimed from wash vater. DYes D No 

(d) Describe method for disposel of waste materials: 

* Does not include metal plating 

<o\ 
P.62 

14. 

(a) Type of material: D Fiberglas D Aluainua 

• Other, describe 

(b) Filter size (inches): Length

 2 0 " Width 20 " Thickness 2" 

No. of filters:

 1 2 No. of filter changes: 5 1 times per year 

_3. Describe material painted Fiberglass Molds 

ALL OPERATIONS (Except paint spray booth) 

Describe type of operation

 Pol Yeste r Gelcoat is applied to the surface of the molds 

used to produce fiberglass products. 

15. Describe method of coating or printing

 Gelcoa t i s applie d vit h airles s spray.equipment. 

16. Identify and describe type(s) of material coated or prlnted_ 

(Coating is transfered to the surface of the molded part). 

Various Fiberlass molds 

ALL OPERATIONS 

17. Complete the following information for each general type of surface coating of printing 

material. Report on the material as it is employed after the addition of any pigments, 

solvents, etc. If there .are more than three types of materials, furnish the same data 

for the additional ma-eri^ls on. a separate sheet or another appendix form. 

(a) Material -employed Mix Resin No. 944A083 Gray 

Solids content 49 

Density 10.795 _lbs./gallon 

X by weight 

Solvent content 51 

X by volume or 

% by volume; Solvent density 7.59 lbs./gallon 

Normal application schedule 15 hrs./day, 5 days/wk., 52 vks./year. 

Quantity used (gallons/hour): Nonnai 2^0 Maximum Unknown 

(gallons /year): 7695 , 

Complete the solvent composition by identifying each solvent component 

and its respective X by volume of the total solvent. (The X by volume 

should torai to 100%). 

Solvent Composition 

Solvent 

Styrene Monomer 

Hexylene Glycol 

MEK 

X by Volume 

48.6 

.20 

.118 

* 

Y 

N 

N 

Solvent 

Solvent Composition 

Dimethyl Phthalate 

X by Volume 3 

* If solvent is photochemically reactive enter "Y", if not photochemically 

reactive enter "N", if unknown enter "U". 

Is the material photochemically reactive? 0 Yes • No • Do not know 

6 1 
P.63_ 

•(b) Material eoployedResin Mix No. 944B025 Black 

Solids content 47.37 % by volume or 

Density 10_146 lbs./gallc n 

% by weight 

Solvent content 52.63 7, by volume Solvent density

 7-64 lbs./gallon 

Normal application schedule:

 l hrs./day.

 5 days/wk., 52 vks./year. 

Quantity used (gallons/hour): Normal ' 2.73 Maximum Unknown 

(gallons/year): 709.8 

Complete the solvent composition by identifying each solvent component and its 

respective 7. by volume of the total solvent. (The X by volume should total to 

100%). 

Solvent Composition 

Solvent 

Styrene Monomer 

Methyl Methacrylate 

Dimethyl Rithalate 

7. by Volume 

87.25 

11.61 

.828 

* 

Y 

U 

N 

Solvent Composition 

Solvent 

Hexylene Glycol 

MEK 

X by Volume 

.105 

.06 

* 

N 

N 

* If solvent is photochemically reactive enter "Y", if not photochemically 

reactive enter "N", if unknown enter "U". 

Is the material photochemically reactive? 

(c) Material employed_ 

Solids content X by volume or 

E Yes • No 

Density 

X by veight 

• Do not know 

lbs./gallon 

Solvent content X by volume Solvent density 

Normal application schedule: hrs./day, days/vk.,_ 

Quantity used (gallons/hour): Normal 

(gallons/year): 

_lbs./gallon 

wks./year. 

Maximum 

Complete the solvent composition by identifying each solvent component and its 

respective % by volume of the total solvent. (The X by volume should total to 

100%). 

Solvent Coai 

Solvent 

position 

X by Volume * 

Solvent Composition 

Solvent X by Volume 

• 

• 

* 

18. 

* If sclvenr is photochemically reactive enter "Y", if not photochemically 

reactive eater.. *'N", if unknown enter "U". 

Is the materia l photochemically reactive? • Yes D No • Do not know 

Identify al l liqui d organic cleanup materials for this process and indicat e the amount 

used per average operating day and per year. 

Cleanup Material 

Acetone 

* 

N 

Gallons Used . 

Daily 

6.8 

Yearly 

1769 

* If material is photochemically reactive enter "Y", if not photochemically reactive 

er.ter "S", if unknown enter "U". 

^ 
P.64 

points of al l materials and finished products. Label al l materials including 

aiTborne contaminants and other vaste materials. Label the process equipment and 

contro l equipment. 

CONTROL EQUIPMENT 

!0. Type of control equipnent: QNone 

• Incinerator, Temp. °F, Thermal/Catalytic (Circle one) 

D Adsorption, 'describe . • ' . 

• Condensation, describe 

B Other, describe Filtered Spray Booth 

21. Manufacturer DevilMss Model No. *DQ Year Installed

 1985 

22. Percent collectio n or removal efficiency: Design . ^ X Operating ^ _ 

23. For non-incineration method identify specifi c pollutant controlled Polyester Gelcoat 

STACK DATA 

24. Your stack identification

 36" Dianete r Round

 **** 

25. Are othe r sources vented t o this stack? DYe s 0No 

If yes, identif y sources [ _^ 

26. Type: E Round, top inside diameter dimension 36" 

• Rectangular, top. inside dimensions (L) x (W) 

27. Height: Above roof ° ft.,-above ground

 8 ft. 

28. Exit gas: . Temp. -BMB °F, Volume 6750 • ACPM, Velocity 250 ft./min. 

29. Continuous monitoring equipment: DYes : • - f_fNo 

If yes, indicat e Type - . . .'- . . .. ., Manufacturer . 

--•• Make or Model • , Pollutant (s) monitored 

30. Emission data: Emissions from this source have been determined and such data is 

included vit h til s appendix: Dye s B No 

If yes, check method: • Stack Test •Emissio n factor • Material balance 

Completed by - //pJmffi.yvS/fof ,Date________^ 

rr;.*-.

 r

,~. 

04-
P.65 

=or Office Use Only 

Check Appropriate box(es) 

\ | Air Discharge 

{ | Water Discharge to New 

Source Treatment Works 

1 I Solid Waste Disposal Facility 

| | Hazardous Waste Disposal Facility 

For Office Use Only 

PTI Application No. 

Date Received — 

Premise No. 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

Application for Permit to Install 

NiCVc feV\* AW V it. "Tu c 

Applicant's Name 

Mailing Address XuTa.,L H-U-.U-U dito tM. m-it-nL-fr* 

City 

ku 

County State Zip Code Telephone Number 

Person to contact (Name and Title and Telephone Number) 

Location of Proposed Facility (State the location as completely and precisely as possible)* 

fii>hf<k(-uJlL As/sldJA Woo? 

City or Township 

3021 

County Zip Code 

Standard Industrial Classification Code 

Directions: A Permit to Install is required for new or modified source of pollution 

under the provisions of OAC Rule 3745-31. An application cannot be considered 

complete unless all applicable questions are answered and the required information 

has been submitted. This application must be signed in accordance with OAC Rule 

3745-31-04(B) or it cannot be accepted. 

Applicants for permits involving air emissions or wastewater treatment facilities 

will be required to pay a permit to install fee as shown in Section 3745.11(B) and 

(C) of the Ohio Revised Code. This fee is payable fifteen days after the date of 

final issuance of the permit. 

Name of new or modified source or facility: //tt'mmiitt. 

Product of new or modified source/facility: FlkeYt-sjass -xag-k £o«."^*riaocA. 

Will the proposed source/facility involve any of the following: Check all that apply. 

A. • Air Discharge fte^Uw.U'a^ ? 

B. • Wastewater Treatment Works 

C. • Solid Waste Disposal Facility 

D. • Hazardous Waste Disposal Facility 

• Example: "The source will be constructed on a 20 acre pbt tc be loca'.s-d on Franklin Township Road No. 17. 

Esprcxin-.Eteiy 1 1/4 nvles nsr.h of the ir.iersecv.cr. c'. H't'.e F.cr.e 9^ E-.i FrEnKlin Townsfvp 

6£ 
P.66 

X 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

INSTALLATION SCHEDULE 

TO ACCOMPANY APPLICATION FOR PERMITTO INSTALL 

This form constitutes part of the application of: 

FACILITY NAMEf -WeWwc, 'TAQL.A i c TUe , ; 

ADDRESS: . 

For a Permit to Install the following air contaminant source: 

IDENTIFICATION: "bC LCsbG J^tisf QoKgcVo-o.. , 

DESCRIPTION: /WiV QcUfrftott, ,?frxA- Sg^t'rva 3 iitettYg. ^Wkft-AS. e<A. 

7Zs*m LrtL J3 X \kvkl \ IvAe^cJ gaefci^ Ri«. 

The installation of the above air contaminant source is planned to follow the time 

schedule described below: 

DATE 

1. Equipment ordered 

2. Commence Construction 

3. Startup fW jy \*f\\ 

4. Performance Testing 

ftoW.: Tltte. uv.;k exUu*!- To ivAuadL••Tac.t,(t, A;*.-, \W _ 

f\\<\ S»UJC\CS OVV- "WC \i> ? Tntm irootL Afvre, 6ee„ CAptd ct*%d 

eu.i 

& £> 
P.67 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

APPLICATION FOR A PERMIT TO OPERATE 

AN AIR CONTAMINANT SOURCE 

•ReV-fe** ^Wfrk c \» \v.c- •^jg^t riickotct 

Facility Name 

¥X/0 fir>n five. 

Facility Address . 

City County Zip 

n/c 99Z - Voce 

Person to Contact 

Vl/* /?nrt. Ave 

Mailing Address 

City 

2/C 

Telephone Area Number 

County Zip 

Telephone 

(Application No., If this is a renewal 

application) 

Area Number 

Standard Industrial 

Classification Code 

1. Complete and attach any of the following appendices most appropriate to the 

air contaminant source. In addition, a compliance time schedule form is to be 

attached when applicable. Check as appropriate the following: 

Appendix A, 

Appendix B, 

Appendix C, 

Appendix D, 

Appendix E, 

Appendix H, 

Appendix J, 

Appendix K, 

Process 

Fuel-Burning Equipment 

Incinerator 

Surface Coating or 

Printing Operation 

Storage Tank 

Gasoline Dispensing 

Facility 

Loading Rack at Bulk 

Gasoline Plant or Terminal 

Surface Coating Line or 

Printing Line 

Appendix L, 

Appendix M, 

Solvent Metal 

Cleaning 

Fugitive Dust 

Emission Sources 

(Specify Appendix No.) 

Appendix N, Rubber Tire 

Manufacturing 

Dry Cleaning 

Facility 

Landfills 

2. Description of Source (same as used on appendix): 

(jfaAhwi \-C) 

Appendix O, 

Appendix P, 

Other Appendix ' 

Compliance Time Schedule 

3. Your identification for Source (same as used on appendix): 

I, being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents are submitted as part of this application (describe all 

attachments): W7\")' 

AuthdSzed Signature* 

Title 

Date 

•Pursuant to OAC Rule 3745-35-02(B) (Permit to Operate). 

Operation of an air contaminant source without an effective permit to operate is 

prohibited to 3704.05 Ohio Revised Code. 

Pc?c- 1 EPA-31G1 

QI 
P.68 

r Official Use Only 

"remise No. 

aurce No. 

Application No. 

Appendix A, Process 

Process Data 

1. 

• » 

2. 

3. 

4. 

5. 

6. 

7. 

6. 

9. 

10. 

11. 

12. 

13. 

14. 

Name of process ^i(r£?r».-aWt«> (pft-.w-ltv^ SWAWh CUHIKO^ 

End product of this process ^*tW,rtAWfrS ""^m.V »^ft>trwrl 

Primary process equipment 1W-A y\wAe.<_s . Scad-k ^frills (^tt«uv*a*icWvxA "Tftfelc 

Your indentification _ JB£. Year installed mi 

Manufacturer J-^S**-— Make or model 

Capacity of equipment (lbs./hr.): Rated 

Method ot exhau^ ventilation: • Stack [_] Window Fan • Roof Vent 

Max. /fefrXfrgQ tttVA 

Are there multiple exhausts? 

Normal operating schedule: 

J3 Other, describe "/* fti hah*/fiitl, 

D Yes E l No OW£ €J.VjUJ*b V*» ' U/A ^ 

Operating Data 

hrs./day, —£L!—days/wk., . wks./year 

Percent annual production (finished units) by season: 

Winter +&/• Spring — 2 C A Summer &£~/( Fall &Tk 

Hourly production rates (lbs.): Average /JO/3Q Maximum —£4- **'?... 

"J?***.- sfrud^ on -mx. tt p+mfm* ieaeiv sV-aJUe-A \>«n. «/© vr\.!v\ C S-Vc*©w( & 

Annual production (indicate units) 2-Zj «Too 

Projected percent annual increase in production 

Type of operation: P_( Cont 

If batch, indicate: Minutes per cycle 

Materials used in process: 

^L 

tinuous 

flfl. 

• Batch 

Minutes between cycles na 

List of Raw Materials 

•Aft 

Principal Use Amount (Ibs./hr.) 

•» 

A PROCESS FLOV/ DIAGRAM MUST BE INCLUDED V/ITH THIS APPENDIXSho . w 

entry and exit points of all rav/ material, intermediate products, by-products and 

finished products. Label all materials including airborne contaminants and other 

waste materials. Label the process equipment and control equipment. 

(Continued on reverse side) 

6<& 
P.69 

Control Equipment Code: 

A T ) Settling chamber 

B\) Cyclone 

C) Multiple cyclone 

D) Electrostatic precipitator 

;E) Fabric filter 

(F) Spraychamber 

(G) 

(H) 

0) 

(J) 

(K) 

(L) 

Cyclonic scrubber 

Impingement scrubber 

Orifice scrubber 

Venturi scrubber 

Plate or tray tower 

Packed tower 

(M) 

(N) 

(0) 

(P) 

(Q) 

Adsorber 

Condenser 

Afterburner-catalyst 

Afterburner-thermal 

Other, describe 

\ 

i. Control Equipment data: 

ITEM 

(a) Type (See above code) 

(b) Manufacturer 

(c) Model No. 

(d) Year installed 

PRIMARY COLLECTOR 

* + & 

"WskhNX-V-ftp&l T^«L 

"^C CmtCXS 

(e) Your identification 

(f) Pollutant Controlled 

(g) Controlled pollutant emission 

rate (if known) 

(h) Pressure drop 

mi 

TbS >Clooa 

SECONDARY COLLECTOR 

O 

99,97 % ^T - K4wrt_\ 

nm*/ ecfWr. 

(i) Design efficiency 

(j) Operating efficiency 

JW____ 

Wl 

w.sn 

STACK DATA 

16. Your stack identification 

17. Are other sources vented to this stack? 

18. Type: L J Round, top inside diameter dimension 

\ \ Rectangular, top inside dimension (L) 

£UcU. Vic l.»»yfi, U&feA. ^\-Call<_tW&. V\^W' 

• ves g| N o • 7 T in-few*! Rlfc 

J1Qnn~ x (w) 

19. Height: Above roof 

20. Exit gas: Temp. 

M. ft., aboveground ft. m=. F, Volume 

21. Continuous monitoring equipment: 

If yes, indicate: Type 

Make or Model £/_2__. 

____ 

D Yes 

ACFM, Velocity 

• NO 

., Manufacturer 

ft ./min. 

., Pollutant(s) monitored 

22 Emisssion data: Emissions from this source have been determined and such data is 

included with this appendix: /ifr DYes DNO 

If yes, check method: 

Completed 

[_JStackTest J~] Emission factor | | Material balance 

by rfZL JUU^ /-/*/-93 

(o <\ 
FICKEN'3 PLASTICS INC. 

247.5' 

t\c*tt ff 

SS 

TT 

sx 

TT= 

st § 

V * 

H L 

Gelcoat 

Booth 

£xWx.u<w\ "T. ^«*>vn H**K 

CMe.Gowv^l«i«- £*cl\.. ^ii c /^'*»J ^<»y/ 58" 
P.71 

:

or Office Use Only 

Check Appropriate box(es) 

[ | Air Discharge 

j \ Water Discharge to New 

Source Treatment Works 

Q Solid Waste Disposal Facility 

r~j Hazardous Waste Disposal Facility 

For Office Use Only 

PTI Application No. 

Date Received 

Premise No. 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

Application for Permit to Install 

P.<-.kewr P-laW icy J/ic . 

Applicant's Name 

P. o. BtmX fan* 

Mailing Address 

/tfk4m.t)mm.U /UkhUU Off WOOY (a/6>) tla-Veoo 

City County State Zip Code Telephone Number 

(3/6) <ZHmm-vooc 

Person to contact (Name and Title and Telephone Number) 

Vs/mi /!*,» Ayr fiU *t hffiLocation of Proposed Facility (State the location es completely and precisely as possible)* 

/Isk + o-bJ* Axk-fc.hu lo. YVooY 

City or Township 

308<\ 

County Zip Code 

Standard Industrial Classification Code 

Directions: A Permit to Install is required for new or modified source of pollution 

under the provisions of OAC Rule 3745-31. An application cannot be considered 

complete unless all applicable questions are answered and the required information 

has been submitted. This application must be signed in accordance with OAC Rule 

3745-31-04(B) or it cannot be accepted. 

Applicants for permits involving air emissions or wastewater treatment facilities 

will be required to pay a permit to install fee as shown in Section 3745.11(B) and 

(C) of the Ohio Revised Code. This fee is payable fifteen days after the date qf 

final issuance of the permit. 

Name of new or modified source or facility 

Product of new or modified source/facility: 

'fc-A^Yia feotfUv KH-hx 

Will the proposed source/facility involve any of the following: Check all that apply. 

A. D8 Air Discharge & H teeotW v*i\Vk Xft*.AS 2.€fcWvi»\ owe ?Mfc<t&avA< OhC fcoolVx 

Wastewater Treatment Works 

Solid Waste Disposal Facility 

Hazardous Waste Disposal Facility 

Example: The source will be constructed on a 20 acre plot tc be located on Franklin Township Road No. 17, 

e-orcxirr.e'.e'y 1 MA miles north ofthe ir.terser'.icr, c! State Route 99 and Fra'".'•'Jin Township 

*S..\>' "7" 

B. 

C. 

D. 

D 

D • 

"7 
P.72 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

INSTALLATION SCHEDULE 

TO ACCOMPANY APPLICATION FOR PERMIT TO INSTALL 

THIS FORM CONSTITUTES PART OF THE APPLICATION OF: 

FACILITY NAME: fie hex* f/dtt'cS £/'C:.. 

ADDR ESS: H2I2 flhh A- e Js6fe/?i</c>: #A/b yYOOV 

FOR A PERMIT TO INSTALL THE FOLLOWING AIR CONTAMINANT SOURCE: 

IDENTIFICATION: 0*i/i/£iSS /-fadv/. JfflO f/'*//'s/lju* Av # J3J~/ 

DESCRIPTION: Tr'*?'X/2 / /*/' Fi/fcr*c/ f/hisAftt* &o/?* 

n/fzf* /?;«. fen $'£*A**tst/Ad-el £r/-jo?'$~?/) &'**«*? Ms 

S-WU «* B-Vl «-vv-i WWe l ?W(.fVol«-/j2 - "fced'owce S*Vack. 8?-a. 

THE INSTALLATION OF THE ABOVE AIR CONTAMINANT SOURCE IS PLANNED TO FOLLOW THE TIME 

SCHEDULE DESCRIBED BELOW: 

DATE 

l . EQUIPMENT ORDERED /7TJ 

2. COMMENCE CONSTRUCTION - - - / ?<T ^ 

3. STARTUP / jZ~7 

4. PERFORMANCE TESTING 

1% 
E.73_ 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

APPLICATION FOR A PERMIT TO OPERATE 

AN AIR CONTAMINANT SOURCE 

^j'cVe-A* yio^kc y Tw« r?ftvJl WtcViJ&s 

Facility Name 

V2/3 fin*. J-W 

Facility Address . . 

peloid A fokkU* W#></ 

City County Zip 

•2/£ 9frl- Vcco 

Person to Contact 

Mailing Address 

City County Zip 

IIL 992. - 4/6O0 

Telephone Area Number 

(Application No., If this is a renewal 

application) 

Telephone Area 

3oS9 

Number 

Standard Industrial 

Classification Code 

1. Complete and attach any of the following appendices most appropriate' to the 

air contaminant source. In addition, a compliance time schedule form is to be 

attached when applicable. Check as appropriate the following: 

X Appendix A, 

Appendix B, 

Appendix C, 

Appendix D, 

Appendix E, 

Appendix H, 

Appendix J, 

Appendix K, 

Process 

Fuel-Burning Equipment 

Incinerator 

Surface Coating or 

Printing Operation 

Storage Tank 

Gasoline Dispensing 

Facility 

Loading Rack at Bulk 

Gasoline Plant or Terminal 

Surface Coating Line or 

Printing Line 

Appendix L, 

Appendix M, 

Solvent Metal 

Cleaning 

Fugitive Dust 

Emission Sources 

(Specify Appendix No.) 

Appendix N, Rubber Tire 

Manufacturing 

Dry Cleaning 

Facility 

.Landfills 

2. Description of Source (same as used on appendix): 

Appendix O, 

Appendix P, 

Other Appendix 

Compliance Time Schedule 

Your identification for Source (same as used on appendix): 

__& 3 

I, being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents are submitted as part of this applicationjgescribe all 

attachments): ^ ,, _ 

mm-m-Cm-^*-m~m 

Authorized Signature* 

•^\rWi<i-*V ^>\c\(fe^ \WWcs TK . 

Title 

Date 

•Pursuant to OAC Rule 3745-35-02(B) (Permit to Operate). 

Operation of an air contaminant source without an effective permit to operate is 

prohibited to 3704.05 Ohio Revised Code. 

Paot 1 EPA-31C1 

73 
P.74 

or Official Use Only 

remise No. 

urce No. 

^plication No. 

Appendix A, Process 

Process Data 

1. Name of process ^TlfcviaWcg StuwAi*^ c<f ^ftr-jVs, 

4. 

5. 

6. 

7. 

8. 

9. 

10. 

11. 

12. 

13. 

14. 

nUwcAc.-i.c ^•*<?6'o.cel ^WW^-Vi . 

3. Primary process equipment 

2. End product of this process __ — 

Your indentification _ il 

Manufacturer PfcvUkte& 

Year installed 

Make or model 

m\ 

^a. 

Capacity of equipment (IbsVhr.): Rated M faX-tiA Max. W T ftftkdMethod of exhau^ ventilation: [_3 Stack C l Window Fan O Roof Vent 

D Other, describe 

Are there multiple exhausts? E Yes D No 7*» f-W, 1** Skclt* of>«.a*U*^ 

Operating Data 

Normal operating schedule: J5" hrs./day, -5 , days/wk., •••SO wks./year 

•AT ft 

Percent annual production (finished units) by season: 

Winter Z^'A Spring — ^ /• Summer — ^ £ 6 Fall 

Hourly production rates (lbs.): Average _ Maximum 

TF^ie *^*&u ° * lots pan*> ImXt-eAd. Y m% SW-V*** &«**$*. / fy p«*U. pe*. *ut f«a iWU 

Annual production (indicate units) /3ooo 

Projected percent annual increase in production 

Type of operation: E [ Continuous 

If batch, indicate: Minutes per cycle 

Materials used in process: . 

JUL 

• Batch 

Minutes between cycles 

List of Raw Materials Principal Use Amount (Ibs./hr.) 

ja___ 

A PROCESS FLOV/ DIAGRAM MUST BE INCLUDED WITH THIS APPENDIX. Show 

entry and exit points of all raw material, intermediate products, by-products and 

finished products. Label all materials including airborne contaminants and other 

waste materials. Label the process equipment and control equipment. 

(Continued on reverse side) 

Ik 
Control Equipment Code: 

A) 

B) 

C) 

.D) 

.E) 

IF) 

Settling chamber 

Cyclone 

Multiple cyclone 

Electrostatic precipitator 

Fabric filler 

Spray chamber 

P.75 

(G) Cyclonic scrubber (M) 

(H) Impingement scrubber (N) 

(I) Orifice scrubber (O) 

(J) Venturi scrubber (P) 

(K) Plate or tray tower (Q) 

(L) Packed tower 

Adsorber 

Condenser 

Afterburner-catalyst 

Afterburner-thermal 

Other, describe 

i. Control Equipment data: 

ITEM 

(a) Type (See above code) 

(b) Manufacturer 

(d) 

Model No. 

PRIMARY COLLECTOR 

Year installed 

[jW^fyft ftik«.runsv toos. 

(e) Your identification 

Pollutant Controlled 

(g) Controlled pollutant emission 

rate (if known) 

(h) Pressure drop 

(i) Design efficiency 

Wi^ 

M 

t)u,s,V 

SECONDARY COLLECTOR 

Xi 4£ y 

(j) Operating efficiency 

U.V-.V-AO VOVUvvUvvovOvs. 

SUU^ W/m 

^ 

^ s _Q_LL 

STACK DATA 

16. Your stack identification 

17. Are other sources vented to this stack? L J Yes [££) No 

18. Type: [Xl Round, top inside diameter dimension 

\ \ Rectangular, top inside dimension (L) x (W) 

19. Height: Above roof — 

20. Exit gas: Temp. r* w9 

i ft., above ground —, ~ ' 

€Actt_&Uk. 

tt. 

(

F, Volume 2J£LfZTMm, Velocity J3£ 

21. Continuous monitoring equipment: 

If yes, indicate: Type 

Make or Model 

• ves [^]NO 

, Manufacturer 

., Pollutant(s) monitored 

. ft./mln. 

22. Emisssion data: Emissions from this source have been determined and such data is 

•included with this appendix: DYes K)NO 

If yes. check method: QstackTest Q Emission factor [~| Material balance 

Completed by "7 

.Date i-w-n 

7S 
P.76 

•> i : U i» 

• i a m o O , LU 

$ 

o 

1 

c 

& 

I 

•mt. cn r j 

»-i t • .1 

U-, 

tr. 

Ki 

r»i r *i 

H 

i 

PO 

•5 

0 

3 

§ 

•^(fl 
P.77 

OHIO ENVIRONMENTAL PROTECTION AGENCY 

APPLICATION FOR A PERMIT TO OPERATE 

AN AIR CONTAMINANT SOURCE 

-"UcU-gy^ MoAie i Yv-x. ^ n>cL\ &hFacility Name 

VlLll. Jinn- /!„. 

Person to Contact 

%/hjJL AdkUtLm. ¥6f/ 

City County Zip 

Mailing Address ^ . , , . 

City County Zip 

2U - 992. Vcce 

Telephone Area Number 

(Application No., If this is a renewal 

application) 

Telephone Area 

3oV9 

Number 

Standard Industrial 

Classification Code 

1. Complete and attach any of the following appendices most appropriate to the 

air contaminant source. In addition, a compliance time schedule form is to be 

attached when applicable. Check as appropriate the following: 

Appendix A, 

Appendix B, 

Appendix C, 

Appendix D, 

Appendix E, 

Appendix H, 

Appendix J, 

Appendix K, 

Process 

Fuel-Burning Equipment 

Incinerator 

Surface Coating or 

Printing Operation 

Storage Tank 

Gasoline Dispensing 

Facility 

Loading Rack at Bulk 

Gasoline Plant or Terminal 

Surface Coating Une or 

Printing Line 

Appendix L, 

Appendix M, 

Solvent Metal 

Cleaning 

Fugitive Dust 

Emission Sources 

(Specify Appendix No.) 

Appendix N, Rubber Tire 

Manufacturing 

Dry Cleaning 

Facility . 

Landfills 

Description of Source (same as used on appendix): 

flssemLly fiooth B lo 

Appendix O, 

Appendix P, 

Olher Appendix 

Compliance Time Schedule 

tmn.it. <i o< V3. Your identification for Source (same as used on appendix): 

I, being the individual specified in Rule 3745-35-02(B) of the Ohio 

Administrative Code, hereby apply for a Permit to Operate the air 

contaminant source(s) described herein. As required, the following 

additional documents are submitted as part of this application ^describe all 

attachments): 

Autnfc signature* 

nne*iA^V^vcW- v tAuAto A 

Title 

Date 

•Pursuant to OAC Rule 3745-35-02(B) (Permit to Operate). 

Operation of an air contaminant source v/ithout an effective permit to operate is 

prohibited to 3704.05 Ohio Revised Code. 

Pcce-1 EPA-31C-1 

T7 
P.78 

X 

or Official Use Only 

•remise No. 

Source No. 

application No. 

Appendix A, Process 

Process Data 

1. 

2. 

3. 

4. 

5. 

6. 

7. 

8. 

9. 

10. 

11. 

12. 

13. 

14. 

Name ot process •VTUfta.q^s^ Mwdt. Uo-L7«7r>\*M-.WQ ••*- Asae-Aii-U^ 

End product of this process •Ui-t.tt*U 

Primary process equipment y^* * ( S&UJ> , Rou.W_> Pneu.-M.eLAn' c 

Your indentification _£Ac_ Year installed J3& 

Manufacturer Sfcy-A.; ft^fr «-v*.4- ft-Vfr Make or model f W Speciei c 

Capacity of equipment (IbsJhr.): Rated M ftfrWl Max. UoV ftaW 

Method of exhaust ventilation: J ^ Stack D Window Fan O Roof Vent 

C3 Other, describe 

Are there multiple exhausts? • Yes (3

 N o 

Operating Data 

Normal operating schedule: hrs./day, __s_—days/wk., - wks./year 

Percent annual production (finished units) by season: 

Winter . -*••* /• Spring —- ^ A Summer — •r-K/a Fall __4___. 

Hourly production rates (lbs.): Average Maximum

 >o u

 „ . 

77i«c Sf-udi** InA^c^t*. -V U*ih> A.V OL(o pouful-v eucX. c*.u. U t T-Vv.v'tli-t.cL tn S>wimv 

Annual production (indicate units) V&cxs ; 

Projected yw-g,. percent annual increase in production 

Type of operation: [_3 Continuous !Q Batch 

If batch, indicate: Minutes per cycle if** Minutes between cycles ''rr 

Materials used in process: 

List of Raw Materials Principal Use Amount (ibs./hr.) 

Pluscttip CioC &nJmo^ftgf.w-t- /6 . PoUyytis. 

A PROCESS FLOW DIAGRAM MUST BE INCLUDED WITH THIS APPENDIX. Show 

entry and exit points of all raw material, intermediate products, by-products and 

finished products. Label all materials including airborne contaminants and other 

v/aste materials. Label the process equipment and control equipment. 

(Continued on reverse side) 

il 
P.79 

Control Equipment Code: 

A) Settling chamber 

B) Cyclone 

C) Multiple cyclone 

D) Electrostatic precipitator 

;E) Fabric filter 

;F) Spray chamber 

(G) 

(H) 

0) 

(J) 

(K) 

(L) 

Cyclonic scrubber 

Impingement scrubber 

Orifice scrubber 

Venturi scrubber 

Plate or tray tower 

Packed tower 

(M) 

(N) 

(0) 

(P) 

(Q) 

Adsorber 

Condenser 

Afterburner-catalyst 

Afterburner-thermal 

Other, describe 

i. Control Equipment data: 

ITEM 

(a) Type (See above code) 

(b) Manufacturer 

(c) Model No. 

(d) Year installed 

(e) Your identification 

(f) Pollutant Controlled 

(g) Controlled pollutant emission 

rate (if known) 

(h) Pressure drop 

(i) Design efficiency 

1 (j) Operating efficiency 

PRIMARY COLLECTOR 

E 

mai» Aw >!W.t 

r\t*\t, 

m 

B/o 

Jfcusf 

JDu^V Cov\UveV 

Unk-AeVgwUv-vk-nouJvv 

/lA<keaMea. <ft% 

SECONDARY COLLECTOR 

>. / 

s# sf 

.<r *+ 

<? C 

V 

16. Your stack identification 

17. 

18. 

STACK PATA 

B\6 

Are other sources vented to this stack? L J Yes [)£j No 

Type: fc__J Round, top inside diameter dimension 

\ \ Rectangular, top inside dimension (L) x (W) 

19. Height: Above roof / ft., above ground Iv ft. 

20. 

21. 

Exit gas: Temp. lk*S. ° F, Volume 4S- 2 ACFM, Velocity ^£ l 

Continuous monitoring equipment: | ] Yes i2_J

 N o 

If yes, indicate: Type \ , Manufacturer 

Make or Model , Pollutant(s) monitored 

ft./mln. 

22. Emisssion data: Emissions from this source have been determined and such data is 

Included with this appendix: [_J Yes yQ No 

If yes, check method: j_]stack Test Q Emission factor J_J Material balance 

Completed by _,Date 

it 
F::K=rc*3 FUSTICS IKC. 

209.9' 

Open Air 

Concrete 

.Dock 

Trim Booth 

Trim Booth 

3te -r 

H 1-

**i^ «. «o 

=

:

 Loading 

Docks 

36! 37.4' 

-+-4-

"fc-\b ^Vw^e. ^«" k ^" ^ 

247.5' 

lOonV.fW.**. 

c 

*»•» • 

o 

o 

ft 

x

 h 

n 

s 

6 

e. 

J)ven 

B 1 

,(J3.:: _ 

£ o - "^ ". 

•4 1-

O 

vO 
P.81 

ATTACHMENT 3 

P icken's p]g st ics , Inc. 

Used in Spray/lay-up Booths ROOl, R004, R005, R006 

DC %••. Photo RX Release Calculations per CTB Gal of: 

Mix Resin No. 75-3730 

Component -Sl i 

i 

Resin No: 75-3730 ! 

Volume Mix Ration: 97Vi | 

Specific gravity: 1.1 j 

Weight V. VOC: 46'/. i 

Organic Chemical V. by wt. 

Styrene: 46V, j 

Alpha Methyl I 

Styrene: 1.5% j 

i 

Component 

Catalyst ] 

1 . 5*/. 

1 .084 

41 '/. 

Dimethyl 

Phthalate 

Hexylene 

Glycol: 

MEK: 

#2 

DDM9 

: 32V, 

6% 

3% 

Component #3 

Styrid: P5505001P 

1.5% 

.79 

53 - 55V. 

Minera1 

Spirits: 54.5V. 

by volume 

Therefore V. volume component #1 equals: 

NOTE: Combine Styrene and Alpha Methyl Styrene 

(Sq 75-3730 x 8.33) (wt % VOC Styrene) 

Density Styrene/gal. 

(1.1 x 8.33) (47.5'/.) 

7.587 

*/. Volume Styrene 

57.37 V. Volume Styrene 

*/• Vol Styrene x V, mix ratio = V. Vol. Styrene Per CTG Gal. 

57.37 x 97 = 55.64 •/. Vol Styrene Per CTG gal 

Therefore */. Vol Component #2 equals 

(1.0840 x 8.33)(.32) 

= 29*/, by vol. Dimethyl Phthalate (DP) 

9.93 

29V. x 1.5% = .436 •/. by vol/CTG Gal. (DP) 

(1.0840 x 8.33)(.06) 

7.71 

7.027. x 1.5*/, 

= 7.02V. Vol. Hexylene Glycol (HG) 

.105% Volatile by volume/CTG Gal 

Hexylene Glycol 

(1.0840 x 8.33)(.03) 

6.75 

4.0 V, V: • I-.' / . 

= 4.0V. Vol. MEK 

.06 V< by Vcl /CTG Gel. MEK 

9 [ 
P.82_ 

MIX RESIN NO. 75-3730 SOLVENT COMPOSITION 

Therefore; '/. by volume: Component #• 3 equals: 

54.5'/.'x 1.5 = .82'/. mineral spirits per CTG gal. 

'/. Composition 

CTG Gal. Compostion % Volume per Gal, of Solvent 

Styrene 55.64 '/. = 97.54 '/. 

Dimethyl Phthalate .436*/. = .76 % 

Hexylene Glycol .105% = .18 % 

MEK .06 % = .105% 

Mineral Spirits .8 % 1.40 % 

Total % Vol. 57.04 % 99.985% 

Solvent Density 

0C % Comp. x Density= Pounds/gal Solvent 

Density 

Styrene 97.54% x 7.587 = 7.40 > 

Dimethyl Phthalate .76 % x 9.93 = .075* 

Hexylene Glycol .18 % x 7.71 = .014* 7.588 

MEK .105% x 6.75 = .007* 

Mineral Spirits 1.40 % x 6.59 = .0923-

Note: This resin mix contains styrene suppressent. 

Therefore; for each CTG gal. used, assume 6% styrene loss to 

the atmosphere. 

Therefore: 1 CTG Gal. has a net loss of: 

55.64% x 7.587 x .06% = .254 pounds/gal styrene. 

<\W 
P.83 

Picken's Plastics, Inc. 

Used in Spray/lay-up Booths ROOl, ROO4b R005 , ROO6 

OC %>. Photo RX Release Calculations per CTG Ga] of: 

Mix Resin Mo. Aropol Q6022S 

Component -Sl Component *i2 Component #3 

Resin No: Aropol Q6022S Catalyst DDM9 Styrid: P5505001P 

Volume Mix Ration: 97% 1.5% 1.5% 

Specific gravity: 1.088 1.084 .79 

Weight % VOC: 46% 41 % 53 - 55% 

Organic Chemical % by wt. 

Styrene 46% 

Dimethyl 

Phthalate: 32% Mineral 

Hexylene Spirits: 54.5% 

Glycol: 6% by volume 

MEK: 3% 

Therefore % volume component tti equals : 

(Sq 6022S x e.33)(wt % VOC Styrene) 

. = y. Volume Styrene 

Density Styrene/gal. 

(1.088 x 8.33)(.46) 

= 54.9 5 % Volume Styren e 

7.587 

V. Vol Styrene x % mix ratio = % Vol. Styrene Per CTG Gal. 

54.98 x 97 = 53.33 % Vol Styrene Per CTG gal 

Therefore % Vol Component #2 equals 

(1.0840 x B.33)(.32) 

= 29% by vol. Dimethyl Phthalate (DP) 

9.93 

29*/. x 1.5% = .436 % by vol /CTG Gal. (DP) 

(1.0840 x 8.33)(.06) 

= 7.02% Vol. Hexylene Glycol (HG 

7.71 

7.02% x 1.5% = .105% Volatile by volume/CTG Gal 

Hexylene Glycol 

(1.0840 x 8.33)(.03) 

= 4.0% Vol. MEK 

6.75 

nh 
P.84 

MIX RESIN AROPOL Q6022S SOLVENT COMPOSITION 

Therefor; % by volume: Component tt 3 equals: 

54.5% x 1.5 = .82% mineral spirits per CTG gal. 

% Composition 

CTG Gal. Compostion % Volume per Gal, of Solvent 

Styrene 53.33 % = 97.4 % 

Dimethyl Phthalate .436% = .79 V. 

Hexylene Glycol .105% = .19 % 

MEK .06 % = .109% 

Mineral Spirits .82 % = 1.50 % 

Total % Vol. 54.75 % 99.989% 

Solvent Density 

OC % Comp. x Density= Pounds/gal Solvent 

Density 

Styrene . 97.4 % x 7.587 = 7.39 3 

Dimethyl Phthalate .79 % x 9.93 = .0783-

Hexylene Glycol .19 % x 7.71 = .015} 7.589 

MEK .109% x 6.75 = .0073-

Mineral Spirits 1.50 % x 6.59 = .0993-

Note: This resin mix contains styrene suppressent. 

Therefore; for each CTG gal. used, assume 6% styrene loss to 

the atmosphere. 

Therefore: 1 CTG Gal. has^e—-Ret loss of: 

53.33% x 7.587 x .06% -(.243ypounds/ga1 styrene 

oi^ 

? * 
P.85 

Picken's Plastics, Int. 

Used jr. Spray /lay-up .booths ROOl, F;004, F\005, F;006 

OC & Photo RX Release Calculations per^CTG Gal of: 

Mix Resin No. Koppers Dion FR 6,004T 

Component -Kl Component tt2 

Resin No: 66041 Catalyst DDM9 

Volume Mix Ration: 98.5% • 1.5% 

Specific, gravity: 1.18 "1.084 

Weight % VOC: 40% 41 % 

Organic Chemical % by wt. 

Styrene 40% 

Dimethyl Phthalate 32% 

Hexylene 61ycol 6% 

MEK 3% 

Therefore % volume component tti equals : 

(Sq 6604T x e.33)(wt V. VOC Styrene) 

s y, Volume Styrene 

Bensi.ty Styrene/gal. 

(1.1B x e.33)(.40) 

_ = 51.8 % 

7.587 

•/« Vol Styren e x mix rati o = V. Vol. Styrene Pe r CTG Gal. 

51. 8 x 98. 5 = 51.0 4 % Vol Styren e Pe r CTG ga l 

Therefor e V. Vol Component tt2 equals 

(1.084 0 x 6.33)(.32 ) 

= 29'/. by vol . Dimethyl Phthalat e (DP) 

9.9 3 

29% x 1.5% = .436 % by vol/CTG Gal . DP 

(1.084 0 x B.33)(.06 ) 

7.02% Vol . Hexylene Glyco l (HG 

7.7 1 

7.02% x 1.5% = .105% Volatil e by volume/CTG Gal. 

Hexylene Glyco l 

(1.0E40 x 8.33)(.03 ) 

ij.o% Vo) . MEK 

6.7 5 

4 . 0 V. x 1.5 V. «= .06 V. by Vol/CTG Bai . MEK 

•BS 
P.86 

MIX RESIN KOPPERS DION FR 6604T SOLVENT COMPOSITION 

*/ Composition 

CTG Gal. CofT.postion % Volume per Gal, of Solvent 

Styrene 51.04 V, = 9B.e3 V. 

Dimethyl Phthalate .436% = - .844% 

Hexylene Glycol .105% = -.203% 

MEK .06 % .116% 

Total % Vol. 51.64 V. 99.99 V, 

Solids from resin 47.48 

Solids from catalyst .6 

Solvent Density 

OC V- Comp. x Den£ity= Pounds/gal Solvent 

_;_ Densi tv 

Styrene 98.8 % x 7.587 = 7.50 > 

Dimethyl Phthalate .e44% x 9.93 = .08 J 

Hexylene Glycol .203% x 7.71 = .02 > 7.61 

MEK .116% x 6.75 - .0083 

Note: This resin mix does not contain styrene suppressent. 

Therefore? for each CTG gal. used, assume 11VJ styrene loss 

to atmosphere. 

Each CTG gallon of resin mix contains 51.04 V. by volume 

styrene and 11% of this is lost to the atmosphere. 

Therefore: 1 CTG Eal. has a net loss of: 

51i04% x 7.587 x 11% ='.425 pounds styrene 

It 
P.87 

Picken's Plastics, Inc. 

Used in Gel Cost Booth R002 

OC + Photo RX Release Calculations per CTG Gal of: 

Mix Resin No. 944A0B3 Gray. 

Component tti Component tt2 

Resin Ha: 944A083 • Catalyst DDM9 

Volume Mix Ration: 98.5% 1.5% 

Specific gravity: 1.30 1.084 

Weight % VOC: 35.847% 41 % 

Organic Chemical % by wt. 

Styrene 35.847% 

Dimethyl Phthalate 32% 

Hexylene Glycol 6% 

MEK 3% 

Therefore % volume component -111 equals : 

(Sq 944A083 x 8.33)(wt % VOC Styrene) 

= % Volume Styrene 

Density Styrene 

(1.30 x 8.33)(35.85) 

= 51.17 % 

7.587 

% Vol Styrene x mix ratio = % Vol. Styrene Per CTG Gal. 

51.17 x 98.5 = 50.40 % Vol Styrene Per CTG gal 

Therefore % Vol Component tt2 equals 

(1.0840 x 8.33)(.32) 

= 29% by vol. Dimethyl Phthalate (DP) 

9.93 

29 % x 1.5% = .456 % by vol/CTG Gal. DP 

(1.0840 x 8.33)(.06) 

= 7.02% Vol. Hexylene Glycol 

7.71 

7.02'/. x 1.5% = .105% Volatile by volume/CTG Gal. 

Hexylene Glycol 

( 1.0840 x 8.33) (.03) 

= 4 y, vol. MEK 

6.75 

4 % x 1.5 % = .06 V. by Vol/CTG Gal. MEK 

?7 
P.88 

MIX RESIN GEL COAT .944A083 GRAY SOLVENT COMPOSITION 

CTG Gal. Compost ion % Volume 

% Composition 

per Gal, of Solvent 

Styrene 50.4 % 

Dimethyl Phthalate .436% 

Hexylene Glycol .105% 

MEK .06 % 

98.8 % 

.85 % 

.20 % 

.118% 

Total 51.00 % 99.968% 

Solvent Density 

OC % Comp. x Density= Pounds/gal Solvent 

Densi ty 

Styrene 98.8 % x 7.58 = 7.49 3-

Dimethyl Phthalate .85% x 9.93 = .08 > 

Hexylene Glycol .20% x 7.71 = .015} 7.59 

MEK .118% x 6.75 = .008J 

This resin mix does not contain styrene suppressent. 

Therefore; for each CTG gal. used, assume a 30.5% emission 

factor for Styrene Monomer. 

Each CTG gallon of resin mix contains 50.4 % by volume 

styrene and 30.5% of this is lost to the atmosphere. 

Therefore: 1 CTG Gal. has a net loss of: 

50.4% x 7.587 x 30.5% = 1.17 pounds styrene 

<H 
P.89 

PICKEN'S PLASTICS, INC. 

USED IN GEL COAT BOOTH R002 

OC + PHOTO RX RELEASE CALCULATIONS FER CTG GAL OF: 

MIX RESIN NO. 944B025 BLACK 

Component #1 Component V.2 

Resin No: 944B025 Catalyst DDM 9 

Volume Mix Ratio: 98.5% 1.5% 

Specific Gravity: 1.22 1.0B40 

Wt. % VOC: 39.79 41 % 

Organic Chemical % by wt. 

Styrene 34.81 Dimethyl Phthalate 32% 

Methyl Methacrylate 4.83 Hexylene Glycol 6% 

MEK 3% 

Therefore % Volume Component tti equals: 

(Sq 944B025 x 8.33)(Wt % VOC Styrene) 

= y. Volume Styrene 

Density Styrene/gal 

(1.22 x 8.33)(34.81) 

- 46.62% Volume Styren e 

7.58 7 

% Vol. Styren e x mix ratio = % Vol . Styren e pe r CTG Gal . 

46.6 2 x 98. 5 = 45.92% Vol. Styren e pe r CTG Gal . 

(1.22 x e.33)(4.e3) 

= 6.20% Volume Methyl Methacrylate (MM) 

7.91 

6.20% x 98.5 = 6.11% Vol MM per CTG Gal. 

Therefore % Volume Component tt2 equals 

(1.0840 x 8.33)(.32) 

= 29% by volume Dimethyl Phthalat e (DP) 

9.93 

29% x 1.5% = .436% by volume/CTG gal. DP 

(1.0840 x 8.33) (.06) 

= 7.02 % Volume Hexylene Glycol 

7.71 

7.02% x 1.5% = .105 by volume/CTG gal. Hexylene Glycol 

(1.0S40 x 8.33) (.03) 

= 4./, Volume MEK 

6.75 

4% x 1.5% = .06% bv volume/CTG- oal. MEK 

41 
P.90 

MIX RESIN GEL COAT 944B025 BLACK SOLVENT COMPOSITION 

CTG Gal. Composition % Vol Composition per Gal of Solvent 

87.25 

11 .61 

.828 

.20 

.114 

100 % 

Styrene 

Methyl Methacrylate 

Dimethyl Phthalate 

Hexylene Glycol 

MEK 

Total 

45.92% 

6.11 % 

. 436% 

. 105 

.06 

52.63% 

7.58 

7.91 

9.93 

7.71 

6.75 

= 

= 

= 

= 

= 

6 .61 > 

.92 3-

.08 > 

.02 > 

.0083-

7.64 

lbs./gal 

OC % Comp. x Density= Pounds/gal Solvent 

Densi ty 

Styrene 87.25 

Methyl Methacrylate 11.61 

Dimethyl Phthalate .828 

Hexylene Glycol .20 

MEK .114 

This resin mix does not contain suppressent for styrene 

Therefore; for each CTG gal., used, assume a 30.5% emission 

factor for styrene monomer. 

Each CTG gallon of resin mix contains 45.92% by volume 

styrene and 30.5% of this is lost to the atmosphere. 

Therefore, one CTG gallon has a net loss of: 

45.92% x 7.587 x 30.5% = 1.063 pounds styrene. 

^ 
P.91 

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P.94 

hjO C 8 ( 

SITE VISIT QUESTIONNAIRE 

COMPOSITES FACILITIES - OH, PA 

August 1993 

aI. 

k:fb 

Facility Information 

- Company name/legal owner 

- Address 

- Contacts, phone nos. 

- No. of employees ~ loo T,d f-h-mer-t , ? 7y ^ fr 

I I. Production Processes 

- process description/products (flow chart) /**.*/- . sm<\ 

«_f *'*- - production schedule

 0<£rA

- ° f*~- >^-o fcU^t. 

- 1992 production (units, tons, etc.) *br*-c. /_: /_v-y-g&? 

2

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- 1992 emissions totals (VOC, styrene, other HAPs) T^"r''"yo 

j) 

S

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',«III. Resins/Gel Coats I ° Y- $f>*^ - cy 

,, j ^ - Identity of resins & gel coats used/function of each - >fr 

t e ~* -•-* fS~J- c^. y*- *+*Jte j ^ 

2, h, -fucUic ~

 st yren e content as received/as applied (other monomers) ^W 

yv, p^ j Y Res i n receiving and storage procedures •>t~

vf«-is<s 

- Resin, gel coat mixing procedures 

W l <7V1 - 5 / -f£ 

- Any other HAPs involved? (refer to HAP list) 26-_;s-

- Fillers/additives/mold release agents / 

- MSDS's for principal materials gpm 30 ^ % ^rr 

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IV. Spray Booths 

- exhaust air flow (acfm) 7 7 $ 7 

\J - quantity, size, function of each \ 

- filter type, size, changeout schedule p . 

- spray eguipment (type used, lifetime, advent. & disadv., 

consideration of upgraded equipment) 

V. Air Management/Control Systems 

- What air management practices are in place at facility? 

- To what process operations do these practices apply? 

- Technical description of air management system 

- Process parameters (air flow rates, air velocities, 

concentrations at collection points) 

- Are any control devices installed? (inlet/outlet 

concentrations, control efficiency, installed cost, costs 

of operation) 

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P.96 

VI. Control Measures 

- What measures have been taken or contemplated to reduce 

VOC/HAPs? 

- What is feasibility of: a) lowering styrene content . 

b) increasing filler content -As**-*-; •«-££_£ 

T

ej) using other monomers 

./ptf use of vapor suppressants 

e) add-on controls 

- Does the facility have a specific environmental program? 

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VII. Clean-up and Disposal Procedures 

</ - Clean-up solvent(s) used; qty. used per employee, units of 

production, month, etc. 

y - Wastewater handling procedures 

c/ - Solid waste procedures (waste resin, rejects, dust, etc.) 

y - Sanding/grinding/cutting/drilling (dust control) 

F'0 drwi- CuA-hv* -h-kf' 

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P.97 

VIII. Regulations 

- What air regulations apply to the facility? 

- What are the applicable OSHA limits? How 

mea sured/frequency? 

Has the facility used or are you familiar with the SPI Static Test 

Method? 

Il 
P.98 

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