y 

EHS Specialist 

ARI Project No. 899-02 

ARI Test Protocol 899-01 

ARI Proposal No. 25110 Revision 1 

Kohler Purchase Order No. 1 003753680C 

Test Dates: August 3 through 6, 2010 

_.- .-.---- --=-==== -~-= 

... __ 

- -

_,...._ 

_ ..... .....__ -

"ff/'ENVIRONMENTAL ..... INC. 

ARI Environmental, Inc. 

951 Old Rand Road, Unit 106 

Wauconda, Illinois 60084 

Phone: 847.487.1580 Ext. 120 

Fax: 847.487.1587 

E-mail: dfitzgerald@arienv.com 

Daniel E. Fitzgerald 

Division Manager 

Source Testing 
Figure 2-1 

Figure 2-2 

Figure 2-3 

Figure 2-4 

TABLES 

Table 1-1 

Table 1-2 

Table 1-3 

Table 2-1 

Table 4-1 

Table 4-2 

Table 4-3 

Table 4-4 

Table 4-5 

Table 4-6 

Table 4-7 

Table 4-8 

Table 4-9 

Table 4-10 

Table 4-11 

Table 4-12 

Table 4-13 

899-02 

USEPA Method 5 Filterable Particulate Matter Sampling Train 

USEPA Method 23 Sampling Train 

USEPA Method 26A Sampling Train 

USEPA Method 5/29 Sampling System 

Summary of Tunnel Kiln #19 POC Stack Test Results 

Summary of Ware Dryer #1 Stack Test Results 

Summary of Spray Booth Exhaust Test Results 

USEPA Method 23 Spike Compounds and Quantity Spiked 

Tunnel Kiln #19- POC Stack D/F Test Results 

Tunnel Kiln #19- POC Stack D/F Emissions Summary (Run 1) 

Tunnel Kiln #19- POC Stack D/F Emissions Summary (Run 2) 

Tunnel Kiln #19- POC Stack D/F Emissions Summary (Run 3) 

Tunnel Kiln #19 POC Stack FPM and Metals Test Results 

Tunnel Kiln #19- POC Stack HCI and HF Test Results 

Tunnel Kiln #19- RCE Stack Volumetric Flow Test Results 

Tunnel Kiln #19- WEE Stack Volumetric Flow Test Results 

Ware Dryer #1 Stack D/F Test Results 

Ware Dryer #1 Stack D/F Emissions Summary (Run 1) 

Ware Dryer #1 Stack D/F Emissions Summary (Run 2) 

Ware Dryer #1 Stack D/F Emissions Summary (Run 3) 

Spray Booth Exhaust FPM Test Results 

2-3 

2-6 

2-11 

2-13 

1-3 

1-4 

1-4 

2-9 

4-2 

4-3 

4-4 

4-5 

4-6 

4-9 

4-10 

4-11 

4-12 

4-13 

4-14 

4-15 

4-16 
899-02 

ii 
899-02 iii 
8/5 & 

8/6/10 

8/5/10 

Ware Dryer 

(WD-1) 

Spray Booth 

(024) 

RCE 

WEE 

WOE 

SSE 

Acid (HCI) 

Oxygen (02) and acfm 

0 2 and acfm 

0/F 

FPM 

Where: POC - products of combustion stack 

RCE - rapid cooling exhaust stack 

SBE- spray booth exhaust 

WOE ware dryer exhaust 

WEE - ware exit exhaust stack 

*The following metals were determined: 

899-02 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Mercury 

Nickel 

Selenium 

USEPA Methods 2 and 3: 

One measurement to coincide 

with each 0/F test run 

USEPA Methods 2 and 3: 

One measurement to coincide 

with each 0/F test run 

USEPA Method 23: 

Three (3) 240-minute test runs 

USEPA Method 5: 

Three (3) 60-minute test runs 

1-1 
899-02 1-2 
1,2,3,7,8,9 HxCDF 23 < 0.00247 < 0.00181 < 0.00559 ng/dscm @ 7% 02 

2,3,4,6,7,8 HxCDF 23 < 0.00113 <0.00119 < 0.00636 09/dscm @ 7% Oz 

Total HxCDF 23 0.00157 0.00998 0.03246 ng/dscm @ 7% 02 

1,2,3,4,6,7,8 HpCDF 23 < 0.00424 0.00345 0.00550 ng/dscm @ 7% 02 

1,2,3,4,7,8,9 HpCDF 23 < 0.00064 < 0.00126 < 0.00665 ng/dscm @ 7% 02 

Total HpCDF 23 < 0.00064 0.00705 0.00941 n9/dscm @ 7% 02 

1 ,2,3,4,6,5,7,8 OCDF (Total) 23 < 0.00580 0.00886 0.00721 ng/dscm @ 7% 02 

Total D/F 23 < 44.82246 < 41.93665 < 47.71955 ng/dscm @ 7% 02 

HCI 26A 1.60 1.39 1.56 ppmv db @ 7% 02 

HF 26A 47.29 50.18 47.27 ppmv db@ 7% 02 

Antimony (Sb) 29 < 0.200 < 0.374 3.425 119/dscm @ 7% 02 

Arsenic (As) 29 10.114 18.587 23.138 119/dscm @ 7% 02 

Beryllium (Be) 29 < 0.200 < 0.190 < 0.201 119/dscm @ 7% 02 

Cadmium (Cd) 29 < 0.100 < 0.095 < 0.168 119/dscm @ 7% Oz 

Chromium (Cr) 29 8.777 11.469 18.898 119/dscm @ 7% Oz 

Cobalt (Co) 29 0.314 0.263 0.388 119/dscm @ 7% Oz 

Lead (Pb) 29 27.722 34.290 30.601 119/dscm @ 7% 02 

Manganese (Mn) 29 0.558 0.988 0.945 119/dscm @ 7% Oz 

Mercury (Hg) 29 15.519 16.730 17.471 119/dscm @ 7% 02 

Nickel (Ni) 29 5.162 1.649 2.608 119/dscm @ 7% Oz 

Selenium (Se) 29 12.896 25.990 26.215 119/dscm @ 7% Oz 

899-02 1-3 
Total HxCDF 23 < 0.00022 < 0.00016 0.00040 ng/dscm 

1 ,2,3,4,6, 7,8 HpCDF 23 < 0.00052 < 0.00041 < 0.00026 ng/dscm 

1 ,2,3,4,7,8,9 HpCDF 23 < 0.00022 < 0.00021 < 0.00026 ng/dscm 

Total HpCDF 23 < 0.00022 < 0.00021 < 0.00033 ng/dscm 

1 ,2,3,4,6,5,7,8 OCDF (Total) 23 < 0.00031 < 0.00032 < 0.00052 ng/dscm 

Total D/F 23 < 0.38613 < 0.21960 < 0.62036 ng/dscm 

TABLE 1-3. SUMMARY OF SPRAY BOOTH EXHAUST TEST RESULTS 

COMPANY Kohler 

LOCATION Kohler, Wisconsin 

SOURCE Spray Booth Exhaust 024 

USEPA 

Parameter Method Run 1 Run2 Run3 Units 

FPM 5 13.277 13.967 11.279 mg/dscm 

FPM 5 0.1899 0.1932 0.1625 kg/hr 

899-02 1-4 
2.2 METHODOLOGY 

Where applicable, test procedures followed 40 CFR 60, Appendix A, USEPA Methods 1-5, 23, 

26A and 29; and the Quality Assurance Handbook for Air Pollution Measurement Systems, 

Volume Ill, Stationary Source Specific Methods. 

2.2.1 Sampling Locations (USEPA Method 1) 

The sampling point locations that were used for the determination of gas velocity and volume 

flow rate were determined following the procedural requirements as detailed in USEPA Method 

1. The sampling locations and number of velocity sampling points were as follows: 

Port Location Port Location 

Duct Upstream from Downstream No. Sampling 

Sampling Diameter Disturbance from Disturbance of Points Total 

Location (inches} {diameters} {diameters} Ports per Port Points 

Tunnel Kiln TK-19 POC 35.25 6.8 >2.0 2 12 24 

Tunnel Kiln TK-19 RCE 23.25 -6.45 >2.0 2 8 16 

Tunnel Kiln TK-19 WEE 26.75 -8.97 >2.0 2 8 16 

Ware Dryer WD-1 WDE 23.75 1.9 >2.0 2 12 24 

Spray Booth Q24 SBE 32.0 -4.84 >2.0 2 12 24 

899-02 2-1 
psychrometric equations in the method were used to calculate the moisture content in % by 

volume. 

2.2.5 Filterable Particulate Matter (USEPA Method 5) 

FPM sampling was performed following the procedures as detailed in USEPA Method 5. 

Sampling Apparatus 

The particulate sampling train was a stand-alone train (see Figure 2-1) for the Glaze Spray 

Booths and combined with the US EPA Method 29 metals sampling train (see Figure 2-4) for the 

Tunnel Kiln. Assembled by ARI personnel, it consisted of the following: 

• Nozzle- Borosilicate glass with sharp, tapered leading edge. 

• Probe - Stainless steel with a borosilicate glass liner and a heating system capable of 

maintaining a probe exit temperature of 248°F ±25°F. 

• Pitot Tube- Type-S attached to probe for monitoring stack gas velocity. 

• Filter Holder- Borosilicate glass with a Teflon frit filter support and a silicone rubber 

gasket. The holder design provides a positive seal against leakage from the outside or 

around the filter. The filter holder was heated to 248°F ±25°F. 

899-02 2-2 
co 

c.o c.o 

I 

0 

I'V 

N 

w 

"S"Type 

Pitot Tube 

1 

4 

Thermocouple 

· 

,, 

02 

-----

in 

( > 

IMPINGER CONTENTS 

1. 100 ml deionized/dist

2. 100 ml deionized/dist

3. Empty 

4. 200 g silica gel 

FIGURE 2-
The sampling train was leak-checked at the sampling site by plugging the inlet to the nozzle and 

pulling a vacuum of 15-in. Hg. Leak rates of less than 0.02 ft /min at a vacuum of 15-in. Hg 

were acceptable to commence sampling. At the completion of each test run, the sampling train 

was again leak-checked by the same procedure, but at the highest vacuum attained during the 

test run. Pre- and post-test leak checks of the pilot tube were made for each test run. Ice was 

used around the impingers to keep the temperature of the gases leaving the last impinger at 

less than 68°F. 

During sampling, stack gas and sampling train data were recorded at specified intervals. 

lsokinetic sampling rates were set throughout the sampling period with the aid of a 

programmable calculator. 

Sample Recovery Procedures 

After sampling was completed, the sampling train was then moved carefully from the test site to 

the recovery area. The sample fractions were recovered as follows: 

899-02 

Container 1 - The filter holder was carefully disassembled and the filter disc was 

removed and placed in a petri dish. Loose particulate and acetone rinse of the sample 

exposed surface prior to the filter were placed in Container 2 listed below. 

Container 2- Loose particulate and acetone washings from all sample-exposed surfaces 

prior to the filter were placed in a glass bottle, sealed, and labeled. Particulate was 

removed from the probe with the aid of a brush and acetone rinsing. The liquid level was 

marked after the container was sealed. 

2-4 
2.2.6 Polychlorinated Dibenzo-P-Dioxins and Polychlorinated Dibenzofurans (USEPA 

Method 23) 

Dioxins and furans were collected in accordance with USEPA Method 23. Specifically, testing 

consisted of isokinetically extracting a sample of the stack gas through a modified Method 5 

(MM5) sampling train, modified to include a cooling condenser and a resin trap between the 

filter holder and the first impinger. See Figure 2-2. 

Samples collected and analyzed included the filter (Container #1 ); probe, nozzle, connecting 

front-half glassware, back-half glassware and coil condenser, acetone and methylene chloride 

rinse (Container #2); probe, nozzle, connecting front-half glassware, back-half glassware and 

coil condenser and toluene rinse (Container #3); and the resin trap, which were capped, labeled 

and covered with aluminum foil immediately at the conclusion of testing for transport to the 

laboratory for analysis. The impinger gains were measured and used in isokinetic calculations. 

The laboratory analysis was conducted in accordance with the requirements of US EPA Method 

23 by ALS Laboratory Group (ALS) located in Burlington, Ontario. 

The MM5 train was assembled and leak-checked before sampling commenced. A minimum of 

3.4 dry standard cubic meters of stack gas was sampled isokinetically and collected in a heated 

sample probe and heated filter (front half catch) and a chiller and sorbent trap containing XAD-2 

resin (back half catch) during each sampling run. At the end of each run, the sampling train was 

disassembled, and all train samples were collected. 

899-02 2-5 
co 

co 

<p 

0 

"' 

1\.') 

I 

0') 
The sample train was assembled as follows: 

a) A glass nozzle was selected and attached to the probe. 

b) A pre-cleaned glass fiber filter was placed in the filter holder and its number 

recorded on the data sheets. 

c) The jacket water sample chiller and sorbent trap containing 25 to 40 grams of 

XAD-2 resin was placed in series after the filter holder. 

The back half of the train consisted offive impingers. The first impinger was assembled empty. 

The second and third impingers contained 100 ml of deionized distilled water. The fourth 

impinger was assembled empty. The fifth impinger contained 200 grams of silica gel. 

The sampling train was then assembled at the sampling location. 

D/F sampling began by positioning the probe and sampling nozzle at the first sampling point in 

the first sample port. Sampling was started and the sampling rate adjusted to maintain an 

isokinetic sampling rate. The sorbent traps were kept below 68°F to ensure that the XAD resin 

stayed efficient during the testing. 

At the completion of each run, a final leak test was performed on the sampling system. 

899-02 2-7 
determination of native compounds using the MM5 methodology is accurate. Good 

recovery of these compounds will reflect the XAD~2 resin's ability to capture and retain 

the various isomers of dioxins and furans. 

• Isotope Dilution Internal Standard Spikes -These compounds are placed directly onto 

the sample just prior to the preparation and extraction steps. The final recovery 

efficiency of these compounds reflects the overall accuracy of the sample's laboratory 

handling and analysis. Accordingly, these compounds are used to generate data that 

indicate the relative accuracy of the analytical methods. 

• 0/F Recovery Standards - These compounds are applied to the sample extracts just 

before the extracts are introduced onto the GC/MS instrument injection ports. These 

compounds are precisely applied at this step in the analytical scheme and provide the 

actual relative response factors that are used to calculate analyte concentrations. 

• Matrix Spike Compounds (back-half and spiked resin blanks only) -These compounds 

are spiked onto a separately prepared aliquot of the MM5 train back half condensate 

sample or XAD-2 resin before analysis. The spiked aliquots are then analyzed, and the 

spike recovery is calculated. Recovery of these spikes provides an independent 

indicator of method accuracy relative to the sample matrix. 

Table 2-1 lists the specific isomers that were used to spike the MM5 train and the quantities that 

were applied. 

899-02 2~8 
13C12-2,3,7,8-Tetrachlorodibenzofuran 10 I"Jg 

13C12-1 ,2,3,7,8-Pentachlorodibenzofuran 10 I"Jg 

13C12-1 ,2,3,6,7,8-Hexachlorodibenzofuran 10 I"Jg 

13C12-1 ,2,3,4,6,7,8-Heptachlorodibenzofuran 10 'lg 

Dioxin and Furan Recovery Standards 

(applied to extracts prior to sample injection) 

Dioxin and Furan 

13C12-1 ,2,3,4-Tetrachlorodibenzodioxin 10 I"Jg 

13C12-1 ,2,3, 7 ,8,9-Hexachlorodibenzodioxin 10 'lg 

Notes: 119 = Nanogram 

899-02 2-9 
or PCDFs in its homologous series. For example, the C12-2,3,7,8-tetra chlorinated 

dibenzodioxin was used to calculate the concentrations of all other tetra chlorinated isomers. 

Recoveries of the tetra- and penta- internal standards were calculated using the 13C12-1 ,2,3,4-

TCDD. Recoveries of the hexa- through octa- internal standards were calculated using 13C12-

1 ,2,3,7,8,9-HxCDD. Recoveries of the surrogate standards were calculated using the 

corresponding homolog from the internal standard. When no peak was detected, the noise 

level, as measured by the intensity of the noise in a clear zone of the chromatogram, was used 

to calculate the detection limit. 

The individual tetra through octa isomers were added together to calculate the total PCDD's and 

PCDF's in each sample. 

2.2. 7 Hydrochloric Acid and Hydrogen Fluoride Determination (USEPA Method 26A) 

HCI and HF sampling was conducted following USEPA Method 26A. Sample gas was 

withdrawn isokinetically through a heated glass lined sample probe and heated Teflon filter 

followed by a series of chilled impingers. 

Specifically, the front half of the sampling train consisted of a glass nozzle, heated glass lined 

probe and heated sample box containing a Teflon filter. The back half of the train consisted of 

five impingers. The first and second impingers (Greenburg-Smith) each contained 100 ml of 

0.1 N H2S04, the third and fourth impingers contained 0.1 N NaOH and the fifth impinger 

contained 200 grams of silica gel. See Figure 2-3. 

899-02 2-10 
co 

(0 

<p 

0 

1\) 

1\.) 

I 

"S" Type 

Pilot Tube 

"" r 

Thermocouple 
Antimony (Sb) 

Arsenic (As) 

Beryllium (Be) 

Cadmium (Cd) 

Chromium (Cr) 

Cobalt (Co) 

Lead (Pb) 

Manganese (Mn) 

Mercury (Hg) 

Nickel (Ni) 

Selenium (Se) 

The samples were withdrawn isokinetically from the exhaust stack and collected in a heated 

sample probe, heated filter (front half catch) and a series of ice cooled impingers containing an 

acid/peroxide solution (back half catch). 

As shown in Figure 2-4, the metals sampling train used for testing was an Apex Instruments 

Method 5/29 sampling train. The major components include the following: 

1. 

2. 

3. 

4. 

899-02 

Nozzle - Borosilicate glass with sharp tapered leading edge. 

Probe- Type 316 stainless steel with borosilicate glass liner and attached pitot 

tube and stack temperature thermocouple. 

Apex Sample Box- Containing Pyrex glass filter holder, glass fiber filter, seven 

Greenburg-Smith impingers and connecting glassware. 

Apex Control Module- (per USEPA Method 5/29 specifications) containing pump, 

heat controllers and oil gauge manometers. 

2-12 
1\:) 

I 

...... 

w 

lmp

1 

2. 

3. 

4. 

5. 

6. 

7. 
c) Flow through the dry gas meter was checked. 

d) The probe inlet was plugged. 

e) The fine flow adjustment valve was adjusted so that the vacuum gauge read 15-

in. Hg. 

f) If the flow exceeded 0.02 ACFM, the pump was shut off and all connections were 

rechecked for tightness and the leak test procedure repeated until acceptable 

results were obtained. 

Crushed ice was added to the impinger compartment and the sample case moved into position 

outside the first port to be sampled. When the filter holder assembly was properly heated, the 

nozzle was uncapped and the probe introduced into the stack to the first sampling point. The 

dry gas meter reading was recorded and sampling was started. At each point, a pitot reading 

was made and the sampling rate adjusted using calculations based on preliminary temperature, 

pressure and estimated moisture. When sampling at the last point in the port was completed, 

the pump was turned off and the probe was carefully removed from that port. The train was 

operated for a period of 4 hours and a minimum of 3.4 m3 of sample gas was collected. 

A final leak test was performed on the sampling train, as previously described. The umbilical 

cord was disconnected, and the sample case and probe were then disassembled. 

899-02 2-14 
measure the total volume collected then rinsed with acidic permanganate solution 

and Dl water then transferred to a bottle and labeled as Container #58. The 

impingers were then rinsed with 8N HCI and transferred to a glass bottle and 

labeled as Container #5C. 

7. The contents of impinger #7 were transferred to a clean bottle and labeled as 

Container #6. The weight of the silica gel was then determined. The difference 

between this final weight and the initial weight was the total moisture collected by 

the silica gel. 

Containers #1, #2, #3, #4, #5A, #58 and #5C were transported to ALS located in Burlington, 

Ontario and analyzed for metals by ICAP and CVAA in accordance with USEPA Method 29. 

One (1) field blank was collected in conjunction with the test program. 

899-02 2-15 
During this time most of the water in the slip is absorbed by the plaster of paris mold. Excess 

slip is drained from places where it was too thick to set up in the time allowed. This creates 

internal cavities. 

When the casting is sufficiently dry, the mold is disassembled and the casting removed. The 

casting, firm enough to be handled, is still very fragile. In this state the unfired cast fixture is 

known as "greenware". 

Ware Drying: The greenware fixture is hand-worked by skilled laborers, who smooth rough 

edges that remain from the mold and punch holes as needed for the finished product. They 

also assemble components of fixtures that could not be cast as a whole. 

The greenware is then subjected to air drying followed by heat drying. As it dries, greenware 

becomes harder and actually shrinks by over 12% throughout the manufacturing process. 

When nearly dry, greenware is ready for glazing. 

Glaze Application: Colored glaze is sprayed on surfaces that will be exposed after the ware is 

installed. It is important to distinguish glaze as discussed herein from other materials that are 

commonly referred to as "glaze". Glaze used at Kohler is a thin layer of clay sprayed onto the 

surface of the dried greenware. The glaze consists of the following raw materials: kaolin (a fine 

white clay), feldspar (silica), flint, wollastonite (calcium silicate), an opacifier (zirconium silicate), 

and pigments. 

899-02 3-1 
899-02 3-2 
899-02 4-1 
Concentration 

ng/dscm @ 7% Oxygen 

2,3,7,8-TCDD 0.07280 0.06224 0.06322 0.06609 

Total TCDD 1.32881 1.44433 1.87411 1.54909 

1,2,3,7,8 PeCDD 0.26294 0.24142 0.33310 0.27915 

Total PeCDD 2.66470 2.90960 3.80480 3.12636 

1 ,2,3,4, 7,8 HxCDD 0.16539 0.16118 0.12023 0.14893 

1,2,3,6,7,8 HxCDD 0.33998 0.30352 0.33875 0.32742 

1,2,3,7,8,9 HxCDD 0.55344 0.51842 0.53394 0.53527 

Total HxCDD 5.80296 5.31682 5.48796 5.53591 

1,2,3,4,6, 7,8 HpCDD 3.42806 3.15381 3.52192 3.36793 

Total HpCDD 6.44616 5.96572 6.49221 6.30136 

1,2,3,4,6,5,7,8 OCDD {Total) 28.41400 26.09567 29.77362 28.09443 

2,3,7,8-TCDF < 0.02545 0.02658 0.02885 < 0.02696 

Total TCDF 0.09966 0.09001 0.17680 0.12216 

1,2,3,7,8 PeCDF 0.00990 0.00858 0.00983 0.00944 

2,3,4,7,8 PeCDF < 0.01555 0.01605 0.01612 < 0.01591 

Total PeCDF 0.05817 0.08861 0.06096 0.06925 

1,2,3,4,7,8 HxCDF < 0.00212 0.00521 < 0.00580 < 0.00437 

1 ,2,3,6,7,8 HxCDF < 0.00431 < 0.00293 < 0.00530 < 0.00418 

1 ,2,3,7,8,9 HxCDF < 0.00247 < 0.00181 < 0.00559 < 0.00329 

2,3,4,6,7,8 HxCDF < 0.00113 < 0.00119 < 0.00636 < 0.00289 

Total HxCDF 0.00157 0.00998 0.03246 0.01467 

1 ,2,3,4,6,7,8 HpCDF < 0.00424 0.00345 0.00550 < 0.00440 

1 ,2,3,4,7,8,9 HpCDF < 0.00064 < 0.00126 < 0.00665 < 0.00285 

Total HpCDF < 0.00064 0.00705 0.00941 < 0.00570 

1 ,2,3,4,6,5, 7,8 OCDF {Total} < 0.00580 0.00886 0.00721 < 0.00729 

TOTAL <44.82246 < 41.93665 < 47.71955 < 44.82622 

899-02 4-2 
---- ------- ---

- -

------

- - -

-----

__ 

--._..-

-----

... 

..... ENVIROMtiENIAL 

--

._._ .... !NO. 

SECTIONFOUR 

T

COMPANY 

LOCATION 

SOURCE 

TEST DATE 

TEST RUN NO. 

TESTTlME 

SAMPLE VOLUME 

SAMPLE VOLUME 

GAS FLOW RATE 

OXYGEN CONTENT : 

DIOXIN I FURAN 

COMPOUND 

2,3,7,8-TCDD 

Total TCDD 

1,2,3,7,8 PeCDD 

Total PeCDD 

1,2,3,4,7,8 HxCDD 

1,2,3,6,7,8 HxCDD 

1,2,3,7,8,9 HxCDD 

Total HxCDD 

1,2,3,4,6,7,8 HpCDD 

Total HpCDD 

1,2,3,4,6,5,7,8 OCDD 

2,3,7,8-TCDF 

Total TCDF 

1,2,3,7,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1,2,3,4,7,8 HxCDF 

1,2,3,6,7,8 HxCDF 

1,2,3,7,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1 ,2,3,4,6, 7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

Total HpCDF 

1 ,2,3,4,6,5, 7,8 OCDF 

TOTAL 

899-02 

Kohler Com

Kohler, Wis

Tunnel Kiln 

8/3/2010 

TK19-M23-

07:34- 11 :

150

4.

344,

1

TOTAL 

SAMPLE 

MASS 

{nanogram

0.10300 

1.88000 

0.37200 

3.77000 

0.23400 

0.48100 

0.78300 

8.21000 

4.85000 

9.12000 

40.20000 

< 0.03600 

0.14100 

0.01400 

< 0.02200 

0.08230 

< 0.00300 

< 0.00610 

< 0.00350 

< 0.00160 

0.00222 

< 0.00600 

< 0.00091 

< 0.00091 

< 0.00820 

63.41463 
---- ------ ---

- -

_, 

- -

__ 

--

--------

__ 

--

... 

-

-----

.,.ENVIRONMI:NTAL ,..._ ..... INC. 

SECTIONFOUR 

T

COMPANY 

LOCATION 

SOURCE 

TEST DATE TEST RUN NO. 

TEST TIME 

SAMPLE VOLUME SAMPLE VOLUME 

GAS FLOW RATE 

OXYGEN CONTENT : 

DIOXIN I FURAN 

COMPOUND 

2,3,7,8-TCDD 

TotaiTCDD 

1,2,3,7,8 PeCDD 

Total PeCDD 

1,2,3,4,7,8 HxCDD 

1,2,3,6,7,8 HxCDD 

1,2,3,7,8,9 HxCDD 

Total HxCDD 

1,2,3,4,6,7,8 HpCDD 

Total HpCDD 

1,2,3,4,6,5,7,8 OCDD 

2,3, 7,8· TCDF 

Total TCDF 

1,2,3,7,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1,2,3,4,7,8 HxCDF 

1,2,3,6,7,8 HxCDF 

1,2,3,7,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1,2,3,4,6,7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

Total HpCDF 

1,2,3,4,6,5,7,8 OCDF 

TOTAL 

899-02 

Kohler CoKohler, W

Tunnel Ki

8/3/2010 

TK19-M23

13:05-17

149.66

4.23

355,85

16

TOTAL 

SAMPLE 

MASS 

{nanogram

0.08920 

2.07000 

0.34600 

4.17000 

0.23100 0.43500 

0.74300 

7.62000 

4.52000 

8.55000 

37.40000 

0.03810 

0.12900 

0.01230 0.02300 0.12700 

0.00746 

< 0.00420 

< 0.00260 < 0.00170 

0.01430 0.00494 

< 0.00180 

0.01010 0.01270 

60.10310 
-

----

-

- - ._. ...... __ _ 

-

.......... .-- - --

_._. 

-

-----

.... 'lfJI"'ENVIRONMENTAL 

--

._._ ..... INC. 

SECTIONFO UR 

T

COMPANY 

LOCATION 

SOURCE 

TEST DATE 

TEST RUN NO. 

TEST TIME 

SAMPLE VOLUME 

SAMPLE VOLUME 

GAS FLOW RATE 

OXYGEN CONTENT : 

DIOXIN I FURAN 

COMPOUND 

2,3,7,8-TCDD 

Total TCDD 

1 ,2,3, 7,8 PeCDD 

Total PeCDD 

1,2,3,4,7,8 HxCDD 

1,2,3,6,7,8 HxCDD 

1,2,3,7,8,9 HxCDD 

Total HxCDD 

1,2,3,4,6,7,8 HpCDD 

Total HpCDD 

1,2,3,4,6,5,7,8 OCDD 

2,3,7,8-TCDF 

Total TCDF 

1,2,3,7,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1 ,2,3,4.7 ,8 HxCDF 

1 ,2,3,6,7,8 HxCDF 

1,2,3,7,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1,2,3,4,6,7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

Total HpCDF 

1,2,3,4,6,5,7,8 OCDF 

TOTAL 

899-02 

Kohler Com

Kohler, Wis

Tunnel Kiln 

8/4/2010 

TK19-M23

07:20 - 11 :

147

4

335

TOTAL 

SAMPLE 

MASS 

{nanogra

0.08940 

2.65000 

0.47100 

5.38000 

0.17000 

0.47900 

0.75500 

7.76000 

4.98000 

9.18000 

42.10000 

0.04080 

0.25000 

0.01390

0.02280 

0.08620 

< 0.00820 

< 0.00750 

< 0.00790 

< 0.00900 

0.04590 

0.00778 

< 0.00940 

0.01330 

0.01020 

67.47560 
Antimony (Sbl 

Concentration 

lb/dscf X 1 0'9 < 0.00413 < 0.00790 0.07229 < 0.02811 

J.!Q/dscm @ 7% 02 < 0.200 < 0.374 3.425 < 1.333 

Emission rate 

lb/hr x 10-4 < 0.01426 < 0.02786 0.24312 < 0.09508 

lb/ton of product x 10-4 < 0.01725 < 0.03371 0.27769 < 0.10955 

kg/hr x 10-4 < 0.00647 < 0.01264 0.11028 < 0.04313 

kg/Mg of product x 10'4 < 0.00862 < 0.01685 0.13885 < 0.05478 

Arsenic (As) 

Concentration 

lb/dscf x 1 o-~ 0.20895 0.39234 0.48841 0.36323 

J.!Q/dscm @ 7% 02 10.114 18.587 23.138 17.280 

Emission rate 

lb/hr x 10-4 0.72039 1.38357 1.64265 1.24887 

lb/ton of product x 10-4 0.87162 1.67401 1.87624 1.47395 

kg/hr x 10'4 0.32677 0.62758 0.74510 0.56648 

kg/Mg of product x 10-4 0.43581 0.83700 0.93812 0.73698 

Beryllium (Be) 

Concentration 

lb/dscf x 10-8 < 0.00413 < 0.00402 < 0.00423 < 0.00413 

J.!Q/dscm @ 7% 02 < 0.200 < 0.190 < 0.201 < 0.197 

Emission rate 

lb/hr x 10'4 < 0.01426 < 0.01417 < 0.01424 < 0.01422 

lb/ton of product x 1 0-4 < 0.01725 < 0.01714 < 0.01627 < 0.01689 

kg/hr x 10-4 < 0.00647 < 0.00643 < 0.00646 < 0.00645 

kg/Mg of product x 10-4 < 0.00862 < 0.00857 < 0.00813 < 0.00844 

899-02 4-6 
IJ.g/dscm @ 7% 02 0.314 0.263 0.388 0.322 

Emission rate 

lb/hr x 10-4 0.02233 0.01960 0.02754 0.02316 

lb/ton of product x 10-4 0.02702 0.02371 0.03145 0.02739 

kg/hr x 10-4 0.01013 0.00889 0.01249 0.01050 

kg/Mg of product x 10-4 0.01351 0.01186 0.01573 0.01370 

Lead {Pb} 

Concentration 

lb/dscf X 1 0·!! 0.57271 0.72381 0.64593 0.64748 

IJ.9/dscm @ 7% 02 27.722 34.290 30.601 30.871 

Emission rate 

lb/hr x 10-4 1.97452 2.55247 2.17242 2.23314 

lb/ton of product x 1 0-4 2.38901 3.08829 2.48135 2.65288 

kg/hr x 10-4 0.89564 1.15779 0.98540 1.01294 

kg/Mg of product x 10-4 1.19451 1.54414 1.24068 1.32644 

Mercur~ {Hg} 

Concentration 

lb/dscf x 10·!! 0.32061 0.35313 0.36879 0.34751 

IJ.Q/dscm @ 7% 02 15.519 16.730 17.471 16.573 

Emission rate 

lb/hr x 10-4 1.10537 1.24531 1.24033 1.19700 

lb/ton of product x 10-4 1.33741 1.50673 1.41671 1.42028 

kg/hr x 10-4 0.50139 0.56487 0.56261 0.54296 

kg/Mg of product x 10-4 0.66870 0.75337 0.70835 0.71014 

899-02 
Jl.Q/dscm @ 7% 02 12.896 25.990 26.215 21.700 

Emission rate 

lb/hr x 10-4 0.91855 .1.93463 1.86103 1.57140 

lb/ton of product x 10-4 1.11137 2.34075 2.12568 1.85927 

kg/hr x 10""'~ 0.41665 0.87754 0.84416 0.71278 

kg/Mg of product x 10-'~ 0.55568 1.17038 1.06284 0.92963 

Filterable PM collected, mg 18.21 18.52 16.31 11.78 

Concentration 

gr/dscf 0.00176 0.00174 0.00161 0.00170 

lb/dscf x 1 0-!5 0.25103 0.24804 0.23027 0.24311 

mg/dscm @ 7% 02 12.149 11.748 10.907 11.602 

Emission rate 

lb/hr 0.08652 0.08744 0.07742 0.08379 

lb/ton of product 0.10468 0.10580 0.08843 0.09964 

kg/hr 0.03925 0.03966 0.03512 0.03801 

kg/Mg of product 0.05234 0.05290 0.04422 0.04982 

899-02 4-8 
Hydrogen Chloride CHCI) 

Concentration 

ppmv db 

ppmv db@ 7% 02 

lb/dscf x 1o·o 

Emission rate 

lb/hr 

lb/ton of Product 

kg/hr 

kg/Mg of Product 

Hydrogen Fluoride (HFl 

Concentration 

ppmv db 

ppmv db @ 7% 02 

lb/dscf x 1 O..o 

Emission rate 

lb/hr 

lblton of Product 

kg/hr 

kg/Mg of Product 

899-02 

0.56 0.48 

1.60 1.39 

0.053 0.045 

0.01777 0.01482 

0.02030 0.01692 

0.00806 0.00672 

0.01015 0.00846 

16.7 17.3 

47.29 50.18 

0.866 0.900 

0.28796 0.29411 

0.32891 0.33594 

0.13062 0.13341 

0.16446 0.16797 

0.56 0.54 

1.56 1.52 

0.053 0.051 

0.01753 0.01671 

0.02003 0.01908 

0.00795 0.00758 

0.01001 0.00954 

17.0 17.0 

47.27 48.25 

0.883 0.883 

0.29145 0.29117 

0.33289 0.33258 

0.13220 0.13208 

0.16645 0.16629 

4-9 
899-02 4-10 
899-02 4-11 
Total Dioxins and Furans Emissions 

Concentration 

ng/dscm 

2,3,7,8-TCDD 

TotaiTCDD 

1,2,3,7,8 PeCDD 

Total PeCDD 

1,2,3,4,7,8 HxCDD 

1 ,2,3,6,7,8 HxCDD 

1,2,3,7,8,9 HxCDD 

Total HxCDD 

1,2,3,4,6,7,8 HpCDD 

Total HpCDD 

1 ,2,3,4,6,5,7 ,8 OCDD (Total) 

2,3,7,8-TCDF 

Total TCDF 

1 ,2,3,7 ,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1 ,2,3,4,7,8 HxCDF 

1 ,2,3,6,7,8 HxCDF 

1 ,2,3,7 ,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1 ,2,3,4,6,7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

Total HpCDF 

1,2,3,4,6,5,7,8 OCDF (Total) 

TOTAL 

899-02 

< 0.00059 

< 0.00059 

< 0.00074 

0.00208 

< 0.00083 

< 0.00218 

< 0.00237 

< 0.00059 

0.03296 

0.06142 

0.32015 

< 0.00026 

< 0.00026 

< 0.00028 

< 0.00026 

< 0.00028 

< 0.00020 

< 0.00019 

< 0.00031 

< 0.00022 

< 0.00022 

< 0.00052 

< 0.00022 

< 0.00022 

< 0.00031 

< 0.38613 

< 0.00117 

< 0.00061 

< 0.00139 

0.00407 

< 0.00046 

< 0.00205 

< 0.00236 

0.00577 

0.01873 

0.03459 

0.17321 

< 0.00027 

< 0.00027 

< 0.00039 

< 0.00037 

< 0.00039 

< 0.00015 

< 0.00013 

< 0.00014 

< 0.00016 

< 0.00016 

< 0.00041 

< 0.00021 

< 0.00021 

< 0.00032 

< 0.21960 

< 0.00066 

< 0.00066 

0.00173 

0.00683 

0.00165 

< 0.00168 

0.00427 

0.01283 

0.04552 

0.08346 

0.51448 

< 0.00038 

< 0.00038 

< 0.00047 

< 0.00047 

< 0.00047 

0.00040 

< 0.00020 

< 0.00022 

< 0.00024 

0.00040 

< 0.00026 

< 0.00026 

< 0.00033 

< 0.00052 

< 0.62036 

< 0.00081 

< 0.00062 

< 0.00129 

0.00433 

< 0.00098 

< 0.00197 

< 0.00300 

< 0.00640 

0.03241 

0.05982 

0.33595 

< 0.00030 

< 0.00030 

< 0.00038 

< 0.00037 

< 0.00038 

< 0.00025 

< 0.00018 

< 0.00022 

< 0.00021 

< 0.00026 

< 0.00040 

< 0.00023 

< 0.00025 

< 0.00038 

< 0.40870 

4-12 
-- --- -

- -

--~-- - -.-.....-- ...... - ----

_._. 

-

-----

... 

.... ENVIRONMENTAL 

--

._._ ..... /NO. 

SECTIONFOUR 

COMPANY Kohler Com

LOCATION Kohler, Wis

SOURCE Ware Drye

TEST DATE 8/5/2010 

TEST RUN NO. WD1-M23-

TEST TIME 07:35- 11:

SAMPLE VOLUME : 148.89

SAMPLE VOLUME : 4.21

GAS FLOW RATE : 149,64

OXYGEN CONTENT : 20

TOTAL 

SAMPLE 

DIOXIN I FURAN MASS 

COMPOUND (nanosram

2,3,7,8-TCDD < 0.00250 

Total TCDD < 0.00250 

1,2,3,7,8 PeCDD < 0.00310 

Total PeCDD 0.00878 

1,2,3,4,7,8 HxCDD < 0.00350 

1,2,3,6,7,8 HxCDD < 0.00920 

1 ,2,3, 7,8,9 HxCDD < 0.01000 

Total HxCDD < 0.00250 

1,2,3,4,6,7,8 HpCDD 0.13900 

Total HpCDD 0.25900 

1,2,3,4,6,5,7,8 OCDD 1.35000 

2,3,7,8-TCDF < 0.00110 

TotaiTCDF < 0.00110 

1,2,3,7,8 PeCDF < 0.00120 

2,3,4,7,8 PeCDF < 0.00110 

Total PeCDF < 0.00120 

1,2,3,4,7,8 HxCDF < 0.00086 

1,2,3,6,7,8 HxCDF < 0.00079 

1,2,3,7,8,9 HxCDF < 0.00130 

2,3,4,6,7,8 HxCDF < 0.00094 

Total HxCDF < 0.00094 

1,2,3,4,6,7,8 HpCDF < 0.00220 

1,2,3,4,7,8,9 HpCDF < 0.00091 

Total HpCDF < 0.00091 

1 ,2,3,4,6,5,7,8 OCDF < 0.00130 

TOTAL 1.62823 

899-02 
---- ------ ---

- -

.------

- -

-

-----

---..-.-

.... Y"ENVIRONMENTAL 

---

--

----

..._._ ... INC. 

-

SECTIONFOUR 

COMPANY Kohler Com

LOCATION : Kohler, Wisc

SOURCE Ware Dryer 

TEST DATE 8/5/2010 

TEST RUN NO. WD1-M23-2 

TEST TIME 12:17- 16:2

SAMPLE VOLUME : 144.938 

SAMPLE VOLUME : 4.105 

GAS FLOW RATE : 146,650 

OXYGEN CONTENT : 20.8 

TOTAL 

SAMPLE 

DIOXIN I FURAN MASS 

COMPOUND 

2,3,7,8-TCDD < 0.00480 

TotaiTCDD < 0.00250 

1,2,3,7,8 PeCDD < 0.00570 

Total PeCDD 0.01670 

1 ,2,3,4, 7,8 HxCDD < 0.00190 

1,2,3,6,7,8 HxCDD < 0.00840 

1,2,3,7,8,9 HxCDD < 0.00970 

Total HxCDD 0.02370 

1,2,3,4,6,7,8 HpCDD 0.07690 

Total HpCDD 0.14200 

1,2,3,4,6,5,7,8 OCDD 0.71100 

2,3, 7,8-TCDF < 0.00110 

TotaiTCDF <0.00110 

1,2,3,7,8 PeCDF < 0.00160 

2,3,4,7,8 PeCDF < 0.00150 

Total PeCDF < 0.00160 

1,2,3,4,7,8 HxCDF < 0.00060 

1,2,3,6,7,8 HxCDF < 0.00055 

1,2,3,7,8,9 HxCDF < 0.00058 

2,3,4,6,7,8 HxCDF < 0.00065 

Total HxCDF < 0.00065 

1 ,2,3,4,6, 7,8 HpCDF < 0.00170 

1 ,2,3,4, 7,8,9 HpCDF < 0.00086 

Total HpCDF < 0.00086 

1,2,3,4,6,5,7,8 OCDF < 0.00130 

TOTAL 0.90141 

899-02 
---- ------ ---

---- ---

.-.----

- -

-----

--

- --..-....- --

---- -

-----...- .. ENVIRONMENrAL ...... INC. 

SECTIONFOUR 

COMPANY Kohler Com

LOCATION Kohler, Wis

SOURCE Ware Dryer 

TEST DATE 8/6/2010 

TEST RUN NO. WD1-M23-3 

TEST TIME 07:30-11:1

SAMPLE VOLUME : 148.931 

SAMPLE VOLUME : 4.218 

GAS FLOW RATE : 150,433 

OXYGEN CONTENT : 20.8 

TOTAL 

SAMPLE 

DIOXIN I FURAN MASS 

COMPOUND 

2,3,7,8-TCDD < 0.00280 

Total TCDD < 0.00280 

1,2,3,7,8 PeCDD 0.00731 

Total PeCDD 0.02880 

1,2,3,4,7,8 HxCDD 0.00695 

1,2,3,6,7,8 HxCDD < 0.00710 

1,2,3,7,8,9 HxCDD 0.01800 

Total HxCDD 0.05410 

1,2,3,4,6,7,8 HpCDD 0.19200 

Total HpCDD 0.35200 

1,2,3,4,6,5,7,8 OCDD 2.17000 

2,3,7,8-TCDF < 0.00160 

Total TCDF < 0.00160 

1,2,3,7,8 PeCDF < 0.00200 2,3,4,7,8 PeCDF < 0.00200 

Total PeCDF < 0.00200 

1,2,3,4,7,8 HxCDF 0.00168 

1,2,3,6,7,8 HxCDF < 0.00086 

1 ,2,3, 7,8,9 HxCDF < 0.00091 

2,3,4,6,7,8 HxCDF < 0.00100 

Total HxCDF 0.00168 

1,2,3,4,6,7,8 HpCDF < 0.00110 

1,2,3,4, 7,8,9 HpCDF < 0.00110 

Total HpCDF < 0.00140 

1,2,3,4,6,5,7,8 OCDF < 0.00220 

TOTAL 2.61658 

899-02 
Sample Volume, dscf 32.848 30.340 34.442 

% lsokinetic 102.4 97.8 106.6 

Filterable PM collected, mg 12.35 12.00 11.00 11.78 

Concentration 

gr/dscf 0.00580 0.00610 0.00493 0.00561 

lb/dscf x 1 0-ti 0.8290 0.8721 0.7042 0.8018 

mg/dscm 13.277 13.967 11.279 12.841 

Emission rate 

lb/hr 0.4186 0.4260 0.3582 0.4009 

lblton of solids sprayed 9.9083 10.0821 8.4775 9.4893 

kg/hr 0.1899 0.1932 0.1625 0.1819 

kg/Mg of solids sprayed 4.9542 5.0411 4.2387 4.7482 

899-02 4-16 
899-02 
Moisture, av. % vol 3.22 3.04 2.50 2.92 

C02, av.% vol, db 0.10 0.10 0.10 0.10 

0 2, av. % vol, db 20.90 20.90 20.90 20.90 

PARTICULATE MATTER {PM} 

Sample Volume, dscf 32.848 30.340 34.442 

% lsokinetic 102.4 97.8 106.6 

Filterable PM collected, mg 12.35 12.00 11.00 11.78 

Concentration 

gr/dscf 0.00580 0.00610 0.00493 0.00561 

lb/dscf x 1 o·6 0.8290 0.8721 0.7042 0.8018 

mg/dscm 13.277 13.967 11.279 12.841 

Emission rate 

lb/hr 0.4186 0.4260 0.3582 0.4009 

lblton of solids sprayed 9.9083 10.0821 8.4775 9.4893 

kg/hr 0.1899 0.1932 0.1625 0.1819 

kg/Mg of solids sprayed 4.9542 5.0411 4.2387 4.7482 

A-1 
VIc= 23.2 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

Bws = 

Vwstd = 0.0322 

Vw&d + Vmstd 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

Bws@saturation = S.V.P. = 0.0378 Ps 

Pbar + 13.6 

S.V.P. = 1.102 in. Hg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0322 

A-2 
ABSOLUTE STACK GAS PRESSURE 

p p Pstatic s = bar+-- 13.6 

STACK GAS VELOCITY 

Vs (85.49)(CP)(avg.JMi) / (Ps;~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Qs = 60 X Vs xAs 

Stack Area= 5.585 tf 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Qstdw (528) (Ps) 29.92 (Qs) T5 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd :.: }os{~: }1- Bws) 

= 29.13 

= 27.355 

= 9,167 

= 8,699 

521,923 

= 8,419 

505,130 

in.Hg 

Wsec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 

A-3 
Vwstd + Vmstd 

PARTICULATE CONCENTRATION IN STACK GAS ON A DRY BASIS 

(0.01543{ ~) Total = 0.00580 gr/dscf 

Cs 

Vmstd 

C _ (Mn)(35.315) 

s,mg/dscm -

(Vmstd) = 13.277 mg/dscm 

c~ (2.205 x 1 o-6 { ) C's Total = 0.8290 x 10.~; lbs/dscf 

EMISSION RATE 

pmr = ( 0 )o51d)(60) = 0.4186 lbs/hr 

1.8336 ton/yr 

ER = pm~bthr x 20001b 

lbltonotProduct PRiblhr 1 ton = 9.9083 lb/ton of solids sprayed 

ER _ pmrlblhr x 1000kg = 4.9542 kg/Mg of solids sprayed kgiMgo!Product- (PR )(2 20461b/k ) 1Mg kglhr • 9 

ISOKINETIC SAMPLING RATE 

%ISO 

(100)(Ts{(o.002669 x VIc)+(~: }r{Pbar +( ~~))] = 102.41 %1 

(60)(e)(V5 )(P5 )(An) 

An= 0.0003547 fr' Runtime= 60 minutes 

A-4 
VIc= 20.2 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

B _ Vwstd ws- Vws.d + Vms.d = 0.0304 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

Bws@saturation 

S.V.P. = 0.0391 

R + Pstatic 

bar 13.6 

S.V.P. = 1.138 in. Hg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0304 

A-5 
ABSOLUTE STACK GAS PRESSURE 

p =R + Pstatic s bar 13_

6 

STACK GAS VELOCITY 

V5 = (85.49)(Cp)(avgJ!;P) /(Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 =60 X V5 XA5 

Stack Area= 5.585 tf 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Ostdw ( 528 ) (Ps J 29.92 (Os) T5 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Ostd =( ~: }as{~:}1-Bws) 

A-6 

= 29.13 

= 26.460 

= 8,867 

= 8,399 

503,911 

= 8,143 

488,599 

in.Hg 

ft/sec 

acfm 

scfm, wb 

seth, wb 

dscfm 

dscfh 
ws - Vwstd + Vmstd 

x100 = 3.04 % 

PARTICULATE CONCENTRATION IN STACK GAS ON A DRY BASIS 

Total = 0.00610 gr/dscf 

C5 = (0.01543{ ~ J 

Vmstd 

C _ (Mn )(35.315) s.mgtdscm - (Vmstd) = 13.967 mg/dscm 

c~ = (2.205 x 10-6 { ~ J C's Total = 0.8721 x 10-ti lbs/dscf 

Vmstd 

EMISSION RATE 

pmr= ( ~~0 )ostd)(60) = 0.4260 lbs/hr 

1.8658 ton/yr 

ER _ pm~bthr 20001b = 10.0821 lb/ton of solids sprayed lbl!onofPrO<luct -~Xtlon lblhr 

ER _ pm~bthr 1000kg X = 5.0411 kg/Mg of solids sprayed kg/MgofProduct- {P~ )(2 2046lb/k ) 1Mg glhr · 9 

ISOKINETIC SAMPLING RATE 

%!SO 

(100)(Ts{(0.002669 x VIc)+(~: }r{Pbar +( ~ ))] 

= 97.79 %1 

(60)(6)(Vs)(Ps )(An) 

An= 0.0003547 tr Runtime= 60 minutes 

A-7 
VIc= 18.8 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

B _ Vwstd ws- = 0.0250 

Vwstd + Vmstd 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

Bws@saturation = S.V.P. = 0.0391 

R + Pstatic 

bar 13.6 

S.V.P. = 1.138 in. Hg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0250 

A-8 
ABSOLUTE STACK GAS PRESSURE 

p p Pstatic s"" bar+-- 13.6 

STACK GAS VELOCITY 

V5 =(85.49)(Cp)(avg~) /(Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Os = 60 X V5 XA5 

Stack Area= 5.585 ff 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

( 528 ) (Ps) Ostdw = 29.92 {Os) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

0 = ( 528 )co { Ps } 1 std 29.92 s T5 

Bws) 

= 29.13 

= 27.402 

= 9,182 

= 8,697 

521,840 

= 8,479 

508,768 

in.Hg 

ft/sec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 
= 

PARTICULATE CONCENTRATION IN STACK GAS ON A DRY BASIS 

C5 = (0.01543) ( ~ J 

Total = 

Vmstd 

{Mn){35.315) 

Cs,mgtdscm = {V ) mstd 

c~ = (2.205 x 1 o- >(~J Vmstd 

C's Total 

EMISSION RATE 

ER _ pm~bthr x 2000 lb 

lbltonofProduct - PRib/hr 1 ton 

ER _ pm~bthr x 1000kg 

kgtMgofProduct- (PR )(2 20461b/k ) 1Mg kg/hr · 9 

ISOKINETIC SAMPLING RATE 

(100)(T5)[(0.002669 x VIc)+ ( ~: }y {Pbar + ( ~~) J] 

%ISO = ---=----:---:-:-""7"":---:-cc----:--:---:-------=-

(60)(8)(V5 )(P5 )(An) 

An= 0.0003547 ftL Runtime= 

A-10 

= 

= 

= 

= 

= 

= 

60 

2.50 % 

0.00493 gr/dscf 

11.279 mg/dscm 

0.7042 x 10-ti lbs/dscf 

0.3582 lbs/hr 

1.5688 ton/yr 

8.4775 lb/ton of solids sprayed 

4.2387 kg/Mg of solids sprayed 

106.61 %1 

minutes 
Temperature, av. oF 316.9 312.6 299.3 309.6 

Velocity, av. ft/sec 40.592 40.656 40.281 40.510 

Volume flow, acfm 9,505.4 9,520.4 9,432.4 9,486.0 

Volume flow, acmm 269.16 269.58 267.09 268.61 

C02, av. % vol, db 0.10 0.20 0.00 0.10 

0 2, av. % vol, db 20.60 20.60 20.60 20.60 

A-11 
ABSOLUTE STACK GAS PRESSURE 

Ps p + Pstatic 

bar 13.6 = 29.28 in.Hg 

STACK GAS VELOCITY 

V5 = (85.49)(cP)(avgEP)~·{Ps~~s) = 40.592 ft/sec 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Os 60 X V5 xA5 = 9,505.4 acfm 

Stack Area= 3.903 tr 

A-12 
ABSOLUTE STACK GAS PRESSURE 

Ps p + Pstatic 

bar 13.6 = 29.27 in.Hg 

STACK GAS VELOCITY 

Vs (85.49)(cP)(avgJM') I (Ps~~s) = 40.656 ftlsec 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V5 XA5 = 9,520.4 acfm 

Stack Area= 3.903 ft2 

A-13 
ABSOLUTE STACK GAS PRESSURE 

P static Ps =Pbar +-- = 29.22 in.Hg 13.6 

STACK GAS VELOCITY 

V5 = (85.49)(CP)(avgfAP) (Ps~~s) = 40.281 ftlsec 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V5 XA5 = 9,432.4 acfm 

Stack Area= 3.903 ff 

A-14 
Temperature, av. oF 293.3 293.1 281.8 289.4 

Velocity, av. ftlsec 9.419 8.489 8.399 8.769 

Volume flow, acfm 1,666.3 1,501.7 1,485.7 1,551.2 

Volume flow, acmm 47.184 42.522 42.071 43.925 

C02, av.% vol, db 0.10 0.10 0.10 0.10 

0 2, av. % vol, db 20.70 20.80 20.60 20.70 

A-15 
ABSOLUTE STACK GAS PRESSURE 

p p Pstatic 

s = bar+ 13.

6 = 29.29 in.Hg 

STACK GAS VELOCITY 

V5 = (85.49)(CP )(avgfAP) / (Ps~~s) = 9.419 ft/sec 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V5 XA5 = 1,666.3 acfm 

Stack Area= 2.948 tt2 

A-16 
ABSOLUTE STACK GAS PRESSURE 

p p Pstatic s = bar+-- = 29.28 in.Hg 13.6 

STACK GAS VELOCITY 

V6 = (85.49)(cp)(avg&) / (Ps~~s) = 8.489 ft/sec 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 8 = 60 X V5 XA8 = 1,501.7 acfm 

Stack Area= 2.948 tf 

A-17 
ABSOLUTE STACK GAS PRESSURE 

p p Pstalic s= bar+-- = 29.23 in.Hg 13.6 

STACK GAS VELOCITY 

V5 = (85.49)(CP)(avgJh.P}~ (Ps;~s) = 8.399 ft/sec 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V5 XA5 = 1,485.7 acfm 

Stack Area= 2.948 ft2 

A-18 
ng/dscm @ 7 % Oxygen 

2,3,7,8-TCDD 0.07280 0.06224 0.06322 0.06609 

Total TCDD 1.32881 1.44433 1.87411 1.54909 

1,2,3,7,8 PeCDD 0.26294 0.24142 0.33310 0.27915 

Total PeCDD 2.66470 2.90960 3.80480 3.12636 

1 ,2,3,4,7,8 HxCDD 0.16539 0.16118 0.12023 0.14893 

1 ,2,3,6,7,8 HxCDD 0.33998 0.30352 0.33875 0.32742 

1,2,3,7,8,9 HxCDD 0.55344 0.51842 0.53394 0.53527 

Total HxCDD 5.80296 5.31682 5.48796 5.53591 

1,2,3,4,6,7,8 HpCDD 3.42806 3.15381 3.52192 3.36793 

Total HpCDD 6.44616 5.96572 6.49221 6.30136 

1,2,3,4,6,5,7,8 OCDD (Total) 28.41400 26.09567 29.77362 28.09443 

2,3,7,8-TCDF < 0.02545 0.02658 0.02885 < 0.02696 

TotaiTCDF 0.09966 0.09001 0.17680 0.12216 

1,2,3,7,8 PeCDF 0.00990 0.00858 0.00983 0.00944 

2,3,4,7,8 PeCDF < 0.01555 0.01605 0.01612 < 0.01591 

Total PeCDF 0.05817 0.08861 0.06096 0.06925 

1,2,3,4,7,8 HxCDF < 0.00212 0.00521 < 0.00580 < 0.00437 

1 ,2,3,6,7,8 HxCDF < 0.00431 < 0.00293 < 0.00530 < O.D0418 

1,2,3,7,8,9 HxCDF < 0.00247 < 0.00181 < 0.00559 < 0.00329 

2,3,4,6,7,8 HxCDF < 0.00113 < 0.00119 < 0.00636 < 0.00289 

Total HxCDF 0.00157 0.00998 0.03246 0.01467 

1 ,2,3,4,6, 7,8 HpCDF < 0.00424 0.00345 0.00550 < 0.00440 

1 ,2,3,4,7,8,9 HpCDF < 0.00064 < 0.00126 < 0.00665 < 0.00285 

Total HpCDF < 0.00064 0.00705 0.00941 < 0.00570 

1 ,2,3,4,6,5,7,8 OCDF (TotaQ < 0.00580 0.00886 0.00721 < 0.00729 

TOTAL <44.82246 < 41.93665 <47.71955 <44.82622 

A-19 
VIc= 272.2 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

0.0782 

FRACTIONAL MOISTURE CONTENT OF STACK GAS @SATURATION 

MF= [J•as1 ( r'•::s)]J_05 = 

p 

T = 506.8 OK 

P = 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 

A-20 

1.0000 

0.0782 
ABSOLUTE STACK GAS PRESSURE 

Ps p + Pstatic 

bar 13.6 

STACK GAS VELOCITY 

Vs (85.49)(CP)(avg.J.hll) I (Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Os 60 X V8 XA5 

Stack Area= 6.7771 ff 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

( 528 ) (Ps) Qsldw == 29.92 (Qs) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Ostd = (528) (PsJ 29.92 (Os) Ts (1 Bws) 

= 29.28 

= 27.081 

= 11,011.77 

= 6,233.75 

374,025.0 

= 5,746.05 

344,763.0 

in.Hg 

ft/sec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 

A-21 
A-22 

%ISO 

(60)(e)(V5 )(Ps)( An) 

= 97.24% I 

0.00076291 ft' Runtime (9) = 240 minutes 
)> 

I 

"' c..v 

COMPANY: 

LOCATION: 

SOURCE: 

TEST DATE: 

TEST RUN NO. : 

TEST TIME: 

Kohler Company 

Kohler, Wisconsin 

Tunnel Kiln #19- POC 

8/3/2010 

TK19-M23-1 

07:34 - 11 :44 

SAMPLE VOLUME (Vm,.,): 

SAMPLE VOLUME (Vm,td): 

GAS FLOW RATE (Q,.,): 

OXYGEN CONTENT (%02): 

TOTAL 

SAMPLE 

DIOXIN I FURAN MASS(M.) 

COMPOUND (nanogram) 

2,3,7,8-TCDD 0.10300 

TotaiTCDD 1.88000 

1,2,3,7,8 PeCDD 0.37200 

Total PeCDD 3.77000 

1,2,3,4,7,8 HxCDD 0.23400 

1,2,3,6,7,8 HxCDD 0.48100 

1,2,3,7,8,9 HxCDD 0.78300 

Total HxCDD 8.21000 

1,2,3,4,6,7,8 HpCDD 4.85000 

Total HpCDD 9.12000 

1,2,3,4,6,5,7,8 OCDD 40.20000 

2,3,7,8-TCDF < 0.03600 

Total TCDF 0.14100 

1,2,3,7,8 PeCDF 0.01400 

2,3,4,7,8 PeCDF < 0.02200 

Total PeCDF 0.08230 

1,2,3,4,7,8 HxCDF < 0.00300 

1,2,3,6,7,8 HxCDF < 0.00610 

1 ,2,3, 7,8,9 HxCDF < 0.00350 

2,3,4,6, 7,8 HxCDF < 0.00160 

Total HxCDF 0.00222 

1,2,3,4,6,7,8 HpCDF < 0.00600 

1,2,3,4,7,8,9 HpCDF < 0.00091 

Total HpCDF < 0.00091 

1 ,2,3,4,6,5,7,8 OCDF < 0.00820 

TOTAL 63.41463 

picograms to nanograms 

tng 

M ..... = M .... X 1 000 pg 
VIc= 270.6 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

0.0784 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

[Ja361 ( r'"~~JJJ o.s 

MF = p 

1.0000 

T = 503.9 OK 

P = 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0784 

A-24 
ABSOLUTE STACK GAS PRESSURE 

p R Pstatic s = bar+-- 13.6 

STACK GAS VELOCITY 

V5 = (85.49)(Cp)(avg/AP) (Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V5 XA5 

Stack Area= 6.7771 tf 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

( 528 ) (Ps) Osldw = 29.92 (Qs) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

( 528 ) (Ps) Qstd = 29.92 (Os) Ts (1 Bws) 

= 29.28 

= 27.795 

= 11,302.41 

= 6,435.64 

386,138.6 

= 5,930.89 

355,853.7 

in.Hg 

ft/sec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 

A-25 
A-26 

%ISO 

(60)(9)(Vs)(Ps)(An) 

= 93.41 %I 

A n = 0.00076291 tr Runtime (9) = 60 minutes 
=!> 

1\J ~ COMPANY: Kohler Company LOCATION: Kohler, Wisconsin SOURCE: Tunnel Kiln #19 POC TEST DATE: 81312010 TEST RUN NO. : TK19-M23-2 TEST TIME: 13:05-17:15 SAMPLE VOLUME (V.,.,td): SAMPLE VOLUME (Vmatd): GAS FLOW RATE (Q,td): OXYGEN CONTENT (%02): TOTAL SAMPLE DIOXIN I FURAN MASS(Mn) COMPOUND (nanogram) 2,3,7,8-TCDD 0.08920 TotaiTCDD 2.07000 1,2,3,7,8 PeCDD 0.34600 Total PeCDD 4.17000 1,2,3,4,7,8 HxCDD 0.23100 1,2,3,6,7,8 HxCDD 0.43500 1,2,3,7,8,9 HxCDD 0.74300 TotaiHxCDD 7.62000 1,2,3,4,6,7,8 HpCDD 4.52000 TotaiHpCDD 8.55000 1,2,3,4,6,5,7,8 OCDD 37.40000 2,3,7,8-TCDF 0.03810 Total TCDF 0.12900 1,2,3,7,8 PeCDF 0.01230 2,3,4,7,8 PeCDF 0.02300 Total PeCDF 0.12700 1,2,3,4,7,8 HxCDF 0.00746 1,2,3,6,7,8 HxCDF < 0.00420 1,2,3,7,8,9 HxCDF < 0.00260 2,3,4,6,7,8 HxCDF < 0.00170 TotaiHxCDF 0.01430 0.00494 < 0.00180 0.01010 picograms to nanograms 1ng M...,. =M,._, X 1000pg 
VIc= 279.6 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

Bws = Vwstd = 0.0818 

Vwstd + Vmstd 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION l [8361 _( 

1

893.5 JJ] 10 T 27.65 _ 0.5 

MF = 1.0000 

p 

T= 502.4 OK 

P= 742.3 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws= 0.0818 

A-28 
ABSOLUTE STACK GAS PRESSURE 

p =P + Pstatic s bar 13_

6 

STACK GAS VELOCITY 

V5 = (85.49)(CP)(avg.J"M>) (Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V8 xA5 

Stack Area= 6.7771 tf 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

( 528 ) (Ps) Qsldw = 29.92 (Os) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qsld = ( 528 ) (Ps) 29_

92 (Os) Ts (1-Bws) 

= 29.22 

= 26.252 

= 10,674.98 

= 6,083.20 

364,992.0 

= 5,585.38 

335,123.0 

in.Hg 

ft/sec 

acfm 

scfm, wb 

seth, wb 

dscfm 

dscfh 

A-29 
A-30 

(60)(8)(V5 )(Ps )(An) 97.86% I 

An = 0.00076291 ff Runtime (8) = 60 minutes 
)> 

I 

w ~ COMPANY: Kohler Company LOCATION: Kohler, Wisconsin SOURCE: Tunnel Kiln #19- POC TEST DATE: 8/412010 TEST RUN NO. : TK19-M23-3 TEST TIME: 07:20-11:33 SAMPLE VOLUME (Vm ... J: SAMPLE VOLUME (Vmstd): GAS FLOW RATE (Q,.,.): OXYGEN CONTENT (%02): TOTAL SAMPLE DIOXIN I FURAN MASS(M0 ) COMPOUND (nanogram) 2,3,7,8-TCDD 0.08940 TotaiTCDD 2.65000 1,2,3,7,8 PeCDD 0.47100 TotaiPeCDD 5.38000 1,2,3,4,7,8 HxCDD 0.17000 1,2,3,6,7,8 HxCDD 0.47900 1,2,3,7,8,9 HxCDD 0.75500 Total HxCDD 7.76000 1,2,3,4,6,7,8 HpCDD 4.98000 TotaiHpCDD 9.18000 1,2,3,4,6,5,7,8 OCDD 42.10000 2,3,7,8-TCDF 0.04080 Total TCDF 0.25000 1,2,3,7,8 PeCDF 0.01390 2,3,4,7,8 PeCDF 0.02280 Total PeCDF 0.08620 1,2,3,4,7,8 HxCDF < 0.00820 1,2,3,6,7,8 HxCDF < 0.00750 1,2,3,7,8,9 HxCDF < 0.00790 2,3,4,6,7,8 HxCDF < 0.00900 TotaiHxCDF 0.04590 1,2,3,4,6,7,8 HpCDF 0.00778 1,2,3,4,7,8,9 HpCDF < 0.00940 TotaiHpCDF 0.01330 1,2,3,4,6,5,7,8 OCOF 0.01020 TOTAL 67.47560 picograms to nanograms 1ng M •. og = M .... X 1000 pg 
Concentration 

ppmvdb 0.56 0.48 0.56 0.54 

ppmv db @ 7% 0 2 1.60 1.39 1.56 1.52 

lb/dscf x 1 o-s 0.053 0.045 0.053 0.051 

Emission rate 

lb/hr 0.01777 0.01482 0.01753 0.01671 

lblton of Product 0.02030 0.01692 0.02003 0.01908 

kg/hr 0.00806 0.00672 0.00795 0.00758 

kg/Mg of Product 0.01015 0.00846 0.01001 0.00954 

HYDROGEN FLUORIDE {HF} 

Concentration 

ppmv db 16.7 17.3 17.0 17.0 

ppmv db @ 7% 02 47.29 50.18 47.27 48.25 

lb/dscf x 1 o-s 0.866 0.900 0.883 0.883 

Emission rate 

lb/hr 0.28796 0.29411 0.29145 0.29117 

lb/ton of Product 0.32891 0.33594 0.33289 0.33258 

kg/hr 0.13062 0.13341 0.13220 0.13208 

kg/Mg of Product 0.16446 0.16797 0.16645 0.16629 

A-32 
VIc= 77.3 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

Bws = Vws.d 

= 0.0853 

Vws.d +Vms.d 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

[ [8361 _( 1893.5 JJj 10 T 27.65 _ 0

_

5 

MF = 1.0000 

p 

T= 508.4 OK 

P= 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0853 

A-33 
A-34 

ABSOLUTE STACK GAS PRESSURE 

p =P + Pstatic s bar 13.

6 

STACK GAS VELOCITY 

V5 = (85.49)(CP)(avg-/b.P) / (Ps;~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Q5 = 60 X V5 xA5 

Stack Area= 6.77713 ft2 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Qsldw (~}as{Ps) 29.92 T5 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd = ( 528 ) (Ps) 29.

92 (Qs) Ts (1-Bws) 

= 29.28 

= 26.409 

= 10,738.63 

= 6,059.72 

363,583 

= 5,543.02 

332,581 

in.Hg 

ftlsec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 
An= 0.00077519 ft' Runtime {B) = 60 minutes 

Total11g HCI in sample (M0 ) 

Concentration of HCI 

3 

C C

. 385.26ft /lb- mole 

1 06 

s(ppmvdb) s(lbldscf) x 36.451b/lb- mole x 

C X 13.9 

s(wmvdb) 20.9-%02 

HCI Mass Rate: E Os X c~(lbldsd) 

20001b 

PR,b/hr 1ton 

ERib/tonofProduct = 

ER _ pm~b/hr x 1000kg 

kg/MgotProduct- (PR )(2 20461b/k ) 1M kg/hr · 9 9 = 

= 

= 

= 

= 

= 

945.9 11g 

0.0534 X 10-6 lbs/ 

dscf 

0.56 ppmv db 

1.60 ppmv db @ 7% 02 

0.01777 lb/hr 

0.00806 kg/hr 

0.02030 lb/ton of product 

0.01015 kg/Mg of product 

A-35 
(

)(

)(

)(

)(

) 

0.00077519 ft' Runtime (l:l) = 60 minutes 

Total ~g HF in sample (M0 ) 

Concentration of HF 

c~(lbldscf) (2,205x 1 o-9 1b/ 119)(Mn) 

vmstd 

c· x 385.26 ft3 /lb mole x 1 o" •tlbld""1 20.011b lib- mole 

C X 13.9 

s(ppm,db) 20.9-%02 

HF Mass Rate: 

ER = pmGblhr x 2000 lb 

lbltono!Product PR 1t lblhr on = 

ERkg/MgofProduct PmGb/hr 1000kg 

(PRkg/hr )(2.20461b/kg) X 1Mg 

A-36 

= 

= 

= 

= 

= 

15,327.1 ~g 

0.8658 x 10-6 lbs/ 

dscf 

16.67 ppmv db 

47.29 ppmv db @ 7% 0 2 

0.28796 lbs/hr 

0.13062 kg/hr 

0.32891 lb/ton of product 

0.16446 kg/Mg of product 
VIc= 76.4 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

B - Vw&d ws- Vw&d + Vm&d = 0.0858 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION l [ 8361 ( 18935 ) lj 10 T 27.65 - 0.5 

MF= = 1.0000 

p 

T= 506.5 OK 

P= 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0858 

A-37 
A-38 

ABSOLUTE STACK GAS PRESSURE 

Ps p + Pstatic 

bar 13.6 

STACK GAS VELOCITY 

v. = (85.49)(Cp)(avgJ6P)~(P.~(M.) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Q5 = 60 X V5 XA5 

Stack Area= 6.77713 ff 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Qstdw ( 528 ) (Ps) 29.92 (Qs) T5 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd = ( 528 ) (Ps) 29.92 (Qs) Ts (1- Bws) 

= 29.28 

= 25.867 

= 10,518.28 

= 5,958.15 

357,489 

= 5,446.90 

326,814 

in.Hg 

ft/sec 

acfm 

scfm, wb 

seth, wb 

dscfm 

dscfh 
(60)(6)(Vs)(Ps )(An) 

An= 0.00077519 ft" Runtime (e) = 60 minutes 

Total J.tg HCI in sample (Mn) = 787.8 1-19 

Concentration of HCI . (2,205x10-9 1b/!-Lg)(Mn) 

cs(lb/dscf) = = 0.0453 x 10,..;1bs/ 

vmstd dscf 

Cs(ppmvdb) c· 385.26ft3 /lb- mole 

s(lb/dsct) x 36.451b lib-mole X 106 = 0.48 ppmvdb 

C = C X 13.9 s(ppmvdbl s(ppmvdb) ZQ.9 _ %Q2 

= 1.39 ppmv db@ 7% 02 

HCI Mass Rate: E Qs X C~(lb/dsd) = 0.01482 lb/hr 

0.00672 kg/hr 

ER = pm~b/hr x 20001b 

lbltono!Product PR = 0.01692 lb/ton of product 1 ton lb/hr 

ER - pmGbthr x 1000kg 0.00846 kg/Mg of product llgiMgofProduct- (PR )(2 20461b/k ) 1Mg = llg/hr · 9 

A-39 
An= 0.00077519 ft' Runtime (e) = 60 minutes 

Total flg HF in sample (M0 ) 

Concentration of HF 

C =C· x385.26ft3/lb-molex 10• •lppnwdb) •Obldsdl 2Q.Q1Jb fib- mole 

C X 13.9 

$(""""""') 20.9 %02 

HF Mass Rate: 

pm~bthr 20001b --x--

PR1bthr 1ton ERibltonofProduct = 

pm~bthr 1000 kg X 

(PRkg/hr )(2.20461b/kg) 1Mg ERkg/MgofProduct = 

A-40 

= 

= 

= 

= 

= 

15,637.3 flg 

0.8999 x 10..s lbs/ 

dscf 

17.33 ppmv db 

50.18 ppmv db@ 7%02 

0.29411 lbs/hr 

0.13341 kg/hr 

0.33594 lb/ton of product 

0.16797 kg/Mg of product 
VIc= 72.1 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

B Vw&d = ws Vw&d + Vm&d 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

MF JJ &361-( T1B:.~ ll)-05 " 

p 

T = 505.7 °K 

P = 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 

0.0813 

1.0000 

0.0813 

A-41 
A-42 

ABSOLUTE STACK GAS PRESSURE 

p = p + Pstatic s bar 13.

6 

STACK GAS VELOCITY 

v. = (85.49)(cP)(avg~)~(P.~CM.) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Qs = 60 X vs xAs 

Stack Area= 6.77713 te 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Ostdw ( 528 ) (Ps J = 29.

92 (Qs) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd :.: )os{~: }1-Bws) 

= 29.28 

= 25.948 

= 10,551.14 

= 5,986.61 

359,196 

= 5,500.01 

330,001 

in.Hg 

ft/sec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 
0.00077519 tr Runtime (9) = 

Total!lg HCI in sample (Mn) = 

Concentration of HCI . (2,205x10-9 1biJ.l9)(Mn) 

cs(lb/dscf) = v 

mstd 

= 

3 C _ c' X 385.26ft fib- mole X 1 0

6 

s(ppmvdb) - s(Jb/dscf) 36.451b /lb- mole = 

C = C X 13.9 s(ppmvdb) s(ppmvdb) 20.

9 _ %Q2 

= 

HCI Mass Rate: E = Qs X c~(lb/dsd) = 

ER _ pm~bthr x 20001b 

lbltono!Product - PR 1 t tbthr on = 

ER = pm~blhr x 1000kg 

kgtMgotProduct (PR ) (2 20461b I k ) 1 Mg kglhr · 9 = 

60 minutes 

924.3 j.lg 

0.0531 x 10..s lbs/ 

dscf 

0.56 ppmvdb 

1.56 ppmv db @ 7% 0 2 

0.01753 lb/hr 

0.00795 kg/hr 

0.02003 lb/ton of product 

0.01001 kg/Mg of product 

A-43 
(60)(8Vs)(s) 

An= 0.00077519 ft' Runtime (0) = 60 minutes 

Total J.lg HF in sample (Mn) = 15,364.4 J.lQ 

Concentration of HF , ( 2,205 X 10-9 lb/ J.l9)(Mn) 

cs(lb/dscf) = = 0.8832 X 10-61bs/ 

vmstd dscf 

c = c· X 385.26ft3 I lb -mole X 10" = 17.00 ppmv db 

•lppmvdo) ' 1'•'dod) 20.011b I lb- mole 

13.9 

ppmv db @ 7% 02 cs(ppmvdb) = C,(ppmvdb) X 20.9 = 47.27 

%02 

HF Mass Rate: E Qs X C~(lb/dsd) = 0.29145 lbs/hr 

0.13220 kg/hr 

ER _ pm~blhr 20001b 

lbltono!Product - --x 1ton = 0.33289 lb/ton of product PRibtnr 

ER _ pm~blhr x 1000kg 0.16645 kg/Mg of product kgiMgorProduct - (PR )(2 20461b/k ) 1M = kglhr · 9 9 

A-44 
lblhrx 10"' 0.72039 1.36357 1.64265 1.24667 

lb/ton of product X 1 O"' 0.87162 1.67401 1.87624 1.47395 

kg/hr x 10 .. 0.32677 0.62758 0.74510 0.56648 

kg/Mg of product x 10"' 0.43581 0.83700 0.93812 0.73698 

Beryllium IBe) 

Concentration 

lbldscf x 1 o-s < 0.00413 < 0.00402 <0.00423 < 0.00413 

119/dscm @ 7% 

0 2 < 0.200 < 0.190 < 0.201 < 0.197 

Emission rate 

lblhrx 10"' < 0.01426 < 0.01417 <0.01424 < 0.01422 

lb/ton of product x 10"' <0.01725 <0.01714 <0.01627 <O.D1669 

kg/hrx 10"' <0.00647 <0.00643 <0.00646 <0.00645 

kg/Mg of product x 1 0 .. <0.00862 <0.00857 <0.00813 <0.00844 

Cadmium !Cdl 

Concentration 

lb/dsct x 1 o·• < 0.00207 < 0.00201 < 0.00355 < 0.00254 

I'Q/dscm @ 7% a. < 0.100 < 0.095 < 0.168 < 0.121 

Emission rate 

lblhrx 10"' <0.00713 < 0.00708 < 0.01193 < 0.00871 

lb/ton of product x 10"' <0.00862 <0.00857 <0.01363 <0.01027 

kglhr x 10 .. <0.00323 <0.00321 <0.00541 <0.00395 

kg/Mg of product x 1 0 .. <0.00431 <0.00429 <0.00661 <0.00514 

Chromium (Crl 

Concentration 

lbtdsct x 1 o·• 0.18133 0.24209 0.39890 0.27411 

119/dscm @ 7% 

0 2 8.777 11.469 18.898 13.048 

Emission rate 

lblhrx 10"' 0.82516 0.85370 1.34160 0.94016 

lbfton of product X 1 O"' 0.75640 1.03291 1.53239 1.10723 

kg/hrx 10 .. 0.28357 0.38724 0.60855 0.42645 

kg/Mg of product x 10"' 0.37820 0.51646 0.76619 0.55362 

A-45 
Cobalt!Col 

Concentration 

lbldscf x 1 o"' 0.00648 0.00558 0.00819 0.00674 

pg/dscm @ 7% 0 2 0.314 0.263 0.388 0.322 

Emission rate 

lb/hrx 10-< 0.02233 0.01960 0.02754 0.02316 

lbllon of productx 10"' 0.02702 0.02371 0.03145 0.02739 

kglhr x 104 0.01013 0.00889 0.01249 0.01050 

kg/Mg of productx 10.,. 0.01351 0.01186 0.01573 0.01370 

FilterablePM collected, mg 18.21 18.52 16.31 11.78 

Concentration 

grldscf 0.00176 0.00174 0.00161 0.00170 

lbldscf x 1 o"' 0.25103 0.24804 0.23027 0.24311 

mgldscm@ 7% ~ 12.149 11.748 10.907 11.602 

Emission rate 

lb/hr 0.08652 0.08744 0.07742 0.08379 

lblton of product 0.10466 0.10580 0.08843 0.09964 

kglhr 0.03925 0.03966 0.03512 0.03801 

kg/Mg of product 0.05234 0.05290 0.04422 0.04982 

A-46 
VIc = 271.1 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

= 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

[ 

[8.361- ( 1~93.5 )J] 

10 T 27.65 _ 0_

5 

MF= = 

p 

T = 504.5 OK 

P = 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 

0.0739 

1.0000 

0.0739 

A-47 
ABSOLUTE STACK GAS PRESSURE 

p =P + Pstatic 

s bar 13.

6 

STACK GAS VELOCITY 

V5 =(85.49)(cp)(avg.JliP) /(Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Qs = 60 X Vs xAs 

Stack Area= 6.7771 ft2 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Os~w =( ~: }as{~:J STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

0 ==( 528 }a {Ps } 1 std 29.92 8 T5 

Bws) 

A-48 

= 29.28 

= 26.830 

= 10,910 

= 6,204.5 

372,271 

= 5,746.1 

344,766 

in.Hg 

ftlsec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 
Vwst.d + Vmst.d 

PARTICULATE CONCENTRATION IN STACK GAS ON A DRY BASIS 

C5 = (0.01543{ ~) Filterable = 0.00176 gr/dscf 

Vmstd 

C _ (Mn){35.315) ( 13.9 ) 

s,mg/dscm@7%0, - {Vmstd) X 20.9-%02 = 12.149 mg/dscm @ 7% 0 2 

c~ = (2.205 x 10-6 { ~) C's Filterable = 0.25103 X 1 0-~ lbs/dscf 

Vmstd 

EMISSION RATE 

pmr = ( ~~ 0 )astd)(60) = 0.08652 lb/hr 

0.03925 kg/hr 

ER = pmr1b/hr x 20001b 

lb/tonofProduct PRib/hr 1ton = 0.10468 lb/ton of product 

ER = pmrlb/hr x 1000kg = 0.05234 kg/Mg of product kg/MgofProduct (PR ) ( 2 20461b f k ) 1M kg/hr · 9 9 

ISOKINETIC SAMPLING RATE 

(100)(Ts{(0.002669 x VIc)+(~: }r{Pbar + c~~) JJ 

%ISO= = 101.40 %1 

(60)(8)(V5 )(Ps )(An) 

An= 0.0007752 ftL Runtime= 240 minutes 

A-49 
0.1 0.2630 0.1000 1.000 0.013 0.013 1.000 0.100 0.1630 

FHSample FH Blank BH Sample BH Blank Total Metal 

(M~~t} (Mftlb} (Mbh} (Mbhb) (MJ 

Metal !micrograms} (micrograms) (micrograms) (micrograms) (micrograms) 

Antimony 2.230 2.050 0.129 0.129 0.300 BDL 

Arsenic 8.270 1.000 8.090 0.200 15.160 ADL 

Beryllium 0.200 0.200 0.100 0.100 0.300 BDL 

Cadmium 0.475 0.330 0.052 0.593 0.150 BDL 

Chromium 16.700 3.880 0.877 0.541 13.156 ADL 

lead 42.700 1.360 0.446 0.234 41.552 ADL 

Manganese 3.000 2.530 1.130 0.763 0.837 ADL 

Nickel 10.100 2.290 0.927 1.000 7.737 ADL 

Selenium 9.630 2.000 12.700 1.000 19.330 ADL 

Cobalt 0.507 0.200 0.263 0.100 0.470 ADL 

Mt =(Mfh -Mfhb)+(Mbh -Mbhb) 

A-50 
:rCJ1 

..... 

------

----

-----

-----

--- 

1:1!!'-! 

---

rEN111110NJ/16NrAl..., IIYC. 

Client: 

Location: 

Source: 

Date: 

Run#: 

Kohler Compa

Kohler, Wisco

Tunnel Kiln #1

8/3/2010 

TK19-M29-1 

Metal Fraction {m

Mercury 1B (Hgfh) 

2B (Hgbh2) 

3A (Hgbh3A) 

3B (Hgbh3e) 

3C (Hgbh3cl 

H
= < 0.004135 x 10"9 lb/dscf 

= 0.208951 x 1 0"9 lb/dscf 

= < 0.004135 x 10"9 1b/dscf 

= < 0.002067 x 10·~ lb/dscf 

= 0.181330 x 1 0_, lb/dscf 

= 0.572713 x 1 o·• lb/dscf 

Metals emission rate ( x104 ibll!r)i 

= < 0.014256 x1 O ... lb/hr 

= 0.720391 x10 ... 1b/hr 

= < 0.014256 x10 ... 1b/hr 

= < 0.007128 x1 O ... lb/hr 

0.625163 x1 O ... lb/hr 

= 1.97 4518 x1 O ... lb/hr 

Metals emission rate ( x10 .. kglhr): 

= < 0.006466 x1 0 ... kg/hr 

= 0.326767 x10 ... kg/hr 

= < 0.006466 x1 0 ... kg/hr 

= < 0.003233 x1 0 ... kg/hr 

= 0.283572 x10 ... kg/hr 

= 0.895635 x10 ... kg/hr 

A-52 

ARI Environmental, Inc. 

(

2.2046x10-9lb xM,J 

c'.= ).lg 

Vmstd 

Antimony (Sb) = 

Arsenic (As) = Beryllium (Be) = 

Cadmium (Cd) = Chromium (Cr) = 

Lead (Pb) 

Em,lbth• = C', x Ostd 

Antimony (Sb) = 

Arsenic (As) = 

Beryllium (Be) = 

Cadmium (Cd) = Chromium (Cr) = 

Lead (Pb) 

Em.kg/hr E X 1kg 

m 2.20461b 

Antimony (Sb) = 

Arsenic (As) = 

Beryllium (Be) = 

Cadmium (Cd) = Chromium (Cr) = 

Lead (Pb) 

Method 29 Mutti-Metals Calc Summary 

0.011536 x 10...,1b/dscf Manganese (Mn) 

0.320614 x 10"9 1b/dscf Mercury (Hg) 

0.106639 x 10"9 lb/dscf Nickel (Nil 

0.266426 x 10..., lb/dscf Selenium (Se) 

0.006478 x 10_, lb/dscf Cobalt (Co) 

0.039774 x1 O ... lb/hr Manganese (Mn) 

1.105366 x10 ... 1b/hr Mercury (Hg) 

0.367656 x1 O ... lb/hr Nickel (Ni) 

0.918546 x1 O ... lb/hr Selenium (Se) 

0.022334 x1 O ... lb/hr Cobalt(Co) 

0.018041 x10 ... kg/hr Manganese (Mn) 

0.501391 x10 ... kg/hr Mercury (Hg) 

0.166768 x1 0 ... kglhr Nickel (Ni) 

0.416650 x10 ... kg/hr Selenium (Se) 

0.010131 x10 ... kg/hr Cobalt(Co) 
A-53 

ARI Environmental. Inc. Method 29 Multi-Metals Calc Summary 
VIc = 304.6 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

Vwstd = 0.0801 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

[ 

[ 8.361 ( 1~93.5 )J] 10 T 27.65 -0.5 

MF= = p 

1.0000 

T = 503.6 °K 

P = 743.8 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0801 

A-54 
ABSOLUTE STACK GAS PRESSURE 

p p Pstatic s = bar+-- 13.6 

STACK GAS VELOCITY 

V5 = (85.49)(CP)(avg.fiP) (Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

as = 60 X Vs xAs 

Stack Area= 6.7771 te 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

( 528 ) (Ps J astdw = 29.92 (as) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

a =( 528 }a f=~}1-B ) std 29.92 s Ts ws 

= 29.28 

= 27.577 

= 11,214 

= 6,389.3 

383,356 

= 5,877.4 

352,646 

in.Hg 

ft/sec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 

A-55 
% 

Vwstd + Vmstd 

PARTICULATE CONCENTRATION IN STACK GAS ON A DRY BASIS 

Filterable = 0.00174 gr/dscf 

Cs (0.01543{ ~) Vmstd 

cs,mg/dsem@7%0, {Mn){35.315) x( 13.9 ) = 11.748 mg/dscm @ 7% 0 2 {Vmstd) 20.9-%02 

c~ = (2.205 x 10-6 { ~) C' s Filterable = 0.24804 x 10.,; lbs/dscf 

Vmstd 

EMISSION RATE 

pmr ~~ )ostd)(6o) = 0.08744 lbs/hr 

0.03966 kg/hr 

ERib/1onofProduct 

20001b 

-- = 0.10580 lb/ton of product PRibthr 1ton 

ER _ pmrlbtnr x 1000kg = 0.05290 kg/Mg of product kgtMgo!Product- (PR )(2 20461b/k ) 1M kg/hr · 9 9 

ISOKINETIC SAMPLING RATE 

(100)(Ts{(0.002669 x VIc)+(~: }r{Pbar +( ~~ ))] 

%ISO= = 102.05 %1 

(60)(9)(V5 )(P5 )(An) 

An= 0.0007752 tr Runtime= 240 minutes 

A-56 
FHSample FH Blank BHSample BH Blank Total Metal 

{Mftl) {Mihbl (Mbh) {Mbhbl (MJ 

Metal (micrograms! !micrograms) {micrograms) (micrograms) (micrograms) 

Antimony 2.600 2.050 0.169 0.129 0.590 ADL 

Arsenic 13.900 1.000 16.600 0.200 29.300 ADL 

Beryllium 0.200 0.200 0.100 0.100 0.300 BDL 

Cadmium 0.577 0.330 0.275 0.593 0.150 BDL 

Chromium 20.600 3.880 1.900 0.541 18.079 ADL 

Lead 55.000 1.360 0.648 0.234 54.054ADL 

Manganese 3.790 2.530 1.060 0.763 1.557 ADL 

Nickel 3.960 2.290 1.930 1.000 2.600 ADL 

Selenium 9.270 2.000 34.700 1.000 40.970 ADL 

Cobalt 0.397 0.200 0.318 0.100 0.415 ADL 

Mt (Mfh - Mfhb) + (Mbh - Mbhb) 

A-57 
)> 

I 

()1 

()) 

------

----

-----

-----

---

---

=r-=1 ~~~II 

-----

.,.. ENVI!fONMENTAL Y INC. 

Client: 

Location: 

Source: 

Date: 

Run#: 

Kohler Comp

Kohler, Wisco

Tunnel Kiln #

8/3/2010 

TK19-M29-2 

Metal Fraction (

Mercury 1B (Hg1h) 

2B (Hgbh2l 

3A (Hgbh3A) 

3B (Hgbh3B) 

3C (Hgbh3c) 

H
Metals c.oncentrat;on ( xio·• lbldscf): 

= < 0.007900 

= 0.392339 

= < 0.004017 

= < 0.002009 

= 0.242085 

= 0.723805 

Metals emission rata ( x10"" lblhr): 

= < 0.027860 

= 1.383567 

= < 0.014166 

= < 0.007083 

= 0.853704 

= 2.552469 

Metals emission rate ( x10~ lcfi/hr): 

= < 0.012637 

= 0.627582 

= < 0.006426 

= < 0.003213 

= 0.387237 

= 1.157792 

x 10""1bldscf Antimony (Sb) 

x 1o·• lbldscf Arsenic (As) 

x 10""1bldscf Beryllium (Be) 

x 10""" lbldscf Cadmium (Cd) 

x 1o·• lbldscf Chromium (Cr) 

x 10-"lb/dscf L~d (Pb) 

= 

= 

= 

= 

Em=C\xQ,.0 

x1 O""lblhr Antimony (Sb) = x10""Ib/hr Arsenic (As) = 

x10""1blhr Beryllium (Be) = x1 O"'lb/hr Cadmium (Cd) = x1 O""lb/hr Chromium (Cr) = x1 O""lb/hr Lead (Pb) 

Em,kg/hr X 

1kg 

2.20461b 

x10"" kg/hr Antimony (Sb) = x10"" kg/hr Arsenic (As) = x104 kg/hr Beryllium (Be) = x10 ... kg/hr Cadmium (Cd) 

x104 kg/hr Chromium (Cr) = x104 kg/hr Lead (Pb) 

0.020849 X 1 o·· lbldscf Manganese (Mn) 

0.353135 x 10'"1b/dscf Mercury (Hg) 

< 0.034815 x 1o·• lbldscf Nickel (Ni) 

0.548605 x 10'"1bldscf Selenium (Se) 

0.005557 x 10-"lb/dscf Cobalt (Co) 

0.073523 

1.245315 

< 0.122774 

1.934633 

0.019597 

0.033350 

0.564871 

<0.055690 

0.877544 

0.008889 

x1 0"" lb/hr Manganese (Mn) 

x10""Ib/hr Mercury (Hg) 

x10""1blhr Nickel (Ni) 

x10"'1b/hr Selenium (Se) 

x1 O""lb/hr Cobalt (Co) 

x10"" kg/hr Manganese (Mn) 

x104 kg/hr Mercury (Hg) 

x104 kg/hr Nickel (Ni) 

x104 kg/hr Selenium (Se) 

x10 ... kg/hr Cobalt (Co) 

A-59 ARI Environmental. Inc. Method 29 Multi-Metals Calc Summary 
A-60 

ARI Environmental, Inc. 

Method 29 Multi-Metals Calc Summary 
VIc = 288.1 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

= 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

[Js361-( ~~:s)]l_ 05 MF= = 

p 

T = 502.6 °K 

P = 742.3 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 

0.0799 

1.0000 

0.0799 

A-61 
ABSOLUTE STACK GAS PRESSURE 

p R Pstatic s = bar+-- 13.6 

STACK GAS VELOCITY 

Vs (85.49)(Cp)(avg,J;1P) /(Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

0 5 = 60 X V5 XA5 

Stack Area= 6.7771 ft2 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

( 528 J (Ps) Qstdw = 29.92 (Qs) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd = (528) (Ps) 29.92 (Qs) T

5 

(

1 Bws) 

A-62 

= 29.22 

= 26.300 

= 10,694 

= 6,092.1 

365,525 

= 5,605.4 

336,322 

in.Hg 

ftlsec 

acfm 

scfm, wb 

seth, wb 

dscfm 

dscfh 
Vws~d + Vmstd 

PARTICULATE CONCENTRATION IN STACK GAS ON A DRY BASIS 

Cs = (0.01543{ ~) Filterable = 0.00161 gr/dscf 

vmstd 

C _(Mn)(35.315)x( 13.9 ) 

s,mgldscm@7%0,- (Vmsld) 20.9-%02 = 10.907 mg/dscm @ 7% 0 2 

c~ (2.205x1o-6 { ~} C's Filterable = 0.23027 x 10-ti lbs/dscf 

Vmstd 

EMISSION RATE 

pmr )as~d)(6o) = 0.07742 lbs/hr 

0.03512 kg/hr 

ER = pmftb/hr x 20001b 

lb/tono!Product PRib/hr 1ton = 0.08843 lb/ton of product 

ERkg/MgofProduet pmrlbthr 1000kg = 0.04422 kg/Mg of product (PRkglhr) ( 2.20461b I kg) 

X 

1Mg 

ISOKINETIC SAMPLING RATE 

%ISO 

(100)(T5 {(0.002669 x VIc)+(~: }r {Pbar +( ~) )] 

(60)(9 )(V5 )(P5 )(An) = 101.50 %1 

An= 0.0007752 ft<: Runtime= 240 minutes 

A-63 
FHSample FH Blank BHSample BH Blank Total Metal 

(M111} (Mn,b) (Mbh} (Mbhb} (MJ 

Metal (micrograms) (micrograms) (micrograms! (microsrams} (micrograms} 

Antimony 2.650 2.050 4.650 0.129 5.121 ADL 

Arsenic 12.900 1.000 22.900 0.200 34.600 ADL 

Beryllium 0.200 0.200 0.100 0.100 0.300 BDL 

Cadmium 1.110 0.330 0.064 0.593 0.251 ADL 

Chromium 30.700 3.880 1.960 0.541 28.259 ADL 

Lead 46.600 1.360 0.753 0.234 45.759 ADL 

Manganese 4.010 2.530 0.696 0.763 1.413 ADL 

Nickel 5.920 2.290 1.270 1.000 3.900 ADL 

Selenium 8.800 2.000 33.400 1.000 39.200 ADL 

Cobalt 0.496 0.200 0.384 0.100 0.580 ADL 

Mt = (Mfh - Mfho) + (Moh - Mohb) 

A-64 
1" 

0> 

01 

------

----

-----

-----

---

ir'll'-1 

---

.... ENVJRON!tiENTAL ....- INC, 

Client: 

Location: 

Source: 

Date: 

Run#: 

Kohler Company 

Kohler, Wisconsin 

Tunnel Kiln #19 - 

8/4/2010 

TK19-M29-3 

Det

L

Metal Fraction (micro

Mercury 1B (Hglll) 0.

2B (Hgbh2) 0.

3A (Hgbh3A) 0.

3B (Hgbh3e) 0.

3C (Hgbh3c) 0.

Hgt 
Metals concentration ( x10 .. lbldsc:t): 

= 0.072288 

= 0.488414 

= < 0.004235 

= < 0.003547 

= 0.398905 

= 0.645935 

Metals emission rate ( x10 .. lblhr): 

= 0.243121 

= 1.642645 

= < 0.014243 

= < 0.011931 

1.341604 

= 2.172422 

Metals emission rate ( xfO .. kg/hr}: 

0.110279 

= 0.745099 

= < 0.006460 

= < 0.005412 

= 0.608548 

= 0.985404 

A-66 

ARI Environmental, Inc. 

(

2.2046x10-9

lb xM,) 

C's = j.LQ 

vmstd 

x 1o·• lb/dscf Antimony (Sb) = 

x 1o·• lb/dscf Arsenic (As) 

x 1o·• lb/dscf Beryllium (Be) 

x 10""1b/dscf Cadmium (Cd) = x 10""1b/dscf Chromium (Cr) = x 1o·• lb/dscf Lead (Pb) 

x1 O""lb/hr Antimony (Sb) 

x1 O"'lblhr Arsenic (As) 

x10"'Iblhr Beryllium (Be) 

x10"'1blhr Cadmium (Cd) 

x10"'1b/hr Chromium (Cr) 

x10"'1blhr Lead (Pb) 

x10"' kglhr Antimony (Sb) 

x10"' kg/hr Arsenic (As) 

x10"' kg/hr Beryllium (Be) 

x10"' kglhr Cadmium (Cd) 

x1 0 ... kg/hr Chromium (Cr) 

x10 ... kglhr Lead (Pb) 

= 

= 

= 

= 

= 

E X 1kg 

m 2.20461b 

= 

= 

= 

= 

= 

Method 29 Multi-Metals Calc Summary 

0.019946 

0.368791 

0.055052 

0.553348 

0.008187 

0.067083 

1.240325 

0.185154 

1.861031 

0.027536 

0.030428 

0.562608 

0.083985 

0.844158 

0.012490 

x 1o·• lbldscf Manganese (Mn) 

x 10""1bldscf Mercury (Hg) 

x 1o·• lb/dscf Nickel (Ni) 

x 1 0"" lb/dscf Selenium (Se) 

X 1 o·• lbldscf Cobalt (Co) 

x1 O""lblhr Manganese (Mn) 

x10"'Ib/hr Mercury (Hg) 

x10"'1b/hr Nickel (Ni) 

x1 O""lb/hr Selenium (Se) 

x10""1b/hr Cobalt (Co) 

x10 ... kglhr Manganese (Mn) 

x10 ... kglhr Mercury (Hg) 

x10 ... kg/hr Nickel (Ni) 

x10 ... kglhr Selenium (Se) 

x10 ... kg/hr Cobalt (Co) 
A-67 

ARI Environmental, Inc. Method 29 Multi-Metals Calc Summary 
Concentration 

ng/dscm 

2,3,7,8-TCDD < 0.00059 < 0.00117 < 0.00066 < 0.00081 

Total TCDD < 0.00059 < 0.00061 < 0.00066 < 0.00062 

1,2,3,7,8 PeCDD < 0.00074 < 0.00139 0.00173 < 0.00129 

Total PeCDD 0.00208 0.00407 0.00683 0.00433 

1 ,2,3,4, 7,8 HxCDD < 0.00083 < 0.00046 0.00165 < 0.00098 

1 ,2,3,6,7,8 HxCDD < 0.00218 < 0.00205 < 0.00168 < 0.00197 

1 ,2,3, 7 ,8,9 HxCDD < 0.00237 < 0.00236 0.00427 < 0.00300 

Total HxCDD < 0.00059 0.00577 0.01283 < 0.00640 

1,2,3,4,6,7,8 HpCDD 0.03296 0.01873 0.04552 0.03241 

Total HpCDD 0.06142 0.03459 0.08346 0.05982 

1,2,3,4,6,5,7,8 OCDD (Total) 0.32015 0.17321 0.51448 0.33595 

2,3,7,8-TCDF < 0.00026 < 0.00027 < 0.00038 < 0.00030 

Total TCDF < 0.00026 < 0.00027 < 0.00038 < 0.00030 

1,2,3,7,8 PeCDF < 0.00028 < 0.00039 < 0.00047 < 0.00038 

2,3,4,7,8 PeCDF < 0.00026 < 0.00037 < 0.00047 < 0.00037 

Total PeCDF < 0.00028 < 0.00039 < 0.00047 < 0.00038 

1,2,3,4,7,8 HxCDF < 0.00020 < 0.00015 0.00040 < 0.00025 

1,2,3,6, 7,8 HxCDF < 0.00019 < 0.00013 < 0.00020 < 0.00018 

1 ,2,3,7,8,9 HxCDF < 0.00031 < 0.00014 < 0.00022 < 0.00022 

2,3,4,6,7,8 HxCDF < 0.00022 < 0.00016 < 0.00024 < 0.00021 

Total HxCDF < 0.00022 < 0.00016 0.00040 < 0.00026 

1 ,2,3,4,6,7,8 HpCDF < 0.00052 < 0.00041 < 0.00026 < 0.00040 

1 ,2,3,4,7,8,9 HpCDF < 0.00022 < 0.00021 < 0.00026 < 0.00023 

Total HpCDF < 0.00022 < 0.00021 < 0.00033 < 0.00025 

1 ,2,3,4,6,5,7,8 OCDF ~Total~ < 0.00031 < 0.00032 < 0.00052 < 0.00038 

TOTAL < 0.38613 < 0.21960 < 0.62036 < 0.40870 

A-68 
VIc= 271.6 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

Bws = vwsld = 0.0791 

V wsld + V msld 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION l [8361 

( 

18

935 )J] 10 T 27.65 0.5 

MF = 0.5014 

p 

T= 354.7 OK 

P= 741.3 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0791 

A-69 
ABSOLUTE STACK GAS PRESSURE 

p =R + Pstatic s bar 13.

6 = 29.18 

STACK GAS VELOCITY 

vs (85.49)(cp)(avgFP) I (Ps;Ms) = 18.204 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Q5 = 60 X V5 xA5 = 3,360.33 

Stack Area= 3.0765 te 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Qstdw (~}as{Ps) = 2,708.28 29.92 T5 162,496.9 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd (~)as{Ps }1 Bws) = 2,494.13 29.92 T5 149,648.1 

A-70 

in.Hg 

ftlsec 

acfm 

scfm,wb 

scfh, wb 

dscfm 

dscfh 
(60)(0)(V5 )(P5 )( An) 

 

0.00077519 ft' Runtime (9) = 240 minutes 

A-71 
)> 

I 

--...! 

N COMPANY: Kohler Company 

Kohler, Wisconsin 

Ware Dryer #1 

81512010 

WD1-M23-1 

07:35- 11:37 

LOCATION: 

SOURCE: 

TEST DATE: 

TEST RUN NO. : 

TEST TIME: 

SAMPLE VOLUME : 

SAMPLE VOLUME : 

GAS FLOW RATE: 

OXYGEN CONTENT : 

DIOXIN I FURAN 

COMPOUND 

2,3,7,8-TCDD 

Total TCDD 

1,2,3,7,8 PeCDD 

TotatPacDD 

1,2,3,4,7,8 HxCDD 

1,2,3,6,7,8 HxCDD 

1,2,3,7,8,9 HxCDD 

Total HxCDD 

1,2,3,4,6,7,8 HpCDD 

TotaiHpCDD 

1,2,3,4,6,5,7,8 OCDD 

2,3,7,8-TCDF 

Total TCDF 

1,2,3,7,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1,2,3,4,7,8 HxCDF 

1,2,3,6,7,8 HxCDF 

1,2,3,7,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1,2,3,4,6,7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

Total HpCDF 

1,2,3,4,6,5,7,8 OCDF 

TOTAL 

148.896 d

4.217 d

149,648 d

20.70 % 

TOTAL 

SAMPLE 

MASS 

(nanogram) 

< 0.00250 

< 0.00250 

< 0.00310 

0.00878 

< 0.00350 

< 0.00920 

< 0.01000 

< 0.00250 

0.13900 

0.25900 

1.35000 

< 0.00110 

< 0.00110 

< 0.00120 

< 0.00110 

< 0.00120 

< 0.00086 

< 0.00079 

< 0.00130 

< 0.00094 

< 0.00094 

< 0.00220 

< 0.00091 

< 0.00091 

< 0.00130 

1.62823 eic~rams to nanograms 

M M, 1ng '·"!! = '"'X 1000pg 
VIc= 236.0 mL 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

0.0712 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION [J8361

-( ~~~J]l o.s 

MF = p 

0.5027 

T = 354.7 °K 

P = 741.1 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 0.0712 

A-73 
ABSOLUTE STACK GAS PRESSURE 

Ps P static 

Pbar + 13.6 

STACK GAS VELOCITY 

V5 = (85.49)(CP)(avg/AP) (Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Qs 60 X Vs xAs 

Stack Area= 3.0765 tf 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

(528) (Ps) Qsldw = 29.92 (Qs) Ts 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

Qstd (~}as{Ps }1 29.92 Ts Bvvs) 

A-74 

= 29.18 

= 17.695 

= 3,266.38 

= 2,631.49 

157,889.2 

= 2,444.16 

146,649.6 

in.Hg 

ft/sec 

acfm 

scfm,wb 

scfh, wb 

dscfm 

dscfh 
0.00077519 ft~ Runtime (e) = 60 minutes 

A-75 
)> 

I 

"-...! 

0) COMPANY: Kohler Company 

Kohler, Wisconsin 

Ware Dryer #1 

8/5/2010 

WD1-M23-2 

12:17-16:20 

LOCATION: 

SOURCE: 

TEST DATE: 

TEST RUN NO. : 

TEST TIME: 

SAMPLE VOLUME : 

SAMPLE VOLUME : 

GAS FLOW RATE : 

OXYGEN CONTENT : 

DIOXIN I FURAN 

COMPOUND 

2,3,7,8-TCDD 

TotaiTCDD 

1,2,3,7,8 PeCDD 

Total PeCDD 

1,2,3,4,7,8 HxCDD 

1,2,3,6,7,8 HxCDD 

1 ,2,3,7,8,9 HxCDD 

Total HxCDD 

1,2,3,4,6,7,8 HpCDD 

TotaiHpCDD 

1,2,3,4,6,5,7,8 OCDD 

2,3,7,8-TCDF 

Total TCDF 

1 ,2,3,7,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1,2,3,4,7,8 HxCDF 

1,2,3,6,7,8 HxCDF 

1,2,3,7,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1,2,3,4,6,7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

Total HpCDF 

1,2 3,4,6,5,7,8 OCDF 

TOTAL 

144.938 d

4.105 d

146,650 d

20.80 % 

TOTAL 

SAMPLE 

MASS 

(nanogram) 

< 0.00480 

< 0.00250 

< 0.00570 

0.01670 

< 0.00190 

<0.00840 

< 0.00970 

0.02370 

0.07690 

0.14200 

0.71100 

< 0.00110 

< 0.00110 

< 0.00160 

< 0.00150 

< 0.00160 

< 0.00060 

< 0.00055 

< 0.00068 

< 0.00065 

< 0.00065 

< 0.00170 

< 0.00086 

< 0.00086 

<0.00130 

0.90141 ~icograms to nanograms 

M,. =M X~ ·"" "·"' 1000 pg 
V,c = 250.3 ml 

FRACTIONAL MOISTURE CONTENT OF STACK GAS AS MEASURED 

FRACTIONAL MOISTURE CONTENT OF STACK GAS@ SATURATION 

[J8361-( 18~~)lJ 0.5 

MF= = p 

T = 354.0 OK 

P = 743.9 mmHg 

FRACTIONAL MOISTURE CONTENT USED IN CALCULATIONS 

Bws = 

0.0733 

0.4862 

0.0733 

A-77 
ABSOLUTE STACK GAS PRESSURE 

p p Pstatic s= bar+-- 13.6 

STACK GAS VELOCITY 

V5 =(85.49)(Cp)(avg.JAP) /(Ps~~s) 

STACK GAS VOLUMETRIC FLOW RATE, actual 

Qs = 60 X Vs xAs 

Stack Area= 3.07651f 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, wet basis 

Qstdw (~)as{Ps) 29.92 T5 

STACK GAS VOLUMETRIC FLOW RATE, 

standard conditions, dry basis 

( 528 ) (Ps) Qstd = 29.92 (Os) Ts (1 Bws) 

A-78 

= 29.29 

= 18.088 

= 3,338.83 

= 2,705.56 

162,333.8 

= 2,507.22 

150,433.3 

in.Hg 

ftlsec 

acfm 

scfm, wb 

scfh, wb 

dscfm 

dscfh 
0.00077519 ft~ 

 98.23% I 

Runtime (e) = 60 minutes 

A-79 
)> 

I 

00 

O COMPANY: Kohler Company 

Kohler, Wisconsin 

Ware Dryer #1 

8/6/2010 

WD1-M23-3 

07:30- 11:12 

LOCATION: 

SOURCE: 

TEST DATE: 

TEST RUN NO. : 

TEST TIME: 

SAMPLE VOLUME : 

SAMPLE VOLUME : 

GAS FLOW RATE: 

OXYGEN CONTENT : 

DIOXIN I FURAN 

COMPOUND 

2.3,7,8-TCDD 

TotaiTCDD 

1,2,3,7,8 PeCDD 

Total PoCDD 

1,2,3,4,7,8 HxCDD 

1,2,3,6,7,8 HxCDD 

1,2,3,7,8,9 HxCDD 

TotaiHxCDD 

1,2,3,4,6,7,8 HpCDD 

TotaiHpCDD 

1,2,3,4,6,5,7 ,8 OCDD 

2,3,7,8-TCDF 

TotaiTCDF 

1,2,3,7,8 PeCDF 

2,3,4,7,8 PeCDF 

Total PeCDF 

1,2,3,4,7,8 HxCDF 

1,2,3,6,7,8 HxCDF 

1,2,3,7,8,9 HxCDF 

2,3,4,6,7,8 HxCDF 

Total HxCDF 

1 ,2,3,4,6, 7,8 HpCDF 

1,2,3,4,7,8,9 HpCDF 

TotaiHpCDF 

1 ,2,3,4,6,5,7,8 OCDF 

TOTAL 

148.931 d

4.218 d

150.433 d

20.80 % 

TOTAl 

SAMPLE 

MASS 

(nanogram) 

< 0.00280 

< 0.00280 

0.00731 

0.02880 

0.00695 

< 0.00710 

0.01800 

0.05410 

0.19200 

0.35200 

2.17000 

< 0.00160 

< 0.00160 

< 0.00200 

< 0.00200 

< 0.00200 

0.00168 

< 0.00086 

< 0.00091 

< 0.00100 

0.00168 

<0.00110 

< 0.00110 

< 0.00140 

< 0.00220 

2.61658 

!!icograms to nanQgrams 

M, 

,,. 

=M ~.. x~ 1000pg 
899-02 
~~--- ..:;-;:'5""".5 = ---

1- _ 15'"5 .... INC. 

Facility }( 17 ~ ltr \J 

Date 't 

- 9 - I 0 

Sampling Location ff~Y ~~ 

Inside of Far Wall to 

Outside of Port (Distance C) 

Inside of Near Wall to 

Outside of Port (Distance D) 

Stack 

ID (Distance C- Distance D) 

Port 

Port Distance 

Distance 

Upstream 

Downstream From Distur

Equivalent 

From Disturba

Diameters Downstream From 

Equivalent Diameters Upstream From D

Number of Ports Used L Tr

2 3 

Port Fractional Stack Pr

Traverse %of· LD. Co

Point Stack I.D. 

Number (frac. %) (inches) (

1 

o.o~ -'i,._ 0-

2 A· Oil- J~ ~ .

3 0 , ( (j' <"'? ') 3. 

4 ()I ?? ~"J s. 

5 (j. 'vi.S ')?_ 

~.o

6 f2· )5G "'~ lf.~

7 O.b''-1"1 ')'d., 'J..O•b

8 (') '15 ''J~ ':{'-1.0

9 0 ·ch~~ )d- U· -

10 0 I tt['J, Ja 'J.f.

11 __{}, C1 f) 3'~ ~"f. <

12 () , v ilf?\ l):;t '3J.

For Stacks I Ducts s 24 inches ID - No trave

from stack w~ll 

For Stacks I Ducts > 24 inches ID- No traver

from stack wall 

QAfQC Check: 

Completeness __ 
{) IO IIJ /

} 

I ' . 1>·1'1 911. 1 

r'tl fl. Lt ~b /L) 

f) 1 O·Ov) I ·{J .J 

't 0-IJ1 llJ 5 ~ O·tN{ ltJ/J 5 ~ 0· pvC, r>(1 & 

I fJ",tbf ~[J b 

' 0 rl>'{.; rb vz 

1 u~"'~) t h 

4 1-'5 fl 'l. 

" /.I) ~l ·!_..; 

lv /rC.U 3 

,, /.0, ~ L/ 

/IV /'.) ~ ~t s 

.... 

AVERAGE AVERAGE 

B-2 
------

----

-----

-----

---

iii'1i iF£= 

-----

PLANT fe-r AMB!EN

DATE cg -$- I Q BAROM

LOCATION i! f ASSUME

OPERA TOR PROBE L

STACK NO. - '-t.\ NOZZLE 

RUN NO. - "" STACK D

SAMPLE BOX NO . A\' e l( MINUTE

METER BOX NO. NUMBER 

START TIME CL!ll5. NUMBER 

CLOCK 

TIME 

TRA VERSEJ SAMPLING 

POINT I TIME 

(Hn) NUMBER (e) min. 

0 ') 15 l,.v I 0 

z 

0 "1 ').0 s 

Vf 7( 

o '7lS ) iv 

1 h·Y' 

0 

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l'l, 

'GJG co 

AVERAGE 

STA

PRESS

(in,H

...-o:I

VOLUME OR WEIGHT OF UQUID I 

COLLECTED I VOL

FINAL 

[&QUID COLLECTED 

#I 

'TOTAL UQUID COLLECTED (sll""ify ml or g) 

trl 
OJ 

.f.. 

-

......, __ 

--

-

-

_ _.._.-... 

-

-

ENVIRONMENTAL....- /NO. 

Company: 

location: 

Source: 

Run No.: 

lmpinger No. 

I 

2. 

) 

t.f 

Net Gain 
---

----

-----

-----

--- 

---

____ 

... 

-

·==~= 

.... ~AL~INC. PLANT l{o~ /e. i AMBIEN

DATE ~ • '-IO BAROM

we"'"" 1'5 v• "'""

OPERATOR PROBE 

STACK NO. Q- ~ $BE' NOZZLE 

RUN NO, frJG--(111 - STACK 

SAMPLE BOX NO. ' APE)(' MINUTE

METER BOX NO, 

START TIME 

6"o !.II'Jj NUMBE

OE'JO NUMBE

CLOCK 

TIME 

TRAVERS, SAMPLING 

POINT TIME 

STA

PRESS

(Bn) I NUMBER 

l(J7J lrJ I 

'l 

<D1) '3 

!pl{b " ) 

c 

<6«5 I ~ f{i__o J ___ q 

u1 ~7'1 f.lop ' co 

lq~n~t 

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I _ l'J- 1'iotl<l~ !LV j 

I I 'l 

q t.fh_ I 1 

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5 

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11 

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(9) min. (in;H

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IS 

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)o 

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ll'o 

45 

5o 

5') 

(;"o 

AVERAGE 

VOLUME OR WEIGHT 0~ UQUID 

COLLECTED 

VOL

Ill 11

FINAL 
ro 

I 

en 

-

____ ------

- .......,_ 

-

-

...._ __ __ __ 

-... 

.._._ .....__ 

-

-

,..ENVIRONMENTAL ..... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

J 

-z.. 

) 

4 

Net Gain 
---

----

-----

-----

---

........... 

---

----- .....-~ .... 1/W). 

PLANT Kohler AMBIEN

DATE <fi~ 5- {O BAROM

LOCA noN Kch 1i 1 W'l ASSUM

OPERATOR [ L PROBE 

STACK NO. a 11i!'i;. NOZZLE 

RUN NO. ${Je - 3 STACK 

SAMPLE BOX NO. A ffX MINUTE

METER BOX NO. 60£.1 I') J' NlJMBE

START TIME 1o:,20 NlJMBE

CWCK TRAVERSE SAMPLING STA

TIME POINT TIME PRES

(Hn) NUMBER (Et) min. {in, H

I o 'Jr) w-1 '0 -/7

1.. 

3 ) 

u 

s lo 

.. 

I {) 

l1J 

~0 

(J 

{{ 'J-) 

I f'L 

J{()bf ( 1111 IJJ 3o 

v 'z. 

2, '3) 

" 

1.{Q 

11 

7 45 

r., 

5'0 

IJ 

/( S) 

jJ"1£ Ill/ 

f:,O 

AVERAGE 

VOLUME OR WEIGRT OF LIQUID 

COLLECTED VOL

#1 #1

FINAL 

~~IAL 

LIQUID COLLECTED 
Ill 

I 

00 

-

-

_. --__ .__._ --

-

-

__ 

---

..... 

-

-------

... .,.ENVIRONMENTAL 

--

.... ..... 

-

/NO. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

2 

3 

lf 

Net Gain 
Carbon dioxide c?.! 

Oxygen 2£1/ '1 

Nitrogen (by difference) 

Run: ~1313--M;-- 3 

Run Clbck Time: 

Analysis Clock Time: 

PARAMETER #1 

Carbon dioxide ~I 

Oxygen 2f}, 7 

Nitrogen (by difference) 

!iTKGSWT.OOC tm 

fl. I 

W7 

#2 

(J.f 

2-4f3 

(2{ 

2.42'7 

#3 

620 

'2.L1r7 

t?t/ 

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Avera~e 

o.f 

zo_ 7 

B-9 
--- =--;=..:;:;5 

tiL'! 

~ate 

FaciRcy lr!r 

~ l ~ 

c$ampling Location j n 1.- 

Inside of Far Wall to • " 

Outside of Port (Distance C) 'tl~, S 

Inside of Near Wall to 

Outside of Port (Distance D) G. J

Stack ID (Distance C- Distance D) ~

Port Distance Downstream From Distur

Port Distance Upstream From Disturba

Equivalent Diameters Downstream From 

Equivalent Diameters Upstream From D

1\l ... nhor of Ports Used _ ~ Tr

2 3 

Port 

Traverse 

Point 

Number 

Fractional 

%of· 

Stack I.D. 

(frac. 

Stack 

I.D. 

Pr

Co

a

(

(inches) 

~ '3>5,5:..~-

2 t:. i l 

3 

rr.~ 

4 11 ,·7 

\9~ 1

l. ·

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5 

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~~ 11

8 l(.n 17 lfb. 

10 

9 

o'b,j_ &J.13 l Lt:t

·~1 t

11 

Q1~1 5I,%

12 q7,, 

~'1.!

For Stacks I Ducts::;; 24 inches ID- No traver

from stack wall 

For Stacks I Ducts > 24 inches ID- No traver

from stack wall 

QAIQC Check: 

Completeness Legibility 

Wle\ncd ~ Ca\cu\a\or Signa\urelmfte Cl~A.

Field Supervisor Signature/Date t::£ ~ 

t 

~+I)(.\<... CA i
-----

----

-----

-----

---

---

-

____ __ 

... 

,_,_ 

-

-----

. 

PLANT 

DATE LOCATION 

OPJ;RATOR 

S'I'ACK NO. 

RUN NO. 

• •- . ,, ,. AMBIEN

LJ-L -· __ BARO

...p...,..,.;-::,:;=---.<-='-'---ASSUME

PROBE L

D

METER BOX NO. 

.START TIME 

_...,..""""'""-'-_NUMBER 

-1-C!f---NUMBER 

CLOCK ITRAVERS,SAMPLING 

TIME POINT TIME 

(Hn) • NUMBER (e) min. 

-z.1 /u I - 

I I · rl .rt:J J 

c;1 J>2 _l ___ 

2! to I 

b. I & 

<> 1 '&.> I 

1 7tiJ 1 

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1 l< /I lt() I 

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111 

111 I ;JtJ I 

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h.l -z. ;6 I 

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AVERAGE 

VOLUME OR WEIG8T LIQUID 

COLLECI'ED 

Ill 112 

c;siNAL 

:rrriAL 

LIQUID COLLECI'ED 

TOTAL LI(LUIJ) COL.l.ECI'ED (spe<:ify ml or g) 
OJ 

I 

..... 

1'-.:1 

- -

-

.....,. ___ _ 

- - _...__ _....._-

"EIIIVIRDIIIMFIIITAL ...... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

I 

2.. 

) 

lf 

( 

Net Gain 
------

----

-----

-----

--- 

;;::::;;; 

---

;; 

___ ,_,__ 

..... 

-

PLAN1' DATE 1..01 () BAROMELOCATION /j ASSUME

OPERATOR 'J PROBE L

STACK NO. NOZZLE 

RUN NO. 7/-z_ J_,. z:; STACK D

SAMPLE BOX NO. . MINUTES 

METER BOX NO. 

START TIME 

NUMBER 

NUMBER 

...... 

CLOCK TRAVERSE! SAMPLING! STAT

TIME 

(Bn).L 

POINT I TIME PRESS

NUMBER I (S) min. (in; H

i v 

'fL:I /U 

JtJ I zp__ 1j_ I Ju 11 I '-t·u 

.., I 51> 

'tfh I__ b!J. 

'vii triO 

.:;: 7_1 qp 

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-' _11 -- Ll!lt? /fl}f/1.151)1 > 121 /Zt() 

Ill 

t!) I J Ct.o 

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VOLUME Olt WEIGHT OF LIQUID I 

COLLECTED 1 

LIQUID COLLECTED 

Ill 

.,tJ._

VOL

#l 

TOTAL LI_QI.Jll)_t::(>I..LECTED (specify ml or g) 
OJ 

I 

..... 

----...-.-

-------

-

-

- __ 

- -

.__ 

.,.,ENVIRONMENTAL ...... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

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'i 

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---

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PLANT h I J r AMBIEN

DATE d . BAROME

LOCATION = 1 £v / ASSUME

OPERATOR ' PROBE L

STACK NO. 1: G NOZZLE 

RUN NO. " J STACK D

SAMPLE BOX NO. . /J:7.?j, MINUTE

::::11&!_ 

METER BOX NO. 

START TIME 

CLOCK 

TIME 

(Bn) 

1-'LJ 

TRAVERS, SAMPLING 

POINT TIME 

NUMBER (6) min. 

)7 0 

"'t- [J 

-rr·v 

(II I 5) 

1 I C.t<J 

(, I 5.> 

TfbJ 

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C,l 'tS 

p 'U 

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1 11-1 Jlv 

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11 

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NUMBER NUMBER 

STAT

PRESS

(in• H

-"'Vrt

AVERAGE VOLUME OR WEIGHT LIQUID 

COLLECTED 

Ill 

t AL mAL QUID COLLECTED 

VOL

112 

TOTAL UOUID COLLECTED (•pec:ify ml or Ill 
OJ 

I 

....... 

(j) 

-

- -

----...--- ~-- --

-

-

- -

__ 

-

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--

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Company: 

Location: 

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lmpinger No. 

I 

2. 

'} 

'-{ 

5 

-

Net Gain 

/

5
Carbon dioxide 2.Z. 2.lj 

Oxygen /6, 2, /b.j 

Nitrogen (by difference) 

. Run: 1fttlf/)tJC-Pt'LJ--) 

Run Obck Time: 

Analysis Clock Time: 

PARAMETER #1 #2 

Carbon dioxide b•S 2.,7 

Oxygen /6~1 lb. z 

Nitrogen (by difference) 

STKGSWT.DOC lftl 

~~ 

~~~3 

#3 

z.s16 2 

2·3 

/6; 2-

Average 

Z.b 

/(,., z. 

B-17 
---

----

-----

-----

---

---

iiii - iiii':. iiii 

-----

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r:pPLANT /4:hl-tr AMBIEN

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OPERATOR * PROBE 

STACK NO. ·f,t;,l&} NOZZLE 

RUN NO. TILJ'l /lrj)..(,A - I STACK 

SAMPLE BOX NO. . :lfl7!?:'i- MINUTE

METER BOX NO. Jt>@) NUMBE

START TIME NUMBE

CLOCK TRAVERSE SAMPLlNG STA

TIMlil POlNT TIME PRESS

(Bn) NlJMBER (@)min. (in' H

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t 

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Ill 

FlNAL 

lNmAL 

LIQUID COLLECTED 

'TOTAL LIOUID COLLECTED fs 

VOL

112 
Ill 

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Company: 

Location: 

Source: 

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lmpinger No. 

I 

l 

1 

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----

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---

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LOCATION i&Jhl-tc \\lk ASSUME

OPERATOR dt PROBEL

STACK NO. 1U-JC, .q, NOZZLE 

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START TIME 1 "'.S NUMBER 

CLOCK TRAVERSE SAMPLING STAT

TIME POINT TIME PRI!SS

(Hrs) NUMBER (@) min. (i"' H

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t. 

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FINAL 

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LIQUID COLLECTED 

TOTAL LIQUID COLLECTED (spedfv ml or g) 
-

---...-- --

.... __ __

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Company: 

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k:ohtel AMBIEN

X, "' -I 0 BAROM

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STACKNO. NOZZLE

RUN NO. L1 -t\Q.6tt -3 STACK D

SAMPLE BOX NO. . MINUTE

............................. ......... 

START TIME 

CLOCK TRAVERSE SAMPLING STAT

TIME POINT TIME PRESS

(Hn) NUMBER (6) min. (in' H

I 50S I () -ovo

1. 

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TOTAL UQUID COLLECTED (specify ml or g) 
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Source: 

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lmpinger No. 

2 lt

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Net Gain 
Carbon dioxide 2-.'-/ 2,3 

Oxygen 16. I /b- <J 

Nitrogen (by difference) 

Run: 1ftttjf}tJc-fiJ1 U;f -3 

Run Obck Time: 

Analysis Clock Time: 

PARAMETER #1 #2 

Carbon dioxide 2.f../ z_, 5' 

Oxygen 15-B /6.0 

Nitrogen (by difference) 

STKGSWT.DOC ltn 

B-24 

2..3 

lb'-l 

#3 

2-<1 

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16-/ 

Average 

z.<f 

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----

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---

---- 

---

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SAMPLE BOX NO. . MrNUI'E

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/3'-J NUMBE

METER BOX NO. 

START TIME 

CLOCK 

TIME 

(lfno.) 

TRAVERSE,SAMPLINGl STA

POINT TIME PRESS

NUMBER (6} min. (In, l

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TOTAL UQUID COLLECTED (specify ml or g) 
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Company: 

Location: 

Source: 

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lmpinger No. 

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/ 

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CLOCK TRAVERSE SAMPLING STA

TIME POINT TIME PRES

(Hrs) NlJMBER (9) min. (in. H

11b'5' I (1 -o.o-

17J '- I 0 

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TOTAL LIQUID COLLECTED (•pecify ml or g) 
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Source: 

Run No.: 

lmpinger No. 

( fiiJ

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----

----

-----

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---

---

=-= ='- = -----

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PLANT j[,\l.-1\-t,r' AMBIEN

DATE g-l.j • j 0 BAROM

LOCATION ft:_q\..,' 4:- wr;,. ASSUME

OPERATOR d'1--' PROBE L

STACK NO ·:ff!,.J'-\ NOZZLE 

RUN NO" ''ffS,}:'\ - t\1\>."! •.3 STACK D

SAMPLE BOX NO" " AJ-J:sl.. MINUTE

METER BOX NO. i(0'3co l NUMBER 

START TIME -7l::tO NUMBER 

CLOCK TRAVERSE SAMPLING STAT

TIME POINT TIME PRESS

(Brs) NUMBER (6) min. (in• H

7"-0 II=- i (\ 

"1A.O I j jO 

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VOLUME OR WEIGHT OF LIQUID I 

-

COLLECTED VOL

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I 

QtJID COLLECTED 

TOTAL LIQtJlD COLLECTED (specify ml or K) 
OJ 

I 

(..V 

0 

-

_, ___ _ 

---....-- --- _,...- _..,_ 

ENVIRONMENTAL 

-

--..- ....... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

1 

'2.. Wl

7 

if 

f J

I? 

Net Gain 
------

----

-----

------

----- 

--

... 

-

·~· Facility ~~~P~ 

Date 'fSiltJ_CY' ----...---,-

Samplinglocati~\= 

~ 

Inside of Far Wall to 

Outside of Port (Distance C) J.:t~S 

Inside of Near Wall to 

Outside of Port (Distance D) 

Stack ID (Distance C. Distance D) 

Port Distance Downstream From Disturb

Port Distance Upstream From Disturban

Equivalent Diameters Downstream From 

Equivalent Diameters Up-stream From D

Number of Ports Used_ .---l.-- Tra

2 3 

Port Fractional Stack Pro

Traverse %of- I.D. Co

Point Stack l.D. a

Number (frac. %) (inches) (i

1 l0J2 ?_'!,:~.s Q. 

2 • /!>)' J..'>.?-S J.. 

3 • I '1 ,_,, ':}_ ').;u 4· 

4 .)d-1 '13·?.5 "),

5 

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6 • '1)06 'J_'):d-5 f'6. 

7 • Cf..[J.,5 'd-.'?·?-5 lo. 

... a I C(b'_51\ ~~.?5 'J,'l_

9 

10 

11 

12 

·-

For Stacks I Ducts::; 24 inches ID- No trave

from stack wall 

For Stacks I Ducts > 24 inches ID - No trave

from stack wall 

QAIQC Check: 

Completeness legibility 

W.e~' Ca\cu\a\or SignatureiDate &

Fi~d Sul'"fVis?r Signatureillate ;f

-:¥ 5-\-~:~..d. 

t.:9l\~~i\ite.~ 
?_ ().o~ !]q"Z,.J i-f 

5 f) .OJ-S !l't'V'I ~ t{ (].OJ. S 2DlY· f !..f 

5 o.o'J.. ~9~.1 s 

(; e.o~ 'l '\6', 4 ~ 

'2 O·ot) ?-qf, 3 J 

'1-. O.o I 1'\Lf·'6 ~ 

.... 

AVERAGE I(), t'!>(k;C\ ..l~l..'S d...Ul AVERAGE 

{} z_ ::: 2-tJ. ~ 7 

~::: ()./&-
1 

~ ()l t 

"' '7 

.... 

AVERAGE 

B-33 
J ,t,T?\ lb. 

3 ~~II lt). 

'1 ,o.u l' I ~ • f) ,q lbo 

(., .. o ~ '1.&'\ 

• {t) t.l 1 

\ ,o\tJ tllo 

.... 

•.. AVERAGE ~~. il~'h l~l ... 'b AVERAGE 

B-34 
Carbon dioxide t20 &7.1 

Oxygen ZC?-0 uJ,5 

Nitrogen (by difference) 

. Run: "TI119!2tlf.-1.h12-'; .. 3 

Run Clock Time: 

Analysis Clock Time: 

PARAMETER #1 #2 

Carbon dioxide OJ t/£1 

Oxygen ?a) 2.£l-) 

Nitrogen (by difference) 

STKGSWT.DOC l!m 

{!2-

V27 

#3 

_(Z I 

v:27 

61.1 

zas 

Avera2e 

at 

20..h 

B-35 
----

--- = ==.=E 

;; i!i'i..! 

·~..-INC. 

' Facility kJk~ ate 

~ VJ 

~ampling Locatio: 

~ 

Inside of Far Wall to 

Outside of Port (Distance C) 

Inside of Near Wall to 

Outside of Port (Distance D) C,, ~ 

Stack ID (Distance C- Distance D) 

Port Distance Downstream From Disturb

Port Distance Upstream From Disturban

Equivalent Diameters Downstream From 

Equivalent Diameters Upstream From D

Number of Ports Used .d..._ Tra

2 3 

Port Fractional Stack Pro

Traverse %of.. I. D. Co

Point Stack 1.0. a

Number (frac. %) (inches) (i

1 -o3-;:{ ctb./5 O·f

2 ·loS t ';).i).']S" 'd_. 

3 t i'1 L.l iJG-?5 s, 

4 

,<);;~'3 26.?5 7f.o

5 , o'>I"J "J_t.? 5 

1~. 

6 • c;s'Q6' '5i·?5 ::l t, s

7 ;ms ~-'15 :l3."1

8 ~ tt(j~ "J-0. ?5 ';;!_<;'I r

9 

10 

11 

12 

For Stacks I Ducts s 24 inches ID- No trave

from stack wall 

For Stacks I Ducts > 24 inches ID - No traver

from stack wall 

QAfQC Check: 

Completeness Legibility 

Wlefuoo ~ Ca\cu\a\or SignatureJDate k= 

Field Supervisor Signature!Oate ~ ~ 

~~\ac..t- LoV\-\-\11\ool, 
~ "~'i ~ r."'.l:\ 

lj \ '\l. 

) \.2~ t; ~--~~ 

I "~t. ~ t)6.. 

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( ,;:? " -::: {J cJ g 

1\.t.-t\ 

'\\\,(\ ' 

1 ' ' n~· ,'t; 

3J ),'; I 

"-t17.1 l.. 

),.ll:, 1 t.J 

!\.* 

··~lC..<\ Xi 

.... 

AVERAGE 

B-37 
7 

B-38 

.... 

AVERAGE 
7 

... 

"l,O} 

·~o) 

• .;r... 

AVERAGE 

B-39 
Carbon dioxide o,:) ().?., 

Oxygen 2£<7 Zt7.) 

Nitrogen (by difference) 

Run: l11/7wee ... 1.4f~1 ,;, 

Run Obck Time: 

Analysis Oock Time: 

PARAMETER #1 #2 

Carbon dioxide (/.(} t20 

Oxygen 2-a) '247 

Nitrogen (by difference) 

STKGSWT.DOC tMS 

B-40 

67./ 

zab 

#3 

~I 

2&1~ 

c22.. 

21J& 

Avera~e 

tlcJ 

2£?-£, 
--- ..=-=.=-== ___ ,.,..__ 

IA~I 

------

Date 

Facility 

~IT.LlfJ 

~~ 

~kc 

Inside 

SamplingLocation):>(' 

of Far Wall yer '

to { c Outside 

of Port (Distance C) ~~~ 2 

Inside of Near Wall to r

Outside of Port (Distance D) I • 1 ~ 

Stack 

ID (Distance C· Distance D) ~

Port 

Port 

Distance 

Distance 

Upstream 

Downstream From Distur

From Disturban

·Equivalent Diameters Downstream From 

Equivalent Diameters Upstream From D

Number of Ports Used 

~ Tr

2 

Port Fractional 

Traverse %of. 

Point Stack I.D. 

(frac. %) 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

3 

Stack Pr

I.D. Co

a

(inches) 

For Stacks I Ducts :::; 24 inches ID - No trave

from stack wall 

For Stacks I Ducts> 24 inches ID No traver

from stack wall 

QAIQC Check: 

Completeness Legibility 

W!e~' Ca\cu\a\or SignatureJDat~ CJ .. -h

Field Supervisor Signatu~JPate · · ~~i
111 .1 

II .) 

lJ s 

I d. 

) 3 

3 J 

l-J I 

5 I 

(, () 

7 } ,-

q., I ~ ~ 

I(J 

II l ' 

IJ. ~ ¥ 

.,., 

,_ AVERAGE AVERAGE 

B-42 
------

----

-----

-----

--- 

:!!'-.! 

---

PLANT lee AMBIEN

DATE 9)/S/11 BAROME

LOCATION \V;( ASSUME

OPERA TOR / 6 PROBE L

STACK NO. NOZZLE 

RUN NO. STACK D

SAMPLE BOX NO. . A 1!"1< MrNUTES 

METER BOX NO 

START TIME 

TIME POINT TIME PRESS

(Hn) I NUMBER I (8) min. I (I"' H

lt.IT----T llf.os 

-I J. I I w I 

.:i:et. 1 _____ \ 

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to 1 11o L _ 

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AVERAGE VOLUME OR WEIGHT OF LIQUID I 

COLLEcrED I VOL

ill 112 

TOTAL LIQUID COLLECTED (specify ml or g) 
OJ 

I 

.j::.. 

.j::.. 

- -

-

.-.----- __ ......__ 

-

---

------

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__ ._._ 

... "ffi""ENVIRONMENTAL 

--

.._.._ ....... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

2 

7 

Lf 

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Net Gain 

J
------

----

-----

-----

---

----

---

-

__ ._._ 

-----

PLANT /{_ obl-er- AMBIENDATE g-).(- / Q BAROME

LOCATION KdJ.t/..or1\II,J;'JI ASSUME

OPERATOR PROBE L

STACK NO. \N{)J- Wb'f NOZZLE 

RUN NO !Nl) I - fV.l."6- C).. STACK D

SAMPLE BOX NO. . MINUTE

METER BOX NO. 

START TIME 

CWCK 

TIME 

TRAVERSE! SAMPLING' STAT

POINT I TIME PRESS

(Hrs) I NUMBER I (9) min. I (in• H

IJ..I-=t- lv.r 1 I 0 .fo.os

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')..;)'o/ I 3 I LO 

I 4 I '36 

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AVERAGE 

VOLUME OR WEIGHT OF LIQUID I 

COLLECfED I VOL

111 I 111. 

EAL I mAL QUID COLLECfED 

TOTAL LIQUID COLLECfED or g) 
OJ 

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C) 

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-

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--------

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-

.... ..... 

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-

_ 

... ..,.-ENVIRONMENTAL 

--

.._.__ .... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

'2 

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Net Gain 
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---

----

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---

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..... WO. 

PLANT k 0 h I::{,C 

DATE R-t;- { 0 

LOCATION k;,Cll,/e,c, \..J1. 

OPERA TOR 

STACK NO. rAJQ I - vy¥2'€.' 

RUN NO. lvhi 

SAMPLE BOX NO 

AMBIEN

BAROME

ASSUME

PROBE L

NOZZLE 

STACK D

MINUTE

METER BOX NO. "f Ol Oo/ NUMBER 

START TIME 730 NUMBE

CLOCK TRAVERSE SAMPLING STAT

TIME POINT TIME PRESS

(Hrs) NUMBER (8) min. (In; H

'130 Ju- I 0 -0.01

1.. lO 

750 "t, -t.c 

4 go 

g(O j" yo 

.(, s-o 

9 ()0 

51"10 .{ IO 

RSO T to 

&ioo !0 "i.O 

vtto ll I vC> 

fiJ..{7 ll .... j,IO 

! IIIJ- j lz-6 

9."1 d.. t. l'?.O 

9-SJ.. }. z!..LO 

i ool.-- '1. lt:O 

/0 ld- ) j(, 0 

10) .. ) . ..- ' 1-10 

Jo""bJ.-- ·-r t 

tOI-i}- t' 

io6d.... 1 -z,vo 

I I"' 'd-.10 

I l I J..... l' ]._, 7..i:J 

IL Z.i3L> 

Z:..'l u 

AVERAGE ).._'if\;! )..,\.jOWl -o.oVOLUME OR WEIGHT OF LIQUID 

COLLECTED VOL

Ill ' Ill 

PAL li::IQutD COLLECTED 

TOTAL LIQUID COLLECTED (spedfy ml or g) 
IJJ 

I 

.,1:::. 

00 

-

-

,...... __ 

---

---..-.- - -

-..-..- _._.-

ENVIRONMENTAL ...... INC. 

Company: 

Location: 

Source: 

Run No.: 

lmpinger No. 

I 

2 

) 

Lf 

) 

Net Gain 
Carbon dioxide rJO 

Oxygen za~ 

Nitrogen (by difference) 

Run: W/J/-..,2)~ 2-

Run Oock Time: 

Analysis Clock Time: 

PARAMETER #1 

Carbon dioxide {},J 

Oxygen 2t28 

Nitrogen (by difference) 

STKGSWT.DOC l!m 

acJ 

217.7 

#2 

ao 

2~5 

tf?, I 

U2& 

#3 

ao 

2127 

t2CJ 

~(I 

Avera~e 

ao 

2t28 

8-49 
~ ;: 1,2,3, three different nozzles diameters, nun (in.); each 

diameter must be within (0.025 nun) 0.001 in. 

b ~D =maximum difference between any two diameters, nun (in.), 

AD ~(0.10 nun) 0.004 in. 

c 

Quality Assurance Handbook MS-2.6 

8-50 
899-02 
All criteria as specified in USEPA Methods 26A and USEPA Method 5 were 

met 

4) Discussion 

These are final results for your review. Any questions can be directed to Eric 

Vogt atARI at (847) 487-1580 x116. 

Respectfully submitted, 

~!Y~ 

Eric Vogt 

Lab Manager 

ARI Environmental, Inc. 

Wauconda, IL 

Texas NELAP 10: T104704428-08A-TX C-1 
C-2 

Sample ID: 

Lab Sample #: 

Analyte 

Particulate 

Sample ID: 

Lab Sample #: 

Analyte 

Particulate 

Run TK19-M29-3 Filter 

0810003 

Result 

15.00 

Field Blank Filter 

0810004 

Result 

0.55 

Units Method 

mg USEPA Method 5 

Units Method 

mg USEPA Method 5 

Date Sampled: 08/04/2010 

Sampled By: JB 

Sample Matrix: Filter 

Analyst Analysis 

Date 

Eric Vogt 08/21/2010 

Date Sampled: 08/04/2010 

Sampled By: JB 

Sample Matrix: Filter 

Analyst Analysis 

Date 

Eric Vogt 08/21/2010 

Page 1 of 5 
Sample 10: 

Lab Sample#: 

Analyte 

Particulate 

SampleiD: 

Lab Sample #: 

Analyte 

Particulate 

Run TK19-M29-3 Probe Wash 

0810007 

Result Units 

1.31 mg 

Field Blank Acetone 

0810008 

Result Units 

1.00 mg 

Method 

US EPA Method 5 

Method 

USEPA Method 5 

Date Sampled: 08/04/2010 

Sampled By: JB 

Sample Matrix: Probe Wash 

Analyst 

Eric Vogt 08/21/2010 

Date Sampled: 08/0412010 

Sampled By: JB 

Sample Matrix: Probe Wash 

Analyst Analysis 

Date 

Eric Vogt 08/21/2010 

Page 2 of 5 

C-3 
C-4 

ydouoc cd 

Sample 10: 

Lab Sample #: 

Analyte 

Hydrochloric Acid 

Hydrofluoric Acid 

Sample ID: 

Lab Sample #: 

Analyte 

Hydrochloric Acid 

g 

Run TK19-M29-3 0.1 N H2S04 

0810011 

Result Units 

924.3 ug 

15364.4 ug 

0.1 N H2S04 Blank 

0810012 

Result Units 

<110.8 ug 

Method 

Method 26 HF & HCI 

Method 26- HF & HCI 

Method 

Method 26- HF & HCI 

g

Date Sampled: 08/041201 o 

Sampled By: JB 

Sample Matrix: Imp Contents 

Analyst 

EricVogt 

Eric Vogt 

Date Sampled: 08/04/2010 

Sampled By: JB 

08/2112010 

08/21/2010 

Sample Matrix: Imp Contents 

Analyst 

Eric Vogt 

Analysis 

Date 

08/21/2010 

Page 3 of 5 
Particulate 

SampleiD: 

Lab Sample #: 

Analyte 

Particulate 

SampleiD: 

Lab Sample #: 

Analyte 

Particulate 

7.40 

Run SBE-MS-2 Filter 

0810015 

Result 

8.45 

Run SBE-MS-3 Filter 

0810016 

Result 

7.50 

mg 

Units 

mg 

Units 

mg 

USEPA Method 5 

Method 

USEPA Method 5 

Method 

USEPA Method 5 

Eric Vogt 

Date Sampled: 08/0512010 

Sampled By: JB 

Sample Matrix: Filter 

Analyst 

Eric Vogt 

Date Sampled: 08/05/2010 

Sampled By: JB 

Sample Matrix: Filter 

Analyst 

Eric Vogt 

Page 4 

08/21/2010 

08/21/2010 

Analysis 

Date 

08/21/2010 

of 5 

C-5 
C-6 

SampleiD: 

Lab Sample #: 

Analyte 

Particulate 

Sample ID: 

Lab Sample#: 

Analyte 

Particulate 

Run SBEM53 Probe Wash 

0810019 

Result 

3.50 

Acetone Blank 

0810020 

Result 

-0.05 

Units Method 

mg USEPA Method 5 

Units Method 

mg USEPA Method 5 

p

Sampled By: JB 

Sample Matrix: Probe Wash 

Analyst Analysis 

Date 

Eric Vogt 08121/2010 

Date Sampled: 08/0512010 

Sampled By: JB 

Sample Matrix: Probe Wash 

Analyst Date 

Eric Vogt 08/2112010 

Page 5 of 5 
I 

Kohler, Kohler, WI; TK-

Chloride Determination 

Std. 

(!!g/ml) 

0.0 

1.0 

2.0 

5.0 

10.0 

ID 

TK 19-M26A-1 

TK19-M26A-2 

TK19-M26A-3 

0.1 N H2S04 Blank 

Reagent Dl Water Blank 

Lab Dl Water Blank 

C1l 4.0 

"C "§ 2.0 

.. 

Pre C

(J.LS*m

0.00 

0.15

0.28

0.67

1.38

Sample 

Analys

(area co

0.25

0.21

0.23

<0.03

<0.03

<0.03

... 

Ch

fi 

0.0~~--------~-

0.0 0.2 0.4 

() 

I 

--..1 
Kohler, WI; TK-

Fluoride Determination 

Std. Pre C

(flg/ml) (JJ.S*mi

0.0 0.00 

1.0 0.183 

2.0 0.358 

5.0 0.909 

10.0 1.898 

Sample C

ID Analysi

(area cou

TK19-M26A-1 1.112 

TK19-M26A-2 1.134 

TK 19-M26A-3 1.105 

0.1 N H2S04 Blank <0.00

Reagent Dl Water Blank <0.00

Lab Dl Water Blank <0.00

-·· --··-----· 

Flu

E 12.0 I 

-

10.0 

-

c.j 8.0 

c 

0 

0 6.0 

(1) 4.0 . 

"0 

"£: 2.0 0 

:::s 0.0 ii: 

0.0 0.5 
2.5-:j 

' 1.3 

3 - Chloride - 5.900 

_0 .5-t--.---.--.,..--...,-.---.--..-.-.--r--;--r---.,----.---.----,---.-,--.--.--r--.--.--,-....--.--.-,-.--,--;m:..:.:.i_,n 

0.00 1.00 2.00 3.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

3 5.90 Chloride 

4 9.40 Nitrate 

Total: 

ChlorideArea/lntegration 

4.00 

Height 

uS 

30.799 

1.129 

3.525 

35.453 

5.00 

Area 

uS* min 

5.8413 

0.2572 

1.0230 

7.121 

6.00 7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-9 
C-10 

3 • Chloride • 5.904 

_0_5,-+--.--.-....-.--.--.-..-,..--.---,r--o--,.---r----r-.---.--.----.--.--,--.-,---.-.--.--..,--.--.-.--,r--'rm=i'-'Jn 

0.00 1.00 2.00 3.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

3 5.90 Chloride 

4 9.40 Nitrate 

Total: 

ChlorideArea/lntegration 

4.00 

Height 

IJS 

31.189 

1.135 

3.549 

35.872 

5.00 

Area 

uS* min 

5.9007 

0.2549 

1.0299 

7.185 

6.00 7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2.5 

1.3 

; 2-4.774 3- Chloride- 5.907 

-0.5-t--.--.--.-..,--.--,----,--r--,---,-----r---r--r--r---r-,-r--..---r--,---.--.--.----,--.--.-,--,--,----,,.----;~ 

0.00 1.00 2.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

3 5.91 Chloride 

4 9.43 Nitrate 

Total: 

ChlorideArea/lntegration 

3.00 4.00 

Height 

llS 

31.064 

0.950 

0.220 

32.235 

5.00 

Area 

llS*min 

5.8864 

0.2133 

0.0607 

6.160 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-11 
C-12 

2. 

~ 1. 3-l 

,. 

~ I -0. 

0.00 1.00 2.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

3 5.91 Chloride 

4 9.44 Nitrate 

Total: 

ChlorideArea/lntegration 

3.00 

I 

4.00 

Height 

us 

31.715 

0.944 

0.227 

32.886 

\ 

. 2·4.777 

5.00 

Area 

uS* min 

6.0071 

0.2132 

0.0658 

6.286 

.l 

3 - Chloride • 5.91 0 

·~~~· 

6.00 

min 

7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2.5~ 

1.3 

_0_5-l--.--.,---.--..,.--.....--..-..---,.-.----.,.----,-.----.---.---r-.---,----r--,--.--.--,-....,--..--.---.--,--,--,.....-,r--',m=i:..:;n 

0.00 1.00 2.00 3.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

3 5.91 Chloride 

4 9.43 Nitrate 

Total: 

Ch lorideArea/1 ntegration 

4.00 

Height 

!lS 

30.882 

1.041 

0.219 

32.141 

5.00 

Area 

llS*min 

5.8572 

0.2393 

0.0587 

6.155 

6.00 7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-13 
C-14 

2.~ j 

1.3 ' 

min -0 .!'>-+--.----.---.---,--.--.--.--..,.--..,.--.,---,---,---,---,----,r--;r--;---,---,------,---,------,--.-.....----.--.----r--.--.----,--~ 

0.00 1.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

3 5.91 Chloride 

4 9.44 Nitrate 

Total: 

Ch lorideArea/1 ntegration 

3.00 4.00 

Height 

llS 

30.916 

1.075 

0.212 

32.203 

5.00 

Area 

IJS*min 

5.8581 

0.2611 

0.0593 

6.179 

6.00 7.00 

Chromeleon (c} Dionex 1996-2001 

Version 6.60 Build 1428 
, 

2.5-

1.3-

-0.5 ' 

0.00 

No. 

1 

2 

3 

Total: 

l I 

1.00 2.00 

Ret. Time Peak Name 

min 

4.20 Flouride 

9.44 Nitrate 

15.23 Sulfate 

ChlorideArea/lntegration 

---~-L--·····-- v I I I 

3.00 4.00 5.00 

Height Area 

llS IJS*min 

5.304 1.1116 

0.692 0.1964 

112.031 50.1057 

118.026 51.414 

' I 

6.00 

min l 

7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-15 
C-16 

l 

2.5~ 

1.3~ J l ~ Chloride- 5.917 

-0.5,-f-....,---,--....-,l-..--.--.---r---'lr--<-.\-'-"r-/....-.-.--,--.--,...--,,.--,l---..--,-____,..-,l-,.-..........----,--.-l,....-,,..-:,m=i'-1n 

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 

No. Ret. Time Peak Name 

min 

1 4.20 Flouride 

2 5.92 Chloride 

3 9.43 Nitrate 

4 15.23 Sulfate 

Total: 

ChlorideArea/lntegration 

Height 

us 

5.272 

0.270 

0.687 

111.493 

117.722 

Area 

uS*min 

1.1067 

0.0553 

0.1998 

49.8217 

51.184 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
'i 2.5-

! 1.3-

.~~~~~-.~~~.-~~~\~~.-~~~~~~-.~~~-.-~~~-.~~~-Tm~in 

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

Total: 

ChlorideArea/lntegration 

Height 

us 

5.326 

5.326 

Area 

IJS*min 

1.1341 

1.134 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-17 
C-18 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

Total: 

ChlorideArea/lntegration 

Height 

us 

5.295 

5.295 

Area 

uS*min 

1.1291 

1.129 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2.~ \ 

1.3J 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

Total: 

ChlorideArea/lntegration 

I 

Height 

us 

5.144 

5.144 

Area 

uS* min 

1.1046 

1.105 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-19 
C-20 

2.5-

1.3-

v ~ min I I I -0. ;;;5-+--.---.-r--,-l,..--,,--,-,--.---,--.,-=c--r--r--r--,--.---.---.--.,--.,-.,---.,..-,-r-"'1--,--,--r--r_;;..=j 

0.00 1.00 2.00 3.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

Total: 

ChlorideArea/lntegration 

4.00 

Height 

us 

5.164 

5.164 

5.00 

Area 

uS* min 

1.1191 

1.119 

6.00 7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2.5~ 

1.3-

1 -Chloride - 5.897 

;+---,----.--...,--,---...-.--.--....--.---.--r---.----,--.--,---,...-,--...--.---,---.-....,.----.---,---.-..,-.--..--,---,,----:,m~in 

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 \ 

No. Ret. Time Peak Name 

min 

1 5.90 Chloride 

Total: 

ChlorideArea/lntegration 

Height 

MS 

0.066 

0.066 

Area 

uS* min 

0.0124 

0.012 

·------ ----.------- -- ----- ___________ j 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-21 
C-22 

No. 

Total: 

Ret. Time 

min 

Peak Name 

ChlorideArea/lntegration 

Height Area 

llS llS*min 

0.000 0.000 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2.5--

1.3-

No. Ret. Time Peak Name Height 

min us 

1 5.93 Chloride 0.077 

Total: 0.077 

ChlorideArea/lntegration 

Area 

uS* min 

0.0143 

0.014 

1 - Chloride • 5.927 

7.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-23 
C-24 

:i 

1.3 ' 

l 

No. 

1 

Total: 

Ret. Time Peak Name 

min 

5.92 Chloride 

ChlorideArea/lntegration 

Height 

us 

0.073 

0.073 

Area 

uS* min 

0.0165 

0.017 

1 - Chloride - 5.920 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2~ 

'1 -!~----------~ 1 1 -Chloride· 5.927 

-0.5:r-~t-l --.---.--.--,-1---.,.---,---,-, -.,-! --.-..--)r'---1J,_C--.--.,---,., ---r-1----r' ---,---.--,-1 --,-...,--.,,r--ol-1~,---,---.-, --.-1 ---,-, --,----T-~'--'iinl 0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 

No. Ret. Time Peak Name Height Area 

min llS JJS*min 

1 5.93 Chloride 0.019 0.0031 

Total: 0.019 0.003 

ChlorideArea/lntegration 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-25 
C-26 

 l 

2.5~ I 

1.3-

No. Ret. Time Peak Name Height 

min us 

1 5.91 Chloride 0.037 

Total: 0.037 

ChlorideArea/lntegration 

Area 

uS* min 

0.0072 

0.007 

1 • Chloride - 5.913 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2. 

1.00 2.00 3.00 

No. Ret. Time Peak Name 

min 

1 4.20 Flouride 

2 5.92 Chloride 

Total: 

ChlorideArea/lntegration 

4.00 

Height 

us 

0.804 

0.775 

1.578 

1 - Flouride • 4.203 2 • Chloride - 5.920 

5.00 

Area 

uS* min 

0.1831 

0.1514 

0.334 

6.00 7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-27 
C-28 

No. Ret. Time Peak Name 

min 

1 4.20 Flour ide 

2 5.92 Chloride 

Total: 

ChlorideArea/lntegration 

Height Area 

us uS* min 

1.661 0.3581 

1.448 0.2892 

3.109 0.647 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
1 .5 

2 

.3 i 

~ 

·~ I -0 

0.00 1.00 2.00 

No. Ret. Time Peak Name 

min 

1 4.20 Flouride 

2 5.92 Chloride 

Total: 

ChlorideArea/lntegration 

\/' _L ········--· 

3.00 4.00 5.00 

Height Area 

us uS* min 

4.362 0.9086 

3.405 0.6728 

7.768 1.581 

) 

~ 

6.00 

min I 

7.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-29 
C-30 

2.5-

131 

-0.5 i I I \~ I 

0.00 1.00 2.00 3.00 

No. Ret. Time Peak Name 

min 

1 4.20 Flouride 

2 5.92 Chloride 

Total: 

ChlorideArea/lntegration 

.. L 

I I 

4.00 5.00 

Height Area 

us uS*min 

9.503 1.8982 

7.114 1.3795 

16.617 3.278 

~ I 

6.00 

min I 

7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
2.51 

1.3j 

Klouride - 4.200 3 • Chloride • 5.914 

1-1.304 

-+--,--...--.,--,.--,---,--.---,---,.--..---\r'-i~'--r--,---,.--.--.--,--..--..--.,--,...--,r--r--.---r---r--.--.--.----Tm~in I I I I I I I 

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 

No. Ret. Time Peak Name Height Area 

min J,.l$ J,.lS*min 

2 4.20 Flouride 0.741 0.1660 

3 5.91 Chloride 0.692 0.1372 

Total: 1.432 0.303 

ChlorideArea/lntegration 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-31 
C-32 

2.5~ 

1.~ ~ • "'"'1•• • 

4

-

197 

2 - Ch~rido - 5.910 

--t-----------------..\ 

/ 

______ j_~~------1 min -o.~~~~~-~~~~-.~~~-T~~~~-.~~~,~~~~-,-~~~~~~~~~ 

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 

No. Ret. Time Peak Name 

min 

1 4.20 Flouride 

2 5.91 Chloride 

Total: 

ChlorideArea/lntegration 

Height 

us 

1.570 

1.399 

2.969 

Area 

uS* min 

0.3433 

0.2795 

0.623 

Chromeleon (c} Dionex 1996-2001 

Version 6.60 Build 1428 
1.3-

~ 

----~~<-----===--~)~--~~,---------~ _ 0 .5-+--.-.---.-.,..--.----r-..---,---,c---;---,.\"'---f/'-r---,..-.--.----,----.---,-----,----,---.---.-.-.---,.--.-----,---,----,----;;m-=-=!i n I I I I I I I 

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 

No. Ret. Time Peak Name Height Area 

min us uS* min 

1 4.19 Flouride 4.385 0.9343 

2 5.91 Chloride 3.484 0.6862 

Total: 7.869 1.621 

ChlorideArea/1 ntegration 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-33 
C-34 

\ 

2~ i 

,} 

••"f"""_ ...... ~ 

1.3-

\/ min I I I I I j I -0 .5-+-.---.---r--,--;---;--r---or--;c--r--.>--f---r--r----r--r----,---r--r---.----.-.-..---,--,---,-,--.,--,----,----,~ 

0.00 1.00 2.00 

No. Ret. Time Peak Name 

min 

1 4.19 Flouride 

2 5.91 Chloride 

Total: 

ChlorideArea/lntegration 

3.00 4.00 

Height 

us 

9.512 

7.160 

16.673 

5.00 

Area 

uS* min 

1.9455 

1.4299 

3.375 

6.00 7.00 8.00 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
0 

I 

(J.) 

01 

---

----

.::::-==-=-= = 

---

----- -

.. ...... .,..4JIWIII~AL ----.. INIC. 

951 N. Old Rand Rd, Unit 106 

Wauconda, Illinois 60084 

lABo~~l 

Lab Project No. ·Client Name 

frol11~ 

C

ARI Project Manager 

0PfYI F/T-z- ~~v-~

Analysis Location (Waucondi or Pasade

Vlautdlvtd '1 

Engineering or Compliance Test sample

Sample No. Date Collec

4u~r (1- 3-JO 

1./~t:lJ .'7--3-ftJ 

4"~t77 9-4-/J} 

J?tlJ!f) ~-'/-{0 

L/d1J'-t7 ~rtP 

L/fJOG7 @-J-U7 

f./tl/l61 {J...-t.f-10 

L/tl{J'b ff,c.f-{0 

'{tlt?(,J g# 3--{0 

4:~ B-rtt:J 

ij(jQf) 'Z- g ... t.f-{0 

£{(/P~7 g.-i.{-10 

L/Chb 2.. B-r-t-o 

'IOOb'? g ... J,-tC7 

L/_(}1/(/"j U-'-1-10 

Special Instructions I Com

Requested Analysis Completion Da

Tieri: ~

Report Level: Engineering 

Route Results Through: 
0 

J 

w 

0'> 

----

----

-----

-------

---

---

__ .,. 9..J!f...:I..AL .... ~ 951 N. Old Rand Rd, Unit 106 

Wauconda, Illinois 60084 

LABUSEONLY I 

og-z:u 

Lab Project No. Client Name 

i1ohfev C 

ARI Project Manager 

/)(4V! 

'{:,'-r-z-9~&e

Analysis Location {Wauconda or Pasaden

\1'1 u uc~vtd 14 

Engineering or Compliance Test Samples 

Sample No. Date Collect

I.JtJOS7 g.A.f-10 

L.fC/799 B-£/..-Hl 

lfa:J61 fi-£1-rO 

t/CI!l'fo e..-'1-to 

'/0'1/ 6-l./-tO 

Special Instructions I Comm

Requested Anal~is Completion Date

Tier 1: 

1 

GT

Report Level: Engineering 

Route Results Through: 
() 

I 

(;.) 

......., 

-----

-- --- -

--- =-==-== ---·-- -----..... INC. 

951 N. Old Rand Rd, Unit 1 06 

Wauconda, Illinois 60084 

lABUSEONLY I 

o e-2-u 

Lab Project No. Client Name 

11tJw ltv 

ARI Project Manager 

fl61VI f, 

Analysis Location (Wauoonoa or Pasade

1¥ 

Engineering or Compliance Test Sample

Sample No. Date Collec

LfZl1oZ. g-r;-;o 

,.,.,5.,., 0 

IJ-)-117 

1../1)/0Z.. g-f-u:? 

f.5- -(" 

8- 

.. 5-t" 

l/tli&J) 9..-S-10 

Special Instructions I Com

Requested Analysis Completion Dat

Tier I: 

1

G

Report Level: Engineering 

Route Results Through: 
Custody seal(s) applied and intact w No 

Quantity of samples match number on COC 'YJ!s No 

Container labeiiD numbers and descriptions match COC ~ No 

All containers received in good condition {'(~ No 

Liquid levels marked and no indications of leakage •ffel No 

All container labels are legible ·~ No 

All sample IDs are unique ~ No 

Samples received in correct type of container 1~ No 

Samples received within the required holding time ~ No 

Samples received under the required preservation code (e6 No 

Nonjonformances and/or Corrective Actions Applied: /1 9Cfmpl-e. r-ec-etfOf. Crtf<t>rt9 J/J?-e/ 

Samples Received by: 

Printed Name Signature 

Date and Time Received: _t§-.L.-;6_6+-./:~!_(}) __ 1_:1 __ ,_CO __ 

C-38 
[:,};·;, ~?"'/ 

Certified by:~-:·~_"/.~, ~ IC~"~~-_~~l-:t_···_/);_7 _, :_:

7 

__________ _ 

Steve Kennedy 

Laboratory Manager 

Results in this cert1ficate relate only to the samples as submitted to the laboratory. 

This report shall not be reproduced, except in full, without the written permission of ALS Canada Ltd. 

ALS Canada Ltd L922690 MM 100915 Page 1 ~439 
ALS Canada Ltd L922690 MM 100915 Page 2 of4 

C-40 
Nickel 0.1 < 31.2 104 31.1 103 

Selenium 1 < 30.7 103 30.7 103 

ALS Canada Ltd L922690 MM 100915 Page 3 of4 

C-41 
ALS Canada Ltd L922690 MM 100915 Page 4 of 4 

C-42 
Y.t;>/ . j .,. /-/.-;:: 

Certified by:~_-'_;,./~:~'-·_· .... _"~·~_ .. _'"'_""'_PJ'_~'_" _____________ _ 

Steve Kennedy 

Laboratory Manager 

Results m th1s certificate relate only to the samples as submitted to the laboratory. 

This report shall not be reproduced, except in full, without the written permission of ALS Canada Ltd. 

· AL8 Canada Ltd L922690 Hg 1 00915 Page 1 ~~3 
ALS Canada Ltd L922690 Hg 100915 Page 2 of4 

C-44 
ALS Canada Ltd L922690 Hg 100915 Page 3 of4 

C-45 
ALS Canada Ltd L922690 Hg 100915 Page 4 of4 

C-46 
Certified by: -:::":":_""_}-:·/(:~~-'~·_.~'-[_·::-·~_.,._,A.;;,y_,i_'· ._~~-----------­ Steve Kennedy 

Laboratory Manager 

Results in this certificate relate only to the samples as submitted to the laboratory. 

This report shall not be reproduced, except in full, withou1 the written permission of ALS Canada Ltd. 

The test results herein meet all of the requirements of ISO 17025:2005 and NELAC (2003) standards unless stated otherwise in the comments above. 

JkS Canada Ltd L918881 100901.xls Page 1 ofYf4 7 
13C12-2,3,718-TCDF 92 97 50 45 82 86 82 96 

13C12-1,2,3,7 ,8-PeCDF 91 109 56 57 82 119 83 123 

13C12-1,2 1316,7 ,8-HxCDF 81 106 101 116 84 94 79 88 

13C12-1,2,3,4,6,7,8-HpCDF 97 89 90 78 80 84 eo 83 

Cleanup Standards 

13C12-1,213,7 ,8,9-HxCDF 83 93 90 85 89 92 85 83 

Homologue Group Totals pg pg pg pg pg pg pg pg 

Totai-TCDD <1.3 1880 2070 2650 <2.5 <2.5 <2.8 <1.0 

Totai-PeCDD <0.69 3770 4170 5380 8.78 16.7 28.8 <0.79 

Totai·HxCDD <0.90 8210 7620 7760 <2.5 23.7 54.1 3.34 

Totai-HpCDD <0.59 9120 8550 9180 259 142 352 <1.0 

Total·TCDF <0.80 141 129 250 <1.1 <1.1 <1.6 <0.79 

Total-PeCDF <1.0 82;3 127 86.2 <1.2 <1.6 <2.0 <1.0 

Total-HxCDF <0.56 2.22 14.3 45.9 <0.94 <0.65 1.68 <0.63 

Totai-HpCDF <0.63 <0.91 10.1 13.3 <0.91 <0.86 <1.4 <0.54 

Toxic Equivalency NATO 

Lower Bound PCDD/F TEQ o.oo 528 502 573 2.74 1.48 8.61 0.125 

Upper Bound PCDD/F TEQ 2.77 544 503 577 10.2 12.3 15.5 2.67 

ALS Canada Ltd L918881 100901.xls Page2of11 

C-48 
13C12-1,2,3, 7,8-PeCDD 

13C12·1,2,3,6,7,8-HxCDD 

13C12-1,2,3,4,6,7,8-HpCDD 

13C12-0CDD 

13C12·2,3,7,8-TCDF 

13C12-1,2,3,7,8-PeCDF 

13C12-1,2,3,6, 7,8-HxCDF 

13C12-1,2,3,4,6,7,8-HpCDF 

Cleanup Standard 

13C12-1,2,3, 7 ,8,9-HxCDF 

Homologue Group Totals 

Totai-TCDO 

Totai-PeCDD 

Totai·HxCDD 

Totai-HpCDD 

Totai·TCDF 

Totai-PeCDF 

Totai-HxCDF 

Totai-HpCDF 

Toxic Equivalency NATO 

lower Bound PCDD/F TEQ 

Upper Bound PCDD/F TEQ 

32:33 

34:46 

36:38 

38:30 

26:38 

31:44 

34:17 

36:01 

35:09 

#peaks 

0 

0 

0 

0 

0 

0 

0 

0 

95 

85 

96 

73 

92 

91 

81 

97 

"'o Ree 

83 

Cone 

pg 

<1.3 

<0.69 

<0.90 

<0.59 

<0.80 

<1.0 

<0.56 

<0.63 

pg 

0.00 

2.77 

40-130 

40-130 

25-130 

25-130 

40-130 

40-130 

40-130 

25-130 

40-130 

EDl 

Pll 

1.3 

0.69 

0.90 

0.59 

0.80 

1.0 

0.56 

0.63 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency 

u Indicates that this compound was not detected above the MDL. 

n/s Indicates that this compound was not spiked. 

l indicates that a target analyte was detected below the LQL. 

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881100901.x!s 

Page 3 of 11 

C-49 
13C12-1,2,3,7,8-PeCDD 32:32 104 40-130 

13C12-1,2,3,6,7,8-HxCDD 34:46 99 40-130 

13C12-1,2,3,4,6,7,8-HpCDD 36:40 132 25-130 

13C12-0CDD 38:30 81 25-130 

13C12-2,3,7,8-TCDF 26:38 97 40-130 

13C12-1,2,3, 7,8-PeCDF 31:44 109 40-130 

13C12-1,2,3,6,7,8-HxCDF 34:17 106 40-130 

13C12-1,2,3,4,6, 7 ,8-HpCDF 36:01 89 25-130 

Cleanup Standard %Ree 

13C12·1,2,3, 7 ,8,9-HxCDF 35:09 93 40-130 

Cone EDL 

Homologue Group Totals #peaks pg pg 

Totai-TCDD 13 1880 1.0 

Totai-PeCDD 9 3770 3.8 

Totai-HxCDD 8 8210 3.1 

Totai-HpCDD 2 9120 2.2 

Totai-TCDF 9 141 1.1 

Totai-PeCDF 6 82.3 2.3 

Totai-HxCDF 1 2.22 1.6 

Totai-HpCDF 0 <0.91 0.91 

Toxic Equivalency NATO Pll 

Lower Bound PCDD/F TEQ 528 

Upper Bound PCDD/F TEQ 544 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic""' ·u·~" 

M Indicates that a peak has been manually Integrated. 

u Indicates that this compound was not detected above the MDL 

l indicates that a target analyte was detected below the LQL. 

R Indicates that the ion al:lundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881 100901.xls Page 4 of 11 

C-50 
13C12-1,2,3,7,8-PeCDD 32:33 58 

13C12-1,2,3,6, 7,8-HxCDD 34:46 94 

13C12-1,2,3,4,6, 7 ,8-HpCDD 36:46 123 

13C12-0CDD 38:30 76 

13C12-2,3,7,8-TCDF 26:39 50 

13C 12·1,2,3, 7 ,8-PeCDF 31:44 56 

13C12-1,2,3,6,7,8-HxCDF 34:17 101 

13C12-1,2,3,4,6,7,8-HpCDF 36:02 90 

Cleanup Standard "'oRee 

13C12·1,2,3, 7 ,8, 9-HxCDF 35:09 90 

Cone EDL 

Homologue Group Totals #peaks pg pg 

Totai-TCDD 16 2070 2.2 

Totai-PeCDD 8 4170 12 

Totai-HxCDD a 7620 17 

Totai-HpCDD 2 8550 4.2 

Totai-TCDF 3 129 1.4 

Totai·PeCDF 7 127 4.0 

Totai-HxCDF 2 14.3 1.7 

Totai-HpCDF 2 10.1 1.8 

Toxic Equivalency NATO pg 

Lower Bound PCDD/F TEQ 502 

Upper Bound PCDD/F TEQ 503 

40-130 

40-130 

25-130 

25-130 

40-130 

40-130 

40-130 

25-130 

40-130 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency 

M Indicates that a peak has been manually integrated. 

u Indicates that this compound was not detected above the MDL. 

l indicates that a target analyte was detected below the LQL. 

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881 100901.xls 

Page 5 of 11 

C-51 
13C12-1,2,3,7,8·PeCDD 

13C12-1,2,3,6,7,8-HXCDD 

13C12-1,2,3,4,6, 7,8-HpCDD 

13C12·0CDD 

13C12-2,3,7,8·TCDF 

13C12-1,2,3, 7,8-PeCDF 

13C12·1,2,3,6,7,8-HxCDF 

13C12-1 ,2,3,4,6, 7 ,8-HpCDF 

Cleanup Standard 

13C12-1,2,3, 7,8, 9-HxCDF 

Homologue Group Totals 

Totai-TCDD 

Totai·PeCDD 

Totai-HxCDD 

Totai-HpCDD 

Totai·TCDF 

Totai-PeCDF 

Totai-HxCDF 

Totai-HpCDF 

Toxic Equivalency NATO 

Lower Bound PCDD/F TEQ 

Upper Bound PCDD/F TEQ 

32:33 

34:46 

36:57 

38:31 

26:41 

31:44 

34:17 

36:04 

35:10 

#peaks 

15 

10 

s 

7 

9 

48 

105 

111 

60 

45 

57 

116 

78 

0/o Rec 

85 

Cone EDL 

pg pg 

2650 0.99 

5380 4.1 

7760 3.4 

9180 8.3 

250 3.2 

86.2 3.2 

pg 

573 

577 

M 

40-130 

40-130 

25-130 

25-130 

40-130 

40-130 

40-130 

25-130 

40-130 

~.· i 

,·; 

... 

,: ;:~ ·.· 

.. ,.; ~) 

.. -,;· 

•" ·' 

OJo Recovery 

# peaks 

2 

Cone 

pg 

45.9 

13.3 

EDL 

pg 

9.0 

9.4 

;.~ 

EDL lndicatas the Estlmatad Detection Limit, based on the measured background noise for this target In this sample. 

TEF Indicates the Toxic EQuivalency Factor TEQ Indicates the Toxic Equivalency 

M Indicates that a peak has been manually integrated. 

U Indicates that this compound was not detected above the MDL. 

J indicates that a target analyte was detected below the LQL. 

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881100901.xls 

C-52 

Page 6 of 11 
13C12-l,2,3,7 ,8-PeCDD 32:32 94 40-130 

13C12-1,2,3,6,7,8-HxCDD 34:46 90 40-130 

13C12-1,2,3,4,6,7,8-HpCDD 36:38 85 25-130 

13C12-0CDD 38:29 56 25-130 

13Cl2-2,3, 7,8-TCDF 26:37 82 40-130 

13Cl2-1, 2,3, 7,8-PeCDF 31:43 82 40-130 

13Cl2-1, 2,3,6,7,8-HxCDF 34:17 84 40-130 

13C12-1,2,3,4,6,7,8-HpCDF 36:01 80 25-130 

Cleanup Standard 0/o Rec 

13C12-1,2.,3, 7,8, 9-HxCDF 35:09 89 40-130 

Cone EDL 

Homologue Group Totals #peaks pg pg 

Total-TCDD 0 <2.5 2.5 

Totai-PeCDD 2 8.78 3.1 

Totai-HxCDD 0 <2.5 2.5 

Totai-HpCDD 2 259 6.2 

Totai-TCDF 0 <1.1 1.1 

Total-PeCDF 0 <1.2 1.2 

Total-HxCDF 0 <0.94 0.94 

Totai-HpCDF 0 <0.91 0.91 

Toxic Equivalency NATO pg 

Lower Bound PCDD/F TEQ 2.74 

Upper Bound PCDD/F TEQ 10.2 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency 

M Indicates that a peak has been manually integrated. 

u Indicates that this compound was not detected above the MDL. 

J indicates that a target analyte was detected below the LQL. 

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881100901.xls Page 7 of 11 

C-53 
13C12-1,2,3, 7,8-PeCDD 

13C12-1,2,3,6,7,8-HxCDD 

13C12-1,2,3,4,6,7,8-HpCDD 

13C12-0CDD 

13C12-2,3,7,8-TCDF 

13C12-1,2,3,7,8-PeCDF 

13C12·1,2,3,6,7,8-HxCDF 

13C12·1,2,3,4,6,7,8-HpCDF 

Cleanup Standard 

13C12-1,2,3,7,8,9-HxCDF 

Homologue Group Totals 

Totai-TCDD 

Totai-PeCDD 

Totai-HxCDD 

Totai-HpCDD 

Totai-TCDF 

Totai-PeCDF 

Totai-HxCDF 

32:32 115 

34:46 89 

36:39 94 

38:30 56 

26:38 86 

31:43 119 

34:17 94 

36:01 84 

%Rec 

35:09 92 

Cone EDL 

#peaks pg pg 

0 <2.5 2.5 

4 16.7 1.9 

1 23.7 2.1 

2 142 3.5 

0 <1.1 1.1 

0 <1.6 1.6 

0 <0.65 0.65 

40-130 

40-130 

25-130 

25-130 

40-130 

40-130 

40-130 

25-130 

40-130 

Totai-HpCDF 0 <0.86 0.86 

Toxic Equivalency NATO Pll 

Lower Bound PCDD/F TEQ 1.48 

Upper Bound PCDD/F TEQ 12.3 

EDL Indicates the Estimated Detection Lim1t, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency 

M Indicates that a peak has been manually integrated. 

u Indicates that this compound was not detected above the MDL. 

J indicates that a target analyte was detected below the LQL. 

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881100901.xls 

C-54 

Page a of 11 
13C12-1,2,3, 7,8-PeCDD 32:32 95 

13C12-1,2,3,6, 7 ,8-HxCDD 34:45 87 

13C12-1,2,3,4,6, 7 ,8-HpCDD 36:38 100 

13C12-0CDD 38:30 65 

13C12-2,3,7,8-TCDF 26:37 82 

13Cl2-1,2,3,7,8-PeCDF 31:43 83 

13C12-1,2,3,6,7,8-HxCDF 34:17 79 

1302-1,2,3,4,6, 7 ,8-HpCDF 36:01 80 

Cleanup Standard o/oRec 

13C12-1,2,3,7,8,9-HxCDF 3S:09 85 

Cone EDL 

Homologue Group Totals #peaks pg pg 

Totai-TCDD 0 <2.8 2.8 

Totai-PeCDD s 28.8 1.1 

Totai-HxCDD 2 54.1 2.0 

Totai-HpCDD 2 352 6.8 

Totai-TCDF 0 <1.6 1.6 

Totai-PeCDf 0 <2.0 2.0 

Totai-HxCDF 1 1.68 1.0 

Totai-HpCDF 0 <1.4 1.4 

Toxic Equivalency NATO pg 

lower Bound PCDD/F TEQ 8.61 

Upper Bound PCDD/F TEQ 15.5 

40-130 

40-130 

25-130 

25-130 

40-130 

40-130 

40-130 

2S-130 

40-130 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency 

M Indicates that a peak has been manually integrated. 

u Indicates that this compound was not detected above the MDL. 

J indicates that a target analyte was detected below the LQL. 

R Indicates that the lon abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L918881 100901 .xis Page 9 of 11 

C-55 
13C12·1,2,3,7,8·PeCDD 32:33 125 40-130 

13C12-1,2,3,6,7,8-HxCDD 34:46 102 40-130 

13C12·1,2,3,4,6,7,8-HpCDD 36:38 83 25·130 

13C12-0CDD 38:29 60 25·130 

13C12-2,3,7,8-TCDF 26:38 96 40·130 

13C12-1,2,3, 7,8-PeCDF 31:44 123 40·130 

13C12-1,2,3,6, 7,8-HxCDF 34:17 88 40-130 

13C12-1,2,3,4,6, 7 ,8-HpCDF 36:01 83 25-130 

Cleanup Standard %Rec 

13C12·1,2,3, 7,8,9-HxCDF 35:09 83 40·130 

Cone EDL 

Homologue Group Totals #peaks pg pg 

Totai-TCDD 0 <1.0 1.0 

Totai-PeCDD 0 <0.79 0.79 

Totai·HxCDD 1 3.34 0.79 

Totai-HpCDD 0 <1.0 1.0 

Totai-TCDF 0 <0.79 0.79 

Totai-PeCDF 0 <1.0 1.0 

Totai-HxCDF 0 <0.63 0.63 

Totai-HpCDF 0 <0.54 0.54 

Toxic Equivalency NATO pg 

Lower Bound PCDD/F TEQ 0.125 

Upper Bound PCDD/F TEQ 2.67 

EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. 

TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic EqUivalency 

u Indicates that this compound was not detected above the MDL. 

J indicates that a target analyte was detected below the LQL. 

R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. 

ALS Canada Ltd L916661100901.xls Page 10 of 11 

C-56 
13C12-1,2,3, 7,8-PeCDD 

13C12-1,2,3,6, 7,8-HxCDD 

13C12-1,2,3,4,6, 7 ,8-HpCDD 

13C12-0CDD 

13C12·2,3,7,8-TCDF 

13C12-1,2,3,7,8-PeCDF 

13C12·1,2,3,6,7,8-HxCDF 

13C12·1,2,3,4,6,7,8-HpCDF 

Cleanup Standard 

13C12-1,2,3, 7,8,9-HxCDF 

32:33 105 

34:46 101 

36:38 80 

38:30 49 

26:38 88 

31:43 93 

34:17 80 

36:01 83 

0/o Rec 

35:09 70 

40-130 

40-130 

25-130 

25-130 

40-130 

40-130 

40-130 

25-130 

40-130 

%Recovery 

nfs Indicates that this compound was not spiked 

M Indicates that a peak has been manually integrated. 

ALS Canada Ltd L91BBB1 100901.xls 

Page11of11 

C-57 
0 

I 

(.11 

(X) 

CLIENT: 

LOCATION: 

SAMPLE DATES: 

ANALYSIS: 

METHOD: 

Identification 

TK19-M29-1 

TK19-M29-1 TK19-M29-2 TK19-M29-2 TK19-M29-3 TK19-M29-3 

Acetone Blank 

Filter Blank 

SBE-M5-1 SBE-M5-1 SBE-M5-2 SBE-M5-2 SBE-M5-3 SBE-M5-3 

Acetone Blank 

-----

FILTE

PW 

FILTE

PW 

FILTER 

PW 

PW 

FILTER FILTER 

PW 

FILTER 

PW 

FILTER 

PW PW 
5.0 PROCEDURE: Follow the procedure below. 

5.1 Obtain reagent blank material of the same matrix as the sample. 

5.2 Determine the spiking level for the MDL study. This may include: 

a. the level of the lowest calibration standard, 

b. a level either 1/5 to 1/10 the level of the lowest calibration standard, or 

c. any level determined to be above three times the signal to noise ratio obtained by 

setting the area reject to zero and averaging the baseline plus three times the 

standard deviation of all the area detects. 

5.3 Prepare at least eight replicates of this sample and carry it through the entire analytic 

procedure. This must be done for every sample matrix to be analyzed using this 

method. 

5.4 Analyze the replicates as samples. 

5.5 The MDL is calculated using the following procedure as an example: 

Eight samples are prepared at 0.10 ppmv and analyzed following the method. 

Procedure For Determination of Method Detection Limit 

C-59 
0.08235 

Determine the square of the mean value 

0.10125A2: 0.010252 

Determine the average mean square sum 

0.010252 X 8 replicates = 0.082013 

Subtract the average mean square sum from the sum of the squares 

0.08235- 0.082013 = 0.000338 

Divide this number by the number of replicates minus one 

0.000338/ (8-1) = 0.00008421429 

Take the square root of the value obtained 

(0.00008421429) "0.5 = 0.006943651 (rounded to 9 figures) 

The above value is the Standard Deviation 

C,§r<6cedure For Determination of Method Detection Limit 
different than a blank sample. 

If the level you ran the eight replicates is less than this value, you must repeat the 

entire study with a higher concentration. 

Example: If this had been determined by running eight replicates at 0.010 ppmv, the 

study is invalid. 

If the level you chose to run the MDL study is less than five times this value, nothing 

more needs to be done. You can report data at the 0.10 ppmv MDL if it meets the 

clients needs. The final verification step has been done by the eight replicates of the 

study. 

If the MDL result obtained is less than five times the value you ran the study at, you 

must re-run the study to use it. 

Example: If you had run eight replicates at 0.10 ppmv and you obtained a MDL of 

0.0098 

0.10/0.0098 = 10.204 10.204 is greater than 5 times the study spiked level. 

You must re-run the MDL study at a lower spiked level to claim a MDL less than 

0.020 ppmv for eight replicates spiked at 0.10 ppmv. 

Procedure For Determination of Method Detection Limit C-61 
not meet a method or instrument expectation, but meets a particular regulatory 

requirement, may be an acceptable method for the determination of regulatory 

compliance. 

6.0 Definitions: Other definitions related to the MDL 

Practical Quantitation Limit (PQL) (EQL): The level of analyte that can be reliably 

achieved within specified limits of precision and accuracy during routine lab 

analysis. The POL has been estimated to be two to five times the MDL. 

Limit of Quantitation (LOQ): The level of the lowest calibration standard on the 

calibration curve. This is the same as the Method Ouantitation Limit (MOL) 

Limit of Detection (LOD): Defined as the lowest concentration level that can be 

reported with 99% confidence that an analyte has been detected and is statistically 

different than a blank non detect. 

Instrument Detection Limit (IDL): Defined as a concentration that produces a 

signal greater that three times the standard deviation of the mean noise level of 

the instrument. No sample preparation steps are required. It can be determined in 

the same manner as an MDL, but delete sample preparation steps (digestion or 

distillation). An IDL may be one half to one fourth of its MDL. If there are no 

sample preparation steps, the MDL and the IDL are essentially the same. 

C,9fbcedure For Determination of Method Detection Limit 
Procedure For Determination of Method Detection Limit C-63 
C-64 

14 

15 

Total Population 

t-Test Population (n-1) 

Average RM reading 

Standard Deviation 

Student t- Test Value 

LOD 

LOQ 

LOD =Limit of detection (same as MDL • method detction limit) 

,

1,000.1 

1,000.1 

15 

14 

1,000.080 

0.056 

2.624 

LOQ = Limit of quantitation (same as PQL ·practical quantitation limit) 

LOD =Student's t value x the standard deviation 

The US EPA defines LOD (MDL) as "the minimum concentration that can be determined with 99% confidence 

that the true concentration is greater than zero." This procedure is outlined in 40CFR 136 and TTN EMC 

studooft~Tesl:Natues.2..S!ded 99% Confidence.·: 

t-restPoputation · · · t,Testvatue 

7 2.998 

8 2.896 

9 2.821 

10 2.764 

11 2.718 

12 2.681 

13 2.650 

14 2.624 
13 

14 

15 

Total Population 

t-Test Population (n-1) 

Average RM reading 

Standard Deviation 

Student t- Test Value 

LOD 

LOQ 

LOD =Limit of detection (same as MDL -method detction limit) 

100,000.0 

100,000.1 

100 1 

15 

14 

100,000.033 

0.049 

2.624 

LOQ = Limit of quantitation (same as PQL practical quantitation limit) 

LOD =Student's t value x the standard deviation 

The US EPA defines LOD (MDL) as "the minimum concentration that can be determined with 99% confidence 

that the true concentration is greater than zero." This procedure is outlined in 40CFR 136 and TTN EMC 

,stud~MestValulis.2-Sided99% Coqfld,en.ce ; ... ,,· • · t-T~t P<:>pulatlon · · t~re~.Vtilue · .... ·. · 

7 2.998 

8 2.896 

9 2.821 

10 2.764 

11 

12 

13 

14 

2.718 

2.681 

2.650 

2.624 

C-65 
C-66 

13 

14 

15 

Total Population 

t-Test Population (n-1) 

Average RM reading 

Standard Deviation 

Student t- Test Value 

LOD 

LOQ 

LOD =Limit of detection (same as MDL. method detction limit) 

200,000.0 

200,000.0 

15 

14 

200,000.013 

0.035 

2.624 

LOQ =Limit of quantitation (same as PQL- practical quantitation limit) 

LOD =Student's t value x the standard deviation 

The USEPA defines LOD (MDL) as "the minimum concentration that can be determined with 99% confidence 

that the true concentration is greater than zero." This procedure is outlined in 40CFR 136 and TTN EMC 

StudimJ·.N~tVall.l:S2-Sided99% yoofide~~· '(+ 

t-Testf'opulatlpn · .. FFestVaiUe 

7 2.998 

8 2.896 

9 2.821 

10 2.764 

11 2.718 

12 2.681 

13 2.650 

14 2.624 
14 

15 

Total Population 

t-Test Population (n-1) 

Average RM reading 

Standard Deviation 

Student t- Test Value 

LOD 

LOQ (3 times LOD) 

L OD =Limit of detection (same as MDL -method detction limit) 

10 

9 

0.090 

0.004 

2.821 

0.010 

0.030 

LOQ =Limit of quantitation (same as PQL practical quantitation limit) 

LOD =Student's t value x the standard deviation 

LOQ = LOD x 3 

The USEPA defines LOD (MDL) as "the minimum concentration that can be determined with 99% confidence 

that the true concentration is greater than zero ... This procedure is outlined in 40CFR 136 and TTN EMC 

Student t-Test Values 2-Sided 99% Confidence 

t-Test Population t-Test Value 

7 2.998 

8 2.896 

9 2.821 

10 2.764 

11 2.718 

12 2.681 

13 2.650 

14 2.624 C-67 
() 

I 

0'> 

C» 

Detection Limit Stu

Flouride Determina

Std. 

0.0 

0.5 

1.0 

2.0 

5.0 

Sa

ID A

(

Injection 82 

Injection 83 

Injection 84 

Injection 85 

Injection 86 

Injection 87 

Injection 88 

InJection 89 

Injection 90 

Injection 91 

=- 6.0 

E 

0, 5.0 

::t 

:4.0 

s:::: 8 3.0 ~ 2.0 

"t: 

:::3 1.0 

0 

u:: 0.0 

0.0 
14 

15 

Total Population 

t-Test Population (n-1) 

Average RM reading 

Standard Deviation 

Student t- Test Value 

LOD 

LOQ (3 times LOD) 

LOD =Limit of detection (same as MDL- method deletion limit) 

10 

9 

0.169 

0.027 

2.821 

0.076 

0.229 

LOQ = Limit of quantitation (same as PQL ·practical quantitation limit) 

LOD Student's t value x the standard deviation 

LOQ = LODx 3 

The USEPA defines LOD (MDL) as "the minimum concentration that can be determined with 99% confidence 

that the true concentration is greater than zero." This procedure is outlined in 4QCFR 136 and TTN EMC 

Student t-Test Values 2-Sided 99% Confidence 

t-Test Population t-Test Value 

7 2.998 

8 2.896 

9 2.821 

10 2.764 

11 2.718 

12 2.681 

13 2.650 

14 2.624 C-69 
() 

I 

-....! 

0 

Detection Limit St

Chloride Determin

Std. 

(pg/ml) 

00 

05 

1 0 

2.0 

5.0 

Sa

10 

Injection 82 

Injection 83 

Injection 84 

InJection 85 

Injection 86 

Injection 87 

InJection 88 

Injection 89 

InJection 90 

.. . Injection 91 

·-

E 

0, 5.0 

::t. 

-:- 4.0 

(..) 

1: 

0 3.0 

u ~ 2.0 

'i: 

0 1.0 

..r:: 

u 0.0 

0.0 
1.00~ ' 

No. 

1 

2 

3 

4 

Total: 

Ret. Time 

min 

4.25 

6.05 

13.45 

16.92 

Peak Name Height 

llS 

Flouride 0.086 

Chloride 0.104 

Phosphate 0.008 

Sulfate 0.024 

0.222 

SulfateArea/lntegration 

Area 

llS*min 

0.0170 

0.0196 

0.0029 

0.0115 

0.051 

3 - Phosphate • 1 ?.44?- Sulfate • 

' 

min 

12.5 15.0 19 0 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-71 
C-72 

l 

i 

1.oo-j 

~ j 

j_ __ ___, ~~ct~ ~t!li:Jride- 6.050 

1 

I/ I . 

I i It 

-0.50 ° I 

o:o 2.5 

No. Ret. Time 

I 

5.0 

Peak Name 

I 

7.5 

Height 

I 

10.0 

Area 

min us uS*min 

1 4.25 Flouride 0.085 0.0164 

2 6.05 Chloride 0.096 0.0180 

3 13.50 Phosphate 0.007 0.0028 

4 16.93 Sulfate 0.024 0.0119 

Total: 0.211 0.049 

Sulf ateArea/1 ntegr a !ion 

3 • Phosphate • 1 j3.497' Sulfate .\ 

. 

1 

minj I 

12.5 15.0 19.0 

Chromeleon (C) Dionex 1996-2001 

Version 6.60 Build 1428 
J 

I 

1.00---j 

~ 

t

l , 1 - FlouridJ~-~--~!P-f-id_e_-_·_050 _____ ---'· 3. Phosphate -13.4~ Sulfate- l 

-0.50-+1--.--,---.-,---.,---'+-1 

\/~ 

J• ---r--r--..----;--r---,-~,..--,---,-~-,---r---r--,--.,---,- I t 1 -~,--,-,-,---.-,---,---,---c-l 

~I 

mi~ 0.0 2.5 5.0 7.5 10.0 12.5 15.0 19.0 

No. Ret. Time Peak Name Height Area 

min ~s 1-iS*min 

1 4.24 Flouride 0.087 0.0180 

2 6.05 Chloride 0.118 0.0222 

3 13.43 Phosphate 0.008 0.0030 

4 16.92 Sulfate 0.023 0.0101 

Total: 0.235 0.053 

SulfateArea/lntegration 

Chrorneleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 

C-73 
C-74 

No. Ret. Time Peak Name Height Area 

min 118 1-lS*min 

1 4.25 Flouride 0.085 0.0165 

2 6.05 Chloride 0.118 0.0221 

3 13.48 Phosphate 0.008 0.0025 

4 16.91 Sulfate 0.021 0.0088 

Total: 0.232 0 050 

S ulfateArea/1 ntegration 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
1.00~ 

-6.047 

No. Ret. Time Peak Name Height Area 

min l-IS 1-!S*min 

1 4.24 Flouride 0.086 0.0163 

2 6.05 Chloride 0.129 0.0245 

3 13.44 Phosphate 0.007 0.0021 

4 16 92 Sulfate 0.025 0.0118 

Total: 0.246 0.055 

SullateArea/lntegration 

Chromeleon (c) Oionex 1996-2001 

Version 6.60 Build 1428 

C-75 
C-76 

1.00~ 

l 

1 - Flouri<M: ~~Jwide - 6.050 ,,-......_ I~\ 

~~···, 

, 3

1 

- Phosphate . 13.~4 1

Sulfate ·j 

I . 

1

1 min -o .so_l:~-,-.,--,-.---,-,-'+--,--,--,---,1--,-~c---;-~ -.---.-~-,-, -.-----,----,.--,---.---.--,--, -.-.--,---,---,-----'~ 

' 

0.0 2.5 5.0 7.5 10.0 12.5 15.0 19.0 

No. Ret. Time Peak Name 

min 

1 4.25 Flouride 

2 6.05 Chlonde 

3 13.48 Phosphate 

4 16.92 Sulfate 

Total: 

S ulf ateAreail ntegration 

Height 

us 

0.087 

0.138 

0.003 

0.023 

0.251 

Area 

uS* min 

0.0180 

0.0261 

0 0009 

0.0104 

0.055 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
1 00~ 

~F-Io_u_ri~"-'--c=_&_2!ttf_id_e_-_

6

·

0

_

4

_

7 

______ ---------'. _3~ Phosphate- 13.440- SulfateNo. Ret. Time Peak Name 

min 

1 4.24 Flouride 

2 6.05 Chloride 

3 13.44 Phosphate 

4 16.92 Sulfate 

Total: 

Su l!ateArea/1 ntegrati on 

Height 

!lS 

0.087 

0.138 

0.004 

0.024 

0.252 

Area 

IJS*min 

0.0179 

0.0261 

0.0010 

0.0104 

0.055 

Chromeleon (cl Dionex 1996-2001 

Version 6.60 Build 1428 

C-77 
l 

1.00~ 

No. 

1 

2 

3 

4 

Total: 

Ret. Time 

min 

4.25 

6.05 

13.47 

16.91 

1 - Flouridi- 4:.1t!W"ide - 6.050 

.~, ·~~~------------ ; 

Peak Name Height 

us 

Flouride 0.086 

Chloride 0.087 

Phosphate 0.006 

Sulfate 0.023 

0.201 

SulfateArea/lntegration 

Area 

uS* min 

0.0169 

0.0157 

0.0019 

0.0104 

0.045 

. 3 - Phosphate • 13.467' Sulfate • 

12.5 15.0 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
No. 

1 

2 

3 

4 

Total: 

Ret. Time 

min 

4.25 

6.05 

13.49 

16.88 

Peak Name Height 

us 

Flouride 0.084 

Chloride 0.116 

Phosphate 0.007 

Sulfate 0.022 

0.229 

SulfateAreailntegration 

Area 

uS* min 

0.0166 

0.0218 

0.0028 

0.0102 

0.051 

12.5 

Chromeleon (C) Oionex 1996-2001 

Version 6.60 Build 1428 

C-79 
C-80 

No. Ret. Time Peak Name Height Area 

min us uS*min 

1 4.24 Flouride 0.085 0.0173 

2 6 05 Chloride 0.134 0.0256 

3 13.55 Phosphate 0.013 0.0055 

Total: 0.232 0.048 

SulfateArea11ntegration 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
No. 

1 

Total: 

Ret. Time Peak Name 

min 

13.43 Phosphate 

SulfateArea/lntegration 

Height 

11S 

0.079 

0.079 

Area 

llS*min 

0.035 

0.035 

Chromeleon IC) Oionex 1996-2001 

Version 6.60 Build 1428 

C-81 
C-82 

1 00~ 

No. Ret. Time 

min 

Peak Name 

1 13.44 Phosphate 

Total: 

SullateArea/lntegration 

Height Area 

llS llS*min 

0.167 0.074 

0.167 0.074 

t'no,spnlate - 13.437 

Cilromeleon (c) 01onex 1996-2001 

Version 6.60 Build 1428 
No. Ret. Time Peak Name 

min 

1 13.44 Phosphate 

Total: 

SulfateArea11ntegration 

7.5 

Height Area 

llS llS*min 

0.405 0.178 

0.405 0.178 

Phosphate- 13.444 

Chromeleon Dionex 1996-2001 

Version 6.60 Build 1428 

C-83 
C-84 

I 

1.00-i I 

No. Ret. Time 

min 

1 4.24 

2 6.05 

3 16.90 

Total: 

.

1 • Ftourid~ : ~~fb'\-ide • 6.047 i\ ~ 

Peak Name Height 

us 

Flouride 0.425 

Chloride 0.343 

Sulfate 0.102 

0.871 

SullateArea/lntegration 

Area 

uS*min 

0.088 

0.068 

0.049 

0.204 

Chromeleon Dionex 1996 · 2001 

Version 6.60 Build 1428 
l 

1.00--1 

I 

J 

No. 

1 

2 

3 

Total: 

Ret. Time 

min 

4.24 

6.05 

16.90 

1 - Flouride • 4.240 

2- Chloride 6.047 

Peak Name Height 

!lS 

Flouride 0.875 

Chloride 0.724 

Sulfate 0.194 

1.793 

SulfateArea;lntegration 

Area 

1-!S .. min 

0.181 

0.147 

0.094 

0.422 

·SulfateChrome!eon (c) Oionex 1996-2001 

Version 6.60 Build 1428 

C-85 
C-86 

2 - Chloride - 6.057 

0.0 2.5 5.0 

No. Ret. Time Peak Name Height 

min l-IS 

1 4.25 Flouride 1.814 

2 6.06 Chloride 1.282 

3 16.90 Sulfate 0.386 

Total: 3.481 

SullateAreailntegration 

Area 

!lS*min 

0.374 

0.261 

0.187 

0.822 

3 ·Sulfate· ·'\ 

\ 

Chromeleon (c) Dionex 1996-2001 

Version 6.60 Build 1428 
1.00~ 

5.0 7.5 

No. Ret. Time Peak Name Height 

min us 

1 4.24 Flouride 4.824 

2 6.05 Chloride 3.229 

3 16.90 Sulfate 0.979 

Total: 9.032 

SulfateArea/lntegration 

Area 

11S*min 

0.958 

0.658 

0.475 

2.091 

19.0 

Chromeleon (C) D1onex 1996-2001 

Version 6.60 Build 1428 

C-87 
PHONE+1 905 3313111 

FAX+ 1 905 331 4567 

www.alsglobal.com 

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C-88 1 
899-02 
D-1 
D-2 
D-3 
0-4 
899-02 
m 

I 

..... 

Meter Console Information 

ConiiOie Model Number MC

Console Serial Number 503

DGM Model Number MS

DGM Serial Number DG

1For valid test results, the Actual Vacuu

~-·- -··---· -~·..--- ---···-....... , .. ' ... • -- 

Run Time 

DGMOrlllce 

Elapsed .AH 

(0) (P..,) 

min lnH,O 

13.0 3.4 

12.0 2.0 

12.0 1.2 

13.0 0.7 

18.0 0.3 

Standardized 

Drv Gas Meter 

(V....,) (Omr""') 

cubic feet crm 

13.018 1.001 

8.991 0.749 

6.887 0.574 

5.775 0.444 

5.329 0.296 
m 

I 

1'\l 

Meter Console lnfonnatlon 

Console Model Number MC

Console Serial Number 

503

DGM Model Number MS

OGM Serial Number DG

1For valid test results, the Actual Vacuu

• ··- -··~·--· -· ~---- ---···-·-··~· .,. l ···--· -- 

Run Time 

DGMOrlflce 

Elapsed AH 

(El) (Pm) 

min inH:P 

10.0 2.0 

13.0 2.0 

12.0 2.0 

Standardized 

Dry Gas Meter 

(Vm...,) (Om.w) 

cubic feet cfm 

7.489 0.749 

9.757 0.751 

9.016 0.751 

Pretest Gamma 0.995 

(Noie:FOrealibretion FactorY, the ratio of lhe r
m 

I 

w 

lilelor Consolo tnf

Console Mode1 Number 

ConsoJe Serial Number 

Number 

Numbor 

'For valid test results, the Actua

···- -····--· _. .... ---•••-•-••• ,,. 

RunTime 

DGMOrillc

Elapaed AH 

(Ell (P.,.) 

min lnH,.O 

17.0 0.2 

11.0 0.6 

12.0 1.0 

10.0 1.7 

10.0 3.1 

Starn

Dry Gao Meter 

(II .... ..! co,.,..,, 

cubic feet cfm 

5.054 0.297 

4.925 0.448 

6.960 0.560 

7.635 0.764 

10.239 1.02.4 
m 

J,.. 

Meter Console Informa

Console Model Number 

Console Serial Number 

DGM Model Number DGM Serial Number 

1For valid test results, the Actual Va

... _ 

-----

. ·-·····--· -·--···-·- .• , ··• ···--

Run Time 

DGM Orifice 

Elaosed AH 

(®) (Pml 

min in H20 

10.0 1.7 

10.0 1.7 

10.0 1.7 

Standard

Dry Gas Meter 

(V""',.) (0,.,,.,) 

cubic feet elm 

7.560 0.756 

7.575 0.757 

7.570 0.757 

Pretest Gamma 0.986 

[Noie: For Ca!iiifaiiOilfaCiO< Y, the ratio of 
m 

I 

01 

Meter Console Jnfonm

Console Model Number 

Console Serial Number 

OGM Model Number 

OGM Serial Number 

'For valid test resultS, the Actual va

'T ~nv WlUI'-Iill Vnlt"'V YVIifiiiVIVUIJ 0 t IU ... P

RunTime 

OGMOrlflce 

Elaosed 4H 

(9) (PmJ 

min lnH,O 

10.0 3.2 

13.0 1.8 

10.0 1.0 

18.0 0.8 

21.0 0.3 

Standard

DtV Gas Meter 

cv .. ...J (Omt""") 

cubic feet elm 

10.072 1.007 

9.644 0.757 

5.776 0.578 

8.061 0.446 

6.285 0.299 

INciiO:ForC'iiiibrallon Factor v, lhe ra~o of 
m 

I 

m 

Meter Console Informa

Console Model Number 

Console Serial Number 

DGM Model Number 

DGM Serial Number 

1For valid test resuhs, the Actual Va

···- ·-····--· -····--

___ , ........... ,,, ... 

Run Time 

DGMOrilica 

Elapsed aH 

(6) (Pml 

min in H20 

10.0 1.8 

10.0 1.8 10.0 1.8 

Standard

Dry Gas Meter 

(Vmt•tdl) (Q""'"") 

cubic lee! ctm 

7.366 0.737 

7.347 0.735 

7.327 0.733 

Pretest Gamma __QJJ!J9 - 

(NO!e:For CalibiiiiioOfacior Y, the ratio of 
100 99 -0.18 99 

200 201 0.15 201 

300 302 0.26 3021 

400 398 -0.23 398 

500 499 -0.10 499 

Reference Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack stack 

0 0 0.00 

200 201 0.15 

400 398 -0.23 

600 601 0.09 

800 803 0.24 

1000 1003 0.21 

-0.18 99 -0.18 

0.15 202 0.30 

358.03 302 0.26 

-0.23 398 -0.23 

-0.10 499 -0.10 

Reference Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack Stack 

1200 1202 0.12 

1400 1400 0.00 

1600 1603 0.15 

1800 1801 0.04 

Revised 1 @!~ 
100 99 -0.18 99 

200 201 0.15 2201 

300 301 0.13 301 

400 398 -0.23 398 

500 499 -0.10 499 

Reference Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack Stack 

0 0 0.00 

200 201 0.15 

400 398 -0.23 

600 601 0.09 

800 803 0.24 

1000 1003 0.21 

E-8 

-0.18 

303.18 

0.13 

-0.23 

-0.10 

Reference 

99 -0.18 

201 0.15 

301 0.13 

398 -0.23 

499 -0.10 

Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack Stack 

1200 1201 0.06 

1400 1400 0.00 

1600 1602 0.10 

1800 1800 0.00 

Revised 1 0/03 
0 5 1.09 5 1.09 

100 102 0.36 102 0.36 

200 205 0.76 205 0.76 

300 304 0.53 304 0.53 

400 401 0.12 401 0.12 

500 501 0.10 501 0.10 

Ref. Thermometer Diff. Ref. 

Temp. Temp. (%}mean Temp. 

Altek Stack Stack Altek 

0 4 0.87 1200 

200 205 0.76 1400 

400 401 0.12 1600 

600 604 0.38 1800 

800 804 0.32 

1000 1004 0.27 

5 1.09 

102 0.36 

205 0.76 

304 0.53 

401 0.12 

501 0.10 

Thermometer Diff. 

Temp. (%)mean 

Stack Stack 

1201 0.06 

1400 0.00 

1604 0.19 

1803 0.13 

Revised 1 0/03 

E-9 
100 99 -0.18 98 

200 201 0.15 200 

300 300 0.00 300 

400 396 -0.47 397 

500 497 -0.31 497 

Reference Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack Stack 

0 0 0.00 

200 201 0.15 

400 397 -0.35 

600 600 0.00 

800 801 0.08 

1000 1000 0.00 

E-10 

-0.36 

0.00 

0.00 

-0.35 

-0.31 

Reference 

98 -0.36 

201 0.15 

300 0.00 

397 -0.35 

497 -0.31 

Thermometer Difference 

Temperature Temperature {%)mean 

Altek Stack Stack 

1200 1198 -0.12 

1400 1396 -0.22 

1600 1599 -0.05 

1800 1797 -0.13 

Revised 1 0/03 
100 98 -0.36 98 

200 199 -0.15 199 

300 300 0.00 300 

400 396 -0.47 396 

500 497 -0.31 497 

Reference Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack Stack 

0 -1 -0.22 

200 199 -0.15 

400 396 -0.47 

600 599 -0.09 

800 800 0.00 

1000 999 -0.07 

-0.36 98 -0.36 

-0.15 200 0.00 

0.00 300 0.00 

-0.47 396 -0.47 

-0.31 497 -0.31 

Reference Thermometer Difference 

Temperature Temperature (%)mean 

Altek Stack Stack 

1200 1197 -0.18 

1400 1395 -0.27 

1600 1598 -0.10 

1800 1795 -0.22 

Revised 10/03 

E-11 
100 100 0.00 100 

200 202 0.30 202 

300 301 0.13 301 

400 398 -0.23 398 

500 498 -0.21 498 

Reference Thermometer Difference 

Temperature Temperature {%}mean 

Altek Stack Stack 

0 1 0.22 

200 202 0.30 

400 398 -0.23 

600 600 0.00 

800 802 0.16 

1000 1001 0.07 

E-12 

0.00 

0.30 

0.13 

-0.23 

-0.21 

Reference 

100 0.00 

202 0.30 

301 0.13 

398 -0.23 

499 -0.10 

Thermometer Difference 

Temperature Temperature {%)mean 

Altek Stack Stack 

1200 1198 -0.12 

1400 1393 -0.38 

1600 1599 -0.05 

1800 1798 -0.09 

Revised 1 0/03 
0.430 0.39375 < PA< 0.5625 0.430 

0.430 0.39375 < PB< 0.5625 0.430 

0.375 O.t875 :$ Dt$ 0.375 0.375 

F¥ i 8'' -~ I : ' I \ ' 

Tmns\'crsc _ ! rv-i I {';:)(r:\ I 

TubeAxis ·-·~·-·~~--·-· 

I I ! 

0.015 A tan y < 0.125" 0.015 

0.01501 A tan 9 < 0.03125" 0.00000 

TRUE p A= PB +/- 0.063 TRUE 

PASS PASS/FAIL PASS 

Comments: 5' effective length s-type pitot tube, 3/8" tips, K-type thermocouple, assembly attached to heated MS probe. 

Pitot tube/probe number 292 meets or exceeds all specifications and criteria and/or applicable 

design features (per 40CFR60 Appendix A; Method 2) and is heareby assigned a pi tot tube calibration 

factor of 0.84. 

Signature: 

Date: E ~3 
Transven;c 

Tube Axis 

·~-· B 

~· I f¥ ·~ I : ' I \ ' 

___ Jry-; __ j/?vB\1 ·-· 

~~~ 

0.360 

0.370 

0.250 

0.025 

0.00000 

TRUE 

PASS 

0.2625 <PA< 0.375 0.360 

0.2625 < PB< 0.375 0.370 

0.1875 :::; Dt::; 0.375 0.250 

A tan y < 0.125" 0.000 

A tan a < 0.03125" 0.00000 

p A = PB +/- 0.063 TRUE 

PASS/FAIL PASS 

Comments: 6' effective length M2 pitot tube, 1/4" tips, K-type thermocouple, and Orsat line enclosed in 1" OD sheath. 

Pitot tube/probe number 692 meets or exceeds all specifications and criteria and/or applicable 

design features (per 40CFR60 Appendix A; Method 2) and is heareby assigned a pi tot tube calibration 

factor of 0.84. 

Signature: 

Date: 

E-14 
0.360 0.2625 <PA<0.375 

0.370 0.2625 <P8< 0.375 

0.250 0.1875 ::£DrS 0.375 

ri I ~ ·q I : · t \ · 

Tfla~~YAcm: ·-· ~ . _jf;:VB\1 . -· \lw~1S ~ ~~ 

i I ~ 

0.000 A tan y < 0.125" 

0.01274 A tan e < 0.03125" 

TRUE P A = Ps +/- 0.063 

PASS PASS/FAIL 

Comments: 6' effective length M2 s-type pitot tube, 1/4" tips, K-type thermocouple, enclosed in l" OD sheath. 

Pitot tube/probe number 836 meets or exceeds all specifications and criteria and/or applicable 

design features (per 40CFR60 Appendix A; Method 2) and is heareby assigned a pitot tube calibration 

factor of0.84. 

Signature: 

Date: 

0.360 

0.370 

0.250 

0.013 

0.00000 

TRUE 

PASS 

E-15 
0.450 0.39375 <PA< 0.5625 0.480 

0.460 0.39375 <P8< 0.5625 0.480 

0.375 0.1875 cS Dt$ 0.375 0.375 

0.032 A tan y < 0.125" 0.017 

0.01588 A tan a< 0.03125" 0.01676 

TRUE P A= P8 +/- 0.063 TRUE 

PASS PASS/FAIL PASS 

Comments: 4' effective lengths-type pitot assembly, 3/8" pitot tips, K-type thermocouple, attached to glass-lined M5 probe. 

Pitot tube/probe number 854 meets or exceeds all specifications and criteria and/or applicable 

design features (per 40CFR60 Appendix A; Method 2) and is heareby assigned a pitot tube calibration 

factor of 0.84. 

Signature: 

Date: 

E-16 
E-17 
E-18 
E-19 
E-20 
* Barometer is adjusted so that the difference is not to exceed 0.05" Hg 

** Barometer is not adjusted. If difference exceeds 0.10" Hg, inform project Mgr. 

*** Barometric pressure may be obtained from a National Weather Service station 

and adjusted for elevation at a rate of -2.5mm (0.1") Hg per 100ft. 

Note: The Weather Service reading is absolute barometric pressure. 

E-21 
899-02 
Fitzgerald has an extensive background in EPA sampling and analysis applications, incinerator 

design and optimization, VOC sampling and analysis, RCRA trial burn testing, sampling 

equipment design and fabrication, implementation of innovative sampling and analysis 

techniques, methods validation and R&D. Mr. Fitzgerald is presently certified as a QSTI by the 

Source Evaluation Society (SES) pursuant to the requirements of ASTM D7036-04. 

His source sampling experience includes conducting over 1 ,000 separate test programs involving 

emissions testing at automotive manufacturing, steel mills, refineries, printing operations, food 

processing, chemical plants, fume incineration systems, hazardous waste incinerators, bulk 

gasoline terminals and power plants. 

Jerry Bovee 

Mr. Bovee is a Senior Project Manager with ARI. His 19 years of experience includes emission 

compliance and CEM certification testing for a wide variety of industries including petrochemical, 

steel mills, electric utilities, cement plants, pulp and paper mills, asphalt plants and general 

manufacturing plants. Mr. Bovee is presently certified as a QSTI by the SES pursuant to the 

requirements of ASTM D7036-04. 

Nathan Sekulic 

Mr. Sekulic is a Project Manager with ARI. His 9 years experience includes emission compliance 

and CEM certification testing for a wide variety of industries including petrochemical, steel mills, 

electric utilities, cement plants, asphalt plants and general manufacturing plants. Mr. Sekulic is 

presently certified as a Ql by the SES pursuant to the requirements of ASTM D7036-04. 

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